WorldWideScience

Sample records for geologic natural analogue

  1. Biodegradation in oils as a geological natural analogue

    Energy Technology Data Exchange (ETDEWEB)

    Rojas, G. [Comision Nacional de Energia Atomica (Argentina)]. E-mail: rojasg@ciudad.com.ar; Julio Salvarredi, J. [Comision Nacional de Energia Atomica (Argentina)]. E-mail: salvarredi@ciudad.com.ar

    2004-07-01

    A synthesis of scientific knowledge about petroleum biodegradation linked to uranium mineralisation is firstly done. Then the genesis of Huemul Uranium ore deposit (Malargue Town, Mendoza Province) is discussed, where Uranium ore is linked only with one type of asphaltite (there are three other types) from an oil field close by. This asphaltite type would be an efficient natural geological barrier for Uranium migration and it could be linked to a particular kind of biodegradation. The authors think that the International Wonuc Conference would be a good opportunity to discuss a way for future investigations. (author)

  2. Natural Analogues of CO2 Geological Storage; Analogos Naturales del Almacenamiento Geologico de CO2

    Energy Technology Data Exchange (ETDEWEB)

    Perez del Villar, L.; Pelayo, M.; Recreo, F.

    2007-07-20

    Geological storage of carbon dioxide is nowadays, internationally considered as the most effective method for greenhouse gas emission mitigation, in order to minimize the global climate change universally accepted. Nevertheless, the possible risks derived of this long-term storage have a direct influence on its public acceptance. Among the favourable geological formations to store CO2, depleted oil and gas fields, deep saline reservoirs, and unamiable coal seams are highlighted. One of the most important objectives of the R and D projects related to the CO2 geological storage is the evaluation of the CO2 leakage rate through the above mentioned geological formations. Therefore, it is absolutely necessary to increase our knowledge on the interaction among CO2, storage and sealing formations, as well as on the flow paths and the physical resistance of the sealing formation. The quantification of the CO2 leakage rate is essential to evaluate the effects on the human and animal health, as well as for the ecosystem and water quality. To achieve these objectives, the study of the natural analogues is very useful in order to know the natural leakage rate to the atmosphere, its flow paths, the physical, chemical and mineralogical modifications due to the long term interaction processes among the CO2 and the storage and sealing formations, as well as the effects on the groundwaters and ecosystems. In this report, we have tried to summarise the main characteristics of the natural reservoirs and surficial sources of CO2, which are both natural analogues of the geological storage and CO2 leakage, studied in EEUU, Europe and Australia. The main objective of this summary is to find the possible applications for long-term risk prediction and for the performance assessment by means of conceptual and numerical modelling, which will allow to validate the predictive models of the CO2 storage behaviour, to design and develop suitable monitoring techniques to control the CO2 behaviour

  3. Gas geochemistry of natural analogues for the studies of geological CO{sub 2} sequestration

    Energy Technology Data Exchange (ETDEWEB)

    Voltattorni, N., E-mail: nunzia.voltattorni@ingv.it [Istituto Nazionale di Geofisica e Vulcanologia, Via di Vigna Murata no 605, 00143 Rome (Italy); Sciarra, A. [Istituto Nazionale di Geofisica e Vulcanologia, Via di Vigna Murata no 605, 00143 Rome (Italy); Caramanna, G. [Earth Science Dep., University ' La Sapienza' , Piazzale A. Moro no 5, 00185 Rome (Italy); Cinti, D.; Pizzino, L.; Quattrocchi, F. [Istituto Nazionale di Geofisica e Vulcanologia, Via di Vigna Murata no 605, 00143 Rome (Italy)

    2009-07-15

    Geological sequestration of anthropogenic CO{sub 2} appears to be a promising method for reducing the amount of greenhouse gases released to the atmosphere. Geochemical modelling of the storage capacity for CO{sub 2} in saline aquifers, sandstones and/or carbonates should be based on natural analogues both in situ and in the laboratory. The main focus of this paper has been to study natural gas emissions representing extremely attractive surrogates for the study and prediction of the possible consequences of leakage from geological sequestration sites of anthropogenic CO{sub 2} (i.e., the return to surface, potentially causing localised environmental problems). These include a comparison among three different Italian case histories: (i) the Solfatara crater (Phlegraean Fields caldera, southern Italy) is an ancient Roman spa. The area is characterised by intense and diffuse hydrothermal activity, testified by hot acidic mud pools, thermal springs and a large fumarolic field. Soil gas flux measurements show that the entire area discharges between 1200 and 1500 tons of CO{sub 2} per day; (ii) the Panarea Island (Aeolian Islands, southern Italy) where a huge submarine volcanic-hydrothermal gas burst occurred in November, 2002. The submarine gas emissions chemically modified seawater causing a strong modification of the marine ecosystem. All of the collected gases are CO{sub 2}-dominant (maximum value: 98.43 vol.%); (iii) the Tor Caldara area (Central Italy), located in a peripheral sector of the quiescent Alban Hills volcano, along the faults of the Ardea Basin transfer structure. The area is characterised by huge CO{sub 2} degassing both from water and soil. Although the above mentioned areas do not represent a storage scenario, these sites do provide many opportunities to study near-surface processes and to test monitoring methodologies.

  4. Tracing the CO2 source and migration in natural analogues from different geological contexts

    Science.gov (United States)

    Battani, A.; Jean Luc, F.; Philippe, S.; Nadine, E.; Olivier, V.; Elodie, J.

    2009-12-01

    Naturally occurring CO2 fields allow studying long-term fluid-rock interactions, and the processes of CO2 migration, useful for the prediction of CO2 behavior in industrial storage sites. Two different provinces showing both leaking systems (hydrothermal areas) and well confined systems (stable sedimentary basins) have been studied. The first province concerns the French CO2 province of Massif Central (volcanic events, seismic activity, high geothermal gradient) and the stable Valence basin. The other study was devoted to the Basin and Range province, USA, with hydrothermal, high seismic and volcanic activity, a high geothermal gradient (Soda Springs; Idaho, Sevier basin), and the non-hydrothermal stable area of the Colorado plateau (Green River, San Rafael anticline and Springerville). The aim is to link the CO2 sources and its subsurface migration to the geological context. In hydrothermal areas, the mesured helium isotopic ratio (R/Ra) is high (close to the mantle ratio), while the CO2/3He ratios move dramatically towards crustal values. In this context, isotopic and elemental noble gas data show that the gas migrates very fast from depth. In more confined areas (natural CO2 fields), the CO2 shows a more important proportion of radiogenic gases (4He) (crustal helium isotopic ratios) and the associated CO2/3He ratios are in the MORB range, or “mantle derived”. We try to explain the apparent discrepancy between the CO2/3He and the R/Ra values in both areas. As a primary assumption, the source of CO2 could be localized in the extensional zones of high geothermal gradient with important seismicity. We suggest that the pseudotachylites formed by frictional melting associated with each seismic event supply an instantaneous crustal CO2.amount to the initial magmatic CO2. This justifies the coeval increase of the CO2/3He ratios without any significant modification in the helium isotopic ratios (instantaneous, no time for 4He production). Moreover, the contact

  5. Oklo, natural analogue of the radionuclides migration through the geological barrier; Oklo, analogue naturel de la migration de radionucleides dans l`environnement

    Energy Technology Data Exchange (ETDEWEB)

    Louvat, D. [CEA Cadarache, 13 - Saint-Paul-lez-Durance (France). Dept. d`Entreposage et de Stockage des Dechets

    1998-12-31

    One of the main part of he CEC project `Oklo-Natural Analogue` is devoted to present time migration studies. This part comprises hydrogeology, groundwater chemistry, isotope geochemistry and modelling. Two sites are being investigated: the less perturbed reactor zone of the Oklo mine (OK84 in the southern mine extension of Okelobondo) at around 400 meters depth and the Bangombe reactor zone, sited in a shallow environment 30 km south of Oklo. The present contribution aims to define regional hydrogeology and hydro-chemistry boundary conditions for the modelling exercise, to assess the present day water-rock interaction in the vicinity of reactor zones, to gather information on the geochemical conditions which allowed the preservation of reactor zones for two billions years, to estimate the uranium migration from the reactor zone in using a natural marker (the depleted {sup 235}U/{sup 238}U ratio resulting from the fission) and to compare these data with predictive modelling. Based on the hydrogeological conceptual modelling, we have sampled waters in recharge areas, discharge areas above and below reactors, and in major local aquifers. We have been able to reconstruct the evolution of the groundwaters, in a way which is consistent with the hydrogeology, using major elements and environmental isotopes. (author) 24 refs.

  6. Natural Analogues - One Way to Help Build Public Confidence in the Predicted Performance of a Mined Geologic Repository for Nuclear Waste

    Energy Technology Data Exchange (ETDEWEB)

    Stuckless, J. S.

    2002-02-26

    The general public needs to have a way to judge the predicted long-term performance of the potential high-level nuclear waste repository at Yucca Mountain. The applicability and reliability of mathematical models used to make this prediction are neither easily understood nor accepted by the public. Natural analogues can provide the average person with a tool to assess the predicted performance and other scientific conclusions. For example, hydrologists with the Yucca Mountain Project have predicted that most of the water moving through the unsaturated zone at Yucca Mountain, Nevada will move through the host rock and around tunnels. Thus, seepage into tunnels is predicted to be a small percentage of available infiltration. This hypothesis can be tested experimentally and with some quantitative analogues. It can also be tested qualitatively using a variety of analogues such as (1) well-preserved Paleolithic to Neolithic paintings in caves and rock shelters, (2) biological remains preserved in caves and rock shelters, and (3) artifacts and paintings preserved in man-made underground openings. These examples can be found in materials that are generally available to the non-scientific public and can demonstrate the surprising degree of preservation of fragile and easily destroyed materials for very long periods of time within the unsaturated zone.

  7. Natural analogues of nuclear waste glass corrosion.

    Energy Technology Data Exchange (ETDEWEB)

    Abrajano, T.A. Jr.; Ebert, W.L.; Luo, J.S.

    1999-01-06

    This report reviews and summarizes studies performed to characterize the products and processes involved in the corrosion of natural glasses. Studies are also reviewed and evaluated on how well the corrosion of natural glasses in natural environments serves as an analogue for the corrosion of high-level radioactive waste glasses in an engineered geologic disposal system. A wide range of natural and experimental corrosion studies has been performed on three major groups of natural glasses: tektite, obsidian, and basalt. Studies of the corrosion of natural glass attempt to characterize both the nature of alteration products and the reaction kinetics. Information available on natural glass was then compared to corresponding information on the corrosion of nuclear waste glasses, specifically to resolve two key questions: (1) whether one or more natural glasses behave similarly to nuclear waste glasses in laboratory tests, and (2) how these similarities can be used to support projections of the long-term corrosion of nuclear waste glasses. The corrosion behavior of basaltic glasses was most similar to that of nuclear waste glasses, but the corrosion of tektite and obsidian glasses involves certain processes that also occur during the corrosion of nuclear waste glasses. The reactions and processes that control basalt glass dissolution are similar to those that are important in nuclear waste glass dissolution. The key reaction of the overall corrosion mechanism is network hydrolysis, which eventually breaks down the glass network structure that remains after the initial ion-exchange and diffusion processes. This review also highlights some unresolved issues related to the application of an analogue approach to predicting long-term behavior of nuclear waste glass corrosion, such as discrepancies between experimental and field-based estimates of kinetic parameters for basaltic glasses.

  8. The Valles natural analogue project

    Energy Technology Data Exchange (ETDEWEB)

    Stockman, H.; Krumhansl, J.; Ho, C. [Sandia National Labs., Albuquerque, NM (United States); McConnell, V. [Alaska Univ., Fairbanks, AK (United States). Geophysical Inst.

    1994-12-01

    The contact between an obsidian flow and a steep-walled tuff canyon was examined as an analogue for a highlevel waste repository. The analogue site is located in the Valles Caldera in New Mexico, where a massive obsidian flow filled a paleocanyon in the Battleship Rock tuff. The obsidian flow provided a heat source, analogous to waste panels or an igneous intrusion in a repository, and caused evaporation and migration of water. The tuff and obsidian samples were analyzed for major and trace elements and mineralogy by INAA, XRF, X-ray diffraction; and scanning electron microscopy and electron microprobe. Samples were also analyzed for D/H and {sup 39}Ar/{sup 4O} isotopic composition. Overall,the effects of the heating event seem to have been slight and limited to the tuff nearest the contact. There is some evidence of devitrification and migration of volatiles in the tuff within 10 meters of the contact, but variations in major and trace element chemistry are small and difficult to distinguish from the natural (pre-heating) variability of the rocks.

  9. MAQARIN natural analogue study: phase III

    Energy Technology Data Exchange (ETDEWEB)

    Alexander, W.R.; Mazurek, M.; Waber, H.N. [Univ. of Berne (Switzerland). Institutes of Geology, Mineralogy and Petrology, Rock-Water Interaction Group (GGWW); Arlinger, J.; Erlandson, A.C.; Hallbeck, L.; Pedersen, K. [Goeteborg University (Sweden). Dept. of General and Marine Microbiology; Boehlmann, W.; Fritz, P.; Geyer, S.; Geyer, W.; Hanschman, G.; Kopinke, F.D.; Poerschmann, J. [Umweltforschungszentrum Leipzig-Halle (Germany); Chambers, A.V.; Haworth, A.; Ilett, D.; Linklater, C.M.; Tweed, C.J. [AEA Technology plc, Harwell (United Kingdom); Chenery, S.R.N.; Kemp, S.J.; Milodowski, A.E.; Pearce, J.M.; Reeder, S.; Rochelle, C.A.; Smith, B.; Wetton, P.D.; Wragg, J. [British Geological Survey, Keyworth (United Kingdom); Clark, I.D. [Univ. of Ottawa (Canada). Dept. of Geology; Hodginson, E.; Hughes, C.R. [Univ. of Manchester (United Kingdom). Dept. of Earth Sciences; Hyslop, E.K. [British Geological Survey, Edinburgh (United Kingdom); Karlsson, F. [Swedish Nuclear Fuel and Waste Management Co., Stockholm (Sweden); Khoury, H.N.; Salameh, E. [Univ. of Jordan, Amman (Jordan); Lagerblad, B. [Cement Institute, Stockholm (Sweden); Longworth, G. [Univ. of Manchester (United Kingdom). Dept. of Geology; Pitty, A.F. [Private consultant, Norwich (United Kingdom); Savage, D. [QuantiSci Ltd, Melton Mowbray (United Kingdom); Smellie, J.A.T. [ed.] [Conterra AB, Uppsala (Sweden)

    1998-12-01

    This report represents the conclusion to Phase III of the Maqarin Natural Analogue Study. The main thrust was to establish the origin and chemistry of the Western Springs hyper alkaline groundwaters (Na/K enriched Ca(OH){sub 2} type) and to study their interaction with rocks of different compositions, as natural analogues to key processes that might occur at an early stage within the `alkali disturbed zone` of cementitious repositories in different host rocks. Whilst earlier studies at Maqarin were very much site-specific and process-oriented, Phase III provided a regional perspective to the geological evolution of the Maqarin region. This was made possible by greater field access which allowed a more systematic structural and geomorphological study of the area. This has resulted in a greater understanding of the age and spatial relationships concerning formation of the cement zones through spontaneous combustion of the Bituminous Marls, and the subsequent formation of high pH groundwaters at the Eastern and Western Springs locations. At the Western Springs locality, hydrochemical and hydrogeological evaluation of new and published data (plus access to unpublished data), together with detailed mineralogical and geochemical studies, helped to clarify the very earliest stage of cement leachate/host rock interaction. The data were used also to test coupled flow/transport codes developed to assess the long-term evolution of a cementitious repository. Additional objectives addressed include: a) rock matrix diffusion, b) the occurrence and chemical controls on zeolite composition, e) the occurrence and chemical controls on clay stability, and d) the role of microbes, organics and colloids in trace element transport. The Maqarin site now provides a consistent picture explaining the origin of the hyperalkaline groundwaters, and is therefore a unique location for the examination of the mechanisms and processes associated with cementitious repositories. Application of these

  10. MAQARIN natural analogue study: phase III

    Energy Technology Data Exchange (ETDEWEB)

    Alexander, W.R.; Mazurek, M.; Waber, H.N. [Univ. of Berne (Switzerland). Institutes of Geology, Mineralogy and Petrology, Rock-Water Interaction Group (GGWW); Arlinger, J.; Erlandson, A.C.; Hallbeck, L.; Pedersen, K. [Goeteborg Univ. (Sweden). Dept. of General and Marine Microbiology; Boehlmann, W.; Fritz, P.; Geyer, S.; Geyer, W.; Hanschman, G.; Kopinke, F.D.; Poerschmann, J. [Umweltforschungszentrum Leipzig-Halle (Germany); Chambers, A.V.; Haworth, A.; Ilett, D.; Linklater, C.M.; Tweed, C.J. [AEA Technology plc, Harwell (United Kingdom); Chenery, S.R.N.; Kemp, S.J.; Milodowski, A.E.; Pearce, J.M.; Reeder, S.; Rochelle, C.A.; Smith, B.; Wetton, P.D.; Wragg, J. [British Geological Survey, Keyworth (United Kingdom); Clark, I.D. [Univ. of Ottawa (Canada). Dept. of Geology; Hodginson, E.; Hughes, C.R. [Univ. of Manchester (United Kingdom). Dept. of Earth Sciences; Hyslop, E.K. [British Geological Survey, Edinburgh (United Kingdom); Karlsson, F. [Swedish Nuclear Fuel and Waste Management Co., Stockholm (Sweden); Khoury, H.N.; Salameh, E. [Univ. of Jordan, Amman (Jordan); Lagerblad, B. [Cement Inst., Stockholm (Sweden); Longworth, G. [Univ. of Manchester (United Kingdom). Dept. of Geology; Pitty, A.F. [Private consultant, Norwich (United Kingdom); Savage, D. [QuantiSci Ltd, Melton Mowbray (United Kingdom); Smellie, J.A.T. [ed.] [Conterra AB, Uppsala (Sweden)

    1998-12-01

    This report represents the conclusion to Phase III of the Maqarin Natural Analogue Study. The main thrust was to establish the origin and chemistry of the Western Springs hyper alkaline groundwaters (Na/K enriched Ca(OH){sub 2} type) and to study their interaction with rocks of different compositions, as natural analogues to key processes that might occur at an early stage within the `alkali disturbed zone` of cementitious repositories in different host rocks. Whilst earlier studies at Maqarin were very much site-specific and process-oriented, Phase III provided a regional perspective to the geological evolution of the Maqarin region. This was made possible by greater field access which allowed a more systematic structural and geomorphological study of the area. This has resulted in a greater understanding of the age and spatial relationships concerning formation of the cement zones through spontaneous combustion of the Bituminous Marls, and the subsequent formation of high pH groundwaters at the Eastern and Western Springs locations. At the Western Springs locality, hydrochemical and hydrogeological evaluation of new and published data (plus access to unpublished data), together with detailed mineralogical and geochemical studies, helped to clarify the very earliest stage of cement leachate/host rock interaction. The data were used also to test coupled flow/transport codes developed to assess the long-term evolution of a cementitious repository. Additional objectives addressed include: a) rock matrix diffusion, b) the occurrence and chemical controls on zeolite composition, e) the occurrence and chemical controls on clay stability, and d) the role of microbes, organics and colloids in trace element transport. The Maqarin site now provides a consistent picture explaining the origin of the hyperalkaline groundwaters, and is therefore a unique location for the examination of the mechanisms and processes associated with cementitious repositories. Application of these

  11. THE PENA BLANCA NATURAL ANALOGUE PERFORMANCE ASSESSMENT MODEL

    Energy Technology Data Exchange (ETDEWEB)

    G. Saulnier and W. Statham

    2006-04-16

    The Nopal I uranium mine in the Sierra Pena Blanca, Chihuahua, Mexico serves as a natural analogue to the Yucca Mountain repository. The Pena Blanca Natural Analogue Performance Assessment Model simulates the mobilization and transport of radionuclides that are released from the mine and transported to the saturated zone. The Pena Blanca Natural Analogue Performance Assessment Model uses probabilistic simulations of hydrogeologic processes that are analogous to the processes that occur at the Yucca Mountain site. The Nopal I uranium deposit lies in fractured, welded, and altered rhyolitic ash-flow tuffs that overlie carbonate rocks, a setting analogous to the geologic formations at the Yucca Mountain site. The Nopal I mine site has the following analogous characteristics as compared to the Yucca Mountain repository site: (1) Analogous source--UO{sub 2} uranium ore deposit = spent nuclear fuel in the repository; (2) Analogous geology--(i.e. fractured, welded, and altered rhyolitic ash-flow tuffs); (3) Analogous climate--Semiarid to arid; (4) Analogous setting--Volcanic tuffs overlie carbonate rocks; and (5) Analogous geochemistry--Oxidizing conditions Analogous hydrogeology: The ore deposit lies in the unsaturated zone above the water table.

  12. Natural analogue studies for the safety case development of radioactive waste disposal in Korea

    Energy Technology Data Exchange (ETDEWEB)

    Choi, Kyung-Woo [Korea Institute of Nuclear Safety, 305-338 Daejeon (Korea, Republic of); Baik, Min-Hoon [Korea Atomic Energy Research Institute, 305-353 Daejeon (Korea, Republic of)

    2014-07-01

    The natural analogue study is an analogy approach to investigate natural occurrences of materials, conditions and processes that are similar to those known or predicted to occur in some part of a radioactive waste disposal system. Countries considering the disposal of radioactive waste have been working on their domestic natural analogue studies for developing the safety case and improving the disposal safety. Natural analogue study can effectively be applied to the understanding of a long-term behavior of the post-closure repository, the provision of quantitative data required for the safety assessment models, and the supplementary safety indicator to prove the safety of deep geological disposal. Therefore the natural analogue studies play an important role in the safety case which requires a multiple lines of evidence including the safety assessment for the geological disposal of radioactive wastes. In this study, current status of foreign natural analogue studies was investigated by summarizing their results related with repository materials, radionuclide migration and retardation. Main results, issues, and their applicability of the foreign natural analogue studies were also analyzed. The results of natural analogue studies in Korea were categorized and summarized according to the studies on the uranium ore bodies, rocks, groundwater, and archeological artifacts. Although so many studies on the natural analogue have been carried out during last several decades in Korea, their results have not been actively applied to the safety assessment and safety case development for radioactive waste disposal. Therefore, applicable methods of natural analogues were summarized and a methodology for improving their applicability was examined. Additionally, in order to improve the application of these results from natural analogue studies, build-up of a natural analogue information database was in progress and its status will be presented. (authors)

  13. Natural analogue studies as supplements to biomineralization research

    Energy Technology Data Exchange (ETDEWEB)

    McNeil, M.B. [Nuclear Regulatory Commission, Washington, DC (United States)

    1995-09-01

    Chemical reactions can alter the chemistry and crystal structure of solid objects over archeological or geological times, while preserving external physical shapes. The reactions resulting in these structures offer natural analogues to laboratory experiments in biomineralization and to biologically influenced alteration of nuclear waste packages, and thus, they offer the only available way of validating models that purport waste package behavior over archaeological or geological times. Potential uses of such analogues in the construction and validation of hypothetical mechanisms of microbiological corrosion and biomineralization are reviewed. Evidence from such analogues suggests that biofilms can control materials alteration in ways usually overlooked. The newly hypothesized mechanisms involve control by biofilms of the cation flow near the solid surface and offer plausible mechanisms for the formation of mixed-cation minerals under conditions that would lead to dealloying in abiotic experiments; they also account for the formation of unusual minerals [such as posnjakite, Cu{sub 4}SO{sub 4}(OH){sub 6{center_dot}}H{sub 2}O] and mineral morphologies unusual in corrosion [malachite, Cu{sub 2}CO{sub 3}(OH){sub 2}, rarely forms botryoidally under corrosion conditions and its occasional presence on archaeological objects that appear to have undergone microbiological corrosion may be related to biofilm phenomena].

  14. THE PENA BLANCA NATURAL ANALOGUE PERFORMANCE ASSESSMENT MODEL

    Energy Technology Data Exchange (ETDEWEB)

    G.J. Saulnier Jr; W. Statham

    2006-03-10

    The Nopal I uranium mine in the Sierra Pena Blanca, Chihuahua, Mexico serves as a natural analogue to the Yucca Mountain repository. The Pena Blanca Natural Analogue Performance Assessment Model simulates the mobilization and transport of radionuclides that are released from the mine and transported to the saturated zone. the Pena Blanca Natural Analogue Model uses probabilistic simulations of hydrogeologic processes that are analogous to the processes that occur at the Yucca Mountain site. The Nopal I uranium deposit lies in fractured, welded, and altered rhyolitic ash flow tuffs that overlie carbonate rocks, a setting analogous to the geologic formations at the Yucca Mountain site. The Nopal I mine site has the following characteristics as compared to the Yucca Mountain repository site. (1) Analogous source: UO{sub 2} uranium ore deposit = spent nuclear fuel in the repository; (2) Analogous geologic setting: fractured, welded, and altered rhyolitic ash flow tuffs overlying carbonate rocks; (3) Analogous climate: Semiarid to arid; (4) Analogous geochemistry: Oxidizing conditions; and (5) Analogous hydrogeology: The ore deposit lies in the unsaturated zone above the water table. The Nopal I deposit is approximately 8 {+-} 0.5 million years old and has been exposed to oxidizing conditions during the last 3.2 to 3.4 million years. The Pena Blanca Natural Analogue Model considers that the uranium oxide and uranium silicates in the ore deposit were originally analogous to uranium-oxide spent nuclear fuel. The Pena Blanca site has been characterized using field and laboratory investigations of its fault and fracture distribution, mineralogy, fracture fillings, seepage into the mine adits, regional hydrology, and mineralization that shows the extent of radionuclide migration. Three boreholes were drilled at the Nopal I mine site in 2003 and these boreholes have provided samples for lithologic characterization, water-level measurements, and water samples for laboratory

  15. Long-term predictions using natural analogues

    Energy Technology Data Exchange (ETDEWEB)

    Ewing, R.C. [Univ. of New Mexico, Albuquerque, NM (United States)

    1995-09-01

    One of the unique and scientifically most challenging aspects of nuclear waste isolation is the extrapolation of short-term laboratory data (hours to years) to the long time periods (10{sup 3}-10{sup 5} years) required by regulatory agencies for performance assessment. The direct validation of these extrapolations is not possible, but methods must be developed to demonstrate compliance with government regulations and to satisfy the lay public that there is a demonstrable and reasonable basis for accepting the long-term extrapolations. Natural systems (e.g., {open_quotes}natural analogues{close_quotes}) provide perhaps the only means of partial {open_quotes}validation,{close_quotes} as well as data that may be used directly in the models that are used in the extrapolation. Natural systems provide data on very large spatial (nm to km) and temporal (10{sup 3}-10{sup 8} years) scales and in highly complex terranes in which unknown synergisms may affect radionuclide migration. This paper reviews the application (and most importantly, the limitations) of data from natural analogue systems to the {open_quotes}validation{close_quotes} of performance assessments.

  16. U.S. Nuclear Regulatory Commission natural analogue research program

    Energy Technology Data Exchange (ETDEWEB)

    Kovach, L.A.; Ott, W.R. [Nuclear Regulatory Commission, Washington, DC (United States)

    1995-09-01

    This article describes the natural analogue research program of the U.S. Nuclear Regulatory Commission (US NRC). It contains information on the regulatory context and organizational structure of the high-level radioactive waste research program plan. It also includes information on the conditions and processes constraining selection of natural analogues, describes initiatives of the US NRC, and describes the role of analogues in the licensing process.

  17. Rheology of pig skin gelatine: Defining the elastic domain and its thermal and mechanical properties for geological analogue experiment applications

    Science.gov (United States)

    van Otterloo, Jozua; Cruden, Alexander R.

    2016-06-01

    Gelatine is a viscoelastic polymer that has been employed widely in geological analogue experiments to study processes related to the elastic behaviour of rocks such as tensile fracturing, seismicity and magma intrusion. However, the elastic domain of this material has not yet been clearly defined by rheological tests. Here we describe the rheology and define the elastic domain of 250 bloom/20 mesh pigskin gelatine at concentrations ≤ 10 wt.% and temperatures of 5-25 °C; however, these results are strongly comparable with gelatine of 245-260 bloom. New equations are given for the shear and elastic moduli in relationship to temperature and gelatine concentration. It is found that at concentrations ≤ 3 wt.% the tested gelatine is best described by a rheological model composed of a combination of Kelvin-Voight and Maxwell elements and, therefore, is not suitable to model elastic behaviour in geological analogue experiments. At higher concentrations it is best described by a simpler viscoelastic model comprising a single Maxwell element. In order to ensure that geological analogue experiments remain within the elastic domain where the elastic component is far greater than the viscous component, strain rates should range between 0.1 and 10 s- 1 and temperature values should be 3 wt.% analogue experiments using gelatine approximate the elastic behaviour of natural rocks more closely than previously assumed.

  18. Naturally occurring crystalline phases: analogues for radioactive waste forms

    Energy Technology Data Exchange (ETDEWEB)

    Haaker, R.F.; Ewing, R.C.

    1981-01-01

    Naturally occurring mineral analogues to crystalline phases that are constituents of crystalline radioactive waste forms provide a basis for comparison by which the long-term stability of these phases may be estimated. The crystal structures and the crystal chemistry of the following natural analogues are presented: baddeleyite, hematite, nepheline; pollucite, scheelite;sodalite, spinel, apatite, monazite, uraninite, hollandite-priderite, perovskite, and zirconolite. For each phase in geochemistry, occurrence, alteration and radiation effects are described. A selected bibliography for each phase is included.

  19. Cytotoxicity of natural ginseng glycosides and semisynthetic analogues

    NARCIS (Netherlands)

    Atopkina, LN; Malinovskaya, GV; Elyakov, GB; Uvarova, NI; Woerdenbag, HJ; Koulman, A; Potier, P

    1999-01-01

    The cytotoxicity of natural glycosides from Ginseng, semisynthetic analogues and related triterpenes of the dammarane series, isolated from the leaves of the Far-East species of the genus Betula was studied in order to elucidate structure-activity relationships. Some of the compounds studied were ac

  20. Cytotoxicity of natural ginseng glycosides and semisynthetic analogues

    NARCIS (Netherlands)

    Atopkina, LN; Malinovskaya, GV; Elyakov, GB; Uvarova, NI; Woerdenbag, HJ; Koulman, A; Potier, P

    The cytotoxicity of natural glycosides from Ginseng, semisynthetic analogues and related triterpenes of the dammarane series, isolated from the leaves of the Far-East species of the genus Betula was studied in order to elucidate structure-activity relationships. Some of the compounds studied were

  1. Cytotoxicity of natural ginseng glycosides and semisynthetic analogues

    NARCIS (Netherlands)

    Atopkina, LN; Malinovskaya, GV; Elyakov, GB; Uvarova, NI; Woerdenbag, HJ; Koulman, A; Potier, P

    1999-01-01

    The cytotoxicity of natural glycosides from Ginseng, semisynthetic analogues and related triterpenes of the dammarane series, isolated from the leaves of the Far-East species of the genus Betula was studied in order to elucidate structure-activity relationships. Some of the compounds studied were ac

  2. Natural geochemical analogues of the near field of high-level nuclear waste repositories

    Energy Technology Data Exchange (ETDEWEB)

    Apps, J.A. [Lawrence Berkeley Lab., CA (United States)

    1995-09-01

    United States practice has been to design high-level nuclear waste (HLW) geological repositories with waste densities sufficiently high that repository temperatures surrounding the waste will exceed 100{degrees}C and could reach 250{degrees}C. Basalt and devitrified vitroclastic tuff are among the host rocks considered for waste emplacement. Near-field repository thermal behavior and chemical alteration in such rocks is expected to be similar to that observed in many geothermal systems. Therefore, the predictive modeling required for performance assessment studies of the near field could be validated and calibrated using geothermal systems as natural analogues. Examples are given which demonstrate the need for refinement of the thermodynamic databases used in geochemical modeling of near-field natural analogues and the extent to which present models can predict conditions in geothermal fields.

  3. Matrix diffusion model. In situ tests using natural analogues

    Energy Technology Data Exchange (ETDEWEB)

    Rasilainen, K. [VTT Energy, Espoo (Finland)

    1997-11-01

    Matrix diffusion is an important retarding and dispersing mechanism for substances carried by groundwater in fractured bedrock. Natural analogues provide, unlike laboratory or field experiments, a possibility to test the model of matrix diffusion in situ over long periods of time. This thesis documents quantitative model tests against in situ observations, done to support modelling of matrix diffusion in performance assessments of nuclear waste repositories. 98 refs. The thesis includes also eight previous publications by author.

  4. Are there pre-Quaternary geological analogues for a future greenhouse warming?

    Science.gov (United States)

    Haywood, A.M.; Ridgwell, A.; Lunt, D.J.; Hill, D.J.; Pound, M.J.; Dowsett, H.J.; Dolan, A.M.; Francis, J.E.; Williams, M.

    2011-01-01

    Given the inherent uncertainties in predicting how climate and environments will respond to anthropogenic emissions of greenhouse gases, it would be beneficial to society if science could identify geological analogues to the human race's current grand climate experiment. This has been a focus of the geological and palaeoclimate communities over the last 30 years, with many scientific papers claiming that intervals in Earth history can be used as an analogue for future climate change. Using a coupled ocean-atmosphere modelling approach, we test this assertion for the most probable pre-Quaternary candidates of the last 100 million years: the Mid- and Late Cretaceous, the Palaeocene-Eocene Thermal Maximum (PETM), the Early Eocene, as well as warm intervals within the Miocene and Pliocene epochs. These intervals fail as true direct analogues since they either represent equilibrium climate states to a long-term CO2 forcing-whereas anthropogenic emissions of greenhouse gases provide a progressive (transient) forcing on climate-or the sensitivity of the climate system itself to CO2 was different. While no close geological analogue exists, past warm intervals in Earth history provide a unique opportunity to investigate processes that operated during warm (high CO2) climate states. Palaeoclimate and environmental reconstruction/modelling are facilitating the assessment and calculation of the response of global temperatures to increasing CO2 concentrations in the longer term (multiple centuries); this is now referred to as the Earth System Sensitivity, which is critical in identifying CO2 thresholds in the atmosphere that must not be crossed to avoid dangerous levels of climate change in the long term. Palaeoclimatology also provides a unique and independent way to evaluate the qualities of climate and Earth system models used to predict future climate. ?? 2011 The Royal Society.

  5. Maqarin natural analogue project: Phase IV. Reconnaissance mission report (April 28 to May 7, 1999)

    Energy Technology Data Exchange (ETDEWEB)

    Smellie, J.A.T. [ed.] [Conterra AB, Uppsala (Sweden)

    2000-08-01

    Final planning of the Technical Proposal for Phase IV of the Maqarin Natural Analogue Project was preceded by a ten day Reconnaissance Mission to the Jordan sites. The main objective of this mission was to: i) allow new organisations within the project to become familiar with the geological context of the Maqarin and Central Jordan sites and also to appreciate the prevailing technical and logistical limitations, ii) carry out limited field investigations, and iii) based on the experience from these two points, provide the opportunity to finalise the Maqarin Phase IV Technical Proposal. This report details the results of the mission.

  6. Terrestrial analogs, planetary geology, and the nature of geological reasoning

    Science.gov (United States)

    Baker, Victor R.

    2014-05-01

    Analogical reasoning is critical to planetary geology, but its role can be misconstrued by those unfamiliar with the practice of that science. The methodological importance of analogy to geology lies in the formulation of genetic hypotheses, an absolutely essential component of geological reasoning that was either ignored or denigrated by most 20th century philosophers of science, who took the theoretical/ experimental methodology of physics to be the sole model for all of scientific inquiry. Following the seminal 19th century work of Grove Karl Gilbert, an early pioneer of planetary geology, it has long been recognized that broad experience with and understanding of terrestrial geological phenomena provide geologists with their most effective resource for the invention of potentially fruitful, working hypotheses. The actions of (1) forming such hypotheses, (2) following their consequences, and (3) testing those consequences comprise integral parts of effective geological practice in regard to the understanding of planetary surfaces. Nevertheless, the logical terminology and philosophical bases for such practice will be unfamiliar to most planetary scientists, both geologists and nongeologists. The invention of geological hypotheses involves both inductive inferences of the type Gilbert termed “empiric classification” and abductive inferences of a logical form made famous by the 19th century American logician Charles Sanders Peirce. The testing and corroboration of geological hypotheses relies less on the correspondence logic of theoretical/ experimental sciences, like physics, and more on the logic of consistency, coherence, and consilience that characterizes the investigative and historical sciences of interpretation exemplified by geology.

  7. Natural analogue synthesis report, TDR-NBS-GS-000027 rev00 icn02

    Energy Technology Data Exchange (ETDEWEB)

    Simmons, A.; Nieder-Westermann, G.; Stuckless, J.; Dobson, P.; Unger, A.J.A.; Kwicklis, E.; Lichtner, P.; Carey, B.; Wolde, G.; Murrel,M.; Kneafsey, T.J.; Meijer, A.; Faybishenko, B.

    2002-04-01

    The purpose of this report is to present analogue studies and literature reviews designed to provide qualitative and quantitative information to test and provide added confidence in process models abstracted for performance assessment (PA) and model predictions pertinent to PA. This report provides updates to studies presented in the Yucca Mountain Site Description (CRWMS M&O 2000 [151945], Section 13) and new examples gleaned from the literature, along with results of quantitative studies conducted specifically for the Yucca Mountain Site Characterization Project (YMP). The intent of the natural analogue studies was to collect corroborative evidence from analogues to demonstrate additional understanding of processes expected to occur during postclosure at a potential Yucca Mountain repository. The report focuses on key processes by providing observations and analyses of natural and anthropogenic (human-induced) systems to improve understanding and confidence in the operation of these processes under conditions similar to those that could occur in a nuclear waste repository. The process models include those that represent both engineered and natural barrier processes. A second purpose of this report is to document the various applications of natural analogues to geologic repository programs, focusing primarily on the way analogues have been used by the YMP. This report is limited to providing support for PA in a confirmatory manner and to providing corroborative inputs for process modeling activities. Section 1.7 discusses additional limitations of this report. Key topics for this report are analogues to emplacement drift degradation, waste form degradation, waste package degradation, degradation of other materials proposed for the engineered barrier, seepage into drifts, radionuclide flow and transport in the unsaturated zone (UZ), analogues to coupled thermal-hydrologic-mechanical-chemical processes, saturated zone (SZ) transport, impact of radionuclide release

  8. The pitchblende of Fe mine (Ciudad Rodrigo, Salamanca) as natural analogue of spent fuel behaviour (matrix I project); La pechblenda de la mina Fe (Ciudad Rodrigo, Salamanca), como analogo natural del comportamiento del combustible gastado (Proyecto Matrix I)

    Energy Technology Data Exchange (ETDEWEB)

    Perez del Villar, L.; Campos, R.; Gomez, P.; Cozar, J.S.; Pardillo, J.; Garralon, A.; Turrero, M.J.; Buil, B.; Pelayo, M.; Ruiz, B.; Rivas, P. [CIEMAT, Madrid (Spain)

    2001-07-01

    Uranium ore deposits have been extensively studied as natural analogues to the deep geological disposal of radioactive waste. These investigations constitute an essential element of both national and international research programmes applied to the assessment of geological repositories in crystalline, clayey and even in schistose rocks. The uranium ore deposit of Fe mine (Ciudad Rodrigo, Salmanca) is placed in highly fractured schistose rocks, a geological setting that has not been envisaged in ENRESA options. However, the similarities with some of the repository features and the analogies with the processes involved in the degradation of the ore deposits made advisable its study as natural analogue. The most important features are. (Author)

  9. Pena Blanca Natural Analogue Project: Summary of activities

    Energy Technology Data Exchange (ETDEWEB)

    Levy, S.; Goldstein, S.; Dobson, P.F.; Goodell, P.; Ku, T.-L.; Abdel-Fattah, A.; Saulnier, G.; Fayek, M.; de la Garza, R.

    2011-02-01

    The inactive Nopal I uranium mine in silicic tuff north of Chihuahua City, Chihuahua, Mexico, was studied as a natural analogue for an underground nuclear-waste repository in the unsaturated zone. Site stratigraphy was confirmed from new drill cores. Data from site studies include chemical and isotopic compositions of saturated- and unsaturated-zone waters. A partial geochronology of uranium enrichment and mineralization was established. Evidence pertinent to uranium-series transport in the soil zone and changing redox conditions was collected. The investigations contributed to preliminary, scoping-level performance assessment modeling.

  10. Pena blanca natural analogue project: summary of activities

    Energy Technology Data Exchange (ETDEWEB)

    Levy, Schon S [Los Alamos National Laboratory; Goldstein, Steven J [Los Alamos National Laboratory; Abdel - Fattah, Amr I [Los Alamos National Laboratory

    2010-12-08

    The inactive Nopal I uranium mine in silicic tuff north of Chihuahua City, Chihuahua, Mexico, was studied as a natural analogue for an underground nuclear-waste repository in the unsaturated zone. Site stratigraphy was confirmed from new drill core. Datafrom site studies include chemical and isotopic compositions of saturated- and unsaturated-zone waters. A partial geochronology of uranium enrichment and mineralization was established. Evidence pertinent to uranium-series transport in the soil zone and changing redox conditions was collected. The investigations contributed to preliminary, scoping-level performance assessment modeling.

  11. Natural analogues for expansion due to the anaerobic corrosion of ferrous materials

    Energy Technology Data Exchange (ETDEWEB)

    Smart, N.R.; Adams, R. [Serco Assurance, Culham Science Centre (United Kingdom)

    2006-10-15

    In Sweden, spent nuclear fuel will be encapsulated in sealed cylindrical canisters, consisting of a cast iron insert and a copper outer container. The canisters will be placed in a deep geologic repository and surrounded by bentonite. If a breach of the outer copper container were to occur the cast iron insert would undergo anaerobic corrosion, forming a magnetite film whose volume would be greater than that of the base metal. In principle there is a possibility that accumulation of iron corrosion product could cause expansion of the copper canister. Anaerobic corrosion rates are very slow, so in the work described in this report reference was made to analogous materials that had been corroding for long periods in natural anoxic aqueous environments. The report considers the types of naturally occurring environments that may give rise to anoxic environments similar to deep geological groundwater and where ferrous materials may be found. Literature information regarding the corrosion of iron archaeological artefacts is summarised and a number of specific archaeological artefacts containing iron and copper corroding in constrained geometries in anoxic natural waters are discussed in detail. No evidence was obtained from natural analogues which would suggest that severe damage is likely to occur to the SKB waste canister design as a result of expansive corrosion of cast iron under repository conditions.

  12. Natural analogue study of CO2 storage monitoring using probability statistics of CO2-rich groundwater chemistry

    Science.gov (United States)

    Kim, K. K.; Hamm, S. Y.; Kim, S. O.; Yun, S. T.

    2016-12-01

    For confronting global climate change, carbon capture and storage (CCS) is one of several very useful strategies as using capture of greenhouse gases like CO2 spewed from stacks and then isolation of the gases in underground geologic storage. CO2-rich groundwater could be produced by CO2 dissolution into fresh groundwater around a CO2 storage site. As consequence, natural analogue studies related to geologic storage provide insights into future geologic CO2 storage sites as well as can provide crucial information on the safety and security of geologic sequestration, the long-term impact of CO2 storage on the environment, and field operation and monitoring that could be implemented for geologic sequestration. In this study, we developed CO2 leakage monitoring method using probability density function (PDF) by characterizing naturally occurring CO2-rich groundwater. For the study, we used existing data of CO2-rich groundwaters in different geological regions (Gangwondo, Gyeongsangdo, and Choongchungdo provinces) in South Korea. Using PDF method and QI (quantitative index), we executed qualitative and quantitative comparisons among local areas and chemical constituents. Geochemical properties of groundwater with/without CO2 as the PDF forms proved that pH, EC, TDS, HCO3-, Ca2+, Mg2+, and SiO2 were effective monitoring parameters for carbonated groundwater in the case of CO2leakage from an underground storage site. KEY WORDS: CO2-rich groundwater, CO2 storage site, monitoring parameter, natural analogue, probability density function (PDF), QI_quantitative index Acknowledgement This study was supported by the "Basic Science Research Program through the National Research Foundation of Korea (NRF), which is funded by the Ministry of Education (NRF-2013R1A1A2058186)" and the "R&D Project on Environmental Management of Geologic CO2 Storage" from KEITI (Project number: 2014001810003).

  13. FINAL REPORT OF THE PEÑA BLANCA NATURAL ANALOGUE PROJECT

    Energy Technology Data Exchange (ETDEWEB)

    Goldstein, Steven Joel [Los Alamos National Laboratory; Levy, Schon S. [Los Alamos National Laboratory (retired); Abdel-Fattah, Amr I. [Los Alamos National Laboratory (formerly); Amato, Ronald S. [Los Alamos National Laboratory; Anthony, Elizabeth [University of Texas at El Paso, Chemisty Division; Cook, Paul [Lawrence Berkeley National Laboratory, Earth Sciences Division; Dobson, Patrick F. [Lawrence Berkeley National Laboratory, Earth Sciences Division; Fayek, Mostafa [University of Manitoba, Department of Geological Sciences; French, Diana [University of Texas at El Paso, Department of Geology; Garza, Rodrigo de [Universidad Autónoma de Chihuahua, Facultad de Ingeniería; Ghezzehei, Teamrat [Lawrence Berkeley National Laboratory, Earth Sciences Division; Goodell, Philip C. [University of Texas at El Paso, Department of Geology; Harder, Steven H. [University of Texas at El Paso, Department of Geology; Ku, Teh-Lung [University of Southern California, Department of Earth Sciences; Luo, Shangde [University of Southern California, Department of Earth Sciences; Murrell, Michael Tildon [Los Alamos National Laboratory; Norman, Deborah E. [Los Alamos National Laboratory; Nunn, Andrew J. [Los Alamos National Laboratory; Oliver, Ronald [Los Alamos National Laboratory (formerly); Pekar-Carpenter, Katrina [University of Texas at El Paso, Department of Geology; Rearick, Michael Sean [Los Alamos National Laboratory; Ren, Minghua [University of Texas at El Paso, Department of Geology; Reyes-Cortes, Ignacio [Universidad Autónoma de Chihuahua, Facultad de Ingeniería; Pineda, Jose Alfredo [El Instituto de Ecología (INECOL), México; Saulnier, George [AREVA Federal Services LLC; Tarimala, Sowmitri [Los Alamos National Laboratory (formerly); Walton, John [University of Texas at El Paso, Department of Geology

    2016-10-04

    The Peña Blanca region, 50 km north of Chihuahua City, Chihuahua, México, was a target of uranium exploration and mining by the Mexican government. After mining ceased in 1981, researchers became interested in this region as a study area for subsurface uranium migration with relevance to geologic disposal of nuclear waste. Many studies related to this concept were conducted at the Nopal I mine site located on a cuesta (hill) of the Sierra Peña Blanca. This site has geologic, tectonic, hydrologic, and geochemical similarities to Yucca Mountain, Nevada, a formerly proposed site for a high-level nuclear-waste repository in the unsaturated zone. The U.S. Department of Energy (U.S. DOE), Office of Civilian Radioactive Waste Management (OCRWM), sponsored studies at Nopal I in the 1990s and supported the drilling of three research wells – PB1, PB2, and PB3 – at the site in 2003. Beginning in 2004, the Peña Blanca Natural Analogue Project was undertaken by U.S. DOE, OCRWM to develop a three-dimensional conceptual model of the transport of uranium and its radiogenic daughter products at the Nopal I site.

  14. Final report of the Peña Blanca natural analogue project

    Energy Technology Data Exchange (ETDEWEB)

    Levy, Schön S. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Goldstein, Steven Joel [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Abdel-Fattah, Amr I. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Amato, Ronald S. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Anthony, Elizabeth [Univ. of Texas, El Paso, TX (United States); Cook, Paul [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Dobson, Patrick F. [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Fayek, Mostafa [Univ. of Manitoba, Winnipeg (Canada); French, Diana [Univ. of Texas, El Paso, TX (United States); Garza, Rodrigo de [Univ. Autonoma de Chihuahua (Mexico); Ghezzehei, Teamrat [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Goodell, Philip C. [Univ. of Texas, El Paso, TX (United States); Harder, Steven H. [Univ. of Texas, El Paso, TX (United States); Ku, Teh-Lung [Univ. of Southern California, Los Angeles, CA (United States); Luo, Shangde [Univ. of Southern California, Los Angeles, CA (United States); Murrell, Michael Tildon [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Norman, Deborah E. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Nunn, Andrew J. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Oliver, Ronald [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Pekar-Carpenter, Katrina [Univ. of Texas, El Paso, TX (United States); Rearick, Michael Sean [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Ren, Minghua [Univ. of Texas, El Paso, TX (United States); Reyes-Cortes, Ignacio [Univ. Autonoma de Chihuahua (Mexico); Pineda, Jose Alfredo [El Instituto de Ecologia (INECOL) (Mexico); Saulnier, George [AREVA Federal Services LLC, Charlotte, NC (United States); Tarimala, Sowmitri [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Walton, John [Univ. of Texas, El Paso, TX (United States)

    2016-10-04

    The Peña Blanca region, 50 km north of Chihuahua City, Chihuahua, México, was a target of uranium exploration and mining by the Mexican government. After mining ceased in 1981, researchers became interested in this region as a study area for subsurface uranium migration with relevance to geologic disposal of nuclear waste. Many studies related to this concept were conducted at the Nopal I mine site located on a cuesta (hill) of the Sierra Peña Blanca. This site has geologic, tectonic, hydrologic, and geochemical similarities to Yucca Mountain, Nevada, a formerly proposed site for a high-level nuclear-waste repository in the unsaturated zone. The U.S. Department of Energy (U.S. DOE), Office of Civilian Radioactive Waste Management (OCRWM), sponsored studies at Nopal I in the 1990s and supported the drilling of three research wells – PB1, PB2, and PB3 – at the site in 2003. Beginning in 2004, the Peña Blanca Natural Analogue Project was undertaken by U.S. DOE, OCRWM to develop a three-dimensional conceptual model of the transport of uranium and its radiogenic daughter products at the Nopal I site.

  15. The paint pots, Kootenay National Park, Canada--a natural acid spring analogue for Mars

    National Research Council Canada - National Science Library

    Grasby, Stephen E; Richards, Barry C; Sharp, Christine E; Brady, Allyson L; Jones, Gareth M; Dunfield, Peter F

    2013-01-01

    The Paint Pots are a natural Fe-SO4 acid spring system along the Kicking Horse Rim, a major geological feature that has controlled fluid flow and mineralization over geologic time. The very low pH (~3...

  16. Siberian Platform: Geology and Natural Bitumen Resources

    Science.gov (United States)

    Meyer, Richard F.; Freeman, P.A.

    2006-01-01

    Summary: The Siberian platform is located between the Yenisey River on the west and the Lena River on the south and east. The Siberian platform is vast in size and inhospitable in its climate. This report is concerned principally with the setting, formation, and potential volumes of natural bitumen. In this report the volumes of maltha and asphalt referred to in the Russian literature are combined to represent natural bitumen. The generation of hydrocarbons and formation of hydrocarbon accumulations are discussed. The sedimentary basins of the Platform are described in terms of the Klemme basin classification system and the conditions controlling formation of natural bitumen. Estimates of in-place bitumen resources are reviewed and evaluated. If the bitumen volume estimate is confined to parts of identified deposits where field observations have verified rock and bitumen grades values, the bitumen resource amounts to about 62 billion barrels of oil in-place. However, estimates of an order of magnitude larger can be obtained if additional speculative and unverified rock volumes and grade measures are included.

  17. Simultaneous development of semigrabens orthogonal and oblique to the extension direction: physical modeling of natural analogues in Northeastern Brazil

    Directory of Open Access Journals (Sweden)

    André João Palma Conde Blanco

    2014-03-01

    Full Text Available The physical modeling tool is being increasingly used in geology to provide information about the evolutionary stages (nucleation, growth and geometry of geological structures at various scales. In the simulations of extensional tectonics, modeling provides a better understanding of fault geometry and evolution of the tectonic-stratigraphic architecture of rift basins. In this study a sandbox type apparatus was used to study the nucleation and development of basins influenced by previous structures in the basement, variably oriented as regards to the main extensional axis. Two types of experiments were conducted in order to: (i simulate the individual (independent development of half-grabens oriented orthogonal or oblique to the extension direction; (ii simulate the simultaneous development of such half-grabens, orthogonal or oblique to the extension direction. In both cases the same materials (sand mixed with gypsum were used and the same boundary conditions were maintained. The results were compared with a natural analogue represented by the Rio do Peixe Basin (one of the eocretaceous interior basins of Northeast Brazil. The obtained models allowed to observe the development of segmented border faults with listric geometry, often forming relay ramps, and the development of inner basins faults that affect only the basal strata, like the ones observed in the seismic sections of the natural analogue. The results confirm the importance of basement tectonic heritage in the geometry of rift depocenters.

  18. New synthetic strategies towards psammaplin A, access to natural product analogues for biological evaluation.

    Science.gov (United States)

    Baud, Matthias G J; Leiser, Thomas; Meyer-Almes, Franz-Josef; Fuchter, Matthew J

    2011-02-07

    New synthetic routes towards the natural product psammaplin A were developed with the particular view to preparing diverse analogues for biological assessment. These routes utilize cheap and commercially available starting materials, and allowed access to psammaplin A analogues not accessible via currently reported methods. Preliminary biological studies revealed these compounds to be the most potent non peptidic inhibitors of the enzyme histone deacetylase 1 (HDAC1, class I) discovered so far. Interestingly, psammaplin A and our synthetic analogues show class I selectivity in vitro, an important feature for the design and synthesis of future isoform selective inhibitors.

  19. Basic investigation and analysis for preferred host rocks and natural analogue study area with reference to high level radioactive waste disposal

    Energy Technology Data Exchange (ETDEWEB)

    Seo, Jeong Ryul; Park, J. K.; Hwang, D. H.; Lee, J. H.; Yun, H. S.; Kim, D. Y.; Park, H. S.; Koo, S. B.; Cho, J. D.; Kim, K. E. [Korea Inst. of Geology, Mining and Materials, Taejon (Korea, Republic of)

    1997-12-01

    The purpose of this study is basic investigation and analysis for preferred host rocks and natural analogue study area to develope underground disposal technique of high level radioactive waste in future. The study has been done for the crystalline rocks(especially granitic rocks) with emphasis of abandoned metallic mines and uranium ore deposits, and for the geological structure study by using gravity and aeromagnetic data. 138 refs., 54 tabs., 130 figs. (author)

  20. Synthesis and biological evaluation of new salvinorin A analogues incorporating natural amino acids.

    Science.gov (United States)

    Fichna, Jakub; Lewellyn, Kevin; Yan, Feng; Roth, Bryan L; Zjawiony, Jordan K

    2011-01-01

    The synthesis and in vitro evaluation of a new series of salvinorin A analogues substituted at the C(2) position with natural amino acids is reported. Compound 12, containing Val, displayed high affinity and full agonist activity at the kappa-opioid receptor. Analogues with bulky and/or aromatic residues were inactive, showing the importance of size and electronegativity of C(2)-substituents for binding affinity of salvinorin A derivatives.

  1. Matsushiro Earthquake Swarm (1965-1967) as a Natural Analogue of CO2 Storage and Leakage

    Science.gov (United States)

    Yamamoto, K.; Koide, H.; Tosha, T.; Todaka, N.; Nakanishi, S.; Aoyagi, R.; Benson, S.; Rutqvist, J.; Lewicki, J.

    2006-12-01

    production test and coring are being conducted using shallow borehole to better understand how surface geology and hydrogeology affect the CO2 migration. The result of this study will be used to better understand CO2 migration in fault systems, combined with knowledge from other natural analogues.

  2. Urban Patterns, Climate Change, Natural Hazards and Geology

    Science.gov (United States)

    Williams, D. E.

    2011-12-01

    Stresses to the natural and human built systems due to global warming and natural hazards are considerable and call for strategic, large-scale planning and design interventions. These interventions are determined by a melding of earth science knowledge with the communities that will be impacted. This session will illustrate how the design and planning professions are integrating the natural sciences in an attempt to create resilient patterns that adapt to climate change impacts on existing regional and urban patterns and improve functional sustainability. The session will be interactive and based upon the work of the speaker. Design and planning principles will be reviewed from the regional and community perspective. Attendees are encouraged to discuss geological elements of climate change, sea level rising and coastal cities and all variant conditions of coastal geological subsidence and the changing geophysical structure and the impacts from flooding and drought.

  3. Sansanmycin natural product analogues as potent and selective anti-mycobacterials that inhibit lipid I biosynthesis

    Science.gov (United States)

    Tran, Anh T.; Watson, Emma E.; Pujari, Venugopal; Conroy, Trent; Dowman, Luke J.; Giltrap, Andrew M.; Pang, Angel; Wong, Weng Ruh; Linington, Roger G.; Mahapatra, Sebabrata; Saunders, Jessica; Charman, Susan A.; West, Nicholas P.; Bugg, Timothy D. H.; Tod, Julie; Dowson, Christopher G.; Roper, David I.; Crick, Dean C.; Britton, Warwick J.; Payne, Richard J.

    2017-03-01

    Tuberculosis (TB) is responsible for enormous global morbidity and mortality, and current treatment regimens rely on the use of drugs that have been in use for more than 40 years. Owing to widespread resistance to these therapies, new drugs are desperately needed to control the TB disease burden. Herein, we describe the rapid synthesis of analogues of the sansanmycin uridylpeptide natural products that represent promising new TB drug leads. The compounds exhibit potent and selective inhibition of Mycobacterium tuberculosis, the etiological agent of TB, both in vitro and intracellularly. The natural product analogues are nanomolar inhibitors of Mtb phospho-MurNAc-pentapeptide translocase, the enzyme responsible for the synthesis of lipid I in mycobacteria. This work lays the foundation for the development of uridylpeptide natural product analogues as new TB drug candidates that operate through the inhibition of peptidoglycan biosynthesis.

  4. Archaeologic analogues: Microstructural changes by natural ageing in carbon steels

    Energy Technology Data Exchange (ETDEWEB)

    Munoz, Esther Bravo [Dpto. de Ciencia de los Materiales e Ingenieria Metalurgica, Facultad de Ciencias Quimicas, Universidad Complutense de Madrid, E-28040 Madrid (Spain); Fernandez, Jorge Chamon [Dpto. de Ciencia de los Materiales e Ingenieria Metalurgica, Facultad de Ciencias Quimicas, Universidad Complutense de Madrid, E-28040 Madrid (Spain); Arasanz, Javier Guzman [Dpto. de Ciencia de los Materiales e Ingenieria Metalurgica, Facultad de Ciencias Quimicas, Universidad Complutense de Madrid, E-28040 Madrid (Spain); Peces, Raquel Arevalo [Dpto. de Ciencia de los Materiales e Ingenieria Metalurgica, Facultad de Ciencias Quimicas, Universidad Complutense de Madrid, E-28040 Madrid (Spain); Criado, Antonio Javier [Dpto. de Ciencia de los Materiales e Ingenieria Metalurgica, Facultad de Ciencias Quimicas, Universidad Complutense de Madrid, E-28040 Madrid (Spain); Dietz, Christian [Dpto. de Ciencia de los Materiales e Ingenieria Metalurgica, Facultad de Ciencias Quimicas, Universidad Complutense de Madrid, E-28040 Madrid (Spain); Martinez, Juan Antonio [Dpto. de Ciencia de los Materiales e Ingenieria Metalurgica, Facultad de Ciencias Quimicas, Universidad Complutense de Madrid, E-28040 Madrid (Spain); Criado Portal, Antonio Jose [Dpto. de Ciencia de los Materiales e Ingenieria Metalurgica, Facultad de Ciencias Quimicas, Universidad Complutense de Madrid, E-28040 Madrid (Spain)]. E-mail: antoniocriado@quim.ucm.es

    2006-02-15

    When discussing the container material for highly active radionuclear waste, carbon steel is one of the materials most frequently proposed by the international scientific community. Evidently, security with respect to the container behaviour into deep geological deposits is fundamental. Among other parameters, knowledge about material mechanical properties is essential when designing the container. Time ageing of carbon steel, apart from possible alterations of the chemical composition (e.g. corrosion) involves important microstructural changes, at the scale of centuries and millenniums. The latter may cause variations of the mechanical properties of carbon steel storage containers, with the corresponding risk of possible leakage. In order to properly estimate such risk and to adjust the corresponding mathematical models to reality, the microstructural changes observed in this study on archaeologic samples are evaluated, comparing ancient and modern steels of similar chemical composition and fabrication processes.

  5. Synthesis of furanone-based natural product analogues with quorum sensing antagonist activity

    DEFF Research Database (Denmark)

    Hjelmgaard, Thomas; Persson, T.; Rasmussen, Thomas Bovbjerg;

    2003-01-01

    The synthesis of 5- and 3-(1'-hydroxyalkyl)-substituted 5H-furan-2-ones 4a-d and 8a-d as well as 5-alkylidene-5H-furan-2-ones 5a-d is described. A study of the structure-activity relationship of these furanone-based natural product analogues towards two different quorum sensing systems is reported....... Although the synthesized compounds are not as potent quorum sensing inhibitors as some natural counterparts and a synthetic analogue hereof, interesting structure-activity relationships are seen....

  6. Minerals as natural analogues for crystalline nuclear waste forms

    Energy Technology Data Exchange (ETDEWEB)

    Giere, R. [Purdue University West Lafayette, Earth and Atmospheric Sciences (United States)

    2000-07-01

    Between the mining of uranium ore (mostly as uraninite) and the final disposal of nuclear waste, there are many processes and steps which together comprise the nuclear fuel cycle. Radioactive waste will be generated as long as nuclear reactors are in operation, but it is also produced by other means, e.g., during certain medical, scientific and industrial procedures. The most dangerous wastes are those resulting from the reprocessing of spent nuclear fuel and from some processes in the production and dismantling of nuclear weapons. A large part of this highly radioactive waste is present as a liquid and thus, its safe isolation from the biosphere requires immobilization of the radionuclides in a durable matrix (waste form). This is a solid which must be resistant to heat, radiation and corrosion over a geologic time scale. Three main categories of waste forms have been developed for the immobilization of radioactive waste, namely glasses, crystalline and multibarrier waste forms. One of the key properties of a nuclear waste form is its chemical durability (or resistance to corrosion), because the waste form represents the primary barrier to radionuclide release. The sciences of mineralogy and petrology have both contributed significantly to the development, characterization and performance assessment of such waste forms. The most important goal of safe nuclear waste disposal is to ensure that practically no radioactive materials reach the biosphere and, ultimately, human beings. Therefore, the design of final repositories is based on an approach that places several obstacles, or barriers, between waste and biosphere, whereby each barrier has a specific role in preventing or delaying migration of radioactive material. This multibarrier concept is different for each type of waste but, for the option of geological disposal, it generally comprises the following five barriers: (1) waste form (contains the actual waste); (2) canister (surrounds waste form; composed of a

  7. Naturally occurring glasses: analogues for radioactive waste forms

    Energy Technology Data Exchange (ETDEWEB)

    Ewing, R.C.; Haaker, R.F.

    1979-04-01

    Volcanic glasses are very often altered by weathering and leaching and recrystallize to their fine-grained equivalents (rhyolites, felsites). The oldest volcanic glasses are dated at 40 million years before the present, but the majority are much younger. Devitrification textures was produced experimentally; and hydration rates for volcanic glasses were determined as a function of composition, temperature, and climate. Presence of water and temperature are the most important rate controlling variables. Even material that may still be described as glassy often exhibits evidence of alteration and recrystallization. Of the volcanic glasses that are preserved in the geologic record, it would be rare to describe such a glass as pristine. Despite the common alteration and recrystallization effects observed in volcanic glasses, glasses formed as a result of impact, tektites and lunar glasses, may occur in substantially unaltered form. In the case of tektites, their resistance to alteration is a result of their high SiO/sub 2/ content and low alkali content. Lunar glasses have been preserved for hundreds of millions of years because they exist in an environment with a low oxygen fugacity and an extremely low water vapor partial presssure. Thus one might expect glasses of particular compositions or in specific types of environment to be stable for long periods of time. These conclusions are applied to radioactive waste disposal over several time periods (0-30h, 30h-20y, 20-200y).

  8. Naturally occurring glasses: analogues for radioactive waste forms

    Energy Technology Data Exchange (ETDEWEB)

    Ewing, R.C.; Haaker, R.F.

    1979-04-01

    Volcanic glasses are very often altered by weathering and leaching and recrystallize to their fine-grained equivalents (rhyolites, felsites). The oldest volcanic glasses are dated at 40 million years before the present, but the majority are much younger. Devitrification textures was produced experimentally; and hydration rates for volcanic glasses were determined as a function of composition, temperature, and climate. Presence of water and temperature are the most important rate controlling variables. Even material that may still be described as glassy often exhibits evidence of alteration and recrystallization. Of the volcanic glasses that are preserved in the geologic record, it would be rare to describe such a glass as pristine. Despite the common alteration and recrystallization effects observed in volcanic glasses, glasses formed as a result of impact, tektites and lunar glasses, may occur in substantially unaltered form. In the case of tektites, their resistance to alteration is a result of their high SiO/sub 2/ content and low alkali content. Lunar glasses have been preserved for hundreds of millions of years because they exist in an environment with a low oxygen fugacity and an extremely low water vapor partial presssure. Thus one might expect glasses of particular compositions or in specific types of environment to be stable for long periods of time. These conclusions are applied to radioactive waste disposal over several time periods (0-30h, 30h-20y, 20-200y).

  9. Natural Capital - putting a value on geological sites

    Science.gov (United States)

    Dunlop, Lesley

    2017-04-01

    Natural Capital is a mechanism through which a value can be placed on nature allowing it to be considered alongside other assets. When the Government of the United Kingdom produced a Natural Environment White Paper (The Natural Choice: securing the value of nature) in 2012 there was no direct mention of geosites, geoheritage or geodiversity. One ambition of the Natural Environment White Paper was to stop environmental degradation and to rebuild natural capital and to value it. Whilst landscapes are mentioned in the paper geodiversity is not directly and this has been problematic for funding and recognition within the UK. Natural Capital is being used as the basis for many of the environmental reviews therefore it is essential that geodiversity can be included within this. The Natural Capital Committee defines natural capital as 'those elements of the natural environment which provide valuable goods and services to people'. In the main, these goods and services are related to ecology/biodiversity rather than to the full range of natural capital. Specifically, the values associated with abiotic nature (geodiversity) are frequently undervalued or ignored. The English Geodiversity Forum have been producing case studies as to how this might be done for different locations and this paper will present the work of this and how a value can be attributed to geodiversity. For example links to tourism and recreation within areas such as the Jurassic Coast World Heritage Site and the Black Country proposed Geopark are easy to place a value on but it is more difficult with educational, scientific sites. Using an ecosystems services and biodiversity analogies this paper presents a framework that can be adopted for evaluation of geological sites. Defra (2015) The state of natural capital: protecting and improving natural capital for prosperity and wellbeing. Department for Environment, Food & Rural Affairs, 73 pages https://www

  10. Reactive surface area in geochemical models - Lessons learned from a natural analogue

    NARCIS (Netherlands)

    Koenen, M.; Wasch, L.J.

    2013-01-01

    Many uncertainties exist in geochemical modeling. Mineral reactive surface area is one of the uncertain parameters. QEMSCAN analyses are performed on sandstone samples from a Dutch CO2 natural analogue to determine reactive surface areas. Geochemical modeling is performed using QEMSCAN surface areas

  11. Na-smectite s in the Cala de Tomate bentonite deposit (Spain): a natural analogue of the salinity effect on the bentonite barrier of a rad waste disposal

    Energy Technology Data Exchange (ETDEWEB)

    Perez del Villar, L.; Pelayo, M.; Fernandez, A.M.; Cozar, J.S. [CIEMAT - Centro de Investigaciones Energeticas, Medioambientales y Tecnologicas (CIEMAT/DIRE/CEAGP), Madrid (Spain); Delgado, A.; Reyes, E. [Ciencias de la Tierra y Quimica Ambiental Estacion Experimental del Zaidin Dpt., Granada (Spain); Fernandez-Soler, J.M. [Granada Univ., Dpt. de Mineralogia y Petrologia (Spain); Tsige, M. [Facultad de Ciencias Geologicas, Dpt. de Geodinamica, Madrid (Spain)

    2005-07-01

    Within the framework of the ENRESA programme for the assessment of the long-term behaviour of the bentonite-engineered barrier for a deep radwaste geological repository, analogue studies on several bentonite deposits are conducted at CIEMAT. Among these analogue studies, the thermal effect induced by volcanic intrusions on bentonite deposits is highlighted. In the Cabo de Gata volcanic region, there are several analogue scenarios where these studies have been performed, such as the Cala de Tomate bentonite deposit that was intruded by a pyroxene andesite volcanic dome. However, geological, mineralogical, physicochemical, geochemical and stable isotopic data obtained from the smectites do not allow to establish any analogy with the thermal effect expected on the bentonite-engineered barrier of a deep geological repository after burial. Thus, the bentonitisation processes took place after the intrusion of the dome, as a result of meteoric diagenesis intensively developed on faulting zone affecting the parent pyroclastic acid tuffs. This faulting process occurred after the dome intrusion. However, the physicochemical characteristics of these smectites, specially the exchangeable cations, allow to consider this bentonite deposit as a natural analogue of the saline effect on the clayey barrier. This analogy has been established because Na-smectites are present in this deposit and, up to our present knowledge, it is the first time that these smectites occur naturally in the Cabo de Gata-La Serrata de Nijar volcanic region. As a consequence, the main objectives of this work are: i) to characterise these smectites; ii) to establish their genesis and processes affecting them after their formation and iii) to identify the effects on the bentonite-engineered barrier should it were affected by a Na-rich saline waterfront. (authors)

  12. Cyprus natural analogue project (CNAP). Phase III final report

    Energy Technology Data Exchange (ETDEWEB)

    Alexander, W.R. [Bedrock Geosciences, Auenstein (Switzerland); Milodowski, A.E. [British Geological Survey, Keyworth (United Kingdom); Pitty, A.F. [Pitty (EIA) Consulting, Norwich (United Kingdom)] (eds.)

    2012-01-15

    The CNAP Phase III project was carried out following identification of the requirement to support ongoing laboratory and modelling efforts on the potential reaction of the bentonite buffer with cementitious leachates in the repository EBS. Although it is known that the higher pH (12.5 to 13) leachates from OPC cement will degrade bentonite, it is unclear if this will also be the case for the lower pH (10 to 11) leachates typical of low alkali cements. Ongoing laboratory and URL programmes which are currently investigating this face the obstacle of slow kinetics and the production of short-lived metastable phases, meaning obtaining unambiguous results may take decades. This is exacerbated by the limitations of the thermodynamic databases for minerals of interest to models of bentonite/low alkali cement leachate reaction. It was therefore decided to implement a focussed NA study on bentonite/low alkali cement leachate reaction to provide indications of likely long-term reaction products and reaction pathways to provide feedback on the existing short-term investigations noted above and to ascertain if any critical path R and D needs to be instigated now. The results of the analyses presented here suggest that there has been very limited alkaline groundwater reaction with the bentonite. This is generally supported by both the geomorphological evidence and the natural decay series data which imply groundwater groundwater/rock interaction in the last 10{sup 5} a. When integrated with the novel data currently being produced in the BIGRAD project, the CNAP data tend to indicate that any long-term bentonite reaction in low alkali cement leachates is minimal. (orig.)

  13. Geological exploration of Angola from Sumbe to Namibe: A review at the frontier between geology, natural resources and the history of geology

    Science.gov (United States)

    Masse, Pierre; Laurent, Olivier

    2016-01-01

    This paper provides a review of the Geological exploration of the Angola Coast (from Sumbe to Namibe) from pioneer's first geological descriptions and mining inventory to the most recent publications supported by the oil industry. We focus our attention on the following periods: 1875-1890 (Paul Choffat's work, mainly), 1910-1949 (first maps at country scale), 1949-1974 (detailed mapping of the Kwanza-Namibe coastal series), 1975-2000, with the editing of the last version of the Angola geological map at 1:1 million scale and the progressive completion of previous works. Since 2000, there is a renewal in geological fieldwork publications on the area mainly due to the work of university teams. This review paper thus stands at the frontier between geology, natural resources and the history of geology. It shows how geological knowledge has progressed in time, fueled by economic and scientific reasons.

  14. Natural and industrial analogues for release of CO2 from storagereservoirs: Identification of features, events, and processes and lessonslearned

    Energy Technology Data Exchange (ETDEWEB)

    Lewicki, Jennifer L.; Birkholzer, Jens; Tsang, Chin-Fu

    2006-03-03

    The injection and storage of anthropogenic CO{sub 2} in deep geologic formations is a potentially feasible strategy to reduce CO{sub 2} emissions and atmospheric concentrations. While the purpose of geologic carbon storage is to trap CO{sub 2} underground, CO{sub 2} could migrate away from the storage site into the shallow subsurface and atmosphere if permeable pathways such as well bores or faults are present. Large-magnitude releases of CO{sub 2} have occurred naturally from geologic reservoirs in numerous volcanic, geothermal, and sedimentary basin settings. Carbon dioxide and natural gas have also been released from geologic CO{sub 2} reservoirs and natural gas storage facilities, respectively, due to influences such as well defects and injection/withdrawal processes. These systems serve as natural and industrial analogues for the potential release of CO{sub 2} from geologic storage reservoirs and provide important information about the key features, events, and processes (FEPs) that are associated with releases, as well as the health, safety, and environmental consequences of releases and mitigation efforts that can be applied. We describe a range of natural releases of CO{sub 2} and industrial releases of CO{sub 2} and natural gas in the context of these characteristics. Based on this analysis, several key conclusions can be drawn, and lessons can be learned for geologic carbon storage. First, CO{sub 2} can both accumulate beneath, and be released from, primary and secondary reservoirs with capping units located at a wide range of depths. Both primary and secondary reservoir entrapments for CO{sub 2} should therefore be well characterized at storage sites. Second, many natural releases of CO{sub 2} have been correlated with a specific event that triggered the release, such as magmatic fluid intrusion or seismic activity. The potential for processes that could cause geomechanical damage to sealing cap rocks and trigger the release of CO{sub 2} from a storage

  15. Tourist and recreational components of monitoring of geological natural monuments of Ukraine.

    Directory of Open Access Journals (Sweden)

    Manyuk.V.V.

    2010-06-01

    Full Text Available Consider the historical background of state monitoring of geological heritage and the problem of Ukraine tourist and recreational use of geological monuments of nature, as an important part of their promotion, aimed at preserving the unique objects of geology. Attention is focused on the legal and legislative basis of geological monuments of nature conservation, ecotourism and use Ecoeducational aspects of their monitoring.

  16. The Palmottu natural analogue project. The behaviour of natural radionuclides in and around uranium deposits. Summary report 1992-1994

    Energy Technology Data Exchange (ETDEWEB)

    Blomqvist, R.; Ruskeeniemi, T.; Ahonen, L. [Geological Survey of Finland, Espoo (Finland); Suksi, J. [Helsinki Univ. (Finland). Lab. of Radiochemistry; Niini, H. [Helsinki Univ. of Technology, Otaniemi (Finland). Lab. of Engineering Geology and Geophysics; Vuorinen, U. [VTT Chemical Technology, Espoo (Finland); Jakobsson, K. [Finnish Centre for Radiation and Nuclear Safety, Helsinki (Finland)

    1995-06-01

    The Palmottu U-Th mineralization at Nummi-Pusula, southwestern Finland, has been studied as a natural analogue to deep disposal of radioactive wastes since 1988. The report gives a summary of the results of investigations carried out during the years 1992-1994. The Palmottu Analogue Project aims at a more profound understanding of radionuclide transport processes in fractured crystalline bedrock. The essential factors controlling transport are groundwater flow and interaction between water and rock. Accordingly, the study includes structural interpretations based in part on geophysical measurements, hydrological studies including hydraulic downhole measurements, flow modelling, hydrogeochemical characterization of groundwater, uranium chemistry and colloid chemistry, mineralogical studies, geochemical interpretation and modelling, including paleohydrogeological aspects, and studies of radionuclide mobilization and migration processes including numerical simulations. The project has produced a large amount of data related to natural analogue aspects. The data obtained have already been utilized in developing logical conceptual ideas of the time frames and processes operating in the bedrock of the site. (61 refs., 24 figs., 8 tabs.).

  17. Natural analogues in the performance assessment of a nuclear waste disposal: the Cortijo de Archidona deposit and the salinity effect

    Energy Technology Data Exchange (ETDEWEB)

    Fernandez, A.; Pelayo, M.; Rivas, P.; Perez del Villar, L. [Centro de Investigaciones Energeticas, Medioambientales y Tecnologicas (CIEMAT), Dpt. of Energy Environmental Impact, Madrid (Spain); Arcos, D. [Enviros, Barcelona (Spain); Tsige, M. [Universidad Complutense de Madrid, Facultad de Ciencias Geologicas, Madrid (Spain); Fernandez-Soler, J.M. [Granada Univ., Dpt. de Mineralogia y Petrologia (Spain)

    2005-07-01

    In this work, the Cortijo de Archidona bentonite deposit, which was selected as a source for buffer material for the potential Spanish repository has been studied as a natural analogue of the behaviour of bentonite engineered barrier affected by a natural saline-water front. It seems that different post-formational processes have affected this bentonite deposit as a consequence of the different types of groundwaters infiltrated during its recent geological history. The objective of this study is to determine the physico-chemical behaviour of the bentonite as a result of the alteration processes induced by changes in the chemistry of the pore water in the deposit. Examinations were mainly focused on the bentonite mineralogy and micro-fabric, the pore water composition and the physico-chemical properties. Special emphasis has been given to the role of the water-bentonite interaction processes involving accessory non-clay minerals, which affect the bentonite cementation and its buffer capacity of pH and redox potential of the near-field pore waters. These are critical parameters for the performance assessment of the engineered barrier. (authors)

  18. Potential impacts on groundwater resources of deep CO2 storage: natural analogues for assessing potential chemical effects

    Science.gov (United States)

    Lions, J.; Gale, I.; May, F.; Nygaard, E.; Ruetters, H.; Beaubien, S.; Sohrabi, M.; Hatzignatiou, D. G.; CO2GeoNet Members involved in the present study Team

    2011-12-01

    Carbon dioxide Capture and Storage (CCS) is considered as one of the promising options for reducing atmospheric emissions of CO2 related to human activities. One of the main concerns associated with the geological storage of CO2 is that the CO2 may leak from the intended storage formation, migrate to the near-surface environment and, eventually, escape from the ground. This is a concern because such leakage may affect aquifers overlying the storage site and containing freshwater that may be used for drinking, industry and agriculture. The IEA Greenhouse Gas R&D Programme (IEAGHG) recently commissioned the CO2GeoNet Association to undertake a review of published and unpublished literature on this topic with the aim of summarizing 'state of the art' knowledge and identifying knowledge gaps and research priorities in this field. Work carried out by various CO2GeoNet members was also used in this study. This study identifies possible areas of conflict by combining available datasets to map the global and regional superposition of deep saline formations (DSF) suitable for CO2 storage and overlying fresh groundwater resources. A scenario classification is developed for the various geological settings where conflict could occur. The study proposes two approaches to address the potential impact mechanisms of CO2 storage projects on the hydrodynamics and chemistry of shallow groundwater. The first classifies and synthesizes changes of water quality observed in natural/industrial analogues and in laboratory experiments. The second reviews hydrodynamic and geochemical models, including coupled multiphase flow and reactive transport. Various models are discussed in terms of their advantages and limitations, with conclusions on possible impacts on groundwater resources. Possible mitigation options to stop or control CO2 leakage are assessed. The effect of CO2 pressure in the host DSF and the potential effects on shallow aquifers are also examined. The study provides a review of

  19. The Use of Natural Polymers in Tissue Engineering: A Focus on Electrospun Extracellular Matrix Analogues

    Directory of Open Access Journals (Sweden)

    Gary L. Bowlin

    2010-11-01

    Full Text Available Natural polymers such as collagens, elastin, and fibrinogen make up much of the body’s native extracellular matrix (ECM. This ECM provides structure and mechanical integrity to tissues, as well as communicating with the cellular components it supports to help facilitate and regulate daily cellular processes and wound healing. An ideal tissue engineering scaffold would not only replicate the structure of this ECM, but would also replicate the many functions that the ECM performs. In the past decade, the process of electrospinning has proven effective in creating non-woven ECM analogue scaffolds of micro to nanoscale diameter fibers from an array of synthetic and natural polymers. The ability of this fabrication technique to utilize the aforementioned natural polymers to create tissue engineering scaffolds has yielded promising results, both in vitro and in vivo, due in part to the enhanced bioactivity afforded by materials normally found within the human body. This review will present the process of electrospinning and describe the use of natural polymers in the creation of bioactive ECM analogues in tissue engineering.

  20. Non-Natural Sugar Analogues: Chemical Probes for Metabolic Oligosaccharide Engineering

    Science.gov (United States)

    Aich, Udayanath; Yarema, Kevin J.

    Metabolic oligosaccharide engineering (MOE) is a rapidly growing technology emerging from the field of chemical biology that allows novel chemical functionalities to be biosynthetically installed into the carbohydrates of living cells and animals. Since pioneering efforts to modulate sialic acid display through the use of non-natural N-acetyl-D-mannosamine (ManNAc) analogues were reported 15 years ago, monosaccharide probes have been developed to manipulate N-acetyl-D-galactosamine (GalNAc), N-acetyl-D-glucosamine (GlcNAc), and fucose-containing glycans. The 'first generation' of analogues, comprised of a series of ManNAc derivatives with elongated N-acyl chains, demonstrated pathway permissivity and the ability of this methodology to impinge on biological processes ranging from pathogen binding to gene expression and cell adhesion. Later analogues have incorporated chemical function groups including ketones, azides, thiols, and alkyne not normally found in carbohydrates. These groups serve as 'tags' for the subsequent use of chemoselective ligation reactions to further elaborate the chemical properties of the cell surface and thereby greatly expand the potential of MOE technology to offer control over biological processes.

  1. Natural and industrial analogues for leakage of CO2 from storagereservoirs: identification of features, events, and processes and lessonslearned

    Energy Technology Data Exchange (ETDEWEB)

    Lewicki, Jennifer L.; Birkholzer, Jens; Tsang, Chin-Fu

    2006-02-28

    The injection and storage of anthropogenic CO2 in deepgeologic formations is a potentially feasible strategy to reduce CO2emissions and atmospheric concentrations. While the purpose of geologiccarbon storage is to trap CO2 underground, CO2 could migrate away fromthe storage site into the shallow subsurface and atmosphere if permeablepathways such as well bores or faults are present. Large-magnitudereleases of CO2 have occurred naturally from geologic reservoirs innumerous volcanic, geothermal, and sedimentary basin settings. Carbondioxide and natural gas have also been released from geologic CO2reservoirs and natural gas storage facilities, respectively, due toinfluences such as well defects and injection/withdrawal processes. Thesesystems serve as natural and industrial analogues for the potentialrelease of CO2 from geologic storage reservoirs and provide importantinformation about the key features, events, and processes (FEPs) that areassociated with releases, as well as the health, safety, andenvironmental consequences of releases and mitigation efforts that can beapplied. We describe a range of natural releases of CO2 and industrialreleases of CO2 and natural gas in the context of these characteristics.Based on this analysis, several key conclusions can be drawn, and lessonscan be learned for geologic carbon storage. First, CO2 can bothaccumulate beneath, and be released from, primary and secondaryreservoirs with capping units located at a wide range of depths. Bothprimary and secondary reservoir entrapments for CO2 should therefore bewell characterized at storage sites. Second, many natural releases of CO2have been correlated with a specific event that triggered the release,such as magmatic fluid intrusion or seismic activity. The potential forprocesses that could cause geomechanical damage to sealing cap rocks andtrigger the release of CO2 from a storage reservoir should be evaluated.Third, unsealed fault and fracture zones may act as fast and directconduits

  2. Recent outputs of the Oklo (Gabon) natural analogue study to nuclear waste disposal; Apports recents de l'etude de l'analogue naturel Oklo (Gabon) dans le domaine du stockage des dechets nucleaires

    Energy Technology Data Exchange (ETDEWEB)

    Michaud, V.; Trotignon, L. [CEA Cadarache, Dept. d' Entreposage et de Stockage des Dechets (DCC/DESD/SESD), 13 - Saint-Paul-lez-Durance (France); Louvat, D. [CEA Cadarache, (IPSN/DPRE/SERNAT/LERCM), 13 - Saint-Paul-lez-Durance (France)

    2000-07-01

    In the past twenty five years, the natural nuclear reactors of Oklo have been the subject of numerous detailed studies. First investigated for the physical and neutron aspects of the nuclear reaction, they were then reconsidered because they provide a unique opportunity in the world to study the containment of actinides and fission products in a geological formation over a broad timescale (two billion years). Although the sites investigated do not represent a complete analogue of a repository system, many of the processes studied (mass transfer to the surface, transport, migration / retention), the spatial extent of these processes, and the timescales involved, are compatible with processes liable to occur during the lifespan of a repository for the deep geological disposal of spent nuclear fuel. A fresh program was therefore initiated as a European Commission project in 1990, entitled''Oklo as a natural analog for transfer processes in a radioactive waste repository'- phase 7, and then extended by a phase 2 entitled Oklo, Natural Analogue - Behavior of Nuclear Reaction Products in a Natural Environment''. Researches conducted in phase I served to determine the physical conditions of the operation of the natural reactor, reconstruct the geological history of the reactor environment, and decode the behavior of actinides as well as fission products in the surrounding geological formations. Phase N, which ended in June 1999, had three main objectives: i) to assess radionuclide migration and retention processes from the reactor zones to the geological environment, ii) to define the confinement properties and long-term behavior of geological materials; iii) to test models of processes related to radionuclide migration and retention, and eventually to provide suitable data and scenarios for performance assessment of nuclear waste disposal. This paper proposes a synthesis of the main outputs of the Oklo project to the performance assessment of

  3. Exploration methods for granitic natural stones – geological and topographical aspects from case studies in Finland

    Directory of Open Access Journals (Sweden)

    Olavi Selonen

    2014-06-01

    Full Text Available Regional and local geological constraints for location of natural stone deposits in glaciated terrains of southern and central Finland have been studied and applied to practical exploration for natural stone. A list of geological and topographical aspects to be considered in exploration, is presented. Important aspects refer to: 1. Regional geology of the target area. 2. Magmatism (type and structure of intrusion, relative time of pluton emplacement. 3. Metamorphism (grade, mineral composition, parent material. 4. Deformation (lineaments, shear zones, folding, fault zones, fracture zones, shape preferred mineral orientations, and 5. Topography (relative elevation, micro topography. The proposed aspects can be used as geological guidelines in exploration for granitic natural stones.

  4. The Alligator rivers natural analogue - Modelling of uranium and thorium migration in the weathered zone at Koongarra

    Energy Technology Data Exchange (ETDEWEB)

    Skagius, K.; Lindgren, M.; Boghammar, A.; Brandberg, F.; Pers, K.; Widen, H. [Kemakta, Stockholm (Sweden)

    1993-08-01

    The Koongarra Uranium Deposit in the Alligator Rivers Region in the Northern Territory of Australia is a natural analogue being investigated with the aim to contribute to the understanding of the scientific basis for the long term prediction of radionuclide migration within geological environments relevant to radioactive waste repositories. The dispersion of uranium and decay products in the weathered zone has been modelled with a simple advection-dispersion-reversible sorption model and with a model extended to also consider {alpha}-recoil and transfer of radionuclides between different mineral phases of the rock. The modelling work was carried out in several iterations, each including a review of available laboratory and field data, selection of the system to be modelled and suitable model, and a comparison of modelling results with field observations. Uranium concentrations in bulk rock calculated with the simple advection-dispersion- reversible sorption model were in fair agreement with observed data using parameter values within ranges recommended based on independent interpretations. The advection-dispersion-reversible sorption model is a large simplification of the system among other things because the partitioning of radionuclides between water and solid phase is described with a sorption equilibrium term only. Although the results from this study not are enough to validate simple performance assessment models in a strict sense, it has been shown that even simple models are able to describe the present day distribution of uranium in the weathered zone at Koongarra. 23 refs, 61 figs.

  5. Synthesis and evaluation of anticancer natural product analogues based on angelmarin: targeting the tolerance towards nutrient deprivation.

    Science.gov (United States)

    Magolan, Jakob; Adams, Nathan B P; Onozuka, Hiroko; Hungerford, Natasha L; Esumi, Hiroyasu; Coster, Mark J

    2012-05-01

    Inspired by nature: Angelmarin is an anticancer natural product with potent antiausterity activity, that is, selective cytotoxicity towards nutrient-deprived, resistant cancer cells. Through structure-activity relationship studies, three analogues were identified as lead compounds for the develpoment of molecular probes for the investigation of the mode of action and biological targets of the antiausterity compounds.

  6. Natural CO{sub 2} accumulations in Europe: understanding long-term geological processes in CO{sub 2} sequestration

    Energy Technology Data Exchange (ETDEWEB)

    J.M. Pearce; J. Baker; S. Beaubien; S. Brune; I. Czernichowski-Lauriol; E. Faber; G. Hatziyannis; A. Hildenbrand; B.M. Krooss; S. Lombardi; A. Nador; H. Pauwels; B.M. Schroot [British Geological Survey, Nottingham (United Kingdom)

    2003-07-01

    Natural CO{sub 2} accumulations offer the potential to understand the long-term geological processes involved in CO{sub 2} sequestration. By identifying the effects of CO{sub 2} on rock properties, such as changes in permeability and porosity or rock strength, models can be corroborated against empirical data. This can build confidence in their ability to predict likely responses of reservoirs and cap-rocks to geological sequestration. In addition, where CO{sub 2} is actively leaking to the surface, the effects of CO{sub 2} on groundwaters and ecosystems can be identified, and migration mechanisms can be described. CO{sub 2} gas accumulations are common throughout the world. The 'Natural Analogues for the Storage of CO{sub 2} in the Geological Environment' (NASCENT: www.bgs.ac.uk/nascent) project is studying several of these accumulations in Europe. The sites include both areas where CO{sub 2} gas pools have been trapped for geological timescales and areas where CO{sub 2} is leaking at the ground surface. The research group is determining the interactions between CO{sub 2}-charged porewaters and both reservoirs and their caprocks through petrographic characterisation, porewater and gas geochemistry, geomechanical testing and gas migration studies in low permeability caprocks. Leakage pathways are identified through soil gas surveys for CO{sub 2} and associated tracer gases. Geochemical analyses of carbonated waters are assessing the effects of CO{sub 2} on groundwaters. An understanding of these processes will be subsequently gained through geochemical and geomechanical modelling. This paper reviews the six European sites being studied to address these issues and the data obtained so far. 10 refs., 1 fig., 1 tab.

  7. Nematicidal activity of natural ester compounds and their analogues against pine wood nematode, Bursaphelenchus xylophilus.

    Science.gov (United States)

    Seo, Seon-Mi; Kim, Junheon; Koh, Sang-Hyun; Ahn, Young-Joon; Park, Il-Kwon

    2014-09-17

    In this study, we evaluated the nematicidal activity of natural ester compounds against the pine wood nematode, Bursaphelenchus xylophilus, to identify candidates for the development of novel, safe nematicides. We also tested the nematicidal activity of synthesized analogues of these ester compounds to determine the structure-activity relationship. Among 28 ester compounds tested, isobutyl 2-methylbutanoate, 3-methylbutyl 2-methylbutanoate, 3-methylbutyl tiglate, 3-methyl-2-butenyl 2-methylbutanoate, and pentyl 2-methylbutanoate showed strong nematicidal activity against the pine wood nematode at a 1 mg/mL concentration. The other ester compounds showed weak nematicidal activity. The LC50 values of 3-methylbutyl tiglate, isobutyl 2-methylbutanoate, 3-methylbutyl 2-methylbutanoate, 3-methyl-2-butenyl 2-methylbutanoate, and pentyl 2-methylbutanoate were 0.0218, 0.0284, 0.0326, 0.0402, and 0.0480 mg/mL, respectively. The ester compounds described herein merit further study as potential nematicides for pine wood nematode control.

  8. Human History and Environmental Geology: A Match Made in Nature

    Science.gov (United States)

    Selvans, M. M.

    2014-12-01

    I draw on my dual educational background in the geological sciences (PhD) and sociology (BA), with an emphasis on environmental justice, for the inspiration to approach issues in my geology courses that are directly connected to modern policy decisions with the goal of increasing students' self-awareness. I believe that giving students the opportunity for increased understanding of their own beliefs and values with respect to the environment will allow them to be more engaged in discussions and debates about environmental policies at the local, national, and global scales. I designed Environmental Geology of Prince William Forest Park (VA), a one-day Field Studies course offered through Northern Virginia Community College, to motivate students to articulate personal convictions about land use. To provide a social context for discussion of environmental issues, students first gave presentations on the demographics, economics, and methods of land use of the people that used the park over the last 400 years. At locations along Quantico Creek, students presented topics that covered geologic processes at work on the landscape, progressive farming methods promoted by some early Virginians, and agricultural methods to stabilize soil and its nutrients. Finally, at the Cabin Branch Pyrite Mine (active 1889-1920) we discussed laborer work conditions and the environmental impact of tailings, as well as the process and effects of remediation. Students tested pH levels in the creek upstream and downstream of the mine as one concrete way to personally observe the results of recent remediation (since 1994), with neutral pH in both locations indicating success. Students wrapped up the course with written reflections, from their own perspectives with respect to socially and environmentally responsible land use, on the geologic processes and human impacts that shaped the park. Social justice and environmental stewardship are two lenses that allow students to find personal meaning

  9. Workshop on the role of natural analogs in geologic disposal of high-level nuclear waste

    Energy Technology Data Exchange (ETDEWEB)

    Murphy, W.M. [Center for Nuclear Waste Regulations Analyses, San Antonio, TX (United States); Kovach, L.A. [Nuclear Regulatory Commission, Washington, DC (United States)

    1995-09-01

    A workshop on the Role of Natural Analogs in Geologic Disposal of High-Level Nuclear Waste (HLW) was held in San Antonio, Texas, on July 22-25, 1991. It was sponsored by the US Nuclear Regulatory Commission (NRC) and the Center for Nuclear Waste Regulatory Analyses (CNWRA). Invitations to the workshop were extended to a large number of individuals with a variety of technical and professional interests related to geologic disposal of nuclear waste and natural analog studies. The objective of the workshop was to examine the role of natural analog studies in performance assessment, site characterization, and prioritization of research related to geologic disposal of HLW.

  10. Impact of the changes in the chemical composition of pore water on chemical and physical stability of natural clays. A review of natural cases and related laboratory experiments and the ideas on natural analogues for bentonite erosion/non-erosion

    Energy Technology Data Exchange (ETDEWEB)

    Puura, Erik (Eridicon OUe, Tartu (Estonia)); Kirsimaee, Kalle (Univ. of Tartu, Inst. of Ecology and Earth Sciences, Tartu (Estonia))

    2010-01-15

    A scientific literature survey was compiled with the specific objective to find information for smectite mobilization and/or retention in natural clay formations caused by contact with water with low ionic concentrations such as can be expected during and after an ice age. Evidence was sought if smectite particles are lost from the clay to the water and if accessory minerals that remain could form a growing filter slowing down or stopping further loss of smectite. Bentonites are present in geological layers for hundreds of millions of years. There is limited exchange with surrounding layers, eg K transported into the bentonite layer from surrounding shale layers leading to the increased illite % in smectite-illite of the bentonite. Another process is silicification of surrounding layers leading to lowered permeability of surrounding rocks. Geological literature data on historical bentonites do not consider colloid formation in low ionic strength water as relevant mechanism for smectite mobilization. However there are no studied cases where this could be a relevant mechanism (as proposed by colloid release scenario). Soil researchers have studied the mechanism of colloid release in laboratory experiments and have found that there has to be an abrupt change in infiltrating water quality leading to 'osmotic explosion'. Clogging the pores in the lower part of the soil column has followed, leading to dramatic decrease of hydraulic conductivity in vertical profile and increased surface runoff. So, although limited, there are literature evidences of clay colloids release from bentonites/smectites caused by low-ionic circumneutral water. The geological settings to look for natural analogue studies include (1) Bentonite/smectite similar to what is used in repository. (2) Water similar to the composition of glacial meltwater. (3) Scenario similar to what is proposed in the bentonite erosion project. The problem related to the study of historical bentonite profiles

  11. Encapsulation of piceatannol, a naturally occurring hydroxylated analogue of resveratrol, by natural and modified cyclodextrins.

    Science.gov (United States)

    Matencio, Adrián; García-Carmona, Francisco; López-Nicolás, José Manuel

    2016-05-18

    In this work, an in-depth study of the interaction between piceatannol (a type of stilbene with high biological activity) and different natural and modified cyclodextrins (CDs) is made, using steady state fluorescence. This bioactive molecule forms a 1 : 1 complex with all the natural (α-CD, β-CD and γ-CD) and modified (HP-β-CD, HE-β-CD and M-β-CD) CDs tested. Among natural CDs, the interaction of piceatannol with β-CD was the most efficient. However, the modified CDs showed higher encapsulation constants (KF) than β-CD, except M-β-CD; the highest KF being found for HP-β-CD (14 048 ± 702 M(-1)). The encapsulation of piceatannol in the internal cavity of CDs showed a strong dependence on pH and temperature. The interaction between HP-β-CD and piceatannol was less effective in the pH region where the stilbene begins to suffer the deprotonation of its hydroxyl group. Moreover, the values of KF decreased as the system temperature increased. To obtain information on the mechanism involved in the piceatannol affinity for CD, the thermodynamic parameters of the complexation (ΔH°, ΔS° and ΔG°) were studied, the results showed a negative entropy (-3.7 ± 0.2 J mol(-1) K(-1)), enthalpy (-24.6 ± 1.2 kJ mol(-1)) and Gibbs free energy change at 25 °C (-23.5 ± 1.2 J mol(-1)). Finally, molecular docking calculations provided further insights into how the different interactions influence the complexation constant. A high degree of correlation was observed between the computed scores and experimental values.

  12. Geology

    Data.gov (United States)

    Kansas Data Access and Support Center — This database is an Arc/Info implementation of the 1:500,000 scale Geology Map of Kansas, M­23, 1991. This work wasperformed by the Automated Cartography section of...

  13. Petroleum and natural gas geology and plate tectonics

    Energy Technology Data Exchange (ETDEWEB)

    Koebel, B.

    1984-01-01

    Several processes of oil and gas geology are studied in connection with plate-tectonical processes. Thus it becomes clear, that there is a distinct difference between the Paleozoic development of the European plate and the Mesozoic development. One can state, that the Paleozoic development is essentially influenced by the positions of the mobile belts and the cratonized parts of the plates. The development during Meso-Caenozoic is mainly characterized by crustal processes in the result of the disintegration of Pangaea.

  14. Multi-isotope tracing of CO2 leakage and water-rock interaction in a natural CCS analogue.

    Science.gov (United States)

    Kloppmann, Wolfram; Gemeni, Vasiliki; Lions, Julie; Koukouzas, Nikolaos; Humez, Pauline; Vasilatos, Charalampos; Millot, Romain; Pauwels, Hélène

    2015-04-01

    Natural analogues of CO2 accumulation and, potentially, leakage, provide a highly valuable opportunity to study (1) geochemical processes within a CO2-reservoir and the overlying aquifers or aquicludes, i.e. gas-water-rock interactions, (2) geology and tightness of reservoirs over geological timescales, (3) potential or real leakage pathways, (3) impact of leakage on shallow groundwater resources quality, and (4) direct and indirect geochemical indicators of gas leakage (Lions et al., 2014, Humez et al., 2014). The Florina Basin in NW Macedonia, Greece, contains a deep CO2-rich aquifer within a graben structure. The graben filling consists of highly heterogeneous Neogene clastic sediments constituted by components from the adjacent massifs including carbonates, schists, gneiss as well as some ultramafic volcanic rocks. Clay layers are observed that isolate hydraulically the deep, partly artesian aquifer. Organic matter, in form of lignite accumulations, is abundant in the Neogene series. The underlying bedrocks are metamorphic carbonates and silicate rocks. The origin of the CO2 accumulation is controversial (deep, partially mantle-derived D'Allessandro et al., 2008 or resulting from thermal decomposition of carbonates, Hatziyannis and Arvanitis, 2011). Groundwaters have been sampled from springs and borewells over 3 years at different depths. First results on major, minor and trace elements give evidence of water-rock interaction, mainly with carbonates but also with ultramafic components but do not indicate that CO2-seepage is the principal driver of those processes (Gemeni et al., submitted). Here we present isotope data on a selection of groundwaters (δ2H , δ18O, δ13CTDIC, 87Sr/86Sr, δ11B, δ7Li). Stable isotopes of water indicate paleo-recharge for some of the groundwaters, limited exchange with gaseous CO2 and, in one case, possibly thermal exchange processes with silicates. Sr isotope ratios vary between marine ratios and radiogenic values indicating

  15. Thermochemically induced transformations in Al-smectites: A Spanish natural analogue of the bentonite barrier behaviour in a radwaste disposal

    Energy Technology Data Exchange (ETDEWEB)

    Perez del Villar, L. [CIEMAT/DIAE/CHE/Ed.20, Avda. Complutense 22, 28040 Madrid (Spain)]. E-mail: l.pvillar@ciemat.es; Delgado, A. [Dpto. de Ciencias de la Tierra y Quimica Ambiental, Estacion Experimental del Zaidin (CSIC), Prof. Albareda 1, 18008 Granada (Spain); Reyes, E. [Dpto. de Ciencias de la Tierra y Quimica Ambiental, Estacion Experimental del Zaidin (CSIC), Prof. Albareda 1, 18008 Granada (Spain); Pelayo, M. [CIEMAT/DIAE/CHE/Ed.20, Avda. Complutense 22, 28040 Madrid (Spain); Fernandez-Soler, J.M. [Dpto. de Mineralogia y Petrologia, Universidad de Granada, Avda. Fuentenueva s/n, 18002 Granada (Spain); Cozar, J.S. [CIEMAT/DIAE/CHE/Ed.20, Avda. Complutense 22, 28040 Madrid (Spain); Tsige, M. [Dpto. de Geodinamica, Facultad de Ciencias Geologicas, Universidad Complutense, Avda. Complutense s/n, 28040 Madrid (Spain); Quejido, A.J. [CIEMAT/DIAE/CHE/Ed.20, Avda. Complutense 22, 28040 Madrid (Spain)

    2005-12-15

    The thermal effect induced by the Morron de Mateo volcanic dome (Cabo de Gata volcanic region, Spain) on the adjacent bentonitised tuffaceous beds has been studied as a natural analogue of the thermal behaviour of the bentonite-engineered barrier of a geological radwaste repository. These bentonites consist mainly of Fe-rich smectites and were formed in equilibrium with seawater at temperatures between 75 and 95 {sup o}C, according to the {delta} {sup 18}O and {delta}D values. In contrast, bentonites from other localities in the region consist mainly of Al-smectites, formed in equilibrium with meteoric water below 25 deg. C. This investigation is focussed on the detection of the chemical differences between smectites from proximal and distal zones to the dome, as well as to test whether the temperatures calculated based on the O and H isotopic values correspond to their formation or transformation. The initial hypothesis was that the chosen smectites could be formed under marine conditions, being later transformed and isotopically re-equilibrated as a result of the intrusion. To check this hypothesis, a detailed mineralogical, chemical, geochemical and isotopic study has been performed on the smectitised tuffaceous materials and the overlaying biocalcarenites outcropping near and far from the dome. The results show that distal smectites are dioctahedral Al-smectites, similar to those from other deposits in the region, while proximal smectites are Fe- and Mg-rich smectites, showing two evolutionary trends on a Fe-Mg-Al ternary diagram. Similar features are observed when their structural formulae are plotted on the muscovite-celadonite-pyrophylite diagram. Thus, they plot in the smectite domain with interlayer charge less than 1, which is mainly due to octahedral substitution for distal smectites, while for proximal ones it is caused by both octahedral and tetrahedral substitutions. In this ternary diagram, the domains of both proximal and distal smectites are

  16. Results of international field experiment on a natural CO{sub 2} analogue

    Energy Technology Data Exchange (ETDEWEB)

    Summers, J.; Bergman, P. [United States Dept. of Energy, Pittsburgh, PA (United States); Smith, C. [Hawaii Univ., Honolulu, HI (United States); Vetter, E. [Hawaii Pacific Univ. Honolulu HI (United States); Adams, E. [Massachusetts Inst. of Technology, Cambridge, MA (United States). Dept. of Civil and Environmental Engineering; Akai, M. [National Inst. of Advanced Industrial Science and Technology, Tokyo (Japan)

    2005-07-01

    This paper described an international field experiment conducted to investigate a natural analogue of carbon dioxide (CO{sub 2}) and its effects on marine biology. The experiment took place at the Loihi seamount volcano in Hawaii. The CO{sub 2} analogue was investigated as a first order proxy in order to determine the potential effects of depressed pH and hypercapnia that may arise as a result of continuous and concentrated deepsea injection of CO{sub 2}. Three categories of potential impacts were investigated: (1) alteration of community structure; (2) alteration of ecosystem function; and (3) creation of a mortality sink. The aim of the study was to ascertain the level of CO{sub 2} enrichment in which marine communities were significantly impacted. End member fluids from Loihi's vents are depleted in oxygen and naturally enriched with salts, CO{sub 2}, metals, and compounds. Loihi vent fluids contain CO{sub 2} at concentrations as high as 418 mol/m{sup 3} at a depth of approximately 1300 m. A typical Loihi vent injects more than 100,000 tonnes of CO{sub 2} into surrounding waters each year. Scavenger trap experiments were designed to evaluate the impact of high CO{sub 2} settings on mobile scavengers. Amphipods were trapped and placed directly over venting fluids for 1 hour at a site where venting fluids were clearly visible due to schlierin effects. Bait parcels were placed at reference sites away from venting fluids and directly adjacent to vents where venting fluids were percolating through a rock and cinder-covered slope rising to the perimeter of the pit crater. Bait parcels at the vent sites were continuously bathed in vent fluids. Animals were monitored and observed and filmed with a video camera. Results of the study showed that the mobile scavengers avoided bait when they would be forced to enter chemically altered conditions to consume it. When forced to enter water with a depressed pH due to high concentrations of CO{sub 2}, the amphipods remained

  17. Heterogeneous seepage at the Nopal I natural analogue site, Chihuahua, Mexico

    Energy Technology Data Exchange (ETDEWEB)

    Dobson, Patrick F.; Cook, Paul J.; Ghezzehei, Teamrat A.; Rodriguez, J. Alfredo; Villalba, Lourdes; de la Garza, Rodrigo

    2008-10-25

    An integrated field, laboratory, and modeling study of the Pena Blanca (Chihuahua, Mexico) natural analogue site is being conducted to evaluate processes that control the mobilization and transport of radionuclides from a uranium ore deposit. One component of this study is an evaluation of the potential for radionuclide transport through the unsaturated zone (UZ) via a seepage study in an adit at the Nopal I uranium mine, excavated 10 m below a mined level surface. Seasonal rainfall on the exposed level surface infiltrates into the fractured rhyolitic ash-flow tuff and seeps into the adit. An instrumented seepage collection system and local automated weather station permit direct correlation between local precipitation events and seepage within the Nopal I +00 adit. Monitoring of seepage within the adit between April 2005 and December 2006 indicates that seepage is highly heterogeneous with respect to time, location, and quantity. Within the back adit area, a few zones where large volumes of water have been collected are linked to fast flow path fractures (0-4 h transit times) presumably associated with focused flow. In most locations, however, there is a 1-6 month time lag between major precipitation events and seepage within the adit, with longer residence times observed for the front adit area. Seepage data obtained from this study will be used to provide input to flow and transport models being developed for the Nopal I hydrogeologic system.

  18. Heterogeneous seepage at the Nopal I natural analogue site, Chihuahua, Mexico

    Science.gov (United States)

    Dobson, Patrick F.; Ghezzehei, Teamrat A.; Cook, Paul J.; Rodríguez-Pineda, J. Alfredo; Villalba, Lourdes; de La Garza, Rodrigo

    2012-02-01

    A study of seepage occurring in an adit at the Nopal I uranium mine in Chihuahua, Mexico, was conducted as part of an integrated natural analogue study to evaluate the effects of infiltration and seepage on the mobilization and transport of radionuclides. An instrumented seepage collection system and local automated weather station permit direct correlation between local precipitation events and seepage. Field observations recorded between April 2005 and December 2006 indicate that seepage is highly heterogeneous with respect to time, location, and quantity. Seepage, precipitation, and fracture data were used to test two hypotheses: (1) that fast flow seepage is triggered by large precipitation events, and (2) that an increased abundance of fractures and/or fracture intersections leads to higher seepage volumes. A few zones in the back adit recorded elevated seepage volumes immediately following large (>20 mm/day) precipitation events, with transit times of less than 4 h through the 8-m thick rock mass. In most locations, there is a 1-6 month time lag between the onset of the rainy season and seepage, with longer times observed for the front adit. There is a less clear-cut relation between fracture abundance and seepage volume; processes such as evaporation and surface flow along the ceiling may also influence seepage.

  19. Assessment of Undiscovered Natural Gas Resources of the Arkoma Basin Province and Geologically Related Areas

    Science.gov (United States)

    Houseknecht, David W.; Coleman, James L.; Milici, Robert C.; Garrity, Christopher P.; Rouse, William A.; Fulk, Bryant R.; Paxton, Stanley T.; Abbott, Marvin M.; Mars, John L.; Cook, Troy A.; Schenk, Christopher J.; Charpentier, Ronald R.; Klett, Timothy R.; Pollastro, Richard M.; Ellis, Geoffrey S.

    2010-01-01

    Using a geology-based assessment methodology, the U.S. Geological Survey estimated mean volumes of 38 trillion cubic feet (TCF) of undiscovered natural gas, 159 million barrels of natural gas liquid (MMBNGL), and no oil in accumulations of 0.5 million barrels (MMBO) or larger in the Arkoma Basin Province and related areas. More than 97 percent of the undiscovered gas occurs in continuous accumulations-70 percent in shale gas formations, 18 percent in a basin-centered accumulation with tight sandstone reservoirs, and 9 percent in coal beds. Less than 3 percent of the natural gas occurs in conventional accumulations.

  20. Natural Hazards Science at the U.S. Geological Survey

    Science.gov (United States)

    Perry, Suzanne C.; Jones, Lucile M.; Holmes, Jr., Robert R.

    2013-01-01

    The mission of the USGS in natural hazards is to develop and apply hazard science to help protect the safety, security, and economic well-being of the Nation. The costs and consequences of natural hazards can be enormous, and each year more people and infrastructure are at risk. The USGS conducts hazard research and works closely with stakeholders and cooperators to inform a broad range of planning and response activities at individual, local, State, national, and international levels. It has critical statutory and nonstatutory roles regarding floods, earthquakes, tsunamis, landslides, coastal erosion, volcanic eruptions, wildfires, and magnetic storms. USGS science can help to understand and reduce risks from natural hazards by providing the information that decisionmakers need to determine which risk management activities are worth­while.

  1. Total Synthesis of Vinblastine, Vincristine, Related Natural Products, and Key Structural Analogues

    Science.gov (United States)

    Ishikawa, Hayato; Colby, David A.; Seto, Shigeki; Va, Porino; Tam, Annie; Kakei, Hiroyuki; Rayl, Thomas J.; Hwang, Inkyu; Boger, Dale L.

    2009-01-01

    Full details of the development of a direct coupling of catharanthine with vindoline to provide vinblastine are described along with key mechanistic and labeling studies. Following an Fe(III)-promoted coupling reaction initiated by generation of a presumed catharanthine radical cation that undergoes a subsequent oxidative fragmentation and diastereoselective coupling with vindoline, addition of the resulting reaction mixture to an Fe(III)–NaBH4/air solution leads to oxidation of the C15′–C20′ double bond and reduction of the intermediate iminium ion directly providing vinblastine (40–43%) and leurosidine (20–23%), its naturally occurring C20′ alcohol isomer. The yield of coupled products, which exclusively possess the natural C16′ stereochemistry, approaches or exceeds 80% and the combined yield of the isomeric C20′ alcohols is >60%. Preliminary studies of Fe(III)–NaBH4/air oxidation reaction illustrate a generalizable trisubstituted olefin scope, identified alternatives to O2 trap at the oxidized carbon, provides a unique entry into C20′ functionalized vinblastines, and affords initial insights into the observed C20′ diastereoselectivity. The first disclosure of the use of exo-catharanthine proceeding through Δ19′,20′-anhydrovinblastine in such coupling reactions is also detailed with identical stereochemical consequences. Incorporating either a catharanthine N-methyl group or a vindoline N-formyl group precludes Fe(III)-promoted coupling, whereas the removal of the potentially key C16 methoxy group of vindoline does not adversely impact the coupling efficiency. Extension of these studies provided a total synthesis of vincristine (2) via N-desmethylvinblastine (36, also a natural product), 16-desmethoxyvinblastine (44) and 4-desacetoxy-16-desmethoxyvinblastine (47) both of which we can now suggest are likely natural products produced by C. roseus, desacetylvinblastine (62) and 4-desacetoxyvinblastine (59), as well as a series of key

  2. Geological component in the formation of natural - reserve fund of Ukraine

    Directory of Open Access Journals (Sweden)

    Manyuk V.V.

    2014-12-01

    Full Text Available The part of geological component of the natural environment in the formation of Natural Reserve Fund of Ukraine, the historical aspects of the origin and development of the geological heritage, as an important part of the environment, as well as the problem of acceptance geodiversity as well as the conservation of biodiversity. It was established that during the long history in countries not only in Europe but also in the world, formed biodiversity strategy in default or unwilling recognition of the need to preserve geodiversity. Underestimating abiotic factors in the development programs of the European environmental network Natura-2000 and EECONET has led to the need to develop special programs and initiatives in the conservation of the lithosphere, atmosphere and hydrosphere. The basic stages of historical development problems of preservation of geological heritage in Ukraine and the world. It is determined that in Ukraine was established May 21, 1910 the first in Russia (which is then part Khortyts'ke Society for Nature Conservation. The Society, based on the initiative of of natural science teachers P.P. Вouzouk, had the goal of nature conservation within the animal, vegetable and mineral kingdoms of nature, and it was spelled out in the Charter of of society. A significant shift towards awareness of the importance of the geological component in the formation of natural reserve fund was effective collaboration with the Department of Environment and Natural Resources in the Dnipropetrovsk region on creation of new protected areas. When conducting a field and office work on reserving areas for new items Natural Heritage, the first fully studied geological and geomorphological structure of these areas. Moreover, the research facility in an unprecedented short time actually bequeathed, that have approved status of natural monuments, landscape reserves and so on.

  3. THOUGHTS ON THE TOXIC EFFECTS OF NATURAL GEOLOGICAL MATERIALS

    OpenAIRE

    YALÇIN, Hüseyin; TETİKER, Sema

    2017-01-01

    The sources assolid (rock, mineral), liquid (water, oil) and gaseous formed in the Earth areknown as natural substances. Human beings are interaction with the Earth'slayers (geosphere, biosphere, hydrosphere, and atmosphere) where they live inevery day. This relationship is carried out by entering of the element andmineral resources to the body by way of eating, drinking, breathing and dermalabsorption. Most of these sources are useful for the essential foods for humanlife, while some ar...

  4. Natural and Semisynthetic Analogues of Manadoperoxide B Reveal New Structural Requirements for Trypanocidal Activity

    Directory of Open Access Journals (Sweden)

    Orazio Taglialatela-Scafati

    2013-08-01

    Full Text Available Chemical analysis of the Indonesian sponge Plakortis cfr. lita afforded two new analogues of the potent trypanocidal agent manadoperoxide B (1, namely 12-isomanadoperoxide B (2 and manadoperoxidic acid B (3. These compounds were isolated along with a new short chain dicarboxylate monoester (4, bearing some interesting relationships with the polyketide endoperoxides found in this sponge. Some semi-synthetic analogues of manadoperoxide B (6–8 were prepared and evaluated for antitrypanosomal activity and cytotoxicity. These studies revealed crucial structure–activity relationships that should be taken into account in the design of optimized and simplified endoperoxyketal trypanocidal agents.

  5. Lessons from Natural Analog Studies for Geologic Disposal of High-Level Nuclear Waste (Invited)

    Science.gov (United States)

    Murphy, W. M.

    2009-12-01

    For over fifty years natural analog studies have provided lessons addressing scientific, technical, and social problems concerning geologic disposal of high-level nuclear waste. Idealized concepts for permanent disposal environments evolved from an understanding of the geological, geochemical and hydrological characteristics of analogous rocks including natural salt deposits (as advocated by the US National Academy of Sciences in 1957), ancient cratonic rocks (as investigated at Lac du Bonnet, Canada, Aspö, Sweden, and Vienne, France), and marine sedimentary rock formations (as studied at Mol, Belgium, and Bure, France). Additional multidisciplinary studies have been conducted at natural sites that bear characteristics analogous to potential repository systems, notably at natural uranium (and thorium) deposits including Poços de Caldas, Brazil, Alligator Rivers, Australia, Peña Blanca, Mexico, and Oklo, Gabon. Researchers of natural analogs for geologic disposal have addressed technical uncertainties regarding processes that have transpired over large time and space scales, which are generally inaccessible to laboratory studies. Principal questions for nuclear waste disposal include the geochemical stability and alteration rates of radionuclide bearing minerals and the mechanisms and rates of transport of radionuclides in groundwater. In their most direct applications, natural analogs studies have been devoted to testing specific models for repository performance and the experimental data that support those models. Parameters used in predictive performance assessment modeling have been compared to natural system data, including mineral solubilities, sorption coefficients, diffusion rates, and colloid transport properties. For example, the rate of uraninite oxidation and the natural paragenesis of uranium mineral alteration at Peña Blanca have been compared favorably to results of experimental studies of spent fuel alteration related to the proposed repository

  6. 3D geological modelling from boreholes, cross-sections and geological maps, application over former natural gas storages in coal mines

    Energy Technology Data Exchange (ETDEWEB)

    Kaufmann, O.; Martin, T. [Service de Geologie Fondamentale et Appliquee, Mons (Belgium). Faculte Polytechnique de Mons

    2008-03-15

    In a wide range of applications involving geological modelling, geological data available at low cost usually consist of documents such as cross-sections or geological maps and punctual data like borehole logs or outcrop descriptions. In order to build accurate 3D geological models based on this information, it is necessary to develop a methodology that takes into account the variety of available data. Such models, of the geometry of geological bodies, should also be easy to edit and update to integrate new data. This kind of model should produce a consistent representation of subsurface geology that may be a support for modelling other subsoil characteristics such as hydrogeologic or geothermic properties of the geological bodies. This paper presents a methodology developed to process geological information in this context. The aims of this methodology are comprehensive data description, effective data validation and easier model updates. Thus, special attention has been given to data structures and processing flows. The adopted methodology is implemented on a system architecture formed by a geographic information system, a geomodeler and a database communicating by file transfers. An application of this methodology, to build a 3D geological model of the subsoil over former coalmines used to store natural gas, is then presented. This model integrates the geological information available and is representative of the geoloigical context. It is a support to the environmental follow-up needed after the end of gas-storage operations.

  7. Numerical Simulation of Natural Convection in Heterogeneous Porous media for CO2 Geological Storage

    NARCIS (Netherlands)

    Ranganathan, P.; Farajzadeh, R.; Bruining, J.; Zitha, P.L.J.

    2012-01-01

    We report a modeling and numerical simulation study of density-driven natural convection during geological CO2 storage in heterogeneous formations. We consider an aquifer or depleted oilfield overlain by gaseous CO2, where the water density increases due to CO2 dissolution. The heterogeneity of the

  8. Joint interpretation of geoelectrical and soil-gas measurements for monitoring CO2 releases at a natural analogue

    DEFF Research Database (Denmark)

    Sauer, U.; Watanabe, N.; Singh, Ashok

    2014-01-01

    The development and validation of hierarchic monitoring concepts is essential for detecting and assessing possible leakages from storage formations, especially for carbon capture and storage (CCS) applications. Joint interpretation of various techniques (such as carbon dioxide (CO2) concentration...... and flux measurements, self-potential (SP) and geoelectrical surveys) showed that the combination of geophysical methods with soil-gas analysis for mesoscale monitoring of the shallow subsurface above geologic CO2 storages can be a valuable tool for mapping and monitoring potential CO2 spread...... in the subsurface. Three measurement campaigns were undertaken - May 2011, July 2011 and April 2012 - at an analogue site in the Cheb Basin, Czech Republic, with the aim of studying CO2 leakages and their temporal and spatial behaviour. Results of geoelectrical investigations give an insight into the structural...

  9. In situ Nd isotopic measurement of natural geological materials by LA-MC-ICPMS

    Institute of Scientific and Technical Information of China (English)

    YANG YueHeng; SUN JinFeng; XIE LieWen; FAN HongRui; WU FuYuan

    2008-01-01

    Using newly determined Sm isotopic abundances for correcting the isobaric interference of 144Sm on 144Nd and the established mass bias relationship between Sm and Nd, a series of in situ Nd isotopic measurements were conducted for relatively high Nd concentrations of natural geological materials, including apatite, titanite, monazite and perovskite on a Neptune multi-collector inductively coupled plasma mass spectrometry (MC-ICPMS), coupled to a 193 nm ArF excimer laser ablation system. The results show that Ce has no significant influence on the precision and accuracy of Nd isotopic analyses for LREE-enriched geological minerals and that our approach is efficient in obtaining reliable 143Nd/144Nd and 147Sm/144Nd ratios for those materials with Sm/Nd<1 (147Sm/144Nd<0.6). When combined with trace element and U-Pb isotope data, the in situ Nd isotopic data can provide important information on geological processes.

  10. Analogue modelling of inclined, brittle-ductile transpression: Testing analytical models through natural shear zones (external Betics)

    Science.gov (United States)

    Barcos, L.; Díaz-Azpiroz, M.; Balanyá, J. C.; Expósito, I.; Jiménez-Bonilla, A.; Faccenna, C.

    2016-07-01

    The combination of analytical and analogue models gives new opportunities to better understand the kinematic parameters controlling the evolution of transpression zones. In this work, we carried out a set of analogue models using the kinematic parameters of transpressional deformation obtained by applying a general triclinic transpression analytical model to a tabular-shaped shear zone in the external Betic Chain (Torcal de Antequera massif). According to the results of the analytical model, we used two oblique convergence angles to reproduce the main structural and kinematic features of structural domains observed within the Torcal de Antequera massif (α = 15° for the outer domains and α = 30° for the inner domain). Two parallel inclined backstops (one fixed and the other mobile) reproduce the geometry of the shear zone walls of the natural case. Additionally, we applied digital particle image velocimetry (PIV) method to calculate the velocity field of the incremental deformation. Our results suggest that the spatial distribution of the main structures observed in the Torcal de Antequera massif reflects different modes of strain partitioning and strain localization between two domain types, which are related to the variation in the oblique convergence angle and the presence of steep planar velocity - and rheological - discontinuities (the shear zone walls in the natural case). In the 15° model, strain partitioning is simple and strain localization is high: a single narrow shear zone is developed close and parallel to the fixed backstop, bounded by strike-slip faults and internally deformed by R and P shears. In the 30° model, strain partitioning is strong, generating regularly spaced oblique-to-the backstops thrusts and strike-slip faults. At final stages of the 30° experiment, deformation affects the entire model box. Our results show that the application of analytical modelling to natural transpressive zones related to upper crustal deformation

  11. The project De Caldas International Project: An example of a large-scale radwaste isolation natural analogue study

    Energy Technology Data Exchange (ETDEWEB)

    Shea, M. [TerraCon, Inc., Chicago, IL (United States)

    1995-09-01

    The proper isolation of radioactive waste is one of today`s most pressing environmental issues. Research is being carried out by many countries around the world in order to answer critical and perplexing questions regarding the safe disposal of radioactive waste. Natural analogue studies are an increasingly important facet of this international research effort. The Pocos de Caldas Project represents a major effort of the international technical and scientific community towards addressing one of modern civilization`s most critical environmental issues - radioactive waste isolation.

  12. Radiation-Induced Defects in Kaolinite as Tracers of Past Occurrence of Radionuclides in a Natural Analogue of High Level Nuclear Waste Repository

    Science.gov (United States)

    Allard, T.; Fourdrin, C.; Calas, G.

    2007-05-01

    Understanding the processes controlling migrations of radioelements at the Earth's surface is an important issue for the long-term safety assessment of high level nuclear waste repositories (HLNWR). Evidence of past occurrence and transfer of radionuclides can be found using radiation-induced defects in minerals. Clay minerals are particularly relevant because of their widespread occurrence at the Earth's surface and their finely divided nature which provides high contact area with radioactive fluids. Owing to its sensitivity to radiations, kaolinite can be used as natural, in situ dosimeter. Kaolinite is known to contain radiation-induced defects which are detected by Electron Paramagnetic Resonance. They are differentiated by their nature, their production kinetics and their thermal stability. One of these defects is stable at the scale of geological periods and provides a record of past radionuclide occurrence. Based on artificial irradiations, a methodology has been subsequently proposed to determine paleodose cumulated by kaolinite since its formation. The paleodose can be used to derive equivalent radioelement concentrations, provided that the age of kaolinite formation can be constrained. This allows quantitative reconstruction of past transfers of radioelements in natural systems. An example is given for the Nopal I U-deposit (Chihuahua, Mexico), hosted in hydrothermally altered volcanic tufs and considered as analogue of the Yucca Mountain site. The paleodoses experienced by kaolinites were determined from the concentration of defects and dosimetry parameters of experimental irradiations. Using few geochemical assumption, a equivalent U-content responsible for defects in kaolinite was calculated from the paleodose, a dose rate balance and model ages of kaolinites constrained by tectonic phases. In a former study, the ages were assumptions derived from regional tectonic events. In thepresent study, ages of mineralization events are measured from U

  13. 3D geological modelling from boreholes, cross-sections and geological maps, application over former natural gas storages in coal mines (vol 34, pg 278, 2008)

    Energy Technology Data Exchange (ETDEWEB)

    Kaufmann, O.; Martin, T. [Service de Geologie Fondamentale et Appliquee, Mons (Belgium)

    2009-01-15

    In a wide range of applications involving geological modelling, geological data available at low cost usually consist of documents such as cross-sections or geological maps and punctual data like borehole logs or outcrop descriptions. In order to build accurate 3D geological models based on this information, it is necessary to develop a methodology that takes into account the variety of available data. Such models, of the geometry of geological bodies, should also be easy to edit and update to integrate new data. This kind of model should produce a consistent representation of subsurface geology that may be a support for modelling other subsoil characteristics such as hydrogeologic or geothermic properties of the geological bodies. This paper presents a methodology developed to process geological information in this context. The aims of this methodology are comprehensive data description, effective data validation and easier model updates. Thus, special attention has been given to data structures and processing flows. The adopted methodology is implemented on a system architecture formed by a geographic information system, a geomodeler and a database communicating by file transfers. An application of this methodology, to build a 3D geological model of the subsoil over former coalmines used to store natural gas, is then presented. This model integrates the geological information available and is representative of the geological context. It is a support to the environmental follow-up needed after the end of gas-storage operations. This is a correction from the paper in the March 2008 issue (volume 34, part 3, pages 278-290).

  14. Synthesis and Anti-Tuberculosis Activity of the Marine Natural Product Caulerpin and Its Analogues

    Directory of Open Access Journals (Sweden)

    Cristina I. Canché Chay

    2014-03-01

    Full Text Available Caulerpin (1a, a bis-indole alkaloid from the marine algal Caulerpa sp., was synthesized in three reaction steps with an overall yield of 11%. The caulerpin analogues (1b–1g were prepared using the same synthetic pathway with overall yields between 3% and 8%. The key reaction involved a radical oxidative aromatic substitution involving xanthate (3 and 3-formylindole compounds (4a–4g. All bis-indole compounds synthesized were evaluated against the Mycobacterium tuberculosis strain H37Rv, and 1a was found to display excellent activity (IC50 0.24 µM.

  15. Synthesis and Anti-Tuberculosis Activity of the Marine Natural Product Caulerpin and Its Analogues

    Science.gov (United States)

    Canché Chay, Cristina I.; Gómez Cansino, Rocío; Espitia Pinzón, Clara I.; Torres-Ochoa, Rubén O.; Martínez, Roberto

    2014-01-01

    Caulerpin (1a), a bis-indole alkaloid from the marine algal Caulerpa sp., was synthesized in three reaction steps with an overall yield of 11%. The caulerpin analogues (1b–1g) were prepared using the same synthetic pathway with overall yields between 3% and 8%. The key reaction involved a radical oxidative aromatic substitution involving xanthate (3) and 3-formylindole compounds (4a–4g). All bis-indole compounds synthesized were evaluated against the Mycobacterium tuberculosis strain H37Rv, and 1a was found to display excellent activity (IC50 0.24 µM). PMID:24681629

  16. Natural arsenic and uranium accumulation and remobilization in different geological environments

    OpenAIRE

    Banning, Andre

    2012-01-01

    Despite the fact that both As and U represent geogenic trace elements potentially toxic to humans, little information is available on the development of their enrichments in German sediments and their potential impact on groundwater quality, let alone a systematic overview of the country´s natural occurrences. This work aims at characterizing accumulation processes in aquifers actually or potentially affected by elevated concentrations of As and/or U, and their timings in geological history. ...

  17. Rheology and density of glucose syrup and honey: Determining their suitability for usage in analogue and fluid dynamic models of geological processes

    Science.gov (United States)

    Schellart, W. P.

    2011-06-01

    glucose syrup and honey, respectively. The new results demonstrate that glucose syrups and (to a lesser degree) honeys are well suited for usage in analogue and fluid dynamic experiments to represent linear-viscous strain independent and shear rate independent rheologies to model geological processes. Glucose syrups have the added advantage of being more transparent than honeys, allowing for accurately resolving and quantifying flow patterns in the fluid during a model run.

  18. Revisiting AI-2 quorum sensing inhibitors: direct comparison of alkyl-DPD analogues and a natural product fimbrolide.

    Science.gov (United States)

    Lowery, Colin A; Abe, Takumi; Park, Junguk; Eubanks, Lisa M; Sawada, Daisuke; Kaufmann, Gunnar F; Janda, Kim D

    2009-11-04

    Quorum sensing (QS) systems have been discovered in a wide variety of bacteria, and mediate both intra- and interspecies communication. The AI-2-based QS system represents the most studied of these proposed interspecies systems and has been shown to regulate diverse functions such as bioluminescence, expression of virulence factors, and biofilm formation. As such, the development of modulatory compounds, both agonists and antagonists, is of great interest for the study of unknown AI-2-based QS systems and the potential treatment of bacterial infections. The fimbrolide class of natural products has exhibited excellent inhibitory activity against AI-2-based QS and as such may be considered the "gold standard" of AI-2 inhibitors. Thus, we sought to include a fimbrolide as a control compound for our recently developed alkyl-DPD panel of AI-2 modulators. Herein, we present a revised synthesis of a commonly studied fimbrolide as well as a direct comparison between the fimbrolide and alkyl-DPD analogues. We demonstrate that our alkyl-DPD analogues are more potent inhibitors of QS in both Vibrio harveyi and Salmonella typhimurium, the two organisms with defined AI-2 QS systems, and in doing so call into question the widely accepted use of fimbrolide-derived compounds as the "gold standard" of AI-2 inhibition.

  19. A Natural Analogue for Thermal-Hydrological-Chemical Coupled Processes at the Proposed Nuclear Waste Repository at Yucca Mountain, Nevada

    Energy Technology Data Exchange (ETDEWEB)

    Bill Carey; Gordon Keating; Peter C. Lichtner

    1999-08-01

    Dike and sill complexes that intruded tuffaceous host rocks above the water table are suggested as natural analogues for thermal-hydrologic-chemical (THC) processes at the proposed nuclear waste repository at Yucca Mountain, Nevada. Scoping thermal-hydrologic calculations of temperature and saturation profiles surrounding a 30-50 m wide intrusion suggest that boiling conditions could be sustained at distances of tens of meters from the intrusion for several thousand years. This time scale for persistence of boiling is similar to that expected for the Yucca Mountain repository with moderate heat loading. By studying the hydrothermal alteration of the tuff host rocks surrounding the intrusions, insight and relevant data can be obtained that apply directly to the Yucca Mountain repository and can shed light on the extent and type of alteration that should be expected. Such data are needed to bound and constrain model parameters used in THC simulations of the effect of heat produced by the waste on the host rock and to provide a firm foundation for assessing overall repository performance. One example of a possible natural analogue for the repository is the Paiute Ridge intrusive complex located on the northeastern boundary of the Nevada Test Site, Nye County, Nevada. The complex consists of dikes and sills intruded into a partially saturated tuffaceous host rock that has stratigraphic sequences that correlate with those found at Yucca Mountain. The intrusions were emplaced at a depth of several hundred meters below the surface, similar to the depth of the proposed repository. The tuffaceous host rock surrounding the intrusions is hydrothermally altered to varying extents depending on the distance from the intrusions. The Paiute Ridge intrusive complex thus appears to be an ideal natural analogue of THC coupled processes associated with the Yucca Mountain repository. It could provide much needed physical and chemical data for understanding the influence of heat

  20. Informatic search strategies to discover analogues and variants of natural product archetypes.

    Science.gov (United States)

    Johnston, Chad W; Connaty, Alex D; Skinnider, Michael A; Li, Yong; Grunwald, Alyssa; Wyatt, Morgan A; Kerr, Russell G; Magarvey, Nathan A

    2016-03-01

    Natural products are a crucial source of antimicrobial agents, but reliance on low-resolution bioactivity-guided approaches has led to diminishing interest in discovery programmes. Here, we demonstrate that two in-house automated informatic platforms can be used to target classes of biologically active natural products, specifically, peptaibols. We demonstrate that mass spectrometry-based informatic approaches can be used to detect natural products with high sensitivity, identifying desired agents present in complex microbial extracts. Using our specialised software packages, we could elaborate specific branches of chemical space, uncovering new variants of trichopolyn and demonstrating a way forward in mining natural products as a valuable source of potential pharmaceutical agents.

  1. Diosgenone Synthesis, Anti-Malarial Activity and QSAR of Analogues of This Natural Product

    Directory of Open Access Journals (Sweden)

    Fernando Echeverri

    2013-03-01

    Full Text Available Solanum nudum Dunal steroids have been reported as being antimalarial compounds; however, their concentration in plants is low, meaning that the species could be threatened by over-harvesting for this purpose. Swern oxidation was used for hemisynthesis of diosgenone (one of the most active steroidal sapogenin diosgenin compounds. Eighteen structural analogues were prepared; three of them were found to be more active than diosgenone (IC50 27.9 μM vs. 10.1 μM, 2.9 μM and 11.3 μM. The presence of a 4-en-3-one grouping in the A-ring of the compounds seems to be indispensable for antiplasmodial activity; progesterone (having the same functional group in the steroid A-ring has also displayed antiplasmodial activity. Quantitative correlations between molecular structure and bioactivity were thus explored in diosgenone and several derivatives using well-established 3D-QSAR techniques. The models showed that combining electrostatic (70% and steric (30% fields can explain most variance regarding compound activity. Malarial parasitemia in mice became reduced by oral administration of two diosgenone derivatives.

  2. Sinefungin, a Natural Nucleoside Analogue of S-Adenosylmethionine, Inhibits Streptococcus pneumoniae Biofilm Growth

    Directory of Open Access Journals (Sweden)

    Mukesh Kumar Yadav

    2014-01-01

    Full Text Available Pneumococcal colonization and disease is often associated with biofilm formation, in which the bacteria exhibit elevated resistance both to antibiotics and to host defense systems, often resulting in infections that are persistent and difficult to treat. We evaluated the effect of sinefungin, a nucleoside analogue of S-adenosylmethionine, on pneumococcal in vitro biofilm formation and in vivo colonization. Sinefungin is bacteriostatic to pneumococci and significantly decreased biofilm growth and inhibited proliferation and structure of actively growing biofilms but did not alter growth or the matrix structure of established biofilms. Sinefungin significantly reduced pneumococcal colonization in rat middle ear. The quorum sensing molecule (autoinducer-2 production was significantly reduced by 92% in sinefungin treated samples. The luxS, pfs, and speE genes were downregulated in biofilms grown in the presence of sinefungin. This study shows that sinefungin inhibits pneumococcal biofilm growth in vitro and colonization in vivo, decreases AI-2 production, and downregulates luxS, pfs, and speE gene expressions. Therefore, the S-adenosylmethionine (SAM inhibitors could be used as lead compounds for the development of novel antibiofilm agents against pneumococci.

  3. USE OF NATURAL WATERS AS U. S. GEOLOGICAL SURVEY REFERENCE SAMPLES.

    Science.gov (United States)

    Janzer, Victor J.

    1985-01-01

    The U. S. Geological Survey conducts research and collects hydrologic data relating to the Nation's water resources. Seven types of natural matrix reference water samples are prepared for use in the Survey's quality assurance program. These include samples containing major constituents, trace metals, nutrients, herbicides, insecticides, trace metals in a water and suspended-sediment mixture, and precipitation (snowmelt). To prepare these reference samples, natural water is collected in plastic drums and the sediment is allowed to settle. The water is then filtered, selected constituents are added, and if necessary the water is acidified and sterilized by ultraviolet irradiation before bottling in plastic or glass. These reference samples are distributed twice yearly to more than 100 laboratories for chemical analysis. The most probable values for each constituent are determined by evaluating the data submitted by the laboratories using statistical techniques recommended by ASTM.

  4. INTRAVAL phase 2, test case 8, Alligator Rivers Natural Analogue: Modelling of uranium transport in the weathered zone at Koongarra (Australia)

    Energy Technology Data Exchange (ETDEWEB)

    Van de Weerd, H.; Leijnse, A.; Hassanizadeh, S.M.; Richardson-van der Poel, M.A.

    1994-04-01

    The purpose of this study is to test the simulation package METROPOL, developed at RIVM to simulate transport of radionuclides over large time scales. At the Koongarra site secondary uranium mineralization and dispersed uranium is present from the surface down to the base of weathering. Field data are analyzed to choose a modelling approach, to estimate model inputs and to test model results. Field data show that three layers can be distinguished in the Koongarra area: (1) a top layer which is fully weathered, (2) an intermediate layer which is partially weathered (the transition zone) and (3) a lower layer which is unweathered. The groundwater velocities are largest in the transition zone which has been moving downward as the weathering process proceeds. The finite element code METROPOL has been adapted to account for the movement of the transition zone and to describe the dissolution of uranium in the orebody by a non-equilibrium relation. In simulations taking into account the downward movement of the transition zone, the dispersion patterns at all depths are simulated. These simulations result in a pseudo steady state situation. Despite the fact that the model results presented are not fully in agreement with the dispersion patterns, it is expected that the present situation may be obtained by changing some of the model parameters. In this study it was shown that over large timescales geologic processes may have an impact on the transport of radionuclides, and the movement of the transition zone will have an impact on the uranium concentration distribution. The simulation results are influenced by the parameters values, which are difficult to estimate for a period of some million years. The largest uncertainties are associated with the boundary conditions. Continuation of natural analogue studies in the framework of nuclear waste disposal research is highly recommended. 24 figs., 13 tabs., 2 appendices, 39 refs.

  5. BALANOL ANALOGUES

    DEFF Research Database (Denmark)

    1997-01-01

    The present invention relates to a solid phase methodology for the preparation of a combinatorial library of structural analogues of the natural product balanol (ophiocordin, azepinostatin), which is a protein kinase C (PKC) and protein kinase A (PKA) inhibitor. The method comprises solid-phase s...... be immobilised to the polymer support either as the monoallyl ester or as the internal anhydride. The libraries produced by the method are especially suited for high throughput screening of potential drug candidates for the treatment of mammals, especially humans....

  6. Magnesium isotope fractionation by chemical diffusion in natural settings and in laboratory analogues

    Science.gov (United States)

    Chopra, Rahul; Richter, Frank M.; Bruce Watson, E.; Scullard, Christian R.

    2012-07-01

    Laboratory experiments are used to document isotopic fractionation of magnesium by chemical diffusion in a silicate melt and the results compared to the magnesium isotopic composition across contacts between igneous rocks of different composition in natural settings. The natural samples are from transects from felsic to mafic rocks at Vinal Cove in the Vinalhaven Intrusive Complex, Maine and from the Aztec Wash pluton in Nevada. Two laboratory diffusion couples made by juxtaposing melts made from powders of the felsic and mafic compositions sampled at Vinal Cove were annealed at about 1500 °C for 22.5 and 10 h, respectively. The transport of magnesium in the diffusion couples resulted in easily measured magnesium isotopic fractionations at the interface (δ26Mg∼1.5‰). These isotopic fractionations provide a distinctive isotopic “fingerprint” that we use to determine whether chemical gradients in natural settings where melts of different composition were juxtaposed were due to chemical diffusion. The magnesium isotopic fractionation along one profile at Vinal Cove is exactly what one would expect based on the fractionations found in the laboratory experiments. This is an important result in that it shows that the isotope fractionation by chemical diffusion found in highly controlled laboratory experiments can be found in a natural setting. This correspondence implies that chemical diffusion was the dominant process responsible for the transport of magnesium across this particular contact at Vinal Cove. A second Vinal Cove profile has a very similar gradient in magnesium concentration but with significantly less magnesium isotopic fractionation than expected. This suggests that mass transport at this location was only partly by diffusion and that some other mass transport mechanism such as mechanical mixing must have also played a role. The magnesium isotopic composition of samples from Aztec Wash shows no resolvable isotopic fractionation across the contact

  7. A natural analogue for copper waste canisters: The copper-uranium mineralised concretions in the Permian mudrocks of south Devon, United Kingdom

    Energy Technology Data Exchange (ETDEWEB)

    Milodowski, A.E.; Styles, M.T.; Hards, V.L. [Natural Environment Research Council (United Kingdom). British Geological Survey

    2000-08-01

    This report presents the results of a small-scale pilot study of the mineralogy and alteration characteristics of unusual sheet-like native copper occurring together with uraniferous and vanadiferous concretions in mudstones and siltstones of the Permian Littleham Mudstone Formation, at Littleham Cove, south Devon, England. The host mudstones and siltstones are smectitic and have been compacted through deep Mesozoic burial. The occurrence of native copper within these rocks represents a natural analogue for the long-term behaviour of copper canisters, sealed in a compacted clay (bentonite) backfill, that will be used for the deep geological disposal of high-level radioactive waste by the SKB. The study was undertaken by the British Geological Survey (BGS) on behalf of SKB between November 1999 and June 2000. The study was based primarily on archived reference material collected by the BGS during regional geological and mineralogical surveys of the area in the 1970's and 1980's. However, a brief visit was made to Littleham Cove in January 2000 to try to examine the native copper in situ and to collect additional material. Unfortunately, recent landslips and mudflows obscured much of the outcrop, and only one new sample of native copper could be collected. The native copper occurs as thin plates, up to 160 mm in diameter, which occur parallel to bedding in the Permian Littleham Mudstone Formation at Littleham Cove (near Budleigh Salterton) in south Devon. Each plate is made up of composite stacks of individual thin copper sheets each 1-2 mm thick. The copper is very pure (>99.4% Cu) but is accompanied by minor amounts of native silver (also pure - >99%) which occurs as small inclusions within the native copper. Detailed mineralogical and petrological studies of the native copper sheets, using optical petrography, backscattered scanning electron microscopy, X-ray diffraction analysis and electron probe microanalytical techniques, reveal a complex history of

  8. Natural glass analogues to alteration of nuclear waste glass: A review and recommendations for further study

    Energy Technology Data Exchange (ETDEWEB)

    McKenzie, W.F.

    1990-01-01

    The purpose of this report is to review previous work on the weathering of natural glasses; and to make recommendations for further work with respect to studying the alteration of natural glasses as it relates quantifying rates of dissolution. the first task was greatly simplified by the published papers of Jercinovic and Ewing (1987) and Byers, Jercinovic, and Ewing (1987). The second task is obviously the more difficult of the two and the author makes no claim of completeness in this regard. Glasses weather in the natural environment by reacting with aqueous solutions producing a rind of secondary solid phases. It had been proposed by some workers that the thickness of this rind is a function of the age of the glass and thus could be used to estimate glass dissolution rates. However, Jercinovic and Ewing (1987) point out that in general the rind thickness does not correlate with the age of the glass owing to the differences in time of contact with the solution compared to the actual age of the sample. It should be noted that the rate of glass dissolution is also a function of the composition of both the glass and the solution, and the temperature. Quantification of the effects of these parameters (as well as time of contact with the aqueous phase and flow rates) would thus permit a prediction of the consequences of glass-fluid interactions under varying environmental conditions. Defense high- level nuclear waste (DHLW), consisting primarily of liquid and sludge, will be encapsulated by and dispersed in a borosilicate glass before permanent storage in a HLW repository. This glass containing the DHLW serves to dilute the radionuclides and to retard their dispersion into the environment. 318 refs.

  9. Novel peptide chemistry in terrestrial animals: natural luciferin analogues from the bioluminescent earthworm Fridericia heliota.

    Science.gov (United States)

    Dubinnyi, Maxim A; Tsarkova, Aleksandra S; Petushkov, Valentin N; Kaskova, Zinaida M; Rodionova, Natalja S; Kovalchuk, Sergey I; Ziganshin, Rustam H; Baranov, Mikhail S; Mineev, Konstantin S; Yampolsky, Ilia V

    2015-03-02

    We report isolation and structure elucidation of AsLn5, AsLn7, AsLn11 and AsLn12: novel luciferin analogs from the bioluminescent earthworm Fridericia heliota. They were found to be highly unusual modified peptides, comprising either of the two tyrosine-derived chromophores, CompX or CompY and a set of amino acids, including threonine, gamma-aminobutyric acid, homoarginine, and unsymmetrical N,N-dimethylarginine. These natural compounds represent a unique peptide chemistry found in terrestrial animals and rise novel questions concerning their biosynthetic origin. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  10. Science Data Management During Real-Time Geological Lunar Analogue Missions to the Sudbury and Mistastin Lake Impact Structures: Recommendations for Future Ground Data Systems

    Science.gov (United States)

    Mader, M. M.; McCullough, E.; Beauchamp, M.; Clayton, J.; Marion, C. L.; Moores, J.; Pickersgill, A. E.; Preston, L. J.; Shankar, B.; Osinski, G. R.; Ilsr Team

    2012-03-01

    Simulating planetary missions on Earth can help test data management procedures and help identify needs and gaps in current ground data systems. We present lessons learned from three lunar analogue missions funded by the Canadian Space Agency.

  11. Geological background of the estimation of natural stresses in soil body

    Directory of Open Access Journals (Sweden)

    Chernyshev Sergey Nikolaevich

    2015-01-01

    Full Text Available Initial and boundary conditions are always given for solving the problem of calculating the interaction of tunnels and other underground structures with soil and rocks. The same conditions are set for calculating the surface buildings. These initial data for calculation are divided into three groups: 1 the geometrical shape of the layers of rocks (geological structure; 2 the parameters of the strength and compressibility of rocks; 3 compressive stresses in the array. These data all over the world are set with engineering surveys. In engineering surveys there are good methods of determining the source of the data 1 and 2. But there is no available methodology for determining the natural stress state. Therefore, compressive and tensile stresses are usually determined by mathematical modeling. The calculation of the compressive stresses is done on the basis of the following hypotheses: compressive stresses are created by the weight of rocks; they go down in proportion to the density of rocks; the main normal stress is has a vertical direction; normal stress in horizontal direction is smaller. The value of the horizontal stress is was calculated using Poisson’s ratio. This hypothesis of the nineteenth century was used another 50 years ago, when it was not known exactly about the movement of the continents and when compressive stresses in the earth’s crust have not yet been measured. Today a universal application of this hypothesis is not correct. Now the application of this hypothesis in many cases is not correct. In this research paper an attempt is made to specify the area, in which the above hypothesis can be used. This is done on the basis of current scientific evidence. Abroad this way of calculating tunnels and other underground structures and bases of buildings should be done taking into account the real field of natural stresses. The geological characteristics of the location of the axes of stresses in soil body are based on the study of

  12. Flood- and Drought-Related Natural Hazards Activities of the U.S. Geological Survey in New England

    Science.gov (United States)

    Lombard, Pamela J.

    2016-03-23

    The U.S. Geological Survey (USGS) has many ongoing and recent water-related natural hazard activities in New England that can be used to help mitigate the effects of natural hazards in cooperation with other agencies. The themes related to potential hazards and the tools and science to better understand and address them include the following:

  13. The Ministry of Land and Natural Resources is Preparing to Delete the Approval Right for Mineral Resources Geological Prospecting

    Institute of Scientific and Technical Information of China (English)

    2013-01-01

    <正>Yu Haifeng, Deputy Director of Geological Prospecting Department and Executive Deputy Director of the Mineral Prospecting Office under the Ministry of Land and Natural Resources, disclosed at the recently concluded National Prospecting Meeting for 2013 that, the Ministry of Land and Natural Resources is con

  14. Natural Occurring Silks and Their Analogues as Materials for Nerve Conduits.

    Science.gov (United States)

    Radtke, Christine

    2016-10-20

    Spider silk and its synthetic derivatives have a light weight in combination with good strength and elasticity. Their high cytocompatibility and low immunogenicity make them well suited for biomaterial products such as nerve conduits. Silk proteins slowly degrade enzymatically in vivo, thus allowing for an initial therapeutic effect such as in nerve scaffolding to facilitate endogenous repair processes, and then are removed. Silks are biopolymers naturally produced by many species of arthropods including spiders, caterpillars and mites. The silk fibers are secreted by the labial gland of the larvae of some orders of Holometabola (insects with pupa) or the spinnerets of spiders. The majority of studies using silks for biomedical applications use materials from silkworms or spiders, mostly of the genus Nephila clavipes. Silk is one of the most promising biomaterials with effects not only in nerve regeneration, but in a number of regenerative applications. The development of silks for human biomedical applications is of high scientific and clinical interest. Biomaterials in use for biomedical applications have to meet a number of requirements such as biocompatibility and elicitation of no more than a minor inflammatory response, biodegradability in a reasonable time and specific structural properties. Here we present the current status in the field of silk-based conduit development for nerve repair and discuss current advances with regard to potential clinical transfer of an implantable nerve conduit for enhancement of nerve regeneration.

  15. Natural Occurring Silks and Their Analogues as Materials for Nerve Conduits

    Science.gov (United States)

    Radtke, Christine

    2016-01-01

    Spider silk and its synthetic derivatives have a light weight in combination with good strength and elasticity. Their high cytocompatibility and low immunogenicity make them well suited for biomaterial products such as nerve conduits. Silk proteins slowly degrade enzymatically in vivo, thus allowing for an initial therapeutic effect such as in nerve scaffolding to facilitate endogenous repair processes, and then are removed. Silks are biopolymers naturally produced by many species of arthropods including spiders, caterpillars and mites. The silk fibers are secreted by the labial gland of the larvae of some orders of Holometabola (insects with pupa) or the spinnerets of spiders. The majority of studies using silks for biomedical applications use materials from silkworms or spiders, mostly of the genus Nephila clavipes. Silk is one of the most promising biomaterials with effects not only in nerve regeneration, but in a number of regenerative applications. The development of silks for human biomedical applications is of high scientific and clinical interest. Biomaterials in use for biomedical applications have to meet a number of requirements such as biocompatibility and elicitation of no more than a minor inflammatory response, biodegradability in a reasonable time and specific structural properties. Here we present the current status in the field of silk-based conduit development for nerve repair and discuss current advances with regard to potential clinical transfer of an implantable nerve conduit for enhancement of nerve regeneration. PMID:27775616

  16. Natural Occurring Silks and Their Analogues as Materials for Nerve Conduits

    Directory of Open Access Journals (Sweden)

    Christine Radtke

    2016-10-01

    Full Text Available Spider silk and its synthetic derivatives have a light weight in combination with good strength and elasticity. Their high cytocompatibility and low immunogenicity make them well suited for biomaterial products such as nerve conduits. Silk proteins slowly degrade enzymatically in vivo, thus allowing for an initial therapeutic effect such as in nerve scaffolding to facilitate endogenous repair processes, and then are removed. Silks are biopolymers naturally produced by many species of arthropods including spiders, caterpillars and mites. The silk fibers are secreted by the labial gland of the larvae of some orders of Holometabola (insects with pupa or the spinnerets of spiders. The majority of studies using silks for biomedical applications use materials from silkworms or spiders, mostly of the genus Nephila clavipes. Silk is one of the most promising biomaterials with effects not only in nerve regeneration, but in a number of regenerative applications. The development of silks for human biomedical applications is of high scientific and clinical interest. Biomaterials in use for biomedical applications have to meet a number of requirements such as biocompatibility and elicitation of no more than a minor inflammatory response, biodegradability in a reasonable time and specific structural properties. Here we present the current status in the field of silk-based conduit development for nerve repair and discuss current advances with regard to potential clinical transfer of an implantable nerve conduit for enhancement of nerve regeneration.

  17. Redox potential tuning by redox-inactive cations in nature's water oxidizing catalyst and synthetic analogues.

    Science.gov (United States)

    Krewald, Vera; Neese, Frank; Pantazis, Dimitrios A

    2016-04-28

    The redox potential of synthetic oligonuclear transition metal complexes has been shown to correlate with the Lewis acidity of a redox-inactive cation connected to the redox-active transition metals of the cluster via oxo or hydroxo bridges. Such heterometallic clusters are important cofactors in many metalloenzymes, where it is speculated that the redox-inactive constituent ion of the cluster serves to optimize its redox potential for electron transfer or catalysis. A principal example is the oxygen-evolving complex in photosystem II of natural photosynthesis, a Mn4CaO5 cofactor that oxidizes water into dioxygen, protons and electrons. Calcium is critical for catalytic function, but its precise role is not yet established. In analogy to synthetic complexes it has been suggested that Ca(2+) fine-tunes the redox potential of the manganese cluster. Here we evaluate this hypothesis by computing the relative redox potentials of substituted derivatives of the oxygen-evolving complex with the cations Sr(2+), Gd(3+), Cd(2+), Zn(2+), Mg(2+), Sc(3+), Na(+) and Y(3+) for two sequential transitions of its catalytic cycle. The theoretical approach is validated with a series of experimentally well-characterized Mn3AO4 cubane complexes that are structural mimics of the enzymatic cluster. Our results reproduce perfectly the experimentally observed correlation between the redox potential and the Lewis acidities of redox-inactive cations for the synthetic complexes. However, it is conclusively demonstrated that this correlation does not hold for the oxygen evolving complex. In the enzyme the redox potential of the cluster only responds to the charge of the redox-inactive cations and remains otherwise insensitive to their precise identity, precluding redox-tuning of the metal cluster as a primary role for Ca(2+) in biological water oxidation.

  18. The Werkendam natural CO2 accumulation: An analogue for CO2 storage in depleted oil reservoirs

    Science.gov (United States)

    Bertier, Pieter; Busch, Andreas; Hangx, Suzanne; Kampman, Niko; Nover, Georg; Stanjek, Helge; Weniger, Philipp

    2015-04-01

    The Werkendam natural CO2 accumulation is hosted in the Röt (Early Triassic) sandstone of the West Netherlands Basin, at a depth of 2.8 km, about 20 km south-east of Rotterdam (NL). This reservoir, in a fault-bound structure, was oil-filled prior to charging with magmatic CO2 in the early Cretaceous. It therefore offers a unique opportunity to study long-term CO2-water-rock interactions in the presence of oil. This contribution will present the results of a detailed mineralogical and geochemical characterisation of core sections from the Werkendam CO2 reservoir and an adjacent, stratigraphically equivalent aquifer. X-ray diffraction combined with X-ray fluorescence spectrometry revealed that the reservoir samples contain substantially more feldspar and more barite and siderite than those from the aquifer, while the latter have higher hematite contents. These differences are attributed to the effects hydrocarbons and related fluids on diagenesis in the closed system of the CO2 reservoir versus the open-system of the aquifer. Petrophysical analyses yielded overall higher and more anisotropic permeability for the reservoir samples, while the porosity is overall not significantly different from that of their aquifer equivalents. The differences are most pronounced in coarse-grained sandstones. These have low anhydrite contents and contain traces of calcite, while all other analyzed samples contain abundant anhydrite, dolomite/ankerite and siderite, but no calcite. Detailed petrography revealed mm-sized zones of excessive primary porosity. These are attributed to CO2-induced dissolution of precompactional, grain-replacive anhydrite cement. Diagenetic dolomite/ankerite crystals are covered by anhedral, epitaxial ankerite, separated from the crystals by bitumen coats. Since these carbonates were oil-wet before CO2-charging, the overgrowths are interpreted to have grown after CO2-charging. Their anhedral habit suggests growth in a 2-phase water-CO2 system. Isotopic

  19. Synthesis of Tonghaosu Analogues

    Institute of Scientific and Technical Information of China (English)

    SUN Hai; LIN Yingjie; WU Yulin; WU Yikang

    2009-01-01

    Several new analogues of natural antifeedant tonghaosu were synthesized via m-CPBA (m-chloroperoxybenzoic acid) oxidation of corresponding 3-(a-furyl)propanols, Luche reduction of the resulting enone, epoxidation, acid-mediated spiroketalization, and radical mediated dehydration.

  20. Improving surface stability of elevated spoil landforms using natural landform analogy and geological information

    Science.gov (United States)

    Emmerton, Bevan; Burgess, Jon; Esterle, Joan; Erskine, Peter; Baumgartl, Thomas

    2017-04-01

    Large-scale open cut mining in the Bowen Basin, Queensland, Australia has undergone an evolutionary process over the period of a few decades, transitioning from shallow mining depths, limited spoil elevation and pasture based rehabilitation to increased mining depths, escalating pre-stripping, elevated mesa-like landforms and native woody species rehabilitation. As a consequence of this development, the stabilisation of recent constructed landforms has to be assured through means other than the establishment of vegetative cover. Recent developments are the specific selection and partitioning of resilient fragmental spoil types for the construction of final landform surface. They can also be used as cladding resources for stabilizing steep erosive batters and this has been identified as a practical methodology that has the potential to significantly improve rehabilitation outcomes. Examples of improvements are an increase of the surface rock cover, roughness and infiltration and reducing inherent erodibility and runoff and velocity of surface flow. However, a thorough understanding of the properties and behavior of individual spoil materials disturbed during mining is required. Relevant information from published literature on the geological origins, lithology and weathering characteristics of individual strata within the Bowen Basin Coal Measures located in Queensland, Australia (and younger overlying weathered strata) has been studied, and related both to natural landforms and to the surface stability of major strata types when disturbed by mining. The resulting spoil classification developed from this study is based primarily on inherent geological characteristics and weathering behaviour of identifiable lithologic components, and as such describes the expected fragmental resilience likely within disturbed materials at Bowen Basin coal mines. The proposed classification system allows the allocation of spoil types to use categories which have application in pre

  1. An overview of the surface and near-surface geology, geomorphology and natural resources of Kuwait

    Science.gov (United States)

    Al-Sulaimi, J.; Mukhopadhyay, A.

    2000-06-01

    The surface and near-surface geology, geomorphology and natural resources of Kuwait have been reviewed based on the published work. The stratigraphy and structure of the near-surface sediments of Kuwait have been mainly controlled by the Tertiary tectonic activity of the Arabian Shield. The shield started separating from the African mainland by the close of the Eocene and drifted northeastward towards the Asian plate, giving rise to the folding and thrusting of the Zagros Mountains of Iran. The tectonic activity superimposed a northwest-southeast trend over an earlier north-south structural trend, and gave rise to parallel ridges and valleys trending northwest-southeast through differential erosion. It has been possible to identify 15 geomorphic zones and 11 morphostructures from analysis of the surface features of Kuwait. Seven of these morphostructures can be attributed to tectonic processes and two to fluvial processes. It has not been possible, however, to explain satisfactorily the origin of the Jal Az-Zor escarpment or the Ad-Dalmaniyah cliff. The whole of Kuwait can be divided into seven drainage zones. Of these, the internal drainage systems of the Ar-Raudhatain-Umm Al-Aish drainage system and the Ad-Dibdibba drainage system are hydrogeologically most important. The clastic deposits of Kuwait Group sediments, often affected by low-temperature carbonate (calcite and dolomite) and sulfate (gypsum) precipitation, form the surface rock of Kuwait. These are covered by recent aeolian and residual deposits; playa deposits in the enclosed basins; and near the coast, oolitic sediments, beach sands and sabkha deposits. The surface and near-surface deposits of Kuwait contain important reserves of construction sand and gravel as well as the only naturally occurring freshwater reserves of the country. An understanding of the nature of these surface deposits is required for the management of environmental issues like sand encroachment, land-use planning, and soil and

  2. A natural analogue for copper waste canisters: The copper-uranium mineralised concretions in the Permian mudrocks of south Devon, United Kingdom

    Energy Technology Data Exchange (ETDEWEB)

    Milodowski, A.E.; Styles, M.T.; Hards, V.L. [Natural Environment Research Council (United Kingdom). British Geological Survey

    2000-08-01

    This report presents the results of a small-scale pilot study of the mineralogy and alteration characteristics of unusual sheet-like native copper occurring together with uraniferous and vanadiferous concretions in mudstones and siltstones of the Permian Littleham Mudstone Formation, at Littleham Cove, south Devon, England. The host mudstones and siltstones are smectitic and have been compacted through deep Mesozoic burial. The occurrence of native copper within these rocks represents a natural analogue for the long-term behaviour of copper canisters, sealed in a compacted clay (bentonite) backfill, that will be used for the deep geological disposal of high-level radioactive waste by the SKB. The study was undertaken by the British Geological Survey (BGS) on behalf of SKB between November 1999 and June 2000. The study was based primarily on archived reference material collected by the BGS during regional geological and mineralogical surveys of the area in the 1970's and 1980's. However, a brief visit was made to Littleham Cove in January 2000 to try to examine the native copper in situ and to collect additional material. Unfortunately, recent landslips and mudflows obscured much of the outcrop, and only one new sample of native copper could be collected. The native copper occurs as thin plates, up to 160 mm in diameter, which occur parallel to bedding in the Permian Littleham Mudstone Formation at Littleham Cove (near Budleigh Salterton) in south Devon. Each plate is made up of composite stacks of individual thin copper sheets each 1-2 mm thick. The copper is very pure (>99.4% Cu) but is accompanied by minor amounts of native silver (also pure - >99%) which occurs as small inclusions within the native copper. Detailed mineralogical and petrological studies of the native copper sheets, using optical petrography, backscattered scanning electron microscopy, X-ray diffraction analysis and electron probe microanalytical techniques, reveal a complex history of

  3. Global profiling and rapid matching of natural products using diagnostic product ion network and in silico analogue database: Gastrodia elata as a case study.

    Science.gov (United States)

    Lai, Chang-Jiang-Sheng; Zha, Liangping; Liu, Da-Hui; Kang, Liping; Ma, Xiaojing; Zhan, Zhi-Lai; Nan, Tie-Gui; Yang, Jian; Li, Fajie; Yuan, Yuan; Huang, Lu-Qi

    2016-07-22

    Rapid discovery of novel compounds of a traditional herbal medicine is of vital significance for pharmaceutical industry and plant metabolic pathway analysis. However, discovery of unknown or trace natural products is an ongoing challenge. This study presents a universal targeted data-independent acquisition and mining strategy to globally profile and effectively match novel natural product analogues from an herbal extract. The famous medical plant Gastrodia elata was selected as an example. This strategy consists of three steps: (i) acquisition of accurate parent and adduct ions (PAIs) and the product ions data of all eluting compounds by untargeted full-scan MS(E) mode; (ii) rapid compound screening using diagnostic product ions (DPIs) network and in silico analogue database with SUMPRODUCT function to find novel candidates; and (iii) identification and isomerism discrimination of multiple types of compounds using ClogP and ions fragment behavior analyses. Using above data mining methods, a total of 152 compounds were characterized, and 70 were discovered for the first time, including series of phospholipids and novel gastroxyl derivatives. Furthermore, a number of gastronucleosides and phase II metabolites of gastrodin and parishins were discovered, including glutathionylated, cysteinylglycinated and cysteinated compounds, and phosphatidylserine analogues. This study extended the application of classical DPIs filter strategy and developed a structure-based screening approach with the potential for significant increase of efficiency for discovery and identification of trace novel natural products. Copyright © 2016 Elsevier B.V. All rights reserved.

  4. Coalbed natural gas exploration, drilling activities, and geologic test results, 2007-2010

    Science.gov (United States)

    Clark, Arthur C.

    2014-01-01

    The U.S. Geological Survey, in partnership with the U.S. Bureau of Land Management, the North Slope Borough, and the Arctic Slope Regional Corporation conducted a four-year study designed to identify, define, and delineate a shallow coalbed natural gas (CBNG) resource with the potential to provide locally produced, affordable power to the community of Wainwright, Alaska. From 2007 through 2010, drilling and testing activities conducted at three sites in or near Wainwright, identified and evaluated an approximately 7.5-ft-thick, laterally continuous coalbed that contained significant quantities of CBNG. This coalbed, subsequently named the Wainwright coalbed, was penetrated at depths ranging from 1,167 ft to 1,300 ft below land surface. Core samples were collected from the Wainwright coalbed at all three drill locations and desorbed-gas measurements were taken from seventeen 1-ft-thick sections of the core. These measurements indicate that the Wainwright coalbed contains enough CBNG to serve as a long-term energy supply for the community. Although attempts to produce viable quantities of CBNG from the Wainwright coalbed proved unsuccessful, it seems likely that with proper well-field design and by utilizing currently available drilling and reservoir stimulation techniques, this CBNG resource could be developed as a long-term economically viable energy source for Wainwright.

  5. Comments on Potential Geologic and Seismic Hazards Affecting Proposed Liquefied Natural Gas Site in Santa Monica Bay, California

    Science.gov (United States)

    Ross, Stephanie L.; Lee, Homa J.; Parsons, Tom E.; Beyer, Larry A.; Boore, David M.; Conrad, James E.; Edwards, Brian D.; Fisher, Michael A.; Frankel, Arthur D.; Geist, Eric L.; Hudnut, Kenneth W.; Hough, Susan E.; Kayen, Robert E.; Lorenson, T.D.; Luco, Nicolas; McCrory, Patricia A.; McGann, Mary; Nathenson, Manuel; Nolan, Michael; Petersen, Mark D.; Ponti, Daniel J.; Powell, Charles L.; Ryan, Holly F.; Tinsley, John C.; Wills, Chris J.; Wong, Florence L.; Xu, Jingping

    2008-01-01

    In a letter to the U.S. Geological Survey (USGS) dated March 25, 2008, Representative Jane Harman (California 36th district) requested advice on geologic hazards that should be considered in the review of a proposed liquefied natural gas (LNG) facility off the California coast in Santa Monica Bay. In 2004, the USGS responded to a similar request from Representative Lois Capps, regarding two proposed LNG facilities offshore Ventura County, Calif., with a report summarizing potential geologic and seismic hazards (Ross and others, 2004). The proposed LNG Deepwater Port (DWP) facility includes single point moorings (SPMs) and 35 miles of underwater pipelines. The DWP submersible buoys, manifolds, and risers would be situated on the floor of the southern Santa Monica Basin, in 3,000 feet of water, about 23 miles offshore of the Palos Verdes Peninsula. Twin 24-inch diameter pipelines would extend northeastward from the buoys across the basin floor, up the basin slope and across the continental shelf, skirting north around the Santa Monica submarine canyon. Figure 1 provides locations of the project and geologic features. Acronyms are defined in table 1. This facility is being proposed in a region of known geologic hazards that arise from both the potential for strong earthquakes and geologic processes related to sediment transport and accumulation in the offshore environment. The probability of a damaging earthquake (considered here as magnitude 6.5 or greater) in the next 30 years within about 30 miles (50 km) of the proposed pipeline ranges from 16% at the pipeline's offshore end to 48% where it nears land (Petersen, 2008). Earthquakes of this magnitude are capable of producing strong shaking, surface fault offsets, liquefaction phenomena, landslides, underwater turbidity currents and debris flow avalanches, and tsunamis. As part of the DWP license application for the Woodside Natural Gas proposal in Santa Monica Bay (known as the OceanWay Secure Energy Project), Fugro

  6. A novel geotechnical/geostatistical approach for exploration and production of natural gas from multiple geologic strata, Phase 1. Volume 2, Geology and engineering

    Energy Technology Data Exchange (ETDEWEB)

    Overbey, W.K. Jr.; Reeves, T.K.; Salamy, S.P.; Locke, C.D.; Johnson, H.R.; Brunk, R.; Hawkins, L. [BDM Engineering Services Co., Morgantown, WV (United States)

    1991-05-01

    This research program has been designed to develop and verify a unique geostatistical approach for finding natural gas resources. The project has been conducted by Beckley College, Inc., and BDM Engineering Services Company (BDMESC) under contract to the US Department of Energy (DOE), Morgantown Energy Technology Center (METC). This section, Volume II, contains a detailed discussion of the methodology used and the geological and production information collected and analyzed for this study. A companion document, Volume 1, provides an overview of the program, technique and results of the study. In combination, Volumes I and II cover the completion of the research undertaken under Phase I of this DOE project, which included the identification of five high-potential sites for natural gas production on the Eccles Quadrangle, Raleigh County, West Virginia. Each of these sites was selected for its excellent potential for gas production from both relatively shallow coalbeds and the deeper, conventional reservoir formations.

  7. A novel geotechnical/geostatistical approach for exploration and production of natural gas from multiple geologic strata, Phase 1. Volume 2, Geology and engineering

    Energy Technology Data Exchange (ETDEWEB)

    Overbey, W.K. Jr.; Reeves, T.K.; Salamy, S.P.; Locke, C.D.; Johnson, H.R.; Brunk, R.; Hawkins, L. [BDM Engineering Services Co., Morgantown, WV (United States)

    1991-05-01

    This research program has been designed to develop and verify a unique geostatistical approach for finding natural gas resources. The project has been conducted by Beckley College, Inc., and BDM Engineering Services Company (BDMESC) under contract to the US Department of Energy (DOE), Morgantown Energy Technology Center (METC). This section, Volume II, contains a detailed discussion of the methodology used and the geological and production information collected and analyzed for this study. A companion document, Volume 1, provides an overview of the program, technique and results of the study. In combination, Volumes I and II cover the completion of the research undertaken under Phase I of this DOE project, which included the identification of five high-potential sites for natural gas production on the Eccles Quadrangle, Raleigh County, West Virginia. Each of these sites was selected for its excellent potential for gas production from both relatively shallow coalbeds and the deeper, conventional reservoir formations.

  8. An analogue peptide from the Cancer/Testis antigen PASD1 induces CD8+ T cell responses against naturally processed peptide.

    Science.gov (United States)

    Hardwick, Nicola; Buchan, Sarah; Ingram, Wendy; Khan, Ghazala; Vittes, Gisella; Rice, Jason; Pulford, Karen; Mufti, Ghulam; Stevenson, Freda; Guinn, Barbara-ann

    2013-01-01

    We have previously identified the novel Cancer/Testis antigen PASD1 by immunoscreening a testis library with pooled acute myeloid leukemia (AML) patient sera. To develop a cytotoxic T lymphocyte (CTL)-inducing vaccine, we have now investigated the carboxy-terminal region, known to contain serological determinants, for MHC class I (HLA-A⋆0201)-binding peptides. Algorithm-selected natural peptides failed to show detectable HLA-A⋆0201 binding in T2 assays. However, anchor-modified analogue peptides showed enhanced binding, with decreased off-rates. Analogue peptide-loaded antigen-presenting cells (APCs) induced IFN-γ production by T cells from normal donors and patients. In addition, peptide-specific T cells could be expanded from cancer patients by stimulation with the PASD1 analogue peptide Pa14. For clinical application, a DNA fusion gene vaccine encoding Pa14 was designed and tested in "humanized" mice. Splenocytes from vaccinated mice showed in vitro cytotoxicity against tumour cells, either exogenously loaded with the corresponding wild-type peptide (Pw8) or expressing endogenously processed PASD1 protein. We show for the first time that a DNA vaccine encoding an altered PASD1 epitope can induce CTLs to target the natural peptide expressed by human tumour cells.

  9. Natural analogs in the petroleum industry

    Energy Technology Data Exchange (ETDEWEB)

    Wood, J.R. [Michigan Technological Univ., Houghton, MI (United States)

    1995-09-01

    This article describes the use of natural analogues in petroleum exploration and includes numerous geologic model descriptions which have historically been used in the prediction of geometries and location of oil and gas accumulations. These geologic models have been passed down to and used by succeeding generations of petroleum geologists. Some examples of these geologic models include the Allan fault-plane model, porosity prediction, basin modelling, prediction of basin compartmentalization, and diagenesis.

  10. Lessons from Natural CO2 Leakage Analogue Site Studies and their Application to Secure CO2 Storage and Monitoring

    Science.gov (United States)

    Han, W.; McPherson, B. J.; Kim, K.; Chae, G.; Yum, B.

    2011-12-01

    At CO2 injection sites, CO2 leakage from the storage formation could be catastrophic. CO2 is a highly compressible fluid, typically injected at high pressure and temperature conditions. If this compressed CO2 reaches highly permeable conduits such as faults and fractures, CO2 could leak unabated to other formations (e.g. fresh water aquifers) and/or to the surface. Assuming a fast-flow path to the surface, CO2 escaping from the storage formation instantaneously reaches the surface while experiencing adiabatic expansion, which results in Joule-Thomson cooling. The addressed eruptive mechanisms are analogues to natural CO2 eruption mechanisms, which are found in CO2-driven cold-water geysers around the world. A notable example of a CO2-driven cold-water geyser is the Crystal Geyser in central Utah. The fluid mechanics of this regularly erupting geyser was investigated by instrumenting its conduit with pressure, temperature, pH, EC, and dissolved oxygen sensors, measuring every 1 minute during and between eruptions. Results of these measurements suggest that the time-scale of a single-eruption cycle is composed of four successive eruption types with two recharge periods ranging from 30 to 40 hours. Current eruption patterns exhibit a bimodal distribution although previous measurements and anecdotal evidence suggests that this pattern was different prior to recent seismic activity. This cold geyser's eruptions are regular and predictable, and reflect pressure, temperature, EC, pH, and dissolved oxygen changes resulting from Joule-Thomson cooling, endothermic CO2 exsolution, and exothermic CO2 dissolution. Specifically, the perturbation of pressure and temperature data observed at the Crystal Geyser suggested the possibility of using temperature sensing technology within the observation well at the engineered CO2 sequestration site. With the lessons learned from the Crystal Geyser studies, we established the theoretical framework of temperature changes caused by CO2

  11. INTRAVAL phase 2, test case 8. Alligator Rivers Natural Analogue. Modelling of uranium transport in the weathered zone at Koongarra, Australia

    Energy Technology Data Exchange (ETDEWEB)

    Hassanizadeh, S.M.; Van de Weerd, H.; Richardson-Van der Poel, M.A. [National Inst. of Public Health and Environmental Protection RIVM, Bilthoven (Netherlands)

    1993-01-01

    Preliminary results of modelling of the dispersion of uranium in the weathered and transition zones are given. In the course of the Alligator Rivers Analogue Project (ARAP) more insight was gained about the formation of the dispersion fan and about the hydrology at Koongarra. The here applied transport modelling strategy takes into account those results. First, a general explanation of Natural Analogue is given, next to a brief description of the ARAP test case, carried out within the INTRAVAL phase 2. INTRAVAL is an international project concerned with the use of mathematical models for predicting the potential transport of radioactive solutes in the geosphere. Following is the analysis of chemical data, necessary for the choice of the modelling approach, for estimation of model inputs and for testing model results. Subsequently, the modelling strategy is expounded and a description is given of METROPOL, the transport code, used for modelling. 11 figs., 2 tabs., 1 appendix, 17 refs.

  12. Gamma-ray characterization of uranium-series nuclides and its application to the study of the Pena Blanca natural analogue site, Chihuahua, Mexico

    Science.gov (United States)

    Wong, Virgina

    Two natural analogue sites located in the Pena Blanca Uranium District, Chihuahua, Mexico were characterized for radionuclide mobility. Analogue I is used to assess the long-term behavior of uranium-series nuclides in a host rock and geochemical environment that is similar to the proposed high-level waste repository at Yucca Mountain, Nevada. Analogue II represents a former dump site to assess short-term radionuclide mobility. Gamma-ray spectroscopy analysis was used to measure radioactivity of the U-series nuclides. Samples analyzed from Analogue I consist of: (1) fracture-infillings associated with different alteration assemblages collected within and outside the breccia pipe from various levels of the deposit and (2) fracture-infillings collected along an east-west trending fracture which intersects the breccia pipe and extends into the host rock. Alteration mineralogy, established via X-ray diffraction analysis, consists of pure kaolinite, a mixture of Fe-oxyhydroxide (goethite, hematite) With inclusions of jarosite and alunite, and carbonates. Results from activity ratios of 230Th/238U versus 226Ra/230Th indicate that majority of the Fe-oxyhydroxides from the breccia zone show a slight disequilibrium with respect to Ra enrichment and U depletion. This observation is modeled as requiring a multiple-event history of U mobility. An amorphous Fe sample distal to the breccia zone shows similar behavior but to a greater extent. This extreme behavior is ascribed to initially low U content and greater late-stage U removal. Two Fe-oxyhydroxide samples from Within the breccia pipe also display multiple-event stages but exhibit both Ra and U leaching. This behavior is shared by Fe-oxyhydroxide samples collected inside and peripheral to the breccia zone from the east-west trending fracture. Finally, three samples, two Fe phase samples outside the breccia zone and a kaolinite inside the breccia zone, show Ra and U enrichment. Also, a distal Fe-oxyhydroxide sample from the

  13. Proteome analysis demonstrates profound alterations in human dendritic cell nature by TX527, an analogue of vitamin D

    DEFF Research Database (Denmark)

    Ferreira, G. B.; van Etten, E.; Lage, K.

    2009-01-01

    Structural analogues of vitamin D have been put forward as therapeutic agents able to exploit the immunomodulatory effects of vitamin D, without its undesired calcemic side effects. We have demonstrated that TX527 affects dendritic cell (DC) maturation in vitro, resulting in the generation of a t...

  14. Application of Fluid Inclusions in the Study of Natural Gas Geology in Ordos Basin

    Institute of Scientific and Technical Information of China (English)

    FAN Ai-ping; YANG Ren-chao; FENG Qiao; LIU Yi-qun; HAN Zuo-zhen

    2006-01-01

    The new recently demonstrated reserves of oil and gas in the Ordos basin are found at the top of petroliferous basins in China. Gas pools discovered in recent years in the Permian system have become the main natural gas resource in the basin. Therefore, synthetic research on fluid inclusions should be done in order to ascertain the pool-forming stage, the maturity of organic matters and the properties of Paleo-fluids. The main types of fluid inclusions in the Permian system in the basin include brine inclusions, carbon dioxide inclusions and organic inclusions. Homogenization temperatures (HT) of brine inclusions can be divided into four intervals: 66-83 ℃, 86-108 ℃, 112-138 ℃ and 142-153 ℃. The fluid inclusions in the interval of 112-138 ℃ are much more than that of other intervals, indicating that the second stage of hydrocarbon migration associated with the third temperature interval is the most important stage of gas pool formations. The fluid inclusion has extensive applications in the study of gas geology, not only in ascertaining the formation stage of gas pools, but also in estimating the maturity of organic matter and restoring Paleo-fluids. The result of testing the HT of brine inclusions shows that there are two stages of gas pool formations in the Permian system occurring ±150 Ma and ±100 Ma. The maturity of organic matter is moderate to high, a conclusion based on the color of fluid inclusions (radiated by fluorescence). The high salinity of Paleo-fluids of the NaCl-H2O and CaCl2-H2O systems shows good preservation conditions of the Paleo-fluids. Two stages of reservoir filling, high maturity of organic matter and good preservation conditions are factors favorable for the formation and preservation of large-scale gas pools in the Permian system in the Ordos basin.

  15. Occurrence of Fe-Mg-rich smectites and corrensite in the Morron de Mateo bentonite deposit (Cabo de Gata region, Spain): A natural analogue of the bentonite barrier in a radwaste repository

    Energy Technology Data Exchange (ETDEWEB)

    Pelayo, M., E-mail: m.pelayo@ciemat.es [Departamento de Medio Ambiente, CIEMAT, Avda. Complutense 22, 28040 Madrid (Spain); Garcia-Romero, E. [Departamento de Cristalografia y Mineralogia, Facultad C.C. Geologicas, UCM, 28040 Madrid (Spain); Labajo, M.A.; Perez del Villar, L. [Departamento de Medio Ambiente, CIEMAT, Avda. Complutense 22, 28040 Madrid (Spain)

    2011-07-15

    Highlights: > A hydrothermal process transformed Fe-Mg smectites into corrensite. > This transformation was favoured by the intrusion of the Morron de Mateo dome. > The intrusion caused a temperature increased and a supply of Fe-Mg rich solutions. > The system can be a good natural analogue of bentonite barrier in a radwaste disposal. > Experimental studies of stability of bentonite are in agreement with the results. - Abstract: The Morron de Mateo bentonite deposit is being studied as a natural analogue of the thermal and geochemical effects on a bentonite barrier in a deep geological repository of high level radioactive wastes. This bentonite deposit and its host rocks were intruded by a rhyodacitic volcanic dome that induced a hydrothermal metasomatic process affecting the biocalcarenite beds close to the dome. In this work, the mineralogical and chemical features of the clay minerals of the hydrothermally altered pyroclastic (white tuffs) and epiclastic rocks (mass flow), located in the NE sector of the Morron de Mateo deposit are described. White tuffs have a high content of phyllosilicates, mainly composed of dioctahedral smectites, while mass flow have a higher proportion of inherited minerals, the neoformed phyllosilicates are dioctahedral smectites and an interlayer chlorite/smectite mineral of corrensite type. The chemical composition of smectites reflects the different nature of the parent rocks, in such a way that smectites from white tuffs have a quite homogeneous chemical composition and their structural formulae correspond to montmorillonite type, while smectites from mass flow show more chemical variability, higher Fe and Mg contents and a mean structural formulae corresponding to Fe-Mg-rich beidellite and/or to an intermediate smectite member between beidellite and saponite. In addition, chemical composition and textural features of corrensite-like clay minerals in relation to Fe-Mg-rich smectites in the samples have also been studied, suggesting

  16. Behavioural activity of angiotensin II (3-7)4Phe--analogue of natural fragment 3-7 of angiotensin II.

    Science.gov (United States)

    Hoły, Z; Wiśniewski, K; Jachimowicz, A; Braszko, J

    1996-01-01

    A study was made of the influence of pentapeptide 3-7 angiotensin II [AII(3-7)], its analogue 3-7(4)Phe [AII(3-7)4Phe] and angiotensin II (AII) on the behaviour of adult male rats. The motility, stereotypy, spatial performance, learning of conditioned and passive avoidance responses allowing to avoid aversive stimulation were estimated. Examined peptides at the dose 1 nmol injected intracerebroventricularly 15 min before the experiment did not produce specific changes in psychomotor activity in the "open field" test and in retention of the spatial task in the Morris water maze. The rate of acquisition of conditioned avoidance responses was stimulated by AII(3-7)4Phe, AII(3-7) and AII administration. In the passive avoidance situation AII improved retention of the responses whereas analogue AII(3-7)4Phe and fragment 3-7 caused similar though less pronounced effect. All the peptides applied immediately before the experiment intensified stereotypy, a behaviour evoked by of apomorphine-1 mg/kg and amphetamine-7.5 mg/kg intraperitonealy injection. These results show similar psychotropic activity of analogue AII(3-7)4Phe, comparable with the activity of natural fragment 3-7 of angiotensin II.

  17. Geology and hydrostratigraphy of Guadalupe River State Park and Honey Creek State Natural Area, Kendall and Comal Counties, Texas

    Science.gov (United States)

    Clark, Allan K.; Blome, Charles D.; Morris, Robert R.

    2014-01-01

    Hydrogeologic mapping and descriptions of the lithostratigraphy and hydrostratigraphy of Guadalupe River State Park and Honey Creek State Natural Area, Kendall and Comal Counties, Texas, are presented in this first detailed 1:24,000 geologic map, along with proposed names and descriptions of the hydrostratigraphic units in the study area. Variations in the amount and type of porosity of the lithostratigraphic unit, which vary depending on the depositional environment, lithology, structural history and diagenesis support the resulting hydrostratigraphy proposed herein.

  18. Workshop on the role of natural analogs in geologic disposal of high-level nuclear waste: Proceedings

    Energy Technology Data Exchange (ETDEWEB)

    Kovach, L.A. [ed.] [Nuclear Regulatory Commission, Washington, DC (United States). Div. of Regulatory Applications; Murphy, W.M. [ed.] [Southwest Research Inst., San Antonio, TX (United States). Center for Nuclear Waste Regulatory Analyses

    1995-09-01

    A Workshop on the Role of Natural Analogs in Geologic Disposal of High-Level Nuclear Waste was held in San Antonio, Texas on July 22--25, 1991. The proceedings comprise seventeen papers submitted by participants at the workshop. A series of papers addresses the relation of natural analog studies to the regulation, performance assessment, and licensing of a geologic repository. Applications of reasoning by analogy are illustrated in papers on the role of natural analogs in studies of earthquakes, petroleum, and mineral exploration. A summary is provided of a recently completed, internationally coordinated natural analog study at Pocos de Caldas, Brazil. Papers also cover problems and applications of natural analog studies in four technical areas of nuclear waste management-. waste form and waste package, near-field processes and environment, far-field processes and environment, and volcanism and tectonics. Summaries of working group deliberations in these four technical areas provide reviews and proposals for natural analog applications. Individual papers have been cataloged separately.

  19. Natural arsenic and uranium accumulation and remobilization in different geological environments

    Energy Technology Data Exchange (ETDEWEB)

    Banning, Andre Wilhelm

    2012-03-05

    Despite the fact that both As and U represent geogenic trace elements potentially toxic to humans, little information is available on the development of their enrichments in German sediments and their potential impact on groundwater quality, let alone a systematic overview of the country's natural occurrences. This work aims at characterizing accumulation processes in aquifers actually or potentially affected by elevated concentrations of As and/or U, and their timings in geological history. The five selected study areas provide different geological and stratigraphical backgrounds. Identification of As and U sources, and structural derivation of their environmental reservoirs as well as remobilization mechanisms potentially resulting in trace element release to groundwater were assessed. Drinking water supply in Franconia/Northern Bavaria is dependent on groundwater extraction from terrestrial Upper Triassic sandstones where elevated concentrations of geogenic U and As exceeding German drinking water limitations were identified. Characterization of aquifer material in terms of geochemical and mineralogical composition, trace elements distribution on a microscale and their mineralogical fractionation and mobilization behaviour showed that uraniferous francolite/hematite inclusions within the aquifer sandstones (''active arkoses'') represent important sources for U and As in the study area. Francolite exhibits biologically, structurally and radiation-enhanced solubility; loss of both U and As during weathering was documented. Jurassic shallow marine Fe ores from the Upper Rhine Graben exhibit significant bulk As hosted in mainly goethite ooids slowly formed in times of condensed sedimentation. The study indicates that As accumulation was favoured over other potential contaminants, esp. heavy metals. Conditions for As accumulation varied during deposition, visible on a macro- (outcrop) as well as on a microscale (single Fe ooid). However, the

  20. ENVIRONMENTAL GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2004-01-01

    <正>20040834 Chen Yijiu (Geological Exploration Bureau of Guangdong Province, Guangzhou, Guangdong) Discussion on Natural Chornic Irradiation Environment and Pertinent Problems in Guangdong Province, China (Guangdong Geology, ISSN 1001 - 8670, CN44-1201/P, 18(1), 2003, p. 30-41, 7 tables, 1 ref. , with English abstract) Keywords: radioactivity radiation environmental pollution Guangdong Province

  1. A novel geotechnical/geostatistical approach for exploration and production of natural gas from multiple geologic strata, Phase 1

    Energy Technology Data Exchange (ETDEWEB)

    Overbey, W.K. Jr.; Reeves, T.K.; Salamy, S.P.; Locke, C.D.; Johnson, H.R.; Brunk, R.; Hawkins, L. (BDM Engineering Services Co., Morgantown, WV (United States))

    1991-05-01

    This research program has been designed to develop and verify a unique geostatistical approach for finding natural gas resources. The research has been conducted by Beckley College, Inc. (Beckley) and BDM Engineering Services Company (BDMESC) under contract to the US Department of Energy (DOE), Morgantown Energy Technology Center. Phase 1 of the project consisted of compiling and analyzing relevant geological and gas production information in selected areas of Raleigh County, West Virginia, ultimately narrowed to the Eccles, West Virginia, 7 {1/2} minute Quadrangle. The Phase 1 analysis identified key parameters contributing to the accumulation and production of natural gas in Raleigh County, developed analog models relating geological factors to gas production, and identified specific sites to test and verify the analysis methodologies by drilling. Based on the Phase 1 analysis, five sites have been identified with high potential for economic gas production. Phase 2 will consist of drilling, completing, and producing one or more wells at the sites identified in the Phase 1 analyses. The initial well is schedules to the drilled in April 1991. This report summarizes the results of the Phase 1 investigations. For clarity, the report has been prepared in two volumes. Volume 1 presents the Phase 1 overview; Volume 2 contains the detailed geological and production information collected and analyzed for this study.

  2. Geochemical modelling of the weathering zone of the 'Mina Fe' U deposit (Spain): A natural analogue for nuclear spent fuel alteration and stability processes in radwaste disposal

    Energy Technology Data Exchange (ETDEWEB)

    Arcos, D. [AMPHOS XXI Consulting S.L., Passeig de Rubi, 29-31, 08197 Valldoreix, Barcelona (Spain)], E-mail: david.arcos@amphos21.com; Perez del Villar, L. [CIEMAT, Dpto.de Medio Ambiente, Avda, Complutense 22, 28040 Madrid (Spain); Bruno, J.; Domenech, C. [AMPHOS XXI Consulting S.L., Passeig de Rubi, 29-31, 08197 Valldoreix, Barcelona (Spain)

    2008-04-15

    The 'Mina Fe' U deposit (Salamanca, Spain) has been studied in the context of Enresa's programme for U-mine sites restoration and also as a natural analogue for processes in high-level nuclear waste (HLNW) geological disposal. The investigations encompassed an array of geoscience disciplines, such as structural geology, mineralogy, hydrogeology and elemental and isotopic geochemistry and hydrogeochemistry of the site. Based on the obtained results, a conceptual mineralogical and geochemical model was performed integrating the main geochemical processes occurring at the site: the interaction between oxidised and slightly acidic water with pyrite, pitchblende, calcite and dolomite, as essential minerals of the U fracture-filling mineralisation, and hydroxyapatite from the host rock, as the main source of P. This conceptual model has been tested in a systematic numerical model, which includes the main kinetic (pyrite and pitchblende dissolution) and equilibrium processes (carbonate mineral dissolution, and goethite, schoepite and autunite secondary precipitation). The results obtained from the reactive-transport model satisfactorily agree with the conceptual model previously established. The assumption of the precipitation of coffinite as a secondary mineral in the system cannot be correctly evaluated due to the lack of hydrochemical data from the reducing zone of the site and valid thermodynamic and kinetic data for this hydrated U(IV)-silicate. This precipitation can also be hampered by the probable existence of dissolved U(IV)-organic matter and/or uranyl carbonate complexes, which are thermodynamically stable under the alkaline and reducing conditions that prevail in the reducing zone of the system. Finally, the intense downwards oxic and acidic alteration in the upper part of the system is of no relevance for the performance assessment of a HLNW disposal. However, the acidic and oxidised conditions are quickly buffered to neutral-alkaline and

  3. Extending the structure-activity relationship study of marine natural ningalin B analogues as P-glycoprotein inhibitors.

    Science.gov (United States)

    Yang, Chao; Wong, Iris L K; Peng, Kai; Liu, Zhen; Wang, Peng; Jiang, Tingfu; Jiang, Tao; Chow, Larry M C; Wan, Sheng Biao

    2017-01-05

    In the present study, a total of 25 novel ningalin B analogues were synthesized and evaluated for their P-gp modulating activity in a P-gp overexpressed breast cancer cell line LCC6MDR. Preliminary structure-activity study shows that A ring and its two methoxy groups are important pharmacophores for P-gp inhibiting activity. Among all derivatives, 23 is the most potent P-gp modulator with EC50 of 120-165 nM in reversing paclitaxel, DOX, vinblastine and vincristine resistance. It is relatively safe to use with selective index at least greater than 606 compared to verapamil. Mechanistic study demonstrates that compound 23 reverses P-gp mediated drug resistance by inhibiting transport activity of P-gp, thereby restoring intracellular drug accumulation. In summary, our study demonstrates that ningalin B analogue 23 is a non-cytotoxic and effective P-gp chemosensitizer that can be used in the future for reversing P-gp mediated clinical cancer drug resistance.

  4. On the nature of gravity and possible change of Earth mass during geological time

    Science.gov (United States)

    Sapunov, Valentin

    2015-04-01

    A number of circumstances can't be explained based on view of the constant force of gravity on the Earth: 1. Dimensions of fossil animals and plants. According to the laws of biomechanics of the giant dinosaurs could not move and fly. 2. The movement of continents, reliably described by A.Vegener, can only be explained on the basis of the model increasing the Earth. Gravity is only one of the fields that define the existence of the world. Field and matter are forms that can be converted into each other. Transition is described, in particular, by Poincare, perhaps not quite accurate: E = (K) mc2. There are indications of the existence of the time field (Kozyrev, 1978), which generates energy, and then the following conditional equation: T, where T is a time. Through this relationship generated energy glow of stars and planets, the mass increases. In particular, there is an increase in the mass of the Earth. This confirms the divergence of the continents and reducing the size of the animals and plants in the Earth's history. According to presented model, the size of Earth increased during 100 millions years two times in linear scale and 8 times in volume and mass scales. Understanding of general principle of space development needs collaboration of different specialists and branches of geosciences. The basis of possible scheme is: 1. The nature of gravity is not explained by science, although some of its properties are described with high accuracy, and these descriptions have predictive power. Indeed, what attracted threads of the body without physical contact? 2. The velocity of propagation of gravitational forces in the universe is many times the speed of light. Perhaps it is infinite, although it is not proven. 3. The universe is infinite, as is clear from logical calculations thinkers more ancient period. However, our universe, i.e. of the universe, available to our senses and instruments, is finite. The volume of our universe is 1070 cubic kilometers. The total

  5. Potential impacts on groundwater resources of deep CO2 storage: natural analogues for assessing potential chemical effects

    OpenAIRE

    Lions, Julie; Gale, Ian; Nygaard, Erik; Rütters, Heike; May, Franz; Beaubien, Stanley; Sohrabi, Mehran; Hatzignatiou, Dimitrios G.; Basava-Reddi, Ludmilla

    2011-01-01

    Carbon dioxide Capture and Storage (CCS) is considered as one of the promising options for reducing atmospheric emissions of CO2 related to human activities. One of the main concerns associated with the geological storage of CO2 is that the CO2 may leak from the intended storage formation, migrate to the near-surface environment and, eventually, escape from the ground. This is a concern because such leakage may affect aquifers overlying the storage site and containing freshwater that may be u...

  6. Dissolution studies of natural analogues spent fuel and U(VI)-Silicon phases of and oxidative alteration process; Estudios de disolucion de analogos naturales de combustible nuclear irradiado y de fases de U(VI)-Silicio representativas de un proceso de alteracion oxidativa

    Energy Technology Data Exchange (ETDEWEB)

    Perez Morales, I.

    2000-07-01

    In order to understand the long-term behavior of the nuclear spent fuel in geological repository conditions, we have performed dissolution studies with natural analogues to UO{sub 2} as well as with solid phases representatives of the oxidative alteration pathway of uranium dioxide, as observed in both natural environment and laboratory studies. In all cases, we have studied the influence of the bicarbonate concentration in the dissolution process, as a first approximation to the groundwater composition of a granitic environment, where carbonate is one of the most important complexing agents. As a natural analogue to the nuclear spent fuel some uraninite samples from the Oklo are deposit in Gabon, where chain fission reactions took place 2000 millions years ago, as well as a pitchblende sample from the mine Fe ore deposit, in Salamanca (spain) have been studied. The studies have been performed at 25 and 60 degree centigree and 60 degree centigree, and they have focussed on the determination of both the thermodynamic and the kinetic properties of the different samples studied, using batch and continuous experimental methodologies, respectively. (Author)

  7. Gamma-ray measurements of naturally occurring radioactive samples from Cyprus characteristic geological rocks

    CERN Document Server

    Tzortzis, M; Christofides, S; Christodoulides, G

    2003-01-01

    Using high-resolution gamma-ray spectroscopy, the terrestrial gamma radiation in all the predominant types of geological rock formations appearing in Cyprus was measured. Soil samples were collected from each rock type, sealed in 1-litre plastic Marinelli beakers, and measured in the laboratory for 24 hours each. From the measured gamma-ray spectra, activity concentrations were determined for Th-232 (range from 1.3 to 52.8 Bq/kg), U-238 (from 0.9 to 90.3 Bq/kg) and K-40 (from 13 to 894 Bq/kg). Elemental concentrations mean values of (2.8 +- 0.7) ppm, (1.3 +- 0.3) ppm and (0.6 +- 0.1) % were extracted, for thorium, uranium and potassium, respectively. Absorbed dose rates in air outdoors were calculated to be in the range of 0.1-50 nGy/h, depending on the geological features, with an overall mean value of (14.7 +- 7.3) nGy/h. The corresponding effective dose rates per person outdoors were estimated to be between 0.1 and 61.4 microSv/y, assuming a 20% occupancy factor.

  8. Natural analogues to the spent fuel behaviour of radioactive wastes (MATRIX, FASES I y II projects); Analogos naturales de la liberacion y migracion del UO2 y elementos metalicos asociados (Proyecto MATRIX, FASES I y II)

    Energy Technology Data Exchange (ETDEWEB)

    Perez del Villa, L.; Campos, R.; Garralon, A.; Crespo, M. T.; Quejido, J. A.; Cozar, J. S.; Arcos, D.; Bruno, J.; Grive, M.; Domenech, C.; Duro, L.; Ruiz Sanchez-Prro, J.; Marin, F.; Izquierdo, A.; Cattetero, G.; Ortuno, F.; Floria, E.

    2005-07-01

    Uranium ore deposits have been extensively studied as natural analogues to the spent fuel behaviour of radioactive wastes. These investigations constitute an essential element of both national and international research programmes applied to the assessment of HLNW repositories and their interaction with the environment. The U ore deposit of Mina Fe (Ciudad Rodrigo, Salamanca) is hosted in highly fractured schistose rocks, a geological setting that has not been envisaged in the ENRESA option for nuclear waste disposal. However, the processes occurring at Mina Fe maintain some analogies with those occurring in a HLNW repository: The existence of large U concentrations as pitchblende (UO{sub 2}+x), which is chemically analogous to the main component of spent nuclear fuel, which has an oxidation degree of 2.25 < x < 2.66 as a result of radiolytic oxidation. The solubility behaviour of pitchblende as a result of interaction with groundwaters of varying chemical composition can be used to validate predictive models for spent fuel stability under severe alteration conditions. Some of the weathering products of pitchblende are similar to those that have been identified during the experimental oxidative dissolution of UO{sub 2}, Sim fuel, as well as natural uraninite and pitchblende. This is a subject that has been previously investigated in other research projects. Fe(III)-oxy hydroxides in the oxidised zone of the deposit could be similar to the spent fuel container corrosion products that could be formed under redox transition conditions. These corrosion products may act as radionuclide and trace metal scavengers. (Author)

  9. A novel geotechnical/geostatistical approach for exploration and production of natural gas from multiple geologic strata, Phase 1

    Energy Technology Data Exchange (ETDEWEB)

    Overbey, W.K. Jr.; Reeves, T.K.; Salamy, S.P.; Locke, C.D.; Johnson, H.R.; Brunk, R.; Hawkins, L. (BDM Engineering Services Co., Morgantown, WV (United States))

    1991-05-01

    This research program has been designed to develop and verify a unique geostatistical approach for finding natural gas resources. The project has been conducted by Beckley College, Inc., and BDM Engineering Services Company (BDMESC) under contract to the US Department of Energy (DOE), Morgantown Energy Technology Center (METC). This section, Volume II, contains a detailed discussion of the methodology used and the geological and production information collected and analyzed for this study. A companion document, Volume 1, provides an overview of the program, technique and results of the study. In combination, Volumes I and II cover the completion of the research undertaken under Phase I of this DOE project, which included the identification of five high-potential sites for natural gas production on the Eccles Quadrangle, Raleigh County, West Virginia. Each of these sites was selected for its excellent potential for gas production from both relatively shallow coalbeds and the deeper, conventional reservoir formations.

  10. Heavy Oil and Natural Bitumen Resources in Geological Basins of the World

    Science.gov (United States)

    Meyer, Richard F.; Attanasi, E.D.; Freeman, P.A.

    2007-01-01

    Heavy oil and natural bitumen are oils set apart by their high viscosity (resistance to flow) and high density (low API gravity). These attributes reflect the invariable presence of up to 50 weight percent asphaltenes, very high molecular weight hydrocarbon molecules incorporating many heteroatoms in their lattices. Almost all heavy oil and natural bitumen are alteration products of conventional oil. Total resources of heavy oil in known accumulations are 3,396 billion barrels of original oil in place, of which 30 billion barrels are included as prospective additional oil. The total natural bitumen resource in known accumulations amounts to 5,505 billion barrels of oil originally in place, which includes 993 billion barrels as prospective additional oil. This resource is distributed in 192 basins containing heavy oil and 89 basins with natural bitumen. Of the nine basic Klemme basin types, some with subdivisions, the most prolific by far for known heavy oil and natural bitumen volumes are continental multicyclic basins, either basins on the craton margin or closed basins along convergent plate margins. The former includes 47 percent of the natural bitumen, the latter 47 percent of the heavy oil and 46 percent of the natural bitumen. Little if any heavy oil occurs in fore-arc basins, and natural bitumen does not occur in either fore-arc or delta basins.

  11. Traces of the future. Learning from the nature for the underground disposal of radioactive wastes; Spuren der Zukunft. Lernen von der Natur fuer die Tiefenlagerung von radioaktiven Abfaellen

    Energy Technology Data Exchange (ETDEWEB)

    Rieser, A

    2007-04-15

    In view of the long term safety of an underground storage facility for radioactive waste, some observations from the nature can be helpful by judging laboratory experiments and theoretical calculations. Some examples which are described in this report (so-called natural analogues) show that in the nature geological systems, materials and processes are found the stability of which can be studied over long time intervals of the past. A natural analogue presents an example that is valid for the actual geological conditions and so can give highly useful remarks. However, such an example should not be over estimated. The examples shown in this report are limited to natural analogues which concern the total storage system, the technical barriers or the host rock of a geological underground repository for highly radioactive wastes as they are produced in a nuclear reactor. (author)

  12. Geological nature of mineral licks and the reasons for geophagy among animals

    Science.gov (United States)

    Panichev, Alexander M.; Popov, Vladimir K.; Chekryzhov, Igor Yu.; Seryodkin, Ivan V.; Sergievich, Alexander A.; Golokhvast, Kirill S.

    2017-06-01

    In this paper, the reasons for geophagy (the eating of rocks by wild herbivores) in two regions of the eastern Sikhote-Alin volcanic belt are considered. The mineralogical and chemical features of the consumed rocks, as well as the geological conditions of their formation, are investigated. A comparative analysis of the mineral and chemical composition of the consumed rocks and the excrement of the animals, almost completely consisting of mineral substances, is carried out. It is established that the consumed rocks are hydrothermally altered rhyolitic tuffs located in the volcanic calderas and early Cenozoic volcano-tectonic depressions. They consist of 30-65 % from zeolites (mainly clinoptilolites) and smectites, possessing powerful sorption properties. According to the obtained data, the main reason for geophagy may be connected with the animals' urge to discard excessive and toxic concentrations of certain elements that are widespread in specific habitats and ingested with forage plants.

  13. The Nature of Carbonate and Organic δ13C Covariance Through Geological Time

    Science.gov (United States)

    Oehlert, A. M.; Swart, P. K.

    2014-12-01

    Significant evolutionary, climatic, and oceanographic events in Earth history are often accompanied by excursions in the carbon isotope composition (δ13C) of marine carbonates and co-occurring sedimentary organic material. The observation of synchronous excursions in the δ13C values of marine carbonates and coeval organic matter is commonly thought to prove that the deposit has not been altered by diagenesis, and that the variations in the δ13C records are the result of a significant change in global carbon cycling. Furthermore, this model suggests that the covariance of carbonate and organic δ13C records is driven only by changes in the δ13C value of the dissolved inorganic carbon in the surface waters of the ocean. However, recent work suggests that there may be at least two alternate models for generating covariance between carbonate and organic δ13C values in the geologic record. One of the models invokes sea-level driven syndepositional mixing between isotopically distinct sources of carbonate and organic material to produce positive covariance between carbonate and organic δ13C values. The second model suggests that post-depositional alteration to the carbonate δ13C values during meteoric diagenesis, in concert with concurrent contributions of terrestrial organic material during subaerial exposure, can also produce co-occurring negative excursions with tightly covariant δ13C records. In contrast to earlier interpretations of covariant δ13C values, these models suggest that both syndepositional and post-depositional factors can significantly influence the relationship between carbonate and organic δ13C values in a variety of depositional environments. The implications for reconstructions of ancient global carbon cycle events will be explored within the context of these three models, and their relative importance throughout geologic time will be discussed.

  14. STRUCTURAL GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2014-01-01

    <正>20141283 Bai Daoyuan(Hunan Institute of Geological Survey,Changsha 410016,China);Zhong Xiang Nature,Origin and Tectonic Setting of Jinzhou Basin in the South Segment of Xuefeng Orogen(Geology in China,ISSN1000-3657,CN11-1167/P,40(4),2013,p.1079-1091,10 illus.,47 refs.)Key words:foreland basins,strike-slip faults,Hunan Province

  15. Geology, Bedrock, Wisconsin Geologic and Natural History Survey has these maps, Published in 2006, 1:24000 (1in=2000ft) scale, Lafayette County Land Records.

    Data.gov (United States)

    NSGIC GIS Inventory (aka Ramona) — This Geology, Bedrock dataset, published at 1:24000 (1in=2000ft) scale, was produced all or in part from Hardcopy Maps information as of 2006. It is described as...

  16. Electronic publishing for academics: geology and physics in Russian network for natural sciences

    OpenAIRE

    A. Selyverstov; P. Plechov; Trusov, S.; A. Krasheninnikov; V. Ustiansky

    2004-01-01

    Electronic publications have proven to be crucial for supplying the scientific community with up-todate research results and instruments for both education and research. Present work summarizes the experience of development and maintenance of two natural science oriented servers and their integration with related databases and web-resources. The Russian network for natural sciences pursues the aim of providing the scientific society of the CIS states with high quality tools for peerreviewed s...

  17. Modelling CO2 flow in naturally fractured geological media using MINC and multiple subregion upscaling procedure

    Science.gov (United States)

    Tatomir, Alexandru Bogdan A. C.; Flemisch, Bernd; Class, Holger; Helmig, Rainer; Sauter, Martin

    2017-04-01

    Geological storage of CO2 represents one viable solution to reduce greenhouse gas emission in the atmosphere. Potential leakage of CO2 storage can occur through networks of interconnected fractures. The geometrical complexity of these networks is often very high involving fractures occurring at various scales and having hierarchical structures. Such multiphase flow systems are usually hard to solve with a discrete fracture modelling (DFM) approach. Therefore, continuum fracture models assuming average properties are usually preferred. The multiple interacting continua (MINC) model is an extension of the classic double porosity model (Warren and Root, 1963) which accounts for the non-linear behaviour of the matrix-fracture interactions. For CO2 storage applications the transient representation of the inter-porosity two phase flow plays an important role. This study tests the accuracy and computational efficiency of the MINC method complemented with the multiple sub-region (MSR) upscaling procedure versus the DFM. The two phase flow MINC simulator is implemented in the free-open source numerical toolbox DuMux (www.dumux.org). The MSR (Gong et al., 2009) determines the inter-porosity terms by solving simplified local single-phase flow problems. The DFM is considered as the reference solution. The numerical examples consider a quasi-1D reservoir with a quadratic fracture system , a five-spot radial symmetric reservoir, and a completely random generated fracture system. Keywords: MINC, upscaling, two-phase flow, fractured porous media, discrete fracture model, continuum fracture model

  18. A synecological account of the Suikerbosrand Nature Reserve. I. The phytosociology of the Witwatersrand geological system

    Directory of Open Access Journals (Sweden)

    G. J. Bredenkamp

    1978-12-01

    Full Text Available The vegetation of the Witwatersrand System of the Suikerbosrand Nature Reserve is analysed and classified according to the Braun-Blanquet table method. Descriptions of the plant communities include habitat features, differentiating species groups, as well as prominent and less conspicuous species for the tree, shrub and herbaceous layers. The habitat factors that are associated with differences in vegetation are mainly altitude, aspect and rockiness of the soil surface, but soil depth, soil texture and slope are also factors of considerable importance. The classification results in very natural communities which represent different ecosystems.

  19. Characterizing the natural radiation levels throughout the main geological units of Sabkhat al Jabboul area, northern Syria.

    Science.gov (United States)

    Al-Hilal, Mohamed; Aissa, Mosa

    2015-02-01

    The concentrations of equivalent eU, eTh, and K% were determined together with soil gas radon values and carborne gamma-ray survey in order to define the natural radioactivity levels throughout main geological units of Sabkhat al Jabboul region. Forty five soil and rock samples were collected from various lithofacies in each geological unit, and analyzed by γ-ray spectrometric technique for determining the concentration values of major radioelements. Such radiometric data could be used to differentiate between various lithologies of the investigated rocks. Although no distinct radioactive anomalies were found in the area, the radiometric profiles showed some minor variations with slightly higher values than the normal level. Despite the low radioactivity and the lack of rocks diversity in the surveyed area, it was possible to classify some certain rock types based on their radiometric response. The relationships between eU, eTh and their ratios were discussed for the Quaternary, Neogene and Paleogene formations, in order to evaluate the degree of uranium distribution and remobilization. The overall results of this radiometric survey were generally low, and lying within the range of the normal background levels in Syrian.

  20. The development of microtextures and dislocation substructures in naturally deformed olivines from various geological environments

    NARCIS (Netherlands)

    Buiskool Toxopeus, J.M.A.

    1978-01-01

    High voltage electron microscopy and petrofabric analysis techniques are used to distinguish dislocation substructures and preferred orientation patterns of the mineral olivine in naturally deformed peridotites. In order to obtain information over a wide field in which different types of deformation

  1. The Galapagos archipelago: A natural laboratory to examine sharp hydroclimatic, geologic and anthropogenic gradients

    Science.gov (United States)

    Percy, Madelyn; Schmitt, Sarah; Riveros-Iregui, Diego; Mirus, Benjamin B.

    2016-01-01

    Poor understanding of the water cycle in tropical ecosystems has the potential to exacerbate water shortages and water crises in the region. We suggest that the Galápagos Islands provide an excellent proxy to regions across the tropics as a result of sharp hydroclimatic, anthropogenic, and pedohydrologic gradients across the archipelago. Hydroclimatic and pedohydrologic gradients are found across different elevations on single islands, as well as across the archipelago, whereas anthropogenic gradients reflect land use and land cover change across islands as population and growth in tourism have affected individual islands differently. This article highlights specific opportunities to further examine our understanding of the interactions between water and critical zone processes in tropical ecosystems, making connections between the Galápagos archipelago and much of the understudied tropics. The Galápagos archipelago offers a natural laboratory through which we can examine current threats to freshwater security as well as the dynamics of coupled natural and human systems.

  2. Geology and Historical Evolution of Sheldon Marsh Nature Preserve, Lake Erie, Ohio

    Science.gov (United States)

    2005-09-01

    kinds of wildflowers .1 1 From Ohio Department of Natural Resources, http...1998, close to the long-term mean. By January of 2000, the water level was at 173.8 m (570.3 ft), the lowest since the spring of 1967. Since then...orienta- tion, during northeasters , northeast winds blow along the axis of the lake and cause seiching. The result can be short-term water level

  3. U.S. Geological Survey research in Handcart Gulch, Colorado—An alpine watershed with natural acid-rock drainage

    Science.gov (United States)

    Manning, Andrew H.; Caine, Jonathan Saul; Verplanck, Philip L.; Bove, Dana J.; Kahn, Katherine G.

    2009-01-01

    Handcart Gulch is an alpine watershed along the Continental Divide in the Colorado Rocky Mountain Front Range. It contains an unmined mineral deposit typical of many hydrothermal mineral deposits in the intermountain west, composed primarily of pyrite with trace metals including copper and molybdenum. Springs and the trunk stream have a natural pH value of 3 to 4. The U.S. Geological Survey began integrated research activities at the site in 2003 with the objective of better understanding geologic, geochemical, and hydrologic controls on naturally occurring acid-rock drainage in alpine watersheds. Characterizing the role of groundwater was of particular interest because mountain watersheds containing metallic mineral deposits are often underlain by complexly deformed crystalline rocks in which groundwater flow is poorly understood. Site infrastructure currently includes 4 deep monitoring wells high in the watershed (300– 1,200 ft deep), 4 bedrock (100–170 ft deep) and 5 shallow (10–30 ft deep) monitoring wells along the trunk stream, a stream gage, and a meteorological station. Work to date at the site includes: geologic mapping and structural analysis; surface sample and drill core mineralogic characterization; geophysical borehole logging; aquifer testing; monitoring of groundwater hydraulic heads and streamflows; a stream tracer dilution study; repeated sampling of surface and groundwater for geochemical analyses, including major and trace elements, several isotopes, and groundwater age dating; and construction of groundwater flow models. The unique dataset collected at Handcart Gulch has yielded several important findings about bedrock groundwater flow at the site. Most importantly, we find that bedrock bulk permeability is nontrivial and that bedrock groundwater apparently constitutes a substantial fraction of the hydrologic budget. This means that bedrock groundwater commonly may be an underappreciated component of the hydrologic system in studies of

  4. Synthesis of psymberin analogues: probing a functional correlation with the pederin/mycalamide family of natural products.

    Science.gov (United States)

    Jiang, Xin; Williams, Noelle; De Brabander, Jef K

    2007-01-18

    In this letter we describe an efficient synthesis of "psympederin", a hybrid between the novel antitumor natural product psymberin and the blister beetle toxin pederin. Evaluation of antiproliferative activity reveals that the dihydroisocoumarin fragment is important for psymberin toxicity and the cyclic pederate fragment is important for pederin/mycalamide toxicity. On the basis of preliminary results described herein, we speculate that, despite their structural resemblance, psymberin and pederin/mycalamide induce toxicity through different mechanisms. [reaction: see text].

  5. Validation of predictive models for geologic disposal of radioactive waste via natural analogs

    Energy Technology Data Exchange (ETDEWEB)

    Cohen, J.J.; Smith, C.F.

    1981-03-01

    The incorporation of toxic or hazardous material in the earth's crust is a phenomenon not unique to radioactive waste burial. Useful insights on the environmental transport and effects of underground toxic or radioactive material can be derived from comparative analysis against natural (mineral) analogs. This paper includes a discussion of the background and rationale for the analog approach, a descripton of several variations of the approach, and some sample applications to illustrate the concept, focusing on Radium-226 and Iodine-129 as specific case studies.

  6. Textural and hydration properties of a synthetic montmorillonite compared with a natural Na-exchanged clay analogue.

    OpenAIRE

    2010-01-01

    International audience; An aluminous montmorillonite has been synthesized at hydrothermal conditions (623 K, 120 MPa) and compared to the natural Na-exchanged Wyoming montmorillonite (Na-SWy2). The synthetic product is characterized by a high cation exchange capacity (83 meq/100g) and ethylene glycol specific surface area (764 m2/g) similar to Na-SWy2 but with a higher purity with one crystalline phase. Compacted smectite samples were percolated with water by using an œdometer cell equipped w...

  7. Synthesis of high-mannose oligosaccharide analogues through click chemistry: true functional mimics of their natural counterparts against lectins?

    Science.gov (United States)

    François-Heude, Marc; Méndez-Ardoy, Alejandro; Cendret, Virginie; Lafite, Pierre; Daniellou, Richard; Ortiz Mellet, Carmen; García Fernández, José M; Moreau, Vincent; Djedaïni-Pilard, Florence

    2015-01-26

    Terminal "high-mannose oligosaccharides" are involved in a broad range of biological and pathological processes, from sperm-egg fusion to influenza and human immunodeficiency virus infections. In spite of many efforts, their synthesis continues to be very challenging and actually represents a major bottleneck in the field. Whereas multivalent presentation of mannopyranosyl motifs onto a variety of scaffolds has proven to be a successful way to interfere in recognition processes involving high-mannose oligosaccharides, such constructs fail at reproducing the subtle differences in affinity towards the variety of protein receptors (lectins) and antibodies susceptible to binding to the natural ligands. Here we report a family of functional high-mannose oligosaccharide mimics that reproduce not only the terminal mannopyranosyl display, but also the core structure and the branching pattern, by replacing some inner mannopyranosyl units with triazole rings. Such molecular design can be implemented by exploiting "click" ligation strategies, resulting in a substantial reduction of synthetic cost. The binding affinities of the new "click" high-mannose oligosaccharide mimics towards two mannose specific lectins, namely the plant lectin concanavalin A (ConA) and the human macrophage mannose receptor (rhMMR), have been studied by enzyme-linked lectin assays and found to follow identical trends to those observed for the natural oligosaccharide counterparts. Calorimetric determinations against ConA, and X-ray structural data support the conclusion that these compounds are not just another family of multivalent mannosides, but real "structural mimics" of the high-mannose oligosaccharides.

  8. Geophysical Research in the Ganuelas-Mazarron Tertiary Basin (Murcia, Spain), as a Natural Analogue of CO{sub 2} Storage and Leakage; Estudio Geofisico del Analogo Natural de Almacenamiento y Escape de CO{sub 2} de la Cuenca Terciaria de Ganuelas-Mazarron (Murcia, Espana)

    Energy Technology Data Exchange (ETDEWEB)

    Rodrigo-Naharro, J.; Aracil, E.; Perez del Villar, L.

    2013-07-01

    In order to determine the depth, morphology and extent of the CO{sub 2}-enriched deep saline aquifer in the Ganuelas-Mazarron Tertiary basin (Murcia, Spain), it was necessary reprocessing the vertical electrical soundings performed by IGME-ADARO in the eighties and to perform several geophysical campaigns by means of electrical tomography, time domain electromagnetic surveys and gravimetry. Densities of the outcropping lithologies in the studied basin were also determined in order to refine the model obtained from gravimetric data. The geophysical results, particularly from gravimetric data, seem to indicate that the CO{sub 2}-enriched deep saline aquifer, located in the contact or within the carbonate materials of the Nevado-Filabride Complex, could reach a depth greater than 800 m. For this reason, the possibility that this CO{sub 2} is in supercritical state in certain areas of the aquifer, is not discardable. Thus, the studied basin would be an excellent natural analogue of a CO{sub 2}-deep geological storage in a deep saline aquifer in volcanic and/or carbonate rocks, anthropogenically perturbed by geothermal exploration wells (La Ermita de El Saladillo and El Alto de El Reventon) and hydrogeological wells for agricultural purposes. (Author)

  9. The applicability and limitations of the geochemical models and tools used in simulating radionuclide behaviour in natural waters. Lessons learned from the Blind Predictive Modelling exercises performed in conjunction with Natural Analogue studies

    Energy Technology Data Exchange (ETDEWEB)

    Bruno, J.; Duro, L.; Grive, M. [QuantiSci SL, Parc Tecnologic del Valles (Spain)

    2001-07-01

    One of the key applications of Natural Analogue studies to the Performance Assessment (PA) of nuclear waste disposal has been the possibility to test the geochemical models and tools to be used in describing the migration of radionuclides in a future radioactive waste repository system. To this end, several geochemical modelling testing exercises (commonly denoted as Blind Predictive Modelling), have formed an integral part of Natural Analogue Studies over the last decade. Consequently, we thought that this is a timely occasion to make an evaluation of the experience gained and lessons learnt. We have reviewed, discussed and compared the results obtained from the Blind Prediction Modelling (BPM) exercises carried out within 7 Natural Analogue Studies: Oman, Pocos de Caldas, Cigar Lake, Maqarin, El Berrocal, Oklo and Palmottu. To make this comparison meaningful, we present the main geochemical characteristics of each site in order to highlight the most relevant mineralogical and hydrochemical differences. From the complete list of elements studied at all the investigated sites we have made a selection based on the relevance of a given element from a PA viewpoint and on the frequency this element has been included in the BPM exercises. The elements selected for discussion are: Sr, Ba, Sn, Pb, Se, Ni, Zn, REEs, Th and U. We have based our discussion on the results obtained from the speciation as well as solubility calculations. From the comparison of the results it is concluded that we can differentiate between three element categories: 1. Elements whose geochemical behaviour can be fairly well described by assuming solubility control exerted by pure solid phases of the given element (i.e. Th, U under reducing conditions and U in some sites under oxidising conditions); 2. Elements for which the association to major geochemical components of the system must be considered in order to explain their concentrations in groundwaters (i.e. Sr, Ba, Zn, Se, REEs and U under

  10. Arsenic removal from groundwater of the Chaco-Pampean plain (Argentina) using natural geological materials as adsorbents.

    Science.gov (United States)

    Bundschuh, Jochen; Bhattacharya, Prosun; Sracek, Ondra; Mellano, M Fernanda; Ramírez, Antonio E; Storniolo, Angel del R; Martín, Raúl A; Cortés, Julia; Litter, Marta I; Jean, Jiin-Shuh

    2011-01-01

    Use of natural geological materials for arsenic (As) removal is an emerging solution at a household level for poor people in remote rural settlements, especially when the materials are locally available and can be collected by the local population. Their low or zero cost makes these materials very attractive compared with synthetic or commercial materials. Sometimes, this may be the only option to provide safe water to very poor settlements. Their suitability for As removal from water is mainly due to adsorption, co-precipitation and ion exchange processes involving Fe- and Al-rich minerals and clay minerals present in the soils or sediments. In the present study, various clay-rich soils from the Santiago del Estero province (SDE, NW Argentina) and, for comparison, a laterite from the Misiones province have been tested as adsorbents for As in shallow naturally contaminated groundwaters of the Río Dulce alluvial aquifer in SDE. Batch adsorption experiments showed higher As(V) removal for the Misiones laterite sample (99 %) as compared with the soils from SDE (40-53 %), which can be related to lower contents of water-soluble and oxalate extractable Al and Fe in the last samples. These results suggest the application of the Misiones laterite soil as an alternative for As removal. However, high transportation costs from Misiones to SDE can be an economical restriction for the low-income population of SDE.

  11. Assessment of natural radioactivity levels in rocks and their relationships with the geological structure of Johor state, Malaysia.

    Science.gov (United States)

    Alnour, I A; Wagiran, H; Ibrahim, N; Hamzah, S; Elias, M S; Laili, Z; Omar, M

    2014-01-01

    The distribution of natural radionuclides ((238)U, (232)Th and (40)K) and their radiological hazard effect in rocks collected from the state of Johor, Malaysia were determined by gamma spectroscopy using a high-purity germanium detector. The highest values of (238)U, (232)Th and (40)K activity concentrations (67±6, 85±7 and 722±18 Bg kg(-1), respectively) were observed in the granite rock. The lowest concentrations of (238)U and (232)Th (2±0.1 Bq kg(-1) for (238)U and 2±0.1 Bq kg(-1) for (232)Th) were observed in gabbro rock. The lowest concentration of (40)K (45±2 Bq kg(-1)) was detected in sandstone. The radium equivalent activity concentrations for all rock samples investigated were lower than the internationally accepted value of 370 Bq kg(-1). The highest value of radium equivalent in the present study (239±17 Bq kg(-1)) was recorded in the area of granite belonging to an acid intrusive rock geological structure. The absorbed dose rate was found to range from 4 to 112 nGy h(-1). The effective dose ranged from 5 to 138 μSv h(-1). The internal and external hazard index values were given in results lower than unity. The purpose of this study is to provide information related to radioactivity background levels and the effects of radiation on residents in the study area under investigation. Moreover, the relationships between the radioactivity levels in the rocks within the geological structure of the studied area are discussed.

  12. Analogues to features and processes of a high-level radioactive waste repository proposed for Yucca Mountain, Nevada

    Science.gov (United States)

    Simmons, Ardyth M.; Stuckless, John S.; with a Foreword by Abraham Van Luik, U.S. Department of Energy

    2010-01-01

    Natural analogues are defined for this report as naturally occurring or anthropogenic systems in which processes similar to those expected to occur in a nuclear waste repository are thought to have taken place over time periods of decades to millennia and on spatial scales as much as tens of kilometers. Analogues provide an important temporal and spatial dimension that cannot be tested by laboratory or field-scale experiments. Analogues provide one of the multiple lines of evidence intended to increase confidence in the safe geologic disposal of high-level radioactive waste. Although the work in this report was completed specifically for Yucca Mountain, Nevada, as the proposed geologic repository for high-level radioactive waste under the U.S. Nuclear Waste Policy Act, the applicability of the science, analyses, and interpretations is not limited to a specific site. Natural and anthropogenic analogues have provided and can continue to provide value in understanding features and processes of importance across a wide variety of topics in addressing the challenges of geologic isolation of radioactive waste and also as a contribution to scientific investigations unrelated to waste disposal. Isolation of radioactive waste at a mined geologic repository would be through a combination of natural features and engineered barriers. In this report we examine analogues to many of the various components of the Yucca Mountain system, including the preservation of materials in unsaturated environments, flow of water through unsaturated volcanic tuff, seepage into repository drifts, repository drift stability, stability and alteration of waste forms and components of the engineered barrier system, and transport of radionuclides through unsaturated and saturated rock zones.

  13. Total synthesis and biological evaluation of a series of macrocyclic hybrids and analogues of the antimitotic natural products dictyostatin, discodermolide, and taxol.

    Science.gov (United States)

    Paterson, Ian; Naylor, Guy J; Gardner, Nicola M; Guzmán, Esther; Wright, Amy E

    2011-02-01

    The design, synthesis, and biological evaluation of a series of hybrids and analogues of the microtubule-stabilizing anticancer agents dictyostatin, discodermolide, and taxol is described. A 22-membered macrolide scaffold was prepared by adapting earlier synthetic routes directed towards dictyostatin and discodermolide, taking advantage of the distinctive structural and stereochemical similarities between these two polyketide-derived marine natural products. Initial endeavors towards accessing novel discodermolide/dictyostatin hybrids led to the adoption of a late-stage diversification strategy and the construction of a small library of methyl-ether derivatives, along with the first triple hybrids bearing the side-chain of taxol or taxotere attached through an ester linkage. Biological assays of the anti-proliferative activity of these compounds in a series of human cancer cell lines, including the taxol-resistant NCI/ADR-Res cell line, allowed the proposal of various structure-activity relationships. This led to the identification of a potent macrocyclic discodermolide/dictyostatin hybrid 12 and its C9 methoxy derivative 38, accessible by an efficient total synthesis and with a similar biological profile to dictyostatin.

  14. GEOTHERMICS GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2015-01-01

    20150342Guan Yu(Geo-Environment Monitoring Station of Anhui Province,Hefei230001,China);Chen Xun On Shallow Geothermal Energy Investigation in Urban Planning Zone of Bengbu in Anhui Province(Journal of Geology,ISSN1674-3636,CN32-1796/P,38(1),2014,p.88-93,2illus.,4tables,6refs.)Key words:geothermal energy,Anhui Province The authors conducted studies on shallow geothermal energy in urban planning zone in Bengbu of Anhui Province,depicted the geological settings of shallow geothermal energy,analyzed the natural features,heat exchange

  15. A natural analogue for CO2 leakage: The release and fate of CO2 at the Jan Mayen vent fields (AMOR)

    Science.gov (United States)

    Baumberger, T.; Lilley, M. D.; Pedersen, R. B.; Thorseth, I. H.

    2013-12-01

    Carbon dioxide capture and storage (CCS) is seen as a new possible technique for reducing the emission of industrial CO2 to the atmosphere. To evaluate the risks of sub-seabed CO2 storage, the European Commission is supporting the international and multi-disciplinary ECO2 project. Among other objectives, this project is dealing with evaluating the likelihood of leakage and the resulting possible impacts on marine ecosystems. In the framework of the ECO2 project, the release and dispersal of CO2 have been studied at several natural seep sites. In this study, we present geochemical data collected at the natural CO2 leakage analogue, Jan Mayen vent fields (JMVF). The basalt-hosted JMVF are located at 71° N on the southern end of the ultra-slow spreading Mohns Ridge, which is part of the Arctic Mid-Ocean Ridge (AMOR) system. The JMVF are composed of several venting sites, spread over a large area. These venting areas include focused high-temperature venting and diffuse low-temperature fluid flow vents as well as areas where free gas bubbles are released. Over the past few years, we have repeatedly visited and extensively sampled these vent fields to study the release and fate of CO2 in this natural seep area. One of our main objectives was to constrain the CO2 content of the widely emitted gas and to study its dispersion and fate in the water column. We have also investigated hydrate formation, which is observed at various locations. The venting fluids are chemically characterized by CO2 concentrations of up to 110 mmol/kg, having an associated isotopic composition representing a mantle carbon source. Thus, the CO2 concentrations measured at the JMVF represent the high-end compared to the concentration range of most other basalt-hosted hydrothermal mid-ocean ridge systems. Even though the concentrations of the emitted CO2 vary over time and with the type of venting (focused flow, diffuse flow or bubbles), the overall release is continuously high. The dispersion of the

  16. Interaction of organic contaminant with natural clay type geo sorbents: potential use as geologic barrier in urban landfill

    Energy Technology Data Exchange (ETDEWEB)

    Sanchez Jimenez, N.; Procopio, J. R.; Sevilla, T.; Cuevas, J.; Rodirguez, M.

    2009-07-01

    The great amount of municipal solid wastes generated by the cities can be processed in different ways such as incineration, derivation to composting plants or, simply, deposition in controlled landfills. One of the landfill characteristics is possess and adequate geological barrier for contaminant contention. The most important chemical processes an adequate geological battier for contaminant contention. (Author)

  17. Theoretical geology

    Science.gov (United States)

    Mikeš, Daniel

    2010-05-01

    Theoretical geology Present day geology is mostly empirical of nature. I claim that geology is by nature complex and that the empirical approach is bound to fail. Let's consider the input to be the set of ambient conditions and the output to be the sedimentary rock record. I claim that the output can only be deduced from the input if the relation from input to output be known. The fundamental question is therefore the following: Can one predict the output from the input or can one predict the behaviour of a sedimentary system? If one can, than the empirical/deductive method has changes, if one can't than that method is bound to fail. The fundamental problem to solve is therefore the following: How to predict the behaviour of a sedimentary system? It is interesting to observe that this question is never asked and many a study is conducted by the empirical/deductive method; it seems that the empirical method has been accepted as being appropriate without question. It is, however, easy to argument that a sedimentary system is by nature complex and that several input parameters vary at the same time and that they can create similar output in the rock record. It follows trivially from these first principles that in such a case the deductive solution cannot be unique. At the same time several geological methods depart precisely from the assumption, that one particular variable is the dictator/driver and that the others are constant, even though the data do not support such an assumption. The method of "sequence stratigraphy" is a typical example of such a dogma. It can be easily argued that all the interpretation resulting from a method that is built on uncertain or wrong assumptions is erroneous. Still, this method has survived for many years, nonwithstanding all the critics it has received. This is just one example of the present day geological world and is not unique. Even the alternative methods criticising sequence stratigraphy actually depart from the same

  18. Solution-phase parallel synthesis of a pharmacophore library of HUN-7293 analogues: a general chemical mutagenesis approach to defining structure-function properties of naturally occurring cyclic (depsi)peptides.

    Science.gov (United States)

    Chen, Yan; Bilban, Melitta; Foster, Carolyn A; Boger, Dale L

    2002-05-15

    HUN-7293 (1), a naturally occurring cyclic heptadepsipeptide, is a potent inhibitor of cell adhesion molecule expression (VCAM-1, ICAM-1, E-selectin), the overexpression of which is characteristic of chronic inflammatory diseases. Representative of a general approach to defining structure-function relationships of such cyclic (depsi)peptides, the parallel synthesis and evaluation of a complete library of key HUN-7293 analogues are detailed enlisting solution-phase techniques and simple acid-base liquid-liquid extractions for isolation and purification of intermediates and final products. Significant to the design of the studies and unique to solution-phase techniques, the library was assembled superimposing a divergent synthetic strategy onto a convergent total synthesis. An alanine scan and N-methyl deletion of each residue of the cyclic heptadepsipeptide identified key sites responsible for or contributing to the biological properties. The simultaneous preparation of a complete set of individual residue analogues further simplifying the structure allowed an assessment of each structural feature of 1, providing a detailed account of the structure-function relationships in a single study. Within this pharmacophore library prepared by systematic chemical mutagenesis of the natural product structure, simplified analogues possessing comparable potency and, in some instances, improved selectivity were identified. One potent member of this library proved to be an additional natural product in its own right, which we have come to refer to as HUN-7293B (8), being isolated from the microbial strain F/94-499709.

  19. Geological safety aspects of nuclear waste disposalin in Finland

    Energy Technology Data Exchange (ETDEWEB)

    Ahonen, L.; Hakkarainen, V.; Kaija, J.; Kuivamaki, A.; Lindberg, A.; Paananen, M.; Paulamaki, S.; Ruskeeniemi, T., e-mail: lasse.ahonen@gtk.fi

    2011-07-01

    The management of nuclear waste from Finnish power companies is based on the final geological disposal of encapsulated spent fuel at a depth of several hundreds of metres in the crystalline bedrock. Permission for the licence requires that the safety of disposal is demonstrated in a safety case showing that processes, events and future scenarios possibly affecting the performance of the deep repository are appropriately understood. Many of the safety-related issues are geological in nature. The Precambrian bedrock of Finland has a long history, even if compared with the time span considered for nuclear waste disposal, but the northern location calls for a detailed study of the processes related to Quaternary glaciations. This was manifested in an extensive international permafrost study in northern Canada, coordinated by GTK. Hydrogeology and the common existence of saline waters deep in the bedrock have also been targets of extensive studies, because water chemistry affects the chemical stability of the repository near-field, as well as radionuclide transport. The Palmottu natural analogue study was one of the international high-priority natural analogue studies in which transport phenomena were explored in a natural geological system. Currently, deep biosphere processes are being investigated in support of the safety of nuclear waste disposal. (orig.)

  20. Geology and hydrocarbon accumulations in the deepwater of the northwestern South China Sea-with focus on natural gas

    Institute of Scientific and Technical Information of China (English)

    WANG Zhenfeng; SUN Zhipeng; ZHANG Daojun; ZHU Jitian; LI Xushen; HUANG Baojia; GUO Minggang; JIANG Rufeng

    2015-01-01

    The deepwater of the northwestern South China Sea is located in the central to southern parts of the Qiongdongnan Basin (QDN Basin), which is a key site for hydrocarbon exploration in recent years. In this study, the authors did a comprehensive analysis of gravity-magnetic data, extensive 3D seismic survey, cores and cuttings, paleontology and geochemical indexes, proposed the mechanism of natural gas origin, identified different oil and gas systems, and established the model of hydrocarbon accumulations in the deep-water region. Our basin tectonic simulation indicates that the evolution of QDN Basin was controlled by multiple-phased tectonic movements, such as Indochina-Eurasian Plate collision, Tibetan Uplift, Red River faulting and the expansion of the South China Sea which is characterized by Paleogene rifting, Neogene depression, and Eocene intensive faulting and lacustrine deposits. The drilling results show that this region is dominated by marine-terrestrial transitional and neritic-bathyal facies from the early Oligocene. The Yacheng Formation of the early Oligocene is rich in organic matter and a main gas-source rock. According to the geological-geochemical data from the latest drilling wells, Lingshui, Baodao, Changchang Sags have good hydrocarbon-generating potentials, where two plays from the Paleogene and Neogene reservoirs were developed. Those reservoirs occur in central canyon structural-lithologic trap zone, Changchang marginal trap zone and southern fault terrace of Baodao Sag. Among them, the central canyon trap zone has a great potential for exploration because the various reservoir-forming elements are well developed, i.e., good coal-measure source rocks, sufficient reservoirs from the Neogene turbidity sandstone and submarine fan, faults connecting source rock and reservoirs, effective vertical migration, late stage aggregation and favorable structural–lithological composite trapping. These study results provide an important scientific basis

  1. Geological conditions of formation of beaches and natural medical assessment of their use in the resort and recreational purposes.

    Directory of Open Access Journals (Sweden)

    Storchak O.V.

    2010-06-01

    Full Text Available In assessing the territory waters and coast, their possible use in resort and recreational purposes, apply the criteria of terapeutic beaches subject to simultaneous patients stayin the bich,as well as geomorphological, hydrological and geological conditions.

  2. Synthesis and analgesic profile of conformationally constrained N-acylhydrazone analogues: discovery of novel N-arylideneamino quinazolin-4(3H)-one compounds derived from natural safrole.

    Science.gov (United States)

    Maia, Rodolfo C; Silva, Leandro L; Mazzeu, Eduardo F; Fumian, Milla M; de Rezende, Claudia M; Doriguetto, Antonio C; Corrêa, Rodrigo S; Miranda, Ana Luisa P; Barreiro, Eliezer J; Fraga, Carlos Alberto Manssour

    2009-09-15

    In this work we reported the synthesis and evaluation of the analgesic, anti-inflammatory, and platelet anti-aggregating properties of new 3-(arylideneamino)-2-methyl-6,7-methylenedioxy-quinazolin-4(3H)-one derivatives (3a-j), designed as conformationally constrained analogues of analgesic 1,3-benzodioxolyl-N-acylhydrazones (1) previously developed at LASSBio. Target compounds were synthesized in very good yields exploiting abundant Brazilian natural product safrole (2) as starting material. The pharmacological assays lead us to identify compounds LASSBio-1240 (3b) and LASSBio-1272 (3d) as new analgesic prototypes, presenting an antinociceptive profile more potent and effective than dipyrone and indomethacin used, respectively, as standards in AcOH-induced abdominal constrictions assay and in the formalin test. These results confirmed the success in the exploitation of conformation restriction strategy for identification of novel cyclic N-acylhydrazone analogues with optimized analgesic profile.

  3. Teaching the content and context of science: The effect of using historical narratives to teach the nature of science and science content in an undergraduate introductory geology course

    Science.gov (United States)

    Vanderlinden, David Winston

    This study reports the use of historically accurate narratives (short stories) to simultaneously teach geology content and the nature of science in an introductory, undergraduate geology course. The stories describe key events involved in the development of geologists' ideas about continental drift/plate tectonics and deep time/the age of the Earth. The design of the stories provides a highly contextualized setting which is designed to promote NOS and geology understanding by explicitly attending students to fundamental concepts and requiring students to reflect on the short story content. Evidence is reported to support the conclusion that students using these short stories constructed a better understanding of (1) the variety of processes involved in the construction of scientific knowledge, (2) the subjective nature of data that allows it to be interpreted differently by different scientists, and (3) the roles that culture and society play in determining the way in which scientific work is conducted and scientific ideas are constructed, while maintaining equal levels of understanding of geology content when compared to students who did not use the short stories. In some cases, students' preconceptions about objectivity in science, the degree to which scientific ideas can be considered as "proven" or "true," and the role of discovery in science appear to have adversely affected their ability to interpret the short story content in the ways intended. In addition, students' misconceptions about differences in how oceanic and continental plates were formed and geologists' use of relative and absolute dating techniques, especially the appropriate uses of radio-isotopic dating, are described. This study has implications for science instructors as they make efforts to efficiently use class time and curriculum resources to teach about the both the content and context of science and for geology instructors as they consider students' misconceptions about plate tectonics

  4. Using Isomap to differentiate between anthropogenic and natural effects on groundwater dynamics in a complex geological setting

    Science.gov (United States)

    Boettcher, Steven; Merz, Christoph; Lischeid, Gunnar

    2015-04-01

    The water budget of many catchments has vastly changed throughout the last decades. Intensified land use and increased water withdrawal for drinking water production and irrigation are likely to intensify pressure on water resources. According to model predictions, changing rainfall intensity, duration and spatial distribution in conjunction with increasing temperatures will worsen the situation in the future. The current water resources management has to adapt to these negative developments and to account for competing demands and threats. Essential for successful management applications is the identification and the quantification of the cause-and-effect chains driving the hydrological behavior of a catchment on the scale of management. It needs to check direction and magnitude of intended effects of measures taken as well as to identify unintended side effects that interact with natural effects in heterogeneous environments (Wood et al., 1988; Bloschl and Sivapalan, 1995). Therefore, these tools have to be able to distinguish between natural and anthropogenic driven impacts, even in complex geological settings like the Pleistocene landscape of North-East Germany. This study presents an approach that utilizes monitoring data to detect and quantitatively describe the predominant processes or factors of an observed hydrological system. The multivariate data analysis involves a non-linear dimension reduction method called Isometric Feature Mapping (Isomap, Tenenbaum et al., 2000) to extract information about the causes for the observed dynamics. Ordination methods like Isomap are used to derive a meaningful low-dimensional representation of a complex, high-dimensional data set. The approach is based on the hypothesis, that the number of processes which explain the variance of the data is relative low although the intensity of the processes varies in time and space. Therefore, the results can be interpreted in reference to the effective hydrological processes which

  5. Analogue computing methods

    CERN Document Server

    Welbourne, D

    1965-01-01

    Analogue Computing Methods presents the field of analogue computation and simulation in a compact and convenient form, providing an outline of models and analogues that have been produced to solve physical problems for the engineer and how to use and program the electronic analogue computer. This book consists of six chapters. The first chapter provides an introduction to analogue computation and discusses certain mathematical techniques. The electronic equipment of an analogue computer is covered in Chapter 2, while its use to solve simple problems, including the method of scaling is elaborat

  6. 3D Virtual Itinerary for Education Using Google Earth as a Tool for the Recovery of the Geological Heritage of Natural Areas: Application in the “Las Batuecas Valley” Nature Park (Salamanca, Spain

    Directory of Open Access Journals (Sweden)

    Antonio Miguel Martínez-Graña

    2014-11-01

    Full Text Available The objective of this study is to develop a methodology that enhances the value and position of the geological heritage of any natural area in the world using a 3D virtual itinerary. Field applications of this geological itinerary enable students to participate actively in teaching and learning theoretical concepts in the earth sciences and engineering. The educational resources, which include a virtual itinerary, a flight simulator, a field notebook with questionnaires, videos, and an augmented reality developed with Google Earth, provide a familiar and effective learning environment that can be implemented by students daily using new technologies (smartphones, tablets, and iPods and can leverage the power of computer games to achieve the objectives of a specific curriculum. The implementation of geological content in an interactive, educational game has been employed in compulsory levels of secondary education, high school, and college in Batuecas Valley. The geomatic applications are free as they can be accessed from existing computer labs.

  7. Design and Synthesis of Analogues of Marine Natural Product Galaxamide, an N-methylated Cyclic Pentapeptide, as Potential Anti-Tumor Agent in Vitro

    Directory of Open Access Journals (Sweden)

    Jignesh Lunagariya

    2016-09-01

    Full Text Available Herein, we report design and synthesis of novel 26 galaxamide analogues with N-methylated cyclo-pentapeptide, and their in vitro anti-tumor activity towards the panel of human tumor cell line, such as, A549, A549/DPP, HepG2 and SMMC-7721 using MTT assay. We have also investigated the effect of galaxamide and its representative analogues on growth, cell-cycle phases, and induction of apoptosis in SMMC-7721 cells in vitro. Reckon with the significance of conformational space and N-Me aminoacid (aa comprising this compound template, we designed the analogues with modification in N-Me-aa position, change in aa configuration from l to d aa and substitute one Leu-aa to d/l Phe-aa residue with respective to the parent structure. The efficient solid phase parallel synthesis approach is employed for the linear pentapeptide residue containing N-Me aa, followed by solution phase macrocyclisation to afford target cyclo pentapeptide compounds. In the present study, all galaxamide analogues exhibited growth inhibition in A549, A549/DPP, SMMC-7721 and HepG2 cell lines. Compounds 6, 18, and 22 exhibited interesting activities towards all cell line tested, while Compounds 1, 4, 15, and 22 showed strong activity towards SMMC-7221 cell line in the range of 1–2 μg/mL IC50. Flow cytometry experiment revealed that galaxamide analogues namely Compounds 6, 18, and 22 induced concentration dependent SMMC-7721 cell apoptosis after 48 h. These compounds induced G0/G1 phase cell-cycle arrest and morphological changes indicating induction of apoptosis. Thus, findings of our study suggest that the galaxamide and its analogues 6, 18 and 22 exerted growth inhibitory effect on SMMC-7721 cells by arresting the cell cycle in the G0/G1 phase and inducing apoptosis. Compound 1 showed promising anti-tumor activity towards SMMC-7721 cancer cell line, which is 9 and 10 fold higher than galaxamide and reference DPP (cisplatin, respectively.

  8. Analogue VLSI for probabilistic networks and spike-time computation.

    Science.gov (United States)

    Murray, A

    2001-02-01

    The history and some of the methods of analogue neural VLSI are described. The strengths of analogue techniques are described, along with residual problems to be solved. The nature of hardware-friendly and hardware-appropriate algorithms is reviewed and suggestions are offered as to where analogue neural VLSI's future lies.

  9. Total Synthesis of the Analogue of Icogenin

    Institute of Scientific and Technical Information of China (English)

    Shu Jie HOU; Peng XU; Liang ZHOU; De Quan YU; Ping Sheng LEI; Chuan Chun ZOU

    2006-01-01

    One of the analogues of icogenin, a natural furostanol saponin showing strong cytotoxic effect on cancer cell, was first synthesized via convergent strategy by using diosgenin and available monosaccharides as starting materials,

  10. ECONOMIC GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2004-01-01

    <正>20041200 Peng Yujing (Regional Geology and Mineral Resources Survey of Jilin Province, Changchun, Jilin); Chen Erzhen A Preliminary Study on the Ore -Forming Geologic Events (Jilin Geology, ISSN 1001-2427, CN22-1099/P, 22(3), 2003, p. 1 -11, 23, 1 illus. , 38 refs. ) Key words: geological eventAn ore - forming geologic event, as a

  11. A novel geotechnical/geostatistical approach for exploration and production of natural gas from multiple geologic strata, Phase 1. Volume 1, Overview

    Energy Technology Data Exchange (ETDEWEB)

    Overbey, W.K. Jr.; Reeves, T.K.; Salamy, S.P.; Locke, C.D.; Johnson, H.R.; Brunk, R.; Hawkins, L. [BDM Engineering Services Co., Morgantown, WV (United States)

    1991-05-01

    This research program has been designed to develop and verify a unique geostatistical approach for finding natural gas resources. The research has been conducted by Beckley College, Inc. (Beckley) and BDM Engineering Services Company (BDMESC) under contract to the US Department of Energy (DOE), Morgantown Energy Technology Center. Phase 1 of the project consisted of compiling and analyzing relevant geological and gas production information in selected areas of Raleigh County, West Virginia, ultimately narrowed to the Eccles, West Virginia, 7 {1/2} minute Quadrangle. The Phase 1 analysis identified key parameters contributing to the accumulation and production of natural gas in Raleigh County, developed analog models relating geological factors to gas production, and identified specific sites to test and verify the analysis methodologies by drilling. Based on the Phase 1 analysis, five sites have been identified with high potential for economic gas production. Phase 2 will consist of drilling, completing, and producing one or more wells at the sites identified in the Phase 1 analyses. The initial well is schedules to the drilled in April 1991. This report summarizes the results of the Phase 1 investigations. For clarity, the report has been prepared in two volumes. Volume 1 presents the Phase 1 overview; Volume 2 contains the detailed geological and production information collected and analyzed for this study.

  12. Putting the geology back into Earth models

    Science.gov (United States)

    McCaffrey, K.; Imber, J.; Holdsworth, R.; Clegg, P.; de Paola, N.; Jones, R.; Hobbs, R.; Holliman, N.

    2005-12-01

    Geological architectures span at least 12 orders of magnitude length-scale from individual microstructures to lithospheric plates. Traditional paper-based geological mapping and fieldwork techniques have not been able to accurately capture the geospatial properties of mesoscale features in surface outcrops. In addition, geophysical imaging of the subsurface is poor at these length scales. This lack of fine-scale spatial precision has meant that the superbly detailed lithological units and structures we see in surface outcrops have not been integrated directly into predictive numerical and analogue models. As a result, models created to simulate mesoscale geology are currently not well calibrated to natural datasets and it is therefore difficult to demonstrate even partial confirmation of predictive, three dimensional (3D) models. This creates significant problems for industrial users interested in the extraction or storage of fluids in subsurface reservoirs, since accurate predictions of these processes rely critically on a complete 3D understanding of the subsurface mesoscale geology. Terrestrial laser scanners and Real Time Kinematic (RTK) GPS units are the principal tools used to capture digital data from surface outcrops. Automatic data collection involves scanning the outcrop surface with a laser to capture the topography with a cm-spaced grid of spatial coordinates in x,y and z. Using built-in digital cameras, the most recent laser scanners collect registered photographs that allow the software to colour the points to match the outcrop, and produce a photo-realistic 3D image. Laser scanning works best on cliff sections or in mines and quarries where the scanner can be placed directly in front of the outcrop. With RTK GPS data collection, any measurable attribute (surface dip, strike, lithology) can be recorded together with the spatial coordinates at a user-controlled sample spacing down to c. 5 cm. As the method is GPS-based, it works best on sub

  13. Geology of the Greenwater Range, and the dawn of Death Valley, California—Field guide for the Death Valley Natural History Conference, 2013

    Science.gov (United States)

    Calzia, J.P.; Rämö, O.T.; Jachens, Robert; Smith, Eugene; Knott, Jeffrey

    2016-05-02

    Much has been written about the age and formation of Death Valley, but that is one—if not the last—chapter in the fascinating geologic history of this area. Igneous and sedimentary rocks in the Greenwater Range, one mountain range east of Death Valley, tell an earlier story that overlaps with the formation of Death Valley proper. This early story has been told by scientists who have studied these rocks for many years and continue to do so. This field guide was prepared for the first Death Valley Natural History Conference and provides an overview of the geology of the Greenwater Range and the early history (10–0 Ma) of Death Valley.

  14. Past and present of analogue modelling, and its future trend

    Science.gov (United States)

    Koyi, Hemin

    2015-04-01

    Since Hull (1815) published his article on modelling, analogue modelling has expanded to simulate both a wider range of tectonic regimes and target more challenging set-ups, and has become an integrated part of the fields of tectonics and structural geology. Establishment of new laboratories testifies for the increased attention the technique receives. The ties between modellers and field geoscientists have become stronger with the focus being on understanding the parameters that govern the evolution of a tectonic regime and the processes that dominate it. Since the first sand castle was built with damp sand on a beach, sand has proven to be an appropriate material analogue. Even though granular materials is the most widely used analogue material, new materials are also (re)introduced as rock analogues. Emphasis has been on more precise measurements of the mechanical properties of the materials and on minimizing the preparation effects, which have a great impact on scaling, interpretations and benchmarking. The analytical technique used to quantify model results has also seen a great deal of improvement. In addition to X-ray tomography used to visualise internal structures of models, new techniques (e.g. PIV, high-resolution laser scanning, and interferometry) have enabled monitoring kinematics with a higher precision. Benchmarking exercises have given modelling an additional checking tool by outlining, in addition to the rheology of the modelling materials, the impact of different preparation approaches, the effect of boundary conditions, and the human factor on model results. However, despite the different approaches and deformation rigs, results of models of different tectonic laboratories have shown a great deal of similarities. Even with the introduction of more sophisticated numerical codes and usage of more powerful computers which enable the simulation of more challenging material properties and combinations of those, and 3D model set-up, analogue modelling

  15. ECONOMIC GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2015-01-01

    20152392 Geng Shufang(Institute of Geology,Chinese Academy of Geological Sciences,Beijing 100037,China);Liu Ping Deep Geological Structure Constraints on Shallow Geology and Mineralization:A Study in the Land and Sea Areas of East China(Marine Geology&Quaternary Geology,ISSN0256-1492,CN37-1117/P,34(6),2014,p.49-61,8illus.,13refs.,with English abstract)

  16. Analogue MIMO Detection

    Directory of Open Access Journals (Sweden)

    McNamara Darren

    2006-01-01

    Full Text Available In this contribution we propose an analogue receiver that can perform turbo detection in MIMO systems. We present the case for a receiver that is built from nonlinear analogue devices, which perform detection in a "free-flow" network (no notion of iterations. This contribution can be viewed as an extension of analogue turbo decoder concepts to include MIMO detection. These first analogue implementations report reductions of few orders of magnitude in the number of required transistors and in consumed energy, and the same order of improvement in processing speed. It is anticipated that such analogue MIMO decoder could bring about the same advantages, when compared to traditional digital implementations.

  17. Environmental Monitoring, Other - GAMMA_RAY_LOGS_IGS_IN: Wells with Natural Gamma-Ray Logs or Physical Samples in Unconsolidated Sediments in Indiana (Indiana Geological Survey, 1:100,000, Point Shapefile)

    Data.gov (United States)

    NSGIC GIS Inventory (aka Ramona) — GAMMA_RAY_LOGS_IGS_IN.shp shows the locations of the Indiana Geological Survey's natural gamma-ray logs that were collected from 1978 to 2012. It was updated by...

  18. Interpreting Urban Geology.

    Science.gov (United States)

    Hannibal, Joseph Timothy; Schmidt, Mark Thomas

    1991-01-01

    Describes field trips to urban locations for geological instruction. The program was developed by the Cleveland Museum of Natural History. Authors claim these field trips have been an effective and enjoyable way of conveying a wide variety of geological information to participants at all levels and backgrounds and have created favorable publicity.…

  19. Radiometric Dating in Geology.

    Science.gov (United States)

    Pankhurst, R. J.

    1980-01-01

    Described are several aspects and methods of quantitatively measuring geologic time using a constant-rate natural process of radioactive decay. Topics include half lives and decay constants, radiogenic growth, potassium-argon dating, rubidium-strontium dating, and the role of geochronology in support of geological exploration. (DS)

  20. GEOCHRONOMETRY & ISOTOPE GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2004-01-01

    <正>20042213 Chen Qinghua (Department of Geology,Northwest University, Xi’an, Shaanxi); Liu Chiyang The Mathematical Representations and Their Significance of Geological Age with Milankovitch Theory (Journal of Northwest University (Natural Science Edition), ISSN1000 - 274X, CN61 -1072/N, 33(5), 2003, p. 599-602, 27 refs. )

  1. Plant Distribution and Habitat, Non-Agriculture - NATURAL_FEATURES_USGS_IN: Natural Features in Indiana (U.S. Geological Survey, 1:24000, Point Shapefile)

    Data.gov (United States)

    NSGIC GIS Inventory (aka Ramona) — Natural_features_usgs_in is a point shapefile showing the locations and attribute values of natural features extracted from the Geographic Names Information System...

  2. GEOTHERMICS GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2014-01-01

    <正>20140958 Mei Huicheng(No.915GeologicalBrigade,Jiangxi Bureau of Geology and Mineral Resources,Nanchang 330002,China);Li Zhongshe Geological Features and Causes of the Huihuang Geotherm in Xiushui,Jiangxi Province(Journal of Geological Hazards and

  3. MATHEMATICAL GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2009-01-01

    <正>20090700 Chen Anshu(Tianjin Institute of Geology and Mineral Resources,China Geological Survey,Tianjin 300170,China);Li Xiaoguang 1:250 000-Scale Regional Geological Map Spatial Database(Geological Survey and Research,ISSN1672-4135,CN12-1353/P,31(1),2008,p.64-69,2 illus.,2 tables,5 refs.)

  4. ECONOMIC GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2014-01-01

    <正>20140805Fan Baocheng(Xi’an Center of Geological Survey,China Geology Survey,Xi’an710054,China);Meng Guanglu The Geological Evolution and Metallization of TalasKalatawu Block in Northern Tianshan,Kyrgyzstan(Northwestern Geology,ISSN1009-6248,CN61-1149/P,46(2),2013,p.54-

  5. The Greenland Analogue Project. Yearly Report 2009

    Energy Technology Data Exchange (ETDEWEB)

    2010-12-15

    A deep geological repository for spent nuclear fuel needs to be designed to keep used nuclear fuel isolated from mankind and the environment for a million years. Within this time frame glacial conditions are expected in regions that have been glaciated in the past two to ten million years. Climate induced changes such as the growth of ice sheets and permafrost will influence and alter the ground surface and subsurface environment, including its hydrology, which may impact repository safety. Glaciation impact assessments have to-date used over-simplified models and conservative assumptions, for example in the representation of ice sheet hydrology, that do not reflect the complexity of natural systems and processes. This is largely due to lack of direct observations of such processes from existing ice sheets, which if more readily available could help reduce uncertainties and provide a strong scientific basis for the treatment of glacial impacts in safety assessments. Our current understanding of the hydrological, hydrogeological and hydrogeochemical processes associated with glacial cycles and their impact on the long-term performance of deep geological repositories for spent nuclear fuel will be significantly improved by studying a modern analogue. To advance the understanding of processes associated with glaciation and their impact on the long-term performance of a deep geological repository, the Greenland Analogue Project (GAP), a four-year field and modelling study of the Greenland ice sheet and sub-surface conditions, has been initiated collaboratively by SKB, Posiva and NWMO. The study site encompasses a land terminus portion of the Greenland ice sheet east of Kangerlussuaq and is in many ways considered to be an appropriate analogue of the conditions that are expected to prevail in much of Canada and Fennoscandia during future glacial cycles. The project is planned to run from 2009 until 2012. The GAP will conduct the first in situ investigations of some of

  6. ENVIRONMENTAL GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    <正>20071510 Chen Ge(No.282 Geological Par- ty,Geological Bureau of Sichuan Nuclear In- dustry,Deyang,Sichuan 618000)Assess- ment of Geological Hazards in the Sichuan Sector of the Nanchong-Wanzhou 500 KV Transmisson Line Engineering(Acta Geolog- ica Sichuan,ISSN 1006-0995,CN 51- 1273/P,26(2),2006,p.88-93,2 tables) Key words:geologic hazards,construction field,Sichuan Province Possibility of inducing and intensifying geological hazards by the Nanhong- Wanzhou 500 KV transmission line engineer- ing,geological hazards which probably occur

  7. [GEOLOGICAL OVERVIEW OF THE VILNIUS REGION BY J. E. GILIBERT (1741-1814), THE FIRST PROFESSOR OF NATURAL HISTORY AT THE UNIVERSITY OF VILNIUS].

    Science.gov (United States)

    Tarkowski, Radosław

    2015-01-01

    In 1775-1783, Jean-Emmanuel Gilibert (1741-1814) stayed in Respublica Poloniae to oranize a veterinary school, the Royal Botanic Garden and the Royal School of Physicians in Grodno, and since 1781 he worked in Vilnius as Professor of Natural History at the Principal School of the Grand Duchy of Lithuania. Little is known about his work conducted in Lithuania in the field of geology and earth sciences. The author has decided, on the basis of Gilibert's publications and analysis of the literature (works of J. Garbowska and P. Daszkiewicz and others), to present his teaching and research activities in this field. In Grodno, Gilibert looked after and multiplied the collections of the natural history cabinet at the Royal School of Physicians, renowned for its rich mineralogical and fossil collections watched and admired by, among others, King Stanisław August, J. Bernoulli (1744-1807) and M. Patrin (1742-1815) who mentions the amber rosary with a different species of insects preserved in each bead. Gilibert's tours around Lithuania were the opportunity to enlarge the geological collections and to adapt them to the needs of the school. He also appreciated the importance of ordinary specimens representing the geology of the area. These specimens not only enriched the natural history cabinet, but also defined the way of working and collecting. Ha was the first to found and gather fossil animals from near Grodno. The signs of mineralogical and geological interests of Gilibert can be found in the works of other authors of that epoch (L. Viteta (1736-1809) and J. Bernoulli). In Vilnius, Gilibert conducted a one year-long full lecture on natural history (zoology, botany and mineralogy). In his lectures on mineralogy, he presented not only the systematics, but also emphasized the usefulness of minerals in medicine, for the production of ornamental items and in different sectors of the economy. He adapted the process of teaching to the needs of practical life, based on

  8. Methods of seismic zone localization in the highly stressed geological environment in mining natural-engineering system

    Science.gov (United States)

    Kozyrev, A.; Fedotova, Iu.; Zhuravleva, O.

    2012-04-01

    During developing mineral deposits in the geological environment the anomalous energy-saturated zones (parts of highly stressed rocks) are being formed. As a result in the rock mass rockbursts and mining-induced earthquakes occur. The largest mining-induced earthquakes (M 4.0 - 4.2) were registered at the mines of the Khibiny and Lovozersky massifs of the Kola Peninsula. The energy-saturated zones migrate subject to displacement of front of working faces. Location and dimensions of the zones are estimated according to data of analytical investigations and experimental determinations in the rock mass. In some cases (for example, when developing blocks-pillars and transition zones between open and underground mining operations or adjacent mines) all the mining area is a united energy-saturated zone, where the main problems occur concerning mining workings stability management, and under rockbursts hazardous conditions there occur problems concerning mining-induced seismicity manifestations. Parameters of geological environment seismic emission are objective indicators of geological environment energy-saturation. The assessment of their changing is a basis of methods of seismic zones localization and detection of their migration during mining operations development. To assess a current state and determine conditions of transition of geological environment parts into the critical state there carried out investigations concerning space-time regularities of rock mass seismicity parameters changing in the mines' geomechanical space. The following parameters are considered as characteristics of rock mass seismicity: fractal criterion, dip angle criterion for seismic events recurrence graph, concentration criterion, and criterion of fissures' average length. A complex assessment of single parameters range is applied to get the better results. The analysis also takes into account influence of deterministic factors: fracture disturbances and stope face boundaries. Analysis

  9. The structure activity relationship of discodermolide analogues.

    Science.gov (United States)

    Shaw, Simon J

    2008-03-01

    The marine polyketide discodermolide is a member of a class of natural products that stabilize microtubules. Many analogues have been synthesized suggesting that few changes can be made to the internal carbon backbone. Both ends of the molecule, however, can be modified. The majority of analogues have been generated via modification of the lactone region. This suggests that significant simplifications can be made in this region provided that the lactone moiety is maintained.

  10. U.S. Geological Survey natural hazards science strategy: promoting the safety, security, and economic well-being of the Nation

    Science.gov (United States)

    Holmes, Jr., Robert R.; Jones, Lucile M.; Eidenshink, Jeffery C.; Godt, Jonathan W.; Kirby, Stephen H.; Love, Jeffrey J.; Neal, Christina A.; Plant, Nathaniel G.; Plunkett, Michael L.; Weaver, Craig S.; Wein, Anne; Perry, Suzanne C.

    2013-01-01

    The mission of the U.S. Geological Survey (USGS) in natural hazards is to develop and apply hazard science to help protect the safety, security, and economic well-being of the Nation. The costs and consequences of natural hazards can be enormous, and each year more people and infrastructure are at risk. USGS scientific research—founded on detailed observations and improved understanding of the responsible physical processes—can help to understand and reduce natural hazard risks and to make and effectively communicate reliable statements about hazard characteristics, such as frequency, magnitude, extent, onset, consequences, and where possible, the time of future events. To accomplish its broad hazard mission, the USGS maintains an expert workforce of scientists and technicians in the earth sciences, hydrology, biology, geography, social and behavioral sciences, and other fields, and engages cooperatively with numerous agencies, research institutions, and organizations in the public and private sectors, across the Nation and around the world. The scientific expertise required to accomplish the USGS mission in natural hazards includes a wide range of disciplines that this report refers to, in aggregate, as hazard science. In October 2010, the Natural Hazards Science Strategy Planning Team (H–SSPT) was charged with developing a long-term (10–year) Science Strategy for the USGS mission in natural hazards. This report fulfills that charge, with a document hereinafter referred to as the Strategy, to provide scientific observations, analyses, and research that are critical for the Nation to become more resilient to natural hazards. Science provides the information that decisionmakers need to determine whether risk management activities are worthwhile. Moreover, as the agency with the perspective of geologic time, the USGS is uniquely positioned to extend the collective experience of society to prepare for events outside current memory. The USGS has critical

  11. Ecstasy analogues found in cacti.

    Science.gov (United States)

    Bruhn, Jan G; El-Seedi, Hesham R; Stephanson, Nikolai; Beck, Olof; Shulgin, Alexander T

    2008-06-01

    Human interest in psychoactive phenethylamines is known from the use of mescaline-containing cacti and designer drugs such as Ecstasy. From the alkaloid composition of cacti we hypothesized that substances resembling Ecstasy might occur naturally. In this article we show that lophophine, homopiperonylamine and lobivine are new minor constituents of two cactus species, Lophophora williamsii (peyote) and Trichocereus pachanoi (San Pedro). This is the first report of putatively psychoactive phenethylamines besides mescaline in these cacti. A search for further biosynthetic analogues may provide new insights into the structure-activity relationships of mescaline. An intriguing question is whether the new natural compounds can be called "designer drugs."

  12. The effects of conducting authentic field-geology research on high school students' understanding of the nature of science, and their views of themselves as research scientists

    Science.gov (United States)

    Millette, Patricia M.

    Authentic field geology research is a inquiry method that encourages students to interact more with their local environment, and by solving genuine puzzles, begin to increase their intuitive understanding of the nature and processes of science. The goal of the current study was to determine if conducting authentic field research and giving high school students the opportunity to present findings to adult audiences outside of the school setting 1) enhances students' understanding of the nature of science, and 2) affects students views of themselves as researchers. To accomplish this, ninth-grade students from a public school in northern New England engaged in a community-initiated glacial geology problem, completed a field research investigation, and presented their findings at several professional conferences. Following the completion of this student-centered field research, I investigated its effects by using a mixed methods approach consisting of qualitative and quantitative data from two sources. These included selected questions from an open-response survey (VNOS-c), and interviews that were conducted with fifteen of the students of different ages and genders. Findings show that conducting original field research seems to have a positive influence on these students' understanding of the NOS as well as the processes of science. Many of the students reported feelings of accomplishment, acceptance of responsibility for the investigation, a sense of their authentic contribution to the body of scientific knowledge in the world, and becoming scientists. This type of authentic field investigation is significant because recent reforms in earth-science education stress the importance of students learning about the nature and processes of scientific knowledge along with science content.

  13. MATHEMATICAL GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2014-01-01

    <正>20141243Chen Ge(Hangzhou Research Institute of Petroleum Geology,PetroChina,Hangzhou 310023,China);Si Chunsong Study on Sedimentary Numerical Simulation Method of Fan Delta Sand Body(Journal of Geology,

  14. Engineering Geology.

    Science.gov (United States)

    Ivey, John B.

    1983-01-01

    Engineering geology activities in government and the private sector are highlighted. Also highlighted are conferences in this field, awards presented at conferences (including an award to an undergraduate geology student), and a new publication "Geotechnology in Massachusetts." (JN)

  15. Carcinogenicity of insulin analogues

    NARCIS (Netherlands)

    Braak, Sebastiaan Johannes ter

    2015-01-01

    There is epidemiological evidence that the use of some insulin analogues by diabetic patients is correlated with an increased cancer risk. In vitro exposure experiments revealed that insulin glargine (LANTUS) was the only commercial insulin analogue with an increased mitogenic potential. In the huma

  16. Survey of analogue spacetimes

    CERN Document Server

    Visser, Matt

    2013-01-01

    Analogue spacetimes, (and more boldly, analogue models both of and for gravity), have attracted significant and increasing attention over the last decade and a half. Perhaps the most straightforward physical example, which serves as a template for most of the others, is Bill Unruh's model for a dumb hole, (mute black hole, acoustic black hole), wherein sound is dragged along by a moving fluid --- and can even be trapped behind an acoustic horizon. This and related analogue models for curved spacetimes are useful in many ways: Analogue spacetimes provide general relativists with extremely concrete physical models to help focus their thinking, and conversely the techniques of curved spacetime can sometimes help improve our understanding of condensed matter and/or optical systems by providing an unexpected and countervailing viewpoint. In this introductory chapter, I shall provide a few simple examples of analogue spacetimes as general background for the rest of the contributions.

  17. ENVIRONMENTAL GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2016-01-01

    20160639Cai Wutian(Center for Hydrogeology a nd Environmental Geology Survey,China Geological Survey,Baoding071051,China)Several Issues on Contaminated Sites(Hydrogeology and Engineering Geology,ISSN1000-3665,CN11-2202/P,42(1),2015,p.123

  18. MATHEMATICAL GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2014-01-01

    <正>20142560Hu Hongxia(Regional Geological and Mineral Resources Survey of Jilin Province,Changchun 130022,China);Dai Lixia Application of GIS Map Projection Transformation in Geological Work(Jilin Geology,ISSN1001-2427,CN22-1099/P,32(4),2013,p.160-163,4illus.,2refs.)

  19. MATHEMATICAL GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    <正>20081307 Cao Xiping(Geological Museum of China,Beijing 100034)Discussion on the Digitization of Geological Specimen Information and Digital Geological Museum Construction(Acta Geoscientica Sinica,ISSN1006-3021,CN11-3474/P,28(2),2007,p.205-208,1 illus.,1 table,4 refs.)

  20. MATHEMATICAL GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2015-01-01

    20152086 Liu Lei(Shandong Zhengyuan Geo-logical Exploration Institute,China Metallurgical Geology Bureau,Jinan 250101,China)Comparison of Gridding Effect of MapGIS Software(Contributions to Geology and Mineral Resources Research,ISSN1001-1412,CN12

  1. MATHEMATICAL GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2009-01-01

    <正>20091383 Cui Yiwen(First Geology and Mineral Resources Prospecting Team of Qinghai Province,Ping’an 810600,China);Zhang Liling Quaternary Three-Dimensional Model of Geological Structures of Changchun City(Jilin Geology,ISSN1001-2427,CN22 -1099/P,27(2),2008,p.125-130,10 illus.,4 tables,14 refs.,with English abstract)

  2. ECONOMIC GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2013-01-01

    <正>20132393 Lü Guxian(Institute of Geomechanics,Chinese Academy of Geological Sciences,Beijing 100081,China);Li Xiuzhang Research and Development of Orefield Geology(Geology and Prospecting,ISSN0495-5331,CN11-2043/P,48(6),2012,p.1143-1150,3illus.,1table,46refs.)Key words:study of mineral deposit

  3. ECONOMIC GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2015-01-01

    20150901Dai Chuangu(Guizhou Academy of Geologic Survey,Guiyang550005,China);Zheng Qiqian Geological Background Study of Metallogenic in Haixi-Yanshan Tectonic Cycle in Guizhou Province(Guizhou Geology,ISSN1000-5943,CN52-1059/P,31(2),2014,p.82-88,3illus.,2tables,13refs.)Key words:metallogenesis,metallogenic area,

  4. ECONOMIC GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2016-01-01

    20160938Gao Xiaowei(Wuhan Center of Geo-logical Survey,China Geological Survey,Wuhan 430223,China);Wu Xiurong Two Types of Terrain and Regional Mineralization in Sumatra,Indonesia(Geological Bulletin of China,ISSN1671-2552,CN11-4648/P,34

  5. ECONOMIC GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2016-01-01

    20160276Jiang Hanbing(Xi’an Institute of Geology and Mineral Resources,Xi’an710054,China);Yang Hequn The Metallogenic Series Family of Geological Formation in Dunhuang Metallogenetic Belt(Northwestern Geology,ISSN1009-6248,CN61-1149/P,48(1),2015,p.63-71,2illus.,2tables,28refs.)

  6. "One-shot" analysis of PDE-5 inhibitors and analogues in counterfeit herbal natural products using an LC-DAD-QTOF system.

    Science.gov (United States)

    Bortolini, Claudio; Pivato, Antonio; Bogialli, Sara; Pastore, Paolo

    2015-08-01

    A highly selective and robust method for simultaneous screening and confirmation of target and non-target phosphodiesterase type 5 (PDE-5) inhibitor analogues within a single chromatographic run in counterfeit herbal products was developed. The protocol, based on an easy and rapid extraction with a water/acetonitrile 1 % formic acid solution, followed by sonication and centrifugation, exploits an LC-diode array detector-quadrupole-time-of-flight (DAD-QTOF) system. The extraction method was optimized both at high concentrations and at trace levels. These two situations are typically encountered in pharmaceutical formulations and herbal food supplements. Carryover effects, never reported before and occurring mainly for vardenafil, were overcome using a polymer-based column. An in-house validation was carried out using five blanks of different bulk matrices spiked with seven standard analytes, namely yohimbine, sildenafil, vardenafil, tadalafil, homosildenafil, pseudovardenafil and hydroxyhomovardenafil. Reliable quantitation was possible using a conventional standard solution for all the pharmaceutical and herbal samples considered, as matrix effects were eliminated. Accuracy ranged from 80.9 to 108.1 % with overall relative standard deviation (RSD) products marketed for the erectile dysfunction.

  7. Nature of the lowest electron transitions in styryl bases benzothiazole derivatives and analogues bearing para-methoxy and -trifluoromethyl substituents in phenylyne moiety

    Science.gov (United States)

    Navozenko, O. M.; Naumenko, A. P.; Yashchuk, V. M.; Bricks, J. L.; Slominskii, Yu. L.; Ryabitskii, A. B.; Kachkovsky, O. D.

    2016-06-01

    Combined quantum-chemical and spectral investigation of cyanine bases derivatives of thiastyryls as well as their analogues with dimethylamino, metoxy and trifluorine-methyl substituents has been fulfilled. The calculations have shown that going from cationic styryl/metoxystyryl to the corresponding neutral bases is accompanied by substantial change of the equilibrium molecular geometry and charge distribution at atoms, while the experimental absorption band undergoes the essential hypsochromic shift. It is established that introducing on the donor groups in the bases causes negligible change of the carbon-carbon bond and atomic charges in the main chromophore, in contrast to the substantial changes of the magnitude and direction state dipole moments in both ground and excited states. It is found that the bases with the donor groups in benzthiazole moiety and with acceptor CF3 substituent demonstrate the inversion of the direction of the dipole moment. Based on the spectral and quantum-chemical study, one has proposed that some widening of the spectral bands is connected with the vibronic interaction, not with the second electron transition.

  8. A stereodivergent strategy for the preparation of corynantheine and ipecac alkaloids, their epimers, and analogues: efficient total synthesis of (-)-dihydrocorynantheol, (-)-corynantheol, (-)-protoemetinol, (-)-corynantheal, (-)-protoemetine, and related natural and nonnatural compounds.

    Science.gov (United States)

    Zhang, Wei; Bah, Juho; Wohlfarth, Andreas; Franzén, Johan

    2011-12-01

    Here we present a general and common catalytic asymmetric strategy for the total and formal synthesis of a broad number of optically active natural products from the corynantheine and ipecac alkaloid families, for example, indolo[2,3-a]- and benzo[a]quinolizidines. Construction of the core alkaloid skeletons with the correct absolute and relative stereochemistry relies on an enantioselective and diastereodivergent one-pot cascade sequence followed by an additional diastereodivergent reaction step. This allows for enantio- and diastereoselective synthesis of three out of four possible epimers of the quinolizidine alkaloids that begin from common and easily accessible starting materials by using a common synthetic route. Focus has been made on excluding protecting groups and limiting isolation and purification of synthetic intermediates. This methodology is applied in the total synthesis of the natural products (-)-dihydrocorynantheol, (-)-hirsutinol, (-)-corynantheol, (-)-protometinol, (-)-dihydrocorynantheal, (-)-corynantheal, (-)-protoemetine, (-)-(15S)-hydroxydihydrocorynantheol, and an array of their nonnatural epimers. The potential of this strategy is also demonstrated in the synthesis of biologically interesting natural product analogues not accessible through synthetic elaboration of alkaloid precursors available from nature, for example, thieno[3,2-a]quinolizidine derivatives. We also report the formal synthesis of (+)-dihydrocorynantheine, (-)-emetine, (-)-cephaeline, (-)-tubulosine, and (-)-deoxytubulosine.

  9. ECONOMIC GEOLOGY (5)GEOTHERMICS GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    <正>20071202 Bai Fu(Second Prospecting Insti- tute of Geology and Mineral Resources of the Gansu Bureau of Geology and Mineral Re- sources,Lanzhou 730020,China);Ma Genxi Analysis of the Occurrence of the Geother- mal Resources in Lanzhou,Gansu Province (Hydrogeology & Engineering Geology,

  10. Vesta's north pole quadrangle Av-1 (Albana): Geologic map and the nature of the south polar basin antipodes

    Science.gov (United States)

    Blewett, David T.; Buczkowski, Debra L.; Ruesch, Ottaviano; Scully, Jennifer E.; O'Brien, David P.; Gaskell, Robert; Roatsch, Thomas; Bowling, Timothy J.; Ermakov, Anton; Hiesinger, Harald; Williams, David A.; Raymond, Carol A.; Russell, Christopher T.

    2014-12-01

    As part of systematic global mapping of Vesta using data returned by the Dawn spacecraft, we have produced a geologic map of the north pole quadrangle, Av-1 Albana. Extensive seasonal shadows were present in the north polar region at the time of the Dawn observations, limiting the ability to map morphological features and employ color or spectral data for determination of composition. The major recognizable units present include ancient cratered highlands and younger crater-related units (undivided ejecta, and mass-wasting material on crater floors). The antipode of Vesta's large southern impact basins, Rheasilvia and Veneneia, lie within or near the Av-1 quadrangle. Therefore it is of particular interest to search for evidence of features of the kind that are found at basin antipodes on other planetary bodies. Albedo markings known as lunar swirls are correlated with basin antipodes and the presence of crustal magnetic anomalies on the Moon, but lighting conditions preclude recognition of such albedo features in images of the antipode of Vesta's Rheasilvia basin. “Hilly and lineated terrain,” found at the antipodes of large basins on the Moon and Mercury, is not present at the Rheasilvia or Veneneia antipodes. We have identified small-scale linear depressions that may be related to increased fracturing in the Rheasilvia and Veneneia antipodal areas, consistent with impact-induced stresses (Buczkowski, D. et al. [2012b]. Analysis of the large scale troughs on Vesta and correlation to a model of giant impact into a differentiated asteroid. Geol. Soc. of America Annual Meeting. Abstract 152-4; Bowling, T.J. et al. [2013]. J. Geophys. Res. - Planets, 118. http://dx.doi.org/10.1002/jgre.20123). The general high elevation of much of the north polar region could, in part, be a result of uplift caused by the Rheasilvia basin-forming impact, as predicted by numerical modeling (Bowling, T.J. et al. [2013]. J. Geophys. Res. - Planets, 118. http://dx.doi.org/10.1002/jgre

  11. Nature and distribution of geological domains at the Africa-Eurasia plate boundary off SW Iberia and regional geodynamic implications

    Science.gov (United States)

    Martínez-Loriente, Sara; Sallarès, Valentí; Gràcia, Eulàlia; Bartolome, Rafael

    2014-05-01

    We present a new classification of geological domains at the Africa-Eurasia plate boundary off SW Iberia, together with a regional geodynamic reconstruction spanning from the Mesozoic extension to the Neogene-to-present-day convergence. It is based on seismic velocity and density models along two regional wide-angle seismic transects, one running NW-SE from the Horseshoe to the Seine abyssal plains, and the other running N-S from S Portugal to the Seine Abyssal Plain, combined with previously available information. The seismic velocity and density structure at the Seine Abyssal Plain and the internal Gulf of Cadiz indicates the presence of a highly heterogeneous oceanic crust, similar to that described in ultra-slow spreading centers, whereas in the Horseshoe and Tagus abyssal plains, the basement structure resembles that of exhumed mantle sections identified in the Northern Atlantic margin. The integration of all this new information allows defining the presence of three oceanic domains offshore SW Iberia: (1) the Seine Abyssal Plain domain, generated during the first stages of slow seafloor spreading in the NE Central Atlantic (Early Jurassic); (2) the Gulf of Cadiz domain, made of oceanic crust generated in the Alpine-Tethys spreading system between Iberia and Africa, which was coeval with the formation of the Seine Abyssal Plain domain and lasted up to the North Atlantic continental break-up (Late Jurassic); and (3) the Gorringe Bank domain, mainly made of rocks exhumed from the mantle with little synchronous magmatism, which formed during the first stages of North Atlantic opening. Our models suggest that the Seine Abyssal Plain and Gulf of Cadiz domains are separated by the Lineament South strike-slip fault, whereas the Gulf of Cadiz and Gorringe Bank domains appear to be limited by a deep thrust fault located at the center of the Horseshoe Abyssal Plain. The formation and evolution of these three domains during the Mesozoic is key to understand the sequence

  12. Assessing understanding of the nature of science and science self-efficacy in undergraduates involved in research in an introductory geology course

    Science.gov (United States)

    Moss, Elizabeth Louise

    As part of a campus-wide effort to transform introductory science courses to be more engaging and to more accurately convey the excitement of discovery in science, we have re-created the curriculum of our introductory geology lab. We have transformed what was a series of `cookbook' lab activities into a series of activities based in scientific inquiry and cooperative learning and have included a six-week, student driven research project focused on local groundwater and surface water issues, seeking to determine whether or not this new curriculum was an effective means to increase students' understanding of the nature of science and self-efficacy towards science. In addition to developing the research project curriculum, we worked with other university faculty to create a local hydrology research station which included eight monitoring wells and a stream gage, allowing students to collect their own water-level and water-quality data as well as to retrieve automatically collected data. In order to measure nature of science understanding, we used a modified version of the Student Understanding of Science and Scientific Inquiry questionnaire (Liang et al., 2005; Clough, 2010). We modified a vocational self-efficacy survey (Riggs et al. 1994) to measure science self-efficacy. Both instruments had average Cronbach's alpha values >0.8, making them reliable for our study. After three semesters of collecting data, we have found that an authentic research project slightly improves, but does not significantly increase overall nature of science understanding or science self-efficacy. Dis-aggregating the data into demographic sub-groups, nature of science understanding increased relatively more in non-STEM students than STEM students, and science self-efficacy increased relatively more in STEM students than non-STEM students. We also measured changes in students' understanding of geologic concepts in the Fall 2011 and Spring 2012 semesters. We gave students enrolled in the lab

  13. HISTORICAL GEOLOGY & STRATIGRAPHY

    Institute of Scientific and Technical Information of China (English)

    2004-01-01

    <正>20042202 Chen Gang (Department of Geology, Northwest University, Xi’an, Shaanxi); Zhao Zhongyuan Natural of Pre-Mesozoic Tectono-Lithostratigraphic Units of North -Huaiyang Belt and Implication for Tectonic Evolution (Journal of Northwest University (Natural Science Edition), ISSN 1000-274X, CN61-1072/N, 33(5), 2003, p. 595 -598, 1 table, 14 refs. )

  14. Petroleum geology of North Africa

    Energy Technology Data Exchange (ETDEWEB)

    MacGregor, D.S. [ed.] [BP Exploration Operating Co. Ltd., Jakarta (Indonesia); Moody, R.T.J. [ed.] [Moody-Sandman Associates, Kingston (United Kingdom); Clark-Lowes, D.D. [ed.] [University of London (United Kingdom). Imperial College of Science, Technology and Medicine

    1998-12-31

    North Africa contains some 4% of the world`s remaining oil and gas reserves, and is now one of the most active exploration areas. This volume represents the first attempt at a compilation of the petroleum geology of North Africa, documenting a series of papers collected on the petroleum geology of Morocco, Algeria, Tunisia, Libya and the western part of Egypt. The main objectives of this book are to increase the level of documentation towards that appropriate for such major petroleum provinces and to facilitate the application of analogues between North African countries and beyond. (author)

  15. Reflectance spectroscopy of natural organic solids, iron sulfides and their mixtures as refractory analogues for Rosetta/VIRTIS' surface composition analysis of 67P/CG

    Science.gov (United States)

    Moroz, Lyuba V.; Markus, Kathrin; Arnold, Gabriele; Henckel, Daniela; Kappel, David; Schade, Ulrich; Rousseau, Batiste; Quirico, Eric; Schmitt, Bernard; Capaccioni, Fabrizio; Bockelee-Morvan, Dominique; Filacchione, Gianrico; Érard, Stéphane; Leyrat, Cedric; VIRTIS Team

    2016-10-01

    Analysis of 0.25-5 µm reflectance spectra provided by the Visible and InfraRed Thermal Imaging Spectrometer (VIRTIS) onboard Rosetta orbiter revealed that the surface of 67P/CG is dark from the near-UV to the IR and is enriched in refractory phases such as organic and opaque components. The broadness and complexity of the ubiquitous absorption feature around 3.2 µm suggest a variety of cometary organic constituents. For example, complex hydrocarbons (aliphatic and polycyclic aromatic) can contribute to the feature between 3.3 and 3.5 µm and to the low reflectance of the surface in the visible. Here we present the 0.25-5 µm reflectance spectra of well-characterized terrestrial hydrocarbon materials (solid oil bitumens, coals) and discuss their relevance as spectral analogues for a hydrocarbon part of 67P/CG's complex organics. However, the expected low degree of thermal processing of cometary hydrocarbons (high (H+O+N+S)/C ratios and low carbon aromaticities) suggests high IR reflectance, intense 3.3-3.5 µm absorption bands and steep red IR slopes that are not observed in the VIRTIS spectra. Fine-grained opaque refractory phases (e.g., iron sulfides, Fe-Ni alloys) intimately mixed with other surface components are likely responsible for the low IR reflectance and low intensities of absorption bands in the VIRTIS spectra of the 67P/CG surface. In particular, iron sulfides are common constituents of cometary dust, "cometary" chondritic IDPs, and efficient darkening agents in primitive carbonaceous chondrites. Their effect on reflectance spectra of an intimate mixture is strongly affected by grain size. We report and discuss the 0.25-5 µm reflectance spectra of iron sulfides (meteoritic troilite and several terrestrial pyrrhotites) ground and sieved to various particle sizes. In addition, we present reflectance spectra of several intimate mixtures of powdered iron sulfides and solid oil bitumens. Based on the reported laboratory data, we discuss the ability of

  16. STRUCTURAL GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2014-01-01

    <正>20141912Cao Hui(State Key Laboratory for Continental Tectonics and Dynamics,Institute of Geology,Chinese Academy of Geological Sciences,Beijing 100037,China)Gravitational Collapse and Folding during Orogenesis:A Comparative Study of FIA Trends and Fold Axial Plane Traces(Geology in China,ISSN1000-3657,CN11-1167/P,40(6),2013,p.1818-1828,9illus.,35refs.,with

  17. GENERAL GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    <正>20071601 Yin Yanhong (Qingdao Institute of Marine Geology, Qingdao 266071, China); Sun Jiashi Discovery of Qingdao Iron Meteorite and Its Chemical Composition and Mineralogy (Marine Geology & Quaternary Geology, ISSN0256-1492, CN37-1117/P, 26(3), 2006, p.121-124, 3 illus., 2 tables, 9 refs.)Key words: iron meteorites, Shandong Province The Qingdao iron meteorite was found in May, 2004.

  18. MATHEMATICAL GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    <正>20070721 Dong Yaosong (National Key La-boratory of Geological Process and Mineral resources, Institute of Mathematical Geology and Remote Sensing, China University of Geosciences, Wuhan 430074, China); Yang Yanchen Mutual Compensation of Nerval Net and Characteristic Analysis in Mineral Resources Exploration (Mineral Resources and Geology, ISSN1001-5663, CN45-1174/TD, 20(1), 2006, p.1-6, 3 illus., 6 tables, 5 refs.) Key words: prospecting and exploration of mineral, neural network systems

  19. ENVIRONMENTAL GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    <正>20072222 Cao Xiuding(Chengdu University of Technology,Chengdu 610059,China);Qin Guoqing General Packet Radio Service(GPRS)Technology and Its Application in Geological Hazard Monitoring(The Chinese Journal of Geological Hazard and Control,ISSN1003-8035,CN11-2852/P,17(1),2006,p.69-72,76,2 illus.,3 refs.)Key words:geologic hazards

  20. STRUCTURAL GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2012-01-01

    <正>20122174 Bai Daoyuan ( Institute of Geological Survey of Hunan Province,Changsha 410011,China );Jia Baohua Neoproterozoic TectonicEvolution of the Xuefeng Orogenic Zone in Hunan Province ( Sedimentary Geology and Tethyan Geology,ISSN1009-3850,CN51-1593 / P,31 ( 3 ), 2011,p.78-87,2illus.,1 table,96refs. ) Key words:structural evolution,Neoproterozoic Era,Hunan Province This paper deals,on the basis of abundant lithogeochemical and geochronologic

  1. ENVIRONMENTAL GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2004-01-01

    <正>20041748 Chen Liang (China University of Geosciences, Nanjing , Jiangsu); Meng Gao-tou Application of Information Model on Geological Hazards Investigating and Zoning of Counties and Cities: Taking Xianju County, Zhejiang Province as an Example (Hydroge-ology & Engineering Geology, ISSN 1000-3665, CN11-2202/P, 30(5), 2003, p. 49 - 52, 4 illus. , 2 tables, 6 refs. ) Key words: geologic hazards, information systems

  2. Antimicrobial evaluation of mangiferin analogues

    Directory of Open Access Journals (Sweden)

    Singh S

    2009-01-01

    Full Text Available The naturally occurring xanthone glycoside mangiferin has been isolated by column chromatography from the ethanol extract of stem bark of Mangifera indica. Mangiferin was further converted to 5-(N-phenylaminomethylenomangiferin, 5-(N-p-chlorophenylaminomethyleno mangiferin, 5-(N-2-methylphenylaminomethyleno mangiferin, 5-(N-p-methoxyphenylaminomethyleno mangiferin, 5-(N,N-diphenylaminomethyleno mangiferin, 5-(N--napthylaminomethyleno mangiferin and 5-(N-4-methylphenylaminomethyleno mangiferin. Mangiferin and its analogues were characterized by melting point and R f value determination and through spectral technique like UV, IR, and NMR spectral analysis. The synthesized compounds were screened for antimicrobial activity.

  3. Antimicrobial Evaluation of Mangiferin Analogues

    Science.gov (United States)

    Singh, S. K.; Kumar, Y.; Kumar, S. Sadish; Sharma, V. K.; Dua, K.; Samad, A.

    2009-01-01

    The naturally occurring xanthone glycoside mangiferin has been isolated by column chromatography from the ethanol extract of stem bark of Mangifera indica. Mangiferin was further converted to 5-(N-phenylaminomethyleno)mangiferin, 5-(N-p-chlorophenylaminomethyleno) mangiferin, 5-(N-2-methylphenylaminomethyleno) mangiferin, 5-(N-p-methoxyphenylaminomethyleno) mangiferin, 5-(N, N-diphenylaminomethyleno) mangiferin, 5-(N--napthylaminomethyleno) mangiferin and 5-(N-4-methylphenylaminomethyleno) mangiferin. Mangiferin and its analogues were characterized by melting point and Rf value determination and through spectral technique like UV, IR, and NMR spectral analysis. The synthesized compounds were screened for antimicrobial activity. PMID:20490307

  4. Regional geological framework for exploration of natural gas in the St. Lawrence Lowlands and the Champlain Valley of northeastern New York and Quebec

    Energy Technology Data Exchange (ETDEWEB)

    Rheault, M. [MIR Teledetection Inc., Longueuil, PQ (Canada); Wallach, J. [JL Wallach Geosciences Inc., Russell, ON (Canada); Sejourne, S. [Institut National de la Recherche Scientifique, Ste-Foy, PQ (Canada). Eau, Terre et Environnement

    2002-07-01

    A geoscientific study was conducted in which the latest remote sensing and GIS technologies were used in combination with existing and newly acquired information from reconnaissance-scale geological and geophysical mapping to determine the potential for hydrocarbon plays in northern New York State. The study area is bounded to the east, north and south by Lake Champlain, the Canadian border, and the Grenvillian basement of the Adirondack Dome. This area was chosen because of its stratigraphy and the presence of faults and uplift associated with the Adirondacks, suggesting that it might contain potential reserves of natural gas. Drainage features in the area appear to be associated with geomorphic depressions on top of the bedrock, and are likely basement-controlled fault zones. The linear features generally trend N-S to NNE, and are defined as ridges and streams that correlate well with geophysically expressed lineaments that pass from the Precambrian basement to the top of the Trenton Group. It is believed that these east-dipping lineaments may be potential pathways for the migration and trapping of natural gas. This is supported by the fact that a regional geophysical anomaly is also thought to be associated with a major intrusion. The anomaly is bounded by magnetic discontinuities where earthquakes have been recorded, another indication that the faults are currently active and may be conduits for hydrocarbon fluid flow. 18 refs., 3 tabs., 10 figs.

  5. Identifying sources, formation pathways and geological controls of methane in shallow groundwater above unconventional natural gas plays in Alberta, Canada

    Science.gov (United States)

    Mayer, B.; Humez, P.; Nightingale, M.; Ing, J.; Kingston, A. W.; Clarkson, C.; Cahill, A.; Parker, B. L.; Cherry, J. A.; Millot, R.; Kloppmann, W.; Osadetz, K.; Lawton, D.

    2015-12-01

    With the advent of shale gas development facilitated by hydraulic fracturing it has become increasingly important to develop tracer tools to scientifically determine potential impacts of stray gases on shallow aquifers. To assess potential future impacts on shallow aquifers by leakage of natural gas from unconventional energy resource development, it is essential to establish a reliable baseline. Occurrence of methane in shallow groundwater in Alberta (Canada) between 2006 and 2014 was assessed and was ubiquitous in 186 sampled monitoring wells. Free and dissolved gas sampling and measurement approaches yielded comparable results with often low methane concentrations in shallow groundwater, but in 28 samples methane exceeded 10 mg/L in dissolved gas and 300,000 ppmv in free gas. Methane concentrations in free and dissolved gas samples were found to increase with well depth and were especially elevated in groundwater obtained from aquifers containing coal seams and shale units. Carbon isotope ratios of methane averaged -69.7 ± 11.1 ‰ in free gas and -65.6 ± 8.9 ‰ in dissolved gas. δ13C values were not found to vary with well depth or lithology indicating that the methane in Alberta groundwater was formed via a similar mechanism. The low δ13C values in concert with average δ2H values of -289 ± 44 ‰ suggest that most methane was of biogenic origin predominantly generated via CO2 reduction. This interpretation is confirmed by gas dryness parameters typically >500 due to only small amounts of ethane and a lack of propane in most samples. Novel approaches of in-situ concentration and isotope measurements for methane during drilling of a 530 m deep well yielded a mud-gas profile characterizing natural gas occurrences in the intermediate zone. Comparison with mudgas profile carbon isotope data revealed that methane in the investigated shallow groundwater in Alberta is isotopically similar to hydrocarbon gases found in 100-250 meter depths in the Western

  6. Natural air ventilation in underground galleries as a tool to increase radon sampling volumes for geologic monitoring

    Energy Technology Data Exchange (ETDEWEB)

    Eff-Darwich, Antonio [Departamento de Edafologia y Geologia, Universidad de La Laguna, Av. Astrofisico Francisco, Sanchez s/n, 38206 La Laguna, Tenerife (Spain); Instituto de Astrofisica de Canarias, c/Via Lactea s/n, 38205 La Laguna, Tenerife (Spain)], E-mail: adarwich@ull.es; Vinas, Ronaldo [Departamento de Edafologia y Geologia, Universidad de La Laguna, Av. Astrofisico Francisco, Sanchez s/n, 38206 La Laguna, Tenerife (Spain); Soler, Vicente [Estacion Volcanologica de Canarias, IPNA-CSIC, Av. Astrofisico Francisco Sanchez s/n, 38206 La Laguna, Tenerife (Spain); Nuez, Julio de la; Quesada, Maria L. [Departamento de Edafologia y Geologia, Universidad de La Laguna, Av. Astrofisico Francisco, Sanchez s/n, 38206 La Laguna, Tenerife (Spain)

    2008-09-15

    A simple numerical model was implemented to infer airflow (natural ventilation) in underground tunnels from the differences in the temporal patterns of radon, {sup 222}Rn, concentration time-series that were measured at two distant points in the interior of the tunnels. The main purpose of this work was to demonstrate that the installation of radon monitoring stations closer to the entrance of the tunnels was sufficient to remotely analyse the distribution of radon concentration in their interiors. This could ease the monitoring of radon, since the effective sampling volume of a single monitoring station located closer to the entrance of a tunnel is approximately 30,000 times larger than the sampling volume of a sub-soil radon sensor. This methodology was applied to an underground gallery located in the volcanic island of Tenerife, Canary Islands. This island constitutes an ideal laboratory to study the geo-dynamical behaviour of radon because of the existence of a vast network of galleries that conforms the main water supply of the island.

  7. The intercrater plains of Mercury and the Moon: Their nature, origin and role in terrestrial planet evolution. Geologic map analyses: Correlation of geologic and cratering histories. Ph.D. Thesis

    Science.gov (United States)

    Leake, M. A.

    1982-01-01

    Geologic map analyses are expanded, beginning with a discussion of particular regions which may illustrate volcanic and ballistic plains emplacement on Mercury. Major attention is focused on the surface history of Mercury through discussion of the areal distribution of plains and craters and the paleogeologic maps of the first quadrant. A summary of the lunar intercrater plains formation similarly interrelates the information from the Moon's geologic and cratering histories.

  8. The intercrater plains of Mercury and the Moon: Their nature, origin and role in terrestrial planet evolution. Geologic map analyses: Correlation of geologic and cratering histories. Ph.D. Thesis

    Science.gov (United States)

    Leake, M. A.

    1982-01-01

    Geologic map analyses are expanded, beginning with a discussion of particular regions which may illustrate volcanic and ballistic plains emplacement on Mercury. Major attention is focused on the surface history of Mercury through discussion of the areal distribution of plains and craters and the paleogeologic maps of the first quadrant. A summary of the lunar intercrater plains formation similarly interrelates the information from the Moon's geologic and cratering histories.

  9. GEOTHERMICS GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2013-01-01

    <正>20131683 Lin Wenjing(Institute of Hydrogeology and Environmental Geology,Chinese Academy of Geological Sciences,Shijiazhuang050061,China);Liu Zhiming An Estimation of HDR Resources in China’s Mainland(Acta Geoscientica Sinica,ISSN1006-3021,CN11-3474/P,33(5),2012,p.807-811,2illus.,2tables,14refs.)

  10. GEOTHERMICS GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2013-01-01

    <正>20131088 Fan Difu (Geological Survey of Jiangsu Province , Nanjing 210018 , China ); Xu Xueqiu Origin Study of Geothermal Field in Xiaoyangkou of Rudong County in Jiangsu (Journal of Geology , ISSN1674-3636 , CN32-1796/P , 36 (2), 2012 , p.192-197 , 3illus. , 9refs.) Key words : geothermal fields , Jiangsu Province

  11. GEOTHERMICS GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    <正>20081086 Feng Wujun(Geological Research Institute,Jiangsu Oil Field Branch Company,Yangzhou 225012,Jiangsu);Cao Bing Geoheat Resources Evaluation and Target Optimization in Gaoyou Region of Jiangsu Province(Jiangsu Geology,ISSN1003-6474,CN32-1258/P,31(2),2007,p.130-13

  12. ECONOMIC GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2005-01-01

    <正>20050726 Cheng Jiabai (Survey Team of Huabei Geological Exploration Bureau, Sanhe 065201, China); Zhao Yuanyi Prospecting Hypothesis and Verification (Contributions to Geology and Mineral Resources Research, ISSN 1001-1412, CN12-1131/P, 19(2), 2004, p. 122-129, 2 refs. , with English abstract) Key words: prospecting model

  13. ENVIRONMENTAL GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2013-01-01

    <正>20131925 Chen Ning(State Key Laboratory of Geological Hazards Prevention,Chengdu University of Technology,Chengdu 610059,China);Wang Yunsheng Features and Chains Genesis Analysis of Earthquake Geo-Hazards in Yuzi Stream of Wenchuan County(Journal of Engineering Geology,ISSN1004-9665,CN11-3249/P,20(3),2012,p.340-349,4

  14. STRUCTURAL GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2013-01-01

    <正>20131382 Chen Tao(Key Laboratory of Active Tectonics and Volcano,Institute of Geology,China Earthquake Administration,Beijing 100029,China);Liu Yugang The Activity Age of Tarwan Fault and Genesis of the Topographic Scarp(Seismology and Geology,ISSN0253-4967,CN11-2192/P,34(3),

  15. ENVIRONMENTAL GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2009-01-01

    <正>20090651 Chen Boyang(Fujian Institute of Geological Survey and Research,Fuzhou 350011,China) Bio-Geochemical Characteristics of High and Low-Incidence Area of Stomach Cancer in the Coastal Area of Fujian Province(Geology of Fujian,ISSN1001-3970,CN35-1080/P,27(1),2008,p.29-36,3 tables,6 refs.)

  16. MATHEMATICAL GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2004-01-01

    <正>20040862 Chen Zhihua (Faculty of Engineering, China University of Geosciences, Wuhan, Hubei); Guan Xuefeng Development of DBMS for Environmental Geologic Hazards on WebGIS (Hydrogeology & Engineering Geology, ISSN1000-3665, CN11-2202/P, 30(2), 2003, p. 20-24, 3 illus. , 9 refs. )

  17. STRUCTURAL GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2005-01-01

    <正>20050576 Li Sanzhong (College of Marine Geosciences, Ocean University of China, Qingdao 266003,China) ; Zhou Lihong Cenozoic Faulting and Basin Formation in the Eastern North China Plate (Marine Geology & Quaternary Geology, ISSN 0256 - 1492, CN37 -1117/P, 24(3), 2004, p. 57-66, 5 illus. , 33 refs. ) Key words: tectonic framework, North China

  18. MATHEMATICAL GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2013-01-01

    <正>20131358 Li Jianzhong (State Key Laboratory of Geological Processes and Mineral Resources , School of Earth Sciences and Resources , China University of Geosciences , Beijing 100083 , China); Cui Jing Geological Application of Mult-Idimensional Data Visualization Based on Geometric Coordinate Method (Earth Science Frontiers

  19. ECONOMIC GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2014-01-01

    <正>20142114Lin Quansheng(China University of Geosciences,Bejing 100083,China)On the Geologic Characteristics and Economic Significance of the Cambrian Lintian Group in Fujian Province(Geology of Fujian,ISSN1001-3970,CN35-1080/P,32(4),2013,p.264-273,2illus.,2tables,6refs.)

  20. ECONOMIC GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2014-01-01

    <正>20140227Li Wenyuan(Xi’an Center of Geological Survey,CGS,Xi’an 710054,ChinaThe Continental Growth and Ore-Forming Processes(Northwestern Geology,ISSN1009-6248,CN61-1149/P,46(1),2013,p.1-10,5illus.,18refs.)

  1. ECONOMIC GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2004-01-01

    <正>20041944 Chen Yuchuan (Chinese Academy of Geological Sciences, Beijing) ; Xue Chunli Discussion on the Regional Mineralizing Pedigree of the Ore Deposits in the Northern Margin of the North China Landmass (Geological Journal of China Universities, ISSN 1006-7493, CN32-1440/P, 9(4), 2003, p. 520-535, 2 illus. , 3 tables, 43 refs. ,

  2. Dipeptide analogues containing 4-ethoxy-3-pyrrolin-2-ones

    DEFF Research Database (Denmark)

    Hosseini, Masood; Kringelum, Henriette; Murray, A.;

    2006-01-01

    Pyrrolidine-2,4-diones (1) are naturally occurring analogues of amino acids. We herein present a facile synthesis of N-acylated, O-alkylated pyrrolin-2-ones (2) in high yield and excellent enantiopurity. Molecular mechanics calculations suggest that the resulting dipeptide analogues adopt a linea...

  3. MATHEMATICAL GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2011-01-01

    <正>20111337 Chen Guoxu(Faculty of Earth Resources,China University of Geosciences,Wuhan 430074,China);Wu Chonglong Study on Integration of 3D Geological Modeling and Mineral Resource Exploration Mapping(Geology and Prospecting,ISSN0495-5331,CN11-2043/P,46(3),2010,p.542-546,5 illus.,19 refs.)Key words:geological modeling,digital cartography According to the workflow of traditional methods of mineral reserve estimation,the authors took mine 3D geological modeling and mineral reserve estimation mapping as a starting point to explore a new method for the integration of 3D geological modeling and mineral resource exploration mapping.In order to verify this method,the authors have applied this method to some real mines.The results show that this method can effectively solve those problems of

  4. Alligator rivers analogue project. Final report; volume 1; summary of findings

    Energy Technology Data Exchange (ETDEWEB)

    Duerden, P.; Lever, D.A.; Sverjensky, D.A.; Townley, L.R

    1992-07-01

    The Koongarra uranium ore deposit is located in the Alligator Rivers Region of the Northern Territory of Australia. Many of the processes that have controlled the development of this natural system are relevant to the performance assessment of radioactive waste repositories. An agreement was reached in 1987 by a number of agencies concerned with radioactive waste disposal to set up the International Alligator Rivers Analogue Project (ARAP) to study relevant aspects of the hydrological and geochemical evolution of the site. The Project ran for five years. The aims of the study were: to contribute to the production of reliable and realistic models for radionuclide migration within geological environments relevant to the assessment of the safety of radioactive waste repositories; to develop methods of validation of models using a combination of laboratory and field data associated with the Koongarra uranium deposit; and to encourage maximum interaction between modellers and experimentalists in achieving these objectives. It was anticipated that the substantial databases generated in the field and laboratory studies would then be used to develop and test geochemical and radionuclide transport models. The findings from the technical studies are discussed in the context of assessments of the long-term performance of geological repositories for radioactive wastes, which are being undertaken in many countries. They are also considered in an integrated 'Scenario Development' approach, aimed to understand the formation of the ore deposit. Despite their inherent uncertainties, the findings provide a basis for assessing the way in which radionuclides will migrate in environments with a variety of geologic settings and over a range of different geologic timescales. This summary report, which highlights the work and findings of the Alligator Rivers Analogue Project is one of a series of 16 volumes.

  5. Magnetic fabric analyses in analogue models of clays

    Science.gov (United States)

    García-Lasanta, Cristina; Román-Berdiel, Teresa; Izquierdo-Llavall, Esther; Casas-Sainz, Antonio

    2017-04-01

    Anisotropy of magnetic susceptibility (AMS) studies in sedimentary rocks subjected to deformation indicate that magnetic fabrics orientation can be conditioned by multiple factors: sedimentary conditions, magnetic mineralogy, successive tectonic events, etc. All of them difficult the interpretation of the AMS as a marker of the deformation conditions. Analogue modeling allows to isolate the variables that act in a geological process and to determine the factors and in which extent they influence in the process. This study shows the magnetic fabric analyses applied to several analogue models developed with common commercial red clays. This material resembles natural clay materials that, despite their greater degree of impurities and heterogeneity, have been proved to record a robust magnetic signal carried by a mixture of para- and ferromagnetic minerals. The magnetic behavior of the modeled clay has been characterized by temperature dependent magnetic susceptibility curves (from 40 to 700°C). The measurements were performed combining a KLY-3S Kappabridge susceptometer with a CS3 furnace (AGICO Inc., Czech Republic). The obtained results indicate the presence of an important content of hematite as ferromagnetic phase, as well as a remarkable paramagnetic fraction, probably constituted by phyllosilicates. This mineralogy is common in natural materials such as Permo-Triassic red facies, and magnetic fabric analyses in these natural examples have given consistent results in different tectonic contexts. In this study, sedimentary conditions and magnetic mineralogy are kept constant and the influence of the tectonic regime in the magnetic fabrics is analyzed. Our main objective is to reproduce several tectonic contexts (strike-slip and compression) in a sedimentary environment where material is not yet compacted, in order to determine how tectonic conditions influence the magnetic fabric registered in each case. By dispersing the clays in water and after allowing their

  6. ECONOMIC GEOLOGY (5)GEOTHERMICS GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    <正>20082442 Han Zaisheng(China Geological Servey,Beijing 100011,China);Ran Weiyan Exploration and Evaluation of Shal- low Geothermal Energy(Geology in China, ISSN1000—3657,CN11—1167/P,34(6), 2007,p.1115—1121,6 refs.,with English abstract) Key words:geothermal exploration, geothermal resources

  7. Synthesis of Natural O-Linked Carba-Disaccharides, (+)- and (−)-Pericosine E, and Their Analogues as α-Glucosidase Inhibitors

    Science.gov (United States)

    Usami, Yoshihide; Mizuki, Koji; Kawahata, Rikiya; Shibano, Makio; Sekine, Atsuko; Yoneyama, Hiroki; Harusawa, Shinya

    2017-01-01

    Pericosine E (6), a metabolite of Periconia byssoides OUPS-N133 was originally isolated from the sea hare Aplysia kurodai, which exists as an enantiomeric mixture in nature. The enantiospecific syntheses of both enantiomers of Periconia byssoides OUPS-N133 has been achieved, along with six stereoisomers, using a common simple synthetic strategy. For these efficient syntheses, highly regio- and steroselective processes for the preparation of bromohydrin and anti-epoxide intermediates were applied. In order to access the unique O-linked carbadisaccharide structure, coupling of chlorohydrin as a donor and anti-epoxide as an acceptor was achieved using catalytic BF3·Et2O. Most of the synthesized compounds exhibited selectively significant inhibitory activity against α-glycosidase derived from yeast. The strongest analog showed almost 50 times the activity of the positive control, deoxynojirimycin.

  8. GEOTHERMICS GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2011-01-01

    <正>20111836 Gao Jian(Sichuan Institute of Geological Survey for Nuclear Industry,Chengdu 610061,China);Shi Yuzhen Feasibility Study of Exploitation of Geothermal Resource in the Lugu Lake Region,Yanyuan,Sichuan Province(Acta Geologica Sichuan,ISSN1006-0995,CN51-1273/P,30(3),2010,p.291-294,1 illus.,1 table,1 ref.,with English abstract)Key words:geothermal water,Sichuan Province20111837 He Jianhua(Geological Brigade 102,Bureau of Geolog

  9. STRUCTURAL GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    <正>20072338 Bai Long(Guizhou Academy of Geology Survey,Guiyang,Guizhou 550005,China);Zhang Zhen Treatment of Discovery on Ductile Shear Belts in Yiwu,Xingjiang Province and Its Ore-Forming Geology Process(Guizhou Geology,ISSN1000-5943,CN52-1059/P,23(4),2006,p.286-291,295,3 illus.,9 refs.)Key words:ductile shear zones,metallogenesis,XinjiangOf ductile shear belts,deformation fabric considerably developed in Yiwu,

  10. Authentication potential of 87Sr/86Sr in water - reference of signatures in natural mineral water to regional geology in Europe

    Science.gov (United States)

    Lorenz, G. D.; Voerkelius, S.

    2009-04-01

    The study presents the investigation of strontium isotope ratios of about 650 different European natural mineral waters as part of the food traceability project "TRACE" funded by the EU. The 87Sr/86Sr analysis is part of a multi-element approach for authen-ticity which also includes 18O, 2H, 3H, main and trace elements as well as 34S. The analysed 87Sr/86Sr cover a wide range of values from 0.7035 to 0.7777 indicating that the natural mineral water samples cover the span from young mantle derived basal-tic rocks to very old silicic continental crust. The results of the large-scale investigation are used to elaborate a novel spatial predic-tion for strontium isotope ratios by combining the measured data with a GIS based geo-logical map of Europe. The resulting map can be used to predict the strontium isotopic composition of ground-water and as such the composition of bioavailable strontium, which can be taken up by plants and further transferred into the food chain. In this study we show, as an example, that the strontium isotopic composition of honey and wheat from specific sample region within the TRACE project correlates well with that of the natural mineral water as pre-dicted by our map. The proof of principle shown is highly relevant for geographical food authentication as it will allow an assessment of the origin of food products without the immediate need for geographically authenticated materials which may not always be available in the first instance. As such, our approach provides a cost effective first instance screening tool. There is an increasing demand for independent analytical methods which can control the geographical origin. The EU project TRACE was started with the aim to develop a gen-eral understanding of the relation between the geo-bio-climatic environment and the isotope and elemental signature in food commodities. As one part of the study detailed isotope maps (e.g. 18O, 87Sr/86Sr) for groundwater will be generated by the isotope re

  11. Studies on chemical structure modification and biology of a natural product, gambogic acid (I): Synthesis and biological evaluation of oxidized analogues of gambogic acid.

    Science.gov (United States)

    Wang, Jinxin; Zhao, Li; Hu, Yang; Guo, Qinglong; Zhang, Lei; Wang, Xiaojian; Li, Nianguang; You, Qidong

    2009-06-01

    Gambogic acid (GA), a natural product, exhibits high potency in inhibiting cancer cell growth through the effective induction of apoptosis. In order to investigate the structure-activity relationships of GA derivatives, 11 oxidized derivatives of GA were synthesized. Some of them showed strong inhibitory effects on HT-29, Bel-7402, BGC-823, A549, and SKOV 3 cell lines. Moreover, in this paper the cellular growth inhibitor 39-hydroxy-6-methoxy-gambogic acid methyl ester (10) was identified as a HepG2 cell apoptosis inhibitor through Annexin-V/PI double staining assay and the expression of the related apoptotic proteins (Bax and Bcl-2). Compound 10 may serve as a potential lead compound for the development of new anticancer drugs. Further SAR studies of GA derivatives indicated that modification of carbon-carbon double bond at C-32/33 or C-37/38 and of the methyl groups at C-39/C-35 can improve antitumor activity.

  12. GEOTHERMICS GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2010-01-01

    <正>20101802 Fang Bin (China University of Geosciences,Beijing 100083,China);Yang Yunjun Characteristics and Resource Evaluation of the Jiwa Geothermal Field in Central Qiangtang,Northern Tibet,China (Geological Bulletin of China,ISSN1671-

  13. GEOTHERMICS GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2011-01-01

    <正>20112453 Li Qing (First Design and Research Institute,Ministry of Mechanical Industry, Bengbu 233000, China); Li Yixiang Application of Shallow Geothermal Energy Resources in the Hefei Area(Geology

  14. Marine geology

    Digital Repository Service at National Institute of Oceanography (India)

    Rao, V.P.; Shankar, R.

    Significant scientific contributions in Marine Geology in India during the Nineties have been highlighted in this paper. Sediment trap data collected in the Arabian Sea and Bay of Bengal have provided much understanding about annual sediment fluxes...

  15. MATHEMATICAL GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2011-01-01

    <正>20112745Cheng Shurang(Geological survey of Shanxi Province,Xi’an 710065,China); Zhang Lin Grade Evaluation Based on Fuzzy Clustering and Pattern Recognition of Comprehensive Anomalies of Geophysics and

  16. ECONOMIC GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2010-01-01

    <正>20101648 Peng Yujing (Survey of Regional Geology and Mineral Resources of Jilin Province, Changchun 130022, China); Zhai Yuchun Age Determination and Characteristics of the Late Indosinian-Yanshanian Metallogenetic Events of Jilin Province

  17. ECONOMIC GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2011-01-01

    <正>20112330 Liu Xifang (Key Laboratory of Saline Lake Resources and Environment, Ministry of Land and Resources,Institute of Mineral Resources, Beijing 100037, China);Zheng Mianping Geological Features

  18. Analogue studies in the Alligator Rivers Region of Australia. Contribution to the scientific basis for the performance assessment of proposed repository sites

    Energy Technology Data Exchange (ETDEWEB)

    Garnett, H.M.; Airey, P.L. [Australian Nuclear Science and Technology Organisation, Lucas Heights, NSW (Australia); Sekine, Keiichi; Hahn, Pil-Soo; Ott, W.R.; Pescatore, C.

    1996-10-01

    The Analogue Studies in the Alligator Rivers Region (ASARR) project is coordinated by the OECD/NEA and involves ANSTO, JAERI, KAERI and the USNRC. Its aim is to contribute to the performance assessment of nuclear waste disposal sites through the building of confidence in predictive transport codes. The project is principally concerned with validating models of sub-surface retardation processes which underpin the codes. This paper will describe recent progress in extending sorption studies from reference minerals to natural materials. The first step in the laboratory program was to investigate uranium uptake on binary systems comprising ferrihydrite and kaolinite. Secondly, the significance of small levels of active minerals such as anatase in a standard kaolinite and iron nodules in geological samples from the Koongarra Uranium deposit is being assessed. Progress towards applying the natural analogue approach to a reference arid site will be reported. The scientific approaches of the individual laboratories are outlined in an annex. (author)

  19. A natural analogue of high-pH cement pore waters from the Maqarin area of northern Jordan: Comparison of predicted and observed trace-element chemistry of uranium and selenium

    Science.gov (United States)

    Linklater, C. M.; Albinsson, Y.; Alexander, W. R.; Casas, I.; McKinley, I. G.; Sellin, P.

    1996-02-01

    Current design concepts for low-/intermediate-level radioactive waste disposal in many countries involve emplacement underground in a cementitious repository. The highly alkaline groundwaters at Maqarin, Jordan, are a good analogue for the cementitious pore waters that will be present within such a repository. A geochemical modelling study of these groundwaters has been carried out in order to test the applicability of equilibrium models in geochemical programs and their associated thermodynamic databases in such hyperalkaline conditions. This was achieved by comparison of elemental solubilities and speciations predicted by the programs with observations in the natural system. Five organisations took part in the study: AEA Technology, U.K.; Chalmers University of Technology, Sweden; MBT Tecnología Ambiental, Spain; Nagra, Switzerland; and SKB, Sweden. The modelling study was coordinated by the University of Berne. The results of the study showed good agreement between the predictions of the programs employed. Comparison of the observed solids with those predicted by the models has allowed limited validation of the databases. The results for U and Se are presented here.

  20. GEOTHERMICS GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2010-01-01

    <正>20102475 Chen Shiliang(No.4 Geological Party of Fujian Province,Ningde 352100,China)A Brief Analysis on Geothermy in the Nantai Isle of Fuzhou Municipality,Fujian Province(Geology of Fujian,ISSN1001-3970,CN35-1080/P,28(4),2009,p.310-314,1 illus.,1 table,3 refs.)Key words:geothermal exploration,Fujian ProvinceBased on the geochemistry and geophysical

  1. GEOTHERMICS GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2012-01-01

    <正>20122531 Hu Lingzhi ( Institute of Geological Engineering Design & Research of Beijing,Miyun 101500,China );Wang Jiankang Discussion on the Feasibility of Geothermal Resources Development and Utilization in Miyun District,Beijing ( City Geology,ISSN1007-1903,CN11-5519 / P,6 ( 3 ), 2011,p.34-35,59 ,) Key words:geothermal resources,Beijing Geothermal,as a new type of clean energy with the integrated trinity of " heat energy-mineral resource-water resource ",

  2. GEOTHERMICS GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2013-01-01

    <正>20132568 Du Guilin(Seismological Bureau of Weihai City,Weihai 264200,China);Cao Wenhai Genesis of Baoquantang Hot Spring in Weihai and Its Influence on Faulting and Seismic Activities(Marine Geology&Quaternary Geology,ISSN0256-1492,CN37-1117/P,32(5),2012,p.67-72,3illus.,2tables,18refs.)Key words:hot springs,seismicity,Shandong Province

  3. ENVIRONMENTAL GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    <正>20072933 Bie Jun(Institute of Oceanology,Chinese Academy of Sciences,Qingdao 266071,China);Huang Haijun Ground Subsidence of the Modern Yellow River Delta and Its Causes(Marine Geology & Quaternary Geology,ISSN0256-1492,CN37-1117/P,28(4),2006,p.29-35,5 illus.,13 refs.,with English abstract)Key words:land subsidence,Yellow River Delta

  4. GENERAL GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2014-01-01

    <正>20141269 Dai Deqiu(Institute of Geology,Hunan University of Science and Technology,Xiangtan 411201,China);Chen Xinyue Contrastive of Petrography and Mineral Chemistry Characteristics among Olivine and Ca,Al-rich Assemblages(Chinese Journal of Geology,ISSN0563-5020,CN11-1937/P,48(3),2013,p.762-772,3 illus.,2 tables,25 refs.)

  5. ENVIRONMENTAL GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2014-01-01

    <正>20141810 Bian Yumei(Geological Environmental Monitoring Center of Liaoning Province,Shenyang 110032,China);Zhang Jing Zoning Haicheng,Liaoning Province,by GeoHazard Risk and Geo-Hazard Assessment(Journal of Geological Hazards and Environment Preservation,ISSN1006-4362,CN51-1467/P,24(3),2013,p.5-9,2 illus.,tables,refs.)

  6. GENERAL GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2014-01-01

    <正>20140001Dong Shuwen(Chinese Academy of Geological Sciences,Beijing 100037,China);Li Tingdong Progress of SinoProbe-Deep Exploration in China 2008~2012(Acta Geoscientica Sinica,ISSN1006-3021,CN11-3474/P,34(1),2013,p.7-23,8illus.,69refs.)Key words:deep geology,deep seismic sounding,Continental Scientific Drilling,China SinoProbe 2008~2012,the initial phase

  7. Geology, summary

    Science.gov (United States)

    Sabins, F. F., Jr.

    1975-01-01

    Trends in geologic application of remote sensing are identified. These trends are as follows: (1) increased applications of orbital imagery in fields such as engineering and environmental geology - some specific applications include recognition of active earthquake faults, site location for nuclear powerplants, and recognition of landslide hazards; (2) utilization of remote sensing by industry, especially oil and gas companies, and (3) application of digital image processing to mineral exploration.

  8. PETROLEUM GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2012-01-01

    <正>20122476 Bao Yunjie ( Wuxi Research Institute of Petroleum Geology,SINOPEC,Wuxi 214151,China );Wang Shuyi Reservoir Diagenesis of 3rd Member of Feixianguan Formation,Jiannan Gas Field ( Petroleum Geology & Experiment,ISSN1001-6112,CN32-1151 / TE,33 ( 6 ), 2011,p.564-568,2 il-lus.,1plate,2tables,10refs. ) Key words:carbonate reservoirs,diagenesis,Chongqing,Hubei Province

  9. MATHEMATICAL GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    <正>20072288 Hong Quan(Ningbo Institute for Engineering Investigation,Ningbo 315012,China)Design of Information Management System for Engineering Investigation Maps Based on C/S Model(The Chinese Journal of Geological Hazard and Control,ISSN1003-8035,CN11-2852/P,17(1),2006,p.86-90,2 illus.,6 refs.)Key words:information systems,engineering geological map

  10. COAL GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2009-01-01

    <正>20091159 Gao Yan(No.3 Prospecting Team of Anhui Bureau of Coal Geology,Suzhou 234000,China) Effect of Depositional Environment of Coal-Bearing Stratum on Major Coal Seams in Suntan Coalmine,Anhui Province(Geology of Anhui,ISSN 1005- 6157,CN34-1111/P,18(2),2008,p.114 -117,5 illus.,1 ref.,with English abstract)

  11. ECONOMIC GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2011-01-01

    <正>20110164 Dong Lianhui(Xinjiang Bureau of Geology and Mineral Resources and Development,Urumqi 830000,China);Feng Jing Research for Classification of Metallogenic Unit of Xinjiang(Xinjiang Geology,ISSN1000-8845,CN65-1092/P,28(1),2010,p.1-15,1 illus.,1 table,17 refs.,with English abstract)Key words:metallogenic provinces,metallogenic belts,metallogenic area,Xinjiang

  12. ECONOMIC GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    <正>20072528 Chen Yuchuan(Chinese Academy of Geological Sciences,Beijing,100037);Pei Rongfu On Minerogenetic(Metallogenetic)Series:Third Discussion(Acta Geologica Sinica,ISSN0001-5717,CN11-1951/P,80(10),2006,p.1501-1508,3illus.,1 table,57 refs.,with English abstract)Key words:metallogenic series20072529 Pei Rongfu(Institute of Mineral Resources,CAGS,Beijing 100037);Mei Yanxiong Event Geology Stimulati

  13. ACTINOMYCIN D ANALOGUES

    DEFF Research Database (Denmark)

    1997-01-01

    The present invention relates to new compounds being structurally and functionally similar to Actinomycin D and to combinatorial libraries of such compounds. The Actinomycin D analogues according to the present invention comprise two linear or cyclic peptide moieties constituted by $g...

  14. ACTINOMYCIN D ANALOGUES

    DEFF Research Database (Denmark)

    1997-01-01

    The present invention relates to new compounds being structurally and functionally similar to Actinomycin D and to combinatorial libraries of such compounds. The Actinomycin D analogues according to the present invention comprise two linear or cyclic peptide moieties constituted by $g...

  15. Quantitative comparisons of analogue models of brittle wedge dynamics

    Science.gov (United States)

    Schreurs, Guido

    2010-05-01

    Analogue model experiments are widely used to gain insights into the evolution of geological structures. In this study, we present a direct comparison of experimental results of 14 analogue modelling laboratories using prescribed set-ups. A quantitative analysis of the results will document the variability among models and will allow an appraisal of reproducibility and limits of interpretation. This has direct implications for comparisons between structures in analogue models and natural field examples. All laboratories used the same frictional analogue materials (quartz and corundum sand) and prescribed model-building techniques (sieving and levelling). Although each laboratory used its own experimental apparatus, the same type of self-adhesive foil was used to cover the base and all the walls of the experimental apparatus in order to guarantee identical boundary conditions (i.e. identical shear stresses at the base and walls). Three experimental set-ups using only brittle frictional materials were examined. In each of the three set-ups the model was shortened by a vertical wall, which moved with respect to the fixed base and the three remaining sidewalls. The minimum width of the model (dimension parallel to mobile wall) was also prescribed. In the first experimental set-up, a quartz sand wedge with a surface slope of ˜20° was pushed by a mobile wall. All models conformed to the critical taper theory, maintained a stable surface slope and did not show internal deformation. In the next two experimental set-ups, a horizontal sand pack consisting of alternating quartz sand and corundum sand layers was shortened from one side by the mobile wall. In one of the set-ups a thin rigid sheet covered part of the model base and was attached to the mobile wall (i.e. a basal velocity discontinuity distant from the mobile wall). In the other set-up a basal rigid sheet was absent and the basal velocity discontinuity was located at the mobile wall. In both types of experiments

  16. ECONOMIC GEOLOGY (3)PETROLEUM GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    <正>20082333 Bai Guoping(Key Laboratory for Hydrocarbon Accumulation of Education Ministry,China University of Petroleum, Beijing 102249,China);Yin Jinyin Petroleum Geological Features and Explo- ration Potential Analyses of North Carnavon Basin,Australia(Petroleum Geology & Ex- periment,ISSN1001—6112,CN32—1151/ TE,29(3),2007,p.253—258,4 illus.,1 table,12 refs.)

  17. Zn(II, Mn(II and Sr(II Behavior in a Natural Carbonate Reservoir System. Part II: Impact of Geological CO2 Storage Conditions

    Directory of Open Access Journals (Sweden)

    Auffray B.

    2016-07-01

    Full Text Available Some key points still prevent the full development of geological carbon sequestration in underground formations, especially concerning the assessment of the integrity of such storage. Indeed, the consequences of gas injection on chemistry and petrophysical properties are still much discussed in the scientific community, and are still not well known at either laboratory or field scale. In this article, the results of an experimental study about the mobilization of Trace Elements (TE during CO2 injection in a reservoir are presented. The experimental conditions range from typical storage formation conditions (90 bar, supercritical CO2 to shallower conditions (60 and 30 bar, CO2 as gas phase, and consider the dissolution of the two carbonates, coupled with the sorption of an initial concentration of 10−5 M of Zn(II, and the consequent release in solution of Mn(II and Sr(II. The investigation goes beyond the sole behavior of TE in the storage conditions: it presents the specific behavior of each element with respect to the pressure and the natural carbonate considered, showing that different equilibrium concentrations are to be expected if a fluid with a given concentration of TE leaks to an upper formation. Even though sorption is evidenced, it does not balance the amount of TE released by the dissolution process. The increase in porosity is clearly evidenced as a linear function of the CO2 pressure imposed for the St-Emilion carbonate. For the Lavoux carbonate, this trend is not confirmed by the 90 bar experiment. A preferential dissolution of the bigger family of pores from the preexisting porosity is observed in one of the samples (Lavoux carbonate while the second one (St-Emilion carbonate presents a newly-formed family of pores. Both reacted samples evidence that the pore network evolves toward a tubular network type.

  18. Destination: Geology?

    Science.gov (United States)

    Price, Louise

    2016-04-01

    "While we teach, we learn" (Roman philosopher Seneca) One of the most beneficial ways to remember a theory or concept is to explain it to someone else. The offer of fieldwork and visits to exciting destinations is arguably the easiest way to spark a students' interest in any subject. Geology at A-Level (age 16-18) in the United Kingdom incorporates significant elements of field studies into the curriculum with many students choosing the subject on this basis and it being a key factor in consolidating student knowledge and understanding. Geology maintains a healthy annual enrollment with interest in the subject increasing in recent years. However, it is important for educators not to loose sight of the importance of recruitment and retention of students. Recent flexibility in the subject content of the UK curriculum in secondary schools has provided an opportunity to teach the basic principles of the subject to our younger students and fieldwork provides a valuable opportunity to engage with these students in the promotion of the subject. Promotion of the subject is typically devolved to senior students at Hessle High School and Sixth Form College, drawing on their personal experiences to engage younger students. Prospective students are excited to learn from a guest speaker, so why not use our most senior students to engage and promote the subject rather than their normal subject teacher? A-Level geology students embarking on fieldwork abroad, understand their additional responsibility to promote the subject and share their understanding of the field visit. They will typically produce a series of lessons and activities for younger students using their newly acquired knowledge. Senior students also present to whole year groups in seminars, sharing knowledge of the location's geology and raising awareness of the exciting destinations offered by geology. Geology fieldwork is always planned, organised and led by the member of staff to keep costs low, with recent visits

  19. Environmental Monitoring, Other - UNCONSOLIDATED_GAMMA_LOGS_IGS_IN:Natural gamma-ray logs in unconsolidated sediments in Indiana (Indiana Geological Survey, 1:100,000, Point Shapefile)

    Data.gov (United States)

    NSGIC GIS Inventory (aka Ramona) — UNCONSOLIDATED_GAMMA_LOGS_IGS_IN.shp shows the locations of the Indiana Geological Survey's gamma-logs that were taken from 1978 to 2005. This shapefile includes...

  20. Geochemical monitoring using noble gases and carbon isotopes: study of a natural reservoir; Monitoring geochimique par couplage entre les gaz rares et les isotopes du carbone: etude d'un reservoir naturel

    Energy Technology Data Exchange (ETDEWEB)

    Jeandel, E

    2008-12-15

    To limit emissions of greenhouse gases in the atmosphere, CO{sub 2} geological sequestration appears as a solution in the fight against climate change. The development of reliable monitoring tools to ensure the sustainability and the safety of geological storage is a prerequisite for the implementation of such sites. In this framework, a geochemical method using noble gas and carbon isotopes geochemistry has been tested on natural and industrial analogues. The study of natural analogues from different geological settings showed systematic behaviours of the geochemical parameters, depending on the containment sites, and proving the effectiveness of these tools in terms of leak detection and as tracers of the behaviour of CO{sub 2}. Moreover, an experience of geochemical tracing on a natural gas storage has demonstrated that it is possible to identify the physical-chemical processes taking place in the reservoir to a human time scale, increasing interest in the proposed tool and providing general information on its use. (author)

  1. GEOCHRONOMETRY & ISOTOPE GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2011-01-01

    <正>20111126Ji Honglei(Institute of Hydrogeol-ogy and Environmental Geology,CAGS,Shi-jiazhuang050061,China);Zhao Hua Pre-liminary Study of Re-OSL on Water-De-posited Sediments(Seismology and Geology,ISSN0253-4967,CN11-2192/P,32(2),2010,p.320-326,4illus.,1table,10refs.)Key words:stream sediments,opticalstimulated luminescence dating,HebeiProvinceAccording to measuring the natural TT-OSL signals of the fine-grained quartzfrom both fluvial and lacustrine sediments,the dose recovery experiment and the comparison of the multiple aliquots

  2. COAL GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2009-01-01

    <正>20091749 Cai Hou’an(College of Energy Geology,China University of Geosciences,Beijing 100083,China);Xu Debin SHRIMP U-Pb Isotope Age of Volcanic Rocks Distributed in the Badaohao Area,Liaoning Province and Its Significance(Coal Geology & Exploration,ISSN1001-1986,CN61-1155/P,36(4),2008,p.17-20,2 illus.,1 table,16 refs.)Key words:coal measures,volcanic rocks,U-Pb dating,LiaoningA set of andesite volcanic rocks distributes in the Badaohao area in Heishan County,Liaoning Province.It’s geological age and stratigraphy sequence relationship between the Lower Cretaceous Badaohao Formation and the volcanic rocks can not make sure till now and is influencing the further prospect for coals.Zircon

  3. MATHEMATICAL GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2015-01-01

    20150599Chen Gang(Nanjing Center,China Geological Survey,Nanjing 210016,China);Yao Zhongyou Mineral Database Construction and Analysis of Oceania Region(Geological Bulletin of China,ISSN1671-2552,CN11-4648/P,33(2),2014,p.164-171,13illus.,6refs.)Key words:mineral localities,data bases Based on the database of the standards,construction process,data quality control measures and methods and processes,the authors constructed the databases of Fe,Mn,Cu,Al,Au,Ni,U and REE mineral resources for Oceanian region.Through a comprehensive analysis of the multi-source data information of geology and mineral resources,

  4. ECONOMIC GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2011-01-01

    <正>20110907 Luo Xue(Faculty of Earth Resource,China Unversity of Geosciences,Wuhan 430074,China);Cao Xinzhi Review on the Change and Development of the Research Thoughts about Mineral Deposit Geology(Contributions to Geology and Mineral Resources Research,ISSN1001-1412,CN12-1131/P,25(2),2010,p.147-152,40 refs.)Key words:study of mineral deposit The development and breakthrough of mineral deposit geology depends to a great extent on the progress and change of its research thoughts.From the traditional study of single mineral,single deposit and single metallogenic model to the comprehensive discussion and whole understanding of metallogenic

  5. STRUCTURAL GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2010-01-01

    <正>20102152 Bai Daoyuan(Hunan Institute of Geology Survey,Changsha 410011,China);Zhou Kejun Study on Quaternary Tectonic-Sedimentary Evolution of Lujiao Area,East Edge of Yuanjiang Sag,Dongting Basin(Journal of Geomechanics,ISSN1006-6616,CN11-3672/P,15(4),2009,p.409-420,7 illus.,1 table,23 refs.)Key words:basins,Dongtinghu BasinQuaternary Yuanjiang sag is an eastern one of the secondary tectonic units of the Dongting Basin.Detailed geologic mapping and bore data were taken to reveal the Quaternary tectonic,sedimentary and

  6. ENGINEERING GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2014-01-01

    <正>20140498An Shize(Sichuan Institute of Geological Engineering Investigation,Chengdu610072,China);Liu Zongxiang On the Failure Mechanism of a Bedding Landslide in Northeast Sichuan(Journal of Geological Hazards and Environment Preservation,ISSN1006-4362,CN51-1467/P,24(1),2013,p.14-19,2illus.,9refs.)Key words:bedding faults,landslides The landslide was caused by excavation engineering.The failure mechanism is explored for slopes with soft interlayer in the red

  7. GEOTHERMICS GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2014-01-01

    <正>20140332 Jiang Lin(School of Earth and Space Sciences,Peking University,Beijing100871,China);Ji Jianqing Geologic Analysis on the Prospects of the Enhanced Geothermal System(EGS)in the Bohaiwan Basin(Geology and Prospecting,ISSN0495-5331,CN11-2043/P,49(1),2013,p.167-178,5illus.,4tables,41refs.)Key words:geothermal systems,Bohaiwan Basin Great amounts of thermal energy is stored ubiquitously in rocks with high tempera-

  8. GENERAL GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2010-01-01

    <正>20102127 S.L.Shvartsev(Tomsk Department,Trofimuk Institute of Petroleum Geology and Geophysics of Siberian Branch of the RAS)Self-Organizing Abiogenic Dissipative Structures in the Geologic History of the Earth(Earth Science Frontiers,ISSN1005-2321,CN11-3370/P,16(6),2009,p.257-275,3 illus.,4 tables,53 refs.)Key words:abiogenic,water-rock interaction,dissipative structureIt is shown that since the appearance of water on the Earth,a stationary disequilibrium-equilibrium

  9. ENVIRONMENTAL GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2011-01-01

    <正>20110635 Bai Jinbin(Tianjin Institute of Geological Survey,Yingshui Road 20,Nankai 300191,China),Niu Xiujun Cenozoic Consolidation Characteristics and Land Subsidence in Tianjin(The Chinese Journal of Geological Hazard and Control,ISSN1003-8035,CN11-2825/P,21(1),2010,p.42-46,4 illus.,4 tables,7 refs.)Key words:consolidation,land subsidence,TianjinAccording to the survey data of oil wells in Dagang oilfield and a lot of laboratory data,the paper discussed the relationship between the consolidation characteristics

  10. MATHEMATICAL GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2011-01-01

    <正>20110686 Bai Wancheng(Gold Headquarters of the Chinese Armed Police Force,Beijing 100055,China);Dong Jianle Statistic Prediction for Gold Ore Prospecting in China(Contributions to Geology and Mineral Resources Research,ISSN1001-1412,CN12-1131/P,25(1),2010,p.1-4,11,1 illus,1 table,7 refs.,with English abstract)Key words:metallogenic prediction,gold ores,China 20110687 Dong Min(Institute of Geology and Exploration Engineering,Xinjiang University,Urumqi 830046,China);Sun Baosheng Drawing and S

  11. Gastric inhibitory polypeptide analogues

    DEFF Research Database (Denmark)

    Holst, Jens Juul

    2002-01-01

    of GIP and GLP-1 receptors, the incretin effect is essential for normal glucose tolerance. In patients with type 2 diabetes mellitus it turns out that the incretin effect is severely impaired or abolished. The explanation seems to be that both the secretion of GLP-1 and the effect of GIP are impaired...... (whereas both the secretion of GIP and the effect of GLP-1 are near normal). The impaired GLP-1 secretion is probably a consequence of diabetic metabolic disturbances. The known genetic variations in the GIP receptor sequence are not associated with type 2 diabetes mellitus, but a defective insulinotropic...... and its analogues are attractive as therapeutic agents for type 2 diabetes mellitus, analogues of GIP are unlikely to be effective. On the other hand, GIP seems to play an important role in lipid metabolism, promoting the disposal of ingested lipids, and mice with a targeted deletion of the GIP receptor...

  12. Aspartame and Its Analogues

    Science.gov (United States)

    Pavlova, L. A.; Komarova, T. V.; Davidovich, Yurii A.; Rogozhin, S. V.

    1981-04-01

    The results of studies on the biochemistry of the sweet taste are briefly reviewed. The methods of synthesis of "aspartame" — a sweet dipeptide — are considered, its structural analogues are described, and quantitative estimates are made of the degree of sweetness relative to sucrose. Attention is concentrated mainly on problems of the relation between the structure of the substance and its taste in the series of aspartyl derivatives. The bibliography includes 118 references.

  13. The Greenland analogue project. Yearly report 2010

    Energy Technology Data Exchange (ETDEWEB)

    Harper, J.; Brinkerhoff, D.; Johnson, J. [University of Montana, Missoula (United States); Ruskeeniemi, T.; Engstroem, J.; Kukkonen, I. [Geological Survey of Finland (Finland)] [and others

    2012-04-15

    A four-year field and modelling study of the Greenland ice sheet and subsurface conditions, Greenland Analogue Project (GAP), has been initiated collaboratively by SKB, Posiva and NWMO to advance the understanding of processes associated with glaciation and their impact on the long-term performance of a deep geological repository. The study site encompasses a land terminus portion of the Greenland ice sheet, east of Kangerlussuaq, and is in many ways considered to be an appropriate analogue of the conditions that are expected to prevail in much of Canada and Fennoscandia during future glacial cycles. The project begins in 2009 and is scheduled for completion in 2012. Our current understanding of the hydrological, hydrogeological and hydrogeochemical processes associated with cold climate conditions and glacial cycles, and their impact on the long-term performance of deep geological repositories for spent nuclear fuel, will be significantly improved by studying a modern analogue. The GAP will conduct the first in situ investigations of some of the parameters and processes needed to achieve a better understanding of how an ice sheet may impact a deep repository, and will provide measurements, observations and data that may significantly improve our safety assessments and risk analyses of glaciation scenarios. This report was produced by the GAP team members and presents an overview of the activities within the GAP during the interval January 1 to December 31, 2010, as well as research results obtained during this time frame. Research for the GAP is ongoing, and additional results related to the data presented here may become available in the future and will be presented in subsequent annual reports. (orig.)

  14. Quantum analogue computing.

    Science.gov (United States)

    Kendon, Vivien M; Nemoto, Kae; Munro, William J

    2010-08-13

    We briefly review what a quantum computer is, what it promises to do for us and why it is so hard to build one. Among the first applications anticipated to bear fruit is the quantum simulation of quantum systems. While most quantum computation is an extension of classical digital computation, quantum simulation differs fundamentally in how the data are encoded in the quantum computer. To perform a quantum simulation, the Hilbert space of the system to be simulated is mapped directly onto the Hilbert space of the (logical) qubits in the quantum computer. This type of direct correspondence is how data are encoded in a classical analogue computer. There is no binary encoding, and increasing precision becomes exponentially costly: an extra bit of precision doubles the size of the computer. This has important consequences for both the precision and error-correction requirements of quantum simulation, and significant open questions remain about its practicality. It also means that the quantum version of analogue computers, continuous-variable quantum computers, becomes an equally efficient architecture for quantum simulation. Lessons from past use of classical analogue computers can help us to build better quantum simulators in future.

  15. GEOTHERMICS GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2009-01-01

    <正>20091163 Jiang Huichao(Tongji University College of Ocean and Earth Science,Shanghai 200092,China);Xiao Yongjun Analysis of Cenozoic Subsurface Temperatures of the Jiyang Depression,Shandong Province(Geology in China,ISSN1000-3657,CN11- 1167/P,35(2),2008,p.273-278,3 illus.,2 tables,15 refs.)

  16. GEOTHERMICS GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2015-01-01

    20151090 Bian Huiying(School of Environmental Sciences and Engineering,Chang’an University,Xi’an 10054,China);Wang Shuangming Hydrodynamic Conditions of Geothermal Water in Gushi Depression of Guanzhong Basin(Coal Geology&Exploration;,ISSN1001-1986,CN61-1155/P,42(3),2014,p.50-54,60,9illus.,11refs.,

  17. ENVIRONMENTAL GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2004-01-01

    <正>20042333 Chen Cuibai (School of Water Resources and Environment, China University of Geosciences, Beijing); Yang Qi The Laboratory Study of Biodegradation and Adsorption and Desorption of Trichloroethylene to Mixed Bacteria (Hydrogeology & Engineering Geology, ISSN1000 - 3665, CN11-2202/P, 31(1), 2004, p. 47-51, 6 illus. , 4 tables, 14 refs. )

  18. GENERAL GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2009-01-01

    <正>20090720 Wang Haiqiao(Institute of Earth Resources and Information,China University of Petroleum(East China),Dongying 257061,China);Zhong Jianhua Theory of Geological Holography(Earth Science Frontiers, ISSN1005-2321,CN11-3370/P,15 (3),2008,p.370-379,8 illus.,24 refs.)

  19. GEOTHERMICS GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    <正>20070403 Deng Xiaoying (Zhengzhou Geo-Engineering Exploration Institute, Zhengzhou 450053, China); Yang Guoping Features and Origin of Geothermal Fluid in the New District of Hebi, Henan Provionce (Hydrogeology & Engineering Geology, ISSN1000-3665, CN11-2202/P, 32(2), 2005, p.111-114, 4 illus., 1 table, 7 refs.) Key words: thermal waters, Henan Province

  20. GENERAL GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2013-01-01

    <正>20131375 Dai Deqiu(Institute of GeologyHunan University of Science and TechnologyXiangtan 411201,China);Wang Shijie Comparison of Petrography and Mineral Chemistry Characters between Plagioclase Olivine Inclusions and Typical Ca,Al-Rich Inclusions(Acta Mineralogica Sinica,ISSN1000-4734CN52-1045/P,32(3),2012,p.341-348,3

  1. ENGINEERING GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2015-01-01

    20152724 Chen Dan(State Key Laboratory of Geohazard Prevention and Geoenvironment Protection,Chengdu University of Technology,Chengdu 610059,China);Fu Ronghua Study on the Responses of Landslide to Earthquake:Taking Kudiguazi Landslide as an Example(Geological Journal of China Universities,

  2. SEISMIC GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2016-01-01

    20160094Cao Lei(Institute of Geology and Geophysics,Chinese Academy of Sciences,Beijing100029,China);Hao Jinlai Rupture Process Of March 10,2014,M W6.9 Earthquake in the Northwestern Coast of California(Chinese Journal of Geophysics,ISSN0001-

  3. STRUCTURAL GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2013-01-01

    <正>20130642 Bai Daoyuan (Hunan Institute of Geology Survey , Mineral Exploration and Development of Hunan Province , Changsha 410011 , China); Jia Baohua Potential Genesis of the Trending Changes of Jinning Period and Caledonian Structural Lineamens in Middle-Southern Hunan Province (Journal of Geomechanics , ISSN1006-6616 ,

  4. ENVIRONMENTAL GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2013-01-01

    <正>20132755 Chang Ming(State Key Laboratory for Geo-Hazard Prevention and Geo-Environment Protection,Chengdu University of Technology,Chengdu 610059,China);Tang Chuan Prediction Model for Debris Flow Hazard Zone on Alluvial Fan in Milin Section of Yarlungzangbo River,Tibet(Journal of Engineering Geology,ISSN1004-9665

  5. GENERAL GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2010-01-01

    <正>20101425 Dai Deqiu (Institute of Geology, Hunan University of Science and Technology, Xiangtan 411201, China); Lin Yangting Petrography, Mineral Chemistry of 6 New Unequilibrated Ordinary Chondrites Collected from the Grove Mountains, Antarctica(Acta Mineralogica Sinica, ISSN1000-4734, CN52-1045/P, 29(3), 2009, p.405-412, 3 illus., 3 tables, 20 refs.)

  6. SEISMIC GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2010-01-01

    <正>20101490 Chen Yuwei (Earthquake Administration of Anhui Province, Hefei 230031, China); Huang Xianliang Analysis of Impact of Source Region Structure on Seismology Parameter Scan Results (Seismology and Geology, ISSN0253-4967, CN11-2192/P, 31(3), 2009, p.433-440, 2 illus., 4 tables, 12 refs.)

  7. MATHEMATICAL GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2013-01-01

    <正>20131958 An Lili(China University of Geosciences,Beijing 100083,China);Chen JianpingIntegration and Exploitation of 3DDigital Mine Information System(Journal of Geology,ISSN1674-3636,CN32-1796/P,36(3),2012,p.280-284,2illus.,14refs.)Key words:geographic information system,Sichuan Province

  8. MATHEMATICAL GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    <正>20071578 Chen Song(College of Civil Engi- neering,Hohai University,Nanjing 210098, China);Han Xuewei Monitoring Program System for the Foundation of Large Bridge (Hydrogeology & Engineering Geology, ISSN 1000-3665,CN 11-2202/P,32(5), 2005,p.44-47,5 illus.,3 refs.) Key words:bridges,footing

  9. MATHEMATICAL GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    <正>20080675 Chen Shucun(College of Civil Engineering,Hohai University,Nanjing 210098);Gao Zhengxia Application of a Refined BP Algorithm Based Elman Network to Settlement Prediction of Soft Soil Ground(Journal of Engineering Geology,ISSN1004-9665,CN11-3249/P,14(3),2006,p.394-397,4 illus.,2 tables,6 refs.)

  10. MATHEMATICAL GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2004-01-01

    <正>20042360 Feng Zhihan (Geological Survey of Gansu Province, Lanzhou, Gansu) Adjustment of Gravitational Base Point Net Using MATLAB (Computing Techniques for Geophysical and Geochemical Exploration, ISSN 1001-1749, CN51-1242/P, 25(4), 2003, p. 336-339, 1 illus. , 3 refs. )

  11. ECONOMIC GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    <正>20071835 Chen Xifeng(China University of Geosciences,Beijing 100083,China);Peng Runmin Analysis on the Necessity and Significance of Concealed Deposits Exploration(Gansu Geology,ISSN1004-4116,CN62-1191/P,15(2),2006,p.1-4,1 table,7 refs.)Key words:blind deposits,China

  12. ECONOMIC GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    <正>20070285 Fu Xiaofang (Institute of Geology and Mineral Resources, SBGMR, Chengdu, Sichuan 610081); Hou Liwei Potential of Mineral Resources of Rare and Dispersed Elements in Sichuan Province and Countermeasures of Exploitation (Acta Geologica Sichuan, ISSN1006-0995, CN51-1273/P, 26(1), 2006, p.10-18, 6 illus., 15 refs.) Key words: mineral resources, Sichuan Province

  13. ECONOMIC GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    <正>20080948 Deng Jinfu(State Key Laboratory of Geological Processes and Mineral Resources,China University of Geosciences,Beijing 100083,China);Su Shangguo Yanshanian(Jura-Cretaceous)Orogenic Processes and Metallogenesis of the Taihangshan-Yanshan-West Liaoning Orogenic Belt,North China(Geoscience,ISSN1000-8527,CN11-2035/P,21(2)

  14. ECONOMIC GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    <正>20080252 Zhai Yusheng(State Key Laboratory of Geological Processes and Mineral Resources,China University of Geosciences,Beijing 100083,China) Earth System,Me-tallogenic System to Exploration System(Earth Science Frontiers,ISSN1005-2321,CN11-3370/P,14(1),2007,p.172-181,6 illus.,18 refs.,with English abstract)

  15. ECONOMIC GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2013-01-01

    <正>20130838 Li Wenyuan (Xi ’ an Center , China Geological Survey , Xi ’ an 710054 , China); Niu Yaoling Geodynamic Setting and FurtherExploration of Magmatism-Related Mineralization Concentrated in the Late Paleozoic in the Northern Xinjiang Autonomous Region (Earth Science Frontiers , ISSN1005-2321 , CN11-3370/P , 19 (4)

  16. ECONOMIC GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2013-01-01

    <正>20131562 Chen Jianping(School of Earth Sciences and Resources,China University of Geosciences,Beijing 100083,China);Shi Rui 3D Metallogenic Prediction for Western Section of Q8 Gold Deposit in Tongguan County of Shaanxi Province Based on Digital Mineral Deposit Model(Journal of Geology,ISSN1674,

  17. Natural and anthropogenic environmental hazards. Research results of the Department of Applied Geology; Natuerliche und anthropogene Umweltgefaehrdungen. Forschungsergebnisse aus dem Lehrstuhl fuer Angewandte Geologie

    Energy Technology Data Exchange (ETDEWEB)

    Czurda, K.; Eiswirth, M.; Hoetzl, H. [comps.

    1998-12-31

    Applied geology is employed in mining geology, raw materials geology, engineering geology, and hydrogeology, of which the two last-mentioned are the most important for the Department of Applied Geology. This series of publications arose from the need of making research findings, dissertations, theses and conference papers accessible to the public faster and more comprehensively than in national and international journals. [Deutsch] Die Aufgaben der angewandten Geologie sind im weitesten Sinne in der Montangeologie, in der Rohstoffgeologie, in der Ingenieurgeologie und in der Hydrogeologie zu sehen. Der engere Aufgabenbereich der Institute fuer Angewandte Geologie konzentriert sich der heutigen Fragestellung entsprechend meist auf die Ingenieurgeologie und Hydrogeologie. Wenn wir daraus noch die Umweltgeologie ableiten, so ist der Lehr- und Forschungsschwerpunkt auch des Karlsruher Lehrstuhles fuer Angewandte Geologie (AGK=Angewandte Geologie Karlsruhe) umrissen. Die vorliegende Schriftenreihe ist aus der Notwendigkeit entstanden, Forschungsergebnisse, Dissertationen und ausgewaehlte Diplomarbeiten sowie Beitraege einschlaegiger Tagungen in Karlsruhe rascher und u.U. umfangreicher als in internationalen oder nationalen Journalen moeglich zu publizieren. (orig.)

  18. Geologic map of Indonesia - Peta geologi Indonesia

    Science.gov (United States)

    Sigit, Soetarjo

    1965-01-01

    The geology, compiled by Th. H. F. Klompe in 1954 from published and unpublished maps of the Direktorat Geologi, has been brought up to date on the basis of investigations carried out to 1962 (Ref. Sigit, Soetarjo, "I. A brief outline of the geology of the Indonesian Archipelago, and II. Geological map of Indonesia;" Direktorat Geologi publication, 1962.)

  19. The intercrater plains of Mercury and the Moon: Their nature, origin and role in terrestrial planet evolution. Geologic mapping of Mercury and the Moon. Ph.D. Thesis

    Science.gov (United States)

    Leake, M. A.

    1982-01-01

    The geologic framework of the intercrater plains on Mercury and the Moon as determined through geologic mapping is presented. The strategies used in such mapping are discussed first. Then, because the degree of crater degradation is applied to both mapping and crater statistics, the correlation of degradation classification of lunar and Mercurian craters is thoroughly addressed. Different imaging systems can potentially affect this classification, and are therefore also discussed. The techniques used in mapping Mercury are discussed in Section 2, followed by presentation of the Geologic Map of Mercury in Section 3. Material units, structures, and relevant albedo and color data are discussed therein. Preliminary conclusions regarding plains' origins are given there. The last section presents the mapping analyses of the lunar intercrater plains, including tentative conclusions of their origin.

  20. The intercrater plains of Mercury and the Moon: Their nature, origin and role in terrestrial planet evolution. Geologic mapping of Mercury and the Moon. Ph.D. Thesis

    Science.gov (United States)

    Leake, M. A.

    1982-01-01

    The geologic framework of the intercrater plains on Mercury and the Moon as determined through geologic mapping is presented. The strategies used in such mapping are discussed first. Then, because the degree of crater degradation is applied to both mapping and crater statistics, the correlation of degradation classification of lunar and Mercurian craters is thoroughly addressed. Different imaging systems can potentially affect this classification, and are therefore also discussed. The techniques used in mapping Mercury are discussed in Section 2, followed by presentation of the Geologic Map of Mercury in Section 3. Material units, structures, and relevant albedo and color data are discussed therein. Preliminary conclusions regarding plains' origins are given there. The last section presents the mapping analyses of the lunar intercrater plains, including tentative conclusions of their origin.

  1. Analogue Methods in Palaeoecology: Using the analogue Package

    OpenAIRE

    Simpson, Gavin L.

    2007-01-01

    Palaeoecology is an important branch of ecology that uses the subfossil remains of organisms preserved in lake, ocean and bog sediments to inform on changes in ecosystems and the environment through time. The analogue package contains functions to perform modern analogue technique (MAT) transfer functions, which can be used to predict past changes in the environment, such as climate or lake-water pH from species data. A related technique is that of analogue matching, which is concerned with i...

  2. Appalachian basin oil and natural gas: stratigraphic framework, total petroleum systems, and estimated ultimate recovery: Chapter C.1 in Coal and petroleum resources in the Appalachian basin: distribution, geologic framework, and geochemical character

    Science.gov (United States)

    Ryder, Robert T.; Milici, Robert C.; Swezey, Christopher S.; Trippi, Michael H.; Ruppert, Leslie F.; Ryder, Robert T.

    2014-01-01

    The most recent U.S. Geological Survey (USGS) assessment of undiscovered oil and gas resources of the Appalachian basin was completed in 2002 (Milici and others, 2003). This assessment was based on the total petroleum system (TPS), a concept introduced by Magoon and Dow (1994) and developed during subsequent studies such as those by the U.S. Geological Survey World Energy Assessment Team (2000) and by Biteau and others (2003a,b). Each TPS is based on specific geologic elements that include source rocks, traps and seals, reservoir rocks, and the generation and migration of hydrocarbons. This chapter identifies the TPSs defined in the 2002 Appalachian basin oil and gas assessment and places them in the context of the stratigraphic framework associated with regional geologic cross sections D–D′ (Ryder and others, 2009, which was re-released in this volume, chap. E.4.1) and E–E′ (Ryder and others, 2008, which was re-released in this volume, chap. E.4.2). Furthermore, the chapter presents a recent estimate of the ultimate recoverable oil and natural gas in the basin.

  3. ECONOMIC GEOLOGY (3)PETROLEUM GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    <正>20071077 An Zuoxiang(Petroleum Industry Press,Beijing 100011,China);Ma Ji On Bo- real-Style Petroliferous Domain(Xinjiang Petroleum Geology,ISSN1001-3873,CN65 -1107/TE,26(4),2005,p.432-436,4 illus.,9 refs.,with English abstract) Key words:oil and gas fields

  4. HYDROGEOLOGY & ENGINEERING GEOLOGY (2)ENGINEERING GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    <正>20071446 Kazue Tazaki(Graduate School of Natural Science and Technology,Kanazawa University,Kakuma,Kanazawa,Ishikawa 920-1192,Japan);Hiroaki Watanabe Hy- drocarbon-Degrading Bacteria and Paraffin from Polluted Seashores 9 Years after the Nakhodka Oil Spill in the Sea of Japan(Acta Geologica Sinica(English Edition)——Jour- nal of the Geological Society of China,ISSN 1000-9515,CN11-2001/P,80(3),2006, p.432-440,6 illus.,54 refs.,with English abstract)

  5. Crustal nature and seismic structure of the geological provinces offshore the SW Iberia: Highlights of the NEAREST-SEIS wide-angle seismic survey

    Science.gov (United States)

    Martínez-Loriente, S.; Sallares, V.; Gailler, A.; Bartolome, R.; Gracia, E.; Gutscher, M.; Diaz, J.

    2011-12-01

    The SW Iberian margin hosts the present day NW-SE plate convergence between the European and African Plates at a rate of 4.5 mm/yr causing seismic activity of moderate magnitude. During fall 2008 and in the frame of the EU-funded NEAREST project, was carried out a wide-angle seismic survey (NEAREST-SEIS cruise) consisting in 2 profiles. The main objectives of the survey were to gather information about the geometry of the crust-mantle boundary, identify the nature of the different geological provinces, obtain the physical properties of the crust, and unveil the deep geometry of the interfaces between main faults. A total of 30 OBS were deployed along profile P1, which is 356 km long and trends NW-SE running from the Tagus Abyssal Plain (TAP), Gorringe Bank (GB), Horseshoe Abyssal Plain (HAP), Coral Patch Ridge (CPR), and finally reaching the thrust-and-fold belt of the Seine Abyssal Plain (SAP). The inverted model shows four well-differentiated domains in terms of seismic structure. In the TAP there is a 3-4 km-thick sediment layer with low velocity, lying above a basement showing a remarkably high velocity (< 7 km/s), similar to that of the basement outcropping in the GB. In the HAP the sedimentary cover is thicker, showing an uppermost unit with very low velocity corresponding to the Upper Miocene Horseshoe Gravitational Unit, on top of a higher velocity lower unit, which corresponds to the Mesozoic sedimentary sequence, with a total thickness of 5 km. The basement shows the same velocity distribution as in TAP and GB, suggesting a common nature and origin. According to its seismic structure, we interpret this basement as very serpentinized, exhumed upper mantle. In contrast, the CPR and SAP show evidence for the presence of a well-developed, 6-7 km-thick oceanic crust, underlying the 2-3 km thick Mesozoic and Neogene sedimentary sequence. Profile P2 is 256 km long and trends N-S, across the Iberian margin shelf, Portimao Bank, Gulf of Cadiz imbricated wedge and

  6. Seismic structure and crustal nature of the geological provinces off the SW Iberian margin: results of the NEAREST-SEIS wide-angle seismic survey

    Science.gov (United States)

    Sallares, V.; Martinez, S.; Gailler, A.; Gutscher, M.; Bartolome, R.; Gracia, E.; Diaz, J.

    2010-12-01

    The region offshore the SW Iberian margin hosts the present-day NW-SE plate convergence between the European and African Plates causing continuous seismic activity of moderate magnitude. In autumn 2008 a Spanish-French team carried out a wide-angle seismic survey in the area (NEAREST-SEIS cruise), in the framework of the EU-funded NEAREST project. During the survey two long profiles were acquired using a pool of 36 Ocean Bottom Seismometers (OBS), to provide information about the crustal structure and nature of the different geological provinces, and to reveal the deep geometry of the main fault interfaces. A total of 30 OBS were deployed along profile P1, which is 356 km long and trends NW-SE from the Tagus abyssal plain (TAP), crossing the Gorringe bank (GB), the Horseshoe abyssal plain (HAP) and the Coral Patch Ridge (CPR), up to the thrust-and-fold belt of the Seine abyssal plain (SAP). The inverted model along this profile show four different domains. In the TAP a 3-4 km-thick, low velocity sedimentary layer covers the basement, which shows a velocity >7 km/s just 2-3 km below its top, similarly to that of the basement outcropping in the Gorringe bank. In the HAP the sedimentary cover is thicker, showing an upper unit with low velocity corresponding to the Horseshoe gravitational unit, on top of a higher velocity lower unit, which may represent the highly consolidated Mesozoic sedimentary sequence, with a total thickness of 5 km. The basement shows the same velocity distribution as in TAP and GB, suggesting a common nature and origin. According to its seismic structure, we interpret this basement as highly serpentinized, exhumed mantle. In contrast, the CPR and SAP show evidences for the presence of a well-developed, 6-7 km-thick oceanic crust, underlying the sedimentary sequence. Profile P2 is 256 km long, and trends S-N from the easternmost SAP beyond the NW Moroccan margin, crossing the Gulf of Cadiz imbricated wedge and the Portimao bank ending at the

  7. GENERAL GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2011-01-01

    <正>20110727 Dai Deqiu (Institute of Geology, Hunan University of Science and Technology, Xiangtan 411201, China); Wang Daode The Evolvement Models and Progress of Research on Formation of Ca-,Al-Rich inclusions in Chondrites (Geological Review, ISSN0371-5736, CN11-1952/P, 56(3), 2010, p.374-383, 2 illus., 1 table, 72 refs.)Key words: chondrites Ca-, Al-rich inclusions (CAIs) are the earliest assemblages formed in the solar nebula. The formation models of CAIs include gas-soild condensation, crystallization from melting or partial melting and high-temperature evaporating residues. The latest study shows similar distribution patterns of the petrographic types and sizes of CAIs in various chondrites. The petrographic characters argue that CAIs in various chemical groups of chondrites formed under similar processes and conditions probably in a same region in the solar nebula.

  8. PETROLEUM GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2011-01-01

    <正>20111769 Bai Yubin(School of Oil and Gas Resources,Xi’an University of Petroleum,Xi’an 710065,China);Zhang Hai Physical Properties and Main Controlling Factors for the Low-Permeability Reservoirs from a Oil Field in the Ordos Basin(Sedimentary Geology and Tethyan Geology,ISSN1009-3850,CN51-1593/P,30(3),2010,p.104-108,4 illus.,2 tables,5 refs.)Key words:low permeability reservoirs,reservoir properties,Ordos BasinThe Chang-2 reservoirs in A oil field in the Ordos Basin dominantly consist of fine-grainded feldspar sandstones which have low porosity and low-permeability,

  9. MATHEMATICAL GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2009-01-01

    <正>20092028 Bai Wancheng(Gold Headquarters,Chinese Armed Police Forces,Beijing 100055,China);Dong Jianle Borrowed Model Method and Application in Metallogenic Prognosis(Geology and Prospecting,ISSN0495-5331,CN11-2043/P,44(4),2008,p.60-63,1 illus.,2 tables,8 refs.,with English abstract)Key words:prediction of deposits,geological model20092029 Cao Zubao(Xi’an Branch of China Coal Research Institute,Xi’an 710054,China)Application Study on Artificial Neural Network Method in Deformation Prediction for Foundation Pit(Exploration Engineering,ISSN1672-7428,CN11-5063/TD,35(5),2008,p.38-40,43,1 illus.,6 tables,8 refs.,

  10. STRUCTURAL GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2011-01-01

    <正>20110016 Cheng Shoude(Xinjiang Institute of Geology and Mineral Recources,Urumqi 830000,China);Liu Tong The Brief Description of the Division of Tectonic Units in the Five-Countries in Central Asia(Xinjiang Geology,ISSN1000-8845,CN65-1092/P,28(1),2010,p.16-21,1 illus.,21 refs.)Key words:tectonics,tectonic units,Central Asia The Five-Countries in Central-Asia border on Xinjiang in the West China,research have been performed in this area,the gists of the division of tectonic units are different from each other and the results are different in a thousand and one ways.According as the investigations of sedimentary formation,conformation,

  11. GEOTHERMICS GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    <正>20080401 Ding Kuan(Coal Mine Managing Branch Company of Datong Mining Industry Group Company,Datong 037003,China) Surveying the Thickness of the Coal Bed by the Method of Reflecting Wave from Synchronistical Shifting of Stimulating and Receiving(Gansu Geology,ISSN1004-4116,CN62-1191/P,16(1-2),2007,p.93-96,70,3 illus.,4 tables,5 refs.)

  12. GEOTHERMICS GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2015-01-01

    20151782 Ding Zhaoqin(Institute of Geophysical Exploration of Jilin Province,Changchun130012,China);Xu Zhihe The Possibility of Structure and Occurrence Geothermal Resources in Dunhua-Mishan Fault Zone(Huinan Section)(Jilin Geology,ISSN1001-2427,CN22-1099/P,33(2),2014,p.98-102,5illus.,1table,4refs.)Key words:geothermal resources,fracture

  13. MATHEMATICAL GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2004-01-01

    <正>20041769 Fang Rui (Department of Earth Sciences, Nanjing University, Nanjing, Jiangsu); Wu Jichun Design and Implementation of New Spatial Database of Groundwa-ter (Hydrogeology & Engineering Geology, ISSN 1000-3665, CN11-2202/P, 30(5), 2003, p. 33 -36, 4 illus. , 1 table, 8 refs. ) Key words: groundwater, data basesBased on system of relational database, a data model of groundwater spatial information

  14. STRUCTURAL GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    <正>20080022 Bai Daoyuan(Hunan Institute of Geology Survey,Xiangtan 411100,China);Xong Yanwang Forming Ages and Uplift Size of the Middle Kunlun Mountain--Based on Study of Plantation Surface and Apatite Fission-Track Ages(Resources Survey & Environment,ISSN1671-4814,CN32-1640/N,28(1),2007,p.5-11,4 illus.,23 refs.)

  15. GEOTHERMICS GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2014-01-01

    <正>20141588 Guo Shiyan(Green Energy Geothermai Development Co.,SINOPEC,Xianyang 712000,China);Li Xiaojun Reservoir Stratum Characteristics and Geothermal Resources Potential of Rongcheng Uplift Geothermal Field in Baoding,Hebei Province(Chinese Journal of Geology,ISSN0563-5020,CN11-1937/P,48(3),2013,p.922-931,2 illus.,4 tables,10 refs.)Key words:geothermal fields,Hebei Province

  16. STRUCTURAL GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    <正>20082072 Chen Bailin(Institute of Geome- chanics,Chinese Academy of Geological Sci- ences,Beijing 100081,China);Wu Ganguo Baldunzl-Xiaoxigong Ductile Shear Zone and Its Ore-Controlling Effect in the Southern Beishan Area,Gansu Province (Journal of Geomeehanics,ISSN 1006—6616,CN11—3672/P,13(2),2007,p.99—109,3 illus.,4 tables,26 refs.)

  17. ECONOMIC GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    <正>20082275 He Longqing(Yichang Institute of Geology and Mineral Resources,Yichang 443003,China);Ji Wei Ore-Controlling Effect of Nappe Structure in the East Ore Zone of the Baiyangping Area,Lanping Basin,Yunnan Province(Journal of Geome- ehanics,ISSN1006—6616,CN11—3672/P, 13(2),2007,p.110—118,6 illus.,2 tables,28 refs.) Key words:nappes,structural controls, Yunnan Province

  18. ENGINEERING GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2012-01-01

    <正>20122683 Cao Guangpeng ( State Key Laboratory of Geohazard Prevention and Geoenvironment Protection,Chengdu University of Technology,Chengdu 610059,China );Li Yusheng A Rock-Mechanical Study on the Stability of the Xigu Power Transmission Sta-tion Site in Jiulong County,Sichuan Province ( Journal of Geological Hazards and Environment Preservation,ISSN1006-4362,CN51-1467 / P,22 ( 4 ), 2011,p.46-49,2illus.,3 tables,5refs. )

  19. ENVIRONMENTAL GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2014-01-01

    <正>20140527Chen Hailong(State Key Laboratory of Geo-Hazard Prevention and Geo-Environment Protection,Chengdu University of Technology,Chengdu 610059,China);Chen Dingcai Features of the Typical Mine Debris Flows in Guizhou Province(Journal of Geological Hazards and Environment Preservation,ISSN1006-4362,CN51-1467/P,24(1),2013,p.9-13,2illus.,1table,6refs.)Key words:debris flows,mine,Guizhou Province

  20. STRUCTURAL GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2015-01-01

    20151407 Bai Daoyuan(Hunan Institute of Geology Survey,Changsha 410016,China);Zhong Xiang Study on the Deformation in the Southern Xuefeng Orogenic Belt(Geotectonica et Metallogenia,ISSN1001-1552,CN44-1595/P,38(3),2014,p.512-529,14illus.,71refs.,with English abstract)Key words:orogenic belts,tectonic deformation,Hunan Province

  1. COAL GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2014-01-01

    <正>20141574 Chen Hao(Exploration and Development Research Institute,Daqing Oilfield Company,Daqing 163712,China)High-Resolution Sequences and Coal Accumulating Laws in Nantun Formation of Huhe Lake Sag(Petroleum Geology&Oilfield Development in Daqing,ISSN1000-3754,CN23-1286/TQ,32(4),2013,p.15-19,5 illus.,15 refs.)Key words:coal accumulation regularity,coal

  2. EXTRATERRESTRIAL GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    <正>20070001 Liang Ying (State Key Laboratory for Mineral Deposits Research, Department of Earth Sciences, Nanjing University, Nanjing 210093, China); Wang Henian Petrology-Mineralogy and Classification of Eleven Ordinary Chondrites from the Grove Mountains in Antarctica (Geological Journal of China Universities, ISSN1006-7493, CN32-1440/P,12(1), 2006, p.53-61, 6 illus., 4 tables, 21 refs.) Key words: meteorites, Antarctica

  3. MATHEMATICAL GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    <正>20072979 Hang Bangming(Jiangning Branch,Nanjing Bureau of Land and Resources,Nanjing 211100,China);Hua Jianwei Application of 3-D GIS Technology in Environmental Supervision of Open Pit Mines(Jiangsu Geology,ISSN1003-6474,CN32-1258/P,30(4),2006,p.275-279,7 illus.,6 refs.)Key words:geographic information systems,mine environmentBased on a

  4. MATHEMATICAL GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2014-01-01

    <正>20140556Tang Hongxu(State Key Laboratory of Geo-Hazard Prevention and Geo-Environment Protection,Chengdu University of Technology,Chengdu 610059,China);Zhu Jing Three-Dimensional Terrain Model Based on GAMBIT(Journal of Geological Hazards and Environment Preservation,ISSN1006-4362,CN51-1467/P,24(1),2013,p.61-65,2illus.,7refs.)Key words:debris flows,three-dimensional models,ARCGIS,GAMBIT,C language

  5. MATHEMATICAL GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2015-01-01

    20151343Chen Jianping(China University of Geosciences,Beijing100083,China);Yu Miao Method and Practice of 3DGeological Modeling at Key Metallogenic Belt with Large and Medium Scale(Acta Geologica Sinica,ISSN0001-5717,CN11-1951/P,88(6),2014,p.1187-1195,9illus.,22refs.)Key words:geological modeling,metallogenic

  6. MATHEMATICAL GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2014-01-01

    <正>20141850 Chen Dongyue(School of Earth Sciences and Resources,China University of Geosciences,Beijing 100083,China);Chen Jianping On 3D Ore Prospecting Modeling of Comprehensive Information for Huangshaping Polymetallic Deposit(Journal of Geology,ISSN1674-3636,CN32-1796/P,37(3),2013,p.489-495,12 illus.,12 refs.) Key words:polymetallic ores,data bases,Hunan Province

  7. ECONOMIC GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2011-01-01

    <正>20111702 He Ying(Depart ment of Geology,Northwest University,Xi’an710069,China);Yue KefenInhomogeneity of Relationship Between Lithospheric Thinning and Mineralization(Journal of Earth Sciences and Environment,ISSN1672-6561,CN61-1423/P,32(3),2010,p.221-224,233,63refs.)Key words:metallogenesis,lithosphere,crustal thinning

  8. MATHEMATICAL GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2010-01-01

    <正>20102798 Gao Shengxiang(School of Resource and Earth Science,China University of Mining and Technology,Xuzhou 221008,China);Ye Rongzhang Establishment of Complex Geological Body FLAC3D Model by Using MATLAB Interface Program(Coal Geology & Exploration,ISSN1001-1986,CN61-1155/P,37(5),2009,p.51-53,5 illus.,4 refs.,with English abstract)Key words:FLAC3D,computer programs20102799 Li Xiuzhen(Key Laboratory of Mountain Hazards and Surface Processes,Chinese Academy of Sciences,Chengdu 610041,China);Wang Chenghua Potential Landslide Identification Model Based on Fisher Discrimination Analysis Method and Its Application(The Chinese Journal of Geological Hazard and Control,ISSN1003-8035,CN11-2825/P,20(4),2009,p.23-26,40,2 tables,11 refs.)Key words:mathematical models,landslidesAiming at ancient(old)landslides,four kinds of discrimination indexes which included nine secondary indexes for potential landslides,such as landform character,slip surface character,landslide body structure and recent activities characters,were presented.Then according to Fisher Discrimination theory,Fisher Discrimination model for the potential landslides was built.The re

  9. Chapter 27: Geology and petroleum potential of the north and east margins of the Siberian Craton, north of the Arctic Circle

    Science.gov (United States)

    Klett, T.R.; Wandrey, C.J.; Pitman, J.K.

    2011-01-01

    The Siberian Craton consists of crystalline rocks and superimposed Precambrian sedimentary rocks deposited in rift basins. Palaeozoic rocks, mainly carbonates, were deposited along the margins of the craton to form an outwardly younger concentric pattern that underlies an outward-thickening Mesozoic sedimentary section. The north and east margins of the Siberian Craton subsequently became foreland basins created by compressional deformation during collision with other tectonic plates. The Tunguska Basin developed as a Palaeozoic rift/sag basin over Proterozoic rifts. The geological provinces along the north and east margins of the Siberian Craton are immature with respect to exploration, so exploration-history analysis alone cannot be used for assessing undiscovered petroleum resources. Therefore, other areas from around the world having greater petroleum exploration maturity and similar geological characteristics, and which have been previously assessed, were used as analogues to aid in this assessment. The analogues included those of foreland basins and rift/sag basins that were later subjected to compression. The US Geological Survey estimated the mean undiscovered, technically recoverable conventional petroleum resources to be approximately 28 billion barrels of oil equivalent, including approximately 8 billion barrels of crude oil, 103 trillion cubic feet of natural gas and 3 billion barrels of natural gas liquids. ?? 2011 The Geological Society of London.

  10. An azumamide C analogue without the zinc-binding functionality

    DEFF Research Database (Denmark)

    Villadsen, Jesper; Kitir, Betül; Wich, Kathrine;

    2014-01-01

    + - coordinating moiety. Herein, we describe the synthesis of an azumamide analogue lacking its native Zn 2+ -binding group and evaluation of its inhibitory activity against recombinant human HDAC1 – 11. Furthermore, kinetic investigation of the inhibitory mechanism of both parent natural product and synthetic...... analogue against HDAC3-NCoR2 is reported as well as their activity against Burkitt's lymphoma cell proliferation....

  11. A new antiproliferative noscapine analogue: chemical synthesis and biological evaluation

    OpenAIRE

    Ghaly, Peter E.; Abou El-Magd, Rabab M.; Churchill, Cassandra D. M.; Tuszynski, Jack A.; West, F. G.

    2016-01-01

    Noscapine, a naturally occurring opium alkaloid, is a widely used antitussive medication. Noscapine has low toxicity and recently it was also found to possess cytotoxic activity which led to the development of many noscapine analogues. In this paper we report on the synthesis and testing of a novel noscapine analogue. Cytotoxicity was assessed by MTT colorimetric assay using SKBR-3 and paclitaxel-resistant SKBR-3 breast cancer cell lines using different concentrations for both noscapine and t...

  12. Application of 3D Fine Geologic Modeling to the Construction of the Underground Natural Gas Storage%三维精细地质建模技术在储气库建设中的应用

    Institute of Scientific and Technical Information of China (English)

    史军

    2011-01-01

    The capacity,effectively working gas volume and peak shaving capability of the underground natural gas storage are the important index in the design of underground natural gas storage,in which the capacity is the basis of other important index of underground natural gas storage and an important factor to design engineer.The calculation of capacity of underground natural gas storage is very critical,which plays an important role not only in the construction of underground natural gas storage,but also in the upstream natural gas development and downstream natural gas demand.In the study of underground natural gas storage of ES3 gas reservoir of Yong 21 block in Shengli oil field,based on the comprehensive analysis of drilling,seismic and logging data,the 3D fine geological model and the calculation of capacity are established with the 3D visual function module and integrated exploratory development module in Petrel software,which supplies a very firm base for the comprehensive evaluation of Yong 21 underground natural gas storage.%在综合分析钻井、地震、测井等资料的基础上,利用Petrel软件的三维可视化和勘探开发一体化功能模块,建立接近油藏实际地质特征的全三维精细地质模型,并进行库容量计算。

  13. Radionuclide migration at the Koongarra uranium deposit, Northern Australia Lessons from the Alligator Rivers analogue project

    Science.gov (United States)

    Payne, Timothy E.; Airey, Peter L.

    The Koongarra uranium deposit in Northern Australia provides a ‘natural analogue’ for processes that are of relevance for assessing the safety of radioactive waste disposal. In an international project extending over two decades, the Koongarra ore body was studied to increase the understanding of radionuclide migration and retention mechanisms that might occur in the vicinity of a geological repository. The research effort included extensive characterisation of the geological, hydrological and geochemical conditions at the site. Patterns of the distribution of radionuclides (predominantly members of the 238U decay chain, but also the rare isotopes 239Pu, 99Tc and 129I) were studied in both solid and groundwater phases. The project included detailed studies of uranium adsorption on mineral surfaces, and of subsequent processes that may lead to long-term uranium immobilisation. Numerous models for uranium migration were developed during the project. This paper provides a comprehensive review of the research at Koongarra, and assesses the value of the site for integrating the results of a complex series of laboratory, modelling and field studies. The insights gained from this review of the Koongarra project may assist in maximising the potential scientific benefit of future natural analogue studies.

  14. GENERAL GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2011-01-01

    <正>20110001 Chi Han (State Key Laboratory of Geological Processes and Mineral Resources, China University of Geosciences, Beijing 100083, China); Li Chusi Shock-Metamorphosed Zircons in the Fragments of the Sudbury Breccias, Ontario, Canada (Earth Science Frontiers, ISSN1005-2321, CN11-3370/P, 17(1), 2010, p.86-92, 5 illus., 42 refs.)Key words: meteorite impacts, suevite, Canada It is widely accepted that the Sudbury structure formed by large bolide impact. To find more supporting evidences, the authors used elec

  15. PETROLEUM GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2011-01-01

    <正>20110263 Chen Anqing(State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation,Chengdu University of Technology,Chengdu 610059,China);Chen Hongde Difference of the Upper Paleozoic Lithostratigraphic Gas Reservoirs in Ordos Basin,China(Journal of Chengdu University of Technology,ISSN1671-9727,CN51-1634/N,37(2),2010,p.120-126,4 illus.,1 table,24 refs.)Key words:lithologic reservoir,stratigraphic reservoir,Ordos BasinThe Upper Paleozoic of Ordos Basin is characterized by "gas-generating in the whole basin,gas-bearing widely and gas controlled by lithology".The comparati

  16. PETROLEUM GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2010-01-01

    <正>20102418 Chen Hongde(Institute of Sedimentary Geology,Chengdu University of Technology,Chengdu 610059,China);Huang Fuxi Distribution Rule and Main Controlling Factors of the Marine Facies Hydrocarbon Substances in the Middle and Upper Parts of Yangtze Region,China(Journal of Chengdu University of Technology,ISSN1671-9727,CN51-1634/N,36(6),2009,p.569-577,7 illus.,15 refs.)Key words:marine oil generation,oil and gas accumulation,Yangtze RegionUnder the guidance of the tectonic-sequence stratigraphy,sedimentology and lithofacies palaeogeography and dynamic evolutionary view,the au

  17. GEOTHERMICS GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2009-01-01

    <正>20091762 Guo Wancheng(Xining Jiulong Engineering Investigation Ltd.,Xining 810700,China);Shi Xingmei Development and Utilization of Guide Basin’s Geothermal Resources of Qinghai Province(Hydrogeology and Engineering Geology,ISSN1000-3665,CN11-2202/P,35(3),2008,p.79-80,92,2 illus.,2 tables,2 refs.)Key words:geothermal resources,QinghaiThis paper introduced the background of geothermal conditions and the many years of geothermal exploration data in Guide Basin.Then,the authors discussed the geothermal resources feature of Guide basin and raised some opinions on the reasonable development and utilization of geothermal resources.

  18. ENVIRONMENTAL GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2010-01-01

    <正>20102721 Bian Jianmin(College of Environment and Resources,Jilin University,Changchun 130026,China);Tang Jie Hydrogeochemical Characteristics in the Arsenic Poisoning Area in Western Jilin Province(Hydrogeology and Engineering Geology,ISSN1000-3665,CN11-2202/P,36(5),2009,p.80-83,4 illus.,2 tables,9 refs.)Key words:groundwater,arsenic,Jilin ProvinceSupported by field survey and sample test data,the SPSS is applied to analyze the relationship between arsenic concentration and chemical components.The results show that th

  19. MATHEMATICAL GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2011-01-01

    <正>20112074 Guo Si(Institute of Sedimentary Geology,Chengdu University of Technology,Chengdu 610059,China);Guo Ke Solid Mineral Reserves Estimation System Development and Practice Based on Arcgis(Computing Techniques for Geophysical and Geochemical Exploration,ISSN1001-1749,CN51-1242/P,32(5),2010,p.560-564,458,10 illus.,4 tables,18 refs.)Key words:computer programs,prospective reservesGeostatistics is now the foundation of mineral reserves estimation,and it has become the industry standard for estimating reserves.The software development of solid mineral reserves estimates

  20. Usefulness of systematic in situ gamma-ray surveys in the radiometric characterization of natural systems with poorly contrasting geological features (examples from NE of Portugal)

    Energy Technology Data Exchange (ETDEWEB)

    Duarte, Pedro [Instituto Tecnologico e Nuclear, Unidade de Proteccao e Seguranca Radiologica, Estrada Nacional no10, Apartado 21, 2686-953 Sacavem (Portugal); Departamento de Geologia e CeGUL, Faculdade de Ciencias da Universidade de Lisboa, Campo Grande, Edificio C6, 1749-016 Lisboa (Portugal); Mateus, Antonio [Departamento de Geologia e CeGUL, Faculdade de Ciencias da Universidade de Lisboa, Campo Grande, Edificio C6, 1749-016 Lisboa (Portugal); Paiva, Isabel, E-mail: ipaiva@itn.p [Instituto Tecnologico e Nuclear, Unidade de Proteccao e Seguranca Radiologica, Estrada Nacional no10, Apartado 21, 2686-953 Sacavem (Portugal); Trindade, Romao [Instituto Tecnologico e Nuclear, Unidade de Proteccao e Seguranca Radiologica, Estrada Nacional no10, Apartado 21, 2686-953 Sacavem (Portugal); Santos, Pedro [Instituto Tecnologico e Nuclear, Unidade de Proteccao e Seguranca Radiologica, Estrada Nacional no10, Apartado 21, 2686-953 Sacavem (Portugal); Departamento de Geologia e CeGUL, Faculdade de Ciencias da Universidade de Lisboa, Campo Grande, Edificio C6, 1749-016 Lisboa (Portugal)

    2011-02-15

    This paper focuses on the starting point of various studies that are being carried out in two possible locations being considered to host a hypothetical site for a repository for low and intermediate level radioactive waste (LILW) produced in Portugal in compliance with international requirements on the long-term safety of this kind of repository. Previous studies concerning the geology of the much larger geographical areas where these locations are included were fundamental in the choice of these locations and for the design of the survey strategy. One of the fundamental assessment studies during the site-selection is the overall radiological characterization of the locations and its relation to the geology. This paper pretends to show the adequability of using a fast and reasonably inexpensive survey technique such as in situ gamma-ray portable detectors, to access the radiometric response of the systems in study by providing the radiometric mapping of the areas. The existence of adequate radiometric maps represents a critical pre-requisite to constrain both the number and spatial distribution of samples to be collected for further analysis, sustaining as well the subsequent extrapolation of results needed to fully characterise the surveyed system. Both areas were surveyed using portable gamma-ray spectrometers with NaI(Tl) detectors. In situ gamma-ray measurements have clearly shown not only the poorly contrasting geological features, but also their differences representing: (i) a deformed/metamorphosed ophiolite complex and (ii) a monotonous meta-sedimentary sequence. The radiometric maps obtained have show heterogeneities that reflect mostly changes in rock-forming mineral assemblages, even in the presence of small variations of gamma radiation. These maps support objective criteria about the number/distribution of samples to be collected for subsequent comprehensive studies and reinforce the valuable contribution of in situ gamma spectrometry to assess, in

  1. Vorticity in analogue gravity

    CERN Document Server

    Cropp, Bethan; Turcati, Rodrigo

    2015-01-01

    In the analogue gravity framework, the acoustic disturbances in a moving fluid can be described by an equation of motion identical to a relativistic scalar massless field propagating in a curved spacetime. This description is possible only when the fluid under consideration is barotropic, inviscid and irrotational. In this case, the propagation of the perturbations is governed by an acoustic metric which depends algebrically on the local speed of sound, density and the background flow velocity, the latter assumed to be vorticity free. In this work we provide an straightforward extension in order to go beyond the irrotational constraint. Using a charged --- relativistic and non-relativistic --- Bose--Einstein condensate as a physical system, we show that in the low momentum limit and performing the eikonal approximation we can derive a d'Alembertian equation of motion for the charged phonons where the emergent acoustic metric depends on a flow velocity in the presence of vorticity.

  2. The use of fluoride as a natural tracer in water and the relationship to geological features: Examples from the Animas River Watershed, San Juan Mountains, Silverton, Colorado

    Science.gov (United States)

    Bove, D.J.; Walton-Day, K.; Kimball, B.A.

    2009-01-01

    Investigations within the Silverton caldera, in southwestern Colorado, used a combination of traditional geological mapping, alteration-assemblage mapping, and aqueous geochemical sampling that showed a relationship between geological and hydrologic features that may be used to better understand the provenance and evolution of the water. Veins containing fluorite, huebnerite, and elevated molybdenum concentrations are temporally and perhaps genetically associated with the emplacement of high-silica rhyolite intrusions. Both the rhyolites and the fluorite-bearing veins produce waters containing elevated concentrations of F-, K and Be. The identification of water samples with elevated F/Cl molar ratios (> 10) has also aided in the location of water draining F-rich sources, even after these waters have been diluted substantially. These unique aqueous geochemical signatures can be used to relate water chemistry to key geological features and mineralized source areas. Two examples that illustrate this relationship are: (1) surface-water samples containing elevated F-concentrations (> 1.8 mg/l) that closely bracket the extent of several small high-silica rhyolite intrusions; and (2) water samples containing elevated concentrations of F-(> 1.8 mg/ l) that spatially relate to mines or areas that contain late-stage fluorite/huebnerite veins. In two additional cases, the existence of high F-concentrations in water can be used to: (1) infer interaction of the water with mine waste derived from systems known to contain the fluorite/huebnerite association; and (2) relate changes in water quality over time at a high elevation mine tunnel to plugging of a lower elevation mine tunnel and the subsequent rise of the water table into mineralized areas containing fluorite/huebnerite veining. Thus, the unique geochemical signature of the water produced from fluorite veins indicates the location of high-silica rhyolites, mines, and mine waste containing the veins. Existence of high F

  3. Benchmarking analogue models of brittle thrust wedges

    Science.gov (United States)

    Schreurs, Guido; Buiter, Susanne J. H.; Boutelier, Jennifer; Burberry, Caroline; Callot, Jean-Paul; Cavozzi, Cristian; Cerca, Mariano; Chen, Jian-Hong; Cristallini, Ernesto; Cruden, Alexander R.; Cruz, Leonardo; Daniel, Jean-Marc; Da Poian, Gabriela; Garcia, Victor H.; Gomes, Caroline J. S.; Grall, Céline; Guillot, Yannick; Guzmán, Cecilia; Hidayah, Triyani Nur; Hilley, George; Klinkmüller, Matthias; Koyi, Hemin A.; Lu, Chia-Yu; Maillot, Bertrand; Meriaux, Catherine; Nilfouroushan, Faramarz; Pan, Chang-Chih; Pillot, Daniel; Portillo, Rodrigo; Rosenau, Matthias; Schellart, Wouter P.; Schlische, Roy W.; Take, Andy; Vendeville, Bruno; Vergnaud, Marine; Vettori, Matteo; Wang, Shih-Hsien; Withjack, Martha O.; Yagupsky, Daniel; Yamada, Yasuhiro

    2016-11-01

    We performed a quantitative comparison of brittle thrust wedge experiments to evaluate the variability among analogue models and to appraise the reproducibility and limits of model interpretation. Fifteen analogue modeling laboratories participated in this benchmark initiative. Each laboratory received a shipment of the same type of quartz and corundum sand and all laboratories adhered to a stringent model building protocol and used the same type of foil to cover base and sidewalls of the sandbox. Sieve structure, sifting height, filling rate, and details on off-scraping of excess sand followed prescribed procedures. Our analogue benchmark shows that even for simple plane-strain experiments with prescribed stringent model construction techniques, quantitative model results show variability, most notably for surface slope, thrust spacing and number of forward and backthrusts. One of the sources of the variability in model results is related to slight variations in how sand is deposited in the sandbox. Small changes in sifting height, sifting rate, and scraping will result in slightly heterogeneous material bulk densities, which will affect the mechanical properties of the sand, and will result in lateral and vertical differences in peak and boundary friction angles, as well as cohesion values once the model is constructed. Initial variations in basal friction are inferred to play the most important role in causing model variability. Our comparison shows that the human factor plays a decisive role, and even when one modeler repeats the same experiment, quantitative model results still show variability. Our observations highlight the limits of up-scaling quantitative analogue model results to nature or for making comparisons with numerical models. The frictional behavior of sand is highly sensitive to small variations in material state or experimental set-up, and hence, it will remain difficult to scale quantitative results such as number of thrusts, thrust spacing

  4. Doing it with Mirrors Classical analogues for Black Hole radiation

    CERN Document Server

    Srinivasan, K

    1998-01-01

    We construct analogues for the quantum phenomena of black hole radiation in the context of {\\it classical field theory}. Hawking radiation from a (radially) collapsing star is mathematically equivalent to radiation from a mirror moving along a specific trajectory in Minkowski spacetime. We construct a classical analogue for this quantum phenomenon and use it to construct a classical analogue for black hole radiation. The radiation spectrum in quantum field theory has the power spectrum as its classical analogue. Monochromatic light is continually reflected off a moving mirror or the silvered surface of a collapsing star.The reflected light is fourier analysed by the observer and the power spectrum is constructed. For a mirror moving along the standard black hole trajectory,it is seen that the power spectrum has a ``thermal'' nature. Mirror-observer configurations like an inertial mirror observed in an accelerated observer's frame and an accelerated mirror observed in a Rindler frame are investigated and condi...

  5. STRUCTURAL GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2011-01-01

    <正>20110743 Bai Bin(State Key Laboratory of Enhanced Oil Recovery,PetroChina Research Institute of Petroleum Exploration & Development,Beijing 100083,China);Zhou Lifa Definition of Some Unconformities in the South Margin of Junggar Basin,NW China(Petroleum Exploration and Development,ISSN1000-0747,CN11-2360/TE,37(3),2010,p.270-280,9 illus.,31 refs.)Key words:unconformities,Junggar Basin The analysis of the south margin of the Junggar Basin and the rock lithologies and attitudes of 18 field geologic sections in its adjacent area reveals that 9 regional unconformities,dominantly angular unconformities exist.The occurrence of these unconformities is justified by geophysical evidences of logging curve and seismic profile and by geochemical evidences of trace elements and rare elements in mudstone samples,sandstone

  6. ENGINEERING GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2009-01-01

    <正>20091943 Cao Zubao(Xi’an Branch of China Coal Research Institute,Xi’an 710054,China);Zhu Mingcheng Application of Pipe-Roof Curtain Grouting in Construction of Coal Mine Tunnel Crossing the Fractured Zone(Exploration Engineering,ISSN1672-7428,CN11-5063/TD,35(8),2008,p.79-81,3 illus.,4 refs.,with English abstract)Key words:curtain grouting20091944 Chen Changfu(Civil Engineering College,Hunan University,Changsha 410082,China);Xiao Shujun Application of Weighted Residual Method in Whole Internal Force Calculation of Anti-Slide Pile(Hydrogeology and Engineering Geology,ISSN1000-3665,CN11-2202/P,35(4),2008,p.75-79,3 illus.,9 refs.)Key words:slide-resistant

  7. ENVIRONMENTAL GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2009-01-01

    <正>20091993 Cao Wei(Cold and Arid Regions Environmental and Engineering Research Institute,CAS,Lanzhou 730000,China);Sheng Yu Grey Relation Projection Model for the Assessment of Permafrost Environment in Coal Mining Areas(Hydrogeology and Engineering Geology,ISSN1000-3665,CN11-2202/P,35(4),2008,p.111-115,2 tables,15 refs.)Key words:miming,frozen ground,environment impact statementsDue to the intense effect of coal mining activity on permafrost,the permafrost environment in coal mining areas is very frail.It is very important to assess the permafrost environment in coal mining areas.The permafrost environment is

  8. NASA/ESMD Analogue Mission Plans

    Science.gov (United States)

    Hoffman, Stephen J.

    2007-01-01

    A viewgraph presentation exploring Earth and its analogues is shown. The topics include: 1) ESMD Goals for the Use of Earth Analogues; 2) Stakeholders Summary; 3) Issues with Current Analogue Situation; 4) Current state of Analogues; 5) External Implementation Plan (Second Step); 6) Recent Progress in Utilizing Analogues; 7) Website Layout Example-Home Page; 8) Website Layout Example-Analogue Site; 9) Website Layout Example-Analogue Mission; 10) Objectives of ARDIG Analog Initiatives; 11) Future Plans; 12) Example: Cold-Trap Sample Return; 13) Example: Site Characterization Matrix; 14) Integrated Analogue Studies-Prerequisites for Human Exploration; and 15) Rating Scale Definitions.

  9. Paired Magmatic-Metallogenic Belts in Myanmar - an Andean Analogue?

    Science.gov (United States)

    Gardiner, Nicholas; Robb, Laurence; Searle, Michael; Morley, Christopher

    2015-04-01

    Myanmar (Burma) is richly endowed in precious and base metals, having one of the most diverse collections of natural resources in SE Asia. Its geological history is dominated by the staged closing of Tethys and the suturing of Gondwana-derived continental fragments onto the South China craton during the Mesozoic-Cenozoic. The country is located at a crucial geologic juncture where the main convergent Tethyan collision zone swings south around the Namche Barwa Eastern Himalayan syntaxis. However, despite recent work, the geological and geodynamic history of Myanmar remains enigmatic. Plate margin processes, magmatism, metasomatism and the genesis of mineral deposits are intricately linked, and there has long been recognized a relationship between the distribution of certain mineral deposit types, and the tectonic settings which favour their genesis. A better knowledge of the regional tectonic evolution of a potential exploration jurisdiction is therefore crucial to understanding its minerals prospectivity. This strong association between tectonics and mineralization can equally be applied in reverse. By mapping out the spatial, and temporal, distribution of presumed co-genetic mineral deposits, coupled with an understanding of their collective metallogenetic origin, a better appreciation of the tectonic evolution of a terrane may be elucidated. Identification and categorization of metallotects within a geodynamically-evolving terrane thus provides a complimentary tool to other methodologies (e.g. geochemical, geochronological, structural, geophysical, stratigraphical), for determining the tectonic history and inferred geodynamic setting of that terrane through time. Myanmar is one such study area where this approach can be undertaken. Here are found two near-parallel magmatic belts, which together contain a significant proportion of that country's mineral wealth of tin, tungsten, copper, gold and silver. Although only a few 100 km's apart, these belts exhibit a

  10. Cobalamin analogues in humans

    DEFF Research Database (Denmark)

    Hardlei, Tore Forsingdal; Obeid, Rima; Herrmann, Wolfgang

    2013-01-01

    BACKGROUND: Haptocorrin (HC) carries cobalamin analogues (CorA), but whether CorA are produced in the body is unknown. All cobalamins (Cbl) to the foetus are delivered by the Cbl-specific protein transcobalamin (TC), and therefore analysis of cord serum for CorA may help to clarify the origin...... of CorA. METHODS: HC-CorA were quantified in paired samples of cord serum from newborns and serum from mothers (n = 69). RESULTS: The CorA-concentration was higher in cord serum (median = 380, range: 41-780 pmol/L) than in serum from the mothers (median = 160, range: 64-330 pmol/L), (p...-analysis showed CorA-peaks with retention times of 13.5, 14,5 and 16.5 min in samples from both the mother and cord serum. The peak with retention time 16.5 min constituted 24% (mother) and 45% (cord serum) of the total amount CorA, and eluted as does dicyanocobinamide. CONCLUSION: Our results support that CorA...

  11. Old Geology and New Geology

    Science.gov (United States)

    2003-01-01

    [figure removed for brevity, see original site] Released 28 May 2003Mangala Vallis one of the large outflow channels that channeled large quantities of water into the northern lowlands, long ago on geological timescales. This valley is one of the few in the southern hemisphere, as well as one of the few west of the Tharsis bulge. A closer look at the channel shows more recent weathering of the old water channel: the walls of the channel show small, dark slope streaks that form in dusty areas; and much of the surrounding terrain has subtle linear markings trending from the upper left to the lower right, which are probably features sculpted and streamlined by the wind. Geology still shapes the surface of Mars today, but its methods over the eons have changed.Image information: VIS instrument. Latitude -6, Longitude 209.6 East (150.4 West). 19 meter/pixel resolution.Note: this THEMIS visual image has not been radiometrically nor geometrically calibrated for this preliminary release. An empirical correction has been performed to remove instrumental effects. A linear shift has been applied in the cross-track and down-track direction to approximate spacecraft and planetary motion. Fully calibrated and geometrically projected images will be released through the Planetary Data System in accordance with Project policies at a later time.NASA's Jet Propulsion Laboratory manages the 2001 Mars Odyssey mission for NASA's Office of Space Science, Washington, D.C. The Thermal Emission Imaging System (THEMIS) was developed by Arizona State University, Tempe, in collaboration with Raytheon Santa Barbara Remote Sensing. The THEMIS investigation is led by Dr. Philip Christensen at Arizona State University. Lockheed Martin Astronautics, Denver, is the prime contractor for the Odyssey project, and developed and built the orbiter. Mission operations are conducted jointly from Lockheed Martin and from JPL, a division of the California Institute of Technology in Pasadena.

  12. Old Geology and New Geology

    Science.gov (United States)

    2003-01-01

    [figure removed for brevity, see original site] Released 28 May 2003Mangala Vallis one of the large outflow channels that channeled large quantities of water into the northern lowlands, long ago on geological timescales. This valley is one of the few in the southern hemisphere, as well as one of the few west of the Tharsis bulge. A closer look at the channel shows more recent weathering of the old water channel: the walls of the channel show small, dark slope streaks that form in dusty areas; and much of the surrounding terrain has subtle linear markings trending from the upper left to the lower right, which are probably features sculpted and streamlined by the wind. Geology still shapes the surface of Mars today, but its methods over the eons have changed.Image information: VIS instrument. Latitude -6, Longitude 209.6 East (150.4 West). 19 meter/pixel resolution.Note: this THEMIS visual image has not been radiometrically nor geometrically calibrated for this preliminary release. An empirical correction has been performed to remove instrumental effects. A linear shift has been applied in the cross-track and down-track direction to approximate spacecraft and planetary motion. Fully calibrated and geometrically projected images will be released through the Planetary Data System in accordance with Project policies at a later time.NASA's Jet Propulsion Laboratory manages the 2001 Mars Odyssey mission for NASA's Office of Space Science, Washington, D.C. The Thermal Emission Imaging System (THEMIS) was developed by Arizona State University, Tempe, in collaboration with Raytheon Santa Barbara Remote Sensing. The THEMIS investigation is led by Dr. Philip Christensen at Arizona State University. Lockheed Martin Astronautics, Denver, is the prime contractor for the Odyssey project, and developed and built the orbiter. Mission operations are conducted jointly from Lockheed Martin and from JPL, a division of the California Institute of Technology in Pasadena.

  13. Geology and bedrock engineering

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1985-11-15

    This book deals with geology of Korea which includes summary, geology in central part and southern part in Korea and characteristic of geology structure, limestone like geology property of limestone, engineered property of limestone, and design and construction case in limestone area. It also introduces engineered property of the cenozoic, clay rock and shale, geologic and engineered property of phyllite and stratum.

  14. SEISMIC GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2009-01-01

    <正>20091465 Cai Xuelin(College of Earth Sciences,Chengdu University of Technology,Chengdu 610059,China);Cao Jiamin Preliminary Study on the 3-D Crust Structure for the Longmen Lithosphere and the Genesis of the Huge Wenchuan Earthquake,Sichuan Province,China(Journal of Chengdu University of Technology,ISSN1671-9727,CN51-1634/N,35(4),2008,p.357-365,8 illus.,39 refs.)Key words:deep-seated structures,large earthquakes,Longmenshan Fracture ZoneBased on a structural analysis of many seismic sounding profiles,there are two fault systems in Longmen collisional orogenic belt,Sichuan Province,China.They are both different obviously and correlative closely.One is shallow fault system composed mainly of brittle shear zones in surface crust,and the other is deep fault system composed mainly of crust-mantle ductile shear zones cutting Moho discontinuity.Based on the result of researching geological structure and seismic sounding profiles,

  15. COAL GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2011-01-01

    <正>20111053 Chen Jian(School of Earth and Environment,Anhui University of Science and Technology,Huainan 232001,China);Liu Wenzhong Organic Affinity of Trace Elements in Coal from No.10 Coal-Bed at Western Huagou,Guoyang(Coal Geology & Exploration,ISSN1001-1986,CN61-1155/P,38(4),2010,p.16-20,24,3 illus.,3 tables,19 refs.)Key words:coal,minor elements,Anhui Province In order to study the organic affinity of trace elements in coal from No.10 coal-bed at western Huagou,Guoyang,10 borehole samples were collected at exploration area of Huaibei mining area.The contents of 12 kinds of trace elements were determined by the inductively coupled plasma mass spectrometry(ICP-MS),the total organic carbon(TOC)of coal was determined by LECO carbon and sulfur analyzer,and the organic affinity of trace elements were deduced from the correlations between contents and TOCs.The results showed that the contents of V,Cr,Co,Ni,Mo,Cd,Sb,Pb and Zn were lower than

  16. PETROLEUM GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2011-01-01

    <正>20110957 Bai Jingru(Engineering Research Centre of Ministry of Education for Comprehensive Utilization of Oil Shale,Northeast Dianli University,Jilin 132012,China);Wang Qing Basic Physicochemical Characteristics of the Huadian Oil Shale Semi-Cokes(Journal of Jilin University,ISSN1671-5888,CN22-1343/P,40(4),2010,p.905-911,5 illus.,8 tables,10 refs.,with English abstract)Key words:oil shale,Jilin Province20110958 Chen Jingyi(Faculty of Resources and Information Technology,China University of Petroleum,Beijing 102249,China);Wang Feiyu Maturity and Genetic Type of Crude Oils in Qikou Sag,Bohai Bay Basin(Xinjiang Petroleum Geology,ISSN1001-3873,CN65-1107/TE,31(3),2010,p.242-244,7 illus.,4 refs.)Key words:crude oil,Bohaiwan Basin Qikou sag is one of the rich-oil areas in Bohai Bay Basin,in which three sets of lacustrine source rocks developed in Tertiary and Paleozoic reservoirs.The geochemical analyses of 59 crude oil and 102 source rock samples from Qikou sag show that the crude oils in Qikou sag belong to mature oil,combined with the biomarkers of n-alkanes,steroid and terpenoid as well as light hydrocarbons index,

  17. natural

    Directory of Open Access Journals (Sweden)

    Elías Gómez Macías

    2006-01-01

    Full Text Available Partiendo de óxido de magnesio comercial se preparó una suspensión acuosa, la cual se secó y calcinó para conferirle estabilidad térmica. El material, tanto fresco como usado, se caracterizó mediante DRX, área superficial BET y SEM-EPMA. El catalizador mostró una matriz de MgO tipo periclasa con CaO en la superficie. Las pruebas de actividad catalítica se efectuaron en lecho fijo empacado con partículas obtenidas mediante prensado, trituración y clasificación del material. El flujo de reactivos consistió en mezclas gas natural-aire por debajo del límite inferior de inflamabilidad. Para diferentes flujos y temperaturas de entrada de la mezcla reactiva, se midieron las concentraciones de CH4, CO2 y CO en los gases de combustión con un analizador de gases tipo infrarrojo no dispersivo (NDIR. Para alcanzar conversión total de metano se requirió aumentar la temperatura de entrada al lecho a medida que se incrementó el flujo de gases reaccionantes. Los resultados obtenidos permiten desarrollar un sistema de combustión catalítica de bajo costo con un material térmicamente estable, que promueva la alta eficiencia en la combustión de gas natural y elimine los problemas de estabilidad, seguridad y de impacto ambiental negativo inherentes a los procesos de combustión térmica convencional.

  18. California Geological Survey Geologic Map Index

    Data.gov (United States)

    California Department of Resources — All the individual maps from the Geologic Atlas of California and the Regional Geologic map series have been georeferenced for display in a GIS (and viewable online...

  19. Geologic Map of Alaska: geologic units

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This dataset consists of a polygon coverage and associated attribute data derived from the 1980 Geologic Map of Alaska compiled by H.M. Beikman and published by the...

  20. Des analogues naturels de sites de stockage de déchets nucléaires vieux de 2 milliards d'années : les réacteurs de fission nucléaire naturels du Gabon (Afrique)

    Science.gov (United States)

    Gauthier-Lafaye, François

    2002-10-01

    Two billion years ago, the increase of oxygen in atmosphere and the high 235U/ 238U uranium ratio (>3%) made possible the occurrence of natural nuclear reactors on Earth. These reactors are considered to be a good natural analogue for nuclear waste disposal. Their preservation during such a long period of time is mainly due to the geological stability of the site, the occurrence of clays surrounding the reactors and acting as an impermeable shield, and the occurrence of organic matter that maintained the environment in reducing conditions, favourable for the stability of uraninite. Hydrogeochemical studies and modelling have shown the complexity of the geochemical system at Oklo and Bangombé (Gabon) and the lack of precise data about uranium and fission products retention and migration mechanisms in geological environments. To cite this article: F. Gauthier-Lafaye, C. R. Physique 3 (2002) 839-849.

  1. Arctic Geology (geoarcst)

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — The digitally compiled map includes geology, oil and gas field centerpoints, and geologic provinces of the Arctic (North Pole area encircled by 640 N Latitude). The...

  2. The relevance of analogue studies for understanding obsessions and compulsions.

    Science.gov (United States)

    Abramowitz, Jonathan S; Fabricant, Laura E; Taylor, Steven; Deacon, Brett J; McKay, Dean; Storch, Eric A

    2014-04-01

    Analogue samples are often used to study obsessive-compulsive (OC) symptoms and related phenomena. This approach is based on the hypothesis that results derived from such samples are relevant to understanding OC symptoms in individuals with a diagnosis of obsessive-compulsive disorder (OCD). Two decades ago, Gibbs (1996) reviewed the available literature and found initial support for this hypothesis. Since then there have been many important advances addressing this issue. The purpose of the present review was to synthesize various lines of research examining the assumptions of using analogue samples to draw inferences about people with OCD. We reviewed research on the prevalence of OC symptoms in non-clinical populations, the dimensional (vs. categorical) nature of these symptoms, phenomenology, etiology, and studies on developmental and maintenance factors in clinical and analogue samples. We also considered the relevance of analogue samples in OCD treatment research. The available evidence suggests research with analogue samples is highly relevant for understanding OC symptoms. Guidelines for the appropriate use of analogue designs and samples are suggested.

  3. Metal cycling along the northwestern Seward Peninsula, Alaska: A possible natural cause of metal contamination in the arctic: A section in Geologic studies in Alaska by the U.S. Geological Survey, 1997

    Science.gov (United States)

    Parnow, C.C.; Goldfarb, Richard J.; Kelley, Karen D.; York, Geoffrey S.

    1999-01-01

    The northwestern Seward Peninsula was targeted for detailed geochemical study after evaluation of data collected during the NURE reconnaissance-level program indicated anomalously high arsenic (60-635 ppm) concentrations in stream sediments. The arsenic is associated with tin skarn, greisen, and replacement deposits in the western Seward Peninsula. Surficial sampling of waters and sediments indicate that arsenic is being transported detritally but that solution transport is insignificant. Our new data indicate that sediments downstream from these tin occurrences are characterized by anomalous values of As (85- 530 ppm) and Sn (14-36 ppm), as well as consistent anomalies of Ag, Be, Cu, Sb, and W. Stream sediments collected from drainages underlain by slate, but distal to the exposed tin occurrences, are characterized by background levels of As ( 10-60 ppm), Li (16-80 ppm), Sn (5-14 ppm), and W (5-10 ppm). These background levels for As and Sn are much higher than concentrations in typical slates and suggest a broad, weak hydrothermal alteration during mineral-deposit formation in much of the study area. A consistent pattern of Ca>>Mg>Na>K and generally alkaline pH (7 .2-8.2) characterize waters throughout the study area. Dissolved sulfate concentrations range from 10 to 40 ppm for waters draining slates and from 3 to 20 ppm for water draining carbonates. The waters collected in areas of known tin occurrences in the Potato Mountain area are characterized by increased dissolved sulfate (43-75 ppm) and are generally acidic (pH 4.7-6.5), but most trace metals are at or below detection limits. Dissolved arsenic concentrations in the areas of known tin occurrences are at or below 2 ppb. Our data suggest that detrital arsenic and tin from mineral occurrences may be naturally entering the nearshore marine environment.

  4. A Study on Effective Evaluation Methods for Analyzing Effects of Nature Experiential Study : Through Case Studies on Evaluations of Geological Field Study

    OpenAIRE

    宮下, 治||ミヤシタ, オサム||Miyashita, Osamu

    2008-01-01

    In this paper, I examined evaluation methods through case studies in order to find out effective methods for analyzing effects of nature experiential study on students. I practiced four evaluation methods, which were often used in previous studies for evaluation of nature experiential study; (1) evaluation by contents of report in texts written by students, (2) evaluation by students'learning activities records, (3) evaluation by students' essays after classes, (4) evaluation by results of pr...

  5. Geology of Cardiff and Faraday Townships

    Energy Technology Data Exchange (ETDEWEB)

    Hewitt, D.F.

    1959-12-31

    The area described in this report lies at the centre of the Haliburton-Bancroft uranium district in Ontario, where prospecting and mining have been carried out for over 50 years. The report describes the area`s physiography, natural resources, general geology (Precambrian metasedimentary, plutonic, and granitic and syenitic rocks), structural geology, and economic geology. The latter section includes descriptions of occurrences, claims, mines, and mineral properties, including the principal uranium properties in the area.

  6. Visible Geology - Interactive online geologic block modelling

    Science.gov (United States)

    Cockett, R.

    2012-12-01

    Geology is a highly visual science, and many disciplines require spatial awareness and manipulation. For example, interpreting cross-sections, geologic maps, or plotting data on a stereonet all require various levels of spatial abilities. These skills are often not focused on in undergraduate geoscience curricula and many students struggle with spatial relations, manipulations, and penetrative abilities (e.g. Titus & Horsman, 2009). A newly developed program, Visible Geology, allows for students to be introduced to many geologic concepts and spatial skills in a virtual environment. Visible Geology is a web-based, three-dimensional environment where students can create and interrogate their own geologic block models. The program begins with a blank model, users then add geologic beds (with custom thickness and color) and can add geologic deformation events like tilting, folding, and faulting. Additionally, simple intrusive dikes can be modelled, as well as unconformities. Students can also explore the interaction of geology with topography by drawing elevation contours to produce their own topographic models. Students can not only spatially manipulate their model, but can create cross-sections and boreholes to practice their visual penetrative abilities. Visible Geology is easy to access and use, with no downloads required, so it can be incorporated into current, paper-based, lab activities. Sample learning activities are being developed that target introductory and structural geology curricula with learning objectives such as relative geologic history, fault characterization, apparent dip and thickness, interference folding, and stereonet interpretation. Visible Geology provides a richly interactive, and immersive environment for students to explore geologic concepts and practice their spatial skills.; Screenshot of Visible Geology showing folding and faulting interactions on a ridge topography.

  7. PETROLEUM GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2014-01-01

    <正>20140280Bi Hailong(College of Energy Resources,Chengdu University of Technology,Chengdu 610059,China);Zhou Wen Distribution Prediction and Evaluation of Natural Fractures in 2nd Xu Member Gas Reservoirs,Xinchang Area,West Sichuan Basin(Computing Techniques for Geophysical and Geochemical Exploration,ISSN1001-1749,CN51-1242/P,35(1),2013,p.76-78,1illus.,1table,7refs.)

  8. Condensed matter analogues of cosmology

    Science.gov (United States)

    Kibble, Tom; Srivastava, Ajit

    2013-10-01

    liveliest. A number of new experiments are reported here studying the dynamical evolution of domains and defects. Another phenomenon that played a key early role was the formation of vortices in the normal-to-superfluid transition in liquid helium-3. The complicated nature of the order parameter energy surface gives rise to a variety of intriguing effects. This too is still a vigorous field. Superconductivity is a special case because the symmetry that is broken is a gauge symmetry. This is also true in fundamental particle physics theories of relevance to cosmology, and for that reason experiments on superconductors are of particular interest to cosmologists. The situation in this case is more complicated because there are competing mechanisms of defect formation. Experiments in the field have not proved easy, either to perform or to interpret, but the papers in this collection show that good progress has been made of late. In recent years a new type of system has proved immensely fruitful, namely atomic Bose-Einstein or Fermi-gas condensates. Experiments on condensates with tunable parameters have in general provided broad support for the theory, and have also revealed a wide range of interesting and novel features, with intriguing possible analogues in cosmology (e.g. causal horizons and particle creation). The basic idea of the Kibble-Zurek mechanism has been shown to be relevant in this whole range of systems. But numerous complexities have also emerged, concerned for example with the role of inhomogeneity or the existence of composite defects. The field is still developing rapidly. Acknowledgments Finally, we would like to thank all the authors who have contributed to this issue, and the staff of Journal of Physics: Condensed Matter who have made it possible. Condensed matter analogues of cosmology contents Condensed matter analogues of cosmologyTom Kibble and Ajit Srivastava Symmetry breaking in nematic liquid crystals: analogy with cosmology and magnetismR Repnik, A

  9. Analogues of uracil nucleosides with intrinsic fluorescence (NIF-analogues): synthesis and photophysical properties.

    Science.gov (United States)

    Segal, Meirav; Fischer, Bilha

    2012-02-28

    Uridine cannot be utilized as fluorescent probe due to its extremely low quantum yield. For improving the uracil fluorescence characteristics we extended the natural chromophore at the C5 position by coupling substituted aromatic rings directly or via an alkenyl or alkynyl linker to create fluorophores. Extension of the uracil base was achieved by treating 5-I-uridine with the appropriate boronic acid under the Suzuki coupling conditions. Analogues containing an alkynyl linker were obtained from 5-I-uridine and the suitable boronic acid in a Sonogashira coupling reaction. The uracil fluorescent analogues proposed here were designed to satisfy the following requirements: a minimal chemical modification at a position not involved in base-pairing, resulting in relatively long absorption and emission wavelengths and high quantum yield. 5-((4-Methoxy-phenyl)-trans-vinyl)-2'-deoxy-uridine, 6b, was found to be a promising fluorescent probe. Probe 6b exhibits a quantum yield that is 3000-fold larger than that of the natural chromophore (Φ 0.12), maximum emission (478 nm) which is 170 nm red shifted as compared to uridine, and a Stokes shift of 143 nm. In addition, since probe 6b adopts the anti conformation and S sugar puckering favored by B-DNA, it makes a promising nucleoside analogue to be incorporated in an oligonucleotide probe for detection of genetic material.

  10. Semisynthetic analogues of the microtubule-stabilizing agent discodermolide: preparation and biological activity.

    Science.gov (United States)

    Gunasekera, Sarath P; Longley, Ross E; Isbrucker, Richard A

    2002-12-01

    A series of 12 semisynthetic discodermolide analogues, 2-13, have been prepared using natural (+)-discodermolide (1) and evaluated for in vitro cytotoxicity against cultured murine P-388 leukemia and A-549 human adenocarcinoma cells. These semisynthetic analogues showed a significant variation of cytotoxicity and confirmed the importance of the C-7 through C-19 molecular fragment for potency. Specifically, these analogues suggested the importance of the C-11 and C-17 hydroxyl groups and the C-13 double bond for the potency of discodermolide. The preparation, structure elucidation, and biological activity of these new analogues are described.

  11. Acetylated analogues of the microtubule-stabilizing agent discodermolide: preparation and biological activity.

    Science.gov (United States)

    Gunasekera, S P; Longley, R E; Isbrucker, R A

    2001-02-01

    A series of eight discodermolide acetates have been prepared using natural (+)-discodermolide and evaluated for in vitro cytotoxicity against the cultured murine P-388 leukemia cells. The acetylated analogues showed a significant variation of cytotoxicity and suggested the importance of C-11 and C-17 hydroxyl groups for potency. The preparation and structure elucidation of the new analogues are described.

  12. GENERAL & GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    <正>20072305 Lü Kejie(Department of Earth Sciences,National Natural Science Foundation of China,Beijing 100085,China);Zhou Xiaogang New Principles and Technology on the Analysis of the Earth System Priority Funding Areas and Earth System Science(Advances in Earth Science,ISSN1001-8166,CN62-1091/P,21(10),2006,p.1097-1100,1 table,2 refs.)Key words:earth system science Earth system science is the science that deals with the interactions between and among subsystems,Earth’s overall structure,characteristics and behavior,law and control mechanism of Earth system changes.

  13. Oil and Gas Information Center of Rio de Janeiro Geological Survey; Criacao do Centro de Informacoes sobre Petroleo e Gas Natural do Servico Geologico do Estado do Rio de Janeiro

    Energy Technology Data Exchange (ETDEWEB)

    Dourado, Francisco; Serrao, Marcio; Ferreira, Ana Paula; Silva, Jose Otavio da; Chaves, Hernani [Centro de Informacoes sobre Petroleo e Gas Natural do Estado do Rio de Janeiro (CIPEG), Rio de Janeiro (Brazil)

    2008-07-01

    The Oil and Gas Information Center (CIPEG) of Rio de Janeiro Geological Survey concentrates data of oil and natural gas (O and G) industry in the State of Rio de Janeiro (RJ) and meet a specialist staff to work with this data. The CIPEG works in partnership with the Geology School of Rio de Janeiro State University. Its creation was motivated by the government necessity to dominate the techniques to calculate the Government take for the production of O and G front the RJ position in the national oil industry. In 2007, the Rio de Janeiro was responsible for 84% of domestic production of oil and of 91 municipalities, 86 received royalties. These resources represent substantial share in the budget of municipalities and the State, and any variation, could be bring deep impact on the economy of these counties and the State. The products of CIPEG are: a map of O and G industry in Rio de Janeiro, a Database, a GIS and a Timing of Predicting Production of O and G. These products are available through a Internet page with accompanying by graphs of the production of O and G or royalties and Web map for viewing the information in the GIS. (author)

  14. Engineering Geology Maps for Planning and Management of Natural Parks: “Las Batuecas-Sierra de Francia” and “Quilamas” (Central Spanish System, Salamanca, Spain

    Directory of Open Access Journals (Sweden)

    Mariano Yenes

    2013-01-01

    Full Text Available Presented herein is a cartographic procedure that is easy to utilise and at low-cost, which facilitates the first stages of planning and management of a naturally protected space and considers the geotechnical parameters that influence human activity. This procedure uses geographical information systems technology by combining the cartographies for the most influential parameters on the stability of the area (lithology, hydrogeology, geomorphology, slopes, lineament/fractures and seismicity with geomechanical mapping generated from geotechnical parameters obtained through field and laboratory tests. This geotechnical mapping facilitates the division of a territory into zones according to each type of problem and generates a cartography for natural hazards. Using this information, it is possible to produce a cartography of constructive conditions or geotechnical hazards. This methodology has been validated by application to two natural protected spaces, “Las Batuecas-Sierra de Francia” and “Quilamas”. The validation confirmed that the cartography procedure described herein is a preventive, and not a structural measure. It is a tool that delimits areas with different constructive use recommendations and limitations, and therefore, is useful for natural space managers.

  15. The U. S. Geological Survey Geologic Hazards Program

    Science.gov (United States)

    Peck, D.L.

    1982-01-01

    In 1879, Congress established the U.S Geological Survey for "the classification of the public lands and the examination of the geological structure, mineral resources, and products of the national domain." Throughout the past 103 years, the Survey has successfully fulfilled these responsibilities, but it has also been responsive to changing national needs. This responsiveness is well exemplified by the development of the agency's natural hazard programs. Our orignial mision has been expanded to include formal investigations of earthquakes, volcanic eruptions, ground failures, and flood hazards. 

  16. Click-based synthesis and proteomic profiling of lipstatin analogues

    OpenAIRE

    Ngai, Mun H.; Yang, Peng-Yu; Liu, Kai; Shen, Yuan; Wenk, Markus R; Yao, Shao Q.; Lear, Martin J.

    2010-01-01

    Using click chemistry to enable both structural diversity and proteome profiling within a natural product derived library, two out of nineteen lipstatin analogues showed similar activity to Orlistat against fatty acid synthase (FAS), but with an improved ability to induce tumour cell death.

  17. OCEANOGRAPHY & MARINE GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2015-01-01

    20152177 Chen Hongjun(Key Laboratory of Marine Mineral Resources,Guangzhou Marine Geological Survey,Ministry of Land and Resources,Guangzhou 510075,China);Pen Xuechao A Brief Review of 1∶1 000 000 Marine Geological Survey and Mapping Results of the Hainan Sheet in the South China Sea(Marine Geology&Quaternary Geology,

  18. OCEANOGRAPHY & MARINE GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2014-01-01

    <正>20140582 Fang Xisheng(Key Lab.of Marine Sedimentology and Environmental Geology,First Institute of Oceanography,State Oceanic Administration,Qingdao 266061,China);Shi Xuefa Mineralogy of Surface Sediment in the Eastern Area off the Ryukyu Islands and Its Geological Significance(Marine Geology & Quaternary Geology,ISSN0256-1492,CN37

  19. QUATERNARY GEOLOGY& GEOMORPHOLOGY

    Institute of Scientific and Technical Information of China (English)

    2016-01-01

    20160466Cao Fugen(No.1Geological Survey Team,Xinjiang Bureau of Geology and Mineral Resources and Development,Urumqi830013,China);Zhao Shuming Geological Characteristics and Significance of the Nanhua Period Tillite from Northern Yamansu Area in Eastern Tianshan,Xinjiang(Xinjiang Geology,ISSN1000-8845,CN65-1092/P,33

  20. Investigations of natural groundwater hazards at the proposed Yucca Mountain high level nuclear waste repository. Part A: Geology at Yucca Mountain. Part B: Modeling of hydro-tectonic phenomena relevant to Yucca Mountain. Annual report - Nevada

    Energy Technology Data Exchange (ETDEWEB)

    Szymanski, J.S.; Schluter, C.M.; Livingston, D.E. [and others

    1993-05-01

    This document is an annual report describing investigations of natural groundwater hazards at the proposed Yucca Mountain, Nevada High-Level Nuclear Waste Repository.This document describes research studies of the origin of near surface calcite/silica deposits at Yucca Mountain. The origin of these deposits is controversial and the authors have extended and strengthened the basis of their arguments for epigenetic, metasomatic alteration of the tuffs at Yucca Mountain. This report includes stratigraphic, mineralogical, and geochronological information along with geochemical data to support the conclusions described by Livingston and Szymanski, and others. As part of their first annual report, they take this opportunity to clarify the technical basis of their concerns and summarize the critical geological field evidence and related information. Selected papers are indexed separately for inclusion in the Energy Science and Technology Database.

  1. International Medical Geology Association (IMGA) formed

    Institute of Scientific and Technical Information of China (English)

    Olle Selinus; Jose Centeno; Robert Finkelman

    2006-01-01

    @@ "Medical Geology" is defined as the science dealing with the relationship between natural geological factors and health problems in man and animals and understanding the influence of ordinary environmental factors on the geographical distribution of such health problems. Medical Geology is therefore a broad and complicated subject and if the problems to be addressed are to be understood, mitigated, or resolved, it will require interdisciplinary contributions from different scientific fields (involving geo-scientists,medical scientists, health professionals, veterinarians, and biologists, etc.). Medical Geology involves the whole geo-sphere and can be considered as dealing with ecosystem health.

  2. Derivatisable Cyanobactin Analogues: A Semisynthetic Approach.

    Science.gov (United States)

    Oueis, Emilia; Adamson, Catherine; Mann, Greg; Ludewig, Hannes; Redpath, Philip; Migaud, Marie; Westwood, Nicholas J; Naismith, James H

    2015-12-01

    Many natural cyclic peptides have potent and potentially useful biological activities. Their use as therapeutic starting points is often limited by the quantities available, the lack of known biological targets and the practical limits on diversification to fine-tune their properties. We report the use of enzymes from the cyanobactin family to heterocyclise and macrocyclise chemically synthesised substrates so as to allow larger-scale syntheses and better control over derivatisation. We have made cyclic peptides containing orthogonal reactive groups, azide or dehydroalanine, that allow chemical diversification, including the use of fluorescent labels that can help in target identification. We show that the enzymes are compatible and efficient with such unnatural substrates. The combination of chemical synthesis and enzymatic transformation could help renew interest in investigating natural cyclic peptides with biological activity, as well as their unnatural analogues, as therapeutics.

  3. Five new discodermolide analogues from the marine sponge Discodermia species.

    Science.gov (United States)

    Gunasekera, Sarath P; Paul, Gopal K; Longley, Ross E; Isbrucker, Richard A; Pomponi, Shirley A

    2002-11-01

    Discodermolide (1) and five new discodermolide analogues trivially named 2-epi-discodermolide (2), 2-des-methyldiscodermolide (3), 5-hydroxymethyldiscodermolate (4), 19-des-aminocarbonyldiscodermolide (5), and 9(13)-cyclodiscodermolide (6) have been isolated from marine sponges belonging to the genus Discodermia collected from the Caribbean Sea. The isolation, structure elucidation, and biological activities of 2-6 are described. The natural analogues, which were isolated in trace amounts, exhibited significant variation of cytotoxicity against the cultured murine P-388 leukemia and A-549 human adenocarcinoma cells and suggested the importance of the C(7) through C(17) moiety for potency against cultured tumor cell lines.

  4. Introduction to electronic analogue computers

    CERN Document Server

    Wass, C A A

    1965-01-01

    Introduction to Electronic Analogue Computers, Second Revised Edition is based on the ideas and experience of a group of workers at the Royal Aircraft Establishment, Farnborough, Hants. This edition is almost entirely the work of Mr. K. C. Garner, of the College of Aeronautics, Cranfield. As various advances have been made in the technology involving electronic analogue computers, this book presents discussions on the said progress, including some acquaintance with the capabilities of electronic circuits and equipment. This text also provides a mathematical background including simple differen

  5. Menstrual regulation with prostaglandin analogues.

    Science.gov (United States)

    Hagenfeldt, K; Bygdeman, M

    1981-01-01

    The development of generally applicable, simple non-surgical methods for menstrual regulation has been desired for a long time. Such an approach to fertility control depends on the availability of a suitable therapeutic agent that should be effective, reliable, simple to administer and free from disturbing side effects. The classical prostaglandins have shown the capability but are unsuitable mainly due to high incidence of side effects. Most of these drawbacks seem to be overcome when prostaglandin analogues are used; however, vaginal administration caused appreciable pain in 10-30% of women, and so severely limits self-administration of these analogues.

  6. Analogue Methods in Palaeoecology: Using the analogue Package

    Directory of Open Access Journals (Sweden)

    Gavin L. Simpson

    2007-08-01

    Full Text Available Palaeoecology is an important branch of ecology that uses the subfossil remains of organisms preserved in lake, ocean and bog sediments to inform on changes in ecosystems and the environment through time. The analogue package contains functions to perform modern analogue technique (MAT transfer functions, which can be used to predict past changes in the environment, such as climate or lake-water pH from species data. A related technique is that of analogue matching, which is concerned with identifying modern sites that are floristically and faunistically similar to fossil samples. These techniques, and others, are increasingly being used to inform public policy on environmental pollution and conservation practices. These methods and other functionality in analogue are illustrated using the Surface Waters Acidification Project diatom:pH training set and diatom counts on samples of a sediment core from the Round Loch of Glenhead, Galloway, Scotland. The paper is aimed at palaeoecologists who are familiar with the techniques described but not with R.

  7. Astrobiology Field Research in Moon/Mars Analogue Environments: Preface

    Science.gov (United States)

    Foing, B. H.; Stoker, C.; Ehrenfreund, P.

    2011-01-01

    Extreme environments on Earth often provide similar terrain conditions to landing/operation sites on Moon and Mars. Several field campaigns (EuroGeoMars2009 and DOMMEX/ILEWG EuroMoonMars from November 2009 to March 2010) were conducted at the Mars Desert Research Station (MDRS) in Utah. Some of the key astrobiology results are presented in this special issue on Astrobiology field research in Moon/Mars analogue environments relevant to investigate the link between geology, minerals, organics and biota. Preliminary results from a multidisciplinary field campaign at Rio Tinto in Spain are presented.

  8. Study on assessment safety of geological disposal of high level radioactive waste

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    Department of Environmental Safety Research of Japan Atomic Energy Research Institute has conducted the study on safety of geological disposal of high level radioactive waste. The long-term safety of the geological disposal is proposed to be secured by the multi barrier system which consists of engineered and natural barriers. Thus, in order to clarify the performance of the engineered barrier, we have studied on the long-term behaviors of waste forms, canister, overpack, back fill materials. We have developed a new waste form, i.e. ceramic waste form. And in order to clarify the performance of the natural barrier, we have studied on the hydrology, rock properties, geochemistry of actinides, sorption and fixation of radionuclides on and to rocks and/or minerals, alteration of minerals, dispersion behavior of radionuclides. Natural analogue studies and in-situ experiments have also been conducted. According to the methodology for the assessment established, the assessment model has been developed. (J.P.N.).

  9. New rubrolide analogues as inhibitors of photosynthesis light reactions.

    Science.gov (United States)

    Varejão, Jodieh O S; Barbosa, Luiz C A; Ramos, Gabriela Álvarez; Varejão, Eduardo V V; King-Díaz, Beatriz; Lotina-Hennsen, Blas

    2015-04-01

    Natural products called rubrolides have been investigated as a model for the development of new herbicides that act on the photosynthesis apparatus. This study comprises a comprehensive analysis of the photosynthesis inhibitory ability of 27 new structurally diverse rubrolide analogues. In general, the results revealed that the compounds exhibited efficient inhibition of the photosynthetic process, but in some cases low water solubility may be a limiting factor. To elucidate their mode of action, the effects of the compounds on PSII and PSI, as well as their partial reaction on chloroplasts and the chlorophyll a fluorescence transients were measured. Our results showed that some of the most active rubrolide analogues act as a Hill reaction inhibitors at the QB level by interacting with the D1 protein at the reducing side of PSII. All of the active analogues follow Tice's rule of 5, which indicates that these compounds present physicochemical properties suitable for herbicides. Copyright © 2015 Elsevier B.V. All rights reserved.

  10. The Immucillins: Design, Synthesis and Application of Transition- State Analogues.

    Science.gov (United States)

    Evans, Gary B; Schramm, Vern L; Tyler, Peter C

    2015-01-01

    Transition-state analysis based on kinetic isotope effects and computational chemistry provides electrostatic potential maps to serve as blueprints for the design and chemical synthesis of transition-state analogues. The utility of these molecules is exemplified by potential clinical applications toward leukemia, autoimmune disorders, gout, solid tumors, bacterial quorum sensing and bacterial antibiotics. In some cases, transition-state analogues have chemical features that have allowed them to be repurposed for new indications, including potential antiviral use. Three compounds from this family have entered clinical trials. The transition-state analogues bind to their target proteins with high affinity and specificity. The physical and structural properties of binding teach valuable and often surprising lessons about the nature of tight-binding inhibitors.

  11. Analogue earthquakes and seismic cycles: experimental modelling across timescales

    Science.gov (United States)

    Rosenau, Matthias; Corbi, Fabio; Dominguez, Stephane

    2017-05-01

    Earth deformation is a multi-scale process ranging from seconds (seismic deformation) to millions of years (tectonic deformation). Bridging short- and long-term deformation and developing seismotectonic models has been a challenge in experimental tectonics for more than a century. Since the formulation of Reid's elastic rebound theory 100 years ago, laboratory mechanical models combining frictional and elastic elements have been used to study the dynamics of earthquakes. In the last decade, with the advent of high-resolution monitoring techniques and new rock analogue materials, laboratory earthquake experiments have evolved from simple spring-slider models to scaled analogue models. This evolution was accomplished by advances in seismology and geodesy along with relatively frequent occurrences of large earthquakes in the past decade. This coincidence has significantly increased the quality and quantity of relevant observations in nature and triggered a new understanding of earthquake dynamics. We review here the developments in analogue earthquake modelling with a focus on those seismotectonic scale models that are directly comparable to observational data on short to long timescales. We lay out the basics of analogue modelling, namely scaling, materials and monitoring, as applied in seismotectonic modelling. An overview of applications highlights the contributions of analogue earthquake models in bridging timescales of observations including earthquake statistics, rupture dynamics, ground motion, and seismic-cycle deformation up to seismotectonic evolution.

  12. Novel acetylcholine and carbamoylcholine analogues

    DEFF Research Database (Denmark)

    Hansen, Camilla Petrycer; Jensen, Anders Asbjørn; Christensen, Jeppe K.

    2008-01-01

    A series of carbamoylcholine and acetylcholine analogues were synthesized and characterized pharmacologically at neuronal nicotinic acetylcholine receptors (nAChRs). Several of the compounds displayed low nanomolar binding affinities to the alpha 4beta 2 nAChR and pronounced selectivity for this ...

  13. Fetal bovine serum influences the stability and bioactivity of resveratrol analogues: A polyphenol-protein interaction approach.

    Science.gov (United States)

    Tang, Fen; Xie, Yixi; Cao, Hui; Yang, Hua; Chen, Xiaoqing; Xiao, Jianbo

    2017-03-15

    Fetal bovine serum (FBS) is a universal growth supplement of cell and tissue culture media. Herein, the influences of FBS on the stability and antioxidant activity of 21 resveratrol analogues were investigated using a polyphenol-protein interaction approach. The structure-stability relationships of resveratrol analogues in FBS showed a clear decrease in the stability of hydroxylated resveratrol analogues in the order: resorcinol-type>pyrogallol-type>catechol-type. The glycosylation and methoxylation of resveratrol analogues enhanced their stability. A linear relationship between the stability of resveratrol analogues in FBS and the affinity of resveratrol analogues-FBS interaction was found. The oxidation process is not the only factor governing the stability of resveratrol analogues in FBS. These results facilitated the insightful investigation of the role of polyphenol-protein interactions in serum, thereby providing some fundamental clues for future clinical research and pharmacological studies on natural small molecules. Copyright © 2016 Elsevier Ltd. All rights reserved.

  14. Reducing CO{sub 2} emissions to the atmosphere using the geological sequestration alternative: the research and development programs in progress; Reduire les emissions de CO{sub 2} dans l'atmosphere par l'alternative de la sequestration geologique: les programmes de recherche et developpement en cours

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-07-01

    The geological sequestration of CO{sub 2}, represents an interesting alternative for the abatement of CO{sub 2} emissions to the atmosphere. It consists in the collection of CO{sub 2} from the main industrial sources of emission and its injection in deep geological formations (exhausted oil and gas fields, deep salt reservoirs, unexploited coal deposits) for its storage during millions of years. This press meeting document presents the 4 European research and development programs in which the French bureau of geological and mining researches (BRGM) is involved: SACS (saline aquifer CO{sub 2} storage: sequestration concept in deep salt aquifer at the Sleipner natural gas field (North-Sea)), GESTCO (assessing the European potential for geological storage of CO{sub 2} from fossil fuel combustion: potentialities and technical-economical feasibility of CO{sub 2} sequestration), NASCENT (natural analogues for the storage of CO{sub 2} in the geological environment: behaviour and long-term safety of geological sequestration sites), and WEYBURN (validation of the convenience of the geological sequestration and assisted oil recovery concept at the Weyburn oil field (Canada)). (J.S.)

  15. Simultaneous preparation of four truncated analogues of discodermolide by fluorous mixture synthesis.

    Science.gov (United States)

    Curran, Dennis P; Furukawa, Takashi

    2002-06-27

    [structure: see text] Four truncated analogues of the natural product discodermolide were synthesized in a single synthetic sequence. Precursors bearing four different groups at C22, each with a unique fluorous p-methoxybenzyl substituent on the C17 hydroxy group, were mixed and taken through an nine-step sequence. Demixing by fluorous chromatography followed by deprotection and purification provided the individual analogues in 3-7% overall yields and with a savings of 24 synthetic steps. Fluorous mixture synthesis is recommended as a new technique to make multiple natural product analogues in a single multistep synthesis.

  16. Extreme light rare earth element mobilization by diagenetic fluids in the geological environment of the Oklo natural reactor zones, Franceville basin, Gabon

    Science.gov (United States)

    Cuney, Michel; Mathieu, Régis

    2000-08-01

    The anomalously high Th/La ratio (˜1.14) of the Early Proterozoic silicified sandstones of the Franceville basin (Gabon), compared to Archean and Proterozoic metasedimentary rocks (Th/La ˜0.27), results from extreme light rare earth element (REE) migration during diagenesis. Monazite, which represents the main light REE-bearing phase in the sandstones, was altered by diagenetic brines at 140 °C and 1 kbar. The alteration phase is a microcrystalline Th-silicate phase, indicating low Th solubility at these conditions. Light REEs are simultaneously leached out together with P and U. The increase in Th/La from detrital monazite to residual Th-silicate phase indicates that about 76% of the light REEs were leached out, corresponding to a global amount of 2.01 × 109 metric tons at the scale of the FA Formation in the Franceville basin. Uranium was also leached during monazite alteration and may have contributed significantly to the genesis of the high-grade uranium deposits of the Franceville basin that host the natural nuclear reaction zones.

  17. Measuring Mental Imagery with Visual Analogue Scales.

    Science.gov (United States)

    Quilter, Shawn M.; Band, Jennie P.; Miller, Gary M.

    1999-01-01

    Investigates some of the psychometric characteristics of the results from visual-analogue scales used to measure mental imagery. Reports that the scores from visual-analogue scales are positively related to scores from longer pencil-and-paper measures of mental imagery. Implications and limitations for the use of visual-analogue scales to measure…

  18. Smaragdyrins and Sapphyrins Analogues.

    Science.gov (United States)

    Chatterjee, Tamal; Srinivasan, A; Ravikanth, Mangalampalli; Chandrashekar, Tavarakere K

    2017-02-22

    Porphyrins and expanded porphyrins have attracted the attention of chemists for a long time in view of their diverse applications in catalysis; as anion, cation, and neutral substrate receptors; as ligands to coordinate large metal ions; as nonlinear optical materials, MRI contrasting agents, and sensitizers for photodynamic therapy (PDT); and more recently as models for aromaticity (both Hückel and Möbius). A diverse range of synthetic expanded porphyrins containing up to 96π electrons have been reported, and their properties have been exploited for various applications. The present Review is only confined to 22π electron expanded porphyrins containing five pyrrole/heterocyclic rings such as sapphyrins and smaragdyrins. Even though these two macrocycles contain 22π electrons and five pyrrole/heterocyclic rings, they are structurally different. In sapphyrins, the five pyrrole/heterocyclic rings are connected through four meso-carbon bridges and one direct pyrrole-pyrrole bond, whereas in smaragdyrins, the five pyrrole/heterocyclic rings are connected through three meso-carbon bridges and two direct pyrrole-pyrrole bonds. The chemistry of sapphyrins has been well-established in recent years due to the availability of easy and efficient synthetic methods. On the other hand, smaragdyrins are not explored significantly because of their unstable nature. However, recently it was shown that smaragdyrins can be stabilized if one of the pyrrole rings is replaced with a furan ring to afford stable oxasmaragdyrin. The availability of oxasmaragdyrin allowed the exploration of smaragdyrin in recent years. Thus, an attempt has been made in this Review to describe the chemistry of both sapphyrins and smaragdyrins in terms of their synthesis, characterization, metal ion coordination, and anion-recognition properties.

  19. GEOCHRONOMETRY & ISOTOPE GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2010-01-01

    <正>20101892 Guo Hongjun (Tianjin Geological Exploration General Survey,Tianjin 300181,China);Lin Xiaohui The Precambrian Geological Characteristics of Kigoma-Mpanda Region,Tanzania and the New Data of U-Pb Age Determination on Zircon

  20. Geologic spatial analysis

    Energy Technology Data Exchange (ETDEWEB)

    Thiessen, R.L.; Eliason, J.R.

    1989-01-01

    This report describes the development of geologic spatial analysis research which focuses on conducting comprehensive three-dimensional analysis of regions using geologic data sets that can be referenced by latitude, longitude, and elevation/depth. (CBS)

  1. Geological Services Laboratory

    Data.gov (United States)

    Federal Laboratory Consortium — Researchers use computed tomography (CT) scanners at NETL’s Geological Services Laboratory in Morgantown, WV, to peer into geologic core samples to determine how...

  2. Geophysics & Geology Inspected.

    Science.gov (United States)

    Neale, E. R. W.

    1981-01-01

    Summarizes findings of a recently published report of the Canadian Geoscience Council, which includes the following topics regarding college geology: facilities; teaching; undergraduate enrollments; postgraduate enrollments; geologic research; and integration of Canadian geoscience with other countries. (CS)

  3. Word Geology – its Roots and Meanings

    Directory of Open Access Journals (Sweden)

    Mihael Brenčič

    2011-12-01

    Full Text Available In the period up to 18th century the meaning of the word geology has substantially changed; from Latin word geologia written by de Bury in the 14th century, through the use of word giologia by Aldrovandi in the beginning of 17th century and to near final definition of word geology that appeared in French Encyclopaedia from 1751.With the help of Internet some other early works not known to the literature of geology history were discovered.Among them are German books where in the title word geology is also present. Works of Zaharius Grapo, JoannesSchnabel and Johann Gregorii can be listed. Short analysis of other German geological works from the second half of the 18th century important for Slovenian territory are briefly presented. Starting from the database of earlier Slovenian publications available on the Internet an analysis of word geology early appearances in Slovene language is presented. First publication of the word root geol- appeared in newspaper Slovenija in year 1849. Amongearly authors Davorin Trstenjak was first using geological information starting in year 1853. Earliest longer textpresented information on geological work in Slovene language was published in the newspaper Novice in year 1853. Based on the available literature and other sources reinterpretation of the meaning of word geology is based in the context of its role in the natural sciences development as well as its historical context.

  4. Chemical, mineralogical and molecular biological characterization of the rocks and fluids from a natural gas storage deep reservoir as a baseline for the effects of geological hydrogen storage

    Science.gov (United States)

    Morozova, Daria; Kasina, Monika; Weigt, Jennifer; Merten, Dirk; Pudlo, Dieter; Würdemann, Hilke

    2014-05-01

    Planned transition to renewable energy production from nuclear and CO2-emitting power generation brings the necessity for large scale energy storage capacities. One possibility to store excessive energy produced is to transfer it to chemical forms like hydrogen which can be subsequently injected and stored in subsurface porous rock formations like depleted gas reservoirs and presently used gas storage sites. In order to investigate the feasibility of the hydrogen storage in the subsurface, the collaborative project H2STORE ("hydrogen to store") was initiated. In the scope of this project, potential reactions between microorganism, fluids and rocks induced by hydrogen injection are studied. For the long-term experiments, fluids of natural gas storage are incubated together with rock cores in the high pressure vessels under 40 bar pressure and 40° C temperature with an atmosphere containing 5.8% He as a tracer gas, 3.9% H2 and 90.3% N2. The reservoir is located at a depth of about 2 000 m, and is characterized by a salinity of 88.9 g l-1 NaCl and a temperature of 80° C and therefore represents an extreme environment for microbial life. First geochemical analyses showed a relatively high TOC content of the fluids (about 120 mg l-1) that were also rich in sodium, potassium, calcium, magnesium and iron. Remarkable amounts of heavy metals like zinc and strontium were also detected. XRD analyses of the reservoir sandstones revealed the major components: quartz, plagioclase, K-feldspar, anhydrite and analcime. The sandstones were intercalated by mudstones, consisting of quartz, plagioclase, K-feldspar, analcime, chlorite, mica and carbonates. Genetic profiling of amplified 16S rRNA genes was applied to characterize the microbial community composition by PCR-SSCP (PCR-Single-Strand-Conformation Polymorphism) and DGGE (Denaturing Gradient Gel Electrophoresis). First results indicate the presence of microorganisms belonging to the phylotypes alfa-, beta- and gamma

  5. Implications of Sub-Hydrostatic Pressures in the Bravo Dome Natural CO2 Reservoir for the Long-Term Security of Geological Carbon Dioxide Storage

    Science.gov (United States)

    Akhbari, D.; Hesse, M. A.; Larson, T.

    2014-12-01

    The Bravo Dome field in northeast New Mexico is one of the largest gas accumulations worldwide and the largest natural CO2 accumulation in North America. The field is only 580-900 m deep and located in the Permian Tubb sandstone that unconformably overlies the granitic basement. Sathaye et al. (2014) estimated that 1.3 Gt of CO2 is stored at the reservoir. A major increase in the pore pressure relative to the hydrostatic pressure is expected due to the large amount of CO2 injected into the reservoir. However, the pre-production gas pressures indicate that most parts of the reservoir are approximately 5 MPa below hydrostatic pressure. Three processes could explain the under pressure in the Bravo Dome reservoir; 1) erosional unloading, 2) CO2 dissolution into the ambient brine, 3) cooling of CO2after injection. Analytical solutions suggest that an erosion rate of 180 m/Ma is required to reduce the pore pressures to the values observed at Bravo Dome. Given that the current erosion rate is only 5 m/Ma (Nereson et al. 2013); the sub-hydrostatic pressures at Bravo Dome are likely due to CO2dissolution and cooling. To investigate the impact of CO2 dissolution on the pore pressure we have developed new analytical solutions and conducted laboratory experiments. We assume that gaseous CO2 was confined to sandstones during emplacement due to the high entry pressure of the siltstones. After emplacement the CO2 dissolves in to the brine contained in the siltstones and the pressure in the sandstones declines. Assuming the sandstone-siltstone system is closed, the pressure decline due to CO2 dissolution is controlled by a single dimensionless number, η = KHRTVw /Vg. Herein, KH is Henry's constant, R is ideal gas constant, T is temperature, Vw is water volume, and Vg is CO2 volume. The pressure drop is controlled by the ratio of water volume to CO2 volume and η varies between 0.1 to 8 at Bravo Dome. This corresponds to pressure drops between 0.8-7.5 MPa and can therefore account

  6. Comparative studies of the antioxidant effects of a naturally occurring resveratrol analogue -- trans-3,3',5,5'-tetrahydroxy-4'-methoxystilbene and resveratrol -- against oxidation and nitration of biomolecules in blood platelets.

    Science.gov (United States)

    Olas, Beata; Wachowicz, Barbara; Nowak, Pawel; Stochmal, Anna; Oleszek, Wieslaw; Glowacki, Rafal; Bald, Edward

    2008-08-01

    The action of two phenolic compounds isolated from the bark of Yucca schidigera: trans-3,3',5,5'-tetrahydroxy-4'-methoxystilbene and its analogue -- resveratrol (trans-3,4',5-trihydroxystilbene, present also in grapes and wine) on oxidative/nitrative stress induced by peroxynitrite (ONOO(-), which is strong physiological oxidant and inflammatory mediator) in human blood platelets was compared. The trans-3,3',5,5'-tetrahydroxy-4'-methoxystilbene, like resveratrol, significantly inhibited protein carbonylation and nitration (measured by enzyme-linked immunosorbent assay method) in the blood platelets treated with peroxynitrite (0.1 mM) and markedly reduced an oxidation of thiol groups of proteins (estimated with 5,5'-dithio-bis(2-nitro-benzoic acid)] or glutathione (measured by high performance liquid chromatography method) in these cells. The trans-3,3',5,5'-tetrahydroxy-4'-methoxystilbene, like resveratrol, also caused a distinct reduction of platelet lipid peroxidation induced by peroxynitrite. The obtained results indicate that in vitro trans-3,3',5,5'-tetrahydroxy-4'-methoxystilbene and resveratrol have very similar protective effects against peroxynitrite-induced oxidative/nitrative damage to the human platelet proteins and lipids. Moreover, trans-3,3',5,5'-tetrahydroxy-4'-methoxystilbene proved to be even more potent than resveratrol in antioxidative tests. We conclude that the novel tested phenolic compound -- trans-3,3',5,5'-tetrahydroxy-4'-methoxystilbene isolated from Y. schidigera bark possessing Generally Recognized As Safe label given by the Food and Drug Administration and allows their human dietary use -- seems to be a promising candidate for future evaluations of its antioxidative activity and may be a good candidate for scavenging peroxynitrite.

  7. GEOCHRONOMETRY & ISOTOPE GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    <正>20081140 Cheng Peng(State Key Laboratory of Loess and Quaternary Geology,Institute of Earth Environment,CAS,Xi’an 710075,China);Zhou Weijian Advances in Radiocarbon Dating Researches in the Loess-Paleosol Sequences(Marine Geology & Quaternary Geology,ISSN0256-1492,CN37-

  8. The geology of Libya

    Energy Technology Data Exchange (ETDEWEB)

    Salem, M.J.; Busrewil, M.T. (eds.)

    1981-01-01

    This book includes 75 of the papers presented at the Second Symposium of Geology of Libya, held in Tripoli in September 1978. The papers are grouped into seven parts: stratigraphy; biostratigraphy and paleontology; sedimentation and petroleum geology; hydrogeology; geomorphology and Quaternary geology; tectonics and geophysics; geochemistry, mineralogy, and ore deposits. Petroleum exploration prompted many of the papers in this volume. (JMT)

  9. OCEANOGRAPHY & MARINE GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2013-01-01

    <正>20132178 Chen Hongjun(Guangzhou Marine Geological Survey,MLR,Guangzhou 510760,China);Cai Guanqiang Features of Canyon Morphology and Their Origin in the Shenhu Area,Northern Slope of the South China Sea(Marine Geology&Quaternary Geology,ISSN0256-1492,CN37-1117/P,32(5),2012,p.19-26

  10. HISTORICAL GEOLOGY & STRATIGRAPHY

    Institute of Scientific and Technical Information of China (English)

    2015-01-01

    20151119Cui Zhengke(No.1 Marine Geological Investigation Party,Shanghai Offshore Petroleum Bureau,SINOPEC,Shanghai201208,China);Yang Wenda Late Quaternary Sequence Stratigraphy and Sedimentary Environment of East China Sea Continental Shelf(Marine Geology&Quaternary; Geology,ISSN0256-1492,CN37-1117/P,34(4),

  11. Geology and Design: Formal and Rational Connections

    Science.gov (United States)

    Eriksson, S. C.; Brewer, J.

    2016-12-01

    Geological forms and the manmade environment have always been inextricably linked. From the time that Upper Paleolithic man created drawings in the Lascaux Caves in the southwest of France, geology has provided a critical and dramatic spoil for human creativity. This inspiration has manifested itself in many different ways, and the history of architecture is rife with examples of geologically derived buildings. During the early 20th Century, German Expressionist art and architecture was heavily influenced by the natural and often translucent quality of minerals. Architects like Bruno Taut drew and built crystalline forms that would go on to inspire the more restrained Bauhaus movement. Even within the context of Contemporary architecture, geology has been a fertile source for inspiration. Architectural practices across the globe leverage the rationality and grounding found in geology to inform a process that is otherwise dominated by computer-driven parametric design. The connection between advanced design technology and the beautifully realized geo natural forms insures that geology will be a relevant source of architectural inspiration well into the 21st century. The sometimes hidden relationship of geology to the various sub-disciplines of Design such as Architecture, Interiors, Landscape Architecture, and Historic Preservation is explored in relation to curriculum and the practice of design. Topics such as materials, form, history, the cultural and physical landscape, natural hazards, and global design enrich and inform curriculum across the college. Commonly, these help define place-based education.

  12. Electromagnetic wave analogue of electronic diode

    CERN Document Server

    Shadrivov, Ilya V; Kivshar, Yuri S; Fedotov, Vassili A; Zheludev, Nikolay I

    2010-01-01

    An electronic diode is a nonlinear semiconductor circuit component that allows conduction of electrical current in one direction only. A component with similar functionality for electromagnetic waves, an electromagnetic isolator, is based on the Faraday effect of the polarization state rotation and is also a key component of optical and microwave systems. Here we demonstrate a chiral electromagnetic diode, which is a direct analogue of an electronic diode: its functionality is underpinned by an extraordinary strong nonlinear wave propagation effect in the same way as electronic diode function is provided by a nonlinear current characteristic of a semiconductor junction. The effect exploited in this new electromagnetic diode is an intensity-dependent polarization change in an artificial chiral metamolecule. This microwave effect exceeds a similar optical effect previously observed in natural crystals by more than 12 orders of magnitude and a direction-dependent transmission that differing by a factor of 65.

  13. Map Service Showing Geology and Geologic Provinces of South Asia

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — The geology data set for this map includes arcs, polygons, and labels that outline and describe the general geologic age and rock type for South Asia. The geologic...

  14. A Short Term Analogue Memory

    DEFF Research Database (Denmark)

    Shah, Peter Jivan

    1992-01-01

    A short term analogue memory is described. It is based on a well-known sample-hold topology in which leakage currents have been minimized partly by circuit design and partly by layout techniques. Measurements on a test chip implemented in a standard 2.4 micron analogue CMOS process show a droop...... rate of 0.075mV per second with a 1pF hold capacitor. This is equivalent to a retention time of approximately 1½ minute with 10 bits accuracy, assuming a full scale of +/-3.5V. It is expected that this can be improved by more than an order of magnitude by improving the layout of the hold capacitor...

  15. Neuronal Analogues of Conditioning Paradigms

    Science.gov (United States)

    1984-04-24

    Although the mechanisms of interneuronal communication have been well established, the changes underlying most forms of learning have thus far eluded...stimulating electrodes on one of the connectives was adjusted so as to produce a small excitatory postsynaptic potential ( EPSP ) in the impaled cell...two stimuli would constitute a neuronal analogue of conditioning by producing an increased EPSP in response to the test stimulus alone. If so, then

  16. Substrate analogues for isoprenoid enzymes

    Energy Technology Data Exchange (ETDEWEB)

    Stremler, K.E.

    1987-01-01

    Diphosphonate analogues of geranyl diphosphate, resistant to degradation by phosphatases, were found to be alternate substrates for the reaction with farnesyl diphosphate synthetase isolated from avian liver. The difluoromethane analogue was shown to be the better alternate substrate, in agreement with solvolysis results which indicate that the electronegativity of the difluoromethylene unit more closely approximates that of the normal bridging oxygen. The usefulness of the C/sub 10/ difluoro analogue, for detecting low levels of isoprenoid enzymes in the presence of high levels of phosphatase activity, was demonstrated with a cell-free preparation from lemon peel. A series of C/sub 5/ through C/sub 15/ homoallylic and allylic diphosphonates, as well as two 5'-nucleotide diphosphonates, was prepared in high overall yield using the activation-displacement sequence. Radiolabeled samples of several of the allylic diphosphonates were prepared with tritium located at C1. A series of geraniols, stereospecifically deuterated at C1, was prepared. The enantiomeric purities and absolute configurations were determined by derivatization as the mandelate esters for analysis by /sup 1/H NMR. The stereochemistry of the activation-displacement sequence was examined using C1-deuterated substrates.

  17. On the Raman Detectability of Biomarkers in Geological Matrices in preparation for Mars Exploration

    Science.gov (United States)

    Malherbe, Cedric; Hutchinson, Ian B.; DEMARET, Lucas; INGLEY, Richard; EDWARDS, Howell G. M.; EPPE, Gauthier; ExoMars Raman Team at the University of Leicester, Group of Inorganic Analytical Chemsitry at the University of Liege

    2016-10-01

    In 2020, Raman spectrometers will be launched to Mars as part of the ESA/ROSCOSMOS's ExoMars 2020 mission and the NASA's Mars 2020 mission. The miniaturized Raman instrument on board the ExoMars rover has two scientific goals: characterize the geochemistry of the surface and subsurface of Mars, and search for molecular evidence of past and present life. Raman spectrometers have indeed the capability to characterize non-destructively the geology of the rocky surface of Mars. Information on the nature and the molecular composition of the surface and subsurface of Mars will provide valuable information about the habitability of the red planet. In addition, Raman spectrometers have the ability to detect potential molecular biomarkers which are substances obtained by biochemical processes or their derivatives preserved in a protective geological niche. In preparation for Mars mission, studying the detection capability of miniaturized Raman spectrometers (specifically developed for space missions and therefore compromised by the associated challenging constraints) is highly important, on both lab synthetic samples and natural terrestrial analogues samples. We present here an analytical strategy to determine the limit of detection achievable based on Raman spectral images. Raman data were recorded with benchtop instruments and a Raman Laser Spectrometer prototype developed at the University of Leicester to optimize/characterize the camera system that will be used for the ExoMars mission.

  18. Methods of analysis by the U.S. Geological Survey National Water Quality Laboratory; arsenic speciation in natural-water samples using laboratory and field methods

    Science.gov (United States)

    Garbarino, John R.; Bednar, Anthony J.; Burkhardt, Mark R.

    2002-01-01

    Analytical methods for the determination of arsenite [As(III)], arsenate [As(V)], dimethylarsinate (DMA), monomethylarsonate (MMA), and roxarsone in filtered natural-water samples are described. Various analytical methods can be used for the determination, depending on the arsenic species being determined. Arsenic concentration is determined by using inductively coupled plasma-mass spectrometry (ICP-MS) as an arsenic-specific detector for all methods. Laboratory-speciation methods are described that use an ion chromatographic column to separate the arsenic species; the column length, column packing, and mobile phase are dependent on the species of interest. Regardless of the separation technique, the arsenic species are introduced into plasma by eithe rpneumatic nebulization or arsine generation. Analysis times range from 2 to 8 minutes and method detection limits range from 0.1 to 0.6 microgram-arsenic per liter (ug-As/L), 10 to 60 picograms absolute (for a 100-microliter injection), depending on the arsenic species determined and the analytical method used. A field-generation specciation method also is described that uses a strong anion exchange cartridge to separate As(III) from As(V) in the field. As(III) in the eluate and the As(V) in the cartridge extract are determined by direct nebulization ICP-MS. Methylated arsenic species that also are retained on the cartridge will positively bias As(V) results without further laboratory separations. The method detection limit for field speciation is 0.3 ug-As/L. The distribution of arsenic species must be preserved in the field to eliminate changes caused by photochemical oxidation or metal oxyhydroxide precipitation. Preservation techniques, such as refrigeration, the addition of acides, or the additoin of ethylene-diaminetetraacetic acid (EDTA) and the effects of ambient light were tested. Of the preservatives evaluated, EDTA was found to work best with the laboratory- and field-speciation methods for all sample

  19. Alligator Rivers Analogue project. Application of scenario development method in evaluation of the Koongarra Analogue. Final Report - Volume 16

    Energy Technology Data Exchange (ETDEWEB)

    Skagius, K. [Kemakta Consultants co., Stockholm (Sweden); Wingefors, S. [Swedish Nuclear Power Inspectorate, Stockholm (Sweden)

    1992-12-31

    The study of natural analogues has been established as one of the most important methods for validation of concepts and models applied for the assessment of long-term performance of repositories for nuclear waste. The objectives of such studies range from detailed investigations of processes and features on a small scale to attempts of explaining the evolution of whole sites. For studies of specific processes it may well be as important to consider the larger scale settings as boundary conditions. This appreciation of context and an integrated view may be as important for evaluation of most natural analogues as for performance assessments. This is more evident the more the evaluation depends on a knowledge about the evolution of the natural analogue. The attempted formulation of scenarios of the Koongarra Analogue has been based on the external conditions and external features. A rapid weathering of the host rock, i.e. the chlorite schist, is assumed to have started around the onset of the Pleistocene Ice Age (ca 1.6 Ma BP). The eventual oxidation and mobilization of the uranium ore could then have occurred under unsaturated or saturated conditions. This leads to the following major scenarios: (1) Uranyl Phosphates formed under unsaturated conditions, with a periodical evolution of the dispersion fan in conjunction with alternating dry (glacial) and wet (interglacial) periods during the Pleistocene Ice Age; (2) Uranyl Phosphates formed under unsaturated conditions as a single event, taking place either early or late during the Pleistocene Ice Age; (3)Uranyl Phosphates formed under saturated conditions, in conjunction with periods of higher and lower flow due to the climatic cycling. Although the original objectives may not have been fully achieved, this work is believed to contribute to a better understanding of the Koongarra Analogue as well as to give a basis for further scenario work

  20. A review of analogue modelling of geodynamic processes: Approaches, scaling, materials and quantification, with an application to subduction experiments

    Science.gov (United States)

    Schellart, Wouter P.; Strak, Vincent

    2016-10-01

    We present a review of the analogue modelling method, which has been used for 200 years, and continues to be used, to investigate geological phenomena and geodynamic processes. We particularly focus on the following four components: (1) the different fundamental modelling approaches that exist in analogue modelling; (2) the scaling theory and scaling of topography; (3) the different materials and rheologies that are used to simulate the complex behaviour of rocks; and (4) a range of recording techniques that are used for qualitative and quantitative analyses and interpretations of analogue models. Furthermore, we apply these four components to laboratory-based subduction models and describe some of the issues at hand with modelling such systems. Over the last 200 years, a wide variety of analogue materials have been used with different rheologies, including viscous materials (e.g. syrups, silicones, water), brittle materials (e.g. granular materials such as sand, microspheres and sugar), plastic materials (e.g. plasticine), visco-plastic materials (e.g. paraffin, waxes, petrolatum) and visco-elasto-plastic materials (e.g. hydrocarbon compounds and gelatins). These materials have been used in many different set-ups to study processes from the microscale, such as porphyroclast rotation, to the mantle scale, such as subduction and mantle convection. Despite the wide variety of modelling materials and great diversity in model set-ups and processes investigated, all laboratory experiments can be classified into one of three different categories based on three fundamental modelling approaches that have been used in analogue modelling: (1) The external approach, (2) the combined (external + internal) approach, and (3) the internal approach. In the external approach and combined approach, energy is added to the experimental system through the external application of a velocity, temperature gradient or a material influx (or a combination thereof), and so the system is open

  1. Alligator rivers analogue project an OECD/NEA international project

    Energy Technology Data Exchange (ETDEWEB)

    Duerden, P.; Airey, P. [ANSTO, Menai (Australia); Pescatore, C. [OECD/NEA Issy-les-Moulineaux (France)

    1994-12-31

    The Koongarra uranium deposit in the Alligator Rivers Region of the Northern Territory of Australia was studied as a natural analogue of the far field behaviour of high level waste repositories following groundwater ingress. A number of mathematical modelling approaches were developed for processes as diverse as groundwater transport, host rock weathering, radionuclide sorption, evolution of the uranium dispersion fan and the distribution of uranium series nuclides between mineral assemblages in weathered host rock. Some of these models are relevant to performance assessment at the level of individual processes and subsystem performance. Through the project, new insights into the application of the natural analogue approach to the assessment of potential waste repository sites were obtained.

  2. Geological testimonies of the Portuguese Empire in the East among the collections of the Museu Nacional de História Natural e da Ciência (Lisbon, Portugal

    Directory of Open Access Journals (Sweden)

    José Manuel Brandão

    2013-08-01

    Full Text Available The Mineralogical and Geological Museum of the Faculty of Sciences in Lisbon preserved until the fire of 1978 samples representing several geological units of Timor, collected willfully by agents of the colonial administration. The study of this unique collection in the mainland museums has helped to shed light on the geology of the most distant overseas Portuguese territory. The results were presented at the International Geological Congress, held in London in 1948. Most of the samples were lost in 1978, saving up however the collections sent by the governor of the province to the author of the study on the geology of Timor, former naturalist of the museum. This paper is based on scientific documentation and revisits the collections in order to contextualize its formation and composition, highlighting its role as landmark of sovereignty and the assertion of colonial science in the Portuguese Empire of the East.

  3. Combinatorial Solid-Phase Synthesis of Balanol Analogues

    DEFF Research Database (Denmark)

    Nielsen, John; Lyngsø, Lars Ole

    1996-01-01

    The natural product balanol has served as a template for the design and synthesis of a combinatorial library using solid-phase chemistry. Using a retrosynthetic analysis, the structural analogues have been assembled from three relatively accessible building blocks. The solid-phase chemistry inclu...... including MSNT-mediated esterification of both support-bound alcohols and carboxylic acids has been implemented successfully. Copyright (C) 1996 Elsevier Science Ltd....

  4. Combinatorial Solid-Phase Synthesis of Balanol Analogues

    DEFF Research Database (Denmark)

    Nielsen, John; Lyngsø, Lars Ole

    1996-01-01

    The natural product balanol has served as a template for the design and synthesis of a combinatorial library using solid-phase chemistry. Using a retrosynthetic analysis, the structural analogues have been assembled from three relatively accessible building blocks. The solid-phase chemistry inclu...... including MSNT-mediated esterification of both support-bound alcohols and carboxylic acids has been implemented successfully. Copyright (C) 1996 Elsevier Science Ltd....

  5. Do film soundtracks contain nonlinear analogues to influence emotion?

    OpenAIRE

    Daniel T. Blumstein; Davitian, Richard; Kaye, Peter D.

    2010-01-01

    A variety of vertebrates produce nonlinear vocalizations when they are under duress. By their very nature, vocalizations containing nonlinearities may sound harsh and are somewhat unpredictable; observations that are consistent with them being particularly evocative to those hearing them. We tested the hypothesis that humans capitalize on this seemingly widespread vertebrate response by creating nonlinear analogues in film soundtracks to evoke particular emotions. We used lists of highly rega...

  6. Flat-ramp vs. convex-concave thrust geometries in a deformable hanging wall: new insights from analogue modeling experiments

    Science.gov (United States)

    Almeida, Pedro; Tomas, Ricardo; Rosas, Filipe; Duarte, Joao; Terrinha, Pedro

    2015-04-01

    Different modes of strain accommodation affecting a deformable hanging-wall in a flat-ramp-flat thrust system were previously addressed through several (sandbox) analog modeling studies, focusing on the influence of different variables, such as: a) thrust ramp dip angle and friction (Bonini et al, 2000); b) prescribed thickness of the hanging-wall (Koy and Maillot, 2007); and c) sin-thrust erosion (compensating for topographic thrust edification, e.g. Persson and Sokoutis, 2002). In the present work we reproduce the same experimental procedure to investigate the influence of two different parameters on hanging-wall deformation: 1) the geometry of the thrusting surface; and 2) the absence of a velocity discontinuity (VD) that is always present in previous similar analogue modeling studies. Considering the first variable we use two end member ramp geometries, flat-ramp-flat and convex-concave, to understand the control exerted by the abrupt ramp edges in the hanging-wall stress-strain distribution, comparing the obtain results with the situation in which such edge singularities are absent (convex-concave thrust ramp). Considering the second investigated parameter, our motivation was the recognition that the VD found in the different analogue modeling settings simply does not exist in nature, despite the fact that it has a major influence on strain accommodation in the deformable hanging-wall. We thus eliminate such apparatus artifact from our models and compare the obtained results with the previous ones. Our preliminary results suggest that both investigated variables play a non-negligible role on the structural style characterizing the hanging-wall deformation of convergent tectonic settings were such thrust-ramp systems were recognized. Acknowledgments This work was sponsored by the Fundação para a Ciência e a Tecnologia (FCT) through project MODELINK EXPL/GEO-GEO/0714/2013. Pedro Almeida wants to thank to FCT for the Ph.D. grant (SFRH/BD/52556/2014) under the

  7. Synthesis of a Functionalized Benzofuran as a Synthon for Salvianolic Acid C Analogues as Potential LDL Antioxidants

    Directory of Open Access Journals (Sweden)

    Gabriela López-Frías

    2015-05-01

    Full Text Available A palladium mediated synthesis of a common synthon for the syntheses of antioxidant analogues of naturally occurring salvianolic acids is presented. The synthetic route may be used to obtain analogues with a balanced lipophilicity/hydrophilicity which may result in potentially interesting LDL antioxidants for the prevention of cardiovascular diseases.

  8. Synthesis of a Functionalized Benzofuran as a Synthon for Salvianolic Acid C Analogues as Potential LDL Antioxidants.

    Science.gov (United States)

    López-Frías, Gabriela; Camacho-Dávila, Alejandro A; Chávez-Flores, David; Zaragoza-Galán, Gerardo; Ramos-Sánchez, Víctor H

    2015-05-14

    A palladium mediated synthesis of a common synthon for the syntheses of antioxidant analogues of naturally occurring salvianolic acids is presented. The synthetic route may be used to obtain analogues with a balanced lipophilicity/hydrophilicity which may result in potentially interesting LDL antioxidants for the prevention of cardiovascular diseases.

  9. Synthesis and bioactivity of analogues of the marine antibiotic tropodithietic acid

    Directory of Open Access Journals (Sweden)

    Patrick Rabe

    2014-08-01

    Full Text Available Tropodithietic acid (TDA is a structurally unique sulfur-containing antibiotic from the Roseobacter clade bacterium Phaeobacter inhibens DSM 17395 and a few other related species. We have synthesised several structural analogues of TDA and used them in bioactivity tests against Staphylococcus aureus and Vibrio anguillarum for a structure–activity relationship (SAR study, revealing that the sulfur-free analogue of TDA, tropone-2-carboxylic acid, has an antibiotic activity that is even stronger than the bioactivity of the natural product. The synthesis of this compound and of several analogues is presented and the bioactivity of the synthetic compounds is discussed.

  10. Synthesis and bioactivity of analogues of the marine antibiotic tropodithietic acid

    DEFF Research Database (Denmark)

    Rabe, Patrick; Klapschinski, Tim A.; Brock, Nelson L.

    2014-01-01

    aureus and Vibrio anguillarum for a structure-activity relationship (SAR) study, revealing that the sulfur-free analogue of TDA, tropone-2-carboxylic acid, has an antibiotic activity that is even stronger than the bioactivity of the natural product. The synthesis of this compound and of several analogues......Tropodithietic acid (TDA) is a structurally unique sulfur-containing antibiotic from the Roseobacter clade bacterium Phaeobacter inhibens DSM 17395 and a few other related species. We have synthesised several structural analogues of TDA and used them in bioactivity tests against Staphylococcus...

  11. Synthesis and bioactivity of analogues of the marine antibiotic tropodithietic acid.

    Science.gov (United States)

    Rabe, Patrick; Klapschinski, Tim A; Brock, Nelson L; Citron, Christian A; D'Alvise, Paul; Gram, Lone; Dickschat, Jeroen S

    2014-01-01

    Tropodithietic acid (TDA) is a structurally unique sulfur-containing antibiotic from the Roseobacter clade bacterium Phaeobacter inhibens DSM 17395 and a few other related species. We have synthesised several structural analogues of TDA and used them in bioactivity tests against Staphylococcus aureus and Vibrio anguillarum for a structure-activity relationship (SAR) study, revealing that the sulfur-free analogue of TDA, tropone-2-carboxylic acid, has an antibiotic activity that is even stronger than the bioactivity of the natural product. The synthesis of this compound and of several analogues is presented and the bioactivity of the synthetic compounds is discussed.

  12. HISTORICAL GEOLOGY & STRATIGRAPHY

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    <正>20072053 Bao Qingzhon(Shenyang Institute of Geology and Mineral Resources,China Geological Survey,Shenyang,Liaoning 110032,China);Zhang Changjie Carboniferous-Permian Marine Lithostratigraphy and Sequence Stratigraphy in Xi Ujimqin Qi,Southeastern Inner Mongolia,China(Geological Bulletin of China,ISSN1671-2552,CN11-4648/P,25(5),2006,p.572-579,4 illus.,2 tables,26 refs.,with English abstract)

  13. HISTORICAL GEOLOGY & STRATIGRAPHY

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    <正>20082513 Chen Guocheng(State Key Labo- ratory of Marine Geology,Tongji University, Shanghai 200092,China);Zheng Hongbo Sedimentary Records of Volcanic Activities in the South China Sea over the Past 480 ka (Marine Geology & Quaternary Geology, ISSN0256—1492,CN37—1117/P,27(4), 2007,p.69—76,4 illus.,1 table,25 refs., with English abstract) Key words:sedimentary sequence,South China Sea

  14. Hong Kong Geological Survey

    Institute of Scientific and Technical Information of China (English)

    R J Sewell

    2007-01-01

    @@ History and objectives The Hong Kong Geological Survey(HKGS) was created on 5 May,1982,wimin the then Engineering Development Department of the Hong Kong Govemment.The initial objective was to carry out a new geological survey of the Territory at 1∶20,000 scale.This followed recognition of an urgent need to produce high quality geological maps at a large scale with sufficient detail to facilitate physical planning and land use management of Hong Kong.

  15. HISTORICAL GEOLOGY & STRATIGRAPHY

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    <正>20081118 Bai Long(Guizhou Academy of Geology Surveying,Guiyang 550005,Guizhou,China);Shi Yuanhua Discovery of Permian Strata and Its Significance in the Mayidang Area,Yiwu County,Xinjiang(Guizhou Geology,ISSN1000-5943,CN52-1059/P,24(2),2007,p.134-137,141,3 illus.,9 refs.)Key words:Upper Permian,XinjiangIn the survey of regional geology and minera

  16. GEOLOGI KAMPUS TEMBALANG

    Directory of Open Access Journals (Sweden)

    Wahju Krisna H

    2012-02-01

    Full Text Available Geological conditions at Tembalang areas and surround, Semarang, as a Undulating – Hillockymorphological. That’s can be representation lithological and structural conditions. This surveysused the Geoelectrical sounding and combined with geological surface mapping. There are 15points sounding of Geoelectrical, after interpreted with geological surface mapping, can beconclusion the Breccias lithologic overlay on the upper of Limestones lithologic and finding thereverse fault in the part north of areas survey.

  17. HYDROGEOLOGY & ENGINEERING GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2009-01-01

    <正>20091306 Dong Hengbi(Geological Survey of Shaanxi Province,Xi’an 710054,China);Hu Xuesheng Geological Setting of Geotechnical Erosion in the Helong Portion at the Middle Reaches of Yellow River(Geology of Shaanxi,ISSN1001-6996,CN61-1150/ P,26(1),2008,p.69-75,4 refs.,with English abstract) Key words:soil erosion,Yellow River

  18. A graphical approach to analogue behavioural modelling

    OpenAIRE

    Moser, Vincent; Nussbaum, Pascal; Amann, Hans-Peter; Astier, Luc; Pellandini, Fausto

    2007-01-01

    In order to master the growing complexity of analogue electronic systems, modelling and simulation of analogue hardware at various levels is absolutely necessary. This paper presents an original modelling method based on the graphical description of analogue electronic functional blocks. This method is intended to be automated and integrated into a design framework: specialists create behavioural models of existing functional blocks, that can then be used through high-level selection and spec...

  19. Alaska geology revealed

    Science.gov (United States)

    Wilson, Frederic H.; Labay, Keith A.

    2016-11-09

    This map shows the generalized geology of Alaska, which helps us to understand where potential mineral deposits and energy resources might be found, define ecosystems, and ultimately, teach us about the earth history of the State. Rock units are grouped in very broad categories on the basis of age and general rock type. A much more detailed and fully referenced presentation of the geology of Alaska is available in the Geologic Map of Alaska (http://dx.doi.org/10.3133/sim3340). This product represents the simplification of thousands of individual rock units into just 39 broad groups. Even with this generalization, the sheer complexity of Alaskan geology remains evident.

  20. Natural weathering of archaeo-metallurgical slags: an analog for present day vitrified wastesL'altération naturelle des scories de la métallurgie ancienne : un analogue de déchets vitrifiés

    Science.gov (United States)

    Mahé-Le Carlier, Cécile; Le Carlier de Veslud, Christian; Ploquin, Alain; Royer, Jean-Jacques

    2000-02-01

    The study of the natural alteration of ancient vitreous slags (100 to 4 000 years) suggests a single global mechanism. In a first stage, weathering consists of a selective extraction of the modifier cations of glass (including Pb and Ba). This phenomenon is associated with an increase of the solution pH, inducing the glass dissolution. The elements with a weak limit of solubility remain in place and can form hydroxides (Al, Fe). Pb and Ba are extracted from weathered glass. Pb is located in Fe-hydroxides, Ba may form sulfides. The rate of alteration varies from 20 to 180 μm per 1 000 years.

  1. Towards a Convention on Geological Heritage (CGH) for the protection of Geological Heritage

    Science.gov (United States)

    Brocx, Margaret; Semeniuk, Vic

    2017-04-01

    2 V & C Semeniuk Research Group; 21 Glenmere Rd., Warwick, WA, 6024 The history of the biological conservation essentially began with the IUCN and the global awakening following publication of "The Silent Spring". Since then the IUCN has been active in species conservation and later, when recognising the importance of biodiversity, in the development of a Convention on Biological Diversity. However, even in a framework of Convention on Biological Diversity, there are organisations, political systems/parties, and personnel that strive to subjugate and control nature and biology and use nature for profit or to benefit humankind (e.g., genetically modified foods, use of terrain for food production, use of forests as a resource, managed ecosystems, construction of luxury resorts and tourist resorts in wildernesses). This has been the same for geology, in that geological materials are fundamental to industrialisation in the use of metals, building materials, other commodities, and fossil fuels, and have been exploited often regardless of their geoheritage values. The history of geology and its conservation actually predates the focus on conservation of biology - Siccar Point, numerous palaeontologic sites, and other iconic geological sites serve as examples. But in spite of their recognition as iconic geological sites, areas such as Siccar Point, Cliefden Caves, Hallett Cove, and the Kimberley are still under threat. Given that firstly there is an importance to geological features of the Earth per se and, secondly, geological features as geodiversity underpin and sustain biological systems, there is a critical need to develop a convention, similar to the Convention on Biological Diversity, that recognises the importance of geology as a part of Nature. The scope of Geoheritage and the diversity of Geology is such that it involves all sub-disciplines of Geology (e.g., palaeontology, mineralogy, igneous, sedimentary, and metamorphic geology, structural geology, hydrology

  2. What Can We Learn From Analogue Experiments?

    CERN Document Server

    Thebault, Karim P Y

    2016-01-01

    In 1981 Unruh proposed that fluid mechanical experiments could be used to probe key aspects of the quantum phenomenology of black holes. In particular, he claimed that an analogue to Hawking radiation could be created within a fluid mechanical `dumb hole', with the event horizon replaced by a sonic horizon. Since then an entire sub-field of `analogue gravity' has been created. In 2016 Steinhauer reported the experimental observation of quantum Hawking radiation and its entanglement in a Bose-Einstein condensate analogue black hole. What can we learn from such analogue experiments? In particular, in what sense can they provide evidence of novel phenomena such as black hole Hawking radiation?

  3. Contributions of vitreous natural analogs to the investigation of long-term nuclear glass behavior; Apports des analogues naturels vitreux a la validation des codes de prediction du comportement a long terme des verres nucleaires

    Energy Technology Data Exchange (ETDEWEB)

    Techer, I

    1999-07-01

    This study assesses the extend of the analogy between the alteration behavior in water and in a moist clay environment of aluminosilicate volcanic glass and alumino-borosilicate nuclear containment glass. Basaltic glass alteration in water initially occurs by hydrolysis processes with an activation energy on the order of 73 kJ.mol{sup -1}. As the reaction progresses, the alteration rate drops by over four orders of magnitude from the initial rate r{sub 0}, The alteration kinetics are not governed by the alteration solution chemistry alone, the glass alteration film appears to have a major role as a diffusion barrier limiting the transfer of reaction species and products. All these aspects highlight the behavioral analogy between basaltic glass and nuclear borosilicate glass in aqueous media. Conversely, the alteration reaction of obsidian-type volcanic glass involves other mechanisms than those governing the dissolution of borosilicate glass. Basaltic glass alteration is also examined in the presence of a clay environmental material, in a study of the natural basaltic glass and argillaceous pelites system of the Salagou basin in southern France, in an approach combining mineralogical, chemical and isotopic data to assess the interactions between a basaltic glass and the argillaceous pelites. Laboratory leach test results with basaltic glass and measured data for the Salagou glass in its natural environment are modeled using a code implementing a kinetic law coupling diffusive transfer of dissolved silica with a reaction affinity law. (author)

  4. Mass spectrometry and photoelectron spectroscopy of tetracene cluster anions, (tetracene)n- (n = 1-100): evidence for the highly localized nature of polarization in a cluster analogue of oligoacene crystals.

    Science.gov (United States)

    Mitsui, Masaaki; Ando, Naoto; Nakajima, Atsushi

    2007-10-04

    Photoelectron spectroscopy of tetracene cluster anions, (tetracene)n- (n = 1-100), reveals the coexistence of two types of isomers, designated as isomers I and II-1 (n = 10-50) or isomers I and II-2 (n > 60), in a wide size range. The vertical detachment energies (VDEs) of isomer I increase persistently due to polarization and structural relaxation effects, where a monomeric anion core is encompassed with geometrically reorganized neutral molecules. Conversely, a characteristic ion distribution in the mass spectrum of (tetracene)n-ensues from the two-dimensional (2D) herringbone-type ordering of isomer II-1, whose VDEs remain constant at 1.80 eV for n >/= 14. Also, isomer II-2, presumably adopting multilayered structural motifs, exhibits invariable VDEs of 2.0 eV, a manifestation of significant charge screening effects in these isomers. The invariable nature of the VDEs of isomers II-1 and II-2 unambiguously demonstrates a largely localized nature of polarization induced by the excess charge residing in microscopic crystal-like environments. Surprisingly, only 14 tetracene molecules within a 2D herringbone-type layer including an excess charge can provide the charge stabilization energy corresponding to approximately 80% of that of the crystal, and the rest of the energy is provided by polarization of neutral molecules in adjacent layers.

  5. OneGeology-Europe - The Challenges and progress of implementing a basic geological infrastructure for Europe

    Science.gov (United States)

    Asch, Kristine; Tellez-Arenas, Agnes

    2010-05-01

    OneGeology-Europe is making geological spatial data held by the geological surveys of Europe more easily discoverable and accessible via the internet. This will provide a fundamental scientific layer to the European Plate Observation System Rich geological data assets exist in the geological survey of each individual EC Member State, but they are difficult to discover and are not interoperable. For those outside the geological surveys they are not easy to obtain, to understand or to use. Geological spatial data is essential to the prediction and mitigation of landslides, subsidence, earthquakes, flooding and pollution. These issues are global in nature and their profile has also been raised by the OneGeology global initiative for the International Year of Planet Earth 2008. Geology is also a key dataset in the EC INSPIRE Directive, where it is also fundamental to the themes of natural risk zones, energy and mineral resources. The OneGeology-Europe project is delivering a web-accessible, interoperable geological spatial dataset for the whole of Europe at the 1:1 million scale based on existing data held by the European geological surveys. Proof of concept will be applied to key areas at a higher resolution and some geological surveys will deliver their data at high resolution. An important role is developing a European specification for basic geological map data and making significant progress towards harmonising the dataset (an essential first step to addressing harmonisation at higher data resolutions). It is accelerating the development and deployment of a nascent international interchange standard for geological data - GeoSciML, which will enable the sharing and exchange of the data within and beyond the geological community within Europe and globally. The geological dataset for the whole of Europe is not a centralized database but a distributed system. Each geological survey implements and hosts an interoperable web service, delivering their national harmonized

  6. Insulin, insulin analogues and diabetic retinopathy.

    Science.gov (United States)

    Chantelau, Ernst; Kimmerle, Renate; Meyer-Schwickerath, Rolf

    2008-02-01

    Insulin is absolutely vital for living beings. It is not only involved in metabolism, but also in the regulation of growth factors, e.g. IGF-1. In this review we address the role insulin has in the natural evolution of diabetic retinopathy. On the one hand, chronic deficiency of insulin and IGF-1 at the retina is thought to cause capillary degeneration, with subsequent ischaemia. On the other hand, acute abundance of (exogenously administered) insulin and IGF-1 enhances ischaemia-induced VEGF expression. A critical ratio of tissue VEGF-susceptibility: VEGF-availability triggers vascular proliferation (i.e. of micro-aneurysms and/or abnormal vessels). The patent-protected insulin analogues Lispro, Glulisine, Aspart, Glargine and Detemir are artificial insulin derivatives with altered biological responses compared to natural insulin (e.g. divergent insulin and /or IGF-1 receptor-binding characteristics, signalling patterns, and mitogenicity). Their safety profiles concerning diabetic retinopathy remain to be established by randomised controlled trials. Anecdotal reports and circumstantial evidence suggest that Lispro and Glargine might worsen diabetic retinopathy.

  7. Geology's Impact on Culture

    Science.gov (United States)

    Pizzorusso, Ann

    2017-04-01

    Most people consider geology boring, static and difficult. The fields of astronomy and physics have "rebranded" themselves with exciting programs formatted so as to be readily understandable to the general public. The same thing can be done for geology. My research on geology's influence on other disciplines has resulted in a book, Tweeting da Vinci, in which I was able to show how geology affected Italy's art, architecture, medicine, religion, literature, engineering and just about everything else. The reaction to the book and my lectures by both students and the general public has been very positive, including four gold medals, with reviews and comments indicating that they never knew geology could be so exciting. The book is very user friendly, packed with facts, full-color photos, paintings, sketches and illustrations. Complex aspects of geology are presented in an easily understandable style. Widely diverse topics—such as gemology, folk remedies, grottoes, painting, literature, physics and religion—are stitched together using geology as a thread. Quoting everyone from Pliny the Elder to NASA physicist Friedemann Freund, the work is solidly backed scholarship that reads as easily as a summer novel. The book can be used in classes such as physics, chemistry, literature, art history, medicine, Classical Studies, Latin, Greek and Italian. By incorporating a "geologic perspective" in these courses, it can be perceived as a more "all encompassing" discipline and encourage more students to study it. The lectures I have given on college campuses have resulted in students seeing their own majors from a different perspective and some have even signed up for introductory geology courses. One college organized summer course to the Bay of Naples based on the book. We followed the geology as well as the culture of the area and the students were profoundly moved. To encourage dialog, the book is linked to Facebook, Twitter and Instagram. This has enabled followers from

  8. Numerical Simulation of the Depressurization Process of a Natural Gas Hydrate Reservoir: An Attempt at Optimization of Field Operational Factors with Multiple Wells in a Real 3D Geological Model

    Directory of Open Access Journals (Sweden)

    Zhixue Sun

    2016-09-01

    Full Text Available Natural gas hydrates, crystalline solids whose gas molecules are so compressed that they are denser than a typical fluid hydrocarbon, have extensive applications in the areas of climate change and the energy crisis. The hydrate deposit located in the Shenhu Area on the continental slope of the South China Sea is regarded as the most promising target for gas hydrate exploration in China. Samples taken at drilling site SH2 have indicated a high abundance of methane hydrate reserves in clay sediments. In the last few decades, with its relatively low energy cost, the depressurization gas recovery method has been generally regarded as technically feasible and the most promising one. For the purpose of a better acquaintance with the feasible field operational factors and processes which control the production behavior of a real 3D geological CH4-hydrate deposit, it is urgent to figure out the effects of the parameters such as well type, well spacing, bottom hole pressure, and perforation intervals on methane recovery. One years’ numerical simulation results show that under the condition of 3000 kPa constant bottom hole pressure, 1000 m well spacing, perforation in higher intervals and with one horizontal well, the daily peak gas rate can reach 4325.02 m3 and the cumulative gas volume is 1.291 × 106 m3. What’s more, some new knowledge and its explanation of the curve tendency and evolution for the production process are provided. Technically, one factor at a time design (OFAT and an orthogonal design were used in the simulation to investigate which factors dominate the productivity ability and which is the most sensitive one. The results indicated that the order of effects of the factors on gas yield was perforation interval > bottom hole pressure > well spacing.

  9. Geological Heritage and Geoscience education in Ukraine

    Directory of Open Access Journals (Sweden)

    Manyuk V.V.

    2015-09-01

    Full Text Available Ukraine has a long history of campaigning for the preservation of not only the biological but alsothe geological component of the natural environment. The first society for the protection of naturein the history of the Russian Empire was created in Ukraine in 1910. The aim of the society was to protect both the animal and the mineral kingdoms of the natural environment. Since 1992Ukrainian geologists have been taking part in the meetings of the European working group (EWGFSC-the future ProGEO, and since 2000 have been members of the Central European Group of ProGEO. One of the symposiums ProGEO 2006 year took place in Ukraine and it was no accident that this allowed us to develop and include in the curriculum of students of geological specialities of Dnipropetrovsk National University a new course: «The Study and Preservation of Natural Geological Monuments (Geosites», which has been taught from 2012. The training course includes the history of the origin and development of the movement for the conservation of the geological heritage, examples of geoconservation in Europe and the world, the legal framework regarding the Nature Reserve Fund of Ukraine as a whole and its geological component in particular, methodological principles of generating a network of geosites in Ukraine, the criteria for the selection of geosites at local, national, European and international levels, and more.

  10. Geology, Bedrock, Tabular data involving the location of design specifics for wells related to the Low-level Radioactive Waste (LLRW) Site Characterization., Published in 1998, North Carolina Department of Environment and Natural Resources (DENR).

    Data.gov (United States)

    NSGIC State | GIS Inventory — Geology, Bedrock dataset current as of 1998. Tabular data involving the location of design specifics for wells related to the Low-level Radioactive Waste (LLRW) Site...

  11. Geology and geological engineering at Syncrude

    Energy Technology Data Exchange (ETDEWEB)

    O' Donnell, N.

    1988-01-01

    This paper outlines the geology of the Athabasca oil sand deposit and describes the activities of the Mine Geology Section of Syncrude Canada, which operates an oil sand mine in that deposit. The Section serves the mine by providing information in support of a variety of operating functions. It is composed of five specialized teams, each one concerned with accurate, detailed data of practical value. Recognition of the unique geological and geotechnical characteristics of each portion of the base mine is reflected in the approach to the work. The Highwall Mapping and Geological Interpretation Team supports three mine planning groups, geotechnical engineering and dragline operations. Ore grading supplies reserve quality and quantity data to planners and to extraction technical staff covering terms ranging from daily to 25 years. The Overburden and Granular Resources Team provides overburden engineering with the information needed for planning of stripping operations, and ensure valuable sand and gravel reserves are identified for mine haul roads and other construction needs. The Hydrogeology and Groundwater Team supports the depressurization operation and environmental monitoring of tailings operations in conjunction with Environmental Affairs. The Drill Programs Team collects data which the other four teams utilize in the course of carrying out their responsibilities. 30 refs., 14 figs.

  12. GEOCHRONOMETRY & ISOTOPE GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2014-01-01

    <正>20141014Wang Hairan(State Key Laboratory of Continental Dynamics,Department of Geology,Northwest University,Xi’an710069,China);Zhao Hongge Theory and Application of Zircon U-Pb Isotope Dating Technique(Geology and Resources,ISSN1671-1947,CN21-1458/P,22(3),2013,p.229

  13. OCEANOGRAPHY & MARINE GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2015-01-01

    20150652 Jiang Yuxuan(Key Laboratory of Marine Chemistry Theory and Technology,Ministry of Education,Ocean University of China,Qingdao 266100,China);Xing Lei Study on the Degradation of Marine Sedimentary Organic Matter and Model Development(Marine Geology&Quaternary; Geology,ISSN0256-1492,CN37-1117/P,34(4),

  14. HISTORICAL GEOLOGY & STRATIGRAPHY

    Institute of Scientific and Technical Information of China (English)

    2015-01-01

    20152571 Bai Ping(Guizhou Academy of Geologic Survey,Guiyang 550005,China);Xiao Jiafei Sequence Stratigraphy and Sedimentary Environment of Early Cambrian in ZunyiDafang Area of Northwest Guizhou Province(Guizhou Geology,ISSN1000-5943,CN52-1059/P,31(4),2014,p.291-296,272,3

  15. HISTORICAL GEOLOGY & STRATIGRAPHY

    Institute of Scientific and Technical Information of China (English)

    2004-01-01

    <正>20040593 A Chengye (Qinghao Institute of Geological Survey, Xinjing, Qinghai); Wang Yizhi Disintegration of the Wanbaogou Group and Discovery of Early Cambrian Strata in the Eastern Kunlun Area, Xinjiang, China (Geology in China, ISSN 1000 -3657, CN11-1167/P, 30(2), 2003, p. 199 - 206, 6 illus. , 2 tables, 15 refs. , with English abstract)

  16. HISTORICAL GEOLOGY & STRATIGRAPHY

    Institute of Scientific and Technical Information of China (English)

    2009-01-01

    <正>20091185 Duan Jianxiang(Institute of Geologic Survey of Jilin Province,Changchun 130061,China);Liu Jingbo Characteristics of Yaojia Formation Petrostratigraphy and Sedimentary Environment in the Songnen Basin in the Fuyu,Yushu Areas(Jilin Geology, ISSN1001-2427,CN22-1099/P,27

  17. OCEANOGRAPHY & MARINE GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2011-01-01

    <正>20112116 Gao Changlin (Wuxi Research Institute of Petroleum Geology,SINOPEC,- , Wuxi 214151,China);Huang Zeguang On Study of Paleo-Oceanology in Orogenic Belts (Petroleum Geology & Experiment, ISSN1001-6112,CN32-1151/TE,32(5), 2010,p.409-414,419,3illus.,1table,34 refs.)

  18. Microbial morphologies in cold fluid-generated geologic bodies

    Science.gov (United States)

    Barbieri, R.; Cavalazzi, B.

    Chemosynthetic-generated (non-hydrothermal) geological bodies abound on Earth since at least the Paleozoic and mostly derive from hydrocarbon gases such as methane, which is the main component of gas hydrates. Because of the abundance of hydrocarbons in the Solar System, it is likely that methane degassing, perhaps stored as hydrate, can occur in other planetary bodies apart from Earth. Similarly to what is described on Earth, where present and past chemoautotrophically-based communities belong to peculiar "island" ecosystems associated with methane or sulfide-rich fluids source, other planetary bodies (especially Mars) may have harbored extinct biota in such environments. This assumption is based on the independence of modern chemosynthetic biota from Earth-like ambient conditions, such as free oxygen and light, as well as the presence of microbial communities that are only sustained by the products of cold seepage. In cold seep-derived carbonate bodies from Morocco and Italy we have described microbial structures from different geologic age and environmental settings. Three-dimensional stromatolite structures, mineralized into iron oxides (hematite), are extensively recovered in recrystallized authigenic carbonates of Silurian age (Morocco), and are attributed to Beggiatoa-like colonies similar to those that abound in present-day areas with active hydrocarbon seepage. Well-preserved microbial structures in form of mucilage and three-dimensional webs have also been isolated from upper Tertiary, methane-derived carbonates (Italy). These structures are contained in cement phases that form irregular calcite layers partially filling voids and pre-existing gas conduits. They are interpreted as derived from anaerobic bacterial oxidation of methane, and a further evidence of anaerobic conditions is the abundance of pyrite of a probable bacterial sulfate-reduction derivation. Microbial morphologies of different nature can therefore be preserved and detected in mineral

  19. Field Geology/Processes

    Science.gov (United States)

    Allen, Carlton; Jakes, Petr; Jaumann, Ralf; Marshall, John; Moses, Stewart; Ryder, Graham; Saunders, Stephen; Singer, Robert

    1996-01-01

    The field geology/process group examined the basic operations of a terrestrial field geologist and the manner in which these operations could be transferred to a planetary lander. Four basic requirements for robotic field geology were determined: geologic content; surface vision; mobility; and manipulation. Geologic content requires a combination of orbital and descent imaging. Surface vision requirements include range, resolution, stereo, and multispectral imaging. The minimum mobility for useful field geology depends on the scale of orbital imagery. Manipulation requirements include exposing unweathered surfaces, screening samples, and bringing samples in contact with analytical instruments. To support these requirements, several advanced capabilities for future development are recommended. Capabilities include near-infrared reflectance spectroscopy, hyper-spectral imaging, multispectral microscopy, artificial intelligence in support of imaging, x ray diffraction, x ray fluorescence, and rock chipping.

  20. Quantitative strain analysis in analogue modelling experiments: insights from X-ray computed tomography and tomographic image correlation

    Science.gov (United States)

    Adam, J.; Klinkmueller, M.; Schreurs, G.; Wieneke, B.

    2009-04-01

    The combination of scaled analogue modelling experiments, advanced research in analogue material mechanics (Lohrmann et al. 2003, Panien et al. 2006), X-ray computed tomography and new high-resolution deformation monitoring techniques (2D/3D Digital Image Correlation) is a new powerful tool not only to examine the evolution and interaction of faulting in analogue models, but also to evaluate relevant controlling factors such as mechanics, sedimentation, erosion and climate. This is of particular interest for applied problems in the energy sector (e.g., structurally complex reservoirs, LG & CO2 underground storage) because the results are essential for geological and seismic interpretation as well as for more realistically constrained fault/fracture simulations and reservoir characterisation. X-ray computed tomography (CT) analysis has been successfully applied to analogue models since the late 1980s. This technique permits visualisation of the interior of an analogue model without destroying it. Technological improvements have resulted in more powerful X-ray CT scanners that allow periodic acquisition of volumetric data sets thus making it possible to follow the 3-D evolution of the model structures with time (e.g. Schreurs et al., 2002, 2003). Optical strain monitoring (Digital Image Correlation, DIC) in analogue experiments (Adam et al., 2005) represents an important advance in quantitative physical modelling and in helping to understand non-linear rock deformation processes. Optical non-intrusive 2D/3D strain and surface flow analysis by DIC is a new methodology in physical modelling that enables the complete quantification of localised and distributed model deformation. The increase in spatial/temporal strain data resolution of several orders of magnitude makes physical modelling - used for decades to visualize the kinematic processes of geological deformation processes - a unique research tool to determine what fundamental physical processes control tectonic