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Sample records for fuel composition effects

  1. Fuel composition effects on HYPER core characteristics

    International Nuclear Information System (INIS)

    Han, Chi Young; Kim, Yong Nam; Kim, Jong Kyung

    2001-01-01

    At KAERI(Korea Atomic Energy Research Institute), a subcritical transmutation reactor is under development, named HYPER(Hybrid Power Extraction Reactor). For the HYPER system, a pyrochemical process is being considered for fuel reprocessing. Separated from the separation process, the fuel contains not only TRU but also the considerable percentages of impurity such as uranium nuclides and lanthanides. The amount of these impurities depends on strongly the refining efficiency of the reprocessing and may change the core characteristics. This paper has analyzed fuel composition effects on th HYPER core characteristics. Assuming various recovery factors of uranium and lanthanides, some dynamic parameters have been evaluated which are the neutron spectrum, the neutron reaction balance, the reactivity coefficients, the effective delayed neutron fraction, and the effective neutron lifetime

  2. Effects of variations in fuel pellet composition and size on mixed-oxide fuel pin performance

    International Nuclear Information System (INIS)

    Makenas, B.J.; Jensen, B.W.; Baker, R.B.

    1980-10-01

    Experiments have been conducted which assess the effects on fuel pin performance of specific minor variations from nominal in both fuel pellet size and pellet composition. Such pellets are generally referred to in the literature as rogue pellets. The effect of these rogue pellets on fuel pin and reactor performance is shown to be minimal

  3. Fuel composition effect on cathode airflow control in fuel cell gas turbine hybrid systems

    Science.gov (United States)

    Zhou, Nana; Zaccaria, Valentina; Tucker, David

    2018-04-01

    Cathode airflow regulation is considered an effective means for thermal management in solid oxide fuel cell gas turbine (SOFC-GT) hybrid system. However, performance and controllability are observed to vary significantly with different fuel compositions. Because a complete system characterization with any possible fuel composition is not feasible, the need arises for robust controllers. The sufficiency of robust control is dictated by the effective change of operating state given the new composition used. It is possible that controller response could become unstable without a change in the gains from one state to the other. In this paper, cathode airflow transients are analyzed in a SOFC-GT system using syngas as fuel composition, comparing with previous work which used humidified hydrogen. Transfer functions are developed to map the relationship between the airflow bypass and several key variables. The impact of fuel composition on system control is quantified by evaluating the difference between gains and poles in transfer functions. Significant variations in the gains and the poles, more than 20% in most cases, are found in turbine rotational speed and cathode airflow. The results of this work provide a guideline for the development of future control strategies to face fuel composition changes.

  4. Effect of variation in LPG composition on emissions and performance in a dual fuel diesel engine

    Energy Technology Data Exchange (ETDEWEB)

    H.E. Saleh [Mattaria, Helwan University, Cairo (Egypt). Department of Mechanical Power Engineering

    2008-10-15

    This paper investigates the effect of variation in LPG composition on emissions and performance characteristics in a dual fuel engine run on diesel fuel and five gaseous fuel of LPG with different composition. To quantify the best LPG composition for dual fuel operation especially in order to improve the exhaust emissions quality while maintaining high thermal efficiency comparable to a conventional diesel engine, a two-cylinder, naturally aspirated, four-stroke, DI diesel engine converted to run as pilot-injected dual fuel engine. The tests and data collection were performed under various conditions of load at constant engine speed. From the results, it is observed that the exhaust emissions and fuel conversion efficiency of the dual fuel engine are found to be affected when different LPG composition is used as higher butane content lead to lower NOx levels while higher propane content reduces CO levels. Fuel No. 3 (70% propane, 30% butane) with mass fraction 40% substitution of the diesel fuel was the best LPG composition in the dual fuel operation except that at part loads. Also, tests were made for fuel No. 3-diesel blend in the dual fuel operation at part loads to improve the engine performances and exhaust emissions by using the Exhaust Gas Recirculation (EGR) method. 26 refs., 15 figs., 5 tabs.

  5. Compositional Effects of Gasoline Fuels on Combustion, Performance and Emissions in Engine

    KAUST Repository

    Ahmed, Ahfaz

    2016-10-17

    Commercial gasoline fuels are complex mixtures of numerous hydrocarbons. Their composition differs significantly owing to several factors, source of crude oil being one of them. Because of such inconsistency in composition, there are multiple gasoline fuel compositions with similar octane ratings. It is of interest to comparatively study such fuels with similar octane ratings and different composition, and thus dissimilar physical and chemical properties. Such an investigation is required to interpret differences in combustion behavior of gasoline fuels that show similar knock characteristics in a cooperative fuel research (CFR) engine, but may behave differently in direct injection spark ignition (DISI) engines or any other engine combustion modes. Two FACE (Fuels for Advanced Combustion Engines) gasolines, FACE F and FACE G with similar Research and Motor Octane Numbers but dissimilar physical properties were studied in a DISI engine under two sets of experimental conditions; the first set involved early fuel injection to allow sufficient time for fuel-air mixing hence permitting operation similar to homogenous DISI engines, while the second set consists of advance of spark timings to attain MBT (maximum brake torque) settings. These experimental conditions are repeated across different load points to observe the effect of increasing temperature and pressure on combustion and emission parameters. The differences in various engine-out parameters are discussed and interpreted in terms of physical and thermodynamic properties of the fuels.

  6. EFFECT OF COMPOSITION OF FUEL CONTAINING BUTANOL ON WORKING PROCESS PARAMETERS OF DIESEL ENGINE

    Directory of Open Access Journals (Sweden)

    D. G. Hershan

    2017-01-01

    Full Text Available Computational researches the effect of composition of fuel containing butanol on working process parameters of 4ЧН 11/12,5 diesel engine on the external speed characteristic have been conducted. Nominal power is 140 kW at engine speed 2300 min–1. The engine is equipped with gas turbine pressure charging with intercooling of charging air, accumulator-type fuel-handling system. Calculations of the working process have been made in accordance with the developed computer program and models. Investigations have been carried out in two stages: without any changes in regulation of fuel-handling system and with cyclic fuel delivery that ensure such value of excess air factor at various operational modes which corresponds to the operation with diesel fuel. All the obtained results have been analyzed in the paper. The paper shows changes in mean indicated pressure, specific indicated fuel consumption, indicated efficiency, specific nitrogen oxides emissions for various modes in question while using 5, 10, 15, 20, 25 and 30 % mixture of diesel fuel with butanol. Dependences of parameters pertaining to diesel operation have been determined according to external speed characteristic for various mixtures and the obtained data make it possible to justify parameters of the fuel-handling system. It has been recommended to use a diesel fuel-butanol mixture containing 15 % of butanol without any changes in regulating and design engine parameters. It has been revealed that in order to improve parameters of the engine operational process mixture composition must be changed while changing the operational mode. An injector nozzle with a compound needle for the fuel-handling system has been developed and it allows to change fuel composition according to engine operational mode.

  7. Fuel effects on the stability of turbulent flames with compositionally inhomogeneous inlets

    KAUST Repository

    Guiberti, T. F.

    2016-10-11

    This paper reports an analysis of the influence of fuels on the stabilization of turbulent piloted jet flames with inhomogeneous inlets. The burner is identical to that used earlier by the Sydney Group and employs two concentric tubes within the pilot stream. The inner tube, carrying fuel, can be recessed, leading to a varying degree of inhomogeneity in mixing with the outer air stream. Three fuels are tested: dimethyl ether (DME), liquefied petroleum gas (LPG), and compressed natural gas (CNG). It is found that improvement in flame stability at the optimal compositional inhomogeneity is highest for CNG and lowest for DME. Three possible reasons for this different enhancement in stability are investigated: mixing patterns, pilot effects, and fuel chemistry. Numerical simulations realized in the injection tube highlight similarities and differences in the mixing patterns for all three fuels and demonstrate that mixing cannot explain the different stability gains. Changing the heat release rates from the pilot affects the three fuels in similar ways and this also implies that the pilot stream is unlikely to be responsible for the observed differences. Fuel reactivity is identified as a key factor in enhancing stability at some optimal compositional inhomogeneity. This is confirmed by inference from joint images of PLIF-OH and PLIF-CHO, collected at a repetition rate of 10kHz in turbulent flames of DME, and from one-dimensional calculations of laminar flames using detailed chemistry for DME, CNG, and LPG.

  8. Effect of Fuel Composition on Particulate Matter Emissions from a Gasoline Direct Injection Engine

    Science.gov (United States)

    Smallwood, Bryden Alexander

    The effects of fuel composition on reducing PM emissions were investigated using a Ford Focus wall-guided gasoline direct injection engine (GDI). Initial results with a 65% isooctane and 35% toluene blend showed significant reductions in PM emissions. Further experiments determined that this decrease was due to a lack of light-end components in that fuel blend. Tests with pentane content lower than 15% were found to have PN concentrations 96% lower than tests with 20% pentane content. This indicates that there is a shift in mode of soot production. Pentane significantly increases the vapour pressure of the fuel blend, potentially resulting in surface boiling, less homogeneous mixtures, or decreased fuel rebound from the piston. PM mass measurements and PN Index values both showed strong correlations with the PN concentration emissions. In the gaseous exhaust, THC, pentane, and 1,3 butadiene showed strong correlations with the PM emissions.

  9. Effect of fission yield libraries on the irradiated fuel composition in Monte Carlo depletion calculations

    International Nuclear Information System (INIS)

    Mitenkova, E.; Novikov, N.

    2014-01-01

    Improving the prediction of radiation parameters and reliability of fuel behaviour under different irradiation modes is particularly relevant for new fuel compositions, including recycled nuclear fuel. For fast reactors there is a strong dependence of nuclide accumulations on the nuclear data libraries. The effect of fission yield libraries on irradiated fuel is studied in MONTEBURNS-MCNP5-ORIGEN2 calculations of sodium fast reactors. Fission yield libraries are generated for sodium fast reactors with MOX fuel, using ENDF/B-VII.0, JEFF3.1, original library FY-Koldobsky, and GEFY 3.3 as sources. The transport libraries are generated from ENDF/B-VII.0 and JEFF-3.1. Analysis of irradiated MOX fuel using different fission yield libraries demonstrates the considerable spread in concentrations of fission products. The discrepancies in concentrations of inert gases being ∼25%, up to 5 times for stable and long-life nuclides, and up to 10 orders of magnitude for short-lived nuclides. (authors)

  10. Fuel composition effect on the electrostatically-driven atomization of bio-butanol containing engine fuel blends

    International Nuclear Information System (INIS)

    Agathou, Maria S.; Kyritsis, Dimitrios C.

    2012-01-01

    Highlights: ► Sprays of alcohol-containing blends are amenable to electrostatic manipulation. ► Monodispersion is non-achievable for conditions pertaining to automotive applications. ► Electrical conductivity and surface tension do not determine fully the spray behavior. ► Non-dimensional analysis was performed to classify flow regimes for each blend. ► We numbers revealed the possibility of droplet secondary break-up. - Abstract: Electrostatically assisted sprays of three fuel blends of bio-butanol, ethanol and heptane were studied experimentally. Mixture composition was selected such that electrical conductivity and surface tension were kept constant for all three mixtures. In this manner, the effect of fuel composition was investigated in a context that broadens the classical focus on the effective decrease of surface tension through the action of electrostatic fields. High-speed visualization was used in order to capture e-spray morphology. In addition, probability density functions of the e-spray droplet size and velocity were measured using Phase-Doppler Anemometry for a variety of flow rates and applied voltages. The dependence of droplet average diameter on both flow rate and applied electric field was highlighted. Polydisperse sprays were observed which was rationalized through the calculation of droplet Weber numbers that pointed to the possibility of a secondary droplet break-up.

  11. Compositional effects on PAH and soot formation in counterflow diffusion flames of gasoline surrogate fuels

    KAUST Repository

    Park, Sungwoo

    2017-02-05

    Gasoline surrogate fuels are widely used to understand the fundamental combustion properties of complex refinery gasoline fuels. In this study, the compositional effects on polycyclic aromatic hydrocarbons (PAHs) and soot formation were investigated experimentally for gasoline surrogate mixtures comprising n-heptane, iso-octane, and toluene in counterflow diffusion flames. A comprehensive kinetic model for the gasoline surrogate mixtures was developed to accurately predict the fuel oxidation along with the formation of PAHs and soot in flames. This combined model was first tested against ignition delay times and laminar burning velocities data. The proposed model for the formation and growth of PAHs up to coronene (C24H12) was based on previous studies and was tested against existing and present new experimental data. Additionally, in the accompanied soot model, PAHs with sizes larger than (including) pyrene were used for the inception of soot particles, followed by particle coagulations and PAH condensation/chemical reactions on soot surfaces. The major pathways for the formation of PAHs were also identified for the surrogate mixtures. The model accurately captures the synergistic PAH formation characteristics observed experimentally for n-heptane/toluene and iso-octane/toluene binary mixtures. Furthermore, the present experimental and modeling results also elucidated different trends in the formation of larger PAHs and soot between binary n-heptane/iso-octane and ternary n-heptane/iso-octane/toluene mixtures. Propargyl radicals (C3H3) were shown to be important in the formation and growth of PAHs for n-heptane/iso-octane mixtures when the iso-octane concentration increased; however, reactions involving benzyl radicals (C6H5CH2) played a significant role in the formation of PAHs for n-heptane/iso-octane/toluene mixtures. These results indicated that the formation of PAHs and subsequently soot was strongly affected by the composition of gasoline surrogate mixtures.

  12. Compositional effects on PAH and soot formation in counterflow diffusion flames of gasoline surrogate fuels

    KAUST Repository

    Park, Sungwoo; Wang, Yu; Chung, Suk-Ho; Sarathy, Mani

    2017-01-01

    Gasoline surrogate fuels are widely used to understand the fundamental combustion properties of complex refinery gasoline fuels. In this study, the compositional effects on polycyclic aromatic hydrocarbons (PAHs) and soot formation were investigated experimentally for gasoline surrogate mixtures comprising n-heptane, iso-octane, and toluene in counterflow diffusion flames. A comprehensive kinetic model for the gasoline surrogate mixtures was developed to accurately predict the fuel oxidation along with the formation of PAHs and soot in flames. This combined model was first tested against ignition delay times and laminar burning velocities data. The proposed model for the formation and growth of PAHs up to coronene (C24H12) was based on previous studies and was tested against existing and present new experimental data. Additionally, in the accompanied soot model, PAHs with sizes larger than (including) pyrene were used for the inception of soot particles, followed by particle coagulations and PAH condensation/chemical reactions on soot surfaces. The major pathways for the formation of PAHs were also identified for the surrogate mixtures. The model accurately captures the synergistic PAH formation characteristics observed experimentally for n-heptane/toluene and iso-octane/toluene binary mixtures. Furthermore, the present experimental and modeling results also elucidated different trends in the formation of larger PAHs and soot between binary n-heptane/iso-octane and ternary n-heptane/iso-octane/toluene mixtures. Propargyl radicals (C3H3) were shown to be important in the formation and growth of PAHs for n-heptane/iso-octane mixtures when the iso-octane concentration increased; however, reactions involving benzyl radicals (C6H5CH2) played a significant role in the formation of PAHs for n-heptane/iso-octane/toluene mixtures. These results indicated that the formation of PAHs and subsequently soot was strongly affected by the composition of gasoline surrogate mixtures.

  13. Effects of actinide compositional variability in the US spent fuel inventory on partitioning-transmutation systems

    International Nuclear Information System (INIS)

    Ludwig, S.B.; Michaels, G.E.; Hanson, B.D.

    1992-01-01

    Partitioning and transmutation (P-T) is an advanced waste management concept by which certain undesirable nuclides in spent fuel are first isolated (partitioned) and later destroyed (transmuted) in a nuclear reactor or other transmutation device. There are wide variabilities in the nuclide composition of spent fuel. This implies that there will also be wide variabilities in the transmutation device feed. As a waste management system, P-T must be able to accept (all) spent fuel. Variability of nuclide composition (i.e., the feed material for transmutation devices) may be important because virtually all transmutation systems propose to configure transuranic (TRU) nuclides recovered from discharged lightwater reactor (LWR) spent fuel in critical or near-critical cores. To date, all transmutation system core analyses assume invariant nuclide concentrations for startup and recycle cores. Using the US Department of Energy's (DOE's) Characteristics Data Base (CDB) and the ORIGEN2 computer code, the current and projected spent fuel discharges until the year 2016 have been categorized according to combinations of fuel burnup, initial enrichment, fuel age (cooling time) and reactor type (boiling-water or pressurized-water reactors). The variability of the infinite multiplication factor (k ∞ ) is calculated for both fast (ALMR) and thermal (accelerator-based) transmuter systems

  14. Effect of chemical composition on corrosion resistance of Zircaloy fuel cladding tube for BWR

    International Nuclear Information System (INIS)

    Inagaki, Masahisa; Akahori, Kimihiko; Kuniya, Jirou; Masaoka, Isao; Suwa, Masateru; Maru, Akira; Yasuda, Teturou; Maki, Hideo.

    1990-01-01

    Effects of Fe and Ni contents on nodular corrosion susceptibility and hydrogen pick-up of Zircaloy were investigated. Total number of 31 Zr alloys having different chemical compositions; five Zr-Sn-Fe-Cr alloys, eight Zr-Sn-Fe-Ni alloys and eighteen Zr-Sn-Fe-Ni-Cr alloys, were melted and processed to thin plates for the corrosion tests in the environments of a high temperature (510degC) steam and a high temperature (288degC) water. In addition, four 450 kg ingots of Zr-Sn-Fe-Ni-Cr alloys were industrially melted and BWR fuel cladding tubes were manufactured through a current material processing sequence to study their producibility, tensile properties and corrosion resistance. Nodular corrosion susceptibility decreased with increasing Fe and Ni contents of Zircaloys. It was seen that the improved Zircaloys having Fe and Ni contents in the range of 0.30 [Ni]+0.15[Fe]≥0.045 (w%) showed no susceptibility to nodular corrosion. An increase of Fe content resulted in a decrease of hydrogen pick-up fraction in both steam and water environments. An increase of Fe and Ni content of Zircaloys in the range of Fe≤0.25 w% and Ni≤0.1 w% did not cause the changes in tensile properties and fabricabilities of fuel cladding tube. The fuel cladding tube of improved Zircaloy, containing more amount of Fe and Ni than the upper limit of Zircaloy-2 specification showed no susceptibility to nodular corrosion even in the 530degC steam test. (author)

  15. Physicochemical effects of varying fuel composition on knock characteristics of natural gas mixtures

    NARCIS (Netherlands)

    Gersen, Sander; van Essen, Martijn; van Dijk, Gerco; Levinsky, Howard

    2014-01-01

    The physicochemical origins of how changes in fuel composition affect autoignition of the end gas, leading to engine knock, are analyzed for a natural gas engine. Experiments in a lean-burn, high-speed medium-BMEP gas engine are performed using a reference natural gas with systematically varied

  16. Effect of fuel composition on poly aromatic hydrocarbons in particulate matter from DI diesel engine; Particulate chu no PAH ni oyobosu nenryo sosei no eikyo

    Energy Technology Data Exchange (ETDEWEB)

    Tanaka, S; Tatani, T; Yoshida, H; Takizawa, H; Miyoshi, K; Ikebe, H [COSMO Research Institute, Tokyo (Japan)

    1997-10-01

    The effect of fuel composition on poly aromatic hydrocarbons (PAH) in particulate matter from DI diesel engine was investigated by using deeply desulfurized fuel and model fuel which properties are not interrelated. It was found that the deeply desulfurized fuel have effect on reducing PAH emissions. Furthermore, it was suggested that poly aromatics in the fuel affect PAH emissions and the influence of tri-aromatics in the fuel was promoted by the coexistence of mono-aromatics or naphthene. PAH formation scheme from each fuel component was proposed by chemical thermodynamic data. 4 refs., 8 figs., 3 tabs.

  17. Effect of composition on the stability and inhibitor response of jet fuels

    Energy Technology Data Exchange (ETDEWEB)

    Nixon, A C; Thorpe, R E

    1956-08-01

    The gas oil portion of jet fuels (that part boiling above 177/sup 0/C (350/sup 0/F)) was separated into compound type fractions by distillation followed by chromatography on silica gel and alumina. The separated fractions were analyzed chemically, by ultraviolet and infrared spectroscopy, and by mass spectrometry. The storage stability of the fractions were determined by aging them at 43/sup 0/C, 70/sup 0/C, or 100/sup 0/C, followed by measurement of the soluble and insoluble gum. The stability of each fraction was then related to the composition of that fraction. The saturate fractions were very stable and did not form gum. The aromatics fractions were fairly stable. Olefins, particularly conjugated diolefins, gave high soluble gum values but formed relatively little insoluble gum. Aromatic olefins were very reactive and produced large amounts of both soluble and insoluble gum. Thiophenes were very unstable toward formation of both soluble and insoluble gum. Nitrogen compounds isolated from the cracked gas oils were mainly nitrogen bases and pyrroles. When the nitrogen bases were blended with a saturate fraction, they had no effect on the stability of the saturates. However, pyrroles were very unstable; addition of pyrroles to a saturate fraction caused formation of large quantities of soluble and insoluble gum.

  18. The effects of fuel characteristics and engine operating conditions on the elemental composition of emissions from heavy duty diesel buses

    Energy Technology Data Exchange (ETDEWEB)

    M.C.H. Lim; G.A. Ayoko; L. Morawska; Z.D. Ristovski; E.R. Jayaratne [Queensland University of Technology, Brisbane, Qld. (Australia). International Laboratory for Air Quality and Health, School of Physical and Chemical Sciences

    2007-08-15

    The effects of fuel characteristics and engine operating conditions on elemental composition of emissions from twelve heavy duty diesel buses have been investigated. Two types of diesel fuels - low sulfur diesel (LSD) and ultra low sulfur diesel (ULSD) fuels with 500 ppm and 50 ppm sulfur contents respectively and 3 driving modes corresponding to 25%, 50% and 100% power were used. Elements present in the tailpipe emissions were quantified by inductively coupled plasma mass spectrometry (ICPMS) and those found in measurable quantities included Mg, Ca, Cr, Fe, Cu, Zn, Ti, Ni, Pb, Be, P, Se, Ti and Ge. Multivariate analyses using multi-criteria decision making methods (MCDM), principal component analysis (PCA) and partial least squares (PLS) facilitated the extraction of information about the structure of the data. MCDM showed that the emissions of the elements were strongly influenced by the engine driving conditions while the PCA loadings plots showed that the emission factors of the elements were correlated with those of other pollutants such as particle number, total suspended particles, CO, CO{sub 2} and NOx. Partial least square analysis revealed that the emission factors of the elements were strongly dependent on the fuel parameters such as the fuel sulfur content, fuel density, distillation point and cetane index. Strong correlations were also observed between these pollutants and the engine power or exhaust temperature. The study provides insights into the possible role of fuel sulfur content in the emission of inorganic elements from heavy duty diesel vehicles. 39 refs., 1 fig., 4 tabs.

  19. Fuel Cell Electric Vehicle Composite Data Products | Hydrogen and Fuel

    Science.gov (United States)

    Cells | NREL Vehicle Composite Data Products Fuel Cell Electric Vehicle Composite Data Products The following composite data products (CDPs) focus on current fuel cell electric vehicle evaluations Cell Operation Hour Groups CDP FCEV 39, 2/19/16 Comparison of Fuel Cell Stack Operation Hours and Miles

  20. The Effect of the UO2/ZrO2 Composition on Fuel/Coolant Interaction

    International Nuclear Information System (INIS)

    Song, Jin Ho; Kim, Jong Hwan

    2005-01-01

    A series of experiments on fuel/coolant interaction (FCI) was performed in the TROI facility, where the composition of the mixture was varied. The compositions of the UO 2 and ZrO 2 mixture in weight percent were 50:50, 70:30, 80:20, and pure ZrO 2 . The responses of the system including the temperature of the pool of water in the test vessel, pressure and temperature of the containment vessel, and dynamic pressures and force were measured. In addition, high-speed movies were taken through the windows. The tests using corium with a 70:30 composition and pure zirconia resulted in a spontaneous energetic steam explosion, while the tests with other compositions did not lead to an energetic FCI. The debris size distribution and pressure and temperature responses clearly indicated the cases with an energetic explosion and the cases without an explosion. The high-speed movie taken during the FCI through the visible window clearly disclosed the outstanding phases of the FCI, which were the melt entry phase, the triggering phase, and the continued melt jet and expansion of the mixing zone phase

  1. Composite Solid Fuel: Research of Formation Parameters

    Directory of Open Access Journals (Sweden)

    Tabakaev Roman

    2016-01-01

    Full Text Available Involving of local low-grade fuels resources in fuel and energy balance is actual question of research in the present. In this paper the possibility of processing low-grade fuel in the solid fuel composite was considered. The aim of the work is to define the optimal parameters for formation of the solid composite fuel. A result of researches determined that dextrin content in the binder allows to obtain solid composite fuel having the highest strength. The drying temperature for the various fuels was determined: for pellets production was 20-80 °C, for briquettes – 20-40 °C.

  2. Compositional Effects of Gasoline Fuels on Combustion, Performance and Emissions in Engine

    KAUST Repository

    Ahmed, Ahfaz; Waqas, Muhammad; Naser, Nimal; Singh, Eshan; Roberts, William L.; Chung, Suk-Ho; Sarathy, Mani

    2016-01-01

    to interpret differences in combustion behavior of gasoline fuels that show similar knock characteristics in a cooperative fuel research (CFR) engine, but may behave differently in direct injection spark ignition (DISI) engines or any other engine combustion

  3. Composition heterogeneity analysis for DUPIC fuel(I) - Statistical analysis

    Energy Technology Data Exchange (ETDEWEB)

    Choi, Hang Bok [Korea Atomic Energy Research Institute, Taejon (Korea)

    1999-08-01

    The fuel composition heterogeneity effect on reactor performance parameters was assessed by refueling simulations for three DUPIC fuel options of fuel composition heterogeneity control: the fissile content adjustment, the reactivity control by slightly enriched and depleted uranium, and the reactivity control by natural uranium. For each DUPIC fuel option, the simulations were performed using 30 heterogeneous fuel types which were determined by the agglomerative hierarchical clustering method. The heterogeneity effect was considered during the refueling simulation by randomly selecting fuel types for the refueling operation. The refueling simulations of the heterogeneous core have shown that the key performance parameters such as the maximum channel power (MCP), maximum bundle power (MBP), and channel power peaking factor (CPPF) are close to those of the core that has single fuel type. For the three DUPIC fuel options, the uncertainties of MCP, MBP, and CPPF due to the fuel composition heterogeneity are less than 0.6, 1.5 and 0.8%, respectively, including the uncertainty of the group-average fuel property. This study has shown that the three DUPIC fuel options reduces the composition heterogeneity effectively and the zone power control system has a sufficient margin to adjust the perturbations cased by the fuel composition heterogeneity. 15 refs., 28 figs.,10 tabs. (Author)

  4. Effect of biodiesel fuel on "real-world", nonroad heavy duty diesel engine particulate matter emissions, composition and cytotoxicity.

    Science.gov (United States)

    Martin, Nathan; Lombard, Melissa; Jensen, Kirk R; Kelley, Patrick; Pratt, Tara; Traviss, Nora

    2017-05-15

    Biodiesel is regarded by many as a "greener" alternative fuel to petroleum diesel with potentially lower health risk. However, recent studies examining biodiesel particulate matter (PM) characteristics and health effects are contradictive, and typically utilize PM generated by passenger car engines in laboratory settings. There is a critical need to analyze diesel and biodiesel PM generated in a "real-world" setting where heavy duty-diesel (HDD) engines and commercially purchased fuel are utilized. This study compares the mass concentrations, chemical composition and cytotoxicity of real-world PM from combustion of both petroleum diesel and a waste grease 20% biodiesel blend (B20) at a community recycling center operating HDD nonroad equipment. PM was analyzed for metals, elemental/organic carbon (EC/OC), polycyclic aromatic hydrocarbons (PAHs), and nitro-polycyclic aromatic hydrocarbons (N-PAHs). Cytotoxicity in a human lung epithelial cell line (BEAS-2B) following 24h exposure to the real-world particles was also evaluated. On average, higher concentrations for both EC and OC were measured in diesel PM. B20 PM contained significantly higher levels of Cu and Mo whereas diesel PM contained significantly higher concentrations of Pb. Principal component analysis determined Mo, Cu, and Ni were the metals with the greatest loading factor, suggesting a unique pattern related to the B20 fuel source. Total PAH concentration during diesel fuel use was 1.9 times higher than during B20 operations; however, total N-PAH concentration was 3.3 times higher during B20 use. Diesel PM cytotoxicity was 8.5 times higher than B20 PM (pengine sources of metals, PAH and N-PAH species, comparing tailpipe PM vs. PM collected inside the equipment cabin. Results suggest PM generated from burning petroleum diesel in nonroad engines may be more harmful to human health, but the links between exposure, composition and toxicity are not straightforward. Copyright © 2016 Elsevier B.V. All rights

  5. Effects of Low Sulfur Fuel and a Catalyzed Particle Trap on the Composition and Toxicity of Diesel Emissions

    Science.gov (United States)

    McDonald, Jacob D.; Harrod, Kevin S.; Seagrave, JeanClare; Seilkop, Steven K.; Mauderly, Joe L.

    2004-01-01

    In this study we compared a “baseline” condition of uncontrolled diesel engine exhaust (DEE) emissions generated with current (circa 2003) certification fuel to an emissions-reduction (ER) case with low sulfur fuel and a catalyzed particle trap. Lung toxicity assessments (resistance to respiratory viral infection, lung inflammation, and oxidative stress) were performed on mice (C57Bl/6) exposed by inhalation (6 hr/day for 7 days). The engine was operated identically (same engine load) in both cases, and the inhalation exposures were conducted at the same exhaust dilution rate. For baseline DEE, this dilution resulted in a particle mass (PM) concentration of approximately 200 μg/m3 PM, whereas the ER reduced the PM and almost every other measured constituent [except nitrogen oxides (NOx)] to near background levels in the exposure atmospheres. These measurements included PM, PM size distribution, PM composition (carbon, ions, elements), NOx, carbon monoxide, speciated/total volatile hydrocarbons, and several classes of semi-volatile organic compounds. After exposure concluded, one group of mice was immediately sacrificed and assessed for inflammation and oxidative stress in lung homogenate. Another group of mice were intratracheally instilled with respiratory syncytial virus (RSV), and RSV lung clearance and inflammation was assessed 4 days later. Baseline DEE produced statistically significant biological effects for all measured parameters. The use of low sulfur fuel and a catalyzed trap either completely or nearly eliminated the effects. PMID:15345344

  6. Hot Surface Ignition of A Composite Fuel Droplet

    Directory of Open Access Journals (Sweden)

    Glushkov Dmitrii O.

    2015-01-01

    Full Text Available The present study examines the characteristics of conductive heating (up to ignition temperature of a composite fuel droplet based on coal, liquid petroleum products, and water. In this paper, we have established the difference between heat transfer from a heat source to a fuel droplet in case of conductive (hot surface and convective (hot gas heat supply. The Leidenfrost effect influences on heat transfer characteristics significantly due to the gas gap between a composite fuel droplet and a hot surface.

  7. Comparison of DUPIC fuel composition heterogeneity control methods

    Energy Technology Data Exchange (ETDEWEB)

    Choi, Hang Bok; Ko, Won Il [Korea Atomic Energy Research Institute, Taejon (Korea)

    1999-08-01

    A method to reduce the fuel composition heterogeneity effect on the core performance parameters has been studied for the DUPIC fuel which is made of spent pressurized water reactor (PWR) fuels by a dry refabrication process. This study focuses on the reactivity control method which uses either slightly enriched, depleted, or natural uranium to minimize the cost rise effect on the manufacturing of DUPIC fuel, when adjusting the excess reactivity of the spent PWR fuel. In order to reduce the variation of isotopic composition of the DUPIC fuel, the inter-assembly mixing operation was taken three times. Then, three options have been considered: reactivity control by slightly enriched and depleted uranium, reactivity control by natural uranium for high reactivity spent PWR fuels, and reactivity control by natural uranium for linear reactivity spent PWR fuels. The results of this study have shown that the reactivity of DUPIC fuel can be tightly controlled with the minimum amount of fresh uranium feed. For the reactivity control by slightly enriched and depleted uranium, all the spent PWR fuels can be utilized as the DUPIC fuel and the fraction of fresh uranium feed is 3.4% on an average. For the reactivity control by natural uranium, about 88% of spent PWR fuel can be utilized as the DUPIC fuel when the linear reactivity spent PWR fuels are used, and the amount of natural uranium feed needed to control the DUPIC fuel reactivity is negligible. 13 refs., 6 figs., 16 tabs. (Author)

  8. Effects of actinide compositional variability in the U.S. spent fuel inventory on partitioning-transmutation systems

    International Nuclear Information System (INIS)

    Ludwig, S.B.; Michaels, G.E.; Hanson, B.D.

    1993-01-01

    The partitioning and transmutation concept (P-T) has as a mission the reduction by many orders of magnitude of certain undesirable nuclides in the waste streams. Given that only a very small fiction of spent fuel can be rejected by a P-T enterprise, a P-T system must therefore be capable of accommodating a wide range of spent fuel characteristics. Variability of nuclide composition (i.e. the feed material for transmutation devices) may be important because virtually all transmutation systems propose to configure TRU nuclides recovered from discharged LWR fuel in critical or near-critical cores. To date, all transmutation system core analyses assume nonvariable nuclide concentrations for startup and recycle cores. Using the Department of Energy (DOES) Characteristic Data Base (CDB) and the ORIGEN2 computer code, the current and projected spent fuel discharges until the year 2016 have been categorized according to combinations of fuel burnup, initial enrichment, fuel age (cooling time) and reactor type (boiling-water or pressurized-water reactor). In addition to quantifying the variability of nuclide composition in current and projected LWR fuel discharge, the variability of the infinite multiplication factor (K ∞ ) is calculated for both fast (ALMR) and thermal (accelerator-based) transmuter systems. It is shown that actinide compositional variations are potentially significant and warrant further investigation. (authors)

  9. New Concept of Designing Composite Fuel for Fast Reactors with Closing Fuel Cycle

    International Nuclear Information System (INIS)

    Savchenko, A.; Vatulin, A.; Uferov, O.; Kulakov, G.; Sorokin, V.

    2013-01-01

    For fast reactors a novel type of promising composite U-PuO2 fuel is proposed which is based on dispersion fuel elements. Basic approach to fuel element development - separated operations of fabricating uranium meat fuel element and introducing into it Pu or MA dioxides powder, that results in minimizing dust forming operations in fuel element fabrication. Novel fuel features higher characteristics in comparison to metallic or MOX fuel its fabrication technology is readily accomplished and is environmentally clean. A possibility is demonstrated of fabricating coated steel claddings to protect from interaction with fuel and fission products when use standard rod type MOX or metallic U-Pu-Zr fuel. Novel approach to reprocessing of composite fuel is demonstrated, which allows to separate uranium from burnt plutonium as well as the newly generated fissile plutonium from burnt one without chemical processes, which simplifies the closing of the nuclear fuel cycle. Novel composite fuel combines the advantages of metallic and ceramic types of fuel and has high uranium density that allows also to implicate it in BREST types reactor with conversion ratio more than 1. Peculiarities of closing nuclear cycle with composite fuel are demonstrated that allows more effective re-usage of generated Pu as well as, minimizing r/a wastes by incineration of MA in specially developed IMF design

  10. Fuel effects on the stability of turbulent flames with compositionally inhomogeneous inlets

    KAUST Repository

    Guiberti, T. F.; Juddoo, M.; Lacoste, Deanna; Dunn, M. J.; Roberts, William L.; Masri, A. R.

    2016-01-01

    This paper reports an analysis of the influence of fuels on the stabilization of turbulent piloted jet flames with inhomogeneous inlets. The burner is identical to that used earlier by the Sydney Group and employs two concentric tubes within

  11. effect of blending on fuel gas composition of pyrolysed plastic wastes

    African Journals Online (AJOL)

    HOD

    heating rate favoured the production of non-condensable gases in HDPE but caused a persistent decrease in LDPE. ... distillation and separation techniques to obtain useful fractions ... for petro-chemical industries or used directly as a fuel.

  12. Composition and methods for improved fuel production

    Science.gov (United States)

    Steele, Philip H.; Tanneru, Sathishkumar; Gajjela, Sanjeev K.

    2015-12-29

    Certain embodiments of the present invention are configured to produce boiler and transportation fuels. A first phase of the method may include oxidation and/or hyper-acidification of bio-oil to produce an intermediate product. A second phase of the method may include catalytic deoxygenation, esterification, or olefination/esterification of the intermediate product under pressurized syngas. The composition of the resulting product--e.g., a boiler fuel--produced by these methods may be used directly or further upgraded to a transportation fuel. Certain embodiments of the present invention also include catalytic compositions configured for use in the method embodiments.

  13. Comparison of DUPIC fuel composition heterogeneity control methods

    International Nuclear Information System (INIS)

    Choi, Hang Bok; Ko, Won Il

    1999-08-01

    A method to reduce the fuel composition heterogeneity effect on the core performance parameters has been studied for the DUPIC fuel which is made of spent pressurized water reactor (PWR) fuels by a dry refabrication process. This study focuses on the reactivity control method which uses either slightly enriched, depleted, or natural uranium to minimize the cost rise effect on the manufacturing of DUPIC fuel, when adjusting the excess reactivity control by slightly enriched and depleted uranium, reactivity control by natural uranium for high reactivity spent PWR fuels, and reactivity control by natural uranium for linear reactivity spent PWR fuels. The results of this study have shown that the reactivity control by slightly enriched and depleted uranium, all the spent PWR fuels can be utilized as the DUPIC fuel and the fraction of fresh uranium feed is 3.4% on an average. For the reactivity control by natural uranium, about 88% of spent PWR fuel can be utilized as the DUPIC fuel when the linear reactivity spent PWR fuels are used, and the amount of natural uranium feed needed to control the DUPIC fuel reactivity is negligible. (author). 13 refs., 16 tabs., 6 figs

  14. Thermophysical properties of composite fuel based on T grade coal (Alardinskoe deposit) and timber industry wastes

    Science.gov (United States)

    Yankovsky, S. A.; Tolokolnikov, A. A.; Gubin, V. E.; Slyusarskiy, K. V.; Zenkov, A. V.

    2017-09-01

    Results of experimental studies of composite fuel thermal decomposition processes based on T grade coal (Alardinskoe deposit) and timber industry wastes (fine wood) are presented. C, H, N, S weight percentage of each component of composite fuel was determined experimentally. It has been established that with an increase in wood concentration up to 50% in composite fuel, its energy characteristics decrease by less than 3.6%, while the yield of fly ash is 39.7%. An effective composite fuel composition has been defined as 50%/50%. Results of performed experimental studies suggest that it is possible to use composite fuels based on coal and wood at thermal power plants.

  15. Investigating the effects of proton exchange membrane fuel cell conditions on carbon supported platinum electrocatalyst composition and performance

    Energy Technology Data Exchange (ETDEWEB)

    Patel, Anant; Artyushkova, Kateryna; Atanassov, Plamen; Colbow, Vesna; Dutta, Monica; Harvey, Davie; Wessel, Silvia

    2011-12-01

    Changes that carbon-supported platinum electrocatalysts undergo in a proton exchange membrane fuel cell environment were simulated by ex situ heat treatment of catalyst powder samples at 150 C and 100% relative humidity. In order to study modifications that are introduced to chemistry, morphology, and performance of electrocatalysts, XPS, HREELS and three-electrode rotating disk electrode experiments were performed. Before heat treatment, graphitic content varied by 20% among samples with different types of carbon supports, with distinct differences between bulk and surface compositions within each sample. Following the aging protocol, the bulk and surface chemistry of the samples were similar, with graphite content increasing or remaining constant and Pt-carbide decreasing for all samples. From the correlation of changes in chemical composition and losses in performance of the electrocatalysts, we conclude that relative distribution of Pt particles on graphitic and amorphous carbon is as important for electrocatalytic activity as the absolute amount of graphitic carbon present

  16. Investigating the effects of proton exchange membrane fuel cell conditions on carbon supported platinum electrocatalyst composition and performance

    Energy Technology Data Exchange (ETDEWEB)

    A. Patel; K. Artyushkova; P. Atanassov; V. Colbow; M. Dutta; D. Harvey; S. Wessel

    2012-04-30

    Changes that carbon-supported platinum electrocatalysts undergo in a proton exchange membrane fuel cell environment were simulated by ex situ heat treatment of catalyst powder samples at 150 C and 100% relative humidity. In order to study modifications that are introduced to chemistry, morphology, and performance of electrocatalysts, XPS, HREELS and three-electrode rotating disk electrode experiments were performed. Before heat treatment, graphitic content varied by 20% among samples with different types of carbon supports, with distinct differences between bulk and surface compositions within each sample. Following the aging protocol, the bulk and surface chemistry of the samples were similar, with graphite content increasing or remaining constant and Pt-carbide decreasing for all samples. From the correlation of changes in chemical composition and losses in performance of the electrocatalysts, we conclude that relative distribution of Pt particles on graphitic and amorphous carbon is as important for electrocatalytic activity as the absolute amount of graphitic carbon present

  17. Assessment of cold composite fuels for PWR

    Energy Technology Data Exchange (ETDEWEB)

    Coulon-Picard, E.; Agard, M.; Boulore, A.; Castelier, E.; Chabert, C.; Conti, A.; Frayssines, P.E.; Lechelle, J.; Maillard, S.; Matheron, P.; Pelletier, M.; Phelip, M.; Piluso, P.; Vaudano, A

    2009-06-15

    This study is devoted to evaluation of a new innovative micro structured fuel for future pressurized water reactor. This fuel would have potential to increase the safety margins, lowering fuel temperatures by adding a small fraction of a high conductivity second phase material in the oxide fuel phase. The behavior of this fuel in a standard rod has been modeled with finite element codes and was assessed for different aspects of the cycle as neutronic studies, thermal behavior, reprocessing and economics. Feasibility of fuels has been investigated with the fabrication and characterizations of the microstructure of composite fuels with powder metallurgy and HIP processes. First, a CERCER (Ceramic = UO{sub 2}- Ceramic matrix made of silicon carbide, SiC) fuel type has been investigated, the advantages of a ceramic being generally its transparency to neutrons and its high melting temperature. A first design of kernel type fuel was first chosen with a gap between the UO{sub 2} particles and the second phase material in order to avoid mechanical interaction between the two components. Due to lowering thermal conductivity of SiC under irradiation, this CERCER fuel did not allow a temperature gain compared to current fuel. No ceramic material seems to exhibit all required properties. Even beryllium oxide (BeO), which conductivity does not decrease with irradiation according to the literature, induces difficulties with ({alpha}, n) reactions and toxicity. The study then focused on Cermet fuels (Ceramic-Metal). The metal matrix must be transparent to neutrons and have a good thermal conductivity. Several materials have been considered such as zirconium alloys, austenitic and ferritic stainless steals and chromium based alloys. The heterogeneous composite fuels were modeled using the 3D/CASTM finite element code. From an economical and neutron point of view, it was important to keep a low fraction of metal phase, i.e. less than 10 % of Zr for example. However, the fuel

  18. Chemical composition and source of fine and nanoparticles from recent direct injection gasoline passenger cars: Effects of fuel and ambient temperature

    Science.gov (United States)

    Fushimi, Akihiro; Kondo, Yoshinori; Kobayashi, Shinji; Fujitani, Yuji; Saitoh, Katsumi; Takami, Akinori; Tanabe, Kiyoshi

    2016-01-01

    Particle number, mass, and chemical compositions (i.e., elemental carbon (EC), organic carbon (OC), elements, ions, and organic species) of fine particles emitted from four of the recent direct injection spark ignition (DISI) gasoline passenger cars and a port fuel injection (PFI) gasoline passenger car were measured under Japanese official transient mode (JC08 mode). Total carbon (TC = EC + OC) dominated the particulate mass (90% on average). EC dominated the TC for both hot and cold start conditions. The EC/TC ratios were 0.72 for PFI and 0.88-1.0 (average = 0.92) for DISI vehicles. A size-resolved chemical analysis of a DISI car revealed that the major organic components were the C20-C28 hydrocarbons for both the accumulation-mode particles and nanoparticles. Contribution of engine oil was estimated to be 10-30% for organics and the sum of the measured elements. The remaining major fraction likely originated from gasoline fuel. Therefore, it is suggested that soot (EC) also mainly originated from the gasoline. In experiments using four fuels at three ambient temperatures, the emission factors of particulate mass were consistently higher with regular gasoline than with premium gasoline. This result suggest that the high content of less-volatile compounds in fuel increase particulate emissions. These results suggest that focusing on reducing fuel-derived EC in the production process of new cars would effectively reduce particulate emission from DISI cars.

  19. Litter Species Composition and Topographic Effects on Fuels and Modeled Fire Behavior in an Oak-Hickory Forest in the Eastern USA.

    Directory of Open Access Journals (Sweden)

    Matthew B Dickinson

    Full Text Available Mesophytic species (esp. Acer rubrum are increasingly replacing oaks (Quercus spp. in fire-suppressed, deciduous oak-hickory forests of the eastern US. A pivotal hypothesis is that fuel beds derived from mesophytic litter are less likely than beds derived from oak litter to carry a fire and, if they do, are more likely to burn at lower intensities. Species effects, however, are confounded by topographic gradients that affect overstory composition and fuel bed decomposition. To examine the separate and combined effects of litter species composition and topography on surface fuel beds, we conducted a common garden experiment in oak-hickory forests of the Ohio Hills. Each common garden included beds composed of mostly oak and mostly maple litter, representative of oak- and maple-dominated stands, respectively, and a mixture of the two. Beds were replenished each fall for four years. Common gardens (N = 16 were established at four topographic positions (ridges, benches on south- and northeast-facing slopes, and stream terraces at each of four sites. Litter source and topographic position had largely independent effects on fuel beds and modeled fire dynamics after four years of development. Loading (kg m-2 of the upper litter layer (L, the layer that primarily supports flaming spread, was least in more mesic landscape positions and for maple beds, implying greater decomposition rates for those situations. Bulk density in the L layer (kg m-3 was least for oak beds which, along with higher loading, would promote fire spread and fireline intensity. Loading and bulk density of the combined fermentation and humic (FH layers were least on stream terrace positions but were not related to species. Litter- and FH-layer moistures during a 5-day dry-down period after a rain event were affected by time and topographic effects while litter source effects were not evident. Characteristics of flaming combustion determined with a cone calorimeter pointed to greater

  20. Litter Species Composition and Topographic Effects on Fuels and Modeled Fire Behavior in an Oak-Hickory Forest in the Eastern USA.

    Science.gov (United States)

    Dickinson, Matthew B; Hutchinson, Todd F; Dietenberger, Mark; Matt, Frederick; Peters, Matthew P

    2016-01-01

    Mesophytic species (esp. Acer rubrum) are increasingly replacing oaks (Quercus spp.) in fire-suppressed, deciduous oak-hickory forests of the eastern US. A pivotal hypothesis is that fuel beds derived from mesophytic litter are less likely than beds derived from oak litter to carry a fire and, if they do, are more likely to burn at lower intensities. Species effects, however, are confounded by topographic gradients that affect overstory composition and fuel bed decomposition. To examine the separate and combined effects of litter species composition and topography on surface fuel beds, we conducted a common garden experiment in oak-hickory forests of the Ohio Hills. Each common garden included beds composed of mostly oak and mostly maple litter, representative of oak- and maple-dominated stands, respectively, and a mixture of the two. Beds were replenished each fall for four years. Common gardens (N = 16) were established at four topographic positions (ridges, benches on south- and northeast-facing slopes, and stream terraces) at each of four sites. Litter source and topographic position had largely independent effects on fuel beds and modeled fire dynamics after four years of development. Loading (kg m-2) of the upper litter layer (L), the layer that primarily supports flaming spread, was least in more mesic landscape positions and for maple beds, implying greater decomposition rates for those situations. Bulk density in the L layer (kg m-3) was least for oak beds which, along with higher loading, would promote fire spread and fireline intensity. Loading and bulk density of the combined fermentation and humic (FH) layers were least on stream terrace positions but were not related to species. Litter- and FH-layer moistures during a 5-day dry-down period after a rain event were affected by time and topographic effects while litter source effects were not evident. Characteristics of flaming combustion determined with a cone calorimeter pointed to greater fireline

  1. Chemical analyses and calculation of isotopic compositions of high-burnup UO{sub 2} fuels and MOX fuels

    Energy Technology Data Exchange (ETDEWEB)

    Matsumura, Tetsuo; Sasahara, Akihiro [Central Research Inst. of Electric Power Industry, Tokyo (Japan)

    2001-08-01

    Chemical analysis activities of isotopic compositions of high-burnup UO{sub 2} fuels and MOX fuels in CRIEPI and calculation evaluation are reviewed briefly. C/E values of ORIGEN2, in which original libraries and JENDL-3.2 libraries are used, and other codes with chemical analysis data are reviewed and evaluated. Isotopic compositions of main U and Pu in fuels can be evaluated within 10% relative errors by suitable libraries and codes. Void ratio is effective parameter for C/E values in BWR fuels. JENDL-3.2 library shows remarkable improvement compared with original libraries in isotopic composition evaluations of FP nuclides. (author)

  2. Surface composition effect of nitriding Ni-free stainless steel as bipolar plate of polymer electrolyte fuel cell

    Energy Technology Data Exchange (ETDEWEB)

    Yu, Yang; Shironita, Sayoko [Nagaoka University of Technology, 1603-1, Kamitomioka, Nagaoka, Niigata 940-2188 (Japan); Nakatsuyama, Kunio [Nakatsuyama Heat Treatment Co., Ltd., 1-1089-10, Nanyou, Nagaoka, Niigata 940-1164 (Japan); Souma, Kenichi [Nagaoka University of Technology, 1603-1, Kamitomioka, Nagaoka, Niigata 940-2188 (Japan); Hitachi Industrial Equipment Systems Co., Ltd., 3 Kanda Neribei, Chiyoda, Tokyo 101-0022 (Japan); Umeda, Minoru, E-mail: mumeda@vos.nagaokaut.ac.jp [Nagaoka University of Technology, 1603-1, Kamitomioka, Nagaoka, Niigata 940-2188 (Japan)

    2016-12-01

    Graphical abstract: The anodic current densities in the passive region of nitrided SUS445-N stainless steel are lower than those of a non heat-treated SUS445 stainless steel and heat-treated SUS445-Ar stainless steel under an Ar atmosphere. It shows a better corrosion resistance for the SUS445 stainless steel after the nitriding heat treatment. - Highlights: • The nitriding heat treatment was carried out using Ni-free SUS445 stainless steel. • The corrosion resistance of the nitrided SUS445-N stainless steel was improved. • The structure of the nitrided SUS445-N stainless steel changed from α-Fe to γ-Fe. • The surface elemental components present in the steels affect the corrosion resistance. - Abstract: In order to increase the corrosion resistance of low cost Ni-free SUS445 stainless steel as the bipolar plate of a polymer electrolyte fuel cell, a nitriding surface treatment experiment was carried out in a nitrogen atmosphere under vacuum conditions, while an Ar atmosphere was used for comparison. The electrochemical performance, microstructure, surface chemical composition and morphology of the sample before and after the electrochemical measurements were investigated using linear sweep voltammetry (LSV), X-ray diffraction (XRD), glow discharge optical emission spectroscopy (GDS) and laser scanning microscopy (LSM) measurements. The results confirmed that the nitriding heat treatment not only increased the corrosion resistance, but also improved the surface conductivity of the Ni-free SUS445 stainless steel. In contrast, the corrosion resistance of the SUS445 stainless steel decreased after heat treatment in an Ar atmosphere. These results could be explained by the different surface compositions between these samples.

  3. Processing of carbon composite paper as electrode for fuel cell

    Energy Technology Data Exchange (ETDEWEB)

    Mathur, R.B.; Maheshwari, Priyanka H.; Dhami, T.L. [Carbon Technology Unit, National Physical Laboratory, New Delhi 110012 (India); Sharma, R.K.; Sharma, C.P. [Soft Polymeric Group, Division of Engineering Materials, National Physical Laboratory, New Delhi 110012 (India)

    2006-10-27

    The porous carbon electrode in a fuel cell not only acts as an electrolyte and a catalyst support, but also allows the diffusion of hydrogen fuel through its fine porosity and serves as a current-carrying conductor. A suitable carbon paper electrode is developed and possesses the characteristics of high porosity, permeability and strength along with low electrical resistivity so that it can be effectively used in proton-exchange membrane and phosphoric acid fuel cells. The electrode is prepared through a combination of two important techniques, viz., paper-making technology by first forming a porous chopped carbon fibre preform, and composite technology using a thermosetting resin matrix. The study reveals an interdependence of one parameter on another and how judicious choice of the processing conditions are necessary to achieve the desired characteristics. The current-voltage performance of the electrode in a unit fuel cell matches that of a commercially-available material. (author)

  4. Correlations among FBR core characteristics for various fuel compositions

    International Nuclear Information System (INIS)

    Maruyama, Shuhei; Ohki, Shigeo; Okubo, Tsutomu; Kawashima, Katsuyuki; Mizuno, Tomoyasu

    2012-01-01

    In the design of a fast breeder reactor (FBR) core for the light water reactor (LWR) to FBR transition stage, it is indispensable to grasp the effect of a wide range of fuel composition variations on the core characteristics. This study finds good correlations between burnup reactivity and safety parameters, such as the sodium void reactivity and Doppler coefficient, for various fuel compositions and determines the mechanisms behind these correlations with the aid of sensitivity analyses. It is clarified that the Doppler coefficient is actually correlated with the other core characteristics by considering the constraint imposed by the requirement of sustaining criticality on the fuel composition variations. These correlations make it easy to specify the various properties ranges for core reactivity control and core safety, which are important for core design in determining the core specifications and performance. They provide significant information for FBR core design for the transition stage. Moreover, as an application of the above-mentioned correlations, a simplified burnup reactivity index is developed for rapid and rational estimation of the core characteristic variations. With the use of this index and these correlations, the core characteristic variations can be estimated for various fuel compositions without repeating the core calculations. (author)

  5. Effect of fuel burnup on the mechanical safety coefficients

    International Nuclear Information System (INIS)

    Plyashkevich, V.Ju.; Sidorenko, V.D.; Shishkov, L.K.

    2001-01-01

    )In the paper the results of studies of changes in the process of campaign 'disturbances' of local heat flux and local fuel burnup, resulting from the 'mechanical' deviations in the composition and geometrical characteristics of fuel rods from the nominal are given. As example, the WWER-440 fuel assembly with burnable poisons used in the five-year fuel cycle is considered. The effect of deviations in fuel enrichment, fuel content, gadolinium content and geometrical size was studied (Authors)

  6. Effect of cesium salt of tungstophosphoric acid (Cs-TPA) on the properties of sulfonated polyether ether ketone (SPEEK) composite membranes for fuel cell applications

    Energy Technology Data Exchange (ETDEWEB)

    Dogan, Hacer; Inan, Tuelay Y.; Unveren, Elif [The Scientific and Technological Research Council of Turkey (TUeBiTAK), Marmara Research Center, Chemistry Institute, P.K. 21, 41470 Gebze-Kocaeli (Turkey); Kaya, Metin [DEMIRDOeKUeM A.S. 4 Eyluel Mah, ismet inoenue Cad. No:245 Bozueyuek/Bilecik (Turkey)

    2010-08-15

    We have prepared composite membranes for fuel cell applications. Cesium salt of tungstophosphoric acid (Cs-TPA) particles was synthesized by aqueous solutions of tungstophosphoric acid and cesium hydroxide and, Cs-TPA particles and sulfonated (polyether ether ketone) (SPEEK) with two sulfonation degrees (DS), 60 and 70%have been used. We examined both the effects of Cs-TPA in SPEEK membranes as functions of sulfonation degrees of SPEEK and the content of Cs-TPA. The performance of the composite membranes was evaluated in terms of water uptake, ion exchange capacity, proton conductivity, chemical stability, hydrolytic stability, thermal stability and methanol permeability. The morphology of the membranes was investigated with SEM micrographs. Increasing sulfonation degree of SPEEK from 60 to 70 caused agglomeration of the Cs-TPA particles. The methanol permeability was reduced to 4.7 x 10{sup -7} cm{sup 2}/s for SPEEK (DS: 60%)/Cs-TPA membrane with 10 wt.% Cs-TPA concentration, and acceptable proton conductivity of 1.3 x 10{sup -1} S/cm was achieved at 80 C under 100% RH. The weight loss at 900 C increased with the addition of inorganic particles, as expected. The hydrolytic stability of the SPEEK/Cs-TPA based composite membranes was improved with the incorporation of the Cs-TPA particles into the matrix. We also noted that SPEEK60/Cs-TPA composite membranes were hydrolytically more stable than SPEEK70/Cs-TPA composite membranes. On the other hand, Methanol, water vapor, and hydrogen permeability values of SPEEK60 composite membranes were found to be lower than that of Nafion {sup registered}. (author)

  7. Hybrid Composites for LH2 Fuel Tank Structure

    Science.gov (United States)

    Grimsley, Brian W.; Cano, Roberto J.; Johnston, Norman J.; Loos, Alfred C.; McMahon, William M.

    2001-01-01

    The application of lightweight carbon fiber reinforced plastics (CFRP) as structure for cryogenic fuel tanks is critical to the success of the next generation of Reusable Launch Vehicles (RLV). The recent failure of the X-33 composite fuel tank occurred in part due to microcracking of the polymer matrix, which allowed cryogen to permeate through the inner skin to the honeycomb core. As part of an approach to solve these problems, NASA Langley Research Center (LaRC) and Marshall Space Flight Center (MSFC) are working to develop and investigate polymer films that will act as a barrier to the permeation of LH2 through the composite laminate. In this study two commercially available films and eleven novel LaRC films were tested in an existing cryogenics laboratory at MSFC to determine the permeance of argon at room temperature. Several of these films were introduced as a layer in the composite to form an interleaved, or hybrid, composite to determine the effects on permeability. In addition, the effects of the interleaved layer thickness, number, and location on the mechanical properties of the composite laminate were investigated. In this initial screening process, several of the films were found to exhibit lower permeability to argon than the composite panels tested.

  8. Reforming petroleum-based fuels for fuel cell vehicles : composition-performance relationships

    International Nuclear Information System (INIS)

    Kopasz, J. P.; Miller, L. E.; Ahmed, S.; Devlin, P. R.; Pacheco, M.

    2001-01-01

    Onboard reforming of petroleum-based fuels, such as gasoline, may help ease the introduction of fuel cell vehicles to the marketplace. Although gasoline can be reformed, it is optimized to meet the demands of ICEs. This optimization includes blending to increase the octane number and addition of oxygenates and detergents to control emissions. The requirements for a fuel for onboard reforming to hydrogen are quite different than those for combustion. Factors such as octane number and flame speed are not important; however, factors such as hydrogen density, catalyst-fuel interactions, and possible catalyst poisoning become paramount. In order to identify what factors are important in a hydrocarbon fuel for reforming to hydrogen and what factors are detrimental, we have begun a program to test various components of gasoline and blends of components under autothermal reforming conditions. The results indicate that fuel composition can have a large effect on reforming behavior. Components which may be beneficial for ICEs for their octane enhancing value were detrimental to reforming. Fuels with high aromatic and naphthenic content were more difficult to reform. Aromatics were also found to have an impact on the kinetics for reforming of paraffins. The effects of sulfur impurities were dependent on the catalyst. Sulfur was detrimental for Ni, Co, and Ru catalysts. Sulfur was beneficial for reforming with Pt catalysts, however, the effect was dependent on the sulfur concentration

  9. Composite fuel behaviour under and after irradiation

    International Nuclear Information System (INIS)

    Dehaudt, P.; Mocellin, A.; Eminet, G.; Caillot, L.; Delette, G.; Bauer, M.; Viallard, I.

    1997-01-01

    Two kinds of composite fuels have been irradiated in the SILOE reactor. They are made of UO 2 particles dispersed in a molybdenum metallic (CERMET) or a MgAl 2 O 4 ceramic (CERCER) matrix. The irradiation conditions have allowed to reach a 50000 MWd/t U burn-up in these composite fuels after a hundred equivalent full power days long irradiation. The irradiation is controlled by a continuous measure of the pellet centre line temperature. It allows to have information about the TANOX rods thermal behaviour and the fuels thermal conductivities in comparing the centre line temperature versus linear power curves among themselves. Our results show that the CERMET centre line temperature is much lower than the CERCER and UO 2 ones: 520 deg. C against 980 deg. C at a 300W/cm linear power. After pin puncturing tests the rods are dismantled to recover each fuel pellet. In the CERCER case, the cladding peeling off has revealed that the fuel came into contact with the cladding and that some of the pellets were linked together. Optical microscopy observations show a changing of the MgAl 2 O 4 matrix state around the UO 2 particles at the pellets periphery. This transformation may have caused a swelling and would be at the origin of the pellet-cladding and the pellet-pellet interactions. No specific damage is seen after irradiation. The CERMET pellets are not cracked and remain as they were before irradiation. The CERCER crack network is slightly different from that observed in UO 2 . Kr retention was evaluated by annealing tests under vacuum at 1580 deg. C or 1700 deg. C for 30 minutes. The CERMET fission gas release is lower than the CERCER one. Inter- and intragranular fission gas bubbles are observed in the UO 2 particles after heat treatments. The CERCER pellet periphery has also cracked and the matrix has transformed again around UO 2 particles to present a granular and porous aspect. (author). 4 refs, 6 figs, 2 tabs

  10. Validation of spent nuclear fuel nuclide composition data using percentage differences and detailed analysis

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Man Cheol [Chung-Ang Univ., Seoul (Korea, Republic of). School of Energy Systems Engineering

    2017-06-15

    Nuclide composition data of spent nuclear fuels are important in many nuclear engineering applications. In reactor physics, nuclear reactor design requires the nuclide composition and the corresponding cross sections. In analyzing the radiological health effects of a severe accident on the public and the environment, the nuclide composition in the reactor inventory is among the important input data. Nuclide composition data need to be provided to analyze the possible environmental effects of a spent nuclear fuel repository. They will also be the basis for identifying the origin of unidentified spent nuclear fuels or radioactive materials.

  11. EXPERIMENTAL SENSOR OF THE BENZOETHANOL COMPOSITION FOR ENGINE FUEL SYSTEM

    Directory of Open Access Journals (Sweden)

    V. Bgantsev

    2017-12-01

    Full Text Available An important aspect of the economy of internal combustion engine on benzoethanol is the accuracy of regulation of the fuel-air mixture composition. This task is complicated by fluctuations in the composition of benzoethanol, depending on the refueling of the vehicle at various filling stations. In this connection, there is a need to control the composition of benzoethanol in the fuel system of the engine and adjust the fuel supply system. With this purpose, fuel systems are equipped with special sensors that generate a signal, depending on the alcohol content of the mixed fuel. In the article one of the design solutions of the experimental sensor of the benzoethanol composition and the results of its testing with fuels of various composition are given.

  12. Effects of microstructure and composition of anode Pt based electrocatalysts on performance of direct alcohol fuel cells

    Energy Technology Data Exchange (ETDEWEB)

    Jiang, L.; Li, H.; Yan, S.; Sun, G. [Dalian Inst. of Chemical Physics, Dalian (China). Direct Alcohol Fuel Cell Lab; Xin, Q. [Dalian Inst. of Chemical Physics, Dalian (China). Direct Alcohol Fuel Cell Lab; Dalian Inst. of Chemical Physics, Dalian (China). State Key Laboratory of Catalysis

    2008-07-01

    This paper reported on a study in which platinum (Pt)-based electrocatalysts were synthesized and characterized by XRD, TEM and EDS. The focus of the study was on the relationship between the microstructure and components of PtRu and PtSn catalysts and the performance of direct alcohol fuel cells (DAFCs). All of the Pt-based electrocatalysts were prepared by a modified polyol method. XRD patterns of the 2 catalysts showed that both catalysts have an fcc pattern of Pt. This was also confirmed by the shift of diffraction peaks of Pt in both catalysts. Electrochemical measurements were carried out using an EG and G model 273A potentiostat/galvanostat and a three-electrode test cell at room temperature. Membrane electrode assemblies (MEAs) were fabricated with a pair of stainless steel plates with parallel flow-fields. The MEAs were activated by 1 M methanol/ethanol at 75 degrees C for 3 hours before all the data were collected. The study showed that PtRu is active to methanol electrooxidation while PtSn is active to ethanol electrooxidation. Based on the above experimental analysis, it was determined that the dilatation of Pt lattice parameter is favourable for ethanol adsorption, while the suitable contract of Pt lattice parameter is favorable for methanol electrooxidation. Since Pt is more electronegative than Sn, the partial electrons of Sn atom could be transferred to Pt atom leading to filling of Pt d band. Although Ru is as electronegative as Pt, the electric effect of Pt and Ru may not be as pronounced. 4 refs., 4 figs.

  13. Improved Retrieval Technique of pin-wise composition for spent fuel recycling

    Energy Technology Data Exchange (ETDEWEB)

    Park, YunSeo; Kim, Myung Hyun [Kyung Hee University , Yongin (Korea, Republic of)

    2016-10-15

    New reutilization method which does not require fabrication processing was suggested and showed feasibility by Dr. Aung Tharn Daing. This new reutilization method is predict spent nuclear fuel pin composition, reconstruct new fuel assembly by spent nuclear pin, and directly reutilize in same PWR core. There are some limitation to predict spent nuclear fuel pin composition on his methodology such as spatial effect was not considered enough. This research suggests improving Dr. Aung Tharn Daing's retrieval technique of pin-wise composition. This new method classify fuel pin groups by its location effect in fuel assembly. Most of fuel pin composition along to burnup in fuel assembly is not highly dependent on location. However, compositions of few fuel pins where near water hole and corner of fuel assembly are quite different in same burnup. Required number of nuclide table is slightly increased from 3 to 6 for one fuel assembly with this new method. Despite of this little change, prediction of the pin-wise composition became more accurate. This new method guarantees two advantages than previous retrieving technique. First, accurate pin-wise isotope prediction is possible by considering location effect in a fuel assembly. Second, it requires much less nuclide tables than using full single assembly database. Retrieving technique of pin-wise composition can be applied on spent fuel management field useful. This technique can be used on direct use of spent fuel such as Dr. Aung Tharn Daing showed or applied on pin-wise waste management instead of conventional assembly-wise waste management.

  14. Effect of diesel fuel pollution on the lipid composition of some wide-spread Black sea algae and invertebrates

    Energy Technology Data Exchange (ETDEWEB)

    Nechev, J.T.; Stefanov, K.L.; Popov, S.S. [Inst. of Organic Chemistry with Centre of Phytochemistry, Bulgarian Academy of Sciences, Sofia (Bulgaria); Khotimchenko, S.V. [Inst. of Marine Biology, Russian Academy of Sciences (Russian Federation); Ivanova, A.P. [Inst. of Plant Physiology, Bulgarian Academy of Sciences, Sofia (Bulgaria); Dimitrova-Konaklieva, S.D. [Faculty of Pharmacy, Higher Medical School, Sofia (Bulgaria); Andreev, S. [Museum of Natural History, Bulgarian Academy of Sciences, Sofia (Bulgaria)

    2002-04-01

    Two green algae (Ulva rigida and Cladophora coelothrix), the mussel Mytilus galloprovincialis and the snail Rapana thomasiana from the Bulgarian Black Sea shore have been treated with diesel fuel (100 mg l{sup -1}) in an aquarium with sea-water for three days. The lipids and their fatty acid changes have been examined. Significant changes have been observed mainly in the polar lipids and in the saturation of the fatty acids. These changes appeared to be bigger in the evolutionary less advanced species from both groups of marine organisms - algae and invertebrates (Ulva rigida and Mytilus galloprovincialis respectively). The data obtained could be used for a biomonitoring of the pollution. (orig.)

  15. Solid recovered fuel: influence of waste stream composition and processing on chlorine content and fuel quality.

    Science.gov (United States)

    Velis, Costas; Wagland, Stuart; Longhurst, Phil; Robson, Bryce; Sinfield, Keith; Wise, Stephen; Pollard, Simon

    2012-02-07

    Solid recovered fuel (SRF) produced by mechanical-biological treatment (MBT) of municipal waste can replace fossil fuels, being a CO(2)-neutral, affordable, and alternative energy source. SRF application is limited by low confidence in quality. We present results for key SRF properties centered on the issue of chlorine content. A detailed investigation involved sampling, statistical analysis, reconstruction of composition, and modeling of SRF properties. The total chlorine median for a typical plant during summer operation was 0.69% w/w(d), with lower/upper 95% confidence intervals of 0.60% w/w(d) and 0.74% w/w(d) (class 3 of CEN Cl indicator). The average total chlorine can be simulated, using a reconciled SRF composition before shredding to limit for ash content marginally below the 20% w/w(d) deemed suitable for certain power plants; and a lower 95% confidence limit of net calorific value (NCV) at 14.5 MJ kg(ar)(-1). The data provide, for the first time, a high level of confidence on the effects of SRF composition on its chlorine content, illustrating interrelationships with other fuel properties. The findings presented here allow rational debate on achievable vs desirable MBT-derived SRF quality, informing the development of realistic SRF quality specifications, through modeling exercises, needed for effective thermal recovery.

  16. Fabrication of fuel elements on the basis of increased concentration fuel composition

    International Nuclear Information System (INIS)

    Alexandrov, A.B.; Afanasiev, V.L.; Enin, A.A.; Suprun, V.B.

    2004-01-01

    As a part of Russian Program RERTR Reduced Enrichment for Research and Test Reactors), at NCCP, Inc. jointly with the State Scientific Centre VNIINM the mastering in industrial environment of design and fabrication process of fuel elements (FE) with increased concentration fuel compositions is performed. Fuel elements with fuel composition on the basis of dioxide uranium with nearly 4 g/cm 3 fuel concentration have been produced thus confirming the principal possibility of fuel enrichment reduction down to 20% for research reactors which were built up according to the projects of the former USSR, by increasing the oxide fuel concentration in fuel assemblies (FAs). The form and geometrical dimensions of FEs and FAs shall remain unchanged, only uranium mass in FA shall be increased. (author)

  17. Isotopic composition of fission gases in LWR fuel

    International Nuclear Information System (INIS)

    Jonsson, T.

    2000-01-01

    Many fuel rods from power reactors and test reactors have been punctured during past years for determination of fission gas release. In many cases the released gas was also analysed by mass spectrometry. The isotopic composition shows systematic variations between different rods, which are much larger than the uncertainties in the analysis. This paper discusses some possibilities and problems with use of the isotopic composition to decide from which part of the fuel the gas was released. In high burnup fuel from thermal reactors loaded with uranium fuel a significant part of the fissions occur in plutonium isotopes. The ratio Xe/Kr generated in the fuel is strongly dependent on the fissioning species. In addition, the isotopic composition of Kr and Xe shows a well detectable difference between fissions in different fissile nuclides. (author)

  18. Corrosion of graphite composites in phosphoric acid fuel cells

    Science.gov (United States)

    Christner, L. G.; Dhar, H. P.; Farooque, M.; Kush, A. K.

    1986-01-01

    Polymers, polymer-graphite composites and different carbon materials are being considered for many of the fuel cell stack components. Exposure to concentrated phosphoric acid in the fuel cell environment and to high anodic potential results in corrosion. Relative corrosion rates of these materials, failure modes, plausible mechanisms of corrosion and methods for improvement of these materials are investigated.

  19. Homogeneous forming technology of composite materials and its application to dispersion nuclear fuel

    International Nuclear Information System (INIS)

    Hong, Soon Hyun; Ryu, Ho Jin; Sohn, Woong Hee; Kim, Chang Kyu

    1997-01-01

    Powder metallurgy processing technique of metal matrix composites is reviewed and its application to process homogeneous dispersion nuclear fuel is considered. The homogeneous mixing of reinforcement with matrix powders is very important step to process metal matrix composites. The reinforcement with matrix powders is very important step to process metal matrix composites. The reinforcement can be ceramic particles, whiskers or chopped fibers having high strength and high modulus. The blended powders are consolidated into billets and followed by various deformation processing, such as extrusion, forging, rolling or spinning into final usable shapes. Dispersion nuclear fuel is a class of metal matrix composite consisted of dispersed U-compound fuel particles and metallic matrix. Dispersion nuclear fuel is fabricated by powder metallurgy process such as hot pressing followed by hot extrusion, which is similar to that of SiC/Al metal matrix composite. The fabrication of homogeneous dispersion nuclear fuel is very difficult mainly due to the inhomogeneous mixing characteristics of the powders from quite different densities between uranium alloy powders and aluminum powders. In order to develop homogeneous dispersion nuclear fuel, it is important to investigate the effect of powder characteristics and mixing techniques on homogeneity of dispersion nuclear fuel. An new quantitative analysis technique of homogeneity is needed to be developed for more accurate analysis of homogeneity in dispersion nuclear fuel. (author). 28 refs., 7 figs., 1tab

  20. Property Enhancement Effects of Side-Chain-Type Naphthalene-Based Sulfonated Poly(arylene ether ketone) on Nafion Composite Membranes for Direct Methanol Fuel Cells.

    Science.gov (United States)

    Wang, Baolong; Hong, Lihua; Li, Yunfeng; Zhao, Liang; Zhao, Chengji; Na, Hui

    2017-09-20

    Nafion/SNPAEK-x composite membranes were prepared by blending raw Nafion and synthesized side-chain-type naphthalene-based sulfonated poly(arylene ether ketone) with a sulfonation degree of 1.35 (SNPAEK-1.35). The incorporation of SNPAEK-1.35 polymer with ion exchange capacity (IEC) of 2.01 mequiv·g -1 into a Nafion matrix has the property enhancement effects, such as increasing IECs, improving proton conductivity, enhancing mechanical properties, reducing methanol crossover, and improving single cell performance of Nafion. Morphology studies show that Nafion/SNPAEK-x composite membranes exhibit a well-defined microphase separation structure depending on the contents of SNPAEK-1.35 polymer. Among them, Nafion/SNPAEK-7.5% with a bicontinuous morphology exhibits the best comprehensive properties. For example, it shows the highest proton conductivities of 0.092 S cm -1 at 25 °C and 0.163 S cm -1 at 80 °C, which are higher than those of recast Nafion with 0.073 S cm -1 at 25 °C and 0.133 S cm -1 at 80 °C, respectively. Nafion/SNPAEK-5.0% and Nafion/SNPAEK-7.5% membranes display an open circuit voltage of 0.77 V and a maximum power density of 47 mW cm -2 at 80 °C, which are much higher than those of recast Nafion of 0.63 V and 24 mW cm -2 under the same conditions. Nafion/SNPAEK-5.0% membrane also has comparable tensile strength (12.7 MPa) to recast Nafion (13.7 MPa), and higher Young's modulus (330 MPa) than that of recast Nafion (240 MPa). By combining their high proton conductivities, comparable mechanical properties, and good single cell performance, Nafion/SNPAEK-x composite membranes have the potential to be polymer electrolyte materials for direct methanol fuel cell applications.

  1. Effect of nonuniform fuel distribution

    International Nuclear Information System (INIS)

    Katakura, Jun-ichi

    1987-01-01

    In order to ensure the subcriticality of nuclear fuel, the method of controlling the mass, form or dimensions below the limit values and the method of confirming subcriticality by calculation are taken, but at this time, it is often assumed that the concentration of fuel is constant in a fuel region, or fuel rods are arranged at constant intervals. However, in the extraction process in fuel reprocessing or in fuel storage vessels, the concentration distribution may arise in fuel regions even though temporarily. Even if subcriticality is expected in a uniform system, when concentration distribution arises, and an uneven system results in, criticality may occur. Therefore, it is important to grasp the effect of uneven fuel distribution for ensuring the safety against criticality. In this paper, the effect of uneven fuel distribution is discussed, centering around the critical mass. The examples in literatures and the examples of calculation of uneven fuel distribution are shown. As the result of calculation in Japan Atomic Energy Research Institute, in a high enrichment U-235-water system, the critical mass decreased by about 7 % due to uneven distribution, which nearly agreed with the result of Clark of about 6 %. As for a low enrichment system, the conspicuous decrease of the critical mass was not observed. (Kako, I.)

  2. Spent reactor fuel benchmark composition data for code validation

    International Nuclear Information System (INIS)

    Bierman, S.R.

    1991-09-01

    To establish criticality safety margins utilizing burnup credit in the storage and transport of spent reactor fuels requires a knowledge of the uncertainty in the calculated fuel composition used in making the reactivity assessment. To provide data for validating such calculated burnup fuel compositions, radiochemical assays are being obtained as part of the United States Department of Energy From-Reactor Cask Development Program. Destructive assay data are being obtained from representative reactor fuels having experienced irradiation exposures up to about 55 GWD/MTM. Assay results and associated operating histories on the initial three samples analyzed in this effort are presented. The three samples were taken from different axial regions of the same fuel rod and represent radiation exposures of about 27, 37, and 44 GWD/MTM. The data are presented in a benchmark type format to facilitate identification/referencing and computer code input

  3. Determination of equilibrium fuel composition for fast reactor in closed fuel cycle

    Directory of Open Access Journals (Sweden)

    Ternovykha Mikhail

    2017-01-01

    Full Text Available Technique of evaluation of multiplying and reactivity characteristics of fast reactor operating in the mode of multiple refueling is presented. We describe the calculation model of the vertical section of the reactor. Calculation validations of the possibility of correct application of methods and models are given. Results on the isotopic composition, mass feed, and changes in the reactivity of the reactor in closed fuel cycle are obtained. Recommendations for choosing perspective fuel compositions for further research are proposed.

  4. Parametric studies on the fuel salt composition in thermal molten salt breeder reactors

    International Nuclear Information System (INIS)

    Nagy, K.; Kloosterman, J.L.; Lathouwers, D.; Van der Hagen, T.H.J.J.

    2008-01-01

    In this paper the salt composition and the fuel cycle of a graphite moderated molten salt self-breeder reactor operating on the thorium cycle is investigated. A breeder molten salt reactor is always coupled to a fuel processing plant which removes the fission products and actinides from the core. The efficiency of the removal process(es) has a large influence on the breeding capacity of the reactor. The aim is to investigate the effect on the breeding ratio of several parameters such as the composition of the molten salt, moderation ratio, power density and chemical processing. Several fuel processing strategies are studied. (authors)

  5. Effects of fuel particle size and fission-fragment-enhanced irradiation creep on the in-pile behavior in CERCER composite pellets

    Energy Technology Data Exchange (ETDEWEB)

    Zhao, Yunmei [Institute of Mechanics and Computational Engineering, Department of Aeronautics and Astronautics, Fudan University, Shanghai 200433 (China); Ding, Shurong, E-mail: dsr1971@163.com [Institute of Mechanics and Computational Engineering, Department of Aeronautics and Astronautics, Fudan University, Shanghai 200433 (China); Zhang, Xunchao; Wang, Canglong; Yang, Lei [Institute of Modern Physics, Chinese Academy of Sciences, Lanzhou 730000 (China)

    2016-12-15

    The micro-scale finite element models for CERCER pellets with different-sized fuel particles are developed. With consideration of a grain-scale mechanistic irradiation swelling model in the fuel particles and the irradiation creep in the matrix, numerical simulations are performed to explore the effects of the particle size and the fission-fragment-enhanced irradiation creep on the thermo-mechanical behavior of CERCER pellets. The enhanced irradiation creep effect is applied in the 10 μm-thick fission fragment damage matrix layer surrounding the fuel particles. The obtained results indicate that (1) lower maximum temperature occurs in the cases with smaller-sized particles, and the effects of particle size on the mechanical behavior in pellets are intricate; (2) the first principal stress and radial axial stress remain compressive in the fission fragment damage layer at higher burnup, thus the mechanism of radial cracking found in the experiment can be better explained. - Highlights: • A grain-scale gas swelling model considering the development of recrystallization and resolution is adopted for particles. • The influence of fission-gas-induced porosity is considered in the constitutive relations for particles. • A simulation method is developed for the multi-scale thermo-mechanical behavior. • The effects of fuel particle size and fission-fragment-enhanced irradiation creep are investigated in pellets.

  6. Dimensional, microstructural and compositional stability of metal fuels

    International Nuclear Information System (INIS)

    Solomon, A.A.; Dayananda, M.A.

    1993-01-01

    The projects undertaken were to address two areas of concern for metal-fueled fast reactors: metallurgical compatibility of fuel and its fission products with the stainless steel cladding, and effects of porosity development in the fuel on fuel/cladding interactions and on sodium penetration in fuel. The following studies are reported on extensively in appendices: hot isostatic pressing of U-10Zr by coupled boundary diffusion/power law creep cavitation, liquid Na intrusion into porous U-10Zr fuel alloy by differential capillarity, interdiffusion between U-Zr fuel and selected Fe-Ni-Cr alloys, interdiffusion between U-Zr fuel vs selected cladding steels, and interdiffusion of Ce in Fe-base alloys with Ni or Cr

  7. Effect of broadened-specification fuels on aircraft engines and fuel systems

    Science.gov (United States)

    Rudey, R. A.

    1979-01-01

    A wide variety of studies on the potential effects of broadened-specification fuels on future aircraft engines and fuel systems are summarized. The compositions and characteristics of aircraft fuels that may be derived from current and future crude-oil sources are described, and the most critical properties that may affect aircraft engines and fuel systems are identified and discussed. The problems that are most likely to be encountered because of changes in selected fuel properties are described; and the related effects on engine performance, component durability and maintenance, and aircraft fuel-system performance are discussed. The ability of current technology to accept possible future fuel-specification changes is discussed, and selected technological advances that can reduce the severity of the potential problems are illustrated.

  8. Thorium utilisation in a small long-life HTR. Part III: Composite-rod fuel blocks

    Energy Technology Data Exchange (ETDEWEB)

    Verrue, Jacques, E-mail: jacques.verrue@polytechnique.org [Delft University of Technology, Reactor Institute Delft, Mekelweg 15, 2629 JB Delft (Netherlands); École Polytechnique (Member of ParisTech), 91128 Palaiseau Cedex (France); Ding, Ming, E-mail: dingm2005@gmail.com [Delft University of Technology, Reactor Institute Delft, Mekelweg 15, 2629 JB Delft (Netherlands); Harbin Engineering University, Nantong Street 145, 150001 Harbin (China); Kloosterman, Jan Leen, E-mail: j.l.kloosterman@tudelft.nl [Delft University of Technology, Reactor Institute Delft, Mekelweg 15, 2629 JB Delft (Netherlands)

    2014-02-15

    Highlights: • Composite-rod fuel blocks are proposed for a small block-type HTR. • An axial separation of fuel compacts is the most important feature. • Three patterns are presented to analyse the effects of the spatial distribution. • The spatial distribution has a large influence on the neutron spectrum. • Composite-rod fuel blocks reach a reactivity swing less than 4%. - Abstract: The U-Battery is a small long-life high temperature gas-cooled reactor (HTR) with power of 20 MWth. In order to increase its lifetime and diminish its reactivity swing, the concept of composite-rod fuel blocks with uranium and thorium was investigated. Composite-rod fuel blocks feature a specific axial separation between UO{sub 2} and ThO{sub 2} compacts in fuel rods. The design parameters, investigated by SCALE 6, include the number and spatial distribution of fuel compacts within the rods, the enrichment of uranium, the radii of fuel kernels and fuel compacts, and the packing fractions of uranium and thorium TRISO particles. The analysis shows that a lower moderation ratio and a larger inventory of heavy metals results in a lower reactivity swing. The optimal atomic carbon-to-heavy metal ratio depends on the mass fraction of U-235 and is commonly in the 160–200 range. The spatial distribution of the fuel compacts within the fuel rods has a large influence on the energy spectrum in each fuel compact and thus on the beginning-of-life reactivity and the reactivity swing. At end-of-life, the differences caused by the spatial distribution of the fuel compacts are smaller due to the fissions of U-233 in the ThO{sub 2} fuel compacts. This phenomenon enables to design fuel blocks with a very low reactivity swing, down to less than 4% in a 10-year lifetime. Among three types of thorium fuelled U-Battery blocks, the composite-rod fuel block achieves the highest end-of-life reactivity and the lowest reactivity swing.

  9. Use of a perfume composition as a fuel for internal combustion engines

    NARCIS (Netherlands)

    2013-01-01

    The present invention relates to fuel compositions containing perfume fractions, that is to say compositions of fragrance materials, and to the use of such perfume fractions containing fuel compositions to provide a fuel for internal combustion engines and burners. According to the present fuel

  10. Diesel/CNG Mixture Autoignition Control Using Fuel Composition and Injection Gap

    Directory of Open Access Journals (Sweden)

    Firmansyah

    2017-10-01

    Full Text Available Combustion phasing is the main obstacle to the development of controlled auto-ignition based (CAI engines to achieve low emissions and low fuel consumption operation. Fuel combinations with substantial differences in reactivity, such as diesel/compressed natural gas (CNG, show desirable combustion outputs and demonstrate great possibility in controlling the combustion. This paper discusses a control method for diesel/CNG mixture combustion with a variation of fuel composition and fuel stratification levels. The experiments were carried out in a constant volume combustion chamber with both fuels directly injected into the chamber. The mixture composition was varied from 0 to 100% CNG/diesel at lambda 1 while the fuel stratification level was controlled by the injection phasing between the two fuels, with gaps between injections ranging from 0 to 20 ms. The results demonstrated the suppressing effect of CNG on the diesel combustion, especially at the early combustion stages. However, CNG significantly enhanced the combustion performance of the diesel in the later stages. Injection gaps, on the other hand, showed particular behavior depending on mixture composition. Injection gaps show less effect on combustion phasing but a significant effect on the combustion output for higher diesel percentage (≥70%, while it is contradictive for lower diesel percentage (<70%.

  11. Experimental study of dual fuel engine performance using variable LPG composition and engine parameters

    International Nuclear Information System (INIS)

    Elnajjar, Emad; Selim, Mohamed Y.E.; Hamdan, Mohammad O.

    2013-01-01

    Highlights: • The effect of using variable LPG is studied. • Five fuels with propane to butane % volume ratio are: 100-70-55-25-0. • 100% Propane composition shows the highest noise levels with similar performance. • At 45° BTDC injection timing 55% Propane LPG the only fuel experience knocking. • LPG fuels gave similar engine performance, with differences in levels of noise. - Abstract: The present work investigates experimentally the effect of LPG fuel with different composition and engine parameters on the performance of a dual compression engine. Five different blends of LPG fuels are used with Propane to Butane volume ratio of 100:0, 70:30, 55:45, 25:75, and 0:100. A single cylinder, naturally aspirated, four strokes, indirectly injected, water cooled modified Ricardo E6 engine, is used in this study. The study is carried out by measuring the cylinder pressure, engine load, engine speed, crank angle, and the fuel’s flow rate. The engine performance under variable LPG fuel composition, engine load, pilot fuel injection timing, compression ratio, pilot fuel mass and engine speed, are estimated by comparing the following engine parameters: the cylinder maximum pressure, the indicated mean effective pressure, the maximum rate of pressure rise, and the thermal efficiency. The experimental data indicates that the engine parameters are playing a major role on the engine’s performance. Different LPG fuel composition did not show a major effect on the engine efficiency but directly impacted the levels of generated combustion noise

  12. Fuel Effective Photonic Propulsion

    Science.gov (United States)

    Rajalakshmi, N.; Srivarshini, S.

    2017-09-01

    With the entry of miniaturization in electronics and ultra-small light-weight materials, energy efficient propulsion techniques for space travel can soon be possible. We need to go for such high speeds so that the generation’s time long interstellar missions can be done in incredibly short time. Also renewable energy like sunlight, nuclear energy can be used for propulsion instead of fuel. These propulsion techniques are being worked on currently. The recently proposed photon propulsion concepts are reviewed, that utilize momentum of photons generated by sunlight or onboard photon generators, such as blackbody radiation or lasers, powered by nuclear or solar power. With the understanding of nuclear photonic propulsion, in this paper, a rough estimate of nuclear fuel required to achieve the escape velocity of Earth is done. An overview of the IKAROS space mission for interplanetary travel by JAXA, that was successful in demonstrating that photonic propulsion works and also generated additional solar power on board, is provided; which can be used as a case study. An extension of this idea for interstellar travel, termed as ‘Star Shot’, aims to send a nanocraft to an exoplanet in the nearest star system, which could be potentially habitable. A brief overview of the idea is presented.

  13. Effects of alpha-decay on spent fuel corrosion behaviour

    International Nuclear Information System (INIS)

    Wiss, T.; Rondinella, V.V.; Cobos, J.; Wegen, D.H.; Amme, M.; Ronchi, C.

    2004-01-01

    An overview of results in the area of spent fuel characterization as nuclear waste is presented. These studies are focused on primary aspects of spent fuel corrosion, by considering different fuel compositions and burn ups, as well as a wide set of environmental conditions. The key parameter is the storage time of the fuel e.g. in view of spent fuel retrieval or in view of its final disposal. To extrapolate data obtainable from a laboratory-acceptable timescale to those expected after storage periods of interest have elapsed (amounting in the extreme case to geological ages) is a tough challenge. Emphasis is put on key aspects of fuel corrosion related to fuel properties at a given age and environmental conditions expected in the repository: e.g. the fuel activity (radiolysis effects), the effects of helium build-up and of groundwater composition. A wide range of techniques, from traditional leaching experiments to advanced electrochemistry, and of materials, including spent fuel with different compositions/burnups and analogues like the so-called alpha-doped UO 2 , are employed for these studies. The results confirm the safety of European underground repository concepts. (authors)

  14. Solid oxide fuel cell having a glass composite seal

    Science.gov (United States)

    De Rose, Anthony J.; Mukerjee, Subhasish; Haltiner, Jr., Karl Jacob

    2013-04-16

    A solid oxide fuel cell stack having a plurality of cassettes and a glass composite seal disposed between the sealing surfaces of adjacent cassettes, thereby joining the cassettes and providing a hermetic seal therebetween. The glass composite seal includes an alkaline earth aluminosilicate (AEAS) glass disposed about a viscous glass such that the AEAS glass retains the viscous glass in a predetermined position between the first and second sealing surfaces. The AEAS glass provides geometric stability to the glass composite seal to maintain the proper distance between the adjacent cassettes while the viscous glass provides for a compliant and self-healing seal. The glass composite seal may include fibers, powders, and/or beads of zirconium oxide, aluminum oxide, yttria-stabilized zirconia (YSZ), or mixtures thereof, to enhance the desirable properties of the glass composite seal.

  15. Edge effects in composites

    International Nuclear Information System (INIS)

    Guz, A.N.; Kokhanenko, Yu.V.

    1995-01-01

    In the present article we survey papers on edge effects investigated by the rigorous approach. We interpret edge effects as stressed states created in a composite as a result of zones in which the stresses exhibit a rapidly changing behavior in comparison with the slow variation of the stresses outside such zones. Here the range of the edge effect is defined as the distance from the point of its inception to the boundary of the edge zone in a given direction. The transition of the stresses to the slowly varying state is determined within prescribed error limits. The size and configuration of the edge zone depends on the tolerated error. Clearly, the main difficulty associated with the rigorous approach is finding solutions of the elasticity problems. The finite-difference approach is suggested for the approximate solution of these problems. In light of the comparative time consumption of the finite-difference approach, it is best directed at certain classes of problems rather than at particular individual problems. Not too many papers on the investigation of edge effects by the rigorous approach have been published to date. Below, following in their footsteps, we formulate edge effect problems in composites, determine classes of problems, and investigate edge effects in composite materials and structural elements using them in Cartesian (planar and three-dimensional problems) and cylindrical (axisymmetric problems) coordinate frames. We note that the division of approaches to the study of edge effects into qualitative (nonrigorous) and quantitative (rigorous) reflects the authors own point of view. Of course, other schemes of classification of the approaches to the investigation of the regions of rapidly varying states in composites are possible

  16. A method to calculate the effect of heterogeneous composition on bundle power

    Energy Technology Data Exchange (ETDEWEB)

    Choi, Hang Bok [Korea Atomic Energy Research Institute, Taejon (Korea)

    1998-09-01

    In the DUPIC fuel cycle, the spent pressurized water reactor (PWR) fuel is used in a Canada deuterium uranium (CANDU) reactor. Depending on the initial condition and burnup history of PWR fuel, the DUPIC fuel composition varies accordingly. In order to see the effect of the fuel composition, a simple and fast method was developed and applied to the DUPIC fuel. This report discusses the method developed to predict the effect of heterogeneous fuel composition on the bundle power. (author). 3 refs., 5 tabs.

  17. Measuring method for effective neutron multiplication factor upon containing irradiated fuel assembly

    International Nuclear Information System (INIS)

    Ueda, Makoto; Mitsuhashi, Ishi; Sasaki, Tomoharu.

    1993-01-01

    A portion of irradiated fuel assemblies at a place where a reactivity effect is high, that is, at a place where neutron importance is high is replaced with standard fuel assemblies having a known composition to measure neutron fluxes at each of the places. An effective composition at the periphery of the standard fuel assemblies is determined by utilizing a calibration curve determined separately based on the composition and neutron flux values of the standard assemblies. By using the calibration curve determined separately based on this composition and the known composition of the standard fuel assemblies, an effective neutron multiplication factor for the fuel containing portion containing the irradiated fuel assemblies is recognized. Then, subcriticality is ensured and critical safety upon containing the fuel assemblies can be secured quantitatively. (N.H.)

  18. Effect of sulfonated carbon nanofiber-supported Pt on performance of Nafion {sup registered} -based self-humidifying composite membrane for proton exchange membrane fuel cell

    Energy Technology Data Exchange (ETDEWEB)

    Hung, T.F. [Department of Chemistry and Center for Nanotechnology, Chung Yuan Christian University, 200 Chung Pei Rd., Chung-Li, 32023 (China); Department of Chemistry, National Taiwan University, No. 1, Sec. 4, Roosevelt Road, Taipei, 10617 (China); Liao, S.H.; Li, C.Y.; Chen-Yang, Y.W. [Department of Chemistry and Center for Nanotechnology, Chung Yuan Christian University, 200 Chung Pei Rd., Chung-Li, 32023 (China)

    2011-01-01

    In the present study, the Nafion {sup registered} -based self-humidifying composite membrane (N-SHCM) with sulfonated carbon nanofiber-supported Pt (s-Pt/CNF) catalyst, N-s-Pt/CNF, is successfully prepared using the solution-casting method. The scanning electron microscopy-energy dispersive spectroscopy (SEM-EDS) images of N-s-Pt/CNF indicate that s-Pt/CNF is well dispersed in the Nafion {sup registered} matrix due to the good compatibility between Nafion {sup registered} and s-Pt/CNF. Compared with those of the non-sulfonated Pt/CNF-containing N-SHCM, N-Pt/CNF, the properties of N-s-Pt/CNF, including electronic resistivity, ion-exchange capacity (IEC), water uptake, dimensional stability, and catalytic activity, significantly increase. The maximum power density of the proton exchange membrane fuel cell (PEMFC) fabricated with N-s-Pt/CNF operated at 50 C under dry H{sub 2}/O{sub 2} condition is about 921 mW cm{sup -2}, which is approximately 34% higher than that with N-Pt/CNF. (author)

  19. Important parameters in ORIGEN2 calculations of spent fuel compositions

    International Nuclear Information System (INIS)

    Welch, T.D.; Notz, K.J.; Andermann, R.J. Jr.

    1990-01-01

    The Department of Energy (DOE) Office of Civilian Radioactive Waste Management (OCRWM) is responsible for implementing federal policy for the management and permanent disposal of spent nuclear fuel from civilian nuclear power reactors and of high-level radioactive waste. The Characteristics Data Base (CDB) provides an extensive collection of data on the four waste steams that may require long-term isolation: LWR spent fuel, high-level waste, non-LWR spent fuel, and miscellaneous wastes (such as greater-than-class-C). The eight-volume report and the five supplemental menu-driven PC data bases encompass radiological characteristics, chemical compositions, physical descriptions, inventories, and projections. An overview of these data bases, which are available through the Oak Ridge National Laboratory, is provided by Notz. This paper reports that the radiological characteristics in the CDB are calculated using ORIGEN2

  20. Glass/Ceramic Composites for Sealing Solid Oxide Fuel Cells

    Science.gov (United States)

    Bansal, Narottam P.; Choi, Sung R.

    2007-01-01

    A family of glass/ceramic composite materials has been investigated for use as sealants in planar solid oxide fuel cells. These materials are modified versions of a barium calcium aluminosilicate glass developed previously for the same purpose. The composition of the glass in mole percentages is 35BaO + 15CaO + 5Al2O3 + 10B2O3 + 35SiO2. The glass seal was found to be susceptible to cracking during thermal cycling of the fuel cells. The goal in formulating the glass/ ceramic composite materials was to (1) retain the physical and chemical advantages that led to the prior selection of the barium calcium aluminosilicate glass as the sealant while (2) increasing strength and fracture toughness so as to reduce the tendency toward cracking. Each of the composite formulations consists of the glass plus either of two ceramic reinforcements in a proportion between 0 and 30 mole percent. One of the ceramic reinforcements consists of alumina platelets; the other one consists of particles of yttria-stabilized zirconia wherein the yttria content is 3 mole percent (3YSZ). In preparation for experiments, panels of the glass/ceramic composites were hot-pressed and machined into test bars.

  1. Modeling of combustion products composition of hydrogen-containing fuels

    International Nuclear Information System (INIS)

    Assad, M.S.

    2010-01-01

    Due to the usage of entropy maximum principal the algorithm and the program of chemical equilibrium calculation concerning hydrogen--containing fuels are devised. The program enables to estimate the composition of combustion products generated in the conditions similar to combustion conditions in heat engines. The program also enables to reveal the way hydrogen fraction in the conditional composition of the hydrocarbon-hydrogen-air mixture influences the harmful components content. It is proven that molecular hydrogen in the mixture is conductive to the decrease of CO, CO 2 and CH x concentration. NO outlet increases due to higher combustion temperature and N, O, OH concentrations in burnt gases. (authors)

  2. Sensitivity of dual fuel engine combustion and knocking limits to gaseous fuel composition

    Energy Technology Data Exchange (ETDEWEB)

    Selim, M.Y.E. [United Arab Emirates University, Al-Ain (United Arab Emirates). Dept. of Mechanical Engineering

    2004-02-01

    Combustion noise, knock and ignition limits data are measured and presented for a dual fuel engine running on dual fuels of Diesel and three gaseous fuels separately. The gaseous fuels used are liquefied petroleum gas, pure methane and compressed natural gas mixture. The maximum pressure rise rate during combustion is presented as a measure of combustion noise, and the knocking and ignition limits are presented as torque output at the onset of knocking and ignition failure. Experimental investigation on the dual fuel engine revealed the noise generated from combustion, knocking and ignition limits for all gases at different design and operating conditions. A Ricardo E6 Diesel version engine is converted to run on dual fuel of Diesel and the tested gaseous fuel and is used throughout the work. The engine is fully computerized, and the cylinder pressure data, crank angle data and engine operating variables are stored in a PC for off line analysis. The effects of engine speeds, loads, pilot injection angle, pilot fuel quantity and compression ratio on combustion noise, knocking torque, thermal efficiency and maximum pressure are examined for the dual engine running on the three gaseous fuels separately. The combustion noise, knocking and ignition limits are found to relate to the type of gaseous fuels and to the engine design and operating parameters. (author)

  3. Sensitivity of dual fuel engine combustion and knocking limits to gaseous fuel composition

    International Nuclear Information System (INIS)

    Selim, Mohamed Y.E.

    2004-01-01

    Combustion noise, knock and ignition limits data are measured and presented for a dual fuel engine running on dual fuels of Diesel and three gaseous fuels separately. The gaseous fuels used are liquefied petroleum gas, pure methane and compressed natural gas mixture. The maximum pressure rise rate during combustion is presented as a measure of combustion noise, and the knocking and ignition limits are presented as torque output at the onset of knocking and ignition failure. Experimental investigation on the dual fuel engine revealed the noise generated from combustion, knocking and ignition limits for all gases at different design and operating conditions. A Ricardo E6 Diesel version engine is converted to run on dual fuel of Diesel and the tested gaseous fuel and is used throughout the work. The engine is fully computerized, and the cylinder pressure data, crank angle data and engine operating variables are stored in a PC for off line analysis. The effects of engine speeds, loads, pilot injection angle, pilot fuel quantity and compression ratio on combustion noise, knocking torque, thermal efficiency and maximum pressure are examined for the dual engine running on the three gaseous fuels separately. The combustion noise, knocking and ignition limits are found to relate to the type of gaseous fuels and to the engine design and operating parameters

  4. Sanitary effects of fossil fuels

    International Nuclear Information System (INIS)

    Nifenecker, H.

    2006-01-01

    In this compilation are studied the sanitary effects of fossil fuels, behavioral and environmental sanitary risks. The risks in connection with the production, the transport and the distribution(casting) are also approached for the oil(petroleum), the gas and the coal. Accidents in the home are evoked. The risks due to the atmospheric pollution are seen through the components of the atmospheric pollution as well as the sanitary effects of this pollution. (N.C.)

  5. Carbon composites with metal nanoparticles for Alcohol fuel cells

    Science.gov (United States)

    Ventrapragada, Lakshman; Siddhardha, R. S.; Podilla, Ramakrishna; Muthukumar, V. S.; Creager, Stephen; Rao, A. M.; Ramamurthy, Sai Sathish

    2015-03-01

    Graphene due to its high surface area and superior conductivity has attracted wide attention from both industrial and scientific communities. We chose graphene as a substrate for metal nanoparticle deposition for fuel cell applications. There are many chemical routes for fabrication of metal-graphene composites, but they have an inherent disadvantage of low performance due to the usage of surfactants, that adsorb on their surface. Here we present a design for one pot synthesis of gold nanoparticles and simultaneous deposition on graphene with laser ablation of gold strip and functionalized graphene. In this process there are two natural advantages, the nanoparticles are synthesized without any surfactants, therefore they are pristine and subsequent impregnation on graphene is linker free. These materials are well characterized with electron microscopy to find their morphology and spectroscopic techniques like Raman, UV-Vis. for functionality. This gold nanoparticle decorated graphene composite has been tested for its electrocatalytic oxidation of alcohols for alkaline fuel cell applications. An electrode made of this composite showed good stability for more than 200 cycles of operation and reported a low onset potential of 100 mV more negative, an important factor for direct ethanol fuel cells.

  6. FABRICATION AND MATERIAL ISSUES FOR THE APPLICATION OF SiC COMPOSITES TO LWR FUEL CLADDING

    Directory of Open Access Journals (Sweden)

    WEON-JU KIM

    2013-08-01

    Full Text Available The fabrication methods and requirements of the fiber, interphase, and matrix of nuclear grade SiCf/SiC composites are briefly reviewed. A CVI-processed SiCf/SiC composite with a PyC or (PyC-SiCn interphase utilizing Hi-Nicalon Type S or Tyranno SA3 fiber is currently the best combination in terms of the irradiation performance. We also describe important material issues for the application of SiC composites to LWR fuel cladding. The kinetics of the SiC corrosion under LWR conditions needs to be clarified to confirm the possibility of a burn-up extension and the cost-benefit effect of the SiC composite cladding. In addition, the development of end-plug joining technology and fission products retention capability of the ceramic composite tube would be key challenges for the successful application of SiC composite cladding.

  7. Influence of fuel composition on the spent fuel verification by Self‑Interrogation Neutron Resonance Densitometry

    International Nuclear Information System (INIS)

    Rossa, Riccardo; Borella, Alessandro; Van der Meer, Klaas; Labeau, Pierre‑Etienne; Pauly, Nicolas

    2015-01-01

    The Self‑Interrogation Neutron Resonance Densitometry (SINRD) is a passive Non‑Destructive Assay (NDA) that is developed for the safeguards verification of spent nuclear fuel. The main goal of SINRD is the direct quantification of 239Pu by estimating the SINRD signature, which is the ratio between the neutron flux in the fast energy region and in the region close to the 0.3 eV resonance of 239 Pu. The resonance region was chosen because the reduction of the neutron flux within 0.2-0.4 eV is due mainly to neutron absorption from 239 Pu, and therefore the SINRD signature can be correlated to the 239Pu mass in the fuel assembly. This work provides an estimate of the influence of 239 Pu and other nuclides on the SINRD signature. This assessment is performed by Monte Carlo simulations by introducing several nuclides in the fuel material composition and by calculating the SINRD signature for each case. The reference spent fuel library developed by SCK CEN was used for the detailed fuel compositions of PWR 17x17 fuel assemblies with different initial enrichments, burnup, and cooling times. The results from the simulations show that the SINRD signature is mainly correlated to the 239 Pu mass, with significant influence by 235 U. Moreover, the SINRD technique is largely insensitive to the cooling time of the assembly, while it is affected by the burnup and initial enrichment of the fuel. Apart from 239 Pu and 235 U, many other nuclides give minor contributions to the SINRD signature, especially at burnup higher than 20 GWd/tHM.

  8. Remarkable adsorptive removal of nitrogen-containing compounds from a model fuel by a graphene oxide/MIL-101 composite through a combined effect of improved porosity and hydrogen bonding

    Energy Technology Data Exchange (ETDEWEB)

    Ahmed, Imteaz; Jhung, Sung Hwa, E-mail: sung@knu.ac.kr

    2016-08-15

    Highlights: • Metal-organic frameworks (MIL-101) were composed with graphene oxide (GnO). • GnO/MIL-101 showed the highest adsorption capacity for indole and quinoline. • Adsorption mechanism was clearly shown based on adsorption results and FTIR. • GnO/MIL-101 might be applied commercially considering capacity and reusability. - Abstract: A composite was prepared by combining a highly porous metal-organic framework (MOF), MIL-101 (Cr-benzenedicarboxylate), and graphene oxide (GnO). The porosity of the composite increased appreciably by the addition of GnO up to a specific amount in the MOF, though further increases in the quantity of GnO was detrimental to porosity. The improved porosity of the GnO/MIL-101 composite was utilized for adsorptive denitrogenation (ADN) of a model fuel where indole (IND) and quinoline (QUI) were used as nitrogen-containing compounds (NCCs). It was found that both IND and QUI showed improved adsorption on the composite compared with pristine MIL-101 or GnO due to the improved porosity of the composite. Interestingly, the improvement in adsorption of IND was much higher than the quantity estimated for the porosity. Importantly, GnO/MIL-101 showed the highest adsorption capacities for NCCs. Irrespective of the studied solvents and co-presence of IND and QUI, the composite adsorbent performed ADN most effectively. This remarkable improvement is explained by the additional mechanism of hydrogen bonding between the surface functional groups of GnO and the hydrogen attached to the nitrogen atom of IND. This hydrogen bonding mechanism is also supported by the results of the adsorption of pyrrole and methylpyrrole. On the other hand, QUI does not show hydrogen-bonding capability, and therefore, its enhanced adsorption originates from only the increased porosity of the adsorbents.

  9. Remarkable adsorptive removal of nitrogen-containing compounds from a model fuel by a graphene oxide/MIL-101 composite through a combined effect of improved porosity and hydrogen bonding

    International Nuclear Information System (INIS)

    Ahmed, Imteaz; Jhung, Sung Hwa

    2016-01-01

    Highlights: • Metal-organic frameworks (MIL-101) were composed with graphene oxide (GnO). • GnO/MIL-101 showed the highest adsorption capacity for indole and quinoline. • Adsorption mechanism was clearly shown based on adsorption results and FTIR. • GnO/MIL-101 might be applied commercially considering capacity and reusability. - Abstract: A composite was prepared by combining a highly porous metal-organic framework (MOF), MIL-101 (Cr-benzenedicarboxylate), and graphene oxide (GnO). The porosity of the composite increased appreciably by the addition of GnO up to a specific amount in the MOF, though further increases in the quantity of GnO was detrimental to porosity. The improved porosity of the GnO/MIL-101 composite was utilized for adsorptive denitrogenation (ADN) of a model fuel where indole (IND) and quinoline (QUI) were used as nitrogen-containing compounds (NCCs). It was found that both IND and QUI showed improved adsorption on the composite compared with pristine MIL-101 or GnO due to the improved porosity of the composite. Interestingly, the improvement in adsorption of IND was much higher than the quantity estimated for the porosity. Importantly, GnO/MIL-101 showed the highest adsorption capacities for NCCs. Irrespective of the studied solvents and co-presence of IND and QUI, the composite adsorbent performed ADN most effectively. This remarkable improvement is explained by the additional mechanism of hydrogen bonding between the surface functional groups of GnO and the hydrogen attached to the nitrogen atom of IND. This hydrogen bonding mechanism is also supported by the results of the adsorption of pyrrole and methylpyrrole. On the other hand, QUI does not show hydrogen-bonding capability, and therefore, its enhanced adsorption originates from only the increased porosity of the adsorbents.

  10. Tensile behavior of humid aged advanced composites for helicopter external fuel tank development

    Directory of Open Access Journals (Sweden)

    Condruz Mihaela

    2018-01-01

    Full Text Available Influence of humid aging on tensile properties of two polymeric composites was studied. The purpose of the study was to evaluate the suitability of the materials for a naval helicopter external fuel tank. Due to the application, the humid environment was kerosene and saline solution to evaluate the sea water effect on the composite tensile strength. The composite samples were immersed in kerosene for 168 hours, respective 1752 hours and in saline solution for 168 hours. Tensile tests were performed after the immersion. The composite sample tensile tests showed that kerosene and saline solution had no influence on the elastic modulus of the materials, but it was observed a slight improvement of the tensile strength of the two polymeric composites.

  11. Process engineering of ceramic composite coatings for fuel cell systems

    Energy Technology Data Exchange (ETDEWEB)

    Li, G.; Kim, H.; Chen, M.; Yang, Q.; Troczynski, T. [British Columbia Univ., Vancouver, BC (Canada). Dept. of Metals and Materials Engineering

    2003-07-01

    Researchers at UBCeram at the Department of Metals and Materials Engineering at the University of British Columbia have developed a technology to chemically bond composite sol-gel (CB-CSG) coating onto metallic surfaces of complex or concave shapes. The process has been optimized for electrically resistive coatings and corrosion-resistant coatings. The CSG is sprayed onto metallic surfaces and is heat-treated at 300 degrees C to partially dehydrate the hydroxides. The CSG film is then chemically bonded through reaction of active alumina with metal phosphates, such as aluminium phosphate. A new chromate-free process is being developed to address the issue of coatings porosity. The electrodeposition technique involves polymer particles mixed with suspended fine alumina particles which are co-deposited by electrophoretic means or by electrocoagulation. The composite e-coatings have excellent mechanical properties and are being considered as a protective coating for various components of fuel cell systems. 9 refs., 7 figs.

  12. Composition and Distribution of Tramp Uranium Contamination on BWR and PWR Fuel Rods

    International Nuclear Information System (INIS)

    Schienbein, Marcel; Zeh, Peter; Hurtado, Antonio; Rosskamp, Matthias; Mailand, Irene; Bolz, Michael

    2012-09-01

    In a joint research project of VGB and AREVA NP GmbH the behaviour of alpha nuclides in nuclear power plants with light water reactors has been investigated. Understanding the source and the behaviour of alpha nuclides is of big importance for planning radiation protection measures for outages and upcoming dismantling projects. Previous publications have shown the correlation between plant specific alpha contamination of the core and the so called 'tramp fuel' or 'tramp uranium' level which is linked to the defect history of fuel assemblies and accordingly the amount of previously washed out fuel from defective fuel rods. The methodology of tramp fuel estimation is based on fission product concentrations in reactor coolant but also needs a good knowledge of tramp fuel composition and in-core distribution on the outer surface of fuel rods itself. Sampling campaigns of CRUD deposits of irradiated fuel assemblies in different NPPs were performed. CRUD analyses including nuclide specific alpha analysis have shown systematic differences between BWR and PWR plants. Those data combined with literature results of fuel pellet investigations led to model improvements showing that a main part of fission products is caused by fission of Pu-239 an activation product of U-238. CRUD investigations also gave a better picture of the in-core composition and distribution of the tramp uranium contamination. It was shown that the tramp uranium distribution in PWR plants is time dependent. Even new fuel assemblies will be notably contaminated after only one cycle of operation. For PWR applies the following logic: the higher the local power the higher the contamination. With increasing burnup the local rod power usually decreases leading to decreasing tramp uranium contamination on the fuel rod surface. This is not applicable for tramp uranium contamination in BWR. CRUD contamination (including the tramp fuel deposits) is much more fixed and is constantly increasing

  13. Fuel containment and damage tolerance in large composite primary aircraft structures. Phase 2: Testing

    Science.gov (United States)

    Sandifer, J. P.; Denny, A.; Wood, M. A.

    1985-01-01

    Technical issues associated with fuel containment and damage tolerance of composite wing structures for transport aircraft were investigated. Material evaluation tests were conducted on two toughened resin composites: Celion/HX1504 and Celion/5245. These consisted of impact, tension, compression, edge delamination, and double cantilever beam tests. Another test series was conducted on graphite/epoxy box beams simulating a wing cover to spar cap joint configuration of a pressurized fuel tank. These tests evaluated the effectiveness of sealing methods with various fastener types and spacings under fatigue loading and with pressurized fuel. Another test series evaluated the ability of the selected coatings, film, and materials to prevent fuel leakage through 32-ply AS4/2220-1 laminates at various impact energy levels. To verify the structural integrity of the technology demonstration article structural details, tests were conducted on blade stiffened panels and sections. Compression tests were performed on undamaged and impacted stiffened AS4/2220-1 panels and smaller element tests to evaluate stiffener pull-off, side load and failsafe properties. Compression tests were also performed on panels subjected to Zone 2 lightning strikes. All of these data were integrated into a demonstration article representing a moderately loaded area of a transport wing. This test combined lightning strike, pressurized fuel, impact, impact repair, fatigue and residual strength.

  14. Emission of pollutants from the combustion of composite fuels by metallurgical processes

    Directory of Open Access Journals (Sweden)

    J. Łabaj

    2015-10-01

    Full Text Available This paper presents the results of the study on emission characteristics of pollutants resulting from combustion process of composite alternative fuels for use in the processes of pyrometallurgy of copper as an alternative fuel to currently used coke breeze. These fuels are mainly based on waste carrier of “C” element, and the composition of the fuel is modelled in order to obtain the appropriate energy and emission parameters as well as strength parameters. These studies confirmed the possibility of using composite fuels as an alternative reducing agent as well as an energy carrier in the processes of pyrometallurgy of copper.

  15. Thermal modeling of the ceramic composite fuel for light water reactors

    International Nuclear Information System (INIS)

    Revankar, S.T.; Latta, R.; Solomon, A.A.

    2005-01-01

    Full text of publication follows: Composite fuel designs capable of providing improved thermal performance are of great interest in advanced reactor designs where high efficiency and long fuel cycles are desired. Thermal modeling of the composite fuel consisting of continuous second phase in a ceramic (uranium oxide) matrix has been carried out with detailed examination of the microstructure of the composite and the interface. Assuming that constituent phases are arranged as slabs, upper and lower bounds for the thermal conductivity of the composite are derived analytically. Bounding calculations on the thermal conductivity of the composite were performed for SiC dispersed in the UO 2 matrix. It is found that with 10% SiC, the thermal conductivity increases from 5.8 to 9.8 W/m.deg. K at 500 K, or an increase of 69% was observed in UO 2 matrix. The finite element analysis computer program ANSYS was used to create composite fuel geometries with set boundary conditions to produce accurate thermal conductivity predictions. A model developed also accounts for SiC-matrix interface resistance and the addition of coatings or interaction barriers. The first set of calculations using the code was to model simple series and parallel fuel slab geometries, and then advance to inter-connected parallel pathways. The analytical calculations were compared with the ANSYS results. The geometry of the model was set up as a 1 cm long by 400 micron wide rectangle. This rectangle was then divided into one hundred sections with the first ninety percent of a single section being UO 2 and the remaining ten percent consisting of SiC. The model was then meshed using triangular type elements. The boundary conditions were set with the sides of the rectangle being adiabatic and having an assigned temperature at the end of the rectangle. A heat flux was then applied to one end of the model producing a temperature gradient. The effective thermal conductivity was then calculated using the geometry

  16. Composition of diesl fuels from German refinery. Products of summer 2003; Zusammensetzung von Dieselkraftstoffen aus deutschen Raffinerien. Sommerware 2003

    Energy Technology Data Exchange (ETDEWEB)

    Froehling, J.C. [ARAL Forschung GmbH, Bochum (Germany)

    2004-08-01

    DGMK research project 583-1 investigates the composition of sulfur-free Diesel fuels as a supplement to DGMK report 583 published in 2002, which reports the composition of Diesel fuels with a sulfur content of max. 350 mg/kg. Thereby the effect of desulfurisation on the composition of Diesel fuels was determined. In summer 2003 fuels from German refineries were sampled and examined. In contrast to the first survey, the number of tests was reduced significantly. Only those parameters were considered that were likely to have changed due to the modified refining processes. Since sulfur-free products have to this extent been investigated for the first time, the results will give a significant contribution to questions regarding application techniques and ecology. (orig.)

  17. Method of producing exfoliated graphite composite compositions for fuel cell flow field plates

    Energy Technology Data Exchange (ETDEWEB)

    Zhamu, Aruna; Shi, Jinjun; Guo, Jiusheng; Jang, Bor Z

    2014-04-08

    A method of producing an electrically conductive composite composition, which is particularly useful for fuel cell bipolar plate applications. The method comprises: (a) providing a supply of expandable graphite powder; (b) providing a supply of a non-expandable powder component comprising a binder or matrix material; (c) blending the expandable graphite with the non-expandable powder component to form a powder mixture wherein the non-expandable powder component is in the amount of between 3% and 60% by weight based on the total weight of the powder mixture; (d) exposing the powder mixture to a temperature sufficient for exfoliating the expandable graphite to obtain a compressible mixture comprising expanded graphite worms and the non-expandable component; (e) compressing the compressible mixture at a pressure within the range of from about 5 psi to about 50,000 psi in predetermined directions into predetermined forms of cohered graphite composite compact; and (f) treating the so-formed cohered graphite composite to activate the binder or matrix material thereby promoting adhesion within the compact to produce the desired composite composition. Preferably, the non-expandable powder component further comprises an isotropy-promoting agent such as non-expandable graphite particles. Further preferably, step (e) comprises compressing the mixture in at least two directions. The method leads to composite plates with exceptionally high thickness-direction electrical conductivity.

  18. Method and apparatus for real-time measurement of fuel gas compositions and heating values

    Science.gov (United States)

    Zelepouga, Serguei; Pratapas, John M.; Saveliev, Alexei V.; Jangale, Vilas V.

    2016-03-22

    An exemplary embodiment can be an apparatus for real-time, in situ measurement of gas compositions and heating values. The apparatus includes a near infrared sensor for measuring concentrations of hydrocarbons and carbon dioxide, a mid infrared sensor for measuring concentrations of carbon monoxide and a semiconductor based sensor for measuring concentrations of hydrogen gas. A data processor having a computer program for reducing the effects of cross-sensitivities of the sensors to components other than target components of the sensors is also included. Also provided are corresponding or associated methods for real-time, in situ determination of a composition and heating value of a fuel gas.

  19. Effect of Feed Composition Changing at Naphtha Catalytic Reforming Unit Due to Involvement of Gasoline Fraction Obtained by Diesel Fuels Hydrodewaxing into the Processing

    OpenAIRE

    Belinskaya, Natalia Sergeevna; Ivanchina, Emilia Dmitrievna; Ivashkina, Elena Nikolaevna; Frantsina, Evgeniya Vladimirovna; Silko, Galina Yurievna

    2014-01-01

    One of the primary products of hydrodewaxing process is stable gasoline, which is characterized by low octane number on the one hand. On the other hand, it contains a significant amount of iso-paraffins (on average 45% wt.) and naphthenes (on average 25% wt.), which are reagents in the naphtha catalytic reforming process primary reactions. Feasibility of stable gasoline obtained by means of diesel fuel catalytic hydrodewaxing process involving into the processing at the naphtha catalytic refo...

  20. Fuel containment, lightning protection and damage tolerance in large composite primary aircraft structures

    Science.gov (United States)

    Griffin, Charles F.; James, Arthur M.

    1985-01-01

    The damage-tolerance characteristics of high strain-to-failure graphite fibers and toughened resins were evaluated. Test results show that conventional fuel tank sealing techniques are applicable to composite structures. Techniques were developed to prevent fuel leaks due to low-energy impact damage. For wing panels subjected to swept stroke lightning strikes, a surface protection of graphite/aluminum wire fabric and a fastener treatment proved effective in eliminating internal sparking and reducing structural damage. The technology features developed were incorporated and demonstrated in a test panel designed to meet the strength, stiffness, and damage tolerance requirements of a large commercial transport aircraft. The panel test results exceeded design requirements for all test conditions. Wing surfaces constructed with composites offer large weight savings if design allowable strains for compression can be increased from current levels.

  1. Post-irradiation examinations of THERMHET composite fuels for transmutation

    Science.gov (United States)

    Noirot, J.; Desgranges, L.; Chauvin, N.; Georgenthum, V.

    2003-07-01

    The thermal behaviour of composite targets dedicated to minor actinide transmutation was studied using THERMHET (thermal behaviour of heterogeneous fuel) irradiation in the SILOE reactor. Three inert matrix fuel designs were tested (macro-mass, jingle and microdispersion) all with a MgAl 2O 4 spinel inert matrix and around 40% weight of UO 2 to simulate minor actinide inclusions. The post-irradiation examinations led to a new interpretation of the temperature measurement by thermocouples located in the central hole of the pellets. A major change in the micro-dispersed structure was detected. The examinations enabled us to understand the behaviour of the spinel during the different stages of irradiation. They revealed an amorphisation at low temperature and then a nano re-crystallisation at high temperature of the spinel in the micro-dispersed case. These results, together with those obtained in the MATINA irradiation of an equivalent structure, show the importance of the irradiation temperature on spinel behaviour.

  2. Post-irradiation examinations of THERMHET composite fuels for transmutation

    Energy Technology Data Exchange (ETDEWEB)

    Noirot, J. E-mail: jnoirot@cea.fr; Desgranges, L.; Chauvin, N.; Georgenthum, V

    2003-07-01

    The thermal behaviour of composite targets dedicated to minor actinide transmutation was studied using THERMHET (thermal behaviour of heterogeneous fuel) irradiation in the SILOE reactor. Three inert matrix fuel designs were tested (macro-mass, jingle and microdispersion) all with a MgAl{sub 2}O{sub 4} spinel inert matrix and around 40% weight of UO{sub 2} to simulate minor actinide inclusions. The post-irradiation examinations led to a new interpretation of the temperature measurement by thermocouples located in the central hole of the pellets. A major change in the micro-dispersed structure was detected. The examinations enabled us to understand the behaviour of the spinel during the different stages of irradiation. They revealed an amorphisation at low temperature and then a nano re-crystallisation at high temperature of the spinel in the micro-dispersed case. These results, together with those obtained in the MATINA irradiation of an equivalent structure, show the importance of the irradiation temperature on spinel behaviour.

  3. Post-irradiation examinations of THERMHET composite fuels for transmutation

    International Nuclear Information System (INIS)

    Noirot, J.; Desgranges, L.; Chauvin, N.; Georgenthum, V.

    2003-01-01

    The thermal behaviour of composite targets dedicated to minor actinide transmutation was studied using THERMHET (thermal behaviour of heterogeneous fuel) irradiation in the SILOE reactor. Three inert matrix fuel designs were tested (macro-mass, jingle and microdispersion) all with a MgAl 2 O 4 spinel inert matrix and around 40% weight of UO 2 to simulate minor actinide inclusions. The post-irradiation examinations led to a new interpretation of the temperature measurement by thermocouples located in the central hole of the pellets. A major change in the micro-dispersed structure was detected. The examinations enabled us to understand the behaviour of the spinel during the different stages of irradiation. They revealed an amorphisation at low temperature and then a nano re-crystallisation at high temperature of the spinel in the micro-dispersed case. These results, together with those obtained in the MATINA irradiation of an equivalent structure, show the importance of the irradiation temperature on spinel behaviour

  4. Nafion®/H-ZSM-5 composite membranes with superior performance for direct methanol fuel cells

    NARCIS (Netherlands)

    Yildirim, M.H.; Curos, Anna Roca; Motuzas, Julius; Motuzas, J.; Julbe, Anne; Stamatialis, Dimitrios; Wessling, Matthias

    2009-01-01

    Solution cast composite direct methanol fuel cell membranes (DEZ) based on DE2020 Nafion® dispersion and in-house prepared H-ZSM-5 zeolites with different Si/Al ratios were prepared and thoroughly characterized for direct methanol fuel cell (DMFC) applications. All composite membranes have indeed

  5. Composite electrolyte with proton conductivity for low-temperature solid oxide fuel cell

    Energy Technology Data Exchange (ETDEWEB)

    Raza, Rizwan, E-mail: razahussaini786@gmail.com [Department of Physics, COMSATS Institute of Information Technology, Lahore 54000 (Pakistan); Department of Energy Technology, Royal Institute of Technology, KTH, Stockholm 10044 (Sweden); Ahmed, Akhlaq; Akram, Nadeem; Saleem, Muhammad; Niaz Akhtar, Majid; Ajmal Khan, M.; Abbas, Ghazanfar; Alvi, Farah; Yasir Rafique, M. [Department of Physics, COMSATS Institute of Information Technology, Lahore 54000 (Pakistan); Sherazi, Tauqir A. [Department of Chemistry, COMSATS Institute of Information Technology, Abbotabad 22060 (Pakistan); Shakir, Imran [Sustainable Energy Technologies (SET) center, College of Engineering, King Saud University, PO-BOX 800, Riyadh 11421 (Saudi Arabia); Mohsin, Munazza [Department of Physics, Lahore College for Women University, Lahore, 54000 (Pakistan); Javed, Muhammad Sufyan [Department of Physics, COMSATS Institute of Information Technology, Lahore 54000 (Pakistan); Department of Applied Physics, Chongqing University, Chongqing 400044 (China); Zhu, Bin, E-mail: binzhu@kth.se, E-mail: zhubin@hubu.edu.cn [Department of Energy Technology, Royal Institute of Technology, KTH, Stockholm 10044 (Sweden); Hubei Collaborative Innovation Center for Advanced Organic Chemical Materials, Faculty of Physics and Electronic Science/Faculty of Computer and Information, Hubei University, Wuhan, Hubei 430062 (China)

    2015-11-02

    In the present work, cost-effective nanocomposite electrolyte (Ba-SDC) oxide is developed for efficient low-temperature solid oxide fuel cells (LTSOFCs). Analysis has shown that dual phase conduction of O{sup −2} (oxygen ions) and H{sup +} (protons) plays a significant role in the development of advanced LTSOFCs. Comparatively high proton ion conductivity (0.19 s/cm) for LTSOFCs was achieved at low temperature (460 °C). In this article, the ionic conduction behaviour of LTSOFCs is explained by carrying out electrochemical impedance spectroscopy measurements. Further, the phase and structure analysis are investigated by X-ray diffraction and scanning electron microscopy techniques. Finally, we achieved an ionic transport number of the composite electrolyte for LTSOFCs as high as 0.95 and energy and power density of 90% and 550 mW/cm{sup 2}, respectively, after sintering the composite electrolyte at 800 °C for 4 h, which is promising. Our current effort toward the development of an efficient, green, low-temperature solid oxide fuel cell with the incorporation of high proton conductivity composite electrolyte may open frontiers in the fields of energy and fuel cell technology.

  6. Composite electrolyte with proton conductivity for low-temperature solid oxide fuel cell

    Science.gov (United States)

    Raza, Rizwan; Ahmed, Akhlaq; Akram, Nadeem; Saleem, Muhammad; Niaz Akhtar, Majid; Sherazi, Tauqir A.; Ajmal Khan, M.; Abbas, Ghazanfar; Shakir, Imran; Mohsin, Munazza; Alvi, Farah; Javed, Muhammad Sufyan; Yasir Rafique, M.; Zhu, Bin

    2015-11-01

    In the present work, cost-effective nanocomposite electrolyte (Ba-SDC) oxide is developed for efficient low-temperature solid oxide fuel cells (LTSOFCs). Analysis has shown that dual phase conduction of O-2 (oxygen ions) and H+ (protons) plays a significant role in the development of advanced LTSOFCs. Comparatively high proton ion conductivity (0.19 s/cm) for LTSOFCs was achieved at low temperature (460 °C). In this article, the ionic conduction behaviour of LTSOFCs is explained by carrying out electrochemical impedance spectroscopy measurements. Further, the phase and structure analysis are investigated by X-ray diffraction and scanning electron microscopy techniques. Finally, we achieved an ionic transport number of the composite electrolyte for LTSOFCs as high as 0.95 and energy and power density of 90% and 550 mW/cm2, respectively, after sintering the composite electrolyte at 800 °C for 4 h, which is promising. Our current effort toward the development of an efficient, green, low-temperature solid oxide fuel cell with the incorporation of high proton conductivity composite electrolyte may open frontiers in the fields of energy and fuel cell technology.

  7. Fabrication and properties of carbon network reinforced composite fuel

    International Nuclear Information System (INIS)

    Umer, Malik Adeel; Mistarihi, Qusai Mahmoud; Kim, Joon Hui; Hong, Soon Hyung; Ryu, Ho Jin

    2014-01-01

    Zirconium dioxide composites reinforced with 3D glassy carbon foam was fabricated using Spark Plasma Sintering (SPS) with a heating rate of 100degC/min and a uniaxial pressure of 50 MPa at 1500degC, 1600degC, and 1700degC, respectively. The effect of carbon foam on the thermal properties of the ZrO 2 composites was investigated. In addition, the effect of the sintering temperature on the densification of the composites was also investigated and the optimized sintering temperature was identified. The microstructures of 3D carbon foam reinforced ZrO 2 composites showed that the 3D shape of carbon foam was retained after the sintering process, and the ZrO 2 was homogeneously distributed within the 3D carbon foam. At the interfaces between the 3D carbon foam and ZrO 2 , neither a chemical reaction nor a new phase formation was detected by Scanning Electron Microscopy (SEM) and X-ray Diffractometry (XRD). The thermal diffusivity of carbon foam reinforced ZrO 2 composites measured at 1100degC was increased by 47% and reached to 0.66 mm 2 s -1 and the thermal conductivity was increased by 50% and reached to 2.428 W/m-K. (author)

  8. Carbon nanotubes based nafion composite membranes for fuel cell applications

    CSIR Research Space (South Africa)

    Cele, NP

    2009-01-01

    Full Text Available Carbon nanotubes (CNTs) containing Nafion composite membranes were prepared via melt-blending at 250 °C. Using three different types of CNTs such as pure CNTs (pCNTs), oxidised CNTs (oCNTs) and amine functionalised CNTs (fCNTs); the effect of CNTs...

  9. Diesel Surrogate Fuels for Engine Testing and Chemical-Kinetic Modeling: Compositions and Properties.

    Science.gov (United States)

    Mueller, Charles J; Cannella, William J; Bays, J Timothy; Bruno, Thomas J; DeFabio, Kathy; Dettman, Heather D; Gieleciak, Rafal M; Huber, Marcia L; Kweon, Chol-Bum; McConnell, Steven S; Pitz, William J; Ratcliff, Matthew A

    2016-02-18

    The primary objectives of this work were to formulate, blend, and characterize a set of four ultralow-sulfur diesel surrogate fuels in quantities sufficient to enable their study in single-cylinder-engine and combustion-vessel experiments. The surrogate fuels feature increasing levels of compositional accuracy (i.e., increasing exactness in matching hydrocarbon structural characteristics) relative to the single target diesel fuel upon which the surrogate fuels are based. This approach was taken to assist in determining the minimum level of surrogate-fuel compositional accuracy that is required to adequately emulate the performance characteristics of the target fuel under different combustion modes. For each of the four surrogate fuels, an approximately 30 L batch was blended, and a number of the physical and chemical properties were measured. This work documents the surrogate-fuel creation process and the results of the property measurements.

  10. The Influence Of Mass Fraction Of Dressed Coal On Ignition Conditions Of Composite Liquid Fuel Droplet

    Directory of Open Access Journals (Sweden)

    Shlegel Nikita E.

    2015-01-01

    Full Text Available The laws of condition modification of inert heat and ignition in an oxidant flow of composite liquid fuel droplet were studied by the developed experimental setup. Investigations were for composite liquid fuel composition based on the waste of bituminous and nonbaking coal processing, appropriate carbon dust, water, used motor oil. The characteristics of boundary layer inertia heat of composite liquid fuel droplet, thermal decomposition of coal organic part, the yield of volatiles and evaporation of liquid combustion component, ignition of the gas mixture and coke residue were defined.

  11. The Effect of COD Concentration Containing Leaves Litter, Canteen and Composite Waste to the Performance of Solid Phase Microbial Fuel Cell (SMFC)

    Science.gov (United States)

    Samudro, Ganjar; Syafrudin; Nugraha, Winardi Dwi; Sutrisno, Endro; Priyambada, Ika Bagus; Muthi'ah, Hilma; Sinaga, Glory Natalia; Hakiem, Rahmat Tubagus

    2018-02-01

    This research is conducted to analyze and determine the optimum of COD concentration containing leaves litter, canteen and composite waste to power density and COD removal efficiency as the indicator of SMFC performance. COD as the one of organic matter parameters perform as substrate, nutrient and dominating the whole process of SMFC. Leaves litter and canteen based food waste were obtained from TPST UNDIP in Semarang and treated in SMFC reactor. Its reactor was designed 2 liter volume and equipped by homemade graphene electrodes that were utilized at the surface of organic waste as cathode and in a half of reactor height as anode. COD concentration was initially characterized and became variations of initial COD concentration. Waste volume was maintained 2/3 of volume of reactor. Bacteria sources as the important process factor in SMFC were obtained from river sediment which contain bacteroides and exoelectrogenic bacteria. Temperature and pH were not maintained while power density and COD concentration were periodically observed and measured during 44 days. The results showed that power density up to 4 mW/m2 and COD removal efficiency performance up to 70% were reached by leaves litter, canteen and composite waste at days 11 up to days 44 days. Leaves litter contain 16,567 mg COD/l providing higher COD removal efficiency reached approximately 87.67%, more stable power density reached approximately 4.71 mW/m2, and faster optimum time in the third day than canteen based food waste and composite waste. High COD removal efficiency has not yet resulted in high power density.

  12. Highly conductive composites for fuel cell flow field plates and bipolar plates

    Science.gov (United States)

    Jang, Bor Z; Zhamu, Aruna; Song, Lulu

    2014-10-21

    This invention provides a fuel cell flow field plate or bipolar plate having flow channels on faces of the plate, comprising an electrically conductive polymer composite. The composite is composed of (A) at least 50% by weight of a conductive filler, comprising at least 5% by weight reinforcement fibers, expanded graphite platelets, graphitic nano-fibers, and/or carbon nano-tubes; (B) polymer matrix material at 1 to 49.9% by weight; and (C) a polymer binder at 0.1 to 10% by weight; wherein the sum of the conductive filler weight %, polymer matrix weight % and polymer binder weight % equals 100% and the bulk electrical conductivity of the flow field or bipolar plate is at least 100 S/cm. The invention also provides a continuous process for cost-effective mass production of the conductive composite-based flow field or bipolar plate.

  13. Fuel containment and damage tolerance for large composite primary aircraft structures. Phase 1: Testing

    Science.gov (United States)

    Sandifer, J. P.

    1983-01-01

    Technical problems associated with fuel containment and damage tolerance of composite material wings for transport aircraft were identified. The major tasks are the following: (1) the preliminary design of damage tolerant wing surface using composite materials; (2) the evaluation of fuel sealing and lightning protection methods for a composite material wing; and (3) an experimental investigation of the damage tolerant characteristics of toughened resin graphite/epoxy materials. The test results, the test techniques, and the test data are presented.

  14. SiC Composite for Fuel Structure Applications

    Energy Technology Data Exchange (ETDEWEB)

    Yueh, Ken [Electric Power Research Inst. (EPRI), Charlotte, NC (United States)

    2017-12-22

    Extensive evaluation was performed to determine the suitability of using SiC composite as a boiling water reactor (BWR) fuel channel material. A thin walled SiC composite box, 10 cm in dimension by approximately 1.5 mm wall thickness was fabricated using chemical vapor deposition (CVD) for testing. Mechanical test results and performance evaluations indicate the material could meet BWR channel mechanical design requirement. However, large mass loss of up to 21% was measured in in-pile corrosion test under BWR-like conditions in under 3 months of irradiation. A fresh sister sample irradiated in a follow-up cycle under PWR conditions showed no measureable weight loss and thus supports the hypothesis that the oxidizing condition of the BWR-like coolant chemistry was responsible for the high corrosion rate. A thermodynamic evaluation showed SiC is not stable and the material may oxidize to form SiO2 and CO2. Silica has demonstrated stability in high temperature steam environment and form a protective oxide layer under severe accident conditions. However, it does not form a protective layer in water under normal BWR operational conditions due to its high solubility. Corrosion product stabilization by modifying the SiC CVD surface is an approach evaluated in this study to mitigate the high corrosion rate. Titanium and zirconium have been selected as stabilizing elements since both TiSiO4 and ZrSiO4 are insoluble in water. Corrosion test results in oxygenated water autoclave indicate TiSiO4 does not form a protective layer. However, zirconium doped test samples appear to form a stable continuous layer of ZrSiO4 during the corrosion process. Additional process development is needed to produce a good ZrSiC coating to verify functionality of the mitigation concept.

  15. Fuel Cycle Concept with Advanced METMET and Composite Fuel in LWRs

    International Nuclear Information System (INIS)

    Savchenko, A.; Skupov, M.; Vatulin, A.; Glushenkov, A.; Kulakov, G.; Lipkina, K.

    2014-01-01

    The basic factor that limits the serviceability of fuel elements developing in the framework of RERTR Program (transition from HEU to LEU fuel of research reactors) is interaction between U10Mo fuel and aluminium matrix . Interaction results in extra swelling of fuels, disappearance of a heat conducting matrix, a temperature rise in the fuel centre, penetration porosity, etc. Several methods exist to prevent fuel-matrix interaction. In terms of simplifying fuel element fabrication technology and reducing interaction, doping of fuel is the most optimal version

  16. Fire, fuel composition and resilience threshold in subalpine ecosystem.

    Directory of Open Access Journals (Sweden)

    Olivier Blarquez

    Full Text Available BACKGROUND: Forecasting the effects of global changes on high altitude ecosystems requires an understanding of the long-term relationships between biota and forcing factors to identify resilience thresholds. Fire is a crucial forcing factor: both fuel build-up from land-abandonment in European mountains, and more droughts linked to global warming are likely to increase fire risks. METHODS: To assess the vegetation response to fire on a millennium time-scale, we analyzed evidence of stand-to-local vegetation dynamics derived from sedimentary plant macroremains from two subalpine lakes. Paleobotanical reconstructions at high temporal resolution, together with a fire frequency reconstruction inferred from sedimentary charcoal, were analyzed by Superposed Epoch Analysis to model plant behavior before, during and after fire events. PRINCIPAL FINDINGS: We show that fuel build-up from arolla pine (Pinus cembra always precedes fires, which is immediately followed by a rapid increase of birch (Betula sp., then by ericaceous species after 25-75 years, and by herbs after 50-100 years. European larch (Larix decidua, which is the natural co-dominant species of subalpine forests with Pinus cembra, is not sensitive to fire, while the abundance of Pinus cembra is altered within a 150-year period after fires. A long-term trend in vegetation dynamics is apparent, wherein species that abound later in succession are the functional drivers, loading the environment with fuel for fires. This system can only be functional if fires are mainly driven by external factors (e.g. climate, with the mean interval between fires being longer than the minimum time required to reach the late successional stage, here 150 years. CONCLUSION: Current global warming conditions which increase drought occurrences, combined with the abandonment of land in European mountain areas, creates ideal ecological conditions for the ignition and the spread of fire. A fire return interval of less

  17. Effect of advanced fuel cycles on waste management policies

    International Nuclear Information System (INIS)

    Cavedon, J.M.; Haapalehto, T.

    2005-01-01

    The study aims at analysing a range of future fuel cycle options from the perspective of their impact on waste repository demand and specification. The study would focus on: Assessment of the characteristics of radioactive wastes arising from advanced nuclear fuel cycle options, repository performance analysis studies using source terms for waste arising from such advanced nuclear fuel cycles, identification of new options for waste management and disposal. Three families of fuel cycles having increasing recycling capabilities are assessed. Each cycle is composed of waste generating and management processes. Examples of waste generating processes are fuel factories (7 types) and reprocessing plants (7 types). Packaging and conditioning plants (7) and disposal facilities are examples of waste management processes. The characteristic of all these processes have been described and then total waste flows are summarised. In order to simplify the situation, three waste categories have been defined based on the IAEA definitions in order to emphasize the major effects of different types of waste. These categories are: short-life waste for surface or sub-surface disposal, long-life low heat producing waste for geological disposal, high-level waste for geological disposal. The feasibilities of the fuel cycles are compared in terms of economics, primary resource consumption and amount of waste generated. The effect of high-level waste composition for the repository performance is one of the tools in these comparisons. The results of this will be published as an NEA publication before the end of 2005. (authors)

  18. Effect of biodiesel fuels on diesel engine emissions

    Energy Technology Data Exchange (ETDEWEB)

    Lapuerta, Magin; Armas, Octavio; Rodriguez-Fernandez, Jose [Escuela Tecnica Superior de Ingenieros Industriales, University of Castilla-La Mancha, Avda. Camilo Jose Cela, s/n. 13071 Ciudad Real (Spain)

    2008-04-15

    The call for the use of biofuels which is being made by most governments following international energy policies is presently finding some resistance from car and components manufacturing companies, private users and local administrations. This opposition makes it more difficult to reach the targets of increased shares of use of biofuels in internal combustion engines. One of the reasons for this resistance is a certain lack of knowledge about the effect of biofuels on engine emissions. This paper collects and analyzes the body of work written mainly in scientific journals about diesel engine emissions when using biodiesel fuels as opposed to conventional diesel fuels. Since the basis for comparison is to maintain engine performance, the first section is dedicated to the effect of biodiesel fuel on engine power, fuel consumption and thermal efficiency. The highest consensus lies in an increase in fuel consumption in approximate proportion to the loss of heating value. In the subsequent sections, the engine emissions from biodiesel and diesel fuels are compared, paying special attention to the most concerning emissions: nitric oxides and particulate matter, the latter not only in mass and composition but also in size distributions. In this case the highest consensus was found in the sharp reduction in particulate emissions. (author)

  19. The Role of Hydrogen Bonds Of The Azeotropic Hydrous Ethanol Fuel Composition To The Exhaust Emissions

    Science.gov (United States)

    Made Suarta, I.; Nyoman Gede Baliarta, I.; Sopan Rahtika, I. P. G.; Wijaya Sunu, Putu

    2018-01-01

    In this study observed the role of hydrogen bonding to the composition of exhaust emissions which is produced hydrous ethanol fuel (95.5% v). Testing is done by using single cylinder four stroke motor engine. The composition of exhaust gas emissions is tested using exhaust gas analyzer on lean and stoichiometry mixer. The exhaust emissions produced by anhydrous ethanol were also tested. The composition of emissions produced by that two fuels is compared. The results showed CO emissions levels produced by hydrous ethanol are slightly higher than anhydrous ethanol in stoichiometric mixtures. But the composition of CO hydrous ethanol emissions is lower in the lean mix. If lean the mixer the different in the composition of emissions is increasing. On hydrous ethanol emission CO2 content little bit lower on the stoichiometric mixer and higher on the lean mixture. Exhaust emissions of ethanol fuel also produce O2. O2 hydrous ethanol emissions is higher than anhydrous ethanol fuel.

  20. Fuel Price Effects on Readiness

    Science.gov (United States)

    2014-05-01

    have also excluded liquefied propane gas ( LPG ), from this study. 10 through four IDIQ...Wide Fuel Management 1. DLA’s Role DLA-E has the mission of acquiring, storing, selling, and distributing energy including petroleum, natural gas ...energy, and installations also use energy in the form of electricity (11 percent), natural gas (8 percent), and coal (2 percent). See Schwartz, Blakely

  1. Feasibility of Carbon Fiber/PEEK Composites for Cryogenic Fuel Tank Applications

    Science.gov (United States)

    Doyle, K.; Doyle, A.; O Bradaigh, C. M.; Jaredson, D.

    2012-07-01

    This paper investigates the feasibility of CF/PEEK composites for manufacture of cryogenic fuel tanks for Next Generation Space Launchers. The material considered is CF/PEEK tape from Suprem SA and the proposed manufacturing process for the fuel tank is Automated Tape Placement. Material characterization was carried out on test laminates manufactured in an autoclave and also by Automated Tape Placement with in-situ consolidation. The results of the two processes were compared to establish if there is any knock down in properties for the automated tape placement process. A permeability test rig was setup with a helium leak detector and the effect of thermal cycling on the permeability properties of CF/PEEK was measured. A 1/10th scale demonstrator was designed and manufactured consisting of a cylinder manufactured by automated tape placement and an upper dome manufactured by autoclave processing. The assembly was achieved by Amorphous Interlayer Bonding with PEI.

  2. Compositional effects on the ignition of FACE gasolines

    KAUST Repository

    Sarathy, Mani; Kukkadapu, Goutham; Mehl, Marco; Javed, Tamour; Ahmed, Ahfaz; Naser, Nimal; Tekawade, Aniket; Kosiba, Graham; Alabbad, Mohammed; Singh, Eshan; Park, Sungwoo; Rashidi, Mariam Al; Chung, Suk-Ho; Roberts, William L.; Oehlschlaeger, Matthew A.; Sung, Chih-Jen; Farooq, Aamir

    2016-01-01

    As regulatory measures for improved fuel economy and decreased emissions are pushing gasoline engine combustion technologies towards extreme conditions (i.e., boosted and intercooled intake with exhaust gas recirculation), fuel ignition characteristics become increasingly important for enabling stable operation. This study explores the effects of chemical composition on the fundamental ignition behavior of gasoline fuels. Two well-characterized, high-octane, non-oxygenated FACE (Fuels for Advanced Combustion Engines) gasolines, FACE F and FACE G, having similar antiknock indices but different octane sensitivities and chemical compositions are studied. Ignition experiments were conducted in shock tubes and a rapid compression machine (RCM) at nominal pressures of 20 and 40. atm, equivalence ratios of 0.5 and 1.0, and temperatures ranging from 650 to 1270. K. Results at temperatures above 900. K indicate that ignition delay time is similar for these fuels. However, RCM measurements below 900. K demonstrate a stronger negative temperature coefficient behavior for FACE F gasoline having lower octane sensitivity. In addition, RCM pressure profiles under two-stage ignition conditions illustrate that the magnitude of low-temperature heat release (LTHR) increases with decreasing fuel octane sensitivity. However, intermediate-temperature heat release is shown to increase as fuel octane sensitivity increases. Various surrogate fuel mixtures were formulated to conduct chemical kinetic modeling, and complex multicomponent surrogate mixtures were shown to reproduce experimentally observed trends better than simpler two- and three-component mixtures composed of n-heptane, iso-octane, and toluene. Measurements in a Cooperative Fuels Research (CFR) engine demonstrated that the multicomponent surrogates accurately captured the antiknock quality of the FACE gasolines. Simulations were performed using multicomponent surrogates for FACE F and G to reveal the underlying chemical

  3. Compositional effects on the ignition of FACE gasolines

    KAUST Repository

    Sarathy, Mani

    2016-05-08

    As regulatory measures for improved fuel economy and decreased emissions are pushing gasoline engine combustion technologies towards extreme conditions (i.e., boosted and intercooled intake with exhaust gas recirculation), fuel ignition characteristics become increasingly important for enabling stable operation. This study explores the effects of chemical composition on the fundamental ignition behavior of gasoline fuels. Two well-characterized, high-octane, non-oxygenated FACE (Fuels for Advanced Combustion Engines) gasolines, FACE F and FACE G, having similar antiknock indices but different octane sensitivities and chemical compositions are studied. Ignition experiments were conducted in shock tubes and a rapid compression machine (RCM) at nominal pressures of 20 and 40. atm, equivalence ratios of 0.5 and 1.0, and temperatures ranging from 650 to 1270. K. Results at temperatures above 900. K indicate that ignition delay time is similar for these fuels. However, RCM measurements below 900. K demonstrate a stronger negative temperature coefficient behavior for FACE F gasoline having lower octane sensitivity. In addition, RCM pressure profiles under two-stage ignition conditions illustrate that the magnitude of low-temperature heat release (LTHR) increases with decreasing fuel octane sensitivity. However, intermediate-temperature heat release is shown to increase as fuel octane sensitivity increases. Various surrogate fuel mixtures were formulated to conduct chemical kinetic modeling, and complex multicomponent surrogate mixtures were shown to reproduce experimentally observed trends better than simpler two- and three-component mixtures composed of n-heptane, iso-octane, and toluene. Measurements in a Cooperative Fuels Research (CFR) engine demonstrated that the multicomponent surrogates accurately captured the antiknock quality of the FACE gasolines. Simulations were performed using multicomponent surrogates for FACE F and G to reveal the underlying chemical

  4. Experimental study on the impact of operating conditions and fuel composition on PCCI combustion

    Energy Technology Data Exchange (ETDEWEB)

    Leermakers, C.A.J.

    2010-03-15

    Premixed Charge Compression Ignition (PCCI) is a combustion concept that holds the promise of combining emission levels of a spark-ignition (SI) engine with the efficiency of a compressionignition (CI) engine. In a short term scenario, PCCI combustion will be used in the low load part of the engine operating range only. This would guarantee low engine-out emission levels at operating conditions where exhaust temperatures are too low for effective NOx reduction through catalytic after treatment. At higher loads, the engine would run in conventional CI combustion mode, with emission requirements met through catalytic NOx reduction. Implicit with this scenario is that engine hardware design would be very close to that of current modern diesel engines. Compression ratio could be made load dependent through implementation of variable valve actuation. The PCCI experiments presented here have been performed using a modified 6 cylinder 12.6 liter heavy duty DI DAF XE 355 C engine. Experiments are conducted in one dedicated cylinder, which is equipped with a stand-alone fuel injection system, EGR circuit, and air compressor. For the low to medium load operating range the compression ratio has been lowered to 12:1 by means of a thicker head gasket. As engine hardware should - in the short term - preferably remain close to current diesel engines, optimizing operating conditions should focus on parameters like EGR level, intake temperature, intake pressure and injection timing. While past work in the Combustion Technology group has focused on low load PCCI combustion, in this report the effects on engine performance and emission behavior are investigated for both low and medium load PCCI combustion, up to 40% of full load. In the interpretation of experimental results, emphasis lies on the effect on combustion phasing and maximum pressure rise rate, which are inherent challenges to enable viable PCCI combustion. As in the short term scenario fuels will be used that are not too

  5. Cost-Effective Fuel Treatment Planning

    Science.gov (United States)

    Kreitler, J.; Thompson, M.; Vaillant, N.

    2014-12-01

    The cost of fighting large wildland fires in the western United States has grown dramatically over the past decade. This trend will likely continue with growth of the WUI into fire prone ecosystems, dangerous fuel conditions from decades of fire suppression, and a potentially increasing effect from prolonged drought and climate change. Fuel treatments are often considered the primary pre-fire mechanism to reduce the exposure of values at risk to wildland fire, and a growing suite of fire models and tools are employed to prioritize where treatments could mitigate wildland fire damages. Assessments using the likelihood and consequence of fire are critical because funds are insufficient to reduce risk on all lands needing treatment, therefore prioritization is required to maximize the effectiveness of fuel treatment budgets. Cost-effectiveness, doing the most good per dollar, would seem to be an important fuel treatment metric, yet studies or plans that prioritize fuel treatments using costs or cost-effectiveness measures are absent from the literature. Therefore, to explore the effect of using costs in fuel treatment planning we test four prioritization algorithms designed to reduce risk in a case study examining fuel treatments on the Sisters Ranger District of central Oregon. For benefits we model sediment retention and standing biomass, and measure the effectiveness of each algorithm by comparing the differences among treatment and no treat alternative scenarios. Our objective is to maximize the averted loss of net benefits subject to a representative fuel treatment budget. We model costs across the study landscape using the My Fuel Treatment Planner software, tree list data, local mill prices, and GIS-measured site characteristics. We use fire simulations to generate burn probabilities, and estimate fire intensity as conditional flame length at each pixel. Two prioritization algorithms target treatments based on cost-effectiveness and show improvements over those

  6. Rhodium self-powered detector for monitoring neutron fluence, energy production, and isotopic composition of fuel

    International Nuclear Information System (INIS)

    Sokolov, A.P.; Pochivalin, G.P.; Shipovskikh, Yu.M.; Garusov, Yu.V.; Chernikov, O.G.; Shevchenko, V.G.

    1993-01-01

    The use of self-powered detectors (SPDs) with a rhodium emitter customarily involves monitoring of neutron fields in the core of a nuclear reactor. Since current in an SPD is generated primarily because of the neutron flux, which is responsible for the dynamics of particular nuclear transformations, including fission reactions of heavy isotopes, the detector signal can be attributed unambiguously to energy release at the location of the detector. Computation modeling performed with the KOMDPS package of programs of the current formation in a rhodium SPD along with the neutron-physical processes that occur in the reactor core makes it possible to take account of the effect of the principal factors characterizing the operating conditions and the design features of the fuel channel and the detector, reveal quantitative relations between the generated signal and individual physical parameters, and determine the metrological parameters of the detector. The formation and transport of changed particles in the sensitive part of the SPC is calculated by the Monte Carlo method. The emitter activation, neutron transport, and dynamics of the isotopic composition in the fuel channel containing the SPD are determined by solving the kinetic equation in the multigroup representation of the neutron spectrum, using the discrete ordinate method. In this work the authors consider the operation of a rhodium SPD in a bundle of 49 fuel channels of the RBMK-1000 reactor with a fuel enrichment of 2.4% from the time it is inserted into a fresh channel

  7. Effect of Propellant Composition to the Temperature Sensitivity of Composite Propellant

    International Nuclear Information System (INIS)

    Aziz, Amir; Mamat, Rizalman; Amin, Makeen; Wan Ali, Wan Khairuddin

    2012-01-01

    The propellant composition is one of several parameter that influencing the temperature sensitivity of composite propellant. In this paper, experimental investigation of temperature sensitivity in burning rate of composite propellant was conducted. Four sets of different propellant compositions had been prepared with the combination of ammonium perchlorate (AP) as an oxidizer, aluminum (Al) as fuel and hydroxy-terminated polybutadiene (HTPB) as fuel and binder. For each mixture, HTPB binder was fixed at 15% and cured with isophorone diisocyanate (IPDI). By varying AP and Al, the effect of oxidizer- fuel mixture ratio (O/F) on the whole propellant can be determined. The propellant strands were manufactured using compression molded method and burnt in a strand burner using wire technique over a range of pressure from 1 atm to 31 atm. The results obtained shows that the temperature sensitivity, a, increases with increasing O/F. Propellant p80 which has O/F ratio of 80/20 gives the highest value of temperature sensitivity which is 1.687. The results shows that the propellant composition has significant effect on the temperature sensitivity of composite propellant

  8. Isotopic composition and radiological properties of uranium in selected fuel cycles

    International Nuclear Information System (INIS)

    Fleischman, R.M.; Liikala, R.C.

    1975-04-01

    Three major topic areas are discussed: First, the properties of the uranium isotopes are defined relative to their respective roles in the nuclear fuel cycle. Secondly, the most predominant fuel cycles expected in the U. S. are described. These are the Light Water Reactor (LWR), High Temperature Gas Cooled Reactor (HTGR), and Liquid Metal Fast Breeder Reactor (LMFBR) fuel cycles. The isotopic compositions of uranium and plutonium fuels expected for these fuel cycles are given in some detail. Finally the various waste streams from these fuel cycles are discussed in terms of their relative toxicity. Emphasis is given to the high level waste streams from reprocessing of spent fuel. Wastes from the various fuel cycles are compared based on projected growth patterns for nuclear power and its various components. (U.S.)

  9. Nafion®/ODF-silica composite membranes for medium temperature proton exchange membrane fuel cells

    KAUST Repository

    Treekamol, Yaowapa

    2014-01-01

    A series of composite membranes were prepared by dispersing fluorinated polyoxadiazole oligomer (ODF)-functionalized silica nanoparticles in a Nafion matrix. Both melt-extrusion and solvent casting processes were explored. Ion exchange capacity, conductivity, water uptake and dimensional stability, thermal stability and morphology were characterized. The inclusion of functionalized nanoparticles proved advantageous, mainly due to a physical crosslinking effect and better water retention, with functionalized nanoparticles performing better than the pristine silica particles. For the same filler loading, better nanoparticle dispersion was achieved for solvent-cast membranes, resulting in higher proton conductivity. Filler agglomeration, however,was more severe for solvent-castmembranes at loadings beyond 5wt.%. The composite membranes showed excellent thermal stability, allowing for operation in medium temperature PEM fuel cells. Fuel cell performance of the compositemembranesdecreaseswithdecreasing relativehumidity, but goodperformance values are still obtained at 34% RHand 90 °C,with the best results obtained for solvent castmembranes loaded with 10 wt.% ODF-functionalized silica. Hydrogen crossover of the composite membranes is higher than that forpureNafion membranes,possiblydue toporosityresulting fromsuboptimalparticle- matrixcompatibility. © 2013 Crown Copyright and Elsevier BV. All rights reserved.

  10. Evaluation of core compositions for use in breed and burn reactors and limited-separations fuel cycles

    International Nuclear Information System (INIS)

    Petroski, Robert; Forget, Benoit; Forsberg, Charles

    2013-01-01

    Highlights: ► Calculated minimum burnup and irradiation damage for B and B reactor compositions. ► Computed doubling time of fuel cycles using B and B reactors and no chemical separations. ► Determined sensitivity of doubling time to using melt refining vs. direct reuse. ► Examined tradeoff between power density and neutronics for different coolants. - Abstract: Previously developed methods for analyzing breed-and-burn (B and B) reactors are applied to a wide range of core compositions. The compositions studied include different fuel types, steel and silicon carbide structure, and sodium, lead/lead bismuth eutectic (LBE), and gas coolants. These compositions are evaluated for use in “minimum burnup” B and B reactors in which it is assumed that blocks comprising the core can be shuffled in all three dimensions to flatten out non-uniformities in burnup. The two figures of merit evaluated are the minimum irradiation damage requirement and reactor fleet doubling time. To minimize irradiation damage, gas coolants perform best, followed by lead/LBE then sodium. High uranium-content metal fuel outperforms compound fuels, and different types of steel are similar and perform slightly better than silicon carbide. Once-through irradiation damage requirements can be surprisingly modest in minimum burnup B and B reactors, with a wide range of compositions viable at irradiation damage levels 50% higher than existing materials data. Doubling times were calculated for a reactor fleet consisting of B and B reactors operating in a limited-separations fuel cycle; i.e., a fuel cycle with no chemical separation of actinides. The effects of different cooling times and removal of fission products using a melt refining process are evaluated. To minimize doubling time, sodium cooled compositions perform best because they are able to achieve core power densities several times larger than compositions using other coolants. A hypothetical sodium-cooled core composition with high

  11. Plutonium isotopic composition of high burnup spent fuel discharged from light water reactors

    International Nuclear Information System (INIS)

    Nakano, Yoshihiro; Okubo, Tsutomu

    2011-01-01

    Highlights: → Pu isotopic composition of fuel affects FBR core nuclear characteristics very much. → Spent fuel compositions of next generation LWRs with burnup of 70 GWd/t were obtained. → Pu isotopic composition and amount in the spent fuel with 70 GWd/t were evaluated. → Spectral shift rods of high burnup BWR increases the fissile Pu fraction of spent fuel. → Wide fuel rod pitch of high burnup PWR lowers the fissile Pu fraction of spent fuel. - Abstract: The isotopic composition and amount of plutonium (Pu) in spent fuel from a high burnup boiling water reactor (HB-BWR) and a high burnup pressurized water reactor (HB-PWR), each with an average discharge burnup of 70 GWd/t, were estimated, in order to evaluate fast breeder reactor (FBR) fuel composition in the transition period from LWRs to FBRs. The HB-BWR employs spectral shift rods and the neutron spectrum is shifted through the operation cycle. The weight fraction of fissile plutonium (Puf) isotopes to the total plutonium in HB-BWR spent fuel after 5 years cooling is 62%, which is larger than that of conventional BWRs with average burnup of 45 GWd/t, because of the spectral shift operation. The amount of Pu produced in the HB-BWR is also larger than that produced in a conventional BWR. The HB-PWR uses a wider pitch 17 x 17 fuel rod assembly to optimize neutron slowing down. The Puf fraction of HB-PWR spent fuel after 5 years cooling is 56%, which is smaller than that of conventional PWRs with average burnup of 49 GWd/t, mainly because of the wider pitch. The amount of Pu produced in the HB-PWR is also smaller than that in conventional PWRs.

  12. Effects of fueling profiles on plasma transport

    International Nuclear Information System (INIS)

    Houlberg, W.A.; Mense, A.T.; Attenberger, S.E.; Milora, S.L.

    1977-01-01

    The effects of cold particle fueling profiles on particle and energy transport in an ignition sized tokamak plasma are investigated in this study with a one-dimensional, multifluid transport model. A density gradient driven trapped particle microinstability model for plasma transport is used to demonstrate potential effects of fueling profiles on ignition requirements. Important criteria for the development of improved transport models under the conditions of shallow particle fueling profiles are outlined. A discrete pellet fueling model indicates that large fluctuations in density and temperature may occur in the outer regions of the plasma with large, shallowly penetrating pellets, but fluctuations in the pressure profile are small. The hot central core of the plasma remains unaffected by the large fluctuations near the plasma edge

  13. VOC composition of current motor vehicle fuels and vapors, and collinearity analyses for receptor modeling.

    Science.gov (United States)

    Chin, Jo-Yu; Batterman, Stuart A

    2012-03-01

    The formulation of motor vehicle fuels can alter the magnitude and composition of evaporative and exhaust emissions occurring throughout the fuel cycle. Information regarding the volatile organic compound (VOC) composition of motor fuels other than gasoline is scarce, especially for bioethanol and biodiesel blends. This study examines the liquid and vapor (headspace) composition of four contemporary and commercially available fuels: gasoline (gasoline), ultra-low sulfur diesel (ULSD), and B20 (20% soy-biodiesel and 80% ULSD). The composition of gasoline and E85 in both neat fuel and headspace vapor was dominated by aromatics and n-heptane. Despite its low gasoline content, E85 vapor contained higher concentrations of several VOCs than those in gasoline vapor, likely due to adjustments in its formulation. Temperature changes produced greater changes in the partial pressures of 17 VOCs in E85 than in gasoline, and large shifts in the VOC composition. B20 and ULSD were dominated by C(9) to C(16)n-alkanes and low levels of the aromatics, and the two fuels had similar headspace vapor composition and concentrations. While the headspace composition predicted using vapor-liquid equilibrium theory was closely correlated to measurements, E85 vapor concentrations were underpredicted. Based on variance decomposition analyses, gasoline and diesel fuels and their vapors VOC were distinct, but B20 and ULSD fuels and vapors were highly collinear. These results can be used to estimate fuel related emissions and exposures, particularly in receptor models that apportion emission sources, and the collinearity analysis suggests that gasoline- and diesel-related emissions can be distinguished. Copyright © 2011 Elsevier Ltd. All rights reserved.

  14. Effect of different fuel options on performance of high-temperature PEMFC (proton exchange membrane fuel cell) systems

    International Nuclear Information System (INIS)

    Authayanun, Suthida; Saebea, Dang; Patcharavorachot, Yaneeporn; Arpornwichanop, Amornchai

    2014-01-01

    High-temperature proton exchange membrane fuel cells (HT-PEMFCs) have received substantial attention due to their high CO (carbon monoxide) tolerance and simplified water management. The hydrogen and CO fractions affect the HT-PEMFC performance and different fuel sources for hydrogen production result in different product gas compositions. Therefore, the aim of this study is to investigate the theoretical performance of HT-PEMFCs fueled by the reformate gas derived from various fuel options (i.e., methane, methanol, ethanol, and glycerol). Effects of fuel types and CO poisoning on the HT-PEMFC performance are analyzed. Furthermore, the necessity of a water-gas shift (WGS) reactor as a CO removal unit for pretreating the reformate gas is investigated for each fuel type. The methane steam reforming shows the highest possibility of CO formation, whereas the methanol steam reforming produces the lowest quantity of CO in the reformate gas. The methane fuel processing gives the maximum fraction of hydrogen (≈0.79) when the WGS reactor is included. The most suitable fuel is the one with the lowest CO poisoning effect and the maximum fuel cell performance. It is found that the HT-PEMFC system fueled by methanol without the WGS reactor and methane with WGS reactor shows the highest system efficiency (≈50%). - Highlights: • Performance of HT-PEMFC run on different fuel options is theoretically investigated. • Glycerol, methanol, ethanol and methane are hydrogen sources for the HT-PEMFC system. • Effect of CO poisoning on the HT-PEMFC performance is taken into account. • The suitable fuel for HT-PEMFC system is identified regarding the system efficiency

  15. Catalytic Surface Promotion of Composite Cathodes in Protonic Ceramic Fuel Cells

    DEFF Research Database (Denmark)

    Solis, Cecilia; Navarrete, Laura; Bozza, Francesco

    2015-01-01

    Composite cathodes based on an electronic conductor and a protonic conductor show advantages for protonic ceramic fuel cells. In this work, the performance of a La5.5WO11.25-δ/ La0.8Sr0.2MnO3+δ (LWO/LSM) composite cathode in a fuel cell based on an LWO protonic conducting electrolyte is shown...

  16. Method for forming nuclear fuel containers of a composite construction and the product thereof

    International Nuclear Information System (INIS)

    Cheng, B.-C.; Rosenbaum, H.S.; Armijo, J.S.

    1981-01-01

    An improved method of producing a composite nuclear fuel container is described which comprises a casing or fuel sheath of zirconium or its alloy with a lining cladding of deposited copper superimposed over the inside surface of the zirconium or alloy and a layer of oxide of the zirconium or alloy formed on the inside surface of the casing or sheath. (U.K.)

  17. Synthesis and sintering of UN-UO{sub 2} fuel composites

    Energy Technology Data Exchange (ETDEWEB)

    Jaques, Brian J., E-mail: BrianJaques@BoiseState.edu [Department of Materials Science and Engineering, Boise State University, 1910 University Dr., Boise, ID 83725 (United States); Center for Advanced Energy Studies, 995 University Blvd., Idaho Falls, ID 83401 (United States); Watkins, Jennifer; Croteau, Joseph R.; Alanko, Gordon A. [Department of Materials Science and Engineering, Boise State University, 1910 University Dr., Boise, ID 83725 (United States); Center for Advanced Energy Studies, 995 University Blvd., Idaho Falls, ID 83401 (United States); Tyburska-Püschel, Beata [Department of Engineering Physics, University of Wisconsin–Madison, 1500 Engineering Dr., Madison, WI 53706 (United States); Meyer, Mitch [Idaho National Laboratory, Idaho Falls, ID 83415 (United States); Xu, Peng; Lahoda, Edward J. [Westinghouse Electric Company LLC, Pittsburgh, PA 15235 (United States); Butt, Darryl P., E-mail: DarrylButt@BoiseState.edu [Department of Materials Science and Engineering, Boise State University, 1910 University Dr., Boise, ID 83725 (United States); Center for Advanced Energy Studies, 995 University Blvd., Idaho Falls, ID 83401 (United States)

    2015-11-15

    The design and development of an economical, accident tolerant fuel (ATF) for use in the current light water reactor (LWR) fleet is highly desirable for the future of nuclear power. Uranium mononitride has been identified as an alternative fuel with higher uranium density and thermal conductivity when compared to the benchmark, UO{sub 2}, which could also provide significant economic benefits. However, UN by itself reacts with water at reactor operating temperatures. In order to reduce its reactivity, the addition of UO{sub 2} to UN has been suggested. In order to avoid carbon impurities, UN was synthesized from elemental uranium using a hydride-dehydride-nitride thermal synthesis route prior to mixing with up to 10 wt% UO{sub 2} in a planetary ball mill. UN and UN – UO{sub 2} composite pellets were sintered in Ar – (0–1 at%) N{sub 2} to study the effects of nitrogen concentration on the evolved phases and microstructure. UN and UN-UO{sub 2} composite pellets were also sintered in Ar – 100 ppm N{sub 2} to assess the effects of temperature (1700–2000 °C) on the final grain morphology and phase concentration.

  18. Multidisciplinary Simulation of Graphite-Composite and Cermet Fuel Elements for NTP Point of Departure Designs

    Science.gov (United States)

    Stewart, Mark E.; Schnitzler, Bruce G.

    2015-01-01

    This paper compares the expected performance of two Nuclear Thermal Propulsion fuel types. High fidelity, fluid/thermal/structural + neutronic simulations help predict the performance of graphite-composite and cermet fuel types from point of departure engine designs from the Nuclear Thermal Propulsion project. Materials and nuclear reactivity issues are reviewed for each fuel type. Thermal/structural simulations predict thermal stresses in the fuel and thermal expansion mis-match stresses in the coatings. Fluid/thermal/structural/neutronic simulations provide predictions for full fuel elements. Although NTP engines will utilize many existing chemical engine components and technologies, nuclear fuel elements are a less developed engine component and introduce design uncertainty. Consequently, these fuel element simulations provide important insights into NTP engine performance.

  19. Performance of direct methanol fuel cell with a palladium–silica nanofibre/Nafion composite membrane

    International Nuclear Information System (INIS)

    Thiam, H.S.; Daud, W.R.W.; Kamarudin, S.K.; Mohamad, A.B.; Kadhum, A.A.H.; Loh, K.S.; Majlan, E.H.

    2013-01-01

    Highlights: • This study introduces Pd–SiO 2 Carbon Nano Fibre as an additive to Nafion membrane. • It investigates the effects of membrane annealing temperature and casting solvent. • Results show that Pd–SiO 2 fibre/Nafion performs lower methanol permeability. • This could effectively reduces methanol crossover in direct methanol fuel cell. - Abstract: Palladium–silica nanofibres (Pd–SiO 2 fibre) were adopted as an additive to Nafion recast membranes in order to reduce methanol crossover and improve the cell performance. The performance of a membrane electrode assembly (MEA) with fabricated composite membrane was evaluated through a passive air-breathing single cell direct methanol fuel cell (DMFC). The limiting crossover current density was measured to determine the methanol permeation in the DMFC. The effects of membrane annealing temperature and casting solvent of composite membrane on the cell performance were investigated and are discussed here. Compared to recast Nafion with the same thickness (150 μm), the Pd–SiO 2 fibre/Nafion composite membrane exhibited higher performance and lower methanol permeability. A maximum power density of 10.4 mW cm −2 was obtained with a 2 M methanol feed, outperforming the much thicker commercial Nafion 117 with a power density of 7.95 mW cm −2 under the same operating conditions. The experimental results showed that the Pd–SiO 2 fibre as inorganic fillers for Nafion could effectively reduce methanol crossover and improve the membrane performance in DMFC applications

  20. Copper-substituted perovskite compositions for solid oxide fuel cell cathodes and oxygen reduction electrodes in other electrochemical devices

    Science.gov (United States)

    Rieke, Peter C [Pasco, WA; Coffey, Gregory W [Richland, WA; Pederson, Larry R [Kennewick, WA; Marina, Olga A [Richland, WA; Hardy, John S [Richland, WA; Singh, Prabhaker [Richland, WA; Thomsen, Edwin C [Richland, WA

    2010-07-20

    The present invention provides novel compositions that find advantageous use in making electrodes for electrochemical cells. Also provided are electrochemical devices that include active oxygen reduction electrodes, such as solid oxide fuel cells, sensors, pumps and the like. The compositions comprises a copper-substituted ferrite perovskite material. The invention also provides novel methods for making and using the electrode compositions and solid oxide fuel cells and solid oxide fuel cell assemblies having cathodes comprising the compositions.

  1. Thermochemical modeling of nuclear fuel and the effects of oxygen potential buffers

    Energy Technology Data Exchange (ETDEWEB)

    Loukusa, Henri, E-mail: henri.loukusa@vtt.fi; Ikonen, Timo; Valtavirta, Ville; Tulkki, Ville

    2016-12-01

    The elemental and chemical composition of nuclear fuel pellets are key factors influencing the material properties of the pellets. The oxidation state of the fuel is one of the most important chemical properties influencing the material properties of the fuel, and it can only be determined with the knowledge of the chemical composition. A measure of the oxidation state is the oxygen chemical potential of the fuel. It can be buffered by redox pairs, such as the well-known Mo/MoO{sub 2} pair. In this work, the elemental composition of the fuel is obtained from a burnup calculation and the temperature and pressure calculated with a fuel performance code. An estimate of the oxygen potential of fuel is calculated with Gibbs energy minimization. The results are compared against experimental data from the literature. The significance of the UMoO{sub 6} compound and its buffering effect on the oxygen potential is emphasized. - Highlights: • A Gibbs energy minimization routine has been developed for nuclear fuel modeling. • The initial stoichiometry affects the development of the oxygen potential of fuel. • UMoO{sub 6} is found to buffer the oxygen potential of nuclear fuel.

  2. A Nafion-Ceria Composite Membrane Electrolyte for Reduced Methanol Crossover in Direct Methanol Fuel Cells

    Directory of Open Access Journals (Sweden)

    Parthiban Velayutham

    2017-02-01

    Full Text Available An alternative Nafion composite membrane was prepared by incorporating various loadings of CeO2 nanoparticles into the Nafion matrix and evaluated its potential application in direct methanol fuel cells (DMFCs. The effects of CeO2 in the Nafion matrix were systematically studied in terms of surface morphology, thermal and mechanical stability, proton conductivity and methanol permeability. The composite membrane with optimum filler content (1 wt. % CeO2 exhibits a proton conductivity of 176 mS·cm−1 at 70 °C, which is about 30% higher than that of the unmodified membrane. Moreover, all the composite membranes possess a much lower methanol crossover compared to pristine Nafion membrane. In a single cell DMFC test, MEA fabricated with the optimized composite membrane delivered a peak power density of 120 mW·cm−2 at 70 °C, which is about two times higher in comparison with the pristine Nafion membrane under identical operating conditions.

  3. Data book of the isotopic composition of spent fuel in light water reactors

    International Nuclear Information System (INIS)

    Naito, Yoshitaka; Kurosawa, Masayoshi; Kaneko, Toshiyuki.

    1994-03-01

    In the framework of the activity of the working group on Evaluation of Nuclide Generation and Depletion in the Japanese Nuclear Data Committee, we summarized the assay data of the isotopic composition of LWR spent fuels in order to verify the accuracy of the burnup calculation codes. The report contains the data collected from the 13 light water reactors (LWRs) including the 9 LWRs (5 PWRs and 4 BWRs) in Europe and USA, the 4 LWRs (2 PWRs and 2 BWRs) in Japan. The collected data were sorted into the irradiation history of the fuel samples, the composition of the fuel assemblies, the sampling position and the isotopic composition of the fuel samples. (author)

  4. Databook of the isotopic composition of spent fuel in light water reactors

    International Nuclear Information System (INIS)

    Naito, Yoshitaka; Kurosawa, Masayoshi; Kaneko, Toshiyuki.

    1993-03-01

    In the framework of the activity of the nuclide production evaluation WG in the sigma committee, we summarized the measurement data of the isotopic composition of LWR spent fuels necessary to evaluate the accuracy of the burnup calculation codes. The collected data were arranged to be classified into the irradiation history of the fuel samples, the composition of the fuel assemblies, the sampling position and the isotopic composition of the fuel samples, in order to supply the information necessary to the benchmark calculation. This report describes the data collected from the 13 LWRs including the 9 LWRs (5 PWR and 4 BWR) in Europe and the USA, the 4 LWRs (2 PWR and 2 BWR) in Japan. Finally, the study on the burnup characteristics of the U, Pu isotopes is described. (author)

  5. Effects of fueling profiles on plasma transport

    International Nuclear Information System (INIS)

    Mense, A.T.; Houlberg, W.A.; Attenberger, S.E.; Milora, S.L.

    1978-04-01

    A one-dimensional (1-D), multifluid transport model is used to investigate the effects of particle fueling profiles on plasma transport in an ignition-sized tokamak (TNS). Normal diffusive properties of plasmas will likely maintain the density at the center of the discharge even if no active fueling is provided there. This significantly relaxes the requirements for fuel penetration. Not only is lower fuel penetration easier to achieve, but it may have the advantage of reducing or eliminating density gradient-driven trapped particle microinstabilities. Simulation of discrete pellet fueling indicates that relatively low velocity (approximately 10 3 m/sec) pellets may be sufficient to fuel a TNS-sized device (approximately 1.25-m minor radius), to produce a relatively broad, cool edge region of plasma which should reduce the potential for sputtering, and also to reduce the likelihood of trapped particle mode dominated transport. Low penetrating pellets containing up to 10 to 20 percent of the total plasma ions can produce fluctuations in density and temperature at the plasma edge, but the pressure profile and fusion alpha production remain almost constant

  6. Nitrogen Isotope Composition of Thermally Produced NOx from Various Fossil-Fuel Combustion Sources.

    Science.gov (United States)

    Walters, Wendell W; Tharp, Bruce D; Fang, Huan; Kozak, Brian J; Michalski, Greg

    2015-10-06

    The nitrogen stable isotope composition of NOx (δ(15)N-NOx) may be a useful indicator for NOx source partitioning, which would help constrain NOx source contributions in nitrogen deposition studies. However, there is large uncertainty in the δ(15)N-NOx values for anthropogenic sources other than on-road vehicles and coal-fired energy generating units. To this end, this study presents a broad analysis of δ(15)N-NOx from several fossil-fuel combustion sources that includes: airplanes, gasoline-powered vehicles not equipped with a three-way catalytic converter, lawn equipment, utility vehicles, urban buses, semitrucks, residential gas furnaces, and natural-gas-fired power plants. A relatively large range of δ(15)N-NOx values was measured from -28.1‰ to 8.5‰ for individual exhaust/flue samples that generally tended to be negative due to the kinetic isotope effect associated with thermal NOx production. A negative correlation between NOx concentrations and δ(15)N-NOx for fossil-fuel combustion sources equipped with selective catalytic reducers was observed, suggesting that the catalytic reduction of NOx increases δ(15)N-NOx values relative to the NOx produced through fossil-fuel combustion processes. Combining the δ(15)N-NOx measured in this study with previous published values, a δ(15)N-NOx regional and seasonal isoscape was constructed for the contiguous U.S., which demonstrates seasonal and regional importance of various NOx sources.

  7. Highly Zeolite-Loaded Polyvinyl Alcohol Composite Membranes for Alkaline Fuel-Cell Electrolytes

    Directory of Open Access Journals (Sweden)

    Po-Ya Hsu

    2018-01-01

    Full Text Available Having a secure and stable energy supply is a top priority for the global community. Fuel-cell technology is recognized as a promising electrical energy generation system for the twenty-first century. Polyvinyl alcohol/zeolitic imidazolate framework-8 (PVA/ZIF-8 composite membranes were successfully prepared in this work from direct ZIF-8 suspension solution (0–45.4 wt % and PVA mixing to prevent filler aggregation for direct methanol alkaline fuel cells (DMAFCs. The ZIF-8 fillers were chosen for the appropriate cavity size as a screening aid to allow water and suppress methanol transport. Increased ionic conductivities and suppressed methanol permeabilities were achieved for the PVA/40.5% ZIF-8 composites, compared to other samples. A high power density of 173.2 mW cm−2 was achieved using a KOH-doped PVA/40.5% ZIF-8 membrane in a DMAFC at 60 °C with 1–2 mg cm−2 catalyst loads. As the filler content was raised beyond 45.4 wt %, adverse effects resulted and the DMAFC performance (144.9 mW cm−2 was not improved further. Therefore, the optimal ZIF-8 content was approximately 40.5 wt % in the polymeric matrix. The specific power output was higher (58 mW mg−1 than most membranes reported in the literature (3–18 mW mg−1.

  8. Fabrication of carbon-polymer composite bipolar plates for polymer electrolyte membrane fuel cells by compression moulding

    International Nuclear Information System (INIS)

    Raza, M.A.; Ahmed, R.; Saleem, A.; Din, R.U.

    2009-01-01

    Fuel cells are considered as one of the most important technologies to address the future energy and environmental pollution problems. These are the most promising power sources for road transportation and portable devices. A fuel cell is an electrochemical device that converts chemical energy into electrical energy. A fuel cell stack consists of bipolar plates and membrane electrode assemblies (MEA). The bipolar plate is by weight, volume and cost one of the most significant components of a fuel cell stack. Major functions of bipolar plates are to separate oxidant and fuel gas, provide flow channels, conduct electricity and provide heat transfer. Bipolar plates can be made from various materials including graphite, metals, carbon / carbon and carbon/ polymer composites. Materials for carbon-polymer composites are relatively inexpensive, less corrosive, strong and channels can be formed by means of a moulding process. Carbon-polymer composites are of two type i.e; thermosetting and thermoplastic. For thermosetting composite a bulk molding compound (BMC) was prepared by adding graphite, vinyl ester resin, methyl ethyl ketone peroxide and cobalt naphthalate. The BMC was thoroughly mixed, poured into a die mould of a bipolar plate with channels and hot pressed at a specific temperature and pressure. A bipolar plate was formed according to the die mould. Design of the mould is also discussed. Conducting polymers were also added to BMC to increase the conductivity of bipolar plates. Particle size of the graphite has also a significant effect on the conductivity of the bipolar plates. Thermoplastic composites were also prepared using polypropylene and graphite.

  9. Recovery of protactinium from molten fluoride nuclear fuel compositions

    Science.gov (United States)

    Baes, C.F. Jr.; Bamberger, C.; Ross, R.G.

    1973-12-25

    A method is provided for separating protactinium from a molten fluonlde salt composition consisting essentially of at least one alkali and alkaline earth metal fluoride and at least one soluble fluoride of uranium or thorium which comprises oxidizing the protactinium in said composition to the + 5 oxidation state and contacting said composition with an oxide selected from the group consisting of an alkali metal oxide, an alkaline earth oxide, thorium oxide, and uranium oxide, and thereafter isolating the resultant insoluble protactinium oxide product from said composition. (Official Gazette)

  10. Fuel property effects on Navy aircraft fuel systems

    Science.gov (United States)

    Moses, C. A.

    1984-01-01

    Problems of ensuring compatibility of Navy aircraft with fuels that may be different than the fuels for which the equipment was designed and qualified are discussed. To avoid expensive requalification of all the engines and airframe fuel systems, methodologies to qualify future fuels by using bench-scale and component testing are being sought. Fuel blends with increasing JP5-type aromatic concentration were seen to produce less volume swell than an equivalent aromatic concentration in the reference fuel. Futhermore, blends with naphthenes, decalin, tetralin, and naphthalenes do not deviate significantly from the correlation line of aromatic blends, Similar results are found with tensile strenth and elongation. Other elastomers, sealants, and adhesives are also being tested.

  11. Sulfonated carbon black-based composite membranes for fuel cell

    Indian Academy of Sciences (India)

    Composite membranes were then prepared using S–C as fillers and sulfonated poly(ether ether ketone) (SPEEK) as polymer matrix with three different sulfonation degrees (DS = 60, 70 and 82%). Structure and properties of the composite membranes were characterized by FTIR, TGA, scanning electron microscopy, proton ...

  12. the effect of advanced fuel designs on fuel utilization

    International Nuclear Information System (INIS)

    Sarikaya, B.; Colak, U.; Tombakoglu, M.; Yilmazbayhan, A.

    1997-01-01

    Fuel management is one of the key topic in nuclear engineering. It is possible to increase fuel burnup and reactor lifetime by using advanced fuel management strategies. In order to increase the cycle lifetime, required amount of excess reactivity must be added to system. Burnable poisons can be used to compensate this excess reactivity. Usually gadolinium (Gd) is used as burnable poison. But the use of Gd presents some difficulties that have not been encountered with the use of boron

  13. Effect analysis of air introduced by pressurization on fuel rod performances

    International Nuclear Information System (INIS)

    Ren Qisen; Liu Tong; Sheng Guofu

    2012-01-01

    In the process of pressurization and seal welding, it is common practice to vacuumize before gas filling for the sake of preventing introducing air and other impurities, which would affect the gas composition inside of the fuel rod. However, vacuumization during pressurization is likely not being required sometimes in order to simplify the fabrication procedure. In the present work, based on the AFA3G fuel rod design with 2 MPa of filling gas, analyses on fuel rod performances were carried out under the condition of pressurization with and without vacuumization, respectively. Furthermore, the effect on hydrogen content in fuel rod was preliminarily discussed. Results indicate that the impacts of air composition introduced by pressurization on fuel rod thermal-mechanical performances, such as internal pressure and fuel center temperature, were extremely slight. The gap conductance varies to some extent as a result of the change of gas composition due to air introduced in fuel rod. The impact of humidity on water content in fuel rod is negligible at a low temperature of around 25℃. However, at higher temperature, it is essential to pay attention on the control of fabrication process, and prevent much moisture entering into the fuel rod and increasing the probability of hydriding failure. (authors)

  14. Effect of Alternative Fuels on SCR Chemistry

    OpenAIRE

    Faramarzi, Simin

    2012-01-01

    In the time line of world industrial age, the most important era begins in the late 18th century when the use of fossil fuels was growing intensively. This approach has continued and developed up to the 20th century. Besides, this trend has had side effects like polluting environment. Air pollution is one of the critical issues nowadays that stems from using hydrocarbon fuels. One type of the problematic compounds in polluting air is nitrogen oxides that can be produced in combustion process ...

  15. Optimisation of composite metallic fuel for minor actinide transmutation in an accelerator-driven system

    Science.gov (United States)

    Uyttenhove, W.; Sobolev, V.; Maschek, W.

    2011-09-01

    A potential option for neutralization of minor actinides (MA) accumulated in spent nuclear fuel of light water reactors (LWRs) is their transmutation in dedicated accelerator-driven systems (ADS). A promising fuel candidate dedicated to MA transmutation is a CERMET composite with Mo metal matrix and (Pu, Np, Am, Cm)O 2-x fuel particles. Results of optimisation studies of the CERMET fuel targeting to increasing the MA transmutation efficiency of the EFIT (European Facility for Industrial Transmutation) core are presented. In the adopted strategy of MA burning the plutonium (Pu) balance of the core is minimized, allowing a reduction in the reactivity swing and the peak power form-factor deviation and an extension of the cycle duration. The MA/Pu ratio is used as a variable for the fuel optimisation studies. The efficiency of MA transmutation is close to the foreseen theoretical value of 42 kg TW -1 h -1 when level of Pu in the actinide mixture is about 40 wt.%. The obtained results are compared with the reference case of the EFIT core loaded with the composite CERCER fuel, where fuel particles are incorporated in a ceramic magnesia matrix. The results of this study offer additional information for the EFIT fuel selection.

  16. Optimisation of composite metallic fuel for minor actinide transmutation in an accelerator-driven system

    International Nuclear Information System (INIS)

    Uyttenhove, W.; Sobolev, V.; Maschek, W.

    2011-01-01

    A potential option for neutralization of minor actinides (MA) accumulated in spent nuclear fuel of light water reactors (LWRs) is their transmutation in dedicated accelerator-driven systems (ADS). A promising fuel candidate dedicated to MA transmutation is a CERMET composite with Mo metal matrix and (Pu, Np, Am, Cm)O 2-x fuel particles. Results of optimisation studies of the CERMET fuel targeting to increasing the MA transmutation efficiency of the EFIT (European Facility for Industrial Transmutation) core are presented. In the adopted strategy of MA burning the plutonium (Pu) balance of the core is minimized, allowing a reduction in the reactivity swing and the peak power form-factor deviation and an extension of the cycle duration. The MA/Pu ratio is used as a variable for the fuel optimisation studies. The efficiency of MA transmutation is close to the foreseen theoretical value of 42 kg TW -1 h -1 when level of Pu in the actinide mixture is about 40 wt.%. The obtained results are compared with the reference case of the EFIT core loaded with the composite CERCER fuel, where fuel particles are incorporated in a ceramic magnesia matrix. The results of this study offer additional information for the EFIT fuel selection.

  17. THE DETERMINATION OF VOLATILE COMPOSITION OF SOLID FUELS BY CHROMATOGRAPHY

    OpenAIRE

    BICA Marin; SOFRONIE Sorin; CERNAIANU Corina Dana

    2014-01-01

    The volatile materials released during the heating of solid fuels ignite at relatively low temperatures releasing heat function of their quantity and quality. This heat raises the temperature of the solid residue creating the conditions for his ignition and burning. In the case of burning of the pulverized coal the phenomenon of production, ignition and burning of volatile materials are studied in different articles.

  18. Fuel composition impact on heavy duty diesel engine combustion & emissions

    NARCIS (Netherlands)

    Frijters, P.J.M.

    2012-01-01

    The Heavy Duty Diesel or compression ignition (CI) engine plays an important economical role in societies all over the world. Although it is a fuel efficient internal combustion engine design, CI engine emissions are an important contributor to global pollution. To further reduce engine emissions

  19. Parametric Evaluation of SiC/SiC Composite Cladding with UO2 Fuel for LWR Applications: Fuel Rod Interactions and Impact of Nonuniform Power Profile in Fuel Rod

    Science.gov (United States)

    Singh, G.; Sweet, R.; Brown, N. R.; Wirth, B. D.; Katoh, Y.; Terrani, K.

    2018-02-01

    SiC/SiC composites are candidates for accident tolerant fuel cladding in light water reactors. In the extreme nuclear reactor environment, SiC-based fuel cladding will be exposed to neutron damage, significant heat flux, and a corrosive environment. To ensure reliable and safe operation of accident tolerant fuel cladding concepts such as SiC-based materials, it is important to assess thermo-mechanical performance under in-reactor conditions including irradiation and realistic temperature distributions. The effect of non-uniform dimensional changes caused by neutron irradiation with spatially varying temperatures, along with the closing of the fuel-cladding gap, on the stress development in the cladding over the course of irradiation were evaluated. The effect of non-uniform circumferential power profile in the fuel rod on the mechanical performance of the cladding is also evaluated. These analyses have been performed using the BISON fuel performance modeling code and the commercial finite element analysis code Abaqus. A constitutive model is constructed and solved numerically to predict the stress distribution in the cladding under normal operating conditions. The dependence of dimensions and thermophysical properties on irradiation dose and temperature has been incorporated into the models. Initial scoping results from parametric analyses provide time varying stress distributions in the cladding as well as the interaction of fuel rod with the cladding under different conditions of initial fuel rod-cladding gap and linear heat rate. It is found that a non-uniform circumferential power profile in the fuel rod may cause significant lateral bowing in the cladding, and motivates further analysis and evaluation.

  20. Sulfonated carbon black-based composite membranes for fuel cell ...

    Indian Academy of Sciences (India)

    the properties of the composite membranes with the addition of S–C particles at high concentrations due to the .... metry and nuclear magnetic resonance that assured no sol- ... BT-512 BekkTech membrane test system at varying relative.

  1. Incorporation of Collision Probability Method in STREAM to Consider Non-uniform Material Composition in Fuel Subregions

    International Nuclear Information System (INIS)

    Choi, Sooyoung; Choe, Jiwon; Lee, Deokjung

    2016-01-01

    STREAM uses a pin-based slowing-down method (PSM) which solves pointwise energy slowing-down problems with sub-divided fuel pellet, and shows a great performance in calculating effective cross-section (XS). Various issues in the conventional resonance treatment methods (i.e., approximations on resonance scattering source, resonance interference effect, and intrapellet self-shielding effect) were successfully resolved by PSM. PSM assumes that a fuel rod has a uniform material composition and temperature even though PSM calculates spatially dependent effective XSs of fuel subregions. When the depletion calculation or thermal/hydraulic (T/H) coupling are performed with sub-divided material meshes, each subregion has its own material condition depending on position. It was reported that the treatment of distributed temperature is important to calculate an accurate fuel temperature coefficient (FTC). In order to avoid the approximation in PSM, the collision probability method (CPM) has been incorporated as a calculation option. The resonance treatment method, PSM, used in the transport code STREAM has been enhanced to accurately consider a non-uniform material condition. The method incorporates CPM in computing collision probability of isolated fuel pin. From numerical tests with pin-cell problems, STREAM with the method showed very accurate multiplication factor and FTC results less than 83 pcm and 1.43 % differences from the references, respectively. The original PSM showed larger differences than the proposed method but still has a high accuracy

  2. Incorporation of Collision Probability Method in STREAM to Consider Non-uniform Material Composition in Fuel Subregions

    Energy Technology Data Exchange (ETDEWEB)

    Choi, Sooyoung; Choe, Jiwon; Lee, Deokjung [UNIST, Ulsan (Korea, Republic of)

    2016-10-15

    STREAM uses a pin-based slowing-down method (PSM) which solves pointwise energy slowing-down problems with sub-divided fuel pellet, and shows a great performance in calculating effective cross-section (XS). Various issues in the conventional resonance treatment methods (i.e., approximations on resonance scattering source, resonance interference effect, and intrapellet self-shielding effect) were successfully resolved by PSM. PSM assumes that a fuel rod has a uniform material composition and temperature even though PSM calculates spatially dependent effective XSs of fuel subregions. When the depletion calculation or thermal/hydraulic (T/H) coupling are performed with sub-divided material meshes, each subregion has its own material condition depending on position. It was reported that the treatment of distributed temperature is important to calculate an accurate fuel temperature coefficient (FTC). In order to avoid the approximation in PSM, the collision probability method (CPM) has been incorporated as a calculation option. The resonance treatment method, PSM, used in the transport code STREAM has been enhanced to accurately consider a non-uniform material condition. The method incorporates CPM in computing collision probability of isolated fuel pin. From numerical tests with pin-cell problems, STREAM with the method showed very accurate multiplication factor and FTC results less than 83 pcm and 1.43 % differences from the references, respectively. The original PSM showed larger differences than the proposed method but still has a high accuracy.

  3. Fuel Composition and Performance Analysis of Endothermically Heated Fuels for Pulse Detonation Engines

    Science.gov (United States)

    2009-03-01

    exchanger was constructed on an inner 2 in Inconel 625 schedule 10 pipe and an outer 2 ½ in Inconel 600 schedule 40 pipe 0.91 m (36 in) in length. The...switched to positions two and three for the remainder of the experiments. 46 The detonation tubes are fabricated from inconel and include heat...and four. Fuel Heating System 47 The fuel heating system centers around two pairs of inconel heat exchangers. The first pair was developed in

  4. Evaluation of the Optimum Composition of Low-Temperature Fuel Cell Electrocatalysts for Methanol Oxidation by Combinatorial Screening.

    Science.gov (United States)

    Antolini, Ermete

    2017-02-13

    Combinatorial chemistry and high-throughput screening represent an innovative and rapid tool to prepare and evaluate a large number of new materials, saving time and expense for research and development. Considering that the activity and selectivity of catalysts depend on complex kinetic phenomena, making their development largely empirical in practice, they are prime candidates for combinatorial discovery and optimization. This review presents an overview of recent results of combinatorial screening of low-temperature fuel cell electrocatalysts for methanol oxidation. Optimum catalyst compositions obtained by combinatorial screening were compared with those of bulk catalysts, and the effect of the library geometry on the screening of catalyst composition is highlighted.

  5. Composite Bipolar Plate for Unitized Fuel Cell/Electrolyzer Systems

    Science.gov (United States)

    Mittelsteadt, Cortney K.; Braff, William

    2009-01-01

    In a substantial improvement over present alkaline systems, an advanced hybrid bipolar plate for a unitized fuel cell/electrolyzer has been developed. This design, which operates on pure feed streams (H2/O2 and water, respectively) consists of a porous metallic foil filled with a polymer that has very high water transport properties. Combined with a second metallic plate, the pore-filled metallic plates form a bipolar plate with an empty cavity in the center.

  6. Modelling the effects of transport policy levers on fuel efficiency and national fuel consumption

    International Nuclear Information System (INIS)

    Kirby, H.R.; Hutton, B.; McQuaid, R.W.; Napier Univ., Edinburgh; Raeside, R.; Napier Univ., Edinburgh; Zhang, Xiayoan; Napier Univ., Edinburgh

    2000-01-01

    The paper provides an overview of the main features of a Vehicle Market Model (VMM) which estimates changes to vehicle stock/kilometrage, fuel consumed and CO 2 emitted. It is disaggregated into four basic vehicle types. The model includes: the trends in fuel consumption of new cars, including the role of fuel price: a sub-model to estimate the fuel consumption of vehicles on roads characterised by user-defined driving cycle regimes; procedures that reflect distribution of traffic across different area/road types; and the ability to vary the speed (or driving cycle) from one year to another, or as a result of traffic growth. The most significant variable influencing fuel consumption of vehicles was consumption in the previous year, followed by dummy variables related to engine size. the time trend (a proxy for technological improvements), and then fuel price. Indeed the effect of fuel price on car fuel efficiency was observed to be insignificant (at the 95% level) in two of the three versions of the model, and the size of fuel price term was also the smallest. This suggests that the effectiveness of using fuel prices as a direct policy tool to reduce fuel consumption may he limited. Fuel prices may have significant indirect impacts (such as influencing people to purchase more fuel efficient cars and vehicle manufacturers to invest in developing fuel efficient technology) as may other factors such as the threat of legislation. (Author)

  7. Effect of pilot fuel quantity on the performance of a dual fuel engine

    Energy Technology Data Exchange (ETDEWEB)

    Abd Alla, G.H.; Soliman, H.A.; Badr, O.A.; Abd Rabbo, M.F. [Zagazig University, Cairo (Egypt). Shoubra Faculty of Engineering

    2000-04-01

    It is well known that the operation of dual fuel engines at lower loads suffers from lower thermal efficiency and higher unburned percentages of fuel. To rectify this problem, tests have been conducted on a special single cylinder compression ignition research engine (Ricardo E6) to investigate the effect of pilot fuel quantity on the performance of an indirect injection diesel engine fuelled with gaseous fuel. Diesel fuel was used as the pilot fuel and methane or propane was used as the main fuel which was inducted into the intake manifold to mix with the intake air. Through experimental investigations, it is shown that, the low efficiency and excess emissions at light loads can be improved significantly by increasing the amount of pilot fuel, while increasing the amount of pilot fuel at high loads led to early knocking. (author)

  8. α-MnO2 Nanowires/Graphene Composites with High Electrocatalytic Activity for Mg-Air Fuel Cell

    International Nuclear Information System (INIS)

    Jiang, Min; He, Hao; Huang, Chen; Liu, Bo; Yi, Wen-Jun; Chao, Zi-Sheng

    2016-01-01

    Highlights: • α-MnO 2 NWs/graphene was synthesized and studied in Mg-air fuel cell. • The performance of α-MnO 2 NWs/graphene is close to the Pt/C. • The ORR mechanism involves a one-step, quasi-4-electron pathway. • A large area (5 cm*5 cm) cathode was prepared and tested in a full cell. - Abstract: This paper reports the preparation of α-MnO 2 NWs/graphene composites as the cathode catalyst for magnesium-air fuel cell and its excellent electrochemistry performance. The composites are synthesized by self-assembly of α-MnO 2 nan α-MnO 2 NWs/graphene was synthesized and studied in Mg-air fuel cell. α-MnO 2 NWs/graphene was synthesized and studied in Mg-air fuel cell. owires (NWs) on the surface of graphene via a simple hydrothermal method. The α-MnO 2 NWs/graphene composites showed a higher electrochemical activity than the commercial MnO 2 . The oxygen reduction peak of the α-MnO 2 NWs/graphene composites catalyst is tested in a 0.1 M KOH solution at −0.252 V, which is more positive than the commercial MnO 2 (−0.287 V). The ORR limit current density for 28% α-MnO2 NWs/graphene composite is approximately 2.74 mA/cm 2 , which is similar to that of the 20% Pt/C(2.79 mA/cm 2 ) in the same conditions. Based on the Koutecky–Levich plot, the ORR mechanism of the composite involves a one-step, quasi-4-electron pathway. In addition, magnesium-air fuel cell with α-MnO 2 NWs/graphene as catalyst possesses higher current density (140 mA/cm 2 ) and power density (96 mW/cm 2 ) compared to the commercial MnO 2 . This study proves that the cost-effective α-MnO 2 NWs/graphene with higher power generation ability make it possible for the substitute of the noble metals catalyst in the Mg-air fuel cell.

  9. SFCOMPO: A new database of isotopic compositions of spent nuclear fuel

    International Nuclear Information System (INIS)

    Michel-Sendis, Franco; Gauld, Ian

    2014-01-01

    The numerous applications of nuclear fuel depletion simulations impact all areas related to nuclear safety. They are at the basis of, inter alia, spent fuel criticality safety analyses, reactor physics calculations, burn-up credit methodologies, decay heat thermal analyses, radiation shielding, reprocessing, waste management, deep geological repository safety studies and safeguards. Experimentally determined nuclide compositions of well-characterised spent nuclear fuel (SNF) samples are used to validate the accuracy of depletion code predictions for a given burn-up. At the same time, the measured nuclide composition of the sample is used to determine the burn-up of the fuel. It is therefore essential to have a reliable and well-qualified database of measured nuclide concentrations and relevant reactor operational data that can be used as experimental benchmark data for depletion codes and associated nuclear data. The Spent Fuel Isotopic Composition Database (SFCOMPO) has been hosted by the NEA since 2001. In 2012, a collaborative effort led by the NEA Data Bank and Oak Ridge National Laboratory (ORNL) in the United States, under the guidance of the NEA Expert Group on Assay Data of Spent Nuclear Fuel (EGADSNF) of the Working Party on Nuclear Criticality Safety (WPNCS), has resulted in the creation of an enhanced relational database structure and a significant expansion of the SFCOMPO database, which now contains experimental assay data for a wider selection of international reactor designs. The new database was released online in 2014. This new SFCOMPO database aims to provide access to open experimental SNF assay data to ensure their preservation and to facilitate their qualification as evaluated assay data suitable for the validation of methodologies used to predict the composition of irradiated nuclear fuel. Having a centralised, internationally reviewed database that makes these data openly available for a large selection of international reactor designs is of

  10. Improvements to SFCOMPO - a database on isotopic composition of spent nuclear fuel

    International Nuclear Information System (INIS)

    Suyama, Kenya; Nouri, Ali; Mochizuki, Hiroki; Nomura, Yasushi

    2003-01-01

    Isotopic composition is one of the most relevant data to be used in the calculation of burnup of irradiated nuclear fuel. Since autumn 2002, the Organisation for Economic Co-operation and Development/Nuclear Energy Agency (OECD/NEA) has operated a database of isotopic composition - SFCOMPO, initially developed in Japan Atomic Energy Research Institute. This paper describes the latest version of SFCOMPO and the future development plan in OECD/NEA. (author)

  11. Computer Simulations of Composite Electrodes in Solid-Oxide Fuel-Cells

    Energy Technology Data Exchange (ETDEWEB)

    Sunde, Svein

    1999-07-01

    Fuel cells are devices for converting the combined chemical (free) energy of fuels and oxygen (air) directly to electrical energy without relying on the dynamic action of steam heated by reacting fuel-oxygen mixtures, like in steam turbines, or of the reacting gas mixtures themselves, like in gas turbines. The basic rationale for fuel cells is their high efficiencies as compared to indirect-conversion methods. Fuel cells are currently being considered for a number of applications, among them de-centralised power supply. Fuel cells come in five basic types and are usually classified according to the type of electrolyte used, which in turn to a significant degree limits the options for anode and cathode materials. The solid-oxide fuel-cell (SOFC) , with which this thesis is concerned, is thus named after its oxide electrolyte, typically the oxide-ion conducting material yttria-stabilised zirconia (YSZ). While the cathode of an SOFC is often uniform in chemical composition (or at least intended to be), various problems of delamination, cracking etc. associated with the use of metallic anode electrocatalysts led to the development of composite SOFC anodes. Porous anodes consisting of Ni and YSZ particles in roughly 50/50 wt-% mixtures are now almost standard with any SOFC-development programme. The designer of composite SOFC electrodes is faced with at least three, interrelated questions: (1) What will be the optimum microstructure and composition of the composite electrode? (2) If the structure changes during operation, as is often observed, what will be the consequences for the internal losses in the cell? (3) How do we interpret electrochemical and conductivity measurements with regard to structure and composition? It is the primary purpose of this thesis to provide a framework for modelling the electrochemical and transport properties of composite electrodes for SOFC, and to arrive at some new insights that cannot be offered by experiment alone. Emphasis is put on

  12. Experimental Measurement and Numerical Modeling of the Effective Thermal Conductivity of TRISO Fuel Compacts

    International Nuclear Information System (INIS)

    Folsom, Charles

    2015-01-01

    Accurate modeling capability of thermal conductivity of tristructural-isotropic (TRISO) fuel compacts is important to fuel performance modeling and safety of Generation IV reactors. To date, the effective thermal conductivity (ETC) of tristructural-isotropic (TRISO) fuel compacts has not been measured directly. The composite fuel is a complicated structure comprised of layered particles in a graphite matrix. In this work, finite element modeling is used to validate an analytic ETC model for application to the composite fuel material for particle-volume fractions up to 40%. The effect of each individual layer of a TRISO particle is analyzed showing that the overall ETC of the compact is most sensitive to the outer layer constituent. In conjunction with the modeling results, the thermal conductivity of matrix-graphite compacts and the ETC of surrogate TRISO fuel compacts have been successfully measured using a previously developed measurement system. The ETC of the surrogate fuel compacts varies between 50-30 W m -1 K -1 over a temperature range of 50-600°C. As a result of the numerical modeling and experimental measurements of the fuel compacts, a new model and approach for analyzing the effect of compact constituent materials on ETC is proposed that can estimate the fuel compact ETC with approximately 15-20% more accuracy than the old method. Using the ETC model with measured thermal conductivity of the graphite matrix-only material indicate that, in the composite form, the matrix material has a much greater thermal conductivity, which is attributed to the high anisotropy of graphite thermal conductivity. Therefore, simpler measurements of individual TRISO compact constituents combined with an analytic ETC model, will not provide accurate predictions of overall ETC of the compacts emphasizing the need for measurements of composite, surrogate compacts.

  13. Effect of Pu-rich agglomerate in MOX fuel on a lattice calculation

    International Nuclear Information System (INIS)

    Kawashima, Katsuyuki; Yamamoto, Toru; Namekawa, Masakazu

    2007-01-01

    The effect of Pu-rich agglomerates in U-Pu mixed oxide (MOX) fuel on a lattice calculation has been demonstrated. The Pu-rich agglomerate parameters are defined based on the measurement data of MIMAS-MOX and the focus is on the highly enriched MOX fuel in accordance with increased burnup resulting in a higher volume fraction of the Pu-rich agglomerates. The lattice calculations with a heterogeneous fuel model and a homogeneous fuel model are performed simulating the PWR 17x17 fuel assembly. The heterogeneous model individually treats the Pu-rich agglomerate and U-Pu matrix, whereas the homogeneous model homogenizes the compositions within the fuel pellet. A continuous-energy Monte Carlo burnup code, MVP-BURN, is used for burnup calculations up to 70 GWd/t. A statistical geometry model is applied in modeling a large number of Pu-rich agglomerates assuming that they are distributed randomly within the MOX fuel pellet. The calculated nuclear characteristics include k-inf, Pu isotopic compositions, power density and burnup of the Pu-rich agglomerates, as well as the pellet-averaged Pu compositions as a function of burnup. It is shown that the effect of Pu-rich agglomerates on the lattice calculation is negligibly small. (author)

  14. Fast reactor core design studies to cope with TRU fuel composition changes in the LWR-to-FBR transition period

    International Nuclear Information System (INIS)

    Kawashima, Katsuyuki; Maruyama, Shuhei; Ohki, Shigeo; Mizuno, Tomoyasu

    2009-01-01

    As part of the Fast Reactor Cycle Technology Development Project (FaCT Project), sodium-cooled fast reactor core design efforts have been made to cope with the TRU fuel composition changes expected during LWR-to-FBR transition period, in which a various kind of TRU fuel compositions are available depending on the characteristics of the LWR spent fuels and a way of recycling them. A 750 MWe mixed-oxide fuel core is firstly defined as a FaCT medium-size reference core and its neutronics characteristics are determined. The core is a high internal conversion type and has an average burnup of 150 GWD/T. The reference TRU fuel composition is assumed to come from the FBR equilibrium state. Compared to the LWR-to-FBR transition period, the TRU fuels in the FBR equilibrium period are multi-recycled through fast reactors and have a different composition. An available TRU fuel composition is determined by fast reactor spent fuel multi-recycling scenarios. Then the FaCT core corresponding to the TRU fuel with different compositions is set according to the TRU fuel composition changes in LWR-to-FBR transition period, and the key core neutronics characteristics are assessed. It is shown that among the core neutronics characteristics, the burnup reactivity and the safety parameters such as sodium void reactivity and Doppler coefficient are significantly influenced by the TRU fuel composition changes. As a result, a general characteristic in the FaCT core design to cope with TRU fuel composition changes is grasped and the design envelopes are identified in terms of the burnup reactivity and the safety parameters. (author)

  15. Determination of optimal wet ethanol composition as a fuel in spark ignition engine

    International Nuclear Information System (INIS)

    Fagundez, J.L.S.; Sari, R.L.; Mayer, F.D.; Martins, M.E.S.; Salau, N.P.G.

    2017-01-01

    Highlights: • Batch distillation to produce HEF and fuel blends of wet ethanol. • Conversion efficiency of a SI engine operating with HEF and wet ethanol. • NEF as a new metric to calculate the energy efficiency of HEF and wet ethanol. • Optimal wet ethanol composition as a fuel in SI engine based on NEF. - Abstract: Studies are unanimous that the greatest fraction of the energy necessary to produce hydrous ethanol fuel (HEF), i.e. above 95%v/v of ethanol in water, is spent on water removal (distillation). Previous works have assessed the energy efficiency of HEF; but few, if any, have done the same for wet ethanol fuel (sub-azeotropic hydrous ethanol). Hence, a new metric called net energy factor (NEF) is proposed to calculate the energy efficiency of wet ethanol and HEF. NEF calculates the ratio of Lower Heating Value (LHV) derived from ethanol fuel, total energy out, to energy used to obtain ethanol fuel as distillate, total energy in. Distillation tests were performed batchwise to obtain as distillate HEF and four different fuel blends of wet ethanol with a range from 60%v/v to 90%v/v of ethanol and the amount of energy spent to distillate each ethanol fuel calculated. The efficiency parameters of a SI engine operating with the produced ethanol fuels was tested to calculate their respective conversion efficiency. The results of net energy factors show a clear advantage of wet ethanol fuels over HEF; the optimal efficiency was wet ethanol fuel with 70%v/v of ethanol.

  16. Nanostructured electrocatalyst for fuel cells : silica templated synthesis of Pt/C composites.

    Energy Technology Data Exchange (ETDEWEB)

    Stechel, Ellen Beth; Switzer, Elise E.; Fujimoto, Cy H.; Atanassov, Plamen Borissov; Cornelius, Christopher James; Hibbs, Michael R.

    2007-09-01

    Platinum-based electrocatalysts are currently required for state-of-the-art fuel cells and represent a significant portion of the overall fuel cell cost. If fuel cell technology is to become competitive with other energy conversion technologies, improve the utilization of precious metal catalysts is essential. A primary focus of this work is on creating enhanced nanostructured materials which improve precious-metal utilization. The goal is to engineer superior electrocatalytic materials through the synthesis, development and investigation of novel templated open frame structures synthesized in an aerosol-based approach. Bulk templating methods for both Pt/C and Pt-Ru composites are evaluated in this study and are found to be limited due to the fact that the nanostructure is not maintained throughout the entire sample. Therefore, an accurate examination of structural effects was previously impossible. An aerosol-based templating method of synthesizing nanostructured Pt-Ru electrocatalysts has been developed wherein the effects of structure can be related to electrocatalytic performance. The aerosol-based templating method developed in this work is extremely versatile as it can be conveniently modified to synthesize alternative materials for other systems. The synthesis method was able to be extended to nanostructured Pt-Sn for ethanol oxidation in alkaline media. Nanostructured Pt-Sn electrocatalysts were evaluated in a unique approach tailored to electrocatalytic studies in alkaline media. At low temperatures, nanostructured Pt-Sn electrocatalysts were found to have significantly higher ethanol oxidation activity than a comparable nanostructured Pt catalyst. At higher temperatures, the oxygen-containing species contribution likely provided by Sn is insignificant due to a more oxidized Pt surface. The importance of the surface coverage of oxygen-containing species in the reaction mechanism is established in these studies. The investigations in this work present

  17. Laminated exfoliated graphite composite-metal compositions for fuel cell flow field plate or bipolar plate applications

    Science.gov (United States)

    Zhamu, Aruna; Shi, Jinjun; Guo, Jiusheng; Jang, Bor Z

    2014-05-20

    An electrically conductive laminate composition for fuel cell flow field plate or bipolar plate applications. The laminate composition comprises at least a thin metal sheet having two opposed exterior surfaces and a first exfoliated graphite composite sheet bonded to the first of the two exterior surfaces of the metal sheet wherein the exfoliated graphite composite sheet comprises: (a) expanded or exfoliated graphite and (b) a binder or matrix material to bond the expanded graphite for forming a cohered sheet, wherein the binder or matrix material is between 3% and 60% by weight based on the total weight of the first exfoliated graphite composite sheet. Preferably, the first exfoliated graphite composite sheet further comprises particles of non-expandable graphite or carbon in the amount of between 3% and 60% by weight based on the total weight of the non-expandable particles and the expanded graphite. Further preferably, the laminate comprises a second exfoliated graphite composite sheet bonded to the second surface of the metal sheet to form a three-layer laminate. Surface flow channels and other desired geometric features can be built onto the exterior surfaces of the laminate to form a flow field plate or bipolar plate. The resulting laminate has an exceptionally high thickness-direction conductivity and excellent resistance to gas permeation.

  18. Polybenzimidazole and sulfonated polyhedral oligosilsesquioxane composite membranes for high temperature polymer electrolyte membrane fuel cells

    DEFF Research Database (Denmark)

    Aili, David; Allward, Todd; Alfaro, Silvia Martinez

    2014-01-01

    Composite membranes based on poly(2,2′(m-phenylene)-5,5́bibenzimidazole) (PBI) and sulfonated polyhedral oligosilsesquioxane (S-POSS) with S-POSS contents of 5 and 10wt.% were prepared by solution casting as base materials for high temperature polymer electrolyte membrane fuel cells. With membranes...

  19. Impact of burnable absorber Gd on nuclide composition for VVER-440 fuel (Gd-2)

    International Nuclear Information System (INIS)

    Zajac, R.; Chrapciak, V.

    2010-01-01

    The latest version of Russian fuel VVER-440 includes burnable absorber in 6 pins. In this article is impact of burnable absorber on nuclide composition and criticality analyzed. In part 1 was analyzed whole burnup interval 0-50 MWd/kgU. In present part 2 are detailed analysis only for first cycle (burnup 0-10 MWd/kgU). (Authors)

  20. Radionuclide compositions of spent fuel and high level waste from commercial nuclear reactors

    International Nuclear Information System (INIS)

    Goodill, D.R.; Tymons, B.J.

    1984-10-01

    This report provides information on radionuclide compositions of spent fuel and high level waste produced during reprocessing. The reactor types considered are Magnox, AGR, PWR and CFR. The activities of the radionuclides are calculated using the FISPIN code. The results are presented in a form suitable for radioactive waste management calculations. (author)

  1. Method of fabricating zirconium metal for use in composite type fuel cans

    International Nuclear Information System (INIS)

    Imahashi, Hiromichi; Inagaki, Masatoshi; Akabori, Kimihiko; Tada, Naofumi; Yasuda, Tetsuro.

    1985-01-01

    Purpose: To mass produce zirconium metal for fuel cans with less radiation hardening. Method: Zirconium sponges as raw material are inserted in a hearth mold and a procedure of melting the zirconium sponges portionwise by using a melting furnace having electron beams as a heat source while moving the hearth is repeated at least for once. Then, the rod-like ingot after melting is melted again in a vacuum or inert gas atmosphere into an ingot of a low oxygen density capable of fabrication. A composite fuel can billet is formed by using the thus obtained zirconium ingot and a zircalloy, and a predetermined composite type fuel can is manufactured by way of hot extrusion and pipe drawing fabrication. The raw material usable herein is zirconium sponge with an oxygen density of 400 ppm or higher and the content of impurity other than oxygen is between 1000 - 5000 ppm in total, or the molten material thereof. (Kamimura, M.)

  2. Effects of cooling time on a closed LWR fuel cycle

    International Nuclear Information System (INIS)

    Arnold, R. P.; Forsberg, C. W.; Shwageraus, E.

    2012-01-01

    In this study, the effects of cooling time prior to reprocessing spent LWR fuel has on the reactor physics characteristics of a PWR fully loaded with homogeneously mixed U-Pu or U-TRU oxide (MOX) fuel is examined. A reactor physics analysis was completed using the CASM04e code. A void reactivity feedback coefficient analysis was also completed for an infinite lattice of fresh fuel assemblies. Some useful conclusions can be made regarding the effect that cooling time prior to reprocessing spent LWR fuel has on a closed homogeneous MOX fuel cycle. The computational analysis shows that it is more neutronically efficient to reprocess cooled spent fuel into homogeneous MOX fuel rods earlier rather than later as the fissile fuel content decreases with time. Also, the number of spent fuel rods needed to fabricate one MOX fuel rod increases as cooling time increases. In the case of TRU MOX fuel, with time, there is an economic tradeoff between fuel handling difficulty and higher throughput of fuel to be reprocessed. The void coefficient analysis shows that the void coefficient becomes progressively more restrictive on fuel Pu content with increasing spent fuel cooling time before reprocessing. (authors)

  3. Production of ZrC Matrix for Use in Gas Fast Reactor Composite Fuels

    International Nuclear Information System (INIS)

    Vasudevamurthy, Gokul; Knight, Travis W.; Roberts, Elwyn; Adams, Thad

    2007-01-01

    Zirconium carbide is being considered as a candidate for inert matrix material in composite nuclear fuel for Gas fast reactors due to its favorable characteristics. ZrC can be produced by the direct reaction of pure zirconium and graphite powders. Such a reaction is exothermic in nature. The reaction is self sustaining once initial ignition has been achieved. The heat released during the reaction is high enough to complete the reaction and achieve partial sintering without any external pressure applied. External heat source is required to achieve ignition of the reactants and maintain the temperature close to the adiabatic temperature to achieve higher levels of sintering. External pressure is also a driving force for sintering. In the experiments described, cylindrical compacts of ZrC were produced by direct combustion reaction. External induction heating combined with varying amounts of external applied pressure was employed to achieve varying degrees of density/porosity. The effect of reactant particle size on the product characteristics was also studied. The samples were characterized for density/porosity, composition and microstructure. (authors)

  4. Analysis of burnup and isotopic compositions of BWR 9 x 9 UO2 fuel assemblies

    International Nuclear Information System (INIS)

    Suzuki, M.; Yamamoto, T.; Ando, Y.; Nakajima, T.

    2012-01-01

    In order to extend isotopic composition data focusing on fission product nuclides, measurements are progressing using facilities of JAEA for five samples taken from high burnup BWR 9 x 9 UO 2 fuel assemblies. Neutronics analysis with an infinite assembly model was applied to the preliminary measurement data using a continuous-energy Monte Carlo burnup calculation code MVP-BURN with nuclear libraries based on JENDL-3.3 and JENDL-4.0. The burnups of the samples were determined to be 28.0, 39.3, 56.6, 68.1, and 64.0 GWd/t by the Nd-148 method. They were compared with those calculated using node-average irradiation histories of power and in-channel void fractions which were taken from the plant data. The comparison results showed that the deviations of the calculated burnups from the measurements were -4 to 3%. It was confirmed that adopting the nuclear data library based on JENDL-4.0 reduced the deviations of the calculated isotopic compositions from the measurements for 238 Pu, 144 Nd, 145 Nd, 146 Nd, 148 Nd, 134 Cs, 154 Eu, 152 Sm, 154 Gd, and 157 Gd. On the other hand, the effect of the revision in the nuclear. data library on the neutronics analysis was not significant for major U and Pu isotopes. (authors)

  5. Performance enhancement of direct ethanol fuel cell using Nafion composites with high volume fraction of titania

    Science.gov (United States)

    Matos, B. R.; Isidoro, R. A.; Santiago, E. I.; Fonseca, F. C.

    2014-12-01

    The present study reports on the performance enhancement of direct ethanol fuel cell (DEFC) at 130 °C with Nafion-titania composite electrolytes prepared by sol-gel technique and containing high volume fractions of the ceramic phase. It is found that for high volume fractions of titania (>10 vol%) the ethanol uptake of composites is largely reduced while the proton conductivity at high-temperatures is weakly dependent on the titania content. Such tradeoff between alcohol uptake and conductivity resulted in a boost of DEFC performance at high temperatures using Nafion-titania composites with high fraction of the inorganic phase.

  6. Spent fuel composition database system on WWW. SFCOMPO on WWW Ver.2

    International Nuclear Information System (INIS)

    Mochizuki, Hiroki; Suyama, Kenya; Nomura, Yasushi; Okuno, Hiroshi

    2001-08-01

    'SFCOMPO on WWW Ver.2' is an advanced version of 'SFCOMPO on WWW (Spent Fuel Composition Database System on WWW' released in 1997. This new version has a function of database management by an introduced relational database software 'PostgreSQL' and has various searching methods. All of the data required for the calculation of isotopic composition is available from the web site of this system. This report describes the outline of this system and the searching method using Internet. In addition, the isotopic composition data and the reactor data of the 14 LWRs (7 PWR and 7 BWR) registered in this system are described. (author)

  7. Burn-up credit criticality safety benchmark phase VII - UO2 fuel: study of spent fuel compositions for long-term disposal

    International Nuclear Information System (INIS)

    2012-01-01

    After spent nuclear fuel (SNF) is discharged from a nuclear reactor, fuel composition and reactivity continue to vary as a function of time due to the decay of unstable nuclides. Accurate predictions of the concentrations of long-lived radionuclides in SNF, which represent a significant potential hazard to human beings and to the environment over a very long period, are particularly necessary for radiological dose assessments. This report assesses the ability of existing computer codes and associated nuclear data to predict isotopic compositions and their corresponding neutron multiplication factor (k eff ) values for pressurised-water-reactor (PWR) UO 2 fuel at 50 GWd/MTU burn-up in a generic spent fuel cask configuration. Fuel decay compositions and k eff values have been calculated for 30 post-irradiation time steps out to one million years

  8. Size distribution, chemical composition and oxidation reactivity of particulate matter from gasoline direct injection (GDI) engine fueled with ethanol-gasoline fuel

    International Nuclear Information System (INIS)

    Luo, Yueqi; Zhu, Lei; Fang, Junhua; Zhuang, Zhuyue; Guan, Chun; Xia, Chen; Xie, Xiaomin; Huang, Zhen

    2015-01-01

    Ethanol-gasoline blended fuels have been widely applied in markets recently, as ethanol reduces life-cycle greenhouse gas emissions and improves anti-knock performance. However, its effects on particulate matter (PM) emissions from gasoline direct injection (GDI) engine still need further investigation. In this study, the effects of ethanol-gasoline blended fuels on particle size distributions, number concentrations, chemical composition and soot oxidation activity of GDI engine were investigated. It was found that ethanol-gasoline blended fuels increased the particle number concentration in low-load operating conditions. In higher load conditions, the ethanol-gasoline was effective for reducing the particle number concentration, indicating that the chemical benefits of ethanol become dominant, which could reduce soot precursors such as large n-alkanes and aromatics in gasoline. The volatile organic mass fraction in ethanol-gasoline particulates matter was higher than that in gasoline particulate matter because ethanol reduced the amount of soot precursors during combustion and thereby reduced the elemental carbon proportions in PM. Ethanol addition also increased the proportion of small particles, which confirmed the effects of ethanol on organic composition. Ethanol-gasoline reduced the concentrations of most PAH species, except those with small aromatic rings, e.g., naphthalene. Soot from ethanol-gasoline has lower activation energy of oxidation than that from gasoline. The results in this study indicate that ethanol-gasoline has positive effects on PM emissions control, as the soot oxidation activity is improved and the particle number concentrations are reduced at moderate and high engine loads. - Highlights: • Ethanol-gasoline reduces elemental carbon in PM. • Ethanol-gasoline increases volatile organic fraction in PM. • Soot generated from ethanol-gasoline has higher oxidation activity.

  9. Some implications of batch average burnup calculations on predicted spent fuel compositions

    International Nuclear Information System (INIS)

    Alexander, C.W.; Croff, A.G.

    1984-01-01

    The accuracy of using batch-averaged burnups to determine spent fuel characteristics (such as isotopic composition, activity, etc.) was examined for a typical pressurized-water reactor (PWR) fuel discharge batch by comparing characteristics computed by (a) performing a single depletion calculation using the average burnup of the spent fuel and (b) performing separate depletion calculations based on the relative amounts of spent fuel in each of twelve burnup ranges and summing the results. The computations were done using ORIGEN 2. Procedure (b) showed a significant shift toward a greater quantity of the heavier transuranics, which derive from multiple neutron captures, and a corresponding decrease in the amounts of lower transuranics. Those characteristics which derive primarily from fission products, such as total radioactivity and total thermal power, are essentially identical for the two procedures. Those characteristics that derive primarily from the heavier transuranics, such as spontaneous fission neutrons, are underestimated by procedure (a)

  10. Composite polymer membranes for proton exchange membrane fuel cells operating at elevated temperatures and reduced humidities

    Science.gov (United States)

    Zhang, Tao

    Proton Exchange Membrane Fuel Cells (PEMFCs) are the leading candidate in the fuel cell technology due to the high power density, solid electrolyte, and low operational temperature. However, PEMFCs operating in the normal temperature range (60-80°C) face problems including poor carbon monoxide tolerance and heat rejection. The poisoning effect can be significantly relieved by operating the fuel cell at elevated temperature, which also improves the heat rejection and electrochemical kinetics. Low relative humidity (RH) operation is also desirable to simplify the reactant humidification system. However, at elevated temperatures, reduced RH PEMFC performance is seriously impaired due to irreversible water loss from presently employed state-of-the-art polymer membrane, Nafion. This thesis focuses on developing polymer electrolyte membranes with high water retention ability for operation in elevated temperature (110-150°C), reduced humidity (˜50%RH) PEMFCs. One approach is to alter Nafion by adding inorganic particles such as TiO2, SiO2, Zr(HPO 4)2, etc. While the presence of these materials in Nafion has proven beneficial, a reduction or no improvement in the PEMFC performance of Nafion/TiO2 and Nafion/Zr(HPO4)2 membranes is observed with reduced particle sizes or increased particle loadings in Nafion. It is concluded that the PEMFC performance enhancement associated with addition of these inorganic particles was not due to the particle hydrophilicity. Rather, the particle, partially located in the hydrophobic region of the membrane, benefits the cell performance by altering the membrane structure. Water transport properties of some Nafion composite membranes were investigated by NMR methods including pulsed field gradient spin echo diffusion, spin-lattice relaxation, and spectral measurements. Compared to unmodified Nafion, composite membranes materials exhibit longer longitudinal relaxation time constant T1. In addition to the Nafion material, sulfonated styrene

  11. Analysis of the optimal fuel composition for the Indonesian experimental power reactor

    Energy Technology Data Exchange (ETDEWEB)

    Liem, Peng Hong [Nippon Advanced Information Service (NAIS Co., Inc.), Ibaraki (Japan); Sembiring, Tagor Malem [National Nuclear Energy Agency of Indonesia, Banten (Indonesia). Center for Nuclear Reactor Technology and Safety; Arbie, Bakri; Subki, Iyos [PT MOTAB Technology, Jakarta Barat (Indonesia)

    2017-03-15

    The optimal fuel composition of the 10 MWth Experimental Power Reactor (RDE), to be built by the Indonesian National Nuclear Energy Agency (BATAN), is a very important design parameter since it will directly affect the fuel cost, new and spent fuel storage capacity, and other back-end environmental burden. The RDE is a very small sized pebble-bed high temperature gas-cooled reactor (HTGR) with low enriched uranium (LEU) UO{sub 2} TRISO fuel under multipass or once-through-then-out fueling scheme. A scoping study on fuel composition parameters, namely heavy metal (HM) loading per pebble and uranium enrichment is conducted. All burnup, criticality calculations and core equilibrium search are carried out by using BATAN-MPASS, a general in-core fuel management code for pebble bed HTGRs, featured with many automatic equilibrium searching options as well as thermal-hydraulic calculation capability. The RDE User Requirement Document issued by BATAN is used to derive the main core design parameters and constraints. The scoping study is conducted over uranium enrichment in the range of 10 to 20 w/o and HM loading in the range of 4 g to 10 g/pebble. Fissile loading per unit energy generated (kg/GWd) is taken as the objective function for the present scoping study. The analysis results show that the optimal HM loading is around 8 g/pebble. Under the constraint of 80 GWd/t fuel discharge burnup imposed by the technical specification, the uranium enrichment for the optimal HM loading is approximately 13 w/o.

  12. Analysis of the optimal fuel composition for the Indonesian experimental power reactor

    International Nuclear Information System (INIS)

    Liem, Peng Hong; Sembiring, Tagor Malem

    2017-01-01

    The optimal fuel composition of the 10 MWth Experimental Power Reactor (RDE), to be built by the Indonesian National Nuclear Energy Agency (BATAN), is a very important design parameter since it will directly affect the fuel cost, new and spent fuel storage capacity, and other back-end environmental burden. The RDE is a very small sized pebble-bed high temperature gas-cooled reactor (HTGR) with low enriched uranium (LEU) UO_2 TRISO fuel under multipass or once-through-then-out fueling scheme. A scoping study on fuel composition parameters, namely heavy metal (HM) loading per pebble and uranium enrichment is conducted. All burnup, criticality calculations and core equilibrium search are carried out by using BATAN-MPASS, a general in-core fuel management code for pebble bed HTGRs, featured with many automatic equilibrium searching options as well as thermal-hydraulic calculation capability. The RDE User Requirement Document issued by BATAN is used to derive the main core design parameters and constraints. The scoping study is conducted over uranium enrichment in the range of 10 to 20 w/o and HM loading in the range of 4 g to 10 g/pebble. Fissile loading per unit energy generated (kg/GWd) is taken as the objective function for the present scoping study. The analysis results show that the optimal HM loading is around 8 g/pebble. Under the constraint of 80 GWd/t fuel discharge burnup imposed by the technical specification, the uranium enrichment for the optimal HM loading is approximately 13 w/o.

  13. Influence of dispersing additives and blend composition on stability of marine high-viscosity fuels

    Directory of Open Access Journals (Sweden)

    Т. Н. Митусова

    2017-12-01

    Full Text Available The article offers a definition of the stability of marine high-viscosity fuel from the point of view of the colloid-chemical concept of oil dispersed systems. The necessity and importance of the inclusion in the current regulatory requirements of this quality parameter of high-viscosity marine fuel is indicated. The objects of the research are high-viscosity marine fuels, the basic components of which are heavy oil residues: fuel oil that is the atmospheric residue of oil refining and viscosity breaking residue that is the product of light thermal cracking of fuel oil. As a thinning agent or distillate component, a light gas oil was taken from the catalytic cracking unit. The stability of the obtained samples was determined through the xylene equivalent index, which characterizes the stability of marine high-viscosity fuel to lamination during storage, transportation and operation processes. To improve performance, the resulting base compositions of high-viscosity marine fuels were modified by introducing small concentrations (0.05 % by weight of stabilizing additives based on oxyethylated amines of domestic origin and alkyl naphthalenes of foreign origin.

  14. Fuel Thermo-physical Characterization Project: Evaluation of Models to Calculate Thermal Diffusivity of Layered Composites

    Energy Technology Data Exchange (ETDEWEB)

    Burkes, Douglas [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Casella, Amanda J. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Gardner, Levi D. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Casella, Andrew M. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Huber, Tanja K. [Technische Universität München, Munich (Germany); Breitkreutz, Harald [Technische Universität München, Munich (Germany)

    2015-02-11

    The Office of Material Management and Minimization Fuel Thermo-physical Characterization Project at Pacific Northwest National Laboratory (PNNL) is tasked with using PNNL facilities and processes to receive irradiated low enriched uranium-molybdenum fuel plate samples and perform analyses in support of the Office of Material Management and Minimization Reactor Conversion Program. This work is in support of the Fuel Development Pillar that is managed by Idaho National Laboratory. A key portion of the scope associated with this project was to measure the thermal properties of fuel segments harvested from plates that were irradiated in the Advanced Test Reactor. Thermal diffusivity of samples prepared from the fuel segments was measured using laser flash analysis. Two models, one developed by PNNL and the other developed by the Technische Universität München (TUM), were evaluated to extract the thermal diffusivity of the uranium-molybdenum alloy from measurements made on the irradiated, layered composites. The experimental data of the “TC” irradiated fuel segment was evaluated using both models considering a three-layer and five-layer system. Both models are in acceptable agreement with one another and indicate that the zirconium diffusion barrier has a minimal impact on the overall thermal diffusivity of the monolithic U-Mo fuel.

  15. Composite cathode based on yttria stabilized bismuth oxide for low-temperature solid oxide fuel cells

    International Nuclear Information System (INIS)

    Xia Changrong; Zhang Yuelan; Liu Meilin

    2003-01-01

    Composites consisting of silver and yttria stabilized bismuth oxide (YSB) have been investigated as cathodes for low-temperature honeycomb solid oxide fuel cells with stabilized zirconia as electrolytes. At 600 deg. C, the interfacial polarization resistances of a porous YSB-Ag cathode is about 0.3 Ω cm 2 , more than one order of magnitude smaller than those of other reported cathodes on stabilized zirconia. For example, the interfacial resistances of a traditional YSZ-lanthanum maganites composite cathode is about 11.4 Ω cm 2 at 600 deg. C. Impedance analysis indicated that the performance of an YSB-Ag composite cathode fired at 850 deg. C for 2 h is severely limited by gas transport due to insufficient porosity. The high performance of the YSB-Ag cathodes is very encouraging for developing honeycomb fuel cells to be operated at temperatures below 600 deg. C

  16. Fuel effect on solution combustion synthesis of Co(Cr,Al)2O4 pigments

    International Nuclear Information System (INIS)

    Gilabert, J.; Palacios, M.D.; Sanz, V.; Mestre, S.

    2017-01-01

    The fuel effect on the synthesis of a ceramic pigment with a composition CoCr2−2ΨAl2ΨO4 (0≤Ψ≤1) by means of solution combustion synthesis process (SCS) has been studied. Three different fuels were selected to carry out the synthesis (urea, glycine and hexamethylentetramine (HMT)). Highly foamy pigments with very low density were obtained. Fd-3m spinel-type structure was obtained in all the experiments. Nevertheless, crystallinity and crystallite size of the spinels show significant differences with composition and fuel. The use of glycine along with the chromium-richest composition favours ion rearrangement to obtain the most ordered structure. Lattice parameter does not seem to be affected by fuel, although it evolves with Ψ according to Vegard's law. Colouring power in a transparent glaze shows important variations with composition. On the other hand, fuel effect presents a rather low influence since practically the same shades are obtained. However, it exerts certain effect on luminosity (L*). [es

  17. Responding effectively to fuel spills at airports

    International Nuclear Information System (INIS)

    Williams, L.E.

    1991-01-01

    Fuel spills are among the most frequent causes of emergency calls faced by airport firefighters. Most fuel spills are a result of human error and careless procedures. They always constitute an emergency and require fast, efficient action to prevent disaster. A fuel spill is an accidental release of fuel, in this case, from an aircraft fuel system, refueling vehicle or refueling system. A normal release of a few drops of fuel associated with a disconnection or other regular fueling operations should not be classified as a fuel spill. However, anytime fuel must be cleaned up and removed from an area, a fuel spill has occurred. Volatile fuels pose significant threats to people, equipment, facilities and cargo when they are released. Anyone near a spill, including ramp workers, fueling personnel and aircraft occupants, are in danger if the fuel ignites. Buildings and equipment in a spill area, such as terminals, hangars, aircraft, fuel trucks and service equipment also are at risk. An often neglected point is that aircraft cargo also is threatened by fuel spills

  18. EFFECT SIGNIFICANCE ASSESSMENT OF THE THERMODYNAMICAL FACTORS ON THE SOLID OXIDE FUEL CELL OPERATION

    Directory of Open Access Journals (Sweden)

    V. A. Sednin

    2015-01-01

    Full Text Available Technologies of direct conversion of the fuel energy into electrical power are an upcoming trend in power economy. Over the last decades a number of countries have created industrial prototypes of power plants on fuel elements (cells, while fuel cells themselves became a commercial product on the world energy market. High electrical efficiency of the fuel cells allows predictting their further spread as part of hybrid installations jointly with gas and steam turbines which specifically enables achieving the electrical efficiency greater than 70 %. Nevertheless, investigations in the area of increasing efficiency and reliability of the fuel cells continue. Inter alia, research into the effects of oxidizing reaction thermodynamic parameters, fuel composition and oxidation reaction products on effectiveness of the solid oxide fuel cells (SOFC is of specific scientific interest. The article presents a concise analysis of the fuel type effects on the SOFC efficiency. Based on the open publications experimental data and the data of numerical model studies, the authors adduce results of the statistical analysis of the SOFC thermodynamic parameters effect on the effectiveness of its functioning as well as of the reciprocative factors of these parameters and gas composition at the inlet and at the outlet of the cell. The presented diagrams reflect dimension of the indicated parameters on the SOFC operation effectiveness. The significance levels of the above listed factors are ascertained. Statistical analysis of the effects of the SOFC functionning process thermodynamical, consumption and concentration parameters demonstrates quintessential influence of the reciprocative factors (temperature – flow-rate and pressure – flow-rate and the nitrogen N2 and oxygen O2 concentrations on the operation efficiency in the researched range of its functioning. These are the parameters to be considered on a first-priority basis while developing mathematical models

  19. Gas fired boilers: Perspective for near future fuel composition and impact on burner design process

    Science.gov (United States)

    Schiro, Fabio; Stoppato, Anna; Benato, Alberto

    2017-11-01

    The advancements on gas boiler technology run in parallel with the growth of renewable energy production. The renewable production will impact on the fuel gas quality, since the gas grid will face an increasing injection of alternative fuels (biogas, biomethane, hydrogen). Biogas allows producing energy with a lower CO2 impact; hydrogen production by electrolysis can mitigate the issues related to the mismatch between energy production by renewable and energy request. These technologies will contribute to achieve the renewable production targets, but the impact on whole fuel gas production-to-consumption chain must be evaluated. In the first part of this study, the Authors present the future scenario of the grid gas composition and the implications on gas fed appliances. Given that the widely used premixed burners are currently designed mainly by trial and error, a broader fuel gas quality range means an additional hitch on this design process. A better understanding and structuring of this process is helpful for future appliance-oriented developments. The Authors present an experimental activity on a premixed condensing boiler setup. A test protocol highlighting the burners' flexibility in terms of mixture composition is adopted and the system fuel flexibility is characterized around multiple reference conditions.

  20. Gas fired boilers: Perspective for near future fuel composition and impact on burner design process

    Directory of Open Access Journals (Sweden)

    Schiro Fabio

    2017-01-01

    Full Text Available The advancements on gas boiler technology run in parallel with the growth of renewable energy production. The renewable production will impact on the fuel gas quality, since the gas grid will face an increasing injection of alternative fuels (biogas, biomethane, hydrogen. Biogas allows producing energy with a lower CO2 impact; hydrogen production by electrolysis can mitigate the issues related to the mismatch between energy production by renewable and energy request. These technologies will contribute to achieve the renewable production targets, but the impact on whole fuel gas production-to-consumption chain must be evaluated. In the first part of this study, the Authors present the future scenario of the grid gas composition and the implications on gas fed appliances. Given that the widely used premixed burners are currently designed mainly by trial and error, a broader fuel gas quality range means an additional hitch on this design process. A better understanding and structuring of this process is helpful for future appliance-oriented developments. The Authors present an experimental activity on a premixed condensing boiler setup. A test protocol highlighting the burners' flexibility in terms of mixture composition is adopted and the system fuel flexibility is characterized around multiple reference conditions.

  1. Health effects attributable to coal and nuclear fuel cycle alternatives

    International Nuclear Information System (INIS)

    Gotchy, R.L.

    1977-09-01

    Estimates of mortality and morbidity are presented based on present-day knowledge of health effects resulting from current component designs and operations of the fuel cycles, and anticipated emission rates and occupational exposure for the various fuel cycle facilities expected to go into operation in approximately the 1975-1985 period. It was concluded that, although there are large uncertainties in the estimates of potential health effects, the coal fuel cycle alternative has a greater health impact on man than the uranium fuel cycle. However, the increased risk of health effects for either fuel cycle represents a very small incremental risk to the average individual in the public

  2. Lanthanum gallate and ceria composite as electrolyte for solid oxide fuel cells

    International Nuclear Information System (INIS)

    Li Shuai; Li Zhicheng; Bergman, Bill

    2010-01-01

    The composite of doped lanthanum gallate (La 0.9 Sr 0.1 Ga 0.8 Mg 0.2 O 2.85 , LSGM) and doped ceria (Ce 0.8 Sm 0.2 O 1.9 , CSO) was investigated as an electrolyte for solid oxide fuel cell (SOFC). The LSGM-CSO composite was examined by X-ray diffraction (XRD) and impedance spectroscopy. It was found that the sintered LSGM-CSO composite contains mainly fluorite CeO 2 phase and a minority impurity phase, Sm 3 Ga 5 O 12 . The LSGM-CSO composite electrolyte shows a small grain boundary response in the impedance spectroscopy as compared to LSGM and CSO pellets. The composite electrolyte exhibits the highest conductivity in the temperature range of 250-600 o C, compared to LSGM and CSO. The LSGM-CSO composite can be expected to be an attractive intermediate temperature electrolyte material for solid oxide fuel cells.

  3. Lanthanum gallate and ceria composite as electrolyte for solid oxide fuel cells

    Energy Technology Data Exchange (ETDEWEB)

    Li Shuai, E-mail: shuail@kth.s [Department of Materials Science and Engineering, School of Industrial Engineering and Management, Royal Institute of Technology, SE 10044 Stockholm (Sweden); Li Zhicheng [School of Materials Science and Engineering, Central South University, 410083 Changsha, Hunan (China); Bergman, Bill [Department of Materials Science and Engineering, School of Industrial Engineering and Management, Royal Institute of Technology, SE 10044 Stockholm (Sweden)

    2010-03-04

    The composite of doped lanthanum gallate (La{sub 0.9}Sr{sub 0.1}Ga{sub 0.8}Mg{sub 0.2}O{sub 2.85}, LSGM) and doped ceria (Ce{sub 0.8}Sm{sub 0.2}O{sub 1.9}, CSO) was investigated as an electrolyte for solid oxide fuel cell (SOFC). The LSGM-CSO composite was examined by X-ray diffraction (XRD) and impedance spectroscopy. It was found that the sintered LSGM-CSO composite contains mainly fluorite CeO{sub 2} phase and a minority impurity phase, Sm{sub 3}Ga{sub 5}O{sub 12}. The LSGM-CSO composite electrolyte shows a small grain boundary response in the impedance spectroscopy as compared to LSGM and CSO pellets. The composite electrolyte exhibits the highest conductivity in the temperature range of 250-600 {sup o}C, compared to LSGM and CSO. The LSGM-CSO composite can be expected to be an attractive intermediate temperature electrolyte material for solid oxide fuel cells.

  4. Effect of increased fuel exploitation on the main characteristics of spent WWER 440 fuel

    International Nuclear Information System (INIS)

    Zib, A.

    2001-01-01

    The article deals with the effect of a higher fuel exploitation on the main characteristics (particularly radioactivity and decay heat power) of spent WWER 440 fuel. The main characteristics were calculated by using the Origen code. The study was implemented as a three-stage process. In the first stage, the radioactivity and residual thermal power time evolution values were calculated for the 'typical fuel', i. e. fuel assembly with initial enrichment of 3.6% U-235, 3 years in reactor, and burnup of 30 MWd/kg U. In the second stage, ceteris paribus radioactivity and thermal power analyses of sensitivity to changes in the fuel burnup, initial fuel enrichment, and time in reactor were carried out for the typical fuel assembly. In the third stage, the effect of changes in all three variables was investigated for fuel assemblies possessing parameters that approach those applied at the Dukovany NPP. The effect of a higher fuel exploitation on the interim fuel storage is also mentioned. (author)

  5. Effective equivalencies of industrial fuels; Equivalencias efetivas de combustiveis industriais

    Energy Technology Data Exchange (ETDEWEB)

    Fehr, Manfred [Uberlandia Univ., MG (Brazil). Dept. de Engenharia Quimica

    1986-01-01

    This work perform comparison criteria between various solid, liquid and gaseous fuels, under several burn conditions. The objective of this comparison is to choose the most cost-effective fuel for heat generation, including the variables of fuel price, consumption, waste generation and safety conditions 16 refs., 1 fig., 8 tabs.

  6. Impact of Alternative Jet Fuels on Engine Exhaust Composition During the 2015 ECLIF Ground-Based Measurements Campaign.

    Science.gov (United States)

    Schripp, Tobias; Anderson, Bruce; Crosbie, Ewan C; Moore, Richard H; Herrmann, Friederike; Oßwald, Patrick; Wahl, Claus; Kapernaum, Manfred; Köhler, Markus; Le Clercq, Patrick; Rauch, Bastian; Eichler, Philipp; Mikoviny, Tomas; Wisthaler, Armin

    2018-04-17

    The application of fuels from renewable sources ("alternative fuels") in aviation is important for the reduction of anthropogenic carbon dioxide emissions, but may also attribute to reduced release of particles from jet engines. The present experiment describes ground-based measurements in the framework of the ECLIF (Emission and Climate Impact of Alternative Fuels) campaign using an Airbus A320 (V2527-A5 engines) burning six fuels of chemically different composition. Two reference Jet A-1 with slightly different chemical parameters were applied and further used in combination with a Fischer-Tropsch synthetic paraffinic kerosene (FT-SPK) to prepare three semi synthetic jet fuels (SSJF) of different aromatic content. In addition, one commercially available fully synthetic jet fuel (FSJF) featured the lowest aromatic content of the fuel selection. Neither the release of nitrogen oxide or carbon monoxide was significantly affected by the different fuel composition. The measured particle emission indices showed a reduction up to 50% (number) and 70% (mass) for two alternative jet fuels (FSJF, SSJF2) at low power settings in comparison to the reference fuels. The reduction is less pronounced at higher operating conditions but the release of particle number and particle mass is still significantly lower for the alternative fuels than for both reference fuels. The observed correlation between emitted particle mass and fuel aromatics is not strict. Here, the H/C ratio is a better indicator for soot emission.

  7. Three-dimensional random resistor-network model for solid oxide fuel cell composite electrodes

    International Nuclear Information System (INIS)

    Abbaspour, Ali; Luo Jingli; Nandakumar, K.

    2010-01-01

    A three-dimensional reconstruction of solid oxide fuel cell (SOFC) composite electrodes was developed to evaluate the performance and further investigate the effect of microstructure on the performance of SOFC electrodes. Porosity of the electrode is controlled by adding pore former particles (spheres) to the electrode and ignoring them in analysis step. To enhance connectivity between particles and increase the length of triple-phase boundary (TPB), sintering process is mimicked by enlarging particles to certain degree after settling them inside the packing. Geometrical characteristics such as length of TBP and active contact area as well as porosity can easily be calculated using the current model. Electrochemical process is simulated using resistor-network model and complete Butler-Volmer equation is used to deal with charge transfer process on TBP. The model shows that TPBs are not uniformly distributed across the electrode and location of TPBs as well as amount of electrochemical reaction is not uniform. Effects of electrode thickness, particle size ratio, electron and ion conductor conductivities and rate of electrochemical reaction on overall electrochemical performance of electrode are investigated.

  8. The influence of weather and fuel type on the fuel composition of the area burned by forest fires in Ontario, 1996-2006.

    Science.gov (United States)

    Podur, Justin J; Martell, David L

    2009-07-01

    Forest fires are influenced by weather, fuels, and topography, but the relative influence of these factors may vary in different forest types. Compositional analysis can be used to assess the relative importance of fuels and weather in the boreal forest. Do forest or wild land fires burn more flammable fuels preferentially or, because most large fires burn in extreme weather conditions, do fires burn fuels in the proportions they are available despite differences in flammability? In the Canadian boreal forest, aspen (Populus tremuloides) has been found to burn in less than the proportion in which it is available. We used the province of Ontario's Provincial Fuels Database and fire records provided by the Ontario Ministry of Natural Resources to compare the fuel composition of area burned by 594 large (>40 ha) fires that occurred in Ontario's boreal forest region, a study area some 430,000 km2 in size, between 1996 and 2006 with the fuel composition of the neighborhoods around the fires. We found that, over the range of fire weather conditions in which large fires burned and in a study area with 8% aspen, fires burn fuels in the proportions that they are available, results which are consistent with the dominance of weather in controlling large fires.

  9. Normal composite face effects in developmental prosopagnosia.

    Science.gov (United States)

    Biotti, Federica; Wu, Esther; Yang, Hua; Jiahui, Guo; Duchaine, Bradley; Cook, Richard

    2017-10-01

    Upright face perception is thought to involve holistic processing, whereby local features are integrated into a unified whole. Consistent with this view, the top half of one face appears to fuse perceptually with the bottom half of another, when aligned spatially and presented upright. This 'composite face effect' reveals a tendency to integrate information from disparate regions when faces are presented canonically. In recent years, the relationship between susceptibility to the composite effect and face recognition ability has received extensive attention both in participants with normal face recognition and participants with developmental prosopagnosia. Previous results suggest that individuals with developmental prosopagnosia may show reduced susceptibility to the effect suggestive of diminished holistic face processing. Here we describe two studies that examine whether developmental prosopagnosia is associated with reduced composite face effects. Despite using independent samples of developmental prosopagnosics and different composite procedures, we find no evidence for reduced composite face effects. The experiments yielded similar results; highly significant composite effects in both prosopagnosic groups that were similar in magnitude to the effects found in participants with normal face processing. The composite face effects exhibited by both samples and the controls were greatly diminished when stimulus arrangements were inverted. Our finding that the whole-face binding process indexed by the composite effect is intact in developmental prosopagnosia indicates that other factors are responsible for developmental prosopagnosia. These results are also inconsistent with suggestions that susceptibility to the composite face effect and face recognition ability are tightly linked. While the holistic process revealed by the composite face effect may be necessary for typical face perception, it is not sufficient; individual differences in face recognition ability

  10. Usage of burnt fuel isotopic compositions from engineering codes in Monte-Carlo code calculations

    International Nuclear Information System (INIS)

    Aleshin, Sergey S.; Gorodkov, Sergey S.; Shcherenko, Anna I.

    2015-01-01

    A burn-up calculation of VVER's cores by Monte-Carlo code is complex process and requires large computational costs. This fact makes Monte-Carlo codes usage complicated for project and operating calculations. Previously prepared isotopic compositions are proposed to use for the Monte-Carlo code (MCU) calculations of different states of VVER's core with burnt fuel. Isotopic compositions are proposed to calculate by an approximation method. The approximation method is based on usage of a spectral functionality and reference isotopic compositions, that are calculated by engineering codes (TVS-M, PERMAK-A). The multiplication factors and power distributions of FA and VVER with infinite height are calculated in this work by the Monte-Carlo code MCU using earlier prepared isotopic compositions. The MCU calculation data were compared with the data which were obtained by engineering codes.

  11. Structural Study of Reduced Graphene Oxide/ Polypyrrole Composite as Methanol Sensor in Direct Methanol Fuel Cell

    International Nuclear Information System (INIS)

    Mumtazah Atiqah Hassan; Siti Kartom Kamarudin; Siti Kartom Kamarudin

    2016-01-01

    Density functional theory (DFT) computations were performed on the optimized geometric and electronic properties of reduced graphene oxide/polypyrole (rGO/ PPy) composite in comparison with pure graphene and graphene oxide structures. Incorporation of both reduced GO (rGO) and PPy will form a good composite which have advantages from both materials such as good mechanical strength and excellent electrical conductivity. These composite would be very suitable in fabrication of methanol sensor in direct methanol fuel cell (DMFC). The HOMO-LUMO energy (eV) was also calculated. These computations provide a theoretical explanation for the good performance of rGO/ PPy composite as electrode materials in methanol sensor. (author)

  12. Measurement of reactivity effect caused by nonuniform fuel distribution

    International Nuclear Information System (INIS)

    Yamane, Yoshihiro; Hirano, Yasushi; Yasui, Hazime; Nishina, Kojiro; Shiroya, Seiji

    1991-01-01

    A reactivity effect due to a spatial variation of nuclear fuel concentration is an important problem in a reprocessing plant. To estimate this reactivity effect theoretically, the ''Goertzel's necessary condition, and th Fuel Importance'' theory have been proposed. In order to verify these theories, we have performed systematic measurements of reactivity effect due to the nonuniformity in the fuel distribution within the Kyoto University Critical Assembly. Neutron flux distribution and Fuel Importance distribution were also determined. A nonuniform assembly whose fuel concentration in the center region was 40% higher than the uniform one was found to have an excess reactivity of 0.3%Δk/k, with the same total uranium mass for which the uniform assembly was just critical. Moreover, its spatial distribution of thermal neutron flux and of Fuel Importance were more flat than those of the uniform assembly, as expected by the Goertzel's condition and the Fuel Importance theory. (Author)

  13. Fuel fragmentation data review and separate effects testing

    International Nuclear Information System (INIS)

    Yueh, Ken. H.; Snis, N.; Mitchell, D.; Munoz-Reja, C.

    2014-01-01

    A simple alternative test has been developed to study the fuel fragmentation process at loss of coolant accident (LOCA) temperatures. The new test heats a short section of fuel, approximately two pellets worth of material, in a tube furnace open to air. An axial slit is cut in the test sample cladding to reduce radial restraint and to simulate ballooned condition. The tube furnace allows the fuel fragmentation process be observed during the experiment. The test was developed as a simple alternative so large number of tests could be conducted quickly and efficiently to identify key variables that influence fuel fragmentation and to zeroing on the fuel fragmentation burn-up threshold. Several tests were conducted, using fuel materials from fuel rods that were used in earlier integral tests to benchmark and validate the test technique. High burn-up fuel materials known to be above the fragmentation threshold was used to evaluate the fragmentation process as a function of temperature. Even with an axial slit and both ends open, no significant fuel detachment/release was detected until above 750°C. Additional tests were conducted with fuel materials at burn-ups closer to the fuel fragmentation burn-up threshold. Results from these tests indicate a minor power history effect on the fuel fragmentation burn-up threshold. An evaluation of available literature and data generated from this work suggest a fuel fragmentation burn-up threshold between 70 and 75 GWd/MTU. (author)

  14. Instant release fraction and matrix release of high burn-up UO{sub 2} spent nuclear fuel: Effect of high burn-up structure and leaching solution composition

    Energy Technology Data Exchange (ETDEWEB)

    Serrano-Purroy, D., E-mail: Daniel.serrano-purroy@ec.europa.eu [European Commission, Joint Research Centre, Institute for Transuranium Elements, P.O. Box 2340, D-76125 Karlsruhe (Germany); Clarens, F.; Gonzalez-Robles, E. [CTM Centre Tecnologic, Avda. Bases de Manresa 1, 08240 Barcelona (Spain); Glatz, J.P.; Wegen, D.H. [European Commission, Joint Research Centre, Institute for Transuranium Elements, P.O. Box 2340, D-76125 Karlsruhe (Germany); Pablo, J. de [CTM Centre Tecnologic, Avda. Bases de Manresa 1, 08240 Barcelona (Spain); Department of Chemical Engineering, Universitat Politecnica de Catalunya, Avda. Diagonal 647, 08028 Barcelona (Spain); Casas, I.; Gimenez, J. [Department of Chemical Engineering, Universitat Politecnica de Catalunya, Avda. Diagonal 647, 08028 Barcelona (Spain); Martinez-Esparza, A. [ENRESA, C/Emilio Vargas 7, 28043 Madrid (Spain)

    2012-08-15

    Two weak points in Performance Assessment (PA) exercises regarding the alteration of Spent Nuclear Fuel (SNF) are the contribution of the so-called Instant Release Fraction (IRF) and the effect of High Burn-Up Structure (HBS). This manuscript focuses on the effect of HBS in matrix (long term) and instant release of a Pressurised Water Reactor (PWR) SNF irradiated in a commercial reactor with a mean Burn-Up (BU) of 60 GWd/tU. In order to study the HBS contribution, two samples from different radial positions have been prepared. One from the centre of the SNF, labelled CORE, and one from the periphery, enriched with HBS and labelled OUT. Static leaching experiments have been carried out with two synthetic leaching solutions: bicarbonate (BIC) and Bentonitic Granitic Groundwater (BGW), and in all cases under oxidising conditions. IRF values have been calculated from the determined Fraction of Inventory in Aqueous Phase (FIAP). In all studied cases, some radionuclides (RN): Rb, Sr and Cs, have shown higher release rates than uranium, especially at the beginning of the experiment, and have been considered as IRF. Redox sensitive RN like Mo and Tc have been found to dissolve slightly faster than uranium and further studies might be needed to confirm if they can also be considered part of the IRF. Most of the remaining studied RN, mainly actinides and lanthanides, have been found to dissolve congruently with the uranium matrix. Finally, Zr, Ru and Rh presented lower release rates than the matrix. Higher matrix release has been determined for CORE than for OUT samples showing that the formation of HBS might have a protective effect against the oxidative corrosion of the SNF. On the contrary, no significant differences have been observed between the two studied leaching solutions (BIC and BGW). Two different IRF contributions have been determined. One corresponding to the fraction of inventory segregated in the external open grain boundaries, directly available to water and

  15. Method of determining the composition of fuels for FBR type reactors

    International Nuclear Information System (INIS)

    Tsutsumi, Kiyoshi.

    1981-01-01

    Purpose: To improve the core safety of FBR type reactors by determining the composition of fuels composed of oxide mixture of plutonium and uranium, using a relation between specific plutonium seed and plutonium enrichment degree. Method: Relation is determined between the ratio of a specific plutonium seed for constituting plutonium oxide, for example 239 U ratio and a plutonium enrichment degree required for setting the assembly power to a constant level. The ratio of 239 U is plutonium having a given isotopic ratio is also determined. The accuracy of the 239 U ratio can be improved by the correction using the density coefficient. Then, the plutonium enrichment degree is determined using the relation determined as above based on the thus determined 239 U ratio. The composition of the fuel using oxide mixture of plutonium and uranium is determined by utilizing the thus obtained plutonium enrichment degree. (Moriyama, K.)

  16. Spent fuel isotopic composition data base system on WWW. SFCOMPO on W3

    Energy Technology Data Exchange (ETDEWEB)

    Suyama, Kenya [Japan Atomic Energy Research Inst., Tokai, Ibaraki (Japan). Tokai Research Establishment

    1997-11-01

    Spent Fuel Composition Data Base System `SFCOMPO` has been developed on IBM compatible PC. This data base system is not widely used, since users must purchase the data base software by themselves. `SFCOMPO on W3` is a system to overcome this problem. User can search and visualize the data in the data base by accessing WWW server through the Internet from local machine. Only a browsing software to access WWW should be prepared. It enables us to easily search data of spent fuel composition if we can access the Internet. This system can be operated on WWW server machine which supports use of Common Gateway Interface (CGI). This report describes the background of the development of SFCOMPO on W3 and is it`s user`s manual. (author)

  17. Spent fuel isotopic composition data base system on WWW. SFCOMPO on W3

    International Nuclear Information System (INIS)

    Suyama, Kenya

    1997-11-01

    Spent Fuel Composition Data Base System 'SFCOMPO' has been developed on IBM compatible PC. This data base system is not widely used, since users must purchase the data base software by themselves. 'SFCOMPO on W3' is a system to overcome this problem. User can search and visualize the data in the data base by accessing WWW server through the Internet from local machine. Only a browsing software to access WWW should be prepared. It enables us to easily search data of spent fuel composition if we can access the Internet. This system can be operated on WWW server machine which supports use of Common Gateway Interface (CGI). This report describes the background of the development of SFCOMPO on W3 and is it's user's manual. (author)

  18. Development of cesium phosphotungstate salt and chitosan composite membrane for direct methanol fuel cells.

    Science.gov (United States)

    Xiao, Yanxin; Xiang, Yan; Xiu, Ruijie; Lu, Shanfu

    2013-10-15

    A novel composite membrane has been developed by doping cesium phosphotungstate salt (CsxH3-xPW12O40 (0≤x≤3), Csx-PTA) into chitosan (CTS/Csx-PTA) for application in direct methanol fuel cells (DMFCs). Uniform distribution of Csx-PTA nanoparticles has been achieved in the chitosan matrix. The proton conductivity of the composite membrane is significantly affected by the Csx-PTA content in the composite membrane as well as the Cs substitution in PTA. The highest proton conductivity for the CTS/Csx-PTA membranes was obtained with x=2 and Cs2-PTA content of 5 wt%. The value is 6×10(-3) S cm(-1) and 1.75×10(-2) S cm(-1) at 298 K and 353 K, respectively. The methanol permeability of CTS/Cs2-PTA membrane is about 5.6×10(-7), 90% lower than that of Nafion-212 membrane. The highest selectivity factor (φ) was obtained on CTS/Cs2-PTA-5 wt% composite membrane, 1.1×10(4)/Scm(-3)s. The present study indicates the promising potential of CTS/Csx-PTA composite membrane as alternative proton exchange membranes in direct methanol fuel cells. Copyright © 2013 Elsevier Ltd. All rights reserved.

  19. Investigating the mechanical and barrier properties to oxygen and fuel of high density polyethylene–graphene nanoplatelet composites

    Energy Technology Data Exchange (ETDEWEB)

    Honaker, K., E-mail: honakers@egr.msu.edu; Vautard, F.; Drzal, L.T.

    2017-02-15

    Highlights: • Melt mixing used to investigate high density polyethylene and graphene nanoplatelet composite. • Addition of graphene nanoplatelets resulted in a stiffer polymer matrix. • Presence of graphene nanoplatelets causes a decrease in oxygen and fuel permeation. - Abstract: Graphene nanoplatelets (GnP) of different sizes were investigated for their ability to modify high density polyethylene (HDPE) for potential fuel system applications, focusing on compounding via melt mixing in a twin-screw extruder. Mechanical properties, crystallinity of the polymer, and permeation to oxygen and fuel were assessed as a function of GnP concentration. The surface of GnP acted as a nucleation site for the generation of HDPE crystallites, increasing the crystallinity. The flexural properties were improved, clearly influenced by platelet size and quality of dispersion. A sharp, 46% decrease of the impact resistance was observed, even at low GnP concentration (0.2 wt.%). With a 15 wt.% GnP-M-15 (platelets with a 15 μm diameter), a 73% reduction in oxygen permeation was observed and a 74% reduction in fuel vapor transmission. This correlation was similar throughout the GnP concentration range. The smaller diameter platelets had a lesser effect on the properties.

  20. Cost and performance prospects for composite bipolar plates in fuel cells and redox flow batteries

    Science.gov (United States)

    Minke, Christine; Hickmann, Thorsten; dos Santos, Antonio R.; Kunz, Ulrich; Turek, Thomas

    2016-02-01

    Carbon-polymer-composite bipolar plates (BPP) are suitable for fuel cell and flow battery applications. The advantages of both components are combined in a product with high electrical conductivity and good processability in convenient polymer forming processes. In a comprehensive techno-economic analysis of materials and production processes cost factors are quantified. For the first time a technical cost model for BPP is set up with tight integration of material characterization measurements.

  1. Experimental Assessment of the Mass of Ash Residue During the Burning of Droplets of a Composite Liquid Fuel

    Science.gov (United States)

    Glushkov, D. O.; Zakharevich, A. V.; Strizhak, P. A.; Syrodoi, S. V.

    2018-05-01

    An experimental study has been made of the regularities of burning of single droplets of typical compositions of a composite liquid fuel during the heating by an air flow with a varied temperature (600-900 K). As the basic components of the compositions of the composite liquid fuel, use was made of the: waste of processing (filter cakes) of bituminous coals of ranks K, C, and T, waste motor, turbine, and transformer oils, process mixture of mazut and oil, heavy crude, and plasticizer. The weight fraction of a liquid combustible component (petroleum) product) ranged within 0-15%. Consideration has been given to droplets of a composite liquid fuel with dimensions (radius) of 0.5 to 2 mm. Conditions of low-temperature initiation of combustion to ensure a minimum possible mass of solid incombustible residue have been determined. Petroleum products have been singled out whose addition to the composition of the composite liquid fuel tends to increase the ash mass (compared to the corresponding composition without a liquid combustible component). Approximation dependences have been obtained which permit predicting the influence of the concentration of the liquid petroleum product as part of the composite liquid fuel on the ash-residue mass.

  2. Electrospun Nafion®/Polyphenylsulfone Composite Membranes for Regenerative Hydrogen Bromine Fuel Cells

    Science.gov (United States)

    Park, Jun Woo; Wycisk, Ryszard; Pintauro, Peter N.; Yarlagadda, Venkata; Van Nguyen, Trung

    2016-01-01

    The regenerative H2/Br2-HBr fuel cell, utilizing an oxidant solution of Br2 in aqueous HBr, shows a number of benefits for grid-scale electricity storage. The membrane-electrode assembly, a key component of a fuel cell, contains a proton-conducting membrane, typically based on the perfluorosulfonic acid (PFSA) ionomer. Unfortunately, the high cost of PFSA membranes and their relatively high bromine crossover are serious drawbacks. Nanofiber composite membranes can overcome these limitations. In this work, composite membranes were prepared from electrospun dual-fiber mats containing Nafion® PFSA ionomer for facile proton transport and an uncharged polymer, polyphenylsulfone (PPSU), for mechanical reinforcement, and swelling control. After electrospinning, Nafion/PPSU mats were converted into composite membranes by softening the PPSU fibers, through exposure to chloroform vapor, thus filling the voids between ionomer nanofibers. It was demonstrated that the relative membrane selectivity, referenced to Nafion® 115, increased with increasing PPSU content, e.g., a selectivity of 11 at 25 vol% of Nafion fibers. H2-Br2 fuel cell power output with a 65 μm thick membrane containing 55 vol% Nafion fibers was somewhat better than that of a 150 μm Nafion® 115 reference, but its cost advantage due to a four-fold decrease in PFSA content and a lower bromine species crossover make it an attractive candidate for use in H2/Br2-HBr systems. PMID:28773268

  3. Development of composite membranes of PVA-TEOS doped KOH for alkaline membrane fuel cell

    International Nuclear Information System (INIS)

    Haryadi,; Sugianto, D.; Ristopan, E.

    2015-01-01

    Anion exchange membranes (AEMs) play an important role in separating fuel and oxygen (or air) in the Alkaline Membrane Fuel Cells. Preparation of hybrid organic inorganic materials of Polyvinylalcohol (PVA) - Tetraethylorthosilicate (TEOS) composite membrane doped KOH for direct alcohol alkaline fuel cell application has been investigated. The sol-gel method has been used to prepare the composite membrane of PVA-TEOS through crosslinking step and catalyzed by concentrated of hydrochloric acid. The gel solution was cast on the membrane plastic plate to obtain membrane sheets. The dry membranes were then doped by immersing in various concentrations of KOH solutions for about 4 hours. Investigations of the cross-linking process and the presence of hydroxyl group were conducted by FTIR as shown for frequency at about 1600 cm −1 and 3300 cm −1 respectively. The degree of swelling in ethanol decreased as the KOH concentration for membrane soaking process increased. The ion exchange capacity (IEC) of the membrane was 0.25meq/g. This composite membranes display significant ionic conductivity of 3.23 x 10 −2 S/cm in deionized water at room temperature. In addition, the morphology observation by scanning electron microscope (SEM) of the membrane indicates that soaking process of membrane in KOH increased thermal resistant

  4. Development of composite membranes of PVA-TEOS doped KOH for alkaline membrane fuel cell

    Energy Technology Data Exchange (ETDEWEB)

    Haryadi,, E-mail: haryadi@polban.ac.id; Sugianto, D.; Ristopan, E. [Department of Chemical Engineering, Politeknik Negeri Bandung Jl. Gegerkalong Hilir, Ds. Ciwaruga, Bandung West Java (Indonesia)

    2015-12-29

    Anion exchange membranes (AEMs) play an important role in separating fuel and oxygen (or air) in the Alkaline Membrane Fuel Cells. Preparation of hybrid organic inorganic materials of Polyvinylalcohol (PVA) - Tetraethylorthosilicate (TEOS) composite membrane doped KOH for direct alcohol alkaline fuel cell application has been investigated. The sol-gel method has been used to prepare the composite membrane of PVA-TEOS through crosslinking step and catalyzed by concentrated of hydrochloric acid. The gel solution was cast on the membrane plastic plate to obtain membrane sheets. The dry membranes were then doped by immersing in various concentrations of KOH solutions for about 4 hours. Investigations of the cross-linking process and the presence of hydroxyl group were conducted by FTIR as shown for frequency at about 1600 cm{sup −1} and 3300 cm{sup −1} respectively. The degree of swelling in ethanol decreased as the KOH concentration for membrane soaking process increased. The ion exchange capacity (IEC) of the membrane was 0.25meq/g. This composite membranes display significant ionic conductivity of 3.23 x 10{sup −2} S/cm in deionized water at room temperature. In addition, the morphology observation by scanning electron microscope (SEM) of the membrane indicates that soaking process of membrane in KOH increased thermal resistant.

  5. Development of composite membranes of PVA-TEOS doped KOH for alkaline membrane fuel cell

    Science.gov (United States)

    Haryadi, Sugianto, D.; Ristopan, E.

    2015-12-01

    Anion exchange membranes (AEMs) play an important role in separating fuel and oxygen (or air) in the Alkaline Membrane Fuel Cells. Preparation of hybrid organic inorganic materials of Polyvinylalcohol (PVA) - Tetraethylorthosilicate (TEOS) composite membrane doped KOH for direct alcohol alkaline fuel cell application has been investigated. The sol-gel method has been used to prepare the composite membrane of PVA-TEOS through crosslinking step and catalyzed by concentrated of hydrochloric acid. The gel solution was cast on the membrane plastic plate to obtain membrane sheets. The dry membranes were then doped by immersing in various concentrations of KOH solutions for about 4 hours. Investigations of the cross-linking process and the presence of hydroxyl group were conducted by FTIR as shown for frequency at about 1600 cm-1 and 3300 cm-1 respectively. The degree of swelling in ethanol decreased as the KOH concentration for membrane soaking process increased. The ion exchange capacity (IEC) of the membrane was 0.25meq/g. This composite membranes display significant ionic conductivity of 3.23 x 10-2 S/cm in deionized water at room temperature. In addition, the morphology observation by scanning electron microscope (SEM) of the membrane indicates that soaking process of membrane in KOH increased thermal resistant.

  6. Electrospun Nafion®/Polyphenylsulfone Composite Membranes for Regenerative Hydrogen Bromine Fuel Cells.

    Science.gov (United States)

    Park, Jun Woo; Wycisk, Ryszard; Pintauro, Peter N; Yarlagadda, Venkata; Van Nguyen, Trung

    2016-02-29

    The regenerative H₂/Br₂-HBr fuel cell, utilizing an oxidant solution of Br₂ in aqueous HBr, shows a number of benefits for grid-scale electricity storage. The membrane-electrode assembly, a key component of a fuel cell, contains a proton-conducting membrane, typically based on the perfluorosulfonic acid (PFSA) ionomer. Unfortunately, the high cost of PFSA membranes and their relatively high bromine crossover are serious drawbacks. Nanofiber composite membranes can overcome these limitations. In this work, composite membranes were prepared from electrospun dual-fiber mats containing Nafion ® PFSA ionomer for facile proton transport and an uncharged polymer, polyphenylsulfone (PPSU), for mechanical reinforcement, and swelling control. After electrospinning, Nafion/PPSU mats were converted into composite membranes by softening the PPSU fibers, through exposure to chloroform vapor, thus filling the voids between ionomer nanofibers. It was demonstrated that the relative membrane selectivity, referenced to Nafion ® 115, increased with increasing PPSU content, e.g., a selectivity of 11 at 25 vol% of Nafion fibers. H₂-Br₂ fuel cell power output with a 65 μm thick membrane containing 55 vol% Nafion fibers was somewhat better than that of a 150 μm Nafion ® 115 reference, but its cost advantage due to a four-fold decrease in PFSA content and a lower bromine species crossover make it an attractive candidate for use in H₂/Br₂-HBr systems.

  7. Electrospun Nafion®/Polyphenylsulfone Composite Membranes for Regenerative Hydrogen Bromine Fuel Cells

    Directory of Open Access Journals (Sweden)

    Jun Woo Park

    2016-02-01

    Full Text Available The regenerative H2/Br2-HBr fuel cell, utilizing an oxidant solution of Br2 in aqueous HBr, shows a number of benefits for grid-scale electricity storage. The membrane-electrode assembly, a key component of a fuel cell, contains a proton-conducting membrane, typically based on the perfluorosulfonic acid (PFSA ionomer. Unfortunately, the high cost of PFSA membranes and their relatively high bromine crossover are serious drawbacks. Nanofiber composite membranes can overcome these limitations. In this work, composite membranes were prepared from electrospun dual-fiber mats containing Nafion® PFSA ionomer for facile proton transport and an uncharged polymer, polyphenylsulfone (PPSU, for mechanical reinforcement, and swelling control. After electrospinning, Nafion/PPSU mats were converted into composite membranes by softening the PPSU fibers, through exposure to chloroform vapor, thus filling the voids between ionomer nanofibers. It was demonstrated that the relative membrane selectivity, referenced to Nafion® 115, increased with increasing PPSU content, e.g., a selectivity of 11 at 25 vol% of Nafion fibers. H2-Br2 fuel cell power output with a 65 μm thick membrane containing 55 vol% Nafion fibers was somewhat better than that of a 150 μm Nafion® 115 reference, but its cost advantage due to a four-fold decrease in PFSA content and a lower bromine species crossover make it an attractive candidate for use in H2/Br2-HBr systems.

  8. Synthesis of Poly(3,4-Ethylenedioxy thiophene)-Poly(Styrene-4-Sulfonate) Composites for Support Fuel Cell Catalyst Layer

    International Nuclear Information System (INIS)

    Eko Sulistiyono; Murni Handayani

    2009-01-01

    Synthesis of poly(3,4-ethylenedioxy thiophene)-poly(styrene-4-sulfonate) composites for support fuel cell catalyst layer are synthesis composites which become fuel cell catalyst support so that catalyst has optimal performance. Main function of composites is support platinum particle for application in fuel cell. This article explains the result of composites production process from ( 3,4 Ethylenedioxy thiophene) and Sodium poly( styrene - 4-sulfonate) using two methods Jingning Shan method (method 1) and Zhigang Qi and Peter G.Pickup method (method 2). Analysis of the synthesis results used Scanning Electron Microscopic –Electron Dispersive X – Ray Spectrophotometer (SEM-EDS ). The analysis result show that both methods produce polymer agglomerate into a sponge-like morphology. Composite from method 1 has morphology, pores and proton transport better than composite produced by method 2. (author)

  9. Thermal conductivity analysis of SiC ceramics and fully ceramic microencapsulated fuel composites

    International Nuclear Information System (INIS)

    Lee, Hyeon-Geun; Kim, Daejong; Lee, Seung Jae; Park, Ji Yeon; Kim, Weon-Ju

    2017-01-01

    Highlights: • Thermal conductivity of SiC ceramics and FCM pellets was measured and discussed. • Thermal conductivity of FCM pellets was analyzed by the Maxwell-Eucken equation. • Effective thermal conductivity of TRISO particles applied in this study was assumed. - Abstract: The thermal conductivity of SiC ceramics and FCM fuel composites, consisting of a SiC matrix and TRISO coated particles, was measured and analyzed. SiC ceramics and FCM pellets were fabricated by hot press sintering with Al_2O_3 and Y_2O_3 sintering additives. Several factors that influence thermal conductivity, specifically the content of sintering additives for SiC ceramics and the volume fraction of TRISO particles and the matrix thermal conductivity of FCM pellets, were investigated. The thermal conductivity values of samples were analyzed on the basis of their microstructure and the arrangement of TRISO particles. The thermal conductivity of the FCM pellets was compared to that predicted by the Maxwell-Eucken equation and the thermal conductivity of TRISO coated particles was calculated. The thermal conductivity of FCM pellets in various sintering conditions was in close agreement to that predicted by the Maxwell-Eucken equation with the fitted thermal conductivity value of TRISO particles.

  10. Fuel-cladding mechanical interaction effects in fast reactor mixed oxide fuel

    Energy Technology Data Exchange (ETDEWEB)

    Boltax, A [Westinghouse Electric Corporation, Advanced Reactor Division, Madison, PA (United States); Biancheria, A

    1977-04-01

    Thermal and fast reactor irradiation experiments on mixed oxide fuel pins under steady-state and power change conditions reveal evidence for significant fuel-cladding mechanical interaction (FCMI) effects. Analytical studies with the LIFE-III fuel performance code indicate that high cladding stresses can be produced by general and local FCMI effects. Also, evidence is presented to show that local cladding strains can be caused by the accumulation of cesium at the fuel-cladding interface. Although it is apparent that steady-state FCMI effects have not given rise to cladding breaches in current fast reactors, it is anticipated that FCMI may become more important in the future because of interest in: higher fuel burnups; increased power ramp rates; load follow operation; and low swelling cladding alloys. (author)

  11. Fuel-cladding mechanical interaction effects in fast reactor mixed oxide fuel

    International Nuclear Information System (INIS)

    Boltax, A.; Biancheria, A.

    1977-01-01

    Thermal and fast reactor irradiation experiments on mixed oxide fuel pins under steady-state and power change conditions reveal evidence for significant fuel-cladding mechanical interaction (FCMI) effects. Analytical studies with the LIFE-III fuel performance code indicate that high cladding stresses can be produced by general and local FCMI effects. Also, evidence is presented to show that local cladding strains can be caused by the accumulation of cesium at the fuel-cladding interface. Although it is apparent that steady-state FCMI effects have not given rise to cladding breaches in current fast reactors, it is anticipated that FCMI may become more important in the future because of interest in: higher fuel burnups; increased power ramp rates; load follow operation; and low swelling cladding alloys. (author)

  12. Fabrication and thermophysical property characterization of UN/U3Si2 composite fuel forms

    Science.gov (United States)

    White, J. T.; Travis, A. W.; Dunwoody, J. T.; Nelson, A. T.

    2017-11-01

    High uranium density composite fuels composed of UN and U3Si2 have been fabricated using a liquid phase sintering route at temperatures between 1873 K and 1973 K and spanning compositions of 10 vol% to 40 vol% U3Si2. Microstructural analysis and phase characterization revealed the formation of an U-Si-N phase of unknown structure. Microcracking was observed in the U-Si portion of the composite microstructure that likely originates from the mismatched coefficient of thermal expansion between the UN and U3Si2 leading to stresses on heating and cooling of the composite. Thermal expansion coefficient, thermal diffusivity, and thermal conductivity were characterized for each of the compositions as a function of temperature to 1673 K. Hysteresis is observed in the thermal diffusivity for the 20 vol% through 40 vol% specimens between room temperature and 1273 K, which is attributed to the microcracking in the U-Si phase. Thermal conductivity of the composites was modeled using the MOOSE framework based on the collected microstructure data. The impact of irradiation on thermal conductivity was also simulated for this class of composite materials.

  13. Cost effectiveness of transportation fuels from biomass

    International Nuclear Information System (INIS)

    De Jager, D.; Faaij, A.P.C.; Troelstra, W.P.

    1998-06-01

    The aim of the study on the title subject was to investigate whether stimulation of the production and use of biofuels for transportation is worthwhile compared to the production of electricity from biomass. Several options are compared to each other and with reference technologies on the basis of the consumption or the avoided input of fossil fuels, emissions of greenhouse gases, specific costs and cost effectiveness. For each phase in the biomass conversion process (cultivation, pretreatment, transportation, conversion, distribution and final consumption) indicators were collected from the literature. Next to costs of the bioconversion routes attention is paid to other relevant aspects that are important for the introduction of the technological options in the Netherlands. 41 refs

  14. Fluid Effects in Polymers and Polymeric Composites

    CERN Document Server

    Weitsman, Y Jack

    2012-01-01

    Fluid Effects in Polymers and Polymeric Composites, written by the late Dr. Y. Jack Weitsman, addresses the wide range of parameters that affect the interaction of fluids with polymers and polymeric composites. The book aims at broadening the scope of available data, mostly limited up to this time to weight-gain recordings of fluid ingress into polymers and composites, to the practical circumstances of fluctuating exposure. Various forms of experimental data are given, in conjunction with theoretical models derived from basic scientific principles, and correlated with severity of exposure conditions and interpreted by means of rationally based theoretical models. The practical implications of the effects of fluids are discussed. The issue of fluid effects on polymers and polymeric composites is of concern to engineers and scientists active in aerospace and naval structures, as an increasing portion of these structures are made of polymeric composites and employ polymeric adhesives as a joining device. While...

  15. Environmental effects of fossil fuel combustion

    International Nuclear Information System (INIS)

    Chmielewski, A.G.

    1999-01-01

    Fossil fuel which include natural gas, petroleum, shale oil and bitumen are the main source of heat and electrical energy. All these fuels contain beside major constituents (carbon, hydrogen, oxygen) other materials as metal, sulfur and nitrogen compounds. During the combustion process different pollutants as fly ash, sulfur oxides (SO 2 and SO 3 ), nitrogen oxides (NO x NO + NO 2 ) and volatile organic compounds are emitted. Fly ash contain different trace elements (heavy metals). Gross emission of pollutants is tremendous all over the world. These pollutants are present in the atmosphere in such conditions that they can affect man and his environment. Air pollution caused by the particulate matter and other pollutants not only acts directly on environment but by contamination of water and soil leads to their degradation. Wet and dry deposition of inorganic pollutants leads to acidification of environment. These phenomena affect health of the people, increase corrosion, destroy cultivated soil and forests. Most of the plants, especially coniferous trees are not resistant to sulfur and nitrogen oxides. Following longer exposure leaves wither and fall. Widespread forest damage has been reported in Europe and North America regions. Many cultivated plants are not resistant to these pollutants either especially in the early period vegetation. The mechanisms of pollutants transformation in atmosphere are described by environmental chemistry. An important role in these transformations plays photochemistry. SO 2 and NO x are oxidized and sulfuric and nitric acids are formed in presence of water vapours, fog and droplets. Other problem discussed connected with human activities is emission of volatile organic compounds to the atmosphere. These emissions cause stratospheric ozone depletion, ground level photochemical ozone formation, toxic or carcinogenic human health effects, enhancing the global greenhouse effect, accumulation and persistence in environment. Wet flue gas

  16. Environmental effects of fossil fuel combustion

    Energy Technology Data Exchange (ETDEWEB)

    Chmielewski, A G

    1999-07-01

    Fossil fuel which include natural gas, petroleum, shale oil and bitumen are the main source of heat and electrical energy. All these fuels contain beside major constituents (carbon, hydrogen, oxygen) other materials as metal, sulfur and nitrogen compounds. During the combustion process different pollutants as fly ash, sulfur oxides (SO{sub 2} and SO{sub 3}), nitrogen oxides (NO{sub x} NO + NO{sub 2}) and volatile organic compounds are emitted. Fly ash contain different trace elements (heavy metals). Gross emission of pollutants is tremendous all over the world. These pollutants are present in the atmosphere in such conditions that they can affect man and his environment. Air pollution caused by the particulate matter and other pollutants not only acts directly on environment but by contamination of water and soil leads to their degradation. Wet and dry deposition of inorganic pollutants leads to acidification of environment. These phenomena affect health of the people, increase corrosion, destroy cultivated soil and forests. Most of the plants, especially coniferous trees are not resistant to sulfur and nitrogen oxides. Following longer exposure leaves wither and fall. Widespread forest damage has been reported in Europe and North America regions. Many cultivated plants are not resistant to these pollutants either especially in the early period vegetation. The mechanisms of pollutants transformation in atmosphere are described by environmental chemistry. An important role in these transformations plays photochemistry. SO{sub 2} and NO{sub x} are oxidized and sulfuric and nitric acids are formed in presence of water vapours, fog and droplets. Other problem discussed connected with human activities is emission of volatile organic compounds to the atmosphere. These emissions cause stratospheric ozone depletion, ground level photochemical ozone formation, toxic or carcinogenic human health effects, enhancing the global greenhouse effect, accumulation and persistence in

  17. A study on the criticality search of transuranium recycling BWR core by adjusting supplied fuel composition in equilibrium state

    International Nuclear Information System (INIS)

    Seino, Takeshi; Sekimoto, Hiroshi

    1998-01-01

    There have been some difficulties in carrying out an extensive evaluation of the equilibrium state of Light Water Reactor (LWR) recycling operations keeping their fixed criticality condition using conventional design codes because of the complexity of their calculation model for practical fuel and core design and because of a large amount of calculation time. This study presents an efficient approach to secure the criticality in an equilibrium cycle by adjusting a supplied fuel composition. The criticality search is performed by the use of fuel importance obtained from the equation adjoint to a continuously fuel supplied core burnup equation. Using this method, some numerical analyses were carried out in order to evaluate the mixed oxide (MOX) fuel composition of equilibrium Boiling Water Reactor (BWR) cores satisfying the criticality requirement. The results showed the comprehensive and quantitative characteristics on the equilibrium cores confining transuraniums for different MOX fuel loading fractions and irradiating conditions

  18. A study on the criticality search of transuranium recycling BWR core by adjusting supplied fuel composition in equilibrium state

    International Nuclear Information System (INIS)

    Seino, Takeshi; Sekimoto, Hiroshi

    1997-01-01

    There have been some difficulties in carrying out an extensive evaluation of the equilibrium state of Light Water Reactor (LWR) recycling operations keeping their fixed criticality condition using conventional design codes, because of the complexity of their calculational model for practical fuel and core design and because of a large amount of calculation time. This study presents an efficient approach to secure the criticality in an equilibrium cycle by adjusting a supplied fuel composition. The criticality search is performed by the use of fuel importance obtained from the equilibrium adjoint to a continuously fuel supplied core burnup equation. Using this method, some numerical analyses were carried out in order to evaluate the mixed oxide (MOX) fuel composition of equilibrium Boiling Water Reactor (BWR) cores satisfying the criticality requirement. The results showed the comprehensive and quantitative characteristics on the equilibrium cores confining transuranium for different MOX fuel loading fractions and irradiating conditions. (author)

  19. Fuel morphology effects on fission product release

    International Nuclear Information System (INIS)

    Osetek, D.J.; Hartwell, J.K.; Cronenberg, A.W.

    1986-01-01

    Results are presented of fission product release behavior observed during four severe fuel damage tests on bundles of UO 2 fuel rods. Transient temperatures up to fuel melting were obtained in the tests that included both rapid and slow cooldown, low and high (36 GWd/t) burnup fuel and the addition of Ag-In-Cd control rods. Release fractions of major fission product species and release rates of noble gas species are reported. Significant differences in release behavior are discussed between heatup and cooldown periods, low and high burnup fuel and long- and short-lived fission products. Explanations for the observed differences are offered that relate fuel morphology changes to the releases

  20. Effects of Transverse Power Distribution on Fuel Temperature

    International Nuclear Information System (INIS)

    Jo, Daeseong; Park, Jonghark; Seo, Chul Gyo; Chae, Heetaek

    2014-01-01

    In the present study, transverse power distributions with segments of 4 and 18 are evaluated. Based on the power distribution, the fuel temperatures are evaluated with a consideration of lateral heat conduction. In the present study, the effect of the transverse power distribution on the fuel temperature is investigated. The transverse power distributions with variation of fuel segment number are evaluated. The maximum power peaking with 12 segments is higher than that with 4 segments. Based on the calculation, 6-order polynomial is generated to express the transverse power distributions. The maximum power peaking factor increases with segments. The averaged power peaking is 2.10, and the maximum power peaking with 18 segments is 2.80. With the uniform power distribution, the maximum fuel temperature is found in the middle of the fuel. As the power near the side ends of the fuel increases, the maximum fuel temperature is found near the side ends. However, the maximum fuel temperature is not found where the maximum transverse power is. This is because the high power locally released from the edge of the fuel is laterally conducted to the cladding. As a result of the present study, it can be concluded that the effect of the high power peaking at the edge of the fuel on the fuel outer wall temperature is not significant

  1. Porous Composite for Bipolar Plate in Low Emission Hydrogen Fuel Cells

    Directory of Open Access Journals (Sweden)

    Renata Katarzyna Włodarczyk

    2018-01-01

    Full Text Available The paper presents the results of graphite-stainless steel composites for the bipolar plates in low-temperature fuel cells. The sinters were performed by powder metallurgy technology. The influenceof technological parameters, especially molding pressure were examined. Following the requirements formulated by the DOE concerning the parameters of the materials, it indicated by the value of the parameters. The density, flowabilit, particle size of graphite and stainless steel powders have been evaluated. Composites have been tested by microstructure and phase analysis, properties of strength, functional properties: wettability, porosity, roughness. The special attention was paid to the analysis of corrosion resistance obtained sinters and influenceof technological parameters on the corrosion. Corrosion tests were carried out under conditions simulating the environment of the fuel cell under anode and cathode conditions. The effectof pH solution during working of the cell on corrosion resistance of composites have been evaluated. Contact resistance depends on roughness of sinters. Low ICR determined high contact area GDL-BP and high electrical conductivity on the contact surface. The ICR in anode conditions after corrosion tests are not change significantly; composite materials can be used for materials for B in terms of H 2 .

  2. Composite cathode materials development for intermediate temperature solid oxide fuel cell systems

    Science.gov (United States)

    Qin, Ya

    Solid oxide fuel cell (SOFC) systems are of particular interest as electrochemical power systems that can operate on various hydrocarbon fuels with high fuel-to-electrical energy conversion efficiency. Within the SOFC stack, La0.8Sr 0.2Ga0.8Mg0.115Co0.085O3-delta (LSGMC) has been reported as an optimized composition of lanthanum gallate based electrolytes to achieve higher oxygen ionic conductivity at intermediate temperatures, i.e., 500-700°C. The electrocatalytic properties of interfaces between LSGMC electrolytes and various candidate intermediate-temperature SOFC cathodes have been investigated. Sm0.5Sr0.5CoO 3-delta (SSC), and La0.6Sr0.4Co0.2Fe 0.8O3-delta (LSCF), in both pure and composite forms with LSGMC, were investigated with regards to both oxygen reduction and evolution, A range of composite cathode compositions, having ratios of SSC (in wt.%) with LSGMC (wt.%) spanning the compositions 9:1, 8:2, 7:3, 6:4 and 5:5, were investigated to determine the optimal cathode-electrolyte interface performance at intermediate temperatures. All LSGMC electrolyte and cathode powders were synthesized using the glycine-nitrate process (GNP). Symmetrical electrochemical cells were investigated with three-electrode linear dc polarization and ac impedance spectroscopy to characterize the kinetics of the interfacial reactions in detail. Composite cathodes were found to perform better than the single phase cathodes due to significantly reduced polarization resistances. Among those composite SSC-LSGMC cathodes, the 7:3 composition has demonstrated the highest current density at the equivalent overpotential values, indicating that 7:3 is an optimal mixing ratio of the composite cathode materials to achieve the best performance. For the composite SC-LSGMC cathode/LSGMC interface, the cathodic overpotential under 1 A/cm2 current density was as low as 0.085 V at 700°C, 0.062V at 750°C and 0.051V at 800°C in air. Composite LSCF-LSGMC cathode/LSGMC interfaces were found to have

  3. Gas composition modeling in a reformed Methanol Fuel Cell system using adaptive Neuro-Fuzzy Inference Systems

    DEFF Research Database (Denmark)

    Justesen, Kristian Kjær; Andreasen, Søren Juhl; Shaker, Hamid Reza

    2013-01-01

    This work presents a method for modeling the gas composition in a Reformed Methanol Fuel Cell system. The method is based on Adaptive Neuro-Fuzzy-Inference-Systems which are trained on experimental data. The developed models are of the H2, CO2, CO and CH3OH mass flows of the reformed gas. The ANFIS......, or fuel cell diagnostics systems....

  4. A fundamental investigation into the relationship between lubricant composition and fuel ignition quality

    KAUST Repository

    Kuti, Olawole Abiola

    2015-11-01

    A fundamental experiment involving the use of an ignition quality tester (IQT) was carried out to elucidate the effects of lubricant oil composition which could lead to low speed pre-ignition (LSPI) processes in direct injection spark ignition (DISI) engines. Prior to the IQT tests, lubricant base oils were analyzed using ultra-high resolution mass spectrometry to reveal their molecular composition. High molecular-weight hydrocarbons such as nC16H34, nC17H36, and nC18H38 were selected as surrogates of lubricant base oil constituents, and then mixed with iso-octane (iC8H18-gasoline surrogate) in proportions of 1 vol.% (iC8H18 = 99 vol.%) and 10 vol.% (iC8H18 = 90 vol.%) for the IQT experiments. In addition, lubricant base oils such as SN100 (Group I) and HC4 and HC6 (Group III) and a fully formulated lubricant (SAE 20W50) were mixed with iso-octane in the same proportions. The IQT results were conducted at an ambient pressure of 15 bar and a temperature range of 680-873 K. In the temperature range of 710-850 K, the addition of 10 vol.% base oils surrogates, base oils, and lubricating oil to the 90 vol.% iC8H18 reduces the average total ignition delay time by up to 54% for all mixtures, while the addition of 1 vol.% to 99 vol.% iC8H18 yielded a 7% reduction within the same temperature range. The shorter total ignition delay was attributed to the higher reactivity of the lubricant base oil constituents in the fuel mixtures. A correlation between reactivity of base oils and their molecular composition was tentatively established. These results suggest that the lubricants have the propensity of initiating LSPI in DISI engines. Furthermore, similar results for n-alkanes, lubricant base oils, and fully formulated commercial lubricants suggest that it is the hydrocarbon fraction that contributes primarily to enhanced reactivity, and not the inorganic or organometallic additives. © 2015 Elsevier Ltd. All rights reserved.

  5. A fundamental investigation into the relationship between lubricant composition and fuel ignition quality

    KAUST Repository

    Kuti, Olawole Abiola; Yang, Seung Yeon; Hourani, Nadim; Naser, Nimal; Roberts, William L.; Chung, Suk-Ho; Sarathy, Mani

    2015-01-01

    A fundamental experiment involving the use of an ignition quality tester (IQT) was carried out to elucidate the effects of lubricant oil composition which could lead to low speed pre-ignition (LSPI) processes in direct injection spark ignition (DISI) engines. Prior to the IQT tests, lubricant base oils were analyzed using ultra-high resolution mass spectrometry to reveal their molecular composition. High molecular-weight hydrocarbons such as nC16H34, nC17H36, and nC18H38 were selected as surrogates of lubricant base oil constituents, and then mixed with iso-octane (iC8H18-gasoline surrogate) in proportions of 1 vol.% (iC8H18 = 99 vol.%) and 10 vol.% (iC8H18 = 90 vol.%) for the IQT experiments. In addition, lubricant base oils such as SN100 (Group I) and HC4 and HC6 (Group III) and a fully formulated lubricant (SAE 20W50) were mixed with iso-octane in the same proportions. The IQT results were conducted at an ambient pressure of 15 bar and a temperature range of 680-873 K. In the temperature range of 710-850 K, the addition of 10 vol.% base oils surrogates, base oils, and lubricating oil to the 90 vol.% iC8H18 reduces the average total ignition delay time by up to 54% for all mixtures, while the addition of 1 vol.% to 99 vol.% iC8H18 yielded a 7% reduction within the same temperature range. The shorter total ignition delay was attributed to the higher reactivity of the lubricant base oil constituents in the fuel mixtures. A correlation between reactivity of base oils and their molecular composition was tentatively established. These results suggest that the lubricants have the propensity of initiating LSPI in DISI engines. Furthermore, similar results for n-alkanes, lubricant base oils, and fully formulated commercial lubricants suggest that it is the hydrocarbon fraction that contributes primarily to enhanced reactivity, and not the inorganic or organometallic additives. © 2015 Elsevier Ltd. All rights reserved.

  6. Indirect Determination of Chemical Composition and Fuel Characteristics of Solid Waste

    DEFF Research Database (Denmark)

    Riber, Christian; Christensen, Thomas Højlund

    Determination of chemical composition of solid waste can be performed directly or indirectly by analysis of combustion products. The indirect methodology instrumented by a full scale incinerator is the only method that can conclude on elements in trace concentrations. These elements are of great...... interest in evaluating waste management options by for example LCA modeling. A methodology description of indirect determination of chemical composition and fuel properties of waste is provided and validated by examples. Indirect analysis of different waste types shows that the chemical composition...... is significantly dependent on waste type. And the analysis concludes that the transfer of substances in the incinerator is a function of waste chemical content, incinerator technology and waste physical properties. The importance of correct representation of rare items in the waste with high concentrations...

  7. Spent fuel composition database system on WWW. SFCOMPO on WWW Ver.2

    Energy Technology Data Exchange (ETDEWEB)

    Mochizuki, Hiroki [Japan Research Institute, Ltd., Tokyo (Japan); Suyama, Kenya; Nomura, Yasushi; Okuno, Hiroshi [Japan Atomic Energy Research Inst., Tokai, Ibaraki (Japan). Tokai Research Establishment

    2001-08-01

    'SFCOMPO on WWW Ver.2' is an advanced version of 'SFCOMPO on WWW' ('Spent Fuel Composition Database System on WWW') released in 1997. This new version has a function of database management by an introduced relational database software 'PostgreSQL' and has various searching methods. All of the data required for the calculation of isotopic composition is available from the web site of this system. This report describes the outline of this system and the searching method using Internet. In addition, the isotopic composition data and the reactor data of the 14 LWRs (7 PWR and 7 BWR) registered in this system are described. (author)

  8. Effect of long-term storage of LWR spent fuel on Pu-thermal fuel cycle

    International Nuclear Information System (INIS)

    Kurosawa, Masayoshi; Naito, Yoshitaka; Suyama, Kenya; Itahara, Kuniyuki; Suzuki, Katsuo; Hamada, Koji

    1998-01-01

    According to the Long-term Program for Research, Development and Utilization of Nuclear Energy (June, 1994) in Japan, the Rokkasho Reprocessing Plant will be operated shortly after the year 2000, and the planning of the construction of the second commercial plant will be decided around 2010. Also, it is described that spent fuel storage has a positive meaning as an energy resource for the future utilization of Pu. Considering the balance between the increase of spent fuels and the domestic reprocessing capacity in Japan, it can be expected that the long-term storage of UO 2 spent fuels will be required. Then, we studied the effect of long-term storage of spent fuels on Pu-thermal fuel cycle. The burnup calculation were performed on the typical Japanese PWR fuel, and the burnup and criticality calculations were carried out on the Pu-thermal cores with MOX fuel. Based on the results, we evaluate the influence of extending the spent fuel storage term on the criticality safety, shielding design of the reprocessing plant and the core life time of the MOX core, etc. As the result of this work on long-term storage of LWR spent fuels, it becomes clear that there are few demerits regarding the lifetime of a MOX reactor core, and that there are many merits regarding the safety aspects of the fuel cycle facilities. Furthermore, long-term storage is meaningful as energy storage for effective utilization of Pu to be improved by technological innovation in future, and it will allow for sufficient time for the important policymaking of nuclear fuel cycle establishment in Japan. (author)

  9. The effect of copper, MDA, and accelerated aging on jet fuel thermal stability as measured by the gravimetric JFTOT

    Energy Technology Data Exchange (ETDEWEB)

    Pande, S.G. [Geo-Centers, Inc., Ft. Washington, MD (United States); Hardy, D.R. [Navy Technology Center for Safety and Survivability, Washington, DC (United States)

    1995-05-01

    Thermally unstable jet fuels pose operational problems. In order to adequately identify such fuels, factors that realistically impact on thermal stability were examined. Evaluation was based on a quantitative method of measuring thermal stability, viz., NRL`s recently developed gravimetric JFTOT. This method gives a quantitative measurement of both the strip deposit and filterables formed. The pertinent factors examined, included the individual and interactive effects of: soluble copper, MDA (metal deactivator), and aging. The latter was accelerated to simulate field conditions of approximately six months aging at ambient temperature and pressure. The results indicate that the individual and interactive effects of copper, MDA, and accelerated aging appear to be fuel dependent. Based on the results, the three test fuels examined (one JP-8 and two JP-5s) were categorized as exhibiting very good, typical, and poor thermal stabilities, respectively. For both the very good and poor thermal stability fuels, the effect of copper in conjunction with accelerated aging did not significantly increase the total thermal deposits of the neat fuels. In contrast, for the typical thermal stability fuel, the combined effects of copper and accelerated aging, did. Furthermore, the addition of MDA prior to aging of the copper-doped, typical stability fuel significantly counteracted the adverse effect of copper and aging. A similar beneficial effect of MDA was not observed for the poor stability fuel. These results focus on the compositional differences among fuels and the need to elucidate these differences (physical and chemical) for a better understanding and prediction of their performance.

  10. Nanocarbon/oxide composite catalysts for bifunctional oxygen reduction and evolution in reversible alkaline fuel cells: A mini review

    Science.gov (United States)

    Chen, Mengjie; Wang, Lei; Yang, Haipeng; Zhao, Shuai; Xu, Hui; Wu, Gang

    2018-01-01

    A reversible fuel cell (RFC), which integrates a fuel cell with an electrolyzer, is similar to a rechargeable battery. This technology lies on high-performance bifunctional catalysts for the oxygen reduction reaction (ORR) in the fuel cell mode and the oxygen evolution reaction (OER) in the electrolyzer mode. Current catalysts are platinum group metals (PGM) such as Pt and Ir, which are expensive and scarce. Therefore, it is highly desirable to develop PGM-free catalysts for large-scale application of RFCs. In this mini review, we discussed the most promising nanocarbon/oxide composite catalysts for ORR/OER bifunctional catalysis in alkaline media, which is mainly based on our recent progress. Starting with the effectiveness of selected oxides and nanocarbons in terms of their activity and stability, we outlined synthetic methods and the resulting structures and morphologies of catalysts to provide a correlation between synthesis, structure, and property. A special emphasis is put on understanding of the possible synergistic effect between oxide and nanocarbon for enhanced performance. Finally, a few nanocomposite catalysts are discussed as typical examples to elucidate the rules of designing highly active and durable bifunctional catalysts for RFC applications.

  11. Reactivity effect of spent fuel depending on burn-up history

    International Nuclear Information System (INIS)

    Hayashi, Takafumi; Suyama, Kenya; Nomura, Yasushi

    2001-06-01

    It is well known that a composition of spent fuel depends on various parameter changes throughout a burn-up period. In this study we aimed at the boron concentration and its change, the coolant temperature and its spatial distribution, the specific power, the operation mode, and the duration of inspection, because the effects due to these parameters have not been analyzed in detail. The composition changes of spent fuel were calculated by using the burn-up code SWAT, when the parameters mentioned above varied in the range of actual variations. Moreover, to estimate the reactivity effect caused by the composition changes, the criticality calculations for an infinite array of spent fuel were carried out with computer codes SRAC95 or MVP. In this report the reactivity effects were arranged from the viewpoint of what parameters gave more positive reactivity effect. The results obtained through this study are useful to choose the burn-up calculation model when we take account of the burn-up credit in the spent fuel management. (author)

  12. Estimation of PWR spent fuel composition using SCALE and SWAT code systems

    Energy Technology Data Exchange (ETDEWEB)

    Shin, Hee Sung [Korea Atomic Energy Research Institute, Taejon (Korea, Republic of); Kenya, Suyama; Hiroshi, Okuno [Japan Atomic Energy Research Institute, Tokyo (Japan)

    2001-05-01

    The isotopic composition calculations were performed for 26 spent fuel samples from Obrigheim PWR reactor and 55 spent fuel samples from 7 PWR reactors using SCALE4.4 SAS2H with 27, 44 and 238 group cross-section libraries and SWAT with 107 group cross-section library. For convenience, the ratio of the measured to calculated value was used as a parameter. The four kinds of the calculation results were compared with the measured data. For many important nuclides for burnup credit criticality safety evaluation, the four methods applied in this study showed good coincidence with measurements in general. More precise observations showed the following results. Less unity ratios were found for Pu-239 and -241 for selected 16 samples out of the 26 samples from Obrigheim reactor. Larger than unity ratios were found for Am-241 for both the 16 and 55 samples. Larger than unity ratios were found for Sm-149 for the 55 samples. In the case of 26 sample SWAT was generally accompanied by larger ratios than those of SAS2H with some exceptions. Based on the measured-to-calculated ratios for 71 samples of a combined set in which 16 selected samples and 55 samples were included, the correction factors that should be multiplied to the calculated isotopic compositions were generated for a conservative estimate of the neutron multiplication factor of a system containing PWR spent fuel, taking burnup credit into account.

  13. Composite fermions in the quantum Hall effect

    International Nuclear Information System (INIS)

    Johnson, B.L.; Kirczenow, G.

    1997-01-01

    The quantum Hall effect and associated quantum transport phenomena in low-dimensional systems have been the focus of much attention for more than a decade. Recent theoretical development of interesting quasiparticles - 'composite fermions' - has led to significant advances in understanding and predicting the behaviour of two-dimensional electron systems under high transverse magnetic fields. Composite fermions may be viewed as fermions carrying attached (fictitious) magnetic flux. Here we review models of the integer and fractional quantum Hall effects, including the development of a unified picture of the integer and fractional effects based upon composite fermions. The composite fermion picture predicts remarkable new physics: the formation of a Fermi surface at high magnetic fields, and anomalous ballistic transport, thermopower, and surface acoustic wave behaviour. The specific theoretical predictions of the model, as well as the body of experimental evidence for these phenomena are reviewed. We also review recent edge-state models for magnetotransport in low-dimensional devices based on the composite fermion picture. These models explain the fractional quantum Hall effect and transport phenomena in nanoscale devices in a unified framework that also includes edge state models of the integer quantum Hall effect. The features of the composite fermion edge-state model are compared and contrasted with those of other recent edge-state models of the fractional quantum Hall effect. (author)

  14. Experiments to investigate the effects of small changes in fuel stoichiometry on fission gas release

    Energy Technology Data Exchange (ETDEWEB)

    Copeland, P S; Smith, R C [Windscale Lab., AEA Technology, Seascale, Cumbria (United Kingdom)

    1997-08-01

    Fuel pin failure in-reactor leads to fission product and in the case of a PWR fuel debris release to the coolant. For economic reasons immediate shutdown and discharge of failed fuel needs to be avoided but this needs to be counter-balanced against the increasing dose to operators. PWR practice is to continue running wit failed rods, monitoring coolant activity, and only shutting down the reactor and discharging the fuel when circuit activity levels become unacceptable. The rate of fission product release under failed fuel conditions is of key importance and considerable effort has been directed towards establishing the dependency of release on temperature, heating rate, burn-up, and also the extent of fuel oxidation. As a precursor to a possible wider investigation of this area, a small programme was mounted during 1992/1993 to confirm whether small changes in the oxidation state of the fuel, for example those caused by minor cladding defects, would significantly effect fuel behaviour during postulated design basis faults. The objective of the programme was to determine the effects of small departures from stoichiometric fuel composition on fission gas release, and to compare the results with the current methodology for calculating releases under fault conditions. A total of eight experiments was performed. Two were intended as baseline tests to provide a reference with which to compare the effect of oxidation state influenced behaviour with that of thermal effects. It was found that small changes in stoichiometry of {sup {approx}}1 x 10{sup -6} had little or no effect on release but that changes of {sup {approx}} 1 x 10{sup -4} were observed to increase the diffusion coefficient, for {sup 85}Kr, by up to an order of magnitude and hence greatly increase the release rate. The stoichiometry of the sample used in these tests was, for convenience, adjusted using He/H{sub 2}/H{sub 2}O atmospheres. (Abstract Truncated)

  15. Effects of salvage logging and pile-and-burn on fuel loading, potential fire behaviour, fuel consumption and emissions

    Science.gov (United States)

    Morris C. Johnson; Jessica E. Halofsky; David L. Peterson

    2013-01-01

    We used a combination of field measurements and simulation modelling to quantify the effects of salvage logging, and a combination of salvage logging and pile-and-burn fuel surface fuel treatment (treatment combination), on fuel loadings, fire behaviour, fuel consumption and pollutant emissions at three points in time: post-windstorm (before salvage logging), post-...

  16. Effects of UO2 fuel microstructure and density on fuel in-reactor performance

    International Nuclear Information System (INIS)

    Hansson, L.

    1988-02-01

    The volume changes of UO 2 fuel pellets, produced by neutron irradiation, can be characterized by two processes: fission spike induced densification through pore skrinkage and later fission produced induced swelling of UO 2 matrix. In-pile densification is controlled by the initial density and microstructure of the fuel, particularly by the pore size distribution. The extent of swelling depends mainly on the amount of fission products produced, but the fission gas release as well as the swelling may be reduced by increasing the grain size of UO 2 . Fabrication of fuel pellets having certain in-reactor properties requires detailed knowledge of the effects of individual fabrication parameters. The irradiation experience of fuels fabricated by using different conversion and pelletizing methods is extensive. Based on this experience, some general characteristics of stable/well-performing fuel microstructures have been summarized

  17. Final Scientific Report, New Proton Conductive Composite Materials for PEM Fuel Cells

    Energy Technology Data Exchange (ETDEWEB)

    Lvov, Serguei

    2010-11-08

    This project covered one of the main challenges in present-day PEM fuel cell technology: to design a membrane capable of maintaining high conductivity and mechanical integrity when temperature is elevated and water vapor pressure is severely reduced. The DOE conductivity milestone of 0.1 S cm-1 at 120 degrees C and 50 % relative humidity (RH) for designed membranes addressed the target for the project. Our approach presumed to develop a composite membrane with hydrophilic proton-conductive inorganic material and the proton conductive polymeric matrix that is able to “bridge” the conduction paths in the membrane. The unique aspect of our approach was the use of highly functionalized inorganic additives to benefit from their water retention properties and high conductivity as well. A promising result turns out that highly hydrophilic phosphorsilicate gels added in Nafion matrix improved PEM fuel cell performance by over 50% compared with bare Nafion membrane at 120 degrees C and 50 % RH. This achievement realizes that the fuel cell operating pressure can be kept low, which would make the PEM fuel cell much more cost efficient and adaptable to practical operating conditions and facilitate its faster commercialization particularly in automotive and stationary applications.

  18. Modelling the bending/bowing of composite beams such as nuclear fuel

    International Nuclear Information System (INIS)

    Tayal, M.

    1989-01-01

    Arrays of tubes are used in many engineered structures, such as in nuclear fuel bundles and in steam generators. The tubes can bend (bow) due to in-service temperatures and loads. Assessments of bowing of nuclear fuel elements can help demonstrate the integrity of fuel and of surrounding components, as a function of operating conditions such as channel power. The BOW code calculates the bending of composite beams such as fuel elements, due to gradients of temperature and due to hydraulic forces. The deflections and rotations are calculated in both lateral directions, for given conditions of temperatures. Wet and dry operation of the sheath can be simulated. BOW accounts for the following physical phenomena: circumferential and axial variations in the temperatures of the sheath and of the pellet; cracking of pellets; grip and slip between the pellets and the sheath; hydraulic drag; restraint from endplates, from neighbouring elements, and from the pressure-tube; gravity; concentric or eccentric welds between endcaps and endplate; neutron flux gradients; and variations of material properties with temperature. The code is based on fundamental principles of mechanics. The governing equations are solved numerically using the finite element method. Several comparisons with closed-form equations shoe that the solutions of BOW are accurate. BOW's predictions for initial in-reactor bow are also consistent with two post-irradiation measurements

  19. Release to the Gas Phase of Inorganic Elements during Wood Combustion. Part 2: Influence of Fuel Composition

    DEFF Research Database (Denmark)

    van Lith, Simone Cornelia; Jensen, Peter Arendt; Frandsen, Flemming

    2008-01-01

    temperatures in the range of 500–1150 °C in a laboratory-scale tube reactor and by performing mass balance calculations based on the weight measurements and chemical analyses of the wood fuels and the residual ash samples. Four wood fuels with different ash contents and inorganic compositions were investigated...... of the alkali metals K and Na was, however, strongly dependent on both the temperature and the fuel composition under the investigated conditions. The release of the heavy metals Zn and Pb started around 500 °C and increased sharply to more than 85% at 850 °C in the case of spruce, beech, and bark...

  20. First results on the effect of fuel-cladding eccentricity

    International Nuclear Information System (INIS)

    Panka, I.; Kereszturi, A.

    2009-01-01

    In the traditional fuel-behaviour or hot channel calculations it is assumed that the fuel pellet is centered within the clad. However, in the real life the pellet could be positioned asymmetrically within the clad, which leads to asymmetric gap conductance and therefore it is worthwhile to investigate the magnitude of the effect on maximal fuel temperature and surface heat flux. In this paper our first experiences are presented on this topic. (Authors)

  1. Emission Control Cost-Effectiveness of Alternative-Fuel Vehicles

    OpenAIRE

    Wang, Quanlu; Sperling, Daniel; Olmstead, Janis

    1993-01-01

    Although various legislation and regulations have been adopted to promote the use of alternative-fuel vehicles for curbing urban air pollution problems, there is a lack of systematic comparisons of emission control cost-effectiveness among various alternative-fuel vehicle types. In this paper, life-cycle emission reductions and life-cycle costs were estimated for passenger cars fueled with methanol, ethanol, liquified petroleum gas, compressed natural gas, and electricity. Vehicle emission es...

  2. Effects of Fuel Type and Fuel Delivery System on Pollutant Emissions of Pride and Samand Vehicles

    Directory of Open Access Journals (Sweden)

    Akbar Sarhadi

    2017-04-01

    Full Text Available This research was aimed to study the effect of the type of fuel delivery system (petrol, dedicated or bifuel, the type of consumed fuel (petrol or gas, the portion of consumed fuel and also the duration of dual-fuelling in producing carbon monoxide, carbon dioxide and unburned hydrocarbons from Pride and Samand. According to research objectives, data gathering from 2000 vehicles has been done by visiting Hafiz Vehicle Inspection Center every day for 2 months. The results of this survey indicated that although there is no significant difference between various fuel delivery systems in terms of producing the carbon monoxide, carbon dioxide and unburned hydrocarbons by Samand, considering the emission amount of carbon dioxide, the engine performance of Pride in bifuel and dedicated state in GTXI and 132 types is more unsatisfactory than that of petrol state by 0.3 and 0.4%, respectively. On the other hand, consuming natural gas increases the amount of carbon monoxide emission in dual- fuel Pride by 0.18% and decreases that in dual-fuel Samand by 1.2%, which signifies the better design of Samand in terms of fuel pumps, used kit type and other engine parts to use this alternative fuel compared to Pride. Since the portion of consumed fuel and also duration of dual-fuelling does not have a significant effect on the amount of output pollutants from the studied vehicles, it can be claimed that the output substances from the vehicle exhaust are more related to the vehicle’s condition than the fuel type.

  3. Microstructural characterization of composite cobaltite and lanthanum-based ceria for use as fuel cell cathodes

    International Nuclear Information System (INIS)

    Rodrigues, E.R.T.; Nascimento, R.M.; Miranda, A.C. de; Lima, A.M. de; Macedo, D.A.

    2016-01-01

    Fuel cells are devices that convert chemical energy into electricity via redox reactions. In this work, the lanthanum cobaltite doped with strontium and iron (La_0_,_6Sr_0_,_4Co_0_,_2Fe_0_,_8O_3 - LSCF) a traditional cathodes material of the fuel cell was mixed with an electrolyte material (composite) to the base ceria doped with gadolinia and a eutectic mixture of lithium carbonates and sodium (CGO-NLC). The powders of LSCF and CGO-NLC were obtained by the citrate method and mixed to obtain a composite cathode. Samples obtained by uniaxial pressure between 5 and 10 MPa were sintered at 1100°C and investigated by X-ray diffraction, scanning electron microscopy and micro hardness test. A symmetric cell cathode / electrolyte / cathode, obtained by co-pressing and co-sintering was investigated by electron microscopy. The results indicated that the composite is chemically stable up to the sintering temperature used. The hardness ranged between 51 and 227 HV. (author)

  4. Proton conductive montmorillonite-Nafion composite membranes for direct ethanol fuel cells

    International Nuclear Information System (INIS)

    Wu, Xiu-Wen; Wu, Nan; Shi, Chun-Qing; Zheng, Zhi-Yuan; Qi, Hong-Bin; Wang, Ya-Fang

    2016-01-01

    Highlights: • Composite membranes are prepared with different montmorillonites and nafion solution. • Proton conductivities of the composite membranes are between 36.0 mS/cm and 38.5 mS/cm. • Ethanol permeability is between 0.69 × 10"−"6 cm"2/s and 2.67 × 10"−"6 cm"2/s. • Water uptake is approximately 24.30 mass%. - Abstract: The preparation of Nafion membranes modified with montmorillonites is less studied, and most relative works mainly applied in direct methanol fuel cells, less in direct ethanol fuel cells. Organic/inorganic composite membranes are prepared with different montmorillonites (Ca-montmorillonite, Na-montmorillonite, K-montmorillonite, Mg-montmorillonite, and H-montmorillonite) and Nafion solution via casting method at 293 K in air, and with balance of their proton conductivity and ethanol permeability. The ethanol permeability and proton conductivity of the membranes are comparatively studied. The montmorillonites can well decrease the ethanol permeability of the membranes via inserted them in the membranes, while less decrease the proton conductivities of the membranes depending on the inserted amount and type of montmorillonites. The proton conductivities of the membranes are between 36.0 mS/cm and 38.5 mS/cm. The ethanol permeability of the membranes is between 0.69 × 10"−"6 cm"2/s and 2.67 × 10"−"6 cm"2/s.

  5. The evaluation of isotopic composition for TRIGA 14 MW spent fuel

    International Nuclear Information System (INIS)

    Covaci, St.; Toma, C.; Preda, M.

    2008-01-01

    In the summer of 1999 year, a first shipment of TRIGA HEU spent fuel to INEEL U.S.A. has taken place. he TRIGA HEU fuel was burned in the TRIGA steady state 14 MW reactor between 1980 and 1996 years. At the moment of prepared documentation for the shipment (July 1999), the evaluation of isotopic composition was calculated with ORIGEN-2 code with an irradiation history adequately prepared. Subsequently (May - June 2000), the evaluation was repeated with SAS2H module of SCALE 4.4a system. In the paper the results and the comparisons of the codes are presented, and the accuracy and convenient application of SCALE 4.4a system are emphasized. (authors)

  6. Reactivity effect of non-uniformly distributed fuel in fuel solution systems

    International Nuclear Information System (INIS)

    Hirano, Yasushi; Yamane, Yoshihiro; Nishina, Kojiro; Mitsuhashi, Ishi.

    1991-01-01

    A numerical method to determine the optimal fuel distribution for minimum critical mass, or maximum k-effective, is developed using the Maximum Principle in order to evaluate the maximum effect of non-uniformly distributed fuel on reactivity. This algorithm maximizes the Hamiltonian directly by an iterative method under a certain constraint-the maintenance of criticality or total fuel mass. It ultimately reaches the same optimal state of a flattened fuel importance distribution as another algorithm by Dam based on perturbation theory. This method was applied to two kinds of spherical cores with water reflector in the simulating reprocessing facility. In the slightly-enriched uranyl nitrate solution core, the minimum critical mass decreased by less than 1% at the optimal moderation state. In the plutonium nitrate solution core, the k-effective increment amounted up to 4.3% Δk within the range of present study. (author)

  7. Composites

    International Nuclear Information System (INIS)

    Kasen, M.B.

    1983-01-01

    This chapter discusses the roles of composite laminates and aggregates in cryogenic technology. Filamentary-reinforced composites are emphasized because they are the most widely used composite materials. Topics considered include composite systems and terminology, design and fabrication, composite failure, high-pressure reinforced plastic laminates, low-pressure reinforced plastics, reinforced metals, selectively reinforced structures, the effect of cryogenic temperatures, woven-fabric and random-mat composites, uniaxial fiber-reinforced composites, composite joints in cryogenic structures, joining techniques at room temperature, radiation effects, testing laminates at cryogenic temperatures, static and cyclic tensile testing, static and cyclic compression testing, interlaminar shear testing, secondary property tests, and concrete aggregates. It is suggested that cryogenic composite technology would benefit from the development of a fracture mechanics model for predicting the fitness-for-purpose of polymer-matrix composite structures

  8. Mathematical micro-model of a solid oxide fuel cell composite cathode

    International Nuclear Information System (INIS)

    Kenney, B.; Karan, K.

    2004-01-01

    In a solid oxide fuel cell (SOFC), the cathode processes account for a majority of the overall electrochemical losses. A composite cathode comprising a mixture of ion-conducting electrolyte and electron-conducting electro-catalyst can help minimize cathode losses provided microstructural parameters such as particle-size, composition, and porosity are optimized. The cost of composite cathode research can be greatly reduced by incorporating mathematical models into the development cycle. Incorporated with reliable experimental data, it is possible to conduct a parametric study using a model and the predicted results can be used as guides for component design. Many electrode models treat the cathode process simplistically by considering only the charge-transfer reaction for low overpotentials or the gas-diffusion at high overpotentials. Further, in these models an average property of the cathode internal microstructure is assumed. This paper will outline the development of a 1-dimensional SOFC composite cathode micro-model and the experimental procedures for obtaining accurate parameter estimates. The micro-model considers the details of the cathode microstructure such as porosity, composition and particle-size of the ionic and electronic phases, and their interrelationship to the charge-transfer reaction and mass transport processes. The micro-model will be validated against experimental data to determine its usefulness for performance prediction. (author)

  9. Study of Irradiation Effect onto Uranium silicide Fuel

    International Nuclear Information System (INIS)

    Suparjo

    1998-01-01

    The irradiation effect onto the U 3 Si-Al and U 3 Si 2 -Al dispersion type of fuel element has been studied. The fuel material performs swelling during irradiation due to boehmite (Al 2 O 3 (H 2 O)) formation in which might occurs inside the meat and on the cladding surface, the interaction between the fuel and aluminium matrix that produce U(Al,Si) 3 phase, and the formation of fission gas bubble inside the fuel. At a constant fission density, the U 3 Si-Al fuel swelling is higher than that of U 3 Si 2 -Al fuel. The swellings of both fuels increase with the increasing of fission density. The difference of swelling behavior was caused by formation of large bubble gases generated from fission product of U 3 Si fuel and distributed non-uniformly over all of fuel zone. On the other hand, the U 3 Si 2 fission produced small bubble gases, and those were uniformly distributed. The growth rate of fission gas bubble in the U 3 Si fuel has shown high diffusivity, transformation into amorph material and thus decrease its mechanical strength

  10. Ecological effects of fuel cycle activities

    Energy Technology Data Exchange (ETDEWEB)

    Barnthouse, L; Cada, G; Kroodsma, R; Shriner, D; Tolbert, V; Turner, R

    1994-07-01

    The purpose of this paper is to summarize the approach used to characterize ecological impacts of the coal fuel cycle. The same approach is used for many of the impacts in other fuel cycles as well. The principal analytical approach being used in the study is an accounting framework - that is, a series of matrices that map each phase of the fuel cycle to a suite of possible. emissions, each emission to a suite of impact categories, and each impact category to an external cost. This paper summarizes the ecological impacts of all phases of the coal fuel cycle, defines the ecological impact categories used in the study's 'accounting framework', and discusses alternative approaches to quantification. Externalities associated with CO{sub 2}-induced global climate change are beyond the scope of this paper and are not discussed.

  11. Effects of environments on spent fuel

    International Nuclear Information System (INIS)

    Funk, C.W.; Jacobson, L.D.; Menon, M.N.

    1979-07-01

    This report describes the influence of water storage environment and transportation on spent light water reactor (LWR) fuel assemblies. It also estimates the storage duration and capacity requirements for several assumed scenarios

  12. Ecological effects of fuel cycle activities

    International Nuclear Information System (INIS)

    Barnthouse, L.; Cada, G.; Kroodsma, R.; Shriner, D.; Tolbert, V.; Turner, R.

    1994-01-01

    The purpose of this paper is to summarize the approach used to characterize ecological impacts of the coal fuel cycle. The same approach is used for many of the impacts in other fuel cycles as well. The principal analytical approach being used in the study is an accounting framework - that is, a series of matrices that map each phase of the fuel cycle to a suite of possible. emissions, each emission to a suite of impact categories, and each impact category to an external cost. This paper summarizes the ecological impacts of all phases of the coal fuel cycle, defines the ecological impact categories used in the study's 'accounting framework', and discusses alternative approaches to quantification. Externalities associated with CO 2 -induced global climate change are beyond the scope of this paper and are not discussed

  13. Engine control techniques to account for fuel effects

    Science.gov (United States)

    Kumar, Shankar; Frazier, Timothy R.; Stanton, Donald W.; Xu, Yi; Bunting, Bruce G.; Wolf, Leslie R.

    2014-08-26

    A technique for engine control to account for fuel effects including providing an internal combustion engine and a controller to regulate operation thereof, the engine being operable to combust a fuel to produce an exhaust gas; establishing a plurality of fuel property inputs; establishing a plurality of engine performance inputs; generating engine control information as a function of the fuel property inputs and the engine performance inputs; and accessing the engine control information with the controller to regulate at least one engine operating parameter.

  14. Effects of spent nuclear fuel aging on disposal requirements

    International Nuclear Information System (INIS)

    McKee, R.W.; Johnson, K.I.; Huber, H.D.; Bierschbach, M.C.

    1991-10-01

    This paper describes results of a study to analyze the waste management systems effects of extended spent fuel aging on spent fuel disposal requirements. The analysis considers additional spent fuel aging up to a maximum of 50 years relative to the currently planned 2010 repository startup in the United States. As part of the analysis, an equal energy disposition (EED) methodology was developed for determining allowable waste emplacement densities and waste container loading in a geologic repository. Results of this analysis indicate that substantial benefits of spent fuel aging will already have been achieved by a repository startup in 2010 (spent fuel average age will be 28 years). Even so, further significant aging benefits, in terms of reduced emplacement areas and mining requirements and reduced number of waste containers, will continue to accrue for at least another 50 years when the average spent fuel age would be 78 years, if the repository startup is further delayed

  15. Inorganic-based proton conductive composite membranes for elevated temperature and reduced relative humidity PEM fuel cells

    Science.gov (United States)

    Wang, Chunmei

    Proton exchange membrane (PEM) fuel cells are regarded as highly promising energy conversion systems for future transportation and stationary power generation and have been under intensive investigations for the last decade. Unfortunately, cutting edge PEM fuel cell design and components still do not allow economically commercial implementation of this technology. The main obstacles are high cost of proton conductive membranes, low-proton conductivity at low relative humidity (RH), and dehydration and degradation of polymer membranes at high temperatures. The objective of this study was to develop a systematic approach to design a high proton conductive composite membrane that can provide a conductivity of approximately 100 mS cm-1 under hot and dry conditions (120°C and 50% RH). The approach was based on fundamental and experimental studies of the proton conductivity of inorganic additives and composite membranes. We synthesized and investigated a variety of organic-inorganic Nafion-based composite membranes. In particular, we analyzed their fundamental properties, which included thermal stability, morphology, the interaction between inorganic network and Nafion clusters, and the effect of inorganic phase on the membrane conductivity. A wide range of inorganic materials was studied in advance in order to select the proton conductive inorganic additives for composite membranes. We developed a conductivity measurement method, with which the proton conductivity characteristics of solid acid materials, zirconium phosphates, sulfated zirconia (S-ZrO2), phosphosilicate gels, and Santa Barbara Amorphous silica (SBA-15) were discussed in detail. Composite membranes containing Nafion and different amounts of functionalized inorganic additives (sulfated inorganics such as S-ZrO2, SBA-15, Mobil Composition of Matter MCM-41, and S-SiO2, and phosphonated inorganic P-SiO2) were synthesized with different methods. We incorporated inorganic particles within Nafion clusters

  16. Toxicity of power vehicles exhaust gases using bio fuels of different composition

    International Nuclear Information System (INIS)

    Kalnins, I.; Berjoza, D.

    2003-01-01

    The aim of the work is to state the influence of different bio fuels on the surrounding environment using them in diesel motors. The work summarises information on the composition of toxic components in vehicle exhaust gases, their influence on the surrounding environment. Characteristic features of different biofuels are summarised as well as their application possibilities in diesel motors. Measuring devices and measuring methods of toxic components of exhaust gases have been classified. Different measuring regimes of diesel motor exhaust gases have been described. Research in automobile Renault, equipped with diesel motor, exhaust gas smokiness using different biofuels has been carried out (author)

  17. Radiation effects in fuel materials for fission reactors

    International Nuclear Information System (INIS)

    Matzke, H.

    1983-01-01

    Physical and chemical changes that occur in fuel materials during fission are described. Emphasis is placed on the fuels used today, or those foreseen for the future, hence oxides and carbides of uranium and plutonium. Examples are given to illustrate the most interesting neutron effects. (author)

  18. Effects of Fuel Oil on the Geotechnical Properties of Clay Soil

    Directory of Open Access Journals (Sweden)

    Mahdi Obaid Karkush

    2017-08-01

    Full Text Available The present study highlights the effects of medium fuel oil (MFO on the chemical, physical and mechanical properties of clay soil samples (disturbed and undisturbed obtained from the site of the electrical power plant in the campus of the University of Baghdad at Al-Jadriah district in Baghdad/Iraq. The soil sample was classified according to the unified soil classification system (USCS as CL and described as lean clay of low plasticity. The medium fuel oil is an industrial wastewater disposed as a byproduct from the fuel used in the electricity power plant. The soil samples are artificially contaminated with two percentages of medium fuel oil, 10 and 20 % related to the dry weight of soil. The soil samples were mixed with the contaminant (MFO by hand and then left for 4 days for homogeneity. A series of laboratory tests are conducted on both natural and artificially contaminated soil samples to measure the effects of medium fuel oil on the chemical, physical and mechanical properties of soil samples. The results of tests showed that the medium fuel oil has significant impacts on some properties of soil and slight effects on the others. Increasing the percentage of contaminant causes a slight decrease in the liquid limit and particle size distribution; on the other hand, it causes a considerable increase in the consolidation parameters and decrease in shear strength parameters. Also, there is a slight change in the chemical composition of soil samples.

  19. On the effect of a moderator in the central region of a hollow fuel element

    International Nuclear Information System (INIS)

    Simopoulos, S.; Leonidou, D.

    1980-01-01

    An experimental investigation of the effect of a short slowing down length moderator, in the central region of a hollow fuel element, is attempted in the present work. Water, paraffin and plexiglass have been used as moderator materials. The results obtained show that an increase of the flux level is observed with such a moderator positioned in the central region of the fuel element, when comparing the situation with that existing without a central moderator. The increase is found to depend at least upon the thermal to fast neutron composition of the neutron spectrum. (author)

  20. Irradiation effects on fuels for space reactors

    International Nuclear Information System (INIS)

    Ranken, W.A.; Cronenberg, A.W.

    1984-01-01

    A review of irradiation-induced swelling and gas release experience is presented here for the three principal fuels UO 2 , UC, and UN. The primary advantage of UC and UN over UO 2 is higher thermal conductivity and attendant lower fuel temperature at equivalent pellet diameter and power density, while UO 2 offers the distinct benefit of well-known irradiation performance. Irradiation test results indicate that at equivalent burnup, temperature, and porosity conditions, UC experiences higher swelling than UO 2 or UN. Fission gas swelling becomes important at fuel temperatures above 1320 K for UC, and at somewhat higher temperatures for UO 2 and UN. Evidence exists that at equivalent fuel temperatures and burnups, high density UO 2 and UN experience comparable swelling behavior; however, differences in thermal conductivity influence overall irradiation performance. The low conductivity of UO 2 results in higher thermal gradients which contribute to fuel microcracking and gas release. As a result UO 2 exhibits higher fractional gas release than UN, at least or burnups up to about 3%

  1. Experimental study of fuel sootiness effects on flashover

    Energy Technology Data Exchange (ETDEWEB)

    Tsai, Kuang-Chung, E-mail: tsaikc@ccms.nkfust.edu.tw [Dept. of Safety, Health and Environmental Engineering, National Kaohsiung First University of Science and Technology, 2 Juoyue Road, Nantzu, Kaohsiung 811, Taiwan (China); Chen, Hung-Hsiang [Dept. of Safety, Health and Environmental Engineering, National Kaohsiung First University of Science and Technology, 2 Juoyue Road, Nantzu, Kaohsiung 811, Taiwan (China)

    2010-06-15

    Previous fire safety studies have demonstrated that flashover can result in severe injure and death and heat radiating back to a fuel is an important mechanism. Fuel sootiness dominates in radiative heat transfer. However, empirical correlations from previous investigations did not consider the fuel sootiness but nevertheless generated reasonably good predictions of flashover. In this study, a series of experiments was employed to examine fuel sootiness effects on flashover. The fuels used, in the order of their sootiness, were gasoline, n-hexane, iso-propanol and methanol. These fuels were filled in circular pans 100-320 mm in diameter to generate fires with different heat release rates and levels of sootiness. The pans were in 1/3 the size of the ISO 9705 test chamber. After ignition, the heat release rate (HRR), temperature inside the chamber, as well as heat flux on the floor and time to flashover (t{sub fo}) were determined. Experimental data show that HRR at flashover and t{sub fo} were strongly corrected and their relationship was independent of the fuel burned. Although heat feedback to the floor increased as fuel sootiness increased, consequently enhancing the burning of sooty fuels, flashover occurs only when the HRR at flashover criterion is reached.

  2. Theoretical modeling of iodine value and saponification value of biodiesel fuels from their fatty acid composition

    Energy Technology Data Exchange (ETDEWEB)

    Gopinath, A.; Puhan, Sukumar; Nagarajan, G. [Internal Combustion Engineering Division, Department of Mechanical Engineering, Anna University, Chennai 600 025, Tamil Nadu (India)

    2009-07-15

    Biodiesel is an alternative fuel consisting of alkyl esters of fatty acids from vegetable oils or animal fats. The properties of biodiesel depend on the type of vegetable oil used for the transesterification process. The objective of the present work is to theoretically predict the iodine value and the saponification value of different biodiesels from their fatty acid methyl ester composition. The fatty acid ester compositions and the above values of different biodiesels were taken from the available published data. A multiple linear regression model was developed to predict the iodine value and saponification value of different biodiesels. The predicted results showed that the prediction errors were less than 3.4% compared to the available published data. The predicted values were also verified by substituting in the available published model which was developed to predict the higher heating values of biodiesel fuels from their iodine value and the saponification value. The resulting heating values of biodiesels were then compared with the published heating values and reported. (author)

  3. Effect of engine parameters and gaseous fuel type on the cyclic variability of dual fuel engines

    Energy Technology Data Exchange (ETDEWEB)

    Mohamed Y.E. Selim [United Arab Emirates University, Al-Ain (United Arab Emirates). Mechanical Engineering Department, Faculty of Engineering

    2005-05-01

    This paper presents an analysis of the cycle-to-cycle combustion variation as reflected in the combustion pressure data of a single cylinder, naturally aspirated, four stroke, Ricardo E6 engine converted to run as dual fuel engine on diesel and gaseous fuel of LPG or methane. A measuring set-up consisting of a piezo-electric pressure transducer with charge amplifier and fast data acquisition card installed on an IBM microcomputer was used to gather the data of up to 1200 consecutive combustion cycles of the cylinder under various combination of engine operating and design parameters. These parameters included type of gaseous fuel, engine load, compression ratio, pilot fuel injection timing, pilot fuel mass, and engine speed. The data for each operating conditions were analyzed for the maximum pressure, the maximum rate of pressure rise representing the combustion noise, and indicated mean effective pressure. The cycle-to-cycle variation is expressed as the mean value, standard deviation, and coefficient of variation of these three parameters. It was found that the type of gaseous fuel and engine operating and design parameters affected the combustion noise and its cyclic variation and these effects have been presented. 21 refs., 6 figs., 1 tab.

  4. Effect of fuel particles' size variations on multiplication factor in pebble-bed nuclear reactor

    International Nuclear Information System (INIS)

    Snoj, L.; Ravnik, M.

    2005-01-01

    The pebble-bed reactor (Pbr) spherical fuel element consists of two radial zones: the inner zone, in which the fissile material in form of the so-called TRISO particles is uniformly dispersed in graphite matrix and the outer zone, a shell of pure graphite. A TRISO particle is composed of a fissile kernel (UO 2 ) and several layers of carbon composites. The effect of TRISO particles' size variations and distance between them on PBR multiplication factor is studied using MCNP code. Fuel element is modelled in approximation of a cubical unit cell with periodic boundary condition. The multiplication factor of the fuel element depends on the size of the TRISO particles due to resonance self-shielding effect and on the inter-particle distance due to inter-kernel shadowing. (author)

  5. Distributional effects of taxing transport fuel

    International Nuclear Information System (INIS)

    Sterner, Thomas

    2012-01-01

    This paper takes as its starting point the observation that fuel prices – and thus taxes – are important for good management of climate change and other environmental problems. To economists this should be no surprise yet it seems that the role of fuel taxation as an instrument of climate policy has not been fully appreciated. It is however one of the few policy instruments that, since several decades, has actually reduced fuel consumption appreciably. Thanks to taxation (mainly in Europe and Japan), carbon emissions are considerably lower than they would have been otherwise. In future where carbon emissions are to be cut drastically, this instrument will be crucial. There is however much opposition to the instrument. This opposition uses various arguments, for instance that fuel taxes hurt the poor since they are strongly regressive. We however find that the choice of country and methodology turns out to be of great consequence. We study seven European countries—France, Germany, United Kingdom, Italy, Serbia, Spain and Sweden and do find some evidence of regressivity but the evidence is very weak. It does not apply when lifetime income is used and it does not apply to the poorest country in the group. The best one-line summary is probably that the tax is approximately proportional.

  6. Diffuse Charge Effects in Fuel Cell Membranes

    NARCIS (Netherlands)

    Biesheuvel, P.M.; Franco, A.A.; Bazant, M.Z.

    2009-01-01

    It is commonly assumed that electrolyte membranes in fuel cells are electrically neutral, except in unsteady situations, when the double-layer capacitance is heuristically included in equivalent circuit calculations. Indeed, the standard model for electron transfer kinetics at the membrane/electrode

  7. The agnion Heatpipe-Reformer - operating experiences and evaluation of fuel conversion and syngas composition

    Energy Technology Data Exchange (ETDEWEB)

    Gallmetzer, Georg; Ackermann, Pascal [Highterm Research GmbH, Hettenshausen (Germany); Schweiger, Andreas; Kienberger, Thomas [Highterm Research GmbH, Graz (Austria); Groebl, Thomas; Walter, Heimo [Technische Universitaet Wien, Institut fuer Energietechnik und Thermodynamik, Wien (Austria); Zankl, Markus; Kroener, Martin [Agnion Technologies GmbH, Hettenshausen (Germany)

    2012-09-15

    Fluidized bed gasification of solid fuels is considered as one of the core technologies for future sustainable energy supply. Whereas autothermal oxygen-driven gasification is applied in large-scale substitute natural gas (SNG) and Fischer-Tropsch (FT) plants or small-scale combined heat and power (CHP) plants, the allothermal steam-reforming process of the agnion Heatpipe-Reformer is designed for cost- and fuel-efficient syngas generation at small scales for distributed applications. The Heatpipe-Reformer's pressurized syngas generation provides a number of benefits for SNG, biomass to liquid (BTL) and CHP applications. A modified gas engine concept uses the pressurized and hydrogen-rich syngas for increased performance and tar tolerance at decreased capital expenses. Agnion has installed and operated a 500-kW thermal input pilot plant in Pfaffenhofen, Germany, over the last 2 years, showing stable operation over a variety of operating points. The syngas composition has been measured at values expected by thermodynamic models. An influence of the steam-to-fuel ratio and reformer temperature was observed. Tar and sulphur contents have been monitored and correlated to operation parameters, showing influences on stoichiometry and carbon conversion. The mass and energy streams of the plant were balanced. One of the main observations in the monitoring programme is the fact that syngas output, efficiency and syngas quality correlate to high values if the carbon conversion is high. Carbon conversion rates and cold gas efficiencies are comparably high in respect to today's processes, promising economic and fuel-efficient operation of the Heatpipe-Reformer applications. (orig.)

  8. Effect of Intake Air Filter Condition on Vehicle Fuel Economy

    Energy Technology Data Exchange (ETDEWEB)

    Norman, Kevin M [ORNL; Huff, Shean P [ORNL; West, Brian H [ORNL

    2009-02-01

    The U.S. Department of Energy (DOE) Office of Energy Efficiency and Renewable Energy and the U.S. Environmental Protection Agency (EPA) jointly maintain a fuel economy website (www.fueleconomy.gov), which helps fulfill their responsibility under the Energy Policy Act of 1992 to provide accurate fuel economy information [in miles per gallon (mpg)] to consumers. The site provides information on EPA fuel economy ratings for passenger cars and light trucks from 1985 to the present and other relevant information related to energy use such as alternative fuels and driving and vehicle maintenance tips. In recent years, fluctuations in the price of crude oil and corresponding fluctuations in the price of gasoline and diesel fuels have renewed interest in vehicle fuel economy in the United States. (User sessions on the fuel economy website exceeded 20 million in 2008 compared to less than 5 million in 2004 and less than 1 million in 2001.) As a result of this renewed interest and the age of some of the references cited in the tips section of the website, DOE authorized the Oak Ridge National Laboratory (ORNL) Fuels, Engines, and Emissions Research Center (FEERC) to initiate studies to validate and improve these tips. This report documents a study aimed specifically at the effect of engine air filter condition on fuel economy. The goal of this study was to explore the effects of a clogged air filter on the fuel economy of vehicles operating over prescribed test cycles. Three newer vehicles (a 2007 Buick Lucerne, a 2006 Dodge Charger, and a 2003 Toyota Camry) and an older carbureted vehicle were tested. Results show that clogging the air filter has no significant effect on the fuel economy of the newer vehicles (all fuel injected with closed-loop control and one equipped with MDS). The engine control systems were able to maintain the desired AFR regardless of intake restrictions, and therefore fuel consumption was not increased. The carbureted engine did show a decrease in

  9. Fossil fuel produced radioactivities and their effect on foodchains

    Energy Technology Data Exchange (ETDEWEB)

    Okamoto, K [New South Wales Univ., Kensington (Australia). Dept. of Applied Mathematics

    1980-10-01

    The environmental impact of radioactivities produced from fossil fuel burning is not necessarily small compared with that of nuclear energy. The effect of these radioactivities on the foodchain through seafoods is discussed.

  10. Effects of ambient conditions on fuel cell vehicle performance

    Science.gov (United States)

    Haraldsson, K.; Alvfors, P.

    Ambient conditions have considerable impact on the performance of fuel cell hybrid vehicles. Here, the vehicle fuel consumption, the air compressor power demand, the water management system and the heat loads of a fuel cell hybrid sport utility vehicle (SUV) were studied. The simulation results show that the vehicle fuel consumption increases with 10% when the altitude increases from 0 m up to 3000 m to 4.1 L gasoline equivalents/100 km over the New European Drive Cycle (NEDC). The increase is 19% on the more power demanding highway US06 cycle. The air compressor is the major contributor to this fuel consumption increase. Its load-following strategy makes its power demand increase with increasing altitude. Almost 40% of the net power output of the fuel cell system is consumed by the air compressor at the altitude of 3000 m with this load-following strategy and is thus more apparent in the high-power US06 cycle. Changes in ambient air temperature and relative humidity effect on the fuel cell system performance in terms of the water management rather in vehicle fuel consumption. Ambient air temperature and relative humidity have some impact on the vehicle performance mostly seen in the heat and water management of the fuel cell system. While the heat loads of the fuel cell system components vary significantly with increasing ambient temperature, the relative humidity did not have a great impact on the water balance. Overall, dimensioning the compressor and other system components to meet the fuel cell system requirements at the minimum and maximum expected ambient temperatures, in this case 5 and 40 °C, and high altitude, while simultaneously choosing a correct control strategy are important parameters for efficient vehicle power train management.

  11. Proton conductive montmorillonite-Nafion composite membranes for direct ethanol fuel cells

    Energy Technology Data Exchange (ETDEWEB)

    Wu, Xiu-Wen, E-mail: wuxw2008@163.com [School of Science, China University of Geosciences, Beijing 100083 (China); National Laboratory of Mineral Materials, China University of Geosciences, Beijing 100083 (China); Wu, Nan; Shi, Chun-Qing; Zheng, Zhi-Yuan; Qi, Hong-Bin; Wang, Ya-Fang [School of Science, China University of Geosciences, Beijing 100083 (China)

    2016-12-01

    Highlights: • Composite membranes are prepared with different montmorillonites and nafion solution. • Proton conductivities of the composite membranes are between 36.0 mS/cm and 38.5 mS/cm. • Ethanol permeability is between 0.69 × 10{sup −6} cm{sup 2}/s and 2.67 × 10{sup −6} cm{sup 2}/s. • Water uptake is approximately 24.30 mass%. - Abstract: The preparation of Nafion membranes modified with montmorillonites is less studied, and most relative works mainly applied in direct methanol fuel cells, less in direct ethanol fuel cells. Organic/inorganic composite membranes are prepared with different montmorillonites (Ca-montmorillonite, Na-montmorillonite, K-montmorillonite, Mg-montmorillonite, and H-montmorillonite) and Nafion solution via casting method at 293 K in air, and with balance of their proton conductivity and ethanol permeability. The ethanol permeability and proton conductivity of the membranes are comparatively studied. The montmorillonites can well decrease the ethanol permeability of the membranes via inserted them in the membranes, while less decrease the proton conductivities of the membranes depending on the inserted amount and type of montmorillonites. The proton conductivities of the membranes are between 36.0 mS/cm and 38.5 mS/cm. The ethanol permeability of the membranes is between 0.69 × 10{sup −6} cm{sup 2}/s and 2.67 × 10{sup −6} cm{sup 2}/s.

  12. Effect of Fuel Additives on Spray Performance of Alternative Jet Fuels

    Science.gov (United States)

    Kannaiyan, Kumaran; Sadr, Reza

    2015-11-01

    Role of alternative fuels on reducing the combustion pollutants is gaining momentum in both land and air transport. Recent studies have shown that addition of nanoscale metal particles as fuel additives to liquid fuels have a positive effect not only on their combustion performance but also in reducing the pollutant formation. However, most of those studies are still in the early stages of investigation with the addition of nanoparticles at low weight percentages. Such an addition can affect the hydrodynamic and thermo-physical properties of the fuel. In this study, the near nozzle spray performance of gas-to-liquid jet fuel with and without the addition of alumina nanoparticles are investigated at macro- and microscopic levels using optical diagnostic techniques. At macroscopic level, the addition of nanoparticles is seen to enhance the sheet breakup process when compared to that of the base fuel. Furthermore, the microscopic spray characteristics such as droplet size and velocity are also found to be affected. Although the addition of nanoscale metal particles at low weight percentages does not affect the bulk fluid properties, the atomization process is found to be affected in the near nozzle region. Funded by Qatar National Research Fund.

  13. Chemical composition, antioxidant effects and antimicrobial ...

    African Journals Online (AJOL)

    Thymus vulgaris, Cinnamomum zeylanicum and Ocimum gratissimum are spices widely used as aroma enhancers and food preservatives. This work assessed the chemical composition, antioxidant and antimicrobial effect of their essential oils on some food pathogenic bacteria, namely, Staphylococcus aureus, Citrobacter ...

  14. Synthesis and ceramic processing of zirconia alumina composites for application as solid oxide fuel cell electrolytes

    International Nuclear Information System (INIS)

    Garcia, Rafael Henrique Lazzari

    2007-01-01

    The global warmness and the necessity to obtain clean energy from alternative methods than petroleum raises the importance of developing cleaner and more efficient systems of energy generation, among then, the solid oxide fuel cell (SOFC). Cubic stabilized zirconia (CSZ) has been the most studied material as electrolyte in SOFC, due to its ionic conductivity and great stability at operation conditions. However, its low fracture toughness difficulties its application as a thin layer, what could lead to an improvement of cell efficiency. In this sense, the alumina addition in CSZ forms a composite, which can shift its mechanical properties, without compromising its electrical properties. In this work, coprecipitation synthesis route and ceramic processing of zirconia-alumina composites were studied, in order to establish optimum conditions to attain high density, homogeneous microstructure, and better mechanical properties than CSZ, without compromising ionic conductivity. For this purpose, composites containing up to 40 wt % of alumina, in a 9 mol % yttria-stabilized zirconia (9Y-CSZ) matrix were evaluated. In order to optimize the synthesis of the composites, a preliminary study of powder obtaining and processing were carried out, at compositions containing 20 wt % of alumina, in 9Y-CSZ. The ceramic powders were characterized by helium picnometry, X-ray diffraction, scanning electronic microscopy, transmission electronic microscopy, thermogravimetry, differential scanning calorimetry, granulometry by laser diffraction and gas adsorption (BET). The characterization of sinterized compacts were performed by X-ray diffraction, scanning electron microscopy, optical microscopy, density measurements, Vickers indentation and impedance spectroscopy. The obtained results show that the alumina addition, in the 9Y-CSZ matrix powders, raises the specific surface area, promotes deagglomeration of powders and elevates the oxides crystallization temperature, requiring higher

  15. The Effect of Wood Fuels on Power Plant Availability

    Energy Technology Data Exchange (ETDEWEB)

    Orjala, Markku (Markku.Orjala@vtt.fi); Kaerki, Janne; Vainikka, Pasi [VTT Processes, Jyvaeskylae (Finland)

    2003-11-01

    There is a growing international interest in utilising renewable fuels, also in multifuel applications. Main reasons for this are the objective to reduce CO{sub 2} emissions and meet emission limits for NO{sub x} and SO{sub 2}. On one hand cofiring, defined as simultaneous combustion of different fuels in the same boiler, provides an alternative to achieve emission reductions. This is not only accomplished by replacing fossil fuel with biomass, but also as a result of the interaction of fuel reactants of different origin (e.g. biomass vs. coal). On the other hand, utilisation of solid biofuels and wastes sets new demands for process control and boiler design, as well as for combustion technologies, fuel blend control and fuel handling systems. In the case of wood-based fuels this is because of their high reactivity, high moisture content and combustion residues' high alkaline metal content. Combustion and cofiring properties of fuels have been studied both in VTT Processes' test facilities and in industrial-scale power plant boilers. The formation of alkaline and chlorine compounds in biomass combustion and their effect on boiler fouling and corrosion have been monitored by temperature controlled deposit formation and material monitoring probes. Deposit formation monitoring at full-scale boilers provides unique information on the rate of deposit formation, the effect of sootblowing and consequent changes in heat transfer. Additionally, the data from deposit formation monitoring has been shown to correlate with boiler performance, which gives basis for studying the interrelation of: fuel blend characteristics; deposit formation; boiler performance. If biomass fuels are blended with coal or peat, following implications may be expected: increased rate of deposit formation, shorter sootblowing interval, cleaning of heat transfer surfaces in revisions may be required, bed material agglomeration (in fluidised beds), increased risk of corrosion, higher in

  16. Effective economics of nuclear fuel power complex

    International Nuclear Information System (INIS)

    Shevelev, Ya.V.; Klimenko, A.V.

    1996-01-01

    Problems of the economic theory and practice of functioning the nuclear fuel power complex (NFPC) are considered. Using the principle of market equilibrium for optimization of the NFPC hierarchical system is analyzed. The main attention is paid to determining the prices of production and consumption of the NFPC enterprises. Economic approaches on the optimal calculations are described. The ecological safety of NPP and NFPC enterprises is analyzed. A conception of the market socialism is presented

  17. Influence of fuel composition on the non-oxidizing heating of steel in a waste gas atmosphere

    Energy Technology Data Exchange (ETDEWEB)

    Minkler, W [LOI Industrieofenanlagen G.m.b.H., Essen (Germany, F.R.)

    1979-04-01

    On the basis of a number of graphs and data on theoretical combustion temperatures and the difference between the heating value of the fuel and the waste gas in respect of 1 m/sup 3/ of waste gas, the author demonstrates the influence of fuel composition on the non-oxidizing heating of steel in a waste gas atmosphere derived from five different fuels. A rotary-hearth furnace is described for the non-oxidizing heating of pressings from plain carbon and alloy steel.

  18. FUEL CONSUMPTION EFFECT OF COMMERCIAL TURBOFANS ON GLOBAL WARMING

    Energy Technology Data Exchange (ETDEWEB)

    Onder Turan; T. Hikmet Karakoc [School of Civil Aviation, Anadolu University, Eskisehir (Turkey)

    2008-09-30

    The main objective pursued in this study is to parametrically investigate the fuel consumption effect of commercial turbofans on global warming. In this regard, Of the important parameters, specific fuel consumption of a commercial turbofans is taken into consideration. In order to minimize the effect of fuel consumption on global warming, the values of engine design parameters are optimized for maintaining minimum specific fuel consumption of high bypass turbofan engine under different flight conditions and design criteria. The backbones of optimization approach consisted of elitism-based genetic algorithm coupled with real parametric cycle analysis of a turbofan engine. For solving optimization problem a new software program is developed in MATLAB, while objective function is determined for minimizing the specific fuel consumption by considering the following parameters such as the fan pressure ratio ({pi}{sub f}), bypass ratio ({alpha}) and the fuel heating value [h{sub PR}-(kJ/kg)]. Accordingly, it may be concluded that the software program developed can successfully solve optimization problems at 1.2{le}{pi}{sub f}{le}2, 2{le}{alpha}{le}10 and 23000{le}h{sub PR}{le}120000 with aircraft flight Mach number {le}0.8. Fuel types used in preliminary engine cycle analysis were JP-4, JP-5, JP-8 and hydrogen in this paper.

  19. Effects of Burnable Absorbers on PWR Spent Nuclear Fuel

    International Nuclear Information System (INIS)

    O'Leary, P.M.; Pitts, M.L.

    2000-01-01

    Burnup credit is an ongoing issue in designing and licensing transportation and storage casks for spent nuclear fuel (SNF). To address this issue, in July 1999, the U.S. Nuclear Regulatory Commission (NRC), Spent Fuel Project Office, issued Interim Staff Guidance-8 (ISG-8), Revision 1 allowing limited burnup credit for pressurized water reactor (PWR) spent nuclear fuel (SNF) to be used in transport and storage casks. However, one of the key limitations for a licensing basis analysis as stipulated in ISG-8, Revision 1 is that ''burnup credit is restricted to intact fuel assemblies that have not used burnable absorbers''. Because many PWR fuel designs have incorporated burnable-absorber rods for more than twenty years, this restriction places an unnecessary burden on the commercial nuclear power industry. This paper summarizes the effects of in-reactor irradiation on the isotopic inventory of PWR fuels containing different types of integral burnable absorbers (BAs). The work presented is illustrative and intended to represent typical magnitudes of the reactivity effects from depleting PWR fuel with different types of burnable absorbers

  20. Advanced Collimators for Verification of the Pu Isotopic Composition in Fresh Fuel by High Resolution Gamma Spectrometry

    International Nuclear Information System (INIS)

    Lebrun, Alain; Berlizov, Andriy

    2013-06-01

    IAEA verification of the nuclear material contained in fresh nuclear fuel assemblies is usually based on neutron coincidence counting (NCC). In the case of uranium fuel, active NCC provides the total content of uranium-235 per unit of length which, combined with active length verification, fully supports the verification. In the case of plutonium fuel, passive NCC provides the plutonium-240 equivalent content which needs to be associated with a measurement of the isotopic composition and active length measurement to complete the verification. Plutonium isotopic composition is verified by high resolution gamma spectrometry (HRGS) applied on fresh fuel assemblies assuming all fuel rods are fabricated from the same plutonium batch. For particular verifications when such an assumption cannot be reasonably made, there is a need to optimize the HRGS measurement so that contributions of internal rods to the recorded spectrum are maximized, thus providing equally strong verification of the internal fuel rods. This paper reports on simulation work carried out to design special collimators aimed at reducing the relative contribution of external fuel rods while enhancing the signal recorded from internal rods. Both cases of square lattices (e.g. 17x17 pressurized water reactor (PWR) fuel) and hexagonal compact lattices (e.g. BN800 fast neutron reactor (FNR) fuel) have been addressed. In the case of PWR lattices, the relatively large optical path to internal pins compensates for low plutonium concentrations and the large size of the fuel assemblies. A special collimator based on multiple, asymmetrical, vertical slots allows recording a spectrum from internal rods only when needed. In the FNR case, the triangular lattice is much more compact and the optical path to internal rods is very narrow. However, higher plutonium concentration and use of high energy ranges allow the verification of internal rods to be significantly strengthened. Encouraging results from the simulation

  1. Effect of PET functionalization in composites of

    Directory of Open Access Journals (Sweden)

    Cristina Cazan

    2017-03-01

    Full Text Available The functionalization of polyethylene terephthalate (PET from tire rubber–PET–high density polyethylene (HDPE composites represents a key strategy for improving the composite properties. This is a practical and effective method to improve the interface between matrix (waste tire rubber and fillers (waste PET and HDPE. By PET functionalization, adherence and surface properties of composite materials can be controlled. PET functionalization was performed with polyethylene glycol (PEG 400, 1% and sodium dodecyl sulphate (SDS 1%. The characterization of the components and composite are discussed in terms of surface energy values (evaluated from water contact angle measurements and surface morphology by using scanning electron microscopy (SEM. The structural and conformational changes were investigated by Fourier Transform Infrared (FTIR Spectroscopy while the crystalline structure was studied by X-ray diffraction (XRD. The improved interfacial adhesion, thermal stability and mechanical properties (stress–strain, compression and impact resistance of the composites are correlated with the PET functionalization, with non-ionic (PEG and an anionic surfactant (SDS. The results proved that the interface properties are improved by functionalization of PET. The best mechanical properties were recorded at 30 min moulding. The samples with 45% PET–SDS showed the best combination of mechanical properties: tensile strength (1.56 N/mm2, impact strength (43.72 kJ/m2 and compression (158.78 N/mm2.

  2. Magnetodielectric effect in relaxor/ferrimagnetic composites

    Energy Technology Data Exchange (ETDEWEB)

    Naveed Ul-Haq, M., E-mail: naveedulhaq07@gmail.com [Department of Physics, Quaid-i-Azam University, Islamabad 45320 (Pakistan); Institute for Materials Sciences and Center for Nanointegration Duisburg-Essen (CENIDE), University of Duisburg-Essen, Essen 45141 (Germany); Yunus, Tayyaba; Mumtaz, Arif [Department of Physics, Quaid-i-Azam University, Islamabad 45320 (Pakistan); Shvartsman, V.V.; Lupascu, Doru C. [Institute for Materials Sciences and Center for Nanointegration Duisburg-Essen (CENIDE), University of Duisburg-Essen, Essen 45141 (Germany)

    2015-08-15

    Highlights: • Single phase ferroelectric (relaxor)/ferrimagnetic composites are synthesized. • The composite shows magnetodielectric effect. • Effect of interface strain is discussed. • MD is explained via defining a local order parameter q(T). - Abstract: We report on the effect of an applied static magnetic field on the dielectric properties of ferroelectric relaxor/ferrimagnetic composites consisting of [Ba(Sn{sub 0.3}Ti{sub 0.7})O{sub 3}]{sub 0.8}–[CoFe{sub 2}O{sub 4}]{sub 0.2} (BST{sub 0.8}–CFO{sub 0.2}). The pure Ba(Sn{sub 0.3}Ti{sub 0.7})O{sub 3} (BST30) as well as the composites, were synthesized by solid state reaction method. The X-ray diffraction analysis confirmed that BST30 and CFO coexist in the composite without any secondary phase. The real and the imaginary part of the dielectric permittivity were studied as a function of temperature, with and without static magnetic field, respectively. Relaxor characteristics such as dielectric permittivity and its peak temperature are observed to vary with the magnetic field. This is explained in the context that the applied magnetic field creates magnetostriction in the ferrite phase which is transferred to the relaxor phase via the interface coupling. The strain in the relaxor phase results in the reorientation of local polarization entities, polar nano regions (PNRs), which alters the dielectric characteristics of the sample. This effect is explained in relation to local order parameter q(T) which is found to increase in a certain temperature range above the typical ferroelectric temperature regime with the application of magnetic field.

  3. Investigation on fabrication of SiC/SiC composite as a candidate material for fuel sub-assembly

    International Nuclear Information System (INIS)

    Lee, Jae-Kwang; Naganuma, Masayuki; Park, Joon-Soo; Kohyama, Akira

    2005-01-01

    The possibility of SiC/SiC (Silicon carbide fiber reinforced Silicon carbide) composites application for fuel sub-assembly of Fast Breeder Reactor was investigated. To select a raw material of SiC/SiC composites, a few kinds of SiC nano powder was estimated by SEM observation and XRD analysis. Furthermore, SiC monolithic was sintered from them and estimated by flexural test. SiC nano-powder which showed good sinterability, it was used for fabrication of SiC/SiC composites by Hot Pressing method. From the sintering condition of 1800, 1820degC temperature and 15, 20 MPa pressure, SiC/SiC composite was fabricated and then estimated by tensile test. SiC/SiC composite, which made by 1820degC and 20 MPa condition, showed the highest mechanical strength by the monotonic tensile test. SiC/SiC composite, which made by 1800degC and 15 MPa condition, showed a stable fracture behavior at the monotonic and cyclic tensile test. And then, the hoop stress of ideal model of SiC/SiC composites was discussed. It was confirmed that applicability of SiC/SiC composites by Hot Pressing method for fuel sub-assembly structural material. To make it real attractive one, to maintain the reliability and safety as a high temperature structural material, the design and process study on SiC/Sic composites material will be continued. (author)

  4. Effect of power variations across a fuel bundle and within a fuel element on fuel centerline temperature in PHWR bundles in uncrept and crept pressure tubes

    International Nuclear Information System (INIS)

    Onder, E.N.; Roubtsov, D.; Rao, Y.F.; Wilhelm, B.

    2017-01-01

    Highlights: • Pressure tube creep effect on fuel pin power and temperatures was investigated. • Noticeable effects were observed for 5.1% crept pressure tube. • Bundle eccentricity effect on power variations was insignificant for uncrept channels. • Difference of 112 °C was observed between top & bottom elements in 5.1% crept channel. • Not discernible fission gas release was expected with temperature difference of 112 °C. - Abstract: The neutron flux and fission power profiles through a fuel bundle and across a fuel element are important aspects of nuclear fuel analysis in multi-scale/multi-physics modelling of Pressurized Heavy Water Reactors (PHWRs) with advanced fuel bundles. Fuel channels in many existing PHWRs are horizontal. With ageing, pressure tubes creep and fuel bundles in these pressure tubes are eccentrically located, which results in an asymmetric coolant flow distribution between the top and bottom of the fuel bundles. The diametral change of the pressure tube due to creep is not constant along the fuel channel; it reaches a maximum in the vicinity of the maximum neutron flux location. The cross-sectional asymmetric positioning of fuel bundles in a crept pressure tube contributes to an asymmetric power distribution within a ring of fuel elements. Modern reactor physics lattice codes (such as WIMS-AECL) are capable of predicting the details of power distribution from basic principles. Thermalhydraulics subchannel codes (such as ASSERT-PV) use models to describe inhomogeneous power distribution within and across fuel elements (e.g., flux tilt model, different powers in different ring elements, or radial power profiles). In this work, physics and thermalhydraulics codes are applied to quantify the effect of eccentricity of a fuel bundle on power variations across it and within a fuel element, and ultimately on the fuel temperature distribution and fuel centerline temperature, which is one of the indicators of fuel performance under normal

  5. Thermal Effects by Firing Oil Shale Fuel in CFB Boilers

    Science.gov (United States)

    Neshumayev, D.; Ots, A.; Parve, T.; Pihu, T.; Plamus, K.; Prikk, A.

    It is well known that during firing of oil shale fuel the amount of heat released during its combustion per kg of fuel is significantly affected by the endothermic and exothermic processes taking place in mineral matter. These thermal effects are calcite and dolomite decomposing, marcasite FeS2 oxidising, CaO sulphation and formation of the new minerals. The given paper deals with the experimental study of the influence of these thermal effects of oil shale fuel having different heating value on total amount of heat released during combustion in calorimetric bomb, circulating fluidized bed (CFB) and pulverized-firing boiler (PFB). The large-scale (250 MWth) experiments were performed in the K11-1 CFB boiler of the Balti Power Plant. During experiments low heating value of a fuel varied within the range 8.5-11 MJ/kg. At the end some conclusions were drawn.

  6. Edge effects in composites by moire interferometry

    Science.gov (United States)

    Czarnek, R.; Post, D.; Herakovich, C.

    1983-01-01

    The very high sensitivity of moire interferometry has permitted the present edge effect experiments to be conducted at a low average stress and strain level, assuring linear and elastic behavior in the composite material samples tested. Sensitivity corresponding to 2450 line/mm moire was achieved with a 0.408 micron/fringe. Simultaneous observations of the specimen face and edge displacement fields showed good fringe definition despite the 1-mm thickness of the specimens and the high gradients, and it is noted that the use of a carrier pattern and optical filtering was effective in even these conditions. Edge effects and dramatic displacement gradients were confirmed in angle-ply composite laminates.

  7. Analytical, 1-Dimensional Impedance Model of a Composite Solid Oxide Fuel Cell Cathode

    DEFF Research Database (Denmark)

    Mortensen, Jakob Egeberg; Søgaard, Martin; Jacobsen, Torben

    2014-01-01

    An analytical, 1-dimensional impedance model for a composite solid oxide fuel cell cathode is derived. It includes geometrical parameters of the cathode, e.g., the internal surface area and the electrode thickness, and also material parameters, e.g., the surface reaction rate and the vacancy...... diffusion coefficient. The model is successfully applied to a total of 42 impedance spectra, obtained in the temperature range 555°C–852°C and in the oxygen partial pressure range 0.028 atm–1.00 atm for a cathode consisting of a 50/50 wt% mixture of (La0.6Sr0.4)0.99CoO3 − δ and Ce0.9Gd0.1O1.95 − δ...... and providing both qualitative and quantitative information on the evolution of the impedance spectra of cathodes with changing parameters....

  8. Characterization of SiC–SiC composites for accident tolerant fuel cladding

    Energy Technology Data Exchange (ETDEWEB)

    Deck, C.P., E-mail: Christian.Deck@ga.com; Jacobsen, G.M.; Sheeder, J.; Gutierrez, O.; Zhang, J.; Stone, J.; Khalifa, H.E.; Back, C.A.

    2015-11-15

    Silicon carbide (SiC) is being investigated for accident tolerant fuel cladding applications due to its high temperature strength, exceptional stability under irradiation, and reduced oxidation compared to Zircaloy under accident conditions. An engineered cladding design combining monolithic SiC and SiC–SiC composite layers could offer a tough, hermetic structure to provide improved performance and safety, with a failure rate comparable to current Zircaloy cladding. Modeling and design efforts require a thorough understanding of the properties and structure of SiC-based cladding. Furthermore, both fabrication and characterization of long, thin-walled SiC–SiC tubes to meet application requirements are challenging. In this work, mechanical and thermal properties of unirradiated, as-fabricated SiC-based cladding structures were measured, and permeability and dimensional control were assessed. In order to account for the tubular geometry of the cladding designs, development and modification of several characterization methods were required.

  9. A Central Composite Face-Centered Design for Parameters Estimation of PEM Fuel Cell Electrochemical Model

    Directory of Open Access Journals (Sweden)

    Khaled MAMMAR

    2013-11-01

    Full Text Available In this paper, a new approach based on Experimental of design methodology (DoE is used to estimate the optimal of unknown model parameters proton exchange membrane fuel cell (PEMFC. This proposed approach combines the central composite face-centered (CCF and numerical PEMFC electrochemical. Simulation results obtained using electrochemical model help to predict the cell voltage in terms of inlet partial pressures of hydrogen and oxygen, stack temperature, and operating current. The value of the previous model and (CCF design methodology is used for parametric analysis of electrochemical model. Thus it is possible to evaluate the relative importance of each parameter to the simulation accuracy. However this methodology is able to define the exact values of the parameters from the manufacture data. It was tested for the BCS 500-W stack PEM Generator, a stack rated at 500 W, manufactured by American Company BCS Technologies FC.

  10. Methods of refining natural oils, and methods of producing fuel compositions

    Science.gov (United States)

    Firth, Bruce E.; Kirk, Sharon E.

    2015-10-27

    A method of refining a natural oil includes: (a) providing a feedstock that includes a natural oil; (b) reacting the feedstock in the presence of a metathesis catalyst to form a metathesized product that includes olefins and esters; (c) passivating residual metathesis catalyst with an agent that comprises nitric acid; (d) separating the olefins in the metathesized product from the esters in the metathesized product; and (e) transesterifying the esters in the presence of an alcohol to form a transesterified product and/or hydrogenating the olefins to form a fully or partially saturated hydrogenated product. Methods for suppressing isomerization of olefin metathesis products produced in a metathesis reaction, and methods of producing fuel compositions are described.

  11. Evaluation of sulfonated polysulfone/zirconium hydrogen phosphate composite membranes for direct methanol fuel cells

    International Nuclear Information System (INIS)

    Ozden, Adnan; Ercelik, Mustafa; Devrim, Yilser; Colpan, C. Ozgur; Hamdullahpur, Feridun

    2017-01-01

    Highlights: •Very thin SPSf/ZrP composite membranes were prepared by solution casting method. •The viability of SPSf/ZrP membranes for DMFCs was investigated for the first time. •Superior proton conductivity over Nafion ® 115 was achieved between 45–80 °C. •Desired membrane characteristics, along with low manufacturing cost were achieved. •Single cell DMFC performance was improved up to 13%. -- Abstract: Direct methanol fuel cell (DMFC) technology has advanced perceivably, but technical challenges remain that must be overcome for further performance improvements. Thus, in this study, sulfonated polysulfone/zirconium hydrogen phosphate (SPSf/ZrP) composite membranes with various sulfonation degrees (20%, 35%, and 42%) and a constant concentration of ZrP (2.5%) were prepared to mitigate the technical challenges associated with the use of conventional Nafion ® membranes in DMFCs. The composite membranes were investigated through Scanning Electron Microscopy (SEM), Electrochemical Impedance Spectroscopy (EIS), Thermogravimetric Analysis (TGA), oxidative stability and water uptake measurements, and single cell testing. Comparison was also made with Nafion ® 115. Single cell tests were performed under various methanol concentrations and cell temperatures. Stability characteristics of the DMFCs under charging and discharging conditions were investigated via 1200 min short-term stability tests. The response characteristics of the DMFCs under dynamic conditions were determined at the start-up and shut-down stages. Composite membranes with sulfonation degrees of 35% and 42% were found to be highly promising due to their advanced characteristics with respect to proton conductivity, water uptake, thermal resistance, oxidative stability, and methanol suppression. For the whole range of parameters studied, the maximum power density obtained for SPSf/ZrP-42 (119 mW cm −2 ) was found to be 13% higher than that obtained for Nafion ® 115 (105 mW cm −2 ).

  12. Learning FuelPHP for effective PHP development

    CERN Document Server

    Tweedie, Ross

    2013-01-01

    The book follows a standard tutorial approach, which will enable readers to use the FuelPHP framework efficiently while developing PHP applications.If you are a PHP developer who is looking to learn more about using the FuelPHP framework for effective PHP development, this book is ideal for you. If you are interested in this book, you should already have a basic understanding of general PHP development.

  13. Coriander seed oil methyl esters as biodiesel fuel: Unique fatty acid composition and excellent oxidative stability

    International Nuclear Information System (INIS)

    Moser, Bryan R.; Vaughn, Steven F.

    2010-01-01

    Coriander (Coriandrum sativum L.) seed oil methyl esters were prepared and evaluated as an alternative biodiesel fuel and contained an unusual fatty acid hitherto unreported as the principle component in biodiesel fuels: petroselinic (6Z-octadecenoic; 68.5 wt%) acid. Most of the remaining fatty acid profile consisted of common 18 carbon constituents such as linoleic (9Z,12Z-octadeca-dienoic; 13.0 wt%), oleic (9Z-octadecenoic; 7.6 wt%) and stearic (octadecanoic; 3.1 wt%) acids. A standard transesterification procedure with methanol and sodium methoxide catalyst was used to provide C. sativum oil methyl esters (CSME). Acid-catalyzed pretreatment was necessary beforehand to reduce the acid value of the oil from 2.66 to 0.47 mg g -1 . The derived cetane number, kinematic viscosity, and oxidative stability (Rancimat method) of CSME was 53.3, 4.21 mm 2 s -1 (40 o C), and 14.6 h (110 o C). The cold filter plugging and pour points were -15 o C and -19 o C, respectively. Other properties such as acid value, free and total glycerol content, iodine value, as well as sulfur and phosphorous contents were acceptable according to the biodiesel standards ASTM D6751 and EN 14214. Also reported are lubricity, heat of combustion, and Gardner color, along with a comparison of CSME to soybean oil methyl esters (SME). CSME exhibited higher oxidative stability, superior low temperature properties, and lower iodine value than SME. In summary, CSME has excellent fuel properties as a result of its unique fatty acid composition.

  14. Mechanical behaviors of the dispersion nuclear fuel plates induced by fuel particle swelling and thermal effect II: Effects of variations of the fuel particle diameters

    International Nuclear Information System (INIS)

    Ding Shurong; Wang Qiming; Huo Yongzhong

    2010-01-01

    In order to predict the irradiation mechanical behaviors of plate-type dispersion nuclear fuel elements, the total burnup is divided into two stages: the initial stage and the increasing stage. At the initial stage, the thermal effects induced by the high temperature differences between the operation temperatures and the room temperature are mainly considered; and at the increasing stage, the intense mechanical interactions between the fuel particles and the matrix due to the irradiation swelling of fuel particles are focused on. The large-deformation thermo-elasto-plasticity finite element analysis is performed to evaluate the effects of particle diameters on the in-pile mechanical behaviors of fuel elements. The research results indicate that: (1) the maximum Mises stresses and equivalent plastic strains at the matrix increase with the fuel particle diameters; the effects of particle diameters on the maximum first principal stresses vary with burnup, and the considered case with the largest particle diameter holds the maximum values all along; (2) at the cladding near the interface between the fuel meat and the cladding, the Mises stresses and the first principal stresses undergo major changes with increasing burnup, and different variations exist for different particle diameter cases; (3) the maximum Mises stresses at the fuel particles rise with the particle diameters.

  15. Multilayered sulphonated polysulfone/silica composite membranes for fuel cell applications

    International Nuclear Information System (INIS)

    Padmavathi, Rajangam; Karthikumar, Rajendhiran; Sangeetha, Dharmalingam

    2012-01-01

    Highlights: ► Multilayered membranes were fabricated with SPSu. ► Aminated polysulfone and silica were used as the layers in order to prevent the crossover of methanol. ► The methanol permeability and selectivity ratio proved a strong influence on DMFC application. ► The suitability of the multilayered membranes was studied in the lab made set-ups of PEMFC and DMFC. - Abstract: Polymer electrolyte membranes used in proton exchange membrane fuel cell (PEMFC) and direct methanol fuel cell (DMFC) suffer from low dimensional stability. Hence multilayered membranes using sulfonated polysulfone (SPSu) and silica (SiO 2 ) were fabricated to alter such properties. The introduction of an SiO 2 layer between two layers of SPSu to form the multilayered composite membrane enhanced its dimensional stability, but slightly lowered its proton conductivity when compared to the conventional SPSu/SiO 2 composite membrane. Additionally, higher water absorption, lower methanol permeability and higher flame retardancy were also observed in this newly fabricated multilayered membrane. The performance evaluation of the 2 wt% SiO 2 loaded multilayered membrane in DMFC showed a maximum power density of 86.25 mW cm −2 , which was higher than that obtained for Nafion 117 membrane (52.8 mW cm −2 ) in the same single cell test assembly. Hence, due to the enhanced dimensional stability, reduced methanol permeability and higher maximum power density, the SPSu/SiO 2 /SPSu multilayered membrane can be a viable and a promising candidate for use as an electrolyte membrane in DMFC applications, when compared to Nafion.

  16. Proton conductive montmorillonite-Nafion composite membranes for direct ethanol fuel cells

    Science.gov (United States)

    Wu, Xiu-Wen; Wu, Nan; Shi, Chun-Qing; Zheng, Zhi-Yuan; Qi, Hong-Bin; Wang, Ya-Fang

    2016-12-01

    The preparation of Nafion membranes modified with montmorillonites is less studied, and most relative works mainly applied in direct methanol fuel cells, less in direct ethanol fuel cells. Organic/inorganic composite membranes are prepared with different montmorillonites (Ca-montmorillonite, Na-montmorillonite, K-montmorillonite, Mg-montmorillonite, and H-montmorillonite) and Nafion solution via casting method at 293 K in air, and with balance of their proton conductivity and ethanol permeability. The ethanol permeability and proton conductivity of the membranes are comparatively studied. The montmorillonites can well decrease the ethanol permeability of the membranes via inserted them in the membranes, while less decrease the proton conductivities of the membranes depending on the inserted amount and type of montmorillonites. The proton conductivities of the membranes are between 36.0 mS/cm and 38.5 mS/cm. The ethanol permeability of the membranes is between 0.69 × 10-6 cm2/s and 2.67 × 10-6 cm2/s.

  17. Polybenzimidazole/Mxene composite membranes for intermediate temperature polymer electrolyte membrane fuel cells

    Science.gov (United States)

    Fei, Mingming; Lin, Ruizhi; Deng, Yuming; Xian, Hongxi; Bian, Renji; Zhang, Xiaole; Cheng, Jigui; Xu, Chenxi; Cai, Dongyu

    2018-01-01

    This report demonstrated the first study on the use of a new 2D nanomaterial (Mxene) for enhancing membrane performance of intermediate temperature (>100 °C) polymer electrolyte membrane fuel cells (ITPEMFCs). In this study, a typical Ti3C2T x -MXene was synthesized and incorporated into polybenzimidazole (PBI)-based membranes by using a solution blending method. The composite membrane with 3 wt% Ti3C2T x -MXene showed the proton conductivity more than 2 times higher than that of pristine PBI membrane at the temperature range of 100 °C-170 °C, and led to substantial increase in maximum power density of fuel cells by ˜30% tested at 150 °C. The addition of Ti3C2T x -MXene also improved the mechanical properties and thermal stability of PBI membranes. At 3 wt% Ti3C2T x -MXene, the elongation at break of phosphoric acid doped PBI remained unaffected at 150 °C, and the tensile strength and Young’s modulus was increased by ˜150% and ˜160%, respectively. This study pointed out promising application of MXene in ITPEMFCs.

  18. Effect of energy taxation on fuel choice and emissions

    International Nuclear Information System (INIS)

    Leino, P.; Kosunen, P.; Rauhamaeki, J.

    1997-01-01

    The aim of the project was to study how various tax models for power plant fuels affect the fuel consumption and emissions of particles, sulphur dioxide (SO 2 ), nitrogen oxide (NO x ) and carbon dioxide (CO 2 ). First, the development of Finnish energy taxation is discussed, followed by a survey of the energy production structure for 1994. For this purpose, it was necessary to prepare a large boiler database, which covers about 95 % of the fuel consumption of Finnish energy production. The boiler database was used to calculate the emissions of particles, SO 2 , NO x and CO 2 in 1994. The year 2010 selected under review is the year by which the Ministry of Trade and Industry has prepared their primary energy consumption estimates. Four different alternatives were studied as future tax models. In the first alternative taxation would be as it in years 1995-1996 and in the second alternative taxation would be as in January 1997. In the third alternative the Finnish application of EU taxes would be in force in full, i.e., the tax on heavy fuel oil would be 10 US dollars a barrel. In the fourth alternative there would be no taxes on fuels. The boiler database was used to find out how the consumption distribution of the fuels used in 2010 would change in the various tax models. The tax models affect most the position of fuel peat and natural gas in Finland. If the EU alternative, which is favourable for fuel peat and natural gas, comes true, the consumption of fuel peat will grow by two thirds and the consumption of natural gas will more than double from the present level. If the taxation is as 1 January 1997, the consumption of peat will remain the same as today and the consumption of natural gas will grow by about 50 %. However, if there are no taxes on fuels, the consumption of fuel peat will fall by almost a third and the consumption of natural gas will remain the same as expected at the existing and planned plants. The effect of the various tax models on emissions

  19. Fundamental characterization of alternate fuel effects in continuous combustion systems

    Energy Technology Data Exchange (ETDEWEB)

    Blazowski, W.S.; Edelman, R.B.; Harsha, P.T.

    1978-09-11

    The overall objective of this contract is to assist in the development of fuel-flexible combustion systems for gas turbines as well as Rankine and Stirling cycle engines. The primary emphasis of the program is on liquid hydrocarbons produced from non-petroleum resouces. Fuel-flexible combustion systems will provide for more rapid transition of these alternate fuels into important future energy utilization centers (especially utility power generation with the combined cycle gas turbine). The specific technical objectives of the program are to develop an improved understanding of relationships between alternate fuel properties and continuous combustion system effects, and to provide analytical modeling/correlation capabilities to be used as design aids for development of fuel-tolerant combustion systems. Efforts this past year have been to evaluate experimental procedures for studying alternate fuel combustion effects and to determine current analytical capabilities for prediction of these effects. Jet Stirred Combustor studies during this period have produced new insights into soot formation in strongly backmixed systems and have provided much information for comparison with analytical predictions. The analytical effort included new applications of quasi-global modeling techniques as well as comparison of prediction with the experimental results generated.

  20. Development of Dynamic Spent Nuclear Fuel Environmental Effect Analysis Model

    International Nuclear Information System (INIS)

    Jeong, Chang Joon; Ko, Won Il; Lee, Ho Hee; Cho, Dong Keun; Park, Chang Je

    2010-07-01

    The dynamic environmental effect evaluation model for spent nuclear fuel has been developed and incorporated into the system dynamic DANESS code. First, the spent nuclear fuel isotope decay model was modeled. Then, the environmental effects were modeled through short-term decay heat model, short-term radioactivity model, and long-term heat load model. By using the developed model, the Korean once-through nuclear fuel cycles was analyzed. The once-through fuel cycle analysis was modeled based on the Korean 'National Energy Basic Plan' up to 2030 and a postulated nuclear demand growth rate until 2150. From the once-through results, it is shown that the nuclear power demand would be ∼70 GWe and the total amount of the spent fuel accumulated by 2150 would be ∼168000 t. If the disposal starts from 2060, the short-term decay heat of Cs-137 and Sr-90 isotopes are W and 1.8x10 6 W in 2100. Also, the total long-term heat load in 2100 will be 4415 MW-y. From the calculation results, it was found that the developed model is very convenient and simple for evaluation of the environmental effect of the spent nuclear fuel

  1. Effects of ashes in solid fuels on fuel particle charging during combustion in an air stream

    Energy Technology Data Exchange (ETDEWEB)

    Zakharov, A.G.; Fialkov, B.S.; Mel' nichuk, A.Yu.; Khvan, L.A.

    1982-09-01

    Black coal from the Karaganda basin is mixed with sodium chloride and graphite. Coal characteristics are given in a table (density, ashes, content of silica, aluminium oxides, iron oxides, calcium oxides, potassium oxides and magnesium oxides). Effects of ash fluctuations on electric potential of fuel particles during combustion are analyzed. Analyses show that with increasing ash content electric potential of fuel particles decreases and reaches the minimum when ash content ranges from 70 to 80 %. Particles with electric potential are generated during chemical processes between carbon and oxygen when coal is burned in an air stream. (5 refs.) (In Russian)

  2. Study The Effect Extension Of Fuel Element Life Time In The Core Small Power Reactor

    International Nuclear Information System (INIS)

    Dewita, E.; Rusli, A.; Tuka, V.

    1998-01-01

    Mini power reactor is a low power nuclear reactor which mostly are designed especially to supply energy demand in the remote areas, such as for electricity generation, industries, desalination and district heating.The goal of the operation cycle extension to 3 - 5 years is to maximize the use of the fuel in order to achieve much cheaper energy generated. From the stand point of fuel element, in order to maximize the fuel life time there is a need to see all possible effects of extended life time to the fuel behavior in the core. This study has been carried out in order to obtain the understanding on all influencing factors to the fuel element behaviors at extended operation cycle whose results are expected to be useful as the input to fuel design and fabrication. The study has show that the material selection for fuel and cladding materials are the essential factor in maximizing the fuel life time. Development of cladding and fuel materials has been done, and shown that the new zirconium alloy, zircaloy, having composition of Zr-1,0 Sn-0,27 Fe-0,16 Cr-0,1 Nb-0,01 Ni has higher corrosion resistance and mechanical characteristics better than that of the standard zircaloy-4. Adding the Nb content (0,005-0,2 wt %), decreasing the Sn content until 0,5 wt %, and decreasing the ratio of Fe/Cr from 0,6 to 0,5 can increase resistance to corrosion, while decreasing the ratio of Fe and Cr from 0,3 to 0,7 wt % can increase the mechanical characteristics. To enhance the resistance to nodular corrosion in the BWR system, adding the Nb-Mo, Nb-W and Nb-V at low Sn zircaloy-2 can be done. In improving the fuel element it has been shown that adding niobium (Nb 2 O 5 -0,3 wt %) can enlarge the particle size of fuel hence improving the fuel performance

  3. Effect of ramp-cavity on hydrogen fueled scramjet combustor

    Directory of Open Access Journals (Sweden)

    J.V.S. Moorthy

    2014-03-01

    Full Text Available Sustained combustion and optimization of combustor are the two challenges being faced by combustion scientists working in the area of supersonic combustion. Thorough mixing, lower stagnation pressure losses, positive thrust and sustained combustion are the key issues in the field of supersonic combustion. Special fluid mechanism is required to achieve good mixing. To induce such mechanisms in supersonic inflows, the fuel injectors should be critically shaped incurring less flow losses. Present investigations are focused on the effect of fuel injection scheme on a model scramjet combustor performance. Ramps at supersonic flow generate axial vortices that help in macro-mixing of fuel with air. Interaction of shocks generated by ramps with the fuel stream generates boro-clinic torque at the air & liquid fuel interface, enhancing micro-mixing. Recirculation zones present in cavities increase the residence time of the combustible mixture. Making use of the advantageous features of both, a ramp-cavity combustor is designed. The combustor has two sections. First, constant height section consists of a backward facing step followed by ramps and cavities on both the top and bottom walls. The ramps are located alternately on top and bottom walls. The complete combustor width is utilized for the cavities. The second section of the combustor is diverging area section. This is provided to avoid thermal choking. In the present work gaseous hydrogen is considered as fuel. This study was mainly focused on the mixing characteristics of four different fuel injection locations. It was found that injecting fuel upstream of the ramp was beneficial from fuel spread point of view.

  4. Modeling fuels and fire effects in 3D: Model description and applications

    Science.gov (United States)

    Francois Pimont; Russell Parsons; Eric Rigolot; Francois de Coligny; Jean-Luc Dupuy; Philippe Dreyfus; Rodman R. Linn

    2016-01-01

    Scientists and managers critically need ways to assess how fuel treatments alter fire behavior, yet few tools currently exist for this purpose.We present a spatially-explicit-fuel-modeling system, FuelManager, which models fuels, vegetation growth, fire behavior (using a physics-based model, FIRETEC), and fire effects. FuelManager's flexible approach facilitates...

  5. Development of Innovative Accident Tolerant High Thermal Conductivity UO2-Diamond Composite Fuel Pellets

    Energy Technology Data Exchange (ETDEWEB)

    Tulenko, James [Univ. of Florida, Gainesville, FL (United States); Subhash, Ghatu [Univ. of Florida, Gainesville, FL (United States)

    2016-01-01

    The University of Florida (UF) evaluated a composite fuel consisting of UO2 powder mixed with diamond micro particles as a candidate as an accident-tolerant fuel (ATF). The research group had previous extensive experience researching with diamond micro particles as an addition to reactor coolant for improved plant thermal performance. The purpose of this research work was to utilize diamond micro particles to develop UO2-Diamond composite fuel pellets with significantly enhanced thermal properties, beyond that already being measured in the previous UF research projects of UO2 – SiC and UO2 – Carbon Nanotube fuel pins. UF is proving with the current research results that the addition of diamond micro particles to UO2 may greatly enhanced the thermal conductivity of the UO2 pellets producing an accident-tolerant fuel. The Beginning of life benefits have been proven and fuel samples are being irradiated in the ATR reactor to confirm that the thermal conductivity improvements are still present under irradiation.

  6. Effect of aviation fuel type and fuel injection conditions on the spray characteristics of pressure swirl and hybrid air blast fuel injectors

    Science.gov (United States)

    Feddema, Rick

    Feddema, Rick T. M.S.M.E., Purdue University, December 2013. Effect of Aviation Fuel Type and Fuel Injection Conditions on the Spray Characteristics of Pressure Swirl and Hybrid Air Blast Fuel Injectors. Major Professor: Dr. Paul E. Sojka, School of Mechanical Engineering Spray performance of pressure swirl and hybrid air blast fuel injectors are central to combustion stability, combustor heat management, and pollutant formation in aviation gas turbine engines. Next generation aviation gas turbine engines will optimize spray atomization characteristics of the fuel injector in order to achieve engine efficiency and emissions requirements. Fuel injector spray atomization performance is affected by the type of fuel injector, fuel liquid properties, fuel injection pressure, fuel injection temperature, and ambient pressure. Performance of pressure swirl atomizer and hybrid air blast nozzle type fuel injectors are compared in this study. Aviation jet fuels, JP-8, Jet A, JP-5, and JP-10 and their effect on fuel injector performance is investigated. Fuel injector set conditions involving fuel injector pressure, fuel temperature and ambient pressure are varied in order to compare each fuel type. One objective of this thesis is to contribute spray patternation measurements to the body of existing drop size data in the literature. Fuel droplet size tends to increase with decreasing fuel injection pressure, decreasing fuel injection temperature and increasing ambient injection pressure. The differences between fuel types at particular set conditions occur due to differences in liquid properties between fuels. Liquid viscosity and surface tension are identified to be fuel-specific properties that affect the drop size of the fuel. An open aspect of current research that this paper addresses is how much the type of aviation jet fuel affects spray atomization characteristics. Conventional aviation fuel specifications are becoming more important with new interest in alternative

  7. Normality test for determining the correction factor of isotopic composition in PWR spent fuel

    International Nuclear Information System (INIS)

    Lee, Y. H.; Shin, H. S.; Noh, S. K.; Seo, K. S.

    2001-01-01

    Normality test has been carried out for the ratios of the measured-to-calculated isotopic compositions in PWR spent fuel, using Shapiro-Wilk W, Lilliefors D, Cramer-von Mises and Anderson-Darling. All 38 istopices have been evaluated by means of the 1.5xIQR rule and then outliers have been discarded. As result, it seems that only 20 nuclides are satisfied with the normality at significance level 5 %. 18 Nuclides(samples) including U-235 have higher significance probability(p-value) than 25 % in W-test and p-values obtained by other three tests exceed the upper limit. Besides, in 6 nuclides including Pu-239, it seems that the p-values are between 5 % and 25 % in W test. From these results, in order to predict the isotopic compositions in the conservative point of view, it is decided that the correction factors for the nuclides are determined at the 95/95 probability and confidence level by using tolerance limit-methods with the assumption that only 18 nuclides are satisfied with thr normality

  8. Oxidation behaviour and electrical properties of cobalt/cerium oxide composite coatings for solid oxide fuel cell interconnects

    DEFF Research Database (Denmark)

    Harthøj, Anders; Holt, Tobias; Møller, Per

    2015-01-01

    This work evaluates the performance of cobalt/cerium oxide (Co/CeO2) composite coatings and pure Co coatings to be used for solid oxide fuel cell (SOFC) interconnects. The coatings are electroplated on the ferritic stainless steels Crofer 22 APU and Crofer 22H. Coated and uncoated samples...

  9. Impact of fuel composition on the recirculation zone structure and its role in lean premixed flame anchoring

    KAUST Repository

    Hong, Seunghyuck; Shanbhogue, Santosh J.; Ghoniem, Ahmed F.

    2015-01-01

    ) and chemiluminescence measurements for C3H8/H2/air lean premixed flames stabilized in a backward-facing step combustor. Results show an intricate coupling between the flame anchoring and the RZ structure and length. For a fixed fuel composition, at relatively low

  10. DUPIC fuel compatibility assessment

    Energy Technology Data Exchange (ETDEWEB)

    Choi, Hang Bok; Rho, G. H.; Park, J. W. [and others

    2000-03-01

    The purpose of this study is to assess the compatibility of DUPIC(Direct Use of Spent PWR Fuel in CANDU Reactors) fuel with the current CANDU 6 reactor, which is one of the technology being developed to utilize the spent PWR fuel in CANDU reactors. The phase 1 study of this project includes the feasibility analysis on applicability of the current core design method, the feasibility analysis on operation of the DUPIC fuel core, the compatibility analysis on individual reactor system, the sensitivity analysis on the fuel composition, and the economic analysis on DUPIC fuel cycle. The results of the validation calculations have confirmed that the current core analysis system is acceptable for the feasibility study of the DUPIC fuel compatibility analysis. The results of core simulations have shown that both natural uranium and DUPIC fuel cores are almost the same from the viewpoint of the operational performance. For individual reactor system including reactively devices, the functional requirements of each system are satisfied in general. However, because of the pronounced power flattening in the DUPIC core, the radiation damage on the critical components increases, which should be investigated more in the future. The DUPIC fuel composition heterogeneity dose not to impose any serious effect on the reactor operation if the fuel composition is adjusted. The economics analysis has been performed through conceptual design studies on the DUPIC fuel fabrication, fuel handling in a plant, and spent fuel disposal, which has shown that the DUPIC fuel cycle is comparable to the once-trough fuel cycle considering uncertainties associated with unit costs of the fuel cycle components. The results of Phase 1 study have shown that it is feasible to use the DUPIC fuel in CANDU reactors without major changes in hardware. However further studies are required to confirm the safety of the reactor under accident condition.

  11. DUPIC fuel compatibility assessment

    International Nuclear Information System (INIS)

    Choi, Hang Bok; Rho, G. H.; Park, J. W. and others

    2000-03-01

    The purpose of this study is to assess the compatibility of DUPIC(Direct Use of Spent PWR Fuel in CANDU Reactors) fuel with the current CANDU 6 reactor, which is one of the technology being developed to utilize the spent PWR fuel in CANDU reactors. The phase 1 study of this project includes the feasibility analysis on applicability of the current core design method, the feasibility analysis on operation of the DUPIC fuel core, the compatibility analysis on individual reactor system, the sensitivity analysis on the fuel composition, and the economic analysis on DUPIC fuel cycle. The results of the validation calculations have confirmed that the current core analysis system is acceptable for the feasibility study of the DUPIC fuel compatibility analysis. The results of core simulations have shown that both natural uranium and DUPIC fuel cores are almost the same from the viewpoint of the operational performance. For individual reactor system including reactively devices, the functional requirements of each system are satisfied in general. However, because of the pronounced power flattening in the DUPIC core, the radiation damage on the critical components increases, which should be investigated more in the future. The DUPIC fuel composition heterogeneity dose not to impose any serious effect on the reactor operation if the fuel composition is adjusted. The economics analysis has been performed through conceptual design studies on the DUPIC fuel fabrication, fuel handling in a plant, and spent fuel disposal, which has shown that the DUPIC fuel cycle is comparable to the once-trough fuel cycle considering uncertainties associated with unit costs of the fuel cycle components. The results of Phase 1 study have shown that it is feasible to use the DUPIC fuel in CANDU reactors without major changes in hardware. However further studies are required to confirm the safety of the reactor under accident condition

  12. Silver/iron oxide/graphitic carbon composites as bacteriostatic catalysts for enhancing oxygen reduction in microbial fuel cells

    Science.gov (United States)

    Ma, Ming; You, Shijie; Gong, Xiaobo; Dai, Ying; Zou, Jinlong; Fu, Honggang

    2015-06-01

    Biofilms from anode heterotrophic bacteria are inevitably formed over cathodic catalytic sites, limiting the performances of single-chamber microbial fuel cells (MFCs). Graphitic carbon (GC) - based nano silver/iron oxide (AgNPs/Fe3O4/GC) composites are prepared from waste pomelo skin and used as antibacterial oxygen reduction catalysts for MFCs. AgNPs and Fe3O4 are introduced in situ into the composites by one-step carbothermal reduction, enhancing their conductivity and catalytic activity. To investigate the effects of Fe species on the antibacterial and catalytic properties, AgNPs/Fe3O4/GC is washed with sulfuric acid (1 mol L-1) for 0.5 h, 1 h, and 5 h and marked as AgNPs/Fe3O4/GC-x (x = 0.5 h, 1 h and 5 h, respectively). A maximum power density of 1712 ± 35 mW m-2 is obtained by AgNPs/Fe3O4/GC-1 h, which declines by 4.12% after 17 cycles. Under catalysis of all AgNP-containing catalysts, oxygen reduction reaction (ORR) proceeds via the 4e- pathway, and no toxic effects to anode microorganisms result from inhibiting the cathodic biofilm overgrowth. With the exception of AgNPs/Fe3O4/GC-5 h, the AgNPs-containing composites exhibit remarkable power output and coulombic efficiency through lowering proton transfer resistance and air-cathode biofouling. This study provides a perspective for the practical application of MFCs using these efficient antibacterial ORR catalysts.

  13. Lead Isotopic Compositions of Selected Coals, Pb/Zn Ores and Fuels in China and the Application for Source Tracing.

    Science.gov (United States)

    Bi, Xiang-Yang; Li, Zhong-Gen; Wang, Shu-Xiao; Zhang, Lei; Xu, Rui; Liu, Jin-Ling; Yang, Hong-Mei; Guo, Ming-Zhi

    2017-11-21

    Lead (Pb) pollution emission from China is becoming a potential worldwide threat. Pb isotopic composition analysis is a useful tool to accurately trace the Pb sources of aerosols in atmosphere. In this study, a comprehensive data set of Pb isotopes for coals, Pb/Zn ores, and fuels from China was presented. The ratios of 206 Pb/ 207 Pb and 208 Pb/ 206 Pb in the coals were in the range of 1.114-1.383 and 1.791-2.317, similar to those from Europe, Oceania, and South Asia, but different from those from America (p fuels from in coals. Urban aerosols demonstrated similar Pb isotopic compositions to coals, Pb/Zn ores, and fuels in China. After removing the leaded gasoline, the Pb in aerosols is more radiogenic, supporting the heavy contribution of coal combustion to the atmospheric Pb pollution.

  14. Prognosis and comparison of performances of composite CERCER and CERMET fuels dedicated to transmutation of TRU in an EFIT ADS

    Science.gov (United States)

    Sobolev, V.; Uyttenhove, W.; Thetford, R.; Maschek, W.

    2011-07-01

    The neutronic and thermomechanical performances of two composite fuel systems: CERCER with (Pu,Np,Am,Cm)O 2-x fuel particles in ceramic MgO matrix and CERMET with metallic Mo matrix, selected for transmutation of minor actinides in the European Facility for Industrial Transmutation (EFIT), were analysed aiming at their optimisation. The ALEPH burnup code system, based on MNCPX and ORIGEN codes and JEFF3.1 nuclear data library, and the modern version of the fuel rod performance code TRAFIC were used for this analysis. Because experimental data on the properties of the mixed minor-actinide oxides are scarce, and the in-reactor behaviour of the T91 steel chosen as cladding, as well as of the corrosion protective layer, is still not well-known, a set of "best estimates" provided the properties used in the code. The obtained results indicate that both fuel candidates, CERCER and CERMET, can satisfy the fuel design and safety criteria of EFIT. The residence time for both types of fuel elements can reach about 5 years with the reactivity swing within ±1000 pcm, and about 22% of the loaded MA is transmuted during this period. However, the fuel centreline temperature in the hottest CERCER fuel rod is close to the temperature above which MgO matrix becomes chemically instable. Moreover, a weak PCMI can appear in about 3 years of operation. The CERMET fuel can provide larger safety margins: the fuel temperature is more than 1000 K below the permitted level of 2380 K and the pellet-cladding gap remains open until the end of operation.

  15. Novel composite membranes based on PBI and dicationic ionic liquids for high temperature polymer electrolyte membrane fuel cells

    International Nuclear Information System (INIS)

    Hooshyari, Khadijeh; Javanbakht, Mehran; Adibi, Mina

    2016-01-01

    Two types of innovative composite membranes based on polybenzimidazole (PBI) containing dicationic ionic liquid 1,3-di(3-methylimidazolium) propane bis (trifluoromethylsulfonyl) imide (PDC 3 ) and monocationic ionic liquid 1-hexyl-3-methylimidazolium bis (trifluoromethanesulfonyl) imide (PMC 6 ) are prepared as electrolyte for high temperature fuel cells applications under anhydrous conditions. The analyses of results display promising characteristics such as high proton conductivity and thermal stability. Moreover the fuel cell performance of PA doped PDC 3 composite membranes is enhanced in comparison with PA doped PMC 6 and PA doped PBI membranes at high temperatures. Dicationic ionic liquid with high number of charge carriers provides well-developed ionic channels which form facile pathways and considerably develop the anhydrous proton conductivity. The highest proton conductivity of 81 mS/cm is achieved for PA doped PDC 3 composite membranes with PBI/IL mole ratio: 4 at 180 °C. A power density of 0.44 W/cm 2 is obtained at 0.5 V and 180 °C for PA doped PDC 3 composite membranes, which proves that these developed composite membranes can be considered as most promising candidates for high temperature fuel cell applications with enhanced proton conductivity.

  16. Air quality effects of alternative fuels. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Guthrie, P.; Ligocki, M.; Looker, R.; Cohen, J.

    1997-11-01

    To support the Alternative Fuels Utilization Program, a comparison of potential air quality effects of alternative transportation fuels is being performed. This report presents the results of Phase 1 of this program, focusing on reformulated gasoline (RFG), methanol blended with 15 percent gasoline (M85), and compressed natural gas (CNG). The fuels are compared in terms of effects on simulated future concentrations of ozone and mobile source air toxics in a photochemical grid model. The fuel comparisons were carried out for the future year 2020 and assumed complete replacement of gasoline in the projected light-duty gasoline fleet by each of the candidate fuels. The model simulations were carried out for the areas surrounding Los Angeles and Baltimore/DC, and other (non-mobile) sources of atmospheric emissions were projected according to published estimates of economic and population growth, and planned emission control measures specific to each modeling domain. The future-year results are compared to a future-year run with all gasoline vehicle emissions removed. The results of the comparison indicate that the use of M85 is likely to produce similar ozone and air toxics levels as those projected from the use of RFG. Substitution of CNG is projected to produce significantly lower levels of ozone and the mobile source air toxics than those projected for RFG or M85. The relative benefits of CNG substitution are consistent in both modeling domains. The projection methodologies used for the comparison are subject to a large uncertainty, and modeled concentration distributions depend on meteorological conditions. The quantitative comparison of fuel effects is thus likely to be sensitive to alternative assumptions. The consistency of the results for two very different modeling domains, using very different base assumptions, lends credibility to the qualitative differentiation among these fuels. 32 refs., 42 figs., 47 tabs.

  17. Fuel Effects on Emissions From Non-Road Engines

    Energy Technology Data Exchange (ETDEWEB)

    Murtonen, T.; Nylund, N.

    2003-10-15

    The objective of this project was to study how fuel quality affects the exhaust emissions from different kinds of non-road engines. The project was divided into two parts: emissions from small gasoline engines and emissions from diesel engines. The measured small engines were a 2-stroke chainsaw engine, and a 4-stroke OHV engine, which could be used in different applications. Measurements were done with three different fuels, with and without catalyst. Also a comparison between biodegradable vs. conventional lubrication oil was done with the 2-stroke engine. Measurements were done according to ISO8178 standard. The results clearly demonstrate that using a good quality fuel (e.g. low sulphur, low aromatics) and a catalyst gives the best outcome in overall emission levels from these small engines. In the second part two different diesel engines were tested with five different fuels. Two of the fuels were biodiesel blends. The engines were chosen to represent old and new engine technology. The old engine (MY 1985) was produced before EU emission regulations were in place, and the new engine fulfilled the current EU Stage 2 emission limits. These measurements were also done according to the ISO8178 standard. With the new engine comparison with and without oxidation catalyst was done using two fuels. The results in general are similar compared to the results from the small gasoline engines: fuel quality has an effect on the emissions and when combining a good quality fuel (e.g. low sulphur, low aromatics) and an oxidation catalyst the emission levels are significantly reduced. Also some unregulated emission measurements were done but those results are not included to this report.

  18. Determining the elemental composition of fuels by bomb calorimetry and the inverse correlation of HHV with elemental composition

    DEFF Research Database (Denmark)

    Bech, Niels; Jensen, Peter Arendt; Dam-Johansen, Kim

    2009-01-01

    heating value. By analysing pure organic substances, literature data, and fuels it is demonstrated that the method can provide hydrogen estimates within +/- 0.7% daf. and carbon and sum of oxygen, nitrogen, and sulphur estimates within +/- 2% daf. for fuels containing less than 90% ash db., 2% nitrogen...

  19. Wood pellets. The cost-effective fuel

    International Nuclear Information System (INIS)

    Anon.

    2001-01-01

    The article is based on an interview with Juhani Hakkarainen of Vapo Oy. Wood pellets are used in Finland primarily to heat buildings such as schools and offices and in the home. They are equally suitable for use in larger installations such as district heating plants and power stations. According to him wood pellets are suitable for use in coal-fired units generating heat, power, and steam. Price-wise, wood pellets are a particularly competitive alternative for small coal-fired plants away from the coast. Price is not the only factor on their side, however. Wood pellets also offer a good environmental profile, as they burn cleanly and generate virtually no dust, an important plus in urban locations. The fact that pellets are a domestically produced fuel is an added benefit, as their price does not fluctuate in the same way that the prices of electricity, oil, coal, and natural gas do. The price of pellets is largely based on direct raw material and labour costs, which are much less subject to ups and downs

  20. Mathematical modeling of current density distribution in composite cathode of solid oxide fuel cells. Paper no. IGEC-1-099

    International Nuclear Information System (INIS)

    Kenney, B.; Karan, K.

    2005-01-01

    Cathodes processes in a solid oxide fuel cell (SOFC) are thought to dominate the overall electrochemical losses. One strategy for minimizing the cathode electrochemical losses in a state-of-the-art SOFC that utilize lanthanum-strontium-manganate (LSM) electrocatalyst and yttria-stabilized-zirconia (YSZ) electrolyte is to utilize composite cathodes comprising a mixture of LSM and YSZ. Composite cathodes improve performance by extending the active reaction zone from electrolyte-electrode interface to throughout the electrode. In this study, a two-dimensional composite cathode model was developed to assess cathode performance in terms of current density distributions. The model results indicate that geometric and microstructural parameters strongly influence current density distribution. In addition electrode composition affects magnitude and distribution of current. An optimum composition for equal-sized LSM/YSZ is 40 vol% LSM and 60 vol% YSZ at 900 o C. (author)

  1. Fuel-reduction management alters plant composition, carbon and nitrogen pools, and soil thaw in Alaskan boreal forest

    Science.gov (United States)

    Melvin, April M.; Celis, Gerardo; Johnstone, Jill F.; McGuire, A. David; Genet, Helene; Schuur, Edward A.G.; Rupp, T. Scott; Mack, Michelle C.

    2018-01-01

    Increasing wildfire activity in Alaska's boreal forests has led to greater fuel-reduction management. Management has been implemented to reduce wildfire spread, but the ecological impacts of these practices are poorly known. We quantified the effects of hand-thinning and shearblading on above- and belowground stand characteristics, plant species composition, carbon (C) and nitrogen (N) pools, and soil thaw across 19 black spruce (Picea mariana) dominated sites in interior Alaska treated 2-12 years prior to sampling. The density of deciduous tree seedlings was significantly higher in shearbladed areas compared to unmanaged forest (6.4 vs. 0.1 stems m−2), and unmanaged stands exhibited the highest mean density of conifer seedlings and layers (1.4 stems m−2). Understory plant community composition was most similar between unmanaged and thinned stands. Shearblading resulted in a near complete loss of aboveground tree biomass C pools while thinning approximately halved the C pool size (1.2 kg C m−2 compared to 3.1 kg C m−2 in unmanaged forest). Significantly smaller soil organic layer (SOL) C and N pools were observed in shearbladed stands (3.2 kg C m−2 and 116.8 g N m−2) relative to thinned (6.0 kg C m−2 and 192.2 g N m−2) and unmanaged (5.9 kg C m−2 and 178.7 g N m−2) stands. No difference in C and N pool sizes in the uppermost 10 cm of mineral soil was observed among stand types. Total C stocks for measured pools was 2.6 kg C m−2 smaller in thinned stands and 5.8 kg C m−2smaller in shearbladed stands when compared to unmanaged forest. Soil thaw depth averaged 13 cm deeper in thinned areas and 46 cm deeper in shearbladed areas relative to adjacent unmanaged stands, although variability was high across sites. Deeper soil thaw was linked to shallower SOL depth for unmanaged stands and both management types, however for any given SOL depth, thaw tended to be deeper in shearbladed areas compared to unmanaged forest. These findings indicate

  2. Bacterial nanocellulose/Nafion composite membranes for low temperature polymer electrolyte fuel cells

    Science.gov (United States)

    Jiang, Gao-peng; Zhang, Jing; Qiao, Jin-li; Jiang, Yong-ming; Zarrin, Hadis; Chen, Zhongwei; Hong, Feng

    2015-01-01

    Novel nanocomposite membranes aimed for both proton-exchange membrane fuel cell (PEMFC) and direct methanol fuel cell (DMFC) are presented in this work. The membranes are based on blending bacterial nanocellulose pulp and Nafion (abbreviated as BxNy, where x and y indicates the mass ratio of bacterial cellulose to Nafion). The structure and properties of BxNy membranes are characterized by FTIR, SEM, TG, DMA and EIS, along with water uptake, swelling behavior and methanol permeability tests. It is found that the BxNy composite membranes with reinforced concrete-like structure show excellent mechanical and thermal stability regardless of annealing. The water uptake plus area and volume swelling ratios are all decreased compared to Nafion membranes. The proton conductivities of pristine and annealed B1N9 are 0.071 and 0.056 S cm-1, respectively, at 30 °C and 100% humidity. Specifically, annealed B1N1 exhibited the lowest methanol permeability of 7.21 × 10-7 cm2 s-1. Through the selectivity analysis, pristine and annealed B1N7 are selected to assemble the MEAs. The performances of annealed B1N7 in PEMFC and DMFC show the maximum power densities of 106 and 3.2 mW cm-2, respectively, which are much higher than those of pristine B1N7 at 25 °C. The performances of the pristine and annealed B1N7 reach a level as high as 21.1 and 20.4 mW cm-2 at 80 °C in DMFC, respectively.

  3. Alternative-Fuel Effects on Contrails & Cruise Emissions (ACCESS-2) Flight Experiment

    Science.gov (United States)

    Anderson, Bruce E.

    2015-01-01

    Although the emission performance of gas-turbine engines burning renewable aviation fuels have been thoroughly documented in recent ground-based studies, there is still great uncertainty regarding how the fuels effect aircraft exhaust composition and contrail formation at cruise altitudes. To fill this information gap, the NASA Aeronautics Research Mission Directorate sponsored the ACCESS flight series to make detailed measurements of trace gases, aerosols and ice particles in the near-field behind the NASA DC-8 aircraft as it burned either standard petroleum-based fuel of varying sulfur content or a 50:50 blend of standard fuel and a hydro-treated esters and fatty acid (HEFA) jet fuel produced from camelina plant oil. ACCESS 1, conducted in spring 2013 near Palmdale CA, focused on refining flight plans and sampling techniques and used the instrumented NASA Langley HU-25 aircraft to document DC-8 emissions and contrails on five separate flights of approx.2 hour duration. ACCESS 2, conducted from Palmdale in May 2014, engaged partners from the Deutsches Zentrum fuer Luft- und Raumfahrt (DLR) and National Research Council-Canada to provide additional scientific expertise and sampling aircraft (Falcon 20 and CT-133, respectively) with more extensive trace gas, particle, or air motion measurement capability. Eight, muliti-aircraft research flights of 2 to 4 hour duration were conducted to document the emissions and contrail properties of the DC-8 as it 1) burned low sulfur Jet A, high sulfur Jet A or low sulfur Jet A/HEFA blend, 2) flew at altitudes between 6 and 11 km, and 3) operated its engines at three different fuel flow rates. This presentation further describes the ACCESS flight experiments, examines fuel type and thrust setting impacts on engine emissions, and compares cruise-altitude observations with similar data acquired in ground tests.

  4. Boiling transition phenomenon in BWR fuel assemblies effect of fuel spacer shape on critical power

    International Nuclear Information System (INIS)

    Yamamoto, Yasushi; Morooka, Shin-ichi; Mitsutake, Toru; Yokobori, Seiichi; Kimura, Jiro.

    1996-01-01

    A thorough understanding of the thermal-hydraulic phenomena near fuel spacer is necessary for the accurate prediction of the critical power of BWR fuel assemblies, and is thus essential for effective developments of a new BWR fuel assembly. The main purpose of this study is to develop an accurate method for predicting the effect of spacer shapes on critical power. Tests have been conducted under actual BWR operating conditions, using an annulus flow channel consisting of a heated rod and circular-tube channel, and BWR simulated 4x4 rod bundles with heater rods unheated just upsteam of spacer. The effect of spacer shapes on critical power was predicted analytically based on the droplet deposition rate estimation. The droplet deposition rate for different spacer shapes was calculated using a single-phase flow model. The prediction results were compared with the test results for the annulus flow channel using ring-type spacers. Analytical results of critical power agreed with measured critical power from point of the effects of changes in the rod-spacer clearance and the spacer thickness on critical power. (author)

  5. Effect of Biodiesel Fuel Injection Timing and Venture for Gaseous Fuel Induction on the Performance, Emissions and Combustion Characteristics of Dual Fuel Engine

    Directory of Open Access Journals (Sweden)

    Mallikarjun Bhovi

    2018-02-01

    Full Text Available Advancing or retarding pilot fuel injection timing in a diesel engine provided with either conventional mechanical fuel injection (CMFIS or high pressure injection as in common rail fuel injection (CRDI systems can significantly affect its performance and tail pipe emissions. Performance of diesel engine when fueled with various biofuels as well as gaseous fuels tends to vary with subsequent changes in pilot fuel injection timings. Biodiesel derived from rubber seed oil called Rubber Seed Oil Methyl Ester (RuOME and hydrogen (H2 and hydrogen enriched compressed natural gas called (HCNG both being renewable fuels when used in diesel engines modified to operate in dual fuel mode can provide complete replacement for fossil diesel. In the present study, effect of injection timings and venture design for gas mixing on the performance, combustion and emission characteristics of dual fuel engine fitted with both CMFIS and CRDI injection systems and operated on RuOME and HCNG/hydrogen has been investigated. Results showed that high pressure CRDI assisted injection of RuOME with optimized mixing chamber (carburetor for hydrogen induction in dual fuel engine performed improved compared to that with CMFIS. In addition, for the same fuel combinations, CRDI resulted in lower biodiesel consumption, lower carbon monoxide (BSCO and hydrocarbon (BSHC emissions and increased NOx emissions than CMFIS operation.

  6. Light-duty vehicle fuel economy improvements, 1979--1998: A consumer purchase model of corporate average fuel economy, fuel price, and income effects

    Science.gov (United States)

    Chien, David Michael

    2000-10-01

    The Energy Policy and Conservation Act of 1975, which created fuel economy standards for automobiles and light trucks, was passed by Congress in response to the rapid rise in world oil prices as a result of the 1973 oil crisis. The standards were first implemented in 1978 for automobiles and 1979 for light trucks, and began with initial standards of 18 MPG for automobiles and 17.2 MPG for light trucks. The current fuel economy standards for 1998 have been held constant at 27.5 MPG for automobiles and 20.5 MPG for light trucks since 1990--1991. While actual new automobile fuel economy has almost doubled from 14 MPG in 1974 to 27.2 MPG in 1994, it is reasonable to ask if the CAFE standards are still needed. Each year Congress attempts to pass another increase in the Corporate Average Fuel Economy (CAFE) standard and fails. Many have called for the abolition of CAFE standards citing the ineffectiveness of the standards in the past. In order to determine whether CAFE standards should be increased, held constant, or repealed, an evaluation of the effectiveness of the CAFE standards to date must be established. Because fuel prices were rising concurrently with the CAFE standards, many authors have attributed the rapid rise in new car fuel economy solely to fuel prices. The purpose of this dissertation is to re-examine the determinants of new car fuel economy via three effects: CAFE regulations, fuel price, and income effects. By measuring the marginal effects of the three fuel economy determinants upon consumers and manufacturers choices, for fuel economy, an estimate was made of the influence of each upon new fuel economy. The conclusions of this dissertation present some clear signals to policymakers: CAFE standards have been very effective in increasing fuel economy from 1979 to 1998. Furthermore, they have been the main cause of fuel economy improvement, with income being a much smaller component. Furthermore, this dissertation has suggested that fuel prices have

  7. Water confinement effects on fuel assembly motion and damping

    International Nuclear Information System (INIS)

    Brenneman, B.; Shah, S.J.; Williams, G.T.; Strumpell, J.H.

    2003-01-01

    It has been established by other authors that the accelerations of the water confined by the reactor core baffle plates has a significant effect on the responses of all the fuel assemblies during LOCA or seismic transients. This particular effect is a consequence of the water being essentially incompressible, and thus experiencing the same horizontal accelerations as the imposed baffle plate motions. These horizontal accelerations of the fluid induce lateral pressure gradients that cause horizontal buoyancy forces on any submerged structures. These forces are in the same direction as the baffle accelerations and, for certain frequencies at least, tend to reduce the relative displacements between the fuel and baffle plates. But there is another confinement effect - the imposed baffle plate velocities must also be transmitted to the water. If the fuel assembly grid strips are treated as simple hydro-foils, these horizontal velocity components change the fluid angle of attack on each strip, and thus may induce large horizontal lift forces on each grid in the same direction as the baffle plate velocity. There is a similar horizontal lift due to inclined flow over the rods when axial flow is present. These combined forces appear to always reduce the relative displacements between the fuel and baffle plates for any significant axial flow velocity. Modeling this effect is very simple. It was shown in previous papers that the mechanism for the large fuel assembly damping due to axial flow may be the hydrodynamic forces on the grid strips, and that this is very well represented by discrete viscous dampers at each grid elevation. To include the imposed horizontal water velocity effects, on both the grids and rods, these dampers are simply attached to the baffle plate rather than 'ground'. The large flow-induced damping really acts in a relative reference frame rather than an absolute or inertial reference frame, and thus it becomes a flow-induced coupling between the fuel

  8. Effect of composition on the polarization and ohmic resistances of ...

    Indian Academy of Sciences (India)

    2017-06-09

    Jun 9, 2017 ... Solid oxide fuel cell; composite cathodes; polarization resistance; ohmic resistance; ... of Oad on LSM, (iii) conversion of Oad into oxygen ion ... ions need to flow through the low temperature sintered ..... TPB's are present) suggest the formation of face-to-face con- ..... calculated using the following equation.

  9. Laser scabbling for nuclear decommissioning: Effect of concrete composition on volume removal efficiency

    International Nuclear Information System (INIS)

    Peach, B.; Petkovski, M.; Blackburn, J.; Engelberg, D.L.

    2015-01-01

    The objective of this study was to determine the effect of concrete composition and moisture content on volume removal with the overarching goal to identify mechanism(s) responsible for laser scabbling. Tests under application of fixed laser parameters showed that concrete composition had a significant effect on material removal but the investigation into moisture content was inconclusive. The mechanical properties and size of coarse aggregates seemed to affect scabbling efficiency, rather than their chemical properties. The presence of pulverized fuel ash as a cement replacement material indicated to be a major factor that determines material removal volumes. (authors)

  10. A comparison of the C{sub 2}-C{sub 9} hydrocarbon compositions of vehicle fuels and urban air in Dublin, Ireland

    Energy Technology Data Exchange (ETDEWEB)

    Broderick, B M; Marnane, I S [Trinity College, Dublin (Ireland). Dept. of Civil, Structural and Environmental Engineering

    2002-07-01

    Hourly roadside hydrocarbon concentrations were measured over a six-week period at a heavily trafficked junction in Dublin city centre. Samples of ten typical leaded and unleaded petrol fuels used in Irish vehicles were also collected and their hydrocarbon compositions determined. The measured ambient hydrocarbon concentrations are presented, as are the properties of each of the analysed fuels. Comparison of the ambient hydrocarbon concentrations and the fuel hydrocarbon composition reveals a strong correlation for most hydrocarbons, except those compounds that were wholly combustion derived (i.e. not present in the fuel). Different characteristics were noted for aromatics, alkanes and alkenes. The comparison of roadside ambient air and fuel hydrocarbon content agrees well with other studies that have compared fuel content and exhaust composition. The relative impacts of exhaust and evaporative emissions on roadside hydrocarbon concentrations are apparent. (Author)

  11. Applying Thermodynamics to Fossil Fuels: Heats of Combustion from Elemental Compositions.

    Science.gov (United States)

    Lloyd, William G.; Davenport, Derek A.

    1980-01-01

    Discussed are the calculations of heats of combustions of some selected fossil fuel compounds such as some foreign shale oils and United States coals. Heating values for coal- and petroleum-derived fuel oils are also presented. (HM)

  12. Theory of precipitation effects on dead cylindrical fuels

    Science.gov (United States)

    Michael A. Fosberg

    1972-01-01

    Numerical and analytical solutions of the Fickian diffusion equation were used to determine the effects of precipitation on dead cylindrical forest fuels. The analytical solution provided a physical framework. The numerical solutions were then used to refine the analytical solution through a similarity argument. The theoretical solutions predicted realistic rates of...

  13. Effect of samaria-doped ceria (SDC) interlayer on the performance of La0.6Sr0.4Co0.2Fe0.8O3-δ/SDC composite oxygen electrode for reversible solid oxide fuel cells

    International Nuclear Information System (INIS)

    Shimura, Kazuki; Nishino, Hanako; Kakinuma, Katsuyoshi; Brito, Manuel E.; Uchida, Hiroyuki

    2017-01-01

    In order to establish clear criteria for designing highly active and highly durable oxygen electrode for reversible solid oxide fuel cells, we have focused on the effect of samaria-doped ceria (SDC) interlayers prepared on YSZ solid electrolyte surface on the performances of La 0.6 Sr 0.4 Co 0.2 Fe 0.8 O 3-δ (LSCF)-SDC composite oxygen electrode. Symmetrical cells with the configuration, LSCF-SDC|SDC interlayer|YSZ|SDC interlayer|LSCF-SDC, were constructed. We prepared two kinds of SDC interlayers, one from a mixed solution of cerium 2-ethylhexanoate (denoted as octoate) and samarium octoates (o-interlayer) and another from a mixed solution of cerium and samarium nitrates (n-interlayer). The LSCF-SDC electrodes with o-interlayer and n-interlayer exhibited very similar performances in both the anodic and cathodic reactions at 900 °C. When temperature was decreased to 800 °C, an increase in overpotentials was observed. However, the LSCF-SDC electrode with o-interlayer exhibited superior performance to that with n-interlayer. It was found that the entire surface of the YSZ electrolyte disk was well covered with a dense o-interlayer of uniform thickness. Such an interlayer enables uniform transport of oxide ions to and from the LSCF-SDC electrode, resulting in an enlarged effective reaction zone (ERZ). The I-E performance of the LSCF-SDC|o-interlayer|YSZ cell was found to be comparable to that of the identical electrode prepared on a dense SDC sintered electrolyte disk (as a reference). This observation supports our views regarding the essential role of a dense interlayer with uniform thickness in enhancing the performance of reversible solid oxide cells.

  14. Response of the global climate to changes in atmospheric chemical composition due to fossil fuel burning

    Science.gov (United States)

    Hameed, S.; Cess, R. D.; Hogan, J. S.

    1980-01-01

    Recent modeling of atmospheric chemical processes (Logan et al, 1978; Hameed et al, 1979) suggests that tropospheric ozone and methane might significantly increase in the future as the result of increasing anthropogenic emissions of CO, NO(x), and CH4 due to fossil fuel burning. Since O3 and CH4 are both greenhouse gases, increases in their concentrations could augment global warming due to larger future amounts of atmospheric CO2. To test the possible climatic impact of changes in tropospheric chemical composition, a zonal energy-balance climate model has been combined with a vertically averaged tropospheric chemical model. The latter model includes all relevant chemical reactions which affect species derived from H2O, O2, CH4, and NO(x). The climate model correspondingly incorporates changes in the infrared heating of the surface-troposphere system resulting from chemically induced changes in tropospheric ozone and methane. This coupled climate-chemical model indicates that global climate is sensitive to changes in emissions of CO, NO(x) and CH4, and that future increases in these emissions could augment global warming due to increasing atmospheric CO2.

  15. Thermal stress effects in intermetallic matrix composites

    Science.gov (United States)

    Wright, P. K.; Sensmeier, M. D.; Kupperman, D. S.; Wadley, H. N. G.

    1993-01-01

    Intermetallic matrix composites develop residual stresses from the large thermal expansion mismatch (delta-alpha) between the fibers and matrix. This work was undertaken to: establish improved techniques to measure these thermal stresses in IMC's; determine residual stresses in a variety of IMC systems by experiments and modeling; and, determine the effect of residual stresses on selected mechanical properties of an IMC. X ray diffraction (XRD), neutron diffraction (ND), synchrotron XRD (SXRD), and ultrasonics (US) techniques for measuring thermal stresses in IMC were examined and ND was selected as the most promising technique. ND was demonstrated on a variety of IMC systems encompassing Ti- and Ni-base matrices, SiC, W, and Al2O3 fibers, and different fiber fractions (Vf). Experimental results on these systems agreed with predictions of a concentric cylinder model. In SiC/Ti-base systems, little yielding was found and stresses were controlled primarily by delta-alpha and Vf. In Ni-base matrix systems, yield strength of the matrix and Vf controlled stress levels. The longitudinal residual stresses in SCS-6/Ti-24Al-llNb composite were modified by thermomechanical processing. Increasing residual stress decreased ultimate tensile strength in agreement with model predictions. Fiber pushout strength showed an unexpected inverse correlation with residual stress. In-plane shear yield strength showed no dependence on residual stress. Higher levels of residual tension led to higher fatigue crack growth rates, as suggested by matrix mean stress effects.

  16. Design and analytic evaluation of a rim effect reduction type LWR fuel for extending burnup

    International Nuclear Information System (INIS)

    Matsumura, Tetsuo; Kameyama, Takanori; Kinoshita, Motoyasu

    1991-01-01

    We have designed a new concept fuel design 'Rim effect reduction type fuel' which has thin natural UO 2 layer on surface of a UO2 pellet. Our neutronic analyses with ANRB code show this fuel design can reduce rim effect (burnup at plelet rim) by about 30 GWd/t comparing a normal fuel. It is known that a high burnup fuel has different microstructure from as-fabricated one at fuel rim (which is called as rim region) due to rim effect. Therefore this fuel design can expect smaller rim region than a normal fuel. Our fuel performance analyses with EIMUS code show this fuel design can reduce fuel center temperature at high burnup if thermal conductivity of fuel pellet decreases with burnup in inverse proportion. However, this fuel design increases fuel center temperature at low and middle burnup than a normal fuel due to increase of thermal power density at pellet center. Additionally Irradiation experiment of this fuel design can be considered to offer important data which make clear the relation between rim effect and fuel performance. (author)

  17. A Multi-Layered Ceramic Composite for Impermeable Fuel Cladding for COmmercial Wate Reactors

    Energy Technology Data Exchange (ETDEWEB)

    Feinroth, Herbert

    2008-03-03

    A triplex nuclear fuel cladding is developed to further improve the passive safety of commercial nuclear plants, to increase the burnup and durablity of nuclear fuel, to improve the power density and economics of nuclear power, and to reduce the amount of spent fuel requiring disposal or recycle.

  18. Radionuclide compositions of spent fuel and high level waste for the uranium and plutonium fuelled PWR

    International Nuclear Information System (INIS)

    Fairclough, M.P.; Tymons, B.J.

    1985-06-01

    The activities of a selection of radionuclides are presented for three types of reactor fuel of interest in radioactive waste management. The fuel types are for a uranium 'burning' PWR, a plutonium 'burning' PWR using plutonium recycled from spent uranium fuel and a plutonium 'burning' PWR using plutonium which has undergone multiple recycle. (author)

  19. Effects of Fuel Ethanol Use on Fuel-Cycle Energy and Greenhouse Gas Emissions; TOPICAL

    International Nuclear Information System (INIS)

    C. Saricks; D. Santini; M. Wang

    1999-01-01

    We estimated the effects on per-vehicle-mile fuel-cycle petroleum use, greenhouse gas (GHG) emissions, and energy use of using ethanol blended with gasoline in a mid-size passenger car, compared with the effects of using gasoline in the same car. Our analysis includes petroleum use, energy use, and emissions associated with chemicals manufacturing, farming of corn and biomass, ethanol production, and ethanol combustion for ethanol; and petroleum use, energy use, and emissions associated with petroleum recovery, petroleum refining, and gasoline combustion for gasoline. For corn-based ethanol, the key factors in determining energy and emissions impacts include energy and chemical usage intensity of corn farming, energy intensity of the ethanol plant, and the method used to estimate energy and emissions credits for co-products of corn ethanol. The key factors in determining the impacts of cellulosic ethanol are energy and chemical usage intensity of biomass farming, ethanol yield per dry ton of biomass, and electricity credits in cellulosic ethanol plants. The results of our fuel-cycle analysis for fuel ethanol are listed below. Note that, in the first half of this summary, the reductions cited are per-vehicle-mile traveled using the specified ethanol/gasoline blend instead of conventional (not reformulated) gasoline. The second half of the summary presents estimated changes per gallon of ethanol used in ethanol blends. GHG emissions are global warming potential (GWP)-weighted, carbon dioxide (CO2)-equivalent emissions of CO2, methane (CH4), and nitrous oxide (N2O)

  20. Effects of Fuel Ethanol Use on Fuel-Cycle Energy and Greenhouse Gas Emissions

    International Nuclear Information System (INIS)

    C. Saricks; D. Santini; M. Wang

    1999-01-01

    We estimated the effects on per-vehicle-mile fuel-cycle petroleum use, greenhouse gas (GHG) emissions, and energy use of using ethanol blended with gasoline in a mid-size passenger car, compared with the effects of using gasoline in the same car. Our analysis includes petroleum use, energy use, and emissions associated with chemicals manufacturing, farming of corn and biomass, ethanol production, and ethanol combustion for ethanol; and petroleum use, energy use, and emissions associated with petroleum recovery, petroleum refining, and gasoline combustion for gasoline. For corn-based ethanol, the key factors in determining energy and emissions impacts include energy and chemical usage intensity of corn farming, energy intensity of the ethanol plant, and the method used to estimate energy and emissions credits for co-products of corn ethanol. The key factors in determining the impacts of cellulosic ethanol are energy and chemical usage intensity of biomass farming, ethanol yield per dry ton of biomass, and electricity credits in cellulosic ethanol plants. The results of our fuel-cycle analysis for fuel ethanol are listed below. Note that, in the first half of this summary, the reductions cited are per-vehicle-mile traveled using the specified ethanol/gasoline blend instead of conventional (not reformulated) gasoline. The second half of the summary presents estimated changes per gallon of ethanol used in ethanol blends. GHG emissions are global warming potential (GWP)-weighted, carbon dioxide (CO2)-equivalent emissions of CO2, methane (CH4), and nitrous oxide (N2O)

  1. Effect of compressive force on PEM fuel cell performance

    Science.gov (United States)

    MacDonald, Colin Stephen

    Polymer electrolyte membrane (PEM) fuel cells possess the potential, as a zero-emission power source, to replace the internal combustion engine as the primary option for transportation applications. Though there are a number of obstacles to vast PEM fuel cell commercialization, such as high cost and limited durability, there has been significant progress in the field to achieve this goal. Experimental testing and analysis of fuel cell performance has been an important tool in this advancement. Experimental studies of the PEM fuel cell not only identify unfiltered performance response to manipulation of variables, but also aid in the advancement of fuel cell modelling, by allowing for validation of computational schemes. Compressive force used to contain a fuel cell assembly can play a significant role in how effectively the cell functions, the most obvious example being to ensure proper sealing within the cell. Compression can have a considerable impact on cell performance beyond the sealing aspects. The force can manipulate the ability to deliver reactants and the electrochemical functions of the cell, by altering the layers in the cell susceptible to this force. For these reasons an experimental study was undertaken, presented in this thesis, with specific focus placed on cell compression; in order to study its effect on reactant flow fields and performance response. The goal of the thesis was to develop a consistent and accurate general test procedure for the experimental analysis of a PEM fuel cell in order to analyse the effects of compression on performance. The factors potentially affecting cell performance, which were a function of compression, were identified as: (1) Sealing and surface contact; (2) Pressure drop across the flow channel; (3) Porosity of the GDL. Each factor was analysed independently in order to determine the individual contribution to changes in performance. An optimal degree of compression was identified for the cell configuration in

  2. Discerning Chemical Composition and Mutagenic Effects of Soy Biodiesel PM

    Science.gov (United States)

    Exhaust particles from the combustion of traditional diesel fuel have been shown to lead to increases in adverse health effects such as impaired lung function, respiratory distress, and cardiovascular disease. This has resulted in an effort to find alternative fuels, such as soy...

  3. DETERMINING THE COMPOSITION OF HIGH TEMPERATURE COMBUSTION PRODUCTS OF FOSSIL FUEL BASED ON VARIATIONAL PRINCIPLES AND GEOMETRIC PROGRAMMING

    Directory of Open Access Journals (Sweden)

    Velibor V Vujović

    2011-01-01

    Full Text Available This paper presents the algorithm and results of a computer program for calculation of complex equilibrium composition for the high temperature fossil fuel combustion products. The method of determining the composition of high temperatures combustion products at the temperatures appearing in the open cycle MHD power generation is given. The determination of combustion product composition is based on minimization of the Gibbs free energy. The number of equations to be solved is reduced by using variational principles and a method of geometric programming and is equal to the sum of the numbers of elements and phases. A short description of the computer program for the calculation of the composition and an example of the results are also given.

  4. School Processes Mediate School Compositional Effects: Model Specification and Estimation

    Science.gov (United States)

    Liu, Hongqiang; Van Damme, Jan; Gielen, Sarah; Van Den Noortgate, Wim

    2015-01-01

    School composition effects have been consistently verified, but few studies ever attempted to study how school composition affects school achievement. Based on prior research findings, we employed multilevel mediation modeling to examine whether school processes mediate the effect of school composition upon school outcomes based on the data of 28…

  5. Global assesment of PCDD/F emissions from the Spanish cement sector. Effect of conventional/alternative fuels

    Energy Technology Data Exchange (ETDEWEB)

    Fabrellas, B.; Larrazabal, D.; Martinez, M.A.; Sanz, P.; Ruiz, M.L. [CIEMAT, Madrid (Spain); Abad, E.; Rivera, J. [IIQAB-CSIC, Barcelona (Spain)

    2004-09-15

    This paper presents the results of the survey on polychlorinated dibenzodioxin and dibenzofuran (PCDD/F) emissions to the air in cement manufacture sector carried out in Spain over the period 2000-2003. It includes 89 samples from 41 furnaces, which represents 69.5% of coverage. It constitutes the subsequent stage of the monitoring program presented previously, enlarging number of facilities assessed as well as considering plants operating with both conventional and waste-derived fuels. The purpose of this survey was to quantify the total emission of dioxins from cement manufacture sector, to study the effect of using waste-derived materials as alternative fuels on total PCDD/F emission and to calculate experimental emission factors. Finally, specific emission profiles were obtained for installations using both conventional fossil and residue-derived fuels and compared in order to establish the influence of fuel composition on PCDD/F releases.

  6. FY13 Summary Report on the Augmentation of the Spent Fuel Composition Dataset for Nuclear Forensics: SFCOMPO/NF

    Energy Technology Data Exchange (ETDEWEB)

    Brady Raap, Michaele C.; Lyons, Jennifer A.; Collins, Brian A.; Livingston, James V.

    2014-03-31

    This report documents the FY13 efforts to enhance a dataset of spent nuclear fuel isotopic composition data for use in developing intrinsic signatures for nuclear forensics. A review and collection of data from the open literature was performed in FY10. In FY11, the Spent Fuel COMPOsition (SFCOMPO) excel-based dataset for nuclear forensics (NF), SFCOMPO/NF was established and measured data for graphite production reactors, Boiling Water Reactors (BWRs) and Pressurized Water Reactors (PWRs) were added to the dataset and expanded to include a consistent set of data simulated by calculations. A test was performed to determine whether the SFCOMPO/NF dataset will be useful for the analysis and identification of reactor types from isotopic ratios observed in interdicted samples.

  7. Change of Composition in Metallic Fuel Slug of U-Zr Alloy from High-Temperature Annealing

    Energy Technology Data Exchange (ETDEWEB)

    Youn, Young Sang; Lee, Jeong Mook; Kim, Jong Yun; Kim, Jong Hwan; Song, Hoon [KAERI, Daejeon (Korea, Republic of)

    2016-09-15

    The U–Zr alloy is a candidate for fuel to be used as metallic fuel in sodium-cooled fast reactors (SFRs). Its chemical composition before and after annealing at the operational temperature of SFRs (610 .deg. C) was investigated using X-ray photoelectron spectroscopy, Raman spectroscopy, and X-ray diffraction. The original alloy surface contained uranium oxides with the U(IV) and U(VI) oxidation states, Zr{sub 2}O{sub 3}, and a low amount of uranium metal. After annealing at 610 .deg. C, the alloy was composed of uranium metal, uranium carbide, uranium oxide with the U(V) valence state, zirconium metal, and amorphous carbon. Meanwhile, X-ray diffraction data indicate that the bulk composition of the alloy remained unchanged.

  8. Change of Composition in Metallic Fuel Slug of U-Zr Alloy from High-Temperature Annealing

    International Nuclear Information System (INIS)

    Youn, Young Sang; Lee, Jeong Mook; Kim, Jong Yun; Kim, Jong Hwan; Song, Hoon

    2016-01-01

    The U–Zr alloy is a candidate for fuel to be used as metallic fuel in sodium-cooled fast reactors (SFRs). Its chemical composition before and after annealing at the operational temperature of SFRs (610 .deg. C) was investigated using X-ray photoelectron spectroscopy, Raman spectroscopy, and X-ray diffraction. The original alloy surface contained uranium oxides with the U(IV) and U(VI) oxidation states, Zr 2 O 3 , and a low amount of uranium metal. After annealing at 610 .deg. C, the alloy was composed of uranium metal, uranium carbide, uranium oxide with the U(V) valence state, zirconium metal, and amorphous carbon. Meanwhile, X-ray diffraction data indicate that the bulk composition of the alloy remained unchanged

  9. Computation of Effective Steady-State Creep of Porous Ni–YSZ Composites with Reconstructed Microstructures

    DEFF Research Database (Denmark)

    Kwok, Kawai; Jørgensen, Peter Stanley; Frandsen, Henrik Lund

    2015-01-01

    This paper investigates the effective steady-state creep response of porous Ni–YSZ composites used in solid oxide fuel cell applications by numerical homogenization based on three-dimensional microstructural reconstructions and steadystate creep properties of the constituent phases. The Ni phase...... is found to carry insignificant stress in the composite and has a negligible role in the effective creep behavior. Thus, when determining effective creep, porous Ni–YSZ composites can be regarded as porous YSZ in which the Ni phase is counted as additional porosity. The stress exponents of porous YSZ...... are the same as that of dense YSZ, but the effective creep rate increases by a factor of 8–10 due to porosity. The relationship of creep rate and volume fraction of YSZ computed by numerical homogenization is underestimated by most existing analytical models. The Ramakrishnan–Arunchalam creep model provides...

  10. Sanitary effects of fossil fuels; Effets sanitaires des combustibles fossiles

    Energy Technology Data Exchange (ETDEWEB)

    Nifenecker, H. [Centre National de la Recherche Scientifique (IN2P3/CNRS), 38 - Grenoble (France)

    2006-07-01

    In this compilation are studied the sanitary effects of fossil fuels, behavioral and environmental sanitary risks. The risks in connection with the production, the transport and the distribution(casting) are also approached for the oil(petroleum), the gas and the coal. Accidents in the home are evoked. The risks due to the atmospheric pollution are seen through the components of the atmospheric pollution as well as the sanitary effects of this pollution. (N.C.)

  11. Effect of high surface area activated carbon on thermal degradation of jet fuel

    Energy Technology Data Exchange (ETDEWEB)

    Gergova, K.; Eser, S.; Arumugam, R.; Schobert, H.H. [Pennsylvania State Univ., University Park, PA (United States)

    1995-05-01

    Different solid carbons added to jet fuel during thermal stressing cause substantial changes in pyrolytic degradation reactions. Activated carbons, especially high surface area activated carbons were found to be very effective in suppressing solid deposition on metal reactor walls during stressing at high temperatures (425 and 450{degrees}C). The high surface area activated carbon PX-21 prevented solid deposition on reactor walls even after 5h at 450{degrees}C. The differences seen in the liquid product composition when activated carbon is added indicated that the carbon surfaces affect the degradation reactions. Thermal stressing experiments were carried out on commercial petroleum-derived JPTS jet fuel. We also used n-octane and n-dodecane as model compounds in order to simplify the study of the chemical changes which take place upon activated carbon addition. In separate experiments, the presence of a hydrogen donor, decalin, together with PX-21 was also studied.

  12. Effects of vehicle type and fuel quality on real world toxic emissions from diesel vehicles

    Science.gov (United States)

    Nelson, Peter F.; Tibbett, Anne R.; Day, Stuart J.

    Diesel vehicles are an important source of emissions of air pollutants, particularly oxides of nitrogen (NO x), particulate matter (PM), and toxic compounds with potential health impacts including volatile organic compounds (VOCs) such as benzene and aldehydes, and polycyclic aromatic hydrocarbons (PAHs). Current developments in engine design and fuel quality are expected to reduce these emissions in the future, but many vehicles exceed 10 years of age and may make a major contribution to urban pollutant concentrations and related health impacts for many years. In this study, emissions of a range of toxic compounds are reported using in-service vehicles which were tested using urban driving cycles developed for Australian conditions. Twelve vehicles were chosen from six vehicle weight classes and, in addition, two of these vehicles were driven through the urban drive cycle using a range of diesel fuel formulations. The fuels ranged in sulphur content from 24 to 1700 ppm, and in total aromatics from 7.7 to 33 mass%. Effects of vehicle type and fuel composition on emissions are reported. The results show that emissions of these toxic species were broadly comparable to those observed in previous dynamometer and tunnel studies. Emissions of VOCs and smaller PAHs such as naphthalene, which are derived largely from the combustion process, appear to be related, and show relatively little variability when compared with the variability in emissions of aldehydes and larger PAHs. In particular, aldehyde emissions are highly variable and may be related to engine operating conditions. Fuels of lower sulphur and aromatic content did not have a significant influence on emissions of VOCs and aldehydes, but tended to result in lower emissions of PAHs. The toxicity of vehicle exhaust, as determined by inhalation risk and toxic equivalency factor (TEF)-weighted PAH emissions, was reduced with fuels of lower aromatic content.

  13. Driving for fun? Comparing the effect of fuel prices on weekday and weekend fuel consumption

    Energy Technology Data Exchange (ETDEWEB)

    Frondel, Manuel; Vance, Colin [Rheinisch-Westfaelisches Institut fuer Wirtschaftsforschung (RWI), Hohenzollernstr. 1-3, D-45128 Essen (Germany)

    2010-01-15

    Focusing on individual motorists in car-owning households in Germany, this paper investigates the determinants of automobile travel, with the specific aim of quantifying the effects of fuel prices and person-level attributes on travel conducted over a five-day week and weekend. Our analysis is predicated on the notion that car use is an individual decision, albeit one that is dependent on intra-household allocation processes, thereby building on a growing body of literature that has identified the importance of socioeconomic factors such as employment status, gender, and the presence of children in determining both access to and use of the car. To capture this two-stage decision process, we employ the two-part model, which consists of probit and OLS estimators, and derive elasticity estimates that incorporate both the discrete and continuous choices pertaining to car use. With fuel price elasticity estimates ranging between - 0.45 and - 0.50, our results suggest raising prices via fuel taxes to be a promising energy conservation and climate protection measure. (author)

  14. Driving for fun? Comparing the effect of fuel prices on weekday and weekend fuel consumption

    International Nuclear Information System (INIS)

    Frondel, Manuel; Vance, Colin

    2010-01-01

    Focusing on individual motorists in car-owning households in Germany, this paper investigates the determinants of automobile travel, with the specific aim of quantifying the effects of fuel prices and person-level attributes on travel conducted over a five-day week and weekend. Our analysis is predicated on the notion that car use is an individual decision, albeit one that is dependent on intra-household allocation processes, thereby building on a growing body of literature that has identified the importance of socioeconomic factors such as employment status, gender, and the presence of children in determining both access to and use of the car. To capture this two-stage decision process, we employ the two-part model, which consists of probit and OLS estimators, and derive elasticity estimates that incorporate both the discrete and continuous choices pertaining to car use. With fuel price elasticity estimates ranging between - 0.45 and - 0.50, our results suggest raising prices via fuel taxes to be a promising energy conservation and climate protection measure. (author)

  15. Chemical composition and fuel wood characteristics of fast growing tree species in India

    Science.gov (United States)

    Chauhan, S. K.; Soni, R.

    2012-04-01

    India is one of the growing economy in the world and energy is a critical input to sustain the growth of development. Country aims at security and efficiency of energy. Though fossil fuel will continue to play a dominant role in energy scenario but country is committed to global environmental well being thus stressing on environment friendly technologies. Concerns of energy security in this changing climatic situation have led to increasing support for the development of new renewable source of energy. Government though is determined to facilitate bio-energy and many projects have been established but initial after-affects more specifically on the domestic fuelwood are evident. Even the biomass power generating units are facing biomass crisis and accordingly the prices are going up. The CDM projects are supporting the viability of these units resultantly the Indian basket has a large number of biomass projects (144 out of total 506 with 28 per cent CERs). The use for fuelwood as a primary source of energy for domestic purpose by the poor people (approx. 80 per cent) and establishment of bio-energy plants may lead to deforestation to a great extent and only solution to this dilemma is to shift the wood harvest from the natural forests to energy plantations. However, there is conspicuous lack of knowledge with regards to the fuelwood characteristics of fast growing tree species for their selection for energy plantations. The calorific value of the species is important criteria for selection for fuel but it is affected by the proportions of biochemical constituents present in them. The aim of the present work was to study the biomass production, calorific value and chemical composition of different short rotation tree species. The study was done from the perspective of using the fast growing tree species for energy production at short rotation and the study concluded that short rotation tree species like Gmelina arborea, Eucalyptus tereticornis, Pongamia pinnata

  16. The effect of fuel chemistry on UO{sub 2} dissolution

    Energy Technology Data Exchange (ETDEWEB)

    Casella, Amanda, E-mail: amanda.casella@pnnl.gov [Pacific Northwest National Laboratory, PO Box 999, MSIN P7-25, Richland, WA 99352 (United States); Hanson, Brady, E-mail: brady.hanson@pnnl.gov [Pacific Northwest National Laboratory, PO Box 999, MSIN P7-27, Richland, WA 99352 (United States); Miller, William [University of Missouri Research Reactor, 1513 Research Park Drive, Columbia, MO 65211 (United States)

    2016-08-01

    The dissolution rate of both unirradiated UO{sub 2} and used nuclear fuel has been studied by numerous countries as part of the performance assessment of proposed geologic repositories. In the scenario of waste package failure and groundwater contact with the fuel, the effects of variables such as temperature, dissolved oxygen, and water and fuel chemistry on the dissolution rates of the fuel are necessary to provide a quantitative estimate of the potential release over geologic time frames. The primary objective of this research was to determine the influence these parameters, with primary focus on the fuel chemistry, have on the dissolution rate of unirradiated UO{sub 2} under oxidizing repository conditions and compare them to the rates predicted by current dissolution models. Both unirradiated UO{sub 2} and UO{sub 2} doped with varying concentrations of Gd{sub 2}O{sub 3}, to simulate used fuel composition after long time periods when radiolysis has minor contributions to dissolution, were examined. In general, a rise in temperature increased the dissolution rate of UO{sub 2} and had a larger effect on pure UO{sub 2} than on those doped with Gd{sub 2}O{sub 3}. Oxygen dependence was observed in the UO{sub 2} samples with no dopant and increased as the temperature rose; in the doped fuels less dependence was observed. The addition of gadolinia into the UO{sub 2} matrix resulted in a significant decrease in the dissolution rate. The matrix stabilization effect resulting from the dopant proved even more beneficial in lowering the dissolution rate at higher temperatures and dissolved O{sub 2} concentrations in the leachate where the rates would typically be elevated. - Highlights: • UO{sub 2} dissolution rates were measured for a matrix of repository relevant conditions. • Dopants in the UO{sub 2} matrix lowered the dissolution rate. • Reduction in rates by dopants were increased at elevated temperature and O{sub 2} levels. • UO{sub 2} may be overly

  17. Power Peaking Effect of OTTO Fuel Scheme Pebble Bed Reactor

    Science.gov (United States)

    Setiadipura, T.; Suwoto; Zuhair; Bakhri, S.; Sunaryo, G. R.

    2018-02-01

    Pebble Bed Reactor (PBR) type of Hight Temperature Gas-cooled Reactor (HTGR) is a very interesting nuclear reactor design to fulfill the growing electricity and heat demand with a superior passive safety features. Effort to introduce the PBR design to the market can be strengthen by simplifying its system with the Once-through-then-out (OTTO) cycle PBR in which the pebble fuel only pass the core once. Important challenge in the OTTO fuel scheme is the power peaking effect which limit the maximum nominal power or burnup of the design. Parametric survey is perform in this study to investigate the contribution of different design parameters to power peaking effect of OTTO cycle PBR. PEBBED code is utilized in this study to perform the equilibrium PBR core analysis for different design parameter and fuel scheme. The parameters include its core diameter, height-per-diameter (H/D), power density, and core nominal power. Results of this study show that diameter and H/D effectsare stronger compare to the power density and nominal core power. Results of this study might become an importance guidance for design optimization of OTTO fuel scheme PBR.

  18. Disturbing effect of free hydrogen on fuel combustion in internal combustion engines

    Science.gov (United States)

    Riedler, A

    1923-01-01

    Experiments with fuel mixtures of varying composition, have recently been conducted by the Motor Vehicle and Airplane Engine Testing Laboratories of the Royal Technical High School in Berlin and at Fort Hahneberg, as well as at numerous private engine works. The behavior of hydrogen during combustion in engines and its harmful effect under certain conditions, on the combustion in the engine cylinder are of general interest. Some of the results of these experiments are given here, in order to elucidate the main facts and explain much that is already a matter of experience with chauffeurs and pilots.

  19. On the effects of fuel properties and injection timing in partially premixed compression ignition of low octane fuels

    KAUST Repository

    Naser, Nimal

    2017-06-29

    A better understanding on the effects of fuel properties and injection timing is required to improve the performance of advanced engines based on low temperature combustion concepts. In this work, an experimental and computational study was conducted to investigate the effects of physical and chemical kinetic properties of low octane fuels and their surrogates in partially premixed compression ignition (PPCI) engines. The main objective was to identify the relative importance of physical versus chemical kinetic properties in predicting practical fuel combustion behavior across a range of injection timings. Two fuel/surrogate pairs were chosen for comparison: light naphtha (LN) versus the primary reference fuel (PRF) with research octane number of 65 (PRF 65), and FACE (fuels for advanced combustion engines) I gasoline versus PRF 70. Two sets of parametric studies were conducted: the first varied the amount of injected fuel mass at different injection timings to match a fixed combustion phasing, and the second maintained the same injected fuel mass at each injection timing to assess resulting combustion phasing changes. Full-cycle computational fluid dynamic engine simulations were conducted by accounting for differences in the physical properties of the original and surrogate fuels, while employing identical chemical kinetics. The simulations were found to capture trends observed in the experiments, while providing details on spatial mixing and chemical reactivity for different fuels and injection timings. It was found that differences in physical properties become increasingly important as injection timing was progressively delayed from premixed conditions, and this was rationalized by analysis of mixture stratification patterns resulting from injection of fuels with different physical properties. The results suggest that accurate descriptions of both physical and chemical behavior of fuels are critical in predictive simulations of PPCI engines for a wide range of

  20. On the effects of fuel properties and injection timing in partially premixed compression ignition of low octane fuels

    KAUST Repository

    Naser, Nimal; Jaasim, Mohammed; Atef, Nour; Chung, Suk-Ho; Im, Hong G.; Sarathy, Mani

    2017-01-01

    A better understanding on the effects of fuel properties and injection timing is required to improve the performance of advanced engines based on low temperature combustion concepts. In this work, an experimental and computational study was conducted to investigate the effects of physical and chemical kinetic properties of low octane fuels and their surrogates in partially premixed compression ignition (PPCI) engines. The main objective was to identify the relative importance of physical versus chemical kinetic properties in predicting practical fuel combustion behavior across a range of injection timings. Two fuel/surrogate pairs were chosen for comparison: light naphtha (LN) versus the primary reference fuel (PRF) with research octane number of 65 (PRF 65), and FACE (fuels for advanced combustion engines) I gasoline versus PRF 70. Two sets of parametric studies were conducted: the first varied the amount of injected fuel mass at different injection timings to match a fixed combustion phasing, and the second maintained the same injected fuel mass at each injection timing to assess resulting combustion phasing changes. Full-cycle computational fluid dynamic engine simulations were conducted by accounting for differences in the physical properties of the original and surrogate fuels, while employing identical chemical kinetics. The simulations were found to capture trends observed in the experiments, while providing details on spatial mixing and chemical reactivity for different fuels and injection timings. It was found that differences in physical properties become increasingly important as injection timing was progressively delayed from premixed conditions, and this was rationalized by analysis of mixture stratification patterns resulting from injection of fuels with different physical properties. The results suggest that accurate descriptions of both physical and chemical behavior of fuels are critical in predictive simulations of PPCI engines for a wide range of

  1. Determining the elemental composition of fuels by bomb calorimetry and the inverse correlation of HHV with elemental composition

    Energy Technology Data Exchange (ETDEWEB)

    Bech, Niels; Jensen, Peter Arendt; Dam-Johansen, Kim [Department of Chemical and Biochemical Engineering, CHEC Research Centre, Technical University of Denmark, Soeltofts Plads, Building 229, DK-2800 Kongens Lyngby (Denmark)

    2009-03-15

    This article presents a method to obtain a simplified elemental analysis of an organic sample in which oxygen, nitrogen, and sulphur are lumped. The method uses a bomb calorimeter, water, and ash measurements combined with a numerical procedure based on a generalised equation for predicting higher heating value. By analysing pure organic substances, literature data, and fuels it is demonstrated that the method can provide hydrogen estimates within {+-}0.7% daf. and carbon and sum of oxygen, nitrogen, and sulphur estimates within {+-}2% daf. for fuels containing less than 90% ash db., 2% nitrogen daf., and 1% daf. sulphur. (author)

  2. Handbook of fuel cell performance

    Energy Technology Data Exchange (ETDEWEB)

    Benjamin, T.G.; Camara, E.H.; Marianowski, L.G.

    1980-05-01

    The intent of this document is to provide a description of fuel cells, their performances and operating conditions, and the relationship between fuel processors and fuel cells. This information will enable fuel cell engineers to know which fuel processing schemes are most compatible with which fuel cells and to predict the performance of a fuel cell integrated with any fuel processor. The data and estimates presented are for the phosphoric acid and molten carbonate fuel cells because they are closer to commercialization than other types of fuel cells. Performance of the cells is shown as a function of operating temperature, pressure, fuel conversion (utilization), and oxidant utilization. The effect of oxidant composition (for example, air versus O/sub 2/) as well as fuel composition is examined because fuels provided by some of the more advanced fuel processing schemes such as coal conversion will contain varying amounts of H/sub 2/, CO, CO/sub 2/, CH/sub 4/, H/sub 2/O, and sulfur and nitrogen compounds. A brief description of fuel cells and their application to industrial, commercial, and residential power generation is given. The electrochemical aspects of fuel cells are reviewed. The phosphoric acid fuel cell is discussed, including how it is affected by operating conditions; and the molten carbonate fuel cell is discussed. The equations developed will help systems engineers to evaluate the application of the phosphoric acid and molten carbonate fuel cells to commercial, utility, and industrial power generation and waste heat utilization. A detailed discussion of fuel cell efficiency, and examples of fuel cell systems are given.

  3. Effect of reduced enrichment on the fuel cycle for research reactors

    International Nuclear Information System (INIS)

    Travelli, A.

    1982-01-01

    The new fuels developed by the RERTR Program and by other international programs for application in research reactors with reduced uranium enrichment (<20% EU) are discussed. It is shown that these fuels, combined with proper fuel-element design and fuel-management strategies, can provide at least the same core residence time as high-enrichment fuels in current use, and can frequently significantly extend it. The effect of enrichment reduction on other components of the research reactor fuel cycle, such as uranium and enrichment requirements, fuel fabrication, fuel shipment, and reprocessing are also briefly discussed with their economic implications. From a systematic comparison of HEU and LEU cores for the same reference research reactor, it is concluded that the new fuels have a potential for reducing the research reactor fuel cycle costs while reducing, at the same time, the uranium enrichment of the fuel

  4. Composite reprocessing of spent nuclear fuel - is a way to low waste nuclear power

    International Nuclear Information System (INIS)

    Kosyakov, Valentin

    2005-01-01

    Further development of nuclear power in many respects depend on the solution of the problems connected to high level radioactive wastes (HLRW), containing highly toxic long-lived radionuclides. Long-term controlled storage of HLRW manages expensively and any advanced technology of reprocessing of spent nuclear fuel (SNF), besides recovery of the basic products, should be aimed at the reduction of this waste amount. However, the existing SNF reprocessing technology, using PUREX - process, is aimed only at extraction of uranium and plutonium, considering the remaining fraction (other transuranium elements and all fission products) as HLRW. In this work an attempt is made to give quantitative and qualitative characteristics to the isotopes and the elements which are included in the composition of HLRW after 15-years storage. Depending on the radiation properties of the isotopes included, these elements were divided into three categories: 1. The elements represented by only stable isotopes; 2. The elements represented by mostly low radioactive isotopes; 3. The elements represented by highly toxic long-lived radionuclides. As a result it appeared, that the weight percentage of the elements of the first, the second and the third categories in HLRW was: 60, 25 and 15% respectively. It means, that the amount of the real HLRW to be disposed in a deep geological repository could be reduced at least by a factor of 6, if to recover completely only 7 most dangerous elements (Sr, J, Cs, Sm, Np, Am and Cm) from the solution remaining after extraction of uranium and plutonium. Then it is meaningful to recover the elements of the first category from the remaining mix. As the main part of this fraction is represented by rare earth elements and noble metals, which can easily find many useful application. (author)

  5. Effect of prenatal exposure to kitchen fuel on birth weight

    Directory of Open Access Journals (Sweden)

    Yugantara Ramesh Kadam

    2013-01-01

    Full Text Available Background: Maternal exposure to kitchen fuel smoke may lead to impaired fetal growth. Objective: To study the effect of exposure to various kitchen fuels on birth weight. Methodology : Study type: Retrospective analytical. Study setting: Hospital based. Study Subjects: Mothers and their newborns. Inclusion Criteria: Mothers registered in first trimester with minimum 3 visits, non-anemic, full-term, and singleton delivery. Exclusion Criteria: History of Pregnancy Induced Hypertension (PIH, Diabetes Mellitus (DM, tobacco chewers or mishri users. Sample size: 328 mothers and their new-borne. Study period: Six months. Study tools: Chi-square, Z-test, ANOVA, and binary logistic regression. Results: Effect of confounders on birth weight was tested and found to be non-significant. Mean ± SD of birth weight was 2.669 ± 0.442 in Liquid Petroleium Gas (LPG users (n = 178, 2.465 ± 0.465 in wood users (n = 94, 2.557 ± 0.603 in LPG + wood users (n = 27 and 2.617 ± 0.470 in kerosene users (n = 29. Infants born to wood users had lowest birth weight and averagely 204 g lighter than LPG users (F = 4.056, P < 0.01. Percentage of newborns with low birth weight (LBW in wood users was 44.68% which was significantly higher than in LPG users (24.16%, LPG + wood users (40.74% and in kerosene users (34.48% (Chi-square = 12.926, P < 0.01. As duration of exposure to wood fuel increases there is significant decline in birth weight (F = 3.825, P < 0.05. By using logistic regression type of fuel is only best predictor. Conclusion: Cooking with wood fuel is a significant risk-factor for LBW, which is modifiable.

  6. An evaluation of UO2-CNT composites made by SPS as an accident tolerant nuclear fuel pellet and the feasibility of SPS as an economical fabrication process for the nuclear fuel cycle

    Science.gov (United States)

    Cartas, Andrew R.

    The innovative and advanced purpose of this study is to understand and establish proper sintering procedures for Spark Plasma Sintering process in order to fabricate high density, high thermal conductivity UO2 -CNT pellets. Mixing quality and chemical reactions have been investigated by field emission scanning electron microscopy (FESEM), wavelength dispersive spectroscopy (WDS), and X-ray diffraction (XRD). The effect of various types of CNTs on the mixing and sintering quality of UO2-CNT pellets with SPS processing have been examined. The Archimedes Immersion Method, laser flash method, and FE-SEM will be used to investigate the density, thermal conductivity, grain size, pinning effects, and CNT dispersion of fabricated UO2-CNT pellets. Pre-fabricated CNT's were added to UO 2 powder and dispersed via sonication and/or ball milling and then made into composite nuclear pellets. An investigation of the economic impact of SPS on the nuclear fuel cycle for producing pure and composite UO2 fuels was conducted.

  7. Navy Fuel Composition and Screening Tool (FCAST) v2.8

    Science.gov (United States)

    2016-05-10

    percentage , (2) Fuel A, (3) Mixed Fuel, (4) Fuel B, (5) Blended properties. 7. FCAST ANOVA screen, showing 1) List of data files; 2) Selected samples for...16. FCAST Hydrocarbon Distribution screen, showing 1) List of data files; 2) Carbon number distributions in area percentages for different classes...Total ion chromatograph UVE-PLS Uninformed variable elimination partial least squares XML Extensible markup language 1 1.0 Introduction The

  8. A Fast Numerical Method for the Calculation of the Equilibrium Isotopic Composition of a Transmutation System in an Advanced Fuel Cycle

    Directory of Open Access Journals (Sweden)

    F. Álvarez-Velarde

    2012-01-01

    Full Text Available A fast numerical method for the calculation in a zero-dimensional approach of the equilibrium isotopic composition of an iteratively used transmutation system in an advanced fuel cycle, based on the Banach fixed point theorem, is described in this paper. The method divides the fuel cycle in successive stages: fuel fabrication, storage, irradiation inside the transmutation system, cooling, reprocessing, and incorporation of the external material into the new fresh fuel. The change of the fuel isotopic composition, represented by an isotope vector, is described in a matrix formulation. The resulting matrix equations are solved using direct methods with arbitrary precision arithmetic. The method has been successfully applied to a double-strata fuel cycle with light water reactors and accelerator-driven subcritical systems. After comparison to the results of the EVOLCODE 2.0 burn-up code, the observed differences are about a few percents in the mass estimations of the main actinides.

  9. Exhaust gas emissions and mutagenic effects of modern diesel fuels, GTL, biodiesel and biodiesel blends

    Energy Technology Data Exchange (ETDEWEB)

    Munack, Axel; Ruschel, Yvonne; Schroeder, Olaf [Federal Research Institute for Rural Areas, Forestry and Fisheries, Braunschweig (Germany)], E-mail: axel.munack@vti.bund.de; Krahl, Juergen [Coburg Univ. of Applied Sciences (Germany); Buenger, Juergen [University of Bochum (Germany)

    2008-07-01

    Biodiesel can be used alone (B100) or blended with petroleum diesel in any proportion. The most popular biodiesel blend in the U.S.A. is B20 (20% biodiesel, 80% diesel fuel), which can be used for Energy Policy Act of 1992 (EPAct) compliance. In the European Union, the use of biofuel blends is recommended and was introduced by federal regulations in several countries. In Germany, biodiesel is currently blended as B5 (5% biodiesel) to common diesel fuel. In 2008, B7 plus three percent hydrotreated vegetable oil (HVO) as well is intended to become mandatory in Germany. To investigate the influence of blends on the emissions and possible health effects, we performed a series of studies with several engines (Euro 0, III and IV) measuring regulated and non-regulated exhaust compounds and determining their mutagenic effects. Emissions of blends showed an approximate linear dependence on the blend composition, in particular when regulated emissions are considered. However, a negative effect of blends was observed with respect to mutagenicity of the exhaust gas emissions. In detail, a maximum of the mutagenic potency was found in the range of B20. From this point of view, B20 must be considered as a critical blend, in case diesel fuel and biodiesel are used as binary mixtures. (author)

  10. Evaluation of source term parameters for spent fuel disposal in foreign countries. (1) Instant release fraction from spent fuel matrices and composition materials for fuel assemblies

    International Nuclear Information System (INIS)

    Nagata, Masanobu; Chikazawa, Takahiro; Kitamura, Akira; Tachi, Yukio; Akahori, Kuniaki

    2016-01-01

    Although spent nuclear fuel is planned to be disposed after reprocessing and vitrification of high-level radioactive waste (HLW), feasibility study on direct disposal of spent nuclear fuel (SF) has been started as one of the alternative disposal options to flexibly apply change of future energy situation in Japan. Radionuclide inventories and their release behavior after breaching spent fuel container should be assessed to confirm safety of the SF disposal. Especially, instant release fractions (IRFs), which are fractions of radionuclide released relatively faster than those released with congruent dissolution with SF and construction materials after breaching spent fuel container, may have an impact on safety assessment of the direct disposal of SF. However, detailed studies on evaluation / estimation of IRF have not been performed in Japan. Therefore, we investigated some foreign safety assessment reports on direct disposal of SF by focusing on IRF for the safety assessment of Japanese SF disposal system. As a result of comparison between the safety assessment reports in foreign countries, although some fundamental data have been referred to the reports in common, the final source term dataset was seen differences between countries in the result of taking into account the national circumstances (reactor types and burnups, etc.). We also found the difference of assignment of uncertainties among the investigated reports; a report selected pessimistic values and another report selected mean values and their deviations. It is expected that these findings are useful as fundamental information for the safety assessment of Japanese SF disposal system. (author)

  11. Effect of water content on partial ternary phase diagram water-in-diesel microemulsion fuel

    Science.gov (United States)

    Mukayat, Hastinatun; Badri, Khairiah Haji; Raman, Ismail Ab.; Ramli, Suria

    2014-09-01

    Introduction of water in the fuel gave a significant effect to the reduction of pollutant such as NOx emission. In this work, water/diesel microemulsion fuels were prepared using compositional method by mixing water and diesel in the presence of non-ionic surfactant and co-surfactant. The effects of water composition on the partial ternary phase diagram were studied at 5%, 10%, 15% and 20% (w/w). The physical stability of the microemulsion was investigated at 45°C over a period of one month. The optimum formulae obtained were diesel/T80/1-penthanol/water 60:20:15:5 wt% (System 1), 55:20:15:10 wt% (System 2), 50:20:15:15 wt% (System 3) and 45:20:15:20 wt% (System 4). Physicochemical characterizations of optimum formulae were studied. The results showed that water content has a significant effect to the formation of microemulsion, its stability, droplet size and viscosity.

  12. Online gas composition estimation in solid oxide fuel cell systems with anode off-gas recycle configuration

    Science.gov (United States)

    Dolenc, B.; Vrečko, D.; Juričić, Ð.; Pohjoranta, A.; Pianese, C.

    2017-03-01

    Degradation and poisoning of solid oxide fuel cell (SOFC) stacks are continuously shortening the lifespan of SOFC systems. Poisoning mechanisms, such as carbon deposition, form a coating layer, hence rapidly decreasing the efficiency of the fuel cells. Gas composition of inlet gases is known to have great impact on the rate of coke formation. Therefore, monitoring of these variables can be of great benefit for overall management of SOFCs. Although measuring the gas composition of the gas stream is feasible, it is too costly for commercial applications. This paper proposes three distinct approaches for the design of gas composition estimators of an SOFC system in anode off-gas recycle configuration which are (i.) accurate, and (ii.) easy to implement on a programmable logic controller. Firstly, a classical approach is briefly revisited and problems related to implementation complexity are discussed. Secondly, the model is simplified and adapted for easy implementation. Further, an alternative data-driven approach for gas composition estimation is developed. Finally, a hybrid estimator employing experimental data and 1st-principles is proposed. Despite the structural simplicity of the estimators, the experimental validation shows a high precision for all of the approaches. Experimental validation is performed on a 10 kW SOFC system.

  13. Synthesizing Nanomaterials for Energy Applications: Probing Activity as a Function of Composition, Morphology and Purity to Address Key Issues Associated with Fuel Cells and Li-Ion Batteries

    Science.gov (United States)

    Scofield, Megan Elaine

    With the growing need to find alternative clean energy sources to fossil fuels, research into developing efficient fuel cells and batteries stands at the forefront of this grand effort. However, before mass commercialization, fundamental key issues need to be addressed. For example, fuel cells are subject to high catalyst costs and poor durability of the underlying carbon support. As a way to alleviate these issues, we have synthesized ultrathin one-dimensional (1D) alloy nanowires to probe the effect of composition, purity, and one-dimensionality upon the observed overall activity, performance, and durability. In terms of chemical composition, crystalline ultrathin PtM alloy nanowires (NWs) ('M' = Fe, Co, Ru, Cu, and Au) were generated and subsequently evaluated for the hydrogen oxidation reaction (HOR). Additionally, ternary-based catalysts were synthesized (PtRuFe) in order to analyze how chemical composition influences CO tolerance as well as methanol oxidation reaction (MOR) and formic acid oxidation reaction (FAOR) activities. In both cases, we utilized a sustainably mild, ambient wet-synthesis method for the fabrication of chemically pure and crystalline systems in order to fabricate ultrathin, homogeneous alloy NWs. Moreover, in these studies, our NW systems exhibit favorable synergistic electronic effects with respect to controls. To address another fundamental issue associated with the durability of fuel cells, we have synthesized various metal oxide and perovskite materials of different sizes and chemical compositions as supports for Pt nanoparticles (NPs). Specifically, we have demonstrated favorable metal support interactions between the Pt NPs and the SrRuO3 NP supports, which lead to increased MOR activity as compared with not only the other metal oxide supports tested but also the commercial Pt NP/C standard. In terms of Li-ion batteries, LiFePO4 materials have become increasingly popular as a cathode material due to the many benefits they possess

  14. Highly conductive, multi-layer composite precursor composition to fuel cell flow field plate or bipolar plate

    Science.gov (United States)

    Jang, Bor Z [Centerville, OH; Zhamu, Aruna [Centerville, OH; Guo, Jiusheng [Centerville, OH

    2011-02-15

    This invention provides a moldable, multiple-layer composite composition, which is a precursor to an electrically conductive composite flow field plate or bipolar plate. In one preferred embodiment, the composition comprises a plurality of conductive sheets and a plurality of mixture layers of a curable resin and conductive fillers, wherein (A) each conductive sheet is attached to at least one resin-filler mixture layer; (B) at least one of the conductive sheets comprises flexible graphite; and (C) at least one resin-filler mixture layer comprises a thermosetting resin and conductive fillers with the fillers being present in a sufficient quantity to render the resulting flow field plate or bipolar plate electrically conductive with a conductivity no less than 100 S/cm and thickness-direction areal conductivity no less than 200 S/cm.sup.2.

  15. Strontium Titanate-based Composite Anodes for Solid Oxide Fuel Cells

    DEFF Research Database (Denmark)

    Blennow Tullmar, Peter; Kammer Hansen, Kent; Wallenberg, L.R.

    2008-01-01

    Surfactant-assisted infiltration of Gd-doped ceria (CGO) in Nb-doped SrTiO3 (STN) was investigated as a potential fuel electrode for solid oxide fuel cells (SOFC). An electronically conductive backbone structure of STN was first fabricated at high temperatures and then combined with the mixed con...

  16. Effects of Fuel Quantity on Soot Formation Process for Biomass-Based Renewable Diesel Fuel Combustion

    KAUST Repository

    Jing, Wei; Wu, Zengyang; Roberts, William L.; Fang, Tiegang

    2016-01-01

    Soot formation process was investigated for biomass-based renewable diesel fuel, such as biomass to liquid (BTL), and conventional diesel combustion under varied fuel quantities injected into a constant volume combustion chamber. Soot measurement

  17. Effect of limestone addition on chlorine compound emissions in grate and fluidized-bed combustion of recovered fuels

    International Nuclear Information System (INIS)

    Vesterinen, R.; Ruuskanen, J.

    2000-01-01

    The aim was to verify the positive results of laboratory experiments concerning the reducing effect of limestone addition on emissions of organic chlorine compounds and acidifying compounds (HCl, HF, SO 2 ) in grate and fluidized-bed combustion of recovered fuels in commercial boilers. The final aim is to develop a cheap and practical way of reducing emissions of organic chlorine compounds in co-combustion of recovered fuels. Pellets produced from the mixture of recovered fuel and limestone is a product ready for use in plants without any need of additional employees or equipment for limestone feed. Pellets produced by Ewapower Oy are used as recovered fuel and Gotland limestone of Partek Nordkalk Oyj Abp as limestone. Ewapower Oy produces pellets by feeding a certain proportion of limestone among recovered fuel at the production stage. Experiments are carried out in one grate-combustion plant and in one or two fluidized-bed plants. The first experiments were carried out in a 3 MWth BioGrate boiler at the new heating station of Pielavesi municipality in autumn 1999. The flue gases are cleaned with a cyclone (FinCleaner). The main fuel was a mixture of bark and sawdust (3:1) from a sawmill. Ewapower pellets with an addition of Gotland limestone were used as recovered fuel. The experiments were carried out at about 2 MW boiler output. Temperatures of the furnace and flue gas, pressure and fuel gas composition were measured continuously. For determining the composition of gas, O 2 , CO, CO 2 , hydrocarbons and N 2 O(FTIR), NO x and SO 2 were measured continuously. HCl, heavy metals (As, Cd, Cr, Cu, Hg, Ni, Pb, Zn), polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/PCDF), polyaromatic hydrocarbons (PAH), chlorobenzenes, chlorophenols and PCB were measured as one-shot determinations. Fuel and ash samples were also collected during the experiments. The organic compounds were analyzed by the Department of Environmental Science of the University of Kuopio, which is

  18. Ag-polytetrafluoroethylene composite coating on stainless steel as bipolar plate of proton exchange membrane fuel cell

    Energy Technology Data Exchange (ETDEWEB)

    Fu, Yu. [Laboratory of Fuel Cells, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Zhongshan Road, Dalian 116023 (China); Graduate University of Chinese Academy of Sciences, Beijing 100049 (China); Hou, Ming; Shao, Zhigang; Yi, Baolian [Laboratory of Fuel Cells, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Zhongshan Road, Dalian 116023 (China); Xu, Hongfeng; Hou, Zhongjun; Ming, Pingwen [Sunrise Power Co., Ltd., Dalian 116025 (China)

    2008-08-01

    Forming a coating on metals by surface treatment is a good way to get high performance bipolar plate of proton exchange membrane fuel cell (PEMFC). In our research, Ag-polytetrafluoroethylene (PTFE) composite film was electrodeposited with silver-gilt solution of nicotinic acid by a bi-pulse electroplating power supply on 316 L stainless steel bipolar plate of PEMFC. Surface topography, contact angle, interfacial conductivity and corrosion resistance of the bipolar plate samples were investigated. Results showed that the defects on the Ag-PTFE composite coating are greatly reduced compared with those on the pure Ag coating fabricated under the same condition; and the contact angle of the Ag-PTFE composite coating with water is 114 , which is much bigger than that of the pure Ag coating (73 ). In addition, the interfacial contact resistance of the composite coating stays as low as the pure Ag coating; and the bipolar plate sample with composite coating shows a close corrosion resistance to the pure Ag coating sample in potentiodynamic and potentiostatic tests. Coated 316 L stainless steel plate with Ag-PTFE composite coating exhibits well hydrophobic characteristic, less defects, high interfacial conductivity and good corrosion resistance, which shows a great potential of the application in PEMFC. (author)

  19. Potential exposures and health effects from spent fuel transportation

    International Nuclear Information System (INIS)

    Sandquist, G.M.; Rogers, V.C.

    1986-01-01

    The radiation exposures and consequent health effects associated with normal operations and accidents during transportation of spent fuel have been analyzed and evaluated. This study was performed for the U.S. Department of Energy (DOE) as contributory data for response to specific public inquires regarding the Draft Environmental Assessments issued by DOE in 1984. Large quantities of spent fuel from power reactors will be shipped by truck and/or rail from the site of generation or temporary storage to nuclear waste repositories. This transportation activity has the potential for increasing radiation exposures and risks above normal background levels in the vicinity of the transportation route. For normal, accident-free transport of spent fuel, radiation exposures arise from both gamma and neutron sources within the spent fuel cask. U.S. regulations limit the radiation dose equivalent rate to 10 millirem per hour at any point 2 meters from the outer lateral surfaces of the transport vehicle. Computer program PATHRAE-T was developed and employed to determine the total, combined dose field. PATHRAE-T was used to estimate the maximum individual doses from rail cask accidents. The maximum individual exposure, primarily due to inhalation, is about 10 rem and occurs about 70 meters downwind. Ground deposited nuclides account for 99 percent of the population dose. The maximum population dose accident could result in about 22 latent health effects for the urban population. The same case rail cask accidents were also evaluated for a maximum water pathway contamination scenario. The nuclide contaminated plume was assumed to be transported over a large reservoir used for domestic and agricultural water. This accident could result in a 63,000 person-rem dose causing about 13 latent health effects in the absence of any natural and industrial processes for nuclide removal from the water

  20. Effect of matrix cracking and material uncertainty on composite plates

    International Nuclear Information System (INIS)

    Gayathri, P.; Umesh, K.; Ganguli, R.

    2010-01-01

    A laminated composite plate model based on first order shear deformation theory is implemented using the finite element method. Matrix cracks are introduced into the finite element model by considering changes in the A, B and D matrices of composites. The effects of different boundary conditions, laminate types and ply angles on the behavior of composite plates with matrix cracks are studied. Finally, the effect of material property uncertainty, which is important for composite material on the composite plate, is investigated using Monte Carlo simulations. Probabilistic estimates of damage detection reliability in composite plates are made for static and dynamic measurements. It is found that the effect of uncertainty must be considered for accurate damage detection in composite structures. The estimates of variance obtained for observable system properties due to uncertainty can be used for developing more robust damage detection algorithms.

  1. Cost-effectiveness, feed utilization and body composition of african ...

    African Journals Online (AJOL)

    Cost-effectiveness, feed utilization and body composition of african sharptooth catfish ( Clarias gariepinus , Burchell 1822) fingerlings fed locally formulated and commercial pelleted diets in tarpaulin tanks.

  2. Impact of fuel composition on the recirculation zone structure and its role in lean premixed flame anchoring

    KAUST Repository

    Hong, Seunghyuck

    2015-01-01

    © 2014 The Combustion Institute. Published by Elsevier Inc. All rights reserved. We investigate the dependence of the recirculation zone (RZ) size and structure on the fuel composition using high-speed particle image velocimetry (PIV) and chemiluminescence measurements for C3H8/H2/air lean premixed flames stabilized in a backward-facing step combustor. Results show an intricate coupling between the flame anchoring and the RZ structure and length. For a fixed fuel composition, at relatively low equivalence ratios, the time-averaged RZ is comprised of two counter rotating eddies: a primary eddy (PE) between the shear layer and the bottom wall; and a secondary eddy (SE) between the vertical step wall and the PE. The flame stabilizes downstream of the saddle point of the dividing streamline between the two eddies. As equivalence ratio is raised, the flame moves upstream, pushing the saddle point with it and reducing the size of the SE. Higher temperature of the products reduces the velocity gradient in the shear layer and thus the reattachment length. As equivalence ratio approaches a critical value, the saddle point reaches the step and the SE collapses while the flame starts to exhibit periodic flapping motions, suggesting a correlation between the RZ structure and flame anchoring. The overall trend in the flow field is the same as we add hydrogen to the fuel at a fixed equivalence ratio, demonstrating the impact of fuel composition on the flow field. We show that the reattachment lengths (LR), which are shown to encapsulate the mean RZ structure, measured over a range of fuel composition and equivalence ratio collapse if plotted against the strained consumption speed (Sc). Results indicate that for the flame to remain anchored, the RZ structure should satisfy lR,isothermal/L R,reacting · S c/U ∞ ∼ 0.1. If this criterion cannot be met, the flame blows off, flashes back or becomes thermoacoustically unstable, suggesting a Damköhler-like criterion for

  3. Effect of increased fuel temperature on emissions of oxides of nitrogen from a gas turbine combustor burning ASTM jet-A fuel

    Science.gov (United States)

    Marchionna, N. R.

    1974-01-01

    An annular gas turbine combustor was tested with heated ASTM Jet-A fuel to determine the effect of increased fuel temperature on the formation of oxides of nitrogen. Fuel temperature ranged from ambient to 700 K. The NOx emission index increased at a rate of 6 percent per 100 K increase in fuel temperature.

  4. Modeling and Predicting the Electrical Conductivity of Composite Cathode for Solid Oxide Fuel Cell by Using Support Vector Regression

    Science.gov (United States)

    Tang, J. L.; Cai, C. Z.; Xiao, T. T.; Huang, S. J.

    2012-07-01

    The electrical conductivity of solid oxide fuel cell (SOFC) cathode is one of the most important indices affecting the efficiency of SOFC. In order to improve the performance of fuel cell system, it is advantageous to have accurate model with which one can predict the electrical conductivity. In this paper, a model utilizing support vector regression (SVR) approach combined with particle swarm optimization (PSO) algorithm for its parameter optimization was established to modeling and predicting the electrical conductivity of Ba0.5Sr0.5Co0.8Fe0.2 O3-δ-xSm0.5Sr0.5CoO3-δ (BSCF-xSSC) composite cathode under two influence factors, including operating temperature (T) and SSC content (x) in BSCF-xSSC composite cathode. The leave-one-out cross validation (LOOCV) test result by SVR strongly supports that the generalization ability of SVR model is high enough. The absolute percentage error (APE) of 27 samples does not exceed 0.05%. The mean absolute percentage error (MAPE) of all 30 samples is only 0.09% and the correlation coefficient (R2) as high as 0.999. This investigation suggests that the hybrid PSO-SVR approach may be not only a promising and practical methodology to simulate the properties of fuel cell system, but also a powerful tool to be used for optimal designing or controlling the operating process of a SOFC system.

  5. Rheology of Colombian coal-water slurry fuels: Effect of particle-size distribution

    Energy Technology Data Exchange (ETDEWEB)

    Pulido, J E; Rojas, C P; Acero, G [Universidad Industrial de Santander, Bucaramanga (Colombia)

    1996-12-31

    Coal-water slurry fuels (CWSF`s) have been prepared and characterized in a research project in Colombia, sponsored by Colciencias and Ecocarbon, in order to evaluate the effects of the different composition variables on the behavior during preparation and pipe line transportation. The authors have previously presented details describing the characteristics of the slurry fuels prepared with five types of Colombian thermal coals and the influence of their chemical composition on the optimum particle-size distribution (PSD) required to prepare highly loaded and workable CWSF`s. The formulation and design of flow systems of suspensions with high solids content, such as the CWSF`s, require a detailed rheological knowledge of the suspension in terms of the governing parameters related to PSD, coal content, surface chemistry of the particles and dispersants used to stabilize the slurries. Important studies on these aspects have been reviewed and carried out experimentally by other authors specially devoted to the correlations between apparent viscosity, solids content and average coal particle-size. One of the targets to obtain an optimum control on the viscosity and flow properties of the CWSF`s must be based in correlating the Theological constants for the prevailing model of viscosity law to the characteristic parameters of the particle-size distribution and to the coal content in the slurry. In spite of the effect of PSD on the rheology of highly-loaded coal slurries have been long recognized as significant, the specific influence of the various PSD`s on the parameters of the Theological model continues to receive attention to further understanding in order to improve the slurry formulations for a specified purpose on preparation and hydraulic handling. This paper reports the results of an experimental technique of examining the various PSD`s on coal slurry fuel rheology, taking special attention for the effect on the parameters of the rheological model.

  6. High polymer composites for containers for the long-term storage of spent nuclear fuel and high level radioactive waste

    International Nuclear Information System (INIS)

    Bonin, H.W.; Vui, V.T.; Legault, J.-F.

    1997-01-01

    The feasibility of using polymeric composite materials as an alternative to metals in the design of a nuclear waste disposal container was examined. The disposal containers would be stored in deep underground vaults in plutonic rock formations within the Canadian Shield for several thousands of years. The conditions of disposal considered in the evaluation of the polymeric composite materials were based on the long-term disposal concept proposed by Atomic Energy of Canada Limited. Four different composites were considered for this work, all based on boron fibre as reinforcing material, imbedded in polymeric matrices made of polystyrene (PS), polymethyl methacrylate (PMMA), Devcon 10210 epoxy, and polyetheretherketone (PEEK). Both PS and PMMA were determined as unsuitable for use in the fabrication of the storage container because of thermal failure. This was determined following thermal analysis of the materials in which heat transfer calculations yielded the temperature of the container wall and of the surroundings resulting from the heat generated by the spent nuclear fuel stored inside the container. In the case of the PS, the temperature of the container, the buffer and the backfill would exceed the 100 degrees C imposed in the AECL's proposal as the maximum allowable. In the case of the PMMA, the 100 degrees temperature is too close to the glass transition temperature of this material (105 degrees C) and would cause structural degradation of the container wall. The other two materials present acceptable thermal characteristics for this application. An important concern for polymeric materials in such use is their resistance to radiations. The Devcon 10210 epoxy has been the object of research at the Royal Military College in the past years and fair, but limited, resistance to both neutrons and gamma radiation has been demonstrated, with the evidence of increased mechanical strength when subjected to moderate doses. Provided that the container wall could be

  7. Methanol as an alternative fuel: Economic and health effects

    International Nuclear Information System (INIS)

    Yuecel, M.K.

    1991-01-01

    Switching from gasoline to methanol fuels has important economic and health effects. Replacing gasoline with methanol will affect oil markets by lowering the demand for oil and thus lowering oil prices. Increased demand for the natural gas feedstock will increase natural gas prices. Because methanol is more costly than gasoline, fuel prices will also increase. On the other hand, methanol use will reduce ozone pollution and some of the health risks associated with gasoline. Considering all three markets affected by the phasing-out of gasoline, the switch to methanol results in net gains. The health benefits from lower pollution and the lives saved from the switch from gasoline to methanol are in addition to these gains. Overall, the benefits of the policy far outweigh the costs. However, the gains in the oil market, arising from the US monopsony power in the world oil market, can be captured by other, more efficient policies. 21 refs., 2 figs., 3 tabs

  8. Aging effect on the fuel behaviors for CANDU fuel safety analysis

    Energy Technology Data Exchange (ETDEWEB)

    Jung, J.Y.; Bae, J.H.; Park, J.H.; Song, Y.M., E-mail: agahee@kaeri.re.kr [Korea Atomic Energy Research Inst., Yuseong-gu, Daejeon (Korea, Republic of)

    2013-07-01

    Because of the aging of heat transport system components, the reactor thermalhydraulic conditions can vary, which may affect the safety response. In a recent safety analysis for the refurbished Wolsong 1 NPP, various aging effects were incorporated into the hydraulic models of the components in the primary heat transport system (PHTS) for conservatism. The aging data of the thermal-hydraulic components for an 11 EFPY of Wolsong 1 were derived based on the site operation data and were modified to the appropriate input data for the thermal-hydraulic code for a safety analysis of a postulated accident. This paper deals with the aging effect of the PHTS of the CANDU reactor on the fuel performance during normal operation and transient period following a postulated accident such as a feeder stagnation break. (author)

  9. Effects of chronic acceleration on body composition

    Science.gov (United States)

    Pitts, G. C.

    1982-01-01

    Studies of the centrifugation of adult rats showed an unexpected decrease in the mass of fat-free muscle and bone, in spite of the added load induced by centrifugation. It is suggested that the lower but constant fat-free body mass was probably regulated during centrifugation. Rats placed in weightless conditions for 18.5 days gave indirect but strong evidence that the muscle had increased in mass. Other changes in the rats placed in weightless conditions included a smaller fraction of skeletal mineral, a smaller fraction of water in the total fat-free body, and a net shift of fluid from skin to viscera. Adult rats centrifuged throughout the post-weaning growth period exhibited smaller masses of bone and central nervous system (probably attributable to slower growth of the total body), and a larger mass of skin than controls at 1 G. Efforts at simulating the effects of weightlessness or centrifugation on the body composition of rats by regimens at terrestrial gravity were inconclusive.

  10. Effect of wood fuels on power plant operability

    International Nuclear Information System (INIS)

    Orjala, M.; Ingalsuo, R.

    2001-01-01

    The objective of the research is to determine the critical properties of wood fuels on the basis of power plant operability, to determine the optimal conditions for reduction of harmful detriments, and to study how the storage and processing of wood fuels effect on the operability. Both the CFB and BFB technologies are studied. The project started in December 2000 and it will be ended by the end of 2002. Experts of the Fuels and Combustion research field of VTT Energy carry out the main parts of the research. Experts of the research field of Mineral Processing of VTT Chemical Technology, located in Outokumpu, and Kemian tutkimuspalvelut Oy/Oulu University, located in Outokumpu, participate in the analytics, and the research field of Materials and Manufacturing Technology of VTT Manufacturing Technology in Otaniemi participates in the research on material effects. System Technology Laboratory of Oulu University carries out the power plant automation and boiler control technology research under supervision of Professor Urpo Kortela. Co-operation with the materials research unit of EU's JRC, located in Petten, which started in the research 'Combustion of Forest Chips', will be continues in this research. Co-operation will be made with Swedish Vaermeforsk in the field of information exchange on experiences in utilisation of wood fuels in Swedish power plants and possibilities to join in the projects of Vaermeforsk in this research field. Following companies participate in the project: Etelae-Savon Energia Oy, Foster Wheeler Energia Oy, Kvaerner Pulping Oy, Simpele pasteboard factory of M-Real Oyj and Vaermeforsk AB (Sweden). (orig.)

  11. Preparation and characterization of the PVDF-based composite membrane for direct methanol fuel cells

    OpenAIRE

    Qian Liu, Laizhou Song, Zhihui Zhang, Xiaowei Liu

    2010-01-01

    The polyvinylidene fluoride-sulfonated polystyrene composite membrane with proton exchange performance, denoted as PVDF-SPS, was prepared using a thermally induced polymerization technique. The thermal stability of the PVDF-SPS composite membrane was investigated using thermogravimetric (TG) analysis. The complex formation of the composite membrane was ascertained by Fourier transform infrared spectroscopy (FTIR). The surface compositions of the PVDF-SPS membrane were analyzed using X-ray pho...

  12. Global radiative effects of solid fuel cookstove aerosol emissions

    Science.gov (United States)

    Huang, Yaoxian; Unger, Nadine; Storelvmo, Trude; Harper, Kandice; Zheng, Yiqi; Heyes, Chris

    2018-04-01

    We apply the NCAR CAM5-Chem global aerosol-climate model to quantify the net global radiative effects of black and organic carbon aerosols from global and Indian solid fuel cookstove emissions for the year 2010. Our assessment accounts for the direct radiative effects, changes to cloud albedo and lifetime (aerosol indirect effect, AIE), impacts on clouds via the vertical temperature profile (semi-direct effect, SDE) and changes in the surface albedo of snow and ice (surface albedo effect). In addition, we provide the first estimate of household solid fuel black carbon emission effects on ice clouds. Anthropogenic emissions are from the IIASA GAINS ECLIPSE V5a inventory. A global dataset of black carbon (BC) and organic aerosol (OA) measurements from surface sites and aerosol optical depth (AOD) from AERONET is used to evaluate the model skill. Compared with observations, the model successfully reproduces the spatial patterns of atmospheric BC and OA concentrations, and agrees with measurements to within a factor of 2. Globally, the simulated AOD agrees well with observations, with a normalized mean bias close to zero. However, the model tends to underestimate AOD over India and China by ˜ 19 ± 4 % but overestimate it over Africa by ˜ 25 ± 11 % (± represents modeled temporal standard deviations for n = 5 run years). Without BC serving as ice nuclei (IN), global and Indian solid fuel cookstove aerosol emissions have net global cooling radiative effects of -141 ± 4 mW m-2 and -12 ± 4 mW m-2, respectively (± represents modeled temporal standard deviations for n = 5 run years). The net radiative impacts are dominated by the AIE and SDE mechanisms, which originate from enhanced cloud condensation nuclei concentrations for the formation of liquid and mixed-phase clouds, and a suppression of convective transport of water vapor from the lower troposphere to the upper troposphere/lower stratosphere that in turn leads to reduced ice cloud formation. When BC is allowed

  13. POLYPROPYLENE-MODIFIED KAOLINITE COMPOSITES: EFFECT ...

    African Journals Online (AJOL)

    Meziane O, Bensedira A, Guessoum M and Haddaoui N

    2016-05-01

    May 1, 2016 ... prepared by the melt intercalation method. ... several beneficial variations on stiffness, hardness, toughness and heat ..... Polypropylene/ untreated and treated kaolinite composites have been prepared via direct melt.

  14. Spent-fuel composition: a comparison of predicted and measured data

    International Nuclear Information System (INIS)

    Thomas, C.C. Jr.; Cobb, D.D.; Ostenak, C.A.

    1981-03-01

    The uncertainty in predictions of the nuclear materials content of spent light-water reactor fuel was investigated to obtain guidelines for nondestructive spent-fuel verification and assay. Values predicted by the reactor operator were compared with measured values from fuel reprocessors for six reactors (three PWR and three BWR). The study indicates that total uranium, total plutonium, fissile uranium, fissile plutonium, and total fissile content can be predicted with biases ranging from 1 to 6% and variabilities (1-sigma) ranging from 2 to 7%. The higher values generally are associated with BWRs. Based on the results of this study, nondestructive assay measurements that are accurate and precise to 5 to 10% (1sigma) or better should be useful for quantitative analyses of typical spent fuel

  15. SEFLEX - fuel rod simulator effects in flooding experiments. Pt. 2

    International Nuclear Information System (INIS)

    Ihle, P.; Rust, K.

    1986-03-01

    This report presents typical data and a limited heat transfer analysis from unblocked bundle reflood tests of an experimental thermal-hydraulic program. Full-length bundles of 5 x 5 fuel rod simulators having a gas-filled gap between the Zy cladding and the alumina pellets were tested in the test rig designed for the earlier Flooding Experiments with Blocked Arrays (FEBA-program). The 5 x 5 FEBA rod bundle tests were performed with gapless heater rods. These rods have a close thermal contact between the stainless steel cladding and the electric insulation material. A comparison of the SEFLEX data with the reference data of FEBA obtained under identical initial and reflood conditions shows the influence of different fuel rod simulators on the thermal-hydraulic behavior during forced feed bottom reflooding of unblocked and blocked arrays. Compared to bundles of gapless rods, bundles of rods with Zy claddings and a gas filled gap between claddings and pellets, which more closely represent the features that exist in an actual fuel rod geometry, produced higher quench front velocities, enhanced removal of stored heat in the rods, reduced peak cladding temperatures, increased grid spacer effects and absolutely unproblematic coolability of 90 percent blockages with bypass. The data offer the opportunity for further validation of computer codes to make realistic predictions of safety margins during a LOCA in a PWR. (orig./HP) [de

  16. SEFLEX fuel rod simulator effects in flooding experiments. Pt. 3

    International Nuclear Information System (INIS)

    Ihle, P.; Rust, K.

    1986-03-01

    This report presents typical data and a limited heat transfer analysis from blocked bundle reflood tests of an experimental thermal-hydraulic program. Full-length bundles of 5x5 fuel rod simulators having a gas-filled gap between the Zy cladding and the alumina pellets were tested in the test rig designed for the earlier Flooding Experiments with Blocked Arrays (FEBA-program). The 5x5 FEBA rod bundle tests were performed with gapless heater rods. These rods have a close thermal contact between the stainless steel cladding and the electric insulation material. A comparison of the SEFLEX data with the reference data of FEBA obtained under identical initial and reflood conditions shows the influence of different fuel rod simulators on the thermal-hydraulic behavior during forced feed bottom reflooding of unblocked and blocked arrays. Compared to bundles of gapless rods, bundles of rods with Zy claddings and a gas filled gap between claddings and pellets, which more closely represent the features that exist in an actual fuel rod geometry, produced higher quench front velocities, enhanced removal of stored heat in the rods, reduced peak cladding temperatures, increased grid spacer effects and absolutely unproblematic coolability of 90 percent blockages with bypass. The data offer the opportunity for further validation of computer codes to make realistic predictions of safety margins during a LOCA in a PWR. (orig./HP) [de

  17. HTGR fuel rods: carbon-carbon composites designed for high weight and low strength

    International Nuclear Information System (INIS)

    Bullock, R.E.

    1977-01-01

    The evolution of the process for fabricating fuel rods for the high-temperature gas-cooled reactor (HTGR) by injection and carbonization of a thermoplastic matrix that bonds close-packed beds of pyrocarbon-coated fuel particles together is reviewed for the fresh-fuel cycle, and a variant process involving a thermosetting matrix that would allow free-standing carbonization of refabricated fuel is discussed. Previous attempts to fabricate such injection-bonded fuel rods from undiluted thermosetting binders filled with powdered graphite were unsuccessful, because of damage to coatings on fuel particles that resulted from strong particle-to-matrix bonding in conjunction with large matrix shrinkage on carbonization and subsequent irradiation. These problems have now been overcome through the use of a diluted thermosetting matrix with a low-char-yield additive (fugitive), which produces a more porous char similar to that from the pitch-based thermoplastic used in fabrication of fresh fuel. A 1-to-1 dilution of resin with fugitive produced the optimum binder for injection and carbonization, where the fired matrix in such rods contained about 20 wt% binder char and 80 wt% powdered graphite. Thermosetting fuel rods diluted with various amounts of fugitive to give binder chars that range from 12 to 48 wt% of the fired matrix have been subjected to irradiation screening tests, and rods with no more than 32 wt% binder char appear to perform about as well under irradiation as do pitch-based rods. However, particle damage does begin to occur in those lightly diluted rods in which the less-stable binder char constitutes more than 32 wt% of the fired matrix. (author)

  18. Radionuclide composition in nuclear fuel waste. Calculations performed by ORIGEN2

    International Nuclear Information System (INIS)

    Lyckman, C.

    1996-01-01

    The report accounts for results from calculations on the content of radionuclides in nuclear fuel waste. It also accounts for the results from calculations on the neutron flow from spent fuel, which is very important during transports. The calculations have been performed using the ORIGEN2 software. The results have been compared to other results from earlier versions of ORIGEN and some differences have been discovered. This is due to the updating of the software. 7 refs, 10 figs, 15 tabs

  19. Gas fired boilers: Perspective for near future fuel composition and impact on burner design process

    OpenAIRE

    Schiro Fabio; Stoppato Anna; Benato Alberto

    2017-01-01

    The advancements on gas boiler technology run in parallel with the growth of renewable energy production. The renewable production will impact on the fuel gas quality, since the gas grid will face an increasing injection of alternative fuels (biogas, biomethane, hydrogen). Biogas allows producing energy with a lower CO2 impact; hydrogen production by electrolysis can mitigate the issues related to the mismatch between energy production by renewable and energy request. These technologies will ...

  20. Mordenite/Nafion and analcime/Nafion composite membranes prepared by spray method for improved direct methanol fuel cell performance

    Science.gov (United States)

    Prapainainar, Paweena; Du, Zehui; Kongkachuichay, Paisan; Holmes, Stuart M.; Prapainainar, Chaiwat

    2017-11-01

    The aim of this work was to improve proton exchange membranes (PEMs) used in direct methanol fuel cells (DMFCs). A membrane with a high proton conductivity and low methanol permeability was required. Zeolite filler in Nafion (NF matrix) composite membranes were prepared using two types of zeolite, mordenite (MOR) and analcime (ANA). Spray method was used to prepare the composite membranes, and properties of the membranes were investigated: mechanical properties, solubility, water and methanol uptake, ion-exchange capacity (IEC), proton conductivity, methanol permeability, and DMFC performance. It was found that MOR filler showed higher performance than ANA. The MOR/Nafion composite membrane gave better properties than ANA/Nafion composite membrane, including a higher proton conductivity and a methanol permeability that was 2-3 times lower. The highest DMFC performance (10.75 mW cm-2) was obtained at 70 °C and with 2 M methanol, with a value 1.5 times higher than that of ANA/Nafion composite membrane and two times higher than that of commercial Nafion 117 (NF 117).

  1. Bayesian modelling of household solid fuel use: insights towards designing effective interventions to promote fuel switching in Africa.

    Science.gov (United States)

    Rehfuess, Eva A; Briggs, David J; Joffe, Mike; Best, Nicky

    2010-10-01

    Indoor air pollution from solid fuel use is a significant risk factor for acute lower respiratory infections among children in sub-Saharan Africa. Interventions that promote a switch to modern fuels hold a large health promise, but their effective design and implementation require an understanding of the web of upstream and proximal determinants of household fuel use. Using Demographic and Health Survey data for Benin, Kenya and Ethiopia together with Bayesian hierarchical and spatial modelling, this paper quantifies the impact of household-level factors on cooking fuel choice, assesses variation between communities and districts and discusses the likely nature of contextual effects. Household- and area-level characteristics appear to interact as determinants of cooking fuel choice. In all three countries, wealth and the educational attainment of women and men emerge as important; the nature of area-level factors varies between countries. In Benin, a two-level model with spatial community random effects best explains the data, pointing to an environmental explanation. In Ethiopia and Kenya, a three-level model with unstructured community and district random effects is selected, implying relatively autonomous economic and social areas. Area-level heterogeneity, indicated by large median odds ratios, appears to be responsible for a greater share of variation in the data than household-level factors. This may be an indication that fuel choice is to a considerable extent supply-driven rather than demand-driven. Consequently, interventions to promote fuel switching will carefully need to assess supply-side limitations and devise appropriate policy and programmatic approaches to overcome them. To our knowledge, this paper represents the first attempt to model the determinants of solid fuel use, highlighting socio-economic differences between households and, notably, the dramatic influence of contextual effects. It illustrates the potential that multilevel and spatial

  2. Effects of Fuel Quantity on Soot Formation Process for Biomass-Based Renewable Diesel Fuel Combustion

    KAUST Repository

    Jing, Wei

    2016-12-01

    Soot formation process was investigated for biomass-based renewable diesel fuel, such as biomass to liquid (BTL), and conventional diesel combustion under varied fuel quantities injected into a constant volume combustion chamber. Soot measurement was implemented by two-color pyrometry under quiescent type diesel engine conditions (1000 K and 21% O2 concentration). Different fuel quantities, which correspond to different injection widths from 0.5 ms to 2 ms under constant injection pressure (1000 bar), were used to simulate different loads in engines. For a given fuel, soot temperature and KL factor show a different trend at initial stage for different fuel quantities, where a higher soot temperature can be found in a small fuel quantity case but a higher KL factor is observed in a large fuel quantity case generally. Another difference occurs at the end of combustion due to the termination of fuel injection. Additionally, BTL flame has a lower soot temperature, especially under a larger fuel quantity (2 ms injection width). Meanwhile, average soot level is lower for BTL flame, especially under a lower fuel quantity (0.5 ms injection width). BTL shows an overall low sooting behavior with low soot temperature compared to diesel, however, trade-off between soot level and soot temperature needs to be carefully selected when different loads are used.

  3. FUEL FORMULATION EFFECTS ON DIESEL FUEL INJECTION, COMBUSTION, EMISSIONS AND EMISSION CONTROL

    Energy Technology Data Exchange (ETDEWEB)

    Boehman, A; Alam, M; Song, J; Acharya, R; Szybist, J; Zello, V; Miller, K

    2003-08-24

    This paper describes work under a U.S. DOE sponsored Ultra Clean Fuels project entitled ''Ultra Clean Fuels from Natural Gas,'' Cooperative Agreement No. DE-FC26-01NT41098. In this study we have examined the incremental benefits of moving from low sulfur diesel fuel and ultra low sulfur diesel fuel to an ultra clean fuel, Fischer-Tropsch diesel fuel produced from natural gas. Blending with biodiesel, B100, was also considered. The impact of fuel formulation on fuel injection timing, bulk modulus of compressibility, in-cylinder combustion processes, gaseous and particulate emissions, DPF regeneration temperature and urea-SCR NOx control has been examined. The primary test engine is a 5.9L Cummins ISB, which has been instrumented for in-cylinder combustion analysis and in-cylinder visualization with an engine videoscope. A single-cylinder engine has also been used to examine in detail the impacts of fuel formulation on injection timing in a pump-line-nozzle fueling system, to assist in the interpretation of results from the ISB engine.

  4. Nuclear fuels

    International Nuclear Information System (INIS)

    Gangwani, Saloni; Chakrabortty, Sumita

    2011-01-01

    Nuclear fuel is a material that can be consumed to derive nuclear energy, by analogy to chemical fuel that is burned for energy. Nuclear fuels are the most dense sources of energy available. Nuclear fuel in a nuclear fuel cycle can refer to the fuel itself, or to physical objects (for example bundles composed of fuel rods) composed of the fuel material, mixed with structural, neutron moderating, or neutron reflecting materials. Long-lived radioactive waste from the back end of the fuel cycle is especially relevant when designing a complete waste management plan for SNF. When looking at long-term radioactive decay, the actinides in the SNF have a significant influence due to their characteristically long half-lives. Depending on what a nuclear reactor is fueled with, the actinide composition in the SNF will be different. The following paper will also include the uses. advancements, advantages, disadvantages, various processes and behavior of nuclear fuels

  5. The effect of the fuel rod friction force to the fuel assembly lateral mechanical characteristics

    International Nuclear Information System (INIS)

    Ha, Dong Geun; Jeon, Sang Youn; Suh, Jung Min

    2012-01-01

    The Fuel Assembly (FA) for light water reactor consists of hundreds of fuel rods, guide tubes, spacer grids, top/bottom nozzles. The guide tubes transmit vertical loads between the top and bottom nozzles, position the fuel rod support grids vertically, react the loads from the fuel rods that are applied to the grids, and provide some of the lateral load capability for the overall fuel assembly. The guide tubes are the structural members of the skeleton assembly. And the spacer grids maintain the fuel rod array by providing positive lateral restraint to the fuel rod but only frictional restraint in the axial direction. Figure 1 shows the outline of skeleton, FA and the location of guide tubes in the view of cross section. 17x17 FA has 24 guide tubes and one instrumentation tube. When the FA is in reactor, the lateral stiffness is one of very important factors from the view point of in reactor integrity of fuel assembly such as guarantee of the cool able geometry, the control rod insertion etc. The lateral stiffness of FA is mainly determined by skeleton lateral stiffness. And the fuel rods loaded in the spacer grids reinforce the FA lateral stiffness. Generally, fuel rods and spacer grids create the nonlinear friction force between fuel rod tube and grid spring/dimple against external lateral force of FA. Thus, it is necessary to study the contribution of the fuel rods friction force to the FA lateral stiffness. So, this paper is to show how much amount of the fuel rod grid interaction contributes to the FA lateral stiffness based on the test results

  6. Performance of Platinum Nanoparticles / Multiwalled Carbon Nanotubes / Bacterial Cellulose Composite as Anode Catalyst for Proton Exchange Membrane Fuel Cells

    Directory of Open Access Journals (Sweden)

    Henry Fonda Aritonang

    2017-05-01

    Full Text Available Highly dispersed platinum (Pt nanoparticles / multiwalled carbon nanotubes (MWCNTs on bacterial cellulose (BC as anode catalysts for proton exchange membrane fuel cells (PEMFC were prepared with various precursors and their electro-catalytic activities towards hydrogen oxidation at 70 oC under non-humidified conditions. The composite was prepared by deposition of Pt nanoparticles and MWCNTs on BC gel by impregnation method using a water solution of metal precursors and MWCNTs followed by reducing reaction using a hydrogen gas. The composite was characterized by using TEM (transmission electron microscopy, EDS (energy dispersive spectroscopy, and XRD (X-ray diffractometry techniques. TEM images and XRD patterns both lead to the observation of spherical metallic Pt nanoparticles with mean diameter of 3-11 nm well impregnated into the BC fibrils. Preliminary tests on a single cell indicate that renewable BC is a good prospect to be explored as a membrane in fuel cell field. Copyright © 2017 BCREC Group. All rights reserved Received: 21st November 2016; Revised: 26th February 2017; Accepted: 27th February 2017 How to Cite: Aritonang, H.F., Kamu, V.S., Ciptati, C., Onggo, D., Radiman, C.L. (2017. Performance of Platinum Nanoparticles / Multiwalled Carbon Nanotubes / Bacterial Cellulose Composite as Anode Catalyst for Proton Exchange Membrane Fuel Cells. Bulletin of Chemical Reaction Engineering & Catalysis, 12 (2: 287-292 (doi:10.9767/bcrec.12.2.803.287-292 Permalink/DOI: http://dx.doi.org/10.9767/bcrec.12.2.803.287-292

  7. Effects of ultra-low sulphur diesel fuel and diesel oxidation catalysts on nitrogen dioxide emissions

    International Nuclear Information System (INIS)

    Stachulak, J.S.; Zarling, D.

    2010-01-01

    Diesel oxidation catalysts (DOCs) are used on diesel equipment in underground mines to reduce exhaust emissions of carbon monoxide (CO), hydrocarbons (C) and odour that are associated with gaseous HCs. New catalysts have also been formulated to minimize sulphate production, but little is know about their effects on nitrogen dioxide (NO 2 ) emissions. DOCs are known to oxidize nitric oxide (NO) to NO 2 , which is more toxic than NO at low levels. Vale Inco uses ultra-low sulphur diesel (ULSD) fuel for its underground diesel equipment. Although ULSD is a cleaner burning fuel, its impact on the emissions performance of DOCs is not fully known. Technical material gathered during a literature review suggested that ULSD fuel may increase NO 2 production if DOCs are used, but that the increase would be small. This paper presented the results of a laboratory evaluation of DOCs with varying amounts of time-in service in Vale Inco mines. The 4 Vale Inco DOCs were found to produce excess NO 2 during some test conditions. In both steady-state and transient testing, there were no obvious trends in NO 2 increases with increasing DOC age. Two possibilities for these observations are that the DOCs may have been well within their useful life or their initial compositions differed. Future studies will make use of improved instrumentation, notably NO 2 analyzers, to definitely determine the influence of DOCs on NO 2 formation. 13 refs., 1 tab., 8 figs.

  8. MOX fuel effective behaviour modeling by a micro-mechanical nonuniform transformation field analysis

    International Nuclear Information System (INIS)

    Largenton, R.

    2012-01-01

    The objective of this research thesis is to develop a modelling by scale change, based on the NTFA approach (Non uniform Transformation Field Analysis). These developments have been achieved on three-dimensional structures which are representative of the MOX fuel, and for local visco-elastic ageing behaviour with free deformations. First, the MOX fuel is represented by using existing methods to process and segment 2D experimental images. 2D information has been upgraded in 3D by a stereo-logic Saltykov method. Tools have been developed to represent and discretize (periodic 3D grid generator) a particulate multiphase composite representative of MOX. Developments made on the NTFA model and on the three-phase particulate composite have been theoretically and numerically studied. The model has then been validated by comparison with reference calculations performed in full field for the effective behaviour as well as for local fields for different test types (imposed strain rate, creep, relaxation, rotating). The approach is then compared with a recently developed homogenisation method: the semi-analytical 'incremental Mori-Tanka' model. Theoretical similarities are outlined. These methods are very fast in terms of CPU time, but the NTFA method remains the one giving the most information, and the most precise, but requires a more important preliminary work (mode identification) [fr

  9. Composition calculations by the KARATE code system for the spent-fuel samples from the Novovoronezh reactor

    International Nuclear Information System (INIS)

    Hordosy, G.

    2006-01-01

    KARATE is a code system developed in KFKI AERI. It is routinely used for core calculation. Its depletion module are now tested against the radiochemical measurements of spent fuel samples from the Novovoronezh Unit IV, performed in RIAR, Dimitrovgrad. Due to the insufficient knowledge of operational history of the unit, the irradiation history of the samples was taken from formerly published Russian calculations. The calculation of isotopic composition was performed by the MULTICEL module of program system. The agreement between the calculated and measured values of the concentration of the most important actinides and fission products is investigated (Authors)

  10. The possible effects of alfa and beta radiolysis on the matrix dissolution of spent nuclear fuel

    International Nuclear Information System (INIS)

    Grenthe, I.; Puigdomenech, I.; Bruno, J.

    1983-01-01

    The effects of oxidants on the retainment of actinides in a nuclear repository have been modelled by using an equilirium procedure. The oxidants are formed as a result of α- and #betta#-radiolysis when spent nuclear fuel is exposed to ground water. From an equilibrium point of view, the strongest reductants in the system (Zr, Pb and Cu) are expected to be oxidized first, leaving the actinoids in the oxidation states they have in the fuel matrix. This is expected to result in a negligible mobilization of the actinoids due to the very low solubility of the MO 2 oxides. However, the formation of protective layers of oxides will most likely decrease the effectiveness of the metallic reducing agents. This will lead to an increased oxidation of the spent fuel which results in an increased actinoid mobilization. The results of the equilibrium calculations show that the oxidation of the fuel matrix results in the formation of UO 2 (OH) 2 (s) and to the formation of the soluble complex UO 2 (CO 3 ) 3 4 . The transport of uranium is limited by the total concentration of carbonate in the aqueous phase. Neptunium may be quantitatvely solubilized as various Np(V) species and transported by ground water from the repository. Plutonium is retained at the repository site as insoluble PuO 2 . Only very small amounts are transported by ground water. The mobile actinoids may be reprecipitated when they encounter reducing conditions along the flow path. The conditions for repricipitation for typical ground water compositions have been modelled by using solubility - pe diagrams. (Authors)

  11. Nuclear fuel assembly

    International Nuclear Information System (INIS)

    Hirano, Yasushi; Hirukawa, Koji; Sakurada, Koichi.

    1994-01-01

    A bundle of fuel rods is divided into four fuel rod group regions of small fuel rod bundles by a cross-shaped partitioning structure consisting of paired plate-like structures which connect two opposing surfaces of a channel box. A water removing material with less neutron absorption (for example, Zr or a Zr alloy) or a solid moderator is inserted and secured to a portion of a non-boiling water region interposed between the paired plate-like structure. It has a structure that light water flows to the region in the plate-like structure. The volume, density or composition of the water removing material is controlled depending on the composition of the fuels, to change the moderating characteristics of neutrons in the non-boiling water region. This can easily moderate the difference of nuclear characteristics between each of fuel assemblies using fuel materials of different fuel compositions. Further, the reactivity control effect of the burnable poisons can be enhanced without worsening fuel economy or linear power density. (I.N.)

  12. Prepreg effects on honeycomb composite manufacturing

    Science.gov (United States)

    Martin, Cary Joseph

    Fiber reinforced composites offer many advantages over traditional materials and are widely utilized in aerospace applications. Advantages include a high stiffness to weight ratio and excellent fatigue resistance. However, the pace of new implementation is slow. The manufacturing processes used to transform composite intermediates into final products are poorly understood and are a source of much variability. This limits new implementation and increases the manufacturing costs of existing designs. One such problem is honeycomb core crush, in which a core-stiffened structure collapses during autoclave manufacture, making the structure unusable and increasing the overall manufacturing cost through increased scrap rates. Consequently, the major goal of this research was to investigate the scaling of core crush from prepreg process-structure-property relations to commercial composite manufacture. The material dependent nature of this defect was of particular interest. A methodology and apparatus were developed to measure the frictional resistance of prepreg materials under typical processing conditions. Through a characterization of commercial and experimental prepregs, it was found that core crush behavior was the result of differences in prepreg frictional resistance. This frictional resistance was related to prepreg morphology and matrix rheology and elasticity. Resin composition and prepreg manufacturing conditions were also found to affect manufacturing behavior. Mechanical and dimensional models were developed and demonstrated utility for predicting this crushing behavior. Collectively, this work explored and identified the process-structure-property relations as they relate to the manufacture of composite materials and suggested several avenues by which manufacturing-robust materials may be developed.

  13. The effect of injection timing on energy and exergy analysis of a diesel engine with biodiesel fuel

    Directory of Open Access Journals (Sweden)

    A Farhadi

    2017-05-01

    Full Text Available Introduction Nowadays, due to higher environmental pollution and decreasing fossil fuels many countries make decisions to use renewable fuels and restrict using of fossil fuels. Renewable fuels generally produce from biological sources. Biodiesel is an alternative diesel fuel derived from the transesterification of vegetable oils, animal fats, or waste frying oils. Considering the differences between diesel and biodiesel fuels, engine condition should be modified based on the fuel or fuel blends to achieve optimum performance. One of the simplest and yet the most widely used models is the thermodynamic model. After verification of the data obtained by model with experimental data it is possible to generalize the extracted data to an unlimited number of functional conditions or unlimited number of fuel types which saves time and reduces costs for experimental engine tests. Using the second law of thermodynamics, it is possible to calculate and analyze the exergy of the engine.4 Materials and Methods In this work, the zero-dimensional model was used to account for internal energy variations, pressure work, heat transfer losses to the solid walls and heat release. The applied assumptions include: The cylinder mixture temperature, pressure and composition were assumed uniform throughout the cylinder. Furthermore, the one-zone thermodynamic model assumes instantaneous mixing between the burned and unburned gases. The cylinder gases were assumed to behave as an ideal gas mixture, Gas properties, include enthalpy, internal energy modeled using polynomial equations associated with temperature. In this research, the equations 1 to 20 were used in Fortran programming language. The results of incylinder pressure obtained by the model were validated by the results of experimental test of OM314 engine. Then the effects of injection timing on Energy and Exergy of the engine were analyzed for B20 fuel. Results and Discussion Comparing the results of the model

  14. Fuel assembly

    International Nuclear Information System (INIS)

    Sano, Hiroki; Fushimi, Atsushi; Tominaga, Kenji; Aoyama, Motoo; Ishii, Kazuya.

    1997-01-01

    In burnable poison-incorporated uranium fuels of a BWR type reactor, the compositional ratio of isotopes of the burnable poisons is changed so as to increase the amount of those having a large neutron absorbing cross sectional area. For example, if the ratio of Gd-157 at the same burnable poison enrichment degree is made greater than the natural ratio, this gives the same effect as the increase of the enrichment degree per one fuel rod, thereby providing an effect of reducing a surplus reactivity. Gadolinium, hafnium and europium as burnable poisons have an absorbing cross sectional area being greater in odd numbered nuclei than in even numbered nuclei, on the contrary, boron has a cross section being greater in even numbered nucleus than odd numbered nuclei. Accordingly, if the ratio of isotopes having greater cross section at the same burnable poison enrichment degree is made greater than the natural ratio, surplus reactivity at the initial stage of the burning can be reduced without greatly increasing the amount of burnable poison-incorporated uranium fuels, fuel loading amount is not reduced and the fuel economy is not worsened. (N.H.)

  15. Influence de la nature des fuels lourds sur la qualité de leur combustion Influence of Heavy Fuel Oil Composition on Particulate Emissions

    Directory of Open Access Journals (Sweden)

    Feugier A.

    2006-11-01

    heavy fuel oils in a 1 MW boiler and an 0. 1 MW furnace, the conclusion was reached that Conradson carbon residue (CCR of fuel oils is a good indicator of their combustibility, but that it is not sufficient in all cases, i. e. for the same CCR, different values of particulate emissions can be measured. Several possible interpretations were proposed and checked:(a Conradson carbon residue is the result of slow pyrolysis, but it is a procedure that is not sufficiently representative of actual conditions. Yet, by subjecting various fuel oils to flash pyrolysis (heated-grid technique, a good correlation is found between the amount of residue resulting and the CCR. Therefore the CCR remains a good combustibility indicator. (b For fuel oils ex atmospheric residue, ex vacuum residue and ex deasphalting, satisfactory correlations have been observed between CCR and various physicochemical properties of the heavy fractions of fuel oils (cut point of 450°C chosen, i. e. polyaromaticity (measured by carbon 13 NMR, C/H and molecular weight. However, visbreaking fuel oils meet other correlations, as do steam-cracking residues. Hence for these classes of fuel oils, anomalies can be predicted between the particulate emissions and CCR, which is effectively observed with some equipments. (c For the same CCR value, the relative proportion between light and heavy fractions of fuels can sometimes be seen to vary quite appreciably, thus causing changes in the richness and temperature maps of the resulting flames, and hence variations in particulate emissions. The extent of such variations will depend on the types of burners and combustion chambers in which the flame develops.

  16. Effect of Heterogeneity of JSFR Fuel Assemblies to Power Distribution

    International Nuclear Information System (INIS)

    Takeda, Toshikazu; Shimazu, Yoichiro; Hibi, Koki; Fujimura, Koji

    2013-01-01

    Conclusion: 1) Strong heterogeneity of JSFR assemblies was successfully calculated by BACH. 2) Verification test of BACH: • Infinite assembly model; • Color set model; • Good agreement with Monte-Carlo results. 3) Core calculations 3 models for inner duct was used; inward model, outward model and homogeneous model. • k eff difference between the inward and out ward model → 0.3%Δk; • ~20% effect on flux and power distributions. Therefore, we have to pay careful attention for the location of inner duct in fuel loading of JSFR

  17. Investigation of microalgae HTL fuel effects on diesel engine performance and exhaust emissions using surrogate fuels

    International Nuclear Information System (INIS)

    Hossain, Farhad M.; Nabi, Md. Nurun; Rainey, Thomas J.; Bodisco, Timothy; Rahman, Md. Mostafizur; Suara, Kabir; Rahman, S.M.A.; Van, Thuy Chu; Ristovski, Zoran; Brown, Richard J.

    2017-01-01

    Highlights: • Development of a microalgae HTL surrogate of biocrude fuel using chemical compounds. • Physiochemical properties of surrogate blends were analysed. • Experimentally investigated diesel engine performance and emissions using surrogate fuels. • No significant changes in engine performance were observed with HTL surrogate blends. • Major emissions including PM, PN and CO were reduced significantly with increasing of NOx emission. - Abstract: This paper builds on previous work using surrogate fuel to investigate advanced internal combustion engine fuels. To date, a surrogate fuel of this nature has not been used for microalgae hydrothermal liquefaction (HTL) biocrude. This research used five different chemical groups found in microalgae HTL biocrude to design a surrogate fuel. Those five chemical groups constitute around 65% (by weight) of a microalgae biocrude produced by HTL. Weight percentage of the microalgae HTL biocrude chemical compounds were used to design the surrogate fuel, which was miscible with diesel at all percentages. The engine experiments were conducted on a EURO IIIA turbocharged common-rail direct-injection six-cylinder diesel engine to test engine performance and emissions. Exhaust emissions, including particulate matter and other gaseous emissions, were measured with the surrogate fuel and a reference diesel fuel. Experimental results showed that without significantly deteriorating engine performance, lower particulate mass, particulate number and CO emissions were observed with a penalty in NOx emissions for all surrogate blends compared to those of the reference diesel.

  18. Effects of composite mango ( Mangifera indica ) fruit reject meal on ...

    African Journals Online (AJOL)

    Effects of composite mango ( Mangifera indica ) fruit reject meal on growth performance, digestibility and economics of production of rabbits. ... The experiment was conducted to determine the effect of mango fruit reject ... HOW TO USE AJOL.

  19. The Effect of adding pore formers on the microstructure of NiO-YSZ ceramic composite

    International Nuclear Information System (INIS)

    Silva, F.S.; Santos, F.S.; Medeiros, L.M.; Yoshito, W.K.; Lazar, D.R.R.; Ussui, V.

    2011-01-01

    The ceramic composite of nickel oxide (NiO) with zirconium stabilized with 8 mol% yttria (8-YSZ) is the most employed material for use as anode for solid oxide fuel cells (SOFC). The nickel oxide in the composite is reduced to metallic nickel and this result in a 15% of porosity although the porosity needed to a proper function of an anode is about 30%, demanding the use of a pore former. In this work, NiO-YSZ composite powders were synthesized by a combustion process with urea as fuel, and the effect of the addition of carbon black and corn and rice starch as pore former were investigated. Powders were pressed as cylindrical pellets, sintered at 1350 °C for 60 minutes and density were measured by an immersion method and microstructure were observed by scanning electron microscopy. Results showed that ceramic composite has homogeneous microstructure and pores have different morphology and size depending on the kind of the pore former employed. (author)

  20. Pre-conceptual Development and characterization of an extruded graphite composite fuel for the TREAT Reactor

    Energy Technology Data Exchange (ETDEWEB)

    Luther, Erik; Rooyen, Isabella van; Leckie, Rafael; Papin, Pallas; Nelson, Andrew; Hunter, James

    2015-03-01

    In an effort to explore fuel systems that are more robust under accident scenarios, the DOE-NE has identified the need to resume transient testing. The Transient Reactor Test (TREAT) facility has been identified as the preferred option for the resumption of transient testing of nuclear fuel in the United States. In parallel, NNSA’s Global Threat Reduction Initiative (GTRI) Convert program is exploring the needs to replace the existing highly enriched uranium (HEU) core with low enriched uranium (LEU) core. In order to construct a new LEU core, materials and fabrication processes similar to those used in the initial core fabrication must be identified, developed and characterized. In this research, graphite matrix fuel blocks were extruded and materials properties of were measured. Initially the extrusion process followed the historic route; however, the project was expanded to explore methods to increase the graphite content of the fuel blocks and explore modern resins. Materials properties relevant to fuel performance including density, heat capacity and thermal diffusivity were measured. The relationship between process defects and materials properties will be discussed.

  1. Effect of Syngas Moisture Content on the Emissions of Micro-Gas Turbine Fueled with Syngas/LPG in Dual Fuel Mode

    Directory of Open Access Journals (Sweden)

    Sadig Hussain

    2014-07-01

    Full Text Available Syngas produced by gasification has a potential to be one of the fueling solutions for gas turbines in the future. In addition to the combustible constituents and inert gases, syngas derived by gasification contains a considerable amount of water vapor which effect on syngas combustion behaviour. In this work, a micro-gas turbine with a thermal capacity of 50 kW was simulated using ASPEN Plus. The micro gas turbine system emissions were characterized using dry syngas fuels with a different composition, syngas 1 (10.53% H2, 24.94% CO, 2.03% CH4, 12.80% CO2, and 49.70% N2 and syngas 2 (21.62% H2, 32.48% CO, 3.72% CH4, 19.69% CO2, and 22.49% N2 mixed with LPG in a dual fueling mode. The effect of syngas moisture content was then studied by testing the system with moist syngas/LPG with a moisture content ranging from 0 to 20% by volume. The study demonstrates that the syngas moisture content has high influence on nitrogen oxides and carbon monoxide emissions. It’s found that for 5% syngas moisture content, the NOx emission were reduced by 75.5% and 83% for Syngas 1 and Syngas 2 respectively. On carbon monoxide emissions and for same moisture content ratio, the reduction was found to be 43% and 57% for syngas1 and syngas 2 respectively.

  2. Algorithm of constructing hybrid effective modules for elastic isotropic composites

    Science.gov (United States)

    Svetashkov, A. A.; Miciński, J.; Kupriyanov, N. A.; Barashkov, V. N.; Lushnikov, A. V.

    2017-02-01

    The algorithm of constructing of new effective elastic characteristics of two-component composites based on the superposition of the models of Reiss and Voigt, Hashin and Strikman, as well as models of the geometric average for effective modules. These effective characteristics are inside forks Voigt and Reiss. Additionally, the calculations of the stress-strain state of composite structures with new effective characteristics give more accurate prediction than classical models do.

  3. Characterizing fuels in treated areas.

    Science.gov (United States)

    Roger D. Ottmar; Clinton S. Wright

    2002-01-01

    Small-log utilization or thinning operations followed by a fuel treatment such as prescribed fire can be used to change the composition and structure of fuelbeds, thereby mitigating deleterious fire effects and reducing the potential for catastrophic wildfires in some forested landscapes. We are developing a national system, Fuel Characteristic Classification (FCC),...

  4. The effects of changing municipal solid waste characteristics on combustion fuel quality

    International Nuclear Information System (INIS)

    Artz, N.S.; Franklin, M.A.

    1991-01-01

    This paper discusses the quality of municipal solid waste (MSW) as a combustion fuel based on two aspects: heat of combustion and heavy metal content. Characterization of MSW by the material flows methodology now provides a historical data series on the composition of MSW for nearly 30 years (1960-1988). Over this period, there have been marked changes in MSW composition, with paper and plastics increasing in percentage while glass and metals have declined. This paper will illustrate the effects of this changing composition on heat of combustion. Using a computer model and standard heat of combustion values for the components of MSW, heating values of MSW (in Btu per pound) are calculated for the 30-year time period. Changes in heating values are highlighted and projections are made to year 2010. Recognizing the increasing importance of the recovery of materials from MSW for recycling, the paper illustrates the effects of removing varying quantities of recyclable materials (e.g., newspapers, corrugated boxes, plastic bottles, glass bottles, metals, yard wastes) on the heating value of the remaining MSW. The paper's final section summarizes recent studies performed for EPA and others on the presence of heavy metals (lead, cadmium, and mercury) in the products discarded in MSW. Again, time trends are used to demonstrate the changing presence of these metals

  5. Water reactor fuel element fabrication, with special emphasis on its effects on fuel performance

    International Nuclear Information System (INIS)

    1979-01-01

    Full text: The performance of nuclear fuel has improved over the years and is now a minor cause of outages and of power limitations in nuclear power plants. On the other hand, an increasing number of countries are in the process of developing or implementing their own capability for manufacturing fuel elements. In this context, the IAEA International Working Group on Water Reactor Fuel Performance and Technology (IWGFPT) advised that a symposium be organized devoted to the relationship between fuel fabrication and performance The Czechoslovak Atomic Energy Commission agreed to co-operate in the organization of this symposium and to host it in Prague. Those factors which influence fuel fabrication requirements are now well ascertained: as little reactor primary circuit contamination as possible, the tendency to increased burnups, reactor manoeuverability to match power grid demands, the desirability of an autonomous fabrication capability. It is the general experience of fuel element suppliers that fuel quality and performance has increased over the years, the importance of quality assurance and process monitoring has been decisive in this respect The ever increasing mass-production aspect of nuclear fuel leads to some processing steps being revised and alternatives being developed. The relation between fabrication processes and fuel performance characteristics, although generally well perceived, are still the subject of a large amount of experiment and assessment in most countries, both industrial and developing This evidence is most encouraging; it means indeed that nuclear power, which is already amongst the cheapest and safest sources of energy, will continue to be improved. The performance of Zircaloy fuel cladding - presently the material used in most water reactors - is under particular consideration. Better understanding of this quite recent alloy will pave the way for broader fuel utilization limits in the future. The panel discussion, which noted some

  6. The determinants of fuel use in the trucking industry – volume, size and the rebound effect

    DEFF Research Database (Denmark)

    Mulalic, Ismir

    2011-01-01

    We analyse the determinants of trucking firm fuel use. We develop a simple model to show that trucking firm fuel use depends, in addition to the fuel price and the traffic volume, also on the output of the trucking firm’s production process (the movement of cargo) measured in tonkilometres...... these elasticities using a simultaneous-equation model based on aggregate time-series data for Denmark for 1980-2007. Our best estimates of the short run and the long run rebound effects for road freight transportation are 19% and 28%, respectively. We also find that an increase in the fuel price surprisingly has...... a small but significant negative effect on the fuel efficiency (measured here as vehicle kilometres travelled (VKT) per litre of consumed fuel), i.e. a 1% increase in the fuel price decreases the fuel efficiency by 0.13% in the long run. However, less distance has to be driven for the same payload. An 1...

  7. URANIUM OXIDE-CONTAINING FUEL ELEMENT COMPOSITION AND METHOD OF MAKING SAME

    Science.gov (United States)

    Handwerk, J.H.; Noland, R.A.; Walker, D.E.

    1957-09-10

    In the past, bodies formed of a mixture of uranium dioxide and aluminum powder have been used in fuel elements; however, these mixtures were found not to be suitable when exposed to temperatures of about 600 deg C, because at such high temperatures the fuel elements were distorted. If uranosic oxide, U/sub 3/O/sub 8/, is substituted for UO/sub 2/, the mechanical properties are not impaired when these materials are used at about 600 deg C and no distortion takes place. The uranosic oxide and aluminum, both in powder form, are first mixed, and after a homogeneous mixture has been obtained, are shaped into fuel elements by extrusion at elevated temperature. Magnesium powder may be used in place of the aluminum.

  8. Optimisation of polypyrrole/Nafion composite membranes for direct methanol fuel cells

    International Nuclear Information System (INIS)

    Zhu Jun; Sattler, Rita R.; Garsuch, Arnd; Yepez, Omar; Pickup, Peter G.

    2006-01-01

    Acidic and neutral Nafion[reg] 115 perfluorosulphonate membranes have been modified by in situ polymerization of pyrrole using Fe(III) and H 2 O 2 as oxidizing agents, in order to decrease methanol crossover in direct methanol fuel cells. Improved selectivities for proton over methanol transport and improved fuel cell performances were only obtained with membranes that were modified while in the acid form. Use of Fe(III) as the oxidizing agent can produce a large decrease in methanol crossover, but causes polypyrrole deposition on the surface of the membrane. This increases the resistance of the membrane, and leads to poor fuel cell performances due to poor bonding with the electrodes. Surface polypyrrole deposition can be minimized, and surface polypyrrole can be removed, by using H 2 O 2 . The use of Nafion in its tetrabutylammonium form leads to very low methanol permeabilities, and appears to offer potential for manipulating the location of polypyrrole within the Nafion structure

  9. Emergency fuels utilization guidebook. Alternative Fuels Utilization Program

    Energy Technology Data Exchange (ETDEWEB)

    1980-08-01

    The basic concept of an emergency fuel is to safely and effectively use blends of specification fuels and hydrocarbon liquids which are free in the sense that they have been commandeered or volunteered from lower priority uses to provide critical transportation services for short-duration emergencies on the order of weeks, or perhaps months. A wide variety of liquid hydrocarbons not normally used as fuels for internal combustion engines have been categorized generically, including limited information on physical characteristics and chemical composition which might prove useful and instructive to fleet operators. Fuels covered are: gasoline and diesel fuel; alcohols; solvents; jet fuels; kerosene; heating oils; residual fuels; crude oils; vegetable oils; gaseous fuels.

  10. Effects of fuel treatments on carbon-disturbance relationships in forests of the northern Rocky Mountains

    Science.gov (United States)

    Elizabeth Reinhardt; Lisa Holsinger

    2010-01-01

    Fuel treatments alter conditions in forested stands at the time of the treatment and subsequently. Fuel treatments reduce on-site carbon and also change the fire potential and expected outcome of future wildfires, including their carbon emissions. We simulated effects of fuel treatments on 140 stands representing seven major habitat type groups of the northern Rocky...

  11. Trace element partitioning in ashes from boilers firing pure wood or mixtures of solid waste with respect to fuel composition, chlorine content and temperature.

    Science.gov (United States)

    Saqib, Naeem; Bäckström, Mattias

    2014-12-01

    Trace element partitioning in solid waste (household waste, industrial waste, waste wood chips and waste mixtures) incineration residues was investigated. Samples of fly ash and bottom ash were collected from six incineration facilities across Sweden including two grate fired and four fluidized bed incinerators, to have a variation in the input fuel composition (from pure biofuel to mixture of waste) and different temperature boiler conditions. As trace element concentrations in the input waste at the same facilities have already been analyzed, the present study focuses on the concentration of trace elements in the waste fuel, their distribution in the incineration residues with respect to chlorine content of waste and combustion temperature. Results indicate that Zn, Cu and Pb are dominating trace elements in the waste fuel. Highly volatile elements mercury and cadmium are mainly found in fly ash in all cases; 2/3 of lead also end up in fly ash while Zn, As and Sb show a large variation in distribution with most of them residing in the fly ash. Lithophilic elements such as copper and chromium are mainly found in bottom ash from grate fired facilities while partition mostly into fly ash from fluidized bed incinerators, especially for plants fuelled by waste wood or ordinary wood chips. There is no specific correlation between input concentration of an element in the waste fuel and fraction partitioned to fly ash. Temperature and chlorine content have significant effects on partitioning characteristics by increasing the formation and vaporization of highly volatile metal chlorides. Zinc and cadmium concentrations in fly ash increase with the incineration temperature. Copyright © 2014 Elsevier Ltd. All rights reserved.

  12. Methanol-Tolerant Cathode Catalyst Composite For Direct Methanol Fuel Cells

    Science.gov (United States)

    Zhu, Yimin; Zelenay, Piotr

    2006-03-21

    A direct methanol fuel cell (DMFC) having a methanol fuel supply, oxidant supply, and its membrane electrode assembly (MEA) formed of an anode electrode and a cathode electrode with a membrane therebetween, a methanol oxidation catalyst adjacent the anode electrode and the membrane, an oxidant reduction catalyst adjacent the cathode electrode and the membrane, comprises an oxidant reduction catalyst layer of a platinum-chromium alloy so that oxidation at the cathode of methanol that crosses from the anode through the membrane to the cathode is reduced with a concomitant increase of net electrical potential at the cathode electrode.

  13. Effect of cathode gas humidification on performance and durability of Solid Oxide Fuel Cells

    DEFF Research Database (Denmark)

    Nielsen, Jimmi; Hagen, Anke; Liu, Yi-Lin

    2010-01-01

    The effect of cathode inlet gas humidification was studied on single anode supported Solid Oxide Fuel Cells (SOFC's). The studied cells were Risø 2 G and 2.5 G. The former consists of a LSM:YSZ composite cathode, while the latter consists of a LSCF:CGO composite cathode on a CGO protection layer....... The humidification effect was found to be dependent on both the degree of humidification and the cathode polarization. No significant effect of humidification was found at OCV which rules out the possibility of a traditional poisoning effect with a blocking of active sites. Post-mortem high resolution FEG......-SEM analysis showed clear changes at and around the cathode/electrolyte contact area. In contrast to Risø 2 G cells, a very high tolerance towards humidification of cathode gas air was observed for Risø 2.5 G cells with no detectable effect of humidification even when the humidification was as high as 12.8 mol%...

  14. A study on domino effect in nuclear fuel cycle facilities

    International Nuclear Information System (INIS)

    Bozzolan, Jean-Claude

    2006-01-01

    Accidents caused by domino effect are among the most severe accidents in the chemical and process industry. Although the destructive potential of these accidental scenarios is widely known, little attention has been paid to this problem in the technical literature and a complete methodology for quantitative assessment of domino accidents contribution to industrial risk is still lacking. The present study proposed a systematic procedure for the quantitative assessment of the risk caused by domino effect in chemical plants that are part of nuclear fuel cycle plants. This work is based on recent advances in the modeling of fire and explosion damage to process equipment due to different escalation vectors (heat radiation, overpressure and fragment projection). Available data from literature and specific vulnerability models derived for several categories of process equipment had been used in the present work. The proposed procedure is applied to a typical storage area of a reconversion plant situated in a complex that shelters other nuclear fuel cycle facilities. The top-events and escalation vectors are identified, their consequences estimated and credible domino scenarios selected on the basis of their frequencies. (author)

  15. Irradiation effects on thermal properties of LWR hydride fuel

    Energy Technology Data Exchange (ETDEWEB)

    Terrani, Kurt, E-mail: terrani@berkeley.edu [University of California, 4155 Etcheverry Hall, M.C. 1730, Berkeley, CA 94720-1730 (United States); Balooch, Mehdi [University of California, 4155 Etcheverry Hall, M.C. 1730, Berkeley, CA 94720-1730 (United States); Carpenter, David; Kohse, Gordon [Massachusetts Institute of Technology, 138 Albany St., Cambridge, MA 02139 (United States); Keiser, Dennis; Meyer, Mitchell [Idaho National Laboratory, Idaho Falls, ID 83415 (United States); Olander, Donald [University of California, 4155 Etcheverry Hall, M.C. 1730, Berkeley, CA 94720-1730 (United States)

    2017-04-01

    Three hydride mini-fuel rods were fabricated and irradiated at the MIT nuclear reactor with a maximum burnup of 0.31% FIMA or ∼5 MWd/kgU equivalent oxide fuel burnup. Fuel rods consisted of uranium-zirconium hydride (U (30 wt%)ZrH{sub 1.6}) pellets clad inside a LWR Zircaloy-2 tubing. The gap between the fuel and the cladding was filled with lead-bismuth eutectic alloy to eliminate the gas gap and the large temperature drop across it. Each mini-fuel rod was instrumented with two thermocouples with tips that are axially located halfway through the fuel centerline and cladding surface. In-pile temperature measurements enabled calculation of thermal conductivity in this fuel as a function of temperature and burnup. In-pile thermal conductivity at the beginning of test agreed well with out-of-pile measurements on unirradiated fuel and decreased rapidly with burnup.

  16. Source Reduction Effectiveness at Fuel Contaminated Sites, Technical Summary Report

    National Research Council Canada - National Science Library

    2000-01-01

    This report assesses the degree to which various types or engineered source-reduction efforts at selected fuel-contaminated sites have resulted in decreasing concentrations of fuel constituents dissolved in groundwater...

  17. Effects of Fiber Coating Composition on Mechanical Behavior of Silicon Carbide Fiber-Reinforced Celsian Composites

    Science.gov (United States)

    Bansal, Narottam P.; Elderidge, Jeffrey I.

    1998-01-01

    Celsian matrix composites reinforced with Hi-Nicalon fibers, precoated with a dual layer of BN/SiC by chemical vapor deposition in two separate batches, were fabricated. Mechanical properties of the composites were measured in three-point flexure. Despite supposedly identical processing, the composite panels fabricated with fibers coated in two batches exhibited substantially different mechanical behavior. The first matrix cracking stresses (sigma(sub mc)) of the composites reinforced with fibers coated in batch 1 and batch 2 were 436 and 122 MPa, respectively. This large difference in sigma(sub mc) was attributed to differences in fiber sliding stresses(tau(sub friction)), 121.2+/-48.7 and 10.4+/-3.1 MPa, respectively, for the two composites as determined by the fiber push-in method. Such a large difference in values of tau(sub friction) for the two composites was found to be due to the difference in the compositions of the interface coatings. Scanning Auger microprobe analysis revealed the presence of carbon layers between the fiber and BN, and also between the BN and SiC coatings in the composite showing lower tau(sub friction). This resulted in lower sigma(sub mc) in agreement with the ACK theory. The ultimate strengths of the two composites, 904 and 759 MPa, depended mainly on the fiber volume fraction and were not significantly effected by tau(sub friction) values, as expected. The poor reproducibility of the fiber coating composition between the two batches was judged to be the primary source of the large differences in performance of the two composites.

  18. Fuel cycles with high fuel burn-up: analysis of reactivity coefficients

    International Nuclear Information System (INIS)

    Kryuchkov, E.F.; Shmelev, A.N.; Ternovykh, M.J.; Tikhomirov, G.V.; Jinhong, L.; Saito, M.

    2003-01-01

    Fuel cycles of light-water reactors (LWR) with high fuel burn-up (above 100 MWd/kg), as a rule, involve large amounts of fissionable materials. It leads to forming the neutron spectrum harder than that in traditional LWR. Change of neutron spectrum and significant amount of non-traditional isotopes (for example, 237 Np, 238 Pu, 231 Pa, 232 U) in such fuel compositions can alter substantially reactivity coefficients as compared with traditional uranium-based fuel. The present work addresses the fuel cycles with high fuel burn-up which are based on Th-Pa-U and U-Np-Pu fuel compositions. Numerical analyses are carried out to determine effective neutron multiplication factor and void reactivity coefficient (VRC) for different values of fuel burn-up and different lattice parameters. The algorithm is proposed for analysis of isotopes contribution to these coefficients. Various ways are considered to upgrade safety of nuclear fuel cycles with high fuel burn-up. So, the results obtained in this study have demonstrated that: -1) Non-traditional fuel compositions developed for achievement of high fuel burn-up in LWR can possess positive values of reactivity coefficients that is unacceptable from the reactor operation safety point of view; -2) The lattice pitch of traditional LWR is not optimal for non-traditional fuel compositions, the increased value of the lattice pitch leads to larger value of initial reactivity margin and provides negative VRC within sufficiently broad range of coolant density; -3) Fuel burn-up has an insignificant effect on VRC dependence on coolant density, so, the measures undertaken to suppress positive VRC of fresh fuel will be effective for partially burnt-up fuel compositions also and; -4) Increase of LWR core height and introduction of additional moderators into the fuel lattice can be used as the ways to reach negative VRC values for full range of possible coolant density variations

  19. Fuel cycles with high fuel burn-up: analysis of reactivity coefficients

    Energy Technology Data Exchange (ETDEWEB)

    Kryuchkov, E.F.; Shmelev, A.N.; Ternovykh, M.J.; Tikhomirov, G.V.; Jinhong, L. [Moscow Engineering Physics Institute (State University) (Russian Federation); Saito, M. [Tokyo Institute of Technology (Japan)

    2003-07-01

    Fuel cycles of light-water reactors (LWR) with high fuel burn-up (above 100 MWd/kg), as a rule, involve large amounts of fissionable materials. It leads to forming the neutron spectrum harder than that in traditional LWR. Change of neutron spectrum and significant amount of non-traditional isotopes (for example, {sup 237}Np, {sup 238}Pu, {sup 231}Pa, {sup 232}U) in such fuel compositions can alter substantially reactivity coefficients as compared with traditional uranium-based fuel. The present work addresses the fuel cycles with high fuel burn-up which are based on Th-Pa-U and U-Np-Pu fuel compositions. Numerical analyses are carried out to determine effective neutron multiplication factor and void reactivity coefficient (VRC) for different values of fuel burn-up and different lattice parameters. The algorithm is proposed for analysis of isotopes contribution to these coefficients. Various ways are considered to upgrade safety of nuclear fuel cycles with high fuel burn-up. So, the results obtained in this study have demonstrated that: -1) Non-traditional fuel compositions developed for achievement of high fuel burn-up in LWR can possess positive values of reactivity coefficients that is unacceptable from the reactor operation safety point of view; -2) The lattice pitch of traditional LWR is not optimal for non-traditional fuel compositions, the increased value of the lattice pitch leads to larger value of initial reactivity margin and provides negative VRC within sufficiently broad range of coolant density; -3) Fuel burn-up has an insignificant effect on VRC dependence on coolant density, so, the measures undertaken to suppress positive VRC of fresh fuel will be effective for partially burnt-up fuel compositions also and; -4) Increase of LWR core height and introduction of additional moderators into the fuel lattice can be used as the ways to reach negative VRC values for full range of possible coolant density variations.

  20. Composite fuels. Defining a strategy for better Pu utilization in PWRs

    Energy Technology Data Exchange (ETDEWEB)

    Porta, Jacques; Baldi, Stefano [DRN/DER/SIS CE Cadarache Bat. 211, 13108 St. Paul lez Durance CEDEX (France); Puill, Andre; Aillaud, Cecile

    1999-07-01

    After a description of the French context dominated by the accumulation of plutonium, and the international context in which the tendency is towards the disappearance of plutonium reserves and the destruction of minor actinides, a few solutions selected in the framework of the Innovating Fuels programme are presented. The aim is to burn the surplus Pu by means of fuel in inert matrices since, in addition to the increased burnup, the absence of plutonium generating conversion must be considered. The experiments intended to qualify selected CERCERs and CERMETs are presented and discussed, the feasibility of CERMET UO2 and MOX cores is established. Things are more complicated for PuO2 CERMET and we show that, in order to optimize loading, a dedicated heterogeneous assembly has to be defined. The Advanced Plutonium Assembly (APA) is presented. The last part of this article is devoted to the first fabrication tests on these very particular fuels and to the definition of reference accidents liable to affect 'cold' fuels such as CERMETs. (author)

  1. Composite fuels. Defining a strategy for better Pu utilization in PWRs

    International Nuclear Information System (INIS)

    Porta, Jacques; Baldi, Stefano; Puill, Andre; Aillaud, Cecile

    1999-01-01

    After a description of the French context dominated by the accumulation of plutonium, and the international context in which the tendency is towards the disappearance of plutonium reserves and the destruction of minor actinides, a few solutions selected in the framework of the Innovating Fuels programme are presented. The aim is to burn the surplus Pu by means of fuel in inert matrices since, in addition to the increased burnup, the absence of plutonium generating conversion must be considered. The experiments intended to qualify selected CERCERs and CERMETs are presented and discussed, the feasibility of CERMET UO2 and MOX cores is established. Things are more complicated for PuO2 CERMET and we show that, in order to optimize loading, a dedicated heterogeneous assembly has to be defined. The Advanced Plutonium Assembly (APA) is presented. The last part of this article is devoted to the first fabrication tests on these very particular fuels and to the definition of reference accidents liable to affect 'cold' fuels such as CERMETs. (author)

  2. Calculating analysis of firing different composition artificial coal liquid fuels (ACLF) in the cyclone primary furnace

    Energy Technology Data Exchange (ETDEWEB)

    Tsepenok, A. [Novosibirsk State Technological Univ. (Russian Federation); Joint Stock company ' ' ZiO-COTES' ' , Novosibirsk (Russian Federation); Ovchinnikov, Yu. [Novosibirsk State Technological Univ. (Russian Federation); Serant, F. [Joint Stock company ' ' ZiO-COTES' ' , Novosibirsk (Russian Federation)

    2013-07-01

    This chapter describes the preparation technologies, results of computer simulation of combustion processes in a cyclone primary furnace during firing of artificial coal liquid fuels prepared from different coal grades and results of live testing. As a result the values of unburned carbon, NO{sub x} emissions and other concentrations in the outlet section primary furnace were estimated.

  3. IMPROVEMENT OF ECOLOGICAL CHARACTERISTICS OF THE DIESEL ENGINE WORKING ON BIODIESEL FUEL COMPOSITIONS

    Directory of Open Access Journals (Sweden)

    A. Levterov

    2015-07-01

    Full Text Available The ways of decreasing the toxicity of exhaust gases produced by the biodiesel engine are determined analitically. Optimization of the corner of advancing the fuel supply and the coefficient of air surplus is offered as the action of adjusting character, providing the improvement of ecological indexes of the biodiesel engine.

  4. Effects of chemical equilibrium on turbine engine performance for various fuels and combustor temperatures

    Science.gov (United States)

    Tran, Donald H.; Snyder, Christopher A.

    1992-01-01

    A study was performed to quantify the differences in turbine engine performance with and without the chemical dissociation effects for various fuel types over a range of combustor temperatures. Both turbojet and turbofan engines were studied with hydrocarbon fuels and cryogenic, nonhydrocarbon fuels. Results of the study indicate that accuracy of engine performance decreases when nonhydrocarbon fuels are used, especially at high temperatures where chemical dissociation becomes more significant. For instance, the deviation in net thrust for liquid hydrogen fuel can become as high as 20 percent at 4160 R. This study reveals that computer central processing unit (CPU) time increases significantly when dissociation effects are included in the cycle analysis.

  5. Antihyperglycemic Effects Of Separate And Composite Extract Of ...

    African Journals Online (AJOL)

    Antihyperglycemic Effects Of Separate And Composite Extract Of Root Of Musa paradisiacal And Leaf Of Coccinia indica In Streptozotocin-Induced Diabetic Male ... We noted that after treatment of aqueous methanolic extract of above plant parts in separate as well as in composite manner at a concentration of 80mg/100g ...

  6. Effect of antimicrobial agents on cellulose acetate nano composites properties

    International Nuclear Information System (INIS)

    Rodriguez, Francisco J.; Bruna, Julio E.; Galotto, Maria J.; Guarda, Abel; Sepulveda, Hugo

    2011-01-01

    Nano composites based on cellulose acetate, Cloisite 30B, triethyl citrate and thymol or cinnamaldehyde were prepared using a dissolution casting technique. The effect of thymol and cinnamaldehyde on the cellulose acetate nano composite properties was evaluated by XRD and DSC. Important changes on the thermal properties and morphological structure were observed according to thymol and cinnamaldehyde content. (author)

  7. Effect of antimicrobial agents on cellulose acetate nano composites properties

    Energy Technology Data Exchange (ETDEWEB)

    Rodriguez, Francisco J.; Bruna, Julio E.; Galotto, Maria J.; Guarda, Abel; Sepulveda, Hugo, E-mail: francisco.rodriguez.m@usach.cl [Center for the Development of Nanoscience and Nanotechnology (CEDENNA). Universidad de Santiago de Chile. Faculty of Technology. Department of Food Science and Technology. Food Packaging Laboratory. Santiago (Chile)

    2011-07-01

    Nano composites based on cellulose acetate, Cloisite 30B, triethyl citrate and thymol or cinnamaldehyde were prepared using a dissolution casting technique. The effect of thymol and cinnamaldehyde on the cellulose acetate nano composite properties was evaluated by XRD and DSC. Important changes on the thermal properties and morphological structure were observed according to thymol and cinnamaldehyde content. (author)

  8. Effect of Soaking Time on Proximate and Mineral Compositions and ...

    African Journals Online (AJOL)

    Effect of soaking time on some composition of yellow maize was investigated. Yellow maize seeds (Zea mays) were soaked in deionized water for 12, 24, 36 and 48 hours respectively followed by draining, drying and milling. The unsoaked seeds were milled and served as the control. Proximate and mineral compositions ...

  9. Effect of Body Composition on Walking Economy

    Directory of Open Access Journals (Sweden)

    Maciejczyk Marcin

    2016-12-01

    Full Text Available Purpose. The aim of the study was to evaluate walking economy and physiological responses at two walking speeds in males with similar absolute body mass but different body composition. Methods. The study involved 22 young men with similar absolute body mass, BMI, aerobic performance, calf and thigh circumference. The participants differed in body composition: body fat (HBF group and lean body mass (HLBM group. In the graded test, maximal oxygen uptake (VO2max and maximal heart rate were measured. Walking economy was evaluated during two walks performed at two different speeds (4.8 and 6.0 km ‧ h-1. Results. The VO2max was similar in both groups, as were the physiological responses during slow walking. The absolute oxygen uptake or oxygen uptake relative to body mass did not significantly differentiate the studied groups. The only indicator significantly differentiating the two groups was oxygen uptake relative to LBM. Conclusions. Body composition does not significantly affect walking economy at low speed, while during brisk walking, the economy is better in the HLBM vs. HBF group, provided that walking economy is presented as oxygen uptake relative to LBM. For this reason, we recommend this manner of oxygen uptake normalization in the evaluation of walking economy.

  10. Trace element partitioning in ashes from boilers firing pure wood or mixtures of solid waste with respect to fuel composition, chlorine content and temperature

    Energy Technology Data Exchange (ETDEWEB)

    Saqib, Naeem, E-mail: naeem.saqib@oru.se; Bäckström, Mattias, E-mail: mattias.backstrom@oru.se

    2014-12-15

    Highlights: • Different solids waste incineration is discussed in grate fired and fluidized bed boilers. • We explained waste composition, temperature and chlorine effects on metal partitioning. • Excessive chlorine content can change oxide to chloride equilibrium partitioning the trace elements in fly ash. • Volatility increases with temperature due to increase in vapor pressure of metals and compounds. • In Fluidized bed boiler, most metals find themselves in fly ash, especially for wood incineration. - Abstract: Trace element partitioning in solid waste (household waste, industrial waste, waste wood chips and waste mixtures) incineration residues was investigated. Samples of fly ash and bottom ash were collected from six incineration facilities across Sweden including two grate fired and four fluidized bed incinerators, to have a variation in the input fuel composition (from pure biofuel to mixture of waste) and different temperature boiler conditions. As trace element concentrations in the input waste at the same facilities have already been analyzed, the present study focuses on the concentration of trace elements in the waste fuel, their distribution in the incineration residues with respect to chlorine content of waste and combustion temperature. Results indicate that Zn, Cu and Pb are dominating trace elements in the waste fuel. Highly volatile elements mercury and cadmium are mainly found in fly ash in all cases; 2/3 of lead also end up in fly ash while Zn, As and Sb show a large variation in distribution with most of them residing in the fly ash. Lithophilic elements such as copper and chromium are mainly found in bottom ash from grate fired facilities while partition mostly into fly ash from fluidized bed incinerators, especially for plants fuelled by waste wood or ordinary wood chips. There is no specific correlation between input concentration of an element in the waste fuel and fraction partitioned to fly ash. Temperature and chlorine

  11. Delayed conifer mortality after fuel reduction treatments: Interactive effects of fuel, fire intensity, and bark beetles

    Science.gov (United States)

    Youngblood, A.; Grace, J.B.; Mciver, J.D.

    2009-01-01

    Many low-elevation dry forests of the western United States contain more small trees and fewer large trees, more down woody debris, and less diverse and vigorous understory plant communities compared to conditions under historical fire regimes. These altered structural conditions may contribute to increased probability of unnaturally severe wildfires, susceptibility to uncharacteristic insect outbreaks, and drought-related mortality. Broad-scale fuel reduction and restoration treatments are proposed to promote stand development on trajectories toward more sustainable structures. Little research to date, however, has quantified the effects of these treatments on the ecosystem, especially delayed and latent tree mortality resulting directly or indirectly from treatments. In this paper, we explore complex hypotheses relating to the cascade of effects that influence ponderosa pine (Pinus ponderosa) and Douglas-fir (Pseudotsuga menziesii) mortality using structural equation modeling (SEM). We used annual census and plot data through six growing seasons after thinning and four growing seasons after burning from a replicated, operational-scale, completely randomized experiment conducted in northeastern Oregon, USA, as part of the national Fire and Fire Surrogate study. Treatments included thin, burn, thin followed by burn (thin+burn), and control. Burn and thin+burn treatments increased the proportion of dead trees while the proportion of dead trees declined or remained constant in thin and control units, although the density of dead trees was essentially unchanged with treatment. Most of the new mortality (96%) occurred within two years of treatment and was attributed to bark beetles. Bark beetle-caused tree mortality, while low overall, was greatest in thin + burn treatments. SEM results indicate that the probability of mortality of large-diameter ponderosa pine from bark beetles and wood borers was directly related to surface fire severity and bole charring, which in

  12. Greenhouse effect and the fuel fossil burning in Brazil

    International Nuclear Information System (INIS)

    Rosa, L.P.; Cecchi, J.C.

    1994-01-01

    In Brazil, the global energy consumption per inhabitant is low and the fraction of renewable energy is high, which represents an advantage in terms of gas released. On the other hand the burning in the Amazon Region releases more greenhouse gases than fossil fuel combustion. This article, considering trends in the energy consumption by different economic sectors, discusses the greenhouse effect and its repercussion in energy planning. As known the energy generation process is in great part responsible for the emission of CO 2 , the main anthropogenic gas which causes the greenhouse effect. A comparison of the brazilian case with other studies from developed countries was made to show the advantages and disadvantages of the adopted energetic solution. Carbon emissions were calculated in different scenarios leading to same interesting conclusions. (B.C.A.)

  13. Modulation of the composite face effect by unintended emotion cues.

    Science.gov (United States)

    Gray, Katie L H; Murphy, Jennifer; Marsh, Jade E; Cook, Richard

    2017-04-01

    When upper and lower regions from different emotionless faces are aligned to form a facial composite, observers 'fuse' the two halves together, perceptually. The illusory distortion induced by task-irrelevant ('distractor') halves hinders participants' judgements about task-relevant ('target') halves. This composite-face effect reveals a tendency to integrate feature information from disparate regions of intact upright faces, consistent with theories of holistic face processing. However, observers frequently perceive emotion in ostensibly neutral faces, contrary to the intentions of experimenters. This study sought to determine whether this 'perceived emotion' influences the composite-face effect. In our first experiment, we confirmed that the composite effect grows stronger as the strength of distractor emotion increased. Critically, effects of distractor emotion were induced by weak emotion intensities, and were incidental insofar as emotion cues hindered image matching, not emotion labelling per se . In Experiment 2, we found a correlation between the presence of perceived emotion in a set of ostensibly neutral distractor regions sourced from commonly used face databases, and the strength of illusory distortion they induced. In Experiment 3, participants completed a sequential matching composite task in which half of the distractor regions were rated high and low for perceived emotion, respectively. Significantly stronger composite effects were induced by the high-emotion distractor halves. These convergent results suggest that perceived emotion increases the strength of the composite-face effect induced by supposedly emotionless faces. These findings have important implications for the study of holistic face processing in typical and atypical populations.

  14. Radiolysis effects on fuel corrosion within a failed nuclear waste container

    International Nuclear Information System (INIS)

    Sunder, S.; Shoeshmith, D.W.; Christensen, H.C.

    2003-01-01

    The concept of geological disposal of used nuclear fuel in corrosion resistant containers is being investigated in several countries. In the Canadian Nuclear Fuel Waste Management Program (CNFWMP), it is assumed that the used fuel will be disposed of in copper containers. Since the predicted lifetimes of these containers are very long (>106 years), only those containers emplaced with an undetected defect will fail within the period for which radionuclide release from the fuel must be considered. Early failure could lead to the entry of water into the container and subsequent release of radionuclides. The release rate of radionuclides from the used fuel will depend upon its dissolution rate. The primary mechanism for release will be the corrosion of the fuel driven by radiolytically-produced oxidants. The studies carried out to determine the effects of water radiolysis on fuel corrosion are reviewed, and some of the procedures used to predict corrosion rates of used fuel in failed nuclear waste containers described. (author)

  15. Effects of cold worked and fully annealed claddings on fuel failure behaviour

    International Nuclear Information System (INIS)

    Saito, Shinzo; Hoshino, Hiroaki; Shiozawa, Shusaku; Yanagihara, Satoshi

    1979-12-01

    Described are the results of six differently heat-treated Zircaloy clad fuel rod tests in NSRR experiments. The purpose of the test is to examine the extent of simulating irradiated claddings in mechanical properties by as-cold worked ones and also the effect of fully annealing on the fuel failure bahaviour in a reactivity initiated accident (RIA) condition. As-cold worked cladding does not properly simulated the embrittlement of the irradiated one in a RIA condition, because the cladding is fully annealed before the fuel failure even in the short transient. Therefore, the fuel behaviour such as fuel failure threshold energy, failure mechanism, cladding deformation and cladding oxidation of the fully annealed cladding fuel, as well as that of the as-cold worked cladding fuel, are not much different from that of the standard stress-relieved cladding fuel. (author)

  16. LaCrO3/CuFe2O4 Composite-Coated Crofer 22 APU Stainless Steel Interconnect of Solid Oxide Fuel Cells

    Science.gov (United States)

    Hosseini, Seyedeh Narjes; Enayati, Mohammad Hossein; Karimzadeh, Fathallah; Dayaghi, Amir Masoud

    2017-07-01

    Rapidly rising contact resistance and cathode Cr poisoning are the major problems associated with unavoidable chromia scale growth on ferritic stainless steel (FSS) interconnects of solid oxide fuel cells. This work investigates the performance of the novel screen-printed composite coatings consisting of dispersed conductive LaCrO3 particles in a CuFe2O4 spinel matrix for Crofer 22 APU FSS, with emphasis on the oxidation behavior and electrical conductivity of these coatings. The results show that the presence of protective spinel coating, accompanied by the effective role of LaCrO3 particle incorporation, prevents the Cr2O3 subscale growth as well as chromium migration into the coating surface at the end of 400 hours of oxidation at 1073 K (800 °C) in air. In addition, the composite coatings decreased the area specific resistance (ASR) from 51.7 and 13.8 mΩ cm2 for uncoated and spinel-coated samples, respectively, to a maximum of 7.7 mΩ cm2 for composite-coated samples after 400 hours of oxidation.

  17. Ethylene glycol oxidation on Pt and Pt-Ru nanoparticle decorated polythiophene/multiwalled carbon nanotube composites for fuel cell applications

    International Nuclear Information System (INIS)

    Selvaraj, Vaithilingam; Alagar, Muthukaruppan

    2008-01-01

    A novel supporting material containing polythiophene (PTh) and multiwalled carbon nanotubes (MWCNTs) (PTh-CNTs) is prepared by in situ polymerization of thiophene on carbon nanotubes using FeCl 3 as oxidizing agent under sonication. The prepared polythiophene/CNT composites are further decorated with Pt and Pt-Ru nanoparticles by chemical reduction of the corresponding metal salts using HCHO as reducing agent at pH = 11 (Pt/PTh-CNT and Pt-Ru/PTh-CNT). The fabricated composite films decorated with nanoparticles were investigated towards the electrochemical oxidation of ethylene glycol (EG). The presence of carbon nanotubes in conjugation with a conducting polymer produces a good catalytic effect, which might be due to the higher electrochemically accessible surface areas, electronic conductivity and easier charge-transfer at polymer/electrolyte interfaces, which allows higher dispersion of Pt and Pt-Ru nanoparticles. Such nanoparticle modified PTh-CNT electrodes exhibit better catalytic behavior towards ethylene glycol oxidation. Results show that Pt/PTh-CNT and Pt-Ru/PTh-CNT modified electrodes show enhanced electrocatalytic activity and stability towards the electro-oxidation of ethylene glycol than the Pt/PTh electrodes, which shows that the composite film is more promising for applications in fuel cells

  18. One- and two-dimension effects on fuel pin lifetime

    International Nuclear Information System (INIS)

    Stephen, J.D.; Biancheria, A.; Leibnitz, D.; O'Reilly, B.D.; Liu, Y.Y.; Labar, M.P.; Gneiting, B.C.

    1979-01-01

    Lifetime, or breach of the cladding, is a difficult performance limit to establish in fuel pin design. The significant benefits of high plant capacity factor favor conservative design to eliminate downtime or partial power operation caused by the breach limit; however, overly conservative design produces significant penalties. The LIFE system is being applied to help understand the range between operation and breach so that appropriate design margins can be selected. Standards are being developed in the USA to assure the structural integrity of all core components. These standards will provide guidelines to account for the failure mechanisms observed in the high temperature, high fluence core environment. The work to date indicates that creep rupture is the most important failure mechanism for mixed-oxide fuel pins during normal operation and slow power changes. The local cumulative creep rupture damage fraction (CDF) has been adopted as the parameter to assess the approach to failure. Several oxide breached pins and siblings have been studied For example, the P23B-73 pin was an FFTR driver design pin irradiated in EBR-II which failed at 10 at,% burnup. Initial evaluation based on LIFE3 led to the conclusion that the pin should not have failed. Further analyses determined the sensitivity of the breach prediction to the time-to-rupture correlation, cladding temperature, and fuel-fission product swelling (which had not been modeled in LIFE3). The uncertainties in the time-to-rupture correlation have been established. But LIFE is a one-dimensional model. The TWOD code is complete, and development of the best way to couple LIFE and TWOD for lifetime analysis is in progress. Two preliminary conclusions from analysis of representative oxide pin geometries are, first, that the circumferential stress distribution may not peak at the hot spot, but the damage (CDF) does. And second, that the effect of stress concentrations near fuel cracks on cladding creep damage is small

  19. Effects of consumer subsidy on household fuel switching from coal to cleaner fuels: A case study for anthracites in Korea

    International Nuclear Information System (INIS)

    Park, Hojeong; Kwon, Hyucksoo

    2011-01-01

    The Korean coal industry is in a transition under low carbon policy through the steady reduction of coal production. Since consumer subsidy for the consumption of anthracites briquette in low-income households caused a distortion in domestic coal market, the so-called coupon program will be the first target in energy reform policy in order to induce fuel switching from anthracites to alternative clean energy. This paper tries to identify various factors that influence househ