WorldWideScience

Sample records for fuel development activities

  1. State activities that promote fuel cell and hydrogen infrastructure development

    Energy Technology Data Exchange (ETDEWEB)

    Gangi, J. [Fuel Cells 2000, Washington, DC (United States). Breakthrough Technologies Inst.

    2007-07-01

    The fuel cell and hydrogen industry provide environmental benefits in addition to economic benefits in the form of jobs and business. This presentation outlined the initiatives, policy and partnerships that individual states are initiating to promote the commercialization of fuel cells and hydrogen fuels. Multi-state partnerships and regional organizations and initiatives were highlighted along with state programs, regulations, demonstrations and incentives that include hydrogen, fuel cells and zero emission vehicles. It was shown that 47 states and the District of Columbia (DC) are involved in the promotion of fuel cell or hydrogen legislation and funding. Breakthrough Technologies Institute, the parent organization of Fuel Cells 2000, and the U.S. Department of Energy's Hydrogen Program has launched a searchable database that catalogues all stationary installations, hydrogen fueling stations and vehicle demonstration programs in the United States, including cars, buses and specialty vehicles. The database is intended to be a guide for local, state and federal lawmakers to implement similar legislation and initiatives in their jurisdictions. The database includes regulations such as interconnection standards, renewable portfolio standards and net metering as well as legislation such as tax credits, grants, and loans. Roadmaps and funding/support for business incubators and relocation are included. The database is also an important tool for the general public who are trying to learn more about the technology. Although federal research money has mainly focused on transportation and related fuel technologies, individual states are targeting other applications and areas such as materials and components, stationary power and fuel storage.

  2. FY2015 ceramic fuels development annual highlights

    Energy Technology Data Exchange (ETDEWEB)

    Mcclellan, Kenneth James [Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)

    2015-09-22

    Key challenges for the Advanced Fuels Campaign are the development of fuel technologies to enable major increases in fuel performance (safety, reliability, power and burnup) beyond current technologies, and development of characterization methods and predictive fuel performance models to enable more efficient development and licensing of advanced fuels. Ceramic fuel development activities for fiscal year 2015 fell within the areas of 1) National and International Technical Integration, 2) Advanced Accident Tolerant Ceramic Fuel Development, 3) Advanced Techniques and Reference Materials Development, and 4) Fabrication of Enriched Ceramic Fuels. High uranium density fuels were the focus of the ceramic fuels efforts. Accomplishments for FY15 primarily reflect the prioritization of identification and assessment of new ceramic fuels for light water reactors which have enhanced accident tolerance while also maintaining or improving normal operation performance, and exploration of advanced post irradiation examination techniques which will support more efficient testing and qualification of new fuel systems.

  3. FY2016 Ceramic Fuels Development Annual Highlights

    Energy Technology Data Exchange (ETDEWEB)

    Mcclellan, Kenneth James [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

    2017-01-24

    Key challenges for the Advanced Fuels Campaign are the development of fuel technologies to enable major increases in fuel performance (safety, reliability, power and burnup) beyond current technologies, and development of characterization methods and predictive fuel performance models to enable more efficient development and licensing of advanced fuels. Ceramic fuel development activities for fiscal year 2016 fell within the areas of 1) National and International Technical Integration, 2) Advanced Accident Tolerant Ceramic Fuel Development, 3) Advanced Techniques and Reference Materials Development, and 4) Fabrication of Enriched Ceramic Fuels. High uranium density fuels were the focus of the ceramic fuels efforts. Accomplishments for FY16 primarily reflect the prioritization of identification and assessment of new ceramic fuels for light water reactors which have enhanced accident tolerance while also maintaining or improving normal operation performance, and exploration of advanced post irradiation examination techniques which will support more efficient testing and qualification of new fuel systems.

  4. NASA's Planned Fuel Cell Development Activities for 2009 and Beyond in Support of the Exploration Vision

    Science.gov (United States)

    Hoberecht, Mark A.

    2010-01-01

    NASA s Energy Storage Project is one of many technology development efforts being implemented as part of the Exploration Technology Development Program (ETDP), under the auspices of the Exploration Systems Mission Directorate (ESMD). The Energy Storage Project is a focused technology development effort to advance lithium-ion battery and proton-exchange-membrane fuel cell (PEMFC) technologies to meet the specific power and energy storage needs of NASA Exploration missions. The fuel cell portion of the project has as its focus the development of both primary fuel cell power systems and regenerative fuel cell (RFC) energy storage systems, and is led by the NASA Glenn Research Center (GRC) in partnership with the Johnson Space Center (JSC), the Jet Propulsion Laboratory (JPL), the Kennedy Space Center (KSC), academia, and industrial partners. The development goals are to improve stack electrical performance, reduce system mass and parasitic power requirements, and increase system life and reliability.

  5. Metallic fuel design development

    Energy Technology Data Exchange (ETDEWEB)

    Hwang, Woan; Kang, H. Y.; Lee, B. O. and others

    1999-04-01

    This report describes the R and D results of the ''Metallic Fuel Design Development'' project that performed as a part of 'Nuclear Research and Development Program' during the '97 - '98 project years. The objectives of this project are to perform the analysis of thermo-mechanical and irradiation behaviors, and preliminary conceptual design for the fuel system of the KALIMER liquid metal reactor. The following are the major results that obtained through the project. The preliminary design requirements and design criteria which are necessary in conceptual design stage, are set up. In the field of fuel pin design, the pin behavior analysis, failure probability prediction, and sensitivity analysis are performed under the operation conditions of steady-state and transient accidents. In the area of assembly duct analysis; 1) KAFACON-2D program is developed to calculate an array configuration of inner shape of assembly duct, 2) Stress-strain analysis are performed for the components of assembly such as, handling socket, mounting rail and wire wrap, 3) The BDI program is developed to analyze mechanical interaction between pin bundle and duct, 4) a vibration analysis is performed to understand flow-induced vibration of assembly duct, 5) The NUBOW-2D, which is bowing and deformation analysis code for assembly duct, is modified to be operated in KALIMER circumstance, and integrity evaluation of KALIMER core assembly is carried out using the modified NUBOW-2D and the CRAMP code in U.K., and 6) The KALIMER assembly duct is manufactured to be used in flow test. In the area of non-fuel assembly, such as control, reflector, shielding, GEM and USS, the states-of-the-arts and the major considerations in designing are evaluated, and the design concepts are derived. The preliminary design description and their design drawing of KALIMER fuel system are prepared based upon the above mentioned evaluation and analysis. The achievement of conceptual

  6. Monolithic Fuel Fabrication Process Development

    Energy Technology Data Exchange (ETDEWEB)

    C. R. Clark; N. P. Hallinan; J. F. Jue; D. D. Keiser; J. M. Wight

    2006-05-01

    The pursuit of a high uranium density research reactor fuel plate has led to monolithic fuel, which possesses the greatest possible uranium density in the fuel region. Process developments in fabrication development include friction stir welding tool geometry and cooling improvements and a reduction in the length of time required to complete the transient liquid phase bonding process. Annealing effects on the microstructures of the U-10Mo foil and friction stir welded aluminum 6061 cladding are also examined.

  7. Development of carbon free diffusion layer for activated carbon air cathode of microbial fuel cells.

    Science.gov (United States)

    Yang, Wulin; Kim, Kyoung-Yeol; Logan, Bruce E

    2015-12-01

    The fabrication of activated carbon air cathodes for larger-scale microbial fuel cells requires a diffusion layer (DL) that is highly resistant to water leakage, oxygen permeable, and made using inexpensive materials. A hydrophobic polyvinylidene fluoride (PVDF) membrane synthesized using a simple phase inversion process was examined as a low cost ($0.9/m(2)), carbon-free DL that prevented water leakage at high pressure heads compared to a polytetrafluoroethylene/carbon black DL ($11/m(2)). The power density produced with a PVDF (20%, w/v) DL membrane of 1400±7mW/m(2) was similar to that obtained using a wipe DL [cloth coated with poly(dimethylsiloxane)]. Water head tolerance reached 1.9m (∼19kPa) with no mesh supporter, and 2.1m (∼21kPa, maximum testing pressure) with a mesh supporter, compared to 0.2±0.05m for the wipe DL. The elimination of carbon black from the DL greatly simplified the fabrication procedure and further reduced overall cathode costs.

  8. Develop high activity, low cost non-PGM fuel cell electrocatalyst and stable supports

    Energy Technology Data Exchange (ETDEWEB)

    Colon-Mercado, H. R. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Elvington, M. C. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL; Garcia-Diaz, B. L. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL; Gaillard, J. B. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL

    2016-09-28

    A unique approach has been developed to probe the non-PGM catalyst active site for the Oxygen Reduction Reaction (ORR) for PEMFC. Iron based functionalities have been engineered into Metallic Organic Framework (MOF) catalysts to evaluate their impact on activity for the ORR. A series of FePhen@MOF catalysts have been synthesized with varying [Fe] to investigate the effect on electrochemical and electrocatalytic properties. The magnitude of the FeII/III redox couple and the electrochemical surface area are analyzed to determine if there is a correlation between [Fe] and the ORR onset potential and/or the relative number of active sites.

  9. Active Interrogation for Spent Fuel

    Energy Technology Data Exchange (ETDEWEB)

    Swinhoe, Martyn Thomas [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Dougan, Arden [National Nuclear Security Administration (NNSA), Washington, DC (United States)

    2015-11-05

    The DDA instrument for nuclear safeguards is a fast, non-destructive assay, active neutron interrogation technique using an external 14 MeV DT neutron generator for characterization and verification of spent nuclear fuel assemblies.

  10. Active Interrogation for Spent Fuel

    Energy Technology Data Exchange (ETDEWEB)

    Swinhoe, Martyn Thomas [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Dougan, Arden [National Nuclear Security Administration (NNSA), Washington, DC (United States)

    2015-11-05

    The DDA instrument for nuclear safeguards is a fast, non-destructive assay, active neutron interrogation technique using an external 14 MeV DT neutron generator for characterization and verification of spent nuclear fuel assemblies.

  11. Ceramic Microchannel Development for Compact Fuel Processors of Hydrocarbon Fuels

    Science.gov (United States)

    Bae, J.-M.; Ahmed, S.; Kumar, R.; Doss, E.

    Fuel processing is a bridging technology for faster commercialization of fuel cell system under lack of hydrogen infrastructures. Argonne national laboratory has been developing fuel processing technologies for fuel cell based electric power. We have reported the development of novel catalysts that are active and selective for hydrocarbon reforming reactions. It has been realized, however, that with pellet or conventional honeycomb catalysts, the reforming process is mass transport limited. This paper reports the development of catalyst structures with microchannels that are able to reduce the diffusion resistance and thereby achieve the same production rate within a smaller reactor bed. These microchannel reforming catalysts were prepared and tested with natural gas and gasoline-type fuels in a microreactor (1-cm dia.) at space velocities of up to 250,000 per hour. These catalysts have also been used in engineering-scale reactors (10 kWe, 7-cm dia.) with similar product qualities. Compared to pellet catalysts, the microchannel catalysts enable a nearly 5-fold reduction in catalyst weight and volume.

  12. Fuel Cell/Reformers Technology Development

    Science.gov (United States)

    2004-01-01

    NASA Glenn Research Center is interested in developing Solid Oxide Fuel Cell for use in aerospace applications. Solid oxide fuel cell requires hydrogen rich feed stream by converting commercial aviation jet fuel in a fuel processing process. The grantee's primary research activities center on designing and constructing a test facility for evaluating injector concepts to provide optimum feeds to fuel processor; collecting and analyzing literature information on fuel processing and desulfurization technologies; establishing industry and academic contacts in related areas; providing technical support to in-house SOFC-based system studies. Fuel processing is a chemical reaction process that requires efficient delivery of reactants to reactor beds for optimum performance, i.e., high conversion efficiency and maximum hydrogen production, and reliable continuous operation. Feed delivery and vaporization quality can be improved by applying NASA's expertise in combustor injector design. A 10 KWe injector rig has been designed, procured, and constructed to provide a tool to employ laser diagnostic capability to evaluate various injector concepts for fuel processing reactor feed delivery application. This injector rig facility is now undergoing mechanical and system check-out with an anticipated actual operation in July 2004. Multiple injector concepts including impinging jet, venturi mixing, discrete jet, will be tested and evaluated with actual fuel mixture compatible with reforming catalyst requirement. Research activities from September 2002 to the closing of this collaborative agreement have been in the following areas: compiling literature information on jet fuel reforming; conducting autothermal reforming catalyst screening; establishing contacts with other government agencies for collaborative research in jet fuel reforming and desulfurization; providing process design basis for the build-up of injector rig facility and individual injector design.

  13. The DUPIC fuel development program in KAERI

    Energy Technology Data Exchange (ETDEWEB)

    Yang, M. S.; Park, H. S. [Korea Atomic Energy Research Institute, Taejon (Korea, Republic of)

    1997-07-01

    This study describes the DUPIC fuel development program in KAERI as follows; Burning spent PWR fuel again in CANDU by DUPIC, Compatibility with existing CANDU system, Feasibility of DUPIC fuel fabrication, Waste reduction, Safeguard ability, Economics of DUPIC fuel cycle, The DUPIC fuel development program, and International prospective. 5 refs., 10 figs.

  14. Development of PEM fuel cell technology at international fuel cells

    Energy Technology Data Exchange (ETDEWEB)

    Wheeler, D.J.

    1996-04-01

    The PEM technology has not developed to the level of phosphoric acid fuel cells. Several factors have held the technology development back such as high membrane cost, sensitivity of PEM fuel cells to low level of carbon monoxide impurities, the requirement to maintain full humidification of the cell, and the need to pressurize the fuel cell in order to achieve the performance targets. International Fuel Cells has identified a hydrogen fueled PEM fuel cell concept that leverages recent research advances to overcome major economic and technical obstacles.

  15. Automotive Fuel Processor Development and Demonstration with Fuel Cell Systems

    Energy Technology Data Exchange (ETDEWEB)

    Nuvera Fuel Cells

    2005-04-15

    The potential for fuel cell systems to improve energy efficiency and reduce emissions over conventional power systems has generated significant interest in fuel cell technologies. While fuel cells are being investigated for use in many applications such as stationary power generation and small portable devices, transportation applications present some unique challenges for fuel cell technology. Due to their lower operating temperature and non-brittle materials, most transportation work is focusing on fuel cells using proton exchange membrane (PEM) technology. Since PEM fuel cells are fueled by hydrogen, major obstacles to their widespread use are the lack of an available hydrogen fueling infrastructure and hydrogen's relatively low energy storage density, which leads to a much lower driving range than conventional vehicles. One potential solution to the hydrogen infrastructure and storage density issues is to convert a conventional fuel such as gasoline into hydrogen onboard the vehicle using a fuel processor. Figure 2 shows that gasoline stores roughly 7 times more energy per volume than pressurized hydrogen gas at 700 bar and 4 times more than liquid hydrogen. If integrated properly, the fuel processor/fuel cell system would also be more efficient than traditional engines and would give a fuel economy benefit while hydrogen storage and distribution issues are being investigated. Widespread implementation of fuel processor/fuel cell systems requires improvements in several aspects of the technology, including size, startup time, transient response time, and cost. In addition, the ability to operate on a number of hydrocarbon fuels that are available through the existing infrastructure is a key enabler for commercializing these systems. In this program, Nuvera Fuel Cells collaborated with the Department of Energy (DOE) to develop efficient, low-emission, multi-fuel processors for transportation applications. Nuvera's focus was on (1) developing fuel

  16. Development of Metallic Fuels for Actinide Transmutation

    Energy Technology Data Exchange (ETDEWEB)

    Hayes, Steven Lowe [Idaho National Laboratory; Fielding, Randall Sidney [Idaho National Laboratory; Benson, Michael Timothy [Idaho National Laboratory; Chichester, Heather Jean MacLean [Idaho National Laboratory; Carmack, William Jonathan [Idaho National Laboratory

    2015-09-01

    Research and development activities on metallic fuels are focused on their potential use for actinide transmutation in future sodium fast reactors. As part of this application, there is also a need for a near zero-loss fabrication process and a desire to demonstrate a multifold increase in burnup potential. The incorporation of Am and Np into the traditional U-20Pu-10Zr metallic fuel alloy was demonstrated in the US during the Integral Fast Reactor Program of the 1980’s and early 1990’s. However, the conventional counter gravity injection casting method performed under vacuum, previously used to fabricate these metallic fuel alloys, was not optimized for mitigating loss of the volatile Am constituent in the casting charge; as a result, approximately 40% of the Am casting charge failed to be incorporated into the as-cast fuel alloys. Fabrication development efforts of the past few years have pursued an optimized bottom-pour casting method to increase utilization of the melted charge to near 100%, and a differential pressure casting approach, performed under an argon overpressure, has been demonstrated to result in essentially no loss of Am due to volatilization during fabrication. In short, a path toward zero-loss fabrication of metallic fuels including minor actinides has been shown to be feasible. Irradiation testing of advanced metallic fuel alloys in the Advanced Test Reactor (ATR) has been underway since 2003. Testing in the ATR is performed inside of cadmium-shrouded positions to remove >99% of the thermal flux incident on the test fuels, resulting in an epi-thermal driven fuel test that is free from gross flux depression and producing an essentially prototypic radial temperature profile inside the fuel rodlets. To date, three irradiation test series (AFC-1,2,3) have been completed. Over 20 different metallic fuel alloys have been tested to burnups as high as 30% with constituent compositions of Pu up to 30%, Am up to 12%, Np up to 10%, and Zr between 10

  17. CANDU RU fuel manufacturing basic technology development and advanced fuel verification tests

    Energy Technology Data Exchange (ETDEWEB)

    Chung, Chang Hwan; Chang, S.K.; Hong, S.D. [and others

    1999-04-01

    A PHWR advanced fuel named the CANFLEX fuel has been developed through a KAERI/AECL joint Program. The KAERI made fuel bundle was tested at the KAERI Hot Test Loop for the performance verification of the bundle design. The major test activities were the fuel bundle cross-flow test, the endurance fretting/vibration test, the freon CHF test, and the fuel bundle heat-up test. KAERI also has developing a more advanced PHWR fuel, the CANFLEX-RU fuel, using recovered uranium to extend fuel burn-up in the CANDU reactors. For the purpose of proving safety of the RU handling techniques and appraising feasibility of the CANFLEX-RU fuel fabrication in near future, a physical, chemical and radiological characterization of the RU powder and pellets was performed. (author). 54 refs., 46 tabs., 62 figs.

  18. Development of spent fuel remote handling technology

    Energy Technology Data Exchange (ETDEWEB)

    Yoon, Ji Sup; Park, B. S.; Park, Y. S.; Oh, S. C.; Kim, S. H.; Cho, M. W.; Hong, D. H

    1997-12-01

    Since the nation`s policy on spent fuel management is not finalized, the technical items commonly required for safe management and recycling of spent fuel - remote technologies of transportation, inspection, maintenance, and disassembly of spent fuel - are selected and pursued. In this regards, the following R and D activities are carried out : collision free transportation of spent fuel assembly, mechanical disassembly of spent nuclear fuel and graphical simulation of fuel handling / disassembly process. (author). 36 refs., 16 tabs., 77 figs

  19. Alternative Fuels and Sustainable Development

    DEFF Research Database (Denmark)

    Jørgensen, Kaj; Nielsen, Lars Henrik

    1996-01-01

    The main report of the project on Transportation Fuels based on Renewable Energy. The report contains a review of potential technologies for electric, hybrid and hydrogen propulsion in the Danish transport sector, including an assessment of their development status. In addition, the energy...

  20. Alternative Fuels and Sustainable Development

    DEFF Research Database (Denmark)

    Jørgensen, Kaj; Nielsen, Lars Henrik

    1996-01-01

    The main report of the project on Transportation Fuels based on Renewable Energy. The report contains a review of potential technologies for electric, hybrid and hydrogen propulsion in the Danish transport sector, including an assessment of their development status. In addition, the energy...... and environmental effects of introduction of these technologies are studied....

  1. Development of alkaline fuel cells.

    Energy Technology Data Exchange (ETDEWEB)

    Hibbs, Michael R.; Jenkins, Janelle E.; Alam, Todd Michael; Janarthanan, Rajeswari; Horan, James L.; Caire, Benjamin R.; Ziegler, Zachary C.; Herring, Andrew M.; Yang, Yuan; Zuo, Xiaobing; Robson, Michael H.; Artyushkova, Kateryna; Patterson, Wendy; Atanassov, Plamen Borissov

    2013-09-01

    This project focuses on the development and demonstration of anion exchange membrane (AEM) fuel cells for portable power applications. Novel polymeric anion exchange membranes and ionomers with high chemical stabilities were prepared characterized by researchers at Sandia National Laboratories. Durable, non-precious metal catalysts were prepared by Dr. Plamen Atanassovs research group at the University of New Mexico by utilizing an aerosol-based process to prepare templated nano-structures. Dr. Andy Herrings group at the Colorado School of Mines combined all of these materials to fabricate and test membrane electrode assemblies for single cell testing in a methanol-fueled alkaline system. The highest power density achieved in this study was 54 mW/cm2 which was 90% of the project target and the highest reported power density for a direct methanol alkaline fuel cell.

  2. Advanced research reactor fuel development

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Chang Kyu; Pak, H. D.; Kim, K. H. [and others

    2000-05-01

    The fabrication technology of the U{sub 3}Si fuel dispersed in aluminum for the localization of HANARO driver fuel has been launches. The increase of production yield of LEU metal, the establishment of measurement method of homogeneity, and electron beam welding process were performed. Irradiation test under normal operation condition, had been carried out and any clues of the fuel assembly breakdown was not detected. The 2nd test fuel assembly has been irradiated at HANARO reactor since 17th June 1999. The quality assurance system has been re-established and the eddy current test technique has been developed. The irradiation test for U{sub 3}Si{sub 2} dispersed fuels at HANARO reactor has been carried out in order to compare the in-pile performance of between the two types of U{sub 3}Si{sub 2} fuels, prepared by both the atomization and comminution processes. KAERI has also conducted all safety-related works such as the design and the fabrication of irradiation rig, the analysis of irradiation behavior, thermal hydraulic characteristics, stress analysis for irradiation rig, and thermal analysis fuel plate, for the mini-plate prepared by international research cooperation being irradiated safely at HANARO. Pressure drop test, vibration test and endurance test were performed. The characterization on powders of U-(5.4 {approx} 10 wt%) Mo alloy depending on Mo content prepared by rotating disk centrifugal atomization process was carried out in order to investigate the phase stability of the atomized U-Mo alloy system. The {gamma}-U phase stability and the thermal compatibility of atomized U-16at.%Mo and U-14at.%Mo-2at.%X(: Ru, Os) dispersion fuel meats at an elevated temperature have been investigated. The volume increases of U-Mo compatibility specimens were almost the same as or smaller than those of U{sub 3}Si{sub 2}. However the atomized alloy fuel exhibited a better irradiation performance than the comminuted alloy. The RERTR-3 irradiation test of nano

  3. Current Status of Japanese Research and Development Activity and Program Plan on Failed Fuel Detection and Location Systems for LMFBR

    OpenAIRE

    1981-01-01

    Progress of research and development on failed fuel detection and location (FFDL) implemented since 1968 in Japan is summarized and reviewed from the viewpoint of availability to reflect to the design and operation of JOYO and MONJU. These include basic experiments of fission product behavior, component development and testing, feasibility study of detection system response, and comparison of several kinds of location methods. The discussion will extend to the role of FFDL in the other survei...

  4. Development of dynamic simulation code for fuel cycle fusion reactor

    Energy Technology Data Exchange (ETDEWEB)

    Aoki, Isao; Seki, Yasushi [Department of Fusion Engineering Research, Naka Fusion Research Establishment, Japan Atomic Energy Research Institute, Naka, Ibaraki (Japan); Sasaki, Makoto; Shintani, Kiyonori; Kim, Yeong-Chan

    1999-02-01

    A dynamic simulation code for fuel cycle of a fusion experimental reactor has been developed. The code follows the fuel inventory change with time in the plasma chamber and the fuel cycle system during 2 days pulse operation cycles. The time dependence of the fuel inventory distribution is evaluated considering the fuel burn and exhaust in the plasma chamber, purification and supply functions. For each subsystem of the plasma chamber and the fuel cycle system, the fuel inventory equation is written based on the equation of state considering the fuel burn and the function of exhaust, purification, and supply. The processing constants of subsystem for steady states were taken from the values in the ITER Conceptual Design Activity (CDA) report. Using this code, the time dependence of the fuel supply and inventory depending on the burn state and subsystem processing functions are shown. (author)

  5. Dry process fuel performance technology development

    Energy Technology Data Exchange (ETDEWEB)

    Kang, Kweon Ho; Kim, K. W.; Kim, B. K. (and others)

    2006-06-15

    The objective of the project is to establish the performance evaluation system of DUPIC fuel during the Phase III R and D. In order to fulfil this objectives, property model development of DUPIC fuel and irradiation test was carried out in Hanaro using the instrumented rig. Also, the analysis on the in-reactor behavior analysis of DUPIC fuel, out-pile test using simulated DUPIC fuel as well as performance and integrity assessment in a commercial reactor were performed during this Phase. The R and D results of the Phase III are summarized as follows: Fabrication process establishment of simulated DUPIC fuel for property measurement, Property model development for the DUPIC fuel, Performance evaluation of DUPIC fuel via irradiation test in Hanaro, Post irradiation examination of irradiated fuel and performance analysis, Development of DUPIC fuel performance code (KAOS)

  6. Development of internal reforming carbonate fuel cell stack technology

    Energy Technology Data Exchange (ETDEWEB)

    Farooque, M.

    1990-10-01

    Activities under this contract focused on the development of a coal-fueled carbonate fuel cell system design and the stack technology consistent with the system design. The overall contract effort was divided into three phases. The first phase, completed in January 1988, provided carbonate fuel cell component scale-up from the 1ft{sup 2} size to the commercial 4ft{sup 2} size. The second phase of the program provided the coal-fueled carbonate fuel cell system (CGCFC) conceptual design and carried out initial research and development needs of the CGCFC system. The final phase of the program emphasized stack height scale-up and improvement of stack life. The results of the second and third phases are included in this report. Program activities under Phase 2 and 3 were designed to address several key development areas to prepare the carbonate fuel cell system, particularly the coal-fueled CFC power plant, for commercialization in late 1990's. The issues addressed include: Coal-Gas Related Considerations; Cell and Stack Technology Improvement; Carbonate Fuel Cell Stack Design Development; Stack Tests for Design Verification; Full-Size Stack Design; Test Facility Development; Carbonate Fuel Cell Stack Cost Assessment; and Coal-Fueled Carbonate Fuel Cell System Design. All the major program objectives in each of the topical areas were successfully achieved. This report is organized along the above-mentioned topical areas. Each topical area has been processed separately for inclusion on the data base.

  7. Development of portable fuel cells

    Energy Technology Data Exchange (ETDEWEB)

    Nakatou, K.; Sumi, S.; Nishizawa, N. [Sanyo Electric Co., Ltd., Osaka (Japan)

    1996-12-31

    Sanyo Electric has been concentrating on developing a marketable portable fuel cell using phosphoric acid fuel cells (PAFC). Due to the fact that this power source uses PAFC that operate at low temperature around 100{degrees} C, they are easier to handle compared to conventional fuel cells that operate at around 200{degrees} C , they can also be expected to provide extended reliable operation because corrosion of the electrode material and deterioration of the electrode catalyst are almost completely nonexistent. This power source is meant to be used independently and stored at room temperature. When it is started up, it generates electricity itself using its internal load to raise the temperature. As a result, the phosphoric acid (the electolyte) absorbs the reaction water when the temperature starts to be raised (around room temperature). At the same time the concentration and volume of the phosphoric acid changes, which may adversely affect the life time of the cell. We have studied means for starting, operating PAFC stack using methods that can simply evaluate changes in the concentration of the electrolyte in the stack with the aim of improving and extending cell life and report on them in this paper.

  8. Interim report spent nuclear fuel retrieval system fuel handling development testing

    Energy Technology Data Exchange (ETDEWEB)

    Ketner, G.L.; Meeuwsen, P.V.; Potter, J.D.; Smalley, J.T.; Baker, C.P.; Jaquish, W.R.

    1997-06-01

    Fuel handling development testing was performed in support of the Fuel Retrieval System (FRS) Sub-Project at the Hanford Site. The project will retrieve spent nuclear fuel, clean and remove fuel from canisters, repackage fuel into baskets, and load fuel into a multi-canister overpack (MCO) for vacuum drying and interim dry storage. The FRS is required to retrieve basin fuel canisters, clean fuel elements sufficiently of uranium corrosion products (or sludge), empty fuel from canisters, sort debris and scrap from whole elements, and repackage fuel in baskets in preparation for MCO loading. The purpose of fuel handling development testing was to examine the systems ability to accomplish mission activities, optimization of equipment layouts for initial process definition, identification of special needs/tools, verification of required design changes to support performance specification development, and validation of estimated activity times/throughput. The test program was set up to accomplish this purpose through cold development testing using simulated and prototype equipment; cold demonstration testing using vendor expertise and systems; and graphical computer modeling to confirm feasibility and throughput. To test the fuel handling process, a test mockup that represented the process table was fabricated and installed. The test mockup included a Schilling HV series manipulator that was prototypic of the Schilling Hydra manipulator. The process table mockup included the tipping station, sorting area, disassembly and inspection zones, fuel staging areas, and basket loading stations. The test results clearly indicate that the Schilling Hydra arm cannot effectively perform the fuel handling tasks required unless it is attached to some device that can impart vertical translation, azimuth rotation, and X-Y translation. Other test results indicate the importance of camera locations and capabilities, and of the jaw and end effector tool design. 5 refs., 35 figs., 3 tabs.

  9. Enhanced Accident Tolerant LWR Fuels: Metrics Development

    Energy Technology Data Exchange (ETDEWEB)

    Shannon Bragg-Sitton; Lori Braase; Rose Montgomery; Chris Stanek; Robert Montgomery; Lance Snead; Larry Ott; Mike Billone

    2013-09-01

    The Department of Energy (DOE) Fuel Cycle Research and Development (FCRD) Advanced Fuels Campaign (AFC) is conducting research and development on enhanced Accident Tolerant Fuels (ATF) for light water reactors (LWRs). This mission emphasizes the development of novel fuel and cladding concepts to replace the current zirconium alloy-uranium dioxide (UO2) fuel system. The overall mission of the ATF research is to develop advanced fuels/cladding with improved performance, reliability and safety characteristics during normal operations and accident conditions, while minimizing waste generation. The initial effort will focus on implementation in operating reactors or reactors with design certifications. To initiate the development of quantitative metrics for ATR, a LWR Enhanced Accident Tolerant Fuels Metrics Development Workshop was held in October 2012 in Germantown, MD. This paper summarizes the outcome of that workshop and the current status of metrics development for LWR ATF.

  10. LIQUID HYDROCARBON FUEL CELL DEVELOPMENT.

    Science.gov (United States)

    A compound anode consists of a reforming catalyst bed in direct contact with a palladium-silver fuel cell anode. The objective of this study was to...prove the feasibility of operating a compound anode fuel cell on a liquid hydrocarbon and to define the important parameters that influence cell...performance. Both reformer and fuel cell tests were conducted with various liquid hydrocarbon fuels. Included in this report is a description of the

  11. Fuel cell transit bus development & commercialization programs at Gerogetown University

    Energy Technology Data Exchange (ETDEWEB)

    Wimmer, R.; Larkins, J.; Romano, S. [Georgetown Univ., Washington, DC (United States)

    1996-12-31

    Fourteen years ago, Georgetown University (GU) perceived the need for a clean, efficient power systems for transportation that could operate on non-petroleum based fuels. The transit bus application was selected to begin system development. GU recognized the range and recharge constraints of a pure battery powered transit bus. A Fuel Cell power system would circumvent these limitations and, with an on board reformer, accommodate liquid fuel for rapid refueling. Feasibility studies for Fuel Cell power systems for transit buses were conducted with the Los Alamos National Laboratory in 1983. Successful results of this investigation resulted in the DOT/DOE Fuel Cell transit bus development program. The first task was to prove that small Fuel Cell power plants were possible. This was achieved with the Phase I development of two 25 kW Phosphoric Acid Fuel Cell (PAFC) brassboard systems. A liquid cooled version was selected for the Phase II activity in which three 30-foot Fuel Cell powered Test Bed Buses (TBBs) were fabricated. The first of these TBBs was delivered in the spring of 1994. All three of these development vehicles are now in Phase III of the program to conduct testing and evaluation, is conducting operational testing of the buses. The test will involve two fuel cell-operated buses; one with a proton exchange fuel cell and the other with a phosphoric acid fuel cell.

  12. Hydrogen Fuel Cell development in Columbia (SC)

    Energy Technology Data Exchange (ETDEWEB)

    Reifsnider, Kenneth [Univ. of South Carolina, Columbia, SC (United States); Chen, Fanglin [Univ. of South Carolina, Columbia, SC (United States); Popov, Branko [Univ. of South Carolina, Columbia, SC (United States); Chao, Yuh [Univ. of South Carolina, Columbia, SC (United States); Xue, Xingjian [Univ. of South Carolina, Columbia, SC (United States)

    2012-09-15

    This is an update to the final report filed after the extension of this program to May of 2011. The activities of the present program contributed to the goals and objectives of the Fuel Cell element of the Hydrogen, Fuel Cells and Infrastructure Technologies Program of the Department of Energy through five sub-projects. Three of these projects have focused on PEM cells, addressing the creation of carbon-based metal-free catalysts, the development of durable seals, and an effort to understand contaminant adsorption/reaction/transport/performance relationships at low contaminant levels in PEM cells. Two programs addressed barriers in SOFCs; an effort to create a new symmetrical and direct hydrocarbon fuel SOFC designs with greatly increased durability, efficiency, and ease of manufacturing, and an effort to create a multiphysics engineering durability model based on electrochemical impedance spectroscopy interpretations that associate the micro-details of how a fuel cell is made and their history of (individual) use with specific prognosis for long term performance, resulting in attendant reductions in design, manufacturing, and maintenance costs and increases in reliability and durability.

  13. Hydrogen Fuel Cell Development in Columbia (SC)

    Energy Technology Data Exchange (ETDEWEB)

    Reifsnider, Kenneth

    2011-07-31

    This is an update to the final report filed after the extension of this program to May of 2011. The activities of the present program contributed to the goals and objectives of the Fuel Cell element of the Hydrogen, Fuel Cells and Infrastructure Technologies Program of the Department of Energy through five sub-projects. Three of these projects have focused on PEM cells, addressing the creation of carbon-based metal-free catalysts, the development of durable seals, and an effort to understand contaminant adsorption/reaction/transport/performance relationships at low contaminant levels in PEM cells. Two programs addressed barriers in SOFCs; an effort to create a new symmetrical and direct hydrocarbon fuel SOFC designs with greatly increased durability, efficiency, and ease of manufacturing, and an effort to create a multiphysics engineering durability model based on electrochemical impedance spectroscopy interpretations that associate the micro-details of how a fuel cell is made and their history of (individual) use with specific prognosis for long term performance, resulting in attendant reductions in design, manufacturing, and maintenance costs and increases in reliability and durability.

  14. Fuel cell development for transportation: Catalyst development

    Energy Technology Data Exchange (ETDEWEB)

    Doddapaneni, N. [Sandia National Lab., Albuquerque, NM (United States)

    1996-04-01

    Fuel cells are being considered as alternate power sources for transportation and stationary applications. With proton exchange membrane (PEM) fuel cells the fuel crossover to cathodes causes severe thermal management and cell voltage drop due to oxidation of fuel at the platinized cathodes. The main goal of this project was to design, synthesize, and evaluate stable and inexpensive transition metal macrocyclic catalysts for the reduction of oxygen and be electrochemically inert towards anode fuels such as hydrogen and methanol.

  15. Neutronic experiment planning for the Fuels Refabrication and Development Program

    Energy Technology Data Exchange (ETDEWEB)

    Gore, B.F.; NcNeese, J.P.; Zimmerman, M.G.; Konzek, G.J.

    1979-12-01

    A program of experiments using /sup 233/UO/sub 2/ - ThO/sub 2/ fuel was proposed to provide new and improved neutronic and criticality data for thorium based nuclear fuels, in order to support the licensing of /sup 233/UO/sub 2/ - ThO/sub 2/ fuels in LWR cores. This would support the goal to develop technology for proliferation resistant fuel cycles to a point where fuel cycle choice is not limited by refabrication technology. The proposed experimental program is described in this document, along with initial planning and fuel acquisition activities undertaken during FY 1979. The program was terminated following notification that the DOE-sponsored denatured LWR Fuel Program which the experiments supported was to be discontinued.

  16. History of fast reactor fuel development

    Energy Technology Data Exchange (ETDEWEB)

    Kittel, J.H. (Argonne National Lab., IL (United States)); Frost, B.R.T. (Argonne National Lab., IL (United States)); Mustelier, J.P. (COGEMA, Velizy-Villacoublay (France)); Bagley, K.Q. (AEA Reactor Services, Risley (United Kingdom)); Crittenden, G.C. (AEA Reactor Services, Dounreay (United Kingdom)); Dievoet, J. van (Belgonucleaire, Brussels (Belgium))

    1993-09-01

    The first fast breeder eactors, constructed in the 1945-1960 time period, used metallic fuels composed of uranium, plutonium, or their alloys. They were chosen because most existing reactor operating experience had been obtained on metallic fuels and because they provided the highest breeding ratios. Difficulties in obtaining adequate dimensional stability in metallic fuel elements under conditions of high fuel burnup led in the 1960s to the virtual worldwide choice of ceramic fuels. Although ceramic fuels provide lower breeding performance, this objective is no longer an important consideration in most national programs. Mixed uranium and plutonium dioxide became the ceramic fuel that has received the widest use. The more advanced ceramic fuels, mixed uranium and plutonium carbides and nitrides, continue under development. More recently, metal fuel elements of improved design have joined ceramic fuels in achieving goal burnups of 15 to 20 percent. Low-swelling fuel cladding alloys have also been continuously developed to deal with the unexpected problem of void formation in stainless steels subjected to fast neutron irradiation, a phenomenon first observed in the 1960s. (orig.)

  17. Nuclear Fuel Design Technology Development for the Future Fuel

    Energy Technology Data Exchange (ETDEWEB)

    Koo, Yang Hyun; Lee, Byung Ho; Cheon, Jin Sik; Oh, Je Yong; Yim, Jeong Sik; Sohn, Dong Seong; Lee, Byung Uk; Ko, Han Suk; So, Dong Sup; Koo, Dae Seo

    2006-04-15

    The test MOX fuels have been irradiated in the Halden reactor, and their burnup attained 40 GWd/t as of October 2005. The fuel temperature and internal pressure were measured by the sensors installed in the fuels and test rig. The COSMOS code, which was developed by KAERI, well predicted in-reactor behavior of MOX fuel. The COSMOS code was verified by OECD-NEA benchmarks, and the result confirmed the superiority of COSMOS code. MOX in-pile database (IFA-629.3, IFA-610.2 and 4) in Halden was also used for the verification of code. The COSMOS code was improved by introducing Graphic User Interface (GUI) and batch mode. The PCMI analysis module was developed and introduced by the new fission gas behavior model. The irradiation test performed under the arbitrary rod internal pressure could also be analyzed with the COSMOS code. Several presentations were made for the preparation to transfer MOX fuel performance analysis code to the industry, and the transfer of COSMOS code to the industry is being discussed. The user manual and COSMOS program (executive file) were provided for the industry to test the performance of COSMOS code. To envisage the direction of research, the MOX fuel research trend of foreign countries, specially focused on USA's GENP policy, was analyzed.

  18. Fuel Fabrication Capability Research and Development Plan

    Energy Technology Data Exchange (ETDEWEB)

    Senor, David J.; Burkes, Douglas

    2014-04-17

    The purpose of this document is to provide a comprehensive review of the mission of the Fuel Fabrication Capability (FFC) within the Global Threat Reduction Initiative Convert Program, along with research and development (R&D) needs that have been identified as necessary to ensuring mission success. The design and fabrication of successful nuclear fuels must be closely linked endeavors. Therefore, the overriding motivation behind the FFC R&D program described in this plan is to foster closer integration between fuel design and fabrication to reduce programmatic risk. These motivating factors are all interrelated, and progress addressing one will aid understanding of the others. The FFC R&D needs fall into two principal categories, 1) baseline process optimization, to refine the existing fabrication technologies, and 2) manufacturing process alternatives, to evaluate new fabrication technologies that could provide improvements in quality, repeatability, material utilization, or cost. The FFC R&D Plan examines efforts currently under way in regard to coupon, foil, plate, and fuel element manufacturing, and provides recommendations for a number of R&D topics that are of high priority but not currently funded (i.e., knowledge gaps). The plan ties all FFC R&D efforts into a unified vision that supports the overall Convert Program schedule in general, and the fabrication schedule leading up to the MP-1 and FSP-1 irradiation experiments specifically. The fabrication technology decision gates and down-selection logic and schedules are tied to the schedule for fabricating the MP-1 fuel plates, which will provide the necessary data to make a final fuel fabrication process down-selection. Because of the short turnaround between MP-1 and the follow-on FSP-1 and MP-2 experiments, the suite of specimen types that will be available for MP-1 will be the same as those available for FSP-1 and MP-2. Therefore, the only opportunity to explore parameter space and alternative processing

  19. Development of a lightweight fuel cell vehicle

    Science.gov (United States)

    Hwang, J. J.; Wang, D. Y.; Shih, N. C.

    This paper described the development of a fuel cell system and its integration into the lightweight vehicle known as the Mingdao hydrogen vehicle (MHV). The fuel cell system consists of a 5-kW proton exchange membrane fuel cell (PEMFC), a microcontroller and other supported components like a compressed hydrogen cylinder, blower, solenoid valve, pressure regulator, water pump, heat exchanger and sensors. The fuel cell not only propels the vehicle but also powers the supporting components. The MHV performs satisfactorily over a hundred-kilometer drive thus validating the concept of a fuel cell powered zero-emission vehicle. Measurements further show that the fuel cell system has an efficiency of over 30% at the power consumption for vehicle cruise, which is higher than that of a typical internal combustion engine. Tests to improve performance such as speed enhancement, acceleration and fuel efficiency will be conducted in the future work. Such tests will consist of hybridizing with a battery pack.

  20. Status of the atomized uranium silicide fuel development at KAERI

    Energy Technology Data Exchange (ETDEWEB)

    Kim, C.K.; Kim, K.H.; Park, H.D.; Kuk, I.H. [Korea Atomic Energy Research Institute, Taejon (Korea, Republic of)

    1997-08-01

    While developing KMRR fuel fabrication technology an atomizing technique has been applied in order to eliminate the difficulties relating to the tough property of U{sub 3}Si and to take advantage of the rapid solidification effect of atomization. The comparison between the conventionally comminuted powder dispersion fuel and the atomized powder dispersion fuel has been made. As the result, the processes, uranium silicide powdering and heat treatment for U{sub 3}Si transformation, become simplified. The workability, the thermal conductivity and the thermal compatibility of fuel meat have been investigated and found to be improved due to the spherical shape of atomized powder. In this presentation the overall developments of atomized U{sub 3}Si dispersion fuel and the planned activities for applying the atomizing technique to the real fuel fabrication are described.

  1. Development of Spent Fuel Examination Technology

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Ho Dong; Park, K. J.; Shin, H. S. (and others)

    2007-04-15

    For the official operation of ACPF Facility Attachment based on facility declared DIQ was issued by IAEA and officialized upon ROK government approval. This procedure gives an essential ground to negotiate Joint Determination between governments of ROK and US. For ACPF process material accountability a neutron coincidence counting system was developed and calibrated with Cf-252 source. Its performance test demonstrated that over-all counting efficiency was about 21% with random error, 1.5% against calibration source, which found to be satisfactory to the expected design specification. A calibration curve derived by MCNP code with relationship between ASNC doublet counts vs. neutron activity of Cm-244 showed calibration constant to be 2.78x10E5 counts/s.g which would be used for initial ACP hot operation test. Nuclear material transportation and temporary storage system was established for active demonstration of advanced spent fuel management process line and would be directly applied to the effective management of wastes arising from active demonstration and would later contribute as a base data to development of inter hot-cell movement system in pyro-processing line. In addition, an optimal spent fuel for the ACP demonstration was selected and a computer code was developed as a tool to estimate the expected source term at each key measurement point of ACP.

  2. Development of metallic fuel fabrication

    Energy Technology Data Exchange (ETDEWEB)

    Kang, Young Ho; Lee, Chong Yak; Lee, Myung Ho and others

    1999-03-01

    With the vacuum melting and casting of the U-10wt%Zr alloy which is metallic fuel for liquid metal fast breeder reactor, we studied the microstructure of the alloy and the parameters of the melting and casting for the fuel rods. Internal defects of the U-10wt%Zr fuel by gravity casting, were inspected by non-destructive test. U-10wt%Zr alloy has been prepared for the thermal stability test in order to estimate the decomposition of the lamellar structure with relation to swelling under irradiation condition. (author)

  3. Update On Monolithic Fuel Fabrication Development

    Energy Technology Data Exchange (ETDEWEB)

    C. R Clark; J. M. Wight; G. C. Knighton; G. A. Moore; J. F. Jue

    2005-11-01

    Efforts to develop a viable monolithic research reactor fuel plate have continued at Idaho National Laboratory. These efforts have concentrated on both fabrication process refinement and scale-up to produce full sized fuel plates. Advancements have been made in the production of U-Mo foil including full sized foils. Progress has also been made in the friction stir welding and transient liquid phase bonding fabrication processes resulting in better bonding, more stable processes and the ability to fabricate larger fuel plates.

  4. DUPIC nuclear fuel manufacturing and process technology development

    Energy Technology Data Exchange (ETDEWEB)

    Yang, Myung Seung; Park, J. J.; Lee, J. W. [and others

    2000-05-01

    In this study, DUPIC fuel fabrication technology and the active fuel laboratory were developed for the study of spent nuclear fuel. A new nuclear fuel using highly radioactive nuclear materials can be studied at the active fuel laboratory. Detailed DUPIC fuel fabrication process flow was developed considering the manufacturing flow, quality control process and material accountability. The equipment layout of about twenty DUPIC equipment at IMEF M6 hot cell was established for the minimization of the contamination during DUPIC processes. The characteristics of the SIMFUEL powder and pellets was studied in terms of milling conditions. The characteristics of DUPIC powder and pellet was studied by using 1 kg of spent PWR fuel at PIEF nr.9405 hot cell. The results were used as reference process conditions for following DUPIC fuel fabrication at IMEF M6. Based on the reference fabrication process conditions, the main DUPIC pellet fabrication campaign has been started at IMEF M6 using 2 kg of spent PWR fuel since 2000 January. As of March 2000, about thirty DUPIC pellets were successfully fabricated.

  5. Overview of activities on CANDU fuel in Argentina

    Energy Technology Data Exchange (ETDEWEB)

    Alvarez, L.; Valesi, J., E-mail: lalvarez@cnea.gov.ar [National Commission on Atomic Energy, Fuel Engineering Department (Argentina)

    2013-07-01

    This paper gives an outline of activities on CANDU fuel in Argentina. It discusses the nuclear activities and electricity production in Argentina, evolution of the activities in fuel engineering, fuel fabrication, fuel performance at Embalse nuclear power plant and spent fuel storage options.

  6. Fuel Fabrication Capability Research and Development Plan

    Energy Technology Data Exchange (ETDEWEB)

    Senor, David J.; Burkes, Douglas

    2013-06-28

    The purpose of this document is to provide a comprehensive review of the mission of the Fuel Fabrication Capability (FFC) within the Global Threat Reduction Initiative (GTRI) Convert Program, along with research and development (R&D) needs that have been identified as necessary to ensuring mission success. The design and fabrication of successful nuclear fuels must be closely linked endeavors.

  7. Development of fuel and energy storage technologies

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-09-01

    Development of fuel cell power plants is intended of high-efficiency power generation using such fuels with less air pollution as natural gas, methanol and coal gas. The closest to commercialization is phosphoric acid fuel cells, and the high in efficiency and rich in fuel diversity is molten carbonate fuel cells. The development is intended to cover a wide scope from solid electrolyte fuel cells to solid polymer electrolyte fuel cells. For new battery power storage systems, development is focused on discrete battery energy storage technologies of fixed type and mobile type (such as electric vehicles). The ceramic gas turbine technology development is purposed for improving thermal efficiency and reducing pollutants. Small-scale gas turbines for cogeneration will also be developed. Development of superconduction power application technologies is intended to serve for efficient and stable power supply by dealing with capacity increase and increase in power distribution distance due to increase in power demand. In the operations to improve the spread and general promotion systems for electric vehicles, load leveling is expected by utilizing and storing nighttime electric power. Descriptions are given also on economical city systems which utilize wide-area energy. 30 figs., 7 tabs.

  8. THE MISSION AND ACCOMPLISHMENTS FROM DOE’S FUEL CYCLE RESEARCH AND DEVELOPMENT (FCRD) ADVANCED FUELS CAMPAIGN

    Energy Technology Data Exchange (ETDEWEB)

    J. Carmack; L. Braase; F. Goldner

    2015-09-01

    The mission of the Advanced Fuels Campaign (AFC) is to perform Research, Development, and Demonstration (RD&D) activities for advanced fuel forms (including cladding) to enhance the performance and safety of the nation’s current and future reactors, enhance proliferation resistance of nuclear fuel, effectively utilize nuclear energy resources, and address the longer-term waste management challenges. This includes development of a state of the art Research and Development (R&D) infrastructure to support the use of a “goal oriented science based approach.” AFC uses a “goal oriented, science based approach” aimed at a fundamental understanding of fuel and cladding fabrication methods and performance under irradiation, enabling the pursuit of multiple fuel forms for future fuel cycle options. This approach includes fundamental experiments, theory, and advanced modeling and simulation. One of the most challenging aspects of AFC is the management, integration, and coordination of major R&D activities across multiple organizations. AFC interfaces and collaborates with Fuel Cycle Technologies (FCT) campaigns, universities, industry, various DOE programs and laboratories, federal agencies (e.g., Nuclear Regulatory Commission [NRC]), and international organizations. Key challenges are the development of fuel technologies to enable major increases in fuel performance (safety, reliability, power and burnup) beyond current technologies, and development of characterization methods and predictive fuel performance models to enable more efficient development and licensing of advanced fuels. Challenged with the research and development of fuels for two different reactor technology platforms, AFC targeted transmutation fuel development and focused ceramic fuel development for Advanced LWR Fuels.

  9. Fuel element development committee: Annual report from the General Electric Company, Hanford

    Energy Technology Data Exchange (ETDEWEB)

    Lewis, M.; Minor, J.E.; Stringer, J.T.

    1964-08-14

    A summary of HAPO activities is given to include separate sections on the N-Reactor and other current production reactors. Specific programs and fuel performance for current production reactor fuels is discussed. Also, the production status, fuel performance, development program and process technology for N-Reactor fuels is presented.

  10. Deep-Burn Modular Helium Reactor Fuel Development Plan

    Energy Technology Data Exchange (ETDEWEB)

    McEachern, D

    2002-12-02

    the Design Data Needs to: (1) fabricate the coated particle fuel, (2) predict its performance in the reactor core, (3) predict the radionuclide release rates from the reactor core, and (4) predict the performance of spent fuel in a geological repository. The heart of this fuel development plan is Section 6, which describes the development activities proposed to satisfy the DDNs presented in Section 5. The development scope is divided into Fuel Process Development, Fuel Materials Development, Fission Product Transport, and Spent Fuel Disposal. Section 7 describes the facilities to be used. Generally, this program will utilize existing facilities. While some facilities will need to be modified, there is no requirement for major new facilities. Section 8 states the Quality Assurance requirements that will be applied to the development activities. Section 9 presents detailed costs organized by WBS and spread over time. Section 10 presents a list of the types of deliverables that will be prepared in each of the WBS elements. Four Appendices contain supplementary information on: (a) design data needs, (b) the interface with the separations plant, (c) the detailed development schedule, and (d) the detailed cost estimate.

  11. Development of a modified independent parallel reactions kinetic model and comparison with the distributed activation energy model for the pyrolysis of a wide variety of biomass fuels.

    Science.gov (United States)

    Sfakiotakis, Stelios; Vamvuka, Despina

    2015-12-01

    The pyrolysis of six waste biomass samples was studied and the fuels were kinetically evaluated. A modified independent parallel reactions scheme (IPR) and a distributed activation energy model (DAEM) were developed and their validity was assessed and compared by checking their accuracy of fitting the experimental results, as well as their prediction capability in different experimental conditions. The pyrolysis experiments were carried out in a thermogravimetric analyzer and a fitting procedure, based on least squares minimization, was performed simultaneously at different experimental conditions. A modification of the IPR model, considering dependence of the pre-exponential factor on heating rate, was proved to give better fit results for the same number of tuned kinetic parameters, comparing to the known IPR model and very good prediction results for stepwise experiments. Fit of calculated data to the experimental ones using the developed DAEM model was also proved to be very good. Copyright © 2015 Elsevier Ltd. All rights reserved.

  12. Coal-fueled diesel technology development -- Fuel injection equipment for coal-fueled diesel engines

    Energy Technology Data Exchange (ETDEWEB)

    Johnson, R.N.; Hayden, H.L.

    1994-01-01

    Because of the abrasive and corrosive nature of coal water slurries, the development of coal-fueled diesel engine technology by GE-Transportation Systems (GE-TS) required special fuel injection equipment. GE-Corporate Research and Development (GE-CRD) undertook the design and development of fuel injectors, piston pumps, and check valves for this project. Components were tested at GE-CRD on a simulated engine cylinder, which included a cam-actuated jerk pump, prior to delivery to GE-TS for engine testing.

  13. History of fast reactor fuel development

    Energy Technology Data Exchange (ETDEWEB)

    Kittel, J.H.; Frost, B.R.T. (Argonne National Lab., IL (United States)); Mustelier, J.P. (COGEMA, Velizy-Villacoublay (France))

    1992-01-01

    Most of the first generation of fast reactors that were operated at significant power levels employed solid metal fuels. They were constructed in the United States and United Kingdom in the 1950s and included Experimental Breeder Reactor (EBR)-I and -II operated by Argonne National Laboratory, United States, the Enrico Fermi Reactor operated by the Atomic Power Development Associates, United States and DFR operated by the U.K. Atomic Energy Authority (UKAEA). Their paper tracer pre-development of fast reactor fuel from these early days through the 1980s including ceramic fuels.

  14. Developments in spent fuel storage

    Energy Technology Data Exchange (ETDEWEB)

    Stallings, R.A. [USDOE Office of Civilian Radioactive Waste Management, Washington, DC (United States)

    1995-04-01

    The author gives a brief review of the his efforts to negotiate a site for monitored retrieval storage (MRS) of spent fuels in 1994. His efforts were centered on finding a voluntary host for the MRS site. He found politician were not opposed but did not want to make it a campaign issue during 1994. The author and his office came to the conclusion that to find a site voluntarily, the project would have to be an economic opportunity for the region.

  15. Development of a diesel substitute fuel

    Energy Technology Data Exchange (ETDEWEB)

    Reiter, Anton; Mair-Zelenka, Philipp [Graz Univ. of Technology (Austria). Inst. of Chemical Engineering and Environmental Technology; Zeymer, Marc [OMV Refining and Marketing GmbH, Vienna (Austria). MRDI-D Product Development and Innovation

    2013-06-01

    Substitute fuels composed of few real chemical compounds are an alternative characterisation approach for conventional fuels as opposed to the traditional pseudo-component method. With the algorithm proposed in this paper the generation of such substitutes will be facilitated and well-established thermodynamic methods can be applied for physical property-data prediction. Based on some quality criteria like true boiling-point curve, liquid density, C/H ratio, or cloud point of a target fuel a surrogate which meets these properties is determined by fitting its composition. The application and capabilities of the algorithm developed are demonstrated by means of an exemplary diesel substitute fuel. The substitute mixture obtained can be generated and used for evaluation of property-prediction methods. Furthermore this approach can help to understand the effects of mixing fossil fuels with biogenic compounds. (orig.)

  16. Further Considerations for Development of the Comprehensive Fuel Services

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Donghoon; Ryu, Jaesoo; Jun, Eunju; Lee, Hanmyung; Lee, Kwangseok [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

    2013-05-15

    The front-end fuel cycle services are reliably provided by commercial suppliers, and some multilateral approaches related on front-end fuel cycle including fuel bank are implemented as well. However in case of the back-end fuel cycle services, reprocessing services are provided by limited number of companies and disposal services are not currently provided in commercial market. In addition, multilateral fuel cycle mechanisms focused on the back-end fuel cycle are not being actively discussed. Recently, multilateral mechanism related to the back-end fuel cycle, called 'Comprehensive Fuel Service (CFS)' was suggested by United States in the International Framework for Nuclear Energy Cooperation (IFNEC). This study provides an overview of the CFS, opportunities and challenges for its implementation. It also provides considerations to encourage development of the multilateral and commercial-based CFS for the back-end fuel cycle. CFS suggested by U. S in IFNEC is commercially-based new nuclear fuel management system and expected to provide an economic alternative to development of long-term storage and disposal facilities and sensitive nuclear facilities. However, the CFS approach is faced with several challenges such as the development of multinational disposal facility. Above all, confidence building among the IFNEC member states based on common understanding is crucial to overcome these challenges. To achieve this, international communities should continually cooperate with stakeholders and discuss the consideration that suggested by this study. And we need to monitor progress of CFS concept that remains under development, and to prepare for multilateral discussion on CFS.

  17. LG Solid Oxide Fuel Cell (SOFC) Model Development

    Energy Technology Data Exchange (ETDEWEB)

    Haberman, Ben [LG Fuel Cell Systems Inc., North Canton, OH (United States); Martinez-Baca, Carlos [LG Fuel Cell Systems Inc., North Canton, OH (United States); Rush, Greg [LG Fuel Cell Systems Inc., North Canton, OH (United States)

    2013-05-31

    This report presents a summary of the work performed by LG Fuel Cell Systems Inc. during the project LG Solid Oxide Fuel Cell (SOFC) Model Development (DOE Award Number: DE-FE0000773) which commenced on October 1, 2009 and was completed on March 31, 2013. The aim of this project is for LG Fuel Cell Systems Inc. (formerly known as Rolls-Royce Fuel Cell Systems (US) Inc.) (LGFCS) to develop a multi-physics solid oxide fuel cell (SOFC) computer code (MPC) for performance calculations of the LGFCS fuel cell structure to support fuel cell product design and development. A summary of the initial stages of the project is provided which describes the MPC requirements that were developed and the selection of a candidate code, STAR-CCM+ (CD-adapco). This is followed by a detailed description of the subsequent work program including code enhancement and model verification and validation activities. Details of the code enhancements that were implemented to facilitate MPC SOFC simulations are provided along with a description of the models that were built using the MPC and validated against experimental data. The modeling work described in this report represents a level of calculation detail that has not been previously available within LGFCS.

  18. Hydrogen and fuel cell activities at UNIDO-ICHET

    Energy Technology Data Exchange (ETDEWEB)

    Suha Yazici, M. [UNIDO International Center for Hydrogen Energy Technologies, Sabri Ulker Sk, 38/4, Cevizlibag-Zeytinburnu, 34015 Istanbul (Turkey)

    2010-04-15

    To place hydrogen energy usage into proper perspective, International Center for Hydrogen Energy Technologies (ICHET) has been implementing measures to demonstrate potential benefits of the ''hydrogen and fuel cell systems'' in developing countries. Demonstration of technologies is the most important aspect of ICHET vision for the formation of an industry in the developing world. ICHET has embarked on a series of educational and laboratory activities designed to increase the knowledge and awareness of students and advanced researchers concerning hydrogen energy technologies. The state of the art fuel cell laboratory is available for joint technology development and demonstration activities. Internship activities facilitate knowledge transfer, exchange of information at regional, national and international levels and involve academics, researchers, experts and service providers. Collaboration is a key part of the organizational strategy for joint projects, funding and trainings in the field of hydrogen and fuel cells. (author)

  19. Nuclear fuels: Development, processing and disposal

    Energy Technology Data Exchange (ETDEWEB)

    Allday, C.

    1982-08-01

    The successful development of the world's energy resources has enabled industries in the more advanced countries to provide the economic basis on which improved living standards are based. As the less well-developed countries seek to improve their standards of living the pressure on existing energy resources will increase. In this context it is essential not to allow the current industrial recession in the developed countries, with its associated apparent abundancy of coal, oil and gas, to mask the longer-term energy situation. It is not here proposed to discuss the role of nuclear power in the energy scene except to say that, with the continuing need to develop energy resources, nuclear as a proven safe and economic system - will have a vital role to fulfil in meeting the world's future energy demands. This paper is concerned with the development of nuclear fuel and the industry which has grown around it during the last 30 years. It shall concentrate on its development in this country and describe the history and activities of BNFL.

  20. Development of CANFLEX fuel fabrication technology

    Energy Technology Data Exchange (ETDEWEB)

    Kang, M. S.; Choi, C. B.; Park, C. H.; Kwon, W. J.; Kim, C. H.; Kim, B. J.; Koo, C. H.; Cho, D. S.; So, D. Y.; Suh, S. W.; Park, C. J.; Chang, D. H.; Yun, S. H. [KEPCO Nuclear Fuel Company, Taejeon (Korea)

    2000-04-01

    Wolsong Unit 1 as the first heavy water reactor in Korea has been in service for 17 years since 1983. It would be about the time to prepare a plan for the solution of problems due to aging of the reactor. The aging of CANDU reactor could lead especially to the steam generator cruding and pressure tube sagging and creep and then decreases the operation margin to make some problems on reactor operations and safety. The counterplan could be made in two ways. One is to repair or modify reactor itself. The other is to develop new advanced fuel to increase of CANDU operation margin effectively, so as to compensate the reduced operation margin. Therefore, the first objectives in the present R and D is to develop the CANFLEX-NU(CANDU Flexible fuelling-Natural Uranium) fuel as a CANDU advanced fuel. One of the improvements in CANDU fuel fabrication technology, and advanced method of Zr-Be brazing was developed. For the formation of Zr-Be alloy, preheating and main heating temperature in the furnace is 700 deg C, 1200 deg C respectively. In order to find an appropriate material for the brazing joints in the CANDU fuel, the composition of Zr based amorphous metals were designed. And, the effect of hydrogen on the mechanical properties of cladding sheath and feasibility of the eddy current test to evaluate quality of end cap weld were also studied for the fundamental research purpose. As a preliminary study to suggest optimal way for the mass production of CANFLEX-NU fuel at KNFC the existing CANDU fuel facilities and fabrication/inspection processes were reviewed. The best way is that the current CANDU facility shall be modified to produce small diametrial CANFLEX elements and a new facility shall be constructed to produce large diametrial CANFLEX fuel elements. 46 refs., 99 figs., 10 tabs. (Author)

  1. NP-MHTGR Fuel Development Program Results

    Energy Technology Data Exchange (ETDEWEB)

    Maki, John Thomas; Petti, David Andrew; Hobbins, Richard Redfield; McCardell, Richard K.; Shaber, Eric Lee; Southworth, Finis Hio

    2002-10-01

    In August 1988, the Secretary of Energy announced a strategy to acquire New Production Reactor capacity for producing tritium. The strategy involved construction of a New Production Modular High Temperature Gas-Cooled Reactor (NP-MHTGR) where the Idaho National Engineering and Environmental Laboratory (INEEL) was selected as the Management and Operations contractor for the project. Immediately after the announcement in August 1988, tritium target particle development began with the INEEL selected as the lead laboratory. Fuel particle development was initially not considered to be on a critical path for the project, therefore, the fuel development program was to run concurrently with the design effort of the NP-MHTGR.

  2. Fuel cells: a survey of current developments

    Science.gov (United States)

    Cropper, Mark A. J.; Geiger, Stefan; Jollie, David M.

    Since the first practical uses of fuel cells were developed, it has become clear that they could find use in many products over a wide power range of milliwatts to tens of megawatts. Throughout the 1990s, and later, there has been significant work carried out on adapting the various different fuel cell technologies for use in targetted consumer and industrial applications. This paper discusses these developments and gives details on the specific market segments for providing power to vehicles, portable devices and large- and small-scale stationary power generation.

  3. Development Status of Accident Tolerant Fuel Cladding for LWRs

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Hyun-Gil; Kim, Il-Hyun; Jung, Yang-Il; Park, Dong-Jun; Park, Jung-Hwan; Yang, Jae-Ho; Koo, Yang-Hyun [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

    2016-10-15

    Hydrogen explosions and the release of radionuclides are caused by severe damage of current nuclear fuels, which are composed of fuel pellets and fuel cladding, during an accident. To reduce the damage to the public, the fuels have to enhance their integrity under an accident environment. Enhanced accident tolerance fuels (ATFs) can tolerate a loss of active cooling in the reactor core for a considerably longer time period during design-basis and beyond design-basis events while maintaining or improving the fuel performance during normal operations as well as operational transients, in comparison with the current UO{sub 2}-Zr alloy system used in the LWR. Surface modified Zr cladding as a new concept was suggested to apply an enhanced ATF cladding. The aim of the partial ODS treatment is to increase the high-temperature strength to suppress the ballooning/rupture behavior of fuel cladding during an accident event. The target of the surface coating is to increase the corrosion resistance during normal operation and increase the oxidation resistance during an accident event. The partial ODS treatment of Zircaloy-4 cladding can be produced using a laser beam scanning method with Y2O3 powder, and the surface Cr-alloy and Cr/FeCrAl coating on Zircaloy-4 cladding can be obtained after the development of 3D laser coating and arc ion plating technologies.

  4. Casting Technology Development for SFR Metallic Fuel

    Energy Technology Data Exchange (ETDEWEB)

    Lee, C.T.; Oh, S.J.; Ryu, H.J.; Kim, K.H.; Lee, Y.S.; Kim, S.K.; Woo, Y.M.; Ko, Y.M.; Lee, C.B. [KAERI, 150 Deokjin-dong, Yuseong, Daejeon, 305-353 (Korea, Republic of)

    2009-06-15

    Fabrication technology of metallic fuel for sodium fast reactor (SFR) is being developed in Korea as a national mid- and long-term nuclear R and D program from 2007. The metallic fuel for SFR should be remotely fabricated under a radiation shielded environment such as a glove box or hot cell, because it contains long-lived minor actinides such as Np, Am and Cm. In order to design a reliable remote fabrication system, various casting techniques have been studied by using U-Zr and U-Zr-RE alloys as surrogate fuel material. Rare earth elements such as Ce or Nd were used as a surrogate for minor actinide elements or solid solution fission products. Macro-scale soundness, microstructures and compositional homogeneity of metallic fuel samples fabricated by vacuum-assisted injection casting, vacuum-assisted gravity casting, centrifugal atomization and continuous casting were compared. Although sound slugs of U-Zr metallic fuel of 4{approx}6 mm in diameter could be fabricated by vacuum-assisted injection casting or vacuum-assisted gravity casting, it was necessary to consider that vaporization of Am and volume of radioactive wastes such as crucibles and molds should be minimized. Effects of casting parameters on the volatile loss, and effects of coatings on the chemical reaction between metallic fuel and molds are discussed. Some methods to reduce the volatile Am loss and waste molds and crucibles will be proposed. Short rods of U-Zr or U-Zr-Ce fuel will be fabricated by the vacuum-assisted gravity casting technique for an irradiation test in the HANARO research reactor from 2010. (authors)

  5. High-pressure coal fuel processor development

    Energy Technology Data Exchange (ETDEWEB)

    Greenhalgh, M.L.

    1992-11-01

    The objective of Subtask 1.1 Engine Feasibility was to conduct research needed to establish the technical feasibility of ignition and stable combustion of directly injected, 3,000 psi, low-Btu gas with glow plug ignition assist at diesel engine compression ratios. This objective was accomplished by designing, fabricating, testing and analyzing the combustion performance of synthesized low-Btu coal gas in a single-cylinder test engine combustion rig located at the Caterpillar Technical Center engine lab in Mossville, Illinois. The objective of Subtask 1.2 Fuel Processor Feasibility was to conduct research needed to establish the technical feasibility of air-blown, fixed-bed, high-pressure coal fuel processing at up to 3,000 psi operating pressure, incorporating in-bed sulfur and particulate capture. This objective was accomplished by designing, fabricating, testing and analyzing the performance of bench-scale processors located at Coal Technology Corporation (subcontractor) facilities in Bristol, Virginia. These two subtasks were carried out at widely separated locations and will be discussed in separate sections of this report. They were, however, independent in that the composition of the synthetic coal gas used to fuel the combustion rig was adjusted to reflect the range of exit gas compositions being produced on the fuel processor rig. Two major conclusions resulted from this task. First, direct injected, ignition assisted Diesel cycle engine combustion systems can be suitably modified to efficiently utilize these low-Btu gas fuels. Second, high pressure gasification of selected run-of-the-mine coals in batch-loaded fuel processors is feasible. These two findings, taken together, significantly reduce the perceived technical risks associated with the further development of the proposed coal gas fueled Diesel cycle power plant concept.

  6. FuelPHP application development blueprints

    CERN Document Server

    Drouyer, Sébastien

    2015-01-01

    This book is for intermediary to seasoned web developers who want to learn how to use the FuelPHP framework and build complex projects using it. You should be familiar with PHP, HTML, CSS, and JavaScript, but no prior knowledge about MVC frameworks is required.

  7. Common sense approach in developing fuel alcohols

    Energy Technology Data Exchange (ETDEWEB)

    Jawetz, P.

    1981-01-01

    This paper develops calculations for what seems to be the most effective use of fuel-ethanol - the displacement of octane boosting additives in high octane unleaded motor-vehicle-fuel gasoline. It is shown how each btu of ethanol does in effect replace 3.77 btu of petroleum crude or petroleum products, and when studying further the energy balance in the production of fermentation ethanol how each btu of energy input can produce 6.6 btu of useful energy. 8 refs.

  8. Development of spent fuel remote handling technology

    Energy Technology Data Exchange (ETDEWEB)

    Park, B. S.; Yoon, J. S.; Hong, H. D. (and others)

    2007-02-15

    In this research, the remote handling technology was developed for the ACP application. The ACP gives a possible solution to reduce the rapidly cumulative amount of spent fuels generated from the nuclear power plants in Korea. The remote technologies developed in this work are a slitting device, a voloxidizer, a modified telescopic servo manipulator and a digital mock-up. A slitting device was developed to declad the spent fuel rod-cuts and collect the spent fuel UO{sub 2} pellets. A voloxidizer was developed to convert the spent fuel UO{sub 2} pellets obtained from the slitting process in to U{sub 3}O{sub 8} powder. Experiments were performed to test the capabilities and remote operation of the developed slitting device and voloxidizer by using simulated rod-cuts and fuel in the ACP hot cell. A telescopic servo manipulator was redesigned and manufactured improving the structure of the prototype. This servo manipulator was installed in the ACP hot cell, and the target module for maintenance of the process equipment was selected. The optimal procedures for remote operation were made through the maintenance tests by using the servo manipulator. The ACP digital mockup in a virtual environment was established to secure a reliability and safety of remote operation and maintenance. The simulation for the remote operation and maintenance was implemented and the operability was analyzed. A digital mockup about the preliminary conceptual design of an enginnering-scale ACP was established, and an analysis about a scale of facility and remote handling was accomplished. The real-time diagnostic technique was developed to detect the possible fault accidents of the slitting device. An assessment of radiation effect for various sensors was also conducted in the radiation environment.

  9. Strategic alliances for the development of fuel cell vehicles

    Energy Technology Data Exchange (ETDEWEB)

    Maruo, Kanehira [Goeteborg Univ. (Sweden). Section of Science and Technology Studies

    1998-12-01

    The aim of this paper is to explore and describe the current stage of fuel cell vehicle development in the world. One can write three possible future scenarios - an optimistic, a realistic, and a pessimistic scenario: - The optimistic scenario -- The Daimler/Ballard/Ford alliance continues to develop fuel cell stacks and fuel cell vehicle systems as eagerly as they have been doing in recent years. Daimler(/Chrysler)-Benz continues to present its Necar 4, Necar 5, and so on, as planned, and thus keeps Toyota and Honda under severe pressure. Toyota`s and Honda`s real motivation seems to be not to allow Daimler-Benz to be the first to market. Their investment in fuel cell technology will be very large. At the same time, governments and other stake-holders will quickly and in a timely fashion build up infrastructures. We will then see many fuel cell vehicles by 2004. A paradigm shift in automotive technology will have taken place. - The realistic scenario -- Fuel cell vehicles will reach the same level of development by 2004/2005 as pure electric vehicles were at in 1997/1998. This means that fuel cell vehicles will be produced at the rate of several hundred vehicles per year per manufacturer and cost about $40,000 or more, which is still considerably more expensive than ordinary gasoline cars. These fuel cell vehicles will have a performance similar to today`s advanced electric vehicles, e.g., Toyota`s RAV4/EV and Honda`s EV Plus. To go further from this stage to the mass-production stage strong government incentives will be needed. - The pessimistic scenario -- It turns out that fuel cells are not as pure or efficient as in theory and in laboratory experiments. Prices of gasoline and diesel gas continue to be very low. The Californian 10% ZEV Requirement that has been meant to be valid at least ten years from 2003 through 2012 will be suspended or greatly modified. Daimler-Benz, Toyota, and Honda slow down their fuel cell vehicle development activities. No one is

  10. Monolithic Solid Oxide Fuel Cell development

    Science.gov (United States)

    Myles, K. M.; McPheeters, C. C.

    1989-12-01

    The Monolithic Solid Oxide Fuel Cell (MSOFC) is an oxide-ceramic structure in which appropriate electronic and ionic conductors are fabricated in a honeycomb shape similar to a block of corrugated paperboard. These electronic and ionic conductors are arranged to provide short conduction paths to minimize resistive losses. The power density achievable with the MSOFC is expected to be about 8 kW/kg or 4 kW/L, at fuel efficienceis over 50 percent, because of small cell size and low resistive losses in the materials. The MSOFC operates in the range of 700 to 1000 C, at which temperatures rapid reform of hydrocarbon fuels is expected within the nickel-YSZ fuel channels. Tape casting and hot roll calendering are used to fabricate the MSOFC structure. The performance of the MSOFC has improved significantly during the course of development. The limitation of this system, based on materials resistance alone without interfacial resistances, is 0.093 ohm-sq cm area-specific resistance (ASR). The current typical performance of MSOFC single cells is characterized by ASRs of about 0.4 to 0.5 ohm-sq cm. With further development the ASR is expected to be reduced below 0.2 ohm-sq cm, which will result in power levels greater than 1.4 W/sq cm. The feasibility of the MSOFC concept was proven, and the performance was dramatically improved. The differences in thermal expansion coefficients and firing shrinkages among the fuel cell materials were minimized. As a result of good matching of these properties, the MSOFC structure was successfully fabricated with few defects, and the system shows excellent promise for development into a practical power source.

  11. MONOLITHIC FUEL FABRICATION PROCESS DEVELOPMENT AT THE IDAHO NATIONAL LABORATORY_

    Energy Technology Data Exchange (ETDEWEB)

    G. A. Moore; F. J. Rice; N. E. Woolstenhulme; J-F. Jue; B. H. Park; S. E. Steffler; N. P. Hallinan; M. D. Chapple; M. C. Marshall; B. L. Mackowiak; C. R. Clark; B. H. Rabin

    2009-11-01

    Full-size/prototypic U10Mo monolithic fuel-foils and aluminum clad fuel plates are being developed at the Idaho National Laboratory’s (INL) Materials and Fuels Complex (MFC). These efforts are focused on realizing Low Enriched Uranium (LEU) high density monolithic fuel plates for use in High Performance Research and Test Reactors. The U10Mo fuel foils under development afford a fuel meat density of ~16 gU/cc and thus have the potential to facilitate LEU conversions without any significant reactor-performance penalty. An overview is provided of the ongoing monolithic UMo fuel development effort, including application of a zirconium barrier layer on fuel foils, fabrication scale-up efforts, and development of complex/graded fuel foils. Fuel plate clad bonding processes to be discussed include: Hot Isostatic Pressing (HIP) and Friction Bonding (FB).

  12. Development of alternative fuels from coal-derived syngas

    Energy Technology Data Exchange (ETDEWEB)

    Brown, D.M.

    1992-05-19

    The overall objectives of this program are to investigate potential technologies for the conversion of coal-derived synthesis gas to oxygenated fuels, hydrocarbon fuels, fuel intermediates, and octane enhancers; and to demonstrate the most promising technologies at DOE's LaPorte, Texas, Slurry Phase Alternative Fuels Development Unit (AFDU). BASF continues to have difficulties in scaling-up the new isobutanol synthesis catalyst developed in Air Products' laboratories. Investigations are proceeding, but the proposed operation at LaPorte in April is now postponed. DOE has accepted a proposal to demonstrate Liquid Phase Shift (LPS) chemistry at LaPorte as an alternative to isobutanol. There are two principal reasons for carrying out this run. First, following the extensive modifications at the site, operation on a relatively benign'' system is needed before we start on Fischer-Tropsch technology in July. Second, use of shift catalyst in a slurry reactor will enable DOE's program on coal-based Fischer-Tropsch to encompass commercially available cobalt catalysts-up to now they have been limited to iron-based catalysts which have varying degrees of shift activity. In addition, DOE is supportive of continued fuel testing of LaPorte methanol-tests of MIOO at Detroit Diesel have been going particularly well. LPS offers the opportunity to produce methanol as the catalyst, in the absence of steam, is active for methanol synthesis.

  13. Development of high performance hybrid rocket fuels

    Science.gov (United States)

    Zaseck, Christopher R.

    In this document I discuss paraffin fuel combustion and investigate the effects of additives on paraffin entrainment and regression. In general, hybrid rockets offer an economical and safe alternative to standard liquid and solid rockets. However, slow polymeric fuel regression and low combustion efficiency have limited the commercial use of hybrid rockets. Paraffin is a fast burning fuel that has received significant attention in the 2000's and 2010's as a replacement for standard fuels. Paraffin regresses three to four times faster than polymeric fuels due to the entrainment of a surface melt layer. However, further regression rate enhancement over the base paraffin fuel is necessary for widespread hybrid rocket adoption. I use a small scale opposed flow burner to investigate the effect of additives on the combustion of paraffin. Standard additives such as aluminum combust above the flame zone where sufficient oxidizer levels are present. As a result no heat is generated below the flame itself. In small scale opposed burner experiments the effect of limited heat feedback is apparent. Aluminum in particular does not improve the regression of paraffin in the opposed burner. The lack of heat feedback from additive combustion limits the applicability of the opposed burner. In turn, the results obtained in the opposed burner with metal additive loaded hybrid fuels do not match results from hybrid rocket experiments. In addition, nano-scale aluminum increases melt layer viscosity and greatly slows the regression of paraffin in the opposed flow burner. However, the reactive additives improve the regression rate of paraffin in the opposed burner where standard metals do not. At 5 wt.% mechanically activated titanium and carbon (Ti-C) improves the regression rate of paraffin by 47% in the opposed burner. The mechanically activated Ti C likely reacts in or near the melt layer and provides heat feedback below the flame region that results in faster opposed burner regression

  14. Metal fuel development and verification for prototype generation- IV Sodium- Cooled Fast Reactor

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Chan Bock; Cheon, Jin Sik; Kim, Sung Ho; Park, Jeong Yong; Joo, Hyung Kook [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

    2016-10-15

    Metal fuel is being developed for the prototype generation-IV sodium-cooled fast reactor (PGSFR) to be built by 2028. U-Zr fuel is a driver for the initial core of the PGSFR, and U -transuranics (TRU)-Zr fuel will gradually replace U-Zr fuel through its qualification in the PGSFR. Based on the vast worldwide experiences of U-Zr fuel, work on U-Zr fuel is focused on fuel design, fabrication of fuel components, and fuel verification tests. U-TRU-Zr fuel uses TRU recovered through pyroelectrochemical processing of spent PWR (pressurized water reactor) fuels, which contains highly radioactive minor actinides and chemically active lanthanide or rare earth elements as carryover impurities. An advanced fuel slug casting system, which can prevent vaporization of volatile elements through a control of the atmospheric pressure of the casting chamber and also deal with chemically active lanthanide elements using protective coatings in the casting crucible, was developed. Fuel cladding of the ferritic-martensitic steel FC92, which has higher mechanical strength at a high temperature than conventional HT9 cladding, was developed and fabricated, and is being irradiated in the fast reactor.

  15. Microchennel development for autothermal reforming of hydrocarbon fuels

    Science.gov (United States)

    Bae, J.-M.; Ahmed, S.; Kumar, R.; Doss, E.

    Fuel-processing is a bridging technology to assist the commercialization of fuel cell systems in the absence of a hydrogen infrastructure. The Argonne National Laboratory has been developing fuel-processing technologies for fuel cells, and has reported the development of novel catalysts that are active and selective for hydrocarbon-reforming reactions. It has been realized, however, that with pellets or conventional honeycomb catalysts, the reforming process is mass-transport limited. This study addresses the development of catalysts structures with microchannels that are able to reduce the diffusion resistance and, thereby, achieve the same production rate within a smaller reactor bed. The microchannel reforming catalysts are prepared and tested with natural gas and gasoline-type fuels in a microreactor (diameter: 1 cm) at space velocities of up to 250 000 h -1. The catalysts have also been used in engineering-scale reactors (10 kWe; diameter: 7 cm) with similar product qualities. Compared with pellet catalysts, the microchannel catalysts offer a nearly five-fold reduction in catalyst weight and volume.

  16. 160 C PROTON EXCHANGE MEMBRANE (PEM) FUEL CELL SYSTEM DEVELOPMENT

    Energy Technology Data Exchange (ETDEWEB)

    L.G. Marianowski

    2001-12-21

    The objectives of this program were: (a) to develop and demonstrate a new polymer electrolyte membrane fuel cell (PEMFC) system that operates up to 160 C temperatures and at ambient pressures for stationary power applications, and (b) to determine if the GTI-molded composite graphite bipolar separator plate could provide long term operational stability at 160 C or higher. There are many reasons that fuel cell research has been receiving much attention. Fuel cells represent environmentally friendly and efficient sources of electrical power generation that could use a variety of fuel sources. The Gas Technology Institute (GTI), formerly Institute of Gas Technology (IGT), is focused on distributed energy stationary power generation systems. Currently the preferred method for hydrogen production for stationary power systems is conversion of natural gas, which has a vast distribution system in place. However, in the conversion of natural gas into a hydrogen-rich fuel, traces of carbon monoxide are produced. Carbon monoxide present in the fuel gas will in time cumulatively poison, or passivate the active platinum catalysts used in the anodes of PEMFC's operating at temperatures of 60 to 80 C. Various fuel processors have incorporated systems to reduce the carbon monoxide to levels below 10 ppm, but these require additional catalytic section(s) with sensors and controls for effective carbon monoxide control. These CO cleanup systems must also function especially well during transient load operation where CO can spike 300% or more. One way to circumvent the carbon monoxide problem is to operate the fuel cell at a higher temperature where carbon monoxide cannot easily adsorb onto the catalyst and poison it. Commercially available polymer membranes such as Nafion{trademark} are not capable of operation at temperatures sufficiently high to prevent this. Hence this project investigated a new polymer membrane alternative to Nafion{trademark} that is capable of operation at

  17. Development of dynamic simulation code for fuel cycle of fusion reactor. 1. Single pulse operation simulation

    Energy Technology Data Exchange (ETDEWEB)

    Aoki, Isao; Seki, Yasushi [Japan Atomic Energy Research Inst., Naka, Ibaraki (Japan). Naka Fusion Research Establishment; Sasaki, Makoto; Shintani, Kiyonori; Kim, Yeong-Chan

    1997-11-01

    A dynamic simulation code for the fuel cycle of a fusion experimental reactor has been developed. The code follows the fuel inventory change with time in the plasma chamber and the fuel cycle system during a single pulse operation. The time dependence of the fuel inventory distribution is evaluated considering the fuel burn and exhaust in the plasma chamber, purification and supply functions. For each subsystem of the plasma chamber and the fuel cycle system, the fuel inventory equation is written based on the equation of state considering the function of fuel burn, exhaust, purification, and supply. The processing constants of subsystem for the steady states were taken from the values in the ITER Conceptual Design Activity (CDA) report. Using the code, the time dependence of the fuel supply and inventory depending on the burn state and subsystem processing functions are shown. (author)

  18. The synchronous active neutron detection system for spent fuel assay

    Energy Technology Data Exchange (ETDEWEB)

    Pickrell, M.M.; Kendall, P.K.

    1994-10-01

    The authors have begun to develop a novel technique for active neutron assay of fissile material in spent nuclear fuel. This approach will exploit the unique operating features of a 14-MeV neutron generator developed by Schlumberger. This generator and a novel detection system will be applied to the direct measurement of the fissile material content in spent fuel in place of the indirect measures used at present. The technique they are investigating is termed synchronous active neutron detection (SAND). It closely follows a method that has been used routinely in other branches of physics to detect very small signals in the presence of large backgrounds. Synchronous detection instruments are widely available commercially and are termed {open_quotes}lock-in{close_quotes} amplifiers. The authors have implemented a digital lock-in amplifier in conjunction with the Schlumberger neutron generator to explore the possibility of synchronous detection with active neutrons. This approach is possible because the Schlumberger system can operate at up to a 50% duty factor, in effect, a square wave of neutron yield. The results to date are preliminary but quite promising. The system is capable of resolving the fissile material contained in a small fraction of the fuel rods in a cold fuel assembly. It also appears to be quite resilient to background neutron interference. The interrogating neutrons appear to be nonthermal and penetrating. Although a significant amount of work remains to fully explore the relevant physics and optimize the instrument design, the underlying concept appears sound.

  19. Analysis and classification of physical and chemical methods of fuel activation

    Directory of Open Access Journals (Sweden)

    Fedorchak Viktoriya

    2015-12-01

    Full Text Available The offered article explores various research studies, developed patents in terms of physical and chemical approaches to the activation of fuel. In this regard, national and foreign researches in the field of fuels activators with different principles of action were analysed, evaluating their pros and cons. The article also intends to classify these methods and compare them regarding diverse desired results and types of fuels used. In terms of physical and chemical influences on fuels and the necessity of making constructive changes in the fuel system of internal combustion engines, an optimal approach was outlined.

  20. Development of the advanced CANDU technology -Development of CANDU advanced fuel fabrication technology-

    Energy Technology Data Exchange (ETDEWEB)

    Choi, Chang Bum; Park, Choon Hoh; Park, Chul Joo; Kwon, Woo Joo [Korea Atomic Energy Research Institute, Taejon (Korea, Republic of)

    1995-07-01

    This project is carrying out jointly with AECL to develop CANFLEX fuel which can enhance reactor safety, fuel economy and can be used with various fuel cycles (natural U, slightly enriched U, other advanced fuel). The final goal of this research is to load the CANFLEX fuel in commercial CANDU reactor for demonstration irradiation. The annual portion of research activities performed during this year are followings ; The detail design of CANFLEX-NU fuel was determined. Based on this design, various fabrication drawings and process specifications were revised. The seventeen CANFLEX-NU fuel bundles for reactivity test in ZED-2 and out-pile test, two CANFLEX-SEU fuel bundles for demo-irradiation in NRU were fabricated. Advanced tack welding machine was designed and sequence control software of automatic assembly welder was developed. The basic researches related to fabrication processes, such as weld evaluation by ECT, effect of additives in UO{sub 2}, thermal stabilities of Zr based metallic glasses, were curried out. 51 figs, 22 tabs, 42 refs. (Author).

  1. Quarterly Progress Report Fuels Development Operation October - December 1960

    Energy Technology Data Exchange (ETDEWEB)

    Cadwell, J. J. [Hanford Site (HNF), Richland, WA (United States); Tobin, J. C. [Hanford Site (HNF), Richland, WA (United States); Last, G. A. [Hanford Site (HNF), Richland, WA (United States); Evans, E. A. [Hanford Site (HNF), Richland, WA (United States); Minor, J. E. [Hanford Site (HNF), Richland, WA (United States)

    1961-01-13

    The present Quarterly Report is the continuation of a series issued by the new Fuels Development Operation. Reports in this series combine portions of the quarterly reports by the former Metallurgy Research and Fuel Technology Sub-Sections.

  2. Recent developments in biodesulfurization of fossil fuels.

    Science.gov (United States)

    Xu, Ping; Feng, Jinhui; Yu, Bo; Li, Fuli; Ma, Cuiqing

    2009-01-01

    The emission of sulfur oxides can have adverse effects on the environment. Biodesulfurization of fossil fuels is attracting more and more attention because such a bioprocess is environmentally friendly. Some techniques of desulfurization have been used or studied to meet the stricter limitation on sulfur content in China. Recent advances have demonstrated the mechanism and developments for biodesulfurization of gasoline, diesel and crude oils by free cells or immobilized cells. Genetic technology was also used to improve sulfur removal efficiencies. In this review, we summarize recent progress mainly in China on petroleum biodesulfurization.

  3. Combustion Characterization and Model Fuel Development for Micro-tubular Flame-assisted Fuel Cells.

    Science.gov (United States)

    Milcarek, Ryan J; Garrett, Michael J; Baskaran, Amrish; Ahn, Jeongmin

    2016-10-02

    Combustion based power generation has been accomplished for many years through a number of heat engine systems. Recently, a move towards small scale power generation and micro combustion as well as development in fuel cell research has created new means of power generation that combine solid oxide fuel cells with open flames and combustion exhaust. Instead of relying upon the heat of combustion, these solid oxide fuel cell systems rely on reforming of the fuel via combustion to generate syngas for electrochemical power generation. Procedures were developed to assess the combustion by-products under a wide range of conditions. While theoretical and computational procedures have been developed for assessing fuel-rich combustion exhaust in these applications, experimental techniques have also emerged. The experimental procedures often rely upon a gas chromatograph or mass spectrometer analysis of the flame and exhaust to assess the combustion process as a fuel reformer and means of heat generation. The experimental techniques developed in these areas have been applied anew for the development of the micro-tubular flame-assisted fuel cell. The protocol discussed in this work builds on past techniques to specify a procedure for characterizing fuel-rich combustion exhaust and developing a model fuel-rich combustion exhaust for use in flame-assisted fuel cell testing. The development of the procedure and its applications and limitations are discussed.

  4. Lean Gasoline System Development for Fuel Efficient Small Cars

    Energy Technology Data Exchange (ETDEWEB)

    Smith, Stuart R. [General Motors LLC, Pontiac, MI (United States)

    2013-11-25

    The General Motors and DOE cooperative agreement program DE-EE0003379 is completed. The program has integrated and demonstrated a lean-stratified gasoline engine, a lean aftertreatment system, a 12V Stop/Start system and an Active Thermal Management system along with the necessary controls that significantly improves fuel efficiency for small cars. The fuel economy objective of an increase of 25% over a 2010 Chevrolet Malibu and the emission objective of EPA T2B2 compliance have been accomplished. A brief review of the program, summarized from the narrative is: The program accelerates development and synergistic integration of four cost competitive technologies to improve fuel economy of a light-duty vehicle by at least 25% while meeting Tier 2 Bin 2 emissions standards. These technologies can be broadly implemented across the U.S. light-duty vehicle product line between 2015 and 2025 and are compatible with future and renewable biofuels. The technologies in this program are: lean combustion, innovative passive selective catalyst reduction lean aftertreatment, 12V stop/start and active thermal management. The technologies will be calibrated in a 2010 Chevrolet Malibu mid-size sedan for final fuel economy demonstration.

  5. Lean Gasoline System Development for Fuel Efficient Small Cars

    Energy Technology Data Exchange (ETDEWEB)

    None

    2013-08-30

    The General Motors and DOE cooperative agreement program DE-EE0003379 is completed. The program has integrated and demonstrated a lean-stratified gasoline engine, a lean aftertreatment system, a 12V Stop/Start system and an Active Thermal Management system along with the necessary controls that significantly improves fuel efficiency for small cars. The fuel economy objective of an increase of 25% over a 2010 Chevrolet Malibu and the emission objective of EPA T2B2 compliance have been accomplished. A brief review of the program, summarized from the narrative is: The program accelerates development and synergistic integration of four cost competitive technologies to improve fuel economy of a light-duty vehicle by at least 25% while meeting Tier 2 Bin 2 emissions standards. These technologies can be broadly implemented across the U.S. light-duty vehicle product line between 2015 and 2025 and are compatible with future and renewable biofuels. The technologies in this program are: lean combustion, innovative passive selective catalyst reduction lean aftertreatment, 12V stop/start and active thermal management. The technologies will be calibrated in a 2010 Chevrolet Malibu mid-size sedan for final fuel economy demonstration.

  6. Evolutionary developments of advanced PWR nuclear fuels and cladding materials

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Kyu-Tae, E-mail: ktkim@dongguk.ac.kr

    2013-10-15

    Highlights: • PWR fuel and cladding materials development processes are provided. • Evolution of PWR advanced fuel in U.S.A. and in Korea is described. • Cutting-edge design features against grid-to-rod fretting and debris are explained. • High performance data of advanced grids, debris filters and claddings are given. -- Abstract: The evolutionary developments of advanced PWR fuels and cladding materials are explained with outstanding design features of nuclear fuel assembly components and zirconium-base cladding materials. The advanced PWR fuel and cladding materials development processes are also provided along with verification tests, which can be used as guidelines for newcomers planning to develop an advanced fuel for the first time. The up-to-date advanced fuels with the advanced cladding materials may provide a high level of economic utilization and reliable performance even under current and upcoming aggressive operating conditions. To be specific, nuclear fuel vendors may achieve high fuel burnup capability of between 45,000 and 65,000 MWD/MTU batch average, overpower thermal margin of as much as 15% and longer cycle length up to 24 months on the one hand and fuel failure rates of around 10{sup −6} on the other hand. However, there is still a need for better understanding of grid-to-rod fretting wear mechanisms leading to major PWR fuel defects in the world and subsequently a driving force for developing innovative spacer grid designs with zero fretting wear-induced fuel failure.

  7. Development of direct hydrocarbon solid oxide fuel cells

    Science.gov (United States)

    McIntosh, Steven

    The focus of this dissertation is the development of a Solid Oxide Fuel Cell (SOFC) that can operate with hydrocarbon fuels without the need for pre-reforming. The design of an active SOFC anode requires the consideration of a number of factors including the catalytic activity of the electrode towards fuel oxidation and electronic conductivity. This work focuses on a novel system for anode fabrication that allows the catalytically active and electronically conducting components of the anode to be easily varied. The catalytic properties of the SOFC anode were examined and a strong link between SOFC performance and oxidation activity demonstrated. Of the rare-earth catalysts investigated ceria was found to have the highest activity leading to the highest fuel cell power density. This activity was further improved, especially for methane fuel, by doping with a precious metal. Furthermore, it was shown that the catalyst not only increased the rate of reaction but increased the cell Open-Circuit Voltage (OCV) suggesting a change in mechanism that increased the cell efficiency. The necessity for high electronic conductivity and connectivity in the electrode was elucidated by studying the impact of anode copper content on cell performance. Low copper loading led to reduced cell performance due to a lack of conductive pathways from the active electrode region to the external circuit. It was observed that additional conductivity was provided by a thermally deposited carbonaceous phase formed upon exposure to hydrocarbon fuels. The electrochemical characterization of SOFC electrodes is a non-trivial problem. Literature reports on the properties of similar electrodes are inconsistent and often contradictory. Using a combined experimental and theoretical approach, significant problems were found with common experimental procedures used to separate the losses associated the cell cathode from those of the anode. By calculating the effect of test geometry on this separation, it

  8. Technology readiness levels for advanced nuclear fuels and materials development

    Energy Technology Data Exchange (ETDEWEB)

    Carmack, W.J., E-mail: jon.carmack@inl.gov [Idaho National Laboratory, Idaho Falls, ID (United States); Braase, L.A.; Wigeland, R.A. [Idaho National Laboratory, Idaho Falls, ID (United States); Todosow, M. [Brookhaven National Laboratory, Upton, NY (United States)

    2017-03-15

    Highlights: • Definition of nuclear fuels system technology readiness level. • Identification of evaluation criteria for nuclear fuel system TRLs. • Application of TRLs to fuel systems. - Abstract: The Technology Readiness process quantitatively assesses the maturity of a given technology. The National Aeronautics and Space Administration (NASA) pioneered the process in the 1980s to inform the development and deployment of new systems for space applications. The process was subsequently adopted by the Department of Defense (DoD) to develop and deploy new technology and systems for defense applications. It was also adopted by the Department of Energy (DOE) to evaluate the maturity of new technologies in major construction projects. Advanced nuclear fuels and materials development is needed to improve the performance and safety of current and advanced reactors, and ultimately close the nuclear fuel cycle. Because deployment of new nuclear fuel forms requires a lengthy and expensive research, development, and demonstration program, applying the assessment process to advanced fuel development is useful as a management, communication, and tracking tool. This article provides definition of technology readiness levels (TRLs) for nuclear fuel technology as well as selected examples regarding the methods by which TRLs are currently used to assess the maturity of nuclear fuels and materials under development in the DOE Fuel Cycle Research and Development (FCRD) Program within the Advanced Fuels Campaign (AFC).

  9. Development of new membrane materials for direct methanol fuel cells

    NARCIS (Netherlands)

    Yildirim, Mustafa Hakan

    2009-01-01

    Development of new membrane materials for direct methanol fuel cells Direct methanol fuel cells (DMFCs) can convert the chemical energy of a fuel directly into electrical energy with high efficiency and low emission of pollutants. DMFCs can be used as the power sources to portable electronic devices

  10. Development of new membrane materials for direct methanol fuel cells

    NARCIS (Netherlands)

    Yildirim, M.H.

    2009-01-01

    Development of new membrane materials for direct methanol fuel cells Direct methanol fuel cells (DMFCs) can convert the chemical energy of a fuel directly into electrical energy with high efficiency and low emission of pollutants. DMFCs can be used as the power sources to portable electronic devices

  11. HTGR fuel recycle development program. Quarterly progress report for the period ending August 31, 1978

    Energy Technology Data Exchange (ETDEWEB)

    1978-09-01

    The work reported includes the development of unit processes and equipment for reprocessing of High-Temperature Gas-Cooled Reactor (HTGR) fuel, the design and development of an integrated pilot line to demonstrate the head end of HTGR reprocessing using unirradiated fuel materials, and design work in support of Hot Engineering Tests (HET). Work is also described on tradeoff studies concerning the required design of facilities and equipment for the large-scale recycle of HTGR fuels in order to guide the development activities for HTGR fuel recycle.

  12. Solid oxide fuel cell power system development

    Energy Technology Data Exchange (ETDEWEB)

    Kerr, Rick [Delphi Automotive Systems, LLC., Troy, MI (United States); Wall, Mark [Independent Energy Partners Technology, LLC., Parker, CO (United States); Sullivan, Neal [Colorado School of Mines, Golden, CO (United States)

    2015-06-26

    This report summarizes the progress made during this contractual period in achieving the goal of developing the solid oxide fuel cell (SOFC) cell and stack technology to be suitable for use in highly-efficient, economically-competitive, commercially deployed electrical power systems. Progress was made in further understanding cell and stack degradation mechanisms in order to increase stack reliability toward achieving a 4+ year lifetime, in cost reduction developments to meet the SECA stack cost target of $175/kW (in 2007 dollars), and in operating the SOFC technology in a multi-stack system in a real-world environment to understand the requirements for reliably designing and operating a large, stationary power system.

  13. Technological Creation Fuels Oil Giant's Development

    Institute of Scientific and Technical Information of China (English)

    Mu Zongyan

    2006-01-01

    @@ Sinopec has focused itself on development, conversion and extension of core technologies and specialized technologies in the recent years to fuel its main business development. With the efforts for IPR protection, Sinopec has achieved a series of technological creation results,which lead to huge social and economic benefits. Sinopec has also seen a significant change in the total amount,structure and quality of its assets thanks to those creation results. The sales income of Sinopec, for the first time,topped 800 billion yuan in 2005 with the profits and taxes exceeding 100 billion yuan. With the core competitiveness boosted continually, Sinopec rose to No.31 in the ranking of Fortune Global Top 500.

  14. Development of DUPIC fuel cycle technology - Assessment of Wolsong NPP fuel handling system for DUPIC fuel

    Energy Technology Data Exchange (ETDEWEB)

    Na, Bok Gyun; Nam, Gung Ihn [Korea Power Engineering Company, Taejon (Korea)

    2000-04-01

    The DUPIC fuel loading and discharge path of Wolsong NPP is studied assuming that DUPIC fuel is used at Wolsong NPP. Spent DUPIC fuel discharge path is irrelevant, since it uses the same spent fuel discharge path. Number of factors such as safety, economics of design change, radiation exposure to operators, easy of operation and maintenance, etc, are considered in the evaluation of path. A more detailed analysis of cost estimation of the selected path is also carried out. The study shows that DUPIC fuel loading path following through Spent Fuel Storage Bay and Spent Fuel Discharge Port in reverse direction will minimize the design change and additional equipment and radiation exposure to operators. The estimated total cost of using DUPIC fuel in Wolsong NPP based on price index of year 2000 is around 4.5 billion won. 4 refs., 30 figs., 13 tabs. (Author)

  15. Polymer electrolyte fuel cell stack research and development

    Energy Technology Data Exchange (ETDEWEB)

    Squadrito, G.; Barbera, O.; Giacoppo, G.; Urbani, F.; Passalacqua, E. [Istituto di Tecnologie Avanzate per l' Energia ' ' Nicola Giordano' ' del CNR (CNR, ITAE), via Salita per, Santa Lucia sopra Contesse 5, Messina (Italy)

    2008-04-15

    The research activity in polymer electrolyte fuel cell (PEFC) is oriented to the evolution of components and devices for the temperature range from 20 to 130{sup o}C, and covers all the aspects of this matter: membranes and electrodes, fuel cell stack engineering (design and manufacturing) and characterization, computational modelling and small demonstration systems prototyping. Particular attention is devoted to portable and automotive application. Membranes research is focused on thermostable polymers (polyetheretherketone, polysulphone, etc.) and composite membranes able to operate at higher temperature (>100{sup o}C) and lower humidification than the commercial Nafion {sup registered}, while Pt load reduction and gas diffusion layer improvement are the main goals for the electrode development. PEFC stack engineering and characterization activity involve different aspects such as the investigation of new materials for stack components, fuel cell modelling and performance optimization by computational techniques, single cell and stack electrochemical characterization, development of investigation tools for stack monitoring and data acquisition. A lot of work has been focused to the fuel cell stack architecture, assembling, gas leakage and cross-over reduction (gasketing), flow field and manifold design. Computational fluid dynamics studies have been performed to investigate and improve reactants distribution inside the cell. A flow field design methodology, developed in this framework and related to serpentine like flow field, is actually under investigation. All of these aspects of PEFC stack research are realized in the framework of National and European research projects, or in collaboration with industries and other research centres. In the present work our stack research activity is reported and the most important results are also considered. (author)

  16. Spent nuclear fuel retrieval system fuel handling development testing. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Jackson, D.R.; Meeuwsen, P.V.

    1997-09-01

    Fuel handling development testing was performed in support of the Fuel Retrieval System (FRS) Sub-Project, a subtask of the Spent Nuclear Fuel Project at the Hanford Site in Richland, Washington. The FRS will be used to retrieve and repackage K-Basin Spent Nuclear Fuel (SNF) currently stored in old K-Plant storage basins. The FRS is required to retrieve full fuel canisters from the basin, clean the fuel elements inside the canister to remove excessive uranium corrosion products (or sludge), remove the contents from the canisters and sort the resulting debris, scrap, and fuel for repackaging. The fuel elements and scrap will be collected in fuel storage and scrap baskets in preparation for loading into a multi canister overpack (MCO), while the debris is loaded into a debris bin and disposed of as solid waste. This report describes fuel handling development testing performed from May 1, 1997 through the end of August 1997. Testing during this period was mainly focused on performance of a Schilling Robotic Systems` Conan manipulator used to simulate a custom designed version, labeled Konan, being fabricated for K-Basin deployment. In addition to the manipulator, the camera viewing system, process table layout, and fuel handling processes were evaluated. The Conan test manipulator was installed and fully functional for testing in early 1997. Formal testing began May 1. The purposes of fuel handling development testing were to provide proof of concept and criteria, optimize equipment layout, initialize the process definition, and identify special needs/tools and required design changes to support development of the performance specification. The test program was set up to accomplish these objectives through cold (non-radiological) development testing using simulated and prototype equipment.

  17. Spent fuel assembly hardware: Characterization and 10 CFR 61 classification for waste disposal: Volume 3, Calculated activity profiles of spent nuclear fuel assembly hardware for boiling water reactors

    Energy Technology Data Exchange (ETDEWEB)

    Short, S.M.; Luksic, A.T.; Schutz, M.E.

    1989-06-01

    Consolidation of spent fuel is under active consideration as the US Department of Energy plans to dispose of spent fuel as required by the Nuclear Waste Policy Act of 1982. During consolidation, the fuel pins are removed from an intact fuel assembly and repackaged into a more compact configuration. After repackaging, approximately 30 kg of residual spent fuel assembly hardware per assembly that is also radioactive and required disposal. Understanding the nature of this secondary waste stream is critical to designing a system that will properly handle, package, store, and dispose of the waste. This report presents a methodology for estimating the radionuclide inventory in irradiated spent fuel hardware. Ratios are developed that allow the use of ORIGEN2 computer code calculations to be applied to regions that are outside the fueled region. The ratios are based on the analysis of samples of irradiated hardware from spent fuel assemblies. The results of this research are presented in three volumes. In Volume 1, the development of scaling factors that can be used with ORIGEN2 calculations to estimate activation of spent fuel assembly hardware is documented. The results from laboratory analysis of irradiated spent-fuel hardware samples are also presented in Volume 1. In Volume 2 and 3, the calculated flux profiles of spent nuclear fuel assemblies are presented for pressurized water reactors and boiling water reactors, respectively. The results presented in Volumes 2 and 3 were used to develop the scaling factors documented in Volume 1.

  18. Spent fuel assembly hardware: Characterization and 10 CFR 61 classification for waste disposal: Volume 1, Activation measurements and comparison with calculations for spent fuel assembly hardware

    Energy Technology Data Exchange (ETDEWEB)

    Luksic, A.

    1989-06-01

    Consolidation of spent fuel is under active consideration as the US Department of Energy plans to dispose of spent fuel. During consolidation, the fuel pins are removed from an intact fuel assembly and repackaged into a more compact configuration. After repackaging, approximately 30 kg of residual spent fuel assembly hardware per assembly remains that is also radioactive and requires disposal. Understanding the nature of this secondary waste stream is critical to designing a system that will properly handle, package, store, and dispose of the waste. This report presents a methodology for estimating the radionuclide inventory in irradiated spent fuel hardware. Ratios are developed that allow the use of ORIGEN2 computer code calculations to be applied to regions that are outside the fueled region. The ratios are based on the analysis of samples of irradiated hardware from spent fuel assemblies. The results of this research are presented in three volumes. In Volume 1, the development of scaling factors that can be used with ORIGEN2 calculations to estimate activation of spent fuel assembly hardware is documented. The results from laboratory analysis of irradiated spent-fuel hardware samples are also presented in Volume 1. In Volumes 2 and 3, the calculated flux profiles of spent nuclear fuel assemblies are presented for pressurized water reactors and boiling water reactors, respectively. The results presented in Volumes 2 and 3 were used to develop the scaling factors documented in Volume 1. 5 refs., 4 figs., 21 tabs.

  19. Spent fuel assembly hardware: Characterization and 10 CFR 61 classification for waste disposal: Volume 2, Calculated activity profiles of spent nuclear fuel assembly hardware for pressurized water reactors

    Energy Technology Data Exchange (ETDEWEB)

    Short, S.M.; Luksic, A.T.; Lotz, T.L.; Schutz, M.E.

    1989-06-01

    Consolidation of spent fuel is under active consideration as the US Department of Energy plans to dispose of spent fuel as required by the Nuclear Waste Policy Act of 1982. During consolidation, the fuel pins are removed from an intact fuel assembly and repackaged into a more compact configuration. After repackaging, approximately 30 kg of residual spent fuel assembly hardware per assembly remains that is also radioactive and requires disposal. Understanding the nature of this secondary waste stream is critical to designing a system that will properly handle, package, store, and dispose of the waste. This report present a methodology for estimating the radionuclide inventory in irradiated spent fuel hardware. Ratios are developed that allow the use of ORIGEN2 computer code calculations to be applied to regions that are outside the fueled region. The ratios are based on the analysis of samples of irradiated hardware from spent fuel assemblies. The results of this research are presented in three volumes. In Volume 1, the development of scaling factors that can be used with ORIGEN2 calculations to estimate activation of spent fuel assembly hardware is documented. The results from Laboratory analysis of irradiated spent-fuel hardware samples are also presented in Volume 1. In Volumes 2 and 3, the calculated flux profiles of spent nuclear fuel assemblies are presented for pressurized water reactors and boiling water reactors, respectively. The results presented in Volumes 2 and 3 were used to develop the scaling factors documented in Volume 1.

  20. Developing clean fuels: Novel techniques for desulfurization

    Science.gov (United States)

    Nehlsen, James P.

    The removal of sulfur compounds from petroleum is crucial to producing clean burning fuels. Sulfur compounds poison emission control catalysts and are the source of acid rain. New federal regulations require the removal of sulfur in both gasoline and diesel to very low levels, forcing existing technologies to be pushed into inefficient operating regimes. New technology is required to efficiently produce low sulfur fuels. Two processes for the removal of sulfur compounds from petroleum have been developed: the removal of alkanethiols by heterogeneous reaction with metal oxides; and oxidative desulfurization of sulfides and thiophene by reaction with sulfuric acid. Alkanethiols, common in hydrotreated gasoline, can be selectively removed and recovered from a hydrocarbon stream by heterogeneous reaction with oxides of Pb, Hg(II), and Ba. The choice of reactive metal oxides may be predicted from simple thermodynamic considerations. The reaction is found to be autocatalytic, first order in water, and zero order in thiol in the presence of excess oxide. The thiols are recovered by reactive extraction with dilute oxidizing acid. The potential for using polymer membrane hydrogenation reactors (PEMHRs) to perform hydrogenation reactions such as hydrodesulfurization is explored by hydrogenating ketones and olefins over Pt and Au group metals. The dependence of reaction rate on current density suggests that the first hydrogen addition to the olefin is the rate limiting step, rather than the adsorption of hydrogen, for all of the metals tested. PEMHRs proved unsuccessful in hydrogenating sulfur compounds to perform HDS. For the removal of sulfides, a two-phase reactor is used in which concentrated sulfuric acid oxidizes aromatic and aliphatic sulfides present in a hydrocarbon solvent, generating sulfoxides and other sulfonated species. The polar oxidized species are extracted into the acid phase, effectively desulfurizing the hydrocarbon. A reaction scheme is proposed for this

  1. Metallic Fuel Casting Development and Parameter Optimization Simulations

    Energy Technology Data Exchange (ETDEWEB)

    R.S. Fielding; J. Crapps; C. Unal; J.R. Kennedy

    2013-03-01

    One of the advantages of metallic fuel is the abilility to cast the fuel slugs to near net shape with little additional processing. However, the high aspect ratio of the fuel is not ideal for casting. EBR-II fuel was cast using counter gravity injection casting (CGIC) but, concerns have been raised concerning the feasibility of this process for americium bearing alloys. The Fuel Cycle Research and Development program has begun developing gravity casting techniques suitable for fuel production. Compared to CGIC gravity casting does not require a large heel that then is recycled, does not require application of a vacuum during melting, and is conducive to re-usable molds. Development has included fabrication of two separate benchscale, approximately 300 grams, systems. To shorten development time computer simulations have been used to ensure mold and crucible designs are feasible and to identify which fluid properties most affect casting behavior and therefore require more characterization.

  2. A Development of Ethanol/Percarbonate Membraneless Fuel Cell

    Directory of Open Access Journals (Sweden)

    M. Priya

    2014-01-01

    Full Text Available The electrocatalytic oxidation of ethanol on membraneless sodium percarbonate fuel cell using platinum electrodes in alkaline-acidic media is investigated. In this cell, ethanol is used as the fuel and sodium percarbonate is used as an oxidant for the first time in an alkaline-acidic media. Sodium percarbonate generates hydrogen peroxide in aqueous medium. At room temperature, the laminar-flow-based microfluidic membraneless fuel cell can reach a maximum power density of 18.96 mW cm−2 with a fuel mixture flow rate of 0.3 mL min−2. The developed fuel cell features no proton exchange membrane. The simple planar structured membraneless ethanol fuel cell presents with high design flexibility and enables easy integration of the microscale fuel cell into actual microfluidic systems and portable power applications.

  3. R and D activities on CANDU-type fuel in Indonesia

    Energy Technology Data Exchange (ETDEWEB)

    Suripto, A.; Badruzzaman, M.; Latief, A. [Nuclear Fuel Element Centre, National Atomic Energy Agency of Indonesia (BATAN), Puspiptek, Serpong (Indonesia)

    1997-07-01

    The status of R and D activities in Indonesia with respect of CANDU-type fuel development is presented. The activities have been started since the first feasibility study to introduce nuclear power plants was carried out in 1970s. The early research comprised the in-situ pilot production of yellow-cake in Kalimantan (Borneo) experimental mining site, uranium purification and pellet preparation. This program continued to gain a full support from the Government which culminated in the realisation of the construction by BATAN of a large fuel development laboratory in Serpong, starting from 1984 in co-operation with NIRA Ansaldo of Italy. The laboratory, which is called the Power Reactor Experimental Fuel Element Installation (EFEI) was originally designed as an experimental facility to integrate the acquired domestic R and D results gained so far on the CANDU-type fuel technology and the additional know-how received from NIRA Ansaldo which at that time was engaged, in developing a CANDU-type fuel, called the CIRENE fuel design. In the present days the facility houses the power reactor fuel development activities carried out to build up the national capability on power reactor fuel fabrication technology in anticipation to embark upon the nuclear energy era in the near future. (author)

  4. Electricity generation using chocolate industry wastewater and its treatment in activated sludge based microbial fuel cell and analysis of developed microbial community in the anode chamber.

    Science.gov (United States)

    Patil, Sunil A; Surakasi, Venkata Prasad; Koul, Sandeep; Ijmulwar, Shrikant; Vivek, Amar; Shouche, Y S; Kapadnis, B P

    2009-11-01

    Feasibility of using chocolate industry wastewater as a substrate for electricity generation using activated sludge as a source of microorganisms was investigated in two-chambered microbial fuel cell. The maximum current generated with membrane and salt bridge MFCs was 3.02 and 2.3 A/m(2), respectively, at 100 ohms external resistance, whereas the maximum current generated in glucose powered MFC was 3.1 A/m(2). The use of chocolate industry wastewater in cathode chamber was promising with 4.1 mA current output. Significant reduction in COD, BOD, total solids and total dissolved solids of wastewater by 75%, 65%, 68%, 50%, respectively, indicated effective wastewater treatment in batch experiments. The 16S rDNA analysis of anode biofilm and suspended cells revealed predominance of beta-Proteobacteria clones with 50.6% followed by unclassified bacteria (9.9%), alpha-Proteobacteria (9.1%), other Proteobacteria (9%), Planctomycetes (5.8%), Firmicutes (4.9%), Nitrospora (3.3%), Spirochaetes (3.3%), Bacteroides (2.4%) and gamma-Proteobacteria (0.8%). Diverse bacterial groups represented as members of the anode chamber community.

  5. Development of Advanced Spent Fuel Management Process

    Energy Technology Data Exchange (ETDEWEB)

    Seo, Chung Seok; Choi, I. K.; Kwon, S. G. (and others)

    2007-06-15

    As a part of research efforts to develop an advanced spent fuel management process, this project focused on the electrochemical reduction technology which can replace the original Li reduction technology of ANL, and we have successfully built a 20 kgHM/batch scale demonstration system. The performance tests of the system in the ACPF hot cell showed more than a 99% reduction yield of SIMFUEL, a current density of 100 mA/cm{sup 2} and a current efficiency of 80%. For an optimization of the process, the prevention of a voltage drop in an integrated cathode, a minimization of the anodic effect and an improvement of the hot cell operability by a modulation and simplization of the unit apparatuses were achieved. Basic research using a bench-scale system was also carried out by focusing on a measurement of the electrochemical reduction rate of the surrogates, an elucidation of the reaction mechanism, collecting data on the partition coefficients of the major nuclides, quantitative measurement of mass transfer rates and diffusion coefficients of oxygen and metal ions in molten salts. When compared to the PYROX process of INL, the electrochemical reduction system developed in this project has comparative advantages in its application of a flexible reaction mechanism, relatively short reaction times and increased process yields.

  6. Development and optimization of microbial fuel cells

    Energy Technology Data Exchange (ETDEWEB)

    Davila, D.; Vigues, N.; Sanchez, O.; Garrido, L.; Tomas, N.; Mas, J. [Univ. Autonoma de Barcelona, Barcelona (Spain). Dept. de Genetica y Microbiologia; Esquivel, J.P.; Sabate, N.; Del Campo, F.J.; Munoz, F.J. [Inst. de Microelectronica de Barcelona-CNM (CSIC), Barcelona (Spain)

    2008-04-15

    While global energy demand increases daily, fossil fuel sources are being depleted at an unsustainable pace. Fuel cells represent a solution as they are more efficient than other energy sources. A microbial fuel cell is an electrochemical device capable of continuously converting chemical energy into electrical energy for as long as adequate fuel and oxidant are available. A microbial fuel cell (MFC) adds the benefit of converting chemical energy from organic compounds, such as simple carbohydrates or organic waste matter, into electricity by using bacteria as biocatalysts. This article described the effect of several parameters that affect the operation of a microbial fuel cell (MFC). The study is based on a methodology utilized in previous studies which employed escherichia coli as biocatalyst and neutral red as the electron mediator in a mediated electron transfer (MET) microbial fuel cell. The study analysed the influence of the bacterial concentration, the effective area of electrode and the volume of the cell. It was concluded that there is a proportional energy production to the bacterial concentration present in the anode compartment. It was demonstrated that an increase in the volume of the cell negatively affects the power produced by the cells. 8 refs., 1 tab., 5 figs.

  7. Innovative membrane development for fuel cells

    CSIR Research Space (South Africa)

    Vaivars, G

    2011-10-01

    Full Text Available The innovative membranes for alternative energy devices will be presented. An electrical car is long waited solution to environmental and fuel supply problems in transport. Most probably, the shift from a combustion engine to an electrical car...

  8. What happens inside a fuel cell? Developing an experimental functional map of fuel cell performance.

    Science.gov (United States)

    Brett, Daniel J L; Kucernak, Anthony R; Aguiar, Patricia; Atkins, Stephen C; Brandon, Nigel P; Clague, Ralph; Cohen, Lesley F; Hinds, Gareth; Kalyvas, Christos; Offer, Gregory J; Ladewig, Bradley; Maher, Robert; Marquis, Andrew; Shearing, Paul; Vasileiadis, Nikos; Vesovic, Velisa

    2010-09-10

    Fuel cell performance is determined by the complex interplay of mass transport, energy transfer and electrochemical processes. The convolution of these processes leads to spatial heterogeneity in the way that fuel cells perform, particularly due to reactant consumption, water management and the design of fluid-flow plates. It is therefore unlikely that any bulk measurement made on a fuel cell will accurately represent performance at all parts of the cell. The ability to make spatially resolved measurements in a fuel cell provides one of the most useful ways in which to monitor and optimise performance. This Minireview explores a range of in situ techniques being used to study fuel cells and describes the use of novel experimental techniques that the authors have used to develop an 'experimental functional map' of fuel cell performance. These techniques include the mapping of current density, electrochemical impedance, electrolyte conductivity, contact resistance and CO poisoning distribution within working PEFCs, as well as mapping the flow of reactant in gas channels using laser Doppler anemometry (LDA). For the high-temperature solid oxide fuel cell (SOFC), temperature mapping, reference electrode placement and the use of Raman spectroscopy are described along with methods to map the microstructural features of electrodes. The combination of these techniques, applied across a range of fuel cell operating conditions, allows a unique picture of the internal workings of fuel cells to be obtained and have been used to validate both numerical and analytical models.

  9. Requirements to the procedure and stages of innovative fuel development

    Science.gov (United States)

    Troyanov, V.; Zabudko, L.; Grachyov, A.; Zhdanova, O.

    2016-04-01

    According to the accepted current understanding under the nuclear fuel we will consider the assembled active zone unit (Fuel assembly) with its structural elements, fuel rods, pellet column, structural materials of fuel rods and fuel assemblies. The licensing process includes justification of safe application of the proposed modifications, including design-basis and experimental justification of the modified items under normal operating conditions and in violation of normal conditions, including accidents as well. Besides the justification of modified units itself, it is required to show the influence of modifications on the performance and safety of the other Reactor Unit’ and Nuclear Plant’ elements (e.g. burst can detection system, transportation and processing operations during fuel handling), as well as to justify the new standards of fuel storage etc. Finally, the modified fuel should comply with the applicable regulations, which often becomes a very difficult task, if only because those regulations, such as the NP-082-07, are not covered modification issues. Making amendments into regulations can be considered as the only solution, but the process is complicated and requires deep grounds for amendments. Some aspects of licensing new nuclear fuel are considered the example of mixed nitride uranium -plutonium fuel application for the BREST reactor unit.

  10. Direct disposal of spent fuel: developing solutions tailored to Japan

    Energy Technology Data Exchange (ETDEWEB)

    Kawamura, Hideki [Obayashi Corporation, Tokyo (Japan); McKinley, Ian G [McKinley Consulting, Baden (Switzerland)

    2013-07-01

    With the past Government policy of 100% reprocessing in Japan now open to discussion, options for direct disposal of spent fuel (SF) are now being considered in Japan. The need to move rapidly ahead in developing spent fuel management concepts is closely related to the ongoing debate on the future of nuclear power in Japan and the desire to understand the true costs of the entire life cycle of different options. Different scenarios for future nuclear power - and associated decisions on extent of reprocessing - will give rise to quite different inventories of SF with different disposal challenges. Although much work has been carried out spent fuel disposal within other national programmes, the potential for mining the international knowledge base is limited by the boundary conditions for disposal in Japan. Indeed, with a volunteer approach to siting, no major salt deposits and few undisturbed sediments, high tectonic activity, relatively corrosive groundwater and no deserts, it is evident that a tailored solution is needed. Nevertheless, valuable lessons can be learned from projects carried out worldwide, if focus is placed on basic principles rather than implementation details. (authors)

  11. Nitride Fuel Development at the INL

    Energy Technology Data Exchange (ETDEWEB)

    W.E. Windes

    2007-06-01

    A new method for fabricating nitride-based fuels for nuclear applications is under development at the Idaho National Laboratory (INL). A primary objective of this research is the development of a process that could be operated as an automated or semi-automated technique reducing costs, worker doses, and eventually improving the final product form. To achieve these goals the fabrication process utilizes a new cryo-forming technique to produce microspheres formed from sub-micron oxide powder to improve material handling issues, yield rapid kinetics for conversion to nitrides, and reduced material impurity levels within the nitride compounds. The microspheres are converted to a nitride form within a high temperature particle fluidizing bed using a carbothermic process that utilizes a hydrocarbon – hydrogen - nitrogen gas mixture. A new monitor and control system using differential pressure changes in the fluidizing gas allows for real-time monitoring and control of the spouted bed reactor during conversion. This monitor and control system can provide real-time data that is used to control the gas flow rates, temperatures, and gas composition to optimize the fluidization of the particle bed. The small size (0.5 µm) of the oxide powders in the microspheres dramatically increases the kinetics of the conversion process yielding reduced process times and temperatures. Initial studies using surrogate ZrO2 powder have yielded conversion efficiencies of 90 -95 % nitride formation with only small levels of oxide and carbide contaminants present. Further studies are being conducted to determine optimal gas mixture ratios, process time, and temperature range for providing complete conversion to a nitride form.

  12. Development of advanced LWR fuel cladding

    Energy Technology Data Exchange (ETDEWEB)

    Jeong, Yong Hwan; Park, S. Y.; Lee, M. H. [and others

    2000-04-01

    This report describes the results from evaluating the preliminary Zr-based alloys to develop the advanced Zr-based alloys for the nuclear fuel claddings, which should have good corrosion resistance and mechanical properties at high burn-up over 70,000MWD/MTU. It also includes the results from the basic studies for optimizing the processes which are involved in the development of the advanced Zr-based alloys. Ten(10) kinds of candidates for the alloys of which performance is over that of the existing Zircaloy-4 or ZIRLO alloy were selected out of the preliminary alloys of 150 kinds which were newly designed and repeatedly manufactured and evaluated to find out the promising alloys. First of all, the corrosion tests on the preliminary alloys were carried out to evaluate their performance in both pure water and LiOH solution at 360 deg C and in steam at 400 deg C. The tensile tests were performed on the alloys which proved to be good in the corrosion resistance. The creep behaviors were tested at 400 deg C for 10 days with the application of constant load on the samples which showed good performance in the corrosion resistance and tensile properties. The effect of the final heat treatment and A-parameters as well as Sn or Nb on the corrosion resistance, tensile properties, hardness, microstructures of the alloys was evaluated for some alloys interested. The other basic researches on the oxides, electrochemical properties, corrosion mechanism, and the establishment of the phase diagrams of some alloys were also carried out.

  13. Development of information management system on LWR spent fuel

    Energy Technology Data Exchange (ETDEWEB)

    Lee, B. D.; Lee, S. H.; Song, D. Y.; Jeon, I.; Park, S. J.; Seo, D. S. [KAERI, Taejon (Korea, Republic of)

    2002-10-01

    LWRs in Korea should manage all the information of spent fuel to implement the obligations under Korea-IAEA safeguards agreement and to perform the nuclear material accountancy work at the facility level. The information management system on LWR spent fuel was developed to manage all movement records from receipt to shipment of LWR fuels, and to get the necessary information such as nuclear fuel inventory lists and status, maps of fresh fuel storage, reactor and spent fuel pool, receipt and shipment records and so on. This information management system has a function to setup the system environments to cover the various kinds of storage types for all LWRs ; reactor, spent fuel pool and fresh fuel storage. The movements of nuclear fuel between the storages can be easily done by double click of the mouse to the destination. It also has a several error checking routines for maintaining the correct accounting data. Using this information management system of LWR spent fuel, facility operators can perform efficiently and effectively the safeguards related works including nuclear material accountancy at each facility.

  14. Learning FuelPHP for effective PHP development

    CERN Document Server

    Tweedie, Ross

    2013-01-01

    The book follows a standard tutorial approach, which will enable readers to use the FuelPHP framework efficiently while developing PHP applications.If you are a PHP developer who is looking to learn more about using the FuelPHP framework for effective PHP development, this book is ideal for you. If you are interested in this book, you should already have a basic understanding of general PHP development.

  15. Development of fuel performance and thermal hydraulic technology

    Energy Technology Data Exchange (ETDEWEB)

    Jung, Youn Ho; Song, K. N.; Kim, H. K. and others

    2000-03-01

    Space grid in LWR fuel assembly is a key structural component to support fuel rods and to enhance heat transfer from fuel rod to the coolant. Therefore, the original spacer grid has been developed. In addition, new phenomena in fuel behavior occurs at the high burnup, so that models to analyze those new phenomena were developed. Results of this project can be summarized as follows. - Seven different spacer grid candidates have been invented and submitted for domestic and US patents. Spacer grid test specimen(3x3 array and 5x5 array) were fabricated for each candidate and the mechanical tests were performed. - Basic technologies in the mechanical and thermal hydraulic behavior in the spacer grid development are studied and relevant test facilities were established - Fuel performance analysis models and programs were developed for the high burnup pellet and cladding, and fuel performance data base were compiled - Procedures of fuel characterization and in-/out of-pile tests were prepared - Conceptual design of fuel rod for integral PWR was carried out. (author)

  16. Microbial biocatalyst developments to upgrade fossil fuels.

    Science.gov (United States)

    Kilbane, John J

    2006-06-01

    Steady increases in the average sulfur content of petroleum and stricter environmental regulations concerning the sulfur content have promoted studies of bioprocessing to upgrade fossil fuels. Bioprocesses can potentially provide a solution to the need for improved and expanded fuel upgrading worldwide, because bioprocesses for fuel upgrading do not require hydrogen and produce far less carbon dioxide than thermochemical processes. Recent advances have demonstrated that biodesulfurization is capable of removing sulfur from hydrotreated diesel to yield a product with an ultra-low sulfur concentration that meets current environmental regulations. However, the technology has not yet progressed beyond laboratory-scale testing, as more efficient biocatalysts are needed. Genetic studies to obtain improved biocatalysts for the selective removal of sulfur and nitrogen from petroleum provide the focus of current research efforts.

  17. Fission products, activity calculation of spent-fuel

    Energy Technology Data Exchange (ETDEWEB)

    Souka, N.; El-Hakiem, M.N.

    1981-01-01

    This work is a scrutiny of the activity of burned up fuel elements of the ET-RR-1. A knowledge of this activity as well as its decay with time is quite helpful in shielding calculations related to construction purposes of hot facilities. The present treatment is based on a knowledge of: fuel composition, percentage burnup, and fission yields of produced isotopes. Cooling periods ranging from 1 hr to 10 years were considered.

  18. International Source Book: Nuclear Fuel Cycle Research and Development Vol 1 Volume 1

    Energy Technology Data Exchange (ETDEWEB)

    Harmon, K. M. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Lakey, L. T. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

    1983-07-01

    This document starts with an overview that summarizes nuclear power policies and waste management activities for nations with significant commercial nuclear fuel cycle activities either under way or planned. A more detailed program summary is then included for each country or international agency conducting nuclear fuel cycle and waste management research and development. This first volume includes the overview and the program summaries of those countries listed alphabetically from Argentina to Italy.

  19. Development of a methanol reformer for fuel cell vehicles

    Energy Technology Data Exchange (ETDEWEB)

    Lindstroem, Baard

    2003-03-01

    Vehicles powered by fuel cells are from an environmental aspect superior to the traditional automobile using internal combustion of gasoline. Power systems which are based upon fuel cell technology require hydrogen for operation. The ideal fuel cell vehicle would operate on pure hydrogen stored on-board. However, storing hydrogen on-board the vehicle is currently not feasible for technical reasons. The hydrogen can be generated on-board using a liquid hydrogen carrier such as methanol and gasoline. The objective of the work presented in this thesis was to develop a catalytic hydrogen generator for automotive applications using methanol as the hydrogen carrier. The first part of this work gives an introduction to the field of methanol reforming and the properties of a fuel cell based power system. Paper I reviews the catalytic materials and processes available for producing hydrogen from methanol. The second part of this thesis consists of an experimental investigation of the influence of the catalyst composition, materials and process parameters on the activity and selectivity for the production of hydrogen from methanol. In Papers II-IV the influence of the support, carrier and operational parameters is studied. In Paper V an investigation of the catalytic properties is performed in an attempt to correlate material properties with performance of different catalysts. In the third part of the thesis an investigation is performed to elucidate whether it is possible to utilize oxidation of liquid methanol as a heat source for an automotive reformer. In the study which is presented in Paper VI a large series of catalytic materials are tested and we were able to minimize the noble metal content making the system more cost efficient. In the final part of this thesis the reformer prototype developed in the project is evaluated. The reformer which was constructed for serving a 5 k W{sub e} fuel cell had a high performance with near 100 % methanol conversion and CO

  20. Development of surface enhanced Raman scattering (SERS) spectroscopy monitoring of fuel markers to prevent fraud

    Science.gov (United States)

    Wilkinson, Timothy; Clarkson, John; White, Peter C.; Meakin, Nicholas; McDonald, Ken

    2013-05-01

    Governments often tax fuel products to generate revenues to support and stimulate their economies. They also subsidize the cost of essential fuel products. Fuel taxation and subsidization practices are both subject to fraud. Oil marketing companies also suffer from fuel fraud with loss of legitimate sales and additional quality and liability issues. The use of an advanced marking system to identify and control fraud has been shown to be effective in controlling illegal activity. DeCipher has developed surface enhanced Raman scattering (SERS) spectroscopy as its lead technology for measuring markers in fuel to identify and control malpractice. SERS has many advantages that make it highly suitable for this purpose. The SERS instruments are portable and can be used to monitor fuel at any point in the supply chain. SERS shows high specificity for the marker, with no false positives. Multiple markers can also be detected in a single SERS analysis allowing, for example, specific regional monitoring of fuel. The SERS analysis from fuel is also quick, clear and decisive, with a measurement time of less than 5 minutes. We will present results highlighting our development of the use of a highly stable silver colloid as a SERS substrate to measure the markers at ppb levels. Preliminary results from the use of a solid state SERS substrate to measure fuel markers will also be presented.

  1. On-site fuel inspection experience and developments in Spain

    Energy Technology Data Exchange (ETDEWEB)

    Sanchez, A.; Alvarez, P. [ENUSA Industrias Avanzadas SA, Fuel Services, C. Salamanca-Vitigudino km 0, 70, 37008 Salamanca (Spain); Fernandez, J.R.; Mendez, M. [TECNATOM SA, Steam Generators and Nuclear Fuel, Av. Montes de Oca no. 1, 28703 San Sebastian de los Reyes, Madrid (Spain)

    2010-07-01

    Fuel performance characterization is essential to assure that new fuel designs and plant changes do not lead to unexpected fuel behaviour. Additionally, measurement of fuel key features is basic for the development of accurate design models needed for licensing purposes when a new fuel design is being proposed. Due to the fact that pool-side inspections are more economical and less time consuming than post irradiation examinations conducted in hot cell facilities it has been necessary to develop reliable equipments able to measure with a sufficient accuracy the main characteristics of irradiated fuel behaviour. Since 1994 ENUSA Industrias Avanzadas SA and TECNATOM are working together to develop the capacities for fuel inspection within the SICOM (Spanish acronym for Fuel Inspection System) family of equipments. Non-Destructive methods (NDE) such as eddy current for oxide thickness determination and defects characterization, and LVDT (Linear Variable Differential Transformer) for dimensional analysis are the main techniques used in the equipments, supported with visual inspections, although new techniques for additional characteristics evaluation are currently being introduced. (authors)

  2. Research Development of MOX Fuel Element Technology

    Institute of Scientific and Technical Information of China (English)

    YANG; Qi-fa; YANG; Ting-gui; SHANG; Gai-bin; YIN; Bang-yue; ZHOU; Guo-liang; LI; Qiang; JIANG; Bao-jun

    2015-01-01

    The project of"MOX Fuel Element Research"led by China Institute of Atomic Energy,404Company Ltd.and CNPE Zhengzhou Branch are members of the project research team.The research task of 2015had been accomplished successfully,and the research productions of this year build up a basis for the future research,also

  3. State-of-the-Art Remote Robotic Systems in the DUPIC Fuel Development

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Ki Ho; Park, Jang Jin; Yang, Myung Seung [Korea Atomic Energy Research Institute, Taejon (Korea, Republic of)

    2005-07-01

    DUPIC (Direct Use of PWR fuel in CANDU reactors) fuel cycle technology is being developed in the DUPIC Fuel Development Facility (DFDF) at the Korea Atomic Energy Research Institute (KAERI). The DFDF is a completely shielded M6 hot-cell and isolation room of the IMEF (Irradiated Material Examination Facility). As the DFDF hot-cell is active, direct human access to the in-cell is not possible because of the nature of the high radioactivity of the spent PWR fuel. All the DUPIC fuel fabrication processes and equipment operations, therefore, are conducted in a fully remote manner. Undesirable products such as spent nuclear fuel powder debris and contaminated wastes are inevitably produced during the DUPIC fuel development processes. They are deposited on the DUPIC fuel fabrication equipment and the inside floor and wall of the DFDF hot-cell and the isolation room's floor, thereby contaminating the interior of the DFDF. Such radioactive waste is required to be cleaned and disposed of to prevent the contamination from spreading inside the DFDF. The objective of this paper was to develop the remote robotic systems for a decontamination to be used in the highly radioactive zone of the DFDF, thereby completely eliminating a human's interaction with hazardous radioactive contaminants.

  4. Development of a Reliable Fuel Depletion Methodology for the HTR-10 Spent Fuel Analysis

    Energy Technology Data Exchange (ETDEWEB)

    Chung, Kiwhan [Los Alamos National Laboratory; Beddingfield, David H. [Los Alamos National Laboratory; Geist, William H. [Los Alamos National Laboratory; Lee, Sang-Yoon [unaffiliated

    2012-07-03

    A technical working group formed in 2007 between NNSA and CAEA to develop a reliable fuel depletion method for HTR-10 based on MCNPX and to analyze the isotopic inventory and radiation source terms of the HTR-10 spent fuel. Conclusions of this presentation are: (1) Established a fuel depletion methodology and demonstrated its safeguards application; (2) Proliferation resistant at high discharge burnup ({approx}80 GWD/MtHM) - Unfavorable isotopics, high number of pebbles needed, harder to reprocess pebbles; (3) SF should remain under safeguards comparable to that of LWR; and (4) Diversion scenarios not considered, but can be performed.

  5. Thoria development activities. Annual report, fiscal year 1978

    Energy Technology Data Exchange (ETDEWEB)

    Hart, P.E.

    1979-02-01

    Pacific Northwest Laboratory's (PNL) ThO/sub 2/ development activities for FY-1978 are reviewed. These activities are in support of the FRAD (Fuels Refabrication and Development) program's goal of developing proliferation resistant fuel cycles. Included are results for the five ThO/sub 2/ fuel related elements that are assigned to PNL. During FY-1978, work on these elements has been directed primarily toward establishing the TOFDL (Thorium Oxide Fuel Development Laboratory) facility where unit operations for ThO/sub 2/-based fuels will be defined and fuels for test irradiations fabricated. Additional activities include evaluation of ThO/sub 2/ powders derived by various oxalate precipitation conditions, the fabricability of commercially available ThO/sub 2/ powders, hybrid pellet fuel fabrication and definition of an irradiation test plan.

  6. Development of Green Fuels From Algae - The University of Tulsa

    Energy Technology Data Exchange (ETDEWEB)

    Crunkleton, Daniel; Price, Geoffrey; Johannes, Tyler; Cremaschi, Selen

    2012-12-03

    The general public has become increasingly aware of the pitfalls encountered with the continued reliance on fossil fuels in the industrialized world. In response, the scientific community is in the process of developing non-fossil fuel technologies that can supply adequate energy while also being environmentally friendly. In this project, we concentrate on green fuels which we define as those capable of being produced from renewable and sustainable resources in a way that is compatible with the current transportation fuel infrastructure. One route to green fuels that has received relatively little attention begins with algae as a feedstock. Algae are a diverse group of aquatic, photosynthetic organisms, generally categorized as either macroalgae (i.e. seaweed) or microalgae. Microalgae constitute a spectacularly diverse group of prokaryotic and eukaryotic unicellular organisms and account for approximately 50% of global organic carbon fixation. The PI's have subdivided the proposed research program into three main research areas, all of which are essential to the development of commercially viable algae fuels compatible with current energy infrastructure. In the fuel development focus, catalytic cracking reactions of algae oils is optimized. In the species development project, genetic engineering is used to create microalgae strains that are capable of high-level hydrocarbon production. For the modeling effort, the construction of multi-scaled models of algae production was prioritized, including integrating small-scale hydrodynamic models of algae production and reactor design and large-scale design optimization models.

  7. Development of Techniques for Spent Fuel Assay – Differential Dieaway Final Report

    Energy Technology Data Exchange (ETDEWEB)

    Swinhoe, Martyn Thomas [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Goodsell, Alison [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Ianakiev, Kiril Dimitrov [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Iliev, Metodi [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Desimone, David J. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Rael, Carlos D. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Henzl, Vladimir [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Polk, Paul John [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

    2016-07-28

    This report summarizes the work done under a DNDO R&D funded project on the development of the differential dieaway method to measure plutonium in spent fuel. There are large amounts of plutonium that are contained in spent fuel assemblies, and currently there is no way to make quantitative non-destructive assay. This has led NA24 under the Next Generation Safeguards Initiative (NGSI) to establish a multi-year program to investigate, develop and implement measurement techniques for spent fuel. The techniques which are being experimentally tested by the existing NGSI project do not include any pulsed neutron active techniques. The present work covers the active neutron differential dieaway technique and has advanced the state of knowledge of this technique as well as produced a design for a practical active neutron interrogation instrument for spent fuel. Monte Carlo results from the NGSI effort show that much higher accuracy (1-2%) for the Pu content in spent fuel assemblies can be obtained with active neutron interrogation techniques than passive techniques, and this would allow their use for nuclear material accountancy independently of any information from the operator. The main purpose of this work was to develop an active neutron interrogation technique for spent nuclear fuel.

  8. Development of machine vision system for PHWR fuel pellet inspection

    Energy Technology Data Exchange (ETDEWEB)

    Kamalesh Kumar, B.; Reddy, K.S.; Lakshminarayana, A.; Sastry, V.S.; Ramana Rao, A.V. [Nuclear Fuel Complex, Hyderabad, Andhra Pradesh (India); Joshi, M.; Deshpande, P.; Navathe, C.P.; Jayaraj, R.N. [Raja Ramanna Centre for Advanced Technology, Indore, Madhya Pradesh (India)

    2008-07-01

    Nuclear Fuel Complex, a constituent of Department of Atomic Energy; India is responsible for manufacturing nuclear fuel in India . Over a million Uranium-di-oxide pellets fabricated per annum need visual inspection . In order to overcome the limitations of human based visual inspection, NFC has undertaken the development of machine vision system. The development involved designing various subsystems viz. mechanical and control subsystem for handling and rotation of fuel pellets, lighting subsystem for illumination, image acquisition system, and image processing system and integration. This paper brings out details of various subsystems and results obtained from the trials conducted. (author)

  9. 2010 Hydrogen and Fuel Cell Global Commercialization & Development Update

    Energy Technology Data Exchange (ETDEWEB)

    none,

    2010-11-01

    This report offers examples of real-world applications and technical progress of hydrogen and fuel cell technologies, including policies adopted by countries to increase technology development and commercialization.

  10. Used fuel disposition research and development roadmap - FY10 status.

    Energy Technology Data Exchange (ETDEWEB)

    Nutt, W. M. (Nuclear Engineering Division)

    2010-10-01

    Since 1987 the U.S. has focused research and development activities relevant to the disposal of commercial used nuclear fuel and U.S. Department of Energy (DOE) owned spent nuclear fuel and high level waste on the proposed repository at Yucca Mountain, Nevada. At the same time, the U.S. successfully deployed a deep geologic disposal facility for defense-related transuranic waste in bedded salt at the Waste Isolation Pilot Plant. In 2009 the DOE established the Used Fuel Disposition Campaign (UFDC) within the Office of Nuclear Energy. The Mission of the UFDC is to identify alternatives and conduct scientific research and technology development to enable storage, transportation and disposal of used nuclear fuel and wastes generated by existing and future nuclear fuel cycles. The U.S. national laboratories have participated on these programs and has conducted research and development related to these issues to a limited extent. However, a comprehensive research and development (R&D) program investigating a variety of geologic media has not been a part of the U.S. waste management program since the mid 1980s. Such a comprehensive R&D program is being developed in the UFDC with a goal of meeting the UFDC Grand Challenge to provide a sound technical basis for absolute confidence in the safety and security of long-term storage, transportation, and disposal of used nuclear fuel and wastes from the nuclear energy enterprise. The DOE has decided to no longer pursue the development of a repository at Yucca Mountain, Nevada. Since a repository site will ultimately have to be selected, sited, characterized, designed, and licensed, other disposal options must now be considered. In addition to the unsaturated volcanic tuff evaluated at Yucca Mountain, several different geologic media are under investigation internationally and preliminary assessments indicate that disposal of used nuclear fuel and high level waste in these media is feasible. Considerable progress has been made in

  11. Fuel cell technology development forges ahead

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    @@ On 11 June, 2006, a bright red sightseeing van attracted much attention at the Xinghai Square in Dalian, a coastal city of northeast China's Liaoning Province. This is no ordinary tour coach, as it is jointly driven by fuel cells (FC) and storage batteries. Acting as its "heart," the FC system could generate electricity not only for driving the mini-coach, but also for re-charging the storage battery system when excess power is yielded.

  12. DEVELOPMENT OF ALTERNATIVE FUELS AND CHEMICALS FROM SYNTHESIS GAS

    Energy Technology Data Exchange (ETDEWEB)

    Peter J. Tijrn

    2003-05-31

    This Final Report for Cooperative Agreement No. DE-FC22-95PC93052, the ''Development of Alternative Fuels and Chemicals from Synthesis Gas,'' was prepared by Air Products and Chemicals, Inc. (Air Products), and covers activities from 29 December 1994 through 31 July 2002. The overall objectives of this program were to investigate potential technologies for the conversion of synthesis gas (syngas), a mixture primarily of hydrogen (H{sub 2}) and carbon monoxide (CO), to oxygenated and hydrocarbon fuels and industrial chemicals, and to demonstrate the most promising technologies at the LaPorte, Texas Alternative Fuels Development Unit (AFDU). Laboratory work was performed by Air Products and a variety of subcontractors, and focused on the study of the kinetics of production of methanol and dimethyl ether (DME) from syngas, the production of DME using the Liquid Phase Dimethyl Ether (LPDME{trademark}) Process, the conversion of DME to fuels and chemicals, and the production of other higher value products from syngas. Four operating campaigns were performed at the AFDU during the performance period. Tests of the Liquid Phase Methanol (LPMEOH{trademark}) Process and the LPDME{trademark} Process were made to confirm results from the laboratory program and to allow for the study of the hydrodynamics of the slurry bubble column reactor (SBCR) at a significant engineering scale. Two campaigns demonstrated the conversion of syngas to hydrocarbon products via the slurry-phase Fischer-Tropsch (F-T) process. Other topics that were studied within this program include the economics of production of methyl tert-butyl ether (MTBE), the identification of trace components in coal-derived syngas and the means to economically remove these species, and the study of systems for separation of wax from catalyst in the F-T process. The work performed under this Cooperative Agreement has continued to promote the development of technologies that use clean syngas produced

  13. DEVELOPMENT OF ALTERNATIVE FUELS AND CHEMICALS FROM SYNTHESIS GAS

    Energy Technology Data Exchange (ETDEWEB)

    Peter J. Tijrn

    2003-05-31

    This Final Report for Cooperative Agreement No. DE-FC22-95PC93052, the ''Development of Alternative Fuels and Chemicals from Synthesis Gas,'' was prepared by Air Products and Chemicals, Inc. (Air Products), and covers activities from 29 December 1994 through 31 July 2002. The overall objectives of this program were to investigate potential technologies for the conversion of synthesis gas (syngas), a mixture primarily of hydrogen (H{sub 2}) and carbon monoxide (CO), to oxygenated and hydrocarbon fuels and industrial chemicals, and to demonstrate the most promising technologies at the LaPorte, Texas Alternative Fuels Development Unit (AFDU). Laboratory work was performed by Air Products and a variety of subcontractors, and focused on the study of the kinetics of production of methanol and dimethyl ether (DME) from syngas, the production of DME using the Liquid Phase Dimethyl Ether (LPDME{trademark}) Process, the conversion of DME to fuels and chemicals, and the production of other higher value products from syngas. Four operating campaigns were performed at the AFDU during the performance period. Tests of the Liquid Phase Methanol (LPMEOH{trademark}) Process and the LPDME{trademark} Process were made to confirm results from the laboratory program and to allow for the study of the hydrodynamics of the slurry bubble column reactor (SBCR) at a significant engineering scale. Two campaigns demonstrated the conversion of syngas to hydrocarbon products via the slurry-phase Fischer-Tropsch (F-T) process. Other topics that were studied within this program include the economics of production of methyl tert-butyl ether (MTBE), the identification of trace components in coal-derived syngas and the means to economically remove these species, and the study of systems for separation of wax from catalyst in the F-T process. The work performed under this Cooperative Agreement has continued to promote the development of technologies that use clean syngas produced

  14. Design & development of innovative proton exchange membrane fuel cells

    OpenAIRE

    Carton, James

    2011-01-01

    The research undertaken in this thesis is concerned with the design and development of Proton Exchange Membrane (PEM) fuel cells and provides a body of information for continued PEM fuel cell development, which will ideally aid in the future commercialisation of these electrochemical devices. Through a combination of numerical analysis, computational fluid dynamic modelling and experimental work, effective flow plate designs, flow field configurations and materials are analysed and new inn...

  15. What Happens Inside a Fuel Cell? Developing an Experimental Functional Map of Fuel Cell Performance

    KAUST Repository

    Brett, Daniel J. L.

    2010-08-20

    Fuel cell performance is determined by the complex interplay of mass transport, energy transfer and electrochemical processes. The convolution of these processes leads to spatial heterogeneity in the way that fuel cells perform, particularly due to reactant consumption, water management and the design of fluid-flow plates. It is therefore unlikely that any bulk measurement made on a fuel cell will accurately represent performance at all parts of the cell. The ability to make spatially resolved measurements in a fuel cell provides one of the most useful ways in which to monitor and optimise performance. This Minireview explores a range of in situ techniques being used to study fuel cells and describes the use of novel experimental techniques that the authors have used to develop an \\'experimental functional map\\' of fuel cell performance. These techniques include the mapping of current density, electrochemical impedance, electrolyte conductivity, contact resistance and CO poisoning distribution within working PEFCs, as well as mapping the flow of reactant in gas channels using laser Doppler anemometry (LDA). For the high-temperature solid oxide fuel cell (SOFC), temperature mapping, reference electrode placement and the use of Raman spectroscopy are described along with methods to map the microstructural features of electrodes. The combination of these techniques, applied across a range of fuel cell operating conditions, allows a unique picture of the internal workings of fuel cells to be obtained and have been used to validate both numerical and analytical models. © 2010 Wiley-VCH Verlag GmbH& Co. KGaA, Weinheim.

  16. DUPIC nuclear fuel manufacturing and process technology development

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Jung Won; Yang, M. S.; Kim, S. S. [and others

    2002-05-01

    In this study, the DUPIC fuel fabrication technology for DUPIC pellet and element satisfying the standard specification was verified through (1) the improvement of fabrication technology and equipment, (2) remote operation of fuel manufacturing and inspection equipment installed at DFDF and (3) the study on the material properties of DUPIC fuel. The blending process was newly developed for making DUPIC powder composition homogeneous, and mixing process was added to the DUPIC process flow for fabricating crack-free pellets. A series of fabrication experiments were carried out in terms of various process conditions. Based on these experimental results, the optimal process flow and conditions for DUPIC fuel fabrication were established. 6 DUPIC elements and 6 mini-elements for irradiation test in HANARO was successfully fabricated using 7.4 kg of spent PWR fuel in 2000. The process qualification tests has been performed using 10 kg of spent PWR fuel since May 2001. The optimal DUPIC fuel fabrication process meeting AECL's quality requirements has been established and qualified. Quality assurance system for DUPIC fuel fabrication was also established in cooperation of AECL.

  17. Performance Evaluation of a High Bandwidth Liquid Fuel Modulation Valve for Active Combustion Control

    Science.gov (United States)

    Saus, Joseph R.; DeLaat, John C.; Chang, Clarence T.; Vrnak, Daniel R.

    2012-01-01

    At the NASA Glenn Research Center, a characterization rig was designed and constructed for the purpose of evaluating high bandwidth liquid fuel modulation devices to determine their suitability for active combustion control research. Incorporated into the rig s design are features that approximate conditions similar to those that would be encountered by a candidate device if it were installed on an actual combustion research rig. The characterized dynamic performance measures obtained through testing in the rig are planned to be accurate indicators of expected performance in an actual combustion testing environment. To evaluate how well the characterization rig predicts fuel modulator dynamic performance, characterization rig data was compared with performance data for a fuel modulator candidate when the candidate was in operation during combustion testing. Specifically, the nominal and off-nominal performance data for a magnetostrictive-actuated proportional fuel modulation valve is described. Valve performance data were collected with the characterization rig configured to emulate two different combustion rig fuel feed systems. Fuel mass flows and pressures, fuel feed line lengths, and fuel injector orifice size was approximated in the characterization rig. Valve performance data were also collected with the valve modulating the fuel into the two combustor rigs. Comparison of the predicted and actual valve performance data show that when the valve is operated near its design condition the characterization rig can appropriately predict the installed performance of the valve. Improvements to the characterization rig and accompanying modeling activities are underway to more accurately predict performance, especially for the devices under development to modulate fuel into the much smaller fuel injectors anticipated in future lean-burning low-emissions aircraft engine combustors.

  18. Used fuel disposition research and development roadmap - FY10 status.

    Energy Technology Data Exchange (ETDEWEB)

    Nutt, W. M. (Nuclear Engineering Division)

    2010-10-01

    Since 1987 the U.S. has focused research and development activities relevant to the disposal of commercial used nuclear fuel and U.S. Department of Energy (DOE) owned spent nuclear fuel and high level waste on the proposed repository at Yucca Mountain, Nevada. At the same time, the U.S. successfully deployed a deep geologic disposal facility for defense-related transuranic waste in bedded salt at the Waste Isolation Pilot Plant. In 2009 the DOE established the Used Fuel Disposition Campaign (UFDC) within the Office of Nuclear Energy. The Mission of the UFDC is to identify alternatives and conduct scientific research and technology development to enable storage, transportation and disposal of used nuclear fuel and wastes generated by existing and future nuclear fuel cycles. The U.S. national laboratories have participated on these programs and has conducted research and development related to these issues to a limited extent. However, a comprehensive research and development (R&D) program investigating a variety of geologic media has not been a part of the U.S. waste management program since the mid 1980s. Such a comprehensive R&D program is being developed in the UFDC with a goal of meeting the UFDC Grand Challenge to provide a sound technical basis for absolute confidence in the safety and security of long-term storage, transportation, and disposal of used nuclear fuel and wastes from the nuclear energy enterprise. The DOE has decided to no longer pursue the development of a repository at Yucca Mountain, Nevada. Since a repository site will ultimately have to be selected, sited, characterized, designed, and licensed, other disposal options must now be considered. In addition to the unsaturated volcanic tuff evaluated at Yucca Mountain, several different geologic media are under investigation internationally and preliminary assessments indicate that disposal of used nuclear fuel and high level waste in these media is feasible. Considerable progress has been made in

  19. Development of biomass fueled stirling engine; Udvikling af biomassefyret stirlingmotor

    Energy Technology Data Exchange (ETDEWEB)

    Carlsen, H.; Bovin, J.

    2001-04-01

    The report treats the development of a stirling engine with an electric effect of 35 kW for small local cogeneration plants, which use wood chips as fuel. The development of the stirling engine, which is named SM3B, is based on the results from an earlier project, where a stirling engine (SM3A) with the same fundamental construction was developed and tested. The report treats the whole development with focus on the activities relating to the further development of the SM3A-engine to SM3B. The developed stirling engines have four double-acting cylinders. The four heat exchangers, to which the heat from the combustion of wood chips is supplied, make a quadratic combustion chamber above the engine. The heat exchangers are constructed in taking into account that solid fuels are used, and they are therefore made of strong pipes and narrow passages are avoided, so that particles in the flue gasses do not clog the heat exchangers. The stirling engine itself is constructed as a hermetic unity, where the generator is built into a pressurized crankcase in the same way as the electricity engine is built into a hermetic refrigeration compressor. Thus the leakage of work gas being helium these engines can be reduced to a minimum. The maximal electric effect for the first stirling engine, SM3A, was 28 kW, which was a little less than expected. The efficiency was about 18% depending on moisture content of the fuel. This engine has run for over 1400 hours with wood chip as fuel, but not without problems. In relation to the first stirling engine for biofuels (SM3A) the following have been obtained by the development of the new 35 kW-engine (SM3B): Electric-effect is improved from 28 kW to 34 kW by the same temperatures in heater and cooling water; The engine has ran satisfactorily for about 800 hours without mechanical problems; More noiseless; Better distribution of the thermic loading of the heater; Piston rods and crosshead connections are strengthened; The piston rod

  20. Intermediate Temperature Solid Oxide Fuel Cell Development

    Energy Technology Data Exchange (ETDEWEB)

    S. Elangovan; Scott Barnett; Sossina Haile

    2008-06-30

    Solid oxide fuel cells (SOFCs) are high efficiency energy conversion devices. Present materials set, using yttria stabilized zirconia (YSZ) electrolyte, limit the cell operating temperatures to 800 C or higher. It has become increasingly evident however that lowering the operating temperature would provide a more expeditious route to commercialization. The advantages of intermediate temperature (600 to 800 C) operation are related to both economic and materials issues. Lower operating temperature allows the use of low cost materials for the balance of plant and limits degradation arising from materials interactions. When the SOFC operating temperature is in the range of 600 to 700 C, it is also possible to partially reform hydrocarbon fuels within the stack providing additional system cost savings by reducing the air preheat heat-exchanger and blower size. The promise of Sr and Mg doped lanthanum gallate (LSGM) electrolyte materials, based on their high ionic conductivity and oxygen transference number at the intermediate temperature is well recognized. The focus of the present project was two-fold: (a) Identify a cell fabrication technique to achieve the benefits of lanthanum gallate material, and (b) Investigate alternative cathode materials that demonstrate low cathode polarization losses at the intermediate temperature. A porous matrix supported, thin film cell configuration was fabricated. The electrode material precursor was infiltrated into the porous matrix and the counter electrode was screen printed. Both anode and cathode infiltration produced high performance cells. Comparison of the two approaches showed that an infiltrated cathode cells may have advantages in high fuel utilization operations. Two new cathode materials were evaluated. Northwestern University investigated LSGM-ceria composite cathode while Caltech evaluated Ba-Sr-Co-Fe (BSCF) based pervoskite cathode. Both cathode materials showed lower polarization losses at temperatures as low as 600

  1. The J-2X Fuel Turbopump - Design, Development, and Test

    Science.gov (United States)

    Tellier, James G.; Hawkins, Lakiesha V.; Shinguchi, Brian H.; Marsh, Matthew W.

    2011-01-01

    Pratt and Whitney Rocketdyne (PWR), a NASA subcontractor, is executing the design, development, test, and evaluation (DDT&E) of a liquid oxygen, liquid hydrogen two hundred ninety four thousand pound thrust rocket engine initially intended for the Upper Stage (US) and Earth Departure Stage (EDS) of the Constellation Program Ares-I Crew Launch Vehicle (CLV). A key element of the design approach was to base the new J-2X engine on the heritage J-2S engine with the intent of uprating the engine and incorporating SSME and RS-68 lessons learned. The J-2S engine was a design upgrade of the flight proven J-2 configuration used to put American astronauts on the moon. The J-2S Fuel Turbopump (FTP) was the first Rocketdyne-designed liquid hydrogen centrifugal pump and provided many of the early lessons learned for the Space Shuttle Main Engine High Pressure Fuel Turbopumps. This paper will discuss the design trades and analyses performed for the current J-2X FTP to increase turbine life; increase structural margins, facilitate component fabrication; expedite turbopump assembly; and increase rotordynamic stability margins. Risk mitigation tests including inducer water tests, whirligig turbine blade tests, turbine air rig tests, and workhorse gas generator tests characterized operating environments, drove design modifications, or identified performance impact. Engineering design, fabrication, analysis, and assembly activities support FTP readiness for the first J-2X engine test scheduled for July 2011.

  2. Development of equipment for fabricating DUPIC fuel powder

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Ki Ho; Yang, M. S.; Park, J. J.; Lee, J. W.; Kim, J. H.; Cho, K. H.; Lee, D. Y.; Lee, Y. S.; Na, S. H

    1999-06-01

    The powder fabrication processes, as the first stage of manufacturing DUPIC (Direct Use of PWR spent fuel In CANDU) fuel, consist of the slitting of spent PWR fuel rods, REOX (Oxidation and REduction of Oxide Fuels) processing to produce the powder feedstock, the milling of the produced powder, the granulation of the milled powder, and the mixing of the granulated powder with pressing lubricants. All these processes should be conducted by remote means in a hot-cell environment where the direct human access is limited to the strictest minimum due to the high radioactivity. This report describe the development of the equipment for fabricating DUPIC fuel powder. These equipment are Slitting Machine, Oxidation and Reduction (OREOX) Furnace, Mill, Roll Compactor, and Mixer. Remote design concept was applied to all the equipment for use in the M6 hot-cell of the IMEF. Mechanical design considerations and capabilities of the equipment for remote operation and maintenance are presented. First prototypes were developed and installed in the DUPIC full scale mock-up and tested using a master-slave manipulator. Redesign and reconstruction were made on each equipment based on mock-up test results. The remote technology acquired through this research was utilized in developing other equipment for DUPIC fuel fabrication, thereby improving safety and increasing productivity. This technology could also be extended to the area of remote handling equipment development for use in hazardous environments. (author). 14 refs., 9 tabs., 21 figs.

  3. Recent Developments in Mems-Based Micro Fuel Cells

    CERN Document Server

    Pichonat, T

    2007-01-01

    Micro fuel cells ($\\mu$-FC) represent promising power sources for portable applications. Today, one of the technological ways to make $\\mu$-FC is to have recourse to standard microfabrication techniques used in the fabrication of micro electromechanical systems (MEMS). This paper shows an overview on the applications of MEMS techniques on miniature FC by presenting several solutions developed throughout the world. It also describes the latest developments of a new porous silicon-based miniature fuel cell. Using a silane grafted on an inorganic porous media as the proton-exchange membrane instead of a common ionomer such as Nafion, the fuel cell achieved a maximum power density of 58 mW cm-2 at room temperature with hydrogen as fuel.

  4. Status of commercial phosphoric acid fuel cell system development

    Science.gov (United States)

    Warshay, M.; Prokopius, P. R.; Simons, S. N.; King, R. B.

    1981-01-01

    A review of the current commercial phosphoric acid fuel cell system development efforts is presented. In both the electric utility and on-site integrated energy system applications, reducing cost and increasing reliability are important. The barrier to the attainment of these goals has been materials. The differences in approach among the three major participants are their technological features, including electrodes, matrices, intercell cooling, bipolar/separator plates, electrolyte management, fuel selection and system design philosophy.

  5. Development of 3D Oxide Fuel Mechanics Models

    Energy Technology Data Exchange (ETDEWEB)

    Spencer, B. W. [Idaho National Lab. (INL), Idaho Falls, ID (United States); Casagranda, A. [Idaho National Lab. (INL), Idaho Falls, ID (United States); Pitts, S. A. [Idaho National Lab. (INL), Idaho Falls, ID (United States); Jiang, W. [Idaho National Lab. (INL), Idaho Falls, ID (United States)

    2017-07-27

    This report documents recent work to improve the accuracy and robustness of the mechanical constitutive models used in the BISON fuel performance code. These developments include migration of the fuel mechanics models to be based on the MOOSE Tensor Mechanics module, improving the robustness of the smeared cracking model, implementing a capability to limit the time step size based on material model response, and improving the robustness of the return mapping iterations used in creep and plasticity models.

  6. Effects of New Fossil Fuel Developments on the Possibilities of Meeting 2C Scenarios

    Energy Technology Data Exchange (ETDEWEB)

    Meindertsma, W.; Blok, K.

    2012-12-15

    Recent years have seen an increasing activity in developing new fossil fuel production capacity. This includes unconventional fossil fuels, such as tar sands and shale gas, fossil fuels from remote locations, and fossil fuels with a very large increase in production in the near future. In this report, the impact of such developments on our ability to mitigate climate change is investigated. Our inventory shows that the new fossil fuel developments currently underway consist of 29,400 billion cubic meters of natural gas, 260,000 million barrels of oil and 49,600 million tonnes of coal. The development of these new fossil fuels would result in emissions of 300 billion tonnes of CO2 -equivalent (CO2e) from 2012 until 2050. Until 2050, a 'carbon budget' of 1550 billion tonnes CO2e is still available if we want to of keep global warming below 2C with a 50% probability. For a 75% probability to stay below 2C this budget is only 1050 billion tonnes CO2e. So, the new fossil fuel developments identified in this report consume 20-33% of the remaining carbon budget until 2050. In a scenario where the new fossil fuels are developed, we need to embark on a rapid emission reductions pathway at the latest in 2019 in order to meet the 50% probability carbon budget. Avoiding the development of new fossil fuels will give us until 2025 to start further rapid emission reductions. These calculations are based on the assumption that the maximum emission reduction rate is 4% per year and that the maximum change in emission trend is 0.5 percentage point per year. The starting year for rapid emission reductions depends on the choice of these parameters. A sensitivity analysis shows that, in all cases, refraining from new fossil fuel development allows for a delay of 5 to 8 years before we should embark on a rapid emission reduction pathway. The high investments required for developing new fossil fuels lead to a lock in effect; once developed, these fossil fuels need to be

  7. Metal Fuel Development and Verification for Prototype Generation IV Sodium-Cooled Fast Reactor

    OpenAIRE

    Chan Bock Lee; Jin Sik Cheon; Sung Ho Kim; Jeong-Yong Park; Hyung-Kook Joo

    2016-01-01

    Metal fuel is being developed for the prototype generation-IV sodium-cooled fast reactor (PGSFR) to be built by 2028. U–Zr fuel is a driver for the initial core of the PGSFR, and U–transuranics (TRU)–Zr fuel will gradually replace U–Zr fuel through its qualification in the PGSFR. Based on the vast worldwide experiences of U–Zr fuel, work on U–Zr fuel is focused on fuel design, fabrication of fuel components, and fuel verification tests. U–TRU–Zr fuel uses TRU recovered through pyroelectrochem...

  8. Distributed H2 Supply for Fuel Cell Utility Vehicles Year 6 - Activity 3.5 - Development fo a National Center for Hydrogen Technology

    Energy Technology Data Exchange (ETDEWEB)

    Almlie, Jay

    2012-04-15

    The Energy & Environmental Research Center (EERC) has developed a high-pressure hydrogen production system that reforms a liquid organic feedstock and water at operating pressures up to 800 bar (~12,000 psig). The advantages of this system include the elimination of energy-intensive hydrogen compression, a smaller process footprint, and the elimination of gaseous or liquid hydrogen transport. This system could also potentially enable distributed hydrogen production from centralized coal. Processes have been investigated to gasify coal and then convert the syngas into alcohol or alkanes. These alcohols and alkanes could then be easily transported in bulk to distributed high-pressure water-reforming (HPWR)-based systems to deliver hydrogen economically. The intent of this activity was to utilize the EERC’s existing HPWR hydrogen production process, previously designed and constructed in a prior project phase, as a basis to improve operational and production performance of an existing demonstration unit. Parameters to be pursued included higher hydrogen delivery pressure, higher hydrogen production rates, and the ability to refill within a 5-minute time frame.

  9. Development of spent fuel remote handling technology - Kinematic analysis of bilateral arms for abnormal spent fuels

    Energy Technology Data Exchange (ETDEWEB)

    Jeong, Kyu Won; Yoo, Ju Sang; Kim, Jong Yoon [Chungbuk National University, Chongju (Korea)

    2000-03-01

    In the project of 'Development of Spent Fuel Remote Handling Technology', Preprocessing technique, mechanism and teleoperation technique are being developed. One of the mechanisms is a device for disassembling of the spent fuel bundle. However, there may be abnormal fuel bar among the fuel bundle, In this case the unpacking task will be difficult and dangerous. So, in that case, a force reflected teleoperation manipulator is desirable. The system is composed of a anthropomorphic input device at control site, power manipulator at remote site and control system. In this research, the forward and inverse kinematic equations of input device and manipulators has been solved, respectively. In addition, the mapping algorithm is proposed and shown using computer simulation. The reaction force of the telemanipulator with the environmental object is reflected through control system. The reaction force is decomposed into joint torque of the input device based on the jacobian equation. The obtained theoretical relations are verified through computer simulation and they will be used effectively in the spent fuel remote handling technology. 6 refs., 26 figs., 7 tabs. (Author)

  10. Advanced Automotive Fuels Research, Development, and Commercialization Cluster (OH)

    Energy Technology Data Exchange (ETDEWEB)

    Linkous, Clovis; Hripko, Michael; Abraham, Martin; Balendiran, Ganesaratnam; Hunter, Allen; Lovelace-Cameron, Sherri; Mette, Howard; Price, Douglas; Walker, Gary; Wang, Ruigang

    2013-08-31

    Technical aspects of producing alternative fuels that may eventually supplement or replace conventional the petroleum-derived fuels that are presently used in vehicular transportation have been investigated. The work was centered around three projects: 1) deriving butanol as a fuel additive from bacterial action on sugars produced from decomposition of aqueous suspensions of wood cellulose under elevated temperature and pressure; 2) using highly ordered, openly structured molecules known as metal-organic framework (MOF) compounds as adsorbents for gas separations in fuel processing operations; and 3) developing a photocatalytic membrane for solar-driven water decomposition to generate pure hydrogen fuel. Several departments within the STEM College at YSU contributed to the effort: Chemistry, Biology, and Chemical Engineering. In the butanol project, sawdust was blended with water at variable pH and temperature (150 – 250{degrees}C), and heated inside a pressure vessel for specified periods of time. Analysis of the extracts showed a wide variety of compounds, including simple sugars that bacteria are known to thrive upon. Samples of the cellulose hydrolysate were fed to colonies of Clostridium beijerinckii, which are known to convert sugars to a mixture of compounds, principally butanol. While the bacteria were active toward additions of pure sugar solutions, the cellulose extract appeared to inhibit butanol production, and furthermore encouraged the Clostridium to become dormant. Proteomic analysis showed that the bacteria had changed their genetic code to where it was becoming sporulated, i.e., the bacteria were trying to go dormant. This finding may be an opportunity, as it may be possible to genetically engineer bacteria that resist the butanol-driven triggering mechanism to stop further fuel production. Another way of handling the cellulosic hydrolysates was to simply add the enzymes responsible for butanol synthesis to the hydrolytic extract ex-vivo. These

  11. Enhancing instruction in Fuels and Combustion Laboratory via a developed computer-assisted program for establishing efficient coal-diesel oil mixture (CDOM) fuel proportions

    Energy Technology Data Exchange (ETDEWEB)

    Maglaya, A.B. [La Salle University, Manila (Philippines). Dept. of Mechanical Engineering

    2004-07-01

    This paper discusses the relevance of digital computation in Fuels and Combustion Laboratory experiments used by the senior students of the Department of Mechanical Engineering, De La Salle University-Manila, Philippines. One of the students' experiments involved the determination of the most efficient CDOM fuel proportion as alternative fuel to diesel oil for steam generators and other industrial applications. Theoretical calculations show that it requires tedious and repetitive computations. A computer-assisted program was developed to lessen the time-consuming activities. The formulation of algorithms were based on the system of equations of the heat interaction between the CDOM fuel, combustion air and products of combustion and by applying the principles of mass and energy equations (or the First Law of Thermodynamics) for reacting systems were utilized. The developed computer-assisted program output verified alternative fuel selected through actual experimentation.

  12. BWR Spent Nuclear Fuel Integrity Research and Development Survey for UKABWR Spent Fuel Interim Storage

    Energy Technology Data Exchange (ETDEWEB)

    Bevard, Bruce Balkcom [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Mertyurek, Ugur [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Belles, Randy [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Scaglione, John M. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

    2015-10-01

    The objective of this report is to identify issues and support documentation and identify and detail existing research on spent fuel dry storage; provide information to support potential R&D for the UKABWR (United Kingdom Advanced Boiling Water Reactor) Spent Fuel Interim Storage (SFIS) Pre-Construction Safety Report; and support development of answers to questions developed by the regulator. Where there are gaps or insufficient data, Oak Ridge National Laboratory (ORNL) has summarized the research planned to provide the necessary data along with the schedule for the research, if known. Spent nuclear fuel (SNF) from nuclear power plants has historically been stored on site (wet) in spent fuel pools pending ultimate disposition. Nuclear power users (countries, utilities, vendors) are developing a suite of options and set of supporting analyses that will enable future informed choices about how best to manage these materials. As part of that effort, they are beginning to lay the groundwork for implementing longer-term interim storage of the SNF and the Greater Than Class C (CTCC) waste (dry). Deploying dry storage will require a number of technical issues to be addressed. For the past 4-5 years, ORNL has been supporting the U.S. Department of Energy (DOE) in identifying these key technical issues, managing the collection of data to be used in issue resolution, and identifying gaps in the needed data. During this effort, ORNL subject matter experts (SMEs) have become expert in understanding what information is publicly available and what gaps in data remain. To ensure the safety of the spent fuel under normal and frequent conditions of wet and subsequent dry storage, intact fuel must be shown to: 1.Maintain fuel cladding integrity; 2.Maintain its geometry for cooling, shielding, and subcriticality; 3.Maintain retrievability, and damaged fuel with pinhole or hairline cracks must be shown not to degrade further. Where PWR (pressurized water reactor) information is

  13. Integrated risk assessment for spent fuel transportation using developed software

    Energy Technology Data Exchange (ETDEWEB)

    Yun, Mi Rae; Christian, Robby; Kim, Bo Gyung; Almomani, Belal; Ham, Jae Hyun; Kang, Gook Hyun [KAIST, Daejeon (Korea, Republic of); Lee, Sang hoon [Keimyung University, Daegu (Korea, Republic of)

    2016-05-15

    As on-site spent fuel storage meets limitation of their capacity, spent fuel need to be transported to other place. In this research, risk of two ways of transportation method, maritime transportation and on-site transportation, and interim storage facility were analyzed. Easier and integrated risk assessment for spent fuel transportation will be possible by applying this software. Risk assessment for spent fuel transportation has not been researched and this work showed a case for analysis. By using this analysis method and developed software, regulators can get some insights for spent fuel transportation. For example, they can restrict specific region for preventing ocean accident and also they can arrange spend fuel in interim storage facility avoiding most risky region which have high risk from aircraft engine shaft. Finally, they can apply soft material on the floor for specific stage for on-site transportation. In this software, because we targeted Korea, we need to use Korean reference data. However, there were few Korean reference data. Especially, there was no food chain data for Korean ocean. In MARINRAD, they used steady state food chain model, but it is far from reality. Therefore, to get Korean realistic reference data, dynamic food chain model for Korean ocean need to be developed.

  14. Development of materials for fuel cell application by radiation technology

    Energy Technology Data Exchange (ETDEWEB)

    Rhee, Chang Kyu; Lee, Min Ku; Park, Junju; Lee, Gyoungja; Lee, Byung Cheol; Shin, Junhwa; Nho, Youngchang; Kang, Philhyun; Sohn, Joon Yong; Rang, Uhm Young

    2012-06-15

    The development of the single cell of SOFC with low operation temperature at and below 650 .deg. C(above 400 mW/cm{sup 2}) Ο The development of fabrication method for the single cell of solid oxide fuel cell (SOFC) by dip-coating of nanoparticles such as NiO, YSZ, Ag, and Ag/C, etc. Ο The optimization of the preparation and performance of SOFC by using nanoparticles. Ο The preparation of samples for SOFC with large dimension. The development of fluoropolymer-based fuel cell membranes with crosslinked structure by radiation grafting technique Ο The development of fuel cell membranes with low methanol permeability via the introduction of novel monomers (e. g. vinylbenzyl chloride and vinylether chloride) by radiation grafting technique Ο The development of hydrocarbon fuel cell membrane by radiation crosslinking technique Ο The structure analysis and the evaluations of the property, performance, and radiation effect of the prepared membranes Ο The optimization of the preparation and performance of DMFC fuel cell membrane via the structure-property analysis (power: above 130 mW/cm{sup 2}/50 cm{sup 2} at 5M methanol) Ο The preparation of samples for MEA stack assembly.

  15. Development of fuel alcohol technology. Development of flash fermentation method

    Energy Technology Data Exchange (ETDEWEB)

    1985-08-01

    This is an annual report for 1984 on the development of fuel alcohol fermentation technology. (1) Continuous operation (total 6,000 hours) with a compact fermentation unit (1 l/d alcohol production) increased the productivity up to 1.5 times by a flush fermentation for a high density bacillus. (2) Salt resistance of the bacillus stock for flush fermentation was examined for the selection of the stock to be used in the operation of the test plant. (3) Zaimomonus-mobilis stock was utilized to examine the influence of high-density condition of a light-curing resin on the fermentation characteristics. (4) For a high density bacillus to be loaded in a test plant, a condition for the stable storage for more than 3 months was selected. (5) A test plant with 5 kl/d alcohol production was installed at Izumi Alcohol Plant of NEDO. (6) A unit for preparing high density bacillus granules for loading in the test plant was installed at Kinuura Laboratory of NIKKI K.K..

  16. CDBG Economic Development Activity

    Data.gov (United States)

    Department of Housing and Urban Development — CDBG activity related to economic development, including commercial or industrial rehab, commercial or industrial land acquisition, commercial or industrial...

  17. Multiscale Multiphysics Developments for Accident Tolerant Fuel Concepts

    Energy Technology Data Exchange (ETDEWEB)

    Gamble, K. A. [Idaho National Lab. (INL), Idaho Falls, ID (United States); Hales, J. D. [Idaho National Lab. (INL), Idaho Falls, ID (United States); Yu, J. [Idaho National Lab. (INL), Idaho Falls, ID (United States); Zhang, Y. [Idaho National Lab. (INL), Idaho Falls, ID (United States); Bai, X. [Idaho National Lab. (INL), Idaho Falls, ID (United States); Andersson, D. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Patra, A. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Wen, W. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Tome, C. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Baskes, M. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Martinez, E. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Stanek, C. R. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Miao, Y. [Argonne National Lab. (ANL), Argonne, IL (United States); Ye, B. [Argonne National Lab. (ANL), Argonne, IL (United States); Hofman, G. L. [Argonne National Lab. (ANL), Argonne, IL (United States); Yacout, A. M. [Argonne National Lab. (ANL), Argonne, IL (United States); Liu, W. [ANATECH Corp., San Diego, CA (United States)

    2015-09-01

    U3Si2 and iron-chromium-aluminum (Fe-Cr-Al) alloys are two of many proposed accident-tolerant fuel concepts for the fuel and cladding, respectively. The behavior of these materials under normal operating and accident reactor conditions is not well known. As part of the Department of Energy’s Accident Tolerant Fuel High Impact Problem program significant work has been conducted to investigate the U3Si2 and FeCrAl behavior under reactor conditions. This report presents the multiscale and multiphysics effort completed in fiscal year 2015. The report is split into four major categories including Density Functional Theory Developments, Molecular Dynamics Developments, Mesoscale Developments, and Engineering Scale Developments. The work shown here is a compilation of a collaborative effort between Idaho National Laboratory, Los Alamos National Laboratory, Argonne National Laboratory and Anatech Corp.

  18. Coal-fueled diesel technology development: Nozzle development for coal-fueled diesel engines

    Energy Technology Data Exchange (ETDEWEB)

    Johnson, R.N.; Lee, M.; White, R.A.

    1994-01-01

    Direct injection of a micronized coal water mixture fuel into the combustion chambers of a diesel engine requires atomizing an abrasive slurry fuel with accurately sized orifices. Five injector orifice materials were evaluated: diamond compacts, chemical vapor deposited diamond tubes, thermally stabilized diamond, tungsten carbide with cobalt binder, and tungsten carbide with nickel binder with brazed and mechanically mounted orifice inserts. Nozzle bodies were fabricated of Armco 17-4 precipitation hardening stainless steel and Stellite 6B in order to withstand cyclic injection pressures and elevated temperatures. Based on a total of approximately 200 cylinder hours of engine operation with coal water mixture fuel diamond compacts were chosen for the orifice material.

  19. Regenerative Fuel Cells for Space Power and Energy Conversion (NaBH4/H2O2 Fuel Cell Development)

    Science.gov (United States)

    Valdez, Thomas I.; Miley, George H.; Luo, Nie; Burton, Rodney; Mather, Joseph; Hawkins, Glenn; Byrd, Ethan; Gu, Lifeng; Shrestha, Prajakti Joshi

    2006-01-01

    A viewgraph presentation describing hydrogen peroxide and sodium borohydride development is shown. The topics include: 1) Motivation; 2) The Sodium Borohydride Fuel Cell; 3) Fuel Cell Comparisons; 4) MEA Optimization; 5) 500-Watt Stack Testing; 6) System Modeling: Fuel Cell Power Source for Lunar Rovers; and 7) Conclusions

  20. Progress in Synthesis Technologies and Development Activities of 2 th Generation Biojet Fuel%第二代生物航空燃油的关键技术分析和进展动态

    Institute of Scientific and Technical Information of China (English)

    李宇萍; 章青; 王铁军; 马隆龙; 刘琪英

    2014-01-01

    概述了第二代生物航空燃油的技术现状和进展动态,着重讨论了生物丁醇/异丁醇脱水-聚合技术、木质纤维素水解-水相重整催化合成技术、油脂加氢脱氧-裂化异构两段加氢技术和生物质气化费托合成技术。介绍了生物丁醇/异丁醇、麻风果油、亚麻荠油和海藻油等影响生物航空燃油成本的原料开发现状,以及国内外在建的示范装置,分析了第二代生物航空燃油的技术特点及价格竞争力,并展望了其未来发展方向。%The progress in synthesis technologies and development activities of 2th generation biojet fuels were reviewed. The feature of synthesis technologies were discussed and compared. They included the processes of biobutanol/bioisobutanol-dehydration-oligomerization, lignocellulose hydrolysis-aqueous phase reforming, two-step hydrogenation ( hydrodeoxygenation-hydroisomerization) of oils and fats and biomass gasification-Fischer Tropsch synthesis. The current status of feedstocks, biobutanol/bioisobutanol, Jatropha, Camelina sativa and algae, as well as the demonstration/pilot-scale plant for 2th generation biojet fuel production were described and analyzed from their technical and economic properties. Finally the development prospect was stated and proposed for its future application in jet planes.

  1. Feasibility study on the development of advanced LWR fuel technology

    Energy Technology Data Exchange (ETDEWEB)

    Jung, Youn Ho; Sohn, D. S.; Jeong, Y. H.; Song, K. W.; Song, K. N.; Chun, T. H.; Bang, J. G.; Bae, K. K.; Kim, D. H. and others

    1997-07-01

    Worldwide R and D trends related to core technology of LWR fuels and status of patents have been surveyed for the feasibility study. In addition, various fuel cycle schemes have been studied to establish the target performance parameters. For the development of cladding material, establishment of long-term research plan for alloy development and optimization of melting process and manufacturing technology were conducted. A work which could characterize the effect of sintering additives on the microstructure of UO{sub 2} pellet has been experimentally undertaken, and major sintering variables and their ranges have been found in the sintering process of UO{sub 2}-Gd{sub 2}O{sub 3} burnable absorber pellet. The analysis of state of the art technology related to flow mixing device for spacer grid and debris filtering device for bottom nozzle and the investigation of the physical phenomena related to CHF enhancement and the establishment of the data base for thermal-hydraulic performance tests has been done in this study. In addition, survey on the documents of the up-to-date PWR fuel assemblies developed by foreign vendors have been carried out to understand their R and D trends and establish the direction of R and D for these structural components. And, to set the performance target of the new fuel, to be developed, fuel burnup and economy under the extended fuel cycle length scheme were estimated. A preliminary study on the failure mechanism of CANDU fuel, key technology and advanced coating has been performed. (author). 190 refs., 31 tabs., 129 figs.

  2. 5.0. Depletion, activation, and spent fuel source terms

    Energy Technology Data Exchange (ETDEWEB)

    Wieselquist, William A. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

    2016-04-01

    SCALE’s general depletion, activation, and spent fuel source terms analysis capabilities are enabled through a family of modules related to the main ORIGEN depletion/irradiation/decay solver. The nuclide tracking in ORIGEN is based on the principle of explicitly modeling all available nuclides and transitions in the current fundamental nuclear data for decay and neutron-induced transmutation and relies on fundamental cross section and decay data in ENDF/B VII. Cross section data for materials and reaction processes not available in ENDF/B-VII are obtained from the JEFF-3.0/A special purpose European activation library containing 774 materials and 23 reaction channels with 12,617 neutron-induced reactions below 20 MeV. Resonance cross section corrections in the resolved and unresolved range are performed using a continuous-energy treatment by data modules in SCALE. All nuclear decay data, fission product yields, and gamma-ray emission data are developed from ENDF/B-VII.1 evaluations. Decay data include all ground and metastable state nuclides with half-lives greater than 1 millisecond. Using these data sources, ORIGEN currently tracks 174 actinides, 1149 fission products, and 974 activation products. The purpose of this chapter is to describe the stand-alone capabilities and underlying methodology of ORIGEN—as opposed to the integrated depletion capability it provides in all coupled neutron transport/depletion sequences in SCALE, as described in other chapters.

  3. Microfabricated microbial fuel cell arrays reveal electrochemically active microbes.

    Directory of Open Access Journals (Sweden)

    Huijie Hou

    Full Text Available Microbial fuel cells (MFCs are remarkable "green energy" devices that exploit microbes to generate electricity from organic compounds. MFC devices currently being used and studied do not generate sufficient power to support widespread and cost-effective applications. Hence, research has focused on strategies to enhance the power output of the MFC devices, including exploring more electrochemically active microbes to expand the few already known electricigen families. However, most of the MFC devices are not compatible with high throughput screening for finding microbes with higher electricity generation capabilities. Here, we describe the development of a microfabricated MFC array, a compact and user-friendly platform for the identification and characterization of electrochemically active microbes. The MFC array consists of 24 integrated anode and cathode chambers, which function as 24 independent miniature MFCs and support direct and parallel comparisons of microbial electrochemical activities. The electricity generation profiles of spatially distinct MFC chambers on the array loaded with Shewanella oneidensis MR-1 differed by less than 8%. A screen of environmental microbes using the array identified an isolate that was related to Shewanella putrefaciens IR-1 and Shewanella sp. MR-7, and displayed 2.3-fold higher power output than the S. oneidensis MR-1 reference strain. Therefore, the utility of the MFC array was demonstrated.

  4. Development of Noncontact Imaging Technology for the Detection of Internal Defects of a Nuclear Fuel Plate

    Energy Technology Data Exchange (ETDEWEB)

    Park, S. K.; Baik, S. H.; Lee, Y. S.; Cheong, Y. M.

    2012-01-15

    The object of the research is to develop a new imaging inspection technology for the quality testing of plate-type nuclear fuel whose demanding is currently increasing in nuclear research reactors. A new noncontact imaging inspection technique is developed for the detection of internal defects in plate-type nuclear fuel. To develop the imaging inspection technique, a hardware system based on active optical interference is configured. An operating software for the developed nondestructive inspection system is developed after designing an advanced signal processing algorithm to improve the detection capability of the system. The developed system is optimized through experiments and optimal heating condition is studied. The performance of a lock-in thermography is also evaluated to see the possibility of the plate-type nuclear fuel application.

  5. Coal-Based Oxy-Fuel System Evaluation and Combustor Development; Oxy-Fuel Turbomachinery Development for Energy Intensive Industrial Applications

    Energy Technology Data Exchange (ETDEWEB)

    Hollis, Rebecca

    2013-03-31

    Clean Energy Systems, Inc. (CES) partnered with the U.S. Department of Energy’s National Energy Technology Laboratory in 2005 to study and develop a competing technology for use in future fossil-fueled power generation facilities that could operate with near zero emissions. CES’s background in oxy-fuel (O-F) rocket technology lead to the award of Cooperative Agreement DE-FC26-05NT42645, “Coal-Based Oxy-Fuel System Evaluation and Combustor Development,” where CES was to first evaluate the potential of these O-F power cycles, then develop the detailed design of a commercial-scale O-F combustor for use in these clean burning fossil-fueled plants. Throughout the studies, CES found that in order to operate at competitive cycle efficiencies a high-temperature intermediate pressure turbine was required. This led to an extension of the Agreement for, “Oxy-Fuel Turbomachinery Development for Energy Intensive Industrial Applications” where CES was to also develop an intermediate-pressure O-F turbine (OFT) that could be deployed in O-F industrial plants that capture and sequester >99% of produced CO2, at competitive cycle efficiencies using diverse fuels. The following report details CES’ activities from October 2005 through March 2013, to evaluate O-F power cycles, develop and validate detailed designs of O-F combustors (main and reheat), and to design, manufacture, and test a commercial-scale OFT, under the three-phase Cooperative Agreement.

  6. Conventional OTSG development for heavy liquid fuel firing in thermal applications

    Energy Technology Data Exchange (ETDEWEB)

    Setchfield, W.P. [Mitchell Engineers Ltd., Glasgow, Scotland (United Kingdom); Roset, J.N. [Total S.A., Paris (France); Schaffer, M. [Total E and P Canada Ltd., Calgary, AB (Canada); O' Connor, D. [MEG Energy Inc., Calgary, AB (Canada); Kense, K. [TIW Western Inc., Calgary, AB (Canada)

    2008-10-15

    The demand for natural gas is expected to increase as a result of future expansion in Canadian extra heavy oil in-situ thermal production, such as steam assisted gravity drainage or SAGD projects. Natural gas is the current predominant fuel utilized for the associated steam generation. Potential natural gas shortages and related price volatility require that operators consider alternative fuels for the projected growth of in-situ thermal production in Alberta. This paper targeted the use of bitumen from upstream sites and derivative residues from upgrading activities as the most convenient alternative fuel sources for thermal operators of established horizontal type gas fired once through steam generators (OTSGs). The paper presented the methodology, the issues associated with bitumen or residue burning and the related technical solutions in developing a multi-fuel OTSG product. The paper provided background information on conventional OTSG design development, conventional OTSG existing deign, and general description of conventional OTSG. The paper also described the configuration of a radiant furnace, convection module, and theories and definitions such as heavy liquid fuels. A description and application of the equipment and processes as well as a presentation of the data and results was then offered. The multi fuel OTSG design is considered to be a practical and workable product capable of firing heavy liquid fuels. However, the design changes have had a significant impact when compared with conventional OTSG boilers. 11 figs.

  7. Development of Voloxidation Process for Treatment of LWR Spent Fuel

    Energy Technology Data Exchange (ETDEWEB)

    Park, J. J.; Jung, I. H.; Shin, J. M. (and others)

    2007-08-15

    The objective of the project is to develop a process which provides a means to recover fuel from the cladding, and to simplify downstream processes by recovering volatile fission products. This work focuses on the process development in three areas ; the measurement and assessment of the release behavior for the volatile and semi-volatile fission products from the voloxidation process, the assessment of techniques to trap and recover gaseous fission products, and the development of process cycles to optimize fuel cladding separation and fuel particle size. High temperature adsorption method of KAERI was adopted in the co-design of OTS for hot experiment in INL. KAERI supplied 6 sets of filter for hot experiment. Three hot experiment in INL hot cell from the 25th of November for two weeks with attaching 4 KAERI staffs had been carried out. The results were promising. For example, trapping efficiency of Cs was 95% and that of I was 99%, etc.

  8. RECENT DEVELOPMENT IN TEM CHARACTERIZATION OF IRRADIATED RERTR FUELS

    Energy Technology Data Exchange (ETDEWEB)

    J. Gan; B.D. Miller; D.D. Keiser Jr.; A.B. Robinson; J.W. Madden; P.G. Medvedev; D.M. Wachs

    2011-10-01

    The recent development on TEM work of irradiated RERTR fuels includes microstructural characterization of the irradiated U-10Mo/alloy-6061 monolithic fuel plate, the RERTR-7 U-7Mo/Al-2Si and U-7Mo/Al-5Si dispersion fuel plates. It is the first time that a TEM sample of an irradiated nuclear fuel was prepared using the focused-ion-beam (FIB) lift-out technical at the Idaho National Laboratory. Multiple FIB TEM samples were prepared from the areas of interest in a SEM sample. The characterization was carried out using a 200kV TEM with a LaB6 filament. The three dimensional orderings of nanometer-sized fission gas bubbles are observed in the crystalline region of the U-Mo fuel. The co-existence of bubble superlattice and dislocations is evident. Detailed microstructural information along with composition analysis is obtained. The results and their implication on the performance of these fuels are discussed.

  9. Globalisation of the nuclear fuel cycle - impact of developments on fuel management

    Energy Technology Data Exchange (ETDEWEB)

    Durpel, L. van den; Bertel, E. [OECD Nuclear Energy Agency, 92 - Issy-les-Moulineaux (France)

    2000-02-01

    Nuclear energy will have to cope more and more with a rapid changing environment due to economic competitive pressure and the deregulatory progress. In current economic environment, utilities will have to focus strongly on the reduction of their total generation costs, covering the fuel cycle costs, which are only partly under their control. Developments in the fuel cycle will be in the short-term rather evolutionary addressing the current needs of utilities. However, within the context of sustainable development and more and more inclusion of externalities in energy generation costs, more performing developments in the fuel cycle could become important and feasible. A life-cycle design approach of the fuel cycle will be requested in order to cover all factors in order to decrease significantly the nuclear energy generation cost to complete with other alternative fuels in the long-term. This paper will report on some of the trends one could distinguish in the fuel cycle with emphasis on cost reduction. OECD/NEA is currently conducting a study on the fuel cycle aiming to assess current and future nuclear fuel cycles according to the potential for further improvement of the full added-value chain of these cycles from a mainly technological and economic perspective including environmental and social considerations. (orig.) [German] Die Kernenergie wird sich mehr und mehr in einem Umfeld behaupten muessen, das durch schnelle Veraenderungen auf Grund des Wettbewerbsdrucks in der Wirtschaft und des Liberalisierungsprozesses gekennzeichnet ist. Im heutigen Wirtschaftsumfeld muessen sich die Energieversorgungsunternehmen hauptsaechlich auf die Senkung ihrer Stromerzeugungs-Gesamtkosten konzentrieren. Darunter fallen auch die Brennstoffkreislaufkosten, die sie nur zum Teil beeinflussen koennen. Kurzfristig gesehen, duerften die Entwicklungen im Brennstoffkreislauf eher evolutionaer verlaufen und den jeweiligen Beduerfnissen der EVUs entsprechen. Im Zusammenhang mit einer

  10. Hydrogen-bromine fuel cell advance component development

    Science.gov (United States)

    Charleston, Joann; Reed, James

    1988-01-01

    Advanced cell component development is performed by NASA Lewis to achieve improved performance and longer life for the hydrogen-bromine fuel cells system. The state-of-the-art hydrogen-bromine system utilizes the solid polymer electrolyte (SPE) technology, similar to the SPE technology developed for the hydrogen-oxygen fuel cell system. These studies are directed at exploring the potential for this system by assessing and evaluating various types of materials for cell parts and electrode materials for Bromine-hydrogen bromine environment and fabricating experimental membrane/electrode-catalysts by chemical deposition.

  11. Process development and fabrication for sphere-pac fuel rods. [PWR; BWR

    Energy Technology Data Exchange (ETDEWEB)

    Welty, R.K.; Campbell, M.H.

    1981-06-01

    Uranium fuel rods containing sphere-pac fuel have been fabricated for in-reactor tests and demonstrations. A process for the development, qualification, and fabrication of acceptable sphere-pac fuel rods is described. Special equipment to control fuel contamination with moisture or air and the equipment layout needed for rod fabrication is described and tests for assuring the uniformity of the fuel column are discussed. Fuel retainers required for sphere-pac fuel column stability and instrumentation to measure fuel column smear density are described. Results of sphere-pac fuel rod fabrication campaigns are reviewed and recommended improvements for high throughput production are noted.

  12. Texas LPG fuel cell development and demonstration project

    Energy Technology Data Exchange (ETDEWEB)

    None, None

    2004-07-26

    The State Energy Conservation Office has executed its first Fuel Cell Project which was awarded under a Department of Energy competitive grant process. The Texas LPG Fuel Processor Development and Fuel Cell Demonstration Program is a broad-based public/private partnership led by the Texas State Energy Conservation Office (SECO). Partners include the Alternative Fuels Research and Education Division (AFRED) of the Railroad Commission of Texas; Plug Power, Inc., Latham, NY, UOP/HyRadix, Des Plaines, IL; Southwest Research Institute (SwRI), San Antonio, TX; the Texas Natural Resource Conservation Commission (TNRCC), and the Texas Department of Transportation (TxDOT). The team proposes to mount a development and demonstration program to field-test and evaluate markets for HyRadix's LPG fuel processor system integrated into Plug Power's residential-scale GenSys(TM) 5C (5 kW) PEM fuel cell system in a variety of building types and conditions of service. The program's primary goal is to develop, test, and install a prototype propane-fueled residential fuel cell power system supplied by Plug Power and HyRadix in Texas. The propane industry is currently funding development of an optimized propane fuel processor by project partner UOP/HyRadix through its national checkoff program, the Propane Education and Research Council (PERC). Following integration and independent verification of performance by Southwest Research Institute, Plug Power and HyRadix will produce a production-ready prototype unit for use in a field demonstration. The demonstration unit produced during this task will be delivered and installed at the Texas Department of Transportation's TransGuide headquarters in San Antonio, Texas. Simultaneously, the team will undertake a market study aimed at identifying and quantifying early-entry customers, technical and regulatory requirements, and other challenges and opportunities that need to be addressed in planning commercialization of the units

  13. BISON and MARMOT Development for Modeling Fast Reactor Fuel Performance

    Energy Technology Data Exchange (ETDEWEB)

    Gamble, Kyle Allan Lawrence [Idaho National Lab. (INL), Idaho Falls, ID (United States); Williamson, Richard L. [Idaho National Lab. (INL), Idaho Falls, ID (United States); Schwen, Daniel [Idaho National Lab. (INL), Idaho Falls, ID (United States); Zhang, Yongfeng [Idaho National Lab. (INL), Idaho Falls, ID (United States); Novascone, Stephen Rhead [Idaho National Lab. (INL), Idaho Falls, ID (United States); Medvedev, Pavel G. [Idaho National Lab. (INL), Idaho Falls, ID (United States)

    2015-09-01

    BISON and MARMOT are two codes under development at the Idaho National Laboratory for engineering scale and lower length scale fuel performance modeling. It is desired to add capabilities for fast reactor applications to these codes. The fast reactor fuel types under consideration are metal (U-Pu-Zr) and oxide (MOX). The cladding types of interest include 316SS, D9, and HT9. The purpose of this report is to outline the proposed plans for code development and provide an overview of the models added to the BISON and MARMOT codes for fast reactor fuel behavior. A brief overview of preliminary discussions on the formation of a bilateral agreement between the Idaho National Laboratory and the National Nuclear Laboratory in the United Kingdom is presented.

  14. DUPIC nuclear fuel manufacturing and process technology development at KAERI

    Energy Technology Data Exchange (ETDEWEB)

    Yim, Sung Paal; Lee, Jung Won; Kim, Jong Ho; Kim, Soo Sung; Kim, Woong Ki; Yang, Myung Seung [Korea Atomic Energy Research Institute, Taejon (Korea, Republic of)

    2000-07-01

    DUPIC fuel cycle development project in KAERI of Korea was initiated in 1991 and has advanced in relevant technologies for last 10 years. The project includes five different topics such as nuclear fuel manufacturing, compatibility evaluation, performance evaluation, manufacturing facility management, and safeguards. The contents and results of DUPIC R and D up to now are as follow: - the basic foundation was established for the critically required pelletizing technology and powder treatment technology for DUPIC. - development of DUPIC process line and deployment of 20 each process equipment and examination instruments in DFDF. - powder and pellet characterization study was done at PIEF based on the simfuel study results, and 30 DUPIC pellets were successfully produced. - the manufactured pellets were used for sample fuel rods irradiated in July,2000 in HANARO research reactor in KAERI and has been under post irradiation examination. (Hong, J. S.)

  15. Development of nuclear spent fuel Maritime transportation scenario

    Energy Technology Data Exchange (ETDEWEB)

    Yoo, Min; Kang, Hyun Gook [KAIST, Daejeon (Korea, Republic of)

    2014-08-15

    Spent fuel transportation of South Korea is to be conducted through near sea because it is able to ship a large amount of the spent fuel far from the public comparing to overland transportation. The maritime transportation is expected to be increased and its risk has to be assessed. For the risk assessment, this study utilizes the probabilistic safety assessment (PSA) method and the notions of the combined event. Risk assessment of maritime transportation of spent fuel is not well developed in comparison with overland transportation. For the assessment, first, the transportation scenario should be developed and categorized. Categories are assorted into the locations, release aspects and exposure aspects. This study deals with accident that happens on voyage and concentrated on ship-ship collision. The collision accident scenario is generated with event tree analysis. The scenario will be exploited for the maritime transportation risk model which includes consequence and accident probability.

  16. Development of Passive Fuel Cell Thermal Management Heat Exchanger

    Science.gov (United States)

    Burke, Kenneth A.; Jakupca, Ian J.; Colozza, Anthony J.

    2010-01-01

    The NASA Glenn Research Center is developing advanced passive thermal management technology to reduce the mass and improve the reliability of space fuel cell systems for the NASA Exploration program. The passive thermal management system relies on heat conduction within highly thermally conductive cooling plates to move the heat from the central portion of the cell stack out to the edges of the fuel cell stack. Using the passive approach eliminates the need for a coolant pump and other cooling loop components within the fuel cell system which reduces mass and improves overall system reliability. Previous development demonstrated the performance of suitable highly thermally conductive cooling plates that could conduct the heat, provide a sufficiently uniform temperature heat sink for each cell of the fuel cell stack, and be substantially lighter than the conventional thermal management approach. Tests were run with different materials to evaluate the design approach to a heat exchanger that could interface with the edges of the passive cooling plates. Measurements were made during fuel cell operation to determine the temperature of individual cooling plates and also to determine the temperature uniformity from one cooling plate to another.

  17. Results from the DOE Advanced Gas Reactor Fuel Development and Qualification Program

    Energy Technology Data Exchange (ETDEWEB)

    David Petti

    2014-06-01

    Modular HTGR designs were developed to provide natural safety, which prevents core damage under all design basis accidents and presently envisioned severe accidents. The principle that guides their design concepts is to passively maintain core temperatures below fission product release thresholds under all accident scenarios. This level of fuel performance and fission product retention reduces the radioactive source term by many orders of magnitude and allows potential elimination of the need for evacuation and sheltering beyond a small exclusion area. This level, however, is predicated on exceptionally high fuel fabrication quality and performance under normal operation and accident conditions. Germany produced and demonstrated high quality fuel for their pebble bed HTGRs in the 1980s, but no U.S. manufactured fuel had exhibited equivalent performance prior to the Advanced Gas Reactor (AGR) Fuel Development and Qualification Program. The design goal of the modular HTGRs is to allow elimination of an exclusion zone and an emergency planning zone outside the plant boundary fence, typically interpreted as being about 400 meters from the reactor. To achieve this, the reactor design concepts require a level of fuel integrity that is better than that claimed for all prior US manufactured TRISO fuel, by a few orders of magnitude. The improved performance level is about a factor of three better than qualified for German TRISO fuel in the 1980’s. At the start of the AGR program, without a reactor design concept selected, the AGR fuel program selected to qualify fuel to an operating envelope that would bound both pebble bed and prismatic options. This resulted in needing a fuel form that could survive at peak fuel temperatures of 1250°C on a time-averaged basis and high burnups in the range of 150 to 200 GWd/MTHM (metric tons of heavy metal) or 16.4 to 21.8% fissions per initial metal atom (FIMA). Although Germany has demonstrated excellent performance of TRISO-coated UO

  18. Technical Development of the Small Fission Gas Measurement in Fuel Rods using the Laser Puncturing

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Heemoon; Baik, Seungje; Jin, Younggwan; Jung, Yanghong; Yoo, Boungok; Ahn, Sangbok; Yang, Yongsik; Lee, Byoungoon

    2013-12-15

    Information of fuel cladding tube and expected gas amount were obtained from fuel development department to design chamber volume and specification of laser device. Laser puncturing tests for several tubes were performed to setup power and capability. Laser puncturing tests for several tubes were performed to setup power and capability. Vacuum system with chamber was established. Additionally, QMS(Quadruple Mass Spectrometer in high vacuum state) was installed in vacuum system. The system was installed in hotcell following the preliminary test for the puncturing, pressure measuring and gas content analysis. After system test was installed in hotcell following the preliminary test for the puncturing, pressure measuring and gas content analysis. After system test was completed, SFR fuel rods were punctured to measure total gas amount and each gas content(He, Xe, Kr). The system for laser puncturing and measurement of small fission gas amout in fuel rod was designed with considering hotcell facility and fuel rod condition for first year. Chamber size, laser capability were well operated and the system showed reasonable results. In second year, QMS(Quadruple Mass Spectrometer) was installed in the system for quantitative analysis of gas contents. Thus, Laser puncturing, amount of gas measurement and gas analysis were carried out in one time. The system was activated for SFR fuel rods after installation and preliminary test. 9 SFR fuel rods were tested and produced total gas amounts and gas analysis data(He, Xe, Kr)

  19. Aid Fuels Faster Socio-Economic Development

    Institute of Scientific and Technical Information of China (English)

    2005-01-01

    In the past 40 years since the founding of the Tibet Autonomous Region, the area has developed at an extraordinarily fast rate. All this has taken place with the strong support of the Central Government and various fraternal provinces and municipalities directly under the Central Government. Blind to the situation, however, the 14th Dalai Lama and his clique, last April,again dished up the so-called Intemational Development Project in Tibet and Guidelines for Sustainable Development (hereinafter referred to as the Guidelines). The proposal contains lies and distorted facts,negating the great achievements in the social and economic development in Tibet, openly attacking national aid to the region and rejecting the idea of the Tibetan people accepting the socialist system.

  20. A cost-effective microbial fuel cell to detect and select for photosynthetic electrogenic activity in algae and cyanobacteria

    NARCIS (Netherlands)

    Luimstra, V.M.; Kennedy, S.J.; Güttler, J.; Wood, S.A.; Williams, D.E.; Packer, M.A.

    2014-01-01

    This work describes the development of an easily constructed, cost-effective photosynthetic microbial fuel cell design with highly reproducible electrochemical characteristics that can be used to screen algae and cyanobacteria for photosynthetic electrogenic activity. It is especially suitable for

  1. Development of a Monolithic Research Reactor Fuel Type at Argonne National Laboratory

    Energy Technology Data Exchange (ETDEWEB)

    Clark, C.R.; Briggs, R.J.

    2004-10-06

    The Reduced Enrichment for Research and Test Reactors (RERTR) program has been tasked with the conversion of research reactors from highly enriched to low-enriched uranium (LEU). To convert several high power reactors, monolithic fuel, a new fuel type, is being developed. This fuel type replaces the standard fuel dispersion with a fuel alloy foil, which allows for fuel densities far in excess of that found in dispersion fuel. The single-piece fuel foil also contains a significantly lower interface area between the fuel and the aluminum in the plate than the standard fuel type, limiting the amount of detrimental fuel-aluminum interaction that can occur. Implementation of monolithic fuel is dependant on the development of a suitable fabrication method as traditional roll-bonding techniques are inadequate.

  2. Flight management concepts development for fuel conservation

    Science.gov (United States)

    Sorensen, J. A.; Morello, S. A.

    1983-01-01

    It is pointed out that increased airspace congestion will produce increased flight delay unless advanced flight management concepts are developed to compensate. It has been estimated that a 5 percent reduction in delay is approximately equivalent, in terms of direct operating costs, to a 5 percent reduction in drag. The present investigation regarding the development of the required flight management concepts is organized into three sections, related to background, current research, and future effort. In the background section, a summary is provided of past technical effort concerning flight management. The second section is concerned with on-going efforts to integrate flight management with ground-based flight planning, and with an advanced concepts simulator to test the new developments. In the third section, attention is given to research concerning airborne flight management integration with other flight functions.

  3. Development of solid oxide fuel cell (SOFC)

    Energy Technology Data Exchange (ETDEWEB)

    Huijsmans, J.P.P.; Van Heuveln, F.H.; Van Berkel, F.P.F.

    1993-12-01

    A description is given of the work performed by the Netherlands Energy Research Foundation, Petten, Netherlands, during the period August 1990 - June 1993. The aim of the project is the development and demonstration of a flat plate, 1 kW SOFC reactor with a metal separator plate, using the 'multiple array cell concept' of Siemens. In the framework of this programme ECN has developed and tested optimized ceramic SOFC components with sizes between 5x5 and 10x10 cm2. For the manufacturing of the ceramic components ECN has used a tape casting technique. Optimized electrode structures with a large amount of three-phase boundaries at the electrolyte/electrode interface were developed. Power density of these cells was 0.7 W/cm2. 21 figs., 5 tabs., 13 refs.

  4. International Source Book: Nuclear Fuel Cycle Research and Development Volume 2

    Energy Technology Data Exchange (ETDEWEB)

    Harmon, K. M.; Lakey, L. T.

    1982-11-01

    This document starts with an overview that summarizes nuclear power policies and waste management activities for nations with significant commercial nuclear fuel cycle activities either under way or planned. A more detailed program summary is then included for each country or international agency conducting nuclear fuel cycle and waste management research and development. This second volume includes the program summaries of those countries listed alphabetically from Japan to Yugoslavia. Information on international agencies and associations, particularly the IAEA, NEA, and CEC, is provided also.

  5. Surveillance system for DUPIC fuel development facility (I)

    Energy Technology Data Exchange (ETDEWEB)

    Kim, D. Y.; Kim, H. D.; Park, C. S.; Cha, H. R.; Hong, J. S.; Yang, M. S. [KAERI, Taejon (Korea, Republic of)

    2000-05-01

    DUPIC Surveillance System is developed to process image data and radiation data together to diagnose intelligently the transportation status of the nuclear material, which makes it possible that usual DUPIC process be carried out without interruption under the surveillance. We developed the neutron monitor for surveillance and the system which takes and processes radiation data and image data, where the system is under the test operation after installed at DFDF (Dupic Fuel Development Facility)

  6. Development of wood fuel delivery logistics; Puupolttoaineiden hankintalogistiikan kehittaeminen

    Energy Technology Data Exchange (ETDEWEB)

    Laitinen, H.

    1996-12-31

    The main aim of the project is to model the energy wood business and total logistics in a certain large region. First, wood utilisation locations inside this area are examined; the most important ones are the wood processing factories, and the heating- and power plants. After that, wood potentials in the forests of the area are evaluated in sub-areas suitable in size and sufficiently detailed for further evaluations. For that purpose, the most valuable source data are forest management plans, up to ten years forward, on which basis the wood fuel potentials can be evaluated following sustainable development. In Finland there are extensive and detailed data bases storing forest information and it is possible to collect necessary data for a data base applicable to our calculations. In logistical sense it is important to know, by which delivery chains the economically best and desired results are achieved. The software prototype based on data base is modelled and developed at VTT Energy, for facilitating these planning activities. The starting point of the planning system in delivery logistics is the implementation of an easy tool for versatile planning so that with this tool model different delivery chains can be flexiblyed, create usage scenarios, make alternative examinations, and calculate impacts of different factors on energy wood amounts yielded and delivery costs. With planning system in delivery logistics we calculate production costs and amounts delivered to different utilisation locations. The system offers tools for definitions of utilisation locations, calculation parameters, and delivery chains

  7. Research and Development wildland fire and fuels accomplishments and outcomes

    Science.gov (United States)

    Matthew Rollins; Carlos Rodriguez-Franco; Tara Haan; Susan Conard

    2017-01-01

    The Research and Development (R&D) Wildland Fire and Fuels program at the Forest Service, an agency of the U.S. Department of Agriculture, continues to be an internationally renowned program for generating critical and essential data, knowledge, and applications for all phases of wildland fire management and response. This report provides a primer on the...

  8. Research and development issues for molten carbonate fuel cells

    Energy Technology Data Exchange (ETDEWEB)

    Krumpelt, M.

    1996-04-01

    This paper describes issues pertaining to the development of molten carbonate fuel cells. In particular, the corrosion resistance and service life of nickel oxide cathodes is described. The resistivity of lithium oxide/iron oxides and improvement with doping is addressed.

  9. Component Development - Advanced Fuel Cells for Transportation Applications

    Energy Technology Data Exchange (ETDEWEB)

    Butler, William

    2000-06-19

    Report summarizes results of second phase of development of Vairex air compressor/expander for automotive fuel cell power systems. Project included optimizing key system performance parameters, as well as reducing number of components and the project cost, size and weight of the air system. Objectives were attained. Advanced prototypes are in commercial test environments.

  10. Coal-fueled diesel: Technology development: Final report

    Energy Technology Data Exchange (ETDEWEB)

    Leonard, G.; Hsu, B.; Flynn, P.

    1989-03-01

    This project consisted of four tasks: (1) to determine if CWM could be ignited and burned rapidly enough for operation in a 1000-rpm diesel engine, (2) to demonstrate that a durable CWM-fueled engine could in principle be developed, (3) to assess current emissions control technology to determine the feasibility of cleaning the exhaust of a CWM-fueled diesel locomotive, and (4) to conduct an economic analysis to determine the attractiveness of powering US locomotives with CWM. 34 refs., 125 figs., 28 tabs.

  11. 76 FR 80362 - Agency Information Collection Activities; Submission to OMB for Review and Approval; Fuel Quality...

    Science.gov (United States)

    2011-12-23

    ... Information Collection Activities; Submission to OMB for Review and Approval; Fuel Quality Regulations for..., or financial resources expended by persons to generate, maintain, retain, or disclose or provide information to or for a Federal agency. This includes the time needed to review instructions; develop,...

  12. Development of TRIGA Fuel Fabrication by Powder Technique

    Directory of Open Access Journals (Sweden)

    H. Suwarno

    2014-12-01

    Full Text Available The prospect of operation of the Indonesian TRIGA reactors may be jeopardizes in the future due to the lack of fuel and control rods. Both fuel and control rods may not longer be imported and should be developed domestically. The most specific technology to fabricate TRIGA fuel rod is the production of UZrH1.6 pellet. The steps include converting the massive U metal into powder in by hydriding-dehydriding technique and mixing the U and Zr powders. A research has been planned to conducted by the National Nuclear Energy Agency (BATAN in Indonesia. Fixed amount of U-Zr mixed powders at the ratio of U/Zr = 10 wt% was pressed into a pellet with a diameter of 1.41 in and a thickness of 1 or 1.5 in, sintered at a temperature of 1200oC, followed by hydriding at 800oC to obtained UZrH1.6. The pellets, cladding, and other components were then fabricated into a fuel rod. A detailed discussion of the TRIGA fuel fabrication is presented in the paper.

  13. The development of CVR coatings for PBR fuels

    Science.gov (United States)

    Barletta, R. E.; Vanier, P. E.; Dowell, M. B.; Lennartz, J. A.

    Particle bed reactors (PBR's) are being developed for both space power and propulsion applications. These reactors operate with exhaust gas temperatures of 2500 to 3000 K and fuel temperatures hundreds of degrees higher. One fuel design for these reactors consists of uranium carbide encapsulated in either carbon or graphite. This fuel kernel must be protected from the coolant gas, usually H2, both to prevent attack of the kernel and to limit fission product release. Refractory carbide coatings have been proposed for this purpose. The typical coating process used for this is a chemical vapor deposition. Testing of other components have indicated the superiority of refractory carbide coatings applied using a chemical vapor reaction (CVR) process, however technology to apply these coatings to large numbers of fuel particles with diameters on the order of 500 pm were not readily available. A process to deposit these CVR coatings on surrogate fuel consisting of graphite particles is described. Several types of coatings have been applied to the graphite substrate: NbC in various thicknesses and a bilayer coating consisting of NbC and TaC with a intermediate layer of pyrolytic graphite. These coated particles have been characterized prior to test; results are presented.

  14. Development of Experimental Facilities for Advanced Spent Fuel Management Technology

    Energy Technology Data Exchange (ETDEWEB)

    You, G. S.; Jung, W. M.; Ku, J. H. [and others

    2004-07-01

    The advanced spent fuel management process(ACP), proposed to reduce the overall volume of the PWR spent fuel and improve safety and economy of the long-term storage of spent fuel, is under research and development. This technology convert spent fuels into pure metal-base uranium with removing the highly heat generating materials(Cs, Sr) efficiently and reducing of the decay heat, volume, and radioactivity from spent fuel by 1/4. In the next phase(2004{approx}2006), the demonstration of this technology will be carried out for verification of the ACP in a laboratory scale. For this demonstration, the hot cell facilities of {alpha}-{gamma} type and auxiliary facilities are required essentially for safe handling of high radioactive materials. As the hot cell facilities for demonstration of the ACP, a existing hot cell of {beta}-{gamma} type will be refurbished to minimize construction expenditures of hot cell facility. In this study, the design requirements are established, and the process detail work flow was analysed for the optimum arrangement to ensure effective process operation in hot cell. And also, the basic and detail design of hot cell facility and process, and safety analysis was performed to secure conservative safety of hot cell facility and process.

  15. Advanced ECU Software Development Method for Fuel Cell Systems

    Institute of Scientific and Technical Information of China (English)

    TIAN Shuo; LIU Yuan; XIA Wenchuan; LI Jianqiu; YANG Minggao

    2005-01-01

    The electronic control unit (ECU) in electrical powered hybrid and fuel cell vehicles is exceedingly complex. Rapid prototyping control is used to reduce development time and eliminate errors during software development. This paper describes a high-efficiency development method and a flexible tool chain suitable for various applications in automotive engineering. The control algorithm can be deployed directly from a Matlab/Simulink/Stateflow environment into the ECU hardware together with an OSEK real-time operating system (RTOS). The system has been successfully used to develop a 20-kW fuel cell system ECU based on a Motorola PowerPC 555 (MPC555) microcontroller. The total software development time is greatly reduced and the code quality and reliability are greatly enhanced.

  16. Development of fuels and structural materials for fast breeder reactors

    Indian Academy of Sciences (India)

    Baldev Raj; S L Mannan; P R Vasudeva Rao; M D Mathew

    2002-10-01

    Fast breeder reactors (FBRs) are destined to play a crucial role inthe Indian nuclear power programme in the foreseeable future. FBR technology involves a multi-disciplinary approach to solve the various challenges in the areas of fuel and materials development. Fuels for FBRs have significantly higher concentration of fissile material than in thermal reactors, with a matching increase in burn-up. The design of the fuel is an important aspect which has to be optimised for efficient, economic and safe production of power. FBR components operate under hostile and demanding environment of high neutron flux, liquid sodium coolant and elevated temperatures. Resistance to void swelling, irradiation creep, and irradiation embrittlement are therefore major considerations in the choice of materials for the core components. Structural and steam generator materials should have good resistance to creep, low cycle fatigue, creep-fatigue interaction and sodium corrosion. The development of carbide fuel and structural materials for the Fast Breeder Test Reactor at Kalpakkam was a great technological challenge. At the Indira Gandhi Centre for Atomic Research (IGCAR), advanced research facilities have been established, and extensive studies have been carried out in the areas of fuel and materials development. This has laid the foundation for the design and development of a 500 MWe Prototype Fast Breeder Reactor. Highlights of some of these studies are discussed in this paper in the context of our mission to develop and deploy FBR technology for the energy security of India in the 21st century.

  17. Development of advanced LWR fuel pellet technology

    Energy Technology Data Exchange (ETDEWEB)

    Song, Kun Woo; Kang, K.W.; Kim, K. S.; Yang, J. H.; Kim, Y. M.; Kim, J. H.; Bang, J. B.; Kim, D. H.; Bae, S. O.; Jung, Y. H.; Lee, Y. S.; Kim, B. G.; Kim, S. H

    2000-03-01

    A UO{sub 2} pellet was designed to have a grain size of larger than 12 {mu}m, and a new duplex design that UO{sub 2}-Gd{sub 2}O{sub 3} is in the core and UO{sub 2}-Er{sub 2}O{sub 3} in the periphery was proposed. A master mixing method was developed to make a uniform mixture of UO{sub 2} and additives. The open porosity of UO{sub 2} pellet was reduced by only mixing AUC-UO{sub 2} powder with ADU-UO{sub 2} or milled powder. Duplex compaction tools (die and punch) were designed and fabricated, and duplex compacting procedures were developed to fabricate the duplex BA pellet. In UO{sub 2} sintering, the relations between sintering variables (additive, sintering gas, sintering temperature) and pellet properties (density, grain size, pore size) were experimentally found. The UO{sub 2}-U{sub 3}O{sub 8} powder which is inherently not sinterable to high density could be sintered well with the aid of additives. U{sub 3}O{sub 8} single crystals were added to UO{sub 2} powder, and homogeneous powder mixture was pressed and sintered in a reducing atmosphere. This technology leads to a large-grained pellet of 12-20 {mu}m. In UO{sub 2}-Gd{sub 2}O{sub 3} sintering, the relations between sintering variables (additives, sintering gas) and pellet properties (density, grain size) were experimentally found. The developed technology of fabricating a large-grained UO{sub 2} pellet has been optimized in a lab scale. Pellet properties were investigated in the fields of (1) creep properties, (2) thermal properties, (3) O/M ratios and (4) unit cell lattice. (author)

  18. Economic incentives and recommended development for commercial use of high burnup fuels in the once-through LWR fuel cycle

    Energy Technology Data Exchange (ETDEWEB)

    Stout, R.B.; Merckx, K.R.; Holm, J.S.

    1981-01-01

    This study calculates the reduced uranium requirements and the economic incentives for increasing the burnup of current design LWR fuels from the current range of 25 to 35 MWD/Kg to a range of 45 to 55 MWD/Kg. The changes in fuel management strategies which may be required to accommodate these high burnup fuels and longer fuel cycles are discussed. The material behavior problems which may present obstacles to achieving high burnup or to license fuel are identified and discussed. These problems are presented in terms of integral fuel response and the informational needs for commercial and licensing acceptance. Research and development programs are outlined which are aimed at achieving a licensing position and commercial acceptance of high burnup fuels.

  19. Irradiation characteristics examination technology development of irradiated nuclear material and high burn-up fuels

    Energy Technology Data Exchange (ETDEWEB)

    Hong, Kwon Pyo; Choo, Y. S.; Oh, Y. W. [and others

    2002-12-01

    The research and development for the first year of the project are performed through specialization of researchers, information from aborad and international cooperation, securement of advanced nuclear technology, development and installation of test equipment, application of external man-power, establishment of advanced test techniques, and certified test method. 1. Absolute efficiency measurement examination technology development of gamma scanning system 2. Sample preparation technology development of SEM and EPMA for micro-structural observation and chemical composition analysis 3. Irradiated high burn-up nuclear fuel transportation and test for PWR 4. Development of hot cell examination techniques and equipment 5. Acquirement of KOLAS system. In addition to the project, the following activities are carried out as follows; - PIE of Hanaro fuel(KH99H-001) - PIE of U-Mo advanced nuclear fuel irradiated at Hanaro - PIE of Hi-MET advanced nuclear fuel irradiated at Hanaro - PIE of DUPIC project - Hot cell examination of Hanaro irradiated capsule - Leaching test of PWR fuels - Surveillance test of PWR vessels - Mechanical test of CANDU pressure tubes.

  20. Development and evaluation of carbon and binder loading in low-cost activated carbon cathodes for air-cathode microbial fuel cells

    KAUST Repository

    Wei, Bin

    2012-01-01

    Activated carbon (AC) air cathodes were constructed using variable amounts of carbon (43-171 mg cm-2) and an inexpensive binder (10 wt% polytetrafluoroethylene, PTFE), and with or without a porous cloth wipe-based diffusion layer (DL) that was sealed with PDMS. The cathodes with the highest AC loading of 171 mg cm-2, and no diffusion layer, produced 1255 ± 75 mW m-2 and did not appreciably vary in performance after 1.5 months of operation. Slightly higher power densities were initially obtained using 100 mg cm-2 of AC (1310 ± 70 mW m-2) and a PDMS/wipe diffusion layer, although the performance of this cathode decreased to 1050 ± 70 mW m-2 after 1.5 months, and 1010 ± 190 mW m-2 after 5 months. AC loadings of 43 mg cm-2 and 100 mg cm-2 did not appreciably affect performance (with diffusion layers). MFCs with the Pt catalyst and Nafion binder initially produced 1295 ± 13 mW m-2, but the performance decreased to 930 ± 50 mW m -2 after 1.5 months, and then to 890 ± 20 mW m-2 after 5 months. Cathode performance was optimized for all cathodes by using the least amount of PTFE binder (10%, in tests using up to 40%). These results provide a method to construct cathodes for MFCs that use only inexpensive AC and a PTFE, while producing power densities similar to those of Pt/C cathodes. The methods used here to make these cathodes will enable further tests on carbon materials in order to optimize and extend the lifetime of AC cathodes in MFCs. © 2012 The Royal Society of Chemistry.

  1. Long life Regenerative Fuel Cell technology development plan

    Science.gov (United States)

    Littman, Franklin D.; Cataldo, Robert L.; Mcelroy, James F.; Stedman, Jay K.

    1992-01-01

    This paper summarizes a technology roadmap for completing advanced development of a Proton Exchange Membrane (PEM) Regenerative Fuel Cell (RFC) to meet long life (20,000 hrs at 50 percent duty cycle) mobile or portable power system applications on the surface of the moon and Mars. Development of two different sized RFC power system modules is included in this plan (3 and 7.5 kWe). A conservative approach was taken which includes the development of a Ground Engineering System, Qualification Unit, and Flight Unit. This paper includes a concept description, technology assessment, development issues, development tasks, and development schedule.

  2. Field to fuel: developing sustainable biorefineries.

    Science.gov (United States)

    Jenkins, Robin; Alles, Carina

    2011-06-01

    Life-cycle assessment (LCA) can be used as a scientific decision support technique to quantify the environmental implications of various biorefinery process, feedstock, and integration options. The goal of DuPont's integrated corn biorefinery (ICBR) project, a cost-share project with the United States Department of Energy, was to demonstrate the feasibility of a cellulosic ethanol biorefinery concept. DuPont used LCA to guide research and development to the most sustainable cellulosic ethanol biorefinery design in its ICBR project and will continue to apply LCA in support of its ongoing effort with joint venture partners. Cellulosic ethanol is a biofuel which has the potential to provide a sustainable solution to the nation's growing concerns around energy supply and climate change. A successful biorefinery begins with sustainable removal of biomass from the field. Michigan State University (MSU) used LCA to estimate the environmental performance of corn grain, corn stover, and the corn cob portion of the stover, grown under various farming practices for several corn growing locations in the United States Corn Belt. In order to benchmark the future technology options for producing cellulosic ethanol with existing technologies, LCA results for fossil energy consumption and greenhouse gas (GHG) emissions are compared to alternative ethanol processes and conventional gasoline. Preliminary results show that the DuPont ICBR outperforms gasoline and other ethanol technologies in the life-cycle impact categories considered here.

  3. Development of novel fuel ion ratio diagnostic techniques

    Energy Technology Data Exchange (ETDEWEB)

    Korsholm, S. B.; Stejner, M.; Bindslev, H.; Furtula, V.; Leipold, F.; Meo, F.; Michelsen, P. K.; Moseev, D.; Nielsen, S. K.; Salewski, M. [Association EURATOM-Risoe DTU, 4000 Roskilde (Denmark); Conroy, S.; Ericsson, G. [Association EURATOM-VR, Uppsala University, 75120 Uppsala (Sweden); Gorini, G.; Tardocchi, M. [Association EURATOM-ENEA CNR, 20125 Milano (Italy); Hellermann, M. von; Lischtschenko, O.; Delabie, E. [Association EURATOM-FOM, 3430 BE Nieuwegein (Netherlands); Jaspers, R. J. E. [Department of Applied Physics, Fusion Group, Eindhoven University of Technology, 5612 AZ Eindhoven (Netherlands)

    2010-10-15

    To overcome the challenge of measuring the fuel ion ratio in the core ({rho}<0.3) of ITER, a coordinated effort aiming at developing diagnostic techniques has been initiated. The investigated techniques are novel uses or further development of existing methods such as charge exchange recombination spectrometry, neutron spectrometry, and collective Thomson scattering. An overview of the work on the three diagnostic techniques is presented.

  4. DOD Alternative Fuels: Policy, Initiatives and Legislative Activity

    Science.gov (United States)

    2012-12-14

    Biorefinery Systems Program. p. 40. 30 U.S. Department of Agriculture, U.S. Department of Agriculture, USDA FY2013 Budget Summary and Annual Performance Plan...Energy: Biomass and Biorefinery Systems Program. p. 40. DOD Alternative Fuels: Policy, Initiatives and Legislative Activity Congressional... Biorefinery Systems R&D. — ... The Committee recommends $203,000,000 for Biomass and Biorefinery Systems R&D, $3,000,000 above fiscal year 2012 and

  5. US Progress on Property Characterization to Support LEU U-10 Mo Monolithic Fuel Development

    Energy Technology Data Exchange (ETDEWEB)

    Cole, James Irvin [Idaho National Laboratory; Rabin, Barry H [Idaho National Laboratory; Smith, James Arthur [Idaho National Laboratory; Scott, Clark Landon [Idaho National Laboratory; Benefiel, Bradley Curtis [Idaho National Laboratory; Larsen, Eric David [Idaho National Laboratory; Lind, Robert Paul [Idaho National Laboratory; Sell, David Alan [Idaho National Laboratory

    2016-03-01

    The US High Performance Research Reactor program is pursuing development and qualification of a new high density monolithic LEU fuel to facilitate conversion of five higher power research reactors located in the US (ATR, HFIR, NBSR, MIT and MURR). In order to support fabrication development and fuel performance evaluations, new testing capabilities are being developed to evaluate the properties of fuel specimens. Residual stress and fuel-cladding bond strength are two characteristics related to fuel performance that are being investigated. In this overview, new measurement capabilities being developed to assess these characteristics in both fresh and irradiated fuel are described. Progress on fresh fuel testing is summarized and on-going hot-cell implementation efforts to support future PIE campaigns are detailed. It is anticipated that benchmarking of as-fabricated fuel characteristics will be critical to establishing technical bases for specifications that optimize fuel fabrication and ensure acceptable in-reactor fuel performance.

  6. A membraneless alkaline direct liquid fuel cell (DLFC) platform developed with a catalyst-selective strategy

    Science.gov (United States)

    Yu, Xingwen; Pascual, Emilio J.; Wauson, Joshua C.; Manthiram, Arumugam

    2016-11-01

    With a logical management of the catalyst selectivity, we present a scalable, membraneless alkaline direct liquid fuel cell (DLFC) platform. The uniqueness of this innovation is that the inexpensive (non-platinum) cathode catalysts, based on strongly coupled transition-metal-oxide nanocrystals and nano-structured carbon materials (e. g., NiCo2O4 nano-particles on a nitrogen-doped graphene and MnNiCoO4 nano-particles on a nitrogen-doped multi-wall carbon nanotube), exhibit high activity for the oxygen reduction reaction (ORR) but without activity for the anode fuel oxidation reaction (FOR). Therefore, operation of the DLFCs allows the anode fuel to freely enter the cathode. This strategy avoids the reliance on expensive or difficult-to-develop cation- or anion-exchange membranes and circumvents the scalability concerns of the conventional membraneless DLFCs that are operated under a laminar-flow principle. With proper catalyst selectivity, a variety of organic liquids can be used as anode fuels. The high power density delivered by the membraneless DLFCs with inexpensive components and safe fuels can enable the development of not only small-scale portable power sources but also large-scale energy generation systems for transportation and stationary storage.

  7. Developments in fluidized bed conversion of solid fuels

    Directory of Open Access Journals (Sweden)

    Leckner Bo

    2016-01-01

    Full Text Available A summary is given on the development of fluidized bed conversion (combustion and gasification of solid fuels. First, gasification is mentioned, following the line of development from the Winkler gasifier to recent designs. The combustors were initially bubbling beds, which were found unsuitable for combustion of coal because of various drawbacks, but they proved more useful for biomass where these drawbacks were absent. Instead, circulating fluidized bed boilers became the most important coal converters, whose design now is quite mature, and presently the increments in size and efficiency are the most important development tasks. The new modifications of these conversion devices are related to CO2 capture. Proposed methods with this purpose, involving fluidized bed, are single-reactor systems like oxy-fuel combustion, and dual-reactor systems, including also indirect biomass gasifiers.

  8. Technology development of nuclear material safeguards for DUPIC fuel cycle

    Energy Technology Data Exchange (ETDEWEB)

    Hong, Jong Sook; Kim, Ho Dong; Kang, Hee Young; Lee, Young Gil; Byeon, Kee Ho; Park, Young Soo; Cha, Hong Ryul; Park, Ho Joon; Lee, Byung Doo; Chung, Sang Tae; Choi, Hyung Rae; Park, Hyun Soo

    1997-07-01

    During the second phase of research and development program conducted from 1993 to 1996, nuclear material safeguards studies system were performed on the technology development of DUPIC safeguards system such as nuclear material measurement in bulk form and product form, DUPIC fuel reactivity measurement, near-real-time accountancy, and containment and surveillance system for effective and efficient implementation of domestic and international safeguards obligation. By securing in advance a optimized safeguards system with domestically developed hardware and software, it will contribute not only to the effective implementation of DUPIC safeguards, but also to enhance the international confidence build-up in peaceful use of spent fuel material. (author). 27 refs., 13 tabs., 89 figs.

  9. The use of microbial gene abundance in the development of fuel remediation guidelines in polar soils.

    Science.gov (United States)

    Richardson, Elizabeth L; King, Catherine K; Powell, Shane M

    2015-04-01

    Terrestrial fuel spills in Antarctica commonly occur on ice-free land around research stations as the result of human activities. Successful spill clean-ups require appropriate targets that confirm contaminated sites are no longer likely to pose environmental risk following remediation. These targets are based on knowledge of the impacts of contaminants on the soil ecosystem and on the response of native biota to contamination. Our work examined the response of soil microbial communities to fuel contamination by measuring the abundance of genes involved in critical soil processes, and assessed the use of this approach as an indicator of soil health in the presence of weathered and fresh fuels. Uncontaminated and contaminated soils were collected from the site of remediation treatment of an aged diesel spill at Casey Station, East Antarctica in December 2012. Uncontaminated soil was spiked with fresh Special Antarctic Blend (SAB) diesel to determine the response of the genes to fresh fuel. Partly remediated soil containing weathered SAB diesel was diluted with uncontaminated soil to simulate a range of concentrations of weathered fuel and used to determine the response of the genes to aged fuel. Quantitative PCR (qPCR) was used to measure the abundance of rpoB, alkB, cat23, and nosZ in soils containing SAB diesel. Differences were observed between the abundance of genes in control soils versus soils containing weathered and fresh fuels. Typical dose-response curves were generated for genes in response to the presence of fresh fuel. In contrast, the response of these genes to the range of weathered fuel appeared to be due to dilution, rather than to the effect of the fuel on the microbial community. Changes in microbial genes in response to fresh contamination have potential as a sensitive measure of soil health and for assessments of the effect of fuel spills in polar soils. This will contribute to the development of remediation guidelines to assist in management

  10. Model development for quantitative evaluation of proliferation resistance of nuclear fuel cycles

    Energy Technology Data Exchange (ETDEWEB)

    Ko, Won Il; Kim, Ho Dong; Yang, Myung Seung

    2000-07-01

    This study addresses the quantitative evaluation of the proliferation resistance which is important factor of the alternative nuclear fuel cycle system. In this study, model was developed to quantitatively evaluate the proliferation resistance of the nuclear fuel cycles. The proposed models were then applied to Korean environment as a sample study to provide better references for the determination of future nuclear fuel cycle system in Korea. In order to quantify the proliferation resistance of the nuclear fuel cycle, the proliferation resistance index was defined in imitation of an electrical circuit with an electromotive force and various electrical resistance components. The analysis on the proliferation resistance of nuclear fuel cycles has shown that the resistance index as defined herein can be used as an international measure of the relative risk of the nuclear proliferation if the motivation index is appropriately defined. It has also shown that the proposed model can include political issues as well as technical ones relevant to the proliferation resistance, and consider all facilities and activities in a specific nuclear fuel cycle (from mining to disposal). In addition, sensitivity analyses on the sample study indicate that the direct disposal option in a country with high nuclear propensity may give rise to a high risk of the nuclear proliferation than the reprocessing option in a country with low nuclear propensity.

  11. Active and passive measures to maintain pressure in LNG fuel systems for ships

    OpenAIRE

    Hernes, Hugo Eugen

    2015-01-01

    The purpose of this master thesis is to investigate the effects of active and passive measures to maintain the pressure in LNG fuel systems for ships. The background was two de-loading events that occurred on the gas engines on KV Bergen, a Norwegian Coast Guard vessel, in 2012 and 2013. The events triggered research, both on why a sudden large drop in the fuel tank pressure can occur, and how they could be prevented in the future. The task required development of two models or simulation ...

  12. Development of sensors for hydrogen safety on fuel cell vehicles

    Energy Technology Data Exchange (ETDEWEB)

    Kitanoya, S.; Furusaki, K.; Inoue, R.; Watanabe, M.; Matsuno, T.; Ichikawa, D. [NGK Spark Plug Co. Ltd, Aichi (Japan)

    2007-07-01

    When combusted, hydrogen fuel used in fuel cell vehicles (FCV) generates water only. Although this technology can help protect against global warming, the safety of hydrogen fuel must be resolved before widespread use of hydrogen-based FCVs can be realized. Hydrogen gas has a broad flammability range and will ignite when mixed with air in the ranges from 4 to 75 per cent. The primary technical requirement for FCV safety is to detect hydrogen leaks and shut off the hydrogen gas. Hydrogen sensors that detect hydrogen leaks are an important part of the safety issue. This paper presented 2 newly developed hydrogen sensors in which micro-electromechanical system (MEMS) technology was used to build a micro-heater with very small heat capacity. Both sensors have different detection principles. One is placed above the hydrogen tank and fuel cells. This combustion type sensor uses catalytic combustion of the hydrogen on the micro-heater. It features quick start-up and high accuracy. The other type of hydrogen sensor can be place in a hydrogen gas purging pipe. This thermal conduction-type sensor can detect the change in thermal conductivity of the gas. The catalytic combustion sensor is based on the detection of the voltage difference between the detection heater and reference heater. 6 refs., 3 tabs., 24 figs.

  13. Development of Melting Crucible Materials of Metallic Fuel Slug for SFR

    Energy Technology Data Exchange (ETDEWEB)

    Kim, K. H.; Lee, C. T.; Oh, S. J.; Kim, S. K.; Lee, C. B.; Ko, Y. M.; Woo, W. M

    2010-01-15

    The fabrication process of metallic fuel for SFR(sodium fast reactor) of Generation-IV candidate reactors is composed of the fabrication of fuel pin, fuel rod, and fuel assembly. The key technology of the fabrication process for SFR can be referred to the fabrication technology of fuel pin. As SFR fuel contains MA(minor actinide) elements proceeding the recycling of actinide elements, it is so important to extinguish MA during irradiation in SFR, included in nuclear fuel through collection of volatile MA elements during fabrication of fuel pin. Hence, it is an imminent circumstance to develop the fabrication process of fuel pin. This report is an state-of art report related to the characteristics of irradiation performance for U-Zr-Pu metallic fuel, and the apparatus and the technology of conventional injection casting process. In addition, to overcome the drawbacks of the conventional injection casting and the U-Zr-Pu fuel, new fabrication technologies such as the gravity casting process, the casting of fuel pin to metal-barrier mold, the fabrication of particulate metallic fuel utilizing centrifugal atomization is surveyed and summarized. The development of new U-10Mo-X metallic fuel as nuclear fuel having a single phase in the temperature range between 550 and 950 .deg. C, reducing the re-distribution of the fuel elements and improving the compatibility between fuel and cladding, is also surveyed and summarized.

  14. A development of solid oxide fuel cell technology

    Energy Technology Data Exchange (ETDEWEB)

    Lim, Hee Chun; Lee, Chang Woo [Korea Electric Power Corp. (KEPCO), Taejon (Korea, Republic of). Research Center; Kim, Kwy Youl; Yoon, Moon Soo; Kim, Ho Ki; Kim, Young Sik; Mun, Sung In; Eom, Sung Wuk [Korea Electrotechnology Research Inst., Changwon (Korea, Republic of)

    1995-12-31

    Solid oxide fuel cell which was consisted of ceramics has high power density and is very simple in shape. The project named A development of SOFC(Solid Oxide Fuel Cell) technology is to develop the unit cell fabrication processing and to evaluate the unit cell of solid oxide full cell. In this project, a manufacturing process of cathode by citrate method and polymeric precursor methods were established. By using tape casting method, high density thin electrolyte was manufactured and has high performance. Unit cell composed with La{sub 17}Sr{sub 13}Mn{sub 3} as cathode, 8YSZ electrolyte and 50% NiYSZ anode had a performance of O.85 W/cm{sup 2} and recorded 510 hours operation time. On the basis of these results. 100 cm{sup 2} class unit cell will be fabricated and tests in next program (author). 59 refs., 120 figs.

  15. Activity targets for nanostructured platinum-group-metal-free catalysts in hydroxide exchange membrane fuel cells

    Science.gov (United States)

    Setzler, Brian P.; Zhuang, Zhongbin; Wittkopf, Jarrid A.; Yan, Yushan

    2016-12-01

    Fuel cells are the zero-emission automotive power source that best preserves the advantages of gasoline automobiles: low upfront cost, long driving range and fast refuelling. To make fuel-cell cars a reality, the US Department of Energy has set a fuel cell system cost target of US$30 kW-1 in the long-term, which equates to US$2,400 per vehicle, excluding several major powertrain components (in comparison, a basic, but complete, internal combustion engine system costs approximately US$3,000). To date, most research for automotive applications has focused on proton exchange membrane fuel cells (PEMFCs), because these systems have demonstrated the highest power density. Recently, however, an alternative technology, hydroxide exchange membrane fuel cells (HEMFCs), has gained significant attention, because of the possibility to use stable platinum-group-metal-free catalysts, with inherent, long-term cost advantages. In this Perspective, we discuss the cost profile of PEMFCs and the advantages offered by HEMFCs. In particular, we discuss catalyst development needs for HEMFCs and set catalyst activity targets to achieve performance parity with state-of-the-art automotive PEMFCs. Meeting these targets requires careful optimization of nanostructures to pack high surface areas into a small volume, while maintaining high area-specific activity and favourable pore-transport properties.

  16. Activity targets for nanostructured platinum-group-metal-free catalysts in hydroxide exchange membrane fuel cells.

    Science.gov (United States)

    Setzler, Brian P; Zhuang, Zhongbin; Wittkopf, Jarrid A; Yan, Yushan

    2016-12-06

    Fuel cells are the zero-emission automotive power source that best preserves the advantages of gasoline automobiles: low upfront cost, long driving range and fast refuelling. To make fuel-cell cars a reality, the US Department of Energy has set a fuel cell system cost target of US$30 kW(-1) in the long-term, which equates to US$2,400 per vehicle, excluding several major powertrain components (in comparison, a basic, but complete, internal combustion engine system costs approximately US$3,000). To date, most research for automotive applications has focused on proton exchange membrane fuel cells (PEMFCs), because these systems have demonstrated the highest power density. Recently, however, an alternative technology, hydroxide exchange membrane fuel cells (HEMFCs), has gained significant attention, because of the possibility to use stable platinum-group-metal-free catalysts, with inherent, long-term cost advantages. In this Perspective, we discuss the cost profile of PEMFCs and the advantages offered by HEMFCs. In particular, we discuss catalyst development needs for HEMFCs and set catalyst activity targets to achieve performance parity with state-of-the-art automotive PEMFCs. Meeting these targets requires careful optimization of nanostructures to pack high surface areas into a small volume, while maintaining high area-specific activity and favourable pore-transport properties.

  17. Real-world activity, fuel use, and emissions of diesel side-loader refuse trucks

    Science.gov (United States)

    Sandhu, Gurdas S.; Frey, H. Christopher; Bartelt-Hunt, Shannon; Jones, Elizabeth

    2016-03-01

    Diesel refuse trucks have the worst fuel economy of onroad highway vehicles. The real-world effectiveness of recently introduced emission controls during low speed and low engine load driving has not been verified for these vehicles. A portable emission measurement system (PEMS) was used to measure rates of fuel use and emissions on six side-loader refuse trucks. The objectives were to: (1) characterize activity, fuel use, and emissions; (2) evaluate variability between cycles and trucks; and (3) compare results with the MOVES emission factor model. Quality assured data cover 210,000 s and 550 miles of operation during which the trucks collected 4200 cans and 50 tons of waste material. The average fuel economy was 2.6 mpg. Trash collection contributed 70%-80% of total fuel use and emissions. The daily activity Operating Mode (OpMode) distribution and cycle average fuel use and emissions is different from previously used cycles such as Central Business District (CBD), New York Garbage Truck (NYGT), and William H. Martin (WHM). NOx emission rates for trucks with selective catalytic reduction were over 90% lower than those for trucks without. Similarly, trucks with diesel particulate filters had over 90% lower particulate matter (PM) emissions than trucks without. Compared to unloaded trucks, loaded truck averaged 18% lower fuel economy while NOx and PM emissions were higher by 65% and 16%, respectively. MOVES predicted values are highly correlated to empirical data; however, MOVES estimates are 37% lower for NOx and 300% higher for PM emission rates. The data presented here can be used to develop more representative cycles and improve emission factors for side-loader refuse trucks, which in turn can improve the accuracy of refuse truck emission inventories.

  18. Development of large scale internal reforming molten carbonate fuel cell

    Energy Technology Data Exchange (ETDEWEB)

    Sasaki, A.; Shinoki, T.; Matsumura, M. [Mitsubishi Electric Corp., Hyogo (Japan)

    1996-12-31

    Internal Reforming (IR) is a prominent scheme for Molten Carbonate Fuel Cell (MCFC) power generating systems in order to get high efficiency i.e. 55-60% as based on the Higher Heating Value (HHV) and compact configuration. The Advanced Internal Reforming (AIR) technology has been developed based on two types of the IR-MCFC technology i.e. Direct Internal Reforming (DIR) and Indirect Internal Reforming (DIR).

  19. Development of nuclear fuel cycle technologies - bases of long-term provision of fuel and environmental safety of nuclear power

    Energy Technology Data Exchange (ETDEWEB)

    Solonin, M.I.; Polyakov, A.S.; Zakharkin, B.S.; Smelov, V.S.; Nenarokomov, E.A.; Mukhin, I.V. [SSC, RF, A.A. Bochvar ALL-Russia Research Institute of Inorganic Materials, Moscow (Russian Federation)

    2000-07-01

    To-day nuclear power is one of the options, however, to-morrow it may become the main source of the energy, thus, providing for the stable economic development for the long time to come. The availability of the large-scale nuclear power in the foreseeable future is governed by not only the safe operation of nuclear power plants (NPP) but also by the environmentally safe management of spent nuclear fuel, radioactive waste conditioning and long-term storage. More emphasis is to be placed to the closing of the fuel cycle in view of substantial quantities of spent nuclear fuel arisings. The once-through fuel cycle that is cost effective at the moment cannot be considered to be environmentally safe even for the middle term since the substantial build-up of spent nuclear fuel containing thousands of tons Pu will require the resolution of the safe management problem in the nearest future and is absolutely unjustified in terms of moral ethics as a transfer of the responsibility to future generations. The minimization of radioactive waste arisings and its radioactivity is only feasible with the closed fuel cycle put into practice and some actinides and long-lived fission radionuclides burnt out. The key issues in providing the environmentally safe fuel cycle are efficient processes of producing fuel for NPP, radionuclide after-burning included, a long-term spent nuclear fuel storage and reprocessing as well as radioactive waste management. The paper deals with the problems inherent in producing fuel for NPP with a view for the closed fuel cycle. Also discussed are options of the fuel cycle, its effectiveness and environmental safety with improvements in technologies of spent nuclear fuel reprocessing and long-lived radionuclide partitioning. (authors)

  20. Tractor Mechanics: Maintaining and Servicing the Fuel System. Learning Activity Packages 20-33.

    Science.gov (United States)

    Clemson Univ., SC. Vocational Education Media Center.

    Learning activity packages are presented for instruction in tractor mechanics. The packages deal with the duties involved in maintaining the fuel system. The following fourteen learning activity packages are included: servicing fuel and air filters, servicing fuel tanks and lines, adjusting a carburetor, servicing a carburetor, servicing the…

  1. Development of Fabrication Technology for Ceramic Nuclear Fuel

    Energy Technology Data Exchange (ETDEWEB)

    Kim, H. S.; Lee, Y. W.; Na, S. H.; Kim, Y. G.; Jung, C. Y.; Kim, S. H.; Lee, S. C.; Son, D. S

    2006-04-15

    Purpose and Necessity Research purposes for the 3rd stage were to reaffirm the MOX fabrication processes and to establish the process database, based on the fabrication technology developed during the previous stage. This project was also proceeded to improve the fuel performance and to accomplish the inherent MOX technology for PWR. The fabrication processes should be proceeded in the glove boxes because the raw powders of MOX fuel is very toxic. Therefore, some special technology were needed to develop besides the fuel fabrication technology. Both core technology and steadiness of fabrication process are important to obtain homogeneity and thermo-physical properties of MOX fuel pellet. By developing these technology in fashion unique to ourselves, we can take the initiative in the nuclear fuel for next generation. The uranium price has been increasing along with the oil price recently. We have to secure the MOX fabrication technology which serves the effective use of uranium resource. Improvement of pellet characteristics along with the MOX irradiation analysis: Collection and monitoring of the MOX irradiation data, Establishment of the improvement methods of pellet characteristics Establishment of the MOX pellet fabrication process by the unique technology, Establishment of database with the MOX fabrication parameters and characteristics, Analysis of co-relation and re-appearance of the pellet characteristics affected by each process parameter, Construction of feedback system between database and process, Application of the unique fabrication technology to the industrial spot. Applicability of the unique fabrication processes to the glove box technology, Installment of process equipment in the glove box and development of operation skill, Methods for modifying, handling, maintaining and fixing of glove box and subsidiary, Construction of transport channel for the connection between glove boxes - MOX fabrication by the unique technology in the glove box. Research

  2. Development of 50 kW Fuel Processor for Stationary Fuel Cell Applications

    Energy Technology Data Exchange (ETDEWEB)

    James F. Stevens; Balaji Krishnamurthy; Paolina Atanassova; Kerry Spilker

    2007-08-29

    The objective of the project was to develop and test a fuel processor capable of producing high hydrogen concentration (>98%) with less than ppm quantities of carbon dioxide and carbon monoxide at lower capital cost and higher efficiency, compared to conventional natural gas reformers. It was intended that we achieve our objective by developing simple reactor/process design, and high durability CO2 absorbents, to replace pressure swing adsorption (PSA) or membrane separators. Cost analysis indicated that we would not meet DOE cost goals so the project was terminated before construction of the full scale fuel processor. The work on adsorbent development was focused on the development of calcium oxide-based reversible CO2 absorbents with various microstructures and morphologies to determine the optimum microstructure for long-term reversible CO2 absorption. The effect of powder production process variables was systematically studied including: the final target compositions, the reagents from which the final products were derived, the pore forming additives, the processing time and temperature. The sorbent materials were characterized in terms of their performance in the reversible reaction with CO2 and correlation made to their microstructure.

  3. CMMs Development Activities

    Institute of Scientific and Technical Information of China (English)

    HU Jun; HU Yefa; HUANG Anyi

    2006-01-01

    The coordinate measuring machine (CMM) has been an important role in the digital manufacturing. This paper reviews CMM early stage development history and current activities. The authors provide some ideas about the areas that academic research can help to the CMMs development.

  4. Development of Low-Intermediate Temperature Fuel Cells for Direct Conversion of Methane to Methanol Fuel

    Energy Technology Data Exchange (ETDEWEB)

    Torabi, Alireza; Barton, Joseph D.; Willman, Carl; Ghezel-Ayagh, Hossein; Li, Na; Poozhikunnath, Abhinav; Maric, Radenka; Marina, Olga A.

    2017-09-26

    The objective of this project is development of a durable, low-cost, and high performance Low Temperature Solid Oxide Fuel Cell (LT-SOFC) for direct conversion of methane to methanol and other liquids, characterized by: a) operating temperature < 500oC, b) current density of > 100 mA/cm2 in liquid hydrocarbon production mode, c) continuous operation of > 100 h, d) cell area >100 cm2, e) cell cost per rate of product output < 100,000/bpd, f) process intensity of > 0.1 bpd/ft3, g) product yield and carbon efficiency > 50%, and h) volumetric output per cell > 30 L/day.

  5. OPTIMIZATION METHOD AND SOFTWARE FOR FUEL COST REDUCTION IN CASE OF ROAD TRANSPORT ACTIVITY

    Directory of Open Access Journals (Sweden)

    György Kovács

    2017-06-01

    Full Text Available The transport activity is one of the most expensive processes in the supply chain and the fuel cost is the highest cost among the cost components of transportation. The goal of the research is to optimize the transport costs in case of a given transport task both by the selecting the optimal petrol station and by determining the optimal amount of the refilled fuel. Recently, in practice, these two decisions have not been made centrally at the forwarding company, but they depend on the individual decision of the driver. The aim of this study is to elaborate a precise and reliable mathematical method for selecting the optimal refuelling stations and determining the optimal amount of the refilled fuel to fulfil the transport demands. Based on the elaborated model, new decision-supporting software is developed for the economical fulfilment of transport trips.

  6. Development and Experimental Evaluation of Passive Fuel Cell Thermal Control

    Science.gov (United States)

    Colozza, Anthony J.; Jakupca, Ian J.; Castle, Charles H.; Burke, Kenneth A.

    2014-01-01

    To provide uniform cooling for a fuel cell stack, a cooling plate concept was evaluated. This concept utilized thin cooling plates to extract heat from the interior of a fuel cell stack and move this heat to a cooling manifold where it can be transferred to an external cooling fluid. The advantages of this cooling approach include a reduced number of ancillary components and the ability to directly utilize an external cooling fluid loop for cooling the fuel cell stack. A number of different types of cooling plates and manifolds were developed. The cooling plates consisted of two main types; a plate based on thermopyrolytic graphite (TPG) and a planar (or flat plate) heat pipe. The plates, along with solid metal control samples, were tested for both thermal and electrical conductivity. To transfer heat from the cooling plates to the cooling fluid, a number of manifold designs utilizing various materials were devised, constructed, and tested. A key aspect of the manifold was that it had to be electrically nonconductive so it would not short out the fuel cell stack during operation. Different manifold and cooling plate configurations were tested in a vacuum chamber to minimize convective heat losses. Cooling plates were placed in the grooves within the manifolds and heated with surface-mounted electric pad heaters. The plate temperature and its thermal distribution were recorded for all tested combinations of manifold cooling flow rates and heater power loads. This testing simulated the performance of the cooling plates and manifold within an operational fuel cell stack. Different types of control valves and control schemes were tested and evaluated based on their ability to maintain a constant temperature of the cooling plates. The control valves regulated the cooling fluid flow through the manifold, thereby controlling the heat flow to the cooling fluid. Through this work, a cooling plate and manifold system was developed that could maintain the cooling plates

  7. Development of a Turnkey Hydrogen Fueling Station Final Report

    Energy Technology Data Exchange (ETDEWEB)

    David E. Guro; Edward Kiczek; Kendral Gill; Othniel Brown

    2010-07-29

    The transition to hydrogen as a fuel source presents several challenges. One of the major hurdles is the cost-effective production of hydrogen in small quantities (less than 1MMscf/month). In the early demonstration phase, hydrogen can be provided by bulk distribution of liquid or compressed gas from central production plants; however, the next phase to fostering the hydrogen economy will likely include onsite generation and extensive pipeline networks to help effect a pervasive infrastructure. Providing inexpensive hydrogen at a fleet operator’s garage or local fueling station is a key enabling technology for direct hydrogen Fuel Cell Vehicles (FCVs). The objective of this project was to develop a comprehensive, turnkey, stand-alone, commercial hydrogen fueling station for FCVs with state-of-the-art technology that is cost-competitive with current hydrocarbon fuels. Such a station would promote the advent of the hydrogen fuel economy for buses, fleet vehicles, and ultimately personal vehicles. Air Products, partnering with the U.S. Department of Energy (DOE), The Pennsylvania State University, Harvest Energy Technology, and QuestAir, developed a turnkey hydrogen fueling station on the Penn State campus. Air Products aimed at designing a station that would have 65% overall station efficiency, 82% PSA (pressure swing adsorption) efficiency, and the capability of producing hydrogen at $3.00/kg (gge) H2 at mass production rates. Air Products designed a fueling station at Penn State from the ground up. This project was implemented in three phases. The first phase evaluated the various technologies available in hydrogen generation, compression, storage, and gas dispensing. In the second phase, Air Products designed the components chosen from the technologies examined. Finally, phase three entailed a several-month period of data collection, full-scale operation, maintenance of the station, and optimization of system reliability and performance. Based on field data

  8. Application and Development of Biomass Fuels for Transportation in China

    Institute of Scientific and Technical Information of China (English)

    WANG Jianxin; SHUAI Shijin; CHEN Hu

    2007-01-01

    Biomass fuels have become a big concern due to the large increase in green house gases and the rapid rise of petroleum prices around the world. This paper reviews recent developments in biomass fuels,such as ethanol and biodiesel, in China. Ethanol-gasoline mixture (E10) for vehicles is currently distributed in nine provinces while biodiesel is under development. One way to extend the application of ethanol is to burn it in diesel engines to lower soot emissions. The effects of the different methods blending ethanol with fossil diesel, and blending biodiesel with fossil diesel and ethanol-diesel on the combustion and emissions are investigated. The test results show that ethanol and biodiesel can be mixed with fossil diesel to greatly reduce particulate matter and soot emissions from diesel engines. But the application of ethanol blending with fossil diesel is more difficult than that of ethanol blending with gasoline, and biodiesel blending with fossil diesel. The dual-fuel injection of ethanol and diesel systems has the highest smoke reduction effect for a high ethanol fraction.

  9. Simulated Coal-Gas-Fueled Molten Carbonate Fuel Cell Development Program. Final report

    Energy Technology Data Exchange (ETDEWEB)

    1992-08-01

    This final report summarizes the technical work performed under Department of Energy Contract DE-AC21-91MC27393, ``Simulated Coal- Gas-Fueled Molten Carbonate Fuel Cell Development Program.`` This work consists of five major tasks and their respective subtasks as listed below. A brief description of each task is also provided. The Stack Design Requirements task focused on requirements and specification for designing, constructing, and testing a nominal 100-kilowatt integrated stack and on requirements for the balance-of-plant equipment to support a 1000-kilowatt integrated stack demonstrator. The Stack Design Preparation task focused on the mechanical design of a 100-kilowatt stack comprised of 8-ft{sup 2} cells incorporating the new cell configuration and component technology improvements developed in the previous DOE MCFC contract. Electrode Casting focused on developing a faster drying solvent for use in the electrode tape casting process. Electrode Heat Treatment was directed at scaling up the laboratory continuous debinding process to a new full-size IFC debinding oven coupled to a continuous belt furnace that will both debind and sinter the electrodes in one continuous process train. Repeat Part Quality Assurance and Testing provided the appropriate effort to ensure consistent, high-quality, reproducible and comparable repeat parts.

  10. Simulated Coal-Gas-Fueled Molten Carbonate Fuel Cell Development Program

    Energy Technology Data Exchange (ETDEWEB)

    1992-08-01

    This final report summarizes the technical work performed under Department of Energy Contract DE-AC21-91MC27393, Simulated Coal- Gas-Fueled Molten Carbonate Fuel Cell Development Program.'' This work consists of five major tasks and their respective subtasks as listed below. A brief description of each task is also provided. The Stack Design Requirements task focused on requirements and specification for designing, constructing, and testing a nominal 100-kilowatt integrated stack and on requirements for the balance-of-plant equipment to support a 1000-kilowatt integrated stack demonstrator. The Stack Design Preparation task focused on the mechanical design of a 100-kilowatt stack comprised of 8-ft[sup 2] cells incorporating the new cell configuration and component technology improvements developed in the previous DOE MCFC contract. Electrode Casting focused on developing a faster drying solvent for use in the electrode tape casting process. Electrode Heat Treatment was directed at scaling up the laboratory continuous debinding process to a new full-size IFC debinding oven coupled to a continuous belt furnace that will both debind and sinter the electrodes in one continuous process train. Repeat Part Quality Assurance and Testing provided the appropriate effort to ensure consistent, high-quality, reproducible and comparable repeat parts.

  11. The DOE advanced gas reactor fuel development and qualification program

    Science.gov (United States)

    Petti, David; Maki, John; Hunn, John; Pappano, Pete; Barnes, Charles; Saurwein, John; Nagley, Scott; Kendall, Jim; Hobbins, Richard

    2010-09-01

    The high outlet temperatures and high thermal-energy conversion efficiency of modular high-temperature gas-cooled reactors (HTGRs) enable an efficient and cost-effective integration of the reactor system with non-electricity-generation applications, such as process heat and/or hydrogen production, for the many petrochemical and other industrial processes that require temperatures between 300°C and 900°C. The U.S. Department of Energy (DOE) has selected the HTGR concept for the Next Generation Nuclear Plant (NGNP) Project as a transformative application of nuclear energy that will demonstrate emissions-free nuclear-assisted electricity, process heat, and hydrogen production, thereby reducing greenhouse-gas emissions and enhancing energy security. The objective of the DOE Advanced Gas Reactor (AGR) Fuel Development and Qualification program is to qualify tristructural isotropic (TRISO)-coated particle fuel for use in HTGRs. An overview of the program and recent progress is presented.

  12. Development and optimisation of electrodematerials in solid oxide fuel cells

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    Solid oxide fuel cell (SOFC) is an all solid electrochemical device to convert fuels such as hydrogen and natural gas to electricity with high efficiency and very low greenhouse gas emission compared to traditional thermal power generation plants. Moreover, the reliability and efficiency of SOFC is critically dependent on the performance and stability of its components including anode, cathode and electrolyte. This in turn is largely dependent on the material selection and the fabrication processes. In this paper, specific examples are given to demonstrate strategy and process in the development and optimisation of electrode materials such as Ni/Y2O3-ZrO2 cermet anodes and (LaSr)MnO3 based cathodes. The results also demonstrate the importance of fabrication processes and that the understanding of the electrode process plays a very important role in the optimisation process of electrode materials.

  13. Full scale phosphoric acid fuel cell stack technology development

    Science.gov (United States)

    Christner, L.; Faroque, M.

    1984-01-01

    The technology development for phosphoric acid fuel cells is summarized. The preparation, heat treatment, and characterization of carbon composites used as bipolar separator plates are described. Characterization included resistivity, porosity, and electrochemical corrosion. High density glassy carbon/graphite composites performed well in long-term fuel cell endurance tests. Platinum alloy cathode catalysts and low-loaded platinum electrodes were evaluated in 25 sq cm cells. Although the alloys displayed an initial improvement, some of this improvement diminished after a few thousand hours of testing. Low platinum loading (0.12 mg/sq cm anodes and 0.3 mg/sq cm cathodes) performed nearly as well as twice this loading. A selectively wetproofed anode backing paper was tested in a 5 by 15 inch three-cell stack. This material may provide for acid volume expansion, acid storage, and acid lateral distribution.

  14. Development of OTM Syngas Process and Testing of Syngas Derived Ultra-clean Fuels in Diesel Engines and Fuel Cells

    Energy Technology Data Exchange (ETDEWEB)

    E.T. (Skip) Robinson; James P. Meagher; Prasad Apte; Xingun Gui; Tytus R. Bulicz; Siv Aasland; Charles Besecker; Jack Chen Bart A. van Hassel; Olga Polevaya; Rafey Khan; Piyush Pilaniwalla

    2002-12-31

    This topical report summarizes work accomplished for the Program from November 1, 2001 to December 31, 2002 in the following task areas: Task 1: Materials Development; Task 2: Composite Development; Task 4: Reactor Design and Process Optimization; Task 8: Fuels and Engine Testing; 8.1 International Diesel Engine Program; 8.2 Nuvera Fuel Cell Program; and Task 10: Program Management. Major progress has been made towards developing high temperature, high performance, robust, oxygen transport elements. In addition, a novel reactor design has been proposed that co-produces hydrogen, lowers cost and improves system operability. Fuel and engine testing is progressing well, but was delayed somewhat due to the hiatus in program funding in 2002. The Nuvera fuel cell portion of the program was completed on schedule and delivered promising results regarding low emission fuels for transportation fuel cells. The evaluation of ultra-clean diesel fuels continues in single cylinder (SCTE) and multiple cylinder (MCTE) test rigs at International Truck and Engine. FT diesel and a BP oxygenate showed significant emissions reductions in comparison to baseline petroleum diesel fuels. Overall through the end of 2002 the program remains under budget, but behind schedule in some areas.

  15. Spent Fuel and Waste Management Technology Development Program. Annual progress report

    Energy Technology Data Exchange (ETDEWEB)

    Bryant, J.W.

    1994-01-01

    This report provides information on the progress of activities during fiscal year 1993 in the Spent Fuel and Waste Management Technology Development Program (SF&WMTDP) at the Idaho Chemical Processing Plant (ICPP). As a new program, efforts are just getting underway toward addressing major issues related to the fuel and waste stored at the ICPP. The SF&WMTDP has the following principal objectives: Investigate direct dispositioning of spent fuel, striving for one acceptable waste form; determine the best treatment process(es) for liquid and calcine wastes to minimize the volume of high level radioactive waste (HLW) and low level waste (LLW); demonstrate the integrated operability and maintainability of selected treatment and immobilization processes; and assure that implementation of the selected waste treatment process is environmentally acceptable, ensures public and worker safety, and is economically feasible.

  16. Leadership Development Activities

    Directory of Open Access Journals (Sweden)

    Malikeh Beheshtifar

    2012-07-01

    Full Text Available Nowadays, human resource development is considered as a developed concept in HR field. It is a process for helping personnel to conduct their duties better. Most organizations tend to leadership development as a separable subject and as areas of responsibility within organization. Whereas the leadership development plans have been unsuccessful. This article aim to draw attention to the fact that leadership development is crucial in organizations. A literature review was conducted by searching journal databases, textbooks, and relevant reports. A categorization of the evidence allowed informed discussions on the key themes surrounding leadership development activities. Leadership development is caused to employees' promotion and progress via nurture of new talents, stimulus in employees by persuade to do individual development, save time and cost, and increase customers' satisfaction by relations improvement. Accordingly, the development systems can cover a wide scope in organization. They are effective to career management, training and development, performance management, strategic human resource planning, recruitment and selection, and succession planning activities. Despite the need for further scientific and validated studies, organizations should be urged to devote sufficient resources and attention towards leadership development for promoting long-term survival and prosperity.

  17. Development of a coal-fueled Internal Manifold Heat Exchanger (IMHEX reg sign ) molten carbonate fuel cell

    Energy Technology Data Exchange (ETDEWEB)

    1991-09-01

    The design of a CGMCFC electric generation plant that will provide a cost of eletricity (COE) which is lower than that of current electric generation technologies and which is competitive with other long-range electric generating systems is presented. This effort is based upon the Internal Manifold Heat Exchanger (IMHEX) technology as developed by the Institute of Gas Technology (IGT). The project was executed by selecting economic and performance objectives for alternative plant arrangements while considering process constraints identified during IMHEX fuel cell development activities at ICT. The four major subsystems of a coal-based MCFC power plant are coal gasification, gas purification, fuel cell power generation and the bottoming cycle. The design and method of operation of each subsystem can be varied, and, depending upon design choices, can have major impact on both the design of other subsystems and the resulting cost of electricity. The challenge of this project was to select, from a range of design parameters, those operating conditions that result in a preferred plant design. Computer modelling was thus used to perform sensitivity analyses of as many system variables as program resources and schedules would permit. In any systems analysis, it is imperative that the evaluation methodology be verifiable and comparable. The TAG Class I develops comparable (if imprecise) data on performance and costs for the alternative cases being studied. It identifies, from a range of options, those which merit more exacting scrutiny to be undertaken at the second level, TAG class II analysis.

  18. Development of dry storage technology of spent nuclear fuel

    Energy Technology Data Exchange (ETDEWEB)

    Maruoka, Kunio [Mitsubishi Heavy Industries Ltd., Yokohama (Japan). Nuclear Energy Systems Engineering Center; Murakami, Kazuo; Yokoyama, Takeshi; Natsume, Tomohiro; Irino, Mitsuhiro

    1998-07-01

    The increasing demand for storage of spent fuel assemblies generated by commercial nuclear power plants is the urgent subject to solve. The dry storage system is as economically more advantageous than the pool storage system, and so, Mitsubishi Heavy Industries, Ltd. has developed the metal storage cask suited to small and medium storage capacity under 2000MTU - 3000MTU. For large scale capacity, the new `Mitsubishi Vault Storage System` has been developed, and it provides a safe and economical solution. Technical study concerning cooling ability was performed. (author)

  19. Recent Progress in the Development of Diesel Surrogate Fuels

    Energy Technology Data Exchange (ETDEWEB)

    Pitz, W J

    2009-09-04

    There has been much recent progress in the area of surrogate fuels for diesel. In the last few years, experiments and modeling have been performed on higher molecular weight components of relevance to diesel fuel such as n-hexadecane (n-cetane) and 2,2,4,4,6,8,8-heptamethylnonane (iso-cetane). Chemical kinetic models have been developed for all the n-alkanes up to 16 carbon atoms. Also, there has been much experimental and modeling work on lower molecular weight surrogate components such as n-decane and do-decane which are most relevant to jet fuel surrogates, but are also relevant to diesel surrogates where simulation of the full boiling point range is desired. For the cycloalkanes, experimental work on decalin and tetralin recently has been published. For multi-component surrogate fuel mixtures, recent work on modeling of these mixtures and comparisons to real diesel fuel is reviewed. Detailed chemical kinetic models for surrogate fuels are very large in size. Significant progress also has been made in improving the mechanism reduction tools that are needed to make these large models practicable in multidimensional reacting flow simulations of diesel combustion. Nevertheless, major research gaps remain. In the case of iso-alkanes, there are experiments and modeling work on only one of relevance to diesel: iso-cetane. Also, the iso-alkanes in diesel are lightly branched and no detailed chemical kinetic models or experimental investigations are available for such compounds. More components are needed to fill out the iso-alkane boiling point range. For the aromatic class of compounds, there has been no new work for compounds in the boiling point range of diesel. Most of the new work has been on alkyl aromatics that are of the range C7 to C8, below the C10 to C20 range that is needed. For the chemical class of cycloalkanes, experiments and modeling on higher molecular weight components are warranted. Finally for multi-component surrogates needed to treat real diesel

  20. Recent Progress in the Development of Diesel Surrogate Fuels

    Energy Technology Data Exchange (ETDEWEB)

    Pitz, W J; Mueller, C J

    2009-12-09

    There has been much recent progress in the area of surrogate fuels for diesel. In the last few years, experiments and modeling have been performed on higher molecular weight components of relevance to diesel fuel such as n-hexadecane (n-cetane) and 2,2,4,4,6,8,8-heptamethylnonane (iso-cetane). Chemical kinetic models have been developed for all the n-alkanes up to 16 carbon atoms. Also, there has been much experimental and modeling work on lower molecular weight surrogate components such as n-decane and n-dodecane that are most relevant to jet fuel surrogates, but are also relevant to diesel surrogates where simulation of the full boiling point range is desired. For two-ring compounds, experimental work on decalin and tetralin recently has been published. For multi-component surrogate fuel mixtures, recent work on modeling of these mixtures and comparisons to real diesel fuel is reviewed. Detailed chemical kinetic models for surrogate fuels are very large in size. Significant progress also has been made in improving the mechanism reduction tools that are needed to make these large models practicable in multi-dimensional reacting flow simulations of diesel combustion. Nevertheless, major research gaps remain. In the case of iso-alkanes, there are experiments and modeling work on only one of relevance to diesel: iso-cetane. Also, the iso-alkanes in diesel are lightly branched and no detailed chemical kinetic models or experimental investigations are available for such compounds. More components are needed to fill out the iso-alkane boiling point range. For the aromatic class of compounds, there has been no new work for compounds in the boiling point range of diesel. Most of the new work has been on alkyl aromatics that are of the range C7 to C8, below the C10 to C20 range that is needed. For the chemical class of cycloalkanes, experiments and modeling on higher molecular weight components are warranted. Finally for multi-component surrogates needed to treat real

  1. Progress and prospects of nuclear fuel development in Japan, (2). Progress and future plan of research and development on PWR fuel in Japan

    Energy Technology Data Exchange (ETDEWEB)

    Kondo, Yoshiaki; Abeta, Sadaaki; Aisu, Hideo; Teranishi, Tomoyuki

    1982-06-01

    13 years have elapsed since the first PWR plant started the operation in Japan, and at present, 11 PWR plants are in operation. During this period, much results of use and experience have been accumulated for the PWR fuel. The improvement and development of the fuel have been performed to meet the supply of the fuel sufficiently adaptable to the severe environment in Japan. In this paper, the evaluation of soundness and the improvement of reliability of PWR fuel made so far are reported, and the response of fuel side to long cycle operation and load following-up operation, which will be required in near future, is explained. The inspection of fuel has been performed at reactor sites for the purpose of sufficiently observing the irradiation behavior of fuel and detecting the points out of order. Effort has been exerted to perform various inspections thoroughly on total number of fuel and reflect the results to the improved design. Fuel leak scarcely occurred from the beginning, accordingly, improvement has been made to reduce the bending of fuel rods. The change of PWR fuel design, the evaluation of soundness and the improvement of reliability of PWR fuel, and the improvement for the future are reported.

  2. Development of Ni-Ba(Zr,Y)O3 cermet anodes for direct ammonia-fueled solid oxide fuel cells

    Science.gov (United States)

    Miyazaki, Kazunari; Okanishi, Takeou; Muroyama, Hiroki; Matsui, Toshiaki; Eguchi, Koichi

    2017-10-01

    In this study, the availability of Ni-Ba(Zr,Y)O3-δ (BZY) cermet for the anode of direct ammonia-fueled solid oxide fuel cells (SOFCs) is evaluated. In this device, the anodes need to be active for the catalytic ammonia decomposition as well as the electrochemical hydrogen oxidation. In the catalytic activity test, ammonia decomposes completely over Ni-BZY at ca. 600 °C, while higher temperature is required to accomplish the complete decomposition over the conventional SOFC anode of Ni-yttria-stabilized zirconia cermet. The high activity of Ni-BZY is attributed to the high basicity of BZY and the high resistance to hydrogen poisoning effect. The electrochemical property of Ni-BZY anode is also evaluated with the anode-supported cell of Ni-BZY|BZY|Pt at 600-700 °C with feeding ammonia or hydrogen as a fuel. Since the residence time of ammonia fuel in the thick Ni-BZY anode is long, the difference in the cell performance between two fuels is relatively small. Furthermore, it is proved that the steam concentration in the fuel strongly affects the cell performance. We find that this factor is important to satisfy the above mentioned requirements for the anode of direct ammonia-fueled SOFCs. Throughout this study, it is concluded that Ni-BZY cermet will be a promising anode.

  3. International symposium on fuel rod simulators: development and application

    Energy Technology Data Exchange (ETDEWEB)

    McCulloch, R.W. (comp.)

    1981-05-01

    Separate abstracts are included for each of the papers presented concerning fuel rod simulator operation and performance; simulator design and evaluation; clad heated fuel rod simulators and fuel rod simulators for cladding investigations; fuel rod simulator components and inspection; and simulator analytical modeling. Ten papers have previously been input to the Energy Data Base.

  4. Coal-fueled diesel technology development Emissions Control

    Energy Technology Data Exchange (ETDEWEB)

    Van Kleunen, W.; Kaldor, S.; Gal, E.; Mengel, M.; Arnold, M.

    1994-01-01

    GEESI Emissions Control program activity ranged from control concept testing of 10 CFM slipstream from a CWS fuel single cylinder research diesel engine to the design, installation, and operation of a full-size Emissions Control system for a full-size CWS fuel diesel engine designed for locomotive operation.Early 10 CFM slipstream testing program activity was performed to determine Emissions Characteristics and to evaluate Emissions Control concepts such a Barrier filtration, Granular bed filtration, and Cyclone particulate collection for reduction of particulate and gaseous emissions. Use of sorbent injection into the engine exhaust gas upstream of the barrier filter or use of sorbent media in the granular bed filter were found to provide reduction of exhaust gas SO{sub 2} and NO{sub x} in addition to collection of ash particulate. Emergence of the use of barrier filtration as a most practical Emissions Control concept disclosed a need to improve cleanability of the filter media in order to avoid reduction of turbocharger performance by excessive barrier filter pressure drop. The next progression of program activity, after the slipstream feasibility state, was 500 CFM cold flow testing of control system concepts. The successful completion of 500 CFM cold flow testing of the Envelope Filter led to a subsequent progression to a similar configuration Envelope Filter designed to operate at 500 CFM hot gas flow from the CWS fuel research diesel engine in the GETS engine test laboratory. This Envelope Filter included the design aspect proven by cold flow testing as well as optimization of the selection of the installed filter media.

  5. Fuel cells: State of the Art and Future Developments

    Energy Technology Data Exchange (ETDEWEB)

    Apfel, H.; Cremers, C.; Stimming, U. [Technische Univ. Muenchen (Germany). Physik-Department E19

    2004-07-01

    Providing electricity and heats is one key issue of our civilization today and in the future. Conserving non-renewable resources and reducing emissions become more and more important in the development of energy converters. Fuel cells are one possibility. They convert energy with high efficiency and extremely low mission of pollutants. In this paper construction and operation of fuel cells are explained briefly. Applications for high (SOFC) and low (PEM) temperature fuel cells are shown by means of several existing prototypes. The main issues inhibiting higher power densities are discussed and a possible solution by an structure of the catalysis is presented. (orig.) [German] Die Bereitstellung von Elektrizitaet und Waerme ist und bleibt eine wesentliche technologische Aufgabe der zivilisatorischen Gesellschaft. Resourcenschonung und Minimierung der Schadstoffemissionen gewinnen zunehmend an Bedeutung. Brennstoffzellen sind Energiewandler, die mit hoher Effizienz bei extrem geringen Schadstoffemissionen arbeiten. Aufbau und Funktionsweise von Brennstoffzellen werden kurz vorgestellt. Es werden Anwendungsbeispiele fuer Hochtemperatur-Brennstoffzellen (z. B. SOFC) fuer die stationaere Erzeugung von Elektrizitaet und Waerme aus Erdgas und fuer Niedertemperatur-Brennstoffzellen (z. B. PEMFC) mit fluessigen Energietraegern im Fahrzeugbereich gegeben. Fuer die Entwicklung geeigneter Brennstoffzellensysteme muss die Peripherie, insbesondere die Gasaufbereitung, so gestaltet werden, dass der hohe elektrische Wirkungsgrad und die Schadstoffarmut erhalten bleiben. Die mikroskopischen Prozesse in Brennstoffzellen werden beleuchtet, und es wird, anhand einer potentiell deutlich verbesserten Katalysatorstruktur, ein moeglicher Weg zur Ueberwindung momentaner Schwierigkeiten bei der Entwicklung von Brennstoffzellen diskutiert. (orig.)

  6. Development of the fabrication technology of the simulated DUPIC fuel

    Energy Technology Data Exchange (ETDEWEB)

    Kang, Kweon Ho; Yang, M. S.; Bae, K. K. and others

    2000-06-01

    It is important to get basic data to analysis physical properties, behavior in reactor and performance of the DUPIC fuel because physical properties of the DUPIC fuel is different from the commercial UO{sub 2} fuel. But what directly measures physical properties et al. of DUPIC fuel being resinterred simulated spent fuel through OREOX process is very difficult in laboratory owing to its high level radiation. Then fabrication of simulated DUPIC fuel is needed to measure its properties. In this study, processes on powder treatment, OREOX, compaction and sintering to fabricate simulated DUPIC fuel using simulated spent fuel are discribed. To fabricate simulated DUPIC fuel, the powder from 3 times OREOX and 5 times attrition milling simulated spent fuel is compacted with 1.3 ton/cm{sup 2}. Pellets are sintered in 100% H{sub 2} atmosphere over 10 h at 1800 deg C. Sintered densities of pellets are 10.2-10.5 g/cm{sup 3}.

  7. Solid oxide fuel cell systems development. Final report

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2012-12-15

    The main objective in this project has been to develop a generic and dynamic tool for SOFC systems simulation and development. Developing integrated fuel cell systems is very expensive and therefore having the right tools to reduce the development cost and time to market for products becomes an important feature. The tools developed in this project cover a wide range of needs in Dantherm Power, R and D, and can be divided into 3 categories: 1. Component selection modeling; to define component specification requirements and selection of suppliers. 2. Application simulation model built from scratch, which can simulate the interface between customer demand and system output and show operation behavior for different control settings. 3. System operation strategy optimization with respect to operation cost and customer benefits. a. Allows to see how system size, in terms of electricity and heat output, and operation strategy influences a specific business case. b. Gives a clear overview of how a different property, in the system, affects the economics (e.g. lifetime, electrical and thermal efficiency, fuel cost sensitivity, country of deployment etc.). The main idea behind the structure of the tool being separated into 3 layers is to be able to service different requirements, from changing stakeholders. One of the major findings in this project has been related to thermal integration between the existing installation in a private household and the fuel cell system. For a normal family requiring 4500 kWh of electricity a year, along with the possibility of only running the system during the heating season (winter), the heat storage demand is only 210kWh of heat with an approximate value of Dkr 160,- in extra gas consumption. In this case, it would be much more cost effective to dump the heat, in the house, and save the expense of adding heat storage to the system. This operation strategy is only valid in Denmark for the time being, since the feed-In-Tariff allows for a

  8. Solid Oxide Fuel Cell (SOFC) Development in Denmark

    DEFF Research Database (Denmark)

    Linderoth, Søren; Larsen, Peter Halvor; Mogensen, Mogens Bjerg;

    2007-01-01

    to develop the SOFC technology all the way to a marketable product. Stack and system modelling including cost optimisation analysis is used to develop multi kW stack modules for operation in the temperature range 700-850oC. To ensure the emergence of cost-competitive solutions, a special effort is focused......The SOFC technology under development at Risø National Laboratory (RISØ) and Topsoe Fuel Cell A/S (TOFC) is based on an integrated approach ranging from basic materials research on single component level over development of cell and stack manufacturing technology to system studies and modelling...... on larger anode-supported cells as well as a new generation of SOFCs based on porous metal supports and new electrode and electrolyte materials. The SOFC program comprises development of next generation of cells and multi stack modules for operation at lower temperature with increased durability...

  9. Development of a Direct Carbon Fuel Cell for Power and Fuels Cogeneration Directly from Plastic Trash Project

    Data.gov (United States)

    National Aeronautics and Space Administration — This small business innovation research is intended to develop a simple processing concept based-on an advanced direct carbon fuel cell (DCFC) technology enabling...

  10. Clean-Burning Fuel for Use in Woodstoves: Feminist Politics, Community Development and Global Sustainability.

    Science.gov (United States)

    Grace, Victoria; Arnoux, Louis

    1998-01-01

    Rural women in less-developed nations use fuels that can be toxic and are becoming scarce. Feminist, sociological, and community-development issues were involved in the process of introducing clear-burning fuel, enabling a focus on both the effects on the health of fuel users and concern for ecological sustainability. (SK)

  11. Advanced LWR Nuclear Fuel Cladding System Development Trade-Off Study

    Energy Technology Data Exchange (ETDEWEB)

    Kristine Barrett; Shannon Bragg-Sitton

    2012-09-01

    The Advanced Light Water Reactor (LWR) Nuclear Fuel Development Research and Development (R&D) Pathway encompasses strategic research focused on improving reactor core economics and safety margins through the development of an advanced fuel cladding system. To achieve significant operating improvements while remaining within safety boundaries, significant steps beyond incremental improvements in the current generation of nuclear fuel are required. Fundamental improvements are required in the areas of nuclear fuel composition, cladding integrity, and the fuel/cladding interaction to allow power uprates and increased fuel burn-up allowance while potentially improving safety margin through the adoption of an “accident tolerant” fuel system that would offer improved coping time under accident scenarios. With a development time of about 20 – 25 years, advanced fuel designs must be started today and proven in current reactors if future reactor designs are to be able to use them with confidence.

  12. Simulated coal-gas-fueled molten carbonate fuel cell development program

    Energy Technology Data Exchange (ETDEWEB)

    Johnson, W.H.

    1992-07-01

    In previous work, International Fuel Cells Corporation (EFC) found interactions between molten carbonate fuel cell cathode materials being considered as replacements for the presently used nickel oxide and matrix materials. Consequently, this work was conducted to screen additional new materials for mutual compatibility. As part of this program, experiments were performed to examine the compatibility of several candidate, alternative cathode materials with the standard lithium aluminate matrix material in the presence of electrolyte at cell potentials. Initial cathode candidates were materials lithium ferrite, yttrium iron garnet, lithium manganite and doped ceria which were developed by universities, national laboratories, or contractors to DOE, EPRI, or GRI. These investigations were conducted in laboratory scale experiments. None of the materials tested can directly replace nickel oxide or indicate greater stability of cell performance than afforded by nickel oxide. Specifically: (1) no further work on niobium doped ceria is warranted; (2) cobalt migration was found in the lithium ferrite cathode tested. This could possibly lead to shorting problems similiar to those encountered with nickel oxide; (3) Possible shorting problems may also exist with the proprietary dopant in YIG; (4) lithium ferrite and YIG cathode were not single phase materials. Assessment of the chemical stability, i.e., dopant loss, was severely impeded by dissolution of these second phases in the electrolyte; and (5) Magnesium doped lithium manganite warrants further work. Electrolytes should contain Mg ions to suppress dopant loss.

  13. Simulated coal-gas-fueled molten carbonate fuel cell development program. Topical report: Cathode compatibility tests

    Energy Technology Data Exchange (ETDEWEB)

    Johnson, W.H.

    1992-07-01

    In previous work, International Fuel Cells Corporation (EFC) found interactions between molten carbonate fuel cell cathode materials being considered as replacements for the presently used nickel oxide and matrix materials. Consequently, this work was conducted to screen additional new materials for mutual compatibility. As part of this program, experiments were performed to examine the compatibility of several candidate, alternative cathode materials with the standard lithium aluminate matrix material in the presence of electrolyte at cell potentials. Initial cathode candidates were materials lithium ferrite, yttrium iron garnet, lithium manganite and doped ceria which were developed by universities, national laboratories, or contractors to DOE, EPRI, or GRI. These investigations were conducted in laboratory scale experiments. None of the materials tested can directly replace nickel oxide or indicate greater stability of cell performance than afforded by nickel oxide. Specifically: (1) no further work on niobium doped ceria is warranted; (2) cobalt migration was found in the lithium ferrite cathode tested. This could possibly lead to shorting problems similiar to those encountered with nickel oxide; (3) Possible shorting problems may also exist with the proprietary dopant in YIG; (4) lithium ferrite and YIG cathode were not single phase materials. Assessment of the chemical stability, i.e., dopant loss, was severely impeded by dissolution of these second phases in the electrolyte; and (5) Magnesium doped lithium manganite warrants further work. Electrolytes should contain Mg ions to suppress dopant loss.

  14. Development of a miniature silicon wafer fuel cell using L-ascorbic acid as fuel

    Institute of Scientific and Technical Information of China (English)

    Jian WO; Zhi-yong XIAO; Yi-bin YING; Philip C.H. CHAN

    2008-01-01

    In the current studies a miniature silicon wafer fuel cell (FC) using L-ascorbic acid as fuel was developed, The cell employs L-ascorbic acid and air as reactants and a thin polymer electrolyte as a separator. Inductively coupled plasma (ICP) silicon etching was employed to fabricate high aspect-ratio columns on the silicon substrate to increase the surface area. A thin platinum layer deposited directly on the silicon surface by the sputtering was used as the catalyst layer for L-ascorbic acid electro-oxidation.Cyclic voltammetry shows that the oxidation of L-ascorbic acid on the sputtered platinum layer is irreversible and that the onset potentials for the oxidation of L-ascorbic acid are from 0.27 V to 0.35 V versus an Ag/AgCI reference electrode. It is found that at the room temperature, with 1 mol/L L-ascorbic acid/PBS (phosphate buffered solution) solution pumped to the anode at 1 ml/min flow rate and air spontaneously diffusing to the cathode as the oxidant, the maximum output power density of the cell was 1.95m W/cm2 at a current density of 10 mA/cm2.

  15. Measuring water activity of aviation fuel using a polymer optical fiber Bragg grating

    Science.gov (United States)

    Zhang, Wei; Webb, David J.; Carpenter, Mark; Williams, Colleen

    2014-05-01

    Poly(methyl methacrylate) (PMMA) based polymer optical fiber Bragg gratings have been used for measuring water activity of aviation fuel. Jet A-1 samples with water content ranging from 100% ERH (wet fuel) to 10 ppm (dried fuel), have been conditioned and calibrated for measurement. The PMMA based optical fiber grating exhibits consistent response and a good sensitivity of 59±3pm/ppm (water content in mass). This water activity measurement allows PMMA based optical fiber gratings to detect very tiny amounts of water in fuels that have a low water saturation point, potentially giving early warning of unsafe operation of a fuel system.

  16. A review on the development of the advanced fuel fabrication technology

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Jung Won; Lee, Yung Woo; Sohn, Dong Sung; Yang, Myung Seung; Bae, Kee Kwang; Nah, Sang Hoh; Kim, Han Soo; Kim, Bong Koo; Song, Keun Woo; Kim, See Hyung [Korea Atomic Energy Research Institute, Taejon (Korea, Republic of)

    1995-07-01

    In this state-of art report, the development status of the advanced nuclear fuel was investigated. The current fabrication technology for coated particle fuel and non-oxide fuel such as sol-gel technology, coating technology, and carbothermic reduction reaction has also been examined. In the view point of inherent safety and efficiency in the operation of power plant, the coated particle fuel will keep going on its reputation as nuclear fuel for a high temperature gas cooled reactor, and the nitride fuel is very prospective for the next liquid metal fast breeder reactor. 43 figs., 17 tabs., 96 refs. (Author).

  17. Fueling dreams of grandeur: Fuel cell research and development and the pursuit of the technological panacea, 1940--2005

    Science.gov (United States)

    Eisler, Matthew Nicholas

    The record of fuel cell research and development is one of the great enigmas in the history of science and technology. For years, this electrochemical power source, which combines hydrogen and oxygen to produce electricity and waste water, excited the imaginations of researchers in many countries. Because fuel cells directly convert chemical into electrical energy, people have long believed them exempt from the so-called Carnot cycle limitation on heat engines, which dictates that such devices must operate at less than 100 per cent efficiency owing to the randomization of energy as heat. Fuel cells have thus struck some scientists and engineers as the "magic bullet" of energy technologies. This dissertation explores why people have not been able to develop a cheap, durable commercial fuel cell despite more than 50 years of concerted effort since the end of Second World War. I argue this is so mainly because expectations have always been higher than the knowledge base. I investigate fuel cell research and development communities as central nodes of expectation generation. They have functioned as a nexus where the physical realities of fuel cell technology meet external factors, those political, economic and cultural pressures that create a "need" for a "miracle" power source. The unique economic exigencies of these communities have shaped distinct material practices that have done much to inform popular ideas of the capabilities of fuel cell technology. After the Second World War, the fuel cell was relatively unknown in industrial and governmental science and technology circles. Researchers in most leading industrialized countries, above all the United States, sought to raise the technology's profile through dramatic demonstrations in reductive circumstances, employing notional fuel cells using pure hydrogen and oxygen. Researchers paid less attention to cost and durability, concentrating on increasing power output, a criterion that could be met relatively easily in

  18. A fuel cell energy storage system for Space Station extravehicular activity

    Science.gov (United States)

    Rosso, Matthew J., Jr.; Adlhart, Otto J.; Marmolejo, Jose A.

    1988-01-01

    The development of a fuel cell energy storage system for the Space Station Extravehicular Mobility Unit (EMU) is discussed. The ion-exchange membrane fuel cell uses hydrogen stored as a metal hydride. Several features of the hydrogen-oxygen fuel cell are examined, including its construction, hydrogen storage, hydride recharge, water heat, water removal, and operational parameters.

  19. Development of solid oxide fuel cells; Desenvolvimento de celulas a combustivel do tipo oxido solido (SOFC)

    Energy Technology Data Exchange (ETDEWEB)

    Boaventura, Jaime S.; Alencar, Marcelo Goncalves F. de; Amaral, Alexandre Alves do; Benedicto, Joao Paulo Santos; Silva, Marcos A. [Universidade Federal da Bahia (UFBA), Salvador, BA (Brazil). Inst. de Quimica. Dept. de Fisico-Quimica

    2006-07-01

    Fuel cells allow the energy production without the thermodynamic restriction of the conversion of heat into work. Among their various types, the solid oxide fuel cells (SOFC), operating at high temperatures, allow the methane conversion into electricity directly on the anode. The main element of the SOFC is the structure A/E/C: anode/electrolyte/cathode, all sintered at high temperature as resistant ceramic materials. Dense electrolyte (YSZ: zirconia stabilized for Yttria) separates the anode (Ni+Co/YSZ: cobalt promoted nickel, supported on YSZ) and cathode (LSM: strontium-doped lanthanum manganite), both with porosity obtained by graphite addition. To obtain suitable A/E/C pellets, the layer sintering with appropriate mechanical and textural characteristics is essential, requiring excellent electric junctions between them. The cell performance has been evaluated between 850 and 950 degree C, using hydrogen or methane fuel; the tension and current for different resistance values in the electrical circuit have been measured. The cobalt addition to the cell anode significantly increased its activity for the reform reaction. The beneficial effect was probably due to the easier nickel reduction in cobalt presence. This work had the objectives of developing and evaluating electro-catalysts, as well as the solid oxide fuel cells using these catalysts as anode. Five SOFC models (SOFC 1 to SOFC 5) are described; all of them were developed aiming at improving the preparation of the anode/electrolyte/cathode structure (A/E/C). (author)

  20. Application of Butler-Volmer equations in the modelling of activation polarization for PEM fuel cells

    Science.gov (United States)

    Mann, R. F.; Amphlett, J. C.; Peppley, B. A.; Thurgood, C. P.

    Proton exchange membrane (PEM) fuel cells have been under development for many years and appear to be the potential solution for many electricity supply applications. Modelling and computer simulation of PEM fuel cells have been equally active areas of work as a means of developing better understanding of cell and stack operation, facilitating design improvements and supporting system simulation studies. In general, fuel cell models must be capable of predicting values of the activation polarization at both the anode and the cathode. Since the magnitude of an activation polarization for a particular electrode depends on the inverse of the chemical (or electrochemical) reaction rate at that electrode, reaction rate expressions are normally required for each electrode. The reaction rate is commonly expressed as an 'exchange current density', typical symbol i 0, and mechanistic expressions to predict i 0 are, therefore, components of an ideal model. Most expressions for i 0 are based on the Butler-Volmer (B-V) equation or on more approximate equations derived from the B-V equation. Many publications use one of these B-V equations without a critical determination of the applicability or accuracy of the particular equation being used. The present paper examines these questions and makes some recommendations regarding the applicability of each equation in the 'B-V family of equations'. In addition, terminology and symbols have been modified, where possible, to make modelling based on B-V equations more easily understood and applied by those without an extensive background in electrochemistry.

  1. The DOE Advanced Gas Reactor (AGR) Fuel Development and Qualification Program

    Energy Technology Data Exchange (ETDEWEB)

    David Petti; Hans Gougar; Gary Bell

    2005-05-01

    The Department of Energy has established the Advanced Gas Reactor Fuel Development and Qualification Program to address the following overall goals: Provide a baseline fuel qualification data set in support of the licensing and operation of the Next Generation Nuclear Plant (NGNP). Gas-reactor fuel performance demonstration and qualification comprise the longest duration research and development (R&D) task for the NGNP feasibility. The baseline fuel form is to be demonstrated and qualified for a peak fuel centerline temperature of 1250°C. Support near-term deployment of an NGNP by reducing market entry risks posed by technical uncertainties associated with fuel production and qualification. Utilize international collaboration mechanisms to extend the value of DOE resources. The Advanced Gas Reactor Fuel Development and Qualification Program consists of five elements: fuel manufacture, fuel and materials irradiations, postirradiation examination (PIE) and safety testing, fuel performance modeling, and fission product transport and source term evaluation. An underlying theme for the fuel development work is the need to develop a more complete fundamental understanding of the relationship between the fuel fabrication process, key fuel properties, the irradiation performance of the fuel, and the release and transport of fission products in the NGNP primary coolant system. Fuel performance modeling and analysis of the fission product behavior in the primary circuit are important aspects of this work. The performance models are considered essential for several reasons, including guidance for the plant designer in establishing the core design and operating limits, and demonstration to the licensing authority that the applicant has a thorough understanding of the in-service behavior of the fuel system. The fission product behavior task will also provide primary source term data needed for licensing. An overview of the program and recent progress will be presented.

  2. The DOE Advanced Gas Reactor (AGR) Fuel Development and Qualification Program

    Energy Technology Data Exchange (ETDEWEB)

    David Petti; Hans Gougar; Gary Bell

    2005-05-01

    The Department of Energy has established the Advanced Gas Reactor Fuel Development and Qualification Program to address the following overall goals: Provide a baseline fuel qualification data set in support of the licensing and operation of the Next Generation Nuclear Plant (NGNP). Gas-reactor fuel performance demonstration and qualification comprise the longest duration research and development (R&D) task for the NGNP feasibility. The baseline fuel form is to be demonstrated and qualified for a peak fuel centerline temperature of 1250°C. Support near-term deployment of an NGNP by reducing market entry risks posed by technical uncertainties associated with fuel production and qualification. Utilize international collaboration mechanisms to extend the value of DOE resources. The Advanced Gas Reactor Fuel Development and Qualification Program consists of five elements: fuel manufacture, fuel and materials irradiations, postirradiation examination (PIE) and safety testing, fuel performance modeling, and fission product transport and source term evaluation. An underlying theme for the fuel development work is the need to develop a more complete fundamental understanding of the relationship between the fuel fabrication process, key fuel properties, the irradiation performance of the fuel, and the release and transport of fission products in the NGNP primary coolant system. Fuel performance modeling and analysis of the fission product behavior in the primary circuit are important aspects of this work. The performance models are considered essential for several reasons, including guidance for the plant designer in establishing the core design and operating limits, and demonstration to the licensing authority that the applicant has a thorough understanding of the in-service behavior of the fuel system. The fission product behavior task will also provide primary source term data needed for licensing. An overview of the program and recent progress will be presented.

  3. Development of an Integrated Performance Model for TRISO-Coated Gas Reactor Particle Fuel

    Energy Technology Data Exchange (ETDEWEB)

    Petti, David Andrew; Miller, Gregory Kent; Martin, David George; Maki, John Thomas

    2005-05-01

    The success of gas reactors depends upon the safety and quality of the coated particle fuel. The understanding and evaluation of this fuel requires development of an integrated mechanistic fuel performance model that fully describes the mechanical and physico-chemical behavior of the fuel particle under irradiation. Such a model, called PARFUME (PARticle Fuel ModEl), is being developed at the Idaho National Engineering and Environmental Laboratory. PARFUME is based on multi-dimensional finite element modeling of TRISO-coated gas reactor fuel. The goal is to represent all potential failure mechanisms and to incorporate the statistical nature of the fuel. The model is currently focused on carbide, oxide nd oxycarbide uranium fuel kernels, while the coating layers are the classical IPyC/SiC/OPyC. This paper reviews the current status of the mechanical aspects of the model and presents results of calculations for irradiations from the New Production Modular High Temperature Gas Reactor program.

  4. 76 FR 78290 - Cooperative Research and Development Agreement: Usage of Biodiesel Fuel Blends Within Marine...

    Science.gov (United States)

    2011-12-16

    ... SECURITY Coast Guard Cooperative Research and Development Agreement: Usage of Biodiesel Fuel Blends Within... technology enhancements, performance, costs, and other issues associated with using biodiesel fuel blends in... notice (investigating the use of biodiesel fuel blends in marine inboard engines) must reach the...

  5. Performance of fire behavior fuel models developed for the Rothermel Surface Fire Spread Model

    Science.gov (United States)

    Robert Ziel; W. Matt Jolly

    2009-01-01

    In 2005, 40 new fire behavior fuel models were published for use with the Rothermel Surface Fire Spread Model. These new models are intended to augment the original 13 developed in 1972 and 1976. As a compiled set of quantitative fuel descriptions that serve as input to the Rothermel model, the selected fire behavior fuel model has always been critical to the resulting...

  6. Fuel Cycle Research and Development Accident Tolerant Fuels Series 1 (ATF-1) Irradiation Testing FY 2016 Status Report

    Energy Technology Data Exchange (ETDEWEB)

    Core, Gregory Matthew [Idaho National Lab. (INL), Idaho Falls, ID (United States)

    2016-09-01

    This report contains a summary of irradiation testing of Fuel Cycle Research and Development (FCRD) Accident Tolerant Fuels Series 1 (ATF 1) experiments performed at Idaho National Laboratory (INL) in FY 2016. ATF 1 irradiation testing work performed in FY 2016 included design, analysis, and fabrication of ATF-1B drop in capsule ATF 1 series experiments and irradiation testing of ATF-1 capsules in the ATR.

  7. Development of the CANDU high-burnup fuel design/analysis technology

    Energy Technology Data Exchange (ETDEWEB)

    Suk, Ho Chun; Sim, K. S.; Oh, D. J.; Park, J. H.; Jun, J. S.; Yoo, K. J.

    1997-08-01

    This report contains all the information related to the development of the CANDU advanced fuel, so-called CANFLEX-NU, which is composed of 43 elements with natural uranium fuel. Also, it contains the compatibility study of CANFLEX-RU which is considered as a CANDU high burnup fuel. This report describes the mechanical design, thermalhydraulic and safety evaluations of CANFLEX fuel bundle. (author). 38 refs., 24 tabs., 74 figs.

  8. Science based integrated approach to advanced nuclear fuel development - vision, approach, and overview

    Energy Technology Data Exchange (ETDEWEB)

    Unal, Cetin [Los Alamos National Laboratory; Pasamehmetoglu, Kemal [IDAHO NATIONAL LAB; Carmack, Jon [IDAHO NATIONAL LAB

    2010-01-01

    Advancing the performance of Light Water Reactors, Advanced Nuclear Fuel Cycles, and Advanced Rcactors, such as the Next Generation Nuclear Power Plants, requires enhancing our fundamental understanding of fuel and materials behavior under irradiation. The capability to accurately model the nuclear fuel systems is critical. In order to understand specific aspects of the nuclear fuel, fully coupled fuel simulation codes are required to achieve licensing of specific nuclear fuel designs for operation. The backbone of these codes, models, and simulations is a fundamental understanding and predictive capability for simulating the phase and microstructural behavior of the nuclear fuel system materials and matrices. The purpose of this paper is to identify the modeling and simulation approach in order to deliver predictive tools for advanced fuels development. The coordination between experimental nuclear fuel design, development technical experts, and computational fuel modeling and simulation technical experts is a critical aspect of the approach and naturally leads to an integrated, goal-oriented science-based R & D approach and strengthens both the experimental and computational efforts. The Advanced Fuels Campaign (AFC) and Nuclear Energy Advanced Modeling and Simulation (NEAMS) Fuels Integrated Performance and Safety Code (IPSC) are working together to determine experimental data and modeling needs. The primary objective of the NEAMS fuels IPSC project is to deliver a coupled, three-dimensional, predictive computational platform for modeling the fabrication and both normal and abnormal operation of nuclear fuel pins and assemblies, applicable to both existing and future reactor fuel designs. The science based program is pursuing the development of an integrated multi-scale and multi-physics modeling and simulation platform for nuclear fuels. This overview paper discusses the vision, goals and approaches how to develop and implement the new approach.

  9. Science based integrated approach to advanced nuclear fuel development - vision, approach, and overview

    Energy Technology Data Exchange (ETDEWEB)

    Unal, Cetin [Los Alamos National Laboratory; Pasamehmetoglu, Kemal [IDAHO NATIONAL LAB; Carmack, Jon [IDAHO NATIONAL LAB

    2010-01-01

    Advancing the performance of Light Water Reactors, Advanced Nuclear Fuel Cycles, and Advanced Rcactors, such as the Next Generation Nuclear Power Plants, requires enhancing our fundamental understanding of fuel and materials behavior under irradiation. The capability to accurately model the nuclear fuel systems is critical. In order to understand specific aspects of the nuclear fuel, fully coupled fuel simulation codes are required to achieve licensing of specific nuclear fuel designs for operation. The backbone of these codes, models, and simulations is a fundamental understanding and predictive capability for simulating the phase and microstructural behavior of the nuclear fuel system materials and matrices. The purpose of this paper is to identify the modeling and simulation approach in order to deliver predictive tools for advanced fuels development. The coordination between experimental nuclear fuel design, development technical experts, and computational fuel modeling and simulation technical experts is a critical aspect of the approach and naturally leads to an integrated, goal-oriented science-based R & D approach and strengthens both the experimental and computational efforts. The Advanced Fuels Campaign (AFC) and Nuclear Energy Advanced Modeling and Simulation (NEAMS) Fuels Integrated Performance and Safety Code (IPSC) are working together to determine experimental data and modeling needs. The primary objective of the NEAMS fuels IPSC project is to deliver a coupled, three-dimensional, predictive computational platform for modeling the fabrication and both normal and abnormal operation of nuclear fuel pins and assemblies, applicable to both existing and future reactor fuel designs. The science based program is pursuing the development of an integrated multi-scale and multi-physics modeling and simulation platform for nuclear fuels. This overview paper discusses the vision, goals and approaches how to develop and implement the new approach.

  10. DEVELOPMENT OF OTM SYNGAS PROCESS AND TESTING OF SYNGAS-DERIVED ULTRA-CLEAN FUELS IN DIESEL ENGINES AND FUEL CELLS

    Energy Technology Data Exchange (ETDEWEB)

    E.T. (Skip) Robinson; James P. Meagher; Ravi Prasad

    2001-10-31

    This topical report summarizes work accomplished for the Program from January 1 through September 15, 2001 in the following task areas: Task 1--materials development; Task 2--composite element development; Task 3--tube fabrication; Task 4--reactor design and process optimization; Task 5--catalyst development; Task 6--P-1 operation; Task 8--fuels and engine testing; and Task 10--project management. OTM benchmark material, LCM1, exceeds the commercial oxygen flux target and was determined to be sufficiently robust to carry on process development activities. Work will continue on second-generation OTM materials that will satisfy commercial life targets. Three fabrication techniques for composite elements were determined to be technically feasible. These techniques will be studied and a lead manufacturing process for both small and large-scale elements will be selected in the next Budget Period. Experiments in six P-0 reactors, the long tube tester (LTT) and the P-1 pilot plant were conducted. Significant progress in process optimization was made through both the experimental program and modeling studies of alternate reactor designs and process configurations. Three tailored catalyst candidates for use in OTM process reactors were identified. Fuels for the International diesel engine and Nuvera fuel cell tests were ordered and delivered. Fuels testing and engine development work is now underway.

  11. Development of FHDS Type Catalyst for Deep Hydrodesulfurization of Diesel Fuel

    Institute of Scientific and Technical Information of China (English)

    Guo Rong; Yao Yunhai; Zhou Yong

    2005-01-01

    The FHDS type catalyst for deep hydrodesulfurization (HDS) of diesel fuel is a highactivity catalyst developed by FRIPP in order to meet the requirements of Chinese refiners for production of low-sulfur clean diesel fuel containing less than 300 ppm of sulfur. The FH-DS type catalyst has excellent HDS and HDN activity thanks to modification of alumina through incorporating additives, optimization of catalyst preparation and optimal combination of active ingredients.Under low pressure the HDS activity of this catalyst is by 50% higher than that of domestic reference catalysts available in the market and is slightly better than that of foreign reference catalyst. When this catalyst is used for manufacture of clean ultra-low sulfur diesel (containing <30 ppm of S), its volumetric relative desulfurization activity is 46% higher than that of foreign reference catalyst, and this catalyst is an excellent catalyst for manufacture of low-sulfur clean diesel fuel derived from imported high-sulfur Kuwaiti and Arabian crude oils.

  12. Green Engines Development Using Compressed Natural Gas as an Alternative Fuel: A Review

    Directory of Open Access Journals (Sweden)

    Semin

    2009-01-01

    Full Text Available Problem statement: The Compressed Natural Gas (CNG is a gaseous form of natural gas, it have been recognized as one of the promising alternative fuel due to its substantial benefits compared to gasoline and diesel. Natural gas is produced from gas wells or tied in with crude oil production. Approach: Natural gas is promising alternative fuel to meet strict engine emission regulations in many countries. Compressed Natural Gas (CNG has long been used in stationary engines, but the application of CNG as a transport engines fuel has been considerably advanced over the last decade by the development of lightweight high-pressure storage cylinders. Results: The technology of engine conversion was well established and suitable conversion equipment is readily available. For petrol engines or spark ignition engines there are two options, a bi-fuel conversion and use a dedicated to CNG engine. The diesel engines converted or designed to run on natural gas, there were two main options discussed. There are dual-fuel engines and normal ignition can be initiated. Natural gas engines can be operated at lean burn and stoichiometric conditions with different combustion and emission characteristics. Conclusions: In this study, the low exhaust gas emissions of CNG engines research and development were highlighted. Stoichiometric natural gas engines were briefly reviewed. To keep the output power, torque and emissions of natural gas engines comparable to their gasoline or diesel counterparts. High activity for future green CNG engines research and development to meet future stringent emissions standards was recorded in the study.

  13. Development of advanced mixed oxide fuels for plutonium management

    Energy Technology Data Exchange (ETDEWEB)

    Eaton, S.; Beard, C.; Buksa, J.; Butt, D.; Chidester, K.; Havrilla, G.; Ramsey, K.

    1997-06-01

    A number of advanced Mixed Oxide (MOX) fuel forms are currently being investigated at Los Alamos National Laboratory that have the potential to be effective plutonium management tools. Evolutionary Mixed Oxide (EMOX) fuel is a slight perturbation on standard MOX fuel, but achieves greater plutonium destruction rates by employing a fractional nonfertile component. A pure nonfertile fuel is also being studied. Initial calculations show that the fuel can be utilized in existing light water reactors and tailored to address different plutonium management goals (i.e., stabilization or reduction of plutonium inventories residing in spent nuclear fuel). In parallel, experiments are being performed to determine the feasibility of fabrication of such fuels. Initial EMOX pellets have successfully been fabricated using weapons-grade plutonium.

  14. Year One Summary of X-energy Pebble Fuel Development at ORNL

    Energy Technology Data Exchange (ETDEWEB)

    Helmreich, Grant W. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Hunn, John D. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); McMurray, Jake W. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Hunt, Rodney D. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Jolly, Brian C. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Trammell, Michael P. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Brown, Daniel R. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Blamer, Brandon J. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Reif, Tyler J. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Kim, Howard T. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

    2017-06-01

    The Advanced Reactor Concepts X-energy (ARC-Xe) Pebble Fuel Development project at Oak Ridge National Laboratory (ORNL) has successfully completed its first year, having made excellent progress in accomplishing programmatic objectives. The primary focus of research at ORNL in support of X-energy has been the training of X-energy fuel fabrication engineers and the establishment of US pebble fuel production capabilities able to supply the Xe-100 pebble-bed reactor. These efforts have been strongly supported by particle fuel fabrication and characterization expertise present at ORNL from the Advanced Gas Reactor (AGR) Fuel Development and Qualification Program.

  15. Combustion instability and active control: Alternative fuels, augmentors, and modeling heat release

    Science.gov (United States)

    Park, Sammy Ace

    Experimental and analytical studies were conducted to explore thermo-acoustic coupling during the onset of combustion instability in various air-breathing combustor configurations. These include a laboratory-scale 200-kW dump combustor and a 100-kW augmentor featuring a v-gutter flame holder. They were used to simulate main combustion chambers and afterburners in aero engines, respectively. The three primary themes of this work includes: 1) modeling heat release fluctuations for stability analysis, 2) conducting active combustion control with alternative fuels, and 3) demonstrating practical active control for augmentor instability suppression. The phenomenon of combustion instabilities remains an unsolved problem in propulsion engines, mainly because of the difficulty in predicting the fluctuating component of heat release without extensive testing. A hybrid model was developed to describe both the temporal and spatial variations in dynamic heat release, using a separation of variables approach that requires only a limited amount of experimental data. The use of sinusoidal basis functions further reduced the amount of data required. When the mean heat release behavior is known, the only experimental data needed for detailed stability analysis is one instantaneous picture of heat release at the peak pressure phase. This model was successfully tested in the dump combustor experiments, reproducing the correct sign of the overall Rayleigh index as well as the remarkably accurate spatial distribution pattern of fluctuating heat release. Active combustion control was explored for fuel-flexible combustor operation using twelve different jet fuels including bio-synthetic and Fischer-Tropsch types. Analysis done using an actuated spray combustion model revealed that the combustion response times of these fuels were similar. Combined with experimental spray characterizations, this suggested that controller performance should remain effective with various alternative fuels

  16. Water activities of polymeric membrane/water systems in fuel cells

    Energy Technology Data Exchange (ETDEWEB)

    Seong, Ji Yun; Bae, Young Chan [Division of Chemical Engineering and Molecular Thermodynamics Laboratory, Hanyang University, Seoul 133-791 (Korea, Republic of); Sun, Yang Kook [Division of Chemical Engineering and Center for Information and Communication Material, Hanyang University, Seoul 133-791 (Korea)

    2006-07-03

    A new equation of state (EOS) is established to describe water activities of polymeric membrane/water systems in fuel cell. It is developed based on the modified perturbed hard-sphere-chain (PHSC) EOS by introducing a new perturbation equation that is obtained from the generalized Lennard-Jones (GLJ) potential function based on a statistical-mechanical relationship. Experimentally observed water activities of polymeric electrolyte/water systems are interpreted by the proposed model. The values calculated from the proposed model are in a good agreement with the experimental data for given systems. (author)

  17. Development of a novel computational tool for optimizing the operation of fuel cells systems: Application for phosphoric acid fuel cells

    Science.gov (United States)

    Zervas, P. L.; Tatsis, A.; Sarimveis, H.; Markatos, N. C. G.

    Fuel cells offer a significant and promising clean technology for portable, automotive and stationary applications and, thus, optimization of their performance is of particular interest. In this study, a novel optimization tool is developed that realistically describes and optimizes the performance of fuel cell systems. First, a 3D steady-state detailed model is produced based on computational fluid dynamics (CFD) techniques. Simulated results obtained from the CFD model are used in a second step, to generate a database that contains the fuel and oxidant volumetric rates and utilizations and the corresponding cell voltages. In the third step mathematical relationships are developed between the input and output variables, using the database that has been generated in the previous step. In particular, the linear regression methodology and the radial basis function (RBF) neural network architecture are utilized for producing the input-output "meta-models". Several statistical tests are used to validate the proposed models. Finally, a multi-objective hierarchical Non-Linear Programming (NLP) problem is formulated that takes into account the constraints and limitations of the system. The multi-objective hierarchical approach is built upon two steps: first, the fuel volumetric rate is minimized, recognizing the fact that our first concern is to reduce consumption of the expensive fuel. In the second step, optimization is performed with respect to the oxidant volumetric rate. The proposed method is illustrated through its application for phosphoric acid fuel cell (PAFC) systems.

  18. Status of Fuel Development and Manufacturing for Space Nuclear Reactors at BWX Technologies

    Science.gov (United States)

    Carmack, W. J.; Husser, D. L.; Mohr, T. C.; Richardson, W. C.

    2004-02-01

    New advanced nuclear space propulsion systems will soon seek a high temperature, stable fuel form. BWX Technologies Inc (BWXT) has a long history of fuel manufacturing. UO2, UCO, and UCx have been fabricated at BWXT for various US and international programs. Recent efforts at BWXT have focused on establishing the manufacturing techniques and analysis capabilities needed to provide a high quality, high power, compact nuclear reactor for use in space nuclear powered missions. To support the production of a space nuclear reactor, uranium nitride has recently been manufactured by BWXT. In addition, analytical chemistry and analysis techniques have been developed to provide verification and qualification of the uranium nitride production process. The fabrication of a space nuclear reactor will require the ability to place an unclad fuel form into a clad structure for assembly into a reactor core configuration. To this end, BWX Technologies has reestablished its capability for machining, GTA welding, and EB welding of refractory metals. Specifically, BWX Technologies has demonstrated GTA welding of niobium flat plate and EB welding of niobium and Nb-1Zr tubing. In performing these demonstration activities, BWX Technologies has established the necessary infrastructure to manufacture UO2, UCx, or UNx fuel, components, and complete reactor assemblies in support of space nuclear programs.

  19. Development of standard fuel models in boreal forests of Northeast China through calibration and validation.

    Science.gov (United States)

    Cai, Longyan; He, Hong S; Wu, Zhiwei; Lewis, Benard L; Liang, Yu

    2014-01-01

    Understanding the fire prediction capabilities of fuel models is vital to forest fire management. Various fuel models have been developed in the Great Xing'an Mountains in Northeast China. However, the performances of these fuel models have not been tested for historical occurrences of wildfires. Consequently, the applicability of these models requires further investigation. Thus, this paper aims to develop standard fuel models. Seven vegetation types were combined into three fuel models according to potential fire behaviors which were clustered using Euclidean distance algorithms. Fuel model parameter sensitivity was analyzed by the Morris screening method. Results showed that the fuel model parameters 1-hour time-lag loading, dead heat content, live heat content, 1-hour time-lag SAV(Surface Area-to-Volume), live shrub SAV, and fuel bed depth have high sensitivity. Two main sensitive fuel parameters: 1-hour time-lag loading and fuel bed depth, were determined as adjustment parameters because of their high spatio-temporal variability. The FARSITE model was then used to test the fire prediction capabilities of the combined fuel models (uncalibrated fuel models). FARSITE was shown to yield an unrealistic prediction of the historical fire. However, the calibrated fuel models significantly improved the capabilities of the fuel models to predict the actual fire with an accuracy of 89%. Validation results also showed that the model can estimate the actual fires with an accuracy exceeding 56% by using the calibrated fuel models. Therefore, these fuel models can be efficiently used to calculate fire behaviors, which can be helpful in forest fire management.

  20. Ambient Laboratory Coater for Advanced Gas Reactor Fuel Development

    Energy Technology Data Exchange (ETDEWEB)

    Duane D. Bruns; Robert M. Counce; Irma D. Lima Rojas

    2010-06-09

    this research is targeted at developing improved experimentally-based scaling relationships for the hydrodynamics of shallow, gas-spouted beds of dense particles. The work is motivated by the need to more effctively scale up shallow spouted beds used in processes such as in the coating of nuclear fuel particles where precise control of solids and gas circulation is critically important. Experimental results reported here are for a 50 mm diameter spouted bed containing two different types of bed solids (alumina and zirconia) at different static bed depths and fluidized by air and helium. Measurements of multiple local average pressures, inlet gas pressure fluctuations, and spout height were used to characterize the bed hydrodynamics for each operating condition. Follow-on studies are planned that include additional variations in bed size, particle properties, and fluidizing gas. The ultimate objective is to identify the most important non-dimensional hydrodynamic scaling groups and possible spouted-bed design correlations based on these groups.

  1. Technology development for phosphoric acid fuel cell powerplant, phase 2

    Science.gov (United States)

    Christner, L.

    1981-01-01

    The development of materials, cell components, and reformers for on site integrated energy systems is described. Progress includes: (1) heat-treatment of 25 sq cm, 350 sq cm and 1200 sq cm cell test hardware was accomplished. Performance of fuel cells is improved by using this material; (2) electrochemical and chemical corrosion rates of heat-treated and as-molded graphite/phenolic resin composites in phosphoric acid were determined; (3) three cell, 5 in. x 15 in. stacks operated for up to 10,000 hours and 12 in. x 17 in. five cell stacks were tested for 5,000 hours; (4) a three cell 5 in. x 15 in. stack with 0.12 mg Pt/sq cm anodes and 0.25 mg Pt/sq cm cathodes was operated for 4,500 hours; and (5) an ERC proprietary high bubble pressure matrix, MAT-1, was tested for up to 10,000 hours.

  2. Development of low temperature solid oxide fuel cells

    Energy Technology Data Exchange (ETDEWEB)

    Bakker, W.T.; Goldstein, R. [Electric Power Research Institute, Palo Alto, CA (United States)

    1996-12-31

    The historical focus of the electric utility industry has been central station power plants. These plants are usually sited outside urban areas and electricity was delivered via high voltage transmission lines. Several things are beginning to change this historical precedent One is the popular concern with EMF as a health hazard. This has rendered the construction of new lines as well as upgrading old ones very difficult. Installation of power generating equipment near the customer enables the utility to better utilize existing transmission and distribution networks and defer investments. Power quality and lark of disturbances and interruptions is also becoming increasingly more important to many customers. Grid connected, but dedicated small power plants can greatly improve power quality. Finally the development of high efficiency, low emission, modular fuel cells promises near pollution free localized power generation with an efficiency equal to or exceeding that of even the most efficient central power stations.

  3. HTGR fuels and core development program. Quarterly progress report for the period ending November 30, 1976. [Graphite and fuel irradiations; fission product release

    Energy Technology Data Exchange (ETDEWEB)

    1976-12-27

    The work reported includes studies of reactions between core materials and coolant impurities, basic fission product transport mechanisms, core graphite development and testing, the development and testing of recyclable fuel systems, and physics and fuel management studies. Materials studies include irradiation capsule tests of both fuel and graphite. Experimental procedures and results are discussed and the data are presented in tables, graphs, and photographs.

  4. HTGR Fuels and Core Development Program. Quarterly progress report for the period ending August 31, 1977. [Graphite and fuel irradiation; fission product release

    Energy Technology Data Exchange (ETDEWEB)

    1977-09-01

    The work reported includes studies of reactions between core materials and coolant impurities, basic fission product transport mechanisms, core graphite development and testing, the development and testing of recyclable fuel systems, and physics and fuel management studies. Materials studies include irradiation capsule tests of both fuel and graphite. Experimental procedures and results are discussed and data are presented.

  5. UP-report. Fuel-based energy systems. Basis of the Development platform. Fuel to the Swedish Energy Agency's strategy work FOKUS; UP-rapport. Braenslebaserade energisystem. Underlag fraan Utvecklingsplattformen. Braensle till Energimyndighetens strategiarbete FOKUS

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2012-11-01

    The report serves as input to the Swedish Energy Agency's strategies and priorities for research and innovation in the fuel-based energy system for the period 2011 - 2016. The report has been compiled by members of the development platform Fuel. This report provides background and conditions for the fuel based energy system, and proposed priorities and activities for future efforts in this area. The development platform has contributed with valuable experience and knowledge which enabled the Swedish Energy Agency to then develop a strategy that meets the needs of the society and business.

  6. Development of Methanol-Reforming Catalysts for Fuel Cell Vehicles

    OpenAIRE

    2003-01-01

    Vehicles powered by proton exchange membrane (PEM) fuelcells are approaching commercialisation. Being inherently cleanand efficient sources of power, fuel cells constitute asustainable alternative to internal combustion engines to meetfuture low-emission legislation. The PEM fuel cell may befuelled directly by hydrogen, but other alternatives appearmore attractive at present, due to problems related to theproduction, transportation and handling of hydrogen. Fuelling with an alcohol fuel, such...

  7. Development and Fielding of a Direct Methanol Fuel Cell

    Science.gov (United States)

    2010-03-01

    fuel cell to power operational test instrumentation in support of the future combat systems test and evaluation. This unit also has application by the German Bundeswehr as a battery-charging station and auxiliary power unit. The direct methanol fuel cell is characterized by its low noise emission, minimal thermal signature, and high fuel efficiency that will enable continuously sustained operation for long duration missions in the

  8. Radiochemical Assays of Irradiated VVER-440 Fuel for Use in Spent Fuel Burnup Credit Activities

    Energy Technology Data Exchange (ETDEWEB)

    Jardine, L J

    2005-04-25

    The objective of this spent fuel burnup credit work was to study and describe a VVER-440 reactor spent fuel assembly (FA) initial state before irradiation, its operational irradiation history and the resulting radionuclide distribution in the fuel assembly after irradiation. This work includes the following stages: (1) to pick out and select a specific spent (irradiated) FA for examination; (2) to describe the FA initial state before irradiation; (3) to describe the irradiation history, including thermal calculations; (4) to examine the burnup distribution of select radionuclides along the FA height and cross-section; (5) to examine the radionuclide distributions; (6) to determine the Kr-85 release into the plenum; (7) to select and prepare FA rod specimens for destructive examinations; (8) to determine the radionuclide compositions, isotope masses and burnup in the rod specimens; and (9) to analyze, document and process the results. The specific workscope included the destructive assay (DA) of spent fuel assembly rod segments with an {approx}38.5 MWd/KgU burnup from a single VVER-440 fuel assembly from the Novovorenezh reactor in Russia. Based on irradiation history criteria, four rods from the fuel assembly were selected and removed from the assembly for examination. Next, 8 sections were cut from the four rods and sent for destructive analysis of radionuclides by radiochemical analyses. The results were documented in a series of seven reports over a period of {approx}1 1/2 years.

  9. Radiochemical Assays of Irradiated VVER-440 Fuel for Use in Spent Fuel Burnup Credit Activities

    Energy Technology Data Exchange (ETDEWEB)

    Jardine, L J

    2005-04-25

    The objective of this spent fuel burnup credit work was to study and describe a VVER-440 reactor spent fuel assembly (FA) initial state before irradiation, its operational irradiation history and the resulting radionuclide distribution in the fuel assembly after irradiation. This work includes the following stages: (1) to pick out and select a specific spent (irradiated) FA for examination; (2) to describe the FA initial state before irradiation; (3) to describe the irradiation history, including thermal calculations; (4) to examine the burnup distribution of select radionuclides along the FA height and cross-section; (5) to examine the radionuclide distributions; (6) to determine the Kr-85 release into the plenum; (7) to select and prepare FA rod specimens for destructive examinations; (8) to determine the radionuclide compositions, isotope masses and burnup in the rod specimens; and (9) to analyze, document and process the results. The specific workscope included the destructive assay (DA) of spent fuel assembly rod segments with an {approx}38.5 MWd/KgU burnup from a single VVER-440 fuel assembly from the Novovorenezh reactor in Russia. Based on irradiation history criteria, four rods from the fuel assembly were selected and removed from the assembly for examination. Next, 8 sections were cut from the four rods and sent for destructive analysis of radionuclides by radiochemical analyses. The results were documented in a series of seven reports over a period of {approx}1 1/2 years.

  10. Thermochemical Process Development Unit: Researching Fuels from Biomass, Bioenergy Technologies (Fact Sheet)

    Energy Technology Data Exchange (ETDEWEB)

    2009-01-01

    The Thermochemical Process Development Unit (TCPDU) at the National Renewable Energy Laboratory (NREL) is a unique facility dedicated to researching thermochemical processes to produce fuels from biomass.

  11. Microbial fuel cells with highly active aerobic biocathodes

    Science.gov (United States)

    Milner, Edward M.; Popescu, Dorin; Curtis, Tom; Head, Ian M.; Scott, Keith; Yu, Eileen H.

    2016-08-01

    Microbial fuel cells (MFCs), which convert organic waste to electricity, could be used to make the wastewater infrastructure more energy efficient and sustainable. However, platinum and other non-platinum chemical catalysts used for the oxygen reduction reaction (ORR) at the cathode of MFCs are unsustainable due to their high cost and long-term degradation. Aerobic biocathodes, which use microorganisms as the biocatalysts for cathode ORR, are a good alternative to chemical catalysts. In the current work, high-performing aerobic biocathodes with an onset potential for the ORR of +0.4 V vs. Ag/AgCl were enriched from activated sludge in electrochemical half-cells poised at -0.1 and + 0.2 V vs. Ag/AgCl. Gammaproteobacteria, distantly related to any known cultivated gammaproteobacterial lineage, were identified as dominant in these working electrode biofilms (23.3-44.3% of reads in 16S rRNA gene Ion Torrent libraries), and were in very low abundance in non-polarised control working electrode biofilms (0.5-0.7%). These Gammaproteobacteria were therefore most likely responsible for the high activity of biologically catalysed ORR. In MFC tests, a high-performing aerobic biocathode increased peak power 9-fold from 7 to 62 μW cm-2 in comparison to an unmodified carbon cathode, which was similar to peak power with a platinum-doped cathode at 70 μW cm-2.

  12. Development of advanced fuel cell system, phase 3

    Science.gov (United States)

    Handley, L. M.; Meyer, A. P.; Bell, W. F.

    1975-01-01

    A multiple task research and development program was performed to improve the weight, life, and performance characteristics of hydrogen-oxygen alkaline fuel cells for advanced power systems. Gradual wetting of the anode structure and subsequent long-term performance loss was determined to be caused by deposition of a silicon-containing material on the anode. This deposit was attributed to degradation of the asbestos matrix, and attention was therefore placed on development of a substitute matrix of potassium titanate. An 80 percent gold 20 percent platinum catalyst cathode was developed which has the same performance and stability as the standard 90 percent gold - 10 percent platinum cathode but at half the loading. A hybrid polysulfone/epoxy-glass fiber frame was developed which combines the resistance to the cell environment of pure polysulfone with the fabricating ease of epoxy-glass fiber laminate. These cell components were evaluated in various configurations of full-size cells. The ways in which the baseline engineering model system would be modified to accommodate the requirements of the space tug application are identified.

  13. Development of Advanced High Uranium Density Fuels for Light Water Reactors

    Energy Technology Data Exchange (ETDEWEB)

    Blanchard, James [Univ. of Wisconsin, Madison, WI (United States); Butt, Darryl [Boise State Univ., ID (United States); Meyer, Mitchell [Idaho National Lab. (INL), Idaho Falls, ID (United States); Xu, Peng [Westinghouse Electric Corporation, Pittsburgh, PA (United States)

    2016-02-15

    This work conducts basic materials research (fabrication, radiation resistance, thermal conductivity, and corrosion response) on U3Si2 and UN, two high uranium density fuel forms that have a high potential for success as advanced light water reactor (LWR) fuels. The outcome of this proposed work will serve as the basis for the development of advance LWR fuels, and utilization of such fuel forms can lead to the optimization of the fuel performance related plant operating limits such as power density, power ramp rate and cycle length.

  14. Utilization of spent activated carbon to enhance the combustion efficiency of organic sludge derived fuel.

    Science.gov (United States)

    Chen, Wei-Sheng; Lin, Chang-Wen; Chang, Fang-Chih; Lee, Wen-Jhy; Wu, Jhong-Lin

    2012-06-01

    This study examines the heating value and combustion efficiency of organic sludge derived fuel, spent activated carbon derived fuel, and derived fuel from a mixture of organic sludge and spent activated carbon. Spent activated carbon was sampled from an air pollution control device of an incinerator and characterized by XRD, XRF, TG/DTA, and SEM. The spent activated carbon was washed with deionized water and solvent (1N sulfuric acid) and then processed by the organic sludge derived fuel manufacturing process. After washing, the salt (chloride) and sulfide content could be reduced to 99% and 97%, respectively; in addition the carbon content and heating value were increased. Different ratios of spent activated carbon have been applied to the organic sludge derived fuel to reduce the NO(x) emission of the combustion.

  15. Fuels planning: science synthesis and integration; social issues fact sheet 02: Developing personal responsibility for fuels reduction: Types of information to encourage proactive behavior

    Science.gov (United States)

    Rocky Mountain Research Station USDA Forest Service

    2004-01-01

    Fuels management responsibilities may include providing local property owners with the information for taking responsibility for reducing fuels on their land. This fact sheet discusses three different types of information that may be useful in programs to engage property owners in fuel reduction activities.

  16. Options Study Documenting the Fast Reactor Fuels Innovative Design Activity

    Energy Technology Data Exchange (ETDEWEB)

    Jon Carmack; Kemal Pasamehmetoglu

    2010-07-01

    This document provides presentation and general analysis of innovative design concepts submitted to the FCRD Advanced Fuels Campaign by nine national laboratory teams as part of the Innovative Transmutation Fuels Concepts Call for Proposals issued on October 15, 2009 (Appendix A). Twenty one whitepapers were received and evaluated by an independent technical review committee.

  17. Perspectives on research and development of microbial fuel cells

    Energy Technology Data Exchange (ETDEWEB)

    Ortega-Martinez, A.; Vazquez Larios, A.L.; Solorza-Feria, O.; Poggi Varaldo, H.M. [Centro de Investigacion y de Estudios Avanzados del IPN, Mexico D.F. (Mexico)]. E-mail: hectorpoggi2001@gmail.com; rareli@hotmail.com

    2009-09-15

    Microbial fuel cells (MFC), is an anoxic electrochemical bioreactor where bacteria grow in the absence of oxygen in a chamber containing an anode which it may be covered by a biofilm. Microorganisms anoxically oxidize the organic substrate and electrons generated are released to the anode. Released protons are transferred to the cathode. Natural or forced aeration of the cathode supplies the oxygen for the final reaction 2H{sup +} + 2e{sup -} + (1/2) O{sub 2} = H{sub 2}O. In this work, we present a critical review on MFC focused on subjects that are receiving a growing interest from the research and technological communities: (i) types of MFC, their relative advantages and disadvantages and ranges of application; (ii) development of biocathodes; (iii) enrichment procedures of microbial communities in MFC. Recent research shows that one-chamber fitted with cathode aerated by natural aeration, and other special types of high performance MFC, have displaced the historical two-chamber MFC. Recent studies showed that electrochemically active bacteria (EAB) can be successfully enriched in MFC. The cost and eventual poisoning of the platinum catalyst used at the cathode is a major limitation to MFC application and economic viability. Researchers have started working on the concept of biocathodes that would use bacteria instead of platinum as a biocatalyst. Microbial enrichment of inocula seeded to MFC may provide a way to enrich the consortium with EAB, thus substantially increasing the transfer of electrons to the anode. Bioaugmentation of consortia in MFC with strains EAB, could contribute to the same goal. [Spanish] Las celdas de combustible microbianas (CCM) son un biorrector anoxico donde las bacterias crecen en ausencia de oxigeno en una camara que contiene un anodo que puede cubrirse con una biopelicula. Los microorganismos oxidan onoxicamente el sustrato organico y los electrones generados se liberan al anodo. Los protones liberados se transfieren al catodo. La

  18. Fuel-rich, catalytic reaction experimental results. [fuel development for high-speed civil transport aircraft

    Science.gov (United States)

    Rollbuhler, Jim

    1991-01-01

    Future aeropropulsion gas turbine combustion requirements call for operating at very high inlet temperatures, pressures, and large temperature rises. At the same time, the combustion process is to have minimum pollution effects on the environment. Aircraft gas turbine engines utilize liquid hydrocarbon fuels which are difficult to uniformly atomize and mix with combustion air. An approach for minimizing fuel related problems is to transform the liquid fuel into gaseous form prior to the completion of the combustion process. Experimentally obtained results are presented for vaporizing and partially oxidizing a liquid hydrocarbon fuel into burnable gaseous components. The presented experimental data show that 1200 to 1300 K reaction product gas, rich in hydrogen, carbon monoxide, and light-end hydrocarbons, is formed when flowing 0.3 to 0.6 fuel to air mixes through a catalyst reactor. The reaction temperatures are kept low enough that nitrogen oxides and carbon particles (soot) do not form. Results are reported for tests using different catalyst types and configurations, mass flowrates, input temperatures, and fuel to air ratios.

  19. Catalyst development and systems analysis of methanol partial oxidation for the fuel processor - fuel cell integration

    Energy Technology Data Exchange (ETDEWEB)

    Newson, E.; Mizsey, P.; Hottinger, P.; Truong, T.B.; Roth, F. von; Schucan, Th.H. [Paul Scherrer Inst. (PSI), Villigen (Switzerland)

    1999-08-01

    Methanol partial oxidation (pox) to produce hydrogen for mobile fuel cell applications has proved initially more successful than hydrocarbon pox. Recent results of catalyst screening and kinetic studies with methanol show that hydrogen production rates have reached 7000 litres/hour/(litre reactor volume) for the dry pox route and 12,000 litres/hour/(litre reactor volume) for wet pox. These rates are equivalent to 21 and 35 kW{sub th}/(litre reactor volume) respectively. The reaction engineering problems remain to be solved for dry pox due to the significant exotherm of the reaction (hot spots of 100-200{sup o}C), but wet pox is essentially isothermal in operation. Analyses of the integrated fuel processor - fuel cell systems show that two routes are available to satisfy the sensitivity of the fuel cell catalysts to carbon monoxide, i.e. a preferential oxidation reactor or a membrane separator. Targets for individual system components are evaluated for the base and best case systems for both routes to reach the combined 40% efficiency required for the integrated fuel processor - fuel cell system. (author) 2 figs., 1 tab., 3 refs.

  20. Research development and demonstration of a fuel cell/battery powered bus system. Interim report, August 1, 1991--April 30, 1992

    Energy Technology Data Exchange (ETDEWEB)

    Romano, S.; Wimmer, R.

    1992-04-30

    This report describes the progress in the Georgetown University research, development and demonstration project of a fuel cell/battery powered bus system. The topics addressed in the report include vehicle design and application analysis, technology transfer activities, coordination and monitoring of system design and integration contractor, application of fuel cells to other vehicles, current problems, work planned, and manpower, cost and schedule reports.

  1. Douglas United Nuclear, Inc. report to the Working Committee of the Fuel Element Development Committee

    Energy Technology Data Exchange (ETDEWEB)

    Stringer, J.T.

    1966-05-04

    This document provides the report to the working committee of the fuel element development committee for small and K reactor production fuels. Topics discussed are: Uranium core production data; uranium specification; future planning -- five year R&D program; thoria development; heat treating; UO{sub 2} irradiation; and alternate process development.

  2. NASA Glenn Research Center Electrochemistry Branch Battery and Fuel Cell Development Overview

    Science.gov (United States)

    Manzo, Michelle A.

    2011-01-01

    This presentation covers an overview of NASA Glenn s history and heritage in the development of electrochemical systems for aerospace applications. Current developments related to batteries and fuel cells are addressed. Specific areas of focus are Li-ion batteries and Polymer Electrolyte Membrane Fuel cells systems and their development for future Exploration missions.

  3. An State-of-Art Report on Remote Fabrication Technology Development for EBR-II Fuel

    Energy Technology Data Exchange (ETDEWEB)

    Song, K. C.; Lee, J. W.; Kim, S. S.; Park, J. J.; Cho, K. H.; Lee, D. Y.; Ryu, H. J.; Lee, C. B

    2008-05-15

    The Generation-IV nuclear system program, aiming to continue the sustainable development of nuclear power utilization, was internationally started from 2000. In order to develop the sodium cooled fast reactor (SFR) that is expected to be commercialized firstly among Gen-IV candidate nuclear systems, it would be essential that construction of hot-cell facility for SFR fuel fabrication will be important. SFR fuel contains minor actinide elements recycled from spent fuel and R and D program on a fabrication technology development of TRU metal fuel is currently conducted. Therefore, SFR fuel fabrication technology in hot cell will be future urgent issue. This report is an state-of art report related to remote fabrication technologies of metal fuel for the development of EBR-II fuel cycle at ANL. The focus in this report is the summary on the development of EBR-II fuel fabrication processes and its equipment, operation experience in each process which covers melt refining process of spent metal fuel, fuel pin and element fabrication processes and subassembly fabrication process, waste management. Argonne National Laboratory (ANL) (retitled to INL) designed and constructed the EBR(Experimental fast neutron Breeder Reactor)-II and were into operation using enriched uranium alloy fuel in July 1964. Over 700 irradiated reactor subassemblies were processed in the FCF (Fuel Cycle Facility) and returned to EBR-II reactor through April 1969. The comprehensive remote fabrication technology in hot cell for metallic fuel has been established according to EBR-II fuel cycle program. In FCF, the spent uranium alloy fuel from reactor was promptly recovered for reuse on site by low-decontamination, pyrometallurgical partial purification process called melt refining process. About 2.4 metric tons of irradiated fuel were processed by melt refining process. From the recovered fuel and additional new alloy, about 34,500 fully acceptable fuel elements were fabricated remotely in hot cell

  4. Analysis of different research activities and description of parties within the Swedish Knowledge Centre for Renewable Transportation Fuels

    Energy Technology Data Exchange (ETDEWEB)

    Lundgren, Joakim [Bio4Energy, Luleaa (Sweden); Wallberg, Ola [Lund Univ., Lund (Sweden)

    2012-07-01

    The Swedish Knowledge Centre for Renewable Transportation Fuels (f3) is a nationwide centre, which through cooperation and a systems approach will contribute to the development of sustainable fossil free fuels for transportation. The centre will, through joint efforts by the centre partners, perform syntheses of current research about the production of renewable fuels as well as supplementing research, such as comparative systems analyses of fuels, processes, raw materials and plant design. f3 provides a platform for collaboration between centre partners, with a common vision of sustainable fuels for transportation and common objectives. The centre partners include Sweden's most active universities and research institutes within the field, as well as a number of highly relevant industrial companies. New fuels will be an important component of a strategy to reduce both greenhouse gas emissions and our dependence on petroleum. The Swedish Government has established a vision for the Swedish transport industry to function without fossil fuels by 2030. Such a development requires a concerted response, with participation from all stake holders. Swedish researchers in various disciplines and at various colleges and institutes have a unique breadth and they are at the forefront in several areas of knowledge appropriate for a centre for renewable fuels. Through collaboration, f3 should help to link engineering and systems research and communicate results and conclusions from these research efforts. Within the f3 centre, several parties with different research activities are represented. This document is a snapshot of the different parties at the end of 2011 where the stake holders are described and their current research is highlighted. Also, the different projects conducted by the parties have been categorized and presented at the end of the document.

  5. Development and experimental characterization of a fuel cell powered aircraft

    Energy Technology Data Exchange (ETDEWEB)

    Bradley, Thomas H.; Moffitt, Blake A.; Mavris, Dimitri N.; Parekh, David E. [Georgia Institute of Technology, Atlanta, GA 30332-0405 (United States)

    2007-09-27

    This paper describes the characteristics and performance of a fuel cell powered unmanned aircraft. The aircraft is novel as it is the largest compressed hydrogen fuel cell powered airplane built to date and is currently the only fuel cell aircraft whose design and test results are in the public domain. The aircraft features a 500 W polymer electrolyte membrane fuel cell with full balance of plant and compressed hydrogen storage incorporated into a custom airframe. Details regarding the design requirements, implementation and control of the aircraft are presented for each major aircraft system. The performances of the aircraft and powerplant are analyzed using data from flights and laboratory tests. The efficiency and component power consumption of the fuel cell propulsion system are measured at a variety of flight conditions. The performance of the aircraft powerplant is compared to other 0.5-1 kW-scale fuel cell powerplants in the literature and means of performance improvement for this aircraft are proposed. This work represents one of the first studies of fuel cell powered aircraft to result in a demonstration aircraft. As such, the results of this study are of practical interest to fuel cell powerplant and aircraft designers. (author)

  6. Advanced fuel developments for an industrial accelerator driven system prototype

    Energy Technology Data Exchange (ETDEWEB)

    Delage, Fabienne; Ottaviani, Jean Pierre [Commissariat a l' Energie Atomique CEA (France); Fernandez-Carretero, Asuncion; Staicu, Dragos [JRC-ITU (Germany); Boccaccini, Claudia-Matzerath; Chen, Xue-Nong; Mascheck, Werner; Rineiski, Andrei [Forschungszentrum Karlsruhe - FZK (Germany); D' Agata, Elio [JRC-IE (Netherlands); Klaassen, Frodo [NRG, PO Box 25, NL-1755 ZG Petten (Netherlands); Sobolev, Vitaly [SCK-CEN (Belgium); Wallenius, Janne [KTH Royal Institute of Technology (Sweden); Abram, T. [National Nuclear Laboratory - NNL (United Kingdom)

    2009-06-15

    Fuel to be used in an Accelerator Driven System (ADS) for transmutation in a fast spectrum, can be described as a highly innovative concept in comparison with fuels used in critical cores. ADS fuel is not fertile, so as to improve the transmutation performance. It necessarily contains a high concentration ({approx}50%) of minor actinides and plutonium. This unusual fuel composition results in high gamma and neutron emissions during its fabrication, as well as degraded core performance. So, an optimal ADS fuel is based on finding the best compromise between thermal, mechanical, chemical, neutronic and technological constraints. CERCER and CERMET composite fuels consisting of particles of (Pu,MA)O{sub 2} phases dispersed in a magnesia or molybdenum matrix are under investigation within the frame of the ongoing European Integrated Project EUROTRANS (European Research programme for Transmutation) which aims at performing a conceptual design of a 400 MWth transmuter: the European Facility for Industrial Transmutation (EFIT). Performances and safety of EFIT cores loaded with CERCER and CERMET fuels have been evaluated. Out-of-pile and in-pile experiments are carried out to gain knowledge on the properties and the behaviour of these fuels. The current paper gives an overview of the work progress. (authors)

  7. Development of burnup dependent fuel rod model in COBRA-TF

    Science.gov (United States)

    Yilmaz, Mine Ozdemir

    The purpose of this research was to develop a burnup dependent fuel thermal conductivity model within Pennsylvania State University, Reactor Dynamics and Fuel Management Group (RDFMG) version of the subchannel thermal-hydraulics code COBRA-TF (CTF). The model takes into account first, the degradation of fuel thermal conductivity with high burnup; and second, the fuel thermal conductivity dependence on the Gadolinium content for both UO2 and MOX fuel rods. The modified Nuclear Fuel Industries (NFI) model for UO2 fuel rods and Duriez/Modified NFI Model for MOX fuel rods were incorporated into CTF and fuel centerline predictions were compared against Halden experimental test data and FRAPCON-3.4 predictions to validate the burnup dependent fuel thermal conductivity model in CTF. Experimental test cases from Halden reactor fuel rods for UO2 fuel rods at Beginning of Life (BOL), through lifetime without Gd2O3 and through lifetime with Gd 2O3 and a MOX fuel rod were simulated with CTF. Since test fuel rod and FRAPCON-3.4 results were based on single rod measurements, CTF was run for a single fuel rod surrounded with a single channel configuration. Input decks for CTF were developed for one fuel rod located at the center of a subchannel (rod-centered subchannel approach). Fuel centerline temperatures predicted by CTF were compared against the measurements from Halden experimental test data and the predictions from FRAPCON-3.4. After implementing the new fuel thermal conductivity model in CTF and validating the model with experimental data, CTF model was applied to steady state and transient calculations. 4x4 PWR fuel bundle configuration from Purdue MOX benchmark was used to apply the new model for steady state and transient calculations. First, one of each high burnup UO2 and MOX fuel rods from 4x4 matrix were selected to carry out single fuel rod calculations and fuel centerline temperatures predicted by CTF/TORT-TD were compared against CTF /TORT-TD /FRAPTRAN

  8. Highly active carbon supported Pd cathode catalysts for direct formic acid fuel cells

    Science.gov (United States)

    Mikolajczuk-Zychora, A.; Borodzinski, A.; Kedzierzawski, P.; Mierzwa, B.; Mazurkiewicz-Pawlicka, M.; Stobinski, L.; Ciecierska, E.; Zimoch, A.; Opałło, M.

    2016-12-01

    One of the drawbacks of low-temperature fuel cells is high price of platinum-based catalysts used for the electroreduction of oxygen at the cathode of the fuel cell. The aim of this work is to develop the palladium catalyst that will replace commonly used platinum cathode catalysts. A series of palladium catalysts for oxygen reduction reaction (ORR) were prepared and tested on the cathode of Direct Formic Acid Fuel Cell (DFAFC). Palladium nanoparticles were deposited on the carbon black (Vulcan) and on multiwall carbon nanotubes (MWCNTs) surface by reduction of palladium(II) acetate dissolved in ethanol. Hydrazine was used as a reducing agent. The effect of functionalization of the carbon supports on the catalysts physicochemical properties and the ORR catalytic activity on the cathode of DFAFC was studied. The supports were functionalized by treatment in nitric acid for 4 h at 80 °C. The structure of the prepared catalysts has been characterized by thermogravimetric analysis (TGA), X-ray diffraction (XRD), transmission electron microscope (TEM) and cyclic voltammetry (CV). Hydrophilicity of the catalytic layers was determined by measuring contact angles of water droplets. The performance of the prepared catalysts has been compared with that of the commercial 20 wt.% Pt/C (Premetek) catalyst. The maximum power density obtained for the best palladium catalyst, deposited on the surface of functionalized carbon black, is the same as that for the commercial Pt/C (Premetek). Palladium is cheaper than platinum, therefore the developed cathode catalyst is promising for future applications.

  9. Development status and research directions on the structural components of the fuel assembly

    Energy Technology Data Exchange (ETDEWEB)

    Song, Ki Nam; Jeong, Yeon Ho; Kim, Hyung Kyu; Kang, Heung Seok; Yoon, Kyung Ho; Bang, Jae Keon

    1997-06-01

    Survey on the structural components of the state-of-the art of the PWR fuel assembly developed by various nuclear fuel vendors has been performed. As a result, some developmental directions and mechanical/structural basic technology to be established for these structural components have been drawn out. The developmental directions are as follows; The top end piece shall be designed in shape to reduce its height to accommodate the fuel rod growth for high burnup and to have a function for easy reconstitution of the fuel assembly. The bottom end piece shall be designed in shape to reduce its height to accommodate the fuel rod growth for high burnup and to have a function for easy reconstitution of the fuel assembly. The bottom end piece shall be designed in shape to reduce its height to accommodate the fuel rod growth for high burnup and to have a function of debris protection. The spacer grid shall be designed in shape to have a function of enhancing the thermal margin and maintaining the fuel rod integrity without fuel failure due to fuel rod fretting and vibration. The mechanical/structural basic technology which must be established is as follows; The stress analysis results shall comply with the stress criteria specified in the ASME code stress limits and the shape optimization technology shall be developed for the top/bottom end pieces. For the spacer grid cell, the nonlinear analysis model of the fuel rod and the analysis model on the flow-induced fuel rod vibration, and a study of the mechanism and a quantified model on the fuel rod fretting wear shall be developed. In addition, numerical analysis model to estimate the buckling strength of the spacer grid assembly shall be developed. Besides above technology, technology related the verification test should be developed. (author). 30 figs., 54 refs.

  10. In-situ electrochemically active surface area evaluation of an open-cathode polymer electrolyte membrane fuel cell stack

    Science.gov (United States)

    Torija, Sergio; Prieto-Sanchez, Laura; Ashton, Sean J.

    2016-09-01

    The ability to evaluate the electrochemically active surface area (ECSA) of fuel cell electrodes is crucial toward characterising designs and component suites in-situ, particularly when evaluating component durability in endurance testing, since it is a measure of the electrode area available to take part in the fuel cell reactions. Conventional methods to obtain the ECSA using cyclic voltammetry, however, rely on potentiostats that cannot be easily scaled to simultaneously evaluate all cells in a fuel cell stack of practical size, which is desirable in fuel cell development. In-situ diagnostics of an open-cathode fuel cell stack are furthermore challenging because the cells do not each possess an enclosed cathode compartment; instead, the cathodes are rather open to the environment. Here we report on a diagnostic setup that allows the electrochemically active surface area of each cell anode or cathode in an open-cathode fuel cell stack to be evaluated in-situ and simultaneously, with high resolution and reproducibility, using an easily scalable chronopotentiometry methodology and a gas-tight stack enclosure.

  11. Synthetic fuels development in Kentucky: Four scenarios for an energy future as constructed from lessons of the past

    Science.gov (United States)

    Musulin, Mike, II

    The continued failure of synthetic fuels development in the United States to achieve commercialization has been documented through the sporadic periods of mounting corporate and government enthusiasm and high levels of research and development efforts. Four periods of enthusiasm at the national level were followed by waning intervals of shrinking financial support and sagging R&D work. The continuing cycle of mobilization and stagnation has had a corresponding history in Kentucky. To better understand the potential and the pitfalls of this type of technological development the history of synthetic fuels development in the United States is presented as background, with a more detailed analysis of synfuels development in Kentucky. The first two periods of interest in synthetic fuels immediately after the Second World War and in the 1950s did not result in any proposed plants for Kentucky, but the third and fourth periods of interest created a great deal of activity. A theoretically grounded case study is utilized in this research project to create four different scenarios for the future of synthetic fuels development. The Kentucky experience is utilized in this case study because a fifth incarnation of synthetic fuels development has been proposed for the state in the form of an integrated gasification combined cycle power plant (IGCC) to utilize coal and refuse derived fuel (RDF). The project has been awarded a grant from the U.S. Department of Energy Clean Coal Technology program. From an examination and analysis of these periods of interest and the subsequent dwindling of interest and participation, four alternative scenarios are constructed. A synfuels breakthrough scenario is described whereby IGCC becomes a viable part of the country's energy future. A multiplex scenario describes how IGCC becomes a particular niche in energy production. The status quo scenario describes how the old patterns of project failure repeat themselves. The fourth scenario describes

  12. A cost-effective microbial fuel cell to detect and select for photosynthetic electrogenic activity in algae and cyanobacteria

    NARCIS (Netherlands)

    Luimstra, V.M.; Kennedy, S.J.; Güttler, J.; Wood, S.A.; Williams, D.E.; Packer, M.A.

    2014-01-01

    This work describes the development of an easily constructed, cost-effective photosynthetic microbial fuel cell design with highly reproducible electrochemical characteristics that can be used to screen algae and cyanobacteria for photosynthetic electrogenic activity. It is especially suitable for b

  13. Molten carbonate fuel cell product development test. Annual report, October 1992--September 1993

    Energy Technology Data Exchange (ETDEWEB)

    1993-12-01

    Advanced fuel cell active components have been developed and scaled up from laboratory scale to commercial scale. Full width components of both the stabilized nickel cathodes and the low chrome anodes have been successfully cast on M-C Power`s production tape caster. An improved design for a fuel cell separator plate has been developed. The improved design meets the goals of lower cost and manufacturing simplicity, and addresses performance issues of the current commercial area plate. The engineering that the Bechtel Corporation has completed for the MCFC power plant includes a site design, a preliminary site layout, a Process Flow Diagram, and specification for the procurement of some of the major equipment items. Raw materials for anode and cathode components were ordered and received during the first half of 1993. Tape casting of anodes was started in late summer and continued through August. In addition to the technical progress mentioned above, an environment assessment was prepared in compliance with the National Environmental Policy Act of 1969 (NEPA). As a result, the PDT has received a categorical exclusion from the Air Pollution Control District permit requirements. The PDT is configured to demonstrate the viability of natural gas-fueled MCFC for the production of electricity and thermal energy in an environmentally benign manner for use in commercial and industrial applications.

  14. Development of LWR Fuels with Enhanced Accident Tolerance

    Energy Technology Data Exchange (ETDEWEB)

    Lahoda, Edward J. [Westinghouse Electric Company, LLC, Cranberry Woods, PA (United States); Boylan, Frank A. [Westinghouse Electric Company, LLC, Cranberry Woods, PA (United States)

    2015-10-30

    Significant progress was made on the technical, licensing, and business aspects of the Westinghouse Electric Company’s Enhanced Accident Tolerant Fuel (ATF) by the Westinghouse ATF team. The fuel pellet options included waterproofed U15N and U3Si2 and the cladding options SiC composites and zirconium alloys with surface treatments. Technology was developed that resulted in U3Si2 pellets with densities of >94% being achieved at the Idaho National Laboratory (INL). The use of U3Si2 will represent a 15% increase in U235 loadings over those in UO₂ fuel pellets. This technology was then applied to manufacture pellets for 6 test rodlets which were inserted in the Advanced Test Reactor (ATR) in early 2015 in zirconium alloy cladding. The first of these rodlets are expected to be removed in about 2017. Key characteristics to be determined include verification of the centerline temperature calculations, thermal conductivity, fission gas release, swelling and degree of amorphization. Waterproofed UN pellets have achieved >94% density for a 32% U3Si2/68% UN composite pellet at Texas A&M University. This represents a U235 increase of about 31% over current UO2 pellets. Pellets and powders of UO2, UN, and U3Si2the were tested by Westinghouse and Los Alamos National Laboratory (LANL) using differential scanning calorimetry to determine what their steam and 20% oxygen corrosion temperatures were as compared to UO2. Cold spray application of either the amorphous steel or the Ti2AlC was successful in forming an adherent ~20 micron coating that remained after testing at 420°C in a steam autoclave. Tests at 1200°C in 100% steam on coatings for Zr alloy have not been successful, possibly due to the low density of the coatings which allowed steam transport to the base zirconium metal. Significant modeling and testing

  15. Fuel Cycle Research & Development Technical Monthly - May 2012

    Energy Technology Data Exchange (ETDEWEB)

    Miller, Michael C. [Los Alamos National Laboratory

    2012-06-28

    Management and Integration LANL - Initial coordination meetings with NE and NA-20 were held the first week of May. Additional meetings, to include NA-82 and the new Proliferation and Terrorism Risk Assessment task are scheduled for June. Work package planning as part of the NTD transition is ongoing. Microcalorimetry LANL - Some parts to attempt repair of a malfunctioning water chiller that has been holding up work on the current detector array have arrived. We will attempt to begin running the compressor/cryostat next week to resume work on commissioning the detector array. We have also been working on a backup plan to temporarily move our system to a different lab space. Completed data analysis and prepared a paper summarizing Pu measurements for peer-review journal. Two members of our team presented work at the SORMA West 2012 conference. Completed data analysis and prepared a milestone report summarizing the development of Monte Carlo tools to study systematic errors. Electrochemical Sensor INL - The second sensor test was stopped short due to the work stand-down. Some activities related to this work have resumed, but not all. The sensor used during the second test was removed from the furnace and it showed cracks and later crumbled when being rinsed for sample preparation. The sensor material will be submitted to SEM analysis once work is resumed in the facilities where analysis is performed. A third sensor test has started. Tests with different arrangements will continue and will be oriented based on post-test analysis of the first three sensor tests. Materials with different annealing temperatures will also be prepared for analysis. Lead slowing down spectrometer LANL - Continued work on perturbation method for LSDS analysis. We are running simulations to delineate issues and are checking additional data libraries to see whether there are differences in simulation results. Electrochemical sensor INL - The second sensor test was stopped short due to the work

  16. Technology development for phosphoric acid fuel cell powerplant (phase 2)

    Science.gov (United States)

    Christner, L.

    1979-01-01

    The status of technology for the manufacturing and testing of 1200 sq. cm cell materials, components, and stacks for on-site integrated energy systems is assessed. Topics covered include: (1) preparation of thin layers of silicon carbide; (2) definition and control schemes for volume changes in phosphoric acid fuel cells; (3) preparation of low resin content graphite phenolic resin composites; (4) chemical corrosion of graphite-phenolic resin composites in hot phosphoric acid; (5) analysis of electrical resistance of composite materials for fuel cells; and (6) fuel cell performance and testing.

  17. Development of OTM Syngas Process and Testing of Syngas Derived Ultra-clean Fuels in Diesel Engines and Fuel Cells

    Energy Technology Data Exchange (ETDEWEB)

    E.T. Robinson; John Sirman; Prasad Apte; Xingun Gui; Tytus R. Bulicz; Dan Corgard; John Hemmings

    2005-05-01

    This final report summarizes work accomplished in the Program from January 1, 2001 through December 31, 2004. Most of the key technical objectives for this program were achieved. A breakthrough material system has lead to the development of an OTM (oxygen transport membrane) compact planar reactor design capable of producing either syngas or hydrogen. The planar reactor shows significant advantages in thermal efficiency and a step change reduction in costs compared to either autothermal reforming or steam methane reforming with CO{sub 2} recovery. Syngas derived ultra-clean transportation fuels were tested in the Nuvera fuel cell modular pressurized reactor and in International Truck and Engine single cylinder test engines. The studies compared emission and engine performance of conventional base fuels to various formulations of ultra-clean gasoline or diesel fuels. A proprietary BP oxygenate showed significant advantage in both applications for reducing emissions with minimal impact on performance. In addition, a study to evaluate new fuel formulations for an HCCI engine was completed.

  18. Electrocatalysis and electrocatalysts for low temperature fuel cells: fundamentals, state of the art, research and development

    Directory of Open Access Journals (Sweden)

    Wendt Hartmut

    2005-01-01

    Full Text Available This article deals with electrocatalysis and electrocatalysts for low temperature fuel cells and also with established means and methods in electrocatalyst research, development and characterization. The intention is to inform about the fundamentals, state of the art, research and development of noble metal electrocatalysts for fuel cells operating at low temperatures.

  19. Development of Advanced Low Emission Injectors and High-Bandwidth Fuel Flow Modulation Valves

    Science.gov (United States)

    Mansour, Adel

    2015-01-01

    Parker Hannifin Corporation developed the 3-Zone fuel nozzle for NASA's Environmentally Responsible Aviation Program to meet NASAs target of 75 LTO NOx reduction from CAEP6 regulation. The nozzle concept was envisioned as a drop-in replacement for currently used fuel nozzle stem, and is built up from laminates to provide energetic mixing suitable for lean direct injection mode at high combustor pressure. A high frequency fuel valve was also developed to provide fuel modulation for the pilot injector. Final testing result shows the LTO NOx level falling just shy of NASAs goal at 31.

  20. Motor fuel taxation, energy conservation, and economic development: A regional approach

    Energy Technology Data Exchange (ETDEWEB)

    England, Richard W. [Department of Economics, University of New Hampshire, Durham, NH 03824-3593 (United States)

    2007-03-01

    Combustion of motor fuels has a variety of environmental impacts on local, regional and global scales. Taxing motor fuels more heavily would mitigate those environmental impacts. However, many governments are reluctant to increase motor fuel taxes because they fear that the tax incidence will be regressive and that economic development will be impeded. Using data for the New England region of the United States, this paper argues that an oil-importing region can conserve energy, avoid regressive impacts and encourage economic development by taxing motor fuels more heavily and rebating the incremental revenues to owners of motor vehicles. (author)

  1. Solid Oxide Fuel Cell Development at Topsoe Fuel Cell A/S and Risø National Laboratory

    DEFF Research Database (Denmark)

    Christiansen, Niels; Hansen, J B.; Larsen, H H.

    2007-01-01

    The consortium of Topsoe Fuel Cell A/S and Riso National Laboratory has up-scaled its production capacity of anode-supported cells to about 1100 per week. Stacks are based on a compact thin plate multilayer design with metallic interconnects and 12x12 cm(2) or 18x18 cm(2) foot print. Larger (500 cm......(2)) cells are currently under evaluation. Stacks have been tested successfully for more than 13000 h. Several 50 or 75 cell stacks in the 1+ kW power range have been tested successfully at a fuel utilisation of up to 92%. Multi stack modules consisting of four 75 cell stacks have been tested...... tolerance towards redox cycling. In collaboration with Wartsila, a 24-stack prototype based on natural gas is being tested. For methanol based systems the methanol is methanated upstream the anode using a newly developed proprietary Haldor Topsoe catalyst. The range of fuels have further been extended...

  2. DEVELOPMENT OF METHODOLOGY AND FIELD DEPLOYABLE SAMPLING TOOLS FOR SPENT NUCLEAR FUEL INTERROGATION IN LIQUID STORAGE

    Energy Technology Data Exchange (ETDEWEB)

    Berry, T.; Milliken, C.; Martinez-Rodriguez, M.; Hathcock, D.; Heitkamp, M.

    2012-06-04

    This project developed methodology and field deployable tools (test kits) to analyze the chemical and microbiological condition of the fuel storage medium and determine the oxide thickness on the spent fuel basin materials. The overall objective of this project was to determine the amount of time fuel has spent in a storage basin to determine if the operation of the reactor and storage basin is consistent with safeguard declarations or expectations. This project developed and validated forensic tools that can be used to predict the age and condition of spent nuclear fuels stored in liquid basins based on key physical, chemical and microbiological basin characteristics. Key parameters were identified based on a literature review, the parameters were used to design test cells for corrosion analyses, tools were purchased to analyze the key parameters, and these were used to characterize an active spent fuel basin, the Savannah River Site (SRS) L-Area basin. The key parameters identified in the literature review included chloride concentration, conductivity, and total organic carbon level. Focus was also placed on aluminum based cladding because of their application to weapons production. The literature review was helpful in identifying important parameters, but relationships between these parameters and corrosion rates were not available. Bench scale test systems were designed, operated, harvested, and analyzed to determine corrosion relationships between water parameters and water conditions, chemistry and microbiological conditions. The data from the bench scale system indicated that corrosion rates were dependent on total organic carbon levels and chloride concentrations. The highest corrosion rates were observed in test cells amended with sediment, a large microbial inoculum and an organic carbon source. A complete characterization test kit was field tested to characterize the SRS L-Area spent fuel basin. The sampling kit consisted of a TOC analyzer, a YSI

  3. Technical Development on Burn-up Credit for Spent LWR Fuel

    Energy Technology Data Exchange (ETDEWEB)

    Gauld, I.C.

    2001-12-26

    Technical development on burn-up credit for spent LWR fuels had been performed at JAERI since 1990 under the contract with Science and Technology Agency of Japan entitled ''Technical Development on Criticality Safety Management for Spent LWR Fuels.'' Main purposes of this work are to obtain the experimental data on criticality properties and isotopic compositions of spent LWR fuels and to verify burnup and criticality calculation codes. In this work three major experiments of exponential experiments for spent fuel assemblies to obtain criticality data, non-destructive gamma-ray measurement of spent fuel rods for evaluating axial burn-up profiles, and destructive analyses of spent fuel samples for determining precise burn-up and isotopic compositions were carried out. The measured data obtained were used for validating calculation codes as well as an examination of criticality safety analyses. Details of the work are described in this report.

  4. Technical development on burn-up credit for spent LWR fuels

    Energy Technology Data Exchange (ETDEWEB)

    Nakahara, Yoshinori; Suyama, Kenya; Suzaki, Takenori [eds.] [Japan Atomic Energy Research Inst., Tokai, Ibaraki (Japan). Tokai Research Establishment

    2000-10-01

    Technical development on burn-up credit for spent LWR fuels had been performed at JAERI since 1990 under the contract with Science and Technology Agency of Japan entitled 'Technical Development on Criticality Safety Management for Spent LWR Fuels'. Main purposes of this work are to obtain the experimental data on criticality properties and isotopic compositions of spent LWR fuels and to verify burn-up and criticality calculation codes. In this work three major experiments of exponential experiments for spent fuel assemblies to obtain criticality data, non-destructive gamma-ray measurement of spent fuel rods for evaluating axial burn-up profiles, and destructive analyses of spent fuel samples for determining precise burn-up and isotopic compositions were carried out. The measured data obtained were used for validating calculation codes as well as an examination of criticality safety analyses. Details of the work are described in this report. (author)

  5. Development of Vibro-packed fuel design code

    Energy Technology Data Exchange (ETDEWEB)

    Nakamura, Masahiro; Sekine, Nobuyuki; Pouchon, M.A.; Miyamoto, Hiroshi [Japan Nuclear Cycle Development Inst., Tokai Works, Waste Management and Fuel Cycle Research Center, Tokai, Ibaraki (Japan); Nakajima, Yasuo [Japan Nuclear Cycle Development Inst., Heat Office, Executive Office for Policy Planning and Administration, Tokai, Ibaraki (Japan)

    2002-06-01

    In the feasibility study of a FBR cycle system, Vibro-packed fuel is considered. For the design and evaluation, three Vibro-pack-specific models are incorporated into the design code. Matthews' sintering model is used to calculate the neck growth rate between particles. The SPACON model, introduced by Botta et al. is used to calculate the effective thermal conductivity of fuel and the heat transport between fuel and cladding. A three-dimensional distinct element method is applied to analyze the mechanical properties, resulting in empirical Young's module. Experimental data will be used for the evaluation of each model, and irradiation test data will be used for evaluation of the total code. Consequently, the code reliability will be determined and potentially increased. This will constitute an important step towards fuel licensing. (author)

  6. An update in the 'development of alternate liquid fuels'

    Science.gov (United States)

    Rose, M. J.

    The Brookhaven National Laboratory has formulated a series of Alternate Liquid Fuels (AIF), compounded from combustible fluids such as alcohols, mineral oils and solvents, found in the waste streams of the cosmetic, petrochemical, electronics and other industries. These fuels are now being processed by a pilot plant with a productive capacity of 40,000 gallons in 8 hours, at direct costs ranging from $0.26 to $0.29 a gallon depending on selected feedstocks and blend ratios

  7. Activity of fuel batches processed through Hanford separations plants, 1944 through 1989

    Energy Technology Data Exchange (ETDEWEB)

    Watrous, R.A.; Wootan, D.W.

    1997-07-29

    This document provides a printout of the ``Fuel Activity Database`` (version U6) generated by the Hanford DKPRO code and transmitted to the Los Alamos National Laboratory for input to their ``Hanford Defined Waste`` model of waste tank inventories. This fuel activity file consists of 1,276 records--each record representing the activity associated with a batch of spent reactor fuel processed by month (or shorter period) through individual Hanford separations plants between 1944 and 1989. Each record gives the curies for 46 key radionuclides, decayed to a common reference date of January 1, 1994.

  8. Laboratory Directed Research and Development (LDRD) on Mono-uranium Nitride Fuel Development for SSTAR and Space Applications

    Energy Technology Data Exchange (ETDEWEB)

    Choi, J; Ebbinghaus, B; Meiers, T; Ahn, J

    2006-02-09

    The US National Energy Policy of 2001 advocated the development of advanced fuel and fuel cycle technologies that are cleaner, more efficient, less waste-intensive, and more proliferation resistant. The need for advanced fuel development is emphasized in on-going DOE-supported programs, e.g., Global Nuclear Energy Initiative (GNEI), Advanced Fuel Cycle Initiative (AFCI), and GEN-IV Technology Development. The Directorates of Energy & Environment (E&E) and Chemistry & Material Sciences (C&MS) at Lawrence Livermore National Laboratory (LLNL) are interested in advanced fuel research and manufacturing using its multi-disciplinary capability and facilities to support a design concept of a small, secure, transportable, and autonomous reactor (SSTAR). The E&E and C&MS Directorates co-sponsored this Laboratory Directed Research & Development (LDRD) Project on Mono-Uranium Nitride Fuel Development for SSTAR and Space Applications. In fact, three out of the six GEN-IV reactor concepts consider using the nitride-based fuel, as shown in Table 1. SSTAR is a liquid-metal cooled, fast reactor. It uses nitride fuel in a sealed reactor vessel that could be shipped to the user and returned to the supplier having never been opened in its long operating lifetime. This sealed reactor concept envisions no fuel refueling nor on-site storage of spent fuel, and as a result, can greatly enhance proliferation resistance. However, the requirement for a sealed, long-life core imposes great challenges to research and development of the nitride fuel and its cladding. Cladding is an important interface between the fuel and coolant and a barrier to prevent fission gas release during normal and accidental conditions. In fabricating the nitride fuel rods and assemblies, the cladding material should be selected based on its the coolant-side corrosion properties, the chemical/physical interaction with the nitride fuel, as well as their thermal and neutronic properties. The US NASA space reactor, the

  9. Developing Singapore Driving Cycle for passenger cars to estimate fuel consumption and vehicular emissions

    Science.gov (United States)

    Ho, Sze-Hwee; Wong, Yiik-Diew; Chang, Victor Wei-Chung

    2014-11-01

    Singapore has pledged to attain 7-11% Business-As-Usual carbon emissions reduction by 2020. Road transport sector is a significant source of carbon emissions, estimated to be the third largest sector in Singapore. A current gap in environmental evaluation for road transport activities in Singapore is the lack of a representative driving cycle for passenger cars (64% of the total population of 974,170 vehicles). This Singapore Driving Cycle (SDC) is hence developed for Singapore roads and traffic conditions. A chase-car (instrumented vehicle) was used to collect on-road data along 12 designed routes, and circulation driving on highly utilized arterial roads (including those in Central Business District (CBD) and both inner and outer ring roads fringing the CBD area). The SDC was thus hence constructed, with consideration of road type proportions, time periods and desired distance, duration and peak-lull proportion. In essence, the SDC is a 2400-s speed-time profile to represent the driving pattern for passenger car in Singapore. Microscopic estimation model (CMEM) shows that, as compared to SDC, the New European Driving Cycle (NEDC) underestimates most of the vehicular emissions (fuel, CO2, HC and NOx by 5%, 5%, 22% and 47%, respectively) and overestimates CO by 8%. The SDC is thus more suitable than the NEDC that is currently in use in Singapore; the SDC can be used to generate more accurate fuel consumption and emissions ratings for various uses (for example, inventory of vehicular emissions and fuel economy labelling).

  10. Effect of a fuel activation device (FAD) on particulate matter and black carbon emissions from a diesel locomotive engine.

    Science.gov (United States)

    Park, Duckshin; Lee, Taejeong; Lee, Yongil; Jeong, Wonseog; Kwon, Soon-Bark; Kim, Dongsool; Lee, Kiyoung

    2017-01-01

    Emission reduction is one of the most efficient control measures in fuel-powered locomotives. The purpose of this study was to determine the reduction in particulate matter (PM) and black carbon (BC) emissions following the installation of a fuel activation device (FAD). The FAD was developed to enhance fuel combustion by atomizing fuel and to increase the surface area per unit volume of injected fuel. Emission reduction by the FAD was evaluated by installing a FAD in an operating diesel locomotive in Mongolia. The test was conducted on a train operating on a round-trip 238-km route between Ulaanbaatar and Choir stations in Mongolia. The fuel consumption rate was slightly reduced following the FAD installation. The FAD installation decreased PM and BC emissions in the diesel locomotive, especially coarse PM. The PM10 reductions achieved after FAD installation were 58.0, 69.7, and 34.2% for the constant velocity, stopping, and acceleration stages of the train's operation, respectively. The BC reduction rates were 29.5, 52.8, and 27.4% for the constant velocity, stopping, and acceleration stages, respectively.

  11. Development of alternative fuels from coal-derived syngas. Quarterly status report No. 6, January 1--March 31, 1992

    Energy Technology Data Exchange (ETDEWEB)

    Brown, D.M.

    1992-05-19

    The overall objectives of this program are to investigate potential technologies for the conversion of coal-derived synthesis gas to oxygenated fuels, hydrocarbon fuels, fuel intermediates, and octane enhancers; and to demonstrate the most promising technologies at DOE`s LaPorte, Texas, Slurry Phase Alternative Fuels Development Unit (AFDU). BASF continues to have difficulties in scaling-up the new isobutanol synthesis catalyst developed in Air Products` laboratories. Investigations are proceeding, but the proposed operation at LaPorte in April is now postponed. DOE has accepted a proposal to demonstrate Liquid Phase Shift (LPS) chemistry at LaPorte as an alternative to isobutanol. There are two principal reasons for carrying out this run. First, following the extensive modifications at the site, operation on a relatively ``benign`` system is needed before we start on Fischer-Tropsch technology in July. Second, use of shift catalyst in a slurry reactor will enable DOE`s program on coal-based Fischer-Tropsch to encompass commercially available cobalt catalysts-up to now they have been limited to iron-based catalysts which have varying degrees of shift activity. In addition, DOE is supportive of continued fuel testing of LaPorte methanol-tests of MIOO at Detroit Diesel have been going particularly well. LPS offers the opportunity to produce methanol as the catalyst, in the absence of steam, is active for methanol synthesis.

  12. Advanced fuel cell development. Progress report for January--March 1977.

    Energy Technology Data Exchange (ETDEWEB)

    Ackerman, J P; Kinoshita, K; Sim, J W; Swaroop, R; Nelson, P A

    1977-06-01

    Advanced fuel cell research and development activities at Argonne National Laboratory (ANL) during the period January to March 1977 is described. Efforts have been directed toward understanding and improvement of molten carbonate electrolyte fuel cells operating at temperatures near 650/sup 0/C. A primary focus of the work has been on developing electrolyte structures which have high strength and conductivity, as well as good electrolyte retention, and on developing methods of synthesis for electrolyte structures that are amenable to mass production. Several synthesis methods have been investigated, and at least one appears to yield a highly desirable product and to greatly simplify production. Cell testing is essential for understanding and evaluating individual component behavior and the interactions of the components under realistic operating conditions. Most of the testing to date has been conducted in a 2/sup 3///sub 4/-in.-dia cylindrical cell with Type 316 stainless steel housings and current collectors, a nickel anode, and a nickel oxide cathode. Reproducible cell operation has been achieved in these cells, and operational parameters have been brought under control. Necessary improvements in cell components have been defined, and a systematic program of optimization has begun. Components evaluation and development include post-test analysis and evaluation of all the cell components and materials as well as development of out-of-cell diagnostic tests for the individual components. Particular attention is being paid to evaluation of the physical properties of the electrolyte and to corrosion of metallic materials in the cell housings.

  13. Coal fueled diesel system for stationary power applications-technology development

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-08-01

    The use of coal as a fuel for diesel engines dates back to the early days of the development of the engine. Dr. Diesel envisioned his concept as a multi-fuel engine, with coal a prime candidate due to the fact that it was Germany`s primary domestic energy resource. It is interesting that the focus on coal burning diesel engines appears to peak about every twenty years as shortages of other energy resources increase the economic attractiveness of using coal. This periodic interest in coal started in Germany with the work of Diesel in the timeframe 1898-1906. Pawlikowski carried on the work from 1916 to 1928. Two German companies commercialized the technology prior to and during World War II. The next flurry of activity occurred in the United States in the period from 1957-69, with work done at Southwest Research Institute, Virginia Polytechnical University, and Howard University. The current period of activity started in 1978 with work sponsored by the Conservation and Renewable Energy Branch of the US Department of Energy. This work was done at Southwest Research Institute and by ThermoElectron at Sulzer Engine in Switzerland. In 1982, the Fossil Energy Branch of the US Department of Energy, through the Morgantown Energy Technology Center (METC) initiated a concentrated effort to develop coal burning diesel and gas turbine engines. The diesel engine work in the METC sponsored program was performed at Arthur D. Little (Cooper-Bessemer as subcontractor), Bartlesville Energy Technology Center (now NIPER), Caterpillar, Detroit Diesel Corporation, General Motor Corporation (Electromotive Division), General Electric, Southwest Research Institute, and various universities and other research and development organizations. This DOE-METC coal engine RD & D initiative which spanned the 1982-1993 timeframe is the topic of this review document. The combustion of a coal-water fuel slurry in a diesel engine is described. The engine modifications necessary are discussed.

  14. BEAM 1.7: development for modelling fuel element and bundle buckling strength

    Energy Technology Data Exchange (ETDEWEB)

    Cheng, G.; Xu, S.; Xu, Z.; Paul, U.K. [Atomic Energy of Canada, Mississauga, Ontario (Canada)

    2010-07-01

    This paper describes BEAM, an AECL developed computer program, used to assess mechanical integrity of CANDU fuel bundles. The BEAM code has been developed to satisfy the need for buckling strength analysis of fuel bundles. Buckling refers to the phenomenon where a compressive axial load is large enough that a small lateral load can cause large lateral deflections. The buckling strength refers to the critical compressive axial load at which lateral instability is reached. The buckling strength analysis has practical significance for the design of fuel bundles, where the buckling strength of a fuel element/bundle is assessed so that the conditions leading to bundle jamming in the pressure tube are excluded. This paper presents the development and qualification of the BEAM code, with emphasis on the theoretical background and code implementation of the newly developed fuel element/bundle buckling strength model. (author)

  15. DEVELOPMENT OF NOVEL ELECTROCATALYSTS FOR PROTON EXCHANGE MEMBRANE FUEL CELLS

    Energy Technology Data Exchange (ETDEWEB)

    Shamsuddin Ilias

    2003-04-24

    Fuel cells are electrochemical devices that convert the available chemical free energy directly into electrical energy, without going through heat exchange process. Of all different types of fuel cells, the Proton Exchange Membrane Fuel Cell (PEMFC) is one of the most promising power sources for stand-alone utility and electric vehicle applications. Platinum (Pt) Catalyst is used for both fuel and air electrodes in PEMFCs. However, carbon monoxide (CO) contamination of H{sub 2} greatly affects electro catalysts used at the anode of PEMFCs and decreases cell performance. The irreversible poisoning of the anode can occur even in CO concentrations as low as few parts per million (ppm). In this work, we have synthesized several novel elctrocatalysts (Pt/C, Pt/Ru/C, Pt/Mo/C, Pt/Ir and Pt/Ru/Mo) for PEMFCs. These catalysts have been tested for CO tolerance in the H{sub 2}/air fuel cell, using CO concentrations in the H{sub 2} fuel that varies from 10 to 100 ppm. The performance of the electrodes was evaluated by determining the cell potential against current density. The effects of catalyst composition and electrode film preparation method on the performance of PEM fuel cell were also studied. It was found that at 70 C and 3.5 atm pressure at the cathode, Pt-alloy catalyst (10 wt% Pt/Ru/C, 20 wt% Pt/Mo/C) were more CO tolerant than the 20 wt% Pt/C catalyst alone. It was also observed that spraying method was better than the brushing technique for the preparation of electrode film.

  16. ULTRA-LOW SULFUR REDUCTION EMISSION CONTROL DEVICE/DEVELOPMENT OF AN ON-BOARD FUEL SULFUR TRAP

    Energy Technology Data Exchange (ETDEWEB)

    Ron Rohrbach; Gary Zulauf; Tim Gavin

    2003-04-01

    Honeywell is actively working on a 3-year program to develop and demonstrate proof-of-concept for an ''on-vehicle'' desulfurization fuel filter for heavy-duty diesel engines. Integration of the filter into the vehicle fuel system will reduce the adverse effects sulfur has on post combustion emission control devices such as NO{sub x} adsorbers. The NO{sub x} adsorber may be required to meet the proposed new EPA Tier II and ''2007-Rule'' emission standards. The proposed filter concept is based on Honeywell's reactive filtration technology and experience in liquids handling and conditioning. A regeneration and recycling plan for the spent filters will also be examined. We have chosen to develop and demonstrate this technology based on criteria set forth for a heavy duty CIDI engine system because it represents a more challenging set of conditions of service intervals and overall fuel usage over light duty systems. It is anticipated that the technology developed for heavy-duty applications will be applicable to light-duty as well. Further, technology developed under this proposal would also have application for the use of liquid based fuels for fuel cell power generation. The program consists of four phases. Phase I will focus on developing a concept design and analysis and resolution of technical barriers concerning removal of sulfur-containing species in low sulfur fuels. In Phase II we will concentrate on prototype filter design and preparation followed by qualification testing of this component in a fuel line application. Phase III will study life cycle and regeneration options for the spent filter. Phase IV will focus on efficacy and life testing and component integration. The project team will include a number of partners, with Honeywell International as the prime contractor. The partners include an emission control technology developer (Honeywell International), a fuel technology developer (Marathon Ashland Petroleum

  17. A review on the status of development in thorium-based nuclear fuels

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Young Woo; Na, S. H.; Lee, Y. W.; Kim, H. S.; Kim, S. H.; Joung, C.Y

    2000-02-01

    Thorium as an alternative nuclear energy source had been widely investigated in the 1950s-1960s because it is more abundant than uranium, but the studies of thorium nuclear fuel cycle were discontinued by political and economic reasons in the 1970s. Recently, however, renewed interest was vested in thorium-based nuclear fuel cycle because it may generate less long-lived minor actinides and has a lower radiotoxicity of high level wastes after reprocessing compared with the thorium fuel cycle. In this state-of the art report, thorium-based nuclear cycle. In this state-of the art report, thorium-based nuclear fuel cycle and fuel fabrication processes developed so far with different reactor types are reviewed and analyzed to establish basic technologies of thorium fuel fabrication which could meet our situation. (author)

  18. Development of air fuel ratio sensor; A/F sensor no kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    Sakawa, T.; Hori, M. [Denso Corp., Aichi (Japan); Nakamura, Y. [Toyota Motor Corp., Aichi (Japan)

    1997-10-01

    The Air Fuel Ratio Sensor (A/F sensor), which is applied to a 1997 model year Low Emission Vehicle (LEV) was developed. This sensor enables the detection of the exhaust gas air fuel ratio, both lean and rich of stoichiometric. It has an effective air fuel ratio range from 12 to 18 as required for LEV regulation. It has the fast light off, - within 20 seconds - to minimize exhaust hydrocarbon content. Further, it has fast response time, less than 200 msec, to improve the air fuel ratio controllability. 3 refs., 7 figs.

  19. Development of Tools for Treating an Irradiated Fuel Rod Assembly in the Pool of HANARO

    Energy Technology Data Exchange (ETDEWEB)

    Hong, J. T.; Ahn, S. H.; Kim, K. H.; Joung, C. Y. [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

    2013-07-01

    To inspect a fuel rod during irradiation testing at the test loop of a research reactor, the test rig should be disassembled from the IPS (In-pile test section), and the targeted fuel rod assembly should be disassembled from the test rig and encapsulated in a cask to deliver the assembly to the hot cell. In addition, the fuel rod assembly under inspection in the hot cell should be delivered to the reactor pool and reassembled into the test rig to resume the irradiation test. Because the irradiated fuel rod is highly radioactive, all of the assembly and disassembly operations should be carried out in the reactor pool. Therefore, special tools need to be developed to treat the test rig in the pool of a research reactor. In this study, a new mechanically detachable fuel rod assembly has been developed for intermediate inspection during irradiation test at HANARO. A fuel rod assembly can be divided into two parts, such as an instrumented fuel rod assembly and a non-instrumented fuel rod assembly. In particular, an instrumented fuel rod assembly is assembled at the lower part of the test rig, and a non-instrumented fuel rod assembly is assembled at the bottom of the instrumented fuel rod assembly. The non-instrumented fuel rod assembly is locked in the test rig during irradiation test, and is easily disassembled from the instrumented fuel rod assembly by pushing the anchor button and twisting the non-instrumented fuel rod assembly. In addition, because a test rig is 5.4 meters long and the disassembling operation should be carried out at 6 meters deep in the pool of HANARO, tools to help disassemble and assemble the non-instrumented fuel rod assembly have also been developed. All components were designed to operate mechanically and are made of stainless steel and Al 6061 to minimize the effects from the radioactivity. The performance of the developed fuel rod assembly and tools have been verified through an out pile test.

  20. Fuel development for gas-cooled fast reactors

    Science.gov (United States)

    Meyer, M. K.; Fielding, R.; Gan, J.

    2007-09-01

    The Generation IV Gas-cooled Fast Reactor (GFR) concept is proposed to combine the advantages of high-temperature gas-cooled reactors (such as efficient direct conversion with a gas turbine and the potential for application of high-temperature process heat), with the sustainability advantages that are possible with a fast-spectrum reactor. The latter include the ability to fission all transuranics and the potential for breeding. The GFR is part of a consistent set of gas-cooled reactors that includes a medium-term Pebble Bed Modular Reactor (PBMR)-like concept, or concepts based on the Gas Turbine Modular Helium Reactor (GT-MHR), and specialized concepts such as the Very High-Temperature Reactor (VHTR), as well as actinide burning concepts [A Technology Roadmap for Generation IV Nuclear Energy Systems, US DOE Nuclear Energy Research Advisory Committee and the Generation IV International Forum, December 2002]. To achieve the necessary high power density and the ability to retain fission gas at high temperature, the primary fuel concept proposed for testing in the United States is dispersion coated fuel particles in a ceramic matrix. Alternative fuel concepts considered in the US and internationally include coated particle beds, ceramic clad fuel pins, and novel ceramic 'honeycomb' structures. Both mixed carbide and mixed nitride-based solid solutions are considered as fuel phases.

  1. Fuel Cycle Research & Development Technical Monthly - June 2012

    Energy Technology Data Exchange (ETDEWEB)

    Miller, Michael C. [Los Alamos National Laboratory

    2012-07-25

    two papers to the upcoming INMM meeting that are related to the fast neutron multiplicity R&D effort. Progress was made on the project's main goal of designing a concept for a prototype fast-neutron multiplicity counter. We started laying out the outline for the final report. We have been working with our ORNL collaborators to develop a new digitizer system to support our experimental campaign planned for next year. (3) MPACT Analysis Tools - (a) Multi-isotope Process Monitor - Fuel characterization framework development continued during June. A report describing the methodologies is being completed. Kenneth Dayman, from University of Texas, spent a week at PNNL wrapping up his master's research and working on a journal submission covering that work. The target journal is the IEEE transactions on Nuclear Science; submission is planned for the end of July. A proposal to instrument H-Canyon is being prepared in conjunction with SRNL and the NNSA's NGSI program. The impact of gamma-ray spectrum counting statistics on the precision of relative radioisotope component intensities as reconstructed via Principal Component Regression (PCR) continued in June with Monte Carlo simulations of a two-component (i.e., two radioisotope) system. This work generalizes earlier studies in FY12 in which Poisson counting variations of only a single spectrum component were simulated. (b) Modeling and Simulation for Analysis of Safeguards Performance (Electrochemical) - Preliminary insights into safeguards challenges and the initial design for an electrochemical plant have been written up into an INMM paper and will be presented at the INMM Summer Meeting. Work is currently adding a new visualization capability for integrating materials accountancy with physical protection. (c) Material Control including Process Monitoring (Pattern Recognition, Sensors) - Fabrication of quartz chips continued at an external foundry. Awaiting delivery of the heat exchange manifold and chip

  2. Technological research and development of fossil fuels; Ricerca e sviluppo tecnologico per lo sfruttamento ottimale dei combustibili fossili

    Energy Technology Data Exchange (ETDEWEB)

    Minghetti, E.; Palazzi, G. [ENEA, Centro Ricerche Casaccia, Rome (Italy). Dip. Energia

    1995-05-01

    The aim of the present document is to supply general information concerning fossil fuels that represent, today and for the near future, the main energy source of our planet. New fossil fuel technologies are in continual development with two principal goals: to decrease environmental impact and increase transformation process efficiency. Examples of this effort are: (1) gas-steam combined cycles integrated with coal gasification plants, or with pressurized-fluidized-bed combustors; (2) new cycles with humid air or coal direct fired turbine, now under development. In the first part of this document the international and national energy situations and trends are shown. After some brief notes on environment problems and alternative fuels, such as biomasses and municipal wastes, technological aspects, mainly relevant to increasing fossil-fueled power plant performances, are examined in greater depth. Finally the research and technological development activities of ENEA (National Agency for New technologies, Energy and the Environment) Engineering Branch in order to improve fossil fuels energy and environmental use are presented.

  3. AECL/U.S. INERI - Development of Inert Matrix Fuels for Plutonium and Minor Actinide Management in Power Reactors Fuel Requirements and Down-Select Report

    Energy Technology Data Exchange (ETDEWEB)

    William Carmack; Randy Fielding; Pavel Medvedev; Mitch Meyer

    2005-08-01

    This report documents the first milestone of the International Nuclear Energy Research Initiative (INERI) U.S./Euratom Joint Proposal 1.8 entitled “Development of Inert Matrix Fuels for Plutonium and Minor Actinide Management in Light-Water Reactors.” The milestone represents the assessment and preliminary study of a variety of fuels that hold promise as transmutation and minor actinide burning fuel compositions for light-water reactors. The most promising fuels of interest to the participants on this INERI program have been selected for further study. These fuel compositions are discussed in this report.

  4. Advanced fuel cell development. Progress report, April--June 1978. [LiAlO/sub 2/

    Energy Technology Data Exchange (ETDEWEB)

    Ackerman, J. P.; Finn, P. A.; Kinoshita, K.; Kucera, G. H.; Sim, J. W.

    1978-08-01

    Advanced fuel cell research and development activities at Argonne National Laboratory (ANL) during the period April--June 1978 is described. These efforts have been directed toward understanding and improving the components of molten-carbonate-electrolyte fuel cells operated at temperatures near 925/sup 0/K. The primary focus of this work has been the development of electrolyte structures that have good electrolyte retention and mechanical properties as well as long term stability, and on developing methods of synthesis amenable to mass production. The characterization of these structures and their stability is an integral part of this effort. Several synthesis procedures have been developed which yield LiAlO/sub 2/ powders with surface areas of 10 to 20 m/sup 2//g and with particles of submicrometer size. Thermal stability tests on LiAlO/sub 2/ powders have shown that a large increase in LiAlO/sub 2/ particle size accompanies phase transformation from ..cap alpha..- or ..beta..- to ..gamma..-LiAlO/sub 2/. Cell testing is essential for understanding and testing individual and collective component behavior. Several square (10.6 cm x 10.6 cm) have been operated with electrolyte tiles containing ..cap alpha..-LiAlO/sub 2/ to establish a baseline performance for comparison with tiles containing ..beta..- and ..gamma..-LiAlO/sub 2/. In addition, capabilities to measure the thermomechanical behavior of electrolyte tiles have been expanded with the construction of a new test apparatus.

  5. Advanced fuel cell development. Progress Report, April-June 1980. [LiAlO/sub 2/

    Energy Technology Data Exchange (ETDEWEB)

    Pierce, R.D.; Arons, R.M.; Dusek, J.T.; Fraioli, A.V.; Kucera, G.H.; Poeppel, R.B.; Sim, J.W.; Smith, J.L.

    1980-11-01

    Advanced fuel cell research and development activities at Argonne National Laboratory (ANL) during the period April-June 1980 are described. These efforts have been directed toward understanding and improving components of molten carbonate fuel cells and have included operation of a 10-cm square cell. Studies have continued on the development of electrolyte structures (LiAlO/sub 2/ and Li/sub 2/CO/sub 3/-K/sub 2/CO/sub 3/). This effort is being concentrated on the preparation of sintered LiAl0/sub 2/ as electrolyte support. Tape casting is presently under investigation as a method for producing green bodies to be sintered; this technique may be an improvement over cold pressing, which was used in the past to produce green bodies. The transition temperature for the ..beta..- to ..gamma..-LiAlO/sub 2/ allotropic transformation is being determined using differential thermal analysis. Work is continuing on the development of preoxidized, prelithiated NiO cathodes. Two techniques, one of which is simpler than the other, have been developed to fabricate plates of Li/sub 0/ /sub 05/Ni/sub 0/ /sub 95/O. In addition, electroless nickel plating is being investigated as a means of providing corrosion protection to structural hardware. To improve its cell testing capability, ANL has constructed a device for improved resistance measurements by the current-interruption technique.

  6. Bacillus spp. produce antibacterial activities against lactic acid bacteria that contaminate fuel ethanol plants

    Science.gov (United States)

    Lactic acid bacteria (LAB) frequently contaminate commercial fuel ethanol fermentations, reducing yields and decreasing profitability of biofuel production. Microorganisms from environmental sources in different geographic regions of Thailand were tested for antibacterial activity against LAB. Fou...

  7. Convergent development of anodic bacterial communities in microbial fuel cells.

    KAUST Repository

    Yates, Matthew D

    2012-05-10

    Microbial fuel cells (MFCs) are often inoculated from a single wastewater source. The extent that the inoculum affects community development or power production is unknown. The stable anodic microbial communities in MFCs were examined using three inocula: a wastewater treatment plant sample known to produce consistent power densities, a second wastewater treatment plant sample, and an anaerobic bog sediment. The bog-inoculated MFCs initially produced higher power densities than the wastewater-inoculated MFCs, but after 20 cycles all MFCs on average converged to similar voltages (470±20 mV) and maximum power densities (590±170 mW m(-2)). The power output from replicate bog-inoculated MFCs was not significantly different, but one wastewater-inoculated MFC (UAJA3 (UAJA, University Area Joint Authority Wastewater Treatment Plant)) produced substantially less power. Denaturing gradient gel electrophoresis profiling showed a stable exoelectrogenic biofilm community in all samples after 11 cycles. After 16 cycles the predominance of Geobacter spp. in anode communities was identified using 16S rRNA gene clone libraries (58±10%), fluorescent in-situ hybridization (FISH) (63±6%) and pyrosequencing (81±4%). While the clone library analysis for the underperforming UAJA3 had a significantly lower percentage of Geobacter spp. sequences (36%), suggesting that a predominance of this microbe was needed for convergent power densities, the lower percentage of this species was not verified by FISH or pyrosequencing analyses. These results show that the predominance of Geobacter spp. in acetate-fed systems was consistent with good MFC performance and independent of the inoculum source.

  8. Development of structured polymer electrolyte membranes for fuel cell applications

    Science.gov (United States)

    Gasa, Jeffrey

    The objective of this research was to explore structure-property relationships to develop the understanding needed for introduction of superior PEM materials. Polymer electrolyte membranes based on sulfonated poly(ether ketone ketone) (SPEKK) were fabricated using N-methyl pyrrolidone as casting solvent. The membranes were characterized in terms of properties that were relevant to fuel cell applications, such as proton conductivity, methanol permeability, and swelling properties, among others. It was found in this study that the proton conductivity of neat SPEKK membranes could reach the conductivity of commercial membranes such as NafionRTM. However, when the conductivity of SPEKK was comparable to NafionRTM, the swelling of SPEKK in water was quite excessive. The swelling problem was remedied by modifying the microstructure of SPEKK using different techniques. One of them involved blending of lightly sulfonated PEKK with highly acidic particles (sulfonated crosslinked polystyrene-SXLPS). Low sulfonation level of SPEKK was used to reduce the swelling of the membrane in water and the role of the highly acidic particles was to enhance the proton conductivity of the membrane. Because of the residual crystallinity in SPEKK with low sulfonation levels (IEC sulfone)) to act as mechanical reinforcement. It was found that miscibility behavior of the blends had a significant impact on the transport and swelling properties of these blends, which could be explained by the blend microstructure. The miscibility behavior was found to be strongly dependent on the sulfonation level of SPEKK. The conductivities of the blends were enhanced by as much as two orders of magnitude when the morphology was modified by electric field. The last approach was ionic crosslinking of the sulfonate groups in SPEKK using divalent cations, specifically barium ions. The crosslinking treatment has greatly improved the thermal stability of the membranes in both dry and wet conditions.

  9. Development of a 200kW multi-fuel type PAFC power plant

    Energy Technology Data Exchange (ETDEWEB)

    Take, Tetsuo; Kuwata, Yutaka; Adachi, Masahito; Ogata, Tsutomu [NTT Integrated Information & Energy System Labs., Tokyo (Japan)

    1996-12-31

    Nippon Telegraph and Telephone Corporation (NFT) has been developing a 200 kW multi-fuel type PAFC power plant which can generate AC 200 kW of constant power by switching fuel from pipeline town gas to liquefied propane gas (LPG) and vice versa. This paper describes the outline of the demonstration test plant and test results of its fundamental characteristics.

  10. Development of Improved Models and Designs for Coated-Particle Gas Reactor Fuels (I-NERI Annual Report)

    Energy Technology Data Exchange (ETDEWEB)

    Petti, David Andrew; Maki, John Thomas; Languille, Alain; Martin, Philippe; Ballinger, Ronald

    2002-11-01

    The objective of this INERI project is to develop improved fuel behavior models for gas reactor coated particle fuels and to develop improved coated-particle fuel designs that can be used reliably at very high burnups and potentially in fast gas-cooled reactors. Thermomechanical, thermophysical, and physiochemical material properties data were compiled by both the US and the French and preliminary assessments conducted. Comparison between U.S. and European data revealed many similarities and a few important differences. In all cases, the data needed for accurate fuel performance modeling of coated particle fuel at high burnup were lacking. The development of the INEEL fuel performance model, PARFUME, continued from earlier efforts. The statistical model being used to simulate the detailed finite element calculations is being upgraded and improved to allow for changes in fuel design attributes (e.g. thickness of layers, dimensions of kernel) as well as changes in important material properties to increase the flexibility of the code. In addition, modeling of other potentially important failure modes such as debonding and asphericity was started. A paper on the status of the model was presented at the HTR-2002 meeting in Petten, Netherlands in April 2002, and a paper on the statistical method was submitted to the Journal of Nuclear Material in September 2002. Benchmarking of the model against Japanese and an older DRAGON irradiation are planned. Preliminary calculations of the stresses in a coated particle have been calculated by the CEA using the ATLAS finite element model. This model and the material properties and constitutive relationships will be incorporated into a more general software platform termed Pleiades. Pleiades will be able to analyze different fuel forms at different scales (from particle to fuel body) and also handle the statistical variability in coated particle fuel. Diffusion couple experiments to study Ag and Pd transport through SiC were

  11. The development of rock suitability classification strategies in the Finnish spent nuclear fuel disposal program

    Energy Technology Data Exchange (ETDEWEB)

    Hellae, Pirjo; Hagros, Annika [Saanio and Riekkola Oy (Finland); Aaltonen, Ismo; Kosunen, Paula; Mattila, Jussi [Posiva Oy (Finland)

    2015-07-01

    This paper describes the development of the rock suitability classification strategies applied to locate the spent fuel repository in crystalline rock in Finland. Development of the classification procedure is motivated not only by the regulatory requirements, but also by the need to more closely integrate site characterization, repository design and long-term safety assessment. The classification procedure has been developed along with the increasing level of detail of the available site data and knowledge on the performance of the engineered barrier system (EBS). The classification system has also been adapted to the changes in the regulations. The present form of the classification system and experiences from testing the system at the site are described. Demonstration activities have shown that the criteria and the stepwise research, construction and decision making protocol can be applied successfully.

  12. Regulatory Technology Development Plan - Sodium Fast Reactor. Mechanistic Source Term - Metal Fuel Radionuclide Release

    Energy Technology Data Exchange (ETDEWEB)

    Grabaskas, David [Argonne National Lab. (ANL), Argonne, IL (United States); Bucknor, Matthew [Argonne National Lab. (ANL), Argonne, IL (United States); Jerden, James [Argonne National Lab. (ANL), Argonne, IL (United States)

    2016-02-01

    The development of an accurate and defensible mechanistic source term will be vital for the future licensing efforts of metal fuel, pool-type sodium fast reactors. To assist in the creation of a comprehensive mechanistic source term, the current effort sought to estimate the release fraction of radionuclides from metal fuel pins to the primary sodium coolant during fuel pin failures at a variety of temperature conditions. These release estimates were based on the findings of an extensive literature search, which reviewed past experimentation and reactor fuel damage accidents. Data sources for each radionuclide of interest were reviewed to establish release fractions, along with possible release dependencies, and the corresponding uncertainty levels. Although the current knowledge base is substantial, and radionuclide release fractions were established for the elements deemed important for the determination of offsite consequences following a reactor accident, gaps were found pertaining to several radionuclides. First, there is uncertainty regarding the transport behavior of several radionuclides (iodine, barium, strontium, tellurium, and europium) during metal fuel irradiation to high burnup levels. The migration of these radionuclides within the fuel matrix and bond sodium region can greatly affect their release during pin failure incidents. Post-irradiation examination of existing high burnup metal fuel can likely resolve this knowledge gap. Second, data regarding the radionuclide release from molten high burnup metal fuel in sodium is sparse, which makes the assessment of radionuclide release from fuel melting accidents at high fuel burnup levels difficult. This gap could be addressed through fuel melting experimentation with samples from the existing high burnup metal fuel inventory.

  13. Fuel Efficient Diesel Particulate Filter (DPF) Modeling and Development

    Energy Technology Data Exchange (ETDEWEB)

    Stewart, Mark L.; Gallant, Thomas R.; Kim, Do Heui; Maupin, Gary D.; Zelenyuk, Alla

    2010-08-01

    The project described in this report seeks to promote effective diesel particulate filter technology with minimum fuel penalty by enhancing fundamental understanding of filtration mechanisms through targeted experiments and computer simulations. The overall backpressure of a filtration system depends upon complex interactions of particulate matter and ash with the microscopic pores in filter media. Better characterization of these phenomena is essential for exhaust system optimization. The acicular mullite (ACM) diesel particulate filter substrate is under continuing development by Dow Automotive. ACM is made up of long mullite crystals which intersect to form filter wall framework and protrude from the wall surface into the DPF channels. ACM filters have been demonstrated to effectively remove diesel exhaust particles while maintaining relatively low backpressure. Modeling approaches developed for more conventional ceramic filter materials, such as silicon carbide and cordierite, have been difficult to apply to ACM because of properties arising from its unique microstructure. Penetration of soot into the high-porosity region of projecting crystal structures leads to a somewhat extended depth filtration mode, but with less dramatic increases in pressure drop than are normally observed during depth filtration in cordierite or silicon carbide filters. Another consequence is greater contact between the soot and solid surfaces, which may enhance the action of some catalyst coatings in filter regeneration. The projecting crystals appear to provide a two-fold benefit for maintaining low backpressures during filter loading: they help prevent soot from being forced into the throats of pores in the lower porosity region of the filter wall, and they also tend to support the forming filter cake, resulting in lower average cake density and higher permeability. Other simulations suggest that soot deposits may also tend to form at the tips of projecting crystals due to the axial

  14. Development of Army Fire-Resistant Diesel Fuel.

    Science.gov (United States)

    1979-12-01

    The prime FRF candidates have comprised diesel fuel with either 10 percent water and 6 percent emulsifier (FRF-A), or 5 percent water, 3 percent...SOURI * Il SOURCE CANVAS I INVESTIGATE SCREENIT WTERT- ERDO FRULANDO COMPOSITION EFFECTSIWTERHNSOURESOFOMLTN LAOATR AND AECHDI-AC I IEEFCSSCE F L-AIIY

  15. Power generation using an activated carbon and metal mesh cathode in a microbial fuel cell

    KAUST Repository

    Zhang, Fang

    2009-11-01

    An inexpensive activated carbon (AC) air cathode was developed as an alternative to a platinum-catalyzed electrode for oxygen reduction in a microbial fuel cell (MFC). AC was cold-pressed with a polytetrafluoroethylene (PTFE) binder to form the cathode around a Ni mesh current collector. This cathode construction avoided the need for carbon cloth or a metal catalyst, and produced a cathode with high activity for oxygen reduction at typical MFC current densities. Tests with the AC cathode produced a maximum power density of 1220 mW/m2 (normalized to cathode projected surface area; 36 W/m3 based on liquid volume) compared to 1060 mW/m2 obtained by Pt catalyzed carbon cloth cathode. The Coulombic efficiency ranged from 15% to 55%. These findings show that AC is a cost-effective material for achieving useful rates of oxygen reduction in air cathode MFCs. © 2009 Elsevier B.V. All rights reserved.

  16. Development of the vibration analysis technique of fuel rod and research on the methodology of fuel fretting wear analysis

    Energy Technology Data Exchange (ETDEWEB)

    Kang, Heung Seok; Kim, Kyung Kyu; Yoon, Hyung Hoo; Song, Ki Nam

    1998-12-01

    The FEM program has been developed to predict the natural frequencies, the FEM program has been developed to predict the natural frequencies, and mode shapes of fuel rod subjected to axial force and continuously supported by a rotational and vent spring system, and to calculate the minimum reaction forces of the spacer grid spring when the maximum vibration amplitude of fuel rod is known. This program has been verified by commercial ANSYS program and the vibration test of dummy rods in air. The test equipment were set to get the fifth modes of test rods. Partial slip problem has been studied for the analysis of fuel fretting problem. Firstly, the assumption of semi-infiniteness of the contact bodies were validated by finite element (FE) analysis. From FE results, a classical bodies were validated by finite element (FE) analysis. From FE results, aclassical theory of elasticity was utilized with regarding the problem as a plane problem. Secondly, the Mindlin-Cattaneo problem was re-evaluated, which gave the fundamental idea for developing the numerical tool for the shear traction on the contact. Shear force of sequentially-changing directions was considered and the corresponding shear traction was evaluated by extending the numerical tool for the Mindlin-Cattaneo problem.

  17. Development of the thermal behavior analysis code DIRAD and the fuel design procedure for LMFBR

    Science.gov (United States)

    Nakae, N.; Tanaka, K.; Nakajima, H.; Matsumoto, M.

    1992-06-01

    It is very important to increase the fuel linear heat rating for improvement of economy in LMFBR without any degradation in safety. A reduction of the design margin is helpful to achieve the high power operation. The development of a fuel design code and a design procedure is effective on the reduction of the design margin. The thermal behavior analysis code DIRAD has been developed with respect to fuel restructuring and gap conductance models. These models have been calibrated and revised using irradiation data of fresh fuel. It is, therefore, found that the code is applicable for the thermal analysis with fresh fuel. The uncertainties in fuel irradiation condition and fuel fabrication tolerance together with the uncertainty of the code prediction have major contributions to the design margin. In the current fuel design the first two uncertainties independently contribute to temperature increment. Another method which can rationally explain the effect of the uncertainties on the temperature increment is adopted here. Then, the design margin may be rationally reduced.

  18. Subtask 3.4 - Fischer - Tropsch Fuels Development

    Energy Technology Data Exchange (ETDEWEB)

    Strege, Joshua; Snyder, Anthony; Laumb, Jason; Stanislowski, Joshua; Swanson, Michael

    2012-05-01

    Under Subtask 3.4, the Energy & Environmental Research Center (EERC) examined the opportunities and challenges facing FischerTropsch (FT) technology in the United States today. Work was completed in two distinct budget periods (BPs). In BP1, the EERC examined the technical feasibility of using modern warm-gas cleanup techniques for FT synthesis. FT synthesis is typically done using more expensive and complex cold-gas sweetening. Warm-gas cleanup could greatly reduce capital and operating costs, making FT synthesis more attractive for domestic fuel production. Syngas was generated from a variety of coal and biomass types; cleaned of sulfur, moisture, and condensables; and then passed over a pilot-scale FT catalyst bed. Laboratory and modeling work done in support of the pilot-scale effort suggested that the catalyst was performing suboptimally with warm-gas cleanup. Long-term trends showed that the catalyst was also quickly deactivating. In BP3, the EERC compared FT catalyst results using warm-gas cleanup to results using cold-gas sweetening. A gas-sweetening absorption system (GSAS) was designed, modeled, and constructed to sweeten syngas between the gasifier and the pilot-scale FT reactor. Results verified that the catalyst performed much better with gas sweetening than it had with warm-gas cleanup. The catalyst also showed no signs of rapid deactivation when the GSAS was running. Laboratory tests in support of this effort verified that the catalyst had deactivated quickly in BP1 because of exposure to syngas, not because of any design flaw with the pilot-scale FT reactor itself. Based on these results, the EERC concludes that the two biggest issues with using syngas treated with warm-gas cleanup for FT synthesis are high concentrations of CO{sub 2} and volatile organic matter. Other catalysts tested by the EERC may be more tolerant of CO{sub 2}, but volatile matter removal is critical to ensuring long-term FT catalyst operation. This subtask was funded through

  19. Review of ALARA plan for activities at the 105 K-East fuel storage basin

    Energy Technology Data Exchange (ETDEWEB)

    Vargo, G.J.; Durham, J.S.; Hickey, E.E.; Stansbury, P.S.; Cicotte, G.R.

    1994-09-01

    As part of its ongoing efforts to reduce doses to workers to levels as low as reasonably achievable (ALARA), Westinghouse Hanford Company (WHC) tasked the Health Protection Department of the Pacific Northwest Laboratory (PNL) to review operations at the 105 K-East Fuel Storage Basin (105 K-East). This review included both routine operations and a proposed campaign to encapsulate N-Reactor fuel stored there. This report summarizes the results of PNL`s reviews of policy, procedures, and practices for operations at 105 K-East as well as an evaluation of the major sources of occupational radiation exposures. Where possible, data previously collected by WHC and its predecessors were used. In addition, PNL staff developed a three-dimensional model of the radiological environment within 105 K-East to assess the relative contributions of different radiation sources to worker dose and to provide a decision tool for use in evaluating alternative methods of dose rate reduction. The model developed by PNL indicates that for most areas in the basin the primary source of occupational radiation exposure is the contaminated concrete surfaces of the basin near the waterline. Basin cooling water piping represents a significant source in a number of areas, particularly the Technical Viewing Pit. This report contains specific recommendations to reduce the impact of these sources of occupational radiation exposure in 105 K-East. Other recommendations to reduce doses to workers during activities such as filter changes and filter sampling are also included.

  20. Annual report of Power Reactor and Nuclear Fuel Development Corporation, fiscal year 1994

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-09-01

    This was the Annual Report of the Power Reactor and Nuclear Fuel Development Corporation, Fiscal Year of 1994. In this report, the following 12 items are described: (1) Development of the fast breeding reactor; (a) operation of the fast experimental reactor, `Joyo`, (b) construction and trial operation of the fast breeding prototype reactor, `Monju`, and (c) R and D of FBR; (2) Development of the new type conversion reactor; (a) operation of prototype reactor, `Fugen`, and (b) R and D of ATR; (3) Development of uranium mining and conversion; (4) Development of uranium concentration technology; (5) Development of plutonium fuel; (a) preparation of the MOX fuel, (b) preparation facility construction of the MOX fuel, (c) R and D of plutonium fuel. and (d) technical development of plutonium mixing and conversion; (6) Reprocessing of spent fuel; (7) Environmental technology development of radioactive waste; (8) Creative and innovative R and D; (9) Management and nuclear non-proliferation countermeasure of nuclear matter; (10) Safety management and safety study; (11) Related common business; and (12) General management business. (G.K.)

  1. HTGR fuels and core development program. Quarterly progress report for the period ending November 30, 1977. [Graphite and fuel irradiation; fission product release

    Energy Technology Data Exchange (ETDEWEB)

    1977-12-01

    The work reported here includes studies of basic fission product transport mechanisms, core graphite development and testing, and the development and testing of recyclable fuel systems. Materials studied include irradiation capsule tests of both fuel and graphite. Experimental procedures and results are discussed and data are presented.

  2. Idaho Chemical Processing Plant spent fuel and waste management technology development program plan: 1994 Update

    Energy Technology Data Exchange (ETDEWEB)

    1994-09-01

    The Department of Energy has received spent nuclear fuel (SNF) at the Idaho Chemical Processing Plant (ICPP) for interim storage since 1951 and reprocessing since 1953. Until April 1992, the major activity of the ICPP was the reprocessing of SNF to recover fissile uranium and the management of the resulting high-level wastes (HLW). In 1992, DOE chose to discontinue reprocessing SNF for uranium recovery and shifted its focus toward the continued safe management and disposition of SNF and radioactive wastes accumulated through reprocessing activities. Currently, 1.8 million gallons of radioactive liquid wastes (1.5 million gallons of radioactive sodium-bearing liquid wastes and 0.3 million gallons of high-level liquid waste), 3,800 cubic meters of calcine waste, and 289 metric tons heavy metal of SNF are in inventory at the ICPP. Disposal of SNF and high-level waste (HLW) is planned for a repository. Preparation of SNF, HLW, and other radioactive wastes for disposal may include mechanical, physical, and/or chemical processes. This plan outlines the program strategy of the ICPP spent Fuel and Waste Management Technology Development Program (SF&WMTDP) to develop and demonstrate the technology required to ensure that SNF and radioactive waste will be properly stored and prepared for final disposal in accordance with regulatory drivers. This Plan presents a brief summary of each of the major elements of the SF&WMTDP; identifies key program assumptions and their bases; and outlines the key activities and decisions that must be completed to identify, develop, demonstrate, and implement a process(es) that will properly prepare the SNF and radioactive wastes stored at the ICPP for safe and efficient interim storage and final disposal.

  3. Alternative-fueled truck demonstration natural gas program: Caterpillar G3406LE development and demonstration

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-06-01

    In 1990, the California Energy Commission, the South Coast Air Quality Management District, and the Southern California Gas Company joined together to sponsor the development and demonstration of compressed natural gas engines for Class 8 heavy-duty line-haul trucking applications. This program became part of an overall Alternative-Fueled Truck Demonstration Program, with the goal of advancing the technological development of alternative-fueled engines. The demonstration showed natural gas to be a technically viable fuel for Class 8 truck engines.

  4. Industrial experience on the development of the molten carbonate fuel cell technology

    Energy Technology Data Exchange (ETDEWEB)

    Bosio, B.; Costamagna, P. [Ist. di Ingegneria Chimica e di Processo ``G.B. Bonino`` Univ. di Genova (Italy); Parodi, F.; Passalacqua, B. [Ansaldo Ricerche, Genova (Italy)

    1998-08-01

    The development of the molten carbonate fuel cell (MCFC) technology at Ansaldo Ricerche (ARI) is reported, starting from small scale single cells up to stacks of several kW capacity. The evolution of material and fabrication strategies as well as the progress in terms of electrical performance are described and discussed. The data reported show that the MCFC technology has been successfully tested on stacks in the kW power class, however some problems still need to be solved to improve the stack performance. In particular, better control of the start-up phase, of electrolyte migration through the manifolds and of the gas feed distribution are required, based on the latest experimental data on a 50 cell stack with cell area 0.1 m{sup 2} (cell active area 0.0702 m{sup 2}), which operated for 780 h with a maximum performance of 4 kW at 206 mA/cm{sup 2} at 50% fuel utilisation. Future development steps, which will lead to the realisation and operation of systems of several hundred kW, are presented. (orig.)

  5. Development and Experimental Research of kW-scale Molten Carbonate Fuel Cells

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    A kW-scale molten carbonate fuel cells stack was developed and 800-hours' operating test and performance experimental research had been done. Utilizing domestic materials completely, we developed NiO cathode and Ni-Al anode with the active area of 336cm2 and Υ-LiAlO2 electrolyte tile and bipolar plate with the area of 900cm2. The stack was composed of thirty cells, with 62%Li2CO3+38%K2CO3 as its electrolyte. During the 800 hours' continuous operating, the performance of the stack was stable. With 99.7%(mole fraction) H2 as fuel and O2 from air as oxidant, the average operating voltage of a cell was about 0.72 V. The maximal current density attained to 165mA/cm2, and the maximal output power attained to 1080 Watt. The whole performance of the stack approached to the international level in the early 90's. This paper gives the main works and experiments results.

  6. Development of a 10 kW PEM fuel cell for stationary applications

    Energy Technology Data Exchange (ETDEWEB)

    Barthels, H.; Mergel, J.; Oetjen, H.F. [Institute fuer Energieverfahrenstechnik (IEV), Juelich (Germany)] [and others

    1996-12-31

    A 10 kW Proton Exchange Membrane Fuel Cell (PEMFC) is being developed as part of a long-term energy storage path for electricity in the photovoltaic demonstration plant called PHOEBUS at the Forschungszentrum Julich.

  7. Competition and alliances in fuel cell power train development

    Energy Technology Data Exchange (ETDEWEB)

    Schlecht, L. [Technische Universitaet Berlin (Germany). Fuel Cell and Hydrogen Research Centre

    2003-07-01

    For the realisation of the effective application and cost effectiveness of fuel cell power trains, and competitiveness with the current internal combustion engine technology, it will be necessary to either: (a) produce a large number of vehicles, (b) reduce the production costs by permanent production optimisation, or (c) introduce new materials. Learning curves, which have been derived from empirical data of past energy technologies, are initially used to provide a cost prognosis for the market launch of fuel cell power trains. Drawing on game theory the paper then describes a basic model which addresses the issue of the optimal strategy of the automotive industry, in either a monopoly or oligopoly structure. When this model's outputs are combined with the anticipated rate of fuel cell vehicles (FCVs), learning curves and network effects, from the first section of the paper we can see that if the successful market launch of FCVs is desired, an alliance structure within the automotive industry is the optimal path. (author)

  8. Overview of the United States department of energy's used fuel disposition research and development campaign

    Energy Technology Data Exchange (ETDEWEB)

    Nutt, Mark [Argonne National Laboratory, Argonne, IL (United States); Swift, Peter; MacKinnon, Robert; McMahon, Kevin; Sorenson, Ken [Sandia National Laboratories, Albuquerque NM (United States); Birkholzer, Jens [Lawrence Berkeley National Laboratory, Berkeley, CA (United States); Boyle, William; Gunter, Timothy; Larson, Ned [U.S. Department of Energy, Las Vegas, NV (United States)

    2013-07-01

    The United States Department of Energy (US DOE) is conducting research and development (R and D) activities within the Used Fuel Disposition Campaign (UFDC) to support storage, transportation, and disposal of used nuclear fuel (UNF) and wastes generated by existing and future nuclear fuel cycles. R and D activities are ongoing at nine national laboratories, and are divided into two major topical areas: (1) storage and transportation research, and (2) disposal research. Storage R and D focuses on closing technical gaps related to extended storage of UNF. For example, uncertainties remain regarding high-burnup nuclear fuel cladding performance following possible hydride reorientation and creep deformation, and also regarding long-term canister integrity. Transportation R and D focuses on ensuring transportability of UNF following extended storage, addressing data gaps regarding nuclear fuel integrity, retrievability, and demonstration of subcriticality. Disposal R and D focuses on identifying multiple viable geologic disposal options and addressing technical challenges for generic disposal concepts in various host media (e.g., mined repositories in salt, clay/shale, and granitic rocks, and deep borehole disposal in crystalline rock). R and D will transition to site-specific challenges as national policy advances. R and D goals at this stage are to increase confidence in the robustness of generic disposal concepts, to reduce generic sources of uncertainty that may impact the viability of disposal concepts, and to develop science and engineering tools that will support the selection, characterization, and ultimately licensing of a repository. The US DOE has also initiated activities that can be conducted within the constraints of the Nuclear Waste Policy Act to facilitate the development of an interim storage facility and supporting transportation infrastructure. (authors)

  9. Development Status of Accident-tolerant Fuel for Light Water Reactors in Korea

    OpenAIRE

    Hyun-Gil Kim; Jae-Ho Yang; Weon-Ju Kim; Yang-Hyun Koo

    2016-01-01

    For a long time, a top priority in the nuclear industry was the safe, reliable, and economic operation of light water reactors. However, the development of accident-tolerant fuel (ATF) became a hot topic in the nuclear research field after the March 2011 events at Fukushima, Japan. In Korea, innovative concepts of ATF have been developing to increase fuel safety and reliability during normal operations, operational transients, and also accident events. The microcell UO2 and high-density compo...

  10. Development of breached pin performance analysis code SAFFRON (System of Analyzing Failed Fuel under Reactor Operation by Numerical method)

    Energy Technology Data Exchange (ETDEWEB)

    Ukai, Shigeharu [Power Reactor and Nuclear Fuel Development Corp., Oarai, Ibaraki (Japan). Oarai Engineering Center

    1995-03-01

    On the assumption of fuel pin failure, the breached pin performance analysis code SAFFRON was developed to evaluate the fuel pin behavior in relation to the delayed neutron signal response during operational mode beyond the cladding failure. Following characteristic behavior in breached fuel pin is modeled in 3-dimensional finite element method : pellet swelling by fuel-sodium reaction, fuel temperature change, and resultant cladding breach extension and delayed neutron precursors release into coolant. Particularly, practical algorithm of numerical procedure in finite element method was originally developed in order to solve the 3-dimensional non-linear contact problem between the swollen pellet due to fuel-sodium reaction and breached cladding. (author).

  11. Work activities within sustainable development

    Directory of Open Access Journals (Sweden)

    Francisco Duarte

    2015-06-01

    Full Text Available This paper presents the main results of a Franco-Brazilian Research project entitled "Work, Innovation and Development". The aim is to conceptually consider work activity within sustainable development, and to contribute methodologically towards developing strategies for designing sustainable work systems. After a brief description of the factors and the dimensions that have contributed to the creation of ideas on sustainable development, we will put forward two main approaches for understanding work activity within the context of sustainability, these being: the durability of work activity and the development of work activities for sustainable development. Both approaches are presented and examples are given. This is followed by a discussion of the design of sustainable work systems that focuses particularly on the political and technical dimensions of project management.

  12. Development and verification of fuel burn-up calculation model in a reduced reactor geometry

    Energy Technology Data Exchange (ETDEWEB)

    Sembiring, Tagor Malem [Center for Reactor Technology and Nuclear Safety (PTKRN), National Nuclear Energy Agency (BATAN), Kawasan PUSPIPTEK Gd. No. 80, Serpong, Tangerang 15310 (Indonesia)], E-mail: tagorms@batan.go.id; Liem, Peng Hong [Research Laboratory for Nuclear Reactor (RLNR), Tokyo Institute of Technology (Tokyo Tech), O-okayama, Meguro-ku, Tokyo 152-8550 (Japan)

    2008-02-15

    A fuel burn-up model in a reduced reactor geometry (2-D) is successfully developed and implemented in the Batan in-core fuel management code, Batan-FUEL. Considering the bank mode operation of the control rods, several interpolation functions are investigated which best approximate the 3-D fuel assembly radial power distributions across the core as function of insertion depth of the control rods. Concerning the applicability of the interpolation functions, it can be concluded that the optimal coefficients of the interpolation functions are not very sensitive to the core configuration and core or fuel composition in RSG GAS (MPR-30) reactor. Consequently, once the optimal interpolation function and its coefficients are derived then they can be used for 2-D routine operational in-core fuel management without repeating the expensive 3-D neutron diffusion calculations. At the selected fuel elements (at H-9 and G-6 core grid positions), the discrepancy of the FECFs (fuel element channel power peaking factors) between the 2-D and 3-D models are within the range of 3.637 x 10{sup -4}, 3.241 x 10{sup -4} and 7.556 x 10{sup -4} for the oxide, silicide cores with 250 g {sup 235}U/FE and the silicide core with 300 g {sup 235}U/FE, respectively.

  13. Development of Welding and Instrumentation Technology for Nuclear Fuel Test Rod

    Energy Technology Data Exchange (ETDEWEB)

    Joung, Chang Young; Ahn, Sung Ho; Heo, Sung Ho; Hong, Jin Tae; Kim, Ka Hye [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

    2013-10-15

    It is necessary to develop various types of welding, instrumentation and helium gas filling techniques that can conduct TIG spot welding exactly at a pin-hole of the end-cap on the nuclear fuel rod to fill up helium gas. The welding process is one of the most important among the instrumentation processes of the nuclear fuel test rod. To manufacture the nuclear fuel test rod, a precision welding system needs to be fabricated to develop various welding technologies of the fuel test rod jointing the various sensors and end-caps on a fuel cladding tube, which is charged with fuel pellets and component parts. We therefore designed and fabricated an orbital TIG welding system and a laser welding system. This paper describes not only some experiment results from weld tests for the parts of a nuclear fuel test rod, but also the contents for the instrumentation process of the dummy fuel test rod installed with the C-type T. C. A dummy nuclear fuel test rod was successfully fabricated with the welding and instrumentation technologies acquired with various tests. In the test results, the round welding has shown a good weldability at both the orbital TIG welding system and the fiber laser welding system. The spot welding to fill up helium gas has shown a good welding performance at a welding current of 30A, welding time of 0.4 sec and gap of 1 mm in a helium gas atmosphere. The soundness of the nuclear fuel test rod sealed by a mechanical sealing method was confirmed by helium leak tests and microstructural analyses.

  14. Spent fuel treatment and mineral waste form development at Argonne National Laboratory-West

    Energy Technology Data Exchange (ETDEWEB)

    Goff, K.M.; Benedict, R.W.; Bateman, K. [Argonne National Lab., Idaho Falls, ID (United States); Lewis, M.A.; Pereira, C. [Argonne National Lab., IL (United States); Musick, C.A. [Lockheed Idaho Technologies Co., Idaho Falls, ID (United States)

    1996-07-01

    At Argonne National Laboratory-West (ANL-West) there are several thousand kilograms of metallic spent nuclear fuel containing bond sodium. This fuel will be treated in the Fuel Conditioning Facility (FCF) at ANL-West to produce stable waste forms for storage and disposal. Both mineral and metal high-level waste forms will be produced. The mineral waste form will contain the active metal fission products and the transuranics. Cold small-scale waste form testing has been on-going at Argonne in Illinois. Large-scale testing is commencing at ANL-West.

  15. Bifunctional activation of a direct methanol fuel cell

    Science.gov (United States)

    Kulikovsky, A. A.; Schmitz, H.; Wippermann, K.; Mergel, J.; Fricke, B.; Sanders, T.; Sauer, D. U.

    We report a novel method for performance recovery of direct methanol fuel cells. Lowering of air flow rate below a critical value turns the cell into bifunctional regime, when the oxygen-rich part of the cell generates current while the rest part works in electrolysis mode (electrolytic domain). Upon restoring the normal (super-critical) air flow rate, the galvanic performance of the electrolytic domain increases. This recovery effect is presumably attributed to Pt surface cleaning on the cathode with the simultaneous increase in catalyst utilization on the anode.

  16. Development of operational criteria for the interim spent fuel storage facility

    Energy Technology Data Exchange (ETDEWEB)

    Kim, M. H.; Kim, J. C.; Kim, D. K.; Cho, D. K.; Bae, K. M. [Kyunghee Univ., Seoul (Korea, Republic of)

    1997-03-15

    The final objective is to develop the technical criteria for the facility operation of the interim spent fuel storage facility. For this purpose, elementary technical issues are evaluated for the wet storage of spent fuels and status of operation in foreign counties are examined. Urgent objective of this study is to provide technical back data for the development of operational criteria. For the back data for the development of operational criteria, domestic technical data for the wet storages are collected as well as standards and criteria related to the spent fuel storage. Operational stutus of spent fuel storages in foreign countries CLAB in Sweden and MRS in the United States are studied. Dry storage concept is also studied in order to find the characteristics of wet storage concept. Also basic technical issues are defined and studied in order to build a draft of operational criteri00.

  17. SOLVENT EXTRACTION RESEARCH AND DEVELOPMENT IN THE U.S. FUEL CYCLE PROGRAM

    Energy Technology Data Exchange (ETDEWEB)

    Terry A. Todd

    2011-10-01

    Treatment or processing of used nuclear fuel to recycle uranium and plutonium has historically been accomplished using the well known PUREX process. The PUREX process has been used on an industrial scale for over 60 years in the nuclear industry. Research is underway to develop advanced separation methods for the recovery of other used fuel components, such as the minor actinides (Np, Am, Cm) for possible transmutation in fast spectrum reactors, or other constituents (e.g. Cs, Sr, transition metals, lanthanides) to help facilitate effective waste management options. This paper will provide an overview of new solvent extraction processes developed for advanced nuclear fuel cycles, and summarize recent experimental results. This will include the utilization of new extractants for selective separation of target metals and new processes developed to selectively recover one or more elements from used fuel.

  18. Development of an empirical dynamic model for a Nexa PEM fuel cell power module

    Energy Technology Data Exchange (ETDEWEB)

    Soltani, Mehdi; Mohammad Taghi Bathaee, S. [Power Systems Laboratory, Department of Electrical Engineering, K.N. Toosi University of Technology, 16317-14191 Tehran (Iran)

    2010-12-15

    The goal of this study is to develop a fuel cell model which is capable of characterizing fuel cell steady-state performance as well as dynamic behavior. In this paper a new dynamic model of a 1.2 kW Polymer Electrolyte Membrane Fuel Cell (PEMFC) is developed and validated through a series of experiments. The experimental results have been obtained from a Nexa trademark PEM fuel cell power module under different load conditions. Based on this model, a simulator software package has been developed using the MATLAB {sup registered} and Simulink {sup registered} software and simulation results have been carried out. The proposed model exhibits good agreement with experiment results in steady-state and dynamic performance. (author)

  19. Engineering interface and surface of noble metal nanoparticle nanotubes toward enhanced catalytic activity for fuel cell applications.

    Science.gov (United States)

    Cui, Chun-Hua; Yu, Shu-Hong

    2013-07-16

    In order for fuel cells to have commercial viability as alternative fuel sources, researchers need to develop highly active and robust fuel cell electrocatalysts. In recent years, the focus has been on the design and synthesis of novel catalytic materials with controlled interface and surface structures. Another goal is to uncover potential catalytic activity and selectivity, as well as understand their fundamental catalytic mechanisms. Scientists have achieved great progress in the experimental and theoretical investigation due to the urgent demand for broad commercialization of fuel cells in automotive applications. However, there are still three main problems: cost, performance, and stability. To meet these targets, the catalyst needs to have multisynergic functions. In addition, the composition and structure changes of the catalysts during the reactions still need to be explored. Activity in catalytic nanomaterials is generally controlled by the size, shape, composition, and interface and surface engineering. As such, one-dimensional nanostructures such as nanowires and nanotubes are of special interest. However, these structures tend to lose the nanoparticle morphology and inhibit the use of catalysts in both fuel cell anodes and cathodes. In 2003, Rubinstein and co-workers proposed the idea of nanoparticle nanotubes (NNs), which combine the geometry of nanotubes and the morphology of nanoparticles. This concept gives both the high surface-to-volume ratio and the size effect, which are both appealing in electrocatalyst design. In this Account, we describe our developments in the construction of highly active NNs with unique surface and heterogeneous interface structures. We try to clarify enhanced activity and stability in catalytic systems by taking into account the activity impact factors. We briefly introduce material structural effects on the electrocatalytic reactivity including metal oxide/metal and metal/metal interfaces, dealloyed pure Pt, and mixed Pt

  20. In-use measurement of the activity, fuel use, and emissions of front-loader refuse trucks

    Science.gov (United States)

    Sandhu, Gurdas S.; Frey, H. Christopher; Bartelt-Hunt, Shannon; Jones, Elizabeth

    2014-08-01

    Field measurements were made for six front-loader refuse trucks for over 560 miles (901 km) and 47 h of operation using a portable emissions measurement system, electronic control unit data logger, and global positioning system receivers. Daily activity, fuel use rates, and emission rates are quantified in terms of operating mode bins defined by the U.S. Environmental Protection Agency for the MOVES emission factor model. On average, 44 (±4) percent of time was spent at idle, 5 (±1) percent braking or decelerating, 11 (±2) percent coasting, 23 (±3) percent cruising or accelerating at low speed (up to 25 mph, 40.2 kmph), 10 (±2) percent cruising or accelerating at moderate speed (25-50 mph, 40.2 to 80.4 kmph), and 7 (±3) percent cruising or accelerating at high speed (50 mph, 80.4 kmph or higher). Fuel use and emission rates varied among operating modes by factors of 6-24. The estimated daily activity cycle average fuel economy ranges from 2.3 to 3.2 mpg (0.98-1.4 kmpl). The PM emission rates for trucks with diesel particulate filters are 98 percent lower compared to those without. Variation in truck weight lead to differences in average fuel use and emission rates of 20 percent or less, except for hydrocarbons. The variation in the empirically-based daily activity cycle average rates were highly correlated with MOVES estimates, except for hydrocarbons. The data collected here are useful for quantifying daily activity specific to front-loaders, and for developing fuel use and emission estimates and models for this type of vehicle.

  1. The development of agro-residue densified fuel in China based on energetics analysis.

    Science.gov (United States)

    Chen, Longjian; Xing, Li; Han, Lujia

    2010-05-01

    Agro-residue is one of the important biomass resources in China and its efficient utilization is crucial for providing bio-energy, releasing risk of environmental pollution, and enhancing rural incomes. Densification is one of the important utilization routes of agro-residues. The objective of this paper is to explore the development of agro-residue densified fuel in China based on energetics analysis. The energetical property and energy potential of main agro-residues in China were firstly analyzed and then the development of agro-residue densified fuel in every region was evaluated based on energetics analysis. The results show that the main agro-residues in China are good feedstocks as densified fuel and they constitute enormous energy potential for developing densified fuel. However, the situation of every region should be considered for the development of agro-residue densified fuel. The primary energy embodied per unit of useful energy indicates that most of the regions in China are suitable for developing agro-residue densified fuel as it is energetically advantageous compared with coal, whereas only about 25% of regions near coal production locations are not suitable as they are less energetically advantageous.

  2. Experimental Studies for CPF and SCR Model, Control System, and OBD Development for Engines Using Diesel and Biodiesel Fuels

    Energy Technology Data Exchange (ETDEWEB)

    Johnson, John; Naber, Jeffrey; Parker, Gordon; Yang, Song-Lin; Stevens, Andrews; Pihl, Josh

    2013-04-30

    The research carried out on this project developed experimentally validated Diesel Oxidation Catalyst (DOC), Diesel Particulate Filter (DPF), and Selective Catalytic Reduction (SCR) high‐fidelity models that served as the basis for the reduced order models used for internal state estimation. The high‐fidelity and reduced order/estimator codes were evaluated by the industrial partners with feedback to MTU that improved the codes. Ammonia, particulate matter (PM) mass retained, PM concentration, and NOX sensors were evaluated and used in conjunction with the estimator codes. The data collected from PM experiments were used to develop the PM kinetics using the high‐fidelity DPF code for both NO2 assisted oxidation and thermal oxidation for Ultra Low Sulfur Fuel (ULSF), and B10 and B20 biodiesel fuels. Nine SAE papers were presented and this technology transfer process should provide the basis for industry to improve the OBD and control of urea injection and fuel injection for active regeneration of the PM in the DPF using the computational techniques developed. This knowledge will provide industry the ability to reduce the emissions and fuel consumption from vehicles in the field. Four MS and three PhD Mechanical Engineering students were supported on this project and their thesis research provided them with expertise in experimental, modeling, and controls in aftertreatment systems.

  3. Fuel tax incidence in developing countries: The case of Costa Rica

    Energy Technology Data Exchange (ETDEWEB)

    Blackman, Allen, E-mail: blackman@rff.or [Resources for the Future, 1616 P Street, N.W. Washington, DC (United States); Environment for Development Center for Central America, Turriabla (Costa Rica); Osakwe, Rebecca; Alpizar, Francisco [Environment for Development Center for Central America, Turriabla (Costa Rica)

    2010-05-15

    Although fuel taxes are a practical means of curbing vehicular air pollution, congestion, and accidents in developing countries-all of which are typically major problems-they are often opposed on distributional grounds. Yet few studies have investigated fuel tax incidence in a developing country context. We use household survey data and income-outcome coefficients to analyze fuel tax incidence in Costa Rica. We find that the effect of a 10% fuel price hike through direct spending on gasoline would be progressive, its effect through spending on diesel-both directly and via bus transportation-would be regressive (mainly because poorer households rely heavily on buses), and its effect through spending on goods other than fuel and bus transportation would be relatively small, albeit regressive. Finally, we find that the overall effect of a 10% fuel price hike through all types of direct and indirect spending would be neutral and the magnitude of this combined effect would be modest. We conclude that distributional concerns need not rule out using fuel taxes to address pressing public health and safety problems, particularly if gasoline and diesel taxes can be differentiated.

  4. Fuel tax incidence in developing countries. The case of Costa Rica

    Energy Technology Data Exchange (ETDEWEB)

    Blackman, Allen [Resources for the Future, 1616 P Street, N.W. Washington, DC (United States); Environment for Development Center for Central America, Turriabla (Costa Rica); Osakwe, Rebecca; Alpizar, Francisco [Environment for Development Center for Central America, Turriabla (Costa Rica)

    2010-05-15

    Although fuel taxes are a practical means of curbing vehicular air pollution, congestion, and accidents in developing countries - all of which are typically major problems - they are often opposed on distributional grounds. Yet few studies have investigated fuel tax incidence in a developing country context. We use household survey data and income-outcome coefficients to analyze fuel tax incidence in Costa Rica. We find that the effect of a 10% fuel price hike through direct spending on gasoline would be progressive, its effect through spending on diesel - both directly and via bus transportation - would be regressive (mainly because poorer households rely heavily on buses), and its effect through spending on goods other than fuel and bus transportation would be relatively small, albeit regressive. Finally, we find that the overall effect of a 10% fuel price hike through all types of direct and indirect spending would be neutral and the magnitude of this combined effect would be modest. We conclude that distributional concerns need not rule out using fuel taxes to address pressing public health and safety problems, particularly if gasoline and diesel taxes can be differentiated. (author)

  5. Renewing Liquid Fueled Molten Salt Reactor Research and Development

    Science.gov (United States)

    Towell, Rusty; NEXT Lab Team

    2016-09-01

    Globally there is a desperate need for affordable, safe, and clean energy on demand. More than anything else, this would raise the living conditions of those in poverty around the world. An advanced reactor that utilizes liquid fuel and molten salts is capable of meeting these needs. Although, this technology was demonstrated in the Molten Salt Reactor Experiment (MSRE) at ORNL in the 60's, little progress has been made since the program was cancelled over 40 years ago. A new research effort has been initiated to advance the technical readiness level of key reactor components. This presentation will explain the motivation and initial steps for this new research initiative.

  6. Cost analysis of electrical power from an ethanol reformer and the fuel cell in the development of productive activities in the community Pico do Amor, MT, Brazil; Analise do custo da energia eletrica proveniente de um reformador de etanol e celula a combustivel no desenvolvimento de atividades produtivas na comunidade Pico do Amor/MT

    Energy Technology Data Exchange (ETDEWEB)

    Lopes, Davi Gabriel; Teixeira, Andre Frazao; Lopes, Daniel Gabriel; Cavaliero, Carla Kazue Nakao [Universidade Estadual de Campinas (DE/FEM/UNICAMP), SP (Brazil). Faculdade de Engenharia Mecanica. Departamento de Energia; Instituto Aqua Genesis, Campinas, SP (Brazil); Hytron, Campinas, SP (Brazil)

    2010-07-01

    This work has the objective to analyze the impact of the cost of from an ethane reformer / fuel cell in the family income considering the development of two productive activities selected by the community itself: the production and marketing of cassava flour and 'rapadura', a typical brazilian candy. The community energy demand was analyzed to achieve the results; estimated the energy cost from the implemented system and the money from the selling of the cassava flour and 'rapadura' produced with this electricity; the study of sensibility of the ethanol price in the electrical energy cost was done too, and the cassava flour and 'rapadura' in the family funds. From the results, it was verified that the electrical energy cost has a 16,4% impact in the family gross income and a net value around R$ 260,85/family, indicating that the community will have enough funds to pay for the energy and also will rise the amount of money for each family. Besides, the comparative analyze of the cost of the electricity from the ethanol/fuel cell reformer and photovoltaic systems shows that, considering only the maintenance and operation costs, the first one should be more attractive than the second one. (author)

  7. Cost analysis of electrical power from an ethanol reformer and the fuel cell in the development of productive activities in the community Pico do Amor, MT, Brazil; Analise do custo da energia eletrica proveniente de um reformador de etanol e celula a combustivel no desenvolvimento de atividades produtivas na comunidade Pico do Amor/MT

    Energy Technology Data Exchange (ETDEWEB)

    Lopes, Davi Gabriel; Teixeira, Andre Frazao; Lopes, Daniel Gabriel; Cavaliero, Carla Kazue Nakao [Universidade Estadual de Campinas (DE/FEM/UNICAMP), SP (Brazil). Faculdade de Engenharia Mecanica. Departamento de Energia; Instituto Aqua Genesis, Campinas, SP (Brazil); Hytron, Campinas, SP (Brazil)

    2010-07-01

    This work has the objective to analyze the impact of the cost of from an ethane reformer / fuel cell in the family income considering the development of two productive activities selected by the community itself: the production and marketing of cassava flour and 'rapadura', a typical brazilian candy. The community energy demand was analyzed to achieve the results; estimated the energy cost from the implemented system and the money from the selling of the cassava flour and 'rapadura' produced with this electricity; the study of sensibility of the ethanol price in the electrical energy cost was done too, and the cassava flour and 'rapadura' in the family funds. From the results, it was verified that the electrical energy cost has a 16,4% impact in the family gross income and a net value around R$ 260,85/family, indicating that the community will have enough funds to pay for the energy and also will rise the amount of money for each family. Besides, the comparative analyze of the cost of the electricity from the ethanol/fuel cell reformer and photovoltaic systems shows that, considering only the maintenance and operation costs, the first one should be more attractive than the second one. (author)

  8. Phosphoric and electric utility fuel cell technology development

    Science.gov (United States)

    Breault, R. D.; Briggs, T. A.; Congdon, J. V.; Demarche, T. E.; Gelting, R. L.; Goller, G. J.; Luoma, W. I.; McCloskey, M. W.; Mientek, A. P.; Obrien, J. J.

    1984-01-01

    The advancement of electric utility cell stack technology and reduction of cell stack cost was initiated. The cell stack has a nominal 10 ft (2) active area and operates at 120 psia/405(0)F. The program comprises six parallel phases, which culminate in a full height, 10-ft(2) stack verification test: (1) provides the information and services needed to manage the effort, including definition of the prototype commercial power plant; (2) develops the technical base for long term improvements to the cell stack; (3) develops materials and processing techniques for cell stack components incorporating the best available technology; (4) provides the design of hardware and conceptual processing layouts, and updates the power plant definition of Phase 1 to reflect the results of Phases 2 and 3; Phase 5 manufactures the hardware to verify the achievements of Phases 2 and 3, and analyzes the cost of this hardware; and Phase 6 tests the cell stacks assembled from the hardware of Phase 5 to assess the state of development.

  9. A phenomenological model of two-phase (air/fuel droplet developing and breakup

    Directory of Open Access Journals (Sweden)

    Pavlović Radomir R.

    2013-01-01

    Full Text Available Effervescent atomization namely the air-filled liquid atomization comprehends certain complex two-phase phenomenon that are difficult to be modeled. Just a few researchers have found the mathematical expressions for description of the complex atomization model of the two-phase mixture air/diesel fuel. In the following review, developing model of twophase (air/fuel droplet of Cummins spray pump-injector is shown. The assumption of the same diameters of the droplet and the opening of the atomizer is made, while the air/fuel mass ratio inside the droplet varies.

  10. Development of the work on fuel cells in the Ministry for Atomic Energy of Russian Federation

    Energy Technology Data Exchange (ETDEWEB)

    Lubovin, B.Y.; Novitski, E.Z.

    1996-04-01

    This paper describes research on fuel cells in the Russian Federation. The beginning of the practical work on fuel cells in Russia dates back to the 50`s and 60`s when the Ural Electrochemical Plant and the Ural Electromechanical Plant of the Ministry of Medium Machine-Building of the USSR, all Russian Research Institute of the power sources and many other institutes of the Ministry of Electrotechnical Industry of the USSR got to the development of the alkaline fuel cells for the spaceships according to the tasks of the SPC `Energy` and for the submarines on the tasks of the Ministry of Defense.

  11. The Importance of Establishing and Maintaining Continuity of Knowledge during 21st Century Nuclear Fuel Cycle Activities

    Energy Technology Data Exchange (ETDEWEB)

    Pickett, Chris A [ORNL; Rowe, Nathan C [ORNL; Younkin, James R [ORNL; Wishard, Bernard [International Atomic Energy Agency (IAEA); Bean, Robert [U.S. Department of Energy, NNSA; Blair, Dianna [Sandia National Laboratories (SNL); Lawson, Ray [Savannah River National Laboratory (SRNL); Weeks, George [Savannah River National Laboratory (SRNL); Tolk, Keith [Milagro Consulting

    2012-01-01

    During this century, the entire nuclear fuel cycle will expand and become increasingly more global, taxing both the resources and capabilities of the International Atomic Energy Agency (IAEA) to maintain an effective Continuity of Knowledge (CoK) and its ability to provide timely detection of diversion. Uranium that currently is mined and milled in one country will be converted, enriched, and fabricated into fuel for reactors in an expanding set of new countries. This expansion will make it harder to guarantee that regional activities stay regional and that diversion detection is timely unless new and sustainable tools are developed to improve inspector effectiveness. To deal with this emerging reality, the IAEA must increase its use of unattended monitoring and employ new tools and methods that enhance CoK during all phases of the fuel cycle. This approach will help provide useful information to aid in detecting undeclared activities and create opportunities for timely and appropriate responses to events well before they enter phases of greater concern (e.g., enrichment). The systems that maintain CoK of safeguarded assets rely on containment and surveillance (C/S) technologies. The 21st century fuel cycle will require increased use of these technologies and systems, plus greater implementation of unattended systems that can securely collect data when inspectors are not present.

  12. Developing a High Thermal Conductivity Fuel with Silicon Carbide Additives

    Energy Technology Data Exchange (ETDEWEB)

    baney, Ronald; Tulenko, James

    2012-11-20

    The objective of this research is to increase the thermal conductivity of uranium oxide (UO{sub 2}) without significantly impacting its neutronic properties. The concept is to incorporate another high thermal conductivity material, silicon carbide (SiC), in the form of whiskers or from nanoparticles of SiC and a SiC polymeric precursor into UO{sub 2}. This is expected to form a percolation pathway lattice for conductive heat transfer out of the fuel pellet. The thermal conductivity of SiC would control the overall fuel pellet thermal conductivity. The challenge is to show the effectiveness of a low temperature sintering process, because of a UO{sub 2}-SiC reaction at 1,377°C, a temperature far below the normal sintering temperature. Researchers will study three strategies to overcome the processing difficulties associated with pore clogging and the chemical reaction of SiC and UO{sub 2} at temperatures above 1,300°C:

  13. Fuel Cell Development for NASA's Human Exploration Program: Benchmarking with "The Hydrogen Economy"

    Science.gov (United States)

    Scott, John H.

    2007-01-01

    The theoretically high efficiency and low temperature operation of hydrogen-oxygen fuel cells has motivated them to be the subject of much study since their invention in the 19th Century, but their relatively high life cycle costs kept them as a "solution in search of a problem" for many years. The first problem for which fuel cells presented a truly cost effective solution was that of providing a power source for NASA's human spaceflight vehicles in the 1960 s. NASA thus invested, and continues to invest, in the development of fuel cell power plants for this application. This development program continues to place its highest priorities on requirements for minimum system mass and maximum durability and reliability. These priorities drive fuel cell power plant design decisions at all levels, even that of catalyst support. However, since the mid-1990's, prospective environmental regulations have driven increased governmental and industrial interest in "green power" and the "Hydrogen Economy." This has in turn stimulated greatly increased investment in fuel cell development for a variety of commercial applications. This investment is bringing about notable advances in fuel cell technology, but, as these development efforts place their highest priority on requirements for minimum life cycle cost and field safety, these advances are yielding design solutions quite different at almost every level from those needed for spacecraft applications. This environment thus presents both opportunities and challenges for NASA's Human Exploration Program

  14. A summary of truck fuel-saving measures developed with industry participation

    Energy Technology Data Exchange (ETDEWEB)

    Bertram, K.M.; Saricks, C.L. [Argonne National Lab., IL (United States); Gregory, E.W. II [USDOE, Washington, DC (United States); Moore, A.J. [Northwestern Univ., Evanston, IL (United States)

    1983-09-01

    This report describes the third project undertaken by the Center for Transportation Research, Argonne National Laboratory (ANL), in a US Department of Energy program designed to develop and distribute compendiums of measures for saving transportation fuel. A matrix, or chart, of more than 60 fuel-saving measures was developed by ANL and refined with the assistance of trucking industry operators and researchers at an industry coordination meeting held in August 1982. The first two projects used similar meetings to refine matrices developed for the international maritime and US railroad industries. The consensus reached by those at the meeting was that the single most important element in a truck fuel-efficiency improvement program is the human element -- namely the development of strong motivation among truck drivers to save fuel. The role of the driver is crucial to the successful use of fuel-saving equipment and operating procedures. Identical conclusions were reached in the earlier maritime and rail meetings, thus providing a strong indication of the pervasive importance of the human element in energy-efficient transportation systems. The number and variety of changes made to the matrix are also delineated, including addition and deletion of various options and revisions of fuel-saving estimates, payback period estimates, and remarks concerning items such as the advantages, disadvantages, and cautions associated with various measures. The quality and quantity of the suggested changes demonstrate the considerable value of using a forum of industry operators and researchers to refine research data that are intended for practical application.

  15. Characterization of Thermal and Mechanical Properties of Polypropylene-Based Composites for Fuel Cell Bipolar Plates and Development of Educational Tools in Hydrogen and Fuel Cell Technologies

    Science.gov (United States)

    Lopez Gaxiola, Daniel

    2011-01-01

    In this project we developed conductive thermoplastic resins by adding varying amounts of three different carbon fillers: carbon black (CB), synthetic graphite (SG) and multi-walled carbon nanotubes (CNT) to a polypropylene matrix for application as fuel cell bipolar plates. This component of fuel cells provides mechanical support to the stack,…

  16. Characterization of Thermal and Mechanical Properties of Polypropylene-Based Composites for Fuel Cell Bipolar Plates and Development of Educational Tools in Hydrogen and Fuel Cell Technologies

    Science.gov (United States)

    Lopez Gaxiola, Daniel

    2011-01-01

    In this project we developed conductive thermoplastic resins by adding varying amounts of three different carbon fillers: carbon black (CB), synthetic graphite (SG) and multi-walled carbon nanotubes (CNT) to a polypropylene matrix for application as fuel cell bipolar plates. This component of fuel cells provides mechanical support to the stack,…

  17. Development And Testing Of Biogas-Petrol Blend As An Alternative Fuel For Spark Ignition Engine

    Directory of Open Access Journals (Sweden)

    Awogbemi

    2015-08-01

    Full Text Available Abstract This research is on the development and testing of a biogas-petrol blend to run a spark ignition engine. A2080 ratio biogaspetrol blend was developed as an alternative fuel for spark ignition engine test bed. Petrol and biogas-petrol blend were comparatively tested on the test bed to determine the effectiveness of the fuels. The results of the tests showed that biogas petrol blend generated higher torque brake power indicated power brake thermal efficiency and brake mean effective pressure but lower fuel consumption and exhaust temperature than petrol. The research concluded that a spark ignition engine powered by biogas-petrol blend was found to be economical consumed less fuel and contributes to sanitation and production of fertilizer.

  18. Cyclone reburn using coal-water fuel: Pilot-scale development and testing. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Eckhart, C.F.; DeVault, R.F.

    1991-10-01

    There is an ongoing effort to develop retrofit technologies capable of converting oil- and/or gas-fired boilers to coal combustion. The objective of this project is to demonstrate the technical feasibility of an improved portion of a previously developed retrofit system designed for the purpose of converting oil/gas boilers. This improvement would almost entirely eliminate the use of premium fuels, thereby significantly increasing the economical attractiveness of the system. Specifically, the goals in this program were to replace natural gas as a reburning fuel with coal-water fuel (CWF). The advantages of such a system include: (1) increased return on investment (ROI) for conversions; (2) nearly complete elimination of premium oil or gas fuel; (3) a more integrated approach to the conversion of oil- or gas-designed boilers to CWF.

  19. Cyclone reburn using coal-water fuel: Pilot-scale development and testing

    Energy Technology Data Exchange (ETDEWEB)

    Eckhart, C.F.; DeVault, R.F.

    1991-10-01

    There is an ongoing effort to develop retrofit technologies capable of converting oil- and/or gas-fired boilers to coal combustion. The objective of this project is to demonstrate the technical feasibility of an improved portion of a previously developed retrofit system designed for the purpose of converting oil/gas boilers. This improvement would almost entirely eliminate the use of premium fuels, thereby significantly increasing the economical attractiveness of the system. Specifically, the goals in this program were to replace natural gas as a reburning fuel with coal-water fuel (CWF). The advantages of such a system include: (1) increased return on investment (ROI) for conversions; (2) nearly complete elimination of premium oil or gas fuel; (3) a more integrated approach to the conversion of oil- or gas-designed boilers to CWF.

  20. Development of some exergetic parameters for PEM fuel cells for measuring environmental impact and sustainability

    Energy Technology Data Exchange (ETDEWEB)

    Midilli, Adnan [Energy Division, Mechanical Engineering Dept., Nigde University, 51100 Nigde (Turkey); Dincer, Ibrahim [Faculty of Engineering and Applied Science, University of Ontario Institute of Technology, 2000 Simcoe Street North, Oshawa, Ontario (Canada)

    2009-05-15

    This paper presents some new exergy-based parameters for PEM fuel cells to study how some of their operating aspects and system characteristics affect the environment and sustainability, based on some actual and literature data. The exergetic parameters of a PEM fuel cell developed here, in conjunction with environmental impact and sustainable development, are exergy efficiency, exergetic stability factor, environmental benign index and exergetic sustainability index. Any increase in efficiency improves exergetic sustainability. However, any increase in waste exergy ratio, exergy destruction factor, environmental destruction coefficient and environmental destruction index results in an increasing environmental impact of the PEM fuel cell and hence, a decreasing sustainability. Such parameters are expected to quantify how PEM fuel cells become more environmentally benign and sustainable. (author)

  1. Fuel cell life improved by metallic sinter activation after electrode assembly welding

    Science.gov (United States)

    Taylor, W. A.

    1967-01-01

    Technique improves the service life of fuel cell electrodes. The welding is done before the metallic sinter is activated by depositing finely divided metal within the sinter structure from a solution with corrosion inhibiting ions. The activator solution flows through the porous sinter while attached to the backup plate.

  2. How do liquid fuel physical properties affect liquid jet development in atomisers?

    Science.gov (United States)

    Charalampous, Georgios; Hardalupas, Yannis

    2016-10-01

    The influence of liquid fuel properties on atomisation remains an open question. The droplet sizes in sprays from atomisers operated with different fuels may be modified despite the small changes of the liquid properties. This paper examines experimentally the development of a liquid jet injected from a plain orifice in order to evaluate changes in its behaviour due to modifications of the liquid properties, which may influence the final atomisation characteristics. Two aviation kerosenes with similar, but not identical physical properties are considered, namely, standard JP8 kerosene as the reference fuel and bio-derived hydro-processed renewable jet fuel as an alternative biofuel. The corresponding density, dynamic viscosity, kinematic viscosity, and surface tension change by about +5%, -5%, -10%, and +5%, respectively, which are typical for "drop-in" fuel substitution. Three aspects of the liquid jet behaviour are experimentally considered. The pressure losses of the liquid jet through the nozzle are examined in terms of the discharge coefficient for different flowrates. The morphology of the liquid jet is visualised using high magnification Laser Induced Fluorescence (LIF) imaging. Finally, the temporal development of the liquid jet interfacial velocity as a function of distance from the nozzle exit is measured from time-dependent motion analysis of dual-frame LIF imaging measurements of the jet. The results show that for the small changes in the physical properties between the considered liquid fuels, the direct substitution of fuel did not result in a drastic change of the external morphology of the fuel jets. However, the small changes in the physical properties modify the interfacial velocities of the liquid and consequently the internal jet velocity profile. These changes can modify the interaction of the liquid jet with the surroundings, including air flows in coaxial or cross flow atomisation, and influence the atomisation characteristics during the

  3. Development of a charge-transfer distribution model for stack simulation of solid oxide fuel cells

    Science.gov (United States)

    Onaka, H.; Iwai, H.; Kishimoto, M.; Saito, M.; Yoshida, H.; Brus, G.; Szmyd, J. S.

    2016-09-01

    An overpotential model for planar solid oxide fuel cells (SOFCs) is developed and applied to a stack numerical simulation. Charge-transfer distribution within the electrodes are approximated using an exponential function, based on which the Ohmic loss and activation overpotential are evaluated. The predicted current-voltage characteristics agree well with the experimental results, and also the overpotentials within the cell can reproduce the results obtained from a numerical analysis where the distribution of the charge-transfer current within the electrodes is fully solved. The proposed model is expected to be useful to maintain the accuracy of SOFC simulations when the cell components, consisting of anode, electrolyte and cathode, are simplified into one layer element.

  4. Status of the Solid Oxide Fuel Cell Development at Topsoe Fuel Cell A/S and DTU Energy Conversion

    DEFF Research Database (Denmark)

    Christiansen, N.; Primdahl, S.; Wandel, Marie

    2013-01-01

    and manufacturing of materials, cells and stacks based on state of the art as well as innovative strategies. Today TOFC provides the SOFC technology platform: Cells, stacks, integrated multi stack module and PowerCore units that integrate stack modules with hot fuel processing units for high electrical efficiency....... TOFC collaborates with integrator partners to develop, test and demonstrate possibilities and challenges in case of CHP, distributed generation, transportation application and electrolysis. Aiming at improved reliability, robustness and low material cost, TOFC has in the collaboration with DTU...

  5. Coal-fueled diesel technology development. Final report, March 3, 1988--January 31, 1994

    Energy Technology Data Exchange (ETDEWEB)

    None

    1994-01-31

    Since 1979, the US Department of Energy has been sponsoring Research and Development programs to use coal as a fuel for diesel engines. In 1984, under the partial sponsorship of the Burlington Northern and Norfolk Southern Railroads, GE completed a 30-month study on the economic viability of a coal-fueled locomotive. In response to a GE proposal to continue researching the economic and technical feasibility of a coal-fueled diesel engine for locomotives, DOE awarded a contract to GE Corporate Research and Development for a three-year program that began in March 1985 and was completed in 1988. That program was divided into two parts: an Economic Assessment Study and a Technical Feasibility Study. The Economic Assessment Study evaluated the benefits to be derived from development of a coal-fueled diesel engine. Seven areas and their economic impact on the use of coal-fueled diesels were examined; impact on railroad infrastructure, expected maintenance cost, environmental considerations, impact of higher capital costs, railroad training and crew costs, beneficiated coal costs for viable economics, and future cost of money. The Technical Feasibility Study used laboratory- and bench-scale experiments to investigate the combustion of coal. The major accomplishments of this study were the development of injection hardware for coal water slurry (CWS) fuel, successful testing of CWS fuel in a full-size, single-cylinder, medium-speed diesel engine, evaluation of full-scale engine wear rates with metal and ceramic components, and the characterization of gaseous and particulate emissions. Full combustion of CWS fuel was accomplished at full and part load with reasonable manifold conditions.

  6. Modification, Development and Design Experimental Investigation of an Updraft Biomass Gasifier Stove with Sawdust as Fuel

    OpenAIRE

    A. M. El-jummah; U. M. Adam; M. B. Kolo; A. N. Musa

    2017-01-01

    This work presents the development of an updraft biomass gasifier stove which has been shown to apply the use of biomass fuels for the production of combustible gases. The updraft biomass gasifier stove designed was modified in order to ease the disposal of ashes, which is subsequently constructed using locally available material resources. The gasifier applies the principles of updraft producer gas flows, whereby the stove utilizes rice husk as it useable fuel. The modified gasifier stove wa...

  7. New In-pile Instrumentation to Support Fuel Cycle Research and Development

    Energy Technology Data Exchange (ETDEWEB)

    J. Rempe; H. MacLean; R. Schley; D. Hurley; J. Daw; S. Taylor; J. Smith; J. Svoboda; D. Kotter; D. Knudson; M. Guers; S. C. Wilkins

    2011-01-01

    New and enhanced nuclear fuels are a key enabler for new and improved reactor technologies. For example, the goals of the next generation nuclear plant (NGNP) will not be met without irradiations successfully demonstrating the safety and reliability of new fuels. Likewise, fuel reliability has become paramount in ensuring the competitiveness of nuclear power plants. Recently, the Office of Nuclear Energy in the Department of Energy (DOE-NE) launched a new direction in fuel research and development that emphasizes an approach relying on first principle models to develop optimized fuel designs that offer significant improvements over current fuels. To facilitate this approach, high fidelity, real-time, data are essential for characterizing the performance of new fuels during irradiation testing. A three-year strategic research program is proposed for developing the required test vehicles with sensors of unprecedented accuracy and resolution for obtaining the data needed to characterize three-dimensional changes in fuel microstructure during irradiation testing. When implemented, this strategy will yield test capsule designs that are instrumented with new sensor technologies for the Advanced Test Reactor (ATR) and other irradiation locations for the Fuel Cycle Research and Development (FC R&D) program. Prior laboratory testing, and as needed, irradiation testing, of these sensors will have been completed to give sufficient confidence that the irradiation tests will yield the required data. Obtaining these sensors must draw upon the expertise of a wide-range of organizations not currently supporting nuclear fuels research. This document defines this strategic program and provides the necessary background information related to fuel irradiation testing, desired parameters for detection, and an overview of currently available in-pile instrumentation. In addition, candidate sensor technologies are identified in this document, and a list of proposed criteria for ranking

  8. Pacific Northwest Laboratory Monthly Activities Report APRIL 1966 on AEC Division of Reactor Development and Technology

    Energy Technology Data Exchange (ETDEWEB)

    S. L. Fawcett

    1966-05-01

    This report has the following sections: Summary of Activities; Civilian Power Reactors; Applied and Reactor Physics; Reactor Fuels and Materials; Engineering Development; Plutonium Recycle Program; Advanced Systems; and Nuclear Safety.

  9. Pacific Northwest Laboratory Monthly Activities Report March 1966 On AEC Division of Reactor Development and Technology

    Energy Technology Data Exchange (ETDEWEB)

    S. L. Fawcett

    1966-04-01

    This report has the following sections: Summary of Activities; Civilian Power Reactors; Applied and Reactor Physics; Reactor Fuels and Materials; Engineering Development; Plutonium Recycle Program; Advanced Systems; and Nuclear Safety.

  10. A review of the development of high temperature proton exchange membrane fuel cells

    Institute of Scientific and Technical Information of China (English)

    Suthida Authayanun; Karittha Im-orb; Amornchai Arpornwichanop

    2015-01-01

    Due to the need for clean energy, the development of an efficient fuel cell technology for electricity generation has received considerable attention. Much of the current research efforts have investi‐gated the materials for and process development of fuel cells, including the optimization and simpli‐fication of the fuel cell components, and the modeling of the fuel cell systems to reduce their cost and improve their performance, durability and reliability to enable them to compete with the con‐ventional combustion engine. A high temperature proton exchange membrane fuel cell (HT‐PEMFC) is an interesting alternative to conventional PEMFCs as it is able to mitigate CO poisoning and water management problems. Although the HT‐PEMFC has many attractive features, it also possesses many limitations and presents several challenges to its widespread commercialization. In this re‐view, the trends of HT‐PEMFC research and development with respect to electrochemistry, mem‐brane, modeling, fuel options, and system design were presented.

  11. Clean coal combustion: development of clean combustion technologies for residual fuels

    Energy Technology Data Exchange (ETDEWEB)

    Montiel, M.F. [Electric Research Institute, Cuernavaca (Mexico)

    2003-07-01

    Most of the large quantities of heavy fuel oil (about 4% sulphur-content) produced in Mexican refineries are burned in power plants. More natural gas is being used, and it is estimated that by 2010, about one-third of Mexico's electricity will be produced from natural gas. As petroleum and gas reserves are depleted, power plants will consume more imported coal. To continue combustion of dirty fuels, advanced clean combustion technologies must be developed. Two feasibility projects were conducted over the period 1989-1995 on combustion of Mexican fuels in a bubbling fluidized combustor and in IGCC power plants. More recent feasibility studies for cogeneration plants in refineries are outlined. Solid fuels for IGCC and CFB are among the most important developments. Over the period 2004-2008, projects to study clean combustion of Mexican fuels will be conducted in the following areas: operational problems in IGCC plants, construction of an entrained flow gasifier for synthesis gas production and for feeding of heavy fuels and coal emulsions, and development of CFD (computational fluid dynamics) models.

  12. Proton Exchange Membranes for Fuel Cells Challenges and Recent Developments

    Institute of Scientific and Technical Information of China (English)

    Qingfeng Li; Jens Oluf Jensen; Pernille P. Noyé; Chao Pan; Niels J. Bjerrum

    2005-01-01

    @@ 1Introduction The current technology of proton exchange membrane fuel cells (PEMFC) is based on perfluorosulfonic acid (PFSA) membranes (e. g. Nafion(R)) as electrolyte. It operates on pure hydrogen and oxygen/air at typically 80℃ with high power density and long-term durability. For the membranes to be conductive, a minimum threshold of absorbed water molecules is about 6 to 7 mole per sulfonic site. The highest conductivity is only obtained under fully hydrated conductions, i.e. 21 - 22 mole water per sulfonic acid site. In other words, the proton conductivity is achieved by the locally liquid-like hydrophilic domain of the nanostructure.This strong dependence of conductivity on the water content in membranes limits the operational temperatureof PEMFC below 100℃.

  13. Surface strontium enrichment on highly active perovskites for oxygen electrocatalysis in solid oxide fuel cells

    KAUST Repository

    Crumlin, Ethan J.

    2012-01-01

    Perovskite oxides have high catalytic activities for oxygen electrocatalysis competitive to platinum at elevated temperatures. However, little is known about the oxide surface chemistry that influences the activity near ambient oxygen partial pressures, which hampers the design of highly active catalysts for many clean-energy technologies such as solid oxide fuel cells. Using in situ synchrotron-based, ambient pressure X-ray photoelectron spectroscopy to study the surface chemistry changes, we show that the coverage of surface secondary phases on a (001)-oriented La 0.8Sr 0.2CoO 3-δ (LSC) film becomes smaller than that on an LSC powder pellet at elevated temperatures. In addition, strontium (Sr) in the perovskite structure enriches towards the film surface in contrast to the pellet having no detectable changes with increasing temperature. We propose that the ability to reduce surface secondary phases and develop Sr-enriched perovskite surfaces of the LSC film contributes to its enhanced activity for O 2 electrocatalysis relative to LSC powder-based electrodes. © 2012 The Royal Society of Chemistry.

  14. Development of a coal-fueled Internal Manifold Heat Exchanger (IMHEX{reg_sign}) molten carbonate fuel cell. Volumes 1--6, Final report

    Energy Technology Data Exchange (ETDEWEB)

    1991-09-01

    The design of a CGMCFC electric generation plant that will provide a cost of eletricity (COE) which is lower than that of current electric generation technologies and which is competitive with other long-range electric generating systems is presented. This effort is based upon the Internal Manifold Heat Exchanger (IMHEX) technology as developed by the Institute of Gas Technology (IGT). The project was executed by selecting economic and performance objectives for alternative plant arrangements while considering process constraints identified during IMHEX fuel cell development activities at ICT. The four major subsystems of a coal-based MCFC power plant are coal gasification, gas purification, fuel cell power generation and the bottoming cycle. The design and method of operation of each subsystem can be varied, and, depending upon design choices, can have major impact on both the design of other subsystems and the resulting cost of electricity. The challenge of this project was to select, from a range of design parameters, those operating conditions that result in a preferred plant design. Computer modelling was thus used to perform sensitivity analyses of as many system variables as program resources and schedules would permit. In any systems analysis, it is imperative that the evaluation methodology be verifiable and comparable. The TAG Class I develops comparable (if imprecise) data on performance and costs for the alternative cases being studied. It identifies, from a range of options, those which merit more exacting scrutiny to be undertaken at the second level, TAG class II analysis.

  15. Best Practices and Testing Protocols for Benchmarking ORR Activities of Fuel Cell Electrocatalysts Using Rotating Disk Electrode

    Energy Technology Data Exchange (ETDEWEB)

    Kocha, Shyam S; Shinozaki, Kazuma; Zack, Jason W; Myers, Deborah J.; Kariuki, Nancy N.; Nowicki, Tammi L.; Stamenkovic, Vojislav; Kang, Yijin; Li, Dongguo; Papageorgopoulos, Dimitrios

    2017-07-01

    Abstract Thin-film-rotating disk electrodes (TF-RDEs) are the half-cell electrochemical system of choice for rapid screening of oxygen reduction reaction (ORR) activity of novel Pt supported on carbon black supports (Pt/C) electrocatalysts. It has been shown that the magnitude of the measured ORR activity and reproducibility are highly dependent on the system cleanliness, evaluation protocols, and operating conditions as well as ink formulation, composition, film drying, and the resultant film thickness and uniformity. Accurate benchmarks of baseline Pt/C catalysts evaluated using standardized protocols and best practices are necessary to expedite ultra-low-platinum group metal (PGM) catalyst development that is crucial for the imminent commercialization of fuel cell vehicles. We report results of evaluation in three independent laboratories of Pt/C electrocatalysts provided by commercial fuel cell catalyst manufacturers (Johnson Matthey, Umicore, Tanaka Kikinzoku Kogyo—TKK). The studies were conducted using identical evaluation protocols/ink formulation/film fabrication albeit employing unique electrochemical cell designs specific to each laboratory. The ORR activities reported in this work provide a baseline and criteria for selection and scale-up of novel high activity ORR electrocatalysts for implementation in proton exchange membrane fuel cells (PEMFCs).

  16. High-activity PtRuPd/C catalyst for direct dimethyl ether fuel cells.

    Science.gov (United States)

    Li, Qing; Wen, Xiaodong; Wu, Gang; Chung, Hoon T; Gao, Rui; Zelenay, Piotr

    2015-06-22

    Dimethyl ether (DME) has been considered as a promising alternative fuel for direct-feed fuel cells but lack of an efficient DME oxidation electrocatalyst has remained the challenge for the commercialization of the direct DME fuel cell. The commonly studied binary PtRu catalyst shows much lower activity in DME than methanol oxidation. In this work, guided by density functional theory (DFT) calculation, a ternary carbon-supported PtRuPd catalyst was designed and synthesized for DME electrooxidation. DFT calculations indicated that Pd in the ternary PtRuPd catalyst is capable of significantly decreasing the activation energy of the CO and CH bond scission during the oxidation process. As evidenced by both electrochemical measurements in an aqueous electrolyte and polymer-electrolyte fuel cell testing, the ternary catalyst shows much higher activity (two-fold enhancement at 0.5 V in fuel cells) than the state-of-the-art binary Pt50 Ru50 /C catalyst (HiSPEC 12100).

  17. Concept of development of nuclear power based on LMFBR operation in open nuclear fuel cycle

    Energy Technology Data Exchange (ETDEWEB)

    Toshinsky, G.I. [Inst. of Physics and Power Engineering, Obninsk (Russian Federation)

    1996-08-01

    The preliminary assessments performed show that it is reasonable to investigate in the future the possibilities of FBR efficient operation with the open NFC. To improve its safety it is expedient to use the lead-bismuth alloy as a coolant. In order to operate with depleted uranium make-up it is necessary to meet a number of requirements providing the reactor criticality due to plutonium build-up and BR > 1. These requirements are as follows: a large core (20--25 m{sup 3}); a high fuel volume fraction (> 60%); utilization of dense metallic fuel; a high fuel burn-up--at a level of 20% of h.a. Making use of these reactors should allow the NP fuel base to be extended more than 10 times without making NFC closed. It provides improving NP safety during a sufficiently long stage of its development.

  18. Development of numerical models for Monte Carlo simulations of Th-Pb fuel assembly

    Directory of Open Access Journals (Sweden)

    Oettingen Mikołaj

    2017-01-01

    Full Text Available The thorium-uranium fuel cycle is a promising alternative against uranium-plutonium fuel cycle, but it demands many advanced research before starting its industrial application in commercial nuclear reactors. The paper presents the development of the thorium-lead (Th-Pb fuel assembly numerical models for the integral irradiation experiments. The Th-Pb assembly consists of a hexagonal array of ThO2 fuel rods and metallic Pb rods. The design of the assembly allows different combinations of rods for various types of irradiations and experimental measurements. The numerical model of the Th-Pb assembly was designed for the numerical simulations with the continuous energy Monte Carlo Burnup code (MCB implemented on the supercomputer Prometheus of the Academic Computer Centre Cyfronet AGH.

  19. A State of Art Report on Development of PIE for Coated Particle Fuel of VHTR

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Hee Moon; Chun, Yong Bum; Lee, Young Woo; Kim, Bong Goo; Cho, Moon Sung; Kim, Young Min; Kim, Woong Ki

    2007-04-15

    In this report, techniques, equipment and hot-cell facilities for PIE were introduced to observe behavior of particle for the safety and stability based on the open literatures. In order to analyse fuel stability, failure of coated layers and behavior of boundaries between layers are examined, and the analytical results gives feedback information to manufacturing process of the particles. On the other hand, the test for the release of fission products is carried out at high temperature for measurement of diffusivity. For PIE of fuel particle, a lot of experimental development and modification of equipment has to be made in our facilities as well as installation and operation in hot cell facility. The IMGA(Irradiated Microsphere Gamma Analyzer) technique needs to be developed for radioisotope analysis of particle to observe fuel failure. KUFA system is necessary to obtain release data of fission products from the fuel kernel and to observe interactions between kernel and coating layers. In addition, some specific techniques for the material properties such as nano-indentation, x-ray radiography and so on. Optical microscope, SEM and EPMA may be possible to perform PIE of fuel particle for microstructure analysis. ICP-AES and ICP-MS are also available for chemical analysis. Some techniques, for example, deconsolidation of fuel compact, should be obtained by technical papers and experts from overseas.

  20. Development of a biodiesel activity

    Directory of Open Access Journals (Sweden)

    Vermeersch Georges

    2001-01-01

    Full Text Available Nutritional values of fatty acid classes are normally discussed on the basis of their saturated, monounsaturated and polyunsaturated structures with implicit understanding that they are straight-chain. Here we focus on chlorophyll-derived phytanic and pristanic acids that are minor isoprenoid branched-chain lipid constituents in food, but of unknown nutritional value. After describing the enzyme machinery that degrades these nutrient fatty acids in the peroxisome, we show by the criteria of a mouse model and of a human cell culture model that they induce with high potency expression of enzymes responsible for beta-oxidation of straight-chain fatty acids in the peroxisome. We summarize present mechanistic knowledge on fatty acid signaling to the nucleus, which involves protein/protein contacts between peroxisome proliferator activated receptor (PPAR and fatty acid binding protein (FABP. In this signaling event the branched-chain fatty acids are the most effective ones. Finally, on the basis of this nutrient-gene interaction we discuss nutritional opportunities and therapeutic aspects of the chlorophyll-derived fatty acids. The circumstances that led to the significant French biodiesel activity will be examined: the oilseed producers and transformers actions, the partnership with the oil refiners, the government support - regulation and detaxation... The French production units will be described, followed by update scientific results highlighting the advantages of biodiesel: functionality and friendly environmentally impact. The current usage of biodiesel by oil refiners will be described and its future in the oncoming context (fuel specifications, HDI engines and post-treatment discussed.

  1. Development of ORIGEN libraries for mixed oxide (MOX) fuel assembly designs

    Energy Technology Data Exchange (ETDEWEB)

    Mertyurek, Ugur, E-mail: mertyureku@ornl.gov; Gauld, Ian C., E-mail: gauldi@ornl.gov

    2016-02-15

    Highlights: • ORIGEN MOX library generation process is described. • SCALE burnup calculations are validated against measured MOX fuel samples from the MALIBU program. • ORIGEN MOX libraries are verified using the OECD Phase IV-B benchmark. • There is good agreement for calculated-to-measured isotopic distributions. - Abstract: ORIGEN cross section libraries for reactor-grade mixed oxide (MOX) fuel assembly designs have been developed to provide fast and accurate depletion calculations to predict nuclide inventories, radiation sources and thermal decay heat information needed in safety evaluations and safeguards verification measurements of spent nuclear fuel. These ORIGEN libraries are generated using two-dimensional lattice physics assembly models that include enrichment zoning and cross section data based on ENDF/B-VII.0 evaluations. Using the SCALE depletion sequence, burnup-dependent cross sections are created for selected commercial reactor assembly designs and a representative range of reactor operating conditions, fuel enrichments, and fuel burnup. The burnup dependent cross sections are then interpolated to provide problem-dependent cross sections for ORIGEN, avoiding the need for time-consuming lattice physics calculations. The ORIGEN libraries for MOX assembly designs are validated against destructive radiochemical assay measurements of MOX fuel from the MALIBU international experimental program. This program included measurements of MOX fuel from a 15 × 15 pressurized water reactor assembly and a 9 × 9 boiling water reactor assembly. The ORIGEN MOX libraries are also compared against detailed assembly calculations from the Phase IV-B numerical MOX fuel burnup credit benchmark coordinated by the Nuclear Energy Agency within the Organization for Economic Cooperation and Development. The nuclide compositions calculated by ORIGEN using the MOX libraries are shown to be in good agreement with other physics codes and with experimental data.

  2. Developing and analyzing long-term fuel management strategies for an advanced Small Modular PWR

    Energy Technology Data Exchange (ETDEWEB)

    Hedayat, Afshin, E-mail: ahedayat@aeoi.org.ir

    2017-03-15

    Highlights: • Comprehensive introduction and supplementary concepts as a review paper. • Developing an integrated long-term fuel management strategy for a SMR. • High reliable 3-D core modeling over fuel pins against the traditional LRM. • Verifying the expert rules of large PWRs for an advanced small PWR. • Investigating large numbers of safety parameters coherently. - Abstract: In this paper, long-term fuel management (FM) strategies are introduced and analyzed for a new advanced Pressurized Light Water Reactor (PWR) type of Small Modular Reactors (SMRs). The FM strategies are developed to be safe and practical for implementation as much as possible. Safety performances, economy of fuel, and Quality Assurance (QA) of periodic equilibrium conditions are chosen as the main goals. Flattening power density distribution over fuel pins is the major method to ensure safety performance; also maximum energy output or permissible discharging burn up indicates economy of fuel fabrication costs. Burn up effects from BOC to EOC have been traced, studied, and highly visualized in both of transport lattice cell calculations and diffusion core calculations. Long-term characteristics are searched to gain periodical equilibrium characteristics. They are fissile changes, neutron spectrum, refueling pattern, fuel cycle length, core excess reactivity, average, and maximum burn up of discharged fuels, radial Power Peaking Factors (PPF), total PPF, radial and axial power distributions, batch effects, and enrichment effects for fine regulations. Traditional linear reactivity model have been successfully simulated and adapted via fine core and burn up calculations. Effects of high burnable neutron poison and soluble boron are analyzed. Different numbers of batches via different refueling patterns have been studied and visualized. Expert rules for large type PWRs have been influenced and well tested throughout accurate equilibrium core calculations.

  3. High Efficiency Interleaved Active Clamped Dc-Dc Converter with Fuel Cell for High Voltage Applications

    Directory of Open Access Journals (Sweden)

    Sona P

    2014-02-01

    Full Text Available A high efficiency interleaved ZVS active clamped current fed dc-dc converter is proposed in this paper specially used for fuel cell applications. As the fuel cell output is very low we are in need of a step up dc-dc converter. Here a current fed dc-dc converter is used. Two current fed dc-dc converters are interleaved by connecting their inputs in parallel and outputs in series. With this proposed methodology input current ripples in the fuel cell stacks can be reduced and a regulated output voltage ripples can be obtained. The active clamping circuit used in this model absorbs the turn off voltage spikes hence low voltage devices with low on state resistance can be used.Voltage doubler circuits will give double the output voltage than normal with smaller transformer turns ratio and flexibility. The proposed method is simulated in MATLAB for verifying the accuracy of the proposed design.

  4. Anionic-exchange membrane development for application in alcohol alkaline fuel cells

    CSIR Research Space (South Africa)

    Nonjola, S

    2010-09-01

    Full Text Available into electrical energy and heat using electrochemical process © CSIR 2010 Slide 4 Fuel Cell Types • Alkaline (AFC) developed for the Apollo program • Polymer membrane (PEMC) leading candidate for transportation • Phosphoric acid (PAFC) 200kW units... Slide 11 Membrane Development • Polymer electrolyte fuel cell (PEFC) – most developed in the past 2 decades. • PEFC – acidic membrane (Nafion) as an electrolyte. • Nafion based FCs several obstacles such as: dependence on Pt catalysts and Me...

  5. Internal reforming development for solid oxide fuel cells

    Science.gov (United States)

    Lee, A. L.

    1987-02-01

    Internal reforming of natural gas within a solid oxide fuel cell (SOFC) should simplify the overall system design and make the SOFC an attractive means for producing electrical power. This program was undertaken to investigate the catalytic properties of nickel cermets, which are prime candidates for SOFC anodes. The initial task in this program was an extensive literature search for information on steam reforming of light hydrocarbons. The second task was to modify and calibrate the reactor systems that were used in the experimental kinetic studies. Two systems were used in this investigation; a continuously stirred tank reactor system (CSTR) and a plug flow reactor system (PFR). In the third task, 16 nickel-zirconia cermets were prepared using four procedures, tape casting, Westinghouse slurry, incorporation of performers, and granulation. The catalytic behavior of three cermets was determined in the fourth task. The reaction was first order with respect to methane and -1.25 for steam. Ethane and propane in the feed did not affect the methane conversion rate. The cermet has a higher initial tolerance for sulfur than standard nickel reforming catalysts. The final task was a mechanistic study of the steam reforming reaction on nickel and nickel-zirconia catalysts.

  6. HIGH-TEMPERATURE TUBULAR SOLID OXIDE FUEL CELL GENERATOR DEVELOPMENT

    Energy Technology Data Exchange (ETDEWEB)

    S.E. Veyo

    1998-09-01

    During the Westinghouse/USDOE Cooperative Agreement period of November 1, 1990 through November 30, 1997, the Westinghouse solid oxide fuel cell has evolved from a 16 mm diameter, 50 cm length cell with a peak power of 1.27 watts/cm to the 22 mm diameter, 150 cm length dimensions of today's commercial prototype cell with a peak power of 1.40 watts/cm. Accompanying the increase in size and power density was the elimination of an expensive EVD step in the manufacturing process. Demonstrated performance of Westinghouse's tubular SOFC includes a lifetime cell test which ran for a period in excess of 69,000 hours, and a fully integrated 25 kWe-class system field test which operated for over 13,000 hours at 90% availability with less than 2% performance degradation over the entire period. Concluding the agreement period, a 100 kW SOFC system successfully passed its factory acceptance test in October 1997 and was delivered in November to its demonstration site in Westervoort, The Netherlands.

  7. Study and Development of a Screener Test for Fuel Economy Passenger Car Motor Oil

    Institute of Scientific and Technical Information of China (English)

    Hiroshi Watanabe; Nobuo Ushioda; Yasuhiro Ogasawara

    2012-01-01

    Fuel economy regulations have been issued in many countries to save energy,and it is one of the most essential performance requirements for Passenger Car Motor Oil(PCMO) this decade.The performance is also important to reduce green house gas(GHG) emissions.Automotive,Oil and Additive industries have been developing fuel economy tests in fired engine for PCMO.The ASTM 5 Car test was started in 1982 and ASTM Sequence Ⅵ series test was also developed by the industries as one of fuel economy tests after the 5 Car test.However,the fired engine(combustion) test condition is more complicated and the combustion mode in engine introduce high variability into a fuel economy measurement.Screening by bench testing is complicated by the difficulty to reproduce friction conditions of all of engine parts.Based on the background,a motored engine friction torque test(MEFT) was developed as one of the solutions for fuel economy screening test.Using a newly developed MEFT,key additive chemistries were evaluated and compared in the test,and it distinguished the differences in additive chemistries,in addition to those in viscosity and friction modifiers.The Sequence Ⅵ-D FEI 1(Seq.Ⅵ-D FEI 1) and chassis dynamometer vehicle tests were also conducted in this study,and the test data has shown an excellent correlation among MEFT,Seq.Ⅵ-D FEI 1 and chassis dynamometer vehicle tests.

  8. Development of Out-pile Test Technology for Fuel Assembly Performance Verification

    Energy Technology Data Exchange (ETDEWEB)

    Chun, Tae Hyun; In, W. K.; Oh, D. S. [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)] (and others)

    2007-03-15

    Out-pile tests with full scale fuel assembly are to verify the design and to evaluate the performance of the final products. HTL for the hydraulic tests and FAMeCT for mechanical/structural tests were constructed in this project. The maximum operating conditions of HTL are 30 bar, 320 .deg. C, and 500 m3/hr. This facility can perform the pressure drop test, fuel assembly uplift test, and flow induced vibration test. FAMeCT can perform the bending and vibration tests. The verification of the developed facilities were carried out by comparing the reference data of the fuel assembly which was obtained at the Westinghouse Co. The compared data showed a good coincidence within uncertainties. FRETONUS was developed for high temperature and high pressure fretting wear simulator and performance test. A performance test was conducted for 500 hours to check the integrity, endurance, data acquisition capability of the simulator. The technology of turbulent flow analysis and finite element analysis by computation was developed. From the establishments of out-pile test facilities for full scale fuel assembly, the domestic infrastructure for PWR fuel development has been greatly upgraded.

  9. Advanced coal-fueled industrial cogeneration gas turbine system particle removal system development

    Energy Technology Data Exchange (ETDEWEB)

    Stephenson, M.

    1994-03-01

    Solar Turbines developed a direct coal-fueled turbine system (DCFT) and tested each component in subscale facilities and the combustion system was tested at full-scale. The combustion system was comprised of a two-stage slagging combustor with an impact separator between the two combustors. Greater than 90 percent of the native ash in the coal was removed as liquid slag with this system. In the first combustor, coal water slurry mixture (CWM) was injected into a combustion chamber which was operated loan to suppress NO{sub x} formation. The slurry was introduced through four fuel injectors that created a toroidal vortex because of the combustor geometry and angle of orientation of the injectors. The liquid slag that was formed was directed downward toward an impaction plate made of a refractory material. Sixty to seventy percent of the coal-borne ash was collected in this fashion. An impact separator was used to remove additional slag that had escaped the primary combustor. The combined particulate collection efficiency from both combustors was above 95 percent. Unfortunately, a great deal of the original sulfur from the coal still remained in the gas stream and needed to be separated. To accomplish this, dolomite or hydrated lime were injected in the secondary combustor to react with the sulfur dioxide and form calcium sulfite and sulfates. This solution for the sulfur problem increased the dust concentrations to as much as 6000 ppmw. A downstream particulate control system was required, and one that could operate at 150 psia, 1850-1900{degrees}F and with low pressure drop. Solar designed and tested a particulate rejection system to remove essentially all particulate from the high temperature, high pressure gas stream. A thorough research and development program was aimed at identifying candidate technologies and testing them with Solar`s coal-fired system. This topical report summarizes these activities over a period beginning in 1987 and ending in 1992.

  10. Design and Development of Membrane Electrode Assembly for Proton Exchange Membrane Fuel Cell

    Science.gov (United States)

    Kasat, Harshal Anil

    This work aimed to characterize and optimize the variables that influence the Gas Diffusion Layer (GDL) preparation using design of experiment (DOE) approach. In the process of GDL preparation, the quantity of carbon support and Teflon were found to have significant influence on the Proton Exchange Membrane Fuel Cell (PEMFC). Characterization methods like surface roughness, wetting characteristics, microstructure surface morphology, pore size distribution, thermal conductivity of GDLs were examined using laser interferometer, Goniometer, SEM, porosimetry and thermal conductivity analyzer respectively. The GDLs were evaluated in single cell PEMFC under various operating conditions of temperature and relative humidity (RH) using air as oxidant. Electrodes were prepared with different PUREBLACKRTM and poly-tetrafluoroethylene (PTFE) content in the diffusion layer and maintaining catalytic layer with a Pt-loading (0.4 mg cm-2). In the study, a 73.16 wt.% level of PB and 34 wt.% level of PTFE was the optimal compositions for GDL at 70°C for 70% RH under air atmosphere. For most electrochemical processes the oxygen reduction is very vita reaction. Pt loading in the electrocatalyst contributes towards the total cost of electrochemical devices. Reducing the Pt loading in electrocatalysts with high efficiency is important for the development of fuel cell technologies. To this end, this thesis work reports the approach to lower down the Pt loading in electrocatalyst based on N-doped carbon nanotubes derived from Zeolitic Imidazolate Frameworks (ZIF-67) for oxygen reduction. This electrocatalyst perform with higher electrocatalytic activity and stability for oxygen reduction in fuel cell testing. The electrochemical properties are mainly due to the synergistic effect from N-doped carbon nanotubes derived from ZIF and Pt loading. The strategy with low Pt loading forecasts in emerging highly active and less expensive electrocatalysts in electrochemical energy devices. This

  11. NASA's PEM Fuel Cell Power Plant Development Program for Space Applications

    Science.gov (United States)

    Hoberecht, Mark A.

    2008-01-01

    A three-center NASA team led by the Glenn Research Center in Cleveland, Ohio is completing a five-year PEM fuel cell power plant development program for future space applications. The focus of the program has been to adapt commercial PEM fuel cell technology for space applications by addressing the key mission requirements of using pure oxygen as an oxidant and operating in a multi-gravity environment. Competing vendors developed breadboard units in the 1 to 5 kW power range during the first phase of the program, and a single vendor developed a nominal 10-kW engineering model power pant during the second phase of the program. Successful performance and environmental tests conducted by NASA established confidence that PEM fuel cell technology will be ready to meet the electrical power needs of future space missions.

  12. A mono-dimensional nuclear fuel performance analysis code, PUMA, development from a coupled approach

    Energy Technology Data Exchange (ETDEWEB)

    Cheon, J. S.; Lee, B. O.; Lee, C. B. [Korea Atomic Energy Research Institute, 989-111 Daedeok-daero, Yuseong, Daejeon, 305-353 (Korea, Republic of); Yacout, A. M. [Argonne National Laboratory, 9700 South Cass Avenue, Argonne, IL 60439 (United States)

    2013-07-01

    Multidimensional-multi-physical phenomena in nuclear fuels are treated as a set of mono-dimensional-coupled problems which encompass heat, displacement, fuel constituent redistribution, and fission gas release. Rather than uncoupling these coupled equations as in conventional fuel performance analysis codes, efforts are put into to obtain fully coupled solutions by relying on the recent advances of numerical analysis. Through this approach, a new SFR metal fuel performance analysis code, called PUMA (Performance of Uranium Metal fuel rod Analysis code) is under development. Although coupling between temperature and fuel constituent was made easily, the coupling between the mechanical equilibrium equation and a set of stiff kinetics equations for fission gas release is accomplished by introducing one-level Newton scheme through backward differentiation formula. Displacement equations from 1D finite element formulation of the mechanical equilibrium equation are solved simultaneously with stress equation, creep equation, swelling equation, and FGR equations. Calculations was made successfully such that the swelling and the hydrostatic pressure are interrelated each other. (authors)

  13. A Development of Technical Specification of a Research Reactor with Plate Fuels Cooled by Upward Flow

    Energy Technology Data Exchange (ETDEWEB)

    Park, Sujin; Kim, Jeongeun; Kim, Hyeonil [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

    2016-10-15

    The contents of the TS(Technical Specifications) are definitions, safety limits, limiting safety system settings, limiting conditions for operation, surveillance requirements, design features, and administrative controls. TS for Nuclear Power Plants (NPPs) have been developed since many years until now. On the other hands, there are no applicable modernized references of TS for research reactors with many differences from NPPs in purpose and characteristics. Fuel temperature and Departure from Nuclear Boiling Ratio (DNBR) are being used as references from the thermal-hydraulic analysis point of view for determining whether the design of research reactors satisfies acceptance criteria for the nuclear safety or not. Especially for research reactors using plate-type fuels, fuel temperature and critical heat flux, however, are very difficult to measure during the reactor operation. This paper described the outline of main contents of a TS for open-pool research reactor with plate-type fuels using core cooling through passive systems, where acceptance criteria for nuclear safety such as CHF and fuel temperature cannot be directly measured, different from circumstances in NPPs. Thus, three independent variables instead of non-measurable acceptance criteria: fuel temperature and CHF are considered as safety limits, i.e., power, flow, and flow temperature.

  14. DEVELOPMENT AND SELECTION OF IONIC LIQUID ELECTROLYTES FOR HYDROXIDE CONDUCTING POLYBENZIMIDAZOLE MEMBRANES IN ALKALINE FUEL CELLS

    Energy Technology Data Exchange (ETDEWEB)

    Fox, E.

    2012-05-01

    Alkaline fuel cell (AFC) operation is currently limited to specialty applications such as low temperatures and pure HO due to the corrosive nature of the electrolyte and formation of carbonates. AFCs are the cheapest and potentially most efficient (approaching 70%) fuel cells. The fact that non-Pt catalysts can be used, makes them an ideal low cost alternative for power production. The anode and cathode are separated by and solid electrolyte or alkaline porous media saturated with KOH. However, CO from the atmosphere or fuel feed severely poisons the electrolyte by forming insoluble carbonates. The corrosivity of KOH (electrolyte) limits operating temperatures to no more than 80°C. This chapter examines the development of ionic liquids electrolytes that are less corrosive, have higher operating temperatures, do not chemically bond to CO and enable alternative fuels. Work is detailed on the IL selection and characterization as well as casting methods within the polybenzimidazole based solid membrane. This approach is novel as it targets the root of the problem (the electrolyte) unlike other current work in alkaline fuel cells which focus on making the fuel cell components more durable.

  15. Development of large aperture projection scatterometry for catalyst loading evaluation in proton exchange membrane fuel cells

    Science.gov (United States)

    Stocker, Michael T.; Barnes, Bryan M.; Sohn, Martin; Stanfield, Eric; Silver, Richard M.

    2017-10-01

    Widespread commercialization of proton exchange membrane fuel cells remains curbed by various manufacturing and infrastructure challenges. One such technical barrier identified by the U. S. Department of Energy is the need for high-speed, in-line process control of platinum-based catalyst layers in the membrane electrode assembly of the fuel cell. Using multiple reflectivity-based optical methods, such as optical scatterometry and large aperture projection scatterometry, we demonstrate in-line-capable catalyst loading measurements of carbon-supported Pt nanoparticle and Pt-alloy nanostructured thin film catalyst coated membranes. Large aperture projection scatterometry is a new high-throughput approach developed at the National Institute of Standards and Technology specifically for fuel cell manufacturing metrology. Angle- and wavelength-resolved measurements of these fuel cell soft goods validate the ability of reflectivity-based measurements to produce industrially relevant sensitivities to changes in Pt and Pt-alloy loading. The successful application of these optical methods to fuel cell manufacturing metrology directly addresses the shortage of high-throughput process control approaches needed to facilitate performance improvements and manufacturing cost-reductions required to make fuel cells commercially viable.

  16. Development of FUELSIM/MOD0 for the detailed analysis of LWR fuel rod behavior under normal operation conditions with extended burnup fuel

    Energy Technology Data Exchange (ETDEWEB)

    Berna, G.A.; Allison, C.M. [Innovative Systems Software LLC, 1284 South Woodruff, Idaho Falls, ID (United States)

    1999-07-01

    The FUELSIM code is being developed by Innovative Systems Software as part of the international SCDAP Development and Training Program. FUELSIM is being developed as a 'stand-alone' best-estimate fuel behavior code with evaluation modeling options. The long term goal of the code is to predict fuel performance over the full range of conditions from normal operating behavior to severe accident conditions using a combination of models from the FRAPCON-3, FRAP-T6, SCDAP, and MATPRO fuel behavior codes. FUELSIM/MOD0 is the first release of the code and includes models to predict the behavior of LWR fuel rods during normal operating conditions including the influence of extended burnup fuel. The code calculates the temperature, pressure, and deformation of a fuel rod as functions of time-dependent fuel rod power and coolant boundary conditions. The code models all the important phenomena that occur during normal operating conditions and contains necessary materials properties, water properties, and heat transfer correlations. The code runs on a variety of computers and operating systems including UNIX, LINUX, and Windows NT or 95. (author)

  17. Solar Power and Solar Fuels Synthesis Report. Technology, market and research activities 2006-2011

    Energy Technology Data Exchange (ETDEWEB)

    Ridell, Bengt; Nilsson, Ronny; Rehnlund, Bjoern [Grontmij, Stockholm (Sweden); Kasemo, Bengt [Chalmers Univ. of Technology, Goeteborg (Sweden)

    2012-11-01

    The objectives of the synthesis is to survey the situation and give an accumulated and concentrated knowledge about status, needs and opportunities for Swedish research and Swedish industry within the area of solar power and solar fuels, to be used for prioritisation of further efforts. The synthesis shall identify strengths and weaknesses in areas fundamental for development of solar power and solar fuels, focused on the development in Sweden, but in an international context. The synthesis shall also cover proposals for future Swedish research efforts and organisation of future Swedish research programs.

  18. Fossil Fuels.

    Science.gov (United States)

    Crank, Ron

    This instructional unit is one of 10 developed by students on various energy-related areas that deals specifically with fossil fuels. Some topics covered are historic facts, development of fuels, history of oil production, current and future trends of the oil industry, refining fossil fuels, and environmental problems. Material in each unit may…

  19. Fossil Fuels.

    Science.gov (United States)

    Crank, Ron

    This instructional unit is one of 10 developed by students on various energy-related areas that deals specifically with fossil fuels. Some topics covered are historic facts, development of fuels, history of oil production, current and future trends of the oil industry, refining fossil fuels, and environmental problems. Material in each unit may…

  20. Prediction of solid oxide fuel cell cathode activity with first-principles descriptors

    DEFF Research Database (Denmark)

    Lee, Yueh-Lin; Kleis, Jesper; Rossmeisl, Jan

    2011-01-01

    In this work we demonstrate that the experimentally measured area specific resistance and oxygen surface exchange of solid oxide fuel cell cathode perovskites are strongly correlated with the first-principles calculated oxygen p-band center and vacancy formation energy. These quantities...... are therefore descriptors of catalytic activity that can be used in the first-principles design of new SOFC cathodes....

  1. Development of a Si-PM based alpha camera for plutonium detection in nuclear fuel facilities

    Science.gov (United States)

    Morishita, Yuki; Yamamoto, Seiichi; Izaki, Kenji; Kaneko, Junichi H.; Toi, Kohei; Tsubota, Youichi

    2014-05-01

    Alpha particles are monitored for detecting nuclear fuel material (i.e., plutonium and uranium) at nuclear fuel facilities. Currently, for monitoring the airborne contamination of nuclear fuel, only energy information measured by Si-semiconductor detectors is used to distinguish nuclear fuel material from radon daughters. In some cases, however, such distinguishing is difficult when the radon concentration is high. In addition, a Si-semiconductor detector is generally sensitive to noise. In this study, we developed a new alpha-particle imaging system by combining a Si-PM array, which is insensitive to noise, with a Ce-doped Gd3Al2Ga3O12(GAGG) scintillator, and evaluated our developed system's fundamental performance. The scintillator was 0.1-mm thick, and the light guide was 3.0 mm thick. An 241Am source was used for all the measurements. We evaluated the spatial resolution by taking an image of a resolution chart. A 1.6 lp/mm slit was clearly resolved, and the spatial resolution was estimated to be less than 0.6-mm FWHM. The energy resolution was 13% FWHM. A slight distortion was observed in the image, and the uniformity near its center was within ±24%. We conclude that our developed alpha-particle imaging system is promising for plutonium detection at nuclear fuel facilities.

  2. Advanced Microbial Fuel Cell Development, Miniaturization and Energy and Power Density Enhancement

    Science.gov (United States)

    2007-04-30

    fuel cell development, miniaturization, and energy and power density enhancement. The anode is very important in the performance of a microbial fuel cell "MFC", and is often the limiting factor for a high power output. In present work, we used the CNT/PANI composite as the anode materials of MFCs for the first time and investigated the electrocatalytic properties of the composite associated with the bacterium biocatalyst. A method was developed to fabricate a nanostructured CNT/PANI composite anode for

  3. Development of Oxide Ceramics for Application in Solid Oxide Fuel Cells

    Institute of Scientific and Technical Information of China (English)

    P.Holtappels; A.Braun; U.Vogt

    2007-01-01

    1 Results Solid oxide fuel cells (SOFC) are ceramic fuel cells that convert chemical into electrical energy in a temperature region between 650 ℃ and 1 000 ℃.Systems are currently under development for a variety of applications e.g. for both small and large scale stationary combined heat and power systems but also for the supply of electrical energy in the automotive area. The current objectives in the development of SOFCs is to lower the operating temperature from 850 ℃ down to below 750 ℃ in order to ...

  4. Research and development of Proton-Exchange-Membrane (PEM) fuel cell system for transportation applications. Fuel cell infrastructure and commercialization study

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-11-01

    This paper has been prepared in partial fulfillment of a subcontract from the Allison Division of General Motors under the terms of Allison`s contract with the U.S. Department of Energy (DE-AC02-90CH10435). The objective of this task (The Fuel Cell Infrastructure and Commercialization Study) is to describe and prepare preliminary evaluations of the processes which will be required to develop fuel cell engines for commercial and private vehicles. This report summarizes the work undertaken on this study. It addresses the availability of the infrastructure (services, energy supplies) and the benefits of creating public/private alliances to accelerate their commercialization. The Allison prime contract includes other tasks related to the research and development of advanced solid polymer fuel cell engines and preparation of a demonstration automotive vehicle. The commercialization process starts when there is sufficient understanding of a fuel cell engine`s technology and markets to initiate preparation of a business plan. The business plan will identify each major step in the design of fuel cell (or electrochemical) engines, evaluation of the markets, acquisition of manufacturing facilities, and the technical and financial resources which will be required. The process will end when one or more companies have successfully developed and produced fuel cell engines at a profit. This study addressed the status of the information which will be required to prepare business plans, develop the economic and market acceptance data, and to identify the mobility, energy and environment benefits of electrochemical or fuel cell engines. It provides the reader with information on the status of fuel cell or electrochemical engine development and their relative advantages over competitive propulsion systems. Recommendations and descriptions of additional technical and business evaluations that are to be developed in more detail in Phase II, are included.

  5. Development of Ultra-Low Platinum Alloy Cathode Catalysts for PEM Fuel Cells

    Energy Technology Data Exchange (ETDEWEB)

    Popov, Branko N. [Univ. of South Carolina, Columbia, SC (United States). Dept. of Chemical Engineering; Weidner, John [Univ. of South Carolina, Columbia, SC (United States)

    2016-01-07

    The goal of this project is to synthesize a low cost PEM fuel cell cathode catalyst and support with optimized average mass activity, stability of mass activity, initial high current density performance under H2/air (power density), and catalyst and support stability able to meet 2017 DOE targets for electrocatalysts for transportation applications. Pt*/ACCS-2 catalyst was synthesized according to a novel methodology developed at USC through: (i) surface modification, (ii) metal catalyzed pyrolysis and (iii) chemical leaching to remove excess meal used to dope the support. Pt* stands for suppressed platinum catalyst synthesized with Co doped platinum. The procedure results in increasing carbon graphitization, inclusion of cobalt in the bulk and formation of non-metallic active sites on the carbon surface. Catalytic activity of the support shows an onset potential of 0.86 V for the oxygen reduction reaction (ORR) with well-defined kinetic and mass transfer regions and 2.5% H2O2 production. Pt*/ACCS-2 catalyst durability under 0.6-1.0 V potential cycling and support stability under 1.0-1.5 V potential cycling was evaluated. The results indicated excellent catalyst and support performance under simulated start-up/shut down operating conditions (1.0 – 1.5 V, 5000 cycles) which satisfy DOE 2017 catalyst and support durability and activity. The 30% Pt*/ACCS-2 catalyst showed high initial mass activity of 0.34 A/mgPGM at 0.9 ViR-free and loss of mass activity of 45% after 30,000 cycles (0.6-1.0 V). The catalyst performance under H2-air fuel cell operating conditions showed only 24 mV (iR-free) loss at 0.8 A/cm2 with an ECSA loss of 42% after 30,000 cycles (0.6-1.0 V). The support stability under 1.0-1.5 V potential cycling showed mass activity loss of 50% and potential loss of 8 mV (iR-free) at 1.5 A/cm2. The ECSA loss was 22% after 5,000 cycles. Furthermore, the Pt*/ACCS-2 catalyst showed an

  6. Development of an Air Assisted Fuel Atomizer (Liquid Siphon Type for a Continuous Combustor

    Directory of Open Access Journals (Sweden)

    Pipatpong Watanawanyoo

    2009-01-01

    Full Text Available This research was the study of a fuel injection system in continuous combustor. Air atomizing nozzle is developed to good efficiency injection and used low air pressure (68.95-275.79kPa to assist the atomizing nozzle. Refined palm oil and automotive diesel oil were the fuels for the experiment for the system of atomization. The atomizer was designed in a manner that air could flow through the small nozzle. Consequently, the low-pressure airflow could induce fuel by siphoning and break oil into small fine droplets that were delivered through the outlet. The aim of design and develop a continuous combustor is emphasized on simplicity for construction, inexpensive, good stability and reduce import fuel for continuous combustor. Material for combustor chamber is stainless steel in order to avoid oxidation at high combustion temperature. The results showed practical combustion performance using refined palm oil as fuel with ultra-low CO and HC emissions less than 206 ppm and 7 ppm. Another main advantage is a clean combustion, as no sulfur content in the fuel. As a result, the combustor performance testing was evaluated with refined palm oil and LPG. By regulating atomizing air pressure between 68.9995- 275.79 kPa (10-40psi, Siphon height 0.45 m and regulating LPG pressure of 6.8 kPa (1 psi, result showed that 0.0001167-0.00019936 kg/s of fuel consumption, hot gas produced from combustion was in the range of 308-4980C depending on oxidizing air mass flow regulated between 0.0695-0.1067kg/s. The LPG mass flow was regulated 0.000489 kg/s in order to sustain the combustion stability.

  7. A fuel-based approach for emission factor development for highway paving construction equipment in China.

    Science.gov (United States)

    Li, Zhen; Zhang, Kaishan; Pang, Kaili; Di, Baofeng

    2016-12-01

    The objective of this paper is to develop and demonstrate a fuel-based approach for emissions factor estimation for highway paving construction equipment in China for better accuracy. A highway construction site in Chengdu was selected for this study with NO emissions being characterized and demonstrated. Four commonly used paving equipment, i.e., three rollers and one paver were selected in this study. A portable emission measurement system (PEMS) was developed and used for emission measurements of selected equipment during real-world highway construction duties. Three duty modes were defined to characterize the NO emissions, i.e., idling, moving, and working. In order to develop a representative emission factor for these highway construction equipment, composite emission factors were estimated using modal emission rates and the corresponding modal durations in the process of typical construction duties. Depending on duty mode and equipment type, NO emission rate ranged from 2.6-63.7mg/s and 6.0-55.6g/kg-fuel with the fuel consumption ranging from 0.31-4.52 g/s correspondingly. The NO composite emission factor was estimated to be 9-41mg/s with the single-drum roller being the highest and double-drum roller being the lowest and 6-30g/kg-fuel with the pneumatic tire roller being the highest while the double-drum roller being the lowest. For the paver, both time-based and fuel consumption-based NO composite emission rates are higher than all of the rollers with 56mg/s and 30g/kg-fuel, respectively. In terms of time-based quantity, the working mode contributes more than the other modes with idling being the least for both emissions and fuel consumption. In contrast, the fuel-based emission rate appears to have less variability in emissions. Thus, in order to estimate emission factors for emission inventory development, the fuel-based emission factor may be selected for better accuracy.

  8. Novel Catalyst Development for Synthetic Endothermic Fuels Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Physical Sciences Incorporated (PSI) and United Technologies Research Center (UTRC) propose to develop, characterize, and evaluate the performance of innovative...

  9. Measurement of the 235U Induced Fission Gamma-ray Spectrum as an Active Non-destructive Assay of Fresh Nucleear Fuel

    Energy Technology Data Exchange (ETDEWEB)

    Sarnoski, Sarah E.; Fast, James E.; Fulsom, Bryan G.; Gilbert, Andrew J.; Jacomb-Hood, Timothy W.; VanDevender, Brent A.; Wood, Lynn S.

    2017-07-17

    Non-destructive assay is a powerful tool the International Atomic Energy Agency (IAEA) employs to verify adherence to safeguards agreements. Current IAEA veri- cation techniques for fresh nuclear fuel include passive gamma-ray spectroscopy to determine fuel enrichment. This technique suers from self-shielding and lakes the percision to detect diversion of central fuel rods. The aim of this research is to develop a new, more capable non-destructive analysis technique using active neutron interroga- tion of fuel assemblies and determining the yields of short-lived ssion products from high-resolution gamma-ray spectroscopy using high-purity germanium (HPGe). This paper reports results from irradiation of a one meter tall mock fresh fuel assembly with low enriched uranium (LEU) or depleted uranium (DU) rods using a down-scattered deuterium-tritium (D-T) neutron source. Both prompt and delayed gamma-ray spec- tra were collected as time-stamped list-mode data in a coax detector and without list mode data in a planar strip detector. No dierentiating signatures were observed in the prompt spectra in either detector; however, both detectors observed several short-lived ssion product signatures in LEU and not DU fuel, indicating that this technique has potential for determination of enrichment of fresh fuel assemblies. There were eight unique ssion products observed in the LEU spectra with the coax detector spectra, and three ssion products were observed in the LEU spectra with the strip detector.

  10. Development of U-frame bending system for studying the vibration integrity of spent nuclear fuel

    Science.gov (United States)

    Wang, Hong; Wang, Jy-An John; Tan, Ting; Jiang, Hao; Cox, Thomas S.; Howard, Rob L.; Bevard, Bruce B.; Flanagan, Michelle

    2013-09-01

    A bending fatigue system developed to evaluate the response of spent nuclear fuel rods to vibration loads is presented. A U-frame testing setup is used for imposing bending loads on the fuel rod specimen. The U-frame setup consists of two rigid arms, side connecting plates to the rigid arms, and linkages to a universal testing machine. The test specimen's curvature is obtained through a three-point deflection measurement method. The tests using surrogate specimens with stainless steel cladding revealed increased flexural rigidity under unidirectional cyclic bending, significant effect of cladding-pellets bonding on the response of surrogate rods, and substantial cyclic softening in reverse bending mode. These phenomena may cast light on the expected response of a spent nuclear fuel rod. The developed U-frame system is thus verified and demonstrated to be ready for further pursuit in hot-cell tests.

  11. Development of an LCV fuel gas combustor for an industrial gas turbine

    Energy Technology Data Exchange (ETDEWEB)

    Constant, D.R.; Bevan, D.M.; Cannon, M.F.; Kelsall, G.J. [British Coal Corporation, Stoke Orchard (United Kingdom). Coal Technology Development Division

    1997-12-31

    An important component of the Air Blown Gasification Cycle (ABGC) development is the gas turbine combustion system. It must burn low calorific value (LCV) coal derived fuel gas, at high turbine inlet temperatures with minimum pollutant emissions. A phase development programme has been completed burning LCV fuel gas (3.6-4.1 MJ/m{sup 3}) with low emissions, particularly NO{sub x} derived from fuel bound nitrogen. Performance tests were carried out on a generic tubo-annular, prototype combustor, at Mach numbers generally lower than those typical to engine applications, with encouraging results. Five design variants, operating at conditions selected to represent a particular medium sized industrial gas turbine each returned an improvement in combustor performance. A further five variants were investigated to establish which design characteristics and operating parameters most affected NO{sub x} emissions. 5 refs., 5 figs., 2 tabs.

  12. Pellet Fueling, ELM pacing, and Disruption Mitigation Technology Development for ITER

    Energy Technology Data Exchange (ETDEWEB)

    Baylor, Larry R [ORNL; Combs, Stephen Kirk [ORNL; Foust, Charles R [ORNL; Jernigan, Thomas C [ORNL; Meitner, S. J. [Oak Ridge National Laboratory (ORNL); Parks, P. B. [General Atomics; Caughman, John B [ORNL; Maruyama, S. [ITER International Team, Garching, Germany; Qualls, A L [ORNL; Rasmussen, David A [ORNL; ThomasJr., C. E. [Third Dimension Technologies, LLC, Knoxville, TN

    2009-01-01

    Plasma fueling with pellet injection, pacing of edge localized modes (ELMs) by small frequent pellets, and disruption mitigation with gas jets or injected pellets are some of the most important technological capabilities needed for successful operation of ITER. Tools are being developed at Oak Ridge National Laboratory that can be employed on ITER to provide the necessary core pellet fueling and the mitigation of ELMs and disruptions. Here we present progress on the development of the technology to provide reliable high throughput inner wall pellet fueling, pellet ELM pacing with high frequency small pellets, and disruption mitigation with gas jets and pellets. Examples of how these tools can be employed on ITER are discussed.

  13. Lattice-strain control of the activity in dealloyed core-shell fuel cell catalysts.

    Science.gov (United States)

    Strasser, Peter; Koh, Shirlaine; Anniyev, Toyli; Greeley, Jeff; More, Karren; Yu, Chengfei; Liu, Zengcai; Kaya, Sarp; Nordlund, Dennis; Ogasawara, Hirohito; Toney, Michael F; Nilsson, Anders

    2010-06-01

    Electrocatalysis will play a key role in future energy conversion and storage technologies, such as water electrolysers, fuel cells and metal-air batteries. Molecular interactions between chemical reactants and the catalytic surface control the activity and efficiency, and hence need to be optimized; however, generalized experimental strategies to do so are scarce. Here we show how lattice strain can be used experimentally to tune the catalytic activity of dealloyed bimetallic nanoparticles for the oxygen-reduction reaction, a key barrier to the application of fuel cells and metal-air batteries. We demonstrate the core-shell structure of the catalyst and clarify the mechanistic origin of its activity. The platinum-rich shell exhibits compressive strain, which results in a shift of the electronic band structure of platinum and weakening chemisorption of oxygenated species. We combine synthesis, measurements and an understanding of strain from theory to generate a reactivity-strain relationship that provides guidelines for tuning electrocatalytic activity.

  14. CONSIDERATIONS FOR THE DEVELOPMENT OF A DEVICE FOR THE DECOMMISSIONING OF THE HORIZONTAL FUEL CHANNELS IN THE CANDU 6 NUCLEAR REACTOR. PART 6 - PRESENTATION OF THE DECOMMISSIONING DEVICE

    Directory of Open Access Journals (Sweden)

    Gabi ROSCA FARTAT

    2015-05-01

    dismantling and extraction of the channel closure plug and shield plug, extraction of the end fitting, cutting and extraction of the pressure tube. The fuel channel decommissioning device consists of following major components: coupling and locking fuel channel module, assembly valve for access to the fuel channel, storage tubes assembly for extracted components, handling elements assembly, cutting and extraction device and housing device. The design of the device and platform support is achieved according to the particular features of the fuel channel components to be dismantled in the program of nuclear reactor decommissioning according to all the safety aspects and environmental protection during the activities, resulting from the decommissioning plan developed.

  15. Advanced fuel cell development. Progress report, July--September 1978. [. gamma. -LiAlO/sub 2/ electrolyte

    Energy Technology Data Exchange (ETDEWEB)

    Finn, P.A.; Kinoshita, K.; Kucera, G.H.; Pierce, R.D.; Sim, J.W.

    1979-05-01

    This report describes advanced fuel cell research and development activities at Argonne National Laboratory (ANL) during the period July--September 1978. These efforts have been directed toward understanding and improving the components of molten-carbonate-electrolyte fuel cells operated at temperatures near 925 K. The primary focus of this work has been the development of electrolyte structures that have good electrolyte retention and mechanical properties as well as long term stability, and on developing methods of synthesis amenable to mass production. The characterization of these structures and their stability is an integral part of this effort. Synthesis studies have concentrated on the use of low-cost starting material to synthesize ..gamma..-LiAlO/sub 2/, the most stable allotrope of LiAlO/sub 2/ for the fuel cell conditions. Thermal stability and thermomechanical tests were performed on electrolyte mixtures to determine the effect of cell operating conditions on electrolyte tile longevity. A square cell (10.6 cm) with an electrolyte tile containing ..gamma..-LiAlO/sub 2/ was tested. This tile was reinforced by a wire screen. Post-test examination of this cell after 1000 h of operation showed that the reinforced tile was considerably stronger than un-reinforced tiles. Future cells will utilize tiles with metal screen reinforcement.

  16. Market Energy efficient and new fuel automobile developments

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    <正>Tsinghua University develops mini electric car OUYANG Mingbao, dean of automotive engineering and director of the key national laboratory of automobile safety and energy efficiency, has recently delivered a speech on the development of mini electric car in the university.

  17. Approaches and Recent Development of Polymer Electrolyte Membranes For Fuel Cells Operational Above 100°C

    DEFF Research Database (Denmark)

    Li, Qingfeng; He, Ronghuan; Jensen, Jens Oluf

    2003-01-01

    The state-of-the-art of polymer electrolyte membrane fuel cell (PEMFC) technology is based on perfluorosulfonic acid (PFSA) polymer membranes operating at a typical temperature of 80 °C. Some of the key issues and shortcomings of the PFSA-based PEMFC technology are briefly discussed. These include...... water management, CO poisoning, hydrogen, reformate and methanol as fuels, cooling, and heat recovery. As a means to solve these shortcomings, hightemperature polymer electrolyte membranes for operation above 100 °C are under active development. This treatise is devoted to a review of the area...... encompassing modified PFSA membranes, alternative sulfonated polymer and their composite membranes, and acidbase complex membranes. PFSA membranes have been modified by swelling with nonvolatile solvents and preparing composites with hydrophilic oxides and solid proton conductors. DMFC and H2/O2(air) cells...

  18. Development of integrated fuel cell hybrid power source for electric forklift

    Science.gov (United States)

    Keränen, T. M.; Karimäki, H.; Viitakangas, J.; Vallet, J.; Ihonen, J.; Hyötylä, P.; Uusalo, H.; Tingelöf, T.

    A hybrid drivetrain comprising a 16 kW polymer electrolyte membrane fuel cell system, ultracapacitor modules and a lead-acid battery was constructed and experimentally tested in a real counterweight forklift application. A scaled-down version of the hybrid system was assembled and tested in a controlled laboratory environment using a controllable resistive load. The control loops were operating in an in-house developed embedded system. The software is designed for building generic control applications, and the source code has been released as open source and made available on the internet. The hybrid drivetrain supplied the required 50 kW peak power in a typical forklift work cycle consisting of both loaded and unloaded driving, and lifting of a 2.4 tonne load. Load variations seen by the fuel cell were a fraction of the total current drawn by the forklift, with the average fuel cell power being 55% of nominal rating. A simple fuel cell hybrid model was also developed to further study the effects of energy storage dimensioning. Simulation results indicate that while a battery alone significantly reduces the load variations of the fuel cell, an ultracapacitor reduces them even further. Furthermore, a relatively small ultracapacitor is enough to achieve most of the potential benefit.

  19. Integrated Decision-Making Tool to Develop Spent Fuel Strategies for Research Reactors

    Energy Technology Data Exchange (ETDEWEB)

    Beatty, Randy L [ORNL; Harrison, Thomas J [ORNL

    2016-01-01

    IAEA Member States operating or having previously operated a Research Reactor are responsible for the safe and sustainable management and disposal of associated radioactive waste, including research reactor spent nuclear fuel (RRSNF). This includes the safe disposal of RRSNF or the corresponding equivalent waste returned after spent fuel reprocessing. One key challenge to developing general recommendations lies in the diversity of spent fuel types, locations and national/regional circumstances rather than mass or volume alone. This is especially true given that RRSNF inventories are relatively small, and research reactors are rarely operated at a high power level or duration typical of commercial power plants. Presently, many countries lack an effective long-term policy for managing RRSNF. This paper presents results of the International Atomic Energy Agency (IAEA) Coordinated Research Project (CRP) #T33001 on Options and Technologies for Managing the Back End of the Research Reactor Nuclear Fuel Cycle which includes an Integrated Decision Making Tool called BRIDE (Back-end Research reactor Integrated Decision Evaluation). This is a multi-attribute decision-making tool that combines the Total Estimated Cost of each life-cycle scenario with Non-economic factors such as public acceptance, technical maturity etc and ranks optional back-end scenarios specific to member states situations in order to develop a specific member state strategic plan with a preferred or recommended option for managing spent fuel from Research Reactors.

  20. Status of molten carbonate fuel cell technology development

    Science.gov (United States)

    Parsons, E. L., Jr.; Williams, M. C.; George, T. J.

    The MCFC technology has been identified by the DOE as a promising product for commercialization. Development of the MCFC technology supports the National Energy Strategy. Review of the status of the MCFC technology indicates that the MCFC technology developers are making rapid and significant progress. Manufacturing facility development and extensive testing is occurring. Improvements in performance (power density), lower costs, improved packaging, and scale up to full height are planned. MCFC developers need to continue to be responsive to end-users in potential markets. It will be market demands for the correct product definition which will ultimately determine the character of MCFC power plants. There is a need for continued MCFC product improvement and multiple product development tests.

  1. Active energy harvesting from microbial fuel cells at the maximum power point without using resistors.

    Science.gov (United States)

    Wang, Heming; Park, Jae-Do; Ren, Zhiyong

    2012-05-01

    Microbial fuel cell (MFC) technology offers a sustainable approach to harvest electricity from biodegradable materials. Energy production from MFCs has been demonstrated using external resistors or charge pumps, but such methods can only dissipate energy through heat or receive electrons passively from the MFC without any controllability. This study developed a new approach and system that can actively extract energy from MFC reactors at any operating point without using any resistors, especially at the peak power point to maximize energy production. Results show that power harvesting from a recirculating-flow MFC can be well maintained by the maximum power point circuit (MPPC) at its peak power point, while a charge pump was not able to change operating point due to current limitation. Within 18-h test, the energy gained from the MPPC was 76.8 J, 76 times higher than the charge pump (1.0 J) that was commonly used in MFC studies. Both conditions resulted in similar organic removal, but the Coulombic efficiency obtained from the MPPC was 21 times higher than that of the charge pump. Different numbers of capacitors could be used in the MPPC for various energy storage requirements and power supply, and the energy conversion efficiency of the MPPC was further characterized to identify key factors for system improvement. This active energy harvesting approach provides a new perspective for energy harvesting that can maximize MFC energy generation and system controllability.

  2. Towards small scale use of asphalt as a fuel. An application of interest to developing countries

    Energy Technology Data Exchange (ETDEWEB)

    Faber, J.

    2002-01-01

    This survey deals with the feasibility of the combustion of asphalt instead of firewood. On the seashores of the numerous islands of Indonesia, especially on those of south and southeast Sulawesi, mangrove forests are endangered by extensive logging, lately on an increasing scale by locals for whom firewood is the sole resource of energy. Urged by Yayasan-Sarna, an Indonesian non-governmental organisation of South East Sulawesi, the Dutch foundation Zephyr-Sama has prompted research on the feasibility to use asphalt from deposits on the island of Buton as a domestic fuel. This research was thought to possibly lead to the development of a porous plug stove, or to a stove in which carbonised bamboo containers filled with asphalt are used as fuel elements. This survey consists of a literature review and an overview of possible routes for controlled combustion of asphalt. Attention has been paid to the environmental effects of the combustion as well. The literature mainly shows side effects of combustion of asphalt, which provide some knowledge on the combustion process. No direct studies on the combustion of asphalt were found. To explore the bottlenecks of the combustion process, an asphalt candle was made, because the taper seemed an ideal capillary active carrier for fluid asphalt. However, this experimental candle did not bum, likely due to high viscosity at the base of the taper and clogging of carbonaceous residue at the liquid/gas interface of the taper. An increase of the porosity of asphalt gives a better chance for a propagating combustion. The pores may increase the diffusion rate of volatile components, thus increasing the combustion rate. However, if asphalt is heated it will melt and the fluid will block the pores. Its melting at a relatively low temperature is a big handicap of asphalt. To overcome this handicap, asphalt could be transported by capillary forces into the combustion zone and combust at solid/liquid/gas interfaces - like is happening in a

  3. Development of CANDU advanced fuel fabrication technology - A development of amorphous alloys for the solder of nuclear reactor materials

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Jai Young; Lee, Ki Young; Kim, Yoon Kee; Jung, Jae Han; Yu, Ji Sang; Kim, Hae Yeol; Han, Young Su [Korea Advanced Institute of Science and Technology, Taejon (Korea, Republic of)

    1996-07-01

    In the case of advanced CANDU fuel being useful in future, the fabrication processes for soundness insurance of a improved nuclear fuel bundle must be developed at the same time because it have three times combustibility as existing fuel. In particular, as the improved nuclear fuel bundle in which a coated layer thickness is thinner than existing that, firmity of a joint part is very important. Therefore, we need to develop a joint technique using new solder which can settle a potential problem in current joining method. As the Zr-Be alloy system and the Ti-Be system are composed with the elements having high neutron permeability, they are suitable for joint of nuclear fuel pack. The various compositions Zr-Be and Ti-Be binary metallic glass alloys were applicable to the joining the nuclear fuel bundles. The thickness of joint layer using the Zr{sub 1-x} Be{sub x} amorphous ribbon as a solder is thinner than that using physical vapor deposited Be. Among the Zr{sub 1-x} Be{sub x} amorphous binary alloys, Zr{sub 0.7} Be{sub 0.3} binary alloy is the most appropriated for joint of nuclear fuel bundle because its joint layer is smooth and thin due to low degree of Be diffusion. The microstructures of brazed layer using Ti{sub 1-y} Be{sub y} alloy, however, a solid-solution layer composed with Zr and Ti is formed toward the Zr cladding sheath and many of Zr is detected in the joint lever. 20 refs., 8 tabs., 23 figs. (author)

  4. Electrode activation and passivation of solid oxide fuel cell electrodes

    DEFF Research Database (Denmark)

    Koch, Søren; Mogensen, Mogens Bjerg; Hendriksen, P.V.

    2006-01-01

    The performance of anode-supported cells with a composite LSM-YSZ cathode and an LSM current collector was investigated. Over the first 48 hours, after the application of a constant current, the cell voltage was observed to increase by up to 20%. When the current was switched off, the cell...... resistance increased significantly over the next four days at open circuit conditions. Apparently, at OCV conditions cell passivation occurs. The cell gradually reactivates, once the current is switched on again. Part of this activation/passivation process is fast enough to influence the resistance...... of the cell during i-V measurements (over less than 1 hour) and a considerable hysteresis is observed in the cell voltage during these measurements. Impedance spectroscopy was used to investigate the activation/passivation process. It was found that the series resistance and the part of the polarisation...

  5. Development of a Safeguards Verification Method and Instrument to Detect Pin Diversion from Pressurized Water Reactor (PWR) Spent Fuel Assemblies Phase I Study

    Energy Technology Data Exchange (ETDEWEB)

    Ham, Y S; Sitaraman, S

    2008-12-24

    A novel methodology to detect diversion of spent fuel from Pressurized Water Reactors (PWR) has been developed in order to address a long unsolved safeguards verification problem for international safeguards community such as International Atomic Energy Agency (IAEA) or European Atomic Energy Community (EURATOM). The concept involves inserting tiny neutron and gamma detectors into the guide tubes of a spent fuel assembly and measuring the signals. The guide tubes form a quadrant symmetric pattern in the various PWR fuel product lines and the neutron and gamma signals from these various locations are processed to obtain a unique signature for an undisturbed fuel assembly. Signatures based on the neutron and gamma signals individually or in a combination can be developed. Removal of fuel pins from the assembly will cause the signatures to be visibly perturbed thus enabling the detection of diversion. All of the required signal processing to obtain signatures can be performed on standard laptop computers. Monte Carlo simulation studies and a set of controlled experiments with actual commercial PWR spent fuel assemblies were performed and validated this novel methodology. Based on the simulation studies and benchmarking measurements, the methodology developed promises to be a powerful and practical way to detect partial defects that constitute 10% or more of the total active fuel pins. This far exceeds the detection threshold of 50% missing pins from a spent fuel assembly, a threshold defined by the IAEA Safeguards Criteria. The methodology does not rely on any operator provided data like burnup or cooling time and does not require movement of the fuel assembly from the storage rack in the spent fuel pool. A concept was developed to build a practical field device, Partial Defect Detector (PDET), which will be completely portable and will use standard radiation measuring devices already in use at the IAEA. The use of the device will not require any information provided

  6. High Temperature Solid Oxide Fuel Cell Generator Development

    Energy Technology Data Exchange (ETDEWEB)

    Joseph Pierre

    2007-09-30

    This report describes the results of the tubular SOFC development program from August 22, 1997 to September 30, 2007 under the Siemens/U.S. Department of Energy Cooperative Agreement. The technical areas discussed include cell manufacturing development, cell power enhancement, SOFC module and system cost reduction and technology advancement, and our field unit test program. Whereas significant progress has been made toward commercialization, significant effort remains to achieve our cost, performance and reliability targets for successful commercialization.

  7. Nuclear fuel cycle and sustainable development: strategies for the future

    Energy Technology Data Exchange (ETDEWEB)

    Bouchard, J

    2004-07-01

    In this presentation, the author aims to define the major role of the nuclear energy in the future, according a sustainable development scenario. The today aging park and the new Generation IV technologies are presented. The transition scenario from Pu mono-recycling in PWRs to actinide global recycling in fast neutron Gen IV systems is also developed. Closed cycles and fast reactors appear as the appropriate answer to sustainable objectives in a vision of a large expansion. (A.L.B.)

  8. Fuel Cell Seminar, 1992: Program and abstracts

    Energy Technology Data Exchange (ETDEWEB)

    1992-12-31

    This year`s theme, ``Fuel Cells: Realizing the Potential,`` focuses on progress being made toward commercial manufacture and use of fuel cell products. Fuel cell power plants are competing for market share in some applications and demonstrations of market entry power plants are proceeding for additional applications. Development activity on fuel cells for transportation is also increasing; fuel cell products have potential in energy and transportation industries, with very favorable environmental impacts. This Seminar has the purpose of fostering communication by providing a forum for the international community interested in development, application, and business opportunities related fuel cells. Over 190 technical papers are included, the majority being processed for the data base.

  9. High-pressure coal fuel processor development. Task 1, Proof of principle testing

    Energy Technology Data Exchange (ETDEWEB)

    Greenhalgh, M.L.

    1992-11-01

    The objective of Subtask 1.1 Engine Feasibility was to conduct research needed to establish the technical feasibility of ignition and stable combustion of directly injected, 3,000 psi, low-Btu gas with glow plug ignition assist at diesel engine compression ratios. This objective was accomplished by designing, fabricating, testing and analyzing the combustion performance of synthesized low-Btu coal gas in a single-cylinder test engine combustion rig located at the Caterpillar Technical Center engine lab in Mossville, Illinois. The objective of Subtask 1.2 Fuel Processor Feasibility was to conduct research needed to establish the technical feasibility of air-blown, fixed-bed, high-pressure coal fuel processing at up to 3,000 psi operating pressure, incorporating in-bed sulfur and particulate capture. This objective was accomplished by designing, fabricating, testing and analyzing the performance of bench-scale processors located at Coal Technology Corporation (subcontractor) facilities in Bristol, Virginia. These two subtasks were carried out at widely separated locations and will be discussed in separate sections of this report. They were, however, independent in that the composition of the synthetic coal gas used to fuel the combustion rig was adjusted to reflect the range of exit gas compositions being produced on the fuel processor rig. Two major conclusions resulted from this task. First, direct injected, ignition assisted Diesel cycle engine combustion systems can be suitably modified to efficiently utilize these low-Btu gas fuels. Second, high pressure gasification of selected run-of-the-mine coals in batch-loaded fuel processors is feasible. These two findings, taken together, significantly reduce the perceived technical risks associated with the further development of the proposed coal gas fueled Diesel cycle power plant concept.

  10. Overview of the International R&D Recycling Activities of the Nuclear Fuel Cycle

    Energy Technology Data Exchange (ETDEWEB)

    Patricia Paviet-Hartmann

    2012-10-01

    Nuclear power has demonstrated over the last 30 years its capacity to produce base-load electricity at a low, predictable and stable cost due to the very low economic dependence on the price of uranium. However the management of used nuclear fuel remains the “Achilles’ Heel” of this energy source since the storage of used nuclear fuel is increasing as evidenced by the following number with 2,000 tons of UNF produced each year by the 104 US nuclear reactor units which equates to a total of 62,000 spent fuel assemblies stored in dry cask and 88,000 stored in pools. Two options adopted by several countries will be presented. The first one adopted by Europe, Japan and Russia consists of recycling the used nuclear fuel after irradiation in a nuclear reactor. Ninety six percent of uranium and plutonium contained in the spent fuel could be reused to produce electricity and are worth recycling. The separation of uranium and plutonium from the wastes is realized through the industrial PUREX process so that they can be recycled for re-use in a nuclear reactor as a mixed oxide (MOX) fuel. The second option undertaken by Finland, Sweden and the United States implies the direct disposal of used nuclear fuel into a geologic formation. One has to remind that only 30% of the worldwide used nuclear fuel are currently recycled, the larger part being stored (90% in pool) waiting for scientific or political decisions. A third option is emerging with a closed fuel cycle which will improve the global sustainability of nuclear energy. This option will not only decrease the volume amount of nuclear waste but also the long-term radiotoxicity of the final waste, as well as improving the long-term safety and the heat-loading of the final repository. At the present time, numerous countries are focusing on the R&D recycling activities of the ultimate waste composed of fission products and minor actinides (americium and curium). Several new chemical extraction processes, such as TRUSPEAK

  11. AECL/US INERI - Development of Inert Matrix Fuels for Plutonium and Minor Actinide Management in Power Reactors -- Fuel Requirements and Down-Select Report

    Energy Technology Data Exchange (ETDEWEB)

    William Carmack; Randy D. Lee; Pavel Medvedev; Mitch Meyer; Michael Todosow; Holly B. Hamilton; Juan Nino; Simon Philpot; James Tulenko

    2005-06-01

    The U.S. Advanced Fuel Cycle Program and the Atomic Energy Canada Ltd (AECL) seek to develop and demonstrate the technologies needed to minimize the overall Pu and minor actinides present in the light water reactor (LWR) nuclear fuel cycles. It is proposed to reuse the Pu from LWR spent fuel both for the energy it contains and to decrease the hazard and proliferation impact resulting from storage of the Pu and minor actinides. The use of fuel compositions with a combination of U and Pu oxide (MOX) has been proposed as a way to recycle Pu and/or minor actinides in LWRs. It has also been proposed to replace the fertile U{sup 238} matrix of MOX with a fertile-free matrix (IMF) to reduce the production of Pu{sup 239} in the fuel system. It is important to demonstrate the performance of these fuels with the appropriate mixture of isotopes and determine what impact there might be from trace elements or contaminants. Previous work has already been done to look at weapons-grade (WG) Pu in the MOX configuration [1][2] and the reactor-grade (RG) Pu in a MOX configuration including small (4000 ppm additions of Neptunium). This program will add to the existing database by developing a wide variety of MOX fuel compositions along with new fuel compositions called inert-matrix fuel (IMF). The goal of this program is to determine the general fabrication and irradiation behavior of the proposed IMF fuel compositions. Successful performance of these compositions will lead to further selection and development of IMF for use in LWRs. This experiment will also test various inert matrix material compositions with and without quantities of the minor actinides Americium and Neptunium to determine feasibility of incorporation into the fuel matrices for destruction. There is interest in the U.S. and world-wide in the investigation of IMF (inert matrix fuels) for scenarios involving stabilization or burn down of plutonium in the fleet of existing commercial power reactors. IMF offer the

  12. Molten carbonate fuel cell cathodes. Improvement of the electrocatalytic activity

    Energy Technology Data Exchange (ETDEWEB)

    Escudero, M.J.; Daza, L. [Dpto. Energia, CIEMAT, Av. Complutense 22, 28040 Madrid (Spain); Rodrigo, T. [Instituto de Catalisis y Petroleoquimica, CSIC, Campus Cantoblanco, 28049 Madrid (Spain)

    2005-10-30

    The purpose of this work is to improve the electrocatalytic activity of Li-Ni mixed oxides by the addition of rare earth oxides (cerium or lanthanum). The influence of cerium and lanthanum on the electrocatalytic activity of these compounds was investigated by means of electrochemical impedance spectroscopy (EIS). The stability of these compounds was studied in a mixture of 62% lithium carbonate and 38% potassium carbonate at high temperature under an atmosphere rich in carbon dioxide to accelerate their dissolution. The morphology and the crystalline structure of the samples were not affected by the incorporation of cerium or lanthanum. The samples impregnated with CeO{sub 2} or La{sub 2}O{sub 3} showed lower resistance to charger-transfer processes than the sample without earth rare oxides. Both cerium and lanthanum improved the charger-transfer processes for oxygen reduction in an atmosphere rich in carbon dioxide. The reason may be due to cerium oxide acting as oxygen donor, and lanthanum oxide capturing CO{sub 2}, and the partial pressure of carbon dioxide on the surface of electrode.

  13. Environmental taxes: an analysis of CIDE-fuel incident in the activities developed by the petroleum and natural gas industries; Tributos ambientais: uma analise da CIDE-combustiveis (Intervention Contribution in Economical Dominium) incidente nas atividades desenvolvidas pela industria do petroleo e do gas natural

    Energy Technology Data Exchange (ETDEWEB)

    Nunes, Cintia Bezerra de Melo Pereira; Azevedo, Flaviana Marques de [Agencia Nacional do Petroleo, Gas Natural e Biocombustiveis (ANP), Brasilia, DF (Brazil). Programa de Recursos Humanos em Direito do Petroleo, Gas Natural e Biocombustiveis

    2010-01-15

    the present study examine, initially, the intrinsic relationship between the environment and economic development envisaged in our Constitution, to then talk about the environmental taxation, limiting its fiscal and extra fiscal function, as well as treating the environmental taxes in the Brazilian legal system, with emphasis on the role of CIDE-fuels (Intervention Contribution in Economical Dominium), occurred on the imports or sales of: oil and its derivatives; natural gas and their derivatives; and ethanol, with a focus on environmental applications. Finally, we will examine the effective implementation of the CIDE-fuels in our country.

  14. China Needs More Oil to Fuel Its Economic Development

    Institute of Scientific and Technical Information of China (English)

    2003-01-01

    @@ The Chinese government has always insisted that development should be the theme of China's 10th Five-Year Plan (2001-2005) and the nation should take advantage of all opportunities to speed up development with economic construction as the focal point. However, economic researchers and energy experts were caught off guard by the surprisingly strong pace in oil imports despite their prediction of China's increasing need for crude oil. In addition, the doubledigit growth of oil-related industries such as automobile and transportation sectors has further resulted in rocketing demand for crude oil consumption and imports.

  15. Development and design of experiments optimization of a high temperature proton exchange membrane fuel cell auxiliary power unit with onboard fuel processor

    Science.gov (United States)

    Karstedt, Jörg; Ogrzewalla, Jürgen; Severin, Christopher; Pischinger, Stefan

    In this work, the concept development, system layout, component simulation and the overall DOE system optimization of a HT-PEM fuel cell APU with a net electric power output of 4.5 kW and an onboard methane fuel processor are presented. A highly integrated system layout has been developed that enables fast startup within 7.5 min, a closed system water balance and high fuel processor efficiencies of up to 85% due to the recuperation of the anode offgas burner heat. The integration of the system battery into the load management enhances the transient electric performance and the maximum electric power output of the APU system. Simulation models of the carbon monoxide influence on HT-PEM cell voltage, the concentration and temperature profiles within the autothermal reformer (ATR) and the CO conversion rates within the watergas shift stages (WGSs) have been developed. They enable the optimization of the CO concentration in the anode gas of the fuel cell in order to achieve maximum system efficiencies and an optimized dimensioning of the ATR and WGS reactors. Furthermore a DOE optimization of the global system parameters cathode stoichiometry, anode stoichiometry, air/fuel ratio and steam/carbon ratio of the fuel processing system has been performed in order to achieve maximum system efficiencies for all system operating points under given boundary conditions.

  16. Development of Nuclear Renewable Oil Shale Systems for Flexible Electricity and Reduced Fossil Fuel Emissions

    Energy Technology Data Exchange (ETDEWEB)

    Daniel Curtis; Charles Forsberg; Humberto Garcia

    2015-05-01

    We propose the development of Nuclear Renewable Oil Shale Systems (NROSS) in northern Europe, China, and the western United States to provide large supplies of flexible, dispatchable, very-low-carbon electricity and fossil fuel production with reduced CO2 emissions. NROSS are a class of large hybrid energy systems in which base-load nuclear reactors provide the primary energy used to produce shale oil from kerogen deposits and simultaneously provide flexible, dispatchable, very-low-carbon electricity to the grid. Kerogen is solid organic matter trapped in sedimentary shale, and large reserves of this resource, called oil shale, are found in northern Europe, China, and the western United States. NROSS couples electricity generation and transportation fuel production in a single operation, reduces lifecycle carbon emissions from the fuel produced, improves revenue for the nuclear plant, and enables a major shift toward a very-low-carbon electricity grid. NROSS will require a significant development effort in the United States, where kerogen resources have never been developed on a large scale. In Europe, however, nuclear plants have been used for process heat delivery (district heating), and kerogen use is familiar in certain countries. Europe, China, and the United States all have the opportunity to use large scale NROSS development to enable major growth in renewable generation and either substantially reduce or eliminate their dependence on foreign fossil fuel supplies, accelerating their transitions to cleaner, more efficient, and more reliable energy systems.

  17. Low emissions combustor development for an industrial gas turbine to utilize LCV fuel gas

    Energy Technology Data Exchange (ETDEWEB)

    Kelsall, G.J.; Smith, M.A. (British Coal Corp., Glos (United Kingdom). Coal Research Establishment); Cannon, M.F. (European Gas Turbines Ltd., Lincoln (United Kingdom). Aero and Technology Products)

    1994-07-01

    Advanced coal-based power generation systems such as the British Coal Topping Cycle offer the potential for high-efficiency electricity generation with minimum environmental impact. An important component of the Topping cycle program is the gas turbine, for which development of a combustion system to burn low calorific value coal derived fuel gas, at a turbine inlet temperature of 1,260 C (2,300 F), with minimum pollutant emissions, is a key R and D issue. A phased combustor development program is underway burning low calorific value fuel gas (3.6--4.1 MJ/m[sup 3]) with low emissions, particularly NO[sub x] derived from fuel-bound nitrogen. The first phase of the combustor development program has now been completed using a generic tubo-annular, prototype combustor design. Tests were carried out at combustor loading and Mach numbers considerably greater than the initial design values. Combustor performance at these conditions was encouraging. The second phase of the program is currently in progress. This will assess, initially, an improved variant of the prototype combustor operating at conditions selected to represent a particular medium sized industrial gas turbine. This combustor will also be capable of operating using natural gas as an auxiliary fuel, to suite the start-up procedure for the Topping Cycle. The paper presents the Phase 1 test program results for the prototype combustor. Design of the modified combustor for Phase 2 of the development program is discussed, together with preliminary combustor performance results.

  18. Developing and Implementing a Simple, Affordable Hydrogen Fuel Cell Laboratory in Introductory Chemistry

    Science.gov (United States)

    Klara, Kristina; Hou, Ning; Lawman, Allison; Wu, Liheng; Morrill, Drew; Tente, Alfred; Wang, Li-Qiong

    2014-01-01

    A simple, affordable hydrogen proton exchange membrane (PEM) fuel cell laboratory was developed through a collaborative effort between faculty and undergraduate students at Brown University. It has been incorporated into the introductory chemistry curriculum and successfully implemented in a class of over 500 students per academic year for over 3…

  19. Evaluation and Development of Chemical Kinetic Mechanism Reduction Scheme for Biodiesel and Diesel Fuel Surrogates

    DEFF Research Database (Denmark)

    Poon, Hiew Mun; Ng, Hoon Kiat; Gan, Suyin

    2013-01-01

    The aim of this study is to evaluate the existing chemical kinetic mechanism reduction techniques. From here, an appropriate reduction scheme was developed to create compact yet comprehensive surrogate models for both diesel and biodiesel fuels for diesel engine applications. The reduction techni...

  20. Developing and Implementing a Simple, Affordable Hydrogen Fuel Cell Laboratory in Introductory Chemistry

    Science.gov (United States)

    Klara, Kristina; Hou, Ning; Lawman, Allison; Wu, Liheng; Morrill, Drew; Tente, Alfred; Wang, Li-Qiong

    2014-01-01

    A simple, affordable hydrogen proton exchange membrane (PEM) fuel cell laboratory was developed through a collaborative effort between faculty and undergraduate students at Brown University. It has been incorporated into the introductory chemistry curriculum and successfully implemented in a class of over 500 students per academic year for over 3…

  1. Developments of Spent Nuclear Fuel Pyroprocessing Technology at Idaho National Laboratory

    Energy Technology Data Exchange (ETDEWEB)

    Michael F. Simpson

    2012-03-01

    This paper summarizes research in used fuel pyroprocessing that has been published by Idaho National Laboratory over the last decade. It includes work done both on treatment of Experimental Breeder Reactor-II and development of advanced technology for potential scale-up and commercialization. Collaborations with universities and other laboratories is included in the cited work.

  2. Annual report of Power Reactor and Nuclear Fuel Development Corporation, fiscal year 1996

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-09-01

    The experimental FBR `Joyo` has continued the irradiation operation at 100 MWt. After the 11th periodic inspection, the 30th cycle operation was carried out. The cumulative operation time as of the end of the fiscal year was 51,630 hours, and the cumulative heat output was about 4.2 billion kWh. The prototype FBR `Monju` has succeeded in electric power generation in August, 1995, but the sodium leak accident occurred in December, 1995. The elucidation of the cause of the sodium leak accident and the total inspection for the safety have been carried out. As for FBRs, the research and development of the reactor physics, the design of a large FBR, the equipment systems, the fuel and materials, the structures and the safety have been advanced. The ATR `Fugen` Power Station has continued the operation smoothly, and as of the end of the fiscal year, the total generated electric power was about 17.3 billion kWh, and the capacity factor was 66.3%. It boasts about the result of using MOX fuel. The exploration of uranium resources, the development of uranium conversion, uranium enrichment and plutonium fuel, the reprocessing of spent fuel, the development of environmental technology for radioactive waste, creative and innovative research and development, safety control and safety research and others are reported. (K.I.)

  3. Development of a Direct Ethanol Fuel Cell System with Anion Exchange Membranes

    Science.gov (United States)

    2015-01-15

    Fuel Cell System with Anion Exchange Membranes Report Title Based on the Phase I research results, we identified that carbon supported Pd-based catalysts...Report 22-0ct-2012- 21-Jan-2013 4. 1ITLE AND SUBTITLE 5a CONTRACT NUMBER Development of a Direct Ethanol Fuel Cell System with Anion Exchange...14. ABSTRACT Based on the Phase I research results, we identified that carbon supported Pd-based catalysts, such as Pd/C and PdRu!C, had better

  4. New Procedure to Develop Lumped Kinetic Models for Heavy Fuel Oil Combustion

    KAUST Repository

    Han, Yunqing

    2016-09-20

    A new procedure to develop accurate lumped kinetic models for complex fuels is proposed, and applied to the experim