Validation of OpenFoam for heavy gas dispersion applications

NARCIS (Netherlands)

Mack, A.; Spruijt, M.P.N.

2013-01-01

In the present paper heavy gas dispersion calculations were performed with OpenFoam. For a windtunnel test case, numerical data was validated with experiments. For a full scale numerical experiment,a code to code comparison was performed with numerical results obtained from Fluent. The validationwas

Gas production potential of disperse low-saturation hydrate accumulations in oceanic sediments

International Nuclear Information System (INIS)

Moridis, George J.; Sloan, E. Dendy

2007-01-01

In this paper, we evaluate the gas production potential of disperse, low-saturation (S H H hydrate-bearing sediments subject to depressurization-induced dissociation over a 10-year production period. We investigate the sensitivity of items (a)-(c) to the following hydraulic properties, reservoir conditions, and operational parameters: intrinsic permeability, porosity, pressure, temperature, hydrate saturation, and constant pressure at which the production well is kept. The results of this study indicate that, despite wide variations in the aforementioned parameters (covering the entire spectrum of such deposits), gas production is very limited, never exceeding a few thousand cubic meters of gas during the 10-year production period. Such low production volumes are orders of magnitude below commonly accepted standards of economic viability, and are further burdened with very unfavorable gas-to-water ratios. The unequivocal conclusion from this study is that disperse, low-S H hydrate accumulations in oceanic sediments are not promising targets for gas production by means of depressurization-induced dissociation, and resources for early hydrate exploitation should be focused elsewhere

Predictive Modelling of Concentration of Dispersed Natural Gas in a Single Room

Directory of Open Access Journals (Sweden)

Abdulfatai JIMOH

2009-07-01

Full Text Available This paper aimed at developing a mathematical model equation to predict the concentration of natural gas in a single room. The model equation was developed by using theoretical method of predictive modelling. The model equation developed is as given in equation 28. The validity of the developed expression was tested through the simulation of experimental results using computer software called MathCAD Professional. Both experimental and simulated results were found to be in close agreement. The statistical analysis carried out through the correlation coefficients for the results of experiment 1, 2, 3 and 4 were found to be 0.9986, 1.0000, 0.9981 and 0.9999 respectively, which imply reasonable close fittings between the experimental and simulated concentrations of dispersed natural gas within the room. Thus, the model equation developed can be considered a good representation of the phenomena that occurred when there is a leakage or accidental release of such gas within the room.

Dispersion of odorants in natural gas distribution networks

Science.gov (United States)

Gross, R.; Fontana, E.; Silva, A.; Quadri, M. B.; Souza, S. M. A. G. U.

2018-03-01

A numerical modeling analysis of a pulse train diffusion, representing an odorant injection in a natural gas pipeline, was carried out and compared with experimental data from a real pipeline. The main purpose of this study is to evaluate how the odorant dispersion occurs along the pipe. Due to technical limitations, the odorant is injected in the line as a pulse and it is important to find out the point in the pipeline where the oscillating concentration of odorant fits into a range of values that meet both the legislation and the interests of customers who may have the quality of their products affected by this oscillation. Since the natural gas pipelines do not have strong streamline curvatures and the flow is always turbulent, it is relatively easy to determine the velocity and concentration fields using the Computational Fluid Dynamics techniques. In this study the RANS (Reynolds Average Navier-Stokes) equations with the k - ɛ turbulence model was used to build the mathematical model. Comparisons of the experimental data and numerical results show a strong agreement for the studied cases. Based on the results, it was possible to know the minimum and maximum values of odorant concentration along the pipelines.

New test for oil soluble/water dispersible gas pipeline inhibitors

Energy Technology Data Exchange (ETDEWEB)

Stegmann, D.W.; Asperger, R.G.

1987-01-01

The wheel test provides good mixing of the condensate and water phases, the coupons are exposed to both phases. Therefore, the wheel test cannot distinguish between inhibitors that need continuous mixing of the these phases to maintain a water dispersion of the inhibitor and inhibitors that will self disperse into the water. This concept becomes important for pipelines in stratified flow where the water can settle out. In these cases with low turbulence, the inhibitor must self disperse into the water to be effective. The paper describes a test method to measure the effectiveness of an inhibitor and its ability to self disperse. The effectiveness of several inhibitors as predicted by the new test method is discussed relative to data from the wheel test and breaker tests. Field performance of these inhibitors in a gas gathering line, with liquids in stratified flow, are cities and compared with the results of the various laboratory tests.

Pion-pair formation and the pion dispersion relation in a hot pion gas

Energy Technology Data Exchange (ETDEWEB)

Chanfay, G. [Lyon-1 Univ., 69 - Villeurbanne (France). Inst. de Physique Nucleaire; Alm, T. [Rostock Univ. (Germany); Schuck, P. [Grenoble-1 Univ., 38 (France). Inst. des Sciences Nucleaires; Welke, G. [Wayne State Univ., Detroit, MI (United States). Dept. of Physics and Astronomy

1996-09-01

The possibility of pion-pair formation in a hot pion gas, based on the bosonic gap equation, is pointed out and discussed in detail. The critical temperature for condensation of pion pairs (Evans-Rashind transition) is determined as a function of the pion density. As for fermions, this phase transition is signaled by the appearance of a pole in the two-particle propagator. In Bose systems there exists a second, lower critical temperature, associated with the appearance of the single-particle condensate. Between the two critical temperatures the pion dispersion relation changes from the usual quasiparticle dispersion to a Bogoliubov-like dispersion relation at low momenta. This generalizes the non-relativistic results for an attractive Bose gas by Evans et al. Possible consequences for the inclusive pion spectra measured in heavy-ion collisions at ultra-relativistic energies are discussed. 21 refs.

The Shoreline Environment Atmospheric Dispersion Experiment (SEADEX): Meteorological and gas tracer data

International Nuclear Information System (INIS)

Johnson, W.B.; Cantrell, B.K.; Morley, B.M.; Uthe, E.E.; Nitz, K.C.

1987-10-01

The SEADEX atmospheric dispersion field study was conducted during the period May 28 to June 8, 1982, in northeastern Wisconsin, the vicinity of the Kewaunee Power Plant on the western shore of Lake Michigan. The specific objectives of SEADEX were to characterize (1) the atmospheric dispersion and (2) the meteorological conditions influencing this dispersion as completely as possible during the test period. This field study included a series of controlled tracer tests utilizing state-of-the-art tracer measurement technology to determine horizontal and vertical dispersion over both land and water. Extensive meteorological measurements were obtained to thoroughly characterize the three-dimensional structure of the atmospheric boundary controlling the dispersion process. This volume presents the meteorological and gas tracer data collected during the field study. 391 figs., 32 tabs

Light-pressure-induced nonlinear dispersion of a laser field interacting with an atomic gas

International Nuclear Information System (INIS)

Grimm, R.; Mlynek, J.

1990-01-01

We report on detailed studies of the effect of resonant light pressure on the optical response of an atomic gas to a single monochromatic laser field. In this very elementary situation of laser spectroscopy, the redistribution of atomic velocities that is induced by spontaneous light pressure leads to a novel contribution to the optical dispersion curve of the medium. This light-pressure-induced dispersion phenomenon displays a pronounced nonlinear dependence on the laser intensity. Moreover, for a given intensity, its strength is closely related to the laser beam diameter. As most important feature, this light-pressure-induced dispersion displays an even symmetry with respect to the optical detuning from line center. As a result, the total Doppler-broadened dispersion curve of the gas can become asymmetric, and a significant shift of the dispersion line center can occur. In addition to a detailed theoretical description of the phenomenon, we report on its experimental investigation on the λ=555.6 nm 1 S 0 - 3 P 1 transition in atomic ytterbium vapor with the use of frequency-modulation spectroscopy. The experimental findings are in good quantitative agreement with theoretical predictions

Generation of multiple VUV dispersive waves using a tapered gas-filled hollow-core anti-resonant fiber

DEFF Research Database (Denmark)

Habib, Md Selim; Markos, Christos; Bang, Ole

2017-01-01

Hollow-core anti-resonant (HC-AR) fibers are perhaps the best platform for ultrafast nonlinear optics based on light-gas interactions because they offer broadband guidance and low-loss guidance. The main advantage of using gases inside HC fibers is that both the dispersion and nonlinearity can...... be tuned by simply changing the pressure of the gas [1]. The emission of efficient dispersive wave (DW) in the deep-UV has been already observed in a uniform Ar-filled hollow-core fiber with tunability from 200 to 320 nm by changing the gas pressure and pulse energy [2]. In the quest of optimizing...

Numerical Simulation of Dispersion from Urban Greenhouse Gas Sources

Science.gov (United States)

Nottrott, Anders; Tan, Sze; He, Yonggang; Winkler, Renato

2017-04-01

Cities are characterized by complex topography, inhomogeneous turbulence, and variable pollutant source distributions. These features create a scale separation between local sources and urban scale emissions estimates known as the Grey-Zone. Modern computational fluid dynamics (CFD) techniques provide a quasi-deterministic, physically based toolset to bridge the scale separation gap between source level dynamics, local measurements, and urban scale emissions inventories. CFD has the capability to represent complex building topography and capture detailed 3D turbulence fields in the urban boundary layer. This presentation discusses the application of OpenFOAM to urban CFD simulations of natural gas leaks in cities. OpenFOAM is an open source software for advanced numerical simulation of engineering and environmental fluid flows. When combined with free or low cost computer aided drawing and GIS, OpenFOAM generates a detailed, 3D representation of urban wind fields. OpenFOAM was applied to model scalar emissions from various components of the natural gas distribution system, to study the impact of urban meteorology on mobile greenhouse gas measurements. The numerical experiments demonstrate that CH4 concentration profiles are highly sensitive to the relative location of emission sources and buildings. Sources separated by distances of 5-10 meters showed significant differences in vertical dispersion of plumes, due to building wake effects. The OpenFOAM flow fields were combined with an inverse, stochastic dispersion model to quantify and visualize the sensitivity of point sensors to upwind sources in various built environments. The Boussinesq approximation was applied to investigate the effects of canopy layer temperature gradients and convection on sensor footprints.

A simple measurement method of molecular relaxation in a gas by reconstructing acoustic velocity dispersion

Science.gov (United States)

Zhu, Ming; Liu, Tingting; Zhang, Xiangqun; Li, Caiyun

2018-01-01

Recently, a decomposition method of acoustic relaxation absorption spectra was used to capture the entire molecular multimode relaxation process of gas. In this method, the acoustic attenuation and phase velocity were measured jointly based on the relaxation absorption spectra. However, fast and accurate measurements of the acoustic attenuation remain challenging. In this paper, we present a method of capturing the molecular relaxation process by only measuring acoustic velocity, without the necessity of obtaining acoustic absorption. The method is based on the fact that the frequency-dependent velocity dispersion of a multi-relaxation process in a gas is the serial connection of the dispersions of interior single-relaxation processes. Thus, one can capture the relaxation times and relaxation strengths of N decomposed single-relaxation dispersions to reconstruct the entire multi-relaxation dispersion using the measurements of acoustic velocity at 2N  +  1 frequencies. The reconstructed dispersion spectra are in good agreement with experimental data for various gases and mixtures. The simulations also demonstrate the robustness of our reconstructive method.

Investigation of liquid phase axial dispersion in Taylor bubble flow by radiotracer residence time distribution analysis

Directory of Open Access Journals (Sweden)

Jin J.H.

2013-05-01

Full Text Available A gas-liquid Taylor bubble flow occurs in small diameter channels in which gas bubbles are separated by slugs of pure liquid. This type of flow regime is well suited for solid catalyzed gas-liquid reactors in which the reaction efficiency is a strong function of axial dispersion in the regions of pure liquid. This paper presents an experimental study of liquid phase axial dispersion in a Taylor bubble flow developed in a horizontal tube using high speed photography and radiotracer residence time distribution (RTD analysis. A parametric dependence of axial dispersion on average volume fraction of gas phase was also investigated by varying the relative volumetric flow rates of the two phases. 137mBa produced from a 137Cs/137mBa radionuclide generator was used as radiotracer and measurements were made using the NaI(Tl scintillation detectors. Validation of 137mBa in the form of barium chloride as aqueous phase radiotracer was also carried out. Axial Dispersion Model (ADM was used to simulate the hydrodynamics of the system and the results of the experiment are presented. It was observed that the system is characterized by very high values of Peclet Number (Pe∼102 which reveals an approaching plug type flow. The experimental and model estimated values of mean residence times were observed in agreement with each other.

Experimental and numerical study of light gas dispersion in a ventilated room

Energy Technology Data Exchange (ETDEWEB)

Gelain, Thomas, E-mail: thomas.gelain@irsn.fr; Prévost, Corinne

2015-11-15

Highlights: • Presentation of many experimental local data for different configurations. • Highlight of the influence of numerical parameters used in the CFD code. • Validation of the CFD code ANSYS CFX on the basis of experimental data. - Abstract: The objective of this study is to validate the ANSYS CFX version 12 computational code on the basis of light gas dispersion tests performed in two ventilated rooms. It follows an initial study on heavy gas dispersion carried out by Ricciardi et al. (2008). First, a study of sensitivity to various numerical parameters allows a set of reference data to be developed and the influence of the numerical scheme of advection to be revealed. Second, two helium (simulating hydrogen) dispersion test grids are simulated for the two rooms studied, and the results of the calculations are compared with experimental results. The very good agreement between these results allows the code and its dataset to be validated for this application. In future, a study with higher levels of helium (on the order of 4% vol at equilibrium) is envisaged in the context of safety analyses related to the hydrogen risk, these levels representing the lower explosive limit (LEL) of hydrogen.

Emission quantification using the tracer gas dispersion method: The influence of instrument, tracer gas species and source simulation

DEFF Research Database (Denmark)

Delre, Antonio; Mønster, Jacob; Samuelsson, Jerker

2018-01-01

The tracer gas dispersion method (TDM) is a remote sensing method used for quantifying fugitive emissions by relying on the controlled release of a tracer gas at the source, combined with concentration measurements of the tracer and target gas plumes. The TDM was tested at a wastewater treatment...... plant for plant-integrated methane emission quantification, using four analytical instruments simultaneously and four different tracer gases. Measurements performed using a combination of an analytical instrument and a tracer gas, with a high ratio between the tracer gas release rate and instrument...... precision (a high release-precision ratio), resulted in well-defined plumes with a high signal-to-noise ratio and a high methane-to-tracer gas correlation factor. Measured methane emission rates differed by up to 18% from the mean value when measurements were performed using seven different instrument...

Modeling blast waves, gas and particles dispersion in urban and hilly ground areas

International Nuclear Information System (INIS)

Hank, S.; Saurel, R.; Le Metayer, O.; Lapebie, E.

2014-01-01

The numerical simulation of shock and blast waves as well as particles dispersion in highly heterogeneous media such as cities, urban places, industrial plants and part of countries is addressed. Examples of phenomena under study are chemical gas products dispersion from damaged vessels, gas dispersion in urban places under explosion conditions, shock wave propagation in urban environment. A three-dimensional simulation multiphase flow code (HI2LO) is developed in this aim. To simplify the consideration of complex geometries, a heterogeneous discrete formulation is developed. When dealing with large scale domains, such as countries, the topography is considered with the help of elevation data. Meteorological conditions are also considered, in particular regarding complex temperature and wind profiles. Heat and mass transfers on sub-scale objects, such as buildings, trees and other obstacles are considered as well. Particles motion is addressed through a new turbulence model involving a single parameter to describe accurately plumes. Validations against experiments in basic situations are presented as well as examples of industrial and environmental computations. (authors)

Gas dispersal potential of bedding as a cause for sudden infant death.

Science.gov (United States)

Sakai, Jun; Kanetake, Jun; Takahashi, Shirushi; Kanawaku, Yoshimasa; Funayama, Masato

2008-09-18

We assessed the gas dispersal potential of bedding articles used by 14 infants diagnosed with sudden unexpected infant death at autopsy. Of these cases, eight exhibited FiCO(2) values greater than 10% within 2.5 min, six of which were found prone and two supine. The results demonstrated that these eight beddings had a high rebreathing potential if they covered the babies' faces. We did not, however, take into account in our model the large tissue stores of CO(2). As some bicarbonate pools will delay or suppress the increase of FiCO(2), the time-FiCO(2) graphs of this study are not true for living infants. This model, however, demonstrated the potential gas dispersal ability of bedding. The higher the FiCO(2) values, the more dangerous the situation for rebreathing infants. In addition, FiO(2) in the potential space around the model's face can be estimated mathematically using FiCO(2) values. The FiO(2) graph pattern for each bedding item corresponded roughly to the inverse of the FiCO(2) time course. The FiO(2) of the above eight cases decreased by 8.5% within 2.5 min. Recent studies using living infants placed prone to sleep reported that some babies exhibited larger decreases in FiO(2) than increases observed in FiCO(2). While the decrease of FiO(2) in our model is still theoretical, CO(2) accumulation and O(2) deprivation are closely related. If a striking O(2) deficiency occurs in a short period, babies can lose consciousness before an arousal response is evoked and all infants could be influenced by the poor gas dispersal of bedding; the main cause of sudden death in infancy would thus be asphyxia. When the bedding is soft, the potential for trapping CO(2) seems to be high; however, it is impossible to assess it by appearance alone. We sought to provide some objective indices for the assessment of respiratory compromise in relation to bedding using our model. When a baby is found unresponsive with his/her face covered with poor gas dispersal bedding, we should

Experimental and Numerical Modelling of CO2 Atmospheric Dispersion in Hazardous Gas Emission Sites.

Science.gov (United States)

Gasparini, A.; sainz Gracia, A. S.; Grandia, F.; Bruno, J.

2015-12-01

Under stable atmospheric conditions and/or in presence of topographic depressions, CO2 concentrations can reach high values resulting in lethal effect to living organisms. The distribution of denser than air gases released from the underground is governed by gravity, turbulence and dispersion. Once emitted, the gas distribution is initially driven by buoyancy and a gas cloud accumulates on the ground (gravitational phase); with time the density gradient becomes less important due to dispersion or mixing and gas distribution is mainly governed by wind and atmospheric turbulence (passive dispersion phase). Natural analogues provide evidences of the impact of CO2 leakage. Dangerous CO2 concentration in atmosphere related to underground emission have been occasionally reported although the conditions favouring the persistence of such a concentration are barely studied.In this work, the dynamics of CO2 in the atmosphere after ground emission is assessed to quantify their potential risk. Two approaches have been followed: (1) direct measurement of air concentration in a natural emission site, where formation of a "CO2 lake" is common and (2) numerical atmospheric modelling. Two sites with different morphology were studied: (a) the Cañada Real site, a flat terrain in the Volcanic Field of Campo de Calatrava (Spain); (b) the Solforata di Pomezia site, a rough terrain in the Alban Hills Volcanic Region (Italy). The comparison between field data and model calculations reveal that numerical dispersion models are capable of predicting the formation of CO2 accumulation over the ground as a consequence of underground gas emission. Therefore, atmospheric modelling could be included as a valuable methodology in the risk assessment of leakage in natural degassing systems and in CCS projects. Conclusions from this work provide clues on whether leakage may be a real risk for humans and under which conditions this risk needs to be included in the risk assessment.

GADEN: A 3D Gas Dispersion Simulator for Mobile Robot Olfaction in Realistic Environments.

Science.gov (United States)

Monroy, Javier; Hernandez-Bennets, Victor; Fan, Han; Lilienthal, Achim; Gonzalez-Jimenez, Javier

2017-06-23

This work presents a simulation framework developed under the widely used Robot Operating System (ROS) to enable the validation of robotics systems and gas sensing algorithms under realistic environments. The framework is rooted in the principles of computational fluid dynamics and filament dispersion theory, modeling wind flow and gas dispersion in 3D real-world scenarios (i.e., accounting for walls, furniture, etc.). Moreover, it integrates the simulation of different environmental sensors, such as metal oxide gas sensors, photo ionization detectors, or anemometers. We illustrate the potential and applicability of the proposed tool by presenting a simulation case in a complex and realistic office-like environment where gas leaks of different chemicals occur simultaneously. Furthermore, we accomplish quantitative and qualitative validation by comparing our simulated results against real-world data recorded inside a wind tunnel where methane was released under different wind flow profiles. Based on these results, we conclude that our simulation framework can provide a good approximation to real world measurements when advective airflows are present in the environment.

Analysis of site-specific dispersion conditions

International Nuclear Information System (INIS)

Paesler-Sauer, J.

1989-03-01

This report presents an analysis of atmospheric dispersion conditions in the environs of nuclear power stations in the Federal Republic of Germany. The analysis is based on meteorological data measured on the power station sites (KFUe = nuclear reactor remote control records) and by neighbouring stations operated by the German Weather Service. The data are series of hourly mean values of wind and temperature gradient or stability class over the period of one or more years. The aim of the data analysis is to find types of dispersion conditions characterized by the flow field and stratification, and to assess the feasibility of calculating these quantities in the case of an emergency. Influences of terrain structures in the environs of the site are considered. The annual frequencies of types of dispersion situations are assessed, the capability to recognize the dispersion situation from meteorological data measured on the site and the applicability of dispersion models are discussed. (orig.) [de

Fundamentals of energy dispersive X-ray analysis

CERN Document Server

Russ, John C; Kiessling, R; Charles, J

1984-01-01

Fundamentals of Energy Dispersive X-ray Analysis provides an introduction to the fundamental principles of dispersive X-ray analysis. It presents descriptions, equations, and graphs to enable the users of these techniques to develop an intuitive and conceptual image of the physical processes involved in the generation and detection of X-rays. The book begins with a discussion of X-ray detection and measurement, which is accomplished by one of two types of X-ray spectrometer: energy dispersive or wavelength dispersive. The emphasis is on energy dispersive spectrometers, given their rather wid

A wind-tunnel study on exhaust gas dispersion from road vehicles. Part 1. Velocity and concentration fields behind single vehicles

Energy Technology Data Exchange (ETDEWEB)

Kanda, Isao; Uehara, Kiyoshi; Yamao, Yukio [National Institute for Environmental Studies, 16-2 Onogawa, Tsukuba, 305-8506 (Japan); Yoshikawa, Yasuo; Morikawa, Tazuko [Petroleum Energy Center, 4-3-9 Toranomon, Minato-ku, Tokyo, 105-0001 (Japan)

2006-09-15

By a reduced-scale model in a wind tunnel, we investigate the dispersion behavior of exhaust gas from automobiles. Two types of vehicles are considered, a passenger car and a small-size truck. Tracer gas experiments show that the exhaust gas dispersion is enhanced significantly by the vehicle wake compared to the case when the vehicle body is absent. The passenger car and the truck promote dispersion in the horizontal and the vertical direction, respectively. The wake field is analyzed by particle image velocimetry (PIV), and the distribution of the mean and the fluctuation fields is found to conform to the concentration field of the exhaust gas. The buoyancy of the exhaust gas has minor effect except on the vertical spread behind the truck whose wake flow amplifies the vertical displacement generated near the pipe exit. (author)

TOXRISK, Toxic Gas Release Accident Analysis

International Nuclear Information System (INIS)

Bennett, D.E.; Chanin, D.I.; Shiver, A.W.

1993-01-01

1 - Description of program or function: TOXRISK is an interactive program developed to aid in the evaluation of nuclear power plant control room habitability in the event of a nearby toxic material release. The program uses a model which is consistent with the approach described in the NRC Regulatory Guide 1.78. Release of the gas is treated as an initial puff followed by a continuous plume. The relative proportions of these as well as the plume release rate are supplied by the user. Transport of the gas is modeled as a Gaussian distribution and occurs through the action of a constant velocity, constant direction wind. Great flexibility is afforded the user in specifying the release description, meteorological conditions, relative geometry of the accident and plant, and the plant ventilation system characteristics. Two types of simulation can be performed: multiple case (parametric) studies and probabilistic analyses. Upon execution, TOXRISK presents a menu, and the user chooses between the Data Base Manager, the Multiple Case program, and the Probabilistic Study Program. The Data Base Manager provides a convenient means of storing, retrieving, and modifying blocks of data required by the analysis programs. The Multiple Case program calculates resultant gas concentrations inside the control room and presents a summary of information that describes the event for each set of conditions given. Optimally, a time history profile of inside and outside concentrations can also be produced. The Probabilistic Study program provides a means for estimating the annual probability of operator incapacitation due to toxic gas accidents on surrounding transportation routes and storage sites. 2 - Method of solution: Dispersion or diffusion of the gas during transport is described by modified Pasquill-Gifford dispersion coefficients

Derivation of simplified basic equations of gas-liquid two-phase dispersed flow based on two-fluid model

International Nuclear Information System (INIS)

Kataoka, Isao; Tomiyama, Akio

2004-01-01

The simplified and physically reasonable basic equations for the gas-liquid dispersed flow were developed based on some appropriate assumptions and the treatment of dispersed phase as isothermal rigid particles. Based on the local instant formulation of mass, momentum and energy conservation of the dispersed flow, time-averaged equations were obtained assuming that physical quantities in the dispersed phase are uniform. These assumptions are approximately valid when phase change rate and/or chemical reaction rate are not so large at gas-liquid interface and there is no heat generation in within the dispersed phase. Detailed discussions were made on the characteristics of obtained basic equations and physical meanings of terms consisting the basic equations. It is shown that, in the derived averaged momentum equation, the terms of pressure gradient and viscous momentum diffusion do not appear and, in the energy equation, the term of molecular thermal diffusion heat flux does not appear. These characteristics of the derived equations were shown to be very consistent concerning the physical interpretation of the gas-liquid dispersed flow. Furthermore, the obtained basic equations are consistent with experiments for the dispersed flow where most of averaged physical quantities are obtained assuming that the distributions of those are uniform within the dispersed phase. Investigation was made on the problem whether the obtained basic equations are well-posed or ill-posed for the initial value problem. The eigenvalues of the simplified mass and momentum equations are calculated for basic equations obtained here and previous two-fluid basic equations with one pressure model. Well-posedness and ill-posedness are judged whether the eigenvalues are real or imaginary. The result indicated the newly developed basic equations always constitute the well-posed initial value problem while the previous two-fluid basic equations based on one pressure model constitutes ill

A dynamic approach for the impact of a toxic gas dispersion hazard considering human behaviour and dispersion modelling.

Science.gov (United States)

Lovreglio, Ruggiero; Ronchi, Enrico; Maragkos, Georgios; Beji, Tarek; Merci, Bart

2016-11-15

The release of toxic gases due to natural/industrial accidents or terrorist attacks in populated areas can have tragic consequences. To prevent and evaluate the effects of these disasters different approaches and modelling tools have been introduced in the literature. These instruments are valuable tools for risk managers doing risk assessment of threatened areas. Despite the significant improvements in hazard assessment in case of toxic gas dispersion, these analyses do not generally include the impact of human behaviour and people movement during emergencies. This work aims at providing an approach which considers both modelling of gas dispersion and evacuation movement in order to improve the accuracy of risk assessment for disasters involving toxic gases. The approach is applied to a hypothetical scenario including a ship releasing Nitrogen dioxide (NO2) on a crowd attending a music festival. The difference between the results obtained with existing static methods (people do not move) and a dynamic approach (people move away from the danger) which considers people movement with different degrees of sophistication (either a simple linear path or more complex behavioural modelling) is discussed. Copyright © 2016 Elsevier B.V. All rights reserved.

Optimization of two different dispersive liquid-liquid microextraction methods followed by gas chromatography-mass spectrometry determination for polycyclic aromatic hydrocarbons (PAHs) analysis in water.

Science.gov (United States)

Tseng, Wan-Chi; Chen, Pai-Shan; Huang, Shang-Da

2014-03-01

Novel sample preparation methods termed "up-and-down shaker-assisted dispersive liquid-liquid microextraction (UDSA-DLLME)" and "water with low concentration of surfactant in dispersed solvent-assisted emulsion dispersive liquid-liquid microextraction (WLSEME)" coupled with gas chromatography-mass spectrometry (GC-MS) have been developed for the analysis of 11 polycyclic aromatic hydrocarbons (PAHs) in aqueous samples. For UDSA-DLLME, an up-and-down shaker-assisted emulsification was employed. Extraction was complete in 3min. Only 14 μL of 1-heptanol was required, without a dispersive solvent. Under the optimum conditions, the linear range was 0.08-100 µg L(-1), and the LODs were in the range 0.022-0.060 µg L(-1). The enrichment factors (EFs) ranged from 392 to 766. Relative recoveries were between 84% and 113% for river, lake, and field water. In WLSEME, 9 μL of 1-nonanol as extraction solvent and 240 μL of 1 mg L(-1) Triton X-100 as surfactant were mixed in a microsyringe to form a cloudy emulsified solution, which was then injected into the samples. Compared with other surfactant-assisted emulsion methods, WLSEME uses much less surfactant. The linear range was 0.08-100 µg L(-1), and the LODs were 0.022-0.13 µg L(-1). The EFs ranged from 388 to 649. The relative recoveries were 86-114% for all three water specimens. Copyright © 2013 Elsevier B.V. All rights reserved.

Self Powered Non-Dispersive Infra-Red CO{sub 2} Gas Sensor

Energy Technology Data Exchange (ETDEWEB)

Gibson, D R; MacGregor, C, E-mail: des@gassensing.co.uk [Gas Sensing Solutions Ltd, 60 Grayshill Road, Westfield North Courtyard, Glasgow G68 9HQ (United Kingdom)

2011-08-17

This paper describes a non-dispersive infra-red CO{sub 2} gas sensor, incorporating a mid-infra-red solid state light source/ detector combination, tuned to match the spectral absorption characteristic of CO{sub 2} gas. Injection moulded optics provide low cost manufacture. Continuous operation power consumption is < 3.5mW and pulsed mode with energy per measurement < 6mJ. Self powered operation using a solar cell is demonstrated together with wireless capability. Performance of two path length variants (20mm and 70mm) is described. The sensor shows invariant temperature output characteristic from -25 to 50 deg. C. Accuracy level is typically {+-}3% of reading.

Axial dispersion of gas and solid phases in a gas—solid packed column at trickle flow

NARCIS (Netherlands)

Roes, A.W.M.; van Swaaij, Willibrordus Petrus Maria

1979-01-01

Axial dispersion of gas and solid phases in a gas—solid packed column at trickle flow, a promising new countercurrent operation, was evaluated using residence time distribution (RTD) experiments. The column was packed with dumped Pall rings, the gas phase was air at ambient conditions and the solid

Validation of OpenFoam for heavy gas dispersion applications.

Science.gov (United States)

Mack, A; Spruijt, M P N

2013-11-15

In the present paper heavy gas dispersion calculations were performed with OpenFoam. For a wind tunnel test case, numerical data was validated with experiments. For a full scale numerical experiment, a code to code comparison was performed with numerical results obtained from Fluent. The validation was performed in a gravity driven environment (slope), where the heavy gas induced the turbulence. For the code to code comparison, a hypothetical heavy gas release into a strongly turbulent atmospheric boundary layer including terrain effects was selected. The investigations were performed for SF6 and CO2 as heavy gases applying the standard k-ɛ turbulence model. A strong interaction of the heavy gas with the turbulence is present which results in a strong damping of the turbulence and therefore reduced heavy gas mixing. Especially this interaction, based on the buoyancy effects, was studied in order to ensure that the turbulence-buoyancy coupling is the main driver for the reduced mixing and not the global behaviour of the turbulence modelling. For both test cases, comparisons were performed between OpenFoam and Fluent solutions which were mainly in good agreement with each other. Beside steady state solutions, the time accuracy was investigated. In the low turbulence environment (wind tunnel test) which for both codes (laminar solutions) was in good agreement, also with the experimental data. The turbulent solutions of OpenFoam were in much better agreement with the experimental results than the Fluent solutions. Within the strong turbulence environment, both codes showed an excellent comparability. Copyright © 2013 Elsevier B.V. All rights reserved.

Short-term gas dispersion in idealised urban canopy in street parallel with flow direction

Science.gov (United States)

Chaloupecká, Hana; Jaňour, Zbyněk; Nosek, Štěpán

2016-03-01

Chemical attacks (e.g. Syria 2014-15 chlorine, 2013 sarine or Iraq 2006-7 chlorine) as well as chemical plant disasters (e.g. Spain 2015 nitric oxide, ferric chloride; Texas 2014 methyl mercaptan) threaten mankind. In these crisis situations, gas clouds are released. Dispersion of gas clouds is the issue of interest investigated in this paper. The paper describes wind tunnel experiments of dispersion from ground level point gas source. The source is situated in a model of an idealised urban canopy. The short duration releases of passive contaminant ethane are created by an electromagnetic valve. The gas cloud concentrations are measured in individual places at the height of the human breathing zone within a street parallel with flow direction by Fast-response Ionisation Detector. The simulations of the gas release for each measurement position are repeated many times under the same experimental set up to obtain representative datasets. These datasets are analysed to compute puff characteristics (arrival, leaving time and duration). The results indicate that the mean value of the dimensionless arrival time can be described as a growing linear function of the dimensionless coordinate in the street parallel with flow direction where the gas source is situated. The same might be stated about the dimensionless leaving time as well as the dimensionless duration, however these fits are worse. Utilising a linear function, we might also estimate some other statistical characteristics from datasets than the datasets means (medians, trimeans). The datasets of the dimensionless arrival time, the dimensionless leaving time and the dimensionless duration can be fitted by the generalized extreme value distribution (GEV) in all sampling positions except one.

Calculations of the mean regional dispersion of a radioactive gas emitted from a continuous source

International Nuclear Information System (INIS)

Persson, C.

1974-10-01

The mean dispersion of a radioactive gas over distances of the order of 1000 kilometers is estimated with the aid of a statistical treatment of computed geostrophic trajectories and simplified vertical diffusion calculations based on the eddy diffusivity theory. (author)

High-resolution modelling of atmospheric dispersion of dense gas using TWODEE-2.1: application to the 1986 Lake Nyos limnic eruption

Science.gov (United States)

Folch, Arnau; Barcons, Jordi; Kozono, Tomofumi; Costa, Antonio

2017-06-01

Atmospheric dispersal of a gas denser than air can threat the environment and surrounding communities if the terrain and meteorological conditions favour its accumulation in topographic depressions, thereby reaching toxic concentration levels. Numerical modelling of atmospheric gas dispersion constitutes a useful tool for gas hazard assessment studies, essential for planning risk mitigation actions. In complex terrains, microscale winds and local orographic features can have a strong influence on the gas cloud behaviour, potentially leading to inaccurate results if not captured by coarser-scale modelling. We introduce a methodology for microscale wind field characterisation based on transfer functions that couple a mesoscale numerical weather prediction model with a microscale computational fluid dynamics (CFD) model for the atmospheric boundary layer. The resulting time-dependent high-resolution microscale wind field is used as input for a shallow-layer gas dispersal model (TWODEE-2.1) to simulate the time evolution of CO2 gas concentration at different heights above the terrain. The strategy is applied to review simulations of the 1986 Lake Nyos event in Cameroon, where a huge CO2 cloud released by a limnic eruption spread downslopes from the lake, suffocating thousands of people and animals across the Nyos and adjacent secondary valleys. Besides several new features introduced in the new version of the gas dispersal code (TWODEE-2.1), we have also implemented a novel impact criterion based on the percentage of human fatalities depending on CO2 concentration and exposure time. New model results are quantitatively validated using the reported percentage of fatalities at several locations. The comparison with previous simulations that assumed coarser-scale steady winds and topography illustrates the importance of high-resolution modelling in complex terrains.

HYDRODYNAMICS OF HIGH-REDSHIFT GALAXY COLLISIONS: FROM GAS-RICH DISKS TO DISPERSION-DOMINATED MERGERS AND COMPACT SPHEROIDS

International Nuclear Information System (INIS)

Bournaud, Frederic; Chapon, Damien; Teyssier, Romain; Powell, Leila C.; Duc, Pierre-Alain; Elmegreen, Bruce G.; Elmegreen, Debra Meloy; Contini, Thierry; Epinat, Benoit; Shapiro, Kristen L.

2011-01-01

Disk galaxies at high redshift (z ∼ 2) are characterized by high fractions of cold gas, strong turbulence, and giant star-forming clumps. Major mergers of disk galaxies at high redshift should then generally involve such turbulent clumpy disks. Merger simulations, however, model the interstellar medium as a stable, homogeneous, and thermally pressurized medium. We present the first merger simulations with high fractions of cold, turbulent, and clumpy gas. We discuss the major new features of these models compared to models where the gas is artificially stabilized and warmed. Gas turbulence, which is already strong in high-redshift disks, is further enhanced in mergers. Some phases are dispersion dominated, with most of the gas kinetic energy in the form of velocity dispersion and very chaotic velocity fields, unlike merger models using a thermally stabilized gas. These mergers can reach very high star formation rates, and have multi-component gas spectra consistent with SubMillimeter Galaxies. Major mergers with high fractions of cold turbulent gas are also characterized by highly dissipative gas collapse to the center of mass, with the stellar component following in a global contraction. The final galaxies are early type with relatively small radii and high Sersic indices, like high-redshift compact spheroids. The mass fraction in a disk component that survives or re-forms after a merger is severely reduced compared to models with stabilized gas, and the formation of a massive disk component would require significant accretion of external baryons afterwards. Mergers thus appear to destroy extended disks even when the gas fraction is high, and this lends further support to smooth infall as the main formation mechanism for massive disk galaxies.

Analysis of hydrodynamic regimes of operation of a gas pipeline from the Samotlor field to the Nizhnevartovsk gas refinery

Energy Technology Data Exchange (ETDEWEB)

Al' tshular, S A; Bragunov, N I; Ivanov, V N; Izmaylov, I Ye; Koroleva, L N

1979-01-01

Results are presented from studying the hydraulic losses of a gas-transport system. Oil gas in the first stage of separation of the Samotlor field according to the plan is transported on two gas pipelines to the Nizhnevartovsk and Belozersk gas refinery. On the route of the first gas pipeline in order to remove the released condensate, 12 gas-separator and condensate-settling tanks are installed. The second gas pipeline in the beginning, middle and end has asemblies for additional separation (separation (separator, drop-separator, condensate-collector). The studied material is presented in the form of the dependence of actual calculatedcoefficients of hydraulic resistance on the rate of gas supply in the range 80,000-230,000 m/sup 3//h (Re-(0.82.0) X 10/sup -6/. It has been established that with Re=1.6 X 10/sup -6/ the calculated and actual coeffic-ients of resistance become the same, while with smaller values of Re, the actual values exceed the calculated by 20-40%. In the opinion of the authors this difference is due to the effect of the liquid phase with low velocities of gas and the formation of stable foam. As a result of transillumination it was also established that the regime of flow on the ascending part is dispersion-ring and dispersion-semiring, and on the descending part stratified. Analysis of the transport of the gas-condensate stream with ring regime of flow permitted the authors to hypothesize transporting of gas without removal of the condensate. A certain increase in the coefficients of resistance for the case where the condensate is not removed from the gas pipeline is noted with experimental realization of the proposed variant. It is explained by the low velocities of gas in the beginning of the gas pipeline. It is stressed that the actual and calculated pressure differentials are distinguished less than the calculated and actual coefficients of resistance and that this indicates the practical preservation of the throughput of the gas pipeline.

A sensitivity analysis of volcanic aerosol dispersion in the stratosphere. [Mt. Fuego, Guatemala eruptions

Science.gov (United States)

Butler, C. F.

1979-01-01

A computer sensitivity analysis was performed to determine the uncertainties involved in the calculation of volcanic aerosol dispersion in the stratosphere using a 2 dimensional model. The Fuego volcanic event of 1974 was used. Aerosol dispersion processes that were included are: transport, sedimentation, gas phase sulfur chemistry, and aerosol growth. Calculated uncertainties are established from variations in the stratospheric aerosol layer decay times at 37 latitude for each dispersion process. Model profiles are also compared with lidar measurements. Results of the computer study are quite sensitive (factor of 2) to the assumed volcanic aerosol source function and the large variations in the parameterized transport between 15 and 20 km at subtropical latitudes. Sedimentation effects are uncertain by up to a factor of 1.5 because of the lack of aerosol size distribution data. The aerosol chemistry and growth, assuming that the stated mechanisms are correct, are essentially complete in several months after the eruption and cannot explain the differences between measured and modeled results.

Modelling airborne dispersion for disaster management

Science.gov (United States)

Musliman, I. A.; Yohnny, L.

2017-05-01

Industrial disasters, like any other disasters, can happen anytime, anywhere and in any form. Airborne industrial disaster is a kind of catastrophic event involving the release of particles such as chemicals and industrial wastes into environment in gaseous form, for instance gas leakages. Unlike solid and liquid materials, gases are often colourless and odourless, the particles are too tiny to be visible to the naked eyes; hence it is difficult to identify the presence of the gases and to tell the dispersion and location of the substance. This study is to develop an application prototype to perform simulation modelling on the gas particles to determine the dispersion of the gas particles and to identify the coverage of the affected area. The prototype adopted Lagrangian Particle Dispersion (LPD) model to calculate the position of the gas particles under the influence of wind and turbulent velocity components, which are the induced wind due to the rotation of the Earth, and Convex Hull algorithm to identify the convex points of the gas cloud to form the polygon of the coverage area. The application performs intersection and overlay analysis over a set of landuse data at Pasir Gudang, Johor industrial and residential area. Results from the analysis would be useful to tell the percentage and extent of the affected area, and are useful for the disaster management to evacuate people from the affected area. The developed application can significantly increase efficiency of emergency handling during a crisis. For example, by using a simulation model, the emergency handling can predict what is going to happen next, so people can be well informed and preparations works can be done earlier and better. Subsequently, this application helps a lot in the decision making process.

Modelling airborne dispersion for disaster management

International Nuclear Information System (INIS)

Musliman, I A; Yohnny, L

2017-01-01

Industrial disasters, like any other disasters, can happen anytime, anywhere and in any form. Airborne industrial disaster is a kind of catastrophic event involving the release of particles such as chemicals and industrial wastes into environment in gaseous form, for instance gas leakages. Unlike solid and liquid materials, gases are often colourless and odourless, the particles are too tiny to be visible to the naked eyes; hence it is difficult to identify the presence of the gases and to tell the dispersion and location of the substance. This study is to develop an application prototype to perform simulation modelling on the gas particles to determine the dispersion of the gas particles and to identify the coverage of the affected area. The prototype adopted Lagrangian Particle Dispersion (LPD) model to calculate the position of the gas particles under the influence of wind and turbulent velocity components, which are the induced wind due to the rotation of the Earth, and Convex Hull algorithm to identify the convex points of the gas cloud to form the polygon of the coverage area. The application performs intersection and overlay analysis over a set of landuse data at Pasir Gudang, Johor industrial and residential area. Results from the analysis would be useful to tell the percentage and extent of the affected area, and are useful for the disaster management to evacuate people from the affected area. The developed application can significantly increase efficiency of emergency handling during a crisis. For example, by using a simulation model, the emergency handling can predict what is going to happen next, so people can be well informed and preparations works can be done earlier and better. Subsequently, this application helps a lot in the decision making process. (paper)

Determination of Organophosphorus Pesticides in Soil by Dispersive Liquid–Liquid Microextraction and Gas Chromatography

Science.gov (United States)

Yang, Zhonghua; Liu, Yu; Liu, Donghui; Zhou, Zhiqiang

2012-01-01

In this article, a rapid and sensitive sample pretreatment technique for the determination of organophosphorus pesticides (OPPs) in soil samples is developed by using dispersive liquid–liquid microextraction (DLLME) combined with gas chromatography–flame photometric detection. Experimental conditions, including the kind of extraction and disperser solvent and their volumes, the extraction time, and the salt addition, are investigated, and the following experiment factors are used: 20 µL chlorobenzene as the extraction solvent; 1.0 mL acetonitrile as the disperser solvent; no addition of salt; and an extraction time of 1 min. Under the optimum conditions, the linearities for the three target OPPs (ethoprophos, chlorpyriphos, and profenofos) are obtained by five points in the concentration range of 2.5–1500 µg/kg, and three replicates are used for each point. Correlation coefficients vary from 0.9987 to 0.9997. The repeatability is tested by spiking soil samples at a concentration level of 5.0 µg/kg. The relative standard deviation (n = 3) varied between 2.0% and 6.6%. The limits of detection, based on a signal-to-noise ratio (S/N) of 3, range from 200 to 500 pg/g. This method is applied to the analysis of the spiked samples S1, S2, and S3, which are collected from the China Agriculture University's orchard, lawn, and garden, respectively. The recoveries for each target analyte are in the range between 87.9% and 108.0%, 87.4% and 108.0%, and 86.7% and 107.2%, respectively. PMID:22291051

NOx Monitoring in Humid Exhaust Gas Using Non-Dispersive Infrared Spectroscopy

DEFF Research Database (Denmark)

Stolberg-Rohr, Thomine Kirstine

This PhD thesis is concerned with the measurement of NOX in moist exhaust gas onboard ships using non-dispersive infrared (NDIR) spectroscopy. In such a measurement one of the major challenges is spectral interference from water vapour which is present in high concentrations in the exhaust. The Ph......D study investigates a possible solution to this problem, which is to balance out the signal contribution from water vapour by means of carefully designed and manufactured optical bandpass filters. The thesis, presents a thorough theoretical description of the NDIR sensor concept together with simulations...... suggesting that it is possible but challenging to measure NOX in moist exhaust gas using NDIR. The characteristics of optical filters tend to change with temperature, and since this compromises the water signal balancing, much of the work presented in the thesis is devoted to the design of optical bandpass...

Review of potential models for UF6 dispersion

International Nuclear Information System (INIS)

Sykes, R.I.; Lewellen, W.S.

1992-07-01

A survey of existing atmospheric dispersion models has been conducted to determine the most appropriate basis for the development of a model for predicting the consequences of an accidental UF 6 release. The model is required for safety analysis studies and should therefore be computationally efficient. The release of UF 6 involves a number of physical phenomena which make the situation more complicated than passive dispersion of a trace gas. The safety analysis must consider the density variations in the UF 6 cloud, which can be heavier or lighter than the ambient air. The release also involves rapid chemical reactions and associated heat release, which must be modeled. Other Department of Energy storage facilities require a dense gas prediction capability, so the model must be sufficiently general for use with a variety of release scenarios. The special problems associated with UF 6 make it unique, so there are very few models with existing capability for the problem. There are, however, a large number of dense gas dispersion models, some with relevant chemical reaction modeling, that could potentially form the basis of an advanced UF 6 model. We have examined a large selection of possible candidates, and selected 5 models for detailed consideration

Time-Frequency Analysis of the Dispersion of Lamb Modes

Science.gov (United States)

Prosser, W. H.; Seale, Michael D.; Smith, Barry T.

1999-01-01

Accurate knowledge of the velocity dispersion of Lamb modes is important for ultrasonic nondestructive evaluation methods used in detecting and locating flaws in thin plates and in determining their elastic stiffness coefficients. Lamb mode dispersion is also important in the acoustic emission technique for accurately triangulating the location of emissions in thin plates. In this research, the ability to characterize Lamb mode dispersion through a time-frequency analysis (the pseudo Wigner-Ville distribution) was demonstrated. A major advantage of time-frequency methods is the ability to analyze acoustic signals containing multiple propagation modes, which overlap and superimpose in the time domain signal. By combining time-frequency analysis with a broadband acoustic excitation source, the dispersion of multiple Lamb modes over a wide frequency range can be determined from as little as a single measurement. In addition, the technique provides a direct measurement of the group velocity dispersion. The technique was first demonstrated in the analysis of a simulated waveform in an aluminum plate in which the Lamb mode dispersion was well known. Portions of the dispersion curves of the A(sub 0), A(sub 1), S(sub 0), and S(sub 2)Lamb modes were obtained from this one waveform. The technique was also applied for the analysis of experimental waveforms from a unidirectional graphite/epoxy composite plate. Measurements were made both along, and perpendicular to the fiber direction. In this case, the signals contained only the lowest order symmetric and antisymmetric modes. A least squares fit of the results from several source to detector distances was used. Theoretical dispersion curves were calculated and are shown to be in good agreement with experimental results.

Development of a code to simulate dispersion of atmospheric released tritium gas in the environmental media and to evaluate doses. TRIDOSE

International Nuclear Information System (INIS)

Murata, Mikio; Noguchi, Hiroshi; Yokoyama, Sumi

2000-11-01

A computer code (TRIDOSE) was developed to assess the environmental impact of atmospheric released tritium gas (T 2 ) from nuclear fusion related facilities. The TRIDOSE simulates dispersion of T 2 and resultant HTO in the atmosphere, land, plant, water and foods in the environment, and evaluates contamination concentrations in the media and exposure doses. A part of the mathematical models in TRIDOSE were verified by comparison of the calculation with the results of the short range (400 m) dispersion experiment of HT gas performed in Canada postulating a short-time (30 minutes) accidental release. (author)

Source strength and dispersion of CO2 releases from high-pressure pipelines: CFD model using real gas equation of state

International Nuclear Information System (INIS)

Liu, Xiong; Godbole, Ajit; Lu, Cheng; Michal, Guillaume; Venton, Philip

2014-01-01

Highlights: • Validated CFD models for decompression and dispersion of CO 2 releases from pipelines. • Incorporation of real gas EOS into CFD code for source strength estimation. • Demonstration of better performance of SST k–ω turbulence model for jet flow. • Demonstration of better performance of real gas EOS compared to ideal gas EOS. • Demonstration of superiority of CFD models over a commercial risk assessment package. - Abstract: Transportation of CO 2 in high-pressure pipelines forms a crucial link in the ever-increasing application of Carbon Capture and Storage (CCS) technologies. An unplanned release of CO 2 from a pipeline presents a risk to human and animal populations and the environment. Therefore it is very important to develop a deeper understanding of the atmospheric dispersion of CO 2 before the deployment of CO 2 pipelines, to allow the appropriate safety precautions to be taken. This paper presents a two-stage Computational Fluid Dynamics (CFD) study developed (1) to estimate the source strength, and (2) to simulate the subsequent dispersion of CO 2 in the atmosphere, using the source strength estimated in stage (1). The Peng–Robinson (PR) EOS was incorporated into the CFD code. This enabled accurate modelling of the CO 2 jet to achieve more precise source strength estimates. The two-stage simulation approach also resulted in a reduction in the overall computing time. The CFD models were validated against experimental results from the British Petroleum (BP) CO 2 dispersion trials, and also against results produced by the risk management package Phast. Compared with the measurements, the CFD simulation results showed good agreement in both source strength and dispersion profile predictions. Furthermore, the effect of release direction on the dispersion was studied. The presented research provides a viable method for the assessment of risks associated with CCS

Droplet dispersion angle measurements on a Pease-Antony Venturi scrubber

Directory of Open Access Journals (Sweden)

N. A. G. Puentes

2012-03-01

Full Text Available A Pease-Anthony Venturi scrubber is a gas cleaning device that uses liquid, injected in the equipment as jets, to remove contaminants from the gas. The liquid jet is atomized into droplets, which are dispersed throughout the equipment due to the turbulence. The performance of the scrubber is affected by the spatial distribution of the droplets. Although CFD models have been used to predict the droplet dispersion, these models are expensive. Alternatively, the concept of "jet spreading angle" could be used as a simple and quick way to estimate droplet dispersion. The purpose of this paper is to measure the spreading angle of jets transversally injected into the throat of a Venturi scrubber and correlate it with both gas and jet velocities. The throat gas velocities varied between 59 and 74 m/s and the jet velocity between 3.18 and 19.1 m/s. The angles were measured through image analysis, obtained with high velocity photography. The spreading angle was found to be strongly dependent on jet velocity.

Dispersed Fringe Sensing Analysis - DFSA

Science.gov (United States)

Sigrist, Norbert; Shi, Fang; Redding, David C.; Basinger, Scott A.; Ohara, Catherine M.; Seo, Byoung-Joon; Bikkannavar, Siddarayappa A.; Spechler, Joshua A.

2012-01-01

Dispersed Fringe Sensing (DFS) is a technique for measuring and phasing segmented telescope mirrors using a dispersed broadband light image. DFS is capable of breaking the monochromatic light ambiguity, measuring absolute piston errors between segments of large segmented primary mirrors to tens of nanometers accuracy over a range of 100 micrometers or more. The DFSA software tool analyzes DFS images to extract DFS encoded segment piston errors, which can be used to measure piston distances between primary mirror segments of ground and space telescopes. This information is necessary to control mirror segments to establish a smooth, continuous primary figure needed to achieve high optical quality. The DFSA tool is versatile, allowing precise piston measurements from a variety of different optical configurations. DFSA technology may be used for measuring wavefront pistons from sub-apertures defined by adjacent segments (such as Keck Telescope), or from separated sub-apertures used for testing large optical systems (such as sub-aperture wavefront testing for large primary mirrors using auto-collimating flats). An experimental demonstration of the coarse-phasing technology with verification of DFSA was performed at the Keck Telescope. DFSA includes image processing, wavelength and source spectral calibration, fringe extraction line determination, dispersed fringe analysis, and wavefront piston sign determination. The code is robust against internal optical system aberrations and against spectral variations of the source. In addition to the DFSA tool, the software package contains a simple but sophisticated MATLAB model to generate dispersed fringe images of optical system configurations in order to quickly estimate the coarse phasing performance given the optical and operational design requirements. Combining MATLAB (a high-level language and interactive environment developed by MathWorks), MACOS (JPL s software package for Modeling and Analysis for Controlled Optical

Droplet behavior analysis in consideration of droplet entrainment from liquid film in annular dispersed flow

International Nuclear Information System (INIS)

Matsuura, Keizo; Otake, Hiroshi; Kataoka, Isao; Serizawa, Akimi

2000-01-01

A method of droplet behavior simulation in an annular dispersed flow has been developed. In this method, both droplet deposition and entrainment from liquid film are considered. The Lagrangian method and stochastic model are used to analyze droplet diffusion and deposition behavior in a turbulent flow, and droplet entrainment from liquid film is calculated by an entrainment correlation. For the verification of this method, Gill's experiment is analyzed, in which the transition from annular flow with no entrainment to equilibrium annular dispersed flow was observed. Analysis results can also show the similar transition tendency. The experimental results of radial distribution of droplet mass flux are compared with analysis results. The agreement is good for low liquid flow rate, but entrainment rate must be adjusted for high liquid flow rate, in which gas turbulence is thought to be modified by high droplet density. In future work the effect of high droplet density on turbulence should be considered. (author)

Mars Exploration Rovers Landing Dispersion Analysis

Science.gov (United States)

Knocke, Philip C.; Wawrzyniak, Geoffrey G.; Kennedy, Brian M.; Desai, Prasun N.; Parker, TImothy J.; Golombek, Matthew P.; Duxbury, Thomas C.; Kass, David M.

2004-01-01

Landing dispersion estimates for the Mars Exploration Rover missions were key elements in the site targeting process and in the evaluation of landing risk. This paper addresses the process and results of the landing dispersion analyses performed for both Spirit and Opportunity. The several contributors to landing dispersions (navigation and atmospheric uncertainties, spacecraft modeling, winds, and margins) are discussed, as are the analysis tools used. JPL's MarsLS program, a MATLAB-based landing dispersion visualization and statistical analysis tool, was used to calculate the probability of landing within hazardous areas. By convolving this with the probability of landing within flight system limits (in-spec landing) for each hazard area, a single overall measure of landing risk was calculated for each landing ellipse. In-spec probability contours were also generated, allowing a more synoptic view of site risks, illustrating the sensitivity to changes in landing location, and quantifying the possible consequences of anomalies such as incomplete maneuvers. Data and products required to support these analyses are described, including the landing footprints calculated by NASA Langley's POST program and JPL's AEPL program, cartographically registered base maps and hazard maps, and flight system estimates of in-spec landing probabilities for each hazard terrain type. Various factors encountered during operations, including evolving navigation estimates and changing atmospheric models, are discussed and final landing points are compared with approach estimates.

Detailed analysis of uranium silicide dispersion fuel swelling

International Nuclear Information System (INIS)

Hofmann, G.L.; Ryu, Woo-Seog

1991-01-01

Swelling of U 3 Si and U 3 Si 2 is analyzed. The growth of fission gas bubbles appears to be affected by fission rate, fuel loading, and micro structural change taking place in the fuel compounds during irradiation. Several mechanisms are explored to explain the observations. The present work is aimed at a better understanding of the basic swelling phenomenon in order to accurately model irradiation behavior of uranium silicide dispersion fuel. (orig.)

Large eddy simulation of pollutant gas dispersion with buoyancy ejected from building into an urban street canyon.

Science.gov (United States)

Hu, L H; Xu, Y; Zhu, W; Wu, L; Tang, F; Lu, K H

2011-09-15

The dispersion of buoyancy driven smoke soot and carbon monoxide (CO) gas, which was ejected out from side building into an urban street canyon with aspect ratio of 1 was investigated by large eddy simulation (LES) under a perpendicular wind flow. Strong buoyancy effect, which has not been revealed before, on such pollution dispersion in the street canyon was studied. The buoyancy release rate was 5 MW. The wind speed concerned ranged from 1 to 7.5m/s. The characteristics of flow pattern, distribution of smoke soot and temperature, CO concentration were revealed by the LES simulation. Dimensionless Froude number (Fr) was firstly introduced here to characterize the pollutant dispersion with buoyancy effect counteracting the wind. It was found that the flow pattern can be well categorized into three regimes. A regular characteristic large vortex was shown for the CO concentration contour when the wind velocity was higher than the critical re-entrainment value. A new formula was theoretically developed to show quantitatively that the critical re-entrainment wind velocities, u(c), for buoyancy source at different floors, were proportional to -1/3 power of the characteristic height. LES simulation results agreed well with theoretical analysis. The critical Froude number was found to be constant of 0.7. Copyright © 2010 Elsevier B.V. All rights reserved.

Development of a code to simulate dispersion of atmospheric released tritium gas in the environmental media and to evaluate doses. TRIDOSE

Energy Technology Data Exchange (ETDEWEB)

Murata, Mikio [Nuclear Engineering Co., Ltd., Hitachi, Ibaraki (Japan); Noguchi, Hiroshi; Yokoyama, Sumi [Japan Atomic Energy Research Inst., Tokai, Ibaraki (Japan). Tokai Research Establishment

2000-11-01

A computer code (TRIDOSE) was developed to assess the environmental impact of atmospheric released tritium gas (T{sub 2}) from nuclear fusion related facilities. The TRIDOSE simulates dispersion of T{sub 2} and resultant HTO in the atmosphere, land, plant, water and foods in the environment, and evaluates contamination concentrations in the media and exposure doses. A part of the mathematical models in TRIDOSE were verified by comparison of the calculation with the results of the short range (400 m) dispersion experiment of HT gas performed in Canada postulating a short-time (30 minutes) accidental release. (author)

Dispersion of Waxy Gas Oil by Some Nonionic Surfactants

International Nuclear Information System (INIS)

Khidr, T.T.; Mahmoud, S.A.

2004-01-01

Straight chain fatty alcohols having the following number of carbon atoms C 12 , C 14 , C 18 and C 21 each alcohol was ethoxylated to the same of ethylene oxide content, characterized through average molecular weight and elemental analysis. The surface properties of these compounds were studied through surface tension measurements. The synthesized additives were tested as flow improvers for improving the cold flow properties of two waxy gas oils through pour point test. The results show the right efficiency of these compounds in improving the flow ability. Comparative evaluation of the synthesized products with available commercial additive (com) showed their efficiency and suitability to use in gas oils. Wax modification was assisted through photo analysis. Correlation between wax modification and flow improvement in term of pour point depression appeared to be merely qualitative in such heterogeneous gas oil systems

Short communication: measurements of methane emissions from feed samples in filter bags or dispersed in the medium in an in vitro gas production system.

Science.gov (United States)

Ramin, M; Krizsan, S J; Jančík, F; Huhtanen, P

2013-07-01

The objective of this study was to compare methane (CH4) emissions from different feeds when incubated within filter bags for in vitro analysis or directly dispersed in the medium in an automated gas in vitro system. Four different concentrates and 4 forages were used in this study. Two lactating Swedish Red cows were used for the collection of rumen fluid. Feed samples were milled to pass a 1.0-mm screen. Aliquots (0.5 g) of samples were weighed directly in the bottles or within the F 0285 filter bags that were placed in the bottles. Gas samples were taken during 24 and 48 h of incubation, and CH4 concentration was determined. The data were analyzed using a general linear model. Feeds differed significantly in CH4 emission both at 24 and at 48 h of incubation. The interaction between feed and method on methane emission in vitro was significant, indicating that the ranking of feeds was not consistent between the methods. Generally, greater amounts of CH4 were emitted from samples directly dispersed in the medium compared with those incubated within the filter bags, which could be a result of lower microbial activity within the filter bags. The ratio of CH4 to total gas was greater when the feeds were incubated within bags compared with samples directly dispersed in the medium. Incubating samples in filter bags during 48 h of incubation cannot be recommended for determination of CH4 emission of feeds in vitro. Copyright © 2013 American Dairy Science Association. Published by Elsevier Inc. All rights reserved.

Computational sensitivity study of spray dispersion and mixing on the fuel properties in a gas turbine combustor

Energy Technology Data Exchange (ETDEWEB)

Grosshans, Holger; Szász, Robert-Zoltán [Division of Fluid Mechanics, Lund University (Sweden); Cao, Le [Key Laboratory for Aerosol-Cloud-Precipitation of China Meteorological Administration, Nanjing University of Information Science and Technology, Nanjing (China); Fuchs, Laszlo, E-mail: holger.grosshans@uclouvain.be [Department of Mechanics, KTH, Stockholm (Sweden)

2017-04-15

A swirl stabilized gas turbine burner has been simulated in order to assess the effects of the fuel properties on spray dispersion and fuel–air mixing. The properties under consideration include fuel surface tension, viscosity and density. The turbulence of the gas phase is modeled applying the methodology of large eddy simulation whereas the dispersed liquid phase is described by Lagrangian particle tracking. The exchange of mass, momentum and energy between the two phases is accounted for by two-way coupling. Bag and stripping breakup regimes are considered for secondary droplet breakup, using the Reitz–Diwakar and the Taylor analogy breakup models. Moreover, a model for droplet evaporation is included. The results reveal a high sensitivity of the spray structure to variations of all investigated parameters. In particular, a decrease in the surface tension or the fuel viscosity, or an increase in the fuel density, lead to less stable liquid structures. As a consequence, smaller droplets are generated and the overall spray surface area increases, leading to faster evaporation and mixing. Furthermore, with the trajectories of the small droplets being strongly influenced by aerodynamic forces (and less by their own inertia), the spray is more affected by the turbulent structures of the gaseous phase and the spray dispersion is enhanced. (paper)

Peer review CALMET/CALPUFF dispersion modelling analysis : Proposed Duke Point generation facility Georgia Strait Crossing pipeline

International Nuclear Information System (INIS)

2002-01-01

A peer review of the air quality dispersion modeling analysis for the proposed gas-fired plant at Duke Point in the vicinity of Nanaimo, British Columbia was required, and SENES Consultants Limited (SENES) was commissioned to perform it. British Columbia Hydro had requested that Levelton Engineering Ltd. prepare an air quality impact assessment, and it was submitted to be included in Vancouver Island Generation Project (VIGP) permit application. This permit application was for the Joint Panel Review of the Georgia Strait Crossing Pipeline (GSX) Project and the British Columbia Environmental Assessment Office. The CALMET/CALPUFF Modelling System had been used by Levelton to conduct the air quality dispersion modelling analysis. Copies of the input and output files that had been used for the conduct of the modelling analysis were provided to SENES. The ability for SENES to reproduce the modelling results that had been published in the GSX application represented the first step in the peer review. This was accomplished by running the files received from Levelton into the CALMET/CALPUFF models. A detailed review of the methodology selected by Levelton during the conduct of the dispersion modelling analysis was then initiated by SENES. Some deficiencies were identified by SENES, despite concurrence with the overall conceptual approach adopted by Levelton. The deficiencies concerned meteorological data; startup, partial load and upset conditions; pollutant emissions; health risk assessment; cumulative impact on ambient particulate matter 10 concentrations; and collateral environmental impacts. refs., 2 tabs., 21 figs

Numerical Analysis of Molten Corium Dispersion during Hypothetical High-Pressure Accidents in APR1400 Nuclear Power Plant

International Nuclear Information System (INIS)

Kim, Jong Tae; Ha, Kwang Soon; Kim, Sang Baik; Kim, Hee Dong; Jeong, Jae Sik

2010-01-01

is not clearly known. During the evaluation of containment integrity by DCH in KNGR (synonym of APR1400), the dispersion correlation developed from experiments for Young-Gang 3 and 4 and Kori-1 cavity geometries was applied in a two-cell equilibrium (TCE) modeling. As can be expected, the benefit of the convolute cavity geometry of APR1400 could not be resolved once the correlation is used. In order to verify that using the correlation for APR1400 is conservative in view of the evaluation of the containment integrity by DCH, corium dispersion in the APR1400 containment was simulated by using MC3D code. The MC3D code is a two-phase analysis code based on Eulerian four-fields for melt jet, melt droplets, water and gas mixture of vapor and noncondensable gas. The dispersion rates of the corium melt depending on the RPV pressure were obtained from the MC3D analyses and the values specific to the APR1400 cavity geometry were compared to the correlation

Solid KHT tumor dispersal for flow cytometric cell kinetic analysis

International Nuclear Information System (INIS)

Pallavicini, M.G.; Folstad, L.J.; Dunbar, C.

1981-01-01

A bacterial neutral protease was used to disperse KHT solid tumors into single cell suspensions suitable for routine cell kinetic analysis by flow cytometry and for clonogenic cell survival. Neutral protease disaggregation under conditions which would be suitable for routine tumor dispersal was compared with a trypsin/DNase procedure. Cell yield, clonogenic cell survival, DNA distributions of untreated and drug-perturbed tumors, rates of radioactive precursor incorporation during the cell cycle, and preferential cell cycle phase-specific cell loss were investigated. Tumors dispersed with neutral protease yielded approximately four times more cells than those dispersed with trypsin/DNase and approximately a 1.5-fold higher plating efficiency in a semisolid agar system. Quantitative analysis of DNA distributions obtained from untreated and cytosine-arabinoside-perturbed tumors produced similar results with both dispersal procedures. The rates of incorporation of tritiated thymidine during the cell cycle were also similar with neutral protease and trypsin/DNase dispersal. Preferential phase-specific cell loss was not obseved with either technique. We find that neutral protease provides good single cell suspensions of the KHT tumor for cell survival measurements and for cell kinetic analysis of drug-induced perturbations by flow cytometry. In addition, the high cell yields facilitate electronic cell sorting where large numbers of cells are often required

Simultaneous derivatisation and preconcentration of parabens in food and other matrices by isobutyl chloroformate and dispersive liquid-liquid microextraction followed by gas chromatographic analysis.

Science.gov (United States)

Jain, Rajeev; Mudiam, Mohana Krishna Reddy; Chauhan, Abhishek; Ch, Ratnasekhar; Murthy, R C; Khan, Haider A

2013-11-01

A simple, rapid and economical method has been proposed for the quantitative determination of parabens (methyl, ethyl, propyl and butyl paraben) in different samples (food, cosmetics and water) based on isobutyl chloroformate (IBCF) derivatisation and preconcentration using dispersive liquid-liquid microextraction in single step. Under optimum conditions, solid samples were extracted with ethanol (disperser solvent) and 200 μL of this extract along with 50 μL of chloroform (extraction solvent) and 10 μL of IBCF was rapidly injected into 2 mL of ultra-pure water containing 150 μL of pyridine to induce formation of a cloudy state. After centrifugation, 1 μL of the sedimented phase was analysed using gas chromatograph-flame ionisation detector (GC-FID) and the peaks were confirmed using gas chromatograph-positive chemical ionisation-mass spectrometer (GC-PCI-MS). Method was found to be linear over the range of 0.1-10 μg mL(-1) with square of correlation coefficient (R(2)) in the range of 0.9913-0.9992. Limit of detection (LOD) and limit of quantification (LOQ) were found to be 0.029-0.102 μg mL(-1) and 0.095-0.336 μg mL(-1) with a signal to noise ratio of 3:1 and 10:1, respectively. Copyright © 2013 Elsevier Ltd. All rights reserved.

Determination of Levetiracetam in Human Plasma by Dispersive Liquid-Liquid Microextraction Followed by Gas Chromatography-Mass Spectrometry

Science.gov (United States)

2016-01-01

Levetiracetam (LEV) is an antiepileptic drug that is clinically effective in generalized and partial epilepsy syndromes. The use of this drug has been increasing in clinical practice and intra- or -interindividual variability has been exhibited for special population. For this reason, bioanalytical methods are required for drug monitoring in biological matrices. So this work presents a dispersive liquid-liquid microextraction method followed by gas chromatography-mass spectrometry (DLLME-GC-MS) for LEV quantification in human plasma. However, due to the matrix complexity a previous purification step is required. Unlike other pretreatment techniques presented in the literature, for the first time, a procedure employing ultrafiltration tubes Amicon® (10 kDa porous size) without organic solvent consumption was developed. GC-MS analyses were carried out using a linear temperature program, capillary fused silica column, and helium as the carrier gas. DLLME optimized parameters were type and volume of extraction and dispersing solvents, salt addition, and vortex agitation time. Under chosen parameters (extraction solvent: chloroform, 130 μL; dispersing solvent: isopropyl alcohol, 400 μL; no salt addition and no vortex agitation time), the method was completely validated and all parameters were in agreement with the literature recommendations. LEV was quantified in patient's plasma sample using less than 550 μL of organic solvent. PMID:27830105

Determination of Levetiracetam in Human Plasma by Dispersive Liquid-Liquid Microextraction Followed by Gas Chromatography-Mass Spectrometry

Directory of Open Access Journals (Sweden)

Greyce Kelly Steinhorst Alcantara

2016-01-01

Full Text Available Levetiracetam (LEV is an antiepileptic drug that is clinically effective in generalized and partial epilepsy syndromes. The use of this drug has been increasing in clinical practice and intra- or -interindividual variability has been exhibited for special population. For this reason, bioanalytical methods are required for drug monitoring in biological matrices. So this work presents a dispersive liquid-liquid microextraction method followed by gas chromatography-mass spectrometry (DLLME-GC-MS for LEV quantification in human plasma. However, due to the matrix complexity a previous purification step is required. Unlike other pretreatment techniques presented in the literature, for the first time, a procedure employing ultrafiltration tubes Amicon® (10 kDa porous size without organic solvent consumption was developed. GC-MS analyses were carried out using a linear temperature program, capillary fused silica column, and helium as the carrier gas. DLLME optimized parameters were type and volume of extraction and dispersing solvents, salt addition, and vortex agitation time. Under chosen parameters (extraction solvent: chloroform, 130 μL; dispersing solvent: isopropyl alcohol, 400 μL; no salt addition and no vortex agitation time, the method was completely validated and all parameters were in agreement with the literature recommendations. LEV was quantified in patient’s plasma sample using less than 550 μL of organic solvent.

A "Greenhouse Gas" Experiment for the Undergraduate Laboratory

Science.gov (United States)

Gomez, Elaine; Paul, Melissa; Como, Charles; Barat, Robert

2014-01-01

This experiment and analysis offer an effective experience in greenhouse gas reduction. Ammoniated water is flowed counter-current to a simulated flue gas of air and CO2 in a packed column. The gaseous CO2 concentrations are measured with an on-line, non- dispersive, infrared analyzer. Column operating parameters include total gas flux, dissolved…

Modeling of corium dispersion in DCH accidents

International Nuclear Information System (INIS)

Wu, Q.

1996-01-01

A model that governs the dispersion process in the direct containment heating (DCH) reactor accident scenario is developed by a stepwise approach. In this model, the whole transient is subdivided into four phases with an isothermal assumption. These are the liquid and gas discharge, the liquid film flow in the cavity before gas blowdown, the liquid and gas flow in the cavity with droplet entrainment, and the liquid transport and re-entrainment in the subcompartment. In each step, the dominant driving mechanisms are identified to construct the governing equations. By combining all the steps together, the corium dispersion information is obtained in detail. The key parameters are predicted quantitatively. These include the fraction of liquid that flows out of the cavity before gas blowdown, the dispersion fraction and the mean droplet diameter in the cavity, the cavity pressure rise due to the liquid friction force, and the dispersion fractions in the containment via different paths. Compared with the data of the 1:10 scale experiments carried out at Purdue University, fairly good agreement is obtained. A stand-alone prediction of the corium dispersion under prototypic Zion reactor conditions is carried out by assuming an isothermal process without chemical reactions. (orig.)

Energy Dispersive Spectrometry and Quantitative Analysis Short Course. Introduction to X-ray Energy Dispersive Spectrometry and Quantitative Analysis

Science.gov (United States)

Carpenter, Paul; Curreri, Peter A. (Technical Monitor)

2002-01-01

This course will cover practical applications of the energy-dispersive spectrometer (EDS) to x-ray microanalysis. Topics covered will include detector technology, advances in pulse processing, resolution and performance monitoring, detector modeling, peak deconvolution and fitting, qualitative and quantitative analysis, compositional mapping, and standards. An emphasis will be placed on use of the EDS for quantitative analysis, with discussion of typical problems encountered in the analysis of a wide range of materials and sample geometries.

Dispersion analysis for waves propagated in fractured media

Energy Technology Data Exchange (ETDEWEB)

Lesniak, A; Niitsuma, H [Tohoku University, Sendai (Japan). Faculty of Engineering

1996-05-01

Dispersion of velocity is defined as a variation of the phase velocity with frequency. This paper describes the dispersion analysis of compressional body waves propagated in the heterogeneous fractured media. The new method proposed and discussed here permitted the evaluation of the variation in P wave arrival with frequency. For this processing method, any information about the attenuation of the medium are not required, and only an assumption of weak heterogeneity is important. It was shown that different mechanisms of dispersion can be distinguished and its value can be quantitatively estimated. Although the frequency used in this study was lower than those in most previous experiments reported in literature, the evaluated dispersion was large. It was suggested that such a large dispersion may be caused by the velocity structure of the media studied and by frequency dependent processes in a highly fractured zone. It was demonstrated that the present method can be used in the evaluation of subsurface fracture systems or characterization of any kind of heterogeneities. 10 refs., 6 figs.

Atmospheric dispersion prediction and source estimation of hazardous gas using artificial neural network, particle swarm optimization and expectation maximization

Science.gov (United States)

Qiu, Sihang; Chen, Bin; Wang, Rongxiao; Zhu, Zhengqiu; Wang, Yuan; Qiu, Xiaogang

2018-04-01

Hazardous gas leak accident has posed a potential threat to human beings. Predicting atmospheric dispersion and estimating its source become increasingly important in emergency management. Current dispersion prediction and source estimation models cannot satisfy the requirement of emergency management because they are not equipped with high efficiency and accuracy at the same time. In this paper, we develop a fast and accurate dispersion prediction and source estimation method based on artificial neural network (ANN), particle swarm optimization (PSO) and expectation maximization (EM). The novel method uses a large amount of pre-determined scenarios to train the ANN for dispersion prediction, so that the ANN can predict concentration distribution accurately and efficiently. PSO and EM are applied for estimating the source parameters, which can effectively accelerate the process of convergence. The method is verified by the Indianapolis field study with a SF6 release source. The results demonstrate the effectiveness of the method.

Research Note: Energy dispersive x-ray fluorescence analysis ...

African Journals Online (AJOL)

Energy Dispersive X-Ray fluorescence (EDXRF) technique for the analysis of geological, biological and environmental samples is described. The technique has been applied in the analysis of 10 (geological, biological, environmental) standard reference materials. The accuracy and precision of the technique were attested ...

Dispersion analysis of spaced antenna scintillation measurement

Directory of Open Access Journals (Sweden)

M. Grzesiak

2009-07-01

Full Text Available We present a dispersion analysis of the phase of GPS signals received at high latitude. Basic theoretical aspects for spectral analysis of two-point measurement are given. To account for nonstationarity and statistical robustness a power distribution of the windowed Fourier transform cross-spectra as a function of frequency and phase is analysed using the Radon transform.

Strongly coupled dispersed two-phase flows; Ecoulements diphasiques disperses fortement couples

Energy Technology Data Exchange (ETDEWEB)

Zun, I.; Lance, M.; Ekiel-Jezewska, M.L.; Petrosyan, A.; Lecoq, N.; Anthore, R.; Bostel, F.; Feuillebois, F.; Nott, P.; Zenit, R.; Hunt, M.L.; Brennen, C.E.; Campbell, C.S.; Tong, P.; Lei, X.; Ackerson, B.J.; Asmolov, E.S.; Abade, G.; da Cunha, F.R.; Lhuillier, D.; Cartellier, A.; Ruzicka, M.C.; Drahos, J.; Thomas, N.H.; Talini, L.; Leblond, J.; Leshansky, A.M.; Lavrenteva, O.M.; Nir, A.; Teshukov, V.; Risso, F.; Ellinsen, K.; Crispel, S.; Dahlkild, A.; Vynnycky, M.; Davila, J.; Matas, J.P.; Guazelli, L.; Morris, J.; Ooms, G.; Poelma, C.; van Wijngaarden, L.; de Vries, A.; Elghobashi, S.; Huilier, D.; Peirano, E.; Minier, J.P.; Gavrilyuk, S.; Saurel, R.; Kashinsky, O.; Randin, V.; Colin, C.; Larue de Tournemine, A.; Roig, V.; Suzanne, C.; Bounhoure, C.; Brunet, Y.; Tanaka, A.T.; Noma, K.; Tsuji, Y.; Pascal-Ribot, S.; Le Gall, F.; Aliseda, A.; Hainaux, F.; Lasheras, J.; Didwania, A.; Costa, A.; Vallerin, W.; Mudde, R.F.; Van Den Akker, H.E.A.; Jaumouillie, P.; Larrarte, F.; Burgisser, A.; Bergantz, G.; Necker, F.; Hartel, C.; Kleiser, L.; Meiburg, E.; Michallet, H.; Mory, M.; Hutter, M.; Markov, A.A.; Dumoulin, F.X.; Suard, S.; Borghi, R.; Hong, M.; Hopfinger, E.; Laforgia, A.; Lawrence, C.J.; Hewitt, G.F.; Osiptsov, A.N.; Tsirkunov, Yu. M.; Volkov, A.N.

2003-07-01

-phase flow, current distribution and mass transfer along a vertical gas evolving electrode; a two-way coupled model for dilute multiphase flows. Topic 3: turbulence modulation by particles, droplets or bubbles in dense systems: influence of particles on the transition to turbulence in pipe flow; comparison between a point particle model and a finite-diameter-model for the particle turbulence interaction in a suspension; the effect on turbulence by bubbles rising through it under buoyancy; the physical mechanisms of modifying the structure of turbulent homogeneous shear flows by dispersed particles; influence of hydrodynamic interactions between particles on the turbulent flow in a suspension; review of relationships between Lagrangian and Eulerian scales; a two-point PDF for modelling turbulent dispersed two-phase flows and derivation of a two field model; mathematical and numerical modeling of two-phase compressible flows with micro-inertia. Topic 4: collective effects in dispersed two-phase flows clustering and phase distribution: hydrodynamic structure of downward bubbly flow; influence of gravity on the dynamics of a turbulent bubbly pipe flow; experimental study of two-phase flows; particle clusters formed in dispersed gas-solid flows: simulations and experiments; experimental study of the turbulence in bubbly flows at high void fraction; first step in the study of the correlation between air/water flow fluctuations and random buffering forces; clustering and settling velocity of micro-droplets in a grid turbulence. Topic 5: large scale instabilities and gravity driven dispersed flows: new 'non-isothermal' linear instability modes in fluidized beds and bubbly flows; large scale instability in a confined buoyant shear layer; convective instability in uniform dispersed layers; structures in gravity driven bubbly flows; effects of concentration profiles on velocity profiles in sewer; pyroclastic density currents viewed as mammoth scale two-phase flows; mixing and

Gas hydrates forming and decomposition conditions analysis

Directory of Open Access Journals (Sweden)

А. М. Павленко

2017-07-01

Full Text Available The concept of gas hydrates has been defined; their brief description has been given; factors that affect the formation and decomposition of the hydrates have been reported; their distribution, structure and thermodynamic conditions determining the gas hydrates formation disposition in gas pipelines have been considered. Advantages and disadvantages of the known methods for removing gas hydrate plugs in the pipeline have been analyzed, the necessity of their further studies has been proved. In addition to the negative impact on the process of gas extraction, the hydrates properties make it possible to outline the following possible fields of their industrial use: obtaining ultrahigh pressures in confined spaces at the hydrate decomposition; separating hydrocarbon mixtures by successive transfer of individual components through the hydrate given the mode; obtaining cold due to heat absorption at the hydrate decomposition; elimination of the open gas fountain by means of hydrate plugs in the bore hole of the gushing gasser; seawater desalination, based on the hydrate ability to only bind water molecules into the solid state; wastewater purification; gas storage in the hydrate state; dispersion of high temperature fog and clouds by means of hydrates; water-hydrates emulsion injection into the productive strata to raise the oil recovery factor; obtaining cold in the gas processing to cool the gas, etc.

[Recent advances in analysis of petroleum geological samples by comprehensive two-dimensional gas chromatography].

Science.gov (United States)

Gao, Xuanbo; Chang, Zhenyang; Dai, Wei; Tong, Ting; Zhang, Wanfeng; He, Sheng; Zhu, Shukui

2014-10-01

Abundant geochemical information can be acquired by analyzing the chemical compositions of petroleum geological samples. The information obtained from the analysis provides scientifical evidences for petroleum exploration. However, these samples are complicated and can be easily influenced by physical (e. g. evaporation, emulsification, natural dispersion, dissolution and sorption), chemical (photodegradation) and biological (mainly microbial degradation) weathering processes. Therefore, it is very difficult to analyze the petroleum geological samples and they cannot be effectively separated by traditional gas chromatography/mass spectrometry. A newly developed separation technique, comprehensive two-dimensional gas chromatography (GC x GC), has unique advantages in complex sample analysis, and recently it has been applied to petroleum geological samples. This article mainly reviews the research progres- ses in the last five years, the main problems and the future research about GC x GC applied in the area of petroleum geology.

Correlation between arterial blood gas analysis and peripheral blood gas analysis in acid-base unbalance state

Directory of Open Access Journals (Sweden)

Hyun Lee Kim

2012-06-01

Full Text Available Acid-base unbalance is most common problem in severe ill patient, especially in condition of abnormal renal function state. Acid-base unbalances are respiratory acidosis, respiratory alkalosis, metabolic acidosis, and metabolic alkalosis. Metabolic acidosis is frequently appeared in clinical state. Arterial blood gas analysis is considered as a basic test to the intensive care unit patient and emergency state. Recently some researches were done, comparing with arterial blood gas analysis and venous blood gas analysis. Because of venous blood sampling is safer than arterial blood gas analysis, and beside not so different among them for detecting pH, pCO2, HCO3, except pO2 measuring. This research was done in emergency room, and for explaining no different between arterial blood gas analysis and peripheral blood gas analysis result in acid-base unbalance state patient. Especially in kidney functions decreased state. : The study was done from March, 2010 to January, 2011. The object was 89 peoples who came to emergency room for treating internal medicine problem. (Women 53, average age: 66.7±12.1 Then compare between arterial blood gas analysis and peripheral blood gas analysis. Result: The mean arterial minus venous difference for pH, pCO2, and bicarbonate was −0.0170, 2.6528, and 0.6124. Bland-Altman plot was done for predicting agreement of two groups, and the scale was pH −2.95 to 4.17, pCO2 −4.45 to 9.76, bicarbonate −2.95 to 4.16, in 95% relative. Conclusion: The peripheral blood gas pH, pCO2, bicarbonate level is almost same as arterial blood gas analysis results. And enough to measuring acid-base unbalance state, in absent of arterial blood testing.

Effect of palladium dispersion on the capture of toxic components from fuel gas by palladium-alumina sorbents

Energy Technology Data Exchange (ETDEWEB)

John P. Baltrus; Evan J. Granite; Erik C. Rupp; Dennis C. Stanko; Bret Howard; Henry W. Pennline [US DOE National Energy Technology Laboratory, Pittsburgh, PA (United States)

2011-05-15

The dispersion and location of Pd in alumina-supported sorbents prepared by different methods was found to influence the performance of the sorbents in the removal of mercury, arsine, and hydrogen selenide from a simulated fuel gas. When Pd is well dispersed in the pores of the support, contact interaction with the support is maximized, Pd is less susceptible to poisoning by sulfur, and the sorbent has better long-term activity for adsorption of arsine and hydrogen selenide, but poorer adsorption capacity for Hg. As the contact interaction between Pd and the support is lessened the Pd becomes more susceptible to poisoning by sulfur, resulting in higher capacity for Hg, but poorer long-term performance for adsorption of arsenic and selenium. 18 refs., 3 figs., 4 tabs.

The influence of the dispersion corrections on the performance of DFT method in modeling HNgY noble gas molecules and their complexes

Science.gov (United States)

Cukras, Janusz; Sadlej, Joanna

2018-01-01

The letter reports a comparative assessment of the usefulness of the two different Grimme's corrections for evaluating dispersion interaction (DFT-D3 and DFT-D3BJ) for the representative molecules of the family of noble-gas hydrides HXeY and their complexes with the HZ molecules, where Y and Z are F/Cl/OH/SH. with special regard to the dispersion term calculated by means of the symmetry-adapted perturbation theory (at the SAPT0 level). The results indicate that despite differences in the total interactions energy (DFT + corrections) versus SAPT0 results, the sequence of contributions of the individual dispersion terms is still maintained. Both dispersion corrections perform similarly and they improve the results suggesting that it is worthwhile to include them in calculations.

Determination of valproic acid in human plasma using dispersive liquid-liquid microextraction followed by gas chromatography-flame ionization detection

Science.gov (United States)

Fazeli-Bakhtiyari, Rana; Panahi-Azar, Vahid; Sorouraddin, Mohammad Hossein; Jouyban, Abolghasem

2015-01-01

Objective(s): Dispersive liquid-liquid microextraction coupled with gas chromatography (GC)-flame ionization detector was developed for the determination of valproic acid (VPA) in human plasma. Materials and Methods: Using a syringe, a mixture of suitable extraction solvent (40 µl chloroform) and disperser (1 ml acetone) was quickly added to 10 ml of diluted plasma sample containing VPA (pH, 1.0; concentration of NaCl, 4% (w/v)), resulting in a cloudy solution. After centrifugation (6000 rpm for 6 min), an aliquot (1 µl) of the sedimented organic phase was removed using a 1-µl GC microsyringe and injected into the GC system for analysis. One variable at a time optimization method was used to study various parameters affecting the extraction efficiency of target analyte. Then, the developed method was fully validated for its accuracy, precision, recovery, stability, and robustness. Results: Under the optimum extraction conditions, good linearity range was obtained for the calibration graph, with correlation coefficient higher than 0.998. Limit of detection and lower limit of quantitation were 3.2 and 6 μg/ml, respectively. The relative standard deviations of intra and inter-day analysis of examined compound were less than 11.5%. The relative recoveries were found in the range of 97 to 107.5%. Finally, the validated method was successfully applied to the analysis of VPA in patient sample. Conclusion: The presented method has acceptable levels of precision, accuracy and relative recovery and could be used for therapeutic drug monitoring of VPA in human plasma. PMID:26730332

Effect of Additional Structure on Effective Stack Height of Gas Dispersion in Atmosphere

Directory of Open Access Journals (Sweden)

Takenobu Michioka

2016-03-01

Full Text Available Wind-tunnel experiments were conducted to evaluate the effect of additional structure (building, sea wall and banking on the effective stack height, which is usually used in safety analyses of nuclear power facilities in Japan. The effective stack heights were estimated with and without the additional structure in addition to the reactor building while varying several conditions such as the source height, the height of additional structure and the distance between the source position and the additional structure. When the source height is equivalent to the reactor building height, the additional structure enhances both the vertical and horizontal gas dispersion widths and decreases the ground gas concentration, and it means that the additional structure does not decrease the effective stack height. When the source height is larger than the reactor height, the additional structures might affect the effective stack height. As the distance between the source and the additional structure decreases, or as the height of the additional structure increases, the structure has a larger effect on the effective stack height.

A new optical rotation dispersion formula

International Nuclear Information System (INIS)

Kimel, I.

1981-12-01

A new dispersion formula for the rotatory power is obtained in the framework of Kubo forlalism for transport coefficients. Unlike the well known Rosenfeld-Condon dispersion law, this formula is consistent with the free electron gas asymptotic behavior. (Author) [pt

Quenching of Particle-Gas Combustible Mixtures Using Electric Particulate Suspension (EPS) and Dispersion Methods

Science.gov (United States)

Colver, Gerald M.; Goroshin, Samuel; Lee, John H. S.

2001-01-01

A cooperative study is being carried out between Iowa State University and McGill University. The new study concerns wall and particle quenching effects in particle-gas mixtures. The primary objective is to measure and interpret flame quenching distances, flammability limits, and burning velocities in particulate suspensions. A secondary objective is to measure particle slip velocities and particle velocity distribution as these influence flame propagation. Two suspension techniques will be utilized and compared: (1) electric particle suspension/EPS; and (2) flow dispersion. Microgravity tests will permit testing of larger particles and higher and more uniform dust concentrations than is possible in normal gravity.

The mechanism of strong electric field effect on the dispersed media in the rarefied gas

International Nuclear Information System (INIS)

Gagarin, A.G.; Savchenko, Y.N.; Vigdonchik, V.H.

1985-01-01

This paper discusses two approaches to the description of the flow of fluids and gases, that is, a phenomenological method and a molecular-kinetic method. Four dispersed admixtures are described using the model of solid spheres as for molecules and a system of aerodynamic equations is obtained. In this system interactions between gas molecules and admixtures are taken into consideration already in the zero approximation. The paper is also concerned with the experimental study of the motion of dispersed particles in corona discharge which is a typical example of a strong nonuniform electric field with a volume discharge. From the comparison of experimental and calculated paths it was found that the particles move five to seven times faster than they would have done under the action of the Coulomb force alone at a real amount of charge of the particle. The result of comparison also shows that their motion primarily depends on the jet flow of electric wind

Modelling of Dispersed Gas-Liquid Flow using LBGK and LPT Approach

Science.gov (United States)

Agarwal, Alankar; Prakash, Akshay; Ravindra, B.

2017-11-01

The dynamics of gas bubbles play a significant, if not crucial, role in a large variety of industrial process that involves using reactors. Many of these processes are still not well understood in terms of optimal scale-up strategies.An accurate modeling of bubbles and bubble swarms become important for high fidelity bioreactor simulations. This study is a part of the development of robust bubble fluid interaction modules for simulation of industrial-scale reactors. The work presents the simulation of a single bubble rising in a quiescent water tank using current models presented in the literature for bubble-fluid interaction. In this multiphase benchmark problem, the continuous phase (water) is discretized using the Lattice Bhatnagar-Gross and Krook (LBGK) model of Lattice Boltzmann Method (LBM), while the dispersed gas phase (i.e. air-bubble) modeled with the Lagrangian particle tracking (LPT) approach. The cheap clipped fourth order polynomial function is used to model the interaction between two phases. The model is validated by comparing the simulation results for terminal velocity of a bubble at varying bubble diameter and the influence of bubble motion in liquid velocity with the theoretical and previously available experimental data. This work is supported by the ``Centre for Development of Advanced Computing (C-DAC), Pune'' by providing the advanced computational facility in PARAM Yuva-II.

Axial dispersion, holdup and slip velocity of dispersed phase in a pulsed sieve plate extraction column by radiotracer residence time distribution analysis.

Science.gov (United States)

Din, Ghiyas Ud; Chughtai, Imran Rafiq; Inayat, Mansoor Hameed; Khan, Iqbal Hussain

2008-12-01

Axial dispersion, holdup and slip velocity of dispersed phase have been investigated for a range of dispersed and continuous phase superficial velocities in a pulsed sieve plate extraction column using radiotracer residence time distribution (RTD) analysis. Axial dispersion model (ADM) was used to simulate the hydrodynamics of the system. It has been observed that increase in dispersed phase superficial velocity results in a decrease in its axial dispersion and increase in its slip velocity while its holdup increases till a maximum asymptotic value is achieved. An increase in superficial velocity of continuous phase increases the axial dispersion and holdup of dispersed phase until a maximum value is obtained, while slip velocity of dispersed phase is found to decrease in the beginning and then it increases with increase in superficial velocity of continuous phase.

A non-dispersive infrared analyser for analysis of HF in the PPM range

International Nuclear Information System (INIS)

Kartha, V.B.; Patel, N.D.; Venkateswaran, S.

1985-01-01

The determination of trace amounts of HF is of importance in many industrial processes, and in nuclear industry in the production of UF 6 . Mass spectrometric and gas chromatographic methods are difficult to use for this purpose, because of the highly corrosive nature of the samples. Infrared Spectroscopy can be conveniently used with the required sensitivity and it has the added advantage that continuous non-destructive on-line monitoring can be conveniently done. A non-dispersive infrared analyser for determination of HF in UF 6 in the concentration range of 50-2000 ppm has been fabricated and tested. The instrument has been shown to possess high sensitivity and good long term stability, so that it can be used as on-line monitor for non-destructive, continuous analysis. (author)

Taylor Dispersion Analysis as a promising tool for assessment of peptide-peptide interactions.

Science.gov (United States)

Høgstedt, Ulrich B; Schwach, Grégoire; van de Weert, Marco; Østergaard, Jesper

2016-10-10

Protein-protein and peptide-peptide (self-)interactions are of key importance in understanding the physiochemical behavior of proteins and peptides in solution. However, due to the small size of peptide molecules, characterization of these interactions is more challenging than for proteins. In this work, we show that protein-protein and peptide-peptide interactions can advantageously be investigated by measurement of the diffusion coefficient using Taylor Dispersion Analysis. Through comparison to Dynamic Light Scattering it was shown that Taylor Dispersion Analysis is well suited for the characterization of protein-protein interactions of solutions of α-lactalbumin and human serum albumin. The peptide-peptide interactions of three selected peptides were then investigated in a concentration range spanning from 0.5mg/ml up to 80mg/ml using Taylor Dispersion Analysis. The peptide-peptide interactions determination indicated that multibody interactions significantly affect the PPIs at concentration levels above 25mg/ml for the two charged peptides. Relative viscosity measurements, performed using the capillary based setup applied for Taylor Dispersion Analysis, showed that the viscosity of the peptide solutions increased with concentration. Our results indicate that a viscosity difference between run buffer and sample in Taylor Dispersion Analysis may result in overestimation of the measured diffusion coefficient. Thus, Taylor Dispersion Analysis provides a practical, but as yet primarily qualitative, approach to assessment of the colloidal stability of both peptide and protein formulations. Copyright © 2016 Elsevier B.V. All rights reserved.

The effect of a micro bubble dispersed gas phase on hydrogen isotope transport in liquid metals under nuclear irradiation

Energy Technology Data Exchange (ETDEWEB)

Fradera, J., E-mail: jfradera@ubu.es; Cuesta-López, S., E-mail: scuesta@ubu.es

2013-12-15

The present work intend to be a first step towards the understanding and quantification of the hydrogen isotope complex phenomena in liquid metals for nuclear technology. Liquid metals under nuclear irradiation in, e.g., breeding blankets of a nuclear fusion reactor would generate tritium which is to be extracted and recirculated as fuel. At the same time that tritium is bred, helium is also generated and may precipitate in the form of nano bubbles. Other liquid metal systems of a nuclear reactor involve hydrogen isotope absorption processes, e.g., tritium extraction system. Hence, hydrogen isotope absorption into gas bubbles modelling and control may have a capital importance regarding design, operation and safety. Here general models for hydrogen isotopes transport in liquid metal and absorption into gas phase, that do not depend on the mass transfer limiting regime, are exposed and implemented in OpenFOAM® CFD tool for 0D–3D simulations. Results for a 0D case show the impact of a He dispersed phase of nano bubbles on hydrogen isotopes inventory at different temperatures as well as the inventory evolution during a He nucleation event. In addition, 1D and 2D axisymmetric cases are exposed showing the effect of a He dispersed gas phase on hydrogen isotope permeation through a lithium lead eutectic alloy and the effect of vortical structures on hydrogen isotope transport at a backward facing step. Exposed results give a valuable insight on current nuclear technology regarding the importance of controlling hydrogen isotope transport and its interactions with nucleation event through gas absorption processes.

Coupling of WRF and Building-resolved CFD Simulations for Greenhouse Gas Transport and Dispersion

Science.gov (United States)

Prasad, K.; Hu, H.; McDermott, R.; Lopez-Coto, I.; Davis, K. J.; Whetstone, J. R.; Lauvaux, T.

2014-12-01

The Indianapolis Flux Experiment (INFLUX) aims to use a top-down inversion methodology to quantify sources of Greenhouse Gas (GHG) emissions over an urban domain with high spatial and temporal resolution. Atmospheric transport of tracer gases from an emission source to a tower mounted receptor are usually conducted using the Weather Research and Forecasting (WRF) model. WRF is used extensively in the atmospheric community to simulate mesoscale atmospheric transport. For such simulations, WRF employs a parameterized turbulence model and does not resolve the fine scale dynamics that are generated by the flow around buildings and communities that are part of a large city. Since the model domain includes the city of Indianapolis, much of the flow of interest is over an urban topography. The NIST Fire Dynamics Simulator (FDS) is a computational fluid dynamics model to perform large eddy simulations of flow around buildings, but it has not been nested within a larger-scale atmospheric transport model such as WRF. FDS has the potential to evaluate the impact of complex urban topography on near-field dispersion and mixing that cannot be simulated with a mesoscale atmospheric model, and which may be important to determining urban GHG emissions using atmospheric measurements. A methodology has been developed to run FDS as a sub-grid scale model within a WRF simulation. The coupling is based on nudging the FDS flow field towards the one computed by WRF, and is currently limited to one way coupling performed in an off-line mode. Using the coupled WRF / FDS model, NIST will investigate the effects of the urban canopy at horizontal resolutions of 2-10 m. The coupled WRF-FDS simulations will be used to calculate the dispersion of tracer gases in an urban domain and to evaluate the upwind areas that contribute to tower observations, referred to in the inversion community as influence functions. Predicted mixing ratios will be compared with tower measurements and WRF simulations

Trends in the analysis of natural gas by capillary gas chromatography

NARCIS (Netherlands)

Cramers, C.A.M.G.; Rossum, van G.J.

1986-01-01

The importance of correct determination of physical and chemical properties of natural gas is evident. The calculation of calorific value or hydrocarbon dew point requires detailed analysis as can be provided by gas chromatography. Analysis by gas chromatography is a necessary complement to direct

Conditions for the formation and atmospheric dispersion of a toxic, heavy gas layer during thermal metamorphism of coal and evaporite deposits by sill intrusion

Science.gov (United States)

Storey, Michael; Hankin, Robin K. S.

2010-05-01

There is compelling evidence for massive discharge of volatiles, including toxic species, into the atmosphere at the end of the Permian. It has been argued that most of the gases were produced during thermal metamorphism of coal and evaporite deposits in the East Siberia Tunguska basin following sill intrusion (Retallack and Jahren, 2008; Svensen et al., 2009). The release of the volatiles has been proposed as a major cause of environmental and extinction events at the end of the Permian, with venting of carbon gases and halocarbons to the atmosphere leading to global warming and atmospheric ozone depletion (Svensen et al., 2009) Here we consider the conditions required for the formation and dispersion of toxic, heavier than air, gas plumes, made up of a mixture of CO2, CH4, H2S and SO2 and formed during the thermal metamorphism of C- and S- rich sediments. Dispersion models and density considerations within a range of CO2/CH4 ratios and volatile fluxes and temperatures, for gas discharge by both seepage and from vents, allow the possibility that following sill emplacement much of the vast East Siberia Tunguska basin was - at least intermittently - covered by a heavy, toxic gas layer that was unfavorable for life. Dispersion scenarios for a heavy gas layer beyond the Siberian region during end-Permian times will be presented. REFERENCES G. J. Retallack and A. H. Jahren, Methane release from igneous intrusion of coal during Late Permian extinction events, Journal of Geology, volume 116, 1-20, 2008 H. Svensen et al., Siberian gas venting and the end-Permian environmental crisis, Earth and Planetary Science Letters, volume 277, 490-500, 2009

Excitation methods for energy dispersive analysis

International Nuclear Information System (INIS)

Jaklevic, J.M.

1976-01-01

The rapid development in recent years of energy dispersive x-ray fluorescence analysis has been based primarily on improvements in semiconductor detector x-ray spectrometers. However, the whole analysis system performance is critically dependent on the availability of optimum methods of excitation for the characteristic x rays in specimens. A number of analysis facilities based on various methods of excitation have been developed over the past few years. A discussion is given of the features of various excitation methods including charged particles, monochromatic photons, and broad-energy band photons. The effects of the excitation method on background and sensitivity are discussed from both theoretical and experimental viewpoints. Recent developments such as pulsed excitation and polarized photons are also discussed

Determination of Parabens by Injection-Port Derivatization Coupled With Gas-Chromatography-Mass Spectrometry and Matrix Solid Phase Dispersion

Science.gov (United States)

Djatmika, Rosalina; Ding, Wang-Hsien; Sulistyarti, Hermin

2018-01-01

A rapid determination of four parabens preservatives (methyl paraben, ethyl paraben, propyl paraben, and butyl paraben) in marketed seafood is presented. Analytes were extracted and purified using matrix solid-phase dispersion (MSPD) method, followed by Injection port acylation gas chromatography-mass spectrometry (GC-MS) with acetic anhydride reagent. In this method, acylation of parabens was performed by acetic anhydride at GC injection-port generating reduction of the time-consuming sample-processing steps, and the amount of toxic reagents and solvents. The parameters affecting this method such as injection port temperature, purge-off time and acylation (acetic anhydride) volume were studied. In addition, the MSPD influence factors (including the amount of dispersant and clean-up co-sorbent, as well as the volume of elution solvent) were also investigated. After MSPD method and Injection port acylation applied, good linearity of analytes was achieved. The limits of quantitation (LOQs) were 0.2 to 1.0 ng/g (dry weight). Compared with offline derivatization commonly performed, injection port acylation employs a rapid, simple, low-cost and environmental-friendly derivatization process. The optimized method has been successfully applied for the analysis of parabens in four kind of marketed seafood. Preliminary results showed that the total concentrations of four selected parabens ranged from 16.7 to 44.7 ng/g (dry weight).

Determination of organophosphorus pesticides by dispersive liquid-liquid micro extraction coupled with gas chromatography-electron capture detection

International Nuclear Information System (INIS)

Mohd Marsin Sanagi; Siti Umairah Mokhtar; Mazidatul Akmam Miskam; Wan Aini Wan Ibrahim

2011-01-01

A simple, rapid and sensitive method termed as dispersive liquid-liquid micro extraction (DLLME) combined with gas chromatography-electron capture detector (GC-ECD) was developed for the determination of selected organophosphorus pesticides (OPPs) namely chloropyrifos, dimethoate and diazinon in water sample. In this method, a mixture of carbon disulfide, CS 2 (extraction solvent) and methanol (disperser solvent) was rapidly injected using syringe into the 5.00 mL water sample to form a cloudy solution where the OPPs were extracted into the fine droplets of extraction solvent. Upon centrifugation for 3 min at 3500 rpm, the fine droplets were sedimented at the bottom of the centrifuge tube. Sedimented phase (1 μL) was injected into the GC-ECD for separation and determination of OPPs. Important extraction parameters, such as type of disperser solvent, volume of extraction solvent and volume of disperser solvent were investigated. The optimized conditions for DLLME of the selected OPPs were methanol as disperser solvent, 30 μL of extraction solvent (CS 2 ) and 1.0 mL of disperser solvent (methanol). Under the optimum extraction conditions, the method showed good linearity in the range of 0.1 to 1.0 μg/ mL with correlation coefficient (r 2 ), in the range of 0.9976 to 0.9994 and low limits of detection (LOD) between 0.047 and 0.201 μg/ mL. The proposed method provided acceptable recoveries (72.67- 144 %) with good RSDs ranging from 2.74 % to 7.48 %. This method was successfully applied to the determination of OPPs in water samples obtained from a golf course and chloropyrifos and diazinon were detected at concentration 0.18 μg/ mL and 0.07 μg/ mL, respectively. (author)

Comparison of Dorris-Gray and Schultz methods for the calculation of surface dispersive free energy by inverse gas chromatography.

Science.gov (United States)

Shi, Baoli; Wang, Yue; Jia, Lina

2011-02-11

Inverse gas chromatography (IGC) is an important technique for the characterization of surface properties of solid materials. A standard method of surface characterization is that the surface dispersive free energy of the solid stationary phase is firstly determined by using a series of linear alkane liquids as molecular probes, and then the acid-base parameters are calculated from the dispersive parameters. However, for the calculation of surface dispersive free energy, generally, two different methods are used, which are Dorris-Gray method and Schultz method. In this paper, the results calculated from Dorris-Gray method and Schultz method are compared through calculating their ratio with their basic equations and parameters. It can be concluded that the dispersive parameters calculated with Dorris-Gray method will always be larger than the data calculated with Schultz method. When the measuring temperature increases, the ratio increases large. Compared with the parameters in solvents handbook, it seems that the traditional surface free energy parameters of n-alkanes listed in the papers using Schultz method are not enough accurate, which can be proved with a published IGC experimental result. © 2010 Elsevier B.V. All rights reserved.

The application of a microstrip gas counter to energy-dispersive x-ray fluorescence analysis

International Nuclear Information System (INIS)

Veloso, J.F.C.A.; Santos, J.M.F. dos; Conde, C.A.N.

1996-01-01

Performance characteristics of a microstrip gas counter operated as a x-ray fluorescence spectrometer are reported. Gas amplification as a function of microstrip anode-cathode voltage was measured, and the breakdown threshold voltage was determined in pure xenon. The detector temporal stability and the effect of gas purity were assessed. Energy resolution and linearity, detection efficiency, and uniformity of spatial response in the 2- to 60-keV x-ray energy range were determined from the pulse-height distributions of the fluorescence x-ray spectra induced in a variety of single- and multi-element sample materials. Energy resolution similar to conventional proportional counters was achieved at 6 keV

Electron probe micro-analysis of gas bubbles in solids: a novel approach

International Nuclear Information System (INIS)

Verwerft, M.; Vos, B.

1999-01-01

The local analysis of retained noble gas in nuclear fuel is inherently difficult since the physical form under which it is stored varies from atomically dispersed to bubbles with a diameter of several hundreds of nanometers. One of the techniques that has been applied since pore than twenty years is EPMA. Although many important results have been obtained with this technique, its application to the analysis of highly inhomogeneous materials is limited. The EPMA technique is indeed difficult to apply to samples that are not homogeneous on the scale of the electron-solid interaction volume. The paper discusses the development of a method to analyse a system of as bubbles distributed in a solid matrix. This method has been based on a multiple voltage EPMA measurement combined with a scanning Electron Microscopic analysis of the bubble size distribution

Building-Resolved CFD Simulations for Greenhouse Gas Transport and Dispersion over Washington DC / Baltimore

Science.gov (United States)

Prasad, K.; Lopez-Coto, I.; Ghosh, S.; Mueller, K.; Whetstone, J. R.

2015-12-01

The North-East Corridor project aims to use a top-down inversion methodology to quantify sources of Greenhouse Gas (GHG) emissions over urban domains such as Washington DC / Baltimore with high spatial and temporal resolution. Atmospheric transport of tracer gases from an emission source to a tower mounted receptor are usually conducted using the Weather Research and Forecasting (WRF) model. For such simulations, WRF employs a parameterized turbulence model and does not resolve the fine scale dynamics generated by the flow around buildings and communities comprising a large city. The NIST Fire Dynamics Simulator (FDS) is a computational fluid dynamics model that utilizes large eddy simulation methods to model flow around buildings at length scales much smaller than is practical with WRF. FDS has the potential to evaluate the impact of complex urban topography on near-field dispersion and mixing difficult to simulate with a mesoscale atmospheric model. Such capabilities may be important in determining urban GHG emissions using atmospheric measurements. A methodology has been developed to run FDS as a sub-grid scale model within a WRF simulation. The coupling is based on nudging the FDS flow field towards that computed by WRF, and is currently limited to one way coupling performed in an off-line mode. Using the coupled WRF / FDS model, NIST will investigate the effects of the urban canopy at horizontal resolutions of 10-20 m in a domain of 12 x 12 km. The coupled WRF-FDS simulations will be used to calculate the dispersion of tracer gases in the North-East Corridor and to evaluate the upwind areas that contribute to tower observations, referred to in the inversion community as influence functions. Results of this study will provide guidance regarding the importance of explicit simulations of urban atmospheric turbulence in obtaining accurate estimates of greenhouse gas emissions and transport.

Analysis of the physical atomic forces between noble gas atoms, alkali ions and halogen ions

Science.gov (United States)

Wilson, J. W.; Heinbockel, J. H.; Outlaw, R. A.

1986-01-01

The physical forces between atoms and molecules are important in a number of processes of practical importance, including line broadening in radiative processes, gas and crystal properties, adhesion, and thin films. The components of the physical forces between noble gas atoms, alkali ions, and halogen ions are analyzed and a data base for the dispersion forces is developed from the literature based on evaluations with the harmonic oscillator dispersion model for higher order coefficients. The Zener model of the repulsive core is used in the context of the recent asymptotic wave functions of Handler and Smith; and an effective ionization potential within the Handler and Smith wave functions is defined to analyze the two body potential data of Waldman and Gordon, the alkali-halide molecular data, and the noble gas crystal and salt crystal data. A satisfactory global fit to this molecular and crystal data is then reproduced by the model to within several percent. Surface potentials are evaluated for noble gas atoms on noble gas and salt crystal surfaces with surface tension neglected. Within this context, the noble gas surface potentials on noble gas and salt crystals are considered to be accurate to within several percent.

Elementary analysis by means of the x fluorescence and energy dispersion

International Nuclear Information System (INIS)

Jbeli, H.

1988-10-01

Three actualisation reports are shown, in the three first chapters, concerning the following subjects: x fluorescence principle, energy dispersive X ray spectroscopy and excitation spectrum characteristics. The matrice effects, the energy equivalence concept, and the correction methods of the interelement effects, related to a calibration curve, are discussed. For the last ones, it is shown that they are supplied to rough values. Quantitative analysis results are shown. A new possibility has been added to those of data processing program usually applied in quantitative analysis. In the second method applied in quantitative analysis, standard samples are used. In both methods an error appreciation analysis is carried out. It is shown that energy dispersive X fluorescence analysis can be applied to thin layers composition and thickness characterization [fr

Life-cycle analysis of shale gas and natural gas.

Energy Technology Data Exchange (ETDEWEB)

Clark, C.E.; Han, J.; Burnham, A.; Dunn, J.B.; Wang, M. (Energy Systems); ( EVS)

2012-01-27

The technologies and practices that have enabled the recent boom in shale gas production have also brought attention to the environmental impacts of its use. Using the current state of knowledge of the recovery, processing, and distribution of shale gas and conventional natural gas, we have estimated up-to-date, life-cycle greenhouse gas emissions. In addition, we have developed distribution functions for key parameters in each pathway to examine uncertainty and identify data gaps - such as methane emissions from shale gas well completions and conventional natural gas liquid unloadings - that need to be addressed further. Our base case results show that shale gas life-cycle emissions are 6% lower than those of conventional natural gas. However, the range in values for shale and conventional gas overlap, so there is a statistical uncertainty regarding whether shale gas emissions are indeed lower than conventional gas emissions. This life-cycle analysis provides insight into the critical stages in the natural gas industry where emissions occur and where opportunities exist to reduce the greenhouse gas footprint of natural gas.

H15-42: CFD analysis for risk analysis in urban environments - Tilburg city case study

NARCIS (Netherlands)

Hulsbosch-Dam, C.; Mack, A.; Ratingen, S. van; Rosmuller, N.; Trijssenaar, I.

2013-01-01

For risk analysis studies, relatively simple dispersion models are generally applied, such as Gaussian dispersion and dense gas dispersion models. For rail transport risk analyses in the Netherlands, fixed consequence distances are applied for various standard scenarios of hazardous materials

The effect of the computational grid size on the prediction of a flammable cloud dispersion

OpenAIRE

Schleder, Adriana; Martins, Marcelon; Pastor Ferrer, Elsa; Planas Cuchi, Eulàlia

2014-01-01

The consequence analysis is used to define the extent and nature of effects caused by undesired events being of great help when quantifying the damage caused by such events. For the case of leaking of flammable and/or toxic materials, effects are analyzed for explosions, fires and toxicity. Specific models are used to analyze the spills or jets of gas or liquids, gas dispersions, explosions and fires. The central step in the analysis of consequences in such cases is to de...

A galactic disk as a two-fluid system: Consequences for the critical stellar velocity dispersion and the formation of condensations in the gas

International Nuclear Information System (INIS)

Jog, C.J.; Solomon, P.M.

1984-01-01

We examine the consequences of treating a galactic disk as a two-fluid system for the stability of the entire disk and for the stability and form of the gas in the disk. We find that the existence of even a small fraction of the total disk surface density in a cold fluid (that is, the gas) makes it much harder to stabilize the entire two-fluid disk. (C/sub s/,min)/sub 2-f/, the critical stellar velocity dispersion for a two-fluid disk in an increasing function of μ/sub g//μ/sub s/, the gas fraction, and μ/sub t//kappa, where μ/sub g/, μ/sub s/, and μ/sub t/ are the gaseous, stellar, and total disk surface densities and kappa is the epicyclic frequency. In the Galaxy, we find that (C/sub s/,min)/sub 2-f/ as a function of R peaks when μ/sub t//kappa peaks-at galactocentric radii of Rapprox.5-7 kpc; two-fluid instabilities are most likely to occur in this region. This region is coincident with the peak in the molecular cloud distribution in the Galaxy. At the higher effective gas density resulting from the growth of a two-fluid instability, the gas may become unstble, even when originally the gas by itself is stable. The wavelength of a typical (induced) gas instability in the inner galaxy is approx.400 pc, and it contains approx.10 7 M/sub sun/ of interstellar matter; these instabilities may be identified with clusters of giant molecular clouds. We suggest that many of the spiral features seen in gas-rich spiral galaxies may be material arms or arm segments resulting from sheared two-fluid gravitational instabilities. The analysis presented here is applicable to any general disk galaxy consisting of stars and gas

Thermal behavior analysis of U-Mo/Al dispersion fuel

Energy Technology Data Exchange (ETDEWEB)

Ryu, Ho Jin; Park, Jong Mang; Lee, Yoon Sang; Kim, Chang Kyu [Korea Atomic Energy Research Institute, Taejon (Korea, Republic of)

2004-07-01

According to the non-proliferation policy under the reduced enrichment for research and test reactors (RERTR) program, low enriched uranium(LEU) fuel such as uranium silicide dispersion fuels are being used in research reactors. Because of a lower enrichment higher uranium density fuels are required for some high performance research reactors. Some uranium alloys with a high uranium density such as U-Mo alloys have been considered as one of the most promising candidates for a dispersion fuel due to the good irradiation performance. An international qualification program to replace the uranium silicide dispersion fuel with U-Mo dispersion fuel is being carried out under the RERTR program. Although U-Mo powders are conventionally supplied by the mechanical comminuting of as-cast U-Mo alloys, KAERI developed a centrifugal atomization method in order to simplify the preparation process and improve the properties. The centrifugally atomized powders have a rapidly solidified gamma uranium structure and a spherical shape. During the in-reactor operation of a dispersion fuel, interdiffusion or chemical reactions between the fuel particles and the matrix occurr. Intermetallic compounds in the form of UAlx are formed as a result of the diffusional reaction. Because the intermetallic compounds are less dense than the combined reactants, the volume of the fuel element increases after the reaction. In addition to the effect on the swelling performance, the reaction layers between the U-Mo and the Al matrix induces a degradation of the thermal properties of the U-Mo/Al dispersion fuels. It is important to investigate the thermal behavior of U-Mo/Al dispersion fuel according to reaction between the fuel particles and the matrix with the burnup and linear power. In this study, a finite element analysis was used for the calculation of the temperature distribution of the U-Mo/Al dispersion fuel with a burnup and linear power. Kinetics data of the reaction layers such as the growth

Thermal behavior analysis of U-Mo/Al dispersion fuel

International Nuclear Information System (INIS)

Ryu, Ho Jin; Park, Jong Mang; Lee, Yoon Sang; Kim, Chang Kyu

2004-01-01

According to the non-proliferation policy under the reduced enrichment for research and test reactors (RERTR) program, low enriched uranium(LEU) fuel such as uranium silicide dispersion fuels are being used in research reactors. Because of a lower enrichment higher uranium density fuels are required for some high performance research reactors. Some uranium alloys with a high uranium density such as U-Mo alloys have been considered as one of the most promising candidates for a dispersion fuel due to the good irradiation performance. An international qualification program to replace the uranium silicide dispersion fuel with U-Mo dispersion fuel is being carried out under the RERTR program. Although U-Mo powders are conventionally supplied by the mechanical comminuting of as-cast U-Mo alloys, KAERI developed a centrifugal atomization method in order to simplify the preparation process and improve the properties. The centrifugally atomized powders have a rapidly solidified gamma uranium structure and a spherical shape. During the in-reactor operation of a dispersion fuel, interdiffusion or chemical reactions between the fuel particles and the matrix occurr. Intermetallic compounds in the form of UAlx are formed as a result of the diffusional reaction. Because the intermetallic compounds are less dense than the combined reactants, the volume of the fuel element increases after the reaction. In addition to the effect on the swelling performance, the reaction layers between the U-Mo and the Al matrix induces a degradation of the thermal properties of the U-Mo/Al dispersion fuels. It is important to investigate the thermal behavior of U-Mo/Al dispersion fuel according to reaction between the fuel particles and the matrix with the burnup and linear power. In this study, a finite element analysis was used for the calculation of the temperature distribution of the U-Mo/Al dispersion fuel with a burnup and linear power. Kinetics data of the reaction layers such as the growth

Buffer gas cooling and mixture analysis

Science.gov (United States)

Patterson, David S.; Doyle, John M.

2018-03-06

An apparatus for spectroscopy of a gas mixture is described. Such an apparatus includes a gas mixing system configured to mix a hot analyte gas that includes at least one analyte species in a gas phase into a cold buffer gas, thereby forming a supersaturated mixture to be provided for spectroscopic analysis.

The effect of the environment conditions on the prediction of flammable cloud dispersion

OpenAIRE

Schleder, Adriana; Martins, Marcelo; Pastor Ferrer, Elsa; Planas Cuchi, Eulàlia

2014-01-01

In order to quantify the damage caused by undesired events involving leakages of flammable materials, specific models are used to analyze the spills or jets of gas and liquid, gas dispersion, explosions and fires. The main step of this analysis is to estimate the concentration, in space and time, of the vapor cloud of hazardous substances released into the atmosphere; the purpose is to determine the area where a fire or explosion might occur and the quantity of flam...

Neutronic Analysis and Radiological Safety of RSG-GAS Reactor on 300 Grams Uranium Silicide Core

International Nuclear Information System (INIS)

Pande Made Udiyani; Lily Suparlina; Rokhmadi

2007-01-01

As starting of usage silicide U 250 g fuel element in the core of RSG-GAS and will be continued with usage of silicide U 300 g fuel element, hence done beforehand neutronic analyse and radiological safety of RSG-GAS. Calculation done by ORIGEN2.1 code to calculate source term, and also by PC-COSYMA code to calculate radiological safety of radioactive dispersion from RSG-GAS. Calculation of radioactive dispersion done at condition of reactor is postulated be happened an accident of LOCA causing one fuel element to melt. Neutronic analysis indicate that silicide U 250 g full core shall to be operated beforehand during 625 MWD before converted to silicide U 300 g core. During operation of transition core with mixture of silicide U 250 g and 300 g, all parameter fulfill criterion of safety Designed Balance core of silicide U 300 g will be reached at the time of fifth full core. Result of calculation indicate that through mixture core of silicide U 250 and 300 g proposed can form silicide U 300 g balance core of reactor RSG-GAS safely. Calculation of radiology safety by deterministic for silicide U 300 g balance core, and accident postulation which is equal to core of silicide U 250 g yield output in the form of radiation activity (radionuclide concentration in the air and deposition on the ground), radiation dose (collective and individual), radiation effect (short- and long-range), which accepted by society in each perceived sector. Result of calculation indicated that dose accepted by society is not pass permitted boundary for public society if happened accident. (author)

Gas dispersal potential of infant bedding of sudden death cases. (I): CO2 accumulation around the face of infant mannequin model.

Science.gov (United States)

Sakai, Jun; Takahashi, Shirushi; Funayama, Masato

2009-04-01

We assessed CO(2) gas dispersal potential of bedding that had actually been used by 26 infants diagnosed with sudden unexpected infant death using a baby mannequin model. The age of victims ranged from 1 to 12 months. In some cases, the parents alleged that the infant faces were not covered with bedding when they were found. The parent's memories, however, may not have been accurate; therefore, we examined the potential for gas dispersal based on the supposition that the bedding had covered their faces. The mannequin was connected with a respirator set on the tidal volume and respiratory rates matched with the baby's age. Before measuring, CO(2) flow was regulated in 5%+/-0.1% of end-tidal PCO(2). After the model was placed on each bedding condition, measurements were performed at least five times under each respiratory condition. Four cases showed a plateau of FiCO(2) bedding. Especially, the latter seven bedding could have high rebreathing potential if they covered the infant's faces and the probability of environmental asphyxia should be considered.

Glyoxal and methylglyoxal as urinary markers of diabetes. Determination using a dispersive liquid-liquid microextraction procedure combined with gas chromatography-mass spectrometry.

Science.gov (United States)

Pastor-Belda, M; Fernández-García, A J; Campillo, N; Pérez-Cárceles, M D; Motas, M; Hernández-Córdoba, M; Viñas, P

2017-08-04

Glyoxal (GO) and methylglyoxal (MGO) are α-oxoaldehydes that can be used as urinary diabetes markers. In this study, their levels were measured using a sample preparation procedure based on salting-out assisted liquid-liquid extraction (SALLE) and dispersive liquid-liquid microextraction (DLLME) combined with gas chromatography-mass spectrometry (GC-MS). The effect of the derivatization reaction with 2,3-diaminonaphthalene, the addition of acetonitrile and sodium chloride to urine, and the DLLME step using the acetonitrile extract as dispersant solvent and carbon tetrachloride as extractant solvent were carefully optimized. Quantification was performed by the internal standard method, using 5-bromo-2-chloroanisole. The intraday and interday precisions were lower than 6%. Limits of detection were 0.12 and 0.06ngmL -1 , and enrichment factors 140 and 130 for GO and MGO, respectively. The concentrations of these α-oxoaldehydes in urine were between 0.9 and 35.8ngg -1 levels (creatinine adjusted). A statistical comparison of the analyte contents of urine samples from non-diabetic and diabetic patients pointed to significant differences (P=0.046, 24 subjects investigated), particularly regarding MGO, which was higher in diabetic patients. The novelty of this study compared with previous procedures lies in the treatment of the urine sample by SALLE based on the addition of acetonitrile and sodium chloride to the urine. The DLLME procedure is performed with a sedimented drop of the extractant solvent, without a surfactant reagent, and using acetonitrile as dispersant solvent. Separation of the analytes was performed using GC-MS detection, being the analytes unequivocal identified. The proposed procedure is the first microextraction method applied to the analysis of urine samples from diabetic and non-diabetic patients that allows a clear differentiation between both groups using a simple analysis. Copyright © 2017 Elsevier B.V. All rights reserved.

DART model for irradiation-induced swelling of dispersion fuel elements including aluminum-fuel interaction

International Nuclear Information System (INIS)

Rest, J.; Hofman, G.L.

1997-01-01

The Dispersion Analysis Research Tool (DART) contains models for fission-gas-induced fuel swelling, interaction of fuel with the matrix aluminum, for the resultant reaction-product swelling, and for the calculation of the stress gradient within the fuel particle. The effects of an aluminide shell on fuel particle swelling are evaluated. Validation of the model is demonstrated by a comparison of DART calculations of fuel swelling of U 3 SiAl-Al and U 3 Si 2 -Al for various dispersion fuel element designs with the data

Identification and elucidation of anthropogenic source contribution in PM10 pollutant: Insight gain from dispersion and receptor models.

Science.gov (United States)

Roy, Debananda; Singh, Gurdeep; Yadav, Pankaj

2016-10-01

Source apportionment study of PM 10 (Particulate Matter) in a critically polluted area of Jharia coalfield, India has been carried out using Dispersion model, Principle Component Analysis (PCA) and Chemical Mass Balance (CMB) techniques. Dispersion model Atmospheric Dispersion Model (AERMOD) was introduced to simplify the complexity of sources in Jharia coalfield. PCA and CMB analysis indicates that monitoring stations near the mining area were mainly affected by the emission from open coal mining and its associated activities such as coal transportation, loading and unloading of coal. Mine fire emission also contributed a considerable amount of particulate matters in monitoring stations. Locations in the city area were mostly affected by vehicular, Liquid Petroleum Gas (LPG) & Diesel Generator (DG) set emissions, residential, and commercial activities. The experimental data sampling and their analysis could aid understanding how dispersion based model technique along with receptor model based concept can be strategically used for quantitative analysis of Natural and Anthropogenic sources of PM 10 . Copyright © 2016. Published by Elsevier B.V.

Analysis on the atmospheric dispersion of radioactive materials

International Nuclear Information System (INIS)

Nagai, Haruyasu

2012-01-01

JAEA has been developing a new prediction system of comprehensive movement, SPEEDI-MP (SPEEDI Multi-model Package), which can treat continuously and strictly with the migration behavior of radioactive materials at atmosphere, sea, and land region. JAEA has been further promoting the detail analysis of atmospheric migration of radioactive materials dispersed by an accident. Then, using a part of this system, the atmospheric-diversion prediction system, WSPEEDI-II, the atmospheric diversion mass and the atmospheric diffusion analysis were carried out. This issue reports the summary. (M.H.)

Experimental simulation of corium dispersion phenomena in direct containment heating

International Nuclear Information System (INIS)

Wu, Q.

1996-01-01

In a direct containment heating (DCH) accident scenario, the degree of corium dispersion is one of the most significant factors responsible for the reactor containment heating and pressurization. To study the mechanisms of the corium dispersion phenomenon, a DCH separate effect test facility of 1:10 linear scale for Zion PWR geometry is constructed. Experiments are carried out with air-water and air-woods metal simulating steam and molten core materials. The physical process of corium dispersion is studied in detail through various instruments, as well as with flow visualization at several locations. The accident transient begins with the liquid jet discharge at the bottom of the reactor pressure vessel. Once the jet impinges on the cavity bottom floor, it immediately spreads out and moves rapidly to the cavity exit as a film flow. Part of the discharged liquid flows out of the cavity before gas blowdown, and the rest is subjected to the entrainment process due to the high speed gas stream. The liquid film and droplet flows from the reactor cavity will then experience subcompartment trapping and re-entrainment. Consequently, the dispersed liquid droplets that follow the gas stream are transported into the containment atmosphere, resulting in containment heating and pressurization in the prototypic condition. Comprehensive measurements are obtained in this study, including the liquid jet velocity, liquid film thickness and velocity transients in the test cavity, gas velocity and velocity profile in the cavity, droplet size distribution and entrainment rate, and the fraction of dispersed liquid in the containment building. These data are of great importance for better understanding of the corium dispersion mechanisms. (orig.)

Performance Analysis of Ad Hoc Dispersed Spectrum Cognitive Radio Networks over Fading Channels

Directory of Open Access Journals (Sweden)

Mohammad Muneer

2011-01-01

Full Text Available Cognitive radio systems can utilize dispersed spectrum, and thus such approach is known as dispersed spectrum cognitive radio systems. In this paper, we first provide the performance analysis of such systems over fading channels. We derive the average symbol error probability of dispersed spectrum cognitive radio systems for two cases, where the channel for each frequency diversity band experiences independent and dependent Nakagami- fading. In addition, the derivation is extended to include the effects of modulation type and order by considering M-ary phase-shift keying ( -PSK and M-ary quadrature amplitude modulation -QAM schemes. We then consider the deployment of such cognitive radio systems in an ad hoc fashion. We consider an ad hoc dispersed spectrum cognitive radio network, where the nodes are assumed to be distributed in three dimension (3D. We derive the effective transport capacity considering a cubic grid distribution. Numerical results are presented to verify the theoretical analysis and show the performance of such networks.

Mechanical and Tribological Characteristics of TIG Hardfaced Dispersive Layer by Reinforced with Particles Extruded Aluminium

Directory of Open Access Journals (Sweden)

R. Dimitrova

2017-05-01

Full Text Available The article presents the results of the implemented technology for generation of hardfaced dispersive layers obtained by additive material containing reinforcing phase of non-metal particles. The wear resistant coatings are deposited on pure aluminium metal matrix by shielded gas metal-arc welding applying tungsten inert gas (TIG with extruded aluminium wire reinforced by particles as additive material. Wire filler is produced by extrusion of a pack containing metalized and plated by flux micro/nano SiC particles. The metalized particles implanting in the metal matrix and its dispersive hardfacing are realized by solid-state welding under conditions of hot plastic deformation. Tribological characteristics are studied of the hardfaced layers of dispersive reinforced material on pure aluminium metal matrix with and without flux. Hardness profiles of the hardfaced layers are determined by nanoindentation. The surface layers are studied by means of Scanning Electron Microscopy (SEM and Energy Dispersive X-ray (EDX analysis. Increase by 15-31 % of the wear resistance of the hardfaced layers and 30-40 % of their hardness was found, which is due to the implanted in the layer reinforcing phase of metalized micro/nano SiC particles.

Insulin diffusion and self-association characterized by real-time UV imaging and Taylor dispersion analysis

DEFF Research Database (Denmark)

Jensen, Sabrine S; Jensen, Henrik; Cornett, Claus

2014-01-01

, self-association, and apparent size of insulin were further characterized by Taylor dispersion analysis, size exclusion chromatography, and dynamic light scattering. At low insulin concentrations and pH 3.0, the hydrodynamic radius of insulin was determined by Taylor dispersion analysis to 1.5±0.1nm...

Dispersant testing : a study on analytical test procedures

International Nuclear Information System (INIS)

Fingas, M.F.; Fieldhouse, B.; Wang, Z.; Environment Canada, Ottawa, ON

2004-01-01

Crude oil is a complex mixture of hydrocarbons, ranging from small, volatile compounds to very large, non-volatile compounds. Analysis of the dispersed oil is crucial. This paper described Environment Canada's ongoing studies on various traits of dispersants. In particular, it describes small studies related to dispersant effectiveness and methods to improve analytical procedures. The study also re-evaluated the analytical procedure for the Swirling Flask Test, which is now part of the ASTM standard procedure. There are new and improved methods for analyzing oil-in-water using gas chromatography (GC). The methods could be further enhanced by integrating the entire chromatogram rather than just peaks. This would result in a decrease in maximum variation from 5 per cent to about 2 per cent. For oil-dispersant studies, the surfactant-dispersed oil hydrocarbons consist of two parts: GC-resolved hydrocarbons and GC-unresolved hydrocarbons. This study also tested a second feature of the Swirling Flask Test in which the side spout was tested and compared with a new vessel with a septum port instead of a side spout. This decreased the variability as well as the energy and mixing in the vessel. Rather than being a variation of the Swirling Flask Test, it was suggested that a spoutless vessel might be considered as a completely separate test. 7 refs., 2 tabs., 4 figs

Accurate Recovery of H i Velocity Dispersion from Radio Interferometers

Energy Technology Data Exchange (ETDEWEB)

Ianjamasimanana, R. [Max-Planck Institut für Astronomie, Königstuhl 17, D-69117, Heidelberg (Germany); Blok, W. J. G. de [Netherlands Institute for Radio Astronomy (ASTRON), Postbus 2, 7990 AA Dwingeloo (Netherlands); Heald, George H., E-mail: roger@mpia.de, E-mail: blok@astron.nl, E-mail: George.Heald@csiro.au [Kapteyn Astronomical Institute, University of Groningen, P.O. Box 800, 9700 AV, Groningen (Netherlands)

2017-05-01

Gas velocity dispersion measures the amount of disordered motion of a rotating disk. Accurate estimates of this parameter are of the utmost importance because the parameter is directly linked to disk stability and star formation. A global measure of the gas velocity dispersion can be inferred from the width of the atomic hydrogen (H i) 21 cm line. We explore how several systematic effects involved in the production of H i cubes affect the estimate of H i velocity dispersion. We do so by comparing the H i velocity dispersion derived from different types of data cubes provided by The H i Nearby Galaxy Survey. We find that residual-scaled cubes best recover the H i velocity dispersion, independent of the weighting scheme used and for a large range of signal-to-noise ratio. For H i observations, where the dirty beam is substantially different from a Gaussian, the velocity dispersion values are overestimated unless the cubes are cleaned close to (e.g., ∼1.5 times) the noise level.

Social Mating System and Sex-Biased Dispersal in Mammals and Birds: A Phylogenetic Analysis

Science.gov (United States)

Mabry, Karen E.; Shelley, Erin L.; Davis, Katie E.; Blumstein, Daniel T.; Van Vuren, Dirk H.

2013-01-01

The hypothesis that patterns of sex-biased dispersal are related to social mating system in mammals and birds has gained widespread acceptance over the past 30 years. However, two major complications have obscured the relationship between these two behaviors: 1) dispersal frequency and dispersal distance, which measure different aspects of the dispersal process, have often been confounded, and 2) the relationship between mating system and sex-biased dispersal in these vertebrate groups has not been examined using modern phylogenetic comparative methods. Here, we present a phylogenetic analysis of the relationship between mating system and sex-biased dispersal in mammals and birds. Results indicate that the evolution of female-biased dispersal in mammals may be more likely on monogamous branches of the phylogeny, and that females may disperse farther than males in socially monogamous mammalian species. However, we found no support for a relationship between social mating system and sex-biased dispersal in birds when the effects of phylogeny are taken into consideration. We caution that although there are larger-scale behavioral differences in mating system and sex-biased dispersal between mammals and birds, mating system and sex-biased dispersal are far from perfectly associated within these taxa. PMID:23483957

Droplet dispersion angle measurements on a Pease-Antony Venturi scrubber

OpenAIRE

Puentes,N. A. G.; Guerra,V. G.; Coury,J. R.; Gonçalves,J. A. S.

2012-01-01

A Pease-Anthony Venturi scrubber is a gas cleaning device that uses liquid, injected in the equipment as jets, to remove contaminants from the gas. The liquid jet is atomized into droplets, which are dispersed throughout the equipment due to the turbulence. The performance of the scrubber is affected by the spatial distribution of the droplets. Although CFD models have been used to predict the droplet dispersion, these models are expensive. Alternatively, the concept of "jet spreading angle" ...

Taylor Dispersion Analysis as a promising tool for assessment of peptide-peptide interactions

DEFF Research Database (Denmark)

Høgstedt, Ulrich B; Schwach, Grégoire; van de Weert, Marco

2016-01-01

solutions increased with concentration. Our results indicate that a viscosity difference between run buffer and sample in Taylor Dispersion Analysis may result in overestimation of the measured diffusion coefficient. Thus, Taylor Dispersion Analysis provides a practical, but as yet primarily qualitative......Protein-protein and peptide-peptide (self-)interactions are of key importance in understanding the physiochemical behavior of proteins and peptides in solution. However, due to the small size of peptide molecules, characterization of these interactions is more challenging than for proteins...

Studies of emulsification, emulsion prevention and underwater dispersion

Energy Technology Data Exchange (ETDEWEB)

Celius, H.K.; Vassbotn, T.

1985-03-01

This is a report from the work performed under task 2: ''Effect of demulsifiers and despersants injected into a blowing oil stream'' of the research program ''Dispersion of oil on sea''. Three ad hoc experiments have been carried out involving laboratory studies in a small turbulent oil plume, tests with revolving flasks, and a small scale field test with a combined gas/oil plume. The results show that emulsion is formed in plume from underwater blowouts, and that this formation is prevented by small amounts (250 ppM) of demulsifiers or dispersants. Larger concentrations of dispersants (ca 2%) disperse the oil, and the oil is transported to the upper water layer in the gas/oil plume. None of the experiments have been designed as true scale tests, and the results cannot be directly transferred to operational, full scale conditions. The experiments have however narroved the necessary extent of studies, and allows for a simpler experimental procedure in the full scale field test planned for June 1985. 19 references.

Ultrastructural and Energy dispersive analysis of inorganic inclusions in a muscle biopsy

International Nuclear Information System (INIS)

Dodson, R.F.; Castillo-Mozun, P.; Hieger, L.R.; Williams, M.G. Jr.

1981-01-01

A muscle biopsy that, by light microscopy, exhibited mild atrophy consistent with chronic denervating disease was submitted for ultrastructural analysis. Inorganic structures within the tissue were defined by energy dispersive analysis as aluminosilicates, magnesium silicates, and iron deposits. These structures were localized in the interstitial (intercollagenous) area and in high concentrations within degenerated muscle bundles. An alteration of the blood/muscle barrier has obviously occurred; however, the extent to which the end result commonly occurs in humans is unknown. Clarification of the question raised by this observation will have to be derived from animal studies, and clinicians must have an awareness of the need for electron microscopy/energy-dispersive x-ray analysis in muscle biopsies from patients with similar therapeutic backgrounds

Origin of Scale-Dependent Dispersivity and Its Implications For Miscible Gas Flooding

Energy Technology Data Exchange (ETDEWEB)

Steven Bryant; Russ Johns; Larry Lake; Thomas Harmon

2008-09-30

Dispersive mixing has an important impact on the effectiveness of miscible floods. Simulations routinely assume Fickian dispersion, yet it is well established that dispersivity depends on the scale of measurement. This is one of the main reasons that a satisfactory method for design of field-scale miscible displacement processes is still not available. The main objective of this project was to improve the understanding of the fundamental mechanisms of dispersion and mixing, particularly at the pore scale. To this end, microsensors were developed and used in the laboratory to measure directly the solute concentrations at the scale of individual pores; the origin of hydrodynamic dispersion was evaluated from first principles of laminar flow and diffusion at the grain scale in simple but geometrically completely defined porous media; techniques to use flow reversal to distinguish the contribution to dispersion of convective spreading from that of true mixing; and the field scale impact of permeability heterogeneity on hydrodynamic dispersion was evaluated numerically. This project solved a long-standing problem in solute transport in porous media by quantifying the physical basis for the scaling of dispersion coefficient with the 1.2 power of flow velocity. The researchers also demonstrated that flow reversal uniquely enables a crucial separation of irreversible and reversible contributions to mixing. The interpretation of laboratory and field experiments that include flow reversal provides important insight. Other advances include the miniaturization of long-lasting microprobes for in-situ, pore-scale measurement of tracers, and a scheme to account properly in a reservoir simulator (grid-block scale) for the contributions of convective spreading due to reservoir heterogeneity and of mixing.

A gas conditioning and analysis system

International Nuclear Information System (INIS)

Busch, F.R.

1974-01-01

A system for carrying out a rapid analysis of explosive gas-mixtures is described. This system comprises a conduit connecting a sample taking point to a detection chamber, said chamber containing a mass of liquid into which the gas sample is discharged and being provided with a detecting unit for analyzing gases and with separate gas exit and liquid exit. The liquid is sent to a level-regulating chamber, whereas said gas exit sends the gas to a gas-stopping chamber which is in turn, connected to the conduit leading to a discharge point, and a vacuum pump for drawing up the gas sample into the system. This can be apply to nuclear power stations [fr

Refined potentials for rare gas atom adsorption on rare gas and alkali-halide surfaces

Science.gov (United States)

Wilson, J. W.; Heinbockel, J. H.; Outlaw, R. A.

1985-01-01

The utilization of models of interatomic potential for physical interaction to estimate the long range attractive potential for rare gases and ions is discussed. The long range attractive force is calculated in terms of the atomic dispersion properties. A data base of atomic dispersion parameters for rare gas atoms, alkali ion, and halogen ions is applied to the study of the repulsive core; the procedure for evaluating the repulsive core of ion interactions is described. The interaction of rare gas atoms on ideal rare gas solid and alkali-halide surfaces is analyzed; zero coverage absorption potentials are derived.

LNG vapor dispersion prediction with the DEGADIS dense-gas dispersion model. Topical report, April 1988-July 1990. Documentation

International Nuclear Information System (INIS)

Havens, J.; Spicer, T.

1990-09-01

The topical report is one of a series on the development of methods for LNG vapor dispersion prediction for regulatory application. The results indicate that the DEGADIS model is superior both phenomenologically and in performance to the Gaussian line source model promulgated in 49 CFR 193 for LNG vapor dispersion simulation. Availability of the DEGADIS model for VAX and IBM-PC formats provides for wider use of the model and greater potential for industry and regulatory acceptance. The acceptance is seen as an important interim objective while research continues on vapor dispersion estimation methods which provide for effects of vapor detention systems, turbulence induced by plant structure, and plant/area topographical features

Gas chromatography-flame ionization determination of benzaldehyde in non-steroidal anti-inflammatory drug injectable formulations using new ultrasound-assisted dispersive liquid-liquid micro extraction

International Nuclear Information System (INIS)

Mashayekhi, H.A.; Pourshamsian, K.

2012-01-01

Summary: In this study, simple and efficient ultrasound-assisted dispersive liquid-liquid micro extraction combined with gas chromatography (GC) was developed for the preconcentration and determination of benzaldehyde in injectable formulations of the non-steroidal anti-inflammatory drugs, diclofenac, Vitamin B-complex and Voltaren injection solutions. Fourteen microliters of toluene was injected slowly into 10 mL home-designed centrifuge glass vial containing an aqueous sample without salt addition that was located inside the ultrasonic water bath. The formed emulsion was centrifuged and 2 macro L of separated toluene was injected into a gas chromatographic system equipped with a flame ionization detector (GC-FID) for analysis. Several factors influencing the extraction efficiency as the nature and volume of organic solvent, extraction temperature, ionic strength and centrifugation time were investigated and optimized. Using optimum extraction conditions a detection limit of 0.3 macro g L/sup -1/ and a good linearity in a calibration range of 2.0-1000 macro g L/sup -1/ were achieved for analyte. This proposed method was successfully applied to the analysis of benzaldehyde in three injection formulations and relative standard deviation (RSD) of analysis (n=3), before spiking with standard benzaldehyde were 3.3, 2.0 and 1.3% for Na-diclofenac, vitamin B-complex and voltaren, respectively and after spiking of standard benzaldehyde (0.3 mg L/sup -1/), the RSD were 6.5, 3.6 and 2.8% for Na-diclofenac, vitamin B-complex and voltaren, respectively. (author)

Parallelization of simulation code for liquid-gas model of lattice-gas fluid

International Nuclear Information System (INIS)

Kawai, Wataru; Ebihara, Kenichi; Kume, Etsuo; Watanabe, Tadashi

2000-03-01

A simulation code for hydrodynamical phenomena which is based on the liquid-gas model of lattice-gas fluid is parallelized by using MPI (Message Passing Interface) library. The parallelized code can be applied to the larger size of the simulations than the non-parallelized code. The calculation times of the parallelized code on VPP500 (Vector-Parallel super computer with dispersed memory units), AP3000 (Scalar-parallel server with dispersed memory units), and a workstation cluster decreased in inverse proportion to the number of processors. (author)

Rapid and sensitive analysis of polychlorinated biphenyls and acrylamide in food samples using ionic liquid-based in situ dispersive liquid-liquid microextraction coupled to headspace gas chromatography.

Science.gov (United States)

Zhang, Cheng; Cagliero, Cecilia; Pierson, Stephen A; Anderson, Jared L

2017-01-20

A simple and rapid ionic liquid (IL)-based in situ dispersive liquid-liquid microextraction (DLLME) method was developed and coupled to headspace gas chromatography (HS-GC) employing electron capture (ECD) and mass spectrometry (MS) detection for the analysis of polychlorinated biphenyls (PCBs) and acrylamide at trace levels from milk and coffee samples. The chemical structures of the halide-based ILs were tailored by introducing various functional groups to the cations to evaluate the effect of different structural features on the extraction efficiency of the target analytes. Extraction parameters including the molar ratio of IL to metathesis reagent and IL mass were optimized. The effects of HS oven temperature and the HS sample vial volume on the analyte response were also evaluated. The optimized in situ DLLME method exhibited good analytical precision, good linearity, and provided detection limits down to the low ppt level for PCBs and the low ppb level for acrylamide in aqueous samples. The matrix-compatibility of the developed method was also established by quantifying acrylamide in brewed coffee samples. This method is much simpler and faster compared to previously reported GC-MS methods using solid-phase microextraction (SPME) for the extraction/preconcentration of PCBs and acrylamide from complex food samples. Copyright © 2016 Elsevier B.V. All rights reserved.

Automated NMR relaxation dispersion data analysis using NESSY

Directory of Open Access Journals (Sweden)

Gooley Paul R

2011-10-01

Full Text Available Abstract Background Proteins are dynamic molecules with motions ranging from picoseconds to longer than seconds. Many protein functions, however, appear to occur on the micro to millisecond timescale and therefore there has been intense research of the importance of these motions in catalysis and molecular interactions. Nuclear Magnetic Resonance (NMR relaxation dispersion experiments are used to measure motion of discrete nuclei within the micro to millisecond timescale. Information about conformational/chemical exchange, populations of exchanging states and chemical shift differences are extracted from these experiments. To ensure these parameters are correctly extracted, accurate and careful analysis of these experiments is necessary. Results The software introduced in this article is designed for the automatic analysis of relaxation dispersion data and the extraction of the parameters mentioned above. It is written in Python for multi platform use and highest performance. Experimental data can be fitted to different models using the Levenberg-Marquardt minimization algorithm and different statistical tests can be used to select the best model. To demonstrate the functionality of this program, synthetic data as well as NMR data were analyzed. Analysis of these data including the generation of plots and color coded structures can be performed with minimal user intervention and using standard procedures that are included in the program. Conclusions NESSY is easy to use open source software to analyze NMR relaxation data. The robustness and standard procedures are demonstrated in this article.

Gas-cooled reactor safety and accident analysis

International Nuclear Information System (INIS)

1985-12-01

The Specialists' Meeting on Gas-Cooled Reactor Safety and Accident Analysis was convened by the International Atomic Energy Agency in Oak Ridge on the invitation of the Department of Energy in Washington, USA. The meeting was hosted by the Oak Ridge National Laboratory. The purpose of the meeting was to provide an opportunity to compare and discuss results of safety and accident analysis of gas-cooled reactors under development, construction or in operation, to review their lay-out, design, and their operational performance, and to identify areas in which additional research and development are needed. The meeting emphasized the high safety margins of gas-cooled reactors and gave particular attention to the inherent safety features of small reactor units. The meeting was subdivided into four technical sessions: Safety and Related Experience with Operating Gas-Cooled Reactors (4 papers); Risk and Safety Analysis (11 papers); Accident Analysis (9 papers); Miscellaneous Related Topics (5 papers). A separate abstract was prepared for each of these papers

Transport of temperature-velocity covariance in gas-solid flow and its relation to the axial dispersion coefficient

Science.gov (United States)

Subramaniam, Shankar; Sun, Bo

2015-11-01

The presence of solid particles in a steady laminar flow generates velocity fluctuations with respect to the mean fluid velocity that are termed pseudo-turbulence. The level of these pseudo-turbulent velocity fluctuations has been characterized in statistically homogeneous fixed particle assemblies and freely evolving suspensions using particle-resolved direct numerical simulation (PR-DNS) by Mehrabadi et al. (JFM, 2015), and it is found to be a significant contribution to the total kinetic energy associated with the flow. The correlation of these velocity fluctuations with temperature (or a passive scalar) generates a flux term that appears in the transport equation for the average fluid temperature (or average scalar concentration). The magnitude of this transport of temperature-velocity covariance is quantified using PR-DNS of thermally fully developed flow past a statistically homogeneous fixed assembly of particles, and the budget of the average fluid temperature equation is presented. The relation of this transport term to the axial dispersion coefficient (Brenner, Phil. Trans. Roy. Soc. A, 1980) is established. The simulation results are then interpreted in the context of our understanding of axial dispersion in gas-solid flow. NSF CBET 1336941.

Dispersion of a layered electron gas with nearest neighbour-tunneling

International Nuclear Information System (INIS)

Miesenboeck, H.M.

1988-09-01

The dispersion of the first plasmon band is calculated within the Random Phase Approximation for a superlattice of two-dimensional electron-gases, mutually interacting, and with nearest neighbour hopping between the planes. It is further shown that the deviations of this dispersion from the one in systems with zero interplane motion are very small in commonly realized experimental situations and that they are expected to be observable only in samples with plane distances of 100A and less. (author). 15 refs, 3 figs, 1 tab

75 FR 53371 - Liquefied Natural Gas Facilities: Obtaining Approval of Alternative Vapor-Gas Dispersion Models

Science.gov (United States)

2010-08-31

.... PHMSA-2010-0226] Liquefied Natural Gas Facilities: Obtaining Approval of Alternative Vapor-Gas... safety standards for siting liquefied natural gas (LNG) facilities. Those standards require that an..., and Handling of Liquefied Natural Gas. That consensus [[Page 53372

Measurement of phase interaction in dispersed gas-particle two-phase flow by phase-doppler anemometry

Directory of Open Access Journals (Sweden)

Mergheni Ali Mohamed

2008-01-01

Full Text Available For simultaneous measurement of size and velocity distributions of continuous and dispersed phases in a two-phase flow a technique phase-Doppler anemometry was used. Spherical glass particles with a particle diameter range from 102 up to 212 µm were used. In this two-phase flow an experimental results are presented which indicate a significant influence of the solid particles on the flow characteristics. The height of influence of these effects depends on the local position in the jet. Near the nozzle exit high gas velocity gradients exist and therefore high turbulence production in the shear layer of the jet is observed. Here the turbulence intensity in the two-phase jet is decreased compared to the single-phase jet. In the developed zone the velocity gradient in the shear layer is lower and the turbulence intensity reduction is higher. .

Critical confrontation of standard and more sophisticated methods for modelling the dispersion in air of heavy gas clouds; evaluation and illustration of the intrinsic limitations of both categories

International Nuclear Information System (INIS)

Riethmuller, M.L.

1983-01-01

Mathematical models of gas dispersion have evolved drastically since the 1930's. For a long time, the most widely used approach was the so-called Gaussian model as described in practical terms by Turner or box models which have shown relative merits. In the field of heavy gas dispersion, the use of such approaches appeared somewhat limited and therefore new models have been proposed. Some of these new generation models were making use of the latest progress in turbulence modelling as derived from laboratory work as well as numerical advances. The advent of faster and larger computers made possible the development of three dimensional codes that were computing both flow field and gas dispersion taking into account details of the ground obstacles, heat exchange and possibly phase changes as well. The description of these new types of models makes them appear as a considerable improvement over the simpler approaches. However, recent comparisons between many of these have led to the conclusion that the scatter between predictions attained with sophisticated models was just as large as with other ones. It seems therefore, that current researchers might have fallen into the trap of confusing mathematical precision with accuracy. It is therefore felt necessary to enlighten this question by an investigation which, rather than comparing individual models, would analyse the key features of both approaches and put in evidence their relative merits and degree of realism when being really applied

Thermodynamic Analysis of Supplementary-Fired Gas Turbine Cycles

DEFF Research Database (Denmark)

Elmegaard, Brian; Henriksen, Ulrik Birk; Qvale, Einar Bjørn

2002-01-01

This paper presents an analysis of the possibilities for improving the efficiency of an indirectly biomass-fired gas turbine (IBFGT) by supplementary direct gas-firing. The supplementary firing may be based on natural gas, biogas, or pyrolysis gas. {The interest in this cycle arise from a recent...... demonstration of a two-stage gasification process through construction of several plants.} A preliminary analysis of the ideal recuperated Brayton cycle shows that for this cycle any supplementary firing will have a marginal efficiency of unity per extra unit of fuel. The same result is obtained...

Investigation of natural gas plume dispersion using mobile observations and large eddy simulations

Science.gov (United States)

Caulton, Dana R.; Li, Qi; Golston, Levi; Pan, Da; Bou-Zeid, Elie; Fitts, Jeff; Lane, Haley; Lu, Jessica; Zondlo, Mark A.

2016-04-01

Recent work suggests the distribution of methane emissions from fracking operations is skewed with a small percentage of emitters contributing a large proportion of the total emissions. These sites are known as 'super-emitters.' The Marcellus shale, the most productive natural gas shale field in the United States, has received less intense focus for well-level emissions and is here used as a test site for targeted analysis between current standard trace-gas advection practices and possible improvements via advanced modeling techniques. The Marcellus shale is topographically complex, making traditional techniques difficult to implement and evaluate. For many ground based mobile studies, the inverse Gaussian plume method (IGM) is used to produce emission rates. This method is best applied to well-mixed plumes from strong point sources and may not currently be well-suited for use with disperse weak sources, short-time frame measurements or data collected in complex terrain. To assess the quality of IGM results and to improve source-strength estimations, a robust study that combines observational data with a hierarchy of models of increasing complexity will be presented. The field test sites were sampled with multiple passes using a mobile lab as well as a stationary tower. This mobile lab includes a Garmin GPS unit, Vaisala weather station (WTX520), LICOR 7700 CH4 open path sensor and LICOR 7500 CO2/H2O open path sensor. The sampling tower was constructed consisting of a Metek uSonic-3 Class A sonic anemometer, and an additional LICOR 7700 and 7500. Data were recorded for at least one hour at these sites. The modeling will focus on large eddy simulations (LES) of the wind and CH4 concentration fields for these test sites. The LES model used 2 m horizontal and 1 m vertical resolution and was integrated in time for 45 min for various test sites under stable, neutral and unstable conditions. It is here considered as the reference to which various IGM approaches can be

Modeling solid-fuel dispersal during slow loss-of-flow-type transients

International Nuclear Information System (INIS)

DiMelfi, R.J.; Fenske, G.R.

1981-01-01

The dispersal, under certain accident conditions, of solid particles of fast-reactor fuel is examined in this paper. In particular, we explore the possibility that solid-fuel fragmentation and dispersal can be driven by expanding fission gas, during a slow LOF-type accident. The consequences of fragmentation are studied in terms of the size and speed of dispersed particles, and the overall quantity of fuel moved. (orig.)

Ultrasound-assisted leaching-dispersive solid-phase extraction followed by liquid-liquid microextraction for the determination of polybrominated diphenyl ethers in sediment samples by gas chromatography-tandem mass spectrometry.

Science.gov (United States)

Fontana, Ariel R; Lana, Nerina B; Martinez, Luis D; Altamirano, Jorgelina C

2010-06-30

Ultrasound-assisted leaching-dispersive solid-phase extraction followed by dispersive liquid-liquid microextraction (USAL-DSPE-DLLME) technique has been developed as a new analytical approach for extracting, cleaning up and preconcentrating polybrominated diphenyl ethers (PBDEs) from sediment samples prior gas chromatography-tandem mass spectrometry (GC-MS/MS) analysis. In the first place, PBDEs were leached from sediment samples by using acetone. This extract was cleaned-up by DSPE using activated silica gel as sorbent material. After clean-up, PBDEs were preconcentrated by using DLLME technique. Thus, 1 mL acetone extract (disperser solvent) and 60 microL carbon tetrachloride (extraction solvent) were added to 5 mL ultrapure water and a DLLME technique was applied. Several variables that govern the proposed technique were studied and optimized. Under optimum conditions, the method detection limits (MDLs) of PBDEs calculated as three times the signal-to-noise ratio (S/N) were within the range 0.02-0.06 ng g(-1). The relative standard deviations (RSDs) for five replicates were or =0.9991. Validation of the methodology was carried out by standard addition method at two concentration levels (0.25 and 1 ng g(-1)) and by comparing with a reference Soxhlet technique. Recovery values were > or =80%, which showed a satisfactory robustness of the analytical methodology for determination of low PBDEs concentration in sediment samples. Copyright 2010 Elsevier B.V. All rights reserved.

The materials science synchrotron beamline EDDI for energy-dispersive diffraction analysis

International Nuclear Information System (INIS)

Genzel, Ch.; Denks, I.A.; Gibmeier, J.; Klaus, M.; Wagener, G.

2007-01-01

In April 2005 the materials science beamline EDDI (Energy Dispersive DIffraction) at the Berlin synchrotron storage ring BESSY started operation. The beamline is operated in the energy-dispersive mode of diffraction using the high energy white photon beam provided by a superconducting 7 T multipole wiggler. Starting from basic information on the beamline set-up, its measuring facilities and data processing concept, the wide range of applications for energy-dispersive diffraction is demonstrated by a series of examples coming from different fields in materials sciences. It will be shown, that the EDDI beamline is especially suitable for the investigation of structural properties and gradients in the near surface region of polycrystalline materials. In particular, this concerns the analysis of multiaxial residual stress fields in the highly stressed surface zone of technical parts. The high photon flux further facilitates fast in situ experiments at room as well as high temperature to monitor for example the growth kinetics and reaction in thin film growth

Assessment of cavity dispersal correlations for possible implementation in the CONTAIN code

International Nuclear Information System (INIS)

Williams, D.C.; Griffith, R.O.

1996-02-01

Candidate models and correlations describing entrainment and dispersal of core debris from reactor cavities in direct containment heating (DCH) event, are assessed against a data base of approximately 600 experiments performed previously at Brookhaven National Laboratory and Sandia National Laboratories reactor cavities was studied. Cavity geometries studied are those of the Surry and Zion nuclear power plants and scale factors of 1/42 and 1/10 were studied for both geometries. Other parameters varied in the experiments include gas pressure driving the dispersal, identities of the driving gas and of the simulant fluid, orifice diameter in the pressure vessel, and volume of the gas pressure vessel. Correlations were assessed in terms of their ability to reproduce the observed trends in the fractions dispersed as the experimental parameters were varied. For the fraction of the debris dispersed, the correlations recommended for inclusion in the CONTAIN code are the Tutu-Ginsberg correlations, the integral form of the correlation proposed by Levy and a modified form of the Whalley-Hewitt correlation. For entrainment rates, the recommended correlations are the time-dependent forms of the Levy correlation, a correlation suggested by Tutu, and the modified Whalley-Hewitt correlation

3D analysis of the gas dynamic loads in the KKB containment resulting from combustion of radiolysis gas

International Nuclear Information System (INIS)

Kotchourko, A.; Breitung, W.; Dorofeev, S.; Ohlmeyer, H.

2003-01-01

The radiolysis gas explosion in the KKB power plant was recalculated in 3D simulations as followed: The total energy released was limited as far as possible. - Pressure generation and dispersion across the containment was calculated for three different initial energies. - Loads in the near field were simulated assuming the most probable total energy (about 14 MJ) and using three different models of the explosion process. The calculation with direct simulation of detonation inside the tube provided realistic results, according to the authors. - Transient local pressure and temperature loads were recorded in specified local points and evaluated in further damage analyses. The results showed that modern 3D flow and combustion calculations provide valuable information on pressure and temperature loads resulting from radiolysis gas reactions in big complex safety containments. (orig.) [de

Growth of plant root cultures in liquid- and gas-dispersed reactor environments.

Science.gov (United States)

McKelvey, S A; Gehrig, J A; Hollar, K A; Curtis, W R

1993-01-01

The growth of Agrobacterium transformed "hairy root" cultures of Hyoscyamus muticus was examined in various liquid- and gas-dispersed bioreactor configurations. Reactor runs were replicated to provide statistical comparisons of nutrient availability on culture performance. Accumulated tissue mass in submerged air-sparged reactors was 31% of gyratory shake-flask controls. Experiments demonstrate that poor performance of sparged reactors is not due to bubble shear damage, carbon dioxide stripping, settling, or flotation of roots. Impaired oxygen transfer due to channeling and stagnation of the liquid phase are the apparent causes of poor growth. Roots grown on a medium-perfused inclined plane grew at 48% of gyratory controls. This demonstrates the ability of cultures to partially compensate for poor liquid distribution through vascular transport of nutrients. A reactor configuration in which the medium is sprayed over the roots and permitted to drain down through the root tissue was able to provide growth rates which are statistically indistinguishable (95% T-test) from gyratory shake-flask controls. In this type of spray/trickle-bed configuration, it is shown that distribution of the roots becomes a key factor in controlling the rate of growth. Implications of these results regarding design and scale-up of bioreactors to produce fine chemicals from root cultures are discussed.

A new approximation of the dispersion relations occurring in the sound-attenuation problem of turbofan aircraft engines

Directory of Open Access Journals (Sweden)

Robert SZABO

2011-12-01

Full Text Available The dispersion relations, appearing in the analysis of the stability of a gas flow in a straight acoustically-lined duct with respect to perturbations produced by a time harmonic source, beside the wave number and complex frequency contain the solution of a boundary value problem of the Pridmore-Brown equation depending on the wave number and frequency. For this reason, in practice the dispersion relations are rarely simple enough for carried out the zeros. The determination of zeros of these dispersion relations is crucial for the prediction of the perturbation attenuation or amplification. In this paper an approximation of the dispersion relations is given. Our approach preserves the general character of the mean flow, the general Pridmore-Brown equation and it’s only in the shear flow that we replace the exact solution of the boundary value problem with its Taylor polynomial approximate. In this way new approximate dispersion relations are obtained which zero’s can be found by computer.

Contaminant dispersion prediction and source estimation with integrated Gaussian-machine learning network model for point source emission in atmosphere

International Nuclear Information System (INIS)

Ma, Denglong; Zhang, Zaoxiao

2016-01-01

Highlights: • The intelligent network models were built to predict contaminant gas concentrations. • The improved network models coupled with Gaussian dispersion model were presented. • New model has high efficiency and accuracy for concentration prediction. • New model were applied to indentify the leakage source with satisfied results. - Abstract: Gas dispersion model is important for predicting the gas concentrations when contaminant gas leakage occurs. Intelligent network models such as radial basis function (RBF), back propagation (BP) neural network and support vector machine (SVM) model can be used for gas dispersion prediction. However, the prediction results from these network models with too many inputs based on original monitoring parameters are not in good agreement with the experimental data. Then, a new series of machine learning algorithms (MLA) models combined classic Gaussian model with MLA algorithm has been presented. The prediction results from new models are improved greatly. Among these models, Gaussian-SVM model performs best and its computation time is close to that of classic Gaussian dispersion model. Finally, Gaussian-MLA models were applied to identifying the emission source parameters with the particle swarm optimization (PSO) method. The estimation performance of PSO with Gaussian-MLA is better than that with Gaussian, Lagrangian stochastic (LS) dispersion model and network models based on original monitoring parameters. Hence, the new prediction model based on Gaussian-MLA is potentially a good method to predict contaminant gas dispersion as well as a good forward model in emission source parameters identification problem.

Contaminant dispersion prediction and source estimation with integrated Gaussian-machine learning network model for point source emission in atmosphere

Energy Technology Data Exchange (ETDEWEB)

Ma, Denglong [Fuli School of Food Equipment Engineering and Science, Xi’an Jiaotong University, No.28 Xianning West Road, Xi’an 710049 (China); Zhang, Zaoxiao, E-mail: zhangzx@mail.xjtu.edu.cn [State Key Laboratory of Multiphase Flow in Power Engineering, Xi’an Jiaotong University, No.28 Xianning West Road, Xi’an 710049 (China); School of Chemical Engineering and Technology, Xi’an Jiaotong University, No.28 Xianning West Road, Xi’an 710049 (China)

2016-07-05

Highlights: • The intelligent network models were built to predict contaminant gas concentrations. • The improved network models coupled with Gaussian dispersion model were presented. • New model has high efficiency and accuracy for concentration prediction. • New model were applied to indentify the leakage source with satisfied results. - Abstract: Gas dispersion model is important for predicting the gas concentrations when contaminant gas leakage occurs. Intelligent network models such as radial basis function (RBF), back propagation (BP) neural network and support vector machine (SVM) model can be used for gas dispersion prediction. However, the prediction results from these network models with too many inputs based on original monitoring parameters are not in good agreement with the experimental data. Then, a new series of machine learning algorithms (MLA) models combined classic Gaussian model with MLA algorithm has been presented. The prediction results from new models are improved greatly. Among these models, Gaussian-SVM model performs best and its computation time is close to that of classic Gaussian dispersion model. Finally, Gaussian-MLA models were applied to identifying the emission source parameters with the particle swarm optimization (PSO) method. The estimation performance of PSO with Gaussian-MLA is better than that with Gaussian, Lagrangian stochastic (LS) dispersion model and network models based on original monitoring parameters. Hence, the new prediction model based on Gaussian-MLA is potentially a good method to predict contaminant gas dispersion as well as a good forward model in emission source parameters identification problem.

Chemical composition dispersion in bi-metallic nanoparticles: semi-automated analysis using HAADF-STEM

International Nuclear Information System (INIS)

Epicier, T.; Sato, K.; Tournus, F.; Konno, T.

2012-01-01

We present a method using high-angle annular dark field scanning transmission electron microscopy (HAADF-STEM) to determine the chemical composition of bi-metallic nanoparticles. This method, which can be applied in a semi-automated way, allows large scale analysis with a statistical number of particles (several hundreds) in a short time. Once a calibration curve has been obtained, e.g., using energy-dispersive X-ray spectroscopy (EDX) measurements on a few particles, the HAADF integrated intensity of each particle can indeed be directly related to its chemical composition. After a theoretical description, this approach is applied to the case of iron–palladium nanoparticles (expected to be nearly stoichiometric) with a mean size of 8.3 nm. It will be shown that an accurate chemical composition histogram is obtained, i.e., the Fe content has been determined to be 49.0 at.% with a dispersion of 10.4 %. HAADF-STEM analysis represents a powerful alternative to fastidious single particle EDX measurements, for the compositional dispersion in alloy nanoparticles.

Evidence for fish dispersal from spatial analysis of stream network topology

Science.gov (United States)

Hitt, N.P.; Angermeier, P.L.

2008-01-01

Developing spatially explicit conservation strategies for stream fishes requires an understanding of the spatial structure of dispersal within stream networks. We explored spatial patterns of stream fish dispersal by evaluating how the size and proximity of connected streams (i.e., stream network topology) explained variation in fish assemblage structure and how this relationship varied with local stream size. We used data from the US Environmental Protection Agency's Environmental Monitoring and Assessment Program in wadeable streams of the Mid-Atlantic Highlands region (n = 308 sites). We quantified stream network topology with a continuous analysis based on the rate of downstream flow accumulation from sites and with a discrete analysis based on the presence of mainstem river confluences (i.e., basin area >250 km2) within 20 fluvial km (fkm) from sites. Continuous variation in stream network topology was related to local species richness within a distance of ???10 fkm, suggesting an influence of fish dispersal within this spatial grain. This effect was explained largely by catostomid species, cyprinid species, and riverine species, but was not explained by zoogeographic regions, ecoregions, sampling period, or spatial autocorrelation. Sites near mainstem river confluences supported greater species richness and abundance of catostomid, cyprinid, and ictalurid fishes than did sites >20 fkm from such confluences. Assemblages at sites on the smallest streams were not related to stream network topology, consistent with the hypothesis that local stream size regulates the influence of regional dispersal. These results demonstrate that the size and proximity of connected streams influence the spatial distribution of fish and suggest that these influences can be incorporated into the designs of stream bioassessments and reserves to enhance management efficacy. ?? 2008 by The North American Benthological Society.

Pseudospectral modeling and dispersion analysis of Rayleigh waves in viscoelastic media

Science.gov (United States)

Zhang, K.; Luo, Y.; Xia, J.; Chen, C.

2011-01-01

Multichannel Analysis of Surface Waves (MASW) is one of the most widely used techniques in environmental and engineering geophysics to determine shear-wave velocities and dynamic properties, which is based on the elastic layered system theory. Wave propagation in the Earth, however, has been recognized as viscoelastic and the propagation of Rayleigh waves presents substantial differences in viscoelastic media as compared with elastic media. Therefore, it is necessary to carry out numerical simulation and dispersion analysis of Rayleigh waves in viscoelastic media to better understand Rayleigh-wave behaviors in the real world. We apply a pseudospectral method to the calculation of the spatial derivatives using a Chebyshev difference operator in the vertical direction and a Fourier difference operator in the horizontal direction based on the velocity-stress elastodynamic equations and relations of linear viscoelastic solids. This approach stretches the spatial discrete grid to have a minimum grid size near the free surface so that high accuracy and resolution are achieved at the free surface, which allows an effective incorporation of the free surface boundary conditions since the Chebyshev method is nonperiodic. We first use an elastic homogeneous half-space model to demonstrate the accuracy of the pseudospectral method comparing with the analytical solution, and verify the correctness of the numerical modeling results for a viscoelastic half-space comparing the phase velocities of Rayleigh wave between the theoretical values and the dispersive image generated by high-resolution linear Radon transform. We then simulate three types of two-layer models to analyze dispersive-energy characteristics for near-surface applications. Results demonstrate that the phase velocity of Rayleigh waves in viscoelastic media is relatively higher than in elastic media and the fundamental mode increases by 10-16% when the frequency is above 10. Hz due to the velocity dispersion of P

Determination of selected UV filters in indoor dust by matrix solid-phase dispersion and gas chromatography-tandem mass spectrometry.

Science.gov (United States)

Negreira, N; Rodríguez, I; Rubí, E; Cela, R

2009-07-31

A simple, inexpensive sample preparation procedure, based on the matrix solid-phase dispersion (MSPD) technique, for the determination of six UV filters: 2-ethylhexyl salicylate (EHS), 3,3,5-trimethylcyclohexyl salicylate (Homosalate, HMS), 3-(4-methylbenzylidene) camphor (4-MBC), isoamyl-p-methoxycinnamate (IAMC), 2-ethylhexyl-p-methoxycinnamate (EHMC) and octocrylene (OCR), in dust from indoor environments is presented and the influence of several operational parameters on the extraction performance discussed. Under the final working conditions, sieved samples (0.5 g) were mixed with the same amount of anhydrous sodium sulphate and dispersed with 2 g of octadecyl bonded silica (C18) in a mortar with a pestle. This blend was transferred to a polypropylene solid-phase extraction cartridge containing 2 g of activated silica, as the clean-up co-sorbent. The cartridge was first rinsed with 5 mL of n-hexane and the analytes were then recovered with 4 mL of acetonitrile. This extract was adjusted to 1 mL, filtered and the compounds were determined by gas chromatography combined with tandem mass spectrometry (GC-MS/MS). Recoveries for samples spiked at two different concentrations ranged between 77% and 99%, and the limits of quantification (LOQs) of the method between 10 and 40 ng g(-1). Analysis of settled dust from different indoor areas, including private flats, public buildings and vehicle cabins, showed that EHMC and OCR were ubiquitous in this matrix, with maximum concentrations of 15 and 41 microg g(-1), respectively. Both UV filters were also quantified in dust reference material SRM 2585 for first time. EHS, 4-MBC and IAMC were detected in some of the analyzed samples, although at lower concentrations than EHMC and OCR.

Determination of ten pyrethroids in various fruit juices: comparison of dispersive liquid-liquid microextraction sample preparation and QuEChERS method combined with dispersive liquid-liquid microextraction.

Science.gov (United States)

Zhang, Yaohai; Zhang, Xuelian; Jiao, Bining

2014-09-15

Dispersive liquid-liquid microextraction (DLLME) sample preparation and the quick, easy, cheap, effective, rugged and safe (QuEChERS) method combined with DLLME were developed and compared for the analysis of ten pyrethroids in various fruit juices using gas chromatography-electron capture detection (GC-ECD). QuEChERS-DLLME method has found its widespread applications to all the fruit juices including those samples with more complex matrices (orange, lemon, kiwi and mango) while DLLME was confined to the fruit juices with simpler matrices (apple, pear, grape and peach). The two methods provided acceptable recoveries and repeatability. In addition, the applicabilities of two methods were demonstrated with the real samples and further confirmed by gas chromatography-mass spectrometry (GC-MS). Copyright © 2014. Published by Elsevier Ltd.

An efficient approach to transient turbulent dispersion modeling by CFD-statistical analysis of a many-puff system

International Nuclear Information System (INIS)

Ching, W-H; K H Leung, Michael; Leung, Dennis Y C

2009-01-01

Transient turbulent dispersion phenomena can be found in various practical problems, such as the accidental release of toxic chemical vapor and the airborne transmission of infectious droplets. Computational fluid dynamics (CFD) is an effective tool for analyzing such transient dispersion behaviors. However, the transient CFD analysis is often computationally expensive and time consuming. In the present study, a computationally efficient CFD-statistical hybrid modeling method has been developed for studying transient turbulent dispersion. In this method, the source emission is represented by emissions of many infinitesimal puffs. Statistical analysis is performed to obtain first the statistical properties of the puff trajectories and subsequently the most probable distribution of the puff trajectories that represent the macroscopic dispersion behaviors. In two case studies of ambient dispersion, the numerical modeling results obtained agree reasonably well with both experimental measurements and conventional k-ε modeling results published in the literature. More importantly, the proposed many-puff CFD-statistical hybrid modeling method effectively reduces the computational time by two orders of magnitude.

Molecularly Imprinted Nanomicrospheres as Matrix Solid-Phase Dispersant Combined with Gas Chromatography for Determination of Four Phosphorothioate Pesticides in Carrot and Yacon

Directory of Open Access Journals (Sweden)

Mengchun Zhou

2015-01-01

Full Text Available An efficient, rapid, and selective method for sample pretreatment, namely, molecularly imprinted matrix solid-phase dispersion (MI-MSPD coupled with gas chromatography (GC, was developed for the rapid isolation of four phosphorothioate organophosphorus pesticides (tolclofos-methyl, phoxim, chlorpyrifos, and parathion-methyl from carrot and yacon samples. New molecularly imprinted polymer nanomicrospheres were synthesized by using typical structural analogue tolclofos-methyl as a dummy template via surface grafting polymerization on nanosilica. Then, these four pesticides in carrot and yacon were extracted and adsorbed using the imprinted nanomicrospheres and further determined by gas chromatography. Under the optimized conditions, a good linearity of four pesticides was obtained in a range of 0.05–17.0 ng·g−1 with R varying from 0.9971 to 0.9996, and the detection limit of the method was 0.012~0.026 ng·g−1 in carrot and yacon samples. The recovery rates at two spiked levels were in the range of 85.4–105.6% with RSD ≤9.6%. The presented MI-MSPD method combined the advantages of MSPD for allowing the extraction, dispersion, and homogenization in two steps and the advantages of MIPs for high affinity and selectivity towards four phosphorothioate pesticides, which could be applied to the determination of pesticide residues in complicated vegetal samples.

Gas analysis by computer-controlled microwave rotational spectrometry

International Nuclear Information System (INIS)

Hrubesh, L.W.

1978-01-01

Microwave rotational spectrometry has inherently high resolution and is thus nearly ideal for qualitative gas mixture analysis. Quantitative gas analysis is also possible by a simplified method which utilizes the ease with which molecular rotational transitions can be saturated at low microwave power densities. This article describes a computer-controlled microwave spectrometer which is used to demonstrate for the first time a totally automated analysis of a complex gas mixture. Examples are shown for a complete qualitative and quantitative analysis, in which a search of over 100 different compounds is made in less than 7 min, with sensitivity for most compounds in the 10 to 100 ppm range. This technique is expected to find increased use in view of the reduced complexity and increased reliabiity of microwave spectrometers and because of new energy-related applications for analysis of mixtures of small molecules

Nanomechanical IR spectroscopy for fast analysis of liquid-dispersed engineered nanomaterials

OpenAIRE

Andersen, Alina Joukainen; Yamada, Shoko; Ek, Pramod Kumar; Andresen, Thomas Lars; Boisen, Anja; Schmid, Silvan

2016-01-01

The proliferated use of engineered nanomaterials (ENMs), e.g. in nanomedicine, calls for novel techniques allowing for fast and sensitive analysis of minute samples. Here we present nanomechanical IR spectroscopy (NAM-IR) for chemical analysis of picograms of ENMs. ENMs are nebulized directly from dispersion and efficiently collected on nanomechanical string resonators through a non-diffusion limited sampling method. Even very small amounts of sample can convert absorbed IR light into a measu...

Modeling and preliminary analysis on the temperature profile of the (TRU-Zr)-Zr dispersion fuel rod for HYPER

International Nuclear Information System (INIS)

Lee, B. W.; Hwang, W.; Lee, B. S.; Park, W. S.

2000-01-01

Either TRU-Zr metal alloy or (TRU-Zr)-Zr dispersion fuel is considered as a blanket fuel for HYPER(Hybrid Power Extraction Reactor). In order to develop the code for dispersion fuel rod performance analysis under steady state condition, the fuel temperature distribution model which is the one of the most important factors in a fuel performance code has been developed in this paper,. This developed model computes the one dimensional radial temperature distribution of a cylindrical fuel rod. The temperature profile results by this model are compared with the temperature distributions of U 3 Si-A1 dispersion fuel and TRU-Zr metal alloy fuel. This model will be installed in performance analysis code for dispersion fuel

Possibilities of gas-phase radio-chromatography application to permanent-gas analysis

International Nuclear Information System (INIS)

Dupuis, M.C.; Charrier, G.; Alba, C.; Massimino, D.

1970-01-01

The gas-phase radio-chromatography technique has been applied to the rapid analysis of permanent gases (H 2 , O 2 , N 2 , A, Kr, Xe, CO, CH 4 ) labelled with radioactive indicators ( 3 H, 37 A, 85 Kr, 133 Xe). After calibration, the components of such a mixture can be identified and their concentrations measured in less than two hours, using a sample volume of from 0.1 to 10 cm 3 . The minimum detectable activity is of the order of 10 -4 μC for each radioactive isotope. The measurements are reproducible to about 2 to 3 per cent. This work has been mainly concerned with the influence of parameters affecting the response of the radioactivity detector (ionization chamber or gas flow proportional counter). The method has very numerous applications both theoretically, for the study of chromatographic phenomena under ideal conditions (infinitesimal concentrations made possible by the use of radioactive tracers), and practically, for rapid and accurate radiochemical analysis of radioactive gas mixtures. (authors) [fr

Testing of a new dense gas approach in the Lagrangian Dispersion Model SPRAY.

Science.gov (United States)

Mortarini, Luca; Alessandrini, Stefano; Ferrero, Enrico; Anfossi, Domenico; Manfrin, Massimiliano

2013-04-01

A new original method for the dispersion of a positively and negatively buoyant plume is proposed. The buoyant pollutant movement is treated introducing a fictitious scalar inside the Lagrangian Stochastic Particle Model SPRAY. The method is based on the same idea of Alessandrini and Ferrero (Phys. A 388:1375-1387, 2009) for the treatment of a background substance entrainment into the plume. In this application, the fictitious scalar is the density and momentum difference between the plume portions and the environment air that naturally takes into account the interaction between the plume and the environment. As a consequence, no more particles than those inside the plume have to be released to simulate the entrainment of the background air temperature. In this way the entrainment is properly simulated and the plume sink is calculated from the local property of the flow. This new approach is wholly Lagrangian in the sense that the Eulerian grid is only used to compute the propriety of a portion of the plume from the particles contained in every cell. No equation of the bulk plume is solved on a fixed grid. To thoroughly test the turbulent velocity field calculated by the model, the latter is compared with a water tank experiment carried out in the TURLAB laboratory in Turin (Italy). A vertical density driven current was created releasing a saline solution (salt and water) in a water tank with no mean flow. The experiment reproduces in physical similarity, based on the density Froud number, the release of a dense gas in the planetary boundary layer and the Particle Image Velocimetry technique has been used to analyze the buoyancy generated velocity field. The high temporal and spatial resolution of the measurements gives a deep insight to the problems of the bouncing of the dense gas and of the creation of the outflow velocity at the ground.

Probabilistic Analysis of Gas Turbine Field Performance

Science.gov (United States)

Gorla, Rama S. R.; Pai, Shantaram S.; Rusick, Jeffrey J.

2002-01-01

A gas turbine thermodynamic cycle was computationally simulated and probabilistically evaluated in view of the several uncertainties in the performance parameters, which are indices of gas turbine health. Cumulative distribution functions and sensitivity factors were computed for the overall thermal efficiency and net specific power output due to the thermodynamic random variables. These results can be used to quickly identify the most critical design variables in order to optimize the design, enhance performance, increase system availability and make it cost effective. The analysis leads to the selection of the appropriate measurements to be used in the gas turbine health determination and to the identification of both the most critical measurements and parameters. Probabilistic analysis aims at unifying and improving the control and health monitoring of gas turbine aero-engines by increasing the quality and quantity of information available about the engine's health and performance.

Gas atomized precursor alloy powder for oxide dispersion strengthened ferritic stainless steel

Energy Technology Data Exchange (ETDEWEB)

Rieken, Joel [Iowa State Univ., Ames, IA (United States)

2011-12-13

Gas atomization reaction synthesis (GARS) was employed as a simplified method for producing precursor powders for oxide dispersion strengthened (ODS) ferritic stainless steels (e.g., Fe-Cr-Y-(Ti,Hf)-O), departing from the conventional mechanical alloying (MA) process. During GARS processing a reactive atomization gas (i.e., Ar-O₂) was used to oxidize the powder surfaces during primary break-up and rapid solidification of the molten alloy. This resulted in envelopment of the powders by an ultra-thin (t < 150 nm) metastable Cr-enriched oxide layer that was used as a vehicle for solid-state transport of O into the consolidated microstructure. In an attempt to better understand the kinetics of this GARS reaction, theoretical cooling curves for the atomized droplets were calculated and used to establish an oxidation model for this process. Subsequent elevated temperature heat treatments, which were derived from Rhines pack measurements using an internal oxidation model, were used to promote thermodynamically driven O exchange reactions between trapped films of the initial Cr-enriched surface oxide and internal Y-enriched intermetallic precipitates. This novel microstructural evolution process resulted in the successful formation of nano-metric Y-enriched dispersoids, as confirmed using high energy X-ray diffraction and transmission electron microscopy (TEM), equivalent to conventional ODS alloys from MA powders. The thermal stability of these Y-enriched dispersoids was evaluated using high temperature (1200°C) annealing treatments ranging from 2.5 to 1,000 hrs of exposure. In a further departure from current ODS practice, replacing Ti with additions of Hf appeared to improve the Y-enriched dispersoid thermal stability by means of crystal structure modification. Additionally, the spatial distribution of the dispersoids was found to depend strongly on the original rapidly solidified microstructure. To exploit this, ODS microstructures were engineered from

Attenuation and velocity dispersion in the exploration seismic frequency band

Science.gov (United States)

Sun, Langqiu

In an anelastic medium, seismic waves are distorted by attenuation and velocity dispersion, which depend on petrophysical properties of reservoir rocks. The effective attenuation and velocity dispersion is a combination of intrinsic attenuation and apparent attenuation due to scattering, transmission response, and data acquisition system. Velocity dispersion is usually neglected in seismic data processing partly because of insufficient observations in the exploration seismic frequency band. This thesis investigates the methods of measuring velocity dispersion in the exploration seismic frequency band and interprets the velocity dispersion data in terms of petrophysical properties. Broadband, uncorrelated vibrator data are suitable for measuring velocity dispersion in the exploration seismic frequency band, and a broad bandwidth optimizes the observability of velocity dispersion. Four methods of measuring velocity dispersion in uncorrelated vibrator VSP data are investigated, which are the sliding window crosscorrelation (SWCC) method, the instantaneous phase method, the spectral decomposition method, and the cross spectrum method. Among them, the SWCC method is a new method and has satisfactory robustness, accuracy, and efficiency. Using the SWCC method, velocity dispersion is measured in the uncorrelated vibrator VSP data from three areas with different geological settings, i.e., Mallik gas hydrate zone, McArthur River uranium mines, and Outokumpu crystalline rocks. The observed velocity dispersion is fitted to a straight line with respect to log frequency for a constant (frequency-independent) Q value. This provides an alternative method for calculating Q. A constant Q value does not directly link to petrophysical properties. A modeling study is implemented for the Mallik and McArthur River data to interpret the velocity dispersion observations in terms of petrophysical properties. The detailed multi-parameter petrophysical reservoir models are built according to

Determination of solvent concentration-dependent dispersion in the vapor extraction (VAPEX) process

Energy Technology Data Exchange (ETDEWEB)

Abukhalifeh, H.; Lohi, A.; Upreti, S. [Ryerson Polytechnic Univ., Toronto, ON (Canada)

2008-07-01

This paper presented the results of a computational algorithm that revealed the optimal conditions required for vapor extraction (VAPEX) for a solvent gas-heavy oil system. VAPEX is a promising recovery process because it requires low energy use and emits fewer greenhouse gases to the atmosphere compared to other enhanced oil recovery methods. The process is governed by the dispersion of solvent gases into heavy oil and bitumen. As such, it is essential to accurately determine solvent dispersion in VAPEX in order to effectively predict the amount and time scale of oil recovery, and to optimize field operations. VAPEX experiments were conducted in this study to determined the dispersion coefficient of a solvent as a function of its concentration in heavy oil and bitumen. The principles of variational calculus were used together with a mass transfer model of the experimental process. It was concluded that the oil production determined by the model should agree with its experimental counterpart, given the optimal gas dispersion versus concentration function.

An anomalous extinction law in the Cep OB3b young cluster: Evidence for dust processing during gas dispersal

International Nuclear Information System (INIS)

Allen, Thomas S.; Prchlik, Jakub J.; Megeath, S. Thomas; Gutermuth, Robert A.; Pipher, Judith L.; Naylor, Tim; Jeffries, R. D.

2014-01-01

We determine the extinction law through Cep OB3b, a young cluster of 3000 stars undergoing gas dispersal. The extinction is measured toward 76 background K giants identified with MMT/Hectospec spectra. Color excess ratios were determined toward each of the giants using V and R photometry from the literature, g, r, i, and z photometry from the Sloan Digital Sky Survey and J, H, and K s photometry from the Two Micron All Sky Survey. These color excess ratios were then used to construct the extinction law through the dusty material associated with Cep OB3b. The extinction law through Cep OB3b is intermediate between the R V = 3.1 and R V = 5 laws commonly used for the diffuse atomic interstellar medium and dense molecular clouds, respectively. The dependence of the extinction law on line-of-sight A V is investigated and we find the extinction law becomes shallower for regions with A V > 2.5 mag. We speculate that the intermediate dust law results from dust processing during the dispersal of the molecular cloud by the cluster.

An anomalous extinction law in the Cep OB3b young cluster: Evidence for dust processing during gas dispersal

Energy Technology Data Exchange (ETDEWEB)

Allen, Thomas S.; Prchlik, Jakub J.; Megeath, S. Thomas [University of Toledo, Ritter Astrophysical Observatory, Department of Physics and Astronomy, Toledo, OH 43606 (United States); Gutermuth, Robert A. [Five College Astronomy Department, Smith College, Northampton, MA 01063 (United States); Pipher, Judith L. [Department of Physics and Astronomy, University of Rochester, Rochester, NY 14627 (United States); Naylor, Tim [School of Physics, University of Exeter, Exeter, UK EX4 4QL (United Kingdom); Jeffries, R. D. [Astrophysics Group, School of Physical and Geographical Sciences, Keele University, Keele, Staffordshire, UK ST5 5BG (United Kingdom)

2014-05-10

We determine the extinction law through Cep OB3b, a young cluster of 3000 stars undergoing gas dispersal. The extinction is measured toward 76 background K giants identified with MMT/Hectospec spectra. Color excess ratios were determined toward each of the giants using V and R photometry from the literature, g, r, i, and z photometry from the Sloan Digital Sky Survey and J, H, and K{sub s} photometry from the Two Micron All Sky Survey. These color excess ratios were then used to construct the extinction law through the dusty material associated with Cep OB3b. The extinction law through Cep OB3b is intermediate between the R{sub V} = 3.1 and R{sub V} = 5 laws commonly used for the diffuse atomic interstellar medium and dense molecular clouds, respectively. The dependence of the extinction law on line-of-sight A{sub V} is investigated and we find the extinction law becomes shallower for regions with A{sub V} > 2.5 mag. We speculate that the intermediate dust law results from dust processing during the dispersal of the molecular cloud by the cluster.

On-line gas chromatographic analysis of airborne particles

Science.gov (United States)

Hering, Susanne V [Berkeley, CA; Goldstein, Allen H [Orinda, CA

2012-01-03

A method and apparatus for the in-situ, chemical analysis of an aerosol. The method may include the steps of: collecting an aerosol; thermally desorbing the aerosol into a carrier gas to provide desorbed aerosol material; transporting the desorbed aerosol material onto the head of a gas chromatography column; analyzing the aerosol material using a gas chromatograph, and quantizing the aerosol material as it evolves from the gas chromatography column. The apparatus includes a collection and thermal desorption cell, a gas chromatograph including a gas chromatography column, heated transport lines coupling the cell and the column; and a quantization detector for aerosol material evolving from the gas chromatography column.

Ammonia Gas Sensing Behavior of Tanninsulfonic Acid Doped Polyaniline-TiO2 Composite

Directory of Open Access Journals (Sweden)

Venu Gopal Bairi

2015-10-01

Full Text Available A highly active tannin doped polyaniline-TiO2 composite ammonia gas sensor was developed and the mechanism behind the gas sensing activity was reported for the first time. A tanninsulfonic acid doped polyaniline (TANIPANI-titanium dioxide nanocomposite was synthesized by an in situ polymerization of aniline in the presence of tanninsulfonic acid and titanium dioxide nanoparticles. X-ray diffraction and thermogravimetric analysis were utilized to determine the incorporation of TiO2 in TANIPANI matrix. UV-Visible and infrared spectroscopy studies provided information about the electronic interactions among tannin, polyaniline, and TiO2. Scanning electron microscopy (SEM along with energy dispersive X-ray spectroscopy (EDS and atomic force microscopy (AFM surface analysis techniques were used to investigate the metal oxide dispersions inside polyaniline matrix. Gas sensors were prepared by spin coating solutions of TANIPANI-TiO2 and TANIPANI composites onto glass slides. Sensors were tested at three different concentrations (20 ppm, 40 ppm, and 60 ppm of ammonia gas at ambient temperature conditions by measuring the changes in surface resistivity of the films with respect to time. Ammonia gas sensing plots are presented showing the response values, response times and recovery times. The TANIPANI-TiO2 composite exhibited better response and shorter recovery times when compared to TANIPANI control and other polyaniline composites that have been reported in the literature. For the first time a proposed mechanism of gas sensing basing on the polaron band localization and its effects on the gas sensing behavior of polyaniline are reported.

Measurement and simulation of the turbulent dispersion of a radioactive tracer in a two-phase flow system

Energy Technology Data Exchange (ETDEWEB)

Hensel, F; Rohde, U

1998-10-01

The turbulent dispersion of a radiotracer in an experimental setup with a natural convection liquid-gaseous flow was investigated. A liquid-gaseous bubbly flow was generated in a narrow tank by injection of pressurized air into water or by catalytic disintegration of H{sub 2}O{sub 2}. Turbulent Prandtl numbers for gas and tracer dispersion were varied. In the case of higher gas superficial velocities (J{sub gas}{approx}5-15 mm/s), a reasonable agreement was achieved between calculated and measured tracer transport velocity and dispersion coefficient values. A nearly linear correlation between j{sub gas} and D was found in agreement with other authors. The calculation results contribute to a better understanding of the phenomena and interpretation of the measurement results as well as to the validation of the CFD code for turbulent two-phase flow applications. Further investigations are necessary to improve the agreement in the cases of H{sub 2}O{sub 2} disintegration and low gas superficial velocities. (orig.)

Measurement and simulation of the turbulent dispersion of a radioactive tracer in a two-phase flow system

International Nuclear Information System (INIS)

Hensel, F.; Rohde, U.

1998-01-01

The turbulent dispersion of a radiotracer in an experimental setup with a natural convection liquid-gaseous flow was investigated. A liquid-gaseous bubbly flow was generated in a narrow tank by injection of pressurized air into water or by catalytic disintegration of H 2 O 2 . Turbulent Prandtl numbers for gas and tracer dispersion were varied. In the case of higher gas superficial velocities (J gas ∼5-15 mm/s), a reasonable agreement was achieved between calculated and measured tracer transport velocity and dispersion coefficient values. A nearly linear correlation between j gas and D was found in agreement with other authors. The calculation results contribute to a better understanding of the phenomena and interpretation of the measurement results as well as to the validation of the CFD code for turbulent two-phase flow applications. Further investigations are necessary to improve the agreement in the cases of H 2 O 2 disintegration and low gas superficial velocities. (orig.)

Definition of regional dependence of activity antioxidative enzymes means of the dispersive analysis

Directory of Open Access Journals (Sweden)

Anatoly T. Bykov

2011-05-01

Full Text Available In article application of the dispersive analysis for an estimation of dependence of activity antioxidative enzymes from region of constant residing, age, sex and the disease diagnosis is considered.

Quantitative analysis of deuterium by gas chromatography

International Nuclear Information System (INIS)

Isomura, Shohei; Kaetsu, Hayato

1981-01-01

An analytical method for the determination of deuterium concentration in water and hydrogen gas by gas chromatography is described. HD and D 2 in a hydrogen gas sample were separated from H 2 by a column packed with Molecular Sieve 13X, using extra pure hydrogen gas as carrier. A thermal conductivity detector was used. Concentrations of deuterium were determined by comparison with standard samples. The error inherent to the present method was less a 1% on the basis of the calibration curves obtained with the standard samples. The average time required for the analysis was about 3 minutes. (author)

Dispersion bias, dispersion effect, and the aerosol-cloud conundrum

International Nuclear Information System (INIS)

Liu Yangang; Daum, Peter H; Guo Huan; Peng Yiran

2008-01-01

This work examines the influences of relative dispersion (the ratio of the standard deviation to the mean radius of the cloud droplet size distribution) on cloud albedo and cloud radiative forcing, derives an analytical formulation that accounts explicitly for the contribution from droplet concentration and relative dispersion, and presents a new approach to parameterize relative dispersion in climate models. It is shown that inadequate representation of relative dispersion in climate models leads to an overestimation of cloud albedo, resulting in a negative bias of global mean shortwave cloud radiative forcing that can be comparable to the warming caused by doubling CO 2 in magnitude, and that this dispersion bias is likely near its maximum for ambient clouds. Relative dispersion is empirically expressed as a function of the quotient between cloud liquid water content and droplet concentration (i.e., water per droplet), yielding an analytical formulation for the first aerosol indirect effect. Further analysis of the new expression reveals that the dispersion effect not only offsets the cooling from the Twomey effect, but is also proportional to the Twomey effect in magnitude. These results suggest that unrealistic representation of relative dispersion in cloud parameterization in general, and evaluation of aerosol indirect effects in particular, is at least in part responsible for several outstanding puzzles of the aerosol-cloud conundrum: for example, overestimation of cloud radiative cooling by climate models compared to satellite observations; large uncertainty and discrepancy in estimates of the aerosol indirect effect; and the lack of interhemispheric difference in cloud albedo.

The Use of Gas Chromatography for Biogas Analysis

Science.gov (United States)

Andersen, Amanda; Seeley, John; Aurandt, Jennifer

2010-04-01

Energy from natural gas accounts for 24 percent of energy consumed in the US. Natural gas is a robust form of energy which is rich in methane content and is low in impurities. This quality suggests that it is a very clean and safe gas; it can be used in providing heat, a source for cooking, and in powering vehicles. The downside is that it is a non-renewable resource. On the contrary, methane rich gas that is produced by the breakdown of organic material in an anaerobic environment, called biogas, is a renewable energy source. This research focuses on the gas analysis portion of the creation of the anaerobic digestion and verification laboratory where content and forensic analysis of biogas is performed. Gas Chromatography is implemented as the optimal analytical tool for quantifying the components of the biogas including methane, carbon dioxide, hydrogen sulfide and siloxanes. In addition, the problems associated with the undesirable components are discussed. Anaerobic digestion of primary sludge has consistently produced about 55 percent methane; future goals of this research include studying different substrates to increase the methane yield and decrease levels of impurities in the gas.

Frequency dispersion analysis of thin dielectric MOS capacitor in a five-element model

Science.gov (United States)

Zhang, Xizhen; Zhang, Sujuan; Zhu, Huichao; Pan, Xiuyu; Cheng, Chuanhui; Yu, Tao; Li, Xiangping; Cheng, Yi; Xing, Guichao; Zhang, Daming; Luo, Xixian; Chen, Baojiu

2018-02-01

An Al/ZrO2/IL/n-Si (IL: interface layer) MOS capacitor has been fabricated by metal organic decomposition of ZrO2 and thermal deposition Al. We have measured parallel capacitance (C m) and parallel resistance (R m) versus bias voltage curves (C m, R m-V) at different AC signal frequency (f), and C m, R m-f curves at different bias voltage. The curves of C m, R m-f measurements show obvious frequency dispersion in the range of 100 kHz-2 MHz. The energy band profile shows that a large voltage is applied on the ZrO2 layer and IL at accumulation, which suggests possible dielectric polarization processes by some traps in ZrO2 and IL. C m, R m-f data are used for frequency dispersion analysis. To exclude external frequency dispersion, we have extracted the parameters of C (real MOS capacitance), R p (parallel resistance), C IL (IL capacitance), R IL (IL resistance) and R s (Si resistance) in a five-element model by using a three-frequency method. We have analyzed intrinsic frequency dispersion of C, R p, C IL, R IL and R s by studying the dielectric characteristics and Si surface layer characteristics. At accumulation, the dispersion of C and R p is attributed to dielectric polarization such as dipolar orientation and oxide traps. The serious dispersion of C IL and R IL are relative to other dielectric polarization, such as border traps and fixed oxide traps. The dispersion of R s is mainly attributed to contact capacitance (C c) and contact resistance (R c). At depletion and inversion, the frequency dispersion of C, R p, C IL, R IL, and R s are mainly attributed to the depletion layer capacitance (C D). The interface trap capacitance (C it) and interface trap resistance (R it) are not dominant for the dispersion of C, R p, C IL, R IL, and R s.

Analysis in temporal regime of dispersive invisible structures designed from transformation optics

Science.gov (United States)

Gralak, B.; Arismendi, G.; Avril, B.; Diatta, A.; Guenneau, S.

2016-03-01

A simple invisible structure made of two anisotropic homogeneous layers is analyzed theoretically in temporal regime. The frequency dispersion is introduced and analytic expression of the transient part of the field is derived for large times when the structure is illuminated by a causal excitation. This expression shows that the limiting amplitude principle applies with transient fields decaying as the power -3 /4 of the time. The quality of the cloak is then reduced at short times and remains preserved at large times. The one-dimensional theoretical analysis is supplemented with full-wave numerical simulations in two-dimensional situations which confirm the effect of dispersion.

Resistive sensing of gaseous nitrogen dioxide using a dispersion of single-walled carbon nanotubes in an ionic liquid

Energy Technology Data Exchange (ETDEWEB)

Mishra, Prabhash [Solidstate Electronics Research Laboratory (SERL), Faculty of Engineering and Technology, Jamia Millia Islamia, Jamia Nagar, New Delhi 110025 (India); Department of Nanoengineering, Samara State Aerospace University, 443086 Samara (Russian Federation); Pavelyev, V.S. [Department of Nanoengineering, Samara State Aerospace University, 443086 Samara (Russian Federation); Patel, Rajan [Center for Interdisciplinary Research in Basic Sciences (CIRBSc), Jamia Millia Islamia, Jamia Nagar, New Delhi 110025 (India); Islam, S.S., E-mail: sislam@jmi.ac.in [Solidstate Electronics Research Laboratory (SERL), Faculty of Engineering and Technology, Jamia Millia Islamia, Jamia Nagar, New Delhi 110025 (India)

2016-06-15

Graphical abstract: Ionic liquid ([C6-mim]PF6) used as dispersant agent for SWCNTs: An investigations were carried out to find the structural quality and surface modification for sensor application. - Highlights: • An effective technique based on Ionic liquids (IL) and their use as a dispersant. • Electron microscopy and spectroscopy for structure characterization. • Covalent linkage of ILs with SWNTs and dispersion of SWCNTs. • The IL-wrapped sensing film, capable for detecting trace levels of gas. - Abstract: Single-walled carbon nanotubes (SWCNTs) were dispersed in an imidazolium-based ionic liquid (IL) and investigated in terms of structural quality, surface functionalization and inter-CNT force. Analysis by field emission electron microscopy and transmission electron microscopy shows the IL layer to coat the SWNTs, and FTIR and Raman spectroscopy confirm strong binding of the ILs to the SWNTs. Two kinds of resistive sensors were fabricated, one by drop casting of IL-wrapped SWCNTs, the other by conventional dispersion of SWCNTs. Good response and recovery to NO{sub 2} is achieved with the IL-wrapped SWCNTs material upon UV-light exposure, which is needed because decrease the desorption energy barrier to increase the gas molecule desorption. NO{sub 2} can be detected in the 1–20 ppm concentration range. The sensor is not interfered by humidity due to the hydrophobic tail of PF6 (ionic liquid) that makes our sensor highly resistant to moisture.

Fabrication of Ni@Ti core-shell nanoparticles by modified gas aggregation source

Science.gov (United States)

Hanuš, J.; Vaidulych, M.; Kylián, O.; Choukourov, A.; Kousal, J.; Khalakhan, I.; Cieslar, M.; Solař, P.; Biederman, H.

2017-11-01

Ni@Ti core-shell nanoparticles were prepared by a vacuum based method using the gas aggregation source (GAS) of nanoparticles. Ni nanoparticles fabricated in the GAS were afterwards coated by a Ti shell. The Ti shell was deposited by means of magnetron sputtering. The Ni nanoparticles were decelerated in the vicinity of the magnetron to the Ar drift velocity in the second deposition chamber. X-ray photoelectron spectroscopy and energy dispersive x-ray spectroscopy analysis of the nanoparticles showed the core-shell structure. It was shown that the thickness of the shell can be easily tuned by the process parameters with a maximum achieved thickness of the Ti shell ~2.5 nm. The core-shell structure was confirmed by the STEM analysis of the particles.

Analysis of natural gas supply strategies at Fort Drum

International Nuclear Information System (INIS)

Stucky, D.J.; Shankle, S.A.; Anderson, D.M.

1992-07-01

This analysis investigates strategies for Fort Drum to acquire a reliable natural gas supply while reducing its gas supply costs. The purpose of this study is to recommend an optimal supply mix based on the life-cycle costs of each strategy analyzed. In particular, this study is intended to provide initial guidance as to whether or not the building and operating of a propane-air mixing station is a feasible alternative to the current gas acquisition strategy. The analysis proceeded by defining the components of supply (gas purchase, gas transport, supplemental fuel supply); identifying alternative options for each supply component; constructing gas supply strategies from different combinations of the options available for each supply component and calculating the life-cycle costs of each supply strategy under a set of different scenarios reflecting the uncertainty of future events

Numerical Study of Particle Interaction in Gas-Particle and Liquid-Particle Flows: Part I Analysis and Validation

Directory of Open Access Journals (Sweden)

K. Mohanarangam

2009-09-01

Full Text Available A detailed study into the turbulent behaviour of dilute particulate flow under the influence of two carrier phases namely gas and liquid has been carried out behind a sudden expansion geometry. The major endeavour of the study is to ascertain the response of the particles within the carrier (gas or liquid phase. The main aim prompting the current study is the density difference between the carrier and the dispersed phases. While the ratio is quite high in terms of the dispersed phase for the gas-particle flows, the ratio is far more less in terms of the liquid-particle flows. Numerical simulations were carried out for both these classes of flows using an Eulerian two-fluid model with RNG based k-emodel as the turbulent closure. An additional kinetic energy equation to better represent the combined fluid-particle behaviour is also employed in the current set of simulations. In the first part of this two part series, experimental results of Fessler and Eaton (1995 for Gas-Particle (GP flow and that of Founti and Klipfel (1998 for Liquid-Particle (LP flow have been compared and analysed. This forms the basis of the current study which aims to look at the particulate behaviour under the influence of two carrier phases. Further numerical simulations were carried out to test whether the current numerical formulation can used to simulate these varied type of flows and the same were validated against the experimental data of both GP as well LP flow. Qualitative results have been obtained for both these classes of flows with their respective experimental data both at the mean as well as at the turbulence level for carrier as well as the dispersed phases.

Cefuroxime axetil solid dispersions prepared using solution enhanced dispersion by supercritical fluids.

Science.gov (United States)

Jun, Seoung Wook; Kim, Min-Soo; Jo, Guk Hyun; Lee, Sibeum; Woo, Jong Soo; Park, Jeong-Sook; Hwang, Sung-Joo

2005-12-01

Cefuroxime axetil (CA) solid dispersions with HPMC 2910/PVP K-30 were prepared using solution enhanced dispersion by supercritical fluids (SEDS) in an effort to increase the dissolution rate of poorly water-soluble drugs. Their physicochemical properties in solid state were characterized by differential scanning calorimeter (DSC), powder X-ray diffraction (PXRD), Fourier transform infrared spectrometry (FT-IR) and scanning electron microscopy. No endothermic and characteristic diffraction peaks corresponding to CA were observed for the solid dispersions in DSC and PXRD. FTIR analysis demonstrated the presence of intermolecular hydrogen bonds between CA and HPMC 2910/PVP K-30 in solid dispersions, resulting in the formation of amorphous or non-crystalline CA. Dissolution studies indicated that the dissolution rates were remarkably increased in solid dispersions compared with those in the physical mixture and drug alone. In conclusion, an amorphous or non-crystalline CA solid dispersion prepared using SEDS could be very useful for the formulation of solid dosage forms.

Photon induced x-ray fluorescence analysis using energy dispersive detector and dichotomous sampler

International Nuclear Information System (INIS)

Jaklevic, J.M.; Loo, B.W.; Goulding, F.S.

1976-01-01

Operating experience in using the photon-excited energy-dispersive x-ray fluorescence analysis system has demonstrated the applicability of this technique to large-scale air-sampling networks. This experience has shown that it is possible to perform automatic sampling and analysis of aerosol particulates at a sensitivity and accuracy more than adequate for most air pollution studies

Characteristic Value Method of Well Test Analysis for Horizontal Gas Well

Directory of Open Access Journals (Sweden)

Xiao-Ping Li

2014-01-01

Full Text Available This paper presents a study of characteristic value method of well test analysis for horizontal gas well. Owing to the complicated seepage flow mechanism in horizontal gas well and the difficulty in the analysis of transient pressure test data, this paper establishes the mathematical models of well test analysis for horizontal gas well with different inner and outer boundary conditions. On the basis of obtaining the solutions of the mathematical models, several type curves are plotted with Stehfest inversion algorithm. For gas reservoir with closed outer boundary in vertical direction and infinite outer boundary in horizontal direction, while considering the effect of wellbore storage and skin effect, the pseudopressure behavior of the horizontal gas well can manifest four characteristic periods: pure wellbore storage period, early vertical radial flow period, early linear flow period, and late horizontal pseudoradial flow period. For gas reservoir with closed outer boundary both in vertical and horizontal directions, the pseudopressure behavior of the horizontal gas well adds the pseudosteady state flow period which appears after the boundary response. For gas reservoir with closed outer boundary in vertical direction and constant pressure outer boundary in horizontal direction, the pseudopressure behavior of the horizontal gas well adds the steady state flow period which appears after the boundary response. According to the characteristic lines which are manifested by pseudopressure derivative curve of each flow period, formulas are developed to obtain horizontal permeability, vertical permeability, skin factor, reservoir pressure, and pore volume of the gas reservoir, and thus the characteristic value method of well test analysis for horizontal gas well is established. Finally, the example study verifies that the new method is reliable. Characteristic value method of well test analysis for horizontal gas well makes the well test analysis

Irradiation behavior of low-enriched U/sub 6/Fe-Al dispersion fuel elements

Energy Technology Data Exchange (ETDEWEB)

Hofman, G.L.; Domagala, R.F.; Copeland, G.L.

1987-10-01

An irradiation test of miniature fuel plates containing low-enriched (20% /sup 235/U)U/sub 6/Fe dispersed and clad in Al was performed. The postirradiation examination shows U/sub 6/Fe to form extensive fission gas bubbles at burnups of only approx. = 20% of the original 20% fuel enrichment. Plate failure by fission gas-driven pillowing occurred at approx. = 40% burnup. This places U/sub 6/FE at the lowest burnup capability among low enriched dispersion fuels that have been tested for use in research and test reactors

Development of a FBR fuel pin bundle deformation analysis code 'BAMBOO' . Development of a dispersion model and its validation

International Nuclear Information System (INIS)

Uwaba, Tomoyuki; Ukai, Shigeharu; Asaga, Takeo

2002-03-01

Bundle Duct Interaction (BDI) is one of the life limiting factors of a FBR fuel subassembly. Under the BDI condition, the fuel pin dispersion would occur mainly by the deviation of the wire position due to the irradiation. In this study the effect of the dispersion on the bundle deformation was evaluated by using the BAMBOO code and following results were obtained. (1) A new contact analysis model was introduced in BAMBOO code. This model considers the contact condition at the axial position other than the nodal point of the beam element that composes the fuel pin. This improvement made it possible in the bundle deformation analysis to cause fuel pin dispersion due to the deviations of the wire position. (2) This model was validated with the results of the out-of-pile compression test with the wire deviation. The calculated pin-to-duct and pin-to-pin clearances with the dispersion model almost agreed with the test results. Therefore it was confirmed that the BAMBOO code reasonably predicts the bundle deformation with the dispersion. (3) In the dispersion bundle the pin-to-pin clearances widely scattered. And the minimum pin-to-duct clearance increased or decreased depending on the dispersion condition compared to the no-dispersion bundle. This result suggests the possibility that the considerable dispersion would affect the thermal integrity of the bundle. (author)

OPIC Greenhouse Gas Emissions Analysis Details

Data.gov (United States)

Overseas Private Investment Corporation — Summary project inventory with independent analysis to quantify the greenhouse gas ("GHG") emissions directly attributable to projects to which the Overseas Private...

Quantitative analysis with energy dispersive X-ray fluorescence analyser

International Nuclear Information System (INIS)

Kataria, S.K.; Kapoor, S.S.; Lal, M.; Rao, B.V.N.

1977-01-01

Quantitative analysis of samples using radioisotope excited energy dispersive x-ray fluorescence system is described. The complete set-up is built around a locally made Si(Li) detector x-ray spectrometer with an energy resolution of 220 eV at 5.94 KeV. The photopeaks observed in the x-ray fluorescence spectra are fitted with a Gaussian function and the intensities of the characteristic x-ray lines are extracted, which in turn are used for calculating the elemental concentrations. The results for a few typical cases are presented. (author)

Surface-plasmon dispersion relation for the inhomogeneous charge-density medium

International Nuclear Information System (INIS)

Harsh, O.K.; Agarwal, B.K.

1989-01-01

The surface-plasmon dispersion relation is derived for the plane-bounded electron gas when there is an inhomogeneous charge-density distribution in the plasma. The hydrodynamical model is used. Both cphi and dcphi/dx are taken to be continuous at the surface of the slab, where cphi is the scalar potential. The dispersion relation is compared with the theoretical works of Stern and Ferrell and of Harsh and Agarwal. It is also compared with the observations of Kunz. A dispersion relation for the volume-plasmon oscillations is derived which resembles the well-known relation of Bohm and Pines

Hypersonic flow past slender bodies in dispersive hydrodynamics

International Nuclear Information System (INIS)

El, G.A.; Khodorovskii, V.V.; Tyurina, A.V.

2004-01-01

The problem of two-dimensional steady hypersonic flow past a slender body is formulated for dispersive media. It is shown that for the hypersonic flow, the original 2+0 boundary-value problem is asymptotically equivalent to the 1+1 piston problem for the fully nonlinear flow in the same physical system, which allows one to take advantage of the analytic methods developed for one-dimensional systems. This type of equivalence, well known in ideal Euler gas dynamics, has not been established for dispersive hydrodynamics so far. Two examples pertaining to collisionless plasma dynamics are considered

Instrumental aspects of tube-excited energy-dispersive X-ray fluorescence analysis

International Nuclear Information System (INIS)

Adams, F.; Nullens, H.; Espen, P. van

1983-01-01

Energy-dispersive X-ray fluorescence spectrometry is an attractive and widely used method for sensitive multi-element analysis. The method suffers from the extreme density of spectral components in a rather limited energy range which implies the need for computer based spectrum analysis. The method of iterative least squares analysis is the most powerful tool for this. It requires a systematic and accurate description of the spectral features. Other important necessities for accurate analysis are the calibration of the spectrometer and the correction for matrix absorption effects in the sample; they can be calculated from available physical constants. Ours and similar procedures prove that semi-automatic analyses are possible with an accuracy of the order of 5%. (author)

Design of broadband dispersion flattened fiber for DWDM system: Performance analysis using various modulation formats

Science.gov (United States)

Goel, Aditya; Pandey, Gaurav

2018-05-01

In this paper, unique design of an optimal broadband optical dispersion flattened fiber (DFF) is proposed, which is capable of supporting the data rate of the order of Tb/s. The analysis of the single mode fiber for the design of the proposed DFF has been carried out by employing the quadratic Finite Element Method (FEM) with generalized refractive index (R. I.) profile. The minimization of the dispersion with respect to various profile parameters within the specified wavelength band is the essential optimization criteria. Computations show that a DFF can be designed where the overall dispersion can be restricted within ± 1 ps/km-nm over the entire spectral span ranging from 1290 to 1540 nm (250 nm) exhibiting a very small maximum value of dispersion slope (± 0.02 ps / (nm2-km)) in particular. The detailed performance analysis of the proposed DFF with different modulation techniques has been carried out in order to critically evaluate the performance of the DFF with respect to various significant parameters. The results suggest an excellent design of broadband optical waveguide capable of supporting high-speed data rate (40 Tb/s) through the single DFF, ideally suitable for the long haul dense wavelength division multiplexing (DWDM) optical transmission systems.

Development of a new microextraction method based on elevated temperature dispersive liquid-liquid microextraction for determination of triazole pesticides residues in honey by gas chromatography-nitrogen phosphorus detection.

Science.gov (United States)

Farajzadeh, Mir Ali; Mogaddam, Mohammad Reza Afshar; Ghorbanpour, Houshang

2014-06-20

In the present study, a rapid, highly efficient, and reliable sample preparation method named "elevated temperature dispersive liquid-liquid microextraction" followed by gas chromatography-nitrogen-phosphorus detection was developed for the extraction, preconcentration, and determination of five triazole pesticides (penconazole, hexaconazole, diniconazole, tebuconazole, and difenoconazole) in honey samples. In this method the temperature of high-volume aqueous phase was adjusted at an elevated temperature and then a disperser solvent containing an extraction solvent was rapidly injected into the aqueous phase. After cooling to room temperature, the phase separation was accelerated by centrifugation. Various parameters affecting the extraction efficiency such as type and volume of the extraction and disperser solvents, temperature, salt addition, and pH were evaluated. Under the optimum extraction conditions, the method resulted in low limits of detection and quantification within the range 0.05-0.21ngg(-1) in honey (15-70ngL(-1) in solution) and 0.15-1.1ngg(-1) in honey (45-210ngL(-1) in solution), respectively. Enrichment factors and extraction recoveries were in the ranges of 1943-1994 and 97-100%, respectively. The method precision was evaluated at 1.5ngg(-1) of each analyte, and the relative standard deviations were found to be less than 4% for intra-day (n=6) and less than 6% for inter-days. The method was successfully applied to the analysis of honey samples and difenoconazole was determined at ngg(-1) levels. Copyright © 2014 Elsevier B.V. All rights reserved.

Dispersal of invasive forest insects via recreational firewood: a quantitative analysis.

Science.gov (United States)

Koch, Frank H; Yemshanov, Denys; Magarey, Roger D; Smith, William D

2012-04-01

Recreational travel is a recognized vector for the spread of invasive species in North America. However, there has been little quantitative analysis of the risks posed by such travel and the associated transport of firewood. In this study, we analyzed the risk of forest insect spread with firewood and estimated related dispersal parameters for application in geographically explicit invasion models. Our primary data source was the U.S. National Recreation Reservation Service database, which records camper reservations at > 2,500 locations nationwide. For > 7 million individual reservations made between 2004 and 2009 (including visits from Canada), we calculated the distance between visitor home address and campground location. We constructed an empirical dispersal kernel (i.e., the probability distribution of the travel distances) from these "origin-destination" data, and then fitted the data with various theoretical distributions. We found the data to be strongly leptokurtic (fat-tailed) and fairly well fit by the unbounded Johnson and lognormal distributions. Most campers ( approximately 53%) traveled 500 km (and as far as 5,500 km). Additionally, we examined the impact of geographic region, specific destinations (major national parks), and specific origin locations (major cities) on the shape of the dispersal kernel, and found that mixture distributions (i.e., theoretical distribution functions composed of multiple univariate distributions) may fit better in some circumstances. Although only a limited amount of all transported firewood is likely to be infested by forest insects, this still represents a considerable increase in dispersal potential beyond the insects' natural spread capabilities.

Numerical Analysis on Transient of Steam-gas Pressurizer

International Nuclear Information System (INIS)

Kim, Jong-Won; Lee, Yeon-Gun; Park, Goon-Cherl

2008-01-01

In nuclear reactors, various pressurizers are adopted to satisfy their characteristics and uses. The additional active systems such as heater, pressurizer cooler, spray and insulator are essential for a steam or a gas pressurizer. With a steam-gas pressurizer, additional systems are not required due to the use of steam and non-condensable gas as pressure-buffering materials. The steam-gas pressurizer in integrated small reactors experiences very complicated thermal-hydraulic phenomena. To ensure the integrity of this pressurizer type, the analysis on the transient behavior of the steam-gas pressure is indispensable. For this purpose, the steam-gas pressurizer model is introduced to predict the accurate system pressure. The proposed model includes bulk flashing, rainout, inter-region heat and mass transfer and wall condensation with non-condensable gas. However, the ideal gas law is not applied because of significant interaction at high pressure between steam and non-condensable gas. The results obtained from this proposed model agree with those from pressurizer tests. (authors)

DART-TM: A thermomechanical version of DART for LEU VHD dispersed and monolithic fuel analysis

International Nuclear Information System (INIS)

Saliba, Roberto; Taboada, Horacio; Moscarda, Ma.Virginia; Rest, Jeff

2003-01-01

A collaboration agreement between ANL/USDOE and CNEA Argentina, in the area of Low Enriched Uranium Advanced Fuels has been in place since October 16, 1997 under the 'Implementation Arrangement for Technical Exchange and Cooperation in the Area of Peaceful Uses of Nuclear Energy'. An annex concerning DART code optimization has been operative since February 8, 1999. Previously, as a part of this annex a visual thermal FASTDART version was developed that includes mechanistic models for the calculation of the fission-gas-bubble and fuel particle size distribution, reaction layer thickness, and meat thermal conductivity. FASTDART was presented at the last RERTR Meeting that included validation against RERTR 3 irradiation data. The thermal FASTDART version was assessed as an adequate tool for modeling the behavior of LEU U-Mo dispersed fuels under irradiation against PIE RERTR irradiation data. During this past year the development of a 3-D thermo-mechanical version of the code for modeling the irradiation behavior of LEU U-Mo monolithic and dispersion fuel was initiated. Some preliminary results of this work will be shown during RERTR-2003 meeting. (author)

Laser control of natural disperse systems

Science.gov (United States)

Vlasova, Olga L.; Bezrukova, Alexandra G.

2003-10-01

Different water disperse systems were studied by integral (spectroturbidemetry) and differential light scattering method with a laser as a source of light. The investigation done concerns the state of kaolin dispersions at storage and under dilution as an example of mineral dispersion systems such as natural water. The role of some light scattering parameters for an optical analysis of water dispersions, like the dispersion of erythrocytes and bacterial cells -Escherichia coli is discussed. The results obtained can help to elaborate the methods for on-line optical control fo natural disperse systems (water, air) with mineral and biological particles.

CFD simulation of gas-liquid floating particles mixing in an agitated vessel

Directory of Open Access Journals (Sweden)

Li Liangchao

2017-01-01

Full Text Available Gas dispersion and floating particles suspension in an agitated vessel were studied numerically by using computational fluid dynamics (CFD. The Eulerian multi-fluid model along with standard k-ε turbulence model was used in the simulation. A multiple reference frame (MRF approach was used to solve the impeller rotation. The velocity field, gas and floating particles holdup distributions in the vessel were first obtained, and then, the effects of operating conditions on gas dispersion and solid suspension were investigated. The simulation results show that velocity field of solid phase and gas phase are quite different in the agitated vessel. Floating particles are easy to accumulate in the center of the surface region and the increasing of superficial gas velocity is in favor of floating particles off-surface suspension. With increasing solids loading, the gas dispersion becomes worse, while relative solid holdup distribution changes little. The limitations of the present modeling are discussed and further research in the future is proposed.

State and trends of ionization gas analysis. 3

International Nuclear Information System (INIS)

Leonhardt, J.W.; Grosse, H.J.; Popp, P.

1980-01-01

Theory, properties, and main fields of application of noble gas detectors are discussed. The theory and design of the indirect electron mobility detector is presented. Conclusions are drawn with regard to possibilities of further development of detectors for the ionization gas analysis

A Novel Solid State Non-Dispersive Infrared CO2 Gas Sensor Compatible with Wireless and Portable Deployment

Directory of Open Access Journals (Sweden)

Desmond Gibson

2013-05-01

Full Text Available This paper describes development of a novel mid-infrared light emitting diode (LED and photodiode (PD light source/detector combination and use within a non-dispersive infrared (NDIR carbon dioxide gas sensor. The LED/PD based NDIR sensor provides fast stabilisation time (time required to turn on the sensor from cold, warm up, take and report a measurement, and power down again ≈1 second, longevity (>15 years, low power consumption and low cost. Described performance is compatible with “fit and forget” wireless deployed sensors in applications such as indoor air quality monitoring/control & energy conservation in buildings, transport systems, horticultural greenhouses and portable deployment for safety, industrial and medical applications. Fast stabilisation time, low intrinsic power consumption and cycled operation offer typical energy consumption per measurement of mJ’s, providing extended operation using battery and/or energy harvesting strategies (measurement interval of ≈ 2 minutes provides >10 years operation from one AA battery. Specific performance data is provided in relation to measurement accuracy and noise, temperature performance, cross sensitivity, measurement range (two pathlength variants are described covering ambient through to 100% gas concentration, comparison with NDIR utilizing thermal source/pyroelectric light source/detector combination and compatibility with energy harvesting. Semiconductor based LED/PD processing together with injection moulded reflective optics and simple assembly provide a route to low cost high volume manufacturing.

A novel solid state non-dispersive infrared CO2 gas sensor compatible with wireless and portable deployment.

Science.gov (United States)

Gibson, Desmond; MacGregor, Calum

2013-05-29

This paper describes development of a novel mid-infrared light emitting diode (LED) and photodiode (PD) light source/detector combination and use within a non-dispersive infrared (NDIR) carbon dioxide gas sensor. The LED/PD based NDIR sensor provides fast stabilisation time (time required to turn on the sensor from cold, warm up, take and report a measurement, and power down again ≈1 second), longevity (>15 years), low power consumption and low cost. Described performance is compatible with "fit and forget" wireless deployed sensors in applications such as indoor air quality monitoring/control & energy conservation in buildings, transport systems, horticultural greenhouses and portable deployment for safety, industrial and medical applications. Fast stabilisation time, low intrinsic power consumption and cycled operation offer typical energy consumption per measurement of mJ's, providing extended operation using battery and/or energy harvesting strategies (measurement interval of ≈ 2 minutes provides >10 years operation from one AA battery). Specific performance data is provided in relation to measurement accuracy and noise, temperature performance, cross sensitivity, measurement range (two pathlength variants are described covering ambient through to 100% gas concentration), comparison with NDIR utilizing thermal source/pyroelectric light source/detector combination and compatibility with energy harvesting. Semiconductor based LED/PD processing together with injection moulded reflective optics and simple assembly provide a route to low cost high volume manufacturing.

Analysis of gold in jewellery articles by energy dispersive XRF

International Nuclear Information System (INIS)

Meor Yusoff Meor Sulaiman; Latifah Amin

2001-01-01

The value of a precious metal article is much related to its fineness. For gold assay, conventional fire assay technique has been used as the standard technique for more than 500 years. Alternative modern techniques like energy dispersive x-ray fluorescence can also be used in the determination of gold purity. Advantages of this technique compared to the conventional method including non-destructive analysis, does not use any toxic or hazardous chemicals, automatic computer control and is user friendly, requires minimum number of personnel, shorter analysis time and able to determine associated elements in the metal. Analysis was performed on different sizes and purity of gold. Comparison results for the analysis using different reference standards show small differences between technique and its certified value. The technique also gives small standard deviation value in its repeatability test. (Author)

Anomalous dispersion due to hydrocarbons: The secret of reservoir geophysics?

Science.gov (United States)

Brown, R.L.

2009-01-01

When P- and S-waves travel through porous sandstone saturated with hydrocarbons, a bit of magic happens to make the velocities of these waves more frequency-dependent (dispersive) than when the formation is saturated with brine. This article explores the utility of the anomalous dispersion in finding more oil and gas, as well as giving a possible explanation about the effect of hydrocarbons upon the capillary forces in the formation. ?? 2009 Society of Exploration Geophysicists.

Exergy analysis of waste emissions from gas flaring

Directory of Open Access Journals (Sweden)

Olawale Saheed ISMAIL

2016-07-01

Full Text Available Gas flaring produces a stream of waste gases at high temperature and pressure which contains carbon monoxide, Hydrogen Sulphide etc. The resultant effect of which is detrimental to our planet and, consequently, to the life of both the living and the non-living things. It’s well known that gas flaring contributes in no small measure to the global warming. Exergy analysis is applied in this work to analyze waste emissions from gas flaring so as to have a model through which impact of gas flaring can be measured. The study considers both the thermo-mechanical exergy and the chemical exergy of these gases. Relevant data on gas flaring activities in the Niger-Delta region of Nigeria between the periods of fifteen (15 years was obtained from the Nigerian National Petroleum Corporation (NNPC. A computer program (Exergy Calculator was developed based on the equations generated in the Model. Exergy associated with gas flaring activities in Nigeria between the periods of 1998 through 2012 was calculated. The results show that 1 mscf (in thousand cubic feet of flared gases generate 0.000041 MWh of energy leading to a value of 440158.607 MWh of energy for the period under review.The analysis provides important conclusions and recommendations for improving oil platforms operationsin in order to safeguard the environment, health of the populace, and maximize recovered exergy from gas flaring.

Computational fluid dynamics modeling of gas dispersion in multi impeller bioreactor.

Science.gov (United States)

Ahmed, Syed Ubaid; Ranganathan, Panneerselvam; Pandey, Ashok; Sivaraman, Savithri

2010-06-01

In the present study, experiments have been carried out to identify various flow regimes in a dual Rushton turbines stirred bioreactor for different gas flow rates and impeller speeds. The hydrodynamic parameters like fractional gas hold-up, power consumption and mixing time have been measured. A two fluid model along with MUSIG model to handle polydispersed gas flow has been implemented to predict the various flow regimes and hydrodynamic parameters in the dual turbines stirred bioreactor. The computational model has been mapped on commercial solver ANSYS CFX. The flow regimes predicted by numerical simulations are validated with the experimental results. The present model has successfully captured the flow regimes as observed during experiments. The measured gross flow characteristics like fractional gas hold-up, and mixing time have been compared with numerical simulations. Also the effect of gas flow rate and impeller speed on gas hold-up and power consumption have been investigated. (c) 2009 The Society for Biotechnology, Japan. Published by Elsevier B.V. All rights reserved.

Microstructuring of piezoresistive cantilevers for gas detection and analysis

International Nuclear Information System (INIS)

Sarov, Y.; Sarova, V.; Bitterlich, Ch.; Richter, O.; Guliyev, E.; Zoellner, J.-P.; Rangelow, I. W.; Andok, R.; Bencurova, A.

2011-01-01

In this work we report on a design and fabrication of cantilevers for gas detection and analysis. The cantilevers have expanded area of interaction with the gas, while the signal transduction is realized by an integrated piezoresistive deflection sensor, placed at the narrowed cantilever base with highest stress along the cantilever. Moreover, the cantilevers have integrated bimorph micro-actuator detection in a static and dynamic mode. The cantilevers are feasible as pressure, temperature and flow sensors and under chemical functionalization - for gas recognition, tracing and composition analysis. (authors)

Development of PRIME for irradiation performance analysis of U-Mo/Al dispersion fuel

Science.gov (United States)

Jeong, Gwan Yoon; Kim, Yeon Soo; Jeong, Yong Jin; Park, Jong Man; Sohn, Dong-Seong

2018-04-01

A prediction code for the thermo-mechanical performance of research reactor fuel (PRIME) has been developed with the implementation of developed models to analyze the irradiation behavior of U-Mo dispersion fuel. The code is capable of predicting the two-dimensional thermal and mechanical performance of U-Mo dispersion fuel during irradiation. A finite element method was employed to solve the governing equations for thermal and mechanical equilibria. Temperature- and burnup-dependent material properties of the fuel meat constituents and cladding were used. The numerical solution schemes in PRIME were verified by benchmarking solutions obtained using a commercial finite element analysis program (ABAQUS). The code was validated using irradiation data from RERTR, HAMP-1, and E-FUTURE tests. The measured irradiation data used in the validation were IL thickness, volume fractions of fuel meat constituents for the thermal analysis, and profiles of the plate thickness changes and fuel meat swelling for the mechanical analysis. The prediction results were in good agreement with the measurement data for both thermal and mechanical analyses, confirming the validity of the code.

Using Willie's Acid-Base Box for Blood Gas Analysis

Science.gov (United States)

Dietz, John R.

2011-01-01

In this article, the author describes a method developed by Dr. William T. Lipscomb for teaching blood gas analysis of acid-base status and provides three examples using Willie's acid-base box. Willie's acid-base box is constructed using three of the parameters of standard arterial blood gas analysis: (1) pH; (2) bicarbonate; and (3) CO[subscript…

Atmospheric dispersion of radioactive materials

International Nuclear Information System (INIS)

Chino, Masamichi

1988-01-01

The report describes currently available techniques for predicting the dispersion of accidentally released radioactive materials and techniques for visualization using computer graphics. A simulation study is also made on the dispersion of radioactive materials released from the Chernobyl plant. The simplest models include the Gauss plume model and the puff model, which cannot serve to analyze the effects of the topography, vertical wind shear, temperature inversion layer, etc. Numerical analysis methods using advection and dispersion equations are widely adopted for detailed evaluation of dispersion in an emergency. An objective analysis model or a hydrodynamical model is often used to calculate the air currents which are required to determine the advection. A small system based on the puff model is widely adopted in Europe, where the topography is considered to have only simple effects. A more sophisticated large-sized system is required in nuclear facilities located in an area with more complex topographic features. An emergency system for dispersion calculation should be equipped with a graphic display to serve for quick understanding of the radioactivity distribution. (Nogami, K.)

Auger and depth profile analysis of synthetic crystals for dispersion of soft x-rays

International Nuclear Information System (INIS)

Rachocki, K.D.; Brown, D.R.; Springer, R.W.; Arendt, P.N.

1983-01-01

Numerous samples have been fabricated and analyzed as part of a program to produce soft x-ray dispersion elements for various laboratory applications. The majority of this work has centered around the carbon/tungsten system, although several other low-Z/high-Z pairs have been investigated. This report describes the development of certain vacuum-deposition techniques for fabricating these dispersion elements, based upon results obtained from x-ray reflectivity measurements and Auger depth-profile analysis. The composition of the films is chiefly alternating layers of tungsten carbide and carbon. Excess carbon is introduced during the deposition of the tungsten to ensure that the carbide layer is fully stoichiometric. Layer thickness ranged from approx. 5 to 30 A for the carbide and from approx. 15 to 80 A for the carbon. The reflectivity measurements were made using Fe and Al K/sub α/ at grazing incidence. The emphasis in these studies is on the application of surface-analysis results in suggesting modifications to the fabrication process and in evaluating the results such modifications have on the layer stoichiometry, continuity, and periodicity of the dispersion elements so produced

Hypercrosslinked Additives for Ageless Gas-Separation Membranes.

Science.gov (United States)

Lau, Cher Hon; Mulet, Xavier; Konstas, Kristina; Doherty, Cara M; Sani, Marc-Antoine; Separovic, Frances; Hill, Matthew R; Wood, Colin D

2016-02-05

The loss of internal pores, a process known as physical aging, inhibits the long-term use of the most promising gas-separation polymers. Previously we reported that a porous aromatic framework (PAF-1) could form a remarkable nanocomposite with gas-separation polymers to stop aging. However, PAF-1 synthesis is very onerous both from a reagent and reaction-condition perspective, making it difficult to scale-up. We now reveal a highly dispersible and scalable additive based on α,α'-dichloro-p-xylene (p-DCX), that inhibits aging more effectively, and crucially almost doubles gas-transport selectivity. These synergistic effects are related to the intimately mixed nanocomposite that is formed though the high dispersibility of p-DCX in the gas-separation polymer. This reduces particle-size effects and the internal free volume is almost unchanged over time. This study shows this inexpensive and scalable polymer additive delivers exceptional gas-transport performance and selectivity. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Analysis of pollutants in air and water using gas chromatography and headspace gas chromatography

Energy Technology Data Exchange (ETDEWEB)

Stenner, H.

1980-01-01

The combination 'personal sampling' with headspace gas chromatography to determine traces of formaldehyde, phenol and benzene in air is investigated in this work, with the aim of developing maximum workplace concentration values (MWL values). Further possible applications of gas chromatography in trace analysis in the environmentally protected area. The analysis of chromium in waste waters (Cr III as acetyl acetonate complex) is investigated as further possible application, whereby optimum conditions are obtained. A modified flame ionization detector was used to increase the detection sensitivity.

'' Ideal Gas '' gluon plasma with medium dependent dispersion relation

International Nuclear Information System (INIS)

Gorenstein, M.I.

1995-01-01

An '' ideal gas '' model with temperature dependent particle mass is constructed for the gluon plasma equation of state. This simple model gives us an example of a system with temperature dependent effective Hamiltonian. To satisfy thermodynamical relations in these systems, standard statistical mechanics formulas have to be supplemented by special requirements which are considered in details. A self-consistent '' ideal gas '' formulation is used to describe Monte Carlo lattice data for the thermodynamical functions of SU(2) and SU(3) gluon plasma. 14 refs., 8 figs

Dispersive microextraction based on water-coated Fe₃O₄ followed by gas chromatography-mass spectrometry for determination of 3-monochloropropane-1,2-diol in edible oils.

Science.gov (United States)

Zhao, Qin; Wei, Fang; Xiao, Neng; Yu, Qiong-Wei; Yuan, Bi-Feng; Feng, Yu-Qi

2012-06-01

In the present work, we developed a novel dispersive microextraction technique by combining the advantages of liquid-phase microextraction (LPME) and magnetic solid-phase extraction (MSPE). In this method, trace amount of water directly absorbed on bare Fe₃O₄ to form water-coated Fe₃O₄ (W-Fe₃O₄) and rapid extraction can be achieved while W-Fe₃O₄ dispersed in the sample solution. The analyte adsorbed W-Fe₃O₄ can be easily collected and isolated from sample solution by application of a magnet. It was worth noting that in the proposed method water was used as extractant and Fe₃O₄ served as the supporter and retriever of water. The performance of the method was evaluated by extraction of 3-monochloropropane-1,2-diol (3-MCPD) from edible oils. The extracted 3-MCPD was then derived by a silylanization reagent (1-trimethylsilylimidazole) before gas chromatography-mass spectrometry (GC-MS) analysis. Several parameters that affected the extraction and derivatization efficiency were investigated. Our results showed that the limit of detection for 3-MCPD was 1.1 ng/g. The recoveries in spiked oil samples were in the range of 70.0-104.9% with the RSDs less than 5.6% (intra-day) and 6.4% (inter-day). Taken together, the simple, rapid and cost-effective method developed in current study, offers a potential application for the extraction and preconcentration of hydrophilic analytes from complex fatty samples. Copyright © 2012 Elsevier B.V. All rights reserved.

New Jersey's natural gas shortage: a policy analysis

Energy Technology Data Exchange (ETDEWEB)

Cecil, J.L.; Morell, D.

1976-12-01

The public policy problems associated with New Jersey's natural gas shortage are extremely complex and rather difficult to examine. They involve a blend of technology, politics and economics; of regulatory mandates and profit-motivated initiatives; of Federal and state interaction and conflict. To understand the state's gas shortage and to lay the basis for recommending measures to deal with it, information about the basic technology, the organization of the gas industry, the national regulatory posture, and the possible causes of the gas shortage encompasses Part I of the overall study. In Part II, the analysis turns from the national level to a direct examination of New Jersey's gas situation. In Part III, Chapter VIII, the following are considered: the state's supply of natural gas, distribution of these supply volumes within New Jersey by the four major gas utilities, and gas consumption patterns within the state as a whole and then for each major consuming sector (electric utility, industrial, commercial, and residential). This chapter concludes with an analysis of the impacts of the gas shortage to date in New Jersey, and of its probable effects in the near-term. In the final chapter, some tentative conclusions and broad suggestions are advanced for public policies to mitigate the gravity of the state's position with respect to natural gas. Analysis proceeds, in turn, through consideration of possible state actions in several areas: increasing total interstate gas supplies; increasing New Jersey's share of whatever national total exists; making greater (or more effective) use of alternate fuels; and moderating demand for gas through aggressive conservation policies. Some short-term measures to cope better with whatever level of gas shortage exists in the state at any particular time are suggested. 151 references. (MCW)

Natural gas product and strategic analysis

Energy Technology Data Exchange (ETDEWEB)

Layne, A.W.; Duda, J.R.; Zammerilli, A.M.

1993-12-31

Product and strategic analysis at the Department of Energy (DOE)/Morgantown Energy Technology Center (METC) crosscuts all sectors of the natural gas industry. This includes the supply, transportation, and end-use sectors of the natural-gas market. Projects in the Natural Gas Resource and Extraction supply program have been integrated into a new product focus. Product development facilitates commercialization and technology transfer through DOE/industry cost-shared research, development, and demonstration (RD&D). Four products under the Resource and Extraction program include Resource and Reserves; Low Permeability Formations; Drilling, Completion, and Stimulation: and Natural Gas Upgrading. Engineering process analyses have been performed for the Slant Hole Completion Test project. These analyses focused on evaluation of horizontal-well recovery potential and applications of slant-hole technology. Figures 2 and 3 depict slant-well in situ stress conditions and hydraulic fracture configurations. Figure 4 presents Paludal Formation coal-gas production curves used to optimize the hydraulic fracture design for the slant well. Economic analyses have utilized data generated from vertical test wells to evaluate the profitability of horizontal technology for low-permeability formations in Yuma County, Colorado, and Maverick County, Texas.

Gas Hydrate-Sediment Morphologies Revealed by Pressure Core Analysis

Science.gov (United States)

Holland, M.; Schultheiss, P.; Roberts, J.; Druce, M.

2006-12-01

Analysis of HYACINTH pressure cores collected on IODP Expedition 311 and NGHP Expedition 1 showed gas hydrate layers, lenses, and veins contained in fine-grained sediments as well as gas hydrate contained in coarse-grained layers. Pressure cores were recovered from sediments on the Cascadia Margin off the North American West Coast and in the Krishna-Godavari Basin in the Western Bay of Bengal in water depths of 800- 1400 meters. Recovered cores were transferred to laboratory chambers without loss of pressure and nondestructive measurements were made at in situ pressures and controlled temperatures. Gamma density, P-wave velocity, and X-ray images showed evidence of grain-displacing and pore-filling gas hydrate in the cores. Data highlights include X-ray images of fine-grained sediment cores showing wispy subvertical veins of gas hydrate and P-wave velocity excursions corresponding to grain-displacing layers and pore-filling layers of gas hydrate. Most cores were subjected to controlled depressurization experiments, where expelled gas was collected, analyzed for composition, and used to calculate gas hydrate saturation within the core. Selected cores were stored under pressure for postcruise analysis and subsampling.

Response surface analysis to improve dispersed crude oil biodegradation

Energy Technology Data Exchange (ETDEWEB)

Zahed, Mohammad A.; Aziz, Hamidi A.; Mohajeri, Leila [School of Civil Engineering, Universiti Sains Malaysia, Nibong Tebal, Penang (Malaysia); Isa, Mohamed H. [Civil Engineering Department, Universiti Teknologi PETRONAS, Tronoh, Perak (Malaysia)

2012-03-15

In this research, the bioremediation of dispersed crude oil, based on the amount of nitrogen and phosphorus supplementation in the closed system, was optimized by the application of response surface methodology and central composite design. Correlation analysis of the mathematical-regression model demonstrated that a quadratic polynomial model could be used to optimize the hydrocarbon bioremediation (R{sup 2} = 0.9256). Statistical significance was checked by analysis of variance and residual analysis. Natural attenuation was removed by 22.1% of crude oil in 28 days. The highest removal on un-optimized condition of 68.1% were observed by using nitrogen of 20.00 mg/L and phosphorus of 2.00 mg/L in 28 days while optimization process exhibited a crude oil removal of 69.5% via nitrogen of 16.05 mg/L and phosphorus 1.34 mg/L in 27 days therefore optimization can improve biodegradation in shorter time with less nutrient consumption. (Copyright copyright 2012 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

Advances in low atomic number element analysis by wavelength dispersive x-ray fluorescence spectrometry

International Nuclear Information System (INIS)

Vrebos, B.

1996-01-01

Traditionally, the analysis of low atomic number has been a chal1enging task for wavelength dispersive x-ray fluorescence spectrometry. Among the most important factors influencing analysis of the low atomic number elements (from Z=11 downwards) are the fluorescence yield, absorption and the dispersion. The effect of each of these factors on the overall performance will be illustrated. The long wavelengths involved (longer than I nm) used to pose severe problems concerning the monochromator used. Early instruments relied on lead stearate or Blodgett Langmuir soap films for the diffraction of the characteristic radiation. Nowadays, synthetic multilayers are commonly used. The performance of these multilayers is determined by the reflectivity, the resolution and the absorption of the characteristic radiation to be diffracted. These parameters can be optimised by adequately selecting the composition of the materials involved. The sensitivity of the modem instruments is sufficient to allow quantitative analysis. However, this aspect of WDS XRF is still met with considerable scepticism. Examples of quantitative analysis will be given to illustrate the current capability

Energy dispersion X-ray fluorescence techniques in water pollution analysis

International Nuclear Information System (INIS)

Holynska, B.

1980-01-01

Advantages and limitations of energy dispersion X-ray fluorescence methods for analysis of pollutants in water are discussed. The necessary equipment for X-ray measurement of insoluble and dissolved trace metals in water is described. Different techniques of enrichment of trace metals are presented: ion exchange on selective Chelex-100 exchanger, precipitation with chelating agents DDTC and APDC, and adsorption on activated carbon. Some results obtained using different preconcentration methods for trace metals determination in different waters are presented. (author)

Analysis of irradiated U-7wt%Mo dispersion fuel microstructures using automated image processing

Energy Technology Data Exchange (ETDEWEB)

Collette, R. [Colorado School of Mines, Nuclear Science and Engineering Program, 1500 Illinois St, Golden, CO 80401 (United States); King, J., E-mail: kingjc@mines.edu [Colorado School of Mines, Nuclear Science and Engineering Program, 1500 Illinois St, Golden, CO 80401 (United States); Buesch, C. [Oregon State University, 1500 SW Jefferson St., Corvallis, OR 97331 (United States); Keiser, D.D.; Williams, W.; Miller, B.D.; Schulthess, J. [Nuclear Fuels and Materials Division, Idaho National Laboratory, P.O. Box 1625, Idaho Falls, ID 83415-6188 (United States)

2016-07-15

The High Performance Research Reactor Fuel Development (HPPRFD) program is responsible for developing low enriched uranium (LEU) fuel substitutes for high performance reactors fueled with highly enriched uranium (HEU) that have not yet been converted to LEU. The uranium-molybdenum (U-Mo) fuel system was selected for this effort. In this study, fission gas pore segmentation was performed on U-7wt%Mo dispersion fuel samples at three separate fission densities using an automated image processing interface developed in MATLAB. Pore size distributions were attained that showed both expected and unexpected fission gas behavior. In general, it proved challenging to identify any dominant trends when comparing fission bubble data across samples from different fuel plates due to varying compositions and fabrication techniques. The results exhibited fair agreement with the fission density vs. porosity correlation developed by the Russian reactor conversion program. - Highlights: • Automated image processing is used to extract fission gas bubble data from irradiated U−Mo fuel samples. • Verification and validation tests are performed to ensure the algorithm's accuracy. • Fission bubble parameters are predictably difficult to compare across samples of varying compositions. • The 2-D results suggest the need for more homogenized fuel sampling in future studies. • The results also demonstrate the value of 3-D reconstruction techniques.

The Energy Conversion Analysis of HTR Gas Turbine System

International Nuclear Information System (INIS)

Utaja

2000-01-01

The energy conversion analysis of HTR gas turbine system by hand calculation is tedious work and need much time. This difficulty comes from the repeated thermodynamic process calculation, both on compression or expansion of the cycle. To make the analysis faster and wider variable analyzed, HTR-1 programme is used. In this paper, the energy conversion analysis of HTR gas turbine system by HTR-1 will be described. The result is displayed as efficiency curve and block diagram with the input and output temperature of the component. This HTR-1 programme is developed by Basic language programming and be compiled by Visual Basic 5.0 . By this HTR-1 programme, the efficiency, specific power and effective compression of the amount of gas can be recognized fast. For example, for CO 2 gas between 40 o C and 700 o C, the compression on maximum efficiency is 4.6 and the energy specific is 18.9 kcal/kg, while the temperature changing on input and output of the component can be traced on monitor. This process take less than one second, while the manual calculation take more than one hour. It can be concluded, that the energy conversion analysis of the HTR gas turbine system by HTR-1 can be done faster and more variable analyzed. (author)

Thermodynamic analysis of steam-injected advanced gas turbine cycles

Science.gov (United States)

Pandey, Devendra; Bade, Mukund H.

2017-12-01

This paper deals with thermodynamic analysis of steam-injected gas turbine (STIGT) cycle. To analyse the thermodynamic performance of steam-injected gas turbine (STIGT) cycles, a methodology based on pinch analysis is proposed. This graphical methodology is a systematic approach proposed for a selection of gas turbine with steam injection. The developed graphs are useful for selection of steam-injected gas turbine (STIGT) for optimal operation of it and helps designer to take appropriate decision. The selection of steam-injected gas turbine (STIGT) cycle can be done either at minimum steam ratio (ratio of mass flow rate of steam to air) with maximum efficiency or at maximum steam ratio with maximum net work conditions based on the objective of plants designer. Operating the steam injection based advanced gas turbine plant at minimum steam ratio improves efficiency, resulting in reduction of pollution caused by the emission of flue gases. On the other hand, operating plant at maximum steam ratio can result in maximum work output and hence higher available power.

Radioactive dispersion analysis for hypothetical nuclear power plant (NPP) candidate site in Perak state, Malaysia

Science.gov (United States)

Shamsuddin, Shazmeen Daniar; Basri, Nor Afifah; Omar, Nurlyana; Koh, Meng-Hock; Ramli, Ahmad Termizi; Saridan Wan Hassan, Wan Muhamad

2017-10-01

Malaysia is planning to build a nuclear power plant (NPP) by 2030 to diversify the national electricity supply and resources. Selection of an NPP site must consider various factors, especially nuclear safety consideration to fulfil the nuclear safety objectives. Environmental Risk Assessment Analysis is a part of safety requirements by the International Atomic Energy Agency (IAEA) prior to the NPP commissioning process. Risk Assessments Analysis (RIA) is compulsory for the NPP site evaluation. One of RIA methods are Radioactive Dispersion Analysis using probabilistic risk analysis software. It is also important to perform studies to estimate the impact to the neighbouring population in the case of a nuclear accident at the power plant. In the present work, aimed to study the impact of a hypothetical nuclear accident by simulating the dispersion pattern of radionuclides originated from a candidate site at Manjung, Perak. The work has been performed using the HotSpot Health Physics codes. Two types of radionuclides have been considered namely 137Cs and 131I. In calculations, the initial concentration of radioactive materials of Fukushima Daiichi accident data are used which are 2.06 x 1016 Bq and 1.68 x 1017 Bq respectively for the two radionuclides. The result shows that the dispersion distance obtained from both software are not the same. It shows that 137Cs and 131I can be dispersed as far as 16 km and 80 km away from the site during radiological accident respectively, reaching major towns in Perak. Using HOTSPOT, the estimated total effective dose equivalent (TEDE) for 137Cs and 131I at major towns in Perak such as Lumut and Sitiawan are 1.2 mSv and 9.9 mSv. As for Taiping, Ipoh, Kampar, and Teluk Intan the estimated TEDE is around 0.2 mSv and 1.6 mSv respectively. In conclusion, the dispersion can reach as far as 80 km from the site. However, estimated annual effective dose is not more than 1 mSv limit, which is considered acceptable in the point of view of

Radioactive dispersion analysis for hypothetical nuclear power plant (NPP candidate site in Perak state, Malaysia

Directory of Open Access Journals (Sweden)

Shamsuddin Shazmeen Daniar

2017-01-01

Full Text Available Malaysia is planning to build a nuclear power plant (NPP by 2030 to diversify the national electricity supply and resources. Selection of an NPP site must consider various factors, especially nuclear safety consideration to fulfil the nuclear safety objectives. Environmental Risk Assessment Analysis is a part of safety requirements by the International Atomic Energy Agency (IAEA prior to the NPP commissioning process. Risk Assessments Analysis (RIA is compulsory for the NPP site evaluation. One of RIA methods are Radioactive Dispersion Analysis using probabilistic risk analysis software. It is also important to perform studies to estimate the impact to the neighbouring population in the case of a nuclear accident at the power plant. In the present work, aimed to study the impact of a hypothetical nuclear accident by simulating the dispersion pattern of radionuclides originated from a candidate site at Manjung, Perak. The work has been performed using the HotSpot Health Physics codes. Two types of radionuclides have been considered namely 137Cs and 131I. In calculations, the initial concentration of radioactive materials of Fukushima Daiichi accident data are used which are 2.06 x 1016 Bq and 1.68 x 1017 Bq respectively for the two radionuclides. The result shows that the dispersion distance obtained from both software are not the same. It shows that 137Cs and 131I can be dispersed as far as 16 km and 80 km away from the site during radiological accident respectively, reaching major towns in Perak. Using HOTSPOT, the estimated total effective dose equivalent (TEDE for 137Cs and 131I at major towns in Perak such as Lumut and Sitiawan are 1.2 mSv and 9.9 mSv. As for Taiping, Ipoh, Kampar, and Teluk Intan the estimated TEDE is around 0.2 mSv and 1.6 mSv respectively. In conclusion, the dispersion can reach as far as 80 km from the site. However, estimated annual effective dose is not more than 1 mSv limit, which is considered acceptable in the point

Infrared dispersion analysis and Raman scattering spectra of taurine single crystals

Science.gov (United States)

Moreira, Roberto L.; Lobo, Ricardo P. S. M.; Dias, Anderson

2018-01-01

A comprehensive set of optical vibrational modes of monoclinic taurine crystals was determined by Raman scattering, and infrared reflectivity and transmission spectroscopies. By using appropriate scattering/reflection geometries, the vibrational modes were resolved by polarization and the most relevant modes of the crystal could be assigned. In particular, we were able to review the symmetry of the gerade modes and to resolve ambiguities in the literature. Owing to the non-orthogonal character of Bu modes in monoclinic crystals (lying on the optic axial plane), we carried out a generalized Lorentz dispersion analysis consisting of simultaneous adjust of infrared-reflectivity spectra at various light polarization angles. The Au modes (parallel to the C2-axis) were treated within the classical Lorentz model. The behavior of off-diagonal and diagonal terms of the complex dielectric tensors and the presence of anomalous dispersion were discussed as consequences of the low symmetry of the crystal.

Mathematical modeling of disperse two-phase flows

CERN Document Server

Morel, Christophe

2015-01-01

This book develops the theoretical foundations of disperse two-phase flows, which are characterized by the existence of bubbles, droplets or solid particles finely dispersed in a carrier fluid, which can be a liquid or a gas. Chapters clarify many difficult subjects, including modeling of the interfacial area concentration. Basic knowledge of the subjects treated in this book is essential to practitioners of Computational Fluid Dynamics for two-phase flows in a variety of industrial and environmental settings. The author provides a complete derivation of the basic equations, followed by more advanced subjects like turbulence equations for the two phases (continuous and disperse) and multi-size particulate flow modeling. As well as theoretical material, readers will discover chapters concerned with closure relations and numerical issues. Many physical models are presented, covering key subjects including heat and mass transfers between phases, interfacial forces and fluid particles coalescence and breakup, a...

Analysis of environmental dispersion in a wetland flow under the effect of wind: Extended solution

Science.gov (United States)

Wang, Huilin; Huai, Wenxin

2018-02-01

The accurate analysis of the contaminant transport process in wetland flows is essential for environmental assessment. However, dispersivity assessment becomes complicated when the wind strength and direction are taken into consideration. Prior studies illustrating the wind effect on environmental dispersion in wetland flows simply focused on the mean longitudinal concentration distribution. Moreover, the results obtained by these analyses are not accurate when done on a smaller scale, namely, the initial stage of the contaminant transport process. By combining the concentration moments method (the Aris' method) and Gill's expansion theory, the previous researches on environmental dispersion in wetland flows with effect of wind have been extended. By adopting up to 4th-order moments, the wind effect-as illustrated by dimensionless parameters Er (wind force) and ω (wind direction)-on kurtosis and skewness is discussed, the up to 4th-order vertical concentration distribution is obtained, and the two-dimensional concentration distribution is illustrated. This work demonstrates that wind intensity and direction can significantly affect the contaminant dispersion. Moreover, the study presents a more accurate analytical solution of environmental dispersion in wetland flows under various wind conditions.

AERMOD as a Gaussian dispersion model for planning tracer gas dispersion tests for landfill methane emission quantification

DEFF Research Database (Denmark)

Matacchiera, F.; Manes, C.; Beaven, R. P.

2018-01-01

that measurements are taken where the plumes of a released tracer-gas and landfill-gas are well-mixed. However, the distance at which full mixing of the gases occurs is generally unknown prior to any experimental campaign. To overcome this problem the present paper demonstrates that, for any specific TDM...

Molecular analysis of petroleum derived compounds that adsorb onto gas hydrate surfaces

International Nuclear Information System (INIS)

Borgund, Anna E.; Hoiland, Sylvi; Barth, Tanja; Fotland, Per; Askvik, Kjell M.

2009-01-01

Field observations have shown that some streams of water, gas and crude oil do not form gas hydrate plugs during petroleum production even when operating within thermodynamic conditions for hydrate formation. Also, when studied under controlled laboratory conditions, some oils are found to form hydrate dispersed systems whereas others form plugs. Oils with low tendency to form hydrate plugs are believed to contain natural hydrate plug inhibiting components (NICs) that adsorb onto the hydrate surface, making them less water-wet and preventing the particles from agglomerating into large hydrate clusters. The molecular structure of the NICs is currently unknown. In this work, hydrate adsorbing components were extracted from crude oils using freon hydrates as an extraction phase. The fractions were found to be enriched in polar material, and more polar material is associated with hydrates generated in biodegraded crude oils than in non-biodegraded oils. Various fractionation schemes and analytical techniques have been applied in the search for molecular characterisation. The average molecular weights were found to be approximately 500 g/mole. GC-MS chromatograms show a large UCM (Unresolved Complex Mixture). Thus, GC-MS has a limited potential for identification of compounds. A commercial biosurfactant was used as a model compound in the search for similar structures in the extracts. The results from analysis of the hydrate adsorbing components suggest that the type and structure are more important for hydrate morphology than the amount of material adsorbed.

ATMOSPHERIC DYNAMICS OF AIR POLLUTION DISPERSION AND SUSTAINABLE ENVIRONMENT IN JOS-NIGERIA

Directory of Open Access Journals (Sweden)

Moses Eterigho Emetere

2017-01-01

Full Text Available The basic properties of chlorine were used to determine the dis persion patterns of the recent Jos explosion. The dynamic aerosols content model was us ed to affirm the eight kinds of dispersion patterns discussed in this text. The locati on of the victims showed that the dispersion at Jos was either linear or polynomial disp ersion. The dispersions are influenced by atmospheric ventilation, stagnation and recir culation. The last chlorine gas explosion follows the linear or polynomial dispers ion because of the current state of aerosol loadings in Jos. The aftermath effect of this kind of dispersion may be more threatening than the initial danger due to the chem ical formation of more dangerous compounds. The atmosphe ric conditions for the formati on of toxic compound were investigated using twelve years MERRA satellite o bservation. The degree of freedom of methane, carbon oxide and ozone was nearly uniform for the past five years. This means the next five years or more may be threa tening for life forms within the region. The installation of gas tracers within major locations in Jos was suggested to monitor the formation of dioxins in the atmosphere.

Suitability of selected free-gas and dissolved-gas sampling containers for carbon isotopic analysis.

Science.gov (United States)

Eby, P; Gibson, J J; Yi, Y

2015-07-15

Storage trials were conducted for 2 to 3 months using a hydrocarbon and carbon dioxide gas mixture with known carbon isotopic composition to simulate typical hold times for gas samples prior to isotopic analysis. A range of containers (both pierced and unpierced) was periodically sampled to test for δ(13)C isotopic fractionation. Seventeen containers were tested for free-gas storage (20°C, 1 atm pressure) and 7 containers were tested for dissolved-gas storage, the latter prepared by bubbling free gas through tap water until saturated (20°C, 1 atm) and then preserved to avoid biological activity by acidifying to pH 2 with phosphoric acid and stored in the dark at 5°C. Samples were extracted using valves or by piercing septa, and then introduced into an isotope ratio mass spectrometer for compound-specific δ(13)C measurements. For free gas, stainless steel canisters and crimp-top glass serum bottles with butyl septa were most effective at preventing isotopic fractionation (pierced and unpierced), whereas silicone and PTFE-butyl septa allowed significant isotopic fractionation. FlexFoil and Tedlar bags were found to be effective only for storage of up to 1 month. For dissolved gas, crimp-top glass serum bottles with butyl septa were again effective, whereas silicone and PTFE-butyl were not. FlexFoil bags were reliable for up to 2 months. Our results suggest a range of preferred containers as well as several that did not perform very well for isotopic analysis. Overall, the results help establish better QA/QC procedures to avoid isotopic fractionation when storing environmental gas samples. Recommended containers for air transportation include steel canisters and glass serum bottles with butyl septa (pierced and unpierced). Copyright © 2015 John Wiley & Sons, Ltd.

Experimental and theoretical investigations on the release and propagation of heavy gas; Experimentelle und theoretische Untersuchungen zur Schwergasfreisetzung und -ausbreitung

Energy Technology Data Exchange (ETDEWEB)

Rauchegger, Christian

2013-06-01

The hazardous potential of accidental heavy gas releases, especially those involving flammable and toxic gases, is widely known. In order to predict the area in which these gases are in hazardous concentrations, an estimation of the dispersion of these gases must be carried out. While the hazardous area for flammable heavy gases is determined by the lower explosion limit (ca. > 1 vol.%), the release of toxic heavy gases can result in a much larger hazardous area, as toxic gases, even in very low concentrations (ca. < 3000 ppm), have the potential to be highly damaging. The VDI guideline 3783, which is considered as state-of-the-art in Germany, can be used to estimate the dispersion of heavy gases. However, VDI 3783 gives no method for the prediction of the height and width of a heavy gas cloud, which are both required for quantitative risk analysis as well as for a possible coupling of a Lagrangian particle model with the VDI 3783 heavy gas dispersion model. Therefore, further calculation methods were used to describe these dimensions and were evaluated against, experimental studies of the length, width and height of the heavy and neutral gas field. The influence of the source height on the heavy gas dispersion was also investigated. It was found that elevating the source leads to a reduction of the length of the heavy gas area. Once the source reaches a critical height, a heavy gas area at ground level no longer exists. Therefore, for release heights above the critical height, heavy gas dispersion effects can be neglected and the calculation of the heavy gas area according to VDI 3783 part 2 is therefore no longer necessary. The release of heavy gases can occur from a process plant as well as from a standard gas bottle. For the release of heavy gases from standard gas bottles, a mathematical model has been developed to predict the time-dependent mass flow. This model takes into account the time-dependent temperature distribution of the bottle wall, and contains a

Combination of (M)DSC and surface analysis to study the phase behaviour and drug distribution of ternary solid dispersions.

Science.gov (United States)

Meeus, Joke; Scurr, David J; Chen, Xinyong; Amssoms, Katie; Davies, Martyn C; Roberts, Clive J; Van den Mooter, Guy

2015-04-01

Miscibility of the different compounds that make up a solid dispersion based formulation play a crucial role in the drug release profile and physical stability of the solid dispersion as it defines the phase behaviour of the dispersion. The standard technique to obtain information on phase behaviour of a sample is (modulated) differential scanning calorimetry ((M)DSC). However, for ternary mixtures (M)DSC alone is not sufficient to characterize their phase behaviour and to gain insight into the distribution of the active pharmaceutical ingredient (API) in a two-phased polymeric matrix. MDSC was combined with complementary surface analysis techniques, specifically time-of-flight secondary ion mass spectrometry (ToF-SIMS) and atomic force microscopy (AFM). Three spray-dried model formulations with varying API/PLGA/PVP ratios were analyzed. MDSC, TOF-SIMS and AFM provided insights into differences in drug distribution via the observed surface coverage for 3 differently composed ternary solid dispersions. Combining MDSC and surface analysis rendered additional insights in the composition of mixed phases in complex systems, like ternary solid dispersions.

Reliability analysis of dispersion nuclear fuel elements

Science.gov (United States)

Ding, Shurong; Jiang, Xin; Huo, Yongzhong; Li, Lin an

2008-03-01

Taking a dispersion fuel element as a special particle composite, the representative volume element is chosen to act as the research object. The fuel swelling is simulated through temperature increase. The large strain elastoplastic analysis is carried out for the mechanical behaviors using FEM. The results indicate that the fission swelling is simulated successfully; the thickness increments grow linearly with burnup; with increasing of burnup: (1) the first principal stresses at fuel particles change from tensile ones to compression ones, (2) the maximum Mises stresses at the particles transfer from the centers of fuel particles to the location close to the interfaces between the matrix and the particles, their values increase with burnup; the maximum Mises stresses at the matrix exist in the middle location between the two particles near the mid-plane along the length (or width) direction, and the maximum plastic strains are also at the above region.

Reliability analysis of dispersion nuclear fuel elements

Energy Technology Data Exchange (ETDEWEB)

Ding Shurong [Department of Mechanics and Engineering Science, Fudan University, Shanghai 200433 (China)], E-mail: dsr1971@163.com; Jiang Xin [Department of Mechanics and Engineering Science, Fudan University, Shanghai 200433 (China); Huo Yongzhong [Department of Mechanics and Engineering Science, Fudan University, Shanghai 200433 (China)], E-mail: yzhuo@fudan.edu.cn; Li Linan [Department of Mechanics, Tianjin University, Tianjin 300072 (China)

2008-03-15

Taking a dispersion fuel element as a special particle composite, the representative volume element is chosen to act as the research object. The fuel swelling is simulated through temperature increase. The large strain elastoplastic analysis is carried out for the mechanical behaviors using FEM. The results indicate that the fission swelling is simulated successfully; the thickness increments grow linearly with burnup; with increasing of burnup: (1) the first principal stresses at fuel particles change from tensile ones to compression ones, (2) the maximum Mises stresses at the particles transfer from the centers of fuel particles to the location close to the interfaces between the matrix and the particles, their values increase with burnup; the maximum Mises stresses at the matrix exist in the middle location between the two particles near the mid-plane along the length (or width) direction, and the maximum plastic strains are also at the above region.

Effect of SnO2/SiO2 nano particle dispersant on the performance characteristic of complex multi-doped composite coating produced through electrodeposition on oil and gas storage tap

Science.gov (United States)

Anawe, P. A. L.; Fayomi, O. S. I.; Ayoola, A. A.; Popoola, A. P. I.

2018-06-01

The effect of SnO2/SiO2 nano particle dispersant on the performance characteristic of complex zinc multi-doped composite coating produced through electrodeposition is studied. The degradation behaviour in term of wear and chemical corrosion activities were considered as a major factor in service. The wear mass loss was carried out with the help of reciprocating tester. The electrochemical corrosion characteristics were investigated using linear polarization technique in 3.5% simulated sodium chloride media. The outcome of the analysis shows that the developed coating was seen to provide a sound anti wear characteristics in its multidoped state. The corrosion resistance properties were observed to be massive compared to the binary based sample. It is expected that this characteristic will impact on the performance life span of storage tap in oil and gas.

State and trends of ionization gas analysis. 1

International Nuclear Information System (INIS)

Leonhardt, J.W.; Grosse, H.J.; Popp, P.

1980-01-01

The ionization gas analysis makes use of the fact that the ionization-induced conductivity of gases and gas mixtures changes with the composition of such mixtures. A general description is given of ionization detectors based on this principle and theory, properties, and main fields of application of electron capture detectors are discussed

Optimisation of Oil Spill Dispersants on Weathered Oils. A New Approach Using Experimental Design and Multivariate Data Analysis

Energy Technology Data Exchange (ETDEWEB)

Brandvik, Per Johan

1997-12-31

This thesis describes how laboratory experiments combined with numerical modelling were used to predict weathering of an oil slick at different environmental conditions (temperature, wind etc.). It also applies laboratory test methods to screen dispersant effectiveness under different temperatures and salinities. A new approach is developed for dispersant optimization based on statistical design and multivariate analysis; this resulted in a new dispersant with low toxicity and high effectiveness on a broad selection of oil types. The thesis illustrates the potential of dispersant used as an operational response method on oil spills by discussing three different oil spill scenarios and compares the effect of using dispersants to using mechanical recovery and to doing nothing. Some recommendations that may increase the effectiveness of the Norwegian oil spill contingency are also given. 172 refs., 65 figs., 9 tabs.

Analysis of chemical warfare agents in organic liquid samples with magnetic dispersive solid phase extraction and gas chromatography mass spectrometry for verification of the chemical weapons convention.

Science.gov (United States)

Singh, Varoon; Purohit, Ajay Kumar; Chinthakindi, Sridhar; Goud, Raghavender D; Tak, Vijay; Pardasani, Deepak; Shrivastava, Anchal Roy; Dubey, Devendra Kumar

2016-05-27

A simple, sensitive and low temperature sample preparation method is developed for detection and identification of Chemical Warfare Agents (CWAs) and scheduled esters in organic liquid using magnetic dispersive solid phase extraction (MDSPE) followed by gas chromatography-mass spectrometry analysis. The method utilizes Iron oxide@Poly(methacrylic acid-co-ethylene glycol dimethacrylate) resin (Fe2O3@Poly(MAA-co-EGDMA)) as sorbent. Variants of these sorbents were prepared by precipitation polymerization of methacrylic acid-co-ethylene glycol dimethacrylate (MAA-co-EGDMA) onto Fe2O3 nanoparticles. Fe2O3@poly(MAA-co-EGDMA) with 20% MAA showed highest recovery of analytes. Extractions were performed with magnetic microspheres by MDSPE. Parameters affecting the extraction efficiency were studied and optimized. Under the optimized conditions, method showed linearity in the range of 0.1-3.0μgmL(-1) (r(2)=0.9966-0.9987). The repeatability and reproducibility (relative standard deviations (RSDs) %) were in the range of 4.5-7.6% and 3.4-6.2% respectively for organophosphorous esters in dodecane. Limits of detection (S/N=3/1) and limit of quantification (S/N=10/1) were found to be in the range of 0.05-0.1μgmL(-1) and 0.1-0.12μgmL(-1) respectively in SIM mode for selected analytes. The method was successfully validated and applied to the extraction and identification of targeted analytes from three different organic liquids i.e. n-hexane, dodecane and silicon oil. Recoveries ranged from 58.7 to 97.3% and 53.8 to 95.5% at 3μgmL(-1) and 1μgmL(-1) spiking concentrations. Detection of diethyl methylphosphonate (DEMP) and O-Ethyl S-2-diisopropylaminoethyl methylphosphonothiolate (VX) in samples provided by the Organization for Prohibition of Chemical Weapons Proficiency Test (OPCW-PT) proved the utility of the developed method for the off-site analysis of CWC relevant chemicals. Copyright © 2016 Elsevier B.V. All rights reserved.

Dispersion properties of photonic crystal fibres

DEFF Research Database (Denmark)

Bjarklev, Anders Overgaard; Broeng, Jes; Dridi, Kim

1998-01-01

Approximate dispersion and bending properties of all-silica two-dimensional photonic crystal fibres are characterised by the combination of an effective-index model and classical analysis tools for optical fibres. We believe for the first time to have predicted the dispersion properties of photonic...... crystal fibres. The results strongly indicate that these fibres have potential applications as dispersion managing components...

Spatially Extended and High-Velocity Dispersion Molecular Component in Spiral Galaxies: Single-Dish Versus Interferometric Observations

Science.gov (United States)

Caldú-Primo, Anahi; Schruba, Andreas; Walter, Fabian; Leroy, Adam; Bolatto, Alberto D.; Vogel, Stuart

2015-02-01

Recent studies of the molecular medium in nearby galaxies have provided mounting evidence that the molecular gas can exist in two phases: one that is clumpy and organized as molecular clouds and another one that is more diffuse. This last component has a higher velocity dispersion than the clumpy one. In order to investigate these two molecular components further, we compare the fluxes and line widths of CO in NGC 4736 and NGC 5055, two nearby spiral galaxies for which high-quality interferometric as well as single-dish data sets are available. Our analysis leads to two main results: (1) employing three different methods, we determine the flux recovery of the interferometer as compared to the single-dish to be within a range of 35%-74% for NGC 4736 and 81%-92% for NGC 5055, and (2) when focusing on high (S/N ≥ 5) lines of sight (LOSs), the single-dish line widths are larger by ˜(40 ± 20)% than the ones derived from interferometric data, which is in agreement with stacking all LOSs. These results point to a molecular gas component that is distributed over spatial scales larger than 30″(˜1 kpc), and is therefore filtered out by the interferometer. The available observations do not allow us to distinguish between a truly diffuse gas morphology and a uniform distribution of small clouds that are separated by less than the synthesized beam size (˜3″ or ˜100 pc), as they would both be invisible for the interferometer. This high velocity dispersion component has a dispersion similar to what is found in the atomic medium, as traced through observations of the H i line.

Plume dispersion and deposition processes of tracer gas and aerosols in short-distance experiments

International Nuclear Information System (INIS)

Taeschner, M.; Bunnenberg, C.

1988-01-01

Data used in this paper were extracted from field experiments carried out in France and Canada to study the pathway of elementary tritium after possible emissions from future fusion reactors and from short-range experiments with nutrient aerosols performed in a German forest in view of a therapy of damaged coniferous trees by foliar nutrition. Comparisons of dispersion parameters evaluated from the tritium field experiments show that in the case of the 30-min release the variations of the wind directions represent the dominant mechanism of lateral plume dispersion under unstable weather conditions. This corresponds with the observation that for the short 2-min emission the plume remains more concentrated during propagation, and the small lateral dispersion parameters typical for stable conditions have to be applied. The investigations on the dispersion of aerosol plumes into a forest boundary layer show that the Gaussian plume model can be modified by a windspeed factor to be valid for predictions on aerosol concentrations and depositions even in a structured topography like a forest

Development of PRIME for irradiation performance analysis of U-Mo/Al dispersion fuel

Energy Technology Data Exchange (ETDEWEB)

Jeong, Gwan Yoon; Kim, Yeon Soo; Jeong, Yong Jin; Park, Jong Man; Sohn, Dong-Seong

2018-04-01

A prediction code for the thermo-mechanical performance of research reactor fuel (PRIME) has been developed with the implementation of developed models to analyze the irradiation behavior of U-Mo dispersion fuel. The code is capable of predicting the two-dimensional thermal and mechanical performance of U-Mo dispersion fuel during irradiation. A finite element method was employed to solve the governing equations for thermal and mechanical equilibria. Temperature-and burnup-dependent material properties of the fuel meat constituents and cladding were used. The numerical solution schemes in PRIME were verified by benchmarking solutions obtained using a commercial finite element analysis program (ABAQUS).The code was validated using irradiation data from RERTR, HAMP-1, and E-FUTURE tests. The measured irradiation data used in the validation were IL thickness, volume fractions of fuel meat constituents for the thermal analysis, and profiles of the plate thickness changes and fuel meat swelling for the mechanical analysis. The prediction results were in good agreement with the measurement data for both thermal and mechanical analyses, confirming the validity of the code. (c) 2018 Elsevier B.V. All rights reserved.

Development and Characterization of Gas Diffusion Layer Using Carbon Slurry Dispersed by Ammonium Lauryl Sulfate for Proton Exchange Member Fuel Cells

Science.gov (United States)

Villacorta, Rashida

Gas diffusion layers (GDLs) are a critical and essential part of proton exchange membrane fuel cells (PEMFCs). They carry out various important functions such as transportation of reactants to and from the reaction sites. The material properties and structural characteristics of the substrate and the microporous layer strongly influence fuel cell performance. The microporous layer of the GDLs was fabricated with the carbon slurry dispersed in water containing ammonium lauryl sulfate (ALS) using the wire rod coating method. GDLs were fabricated with different materials to compose the microporous layer and evaluated the effects on PEMFC power output performance. The consistency of the carbon slurry was achieved by adding 25 wt. % of PTFE, a binding agent with a 75:25 ratio of carbon (Pureblack and vapor grown carbon fiber). The GDLs were investigated in PEMFC under various relative humidity (RH) conditions using H2/O2 and H2/Air. GDLs were also fabricated with the carbon slurry dispersed in water containing sodium dodecyl sulfate (SDS) and multiwalled carbon nanotubes (MWCNTs) with isopropyl alcohol (IPA) based for fuel cell performance comparison. MWCNTs and SDS exhibits the highest performance at 60% and 70% RH with a peak power density of 1100 mW.cm-2 and 850 mW.cm-2 using air and oxygen as an oxidant. This means that the gas diffusion characteristics of these two samples were optimum at 60 and 70 % RH with high limiting current density range. It was also found that the composition of the carbon slurry, specifically ALS concentration has the highest peak power density of 1300 and 500mW.cm-2 for both H2/O 2 and H2/Air at 100% RH. However, SDS and MWCNTs demonstrates the lowest power density using air and oxygen as an oxidants at 100% RH.

First experience with energy dispersive X-ray analysis (EDXA) in lung fibrosis

International Nuclear Information System (INIS)

Liebetrau, G.; Wiesner, B.; Strausz, J.; Zglinicki, T. von

1987-01-01

Biopsies from 68 patients suffering from interstitial lung disease were examined with regard to minerals using energy dispersive X-ray analysis. In 31 patients a higher portion of minerals or elements were found as pigments. The interpretation of these findings is difficult. If there is a occupational exposure and a reaction of the lung parenchyma the findings could be of clinical value. (author)

Investigation of low-latitude hydrogen emission in terms of a two-component interstellar gas model

International Nuclear Information System (INIS)

Baker, P.L.; Burton, W.B.

1975-01-01

The high-resolution 21-cm hydrogen line observations at low galactic latitude of Burton and Verschuur have been analyzed to determine the large-scale distribution of galactic hydrogen. The distribution parameters are found by model fitting. Optical depth affects have been computed using a two-component gas model. Analysis shows that a multiphase description of the medium is essential to the interpretation of low-latitude emission observations. Where possible, the number of free parameters in the gas model has been reduced. Calculations were performed for a one-component, uniform spin temperature, gas model in order to show the systematic departures between this model and the data caused by the incorrect treatment of the optical depth effect. In the two-component gas, radiative transfer is treated by a Monte Carlo calculation since the opacity of the gas arises in a randomly distributed, cold, optically thick, low velocity-dispersion, cloud medium. The emission arises in both the cloud medium and a smoothly distributed, optically thin, high velocity-dispersion, intercloud medium. The synthetic profiles computed from the two-component model reproduce both the large-scale trends of the observed emission profiles and the magnitude of the small-scale emission irregularities. The analysis permits the determination of values for []he thickness of the galactic disk between half density points, the total observed neutral hydrogen mass of the Galaxy, and the central number density of the intercloud atoms. In addition, the analysis is sensitive to the size of clouds contributing to the observations. Computations also show that synthetic emission profiles based on the two-component model display both the zero-velocity and high-velocity ridges, indicative of optical thinness on a large scale, in spite of the presence of optically thick gas

Performance analysis of solar energy integrated with natural-gas-to-methanol process

International Nuclear Information System (INIS)

Yang, Sheng; Liu, Zhiqiang; Tang, Zhiyong; Wang, Yifan; Chen, Qianqian; Sun, Yuhan

2017-01-01

Highlights: • Solar energy integrated with natural-gas-to-methanol process is proposed. • The two processes are modeled and simulated. • Performance analysis of the two processes are conducted. • The proposed process can cut down the greenhouse gas emission. • The proposed process can save natural gas consumption. - Abstract: Methanol is an important platform chemical. Methanol production using natural gas as raw material has short processing route and well developed equipment and technology. However, natural gas reserves are not large in China. Solar energy power generation system integrated with natural-gas-to-methanol (NGTM) process is developed, which may provide a technical routine for methanol production in the future. The solar energy power generation produces electricity for reforming unit and system consumption in solar energy integrated natural-gas-to-methanol system (SGTM). Performance analysis of conventional natural-gas-to-methanol process and solar energy integrated with natural-gas-to-methanol process are presented based on simulation results. Performance analysis was conducted considering carbon efficiency, production cost, solar energy price, natural gas price, and carbon tax. Results indicate that solar energy integrated with natural-gas-to-methanol process is able to cut down the greenhouse gas (GHG) emission. In addition, solar energy can replace natural gas as fuel. This can reduce the consumption of natural gas, which equals to 9.2% of the total consumed natural gas. However, it is not economical considering the current technology readiness level, compared with conventional natural-gas-to-methanol process.

a Real-Time GIS Platform for High Sour Gas Leakage Simulation, Evaluation and Visualization

Science.gov (United States)

Li, M.; Liu, H.; Yang, C.

2015-07-01

The development of high-sulfur gas fields, also known as sour gas field, is faced with a series of safety control and emergency management problems. The GIS-based emergency response system is placed high expectations under the consideration of high pressure, high content, complex terrain and highly density population in Sichuan Basin, southwest China. The most researches on high hydrogen sulphide gas dispersion simulation and evaluation are used for environmental impact assessment (EIA) or emergency preparedness planning. This paper introduces a real-time GIS platform for high-sulfur gas emergency response. Combining with real-time data from the leak detection systems and the meteorological monitoring stations, GIS platform provides the functions of simulating, evaluating and displaying of the different spatial-temporal toxic gas distribution patterns and evaluation results. This paper firstly proposes the architecture of Emergency Response/Management System, secondly explains EPA's Gaussian dispersion model CALPUFF simulation workflow under high complex terrain and real-time data, thirdly explains the emergency workflow and spatial analysis functions of computing the accident influencing areas, population and the optimal evacuation routes. Finally, a well blow scenarios is used for verify the system. The study shows that GIS platform which integrates the real-time data and CALPUFF models will be one of the essential operational platforms for high-sulfur gas fields emergency management.

A comparative study of gas-gas miscibility processes in underground gas storage reservoirs

Energy Technology Data Exchange (ETDEWEB)

Rafiee, M.M.; Schmitz, S. [DBI - Gastechnologisches Institut gGmbH, Freiberg (Germany)

2013-08-01

Intermixture of gases in underground gas reservoirs have had great weight for natural gas storage in UGS projects with substitution of cushion gas by inert gases or changing the stored gas quality or origin, as for the replacement of town gas by natural gas. It was also investigated during the last years for Enhanced Gas Recovery (EGR) and Carbon Capture and Storage (CCS) projects. The actual importance of its mechanisms is discussed for the H{sub 2} storage in Power to Gas to Power projects (PGP). In these approaches miscibility of the injected gas with the gas in place in the reservoir plays an important role in the displacement process. The conditions and parameters for the gas-gas displacement and mixing have been investigated in previous projects, as e.g. the miscibility of CO{sub 2} with natural gas (CLEAN). Furthermore the miscibility process of town gas with natural gas and sauer gas with sweet gas were also previously measured and compared in laboratory. The objective of this work is to investigate the miscibility of H{sub 2} injection into natural gas reservoirs using a compositional and a black oil reservoir simulator. Three processes of convection, dispersion and diffusion are considered precisely. The effect of gas miscibility is studied for both simulators and the results are compared to find optimum miscibility parameters. The findings of this work could be helpful for further pilot and field case studies to predict and monitor the changes in gas composition and quality. In future this monitoring might become more important when PGP together with H{sub 2}-UGS, as storage technology, will help to successfully implement the change to an energy supply from more renewable sources. Similarly the method confirms the use of the black oil simulator as an alternative for gas-gas displacement and sequestration reservoir simulation in comparison to the compositional simulator. (orig.)

Greenhouse gas and energy analysis of substitute natural gas from biomass for space heat

Energy Technology Data Exchange (ETDEWEB)

Pucker, J.; Jungmeier, G. [JOANNEUM RESEARCH Forschungsgesellschaft mbH, RESOURCES - Institute for Water, Energy and Sustainability, Steyrergasse 17, 8010 Graz (Austria); Zwart, R. [Energy Research Centre of The Netherlands (ECN), Westerduinweg 3, 1755 LE Petten (Netherlands)

2012-03-15

In this paper, the greenhouse gas and energy balances of the production and use for space heating of substitute natural gas from biomass (bio-SNG) for space heat are analysed. These balances are compared to the use of natural gas and solid biomass as wood chips to provide the same service. The reduction of the greenhouse gas emissions (CO{sub 2}-eq.) - carbon dioxide, methane and nitrous oxide - and of the fossil primary energy use is investigated in a life cycle assessment (LCA). This assessment was performed for nine systems for bio-SNG; three types of gasification technologies (O{sub 2}-blown entrained flow, O{sub 2}-blown circulating fluidised bed and air-steam indirect gasification) with three different types of feedstock (forest residues, miscanthus and short rotation forestry). The greenhouse gas analysis shows that forest residues using the air-steam indirect gasification technology result in the lowest greenhouse gas emissions (in CO{sub 2}-eq. 32 kg MWh{sup -1} of heat output). This combination results in 80% reduction of greenhouse gas emissions when compared to natural gas and a 29% reduction of greenhouse gases if the forest residues were converted to wood chips and combusted. The gasification technologies O{sub 2}-blown entrained flow and O{sub 2}-blown circulating fluidised bed gasification have higher greenhouse gas emissions that range between in CO{sub 2}-eq. 41 to 75 kg MWh{sup -1} of heat output depending on the feedstock. When comparing feedstocks in the bio-SNG systems, miscanthus had the highest greenhouse gas emissions bio-SNG systems producing in CO2-eq. 57-75 kg MWh{sup -1} of heat output. Energy analysis shows that the total primary energy use is higher for bio-SNG systems (1.59-2.13 MWh MWh{sup -1} of heat output) than for the reference systems (in 1.37-1.51 MWh MWh{sup -1} of heat output). However, with bio-SNG the fossil primary energy consumption is reduced compared to natural gas. For example, fossil primary energy use is reduced by

The Influence of subway climatology on gas dispersion and the effectiveness of guided evacuations in a complex subway station

Directory of Open Access Journals (Sweden)

Markus Brüne

2016-09-01

Full Text Available This paper discusses a strategy that integrates data from tracer gas experiments with results from pedestrian simulation software in the evaluation of different evacuation procedures for subway stations in response to a fire or a terrorist attack with chemical, biological, radiological, nuclear and enhanced conventional weapons (CBRNE. The study demonstrates that by combining the two data sets a greater understanding of the impact of different evacuations routes on an evacuee's health is gained. It is shown that by controlling the routes pedestrians would use to exit a subway station, the number of fatalities and evacuees with long term health issues can be reduced. It is highlighted that a dynamic evacuation guiding system based on subway climatology would take into account the source of the toxin, the resulting dispersal of gas, smoke, etc. and the subway climatology at the time. In doing so, it would be possible to identify the most endangered areas and guide passengers via an adaptive escape route using audio and visual techniques. Information on the evolution of the emergency situation could also simultaneously be relayed back to the rescue forces to help to plan the rescue and evacuation procedures and optimise the deployment of the search and rescue teams.

Irradiation behavior of U 6Mn-Al dispersion fuel elements

Science.gov (United States)

Meyer, M. K.; Wiencek, T. C.; Hayes, S. L.; Hofman, G. L.

2000-02-01

Irradiation testing of U 6Mn-Al dispersion fuel miniplates was conducted in the Oak Ridge Research Reactor (ORR). Post-irradiation examination showed that U 6Mn in an unrestrained plate configuration performs similarly to U 6Fe under irradiation, forming extensive and interlinked fission gas bubbles at a fission density of approximately 3×10 27 m-3. Fuel plate failure occurs by fission gas pressure driven `pillowing' on continued irradiation.

Overview of the phase diagram of ionic magnetic colloidal dispersions

International Nuclear Information System (INIS)

Cousin, F.; Dubois, E.; Cabuil, V.; Boue, F.; Perzynski, R.

2001-01-01

We study ionic magnetic colloidal dispersions, which are constituted of γ-Fe 2 O 3 nanoparticles dispersed in water, and stabilized with electrostatic interparticle repulsion. The phase diagram PV versus Φ (P: osmotic pressure, V: particle volume, Φ: particle volume fraction) is explored, especially in the range of high Π and high Φ. The osmotic pressure P of the colloidal dispersion is known either by a measurement either because it is imposed during the sample preparation by osmotic compression. The structure of the colloidal dispersion is determined from Small Angle Neutron Scattering. Two regimes can be distinguished. At high pressure, fluid and solid phases can exist. Their structure is governed by strong electrostatic repulsion, the range of which is here evaluated. At low pressure, gas, liquid and glassy solids can exist. Their structure results from a sticky hard sphere potential. (author)

An approach for estimating toxic releases of H2S-containing natural gas.

Science.gov (United States)

Jianwen, Zhang; Da, Lei; Wenxing, Feng

2014-01-15

China is well known being rich in sulfurous natural gas with huge deposits widely distributed all over the country. Due to the toxic nature, the release of hydrogen sulfide-containing natural gas from the pipelines intends to impose serious threats to the human, society and environment around the release sources. CFD algorithm is adopted to simulate the dispersion process of gas, and the results prove that Gaussian plume model is suitable for determining the affected region of the well blowout of sulfide hydrogen-containing natural gas. In accordance with the analysis of release scenarios, the present study proposes a new approach for estimating the risk of hydrogen sulfide poisoning hazards, as caused by sulfide-hydrogen-containing natural gas releases. Historical accident-statistical data from the EGIG (European Gas Pipeline Incident Data Group) and the Britain Gas Transco are integrated into the approach. Also, the dose-load effect is introduced to exploit the hazards' effects by two essential parameters - toxic concentration and exposure time. The approach was applied to three release scenarios occurring on the East-Sichuan Gas Transportation Project, and the individual risk and societal risk are classified and discussed. Results show that societal risk varies significantly with different factors, including population density, distance from pipeline, operating conditions and so on. Concerning the dispersion process of hazardous gas, available safe egress time was studied from the perspective of individual fatality risks. The present approach can provide reliable support for the safety management and maintenance of natural gas pipelines as well as evacuations that may occur after release incidents. Copyright © 2013 Elsevier B.V. All rights reserved.

Performance of a gaseous detector based energy dispersive X-ray fluorescence imaging system: Analysis of human teeth treated with dental amalgam

Science.gov (United States)

Silva, A. L. M.; Figueroa, R.; Jaramillo, A.; Carvalho, M. L.; Veloso, J. F. C. A.

2013-08-01

Energy dispersive X-ray fluorescence (EDXRF) imaging systems are of great interest in many applications of different areas, once they allow us to get images of the spatial elemental distribution in the samples. The detector system used in this study is based on a micro patterned gas detector, named Micro-Hole and Strip Plate. The full field of view system, with an active area of 28 × 28 mm2 presents some important features for EDXRF imaging applications, such as a position resolution below 125 μm, an intrinsic energy resolution of about 14% full width at half maximum for 5.9 keV X-rays, and a counting rate capability of 0.5 MHz. In this work, analysis of human teeth treated by dental amalgam was performed by using the EDXRF imaging system mentioned above. The goal of the analysis is to evaluate the system capabilities in the biomedical field by measuring the drift of the major constituents of a dental amalgam, Zn and Hg, throughout the tooth structures. The elemental distribution pattern of these elements obtained during the analysis suggests diffusion of these elements from the amalgam to teeth tissues.

Thermal analysis elements of liquefied gas storage tanks

Science.gov (United States)

Yanvarev, I. A.; Krupnikov, A. V.

2017-08-01

Tasks of solving energy and resource efficient usage problems, both for oil producing companies and for companies extracting and transporting natural gas, are associated with liquefied petroleum gas technology development. Improving the operation efficiency of liquefied products storages provides for conducting structural, functional, and appropriate thermal analysis of tank parks in the general case as complex dynamic thermal systems.

Clinical applications of scanning electron microscopy and energy dispersive X-ray analysis in dermatology--an up-date

International Nuclear Information System (INIS)

Forslind, B.

1988-01-01

Dermatological papers comprising scanning electron microscopy (SEM) and energy dispersive X-ray (EDX) analysis data published 1983 through 1986 in international journals are reviewed, as an update to our 1984 paper on Clinical applications of scanning electron microscopy and X-ray microanalysis in dermatology. The present paper not only deals with a review of recent publications in this area but also presents the application of microincineration to hair and cryosectioned freeze-dried skin specimens. Examples of the increased contrast obtained in hair cross sections are presented and a discussion on the feasibility of microincineration at analysis of hair and skin cross sections is given. Particle probe analysis (EDX: energy dispersive X-ray analysis and PMP: proton microprobe analysis) as applied to hair and skin samples are presented with stress put on the proton probe analysis. The complementarity of EDX and PMP is demonstrated and future applications are suggested. 75 references

Srv mediated dispersal of streptococcal biofilms through SpeB is observed in CovRS+ strains.

Directory of Open Access Journals (Sweden)

Kristie L Connolly

Full Text Available Group A Streptococcus (GAS is a human specific pathogen capable of causing both mild infections and severe invasive disease. We and others have shown that GAS is able to form biofilms during infection. That is to say, they form a three-dimensional, surface attached structure consisting of bacteria and a multi-component extracellular matrix. The mechanisms involved in regulation and dispersal of these GAS structures are still unclear. Recently we have reported that in the absence of the transcriptional regulator Srv in the MGAS5005 background, the cysteine protease SpeB is constitutively produced, leading to increased tissue damage and decreased biofilm formation during a subcutaneous infection in a mouse model. This was interesting because MGAS5005 has a naturally occurring mutation that inactivates the sensor kinase domain of the two component regulatory system CovRS. Others have previously shown that strains lacking covS are associated with decreased SpeB production due to CovR repression of speB expression. Thus, our results suggest the inactivation of srv can bypass CovR repression and lead to constitutive SpeB production. We hypothesized that Srv control of SpeB production may be a mechanism to regulate biofilm dispersal and provide a mechanism by which mild infection can transition to severe disease through biofilm dispersal. The question remained however, is this mechanism conserved among GAS strains or restricted to the unique genetic makeup of MGAS5005. Here we show that Srv mediated control of SpeB and biofilm dispersal is conserved in the invasive clinical isolates RGAS053 (serotype M1 and MGAS315 (serotype M3, both of which have covS intact. This work provides additional evidence that Srv regulated control of SpeB may mediate biofilm formation and dispersal in diverse strain backgrounds.

Streamlined sample cleanup using combined dispersive solid-phase extraction and in-vial filtration for analysis of pesticides and environmental pollutants in shrimp

Energy Technology Data Exchange (ETDEWEB)

Han, Lijun [College of Science, China Agricultural University, Beijing (China); Sapozhnikova, Yelena [U.S. Dept. of Agriculture, Agricultural Research Service, Eastern Regional Research Center, 600 East Mermaid Lane, Wyndmoor, PA 19038 (United States); Lehotay, Steven J., E-mail: Steven.Lehotay@ars.usda.gov [U.S. Dept. of Agriculture, Agricultural Research Service, Eastern Regional Research Center, 600 East Mermaid Lane, Wyndmoor, PA 19038 (United States)

2014-05-01

Highlights: • The first report that combines in-vial filtration and dispersive-SPE for sample cleanup. • The unique application of ammonium formate for salting-out partitioning in QuEChERS. • Evaluations of a new zirconium-based and a non-friable GCB sorbent for d-SPE cleanup. • A new analytical method for 59 pesticides and environmental pollutants in shrimp. Abstract: A new method of sample preparation was developed and is reported for the first time. The approach combines in-vial filtration with dispersive solid-phase extraction (d-SPE) in a fast and convenient cleanup of QuEChERS (quick, easy, cheap, effective, rugged, and safe) extracts. The method was applied to simultaneous analysis of 42 diverse pesticides and 17 environmental contaminants, including polycyclic aromatic hydrocarbons, polychlorinated biphenyls (PCBs), and flame retardants, in shrimp as the sample matrix. Final extracts were analyzed by both low-pressure gas chromatography – triple quadrupole tandem mass spectrometry (LPGC-MS/MS), and high-performance liquid chromatography – triple quadrupole tandem mass spectrometry (HPLC-MS/MS) to provide a wide scope of analysis for targeted analytes. During method development, several different commercial sorbents for d-SPE were investigated and compared with respect to analyte recoveries. The method was validated at 10, 50, and 100 ng g⁻¹ spiking levels (10-fold lower for PCBs), and the results for nearly all analytes were between 70 and 115% recoveries with ≤17% relative standard deviations. The method was shown to be simple, fast, and effective for multi-application analysis of chemical residues in the representative food and environmental marker matrix.

The dispersion of SWCNTs treated by coupling and dispersing agents in fiber reinforced polymer composities

Science.gov (United States)

Duan, Yuexin; Yuan, Lu; Zhao, Yan; Guan, Fengxia

2007-07-01

It is an obstacle issue for Carbon nanotubes (CNTs) applied in fiber reinforced polymer composites that CNTs is dispersed in nano-level, particularly for single-wall Carbon nanotubes (SWCNTs). In this paper, SWCNTs were treated by the coupling agent like volan and dispersing agent as BYK to improve the dispersion in the Glass Fiber/Epoxy composites. The result of dispersion of SWCNTs in composites was observed by Scanning electron microscopy (SEM). Then the Glass Transition Temperature (Tg) of these kinds of composites with treated and untreated SWCNTs were obtained by Dynamic Mechanical Thermal Analysis (DMTA). Moreover, the bending properties of these composites were tested.

Analysis of GRI North American Regional Gas Supply-Demand Model

International Nuclear Information System (INIS)

Nesbitt, D.M.; Singh, J.; Pine, G.D.; Kline, D.; Barron, M.; Cheung, P.D.

1989-01-01

This paper summarizes the results from the GRI North American Regional Gas Supply-Demand Model using the four scenarios defined for the Energy Modeling Forum Number 9 (EMF-9) described in EMF-9 Working Paper 9.4 (1987). The analysis is designed both to showcase the GRI North American Regional model as well as to infer meaningful results about the North American natural gas system. The focus of the analysis is not R ampersand D per se; R ampersand D analysis using the model is conducted regularly by GRI and described elsewhere. Rather, the objective is to analyze some of the major uncertainties in the North American gas market, uncertainties that potentially affect all players including GRI. In particular, the authors seek to quantify the overall economic environment in which production, transmission, distribution, consumption, and R ampersand D decisions will be made and how different that overall environment might be under alternative assumptions. An attendant objective of this analysis has been to enlist economists from a range of organizations (producers, regulators, GRI, and consultants) to carefully scrutinize the GRI North American Regional model and results. In particular, the coauthors were assembled from diverse organizations to review and evaluate model outputs, applying their particular experience and perspective. The four EMF-9 scenarios upon which this paper is based are described in detail later in this document. Briefly, scenario one represents a world with a surfeit of gas and a relatively high oil price projection; scenario two considers a lower oil price forecast; scenario three assumes a pessimistic outlook for the gas resource base with the same oil prices as scenario one; and scenario four examines a higher level of demand for gas in the North American gas market. An important objective of this analysis is to illustrate the predictive power of multi-scenario comparisons (as contrasted with detailed analysis of any individual scenario)

An investigation of the matrix sensitivity of refinery gas analysis using gas chromatography with flame ionisation detection.

Science.gov (United States)

Ferracci, Valerio; Brown, Andrew S; Harris, Peter M; Brown, Richard J C

2015-02-27

The response of a flame ionisation detector (FID) on a gas chromatograph to methane, ethane, propane, i-butane and n-butane in a series of multi-component refinery gas standards was investigated to assess the matrix sensitivity of the instrument. High-accuracy synthetic gas standards, traceable to the International System of Units, were used to minimise uncertainties. The instrument response exhibited a small dependence on the component amount fraction: this behaviour, consistent with that of another FID, was thoroughly characterised over a wide range of component amount fractions and was shown to introduce a negligible bias in the analysis of refinery gas samples, provided a suitable reference standard is employed. No significant effects of the molar volume, density and viscosity of the gas mixtures on the instrument response were observed, indicating that the FID is suitable for the analysis of refinery gas mixtures over a wide range of component amount fractions provided that appropriate drift-correction procedures are employed. Copyright © 2015 Elsevier B.V. All rights reserved.

Turbulent diffusion modelling for windflow and dispersion analysis

International Nuclear Information System (INIS)

Bartzis, J.G.

1988-01-01

The need for simple but reliable models for turbulent diffusion for windflow and atmospheric dispersion analysis is a necessity today if one takes into consideration the relatively high demand in computer time and costs for such an analysis, arising mainly from the often large solution domains needed, the terrain complexity and the transient nature of the phenomena. In the accident consequence assessment often there is a need for a relatively large number of cases to be analysed increasing further the computer time and costs. Within the framework of searching for relatively simple and universal eddy viscosity/diffusivity models, a new three dimensional non isotropic model is proposed applicable to any domain complexity and any atmospheric stability conditions. The model utilizes the transport equation for turbulent kinetic energy but introduces a new approach in effective length scale estimation based on the flow global characteristics and local atmospheric stability. The model is discussed in detail and predictions are given for flow field and boundary layer thickness. The results are compared with experimental data with satisfactory results

Design of compact dispersion interferometer with a high efficiency nonlinear crystal and a low power CO2 laser

Science.gov (United States)

Akiyama, T.; Yoshimura, S.; Tomita, K.; Shirai, N.; Murakami, T.; Urabe, K.

2017-12-01

When the electron density of a plasma generated in high pressure environment is measured by a conventional interferometer, the phase shifts due to changes of the neutral gas density cause significant measurement errors. A dispersion interferometer, which measures the phase shift that arises from dispersion of medium between the fundamental and the second harmonic wavelengths of laser light, can suppress the measured phase shift due to the variations of neutral gas density. In recent years, the CO2 laser dispersion interferometer has been applied to the atmospheric pressure plasmas and its feasibility has been demonstrated. By combining a low power laser and a high efficiency nonlinear crystal for the second harmonic component generation, a compact dispersion interferometer can be designed. The optical design and preliminary experiments are conducted.

Greenhouse gas and energy analysis of substitute natural gas from biomass for space heat

International Nuclear Information System (INIS)

Pucker, Johanna; Zwart, Robin; Jungmeier, Gerfried

2012-01-01

In this paper, the greenhouse gas and energy balances of the production and use for space heating of substitute natural gas from biomass (bio-SNG) for space heat are analysed. These balances are compared to the use of natural gas and solid biomass as wood chips to provide the same service. The reduction of the greenhouse gas emissions (CO 2 -eq.) – carbon dioxide, methane and nitrous oxide – and of the fossil primary energy use is investigated in a life cycle assessment (LCA). This assessment was performed for nine systems for bio-SNG; three types of gasification technologies (O 2 -blown entrained flow, O 2 -blown circulating fluidised bed and air–steam indirect gasification) with three different types of feedstock (forest residues, miscanthus and short rotation forestry). The greenhouse gas analysis shows that forest residues using the air–steam indirect gasification technology result in the lowest greenhouse gas emissions (in CO 2 -eq. 32 kg MWh −1 of heat output). This combination results in 80% reduction of greenhouse gas emissions when compared to natural gas and a 29% reduction of greenhouse gases if the forest residues were converted to wood chips and combusted. The gasification technologies O 2 -blown entrained flow and O 2 -blown circulating fluidised bed gasification have higher greenhouse gas emissions that range between in CO 2 -eq. 41 to 75 kg MWh −1 of heat output depending on the feedstock. When comparing feedstocks in the bio-SNG systems, miscanthus had the highest greenhouse gas emissions bio-SNG systems producing in CO 2 -eq. 57–75 kg MWh −1 of heat output. Energy analysis shows that the total primary energy use is higher for bio-SNG systems (1.59–2.13 MWh MWh −1 of heat output) than for the reference systems (in 1.37–1.51 MWh MWh −1 of heat output). However, with bio-SNG the fossil primary energy consumption is reduced compared to natural gas. For example, fossil primary energy use is reduced by 92% when air�

Results and analysis of reactor-material experiments on ex-vessel corium quench and dispersal

International Nuclear Information System (INIS)

Spencer, B.W.; McUmber, L.M.; Sienicki, J.J.; Squarer, D.

1984-01-01

The results of reactor material experiments and related analysis are described in which molten corium is injected into a mock-up of the reactor cavity region of a PWR. The experiments address exvessel interactions such as steam generation (for those cases in which water is present), water and corium dispersal from the cavity, hydrogen generation, direct atmosphere heating by dispersed corium, and debrids characterization. Test results indicate efficiencies of steam generation by corium quench ranging up to 65%. Corium sweepout of up to 62% of the injected material was found for those conditions in which steam generation flowrate was augmented by vessel blowdown. The dispersed corium caused very little direct heating of the atmosphere for the configuration employing a trap at the exit of the cavity-to-containment pathway. Corium sweepout phenomena were modeled for high-pressure blowdown conditions, and the results applied to the full-size reactor system predict essentially complete sweepout of corium from the reactor cavity. (orig.)

Results and analysis of reactor-material experiments on ex-vessel corium quench and dispersal

International Nuclear Information System (INIS)

Spencer, B.W.; McUmber, L.M.; Sienicki, J.J.; Squarer, D.

1984-01-01

Results of reactor-material experiments and related analysis are described in which molten corium is injected into a mock-up of the reactor cavity region of a PWR. The experiments address ex-vessel interactions such as steam generation (for those cases in which water is present), water and corium dispersal from the cavity, hydrogen generation, direct atmosphere heating by dispersed corium, and debris characterization. Test results indicate efficiencies of steam generation by corium quench ranging up to 65%. Corium sweepout of up to 62% of the injected material was found for those conditions in which steam generation flowrate was augmented by vessel blowdown. The dispersed corium caused very little direct heating of the atmosphere for the configuration employing a trap at the exit of the cavity-to-containment pathway. Corium sweepout phenomena were modeled for high-pressure blowdown conditions, and the results applied to the full-size reactor system predict essentially complete sweepout of corium from the reactor cavity

A mechanistic Eulerian-Lagrangian model for dispersed flow film boiling

International Nuclear Information System (INIS)

Andreani, M.; Yadigaroglu, G.

1991-01-01

In this paper a new mechanistic model of heat transfer in the dispersed flow regime is presented. The usual assumptions that render most of the available models unsuitable for the analysis of the reflooding phase of the LOCA are discussed, and a two-dimensional time-independent numerical model is developed. The gas temperature field is solved in a fixed-grid (Eulerian) mesh, with the droplets behaving as mass and energy sources. The histories of a large number of computational droplets are followed in a Lagrangian frame, considering evaporation, break-up and interactions with the vapor and with the wall. comparisons of calculated wall and vapor temperatures with experimental data are shown for two reflooding tests

Improvement of gas chromatographic analysis for organic acids and ...

African Journals Online (AJOL)

Yomi

2010-08-27

Aug 27, 2010 ... short retention time and fair recognition peak of the compounds were obtained under the ... GC for acid and solvent analysis from ABE fermentation ... FID was kept at 230°C. Nitrogen gas was used as a carrier gas at a.

Gas Chromatography-Mass Spectrometric Analysis and Insecticidal ...

African Journals Online (AJOL)

HP

Original Research Article. Gas Chromatography-Mass Spectrometric Analysis and ... into a natural fumigant/insecticide for the control of stored product insects. Keywords: Mallotus ..... stability as well as reduce cost. ACKNOWLEDGEMENT.

The Improvement Effect of Dispersant in Fluorite Flotation: Determination by the Analysis of XRD and FESEM-EDX

Directory of Open Access Journals (Sweden)

Y. J. Li

2015-01-01

Full Text Available Different dispersants were added in the dispersion process to improve the efficiency of fluorite flotation. The types and dosage of dispersant on the improvement of fluorite flotation were investigated; when the sodium polyacrylate (SPA was used as the dispersant and its addition is 0.5%, the concentrate grade of CaF2 increased from 90% to 98% and the fluorite recovery increased from 81% to 85%. Methods of X-ray powder diffraction (XRD, field emission scanning electron microscopy (FESEM, and Energy dispersive X-ray spectrometer (EDX were used to characterize the sample. According to the analysis of results, the optimal sample consisted of CaF2 and very little CaCO3 in the size range of 0–5 μm. It could be concluded that the mechanism of improvement for the concentrate grade and recovery of CaF2 was attributed to the change of potential energy barrier which caused the separation of particles with different charge. All results indicate that SPA has a great potential to be an efficient and cost-effective dispersant for the improvement of fluorite flotation.

REVIEW ARTICLE: MODELLING AND ANALYSIS OF A GASOLINE ENGINE EXHAUST GAS SYSTEMS

OpenAIRE

Barhm Mohamad

2018-01-01

The engine exhaust gas behaviour is strongly influencing the engine performance. This paper presents the modelling and analysis of four stroke - gasoline engine exhaust gas systems. An automotive example is considered whereby the pulsating exhausts gas flow through an exhaust pipe and silencer are considered over a wide range of speeds. Analytical procedures are outlined enabling the general analysis and modelling of vehicle engine exhaust gas systems also in this paper present...

Broadband Seismic Studies at the Mallik Gas Hydrate Research Well

Science.gov (United States)

Sun, L. F.; Huang, J.; Lyons-Thomas, P.; Qian, W.; Milkereit, B.; Schmitt, D. R.

2005-12-01

The JAPEX/JNOC/GSC et al. Mallik 3L-38, 4L-38 and 5L-38 scientific wells were drilled in the MacKenzie Delta, NWT, Canada in early 2002 primarily for carrying out initial tests of the feasibility of producing methane gas from the large gas hydrate deposits there [1]. As part of this study, high resolution seismic profiles, a pseudo-3D single fold seismic volume and broadband (8~180Hz) multi-offset vertical seismic profiles (VSP) were acquired at the Mallik site. Here, we provide details on the acquisition program, present the results of the 2D field profile, and discuss the potential implications of these observations for the structure of the permafrost and gas hydrate zones. These zones have long been problematic in seismic imaging due to the lateral heterogeneities. Conventional seismic data processing usually assume a stratified, weak-contrast elastic earth model. However, in permafrost and gas hydrate zones this approximation often becomes invalid. This leads to seismic wave scattering caused by multi-scale perturbation of elastic properties. A 3D viscoelastic finite difference modeling algorithm was employed to simulate wave propagation in a medium with strong contrast. Parameters in this modeling analysis are based on the borehole geophysical log data. In addition, an uncorrelated Vibroseis VSP data set was studied to investigate frequency-dependent absorption and velocity dispersion. Our results indicate that scattering and velocity dispersion are important for a better understanding of attenuation mechanisms in heterogeneous permafrost and gas hydrate zones. [1] Dallimore, S.R., Collett, T.S., Uchida, T., and Weber, M., 2005, Overview of the science program for the Mallik 2002 Gas Hydrate Production Research Well Program; in Scientific Results from Mallik 2002 Gas Hydrate production Research Well Program, MacKenzie Delta, Northwest Territories, Canada, (ed.) S.R. Dallimore and T.S. Collett; Geological Survey of Canada, Bulletin 585, in press.

A new NAMA framework for dispersed energy end-use sectors

DEFF Research Database (Denmark)

Cheng, Chia-Chin

2010-01-01

This paper presents a new approach for a nationally appropriate mitigation actions (NAMA) framework that can unlock the huge potential for greenhouse gas mitigation in dispersed energy end-use sectors in developing countries; specifically, the building sector and the industrial sector. These two ...

Development of a tritium dispersion code

International Nuclear Information System (INIS)

Bell, R.P.; Davis, M.W.; Joseph, S.; Wong, K.Y.

1985-01-01

This paper describes the development and verification of a computer code designed to calculate the radiation dose to man following acute or chronic atmospheric releases of tritium gas and oxide from a point source. The Ontario Hydro Tritium Dispersion Code calculates tritium concentrations in air, soil, and vegetation and doses to man resulting from inhalation/immersion and ingestion of food, milk meat and water. The deposition of HT to soil, conversion of HT to HTO by soil enzymes and resuspension of HTO to air have been incorporated into the terrestrial compartment model and are unique features of the code. Sensitivity analysis has identified the HT deposition velocity and the equivalent water depth of the vegetation compartment as two parameters which have a strong influence on dose calculations. Tritium concentrations in vegetation and soil calculated by the code were in reasonable agreement with experimental results. The radiological significance of including the mechanisms of HT to HTO conversion and resuspension of HTO to air is illustrated

High heat load properties of TiC dispersed Mo alloys

International Nuclear Information System (INIS)

Tokunaga, Kazutoshi; Yoshida, Naoaki; Miura, Yasushi; Kurishita, Hiroaki; Kitsunai, Yuji; Kayano, Hideo.

1996-01-01

Electron beam high heat load experiment of new developed three kinds of TiC dispersed Mo alloys (Mo-0.1wt%TiC, Mo-0.5wt%TiC and Mo-1.0wt%TiC) was studied so as to evaluate it's high heat load at using as the surface materials of divertor. The obtained results indicated that cracks were not observed by embrittlement by recrystallization until about 2200degC of surface temperature and the gas emission properties were not different from sintered molibdenum. However, at near melting point, deep cracks on grain boundary and smaller gas emission than that of sintered Mo were observed. So that, we concluded that TiC dispersed Mo alloy was good surface materials used under the conditions of the stationary heat flux and less than the melting point, although not good one to be melted under nonstationary large heat flux. (S.Y.)

Gas generation and migration analysis for TRU waste disposal system

International Nuclear Information System (INIS)

Ando, Kenichi; Noda, Masaru; Yamamoto, Mikihiko; Mihara, Morihiro

2005-09-01

In TRU waste disposal system, significant quantities of gases may be generated due to metal corrosion, radiolysis effect and microorganism activities. It is therefore recommended that the potential impact of gas generation and migration on TRU waste repository should be evaluated. In this study, gas generation rates were calculated in the repository and gas migration analysis in the disposal system were carried out using two phase flow model with results of gas generation rates. First, the time dependencies of gas generation rate in each TRU waste repositories were evaluated based on amounts of metal, organic matter and radioactivity. Next, the accumulation pressure of gases and expelled pore water volume nuclides in the repository were calculated by TOUGH2 code. After that, the results showed that the increase of gas pressure was the range of 1.3 to 1.4 MPa. In the repository with and without buffer, the rate of expelled pore water was 0.006 - 0.009 m 3 /y and 0.018 - 0.24m 3 /y, respectively. In addition, the radioactive gas migration through the repository and geosphere are evaluated. And re-saturation analysis is also performed to evaluate the initial condition of the system. (author)

An approach for estimating toxic releases of H{sub 2}S-containing natural gas

Energy Technology Data Exchange (ETDEWEB)

Jianwen, Zhang, E-mail: zhangjw@mail.buct.edu.cn [Lab of Fluid Flow and Heat Transfer, Beijing University of Chemical Technology, Beijing 100029 (China); Institute of Safety Management, Beijing University of Chemical Technology, Beijing 100029 (China); Da, Lei [Lab of Fluid Flow and Heat Transfer, Beijing University of Chemical Technology, Beijing 100029 (China); College of Mechanical and Electrical Engineering, Beijing University of Chemical Technology, Beijing 100029 (China); Wenxing, Feng [Pipeline Research Center of PetroChina Company Lmited, 51 Golden Road, Langfang 065000 (China)

2014-01-15

Highlights: • Behavior of H{sub 2}S-containing natural gas exhibits appearance of neutral gas by CFD. • The poisoning hazards of H{sub 2}S by gas pipeline releases are successfully estimated. • An assessment method for available safe egress time is proposed. -- Abstract: China is well known being rich in sulfurous natural gas with huge deposits widely distributed all over the country. Due to the toxic nature, the release of hydrogen sulfide-containing natural gas from the pipelines intends to impose serious threats to the human, society and environment around the release sources. CFD algorithm is adopted to simulate the dispersion process of gas, and the results prove that Gaussian plume model is suitable for determining the affected region of the well blowout of sulfide hydrogen-containing natural gas. In accordance with the analysis of release scenarios, the present study proposes a new approach for estimating the risk of hydrogen sulfide poisoning hazards, as caused by sulfide-hydrogen-containing natural gas releases. Historical accident-statistical data from the EGIG (European Gas Pipeline Incident Data Group) and the Britain Gas Transco are integrated into the approach. Also, the dose-load effect is introduced to exploit the hazards’ effects by two essential parameters – toxic concentration and exposure time. The approach was applied to three release scenarios occurring on the East-Sichuan Gas Transportation Project, and the individual risk and societal risk are classified and discussed. Results show that societal risk varies significantly with different factors, including population density, distance from pipeline, operating conditions and so on. Concerning the dispersion process of hazardous gas, available safe egress time was studied from the perspective of individual fatality risks. The present approach can provide reliable support for the safety management and maintenance of natural gas pipelines as well as evacuations that may occur after

Gas Chromatography-Mass Spectrometric Analysis of Nematicidal ...

African Journals Online (AJOL)

Gas Chromatography-Mass Spectrometric Analysis of Nematicidal Essential Oil of Valeriana ... Tropical Journal of Pharmaceutical Research ... have a potential to be developed to natural nematicides for the control of cereal cyst nematodes.

Gas analysis during the chemical vapor deposition of carbon

International Nuclear Information System (INIS)

Lieberman, M.L.; Noles, G.T.

1973-01-01

Gas chromatographic analyses were performed during the chemical vapor deposition of carbon in both isothermal and thermal gradient systems. Such data offer insight into the gas phase processes which occur during deposition and the interrelations which exist between gas composition, deposition rate, and resultant structure of the deposit. The results support a carbon CVD model presented previously. The application of chromatographic analysis to research, development, and full-scale facilities is shown. (U.S.)

A Stirling engine analysis method based upon moving gas nodes

Science.gov (United States)

Martini, W. R.

1986-01-01

A Lagrangian nodal analysis method for Stirling engines (SEs) is described, validated, and applied to a conventional SE and an isothermalized SE (with fins in the hot and cold spaces). The analysis employs a constant-mass gas node (which moves with respect to the solid nodes during each time step) instead of the fixed gas nodes of Eulerian analysis. The isothermalized SE is found to have efficiency only slightly greater than that of a conventional SE.

Definition of global dispersion coefficients

International Nuclear Information System (INIS)

Naff, R.L.

1983-10-01

For estimation of a global longitudinal dispersivity at the Gorleben site, data available primarily consist of suites of geophysical logs from wells penetrating the Quaternary aquifer. A length scale for the principle aquifer at Gorleben is to be found. Samples are to be taken separately to estimate the variance in hydraulic conductivity (Taylor Analysis, Fickian dispersion process). (DG)

The role of ventilation in controlling the dispersion of radon gas from a cellar in a domestic house

International Nuclear Information System (INIS)

Ward, I.C.; Wang, F.; Sharples, S.; Pitts, A.C.

1994-01-01

In certain parts of the United Kingdom where radon gas seeps from the ground into the basement of domestic housing, normal methods of removing this gas by using under floor extract ventilation is not appropriate. In this situation the radon gas enters the basement through the side walls of the cellar and hence into the house. Using mechanical ventilation to either pressurise or de-pressurise the cellar may be an appropriate solution to this problem, however, before installing such a system in a house a ventilation strategy must be established. This paper sets out a ventilation strategy for minimising the ingress of radon into a domestic house, which has been established by simulating the air movement within a domestic house using Breeze Version 6 for a range of environmental conditions. The results of this analysis show that in winter when the emission of radon gas is most strong de-pressurisation of the basement can improve the ingress of the gas to the rest of the house. (author)

Interspecific nematode signals regulate dispersal behavior.

Directory of Open Access Journals (Sweden)

Fatma Kaplan

Full Text Available Dispersal is an important nematode behavior. Upon crowding or food depletion, the free living bacteriovorus nematode Caenorhabditis elegans produces stress resistant dispersal larvae, called dauer, which are analogous to second stage juveniles (J2 of plant parasitic Meloidogyne spp. and infective juveniles (IJs of entomopathogenic nematodes (EPN, e.g., Steinernema feltiae. Regulation of dispersal behavior has not been thoroughly investigated for C. elegans or any other nematode species. Based on the fact that ascarosides regulate entry in dauer stage as well as multiple behaviors in C. elegans adults including mating, avoidance and aggregation, we hypothesized that ascarosides might also be involved in regulation of dispersal behavior in C. elegans and for other nematodes such as IJ of phylogenetically related EPNs.Liquid chromatography-mass spectrometry analysis of C. elegans dauer conditioned media, which shows strong dispersing activity, revealed four known ascarosides (ascr#2, ascr#3, ascr#8, icas#9. A synthetic blend of these ascarosides at physiologically relevant concentrations dispersed C. elegans dauer in the presence of food and also caused dispersion of IJs of S. feltiae and J2s of plant parasitic Meloidogyne spp. Assay guided fractionation revealed structural analogs as major active components of the S. feltiae (ascr#9 and C. elegans (ascr#2 dispersal blends. Further analysis revealed ascr#9 in all Steinernema spp. and Heterorhabditis spp. infected insect host cadavers.Ascaroside blends represent evolutionarily conserved, fundamentally important communication systems for nematodes from diverse habitats, and thus may provide sustainable means for control of parasitic nematodes.

Gaseous detectors for energy dispersive X-ray fluorescence analysis

Science.gov (United States)

Veloso, J. F. C. A.; Silva, A. L. M.

2018-01-01

The energy resolution capability of gaseous detectors is being used in the last years to perform studies on the detection of characteristic X-ray lines emitted by elements when excited by external radiation sources. One of the most successful techniques is the Energy Dispersive X-ray Fluorescence (EDXRF) analysis. Recent developments in the new generation of micropatterned gaseous detectors (MPGDs), triggered the possibility not only of recording the photon energy, but also of providing position information, extending their application to EDXRF imaging. The relevant features and strategies to be applied in gaseous detectors in order to better fit the requirements for EDXRF imaging will be reviewed and discussed, and some application examples will be presented.

Platoon Dispersion Analysis Based on Diffusion Theory

Directory of Open Access Journals (Sweden)

Badhrudeen Mohamed

2017-01-01

Full Text Available Urbanization and gro wing demand for travel, causes the traffic system to work ineffectively in most urban areas leadin g to traffic congestion. Many approaches have been adopted to address this problem, one among them being the signal co-ordination. This can be achieved if the platoon of vehicles that gets discharged at one signal gets green at consecutive signals with minimal delay. However, platoons tend to get dispersed as they travel and this dispersion phenomenon should be taken into account for effective signal coordination. Reported studies in this area are from the homogeneous and lane disciplined traffic conditions. This paper analyse the platoon dispersion characteristics under heterogeneous and lane-less traffic conditions. Out of the various modeling techniques reported, the approach based on diffusion theory is used in this study. The diffusion theory based models so far assumed thedata to follow normal distribution. However, in the present study, the data was found to follow lognormal distribution and hence the implementation was carried out using lognormal distribution. The parameters of lognormal distribution were calibrated for the study condition. For comparison purpose, normal distribution was also calibrated and the results were evaluated. It was foun d that model with log normal distribution performed better in all cases than the o ne with normal distribution.

Potential application of gas chromatography to the analysis of hydrogen isotopes

International Nuclear Information System (INIS)

Warner, D.K.; Sprague, R.E.; Bohl, D.R.

1976-01-01

Gas chromatography is used at Mound Laboratory for the analysis of hydrogen isotopic impurities in gas mixtures. This instrumentation was used to study the applicability of the gas chromatography technique to the determination of the major components of hydrogen isotopic gas mixtures. The results of this study, including chromatograms and precision data, are presented

Thermal performance of gas turbine power plant based on exergy analysis

International Nuclear Information System (INIS)

Ibrahim, Thamir K.; Basrawi, Firdaus; Awad, Omar I.; Abdullah, Ahmed N.; Najafi, G.; Mamat, Rizlman; Hagos, F.Y.

2017-01-01

Highlights: • Modelling theoretical framework for the energy and exergy analysis of the Gas turbine. • Investigated the effects of ambient temperature on the energy and exergy performance. • The maximum exergy loss occurs in the gas turbine components. - Abstract: This study is about energy and exergy analysis of gas turbine power plant. Energy analysis is more quantitatively while exergy analysis is about the same but with the addition of qualitatively. The lack quality of the thermodynamic process in the system leads to waste of potential energy, also known as exergy destruction which affects the efficiency of the power plant. By using the first and second law of thermodynamics, the model for the gas turbine power plant is built. Each component in the thermal system which is an air compressor, combustion chamber and gas turbine play roles in affecting the efficiency of the gas turbine power plant. The exergy flow rate for the compressor (AC), the combustion chamber (CC) and the gas turbine (GT) inlet and outlet are calculated based on the physical exergy and chemical exergy. The exergy destruction calculation based on the difference between the exergy flow in and exergy flow out of the component. The combustion chamber has the highest exergy destruction. The air compressor has 94.9% and 92% of exergy and energy efficiency respectively. The combustion chamber has 67.5% and 61.8% of exergy and energy efficiency respectively while gas turbine has 92% and 82% of exergy and energy efficiency respectively. For the overall efficiency, the plant has 32.4% and 34.3% exergy and energy efficiency respectively. To enhance the efficiency, the intake air temperature should be reduced, modify the combustion chamber to have the better air-fuel ratio and increase the capability of the gas turbine to receive high inlet temperature.

Time-reversal focusing of an expanding soliton gas in disordered replicas

KAUST Repository

Fratalocchi, Andrea; Armaroli, A.; Trillo, S.

2011-01-01

We investigate the properties of time reversibility of a soliton gas, originating from a dispersive regularization of a shock wave, as it propagates in a strongly disordered environment. An original approach combining information measures and spin glass theory shows that time-reversal focusing occurs for different replicas of the disorder in forward and backward propagation, provided the disorder varies on a length scale much shorter than the width of the soliton constituents. The analysis is performed by starting from a new class of reflectionless potentials, which describe the most general form of an expanding soliton gas of the defocusing nonlinear Schrödinger equation.

Time-reversal focusing of an expanding soliton gas in disordered replicas

KAUST Repository

Fratalocchi, Andrea

2011-05-31

We investigate the properties of time reversibility of a soliton gas, originating from a dispersive regularization of a shock wave, as it propagates in a strongly disordered environment. An original approach combining information measures and spin glass theory shows that time-reversal focusing occurs for different replicas of the disorder in forward and backward propagation, provided the disorder varies on a length scale much shorter than the width of the soliton constituents. The analysis is performed by starting from a new class of reflectionless potentials, which describe the most general form of an expanding soliton gas of the defocusing nonlinear Schrödinger equation.

Spatially extended and high-velocity dispersion molecular component in spiral galaxies: Single-dish versus interferometric observations

International Nuclear Information System (INIS)

Caldú-Primo, Anahi; Walter, Fabian; Schruba, Andreas; Leroy, Adam; Bolatto, Alberto D.; Vogel, Stuart

2015-01-01

Recent studies of the molecular medium in nearby galaxies have provided mounting evidence that the molecular gas can exist in two phases: one that is clumpy and organized as molecular clouds and another one that is more diffuse. This last component has a higher velocity dispersion than the clumpy one. In order to investigate these two molecular components further, we compare the fluxes and line widths of CO in NGC 4736 and NGC 5055, two nearby spiral galaxies for which high-quality interferometric as well as single-dish data sets are available. Our analysis leads to two main results: (1) employing three different methods, we determine the flux recovery of the interferometer as compared to the single-dish to be within a range of 35%–74% for NGC 4736 and 81%–92% for NGC 5055, and (2) when focusing on high (S/N ≥ 5) lines of sight (LOSs), the single-dish line widths are larger by ∼(40 ± 20)% than the ones derived from interferometric data, which is in agreement with stacking all LOSs. These results point to a molecular gas component that is distributed over spatial scales larger than 30″(∼1 kpc), and is therefore filtered out by the interferometer. The available observations do not allow us to distinguish between a truly diffuse gas morphology and a uniform distribution of small clouds that are separated by less than the synthesized beam size (∼3″ or ∼100 pc), as they would both be invisible for the interferometer. This high velocity dispersion component has a dispersion similar to what is found in the atomic medium, as traced through observations of the H i line.

Analysis of gas turbine systems for sustainable energy conversion

Energy Technology Data Exchange (ETDEWEB)

Anheden, Marie

2000-02-01

Increased energy demands and fear of global warming due to the emission of greenhouse gases call for development of new efficient power generation systems with low or no carbon dioxide (CO{sub 2}) emissions. In this thesis, two different gas turbine power generation systems, which are designed with these issues in mind, are theoretically investigated and analyzed. In the first gas turbine system, the fuel is combusted using a metal oxide as an oxidant instead of oxygen in the air. This process is known as Chemical Looping Combustion (CLC). CLC is claimed to decrease combustion exergy destruction and increase the power generation efficiency. Another advantage is the possibility to separate CO{sub 2} without a costly and energy demanding gas separation process. The system analysis presented includes computer-based simulations of CLC gas turbine systems with different metal oxides as oxygen carriers and different fuels. An exergy analysis comparing the exergy destruction of the gas turbine system with CLC and conventional combustion is also presented. The results show that it is theoretically possible to increase the power generation efficiency of a simple gas turbine system by introducing CLC. A combined gas/steam turbine cycle system with CLC is, however, estimated to reach a similar efficiency as the conventional combined cycle system. If the benefit of easy and energy-efficient CO{sub 2} separation is accounted for, a CLC combined cycle system has a potential to be favorable compared to a combined cycle system with CO{sub 2} separation. In the second investigation, a solid, CO{sub 2}-neutral biomass fuel is used in a small-scale externally fired gas turbine system for cogeneration of power and district heating. Both open and closed gas turbines with different working fluids are simulated and analyzed regarding thermodynamic performance, equipment size, and economics. The results show that it is possible to reach high power generation efficiency and total (power

Economic impact analysis of natural gas development and the policy implications

International Nuclear Information System (INIS)

De Silva, P.N.K.; Simons, S.J.R.; Stevens, P.

2016-01-01

In the US, the shale gas revolution ensured that the development costs of unconventional natural gas plummeted to the levels of $2–3/Mcf. This success has motivated the development of shale gas in other regions, including Australia and Europe. This study, focussing primarily on aspects of economic impact analysis, estimates the development costs of shale gas extraction in both Australia and Europe, based on both direct and fiscal costs, and also suggests policy initiatives. The increasing liquefied natural gas (LNG) developments in Australia are already straining domestic gas supplies. Hence, the development of more natural gas resources has been given a high priority. However, a majority of the Australian shale resources is non-marine in origin and significantly different to the marine-type shales in the US. In addition, the challenges of high development costs and the lack of infrastructure, service capacity and effective government policy are inhibiting shale gas development. Increasing the attractiveness of low risk investment by new, local, developers is critical for Australian shale gas success, which will simultaneously increase domestic gas security. In the European context, unconventional gas development will be challenged by direct, rather than fiscal costs. High direct costs will translate into average overall gas development costs over $13/Mcf, which is well over the existing market price. - Highlights: • The shale gas development potential of US, Europe and Australia are compared. • An economic impact analysis of shale gas development in Europe and Australia. • Factors important for shale gas development are discussed. • Policy pathways are suggested for shale gas development

Rotordynamic analysis for stepped-labyrinth gas seals using moody's friction-factor model

International Nuclear Information System (INIS)

Ha, Tae Woong

2001-01-01

The governing equations are derived for the analysis of a stepped labyrinth gas seal generally used in high performance compressors, gas turbines, and steam turbines. The bulk-flow is assumed for a single cavity control volume set up in a stepped labyrinth cavity and the flow is assumed to be completely turbulent in the circumferential direction. The Moody's wall-friction-factor model is used for the calculation of wall shear stresses in the single cavity control volume. For the reaction force developed by the stepped labyrinth gas seal, linearized zeroth-order and first-order perturbation equations are developed for small motion about a centered position. Integration of the resultant first-order pressure distribution along and around the seal defines the rotordynamic coefficients of the stepped labyrinth gas seal. The resulting leakage and rotordynamic characteristics of the stepped labyrinth gas seal are presented and compared with Scharrer's theoretical analysis using Blasius' wall-friction-factor model. The present analysis shows a good qualitative agreement of leakage characteristics with Scharrer's analysis, but underpredicts by about 20 %. For the rotordynamic coefficients, the present analysis generally yields smaller predicted values compared with Scharrer's analysis

Possible applications of energy-dispersive powder diffractometry in the phase analysis of metallurgical and geological specimens

International Nuclear Information System (INIS)

Koch, S.; Jugelt, P.

1978-01-01

Energy-dispersive powder diffractometry renders possible nondestructive quantitative determination of both α and γ phases of iron with shorter measuring time as compared to angle-dispersive techniques. In investigating geological specimens above all the possibility of obtaining qualitative survey analyses within short time is advantageous. The comparatively lower separability leads to difficulties because of increased line density. Therefore, quantitative phase analysis requires the use of spectra unfolding programmes. For laboratory analyses it is advantageous that the same measuring equipment allows the performance of multi-element analyses. (author)

Dispersion and exposure of sour gas flare emissions

International Nuclear Information System (INIS)

Davies, M.

2002-01-01

This presentation described the implications of flare research project findings with reference to reduced combustion efficiency, stack plume down wash and minor species. A plume model shows that reduced combustion efficiency decreases the energy available for plume rise. Reduced combustion may therefore decrease H 2 S to SO 2 conversion. Stack plume down wash can decrease plume rise under high wind speed conditions, and in extreme cases can also preclude any plume rise. Minor species include vapour phase emissions of polynuclear aromatic hydrocarbons (PAH), benzene, toluene, ethyl-benzene and xylenes (BTEX), and aldehydes. They also include particulate phase emissions such as soot and PAH. Observed concentrations of minor species were presented along with predicted vapour phase concentrations and particulate phase emissions. The standard modelling approaches used in this study included the Gaussian plume model, flame height, plume rise and dispersion. figs

Analysis of Maisotsenko open gas turbine bottoming cycle

International Nuclear Information System (INIS)

Saghafifar, Mohammad; Gadalla, Mohamed

2015-01-01

Maisotsenko gas turbine cycle (MGTC) is a recently proposed humid air turbine cycle. An air saturator is employed for air heating and humidification purposes in MGTC. In this paper, MGTC is integrated as the bottoming cycle to a topping simple gas turbine as Maisotsenko bottoming cycle (MBC). A thermodynamic optimization is performed to illustrate the advantages and disadvantages of MBC as compared with air bottoming cycle (ABC). Furthermore, detailed sensitivity analysis is reported to present the effect of different operating parameters on the proposed configurations' performance. Efficiency enhancement of 3.7% is reported which results in more than 2600 tonne of natural gas fuel savings per year. - Highlights: • Developed an accurate air saturator model. • Introduced Maisotsenko bottoming cycle (MBC) as a power generation cycle. • Performed Thermodynamic optimization for MBC and air bottoming cycle (ABC). • Performed detailed sensitivity analysis for MBC under different operating conditions. • MBC has higher efficiency and specific net work output as compared to ABC

Two-Fluid Models for Simulating Dispersed Multiphase Flows-A Review

Directory of Open Access Journals (Sweden)

L.X. Zhou

2009-01-01

Full Text Available The development of two-fluid models for simulating dispersed multiphase flows (gas-particle, gas-droplet, bubble-liquid, liquid-particle flows by the present author within the last 20 years is systematically reviewed. The two-fluid models based on Reynolds expansion, time averaging and mass-weighed averaging, and also PDF transport equations are described. Different versions of two-phase turbulence models, including the unified second-order moment (USM and k-ε-kp models, the DSM-PDF model, the SOM-MC model, the nonlinear k-e-kp model, and the USM-Θ model for dense gas-particle flows and their application and experimental validation are discussed.

Gas analysis modeling system forecast for the Energy Modeling Forum North American Natural Gas Market Study

International Nuclear Information System (INIS)

Mariner-Volpe, B.; Trapmann, W.

1989-01-01

The Gas Analysis Modeling System is a large computer-based model for analyzing the complex US natural gas industry, including production, transportation, and consumption activities. The model was developed and first used in 1982 after the passage of the NGPA, which initiated a phased decontrol of most natural gas prices at the wellhead. The categorization of gas under the NGPA and the contractual nature of the natural gas market, which existed at the time, were primary factors in the development of the basic structure of the model. As laws and regulations concerning the natural gas market have changed, the model has evolved accordingly. Recent increases in competition in the wellhead market have also led to changes in the model. GAMS produces forecasts of natural gas production, consumption, and prices annually through 2010. It is an engineering-economic model that incorporates several different mathematical structures in order to represent the interaction of the key groups involved in the natural gas market. GAMS has separate supply and demand components that are equilibrated for each year of the forecast by means of a detailed transaction network

Comparison of some dispersion-corrected and traditional functionals with CCSD(T) and MP2 ab initio methods: Dispersion, induction, and basis set superposition error

Science.gov (United States)

Roy, Dipankar; Marianski, Mateusz; Maitra, Neepa T.; Dannenberg, J. J.

2012-10-01

We compare dispersion and induction interactions for noble gas dimers and for Ne, methane, and 2-butyne with HF and LiF using a variety of functionals (including some specifically parameterized to evaluate dispersion interactions) with ab initio methods including CCSD(T) and MP2. We see that inductive interactions tend to enhance dispersion and may be accompanied by charge-transfer. We show that the functionals do not generally follow the expected trends in interaction energies, basis set superposition errors (BSSE), and interaction distances as a function of basis set size. The functionals parameterized to treat dispersion interactions often overestimate these interactions, sometimes by quite a lot, when compared to higher level calculations. Which functionals work best depends upon the examples chosen. The B3LYP and X3LYP functionals, which do not describe pure dispersion interactions, appear to describe dispersion mixed with induction about as accurately as those parametrized to treat dispersion. We observed significant differences in high-level wavefunction calculations in a basis set larger than those used to generate the structures in many of the databases. We discuss the implications for highly parameterized functionals based on these databases, as well as the use of simple potential energy for fitting the parameters rather than experimentally determinable thermodynamic state functions that involve consideration of vibrational states.

Hydrogen Gas Sensing Characteristics of Nanostructured NiO Thin Films Synthesized by SILAR Method

Science.gov (United States)

Karaduman, Irmak; Çorlu, Tugba; Yıldırım, M. Ali; Ateş, Aytunç; Acar, Selim

2017-07-01

Nanostructured NiO thin films have been synthesized by a facile, low-cost successive ionic layer adsorption and reaction (SILAR) method, and the effects of the film thickness on their hydrogen gas sensing properties investigated. The samples were characterized by scanning electron microscopy (SEM), x-ray diffraction (XRD) analysis, and energy-dispersive x-ray analysis. The XRD results revealed that the crystallinity improved with increasing thickness, exhibiting polycrystalline structure. SEM studies showed that all the films covered the glass substrate well. According to optical absorption measurements, the optical bandgap decreased with increasing film thickness. The gas sensing properties of the nanostructured NiO thin films were studied as a function of operating temperature and gas concentration. The samples showed good sensing performance of H2 gas with high response. The maximum response was 75% at operating temperature of 200°C for hydrogen gas concentration of 40 ppm. These results demonstrate that nanostructured NiO thin films synthesized by the SILAR method have potential for application in hydrogen detection.

A multi vector energy analysis for interconnected power and gas systems

International Nuclear Information System (INIS)

Devlin, Joseph; Li, Kang; Higgins, Paraic; Foley, Aoife

2017-01-01

Highlights: • The first multi vector energy system analysis for Britain and Ireland is performed. • Extreme weather driven gas demands were utilised to increase gas system stress. • GB gas system is capable of satisfying demand but restricts gas generator ramping. • Irish gas system congestion causes a 40% increase in gas generator short run cost. • Gas storage in Ireland relieved congestion reduced operational costs by 14%. - Abstract: This paper presents the first multi vector energy analysis for the interconnected energy systems of Great Britain (GB) and Ireland. Both systems share a common high penetration of wind power, but significantly different security of supply outlooks. Ireland is heavily dependent on gas imports from GB, giving significance to the interconnected aspect of the methodology in addition to the gas and power interactions analysed. A fully realistic unit commitment and economic dispatch model coupled to an energy flow model of the gas supply network is developed. Extreme weather events driving increased domestic gas demand and low wind power output were utilised to increase gas supply network stress. Decreased wind profiles had a larger impact on system security than high domestic gas demand. However, the GB energy system was resilient during high demand periods but gas network stress limited the ramping capability of localised generating units. Additionally, gas system entry node congestion in the Irish system was shown to deliver a 40% increase in short run costs for generators. Gas storage was shown to reduce the impact of high demand driven congestion delivering a reduction in total generation costs of 14% in the period studied and reducing electricity imports from GB, significantly contributing to security of supply.

SAGE measurements of the stratospheric aerosol dispersion and loading from the Soufriere Volcano

Science.gov (United States)

Mccormick, M. P.; Kent, G. S.; Yue, G. K.; Cunnold, D. M.

1981-01-01

Explosions of the Soufriere volcano on the Caribbean Island of St. Vincent reduced two major stratospheric plumes which the stratospheric aerosol and gas experiment (SAGE) satellite tracked to West Africa and the North Atlantic Ocean. The total mass of the stratospheric ejecta measured is less than 0.5% of the global stratospheric aerosol burden. No significant temperature or climate perturbation is expected. It is found that the movement and dispersion of the plumes agree with those deduced from high altitude meteorological data and dispersion theory. The stratospheric aerosol dispersion and loading from the Soufrier volcano was measured.

Annular dispersed flow analysis model by Lagrangian method and liquid film cell method

International Nuclear Information System (INIS)

Matsuura, K.; Kuchinishi, M.; Kataoka, I.; Serizawa, A.

2003-01-01

A new annular dispersed flow analysis model was developed. In this model, both droplet behavior and liquid film behavior were simultaneously analyzed. Droplet behavior in turbulent flow was analyzed by the Lagrangian method with refined stochastic model. On the other hand, liquid film behavior was simulated by the boundary condition of moving rough wall and liquid film cell model, which was used to estimate liquid film flow rate. The height of moving rough wall was estimated by disturbance wave height correlation. In each liquid film cell, liquid film flow rate was calculated by considering droplet deposition and entrainment flow rate. Droplet deposition flow rate was calculated by Lagrangian method and entrainment flow rate was calculated by entrainment correlation. For the verification of moving rough wall model, turbulent flow analysis results under the annular flow condition were compared with the experimental data. Agreement between analysis results and experimental results were fairly good. Furthermore annular dispersed flow experiments were analyzed, in order to verify droplet behavior model and the liquid film cell model. The experimental results of radial distribution of droplet mass flux were compared with analysis results. The agreement was good under low liquid flow rate condition and poor under high liquid flow rate condition. But by modifying entrainment rate correlation, the agreement become good even under high liquid flow rate. This means that basic analysis method of droplet and liquid film behavior was right. In future work, verification calculation should be carried out under different experimental condition and entrainment ratio correlation also should be corrected

Investigations on chloride-induced high temperature corrosion of iron-, nickel-, cobalt-base alloys by scanning electron microscopy and energy dispersive X-ray microspot analysis

International Nuclear Information System (INIS)

Ross, W.; Umland, F.

1984-01-01

The direct oxidation at 900 0 C in air and the corrosion of alloys in air after short exposure to chloride have been compared under identical conditions. Chloride destroys the original oxide layers by recristallisation and modifies the following scale growing in such a manner that no firmly sticking layers can be rebuilt. After a chloride induction therefore all other following corrosions will be enhanced. Experiments in a closed system, a so called transport furnace, showed that the chloride also acts as a gas phase carrier transporting firstly the oxide layer, under reducing conditions metals, too, as volatile chloro metal gas complexes in this case from hot to cold region of the furnace. Cobalt base alloys are less attacked than iron or nickel base alloys. As chloride is not found implicitly on the treated surface the identification of the chloride induced corrosion is difficult. However the scanning electron microscopy combined with quantitative energy dispersive X-ray analysis has been proved as an appropriate method for early detection. As the phenomena depend on the type of alloy, respectively, an illustration and interpretation catalogue is necessary. (orig.) [de

Technology and products of gas companies; Gas gaisha no Technology and Products

Energy Technology Data Exchange (ETDEWEB)

NONE

1998-06-10

This paper presents the latest technology and products of gas companies. `Newly developed gas table for one-push automatic fish broiling` of Tokyo Gas Co. `Catalytic technology for decomposing dioxin generated by incinerator to make it harmless` of Osaka Gas Co. `Newly developed strong and kindly shower head` of Tokyo Gas Co. By laying fish on a sensor in a grill and appropriately setting upper and lower heating levers, user can skillfully broil fish only by pushing an ignition button. A temperature sensor attached to the center of a grill catches a change in surface temperature of fish, and automatically sets an appropriate broiling time according to the kind and volume of fish. A finish buzzer and automatic extinction mechanism are prepared. The technology decomposes dioxin in exhaust gas of incinerators to make it harmless. The catalyst is prepared by dispersing noble metal or oxide of several angstroms into activated carbon fibers. The shower head can switch hot water power by a control handle

Optical transmission testing based on asynchronous sampling techniques: images analysis containing chromatic dispersion using convolutional neural network

Science.gov (United States)

Mrozek, T.; Perlicki, K.; Tajmajer, T.; Wasilewski, P.

2017-08-01

The article presents an image analysis method, obtained from an asynchronous delay tap sampling (ADTS) technique, which is used for simultaneous monitoring of various impairments occurring in the physical layer of the optical network. The ADTS method enables the visualization of the optical signal in the form of characteristics (so called phase portraits) that change their shape under the influence of impairments such as chromatic dispersion, polarization mode dispersion and ASE noise. Using this method, a simulation model was built with OptSim 4.0. After the simulation study, data were obtained in the form of images that were further analyzed using the convolutional neural network algorithm. The main goal of the study was to train a convolutional neural network to recognize the selected impairment (distortion); then to test its accuracy and estimate the impairment for the selected set of test images. The input data consisted of processed binary images in the form of two-dimensional matrices, with the position of the pixel. This article focuses only on the analysis of images containing chromatic dispersion.

Standard test methods for chemical analysis of ceramic whiteware materials using wavelength dispersive X-Ray fluorescence spectrometry

CERN Document Server

American Society for Testing and Materials. Philadelphia

2004-01-01

1.1 These test methods cover the determination of ten major elements (SiO2, Al2O3, Fe2O3, MgO, CaO, Na2O, K2O, TiO2, P2O5, MnO, and LOI in ceramic whitewares clays and minerals using wavelength dispersive X-ray fluorescence spectrometry (WDXRF). The sample is first ignited, then fused with lithium tetraborate and the resultant glass disc is introduced into a wavelength dispersive X-ray spectrometer. The disc is irradiated with X-rays from an X-ray tube. X-ray photons emitted by the elements in the samples are counted and concentrations determined using previously prepared calibration standards. (1) In addition to 10 major elements, the method provides a gravimetric loss-on-ignition. Note 1—Much of the text of this test method is derived directly from Major element analysis by wavelength dispersive X-ray fluorescence spectrometry, included in Ref (1). 1.2 Interferences, with analysis by WDXRF, may result from mineralogical or other structural effects, line overlaps, and matrix effects. The structure of the...

Evaluating realized seed dispersal across fragmented tropical landscapes: a two-fold approach using parentage analysis and the neighbourhood model.

Science.gov (United States)

Ismail, Sascha A; Ghazoul, Jaboury; Ravikanth, Gudasalamani; Kushalappa, Cheppudira G; Uma Shaanker, Ramanan; Kettle, Chris J

2017-05-01

Despite the importance of seed dispersal for survival of plant species in fragmented landscapes, data on seed dispersal at landscape scales remain sparse. Effective seed dispersal among fragments determines recolonization and plant species persistence in such landscapes. We present the first large-scale (216-km 2 ) direct estimates of realized seed dispersal of a high-value timber tree (Dysoxylum malabaricum) across an agro-forest landscape in the Western Ghats, India. Based upon an exhaustive inventory of adult trees and a sample of 488 seedlings all genotyped at 10 microsatellite loci, we estimated realized seed dispersal using parentage analysis and the neighbourhood model. Our estimates found that most realized seed dispersal was within 200 m, which is insufficient to effectively bridge the distances between forest patches. We conclude that using mobility of putative animal dispersers can be misleading when estimating tropical tree species vulnerability to habitat fragmentation. This raises serious concerns about the potential of many tropical trees to recolonize isolated forest patches where high-value tree species have already been removed. © 2017 The Authors. New Phytologist © 2017 New Phytologist Trust.

Technical and Feasibility Analysis of Gasoline and Natural Gas Fuelled Vehicles

Directory of Open Access Journals (Sweden)

Charalambos Chasos

2014-03-01

Full Text Available There is recent interest for the utilisation of natural gas for empowering the internal combustion engines (ICE of vehicles. The production of novel natural gas ICE for vehicles, as well as the conversion of existing gasoline fuelled ICE of vehicles to natural gas fuelled ICE are new technologies which require to be analysed and assessed. The objective of the present study is to examine the adaptation of natural gas as vehicle fuel and carry out a technical analysis and an economical feasibility analysis of the two types of ICE vehicles, namely gasoline and natural gas fuelled vehicles. The technical model uses the physical properties of the two fuels and the performance factors of internal combustion engines including brake thermal efficiency. The resulting exhaust gas emissions are also estimated by the technical model using combustion calculations which provide the expected levels of exhaust gas emissions. Based on the analysis with the technical model, comparisons of the two types of engines are performed. Furthermore, the estimated performance characteristics of the two types of engines, along with local statistical data on annual fuel imports and annual fuel consumption for transportation and data on the vehicles fleet for the case study of Cyprus are used as input in the economical model. For the base year 2013, data of natural gas price is also used in the economical model. The economical model estimates the capital cost, the carbon dioxide emissions avoidance of fines, the net present value and the internal rate of return of the investment of large scale adaptation of natural gas fuelled vehicles for the case study. From the results and comparisons, conclusions are drawn and recommendations are provided for the adaptation of natural gas vehicles which can provide improved performance with reduced pollutant emissions.

Irradiation behavior of U{sub 6}Mn-Al dispersion fuel elements

Energy Technology Data Exchange (ETDEWEB)

Meyer, M.K. E-mail: mitchell.meyer@anl.gov; Wiencek, T.C.; Hayes, S.L.; Hofman, G.L

2000-04-01

Irradiation testing of U{sub 6}Mn-Al dispersion fuel miniplates was conducted in the Oak Ridge Research Reactor (ORR). Post-irradiation examination showed that U{sub 6}Mn in an unrestrained plate configuration performs similarly to U{sub 6}Fe under irradiation, forming extensive and interlinked fission gas bubbles at a fission density of approximately 3x10{sup 27} m{sup -3}. Fuel plate failure occurs by fission gas pressure driven 'pillowing' on continued irradiation.

In-Vial Micro-Matrix-Solid Phase Dispersion for the Analysis of Fragrance Allergens, Preservatives, Plasticizers, and Musks in Cosmetics

Directory of Open Access Journals (Sweden)

Maria Celeiro

2014-07-01

Full Text Available Fragrance allergens, preservatives, plasticizers, and synthetic musks are usually present in cosmetic and personal care products formulations and many of them are subjected to use restrictions or labeling requirements. Matrix solid-phase dispersion (MSPD is a very suitable analytical technique for the extraction of these compounds providing a simple, low cost sample preparation, and the possibility of performing both extraction and clean-up in one step, reducing possible contamination and analyte losses. This extraction technique has been successfully applied to many cosmetics ingredients allowing obtaining quantitative recoveries. A new very simple micro-MSPD procedure performing the disruption step in a vial is proposed for the gas chromatography-mass spectrometry (GC-MS analysis of 66 chemicals usually present in cosmetics and personal care products. The method was validated showing general recoveries between 80% and 110%, relative standard deviation (RSD values lower than 15%, and limits of detection (LODs below 30 ng·g−1. The validated method was applied to a broad range of cosmetics and personal care products, including several products intended for baby care.

Transmission electron microscopy characterization of irradiated U-7Mo/Al-2Si dispersion fuel

International Nuclear Information System (INIS)

Gan, J.; Keiser, D.D.; Wachs, D.M.; Robinson, A.B.; Miller, B.D.; Allen, T.R.

2010-01-01

The plate-type dispersion fuels, with the atomized U(Mo) fuel particles dispersed in the Al or Al alloy matrix, are being developed for use in research and test reactors worldwide. It is found that the irradiation performance of a plate-type dispersion fuel depends on the radiation stability of the various phases in a fuel plate. Transmission electron microscopy was performed on a sample (peak fuel mid-plane temperature ∼109 deg. C and fission density ∼4.5 x 10 27 f m -3 ) taken from an irradiated U-7Mo dispersion fuel plate with Al-2Si alloy matrix to investigate the role of Si addition in the matrix on the radiation stability of the phase(s) in the U-7Mo fuel/matrix interaction layer. A similar interaction layer that forms in irradiated U-7Mo dispersion fuels with pure Al matrix has been found to exhibit poor irradiation stability, likely as a result of poor fission gas retention. The interaction layer for both U-7Mo/Al-2Si and U-7Mo/Al fuels is observed to be amorphous. However, unlike the latter, the amorphous layer for the former was found to effectively retain fission gases in areas with high Si concentration. When the Si concentration becomes relatively low, the fission gas bubbles agglomerate into fewer large pores. Within the U-7Mo fuel particles, a bubble superlattice ordered as fcc structure and oriented parallel to the bcc metal lattice was observed where the average bubble size and the superlattice constant are 3.5 nm and 11.5 nm, respectively. The estimated fission gas inventory in the bubble superlattice correlates well with the fission density in the fuel.

INFLUENCE OF FUEL-MATRIX INTERACTION ON THE BREAKAWAY SWELLING OF U-MO DISPERSION FUEL IN AL

OpenAIRE

HO JIN RYU; YEON SOO KIM

2014-01-01

In order to advance understanding of the breakaway swelling behavior of U-Mo/Al dispersion fuel under a high-power irradiation condition, the effects of fuel-matrix interaction on the fuel performance of U-Mo/Al dispersion fuel were investigated. Fission gas release into large interfacial pores between interaction layers and the Al matrix was analyzed using both mechanistic models and observations of the post-irradiation examination results of U-Mo dispersion fuels. Using the model prediction...

Dispersion Analysis of the XM881APFSDS Projectile

Directory of Open Access Journals (Sweden)

Thomas F. Erline

2001-01-01

Full Text Available This study compares the results of a dispersion test with mathematical modeling. A 10-round group of modified 25-mm XM881 Armor Piercing Fin Stabilized Discarding Sabot projectiles was fired from the M242 chain gun into a designated target. The mathematical modeling results come from BALANS, a product of Arrow Tech Associates. BALANS is a finite-element lumped parameter code that has the capability to model a flexible projectile being fired from a flexible gun. It also has the unique feature of an automated statistical evaluation of dispersion. This study represents an effort to evaluate a simulation approach with experiment.

Compound Method to Disperse CaCO3 Nanoparticles to Nano-Size in Water.

Science.gov (United States)

Gu, Sui; Cai, Jihua; Wang, Jijun; Yuan, Ye; Chang, Dewu; Chikhotkin, Viktor F

2015-12-01

The invalidation of CaCO3 nanoparticles (nCaCO3) is often caused by the fact of agglomeration and inhomogeneous dispersion which limits its application into water-based drilling muds for low permeability reservoirs such as coalbed methane reservoir and shale gas/oil reservoir. Effective methods to disperse nCaCO3 to nano-size (≤ 100 nm) in water have seldom been reported. Here we developed a compound method containing mechanical stirring, ultrasonic treatment, the use of surfactant and stabilizer to disperse nCaCO3 in water. It comprises the steps adding 2% nCaCO3, 1% sodium dodecyl sulfonate (SDS), 2% cetyltrimethyl ammonium bromide (CTAB), 2% OP-10, 3% to 4% biopolymer (XC) in water successively, stirring it at a shear rate of 6000 to 8000 r/min for 15 minutes and treating it with ultrasonic at a frequency of 28 KHz for 30 to 40 minutes. The dispersed nCaCO3 was characterized with scanning electron microscope (SEM), transmission electron microscope (TEM) and particle size distribution (PSD) tests. We found that nCaCO3 could be dispersed to below 100 nm in water and the medium value of nCaCO3 was below 50 nm. This method paved the way for the utilization of nCaCO3 in drilling fluid and completion fluid for low permeability reservoirs such as coal seams and shale gas/oil formations.

Analysis of the dispersion of air pollutants from a factory Asphalt in Nuevo Vallarta, Nay., Mex

Science.gov (United States)

Carrillo-Gonzalez, F. M.; Gaitán-Rodríguez, M.; Cornejo-López, V. M.; Morales-Hernández, J. C.

2013-12-01

An asphalt factory has operated intermittently near the urban area of Nuevo Vallarta on Banderas Bay, Nayarit, Mex. This factory has emissions that can affect the health of people living in the colonies nearest are Valle Dorado and San Vicente. The dispersion of emissions depends on the wind (sea breeze-land breeze) and the roof of the inversion, these phenomena determined by the density and temperature of the lower layers of the atmosphere. Asphalts are dark colored binder materials, formed by a complex non-volatile hydrocarbon chains and high molecular weight. Asphalts are produced from petroleum, but by a process of evaporation of the volatiles, leaving the asphalt alone. Therefore, the material emitted by the fireplace are mainly low molecular weight hydrocarbons known as polycyclic aromatic hydrocarbons (PAHs). The Emergency Response Guide 2008 developed by various agencies in Canada, U.S. and Mexico mentions that the hydrocarbon gas can have health effects. Animal studies have shown that PAHs can cause harmful effects to the skin, body fluids and some PAHs are carcinogenic. An analysis of the wind field, monthly and seasonal averages for the years 2010 and 2011, recorded in AWS administered by the CEMCO and other stations located near the study area.

Application of direct peak analysis to energy dispersive x-ray fluorescence spectra

International Nuclear Information System (INIS)

Nielson, K.K.

1977-07-01

A modified Covell method for direct peak analysis has been applied to energy dispersive x-ray fluorescence spectra. The method is background independent and is well-suited to computerized data reduction. It provides acceptable precision, minimizes errors from instrumental gain shift, and permits peak overlap correction. Peak overlap errors exhibit both positive and negative nodes as a function of peak separation distance, and are corrected using concentration ratios determined from thin, single-element standards. Peak precisions and overlaps are evaluated as a function of window width to aid in width selection. Least-square polynomial smoothing prior to peak analysis significantly improves peak area precisions without significantly affecting their accuracies

Towards Breath Gas Analysis Based on Millimeter-Wave Molecular Spectroscopy

Science.gov (United States)

Rothbart, Nick; Hübers, Heinz-Wilhelm; Schmalz, Klaus; Borngräber, Johannes; Kissinger, Dietmar

2018-03-01

Breath gas analysis is a promising non-invasive tool for medical diagnosis as there are thousands of Volatile Organic Compounds (VOCs) in human breath that can be used as health monitoring markers. Millimeter-wave/terahertz molecular spectroscopy is highly suitable for breath gas analysis due to unique fingerprint spectra of many VOCs in that frequency range. We present our recent work on sensor systems for gas spectroscopy based on integrated transmitters (TX) and receivers (RX) fabricated in IHP's 0.13 μm SiGe BiCMOS technology. For a single-band system, spectroscopic measurements and beam profiles are presented. The frequency is tuned by direct voltage-frequency tuning and by a fractional-n PLL, respectively. The spectroscopic system includes a folded gas absorption cell with gas pre-concentration abilities demonstrating the detection of a 50 ppm mixture of ethanol in ambient air corresponding to a minimum detectable concentration of 260 ppb. Finally, the design of a 3-band system covering frequencies from 225 to 273 GHz is introduced.

Investigation of Factors Influencing Dispersion of Liquid Hydrocarbons in Porous Media

Directory of Open Access Journals (Sweden)

Hussain Ali Baker

2016-08-01

Full Text Available An experimental work has been done to study the major factors that affect the axial dispersion of some hydrocarbons during liquid-liquid miscible displacement. Kerosene and gas oil are used as displacing phase while seven liquid hydrocarbons of high purity represent the displaced phase, three of the liquids are aromatics and the rest are of paraffinic base. In conducting the experiments, two packed beds of different porosity and permeability are used as porous media. The results showed that the displacement process is not a piston flow, breakthrough of displacing fluids are shown before one pore volume has been injected. The processes are stable with no evidence of viscous fingering. Dispersion model as adapted by Brigham et.al (1961 is used to determine the axial dispersion coefficient of displacing fluid. The results show an increasing in dispersion coefficient as the interstitial velocity and viscosity ratio increases.

Effect of the Duration of Meteorological Data Collection on the Atmospheric Dispersion Assessment

International Nuclear Information System (INIS)

Choi, Yoo-mi; Kim, Eun-hee

2017-01-01

This study regards the duration of meteorological data record for a prospective assessment of the environmental impact of gas release from Kori nuclear power plant under normal operation. We compared the atmospheric dispersion factors obtained by employing the meteorological data from 2- and 5-year durations with the corresponding values obtained by employing yearly meteorological data in the period of 2001 to 2008. Influence of the duration of meteorological data collection on short-term atmospheric dispersion factors was previously studied. In this study, long-term dispersion factors were assessed to investigate the influence of the duration of meteorological data collection on the assessment of environmental impact by gas release from Kori nuclear power plant under normal operation. We counted how many yearly meteorological conditions would be represented by 2 or 5 years of long-term data collection. The distribution of shaded cells in Tables I and II indicated that some of the yearly meteorological condition could be properly represented by the conditions averaged over 2- or 5-year durations.

Gas kinematics in FIRE simulated galaxies compared to spatially unresolved H I observations

Science.gov (United States)

El-Badry, Kareem; Bradford, Jeremy; Quataert, Eliot; Geha, Marla; Boylan-Kolchin, Michael; Weisz, Daniel R.; Wetzel, Andrew; Hopkins, Philip F.; Chan, T. K.; Fitts, Alex; Kereš, Dušan; Faucher-Giguère, Claude-André

2018-06-01

The shape of a galaxy's spatially unresolved, globally integrated 21-cm emission line depends on its internal gas kinematics: galaxies with rotationally supported gas discs produce double-horned profiles with steep wings, while galaxies with dispersion-supported gas produce Gaussian-like profiles with sloped wings. Using mock observations of simulated galaxies from the FIRE project, we show that one can therefore constrain a galaxy's gas kinematics from its unresolved 21-cm line profile. In particular, we find that the kurtosis of the 21-cm line increases with decreasing V/σ and that this trend is robust across a wide range of masses, signal-to-noise ratios, and inclinations. We then quantify the shapes of 21-cm line profiles from a morphologically unbiased sample of ˜2000 low-redshift, H I-detected galaxies with Mstar = 107-11 M⊙ and compare to the simulated galaxies. At Mstar ≳ 1010 M⊙, both the observed and simulated galaxies produce double-horned profiles with low kurtosis and steep wings, consistent with rotationally supported discs. Both the observed and simulated line profiles become more Gaussian like (higher kurtosis and less-steep wings) at lower masses, indicating increased dispersion support. However, the simulated galaxies transition from rotational to dispersion support more strongly: at Mstar = 108-10 M⊙, most of the simulations produce more Gaussian-like profiles than typical observed galaxies with similar mass, indicating that gas in the low-mass simulated galaxies is, on average, overly dispersion supported. Most of the lower-mass-simulated galaxies also have somewhat lower gas fractions than the median of the observed population. The simulations nevertheless reproduce the observed line-width baryonic Tully-Fisher relation, which is insensitive to rotational versus dispersion support.

Fate of dispersants associated with the deepwater horizon oil spill.

Science.gov (United States)

Kujawinski, Elizabeth B; Kido Soule, Melissa C; Valentine, David L; Boysen, Angela K; Longnecker, Krista; Redmond, Molly C

2011-02-15

Response actions to the Deepwater Horizon oil spill included the injection of ∼771,000 gallons (2,900,000 L) of chemical dispersant into the flow of oil near the seafloor. Prior to this incident, no deepwater applications of dispersant had been conducted, and thus no data exist on the environmental fate of dispersants in deepwater. We used ultrahigh resolution mass spectrometry and liquid chromatography with tandem mass spectrometry (LC/MS/MS) to identify and quantify one key ingredient of the dispersant, the anionic surfactant DOSS (dioctyl sodium sulfosuccinate), in the Gulf of Mexico deepwater during active flow and again after flow had ceased. Here we show that DOSS was sequestered in deepwater hydrocarbon plumes at 1000-1200 m water depth and did not intermingle with surface dispersant applications. Further, its concentration distribution was consistent with conservative transport and dilution at depth and it persisted up to 300 km from the well, 64 days after deepwater dispersant applications ceased. We conclude that DOSS was selectively associated with the oil and gas phases in the deepwater plume, yet underwent negligible, or slow, rates of biodegradation in the affected waters. These results provide important constraints on accurate modeling of the deepwater plume and critical geochemical contexts for future toxicological studies.

Characterization of volatile organic compounds emissions from municipal landfill and their dispersion in the environment; Caracterisation des emissions de composes organiques volatils issus des centre de stockage de dechets menagers et assimiles et de leur dispersion dans l'environnement

Energy Technology Data Exchange (ETDEWEB)

Chiriac, R.E.

2004-12-15

A municipal landfill causes atmospheric pollution by the emission of trace volatile organic compounds (VOCs) that are harmful for health and environment. Beyond the adsorption technique on sorbent tubes followed by solvent extraction and GC/MS analysis in the laboratory, a pre-concentrator-thermodesorption /micro-gas chromatograph coupling was developed for on-site monitoring of trace VOCs. To evaluate the environmental impact of this traces various studies were realized: 'Study of the emission of VOCs from landfill cells in use', 'Study of the formation of VOCs from a pilot-scale municipal landfill', 'Study of the dispersion of VOCs from a municipal landfill'. All the results permitted a closer appraisal of the emission and dispersion phenomena of VOCs from a municipal landfill. (author)

Analysis of kiwi fruit (Accented deliciosa) by energy dispersive X-ray fluorescence spectra

International Nuclear Information System (INIS)

Oliveira, Ana Claudia S.; Oliveira, Marcia L. de; Silva, Lucia C.A.S.; Arthur, Valter; Almeida, Eduardo

2011-01-01

The search for a healthy life has led consumers to eat fruits and vegetables in place of manufactured products, however, the demand for minimally processed products has evolved rapidly. The kiwi has at least eight nutrients beneficial to health: calcium, magnesium, manganese, phosphorus, iron, potassium, sodium and has also high vitamin C, which has wide acceptance in consumer markets. Energy dispersive spectroscopy X-ray (EDX) is the analytical technique used for elemental analysis or chemical characterization of a sample. It is a variant of fluorescence spectroscopy X-ray based on the sample through an investigation of interactions between electromagnetic radiation and matter, analyzing X-rays emitted by matter in response to being struck by charged particles. The aim of this study were to determine potassium, calcium, iron and bromine (K, Ca, Fe and Br, respectively) present in kiwifruit using the technique of fluorescence X-ray energy dispersive (EDXRF). Kiwifruit were peeled, washed and cut into slices and freeze-dried. After drying the sample was held digestion and subsequent reading of the same equipment in the X-ray fluorescence energy dispersive (EDXRF). The results indicated that the contents of potassium, calcium, iron and bromine are present in kiwifruit as expected when compared to Brazilian Table of Food Composition. (author)

DEVELOPMENT OF MORE-EFFICIENT GAS FLOODING APPLICABLE TO SHALLOW RESERVOIRS

Energy Technology Data Exchange (ETDEWEB)

William R. Rossen; Russell T. Johns; Gary A. Pope

2003-08-21

The objective of this research is to widen the applicability of gas flooding to shallow oil reservoirs by reducing the pressure required for miscibility using gas enrichment and increasing sweep efficiency with foam. Task 1 examines the potential for improved oil recovery with enriched gases. Subtask 1.1 examines the effect of dispersion processes on oil recovery and the extent of enrichment needed in the presence of dispersion. Subtask 1.2 develops a fast, efficient method to predict the extent of enrichment needed for crude oils at a given pressure. Task 2 develops improved foam processes to increase sweep efficiency in gas flooding. Subtask 2.1 comprises mechanistic experimental studies of foams with N2 gas. Subtask 2.2 conducts experiments with CO{sub 2} foam. Subtask 2.3 develops and applies a simulator for foam processes in field application.

Experiments on melt dispersion with lateral failure in the bottom head of the pressure vessel

Energy Technology Data Exchange (ETDEWEB)

Meyer, L.; Gargallo, M. [Forschungszentrum Karlsruhe, Institut fur Kern-und Energietechnik, Karlsruhe (Germany)

2001-07-01

Melt dispersion experiments with lateral failure in the bottom head were carried out in a 1:18 scaled annular cavity design under low pressure conditions. Water and a bismuth alloy were used as melt simulant material and nitrogen as driving gas. With lateral breaches the liquid height in the lower head relative to the upper and lower edge of the breach is an additional parameter for the dispersion process. Shifting the break from the central position towards the side of the lower head leads to smaller melt dispersion, and a larger breach size does not necessarily lead to a larger dispersed melt fraction. (author)

Improvements in or relating to handling of flue gas

International Nuclear Information System (INIS)

Ingham, R.V.

1986-01-01

The patent describes improvements in the method for handling flue gas from the burning of fossil fuels. The method relates to cleaning the flue gas, from which the sulphur compounds are removed. The gas in then heated by heat derived from a nuclear source, which may be nuclear waste. The heat treatment gives efficient atmospheric dispersion from the chimney. (U.K.)

Screening apatites for (U-Th)/He thermochronometry via continuous ramped heating: He age components and implications for age dispersion

Science.gov (United States)

McDannell, Kalin T.; Zeitler, Peter K.; Janes, Darwin G.; Idleman, Bruce D.; Fayon, Annia K.

2018-02-01

Old slowly-cooled apatites often yield dispersed (U-Th)/He ages for a variety of reasons, some well understood and some not. Analytical protocols like careful grain selection can reduce the impact of this dispersion but add costs in time and resources and too often have proven insufficient. We assess a new analytical protocol that utilizes static-gas measurement during continuous ramped heating (CRH) as a means to rapidly screen apatite samples. In about the time required for a conventional total-gas analysis, this method can discriminate between samples showing expected volume-diffusion behavior and those showing anomalous release patterns inconsistent with their direct use in thermochronologic applications. This method also appears able to discriminate between the radiogenic and extraneous 4He fractions released by a sample, potentially allowing ages to be corrected. Well-behaved examples such as the Durango standard and other apatites with good age reproducibility show the expected smooth, sigmoidal gas-release curves predicted for volume diffusion using typical apatite kinetics, with complete exhaustion by ∼900 °C for linear heating at 20 °C/min. Secondary factors such as U and Th zoning and alpha-loss distribution have a relatively minor impact on such profiles. In contrast, samples having greater age dispersion show significant He release in the form of outgassing spikes and He release deferred to higher temperatures. Screening results for a range of samples permit us to assess the degree to which CRH screening can identify misbehaving grains, give insight into the source of extraneous He, and suggest that in some cases it may be possible to correct ages for the presence of such components.

Radiative heat transfer in the Na mist dispersion over the hot surface of liquid Na in the cooling system of nuclear reactor

International Nuclear Information System (INIS)

Kunitomo, T.; Shafey, H.M.

1980-01-01

The analysis has been carried out for the radiative heat transfer in the Na mist dispersion enclosed between the hot surface of liquid Na at temperature Tsub(n) and the cold surface of Na deposit at Tsub(c). The model selected for the present study represents the Na mist formed in a sodium cooled fast breeder reactor in which the condensed liquid particles are dispersed in the mixture of the Ar cover gas and the Na vapor. The analysis is based on replacing the inhomogeneous dispersing medium by three discrete homogeneous layers, and formulating the transfer equation for the monochromatic radiation in each layer according to the Chandrasekhar theory. The numerical calculations of the radiative qsub(r) and convective qsub(c) heat transfers have been performed for the wave length range lambda=1.6-30 μm and are compared. The qsub(r) has the same order of magnitude as the qsub(c) for all conditions of the mist dispersions. Both qsub(r) and qsub(c) increase by nearly equal rates with the increase of Tsub(H) and decrease by different rates with increasing Tsub(c). Variations of the particle diameter of the Na mist do not change substantially the qsub(r). Both qsub(r) and qsub(c) decrease slightly with the increase in the total thickness of the Na mist dispersion

Coal beneficiation by gas agglomeration

Science.gov (United States)

Wheelock, Thomas D.; Meiyu, Shen

2003-10-14

Coal beneficiation is achieved by suspending coal fines in a colloidal suspension of microscopic gas bubbles in water under atmospheric conditions to form small agglomerates of the fines adhered by the gas bubbles. The agglomerates are separated, recovered and resuspended in water. Thereafter, the pressure on the suspension is increased above atmospheric to deagglomerate, since the gas bubbles are then re-dissolved in the water. During the deagglomeration step, the mineral matter is dispersed, and when the pressure is released, the coal portion of the deagglomerated gas-saturated water mixture reagglomerates, with the small bubbles now coming out of the solution. The reagglomerate can then be separated to provide purified coal fines without the mineral matter.

Application of energy dispersive x-ray techniques for water analysis

International Nuclear Information System (INIS)

Funtua, I. I.

2000-07-01

Energy dispersive x-ray fluorescence (EDXRF) is a class of emission spectroscopic techniques that depends upon the emission of characteristic x-rays following excitation of the atomic electron energy levels by tube or isotopic source x-rays. The technique has found wide range of applications that include determination of chemical elements of water and water pollutants. Three EDXRF systems, the isotopic source, secondary target and total reflection (TXRF) are available at the Centre for Energy research and Training. These systems have been applied for the analysis of sediments, suspensions, ground water, river and rainwater. The isotopic source is based on 55 Fe, 109 Cd and 241 Am excitations while the secondary target and the total reflection are utilizing a Mo x-ray tube. Sample preparation requirements for water analysis range from physical and chemical pre-concentration steps to direct analysis and elements from Al to U can be determined with these systems. The EDXRF techniques, TXRF in particular with its multielement capability, low detection limit and possibility of direct analysis for water have competitive edge over the traditional methods of atomic absorption and flame photometry

Dispersion analysis of the Pn -Pn-1DG mixed finite element pair for atmospheric modelling

Science.gov (United States)

Melvin, Thomas

2018-02-01

Mixed finite element methods provide a generalisation of staggered grid finite difference methods with a framework to extend the method to high orders. The ability to generate a high order method is appealing for applications on the kind of quasi-uniform grids that are popular for atmospheric modelling, so that the method retains an acceptable level of accuracy even around special points in the grid. The dispersion properties of such schemes are important to study as they provide insight into the numerical adjustment to imbalance that is an important component in atmospheric modelling. This paper extends the recent analysis of the P2 - P1DG pair, that is a quadratic continuous and linear discontinuous finite element pair, to higher polynomial orders and also spectral element type pairs. In common with the previously studied element pair, and also with other schemes such as the spectral element and discontinuous Galerkin methods, increasing the polynomial order is found to provide a more accurate dispersion relation for the well resolved part of the spectrum but at the cost of a number of unphysical spectral gaps. The effects of these spectral gaps are investigated and shown to have a varying impact depending upon the width of the gap. Finally, the tensor product nature of the finite element spaces is exploited to extend the dispersion analysis into two-dimensions.

Matrix solid-phase dispersion followed by gas chromatography tandem mass spectrometry for the determination of benzotriazole UV absorbers in sediments.

Science.gov (United States)

Carpinteiro, I; Abuín, B; Ramil, M; Rodríguez, I; Cela, R

2012-01-01

A cost-effective and low solvent consumption method, based on the matrix solid-phase dispersion (MSPD) technique, for the determination of six benzotriazole UV absorbers in sediments is presented. Sieved samples (0.5 g) were first mixed in a mortar with a solid sorbent and then transferred to a polypropylene syringe containing a layer of clean-up co-sorbent. Analytes were eluted with a suitable solvent and further determined by gas chromatography with tandem mass spectrometry (GC-MS/MS). Under final conditions, diatomaceous earth and silica, deactivated to 10%, were used as inert dispersant and clean-up co-sorbent, respectively. Analytes were recovered using just 5 mL of dichloromethane, and this extract was concentrated and exchanged to 1 mL of isooctane. Further removal of co-extracted sulphur was achieved adding activated copper powder to final extracts, which were stored overnight, before injection in the GC-MS/MS system. The accuracy of the method was assessed with river and marine sediment samples showing different carbon contents and spiked at different concentrations in the range from 40 to 500 ng g(-1). Recoveries varied between 78% and 110% with associated standard deviations below 14%. The limits of quantification of the method stayed between 3 and 15 ng g(-1). Levels of target compounds in sediment samples ranged from not detected up to a maximum of 56 ng g(-1) for Tinuvin 328.

Scanning electron microscope/energy dispersive x ray analysis of impact residues in LDEF tray clamps

Science.gov (United States)

Bernhard, Ronald P.; Durin, Christian; Zolensky, Michael E.

1993-01-01

Detailed optical scanning of tray clamps is being conducted in the Facility for the Optical Inspection of Large Surfaces at JSC to locate and document impacts as small as 40 microns in diameter. Residues from selected impacts are then being characterized by Scanning Electron Microscopy/Energy Dispersive X-ray Analysis at CNES. Results from this analysis will be the initial step to classifying projectile residues into specific sources.

Development of a natural Gas Systems Analysis Model (GSAM)

International Nuclear Information System (INIS)

Godec, M.; Haas, M.; Pepper, W.; Rose, J.

1993-01-01

Recent dramatic changes in natural gas markets have significant implications for the scope and direction of DOE's upstream as well as downstream natural gas R ampersand D. Open access transportation changes the way gas is bought and sold. The end of the gas deliverability surplus requires increased reserve development above recent levels. Increased gas demand for power generation and other new uses changes the overall demand picture in terms of volumes, locations and seasonality. DOE's Natural Gas Strategic Plan requires that its R ampersand D activities be evaluated for their ability to provide adequate supplies of reasonably priced gas. Potential R ampersand D projects are to be evaluated using a full fuel cycle, benefit-cost approach to estimate likely market impact as well as technical success. To assure R ampersand D projects are evaluated on a comparable basis, METC has undertaken the development of a comprehensive natural gas technology evaluation framework. Existing energy systems models lack the level of detail required to estimate the impact of specific upstream natural gas technologies across the known range of geological settings and likely market conditions. Gas Systems Analysis Model (GSAM) research during FY 1993 developed and implemented this comprehensive, consistent natural gas system evaluation framework. Rather than a isolated research activity, however, GSAM represents the integration of many prior and ongoing natural gas research efforts. When complete, it will incorporate the most current resource base description, reservoir modeling, technology characterization and other geologic and engineering aspects developed through recent METC and industry gas R ampersand D programs

Dispersive analysis of the pion transition form factor

Science.gov (United States)

Hoferichter, M.; Kubis, B.; Leupold, S.; Niecknig, F.; Schneider, S. P.

2014-11-01

We analyze the pion transition form factor using dispersion theory. We calculate the singly-virtual form factor in the time-like region based on data for the cross section, generalizing previous studies on decays and scattering, and verify our result by comparing to data. We perform the analytic continuation to the space-like region, predicting the poorly-constrained space-like transition form factor below , and extract the slope of the form factor at vanishing momentum transfer . We derive the dispersive formalism necessary for the extension of these results to the doubly-virtual case, as required for the pion-pole contribution to hadronic light-by-light scattering in the anomalous magnetic moment of the muon.

Direct analysis of ultra-trace semiconductor gas by inductively coupled plasma mass spectrometry coupled with gas to particle conversion-gas exchange technique.

Science.gov (United States)

Ohata, Masaki; Sakurai, Hiromu; Nishiguchi, Kohei; Utani, Keisuke; Günther, Detlef

2015-09-03

An inductively coupled plasma mass spectrometry (ICPMS) coupled with gas to particle conversion-gas exchange technique was applied to the direct analysis of ultra-trace semiconductor gas in ambient air. The ultra-trace semiconductor gases such as arsine (AsH3) and phosphine (PH3) were converted to particles by reaction with ozone (O3) and ammonia (NH3) gases within a gas to particle conversion device (GPD). The converted particles were directly introduced and measured by ICPMS through a gas exchange device (GED), which could penetrate the particles as well as exchange to Ar from either non-reacted gases such as an air or remaining gases of O3 and NH3. The particle size distribution of converted particles was measured by scanning mobility particle sizer (SMPS) and the results supported the elucidation of particle agglomeration between the particle converted from semiconductor gas and the particle of ammonium nitrate (NH4NO3) which was produced as major particle in GPD. Stable time-resolved signals from AsH3 and PH3 in air were obtained by GPD-GED-ICPMS with continuous gas introduction; however, the slightly larger fluctuation, which could be due to the ionization fluctuation of particles in ICP, was observed compared to that of metal carbonyl gas in Ar introduced directly into ICPMS. The linear regression lines were obtained and the limits of detection (LODs) of 1.5 pL L(-1) and 2.4 nL L(-1) for AsH3 and PH3, respectively, were estimated. Since these LODs revealed sufficiently lower values than the measurement concentrations required from semiconductor industry such as 0.5 nL L(-1) and 30 nL L(-1) for AsH3 and PH3, respectively, the GPD-GED-ICPMS could be useful for direct and high sensitive analysis of ultra-trace semiconductor gas in air. Copyright © 2015 Elsevier B.V. All rights reserved.

Wavelength Dispersive X-ray Fluorescence Spectrometry for the Analysis of Organic Polymer Film

International Nuclear Information System (INIS)

Choi, Yong Suk; Park, Yong Joon; Kim, Jong Yun

2008-01-01

Recently, many studies have been focused on the thin films because there are numerous industrial processes relevant to thin films such as fuel cells, sensors, lubricants, coatings, and so on. Physical and chemical properties of solid surface have been modified by ultra-thin coatings such as Langmuir-Blodgett (LB) method with a variety of types of organic functional materials for the specific purposes in many applications. In addition, the layer-by-layer technique using polyelectrolyte films are now of interest as biosensors, electrochromic and electroluminescent devices, etc. In general, several methods such as X-ray or neutron reflectivity, and quartz crystal microbalance (QCM) have been utilized for the thin film analysis. These optical techniques can measure the film thicknesses up to hundreds of nanometers while X-ray photoelectron spectroscopy is widely used to study a few nanometers thick films. Other methods such as X-ray Photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and atom force microscopy (AFM) have also been used in the film analysis in spite of some disadvantages for each method. X-ray fluorescence (XRF) has long been used as a rapid and simple analytical tool for the analysis of elemental composition of materials. XRF technique is suitable for on-line or in-line real-time monitoring because it is a non-destructive and rapid analysis with good precision and good accuracy at low cost. The aim of this work is to develop a new analytical technique for the quantitative analysis of polymer film on metal substrate. In the present study, Compton peak profile was investigated under different experimental conditions by using wavelength-dispersive XRF (WD-XRF). Compared to energy-dispersive XRF (ED-XRF), WD-XRF is more adequate in an accurate quantitative analysis of thin organic film

Spatial stochasticity and non-continuum effects in gas flows

Energy Technology Data Exchange (ETDEWEB)

Dadzie, S. Kokou, E-mail: k.dadzie@glyndwr.ac.uk [Mechanical and Aeronautical Engineering, Glyndwr University, Mold Road, Wrexham LL11 2AW (United Kingdom); Reese, Jason M., E-mail: jason.reese@strath.ac.uk [Department of Mechanical and Aerospace Engineering, University of Strathclyde, Glasgow G1 1XJ (United Kingdom)

2012-02-06

We investigate the relationship between spatial stochasticity and non-continuum effects in gas flows. A kinetic model for a dilute gas is developed using strictly a stochastic molecular model reasoning, without primarily referring to either the Liouville or the Boltzmann equations for dilute gases. The kinetic equation, a stochastic version of the well-known deterministic Boltzmann equation for dilute gas, is then associated with a set of macroscopic equations for the case of a monatomic gas. Tests based on a heat conduction configuration and sound wave dispersion show that spatial stochasticity can explain some non-continuum effects seen in gases. -- Highlights: ► We investigate effects of molecular spatial stochasticity in non-continuum regime. ► Present a simplify spatial stochastic kinetic equation. ► Present a spatial stochastic macroscopic flow equations. ► Show effects of the new model on sound wave dispersion prediction. ► Show effects of the new approach in density profiles in a heat conduction.

Impact of comprehensive two-dimensional gas chromatography with mass spectrometry on food analysis.

Science.gov (United States)

Tranchida, Peter Q; Purcaro, Giorgia; Maimone, Mariarosa; Mondello, Luigi

2016-01-01

Comprehensive two-dimensional gas chromatography with mass spectrometry has been on the separation-science scene for about 15 years. This three-dimensional method has made a great positive impact on various fields of research, and among these that related to food analysis is certainly at the forefront. The present critical review is based on the use of comprehensive two-dimensional gas chromatography with mass spectrometry in the untargeted (general qualitative profiling and fingerprinting) and targeted analysis of food volatiles; attention is focused not only on its potential in such applications, but also on how recent advances in comprehensive two-dimensional gas chromatography with mass spectrometry will potentially be important for food analysis. Additionally, emphasis is devoted to the many instances in which straightforward gas chromatography with mass spectrometry is a sufficiently-powerful analytical tool. Finally, possible future scenarios in the comprehensive two-dimensional gas chromatography with mass spectrometry food analysis field are discussed. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Indoor air quality inspection and analysis system based on gas sensor array

Science.gov (United States)

Gao, Xiang; Wang, Mingjiang; Fan, Binwen

2017-08-01

A detection and analysis system capable of measuring the concentration of four major gases in indoor air is designed. It uses four gas sensors constitute a gas sensor array, to achieve four indoor gas concentration detection, while the detection of data for further processing to reduce the cross-sensitivity between the gas sensor to improve the accuracy of detection.

Calorimetric energy-dispersive detectors for ion beam analysis

International Nuclear Information System (INIS)

Andersen, H.H.

1985-01-01

Energy-dispersive detectors for photons and alpha particles have recently been built. They are based on designs for infrared bolometric detectors working at liquid helium temperatures. For 5.5 Mev alpha particles the energy resolution (FWHM) has been published to be better than 35 keV in preliminary experiments, but thermodynamic limits to the resolution were calculated to be of the order of a few tens of eV. In the present paper limitations to the resolution caused by fluctuations in the processes converting particle energy to heat in the detectors will be calculated. It appears that an FWHM of a few hundred eV for MeV alphas may realistically be hoped for. As these detectors are windowless and may at the same time extend solid angles as large as surface-barrier detectors, be built in any desired geometrical shape, and work with count rates well above 10 3 Hz, exiting possibilities for ion beam analysis will open up through their realization. (orig.)

Analysis of Mechanical Seals for High-Speed Centrifugal Gas Compressors

OpenAIRE

K.N. Nwaigwe; P.E. Ugwuoke; E.E. Anyanwu; D.P.S. Abam

2012-01-01

A study aimed at seal selection efficiency for centrifugal pumps in the oil and gas industry is presented. A detailed analysis of mechanical seals in use in exploration and production activities of the oil and gas sector was undertaken. The approach of analysis was using seal design equations as mathematical models for simulating the performance of the mechanical seal. The results showed a mechanical seal with balance value of 0.5, an increased surface area between mating surfaces; provided w...

Large-eddy simulation of plume dispersion within regular arrays of cubic buildings

Science.gov (United States)

Nakayama, H.; Jurcakova, K.; Nagai, H.

2011-04-01

There is a potential problem that hazardous and flammable materials are accidentally or intentionally released within populated urban areas. For the assessment of human health hazard from toxic substances, the existence of high concentration peaks in a plume should be considered. For the safety analysis of flammable gas, certain critical threshold levels should be evaluated. Therefore, in such a situation, not only average levels but also instantaneous magnitudes of concentration should be accurately predicted. In this study, we perform Large-Eddy Simulation (LES) of plume dispersion within regular arrays of cubic buildings with large obstacle densities and investigate the influence of the building arrangement on the characteristics of mean and fluctuating concentrations.

Energy dispersive X-ray spectroscopy with microcalorimeters

International Nuclear Information System (INIS)

Hollerith, C.; Wernicke, D.; Buehler, M.; Feilitzsch, F. von; Huber, M.; Hoehne, J.; Hertrich, T.; Jochum, J.; Phelan, K.; Stark, M.; Simmnacher, B.; Weiland, W.; Westphal, W.

2004-01-01

Shrinking feature sizes in semiconductor device production as well as the use of new materials demand innovation in device technology and material analysis. X-ray spectrometers based on superconducting sensor technology are currently closing the gap between fast energy dispersive spectroscopy (EDS) and high-resolution wavelength dispersive spectroscopy (WDS). This work reports on the successful integration of iridium/gold transition edge sensors in the first industrially used microcalorimeter EDS. The POLARIS microcalorimeter system is installed at the failure analysis lab FA5 at Infineon Technologies AG in Neuperlach (Munich) and is used in routine analysis

Dispersions of silica nanoparticles in ionic liquids investigated with advanced rheology

International Nuclear Information System (INIS)

Wittmar, Alexandra; Ruiz-Abad, David; Ulbricht, Mathias

2012-01-01

The colloidal stabilities of dispersions of unmodified and surface-functionalized SiO 2 nanoparticles in hydrophobic and hydrophilic imidazolium-based ionic liquids were studied with advanced rheology at three temperatures (25, 100, and 200 °C). The rheological behavior of the dispersions was strongly affected by the ionic liquids hydrophilicity, by the nanoparticles surface, by the concentration of the nanoparticles in the dispersion as well as by the temperature. The unmodified hydrophilic nanoparticles showed a better compatibility with the hydrophilic ionic liquid. The SiO 2 surface functionalization with hydrophobic groups clearly improved the colloidal stability of the dispersions in the hydrophobic ionic liquid. The temperature increase was found to lead to a destabilization in all studied systems, especially at higher concentrations. The results of this study imply that ionic liquids with tailored properties could be used in absorbers directly after reactors for gas-phase synthesis of nanoparticles or/and as solvents for their further surface functionalization without agglomeration or aggregation.

Greenhouse gas emission measurement and economic analysis of Iran natural gas fired power plants

International Nuclear Information System (INIS)

Shahsavari Alavijeh, H.; Kiyoumarsioskouei, A.; Asheri, M.H.; Naemi, S.; Shahsavari Alavije, H.; Basirat Tabrizi, H.

2013-01-01

This study attempts to examine the natural gas fired power plants in Iran. The required data from natural gas fired power plants were gathered during 2008. The characteristics of thirty two gas turbine power plants and twenty steam power plants have been measured. Their emission factor values were then compared with the standards of Energy Protection Agency, Euro Union and World Bank. Emission factors of gas turbine and steam power plants show that gas turbine power plants have a better performance than steam power plants. For economic analysis, fuel consumption and environmental damages caused by the emitted pollutants are considered as cost functions; and electricity sales revenue are taken as benefit functions. All of these functions have been obtained according to the capacity factor. Total revenue functions show that gas turbine and steam power plants are economically efficient at 98.15% and 90.89% of capacity factor, respectively; this indicates that long operating years of power plants leads to reduction of optimum capacity factor. The stated method could be implemented to assess the economic status of a country’s power plants where as efficient capacity factor close to one means that power plant works in much better condition. - Highlights: • CO 2 and NO x emissions of Iran natural gas fired power plants have been studied. • CO 2 and NO x emission factors are compared with EPA, EU and World Bank standards. • Costs and benefit as economic functions are obtained according to capacity factor. • Maximum economic profit is obtained for gas turbine and steam power plants. • Investment in CO 2 reduction is recommended instead of investment in NO x reduction

A numerical analysis of pollutant dispersion in street canyon: influence of the turbulent Schmidt number

Directory of Open Access Journals (Sweden)

Bouabdellah Abed

2017-12-01

Full Text Available Realizing the growing importance and availability of motor vehicles, we observe that the main source of pollution in the street canyons comes from the dispersion of automobile engine exhaust gas. It represents a substantial effect on the micro-climate conditions in urban areas. Seven idealized-2D building configurations are investigated by numerical simulations. The turbulent Schmidt number is introduced in the pollutant transport equation in order the take into account the proportion between the rate of momentum turbulent transport and the mass turbulent transport by diffusion. In the present paper, we attempt to approach the experimental test results by adjusting the values of turbulent Schmidt number to its corresponding application. It was with interest that we established this link for achieving our objectives, since the numerical results agree well with the experimental ones. The CFD code ANSYS CFX, the k, e and the RNGk-e models of turbulence have been adopted for the resolutions. From the simulation results, the turbulent Schmidt number is a range of 0.1 to 1.3 that has some effect on the prediction of pollutant dispersion in the street canyons. In the case of a flat roof canyon configuration (case: runa000, appropriate turbulent Schmidt number of 0.6 is estimated using the k-epsilon model and of 0.5 using the RNG k-e model.

Dispersion of radioactive materials in air and water

International Nuclear Information System (INIS)

Tolksdorf, P.; Meurin, G.

1976-01-01

A review of current analytical methods for treating the dispersion of radioactive material in air and water is given. It is shown that suitable calculational models, based on experiments, exist for the dispersion in air. By contrast, the analysis of the dispersion of radioactive material in water still depends on the evaluation of experiments with site-specific models. (orig.) [de

Periodic radio variability in NRAO 530: phase dispersion minimization analysis

International Nuclear Information System (INIS)

Lu Junchao; Lin Jiming; Qiu Hongbing; Wang Junyi; An Tao

2012-01-01

A periodicity analysis of the radio light curves of the blazar NRAO 530 at 14.5, 8.0, and 4.8 GHz is presented employing an improved phase dispersion minimization technique. The result, which shows two persistent periodic components of ∼ 6 and ∼ 10 yr at all three frequencies, is consistent with the results obtained with the Lomb-Scargle periodogram and weighted wavelet Z-transform algorithms. The reliability of the derived periodicities is confirmed by the Monte Carlo numerical simulations which show a high statistical confidence. (Quasi-)Periodic fluctuations of the radio luminosity of NRAO 530 might be associated with the oscillations of the accretion disk triggered by hydrodynamic instabilities of the accreted flow. (research papers)

Surface functionalization of microwave plasma-synthesized silica nanoparticles for enhancing the stability of dispersions

Science.gov (United States)

Sehlleier, Yee Hwa; Abdali, Ali; Schnurre, Sophie Marie; Wiggers, Hartmut; Schulz, Christof

2014-08-01

Gas phase-synthesized silica nanoparticles were functionalized with three different silane coupling agents (SCAs) including amine, amine/phosphonate and octyltriethoxy functional groups and the stability of dispersions in polar and non-polar dispersing media such as water, ethanol, methanol, chloroform, benzene, and toluene was studied. Fourier transform infrared spectroscopy showed that all three SCAs are chemically attached to the surface of silica nanoparticles. Amine-functionalized particles using steric dispersion stabilization alone showed limited stability. Thus, an additional SCA with sufficiently long hydrocarbon chains and strong positively charged phosphonate groups was introduced in order to achieve electrosteric stabilization. Steric stabilization was successful with hydrophobic octyltriethoxy-functionalized silica nanoparticles in non-polar solvents. The results from dynamic light scattering measurements showed that in dispersions of amine/phosphonate- and octyltriethoxy-functionalized silica particles are dispersed on a primary particle level. Stable dispersions were successfully prepared from initially agglomerated nanoparticles synthesized in a microwave plasma reactor by designing the surface functionalization.

Method for the simultaneous determination of monoaromatic and polycyclic aromatic hydrocarbons in industrial effluents using dispersive liquid-liquid microextraction with gas chromatography-mass spectrometry.

Science.gov (United States)

Makoś, Patrycja; Fernandes, André; Boczkaj, Grzegorz

2018-02-23

We present a new method for simultaneous determination of 22 monoaromatic and polycyclic aromatic hydrocarbons in postoxidative effluents from the production of petroleum bitumen using dispersive liquid-liquid microextraction coupled to gas chromatography and mass spectrometry. The eight extraction parameters including the type and volume of extraction and disperser solvent, pH, salting out effect, extraction, and centrifugation time were optimized. The low detection limit ranging from 0.36 to 28 μg/L, limit of quantitation (1.1-84 μg/L), good reproducibility, and wide linear ranges, as well as the recoveries ranging from 71.74 to 114.67% revealed that the new method allows the determination of aromatic hydrocarbons at low concentration levels in industrial effluents having a very complex composition. The developed method was applied to the determination of content of mono- and polycyclic aromatic hydrocarbons in samples of raw postoxidative effluents in which 15 compounds were identified at concentrations ranging from 1.21 to 1017.0 μg/L as well as in effluents after chemical treatment. © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Streamlined sample cleanup using combined dispersive solid-phase extraction and in-vial filtration for analysis of pesticides and environmental pollutants in shrimp.

Science.gov (United States)

Han, Lijun; Sapozhnikova, Yelena; Lehotay, Steven J

2014-05-27

A new method of sample preparation was developed and is reported for the first time. The approach combines in-vial filtration with dispersive solid-phase extraction (d-SPE) in a fast and convenient cleanup of QuEChERS (quick, easy, cheap, effective, rugged, and safe) extracts. The method was applied to simultaneous analysis of 42 diverse pesticides and 17 environmental contaminants, including polycyclic aromatic hydrocarbons, polychlorinated biphenyls (PCBs), and flame retardants, in shrimp as the sample matrix. Final extracts were analyzed by both low-pressure gas chromatography - triple quadrupole tandem mass spectrometry (LPGC-MS/MS), and high-performance liquid chromatography - triple quadrupole tandem mass spectrometry (HPLC-MS/MS) to provide a wide scope of analysis for targeted analytes. During method development, several different commercial sorbents for d-SPE were investigated and compared with respect to analyte recoveries. The method was validated at 10, 50, and 100 ng g(-1) spiking levels (10-fold lower for PCBs), and the results for nearly all analytes were between 70 and 115% recoveries with ≤17% relative standard deviations. The method was shown to be simple, fast, and effective for multi-application analysis of chemical residues in the representative food and environmental marker matrix. Copyright © 2014. Published by Elsevier B.V.

Static Structural and Modal Analysis of Gas Turbine Blade

Science.gov (United States)

Ranjan Kumar, Ravi; Pandey, K. M., Prof.

2017-08-01

Gas turbine is one of the most versatile items of turbo machinery nowadays. It is used in different modes such as power generation, oil and gas, process plants, aviation, domestic and related small industries. This paper is based on the problems concerning blade profile selection, material selection and turbine rotor blade vibration that seriously impact the induced stress-deformation and structural functioning of developmental gas turbine engine. In this paper for generating specific power by rotating blade at specific RPM, blade profile and material has been decided by static structural analysis. Gas turbine rotating blade RPM is decided by Modal Analysis so that the natural frequency of blade should not match with the excitation frequency. For the above blade profile has been modeled in SOLIDWORKS and analysis has been done in ANSYS WORKBENCH 14. Existing NACA6409 profile has been selected as base model and then it is modified by bending it through 72.5° and 145°. Hence these three different blade profiles have been analyzed for three different materials viz. Super Alloy X, Nimonic 80A and Inconel 625 at three different speed viz. 20000, 40000 and 60000RPM. It is found that NACA6409 with 72.5° bent gives best result for all material at all speed. Among all the material Inconel 625 gives best result. Hence Blade of Inconel 625 having 72.5° bent profile is the best combination for all RPM.

Influence of fuel-matrix interaction on the breakaway swelling of U-Mo dispersion fuel in Al

Energy Technology Data Exchange (ETDEWEB)

Ryu, Ho Jin [Dept. of Nuclear and Quantum Engineering, Korea Advanced Institute of Science and Technology, Daejeon (Korea, Republic of); Kim, Yeon Soo [Nuclear Engineering Division, Argonne National Laboratory, Arogonne (United States)

2014-04-15

In order to advance understanding of the breakaway swelling behavior of U-Mo/Al dispersion fuel under a high-power irradiation condition, the effects of fuel-matrix interaction on the fuel performance of U-Mo/Al dispersion fuel were investigated. Fission gas release into large interfacial pores between interaction layers and the Al matrix was analyzed using both mechanistic models and observations of the post-irradiation examination results of U-Mo dispersion fuels. Using the model predictions, advantageous fuel design parameters are recommended to prevent breakaway swelling.

Holographic analysis of dispersive pupils in space--time optics

International Nuclear Information System (INIS)

Calatroni, J.; Vienot, J.C.

1981-01-01

Extension of space--time optics to objects whose transparency is a function of the temporal frequency v = c/lambda is examined. Considering the effects of such stationary pupils on white light waves, they are called temporal pupils. It is shown that simultaneous encoding both in the space and time frequency domains is required to record pupil parameters. The space-time impulse response and transfer functions are calculated for a dispersive nonabsorbent material. An experimental method providing holographic recording of the dispersion curve of any transparent material is presented

Holographic analysis of dispersive pupils in space--time optics

Energy Technology Data Exchange (ETDEWEB)

Calatroni, J.; Vienot, J.C.

1981-06-01

Extension of space--time optics to objects whose transparency is a function of the temporal frequency v = c/lambda is examined. Considering the effects of such stationary pupils on white light waves, they are called temporal pupils. It is shown that simultaneous encoding both in the space and time frequency domains is required to record pupil parameters. The space-time impulse response and transfer functions are calculated for a dispersive nonabsorbent material. An experimental method providing holographic recording of the dispersion curve of any transparent material is presented.

Strategic analysis on establishing a natural gas trading hub in China

Directory of Open Access Journals (Sweden)

Xiaoguang Tong

2014-12-01

Full Text Available Since 2010, the LNG importing price premium in the Asia–Pacific markets has become increasingly high, generating great effects on the economic development in China. In addition, the natural gas dependence degree is expanding continuously, making it extremely urgent to establish a natural gas trading hub in China, with the aim to ensure national energy security, to gain the pricing power, and to build the regional benchmark prices. Through a comparative analysis of internal strength/weakness and external competitiveness, we concluded that with intensively-issued supporting policies on the natural gas sector, the initiation of spot and futures markets, the rapid growth of gas production and highly-improved infrastructures, as well as Shanghai's advantageous location, China has more advantages in establishing an Asian Natural Gas Trading Hub than other counties like Singapore, Japan and Malaysia. Moreover, based on the SWOT (strength, weakness, opportunity and threat and the marketization process analysis, the following strategies were presented: to impel the establishment of a natural gas trading hub depending on the gas supply condition, to follow the policies to complete the gas storage system, to form regional communities by taking comparative advantages, and to reinforce the marketization reform and regulation system establishment with foreign experiences for reference. This study rationalized the necessity and practicality of establishing a natural gas trading hub in China and will help China make a proper decision and find a periodical strategic path in this sector.

A numerical model of heavy gas dispersion

International Nuclear Information System (INIS)

Bidokhtti, A.A.

1993-01-01

A simple mathematical model describing the motion of a dense gas released continuously into and environment is presented. The model correctly predicts the laboratory experiments which were carried out by Britter and Snyder (1987). It is an entrainment model better known as box model. In this model, the effects of temperature change and phase change are not considered and it is for a steady-state case. Further work is required for including these effects which are often associated with the mechanisms involved in accidental or natural release of heavy gases in the environment. The results of such a model will be extended to the practical situations which are and will be common to the nuclear industry at the Atomic Energy Organization of Iran. The applicability of such studies to these situations will be discussed

Turbulence modification due to bubbles and particles in dispersed two-phase upflows in a vertical pipe

International Nuclear Information System (INIS)

Hosokawa, Shigeo; Tomiyama, Akio

1999-01-01

One of the key issues in two-phase turbulence modeling is the turbulence modification due to the momentum exchange between the dispersed and continuous phases. As for the gas-liquid two-phase flows in vertical pipes, Serizawa and Kataoka carried out detailed measurement of turbulence intensity and detected the turbulence modification. Gore and Crowe pointed out that the modification is well correlated with the ratio of a particle diameter to a turbulence length scale (d/l t ). However the modification may depend on not only the length scales but also the eddy viscosities of shear-induced and particle-induced turbulence. Hosokawa et al. proposed the ratio φ of the eddy viscosity induced by a dispersed phase to the shear-induced eddy viscosity and confirmed that measured turbulence modification was well correlated with φ for a gas-solid two-phase flow. In this study, we examine whether or not φ is also applicable to gas-liquid and solid-liquid two-phase dispersed upflows in vertical pipes. Using the eddy viscosity ratio instead of d/l t , we could obtain much better correlation. The critical point at which no modification occurred was close to φ = 1, irrespective of a type of a two-phase dispersed flow. Consequently, we could confirm that the eddy viscosity ratio is a more appropriate parameter for correlating the turbulent modification than the conventional critical parameter d/l t . (author)

Mechanical analysis of UMo/Al dispersion fuel

International Nuclear Information System (INIS)

Jeong, Gwan Yoon; Kim, Yeon Soo; Sohn, Dong-Seong

2015-01-01

Deformation of fuel particles and mass transfer from the transverse end of fuel meat toward the meat center was observed. This caused plate thickness peaking at a location between the meat edge and the meat center. The underlying mechanism for this fuel volume transport is believed to be fission induced creep of the U–Mo/Al meat. Fuel meat swelling was measured using optical microscopy images of the cross sections of the irradiated test plates. The time-dependent meat swelling was modeled for use in numerical simulation. A distinctive discrepancy between the predicted and measured meat thickness was found at the meat ends, which was assumed to be due to creep-induced mass relocation from the meat end to the meat center region that was not considered in the meat swelling model. ABAQUS FEA simulation was performed to reproduce the observed phenomenon at the meat ends. Through the simulation, we obtained the effective creep rate constants for the interaction layers (IL) and aluminum matrix. In addition, we obtained the corresponding stress and strain analysis results that can be used to understand mechanical behavior of U–Mo/Al dispersion fuel.

Mechanical analysis of UMo/Al dispersion fuel

Energy Technology Data Exchange (ETDEWEB)

Jeong, Gwan Yoon [Ulsan National Institute of Science and Technology, Department of Nuclear Engineering, 50 UNIST-gil, Eonyang-eup, Ulju-gun, Ulsan, 689-798 (Korea, Republic of); Kim, Yeon Soo [Argonne National Laboratory, 9700 South Cass Avenue, Argonne, IL 60439 (United States); Sohn, Dong-Seong, E-mail: dssohn@unist.ac.kr [Ulsan National Institute of Science and Technology, Department of Nuclear Engineering, 50 UNIST-gil, Eonyang-eup, Ulju-gun, Ulsan, 689-798 (Korea, Republic of)

2015-11-15

Deformation of fuel particles and mass transfer from the transverse end of fuel meat toward the meat center was observed. This caused plate thickness peaking at a location between the meat edge and the meat center. The underlying mechanism for this fuel volume transport is believed to be fission induced creep of the U–Mo/Al meat. Fuel meat swelling was measured using optical microscopy images of the cross sections of the irradiated test plates. The time-dependent meat swelling was modeled for use in numerical simulation. A distinctive discrepancy between the predicted and measured meat thickness was found at the meat ends, which was assumed to be due to creep-induced mass relocation from the meat end to the meat center region that was not considered in the meat swelling model. ABAQUS FEA simulation was performed to reproduce the observed phenomenon at the meat ends. Through the simulation, we obtained the effective creep rate constants for the interaction layers (IL) and aluminum matrix. In addition, we obtained the corresponding stress and strain analysis results that can be used to understand mechanical behavior of U–Mo/Al dispersion fuel.

Preparation of amorphous solid dispersions by rotary evaporation and KinetiSol Dispersing: approaches to enhance solubility of a poorly water-soluble gum extract.

Science.gov (United States)

Bennett, Ryan C; Brough, Chris; Miller, Dave A; O'Donnell, Kevin P; Keen, Justin M; Hughey, Justin R; Williams, Robert O; McGinity, James W

2015-03-01

Acetyl-11-keto-β-boswellic acid (AKBA), a gum resin extract, possesses poor water-solubility that limits bioavailability and a high melting point making it difficult to successfully process into solid dispersions by fusion methods. The purpose of this study was to investigate solvent and thermal processing techniques for the preparation of amorphous solid dispersions (ASDs) exhibiting enhanced solubility, dissolution rates and bioavailability. Solid dispersions were successfully produced by rotary evaporation (RE) and KinetiSol® Dispersing (KSD). Solid state and chemical characterization revealed that ASD with good potency and purity were produced by both RE and KSD. Results of the RE studies demonstrated that AQOAT®-LF, AQOAT®-MF, Eudragit® L100-55 and Soluplus with the incorporation of dioctyl sulfosuccinate sodium provided substantial solubility enhancement. Non-sink dissolution analysis showed enhanced dissolution properties for KSD-processed solid dispersions in comparison to RE-processed solid dispersions. Variances in release performance were identified when different particle size fractions of KSD samples were analyzed. Selected RE samples varying in particle surface morphologies were placed under storage and exhibited crystalline growth following solid-state stability analysis at 12 months in comparison to stored KSD samples confirming amorphous instability for RE products. In vivo analysis of KSD-processed solid dispersions revealed significantly enhanced AKBA absorption in comparison to the neat, active substance.

Hydrodynamic dispersion within porous biofilms

KAUST Repository

Davit, Y.

2013-01-23

Many microorganisms live within surface-associated consortia, termed biofilms, that can form intricate porous structures interspersed with a network of fluid channels. In such systems, transport phenomena, including flow and advection, regulate various aspects of cell behavior by controlling nutrient supply, evacuation of waste products, and permeation of antimicrobial agents. This study presents multiscale analysis of solute transport in these porous biofilms. We start our analysis with a channel-scale description of mass transport and use the method of volume averaging to derive a set of homogenized equations at the biofilm-scale in the case where the width of the channels is significantly smaller than the thickness of the biofilm. We show that solute transport may be described via two coupled partial differential equations or telegrapher\\'s equations for the averaged concentrations. These models are particularly relevant for chemicals, such as some antimicrobial agents, that penetrate cell clusters very slowly. In most cases, especially for nutrients, solute penetration is faster, and transport can be described via an advection-dispersion equation. In this simpler case, the effective diffusion is characterized by a second-order tensor whose components depend on (1) the topology of the channels\\' network; (2) the solute\\'s diffusion coefficients in the fluid and the cell clusters; (3) hydrodynamic dispersion effects; and (4) an additional dispersion term intrinsic to the two-phase configuration. Although solute transport in biofilms is commonly thought to be diffusion dominated, this analysis shows that hydrodynamic dispersion effects may significantly contribute to transport. © 2013 American Physical Society.

GAS CHROMATOGRAPHIC AND SPECTROSCOPIC ANALYSIS OF ...

African Journals Online (AJOL)

Peroxyformic acid prepared in-situ was employed for epoxidation of canola oil in the presence of toluene. Gas chromatographic analysis of the product revealed the following species: C16:0; C18:0; C18:1; C18:2; C18:3; monoepoxy C18:0; monoepoxy C18:1; monoepoxy C18:2; diepoxy C18:0; diepoxy C18:1 and triepoxy ...

Effect of SnO2/SiO2 nano particle dispersant on the performance characteristic of complex multi-doped composite coating produced through electrodeposition on oil and gas storage tap

Directory of Open Access Journals (Sweden)

P.A.L. Anawe

2018-06-01

Full Text Available The effect of SnO2/SiO2 nano particle dispersant on the performance characteristic of complex zinc multi-doped composite coating produced through electrodeposition is studied. The degradation behaviour in term of wear and chemical corrosion activities were considered as a major factor in service. The wear mass loss was carried out with the help of reciprocating tester. The electrochemical corrosion characteristics were investigated using linear polarization technique in 3.5% simulated sodium chloride media. The outcome of the analysis shows that the developed coating was seen to provide a sound anti wear characteristics in its multidoped state. The corrosion resistance properties were observed to be massive compared to the binary based sample. It is expected that this characteristic will impact on the performance life span of storage tap in oil and gas. Keywords: Zn-SnO2-SiO2, Nanocomposite, Electrodeposition, Coatings and corrosion resistance

Description of dedusting in wet flue gas scrubbers with purposeful utilization of the secondary dispersion; Detailliertere Simulation der Staubabscheidung in Nasswaeschern durch Beruecksichtigung der Sekundaerdispersion

Energy Technology Data Exchange (ETDEWEB)

Feldkamp, M.; Lessmann, B.; Neumann, J.; Fahlenkamp, H. [Dortmund Univ. (Germany). Lehrstuhl Umwelttechnik

2003-07-01

Modern wet gas scrubbers are used in the power plant technology for the flue gas desulphurisation of coal-fired plants. For this the washing liquid is sprayed by numerous nozzles. The specific arrangement of the nozzles in several levels makes it possible for the spray to penetrate mutually. The penetration and overlapping of the spray in the wet scrubber causes the effect of secondary dispersion. This effect can be used effectively to improve the efficiency of the atomisation and to improve the absorption of the pollution gases in a flue gas desulphurisation scrubber. Analyses show that the cleaning efficiency of a wet scrubber depends on the distribution and the size of the drops. (orig.) [German] Moderne Gaswaescher werden in der Kraftwerkstechnik fuer die Rauchgasentschwefelung kohlebefeuerter Anlagen eingesetzt. Hierzu wird Waschfluessigkeit mit Hilfe zahlreicher Duesen zerstaeubt. Eine gezielte Anordnung der Duesen in mehreren Spruehebenen ermoeglicht es den Sprays der Duesen, sich gegenseitig zu durchdringen. Der Effekt der Sekundaerdisperson, der beim Ueberschneiden und Durchdringen der Sprays waehrend der Zerstaeubung im Rauchgaswaescher auftritt, laesst sich wirksam zur Verbesserung des Wirkungsgrades einer Rauchgasentschwefelungsanlage nutzen. Durchgefuehrte Untersuchungen zeigen, dass die Reinigungsleistung eines nassen REA-Waeschers von der Verteilung und der Groesse der Tropfen abhaengt. (orig.)

Dispersion Analysis of the ADI-FDTD and S-FDTD Methods

OpenAIRE

KUŞAF, Mehmet; ÖZTOPRAK, Abdullah Y.

2014-01-01

Numerical dispersion performances of ADI-FDTD and S-FDTD methods have been compared. It has been shown that for time steps below the stability limits of the S-FDTD method it has much better dispersion performance compared with the ADI-FDTD method and that the S-FDTD method can be usefully employed for space increments in the order of l/25 to l/50.

Mid-infrared frequency comb via coherent dispersive wave generation in silicon nitride nanophotonic waveguides

Science.gov (United States)

Guo, Hairun; Herkommer, Clemens; Billat, Adrien; Grassani, Davide; Zhang, Chuankun; Pfeiffer, Martin H. P.; Weng, Wenle; Brès, Camille-Sophie; Kippenberg, Tobias J.

2018-06-01

Mid-infrared optical frequency combs are of significant interest for molecular spectroscopy due to the large absorption of molecular vibrational modes on the one hand, and the ability to implement superior comb-based spectroscopic modalities with increased speed, sensitivity and precision on the other hand. Here, we demonstrate a simple, yet effective, method for the direct generation of mid-infrared optical frequency combs in the region from 2.5 to 4.0 μm (that is, 2,500-4,000 cm-1), covering a large fraction of the functional group region, from a conventional and compact erbium-fibre-based femtosecond laser in the telecommunication band (that is, 1.55 μm). The wavelength conversion is based on dispersive wave generation within the supercontinuum process in an unprecedented large-cross-section silicon nitride (Si3N4) waveguide with the dispersion lithographically engineered. The long-wavelength dispersive wave can perform as a mid-infrared frequency comb, whose coherence is demonstrated via optical heterodyne measurements. Such an approach can be considered as an alternative option to mid-infrared frequency comb generation. Moreover, it has the potential to realize compact dual-comb spectrometers. The generated combs also have a fine teeth-spacing, making them suitable for gas-phase analysis.

Phase space analysis of some interacting Chaplygin gas models

Energy Technology Data Exchange (ETDEWEB)

Khurshudyan, M. [Academy of Sciences of Armenia, Institute for Physical Research, Ashtarak (Armenia); Tomsk State University of Control Systems and Radioelectronics, Laboratory for Theoretical Cosmology, Tomsk (Russian Federation); Tomsk State Pedagogical University, Department of Theoretical Physics, Tomsk (Russian Federation); Myrzakulov, R. [Eurasian National University, Eurasian International Center for Theoretical Physics, Astana (Kazakhstan)

2017-02-15

In this paper we discuss a phase space analysis of various interacting Chaplygin gas models in general relativity. Linear and nonlinear sign changeable interactions are considered. For each case appropriate late time attractors of field equations are found. The Chaplygin gas is one of the dark fluids actively considered in modern cosmology due to the fact that it is a joint model of dark energy and dark matter. (orig.)

Physical modelling of the dispersion of heavy gases released in an accident for the assessment of hazardous areas in built-up terrain

International Nuclear Information System (INIS)

Marotzke, K.

1993-01-01

The report on experimental results which were obtained above all within the heavy gas dispersion phase of the clouds. This phase extends up to a distance from the source distance in which the initial heavy gas concentration has decreased to about 1% by volume of the source concentration. The lower ignition limit of all gases of interest for industrial applications is above this threshold; the ignition distances of combustible gases can therefore be determined directly in the physical model. The concentration field in the complex near field of the cloud is modelled physically. The results obtained in the wind tunnel serve as input data for a numeric model; the concentrations and the dose values at points in the far field can be calculated with the model. The main section contains a detailed dimensional analysis for the two fundamentally possible emission types, i.e. spontaneous and continuous emissions. An experimental program was developed on this basis. With the program, the heavy gas dispersion under the influence of 25 different obstacle configurations was investigated. The results were represented in diagrams. With the aid of the diagrams, the lower ignition distances can be determined for combustible gases; for toxic gases, the initial conditions for the numeric far field model. (orig./KW) [de

Catchment Dispersion Mechanisms in an Urban Context

Science.gov (United States)

Gironas, J. A.; Mejia, A.; Rossel, F.; Rinaldo, A.; Rodriguez, F.

2014-12-01

Dispersion mechanisms have been examined in-depth in natural catchments in previous studies. However, these dispersion mechanisms have been studied little in urban catchments, where artificial transport elements and morphological arrangements are expected to modify travel times and mobilize excess rainfall from spatially distributed impervious sites. Thus, these features can modify the variance of the catchment's travel times and hence the total dispersion. This work quantifies the dispersion mechanisms in an urban catchment using the theory of transport by travel times as represented by the Urban Morpho-climatic Instantaneous Unit Hydrograph (U-McIUH) model. This model computes travel times based on kinematic wave theory and accounts explicitly for the path heterogeneities and altered connectivity patterns characteristic of an urban drainage network. The analysis is illustrated using the Aubinière urban catchment (France) as a case study. We found that kinematic dispersion is dominant for small rainfall intensities, whereas geomorphologic dispersion becomes more dominant for larger intensities. The total dispersion scales with the drainage area in a power law fashion. The kinematic dispersion is dominant across spatial scales up to a threshold of approximately 2-3 km2, after which the geomorphologic dispersion becomes more dominant. Overall, overland flow is responsible for most of the dispersion, while conduits tend to counteract the increase of the geomorphologic dispersion with a negative kinematic dispersion. Further studies with other catchments are needed to assess whether the latter is a general feature of urban drainage networks.

Experimental station for gas phase fluorescence spectroscopy

International Nuclear Information System (INIS)

Stankiewicz, M.; Garcia, E. Melero; Ruiz, J. Alvarez; Erman, P.; Hatherly, P.A.; Kivimaeki, A.; Rachlew, E.; Rius i Riu, J.

2004-01-01

The details of an experimental setup for gas phase atomic and molecular fluorescence measurements using synchrotron radiation are described in this article. The most significant part of the apparatus is an optical arrangement, which allows for simultaneous measurements of dispersed as well as total fluorescence intensity using an effusive gas jet and an inbuilt gas cell assembled in a convenient plug and measure configuration. The first measurements concerning fluorescence of the N 2 molecule around the N 1s edge obtained with this setup are presented

Compression of turbulent magnetized gas in giant molecular clouds

Science.gov (United States)

Birnboim, Yuval; Federrath, Christoph; Krumholz, Mark

2018-01-01

Interstellar gas clouds are often both highly magnetized and supersonically turbulent, with velocity dispersions set by a competition between driving and dissipation. This balance has been studied extensively in the context of gases with constant mean density. However, many astrophysical systems are contracting under the influence of external pressure or gravity, and the balance between driving and dissipation in a contracting, magnetized medium has yet to be studied. In this paper, we present three-dimensional magnetohydrodynamic simulations of compression in a turbulent, magnetized medium that resembles the physical conditions inside molecular clouds. We find that in some circumstances the combination of compression and magnetic fields leads to a rate of turbulent dissipation far less than that observed in non-magnetized gas, or in non-compressing magnetized gas. As a result, a compressing, magnetized gas reaches an equilibrium velocity dispersion much greater than would be expected for either the hydrodynamic or the non-compressing case. We use the simulation results to construct an analytic model that gives an effective equation of state for a coarse-grained parcel of the gas, in the form of an ideal equation of state with a polytropic index that depends on the dissipation and energy transfer rates between the magnetic and turbulent components. We argue that the reduced dissipation rate and larger equilibrium velocity dispersion has important implications for the driving and maintenance of turbulence in molecular clouds and for the rates of chemical and radiative processes that are sensitive to shocks and dissipation.

System analysis and planning of a gas distribution network

Energy Technology Data Exchange (ETDEWEB)

Salas, Edwin F.M.; Farias, Helio Monteiro [AUTOMIND, Rio de Janeiro, RJ (Brazil); Costa, Carla V.R. [Universidade Salvador (UNIFACS), BA (Brazil)

2009-07-01

The increase in demand by gas consumers require that projects or improvements in gas distribution networks be made carefully and safely to ensure a continuous, efficient and economical supply. Gas distribution companies must ensure that the networks and equipment involved are defined and designed at the appropriate time to attend to the demands of the market. To do that a gas distribution network analysis and planning tool should use distribution networks and transmission models for the current situation and the future changes to be implemented. These models are used to evaluate project options and help in making appropriate decisions in order to minimize the capital investment in new components or simple changes in operational procedures. Gas demands are increasing and it is important that gas distribute design new distribution systems to ensure this growth, considering financial constraints of the company, as well as local legislation and regulation. In this study some steps of developing a flexible system that attends to those needs will be described. The analysis of distribution requires geographically referenced data for the models as well as an accurate connectivity and the attributes of the equipment. GIS systems are often used as a deposit center that holds the majority of this information. GIS systems are constantly updated as distribution network equipment is modified. The distribution network modeling gathered from this system ensures that the model represents the current network condition. The benefits of this architecture drastically reduce the creation and maintenance cost of the network models, because network components data are conveniently made available to populate the distribution network. This architecture ensures that the models are continually reflecting the reality of the distribution network. (author)

CRUNCH, Dispersion Model for Continuous Dense Vapour Release in Atmosphere

International Nuclear Information System (INIS)

Jagger, S.F.

1987-01-01

1 - Description of program or function: The situation modelled is as follows. A dense gas emerges from a source such that it can be considered to emerge through a rectangular area, placed in the vertical plane and perpendicular to the plume direction, which assumes that of the ambient wind. The gas flux at the source, and in every plane perpendicular to the plume direction, is constant in time and a stationary flow field has been attained. For this to apply, the characteristic time of release must be much larger than that for dispersal of the contaminant. The plume can be thought to consist of a number of rectangular elements or 'puffs' emerging from the source at regular time intervals. The model follows the development of these puffs at a series of downwind points. These puffs are immediately assumed to advect with the ambient wind at their half-height. The plume also slumps due to the action of gravity and is allowed to entrain air through its sides and top surface. Spreading of a fluid element is caused by pressure differences across this element and since the pressure gradient in the wind direction is small, the resulting pressure differences and slumping velocities are small also, thus permitting this convenient approximation. Initially, as the plume slumps, its vertical dimension decreases and with it the slumping velocity and advection velocity. Thus the plume advection velocity varies as a function of downwind distance. With the present steady state modelling, and to satisfy continuity constraints, there must be consequent adjustment of plume height. Calculation of this parameter from the volume flux ensures this occurs. As the cloud height begins to grow, the advection velocity increases and the plume height decreases accordingly. With advection downwind, the cloud gains buoyancy by entraining air and, if the cloud is cold, by absorbing heat from the ground. Eventually the plume begins to disperse as would a passive pollutant, through the action of

PIXE analysis of exhaust gas from diesel engine

International Nuclear Information System (INIS)

Miyake, Hirosi; Michijima, Masami; Onishi, Masayuki; Fujitani, Tatsuya.

1986-01-01

The variation of elemental concentrations in exhaust gas of a Diesel engine with the outputs was studied. Particulates in high temperature gas were collected on silica fiber filters and analyzed by PIXE method. Concentrations of S and V were nearly proportional to particulate masses and fuel consumption rates per discharging rates of exhaust gas respectively. While, concentrations of Fe and Mn were markedly increased together with engine outputs, and Mn/Fe ratios were nearly equal to those of the material of piston rings and the cylinder liner. Concentrations of the elements contained in lubricant, such as Ca and Mo, were also conspicuously increased with the outputs. It was shown that PIXE analysis is a useful tool for engine diagonostics owing to its high sensitive multi-elemental availability without chemical treatments. (author)

The Dispersion of Employees' Wage Increase and Firm Performance

DEFF Research Database (Denmark)

Grund, Christian; Westergård-Nielsen, Niels Chr.

2008-01-01

than the dispersion of wage levels. It is reasonable to expect greater dispersion of wage increases to be associated with higher monetary incentives, but also with increased perceptions of unfairness. The authors' analysis of linked employer-employee data from Denmark for the years 1992-97 shows......Previous studies examining intra-firm wage dispersion and firm performance have focused on wage levels. The authors of this study argue that for purposes of comparing wage dispersion's positive incentive effects with its adverse morale effects, the dispersion of wage increases is more revealing...

Parametric economic analysis of natural gas reburn technologies. Topical report, June 1991-June 1992

International Nuclear Information System (INIS)

Bluestein, J.

1992-06-01

The report presents a parametric economic analysis of natural gas reburn technologies used for control of nitrogen oxides emissions in coal-fired utility boilers. It is a competitive assessment of the economics of gas reburn performed in the context of regulatory requirements and competing conventional technologies. The reburn technologies examined are basic gas reburn, reburn with sorbent injection and advanced gas reburn. The analysis determined the levelized costs of these technologies in $/ton of NOx removed with respect to a gas-coal price differential in $/MMBtu of energy input. For those niches in which reburn was less economical, a breakeven capital cost analysis was carried out to determine the R ampersand D goals which would make reburn more cost competitive

Randomly dispersed particle fuel model in the PSG Monte Carlo neutron transport code

International Nuclear Information System (INIS)

Leppaenen, J.

2007-01-01

High-temperature gas-cooled reactor fuels are composed of thousands of microscopic fuel particles, randomly dispersed in a graphite matrix. The modelling of such geometry is complicated, especially using continuous-energy Monte Carlo codes, which are unable to apply any deterministic corrections in the calculation. This paper presents the geometry routine developed for modelling randomly dispersed particle fuels using the PSG Monte Carlo reactor physics code. The model is based on the delta-tracking method, and it takes into account the spatial self-shielding effects and the random dispersion of the fuel particles. The calculation routine is validated by comparing the results to reference MCNP4C calculations using uranium and plutonium based fuels. (authors)

Method to produce combustible gas with low tar content out of biomass. Foerfarande foer att ur biomassa framstaella en tjaerfattig braennbar gas

Energy Technology Data Exchange (ETDEWEB)

Lindman, N

1988-01-11

The gas is led in a controlled flow to a vertical reactor shaft with a circulating fluidized bed containing dispersed calcined limestone. The biomass is pyrolyzed by means of the reactor heat in order to produce tarry gas and charcoal. While the gas flows upward in the reactor shaft the tar is gasified in a heterogeneous catalytic reaction with limestone. Charcoal and limestone are separated from the gas at the top of the reactor shaft and brought back to the fluidized bed for combustion. (L.F.).

Modelling of non-catalytic reactors in a gas-solid trickle flow reactor: Dry, regenerative flue gas desulphurization using a silica-supported copper oxide sorbent

NARCIS (Netherlands)

Kiel, J.H.A.; Kiel, J.H.A.; Prins, W.; van Swaaij, Willibrordus Petrus Maria

1992-01-01

A one-dimensional, two-phase dispersed plug flow model has been developed to describe the steady-state performance of a relatively new type of reactor, the gas-solid trickle flow reactor (GSTFR). In this reactor, an upward-flowing gas phase is contacted with as downward-flowing dilute solids phase

Evaluation of atmospheric dispersion/consequence models supporting safety analysis

International Nuclear Information System (INIS)

O'Kula, K.R.; Lazaro, M.A.; Woodard, K.

1996-01-01

Two DOE Working Groups have completed evaluation of accident phenomenology and consequence methodologies used to support DOE facility safety documentation. The independent evaluations each concluded that no one computer model adequately addresses all accident and atmospheric release conditions. MACCS2, MATHEW/ADPIC, TRAC RA/HA, and COSYMA are adequate for most radiological dispersion and consequence needs. ALOHA, DEGADIS, HGSYSTEM, TSCREEN, and SLAB are recommended for chemical dispersion and consequence applications. Additional work is suggested, principally in evaluation of new models, targeting certain models for continued development, training, and establishing a Web page for guidance to safety analysts

A constraint on the velocity dispersion of the missing mass in the solar neighborhood

International Nuclear Information System (INIS)

Nakamura, Takashi

1978-01-01

The stability of an N-component stellar disk with finite thickness is examined with the gas dynamical approximation. The dispersion relation for marginal stability is obtained. This dispersion relation for N = 2 is applied to the missing mass problem in the solar neighborhood, where two components represent the observed mass component and the missing mass component in the solar neighborhood. From the requirement that the Galactic disk should be locally stable, it is found that the velocity dispersion of the missing mass component should be greater than about 25km/sec. The stability of an infinitesimally thin disk is also investigated and compared with the disk of finite thickness. (auth.)

A miniaturized optical gas sensor for natural gas analysis

NARCIS (Netherlands)

Ayerden, N.P.

2016-01-01

The depletion of domestic reserves and the growing use of sustainable resources forces a transition from the locally produced natural gas with a well-known composition toward the ‘new’ gas with a more flexible composition in the Netherlands. For safe combustion and proper billing, the natural gas

Multiple inert gas elimination technique by micropore membrane inlet mass spectrometry--a comparison with reference gas chromatography.

Science.gov (United States)

Kretzschmar, Moritz; Schilling, Thomas; Vogt, Andreas; Rothen, Hans Ulrich; Borges, João Batista; Hachenberg, Thomas; Larsson, Anders; Baumgardner, James E; Hedenstierna, Göran

2013-10-15

The mismatching of alveolar ventilation and perfusion (VA/Q) is the major determinant of impaired gas exchange. The gold standard for measuring VA/Q distributions is based on measurements of the elimination and retention of infused inert gases. Conventional multiple inert gas elimination technique (MIGET) uses gas chromatography (GC) to measure the inert gas partial pressures, which requires tonometry of blood samples with a gas that can then be injected into the chromatograph. The method is laborious and requires meticulous care. A new technique based on micropore membrane inlet mass spectrometry (MMIMS) facilitates the handling of blood and gas samples and provides nearly real-time analysis. In this study we compared MIGET by GC and MMIMS in 10 piglets: 1) 3 with healthy lungs; 2) 4 with oleic acid injury; and 3) 3 with isolated left lower lobe ventilation. The different protocols ensured a large range of normal and abnormal VA/Q distributions. Eight inert gases (SF6, krypton, ethane, cyclopropane, desflurane, enflurane, diethyl ether, and acetone) were infused; six of these gases were measured with MMIMS, and six were measured with GC. We found close agreement of retention and excretion of the gases and the constructed VA/Q distributions between GC and MMIMS, and predicted PaO2 from both methods compared well with measured PaO2. VA/Q by GC produced more widely dispersed modes than MMIMS, explained in part by differences in the algorithms used to calculate VA/Q distributions. In conclusion, MMIMS enables faster measurement of VA/Q, is less demanding than GC, and produces comparable results.

Application of large-scale parentage analysis for investigating natal dispersal in highly vagile vertebrates: a case study of American black bears (Ursus americanus).

Science.gov (United States)

Moore, Jennifer A; Draheim, Hope M; Etter, Dwayne; Winterstein, Scott; Scribner, Kim T

2014-01-01

Understanding the factors that affect dispersal is a fundamental question in ecology and conservation biology, particularly as populations are faced with increasing anthropogenic impacts. Here we collected georeferenced genetic samples (n = 2,540) from three generations of black bears (Ursus americanus) harvested in a large (47,739 km2), geographically isolated population and used parentage analysis to identify mother-offspring dyads (n = 337). We quantified the effects of sex, age, habitat type and suitability, and local harvest density at the natal and settlement sites on the probability of natal dispersal, and on dispersal distances. Dispersal was male-biased (76% of males dispersed) but a small proportion (21%) of females also dispersed, and female dispersal distances (mean ± SE  =  48.9±7.7 km) were comparable to male dispersal distances (59.0±3.2 km). Dispersal probabilities and dispersal distances were greatest for bears in areas with high habitat suitability and low harvest density. The inverse relationship between dispersal and harvest density in black bears suggests that 1) intensive harvest promotes restricted dispersal, or 2) high black bear population density decreases the propensity to disperse. Multigenerational genetic data collected over large landscape scales can be a powerful means of characterizing dispersal patterns and causal associations with demographic and landscape features in wild populations of elusive and wide-ranging species.

Application of large-scale parentage analysis for investigating natal dispersal in highly vagile vertebrates: a case study of American black bears (Ursus americanus.

Directory of Open Access Journals (Sweden)

Jennifer A Moore

Full Text Available Understanding the factors that affect dispersal is a fundamental question in ecology and conservation biology, particularly as populations are faced with increasing anthropogenic impacts. Here we collected georeferenced genetic samples (n = 2,540 from three generations of black bears (Ursus americanus harvested in a large (47,739 km2, geographically isolated population and used parentage analysis to identify mother-offspring dyads (n = 337. We quantified the effects of sex, age, habitat type and suitability, and local harvest density at the natal and settlement sites on the probability of natal dispersal, and on dispersal distances. Dispersal was male-biased (76% of males dispersed but a small proportion (21% of females also dispersed, and female dispersal distances (mean ± SE  =  48.9±7.7 km were comparable to male dispersal distances (59.0±3.2 km. Dispersal probabilities and dispersal distances were greatest for bears in areas with high habitat suitability and low harvest density. The inverse relationship between dispersal and harvest density in black bears suggests that 1 intensive harvest promotes restricted dispersal, or 2 high black bear population density decreases the propensity to disperse. Multigenerational genetic data collected over large landscape scales can be a powerful means of characterizing dispersal patterns and causal associations with demographic and landscape features in wild populations of elusive and wide-ranging species.

Investigation of the propagation characteristics in turbulent dispersed two-phase flow

International Nuclear Information System (INIS)

Sami, S.M.

1980-01-01

The propagation characteristics of turbulent dispersed two-phase flows have been studied experimentally using the Pitot tube associated with a conical hot-film anemometer. It is found that the mixture velocity increases with decreasing volumetric mixing ratio of the air and water. The void fraction distribution shows homogeneity across the test section in the special case of fully developed boundary layer two-phase flow. An expression is obtained which relates the local mixture velocity to the local void fraction, gas and liquid densities, and volumetric gas-liquid ratio

Interaction between molecular complexes in dispersive media

International Nuclear Information System (INIS)

Banagas, E.A.; Manykin, E.A.

1987-01-01

The interaction between molecular complexes in different dispersive media with local and nonlocal screening is investigated theoretically. On the basis of results of numerical analysis on a computer, the dependence of the coupled-system spectrum and the interaction energy of the polarized modes on the characteristic parameters of the dispersive media is considered

Accelerating Gas Adsorption on 3D Percolating Carbon Nanotubes.

Science.gov (United States)

Li, Hui; Wen, Chenyu; Zhang, Youwei; Wu, Dongping; Zhang, Shi-Li; Qiu, Zhi-Jun

2016-02-18

In the field of electronic gas sensing, low-dimensional semiconductors such as single-walled carbon nanotubes (SWCNTs) can offer high detection sensitivity owing to their unprecedentedly large surface-to-volume ratio. The sensitivity and responsivity can further improve by increasing their areal density. Here, an accelerated gas adsorption is demonstrated by exploiting volumetric effects via dispersion of SWCNTs into a percolating three-dimensional (3D) network in a semiconducting polymer. The resultant semiconducting composite film is evaluated as a sensing membrane in field effect transistor (FET) sensors. In order to attain reproducible characteristics of the FET sensors, a pulsed-gate-bias measurement technique is adopted to eliminate current hysteresis and drift of sensing baseline. The rate of gas adsorption follows the Langmuir-type isotherm as a function of gas concentration and scales with film thickness. This rate is up to 5 times higher in the composite than only with an SWCNT network in the transistor channel, which in turn results in a 7-fold shorter time constant of adsorption with the composite. The description of gas adsorption developed in the present work is generic for all semiconductors and the demonstrated composite with 3D percolating SWCNTs dispersed in functional polymer represents a promising new type of material for advanced gas sensors.

Analysis of the 48Ca neutron skin using a nonlocal dispersive-optical-model self-energy

Science.gov (United States)

Atkinson, Mack; Mahzoon, Hossein; Dickhoff, Willem; Charity, Robert

2017-09-01

A nonlocal dispersive-optical-model (DOM) analysis of the 40Ca and 48Ca nuclei has been implemented. The real and imaginary potentials are constrained by fitting to elastic-scattering data, total and reaction cross sections, energy level information, particle number, and the charge densities of 40Ca and 48Ca, respectively. The nonlocality of these potentials permits a proper dispersive self-energy which accurately describes both positive and negative energy observables. 48Ca is of particular interest because it is doubly magic and has a neutron skin due to the excess of neutrons. The DOM neutron skin radius is found to be rskin = 0.245 , which is larger than most previous calculations. The neutron skin is closely related to the symmetry energy which is a crucial part of the nuclear equation of state. The combined analysis of 40Ca and 48Ca energy densities provides a description of the density dependence of the symmetry energy which is compared with the 48Ca neutron skin. Results for 208Pb will also become available in the near future. NSF.

An analysis of main factors in electron beam flue gas purification

International Nuclear Information System (INIS)

Zhang Ming; Xu Guang

2003-01-01

Electron beam flue gas purification method is developing very quickly in recent years. Based on the experiment setting for electron beam flue gas purification in Institute of Nuclear Energy and Technology, Tsinghua University, how the technique factors affect the ratio of desulphurization and denitrogenation are described. Radiation dose (D), temperature (T), humidity (H), pour ammonia quantity (α) and initial concentration of SO 2 (C SO 2 ) and NO x (C NO x ) are main factors influencing flue gas purification. Using the methods of correlation analysis and regression analysis, the primary effect factors are found out and the regression equations are set to optimize the system process, predigest the system structure and to forecast the experimental results. (authors)

Laser-plasma sourced, temperature dependent, VUV spectrophotometer using dispersive analysis

International Nuclear Information System (INIS)

French, R.H.

1990-01-01

We have developed a vacuum ultraviolet spectrophotometer with wide energy and temperature range coverage, utilizing a laser-plasma light source (LPLS), CO 2 -laser sample heating and time-resolved dispersive analysis. Reflection and transmission spectra can be taken from 1.7 to 40 eV (31-700 nm) on samples at 15-1800 K with a time resolution of 20-400 ns. These capabilities permit the study of the temperature dependence of the electronic structure, encompassing the effects of thermal lattice expansion and electron-phonon interaction, and changes in the electronic structure associated with equilibrium and metastable phase transitions and stress relaxation. The LPLS utilizes a samarium laser-plasma created by a Q-switched Nd:YAG laser (500 mJ/pulse) to produce high brightness, stable, continuum radiation. The spectrophotometer is of a single beam design using calibrated iridium reference mirrors. White light is imaged off the sample in to the entrance slit of a 1-m polychromator. The resolution is 0.1 to 0.3 nm. The dispersed light is incident on a focal plane phosphor, fiber-optic-coupled to an image-intensified reticon detector. For spectroscopy between 300 and 1800 K, the samples are heated in situ with a 150 Watt CO 2 laser. The signal to noise ratio in the VUV, for samples at 1800 K, is excellent. From 300 K to 15 K samples are cooled using a He cryostat. (orig.)

Performance of a gaseous detector based energy dispersive X-ray fluorescence imaging system: Analysis of human teeth treated with dental amalgam

International Nuclear Information System (INIS)

Silva, A.L.M.; Figueroa, R.; Jaramillo, A.; Carvalho, M.L.; Veloso, J.F.C.A.

2013-01-01

Energy dispersive X-ray fluorescence (EDXRF) imaging systems are of great interest in many applications of different areas, once they allow us to get images of the spatial elemental distribution in the samples. The detector system used in this study is based on a micro patterned gas detector, named Micro-Hole and Strip Plate. The full field of view system, with an active area of 28 × 28 mm 2 presents some important features for EDXRF imaging applications, such as a position resolution below 125 μm, an intrinsic energy resolution of about 14% full width at half maximum for 5.9 keV X-rays, and a counting rate capability of 0.5 MHz. In this work, analysis of human teeth treated by dental amalgam was performed by using the EDXRF imaging system mentioned above. The goal of the analysis is to evaluate the system capabilities in the biomedical field by measuring the drift of the major constituents of a dental amalgam, Zn and Hg, throughout the tooth structures. The elemental distribution pattern of these elements obtained during the analysis suggests diffusion of these elements from the amalgam to teeth tissues. - Highlights: • Demonstration of an EDXRF imaging system based on a 2D-MHSP detector for biological analysis • Evaluation of the drift of the dental amalgam constituents, throughout the teeth • Observation of Hg diffusion, due to hydroxyapatite crystal defects that compose the teeth tissues

Performance of a gaseous detector based energy dispersive X-ray fluorescence imaging system: Analysis of human teeth treated with dental amalgam

Energy Technology Data Exchange (ETDEWEB)

Silva, A.L.M. [I3N, Physics Dept, University of Aveiro, 3810-193 Aveiro (Portugal); Figueroa, R.; Jaramillo, A. [Physics Department, Universidad de La Frontera, Temuco (Chile); Carvalho, M.L. [Atomic Physics Centre, University of Lisbon, 1649-03 Lisboa (Portugal); Veloso, J.F.C.A., E-mail: joao.veloso@ua.pt [I3N, Physics Dept, University of Aveiro, 3810-193 Aveiro (Portugal)

2013-08-01

Energy dispersive X-ray fluorescence (EDXRF) imaging systems are of great interest in many applications of different areas, once they allow us to get images of the spatial elemental distribution in the samples. The detector system used in this study is based on a micro patterned gas detector, named Micro-Hole and Strip Plate. The full field of view system, with an active area of 28 × 28 mm{sup 2} presents some important features for EDXRF imaging applications, such as a position resolution below 125 μm, an intrinsic energy resolution of about 14% full width at half maximum for 5.9 keV X-rays, and a counting rate capability of 0.5 MHz. In this work, analysis of human teeth treated by dental amalgam was performed by using the EDXRF imaging system mentioned above. The goal of the analysis is to evaluate the system capabilities in the biomedical field by measuring the drift of the major constituents of a dental amalgam, Zn and Hg, throughout the tooth structures. The elemental distribution pattern of these elements obtained during the analysis suggests diffusion of these elements from the amalgam to teeth tissues. - Highlights: • Demonstration of an EDXRF imaging system based on a 2D-MHSP detector for biological analysis • Evaluation of the drift of the dental amalgam constituents, throughout the teeth • Observation of Hg diffusion, due to hydroxyapatite crystal defects that compose the teeth tissues.

Exergy analysis of a gas-hydrate cool storage system

International Nuclear Information System (INIS)

Bi, Yuehong; Liu, Xiao; Jiang, Minghe

2014-01-01

Based on exergy analysis of charging and discharging processes in a gas-hydrate cool storage system, the formulas for exergy efficiency at the sensible heat transfer stage and the phase change stage corresponding to gas-hydrate charging and discharging processes are obtained. Furthermore, the overall exergy efficiency expressions of charging, discharging processes and the thermodynamic cycle of the gas-hydrate cool storage system are obtained. By using the above expressions, the effects of number of transfer units, the inlet temperatures of the cooling medium and the heating medium on exergy efficiencies of the gas-hydrate cool storage system are emphatically analyzed. The research results can be directly used to evaluate the performance of gas-hydrate cool storage systems and design more efficient energy systems by reducing the sources of inefficiency in gas-hydrate cool storage systems. - Highlights: • Formulas for exergy efficiency at four stages are obtained. • Exergy efficiency expressions of two processes and one cycle are obtained. • Three mainly influencing factors on exergy efficiencies are analyzed. • With increasing the inlet temperature of cooling medium, exergy efficiency increases. • With decreasing the inlet temperature of heating medium, exergy efficiency increases

Analysis of the effects of meteorology on aircraft exhaust dispersion and deposition using a Lagrangian particle model

Energy Technology Data Exchange (ETDEWEB)

Pecorari, Eliana, E-mail: eliana.pecorari@unive.it [Department of Environmental Science, Informatics and Statistics, University Ca’ Foscari Venice, Calle Larga Santa Marta 2137, Dorsoduro, 30123 Venezia (Italy); Mantovani, Alice [OSMOTECH S.r.l., via Francesco Sforza, 15, 20122 Milano (Italy); Franceschini, Chiara [Department of Environmental Science, Informatics and Statistics, University Ca’ Foscari Venice, Calle Larga Santa Marta 2137, Dorsoduro, 30123 Venezia (Italy); Bassano, Davide [SAVE S.p.A., Marco Polo Venice airport viale G. Galilei 30/1, 30173 Tessera-Venezia (Italy); Palmeri, Luca [Department of Industrial Engineering, University of Padova, v. Marzolo 9, 35131 Padova (Italy); Rampazzo, Giancarlo [Department of Environmental Science, Informatics and Statistics, University Ca’ Foscari Venice, Calle Larga Santa Marta 2137, Dorsoduro, 30123 Venezia (Italy)

2016-01-15

The risk of air quality degradation is of considerable concern particularly for those airports that are located near urban areas. The ability to quantitatively predict the effects of air pollutants originated by airport operations is important for assessing air quality and the related impacts on human health. Current emission regulations have focused on local air quality in the proximity of airports. However, an integrated study should consider the effects of meteorological events, at both regional and local level, that can affect the dispersion and the deposition of exhausts. Rigorous scientific studies and extensive experimental data could contribute to the analysis of the impacts of airports expansion plans. This paper is focused on the analysis of the effects of meteorology on aircraft emission for the Marco Polo Airport in Venice. This is the most important international airport in the eastern part of the Po’ Valley, one of the most polluted area in Europe. Air pollution is exacerbated by meteorology that is a combination of large and local scale effects that do not allow significant dispersion. Moreover, the airport is located near Venice, a city of noteworthy cultural and architectural relevance, and nearby the lagoon that hosts several areas of outstanding ecological importance at European level (Natura 2000 sites). Dispersion and deposit of the main aircraft exhausts (NOx, HC and CO) have been evaluated by using a Lagrangian particle model. Spatial and temporal aircraft exhaust dispersion has been analyzed for LTO cycle. Aircraft taxiing resulted to be the most impacting aircraft operation especially for the airport working area and its surroundings, however occasionally peaks may be observed even at high altitudes when cruise mode starts. Mixing height can affect concentrations more significantly than the concentrations in the exhausts themselves. An increase of HC and CO concentrations (15–50%) has been observed during specific meteorological events

Analysis of the effects of meteorology on aircraft exhaust dispersion and deposition using a Lagrangian particle model

International Nuclear Information System (INIS)

Pecorari, Eliana; Mantovani, Alice; Franceschini, Chiara; Bassano, Davide; Palmeri, Luca; Rampazzo, Giancarlo

2016-01-01

The risk of air quality degradation is of considerable concern particularly for those airports that are located near urban areas. The ability to quantitatively predict the effects of air pollutants originated by airport operations is important for assessing air quality and the related impacts on human health. Current emission regulations have focused on local air quality in the proximity of airports. However, an integrated study should consider the effects of meteorological events, at both regional and local level, that can affect the dispersion and the deposition of exhausts. Rigorous scientific studies and extensive experimental data could contribute to the analysis of the impacts of airports expansion plans. This paper is focused on the analysis of the effects of meteorology on aircraft emission for the Marco Polo Airport in Venice. This is the most important international airport in the eastern part of the Po’ Valley, one of the most polluted area in Europe. Air pollution is exacerbated by meteorology that is a combination of large and local scale effects that do not allow significant dispersion. Moreover, the airport is located near Venice, a city of noteworthy cultural and architectural relevance, and nearby the lagoon that hosts several areas of outstanding ecological importance at European level (Natura 2000 sites). Dispersion and deposit of the main aircraft exhausts (NOx, HC and CO) have been evaluated by using a Lagrangian particle model. Spatial and temporal aircraft exhaust dispersion has been analyzed for LTO cycle. Aircraft taxiing resulted to be the most impacting aircraft operation especially for the airport working area and its surroundings, however occasionally peaks may be observed even at high altitudes when cruise mode starts. Mixing height can affect concentrations more significantly than the concentrations in the exhausts themselves. An increase of HC and CO concentrations (15–50%) has been observed during specific meteorological events

Environmental analysis for pipeline gas demonstration plants

Energy Technology Data Exchange (ETDEWEB)

Stinton, L.H.

1978-09-01

The Department of Energy (DOE) has implemented programs for encouraging the development and commercialization of coal-related technologies, which include coal gasification demonstration-scale activities. In support of commercialization activities the Environmental Analysis for Pipeline Gas Demonstration Plants has been prepared as a reference document to be used in evaluating potential environmental and socioeconomic effects from construction and operation of site- and process-specific projects. Effluents and associated impacts are identified for six coal gasification processes at three contrasting settings. In general, impacts from construction of a high-Btu gas demonstration plant are similar to those caused by the construction of any chemical plant of similar size. The operation of a high-Btu gas demonstration plant, however, has several unique aspects that differentiate it from other chemical plants. Offsite development (surface mining) and disposal of large quantities of waste solids constitute important sources of potential impact. In addition, air emissions require monitoring for trace metals, polycyclic aromatic hydrocarbons, phenols, and other emissions. Potential biological impacts from long-term exposure to these emissions are unknown, and additional research and data analysis may be necessary to determine such effects. Possible effects of pollutants on vegetation and human populations are discussed. The occurrence of chemical contaminants in liquid effluents and the bioaccumulation of these contaminants in aquatic organisms may lead to adverse ecological impact. Socioeconomic impacts are similar to those from a chemical plant of equivalent size and are summarized and contrasted for the three surrogate sites.

Determination of gas recovery efficiency at two Danish landfills by performing downwind methane measurements and stable carbon isotopic analysis

DEFF Research Database (Denmark)

Fathi Aghdam, Ehsan; Fredenslund, Anders Michael; Chanton, Jeffrey

2018-01-01

In this study, the total methane (CH4) generation rate and gas recovery efficiency at two Danish landfills were determined by field measurements. The landfills are located close to each other and are connected to the same gas collection system. The tracer gas dispersion method was used...... for quantification of CH4 emissions from the landfills, while the CH4 oxidation efficiency in the landfill cover layers was determined by stable carbon isotopic technique. The total CH4 generation rate was estimated by a first-order decay model (Afvalzorg) and was compared with the total CH4 generation rate...... determined by field measurements. CH4 emissions from the two landfills combined ranged from 29.1 to 49.6 kg CH4/h. The CH4 oxidation efficiency was 6–37%, with an average of 18% corresponding to an average CH4 oxidation rate of 8.1 kg CH4/h. The calculated gas recovery efficiency was 59–76%, indicating...

A low cost multi-purpose experimental arrangement for variants in energy dispersive X-ray fluorescence analysis

International Nuclear Information System (INIS)

Nascimento Filho, V.F.; Silva, R.M.C.; Moraes, L.M.B.; Parreira, P.S.; Appoloni, R.C.; Silva, R.M.C.

2005-01-01

Based in an X-ray tower with four exits (two line and two point beams) experimental conditions were arranged to carry out variants in energy dispersive X-ray fluorescence analysis: (1) the conventional one (EDXRF), with excitation/detection of thin and thick samples, under vacuum and air atmosphere, (2) the X-ray energy dispersive micro- fluorescence analysis(μ-EDXRF), with 2D mapping, using a quartz capillar, (3) the total reflection X-ray fluorescence (TXRF), under He and air atmosphere, and (4) secondary target/polarized X-ray fluorescence (P-EDXRF). It was possible to use a Cu, Mo or W target on the X-ray tube, with or without filter (V, Fe, Ni and Zr), and Si(Li) or Si-PIN semicondutor detectors coupled to a multichannel analyzer. In addition, it was possible to use the point beam to carry out experiments on (5) X-ray radiography and (6) X-ray absorption, and the line beam on (7) X-ray diffractometry studies.

Residual gas analysis

International Nuclear Information System (INIS)

Berecz, I.

1982-01-01

Determination of the residual gas composition in vacuum systems by a special mass spectrometric method was presented. The quadrupole mass spectrometer (QMS) and its application in thin film technology was discussed. Results, partial pressure versus time curves as well as the line spectra of the residual gases in case of the vaporization of a Ti-Pd-Au alloy were demonstrated together with the possible construction schemes of QMS residual gas analysers. (Sz.J.)

Aspects of the dispersion of denser-than-air vapours relevant to gas cloud explosions

International Nuclear Information System (INIS)

Wheatley, C.J.; Webber, D.M.

1985-01-01

The essential aim of the study presented here is to improve upon the understanding and prediction of the atmospheric dispersion of denser-than-air vapours, and thereby reduce the uncertainties in predicting hazards which might arise from the accidental release of a dense, flammable vapour cloud. In the first phase of the study, models for dispersion in the atmosphere of denser-than-air vapours are reviewed. It is found that a significant source of uncertainty in predictions of all models is the calculation of dilution caused by turbulence. This is due to spreading and stratification caused by the excess density of the cloud and to the interaction of the cloud motion with the ambient flow field. These effects lead to a complex field of turbulence. An additional, significant source of uncertainty is found to be present in '3D' models due to the use of coarse computational grids. A number of experimental tests are proposed which permit fundamental discrimination between the models with the object of reducing uncertainties. In the second phase of the study, a new 'box' model is proposed (A 'box' model is one in which only gross properties of the flow are predicted). All sources of turbulence are included in a way consistent with laboratory studies of entrainment in stratified flows. The prescribed concentration distribution models the initial 'mixed layer'/'gravity spreading' phase and the final 'passive' phase of dispersion with a smooth transition between the two. In the third phase of the study, implications of dispersion of denser-than-air flammable vapour clouds in open terrain for flame speeds following ignition by a weak source are assessed. It is concluded that flame speeds sufficient to cause significant overpressures cannot occur in unobstructed terrain. (author)

Molecular gas analysis by Raman scattering in intracavity laser configuration

International Nuclear Information System (INIS)

Benner, R.E.; Andrade, J.D.; Van Wagenen, R.A.; Westenskow, D.R.

1987-01-01

A system is described for the near simultaneous analysis and quantitation of selected multiple polyatomic gases in a gas sample by Raman light scattering comprising in combination: (a) laser means capable of producing a polarized laser beam of a selected wavelength containing a laser cavity the laser cavity containing a plasma tube and wherein one end of the laser cavity contains a high reflectivity output coupler mirror; (b) a gas sampling cell located within the laser cavity between the plasma tube and the output coupler mirror, the cell having opposing parallel end windows interconnected by a continuous sidewall. The end windows and sidewall define a longitudinal gas chamber oriented such that, when the laser beam is activated, the laser beam is coincident with and traverses the axis of the longitudinal gas chamber, the end windows being positioned to be substantially normal to the axis of the longitudinal gas cell chamber. The cell also has opposing, aligned side windows in the sidewall parallel to and on either side of the axis of the longitudinal gas chamber. The gas cell further contains inlet and outlet means communicating with the chamber to pass a sample gas through the cell

Sensitivity analysis and economic optimization studies of inverted five-spot gas cycling in gas condensate reservoir

Science.gov (United States)

Shams, Bilal; Yao, Jun; Zhang, Kai; Zhang, Lei

2017-08-01

Gas condensate reservoirs usually exhibit complex flow behaviors because of propagation response of pressure drop from the wellbore into the reservoir. When reservoir pressure drops below the dew point in two phase flow of gas and condensate, the accumulation of large condensate amount occurs in the gas condensate reservoirs. Usually, the saturation of condensate accumulation in volumetric gas condensate reservoirs is lower than the critical condensate saturation that causes trapping of large amount of condensate in reservoir pores. Trapped condensate often is lost due to condensate accumulation-condensate blockage courtesy of high molecular weight, heavy condensate residue. Recovering lost condensate most economically and optimally has always been a challenging goal. Thus, gas cycling is applied to alleviate such a drastic loss in resources. In gas injection, the flooding pattern, injection timing and injection duration are key parameters to study an efficient EOR scenario in order to recover lost condensate. This work contains sensitivity analysis on different parameters to generate an accurate investigation about the effects on performance of different injection scenarios in homogeneous gas condensate system. In this paper, starting time of gas cycling and injection period are the parameters used to influence condensate recovery of a five-spot well pattern which has an injection pressure constraint of 3000 psi and production wells are constraint at 500 psi min. BHP. Starting injection times of 1 month, 4 months and 9 months after natural depletion areapplied in the first study. The second study is conducted by varying injection duration. Three durations are selected: 100 days, 400 days and 900 days. In miscible gas injection, miscibility and vaporization of condensate by injected gas is more efficient mechanism for condensate recovery. From this study, it is proven that the application of gas cycling on five-spot well pattern greatly enhances condensate recovery

Decomposition analysis of gas consumption in the residential sector in Ireland

International Nuclear Information System (INIS)

Rogan, Fionn; Cahill, Caiman J.; Ó Gallachóir, Brian P.

2012-01-01

To-date, decomposition analysis has been widely used at the macro-economic level and for in-depth analyses of the industry and transport sectors; however, its application in the residential sector has been rare. This paper uses the Log-Mean Divisia Index I (LMDI-I) methodology to decompose gas consumption trends in the gas-connected residential sector in Ireland from 1990 to 2008, which despite an increasing number of energy efficiency policies, experienced total final consumption growth of 470%. The analysis decomposes this change in gas consumption into a number of effects, examining the impact over time of market factors such as a growing customer base, varying mix of dwelling types, changing share of vacant dwellings, changing size of new dwellings, the impact of building regulations policy and other factors such as the weather. The analysis finds the most significant effects are changing customer numbers and changing intensity; the analysis also quantifies the impact of building regulations and compares it with other effects such as changing size of new dwellings. By comparing the historical impact on gas consumption of policy factors and non-policy factors, this paper highlights the challenge for policy-makers in achieving overall energy consumption reduction. - Highlights: ► Contribution to a gap in the literature with a residential sector decomposition analysis of gas TFC. ► Activity effect had the largest impact and was cumulatively the best explainer of total TFC change. ► Intensity effect was the second biggest effect with a 19% share of total TFC change. ► In line with rising surface temperatures, the weather effect is declining over time. ► Building regulations are having a diminishing impact but are being negated by larger dwellings.