Reduced-order modellin for high-pressure transient flow of hydrogen-natural gas mixture

Science.gov (United States)

Agaie, Baba G.; Khan, Ilyas; Alshomrani, Ali Saleh; Alqahtani, Aisha M.

2017-05-01

In this paper the transient flow of hydrogen compressed-natural gas (HCNG) mixture which is also referred to as hydrogen-natural gas mixture in a pipeline is numerically computed using the reduced-order modelling technique. The study on transient conditions is important because the pipeline flows are normally in the unsteady state due to the sudden opening and closure of control valves, but most of the existing studies only analyse the flow in the steady-state conditions. The mathematical model consists in a set of non-linear conservation forms of partial differential equations. The objective of this paper is to improve the accuracy in the prediction of the HCNG transient flow parameters using the Reduced-Order Modelling (ROM). The ROM technique has been successfully used in single-gas and aerodynamic flow problems, the gas mixture has not been done using the ROM. The study is based on the velocity change created by the operation of the valves upstream and downstream the pipeline. Results on the flow characteristics, namely the pressure, density, celerity and mass flux are based on variations of the mixing ratio and valve reaction and actuation time; the ROM computational time cost advantage are also presented.

Pressure transients analysis of a high-temperature gas-cooled reactor with direct helium turbine cycle

Energy Technology Data Exchange (ETDEWEB)

Dang, M.; Dupont, J. F.; Jacquemoud, P.; Mylonas, R. [Eidgenoessisches Inst. fuer Reaktorforschung, Wuerenlingen (Switzerland)

1981-01-15

The direct coupling of a gas cooled reactor with a closed gas turbine cycle leads to a specific dynamic plant behaviour, which may be summarized as follows: a) any operational transient involving a variation of the core mass flow rate causes a variation of the pressure ratio of the turbomachines and leads unavoidably to pressure and temperature transients in the gas turbine cycle; and b) very severe pressure equalization transients initiated by unlikely events such as the deblading of one or more turbomachines must be taken into account. This behaviour is described and illustrated through results gained from computer analyses performed at the Swiss Federal Institute for Reactor Research (EIR) in Wurenlingen within the scope of the Swiss-German HHT project.

Transient gas flow through layered porous media

International Nuclear Information System (INIS)

Morrison, F.A. Jr.

1975-01-01

Low Reynolds number isothermal flow of an ideal gas through layered porous material was investigated analytically. Relations governing the transient flow in one dimension are obtained. An implicit, iterative, unconditionally stable finite difference scheme is developed for calculation of such flows. A computer code, SIROCCO, employing this technique has been written and implemented on the LLL computer system. A listing of the code is included. This code may be effectively applied to the evaluation of stemming plans for underground nuclear experiments. (U.S.)

Fission gas behaviour modelling in plate fuel during a power transient

International Nuclear Information System (INIS)

Portier, S.

2003-01-01

This thesis is dedicated to the identification and modelization of the phenomena which are at the origin of the release of the fission gas formed in UO 2 plate fuels during the irradiation in a power transient. In the first experimental part, samples of plate fuels, irradiated at 36 GWj/tU, have been annealed to temperatures from 1100 C to 1500 C in a device that enabled the measurement of gas release in real time. At 1300 C, post-annealing observations demonstrated a link between the measured gas releases to a rapid formation of labyrinths at the grain surface. These labyrinths, which were formed by intergranular bubble interconnection, create release paths for the gas atoms which reach the grain surface. At this stage, the available experimental results (annealing and observations) were interpreted considering that it is the spreading of the gas atoms from the grains to the grain boundaries that is at the origin of the observed releases. This interpretation generates the hypothesis that a) at the end of the basic irradiation, the gas is at the atomic state and b) during the annealing, the spreading is reduced by the intragranular bubbles of the gas atoms. The last part of the work is dedicated to the modelization of the main phenomena at the origin of the gas release. The model developed, based on the model of the gas behaviour in MARGARET PWR, highlighted the great influence of the irradiation conditions on the gas distribution at the end of the irradiation and also its influence on the fission gas release during the power transient. (author) [fr

Mountain scale modeling of transient, coupled gas flow, heat transfer and carbon-14 migration

International Nuclear Information System (INIS)

Lu, Ning; Ross, B.

1993-01-01

We simulate mountain-scale coupled heat transfer and gas flow at Yucca Mountain. A coupled rock-gas flow and heat transfer model, TGIF2, is used to simulate mountain-scale two-dimensional transient heat transfer and gas flow. The model is first verified against an analytical solution for the problem of an infinite horizontal layer of fluid heated from below. Our numerical results match very well with the analytical solution. Then, we obtain transient temperature and gas flow distributions inside the mountain. These distributions are used by a transient semianalytical particle tracker to obtain carbon-14 travel times for particles starting at different locations within the repository. Assuming that the repository is filled with 30-year-old waste at an initial areal power density of 57 kw/acre, we find that repository temperatures remain above 60 degrees C for more than 10,000 years. Carbon-14 travel times to the surface are mostly less than 1000 years, for particles starting at any time within the first 10,000 years

Evaluation of Start Transient Oscillations with the J-2X Engine Gas Generator Assembly

Science.gov (United States)

Hulka, J. R.; Morgan, C. J.; Casiano, M. J.

2015-01-01

During development of the gas generator for the liquid oxygen/liquid hydrogen propellant J-2X rocket engine, distinctive and oftentimes high-amplitude pressure oscillations and hardware vibrations occurred during the start transient of nearly every workhorse gas generator assembly test, as well as during many tests of engine system hardware. These oscillations appeared whether the steady-state conditions exhibited stable behavior or not. They occurred similarly with three different injector types, and with every combustion chamber configuration tested, including chamber lengths ranging over a 5:1 range, several different nozzle types, and with or without a side branch line simulating a turbine spin start gas supply line. Generally, two sets of oscillations occurred, one earlier in the start transient and at higher frequencies, and the other almost immediately following and at lower frequencies. Multiple dynamic pressure measurements in the workhorse combustion chambers indicated that the oscillations were associated with longitudinal acoustic modes of the combustion chambers, with the earlier and higher frequency oscillation usually related to the second longitudinal acoustic mode and the later and lower frequency oscillation usually related to the first longitudinal acoustic mode. Given that several early development gas generator assemblies exhibited unstable behavior at frequencies near the first longitudinal acoustic modes of longer combustion chambers, the start transient oscillations are presumed to provide additional insight into the nature of the combustion instability mechanisms. Aspects of the steadystate oscillations and combustion instabilities from development and engine system test programs have been reported extensively in the three previous JANNAF Liquid Propulsion Subcommittee meetings (see references below). This paper describes the hardware configurations, start transient sequence operations, and transient and dynamic test data during the start

Normalization of natural gas composition data measured by gas chromatography

International Nuclear Information System (INIS)

Milton, Martin J T; Harris, Peter M; Brown, Andrew S; Cowper, Chris J

2009-01-01

The composition of natural gas determined by gas chromatography is routinely used as the basis for calculating physico-chemical properties of the gas. Since the data measured by gas chromatography have particular statistical properties, the methods used to determine the composition can make use of a priori assumptions about the statistical model for the data. We discuss a generalized approach to determining the composition, and show that there are particular statistical models for the data for which the generalized approach reduces to the widely used method of post-normalization. We also show that the post-normalization approach provides reasonable estimates of the composition for cases where it cannot be shown to arise rigorously from the statistical structure of the data

Preformed transient gas channels for laser wakefield particle acceleration

International Nuclear Information System (INIS)

Wood, W.M.

1994-01-01

Acceleration of electrons by laser-driven plasma wake fields is limited by the range over which a laser pulse can maintain its intensity. This distance is typically given by the Rayleigh range for the focused laser beam, usually on the order of 0.1 mm to 1 mm. For practical particle acceleration, interaction distances on the order of centimeters are required. Therefore, some means of guiding high intensity laser pulses is necessary. Light intensities on the order of a few times 10 17 W/cm 2 are required for laser wakefield acceleration schemes using near IR radiation. Gas densities on the order of or greater than 10 17 cm -3 are also needed. Laser-atom interaction studies in this density and intensity regime are generally limited by the concomitant problems in beam propagation introduced by the creation of a plasma. In addition to the interaction distance limit imposed by the Rayleigh range, defocusing of the high intensity laser pulse further limits the peak intensity which can be achieved. To solve the problem of beam propagation limitations in laser-plasma wakefield experiments, two potential methods for creating transient propagation channels in gaseous targets are investigated. The first involves creation of a charge-neutral channel in a gas by an initial laser pulse, which then is ionized by a second, ultrashort, high-intensity pulse to create a waveguide. The second method involves the ionization of a gas column by an ultrashort pulse; a transient waveguide is formed by the subsequent expansion of the heated plasma into the neutral gas

Radio interference and transient field from gas-insulated substations

International Nuclear Information System (INIS)

Harvey, S.M.; Wong, P.S.; Balma, P.M.

1995-01-01

Gas-insulated substations (GIS), owing to their compact nature, offer an attractive alternative to conventional substations in areas where space is limited, such as in urban areas. Consequently, it is important to address the issue of environmental conditions within the substation and in the surrounding areas. This paper reports the result of radio interference (RI) and transient field measurements at two GIS in Ontario, Canada. For comparison with RI levels taken at the GIS, RI levels outside two hospitals in the Toronto area were also measured. The transient field study covers electromagnetic interference (EMI) levels generated during switching operations, and includes measurements inside and outside the GIS. Measurements show that RI levels from the GIS were either below background levels, or contributed little to the background. RI levels outside the GIS and the hospitals were similar. Peak transient field values up to 580 V/m were measured inside the station building, and dropped to background values of 10 V/m at about 120 m from the station. The transient field (E) dropped off at a rate of 3/2 power with distance (d) from the air-insulated 115 kV bus, i.e. E ∝ d -1.5

Gas Composition Sensor for Natural Gas and Biogas

NARCIS (Netherlands)

Boersma, A.; Sweelsen, J.; Blokland, H.

2016-01-01

The calorific value of energetic gasses is an important parameter in the quality assessment of gas steams, and can be calculated from the chemical composition of the gas. An array of capacitive sensor electrodes was developed, each functionalized with a gas responsive coating to measure the

Transient heat transfer for helium gas flowing over a horizontal cylinder with exponentially increasing heat input

International Nuclear Information System (INIS)

Liu, Qiusheng; Fukuda, Katsuya

2003-01-01

The transient heat transfer coefficients for forced convection flow of helium gas over a horizontal cylinder were measured under wide experimental conditions. The platinum cylinder with a diameter of 1.0 mm was used as test heater and heated by electric current with an exponentially increasing heat input of Q 0 exp(t/τ). The gas flow velocities ranged from 5 to 35 m/s, the gas temperatures ranged from 25 to 80degC, and the periods of heat generation rate, τ, ranged from 40 ms to 20 s. The surface superheat and heat flux increase exponentially as the heat generation rate increases with the exponential function. It was clarified that the heat transfer coefficient approaches the quasi-steady-state one for the period τ longer than about 1 s, and it becomes higher for the period shorter than around 1 s. The transient heat transfer shows less dependence on the gas flowing velocity when the period becomes very shorter. The gas temperature in this study shows little influence on the heat transfer coefficient. Semi-empirical correlation for quasi-steady-state heat transfer was obtained based on the experimental data. The ratios of transient Nusselt number Nu tr to quasi-steady-state Nusselt number Nu st at various periods, flow velocities, and gas temperatures were obtained. The heat transfer shifts to the quasi-steady-state heat transfer for longer periods and shifts to the transient heat transfer for shorter periods at the same flow velocity. It also approaches the quasi-steady-state one for higher flow velocity at the same period. Empirical correlation for transient heat transfer was also obtained based on the experimental data. (author)

Static and transient characteristics of the shaft seal system for helium gas circulator (Part 1)

International Nuclear Information System (INIS)

Morohoshi, S.; Saki, K.; Nemoto, M.; Taniguchi, S.; Sugimoto, A.; Kojima, M.

1982-01-01

A development program of the shaft seal system for the helium circulator supported by water lubricated bearings is presented. A seal system simulating tester and a computer program which can simulate the transient characteristics of a buffer gas seal system were newly introduced, and an investigation was performed experimentally and analytically of the characteristics of water and gas seals and of the buffer gas seal system including the control system. Main results are as follows: (1) Water seals were especially investigated in detail, and it was found that turbulence in water flow through seal clearance and deformation of seal components affected the leakage characteristics of water seals. They should be considered not only to make safety design but also to get optimum design of the seal system. (2) The calculation method for transient response of the buffer gas seal system including the control system was developed. This digital simulating method can well simulate transients encountered in the tester, and it would make a powerful tool for developing a safe seal system under steady state operation conditions and at depressurization accidents in a reactor

Simple method of calculating the transient thermal performance of composite material and its applicable condition

Institute of Scientific and Technical Information of China (English)

张寅平; 梁新刚; 江忆; 狄洪发; 宁志军

2000-01-01

Degree of mixing of composite material is defined and the condition of using the effective thermal diffusivity for calculating the transient thermal performance of composite material is studied. The analytical result shows that for a prescribed precision of temperature, there is a condition under which the transient temperature distribution in composite material can be calculated by using the effective thermal diffusivity. As illustration, for the composite material whose temperatures of both ends are constant, the condition is presented and the factors affecting the relative error of calculated temperature of composite materials by using effective thermal diffusivity are discussed.

Steady-state and transient simulations of gas cooled reactor with the computer code CATHARE

International Nuclear Information System (INIS)

Tauveron, N.; Saez, M.; Marchand, M.; Chataing, T.; Geffraye, G.; Cherel, J. M.

2003-01-01

This work concerns the design and safety analysis of Gas Cooled Reactors. The CATHARE code is used to test the design and safety of two different concepts, a High Temperature Gas Reactor concept (HTGR) and a Gas Fast Reactor concept (GFR). Relative to the HTGR concept, three transient simulations are performed and described in this paper: loss of electrical load without turbomachine trip, 10 inch cold duct break, 10 inch cold duct break combined with a tube rupture of a cooling exchanger. A second step consists in modelling a GFR concept. A nominal steady state situation at a power of 600 MW is obtained and first transient simulations are carried out to study decay heat removal situations after primary loop depressurisation

Extraction of diagnostic parameters from the transient response of a porous electro ceramic gas sensor

International Nuclear Information System (INIS)

Hossein-Babaei, F.; Orvatinia, M.

2004-01-01

A novel concept for the diagnosis of a pure target gas in air is presented. The method employs a resistive gas sensor with a mm-thick highly porous electro ceramic gas sensitive body. The diagnosis is based on the fact that the diffusion time of the target gas through the porous body would depend on its molecular properties. The transient response of the device was analyzed based on a diffusion reaction equation. The solutions of the equation were shown to be of diagnostic merits. Such a device was fabricated by partial sintering of a Zn O body formed by low pressure pressing. The transient responses of the device to methanol, ethanol, poropanol and butanol were recorded. The analytical data, and the diagnostic parameters were resulted as the fitting parameters. Comparison of the parameters obtained with those available from the calibration experiments afforded target gas identification

Analysis of transient fission gas behaviour in oxide fuel using BISON and TRANSURANUS

Energy Technology Data Exchange (ETDEWEB)

Barani, T.; Bruschi, E.; Pizzocri, D. [Politecnico di Milano, Department of Energy, Nuclear Engineering Division, Via La Masa 34, I-20156 Milano (Italy); Pastore, G. [Fuel Modeling and Simulation Department, Idaho National Laboratory, P.O. Box 1625, Idaho Falls, ID 83415-3840 (United States); Van Uffelen, P. [European Commission, Joint Research Centre, Directorate for Nuclear Safety and Security, P.O. Box 2340, 76125 Karlsruhe (Germany); Williamson, R.L. [Fuel Modeling and Simulation Department, Idaho National Laboratory, P.O. Box 1625, Idaho Falls, ID 83415-3840 (United States); Luzzi, L., E-mail: Lelio.Luzzi@polimi.it [Politecnico di Milano, Department of Energy, Nuclear Engineering Division, Via La Masa 34, I-20156 Milano (Italy)

2017-04-01

The modelling of fission gas behaviour is a crucial aspect of nuclear fuel performance analysis in view of the related effects on the thermo-mechanical performance of the fuel rod, which can be particularly significant during transients. In particular, experimental observations indicate that substantial fission gas release (FGR) can occur on a small time scale during transients (burst release). To accurately reproduce the rapid kinetics of the burst release process in fuel performance calculations, a model that accounts for non-diffusional mechanisms such as fuel micro-cracking is needed. In this work, we present and assess a model for transient fission gas behaviour in oxide fuel, which is applied as an extension of conventional diffusion-based models to introduce the burst release effect. The concept and governing equations of the model are presented, and the sensitivity of results to the newly introduced parameters is evaluated through an analytic sensitivity analysis. The model is assessed for application to integral fuel rod analysis by implementation in two structurally different fuel performance codes: BISON (multi-dimensional finite element code) and TRANSURANUS (1.5D code). Model assessment is based on the analysis of 19 light water reactor fuel rod irradiation experiments from the OECD/NEA IFPE (International Fuel Performance Experiments) database, all of which are simulated with both codes. The results point out an improvement in both the quantitative predictions of integral fuel rod FGR and the qualitative representation of the FGR kinetics with the transient model relative to the canonical, purely diffusion-based models of the codes. The overall quantitative improvement of the integral FGR predictions in the two codes is comparable. Moreover, calculated radial profiles of xenon concentration after irradiation are investigated and compared to experimental data, illustrating the underlying representation of the physical mechanisms of burst release

Excited-state dynamics of a ruthenium(II) catalyst studied by transient photofragmentation in gas phase and transient absorption in solution

Energy Technology Data Exchange (ETDEWEB)

Imanbaew, D.; Nosenko, Y. [Fachbereich Chemie, Technische Universität Kaiserslautern, Erwin-Schrödinger-Str. 52–54, 67663 Kaiserslautern (Germany); Forschungszentrum OPTIMAS, Erwin-Schrödinger-Str. 46, 67663 Kaiserslautern (Germany); Kerner, C. [Fachbereich Chemie, Technische Universität Kaiserslautern, Erwin-Schrödinger-Str. 52–54, 67663 Kaiserslautern (Germany); Chevalier, K.; Rupp, F. [Fachbereich Physik, Technische Universität Kaiserslautern, Erwin-Schrödinger-Str. 46, 67663 Kaiserslautern (Germany); Riehn, C., E-mail: riehn@chemie.uni-kl.de [Fachbereich Chemie, Technische Universität Kaiserslautern, Erwin-Schrödinger-Str. 52–54, 67663 Kaiserslautern (Germany); Forschungszentrum OPTIMAS, Erwin-Schrödinger-Str. 46, 67663 Kaiserslautern (Germany); Thiel, W.R. [Fachbereich Chemie, Technische Universität Kaiserslautern, Erwin-Schrödinger-Str. 52–54, 67663 Kaiserslautern (Germany); Diller, R. [Fachbereich Physik, Technische Universität Kaiserslautern, Erwin-Schrödinger-Str. 46, 67663 Kaiserslautern (Germany)

2014-10-17

Graphical abstract: - Highlights: • Ultrafast dynamics of new Ru(II) catalysts investigated in gas phase and solution. • Catalyst activation (HCl loss) achieved in ion trap by UV photoexcitation. • Electronic relaxation proceeds by IVR and IC followed by ground state dissociation. • No triplet formation in contrast to other Ru-polypyridine complexes. • Solvent prohibits catalyst activation in solution by fast vibrational cooling. - Abstract: We report studies on the excited state dynamics of new ruthenium(II) complexes [(η{sup 6}-cymene)RuCl(apypm)]PF{sub 6} (apypm=2-NR{sub 2}-4-(pyridine-2-yl)-pyrimidine, R=CH{sub 3} (1)/H (2)) which, in their active form [1{sup +}-HCl] and [2{sup +}-HCl], catalyze the transfer hydrogenation of arylalkyl ketones in the absence of a base. The investigations encompass femtosecond pump–probe transient mass spectrometry under isolated conditions and transient absorption spectroscopy in acetonitrile solution, both on the cations [(η{sup 6}-cymene)RuCl(apypm)]{sup +} (1{sup +}, 2{sup +}). Gas phase studies on mass selected ions were performed in an ESI ion trap mass spectrometer by transient photofragmentation, unambiguously proving the formation of the activated catalyst species [1{sup +}-HCl] or [2{sup +}-HCl] after photoexcitation being the only fragmentation channel. The primary excited state dynamics in the gas phase could be fitted to a biexponential decay, yielding time constants of <100 fs and 1–3 ps. Transient absorption spectroscopy performed in acetonitrile solution using femtosecond UV/Vis and IR probe laser pulses revealed additional deactivation processes on longer time scales (∼7–12 ps). However, the formation of the active catalyst species after photoexcitation could not be observed in solution. The results from both studies are compared to former CID investigations and DFT calculations concerning the activation mechanism.

Sensor platform for gas composition measurement

NARCIS (Netherlands)

De Graaf, G.; Bakker, F.; Wolffenbuttel, R.F.

2011-01-01

The gas sensor research presented here has a focus on the measurement of the composition of natural gas and gases from sustainable resources, such as biogas. For efficient and safe combustion, new sensor systems need to be developed to measure the composition of these new gases. In general about 6

Influence of the combustion chamber during the transient performance of gas turbines; Influencias da camara de combustao durante o transitorio de turbinas a gas

Energy Technology Data Exchange (ETDEWEB)

Cunha Alves, M.A. da [Centro Tecnico Aeroespacial, Sao Jose dos Campos, SP (Brazil). Inst. de Pesquisas e Desenvolvimento

1991-12-31

It has been realised that heat transfer and others secondary effects have an important influence on the transient performance of a gas turbine, but until very recently, modelling was carried out either assuming adiabatic conditions, or using expedient but unrealistic models to simulate these effects. This work describes the effects of combustion chamber heat storage and of dead time lag of the combustion process, during a gas turbine transient. These effects have been investigated and the analysis has indicated that these effects do not play an important role in the transient performance of the engine analysed, but in certain circumstances they may become important. (author). 5 refs., 4 figs.

Exhaust gas recirculation – Zero dimensional modelling and characterization for transient diesel combustion control

International Nuclear Information System (INIS)

Asad, Usman; Tjong, Jimi; Zheng, Ming

2014-01-01

Highlights: • Zero-dimensional EGR model for transient diesel combustion control. • Detailed analysis of EGR effects on intake, cylinder charge and exhaust properties. • Intake oxygen validated as an operating condition-independent measure of EGR. • Quantified EGR effectiveness in terms of NOx emission reduction. • Twin lambda sensor technique for estimation of EGR/in-cylinder parameters. - Abstract: The application of exhaust gas recirculation (EGR) during transient engine operation is a challenging task since small fluctuations in EGR may cause larger than acceptable spikes in NOx/soot emissions or deterioration in the combustion efficiency. Moreover, the intake charge dilution at any EGR ratio is a function of engine load and intake pressure, and typically changes during transient events. Therefore, the management of EGR during transient engine operation or advanced combustion cycles (that are inherently less stable) requires a fundamental understanding of the transient EGR behaviour and its impact on the intake charge development. In this work, a zero-dimensional EGR model is described to estimate the transient (cycle-by-cycle) progression of EGR and the time (engine cycles) required for its stabilization. The model response is tuned to a multi-cylinder engine by using an overall engine system time-constant and shown to effectively track the transient EGR changes. The impact of EGR on the actual air–fuel ratio of the cylinder charge is quantified by defining an in-cylinder excess-air ratio that accounts for the oxygen in the recycled exhaust gas. Furthermore, a twin lambda sensor (TLS) technique is implemented for tracking the intake dilution and in-cylinder excess-air ratio in real-time. The modelling and analysis results are validated against a wide range of engine operations, including transient and steady-state low temperature combustion tests

Computational analysis of transient gas release from a high pressure vessel

Energy Technology Data Exchange (ETDEWEB)

Pedro, G.; Oshkai, P.; Djilali, N. [Victoria Univ., BC (Canada). Inst. for Integrated Energy Systems; Penau, F. [CERAM Euro-American Inst. of Technology, Sophia Antipolis (France)

2006-07-01

Gas jets exiting from compressed vessels can undergo several regimes as the pressure in the vessel decreases, and a greater understanding of the characteristics of gas jets is needed to determine safety requirements in the transport, distribution, and use of hydrogen. This paper provided a study of the bow shock waves that typically occur during the initial stage of a gas jet incident. The transient behaviour of an initiated jet was investigated using unsteady, compressible flow simulations. The gas was considered to be ideal, and the domain was considered to be axisymmetric. Tank pressure for the analysis was set at a value of 100 atm. Jet structure was examined, as well as the shock structures and separation due to adverse pressure gradients at the nozzle. Shock structure displacement was also characterized.

Chemical composition, secondary metabolites, in vitro gas ...

African Journals Online (AJOL)

Chemical composition, secondary metabolites, in vitro gas production characteristics and acceptability study of some forage for ruminant feeding in South-Western Nigeria. ... Chemical composition and qualitative analysis of saponins, phenol and steroids of the plants were determined. In vitro gas production (IVGP) was ...

Development of Polymethylmethacrylate Based Composite for Gas Sensing Application

Directory of Open Access Journals (Sweden)

S. Devikala

2011-01-01

Full Text Available Gas detection instruments are increasingly needed for industrial health and safety, environmental monitoring and process control. Conductive polymer composites have various industrial applications. The composite prepared by mixing carbon black with polymethylmethacrylate (PMMA has very good gas sensing applications. The gas sensors based on carbon nanotube/polymer, ceramic and metal oxide composites such as epoxy, polyimide, PMMA / Barium titanate and tin oxide have also been developed. In the present work, a new composite has been prepared by using PMMA and ammonium dihydrogen phosphate (ADP. The PMMA/Ammonium dihydrogen phosphate (PMADP composites PMADP 1 and PMADP 2 were characterized by using Powder XRD. The thick films of the composite on glass plates were prepared by using a spin coating unit at 9000 rpm. The application of the thick film as gas sensor has been studied between 0 and 2000 seconds. The results reveal that the thick film of PMADP composite can function as a very good gas sensor.

IFPE/RISOE-II, Fuel Performance Data from Transient Fission Gas Release

International Nuclear Information System (INIS)

Turnbull, J.A.

1995-01-01

Description: The RISO National Laboratory in Denmark have carried out three irradiation programs of slow ramp and hold tests, so called 'bump tests' to investigate fission gas release and fuel microstructural changes. The second project took place between 1982 and 1986 and was called 'The RISO Transient Fission Gas Project'. The fuel used in the project was from: IFA-161 irradiated in the Halden BWR (27 to 42 MWd/kgUO 2 ) and GE BWR fuel irradiated in the Millstone 1 reactor 14 to 29 MWd/kgUO 2 . Using the re-fabrication technique, it was possible to back fill the test segment with a choice of gas and gas pressure and to measure the time dependence of fission gas release by continuous monitoring of the plenum pressure. The short length of the test segment was an advantage because, depending on where along the original rod the section was taken, burnup could be chosen variable, and during the test the fuel experienced a single power

An integrated transient model for simulating the operation of natural gas transport systems

NARCIS (Netherlands)

Pambour, Kwabena Addo; Bolado-Lavin, Ricardo; Dijkema, Gerard P. J.

This paper presents an integrated transient hydraulic model that describes the dynamic behavior of natural gas transport systems (GTS). The model includes sub models of the most important facilities comprising a GTS, such as pipelines, compressor stations, pressure reduction stations, underground

Research on Model-Based Fault Diagnosis for a Gas Turbine Based on Transient Performance

Directory of Open Access Journals (Sweden)

Detang Zeng

2018-01-01

Full Text Available It is essential to monitor and to diagnose faults in rotating machinery with a high thrust–weight ratio and complex structure for a variety of industrial applications, for which reliable signal measurements are required. However, the measured values consist of the true values of the parameters, the inertia of measurements, random errors and systematic errors. Such signals cannot reflect the true performance state and the health state of rotating machinery accurately. High-quality, steady-state measurements are necessary for most current diagnostic methods. Unfortunately, it is hard to obtain these kinds of measurements for most rotating machinery. Diagnosis based on transient performance is a useful tool that can potentially solve this problem. A model-based fault diagnosis method for gas turbines based on transient performance is proposed in this paper. The fault diagnosis consists of a dynamic simulation model, a diagnostic scheme, and an optimization algorithm. A high-accuracy, nonlinear, dynamic gas turbine model using a modular modeling method is presented that involves thermophysical properties, a component characteristic chart, and system inertial. The startup process is simulated using this model. The consistency between the simulation results and the field operation data shows the validity of the model and the advantages of transient accumulated deviation. In addition, a diagnostic scheme is designed to fulfill this process. Finally, cuckoo search is selected to solve the optimization problem in fault diagnosis. Comparative diagnostic results for a gas turbine before and after washing indicate the improved effectiveness and accuracy of the proposed method of using data from transient processes, compared with traditional methods using data from the steady state.

CATHARE simulation of transients for the 2400 MW gas fast reactor concept

International Nuclear Information System (INIS)

Bentivoglio, Fabrice; Messie, Anne; Geffraye, Genevieve; Malo, Jean-Yves; Bertrand, Frederic; Plancq, David

2009-01-01

The Gas cooled Fast Reactor (GFR) is one of the six reactor concepts selected in the framework of the Generation IV forum and a high priority in the French Commissariat a l'Energie Atomique (CEA) R and D program on the Future Nuclear Energy Systems. A first design of this GFR2400 reactor has been completed by the CEA at the end of year 2005. The main characteristics of the concept are a 2400MW core based on plate type fuel elements, with an inlet temperature of 400degC and an outlet temperature of 850degC. The power conversion system is based on an indirect combined cycle with helium on the primary circuit, a Brayton cycle with a mixture of nitrogen and helium on the secondary circuit and a steam cycle on the tertiary circuit. In accidental situations, the use of the gas coolant circulation as the main way to remove the decay heat has been selected. A specific system (DHR system) has been designed: it consists of three loops (3 * 100% redundancy) in extension of the pressure vessel, equipped with heat exchangers and blowers. Between 2006 and 2007 a pre-conceptual study has been achieve, leading to the CEA milestone project of the 'GFR viability' at the end of year 2007. In the frame of this milestone, a wide range of CATHARE2 transients has been achieved to consolidate and improve the decay heat removal strategy; in particular the DHR blowers working on a large pressure range and the use of natural convection as a second way to remove decay heat. The paper first presents the CATHARE2 code applied to gas cooled reactor, focusing on the dedicated features included in the standard option of the code in order to obtain a multi-fluid reliable and performing tool. Then the modeling of the GFR2400 is presented, including the core, the vessel, the primary and secondary circuit with the turbo-machine, and a simplified tertiary circuit with boundary conditions. The decay heat removal loops (DHR loop) are also modeled, with a first circuit in helium and a secondary circuit in

A simulation model for transient response of a gas separation module using a hollow fiber membrane

Energy Technology Data Exchange (ETDEWEB)

Sugiyama, Takahiko, E-mail: t-sugiyama@nucl.nagoya-u.ac.jp [Nagoya University, Fro-cho, Chikusa-ku, Nagoya 464-8603 (Japan); Miyahara, Naoya [Nagoya University, Fro-cho, Chikusa-ku, Nagoya 464-8603 (Japan); Tanaka, Masahiro [National Institute for Fusion Science, Oroshi-cho 322-6, Toki 509-5292 (Japan); Munakata, Kenzo [Akita University, Tegata Gakuen-cho 1-1, Akita-shi, Akita 010-8502 (Japan); Yamamoto, Ichiro [Nagoya University, Fro-cho, Chikusa-ku, Nagoya 464-8603 (Japan)

2011-10-15

A simulation model has been developed for transient response of a gas separation module using a hollow fiber membrane for the removal of tritium from the atmosphere of the confinement space. The mass transfer process such as sorption and desorption of gases at the surface of the dense layer and the porous support layer, diffusive transfer in the both layers are treated in the model. Sorption isotherm, mass transfer rate and permeance are estimated through step-wise transient response experiments. The present model represents well not only separation factors and recovery ratio at the steady state but also responses to the multi-step wise change in the sweep gas rate.

Development of Polymethylmethacrylate Based Composite for Gas Sensing Application

OpenAIRE

Devikala, S.; Kamaraj, P.

2011-01-01

Gas detection instruments are increasingly needed for industrial health and safety, environmental monitoring and process control. Conductive polymer composites have various industrial applications. The composite prepared by mixing carbon black with polymethylmethacrylate (PMMA) has very good gas sensing applications. The gas sensors based on carbon nanotube/polymer, ceramic and metal oxide composites such as epoxy, polyimide, PMMA / Barium titanate and tin oxide have also been developed. In t...

Numerical Calculation of Transient Thermal Characteristics in Gas-Insulated Transmission Lines

Directory of Open Access Journals (Sweden)

Hongtao Li

2013-11-01

Full Text Available For further knowledge of the thermal characteristics in gas-insulated transmission lines (GILs installed above ground, a finite-element model coupling fluid field and thermal field is established, in which the corresponding assumptions and boundary conditions are given.  Transient temperature rise processes of the GIL under the conditions of variable ambient temperature, wind velocity and solar radiation are respectively investigated. Equivalent surface convective heat transfer coefficient and heat flux boundary conditions are updated in the analysis process. Unlike the traditional finite element methods (FEM, the variability of the thermal properties with temperature is considered. The calculation results are validated by the tests results reported in the literature. The conclusion provides method and theory basis for the knowledge of transient temperature rise characteristics of GILs in open environment.

Description of a heat transfer model suitable to calculate transient processes of turbocharged diesel engines with one-dimensional gas-dynamic codes

Energy Technology Data Exchange (ETDEWEB)

Galindo, J.; Lujan, J.M.; Serrano, J.R.; Dolz, V. [CMT-Motores Termicos, Universidad Politecnica de Valencia, Valencia (Spain); Guilain, S. [Renault s.a.s., Lardy (France)

2006-01-15

This paper describes a heat transfer model to be implemented in a global engine 1-D gas-dynamic code to calculate reciprocating internal combustion engine performance in steady and transient operations. A trade off between simplicity and accuracy has been looked for, in order to fit with the stated objective. To validate the model, the temperature of the exhaust manifold wall in a high-speed direct injection (HSDI) turbocharged diesel engine has been measured during a full load transient. In addition, an indirect assessment of the exhaust gas temperature during this transient process has been carried out. The results show good agreement between the measured and modelled data with good accuracy to predict the engine performance. A dual-walled air gap exhaust manifold has been tested in order to quantify the potential of exhaust gas thermal energy saving on engine transient performance. The experimental results together with the heat transfer model have been used to analyse the influence of thermal energy saving on dynamic performance during the load transient of an HSDI turbocharged diesel engine. (author)

Theoretical and experimental studies on transient heat transfer for forced convection flow of helium gas over a horizontal cylinder

International Nuclear Information System (INIS)

Liu Qiusheng; Katsuya Fukuda; Zhang Zheng

2005-01-01

Forced convection transient heat transfer for helium gas at various periods of exponential increase of heat input to a horizontal cylinder (heater) was theoretically and experimentally studied. In the theoretical study, transient heat transfer was numerically solved based on a turbulent flow model. It was clarified that the surface superheat and heat flux increase exponentially as the heat generation rate increases with the exponential function. The temperature distribution near the cylinder becomes larger as the surface temperature increases. The values of numerical solution for surface temperature and heat flux agree well with the experimental data for the cylinder diameter of 1 mm. However, the heat flux shows difference from the experimental values for the cylinder diameters of 0.7 mm and 2.0 mm. In the experimental studies, the authors measured heat flux, surface temperature, and transient heat transfer coefficients for forced convection flow of helium gas over horizontal cylinders under wide experimental conditions. The platinum cylinders with diameters of 1.0 mm, 0.7 mm, and 2.0 mm were used as test heaters and heated by electric current with an exponential increase of Q 0exp (t/τ) . The gas flow velocities ranged from 2 to 10 m/s, the gas temperatures ranged from 303 to 353 K, and the periods ranged from 50 ms to 20 s. It was clarified that the heat transfer coefficient approaches the quasi-steady-state one for the period τ longer than about 1 s, and it becomes higher for the period shorter than around 1 s. The transient heat transfer shows less dependence on the gas flowing velocity when the period becomes very shorter. The heat transfer shifts to the quasi-steady-state heat transfer for longer periods and shifts to the transient heat transfer for shorter periods at the same flow velocity. It also approaches the quasi-steady-state one for higher flow velocity at the same period. The transient heat transfer coefficients show significant dependence on

Transient Analysis and Design Improvement of a Gas Turbine Rotor Based on Thermal-Mechanical Method

Directory of Open Access Journals (Sweden)

Yang Liu

2018-01-01

Full Text Available The rotor is the core component of a gas turbine, and more than 80% of the failures in gas turbines occur in the rotor system, especially during the start-up period. Therefore, the safety assessment of the rotor during the start-up period is essential for the design of the gas turbine. In this paper, the transient equivalent stress of a gas turbine rotor under the cold start-up condition is investigated and the novel tie rod structure is introduced to reduce the equivalent stress. Firstly, a three-dimensional finite element model of the gas turbine rotor is built, and nonlinear contact behaviors such as friction are taken into account. Secondly, the convective heat transfer coefficients of the gas turbine rotor under the cold start-up condition are calculated using thermal dynamic theory. The transient analysis of the gas turbine rotor is conducted considering the thermal load, the centrifugal load, and the pretightening force. The temperature and stress distributions of the rotor under the cold start-up condition are shown in detail. In particular, the generation mechanism of maximum equivalent stress for tie rods and the change tendency of the pretightening force are illustrated in detail. The tie rod holes of the rear shaft and the turbine tie rod are the dangerous locations during the start-up period. Finally, a novel tie rod is proposed to reduce the maximum equivalent stress at the dangerous location. The maximum equivalent stress at this location is decreased by 15%. This paper provides some reference for the design of the gas turbine rotor.

30 CFR 36.26 - Composition of exhaust gas.

Science.gov (United States)

2010-07-01

... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Composition of exhaust gas. 36.26 Section 36.26... EQUIPMENT Construction and Design Requirements § 36.26 Composition of exhaust gas. (a) Preliminary engine... methane) is a satisfactory substitute for pure methane in these tests. (c) Coupling or adapter. The...

Analyzing transient closed chamber effects on canopy gas exchange for optimizing flux calculation timing

NARCIS (Netherlands)

Langensiepen, M.; Kupisch, M.; Wijk, van M.T.; Ewert, F.

2012-01-01

Transient type canopy chambers are still the only currently available practical solution for rapid screening of gas-exchange in agricultural fields. The technique has been criticized for its effect on canopy microclimate during measurement which affects the transport regime and regulation of plant

Compositional Abstraction of PEPA Models for Transient Analysis

DEFF Research Database (Denmark)

Smith, Michael James Andrew

2010-01-01

- or interval - Markov chains allow us to aggregate states in such a way as to safely bound transient probabilities of the original Markov chain. Whilst we can apply this technique directly to a PEPA model, it requires us to obtain the CTMC of the model, whose state space may be too large to construct......Stochastic process algebras such as PEPA allow complex stochastic models to be described in a compositional way, but this leads to state space explosion problems. To combat this, there has been a great deal of work in developing techniques for abstracting Markov chains. In particular, abstract...

Geometrically nonlinear transient vibrations of actively damped anti-symmetric angle ply laminated composite shallow shell using active fibre composite (AFC) actuators

Science.gov (United States)

Ashok, M. H.; Shivakumar, J.; Nandurkar, Santosh; Khadakbhavi, Vishwanath; Pujari, Sanjay

2018-02-01

In present work, the thin laminated composite shallow shell as smart structure with AFC material’s ACLD treatment is analyzed for geometrically nonlinear transient vibrations. The AFC material is used to make the constraining layer of the ACLD treatment. Golla-Hughes-McTavish (GHM) is used to model the constrained viscoelastic layer of the ACLD treatment in time domain. Along with a simple first-order shear deformation theory the Von Kármán type non-linear strain displacement relations are used for deriving this electromechanical coupled problem. A 3-dimensional finite element model of smart composite panels integrated with the ACLD treated patches has been modelled to reveal the performance of ACLD treated patches on improving the damping properties of slender anti-symmetric angle-ply laminated shallow shell, in controlling the transient vibrations which are geometrically nonlinear. The mathematical results explain that the ACLD treated patches considerably enhance the damping properties of anti-symmetric angle-ply panels undergoing geometrically nonlinear transient vibrations.

Fuel composition effect on cathode airflow control in fuel cell gas turbine hybrid systems

Science.gov (United States)

Zhou, Nana; Zaccaria, Valentina; Tucker, David

2018-04-01

Cathode airflow regulation is considered an effective means for thermal management in solid oxide fuel cell gas turbine (SOFC-GT) hybrid system. However, performance and controllability are observed to vary significantly with different fuel compositions. Because a complete system characterization with any possible fuel composition is not feasible, the need arises for robust controllers. The sufficiency of robust control is dictated by the effective change of operating state given the new composition used. It is possible that controller response could become unstable without a change in the gains from one state to the other. In this paper, cathode airflow transients are analyzed in a SOFC-GT system using syngas as fuel composition, comparing with previous work which used humidified hydrogen. Transfer functions are developed to map the relationship between the airflow bypass and several key variables. The impact of fuel composition on system control is quantified by evaluating the difference between gains and poles in transfer functions. Significant variations in the gains and the poles, more than 20% in most cases, are found in turbine rotational speed and cathode airflow. The results of this work provide a guideline for the development of future control strategies to face fuel composition changes.

Predicting dermal absorption of gas-phase chemicals: transient model development, evaluation, and application

DEFF Research Database (Denmark)

Gong, M.; Zhang, Y.; Weschler, Charles J.

2014-01-01

A transient model is developed to predict dermal absorption of gas-phase chemicals via direct air-to-skin-to-blood transport under non-steady-state conditions. It differs from published models in that it considers convective mass-transfer resistance in the boundary layer of air adjacent to the skin....... Results calculated with this transient model are in good agreement with the limited experimental results that are available for comparison. The sensitivity of the modeled estimates to key parameters is examined. The model is then used to estimate air-to-skin-to-blood absorption of six phthalate esters...... and less absorbed into blood than would a steady-state model. In the 7-day scenario, results calculated by the transient and steady-state models converge over a time period that varies between 3 and 4days for all but the largest phthalate (DEHP). Dermal intake is comparable to or larger than inhalation...

Comparison of a fission-gas effects in a transient overpower test (HUT 5-7A) to FRAS3 code predictions

International Nuclear Information System (INIS)

Gruber, E.E.; Randklev, E.H.

1979-01-01

Fission gas has an important bearing on fuel dynamics during reactor transients. Fission-gas bubble sizes and densities, both within grains and on grain boundaries, are characterized as functions of radial location at the axial midplane in studies of PNL-9 fuel microstructures before and after the HUT 5-7A (PNL 9-25) TREAT test. The FRAS3 code, being developed to model fission-gas effects in reactor transients, is applied to analyze the results of the HUT 5-7A test are presented to illustrate the observed phenomena and the validity of the modeling approach

Static Tensile and Transient Dynamic Response of Cracked Aluminum Plate Repaired with Composite Patch - Numerical Study

Science.gov (United States)

Khalili, S. M. R.; Shariyat, M.; Mokhtari, M.

2014-06-01

In this study, the central cracked aluminum plates repaired with two sided composite patches are investigated numerically for their response to static tensile and transient dynamic loadings. Contour integral method is used to define and evaluate the stress intensity factors at the crack tips. The reinforcement for the composite patches is carbon fibers. The effect of adhesive thickness and patch thickness and configuration in tensile loading case and pre-tension, pre-compression and crack length effect on the evolution of the mode I stress intensity factor (SIF) (KI) of the repaired structure under transient dynamic loading case are examined. The results indicated that KI of the central cracked plate is reduced by 1/10 to 1/2 as a result of the bonded composite patch repair in tensile loading case. The crack length and the pre-loads are more effective in repaired structure in transient dynamic loading case in which, the 100 N pre-compression reduces the maximum KI for about 40 %, and the 100 N pre-tension reduces the maximum KI after loading period, by about 196 %.

Modeling the transient security constraints of natural gas network in day-ahead power system scheduling

DEFF Research Database (Denmark)

Yang, Jingwei; Zhang, Ning; Kang, Chongqing

2017-01-01

The rapid deployment of gas-fired generating units makes the power system more vulnerable to failures in the natural gas system. To reduce the risk of gas system failure and to guarantee the security of power system operation, it is necessary to take the security constraints of natural gas...... accurately, they are hard to be embedded into the power system scheduling model, which consists of algebraic equations and inequations. This paper addresses this dilemma by proposing an algebraic transient model of natural gas network which is similar to the branch-node model of power network. Based...... pipelines into account in the day-ahead power generation scheduling model. However, the minute- and hour-level dynamic characteristics of gas systems prevents an accurate decision-making simply with the steady-state gas flow model. Although the partial differential equations depict the dynamics of gas flow...

Modeling steady state and transient fission gas behaviour with the Karlsruhe code LAKU

International Nuclear Information System (INIS)

Vaeth, L.

1984-08-01

The programme LAKU models the behaviour of gaseous fission products in reactor fuel under steady state and transient conditions, including molten fuel. A presentation of the full model is given, starting with gas behaviour in the grains and on grain faces and including the treatment of release from porosity. The results of some recent calculations are presented. (orig.) [de

Interactive simulations of gas-turbine modular HTGR transients and heatup accidents

International Nuclear Information System (INIS)

Ball, S.J.; Nypaver, D.J.

1994-01-01

An interactive workstation-based simulator has been developed for performing analyses of modular high-temperature gas-cooled reactor (MHTGR) core transients and accidents. It was originally developed at Oak Ridge National Laboratory for the US Nuclear Regulatory Commission to assess the licensability of the US Department of Energy (DOE) steam cycle design 350-MW(t) MHTGR. Subsequently, the code was modified under DOE sponsorship to simulate the 450-MW(t) Gas Turbine (GT) design and to aid in development and design studies. Features of the code (MORECA-GT) include detailed modeling of 3-D core thermal-hydraulics, interactive workstation capabilities that allow user/analyst or ''operator'' involvement in accident scenarios, and options for studying anticipated transients without scram (ATWS) events. In addition to the detailed models for the core, MORECA includes models for the vessel, Shutdown Cooling System (SCS), and Reactor Cavity Cooling System (RCCS), and core point kinetics to accommodate ATWS events. The balance of plant (BOP) is currently not modeled. The interactive workstation features include options for on-line parameter plots and 3-D graphic temperature profiling. The studies to date show that the proposed MHTGR designs are very robust and can generally withstand the consequences of even the extremely low probability postulated accidents with little or no damage to the reactor's fuel or metallic components

Interactive simulations of gas-turbine modular HTGR transients and heatup accidents

Energy Technology Data Exchange (ETDEWEB)

Ball, S.J.; Nypaver, D.J.

1994-06-01

An interactive workstation-based simulator has been developed for performing analyses of modular high-temperature gas-cooled reactor (MHTGR) core transients and accidents. It was originally developed at Oak Ridge National Laboratory for the US Nuclear Regulatory Commission to assess the licensability of the US Department of Energy (DOE) steam cycle design 350-MW(t) MHTGR. Subsequently, the code was modified under DOE sponsorship to simulate the 450-MW(t) Gas Turbine (GT) design and to aid in development and design studies. Features of the code (MORECA-GT) include detailed modeling of 3-D core thermal-hydraulics, interactive workstation capabilities that allow user/analyst or ``operator`` involvement in accident scenarios, and options for studying anticipated transients without scram (ATWS) events. In addition to the detailed models for the core, MORECA includes models for the vessel, Shutdown Cooling System (SCS), and Reactor Cavity Cooling System (RCCS), and core point kinetics to accommodate ATWS events. The balance of plant (BOP) is currently not modeled. The interactive workstation features include options for on-line parameter plots and 3-D graphic temperature profiling. The studies to date show that the proposed MHTGR designs are very robust and can generally withstand the consequences of even the extremely low probability postulated accidents with little or no damage to the reactor`s fuel or metallic components.

Performance analysis of smart laminated composite plate integrated with distributed AFC material undergoing geometrically nonlinear transient vibrations

Science.gov (United States)

Shivakumar, J.; Ashok, M. H.; Khadakbhavi, Vishwanath; Pujari, Sanjay; Nandurkar, Santosh

2018-02-01

The present work focuses on geometrically nonlinear transient analysis of laminated smart composite plates integrated with the patches of Active fiber composites (AFC) using Active constrained layer damping (ACLD) as the distributed actuators. The analysis has been carried out using generalised energy based finite element model. The coupled electromechanical finite element model is derived using Von Karman type nonlinear strain displacement relations and a first-order shear deformation theory (FSDT). Eight-node iso-parametric serendipity elements are used for discretization of the overall plate integrated with AFC patch material. The viscoelastic constrained layer is modelled using GHM method. The numerical results shows the improvement in the active damping characteristics of the laminated composite plates over the passive damping for suppressing the geometrically nonlinear transient vibrations of laminated composite plates with AFC as patch material.

Increasing the computational speed of flash calculations with applications for compositional, transient simulations

DEFF Research Database (Denmark)

Rasmussen, Claus P.; Krejbjerg, Kristian; Michelsen, Michael Locht

2006-01-01

Approaches are presented for reducing the computation time spent on flash calculations in compositional, transient simulations. In a conventional flash calculation, the majority of the simulation time is spent on stability analysis, even for systems far into the single-phase region. A criterion has...

30 CFR 36.43 - Determination of exhaust-gas composition.

Science.gov (United States)

2010-07-01

... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Determination of exhaust-gas composition. 36.43... TRANSPORTATION EQUIPMENT Test Requirements § 36.43 Determination of exhaust-gas composition. (a) Samples shall be..., hydrogen, methane, nitrogen, oxides of nitrogen, and aldehydes, or any other constituent prescribed by MSHA...

Improved lumped models for transient combined convective and radiative cooling of multi-layer composite slabs

International Nuclear Information System (INIS)

An Chen; Su Jian

2011-01-01

Improved lumped parameter models were developed for the transient heat conduction in multi-layer composite slabs subjected to combined convective and radiative cooling. The improved lumped models were obtained through two-point Hermite approximations for integrals. Transient combined convective and radiative cooling of three-layer composite slabs was analyzed to illustrate the applicability of the proposed lumped models, with respect to different values of the Biot numbers, the radiation-conduction parameter, the dimensionless thermal contact resistances, the dimensionless thickness, and the dimensionless thermal conductivity. It was shown by comparison with numerical solution of the original distributed parameter model that the higher order lumped model (H 1,1 /H 0,0 approximation) yielded significant improvement of average temperature prediction over the classical lumped model. In addition, the higher order (H 1,1 /H 0,0 ) model was applied to analyze the transient heat conduction problem of steel-concrete-steel sandwich plates. - Highlights: → Improved lumped models for convective-radiative cooling of multi-layer slabs were developed. → Two-point Hermite approximations for integrals were employed. → Significant improvement over classical lumped model was achieved. → The model can be applied to high Biot number and high radiation-conduction parameter. → Transient heat conduction in steel-concrete-steel sandwich pipes was analyzed as an example.

Transient effects caused by pulsed gas and liquid injections into low pressure plasmas

International Nuclear Information System (INIS)

Ogawa, D; Goeckner, M; Overzet, L; Chung, C W

2010-01-01

The fast injection of liquid droplets into a glow discharge causes significant time variations in the pressure, the chemical composition of the gas and the phases present (liquid and/or solid along with gas). While the variations can be large and important, very few studies, especially kinetic studies, have been published. In this paper we examine the changes brought about in argon plasma by injecting Ar (gas), N 2 (gas) hexane (gas) and hexane (liquid droplets). The changes in the RF capacitively coupled power (forward and reflected), electron and ion density (n e , n i ), electron temperature (T e ) and optical emissions were monitored during the injections. It was found that the Ar injection (pressure change only) caused expected variations. The electron temperature reduced, the plasma density increased and the optical emission intensity remained nearly constant. The N 2 and hexane gas injections (chemical composition and pressure changes) also followed expected trends. The plasma densities increased and electron temperature decreased while the optical emissions changed from argon to the injected gas. These all serve to highlight the fact that the injection of evaporating hexane droplets in the plasma caused very little change. This is because the number of injected droplets is too small to noticeably affect the plasma, even though the shift in the chemical composition of the gas caused by evaporation from those same droplets can be very significant. The net conclusion is that using liquid droplets to inject precursors for low pressure plasmas is both feasible and controllable.

Computational Analysis of Effect of Transient Fluid Force on Composite Structures

Science.gov (United States)

2013-12-01

as they well represent an E-glass fiber reinforced composite frequently used in research and industrial applications. The fluid domain was sized...provide unique perspectives on peak stress ratios . The two models both share increased structural rigidity. The cylinder is reinforced by... Poisson ratio of 0.3 and Young’s modulus of 20 GPa were added to the transient structural engineering data cell (Figure 69). 78 Figure 69. E-Glass

Nodalization Preparation for the Transient Simulation of Cooling System for One Line Mode of RSG-GAS

International Nuclear Information System (INIS)

Sukmanto Dibyo; Susyadi; Tagor MS; Darwis Isnaeni

2004-01-01

Cooling system is important component in RSG-GAS. To carry out the transient simulation of one line-cooling mode, the model of RSG-GAS has been prepared. To illustrate the transient condition, the RELAP5.MOD3 computer code the existing input files were used. This Input consist of kinetic, thermal, hydraulic and geometries data. Modification and decrement of number of nodalization has been done to simplification as well as running time. The reasonable result of model is arranged to determine the initial condition of input data therefore steady state condition have agreement to the analysis result of one line cooling mode of RSG-GAS. Parameter investigated are transient temperatures of cooling system after decreasing of secondary cooling system occur as function of time. These parameters can be requested using input of Minor Edit Request Simulation is conducted at the reactor power of 15 MW steady-state for one-line cooling mode in which the primary and secondary cooling of 430 kg/sec and 550 kg/sec respectively. Decreasing of secondary cooling flow is caused by pump trip. As a consequence, the control rod drop due to reactor protection system. The negative reactivity of control rod causes decreasing of reactor power. Change of pattern for the primary and secondary cooling system can be known. After that simulation depicts that increasing of temperatures occur at the certain moment since initiation temperature conditions, due to reactor shut down, curve inclined move going down. (author)

Fission gas behavior during fast thermal transients

International Nuclear Information System (INIS)

Esteves, R.G.

1976-01-01

The behavior of non-equilibrium fission in fuel elements undergoing fast thermal transients is analyzed. To facilitate the analysis, a new variable, the equilibrium variable (EV) is defined. This variable, together with bubble radius, completely specifies a bubble with respect to its size and equilibrium condition. The analysis is coded using a two-variable (radius and EV) multigroup numerical approximation that accepts as input the time-temperature history, the time-fission rate history, and the time-thermal gradient history of the fuel element. Studies were performed to test the code for convergence with respect to the time interval and the number of groups chosen. For a series of transient simulation studies, the measurements obtained at HEDL (microscopic examination of intragranular porosity in oxide fuel transient-tested in TREAT) are used. Two different transient histories were selected; the first, a high-temperature transient (HTT) with a peak at 2477 0 K and the second, a low-temperature transient (LTT) with a peak-temperature at 2000 0 K. The LTT was simulated for three different conditions: Bubbles were allowed to move via (a) only biased migration, (b) via random migration, and (c) via both mechanisms. The HTT was also run for both mechanisms. The agreement with HEDL microscopic observations was fair for bubbles smaller than 964 A in diameter, and poor for larger bubbles. Bubbles that grew during the heat-up part of the transient were frozen at a larger size during the cool down

Modelling the transient behaviour of pulsed current tungsten-inert-gas weldpools

Science.gov (United States)

Wu, C. S.; Zheng, W.; Wu, L.

1999-01-01

A three-dimensional model is established to simulate the pulsed current tungsten-inert-gas (TIG) welding process. The goal is to analyse the cyclic variation of fluid flow and heat transfer in weldpools under periodic arc heat input. To this end, an algorithm, which is capable of handling the transience, nonlinearity, multiphase and strong coupling encountered in this work, is developed. The numerical simulations demonstrate the transient behaviour of weldpools under pulsed current. Experimental data are compared with numerical results to show the effectiveness of the developed model.

High efficient ethanol and VFAs production from gas fermentation: effect of acetate, gas and inoculum microbial composition

DEFF Research Database (Denmark)

El-Gammal, Maie; Abou-Shanab, Reda; Angelidaki, Irini

2017-01-01

In bioindustry, syngas fermentation is a promising technology for biofuel production without the use of plant biomass as sugar-based feedstock. The aim of this study was to identify optimal conditions for high efficient ethanol and volatile fatty acids (VFA) production from synthetic gas fermenta......In bioindustry, syngas fermentation is a promising technology for biofuel production without the use of plant biomass as sugar-based feedstock. The aim of this study was to identify optimal conditions for high efficient ethanol and volatile fatty acids (VFA) production from synthetic gas...... fatty acids and ethanol was achieved by the pure culture (Clostridium ragsdalei). Depending on the headspace gas composition, VFA concentrations were up to 300% higher after fermentation with Clostridium ragsdalei compared to fermentation with mixed culture. The preferred gas composition with respect...... to highest VFA concentration was pure CO (100%) regardless of microbial composition of the inoculum and media composition. The addition of acetate had a negative impact on the VFA formation which was depending on the initial gas composition in head space....

Online gas composition estimation in solid oxide fuel cell systems with anode off-gas recycle configuration

Science.gov (United States)

Dolenc, B.; Vrečko, D.; Juričić, Ð.; Pohjoranta, A.; Pianese, C.

2017-03-01

Degradation and poisoning of solid oxide fuel cell (SOFC) stacks are continuously shortening the lifespan of SOFC systems. Poisoning mechanisms, such as carbon deposition, form a coating layer, hence rapidly decreasing the efficiency of the fuel cells. Gas composition of inlet gases is known to have great impact on the rate of coke formation. Therefore, monitoring of these variables can be of great benefit for overall management of SOFCs. Although measuring the gas composition of the gas stream is feasible, it is too costly for commercial applications. This paper proposes three distinct approaches for the design of gas composition estimators of an SOFC system in anode off-gas recycle configuration which are (i.) accurate, and (ii.) easy to implement on a programmable logic controller. Firstly, a classical approach is briefly revisited and problems related to implementation complexity are discussed. Secondly, the model is simplified and adapted for easy implementation. Further, an alternative data-driven approach for gas composition estimation is developed. Finally, a hybrid estimator employing experimental data and 1st-principles is proposed. Despite the structural simplicity of the estimators, the experimental validation shows a high precision for all of the approaches. Experimental validation is performed on a 10 kW SOFC system.

Analysis on blow-down transient in water ingress accident of high temperature gas-cooled reactor

International Nuclear Information System (INIS)

Wang, Yan; Zheng, Yanhua; Li, Fu; Shi, Lei

2014-01-01

Water ingress into the primary circuit is generally recognized as one of the severe accidents with potential hazard to the modular high temperature gas-cooled reactor, which will cause a positive reactivity introduction with the increase of steam density in reactor core to enhance neutron slowing-down, also the chemical corrosion of graphite fuel elements and the damage of reflector structure material. The increase of the primary pressure may result in the opening of the safety valves, consequently leading the release of radioactive isotopes and flammable water gas. The research on water ingress transient is significant for the verification of inherent safety characteristics of high temperature gas-cooled reactor. The 200 MWe high temperature gas-cooled reactor (HTR-PM), designed by the Institute of Nuclear and New Energy Technology of Tsinghua University, is exampled to be analyzed in this paper. The design basis accident (DBA) scenarios of double-ended guillotine break of single heat-exchange tube (steam generator heat-exchange tube rupture) are simulated by the thermal-hydraulic analysis code, and some key concerns which are relative to the amount of water into the reactor core during the blow-down transient are analyzed in detail. The results show that both of water mass and steam ratio of the fluid spouting from the broken heat-exchange tube are affected by break location, which will increase obviously with the broken location closing to the outlet of the heat-exchange tube. The double-ended guillotine rupture at the outlet of the heat-exchange will result more steam penetrates into the reactor core in the design basis accident of water ingress. The mass of water ingress will also be affected by the draining system. It is concluded that, with reasonable optimization on design to balance safety and economy, the total mass of water ingress into the primary circuit of reactor could be limited effectively to meet the safety requirements, and the pollution of

An Analytical Solution for Transient Heat Conduction in a Composite Slab with Time-Dependent Heat Transfer Coefficient

Directory of Open Access Journals (Sweden)

Ryoichi Chiba

2018-01-01

Full Text Available An analytical solution is derived for one-dimensional transient heat conduction in a composite slab consisting of n layers, whose heat transfer coefficient on an external boundary is an arbitrary function of time. The composite slab, which has thermal contact resistance at n-1 interfaces, as well as an arbitrary initial temperature distribution and internal heat generation, convectively exchanges heat at the external boundaries with two different time-varying surroundings. To obtain the analytical solution, the shifting function method is first used, which yields new partial differential equations under conventional types of external boundary conditions. The solution for the derived differential equations is then obtained by means of an orthogonal expansion technique. Numerical calculations are performed for two composite slabs, whose heat transfer coefficient on the heated surface is either an exponential or a trigonometric function of time. The numerical results demonstrate the effects of temporal variations in the heat transfer coefficient on the transient temperature field of composite slabs.

Simulation of the effects of grain boundary fission gas during thermal transients

International Nuclear Information System (INIS)

Fenske, G.R.; Emerson, J.E.; Beiersdorf, B.A.

1984-11-01

This report presents the results of an initial set of out-of-cell transient heating experiments performed on unirradiated UO 2 pellets fabricated to simulate the effect of grain boundary fission gas on fuel swelling and cladding failure. The fabrication involved trapping high-pressure argon on internal pores by sintering annular UO 2 pellets in a hot isostatic press (HIP). The pellet stack was subjected to two separate transients (DGF83-03A and -03B). Figures show photomicrographs of HIPped and non-HIPped UO 2 , respectively, and the adjacent cladding after DGF83-03B. Fuel melting occurred at the center of both the HIPped and non-HIPped pellets; however, a dark ring is present near the center in the HIPped fuel but not in the non-HIPped fuel. This dark band is a high-porosity region due to increased grain boundary/edge swelling in that pellet. In contrast, grain boundary/edge swelling did not occur in the non-HIPped pellets. Thus, the presence of the high-pressure argon trapped on internal pores during sintering in the HIP altered the microstructural behavior. Results of these preliminary tests indicate that the microstructural behavior of HIPped fuel during thermal transients is different from the behavior of conventionally fabricated fuel

SiC/SiC composites through transient eutectic-phase route for fusion applications

International Nuclear Information System (INIS)

Katoh, Y.; Kohyama, A.; Nozawa, T.; Sato, M.

2004-01-01

Factors that may limit attractiveness of silicon-carbide-based ceramic composites to fusion applications include thermal conductivity, applicable design stress, chemical compatibility, hermeticity, radiation stability and fabrication cost. A novel SiC/SiC composite, which has recently been developed through nano-infiltration and transient eutectic-phase (NITE) processing route, surpasses conventional materials in many of these properties. In this paper, the latest development, property evaluation and prospect of the NITE SiC/SiC composites are briefly reviewed. The topics range from fundamental aspects of process development to industrial process development. Elevated temperature strength, fracture behavior, and thermo-physical properties in various environments are summarized. Future directions of materials and application technology development are also discussed

Transient response simulation of gas separation membrane module for an atmosphere detritiation system

International Nuclear Information System (INIS)

Sugiyama, Takahiko; Tanaka, Masahiro; Munakata, Kenzo; Yamamoto, Ichiro

2012-01-01

Transient response of a gas separation membrane module for the atmosphere detritiation system was numerically simulated with a mass transfer model. The module contains thousands of hollow fiber type polyimide membranes. The simulation model took into account permeation of water vapor through the dense layer of the membrane, diffusive transfer through the porous support layer and adsorption/desorption of water vapor into the matrix of the porous layer. The slow responses of the water vapor concentration in the retentate and the permeation rate were well reproduced by the present simulation, and transient changes in a follow fiber membrane were investigated in detail. The inventory and the mean residence time of water vapor at 303 K were estimated for the commercial membrane module (UMS-B2, Ube industries, Ltd.) as 5.7 × 10 −3 mol and 380 s, respectively.

Acute chlorine gas exposure produces transient inflammation and a progressive alteration in surfactant composition with accompanying mechanical dysfunction

Energy Technology Data Exchange (ETDEWEB)

Massa, Christopher B.; Scott, Pamela; Abramova, Elena; Gardner, Carol; Laskin, Debra L.; Gow, Andrew J., E-mail: Gow@rci.rutgers.edu

2014-07-01

Acute Cl{sub 2} exposure following industrial accidents or military/terrorist activity causes pulmonary injury and severe acute respiratory distress. Prior studies suggest that antioxidant depletion is important in producing dysfunction, however a pathophysiologic mechanism has not been elucidated. We propose that acute Cl{sub 2} inhalation leads to oxidative modification of lung lining fluid, producing surfactant inactivation, inflammation and mechanical respiratory dysfunction at the organ level. C57BL/6J mice underwent whole-body exposure to an effective 60 ppm-hour Cl{sub 2} dose, and were euthanized 3, 24 and 48 h later. Whereas pulmonary architecture and endothelial barrier function were preserved, transient neutrophilia, peaking at 24 h, was noted. Increased expression of ARG1, CCL2, RETLNA, IL-1b, and PTGS2 genes was observed in bronchoalveolar lavage (BAL) cells with peak change in all genes at 24 h. Cl{sub 2} exposure had no effect on NOS2 mRNA or iNOS protein expression, nor on BAL NO{sub 3}{sup −} or NO{sub 2}{sup −}. Expression of the alternative macrophage activation markers, Relm-α and mannose receptor was increased in alveolar macrophages and pulmonary epithelium. Capillary surfactometry demonstrated impaired surfactant function, and altered BAL phospholipid and surfactant protein content following exposure. Organ level respiratory function was assessed by forced oscillation technique at 5 end expiratory pressures. Cl{sub 2} exposure had no significant effect on either airway or tissue resistance. Pulmonary elastance was elevated with time following exposure and demonstrated PEEP refractory derecruitment at 48 h, despite waning inflammation. These data support a role for surfactant inactivation as a physiologic mechanism underlying respiratory dysfunction following Cl{sub 2} inhalation. - Highlights: • Effect of 60 ppm*hr Cl{sub 2} gas on lung inflammation and mechanical function examined. • Pulmonary inflammation is transient and minor. �

An attempt to detect the greenhouse-gas signal in a transient GCM simulation

International Nuclear Information System (INIS)

Barnett, T.P.

1990-01-01

Results from the GISS model forced by transient greenhouse-gas (GHG) increases are used to demonstrate methods of detecting the theoretically predicted GHG signal. The signal predicted to occur in the surface temperature of the world's ocean since 1958 is not found in the observations but this is not surprising since the signal was small in the first place. The main result of the study is to demonstrate many of the key issues/difficulties that attend the detection problem

Dynamics of gas-phase transient species studied by dissociative photodetachment of molecular anions

OpenAIRE

Lu, Zhou

2007-01-01

Gas-phase transient species, such as the CH₃CO₂ and HOCO free radicals, play important roles in combustion and environment chemistry. In this thesis work, the dynamics of these two radicals were studied by dissociative photodetachment (DPD) of the negative ions, CH₃CO₂-С and HOCO⁻, respectively. The experiments were carried out with a fast-ion-beam photoelectron-photofragment coincidence (PPC) spectrometer. Mass-selected molecular anions in a fast ion beam were intercepted by a linearly polar...

Radiolytic and thermolytic bubble gas hydrogen composition

Energy Technology Data Exchange (ETDEWEB)

Woodham, W. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

2017-12-11

This report describes the development of a mathematical model for the estimation of the hydrogen composition of gas bubbles trapped in radioactive waste. The model described herein uses a material balance approach to accurately incorporate the rates of hydrogen generation by a number of physical phenomena and scale the aforementioned rates in a manner that allows calculation of the final hydrogen composition.

Compositional simulations of producing oil-gas ratio behaviour in low permeable gas condensate reservoir

OpenAIRE

Gundersen, Pål Lee

2013-01-01

Master's thesis in Petroleum engineering Gas condensate flow behaviour below the dew point in low permeable formations can make accurate fluid sampling a difficult challenge. The objective of this study was to investigate the producing oil-gas ratio behaviour in the infinite-acting period for a low permeable gas condensate reservoir. Compositional isothermal flow simulations were performed using a single-layer, radial and two-dimensional, gas condensate reservoir model with low permeabili...

Transient thermoreflectance from graphene composites with matrix of indium and copper

Directory of Open Access Journals (Sweden)

H. Zheng

2013-03-01

Full Text Available Transient thermoreflectance was measured from In and In-graphene composite films pressed on to different substrates that include Si, GaAs, Cu and Cu-graphene composite. Measurements were also made from Al film deposited on substrates of Cu and Cu-graphene composite. The experimental results were modeled using solution to the thermal diffusion equation to determine the thermal conductivity of the phases and thermal conductance of the interface. The In-graphene and Cu-graphene composites are found to spread the heat more rapidly than In and Cu, respectively. The interface thermal conductance of In or In-graphene film pressed on to Cu was found to be smaller than the observed values for metal-metal contacts reported in the literature although higher than the value observed for the interface between Pb-Sn eutectic solder alloy bonded to Cu. The interface thermal conductance between Al film deposited on mechanically polished Cu or Cu-graphene composite is also found to be much lower than the value observed previously. The smaller value of interface thermal conductance of either In or In-gr or Al film on different substrates is explained by absence of atomic level bonding, presence of rough surfaces with incomplete contact and oxygen or water vapor at the interface.

Characteristics of stable carbon isotopic composition of shale gas

Directory of Open Access Journals (Sweden)

Zhenya Qu

2016-04-01

Full Text Available A type Ⅱ kerogen with low thermal maturity was adopted to perform hydrocarbon generation pyrolysis experiments in a vacuum (Micro-Scale Sealed Vessel system at the heating rates of 2 °C/h and 20 °C/h. The stable carbon isotopic compositions of gas hydrocarbons were measured to investigate their evolving characteristics and the possible reasons for isotope reversal. The δ13C values of methane became more negative with the increasing pyrolysis temperatures until it reached the lightest point, after which they became more positive. Meanwhile, the δ13C values of ethane and propane showed a positive trend with elevating pyrolysis temperatures. The carbon isotopic compositions of shale gasses were mainly determined by the type of parent organic matter, thermal evolutionary extent, and gas migration in shale systems. Our experiments and study proved that the isotope reversal shouldn't occur in a pure thermogenic gas reservoir, it must be involved with some other geochemical process/es; although mechanisms responsible for the reversal are still vague. Carbon isotopic composition of the Fayetteville and Barnett shale gas demonstrated that the isotope reversal was likely involved with water–gas reaction and Fischer-Tropsch synthesis during its generation.

Patterns of gas and liquid reflux during transient lower oesophageal sphincter relaxation: a study using intraluminal electrical impedance

OpenAIRE

Sifrim, D; Silny, J; Holloway, R; Janssens, J

1999-01-01

Background—Belching has been proposed as a major mechanism underlying acid gastro-oesophageal reflux in normal subjects. However, the presence of oesophageal gas has not been measured directly but only inferred from manometry. 
Aims—To investigate, using intraluminal electrical impedance, the patterns of gas and liquid reflux during transient lower oesophageal sphincter (LOS) relaxations, the main mechanism of acid reflux in normal subjects. 
Methods—Impedance changes ass...

Adaptive polynomial chaos techniques for uncertainty quantification of a gas cooled fast reactor transient

International Nuclear Information System (INIS)

Perko, Z.; Gilli, L.; Lathouwers, D.; Kloosterman, J. L.

2013-01-01

Uncertainty quantification plays an increasingly important role in the nuclear community, especially with the rise of Best Estimate Plus Uncertainty methodologies. Sensitivity analysis, surrogate models, Monte Carlo sampling and several other techniques can be used to propagate input uncertainties. In recent years however polynomial chaos expansion has become a popular alternative providing high accuracy at affordable computational cost. This paper presents such polynomial chaos (PC) methods using adaptive sparse grids and adaptive basis set construction, together with an application to a Gas Cooled Fast Reactor transient. Comparison is made between a new sparse grid algorithm and the traditionally used technique proposed by Gerstner. An adaptive basis construction method is also introduced and is proved to be advantageous both from an accuracy and a computational point of view. As a demonstration the uncertainty quantification of a 50% loss of flow transient in the GFR2400 Gas Cooled Fast Reactor design was performed using the CATHARE code system. The results are compared to direct Monte Carlo sampling and show the superior convergence and high accuracy of the polynomial chaos expansion. Since PC techniques are easy to implement, they can offer an attractive alternative to traditional techniques for the uncertainty quantification of large scale problems. (authors)

Transient optical studies of charge recombination dynamics in a polymer/fullerene composite at room temperature

NARCIS (Netherlands)

Montanari, Ivan; Nogueira, Ana F.; Nelson, Jenny; Durrant, James R.; Winder, Christoph; Loi, Maria Antonietta; Sariciftci, Niyazi Serdar; Brabec, Christoph

2002-01-01

The recombination kinetics of photogenerated charge carriers in a composite of poly[2-methoxy-5-(3',7'-dimethyloctyloxy)-1-4-phenylene vinylene], (MDMO–PPV) and the functionalised fullerene 1-(3-methoxycarbonyl)-propyl-1-phenyl-(6,6)C61 are investigated at room temperature by transient absorption

Development of THYDE-HTGR: computer code for transient thermal-hydraulics of high-temperature gas-cooled reactor

International Nuclear Information System (INIS)

Hirano, Masashi; Hada, Kazuhiko

1990-04-01

The THYDE-HTGR code has been developed for transient thermal-hydraulic analyses of high-temperature gas-cooled reactors, based on the THYDE-W code. THYDE-W is a code developed at JAERI for the simulation of Light Water Reactor plant dynamics during various types of transients including loss-of-coolant accidents. THYDE-HTGR solves the conservation equations of mass, momentum and energy for compressible gas, or single-phase or two-phase flow. The major code modification from THYDE-W is to treat helium loops as well as water loops. In parallel to this, modification has been made for the neutron kinetics to be applicable to helium-cooled graphite-moderated reactors, for the heat transfer models to be applicable to various types of heat exchangers, and so forth. In order to assess the validity of the modifications, analyses of some of the experiments conducted at the High Temperature Test Loop of ERANS have been performed. In this report, the models applied in THYDE-HTGR are described focusing on the present modifications and the results from the assessment calculations are presented. (author)

Summarizing evaluation of the results of in-pile experiments for the transient fission gas release under accidental conditions of fast breeders

International Nuclear Information System (INIS)

Fischer, E.A.; Vaeth, L.

1989-04-01

The transient fission gas behaviour and the fission gas induced fuel motion were studied in in-pile experiments in different countries, under conditions typical for hypothetical accidents. This report summarizes first the different experiment series and the main results. Then, a comparative evaluation is given, which provides a basis for the choice of the fission gas parameters in the accident code SAS3D

Effect of gas release in hot molding on flexural strength of composite friction brake

Science.gov (United States)

Rusdja, Andy Permana; Surojo, Eko; Muhayat, Nurul; Raharjo, Wijang Wisnu

2018-02-01

Composite friction brake is a vital part of braking system which serves to reduce the speed of vehicle. To fulfill the requirement of brake performance, composite friction brake must have friction and mechanical characteristic as required. The characteristics of composite friction brake are affected by brake material formulation and manufacturing parameter. In the beginning of hot molding, intermittent hot pressing was carried out to release the gases that consist of ammonia gas and water vapor. In composite friction brake, phenolic resin containing hexamethylenetetramine (HMTA) is often used as a binder. During hot molding, the reaction of phenolic resin and HMTA forms ammonia gas. Hot molding also generates water vapor because raw materials absorb moisture from environment when they are placed in storage. The gas release in hot molding is supposed affecting mechanical properties because it avoid entrapped gas in composite, so that this research investigated effect of gas release on flexural strength. Manufacturing of composite specimen was carried out as follow: mixing of raw materials, cold molding, and hot molding. In this research, duration of intermittent hot pressing and number of gas release were varied. The flexural strength of specimen was measured using three point bending test. The results showed that flexural strength specimens that were manufactured without gas release, using 4 times gas release with intermittent hot pressing for 5 and 10 seconds were not remarkably different. Conversely, hot molding using 4 times gas release with intermittent hot pressing for 15 seconds decreased flexural strength of composite. Hot molding using 2, 4, and 8 times gas release with intermittent hot pressing for 10 seconds also had no effect on increasing flexural strength. Increasing of flexural strength of composite was obtained only by using 6 times gas release with intermittent hot pressing for 10 seconds.

Gas-core reactor power transient analysis. Final report

International Nuclear Information System (INIS)

Kascak, A.F.

1972-01-01

The gas core reactor is a proposed device which features high temperatures. It has applications in high specific impulse space missions, and possibly in low thermal pollution MHD power plants. The nuclear fuel is a ball of uranium plasma radiating thermal photons as opposed to gamma rays. This thermal energy is picked up before it reaches the solid cavity liner by an inflowing seeded propellant stream and convected out through a rocket nozzle. A wall-burnout condition will exist if there is not enough flow of propellant to convect the energy back into the cavity. A reactor must therefore operate with a certain amount of excess propellant flow. Due to the thermal inertia of the flowing propellant, the reactor can undergo power transients in excess of the steady-state wall burnout power for short periods of time. The objective of the study was to determine how long the wall burnout power could be exceeded without burning out the cavity liner. The model used in the heat-transfer calculation was one-dimensional, and thermal radiation was assumed to be a diffusion process. (auth)

High efficient ethanol and VFAs production from gas fermentation: effect of acetate, gas and inoculum microbial composition

DEFF Research Database (Denmark)

El-Gammal, Maie; Abou-Shanab, Reda; Angelidaki, Irini

2017-01-01

In bioindustry, syngas fermentation is a promising technology for biofuel production without the use of plant biomass as sugar-based feedstock. The aim of this study was to identify optimal conditions for high efficient ethanol and volatile fatty acids (VFA) production from synthetic gas...... fatty acids and ethanol was achieved by the pure culture (Clostridium ragsdalei). Depending on the headspace gas composition, VFA concentrations were up to 300% higher after fermentation with Clostridium ragsdalei compared to fermentation with mixed culture. The preferred gas composition with respect...

Gas composition and isotopic geochemistry of cuttings, core, and gas hydrate from the JAPEX/JNOC/GSC Mallik 2L-38 gas hydrate research well

Science.gov (United States)

Lorenson, T.D.

1999-01-01

Molecular and isotopic composition of gases from the JAPEX/JNOC/GSC Mallik 2L-38 gas hydrate research well demonstrate that the in situ gases can be divided into three zones composed of mixtures of microbial and thermogenic gases. Sediments penetrated by the well are thermally immature; thus the sediments are probably not a source of thermogenic gas. Thermogenic gas likely migrated from depths below 5000 m. Higher concentrations of gas within and beneath the gas hydrate zone suggest that gas hydrate is a partial barrier to gas migration. Gas hydrate accumulations occur wholly within zone 3, below the base of permafrost. The gas in gas hydrate resembles, in part, the thermogenic gas in surrounding sediments and gas desorbed from lignite. Gas hydrate composition implies that the primary gas hydrate form is Structure I. However, Structure II stabilizing gases are more concentrated and isotopically partitioned in gas hydrate relative to the sediment hosting the gas hydrate, implying that Structure II gas hydrate may be present in small quantities.

Method for online measurement of the CHON composition of raw gas from biomass gasifier

International Nuclear Information System (INIS)

Neves, Daniel; Thunman, Henrik; Tarelho, Luís; Larsson, Anton; Seemann, Martin; Matos, Arlindo

2014-01-01

Highlights: • Measuring the CHON composition of a raw gas by current methods is challenging. • An alternative method is to burn the raw gas before measuring the CHON composition. • The CHON contents of the raw gas can be accurately measured by the alternative method. • Measuring the CHON contents of the raw gas is now performed in a “one-step” analysis. • The new method is used to evaluate the operation of a dual fluidised bed gasifier. - Abstract: For unattended biomass gasification processes, rapid methods for monitoring the elemental composition (CHON) of the raw gas leaving the gasifier are needed. Conventional methods rely on time-consuming and costly laboratory procedures for analysing the condensable part of the raw gas. An alternative method, presented in this work, assesses the CHON composition of raw gas in a “one step” analysis without the need to previously characterise its chemical species composition. Our method is based on the quantitative conversion of a raw gas of complex chemical composition into CO 2 , H 2 O, and N 2 in a small combustor. The levels of these simple species can be measured with high accuracy and good time resolution, and the CHON composition of the raw gas can be determined from the mass balance across the combustor. To evaluate this method, an online combustion facility was built and used to analyse the raw gas from the Chalmers 2-MW th dual fluidised bed steam gasifier. Test runs of the developed facility demonstrated complete combustion of the raw gas and the measurements were both fast and reliable. The new method used in combination with zero-dimensional reactor modelling provides valuable data for the operational monitoring of gasification processes, such as the degree of fuel conversion, composition of the char exiting the gasifier, oxygen transport by catalytic bed material, and amount of condensables in raw gas

Binary nucleation kinetics. III. Transient behavior and time lags

International Nuclear Information System (INIS)

Wyslouzil, B.E.; Wilemski, G.

1996-01-01

Transient binary nucleation is more complex than unary because of the bidimensionality of the cluster formation kinetics. To investigate this problem qualitatively and quantitatively, we numerically solved the birth-death equations for vapor-to-liquid phase transitions. Our previous work showed that the customary saddle point and growth path approximations are almost always valid in steady state gas phase nucleation and only fail if the nucleated solution phase is significantly nonideal. Now, we demonstrate that in its early transient stages, binary nucleation rarely, if ever, occurs via the saddle point. This affects not only the number of particles forming but their composition and may be important for nucleation in glasses and other condensed mixtures for which time scales are very long. Before reaching the state of saddle point nucleation, most binary systems pass through a temporary stage in which the region of maximum flux extends over a ridge on the free energy surface. When ridge crossing nucleation is the steady state solution, it thus arises quite naturally as an arrested intermediate state that normally occurs in the development of saddle point nucleation. While the time dependent and steady state distributions of the fluxes and concentrations for each binary system are strongly influenced by the gas composition and species impingement rates, the ratio of nonequilibrium to equilibrium concentrations has a quasiuniversal behavior that is determined primarily by the thermodynamic properties of the liquid mixture. To test our quantitive results of the transient behavior, we directly calculated the time lag for the saddle point flux and compared it with the available analytical predictions. Although the analytical results overestimate the time lag by factors of 1.2-5, they should be adequate for purposes of planning experiments. We also found that the behavior of the saddle point time lag can indicate when steady state ridge crossing nucleation will occur

A Transient Model for Fuel Cell Cathode-Water Propagation Behavior inside a Cathode after a Step Potential

Directory of Open Access Journals (Sweden)

Der-Sheng Chan

2010-04-01

Full Text Available Most of the voltage losses of proton exchange membrane fuel cells (PEMFC are due to the sluggish kinetics of oxygen reduction on the cathode and the low oxygen diffusion rate inside the flooded cathode. To simulate the transient flooding in the cathode of a PEMFC, a transient model was developed. This model includes the material conservation of oxygen, vapor, water inside the gas diffusion layer (GDL and micro-porous layer (MPL, and the electrode kinetics in the cathode catalyst layer (CL. The variation of hydrophobicity of each layer generated a wicking effect that moves water from one layer to the other. Since the GDL, MPL, and CL are made of composite materials with different hydrophilic and hydrophobic properties, a linear function of saturation was used to calculate the wetting contact angle of these composite materials. The balance among capillary force, gas/liquid pressure, and velocity of water in each layer was considered. Therefore, the dynamic behavior of PEMFC, with saturation transportation taken into account, was obtained in this study. A step change of the cell voltage was used to illustrate the transient phenomena of output current, water movement, and diffusion of oxygen and water vapor across the entire cathode.

Non-isothermal compositional gas flow during carbon dioxide storage and enhanced gas recovery

DEFF Research Database (Denmark)

Singh, Ashok; Böettcher, N.; Wang, W.

2011-01-01

In this work we present the conceptual modeling and the numerical scheme for carbon dioxide storage into nearly depleted gas reservoirs for enhanced gas recovery reasons. For this we develop non-isothermal compositional gas flow model. We used a combined monolithic / staggered coupling scheme...... to solve mass balance equation for the gaseous mixture with heat and fractional mass transport equations. Temperature change resulting from fluid expansion and viscous heat dissipation is included in heat transport in addition to advection and conduction. We have used a modified version of the Peng...

Thermal shock behavior of W-ZrC/Sc2O3 composites under two different transient events by electron and laser irradiation

Science.gov (United States)

Chen, Hong-Yu; Luo, Lai-Ma; Zan, Xiang; Xu, Qiu; Tokunaga, Kazutoshi; Liu, Jia-Qin; Zhu, Xiao-Yong; Cheng, Ji-Gui; Wu, Yu-Cheng

2018-02-01

The transient thermal shock behaviors of W-ZrC/Sc2O3 composites with different ZrC contents were evaluated using transient thermal shock test by electron and laser beams. The effects of different ZrC doping contents on the surface morphology and thermal shock resistance of W-ZrC/Sc2O3 composites were then investigated. Similarity and difference between effects of electron and laser beam transient heat loading were also discussed in this study. Repeated heat loading resulted in thermal fatigue of the irradiated W-ZrC/Sc2O3 samples by thermal stress, leading to the rough surface morphologies with cracks. After different transient thermal tests, significant surface roughening, cracks, surface melting, and droplet ejection occurred. W-2vol.%Sc2O3 sample has superior thermal properties and greater resistance to surface modifications under transient thermal shock, and with the increasing ZrC content in W alloys, thermal shock resistance of W-Zr/Sc2O3 sample tends to be unsatisfied.

Emissions and efficiency of a domestic gas stove burning natural gases with various compositions

International Nuclear Information System (INIS)

Yungchang Ko; Tahui Lin

2003-01-01

The heating value of a fuel, which depends on its composition, strongly affects burner performance. Using the same gas stove to burn natural gas with various heating values is inappropriate and hazardous due to the possible occurrence of incomplete combustion (i.e. a great increase of CO emissions and/or soot formation), liftoff, flashback and inadequate heat input. In this study, we aim to assess the effects of changes in gas composition on burner performance and propose suitable design or operational factors of domestic gas stoves burning natural gas with various heating values. A single gas burner, originally designed for burning natural gas with low heating value, is adopted to investigate the effects of variations in gas composition on the burner performance. The influence of five significant parameters, including gas composition, primary aeration, gas flow rate (heat input), gas supply pressure, and loading height, on the thermal efficiency and CO emissions were reported and discussed. Using natural gas with high heating value instead of natural gas with low heating value results in a decrease in thermal efficiency (due to higher thermal input) and an increase in CO emission (caused by incomplete combustion). These problems can be significantly improved by decreasing the gas pressure to a suitable value, by enlarging the primary aeration to a favorable level, by selecting a proper thermal input, or by adjusting the optimized heating height. (Author)

Methods of Off-Gas Flammability Control for DWPF Melter Off-Gas System at Savannah River Site

International Nuclear Information System (INIS)

Choi, A.S.; Iverson, D.C.

1996-01-01

Several key operating variables affecting off-gas flammability in a slurry-fed radioactive waste glass melter are discussed, and the methods used to prevent potential off-gas flammability are presented. Two models have played a central role in developing such methods. The first model attempts to describe the chemical events occurring during the calcining and melting steps using a multistage thermodynamic equilibrium approach, and it calculates the compositions of glass and calcine gases. Volatile feed components and calcine gases are fed to the second model which then predicts the process dynamics of the entire melter off-gas system including off-gas flammability under both steady state and various transient operating conditions. Results of recent simulation runs are also compared with available data

Transient photoconductivity and femtosecond nonlinear optical properties of a conjugated polymer-graphene oxide composite

Energy Technology Data Exchange (ETDEWEB)

Nalla, Venkatram; Ji Wei [Department of Physics, National University of Singapore, Singapore 117542 (Singapore); Polavarapu, Lakshminarayana; Manga, Kiran Kumar; Goh, Bee Min; Loh, Kian Ping; Xu Qinghua, E-mail: chmxqh@nus.edu.sg, E-mail: phyjiwei@nus.edu.sg [Department of Chemistry, National University of Singapore, Singapore 117543 (Singapore)

2010-10-15

A water soluble conjugated thiophene polymer, sodium salt of poly[2-(3-thienyl)ethoxy-4-butylsulfonate] (TPP), and graphene oxide (GO) composite film (GO-TPP) device was prepared. Transient photoconductivity measurements were carried out on the GO-TPP composite film using 150 ns laser pulses of 527 nm wavelength. Highly efficient photocurrent generation was observed from the GO-TPP film. The relationships of the film photoconductivity, photocurrent decay time and electron decay times with the incident light intensity were investigated. The photoconductive gain of the film was determined to be greater than 40% and to be independent of the light intensity. Furthermore, the femtosecond nonlinear optical properties of the GO-TPP film were measured using 800 nm femtosecond laser pulses and the composite film exhibited high nonlinear absorption and nonlinear refraction coefficients.

Transient photoconductivity and femtosecond nonlinear optical properties of a conjugated polymer-graphene oxide composite

International Nuclear Information System (INIS)

Nalla, Venkatram; Ji Wei; Polavarapu, Lakshminarayana; Manga, Kiran Kumar; Goh, Bee Min; Loh, Kian Ping; Xu Qinghua

2010-01-01

A water soluble conjugated thiophene polymer, sodium salt of poly[2-(3-thienyl)ethoxy-4-butylsulfonate] (TPP), and graphene oxide (GO) composite film (GO-TPP) device was prepared. Transient photoconductivity measurements were carried out on the GO-TPP composite film using 150 ns laser pulses of 527 nm wavelength. Highly efficient photocurrent generation was observed from the GO-TPP film. The relationships of the film photoconductivity, photocurrent decay time and electron decay times with the incident light intensity were investigated. The photoconductive gain of the film was determined to be greater than 40% and to be independent of the light intensity. Furthermore, the femtosecond nonlinear optical properties of the GO-TPP film were measured using 800 nm femtosecond laser pulses and the composite film exhibited high nonlinear absorption and nonlinear refraction coefficients.

Biofilm population dynamics in a trickle-bed bioreactor used for the biodegradation of aromatic hydrocarbons from waste gas under transient conditions.

Science.gov (United States)

Hekmat, D; Feuchtinger, A; Stephan, M; Vortmeyer, D

2004-04-01

The dynamics of a multispecies biofilm population in a laboratory-scale trickle-bed bioreactor for the treatment of waste gas was examined. The model pollutant was a VOC-mixture of polyalkylated benzenes called Solvesso 100. Fluorescence in-situ hybridization (FISH) was applied in order to characterise the population composition. The bioreactor was operated under transient conditions by applying pollutant concentration shifts and a starvation phase. Only about 10% of the biofilm mass were cells, the rest consisted of extracellular polymeric substances (EPS). The average fraction of Solvesso 100-degrading cells during pollutant supply periods was less than 10%. About 60% of the cells were saprophytes and about 30% were inactive cells. During pollutant concentration shift experiments, the bioreactor performance adapted within a few hours. The biofilm population exhibited a dependency upon the direction of the shifts. The population reacted within days after a shift-down and within weeks after a shift-up. The pollutant-degraders reacted significantly faster compared to the other cells. During the long-term starvation phase, a shift of the population composition took place. However, this change of composition as well as the degree of metabolic activity was completely reversible. A direct correlation between the biodegradation rate of the bioreactor and the number of pollutant-degrading cells present in the biofilm could not be obtained due to insufficient experimental evidence.

Effects of gas composition in headspace and bicarbonate concentrations in media on gas and methane production, degradability, and rumen fermentation using in vitro gas production techniques.

Science.gov (United States)

Patra, Amlan Kumar; Yu, Zhongtang

2013-07-01

Headspace gas composition and bicarbonate concentrations in media can affect methane production and other characteristics of rumen fermentation in in vitro gas production systems, but these 2 important factors have not been evaluated systematically. In this study, these 2 factors were investigated with respect to gas and methane production, in vitro digestibility of feed substrate, and volatile fatty acid (VFA) profile using in vitro gas production techniques. Three headspace gas compositions (N2+ CO2+ H2 in the ratio of 90:5:5, CO2, and N2) with 2 substrate types (alfalfa hay only, and alfalfa hay and a concentrate mixture in a 50:50 ratio) in a 3×2 factorial design (experiment 1) and 3 headspace compositions (N2, N2 + CO2 in a 50:50 ratio, and CO2) with 3 bicarbonate concentrations (80, 100, and 120 mM) in a 3×3 factorial design (experiment 2) were evaluated. In experiment 1, total gas production (TGP) and net gas production (NGP) was the lowest for CO2, followed by N2, and then the gas mixture. Methane concentration in headspace gas after fermentation was greater for CO2 than for N2 and the gas mixture, whereas total methane production (TMP) and net methane production (NMP) were the greatest for CO2, followed by the gas mixture, and then N2. Headspace composition did not affect in vitro digestibility or the VFA profile, except molar percentages of propionate, which were greater for CO2 and N2 than for the gas mixture. Methane concentration in headspace gas, TGP, and NGP were affected by the interaction of headspace gas composition and substrate type. In experiment 2, increasing concentrations of CO2 in the headspace decreased TGP and NGP quadratically, but increased the concentrations of methane, NMP, and in vitro fiber digestibility linearly, and TMP quadratically. Fiber digestibility, TGP, and NGP increased linearly with increasing bicarbonate concentrations in the medium. Concentrations of methane and NMP were unaffected by bicarbonate concentration, but

Gas composition of sludge residue profiles in a sludge treatment reed bed between loadings

DEFF Research Database (Denmark)

Larsen, Julie Dam; Nielsen, Steen M; Scheutz, Charlotte

2017-01-01

Treatment of sludge in sludge treatment reed bed systems includes dewatering and mineralization. The mineralization process, which is driven by microorganisms, produces different gas species as by-products. The pore space composition of the gas species provides useful information on the biological...... processes occurring in the sludge residue. In this study, we measured the change in composition of gas species in the pore space at different depth levels in vertical sludge residue profiles during a resting period of 32 days. The gas composition of the pore space in the sludge residue changed during...

Thermal conductivity of wood ash diatomite composites using the transient hot strip method

International Nuclear Information System (INIS)

Muia, L.M.; Gaitho, F.

2003-08-01

The transient Hot Strip method (THS) was used to determine the thermal conductivities of pure Wood Ash (WA), two kinds of diatomite i.e., DB and DF, and their composites. The effects of grain size and temperature on the thermal conductivities of the three systems and their composites were also determined. The lowest thermal conductivities of 0.02x10 -2 Wm -1 K -1 for wood ash and ∼ 3x10 -2 Wm -1 K -1 for the diatomites are found in the particle size range 60 -80μm. The thermal conductivities of the various composites range between 1.3x10 -3 and 6.8x10 -2 Wm -1 K -1 . These values are a factor of 10 lower than those of the pure materials. The thermal conductivity of the three composites is independent of temperature in the range 26-350 deg. C, in contrast to those pure materials which increase with temperature. Generally, the thermal conductivites of the pure materials which increase as their porosity or moisture contents are increased. (author)

Composite Chern-Simons gauge boson in anyon gas

International Nuclear Information System (INIS)

Nguyen Van Hieu; Nguyen Hung Son.

1990-08-01

It was shown that in a free anyon gas there exists a composite vector gauge field with the effective action containing a Chern-Simons term. The momentum dependence of the energy of the composite boson was found. The mixing between Chern-Simons boson and photon gives rise to the appearance of new quasiparticles - Chern-Simons polaritons. The dispersion equations of Chern-Simons polaritons were derived. (author). 14 refs

Gas leak tightness of SiC/SiC composites at elevated temperature

Energy Technology Data Exchange (ETDEWEB)

Hayasaka, Daisuke, E-mail: hayasaka@oasis.muroran-it.ac.jp [OASIS, Muroran Institute of Technology, Muroran, Hokkaido (Japan); Graduate School of Engineering, Muroran Institute of Technology, Muroran, Hokkaido (Japan); Park, Joon-Soo. [OASIS, Muroran Institute of Technology, Muroran, Hokkaido (Japan); Kishimoto, Hirotatsu [OASIS, Muroran Institute of Technology, Muroran, Hokkaido (Japan); Graduate School of Engineering, Muroran Institute of Technology, Muroran, Hokkaido (Japan); Kohyama, Akira [OASIS, Muroran Institute of Technology, Muroran, Hokkaido (Japan)

2016-11-01

Highlights: • NITE-SiC/SiC has extremely densified microstructure compared with other SiC/SiC composite like CVI. • Excellent helium and hydrogen gas-leak tightness of SiC/SiC composites by DEMO-NITE method from prototype industrialization production line was presented. • The excellence against stainless steel and Zircaloy at elevated temperature, together with generic excellent properties of SiC will be inevitable for innovative blanket and divertors for DEMO- and power- fusion reactors. - Abstract: SiC/SiC composite materials are attractive candidates for high heat flux components and blanket of fusion reactor, mainly due to their high temperature properties, radiation damage tolerance and low induced radioactivity. One of the challenges for SiC/SiC application in fusion reactors is to satisfy sufficient gas leak tightness of hydrogen and helium isotopes. Although many efforts have been carried-out, SiC/SiC composites by conventional processes have not been successful to satisfy the requirements, except SiC/SiC composites by NITE-methods. Toward the early realization of SiC/SiC components into fusion reactor systems process development of NITE-process has been continued. Followed to the brief introduction of recently developed DEMO-NITE process, baseline properties and hydrogen and helium gas leak tightness is presented. SiC/SiC claddings with 10 mm in diameter and 1 mm in wall thickness are tested by gas leak tightness system developed. The leak tightness measurements are done room temperature to 400 °C. Excellent gas leak tightness equivalent or superior to Zircaloy claddings for light water fission reactors is confirmed. The excellent gas leak tightness suggests nearly perfect suppression of large gas leak path in DEMO-NITE SiC/SiC.

On the rate determining step in fission gas release from high burn-up water reactor fuel during power transients

International Nuclear Information System (INIS)

Walker, C.T.; Mogensen, M.

1987-01-01

The radial distribution of grain boundary gas in a PWR and a BWR fuel is reported. The measurements were made using a new approach involving X-ray fluorescence analysis and electron probe microanalysis. In both fuels the concentration of grain boundary gas was much higher than hitherto suspected. The gas was mainly contained in the bubble/pore structure. The factors that determined the fraction of gas released from the grains and the level of gas retention on the grain boundaries are identified and discussed. The variables involved are the local fuel stoichiometry, the amount of open porosity, the magnitude of the local compressive hydrostatic stress and the interaction of metallic precipitates with gas bubbles on the grain faces. It is concluded that under transient conditions the interlinkage of gas bubbles on the grain faces and the subsequent formation of grain edge tunnels is the rate determining step for gas release; at least when high burn-up fuel is involved. (orig.)

Temperature dependence of gas sensing behaviour of TiO2 doped PANI composite thin films

Science.gov (United States)

Srivastava, Subodh; Sharma, S. S.; Sharma, Preetam; Sharma, Vinay; Rajura, Rajveer Singh; Singh, M.; Vijay, Y. K.

2014-04-01

In the present work we have reported the effect of temperature on the gas sensing properties of TiO2 doped PANI composite thin film based chemiresistor type gas sensors for hydrogen gas sensing application. PANI and TiO2 doped PANI composite were synthesized by in situ chemical oxidative polymerization of aniline at low temperature. The electrical properties of these composite thin films were characterized by I-V measurements as function of temperature. The I-V measurement revealed that conductivity of composite thin films increased as the temperature increased. The changes in resistance of the composite thin film sensor were utilized for detection of hydrogen gas. It was observed that at room temperature TiO2 doped PANI composite sensor shows higher response value and showed unstable behavior as the temperature increased. The surface morphology of these composite thin films has also been characterized by scanning electron microscopy (SEM) measurement.

Real-time composition determination of gas mixtures

NARCIS (Netherlands)

Lötters, Joost Conrad; van der Wouden, E.J.; Groenesteijn, Jarno; Sparreboom, Wouter; Lammerink, Theodorus S.J.; Wiegerink, Remco J.

2014-01-01

We have designed and implemented an analytical calculation model with which we can real-time determine the composition of gas mixtures. The model is based upon a multi-parameter flow measurement system, consisting of a Coriolis and thermal flow sensor, a density meter and a pressure sensor. The

ORTAP: a nuclear steam supply system simulation for the dynamic analysis of high temperature gas cooled reactor transients

International Nuclear Information System (INIS)

Cleveland, J.C.; Hedrick, R.A.; Ball, S.J.; Delene, J.G.

1977-01-01

ORTAP was developed to predict the dynamic behavior of the high temperature gas cooled reactor (HTGR) Nuclear Steam Supply System for normal operational transients and postulated accident conditions. It was developed for the Nuclear Regulatory Commission (NRC) as an independent means of obtaining conservative predictions of the transient response of HTGRs over a wide range of conditions. The approach has been to build sufficient detail into the component models so that the coupling between the primary and secondary systems can be accurately represented and so that transients which cover a wide range of conditions can be simulated. System components which are modeled in ORTAP include the reactor core, a typical reheater and steam generator module, a typical helium circulator and circulator turbine and the turbine generator plant. The major plant control systems are also modeled. Normal operational transients which can be analyzed with ORTAP include reactor start-up and shutdown, normal and rapid load changes. Upset transients which can be analyzed with ORTAP include reactor trip, turbine trip and sudden reduction in feedwater flow. ORTAP has also been used to predict plant response to emergency or faulted conditions such as primary system depressurization, loss of primary coolant flow and uncontrolled removal of control poison from the reactor core

Transient cavitation in pipelines

NARCIS (Netherlands)

Kranenburg, C.

1974-01-01

The aim of the present study is to set up a one-dimensional mathematical model, which describes the transient flow in pipelines, taking into account the influence of cavitation and free gas. The flow will be conceived of as a three-phase flow of the liquid, its vapour and non-condensible gas. The

GRASS-SST, Fission Products Gas Release and Fuel Swelling in Steady-State and Transients

International Nuclear Information System (INIS)

Zawadzki, S.

2001-01-01

1 - Description of program or function: GRASS-SST is a comprehensive, mechanistic model for the prediction of fission-gas behaviour in UO 2 -base fuels during steady-state and transient conditions. GRASS-SST treats fission-gas release and fuel swelling on an equal basis and simultaneously treats all major mechanisms that influence fission-gas behaviour. Models are included for intra- and inter-granular fission-gas bubble behaviour as well as a mechanistic description of the role of grain-edge inter-linked porosity on fission-gas release and swelling. GRASS-SST calculations include the effects of gas production from fissioning uranium atoms, bubble nucleation, a realistic equation of state for xenon, lattice bubble diffusivities based on experimental observations, bubble migration, bubble coalescence, re-solution, temperature and temperature gradients, inter-linked porosity, and fission-gas interaction with structural defects (dislocations and grain boundaries) on both the distribution of fission-gas within the fuel and on the amount of fission-gas released from the fuel. GRASS-SST includes the effects of the degree of nonequilibrium in the UO 2 lattice on fission-gas bubble mobility and bubble coalescence and also accounts for the observed formation of grain-surface channels. GRASS-SST also includes mechanistic models for grain-growth/grain boundary sweeping and for the behaviour of fission gas during liquefaction/dissolution and fuel melting conditions. 2 - Method of solution: A system of coupled equations for the evolution of the fission-gas bubble-size distributions in the lattice, on dislocations, on grain faces, and grain edges is derived based on the GRASS-SST models. Given a set of operating conditions, GRASS-SST calculates the bubble radii for the size classes of bubbles under consideration using a realistic equation of state for xenon as well as a generalised capillary relation. 3 - Restrictions on the complexity of the problem: Maxima of : 1 axial section

Stall/surge dynamics of a multi-stage air compressor in response to a load transient of a hybrid solid oxide fuel cell-gas turbine system

Science.gov (United States)

Azizi, Mohammad Ali; Brouwer, Jacob

2017-10-01

A better understanding of turbulent unsteady flows in gas turbine systems is necessary to design and control compressors for hybrid fuel cell-gas turbine systems. Compressor stall/surge analysis for a 4 MW hybrid solid oxide fuel cell-gas turbine system for locomotive applications is performed based upon a 1.7 MW multi-stage air compressor. Control strategies are applied to prevent operation of the hybrid SOFC-GT beyond the stall/surge lines of the compressor. Computational fluid dynamics tools are used to simulate the flow distribution and instabilities near the stall/surge line. The results show that a 1.7 MW system compressor like that of a Kawasaki gas turbine is an appropriate choice among the industrial compressors to be used in a 4 MW locomotive SOFC-GT with topping cycle design. The multi-stage radial design of the compressor enhances the ability of the compressor to maintain air flow rate during transient step-load changes. These transient step-load changes are exhibited in many potential applications for SOFC/GT systems. The compressor provides sustained air flow rate during the mild stall/surge event that occurs due to the transient step-load change that is applied, indicating that this type of compressor is well-suited for this hybrid application.

Validation of spectroscopic gas analyzer accuracy using gravimetric standard gas mixtures: impact of background gas composition on CO2 quantitation by cavity ring-down spectroscopy

Science.gov (United States)

Lim, Jeong Sik; Park, Miyeon; Lee, Jinbok; Lee, Jeongsoon

2017-12-01

The effect of background gas composition on the measurement of CO2 levels was investigated by wavelength-scanned cavity ring-down spectrometry (WS-CRDS) employing a spectral line centered at the R(1) of the (3 00 1)III ← (0 0 0) band. For this purpose, eight cylinders with various gas compositions were gravimetrically and volumetrically prepared within 2σ = 0.1 %, and these gas mixtures were introduced into the WS-CRDS analyzer calibrated against standards of ambient air composition. Depending on the gas composition, deviations between CRDS-determined and gravimetrically (or volumetrically) assigned CO2 concentrations ranged from -9.77 to 5.36 µmol mol-1, e.g., excess N2 exhibited a negative deviation, whereas excess Ar showed a positive one. The total pressure broadening coefficients (TPBCs) obtained from the composition of N2, O2, and Ar thoroughly corrected the deviations up to -0.5 to 0.6 µmol mol-1, while these values were -0.43 to 1.43 µmol mol-1 considering PBCs induced by only N2. The use of TPBC enhanced deviations to be corrected to ˜ 0.15 %. Furthermore, the above correction linearly shifted CRDS responses for a large extent of TPBCs ranging from 0.065 to 0.081 cm-1 atm-1. Thus, accurate measurements using optical intensity-based techniques such as WS-CRDS require TPBC-based instrument calibration or use standards prepared in the same background composition of ambient air.

Transient Dynamic Response of Delaminated Composite Rotating Shallow Shells Subjected to Impact

Directory of Open Access Journals (Sweden)

Amit Karmakar

2006-01-01

Full Text Available In this paper a transient dynamic finite element analysis is presented to study the response of delaminated composite pretwisted rotating shallow shells subjected to low velocity normal impact. Lagrange's equation of motion is used to derive the dynamic equilibrium equation and moderate rotational speeds are considered wherein the Coriolis effect is negligible. An eight noded isoparametric plate bending element is employed in the finite element formulation incorporating rotary inertia and effects of transverse shear deformation based on Mindlin's theory. To satisfy the compatibility of deformation and equilibrium of resultant forces and moments at the delamination crack front a multipoint constraint algorithm is incorporated which leads to unsymmetric stiffness matrices. The modified Hertzian contact law which accounts for permanent indentation is utilized to compute the contact force, and the time dependent equations are solved by Newmark's time integration algorithm. Parametric studies are performed in respect of location of delamination, angle of twist and rotational speed for centrally impacted graphite-epoxy composite cylindrical shells.

Methanol Gas-Sensing Properties of SWCNT-MIP Composites

Science.gov (United States)

Zhang, Jin; Zhu, Qin; Zhang, Yumin; Zhu, Zhongqi; Liu, Qingju

2016-11-01

The single-walled carbon nanotube (SWCNT)-molecularly imprinted powder (MIP) composites in this paper were prepared by mixing SWCNTs with MIPs. The structure and micrograph of the as-prepared SWCNTs-MIPs samples were characterized by XRD and TEM. The gas-sensing properties were tested through indirect-heating sensors based on SWCNT-MIP composites fabricating on an alumina tube with Au electrodes and Pt wires. The results showed that the structure of SWCNTs-MIPs is of orthogonal perovskite and the average particle size of the SWCNTs-MIPs was in the range of 10-30 nm. SWCNTs-MIPs exhibit good methanol gas-sensitive properties. At 90 °C, the response to 1 ppm methanol is 19.7, and the response to the interferent is lower than 5 to the other interferent gases (ethanol, formaldehyde, toluene, acetone, ammonia, and gasoline). The response time and recovery time are 50 and 58 s, respectively.

Transient two-phase flow

International Nuclear Information System (INIS)

Hsu, Y.Y.

1974-01-01

The following papers related to two-phase flow are summarized: current assumptions made in two-phase flow modeling; two-phase unsteady blowdown from pipes, flow pattern in Laval nozzle and two-phase flow dynamics; dependence of radial heat and momentum diffusion; transient behavior of the liquid film around the expanding gas slug in a vertical tube; flooding phenomena in BWR fuel bundles; and transient effects in bubble two-phase flow. (U.S.)

Physicochemical effects of varying fuel composition on knock characteristics of natural gas mixtures

NARCIS (Netherlands)

Gersen, Sander; van Essen, Martijn; van Dijk, Gerco; Levinsky, Howard

2014-01-01

The physicochemical origins of how changes in fuel composition affect autoignition of the end gas, leading to engine knock, are analyzed for a natural gas engine. Experiments in a lean-burn, high-speed medium-BMEP gas engine are performed using a reference natural gas with systematically varied

Transient fission gas release from UO2 fuel for high temperature and high burnup

International Nuclear Information System (INIS)

Szuta, M.

2001-01-01

In the present paper it is assumed that the fission gas release kinetics from an irradiated UO 2 fuel for high temperature is determined by the kinetics of grain growth. A well founded assumption that Vitanza curve describes the change of uranium dioxide re-crystallization temperature and the experimental results referring to the limiting grain size presented in the literature are used to modify the grain growth model. Algorithms of fission gas release due to re-crystallization of uranium dioxide grains are worked out. The defect trap model of fission gas behaviour described in the earlier papers is supplemented with the algorithms. Calculations of fission gas release in function of time, temperature, burn-up and initial grain sizes are obtained. Computation of transient fission gas release in the paper is limited to the case where steady state of irradiation to accumulate a desired burn-up is performed below the temperature of re-crystallization then the subsequent step temperature increase follows. There are considered two kinds of step temperature increase for different burn-up: the final temperature of the step increase is below and above the re-crystallization temperature. Calculations show that bursts of fission gas are predicted in both kinds. The release rate of gas liberated for the final temperature above the re-crystallization temperature is much higher than for final temperature below the re-crystallization temperature. The time required for the burst to subside is longer due to grain growth than due to diffusion of bubbles and knock-out release. The theoretical results explain qualitatively the experimental data but some of them need to be verified since this sort of experimental data are not found in the available literature. (author)

Ammonia Gas Sensing Behavior of Tanninsulfonic Acid Doped Polyaniline-TiO2 Composite

Directory of Open Access Journals (Sweden)

Venu Gopal Bairi

2015-10-01

Full Text Available A highly active tannin doped polyaniline-TiO2 composite ammonia gas sensor was developed and the mechanism behind the gas sensing activity was reported for the first time. A tanninsulfonic acid doped polyaniline (TANIPANI-titanium dioxide nanocomposite was synthesized by an in situ polymerization of aniline in the presence of tanninsulfonic acid and titanium dioxide nanoparticles. X-ray diffraction and thermogravimetric analysis were utilized to determine the incorporation of TiO2 in TANIPANI matrix. UV-Visible and infrared spectroscopy studies provided information about the electronic interactions among tannin, polyaniline, and TiO2. Scanning electron microscopy (SEM along with energy dispersive X-ray spectroscopy (EDS and atomic force microscopy (AFM surface analysis techniques were used to investigate the metal oxide dispersions inside polyaniline matrix. Gas sensors were prepared by spin coating solutions of TANIPANI-TiO2 and TANIPANI composites onto glass slides. Sensors were tested at three different concentrations (20 ppm, 40 ppm, and 60 ppm of ammonia gas at ambient temperature conditions by measuring the changes in surface resistivity of the films with respect to time. Ammonia gas sensing plots are presented showing the response values, response times and recovery times. The TANIPANI-TiO2 composite exhibited better response and shorter recovery times when compared to TANIPANI control and other polyaniline composites that have been reported in the literature. For the first time a proposed mechanism of gas sensing basing on the polaron band localization and its effects on the gas sensing behavior of polyaniline are reported.

Mineral and chemical composition of rock core and surface gas composition in Horonobe Underground Research Laboratory project. Phase 1

International Nuclear Information System (INIS)

Hiraga, Naoto; Ishii, Eiichi

2008-02-01

The following three kinds of analyses were conducted for the 1st phase of the Horonobe Underground Research Laboratory Project. Mineral composition analysis of core sample. Whole rock chemical composition analysis of core sample. Surface gas composition analysis. This document summarizes the results of these analyses. (author)

Transient Flow Dynamics in Optical Micro Well Involving Gas Bubbles

Science.gov (United States)

Johnson, B.; Chen, C. P.; Jenkins, A.; Spearing, S.; Monaco, L. A.; Steele, A.; Flores, G.

2006-01-01

The Lab-On-a-Chip Application Development (LOCAD) team at NASA s Marshall Space Flight Center is utilizing Lab-On-a-Chip to support technology development specifically for Space Exploration. In this paper, we investigate the transient two-phase flow patterns in an optic well configuration with an entrapped bubble through numerical simulation. Specifically, the filling processes of a liquid inside an expanded chamber that has bubbles entrapped. Due to the back flow created by channel expansion, the entrapped bubbles tend to stay stationary at the immediate downstream of the expansion. Due to the huge difference between the gas and liquid densities, mass conservation issues associated with numerical diffusion need to be specially addressed. The results are presented in terms of the movement of the bubble through the optic well. Bubble removal strategies are developed that involve only pressure gradients across the optic well. Results show that for the bubble to be moved through the well, pressure pulsations must be utilized in order to create pressure gradients across the bubble itself.

Tucurui`s 500 kV S F{sub 6} gas-insulated substation modeling for fast transients - field tests comparison

Energy Technology Data Exchange (ETDEWEB)

Lima Filho, Joao Ferreira de; Pazo Blanco, Flavio A.F.; D` Ajuz, Ary; Nascimento, Lidio F.A. [ELETRONORTE, Brasilia, DF (Brazil)

1994-12-31

Many problems in insulation, devices and equipment have been resulted from switching operations in the 500 kV Gas-Insulated Substation (GIS) of Tucurui power plant. Disconnector closing or opening action can subject the GIS components to great stresses from excessive voltages at high frequencies caused by successive reflections of travelling waves at discontinuities (1,2,3). Field tests were carried out in September 18-23, 1991 to verify the actual GIS stresses at Tucurui. From these results simulations on the Alternative Transients Program (ATP) were performed in order to check the substation modeling. This paper presents and discusses the Tucurui GIS modeling for switching fast transients and its field test validation. (author) 8 refs., 6 figs.

Melt Infiltrated Ceramic Composites (Hipercomp) for Gas Turbine Engine Applications

Energy Technology Data Exchange (ETDEWEB)

Gregory Corman; Krishan Luthra

2005-09-30

This report covers work performed under the Continuous Fiber Ceramic Composites (CFCC) program by GE Global Research and its partners from 1994 through 2005. The processing of prepreg-derived, melt infiltrated (MI) composite systems based on monofilament and multifilament tow SiC fibers is described. Extensive mechanical and environmental exposure characterizations were performed on these systems, as well as on competing Ceramic Matrix Composite (CMC) systems. Although current monofilament SiC fibers have inherent oxidative stability limitations due to their carbon surface coatings, the MI CMC system based on multifilament tow (Hi-Nicalon ) proved to have excellent mechanical, thermal and time-dependent properties. The materials database generated from the material testing was used to design turbine hot gas path components, namely the shroud and combustor liner, utilizing the CMC materials. The feasibility of using such MI CMC materials in gas turbine engines was demonstrated via combustion rig testing of turbine shrouds and combustor liners, and through field engine tests of shrouds in a 2MW engine for >1000 hours. A unique combustion test facility was also developed that allowed coupons of the CMC materials to be exposed to high-pressure, high-velocity combustion gas environments for times up to {approx}4000 hours.

Gas storage cylinder formed from a composition containing thermally exfoliated graphite

Science.gov (United States)

Prud'Homme, Robert K. (Inventor); Aksay, Ilhan A. (Inventor)

2012-01-01

A gas storage cylinder or gas storage cylinder liner, formed from a polymer composite, containing at least one polymer and a modified graphite oxide material, which is a thermally exfoliated graphite oxide with a surface area of from about 300 m(exp 2)/g to 2600 m(exp 2)2/g.

Fluidized bed gasification of sugar cane bagasse. Influence on gas composition

Energy Technology Data Exchange (ETDEWEB)

Esperanza, E.; Aleman, Y. [Univ. of las Villas, Santa Clara (Cuba). Biomass Thermoconversion group/CETA; Arauzo, J.; Gea, G. [Univ. of Zaragoza (Spain). Chemical and Environmental Engineering Dept.

1999-07-01

Air and steam gasification of biomass has been studied at different temperatures. The experiments have been carried out in a bench scale plant. It consists of an atmospheric bubbling fluidized bed gasifier heated by an electric furnace. The gasification process have been carried out at high heating rates and low residence time of the gases. The biomass used has been Cuban sugar cane bagasse. Three operating parameters have been evaluated to improve the gas composition: Equivalence Ratio (E.R.) in the range of 0.15 to 0.55; the bed temperature from 780 to 920 deg C; and steam/biomass ratio (S/B) from 0.1 g/g to 0.5 g/g. The results obtained show the effect of these operating parameters in gas composition and the conditions to obtain higher yield to gas and else the maximum energy.

Rate transient analysis for homogeneous and heterogeneous gas reservoirs using the TDS technique

International Nuclear Information System (INIS)

Escobar, Freddy Humberto; Sanchez, Jairo Andres; Cantillo, Jose Humberto

2008-01-01

In this study pressure test analysis in wells flowing under constant wellbore flowing pressure for homogeneous and naturally fractured gas reservoir using the TDS technique is introduced. Although, constant rate production is assumed in the development of the conventional well test analysis methods, constant pressure production conditions are sometimes used in the oil and gas industry. The constant pressure technique or rate transient analysis is more popular reckoned as decline curve analysis under which rate is allows to decline instead of wellbore pressure. The TDS technique, everyday more used even in the most recognized software packages although without using its trade brand name, uses the log-log plot to analyze pressure and pressure derivative test data to identify unique features from which exact analytical expression are derived to easily estimate reservoir and well parameters. For this case, the fingerprint characteristics from the log-log plot of the reciprocal rate and reciprocal rate derivative were employed to obtain the analytical expressions used for the interpretation analysis. Many simulation experiments demonstrate the accuracy of the new method. Synthetic examples are shown to verify the effectiveness of the proposed methodology

Simulation of the impact of thunderstorm activity on atmospheric gas composition

Science.gov (United States)

Smyshlyaev, S. P.; Mareev, E. A.; Galin, V. Ya.

2010-08-01

A chemistry-climate model of the lower and middle atmosphere has been used to estimate the sensitivity of the atmospheric gas composition to the rate of thunderstorm production of nitrogen oxides at upper tropospheric and lower stratospheric altitudes. The impact that nitrogen oxides produced by lightning have on the atmospheric gas composition is treated as a subgrid-scale process and included in the model parametrically. The natural uncertainty in the global production rate of nitrogen oxides in lightning flashes was specified within limits from 2 to 20 Tg N/year. Results of the model experiments have shown that, due to the variability of thunderstorm-produced nitrogen oxides, their concentration in the upper troposphere and lower stratosphere can vary by a factor of 2 or 3, which, given the influence of nitrogen oxides on ozone and other gases, creates the potential for a strong perturbation of the atmospheric gas composition and thermal regime. Model calculations have shown the strong sensitivity of ozone and the OH hydroxyl to the amount of lightning nitrogen oxides at different atmospheric altitudes. These calculations demonstrate the importance of nitrogen oxides of thunderstorm origin for the balance of atmospheric odd ozone and gases linked to it, such as ozone and hydroxyl radicals. Our results demonstrate that one important task is to raise the accuracy of estimates of the rate of nitrogen oxide production by lightning discharges and to use physical parametrizations that take into account the local lightning effects and feedbacks arising in this case rather than climatological data in models of the gas composition and general circulation of the atmosphere.

Heat transfer in turbocharger turbines under steady, pulsating and transient conditions

International Nuclear Information System (INIS)

Burke, R.D.; Vagg, C.R.M.; Chalet, D.; Chesse, P.

2015-01-01

Highlights: • Compare turbine heat transfer correlations from different studies. • Compare heat transfer for a same turbine on-engine and on gas-stand. • Analyse heat transfer under steady and transient operating conditions. • Gas stand heat transfer correlations are transferrable to engine conditions. • Heat flows can be reversed compared to steady conditions during transients. - Abstract: Heat transfer is significant in turbochargers and a number of mathematical models have been proposed to account for the heat transfer, however these have predominantly been validated under steady flow conditions. A variable geometry turbocharger from a 2.2 L Diesel engine was studied, both on gas stand and on-engine, under steady and transient conditions. The results showed that heat transfer accounts for at least 20% of total enthalpy change in the turbine and significantly more at lower mechanical powers. A convective heat transfer correlation was derived from experimental measurements to account for heat transfer between the gases and the turbine housing and proved consistent with those published from other researchers. This relationship was subsequently shown to be consistent between engine and gas stand operation: using this correlation in a 1D gas dynamics simulation reduced the turbine outlet temperature error from 33 °C to 3 °C. Using the model under transient conditions highlighted the effect of housing thermal inertia. The peak transient heat flow was strongly linked to the dynamics of the turbine inlet temperature: for all increases, the peak heat flow was higher than under thermally stable conditions due to colder housing. For all decreases in gas temperature, the peak heat flow was lower and for temperature drops of more than 100 °C the heat flow was reversed during the transient

Fluid-induced vibration of composite natural gas pipelines

Energy Technology Data Exchange (ETDEWEB)

Zou, G.P.; Cheraghi, N.; Taheri, F. [Dalhousie Univ., Dept. of Civil Engineering, Halifax, NS (Canada)

2005-02-01

Advancements in materials bonding techniques have led to the use of reinforced composite pipelines. The use of steel pipe with a fiber-reinforced composite over-wrap together has produced an exceptionally strong pipe with positive advantages in weight and corrosion resistivity. Understanding the dynamic characteristics of this kind of sub-sea composite pipelines, which often accommodate axial flow of gas, and prediction of their response is of great interest. This paper presents a state-variable model developed for the analysis of fluid-induced vibration of composite pipeline systems. Simply supported, clamped and clamped-simply supported pipelines are investigated. The influence of fluid's Poisson ratio, the ratio of pipe radius to pipe-wall thickness, laminate layup, the ratio of liquid mass density to pipe-wall mass density, the fluid velocity, initial tension and fluid pressure are all considered. The results of our proposed methodology are compared with those of finite element analysis, using ANSYS ssoftware. (Author)

Real-time drilling mud gas monitoring for qualitative evaluation of hydrocarbon gas composition during deep sea drilling in the Nankai Trough Kumano Basin.

Science.gov (United States)

Hammerschmidt, Sebastian B; Wiersberg, Thomas; Heuer, Verena B; Wendt, Jenny; Erzinger, Jörg; Kopf, Achim

2014-01-01

Integrated Ocean Drilling Program Expedition 338 was the second scientific expedition with D/V Chikyu during which riser drilling was conducted as part of the Nankai Trough Seismogenic Zone Experiment. Riser drilling enabled sampling and real-time monitoring of drilling mud gas with an onboard scientific drilling mud gas monitoring system ("SciGas"). A second, independent system was provided by Geoservices, a commercial mud logging service. Both systems allowed the determination of (non-) hydrocarbon gas, while the SciGas system also monitored the methane carbon isotope ratio (δ(13)CCH4). The hydrocarbon gas composition was predominated by methane (> 1%), while ethane and propane were up to two orders of magnitude lower. δ(13)CCH4 values suggested an onset of thermogenic gas not earlier than 1600 meter below seafloor. This study aims on evaluating the onboard data and subsequent geological interpretations by conducting shorebased analyses of drilling mud gas samples. During shipboard monitoring of drilling mud gas the SciGas and Geoservices systems recorded up to 8.64% and 16.4% methane, respectively. Ethane and propane concentrations reached up to 0.03 and 0.013%, respectively, in the SciGas system, but 0.09% and 0.23% in the Geoservices data. Shorebased analyses of discrete samples by gas chromatography showed a gas composition with ~0.01 to 1.04% methane, 2 - 18 ppmv ethane, and 2 - 4 ppmv propane. Quadruple mass spectrometry yielded similar results for methane (0.04 to 4.98%). With δD values between -171‰ and -164‰, the stable hydrogen isotopic composition of methane showed little downhole variability. Although the two independent mud gas monitoring systems and shorebased analysis of discrete gas sample yielded different absolute concentrations they all agree well with respect to downhole variations of hydrocarbon gases. The data point to predominantly biogenic methane sources but suggest some contribution from thermogenic sources at depth, probably due

Formation and migration of Natural Gases: gas composition and isotopes as monitors between source, reservoir and seep

Science.gov (United States)

Schoell, M.; Etiope, G.

2015-12-01

Natural gases form in tight source rocks at temperatures between 120ºC up to 200ºC over a time of 40 to 50my depending on the heating rate of the gas kitchen. Inferring from pyrolysis experiments, gases after primary migration, a pressure driven process, are rich in C2+ hydrocarbons (C2 to C5). This is consistent with gas compositions of oil-associated gases such as in the Bakken Shale which occur in immediate vicinity of the source with little migration distances. However, migration of gases along porous rocks over long distances (up to 200km in the case of the Troll field offshore Norway) changes the gas composition drastically as C2+ hydrocarbons tend to be retained/sequestered during migration of gas as case histories from Virginia and the North Sea will demonstrate. Similar "molecular fractionation" is observed between reservoirs and surface seeps. In contrast to gas composition, stable isotopes in gases are, in general, not affected by the migration process suggesting that gas migration is a steady state process. Changes in isotopic composition, from source to reservoir to surface seeps, is often the result of mixing of gases of different origins. Examples from various gas provinces will support this notion. Natural gas basins provide little opportunity of tracking and identifying gas phase separation. Future research on experimental phase separation and monitoring of gas composition and gas ratio changes e.g. various C2+ compound ratios over C1 or isomer ratios such as iso/n ratios in butane and pentane may be an avenue to develop tracers for phase separation that could possibly be applied to natural systems of retrograde natural condensate fields.

Kinetics of a gas adsorption compressor

International Nuclear Information System (INIS)

Chan, C.K.; Elleman, D.D.; Tward, E.

1984-01-01

This chapter uses a two-phase model to analyze the transients of a gas adsorption compressor. The modeling of the adsorption process is based on complete thermal and mechanical equilibrium between the gaseous phase and the adsorbed gas phase. The theories and techniques that have been developed for a two-phase system are used to predict the pressure, the temperature and the mass flow transients in a gas sorption compressor. The analytical solutions are then compared with the performance of a laboratory gas adsorption compressor. A computer code was written to solve the governing equations, using a standard forward marching predictor-corrector method. It is found that while the analytical model overpredicts the pressure and the temperature transient, it predicts the general trend of the transient profile and the existence of the turning point

DYNAVAC: a transient-vacuum-network analysis code

International Nuclear Information System (INIS)

Deis, G.A.

1980-01-01

This report discusses the structure and use of the program DYNAVAC, a new transient-vacuum-network analysis code implemented on the NMFECC CDC-7600 computer. DYNAVAC solves for the transient pressures in a network of up to twenty lumped volumes, interconnected in any configuration by specified conductances. Each volume can have an internal gas source, a pumping speed, and any initial pressure. The gas-source rates can vary with time in any piecewise-linear manner, and up to twenty different time variations can be included in a single problem. In addition, the pumping speed in each volume can vary with the total gas pumped in the volume, thus simulating the saturation of surface pumping. This report is intended to be both a general description and a user's manual for DYNAVAC

On-line mass spectrometry measurement of fission gas release from nuclear fuel submitted to thermal transients

International Nuclear Information System (INIS)

Guigues, E.; Janulyte, A.; Zerega, Y.; Pontillon, Y.

2013-06-01

The work presented in this paper has been performed in the framework of a joint research program between Aix-Marseille University and CEA Cadarache. The aim is to develop a mass spectrometer (MS) device for the MERARG facility. MERARG is devoted to the study of fission gas release measurement, from nuclear fuels submitted to annealing tests in high activity laboratory such as LECA-STAR, thanks to gamma spectrometry. The mass spectrometer will then extend the measurement capability from the γ-emitters gases to all the gases involved in the release in order to have a better understanding of the fission gas release dynamics from fuel during thermal transients. Furthermore, the mass spectrometer instrument combines the capabilities and performances of both on-line (for release kinetic) and off-line implementations (for delayed accurate analysis of capacities containing total release gas). The paper deals with two main axes: (1) the modelling of gas sampling inlet device and its performance and (2) the first MS qualification/calibration results. The inlet device samples the gas and also adapts the pressure between MERARG sweeping line at 1.2 bar and mass spectrometer chamber at high vacuum. It is a two-stage device comprising a capillary at inlet, an intermediate vacuum chamber, a molecular leak inlet and a two-stage pumping device. Pressure drops, conductance and throughputs are estimated both for mass spectrometer operation and for exhaust gas recovery. Possible gas segregation is also estimated and device modification is proposed to attain a more accurate calibration. First experimental results obtained from a standard gas bottle show that the quantitative analysis at a few ppm level can be achieved for all isotopes of Kr and Xe, as well as masses 2 and 4 u. (authors)

Selectively gas-permeable composite membrane and process for production thereof

International Nuclear Information System (INIS)

Okita, K.; Asako, S.

1984-01-01

A selectively gas-permeable composite membrane and a process for producing said composite membrane are described. The composite membrane comprises a polymeric material support and a thin membrane deposited on the support, said thin membrane being obtained by glow discharge plasma polymerization of an organosilane compound containing at least one double bond or triple bond. Alternatively, the composite membrane comprises a polymeric material support having an average pore diameter of at least 0.1 micron, a hardened or cross-linked polyorganosiloxane layer on the support, and a thin membrane on the polyorganosiloxane layer, said thin membrane being obtained by plasma polymerization due to glow discharge of an organosilane compound containing at least one double bond or triple bond

Dew point, internal gas pressure, and chemical composition of the gas within the free volume of DWPF canistered waste forms

International Nuclear Information System (INIS)

Harbour, J.R.; Herman, D.T.; Crump, S.; Miller, T.J.; McIntosh, J.

1996-01-01

The Defense Waste Processing Facility (DWPF) produced 55 canistered waste forms containing simulated waste glass during the four Waste Qualification campaigns of the DWPF Startup Test Program. Testing of the gas within the free volume of these canisters for dew point, internal gas pressure, and chemical composition was performed as part of a continuing effort to demonstrate compliance with the Waste Acceptance Product Specifications. Results are presented for six glass-filled canisters. The dew points within the canisters met the acceptance criterion of < 20 degrees C for all six canisters. Factors influencing the magnitude of the dew point are presented. The chemical composition of the free volume gas was indistinguishable from air for all six canisters. Hence, no foreign materials were present in the gas phase of these canisters. The internal gas pressures within the sealed canisters were < 1 atm at 25 degrees C for all six canisters which readily met the acceptance criterion of an internal gas pressure of less than 1.5 atm at 25 degrees C. These results provided the evidence required to demonstrate compliance with the Waste Acceptance Product Specifications

Composite harm to plants by sulfurous acid gas and oxidant

Energy Technology Data Exchange (ETDEWEB)

Matsushima, J

1971-01-01

The composite effects on plants of sulfur dioxide and ozone, SO/sub 2/ and PAN, SO/sub 2/ and nitrogen dioxide, and NO/sub 2/ and ozone were studied. Pinto bean plants were exposed to SO/sub 2/ or O/sub 3/ only, to each gas alternately, and to a mixture of the two. The degree of injury by the gas or gases was indicated in percentage by area of the leaves damaged. In cases where no geometric effect occurred the damage to the plant by the individual gas had been great; damage from the individual gas had been slight in these cases where such an effect was observed. The geometric effect is produced when the density of SO/sub 2/ is rather low, generally 0.05-0.25 ppm. A mixture of SO/sub 2/ and O/sub 3/ was applied to a tabacco plant; it affected fully grown leaves. In experiments on the composite effects of SO/sub 2/ and PAN on bean, tomato and pepper plants, PAN affected mainly young leaves while SO/sub 2/ affected mature ones. These effects were arithmetric rather then geometric. The SO/sub 2/ and NO/sub 2/ were also studied in the same manner. When SO/sub 2/ and NO/sub 2/ were mixed, a geometric effect was conspicuous in damage to vegetables, the symptoms of damage by either of the two appeared about the same, younger leaves being affected less. When treated with the two gases alternately, the damage was greater if the plants were first treated with NO/sub 2/; possible causes for this effect are discussed. No significant composite effect of NO/sub 2/ and O/sub 3/ was observed.

Gas and porewater composition of shallow sediments in the Tuaheni Basin, New Zealand

Science.gov (United States)

Rose, P. S.; Coffin, R. B.; Yoza, B.; Boyd, T. J.; Crutchley, G. J.; Mountjoy, J. J.; Pecher, I. A.

2015-12-01

Seismic profiles collected during previous investigations on the Hikurangi Margin, off the North Island, New Zealand showed bottom simulating reflectors (BSRs), which are generally indicative of the presence of free gas. Further, double BSRs clearly identified in the Tuaheni Basin were hypothesized to result from differences in gas composition and fluid migration. During a cruise on the RV Tangaroa in June 2015 (TAN 1508) additional seismic data were collected and used to identify piston coring targets. Coring locations were selected to sample around BSR pinch-outs and possible fluid migration pathways to determine gas composition and flux. Shallow sediments collected in June 2015 in the Tuaheni Basin had relatively low sediment headspace CH4 concentrations (6000ppm. Higher molecular weight alkanes were not detected in the sediment headspace gas at any location. Sediment porewater sulfate, chloride and sulfide concentrations will be presented with CH4concentration profiles and geophysical data.

Modeling of oxygen gas diffusion and consumption during the oxic transient in a disposal cell of radioactive waste

International Nuclear Information System (INIS)

De Windt, Laurent; Marsal, François; Corvisier, Jérôme; Pellegrini, Delphine

2014-01-01

Highlights: • This paper deals with the geochemistry of underground HLW disposals. • The oxic transient is a key issue in performance assessment (e.g. corrosion, redox). • A reactive transport model is explicitly coupled to gas diffusion and reactivity. • Application to in situ experiment (Tournemire laboratory) and HLW disposal cell. • Extent of the oxidizing/reducing front is investigated by sensitivity analysis. - Abstract: The oxic transient in geological radioactive waste disposals is a key issue for the performance of metallic components that may undergo high corrosion rates under such conditions. A previous study carried out in situ in the argillite formation of Tournemire (France) has suggested that oxic conditions could have lasted several years. In this study, a multiphase reactive transport model is performed with the code HYTEC to analyze the balance between the kinetics of pyrite oxidative dissolution, the kinetics of carbon steel corrosion and oxygen gas diffusion when carbon steel components are emplaced in the geological medium. Two cases were modeled: firstly, the observations made in situ have been reproduced, and the model established was then applied to a disposal cell for high-level waste (HLW) in an argillaceous formation, taking into account carbon steel components and excavated damaged zones (EDZ). In a closed system, modeling leads to a complete and fast consumption of oxygen in both cases. Modeling results are more consistent with the in situ test while considering residual voids between materials and/or a water unsaturated state allowing for oxygen gas diffusion (open conditions). Under similar open conditions and considering ventilation of the handling drifts, a redox contrast occurs between reducing conditions at the back of the disposal cell (with anoxic corrosion of steel and H 2 production) and oxidizing conditions at the front of the cell (with oxic corrosion of steel). The extent of the oxidizing/reducing front in the

Transient two-dimensional flow in porous media

International Nuclear Information System (INIS)

Sharpe, L. Jr.

1979-01-01

The transient flow of an isothermal ideal gas from the cavity formed by an underground nuclear explosion is investigated. A two-dimensional finite element method is used in analyzing the gas flow. Numerical results of the pressure distribution are obtained for both the stemming column and the surrounding porous media

COMETHE III-M for transient fuel rod behaviour prediction

International Nuclear Information System (INIS)

Billaux, M.; Vliet, J. van

1983-01-01

The COMETHE III-M version is being developed in order to provide fuel rod behaviour prediction capability both in steady-state and in transient situations. It also allows to estimate the fuel rod enthalpy evolution versus time or burnup which may be important in core-related safety studies. This paper describes the transient heat transfer models, including transient heat conduction inside the fuel rod, and a subchannel model providing transient flow as well as enthalpy calculation capability. Transient fission gas release is also modelled on basis of the change rate of oxide temperature. The models are illustrated by a few calculation examples. (author)

Method and apparatus for real-time measurement of fuel gas compositions and heating values

Science.gov (United States)

Zelepouga, Serguei; Pratapas, John M.; Saveliev, Alexei V.; Jangale, Vilas V.

2016-03-22

An exemplary embodiment can be an apparatus for real-time, in situ measurement of gas compositions and heating values. The apparatus includes a near infrared sensor for measuring concentrations of hydrocarbons and carbon dioxide, a mid infrared sensor for measuring concentrations of carbon monoxide and a semiconductor based sensor for measuring concentrations of hydrogen gas. A data processor having a computer program for reducing the effects of cross-sensitivities of the sensors to components other than target components of the sensors is also included. Also provided are corresponding or associated methods for real-time, in situ determination of a composition and heating value of a fuel gas.

Effects of atmospheric gas composition and temperature on the gasification of coal in hot briquetting carbon composite iron ore

Energy Technology Data Exchange (ETDEWEB)

Ueki, Y.; Kanayama, M.; Maeda, T.; Nishika, K.; Shimizu, M. [Kyushu University, Fukuoka (Japan). Dept. of Materials Science & Engineering

2007-01-15

The gasification behavior of carbon composite iron ore produced by hot briquetting process was examined under various gas atmospheres such as CO-N{sub 2}, CO{sub 2}-N, and CO-CO{sub 2} at various temperatures. The gasification of coal was affected strongly by atmospheric gas concentration and reaction temperature. Kinetic analysis in various gas atmospheres was carried out by using the first order reaction model, which yields the straight line relation between reaction rate constants for the gasification of coal and the gas concentration. Therefore, reaction rate constants for the gasification of coal in CO-CO{sub 2}-N{sub 2} gas atmosphere were derived.

Gas separation by composite solvent-swollen membranes

Science.gov (United States)

Matson, Stephen L.; Lee, Eric K. L.; Friesen, Dwayne T.; Kelly, Donald J.

1989-01-01

There is disclosed a composite immobulized liquid membrane of a solvent-swollen polymer and a microporous organic or inorganic support, the solvent being at least one highly polar solvent containing at least one nitrogen, oxygen, phosphorous or sulfur atom, and having a boiling point of at least 100.degree. C. and a specified solubility parameter. The solvent or solvent mixture is homogeneously distributed through the solvent-swollen polymer from 20% to 95% by weight. The membrane is suitable for acid gas scrubbing and oxygen/nitrogen separation.

Gas separation by composite solvent-swollen membranes

Science.gov (United States)

Matson, S.L.; Lee, E.K.L.; Friesen, D.T.; Kelly, D.J.

1989-04-25

There is disclosed a composite immobilized liquid membrane of a solvent-swollen polymer and a microporous organic or inorganic support, the solvent being at least one highly polar solvent containing at least one nitrogen, oxygen, phosphorus or sulfur atom, and having a boiling point of at least 100 C and a specified solubility parameter. The solvent or solvent mixture is homogeneously distributed through the solvent-swollen polymer from 20% to 95% by weight. The membrane is suitable for acid gas scrubbing and oxygen/nitrogen separation. 3 figs.

Probing carrier dynamics of individual layers in a heterostructure using transient reflectivity

Energy Technology Data Exchange (ETDEWEB)

Khan, Salahuddin; Jayabalan, J., E-mail: jjaya@rrcat.gov.in; Singh, Asha; Yogi, Rachana; Chari, Rama [Laser Physics Applications Section, Raja Ramanna Centre for Advanced Technology, Indore 452013 (India)

2015-09-21

We report the wavelength dependent transient reflectivity measurements in AlGaAs-GaAs heterostructures having two-dimensional electron (or hole) gas near the interface. Using a multilayer model for transient reflectivity, we show that the magnitude and sign of contributions from the carriers in two-dimensional electron (or hole) gas and GaAs to the total signal depends on the wavelength. Further, it has been shown that it is possible to study the carrier dynamics in a given layer of a heterostructure by performing transient reflectivity at specific wavelengths.

Probing carrier dynamics of individual layers in a heterostructure using transient reflectivity

International Nuclear Information System (INIS)

Khan, Salahuddin; Jayabalan, J.; Singh, Asha; Yogi, Rachana; Chari, Rama

2015-01-01

We report the wavelength dependent transient reflectivity measurements in AlGaAs-GaAs heterostructures having two-dimensional electron (or hole) gas near the interface. Using a multilayer model for transient reflectivity, we show that the magnitude and sign of contributions from the carriers in two-dimensional electron (or hole) gas and GaAs to the total signal depends on the wavelength. Further, it has been shown that it is possible to study the carrier dynamics in a given layer of a heterostructure by performing transient reflectivity at specific wavelengths

The development of the fuel rod transient performance analysis code FTPAC

International Nuclear Information System (INIS)

Han Zhijie; Ji Songtao

2014-01-01

Fuel rod behavior, especially the integrity of cladding, played an important role in fuel safety research during reactor transient and hypothetical accidents conditions. In order to study fuel rod performance under transient accidents, FTPAC (Fuel Transient Performance Analysis Code) has been developed for simulating light water reactor fuel rod transient behavior when power or coolant boundary conditions are rapidly changing. It is composed of temperature, mechanical deformation, cladding oxidation and gas pressure model. The assessment was performed by comparing FTPAC code analysis result to experiments data and FRAPTRAN code calculations. Comparison shows that, the FTPAC gives reasonable agreement in temperature, deformation and gas pressure prediction. And the application of slip coefficient is more suitable for simulating the sliding between pellet and cladding when the gap is closed. (authors)

Numerical simulation coupling with experimental study on the non-uniform of each cylinder gas exchange and working processes of a multi-cylinder gasoline engine under transient conditions

International Nuclear Information System (INIS)

Zhou, Feng; Fu, Jianqin; Shu, Jun; Liu, Jingping; Wang, Shuqian; Feng, Renhua

2016-01-01

Highlights: • An approach is presented to detect the CTCV of engine under transient conditions. • The range and influence factors of CTCV of engine performances were revealed. • The maximum relative deviation of IMEP in each cylinder is larger than ±30%. • There appears a symmetry relation between CTCV of RGF and excess air coefficient. - Abstract: Cylinder-to-cylinder variation is unavoidable in multi-cylinder engine and has a severe impact on engine performance. To explore the cylinder-to-cylinder variation of engine under transient conditions, a hybrid method of dynamic signal measurement coupling with gas dynamics and thermodynamics processes simulation is presented to detect the parameters of engine. Then, this method is applied to an automobile engine under road test conditions, and the continuous state and performance parameters of each cylinder were obtained from cycle to cycle. On this basis, the range and influence factors of non-uniform of engine performance parameters were analyzed. The results show that, under transient conditions, the relative deviation of excess air coefficient in each cylinder is within ±5%, which is mainly affected by intake average pressure in low to medium speed operating regions but influenced by exhaust pressure wave and residual gas fraction in high-speed and high-load operating regions. There appears a symmetry relation between the non-uniform of RGF and excess air coefficient. The relative deviation of indicated mean effective pressure in each cylinder depends largely on the gas exchange performance, including excess air coefficient and residual gas fraction, and the maximum is larger than ±30%.

Autoresonant-spectrometric determination of the residual gas composition in the ALPHA experiment apparatus

Energy Technology Data Exchange (ETDEWEB)

Amole, C.; Capra, A.; Menary, S. [Department of Physics and Astronomy, York University, Toronto, Ontario M3J 1P3 (Canada); Ashkezari, M. D.; Hayden, M. E. [Department of Physics, Simon Fraser University, Burnaby, British Columbia V5A 1S6 (Canada); Baquero-Ruiz, M.; Chapman, S.; Little, A.; Povilus, A.; So, C.; Turner, M. [Department of Physics, University of California, Berkeley, California 94720-7300 (United States); Bertsche, W. [Department of Physics, Swansea University, Swansea SA2 8PP (United Kingdom); School of Physics and Astronomy, University of Manchester, Manchester M13 9PL, United Kingdom and The Cockcroft Institute, Daresbury Laboratory, Warrington WA4 4AD (United Kingdom); Butler, E. [Physics Department, CERN, CH-1211 Geneva 23 (Switzerland); Cesar, C. L.; Silveira, D. M. [Instituto de Fisica, Universidade Federal do Rio de Janeiro, Rio de Janeiro 21941-972 (Brazil); Charlton, M.; Eriksson, S.; Isaac, C. A.; Madsen, N.; Napoli, S. C. [Department of Physics, Swansea University, Swansea SA2 8PP (United Kingdom); Collaboration: ALPHA Collaboration; and others

2013-06-15

Knowledge of the residual gas composition in the ALPHA experiment apparatus is important in our studies of antihydrogen and nonneutral plasmas. A technique based on autoresonant ion extraction from an electrostatic potential well has been developed that enables the study of the vacuum in our trap. Computer simulations allow an interpretation of our measurements and provide the residual gas composition under operating conditions typical of those used in experiments to produce, trap, and study antihydrogen. The methods developed may also be applicable in a range of atomic and molecular trap experiments where Penning-Malmberg traps are used and where access is limited.

The impact of aerosol composition on the particle to gas partitioning of reactive mercury.

Science.gov (United States)

Rutter, Andrew P; Schauer, James J

2007-06-01

A laboratory system was developed to study the gas-particle partitioning of reactive mercury (RM) as a function of aerosol composition in synthetic atmospheric particulate matter. The collection of RM was achieved by filter- and sorbent-based methods. Analyses of the RM collected on the filters and sorbents were performed using thermal extraction combined with cold vapor atomic fluorescence spectroscopy (CVAFS), allowing direct measurement of the RM load on the substrates. Laboratory measurements of the gas-particle partitioning coefficients of RM to atmospheric aerosol particles revealed a strong dependence on aerosol composition, with partitioning coefficients that varied by orders of magnitude depending on the composition of the particles. Particles of sodium nitrate and the chlorides of potassium and sodium had high partitioning coefficients, shifting the RM partitioning toward the particle phase, while ammonium sulfate, levoglucosan, and adipic acid caused the RM to partition toward the gas phase and, therefore, had partitioning coefficients that were lower by orders of magnitude.

Thermodynamic properties calculation of the flue gas based on its composition estimation for coal-fired power plants

International Nuclear Information System (INIS)

Xu, Liang; Yuan, Jingqi

2015-01-01

Thermodynamic properties of the working fluid and the flue gas play an important role in the thermodynamic calculation for the boiler design and the operational optimization in power plants. In this study, a generic approach to online calculate the thermodynamic properties of the flue gas is proposed based on its composition estimation. It covers the full operation scope of the flue gas, including the two-phase state when the temperature becomes lower than the dew point. The composition of the flue gas is online estimated based on the routinely offline assays of the coal samples and the online measured oxygen mole fraction in the flue gas. The relative error of the proposed approach is found less than 1% when the standard data set of the dry and humid air and the typical flue gas is used for validation. Also, the sensitivity analysis of the individual component and the influence of the measurement error of the oxygen mole fraction on the thermodynamic properties of the flue gas are presented. - Highlights: • Flue gas thermodynamic properties in coal-fired power plants are online calculated. • Flue gas composition is online estimated using the measured oxygen mole fraction. • The proposed approach covers full operation scope, including two-phase flue gas. • Component sensitivity to the thermodynamic properties of flue gas is presented.

Extending Lean and Exhaust Gas Recirculation-Dilute Operating Limits of a Modern Gasoline Direct-Injection Engine Using a Low-Energy Transient Plasma Ignition System

Energy Technology Data Exchange (ETDEWEB)

Sevik, James; Wallner, Thomas; Pamminger, Michael; Scarcelli, Riccardo; Singleton, Dan; Sanders, Jason

2016-05-24

The efficiency improvement and emissions reduction potential of lean and exhaust gas recirculation (EGR)-dilute operation of spark-ignition gasoline engines is well understood and documented. However, dilute operation is generally limited by deteriorating combustion stability with increasing inert gas levels. The combustion stability decreases due to reduced mixture flame speeds resulting in significantly increased combustion initiation periods and burn durations. A study was designed and executed to evaluate the potential to extend lean and EGR-dilute limits using a low-energy transient plasma ignition system. The low-energy transient plasma was generated by nanosecond pulses and its performance compared to a conventional transistorized coil ignition (TCI) system operated on an automotive, gasoline direct-injection (GDI) single-cylinder research engine. The experimental assessment was focused on steady-state experiments at the part load condition of 1500 rpm 5.6 bar indicated mean effective pressure (IMEP), where dilution tolerance is particularly critical to improving efficiency and emission performance. Experimental results suggest that the energy delivery process of the low-energy transient plasma ignition system significantly improves part load dilution tolerance by reducing the early flame development period. Statistical analysis of relevant combustion metrics was performed in order to further investigate the effects of the advanced ignition system on combustion stability. Results confirm that at select operating conditions EGR tolerance and lean limit could be improved by as much as 20% (from 22.7 to 27.1% EGR) and nearly 10% (from λ = 1.55 to 1.7) with the low-energy transient plasma ignition system.

Grain-scale imaging and compositional characterization of cryo-preserved India NGHP 01 gas-hydrate-bearing cores

Science.gov (United States)

Stern, Laura A.; Lorenson, T.D.

2014-01-01

We report on grain-scale characteristics and gas analyses of gas-hydrate-bearing samples retrieved by NGHP Expedition 01 as part of a large-scale effort to study gas hydrate occurrences off the eastern-Indian Peninsula and along the Andaman convergent margin. Using cryogenic scanning electron microscopy, X-ray spectroscopy, and gas chromatography, we investigated gas hydrate grain morphology and distribution within sediments, gas hydrate composition, and methane isotopic composition of samples from Krishna–Godavari (KG) basin and Andaman back-arc basin borehole sites from depths ranging 26 to 525 mbsf. Gas hydrate in KG-basin samples commonly occurs as nodules or coarse veins with typical hydrate grain size of 30–80 μm, as small pods or thin veins 50 to several hundred microns in width, or disseminated in sediment. Nodules contain abundant and commonly isolated macropores, in some places suggesting the original presence of a free gas phase. Gas hydrate also occurs as faceted crystals lining the interiors of cavities. While these vug-like structures constitute a relatively minor mode of gas hydrate occurrence, they were observed in near-seafloor KG-basin samples as well as in those of deeper origin (>100 mbsf) and may be original formation features. Other samples exhibit gas hydrate grains rimmed by NaCl-bearing material, presumably produced by salt exclusion during original hydrate formation. Well-preserved microfossil and other biogenic detritus are also found within several samples, most abundantly in Andaman core material where gas hydrate fills microfossil crevices. The range of gas hydrate modes of occurrence observed in the full suite of samples suggests a range of formation processes were involved, as influenced by local in situconditions. The hydrate-forming gas is predominantly methane with trace quantities of higher molecular weight hydrocarbons of primarily microbial origin. The composition indicates the gas hydrate is Structure I.

Synthesis of Plate-Like Nanoalumina and Its Effect on Gas Permeability of Carbon Fiber Epoxy Composite

Directory of Open Access Journals (Sweden)

Ghadamali Karimi Khozani

2017-03-01

Full Text Available In recent years considerable efforts have been made to develop gas impermeable polymer systems. Compared with metal system counterparts they have advantages such as low density and production costs. The most important challenge in development of impermeable polymer systems is to reduce their gas permeability by proper selection of system composition and process conditions. In this work, nanoparticles were initially synthesized using Al (NO33•9H2O and sodium dodecyl sulfate as a structure-directing agent via hydrothermal method and a plate-like structure was characterized by FESEM and EDAX analyses. In the second step, epoxy/plate-like nanoalumina nanocomposites and epoxy-carbon fiber composites containing 1, 2.5, and 5 wt% nanoalumina were prepared. The effect of nanoparticle loading level on permeability of nitrogen, argon, and carbon dioxide in epoxy/plate-like nanoalumina nanocomposites was investigated. It was observed that the permeability of epoxy/plate-like nanoalumina nanocomposites toward nitrogen, argon, and carbon dioxide gases reduced 83%, 74%, and 50%, respectively. It was deduced that the permeability reduction was clearly associated with the diameter of gas molecules. Generally speaking, the results showed that the incorporation of plate-like nanoalumina particles significantly reduced the gas permeability. Also, carbon dioxide gas permeability of carbon fiber epoxy composites containing plate-like nanoalumina was investigated to show the effect of ingredients on the gas permeability of the system. The results indicated that carbon dioxide gas permeability of epoxy carbon fiber composite containing 5 wt% of plate-like nanoalumina was totally reduced 84%.

Transient Vibrations of an Elastic Cylinder Inserted in the Elastic Medium

Directory of Open Access Journals (Sweden)

Sulym Heorgij

2016-06-01

Full Text Available Using method of Laguerre polynomials we have obtained the solution of the dynamic problem of the theory of elasticity for elastic cylinder inserted into massive body modeled as a space. The source of non-stationary processes in composite is high intensity force load of the inner surface of the cylinder. On the surface separation of materials of space and cylinder the conditions of ideal mechanical contact are satisfied. The solution is obtained as series of Laguerre polynomials, which coefficients are found from recurrent relations. The results of numerical analysis of transient stress-strain state in elastic space with cylindrical insertion might be used for the technological process of hydraulic fracturing during shale gas extraction.

Measuring and understanding total dissolved gas pressure in groundwater

Science.gov (United States)

Ryan, C.; Roy, J. W.; Randell, J.; Castellon, L.

2009-05-01

Since dissolved gases are important to a number of aspects of groundwater (e.g. age dating, active or passive bioremediation, greenhouse gas fluxes, understanding biogeochemical processes involving gases, assessing potential impacts of coal bed methane activities), accurate concentration measurements, and understanding of their subsurface behaviour are important. Researchers have recently begun using total dissolved gas pressure (TGP) sensor measurements, more commonly applied for surface water monitoring, in concert with gas composition analyses to estimate more accurate groundwater gas concentrations in wells. We have used hydraulic packers to isolate the well screens where TDP is being measured, and pump tests to indicate that in-well degassing may reduce TDG below background groundwater levels. Thus, in gas-charged groundwater zones, TGPs can be considerably underestimated in the absence of pumping or screen isolation. We have also observed transient decreased TGPs during pumping that are thought to result from ebullition induced when the water table or water level in the well is lowered below a critical hydrostatic pressure.

Analysis of Precooling Injection Transient of Steam Generator for High Temperature Gas Cooled Reactor

Directory of Open Access Journals (Sweden)

Yan Wang

2017-01-01

Full Text Available After a postulated design basis accident leads high temperature gas cooled reactor to emergency shutdown, steam generator still remains with high temperature level and needs to be cooled down by a precooling before reactor restarts with clearing of fault. For the large difference of coolant temperature between inlet and outlet of steam generator in normal operation, the temperature distribution on the components of steam generator is very complicated. Therefore, the temperature descending rate of the components in steam generator needs to be limited to avoid the potential damage during the precooling stage. In this paper, a pebble-bed high temperature gas cooled reactor is modeled by thermal-hydraulic system analysis code and several postulated precooling injection transients are simulated and compared to evaluate their effects, which will provide support for the precooling design. The analysis results show that enough precooling injection is necessary to satisfy the precooling requirements, and larger mass flow rate of precooling water injection will accelerate the precooling process. The temperature decrease of steam generator is related to the precooling injection scenarios, and the maximal mass flow rate of the precooling injection should be limited to avoid the excessively quick temperature change of the structures in steam generator.

Effects of natural gas composition on performance and regulated, greenhouse gas and particulate emissions in spark-ignition engines

International Nuclear Information System (INIS)

Amirante, R.; Distaso, E.; Di Iorio, S.; Sementa, P.; Tamburrano, P.; Vaglieco, B.M.; Reitz, R.D.

2017-01-01

Highlights: • The influence of natural gas composition is investigated. • Real-time methane/propane fuel mixtures were realized. • IMEP, HRR and MBF were used to evaluate the effects on engine performance. • Gaseous, greenhouse and Particulate emissions were studied. • The propane content strongly influenced performance and emissions. - Abstract: In vehicles fueled with compressed natural gas, a variation in the fuel composition can have non-negligible effects on their performance, as well as on their emissions. The present work aimed to provide more insight on this crucial aspect by performing experiments on a single-cylinder port-fuel injected spark-ignition engine. In particular, methane/propane mixtures were realized to isolate the effects of a variation of the main constituents in natural gas on engine performance and associated pollutant emissions. The propane volume fraction was varied from 10 to 40%. Using an experimental procedure designed and validated to obtain precise real-time mixture fractions to inject directly into the intake manifold. Indicative Mean Effective Pressure, Heat Release Rate and Mass Burned Fraction were used to evaluate the effects on engine performance. Gaseous emissions were measured as well. Particulate Mass, Number and Size Distributions were analyzed with the aim to identify possible correlations existing between fuel composition and soot emissions. Emissions samples were taken from the exhaust flow, just downstream of the valves. Opacity was measured downstream the Three-Way Catalyst. Three different engine speeds were investigated, namely 2000, 3000 and 4000 rpm. Stoichiometric and full load conditions were considered in all tests. The results were compared with pure methane and propane, as well as with natural gas. The results indicated that both performance and emissions were strongly influenced by the variation of the propane content. Increasing the propane fraction favored more complete combustion and increased NO

Analysis of Water Hammer with Different Closing Valve Laws on Transient Flow of Hydrogen-Natural Gas Mixture

Directory of Open Access Journals (Sweden)

Norazlina Subani

2015-01-01

Full Text Available Water hammer on transient flow of hydrogen-natural gas mixture in a horizontal pipeline is analysed to determine the relationship between pressure waves and different modes of closing and opening of valves. Four types of laws applicable to closing valve, namely, instantaneous, linear, concave, and convex laws, are considered. These closure laws describe the speed variation of the hydrogen-natural gas mixture as the valve is closing. The numerical solution is obtained using the reduced order modelling technique. The results show that changes in the pressure wave profile and amplitude depend on the type of closing laws, valve closure times, and the number of polygonal segments in the closing function. The pressure wave profile varies from square to triangular and trapezoidal shape depending on the type of closing laws, while the amplitude of pressure waves reduces as the closing time is reduced and the numbers of polygonal segments are increased. The instantaneous and convex closing laws give rise to minimum and maximum pressure, respectively.

The OECD/NEA/NSC PBMR 400 MW coupled neutronics thermal hydraulics transient benchmark: transient results - 290

International Nuclear Information System (INIS)

Strydom, G.; Reitsma, F.; Ngeleka, P.T.; Ivanov, K.N.

2010-01-01

The PBMR is a High-Temperature Gas-cooled Reactor (HTGR) concept developed to be built in South Africa. The analysis tools used for core neutronic design and core safety analysis need to be verified and validated, and code-to-code comparisons are an essential part of the V and V plans. As part of this plan the PBMR 400 MWth design and a representative set of transient exercises are defined as an OECD benchmark. The scope of the benchmark is to establish a series of well defined multi-dimensional computational benchmark problems with a common given set of cross sections, to compare methods and tools in coupled neutronics and thermal hydraulics analysis with a specific focus on transient events. This paper describes the current status of the benchmark project and shows the results for the six transient exercises, consisting of three Loss of Cooling Accidents, two Control Rod Withdrawal transients, a power load-follow transient, and a Helium over-cooling Accident. The participants' results are compared using a statistical method and possible areas of future code improvement are identified. (authors)

Safety aspects of forced flow cooldown transients in modular high temperature gas-cooled reactors

International Nuclear Information System (INIS)

Kroeger, P.G.

1992-01-01

During some of the design basis accidents in Modular High Temperature Gas Cooled Reactors (MHTGRs) the main Heat Transport System (HTS) and the Shutdown Cooling System (SCS), are assumed to have failed. Decay heat is then removed by the passive Reactor Cavity Cooling System (RCCS) only. If either forced flow cooling system becomes available during such a transient, its restart could significantly reduce the down-time. This paper uses the THATCH code to examine whether such restart, during a period of elevated core temperatures, can be accomplished within safe limits for fuel and metal component temperatures. If the reactor is scrammed, either system can apparently be restarted at any time, without exceeding any safe limits. However, under unscrammed conditions a restart of forced cooling can lead to recriticality, with fuel and metal temperatures significantly exceeding the safety limits

Highly selective room temperature NO2 gas sensor based on rGO-ZnO composite

Science.gov (United States)

Jyoti, Kanaujiya, Neha; Varma, G. D.

2018-05-01

Blending metal oxide nanoparticles with graphene or its derivatives can greatly enhance gas sensing characteristics. In the present work, ZnO nanoparticles have been synthesized via reflux method. Thin films of reduced graphene oxide (rGO) and composite of rGO-ZnO have been fabricated by drop casting method for gas sensing application. The samples have been characterized by X-ray diffraction (XRD) and Field-emission scanning electron microscope (FESEM) for the structural and morphological studies respectively. Sensing measurements have been carried out for the composite film of rGO-ZnO for different concentrations of NO2 ranging from 4 to 100 ppm. Effect of increasing temperature on the sensing performance has also been studied and the rGO-ZnO composite sensor shows maximum percentage response at room temperature. The limit of detection (LOD) for rGO-ZnO composite sensor is 4ppm and it exhibits a high response of 48.4% for 40 ppm NO2 at room temperature. To check the selectivity of the composite sensor, sensor film has been exposed to 40 ppm different gases like CO, NH3, H2S and Cl2 at room temperature and the sensor respond negligibly to these gases. The present work suggests that rGO-ZnO composite material can be a better candidate for fabrication of highly selective room temperature NO2 gas sensor.

Gas composition of sludge residue profiles in a sludge treatment reed bed between loadings.

Science.gov (United States)

Larsen, Julie D; Nielsen, Steen M; Scheutz, Charlotte

2017-11-01

Treatment of sludge in sludge treatment reed bed systems includes dewatering and mineralization. The mineralization process, which is driven by microorganisms, produces different gas species as by-products. The pore space composition of the gas species provides useful information on the biological processes occurring in the sludge residue. In this study, we measured the change in composition of gas species in the pore space at different depth levels in vertical sludge residue profiles during a resting period of 32 days. The gas composition of the pore space in the sludge residue changed during the resting period. As the resting period proceeded, atmospheric air re-entered the pore space at all depth levels. The methane (CH 4 ) concentration was at its highest during the first part of the resting period, and then declined as the sludge residue became more dewatered and thereby aerated. In the pore space, the concentration of CH 4 often exceeded the concentration of carbon dioxide (CO 2 ). However, the total emission of CO 2 from the surface of the sludge residue exceeded the total emission of CH 4 , suggesting that CO 2 was mainly produced in the layer of newly applied sludge and/or that CO 2 was emitted from the sludge residue more readily compared to CH 4 .

Fuel rod behaviour during transients

International Nuclear Information System (INIS)

Hughes, H.; Haste, T.J.; Cameron, R.F.; Sinclair, J.E.

1982-04-01

The fuel pin performance code SLEUTH, the transient codes FRAP-T5 and TRAFIC and the clad deformation code CANSWEL-2 are described. It is shown how the codes treat gas release, pin cooling, cladding deformation and interaction, gap conductance etc. The materials properties used are indicated. (author)

Experimental and numerical study on transient heat transfer for helium gas flowing over a twisted plate with different length

International Nuclear Information System (INIS)

Wang, Li; Liu, Qiusheng; Fukuda, Katsuya

2015-01-01

This study was conducted to investigate the transient heat transfer process between the solid surface and the coolant (helium gas) in Very High Temperature Reactor (VHTR). Forced convection transient heat transfer for helium gas flowing over a twisted plate with different length was experimentally and theoretically studied. The heat generation rate of the twisted plate was increased with a function of Q = Q_0exp(t/τ)(where t is time, τ is period). Experiment was carried out at various periods ranged from 35 ms to 14 s and gas temperature of 303 K under 500 kPa. The flow velocities ranged from 4 m/s to 10 m/s. Platinum plates with a thickness of 0.1 mm and width of 4 mm were used as the test heaters. The plates were twisted with the same helical pitch of 20 mm, and length of 26.8 mm, 67.8 mm and 106.4 mm (pitch numbers of 1, 3 and 5), respectively. Based on the experimental data, it was found that the average heat transfer coefficient approaches the quasi-steady-state value when the dimensionless period τ* (τ* = τU/L, U is flow velocity, and L is effective length) is larger than about 100 and it becomes higher when τ* is small. The heat transfer coefficient decreases with the increase of twisted plate length under the same period of heat generation rate. According to the experimental data, the distribution for heat transfer coefficient along the heater is nonlinear. Numerical simulation results were obtained for average surface temperature difference, heat flux and heat transfer coefficient of the twisted plates with different length and showed reasonable agreement with experimental data. Based on the numerical simulation, mechanism of local heat transfer coefficient distribution was clarified. (author)

Carbon-fiber composite molecular sieves for gas separation

Energy Technology Data Exchange (ETDEWEB)

Jagtoyen, M.; Derbyshire, F. [Univ. of Kentucky, Lexington, KY (United States)

1996-08-01

This report describes continuing work on the activation and characterization of formed carbon fiber composites. The composites are produced at the Oak Ridge National Laboratory (ORNL) and activated at the Center for Applied Energy Research (CAER) using steam, CO{sub 2}, or O{sub 2} at different conditions of temperature and time, and with different furnace configurations. The general aims of the project are to produce uniformly activated samples with controlled pore structures for specialist applications such as gas separation and water treatment. In previous work the authors reported that composites produced from isotropic pitch fibers weighing up to 25g can be uniformly activated through the appropriate choice of reaction conditions and furnace configurations. They have now succeeded in uniformly activating composites of dimensions up to 12 x 7 x 6 cm, or up to about 166 gram - a scale-up factor of about six. Part of the work has involved the installation of a new furnace that can accommodate larger composites. Efforts were made to achieve uniform activation in both steam and CO{sub 2}. The authors have also succeeded in producing materials with very uniform and narrow pore size distributions by using a novel method involving low temperature oxygen chemisorption in combination with heat treatment in N{sub 2} at high temperatures. Work has also started on the activation of PAN based carbon fibers and fiber composites with the aim of producing composites with wide pore structures for use as catalyst supports. So far activation of the PAN fiber composites supplied by ORNL has been difficult which is attributed to the low reactivity of the PAN fibers. As a result, studies are now being made of the activation of the PAN fibers to investigate the optimum carbonization and activation conditions for PAN based fibers.

Multi Parameter Flow Meter for On-Line Measurement of Gas Mixture Composition

Directory of Open Access Journals (Sweden)

Egbert van der Wouden

2015-04-01

Full Text Available In this paper we describe the development of a system and model to analyze the composition of gas mixtures up to four components. The system consists of a Coriolis mass flow sensor, density, pressure and thermal flow sensor. With this system it is possible to measure the viscosity, density, heat capacity and flow rate of the medium. In a next step the composition can be analyzed if the constituents of the mixture are known. This makes the approach universally applicable to all gasses as long as the number of components does not exceed the number of measured properties and as long as the properties are measured with a sufficient accuracy. We present measurements with binary and ternary gas mixtures, on compositions that range over an order of magnitude in value for the physical properties. Two platforms for analyses are presented. The first platform consists of sensors realized with MEMS fabrication technology. This approach allows for a system with a high level of integration. With this system we demonstrate a proof of principle for the analyses of binary mixtures with an accuracy of 10%. In the second platform we utilize more mature steel sensor technology to demonstrate the potential of this approach. We show that with this technique, binary mixtures can be measured within 1% and ternary gas mixtures within 3%.

Gas sensing properties of graphene–WO3 composites prepared by hydrothermal method

International Nuclear Information System (INIS)

Chu, Xiangfeng; Hu, Tao; Gao, Feng; Dong, Yongping; Sun, Wenqi; Bai, Linshan

2015-01-01

Graphical abstract: - Highlights: • The amount of graphene had an effect on the morphology of graphene–WO 3 composites. • The optimum temperature of 0.1 wt% graphene–WO 3 sensor to acetaldehyde was 100 °C. • 0.1 wt% graphene–WO 3 sensor exhibited good selectivity to acetaldehyde at 100 °C. - Abstract: Graphene–WO 3 composites mixed with different amounts of graphene (0, 0.1, 0.5, 1 and 3 wt%) were prepared by hydrothermal method at 180 °C for 24 h. The as-prepared graphite oxide, graphene and graphene–WO 3 composites were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), Fourier transform infrared spectra (FT-IR) and Raman spectroscopy, respectively. The effect of the amount of graphene in the composites on the gas-sensing responses and the gas-sensing selectivity of the materials was investigated. The experimental results revealed that the sensor based on 0.1 wt% graphene–WO 3 composite exhibited high response and good selectivity to acetaldehyde vapor at 100 °C, the optimum operating temperature of this sensor to 1000 ppm acetaldehyde vapor decreased from 180 °C to 100 °C comparing with that of pure WO 3 . The response time and the recovery time for 100 ppm acetaldehyde vapor were 250 s and 225 s, respectively

Temporal variation of soil gas compositions for earthquake surveillance in Taiwan

International Nuclear Information System (INIS)

Walia, Vivek; Yang, Tsanyao Frank; Lin, Shih-Jung; Kumar, Arvind; Fu, Ching-Chou; Chiu, Jun-Ming; Chang, Hsaio-Hsien; Wen, Kuo-Liang; Chen, Cheng-Hong

2013-01-01

The present study is proposed to investigate temporal variations of soil–gas composition in the vicinity of different fault zones in Taiwan. To carry out the investigations, variations of soil–gases compositions were measured at continuous earthquake monitoring stations along Hsincheng and Hsinhua faults in Hsinchu and Tainan areas, respectively. Before selecting a monitoring site, the occurrence of deeper gas emanation was investigated by the soil–gas surveys and followed by continuous monitoring of some selected sites with respect to tectonic activity to check the sensitivity of the sites. Based on the results of long term geochemical monitoring at the established monitoring stations we can divide the studied area in two different tectonic zones. We proposed tectonic based model for earthquake forecasting in Taiwan and tested it for some big earthquakes occurred during observation period i.e. 2009–2010. Based on the anomalous signatures from particular monitoring stations we are in a state to identify the area for impending earthquakes of magnitude ≥5 and we have tested it for some earthquakes which rocked the country during that period. It can be concluded from above results that the stress/strain transmission for a particular earthquake is hindered by different tectonic settings of the region under study. - Highlights: ► Variations of soil–gases composition is studied at two different faults of Taiwan. ► Tectonic based model for earthquake forecasting in Taiwan was proposed and tested. ► Selection criteria to identify threshold earthquakes have been defined. ► Stress/strain transmission for earthquake may be hindered by tectonic settings

Transient Analysis of a Gas-cooled Fast Reactor for Single Control Assembly Withdrawal

International Nuclear Information System (INIS)

Choi, Hangbok

2014-01-01

The Energy Multiplier Module (EMZ) system response has been evaluated for control assembly withdrawal transients. Currently the EM2 core is equipped with six cylindrical drum-type control assemblies in the reflector zone for excess reactivity control and power maneuvering during the operating core life. This study investigates the system response to the control assembly withdrawal accident with various rotational speeds and reactivity worth to determine feasible control assembly design requirements from the physics viewpoint. The simulations have been conducted for single control assembly withdrawal transients without scram by a gas-cooled reactor plant simulator, which is based on a simplified plant nodal model, including the point reactor kinetics, single channel core thermal-fluid model, and a turbo-machinery performance model. Simulations were conducted for the middle-of- cycle core, when the excess reactivity of the core is the highest. Control assembly withdrawal times were varied from 1 (runaway) to 180 sec and reactivity worth was varied from 100 to 400 pcm. For a single control assembly withdrawal, the simulation has shown that the peak fuel temperature is expected to be ~1820°C when the assembly worth is 200 pcm and the runaway time is 1 sec per 180 degree rotation. The peak temperature could be reduced to ~1780°C if the assembly is rotated out in a moderate speed such as 1 degree/sec. These peak temperatures give a thermal margin of 22 to 24% to the melting point of uranium carbide fuel. The results also indicate that the current design with a single control assembly worth of 314 pcm may need adjustments in the future design. (author)

Greenhouse Gas and Noxious Emissions from Dual Fuel Diesel and Natural Gas Heavy Goods Vehicles.

Science.gov (United States)

Stettler, Marc E J; Midgley, William J B; Swanson, Jacob J; Cebon, David; Boies, Adam M

2016-02-16

Dual fuel diesel and natural gas heavy goods vehicles (HGVs) operate on a combination of the two fuels simultaneously. By substituting diesel for natural gas, vehicle operators can benefit from reduced fuel costs and as natural gas has a lower CO2 intensity compared to diesel, dual fuel HGVs have the potential to reduce greenhouse gas (GHG) emissions from the freight sector. In this study, energy consumption, greenhouse gas and noxious emissions for five after-market dual fuel configurations of two vehicle platforms are compared relative to their diesel-only baseline values over transient and steady state testing. Over a transient cycle, CO2 emissions are reduced by up to 9%; however, methane (CH4) emissions due to incomplete combustion lead to CO2e emissions that are 50-127% higher than the equivalent diesel vehicle. Oxidation catalysts evaluated on the vehicles at steady state reduced CH4 emissions by at most 15% at exhaust gas temperatures representative of transient conditions. This study highlights that control of CH4 emissions and improved control of in-cylinder CH4 combustion are required to reduce total GHG emissions of dual fuel HGVs relative to diesel vehicles.

SCANAIR: A transient fuel performance code

International Nuclear Information System (INIS)

Moal, Alain; Georgenthum, Vincent; Marchand, Olivier

2014-01-01

Highlights: • Since the early 1990s, the code SCANAIR is developed at IRSN. • The software focuses on studying fast transients such as RIA in light water reactors. • The fuel rod modelling is based on a 1.5D approach. • Thermal and thermal-hydraulics, mechanical and gas behaviour resolutions are coupled. • The code is used for safety assessment and integral tests analysis. - Abstract: Since the early 1990s, the French “Institut de Radioprotection et de Sûreté Nucléaire” (IRSN) has developed the SCANAIR computer code with the view to analysing pressurised water reactor (PWR) safety. This software specifically focuses on studying fast transients such as reactivity-initiated accidents (RIA) caused by possible ejection of control rods. The code aims at improving the global understanding of the physical mechanisms governing the thermal-mechanical behaviour of a single rod. It is currently used to analyse integral tests performed in CABRI and NSRR experimental reactors. The resulting validated code is used to carry out studies required to evaluate margins in relation to criteria for different types of fuel rods used in nuclear power plants. Because phenomena occurring during fast power transients are complex, the simulation in SCANAIR is based on a close coupling between several modules aimed at modelling thermal, thermal-hydraulics, mechanical and gas behaviour. During the first stage of fast power transients, clad deformation is mainly governed by the pellet–clad mechanical interaction (PCMI). At the later stage, heat transfers from pellet to clad bring the cladding material to such high temperatures that the boiling crisis might occurs. The significant over-pressurisation of the rod and the fact of maintaining the cladding material at elevated temperatures during a fairly long period can lead to ballooning and possible clad failure. A brief introduction describes the context, the historical background and recalls the main phenomena involved under

SCANAIR: A transient fuel performance code

Energy Technology Data Exchange (ETDEWEB)

Moal, Alain, E-mail: alain.moal@irsn.fr; Georgenthum, Vincent; Marchand, Olivier

2014-12-15

Highlights: • Since the early 1990s, the code SCANAIR is developed at IRSN. • The software focuses on studying fast transients such as RIA in light water reactors. • The fuel rod modelling is based on a 1.5D approach. • Thermal and thermal-hydraulics, mechanical and gas behaviour resolutions are coupled. • The code is used for safety assessment and integral tests analysis. - Abstract: Since the early 1990s, the French “Institut de Radioprotection et de Sûreté Nucléaire” (IRSN) has developed the SCANAIR computer code with the view to analysing pressurised water reactor (PWR) safety. This software specifically focuses on studying fast transients such as reactivity-initiated accidents (RIA) caused by possible ejection of control rods. The code aims at improving the global understanding of the physical mechanisms governing the thermal-mechanical behaviour of a single rod. It is currently used to analyse integral tests performed in CABRI and NSRR experimental reactors. The resulting validated code is used to carry out studies required to evaluate margins in relation to criteria for different types of fuel rods used in nuclear power plants. Because phenomena occurring during fast power transients are complex, the simulation in SCANAIR is based on a close coupling between several modules aimed at modelling thermal, thermal-hydraulics, mechanical and gas behaviour. During the first stage of fast power transients, clad deformation is mainly governed by the pellet–clad mechanical interaction (PCMI). At the later stage, heat transfers from pellet to clad bring the cladding material to such high temperatures that the boiling crisis might occurs. The significant over-pressurisation of the rod and the fact of maintaining the cladding material at elevated temperatures during a fairly long period can lead to ballooning and possible clad failure. A brief introduction describes the context, the historical background and recalls the main phenomena involved under

Preparation of sulfur/multiple pore size porous carbon composite via gas-phase loading method for lithium-sulfur batteries

International Nuclear Information System (INIS)

Li, Long-Yan; Chen, Yan-Xiao; Guo, Xiao-Dong; Zhong, Ben-He; Zhong, Yan-Jun

2014-01-01

A porous carbon with multiple pore size distribution was synthesized, and regarded as a carrier to obtain the sulfur/carbon (S/C) composite via a gas-phase loading method. We proposed this novel gas-phase loading method by using a specially designed fluid-bed reactor to encapsulate and sequester gas-phase sulfur molecules into the porous carbon in current study. The nitrogen Brunauer-Emmett-Teller (BET), scanning electron microscopy (SEM) and X-ray powder diffraction (XRD) characterizations were investigated on both the porous carbon and the sulfur/carbon composite. The results show that the gas-phase loading method contributes to the combination of sulfur molecules and matrix porous carbon. Furthermore, the sulfur/multiple pore size distribution carbon composite based on the gas-phase loading method demonstrate an excellent electrochemical property. The initial specific discharge capacity is 795.0 mAh g −1 at 800 mA g −1 , with a capacity retention of 86.3% after 100 cycles

Transient compressible flows in porous media

International Nuclear Information System (INIS)

Morrison, F.A. Jr.

1975-09-01

Transient compressible flow in porous media was investigated analytically. The major portion of the investigation was directed toward improving and understanding of dispersion in these flows and developing rapid accurate numerical techniques for predicting the extent of dispersion. The results are of interest in the containment of underground nuclear experiments. The transient one-dimensional transport of a trace component in a gas flow is analyzed. A conservation equation accounting for the effects of convective transport, dispersive transport, and decay, is developed. This relation, as well as a relation governing the fluid flow, is used to predict trace component concentration as a function of position and time. A detailed analysis of transport associated with the isothermal flow of an ideal gas is done. Because the governing equations are nonlinear, numerical calculations are performed. The ideal gas flow is calculated using a highly stable implicit iterative procedure with an Eulerian mesh. In order to avoid problems of anomolous dispersion associated with finite difference calculation, trace component convection and dispersion are calculated using a Lagrangian mesh. Details of the Eulerian-Lagrangian numerical technique are presented. Computer codes have been developed and implemented on the Lawrence Livermore Laboratory computer system

Impact of Load Behavior on Transient Stability and Power Transfer Limitations

DEFF Research Database (Denmark)

Gordon, Mark

2009-01-01

This paper presents utility based load modeling practices and explores the interaction between loads and the power system and the effect of the interaction on transient stability and power transfer limitations. The effect of load composition is investigated at major load centers together with the......This paper presents utility based load modeling practices and explores the interaction between loads and the power system and the effect of the interaction on transient stability and power transfer limitations. The effect of load composition is investigated at major load centers together...... with the impact on rotor angle excursions of large scale generators during the transient and post-transient period. Responses of multi-induction motor stalling are also considered for different fault clearances in the system. Findings of the investigations carried out on the Eastern Australian interconnected...

Transient fission gas release during direct electrical heating experiments

International Nuclear Information System (INIS)

Fenske, G.R.; Emerson, J.E.; Savoie, F.E.

1983-12-01

The gas release behavior of irradiated EBR-II fuel was observed to be dependent on several factors: the presence of cladding, the retained gas content, and the energy absorbed. Fuel that retained in excess of 16 to 17 μmoles/g of fission gas underwent spallation as the cladding melted and released 22 to 45% of its retained gas, while fuel with retained gas levels below approx. 15 to 16 μmoles/g released less than approx. 9% of its gas as the cladding melted. During subsequent direct electrical heating ramps, fuel that did not spall released an additional quantity of gas (up to 4 μmoles/g), depending on the energy absorbed

Transient Characteristics of Free Piston Vuilleurnier Cycle Heat Pumps

Science.gov (United States)

Matsue, Junji; Fujimoto, Norioki; Shirai, Hiroyuki

A dynamic analysis of a free piston Vuilleumier cycle heat pump was performed using a time-stepping integration method to investigate transient characteristics under power controlling. The nonlinear relationship between displacement and force for pistons was taken into account for the motion of reciprocating components. The force for pistons is mainly caused by the pressure change of working gas varying with piston displacements; moreover nonlinear viscous dissipative force due to the oscillating flow of working gas in heat exchangers and discontinuous damping force caused by solid friction at piston seals and rod seals are included. The displacements of pistons and pressure changes in the Vuilleumier cycle heat pump were integrated by an ideal isothermal thermodynamic relationship. It was assumed that the flow friction was proportional to the kinematic pressure of working gas, and that the solid friction at the seals was due to the functions of the working gas pressure and the tension of seal springs. In order to investigate the transient characteristics of a proposed free piston Vuilleumier cycle heat pump machine when hot-side working gas temperatures and alternate force were changed, some calculations were performed and discussed. These calculation results make clear transient characteristics at starting and power controlling. It was further found that only a small amount of starter power is required in particular conditions. During controlling, the machine becomes unstable when there is ar elatively large reduction in cooling or heating power. Therefore, an auxiliary device is additionally needed to obtain stable operation, such as al inear motor.

Rio Blanco gas composition: preproduction testing of the RBE-01 wellhead

International Nuclear Information System (INIS)

Smith, C.F.; Fontanilla, J.E.

1976-01-01

The chemical composition and radionuclide concentration of Rio Blanco gas samples collected prior to the production testing of the RBE-01 well and analyzed at LLL are presented. The analytical procedures and their uncertainties are briefly summarized. Information that associates the analytical data with the field operations is included

Gas fired boilers: Perspective for near future fuel composition and impact on burner design process

Science.gov (United States)

Schiro, Fabio; Stoppato, Anna; Benato, Alberto

2017-11-01

The advancements on gas boiler technology run in parallel with the growth of renewable energy production. The renewable production will impact on the fuel gas quality, since the gas grid will face an increasing injection of alternative fuels (biogas, biomethane, hydrogen). Biogas allows producing energy with a lower CO2 impact; hydrogen production by electrolysis can mitigate the issues related to the mismatch between energy production by renewable and energy request. These technologies will contribute to achieve the renewable production targets, but the impact on whole fuel gas production-to-consumption chain must be evaluated. In the first part of this study, the Authors present the future scenario of the grid gas composition and the implications on gas fed appliances. Given that the widely used premixed burners are currently designed mainly by trial and error, a broader fuel gas quality range means an additional hitch on this design process. A better understanding and structuring of this process is helpful for future appliance-oriented developments. The Authors present an experimental activity on a premixed condensing boiler setup. A test protocol highlighting the burners' flexibility in terms of mixture composition is adopted and the system fuel flexibility is characterized around multiple reference conditions.

Gas fired boilers: Perspective for near future fuel composition and impact on burner design process

Directory of Open Access Journals (Sweden)

Schiro Fabio

2017-01-01

Full Text Available The advancements on gas boiler technology run in parallel with the growth of renewable energy production. The renewable production will impact on the fuel gas quality, since the gas grid will face an increasing injection of alternative fuels (biogas, biomethane, hydrogen. Biogas allows producing energy with a lower CO2 impact; hydrogen production by electrolysis can mitigate the issues related to the mismatch between energy production by renewable and energy request. These technologies will contribute to achieve the renewable production targets, but the impact on whole fuel gas production-to-consumption chain must be evaluated. In the first part of this study, the Authors present the future scenario of the grid gas composition and the implications on gas fed appliances. Given that the widely used premixed burners are currently designed mainly by trial and error, a broader fuel gas quality range means an additional hitch on this design process. A better understanding and structuring of this process is helpful for future appliance-oriented developments. The Authors present an experimental activity on a premixed condensing boiler setup. A test protocol highlighting the burners' flexibility in terms of mixture composition is adopted and the system fuel flexibility is characterized around multiple reference conditions.

Fabrication of AlN-TiC/Al composites by gas injection processing

Institute of Scientific and Technical Information of China (English)

YU Huashun; CHEN Hongmei; MA Rendian; MIN Guanghui

2006-01-01

The fabrication of AlN-TiC/Al composites by carbon-and nitrogen-containing gas injection into Al-Mg-Ti melts was studied. It was shown that AlN and TiC particles could be formed by the in situ reaction of mixture gas (N2+C2H2+NH3) with Al-Mg-Ti melts. The condition for the formation of AlN was that the treatment temperature must be higher than 1373 K, and the amounts of AlN and TiC increased with the increase of the treatment temperature and the gas injection time.It was considered that AlN was formed by the direct reaction of Al with nitrogen-containing gas at the interface of the gas bubble and the melt. However, the mechanism of TiC formation is a combination mechanism of solution-precipitation and solid-liquid reaction.

Estimation of internal heat transfer coefficients and detection of rib positions in gas turbine blades from transient surface temperature measurements

International Nuclear Information System (INIS)

Heidrich, P; Wolfersdorf, J v; Schmidt, S; Schnieder, M

2008-01-01

This paper describes a non-invasive, non-destructive, transient inverse measurement technique that allows one to determine internal heat transfer coefficients and rib positions of real gas turbine blades from outer surface temperature measurements after a sudden flow heating. The determination of internal heat transfer coefficients is important during the design process to adjust local heat transfer to spatial thermal load. The detection of rib positions is important during production to fulfill design and quality requirements. For the analysis the one-dimensional transient heat transfer problem inside of the turbine blade's wall was solved. This solution was combined with the Levenberg-Marquardt method to estimate the unknown boundary condition by an inverse technique. The method was tested with artificial data to determine uncertainties with positive results. Then experimental testing with a reference model was carried out. Based on the results, it is concluded that the presented inverse technique could be used to determine internal heat transfer coefficients and to detect rib positions of real turbine blades.

Transient Thermal Response of Lightweight Cementitious Composites Made with Polyurethane Foam Waste

Science.gov (United States)

Kismi, M.; Poullain, P.; Mounanga, P.

2012-07-01

The development of low-cost lightweight aggregate (LWA) mortars and concretes presents many advantages, especially in terms of lightness and thermal insulation performances of structures. Low-cost LWA mainly comes from the recovery of vegetal or plastic wastes. This article focuses on the characterization of the thermal conductivity of innovative lightweight cementitious composites made with fine particles of rigid polyurethane (PU) foam waste. Five mortars were prepared with various mass substitution rates of cement with PU-foam particles. Their thermal conductivity was measured with two transient methods: the heating-film method and the hot-disk method. The incorporation of PU-foam particles causes a reduction of up to 18 % of the mortar density, accompanied by a significant improvement of the thermal insulating performance. The effect of segregation on the thermal properties of LWA mortars due to the differences of density among the cementitious matrix, sand, and LWA has also been quantified. The application of the hot-disk method reveals a gradient of thermal conductivity along the thickness of the specimens, which could be explained by a non-uniform repartition of fine PU-foam particles and mineral aggregates within the mortars. The results show a spatial variation of the thermal conductivity of the LWA mortars, ranging from 9 % to 19 %. However, this variation remains close to or even lower than that observed on a normal weight aggregate mortar. Finally, a self-consistent approach is proposed to estimate the thermal conductivity of PU-foam cement-based composites.

Production of ammonia from plasma-catalytic decomposition of urea: Effects of carrier gas composition.

Science.gov (United States)

Fan, Xing; Li, Jian; Qiu, Danqi; Zhu, Tianle

2018-04-01

Effects of carrier gas composition (N 2 /air) on NH 3 production, energy efficiency regarding NH 3 production and byproducts formation from plasma-catalytic decomposition of urea were systematically investigated using an Al 2 O 3 -packed dielectric barrier discharge (DBD) reactor at room temperature. Results show that the presence of O 2 in the carrier gas accelerates the conversion of urea but leads to less generation of NH 3 . The final yield of NH 3 in the gas phase decreased from 70.5%, 78.7%, 66.6% and 67.2% to 54.1%, 51.7%, 49.6% and 53.4% for applied voltages of 17, 19, 21 and 23kV, respectively when air was used as the carrier gas instead of N 2 . From the viewpoint of energy savings, however, air carrier gas is better than N 2 due to reduced energy consumption and increased energy efficiency for decomposition of a fixed amount of urea. Carrier gas composition has little influence on the major decomposition pathways of urea under the synergetic effects of plasma and Al 2 O 3 catalyst to give NH 3 and CO 2 as the main products. Compared to a small amount of N 2 O formed with N 2 as the carrier gas, however, more byproducts including N 2 O and NO 2 in the gas phase and NH 4 NO 3 in solid deposits were produced with air as the carrier gas, probably due to the unproductive consumption of NH 3 , the possible intermediate HNCO and even urea by the abundant active oxygen species and nitrogen oxides generated in air-DBD plasma. Copyright © 2017. Published by Elsevier B.V.

Chemically designed Pt/PPy nano-composite for effective LPG gas sensor.

Science.gov (United States)

Gaikwad, Namrata; Bhanoth, Sreenu; More, Priyesh V; Jain, G H; Khanna, P K

2014-03-07

Simultaneous in situ reduction of hexachloroplatinic acid by the amine group in the pyrrole monomer and oxidation of pyrrole to form polypyrrole (PPy) was examined. The reactions were performed at various temperatures to understand the degree of reduction of platinum precursor as well as doping of polypyrrole with Pt(II) chloro-complex. Spectroscopic images revealed different morphologies for the Pt/PPy nano-composite prepared at various temperatures. The as-prepared Pt/PPy nano-composite samples were tested for their ability to sense liquefied petroleum gas (LPG) which resulted in excellent sensing at relatively low temperature. The porous nature and ohmic contact between the PPy and platinum nanoparticles makes the as-prepared Pt/PPy nano-composite highly useful for sensors as well as electronic applications.

Variable composition hydrogen/natural gas mixtures for increased engine efficiency and decreased emissions

Energy Technology Data Exchange (ETDEWEB)

Sierens, R.; Rosseel, E.

2000-01-01

It is well known that adding hydrogen to natural gas extends the lean limit of combustion and that in this way extremely low emission levels can be obtained: even the equivalent zero emission vehicle (EZEV) requirements can be reached. The emissions reduction is especially important at light engine loads. In this paper results are presented for a GM V8 engine. Natural gas, pure hydrogen and different blends of these two fuels have been tested. The fuel supply system used provides natural gas/hydrogen mixtures in variable proportion, regulated independently of the engine operating condition. The influence of the fuel composition on the engine operating characteristics and exhaust emissions has been examined, mainly but not exclusively for 10 and 20% hydrogen addition. At least 10% hydrogen addition is necessary for a significant improvement in efficiency. Due to the conflicting requirements for low hydrocarbons and low NO{sub x} determining the optimum hythane composition is not straight-forward. For hythane mixtures with a high hydrogen fraction, it is found that a hydrogen content of 80% or less guarantees safe engine operation (no backfire nor knock), whatever the air excess factor. It is shown that to obtain maximum engine efficiency for the whole load range while taking low exhaust emissions into account, the mixture composition should be varied with respect to engine load.

Modelling for near-surface interaction of lithium ceramics and sweep-gas by use of cellular automation

International Nuclear Information System (INIS)

Shimura, K.; Terai, T.; Yamawaki, M.; Yamaguchi, K.

2003-01-01

Tritium release from the lithium ceramics as a fusion reactor breeder material is strongly affected by the composition of the sweep-gas as result of its influences with the material's surface. The typical surface processes which play important roles are adsorption, desorption and interaction between vacancy site and the constituents of the sweep-gas. Among a large number of studies and models, yet it seems to be difficult to model the overall behaviour of those processes due to its complex time-transient nature. In the present work the coarse grained atomic simulation based on the Cellular Automaton (CA) is used to model the dynamics of near-surface interaction between Li 2 O surface and sweep-gas that is consisting of a noble gas, hydrogen gas and water vapour. (author)

Burned gas and unburned mixture composition prediction in biodiesel-fuelled compression igniton engine

International Nuclear Information System (INIS)

Chuepeng, S.; Komintarachati, C.

2009-01-01

A prediction of burned gas and unburned mixture composition from a variety of methyl ester based bio diesel combustion in compression ignition engine, in comparison with conventional diesel fuel is presented. A free-energy minimisation scheme was used to determine mixture composition. Firstly, effects of bio diesel type were studied without exhaust gas recirculation (EGR). The combustion of the higher hydrogen-to-carbon molar ratio (H/C) bio diesel resulted in lower carbon dioxide and oxygen emissions but higher water vapour in the exhaust gases, compared to those of lower H/C ratios. At the same results also show that relative air-to-fuel ratio, that bio diesel combustion gases contain a higher amount of water vapour and a higher level of carbon dioxide compared to those of diesel. Secondly, influences of EGR (burned gas fraction) addition to bio diesel-fuelled engine on unburned mixture were simulated. For both diesel and bio diesel, the increased burned gas fraction addition to the fresh charge increased carbon dioxide and water vapour emissions while lowering oxygen content, especially for the bio diesel case. The prediction was compared with experimental results from literatures; good agreement was found. This can be considered to be a means for explaining some phenomenon occurring in bio diesel-fuelled engines. (author)

Determination of the vertical distribution and areal of the composition in volatile oil and/or gas condensate reservoirs

International Nuclear Information System (INIS)

Santos Santos, Nicolas; Ortiz Cancino, Olga Patricia; Barrios Ortiz, Wilson

2005-01-01

The compositional variation in vertical and areal direction due to gravitational and thermal effects plays an important role in the determination of the original reserves in-situ and in the selection of the operation scheme for volatile oil and/or gas condensate reservoirs. In this work we presented the mathematical formulation of the thermodynamic behavior experienced by compositional fluids, such as volatile oil and/or gas condensate, under the influence of the mentioned effects (gravitational and thermal), which was implemented in a software tool, this tool determine the compositional variation in vertical direction and, in addition, it allows to know the saturation pressure variation in the hydrocarbon column and the location of the gas-oil contact. With the obtained results, product of the use of this tool, was developed a methodology to obtain one first approach of the compositional variation in areal direction to obtain compositional spatial distribution (iso composition maps) in the reservoir, for components like the methane, which experiences the greater variations. These iso composition maps allow to determine the location of the hydrocarbon deposits, in such a way that the production strategies can be selected and be applied to maximize the recovery, such as in fill wells, perforation of new zones, EOR processes, etc

Systematic study of RPC performances in polluted or varying gas mixtures compositions: an online monitor system for the RPC gas mixture at LHC

CERN Document Server

Capeans, M; Mandelli, B

2012-01-01

The importance of the correct gas mixture for the Resistive Plate Chamber (RPC) detector systems is fundamental for their correct and safe operation. A small change in the percentages of the gas mixture components can alter the RPC performance and this will rebound on the data quality in the ALICE, ATLAS and CMS experiments at CERN. A constant monitoring of the gas mixture injected in the RPCs would avoid such kind of problems. A systematic study has been performed to understand RPC performances with several gas mixture compositions and in the presence of common gas impurities. The systematic analysis of several RPC performance parameters in different gas mixtures allows the rapid identification of any variation in the RPC gas mixture. A set-up for the online monitoring of the RPC gas mixture in the LHC gas systems is also proposed.

Variations in composition of farmyard manure in biologic gas production

Energy Technology Data Exchange (ETDEWEB)

Scheffer, F; Welte, E; Kemmler, G

1953-01-01

The advantages of the ''Bihugas'' method, Schmidt-Eggersgluss system, are discussed. The losses of organic matter and of C are about 33 percent for a gas output of 270 l/kg of organic matter, but 55 percent of the C of the decomposition products is utilized as mixed gas (about 60 percent as methane). The gas output amounts to 3-7 m/sup 3/ per 100 kg fresh manure. The maximum heating value of the mixed gas is 5700 kcal. The loss of N is only 1 percent of the total N; no P, K, and Ca are lost. No formation of humus was observed. The average composition of fermented manure was dry matter 10.56 organic matter 6.9, C 3.47, N 0.36, ammonia N in percentage of total N 38, K/sub 2/O/sub 7/ 0.27, CaO 0.18, and P/sub 2/O/sub 5/ 0.13 percent. The process, compared with the conventional handling of manure, decreases losses in N from 18.5 percent to 1 percent, and those in C from 38 percent to 7.3 percent.

Fission gas induced fuel swelling in low and medium burnup fuel during high temperature transients

International Nuclear Information System (INIS)

Vinjamuri, K.

1980-01-01

The behavior of light water reactor fuel elements under postulated accident conditions is being studied by the EG and G Idaho, Inc., Thermal Fuels Behavior Program for the Nuclear Regulatory Commission. As a part of this program, unirradiated and previously irradiated, pressurized-water-reactor type fuel rods were tested under power-cooling-mismatch (PCM) conditions in the Power Burst Facility (PBF). During these integral in-reactor experiments, film boiling was produced on the fuel rods which created high fuel and cladding temperatures. Fuel rod diameters increased in the film boiling region to a greater extent for irradiated rods than for unirradiated rods. The purpose of the study was to investigate and assess the fuel swelling which caused the fuel rod diameter increases and to evaluate the ability of an analytical code, the Gas Release and Swelling Subroutine - Steady-State and Transient (GRASS-SST), to predict the results

Molecular Simulation of Ionic Polyimides and Composites with Ionic Liquids as Gas-Separation Membranes.

Science.gov (United States)

Abedini, Asghar; Crabtree, Ellis; Bara, Jason E; Turner, C Heath

2017-10-24

Polyimides are at the forefront of advanced membrane materials for CO 2 capture and gas-purification processes. Recently, ionic polyimides (i-PIs) have been reported as a new class of condensation polymers that combine structural components of both ionic liquids (ILs) and polyimides through covalent linkages. In this study, we report CO 2 and CH 4 adsorption and structural analyses of an i-PI and an i-PI + IL composite containing [C 4 mim][Tf 2 N]. The combination of molecular dynamics (MD) and grand canonical Monte Carlo (GCMC) simulations is used to compute the gas solubility and the adsorption performance with respect to the density, fractional free volume (FFV), and surface area of the materials. Our results highlight the polymer relaxation process and its correlation to the gas solubility. In particular, the surface area can provide meaningful guidance with respect to the gas solubility, and it tends to be a more sensitive indicator of the adsorption behavior versus only considering the system density and FFV. For instance, as the polymer continues to relax, the density, FFV, and pore-size distribution remain constant while the surface area can continue to increase, enabling more adsorption. Structural analyses are also conducted to identify the nature of the gas adsorption once the ionic liquid is added to the polymer. The presence of the IL significantly displaces the CO 2 molecules from the ligand nitrogen sites in the neat i-PI to the imidazolium rings in the i-PI + IL composite. However, the CH 4 molecules move from the imidazolium ring sites in the neat i-PI to the ligand nitrogen atoms in the i-PI + IL composite. These molecular details can provide critical information for the experimental design of highly selective i-PI materials as well as provide additional guidance for the interpretation of the simulated adsorption systems.

Study of condensate composition during field processing of gas of the Shatlyk field

Energy Technology Data Exchange (ETDEWEB)

Kuldzhayev, B.A.; Annamukhamedov, M.B.; Makarov, V.V.; Serbnenko, S.R.; Talalayev, Ye.I.

1983-01-01

Studies were made of the composition and properties of condensates from field separators of the East Shatlyk field. The expediency is shown of separate collection of the condensates into a separate container and used for local needs as the diesel fuel. The condensates from the UNTS separators are used as chemical raw material to produce the lowest olephins by pyrolysis of gas-oil fraction and normal paraffins from kerosene-gas-oil part to obtain the protein-vitamin concentrates.

Effect of transient liquid flow on retention characteristics of screen acquisition systems. [design of Space Shuttle feed system

Science.gov (United States)

Cady, E. C.

1977-01-01

A design analysis, is developed based on experimental data, to predict the effects of transient flow and pressure surges (caused either by valve or pump operation, or by boiling of liquids in warm lines) on the retention performance of screen acquisition systems. A survey of screen liquid acquisition system applications was performed to determine appropriate system environment and classification. A screen model was developed which assumed that the screen device was a uniformly distributed composite orthotropic structure, and which accounted for liquid inflow/outflow, gas ingestion quality, screen stress, and liquid spill. A series of 177 tests using 13 specimens (5 screen meshes, 4 screen device construction/backup methods, and 2 orientations) with three test fluids (isopropyl alcohol, Freon 114, and LH2) provided data which verified important features of the screen model and resulted in a design tool which could accurately predict the transient startup performance acquisition devices.

Determination of equilibrium composition of thermally ionized monoatomic gas under different physical conditions

Science.gov (United States)

Romanova, M. S.; Rydalevskaya, M. A.

2017-05-01

Perfect gas mixtures that result from thermal ionization of spatially and chemically homogeneous monoatomic gases are considered. Equilibrium concentrations of the components of such mixtures are determined using integration over the momentum space and summation with respect to energy levels of the distribution functions that maximize the entropy of system under condition for constancy of the total number of nuclei and electrons. It is demonstrated that such a method allows significant simplification of the calculation of the equilibrium composition for ionized mixtures at different temperatures and makes it possible to study the degree of ionization of gas versus gas density and number in the periodic table of elements.

A theoretical model for gas permeability in a composite membrane

International Nuclear Information System (INIS)

Serrano, D. A

2009-01-01

We present in this work an analytical expression for permeability in a two-layer composite membrane, which was derived assuming the same hypothesis as those of Adzumi model for permeability in a homogeneous membrane. Whereas in Adzumi model permeability shows a linear dependence on the mean pressure, our model for a composite membrane related permeability to pressure through a rather complex expression, which covers the whole range of flow, from molecular-Knudsen to viscous-Poiseuille regimes. The expression obtained for permeability contained information of membrane structural properties as pore size, porosity and thickness of each layer, as well as gas nature and operational conditions. Our two-layer-model expression turns into Adzumi formula when the structure of the layers approach to each other. [es

Computer-Aided System of Virtual Testing of Gas Turbine Engines

Directory of Open Access Journals (Sweden)

Rybakov Viktor N.

2016-01-01

Full Text Available The article describes the concept of a virtual lab that includes subsystem of gas turbine engine simulation, subsystem of experiment planning, subsystem of measurement errors simulation, subsystem of simulator identification and others. The basis for virtual lab development is the computer-aided system of thermogasdynamic research and analysis “ASTRA”. The features of gas turbine engine transient modes simulator are described. The principal difference between the simulators of transient and stationary modes of gas turbine engines is that the energy balance of the compressor and turbine becomes not applicable. The computer-aided system of virtual gas turbine engine testing was created using the developed transient modes simulator. This system solves the tasks of operational (throttling, speed, climatic, altitude characteristics calculation, analysis of transient dynamics and selection of optimal control laws. Besides, the system of virtual gas turbine engine testing is a clear demonstration of gas turbine engine working process and the regularities of engine elements collaboration. The interface of the system of virtual gas turbine engine testing is described in the article and some screenshots of the interface elements are provided. The developed system of virtual gas turbine engine testing provides means for reducing the laboriousness of gas turbine engines testing. Besides, the implementation of this system in the learning process allows the diversification of lab works and therefore improve the quality of training.

Impact of waves on the circulation flow in the Iguasu gas centrifuge

Science.gov (United States)

Bogovalov, S.; Kislov, V.; Tronin, I.

2017-01-01

2D axisymmetric transient flow induced by a pulsed braking force in the Iguasu gas centrifuge (GC) is simulated numerically. The simulation is performed for two cases: transient and stationary. The braking forces averaged over the period of rotation are equal to each other in both cases. The transient case is compared with the stationary case where the flow is excited by the stationary braking force.Two models of the gas cenrifuge is simulated. There are two cameras in the first model and three cameras in the second one. In the transient case for the two cameras model pulsations almost doubles the axial circulation flux in the working camera. In the transient case for the three cameras model the gas flux through the gap in the bottom baffle exceeds on 15 % the same flux in the stationary case for the same gas content and temperature at the walls of the rotor. We argue that the waves can reduce the gas content in the GC on the same 15 %.

CHEMICAL COMPOSITION AND in vitro GAS PRODUCTION OF SOME LEGUME BROWSE SPECIES IN SUBTROPICAL AREAS OF MEXICO

Directory of Open Access Journals (Sweden)

Carlos A Garcia Montes de Oca

2011-03-01

Full Text Available The objective of the present study was to determine the chemical composition and in vitro gas production of different legume and wild arboreal pods. Seven seeds of legume browse species, Mexican calabash (Crescentia alata, esculent leadtree (Leucaena esculenta, guamuchil (Phitecellobium dulce, bastard cedar (Guazuma ulmifolia, needle bush (Acacia farnesiana, mimosa (Mimosa sp. and elephant ear tree (Enterolobium cyclocarpum. Were evaluated for their chemical composition (g/kg DM and in vitro gas production pattern. Crude Protein was higher for L. esculenta (220 and lower for G. ulmifolia (70. Neutral and acid detergent fiber were higher for G. ulmifolia (687 and 554 and lower for A. farnesiana (267 and 176. Lignin was higher for Mimosa sp. (219 and lower for P. dulce (81. Total gas production (ml gas/g DM of P. dulce (187 and E. cyclocarpum (164 were higher (P

Evaluation of LWR fuel rod behavior under operational transient conditions

International Nuclear Information System (INIS)

Nakamura, M.; Hiramoto, K.; Maru, A.

1984-01-01

To evaluate the effects of fission gas flow and diffusion in the fuel-cladding gap on fuel rod thermal and mechanical behaviors in light water reactor (LWR) fuel rods under operational transient conditions, computer sub-programs which can calculate the gas flow and diffusion have been developed and integrated into the LWR fuel rod performance code BEAF. This integrated code also calculates transient temperature distribution in the fuel-pellet and cladding. The integrated code was applied to an analysis of Inter Ramp Project data, which showed that by taking into account the gas flow and diffusion effects, the calculated cladding damage indices predicted for the failed rods in the ramp test were consistent with iodine-SCC (Stress Corrosion Cracking) failure conditions which were obtained from out-of-reactor pressurized tube experiments with irradiated Zircaloy claddings. This consistency was not seen if the gas flow and diffusion effects were neglected. Evaluation were also made for the BWR 8x8 RJ fuel rod temperatures under power ramp conditions. (orig.)

Statistical characteristics of transient enclosure voltage in ultra-high-voltage gas-insulated switchgear

Science.gov (United States)

Cai, Yuanji; Guan, Yonggang; Liu, Weidong

2017-06-01

Transient enclosure voltage (TEV), which is a phenomenon induced by the inner dielectric breakdown of SF6 during disconnector operations in a gas-insulated switchgear (GIS), may cause issues relating to shock hazard and electromagnetic interference to secondary equipment. This is a critical factor regarding the electromagnetic compatibility of ultra-high-voltage (UHV) substations. In this paper, the statistical characteristics of TEV at UHV level are collected from field experiments, and are analyzed and compared to those from a repeated strike process. The TEV waveforms during disconnector operations are recorded by a self-developed measurement system first. Then, statistical characteristics, such as the pulse number, duration of pulses, frequency components, magnitude and single pulse duration, are extracted. The transmission line theory is introduced to analyze the TEV and is validated by the experimental results. Finally, the relationship between the TEV and the repeated strike process is analyzed. This proves that the pulse voltage of the TEV is proportional to the corresponding breakdown voltage. The results contribute to the definition of the standard testing waveform of the TEV, and can aid the protection of electronic devices in substations by minimizing the threat of this phenomenon.

Development of textile-reinforced carbon fibre aluminium composites manufactured with gas pressure infiltration methods

OpenAIRE

W. Hufenbach; M. Gude; A. Czulak; J. Śleziona; A. Dolata-Grosz; M. Dyzia

2009-01-01

Purpose: The aim of his paper is to show potential of textile-reinforced carbon fibre aluminium composite with advantage of the lightweight construction of structural components subjected to thermo-mechanical stress.Design/methodology/approach: The manufacture of specimens of the carbon fibre-reinforced aluminium was realised with the aid of an advanced differential gas pressure infiltration technique, which was developed at ILK, TU Dresden.Findings: The gas pressure infiltration technology e...

Gas desorption properties of ammonia borane and metal hydride composites

International Nuclear Information System (INIS)

Matin, M.R.

2009-01-01

'Full text': Ammonia borane (NH 3 BH 3 ) has been of great interest owing to its ideal combination of low molecular weight and high H 2 storage capacity of 19.6 mass %, which exceeds the current capacity of gasoline. DOE's year 2015 targets involve gravimetric as well as volumetric energy densities. In this work, we have investigated thermal decomposition of ammonia borane and calcium hydride composites at different molar ratio. The samples were prepared by planetary ball milling under hydrogen gas atmosphere pressure of 1Mpa at room temperature for 2, and 10 hours. The gas desorption properties were examined by thermal desorption mass spectroscopy (TDMS). The identification of phases was carried out by X-ray diffraction. The results obtain were shown in fig (a),(b),and (c). Hydrogen desorption properties were observed at all molar ratios, but the desorption temperature is significantly lower at around 70 o C at molar ratio 1:1 as shown in fig (c), and unwanted gas (ammonia) emissions were remarkably suppressed by mixing with the calcium hydride. (author)

Oxide fuel pin transient performance analysis and design with the TEMECH code

International Nuclear Information System (INIS)

Bard, F.E.; Dutt, S.P.; Hinman, C.A.; Hunter, C.W.; Pitner, A.L.

1986-01-01

The TEMECH code is a fast-running, thermal-mechanical-hydraulic, analytical program used to evaluate the transient performance of LMR oxide fuel pins. The code calculates pin deformation and failure probability due to fuel-cladding differential thermal expansion, expansion of fuel upon melting, and fission gas pressurization. The mechanistic fuel model in the code accounts for fuel cracking, crack closure, porosity decrease, and the temperature dependence of fuel creep through the course of the transient. Modeling emphasis has been placed on results obtained from Fuel Cladding Transient Test (FCTT) testing, Transient Fuel Deformation (TFD) tests and TREAT integral fuel pin experiments

Vacuum system transient simulator and its application to TFTR

International Nuclear Information System (INIS)

Sredniawski, J.

1978-01-01

The vacuum system transient simulator (VSTS) models transient gas transport throughout complex networks of ducts, valves, traps, vacuum pumps, and other related vacuum system components. VSTS is capable of treating gas models of up to 10 species, for all flow regimes from pure molecular to continuum. Viscous interactions between species are considered as well as non-uniform temperature of a system. Although this program was specifically developed for use on the Tokamak Fusion Test Reactor (TFTR) project at Princeton, it is a generalized tool capable of handling a broad range of vacuum system problems. During the TFTR engineering design phase, VSTS has been used in many applications. Two applications selected for presentation are: (1) torus vacuum pumping system performance between 400 Ci tritium pulses and (2) tritium backstreaming to neutral beams during pulses

Vacuum system transient simulator and its application to TFTR

International Nuclear Information System (INIS)

Sredniawski, J.

1977-01-01

The vacuum system transient simulator (VSTS) models transient gas transport throughout complex networks of ducts, valves, traps, vacuum pumps, and other related vacuum system components. VSTS is capable of treating gas models of up to 10 species, for all flow regimes from pure molecular to continuum. Viscous interactions between species are considered as well as non-uniform temperature of a system. Although this program was specifically developed for use on the Tokamak Fusion Test Reactor (TFTR) project at Princeton, it is a generalized tool capable of handling a broad range of vacuum system problems. During the TFTR engineering design phase, VSTS has been used in many applications. Two applications selected for presentation are: torus vacuum pumping system performance between 400 Ci tritium pulses and tritium backstreaming to neutral beams during pulses

Thin film composite membranes of glossy polymers for gas separation : preparation and characterization

NARCIS (Netherlands)

Ebert, Katrin

1995-01-01

The application of polymeric composite membranes can be very interesting in the field of gas separation. The two main parameters which determine the applicability of membranes are the selectivity and the permeability. Good selectivities can be achieved by developing proper materials, high permeation

Transient performance simulation of aircraft engine integrated with fuel and control systems

International Nuclear Information System (INIS)

Wang, C.; Li, Y.G.; Yang, B.Y.

2017-01-01

Highlights: • A new performance simulation method for engine hydraulic fuel systems is introduced. • Time delay of engine performance due to fuel system model is noticeable but small. • The method provides details of fuel system behavior in engine transient processes. • The method could be used to support engine and fuel system designs. - Abstract: A new method for the simulation of gas turbine fuel systems based on an inter-component volume method has been developed. It is able to simulate the performance of each of the hydraulic components of a fuel system using physics-based models, which potentially offers more accurate results compared with those using transfer functions. A transient performance simulation system has been set up for gas turbine engines based on an inter-component volume (ICV) method. A proportional-integral (PI) control strategy is used for the simulation of engine controller. An integrated engine and its control and hydraulic fuel systems has been set up to investigate their coupling effect during engine transient processes. The developed simulation system has been applied to a model aero engine. The results show that the delay of the engine transient response due to the inclusion of the fuel system model is noticeable although relatively small. The developed method is generic and can be applied to any other gas turbines and their control and fuel systems.

Probing the phase composition of silicon films in situ by etch product detection

International Nuclear Information System (INIS)

Dingemans, G.; Donker, M. N. van den; Gordijn, A.; Kessels, W. M. M.; Sanden, M. C. M. van de

2007-01-01

Exploiting the higher etch probability for amorphous silicon relative to crystalline silicon, the transiently evolving phase composition of silicon films in the microcrystalline growth regime was probed in situ by monitoring the etch product (SiH 4 ) gas density during a short H 2 plasma treatment step. Etch product detection took place by the easy-to-implement techniques of optical emission spectroscopy and infrared absorption spectroscopy. The phase composition of the films was probed as a function of the SiH 4 concentration during deposition and as a function of the film thickness. The in situ results were corroborated by Raman spectroscopy and solar cell analysis

Analytical model for transient fluid mixing in upper outlet plenum of an LMFBR

International Nuclear Information System (INIS)

Yang, J.W.; Agrawal, A.K.

1976-01-01

A two-zone mixing model based on the lumped-parameter approach was developed for the analysis of transient thermal response in the outlet plenum of an LMFBR. The maximum penetration of core flow is used as the criterion for dividing the sodium region into two mixing zones. The model considers the transient sodium temperature affected by the thermal expansion of sodium, heat transfer with cover gas, heat capacity of different sections of metal and the addition of by-pass flow into the plenum. The results of numerical calculations indicate that effects of flow stratification, chimney height, metal heat capacity and by-pass flow are important for transient sodium temperature calculation. Thermal expansion of sodium and heat transfer with the cover gas do not play any significant role on sodium temperature

Thermodynamic simulations of hydrate formation from gas mixtures in batch operations

International Nuclear Information System (INIS)

Kobayashi, Takehito; Mori, Yasuhiko H.

2007-01-01

This paper deals with the hydrate formation from mixed hydrate-forming gases such as natural gas to be converted to hydrates for the purpose of its storage and biogases from which carbon dioxide is to be separated by hydrate formation. When a batch operation is selected for processing such a gas mixture in a closed reactor, we need to predict the evolution of the thermodynamic and compositional states inside the reactor during the operation. We have contrived a simulation scheme that allows us to estimate the simultaneous changes in the composition of the residual gas, the structure of the hydrate formed and the guest composition in the hydrate, in addition to the change in the system pressure, with the progress of hydrate formation during each operation. This scheme assumes the transient hydrate forming process in a reactor during each operation to be a series of numerous equilibrium states, each slightly deviating from the preceding state. That is, a thermodynamic system composed of the contents of the reactor is assumed to be subjected to a quasi-static, irreversible change in state, instantaneously keeping itself in thermodynamic equilibrium. The paper demonstrates a simulation of a process of hydrate formation from a methane + propane mixture and compares its results to relevant experimental results reported by Uchida et al. [Uchida T, Morikawa M, Takeya S, Ikeda IY, Ohmura R, Nagao J, et al. Two-step formation of methane-propane mixed gas hydrates in a batch-type reactor. AIChE J 2004;50(2):518-23

A miniaturized optical gas sensor for natural gas analysis

NARCIS (Netherlands)

Ayerden, N.P.

2016-01-01

The depletion of domestic reserves and the growing use of sustainable resources forces a transition from the locally produced natural gas with a well-known composition toward the ‘new’ gas with a more flexible composition in the Netherlands. For safe combustion and proper billing, the natural gas

Robust high temperature composite and CO sensor made from such composite

Science.gov (United States)

Dutta, Prabir K.; Ramasamy, Ramamoorthy; Li, Xiaogan; Akbar, Sheikh A.

2010-04-13

Described herein is a composite exhibiting a change in electrical resistance proportional to the concentration of a reducing gas present in a gas mixture, detector and sensor devices comprising the composite, a method for making the composite and for making devices comprising the composite, and a process for detecting and measuring a reducing gas in an atmosphere. In particular, the reducing gas may be carbon monoxide and the composite may comprise rutile-phase TiO2 particles and platinum nanoclusters. The composite, upon exposure to a gas mixture containing CO in concentrations of up to 10,000 ppm, exhibits an electrical resistance proportional to the concentration of the CO present. The composite is useful for making sensitive, low drift, fast recovering detectors and sensors, and for measuring CO concentrations in a gas mixture present at levels from sub-ppm up to 10,000 ppm. The composites, and devices made from the composites, are stable and operable in a temperature range of from about 450.degree. C. to about 700.degree. C., such as may be found in a combustion chamber.

Fission gas induced fuel swelling in low and medium burnup fuel during high temperature transients. [PWR

Energy Technology Data Exchange (ETDEWEB)

Vinjamuri, K.

1980-01-01

The behavior of light water reactor fuel elements under postulated accident conditions is being studied by the EG and G Idaho, Inc., Thermal Fuels Behavior Program for the Nuclear Regulatory Commission. As a part of this program, unirradiated and previously irradiated, pressurized-water-reactor type fuel rods were tested under power-cooling-mismatch (PCM) conditions in the Power Burst Facility (PBF). During these integral in-reactor experiments, film boiling was produced on the fuel rods which created high fuel and cladding temperatures. Fuel rod diameters increased in the film boiling region to a greater extent for irradiated rods than for unirradiated rods. The purpose of the study was to investigate and assess the fuel swelling which caused the fuel rod diameter increases and to evaluate the ability of an analytical code, the Gas Release and Swelling Subroutine - Steady-State and Transient (GRASS-SST), to predict the results.

Study on Transient Properties of Levitated Object in Near-Field Acoustic Levitation

International Nuclear Information System (INIS)

Jia Bing; Chen Chao; Zhao Chunsheng

2011-01-01

A new approach to the study on the transient properties of the levitated object in near-field acoustic levitation (NFAL) is presented. In this article, the transient response characteristics, including the levitated height of an object with radius of 24 mm and thickness of 5 mm, the radial velocity and pressure difference of gas at the boundary of clearance between the levitated object and radiating surface (squeeze film), is calculated according to several velocity amplitudes of radiating surface. First, the basic equations in fluid areas on Arbitrary Lagrange-Euler (ALE) form are numerically solved by using streamline upwind petrov galerkin (SUPG) finite elements method. Second, the formed algebraic equations and solid control equations are solved by using synchronous alternating method to gain the transient messages of the levitated object and gas in the squeeze film. Through theoretical and numerical analyses, it is found that there is a oscillation time in the transient process and that the response time does not simply increase with the increasing of velocity amplitudes of radiating surface. More investigations in this paper are helpful for the understanding of the transient properties of levitated object in NFAL, which are in favor of enhancing stabilities and responsiveness of levitated object. (electromagnetism, optics, acoustics, heat transfer, classical mechanics, and fluid dynamics)

Study on Transient Properties of Levitated Object in Near-Field Acoustic Levitation

Science.gov (United States)

Jia, Bing; Chen, Chao; Zhao, Chun-Sheng

2011-12-01

A new approach to the study on the transient properties of the levitated object in near-field acoustic levitation (NFAL) is presented. In this article, the transient response characteristics, including the levitated height of an object with radius of 24 mm and thickness of 5 mm, the radial velocity and pressure difference of gas at the boundary of clearance between the levitated object and radiating surface (squeeze film), is calculated according to several velocity amplitudes of radiating surface. First, the basic equations in fluid areas on Arbitrary Lagrange—Euler (ALE) form are numerically solved by using streamline upwind petrov galerkin (SUPG) finite elements method. Second, the formed algebraic equations and solid control equations are solved by using synchronous alternating method to gain the transient messages of the levitated object and gas in the squeeze film. Through theoretical and numerical analyses, it is found that there is a oscillation time in the transient process and that the response time does not simply increase with the increasing of velocity amplitudes of radiating surface. More investigations in this paper are helpful for the understanding of the transient properties of levitated object in NFAL, which are in favor of enhancing stabilities and responsiveness of levitated object.

Estimating the composition of gas hydrate using 3D seismic data from Penghu Canyon, offshore Taiwan

Directory of Open Access Journals (Sweden)

Sourav Kumar Sahoo

2018-01-01

Full Text Available Direct measurements of gas composition by drilling at a few hundred meters below seafloor can be costly, and a remote sensing method may be preferable. The hydrate occurrence is seismically shown by a bottom-simulating reflection (BSR which is generally indicative of the base of the hydrate stability zone. With a good temperature profile from the seafloor to the depth of the BSR, a near-correct hydrate phase diagram can be calculated, which can be directly related to the hydrate composition. However, in the areas with high topographic anomalies of seafloor, the temperature profile is usually poorly defined, with scattered data. Here we used a remote method to reduce such scattering. We derived gas composition of hydrate in stability zone and reduced the scattering by considering depth-dependent geothermal conductivity and topographic corrections. Using 3D seismic data at the Penghu canyon, offshore SW Taiwan, we corrected for topographic focusing through 3D numerical thermal modeling. A temperature profile was fitted with a depth-dependent geothermal gradient, considering the increasing thermal conductivity with depth. Using a pore-water salinity of 2%, we constructed a gas hydrate phase model composed of 99% methane and 1% ethane to derive a temperature depth profile consistent with the seafloor temperature from in-situ measurements, and geochemical analyses of the pore fluids. The high methane content suggests predominantly biogenic source. The derived regional geothermal gradient is 40°C km-1. This method can be applied to other comparable marine environment to better constrain the composition of gas hydrate from BSR in a seismic data, in absence of direct sampling.

Volcanic gas composition changes during the gradual decrease of the gigantic degassing activity of Miyakejima volcano, Japan, 2000-2015

Science.gov (United States)

Shinohara, Hiroshi; Geshi, Nobuo; Matsushima, Nobuo; Saito, Genji; Kazahaya, Ryunosuke

2017-02-01

The composition of volcanic gases discharged from Miyakejima volcano has been monitored during the intensive degassing activity that began after the eruption in 2000. During the 15 years from 2000 to 2015, Miyakejima volcano discharged 25.5 Mt of SO2, which required degassing of 3 km3 of basaltic magma. The SO2 emission rate peaked at 50 kt/day at the end of 2000 and quickly decreased to 5 kt/day by 2003. During the early degassing period, the volcanic gas composition was constant with the CO2/SO2 = 0.8 (mol ratio), H2O/SO2 = 35, HCl/SO2 = 0.08, and SO2/H2S = 15. The SO2 emission rate decreased gradually to 0.5 kt/day by 2012, and the gas composition also changed gradually to CO2/SO2 = 1.5, H2O/SO2 = 150, HCl/SO2 = 0.15, and SO2/H2S = 6. The compositional changes are not likely caused by changes in degassing pressure or volatile heterogeneity of a magma chamber but are likely attributed to an increase of hydrothermal scrubbing caused by large decrease of the volcanic gas emission rate, suggesting a supply of gases with constant composition during the 15 years. The intensive degassing was modeled based on degassing of a convecting magma conduit. The gradual SO2 emission rate that decrease without changes in volcanic gas composition is attributed to a reduction of diameter of the convecting magma conduit.

Quantitative measurement of carbon isotopic composition in CO2 gas reservoir by Micro-Laser Raman spectroscopy

Science.gov (United States)

Li, Jiajia; Li, Rongxi; Zhao, Bangsheng; Guo, Hui; Zhang, Shuan; Cheng, Jinghua; Wu, Xiaoli

2018-04-01

The use of Micro-Laser Raman spectroscopy technology for quantitatively determining gas carbon isotope composition is presented. In this study, 12CO2 and 13CO2 were mixed with N2 at various molar fraction ratios to obtain Raman quantification factors (F12CO2 and F13CO2), which provide a theoretical basis for calculating the δ13C value. And the corresponding values were 0.523 (0 Laser Raman analysis were carried out on natural CO2 gas from Shengli Oil-field at room temperature under different pressures. The δ13C values obtained by Micro-Laser Raman spectroscopy technology and Isotope Ratio Mass Spectrometry (IRMS) technology are in good agreement with each other, and the relative errors range of δ13C values is 1.232%-6.964%. This research provides a fundamental analysis tool for determining gas carbon isotope composition (δ13C values) quantitatively by using Micro-Laser Raman spectroscopy. Experiment of results demonstrates that this method has the potential for obtaining δ13C values in natural CO2 gas reservoirs.

Transient attenuation in optical fibers

International Nuclear Information System (INIS)

Hopkins, A.A.; Kelly, R.E.; Looney, L.D.; Lyons, P.B.

1984-01-01

Low and high energy pulsed electron beams were used to generate radiation-induced transient attenuation in high-OH, Suprasil core, PCS fibers, demonstrating the energy dependence of the radiation damage and recovery mechanisms. A radiation resistant low-OH fiber was studied and its performance contrasted to that of high-OH materials. Several fibers with differing core compositions were also studied

Steel reinforced composite silicone membranes and its integration to microfluidic oxygenators for high performance gas exchange.

Science.gov (United States)

Matharoo, Harpreet; Dabaghi, Mohammadhossein; Rochow, Niels; Fusch, Gerhard; Saraei, Neda; Tauhiduzzaman, Mohammed; Veldhuis, Stephen; Brash, John; Fusch, Christoph; Selvaganapathy, P Ravi

2018-01-01

Respiratory distress syndrome (RDS) is one of the main causes of fatality in newborn infants, particularly in neonates with low birth-weight. Commercial extracorporeal oxygenators have been used for low-birth-weight neonates in neonatal intensive care units. However, these oxygenators require high blood volumes to prime. In the last decade, microfluidics oxygenators using enriched oxygen have been developed for this purpose. Some of these oxygenators use thin polydimethylsiloxane (PDMS) membranes to facilitate gas exchange between the blood flowing in the microchannels and the ambient air outside. However, PDMS is elastic and the thin membranes exhibit significant deformation and delamination under pressure which alters the architecture of the devices causing poor oxygenation or device failure. Therefore, an alternate membrane with high stability, low deformation under pressure, and high gas exchange was desired. In this paper, we present a novel composite membrane consisting of an ultra-thin stainless-steel mesh embedded in PDMS, designed specifically for a microfluidic single oxygenator unit (SOU). In comparison to homogeneous PDMS membranes, this composite membrane demonstrated high stability, low deformation under pressure, and high gas exchange. In addition, a new design for oxygenator with sloping profile and tapered inlet configuration has been introduced to achieve the same gas exchange at lower pressure drops. SOUs were tested by bovine blood to evaluate gas exchange properties. Among all tested SOUs, the flat design SOU with composite membrane has the highest oxygen exchange of 40.32 ml/min m 2 . The superior performance of the new device with composite membrane was demonstrated by constructing a lung assist device (LAD) with a low priming volume of 10 ml. The LAD was achieved by the oxygen uptake of 0.48-0.90 ml/min and the CO 2 release of 1.05-2.27 ml/min at blood flow rates ranging between 8 and 48 ml/min. This LAD was shown to increase the

Gas permeability of bentonite barriers: development, construction and testing of a measurement system

Directory of Open Access Journals (Sweden)

Heraldo Nunes Pitanga

Full Text Available Abstract This article proposes a testing device to quickly and reliably estimate the gas permeability of bentonite-based clay barriers used in landfill cover systems. The testing methodology is based on a transient gas flow regime that passes through the barrier, therefore not requiring the use of sophisticated equipment that aim to maintain constant differential pressure and measure the gas flow, common requirements for testing methods under a permanent flow regime. To confirm the feasibility of the proposed technique, tests were performed on a pure hydrated bentonite layer, which subsequently encompassed samples of geosynthetic clay liner (GCL at different moisture contents. Geosynthetic clay liners are often selected as a part of the barrier layer for cover systems in solid waste landfills to prevent infiltration of rainfall and migration of biogas into the atmosphere. The results confirmed the equipment reliability and differentiate the different responses of the gas flow barriers studied, considering their different compositions and different moistures.

Transient Fuel Behavior and Failure Condition in the CABRI-2 Experiments

International Nuclear Information System (INIS)

Sato, Ikken; Lemoine, Francette; Struwe, Dankward

2004-01-01

In the CABRI-2 program, 12 tests were performed under various transient conditions covering a wide range of accident scenarios using two types of preirradiated fast breeder reactor (FBR) fuel pins with different smear densities and burnups. For each fuel, a nonfailure-transient test was performed, and it provided basic information such as fuel thermal condition, fuel swelling, and gas release. From the failure tests, information on failure mode, failure time, and axial location was obtained. Based on this information, failure conditions such as fuel enthalpy and cladding temperature were evaluated. These failure conditions were compared with the CABRI-1 tests in which different fuels as well as different transient conditions were used. This comparison, together with supporting information available from existing in-pile and out-of-pile experiments, allowed an effective understanding on failure mechanisms depending on fuel and transient conditions. It is concluded that pellet-cladding mechanical interaction (PCMI) due to fuel thermal expansion and fission-gas-induced swelling is playing an important role on mechanical clad loading especially with high smear density and low fuel-heating-rate conditions. At very high heating-rate conditions, there is no sufficient time to allow significant fuel swelling, so that cavity pressurization with fuel melting becomes the likely failure mechanism. Fuel smear density and fission-gas retention have a strong impact both on PCMI and cavity pressurization. Furthermore, pin failure is strongly dependent on cladding temperature, which plays an important role in the axial failure location. With the low smear-density fuel, considerable PCMI mitigation is possible leading to a high failure threshold as well as in-pin molten-fuel relocation along the central hole. However, even with the low smear density fuel, PCMI failure could take place with an elevated cladding-temperature condition. On the other hand, in case of a sufficiently long

Millimeterwave spectroscopy of transient molecules produced in a ...

Indian Academy of Sciences (India)

The construction of a millimeterwave spectrometer to study the pure rotational spectra of transient molecules in the gas phase is presented. The spectrometer is a source-modulated system combined with a free space glass discharge cell. Millimeterwave radiation has been produced using a frequency multiplier, the ...

Annual and transient signatures of gas exchange and transport in the Castañar de Ibor cave (Spain

Directory of Open Access Journals (Sweden)

Fernandez-Cortes A.

2009-07-01

Full Text Available The large microclimatic stability is a basic characteristic of the subterranean karst systems and causes a high sensitivity to changesin environmental conditions. High-accuracy monitoring of Castañar de Ibor cave (Spain determined the temporal evolution of theaerodynamic processes and ventilation rate by tracking CO2 and 222Rn levels over a twelve-month period. This cave is characterizedby a very stable microclimate, with high and relatively constant radon content (the mean value is 32200 Bq/m3, roughly, and thestandard deviation is 7600 Bq/m3 and a moderate and quite stable CO2 concentration (the mean value is 3730 ppm and the standarddeviation is 250 ppm. Beside the general patterns of cave microclimate throughout an annual cycle, some particular microclimaticprocesses are described with regard to the gas exchange between the cave and the outside atmosphere. There is a complexmicroclimatic functional relationship between the meteorological and cave microclimate conditions and the diffusion and flow of tracergases from the fractures and the pore system of soil and host rock to cave atmosphere. Transient variations of tracer gas on cave airare controlled by natural barometric fluxes and anthropogenic forced ventilation due to uncontrolled opening of cave entrance. Theshort-term fluctuations of gas levels on cave air reveal distinct patterns during the exhalation process of theses gases from the netof fissures and pores to the cave atmosphere, depending on the isolation effect of soil and host rock.

Synthesis of the cactus-like silicon nanowires/tungsten oxide nanowires composite for room-temperature NO{sub 2} gas sensor

Energy Technology Data Exchange (ETDEWEB)

Zhang, Weiyi, E-mail: zhangweiyi@tju.edu.cn [School of Electronic Information Engineering, Tianjin University, Tianjin, 300072 (China); Hu, Ming [School of Electronic Information Engineering, Tianjin University, Tianjin, 300072 (China); Key Laboratory for Advanced Ceramics and Machining Technology, Ministry of Education, School of Materials Science and Engineering, Tianjin University, Tianjin 300072 (China); Liu, Xing; Wei, Yulong; Li, Na [School of Electronic Information Engineering, Tianjin University, Tianjin, 300072 (China); Qin, Yuxiang, E-mail: qinyuxiang@tju.edu.cn [School of Electronic Information Engineering, Tianjin University, Tianjin, 300072 (China); Key Laboratory for Advanced Ceramics and Machining Technology, Ministry of Education, School of Materials Science and Engineering, Tianjin University, Tianjin 300072 (China)

2016-09-15

In the present work, the tungsten oxide (WO{sub 3}) nanowires functionalized silicon nanowires (SiNWs) with cactus-like structure has been successfully synthesized for room-temperature NO{sub 2} detection. The novel nanocomposite was fabricated by metal-assisted chemical etching (MACE) and thermal annealing of tungsten film. The WO{sub 3} nanowires were evenly distributed from the upper to the lower part of the SiNWs, indicating excellent uniformity which is conducive to adsorption and desorption of gas molecules. The gas-sensing properties have been examined by measuring the resistance change towards 0.25–5 ppm NO{sub 2} gas. At room temperature, which is the optimum working temperature, the SiNWs/WO{sub 3} nanowires composite showed two-times higher NO{sub 2} response than that of the bare SiNWs at 2 ppm NO{sub 2}. On the contrary, the responses of composite sensors to high concentrations of other reducing gases were very low, indicating excellent selectivity. Simultaneously, the composite sensors exhibited good sensing repeatability and stability. The enhancement in gas sensing properties may be attributed to the change in width of the space charge region, which is similar to the behavior of p-n junctions under forward bias, in the high-density p-n heterojunction structure formed between SiNWs and WO{sub 3} nanowires. - Highlights: • SiNWs/WO{sub 3} nanowires composite with cactus-like structure is synthesized. • The morphology of WO{sub 3} nanowires depends on the thermal annealing temperature. • The nanocomposite sensor exhibit better gas response than that of bare SiNWs. • The gas sensing mechanism is discussed using p-n heterojunction theory.

Influence of fuel composition on the non-oxidizing heating of steel in a waste gas atmosphere

Energy Technology Data Exchange (ETDEWEB)

Minkler, W [LOI Industrieofenanlagen G.m.b.H., Essen (Germany, F.R.)

1979-04-01

On the basis of a number of graphs and data on theoretical combustion temperatures and the difference between the heating value of the fuel and the waste gas in respect of 1 m/sup 3/ of waste gas, the author demonstrates the influence of fuel composition on the non-oxidizing heating of steel in a waste gas atmosphere derived from five different fuels. A rotary-hearth furnace is described for the non-oxidizing heating of pressings from plain carbon and alloy steel.

Apparatus and method for transient thermal infrared emission spectrometry

Science.gov (United States)

McClelland, John F.; Jones, Roger W.

1991-12-24

A method and apparatus for enabling analysis of a solid material (16, 42) by applying energy from an energy source (20, 70) top a surface region of the solid material sufficient to cause transient heating in a thin surface layer portion of the solid material (16, 42) so as to enable transient thermal emission of infrared radiation from the thin surface layer portion, and by detecting with a spectrometer/detector (28, 58) substantially only the transient thermal emission of infrared radiation from the thin surface layer portion of the solid material. The detected transient thermal emission of infrared radiation is sufficiently free of self-absorption by the solid material of emitted infrared radiation, so as to be indicative of characteristics relating to molecular composition of the solid material.

A comparative study of gas-gas miscibility processes in underground gas storage reservoirs

Energy Technology Data Exchange (ETDEWEB)

Rafiee, M.M.; Schmitz, S. [DBI - Gastechnologisches Institut gGmbH, Freiberg (Germany)

2013-08-01

Intermixture of gases in underground gas reservoirs have had great weight for natural gas storage in UGS projects with substitution of cushion gas by inert gases or changing the stored gas quality or origin, as for the replacement of town gas by natural gas. It was also investigated during the last years for Enhanced Gas Recovery (EGR) and Carbon Capture and Storage (CCS) projects. The actual importance of its mechanisms is discussed for the H{sub 2} storage in Power to Gas to Power projects (PGP). In these approaches miscibility of the injected gas with the gas in place in the reservoir plays an important role in the displacement process. The conditions and parameters for the gas-gas displacement and mixing have been investigated in previous projects, as e.g. the miscibility of CO{sub 2} with natural gas (CLEAN). Furthermore the miscibility process of town gas with natural gas and sauer gas with sweet gas were also previously measured and compared in laboratory. The objective of this work is to investigate the miscibility of H{sub 2} injection into natural gas reservoirs using a compositional and a black oil reservoir simulator. Three processes of convection, dispersion and diffusion are considered precisely. The effect of gas miscibility is studied for both simulators and the results are compared to find optimum miscibility parameters. The findings of this work could be helpful for further pilot and field case studies to predict and monitor the changes in gas composition and quality. In future this monitoring might become more important when PGP together with H{sub 2}-UGS, as storage technology, will help to successfully implement the change to an energy supply from more renewable sources. Similarly the method confirms the use of the black oil simulator as an alternative for gas-gas displacement and sequestration reservoir simulation in comparison to the compositional simulator. (orig.)

Studies on nitric oxide removal in simulated gas compositions under plasma-dielectric/catalytic discharges

International Nuclear Information System (INIS)

Rajanikanth, B.S.; Rout, Satyabrata

2001-01-01

Application of pulsed electrical discharges for gas cleaning is gaining prominence, mainly from the energy consideration point of view. This present paper presents recent work on applying the electrical discharge plasma technology for treating gaseous pollutants, in general, and nitric oxide, in particular, as this is one of the major contributors to air pollution. The present work focuses attention on pulsed electrical discharge technique for nitric oxide removal from simulated gas compositions and study of effect of packed dielectric pellets, with and without a coating of catalyst, on the removal process. Experiments were conducted in a cylindrical corona reactor energized by repetitive high voltage pulses. The effects of various parameters, viz. pulse voltage magnitude, pulse frequency, initial nitric oxide concentration and gas mixture composition on nitric oxide removal efficiency, are discussed. When the reactors were filled with different dielectric pellets like, barium titanate, alumina, and alumina coated with palladium catalyst, the improvement in nitric oxide removal efficiency is studied and discussed. The power dissipated in the reactor and the energy consumed per nitric oxide molecule removed was calculated. Further results and comparative study of various cases are presented in the paper

ELOCA: fuel element behaviour during high temperature transients

International Nuclear Information System (INIS)

Sills, H.E.

1979-03-01

The ELOCA computer code was developed to simulate the uniform thermal-mechanical behaviour of a fuel element during high-temperature transients such as a loss-of-coolant accident (LOCA). Primary emphasis is on the diametral expansion of the fuel sheath. The model assumed is a single UO2/zircaloy-clad element with axisymmetric properties. Physical effects considered by the code are fuel expansion, cracking and melting; variation, during the transient, of internal gas pressure; changing fuel/sheath heat transfer; thermal, elastic and plastic sheath deformation (anisotropic); Zr/H 2 O chemical reaction effects; and beryllium-assisted crack penetration of the sheath. (author)

Gas composition modeling in a reformed Methanol Fuel Cell system using adaptive Neuro-Fuzzy Inference Systems

DEFF Research Database (Denmark)

Justesen, Kristian Kjær; Andreasen, Søren Juhl; Shaker, Hamid Reza

2013-01-01

This work presents a method for modeling the gas composition in a Reformed Methanol Fuel Cell system. The method is based on Adaptive Neuro-Fuzzy-Inference-Systems which are trained on experimental data. The developed models are of the H2, CO2, CO and CH3OH mass flows of the reformed gas. The ANFIS......, or fuel cell diagnostics systems....

Analysis of transient thermal response in the outlet plenum of an LMFBR

International Nuclear Information System (INIS)

Yang, J.W.

1976-05-01

A two-zone mixing model based on the lumped-parameter approach was developed for the analysis of transient thermal response in the upper outlet plenum of an LMFBR. The one-dimensional turbulent jet flow equations were solved to determine the maximum penetration of the core flow. The maximum penetration is used as the criterion for dividing the sodium region into two mixing zones. The lumped-parameter model considers the transient sodium temperature affected by the thermal expansion of sodium, heat transfer with cover gas, heat capacity of different sections of metal and the addition of bypass flow into the plenum. Numerical calculations were performed for two cases. The first case corresponds to a normal scram followed by flow coast-down. The second case represents the double-ended pipe rupture at the inlet of cold leg followed by reactor scram. The results indicate that effects of flow stratification, chimney height, metal heat capacity and bypass flow are important for transient sodium temperature calculation. Thermal expansion of sodium and heat transfer with the cover gas does not play any significant role on sodium temperature. This two-zone mixing model will be a part of the thermohydraulic transient code SSC

TRANSIENT FINITE ELEMENT SIMULATION AND MICROSTRUCTURE EVOLUTION OF AA2219 WELD JOINT USING GAS TUNGSTEN ARC WELDING PROCESS

Directory of Open Access Journals (Sweden)

Sivaraman Arunkumar

2016-09-01

Full Text Available In this study we focus on finite element simulation of gas tungsten arc welding (GTAW of AA2219 aluminum alloy and the behavioral of the microstructure before and after weld. The simulations were performed using commercial COMSOL Multiphysics software. The thermal history of the weld region was studied by initially developed mathematical model. A sweep type meshing was used and transient analysis was performed for one welding cycle. The highest temperature noted was 3568 °C during welding. The welding operation was performed on 200×100×25 mm plates. Through metallurgical characterization, it was observed that a fair copper rich cellular (CRC network existed in the weld region. A small amount of intermetallic compounds like Al2Cu is observed through the XRD pattern.

The development of a transient neutron flux solution in the PANTHER code

International Nuclear Information System (INIS)

Hutt, P.K.; Knight, M.P.

1990-01-01

In the United Kingdom a new three-dimensional, two-group, homogeneous reactor diffusion code, PANTHER, has been developed for the analysis of pressurized water reactors (PWRs) and advanced gas-cooled reactors (AGRs). The code can perform a comprehensive range of calculations, steady state, depletion, and transient with either a finite difference or analytic nodal flux solution. The nodal solution allows the representation of within-node burnup variation and pin-power reconstruction in either steady-state or transient mode. Specific steady-state and transient thermal feedback modules are included for both PWRs and AGRs. The code is being developed to perform a complete range of reactor calculations from online operational support to fuel management and fault transient analysis. In the area of transient analysis, the code is currently being used for a number of PWR fault transient assessments, including rod ejection and steam-line break. In addition, work is proceeding to incorporate the PANTHER 3D nodal transient solution in the TRAC-P code. This paper outlines the development of the transient flux solutions within PANTHER

Ultrafast triggered transient energy storage by atomic layer deposition into porous silicon for integrated transient electronics

Science.gov (United States)

Douglas, Anna; Muralidharan, Nitin; Carter, Rachel; Share, Keith; Pint, Cary L.

2016-03-01

porous silicon, dissolution tests for 0.1 M and 0.01 M NaOH trigger solutions, EIS analysis for VOx coated devices, and EDS compositional analysis of VOx. (ii) Video showing transient behavior of integrated VOx/porous silicon scaffolds. See DOI: 10.1039/c5nr09095d

Tamoxifen affects glucose and lipid metabolism parameters, causes browning of subcutaneous adipose tissue and transient body composition changes in C57BL/6NTac mice

International Nuclear Information System (INIS)

Hesselbarth, Nico; Pettinelli, Chiara; Gericke, Martin; Berger, Claudia; Kunath, Anne; Stumvoll, Michael; Blüher, Matthias; Klöting, Nora

2015-01-01

Tamoxifen is a selective estrogen receptor (ER) modulator which is widely used to generate inducible conditional transgenic mouse models. Activation of ER signaling plays an important role in the regulation of adipose tissue (AT) metabolism. We therefore tested the hypothesis that tamoxifen administration causes changes in AT biology in vivo. 12 weeks old male C57BL/6NTac mice were treated with either tamoxifen (n = 18) or vehicle (n = 18) for 5 consecutive days. Tamoxifen treatment effects on body composition, energy homeostasis, parameters of AT biology, glucose and lipid metabolism were investigated up to an age of 18 weeks. We found that tamoxifen treatment causes: I) significantly increased HbA 1c , triglyceride and free fatty acid serum concentrations (p < 0.01), II) browning of subcutaneous AT and increased UCP-1 expression, III) increased AT proliferation marker Ki67 mRNA expression, IV) changes in adipocyte size distribution, and V) transient body composition changes. Tamoxifen may induce changes in body composition, whole body glucose and lipid metabolism and has significant effects on AT biology, which need to be considered when using Tamoxifen as a tool to induce conditional transgenic mouse models. Our data further suggest that tamoxifen-treated wildtype mice should be characterized in parallel to experimental transgenic models to control for tamoxifen administration effects. - Highlights: • Tamoxifen treatment causes significantly increased HbA 1c , triglyceride and free fatty acid serum concentrations. • Tamoxifen induces browning of subcutaneous AT and increased UCP-1 expression. • Tamoxifen changes adipocyte size distribution, and transient body composition

Enhancing the ABAQUS Thermomechanics Code to Simulate Steady and Transient Fuel Rod Behavior

International Nuclear Information System (INIS)

Williamson, R.L.; Knoll, D.A.

2009-01-01

A powerful multidimensional fuels performance capability, applicable to both steady and transient fuel behavior, is developed based on enhancements to the commercially available ABAQUS general-purpose thermomechanics code. Enhanced capabilities are described, including: UO2 temperature and burnup dependent thermal properties, solid and gaseous fission product swelling, fuel densification, fission gas release, cladding thermal and irradiation creep, cladding irradiation growth, gap heat transfer, and gap/plenum gas behavior during irradiation. The various modeling capabilities are demonstrated using a 2D axisymmetric analysis of the upper section of a simplified multi-pellet fuel rod, during both steady and transient operation. Computational results demonstrate the importance of a multidimensional fully-coupled thermomechanics treatment. Interestingly, many of the inherent deficiencies in existing fuel performance codes (e.g., 1D thermomechanics, loose thermo-mechanical coupling, separate steady and transient analysis, cumbersome pre- and post-processing) are, in fact, ABAQUS strengths.

Transient analysis of a variable speed rotary compressor

International Nuclear Information System (INIS)

Park, Youn Cheol

2010-01-01

A transient simulation model of a rolling piston type rotary compressor is developed to predict the dynamic characteristics of a variable speed compressor. The model is based on the principles of conservation, real gas equations, kinematics of the crankshaft and roller, mass flow loss due to leakage, and heat transfer. For the computer simulation of the compressor, the experimental data were obtained from motor performance tests at various operating frequencies. Using the developed model, re-expansion loss, friction loss, mass flow loss and heat transfer loss is estimated as a function of the crankshaft speed in a variable speed compressor. In addition, the compressor efficiency and energy losses are predicted at various compressor-operating frequencies. Since the transient state of the compressor strongly depends on the system, the developed model is combined with a transient system simulation program to get transient variations of the compression process in the system. Motor efficiency, mechanical efficiency, motor torque and volumetric efficiency are calculated with respect to variation of the driving frequency in a rotary compressor.

TORT-TD/ATTICA3D: a coupled neutron transport and thermal hydraulics code system for 3-D transient analysis of gas cooled high temperature reactors

International Nuclear Information System (INIS)

Lapins, J.; Seubert, A.; Buck, M.; Bader, J.; Laurien, E.

2011-01-01

Comprehensive safety studies of high temperature gas cooled reactors (HTR) require full three dimensional coupled treatments of both neutron kinetics and thermal-hydraulics. In a common effort, GRS and IKE developed the coupled code system TORT-TD/ATTICA3D for pebble bed type HTR that connects the 3-D transient discrete-ordinates transport code TORT-TD with the 3-D porous medium thermal-hydraulics code ATTICA3D. In this paper, the physical models and calculation capabilities of TORT-TD and ATTICA3D are presented, focusing on model improvements in ATTICA3D and extensions made in TORT-TD related to HTR application. For first applications, the OECD/NEA/NSC PBMR-400 benchmark has been chosen. Results obtained with TORT-TD/ATTICA3D will be shown for transient exercises, e.g. control rod withdrawal and a control rod ejection. Results are compared to other benchmark participants' solutions with special focus on fuel temperature modelling features of ATTICA3D. The provided “grey-curtain” nuclear cross section libraries have been used. First results on 3-D effects during a control rod withdrawal transient will be presented. (author)

Behavior of mixed-oxide fuel subjected to multiple thermal transients

International Nuclear Information System (INIS)

Fenske, G.R.; Hofman, G.L.; Neimark, L.A.; Poeppel, R.B.

1983-11-01

The microstructural behavior of irradiated mixed-oxide fuel subjected to multiple, mild thermal transients was investigated using direct electrical heating. The results demonstrate that significant intergranular porosity, accompanied by large-scale (>90%) release of the retained fission gas, developed as a result of the cyclic heating. Microstructural examination of the fuel indicated that thermal-shock-induced cracking of the fuel contributed significantly to the increased swelling and gas release

Gas production, composition and emission at a modern disposal site receiving waste with a low-organic content

DEFF Research Database (Denmark)

Scheutz, Charlotte; Fredenslund, Anders Michael; Nedenskov, Jonas

2011-01-01

AV Miljø is a modern waste disposal site receiving non-combustible waste with a low-organic content. The objective of the current project was to determine the gas generation, composition, emission, and oxidation in top covers on selected waste cells as well as the total methane (CH4) emission from....... The results indicated that the gas composition in the shredder waste was governed by chemical reactions as well as microbial reactions. CH4 mass balances from three individual waste cells showed that a significant part (between 15% and 67%) of the CH4 generated in cell 1.3 and 2.2.2 was emitted through...

HTGR-GT primary coolant transient resulting from postulated turbine deblading

International Nuclear Information System (INIS)

Cadwallader, G.J.; Deremer, R.K.

1980-11-01

The turbomachine is located within the primary coolant system of a nuclear closed cycle gas turbine plant (HTGR-GT). The deblading of the turbine can cause a rapid pressure equilibration transient that generates significant loads on other components in the system. Prediction of and design for this transient are important aspects of assuring the safety of the HTGR-GT. This paper describes the adaptation and use of the RATSAM program to analyze the rapid fluid transient throughout the primary coolant system during a spectrum of turbine deblading events. Included are discussions of (1) specific modifications and improvements to the basic RATSAM program, which is also briefly described; (2) typical results showing the expansion wave moving upstream from the debladed turbine through the primary coolant system; and (3) the effect on the transient results of different plenum volumes, flow resistances, times to deblade, and geometries that can choke the flow

Charged particle transport in gaseous nitrogen at intermediate E/N using the voltage transient method

International Nuclear Information System (INIS)

Purdie, P.H.; Fletcher, J.

1992-01-01

A pulsed swarm of charged particles crossing an inter-electrode gap under the influence of an applied electric field E will produce a pulsed current in the external circuit which, when integrated over time, will result in a transient voltage pulse, the shape and magnitude of which is characteristic of the number of type of charged particles. This voltage transient technique has been used to investigate a gas discharge in nitrogen gas at values of E/N (the ratio of applied electric field to gas number density), such that ionization is non-negligible. The voltage transients have been subjected to a theoretical analysis, which has previously been reported, which includes not only cathode and anode image terms but also both electron and ion diffusion terms. Electron transport parameters are reported for E/N ≤ 350 Td (1 Td = 10 -17 V cm 2 ). Data are also obtained for the drift velocities and diffusion coefficients of the ions operative within the nitrogen discharge. An estimate is obtained for the collisional decay rate of N 2 + . 21 refs., 7 figs

Behavior of mixed-oxide fuel subjected to multiple thermal transients

International Nuclear Information System (INIS)

Fenske, G.R.; Neimark, L.A.; Poeppel, R.B.; Hofman, G.L.

1985-01-01

The microstructural behavior of irradiated mixed-oxide fuel subjected to multiple, mild thermal transients was investigated using direct electrical heating. The results demonstrate that significant intergranular porosity, accompanied by large-scale (>90%) release of the retained fission gas, developed as a result of the cyclic heating. Microstructural examination of the fuel indicated that thermal-shock-induced cracking of the fuel contributed significantly to the increased swelling and gas release. 29 refs., 12 figs

Simulation of transient fluid flow in mold region during steel continuous casting

International Nuclear Information System (INIS)

Liu, R; Thomas, B G; Sengupta, J

2012-01-01

A system of models has been developed to study transient flow during continuous casting and applied to simulate an event of multiple stopper-rod movements. It includes four sub-models to incorporate different aspects in this transient event. A three-dimensional (3-D) porous-flow model of the nozzle wall calculates the rate argon gas flow into the liquid steel, and the initial mean bubble size is estimated. Transient CFD models simulate multiphase flow of steel and gas bubbles in the Submerged Entry Nozzle (SEN) and mold and have been validated with experimental data from both nail dipping and Sub-meniscus Velocity Control (SVC) measurements. To obtain the transient inlet boundary conditions for the simulation, two semi-empirical models, a stopper-rod-position based model and a metal-level-based model, predict the liquid steel flow rate through the SEN based on recorded plant data. Finally the model system was applied to study the effects of stopper rod movements on SEN/mold flow patterns. Meniscus level fluctuations were calculated using a simple pressure method and compared well with plant measurements. Insights were gained from the simulation results to explain the cause of meniscus level fluctuations and the formation of sliver defects during stopper rod movements.

Tamoxifen affects glucose and lipid metabolism parameters, causes browning of subcutaneous adipose tissue and transient body composition changes in C57BL/6NTac mice

Energy Technology Data Exchange (ETDEWEB)

Hesselbarth, Nico; Pettinelli, Chiara [Department of Medicine, University of Leipzig, D-04103 Leipzig (Germany); Gericke, Martin [Institute of Anatomy, University of Leipzig, D-04103 Leipzig (Germany); Berger, Claudia [IFB Adiposity Disease, Core Unit Animal Models, University of Leipzig, D-04103 Leipzig (Germany); Kunath, Anne [German Center for Diabetes Research (DZD), Leipzig (Germany); Stumvoll, Michael; Blüher, Matthias [Department of Medicine, University of Leipzig, D-04103 Leipzig (Germany); Klöting, Nora, E-mail: nora.kloeting@medizin.uni-leipzig.de [IFB Adiposity Disease, Core Unit Animal Models, University of Leipzig, D-04103 Leipzig (Germany)

2015-08-28

Tamoxifen is a selective estrogen receptor (ER) modulator which is widely used to generate inducible conditional transgenic mouse models. Activation of ER signaling plays an important role in the regulation of adipose tissue (AT) metabolism. We therefore tested the hypothesis that tamoxifen administration causes changes in AT biology in vivo. 12 weeks old male C57BL/6NTac mice were treated with either tamoxifen (n = 18) or vehicle (n = 18) for 5 consecutive days. Tamoxifen treatment effects on body composition, energy homeostasis, parameters of AT biology, glucose and lipid metabolism were investigated up to an age of 18 weeks. We found that tamoxifen treatment causes: I) significantly increased HbA{sub 1c}, triglyceride and free fatty acid serum concentrations (p < 0.01), II) browning of subcutaneous AT and increased UCP-1 expression, III) increased AT proliferation marker Ki67 mRNA expression, IV) changes in adipocyte size distribution, and V) transient body composition changes. Tamoxifen may induce changes in body composition, whole body glucose and lipid metabolism and has significant effects on AT biology, which need to be considered when using Tamoxifen as a tool to induce conditional transgenic mouse models. Our data further suggest that tamoxifen-treated wildtype mice should be characterized in parallel to experimental transgenic models to control for tamoxifen administration effects. - Highlights: • Tamoxifen treatment causes significantly increased HbA{sub 1c}, triglyceride and free fatty acid serum concentrations. • Tamoxifen induces browning of subcutaneous AT and increased UCP-1 expression. • Tamoxifen changes adipocyte size distribution, and transient body composition.

Macroscopic behavior of fast reactor fuel subjected to simulated thermal transients

International Nuclear Information System (INIS)

Fenske, G.R.; Emerson, J.E.; Savoie, F.E.

1983-06-01

High-speed cinematography has been used to characterize the macroscopic behavior of irradiated and unirradiated fuel subjected to thermal transients prototypical of fast reactor transients. The results demonstrate that as the cladding melts, the fuel can disperse via spallation if the fuel contains in excess of approx. 16 μmoles/gm of fission gas. Once the cladding has melted, the macroscopic behavior (time to failure and dispersive nature) was strongly influenced by the presence of volatile fission products and the heating rate

Vibrations of composite circular shell structures due to transient loads

International Nuclear Information System (INIS)

Schrader, K.-H.; Krutzik, N.; Winkel, G.

1975-01-01

Referring to a container consisting of different shell structures - such as spherical, cylindrical and conical shells - the dynamic behavior of coupled spatial shell structures due to transient loads will be investigated. The spatial structure including the filling of water will be idealized as a three-dimensional model consisting of ring elements. The influence of the water filling on the vibrations will be considered by virtual masses added to the shell structures. In circular direction as well as in meridional direction a consistent mass model has been used. By variation of the virtual masses it will be clarified, how these additional masses influence the vibrational behavior of the composed system. Another aspect which will be investigated is the influence of different stiffnesses of substructures or parts of substructures on the natural frequencies, and on their affiliated eigensystems. Furthermore, the maximum and minimum stresses in the structures caused by transient loads acting on the inner surface of the shells will be explored. Here it seems to be possible to locate an area of maximum strain. Rotational loads as well as nonrotational loads will be considered

Electronically controlled mechanical seal for aerospace applications--Part 2: Transient tests

Science.gov (United States)

Wolff, Paul J.; Salant, Richard F.

1995-01-01

An electronically controlled mechanical seal for use as the purge gas seal in a liquid oxygen turbopump has been fabricated and tested under transient operating conditions. The thickness of the lubricating film is controlled by adjusting the coning of the carbon face. This is accomplished by applying a voltage to a piezoelectric actuator to which the carbon face is bonded. The seal has been operated with a closed-loop control system that utilizes either the leakage rate or seal face temperature as the feedback. Both speed and pressure transients have been imposed on the seal. The transient tests have demonstrated that the seal is capable of maintaing low leakage rates while limiting face temperatures.

The effect of heat treatment on the magnitude and composition of residual gas in sealed silica glass ampoules

Science.gov (United States)

Palosz, W.; Szofran, F. R.; Lehoczky, S. L.

1994-01-01

The residual gas pressure and composition in sealed silica glass ampoules as a function of different treatment procedures has been investigated. The dependence of the residual gas on the outgassing and annealing parameters has been determined. The effects of the fused silica brand, of the ampoule fabrication, and of post-outgassing procedures have been evaluated.

Composite Material Switches

Science.gov (United States)

Javadi, Hamid (Inventor)

2002-01-01

A device to protect electronic circuitry from high voltage transients is constructed from a relatively thin piece of conductive composite sandwiched between two conductors so that conduction is through the thickness of the composite piece. The device is based on the discovery that conduction through conductive composite materials in this configuration switches to a high resistance mode when exposed to voltages above a threshold voltage.

Noble gas composition of subcontinental lithospheric mantle: An extensively degassed reservoir beneath Southern Patagonia

Science.gov (United States)

Jalowitzki, Tiago; Sumino, Hirochika; Conceição, Rommulo V.; Orihashi, Yuji; Nagao, Keisuke; Bertotto, Gustavo W.; Balbinot, Eduardo; Schilling, Manuel E.; Gervasoni, Fernanda

2016-09-01

Patagonia, in the Southern Andes, is one of the few locations where interactions between the oceanic and continental lithosphere can be studied due to subduction of an active spreading ridge beneath the continent. In order to characterize the noble gas composition of Patagonian subcontinental lithospheric mantle (SCLM), we present the first noble gas data alongside new lithophile (Sr-Nd-Pb) isotopic data for mantle xenoliths from Pali-Aike Volcanic Field and Gobernador Gregores, Southern Patagonia. Based on noble gas isotopic compositions, Pali-Aike mantle xenoliths represent intrinsic SCLM with higher (U + Th + K)/(3He, 22Ne, 36Ar) ratios than the mid-ocean ridge basalt (MORB) source. This reservoir shows slightly radiogenic helium (3He/4He = 6.84-6.90 RA), coupled with a strongly nucleogenic neon signature (mantle source 21Ne/22Ne = 0.085-0.094). The 40Ar/36Ar ratios vary from a near-atmospheric ratio of 510 up to 17700, with mantle source 40Ar/36Ar between 31100-6800+9400 and 54000-9600+14200. In addition, the 3He/22Ne ratios for the local SCLM endmember, at 12.03 ± 0.15 to 13.66 ± 0.37, are higher than depleted MORBs, at 3He/22Ne = 8.31-9.75. Although asthenospheric mantle upwelling through the Patagonian slab window would result in a MORB-like metasomatism after collision of the South Chile Ridge with the Chile trench ca. 14 Ma, this mantle reservoir could have remained unhomogenized after rapid passage and northward migration of the Chile Triple Junction. The mantle endmember xenon isotopic ratios of Pali-Aike mantle xenoliths, which is first defined for any SCLM-derived samples, show values indistinguishable from the MORB source (129Xe/132Xe =1.0833-0.0053+0.0216 and 136Xe/132Xe =0.3761-0.0034+0.0246). The noble gas component observed in Gobernador Gregores mantle xenoliths is characterized by isotopic compositions in the MORB range in terms of helium (3He/4He = 7.17-7.37 RA), but with slightly nucleogenic neon (mantle source 21Ne/22Ne = 0.065-0.079). We

Transient refractory material dissolution by a volumetrically-heated melt

Energy Technology Data Exchange (ETDEWEB)

Seiler, Jean Marie, E-mail: jean-marie.seiler@cea.fr [CEA, DEN, DTN, 17 Rue des Martyrs, 38054 Grenoble Cedex 9 (France); Ratel, Gilles [CEA, DEN, DTN, 17 Rue des Martyrs, 38054 Grenoble Cedex 9 (France); Combeau, Hervé [Institut Jean Lamour, UMR 7198, Lorraine University, Ecole des Mines de Nancy, Parc de Saurupt, 54042 Nancy Cedex (France); Gaus-Liu, Xiaoyang; Kretzschmar, Frank; Miassoedov, Alexei [Karlsruhe Institut of Technology, Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen (Germany)

2014-12-15

Highlights: • We describe a test investigating ceramic dissolution by a molten non-eutectic melt. • The evolution of the interface temperature between melt and refractory is measured. • A theoretical model describing dissolution kinetics is proposed. • When dissolution stops, interface temperature is the liquidus temperature of the melt. - Abstract: The present work addresses the question of corium–ceramic interaction in a core catcher during a core-melt accident in a nuclear power plant. It provides an original insight into transient aspects concerning dissolution of refractory material by a volumetrically heated pool. An experiment with simulant material (LIVECERAM) is presented. Test results clearly show that dissolution of solid refractory material can occur in a non-eutectic melt at a temperature which is lower than the melting temperature of the refractory material. During the dissolution transient, the interface temperature rises above the liquidus temperature, corresponding to the instantaneous average composition of the melt pool. With constant power dissipation in the melt and external cooling of the core-catcher, a final steady-state situation is reached. Dissolution stops when the heat flux (delivered by the melt to the refractory) can be removed by conduction through the residual thickness of the ceramic, with T{sub interface} = T{sub liquidus} (calculated for the average composition of the final liquid pool). The final steady state corresponds to a uniform pool composition and uniform interface temperature distribution. Convection in the pool is governed by natural thermal convection and the heat flux distribution is therefore similar to what would be obtained for a single component pool. An interpretation of the experiment with two model-based approaches (0D and 1D) is presented. The mass transfer kinetics between the interface and the bulk is controlled by a diffusion sublayer within the boundary layer. During the dissolution transient

A Model of Solid State Gas Sensors

Science.gov (United States)

Woestman, J. T.; Brailsford, A. D.; Shane, M.; Logothetis, E. M.

1997-03-01

Solid state gas sensors are widely used to measure the concentrations of gases such as CO, CH_4, C_3H_6, H_2, C_3H8 and O2 The applications of these sensors range from air-to-fuel ratio control in combustion processes including those in automotive engines and industrial furnaces to leakage detection of inflammable and toxic gases in domestic and industrial environments. As the need increases to accurately measure smaller and smaller concentrations, problems such as poor selectivity, stability and response time limit the use of these sensors. In an effort to overcome some of these limitations, a theoretical model of the transient behavior of solid state gas sensors has been developed. In this presentation, a model for the transient response of an electrochemical gas sensor to gas mixtures containing O2 and one reducing species, such as CO, is discussed. This model accounts for the transport of the reactive species to the sampling electrode, the catalyzed oxidation/reduction reaction of these species and the generation of the resulting electrical signal. The model will be shown to reproduce the results of published steady state models and to agree with experimental steady state and transient data.

COMEDIE BD1 experiment: Fission product behaviour during depressurization transients

International Nuclear Information System (INIS)

Gillet, R.; Brenet, D.; Hanson, D.L.; Kimball, O.F.

1996-01-01

An experimental program in the CEA COMEDIE loop has been carried out to obtain integral test data to validate the methods and transport models used to predict fission product release from the core and plate-out in the primary coolant circuit of the Modular High Temperature Gas Cooled Reactor (MHTGR) during normal operation and liftoff, and during rapid depressurization transients. The loop consists of an in-pile section with the fuel element, deposition section (heat exchanger), filters for collecting condensible Fission Productions (FP) during depressurization tests and an out-of-pile section devoted to chemical composition control of the gas and on-line analysis of gaseous FP. After steady state irradiation, the loop was subjected to a series of in-situ blowdowns at shear ratios (ratio of the wall shear stress during blowdown to that during steady state operation) ranging from 0.7 to 5.6. The results regarding the FP profiles on the plate-out section, before and after blowdowns are given. It appears that: the plate-out profiles depend on the FP chemistry; the depressurization phases have led to significant desorption of I 131, but on the contrary, they have almost no effect for the other FP such as Ag 110m, Cs 134, Cs 137 and Te 132. (author). 1 ref., 15 figs

Transient fuel melting

International Nuclear Information System (INIS)

Roche, L.; Schmitz, F.

1982-10-01

The observation of micrographic documents from fuel after a CABRI test leads to postulate a specific mode of transient fuel melting during a rapid nuclear power excursion. When reaching the melt threshold, the bands which are characteristic for the solid state are broken statistically over a macroscopic region. The time of maintaining the fuel at the critical enthalpy level between solid and liquid is too short to lead to a phase separation. A significant life-time (approximately 1 second) of this intermediate ''unsolide'' state would have consequences on the variation of physical properties linked to the phase transition solid/liquid: viscosity, specific volume and (for the irradiated fuel) fission gas release [fr

Correlation between photoconductivity in nanocrystalline titania and short circuit current transients in MEH-PPV/titania solar cells

International Nuclear Information System (INIS)

Xie, Z B; Henry, B M; Kirov, K R; Barkhouse, D A R; Burlakov, V M; Smith, H E; Grovenor, C R M; Assender, H E; Briggs, G A D; Kano, M; Tsukahara, Y

2007-01-01

We report the first experimental observation of a direct relationship between electron transport in different nanocrystalline TiO 2 thin films and the photovoltaic performance of TiO 2 /MEH-PPV composite solar cells made using these same TiO 2 films. We show that the transient behaviour in the composite solar cells under illumination can be explained by the transient photoconductivity performance of the TiO 2 layer

Fully integrated microfluidic measurement system for real-time determination of gas and liquid mixtures composition

NARCIS (Netherlands)

Lötters, Joost Conrad; Groenesteijn, Jarno; van der Wouden, E.J.; Sparreboom, Wouter; Lammerink, Theodorus S.J.; Wiegerink, Remco J.

2015-01-01

We have designed and realised a fully integrated microfluidic measurement system for real-time determination of both flow rate and composition of gas- and liquid mixtures. The system comprises relative permittivity sensors, pressure sensors, a Coriolis flow and density sensor, a thermal flow sensor

Volatile organic compound emissions from the oil and natural gas industry in the Uintah Basin, Utah: oil and gas well pad emissions compared to ambient air composition

Science.gov (United States)

Warneke, C.; Geiger, F.; Edwards, P. M.; Dube, W.; Pétron, G.; Kofler, J.; Zahn, A.; Brown, S. S.; Graus, M.; Gilman, J. B.; Lerner, B. M.; Peischl, J.; Ryerson, T. B.; de Gouw, J. A.; Roberts, J. M.

2014-10-01

Emissions of volatile organic compounds (VOCs) associated with oil and natural gas production in the Uintah Basin, Utah were measured at a ground site in Horse Pool and from a NOAA mobile laboratory with PTR-MS instruments. The VOC compositions in the vicinity of individual gas and oil wells and other point sources such as evaporation ponds, compressor stations and injection wells are compared to the measurements at Horse Pool. High mixing ratios of aromatics, alkanes, cycloalkanes and methanol were observed for extended periods of time and for short-term spikes caused by local point sources. The mixing ratios during the time the mobile laboratory spent on the well pads were averaged. High mixing ratios were found close to all point sources, but gas well pads with collection and dehydration on the well pad were clearly associated with higher mixing ratios than other wells. The comparison of the VOC composition of the emissions from the oil and natural gas well pads showed that gas well pads without dehydration on the well pad compared well with the majority of the data at Horse Pool, and that oil well pads compared well with the rest of the ground site data. Oil well pads on average emit heavier compounds than gas well pads. The mobile laboratory measurements confirm the results from an emissions inventory: the main VOC source categories from individual point sources are dehydrators, oil and condensate tank flashing and pneumatic devices and pumps. Raw natural gas is emitted from the pneumatic devices and pumps and heavier VOC mixes from the tank flashings.

The effects of fission gas release on PWR fuel rod design and performance

International Nuclear Information System (INIS)

Leech, W.J.; Kaiser, R.S.

1980-01-01

The purpose of this investigation was to determine the effects of fission gas release on PWR fuel rod design and performance. Empirical models were developed from fission gas release data. Fission gas release during normal operation is a function of burnup. There is little additional fission gas release during anticipated transients. The empirical models were used to evaluate Westinghouse fuel rod designs. It was determined that fission gas release is not a limiting parameter for obtaining rod average burnups in the range of 50,000 to 60,000 MWD/MTU. Fission gas release during anticipated transients has a negligible effect on the margins to rod design limits. (author)

Effect of carrier gas composition on transferred arc metal nanoparticle synthesis

International Nuclear Information System (INIS)

Stein, Matthias; Kiesler, Dennis; Kruis, Frank Einar

2013-01-01

Metal nanoparticles are used in a great number of applications; an effective and economical production scaling-up is hence desirable. A simple and cost-effective transferred arc process is developed, which produces pure metal (Zn, Cu, and Ag) nanoparticles with high production rates, while allowing fast optimization based on energy efficiency. Different carrier gas compositions, as well as the electrode arrangements and the power input are investigated to improve the production and its efficiency and to understand the arc production behavior. The production rates are determined by a novel process monitoring method, which combines an online microbalance method with a scanning mobility particle sizer for fast production rate and size distribution measurement. Particle characterization is performed via scanning electron microscopy, energy-dispersive X-ray spectroscopy, and X-ray diffraction measurements. It is found that the carrier gas composition has the largest impact on the particle production rate and can increase it with orders of magnitude. This appears to be not only a result of the increased heat flux and melt temperature but also of the formation of tiny nitrogen (hydrogen) bubbles in the molten feedstock, which impacts feedstock evaporation significantly in bi-atomic gases. A production rate of sub 200 nm particles from 20 up to 2,500 mg/h has been realized for the different metals. In this production range, specific power consumptions as low as 0.08 kWh/g have been reached.

Effects of Operating Temperature on Droplet Casting of Flexible Polymer/Multi-Walled Carbon Nanotube Composite Gas Sensors

Directory of Open Access Journals (Sweden)

Jin-Chern Chiou

2016-12-01

Full Text Available This study examined the performance of a flexible polymer/multi-walled carbon nanotube (MWCNT composite sensor array as a function of operating temperature. The response magnitudes of a cost-effective flexible gas sensor array equipped with a heater were measured with respect to five different operating temperatures (room temperature, 40 °C, 50 °C, 60 °C, and 70 °C via impedance spectrum measurement and sensing response experiments. The selected polymers that were droplet cast to coat a MWCNT conductive layer to form two-layer polymer/MWCNT composite sensing films included ethyl cellulose (EC, polyethylene oxide (PEO, and polyvinylpyrrolidone (PVP. Electrical characterization of impedance, sensing response magnitude, and scanning electron microscope (SEM morphology of each type of polymer/MWCNT composite film was performed at different operating temperatures. With respect to ethanol, the response magnitude of the sensor decreased with increasing operating temperatures. The results indicated that the higher operating temperature could reduce the response and influence the sensitivity of the polymer/MWCNT gas sensor array. The morphology of polymer/MWCNT composite films revealed that there were changes in the porous film after volatile organic compound (VOC testing.

Ultraviolet photoelectron spectroscopy of transient species

International Nuclear Information System (INIS)

Leeuw, D.M. de.

1979-01-01

Transient species are studied in the isolation of the gas phase using ultraviolet photoelectron spectroscopy (PES). A description of the equipment used and a discussion of some theoretical topics, which play a role in the interpretation of PE spectra, are given. Koopmans' theorem, Hartree-Fock-Slater (HFS) calculations and the sum rule are discussed. A versatile ultraviolet PE spectrometer, designed specifically for this purpose, has been built and the construction and performance of this instrument are described. (Auth.)

Dual layer hollow fiber sorbents for trace H2S removal from gas streams

KAUST Repository

Bhandari, Dhaval A.; Bessho, Naoki; Koros, William J.

2013-01-01

Hollow fiber sorbents are pseudo monolithic materials with potential use in various adsorption based applications. Dual layer hollow fiber sorbents have the potential to allow thermal regeneration without direct contact of the regeneration fluid with the sorbent particles. This paper considers the application of dual layer hollow fiber sorbents for a case involving trace amounts of H2S removal from a simulated gas stream and offers a comparison with single layer hollow fiber sorbents. The effect of spin dope composition and core layer zeolite loading on the gas flux, H2S transient sorption capacity and pore structure are also studied. This work can be used as a guide to develop and optimize dual layer hollow fiber sorbent properties beyond the specific example considered here. © 2013 Elsevier Ltd.

Dual layer hollow fiber sorbents for trace H2S removal from gas streams

KAUST Repository

Bhandari, Dhaval A.

2013-05-01

Hollow fiber sorbents are pseudo monolithic materials with potential use in various adsorption based applications. Dual layer hollow fiber sorbents have the potential to allow thermal regeneration without direct contact of the regeneration fluid with the sorbent particles. This paper considers the application of dual layer hollow fiber sorbents for a case involving trace amounts of H2S removal from a simulated gas stream and offers a comparison with single layer hollow fiber sorbents. The effect of spin dope composition and core layer zeolite loading on the gas flux, H2S transient sorption capacity and pore structure are also studied. This work can be used as a guide to develop and optimize dual layer hollow fiber sorbent properties beyond the specific example considered here. © 2013 Elsevier Ltd.

Gas chromatographic/mass spectrometric determination of carbon isotope composition in unpurified samples: methamphetamine example.

Science.gov (United States)

Low, I A; Liu, R H; Legendre, M G; Piotrowski, E G; Furner, R L

1986-10-01

A gas chromatograph/quadrupole mass spectrometer system, operated in electron impact/selected ion monitoring mode, is used to determine the intensity ratio of the m/z 59 and the m/z 58 ions of the [C3H8N]+ fragment derived from methamphetamine samples synthesized with varying amounts of 13C-labeled methylamine. Crude products are introduced into the gas chromatograph without prior cleanup. The ratios measured were in excellent agreement with those calculated. A change in 0.25% use of 13C-methylamine is sufficient for product differentiation. The feasibility of using isotope labeling and subsequent mass spectrometric isotope ratio measurement as the basis of a compound tracing mechanism is discussed. Specifically, if methamphetamine samples manufactured from legal sources are asked to incorporate distinct 13C compositions, their sources can be traced when samples are diverted into illegal channels. Samples derived from illicit preparations can also be traced if the manufacturers of a precursor (methylamine in this case) incorporate distinct 13C compositions in their products.

The transient creep of vapor deposited Ti-6Al-4V

International Nuclear Information System (INIS)

Warren, J.; Wadley, H.N.G.

1996-01-01

Titanium matrix composites can be synthesized by the consolidation of ceramic fibers (for example, alumina and silicon carbide monofilaments) coated with titanium alloy deposited on the fiber by physical vapor deposition (PVD). Consolidation involves deformation of the matrix coating by both transient and steady-state creep. In a recent paper the mechanisms responsible for steady-state creep in PVD Ti-6Al-4V, between 600 and 900 C, were determined. The analysis of the data first presented has been extended here to consider the transient creep behavior of the material and identify an analogous constitutive law for use in simulating the transient creep contribution to consolidation

Thermodynamic analysis of oil and gas platforms over various production profiles and feed compositions

DEFF Research Database (Denmark)

Nguyen, Tuong-Van; Junior, Silvio de Oliveira

2017-01-01

Oil and gas platforms present similar structural designs but process fluids with different thermo-physical and chemical properties. In addition, the field properties, such as the gas-to-oil and water-to-oil ratios, change significantly over time. It is therefore not possible to suggest a standard...... of energy and exergy. Feed compositions and production profiles, which correspond to data from actual fields, are used for calibrating the simulations. In a second step, the minimum energy and exergy losses of the platform are assessed by performing thermodynamic analyses, assuming an ideal scenario...... in which all processes are run at their design points. This approach proves to be useful for evaluating consistently different options for oil and gas production, and for determining, in a further step, the most promising solutions for minimising the energy use over a field lifetime....

Quantitative measurements of in-cylinder gas composition in a controlled auto-ignition combustion engine

Science.gov (United States)

Zhao, H.; Zhang, S.

2008-01-01

One of the most effective means to achieve controlled auto-ignition (CAI) combustion in a gasoline engine is by the residual gas trapping method. The amount of residual gas and mixture composition have significant effects on the subsequent combustion process and engine emissions. In order to obtain quantitative measurements of in-cylinder residual gas concentration and air/fuel ratio, a spontaneous Raman scattering (SRS) system has been developed recently. The optimized optical SRS setups are presented and discussed. The temperature effect on the SRS measurement is considered and a method has been developed to correct for the overestimated values due to the temperature effect. Simultaneous measurements of O2, H2O, CO2 and fuel were obtained throughout the intake, compression, combustion and expansion strokes. It shows that the SRS can provide valuable data on this process in a CAI combustion engine.

Quantitative measurements of in-cylinder gas composition in a controlled auto-ignition combustion engine

International Nuclear Information System (INIS)

Zhao, H; Zhang, S

2008-01-01

One of the most effective means to achieve controlled auto-ignition (CAI) combustion in a gasoline engine is by the residual gas trapping method. The amount of residual gas and mixture composition have significant effects on the subsequent combustion process and engine emissions. In order to obtain quantitative measurements of in-cylinder residual gas concentration and air/fuel ratio, a spontaneous Raman scattering (SRS) system has been developed recently. The optimized optical SRS setups are presented and discussed. The temperature effect on the SRS measurement is considered and a method has been developed to correct for the overestimated values due to the temperature effect. Simultaneous measurements of O 2 , H 2 O, CO 2 and fuel were obtained throughout the intake, compression, combustion and expansion strokes. It shows that the SRS can provide valuable data on this process in a CAI combustion engine

Assessment of undiscovered oil and gas resources of the Cretaceous-Tertiary Composite Total Petroleum System, Taranaki Basin Assessment Unit, New Zealand

Science.gov (United States)

Wandrey, Craig J.; Schenk, Christopher J.; Klett, Timothy R.; Brownfield, Michael E.; Charpentier, Ronald R.; Cook, Troy A.; Pollastro, Richard M.; Tennyson, Marilyn E.

2013-01-01

The Cretaceous-Tertiary Composite Total Petroleum System coincident Taranaki Basin Assessment Unit was recently assessed for undiscovered technically recoverable oil, natural gas, and natural gas liquids resources as part of the U.S. Geological Survey (USGS) World Energy Resources Project, World Oil and Gas Assessment. Using a geology-based assessment methodology, the USGS estimated mean volumes of 487 million barrels of oil, 9.8 trillion cubic feet of gas, and 408 million barrels of natural gas liquids.

Graphites and composites irradiations for gas cooled reactor core structures

International Nuclear Information System (INIS)

Van der Laan, J.G.; Vreeling, J.A.; Buckthorpe, D.E.; Reed, J.

2008-01-01

Full text of publication follows. Material investigations are undertaken as part of the European Commission 6. Framework Programme for helium-cooled fission reactors under development like HTR, VHTR, GCFR. The work comprises a range of activities, from (pre-)qualification to screening of newly designed materials. The High Flux Reactor at Petten is the main test bed for the irradiation test programmes of the HTRM/M1, RAPHAEL and ExtreMat Integrated Projects. These projects are supported by the European Commission 5. and 6. Framework Programmes. To a large extent they form the European contribution to the Generation-IV International Forum. NRG is also performing a Materials Test Reactor project to support British Energy in preparing extended operation of their Advanced Gas-cooled Reactors (AGR). Irradiations of commercial and developmental graphite grades for HTR core structures are undertaken in the range of 650 to 950 deg C, with a view to get data on physical and mechanical properties that enable engineering design. Various C- and SiC-based composite materials are considered for support structures or specific components like control rods. Irradiation test matrices are chosen to cover commercial materials, and to provide insight on the behaviour of various fibre and matrix types, and the effects of architecture and manufacturing process. The programme is connected with modelling activities to support data trending, and improve understanding of the material behaviour and micro-structural evolution. The irradiation programme involves products from a large variety of industrial and research partners, and there is strong interaction with other high technology areas with extreme environments like space, electronics and fusion. The project on AGR core structures graphite focuses on the effects of high dose neutron irradiation and simultaneous radiolytic oxidation in a range of 350 to 450 deg C. It is aimed to provide data on graphite properties into the parameter space

Measurement of the Air Chance Rate and Ventilation Characteristics During Short Term Transient Phenomena

DEFF Research Database (Denmark)

Heiselberg, Per Kvols; Perino, M.

2004-01-01

Different measurement procedures are available for the experimental assessment of air change rates inside ventilated enclosures. These mainly consist of tracer gas techniques and can usually be applied to steady-state or moderately transient conditions and when a continous mixing of the indoor air...... ventilation. The results are critically compared with the air flow rates assessed through anemometric measurements. The measurement features, limitations, shortcomings and uncertainties are also discussed....... is assured throughout the test. However, due to the relatively slow response of the gas analysers, none of these procedures can usually be applied to fast transient phenomena that last 15 minutes or less. Moreover in many cases of natural ventilation strategies, the continuous mixing of the indoor air would...

The reactive solid-gas flow of a fluidized bed for UO2 conversion

International Nuclear Information System (INIS)

Juanico, L.E.

1991-01-01

The reactive solid-gas flow of a fluidized bed for UO 2 conversion was modeled. The sedimentation-reaction process was treated using the drift-flux equations. Also, the associated pressure transient due to the reaction gas release was analyzed. An experiment was carried out to compare the results, and pressure transient was numerically simulated, reaching interesting conclusions. (Author) [es

Polyaniline-Cadmium Ferrite Nanostructured Composite for Room-Temperature Liquefied Petroleum Gas Sensing

Science.gov (United States)

Kotresh, S.; Ravikiran, Y. T.; Tiwari, S. K.; Vijaya Kumari, S. C.

2017-08-01

We introduce polyaniline-cadmium ferrite (PANI-CdFe2O4) nanostructured composite as a room-temperature-operable liquefied petroleum gas (LPG) sensor. The structure of PANI and the composite prepared by chemical polymerization was characterized by Fourier-transform infrared (FT-IR) spectroscopy, x-ray diffraction (XRD) analysis, and field-emission scanning electron microscopy. Comparative XRD and FT-IR analysis confirmed CdFe2O4 embedded in PANI matrix with mutual interfacial interaction. The nanostructure of the composite was confirmed by transmission electron microscopy. A simple LPG sensor operable at room temperature, exclusively based on spin-coated PANI-CdFe2O4 nanocomposite, was fabricated with maximum sensing response of 50.83% at 1000 ppm LPG. The response and recovery time of the sensor were 50 s and 110 s, respectively, and it was stable over a period of 1 month with slight degradation of 4%. The sensing mechanism is discussed on the basis of the p- n heterojunction barrier formed at the interface of PANI and CdFe2O4.

Anomalies of natural gas compositions and carbon isotope ratios caused by gas diffusion - A case from the Donghe Sandstone reservoir in the Hadexun Oilfield, Tarim Basin, northwest China

Science.gov (United States)

Wang, Yangyang; Chen, Jianfa; Pang, Xiongqi; Zhang, Baoshou; Wang, Yifan; He, Liwen; Chen, Zeya; Zhang, Guoqiang

2018-05-01

Natural gases in the Carboniferous Donghe Sandstone reservoir within the Block HD4 of the Hadexun Oilfield, Tarim Basin are characterized by abnormally low total hydrocarbon gas contents ( δ13C ethane (C2) gas has never been reported previously in the Tarim Basin and such large variations in δ13C have rarely been observed in other basins globally. Based on a comprehensive analysis of gas geochemical data and the geological setting of the Carboniferous reservoirs in the Hadexun Oilfield, we reveal that the anomalies of the gas compositions and carbon isotope ratios in the Donghe Sandstone reservoir are caused by gas diffusion through the poorly-sealed caprock rather than by pathways such as gas mixing, microorganism degradation, different kerogen types or thermal maturity degrees of source rocks. The documentation of an in-reservoir gas diffusion during the post entrapment process as a major cause for gas geochemical anomalies may offer important insight into exploring natural gas resources in deeply buried sedimentary basins.

Fission gas behaviour in UO2 under steady state and transient conditions

International Nuclear Information System (INIS)

Zimmermann, H.

1980-01-01

Fission gas behaviour in UO 2 is determined by the limited capacity of the fuel to retain fission gas. This capacity depends primarily on temperature, but also on fission rate, pressure loading, and fuel microstructure. Under steady state irradiation conditions fission gas behaviour can be described qualitatively as follows: At the beginning of the irradiation most of the fission gas remains in the grains in irradiation-induced solution. With increasing gas content in the grains the gas transport to the grain boundaries increases, too. The fission gas release from the grain boundaries occurs primarily by interlinkage of inter-granular bubbles. The fission gas release without noticeable fuel swelling during the short-term heating in the LOCA tests and the powdering of the high burnup UO 2 in the annealing tests can only be accounted for by formation of inter-granular separations, which are caused by the fission gas accumulated in the grain boundaries. Besides this short-term effect there are diffusion-controlled long-term effects, such as growth and coalescence of bubbles and formation of inter-connected porosity, which result in time-dependent fission gas release and fuel swelling

Transient behavior of Cu/ZnO-based methanol synthesis catalysts

DEFF Research Database (Denmark)

Vesborg, Peter Christian Kjærgaard; Chorkendorff, Ib; Knudsen, Ida

2009-01-01

Time-resolved measurements of the methanol synthesis reaction over a Cu/ZnO-based catalyst reveal a transient methanol production that depends on the pretreatment gas. Specifically, the methanol production initially peaks after a pretreatment with an intermediate mixture of H2 and CO (20–80% H2...

Benign hepatic portal venous gas following caustic ingestion

International Nuclear Information System (INIS)

Lewin, Maite; Tubiana, Jean-Michel; Pocard, Marc; Caplin, Scott; Parc, Rolland; Blain, Antoine

2002-01-01

Hepatic portal vein gas has been documented in numerous conditions and is traditionally regarded as a poor prognostic sign. There are, however, several reports of portal vein gas with a benign course. We report the first case of transient hepatic portal vein gas secondary to the ingestion of a caustic substance. The literature of hepatic portal vein gas in benign disease is reviewed. (orig.)

Assessment of the 3He pressure inside the CABRI transient rods - Development of a surrogate model based on measurements and complementary CFD calculations

Science.gov (United States)

Clamens, Olivier; Lecerf, Johann; Hudelot, Jean-Pascal; Duc, Bertrand; Cadiou, Thierry; Blaise, Patrick; Biard, Bruno

2018-01-01

CABRI is an experimental pulse reactor, funded by the French Nuclear Safety and Radioprotection Institute (IRSN) and operated by CEA at the Cadarache research center. It is designed to study fuel behavior under RIA conditions. In order to produce the power transients, reactivity is injected by depressurization of a neutron absorber (3He) situated in transient rods inside the reactor core. The shapes of power transients depend on the total amount of reactivity injected and on the injection speed. The injected reactivity can be calculated by conversion of the 3He gas density into units of reactivity. So, it is of upmost importance to properly master gas density evolution in transient rods during a power transient. The 3He depressurization was studied by CFD calculations and completed with measurements using pressure transducers. The CFD calculations show that the density evolution is slower than the pressure drop. Surrogate models were built based on CFD calculations and validated against preliminary tests in the CABRI transient system. Studies also show that it is harder to predict the depressurization during the power transients because of neutron/3He capture reactions that induce a gas heating. This phenomenon can be studied by a multiphysics approach based on reaction rate calculation thanks to Monte Carlo code and study the resulting heating effect with the validated CFD simulation.

Assessment of the 3He pressure inside the CABRI transient rods - Development of a surrogate model based on measurements and complementary CFD calculations

Directory of Open Access Journals (Sweden)

Clamens Olivier

2018-01-01

Full Text Available CABRI is an experimental pulse reactor, funded by the French Nuclear Safety and Radioprotection Institute (IRSN and operated by CEA at the Cadarache research center. It is designed to study fuel behavior under RIA conditions. In order to produce the power transients, reactivity is injected by depressurization of a neutron absorber (3He situated in transient rods inside the reactor core. The shapes of power transients depend on the total amount of reactivity injected and on the injection speed. The injected reactivity can be calculated by conversion of the 3He gas density into units of reactivity. So, it is of upmost importance to properly master gas density evolution in transient rods during a power transient. The 3He depressurization was studied by CFD calculations and completed with measurements using pressure transducers. The CFD calculations show that the density evolution is slower than the pressure drop. Surrogate models were built based on CFD calculations and validated against preliminary tests in the CABRI transient system. Studies also show that it is harder to predict the depressurization during the power transients because of neutron/3He capture reactions that induce a gas heating. This phenomenon can be studied by a multiphysics approach based on reaction rate calculation thanks to Monte Carlo code and study the resulting heating effect with the validated CFD simulation.

Facile Fabrication of Multi-hierarchical Porous Polyaniline Composite as Pressure Sensor and Gas Sensor with Adjustable Sensitivity

Science.gov (United States)

He, Xiao-Xiao; Li, Jin-Tao; Jia, Xian-Sheng; Tong, Lu; Wang, Xiao-Xiong; Zhang, Jun; Zheng, Jie; Ning, Xin; Long, Yun-Ze

2017-08-01

A multi-hierarchical porous polyaniline (PANI) composite which could be used in good performance pressure sensor and adjustable sensitivity gas sensor has been fabricated by a facile in situ polymerization. Commercial grade sponge was utilized as a template scaffold to deposit PANI via in situ polymerization. With abundant interconnected pores throughout the whole structure, the sponge provided sufficient surface for the growth of PANI nanobranches. The flexible porous structure helped the composite to show high performance in pressure detection with fast response and favorable recoverability and gas detection with adjustable sensitivity. The sensing mechanism of the PANI/sponge-based flexible sensor has also been discussed. The results indicate that this work provides a feasible approach to fabricate efficient sensors with advantages of low cost, facile preparation, and easy signal collection.

Synthesis and application of graphene–silver nanowires composite for ammonia gas sensing

International Nuclear Information System (INIS)

Tran, Quang Trung; Huynh, Tran My Hoa; Tong, Duc Tai; Tran, Van Tam; Nguyen, Nang Dinh

2013-01-01

Graphene, consisting of a single carbon layer in a two-dimensional (2D) lattice, has been a promising material for application to nanoelectrical devices in recent years. In this study we report the development of a useful ammonia (NH 3 ) gas sensor based on graphene–silver nanowires ‘composite’ with planar electrode structure. The basic strategy involves three steps: (i) preparation of graphene oxide (GO) by modified Hummers method; (ii) synthesis of silver nanowires by polyol method; and (iii) preparation of graphene and silver nanowires on two electrodes using spin and spray-coating of precursor solutions, respectively. Exposure of this sensor to NH 3 induces a reversible resistance change at room temperature that is as large as ΔR/R 0 ∼ 28% and this sensitivity is eight times larger than the sensitivity of the ‘intrinsic’ graphene based NH 3 gas sensor (ΔR/R 0 ∼ 3,5%). Their responses and the recovery times go down to ∼200 and ∼60 s, respectively. Because graphene synthesized by chemical methods has many defects and small sheets, it cannot be perfectly used for gas sensor or for nanoelectrical devices. The silver nanowires are applied to play the role of small bridges connecting many graphene islands together to improve electrical properties of graphene/silver nanowires composite and result in higher NH 3 gas sensitivity. (paper)

Gulping phenomena in transient countercurrent two-phase flow

International Nuclear Information System (INIS)

Tehrani, Ali A.K.

2001-04-01

Apart from previous work on countercurrent gas-liquid flow, transient tank drainage through horizontal off-take pipes is described, including experimental procedure, flow pattern on observations and countercurrent flow limitation results. A separate chapter is devoted to countercurrent two-phase flow in a pressurised water reactor hot-leg scaled model. Results concerning low head flooding, high head and loss of bowl flooding, transient draining of the steam generator and pressure variation and bubble detachment are presented. The following subjects are covered as well: draining of sealed tanks of vertical pipes, unsteady draining of closed vessel via vertical tube, unsteady filling of a closed vessel via vertical tube from a constant head reservoir. Practical significance of the results obtained is discussed

TS-1 and TS-2 transient overpower tests on FFTF fuel

International Nuclear Information System (INIS)

Pitner, A.L.; Ferrell, P.C.; Culley, G.E.; Weber, E.T.

1985-01-01

The TS-1 and TS-2 TREAT transient experiments subjected a low burnup (2 MWd/kg) and a medium burnup (58 MWd/kg), respectively, FFTF irradiated fuel pin to unprotected 5 cents/s overpower transient conditions. The fuel pin failure response was similar in the two tests, which demonstrated a large margin to failure (P/P 0 > 3) and a favorable upper level failure location. Thus, for these transient conditions, burnup effects on transient performance appeared to be minimal in the range tested. Pin disruption in the medium burnup TS-2 test was more severe due to the higher fission gas pressurization, but failure occurred at only a 5% lower power level than for the low burnup TS-1 fuel pin. Both tests exhibited axial extrusion of molten fuel to the region above the fuel column several seconds before pin failure, demonstrating a potentially beneficial inherent safety mechanism to delay failure and mitigate accident consequences

TMCC: a transient three-dimensional neutron transport code by the direct simulation method - 222

International Nuclear Information System (INIS)

Shen, H.; Li, Z.; Wang, K.; Yu, G.

2010-01-01

A direct simulation method (DSM) is applied to solve the transient three-dimensional neutron transport problems. DSM is based on the Monte Carlo method, and can be considered as an application of the Monte Carlo method in the specific type of problems. In this work, the transient neutronics problem is solved by simulating the dynamic behaviors of neutrons and precursors of delayed neutrons during the transient process. DSM gets rid of various approximations which are always necessary to other methods, so it is precise and flexible in the requirement of geometric configurations, material compositions and energy spectrum. In this paper, the theory of DSM is introduced first, and the numerical results obtained with the new transient analysis code, named TMCC (Transient Monte Carlo Code), are presented. (authors)

Laboratory investigations of Titan haze formation: In situ measurement of gas and particle composition

Science.gov (United States)

Hörst, Sarah M.; Yoon, Y. Heidi; Ugelow, Melissa S.; Parker, Alex H.; Li, Rui; de Gouw, Joost A.; Tolbert, Margaret A.

2018-02-01

Prior to the arrival of the Cassini-Huygens spacecraft, aerosol production in Titan's atmosphere was believed to begin in the stratosphere where chemical processes are predominantly initiated by far ultraviolet (FUV) radiation. However, measurements taken by the Cassini Ultraviolet Imaging Spectrograph (UVIS) and Cassini Plasma Spectrometer (CAPS) indicate that haze formation initiates in the thermosphere where there is a greater flux of extreme ultraviolet (EUV) photons and energetic particles available to initiate chemical reactions, including the destruction of N2. The discovery of previously unpredicted nitrogen species in measurements of Titan's atmosphere by the Cassini Ion and Neutral Mass Spectrometer (INMS) indicates that nitrogen participates in the chemistry to a much greater extent than was appreciated before Cassini. The degree of nitrogen incorporation in the haze particles is important for understanding the diversity of molecules that may be present in Titan's atmosphere and on its surface. We have conducted a series of Titan atmosphere simulation experiments using either spark discharge (Tesla coil) or FUV photons (deuterium lamp) to initiate chemistry in CH4/N2 gas mixtures ranging from 0.01% CH4/99.99% N2 to 10% CH4/90% N2. We obtained in situ real-time measurements using a high-resolution time-of-flight aerosol mass spectrometer (HR-ToF-AMS) to measure the particle composition as a function of particle size and a proton-transfer ion-trap mass spectrometer (PIT-MS) to measure the composition of gas phase products. These two techniques allow us to investigate the effect of energy source and initial CH4 concentration on the degree of nitrogen incorporation in both the gas and solid phase products. The results presented here confirm that FUV photons produce not only solid phase nitrogen bearing products but also gas phase nitrogen species. We find that in both the gas and solid phase, nitrogen is found in nitriles rather than amines and that both the

Synthetic crystalline ferroborosilicate compositions, the preparation thereof and their use in the conversion of synthesis gas to low molecular weight hydrocarbons

International Nuclear Information System (INIS)

Hinnenkamp, J.A.; Walatka, V.V.

1987-01-01

A method for the conversion of synthesis gas is described comprising: contacting synthesis gas which comprises hydrogen and carbon monoxide with a catalytically effective amount of a crystalline ferroborosilicate composition, under conversion conditions effective to provide ethane selectivity of at least 40%. The borosilicate composition is represented in terms of mole ratios as follows: (0.2 to 15) M/sub 2/m/O:(0.2 to 10) Z/sub 2/ O /sub 3/: (5 to 1000) SiO/sub 2/: Fe/sub 2/n/O: (0 to 2000) H/sub 2/O wherein M comprises a cation of a quaternary ammonium, metal, ammonium, hydrogen and mixtures thereof, m is the valence of the cation, n is the valence of the iron cation, and Z is boron. The composition contains ion-exchanged palladium or palladium impregnated onto the composition

Influence of Aerogel Morphology and Reinforcement Architecture on Gas Convection in Aerogel Composites

Science.gov (United States)

Hurwitz, Frances I.; Meyer, Matthew; Guo, Haiquan; Rogers, Richard B.; DeMange, Jeffrey J.; Richardson, Hayley

2016-01-01

A variety of thermal protection applications require lightweight insulation capable of withstanding temperatures well above 900 C. Aerogels offer extremely low-density thermal insulation due to their mesoporous structure, which inhibits both gas convection and solid conduction. Silica aerogel systems are limited to use temperatures of 600-700 C, above which they sinter. Alumina aerogels maintain a porous structure to higher temperatures than silica, before transforming to -alumina and densifying. We have synthesized aluminosilicate aerogels capable of maintaining higher surface areas at temperatures above 1100 C than an all-alumina aerogel using -Boehmite as the aluminum source and tetraethoxysilane (TEOS) as the silicon source. The pore structure of these aerogels varies with thermal exposure temperature and time, as the aluminosilicate undergoes a variety of phase changes to form transition aluminas. Transformation to -alumina is inhibited by incorporation of silica into the alumina lattice. The aerogels are fragile, but can be reinforced using a large variety of ceramic papers, felts or fabrics. The objective of the current study is to characterize the influence of choice of reinforcement and architecture on gas permeability of the aerogel composites in both the as fabricated condition and following thermal exposure, as well as understand the effects of incorporating hydrophobic treatments in the composites.

Effects of gas composition on the growth of multi-walled carbon nanotube

International Nuclear Information System (INIS)

Fang, T.-H.; Chang, W.-J.; Lu, D.-M.; Lien, W.-C.

2007-01-01

This paper studies the effects of different gas compositions on the growth of multi-walled carbon nanotube (MWCNT) films by using an electron cyclotron resonance chemical vapor deposition (ECR-CVD) method. The Raman spectrum was employed to explore the composition of the MWCNT films grown under different mixtures of C 3 H 8 and H 2 . The results showed that the optimum relative intensity ratio of the D band to G band (i.e., I D /I G ) is 2 for the cases considered in this study. In addition, the morphology and microstructure of the MWCNTs were examined by field emission scanning electron microscopy (FE-SEM) and field emission gun transmission electron microscopy (FEG-TEM). Furthermore, atomic force microscopy (AFM) and scanning thermal microscopy (SThM) were used to study the surface topography and thermal properties of the MWCNTs

FORAGE YIELD, CHEMICAL COMPOSITION AND IN VITRO GAS PRODUCTION OF YELLOW HYBRID MAIZE GROWN IN MEXICO

Directory of Open Access Journals (Sweden)

Lizbeth Esmeralda Roblez Jimenez

2017-12-01

Full Text Available Maize is the most important forage in feed cattle, due to its higher energy content, however, it is characterized by its wide range of varieties and the possibility of generating a large quantity of final products. The objective of the present study was to evaluate and compare the forage yield, chemical composition and in vitro gas production as fresh and hay of a local yellow criollo maize and six varieties of yellow hybrid maize (HIT13, CML460, PIONER, COPPER, CDMO80001 and CLO80902. Fresh and dry yield did not show differences between treatments (P>0.05, their chemical composition (g / kg DM showed differences (P ˂ 0.05 for the protein content by various storage methods ranging from 59.87 to 59.61 g kg-1 DM per conservation method, NDF ranged from 591 to 686 g kg-1 DM by variety and by the method ranged from 619 to 639 g kg -1 DM, ADF ranged from 298 to 345 g kg-1 DM by variety and 317 to 340 g kg-1 DM by conservation method; ADL ranged from 58 to 41 g kg-1 DM by variety and 41 to 57 g kg-1 DM by conservation method, in vitro gas production  there were no differences (P>0.05 between varieties and conservation method. It is concluded that according to the results obtained, the varieties studied show the same forage yields in both hay and fresh, chemical composition, and in vitro gas production.

PALLADIUM/COPPER ALLOY COMPOSITE MEMBRANES FOR HIGH TEMPERATURE HYDROGEN SEPARATION FROM COAL-DERIVED GAS STREAMS; F

International Nuclear Information System (INIS)

J. Douglas Way; Robert L. McCormick

2001-01-01

Recent advances have shown that Pd-Cu composite membranes are not susceptible to the mechanical, embrittlement, and poisoning problems that have prevented widespread industrial use of Pd for high temperature H(sub 2) separation. These membranes consist of a thin ((approx)10(micro)m) film of metal deposited on the inner surface of a porous metal or ceramic tube. Based on preliminary results, thin Pd(sub 60)Cu(sub 40) films are expected to exhibit hydrogen flux up to ten times larger than commercial polymer membranes for H(sub 2) separation, and resist poisoning by H(sub 2)S and other sulfur compounds typical of coal gas. Similar Pd-membranes have been operated at temperatures as high as 750 C. The overall objective of the proposed project is to demonstrate the feasibility of using sequential electroless plating to fabricate Pd(sub 60)Cu(sub 40) alloy membranes on porous supports for H(sub 2) separation. These following advantages of these membranes for processing of coal-derived gas will be demonstrated: High H(sub 2) flux; Sulfur tolerant, even at very high total sulfur levels (1000 ppm); Operation at temperatures well above 500 C; and Resistance to embrittlement and degradation by thermal cycling. The proposed research plan is designed to providing a fundamental understanding of: Factors important in membrane fabrication; Optimization of membrane structure and composition; Effect of temperature, pressure, and gas composition on H(sub 2) flux and membrane selectivity; and How this membrane technology can be integrated in coal gasification-fuel cell systems

Temperature and distortion transients in gas tungsten-arc weldments

International Nuclear Information System (INIS)

Glickstein, S.S.; Friedman, E.

1979-10-01

An analysis and test program to develop a fundamental understanding of the gas tungsten-arc welding process has been undertaken at the Bettis Atomic Power Laboratory to develop techniques to determine and control the various welding parameters and weldment conditions so as to result in optimum weld response characteristics. These response characteristics include depth of penetration, weld bead configuration, weld bead sink and roll, distortion, and cracking sensitivity. The results are documented of that part of the program devoted to analytical and experimental investigations of temperatures, weld bead dimensions, and distortions for moving gas tungsten-arc welds applied to Alloy 600 plates

Equation of state for L.M.F.B.R. fuel (measurement of fission gas release during transients)

International Nuclear Information System (INIS)

Combette, P.; Barthelemy, P.

1979-01-01

A sample of fuel (UO 2 or UPuO 2 ) can be heated by fission in a heating transient up to energy deposition 4000 j/g, in the Silene reactor. The Kistler type capsule, the calorimeter device and the radiochemical analysis of fission products enable the pressure pulse and the fuel energy deposition to be measured. So, the relationship between the fuel vapour pressure and the fuel specific energy can be deduced. Peaks pressure (about 1 MPa) coming from fresh UO 2 vaporization, have been measured on a 7 milliseconds time scale. There is a good agreement with the E.O.S. for fresh UO 2 , which is well known for low pressure (1 MPa). Numerous tests have been done with 93% enriched UO 2 and a first test with highly active fuel containing plutonium (15 at %) has been performed. The capsule allows the released gas coming from the irradiated fuel to be retained for measurements and analysis. To investigate the mode of fuel disruption, in-pile fission-heated fuel pellets has been recorded by high speed cinematography

Effects of neutron irradiation on mechanical properties of silicon carbide composites fabricated by nano-infiltration and transient eutectic-phase process

International Nuclear Information System (INIS)

Koyanagi, T.; Hinoki, T.; Shimoda, K.; Ozawa, K.; Katoh, Y.

2014-01-01

Unidirectional silicon carbide (SiC)-fiber-reinforced SiC matrix (SiC/SiC) composites fabricated by a nano-infiltration and transient eutectic-phase (NITE) process were irradiated with neutrons at 830°C to 5.9 dpa, and at 1270°C to 5.8 dpa. The in-plane and trans-thickness tensile and the inter-laminar shear properties were evaluated at ambient temperature. The mechanical characteristics, including the quasi-ductile behavior, the proportional limit stress, and the ultimate tensile strength, were retained subsequent to irradiation. Analysis of the stress–strain hysteresis loop indicated the increased fiber/matrix interface friction and the decreased residual stresses. The inter-laminar shear strength exhibited a significant decrease following irradiation. (author)

Quantitative measurement of carbon isotopic composition in CO2 gas reservoir by Micro-Laser Raman spectroscopy.

Science.gov (United States)

Li, Jiajia; Li, Rongxi; Zhao, Bangsheng; Guo, Hui; Zhang, Shuan; Cheng, Jinghua; Wu, Xiaoli

2018-04-15

The use of Micro-Laser Raman spectroscopy technology for quantitatively determining gas carbon isotope composition is presented. In this study, 12 CO 2 and 13 CO 2 were mixed with N 2 at various molar fraction ratios to obtain Raman quantification factors (F 12CO2 and F 13CO2 ), which provide a theoretical basis for calculating the δ 13 C value. And the corresponding values were 0.523 (0Raman peak area can be used for the determination of δ 13 C values within the relative errors range of 0.076% to 1.154% in 13 CO 2 / 12 CO 2 binary mixtures when F 12CO2 /F 13CO2 is 0.466972625. In addition, measurement of δ 13 C values by Micro-Laser Raman analysis were carried out on natural CO 2 gas from Shengli Oil-field at room temperature under different pressures. The δ 13 C values obtained by Micro-Laser Raman spectroscopy technology and Isotope Ratio Mass Spectrometry (IRMS) technology are in good agreement with each other, and the relative errors range of δ 13 C values is 1.232%-6.964%. This research provides a fundamental analysis tool for determining gas carbon isotope composition (δ 13 C values) quantitatively by using Micro-Laser Raman spectroscopy. Experiment of results demonstrates that this method has the potential for obtaining δ 13 C values in natural CO 2 gas reservoirs. Copyright © 2018. Published by Elsevier B.V.

Current status of the transient integral fuel element performance code URANUS

International Nuclear Information System (INIS)

Preusser, T.; Lassmann, K.

1983-01-01

To investigate the behavior of fuel pins during normal and off-normal operation, the integral fuel rod code URANUS has been extended to include a transient version. The paper describes the current status of the program system including a presentation of newly developed models for hypothetical accident investigation. The main objective of current development work is to improve the modelling of fuel and clad material behavior during fast transients. URANUS allows detailed analysis of experiments until the onset of strong material transport phenomena. Transient fission gas analysis is carried out due to the coupling with a special version of the LANGZEIT-KURZZEIT-code (KfK). Fuel restructuring and grain growth kinetics models have been improved recently to better characterize pre-experimental steady-state operation; transient models are under development. Extensive verification of the new version has been carried out by comparison with analytical solutions, experimental evidence, and code-to-code evaluation studies. URANUS, with all these improvements, has been successfully applied to difficult fast breeder fuel rod analysis including TOP, LOF, TUCOP, local coolant blockage and specific carbide fuel experiments. Objective of further studies is the description of transient PCMI. It is expected that the results of these developments will contribute significantly to the understanding of fuel element structural behavior during severe transients. (orig.)

Investigation of Continuous Gas Engine CHP Operation on Biomass Producer Gas

DEFF Research Database (Denmark)

Ahrenfeldt, Jesper; Henriksen, Ulrik Birk; Jensen, Torben Kvist

2005-01-01

More than 2000 hours of gas engine operation with producer gas from biomass as fuel has been conducted on the gasification CHP demonstration and research plant, named “Viking” at the Technical University of Denmark. The gas engine is an integrated part of the entire gasification plant. The excess...... operates with varying excess of air due to variation in gas composition and thus stoichiometry, and a second where the excess of air in the exhaust gas is fixed and the flow rate of produced gas from the gasifier is varying. The interaction between the gas engine and the gasification system has been...... investigated. The engine and the plant are equipped with continuously data acquisition that monitors the operation including the composition of the producer gas and the flow. Producer gas properties and contaminations have been investigated. No detectable tar or particle content was observed...

Linkages between ocean circulation, heat uptake and transient warming: a sensitivity study

Science.gov (United States)

Pfister, Patrik; Stocker, Thomas

2016-04-01

Transient global warming due to greenhouse gas radiative forcing is substantially reduced by ocean heat uptake (OHU). However, the fraction of equilibrium warming that is realized in transient climate model simulations differs strongly between models (Frölicher and Paynter 2015). It has been shown that this difference is not only related to the magnitude of OHU, but also to the radiative response the OHU causes, measured by the OHU efficacy (Winton et al., 2010). This efficacy is strongly influenced by the spatial pattern of the OHU and its changes (Rose et al. 2014, Winton et al. 2013), predominantly caused by changes in the Atlantic meridional overturning circulation (AMOC). Even in absence of external greenhouse gas forcing, an AMOC weakening causes a radiative imbalance at the top of the atmosphere (Peltier and Vettoretti, 2014), inducing in a net warming of the Earth System. We investigate linkages between those findings by performing both freshwater and greenhouse gas experiments in an Earth System Model of Intermediate Complexity. To assess the sensitivity of the results to ocean and atmospheric transport as well as climate sensitivity, we use an ensemble of model versions, systematically varying key parameters. We analyze circulation changes and radiative adjustments in conjunction with traditional warming metrics such as the transient climate response and the equilibrium climate sensitivity. This aims to improve the understanding of the influence of ocean circulation and OHU on transient climate change, and of the relevance of different metrics for describing this influence. References: Frölicher, T. L. and D.J. Paynter (2015), Extending the relationship between global warming and cumulative carbon emissions to multi-millennial timescales, Environ. Res. Lett., 10, 075022 Peltier, W. R., and G. Vettoretti (2014), Dansgaard-Oeschger oscillations predicted in a comprehensive model of glacial climate: A "kicked" salt oscillator in the Atlantic, Geophys. Res

Renormalization of Fermi Velocity in a Composite Two Dimensional Electron Gas

Science.gov (United States)

Weger, M.; Burlachkov, L.

We calculate the self-energy Σ(k, ω) of an electron gas with a Coulomb interaction in a composite 2D system, consisting of metallic layers of thickness d ≳ a0, where a0 = ħ2ɛ1/me2 is the Bohr radius, separated by layers with a dielectric constant ɛ2 and a lattice constant c perpendicular to the planes. The behavior of the electron gas is determined by the dimensionless parameters kFa0 and kFc ɛ2/ɛ1. We find that when ɛ2/ɛ1 is large (≈5 or more), the velocity v(k) becomes strongly k-dependent near kF, and v(kF) is enhanced by a factor of 5-10. This behavior is similar to the one found by Lindhard in 1954 for an unscreened electron gas; however here we take screening into account. The peak in v(k) is very sharp (δk/kF is a few percent) and becomes sharper as ɛ2/ɛ1 increases. This velocity renormalization has dramatic effects on the transport properties; the conductivity at low T increases like the square of the velocity renormalization and the resistivity due to elastic scattering becomes temperature dependent, increasing approximately linearly with T. For scattering by phonons, ρ ∝ T2. Preliminary measurements suggest an increase in vk in YBCO very close to kF.

Development of a system code for transient analysis in a HTGR

International Nuclear Information System (INIS)

Lee, Tae Beom

2004-02-01

A GAMMA (GAs Multi-component Multi-dimensional Analysis) code is developed for transient analysis and air ingress analysis in High Temperature Gas-cooled Reactors (HTGR). The PBMR of ESKOM is selected as a reference plant for the High Temperature Gas-cooled Reactor here, which uses a direct helium cycle and pebble fuel. Physical models included in GAMMA are the pebble conduction model, radiation heat transfer model, point kinetics model, decay heat model, and component models for break flow, valve, pump, cooler, power conversion unit model. The temperature distribution and the flow distribution of the PBMR are calculated for initial and accident core in the present study. In the accident analysis, typical design basis accident (DBA), including the load transient accident and depressurization accident into the system are selected and analyzed in detail. The predictions by GAMMA for PBMR at 100% power are compared with those by VSOP and PBR S IM. It turns out that the temperature in the upper region in the third channel predicted by GAMMA is about 62 .deg. C at maximum higher than that by VSOP, but is pretty close to that by PBR S IM. The center temperature of the fuel shows that that predicted by considering swelling effect is higher than that without swelling effect by about 10 .deg. C. The net efficiency of direct system is higher than that of indirect system due to an effect of the circulator power. The transient capability of GAMMA is validated through analytical solution and PBR S IM analyzing the depressurization (Loss Of Coolant Accident, LOCA) and load transient accident. After the LOCA the system pressure decreases dramatically from 8MPa to 0.4MPa within 2 sec. After the PI (Proportional-plus-Integral) controller senses that the power shaft is over the set-point of 3,600 rpm, the bypass valve makes shaft speed back to the set-point

In-situ study of the gas-phase composition and temperature of an intermediate-temperature solid oxide fuel cell anode surface fed by reformate natural gas

Science.gov (United States)

Santoni, F.; Silva Mosqueda, D. M.; Pumiglia, D.; Viceconti, E.; Conti, B.; Boigues Muñoz, C.; Bosio, B.; Ulgiati, S.; McPhail, S. J.

2017-12-01

An innovative experimental setup is used for in-depth and in-operando characterization of solid oxide fuel cell anodic processes. This work focuses on the heterogeneous reactions taking place on a 121 cm2 anode-supported cell (ASC) running with a H2, CH4, CO2, CO and steam gas mixture as a fuel, using an operating temperature of 923 K. The results have been obtained by analyzing the gas composition and temperature profiles along the anode surface in different conditions: open circuit voltage (OCV) and under two different current densities, 165 mA cm-2 and 330 mA cm-2, corresponding to 27% and 54% of fuel utilization, respectively. The gas composition and temperature analysis results are consistent, allowing to monitor the evolution of the principal chemical and electrochemical reactions along the anode surface. A possible competition between CO2 and H2O in methane internal reforming is shown under OCV condition and low current density values, leading to two different types of methane reforming: Steam Reforming and Dry Reforming. Under a current load of 40 A, the dominance of exothermic reactions leads to a more marked increase of temperature in the portion of the cell close to the inlet revealing that current density is not uniform along the anode surface.

Standard practice for examination of Gas-Filled filament-wound composite pressure vessels using acoustic emission

CERN Document Server

American Society for Testing and Materials. Philadelphia

2010-01-01

1.1 This practice provides guidelines for acoustic emission (AE) examination of filament-wound composite pressure vessels, for example, the type used for fuel tanks in vehicles which use natural gas fuel. 1.2 This practice requires pressurization to a level equal to or greater than what is encountered in normal use. The tanks' pressurization history must be known in order to use this practice. Pressurization medium may be gas or liquid. 1.3 This practice is limited to vessels designed for less than 690 bar [10,000 psi] maximum allowable working pressure and water volume less than 1 m3 or 1000 L [35.4 ft3]. 1.4 AE measurements are used to detect emission sources. Other nondestructive examination (NDE) methods may be used to gain additional insight into the emission source. Procedures for other NDE methods are beyond the scope of this practice. 1.5 This practice applies to examination of new and in-service filament-wound composite pressure vessels. 1.6 This practice applies to examinations conducted at amb...

Effect of pressure on the transient swelling rate of oxide fuel

International Nuclear Information System (INIS)

Gruber, E.E.

1982-04-01

An analysis of the transient swelling rate of oxide fuel, based on fission-gas bubble conditions calculated with the FRAS3 code, has been developed and implemented in the code. The need for this capability arises in the coupling of the FRAS3 fission-gas analysis code to the FPIN fuel-pin mechanics code. An efficient means of closely coupling the calculations of swelling strains and stresses between the modules is required. The present analysis provides parameters that allow the FPIN calculation to proceed through a fairly large time step, using estimated swelling rates, to calculate the stresses. These stress values can then be applied in the FRAS3 detailed calculation to refine the swelling calculation, and to provide new values for the parameters to estimate the swelling in the next time step. The swelling rates were calculated for two representative transients and used to estimate swelling over a short time period for various stress levels

Theoretical study on composition of gas produced by coal gasification; Sekitan gas ka de seiseisuru gas no sosei ni kansuru kosatsu (HYCOL data no doteki kaiseki)

Energy Technology Data Exchange (ETDEWEB)

Kaiho, M.; Yasuda, H.; Kobayashi, M.; Yamada, O.; Soneda, Y.; Makino, M. [National Institute for Resources and Environment, Tsukuba (Japan)

1996-10-28

In relation to considerations on composition of gas produced by coal gasification, the HYCOL hydrogen generation process data were analyzed. From the fact that CO concentration (Y) decreases linearly with CO2 concentration (X), element balance of gasification of reacted coal was used to introduce a reaction analysis equation. The equation includes a term of oxygen excess {Delta}(amount of oxygen consumed for combustion of CO and H2 in excess of the theoretical amount), derived by subtracting the stoichiometric oxygen amount used to gasify coal into CO and H2 from the consumed oxygen amount. The {Delta} can be used as a reference to oxygen utilization efficiency. An equation for the {Delta} was introduced. Also introduced was a term for steam decomposition amount derived by subtracting the generated steam from the supplied steam. These terms may be used as a clue to permeate into the gasifying reaction process. This suggestion was discussed by applying the terms to gas composition value during operation. According to the HYCOL analysis, when a gasification furnace is operated at higher than the reference oxygen amount, coal supply variation is directly reflected to the combustion reaction, making the {Delta} distribution larger. In an inverse case, unreacted carbon remains in the furnace due to oxygen shortage, and shift reaction may occur more easily even if oxygen/coal supply ratio varies. 6 figs., 1 ref.

Kinetics of a gas adsorption compressor

Science.gov (United States)

Chan, C. K.; Tward, E.; Elleman, D. D.

1984-01-01

Chan (1981) has suggested that a process based on gas adsorption could be used as a means to drive a Joule-Thomson (J-T) device. The resulting system has several advantages. It is heat powered, it has no sealing, there are no mechanical moving parts, and no active control is required. In the present investigation, a two-phase model is used to analyze the transients of a gas adsorption compressor. The modeling of the adsorption process is based on a consideration of complete thermal and mechanical equilibrium between the gaseous phase and the adsorbed gas phase. The experimental arrangement for two sets of kinetic tests is discussed, and data regarding the experimental results are presented in graphs. For a theoretical study, a two-phase model was developed to predict the transient behavior of the compressor. A computer code was written to solve the governing equations with the aid of a standard forward marching predictor-corrector method.

SOIL-AIR PERMEABILITY MEASUREMENT WITH A TRANSIENT PRESSURE BUILDUP METHOD

Science.gov (United States)

An analytical solution for transient pressure change in a single venting well was derived from mass conservation of air, Darcy's law of flow in porous media, and the ideal gas law equation of state. Slopes of plots of Pw2 against ln (t+Δt)/Δt similar to Homer's plot were used to ...

Modelling transient 3D multi-phase criticality in fluidised granular materials - the FETCH code

International Nuclear Information System (INIS)

Pain, C.C.; Gomes, J.L.M.A.; Eaton, M.D.; Ziver, A.K.; Umpleby, A.P.; Oliveira, C.R.E. de; Goddard, A.J.H.

2003-01-01

The development and application of a generic model for modelling criticality in fluidised granular materials is described within the Finite Element Transient Criticality (FETCH) code - which models criticality transients in spatial and temporal detail from fundamental principles, as far as is currently possible. The neutronics model in FETCH solves the neutron transport in full phase space with a spherical harmonics angle of travel representation, multi-group in neutron energy, Crank Nicholson based in time stepping, and finite elements in space. The fluids representation coupled with the neutronics model is a two-fluid-granular-temperature model, also finite element fased. A separate fluid is used to represent the liquid/vapour gas and the solid fuel particle phases, respectively. Particle-particle, particle-wall interactions are modelled using a kinetic theory approach on an analogy between the motion of gas molecules subject to binary collisions and granular flows. This model has been extensively validated by comparison with fluidised bed experimental results. Gas-fluidised beds involve particles that are often extremely agitated (measured by granular temperature) and can thus be viewed as a particularly demanding application of the two-fluid model. Liquid fluidised systems are of criticality interest, but these can become demanding with the production of gases (e.g. radiolytic and water vapour) and large fluid/particle velocities in energetic transients. We present results from a test transient model in which fissile material ( 239 Pu) is presented as spherical granules subsiding in water, located in a tank initially at constant temperature and at two alternative over-pressures in order to verify the theoretical model implemented in FETCH. (author)

Serbian gas sector in the spotlight of oil and gas agreement with Russia

International Nuclear Information System (INIS)

Brkic, Dejan

2009-01-01

The Russian natural gas industry is the world's largest producer and transporter of natural gas. This paper identifies the benefits for Serbia as transient country to European Union for Russian natural gas through South Stream gas-line in the current political context of implementation of gas agreement. On the other hand, according to the Agreement on Stabilization and Integration to European Union, Serbia is obligatory to implement reforms in energy sector and its energy policy must be in accordance with the European Union policy. Republic of Serbia has produced and consumed natural gas domestically since 1952, but has always been net importer. Strategy of Energy Development in Serbia and especially, National Action Plan for the gasification on the territory of Republic of Serbia dedicated special attention to gas economy development in respect with expected contribution in efficient energy use and environmental policy protection in the country.

HEXEREI: a multi-channel heat conduction convection code for use in transient thermal hydraulic analysis of high-temperature, gas-cooled reactors. Interim report

International Nuclear Information System (INIS)

Giles, G.E.; DeVault, R.M.; Turner, W.D.; Becker, B.R.

1976-05-01

A description is given of the development and verification of a generalized coupled conduction-convection, multichannel heat transfer computer program to analyze specific safety questions involving high temperature gas-cooled reactors (HTGR). The HEXEREI code was designed to provide steady-state and transient heat transfer analysis of the HTGR active core using a basic hexagonal mesh and multichannel coolant flow. In addition, the core auxiliary cooling systems were included in the code to provide more complete analysis of the reactor system during accidents involving reactor trip and cooling down on the auxiliary systems. Included are brief descriptions of the components of the HEXEREI code and sample HEXEREI analyses compared with analytical solutions and other heat transfer codes

System transient analysis code development for low pressure and low power

International Nuclear Information System (INIS)

Kim, Hee Cheol

1998-02-01

A real time reactor system analysis code, ARTIST, based on drift flux model has been developed to investigate the transient system behavior under low pressure, low flow and low power conditions with noncondensable gas present in the system. The governing equations of the ARTIST code consist of three mass continuity equations (steam, liquid and noncondensable), two energy equations (gas and mixture) and one momentum equation (mixture) constituted with the drift flux model. The capability of ARTIST in predicting two-phase flow void distribution in the system has been validated against experimental data. The results of the ARTIST axial void distribution at low pressure and low flow, are far better than the results of both the homogeneous model of TASS code and the two-fluid model of RELAP5/MOD3 code. Also, RELAP5/MOD3 calculation shows the large amplitude of void fraction oscillations at low pressure. These results imply that interfacial momentum transfer terms in the two-fluid model formulation should be carefully constituted, especially for the low pressure condition due to the big density differences between steam and water. Thermal-hydraulic state solution scheme is developed when noncondensable gas exists. Numerical consistency and convergence of obtaining equilibrium state is tested with the ideal problems for various situations including very low partial pressure conditions. Calculated thermal-hydraulic state for each test shows consistent and expected behaviour. A new multi-layer back propagation network algorithm for calculating the departure from nucleate boiling ratio (DNBR) is developed and adopted in ARTIST code in order to have real-time DNBR evaluation by eliminating the tandem procedure of the transient DNBR calculation. The algorithm trained by different patterns generated by latin hypercube sampling method on the performance space is tested for the randomly sampled untrained data and the transient DNBR data. The uncertainty of the algorithm is

The supermassive black hole coincident with the luminous transient ASASSN-15lh

Science.gov (United States)

Krühler, T.; Fraser, M.; Leloudas, G.; Schulze, S.; Stone, N. C.; van Velzen, S.; Amorin, R.; Hjorth, J.; Jonker, P. G.; Kann, D. A.; Kim, S.; Kuncarayakti, H.; Mehner, A.; Nicuesa Guelbenzu, A.

2018-02-01

The progenitors of astronomical transients are linked to a specific stellar population and galactic environment, and observing their host galaxies hence constrains the physical nature of the transient itself. Here, we use imaging from the Hubble Space Telescope, and spatially resolved, medium-resolution spectroscopy from the Very Large Telescope obtained with X-shooter and MUSE to study the host of the very luminous transient ASASSN-15lh. The dominant stellar population at the transient site is old (around 1 to 2 Gyr) without signs of recent star formation. We also detect emission from ionized gas, originating from three different, time invariable, narrow components of collisionally excited metal and Balmer lines. The ratios of emission lines in the Baldwin-Phillips-Terlevich diagnostic diagram indicate that the ionization source is a weak active galactic nucleus with a black hole mass of M• = 5-3+8 × 108 M⊙, derived through the M•-σ relation. The narrow line components show spatial and velocity offsets on scales of 1 kpc and 500 km s-1, respectively; these offsets are best explained by gas kinematics in the narrow-line region. The location of the central component, which we argue is also the position of the supermassive black hole, aligns with that of the transient within an uncertainty of 170 pc. Using this positional coincidence as well as other similarities with the hosts of tidal disruption events, we strengthen the argument that the transient emission observed as ASASSN-15lh is related to the disruption of a star around a supermassive black hole, most probably spinning with a Kerr parameter a• ≳ 0.5. Based on observations at ESO, Program IDs: 097.D-1054, 297.B-5035, 099.D-0115.The data used in this manuscript are only available at the CDS via anonymous ftp to http://cdsarc.u-strasbg.fr (http://130.79.128.5) or via http://cdsarc.u-strasbg.fr/viz-bin/qcat?J/A+A/610/A14

THE CHEMICAL COMPOSITION AND VARIOUS SAMPLES PREPARATION METHODS FOR In Vitro GAS TEST OF TWO TROPICAL FEEDS

Directory of Open Access Journals (Sweden)

J. Daryatmo

2015-04-01

Full Text Available A 3x2 factorial experimental design was conducted to evaluate the chemical composition ofSesbania grandiflora (SG and Manihot esculenta Crantz (MEC leaves and to measure the effects ofpreparation and drying methods on the in vitro gas production in the presence and absence of PEG. Thecollected samples were divided into three groups: One group was fresh samples (F. The second groupwas oven-dried at 55°C for 48h (OD and the last group was freeze-dried at –40°C for 72h (FD. Resultsshowed that the mean value of gas production from fresh SG and MEC samples were not significantlyhigher (P<0.05 than from FD and OD samples. In SG and MEC, the mean value of gas production ofFD was not significant compared to OD samples (P>0.05. Gas production from samples added withPEG were higher (P<0.05 than without PEG. In conclusion, the preparation and drying methods of feedsamples could affect the volume of gas production. The addition of PEG in SG and MEC resulted inhigher gas production volumes.

Simulation of Water Level Fluctuations in a Hydraulic System Using a Coupled Liquid-Gas Model

Directory of Open Access Journals (Sweden)

Chao Wang

2015-08-01

Full Text Available A model for simulating vertical water level fluctuations with coupled liquid and gas phases is presented. The Preissmann implicit scheme is used to linearize the governing equations for one-dimensional transient flow for both liquid and gas phases, and the linear system is solved using the chasing method. Some classical cases for single liquid and gas phase transients in pipelines and networks are studied to verify that the proposed methods are accurate and reliable. The implicit scheme is extended using a dynamic mesh to simulate the water level fluctuations in a U-tube and an open surge tank without consideration of the gas phase. Methods of coupling liquid and gas phases are presented and used for studying the transient process and interaction between the phases, for gas phase limited in a chamber and gas phase transported in a pipeline. In particular, two other simplified models, one neglecting the effect of the gas phase on the liquid phase and the other one coupling the liquid and gas phases asynchronously, are proposed. The numerical results indicate that the asynchronous model performs better, and are finally applied to a hydropower station with surge tanks and air shafts to simulate the water level fluctuations and air speed.

A simple method to evaluate the fission gas release at fuel grain boundary including the grain growth both at constant and at transient power histories

International Nuclear Information System (INIS)

Paraschiv, M.; Paraschiv, A.

1991-01-01

A method to rewrite Fick's second law for a region with a moving boundary when the moving law in time of this boundary is known, has been proposed. This method was applied to Booth's sphere model for radioactive and stable fission product diffusion from the oxide fuel grain in order to take into account the grain growth. The solution of this new equation was presented in the mathematical formulation for power histories from ANS 5.4 model for the stable species. It is very simple to apply and very accurate. The results obtained with this solution for constant and transient temperatures show that the fission gas release (FGR) at grain boundary is strongly dependent on kinetics of grain growth. The utilization of two semiempirical grain growth laws, from published information, shows that the fuel microstructural properties need to be multicitly considered in the fission gas release for every manufacturer of fuel. (orig.)

A summary of volatile impurity measurements and gas generation studies on MISSTD-1, a high-purity plutonium oxide produced by low-temperature calcination of plutonium oxalate

Energy Technology Data Exchange (ETDEWEB)

Berg, John M. [Los Alamos National Laboratory; Narlesky, Joshua E. [Los Alamos National Laboratory; Veirs, Douglas K. [Los Alamos National Laboratory

2012-06-08

Plutonium dioxide of high specific surface area was subjected to long-term tests of gas generation in sealed containers. The material preparation and the storage conditions were outside the bounds of acceptable parameters defined by DOE-STD-3013-2012 in that the material was stabilized to a lower temperature than required and had higher moisture content than allowed. The data provide useful information for better defining the bounding conditions for safe storage. Net increases in internal pressure and transient increases in H{sub 2} and O{sub 2} were observed, but were well within the bounds of gas compositions previously shown to not threaten integrity of 3013 containers.

A summary of volatile impurity measurements and gas generation studies on MISSTD-1, a high-purity plutonium oxide produced by low-temperature calcination of plutonium oxalate

International Nuclear Information System (INIS)

Berg, John M.; Narlesky, Joshua E.; Veirs, Douglas K.

2012-01-01

Plutonium dioxide of high specific surface area was subjected to long-term tests of gas generation in sealed containers. The material preparation and the storage conditions were outside the bounds of acceptable parameters defined by DOE-STD-3013-2012 in that the material was stabilized to a lower temperature than required and had higher moisture content than allowed. The data provide useful information for better defining the bounding conditions for safe storage. Net increases in internal pressure and transient increases in H 2 and O 2 were observed, but were well within the bounds of gas compositions previously shown to not threaten integrity of 3013 containers.

Transient response of level instruments in a research reactor

International Nuclear Information System (INIS)

Cheng, Lap Y.

1989-01-01

A numerical model has been developed to simulate the dynamics of water level instruments in a research nuclear reactor. A bubble device, with helium gas as the working fluid, is used to monitor liquid level by sensing the static head pressure due to the height of liquid in the reactor vessel. A finite-difference model is constructed to study the transient response of the water level instruments to pressure perturbations. The field equations which describe the hydraulics of the helium gas in the bubbler device are arranged in the form of a tridiagonal matrix and the field variables are solved at each time step by the Thomas algorithm. Simulation results indicate that the dynamic response of the helium gas depends mainly on the volume and the inertia of the gas in the level instrument tubings. The anomalies in the simulated level indication are attributed to the inherent lag in the level instrument due to the hydraulics of the system. 1 ref., 5 figs

Improved lumped models for transient combined convective and radiative cooling of a two-layer spherical fuel element

International Nuclear Information System (INIS)

Silva, Alice Cunha da; Su, Jian

2013-01-01

The High Temperature Gas cooled Reactor (HTGR) is a fourth generation thermal nuclear reactor, graphite-moderated and helium cooled. The HTGRs have important characteristics making essential the study of these reactors, as well as its fuel element. Examples of these are: high thermal efficiency,low operating costs and construction, passive safety attributes that allow implication of the respective plants. The Pebble Bed Modular Reactor (PBMR) is a HTGR with spherical fuel elements that named the reactor. This fuel element is composed by a particulate region with spherical inclusions, the fuel UO2 particles, dispersed in a graphite matrix and a convective heat transfer by Helium happens on the outer surface of the fuel element. In this work, the transient heat conduction in a spherical fuel element of a pebble-bed high temperature reactor was studied in a transient situation of combined convective and radiative cooling. Improved lumped parameter model was developed for the transient heat conduction in the two-layer composite sphere subjected to combined convective and radiative cooling. The improved lumped model was obtained through two-point Hermite approximations for integrals. Transient combined convective and radiative cooling of the two-layer spherical fuel element was analyzed to illustrate the applicability of the proposed lumped model, with respect to die rent values of the Biot number, the radiation-conduction parameter, the dimensionless thermal contact resistance, the dimensionless inner diameter and coating thickness, and the dimensionless thermal conductivity. It was shown by comparison with numerical solution of the original distributed parameter model that the improved lumped model, with H2,1/H1,1/H0,0 approximation yielded significant improvement of average temperature prediction over the classical lumped model. (author)

Commissioning of the KATRIN Raman system for monitoring of the WGTS gas composition

Energy Technology Data Exchange (ETDEWEB)

Fischer, Sebastian; Bornschein, Beate; James, Timothy M.; Off, Andreas; Rupp, Simone; Seitz-Moskaliuk, Hendrik; Sturm, Michael; Wecker, Matthias [Karlsruhe Institute of Technology (Germany); Schloesser, Magnus [Universidad Complutense de Madrid (Spain); Karlsruhe Institute of Technology (Germany); Telle, Helmut H. [Universidad Complutense de Madrid (Spain)

2015-07-01

The Karlsruhe Tritium Neutrino (KATRIN) Experiment aims at determining the neutrino mass by the investigation of the endpoint energy-region of the tritium β-spectrum. Tritium in its molecular form ({sup 3}H{sub 2}) is injected into the Windowless Gaseous Tritium Source (WGTS) of KATRIN, and thus molecular effects, e.g. ro-vibrational excitations levels, have to be considered in the neutrino mass analysis in order to reach the design sensitivity of 200 meV/c{sup 2} (90% C.L.). As the source gas also contains impurities of the other hydrogen isotopes protium and deuterium - giving rise to different molecular excitation levels - continuous and precise monitoring of the source gas composition is required. Raman spectroscopy is the method of choice for this task as it is an inline and non-contact analysis method. In this talk, results from the recently performed commissioning phase of the KATRIN Raman system are presented: over the course of more than 50 days, consecutive Raman spectra (recorded with acquisition times of 60 s) of circulating tritium gas were acquired and analysed in real-time. In addition, valuable information on the system performance during long-term operation was gained.

A simple treatment of fission gas for normal and accident conditions

International Nuclear Information System (INIS)

Matthews, J.R.; Wood, M.H.

1980-01-01

A set of simple modules have been developed to describe fission gas release and swelling in oxide nuclear fuels for use in fuel behaviour codes. The methods used are simplifications of earlier more detailed work and contain several important developments that allow for improved accuracy over earlier simple treatments and the description of the fission gas bubble population with little penalty in computer time or storage. The three modules are: (i) intragranular fission gas behaviour during normal operation, which treats gas bubble nucleation, growth and destruction by fission fragments and the diffusion of gas to the grain boundaries by single gas atom diffusion, (ii) intragranular fission gas behaviour during rapid transients which treats the migration and coalescence of gas bubbles, the sweeping up of fission gas atoms by bubbles and the drift of gas bubbles to the grain boundary under the driving force of the temperature gradient, and (iii) intergranular fission gas behaviour, which treats the growth and interaction of face and edge bubbles on the grain boundary, their interlinkage and gas release. All these models allow for transient behaviour and are compared with experimental observations of both macroscopic swelling and gas release (and retention) and microscopic observations of bubble sizes and concentrations. (author)

Titan's organic aerosols: Molecular composition and structure of laboratory analogues inferred from pyrolysis gas chromatography mass spectrometry analysis

Science.gov (United States)

Morisson, Marietta; Szopa, Cyril; Carrasco, Nathalie; Buch, Arnaud; Gautier, Thomas

2016-10-01

Analogues of Titan's aerosols are of primary interest in the understanding of Titan's atmospheric chemistry and climate, and in the development of in situ instrumentation for future space missions. Numerous studies have been carried out to characterize laboratory analogues of Titan aerosols (tholins), but their molecular composition and structure are still poorly known. If pyrolysis gas chromatography mass spectrometry (pyr-GCMS) has been used for years to give clues about their chemical composition, highly disparate results were obtained with this technique. They can be attributed to the variety of analytical conditions used for pyr-GCMS analyses, and/or to differences in the nature of the analogues analyzed, that were produced with different laboratory set-ups under various operating conditions. In order to have a better description of Titan's tholin's molecular composition by pyr-GCMS, we carried out a systematic study with two major objectives: (i) exploring the pyr-GCMS analytical parameters to find the optimal ones for the detection of a wide range of chemical products allowing a characterization of the tholins composition as comprehensive as possible, and (ii) highlighting the role of the CH4 ratio in the gaseous reactive medium on the tholin's molecular structure. We used a radio-frequency plasma discharge to synthetize tholins with different concentrations of CH4 diluted in N2. The samples were pyrolyzed at temperatures covering the 200-700°C range. The extracted gases were then analyzed by GCMS for their molecular identification. The optimal pyrolysis temperature for characterizing the molecular composition of our tholins by GCMS analysis is found to be 600°C. This temperature choice results from the best compromise between the number of compounds released, the quality of the signal and the appearance of pyrolysis artifacts. About a hundred molecules are identified as pyrolysates. A common major chromatographic pattern appears clearly for all the

Earthworms change the quantity and composition of dissolved organic carbon and reduce greenhouse gas emissions during composting.

Science.gov (United States)

Nigussie, Abebe; Bruun, Sander; de Neergaard, Andreas; Kuyper, Thomas W

2017-04-01

Dissolved organic carbon (DOC) has recently been proposed as an indicator of compost stability. We assessed the earthworms' effect on DOC content and composition during composting, and linked compost stability to greenhouse gas emissions and feeding ratio. Earthworms reduced total DOC content, indicating larger stability of vermicompost than of thermophilic compost. The concentrations of humic acid and fulvic acid were reduced by earthworms, whereas there was no significant effect on hydrophobic neutrals and hydrophilics. The humic acid fraction was depleted more quickly than the other compounds, indicating humic acid degradation during composting. The optimum feeding ratio decreased DOC content compared to the high feeding ratio. The lowest N 2 O emissions were also observed at the optimum feeding ratio. Our study confirmed the use of DOC content and composition as an indicator of compost stability and suggested that feeding ratio should be considered when assessing the earthworms' effect on stabilisation and greenhouse gas emissions. Copyright © 2017 Elsevier Ltd. All rights reserved.

Characterization of gas tunnel type plasma sprayed hydroxyapatite-nanostructure titania composite coatings

Science.gov (United States)

Yugeswaran, S.; Kobayashi, A.; Ucisik, A. Hikmet; Subramanian, B.

2015-08-01

Hydroxyapatite (HA) can be coated onto metal implants as a ceramic biocompatible coating to bridge the growth between implants and human tissue. Meanwhile many efforts have been made to improve the mechanical properties of the HA coatings without affecting its bioactivity. In the present study, nanostructure titania (TiO2) was mixed with HA powder and HA-nanostructure TiO2 composite coatings were produced by gas tunnel type plasma spraying torch under optimized spraying conditions. For this purpose, composition of 10 wt% TiO2 + 90 wt% HA, 20 wt% TiO2 + 80 wt% HA and 30 wt% TiO2 + 70 wt% HA were selected as the feedstock materials. The phase, microstructure and mechanical properties of the coatings were characterized. The obtained results validated that the increase in weight percentage of nanostructure TiO2 in HA coating significantly increased the microhardness, adhesive strength and wear resistance of the coatings. Analysis of the in vitro bioactivity and cytocompatibility of the coatings were done using conventional simulated body fluid (c-SBF) solution and cultured green fluorescent protein (GFP) labeled marrow stromal cells (MSCs) respectively. The bioactivity results revealed that the composite coating has bio-active surface with good cytocompatibility.

Improvements to the transient solution in the PANTHER space-time code

International Nuclear Information System (INIS)

Kutt, P.K.; Knight, M.P.

1993-01-01

The three dimensional, two-group, nodal diffusion code PANTHER has been developed for the analysis of almost all thermal reactor types [pressurized water reactor (PWR), boiling water reactor, VVER, RBMK, advanced gas-cooled reactor, MAGNOX]. It can perform a comprehensive range of calculations for fuel management, operational support including on-line application, and transient analysis. Transient results for a number of light water reactor (LWR) benchmark problems have been reported previously. This paper outlines some recent developments of the transient solution in PANTHER, showing results for two LWR benchmark problems. Recently, PANTHER results have been accepted as the reference solutions for a Nuclear Energy Agency Committee on Reactor Physics (NEACRP) rod ejection benchmark Unlike previous simplified rod ejection benchmarks, it represents a real PWR with a detailed thermal model and cross sections dependent on boron, fuel temperature, and water density and temperature. This reference solution was computed with fine time steps

Segregated copper ratio experiment on transient stability (SeCRETS). Final Report

International Nuclear Information System (INIS)

Bruzzone, P.

2001-01-01

Two Nb 3 Sn, steel jacketed, cable-in-conduit conductors have been manufactured with identical non-Cu cross sections and the stabilizer either included in the Nb 3 Sn composite or partly segregated as copper wires. The two conductors are series connected and wound as a bifilar , single layer solenoid, assembled in the high field bore (11 T) of the SULTAN test facility. The operating current is up to 12 kA (400 A/mm 2 ). A transverse pulsed field is applied with ΔB up to 2.7 T, field rate up to 180 T/s and field integral up to 530 T 2 /s. In the dc test, a good agreement is found between the I c and the T cs results, both correctly scaling according to the parameters derived from the strand tests. The n-value from the V-I curve is in the range of 15. The current sharing at the high field section is correlated with a local current re-distribution, observed by arrays of miniature Hall sensors, detecting the self-field around the conductor. The ac losses results in the range of 2 to 9 Hz by gas flow calorimetry indicate coupling currents constant, nτ, in the range of 1.5 ms at high field, increasing by a factor of 2 with 12 kA transport current. Loss extrapolation to 0 frequency suggests that the loss curve may be not linear outside the test range, with higher nτ at lower field rate. The calorimetric loss estimation at the fast field transient (f=15 Hz) indicates nτ ≅ 2 ms. The ITER plasma disruption transients have been reproduced by the pulsed coils. Due to the very low ac losses, no quench could be generated in either conductor even reducing the temperature margin below 0.2-0.3 K. Very large field transients, with integral above 100 T 2 /s, are required to quench the conductors. In that range, the conductor without segregated copper has superior performance. Due to the large interstrand resistance (very low ac losses), the segregated copper has marginal contribution to the stability. No evidence of current redistribution is observed during the field transients

High temperature hydrogen sulfide adsorption on activated carbon - I. Effects of gas composition and metal addition

Science.gov (United States)

Cal, M.P.; Strickler, B.W.; Lizzio, A.A.

2000-01-01

Various types of activated carbon sorbents were evaluated for their ability to remove H2S from a simulated coal gas stream at a temperature of 550 ??C. The ability of activated carbon to remove H2S at elevated temperature was examined as a function of carbon surface chemistry (oxidation, thermal desorption, and metal addition), and gas composition. A sorbent prepared by steam activation, HNO3 oxidation and impregnated with Zn, and tested in a gas stream containing 0.5% H2S, 50% CO2 and 49.5% N2, had the greatest H2S adsorption capacity. Addition of H2, CO, and H2O to the inlet gas stream reduced H2S breakthrough time and H2S adsorption capacity. A Zn impregnated activated carbon, when tested using a simulated coal gas containing 0.5% H2S, 49.5% N2, 13% H2, 8.5% H2O, 21% CO, and 7.5% CO2, had a breakthrough time of 75 min, which was less than 25 percent of the length of breakthrough for screening experiments performed with a simplified gas mixture of 0.5% H2S, 50% CO2, and 49.5% N2.

A fishery-dependent based study of fish species composition and associated catch rates around oil and gas structures off Louisiana

International Nuclear Information System (INIS)

Stanley, D.R.; Wilson, C.A.

1990-01-01

The impact of oil and gas development on fish populations off Louisiana is presumed significant but poorly understood. This study was undertaken to determine the applicability of a logbook program in developing a long-term database of species composition and relative abundance of fish associated with oil and gas structures. A pilot logbook program involving 120 private vessel owners and 25 charterboat operators was conducted between March 1987 and December 1988. Participants recorded date, fishing time, fishing method, number of anglers, and catch composition at each structure fished. Logbooks from a total of 55 private vessel owners and 10 charterboat operators were used in the analysis. Data collected included 15,780 angler hours of fishing effort and 61,227 fish caught over the study period. A total of 1,719 trips were made to 589 different oil and gas structures with at least 46 different species of fish caught. Red snapper and spotted seatrout were the most commonly caught species and had the highest catch rates. Results differed from past logbook programs and creel surveys, possibly indicating a change in the community of fish associated with oil and gas structures

Exhaust gas recirculation for advanced diesel combustion cycles

International Nuclear Information System (INIS)

Asad, Usman; Zheng, Ming

2014-01-01

Highlights: • Analysis of the incremental (cycle-by-cycle) build-up of EGR. • Proposed one-step equations for transient/steady-state gas concentration estimation. • Defined an in-cylinder excess-air ratio to account for the recycled oxygen with EGR. • Demonstrated the use of intake oxygen as a reliable measure of EGR effectiveness. • Demonstrated the impact of engine load and intake pressure on EGR effectiveness. - Abstract: Modern diesel engines tend to utilize significantly large quantities of exhaust gas recirculation (EGR) and high intake pressures across the engine load range to meet NOx targets. At such high EGR rates, the combustion process and exhaust emissions tend to exhibit a marked sensitivity to small changes in the EGR quantity, resulting in unintended deviations from the desired engine performance characteristics (energy efficiency, emissions, stability). An accurate estimation of EGR and its effect on the intake dilution are, therefore, necessary to enable its application during transient engine operation or unstable combustion regimes. In this research, a detailed analysis that includes estimation of the transient (cycle-by-cycle) build-up of EGR and the time (engine cycles) required to reach the steady-state EGR operation has been carried out. One-step global equations to calculate the transient and steady-state gas concentrations in the intake and exhaust are proposed. The effects of engine load and intake pressure on EGR have been examined and explained in terms of intake charge dilution and in-cylinder excess-air ratio. The EGR analysis is validated against a wide range of empirical data that include low temperature combustion cycles, intake pressure and load sweeps. This research intends to not only formulate a clear understanding of EGR application for advanced diesel combustion but also to set forth guidelines for transient analysis of EGR

Gas flow characteristics of a time modulated APPJ: the effect of gas heating on flow dynamics

International Nuclear Information System (INIS)

Zhang, S; Sobota, A; Van Veldhuizen, E M; Bruggeman, P J

2015-01-01

This work investigates the flow dynamics of a radio-frequency (RF) non-equilibrium argon atmospheric pressure plasma jet. The RF power is at a frequency of 50 Hz or 20 kHz. Combined flow pattern visualizations (obtained by shadowgraphy) and gas temperature distributions (obtained by Rayleigh scattering) are used to study the formation of transient vortex structures in initial flow field shortly after the plasma is switched on and off in the case of 50 Hz modulation. The transient vortex structures correlate well with observed temperature differences. Experimental results of the fast modulated (20 kHz) plasma jet that does not induce changes of the gas temperature are also presented. The latter result suggests that momentum transfer by ions does not have dominant effect on the flow pattern close to the tube. It is argued that the increased gas temperature and corresponding gas velocity increase at the tube exit due to the plasma heating increases the admixing of surrounding air and reduces the effective potential core length. With increasing plasma power a reduction of the effective potential core length is observed with a minimum length for 5.6 W after which the length extends again. Possible mechanisms related to viscosity effects and ionic momentum transfer are discussed. (paper)

Theories of fission gas behaviour

Energy Technology Data Exchange (ETDEWEB)

Dias, J W.C. [Companhia Brasileira de Tecnologia Nuclear, Rio de Janeiro (Brazil). Diretoria de Tecnologia e Desenvolvimento; Merckx, K R

1976-01-01

A review is presented of the theoretical developments and experimental evidence that have helped to evolve current models used to describe the behavior of inert fission gases created during the irradiation of reactor fuel materials. The phenomena which are stressed relate primarily to steady state behavior of fuel elements but are also relevant to an understanding of transient behavior. The processes considered include gas atom solubility; gas atom diffusivity; bubble nucleation; and bubble growth by bubble coalescence.

Modeling the Control Systems of Gas-Turbines to Ensure Their Reliable Parallel Operation in the UPS of Russia

Energy Technology Data Exchange (ETDEWEB)

Vinogradov, A. Yu., E-mail: vinogradov-a@ntcees.ru; Gerasimov, A. S.; Kozlov, A. V.; Smirnov, A. N. [JSC “STC UPS” (Russian Federation)

2016-05-15

Consideration is given to different approaches to modeling the control systems of gas turbines as a component of CCPP and GTPP to ensure their reliable parallel operation in the UPS of Russia. The disadvantages of the approaches to the modeling of combined-cycle units in studying long-term electromechanical transients accompanied by power imbalance are pointed out. Examples are presented to support the use of more detailed models of gas turbines in electromechanical transient calculations. It is shown that the modern speed control systems of gas turbines in combination with relatively low equivalent inertia have a considerable effect on electromechanical transients, including those caused by disturbances not related to power imbalance.

Review of behavior of mixed-oxide fuel elements in extended overpower transient tests in EBR-II

International Nuclear Information System (INIS)

Tsai, H.; Neimark, L.A.

1994-10-01

From a series of five tests conducted in EBR-II, a substantial data base has been established on the performance of mixed-oxide fuel elements in a liquid-metal-cooled reactor under slow-ramp transient overpower conditions. Each test contained 19 preirradiated fuel elements with varying design and prior operating histories. Elements with aggressive design features, such as high fuel smear density and/or thin cladding, were included to accentuate transient effects. The ramp rates were either 0.1 or 10% ΔP/P/s and the overpowers ranged between ∼60 and 100% of the elements' prior power ratings. Six elements breached during the tests, all with aggressive design parameters. The other elements, including all those with moderate design features for the reference or advanced long-life drivers for PNC's prototype fast reactor Monju, maintained their cladding integrity during the tests. Posttest examination results indicated that fuel/cladding mechanical interaction (FCMI) was the most significant mechanism causing the cladding strain and breach. In contrast, pressure loading from the fission gas in the element plenum was less important, even in high-burnup elements. During an overpower transient, FCMI arises from fuel/cladding differential thermal expansion, transient fuel swelling, and, significantly, the gas pressure in the sealed central cavity of elements with substantial centerline fuel melting. Fuel performance data from these tests, including cladding breaching margin and transient cladding strain, are correlatable with fuel-element design and operating parameters. These correlations are being incorporated into fuel-element behavior codes. At the two tested ramp rates, fuel element behavior appears to be insensitive to transient ramp rate and there appears to be no particular vulnerability to slow ramp transients as previously perceived

ZEISIG: Approximate calculation of the intergranular gas fraction and the intragranular gas driven swelling for SAS4A

International Nuclear Information System (INIS)

Vaeth, L.

1993-02-01

A simple model has been developed for estimating, under steady-state irradiation conditions and for operational transients, the fraction of intergranular gas residing in fast reactor fuel and the intragranular gas driven swelling. The total gas retention in the fuel, the grain size and the irradiation conditions (mainly time dependent temperatures) must be known. Use has been made of parts of the fission gas model contained in the code LAKU and of results calculated with this code. The routine (named ZEISIG) is intended for insertion into the fast reactor accident model SAS4A as an extension of its fission gas model for steady-state reactor operation. (orig.) [de

Temperature profile and producer gas composition of high temperature air gasification of oil palm fronds

International Nuclear Information System (INIS)

Guangul, F M; Sulaiman, S A; Ramli, A

2013-01-01

Environmental pollution and scarcity of reliable energy source are the current pressing global problems which need a sustainable solution. Conversion of biomass to a producer gas through gasification process is one option to alleviate the aforementioned problems. In the current research the temperature profile and composition of the producer gas obtained from the gasification of oil palm fronds by using high temperature air were investigated and compared with unheated air. By preheating the gasifying air at 500°C the process temperature were improved and as a result the concentration of combustible gases and performance of the process were improved. The volumetric percentage of CO, CH4 and H2 were improved from 22.49, 1.98, and 9.67% to 24.98, to 2.48% and 13.58%, respectively. In addition, HHV, carbon conversion efficiency and cold gas efficiency were improver from 4.88 MJ/Nm3, 83.8% and 56.1% to 5.90 MJ/Nm3, 87.3% and 62.4%, respectively.

DEFORM-4: fuel pin characterization and transient response in the SAS4A accident analysis code system

International Nuclear Information System (INIS)

Miles, K.J.; Hill, D.J.

1986-01-01

The DEFORM-4 module is the segment of the SAS4A Accident Analysis Code System that calculates the fuel pin characterization in response to a steady state irradiation history, thereby providing the initial conditions for the transient calculation. The various phenomena considered include fuel porosity migration, fission gas bubble induced swelling, fuel cracking and healing, fission gas release, cladding swelling, and the thermal-mechanical state of the fuel and cladding. In the transient state, the module continues the thermal-mechanical response calculation, including fuel melting and central cavity pressurization, until cladding failure is predicted and one of the failed fuel modules is initiated. Comparisons with experimental data have demonstrated the validity of the modeling approach

Synthesis and Gas Transport Properties of Hyperbranched Polyimide–Silica Hybrid/Composite Membranes

Directory of Open Access Journals (Sweden)

Masako Miki

2013-12-01

Full Text Available Hyperbranched polyimide–silica hybrids (HBPI–silica HBDs and hyperbranched polyimide–silica composites (HBPI–silica CPTs were prepared, and their general and gas transport properties were investigated to clarify the effect of silica sources and preparation methods. HBPI–silica HBDs and HBPI–silica CPTs were synthesized by two-step polymerization of A2 + B3 monomer system via polyamic acid as precursor, followed by hybridizing or blending silica sources. Silica components were incorporated by the sol-gel reaction with tetramethoxysilane (TMOS or the addition of colloidal silica. In HBPI-silica HBDs, the aggregation of silica components is controlled because of the high affinity of HBPI and silica caused by the formation of covalent bonds between HBPI and silica. Consequently, HBPI-silica HBDs had good film formability, transparency, and mechanical properties compared with HBPI-silica CPTs. HBPI-silica HBD and CPT membranes prepared via the sol-gel reaction with TMOS showed specific gas permeabilities and permselectivities for CO2/CH4 separation, that is, both CO2 permeability and CO2/CH4 selectivity increased with increasing silica content. This result suggests that gas transport can occur through a molecular sieving effect of the porous silica network derived from the sol-gel reaction and/or through the narrow interfacial region between the silica networks and the organic matrix.

Analysis of fuel pin behavior under slow-ramp type transient overpower condition by using the fuel performance evaluation code 'FEMAXI-FBR'

International Nuclear Information System (INIS)

Tsuboi, Yasushi; Ninokata, Hisashi; Endo, Hiroshi; Ishizu, Tomoko; Tatewaki, Isao; Saito, Hiroaki

2012-01-01

FEMAXI-FBR has been developed as the one module of the core disruptive accident analysis code 'ASTERIA-FBR' in order to evaluate the mixed oxide (MOX) fuel performance under steady, transient and accident conditions of fast reactors consistently. On the basis of light water reactor (LWR) fuel performance evaluation code 'FEMAXI-6', FEMAXI-FBR develops specific models for the fast reactor fuel performance, such as restructuring, material migration during steady state and transient, melting cavity formation and pressure during accident, so that it can evaluate the fuel failure during accident. The analysis of test pin with slow transient over power test of CABRI-2 program was conducted from steady to transient. The test pin was pre-irradiated and tested under transient overpower with several % P 0 /s (P 0 : steady state power) of the power rate. Analysis results of the gas release ratio, pin failure time, and fuel melt radius were compared to measured values. The analysis results of the steady and transient performances were also compared with the measured values. The compared performances are gas release ratio, fuel restructuring for steady state and linear power and melt radius at failure during transient. This analysis result reproduces the measured value. It was concluded that FEMAXI-FBR is effective to evaluate fast reactor fuel performances from steady state to accident conditions. (author)

National Gas Hydrate Program Expedition 01 offshore India; gas hydrate systems as revealed by hydrocarbon gas geochemistry

Science.gov (United States)

Lorenson, Thomas; Collett, Timothy S.

2018-01-01

The National Gas Hydrate Program Expedition 01 (NGHP-01) targeted gas hydrate accumulations offshore of the Indian Peninsula and along the Andaman convergent margin. The primary objectives of coring were to understand the geologic and geochemical controls on the accumulation of methane hydrate and their linkages to underlying petroleum systems. Four areas were investigated: 1) the Kerala-Konkan Basin in the eastern Arabian Sea, 2) the Mahanadi and 3) Krishna-Godavari Basins in the western Bay of Bengal, and 4) the Andaman forearc Basin in the Andaman Sea.Upward flux of methane at three of the four of the sites cored during NGHP-01 is apparent from the presence of seafloor mounds, seismic evidence for upward gas migration, shallow sub-seafloor geochemical evidence of methane oxidation, and near-seafloor gas composition that resembles gas from depth.The Kerala-Konkan Basin well contained only CO2 with no detectable hydrocarbons suggesting there is no gas hydrate system here. Gas and gas hydrate from the Krishna-Godavari Basin is mainly microbial methane with δ13C values ranging from −58.9 to −78.9‰, with small contributions from microbial ethane (−52.1‰) and CO2. Gas from the Mahanadi Basin was mainly methane with lower concentrations of C2-C5 hydrocarbons (C1/C2 ratios typically >1000) and CO2. Carbon isotopic compositions that ranged from −70.7 to −86.6‰ for methane and −62.9 to −63.7‰ for ethane are consistent with a microbial gas source; however deeper cores contained higher molecular weight hydrocarbon gases suggesting a small contribution from a thermogenic gas source. Gas composition in the Andaman Basin was mainly methane with lower concentrations of ethane to isopentane and CO2, C1/C2 ratios were mainly >1000 although deeper samples were compositions range from −65.2 to −80.7‰ for methane, −53.1 to −55.2‰ for ethane is consistent with mainly microbial gas sources, although one value recorded of −35.4‰ for propane

Effect of N{sub 2} and Ar gas on DC arc plasma generation and film composition from Ti-Al compound cathodes

Energy Technology Data Exchange (ETDEWEB)

Zhirkov, Igor, E-mail: igozh@ifm.liu.se; Rosen, Johanna [Thin Film Physics Division, Department of Physics, Chemistry and Biology (IFM), Linköping University, SE-581 83 Linköping (Sweden); Oks, Efim [Institute of High Current Electronics SB RAS, 2/3 Akademichesky Avenue, 634055 Tomsk (Russian Federation)

2015-06-07

DC arc plasma from Ti, Al, and Ti{sub 1−x}Al{sub x} (x = 0.16, 0.25, 0.50, and 0.70) compound cathodes has been characterized with respect to plasma chemistry (charged particles) and charge-state-resolved ion energy for Ar and N{sub 2} pressures in the range 10{sup −6} to 3 × 10{sup −2} Torr. Scanning electron microscopy was used for exploring the correlation between the cathode and film composition, which in turn was correlated with the plasma properties. In an Ar atmosphere, the plasma ion composition showed a reduction of Al of approximately 5 at. % compared to the cathode composition, while deposited films were in accordance with the cathode stoichiometry. Introducing N{sub 2} above ∼5 × 10{sup −3} Torr, lead to a reduced Al content in the plasma as well as in the film, and hence a 1:1 correlation between the cathode and film composition cannot be expected in a reactive environment. This may be explained by an influence of the reactive gas on the arc mode and type of erosion of Ti and Al rich contaminations, as well as on the plasma transport. Throughout the investigated pressure range, a higher deposition rate was obtained from cathodes with higher Al content. The origin of generated gas ions was investigated through the velocity rule, stating that the most likely ion velocities of all cathode elements from a compound cathode are equal. The results suggest that the major part of the gas ions in Ar is generated from electron impact ionization, while gas ions in a N{sub 2} atmosphere primarily originate from a nitrogen contaminated layer on the cathode surface. The presented results provide a contribution to the understanding processes of plasma generation from compound cathodes. It also allows for a more reasonable approach to the selection of composite cathode and experimental conditions for thin film depositions.

Irradiated fuel behavior under accident heating conditions and correlation with fission gas release and swelling model (Chicago)

International Nuclear Information System (INIS)

Kryger, B.; Ducamp, F.; Combette, P.

1981-08-01

We analyse the mixed oxide fast fuel response to off normal conditions obtained by means of an out-of-pile transient simulation apparatus designed to provide direct observations (temperature, pressure, fuel motion) of fuel fission gas phenomena that might occur during the transients. The results are concerning fast transient tests (0,1 to 1 second) obtained with high gas concentration irradiated fuel (4 to 7 at % burn up, 0,4 cm 3 Xe + Kr /g.UPuO 2 ). The kinetics of fission gas release during the transients have been directly measured and then compared with the calculated results issued of the Chicago model. This model agrees, quite well, with other experiments done in the silene prompt reactor. Other gases than xenon and krypton (such as hydrogen and carbon monoxide) do not play any role in fuel behavior, since they have been completely ruled out

Overall simulation of a HTGR plant with the gas adapted MANTA code

International Nuclear Information System (INIS)

Emmanuel Jouet; Dominique Petit; Robert Martin

2005-01-01

Full text of publication follows: AREVA's subsidiary Framatome ANP is developing a Very High Temperature Reactor nuclear heat source that can be used for electricity generation as well as cogeneration including hydrogen production. The selected product has an indirect cycle architecture which is easily adapted to all possible uses of the nuclear heat source. The coupling to the applications is implemented through an Intermediate Heat exchanger. The system code chosen to calculate the steady-state and transient behaviour of the plant is based on the MANTA code. The flexible and modular MANTA code that is originally a system code for all non LOCA PWR plant transients, has been the subject of new developments to simulate all the forced convection transients of a nuclear plant with a gas cooled High Temperature Reactor including specific core thermal hydraulics and neutronics modelizations, gas and water steam turbomachinery and control structure. The gas adapted MANTA code version is now able to model a total HTGR plant with a direct Brayton cycle as well as indirect cycles. To validate these new developments, a modelization with the MANTA code of a real plant with direct Brayton cycle has been performed and steady-states and transients compared with recorded thermal hydraulic measures. Finally a comparison with the RELAP5 code has been done regarding transient calculations of the AREVA indirect cycle HTR project plant. Moreover to improve the user-friendliness in order to use MANTA as a systems conception, optimization design tool as well as a plant simulation tool, a Man- Machine-Interface is available. Acronyms: MANTA Modular Advanced Neutronic and Thermal hydraulic Analysis; HTGR High Temperature Gas-Cooled Reactor. (authors)

Natural gas in the transportation sector

Energy Technology Data Exchange (ETDEWEB)

Ask, T Oe; Einang, P M; Stenersen, D [MARINTEK (Norway)

1996-12-01

The transportation sector is responsible for more than 50% of all oil products consumed, and it is the fastest growing oil demand sector and the fastest growing source of emissions. During the last 10 years there have been a considerable and growing effort in developing internal combustion gas engines. This effort has resulted in gas engines with efficiencies comparable to the diesel engines and with emissions considerably lower than engines burning conventional fuels. This development offers us opportunities to use natural gas very efficiently also in the transportation sector, resulting in reduced emissions. However, to utilize all the built in abilities natural gas has as engine fuel, the natural gas composition must be kept within relatively narrow limits. This is the case with both diesel and gasoline today. A further development require therefore specified natural gas compositions, and the direct use of pipeline natural gas as today would only in limited areas be acceptable. An interesting possibility for producing a specified natural gas composition is by LNG (Liquid Natural Gas) production. (EG)

A model of gas cavity breakup behind a blockage in fast breeder reactor subassembly geometry

International Nuclear Information System (INIS)

Fukuzawa, Y.

1980-05-01

A semi-empirical model has been developed to describe the transient behaviour of a gas cavity due to breakup behind a blockage in Liquid Metal Fast Breeder Reactor subassembly geometry. The main mechanisms assumed for gas cavity breakup in the present model are as follows: The gas cavity is broken up by the pressure fluctuation at the interface due to turbulence in the liquid. The centrifugal force on the liquid opposes breakup. The model is able to describe experimental results on the transient behaviour of a gas cavity due to breakup after the termination of gas injection. On the basis of the present model the residence time of a gas cavity behind a blockage in sodium is predicted and the dependence of the residence time on blockage size is discussed. (orig.) [de

Natural Gas : Physical Properties and Combustion Features

OpenAIRE

Corre, Olivier Le; Loubar, Khaled

2010-01-01

The actual composition of natural gas depends primarily on the production field from which it is extracted and limited variations in composition must therefore be accepted. Moreover, at a local distribution level, seasonal adjustments by the local gas distributor may cause significant variations in the gas composition. Consequently, physical properties and energy content are subject to variations and their calculation / estimation is of great importance for technical and economical aspects. I...

CO gas sensing properties of In_4Sn_3O_1_2 and TeO_2 composite nanoparticle sensors

International Nuclear Information System (INIS)

Mirzaei, Ali; Park, Sunghoon; Sun, Gun-Joo; Kheel, Hyejoon; Lee, Chongmu

2016-01-01

Highlights: • In4Sn3O12–TeO2 composite nanoparticles were synthesized via a facile hydrothermal route. • The response of the In4Sn3O12–TeO2 composite sensor to CO was stronger than the pristine In4Sn3O12 sensor. • The response of the In4Sn3O12–TeO2 composite sensor to CO was faster than the pristine In4Sn3O12 sensor. • The improved sensing performance of the In4Sn3O12–TeO2 nanocomposite sensor is discussed in detail. • The In4Sn3O12-based nanoparticle sensors showed selectivity to CO over NH3, HCHO and H2. - Abstract: A simple hydrothermal route was used to synthesize In_4Sn_3O_1_2 nanoparticles and In_4Sn_3O_1_2–TeO_2 composite nanoparticles, with In(C_2H_3O_2)_3, SnCl_4, and TeCl_4 as the starting materials. The structure and morphology of the synthesized nanoparticles were examined by X-ray diffraction and scanning electron microscopy (SEM), respectively. The gas-sensing properties of the pure and composite nanoparticles toward CO gas were examined at different concentrations (5–100 ppm) of CO gas at different temperatures (100–300 °C). SEM observation revealed that the composite nanoparticles had a uniform shape and size. The sensor based on the In_4Sn_3O_1_2–TeO_2 composite nanoparticles showed stronger response to CO than its pure In_4Sn_3O_1_2 counterpart. The response of the In_4Sn_3O_1_2–TeO_2 composite-nanoparticle sensor to 100 ppm of CO at 200 °C was 10.21, whereas the maximum response of the In_4Sn_3O_1_2 nanoparticle sensor was 2.78 under the same conditions. Furthermore, the response time of the composite sensor was 19.73 s under these conditions, which is less than one-third of that of the In_4Sn_3O_1_2 sensor. The improved sensing performance of the In_4Sn_3O_1_2–TeO_2 nanocomposite sensor is attributed to the enhanced modulation of the potential barrier height at the In_4Sn_3O_1_2–TeO_2 interface, the stronger oxygen adsorption of p-type TeO_2, and the formation of preferential adsorption sites.

National Gas Hydrate Program Expedition 01 offshore India; gas hydrate systems as revealed by hydrocarbon gas geochemistry

Science.gov (United States)

Lorenson, Thomas; Collett, Timothy S.

2018-01-01

The National Gas Hydrate Program Expedition 01 (NGHP-01) targeted gas hydrate accumulations offshore of the Indian Peninsula and along the Andaman convergent margin. The primary objectives of coring were to understand the geologic and geochemical controls on the accumulation of methane hydrate and their linkages to underlying petroleum systems. Four areas were investigated: 1) the Kerala-Konkan Basin in the eastern Arabian Sea, 2) the Mahanadi and 3) Krishna-Godavari Basins in the western Bay of Bengal, and 4) the Andaman forearc Basin in the Andaman Sea.Upward flux of methane at three of the four of the sites cored during NGHP-01 is apparent from the presence of seafloor mounds, seismic evidence for upward gas migration, shallow sub-seafloor geochemical evidence of methane oxidation, and near-seafloor gas composition that resembles gas from depth.The Kerala-Konkan Basin well contained only CO2 with no detectable hydrocarbons suggesting there is no gas hydrate system here. Gas and gas hydrate from the Krishna-Godavari Basin is mainly microbial methane with δ13C values ranging from −58.9 to −78.9‰, with small contributions from microbial ethane (−52.1‰) and CO2. Gas from the Mahanadi Basin was mainly methane with lower concentrations of C2-C5 hydrocarbons (C1/C2 ratios typically >1000) and CO2. Carbon isotopic compositions that ranged from −70.7 to −86.6‰ for methane and −62.9 to −63.7‰ for ethane are consistent with a microbial gas source; however deeper cores contained higher molecular weight hydrocarbon gases suggesting a small contribution from a thermogenic gas source. Gas composition in the Andaman Basin was mainly methane with lower concentrations of ethane to isopentane and CO2, C1/C2 ratios were mainly >1000 although deeper samples were exploration and occurs in a forearc basin. Each of these hydrate-bearing systems overlies and is likely supported by the presence and possible migration of gas from deeper gas-prone petroleum

Novel manufacturing process of nanoparticle/Al composite filler metals of tungsten inert gas welding by accumulative roll bonding

Energy Technology Data Exchange (ETDEWEB)

Fattahi, M., E-mail: fattahi.put@gmail.com [Technical Inspection Engineering Department, Petroleum University of Technology, Abadan (Iran, Islamic Republic of); Noei Aghaei, V. [Aerospace Engineering Department, Sharif University of Technology, Tehran (Iran, Islamic Republic of); Dabiri, A.R. [Technical Inspection Engineering Department, Petroleum University of Technology, Abadan (Iran, Islamic Republic of); Amirkhanlou, S. [Young Researchers and Elite Club, Najafabad Branch, Islamic Azad University, Najafabad (Iran, Islamic Republic of); Akhavan, S.; Fattahi, Y. [Materials Engineering Department, Isfahan University of Technology, Isfahan (Iran, Islamic Republic of)

2015-11-11

In the present work, accumulative roll bonding (ARB) was used as an effective method for manufacturing nanoparticle/Al composite filler metals of tungsten inert gas (TIG) welding. After welding, the distribution of ceramic nanoparticles and mechanical properties of welds were investigated. By applying ARB, ceramic nanoparticles were uniformly dispersed in the composite filler metals. Consequently, the welds produced by these filler metals had a uniform dispersion of ceramic nanoparticles in their compositions. The test results showed that the yield strength of welds was greatly increased when using the nanoparticle/Al composite filler metals. The improvement in the yield strength was attributed to the coefficient of thermal expansion mismatch and Orowan strengthening mechanisms. Therefore, according to the results presented in this paper, it can be concluded that the nanoparticle/Al composite filler metals can serve as a novel filler metal for TIG welding of aluminum and its alloys.

Natural gas

Energy Technology Data Exchange (ETDEWEB)

Fraser, J W

1967-08-01

This report on the natural gas industry of Canada includes: composition and uses of natural gas, production statistics, exploration and development, reserve estimates, natural gas processing, transportation, and marketing. For the Canadian natural gas industry, 1966 was a year of moderate expansion in all phases, with a strong demand continuing for sulfur and liquid hydrocarbons produced as by-products of gas processing. Value of natural gas production increased to $199 million and ranked sixth in terms of value of mineral ouput in Canada. Currently, natural gas provides over 70% of Canada's energy requirements. Proved remaining marketable reserves are estimated to be in excess of a 29-yr supply.

A 2D Daubechies finite wavelet domain method for transient wave response analysis in shear deformable laminated composite plates

Science.gov (United States)

Nastos, C. V.; Theodosiou, T. C.; Rekatsinas, C. S.; Saravanos, D. A.

2018-03-01

An efficient numerical method is developed for the simulation of dynamic response and the prediction of the wave propagation in composite plate structures. The method is termed finite wavelet domain method and takes advantage of the outstanding properties of compactly supported 2D Daubechies wavelet scaling functions for the spatial interpolation of displacements in a finite domain of a plate structure. The development of the 2D wavelet element, based on the first order shear deformation laminated plate theory is described and equivalent stiffness, mass matrices and force vectors are calculated and synthesized in the wavelet domain. The transient response is predicted using the explicit central difference time integration scheme. Numerical results for the simulation of wave propagation in isotropic, quasi-isotropic and cross-ply laminated plates are presented and demonstrate the high spatial convergence and problem size reduction obtained by the present method.

Using fumarolic inert gas composition to investigate magma dynamics at Campi Flegrei (Italy)

Science.gov (United States)

Chiodini, G.; Caliro, S.; Paonita, A.; Cardellini, C.

2013-12-01

Since 2000 the Campi Flegrei caldera sited in Neapolitan area (Italy), has showed signs of reactivation, marked by ground uplift, seismic activity, compositional variations of fumarolic effluents from La Solfatara, an increase of the fumarolic activity as well as of soil CO2 fluxes. Comparing long time series of geochemical signals with ground deformation and seismicity, we show that these changes are at least partially caused by repeated injections of magmatic fluid into the hydrothermal system. The frequency of these degassing episodes has increased in the last years, causing pulsed uplift episodes and swarms of low magnitude earthquakes. We focus here in the inert gas species (CO2-He-Ar-N2) of Solfatara fumaroles which displayed in the time spectacular and persistent variation trends affecting all the monitored vents. The observed variations, which include a continuous decrease of both N2/He and N2/CO2 ratios since 1985, paralleled by an increase of He/CO2, can not be explained neither with changes in processes of boiling-condensation in the local hydrothermal system nor with changes in the mixing proportions between a magmatic vapour and hydrothermal fluids. Consequently we investigated the possibility that the trends of inert gas species are governed by changes in the conditions controlling magma degassing at depth. We applied a magma degassing model, with the most recent updates for inert gas solubilities, after to have included petrologic constraints from the ranges of melt composition and reservoir pressure at Campi Flegrei. The model simulations for mafic melts (trachybasalt and shoshonite) show a surprising agreement with the measured data. Both decompressive degassing of an ascending magma and mixing between magmatic fluids exsolved at various levels along the ascent path can explain the long-time geochemical changes. Our work highlights that, in caldera systems where the presence of hydrothermal aquifers commonly masks the magmatic signature of reactive

Transient Go: A Mobile App for Transient Astronomy Outreach

Science.gov (United States)

Crichton, D.; Mahabal, A.; Djorgovski, S. G.; Drake, A.; Early, J.; Ivezic, Z.; Jacoby, S.; Kanbur, S.

2016-12-01

Augmented Reality (AR) is set to revolutionize human interaction with the real world as demonstrated by the phenomenal success of `Pokemon Go'. That very technology can be used to rekindle the interest in science at the school level. We are in the process of developing a prototype app based on sky maps that will use AR to introduce different classes of astronomical transients to students as they are discovered i.e. in real-time. This will involve transient streams from surveys such as the Catalina Real-time Transient Survey (CRTS) today and the Large Synoptic Survey Telescope (LSST) in the near future. The transient streams will be combined with archival and latest image cut-outs and other auxiliary data as well as historical and statistical perspectives on each of the transient types being served. Such an app could easily be adapted to work with various NASA missions and NSF projects to enrich the student experience.

Composition, preparation, and gas generation results from simulated wastes of Tank 241-SY-101

International Nuclear Information System (INIS)

Bryan, S.A.; Pederson, L.R.

1994-08-01

This document reviews the preparation and composition of simulants that have been developed to mimic the wastes temporarily stored in Tank 241-SY-101 at Hanford. The kinetics and stoichiometry of gases that are generated using these simulants are also compared, considering the roles of hydroxide, chloride, and transition metal ions; the identities of organic constituents; and the effects of dilution, radiation, and temperature. Work described in this report was conducted for the Flammable Gas Safety Program at Pacific Northwest Laboratory, (a) whose purpose is to develop information that is necessary to mitigate potential safety hazards associated with waste tanks at the Hanford Site. The goal of this research and of related efforts at the Georgia Institute of Technology (GIT), Argonne National Laboratory (ANL), and Westinghouse Hanford Company (WHC) is to determine the thermal and thermal/radiolytic mechanisms by which flammable and other gases are produced in Hanford wastes, emphasizing those stored in Tank 241-SY-101. A variety of Tank 241-SY-101 simulants have been developed to date. The use of simulants in laboratory testing activities provides a number of advantages, including elimination of radiological risks to researchers, lower costs associated with experimentation, and the ability to systematically alter simulant compositions to study the chemical mechanisms of reactions responsible for gas generation. The earliest simulants contained the principal inorganic components of the actual waste and generally a single complexant such as N-(2-hydroxyethyl) ethylenediaminetriacetic acid (HEDTA) or ethylenediaminetriacetic acid (EDTA). Both homogeneous and heterogeneous compositional forms were developed. Aggressive core sampling and analysis activities conducted during Windows C and E provided information that was used to design new simulants that more accurately reflected major and minor inorganic components

Present status of numerical analysis on transient two-phase flow

International Nuclear Information System (INIS)

Akimoto, Masayuki; Hirano, Masashi; Nariai, Hideki.

1987-01-01

The Special Committee for Numerical Analysis of Thermal Flow has recently been established under the Japan Atomic Energy Association. Here, some methods currently used for numerical analysis of transient two-phase flow are described citing some information given in the first report of the above-mentioned committee. Many analytical models for transient two-phase flow have been proposed, each of which is designed to describe a flow by using differential equations associated with conservation of mass, momentum and energy in a continuous two-phase flow system together with constructive equations that represent transportation of mass, momentum and energy though a gas-liquid interface or between a liquid flow and the channel wall. The author has developed an analysis code, called MINCS, that serves for systematic examination of conservation equation and constructive equations for two-phase flow models. A one-dimensional, non-equilibrium two-liquid flow model that is used as the basic model for the code is described. Actual procedures for numerical analysis is shown and some problems concerning transient two-phase analysis are described. (Nogami, K.)

Plasma cleaning of beamline optical components: Contamination and gas composition effects

International Nuclear Information System (INIS)

Rosenberg, R.A.; Smith, J.A.; Wallace, D.J.

1992-01-01

We have initiated a program to study the impact of gas composition on the carbon removal rate during plasma cleaning of optical components, and of possible contamination due to the plasma processing. The measurements were performed in a test chamber designed to simulate the geometry of the grating/Codling mirror section of a Grasshopper monochromator. Removal rates were determined for a direct-current (dc) (Al electrode) discharge using a quartz crystal microbalance coated with polymethylmethacrylate, located at the position of the grating. Auger electron spectroscopy analysis of strateg- ically located, gold-coated stainless steel samples was employed to determine contamination. The relative removal rates of the gases studied were 3% C 2 F 6 /O 2 much-gt O 2 +H 2 O>O 2 ∼N 2 O>H 2 >N 2 . Although the C 2 F 6 /O 2 gas mixture showed a 20 times greater removal rate than its nearest competitor, it also caused significant contamination to occur. Contamination studies were performed for both dc and radio-frequency (rf) discharges. For the dc discharge we found that great care must be taken in order to avoid Al contamination; for the rf discharge, significant Fe contamination was observed

Transient Mass and Thermal Transport during Methane Adsorption into the Metal-Organic Framework HKUST-1.

Science.gov (United States)

Babaei, Hasan; McGaughey, Alan J H; Wilmer, Christopher E

2018-01-24

Methane adsorption into the metal-organic framework (MOF) HKUST-1 and the resulting heat generation and dissipation are investigated using molecular dynamics simulations. Transient simulations reveal that thermal transport in the MOF occurs two orders of magnitude faster than gas diffusion. A large thermal resistance at the MOF-gas interface (equivalent to 127 nm of bulk HKUST-1), however, prevents fast release of the generated heat. The mass transport resistance at the MOF-gas interface is equivalent to 1 nm of bulk HKUST-1 and does not present a bottleneck in the adsorption process. These results provide important insights into the application of MOFs for gas storage applications.

210Pb content in natural gas pipeline residues ('black-powder') and its correlation with the chemical composition

International Nuclear Information System (INIS)

Godoy, Jose Marcus; Carvalho, Franciane; Cordilha, Aloisio; Matta, Luiz Ernesto; Godoy, Maria Luiza

2005-01-01

The present work was carried out to assess the 210 Pb content in 'black-powder' found in pigging operations on gas pipelines in Brazil, in particular, on the Campos Basin gas pipeline. Additionally, the chemical composition of such deposits was determined and an eventual correlation with 210 Pb concentration evaluated. Typical 'black-powder' generated in the natural gas pipeline from Campos Basin oilfield contains mainly iron oxide (∼81%) and residual organic matter (∼9%). The 210 Pb content ranges from 4.9 to 0.04 kBq kg -1 and seems to be inversely correlated with the distance to the platforms. On the other hand, 226 Ra concentration is higher on the pipeline branch between the platform and the onshore installations. 228 Ra was only observed in few samples, in particular, in the samples with the highest 226 Ra content

Review of Transient Fuel Test Results at Sandia National Laboratories and the Potential for Future Fast Reactor Fuel Transient Testing in the Annular Core Research Reactor

Energy Technology Data Exchange (ETDEWEB)

Wright, Steven A.; Pickard, Paul S.; Parma, Edward J.; Vernon, Milton E.; Kelly, John; Tikare, Veena [Sandia National Laboratories, Org 6872 MS-1146, PO Box 5800 Albuquerque, New Mexico 87185 (United States)

2009-06-15

Reactor driven transient tests of fast reactor fuels may be required to support the development and certification of new fuels for Fast Reactors. The results of the transient fuel tests will likely be needed to support licensing and to provide validation data to support the safety case for a variety of proposed fast fuel types and reactors. In general reactor driven transient tests are used to identify basic phenomenology during reactor transients and to determine the fuel performance limits and margins to failure during design basis accidents such as loss of flow, loss of heat sink, and reactivity insertion accidents. This paper provides a summary description of the previous Sandia Fuel Disruption and Transient Axial Relocation tests that were performed in the Annular Core Research Reactor (ACRR) for the U.S. Nuclear Regulatory Commission almost 25 years ago. These tests consisted of a number of capsule tests and flowing gas tests that used fission heating to disrupt fresh and irradiated MOX fuel. The behavior of the fuel disruption, the generation of aerosols and the melting and relocation of fuel and cladding was recorded on high speed cinematography. This paper will present videos of the fuel disruption that was observed in these tests which reveal stark differences in fuel behavior between fresh and irradiated fuel. Even though these tests were performed over 25 years ago, their results are still relevant to today's reactor designs. These types of transient tests are again being considered by the Advanced Fuel Cycle Initiative to support the Global Nuclear Energy Partnership because of the need to perform tests on metal fuels and transuranic fuels. Because the Annular Core Research Reactor is the only transient test facility available within the US, a brief summary of Sandia's continued capability to perform these tests in the ACRR will also be provided. (authors)

Utilizing the response patterns of a temperature modulated chemoresistive gas sensor for gas diagnosis

International Nuclear Information System (INIS)

Amini, Amir; Ghafarinia, Vahid

2011-01-01

The observed features in the temporal response patterns of a temperature-modulated chemoresistive gas sensor were used for gas diagnosis. The patterns were recorded for clean air and air contaminated with different levels of some volatile organic compounds while a staircase heating voltage waveform had been applied to the microheater of a tin oxide gas sensor that modulated its operating temperature. Combining the steady-state and transient parameters of the recorded responses in the 50-400 deg. C range resulted in discriminatory feature vectors which were utilized for contaminant classification. The information content of these feature vectors was proved sufficient for discrimination of methanol, ethanol, 1-butanol, and acetone contaminations in a wide concentration range.

Utilizing the response patterns of a temperature modulated chemoresistive gas sensor for gas diagnosis

Energy Technology Data Exchange (ETDEWEB)

Amini, Amir [Jannatabad College, Sama Organization, Islamic Azad University, Tehran (Iran, Islamic Republic of); Ghafarinia, Vahid, E-mail: amir.amini.elec@gmail.com, E-mail: ghafarinia@ee.kntu.ac.ir [Electrical Engineering Department, K. N. Toosi University of Technology, Tehran (Iran, Islamic Republic of)

2011-02-15

The observed features in the temporal response patterns of a temperature-modulated chemoresistive gas sensor were used for gas diagnosis. The patterns were recorded for clean air and air contaminated with different levels of some volatile organic compounds while a staircase heating voltage waveform had been applied to the microheater of a tin oxide gas sensor that modulated its operating temperature. Combining the steady-state and transient parameters of the recorded responses in the 50-400 deg. C range resulted in discriminatory feature vectors which were utilized for contaminant classification. The information content of these feature vectors was proved sufficient for discrimination of methanol, ethanol, 1-butanol, and acetone contaminations in a wide concentration range.

Gas composition generated by Eucalyptus firewood gasification in different dimensions; Composicao dos gases gerados pela gasificacao de lenha de Eucalipto em diferentes dimensoes

Energy Technology Data Exchange (ETDEWEB)

Zanatta, Fabio L.; Silva, Jadir Nogueira da; Galvarro, Svetlana S.F.; Laureano, Juliane [Universidade Federal de Vicosa (UFV), MG (Brazil). Dept. de Engenharia Agricola], email: fabio.zanatta@ufv.br; Martin, Samuel [Universidade de Brasilia (UNB), DF (Brazil). Dept. de Engenharia Rural

2011-07-01

Gasification is a technology that yields an energetic gas from the partial oxidation of organic wastes at high temperatures, by an air factor of 20 to 40% of the stoichiometric amount. The gas generated by gasifier can be used to generate electricity or heat as needed. The gas quality is very dependent of the combustible gases present such as CO, CH{sub 4} and H{sub 2}. On this basis, we investigated the composition of gases generated by an updraft gasifier operating with eucalyptus firewood in four different dimensions to determinate the heating value of gas and evaluate which dimension provides the best results. The experiment was conducted at the Post-Harvest and Renewable Energy Experimental Area of the Agricultural Engineering Department at UFV. It had been used logs of eucalyptus firewood in standard diameter and length of 15, 50 and 100 cm. In addition, chips made of eucalyptus firewood were used with approximate dimensions of 2,5x2,0x0,3 cm. According to conditions under which the experiment was set, the results indicated that chips of eucalyptus firewood have provided more homogeneous conditions in gas composition, thus facilitating use. (author)

CANDU fuel behaviour under transient conditions

International Nuclear Information System (INIS)

Segel, A.W.L.

1979-04-01

The Canadian R and D program to understand CANDU fuel behaviour under transient conditions is described. Fuel sheath behaviour studies have led to the development of a model of transient plastic strain in inert gas, which integrates the deformation due to several mechanisms. Verification tests demonstrated that on average the model overpredicts strain by 20%. From oxidation kinetics studies a sheath failure embrittlement criterion based on oxygen distribution has been developed. We have also established a rate equation for high-temperature stress-dependent crack formation due to embrittlement of the sheath by beryllium. An electric, simulated fuel element is being used in laboratory tests to characterize the behaviour of fuel in the horizontal. In-reactor, post-dryout tests have been done for several years. There is an axially-segmented, axisymmetric fuel element model in place and a fully two-dimensional code is under development. Laboratory testing of bundles, in its early stages, deals with the effects of geometric distortion and sheath-to-sheath interaction. In-reactor, post-dryout tests of CANDU fuel bundles with extensive central UO 2 melting did not result in fuel fragmentation nor damage to the pressure tube. (author)

A methodology to model flow-thermals inside a domestic gas oven

International Nuclear Information System (INIS)

Mistry, Hiteshkumar; Ganapathisubbu, S.; Dey, Subhrajit; Bishnoi, Peeush; Castillo, Jose Luis

2011-01-01

In this paper, the authors describe development of a CFD based methodology to evaluate performance of a domestic gas oven. This involves modeling three-dimensional, unsteady, forced convective flow field coupled with radiative participating media. Various strategies for capturing transient heat transfer coupled with mixed convection flow field are evaluated considering the trade-off between computational time and accuracy of predictions. A new technique of modeling gas oven that does not require detailed modeling of flow-thermals through the burner is highlighted. Experiments carried out to support this modeling development shows that heat transfer from burners can be represented as non-dimensional false bottom temperature profiles. Transient validation of this model with experiments show less than 6% discrepancy in thermal field during preheating of bake cycle of gas oven.

A nanostructured composite based on polyaniline and gold nanoparticles: synthesis and gas sensing properties

International Nuclear Information System (INIS)

Venditti, Iole; Fratoddi, Ilaria; Russo, Maria Vittoria; Bearzotti, Andrea

2013-01-01

Nanostructured composite materials based on polyaniline (PANI) and gold nanoparticles have been prepared by means of an osmosis based method. Several morphologies have been obtained for the pristine nanoPANI and for nanoPANI–Au composite, ranging from amorphous to sponge-like and spherical shapes. On the basis of this morphological investigation, different materials with high surface area have been selected and tested as chemical interactive materials for room temperature gas and vapor sensing. The resistive sensor devices have been exposed to different vapor organic compounds (VOCs) of interest in the fields of environmental monitoring and biomedical applications, such as toluene, acetic acid, ethanol, methanol, acetonitrile, water, ammonia and nitrogen dioxide. The effect of doping with H 2 SO 4 has been studied for both nanoPANI and nanoPANI–Au samples. In particular, nanoPANI–Au showed sensitivity to ammonia (up to 10 ppm) higher than that to other VOCs or interfering analytes. The facile preparation method and the improved properties achieved for the polyaniline–gold composite materials are significant in the nanomaterials field and have promise for applications in ammonia vapor monitoring. (paper)

Some interesting developments relating to gas dynamics in the application of the UCOR process for isotope separation

International Nuclear Information System (INIS)

Alant, T.G.; Schumann, W.A.

1980-01-01

The separating element employed in the UCOR process for uranium enrichment has a very small cut, i.e. is highly asymmetrical with respect to the UF 6 flow in the enriched and depleted streams. For the commercial exploitation of the process, the so-called helikon technique of cascading was developed. The process is dependent on the transmission of parallel streams of diffferent isotopic composition through an axial compressor without significant mixing between them. A light gas (H 2 ), which is present in large molar excess, increases the flow velocity of the process gas (UF 6 ) and hence adds to improved separation performance. The separating element not only separates isotopes but also causes appreciable separation between the process gas and the light carrier gas. The paper consists of a brief description of the helikon cascading technique followed by a comprehensive assessment of the various aspects of gas mixing in an axial compressor. Phenomena of mole mass and pressure transients which occur in the module during run-up of the compressors are also discussed. The operating characteristics of axial compressors and of the separating element produce a driving force which tends to cause mole mass and associated pressure gradients to occur circumferentially in a helikon module under static conditions. The paper includes 5 references and 10 figures

On the behaviour of dissolved fission gases prior to transient testing of fuel pins

International Nuclear Information System (INIS)

Wood, M.H.; Matthews, J.R.

1978-10-01

The TREAT and CABRI series of reactor safety experiments on irradiated fuel require the transfer of fuel pins from the reactor in which the fuel has achieved some burn-up to the test facility. Subsequently, the fuel is restored to power in the test facility for some time before transient heating is initiated. Such pre-test manoeuvres, where the fuel is subjected to changes in the fission rate and temperature, may have important consequences for the fission gas behaviour during the transient experiment. The results of rate theory calculations are used to assess these effects. (author)

Local Fission Gas Release and Swelling in Water Reactor Fuel during Slow Power Transients

DEFF Research Database (Denmark)

Mogensen, Mogens Bjerg; Walker, C.T.; Ray, I.L.F.

1985-01-01

Gas release and fuel swelling caused by a power increase in a water reactor fuel (burn-up 2.7–4.5% FIMA) is described. At a bump terminal level of about 400 W/cm (local value) gas release was 25–40%. The formation of gas bubbles on grain boundaries and their degree of interlinkage are the two...... factors that determine the level of fission gas release during a power bump. Release begins when gas bubbles on grain boundaries start o interlink. This occurred at r/r0 ~ 0.75. Release tunnels were fully developed at r/r0 ~ 0.55 with the result that gas release was 60–70% at this position....

Statistical dynamics of transient processes in a gas discharge plasma

International Nuclear Information System (INIS)

Smirnov, G.I.; Telegin, G.G.

1991-01-01

The properties of a gas discharge plasma to a great extent depend on random processes whose study has recently become particularly important. The present work is concerned with analyzing the statistical phenomena that occur during the prebreakdown stage in a gas discharge. Unlike other studies of breakdown in the discharge gap, in which secondary electron effects and photon processes at the electrodes must be considered, here the authors treat the case of an electrodeless rf discharge or a laser photoresonant plasma. The analysis is based on the balance between the rates of electron generation and recombination in the plasma. The fluctuation kinetics for ionization of atoms in the hot plasma may also play an important role when the electron temperature changes abruptly, as occurs during adiabatic pinching of the plasma or during electron cyclotron heating

Comparison of information content of temporal response of chemoresistive gas sensor under three different temperature modulation regimes for gas detection of different feature reduction methods

Science.gov (United States)

Hosseini-Golgoo, S. M.; Salimi, F.; Saberkari, A.; Rahbarpour, S.

2017-12-01

In the present work the feature extraction of transient response of a resistive gas sensor under temperature cycling, temperature transient, and temperature combination methods were compared. So, the heater were stimulated by three pulse (cycling), ramp (transient) and staircase (combination) waveforms. The period or duration of all waves was equal to 40 s. Methanol, ethanol, 1-propanol, 1-butanol, toluene and acetone each at 11 different concentration levels in the range of 100 to 2000 ppm were used as the target gases. The utilized sensor was TGS-813 that made by Figaro Company. Recorded results were studied and heuristic features such as peak, rise time, slope and curvature of recorded responses were extracted for each heater waveform. Results showed that although application of this feature extraction method to all waveforms led to gas diagnoses, best results were achieved in the case of staircase waveform. The combination waveform had enough information to separate all examined target gases.

Stabilization of the composition of the gas medium of a repetitively pulsed CO2 laser by means of hopcalite

Science.gov (United States)

Baranov, V. Iu.; Drokov, G. F.; Kuzmenko, V. A.; Mezhevov, V. S.; Pigulskaia, V. V.

1986-05-01

Results of experiments in which hopcalite was used to stabilize the composition of the gas medium of repetitively pulsed and monopulse CO2 lasers are reported. In particular, the mechanisms of the decrease in the catalyst activity with time under conditions for catalyst regeneration are determined. It is shown that the use of hopcalite has made it possible to achieve long-term operation of a high-power repetitively pulsed CO2 laser without changing the gas mixture in a closed circuit. Some details related to the use of hopcalite are discussed.

Current interruption transients calculation

CERN Document Server

Peelo, David F

2014-01-01

Provides an original, detailed and practical description of current interruption transients, origins, and the circuits involved, and how they can be calculated Current Interruption Transients Calculationis a comprehensive resource for the understanding, calculation and analysis of the transient recovery voltages (TRVs) and related re-ignition or re-striking transients associated with fault current interruption and the switching of inductive and capacitive load currents in circuits. This book provides an original, detailed and practical description of current interruption transients, origins,

Barometric pressure transient testing applications at the Nevada Test Site: formation permeability analysis. Final report

International Nuclear Information System (INIS)

Hanson, J.M.

1984-12-01

The report evaluates previous investigations of the gas permeability of the rock surrounding emplacement holes at the Nevada Test Site. The discussion sets the framework from which the present uncertainty in gas permeability can be overcome. The usefulness of the barometric pressure testing method has been established. Flow models were used to evaluate barometric pressure transients taken at NTS holes U2fe, U19ac and U20ai. 31 refs., 103 figs., 18 tabs

Radiation Fog in the US Mid-Atlantic Region: Chemical Composition, Trends, and Gas-Liquid Partitioning

Science.gov (United States)

Straub, D.

2016-12-01

The chemical composition of radiation fog has been studied at a rural site in central Pennsylvania over an eight year period extending through 2015. Bulk fog samples were collected with an automated Caltech Heated Rod Cloud Collector (CHRCC) and analyzed for pH, inorganic ions, organic acids, total organic carbon (TOC), and total nitrogen (TN). Over the duration of the project, 146 samples were collected and used to document chemical composition, evaluate changes over time, and to investigate partitioning between the gas and aqueous phases. Ammonium, sulfate, calcium, and nitrate were the most abundant inorganic ions while acetate and formate were the dominant organic acids. Organic acids contributed about 15% to TOC. Inorganic nitrogen accounted for the majority of TN, with only 18% of TN attributed to organic nitrogen. Overall, organic matter contributed 52% to the total mass loading of the fog samples, a value that is higher than reported for other radiation fog studies. Statistically significant decreasing trends were observed for sulfate, ammonium, chloride, nitrate, and pH. These trends coincide with reductions in emissions from fossil fuel combustion that have been documented over this time period. Seasonal trends were also detected for nitrate, ammonium, potassium, phosphate, acetate and formate which appear to be related to the agricultural growing season. Based on simultaneous measurements of gas phase ammonia and ammonium in the fog samples, significant deviations from equilibrium were found. In low pH samples, ammonium concentrations were much lower than equilibrium predicts, while the opposite occurred in high pH samples. Modeling suggested that mass transfer limitations contributed to the departure from equilibrium. Similarly, predictions of bicarbonate concentrations based on equilibrium with gas phase carbon dioxide appears to underestimate the actual amount of bicarbonate present in samples collected during this study.

Development of transient internal probe (TIP) magnetic field diagnostic

International Nuclear Information System (INIS)

Galambos, J.P.; Bohnet, M.A.; Jarboe, T.R.; Mattick, A.T.

1994-01-01

The Transient Internal Probe (TIP) is designed to permit measurement of internal magnetic fields, in hot, high density plasmas. The concept consists of accelerating a probe to high velocities (2.2 Km/s) in order to minimize probe exposure time to plasma. Faraday rotation within the probe is used to measure the local magnetic field. An Argon laser illuminates the probe consisting of a Faraday-rotator material with a retro-reflector that returns the incident light to the detection system. Performance results of the light gas gun and optical detection system will be shown. To date, the gas gun has been extensively tested consistently achieving velocities between 2 and 3 km/s. The probe and detection scheme have been tested by dropping the probe through a static magnetic field. Magnetic field resolution of 20 gauss and spatial resolution of 5 mm has been achieved. System frequency response is 10Mhz. Work is currently being conducted to integrate the diagnostic system with laboratory plasma experiments. Specifically a gas interfaced system has been developed to prevent helium muzzle gas from entering the plasma chamber with the probe. Additionally the probe must be separated from the sabot which protects the probe during acceleration in the gas gun. Data will be presented showing the results of various separation techniques

Investigation on Nano composite Membrane of Multi walled Carbon Nano tube Reinforced Polycarbonate Blend for Gas Separation

International Nuclear Information System (INIS)

Kausar, A.

2016-01-01

Carbon nano tube has been explored as a nano filler in high performance polymeric membrane for gas separation. In this regard, nano composite membrane of polycarbonate (PC), poly(vinylidene fluoride-co-hexafluoropropylene) (PVFHFP), and multi walled carbon nano tube (MWCNT) was fabricated via phase inversion technique. Poly (ethylene glycol) (PEG) was employed for the compatibilization of the blend system. Two series of PC/PVFHFP/PEG were developed using purified P-MWCNT and acid functional A-MWCNT nano filler. Scanning and transmission electron micrographs have shown fine nano tube dispersion and wetting by matrix, compared with the purified system. Tensile strength and Young s modulus of PC/PVFHFP/PEG/MWCNT-A 1-5 were found to be in the range of 63.6-72.5 MPa and 110.6-122.1 MPa, respectively. The nano composite revealed 51% increase in Young s modulus and 28% increase in tensile stress relative to the pristine blend. The A-MWCNT was also effective in enhancing the perm selectivity αCO 2 /N 2 (31.2-39.9) of nano composite membrane relative to the blend membrane (21.6). The permeability ρCO 2 of blend was 125.6 barrer; however, the functional series had enhancedρCO 2 values ranging from 142.8 to 186.6 barrer. Moreover, A-MWCNT loading improved the gas diffusivity of PC/PVFHFP/PEG/MWCNT-A 1-5; however, filler content did not significantly influence the CO 2 and N 2 solubility.

Volatile organic compound emissions from the oil and natural gas industry in the Uinta Basin, Utah: point sources compared to ambient air composition

Science.gov (United States)

Warneke, C.; Geiger, F.; Edwards, P. M.; Dube, W.; Pétron, G.; Kofler, J.; Zahn, A.; Brown, S. S.; Graus, M.; Gilman, J.; Lerner, B.; Peischl, J.; Ryerson, T. B.; de Gouw, J. A.; Roberts, J. M.

2014-05-01

The emissions of volatile organic compounds (VOCs) associated with oil and natural gas production in the Uinta Basin, Utah were measured at a ground site in Horse Pool and from a NOAA mobile laboratory with PTR-MS instruments. The VOC compositions in the vicinity of individual gas and oil wells and other point sources such as evaporation ponds, compressor stations and injection wells are compared to the measurements at Horse Pool. High mixing ratios of aromatics, alkanes, cycloalkanes and methanol were observed for extended periods of time and short-term spikes caused by local point sources. The mixing ratios during the time the mobile laboratory spent on the well pads were averaged. High mixing ratios were found close to all point sources, but gas wells using dry-gas collection, which means dehydration happens at the well, were clearly associated with higher mixing ratios than other wells. Another large source was the flowback pond near a recently hydraulically re-fractured gas well. The comparison of the VOC composition of the emissions from the oil and natural gas wells showed that wet gas collection wells compared well with the majority of the data at Horse Pool and that oil wells compared well with the rest of the ground site data. Oil wells on average emit heavier compounds than gas wells. The mobile laboratory measurements confirm the results from an emissions inventory: the main VOC source categories from individual point sources are dehydrators, oil and condensate tank flashing and pneumatic devices and pumps. Raw natural gas is emitted from the pneumatic devices and pumps and heavier VOC mixes from the tank flashings.

Plasma sprayed thermal barrier coatings for industrial gas turbines: morphology, processing and properties

International Nuclear Information System (INIS)

Gruenling, H.W.; Mannsmann, W.

1993-01-01

Thermal barrier coatings out of fully or partially stabilized zirconia offer a unique chance in gas turbines to increase the gas inlet temperature significantly while keeping the temperature of the structural material of the component within conventional limits. The protection of combustor parts and transition pieces as well as of some stationary gas turbine parts however is state of the art. As a consequence of still insufficient reliability, the application for hot rotating parts is very limited. The introduction as a design element requires safe life within defined time intervals. These depend on the overhaul and repair intervals of the engines. For large land based industrial or utility gas turbines, for example, coating life between 25.000 and 30.000 hrs. is a minimum requirement. Premature failure of a coating by e.g. local spalling causes local overheating of the component with the consequence of its total destruction or even more expensive secondary damages. Life limiting is the corrosion rate at the ceramic-metal interface and the behavior of the coated system under transient operating conditions, where multiaxial strain and stress distributions are generated. Sufficient strain tolerance of the coating both under tensile as well as compressive conditions is required. The properties of thermal barrier coating systems depend strongly on the structure and phase composition of the coating layers and the morphology of and the adhesion at the ceramic-metal interface. They have to be controlled by the process itself, the process parameters and the characteristics of the applied materials (e.g. chemical composition, processing, morphology, particle size and size distribution). It will be reviewed, how properties and structures of coating systems correlate and how structures can be modified by careful control of the process parameters. (orig.)

Transient ischemic attack presenting in an elderly patient with transient ophthalmic manifestations

Directory of Open Access Journals (Sweden)

Sparshi Jain

2016-01-01

Full Text Available Transient ischemic attack (TIA is a transient neurological deficit of cerebrovascular origin without infarction which may last only for a short period and can have varying presentations. We report a case of 58-year-old male with presenting features of sudden onset transient vertical diplopia and transient rotatory nystagmus which self-resolved within 12 h. Patient had no history of any systemic illness. On investigating, hematological investigations and neuroimaging could not explain these sudden and transient findings. A TIA could possibly explain these sudden and transient ocular findings in our patient. This case report aims to highlight the importance of TIA for ophthalmologists. We must not ignore these findings as these could be warning signs of an impending stroke which may or may not be detected on neuroimaging. Thus, early recognition, primary prevention strategies, and timely intervention are needed.

Influence of Metal Transfer Stability and Shielding Gas Composition on CO and CO2 Emissions during Short-circuiting MIG/MAG Welding

Directory of Open Access Journals (Sweden)

Valter Alves de Meneses

Full Text Available Abstract: Several studies have demonstrated the influence of parameters and shielding gas on metal transfer stability or on the generation of fumes in MIG/MAG welding, but little or nothing has been discussed regarding the emission of toxic and asphyxiating gases, particularly as it pertains to parameterization of the process. The purpose of this study was to analyze and evaluate the effect of manufacturing aspects of welding processes (short-circuit metal transfer stability and shielding gas composition on the gas emission levels during MIG/MAG welding (occupational health and environmental aspects. Using mixtures of Argon with CO2 and O2 and maintaining the same average current and the same weld bead volume, short-circuit welding was performed with carbon steel welding wire in open (welder’s breathing zone and confined environments. The welding voltage was adjusted to gradually vary the transfer stability. It was found that the richer the composition of the shielding gas is in CO2, the more CO and CO2 are generated by the arc. However, unlike fume emission, voltage and transfer stability had no effect on the generation of these gases. It was also found that despite the large quantity of CO and CO2 emitted by the arc, especially when using pure CO2 shielding gas, there was no high level residual concentration of CO and CO2 in or near the worker’s breathing zone, even in confined work cells.

In situ laser-induced breakdown spectroscopy measurements of chemical compositions in stainless steels during tungsten inert gas welding

Science.gov (United States)

Taparli, Ugur Alp; Jacobsen, Lars; Griesche, Axel; Michalik, Katarzyna; Mory, David; Kannengiesser, Thomas

2018-01-01

A laser-induced breakdown spectroscopy (LIBS) system was combined with a bead-on-plate Tungsten Inert Gas (TIG) welding process for the in situ measurement of chemical compositions in austenitic stainless steels during welding. Monitoring the weld pool's chemical composition allows governing the weld pool solidification behavior, and thus enables the reduction of susceptibility to weld defects. Conventional inspection methods for weld seams (e.g. ultrasonic inspection) cannot be performed during the welding process. The analysis system also allows in situ study of the correlation between the occurrence of weld defects and changes in the chemical composition in the weld pool or in the two-phase region where solid and liquid phase coexist. First experiments showed that both the shielding Ar gas and the welding arc plasma have a significant effect on the selected Cr II, Ni II and Mn II characteristic emissions, namely an artificial increase of intensity values via unspecific emission in the spectra. In situ investigations showed that this artificial intensity increase reached a maximum in presence of weld plume. Moreover, an explicit decay has been observed with the termination of the welding plume due to infrared radiation during sample cooling. Furthermore, LIBS can be used after welding to map element distribution. For austenitic stainless steels, Mn accumulations on both sides of the weld could be detected between the heat affected zone (HAZ) and the base material.

Production of ZrC Matrix for Use in Gas Fast Reactor Composite Fuels

International Nuclear Information System (INIS)

Vasudevamurthy, Gokul; Knight, Travis W.; Roberts, Elwyn; Adams, Thad

2007-01-01

Zirconium carbide is being considered as a candidate for inert matrix material in composite nuclear fuel for Gas fast reactors due to its favorable characteristics. ZrC can be produced by the direct reaction of pure zirconium and graphite powders. Such a reaction is exothermic in nature. The reaction is self sustaining once initial ignition has been achieved. The heat released during the reaction is high enough to complete the reaction and achieve partial sintering without any external pressure applied. External heat source is required to achieve ignition of the reactants and maintain the temperature close to the adiabatic temperature to achieve higher levels of sintering. External pressure is also a driving force for sintering. In the experiments described, cylindrical compacts of ZrC were produced by direct combustion reaction. External induction heating combined with varying amounts of external applied pressure was employed to achieve varying degrees of density/porosity. The effect of reactant particle size on the product characteristics was also studied. The samples were characterized for density/porosity, composition and microstructure. (authors)

SF6 gas insulated power substations. Effects of fast transients (VFT) on the equipment and adjacent equipment of the Itaipu Binacional SF6 insulated power substations; Subestaciones aisladas a gas SF6. Efectos de los transitorios rapidos (VFT's) sobre equipos y equipos adyacentes de las SE's SF6 de Itaipu Binacional

Energy Technology Data Exchange (ETDEWEB)

Santacruz Martinez, Miguel [Usina Hidroelectrica de Itaipu, Assuncao (Paraguay)]. E-mail: santcruz@itaipu.gov.py

2001-07-01

With the operation starting of the S F6 gas substations in high voltage systems occurs a new form of overvoltage presently known as Very Fast Transients. This paper aims the phenomenon characterization, defining the origins and the behaviour of the electric systems, and briefly presents the damages caused by the phenomenon on the equipment and adjacent equipment of S F6 gas insulated substations of the Itaipu Binacional, mainly on the power transformers and oil/S F6 isolators of the step-up transformers. These equipment was modified or are been modified as a consequence of the this overvoltage effects.

On transient irradiation behavior of HTGR fuel particles

International Nuclear Information System (INIS)

Mortenson, S.C.; Okrent, D.

1977-01-01

An examination of HTGR TRISO coated fuel particles was made in which the particles' stress-strain histories were determined during both steady-state and transient operating conditions. The basis for the examination was a modified version of a computer code written by Kaae which assumed spherical symmetry, isotropic thermal expansion, isotropic elastic constants, time-temperature-irradiation invariant materials properties, and steady state operation during particle exposure. Additionally, the Kaae code modelled potential separation of layers at the SiC-inner PyC interface and considered that several entrapped fission products could exist in either the gaseous or solid state, dependent upon particle operating conditions. Using the modified code which modelled transient behavior in a quasi-static fashion, a series of both steady-state and transient operating condition computer simulations was made. For the former set of runs, a candidate set of particle dimensions and a nominal set of materials' properties was assumed. Layer thicknesses were assumed to be normally distributed about the nominal thickenesses and a probability distribution of SiC tensile stresses was generated; sensitivity of the stress distribution to assumed standard deviation of the layer thicknesses was acute. Further, this series of steady-state runs demonstrated that for certain combinations of the assumed PyC-SiC bond interface strength and irradiation-induced creep constant, anomalous predicted stresses may be obtained in the PyC layers. The steady-state runs also suggest that transient behavior would most likely not be significant at fast neutron exposures below about 10 21 NVT due to both low fission gas pressure and likely beneficial interface separation

Manure gas

Energy Technology Data Exchange (ETDEWEB)

Carre, I

1947-05-01

A short description of the process is given, with gas yields from various feedstocks, and the composition of the gas. Short descriptions of several batch digester designs are given: Algerian, Salubra, Betur, Baudot-Hardoll and Ofta, and Somagaz. The utilization and the economics of the process are discussed. Two diagrams of Ducellier and Isman designs are included.

Surface-Anchored Poly(4-vinylpyridine)–Single-Walled Carbon Nanotube–Metal Composites for Gas Detection

KAUST Repository

Yoon, Bora

2016-08-05

A platform for chemiresistive gas detectors based upon single-walled carbon nanotube (SWCNT) dispersions stabilized by poly(4-vinylpyridine) (P4VP) covalently immobilized onto a glass substrate was developed. To fabricate these devices, a glass substrate with gold electrodes is treated with 3-bromopropyltrichlorosilane. The resulting alkyl bromide coating presents groups that can react with the P4VP to covalently bond (anchor) the polymer–SWCNT composite to the substrate. Residual pyridyl groups in P4VP not consumed in this quaternization reaction are available to coordinate metal nanoparticles or ions chosen to confer selectivity and sensitivity to target gas analytes. Generation of P4VP coordinated to silver nanoparticles produces an enhanced response to ammonia gas. The incorporation of soft Lewis acidic Pd2+ cations by binding PdCl2 to P4VP yields a selective and highly sensitive device that changes resistance upon exposure to vapors of thioethers. The latter materials have utility for odorized fuel leak detection, microbial activity, and breath diagnostics. A third demonstration makes use of permanganate incorporation to produce devices with large responses to vapors of volatile organic compounds that are susceptible to oxidation.

Transient analyzer

International Nuclear Information System (INIS)

Muir, M.D.

1975-01-01

The design and design philosophy of a high performance, extremely versatile transient analyzer is described. This sub-system was designed to be controlled through the data acquisition computer system which allows hands off operation. Thus it may be placed on the experiment side of the high voltage safety break between the experimental device and the control room. This analyzer provides control features which are extremely useful for data acquisition from PPPL diagnostics. These include dynamic sample rate changing, which may be intermixed with multiple post trigger operations with variable length blocks using normal, peak to peak or integrate modes. Included in the discussion are general remarks on the advantages of adding intelligence to transient analyzers, a detailed description of the characteristics of the PPPL transient analyzer, a description of the hardware, firmware, control language and operation of the PPPL transient analyzer, and general remarks on future trends in this type of instrumentation both at PPPL and in general

Preliminary study on application of Pd composite membrane in helium purification system of high-temperature gas-cooled reactor

International Nuclear Information System (INIS)

Cai Jianhua; Yang Xiaoyong; Wang Jie; Yu Suyuan

2008-01-01

Helium purification system (HPS) is the main part of the helium auxiliary system of high-temperature gas-cooled reactors (HTGR), also in fusion reactors. Some exploratory work was carried out on the application of Pd composite membrane in the separation of He and H 2 . A typical single stripper permeator with recycle (SSP) system was designed, based on the design parameters of a small scale He purification test system CIGNE in CADARACHE, CEA, France, and finite element analysis method was used to solve the model. The total length of membrane module is fixed to 0.5 m. The results show that the concentration of H 2 is found to reduce from 1 000 μL/L in feed gas to 5 μL/L in the product He (the upper limitation of HPS in HTGR). And the molar ratio of product He to feed gas is 96.18% with the optimized ratio of sweep gas to retentive gas 0. 3970. It's an exponential distribution of H 2 concentration along the membrane module. The results were also compared with the other two popular designs, two stripper in series permeator (TSSP) and continuous membrane column (CMC). (authors)

Current status of modeling fission gas behaviour in the Karlsruhe code LANGZEIT/KURZZEIT

International Nuclear Information System (INIS)

Vaeth, L.

1980-12-01

The programme LANGZEIT/KURZZEIT has been recently extended to describe intragranular bubble coalescence and volume equilibration, to model intergranular gas behaviour and transient release from closed porosity. The model is described and the results of some comparisons with transient experiments are discussed. Further necessary refinements of the model are outlined. (orig.) [de

Influence of Carrier Gas Composition on the Stress of Al₂O₃ Coatings Prepared by the Aerosol Deposition Method.

Science.gov (United States)

Schubert, Michael; Exner, Jörg; Moos, Ralf

2014-08-05

Al₂O₃ films were prepared by the aerosol deposition method at room temperature using different carrier gas compositions. The layers were deposited on alumina substrates and the film stress of the layer was calculated by measuring the deformation of the substrate. It was shown that the film stress can be halved by using oxygen instead of nitrogen or helium as the carrier gas. The substrates were annealed at different temperature steps to gain information about the temperature dependence of the reduction of the implemented stress. Total relaxation of the stress can already be achieved at 300 °C. The XRD pattern shows crystallite growth and reduction of microstrain while annealing.

Optimizing transient processes with AVL-GCA for a highly flexible gasoline engine; Optimierung transienter Vorgaenge mit AVL-GCA an einem Otto-Motor hoher Flexibilitaet

Energy Technology Data Exchange (ETDEWEB)

Leifert, Thomas; Moreno Nevado, Fernando; Fairbrother, Robert; Prevedel, Kurt [AVL List GmbH, Graz (Austria)

2011-07-01

Optimizing the dynamic operation of a gasoline engine with high flexibility by means of AVL-GCA. Downsizing and Downspeeding are considered being the most promising approaches to significantly reduce CO{sub 2} emission. Because of synergy effects between its technologies, downsized Turbocharged Gasoline Direct Injection (TGDI) engines have the highest potential for fuel economy. The key for high market penetration of such concepts requires customer acceptance and this is closely linked to driver satisfaction. For the drivability rating of vehicles fitted with turbocharged engines, tip-in behavior is of paramount importance. A combined combustion analysis and gas-exchange analysis was performed with AVL GCA (Gas exchange and Combustion Analysis) on a ''beyond-state-of-the-art'' TGDI engine, namely a variable compression ratio engine featuring MCE-5 VCRi technology. With variable compression ratio and 2-stage boosting this engine features an unusually high level of flexibility. Therefore the analysis is used to examine the thermodynamic processes taking place in the cylinders not only in steady state operation but also under highly transient boundary conditions and on a ''cycle-by-cycle'' basis in order to examine hints for optimizing transient response. An established numerical approach for analysis was applied to measurement data acquired on an engine dynamometer thanks to a dedicated measurement chain that will be described in detail. (orig.)

Modeling the Phase Composition of Gas Condensate in Pipelines

Science.gov (United States)

Dudin, S. M.; Zemenkov, Yu D.; Shabarov, A. B.

2016-10-01

Gas condensate fields demonstrate a number of thermodynamic characteristics to be considered when they are developed, as well as when gas condensate is transported and processed. A complicated phase behavior of the gas condensate system, as well as the dependence of the extracted raw materials on the phase state of the deposit other conditions being equal, is a key aspect. Therefore, when designing gas condensate lines the crucial task is to select the most appropriate methods of calculating thermophysical properties and phase equilibrium of the transported gas condensate. The paper describes a physical-mathematical model of a gas-liquid flow in the gas condensate line. It was developed based on balance equations of conservation of mass, impulse and energy of the transported medium within the framework of a quasi-1D approach. Constitutive relationships are given separately, and practical recommendations on how to apply the research results are provided as well.

Statics and rotational dynamics of composite beams

CERN Document Server

Ghorashi, Mehrdaad

2016-01-01

This book presents a comprehensive study of the nonlinear statics and dynamics of composite beams and consists of solutions with and without active elements embedded in the beams. The static solution provides the initial conditions for the dynamic analysis. The dynamic problems considered include the analyses of clamped (hingeless) and articulated (hinged) accelerating rotating beams. Two independent numerical solutions for the steady state and the transient responses are presented. The author illustrates that the transient solution of the nonlinear formulation of accelerating rotating beam converges to the steady state solution obtained by the shooting method. Other key areas considered include calculation of the effect of perturbing the steady state solution, coupled nonlinear flap-lag dynamics of a rotating articulated beam with hinge offset and aerodynamic damping, and static and dynamic responses of nonlinear composite beams with embedded anisotropic piezo-composite actuators. The book is intended as a t...

Modelling, simulation and measurements of fast transients in transformer windings with consideration of frequency-dependent losses

NARCIS (Netherlands)

Popov, M.; Sluis, van der L.; Smeets, R.P.P.; Lopez Roldan, J.; Terzija, V.V.

2007-01-01

For the specification of winding insulation of transformers, it is important to know the electrical stresses to which the winding can be exposed during fast transient oscillations. These oscillations occur during switching operations performed by circuit breakers, or when gas-insulated substations

The improvement of gas-sensing properties of SnO2/zeolite-assembled composite

Science.gov (United States)

Sun, Yanhui; Wang, Jing; Li, Xiaogan; Du, Haiying; Huang, Qingpan

2018-05-01

SnO2-impregnated zeolite composites were used as gas-sensing materials to improve the sensitivity and selectivity of the metal oxide-based resistive-type gas sensors. Nanocrystalline MFI type zeolite (ZSM-5) was prepared by hydrothermal synthesis. Highly dispersive SnO2 nanoparticles were then successfully assembled on the surface of the ZSM-5 nanoparticles by using the impregnation methods. The SnO2 nanoparticles are nearly spherical with the particle size of 10 nm. An enhanced formaldehyde sensing of as-synthesized SnO2-ZSM-5-based sensor was observed whereas a suppression on the sensor response to other volatile organic vapors (VOCs) such as acetone, ethanol, and methanol was noticed. The possible reasons for this contrary observation were proposed to be related to the amount of the produced water vapor during the sensing reactions assisted by the ZSM-5 nanoparticles. This provides a possible new strategy to improve the selectivity of the gas sensors. The effect of the humidity on the sensor response to formaldehyde was investigated and it was found the higher humidity would decrease the sensor response. A coating layer of the ZSM-5 nanoparticles on top of the SnO2-ZSM-5-sensing film was thus applied to further improve the sensitivity and selectivity of the sensor through the strong adsorption ability to polar gases and the "filtering effect" by the pores of ZSM-5.

Titanium Matrix Composite Ti/TiN Produced by Diode Laser Gas Nitriding

Directory of Open Access Journals (Sweden)

Aleksander Lisiecki

2015-01-01

Full Text Available A high power direct diode laser, emitting in the range of near infrared radiation at wavelength 808–940 nm, was applied to produce a titanium matrix composite on a surface layer of titanium alloy Ti6Al4V by laser surface gas nitriding. The nitrided surface layers were produced as single stringer beads at different heat inputs, different scanning speeds, and different powers of laser beam. The influence of laser nitriding parameters on the quality, shape, and morphology of the surface layers was investigated. It was found that the nitrided surface layers consist of titanium nitride precipitations mainly in the form of dendrites embedded in the titanium alloy matrix. The titanium nitrides are produced as a result of the reaction between molten Ti and gaseous nitrogen. Solidification and subsequent growth of the TiN dendrites takes place to a large extent at the interface of the molten Ti and the nitrogen gas atmosphere. The direction of TiN dendrites growth is perpendicular to the surface of molten Ti. The roughness of the surface layers depends strongly on the heat input of laser nitriding and can be precisely controlled. In spite of high microhardness up to 2400 HV0.2, the surface layers are crack free.

R + D work on gas-cooled breeder development

International Nuclear Information System (INIS)

Dalle Donne, M.; Dorner, S.; Jacobs, G.; Meyer, L.; Rehme, K.; Schumacher, G.; Wilhelm, D.

1978-01-01

The development work for the gas-cooled breeder in the Karlsruhe Nuclear Research Center may be assigned to two different groups: a) Investigations on fuel elements. b) Studies concerning the safety of gas-cooled fast breeder reactors. To the first group there belongs the work related to the: - heat transfer between fuel elements and coolant gas, - influence of increased content of water vapor in helium or the fuel rods. The second group concerns: - establishing a computer code for transient calculations in the primary and secondary circuit of a gas-cooled fast breeder reactor, - steam reactivity coefficients, - the core destruction phase of hypothetical accidents, - the core-catcher using borax. (orig./RW) [de

Development of robust fluorinated TiO2/PVDF composite hollow fiber membrane for CO2 capture in gas-liquid membrane contactor

Science.gov (United States)

Lin, Yuqing; Xu, Yilin; Loh, Chun Heng; Wang, Rong

2018-04-01

Gas-liquid membrane contactor (GLMC) is a promising method to attain high efficiency for CO2 capture from flue gas, biogas and natural gas. However, membranes used in GLMC are prone to pore wetting due to insufficient hydrophobicity and low chemical resistance, resulting in significant increase in mass transfer resistance. To mitigate this issue, inorganic-organic fluorinated titania/polyvinylidene fluoride (fTiO2/PVDF) composite hollow fiber (HF) membranes was prepared via facile in-situ vapor induced hydrolyzation method, followed by hydrophobic modification. The proposed composite membranes were expected to couple the superb chemical stability of inorganic and high permeability/low cost of organic materials. The continuous fTiO2 layer deposited on top of PVDF substrate was found to possess a tighter microstructure and better hydrophobicity, which effectively prevented the membrane from wetting and lead to a high CO2 absorption flux (12.7 × 10-3 mol m-2 s-1). In a stability test with 21-day operation of GLMC using 1M monoethanolamine (MEA) as the absorbent, the fTiO2/PVDF membrane remained to be intact with a CO2 absorption flux decline of ∼16%, while the pristine PVDF membrane suffered from a flux decline of ∼80% due to membrane damage. Overall, this work provides an insight into the preparation of high-quality inorganic/organic composite HF membranes for CO2 capture in GLMC application.

Transient drainage summary report

International Nuclear Information System (INIS)

1996-09-01

This report summarizes the history of transient drainage issues on the Uranium Mill Tailings Remedial Action (UMTRA) Project. It defines and describes the UMTRA Project disposal cell transient drainage process and chronicles UMTRA Project treatment of the transient drainage phenomenon. Section 4.0 includes a conceptual cross section of each UMTRA Project disposal site and summarizes design and construction information, the ground water protection strategy, and the potential for transient drainage

Segregated copper ratio experiment on transient stability (SeCRETS). Final Report

Energy Technology Data Exchange (ETDEWEB)

Bruzzone, P. [ed.] [Ecole Polytechnique Federale de Lausanne, Centre de Recherches en Physique des Plasmas (CRPP), CH-1015 Lausanne (Switzerland)

2001-01-01

Two Nb{sub 3}Sn, steel jacketed, cable-in-conduit conductors have been manufactured with identical non-Cu cross sections and the stabilizer either included in the Nb{sub 3}Sn composite or partly segregated as copper wires. The two conductors are series connected and wound as a bifilar , single layer solenoid, assembled in the high field bore (11 T) of the SULTAN test facility. The operating current is up to 12 kA (400 A/mm{sup 2}). A transverse pulsed field is applied with {delta}B up to 2.7 T, field rate up to 180 T/s and field integral up to 530 T{sup 2}/s. In the dc test, a good agreement is found between the I{sub c} and the T{sub cs} results, both correctly scaling according to the parameters derived from the strand tests. The n-value from the V-I curve is in the range of 15. The current sharing at the high field section is correlated with a local current re-distribution, observed by arrays of miniature Hall sensors, detecting the self-field around the conductor. The ac losses results in the range of 2 to 9 Hz by gas flow calorimetry indicate coupling currents constant, n{tau}, in the range of 1.5 ms at high field, increasing by a factor of 2 with 12 kA transport current. Loss extrapolation to 0 frequency suggests that the loss curve may be not linear outside the test range, with higher n{tau} at lower field rate. The calorimetric loss estimation at the fast field transient (f=15 Hz) indicates n{tau} {approx_equal} 2 ms. The ITER plasma disruption transients have been reproduced by the pulsed coils. Due to the very low ac losses, no quench could be generated in either conductor even reducing the temperature margin below 0.2-0.3 K. Very large field transients, with integral above 100 T{sup 2}/s, are required to quench the conductors. In that range, the conductor without segregated copper has superior performance. Due to the large interstrand resistance (very low ac losses), the segregated copper has marginal contribution to the stability. No evidence of current

TRANSIENT ELECTRONICS CATEGORIZATION

Science.gov (United States)

2017-08-24

AFRL-RY-WP-TR-2017-0169 TRANSIENT ELECTRONICS CATEGORIZATION Dr. Burhan Bayraktaroglu Devices for Sensing Branch Aerospace Components & Subsystems...SUBTITLE TRANSIENT ELECTRONICS CATEGORIZATION 5a. CONTRACT NUMBER In-house 5b. GRANT NUMBER N/A 5c. PROGRAM ELEMENT NUMBER N/A 6. AUTHOR(S) Dr. Burhan...88ABW-2017-3747, Clearance Date 31 July 2017. Paper contains color. 14. ABSTRACT Transient electronics is an emerging technology area that lacks proper

LOFA and RIA analysis of the Indonesian Multipurpose research reactor RSG-GAS 1)

International Nuclear Information System (INIS)

Endiah Puji Hastuti; Hudi Hastowo; Iman Kuntoro

1999-01-01

Investigation on accident of the Indonesian Multipurpose research reactor RSG-GAS has been performed by computer simulation technique. Two groups of transients were considered, namely transient due to loss of primary cooling system (LOFA) and power excursion due to reactivity insertion (RIA). In such a transient condition, the Common Mode Failure (CMF) is considered and it will induce a situation so called unprotected transient or Anticipated Transient Without Scram (ATWS). RELAP5, PARET-ANL and EUREKA-2RR computer packages have been applied for these analyses. Simulations result done using these computer packages showed that in the occurrence of LOFA and RIA, failure on fuel elements is limited to the region with the highest power factor. (author)

Coupling of a two phase gas liquid 3D Darcy flow in fractured porous media with a 1D free gas flow

OpenAIRE

Brenner , Konstantin; Masson , Roland; Trenty , Laurent; Zhang , Yumeng

2015-01-01

A model coupling a three dimensional gas liquid compositional Darcy flow in a frac-tured porous medium, and a one dimensional compositional free gas flow is presented. The coupling conditions at the interface between the gallery and the porous medium account for the molar normal fluxes continuity for each component, the gas liquid thermody-namical equilibrium, the gas pressure continuity and the gas and liquid molar fractions continuity. The fractures are represented as interfaces of codimens...

Analysis of the chemical composition of the essential oils extracted from Lippia lacunosa Mart. and Schauer and Lippia rotundifolia Cham. (Verbenaceae) by gas chromatography and gas chromatography-mass spectrometry

International Nuclear Information System (INIS)

Leitao, Suzana G.; Barbosa, Ymira Galico; Viccini, Lyderson F.; Salimena, Fatima R.G.; Peixoto, Paulo H.P.

2008-01-01

Lippia lacunosa and L. rotundifolia (Verbenaceae) are two Brazilian species of complex taxonomic delimitation. The composition of the essential oils from leaves and flowers of these plants was investigated by gas chromatography (GC) and gas chromatography coupled with mass spectrometry (GC-MS) analysis. The major components of the essential oils of flowers and leaves of L. lacunosa were: myrcene (14.7% and 11.9%), myrcenone (45.2% and 64.2%), Z-ocimenone (5.7% and 5.2%), and E-ocimenone (14.7% and 4.1%), respectively; whereas in L. rotundifolia (flowers and leaves) were ..-pinene (8.7% and 1.8%), myrcene (5.1% and 3.6%), limonene (26.0% and 7.9 %), cis-pinocamphone (4.5% and 3.1%) and myrtenal (22.3% and 16.7%), respectively. The essential oils from L. lacunosa exhibited a strong and pleasant mango aroma, which was related to the presence of myrcene and myrcenone. The marked differences in the chemical composition of their essential oils may represent a powerful tool for the botanical classification. (author)

Analysis of the chemical composition of the essential oils extracted from Lippia lacunosa Mart. and Schauer and Lippia rotundifolia Cham. (Verbenaceae) by gas chromatography and gas chromatography-mass spectrometry

Energy Technology Data Exchange (ETDEWEB)

Leitao, Suzana G.; Barbosa, Ymira Galico [Universidade Federal do Rio de Janeiro (UFRJ), Rio de Janeiro, RJ (Brazil). Fac. de Farmacia; Oliveira, Danilo R. de; Leitao, Gilda G. [Universidade Federal do Rio de Janeiro (UFRJ), Rio de Janeiro, RJ (Brazil). Nucleo de Pesquisas de Produtos Naturais]. E-mail: sgleitao@pharma.ufrj.br; Suelsen, Valeria; Martino, Virginia [Universidad de Buenos Aires (Argentina). Facultad de Farmacia y Bioquimica; Bizzo, Humberto R.; Lopes, Daise [EMBRAPA Agroindustria de Alimentos, Rio de Janeiro, RJ (Brazil); Viccini, Lyderson F.; Salimena, Fatima R.G.; Peixoto, Paulo H.P. [Universidade Federal de Juiz de Fora (UFJF), Juiz de Fora, MG (Brazil). Inst. de Ciencias Biolgicas

2008-07-01

Lippia lacunosa and L. rotundifolia (Verbenaceae) are two Brazilian species of complex taxonomic delimitation. The composition of the essential oils from leaves and flowers of these plants was investigated by gas chromatography (GC) and gas chromatography coupled with mass spectrometry (GC-MS) analysis. The major components of the essential oils of flowers and leaves of L. lacunosa were: myrcene (14.7% and 11.9%), myrcenone (45.2% and 64.2%), Z-ocimenone (5.7% and 5.2%), and E-ocimenone (14.7% and 4.1%), respectively; whereas in L. rotundifolia (flowers and leaves) were ..-pinene (8.7% and 1.8%), myrcene (5.1% and 3.6%), limonene (26.0% and 7.9 %), cis-pinocamphone (4.5% and 3.1%) and myrtenal (22.3% and 16.7%), respectively. The essential oils from L. lacunosa exhibited a strong and pleasant mango aroma, which was related to the presence of myrcene and myrcenone. The marked differences in the chemical composition of their essential oils may represent a powerful tool for the botanical classification. (author)

Stabilization of the composition of the gas medium of a repetitively pulsed CO/sub 2/ laser by means of hopcalite

Energy Technology Data Exchange (ETDEWEB)

Baranov, V.IU.; Drokov, G.F.; Kuzmenko, V.A.; Mezhevov, V.S.; Pigulskaia, V.V.

1986-05-01

Results of experiments in which hopcalite was used to stabilize the composition of the gas medium of repetitively pulsed and monopulse CO/sub 2/ lasers are reported. In particular, the mechanisms of the decrease in the catalyst activity with time under conditions for catalyst regeneration are determined. It is shown that the use of hopcalite has made it possible to achieve long-term operation of a high-power repetitively pulsed CO/sub 2/ laser without changing the gas mixture in a closed circuit. Some details related to the use of hopcalite are discussed. 11 references.

Fabrication of Cubic p-n Heterojunction-Like NiO/In2O3 Composite Microparticles and Their Enhanced Gas Sensing Characteristics

Directory of Open Access Journals (Sweden)

Hou Xuemei

2016-01-01

Full Text Available Oxide semiconductor In2O3 has been extensively used as a gas sensing material for the detection of various toxic gases. However, the pure In2O3 sensor is always suffering from its low sensitivity. In the present study, a dramatic enhancement of sensing characteristic of cubic In2O3 was achieved by deliberately fabricating p-n heterojunction-like NiO/In2O3 composite microparticles as sensor material. The NiO-decorated In2O3 p-n heterojunction-like sensors were prepared through the hydrothermal transformation method. The as-synthesized products were characterized using SEM-EDS, XRD, and FT-IR, and their gas sensing characteristics were investigated by detecting the gas response. The experimental results showed that the response of the NiO/In2O3 sensors to 600 ppm methanal was 85.5 at 260°C, revealing a dramatic enhancement over the pure In2O3 cubes (21.1 at 260°C. Further, a selective detection of methanol with inappreciable cross-response to other gases, like formaldehyde, benzene, methylbenzene, trichloromethane, ethanol, and ammonia, was achieved. The cause for the enhanced gas response was discussed in detailed. In view of the facile method of fabrication of such composite sensors and the superior gas response performance of samples, the cubic p-n heterojunction-like NiO/In2O3 sensors present to be a promising and viable strategy for the detection of indoor air pollution.

The effect of the gas composition on hydrogen-assisted NH3-SCR over Ag/Al2O3

DEFF Research Database (Denmark)

Tamm, Stefanie; Fogel, Sebastian; Gabrielsson, Pär

2013-01-01

In addition to high activity in hydrocarbon-SCR, Ag/Al2O3 catalysts show excellent activity for NOx reduction for H2-assisted NH3-SCR already at 200°C. Here, we study the influence of different gas compositions on the activity of a pre-sulfated 6wt% Ag/Al2O3 catalyst for NOx reduction, and oxidat...

Gas dynamic lasers

International Nuclear Information System (INIS)

Hill, R.J.; Jewell, N.T.

1975-01-01

In a high powered laser system it is proposed that combustion gases be bled off from a gas turbine engine and their composition adjusted by burning extra fuel in the bleed gases or adding extra substances. Suitable aerodynamic expansion produces a population inversion resulting in laser action in the CO 2 species. Alternatively, bleed gases may be taken from the high pressure compressor of the gas turbine engine and an appropriate fuel burned therein. If required, other adjustments may also be made to the composition and the resulting gaseous mixture subjected to aerodynamic expansion to induce laser action as before. (auth)

Composite interlayer for diffusion bonding

International Nuclear Information System (INIS)

1976-01-01

A ductile interlayer is described, which is useful for transient liquid phase diffusion bonding of metallic articles; the interlayer consisting of a melting point depressant and a plurality of ductile lamellae which are free from carbides, aluminides and borides. The composition and fabrication of the lamellae, and the process for bonding the metallic articles, depend on the composition of the metals to be bonded, and are exemplified in the specification. (U.K.)

PSH Transient Simulation Modeling

Energy Technology Data Exchange (ETDEWEB)

Muljadi, Eduard [National Renewable Energy Laboratory (NREL), Golden, CO (United States)

2017-12-21

PSH Transient Simulation Modeling presentation from the WPTO FY14 - FY16 Peer Review. Transient effects are an important consideration when designing a PSH system, yet numerical techniques for hydraulic transient analysis still need improvements for adjustable-speed (AS) reversible pump-turbine applications.

Influence of surrounding gas, composition and pressure on plasma plume dynamics of nanosecond pulsed laser-induced aluminum plasmas

Directory of Open Access Journals (Sweden)

Mahmoud S. Dawood

2015-10-01

Full Text Available In this article, we present a comprehensive study of the plume dynamics of plasmas generated by laser ablation of an aluminum target. The effect of both ambient gas composition (helium, nitrogen or argon and pressure (from ∼5 × 10−7 Torr up to atmosphere is studied. The time- and space- resolved observation of the plasma plume are performed from spectrally integrated images using an intensified Charge Coupled Device (iCCD camera. The iCCD images show that the ambient gas does not significantly influence the plume as long as the gas pressure is lower than 20 Torr and the time delay below 300 ns. However, for pressures higher than 20 Torr, the effect of the ambient gas becomes important, the shortest plasma plume length being observed when the gas mass species is highest. On the other hand, space- and time- resolved emission spectroscopy of aluminum ions at λ = 281.6 nm are used to determine the Time-Of-Flight (TOF profiles. The effect of the ambient gas on the TOF profiles and therefore on the propagation velocity of Al ions is discussed. A correlation between the plasma plume expansion velocity deduced from the iCCD images and that estimated from the TOF profiles is presented. The observed differences are attributed mainly to the different physical mechanisms governing the two diagnostic techniques.

Polyvinylpyrrolidone/ Poly aniline Composite Based 36 degree YX LiTaO3 Surface Acoustic Wave H2 Gas Sensor

International Nuclear Information System (INIS)

Amir Sidek; Rashidah Arsat; Xiuli, He; Kalantar-zadeh, K.; Wlodarski, W.

2013-01-01

Poly-vinyl-pyrrolidone (PVP)/ poly aniline based surface acoustic wave (SAW) sensors were fabricated and characterized and their performances towards hydrogen gas were investigated. The PVP/ poly aniline fibers composite were prepared by electro spinning of the composite aqueous solution deposited directly onto the active area of SAW transducers. Via scanning electron microscopy (SEM), the morphology of the deposited nano structure material was observed. From the dynamic response, frequency shifts of 6.243 kHz (1% H 2 ) and 8.051 kHz (1% H 2 ) were recorded for the sensors deposited with PVP/ ES and PVP/ EB, respectively. (author)

A Novel Boil-Off Gas Re-Liquefaction Using a Spray Recondenser for Liquefied Natural-Gas Bunkering Operations

Directory of Open Access Journals (Sweden)

Jiheon Ryu

2016-11-01

Full Text Available This study presents the design of a novel boil-off gas (BOG re-liquefaction technology using a BOG recondenser system. The BOG recondenser system targets the liquefied natural gas (LNG bunkering operation, in which the BOG phase transition occurs in a pressure vessel instead of a heat exchanger. The BOG that is generated during LNG bunkering operation is characterized as an intermittent flow with various peak loads. The system was designed to temporarily store the transient BOG inflow, condense it with subcooled LNG and store the condensed liquid. The superiority of the system was verified by comparing it with the most extensively employed conventional re-liquefaction system in terms of consumption energy and via an exergy analysis. Static simulations were conducted for three compositions; the results indicated that the proposed system provided 0 to 6.9% higher efficiencies. The exergy analysis indicates that the useful work of the conventional system is 24.9%, and the useful work of the proposed system is 26.0%. Process dynamic simulations of six cases were also performed to verify the behaviour of the BOG recondenser system. The results show that the pressure of the holdup in the recondenser vessel increased during the BOG inflow mode and decreased during the initialization mode. The maximum pressure of one of the bunkering cases was 3.45 bar. The system encountered a challenge during repetitive operations due to overpressurizing of the BOG recondenser vessel.

Improved irradiation tolerance of reactive gas pulse sputtered TiN coatings with a hybrid architecture of multilayered and compositionally graded structures

Science.gov (United States)

Liang, Wei; Yang, Jijun; Zhang, Feifei; Lu, Chenyang; Wang, Lumin; Liao, Jiali; Yang, Yuanyou; Liu, Ning

2018-04-01

This study investigates the improved irradiation tolerance of reactive gas pulse (RGP) sputtered TiN coatings which has hybrid architecture of multilayered and compositionally graded structures. The multilayered RGP-TiN coating is composed of hexagonal close-packed Ti phase and face-centred cubic TiN phase sublayers, where the former sublayer has a compositionally graded structure and the latter one maintains constant stoichiometric atomic ratio of Ti:N. After 100 keV He ion irradiation, the RGP-TiN coating exhibits improved irradiation resistance compared with its single layered (SL) counterpart. The size and density of He bubbles are smaller in the RGP-TiN coating than in the SL-TiN coating. The irradiation-induced surface blistering of the coatings shows a similar tendency. Meanwhile, the irradiation hardening and adhesion strength of the RGP-TiN coatings were not greatly affected by He irradiation. Moreover, the irradiation damage tolerance of the coatings can be well tuned by changing the undulation period number of N2 gas flow rate. Detailed analysis suggested that this improved irradiation tolerance could be related to the combined contribution of the multilayered and compositionally graded structures.

A study of transient jet and spray using a Schlieren method and digital image processing

Energy Technology Data Exchange (ETDEWEB)

Paulsen, H.

1995-12-31

This thesis discusses visualization and image-based data acquisition and analyses on transient gas jet, evaporating spray and burning jet in an attempt to find a method of measuring the transient behaviour of these phenomena, which influence the combustion process in diesel engines. The experimental approach is based on visualization of the injection process inside a constant volume air chamber. The influence of different experimental conditions such as fuel type, injection conditions, temperature and pressure of the chamber is investigated. To control the dynamics of the injection, a constant pressure injection system is used. The dynamics of the fuel injection system itself is not discussed. A full-field classical Schlieren technique is used, and the data recorded by means of a CCD camera and frame-grabber combination. The method has the unusual property of being particularly useful for measurements on a dynamic system, since the gradients in the light refraction index used by the Schlieren method are enhanced by the dynamics. The method was used to measure local gas concentration inside a room temperature methane gas jet, and vapour phase concentration evaporating propane spray. The system was also used to measure the local temperature of burning methane jet based on calculated density distribution. 47 refs., 92 figs., 3 tabs.

Enhancing the ABAQUS thermomechanics code to simulate multipellet steady and transient LWR fuel rod behavior

International Nuclear Information System (INIS)

Williamson, R.L.

2011-01-01

Highlights: → The ABAQUS thermomechanics code is enhanced to enable simulation of nuclear fuel behavior. → Comparisons are made between discrete and smeared fuel pellet analysis. → Multidimensional and multipellet analysis is important for accurate prediction of PCMI. → Fully coupled thermomechanics results in very smooth prediction of fuel-clad gap closure. → A smeared-pellet approximation results in significant underprediction of clad radial displacements and plastic strain. - Abstract: A powerful multidimensional fuels performance analysis capability, applicable to both steady and transient fuel behavior, is developed based on enhancements to the commercially available ABAQUS general-purpose thermomechanics code. Enhanced capabilities are described, including: UO 2 temperature and burnup dependent thermal properties, solid and gaseous fission product swelling, fuel densification, fission gas release, cladding thermal and irradiation creep, cladding irradiation growth, gap heat transfer, and gap/plenum gas behavior during irradiation. This new capability is demonstrated using a 2D axisymmetric analysis of the upper section of a simplified multipellet fuel rod, during both steady and transient operation. Comparisons are made between discrete and smeared-pellet simulations. Computational results demonstrate the importance of a multidimensional, multipellet, fully-coupled thermomechanical approach. Interestingly, many of the inherent deficiencies in existing fuel performance codes (e.g., 1D thermomechanics, loose thermomechanical coupling, separate steady and transient analysis, cumbersome pre- and post-processing) are, in fact, ABAQUS strengths.

Multilayer composite membranes for gas separation based on crosslinked PTMSP gutter layer and partially crosslinked Matrimid R 5218 selective layer

Czech Academy of Sciences Publication Activity Database

Peter, Jakub; Peinemann, K.; V.

2009-01-01

Roč. 340, 1-2 (2009), s. 62-72 ISSN 0376-7388 Grant - others:Marie Curie fellowship(XE) HPMT-CT-2001-00220 Institutional research plan: CEZ:AV0Z40500505 Keywords : composite membrane * gas separation * PTMSP * Matrimid Subject RIV: CD - Macromolecular Chemistry Impact factor: 3.203, year: 2009

Design of Low-Melting Point Compositions Suitable for Transient Liquid Phase Sintering of PM Steels Based on a Thermodynamic and Kinetic Study

Science.gov (United States)

Bernardo, Elena; de Oro, Raquel; Campos, Mónica; Torralba, José Manuel

2014-04-01

The possibility of tailoring the characteristics of a liquid metal is an important asset in a wide number of processing techniques. For most of these processes, the nature and degree of the interaction between liquid and solid phases are usually a focus of interest since they determine liquid properties such as wettability and infiltration capacity. Particularly, within the powder metallurgy (PM) technology, it is considered one of the key aspects to obtain high performance steels through liquid phase sintering. In this work, it is proved how thermodynamic and kinetics software is a powerful tool to study the liquid/solid interactions. The assessment of different liquid phase promoters for transient liquid phase sintering is addressed through the use of ThermoCalc and DICTRA calculations. Besides melting temperatures, particular attention is given to the solubility phenomena between the phases and the kinetics of these processes. Experimental validation of thermodynamic results is carried out by wetting and infiltration experiments at high temperatures. Compositions presenting different liquid/solid solubility are evaluated and directly correlated to the behavior of the liquid during a real sintering process. Therefore, this work opens the possibility to optimize liquid phase compositions and predict the liquid behavior from the design step, which is considered of high technological value for the PM industry.

Study of transient phenomena in the Vivitron during an electric discharge

International Nuclear Information System (INIS)

Roumie, M.

1994-04-01

The Vivitron is a new Van der Graaff Tandem type accelerator, which is designed to reach 35 millions volts. The major problem which limits the voltage is the electrical discharge in insulating gas. This discharge leads to a spark short-circuiting two discrete electrodes, or column, and creates a transient developing a high electric field. Damage is observed on the column insulators. The aim of this work is to study the time evolution of the phenomena when the first spark is established. The use of computer simulations, with the PSpice code and physical models based on 'transmission lines' is first justified. Simulations of the real spark by a short-circuit are then carried out, using this model, to explain the progress of transients and to show the voltage modification. Several solutions for this problem are then proposed. (from author) 67 figs., 23 refs

Transient analysis on the SMART-P anticipated transients without scram