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Sample records for fr18au10r mancozeb pesticide

  1. Mancozeb is an optimum example of diversity of toxicological classification of pesticides in Portugal

    OpenAIRE

    Amaro, Pedro

    2012-01-01

    The Portuguese Pesticide Regulation Authority (AFN) classifies the fungicide MANCOZEB as Harmful (Xn) or Irritant (Xi), ignoring that: in UE, the European Food Safety Authority (EFSA) classify, beyond Xi, as R63 – Possible risk of harm to the unborn child; and, in the USA, the Environmental Protection Agence (EPA) classify as Carcinogenic (Probable human carcinogen). These reality justify that mancozeb is a optimum example, in Portugal, of the strange and frequen...

  2. 78 FR 44444 - Mancozeb; Pesticide Tolerances

    Science.gov (United States)

    2013-07-24

    ... sensitizer, although it does cause mild eye irritation. The findings in multiple studies demonstrate that the... rounded up to the nearest multiple of 5%. Also, for the acute risk assessment for mancozeb and ETU derived... effects were observed in offspring, while thyroid effects and body weight gain decrements occurred in...

  3. Phytotoxicity of pesticides mancozeb and chlorpyrifos: correlation with the antioxidative defence system in Allium cepa.

    Science.gov (United States)

    Fatma, Firdos; Verma, Sonam; Kamal, Aisha; Srivastava, Alka

    2018-02-01

    Pesticides are a group of chemical substances which are widely used to improve agricultural production. However, these substances could be persistent in soil and water, accumulative in sediment or bio-accumulative in biota depending on their solubility, leading to different types of environmental pollution. The present study was done to assess the impact of pesticides-mancozeb and chlorpyrifos, via morphological and physiological parameters using Allium cepa test system. Phytotoxic effects of pesticides were examined via germination percentage, survival percentage, root and shoot length, root shoot length ratio, seedling vigor index, percentage of phytotoxicity and tolerance index. Oxidative stress on Allium seedlings caused by pesticides was also assessed by investigating the activity of antioxidative enzymes viz. catalase, peroxidase and superoxide dismutase. Correlation was worked out between morphological parameters and antioxidative enzymes to bring out the alliance between them. Mancozeb and chlorpyrifos concentrations were significantly and positively correlated with the activity of antioxidative enzymes and negatively correlated with morphological parameters. Significant positive correlation between various morphological parameters showed their interdependency. However, negative correlation was obtained between activity of antioxidative enzymes and morphological parameters. The enzymes however, showed positive correlation with each other. Based on our result we can conclude that all morphological parameters were adversely affected by the two pesticides as reflected by phytotoxicity in Allium . Their negative correlation with activity of antioxidative enzymes indicates that upregulation of antioxidative enzymes is not sufficient to overcome the toxic effect, thereby signifying the threat being caused by the regular use of these pesticides.

  4. Occupational and Environmental Risks from Mancozeb in Aviation ...

    African Journals Online (AJOL)

    Conclusion: Areas of opportunity to improve worker health and the environment include proper and consistent use of protective equipment, re-use of unused product, wastewater reduction and appropriate wastewater treatment. Keywords: Black Sigatoka, Ethylene thiourea, Fumigation, Pesticide, Mancozeb, Airports, ...

  5. 75 FR 4383 - Pesticide Products: Registration Applications

    Science.gov (United States)

    2010-01-27

    ..., Biopesticides and Pollution Prevention Division (7511P), Office of Pesticide Programs, Environmental Protection..., Biopesticides and Pollution Prevention Division, Office of Pesticide Programs. [FR Doc. 2010-1582 Filed 1-26-10...

  6. Occupational and Environmental Risks from Mancozeb in Aviation ...

    African Journals Online (AJOL)

    1Colegio de Postgraduados Campus Tabasco, Periferico Carlos A. Molina S/N Carr. .... Base system [14], the predominant soils correspond to Fluvisols, Gleysols ..... Ficha de datos de seguridad R. D. River Fungicida Rojas. Mancozeb [River ...

  7. Molecular mechanisms underlying mancozeb-induced inhibition of TNF-alpha production

    International Nuclear Information System (INIS)

    Corsini, Emanuela; Viviani, Barbara; Birindelli, Sarah; Gilardi, Federica; Torri, Anna; Codeca, Ilaria; Lucchi, Laura; Bartesaghi, Stefano; Galli, Corrado L.; Marinovich, Marina; Colosio, Claudio

    2006-01-01

    Mancozeb, a polymeric complex of manganese ethylenebisdithiocarbamate with zinc salt, is widely used in agriculture as fungicide. Literature data indicate that ethylenebisdithiocarbamates (EBDTCs) may have immunomodulatory effects in humans. We have recently found in agricultural workers occupationally exposed to the fungicide mancozeb a statistically significant decrease in lipopolysaccharide (LPS)-induced tumor necrosis factor-alpha (TNF) production in leukocytes. TNF is an essential proinflammatory cytokine whose production is normally stimulated during an infection. The purpose of this work was to establish an in vitro model reflecting in vivo data and to characterize the molecular mechanism of action of mancozeb. The human promyelocytic cell line THP-1 was used as in vitro model to study the effects of mancozeb and its main metabolite ethylenthiourea (ETU) on LPS-induced TNF release. Mancozeb, but not ETU, at non-cytotoxic concentrations (1-100 μg/ml), induced a dose- and time-dependent inhibition of LPS-induced TNF release, reflecting in vivo data. The modulatory effect observed was not limited to mancozeb but also other EBDTCs, namely zineb and ziram, showed similar inhibitory effects. Mancozeb must be added before or simultaneously to LPS in order to observe the effect, indicating that it acts on early events triggered by LPS. It is known that nuclear factor-κB (NF-κB) tightly regulates TNF transcription. We could demonstrate that mancozeb, modulating LPS-induced reactive oxygen species generation, prevented IκB degradation and NF-κB nuclear translocation, which in turn resulted in decreased TNF production. To further understand the mechanism of the effect of mancozeb on TNF transcription, THP-1 cells were transfected with NF-κB promoter-luciferase construct, and the effect of mancozeb on luciferase activity was measured. Cells transfected with promoter constructs containing κB site showed decreased LPS-induced luciferase activity relative to control

  8. 76 FR 18906 - Mancozeb; Pesticide Tolerances

    Science.gov (United States)

    2011-04-06

    ..., 32%; cantaloupe, 12.5%; carrot, 2.5%; casaba, 12.5%; cauliflower, 15%; celery, 12%; chickpea, 2.5...%; cauliflower, 5%; celery, 12%; chickpea, 1%; Chinese waxgourd, 5%; chive, 10%; collards, 10%; corn, field, 1...%; cauliflower, 10%; chickpea, 1%; collards, 31%; corn, field, 1%; corn, sweet, 6%; cottonseed, oil, 11...

  9. The fungicide mancozeb induces toxic effects on mammalian granulosa cells

    International Nuclear Information System (INIS)

    Paro, Rita; Tiboni, Gian Mario; Buccione, Roberto; Rossi, Gianna; Cellini, Valerio; Canipari, Rita; Cecconi, Sandra

    2012-01-01

    The ethylene-bis-dithiocarbamate mancozeb is a widely used fungicide with low reported toxicity in mammals. In mice, mancozeb induces embryo apoptosis, affects oocyte meiotic spindle morphology and impairs fertilization rate even when used at very low concentrations. We evaluated the toxic effects of mancozeb on the mouse and human ovarian somatic granulosa cells. We examined parameters such as cell morphology, induction of apoptosis, and p53 expression levels. Mouse granulosa cells exposed to mancozeb underwent a time- and dose-dependent modification of their morphology, and acquired the ability to migrate but not to proliferate. The expression level of p53, in terms of mRNA and protein content, decreased significantly in comparison with unexposed cells, but no change in apoptosis was recorded. Toxic effects could be attributed, at least in part, to the presence of ethylenthiourea (ETU), the main mancozeb catabolite, which was found in culture medium. Human granulosa cells also showed dose-dependent morphological changes and reduced p53 expression levels after exposure to mancozeb. Altogether, these results indicate that mancozeb affects the somatic cells of the mammalian ovarian follicles by inducing a premalignant-like status, and that such damage occurs to the same extent in both mouse and human GC. These results further substantiate the concept that mancozeb should be regarded as a reproductive toxicant. Highlights: ► The fungicide mancozeb affects oocyte spindle morphology and fertilization rate. ► We investigated the toxic effects of mancozeb on mouse and human granulosa cells. ► Granulosa cells modify their morphology and expression level of p53. ► Mancozeb induces a premalignant-like status in exposed cells.

  10. The fungicide mancozeb induces toxic effects on mammalian granulosa cells

    Energy Technology Data Exchange (ETDEWEB)

    Paro, Rita [Department of Health Sciences, University of L' Aquila, Via Vetoio, L' Aquila (Italy); Tiboni, Gian Mario [Department of Medicine and Aging, Section of Reproductive Sciences, University “G. D' Annunzio”, Chieti-Pescara (Italy); Buccione, Roberto [Tumor Cell Invasion Laboratory, Consorzio Mario Negri Sud, Santa Maria Imbaro, Chieti (Italy); Rossi, Gianna; Cellini, Valerio [Department of Health Sciences, University of L' Aquila, Via Vetoio, L' Aquila (Italy); Canipari, Rita [Department of Anatomy, Histology, Forensic Medicine and Orthopedics, Section of Histology and Embryology, School of Pharmacy and Medicine, “Sapienza” University of Rome, Rome (Italy); Cecconi, Sandra, E-mail: sandra.cecconi@cc.univaq.it [Department of Health Sciences, University of L' Aquila, Via Vetoio, L' Aquila (Italy)

    2012-04-15

    The ethylene-bis-dithiocarbamate mancozeb is a widely used fungicide with low reported toxicity in mammals. In mice, mancozeb induces embryo apoptosis, affects oocyte meiotic spindle morphology and impairs fertilization rate even when used at very low concentrations. We evaluated the toxic effects of mancozeb on the mouse and human ovarian somatic granulosa cells. We examined parameters such as cell morphology, induction of apoptosis, and p53 expression levels. Mouse granulosa cells exposed to mancozeb underwent a time- and dose-dependent modification of their morphology, and acquired the ability to migrate but not to proliferate. The expression level of p53, in terms of mRNA and protein content, decreased significantly in comparison with unexposed cells, but no change in apoptosis was recorded. Toxic effects could be attributed, at least in part, to the presence of ethylenthiourea (ETU), the main mancozeb catabolite, which was found in culture medium. Human granulosa cells also showed dose-dependent morphological changes and reduced p53 expression levels after exposure to mancozeb. Altogether, these results indicate that mancozeb affects the somatic cells of the mammalian ovarian follicles by inducing a premalignant-like status, and that such damage occurs to the same extent in both mouse and human GC. These results further substantiate the concept that mancozeb should be regarded as a reproductive toxicant. Highlights: ► The fungicide mancozeb affects oocyte spindle morphology and fertilization rate. ► We investigated the toxic effects of mancozeb on mouse and human granulosa cells. ► Granulosa cells modify their morphology and expression level of p53. ► Mancozeb induces a premalignant-like status in exposed cells.

  11. Silver Nanopartical over AuFON Substrate for Enhanced Raman Readout and Their Application in Pesticide Monitoring

    Directory of Open Access Journals (Sweden)

    Kun Guo

    2015-04-01

    Full Text Available Surface-enhanced Raman detection of thiram is demonstrated by using Ag-nanoparticles (Ag NPs on Au film over nanosphere (AuFON substrate as the hybrid substrate. The SERS signal of the Ag NPs attached to solid supports is studied. The close coupling together of thousands of Ag NPs on AuFON leads to the generation of hot spots for SERS. The Ag NPs on AuFON can be applied to detect rhodamine-6G (R6G with the detection limitation of 10−11 M and the pesticide thiram in acetone with a detection limit of as low as 0.24 ppm, which is much lower than the maximal residue limit (MRL of 7 ppm in fruit prescribed by the U.S. Environmental Protection Agency (EPA. The hybrid substrates are shown to be highly sensitive for the detection of thriam, which produce highly enhanced Raman signals with good uniformity and reproducibility due to having plenty of hot spots on its surface.

  12. Effects of currently used pesticides and their mixtures on the function of thyroid hormone and aryl hydrocarbon receptor in cell culture

    Energy Technology Data Exchange (ETDEWEB)

    Ghisari, Mandana; Long, Manhai; Tabbo, Agnese; Bonefeld-Jørgensen, Eva Cecilie, E-mail: ebj@mil.au.dk

    2015-05-01

    Evidence suggest that exposure to pesticides can interfere with the endocrine system by multiple mechanisms. The endocrine disrupting potential of currently used pesticides in Denmark was analyzed as single compounds and in an equimolar mixture of 5 selected pesticides. The pesticides were previously analyzed for effects on the function of estrogen and androgen receptors, the aromatase enzyme and steroidogenesis in vitro. In this study, the effect on thyroid hormone (TH) function and aryl hydrocarbon receptor (AhR) transactivity was assessed using GH3 cell proliferation assay (T-screen) and AhR responsive luciferase reporter gene bioassay, respectively. Thirteen pesticides were analyzed as follows: 2-methyl-4-chlorophenoxyacetic acid, terbuthylazine, iodosulfuron-methyl-sodium, mesosulfuron-methyl, metsulfuron-methyl, chlormequat chloride, bitertanol, propiconazole, prothioconazole, mancozeb and its metabolite ethylene thiourea, cypermethrin, tau-fluvalinate, and malathion (currently banned in DK). In the T-screen, prothioconazole, malathion, tau-fluvalinate, cypermethrin, terbuthylazine and mancozeb significantly stimulated and bitertanol and propiconazole slightly reduced the GH3 cell proliferation. In the presence of triiodothyronine (T3), prothioconazole, tau-fluvalinate, propiconazole, cypermethrin and bitertanol significantly antagonized the T3-induced GH3 cell proliferation. Eleven of the tested pesticides agonized the AhR function, and bitertanol and prothioconazole inhibited the basal AhR activity. Bitertanol, propiconazole, prothioconazole and cypermethrin antagonized the TCDD-induced AhR transactivation at the highest tested concentration. The 5-component mixture had inducing effect but the combined effect could not be predicted due to the presence of bitertanol eliciting inhibitory effect. Upon removal of bitertanol from the mixture, the remaining four pesticides acted additively. In conclusion, our data suggest that pesticides currently used in Denmark

  13. Determining the Residual Cypermethrin, Permethrin, Indoxacarb and Mancozeb in Tomato Produced in Bushehr Province Farms

    Directory of Open Access Journals (Sweden)

    Maimanat Tobeh Khak

    2016-05-01

    Full Text Available Food is necessary for a healthy lifestyle, but it’s an important way of spreading many pathogens and toxic chemicals. The food contamination may happen during planting, harvesting, storing, processing or transporting. Hence, the food quality monitoring is necessary. Plants constitute the main source of food for human being. Fighting against pests and plant diseases in some cases, prevents product loss. It is obvious that the pest control is crucial for the future agriculture, industry and hygiene. Despite the current discussions and critics in scientific conventions about the adverse effects of pesticide use on human life, chemical based methods of pest control are still the most common among the farmers. Pesticide residues in agricultural products due to inappropriate and excessive consumption of pesticides is a worldwide problem that has overshadowed the health of human societies (1. Bushehr province, according to its weather conditions, is one of the major tomato growers in the country in autumn and winter. In this study, the residues of 9 toxins (Cypermethrin, Permethrin, Indoxacarb And Mancozeb, Chlorothalonil, Iprodione, Thiophanate methyl, Carbendazim Golsam, and Abamectin has been investigated in 37 Tomato samples from the farms of Jam, Dashtestan, Dashti, Deir and kangan cities, and Except Abamectin other toxins were detected. Cypermethrin rate was higher than standard in 2.8% of the samples. The residues of Permethrin, Indoxacarb, Mancozeb, Chlorothalonil, Iprodione and Thiophanate methyl was lower than the allowed limits in all the samples. The amount of Carbendazim was determined to be higher than the allowed limits in 4.8% of the samples.

  14. 75 FR 62323 - Pesticide Management and Disposal; Standards for Pesticide Containers and Containment; Change to...

    Science.gov (United States)

    2010-10-08

    ... Pesticide Management and Disposal; Standards for Pesticide Containers and Containment; Change to Labeling... the pesticide container and containment regulations to provide an 8-month extension of the labeling... titled ``Pesticide Management and Disposal; Standards for Pesticide Containers and Containment'' (71 FR...

  15. Traditions matrimoniales dans la région de Rabat-Salé-Zemmour-Zaer au Maroc

    OpenAIRE

    Hami, H.; Soulaymani, A.; Mokhtari, A.

    2011-01-01

    La pratique des mariages consanguins est très répandue au Moyen-Orient, en Afrique du Nord et dans le Sud-Ouest Asiatique où 20 à plus de 50 % de mariages sont consanguins. L’analyse d’un échantillon de 270 femmes mariées, pris au hasard dans le service de Maternité de l’Hôpital Souissi à Rabat (2004-2005), a fait l’objet d’une étude prospective visant à déterminer la fréquence des mariages consanguins dans la région de Rabat-Salé-Zemmour-Zaer au Maroc. Les résultats obtenus montrent que 20...

  16. Reproduction impact of mancozeb on rainbow trout (Oncorhynchus mykiss W. and accumulation of its carcinogen metabolite, ethylene thiourea in fish products

    Directory of Open Access Journals (Sweden)

    Milena TZANOVA

    2017-06-01

    Full Text Available Pesticides can be taken up from the water and accumulated in tissues of hydrobionts, often becoming multiplied thousands of times higher in the organism than in the surrounding water. The dithiocarbamate mancozeb is applied in plant protection as fungicide. In recent years the amount of mancozeb used in Europe significantly increased. It is carcinogen due to its metabolite - ethylene thiourea (ETU, which causes thyroid and pituitary tumors. The purpose of this study is to determinate the quantity of ethylene thiourea in products of rainbow trout (Oncorhynchus mykiss W., reared in environment containing permissible, according to the European law, amount of mancozeb. Seeking an answer to the question: is this concentration limit really safe for the reproduction of rainbow trout and can the more toxic metabolite - ETU, be accumulated in the fish eggs and fillet and afterwards make them harmful to the consumers? The study included 3 stages: feeding, analysis of ethylene thiourea in fish eggs and fillet by a new developed and validated HPLC (high performance liquid chromatography method and study of the reproductive indicators. The assays of ETU in all analyzed samples (fish and water were below the limit of quantification of the method, 0.05 mg*l-1, so fish do not accumulate the carcinogen degradation product of mancozeb and the maximum residue level of mancozeb is really safe for the humans as consumers. But these environmental conditions caused reproductive disorders. They can be partly compensated by using sperm activation medium for artificial insemination of trout eggs, but successful fertilization does not guarantee successful hatching, especially of eggs in trout farms with presence of mancozeb in water, even in allowable concentration. The presented results confirm previous investigation, that Salmonidae are very sensitive fish species, react to the lowest deviations in concentration levels of xenobiotics and are used for indicator of non

  17. Occupational Exposure to Pesticides With Occupational Sun Exposure Increases the Risk for Cutaneous Melanoma.

    Science.gov (United States)

    Fortes, Cristina; Mastroeni, Simona; Segatto M, Marjorie; Hohmann, Clarissa; Miligi, Lucia; Bakos, Lucio; Bonamigo, Renan

    2016-04-01

    The objective of the study was to examine the association between occupational exposure to pesticides and cutaneous melanoma, controlling for all possible confounders. A pooled analysis of two case-control studies was conducted in two different geographic areas (Italy and Brazil). Detailed pesticides exposure histories were obtained. Ever use of any pesticide was associated with a high risk of cutaneous melanoma (odds ratio 2.58; 95% confidence interval 1.18-5.65) in particular exposure to herbicides (glyphosate) and fungicides (mancozeb, maneb), after controlling for confounding factors. When subjects were exposed to both pesticides and occupational sun exposure, the risk increased even more (odds ratio 4.68; 95% confidence interval 1.29-17.0). The study suggests an augmented risk of cutaneous melanoma among subjects with exposure to pesticides, in particular among those exposed to occupational sun exposure.

  18. HSP90 and pCREB alterations are linked to mancozeb-dependent behavioral and neurodegenerative effects in a marine teleost

    International Nuclear Information System (INIS)

    Zizza, Merylin; Di Lorenzo, Mariana; Laforgia, Vincenza; Furia, Emilia; Sindona, Giovanni; Canonaco, Marcello; Facciolo, Rosa Maria

    2017-01-01

    The pesticide mancozeb (mz) is recognized as a potent inducer of oxidative stress due to its ability to catalyze the production of reactive oxygen species plus inhibiting mitochondrial respiration thus becoming an environmental risk for neurodegenerative diseases. Despite numerous toxicological studies on mz have been directed to mammals, attention on marine fish is still lacking. Thus, it was our intention to evaluate neurobehavioral activities of ornate wrasses (Thalassoma pavo) exposed to 0.2 mg/l of mz after a preliminary screening test (0.07–0.3 mg/l). Treated fish exhibited an evident (p < 0.001) latency to reach T-maze arms (> 1000%) while exploratory attitudes (total arm entries) diminished (− 50%; p < 0.05) versus controls during spontaneous exploration tests. Moreover, they showed evident enhancements (+ 111%) of immobility in the cylinder test. Contextually, strong (− 88%; p < 0.01) reductions of permanence in light zone of the Light/Dark apparatus along with diminished crossings (− 65%) were also detected. Conversely, wrasses displayed evident enhancements (160%) of risk assessment consisting of fast entries in the dark side of this apparatus. From a molecular point of view, a notable activation (p < 0.005) of the brain transcription factor pCREB occurred during mz-exposure. Similarly, in situ hybridization supplied increased HSP90 mRNAs in most brain areas such as the lateral part of the dorsal telencephalon (Dl; + 68%) and valvula of the cerebellum (VCe; + 35%) that also revealed evident argyrophilic signals. Overall, these first indications suggest a possible protective role of the early biomarkers pCREB and HSP90 against fish toxicity. - Highlights: • Fish exposed to mancozeb exhibited an evident latency to reach T-maze arms. • Mancozeb caused immobility and reduction of explorative attitudes. • Fish exposed to mancozeb showed anxiogenic performances in the Light/Dark apparatus. • The brain of fish exposed to mancozeb supplied p

  19. HSP90 and pCREB alterations are linked to mancozeb-dependent behavioral and neurodegenerative effects in a marine teleost

    Energy Technology Data Exchange (ETDEWEB)

    Zizza, Merylin [Comparative Neuroanatomy Laboratory, Biology, Ecology and Earth Science Department (DiBEST), University of Calabria, Arcavacata of Rende, 87036, CS (Italy); Di Lorenzo, Mariana; Laforgia, Vincenza [Department of Biology, Section of Evolutionary and Comparative Biology, University of Naples Federico II, 80134 Naples (Italy); Furia, Emilia; Sindona, Giovanni [Department of Chemistry and Chemical Technologies (DCTC), University of Calabria, Arcavacata of Rende, 87036, CS (Italy); Canonaco, Marcello [Comparative Neuroanatomy Laboratory, Biology, Ecology and Earth Science Department (DiBEST), University of Calabria, Arcavacata of Rende, 87036, CS (Italy); Facciolo, Rosa Maria, E-mail: rm.facciolo@unical.it [Comparative Neuroanatomy Laboratory, Biology, Ecology and Earth Science Department (DiBEST), University of Calabria, Arcavacata of Rende, 87036, CS (Italy)

    2017-05-15

    The pesticide mancozeb (mz) is recognized as a potent inducer of oxidative stress due to its ability to catalyze the production of reactive oxygen species plus inhibiting mitochondrial respiration thus becoming an environmental risk for neurodegenerative diseases. Despite numerous toxicological studies on mz have been directed to mammals, attention on marine fish is still lacking. Thus, it was our intention to evaluate neurobehavioral activities of ornate wrasses (Thalassoma pavo) exposed to 0.2 mg/l of mz after a preliminary screening test (0.07–0.3 mg/l). Treated fish exhibited an evident (p < 0.001) latency to reach T-maze arms (> 1000%) while exploratory attitudes (total arm entries) diminished (− 50%; p < 0.05) versus controls during spontaneous exploration tests. Moreover, they showed evident enhancements (+ 111%) of immobility in the cylinder test. Contextually, strong (− 88%; p < 0.01) reductions of permanence in light zone of the Light/Dark apparatus along with diminished crossings (− 65%) were also detected. Conversely, wrasses displayed evident enhancements (160%) of risk assessment consisting of fast entries in the dark side of this apparatus. From a molecular point of view, a notable activation (p < 0.005) of the brain transcription factor pCREB occurred during mz-exposure. Similarly, in situ hybridization supplied increased HSP90 mRNAs in most brain areas such as the lateral part of the dorsal telencephalon (Dl; + 68%) and valvula of the cerebellum (VCe; + 35%) that also revealed evident argyrophilic signals. Overall, these first indications suggest a possible protective role of the early biomarkers pCREB and HSP90 against fish toxicity. - Highlights: • Fish exposed to mancozeb exhibited an evident latency to reach T-maze arms. • Mancozeb caused immobility and reduction of explorative attitudes. • Fish exposed to mancozeb showed anxiogenic performances in the Light/Dark apparatus. • The brain of fish exposed to mancozeb supplied p

  20. Devenir victime des pesticides:Le recours au droit et ses effets sur la mobilisation des agriculteurs Phyto-victimes

    OpenAIRE

    Jouzel, Jean-Noël; Prete, Giovanni

    2014-01-01

    Cet article analyse les effets du recours au droit sur la mobilisation des travailleurs agricoles victimes des pesticides. Il repose sur une enquête qualitative auprès des membres de l’association Phyto-victimes, qui réunit ces agriculteurs, ainsi que de leurs proches et des professionnels du droit avec lesquels ils interagissent. À partir de ce matériau, nous retraçons les parcours suivis par les agriculteurs pour obtenir une reconnaissance de leur statut de victimes des pesticides. Nous ren...

  1. 75 FR 16111 - Antimicrobial Pesticide Products; Registration Applications

    Science.gov (United States)

    2010-03-31

    ... ENVIRONMENTAL PROTECTION AGENCY [EPA-HQ-OPP-2009-0935; FRL-8807-1] Antimicrobial Pesticide... . List of Subjects Environmental protection, Antimicrobial pesticides and pest. Dated: March 15, 2010. Joan Harrigan Farrelly, Director, Antimicrobial Division, Office of Pesticide Programs. [FR Doc. 2010...

  2. Toxicity interaction between chlorpyrifos, mancozeb and soil moisture to the terrestrial isopod Porcellionides pruinosus.

    Science.gov (United States)

    Morgado, Rui G; Gomes, Pedro A D; Ferreira, Nuno G C; Cardoso, Diogo N; Santos, Miguel J G; Soares, Amadeu M V M; Loureiro, Susana

    2016-02-01

    A main source of uncertainty currently associated with environmental risk assessment of chemicals is the poor understanding of the influence of environmental factors on the toxicity of xenobiotics. Aiming to reduce this uncertainty, here we evaluate the joint-effects of two pesticides (chlorpyrifos and mancozeb) on the terrestrial isopod Porcellionides pruinosus under different soil moisture regimes. A full factorial design, including three treatments of each pesticide and an untreated control, were performed under different soil moisture regimes: 25%, 50%, and 75% WHC. Our results showed that soil moisture had no effects on isopods survival, at the levels assessed in this experiment, neither regarding single pesticides nor mixture treatments. Additivity was always the most parsimonious result when both pesticides were present. Oppositely, both feeding activity and biomass change showed a higher sensitivity to soil moisture, with isopods generally showing worse performance when exposed to pesticides and dry or moist conditions. Most of the significant differences between soil moisture regimes were found in single pesticide treatments, yet different responses to mixtures could still be distinguished depending on the soil moisture assessed. This study shows that while soil moisture has the potential to influence the effects of the pesticide mixture itself, such effects might become less important in a context of complex combinations of stressors, as the major contribution comes from its individual interaction with each pesticide. Finally, the implications of our results are discussed in light of the current state of environmental risk assessment procedures and some future perspectives are advanced. Copyright © 2015 Elsevier Ltd. All rights reserved.

  3. Assessment of pesticide residues on selected vegetables of Pakistan

    International Nuclear Information System (INIS)

    Khan, M.S.; Shah, M.M.

    2011-01-01

    The present study was conducted to determine the pesticide residues on selected summer vegetables. Five vegetables were grown with three replicates in a split plot randomized complete block design. Pesticides were sprayed on vegetables thrice at regular intervals each after 15 days. At maturity the pesticides residues were extracted from edible and leaf portions using anhydrous sodium sulfate and ethyl acetate while adsorption chromatography technique was used for cleanup. The extracts were subjected to high performance liquid chromatography (HPLC) for separation and analysis of the compounds. Significant differences (p<0.05) were found in the pesticides residues on edible portions whereas highly significant differences (p<0.001) were observed for the leafy portions. The residual level of cypermethrin was highest (16.2 mg kg/sup -1/) in edible portion of bitter gourd, while Lambdacyhalothrin and Mancozeb residues were detected high (4.50 mg kg/sup -1/, 6.26 mg kg/sup -1/) in edible portion of bitter gourd and Cucumber respectively. Cypermethrin residues were high (1.86 mg kg/sup -1/) in Okra leaves. Mancozeb and Lambdacyhalothrin residual level was high (1.23 mg kg/sup -1/, and 0.0002 mg kg/sup -1/) in chili and tomato leaves. Cypermethrin residues were readily detected in edible and leaf portion of the selected vegetables. (author)

  4. Pesticide Flow Analysis to Assess Human Exposure in Greenhouse Flower Production in Colombia

    Directory of Open Access Journals (Sweden)

    Claudia R. Binder

    2013-03-01

    Full Text Available Human exposure assessment tools represent a means for understanding human exposure to pesticides in agricultural activities and managing possible health risks. This paper presents a pesticide flow analysis modeling approach developed to assess human exposure to pesticide use in greenhouse flower crops in Colombia, focusing on dermal and inhalation exposure. This approach is based on the material flow analysis methodology. The transfer coefficients were obtained using the whole body dosimetry method for dermal exposure and the button personal inhalable aerosol sampler for inhalation exposure, using the tracer uranine as a pesticide surrogate. The case study was a greenhouse rose farm in the Bogota Plateau in Colombia. The approach was applied to estimate the exposure to pesticides such as mancozeb, carbendazim, propamocarb hydrochloride, fosetyl, carboxin, thiram, dimethomorph and mandipropamide. We found dermal absorption estimations close to the AOEL reference values for the pesticides carbendazim, mancozeb, thiram and mandipropamide during the study period. In addition, high values of dermal exposure were found on the forearms, hands, chest and legs of study participants, indicating weaknesses in the overlapping areas of the personal protective equipment parts. These results show how the material flow analysis methodology can be applied in the field of human exposure for early recognition of the dispersion of pesticides and support the development of measures to improve operational safety during pesticide management. Furthermore, the model makes it possible to identify the status quo of the health risk faced by workers in the study area.

  5. Eco-friendly PEG-based controlled release nano-formulations of Mancozeb: Synthesis and bioefficacy evaluation against phytopathogenic fungi Alternaria solani and Sclerotium rolfsii.

    Science.gov (United States)

    Majumder, Sujan; Shakil, Najam A; Kumar, Jitendra; Banerjee, Tirthankar; Sinha, Parimal; Singh, Braj B; Garg, Parul

    2016-12-01

    Controlled release (CR) nano-formulations of Mancozeb (manganese-zinc double salt of N,N-bisdithiocarbamic acid), a protective fungicide, have been prepared using laboratory-synthesized poly(ethylene glycols) (PEGs)-based functionalized amphiphilic copolymers without using any surfactants or external additives. The release kinetics of the developed Mancozeb CR formulations were studied and compared with that of commercially available 42% suspension concentrate and 75% wettable powder. Maximum amount of Mancozeb was released on 42nd day for PEG-600 and octyl chain, PEG-1000 and octyl chain, and PEG-600 and hexadecyl chain, on 35th day for PEG-1000 and hexadecyl chain, on 28th day for PEG-1500 and octyl chain, PEG-2000 and octyl chain, PEG-1500 and hexadecyl chain, and PEG-2000 and hexadecyl chain in comparison to both commercial formulations (15th day). The diffusion exponent (n value) of Mancozeb in water ranged from 0.42 to 0.62 in tested formulations. The half-release (t 1/2 ) values ranged from 17.35 to 35.14 days, and the period of optimum availability of Mancozeb ranged from 18.54 to 35.42 days. Further, the in vitro bioefficacy evaluation of developed formulations was done against plant pathogenic fungi Alternaria solani and Sclerotium rolfsii by poison food technique. Effective dose for 50% inhibition in mgL -1 (ED 50 ) values of developed formulations varied from 1.31 to 2.79 mg L -1 for A. solani, and 1.60 to 3.14 mg L -1 for S. rolfsii. The present methodology is simple, economical, and eco-friendly for the development of environment-friendly CR formulations of Mancozeb. These formulations can be used to optimize the release of Mancozeb to achieve disease control for the desired period depending upon the matrix of the polymer used. Importantly, the maximum amount of active ingredient remains available for a reasonable period after application. In addition, the developed CR formulations were found to be suitable for fungicidal applications, allowing

  6. TOXICOLOGICAL ASSESSMENT OF EFFECT OF MANCOZEB ...

    African Journals Online (AJOL)

    Osondu

    2013-01-11

    Jan 11, 2013 ... The plasmatic concentration of total protein is not decreased significantly. .... L−1 Fe3+-TPTZ in 40 mmol of HCl; and 2.5 ml of. FeCl3- 6H2O) (300 μl) was .... synthesis in mancozeb-exposed mouse skin. Carcinogenesis, 13 ...

  7. Seletividade de agrotóxicos usados na produção integrada de maçã para adultos de Trichogramma pretiosum Side effects of pesticides used in integrated production of apple in adults of Trichogramma pretiosum

    Directory of Open Access Journals (Sweden)

    Cristiane Gindri Manzoni

    2006-10-01

    Full Text Available O objetivo deste trabalho foi avaliar a seletividade de 12 agrotóxicos usados na produção integrada de maçã, em laboratório (temperatura 25±1ºC, umidade relativa 70±10% e fotófase de 14 horas, tendo-se exposto adultos de Trichogramma pretiosum a resíduos secos dos agrotóxicos, na máxima dosagem recomendada para uso em campo, e tendo-se posteriormente mensurado o número de ovos parasitados por fêmea. Reduções no parasitismo, em relação à testemunha (água, foram utilizadas para classificar os agrotóxicos em inócuo (99%. Foram inócuos os acaricidas Envidor (espirodiclofeno, Kendo 50 SC (fenpiroximato e Ortus 50 SC (fenpiroximato, os fungicidas Antracol 700 PM (propinebe, Midas BR (famoxadona + mancozebe, Palisade (fluquinconazol, Persist SC (mancozebe e Systhane PM (miclobutanil e o inseticida Mimic 240 SC (tebufenozida; o herbicida Polaris (glifosato foi levemente nocivo; os herbicidas Finale (glufosinato sal de amônio e Roundup Original (glifosato foram moderadamente nocivos a T. pretiosum.The objective of this work was to evaluate the side effects of 12 pesticides used in the integrated production of apple, in laboratory (25±1ºC temperature, 70±10% relative humidity and 14 hours photophase, exposing adults of Trichogramma pretiosum to fresh dry pesticide film, in the maximum dosage recommended for field use, with subsequent assessement of the number of eggs parasitized per female. The reduction in the parasitism, compared with the control (water, was used to classify the pesticides as harmless (99%. The acaricides Envidor (spirodiclofen, Kendo 50 SC (fenpyroximate and Ortus 50 SC (fenpyroximate, the fungicides Antracol 700 PM (propineb, Midas BR (famoxadone + mancozeb, Palisade (fluquinconazole, Persist SC (mancozeb and Systhane PM (myclobutanil and the insecticide Mimic 240 SC (tebufenozide were harmless; the herbicide Polaris (glyphosate was slightly harmful; the herbicides Finale (gluphosinate-ammonium and Roundup

  8. A computational approach to mechanistic and predictive toxicology of pesticides

    DEFF Research Database (Denmark)

    Kongsbak, Kristine Grønning; Vinggaard, Anne Marie; Hadrup, Niels

    2014-01-01

    Emerging challenges of managing and interpreting large amounts of complex biological data have given rise to the growing field of computational biology. We investigated the applicability of an integrated systems toxicology approach on five selected pesticides to get an overview of their modes...... of action in humans, to group them according to their modes of action, and to hypothesize on their potential effects on human health. We extracted human proteins associated to prochloraz, tebuconazole, epoxiconazole, procymidone, and mancozeb and enriched each protein set by using a high confidence human......, and procymidone exerted their effects mainly via interference with steroidogenesis and nuclear receptors. Prochloraz was associated to a large number of human diseases, and together with tebuconazole showed several significant associations to Testicular Dysgenesis Syndrome. Mancozeb showed a differential mode...

  9. Currently used pesticides and their mixtures affect the function of sex hormone receptors and aromatase enzyme activity

    Energy Technology Data Exchange (ETDEWEB)

    Kjeldsen, Lisbeth Stigaard; Ghisari, Mandana; Bonefeld-Jørgensen, Eva Cecilie, E-mail: ebj@mil.au.dk

    2013-10-15

    The endocrine-disrupting potential of pesticides is of health concern, since they are found ubiquitously in the environment and in food items. We investigated in vitro effects on estrogen receptor (ER) and androgen receptor (AR) transactivity, and aromatase enzyme activity, of the following pesticides: 2-methyl-4-chlorophenoxyacetic acid (MCPA), terbuthylazine, iodosulfuron-methyl-sodium, mesosulfuron-methyl, metsulfuron-methyl, chlormequat chloride, bitertanol, propiconazole, prothioconazole, mancozeb, cypermethrin, tau fluvalinate, malathion and the metabolite ethylene thiourea (ETU). The pesticides were analyzed alone and in selected mixtures. Effects of the pesticides on ER and AR function were assessed in human breast carcinoma MVLN cells and hamster ovary CHO-K1 cells, respectively, using luciferase reporter gene assays. Effects on aromatase enzyme activity were analyzed in human choriocarcinoma JEG-3 cells, employing the classical [{sup 3}H]{sub 2}O method. Five pesticides (terbuthylazine, propiconazole, prothioconazole, cypermethrin and malathion) weakly induced the ER transactivity, and three pesticides (bitertanol, propiconazole and mancozeb) antagonized the AR activity in a concentration-dependent manner. Three pesticides (terbuthylazine, propiconazole and prothioconazole) weakly induced the aromatase activity. In addition, two mixtures, consisting of three pesticides (bitertanol, propiconazole, cypermethrin) and five pesticides (terbuthylazine, bitertanol, propiconazole, cypermethrin, malathion), respectively, induced the ER transactivity and aromatase activity, and additively antagonized the AR transactivity. In conclusion, our data suggest that currently used pesticides possess endocrine-disrupting potential in vitro which can be mediated via ER, AR and aromatase activities. The observed mixture effects emphasize the importance of considering the combined action of pesticides in order to assure proper estimations of related health effect risks

  10. Immunomodulatory effects of the fungicide Mancozeb in agricultural workers

    International Nuclear Information System (INIS)

    Corsini, Emanuela; Birindelli, Sarah; Fustinoni, Silvia; De Paschale, Gioia; Mammone, Teresa; Visentin, Sara; Galli, Corrado L.; Marinovich, Marina; Colosio, Claudio

    2005-01-01

    Available data suggest that ethylenebisdithiocarbamates (EBDCs) may have immunomodulatory effects. This study aimed to investigate the immunological profile of farmers exposed to Mancozeb, an EBDC fungicide, through the determination of several serum, cellular, and functional immune parameters. Twenty-six healthy subjects entered the study, 13 vineyards exposed to Mancozeb and 13 unexposed controls. Exposure was assessed through the determination of ethylentiourea (ETU) in urine. Complete and differential blood count, serum immunoglobulins, complement fractions, autoantibodies, lymphocyte subpopulations, proliferative response to mitogens, natural killer (NK) activity, and cytokine production were measured. Post-exposure samples showed ETU urine concentration significantly higher than pre-exposure and control groups. A significant increase in CD19+ cells, both percentage and absolute number, and a significant decrease in the percentage of CD25+ cells were found in post-exposure samples compared to controls. A statistically significant increase in the proliferative response to phorbol myristate acetate plus ionomycin (PMA + ionomycin) was observed in the post-exposure group compared to controls and baseline, while a significant reduction in LPS-induced TNF-α release in post-exposure samples was observed. Overall, our results suggest that low-level exposure to Mancozeb has slight immunomodulatory effects, and point out a method adequate to reveal immune-modifications in workers occupationally exposed to potential immunotoxic compounds, based on a whole blood assay

  11. 75 FR 50902 - Mancozeb; Pesticide Tolerances

    Science.gov (United States)

    2010-08-18

    ... . Although listed in the index, some information is not publicly available, e.g., Confidential Business... Potomac Yard (South Bldg.), 2777 S. Crystal Dr., Arlington, VA. The Docket Facility is open from 8:30 a.m... Research Project Number 4 (IR-4), 681 US Highway No. 1 South, North Brunswick, NJ 08902-3390. The petitions...

  12. 75 FR 1773 - Notice of Receipt of a Pesticide Petition Filed for Residues of Polymeric Polyhydroxy Acid in or...

    Science.gov (United States)

    2010-01-13

    ... telephone number is (703) 305-5805. FOR FURTHER INFORMATION CONTACT: Menyon Adams, Biopesticides and..., Biopesticides and Pollution Prevention Division, Office of Pesticide Programs. [FR Doc. 2010-490; Filed 1-12-10...

  13. The Mancozeb-containing carbamate fungicide tattoo induces mild oxidative stress in goldfish brain, liver, and kidney.

    Science.gov (United States)

    Atamaniuk, Tetiana M; Kubrak, Olga I; Husak, Viktor V; Storey, Kenneth B; Lushchak, Volodymyr I

    2014-11-01

    Tattoo belongs to the group of carbamate fungicides and contains Mancozeb (ethylene(bis)dithiocarbamate) as its main constituent. The toxicity of Mancozeb to living organisms, particularly fish, is not resolved. This work investigated the effects of 96 h of exposure to 3, 5, or 10 mg L(-1) of Tattoo (corresponding to 0.9, 1.5, or 3 mg L(-1) of Mancozeb) on the levels of oxidative stress markers and the antioxidant enzyme system of brain, liver, and kidney of goldfish, Carassius auratus). In liver, Tattoo exposure resulted in increased activities of superoxide dismutase (SOD) by 70%-79%, catalase by 23%-52% and glutathione peroxidase (GPx) by 49%. The content of protein carbonyls (CP) in liver was also enhanced by 92%-125% indicating extensive damage to proteins. Similar increases in CP levels (by 98%-111%) accompanied by reduced glucose-6-phosphate dehydrogenase activity (by 13%-15%) was observed in kidney of fish exposed to Tattoo; however, SOD activity increased by 37% in this tissue after treatment with 10 mg L(-1) Tattoo. In brain, a rise in lipid peroxide level (by 29%) took place after exposure to 10 mg L(-1) Tattoo and was accompanied by elevation of high-molecular mass thiols (by 14%). Tattoo exposure also resulted in a concentration-dependent decrease in glutathione reductase activity (by 26%-37%) in brain. The data collectively show that exposure of goldfish to 3-10 mg L(-1) of the carbamate fungicide Tattoo resulted in the development of mild oxidative stress and activation of antioxidant defense systems in goldfish tissues. Copyright © 2013 Wiley Periodicals, Inc., a Wiley company.

  14. Seletividade de agrotóxicos utilizados em pomares de pêssego a adultos do predador Chrysoperla externa (Hagen, 1861 (Neuroptera: Chrysopidae Selectivity of pesticides used in peach orchard on adults of Chrysoperla externa (Hagen, 1861 (Neuroptera: Chrysopidae

    Directory of Open Access Journals (Sweden)

    Rodolfo Vargas Castilhos

    2011-03-01

    Full Text Available A seletividade de dezesseis agrotóxicos utilizados na produção integrada e convencional de pêssego foi avaliada sobre a fase adulta de Chrysoperla externa através de bioensaios de exposição residual conduzidos em laboratório (temperatura de 25±1ºC, umidade relativa 70±10% e fotofase 14 horas, utilizando-se de metodologia prescrita pela "International Organization for Biological Control" (IOBC. Os agrotóxicos (% de ingrediente ativo na calda azoxystrobina (0,016, captana (0,192, dodina (0,126, folpete (0,200, mancozebe (0,256, mancozebe + oxicloreto de cobre (0,140 + 0,096, tebuconazole (0,320, abamectina (0,002, óleo mineral 1 (2,420, óleo mineral 2 (1,920, dicloreto de paraquate (0,300 e glifosato (1,440 foram inócuos; deltametrina (0,002 foi levemente nocivo e dimetoato (0,160, fosmete (0,160 e malationa (0,240 foram nocivos a adultos de C. externa.The selectivity of sixteen pesticides used in integrated and conventional peach production was evaluated on adults of Chrysoperla externa (Hagen,1861 (Neuroptera: Chrysopidae under bioassays in laboratory conditions (temperature of 25±1ºC, relative humidity 70±10% and 14 hours photophase, using the "International Organization for Biological Control" (IOBC methodology. The pesticides (% active ingredient azoxystrobin (0.016, captan (0.192, dodine (0.126, pholpet (0.200, mancozeb (0.256, mancozeb + cooper oxichloride (0.140 + 0.096, tebuconazole (0.320, abamectin (0.002, mineral oil 1 (2.420, mineral oil 2 (1.920, paraquat dichloride (0.300 and gliphosate (1.440 were harmless; deltametrin (0.002 was slightly harmful and dimetoate (0.160, phosmet (0.160 and malathion (0.240, were harmful to C. externa adults.

  15. Non-omnia moriantur-toxicity of mancozeb on dead wood microarthropod fauna.

    Science.gov (United States)

    Adamski, Zbigniew; Bloszyk, Jerzy; Bruin, Jan; Ziemnicki, Kazimierz

    2007-01-01

    The effect of Dithane M-45 (dithiocarbamate fungicide; active substance: mancozeb) was studied on microarthropod fauna inhabiting dead wood. Although the exposure was almost never 100% lethal for the majority of observed taxa, almost all (Mesostigmata, Oribatida, some Uropodina, Actinedida, Collembola and Diplopoda) showed very high correlation between concentration of the fungicide and mortality (r > 0.86). Only Stigmaeidae showed low correlation (r = 0.293). For the majority of taxa LC(50 )values were close to the concentrations used during agrochemical activities in woods. Only Trachytes aegrota showed full susceptibility to the fungicide within the range of recommended field concentrations used in forestry (characterised by the low LC(95 )value). Tolerance of mesostigmatid and oribatid mites was found to differ between juveniles and adults, but not consistently. Related Uropodina species varied in susceptibility to the fungicide.

  16. Pesticides and brain cancer linked in orchard farmers of Kashmir

    OpenAIRE

    Bhat, Abdul Rashid; Wani, Muhammed Afzal; Kirmani, A. R.; Raina, T. H.

    2010-01-01

    Background: The atmosphere of valley of Kashmir is ideal for fresh and dry fruit production. Millions of tons of pesticides, insecticides and fungicides (chemicals like chlorpyriphos, mancozeb, captan, dimethoate, phosalone, etc.) are being used by the orchard farmers to spray the plants, fruits and the leaves every year. The increasing trend in the incidence of primary malignant brain tumors in orchard farmers of Kashmir is alarming. Aim: To determine the relationship between the patients of...

  17. Les séquelles de brûlures cervicales: aspects épidémiologique, clinique et thérapeutique au Maroc

    Science.gov (United States)

    Rafik, Amine; Chabak, Hakim; Diouri, Mounia; Bahechar, Naïma; Chlihi, Abdessamad

    2015-01-01

    Les séquelles de brûlures cervicales représentent une entité fréquente des séquelles de brûlure, elles affectent la fonction, l'esthétique et l’état psychologique des patients et peuvent être de traitement difficile. Il s'agit d'une étude rétrospective étalée sur 5 ans de Mars 2009 au Octobre2014, réalisée au centre national des brûlés et de chirurgie plastique au CHU Ibn Rochd Casablanca. Nous avons analysé les caractéristiques épidémiologiqueset cliniques ainsi que les indications et les résultats thérapeutiques chez 300 patients présentant des rétractions cervicales post-brûlure, suivis dans notre formation. Les jeunes femmes étaient le plus souvent touchées (56%). la brûlure thermique par flamme de butane dans le cadre d'accident domestique était l’étiologie la plus fréquente (91%).75% des patients ont été pris en charge dans un délai de 18 mois après avoir présenté une incapacité fonctionnelle. Les brides cervicales modérées et sévères sont les plus fréquentes et représentent respectivement 60% et 16% des cas. Le traitement chirurgical a fait appel aux greffes cutanées dans 67%des cas, aux plasties locales dans 24%des cas et aux lambeaux dans 24% des cas, les résultats sont jugés bons dans 75%des cas et moyens dans 18% des cas, tandis que les cas restants (7%) ont nécessité une reprise chirurgicale. Le traitement des brides cervicales doit être associé à un programme de rééducation adapté, afin d'assurer la pérennité des résultats fonctionnels et esthétiques. PMID:26301017

  18. Pesticides and brain cancer linked in orchard farmers of Kashmir.

    Science.gov (United States)

    Bhat, Abdul Rashid; Wani, Muhammed Afzal; Kirmani, A R; Raina, T H

    2010-10-01

    The atmosphere of valley of Kashmir is ideal for fresh and dry fruit production. Millions of tons of pesticides, insecticides and fungicides (chemicals like chlorpyriphos, mancozeb, captan, dimethoate, phosalone, etc.) are being used by the orchard farmers to spray the plants, fruits and the leaves every year. The increasing trend in the incidence of primary malignant brain tumors in orchard farmers of Kashmir is alarming. To determine the relationship between the patients of primary malignant brain tumors and their occupation. Retrospectively case files along with death certificates of 432 patients of primary malignant brain tumors and 457 controls (non-tumor neurologic diseases), admitted for treatment simultaneously over a period of 4 years from January 2005 to December 2008, to the Department of Neurosurgery, Sher-I-Kashmir Institute of Medical Sciences (SKIMS), Kashmir, were studied. Follow-up and family contact was established. The serum cholinesterase activity was measured by kinetic/DGKC calorimetric method and ethylenediaminetetraacetic acid (EDTA) samples were sent to the laboratory. The results are expressed in U/l which is U/l×1000. The laboratory at SKIMS, Srinagar, and Dr Lal PathLabs at New Delhi used a reference range for serum cholinesterase as 3167-6333 U/l. Analysis revealed that 90.04% (389 out of 432) patients were orchard-farm workers, orchard residents and orchard playing children exposed to the high levels of multiple types of neurotoxic and carcinogenic (chlorpyriphos, dimethoate, mancozeb and captan) chemicals for more than 10-20 years. About 31.9% (124 out of 389) of these from both sexes were younger than 40 years beginning exposure at an early age and had higher (orchard-related 389 patients had high grade tumors as compared to the non-pesticide tumors. Mortality in pesticide exposed tumors was 12%. Higher levels of SCE were found in 31.9% (124 out of 389) patients and decreased levels in only 45.3% (176 out of 389) orchard

  19. EFFECT OF RINSING SOLUTIONS FOR REMOVING MANCOZEB RESIDUES IN TABLE TOMATOES EFEITO DE SOLUÇÕES DE ENXÁGUE NA REMOÇÃO DE RESÍDUOS DE MANCOZEB EM TOMATES DE MESA

    Directory of Open Access Journals (Sweden)

    Míriam Fontes Araujo Silveira

    2009-12-01

    Full Text Available

    Fungicides are the pesticides most widely used for tomato cultivation, mainly dithiocarbamates. The objective of this research was to study the efficiency of dithiocarbamate mancozeb removal from table tomatoes, through rinsing processes. Analyses of tomato acidity, brix, water activity, pH, and manganese content were carried out. After rinsing tomatoes with drinking water and solutions of vinegar (made from alcohol, sodium bicarbonate, and dihidrated sodium dichloroisocyanurate, mancozeb levels were assessed in skin and whole fruit, by quantifying the manganese content present in the samples. It was observed that the rinsing processes reduced significantly the amount of residues in the tomatoes. The reduction of mancozeb was higher in the skin, where it can be found in its highest concentration. Treatments using drinking water and sodium bicarbonate solution removed over 61% of the residues present in tomatoes skin.

    KEY-WORDS: Fungicides; dithiocarbamates; Lycopersicum esculentum Mill.

    A viable logarithmic f(R) model for inflation

    Energy Technology Data Exchange (ETDEWEB)

    Amin, M.; Khalil, S. [Center for Fundamental Physics, Zewail City of Science and Technology,6 October City, Giza (Egypt); Salah, M. [Center for Fundamental Physics, Zewail City of Science and Technology,6 October City, Giza (Egypt); Department of Mathematics, Faculty of Science, Cairo University,Giza (Egypt)

    2016-08-18

    Inflation in the framework of f(R) modified gravity is revisited. We study the conditions that f(R) should satisfy in order to lead to a viable inflationary model in the original form and in the Einstein frame. Based on these criteria we propose a new logarithmic model as a potential candidate for f(R) theories aiming to describe inflation consistent with observations from Planck satellite (2015). The model predicts scalar spectral index 0.9615r of order 10{sup −3}. Furthermore, we show that for a class of models, a natural coupling between inflation and a scalar boson is generated through the minimal coupling between gravity and matter fields and a reheating temperature less that 10{sup 9} GeV is obtained.

  1. Pesticides in Wyoming Groundwater, 2008-10

    Science.gov (United States)

    Eddy-Miller, Cheryl A.; Bartos, Timothy T.; Taylor, Michelle L.

    2013-01-01

    Groundwater samples were collected from 296 wells during 1995-2006 as part of a baseline study of pesticides in Wyoming groundwater. In 2009, a previous report summarized the results of the baseline sampling and the statistical evaluation of the occurrence of pesticides in relation to selected natural and anthropogenic (human-related) characteristics. During 2008-10, the U.S. Geological Survey, in cooperation with the Wyoming Department of Agriculture, resampled a subset (52) of the 296 wells sampled during 1995-2006 baseline study in order to compare detected compounds and respective concentrations between the two sampling periods and to evaluate the detections of new compounds. The 52 wells were distributed similarly to sites used in the 1995-2006 baseline study with respect to geographic area and land use within the geographic area of interest. Because of the use of different types of reporting levels and variability in reporting-level values during both the 1995-2006 baseline study and the 2008-10 resampling study, analytical results received from the laboratory were recensored. Two levels of recensoring were used to compare pesticides—a compound-specific assessment level (CSAL) that differed by compound and a common assessment level (CAL) of 0.07 microgram per liter. The recensoring techniques and values used for both studies, with the exception of the pesticide 2,4-D methyl ester, were the same. Twenty-eight different pesticides were detected in samples from the 52 wells during the 2008-10 resampling study. Pesticide concentrations were compared with several U.S. Environmental Protection Agency drinking-water standards or health advisories for finished (treated) water established under the Safe Drinking Water Act. All detected pesticides were measured at concentrations smaller than U.S. Environmental Protection Agency drinking-water standards or health advisories where applicable (many pesticides did not have standards or advisories). One or more pesticides

  2. Adverse effects on sexual development in rat offspring after low dose exposure to a mixture of endocrine disrupting pesticides

    DEFF Research Database (Denmark)

    Hass, Ulla; Boberg, Julie; Christiansen, Sofie

    2012-01-01

    The present study investigated whether a mixture of low doses of five environmentally relevant endocrine disrupting pesticides, epoxiconazole, mancozeb, prochloraz, tebuconazole and procymidone, would cause adverse developmental toxicity effects in rats. In rat dams, a significant increase...... and cumulative intake, because of the potentially serious impact of mixed exposure on development and reproduction in humans....

  3. Effets des pesticides à faibles doses sur le système nerveux et la reproduction chez l'abeille

    OpenAIRE

    Belzunces, Luc; Collet, Claude; Brunet, Jean-Luc

    2016-01-01

    Au cours de leur activité de butinage, les abeilles sont soumises au contact de nombreux polluants dont les produits phytopharmaceutiques ou pesticides. Les pesticides peuvent induire des effets létaux ou des effets sublétaux délétères qui compromettent la survie des colonies d’abeilles. La caractérisation des effets des pesticides peut s’effectuer a priori, c’est à dire dans un cadre règlementaire avant homologation du produits phytopharmaceutique, soit a posteriori, c’est dire dans le cadre...

  4. Affections cutaneo-muqueuses au cours de l'Infection a VIH /SIDA ...

    African Journals Online (AJOL)

    Les affections dermatologiques sont fréquentes au cours de l'infection par le virus de l'Immunodéficience Humaine (VIH). Nous avons réalisé une étude prospective de janvier à décembre 2003 au service de l'hôpital du jour de Hôpital Central de Yaoundé, afin de répertorier les affections cutanes et muqueuses associées ...

  5. Mode of carcinogenic action of pesticides inducing thyroid follicular cell tumors in rodents.

    Science.gov (United States)

    Hurley, P M

    1998-08-01

    Of 240 pesticides screened for carcinogenicity by the U.S. Environmental Protection Agency Office of Pesticide Programs, at least 24 (10%) produce thyroid follicular cell tumors in rodents. Thirteen of the thyroid carcinogens also induce liver tumors, mainly in mice, and 9 chemicals produce tumors at other sites. Some mutagenic data are available on all 24 pesticides producing thyroid tumors. Mutagenicity does not seem to be a major determinant in thyroid carcinogenicity, except for possibly acetochlor; evidence is less convincing for ethylene thiourea and etridiazole. Studies on thyroid-pituitary functioning, including indications of thyroid cell growth and/or changes in thyroxine, triiodothyronine, or thyroid-stimulating hormone levels, are available on 19 pesticides. No such antithyroid information is available for etridiazole, N-octyl bicycloheptene dicarboximide, terbutryn, triadimefon, and trifluralin. Of the studied chemicals, only bromacil lacks antithyroid activity under study conditions. Intrathyroidal and extrathyroidal sites of action are found: amitrole, ethylene thiourea, and mancozeb are thyroid peroxidase inhibitors; and acetochlor, clofentezine, fenbuconazole, fipronil, pendimethalin, pentachloronitrobenzene, prodiamine, pyrimethanil, and thiazopyr seem to enhance the hepatic metabolism and excretion of thyroid hormone. Thus, with 12 pesticides that mode of action judgments can be made, 11 disrupt thyroid-pituitary homeostasis only; no chemical is mutagenic only; and acetochlor may have both antithyroid and some mutagenic activity. More information is needed to identify other potential antithyroid modes of thyroid carcinogenic action.

  6. Seletividade de produtos fitossanitários utilizados na cultura do pessegueiro a Trichogramma pretiosum Riley, 1879 (Hymenoptera: Trichogrammatidae Selectivity of pesticides used in peach orchard to Trichogramma pretiosum Riley, 1879 (Hymenoptera: Trichogrammatidae

    Directory of Open Access Journals (Sweden)

    Fabrizio Pinheiro Giolo

    2007-10-01

    Full Text Available A seletividade de dez formulações comerciais de produtos fitossanitários utilizados na cultura do pessegueiro foi avaliada em laboratório (25±1 ºC, UR 70±10% e fotofase de 14 horas, através da exposição de adultos de Trichogramma pretiosum Riley a resíduos secos dos produtos pulverizados sobre placas de vidro. O número de ovos parasitados por fêmea, foi mensurado e a redução no parasitismo (RP, em relação à testemunha (água, foi utilizada para classificar os compostos em: inócuos (99% RP. Os produtos fitossanitários captana, ditianona, mancozebe, metoxifenozida e óxido cuproso foram inócuos; glifosato e óleo mineral foram levemente nocivos e abamectina, cianamida e etofenproxi foram nocivos a T. pretiosum.The selectivity of ten commercial pesticide formulations used in peach orchard was evaluated in laboratory tests (25±1 ºC, RH 70±10% and 14 hours photophase by exposing the adult of Trichogramma pretiosum Riley to fresh dry pesticide film applied on glass plates. The number of eggs parasitized per adult female and the reduction in parasitism (RP compared to control (treated with water were used to measure the effect of the chemical in harmless (99% RP. The pesticides captan, copper oxide, dithianon, mancozeb and methoxyfenozide were harmless; gliphosate and mineral oil was slightly harmful and abamectin, cyanamide and etofenprox were harmful to T. pretiosum.

  7. Future dynamics in f(R) theories

    International Nuclear Information System (INIS)

    Mueller, D.; Andrade, V.C. de; Maia, C.; Reboucas, M.J.; Teixeira, A.F.F.

    2015-01-01

    The f(R) gravity theories provide an alternative way to explain the current cosmic acceleration without invoking a dark energy matter component used in the cosmological modeling in the framework of general relativity. However, the freedom in the choice of the functional forms of f(R) gives rise to the problem of the degeneracy among these gravity theories on theoretical and (or) observational grounds. In this paper we examine the question as to whether the future dynamics can be used to break the degeneracy between f(R) gravity theories by investigating the dynamics of spatially homogeneous and isotropic dust flat models in two f(R) gravity theories, namely the well known f(R) = R+αR n gravity and another byAviles et al., whose motivation comes from the cosmographic approach to f(R) gravity. We perform a detailed numerical study of the dynamics of these theories taking into account the recent constraints on the cosmological parameters made by the Planck Collaboration. We demonstrate that besides being useful for discriminating between these two f(R) gravity theories, the future dynamics technique can also be used to determine the finite-time behavior as well as the fate of the Universe in the framework of these f(R) gravity theories. There also emerges from our analysis the result that one still can have a dust flat FLRWsolution with a big rip, if gravity is governed by f(R) = R+αR n . We also show that FLRW dust solutions with f'' < 0 do not necessarily lead to singularities. (orig.)

  8. Brain cancer and pesticide relationship in orchard farmers of Kashmir.

    Science.gov (United States)

    Bhat, Abdul Rashid; Wani, Muhammed Afzal; Kirmani, A R

    2010-09-01

    The increasing trend in the incidence of primary malignant brain tumors in orchard farmers and their families in Kashmir. To determine the relationship between the patients of primary malignant brain tumors and their occupation. Retrospectively, case files along with death certificates of 432 patients of primary malignant brain tumors and 457 controls (non-tumor neurologic diseases), admitted for treatment simultaneously over a period of 4 years from January 2005 to December 2008, to the Neurosurgery, Sher-i-Kashmir Institute of Medical Sciences (SKIMS), Kashmir, were studied. Follow-up and family interaction was established. Analysis revealed that 90.04% (389 out of 432) patients were orchard farm workers, orchard residents and orchard playing children exposed to the high levels of multiple types of neurotoxic and carcinogenic (chlorpyriphos, dimethoate, mancozeb and captan) chemicals for more than 10 years [relative risk (RR) = 10.6; odds ratio (OR) = >10; 95% confidence interval (CI) = >25-40]. The 9.96% (43 out of 432) patients were not exposed to pesticides. On the other hand, only 19 patients out of 457 controls had recorded history of pesticide exposure and 438 were unrelated to pesticides. Out of 389 patients, 71.7% (279 out of 389) were males and 28.3% (110 out of 389), including six members of three families, were females (one male child). All orchard-related 389 patients had high-grade tumors as compared to the non-pesticide tumors. Mortality in pesticide-exposed tumors was 12%. The higher or upper-normal levels of serum cholinesterase (AChE) were observed in 54.7% (213 out of 389) patients and decreased levels were found in only 45.3% (176 out of 389) orchard-related patients (RR = 19.4; OR = >5; 95% CI = >1-10). Although serum AChE levels were a routine investigation in malignant brain tumors, this was not a routine in other neurological conditions (hospitalized controls). The familial gliomas have shown an emerging trend in the orchard residents of

  9. Soil fungi as indicators of pesticide soil pollution

    Directory of Open Access Journals (Sweden)

    Mandić Leka

    2005-01-01

    Full Text Available Soil fungi, with their pronounced enzymic activity and high osmotic potential, represent a significant indicator of negative effects of different pesticides on the agroecosystem as a whole. In that respect, a trial was set up on the alluvium soil type with the aim to investigate the effect of different herbicides (Simazine, Napropamid, Paraquat, fungicides (Captan and Mancozeb and insecticides (Fenitrothion and Dimethoate on a number of soil fungi under apple trees. The number of soil fungi was determined during four growing seasons by an indirect method of dilution addition on the Czapek agar. The study results indicate that the fungi belong to the group of microorganisms that, after an initial sensible response to the presence of pesticides in the soil, very rapidly establish normal metabolism enabling them even to increase their number. The fungicides and insecticides applied were found to be particularly effective in that respect.

  10. Thermodynamic laws for generalized f(R) gravity with curvature-matter coupling

    International Nuclear Information System (INIS)

    Wu Yabo; Zhao Yueyue; Cai Ronggen; Lu Jianbo; Lu Junwang; Gao Xiaojing

    2012-01-01

    The first law and the generalized second law (GSL) of thermodynamics for the generalized f(R) gravity with curvature-matter coupling are studied in the spatially homogeneous, isotropic FRW universe. The research results show that the field equations of the generalized f(R) gravity with curvature-matter coupling can be cast to the form of the first law of thermodynamics with the so-called the entropy production terms dS ¯ and the GSL can be given by considering the FRW universe filled only with ordinary matter enclosed by the dynamical apparent horizon with the Hawking temperature. Furthermore, as a concrete example, by utilizing the GSL the constraints on the gravitational model with f 1 (R)=R+αR l and f 2 (R)=R m are also discussed. It is worth noting these results given by us are quite general and can degenerate to the ones in Einstein's general relativity and pure f(R) gravity with non-coupling and non-minimal coupling as special cases. Comparing with the case of Einstein's general relativity, the appearance of the entropy production term dS ¯ in the first law of thermodynamics demonstrates that the horizon thermodynamics is non-equilibrium one for generalized f(R) gravity with curvature-matter coupling, which is consistent with the arguments given in Akbar and Cai (2007) [13] and Eling et al. (2006) [18].

  11. Production of Trichoderma strains with pesticide-polyresistance by mutagenesis and protoplast fusion.

    Science.gov (United States)

    Hatvani, Lóránt; Manczinger, László; Kredics, László; Szekeres, András; Antal, Zsuzsanna; Vágvölgyi, Csaba

    2006-01-01

    The sensitivity of two cold-tolerant Trichoderma strains belonging to the species T. harzianum and T. atroviride was determined to a series of pesticides widely used in agriculture. From the 16 pesticides tested, seven fungicides: copper sulfate, carbendazim, mancozeb, tebuconazole, imazalil, captan and thiram inhibited colony growth of the test strains significantly with minimal inhibitory concentrations of 300, 0.4, 50, 100, 100, 100 and 50 microg/ml, respectively. Mutants resistant to carbendazim and tebuconazole were produced from both wild type strains by means of UV-mutagenesis. The cross-resistance capabilities and in vitro antagonistic properties of the mutants were determined. Carbendazim-resistant mutants showed total cross-resistance to benomyl and thiabendazole at a concentration of 20 microg/ml. Intraspecific protoplast fusion was carried out between carbendazim- and tebuconazole-resistant mutants of both parental strains, and putative haploid recombinants with stable resistance to both pesticides were produced in the case of T. atroviride. These pesticide-polyresistant progenies are potential candidates for application in an integrated pest management system.

  12. 40 CFR 152.10 - Products that are not pesticides because they are not intended for a pesticidal purpose.

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 23 2010-07-01 2010-07-01 false Products that are not pesticides because they are not intended for a pesticidal purpose. 152.10 Section 152.10 Protection of Environment... pesticidal purpose. A product that is not intended to prevent, destroy, repel, or mitigate a pest, or to...

  13. f(R) gravity solutions for evolving wormholes

    Energy Technology Data Exchange (ETDEWEB)

    Bhattacharya, Subhra [Presidency University, Department of Mathematics, Kolkata (India); Chakraborty, Subenoy [Jadavpur University, Department of Mathematics, Kolkata (India)

    2017-08-15

    The scalar-tensor f(R) theory of gravity is considered in the framework of a simple inhomogeneous space-time model. In this research we use the reconstruction technique to look for possible evolving wormhole solutions within viable f(R) gravity formalism. These f(R) models are then constrained so that they are consistent with existing experimental data. Energy conditions related to the matter threading the wormhole are analyzed graphically and are in general found to obey the null energy conditions (NEC) in regions around the throat, while in the limit f(R) = R, NEC can be violated at large in regions around the throat. (orig.)

  14. Toxicity of chlorpyrifos, carbofuran, mancozeb and their formulations to the tropical earthworm Perionyx excavatus.

    NARCIS (Netherlands)

    De Silva, P.M.C.S.; Pathiratne, A.; van Gestel, C.A.M.

    2010-01-01

    Effects of chlorpyrifos, carbofuran, mancozeb and their formulated products on survival, growth and reproduction of the tropical earthworm Perionyx excavatus were investigated in standard artificial soil. The toxicity of the three chemicals decreased in the order carbofuran > chlorpyrifos >

  15. Antimicrobial photodynamic activity and cytocompatibility of Au25(Capt18 clusters photoexcited by blue LED light irradiation

    Directory of Open Access Journals (Sweden)

    Miyata S

    2017-04-01

    Full Text Available Saori Miyata,1 Hirofumi Miyaji,1 Hideya Kawasaki,2 Masaki Yamamoto,2 Erika Nishida,1 Hiroko Takita,3 Tsukasa Akasaka,4 Natsumi Ushijima,3 Toshihiko Iwanaga,5 Tsutomu Sugaya1 1Department of Periodontology and Endodontology, Hokkaido University Graduate School of Dental Medicine, Kita-ku, Sapporo, 2Department of Chemistry and Materials Engineering, Faculty of Chemistry, Materials and Bioengineering, Kansai University, Suita-shi, Osaka, 3Support Section for Education and Research, Hokkaido University Graduate School of Dental Medicine, 4Department of Biomedical, Dental Materials and Engineering, Graduate School of Dental Medicine, Hokkaido University, 5Department of Anatomy, Laboratory of Histology and Cytology, Hokkaido University Graduate School of Medicine, Kita-ku, Sapporo, Japan Abstract: Antimicrobial photodynamic therapy (aPDT has beneficial effects in dental treatment. We applied captopril-protected gold (Au25(Capt18 clusters as a novel photosensitizer for aPDT. Photoexcited Au clusters under light irradiation generated singlet oxygen (1O2. Accordingly, the antimicrobial and cytotoxic effects of Au25(Capt18 clusters under dental blue light-emitting diode (LED irradiation were evaluated. 1O2 generation of Au25(Capt18 clusters under blue LED irradiation (420–460 nm was detected by a methotrexate (MTX probe. The antimicrobial effects of photoexcited Au clusters (0, 5, 50, and 500 µg/mL on oral bacterial cells, such as Streptococcus mutans, Aggregatibacter actinomycetemcomitans, and Porphyromonas gingivalis, were assessed by morphological observations and bacterial growth experiments. Cytotoxicity testing of Au clusters and blue LED irradiation was then performed against NIH3T3 and MC3T3-E1 cells. In addition, the biological performance of Au clusters (500 µg/mL was compared to an organic dye photosensitizer, methylene blue (MB; 10 and 100 µg/mL. We confirmed the 1O2 generation ability of Au25(Capt18 clusters through the fluorescence

  16. Repeated dose 28-day oral toxicity study in Wistar rats with a mixture of five pesticides often found as residues in food: alphacypermethrin, bromopropylate, carbendazim, chlorpyrifos and mancozeb

    DEFF Research Database (Denmark)

    Jacobsen, H.; Østergaard, G.; Lam, Henrik Rye

    2004-01-01

    Six dose groups of 8 male and female rats respectively received a daily dose equivalent to 0, 0.15, 0.006, 0.03, 0.15 or 0.3 mg/kg b.w./day chlorpyrifos (groups 1-6) and the last four dose groups (groups 3-6) received in addition daily doses equivalent to 18 mg/kg b.w./day alphacypermethrin, 30 mg...... of acetylcholinesterase activity in plasma and brain by chlorpyrifos was not enhanced by coadministration of the other four pesticides. Effects were seen in liver, thyroid, thymus and blood in the combination groups. However, identification of the pesticide(s) responsible for these changes would require further studies...

  17. 76 FR 17644 - Pesticide Product; Registration Application

    Science.gov (United States)

    2011-03-30

    ... telephone number is (703) 305-5805. FOR FURTHER INFORMATION CONTACT: Gina Casciano, Biopesticides and... Environmental protection, Pesticides and pest. Dated: March 18, 2011. Keith A. Matthews, Director, Biopesticides...

  18. Douleurs induites par les soins: la réalité au Centre Hospitalier Universitaire de Befelatanana Antananarivo, Madagascar

    Science.gov (United States)

    Mahavivola, Ernestho-Ghoud Indretsy; Olivah, Razanaparany Miarisoa Mireille; Mihary, Dodo; Hendriniaina, Rakotoharivelo; Lalao, Randriamboavonjy Rado; Henintsoa, Rakotonirainy Oliva; Fahafahantsoa, Rapelanoro Rabenja

    2014-01-01

    La douleur induite par les soins correspond à la douleur survenant lors des actes à visé diagnostique et/ou thérapeutique. A notre connaissance, nous n'avons pas encore des données disponibles pour les douleurs induites par les soins à l'Hôpital de Befelatanana. Nos objectifs étaient de décrire le profil épidémiologique de la douleur induite par les soins, d'identifier les principaux facteurs influençant sur l'intensité de la douleur et leurs retentissements chez les patients. Il s'agissait d'une étude rétrospective, transversale type un jour donné menée dans les douze services de Médecines au Centre Hospitalier Universitaire de Befelatanana en Novembre 2013. Cent deux patients ont été retenus dans l’étude et trois cent vingt trois actes douloureux étaient enregistrés. La fréquence de la douleur induite par les soins était de 69,86%. Le genre féminin prédominait dans 52% des cas (n = 53) avec un sex-ratio à 0,92. L’âge moyen était de 46 ans. Les ponctions vasculaires étaient l'acte prédominant dans 49,54% (n = 109) des cas. Les infirmiers réalisaient les soins dans 47,05% (n = 48) des cas. L'information verbale était la mesure préventive utilisée dans 57,84% des cas (n = 59). Le transport par marche à pied et au dos représentait 16,67% des cas (n = 17). Les patients naïfs des gestes étaient plus anxieux. Ces patients gardaient de mauvais souvenir dans 64,71% des cas (n = 66). La fréquence de douleur induite par les soins était trop élevée. Un effort important est nécessaire pour réduire la douleur induite par les soins PMID:25932071

  19. Les déterminants du statut “perdu de vue” chez les patients pris en charge pour cancer au Maroc: situation avant le Plan Cancer

    Science.gov (United States)

    Najdi, Adil; Berraho, Mohamed; Bendahhou, Karima; Obtel, Majdouline; Zidouh, Ahmed; Errihani, Hassan; Nejjari, Chakib

    2014-01-01

    Introduction Le cancer au Maroc représente un problème majeur de santé publique, sa prise en charge doit être globale, active et complète pour tous les patients. L'objectif de ce travail était d'estimer la fréquence des perdus de vue « PDV » en oncologie au Maroc durant la première année de suivi et de déterminer les facteurs associés à ce problème. Méthodes Par une étude rétrospective portant sur 2854 dossiers de malades hospitalisés dans les trois principaux centres d'oncologie au Maroc depuis janvier 2003 jusqu’à juin 2007 et concernant les cinq principales localisations de cancer au Maroc, nous avons cherché la date des dernières nouvelles des patients ayant un recul de 18 mois minimum afin de déterminer le statut de ces malades après un an de suivi. Résultats La moyenne d’âge était de 52±14 ans, une proportion féminine de 63%, les sujets actifs constituaient 28%, les mariés 71%, les analphabètes 51%, 70% des patients habitaient en milieu urbain et seulement 11% des malades disposaient d'une couverture sociale. La localisation cancéreuse la plus fréquente était le poumon (23,8%) suivie du colon-rectum (23,5%) puis le col (21,9%), le sein (20,4%) et les lymphomes (10,4%). Le taux des «PDV» à un an de suivi était de 48%, ce statut était significativement lié au sexe, à l’âge, au NSE et au statut matrimonial. Sur le plan médical, le statut «PDV» était lié à la localisation du cancer, au stade de diagnostic et au type de traitement reçu. Conclusion Notre étude a mis en évidence la grande ampleur du problème des PDV en cancérologie au Maroc ainsi que ces déterminants. Ces résultats incitent tous les acteurs dans le domaine de la cancérologie à collaborer ensemble pour prendre les mesures qui s'imposent pour y pallier PMID:25400850

  20. Exploring plane-symmetric solutions in f(R) gravity

    Energy Technology Data Exchange (ETDEWEB)

    Shamir, M. F., E-mail: farasat.shamir@nu.edu.pk [National University of Computer and Emerging Sciences, Department of Sciences and Humanities (Pakistan)

    2016-02-15

    The modified theories of gravity, especially the f(R) gravity, have attracted much attention in the last decade. This paper is devoted to exploring plane-symmetric solutions in the context of metric f(R) gravity. We extend the work on static plane-symmetric vacuum solutions in f(R) gravity already available in the literature [1, 2]. The modified field equations are solved using the assumptions of both constant and nonconstant scalar curvature. Some well-known solutions are recovered with power-law and logarithmic forms of f(R) models.

  1. Occupational exposure to pesticides and occurrence of the chromosomal translocation t(14;18 among farmers in Jordan

    Directory of Open Access Journals (Sweden)

    Bara’a M. Qaqish

    Full Text Available Background: An increased incidence of non-Hodgkin’s lymphoma (NHL has been reported in farmers and other occupational groups working with pesticides. In these individuals, an increased prevalence of the chromosomal translocation t(14;18(q32;q21, one of the most common chromosomal abnormalities in NHL, has been detected in peripheral blood lymphocytes. This translocation juxtaposes the antiapoptotic BCL2 protein to the immunoglobulin heavy chain gene locus (IGH leading to overexpression of BCL2. This causes an increase in cell survival, paving the way for malignant transformation. Aim of the study: The present study aimed to evaluate the association between the occurrence of the chromosomal translocation t(14;18 and occupational exposure to pesticides among a group of Jordanian farmers. Methods: A total of 192 male subjects including 96 agricultural workers and 96 control subjects participated in this study. BCL2-IGH t(14;18 fusions were detected by a nested polymerase chain reaction (PCR assay targeting the major breakpoint region (MBR. Results: We found that occupational exposure to pesticides in open-field farming and insecticide used on animals increased the frequency of the chromosomal translocation t(14;18. Farmers occupationally exposed to pesticides and insecticide were 13.5 times more likely to harbor t(14;18. 63.5% (61 of 96 of farmers compared to 11.5% (11 of 96 of controls carried the translocation (odds ratio: 13.5; 95% confidence interval (CI = 6.3–28.6. We ruled out the influence of possible confounding factors such as age, duration of sun exposure, alcohol intake, smoking, and use of personal protective equipment. Conclusion: Our results indicate that pesticides increased the frequency of chromosomal translocation in the 14q32 region. Accordingly, the presented data agrees with previous suggestions from the literature that pesticides might be involved in the development of NHL through the t(14;18 pathway. Keywords

  2. Templated Atom-Precise Galvanic Synthesis and Structure Elucidation of a [Ag 24 Au(SR) 18 ] − Nanocluster

    KAUST Repository

    Bootharaju, Megalamane Siddaramappa

    2015-11-27

    Synthesis of atom-precise alloy nanoclusters with uniform composition is challenging when the alloying atoms are similar in size (for example, Ag and Au). A galvanic exchange strategy has been devised to produce a compositionally uniform [Ag24Au(SR)18]- cluster (SR: thiolate) using a pure [Ag25(SR)18]- cluster as a template. Conversely, the direct synthesis of Ag24Au cluster leads to a mixture of [Ag25-xAux(SR)18]-, x=1-8. Mass spectrometry and crystallography of [Ag24Au(SR)18]- reveal the presence of the Au heteroatom at the Ag25 center, forming Ag24Au. The successful exchange of the central Ag of Ag25 with Au causes perturbations in the Ag25 crystal structure, which are reflected in the absorption, luminescence, and ambient stability of the particle. These properties are compared with those of Ag25 and Ag24Pd clusters with same ligand and structural framework, providing new insights into the modulation of cluster properties with dopants at the single-atom level.

  3. 75 FR 807 - Pesticide Tolerance Crop Grouping Program II; Revision to General Tolerance Regulations

    Science.gov (United States)

    2010-01-06

    .... pubescens Ruiz & Pav., Capsicum spp.; (12) Roselle, Hibiscus sabdariffa L.; (13) Scarlet eggplant, Solanum..., specialty crop producers, pesticide registrants, the environment, or human health. No crop group tolerance... Environmental Health Risks and Safety Risks (62 FR 19885, April 23, 1997) does not apply to this proposed rule...

  4. Validation of a GC-MS method for the estimation of dithiocarbamate fungicide residues and safety evaluation of mancozeb in fruits and vegetables.

    Science.gov (United States)

    Mujawar, Sumaiyya; Utture, Sagar C; Fonseca, Eddie; Matarrita, Jessie; Banerjee, Kaushik

    2014-05-01

    A sensitive and rugged residue analysis method was validated for the estimation of dithiocarbamate fungicides in a variety of fruit and vegetable matrices. The sample preparation method involved reaction of dithiocarbamates with Tin(II) chloride in aqueous HCl. The CS2 produced was absorbed into an isooctane layer and estimated by GC-MS selected ion monitoring. Limit of quantification (LOQ) was ⩽40μgkg(-1) for grape, green chilli, tomato, potato, brinjal, pineapple and chayote and the recoveries were within 75-104% (RSD<15% at LOQ). The method could be satisfactorily applied for analysis of real world samples. Dissipation of mancozeb, the most-used dithiocarbamate fungicide, in field followed first+first order kinetics with pre-harvest intervals of 2 and 4days in brinjal, 7 and 10days in grapes and 0day in chilli at single and double dose of agricultural applications. Cooking practices were effective for removal of mancozeb residues from vegetables. Copyright © 2013 Elsevier Ltd. All rights reserved.

  5. Earthworms lost from pesticides application in potato crops

    Science.gov (United States)

    Garcia-Santos, Glenda; Forrer, Karin; Binder, Claudia R.

    2010-05-01

    Bioturbation from earthworm's activity contributes to soil creep and soil carbon dynamics, and provide enough aeration conditions for agricultural practices all over the world. In developing countries where there is a long term misuse of pesticides for agricultural purposes, lost of these benefits from earthworms activity might already yielded negative effects in the current crop production. Little research has been performed on earthworms avoidance to pesticides in developing countries located in the tropics. Furthermore, the complete avoidance reaction (from attraction to 100% avoidance) from earthworms to most of the pesticides used in potato cultivation in developing countries like Colombia is incomplete as yet. Hence the aim of this study is to assess the lost of earthworm on the soils caused by different concentrations of pesticides and associated agricultural impacts caused by a lost in the soil bioturbation. As a first stage, we have studied earthworm's avoidance to pesticide concentration in a potato agricultural area located in Colombia. Local cultivated Eisenia fetida were exposed to four of the most frequent applied active ingredients in potato crops i.e. carbofuran, mancozeb, methamidophos and chlorpyriphos. Adult earthworm toxicity experiments were carried out in two soils, untreated grasslands under standard (ISO guidelines) and undisturbed conditions, and exposed to six different concentrations of the active ingredients. The results of the avoidance reaction on the standard soils were significant for carbofuran, mancoceb and chlorpyrifos. For each of the three active ingredients, we found i) overuse of pesticide, ii) applied dose of carbofuran, mancoceb and chlorpyrifos by the farmers potentially caused 20%, 11% and 9% of earthworms avoidance on the cultivated soils, respectively.

  6. Exposure to the widely used fungicide Mancozeb causes thyroid hormone disruption in rat dams but no behavioral effects in the offspring

    DEFF Research Database (Denmark)

    Petersen, Marta Axelstad; Boberg, Julie; Nellemann, Christine Lydia

    2011-01-01

    The widely used fungicide Mancozeb has been shown to cause hypothyroxinemia and other adverse effects on the thyroid hormone system in adult experimental animals. In humans, hypothyroxinemia early in pregnancy is associated with adverse effects on the developing nervous system and can lead...... to impaired cognitive function and motor development in children. The aim of the present study was therefore to assess whether perinatal Mancozeb exposure would cause developmental neurotoxicity in rats. Groups of 9-21 time-mated Wistar rats were dosed with 0, 50, 100 or 150 mg Mancozeb/kg bw/day by gavage...... offspring. The dose of 150 mg/kg/day caused neurotoxicity in the pregnant dams, and was therefore reduced to 100 mg/kg bw/day in mid study. T4 levels showed a dose-dependent and significant decreased in dams from all three dose groups on GD 15, whereas offspring T4 levels, thyroid weights and histology were...

  7. Disentangling the f(R). Duality

    International Nuclear Information System (INIS)

    Broy, Benedict J.; Westphal, Alexander; Pedro, Francisco G.; Univ. Autonoma de Madrid

    2014-11-01

    Motivated by UV realisations of Starobinsky-like inflation models, we study generic exponential plateau-like potentials to understand whether an exact f(R)-formulation may still be obtained when the asymptotic shift-symmetry of the potential is broken for larger field values. Potentials which break the shift symmetry with rising exponentials at large field values only allow for corresponding f(R)-descriptions with a leading order term R n with 1 2 -term survives as part of a series expansion of the function f(R) and thus cannot maintain a plateau for all field values. We further find a lean and instructive way to obtain a function f(R) describing m 2 φ 2 -inflation which breaks the shift symmetry with a monomial, and corresponds to effectively logarithmic corrections to an R+R 2 model. These examples emphasise that higher order terms in f(R)-theory may not be neglected if they are present at all. Additionally, we relate the function f(R) corresponding to chaotic inflation to a more general Jordan frame set-up. In addition, we consider f(R)-duals of two given UV examples, both from supergravity and string theory. Finally, we outline the CMB phenomenology of these models which show effects of power suppression at low-l.

  8. Geodesic congruences in the Palatini f(R) theory

    International Nuclear Information System (INIS)

    Shojai, Fatimah; Shojai, Ali

    2008-01-01

    We shall investigate the properties of a congruence of geodesics in the framework of Palatini f(R) theories. We shall evaluate the modified geodesic deviation equation and the Raychaudhuri's equation and show that f(R) Palatini theories do not necessarily lead to attractive forces. Also, we shall study energy condition for f(R) Palatini gravity via a perturbative analysis of the Raychaudhuri's equation.

  9. Clustering of galaxies with f(R) gravity

    Science.gov (United States)

    Capozziello, Salvatore; Faizal, Mir; Hameeda, Mir; Pourhassan, Behnam; Salzano, Vincenzo; Upadhyay, Sudhaker

    2018-02-01

    Based on thermodynamics, we discuss the galactic clustering of expanding Universe by assuming the gravitational interaction through the modified Newton's potential given by f(R) gravity. We compute the corrected N-particle partition function analytically. The corrected partition function leads to more exact equations of state of the system. By assuming that the system follows quasi-equilibrium, we derive the exact distribution function that exhibits the f(R) correction. Moreover, we evaluate the critical temperature and discuss the stability of the system. We observe the effects of correction of f(R) gravity on the power-law behaviour of particle-particle correlation function also. In order to check the feasibility of an f(R) gravity approach to the clustering of galaxies, we compare our results with an observational galaxy cluster catalogue.

  10. Nonlinear evolution of f(R) cosmologies. I. Methodology

    International Nuclear Information System (INIS)

    Oyaizu, Hiroaki

    2008-01-01

    We introduce the method and the implementation of a cosmological simulation of a class of metric-variation f(R) models that accelerate the cosmological expansion without a cosmological constant and evade solar-system bounds of small-field deviations to general relativity. Such simulations are shown to reduce to solving a nonlinear Poisson equation for the scalar degree of freedom introduced by the f(R) modifications. We detail the method to efficiently solve the nonlinear Poisson equation by using a Newton-Gauss-Seidel relaxation scheme coupled with the multigrid method to accelerate the convergence. The simulations are shown to satisfy tests comparing the simulated outcome to analytical solutions for simple situations, and the dynamics of the simulations are tested with orbital and Zeldovich collapse tests. Finally, we present several static and dynamical simulations using realistic cosmological parameters to highlight the differences between standard physics and f(R) physics. In general, we find that the f(R) modifications result in stronger gravitational attraction that enhances the dark matter power spectrum by ∼20% for large but observationally allowed f(R) modifications. A more detailed study of the nonlinear f(R) effects on the power spectrum are presented in a companion paper.

  11. Solar System constraints to general f(R) gravity

    International Nuclear Information System (INIS)

    Chiba, Takeshi; Smith, Tristan L.; Erickcek, Adrienne L.

    2007-01-01

    It has been proposed that cosmic acceleration or inflation can be driven by replacing the Einstein-Hilbert action of general relativity with a function f(R) of the Ricci scalar R. Such f(R) gravity theories have been shown to be equivalent to scalar-tensor theories of gravity that are incompatible with Solar System tests of general relativity, as long as the scalar field propagates over Solar System scales. Specifically, the parameterized post-Newtonian (PPN) parameter in the equivalent scalar-tensor theory is γ=1/2, which is far outside the range allowed by observations. In response to a flurry of papers that questioned the equivalence of f(R) theory to scalar-tensor theories, it was recently shown explicitly, without resorting to the scalar-tensor equivalence, that the vacuum field equations for 1/R gravity around a spherically symmetric mass also yield γ=1/2. Here we generalize this analysis to f(R) gravity and enumerate the conditions that, when satisfied by the function f(R), lead to the prediction that γ=1/2

  12. Biogenic synthesis of Ag-Au-In decorated on rGO nanosheet and its antioxidant and biological activities

    Science.gov (United States)

    Hazarika, Moushumi; Sonowal, Shashanka; Saikia, Indranirekha; Boruah, Purna K.; Das, Manash R.; Tamuly, Chandan

    2017-09-01

    Au-Ag-In-rGO nanocomposite was synthesized using fruit extract of Zanthoxylum rhetsa which is an eco-friendly, simple and green method. It was characterized by UV-visible, FT-IR, XRD, XPS, EDX, TEM technique. The antioxidant capacity of the nanocomposite was evaluated in presence of AgNO3, HAuCl4 and InCl3 solution respectively at 25 °C. The results showed significant antioxidant activity in presence of 1  ×  10-5 mM AgNO3 solution. The antibacterial activity of Au-Ag-In-rGO nanoparticles was carried out against the gram  -ve bacteria Pseudomonas aeruginosa, Escherichia coli and gram  +ve bacteria Staphylococcus aureus and Bacillus cereus. The bacterial growth kinetics was studied. The bacterial strain E. coli and S. aureus showed complete inhibition at concentration 100 µg ml-1. The activity is more effective in case of Au-Ag-In-rGO compared to GO.

  13. Toxicidade de produtos fitossanitários utilizados na cultura do pessegueiro sobre adultos de Trichogramma pretiosum Toxicity of pesticides used in peach orchard on adults Trichogramma pretiosum

    Directory of Open Access Journals (Sweden)

    Fabrizio Pinheiro Giolo

    2007-01-01

    Full Text Available A toxicidade de dezesseis formulações comerciais de produtos fitossanitários utilizados na cultura do pessegueiro foi avaliada para adultos de Trichogramma pretiosum Riley, 1879 (Hymenoptera: Trichogrammatidae. Os experimentos foram desenvolvidos utilizando-se a metodologia padrão da International Organization for Biological and Integrated Control of Noxious Animals and Plants, West Palaearctic Regional Section (IOBC/WPRS, em condições de laboratório, sob temperatura de 25 ± 1 ºC, umidade relativa de 70 ± 10% e fotofase de 14 horas. Os testes consistiram na exposição de adultos do parasitóide a resíduos secos dos produtos fitossanitários pulverizados sobre placas de vidro e mensuração do número de ovos parasitados por fêmea. Reduções no número de ovos parasitados por fêmea de T. pretiosum em relação à testemunha (somente água foram utilizadas para classificar os produtos segundo a IOBC/WPRS nas classes: 1, inócuo (99%. Os fungicidas (g ingrediente ativo 100 L-1 de água cálcio + cobre (40+100, dodina (79, folpete (125, iprodione (75, mancozebe (160, mancozebe + óxicloreto de cobre (88+60 e triforina (24 e o inseticida teflubenzurom (3,75 foram inócuos (classe 1; o fungicida tebuconazol (20 e óleo mineral (800 foram levemente nocivos (classe 2; o fungicida-acaricida enxofre (480 e o herbicida glufosinato de amônio (200 foram moderadamente nocivos (classe 3; os inseticidas espinosade (6, fenitrotiona (75, fosmete (100 e malationa (200 foram nocivos (classe 4 a T. pretiosum.The toxicity of sixteen commercial formulations of pesticides used in peach orchard was assessed on adults of Trichogramma pretiosum Riley, 1879 (Hymenoptera: Trichogrammatidae. The experiments were carried out using the International Organization for Biological and Integrated Control of Noxious Animals and Plants, West Palaearctic Regional Section (IOBC/WPRS standard methodology, under laboratory conditions at temperature of 25±1ºC, relative

  14. f(R) gravity and chameleon theories

    International Nuclear Information System (INIS)

    Brax, Philippe; Bruck, Carsten van de; Davis, Anne-Christine; Shaw, Douglas J.

    2008-01-01

    We analyze f(R) modifications of Einstein's gravity as dark energy models in the light of their connection with chameleon theories. Formulated as scalar-tensor theories, the f(R) theories imply the existence of a strong coupling of the scalar field to matter. This would violate all experimental gravitational tests on deviations from Newton's law. Fortunately, the existence of a matter dependent mass and a thin-shell effect allows one to alleviate these constraints. The thin-shell condition also implies strong restrictions on the cosmological dynamics of the f(R) theories. As a consequence, we find that the equation of state of dark energy is constrained to be extremely close to -1 in the recent past. We also examine the potential effects of f(R) theories in the context of the Eoet-wash experiments. We show that the requirement of a thin shell for the test bodies is not enough to guarantee a null result on deviations from Newton's law. As long as dark energy accounts for a sizeable fraction of the total energy density of the Universe, the constraints that we deduce also forbid any measurable deviation of the dark energy equation of state from -1. All in all, we find that both cosmological and laboratory tests imply that f(R) models are almost coincident with a ΛCDM model at the background level.

  15. Stellar equilibrium configurations of white dwarfs in the f(R, T) gravity

    Energy Technology Data Exchange (ETDEWEB)

    Carvalho, G.A.; Moraes, P.H.R.S.; Marinho, R.M.; Malheiro, M. [Instituto Tecnologico de Aeronautica, Departamento de Fisica, Sao Jose dos Campos, SP (Brazil); Lobato, R.V. [Instituto Tecnologico de Aeronautica, Departamento de Fisica, Sao Jose dos Campos, SP (Brazil); Sapienza Universita di Roma, Dipartimento di Fisica, Rome (Italy); ICRANet, Pescara (Italy); Arbanil, Jose D.V. [Universidad Privada del Norte, Departamento de Ciencias, Lima (Peru); Otoniel, E. [Universidade Federal do Cariri, Instituto de Formacao de Professores, Brejo Santo, CE (Brazil)

    2017-12-15

    In this work we investigate the equilibrium configurations of white dwarfs in a modified gravity theory, namely, f(R, T) gravity, for which R and T stand for the Ricci scalar and trace of the energy-momentum tensor, respectively. Considering the functional form f(R, T) = R+2λT, with λ being a constant, we obtain the hydrostatic equilibrium equation for the theory. Some physical properties of white dwarfs, such as: mass, radius, pressure and energy density, as well as their dependence on the parameter λ are derived. More massive and larger white dwarfs are found for negative values of λ when it decreases. The equilibrium configurations predict a maximum mass limit for white dwarfs slightly above the Chandrasekhar limit, with larger radii and lower central densities when compared to standard gravity outcomes. The most important effect of f(R, T) theory for massive white dwarfs is the increase of the radius in comparison with GR and also f(R) results. By comparing our results with some observational data of massive white dwarfs we also find a lower limit for λ, namely, λ > -3 x 10{sup -4}. (orig.)

  16. Thin layer chromatographic analyses of pesticides in a soil ecosystem

    International Nuclear Information System (INIS)

    Afful, S.; Dogbe, S.A.; Ahmad, K.; Ewusie, A.T.

    2008-01-01

    Silica gel 60, silica gel 60 F 254 , and aluminium oxide as adsorbents were used to investigate their suitability for the analysis and detection of the pesticides: nitrofen, atrazine, diuron, dioxacarb, propoxur, propanil, carbaryl and cypermethrin in soil ecosystem using ethyl acetate, chloroform, dichloromethane and ethyl acetate/chloroform (1:1) as developing solvents. O-tolidine and potassium iodide reagent were used for the detection of pesticides. R f values obtained for the pesticides using the silica gel 60-ethyl acetate. silica gel 60F 254 -ethyl acetate, silica gel 60 chloroform, silica gel 60 F 254 - chloroform, silica gel 60 - (1:1) ethyl acetate/chloroform and silica gel 60 F 254 - (1:1) ethyl acetate/chloroform systems generally were within the stipulated range of 0.4-0.8. R f values obtained for the pesticides using silica gel 60-dichloromethane systems were very low except for cypermethrin and nitrofen. Analysis with aluminium oxide coated plates gave a heavy yellow background with the detection reagent making visualization of spots difficult. Aluminium oxide coated plate is, therefore, not recommended when o-tolidine plus potassium iodide is used as detection reagent. (au)

  17. Ternary Au/ZnO/rGO nanocomposites electrodes for high performance electrochemical storage devices

    Science.gov (United States)

    Chaudhary, Manchal; Doong, Ruey-an; Kumar, Nagesh; Tseng, Tseung Yuen

    2017-10-01

    The combination of metal and metal oxide nanoparticles with reduced graphene oxides (rGO) is an active electrode material for electrochemical storage devices. Herein, we have, for the first time, reported the fabrication of ternary Au/ZnO/rGO nanocomposites by using a rapid and environmentally friendly microwave-assisted hydrothermal method for high performance supercapacitor applications. The ZnO/rGO provides excellent electrical conductivity and good macro/mesopore structures, which can facilitate the rapid electrons and ions transport. The Au nanoparticles with particle sizes of 7-12 nm are homogeneously distributed onto the ZnO/rGO surface to enhance the electrochemical performance by retaining the capacitance at high current density. The Au/ZnO/rGO nanocomposites, prepared with the optimized rGO amount of 100 mg exhibit a high specific capacitance of 875 and 424 F g-1 at current densities of 1 and 20 A g-1, respectively, in 2 M KOH. In addition, the energy and power densities of ternary Au/ZnO/rGO can be up to 17.6-36.5 Wh kg-1 and 0.27-5.42 kW kg-1, respectively. Results obtained in this study clearly demonstrate the excellence of ternary Au/ZnO/rGO nanocomposites as the active electrode materials for electrochemical pseudocapacitor performance and can open an avenue to fabricate metal/metal oxide/rGO nanocomposites for electrochemical storage devices with both high energy and power densities.

  18. Dynamics of anisotropic power-law f(R) cosmology

    International Nuclear Information System (INIS)

    Shamir, M. F.

    2016-01-01

    Modified theories of gravity have attracted much attention of the researchers in the recent years. In particular, the f(R) theory has been investigated extensively due to important f(R) gravity models in cosmological contexts. This paper is devoted to exploring an anisotropic universe in metric f(R) gravity. A locally rotationally symmetric Bianchi type I cosmological model is considered for this purpose. Exact solutions of modified field equations are obtained for a well-known f(R) gravity model. The energy conditions are also discussed for the model under consideration. The viability of the model is investigated via graphical analysis using the present-day values of cosmological parameters. The model satisfies null energy, weak energy, and dominant energy conditions for a particular range of the anisotropy parameter while the strong energy condition is violated, which shows that the anisotropic universe in f(R) gravity supports the crucial issue of accelerated expansion of the universe.

  19. Dynamics of anisotropic power-law f(R) cosmology

    Energy Technology Data Exchange (ETDEWEB)

    Shamir, M. F., E-mail: farasat.shamir@nu.edu.pk [National University of Computer and Emerging Sciences, Lahore Campus, Department of Sciences and Humanities (Pakistan)

    2016-12-15

    Modified theories of gravity have attracted much attention of the researchers in the recent years. In particular, the f(R) theory has been investigated extensively due to important f(R) gravity models in cosmological contexts. This paper is devoted to exploring an anisotropic universe in metric f(R) gravity. A locally rotationally symmetric Bianchi type I cosmological model is considered for this purpose. Exact solutions of modified field equations are obtained for a well-known f(R) gravity model. The energy conditions are also discussed for the model under consideration. The viability of the model is investigated via graphical analysis using the present-day values of cosmological parameters. The model satisfies null energy, weak energy, and dominant energy conditions for a particular range of the anisotropy parameter while the strong energy condition is violated, which shows that the anisotropic universe in f(R) gravity supports the crucial issue of accelerated expansion of the universe.

  20. Effects of currently used pesticides in the AhR-CALUX assay

    DEFF Research Database (Denmark)

    Long, Manhai; Laier, Peter; Vinggaard, Anne Marie

    2003-01-01

    101L hepatoma cell lines. In comparison the results indicated that the rat H4IIE cell line is more sensitive than the human TV101L for detection of TCDD inducing AhR-CALUX activity. The pesticides iprodione, chlorpyrifos and prochloraz showed dose-dependent AhR agonistic effects in both cell lines...

  1. De l’utopie socialiste au réalisme chrétien

    Directory of Open Access Journals (Sweden)

    Isabelle Richet

    2006-03-01

    Full Text Available Le New Deal est le premier mouvement réformiste d’ampleur dans l’histoire des Etats‑Unis qui n’ait pas été inspiré, ni soutenu, par les forces du protestantisme. Si une majorité des protestants et de leur clergé se sont opposés au New Deal à partir de positions conservatrices, le théologien Reinhold Niebuhr en a développé au départ une virulente critique de gauche avant de finalement rallier le président démocrate à la fin des années trente. Nourrie par le rejet de l’idéalisme du Social Gospel, incapable à ses yeux de comprendre les rapports sociaux en terme de classe et de pouvoir, la critique de Niebuhr emprunte les outils d’analyse marxistes pour développer une approche réaliste, tant du point de vue des fins que des moyens de la lutte politique. Le New Deal lui apparaît avant tout comme un programme visant à sauver le capitalisme, alors que la société fondée sur la justice qu’il envisage passe par la socialisation des moyens de production qui ne pourra émerger qu’à travers des conflits sociaux au cours desquels les moyens de lutte même violents sont justifiés. Mais sous l’influence des évènements en Europe au lendemain de la victoire d’Hitler, Reinhold Niebuhr se tourne au milieu des années trente vers une réflexion théologique inspirée de l’orthodoxie de Karl Barth et de son frère Richard Niebuhr, qui l’amène à réintroduire le péché comme la limite absolue de toute l’expérience humaine, interdisant d’envisager la création d’une société de paix et de justice. Ce nouvel absolutisme théologique nourrit un relativisme politique, le réalisme chrétien consistant désormais à choisir la moins mauvaise des options en présence. De ce point de vue, le président démocrate qui appelle à la préparation militaire s’impose désormais comme le choix le plus réaliste face à la montée du fascisme en Europe.The New Deal was the first major reformist experiment in the

  2. Manganese concentrations in drinking water from villages near banana plantations with aerial mancozeb spraying in Costa Rica: Results from the Infants' Environmental Health Study (ISA).

    Science.gov (United States)

    van Wendel de Joode, Berna; Barbeau, Benoit; Bouchard, Maryse F; Mora, Ana María; Skytt, Åsa; Córdoba, Leonel; Quesada, Rosario; Lundh, Thomas; Lindh, Christian H; Mergler, Donna

    2016-08-01

    Elevated manganese (Mn) in drinking water has been reported worldwide. While, naturally occurring Mn in groundwater is generally the major source, anthropogenic contamination by Mn-containing fungicides such as mancozeb may also occur. The main objective of this study was to examine factors associated with Mn and ethylenethiourea (ETU), a degradation product of mancozeb, in drinking water samples from villages situated near banana plantations with aerial spraying of mancozeb. Drinking water samples (n = 126) were obtained from 124 homes of women participating in the Infants' Environmental Health Study (ISA, for its acronym in Spanish), living nearby large-scale banana plantations. Concentrations of Mn, iron (Fe), arsenic (As), lead (Pb), cadmium (Cd) and ethylenethiourea (ETU), a degradation product of mancozeb, were measured in water samples. Only six percent of samples had detectable ETU concentrations (limit of detection (LOD) = 0.15 μg/L), whereas 94% of the samples had detectable Mn (LOD = 0.05 μg/L). Mn concentrations were higher than 100 and 500 μg/L in 22% and 7% of the samples, respectively. Mn was highest in samples from private and banana farm wells. Distance from a banana plantation was inversely associated with Mn concentrations, with a 61.5% decrease (95% CI: -97.0, -26.0) in Mn concentrations for each km increase in distance. Mn concentrations in water transported with trucks from one village to another were almost 1000 times higher than Mn in water obtained from taps in houses supplied by the same well but not transported, indicating environmental Mn contamination. Elevated Mn in drinking water may be partly explained by aerial spraying of mancozeb; however, naturally occurring Mn in groundwater, and intensive agriculture may also contribute. Drinking water risk assessment for mancozeb should consider Mn as a health hazard. The findings of this study evidence the need for health-based World Health Organization (WHO) guidelines on Mn in

  3. Effects of pesticides on the peripheral and central nervous system in tobacco farmers in Malaysia: studies on peripheral nerve conduction, brain-evoked potentials and computerized posturography.

    Science.gov (United States)

    Kimura, Kaoru; Yokoyama, Kazuhito; Sato, Hajime; Nordin, Rusli Bin; Naing, Lin; Kimura, Satoshi; Okabe, Shingo; Maeno, Takashi; Kobayashi, Yasuki; Kitamura, Fumihiko; Araki, Shunichi

    2005-04-01

    We examined the effects of pesticides on the central and peripheral nervous system in the setting of a tobacco farm at a developing country. Maximal motor and sensory nerve conduction velocities (MCV and SCV, respectively) in the median, sural and tibial nerves, postural sway, and brain-evoked potentials (auditory event-related and visual-evoked potentials) were measured in 80 male tobacco farmers and age- and sex-matched 40 controls in Kelantan, Malaysia. Median SCV (finger-wrist) in farmers using Delsen (mancozeb, dithiocarbamate fungicide), who showed significant decrease of serum cholinesterase activities, were significantly lower compared with the controls. Sural SCV in farmers using Fastac (alpha-cypermethrin, pyrethroid insecticide) and median MCV (elbow-wrist) in farmers using Tamex (butralin, dinitroaniline herbicide) were significantly slowed compared with their respective controls. In Delsen (mancozeb, dithiocarbamate) users, the power of postural sway of 0-1 Hz was significantly larger than that in the controls both in the anterior-posterior direction with eyes open and in the right-left direction with eyes closed. The former type of sway was also significantly increased in Tamaron (methamidophos, organophosphorus insecticide) users. In conclusion, nerve conduction velocities and postural sway seem to be sensitive indicators of the effects of pesticides on the central and peripheral nervous system.

  4. Synthesis of Au38(SCH2CH2Ph)24, Au36(SPh-tBu)24, and Au30(S-tBu)18 Nanomolecules from a Common Precursor Mixture.

    Science.gov (United States)

    Rambukwella, Milan; Dass, Amala

    2017-10-17

    Phenylethanethiol protected nanomolecules such as Au 25 , Au 38 , and Au 144 are widely studied by a broad range of scientists in the community, owing primarily to the availability of simple synthetic protocols. However, synthetic methods are not available for other ligands, such as aromatic thiol and bulky ligands, impeding progress. Here we report the facile synthesis of three distinct nanomolecules, Au 38 (SCH 2 CH 2 Ph) 24 , Au 36 (SPh-tBu) 24 , and Au 30 (S-tBu) 18 , exclusively, starting from a common Au n (glutathione) m (where n and m are number of gold atoms and glutathiolate ligands) starting material upon reaction with HSCH 2 CH 2 Ph, HSPh-tBu, and HStBu, respectively. The systematic synthetic approach involves two steps: (i) synthesis of kinetically controlled Au n (glutathione) m crude nanocluster mixture with 1:4 gold to thiol molar ratio and (ii) thermochemical treatment of the purified nanocluster mixture with excess thiols to obtain thermodynamically stable nanomolecules. Thermochemical reactions with physicochemically different ligands formed highly monodispersed, exclusively three different core-size nanomolecules, suggesting a ligand induced core-size conversion and structural transformation. The purpose of this work is to make available a facile and simple synthetic method for the preparation of Au 38 (SCH 2 CH 2 Ph) 24 , Au 36 (SPh-tBu) 24 , and Au 30 (S-tBu) 18 , to nonspecialists and the broader scientific community. The central idea of simple synthetic method was demonstrated with other ligand systems such as cyclopentanethiol (HSC 5 H 9 ), cyclohexanethiol(HSC 6 H 11 ), para-methylbenzenethiol(pMBT), 1-pentanethiol(HSC 5 H 11 ), 1-hexanethiol(HSC 6 H 13 ), where Au 36 (SC 5 H 9 ) 24 , Au 36 (SC 6 H 11 ) 24 , Au 36 (pMBT) 24 , Au 38 (SC 5 H 11 ) 24 , and Au 38 (SC 6 H 13 ) 24 were obtained, respectively.

  5. Facteurs de risque de mortalité chez les nouveaux-nés transférés au service de néonatologie de l'Hôpital Jason Sendwe de Lubumbashi, République Démocratique du Congo

    Science.gov (United States)

    Katamea, Tina; Mukuku, Olivier; Kamona, Lewis; Mukelenge, Kethye; Mbula, Otikeke; Baledi, Lambert; Ntambwe, Emile; Mutombo, Augustin Mulangu; Wembonyama, Stanis Okitotsho; Luboya, Oscar Numbi

    2014-01-01

    Introduction La mortalité néonatale reste préoccupante dans notre milieu et plusieurs facteurs dont ceux liés à l'organisation du transfert de nouveau-nés au niveau des structures de prise en charge y contribuent. Les objectifs de notre étude sont de déterminer la fréquence du transfert néonatal extrahospitalier à l'unité de néonatologie et identifier les facteurs de risque de mortalité dans notre milieu. Méthodes Il s'agit d'une étude prospective et analytique menée sur une période de douze mois allant du 1er Janvier 2012 au 31 décembre 2012 ayant ciblé tous les nouveau-nés transférés des maternités extérieurs, traités et suivis dans le service de néonatologie de l'hôpital Sendwe. Les caractéristiques maternelles (âge, parité, état-civil, profession, niveau d’étude, antécédents médicaux et toxicologiques) et perpartales (âge gestationnel, état de la poche des eaux, voie d'accouchement) et néonataux (âge lors du transfert, sexe, poids de naissance, moyen de transfert, motif de transfert et évolution (guérison ou décès)) ont été étudiés. La saisie et l'analyse des données ont été faites sur le logiciel Epi Info 2011 (version 7.0.8.3) et le seuil de signification de 5%. Résultats La fréquence du transfert néonatal extrahospitalier est de 12,9%. La mortalité était significativement liée à la profession (vendeuse ou travailleuse) de la mère (OR = 7,43 (1,38-39,97)), au niveau d’étude élevé (OR = 4,22 (1,18-15,10)), à l’âge gestationnel sexe masculin du nouveau-né (OR=2,43 (1,08-5,46)), au poids de naissance <1500 grammes (OR=15,3 (5,73-40,78)) et à la prématurité comme motif de transfert (OR=5,56 (1,47-20,98)). Conclusion Le bilan de la mortalité néonatale est lourd dans les pays en développement où les nouveau-nés continuent de mourir pour des causes souvent évitables. La réduction de la morbidité et la mortalité néonatales passe par une amélioration du système de référence des

  6. Cosmology of f(R) gravity in the metric variational approach

    Science.gov (United States)

    Li, Baojiu; Barrow, John D.

    2007-04-01

    We consider the cosmologies that arise in a subclass of f(R) gravity with f(R)=R+μ2n+2/(-R)n and n∈(-1,0) in the metric (as opposed to the Palatini) variational approach to deriving the gravitational field equations. The calculations of the isotropic and homogeneous cosmological models are undertaken in the Jordan frame and at both the background and the perturbation levels. For the former, we also discuss the connection to the Einstein frame in which the extra degree of freedom in the theory is associated with a scalar field sharing some of the properties of a “chameleon” field. For the latter, we derive the cosmological perturbation equations in general theories of f(R) gravity in covariant form and implement them numerically to calculate the cosmic microwave background (CMB) temperature and matter power spectra of the cosmological model. The CMB power is shown to reduce at low l’s, and the matter power spectrum is almost scale independent at small scales, thus having a similar shape to that in standard general relativity. These are in stark contrast with what was found in the Palatini f(R) gravity, where the CMB power is largely amplified at low l’s and the matter spectrum is strongly scale dependent at small scales. These features make the present model more adaptable than that arising from the Palatini f(R) field equations, and none of the data on background evolution, CMB power spectrum, or matter power spectrum currently rule it out.

  7. Degradation of the Neonicotinoid Pesticides in the Atmospheric Pressure Ionization Source

    Science.gov (United States)

    Chai, Yunfeng; Chen, Hongping; Liu, Xin; Lu, Chengyin

    2018-02-01

    During the analysis of neonicotinoid pesticide standards (thiamethoxam, clothianidin, imidacloprid, acetamiprid, and thiacloprid) by mass spectrometry, the degradation of these pesticides (M-C=N-R is degraded into M-C=O, M is the skeleton moiety, and R is NO2 or CN) was observed in the atmospheric pressure ionization interfaces (ESI and APCI). In APCI, the degradation of all the five neonicotinoid pesticides studied took place, and the primary mechanism was in-source ion/molecule reaction, in which a molecule of water (confirmed by use of H2 18O) attacked the carbon of the imine group accompanying with loss of NH2R (R=NO2, CN). For the nitroguanidine neonicotinoid pesticides (R=NO2, including thiamethoxam, clothianidin, and imidacloprid), higher auxiliary gas heater temperature also contributed to their degradation in APCI due to in-source pyrolysis. The degradation of the five neonicotinoid pesticides studied in ESI was not significant. In ESI, only the nitroguanidine neonicotinoid pesticides could generate the degradation products through in-source fragmentation mechanism. The degradation of cyanoamidine neonicotinoid pesticides (R=CN, including acetamiprid and thiacloprid) in ESI was not observed. The degradation of neonicotinoid pesticides in the ion source of mass spectrometer renders some adverse consequences, such as difficulty interpreting the full-scan mass spectrum, reducing the sensitivity and accuracy of quantitative analysis, and misleading whether these pesticides have degraded in the real samples. Therefore, a clear understanding of these unusual degradation reactions should facilitate the analysis of neonicotinoid pesticides by atmospheric pressure ionization mass spectrometry.

  8. Degradation of the Neonicotinoid Pesticides in the Atmospheric Pressure Ionization Source.

    Science.gov (United States)

    Chai, Yunfeng; Chen, Hongping; Liu, Xin; Lu, Chengyin

    2018-02-01

    During the analysis of neonicotinoid pesticide standards (thiamethoxam, clothianidin, imidacloprid, acetamiprid, and thiacloprid) by mass spectrometry, the degradation of these pesticides (M-C=N-R is degraded into M-C=O, M is the skeleton moiety, and R is NO 2 or CN) was observed in the atmospheric pressure ionization interfaces (ESI and APCI). In APCI, the degradation of all the five neonicotinoid pesticides studied took place, and the primary mechanism was in-source ion/molecule reaction, in which a molecule of water (confirmed by use of H 2 18 O) attacked the carbon of the imine group accompanying with loss of NH 2 R (R=NO 2 , CN). For the nitroguanidine neonicotinoid pesticides (R=NO 2 , including thiamethoxam, clothianidin, and imidacloprid), higher auxiliary gas heater temperature also contributed to their degradation in APCI due to in-source pyrolysis. The degradation of the five neonicotinoid pesticides studied in ESI was not significant. In ESI, only the nitroguanidine neonicotinoid pesticides could generate the degradation products through in-source fragmentation mechanism. The degradation of cyanoamidine neonicotinoid pesticides (R=CN, including acetamiprid and thiacloprid) in ESI was not observed. The degradation of neonicotinoid pesticides in the ion source of mass spectrometer renders some adverse consequences, such as difficulty interpreting the full-scan mass spectrum, reducing the sensitivity and accuracy of quantitative analysis, and misleading whether these pesticides have degraded in the real samples. Therefore, a clear understanding of these unusual degradation reactions should facilitate the analysis of neonicotinoid pesticides by atmospheric pressure ionization mass spectrometry. Graphical Abstract.

  9. [Hyp-Au-Sn9(Hyp)3-Au-Sn9(Hyp)3-Au-Hyp]-: the longest intermetalloid chain compound of tin.

    Science.gov (United States)

    Binder, Mareike; Schrenk, Claudio; Block, Theresa; Pöttgen, Rainer; Schnepf, Andreas

    2017-10-12

    The reaction of the metalloid tin cluster [Sn 10 (Hyp) 4 ] 2- with (Ph 3 P)Au-SHyp (Hyp = Si(SiMe 3 ) 3 ) gave an intermetalloid cluster [Au 3 Sn 18 (Hyp) 8 ] - 1, which is the longest intermetalloid chain compound of tin to date. 1 shows a structural resemblance to binary AuSn phases, which is expected for intermetalloid clusters.

  10. Impact of pesticides on farmer health and the rice environment

    OpenAIRE

    Pingali, P.L. (ed.); Roger, Pierre-Armand (ed.)

    1995-01-01

    Cet ouvrage présente les conséquences indésirables ou involontaires de l'utilisation des pesticides sur les riziculteurs et les environnements rizicoles. Ses quatorze chapitres et cinq annexes comprennent des revues bibliographiques, des résultats d'enquêtes en milieu paysan, et les résultats d'études au champ et d'études expérimentales conduites entre 1989 et 1991 aux Philippines sous la forme d'un projet multidisciplinaire rassemblant des chercheurs de l'IRRI, du NRI (Angleterre), de l'ORST...

  11. Further stable neutron star models from f(R) gravity

    Energy Technology Data Exchange (ETDEWEB)

    Astashenok, Artyom V. [I. Kant Baltic Federal University, Institute of Physics and Technology, Nevskogo st. 14, Kaliningrad, 236041 (Russian Federation); Capozziello, Salvatore [Dipartimento di Fisica, Università di Napoli ' ' Federico II' ' , Via Cinthia, 9, Napoli, I–80126 (Italy); Odintsov, Sergei D., E-mail: artyom.art@gmail.com, E-mail: capozziello@na.infn.it, E-mail: odintsov@ieec.uab.es [Instituciò Catalana de Recerca i Estudis Avançats (ICREA), Barcelona (Spain)

    2013-12-01

    Neutron star models in perturbative f(R) gravity are considered with realistic equations of state. In particular, we consider the FPS, SLy and other equations of state and a case of piecewise equation of state for stars with quark cores. The mass-radius relations for f(R) = R+R(e{sup −R/R{sub 0}}−1) model and for R{sup 2} models with logarithmic and cubic corrections are obtained. In the case of R{sup 2} gravity with cubic corrections, we obtain that at high central densities (ρ > 10ρ{sub ns}, where ρ{sub ns} = 2.7 × 10{sup 14} g/cm{sup 3} is the nuclear saturation density), stable star configurations exist. The minimal radius of such stars is close to 9 km with maximal mass ∼ 1.9M{sub ⊙} (SLy equation). A similar situation takes place for AP4 and BSK20 EoS. Such an effect can give rise to more compact stars than in General Relativity. If observationally identified, such objects could constitute a formidable signature for modified gravity at astrophysical level. Another interesting result can be achieved in modified gravity with only a cubic correction. For some EoS, the upper limit of neutron star mass increases and therefore these EoS can describe realistic star configurations (although, in General Relativity, these EoS are excluded by observational constraints)

  12. Further stable neutron star models from f(R) gravity

    International Nuclear Information System (INIS)

    Astashenok, Artyom V.; Capozziello, Salvatore; Odintsov, Sergei D.

    2013-01-01

    Neutron star models in perturbative f(R) gravity are considered with realistic equations of state. In particular, we consider the FPS, SLy and other equations of state and a case of piecewise equation of state for stars with quark cores. The mass-radius relations for f(R) = R+R(e −R/R 0 −1) model and for R 2 models with logarithmic and cubic corrections are obtained. In the case of R 2 gravity with cubic corrections, we obtain that at high central densities (ρ > 10ρ ns , where ρ ns = 2.7 × 10 14 g/cm 3 is the nuclear saturation density), stable star configurations exist. The minimal radius of such stars is close to 9 km with maximal mass ∼ 1.9M ⊙ (SLy equation). A similar situation takes place for AP4 and BSK20 EoS. Such an effect can give rise to more compact stars than in General Relativity. If observationally identified, such objects could constitute a formidable signature for modified gravity at astrophysical level. Another interesting result can be achieved in modified gravity with only a cubic correction. For some EoS, the upper limit of neutron star mass increases and therefore these EoS can describe realistic star configurations (although, in General Relativity, these EoS are excluded by observational constraints)

  13. Efeito de fungicidas cúpricos, aplicados isoladamente ou em combinação com mancozeb, na expressão de sintomas de fitotoxicidade e controle da ferrugem causada por Puccinia psidii em goiabeira Effect of copper fungicides, sprayed alone or in combination with mancozeb, in expression of phytotoxicity symptoms and rust control caused by Puccinia psidii in guava

    Directory of Open Access Journals (Sweden)

    Antonio de Goes

    2004-08-01

    Full Text Available Dois experimentos foram conduzidos em pomares de goiabeira 'Paluma', nos municípios de Monte Alto e Vista Alegre do Alto-SP. No primeiro experimento, avaliou-se o efeito de formulações de fungicidas cúpricos, aplicados isoladamente e em mistura com mancozeb, quanto ao efeito fitotóxico em botões florais e em frutos de goiabeira, em três estádios de desenvolvimento. No segundo experimento, foram avaliados os mesmos fungicidas usados no primeiro experimento, sendo, porém, acrescido do tratamento constituído por tebuconazole, cujo alvo foi sua eficiência no controle da ferrugem. No primeiro experimento, verificou-se que nenhum dos fungicidas testados causou abortamento de flores ou outros tipos de sintomas de fitotoxicidade em frutos de tamanho inferior a 15 mm de diâmetro. Contrariamente, estes fungicidas, quando aplicados isoladamente, em frutos entre 25 a 35 mm de diâmetro, causaram sintomas severos de fitotoxicidade. Em frutos de tamanho superior a 40 mm de diâmetro, estes fungicidas causaram sintomas de fitotoxicidade de níveis leves a moderados. A combinação de fungicidas cúpricos com mancozeb causou sintomas de fitotoxicidade em níveis leves, enquanto com mancozeb isoladamente não foram verificados sintomas de fitotoxicidade. No segundo experimento, verificou-se que os fungicidas cúpricos, aplicados isoladamente, foram eficientes no controle da ferrugem da goiabeira, apresentando eficiência comparável ao tratamento-padrão representado por tebuconazole. Esta eficiência foi também observada mediante o emprego da combinação mancozeb e óxido cuproso ou hidróxido de cobre.Two experiments were carried out in guava orchards cv. 'Paluma' at Monte Alto and Vista Alegre do Alto/SP. In Experiment 1 it was used copper fungicides applied alone and in combination with mancozeb to evaluate the effect of phytotoxicity on floral buds and guava fruits in three developmental stages. In Experiment 2 it was used the same fungicides

  14. Cancer du sein au Cameroun, profil histo-épidémiologique: à propos de 3044 cas

    Science.gov (United States)

    Engbang, Jean Paul Ndamba; Essome, Henri; Koh, Valère Mve; Simo, Godefroy; Essam, Jean Daniel Sime; Mouelle, Albert Sone; Essame, Jean Louis Oyono

    2015-01-01

    Décrire les caractéristiques épidémiologiques et histo-pathologiques des tumeurs malignes du sein au Cameroun. Il s'agissait d'une étude rétrospective descriptive portant sur les tumeurs malignes du sein, colligées, dans les registres des différents laboratoires d'Anatomie Pathologique publiques et privés repartis dans cinq régions (centre, littoral, Ouest, Nord-ouest, Sud-ouest), pendant une période de 10 ans (2004-2013). Les paramètres étudiés étaient la fréquence, l’âge, le sexe, la localisation, le type et le grade histologique, et les récepteurs hormonaux. Un total de 3044 cas de cancers du sein a été recensé, soit une fréquence annuelle de 304,4 cas en moyenne. Le sexe féminin était le plus représenté avec 2971 cas (97,60%) et les hommes avec 73 cas (2,40%), soit un sexe ratio (H/F) de 0,02. L’âge moyen des patients était de 46±15,87 ans, avec des extrêmes de 13 et 95 ans. Selon la localisation, le sein gauche était atteint dans 1244 cas (52%) et le sein droit dans 1115 cas (47%). Au plan histologique, on retrouvait essentiellement des carcinomes avec 96,50% des cas, des sarcomes 1,39%, des lymphomes 1,07% et la maladie de Paget du mamelon, 1,03%. Les tumeurs épithéliales étaient infiltrantes dans 2049 cas (84,46%), avec une prédominance du carcinome canalaire infiltrant (1870 cas) et non infiltrantes dans 377 cas (15,54%). Le grade histo-pronostic de SBR avait révélé une prédominance du grade II dans 66% des cas. Les cancers du sein restent une pathologie fréquente au Cameroun et atteignent principalement la population féminine en âge de procréer. Ils sont caractérisés par la prédominance du carcinome canalaire infiltrant. PMID:26523182

  15. Les fondements de la mesure du temps comment les fréquences atomiques règlent le monde

    CERN Document Server

    Audoin, Claude

    1998-01-01

    La mesure du temps fondée sur des propriétés atomiques est née en 1955, avec le premier étalon de fréquence à jet de césium. Depuis, les horloges atomiques ne cessent de progresser et sont au coeur de nombreuses activités, telles que les comparaisons de temps, l'unification mondiale de l'heure ou la recherche en astronomie, géodésie, géophysique, télécommunications, etc. Cet ouvrage fournira des réponses détaillées au lecteur intéressé par la mesure du temps appliquée aux divers domaines cités.

  16. Exposure to pesticides or solvents and risk of Parkinson disease.

    Science.gov (United States)

    Pezzoli, Gianni; Cereda, Emanuele

    2013-05-28

    To investigate the risk of Parkinson disease (PD) associated with exposure to pesticides and solvents using meta-analyses of data from cohort and case-control studies. Prospective cohort and case-control studies providing risk and precision estimates relating PD to exposure to pesticides or solvents or to proxies of exposure were considered eligible. The heterogeneity in risk estimates associated with objective study quality was also investigated. A total of 104 studies/3,087 citations fulfilled inclusion criteria for meta-analysis. In prospective studies, study quality was not a source of heterogeneity. PD was associated with farming and the association with pesticides was highly significant in the studies in which PD diagnosis was self-reported. In case-control studies, study quality appeared to be a source of heterogeneity in risk estimates for some exposures. Higher study quality was frequently associated with a reduction in heterogeneity. In high-quality case-control studies, PD risk was increased by exposure to any-type pesticides, herbicides, and solvents. Exposure to paraquat or maneb/mancozeb was associated with about a 2-fold increase in risk. In high-quality case-control studies including an appreciable number of cases (>200), heterogeneity remained significantly high (>40%) only for insecticides, organochlorines, organophosphates, and farming; also, the risk associated with rural living was found to be significant. The literature supports the hypothesis that exposure to pesticides or solvents is a risk factor for PD. Further prospective and high-quality case-control studies are required to substantiate a cause-effect relationship. The studies should also focus on specific chemical agents.

  17. 77 FR 14361 - Pesticide Products; Receipt of Applications To Register New Uses

    Science.gov (United States)

    2012-03-09

    ... docket are listed in the docket index available at http://www.regulations.gov . Although listed in the index, some information is not publicly available, e.g., CBI or other information whose disclosure is... ingredient: Mancozeb. Proposed use: Walnut. Contact: Lisa Jones, Registration Division, (703) 308-9424, jones...

  18. Closed string tachyon driving f(R) cosmology

    Science.gov (United States)

    Wang, Peng; Wu, Houwen; Yang, Haitang

    2018-05-01

    To study quantum effects on the bulk tachyon dynamics, we replace R with f(R) in the low-energy effective action that couples gravity, the dilaton, and the bulk closed string tachyon of bosonic closed string theory and study properties of their classical solutions. The α' corrections of the graviton-dilaton-tachyon system are implemented in the f(R). We obtain the tachyon-induced rolling solutions and show that the string metric does not need to remain fixed in some cases. In the case with H( t=‑∞ ) = , only the R and R2 terms in f(R) play a role in obtaining the rolling solutions with nontrivial metric. The singular behavior of more classical solutions are investigated and found to be modified by quantum effects. In particular, there could exist some classical solutions, in which the tachyon field rolls down from a maximum of the tachyon potential while the dilaton expectation value is always bounded from above during the rolling process.

  19. f(R) gravity, torsion and non-metricity

    International Nuclear Information System (INIS)

    Sotiriou, Thomas P

    2009-01-01

    For both f(R) theories of gravity with an independent symmetric connection (no torsion), usually referred to as Palatini f(R) gravity theories, and for f(R) theories of gravity with torsion but no non-metricity, called U4 theories, it has been shown that the independent connection can actually be eliminated algebraically, as long as this connection does not couple to matter. Remarkably, the outcome in both cases is the same theory, which is dynamically equivalent with an ω 0 = -3/2 Brans-Dicke theory. It is shown here that even for the most general case of an independent connection with both non-metricity and torsion, one arrives at exactly the same theory as in the more restricted cases. This generalizes the previous results and explains why assuming that either the torsion or the non-metricity vanishing ultimately leads to the same theory. It also demonstrates that f(R) actions cannot support an independent connection which carries dynamical degrees of freedom, irrespective of how general this connection is, at least as long as there is no connection-matter coupling. (fast track communication)

  20. Standard cosmological evolution in the f(R) model to Kaluza-Klein cosmology

    International Nuclear Information System (INIS)

    Aghmohammadi, A; Abolhassani, M R; Saaidi, Kh; Vajdi, A

    2009-01-01

    In this paper, using f(R) theory of gravity we explicitly calculate cosmological evolution in the presence of a perfect fluid source in four- and five-dimensional space-time in which this cosmological evolution in self-creation is presented by Reddy et al (2009 Int. J. Theor. Phys. 48 10). An exact cosmological model is presented using a relation between Einstein's gravity field equation components due to a metric with the same component from f(R) theory of gravity. Some physics and kinematical properties of the model are also discussed.

  1. Effective Dark Matter Halo Catalog in f(R) Gravity.

    Science.gov (United States)

    He, Jian-Hua; Hawken, Adam J; Li, Baojiu; Guzzo, Luigi

    2015-08-14

    We introduce the idea of an effective dark matter halo catalog in f(R) gravity, which is built using the effective density field. Using a suite of high resolution N-body simulations, we find that the dynamical properties of halos, such as the distribution of density, velocity dispersion, specific angular momentum and spin, in the effective catalog of f(R) gravity closely mimic those in the cold dark matter model with a cosmological constant (ΛCDM). Thus, when using effective halos, an f(R) model can be viewed as a ΛCDM model. This effective catalog therefore provides a convenient way for studying the baryonic physics, the galaxy halo occupation distribution and even semianalytical galaxy formation in f(R) cosmologies.

  2. Constraints on perturbative f(R) gravity via neutron stars

    Energy Technology Data Exchange (ETDEWEB)

    Arapoğlu, Savaş; Ekşi, K. Yavuz [İstanbul Technical University, Faculty of Science and Letters, Physics Engineering Department, Maslak 34469, İstanbul (Turkey); Deliduman, Cemsinan, E-mail: arapoglu@itu.edu.tr, E-mail: cemsinan@msgsu.edu.tr, E-mail: eksi@itu.edu.tr [Mimar Sinan Fine Arts University, Department of Physics, Beşiktaş 34349, İstanbul (Turkey)

    2011-07-01

    We study the structure of neutron stars in perturbative f(R) gravity models with realistic equations of state. We obtain mass-radius relations in a gravity model of the form f(R) = R+αR{sup 2}. We find that deviations from the results of general relativity, comparable to the variations due to using different equations of state (EoS'), are induced for |α| ∼ 10{sup 9} cm{sup 2}. Some of the soft EoS' that are excluded within the framework of general relativity can be reconciled with the 2 solar mass neutron star recently observed for certain values of α within this range. For some of the EoS' we find that a new solution branch, which allows highly massive neutron stars, exists for values of α greater than a few 10{sup 9} cm{sup 2}. We find constraints on α for a variety of EoS' using the recent observational constraints on the mass-radius relation. These are all 5 orders of magnitude smaller than the recent constraint obtained via Gravity Probe B for this gravity model. The associated length scale √(alpha)approx 10{sup 5} cm is only an order of magnitude smaller than the typical radius of a neutron star, the probe used in this test. This implies that real deviations from general relativity can be even smaller.

  3. Liaison, élision et enchaînement : le rôle de la phonologie et du lexique chez les enfants au début de l’école primaire

    Directory of Open Access Journals (Sweden)

    Ruvoletto Samantha

    2014-07-01

    Dans cette étude nous cherchons d'évaluer de manière détaillée l’importance relative de la phonologie et des connaissances lexicales de 43 enfants français à l’entrée du CP et d'analyser les problématiques causées par les phénomènes consonantiques de liaison, d’élision et d’enchaînement dans cette phase d'acquisition. Les résultats d'une tâche de dénomination guidée montrent que les enfants de 6 ans et demi ont encore des problèmes avec le calcul des frontières des mots en français au début de l'école primaire. De plus dans nos données, la fréquence lexicale des mots tests ne résulte pas corrélée au nombre d'erreurs. Les fautes résiduelles dans la tâche sont donc consécutives à un problème phonologique et pas exclusivement lexical. Le rôle prioritaire de la phonologie à l'entrée de l'école primaire est en accord avec les conclusions de Sprenger-Charolles (1994 qui proposent que la première phase d’apprentissage de la lecture et de l'écriture repose essentiellement sur une analyse phonologique indépendante de la fréquence lexicale.

  4. Multi-Residue studies of pesticides in fermented dried cocoa beans and selected cocoa products produced in Ghana

    International Nuclear Information System (INIS)

    Frimpong, S. K

    2011-01-01

    the organochlorine, organophosphorous and synthetic pyrethroids pesticides respectively. Multivariate analysis on the residue data obtained from fermented dried cocoa beans in R-mode and Q-mode grouped the detected pesticides into currently used, previously used and drift from neighbouring crops pesticides applications. It also grouped sampled cocoa beans into four major clusters based on similarities in crop storage and farm practices. Beta-HCH (18.7 μg/kg), Gamma-chlordane (152.0 μg/kg), Methamidophos (18.5 μg/kg), Profenofos (31.8 μg/kg), Allethrin (10.5 μg/kg), Cypermethrin (32.0 μg/kg) and Fenvalerate (14.6 μg/kg) were the average residues concentrations of pesticides that exceeded the Japanese maximum residue levels (MRLs). However, all the detected pesticides with exception of Allethrin were below the MRLs for European Union. From results recorded in semi-finished and finished cocoa beans products produced in Ghana, de-shelling and roasting temperatures drastically reduced the residue levels in the cocoa products, but these were not enough solution for pesticide residues in cocoa beans. And thus raises concern about the health implication of these chemicals for domestic consumption of these products. It is highly recommended that a national quality control laboratory be established to continually monitor pesticides efficacy in order to avoid overdose of pesticides application.[au

  5. Wormholes in R{sup 2}-gravity within the f(R, T) formalism

    Energy Technology Data Exchange (ETDEWEB)

    Sahoo, P.K.; Sahoo, Parbati [Birla Institute of Technology and Science-Pilani, Department of Mathematics, Hyderabad (India); Moraes, P.H.R.S. [ITA-Instituto Tecnologico de Aeronautica, Departamento de Fisica, Sao Jose dos Campos, Sao Paulo (Brazil)

    2018-01-15

    We propose, as a novelty in the literature, the modeling of wormholes within a particular case of f(R, T) gravity, namely f(R, T) = R + αR{sup 2} + λT, with R and T being the Ricci scalar and trace of the energy-momentum tensor, respectively, while α and λ are constants. Although such a functional form application can be found in the literature, those concern compact astrophysical objects, such that no wormhole analysis has been done so far. The quadratic geometric and linear material corrections of this theory render the matter content of the wormhole remarkably able to obey the energy conditions. (orig.)

  6. Existence of relativistic stars in f(R) gravity

    International Nuclear Information System (INIS)

    Upadhye, Amol; Hu, Wayne

    2009-01-01

    We refute recent claims in the literature that stars with relativistically deep potentials cannot exist in f(R) gravity. Numerical examples of stable stars, including relativistic (GM * /r * ∼0.1), constant density stars, are studied. As a star is made larger, nonlinear 'chameleon' effects screen much of the star's mass, stabilizing gravity at the stellar center. Furthermore, we show that the onset of this chameleon screening is unrelated to strong gravity. At large central pressures P>ρ/3, f(R) gravity, like general relativity, does have a maximum gravitational potential, but at a slightly smaller value: GM * /r * | max =0.345<4/9 for constant density and one choice of parameters. This difference is associated with negative central curvature R under general relativity not being accessed in the f(R) model, but does not apply to any known astrophysical object.

  7. f(R) gravity: scalar perturbations in the late Universe

    Czech Academy of Sciences Publication Activity Database

    Eingorn, M.; Novák, Jan; Zhuk, A.

    2014-01-01

    Roč. 74, č. 8 (2014), s. 3005 ISSN 1434-6044 Institutional support: RVO:67985840 Keywords : nonlinear f(R) gravity * scalar cosmological perturbations * scalaron Subject RIV: BA - General Mathematics Impact factor: 5.084, year: 2014 http://link.springer.com/article/10.1140/epjc/s10052-014-3005-1

  8. Models of f(R) cosmic acceleration that evade solar system tests

    International Nuclear Information System (INIS)

    Hu, Wayne; Sawicki, Ignacy

    2007-01-01

    We study a class of metric-variation f(R) models that accelerates the expansion without a cosmological constant and satisfies both cosmological and solar-system tests in the small-field limit of the parameter space. Solar-system tests alone place only weak bounds on these models, since the additional scalar degree of freedom is locked to the high-curvature general-relativistic prediction across more than 25 orders of magnitude in density, out through the solar corona. This agreement requires that the galactic halo be of sufficient extent to maintain the galaxy at high curvature in the presence of the low-curvature cosmological background. If the galactic halo and local environment in f(R) models do not have substantially deeper potentials than expected in ΛCDM, then cosmological field amplitudes |f R | > or approx.10 -6 will cause the galactic interior to evolve to low curvature during the acceleration epoch. Viability of large-deviation models therefore rests on the structure and evolution of the galactic halo, requiring cosmological simulations of f(R) models, and not directly on solar-system tests. Even small deviations that conservatively satisfy both galactic and solar-system constraints can still be tested by future, percent-level measurements of the linear power spectrum, while they remain undetectable to cosmological-distance measures. Although we illustrate these effects in a specific class of models, the requirements on f(R) are phrased in a nearly model-independent manner

  9. f(R) gravity cosmology in scalar degree of freedom

    International Nuclear Information System (INIS)

    Goswami, Umananda Dev; Deka, Kabita

    2014-01-01

    The models of f(R) gravity belong to an important class of modified gravity models where the late time cosmic accelerated expansion is considered as the manifestation of the large scale modification of the force of gravity. f(R) gravity models can be expressed in terms of a scalar degree of freedom by explicit redefinition of model's variable. Here we report about the study of the features of cosmological parameters and hence the cosmological evolution using the scalar degree of freedom of the f(R) = ξR n gravity model in the Friedmann-Lemaître-Robertson-Walker (FLRW) background

  10. Galactic cosmic-ray intensity to a heliocentric distance of 18 AU

    International Nuclear Information System (INIS)

    Van Allen, J.A.

    1980-01-01

    An updated report is given of observations of galactic cosmic-ray intensity to heliocentric radial distance of 8.6 and 18.4 AU with Pioneer 11 and Pioneer 10, respectively. Solar activity via the magnetic structure of the interplanetary medium continues to modulate the intensity out to the greatest distance reached thus far. During the 7 year period 1972 March to 1979 March, the galactic cosmic-ray intensity E/sub p/>80 MeV as measured by detectors on Pioneers 10 and 11 exhibited aperiodic temporal variations by about a factor of 2 and on a time scale of the order of a year and quasi-persistent cyclic variations of 26 day period and amplitude a few percent. The former are attributed to overall changes in the magnetic field structure of the heliosphere, the latter to fast-slow solar wind streams in and near the ecliptic plane and not to toward-away magnetic field sectors. The apparent heliographic latitude dependence of intensity is 0( +- 1.5)% per 10 0 in the latitude range +7 0 .7 to +15. 0 8, though it is possible that radially dependent temporal variations over the large difference in the heliocentric radial distances of the two spacecraft may make this result of limited significance. For protons of energy E/sub p/>80 MeV, there is a fairly consistent heliocentric radial gradient of +2.1( +- 0.3)% per AU integral intensity until 1978 April--May, at which time a substantial disruption of the distribution of cosmic rays in the heliosphere occurred

  11. Innovations en apprentissage numérique pour les réfugiés syriens ...

    International Development Research Centre (IDRC) Digital Library (Canada)

    Les répercussions du conflit syrien et de la conséquente crise des réfugiés syriens sur les systèmes scolaires en Jordanie et au Liban sont très lourdes. Selon les estimations, quelque 714 000 enfants syriens déplacés ne fréquentent pas l'école et environ la moitié de ce nombre est en Jordanie et au Liban. Plus de 100 ...

  12. Constraint propagation equations of the 3+1 decomposition of f(R) gravity

    International Nuclear Information System (INIS)

    Paschalidis, Vasileios; Shapiro, Stuart L; Halataei, Seyyed M H; Sawicki, Ignacy

    2011-01-01

    Theories of gravity other than general relativity (GR) can explain the observed cosmic acceleration without a cosmological constant. One such class of theories of gravity is f(R). Metric f(R) theories have been proven to be equivalent to Brans-Dicke (BD) scalar-tensor gravity without a kinetic term (ω = 0). Using this equivalence and a 3+1 decomposition of the theory, it has been shown that metric f(R) gravity admits a well-posed initial value problem. However, it has not been proven that the 3+1 evolution equations of metric f(R) gravity preserve the (Hamiltonian and momentum) constraints. In this paper, we show that this is indeed the case. In addition, we show that the mathematical form of the constraint propagation equations in BD-equilavent f(R) gravity and in f(R) gravity in both the Jordan and Einstein frames is exactly the same as in the standard ADM 3+1 decomposition of GR. Finally, we point out that current numerical relativity codes can incorporate the 3+1 evolution equations of metric f(R) gravity by modifying the stress-energy tensor and adding an additional scalar field evolution equation. We hope that this work will serve as a starting point for relativists to develop fully dynamical codes for valid f(R) models.

  13. Self-Reported Symptoms and Pesticide Use among Farm Workers in Arusha, Northern Tanzania: A Cross Sectional Study

    Directory of Open Access Journals (Sweden)

    Wilbert Bunini Manyilizu

    2017-09-01

    Full Text Available The objective of the study was to describe self-reported health symptoms, the use of personal protective gear and clothing and poor safety procedures when applying pesticides among farm workers. A total of 128 adult farm workers were interviewed using a structured questionnaire during the farming season. The commonly used pesticides included profenofos, mancozeb, chlorpyrifos, cypermethrin, deltamethrin, permethrin, lambda-cyhalothrin, endosulfan and carbosulfan. The majority (>90% of farm workers used no personal protective clothing while handling pesticides. More than one-third of farm workers ate and drank without washing their hands following pesticide handling, while a smaller number smoked or chewed gum. Wearing special boots during pesticide application was found to reduce the risk of skin rash (OR = 0.2, 95% CI: 0.06–0.66, whereas smoking when applying pesticides increased the risk of chest pain occurrence (OR = 4.0, 95% CI: 1.14–15.43, as well as forgetfulness (OR = 4.0, 95% CI: 1.30–14.02. Chewing gum and eating when applying pesticides was associated with diarrhoea (OR = 11.0, 95% CI: 1.80–6.84 and OR = 7.0, 95% CI: 1.27–3.67 respectively. The increased self-reported prevalence of post-exposure adverse health effects among farm workers was associated with poor use of personal protective clothing and poor safety practices during pesticide use and handling. These data indicate the need for improved availability and use of protective equipment, and training in crop and pest management practices to prevent risky behavioursand for safer and sustainable vegetable production.

  14. Robust approach to f(R) gravity

    International Nuclear Information System (INIS)

    Jaime, Luisa G.; Patino, Leonardo; Salgado, Marcelo

    2011-01-01

    We consider metric f(R) theories of gravity without mapping them to their scalar-tensor counterpart, but using the Ricci scalar itself as an ''extra'' degree of freedom. This approach avoids then the introduction of a scalar-field potential that might be ill defined (not single valued). In order to explicitly show the usefulness of this method, we focus on static and spherically symmetric spacetimes and deal with the recent controversy about the existence of extended relativistic objects in certain class of f(R) models.

  15. 75 FR 16105 - Dicloran; Cancellation Order for Amendment to Terminate a Use of DCNA Pesticide Registrations

    Science.gov (United States)

    2010-03-31

    ... identified in Table 1 in Unit II. in a manner inconsistent with any of the Provisions for Disposition of... for pesticide registrations listed in Table 1 in Unit II. pursuant to section 6(f)(1) of the Federal..., 2009 (74 FR 63151) Federal Register Notice of Receipt of Request from the registrant listed in Table 2...

  16. Possible antigravity regions in F(R) theory?

    Energy Technology Data Exchange (ETDEWEB)

    Bamba, Kazuharu, E-mail: bamba@kmi.nagoya-u.ac.jp [Kobayashi-Maskawa Institute for the Origin of Particles and the Universe, Nagoya University, Nagoya 464-8602 (Japan); Nojiri, Shin' ichi, E-mail: nojiri@phys.nagoya-u.ac.jp [Kobayashi-Maskawa Institute for the Origin of Particles and the Universe, Nagoya University, Nagoya 464-8602 (Japan); Department of Physics, Nagoya University, Nagoya 464-8602 (Japan); Odintsov, Sergei D., E-mail: odintsov@ieec.uab.es [Department of Physics, Nagoya University, Nagoya 464-8602 (Japan); Instituciò Catalana de Recerca i Estudis Avançats (ICREA), Barcelona (Spain); Institut de Ciencies de l' Espai (CSIC-IEEC), Campus UAB, Facultat de Ciencies, Torre C5-Par-2a pl, E-08193 Bellaterra (Barcelona) (Spain); Tomsk State Pedagogical University, Kievskaya Avenue, 60, 634061, Tomsk (Russian Federation); Sáez-Gómez, Diego, E-mail: diego.saezgomez@uct.ac.za [Astrophysics, Cosmology and Gravity Centre (ACGC) and Department of Mathematics and Applied Mathematics, University of Cape Town, Rondebosch 7701, Cape Town (South Africa); Fisika Teorikoaren eta Zientziaren Historia Saila, Zientzia eta Teknologia Fakultatea, Euskal Herriko Unibertsitatea, 644 Posta Kutxatila, 48080 Bilbao (Spain)

    2014-03-07

    We construct an F(R) gravity theory corresponding to the Weyl invariant two scalar field theory. We investigate whether such F(R) gravity can have the antigravity regions where the Weyl curvature invariant does not diverge at the Big Bang and Big Crunch singularities. It is revealed that the divergence cannot be evaded completely but can be much milder than that in the original Weyl invariant two scalar field theory.

  17. Holographic dark energy and f(R) gravity

    Energy Technology Data Exchange (ETDEWEB)

    Aghamohammadi, A [Faculty of Science, Islamic Azad University of Sanandaj, Sanandaj (Iran, Islamic Republic of); Saaidi, Kh, E-mail: ksaaidi@uok.ac.ir, E-mail: agha35484@yahoo.com [Department of Physics, Faculty of Science, University of Kurdistan, Sanandaj (Iran, Islamic Republic of)

    2011-02-15

    We investigate the corresponding relation between f(R) gravity and holographic dark energy. We introduce a type of energy density from f(R) that has the same role as holographic dark energy. We obtain the differential equation that specifies the evolution of the introduced energy density parameter based on a varying gravitational constant. We discover the relation for the equation of state parameter for low redshifts that contains varying G correction.

  18. Possible antigravity regions in F(R) theory?

    Science.gov (United States)

    Bamba, Kazuharu; Nojiri, Shin'ichi; Odintsov, Sergei D.; Sáez-Gómez, Diego

    2014-03-01

    We construct an F(R) gravity theory corresponding to the Weyl invariant two scalar field theory. We investigate whether such F(R) gravity can have the antigravity regions where the Weyl curvature invariant does not diverge at the Big Bang and Big Crunch singularities. It is revealed that the divergence cannot be evaded completely but can be much milder than that in the original Weyl invariant two scalar field theory.

  19. Possible antigravity regions in F(R) theory?

    International Nuclear Information System (INIS)

    Bamba, Kazuharu; Nojiri, Shin'ichi; Odintsov, Sergei D.; Sáez-Gómez, Diego

    2014-01-01

    We construct an F(R) gravity theory corresponding to the Weyl invariant two scalar field theory. We investigate whether such F(R) gravity can have the antigravity regions where the Weyl curvature invariant does not diverge at the Big Bang and Big Crunch singularities. It is revealed that the divergence cannot be evaded completely but can be much milder than that in the original Weyl invariant two scalar field theory.

  20. f(R) constant-roll inflation

    Energy Technology Data Exchange (ETDEWEB)

    Motohashi, Hayato [Universidad de Valencia-CSIC, Instituto de Fisica Corpuscular (IFIC), Valencia (Spain); Starobinsky, Alexei A. [L.D. Landau Institute for Theoretical Physics, RAS, Moscow (Russian Federation); National Research University Higher School of Economics, Moscow (Russian Federation)

    2017-08-15

    The previously introduced class of two-parametric phenomenological inflationary models in general relativity in which the slow-roll assumption is replaced by the more general, constant-roll condition is generalized to the case of f(R) gravity. A simple constant-roll condition is defined in the original Jordan frame, and exact expressions for a scalaron potential in the Einstein frame, for a function f(R) (in the parametric form) and for inflationary dynamics are obtained. The region of the model parameters permitted by the latest observational constraints on the scalar spectral index and the tensor-to-scalar ratio of primordial metric perturbations generated during inflation is determined. (orig.)

  1. IMS Learning Design : la flexibilité pédagogique au service des besoins de la e-formation

    NARCIS (Netherlands)

    Burgos, Daniel; Arnaud, Michel; Neuhauser, Patrick; Koper, Rob

    2005-01-01

    Burgos, D., Arnaud, M., Neuhauser, P., Koper, R. IMS Learning Design : la flexibilité pédagogique au service des besoins de la e-formation. In La Revue de l'EPI. France: L'association Enseignement Public et Informatique [http://www.epi.asso.fr/revue/articsom.htm]. Available at

  2. Side effects of different pesticides used in citrus on the adult stage of the parasitoid Aphytis melinus DeBach (Hymenoptera Aphelinidae and its progeny

    Directory of Open Access Journals (Sweden)

    J. E. Gonzalez-Zamora

    2013-05-01

    Full Text Available Twelve pesticides commonly used in citrus in Spain were tested on adults of Aphytis melinus DeBach to determine their effects on parasitoid survival and fecundity, and the duration of the residue of each pesticide. Six of these pesticides were found to be harmless to moderately harmful to this parasitoid in a laboratory assay in closed Petri dishes: spinosad (bait formulation, azadirachtin, fenbutatin, fosetyl-Al, copper oxichloride, and mancozeb, with their scores on the reduction of beneficial capacity (RBC index being between 21.4 and 94.6% after one week. The other six pesticides classified as harmful were tested on citrus plants to study their persistence over time under greenhouse conditions: Pirimicarb, pyriproxifen, paraffinic oil, abamectin, chlorpyrifos, and lambda-cyhalothrin. Most of these products reduced their negative effect on adults of A. melinus between one and six weeks after treatment, although lambda-cyhalothrin was still harmful to parasitoids 11 weeks after application. This information can help growers and consultants to make decisions about pesticide selection and application timing in citrus in order to support IPM implementation when A. melinus is present.

  3. 77 FR 1656 - Proposed Establishment of Restricted Areas R-5402, R-5403A, R-5403B, R-5403C, R-5403D, R-5403E, R...

    Science.gov (United States)

    2012-01-11

    ...-0117; Airspace Docket No. 09-AGL-31] RIN 2120-AI92 Proposed Establishment of Restricted Areas R-5402, R-5403A, R- 5403B, R-5403C, R-5403D, R-5403E, R-5403F; Devils Lake, ND AGENCY: Federal Aviation... Restricted Areas R-5402, R-5403A, R-5403B, R- 5403C, R-5403D, R-5403E, R-5403F; Devils Lake, ND (76 FR 72869...

  4. 77 FR 12295 - Pesticide Products; Registration Applications

    Science.gov (United States)

    2012-02-29

    ........ Pollution Prevention Division (7511P), Office of Pesticide Programs, Environmental Protection Agency, 1200... 9); citrus fruits (crop group 10-10); pome fruits (crop group 11-10); stone fruits (crop group 12); berries and small fruits, bushberries (crop subgroup 13-07B); tree nuts (crop group 14); oilseeds (crop...

  5. Accouchement gémellaire en milieu africain: une analyse de 10 ans dans le district de Bamako au Mali

    Science.gov (United States)

    Théra, Tiounkani; Mounkoro, Niani; Traore, Soumana Omar; Hamidou, Albachar; Traore, Mamadou; Doumbia, Saleck; Tall, Saoudatou; Kouma, Aminata

    2018-01-01

    Introduction Le but de cette étude était de déterminer les facteurs influençant le pronostic de l'accouchement du deuxième jumeau. Méthodes L'étude était rétrospective et a porté sur tous les cas d'accouchements gémellaires enregistrés à la maternité du Centre de Santé de Référence de la commune V du District de Bamako du 1erJanvier 2007 au 31 Décembre 2016 soit sur une période de dix ans. Résultats Nous avons enregistré 34.899 accouchements dont 1374 accouchements gémellaires soit une fréquence de 2,54%; près de 15% étaient des primipares; 39,16% étaient référées; 69,10% et 15,5% autres sans aucun suivi prénatal. Les facteurs influençant négativement pronostic du deuxième jumeau étaient: un délai ≥ 15minutes entre les jumeaux, le recours tardif à la césarienne, la non qualification de l'accoucheur, la grossesse monochoréale, le faible poids de naissance. Par contre la parité, la réalisation de manœuvres obstétricales n'avaient aucune influence sur le pronostic du deuxième jumeau. Conclusion Le pronostic du deuxième jumeau est fortement influencé par un délai de naissance de plus de 15 minutes entre les jumeaux, les autres facteurs agissant comme des cofacteurs. PMID:29662606

  6. STM study of C60F18 high dipole moment molecules on Au(111)

    Science.gov (United States)

    Bairagi, K.; Bellec, A.; Chumakov, R. G.; Menshikov, K. A.; Lagoute, J.; Chacon, C.; Girard, Y.; Rousset, S.; Repain, V.; Lebedev, A. M.; Sukhanov, L. P.; Svechnikov, N. Yu.; Stankevich, V. G.

    2015-11-01

    Scanning tunneling microscopy and spectroscopy studies of C60F18 molecules deposited on Au(111) are reported and compared to C60 molecules both at liquid helium temperature and room temperature (RT). Whereas adsorption and electronic properties of C60F18 single molecules were studied at low temperature (LT), self-assemblies were investigated at RT. In both cases, the fluorine atoms of the C60F18 molecules are pointed towards the surface. Individual C60F18 molecules on Au(111) have a HOMO-LUMO gap of 2.9 eV. The self-assembled islands exhibit a close-packed hexagonal lattice with amorphous borders. The comparison with C60 molecules clearly demonstrates the influence of the C60F18 electric dipole moment (EDM) on the electronic properties of single molecules and on the thermodynamics of self-assembled islands. Besides, the apparent height value of a separate molecule increases in a self-assembly environment as a result of a depolarization phenomenon.

  7. Stellar configurations in f(R) theories of gravity

    International Nuclear Information System (INIS)

    Henttunen, K.; Multamaeki, T.; Vilja, I.

    2008-01-01

    We study stellar configurations and the space-time around them in metric f(R) theories of gravity. In particular, we focus on the polytropic model of the Sun in two specific cases: the f(R)=R-μ 4 /R model and a model with a stabilizing higher order term f(R)=R-μ 4 /R+βR 3 /(3μ 4 ). We show how the stellar configuration in the f(R) theory can, by appropriate initial conditions, be selected to be equal to that described by the Lane-Emden equation and how a simple scaling relation exists between the solutions. We also derive the correct solution analytically near the center of the star in f(R) theory. Previous analytical and numerical results are confirmed, indicating that the space-time around the Sun is incompatible with solar system constraints in the f(R)=R-μ 4 /R model. Numerical work shows that stellar configurations, with a regular metric at the center, lead to γ PPN ≅1/2 outside the star for both models, i.e., the Schwarzschild-de Sitter space-time is not the correct vacuum solution for such configurations. This shows that even when one fine-tunes the initial conditions inside a star such that the mass of the effective scalar in the equivalent scalar-tensor theory is large, γ PPN is still 1/2 outside the star. Conversely, by selecting the Schwarzschild-de Sitter metric as the outside solution, or equivalently setting the mass of the effective scalar to be large outside the star, we find that the stellar configuration is unchanged but the metric is irregular at the center. The possibility of constructing a f(R) theory compatible with the solar system experiments and possible new constraints arising from the radius-mass relation of stellar objects is discussed

  8. Cosmological reconstruction of realistic modified F(R) gravities

    International Nuclear Information System (INIS)

    Nojiri, Shin'ichi; Odintsov, Sergei D.; Saez-Gomez, Diego

    2009-01-01

    The cosmological reconstruction scheme for modified F(R) gravity is developed in terms of e-folding (or, redshift). It is demonstrated how any FRW cosmology may emerge from specific F(R) theory. The specific examples of well-known cosmological evolution are reconstructed, including ΛCDM cosmology, deceleration with transition to phantom superacceleration era which may develop singularity or be transient. The application of this scheme to viable F(R) gravities unifying inflation with dark energy era is proposed. The additional reconstruction of such models leads to non-leading gravitational correction mainly relevant at the early/late universe and helping to pass the cosmological bounds (if necessary). It is also shown how cosmological reconstruction scheme may be generalized in the presence of scalar field.

  9. Les réseaux d’investissement dans le thermalisme au XIXe siècle en France

    Directory of Open Access Journals (Sweden)

    Jérôme Penez

    2004-03-01

    Full Text Available Le XIXe siècle est le siècle de la « fièvre thermale » en France. Pour permettre cet extraordinaire développement, l’argent est nécessaire. La station thermale apparaît comme un eldorado où la fortune est à portée de la main. Cette fortune n’est pourtant pas si facile à obtenir, la gestion thermale est ingrate, et les centaines de villes d’eaux françaises ne peuvent pas toutes obtenir un succès comparable à celui de Vichy ou d’Aix-les-Bains. Le thermalisme français est diversité, diversité dans les réussites, diversité dans les types de gestion (de la gestion étatique à la gestion privée, diversité dans sa fréquentation, diversité dans ses périodes de développement, diversité dans les moyens de son financement. Etudier l’importance ou au contraire la rareté des réseaux d’investissement dans le thermalisme permet de lever une partie du voile de l’histoire encore bien mystérieuse des villes d’eaux françaises.

  10. Hossegor (Landes, une station au cœur des réseaux de villégiature

    Directory of Open Access Journals (Sweden)

    Claude Laroche

    2012-04-01

    Full Text Available La station balnéaire d’Hossegor (Landes a connu son véritable lancement à partir de 1923, alors que le site avait été révélé quelques années auparavant, au tout début du siècle, par les séjours d’un groupe d’écrivains, parmi lesquels J.-H. Rosny jeune (1859-1948, Maxime Leroy (1873-1957 et Paul Margueritte (1860-1918. A partir de cet exemple landais, l’exposé tend à démontrer combien la création d’une station balnéaire, de sa découverte à sa promotion en passant par sa révélation au monde extérieur, doit au jeu des réseaux de tous ordres. Contemplatifs, les premiers occupants d’Hossegor n’auront pourtant de cesse de faire connaître le lieu en s’appuyant pour cela sur un puissant réseau de relations, notamment journalistiques. Actif, le promoteur de la station, Alfred Eluère (1893-1985, ne pourra assurer son succès qu’en utilisant le cercle relationnel très ouvert et très efficace que ses multiples activités – immobilières, mais aussi sportives et politiques – l’auront amené à constituer. Sa venue à Hossegor n’est d’ailleurs rien d’autre que le résultat de circonstances permises par le jeu de tout un tissu de relations au milieu duquel on trouve entre autres Maurice Martin (1861-1941, personnage haut en couleur, journaliste cultivant lui aussi au plus haut point le réseau des connaissances. Une fois la station lancée, la promotion immobilière saura jouer de tous les ressorts offerts par ces différents réseaux pour amener sur place la clientèle : de la propagande journalistique au réseau des agences immobilières en passant par le propre réseau relationnel d’Eluère. Parallèlement, le réseau des architectes sera lui aussi particulièrement actif, que ce soit pour s’attirer la commande ou pour propager la formule régionaliste. En conclusion, à côté de l’histoire officielle des stations balnéaires – une histoire au premier degré que les archives documentent

  11. Substrate-bound tyrosinase electrode using gold nanoparticles anchored to pyrroloquinoline quinone for a pesticide biosensor

    Energy Technology Data Exchange (ETDEWEB)

    Kim, G.Y.; Kang, M.S.; Shim, J.; Moon, S.H. [Gwangju Inst. of Science and Technology (Korea, Republic of). Dept. of Environmental Science and Engineering

    2008-07-01

    Enzyme electrodes are now being considered for use in the detection of pesticides. However, the electrodes do not have the sensitivity to detect low concentration pesticides, and external substrates are needed to measure changes in enzyme activity. This study discussed a chemical species designed to mimic a substrate in the preparation of a tyrosinase (TYR) electrode for use without substrate standard solutions. Pyrroloquinolone quinone (PQQ) was integrated within the tyrosinase electrode and used as an assimilated substrate for measuring the pesticide. Gold (Au) nanoparticles were also used to detect low concentration pesticides. The TYR was immobilized on the PQQ-anchored Au nanoparticles by a covalent bond. The tethered PQQ was then reduced by obtaining 2-electrons from the electrode. The study showed that the substrate-bound enzyme electrode can be used to detect pesticide without a substrate standard solution through the immobilization of the enzyme and the substrate on the Au nanoparticles.

  12. Chelles (Seine-et-Marne). 10-18, rue Sainte-Bathilde.

    OpenAIRE

    Paccard, Nathalie

    2018-01-01

    Après un diagnostic réalisé en 2011, une fouille a été menée durant l’été 2013 sur une emprise de près de 2 000 m2, au sud du centre historique de Chelles. Ce secteur, qui est la zone d’investigation la plus méridionale du bourg médiéval, est encore très mal connu. Il s’agit au xviiie s. d’un espace dévolu au jardin de l’abbaye. La fouille a porté essentiellement sur une aire empierrée, reconnue sur près de 1 000 m2 au sein de l’espace décapé, mais qui se poursuit au-delà des limites d’empris...

  13. Cosmology of Horava-Lifshitz f(R) gravity

    International Nuclear Information System (INIS)

    Chakrabarti, Sayan K.; Sen, Anjan A.

    2011-08-01

    We discuss the cosmology of recently proposed Horava-Lifshitz f(R) gravity. In particular, we derive the modified Hubble equation that reduces to the standard HL gravity case in appropriate limit. We show how the bounce solutions in this theory are modified due to nonlinear effect of f(R) gravity. In addition we find that the solutions exist when the Universe can make turn around for large scale-factor. Therefore, in principle, the Universe in this set-up can show cyclic behavior. (orig.)

  14. Cosmology of Horava-Lifshitz f(R) gravity

    Energy Technology Data Exchange (ETDEWEB)

    Chakrabarti, Sayan K. [Univ. Tecnica de Lisboa (Portugal). Inst. Superior Tecnico; Dutta, Koushik [Deutsches Elektronen-Synchrotron (DESY), Hamburg (Germany); Sen, Anjan A. [Centre of Theoretical Physics, Jamia Millia Islamia, New Dehli (India)

    2011-08-15

    We discuss the cosmology of recently proposed Horava-Lifshitz f(R) gravity. In particular, we derive the modified Hubble equation that reduces to the standard HL gravity case in appropriate limit. We show how the bounce solutions in this theory are modified due to nonlinear effect of f(R) gravity. In addition we find that the solutions exist when the Universe can make turn around for large scale-factor. Therefore, in principle, the Universe in this set-up can show cyclic behavior. (orig.)

  15. 75 FR 34117 - Notice of Receipt of Requests to Voluntarily Cancel Certain Pesticide Registrations

    Science.gov (United States)

    2010-06-16

    ... Agricultural Miticide CA010016 Ridomil Gold EC D-Alanine,N-(2,6- dimethylphenyl)-N- (methoxyacetyl)- methyl... Gold SL D-Alanine,N-(2,6- dimethylphenyl)-N- (methoxyacetyl)- methyl ester CA880005 Dormant Flowable... OR010030 Direx 80DF Diuron OR010033 Mankocide MancozebCopper hydroxide OR030022 Omite-6E Propargite...

  16. Matrix of occupational exposures to carcinogenic agents and pesticides in Costa Rica

    International Nuclear Information System (INIS)

    Chaves, Jorge; Partanen, Timo; Wesseling, Catharina; Chaverri, Fabio; Monge, Patricia; Ruepert, Clemens; Guardado, Jorge; Aragon, Aurora; Kauppinen, Timo

    2004-01-01

    The European data system CAREX converts national numbers of workers in 55 sectors and estimated proportions of workers exposed to carcinogenic agents into numbers of workers exposed to each agent. CAREX is applied and modified in Costa Rica (TICAREX) for the first time outside Europe. 27 carcinogenic agents and 7 groups of pesticides were included. Numbers of exposed were estimated separately for men and women. The most frequent agents in the 1.3 million labor force of Costa Rica were solar radiation (333,000 workers); diesel engine emissions (278,000); paraquat and diquat (175,000); environmental tobacco smoke (71,000); chromium (VI) compounds (55,000); benzene (52,000); mancozeb, maneb and zineb (49,000); chlorothalonil (38,000); wood dust (32,000); silica dust (27,000); benomyl (19,000); lead and its inorganic compounds (19,000); tetrachloroethylene (18,000); and polycyclic aromatic hydrocarbons (17,000). Owing to the different occupational distribution between the genders, formaldehyde, radon and methylene chloride were more frequent than pesticides, chromium (VI), wood dust, and silica dust in women. Agriculture, construction, personal and domestic services, land and water transport and allied services, pottery and similar industries, manufacture of wood products, mining, forestry, fishing, manufacture of electric products, and bars and restaurants were sectors with frequent exposures. Substantial reduction of occupational and environmental exposures to these agents would improve considerably public and occupational health. Reduction of occupational exposures is usually also followed by improvement of environmental quality. Monitoring of exposures and health of workers and the general public is essential in the control of environmental contamination and human exposures. This report presents details of the exposures matrix, which is the basis of TICAREX. (author) [es

  17. 48 CFR 53.301-18 - SF 18 (Rev. 6/95), Request for Quotations.

    Science.gov (United States)

    2010-10-01

    ... 48 Federal Acquisition Regulations System 2 2010-10-01 2010-10-01 false SF 18 (Rev. 6/95), Request for Quotations. 53.301-18 Section 53.301-18 Federal Acquisition Regulations System FEDERAL ACQUISITION... for Quotations. EC01MY91.002 [60 FR 34763, July 3, 1995] ...

  18. Galaxy-galaxy weak gravitational lensing in f(R) gravity

    Science.gov (United States)

    Li, Baojiu; Shirasaki, Masato

    2018-03-01

    We present an analysis of galaxy-galaxy weak gravitational lensing (GGL) in chameleon f(R) gravity - a leading candidate of non-standard gravity models. For the analysis, we have created mock galaxy catalogues based on dark matter haloes from two sets of numerical simulations, using a halo occupation distribution (HOD) prescription which allows a redshift dependence of galaxy number density. To make a fairer comparison between the f(R) and Λ cold dark matter (ΛCDM) models, their HOD parameters are tuned so that the galaxy two-point correlation functions in real space (and therefore the projected two-point correlation functions) match. While the f(R) model predicts an enhancement of the convergence power spectrum by up to ˜ 30 per cent compared to the standard ΛCDM model with the same parameters, the maximum enhancement of GGL is only half as large and less than 5 per cent on separations above ˜1-2 h-1 Mpc, because the latter is a cross-correlation of shear (or matter, which is more strongly affected by modified gravity) and galaxy (which is weakly affected given the good match between galaxy autocorrelations in the two models) fields. We also study the possibility of reconstructing the matter power spectrum by combination of GGL and galaxy clustering in f(R) gravity. We find that the galaxy-matter cross-correlation coefficient remains at unity down to ˜2-3 h-1 Mpc at relevant redshifts even in f(R) gravity, indicating joint analysis of GGL and galaxy clustering can be a powerful probe of matter density fluctuations in chameleon gravity. The scale dependence of the model differences in their predictions of GGL can potentially allows us to break the degeneracy between f(R) gravity and other cosmological parameters such as Ωm and σ8.

  19. Prise en charge de l'hematurie au chu Sylvanus Olympio de Lome ...

    African Journals Online (AJOL)

    Une transfusion sanguine avait été réalisée dans 64,8% des cas et nous avions enregistré 4 cas de décès. Conclusion : Les hématuries sont relativement fréquentes au Togo et souvent de causes tumorales. Elles nécessitent une prise en charge précoce pour un meilleur pronostic. Mots clés : hématurie, épidémiologie, ...

  20. 75 FR 22256 - Difenoconazole Pesticide Tolerances

    Science.gov (United States)

    2010-04-28

    ...; fruit, citrus, group 10; grape; grape, raisin; nut, tree, group 14; onion, bulb, subgroup 3-07A; onion... entities may include, but are not limited to those engaged in the following activities: Crop production (NAICS code 111). Animal production (NAICS code 112). Food manufacturing (NAICS code 311). Pesticide...

  1. Late-time cosmological approach in mimetic f(R, T) gravity

    Energy Technology Data Exchange (ETDEWEB)

    Baffou, E.H. [Institut de Mathematiques et de Sciences Physiques (IMSP), Porto-Novo (Benin); Houndjo, M.J.S. [Institut de Mathematiques et de Sciences Physiques (IMSP), Porto-Novo (Benin); Faculte des Sciences et Techniques de Natitingou, Natitingou (Benin); Hamani-Daouda, M. [Universite de Niamey, Departement de Physique, Niamey (Niger); Alvarenga, F.G. [Universidade Federal do Espirito Santo, Departamento de Engenharia e Ciencias Naturais, CEUNES, Sao Mateus, ES (Brazil)

    2017-10-15

    In this paper, we investigate the late-time cosmic acceleration in mimetic f(R, T) gravity with the Lagrange multiplier and potential in a Universe containing, besides radiation and dark energy, a self-interacting (collisional) matter. We obtain through the modified Friedmann equations the main equation that can describe the cosmological evolution. Then, with several models from Q(z) and the well-known particular model f(R, T), we perform an analysis of the late-time evolution. We examine the behavior of the Hubble parameter, the dark energy equation of state and the total effective equation of state and in each case we compare the resulting picture with the non-collisional matter (assumed as dust) and also with the collisional matter in mimetic f(R, T) gravity. The results obtained are in good agreement with the observational data and show that in the presence of the collisional matter the dark energy oscillations in mimetic f(R, T) gravity can be damped. (orig.)

  2. Generation of spherically symmetric metrics in f(R) gravity

    Energy Technology Data Exchange (ETDEWEB)

    Amirabi, Z.; Halilsoy, M.; Mazharimousavi, S.H. [Eastern Mediterranean University, Department of Physics, Gazimagusa (Turkey)

    2016-06-15

    In D-dimensional spherically symmetric f(R) gravity there are three unknown functions to be determined from the fourth order differential equations. It is shown that the system remarkably may be integrated to relate two functions through the third one to provide a reduction to second order equations accompanied with a large class of potential solutions. The third function, which acts as the generator of the process, is F(R) = (df(R))/(dR). We recall that our generating function has been employed as a scalar field with an accompanying self-interacting potential previously, which is entirely different from our approach. Reduction of f(R) theory into a system of equations seems to be efficient enough to generate a solution corresponding to each generating function. As particular examples, besides the known ones, we obtain new black hole solutions in any dimension D. We further extend our analysis to cover non-zero energy-momentum tensors. Global monopole and Maxwell sources are given as examples. (orig.)

  3. Rational approximations of f(R) cosmography through Pad'e polynomials

    Science.gov (United States)

    Capozziello, Salvatore; D'Agostino, Rocco; Luongo, Orlando

    2018-05-01

    We consider high-redshift f(R) cosmography adopting the technique of polynomial reconstruction. In lieu of considering Taylor treatments, which turn out to be non-predictive as soon as z>1, we take into account the Pad&apose rational approximations which consist in performing expansions converging at high redshift domains. Particularly, our strategy is to reconstruct f(z) functions first, assuming the Ricci scalar to be invertible with respect to the redshift z. Having the so-obtained f(z) functions, we invert them and we easily obtain the corresponding f(R) terms. We minimize error propagation, assuming no errors upon redshift data. The treatment we follow naturally leads to evaluating curvature pressure, density and equation of state, characterizing the universe evolution at redshift much higher than standard cosmographic approaches. We therefore match these outcomes with small redshift constraints got by framing the f(R) cosmology through Taylor series around 0zsimeq . This gives rise to a calibration procedure with small redshift that enables the definitions of polynomial approximations up to zsimeq 10. Last but not least, we show discrepancies with the standard cosmological model which go towards an extension of the ΛCDM paradigm, indicating an effective dark energy term evolving in time. We finally describe the evolution of our effective dark energy term by means of basic techniques of data mining.

  4. F(R Gravity’s Rainbow and Its Einstein Counterpart

    Directory of Open Access Journals (Sweden)

    S. H. Hendi

    2016-01-01

    Full Text Available Motivated by UV completion of general relativity with a modification of a geometry at high energy scale, it is expected to have an energy dependent geometry. In this paper, we introduce charged black hole solutions with power Maxwell invariant source in the context of gravity’s rainbow. In addition, we investigate two classes of F(R gravity’s rainbow solutions. At first, we study energy dependent F(R gravity without energy-momentum tensor, and then we obtain F(R gravity’s rainbow in the presence of conformally invariant Maxwell source. We study geometrical properties of the mentioned solutions and compare their results. We also give some related comments regarding thermodynamical behavior of the obtained solutions and discuss thermal stability of the solutions.

  5. On the rumors about the silent spring: review of the scientific evidence linking occupational and environmental pesticide exposure to endocrine disruption health effects

    Directory of Open Access Journals (Sweden)

    Cocco Pierluigi

    2002-01-01

    Full Text Available Occupational exposure to some pesticides, and particularly DBCP and chlordecone, may adversely affect male fertility. However, apart from the therapeutic use of diethylstilbestrol, the threat to human reproduction posed by "endocrine disrupting" environmental contaminants has not been supported by epidemiological evidence thus far. As it concerns other endocrine effects described in experimental animals, only thyroid inhibition following occupational exposure to amitrole and mancozeb has been confirmed in humans. Cancer of the breast, endometrium, ovary, prostate, testis, and thyroid are hormone-dependent, which fostered research on the potential risk associated with occupational and environmental exposure to the so-called endocrine-disrupting pesticides. The most recent studies have ruled out the hypothesis of DDT derivatives as responsible for excess risks of cancer of the reproductive organs. Still, we cannot exclude a role for high level exposure to o,p'-DDE, particularly in post-menopausal ER+ breast cancer. On the other hand, other organochlorine pesticides and triazine herbicides require further investigation for a possible etiologic role in some hormone-dependent cancers.

  6. Exploring the liminality: properties of haloes and subhaloes in borderline f(R) gravity

    Science.gov (United States)

    Shi, Difu; Li, Baojiu; Han, Jiaxin; Gao, Liang; Hellwing, Wojciech A.

    2015-09-01

    We investigate the properties of dark matter haloes and subhaloes in an f(R) gravity model with |fR0| = 10-6, using a very-high-resolution N-body simulation. The model is a borderline between being cosmologically interesting and yet still consistent with current data. We find that the halo mass function in this model has a maximum 20 per cent enhancement compared with the Λ-cold-dark-matter (ΛCDM) predictions between z = 1 and 0. Because of the chameleon mechanism which screens the deviation from standard gravity in dense environments, haloes more massive than 1013 h-1 M⊙ in this f(R) model have very similar properties to haloes of similar mass in ΛCDM, while less massive haloes, such as that of the Milky Way, can have steeper inner density profiles and higher velocity dispersions due to their weaker screening. The halo concentration is remarkably enhanced for low-mass haloes in this model due to a deepening of the total gravitational potential. Contrary to the naive expectation, the halo formation time zf is later for low-mass haloes in this model, a consequence of these haloes growing faster than their counterparts in ΛCDM at late times and the definition of zf. Subhaloes, especially those less massive than 1011 h-1 M⊙, are substantially more abundant in this f(R) model for host haloes less massive than 1013 h-1 M⊙. We discuss the implications of these results for the Milky Way satellite abundance problem. Although the overall halo and subhalo properties in this borderline f(R) model are close to their ΛCDM predictions, our results suggest that studies of the Local Group and astrophysical systems, aided by high-resolution simulations, can be valuable for further tests of it.

  7. Defects induced by swift heavy ions in the 18R martensite of Cu-Zn-Al alloy

    International Nuclear Information System (INIS)

    Zelaya, Eugenia; Tolley, Alfredo; Condo, Adriana; Lovey, Francisco; Schumacher, G

    2003-01-01

    The swift heavy ion incidence over the surface of a given material produces a strong energy deposition in a nanometric scale.Swift heavy ions, of the order of one thousand of MeV, deposit their energy as electronic excitations.This highly localized deposition can induce metastable transformations within the material. For example, in martensitic NiTi alloys irradiated with swift heavy ions, it has been observed changes on the martensitic transformation temperature and amorphous areas induced by the irradiation.In this work, the effects produced by swift heavy ions on the martensitic 18R structure of Cu-Zn-Al alloy (Cu - 12.17 Zn - 17.92 Al, in %at) were analyzed.Crystalline samples were irradiated in a direction close to the [2 1 0] of 18R with Xe + 230 MeV, Au + of 350 MeV and Kr + of 200 MeV ion beams.Defects of the order of nanometers induced by the irradiation were observed by transmission electron microscopy (TEM) and high resolution electron microscopy (HREM).It was also observed, that the average size of the irradiation defects induced by Au + ion is larger than those induced by Xe + and Kr + ions.In this case, no relationship between the observed defects and the energy deposition was found in the 23 keV/nn to 48 keV/nn range

  8. Compatibilidade de Dicyma pulvinata com defensivos agrícolas e eficiência do biocontrole do mal-das-folhas da seringueira em campo Compatibility of Dicyma pulvinata with pesticides and biocontrol efficiency of South American leaf blight of rubber tree under field conditions

    Directory of Open Access Journals (Sweden)

    Débora Ferreira Melo

    2008-02-01

    Full Text Available O objetivo deste trabalho foi avaliar quatro isolados do fungo antagonista Dicyma pulvinata quanto à compatibilidade com defensivos agrícolas e adjuvantes, e a eficiência desses isolados no controle do mal-das-folhas (Microcyclus ulei da seringueira (Hevea sp. em campo. A compatibilidade dos isolados com defensivos e adjuvantes foi avaliada com base no crescimento micelial e na esporulação do fungo, em testes conduzidos in vitro. Para avaliação da eficiência do antagonista contra M. ulei, em campo, os quatros isolados do antagonista foram comparados ao controle exercido pelo tratamento com os fungicidas propiconazol + mancozeb. Os ensaios conduzidos em laboratório indicaram a incompatibilidade de D. pulvinata com os fungicidas benomyl, carbendazim, mancozeb, propiconazol e, ainda, com o inseticida acaricida endosulfan. Dois dos adjuvantes testados (Tween 20 e Tween 80 não afetaram o desenvolvimento do fungo. Foi comprovada a ação do antagonista D. pulvinata sobre M. ulei, em campo, com destaque para os isolados CEN 62 e CEN 93, que apresentaram eficiência de controle semelhante ao tratamento fungicida padrão.The objective of this work was to evaluate four isolates of the antagonist fungus Dicyma pulvinata in terms of its compatibility with chemical pesticides and adjuvants products, and the efficiency of these isolates as biocontrol agent against South American leaf blight (Microcyclus ulei of rubber tree (Hevea sp. under field conditions. Isolates compatibility with chemical pesticides and adjuvants was evaluated on mycelial growth and fungus sporulation in vitro. To assess the efficiency of the antagonist against M. ulei under field conditions, the four isolates were compared to the control by the fungicide mixture propiconazol + mancozeb. The assays showed incompatibility of the antagonistic fungus with the fungicides benomyl, carbendazim, mancozeb, propiconazol, besides the insecticide-acaricide endosulfan. Two of the adjuvants

  9. Comparison of questionnaire-based estimation of pesticide residue intake from fruits and vegetables with urinary concentrations of pesticide biomarkers.

    Science.gov (United States)

    Chiu, Yu-Han; Williams, Paige L; Mínguez-Alarcón, Lidia; Gillman, Matthew; Sun, Qi; Ospina, Maria; Calafat, Antonia M; Hauser, Russ; Chavarro, Jorge E

    2018-01-01

    We developed a pesticide residue burden score (PRBS) based on a food frequency questionnaire and surveillance data on food pesticide residues to characterize dietary exposure over the past year. In the present study, we evaluated the association of the PRBS with urinary concentrations of pesticide biomarkers. Fruit and vegetable (FV) intake was classified as having high (PRBS≥4) or low (PRBSEARTH study. Two urine samples per man were analyzed for seven biomarkers of organophosphate and pyrethroid insecticides, and the herbicide 2,4-dichlorophenoxyacetic acid. We used generalized estimating equations to analyze the association of the PRBS with urinary concentrations of pesticide biomarkers. Urinary concentrations of pesticide biomarkers were positively related to high pesticide FV intake but inversely related to low pesticide FV intake. The molar sum of urinary concentrations of pesticide biomarkers was 21% (95% confidence interval (CI): 2%, 44%) higher for each one serving/day increase in high pesticide FV intake, and 10% (95% CI: 1%, 18%) lower for each one serving/day increase in low pesticide FV intake. Furthermore, intake of high pesticide FVs positively related to most individual urinary biomarkers. Our findings support the usefulness of the PRBS approach to characterize dietary exposure to select pesticides.

  10. The holographic bound in the scalar-tensor and f(R) gravities

    International Nuclear Information System (INIS)

    Firouzjaee, J.T.

    2013-01-01

    The holographic bound has been extended to the different theory of gravities such as scalar-tensor gravity and f(R) gravity according to the Noether charge definition of the entropy for a black hole surface. We have introduced some popular examples of the flat FRW cosmology in order to investigate holographic bound in scalar-tensor and f(R) gravity. Using the holographic bound, we put an additional constraint on scalar-tensor gravity and the f(R) gravity parameters. We also discuss the transformation from Jordan frame to Einstein frame. (orig.)

  11. Au 38 (SPh) 24 : Au 38 Protected with Aromatic Thiolate Ligands

    Energy Technology Data Exchange (ETDEWEB)

    Rambukwella, Milan; Burrage, Shayna; Neubrander, Marie; Baseggio, Oscar; Aprà, Edoardo; Stener, Mauro; Fortunelli, Alessandro; Dass, Amala

    2017-03-21

    Au38(SR)24 is one of the most extensively investigated gold nanomolecules along with Au25(SR)18 and Au144(SR)60. However, so far it has only been prepared using aliphatic-like ligands, where R = –SC6H13, -SC12H25 and –SCH2CH2Ph. Au38(SCH2CH2Ph)24 when reacted with HSPh undergoes core-size conversion to Au36(SPh)24, and existing literature suggest that Au38(SPh)24 cannot be synthesized. Here, contrary to prevailing knowledge, we demonstrate that Au38(SPh)24 can be prepared if the ligand exchanged conditions are optimized, without any formation of Au36(SPh)24. Conclusive evidence is presented in the form of MALDI-MS, ESI-MS characterization, and optical spectra of Au38(SPh)24 in a solid glass form showing distinct differences from that of Au38(S-aliphatic)24. Theoretical analysis confirms experimental assignment of the optical spectrum and shows that the stability of Au38(SPh)24 is comparable to that of its aliphatic analogues, but results from different physical origins, with a significant component of ligand-ligand attractive interactions.

  12. De nouveaux mécanismes de résilience : rapport interactif au sujet ...

    International Development Research Centre (IDRC) Digital Library (Canada)

    13 nov. 2012 ... On y trouve de nombreux liens vers des ressources relatives au programme et aux projets, ainsi que des pistes pour explorer plus en profondeur les résultats des recherches scientifiques. Lire le rapport De nouveaux mécanismes de résilience (PDF, 2,98 Mo). Une version récente d'Adobe Reader est ...

  13. Analyse de régression quantile de la relation entre la langue et l’intervalle entre les grossesses au Québec (Canada

    Directory of Open Access Journals (Sweden)

    Nathalie Auger

    2018-01-01

    Full Text Available Introduction. On sait que les intervalles courts comme les intervalles longs entre les grossesses sont associés à des issues périnatales défavorables, comme des fausses couches et des accouchements prématurés, mais les différences culturelles à ce sujet sont mal connues. Repérer les inégalités culturelles dans les intervalles entre les grossesses est nécessaire afin d'améliorer les résultats relatifs à la santé de la mère et de l’enfant. Nous avons ainsi évalué les intervalles entre les grossesses chez les anglophones et les francophones du Québec. Méthodologie. Nous avons obtenu les dossiers de naissance de tous les enfants nés au Québec entre 1989 et 2011. Nous avons recensé 571 461 femmes ayant eu au moins deux naissances et déterminé l’intervalle entre leurs grossesses. Les intervalles courts entre les grossesses (moins de 18 mois ont été définis comme étant le 20e percentile de la distribution, et les intervalles longs (60 mois ou plus, comme le 80e percentile. À l’aide de régressions quantiles, nous avons évalué l’association entre la langue et les intervalles courts et longs, ajustés en fonction des caractéristiques de la mère. Nous avons évalué les différences au fil du temps et selon l’âge de la mère pour les groupes défavorisés, qui ont été définis par l’absence de diplôme d’études secondaires, la résidence en milieu rural et le fait de vivre dans un quartier défavorisé matériellement. Résultats. Dans les modèles de régression ajustés, les anglophones sans diplôme d’études secondaires avaient des intervalles plus courts de 1,0 mois (intervalle de confiance [IC] à 95 % : −1,5 à −0,4 par rapport à leurs homologues francophones au 20e percentile de la distribution et plus longs de 1,9 mois (−0,5 à 4,3 au 80e percentile. Les résultats étaient similaires pour les anglophones des régions rurales et des quartiers matériellement défavorisés. Les

  14. Sequelles de Brulures au Centre Hospitalier Universitaire Ibn Rochd de Casablanca: Aspects Epidemio-Cliniques

    Science.gov (United States)

    Chafiki, N.; Fassi Fihri, J.; Boukind, E.H.

    2007-01-01

    Summary Il s'agit d'une étude épidémiologique des séquelles de brûlures à propos de 100 cas colligés au service de chirurgie réparatrice et de brûlés du centre hospitalier universitaire Ibn Rochd (Casablanca). Les adultes représentent 55% de la population étudiée, l'âge moyen global est de 20 ans. Le sexe féminin est le plus touché avec 61% des cas. Les brûlures survenues à domicile sont les plus fréquentes avec 80%. L'agent causal le plus incriminé est la petite bouteille de butane avec 44,4%. Plus de la moitié de la population brûlée (55%) sont accueillis initialement au niveau d'hôpitaux régionaux. Le délai de cicatrisation moyen de 7 mois et 11 jours et par conséquent les séquelles mineures (dyschromie dans 90% des cas et prurit dans 49% des cas) et majeures (rétractions dans 86% et l'hypertrophie dans 51%) sont fréquentes. La répartition globale des séquelles montre une prédominance du segment cervicocéphalique avec 89% des cas et des membres supérieurs dans 82% des cas. Les différents aspects anatomocliniques essentiels ont été décrits au niveau de chaque segment corporel. Nos résultats ont été comparés aux données de la littérature, ce qui nous amène à considérer qu'une large campagne de prévention couplée à une meilleure prise en charge initiale, précoce, bien conduite et multidisciplinaire permet non seulement de réduire le nombre de séquelles mais aussi de diminuer leur sévérité. PMID:21991060

  15. Le developpement de Limacella glioderma (Fr.) R. Maire

    NARCIS (Netherlands)

    Reijnders, A.F.M.

    1979-01-01

    A comparison of the development of Limacella guttata (Fr.) Konrad & Maublanc with that of L. glioderma (Fr.) R. Maire shows clearly that the latter is of a more primitive type. This conclusion is based on the following observations: a. Limacella guttata has a pileocarpic development: the first

  16. Occurrence of pesticides in water and sediment collected from amphibian habitats located throughout the United States, 2009-10

    Science.gov (United States)

    Smalling, Kelly L.; Orlando, James L.; Calhoun, Daniel; Battaglin, William A.; Kuivila, Kathryn

    2012-01-01

    Water and bed-sediment samples were collected by the U.S. Geological Survey (USGS) in 2009 and 2010 from 11 sites within California and 18 sites total in Colorado, Georgia, Idaho, Louisiana, Maine, and Oregon, and were analyzed for a suite of pesticides by the USGS. Water samples and bed-sediment samples were collected from perennial or seasonal ponds located in amphibian habitats in conjunction with research conducted by the USGS Amphibian Research and Monitoring Initiative and the USGS Toxic Substances Hydrology Program. Sites selected for this study in three of the states (California, Colorado, and Orgeon) have no direct pesticide application and are considered undeveloped and remote. Sites selected in Georgia, Idaho, Louisiana, and Maine were in close proximity to either agricultural or suburban areas. Water and sediment samples were collected once in 2009 during amphibian breeding seasons. In 2010, water samples were collected twice. The first sampling event coincided with the beginning of the frog breeding season for the species of interest, and the second event occurred 10-12 weeks later when pesticides were being applied to the surrounding areas. Additionally, water was collected during each sampling event to measure dissolved organic carbon, nutrients, and the fungus, Batrachochytrium dendrobatidis, which has been linked to amphibian declines worldwide. Bed-sediment samples were collected once during the beginning of the frog breeding season, when the amphibians are thought to be most at risk to pesticides. Results of this study are reported for the following two geographic scales: (1) for a national scale, by using data from the 29 sites that were sampled from seven states, and (2) for California, by using data from the 11 sampled sites in that state. Water samples were analyzed for 96 pesticides by using gas chromatography/mass spectrometry. A total of 24 pesticides were detected in one or more of the 54 water samples, including 7 fungicides, 10

  17. 40 CFR 180.464 - Dimethenamid; tolerances for residues.

    Science.gov (United States)

    2010-07-01

    ...) PESTICIDE PROGRAMS TOLERANCES AND EXEMPTIONS FOR PESTICIDE CHEMICAL RESIDUES IN FOOD Specific Tolerances...)-acetamide, applied as either the 90:10 or 50:50 S:R isomers, in or on the following food commodities... Pumpkin 0.01 Squash, winter 0.01 (d) Indirect or inadvertent residues. [Reserved] [65 FR 51551, Aug. 24...

  18. Le rôle des chefs traditionnels au Ghana : un modèle inspirant ...

    International Development Research Centre (IDRC) Digital Library (Canada)

    8 févr. 2011 ... Avec ses partenaires du Sud, avec aussi le soutien du Centre de recherches pour le développement international ( CRDI ), organisme canadien, Ray a étudié le rôle des chefs traditionnels au Ghana dans la lutte contre le VIH et le sida. Les collectivités politiques antérieures au colonialisme sont une ...

  19. Au-delà du plan. La topologie urbaine des livreurs

    Directory of Open Access Journals (Sweden)

    Céline Cholez

    2011-03-01

    Full Text Available Nombreuses sont les activités professionnelles au sein desquelles s’orchestrent des « défis » classant les professionnels en fonction de leur degré d’expertise. Parmi les livreurs, une joute fréquente consiste à soumettre à un collègue un nom et un numéro de rue au hasard pour qu’il indique le plus rapidement possible le plus court chemin pour y parvenir. Ces jeux professionnels révèlent un aspect essentiel de l’engagement dans l’activité de travail : l’ancrage dans un espace approprié comme territoire, le secteur de tournée. Les livreurs maîtrisent en effet leurs tâches grâce à leur connaissance des zones géographiques qu’ils sillonnent quotidiennement.

  20. 75 FR 68970 - Amendment of Using Agency for Restricted Areas R-4002, R-4005, R-4006 and R-4007; MD

    Science.gov (United States)

    2010-11-10

    ...-1070; Airspace Docket No. 10-AEA-18] RIN 2120-AA66 Amendment of Using Agency for Restricted Areas R-4002, R-4005, R- 4006 and R-4007; MD AGENCY: Federal Aviation Administration (FAA), DOT. ACTION: Final rule. SUMMARY: This action makes a minor change to the name of the using agency for restricted areas R...

  1. Ligand-Enhanced Optical Response of Gold Nanomolecules and Its Fragment Projection Analysis: The Case of Au 30 (SR) 18

    Energy Technology Data Exchange (ETDEWEB)

    Sementa, Luca; Barcaro, Giovanni; Baseggio, Oscar; De Vetta, Martina; Dass, Amala; Apra, Edoardo; Stener, Mauro; Fortunelli, Alessandro

    2017-01-10

    Here we investigate via first-principles simulations the optical absorption spectra of three different Au30(SR)18 monolayer-protected clusters (MPC): Au30(StBu)18, which is known in the literature and whose crystal structure is available, and two species – Au30(SPh)18 and Au30(SPh-pNO2)18 – which have been designed by replacing the tert-butyl organic residues with aromatic ones so as to investigate the effects of ligand replacement on the optical response of Au nanomolecules. In analogy with previously studied but rather different Au23(SR)16- anionic species, a substantial ligand-enhancement of the absorption intensity in the optical region is obtained for the Au30(SPhpNO2)18 neutral MPC. This demonstrates that using conjugated aromatic ligands with properly chosen electron withdrawal substituents and exhibiting steric hindrance so as to also achieve charge decompression at the surface is a general approach to enhance MPC photo-absorption intensity in the optical region. Moreover, the ligand-enhancement phenomenon is subjected to a detailed analysis based on fragment projection of electronic excited states and on induced transition densities, leading to a better understanding of its physical origin, thus opening avenues to its more precise control and exploitation.

  2. Effets perturbateurs endocriniens des pesticides organochlores.

    Science.gov (United States)

    Charlier, C; Plomteux, G

    2002-01-01

    Xenoestrogens such organochlorine pesticides are known to induce changes in reproductive development, function or behaviour in wildlife. Because these compounds are able to modify the estrogens metabolism, or to compete with estradiol for binding to the estrogen receptor, it may be possible that these products affect the risk of developing impaired fertility, precocious puberty or some kinds of cancer in man. Le plus ancien récit de lutte contre la pollution remonte à une légende indienne racontant que la divinité Sing-bonga était incommodée par les émanations des fours dans lesquels les Asuras fondaient leurs métaux (1). Evidemment depuis, la problématique n-a cessé de s-accroître et la contamination de la Terre par de nombreux polluants est devenue aujourd-hui un problème majeur de notre Société. La protection de notre environnement est une question capitale qui doit être respectée malgré la pression économique actuelle et qui ne cessera de croître au cours des prochaines années même si l-identification objective et indiscutable de ce qui est essentiel - donc devant être prioritairement garanti sur la planète - est difficile à cerner (2). « Un oiseau en mauvais état ne pond pas de bons oeufs » disait un proverbe grec. Mais ce n-est qu-à partir de la seconde moitié du XXème siècle que les toxicologues ont commencé à identifier les effets qu-avaient entraînés à l-échelle mondiale les pollutions émises aux XIXème siècle sur la faune sauvage et sur le cheptel (3). L-histoire contemporaine des pesticides industriels commence vers 1874 (synthèse des organochlorés) et se poursuit tout au long de ces 2 siècles en passant par la synthèse des organophosphorés (1950), des carbamates (1970) et des pyréthroïdes (1975) (4). Le dichlorodiphényltrichloroéthane (DDT) a été synthétisé pour la première fois par un étudiant en cours de préparation de sa thèse de doctorat : Othmer Zeidler. La production, reprise par les

  3. Anomalous decrease of resistance at 250 K in ultrathin Au-Nb film on single-crystal silicon

    International Nuclear Information System (INIS)

    Yamamoto, H.; Kawashima, T.; Tanaka, M.

    1986-01-01

    Ultrathin Au-Nb films as thin as 0.2 about 10 nm were deposited on clean surfaces of single-crystal silicon in order to investigate interfacial excitonic superconductivity. The samples were classified into two types, Nb-Au/Si and Au-Nb-Au/Si. In the latter case, the secondary Au film was deposited on the former sample cooled by liquid nitrogen. In the Nb-Au/ Si type of sample, a sheet resistance, R /SUB s/ at room temperature abruptly increased from 10 3 Ωsq -1 order to about 10 5 Ωsq -1 in several days a few months after the sample preparation. Then the sample showed an anomalous decrease of R /SUB s/ at about 250 K and an approximately null resistance at lower temperatures. This phenomenon was not so stable and was observed only for a few days. The Au-Nb-Au/Si type of sample showed low R /SUB s/ (10 2 about 10 3 Ωsq -1 ) at room temperature. A decrease and disappearance of R /SUB s/ were also observed at about 240 K in the sample with comparatively good reproducibility. These phenomena are discussed qualitatively, based on the excitonic superconductive model for an interface of metal/semiconductor by Allender, Bray, and Bardeen

  4. Bi-functional Au/FeS (Au/Co{sub 3}O{sub 4}) composite for in situ SERS monitoring and degradation of organic pollutants

    Energy Technology Data Exchange (ETDEWEB)

    Ma, Shuzhen; Cai, Qian; Lu, Kailing; Liao, Fan, E-mail: fliao@suda.edu.cn; Shao, Mingwang, E-mail: mwshao@suda.edu.cn [Institute of Functional Nano & Soft Materials (FUNSOM), Jiangsu Key Laboratory for Carbon-Based Functional Materials and Devices & Collaborative Innovation Center of Suzhou Nano Science and Technology, Soochow University (China)

    2016-01-15

    The bi-functional Au/FeS (Au/Co{sub 3}O{sub 4}) composite was fabricated by in situ reducing Au nanoparticles onto the surface of FeS (Co{sub 3}O{sub 4}). The as-prepared FeS possessed a multi-structure composed of plenty of nanoplates, which were coated by Au nanoparticles with an average size of ∼47.5 nm. While the Co{sub 3}O{sub 4} showed a thin hexagonal sheet containing Au nanoparticles on its surface with an average size of ∼79.0 nm. Both the as-prepared Au/FeS and Au/Co{sub 3}O{sub 4} composites exhibited excellent SERS performance, capable of enhancing the Raman signals of R6G molecules with the enhancement factor up to 1.81 × 10{sup 6} and 7.60 × 10{sup 4}, respectively. Moreover, Au/FeS (Au/Co{sub 3}O{sub 4}) composite also has been verified to have intrinsic peroxidase-like activity, which could decompose H{sub 2}O{sub 2} into hydroxyl radicals and then degrade organic pollutants into small molecules. Therefore, SERS can be used to real-time and in situ monitoring the degradation process of R6G molecules, employing the Au/FeS (Au/Co{sub 3}O{sub 4}) composite both as SERS substrate and catalyst. Graphical abstract: SERS was used to real-time and in situ monitoring the degradation of R6G, employing the Au/FeS and Au/Co{sub 3}O{sub 4} composites both as SERS substrates and catalysts.

  5. Propagating Degrees of Freedom in f(R Gravity

    Directory of Open Access Journals (Sweden)

    Yun Soo Myung

    2016-01-01

    Full Text Available We have computed the number of polarization modes of gravitational waves propagating in the Minkowski background in f(R gravity. These are three of two from transverse-traceless tensor modes and one from a massive trace mode, which confirms the results found in the literature. There is no massless breathing mode and the massive trace mode corresponds to the Ricci scalar. A newly defined metric tensor in f(R gravity satisfies the transverse-traceless (TT condition as well as the TT wave equation.

  6. The coincidence problem in holographic f(R) gravity

    Energy Technology Data Exchange (ETDEWEB)

    Bisabr, Yousef, E-mail: y-bisabr@srttu.edu [Department of Physics, Shahid Rajaee Teacher Training University, Lavizan, Tehran 16788 (Iran, Islamic Republic of)

    2011-09-15

    It is well known that f(R) gravity models formulated in the Einstein conformal frame are equivalent to Einstein gravity together with a minimally coupled scalar field. In this case, the scalar field couples with the matter sector and the coupling term is given by the conformal factor. We apply the holographic principle to such interacting models. In a spatially flat universe, we show that the Einstein frame representation of f(R) models leads to a constant ratio of energy densities of dark matter to dark energy.

  7. L'Asie du Sud peut-elle éliminer les obstacles au travail rémunéré ...

    International Development Research Centre (IDRC) Digital Library (Canada)

    22 janv. 2018 ... Il est donc prioritaire d'élaborer et de mettre en place des politiques ... à la vie économique et qui reconnaissent et valorisent les soins non ... par semaine aux activités professionnelles et non professionnelles ... par le CRDI au Bangladesh a révélé qu'une combinaison de formation, ... Tous droits réservés.

  8. Distinguishing f(R) theories from general relativity by gravitational lensing effect

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Hongguang [Beijing Normal University, Department of Physics, Beijing (China); Aix Marseille Universite et Universite de Toulon, Centre de Physique Theorique (UMR 7332), Marseille (France); Wang, Xin; Li, Haida; Ma, Yongge [Beijing Normal University, Department of Physics, Beijing (China)

    2017-11-15

    The post-Newtonian formulation of a general class of f(R) theories is set up in a third-order approximation. It turns out that the information of a specific form of f(R) gravity is encoded in the Yukawa potential, which is contained in the perturbative expansion of the metric components. Although the Yukawa potential is canceled in the second-order expression of the effective refraction index of light, detailed analysis shows that the difference of the lensing effect between the f(R) gravity and general relativity does appear at the third order when √(f''(0)/f{sup '}(0)) is larger than the distance d{sub 0} to the gravitational source. However, the difference between these two kinds of theories will disappear in the axially symmetric spacetime region. Therefore only in very rare case the f(R) theories are distinguishable from general relativity by gravitational lensing effect in a third-order post-Newtonian approximation. (orig.)

  9. General proof of the entropy principle for self-gravitating fluid in f(R) gravity

    Energy Technology Data Exchange (ETDEWEB)

    Fang, Xiongjun [Department of Physics and Key Laboratory of Low Dimensional Quantum Structures andQuantum Control of Ministry of Education, Hunan Normal University,Changsha, Hunan 410081 (China); Guo, Minyong [Department of Physics, Beijing Normal University,Beijing 100875 (China); Jing, Jiliang [Department of Physics and Key Laboratory of Low Dimensional Quantum Structures andQuantum Control of Ministry of Education, Hunan Normal University,Changsha, Hunan 410081 (China)

    2016-08-29

    The discussions on the connection between gravity and thermodynamics attract much attention recently. We consider a static self-gravitating perfect fluid system in f(R) gravity, which is an important theory could explain the accelerated expansion of the universe. We first show that the Tolman-Oppenheimer-Volkoff equation of f(R) theories can be obtained by thermodynamical method in spherical symmetric spacetime. Then we prove that the maximum entropy principle is also valid for f(R) gravity in general static spacetimes beyond spherical symmetry. The result shows that if the constraint equation is satisfied and the temperature of fluid obeys Tolmans law, the extrema of total entropy implies other components of gravitational equations. Conversely, if f(R) gravitational equation hold, the total entropy of the fluid should be extremum. Our work suggests a general and solid connection between f(R) gravity and thermodynamics.

  10. Eficiência do metalaxyl no controle da requeima do tomateiro Efficiency of Metalaxyl to control tomato late blight

    Directory of Open Access Journals (Sweden)

    Celson Rodrigues

    2000-03-01

    Full Text Available Foi avaliada a eficiência das dosagens de 1; 2,5 e 5 g/cova do fungicida Ridomil 50 gr (metalaxyl 50 g/kg, em aplicação única no solo, comparada com a dosagem de 400 g/100 litros de água do Fólio (metalaxyl + clorotalonil, 80 + 400 g/kg e do Ridomil Mancozeb br (metalaxyl + mancozeb, 80 + 640 g/kg, em dez pulverizações, para o controle da requeima do tomateiro cv. Santa Clara. O delineamento experimental foi de blocos ao acaso com seis tratamentos e quatro repetições. A percentagem de área foliar lesionada pela requeima foi de 2,75% no tratamento com Folio, 7,25% com Ridomil Mancozeb br; 18,25; 18,50 e 24,25% com as dosagens crescentes do Ridomil 50 gr, e 34,25% com a ausência de tratamento com fungicidas (testemunha. A produção de frutos comercialmente aceitáveis por dez plantas de tomateiro, avaliadas em cada parcela experimental, durante quatro semanas a partir de 90 dias do transplantio do tomateiro foi de 10,26 kg para o tratamento com o Folio, 9,10 kg para o Ridomil Mancozeb br, 2,07 kg; 1,86 e 1,74 kg para as dosagens crescentes do Ridomil 50 gr, enquanto para a testemunha foi de 1,58 kg. Estes resultados demonstraram a superioridade dos fungicidas Folio e Ridomil Mancozeb br em relação ao Ridomil 50 gr, para o controle da requeima do tomateiro, nas condições experimentais utilizadas.An experiment was conducted to study the efficiency of the dosages of 1; 2.5 and 5 g/plant, of the fungicide ridomil 50 gr (metalaxyl, 50 g/kg, in only one application in the soil, compared with the dosage of 400 g/100 liters of water, of the folio (metalaxyl + chlorothalonil, 80 + 400 g/kg and of the ridomil mancozeb br (metalaxyl + mancozeb, 80 + 640 g/kg, in ten pulverizations for the control of the late blight of the tomato cv. Santa Clara. The experiments were set up in a complete randomized design, with six treatments and four replications. The percentage of the damaged foliage area caused by late blight was of 2.75% in the treatment

  11. Constraining f(R gravity in solar system, cosmology and binary pulsar systems

    Directory of Open Access Journals (Sweden)

    Tan Liu

    2018-02-01

    Full Text Available The f(R gravity can be cast into the form of a scalar–tensor theory, and scalar degree of freedom can be suppressed in high-density regions by the chameleon mechanism. In this article, for the general f(R gravity, using a scalar–tensor representation with the chameleon mechanism, we calculate the parametrized post-Newtonian parameters γ and β, the effective gravitational constant Geff, and the effective cosmological constant Λeff. In addition, for the general f(R gravity, we also calculate the rate of orbital period decay of the binary system due to gravitational radiation. Then we apply these results to specific f(R models (Hu–Sawicki model, Tsujikawa model and Starobinsky model and derive the constraints on the model parameters by combining the observations in solar system, cosmological scales and the binary systems.

  12. On the rumors about the silent spring: review of the scientific evidence linking occupational and environmental pesticide exposure to endocrine disruption health effects Rumores de uma primavera silenciosa: uma revisão das evidências científicas sobre a associação entre exposição ocupacional e ambiental a pesticidas e distúrbios endócrinos

    OpenAIRE

    Pierluigi Cocco

    2002-01-01

    Occupational exposure to some pesticides, and particularly DBCP and chlordecone, may adversely affect male fertility. However, apart from the therapeutic use of diethylstilbestrol, the threat to human reproduction posed by "endocrine disrupting" environmental contaminants has not been supported by epidemiological evidence thus far. As it concerns other endocrine effects described in experimental animals, only thyroid inhibition following occupational exposure to amitrole and mancozeb has been...

  13. A no-hair theorem for black holes in f(R) gravity

    Science.gov (United States)

    Cañate, Pedro

    2018-01-01

    In this work we present a no-hair theorem which discards the existence of four-dimensional asymptotically flat, static and spherically symmetric or stationary axisymmetric, non-trivial black holes in the frame of f(R) gravity under metric formalism. Here we show that our no-hair theorem also can discard asymptotic de Sitter stationary and axisymmetric non-trivial black holes. The novelty is that this no-hair theorem is built without resorting to known mapping between f(R) gravity and scalar–tensor theory. Thus, an advantage will be that our no-hair theorem applies as well to metric f(R) models that cannot be mapped to scalar–tensor theory.

  14. Au nanoparticles attached carbon nanotubes as a high performance active element in field effect transistor

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Myeongsoon; Kim, Don, E-mail: donkim@pknu.ac.kr

    2016-08-15

    The Au nanoparticles attached carbon nanotubes (Au-CNTs), diameter ranged from 40 to 250 nm, were prepared and discussed their chemical and electrical properties. The shape and crystallinity of the carbon nanotubes (CNTs) phase depended main2ly on the diameter of CNTs (r{sub Au-CNT}). Highly crystalline, straight CNTs were observed when the r{sub Au-CNT} exceeded 80 nm, and less crystalline noodle-shaped CNTs were observed when the r{sub Au-CNT} was smaller than 80 nm. The crystallinity of the CNT phase was confirmed by analyzing the G and D bands in their Raman spectra and the electrical conductivities of the Au-CNTs. The electrical conductivity of the highly crystalline carbon phase of Au-CNTs (r{sub Au-CNT} = 250 nm) was ∼10{sup 4} S/cm. The back-gated field effect transistors (FETs) based on the Au-CNTs, which were assembled on a SiO{sub 2}/Si wafer using the dielectrophoresis technique, showed that the Au-CNTs would be a good functional electronic material for future electronic and sensing applications. The transconductance and hole mobility of the FETs, which were assembled with the highly crystalline Au-CNTs (r{sub Au-CNT} = 250 nm), reached to 3.6 × 10{sup −4} A/V and 3.1 × 10{sup 4} cm{sup 2}/V s, respectively. These values are in the middle of those of reported for single walled carbon nanotubes and graphene. However, we could not find any field effect in a CNTFET, which assembled without Au nanoparticles, through the same process. - Highlights: • The shape and crystallinity of the CNTs depended mainly on the diameter of CNTs. • The electrical conductivity of the highly crystalline Au-CNTs was ∼10{sup 4} S/cm. • The Au-CNT FET shows typical p-channel gate effect with the on/off ratio of ∼10{sup 4}. • The Au-CNT FET shows very high transconductance (g{sub m}) and carrier mobility (μ{sub h}).

  15. Extension of loop quantum gravity to f(R) theories.

    Science.gov (United States)

    Zhang, Xiangdong; Ma, Yongge

    2011-04-29

    The four-dimensional metric f(R) theories of gravity are cast into connection-dynamical formalism with real su(2) connections as configuration variables. Through this formalism, the classical metric f(R) theories are quantized by extending the loop quantization scheme of general relativity. Our results imply that the nonperturbative quantization procedure of loop quantum gravity is valid not only for general relativity but also for a rather general class of four-dimensional metric theories of gravity.

  16. Ajout d’équivalents des groupes alimentaires au Questionnaire canadien de fréquence alimentaire II pour estimer l’Indice canadien de saine alimentation-2005

    Directory of Open Access Journals (Sweden)

    Maria McInerney

    2018-01-01

    Full Text Available Introduction : Il a été prouvé qu’un régime alimentaire de piètre qualité augmente le risque de maladies chroniques courantes susceptibles de nuire à la qualité de vie et d'alourdir le fardeau qui pèse sur le système de santé. Les recommandations fondées sur des données probantes du Guide alimentaire canadien (GAC fournissent des conseils nutritionnels destinés à améliorer la qualité du régime alimentaire. L’Indice canadien de saine alimentation (ICSA, un outil de mesure de la qualité du régime alimentaire, permet d'évaluer la conformité au GAC. Le Questionnaire canadien de fréquence alimentaire II (QFA-C II [Canadian Diet History Questionnaire II, C-DHQ II], mis au point récemment, pourrait quant à lui servir à estimer l’ICSA au sein de la population canadienne si on pouvait ajouter à sa base de données sur les éléments nutritifs les équivalents des groupes alimentaires (correspondant aux portions du GAC. Nous décrivons dans cet article des méthodes destinées à enrichir cette base de données sur les éléments nutritifs du QFA-C II en vue d’estimer l’ICSA. Méthodologie : Nous avons créé des équivalents des groupes alimentaires à partir de données provenant de diverses bases de données sur les aliments et les éléments nutritifs, en particulier l’Enquête sur la santé dans les collectivités canadiennes, cycle 2.2 Nutrition de 2004. Nous avons ajouté ces variables à la base de données sur les éléments nutritifs du QFA-C II. Nous avons déterminé les scores de l’ICSA et avons effectué des analyses descriptives pour les participants qui ont répondu au QFA-C II dans le cadre d’une étude transversale canadienne. Résultats : Le score moyen de l’ICSA dans notre échantillon de 446 adultes de 20 à 83 ans était de 64,4 (écart-type : 10,8. Les femmes, les non-fumeurs et les personnes ayant un niveau de scolarité supérieur au secondaire ont obtenu de manière statistiquement

  17. Indefid particle elliptic flow in Au collisions at root s(NN)=130 GeV

    Czech Academy of Sciences Publication Activity Database

    Adler, C.; Ahammed, Z.; Allgower, C.; Amonett, J.; Anderson, B. D.; Anderson, M.; Averichev, G. S.; Balewski, J.; Barannikova, O.; Barnby, L. S.; Šumbera, Michal; Zborovský, Imrich

    2001-01-01

    Roč. 8718, č. 18 (2001), s. 2301 ISSN 0031-9007 R&D Projects: GA MŠk ME 475 Keywords : cellective expansion * anisotropc flow * Au+Au collisions * transition * energy * SPS Subject RIV: BF - Elementary Particles and High Energy Physics Impact factor: 6.668, year: 2001

  18. 48 CFR 18.001 - Definition.

    Science.gov (United States)

    2010-10-01

    ... CONTRACT TYPES EMERGENCY ACQUISITIONS 18.001 Definition. Emergency acquisition flexibilities, as used in... 48 Federal Acquisition Regulations System 1 2010-10-01 2010-10-01 false Definition. 18.001 Section... President issues an emergency declaration, or a major disaster declaration. [71 FR 38248, July 5, 2006, as...

  19. Les cultures transgéniques permettent-elles de réduire l’usage des produits phytosanitaires ? Considérations à partir du cas du soja tolérant au glyphosate

    Directory of Open Access Journals (Sweden)

    Bonny Sylvie

    2004-03-01

    Full Text Available L’article s’interroge sur l’impact des cultures transgéniques sur l’emploi des pesticides, objet de nombreux débats. Sont examinés les résultats de plusieurs études portant sur le bilan des premières années d’utilisation à grande échelle des OGM aux États-Unis, plus particulièrement du soja tolérant au glyphosate. Les travaux analysés présentent des résultats variables, surtout pour les années récentes, selon les méthodes choisies et le type d’extrapolations faites. Divers facteurs expliquant l’accroissement de l’emploi global du glyphosate sont passés en revue. Mais l’estimation des quantités d’herbicides utilisées qui dépendent de nombreux facteurs n’est pas un indicateur valide de l’impact des cultures transgéniques sur l’environnement.

  20. Constraint on reconstructed f(R) gravity models from gravitational waves

    Science.gov (United States)

    Lee, Seokcheon

    2018-06-01

    The gravitational wave (GW) detection of a binary neutron star inspiral made by the Advanced LIGO and Advanced Virgo paves the unprecedented way for multi-messenger observations. The propagation speed of this GW can be scrutinized by comparing the arrival times between GW and neutrinos or photons. It provides the constraint on the mass of the graviton. f(R) gravity theories have the habitual non-zero mass gravitons in addition to usual massless ones. Previously, we show that the model independent f(R) gravity theories can be constructed from the both background evolution and the matter growth with one undetermined parameter. We show that this parameter can be constrained from the graviton mass bound obtained from GW detection. Thus, the GW detection provides the invaluable constraint on the validity of f(R) gravity theories.

  1. 75 FR 6027 - Pesticide Experimental Use Permit; Receipt of Application; Comment Request

    Science.gov (United States)

    2010-02-05

    ... Agrochemicals Ltd. requesting an experimental use permit (EUP) for the end-use product FAL 1800, containing the... Agrochemicals Ltd., (62097-EUP-R). Pesticide Chemical: Prohydrojasmon (PDJ). Summary of Request: Use as a plant...

  2. Cosmic constraint on massive neutrinos in viable f(R) gravity with producing ΛCDM background expansion

    Energy Technology Data Exchange (ETDEWEB)

    Lu, Jianbo; Wu, Yabo; Wang, Yan; Yang, Weiqiang [Liaoning Normal University, Department of Physics, Dalian (China); Liu, Molin [Xinyang Normal University, Department of Physics, Xinyang (China)

    2016-12-15

    Tensions between several cosmic observations were found recently, such as the inconsistent values of H{sub 0} (or σ{sub 8}) were indicated by the different cosmic observations. Introducing the massive neutrinos in ΛCDM could potentially solve the tensions. Viable f(R) gravity producing ΛCDM background expansion with massive neutrinos is investigated in this paper. We fit the current observational data: Planck-2015 CMB, RSD, BAO, and SNIa to constrain the mass of neutrinos in viable f(R) theory. The constraint results at 95% confidence level are: Σm{sub ν} < 0.202 eV for the active-neutrino case, m{sub ν,sterile}{sup eff} < 0.757 eV with N{sub eff} < 3.22 for the sterile neutrino case. For the effects due to the mass of the neutrinos, the constraint results on model parameter at 95% confidence level become f{sub R0} x 10{sup -6} > -1.89 and f{sub R0} x 10{sup -6} > -2.02 for two cases, respectively. It is also shown that the fitting values of several parameters much depend on the neutrino properties, such as the cold dark matter density, the cosmological quantities at matter-radiation equality, the neutrino density and the fraction of baryonic mass in helium. Finally, the constraint result shows that the tension between direct and CMB measurements of H{sub 0} gets slightly weaker in the viable f(R) model than that in the base ΛCDM model. (orig.)

  3. Père au foyer : une nouvelle entrée au répertoire du masculin ?

    OpenAIRE

    Chatot, Myriam

    2017-01-01

    Cadre de la recherche : En dépit de la promotion dans les représentations d’un partage égalitaire des tâches domestiques et des responsabilités parentales entre conjoints, les femmes sont encore largement responsables de la prise en charge des enfants et des tâches ménagères ; l’entrée d’un homme dans la situation de « père au foyer » représente une inversion des rôles traditionnels.Objectifs : L’objectif de cet article est de comprendre comment se recomposent les rôles de genre traditionnels...

  4. Probing the f(R) formalism through gravitational wave polarizations

    International Nuclear Information System (INIS)

    Alves, M.E.S.; Miranda, O.D.; Araujo, J.C.N. de

    2009-01-01

    The direct observation of gravitational waves (GW) in the near future, and the corresponding determination of the number of independent polarizations, is a powerful tool to test general relativity and alternative theories of gravity. In the present work we use the Newman-Penrose formalism to characterize GWs in quadratic gravity and in a particular class of f(R) Lagrangians. We find that both quadratic gravity and the f(R) theory belong to the most general invariant class of GWs, i.e., they can present up to six independent polarizations of GWs. For a particular combination of the parameters, we find that quadratic gravity can present up to five polarizations states. On the other hand, if we use the Palatini approach for f(R) theories, GWs present only the usual two transverse-traceless polarizations such as in general relativity. Thus, we conclude that the observation of GWs can strongly constrain the suitable formalism for these theories.

  5. On Analytical Solutions of f(R) Modified Gravity Theories in FLRW Cosmologies

    Science.gov (United States)

    Domazet, Silvije; Radovanović, Voja; Simonović, Marko; Štefančić, Hrvoje

    2013-02-01

    A novel analytical method for f(R) modified theories without matter in Friedmann-Lemaitre-Robertson-Walker (FLRW) spacetimes is introduced. The equation of motion for the scale factor in terms of cosmic time is reduced to the equation for the evolution of the Ricci scalar R with the Hubble parameter H. The solution of equation of motion for actions of the form of power law in Ricci scalar R is presented with a detailed elaboration of the action quadratic in R. The reverse use of the introduced method is exemplified in finding functional forms f(R), which leads to specified scale factor functions. The analytical solutions are corroborated by numerical calculations with excellent agreement. Possible further applications to the phases of inflationary expansion and late-time acceleration as well as f(R) theories with radiation are outlined.

  6. f(R in Holographic and Agegraphic Dark Energy Models and the Generalized Uncertainty Principle

    Directory of Open Access Journals (Sweden)

    Barun Majumder

    2013-01-01

    Full Text Available We studied a unified approach with the holographic, new agegraphic, and f(R dark energy model to construct the form of f(R which in general is responsible for the curvature driven explanation of the very early inflation along with presently observed late time acceleration. We considered the generalized uncertainty principle in our approach which incorporated the corrections in the entropy-area relation and thereby modified the energy densities for the cosmological dark energy models considered. We found that holographic and new agegraphic f(R gravity models can behave like phantom or quintessence models in the spatially flat FRW universe. We also found a distinct term in the form of f(R which goes as R 3 / 2 due to the consideration of the GUP modified energy densities. Although the presence of this term in the action can be important in explaining the early inflationary scenario, Capozziello et al. recently showed that f(R ~ R 3 / 2 leads to an accelerated expansion, that is, a negative value for the deceleration parameter q which fits well with SNeIa and WMAP data.

  7. 78 FR 3422 - Notice of Receipt of Pesticide Products; Registration Applications

    Science.gov (United States)

    2013-01-16

    ... included in any currently registered pesticide products. Pursuant to the Federal Insecticide, Fungicide.... Box 667, Ames, IA 50010. Active Ingredient: Trichoderma fertile strain JM41R at 96.0%. Product Type: Fungicide. Proposed Use: Manufacturing use. Contact: Jeannine Kausch, (703) 347-8920, email address: kausch...

  8. Reconstructing an f(R) model from holographic dark energy: using the observational evidence

    International Nuclear Information System (INIS)

    Saaidi, Kh; Aghamohammadi, A

    2012-01-01

    We investigate the correspondence relation between f(R) gravity and an interacting holographic dark energy (HDE). By obtaining the conditions needed for some observational evidence such as positive acceleration expansion of the Universe, crossing the phantom divide line and validity of the thermodynamics second law in an interacting HDE model and corresponding it with the f(R) model of gravity, we find a viable f(R) model that can explain the present Universe. We also obtain the explicit evolutionary forms of the corresponding scalar field, potential and scale factor of the Universe. (paper)

  9. String duality transformations in f(R) gravity from Noether symmetry approach

    Energy Technology Data Exchange (ETDEWEB)

    Capozziello, Salvatore [Dipartimento di Fisica, Università di Napoli ' ' Federico II' ' , Compl. Univ. di Monte S. Angelo, Edificio G, Via Cinthia, I-80126, Napoli (Italy); Gionti, Gabriele S.J. [Specola Vaticana, Vatican City, V-00120, Vatican City State (Vatican City State, Holy See); Vernieri, Daniele, E-mail: capozziello@na.inf.it, E-mail: ggionti@as.arizona.edu, E-mail: vernieri@iap.fr [Sorbonne Universités, UPMC Univ Paris 6 et CNRS, UMR 7095, Institut d' Astrophysique de Paris, GReCO, 98bis Bd Arago, 75014 Paris (France)

    2016-01-01

    We select f(R) gravity models that undergo scale factor duality transformations. As a starting point, we consider the tree-level effective gravitational action of bosonic String Theory coupled with the dilaton field. This theory inherits the Busher's duality of its parent String Theory. Using conformal transformations of the metric tensor, it is possible to map the tree-level dilaton-graviton string effective action into f(R) gravity, relating the dilaton field to the Ricci scalar curvature. Furthermore, the duality can be framed under the standard of Noether symmetries and exact cosmological solutions are derived. Using suitable changes of variables, the string-based f(R) Lagrangians are shown in cases where the duality transformation becomes a parity inversion.

  10. String duality transformations in f(R) gravity from Noether symmetry approach

    International Nuclear Information System (INIS)

    Capozziello, Salvatore; Gionti, Gabriele S.J.; Vernieri, Daniele

    2016-01-01

    We select f(R) gravity models that undergo scale factor duality transformations. As a starting point, we consider the tree-level effective gravitational action of bosonic String Theory coupled with the dilaton field. This theory inherits the Busher's duality of its parent String Theory. Using conformal transformations of the metric tensor, it is possible to map the tree-level dilaton-graviton string effective action into f(R) gravity, relating the dilaton field to the Ricci scalar curvature. Furthermore, the duality can be framed under the standard of Noether symmetries and exact cosmological solutions are derived. Using suitable changes of variables, the string-based f(R) Lagrangians are shown in cases where the duality transformation becomes a parity inversion

  11. Risque de réémergence du paludisme au Maroc Étude de la capacité vectorielle d’Anopheles labranchiae dans une zone rizicole au nord du pays

    Directory of Open Access Journals (Sweden)

    Faraj C.

    2008-12-01

    Full Text Available Dans le but d’estimer le risque de réintroduction du paludisme au Maroc, nous avons analysé le potentiel paludogène d’une zone rizicole au nord du pays. Nos résultats ont montré que la capacité vectorielle d’An. labranchiae, vecteur du paludisme au Maroc, était particulièrement élevée pendant la période estivale qui correspond à la période de culture du riz. Le risque d’une reprise de la transmission du paludisme autochtone est élevé du fait de l’éventuelle présence de porteurs de parasite dans le dernier foyer de paludisme limitrophe de la zone d’étude. Le risque d’une introduction du paludisme tropical est faible, vu la faible vulnérabilité de la région et la compétence de ses vecteurs, considérée comme faible. Toutefois, ce risque doit faire l’objet d’une grande attention.

  12. Gold(I) Complexes with N-Donor Ligands. 2.(1) Reactions of Ammonium Salts with [Au(acac-kappaC(2))(PR(3))] To Give [Au(NH(3))L](+), [(AuL)(2)(&mgr;(2)-NH(2))](+), [(AuL)(4)(&mgr;(4)-N)](+), or [(AuL)(3)(&mgr;(3)-O)](+). A New and Facile Synthesis of [Au(NH(3))(2)](+) Salts. Crystal Structure of [{AuP(C(6)H(4)OMe-4)(3)}(3)(&mgr;(3)-O)]CF(3)SO(3).

    Science.gov (United States)

    Vicente, José; Chicote, María-Teresa; Guerrero, Rita; Jones, Peter G.; Ramírez De Arellano, M. Carmen

    1997-09-24

    The complexes [Au(acac-kappaC(2))(PR(3))] (acac = acetylacetonate, R = Ph, C(6)H(4)OMe-4) react with (NH(4))ClO(4) to give amminegold(I), [Au(NH(3))(PR(3))]ClO(4), amidogold(I), [(AuPR(3))(2)(&mgr;(2)-NH(2))]ClO(4), or nitridogold(I), [(AuPR(3))(4)(&mgr;(4)-N)]ClO(4), complexes, depending on the reaction conditions. Similarly, [Au(acac-kappaC(2))(PPh(3))] reacts with (NH(3)R')OTf (OTf = CF(3)SO(3)) (1:1) or with [H(3)N(CH(2))(2)NH(2)]OTf (1:1) to give (amine)gold(I) complexes [Au(NH(2)R')(PPh(3))]OTf (R' = Me, C(6)H(4)NO(2)-4) or [(AuPPh(3))(2){&mgr;(2)-H(2)N(CH(2))(2)NH(2)}](OTf)(2), respectively. The ammonium salts (NH(2)R'(2))OTf (R' = Et, Ph) react with [Au(acac-kappaC(2))(PR(3))] (R = Ph, C(6)H(4)OMe-4) (1:2) to give, after hydrolysis, the oxonium salts [(AuPR(3))(3)(&mgr;(3)-O)]OTf (R = Ph, C(6)H(4)OMe-4). When NH(3) is bubbled through a solution of [AuCl(tht)] (tht = tetrahydrothiophene), the complex [Au(NH(3))(2)]Cl precipitates. Addition of [Au(NH(3))(2)]Cl to a solution of AgClO(4) or TlOTf leads to the isolation of [Au(NH(3))(2)]ClO(4) or [Au(NH(3))(2)]OTf, respectively. The crystal structure of [(AuPR(3))(3)(&mgr;(3)-O)]OTf.Me(2)CO (R = C(6)H(4)OMe-4) has been determined: triclinic, space group P&onemacr;, a = 14.884(3) Å, b = 15.828(3) Å, c = 16.061(3) Å, alpha = 83.39(3) degrees, beta = 86.28(3) degrees, gamma = 65.54(3) degrees, R1 (wR2) = 0.0370 (0.0788). The [(AuPR(3))(3)(&mgr;(3)-O)](+) cation shows an essentially trigonal pyramidal array of three gold atoms and one oxygen atom with O-Au-P bond angles of ca. 175 degrees and Au.Au contacts in the range 2.9585(7)-3.0505(14) Å. These cations are linked into centrosymmetric dimers through two short Au.Au [2.9585(7), 3.0919(9) Å] contacts. The gold atoms of the dimer form a six-membered ring with a chair conformation.

  13. Unifying inflation with dark energy in modified F(R) Horava-Lifshitz gravity

    International Nuclear Information System (INIS)

    Elizalde, E.; Saez-Gomez, D.; Nojiri, S.; Odintsov, S.D.

    2010-01-01

    We study FRW cosmology for a non-linear modified F(R) Horava-Lifshitz gravity which has a viable convenient counterpart. A unified description of early-time inflation and late-time acceleration is possible in this theory, but the cosmological dynamic details are generically different from the ones of the convenient viable F(R) model. Remarkably, for some specific choice of parameters they do coincide. The emergence of finite-time future singularities is investigated in detail. It is shown that these singularities can be cured by adding an extra, higher-derivative term, which turns out to be qualitatively different when compared with the corresponding one of the convenient F(R) theory. (orig.)

  14. 76 FR 41246 - Pesticide Program Dialogue Committee, Pesticide Registration Improvement Act Process Improvement...

    Science.gov (United States)

    2011-07-13

    ... Committee, Pesticide Registration Improvement Act Process Improvement Workgroup; Notice of Public Meeting...) Process Improvement Work Group. EPA plans to meet its ESA consultation obligations through the pesticide... a pesticide during the registration review process. This meeting of the PRIA Process Improvement...

  15. Late time acceleration of the universe in f(R) gravity model

    International Nuclear Information System (INIS)

    Mukherjee, Ankan

    2014-01-01

    In this work, a new way to look at the nature of late time dynamics of the universe for f(R) gravity models using the contracted Bianchi Identity has been proposed. As the Einstein field equations contain derivatives of the curvature scalar R, the contracted Bianchi identity yields a second order nonlinear differential equation in H, the Hubble parameter. This equation is studied for two particular forms of f(R), and the late time behaviour of the model is discussed. (author)

  16. Stability of the Einstein static universe in f(R, T) gravity

    Energy Technology Data Exchange (ETDEWEB)

    Shabani, Hamid [University of Sistan and Baluchestan, Physics Department, Faculty of Sciences, Zahedan (Iran, Islamic Republic of); Ziaie, Amir Hadi [Kahnooj Branch, Islamic Azad University, Department of Physics, Kerman (Iran, Islamic Republic of)

    2017-01-15

    The Einstein static (ES) universe has played a major role in various emergent scenarios recently proposed in order to cure the problem of the initial singularity of the standard model of cosmology. In the model we address, we study the existence and stability of an ES universe in the context of f(R, T) modified theories of gravity. Considering specific forms of the f(R, T) function, we seek for the existence of solutions representing ES state. Using dynamical system techniques along with numerical analysis, we find two classes of solutions: the first one is always unstable of the saddle type, while the second is always stable so that its dynamical behavior corresponds to a center equilibrium point. The importance of the second class of solutions is due to the significant role they play in constructing non-singular emergent models in which the universe could have experienced past-eternally a series of infinite oscillations about such an initial static state after which it enters, through a suitable physical mechanism, to an inflationary era. Considering specific forms for the functionality of f(R, T), we show that this theory is capable of providing cosmological solutions which admit emergent universe (EU) scenarios. We also investigate homogeneous scalar perturbations for the mentioned models. The stability regions of the solutions are parametrized by a linear equation of state (EoS) parameter and other free parameters that will be introduced for the models. Our results suggest that modifications in f(R, T) gravity would lead to stable solutions which are unstable in f(R) gravity model. (orig.)

  17. Stability of the Einstein static universe in f(R, T) gravity

    International Nuclear Information System (INIS)

    Shabani, Hamid; Ziaie, Amir Hadi

    2017-01-01

    The Einstein static (ES) universe has played a major role in various emergent scenarios recently proposed in order to cure the problem of the initial singularity of the standard model of cosmology. In the model we address, we study the existence and stability of an ES universe in the context of f(R, T) modified theories of gravity. Considering specific forms of the f(R, T) function, we seek for the existence of solutions representing ES state. Using dynamical system techniques along with numerical analysis, we find two classes of solutions: the first one is always unstable of the saddle type, while the second is always stable so that its dynamical behavior corresponds to a center equilibrium point. The importance of the second class of solutions is due to the significant role they play in constructing non-singular emergent models in which the universe could have experienced past-eternally a series of infinite oscillations about such an initial static state after which it enters, through a suitable physical mechanism, to an inflationary era. Considering specific forms for the functionality of f(R, T), we show that this theory is capable of providing cosmological solutions which admit emergent universe (EU) scenarios. We also investigate homogeneous scalar perturbations for the mentioned models. The stability regions of the solutions are parametrized by a linear equation of state (EoS) parameter and other free parameters that will be introduced for the models. Our results suggest that modifications in f(R, T) gravity would lead to stable solutions which are unstable in f(R) gravity model. (orig.)

  18. 77 FR 38285 - Pesticide Products; Registration Applications

    Science.gov (United States)

    2012-06-27

    ... ENVIRONMENTAL PROTECTION AGENCY [EPA-HQ-OPP-2012-0101; FRL-9348-5] Pesticide Products... announces receipt of applications to register pesticide products containing new active ingredients not... Pollution Prevention Division (7511P) or the Registration Division (7505P), Office of Pesticide Programs...

  19. Effects of water extraction in a vulnerable phreatic aquifer: Consequences for groundwater contamination by pesticides, Sint-Jansteen area, The Netherlands

    Science.gov (United States)

    Gaus, Irina

    pesticides, ce qui rend l'eau impropre à la consommation. La contamination plus importante de l'eau pompée est provoquée par la modification des directions d'écoulement souterrain naturel au voisinage des puits de pompage. Dans cette région, l'usage des pesticides ne peut pas être évité facilement; c'est pourquoi une approche est développée pour différencier les usages de pesticides dans ce secteur en fonction des temps de parcours prévus en direction des puits et des caractéristiques chimiques des pesticides. Un modèle d'écoulement des eaux souterraines pour cette région a été développé et les effets des pompages sur les directions d'écoulement naturel ont étéévalués. Les zones de temps de parcours ont été déterminées au moyen de la méthode du suivi de particules (particle tracking). La combinaison de ces résultats avec le comportement de certains pesticides au cours de leur dégradation conduit à un schéma optimisé conciliant les activités agricoles et les prélèvements d'eaux souterraines dans cette région. Cette question est abordée pour cinq types de pesticides (atrazine, simazine, bentazone, MCPA et mecoprop). Resumen Los pesticidas son una amenaza para la calidad de las aguas subterráneas cuando el área de suministro se encuentra en una zona agrícola. Un ejemplo tiene lugar en la zona de Sint-Jansteen, Holanda, donde mientras que las muestras de agua subterránea tomadas directamente del acuífero tienen un bajo nivel de contaminación por pesticidas, las muestras tomadas del agua extraída exceden con regularidad los límites de la UE (0.1μg/l), lo que hace que el agua sea no potable. Esta diferencia está causada por las variaciones respecto al régimen de flujo natural a consecuencia de las propias extracciones. En esta zona el uso de pesticidas es difícilmente evitable, por lo que se está desarrollando un método para diferenciar la posibilidad de uso de pesticidas en función de las características químicas de los

  20. An Innovative Rapid Method for Analysis of 10 Organophosphorus Pesticide Residues in Wheat by HS-SPME-GC-FPD/MSD.

    Science.gov (United States)

    Du, Xin; Ren, YongLin; Beckett, Stephen J

    2016-01-01

    The rapid detection of pesticide residues in wheat has become a top food security priority. A solvent-free headspace solid-phase microextraction (HS-SPME) has been evaluated for rapid screening of organophosphorus pesticide (OPP) residues in wheat with high sensitivity. Individual wheat samples (1.7 g), spiked with 10 OPPs, were placed in a 4 mL sealed amber glass vial and heated at 60°C for 45 min. During this time, the OPP residues were extracted with a 50 μm/30 μm divinylbenzene (DVB)/carboxen (CAR)/plasma desorption mass spectroscopy polydimethylsiloxane (PDMS) fiber from the headspace above the sample. The fiber was then removed and injected into the GC injection port at 250°C for desorption of the extracted chemicals. The multiple residues were identified by a GC mass spectrometer detector (GC-MSD) and quantified with a GC flame photometric detector (GC-FPD). Seven spiked levels of 10 OPPs on wheat were analyzed. The GC responses for a 50 μm/30 μm DVB/CAR/PDMS fiber increased with increasing spiking levels, yielding significant (R(2) > 0.98) linear regressions. The lowest LODs of the multiple pesticide standards were evaluated under the conditions of the validation study in a range of levels from 0 (control) to 100 ng of pesticide residue per g of wheat that separated on a low-polar GC capillary column (Agilent DB-35UI). The results of the HS-SPME method were compared with the QuEChERS AOAC 2007.01 method and they showed several advantages over the latter. These included improved sensitivity, selectivity, and simplicity.

  1. Exact solutions for scalar field cosmology in f(R) gravity

    Science.gov (United States)

    Maharaj, S. D.; Goswami, R.; Chervon, S. V.; Nikolaev, A. V.

    2017-09-01

    We study scalar field FLRW cosmology in the content of f(R) gravity. Our consideration is restricted to the spatially flat Friedmann universe. We derived the general evolution equations of the model, and showed that the scalar field equation is automatically satisfied for any form of the f(R) function. We also derived representations for kinetic and potential energies, as well as for the acceleration in terms of the Hubble parameter and the form of the f(R) function. Next we found the exact cosmological solutions in modified gravity without specifying the f(R) function. With negligible acceleration of the scalar curvature, we found that the de Sitter inflationary solution is always attained. Also we obtained new solutions with special restrictions on the integration constants. These solutions contain oscillating, accelerating, decelerating and even contracting universes. For further investigation, we selected special cases which can be applied with early or late inflation. We also found exact solutions for the general case for the model with negligible acceleration of the scalar curvature in terms of special Airy functions. Using initial conditions which represent the universe at the present epoch, we determined the constants of integration. This allows for the comparison of the scale factor in the new solutions with that for current stage of the universe evolution in the ΛCDM model.

  2. A sensitive acetylcholinesterase biosensor based on gold nanorods modified electrode for detection of organophosphate pesticide.

    Science.gov (United States)

    Lang, Qiaolin; Han, Lei; Hou, Chuantao; Wang, Fei; Liu, Aihua

    2016-08-15

    A sensitive amperometric acetylcholinesterase (AChE) biosensor, based on gold nanorods (AuNRs), was developed for the detection of organophosphate pesticide. Compared with Au@Ag heterogeneous NRs, AuNRs exhibited excellent electrocatalytic properties, which can electrocatalytically oxidize thiocholine, the hydrolysate of acetylthiocholine chloride (ATCl) by AChE at +0.55V (vs. SCE). The AChE/AuNRs/GCE biosensor was fabricated on basis of the inhibition of AChE activity by organophosphate pesticide. The biosensor could detect paraoxon in the linear range from 1nM to 5μM and dimethoate in the linear range from 5nM to 1μM, respectively. The detection limits of paraoxon and dimethoate were 0.7nM and 3.9nM, which were lower than the reported AChE biosensor. The proposed biosensor could restore to over 95% of its original current, which demonstrated the good reactivation. Moreover, the biosensor can be applicable to real water sample measurement. Thus, the biosensor exhibited low applied potential, high sensitivity and good stability, providing a promising tool for analysis of pesticides. Copyright © 2016 Elsevier B.V. All rights reserved.

  3. Chameleon halo modeling in f(R) gravity

    International Nuclear Information System (INIS)

    Li Yin; Hu, Wayne

    2011-01-01

    We model the chameleon effect on cosmological statistics for the modified gravity f(R) model of cosmic acceleration. The chameleon effect, required to make the model compatible with local tests of gravity, reduces force enhancement as a function of the depth of the gravitational potential wells of collapsed structure and so is readily incorporated into a halo model by including parameters for the chameleon mass threshold and rapidity of transition. We show that the abundance of halos around the chameleon mass threshold is enhanced by both the merging from below and the lack of merging to larger masses. This property also controls the power spectrum in the nonlinear regime and we provide a description of the transition to the linear regime that is valid for a wide range of f(R) models.

  4. Au nanoparticles attached carbon nanotubes as a high performance active element in field effect transistor

    International Nuclear Information System (INIS)

    Lee, Myeongsoon; Kim, Don

    2016-01-01

    The Au nanoparticles attached carbon nanotubes (Au-CNTs), diameter ranged from 40 to 250 nm, were prepared and discussed their chemical and electrical properties. The shape and crystallinity of the carbon nanotubes (CNTs) phase depended main2ly on the diameter of CNTs (r_A_u_-_C_N_T). Highly crystalline, straight CNTs were observed when the r_A_u_-_C_N_T exceeded 80 nm, and less crystalline noodle-shaped CNTs were observed when the r_A_u_-_C_N_T was smaller than 80 nm. The crystallinity of the CNT phase was confirmed by analyzing the G and D bands in their Raman spectra and the electrical conductivities of the Au-CNTs. The electrical conductivity of the highly crystalline carbon phase of Au-CNTs (r_A_u_-_C_N_T = 250 nm) was ∼10"4 S/cm. The back-gated field effect transistors (FETs) based on the Au-CNTs, which were assembled on a SiO_2/Si wafer using the dielectrophoresis technique, showed that the Au-CNTs would be a good functional electronic material for future electronic and sensing applications. The transconductance and hole mobility of the FETs, which were assembled with the highly crystalline Au-CNTs (r_A_u_-_C_N_T = 250 nm), reached to 3.6 × 10"−"4 A/V and 3.1 × 10"4 cm"2/V s, respectively. These values are in the middle of those of reported for single walled carbon nanotubes and graphene. However, we could not find any field effect in a CNTFET, which assembled without Au nanoparticles, through the same process. - Highlights: • The shape and crystallinity of the CNTs depended mainly on the diameter of CNTs. • The electrical conductivity of the highly crystalline Au-CNTs was ∼10"4 S/cm. • The Au-CNT FET shows typical p-channel gate effect with the on/off ratio of ∼10"4. • The Au-CNT FET shows very high transconductance (g_m) and carrier mobility (μ_h).

  5. Kinetic Investigation of Homogeneous H(2)-D(2) Equilibration Catalyzed by Pt-Au Cluster Compounds. Characterization of the Cluster [(H)Pt(AuPPh(3))(9)](NO(3))(2).

    Science.gov (United States)

    Rubinstein, Leon I.; Pignolet, Louis H.

    1996-11-06

    The new Pt-Au hydrido cluster compound [(H)Pt(AuPPh(3))(9)](NO(3))(2) (3) has been synthesized and characterized by NMR, FABMS, and single-crystal X-ray diffraction [triclinic, P&onemacr;, a = 17.0452(1) Å, b = 17.4045(2) Å, c = 55.2353(1) Å, alpha = 89.891(1) degrees, beta = 85.287(1) degrees, gamma = 75.173(1) degrees, V = 15784.0(2) Å(3), Z = 4 (two molecules in asymmetric unit), residual R = 0.089 for 45 929 observed reflections and 3367 variables, Mo Kalpha radiation]. The Pt(AuP)(9) core geometry is a distorted icosahedron with three vertices vacant. The Pt-Au, Au-Au, and Au-P distances are within the normal ranges observed in other Pt-Au clusters. This cluster is a catalyst for H(2)-D(2) equilibration in homogeneous solution phase and has been used in a general mechanistic study of this reaction catalyzed by Pt-Au clusters. We previously proposed that a key step in the mechanism for catalytic H(2)-D(2) equilibration is the dissociation of a PPh(3) ligand to give a cluster with an open Au site for bonding of H(2) or D(2). This was based on qualitative observations that PPh(3) inhibited the rate of HD production with [Pt(AuPPh(3))(8)](NO(3))(2) (1) as catalyst. In order to test this hypothesis, phosphine inhibition (on the rate of HD production) and phosphine ligand exchange kinetic experiments were carried out with [(H)(PPh(3))Pt(AuPPh(3))(7)](NO(3))(2) (2) and 3. In this paper we show that the rate constant for phosphine dissociation determined from the PPh(3) inhibition rate study of H(2)-D(2) equilibration with cluster 2 is nearly identical to the rate constant for dissociative phosphine ligand exchange. The slower rate for H(2)-D(2) equilibration observed with 3 compared with 2 (5.5 x 10(-3) vs 7.7 x 10(-2) turnover s(-1)) is explained by its smaller rate constant for phosphine dissociation (2.8 x 10(-5) vs 2.9 x 10(-4) s(-1)). The fact that clusters 2 and 3 show similar kinetic behaviors suggests that the PPh(3) dissociation step in the catalytic H(2

  6. Organochlorine pesticide contamination of ground water in the city of Hyderabad.

    Science.gov (United States)

    Shukla, Gangesh; Kumar, Anoop; Bhanti, Mayank; Joseph, P E; Taneja, Ajay

    2006-02-01

    Organochlorine pesticides are ubiquitous and persistent organic pollutants used widely throughout the world. Due to the extensive use in agriculture, organic environmental contaminants such as HCH, DDT along with other organochlorine pesticides are distributed globally by transport through air and water. The main aim of present study is to determine contamination levels of organochlorine pesticides in the ground water of Hyderabad City. Water samples were collected from 28 domestic well supplies of the city. For this study, random sampling technique was applied, all the samples were collected in high purity glass bottles and refrigerated at 4 degrees C until analysis. Solid Phase Extraction (SPE) is used for the extraction of organochlorine pesticide residues in water sample. The collected water samples were pre-filtered through a 0.45 microg glass fiber filter (Wattman GF/F) to remove particulate matter and were acidified with hydrochloric acid (6N) to pH 2.5. Methanol modifier (BDH, for pesticide residue analysis, 10 mL) was added to water sample for better extraction. SPE using pre-packed reversed phase octadecyl (C-18 bonded silica) contained in cartridges was used for sample preparation. Prior to the extraction, the C-18 bonded phase, which contains 500 mg of bonded phase, was washed with 20 mL methanol. The sample was mixed well and allowed to percolate through the cartridges with flow rate of 10-15 mL/min under vacuum. After sample extraction, suction continued for 15 min to dry the packing material and pesticides trapped in the C-18 bonded phases were eluted by passing 10 mL hexane and fraction was evaporated in a gentle steam of Nitrogen. In all samples pesticide residues were analyzed by GC (Chemito-8510) with Ni63 ECD detector. Helium was used as carrier gas and nitrogen was used as make up gas. The injection technique was split/split less. All the samples analyzed were found to be contaminated with four pesticides i.e. DDT, beta-Endosulfan, alpha

  7. 20 Years of Air-Water Gas Exchange Observations for Pesticides in the Western Arctic Ocean.

    Science.gov (United States)

    Jantunen, Liisa M; Wong, Fiona; Gawor, Anya; Kylin, Henrik; Helm, Paul A; Stern, Gary A; Strachan, William M J; Burniston, Deborah A; Bidleman, Terry F

    2015-12-01

    The Arctic has been contaminated by legacy organochlorine pesticides (OCPs) and currently used pesticides (CUPs) through atmospheric transport and oceanic currents. Here we report the time trends and air-water exchange of OCPs and CUPs from research expeditions conducted between 1993 and 2013. Compounds determined in both air and water were trans- and cis-chlordanes (TC, CC), trans- and cis-nonachlors (TN, CN), heptachlor exo-epoxide (HEPX), dieldrin (DIEL), chlorobornanes (ΣCHBs and toxaphene), dacthal (DAC), endosulfans and metabolite endosulfan sulfate (ENDO-I, ENDO-II, and ENDO SUL), chlorothalonil (CHT), chlorpyrifos (CPF), and trifluralin (TFN). Pentachloronitrobenzene (PCNB and quintozene) and its soil metabolite pentachlorothianisole (PCTA) were also found in air. Concentrations of most OCPs declined in surface water, whereas some CUPs increased (ENDO-I, CHT, and TFN) or showed no significant change (CPF and DAC), and most compounds declined in air. Chlordane compound fractions TC/(TC + CC) and TC/(TC + CC + TN) decreased in water and air, while CC/(TC + CC + TN) increased. TN/(TC + CC + TN) also increased in air and slightly, but not significantly, in water. These changes suggest selective removal of more labile TC and/or a shift in chlordane sources. Water-air fugacity ratios indicated net volatilization (FR > 1.0) or near equilibrium (FR not significantly different from 1.0) for most OCPs but net deposition (FR exchange direction of other CUPs varied. Understanding the processes and current state of air-surface exchange helps to interpret environmental exposure and evaluate the effectiveness of international protocols and provides insights for the environmental fate of new and emerging chemicals.

  8. Absolute measurement of the cross sections of neutron radiative capture for 23Na, Cr, 55Mn, Fe, Ni, 103Rh, Ta, 197Au and 238U in the 10-600keV energy range

    International Nuclear Information System (INIS)

    Le Rigoleur, Claude; Arnaud, Andre; Taste, Jean.

    1976-10-01

    The total energy weighting technique has been applied to measuring absolute neutron capture cross sections for 23 Na, Cr, 55 Mn, Fe, Ni, 103 Rh, Ta, 197 Au, 238 U in the 10-600keV energy range. A non hydrogeneous liquid scintillator was used to detect the gamma from the cascade. The neutron flux was measured with a 10 B INa(Tl) detector or a 6 Li glass scintillator of well known efficiency. The fast time-of-flight technique was used with on line digital computer data processing [fr

  9. Thick brane in f(R) gravity with Palatini dynamics

    Energy Technology Data Exchange (ETDEWEB)

    Bazeia, D.; Losano, L. [Universidade Federal da Paraiba, Departamento de Fisica, Joao Pessoa, PB (Brazil); Menezes, R. [Universidade Federal da Paraiba, Departamento de Ciencias Exatas, Rio Tinto, PB (Brazil); Universidade Federal de Campina Grande, Departamento de Fisica, Campina Grande, PB (Brazil); Olmo, Gonzalo J. [Universidade Federal da Paraiba, Departamento de Fisica, Joao Pessoa, PB (Brazil); Universidad de Valencia, Departamento de Fisica Teorica, IFIC, Centro Mixto Universidad de Valencia-CSIC, Burjassot, Valencia (Spain); Rubiera-Garcia, D. [Universidade Federal da Paraiba, Departamento de Fisica, Joao Pessoa, PB (Brazil); Universidade de Lisboa, Faculdade de Ciencias, Instituto de Astrofisica e Ciencias do Espaco, Lisbon (Portugal); Fudan University, Department of Physics, Center for Field Theory and Particle Physics, Shanghai (China)

    2015-12-15

    This work deals with modified gravity in five-dimensional space-time. We study a thick Palatini f(R) brane, that is, a braneworld scenario described by an anti-de Sitter warped geometry with a single extra dimension of infinite extent, sourced by a real scalar field under the Palatini approach, where the metric and the connection are regarded as independent degrees of freedom. We consider a first-order framework which we use to provide exact solutions for the scalar field and warp factor. We also investigate a perturbative scenario such that the Palatini approach is implemented through a Lagrangian f(R) = R + εR{sup n}, where the small parameter ε controls the deviation from the standard thick brane case. In both cases it is found that the warp factor tends to localize the extra dimension due to the nonlinear corrections. (orig.)

  10. 75 FR 33705 - Pesticide Management and Disposal; Standards for Pesticide Containers and Containment; Change to...

    Science.gov (United States)

    2010-06-15

    ... Pesticide Management and Disposal; Standards for Pesticide Containers and Containment; Change to Labeling... the pesticide container and containment regulations to provide a 4-month extension of the 40 CFR 156... pesticide labels to comply with the label requirements in the container and containment regulations. DATES...

  11. Physical attributes of anisotropic compact stars in f(R, G) gravity

    Energy Technology Data Exchange (ETDEWEB)

    Shamir, M.F.; Zia, Saeeda [National University of Computer and Emerging Sciences, Department of Sciences and Humanities, Lahore (Pakistan)

    2017-07-15

    Modified gravity is one of the potential candidates to explain the accelerated expansion of the universe. Current study highlights the materialization of anisotropic compact stars in the context of f(R, G) theory of gravity. In particular, to gain insight in the physical behavior of three stars namely, Her X1, SAX J 1808-3658 and 4U 1820-30, energy density, and radial and tangential pressures are calculated. The f(R, G) gravity model is split into a Starobinsky like f(R) model and a power law f(G) model. The main feature of the work is a 3-dimensional graphical analysis in which, anisotropic measurements, energy conditions and stability attributes of these stars are discussed. It is shown that all three stars behave as usual for positive values of the f(G) model parameter n. (orig.)

  12. Health risk assessment of pesticides and polychlorinated biphenyls contaminations in dairy products from selected farms in Greater Accra Region - Ghana

    International Nuclear Information System (INIS)

    Amoako, D.

    2013-07-01

    The residual concentrations of synthetic chemicals such as organochlorines pesticides (OCPs), pyrethroids and polychlorinated biphenyls (PCBs) in dairy products (milk, yoghurt, cheese) from selected farms in Greater Accra were analyzed using Gas Chromatography (GC). A total of 50 samples of dairy products (9 cheese, 25 cow milk and 16 yogourt) were analyzed for OCPs, prethroids and PCBs. Of the numerious pesticides evaluated, detectable levels of OCPs (β-HCH, endrin, heptachlor, endosulfan, p ' p-DDT and methoxchlor); synthetic prethroids (permathrin, allethrin, cypermethrin and deltamethrin) and PCBs (18, 28, 52, 101, 153, 138, and 180) were found in all the dairy product samples analysed. Milk samples were found to be the most contaminated with respect to the OCPs and the levels ranged between 0.0001µg/ml and 0.0407µg/ml. ß-HCH was the highest OCP with concentration of 0.0407µg/ml while cyfluthrin was the highest synthetic prethroids recorded in yoghurt sample (0.0318µg/ml). The highest PCB 18 (2,2,5-Trichlorobiphenyl) recorded (0.2668µg/ml) in yoghurt samples. (Data obtained from the field survey regarding safe use of pesticides, toxicity awareness and symptoms among farmers indicated that a very high proportion of animal farmers were at a high risk of pesticide poisoning from occupational exposure. More than 70% of farm workers did not practise safety precaution during pesticide mixing and application leading to considerable prevalence of pesticide related illness including nausea, vomiting, blurred vision, abdominal cramps, dizziness, diarrhoea and headaches in this agricultural community. The presence of pesticide residues in dairy products was of further concern because milk is the main protein diet for infants. The estimated dose for γ-chlordane(8.5x10 5 µ/ml), endrin(0.0114 µg/ml) p ' p ' -DDT(8.5x10 5 µg/ml), DDE(8.5x10 5 µg/ml),heptachlor(2.5x10 5 µg/ml), dieldrin(6.8x10 5 µg/ml) do not pose a direct hazard to human health, although present

  13. Identification d’une nouvelle molécule d’intérêt chez le cheval atteint d’obstruction récurrente des voies respiratoires: La Pentraxine 3

    OpenAIRE

    Ramery, Eve

    2010-01-01

    L’ORVR ou obstruction récurrente des voies respiratoires (ORVR) est la cause la plus fréquente de maladie pulmonaire chronique chez le cheval adulte. La maladie se caractérise par une hyperréactivité bronchique, une production excessive de mucus et une inflammation neutrophilique pulmonaire qui ont pour effet de réduire la compliance dynamique du poumon et d’augmenter la résistance des voies respiratoires au débit aérien. Alors que la maladie est une entité documentée dans la littérature depu...

  14. Enhanced fullerene–Au(111 coupling in (2√3 × 2√3R30° superstructures with intermolecular interactions

    Directory of Open Access Journals (Sweden)

    Michael Paßens

    2015-06-01

    Full Text Available Disordered and uniform (2√3 × 2√3R30° superstructures of fullerenes on the Au(111 surface have been studied using scanning tunneling microscopy and spectroscopy. It is shown that the deposition and growth process of a fullerene monolayer on the Au(111 surface determine the resulting superstructure. The supply of thermal energy is of importance for the activation of a Au vacancy forming process and thus, one criterion for the selection of the respective superstructure. However, here it is depicted that a vacancy–adatom pair can be formed even at room temperature. This latter process results in C60 molecules that appear slightly more bright in scanning tunnelling microscopy images and are identified in disordered (2√3 x 2√3R30° superstructures based on a detailed structure analysis. In addition, these slightly more bright C60 molecules form uniform (2√3 x 2√3R30° superstructures, which exhibit intermolecular interactions, likely mediated by Au adatoms. Thus, vacancy–adatom pairs forming at room temperature directly affect the resulting C60 superstructure. Differential conductivity spectra reveal a lifting of the degeneracy of the LUMO and LUMO+1 orbitals in the uniform (2√3 x 2√3R30° superstructure and in addition, hybrid fullerene–Au(111 surface states suggest partly covalent interactions.

  15. An Atomically Precise Au10 Ag2 Nanocluster with Red-Near-IR Dual Emission.

    Science.gov (United States)

    Lei, Zhen; Guan, Zong-Jie; Pei, Xiao-Li; Yuan, Shang-Fu; Wan, Xian-Kai; Zhang, Jin-Yuan; Wang, Quan-Ming

    2016-08-01

    A red-near-IR dual-emissive nanocluster with the composition [Au10 Ag2 (2-py-C≡C)3 (dppy)6 ](BF4 )5 (1; 2-py-C≡C is 2-pyridylethynyl, dppy=2-pyridyldiphenylphosphine) has been synthesized. Single-crystal X-ray structural analysis reveals that 1 has a trigonal bipyramidal Au10 Ag2 core that contains a planar Au4 (2-py-C≡C)3 unit sandwiched by two Au3 Ag(dppy)3 motifs. Cluster 1 shows intense red-NIR dual emission in solution. The visible emission originates from metal-to-ligand charge transfer (MLCT) from silver atoms to phosphine ligands in the Au3 Ag(dppy)3 motifs, and the intense NIR emission is associated with the participation of 2-pyridylethynyl in the frontier orbitals of the cluster, which is confirmed by a time-dependent density functional theory (TD-DFT) calculation. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  16. Évaluation du risque de dysglycémie dans la région de Kitikmeot (Nunavut au moyen de l'outil CANRISK

    Directory of Open Access Journals (Sweden)

    Ying Jiang

    2017-01-01

    Full Text Available Introduction : L'Agence de la santé publique du Canada a adapté un outil finlandais de dépistage du diabète (FINDRISC dans le but de créer un outil, CANRISK, conçu sur mesure pour la population multiethnique du Canada. Cet outil a été élaboré à partir de données recueillies dans sept provinces canadiennes. Dans le but d'élargir son applicabilité aux populations des territoires nordiques, nous avons réalisé une étude auprès de la population majoritairement inuite de la région de Kitikmeot (Nunavut. Méthodologie : Nous avons recueilli des questionnaires CANRISK, des mesures physiques et des échantillons de sang auprès de participants vivant dans cinq collectivités de la région de Kitikmeot. Nous avons utilisé une régression logistique pour évaluer l'ajustement du modèle à l'aide des facteurs de risque de l'outil CANRISK d'origine associés à la dysglycémie (prédiabète et diabète. La dysglycémie a été évaluée au moyen d'un test de glycémie plasmatique à jeun (GPJ administré seul ou avec une épreuve d'hyperglycémie provoquée par voie orale. Nous avons mis au point les scores CANRISK des participants pour tester le fonctionnement de cet outil au sein d'une population inuite. Résultats : Au total, 303 personnes ont participé à l'étude. La moitié d'entre elles avaient moins de 45 ans, les deux tiers étaient des femmes et 84 % étaient inuites. Sur les 303 participants, 18 % étaient atteints de prédiabète et 4 % avaient un diabète non diagnostiqué. La probabilité de présenter un état dysglycémique augmentait de façon exponentielle avec l'âge et la relation avec l'indice de masse corporelle (IMC suivait une courbe en U. Par rapport aux résultats d'analyse en laboratoire, l'outil CANRISK avec un seuil de 32 points a présenté une sensibilité de 61 %, une spécificité de 66 %, une valeur prédictive positive de 34 % et un taux d'exactitude de 65 %. Conclusion : L'outil CANRISK a permis de d

  17. Nuclear modification factors of phi mesons in d+Au, Cu+Cu and Au+Au collisions at sqrt(S_NN)=200 GeV

    Czech Academy of Sciences Publication Activity Database

    Adare, A.; Afanasiev, S.; Aidala, C.; Mašek, L.; Mikeš, P.; Růžička, Pavel; Tomášek, Lukáš; Vrba, Václav

    2011-01-01

    Roč. 83, č. 2 (2011), "024909-1"-"024909-10" ISSN 0556-2813 R&D Projects: GA MŠk LA08015 Institutional research plan: CEZ:AV0Z10100502 Keywords : PHENIX experiment * d+AU collisions Subject RIV: BF - Elementary Particles and High Energy Physics Impact factor: 3.308, year: 2011

  18. Téléphones mobiles, Internet et sexospécificité au Myanmar | CRDI ...

    International Development Research Centre (IDRC) Digital Library (Canada)

    18 déc. 2017 ... Parmi les marchés mobiles les moins exploités au monde, celui du Myanmar se classe toujours au troisième rang en raison du fait que les dirigeants militaires du pays ont étroitement contrôlé les médias et les communications au cours des 50 dernières années. Jusqu'à 2004, même si les réseaux à large ...

  19. rändrat omhändertagande av patienter med uretärsten : - Lärdomar från ett förbättringsarbete

    OpenAIRE

    Khatami, Annelie

    2014-01-01

    Bakgrund: Omkring 10-15 % av befolkningen, oftast i arbetsför ålder, riskerar att någon gång drabbas av njursten. Nationella riktlinjer för njurstensbehandling saknas, men studier stödjer behandling inom 48 timmar för snabb symtomlindring och minskade besvärr patienten. Inom studerad verksamhet var tiden från diagnos till behandling lång och återinläggningarna var många, varför ett förbättringsarbete initierades. Syfte: Syftet med förbättringsarbetet var att halvera tiden från diagnos till...

  20. The synthesis of 18F-labelled amino acid O-(2-[18F]fluoroethyl)-L-tyrosine (FET) in NPI

    Czech Academy of Sciences Publication Activity Database

    Švecová, Helena; Procházka, Libor; Fedorova, S.; Kropáček, Martin; Melichar, František

    2007-01-01

    Roč. 2, č. 331 (2007), s. 34-34 ISSN 1619-7070 R&D Projects: GA MPO 2A-1TP1/055 Institutional research plan: CEZ:AV0Z10480505 Keywords : [18F]FET * PET * tumor imaging Subject RIV: FR - Pharmacology ; Medidal Chemistry

  1. Les infections urinaires chez les patients insuffisants rénaux chroniques hospitalisés au service de néphrologie: profil bactériologique et facteurs de risque

    Science.gov (United States)

    Chemlal, Abdeljalil; Ismaili, Fatiha Alaoui; Karimi, Ilham; Elharraqui, Ryme; Benabdellah, Nawal; Bekaoui, Samira; Haddiya, Intissar; Bentata, Yassamine

    2015-01-01

    L'infection urinaire chez l'insuffisant rénal est fréquente et particulière dans sa prise en charge diagnostique et thérapeutique. L'objectif de notre étude est de déterminer le profil bactériologique et d’étudier les facteurs de risque des infections urinaires chez le patient insuffisant rénal chronique en milieu de néphrologie. Etude prospective débutée en Septembre 2012 menée au service de néphrologie à l'hôpital régional d'Oujda de l'oriental Marocain. Ont été inclus tous les patients hospitalisés en néphrologie avec une infection urinaire documentée. Nous avons analysé les données démographiques, cliniques, biologiques, et thérapeutiques de nos patients à l'admission et au cours de leurs hospitalisations. 48 épisodes d'infections urinaires chez 43 patients ont été colligés dont 3 enfants. L'incidence de l'infection urinaire dans notre étude était de 4,65%. La médiane d’âge était de 53 (32-66) années. 60,4% étaient de sexe féminin. Le germe isolé était un Escheria Coli dans 58,3% et un Klebsiella dans 29,2%. Le germe isolé était résistant à l'amoxicilline-acide clavulanique dans 83% des cas. L'antibiotique prescris en premiére intention chez nos patients était une céphalosporine de 3 éme génération dans 50%. L’évolution chez nos patients était favorable dans 89,6% des cas. 33,3% avaient présenté un sepsis et on a noté le décès dans 10,4% des cas. Les infections urinaires chez l'insuffisant rénal chronique reste très grave vu leur lourde morbi-mortalié d'où l'intêrét d'un dépistage précoce chez cette population. Un usage raisonné des antibiotiques est nécessaire afin de prévenir l'extension des résistances bactériennes. PMID:26213601

  2. Combined exposure to endocrine disrupting pesticides impairs parturition, causes pup mortality and affects sexual differentiation in rats

    DEFF Research Database (Denmark)

    Jacobsen, Pernille Rosenskjold; Christiansen, Sofie; Boberg, Julie

    2010-01-01

    Risk assessment is currently based on the no observed adverse effect levels (NOAELs) for single compounds. Humans are exposed to a mixture of chemicals and recent studies in our laboratory have shown that combined exposure to endocrine disrupters can cause adverse effects on male sexual development...... were gavaged during gestation and lactation with five doses of a mixture of the fungicides procymidone, mancozeb, epoxyconazole, tebuconazole and prochloraz. The mixture ratio was chosen according to the doses of each individual pesticide that produced no observable effects on pregnancy length and pup...... survival in our laboratory and the dose levels used ranged from 25 to 100% of this mixture. All dose levels caused increased gestation length and dose levels above 25% caused impaired parturition leading to markedly decreased number of live born offspring and high pup perinatal mortality. The sexual...

  3. Generalisation for regular black holes on general relativity to f(R) gravity

    Energy Technology Data Exchange (ETDEWEB)

    Rodrigues, Manuel E. [Universidade Federal do Para Campus Universitario de Abaetetuba, Faculdade de Ciencias Exatas e Tecnologia, Abaetetuba, Para (Brazil); Universidade Federal do Para, Faculdade de Fisica, PPGF, Belem, Para (Brazil); Fabris, Julio C. [Universidade Federal do Espirito Santo, Vitoria, ES (Brazil); National Research Nuclear University MEPhI, Moscow (Russian Federation); Junior, Ednaldo L.B. [Universidade Federal do Para, Faculdade de Fisica, PPGF, Belem, Para (Brazil); Universidade Federal do Para, Campus Universitario de Tucurui, Faculdade de Engenharia da Computacao, Tucurui, Para (Brazil); Marques, Glauber T. [Universidade Federal Rural da Amazonia ICIBE - LASIC, Belem, PA (Brazil)

    2016-05-15

    IIn this paper, we determine regular black hole solutions using a very general f(R) theory, coupled to a nonlinear electromagnetic field given by a Lagrangian L{sub NED}. The functions f(R) and L{sub NED} are in principle left unspecified. Instead, the model is constructed through a choice of the mass function M(r) presented in the metric coefficients. Solutions which have a regular behaviour of the geometric invariants are found. These solutions have two horizons, the event horizon and the Cauchy horizon. All energy conditions are satisfied in the whole space-time, except the strong energy condition (SEC), which is violated near the Cauchy horizon.We present also a new theorem related to the energy conditions in f(R) gravity, re-obtaining the well-known conditions in the context of general relativity when the geometry of the solution is the same. (orig.)

  4. Static spherically symmetric wormholes in f(R, T) gravity

    Energy Technology Data Exchange (ETDEWEB)

    Zubair, M.; Ahmad, Yasir [Institute Of Information Technology, Department of Mathematics, COMSATS, Lahore (Pakistan); Waheed, Saira [Prince Mohammad Bin Fahd University, Al Khobar (Saudi Arabia)

    2016-08-15

    In this work, we explore wormhole solutions in f(R, T) theory of gravity, where R is the scalar curvature and T is the trace of stress-energy tensor of matter. To investigate this, we consider a static spherically symmetric geometry with matter contents as anisotropic, isotropic, and barotropic fluids in three separate cases. By taking into account the Starobinsky f(R) model, we analyze the behavior of energy conditions for these different kinds of fluids. It is shown that the wormhole solutions can be constructed without exotic matter in few regions of space-time. We also give the graphical illustration of the results obtained and discuss the equilibrium picture for the anisotropic case only. It is concluded that the wormhole solutions with anisotropic matter are realistic and stable in this theory of gravity. (orig.)

  5. Direct flow in 10.8 GeV/nucleon Au+Au collisions measured in experiment E917 at the AGS

    International Nuclear Information System (INIS)

    Back, B. B.; Betts, R. R.; Britt, H. C.; Chang, J.; Chang, W. C.; Gillitzer, A.; Henning, W. F.; Hofman, D. J.; Nanal, V.; Wuosmaa, A. H.

    1999-01-01

    Analysis of directed flow observable for protons and pions from Au+Au collisions at 10.8 GeV/nucleon from experiment E917 at the AGS is presented. Using a Fourier series expansion, the first Fourier component, ν 1 ,was extracted as a function of rapidity for mid-central collisions (17-24%). Clear evidence for positive directed flow is found in the proton data, and a weak, possibly negative directed flow signal is observed for π + and π -

  6. L’apprentissage au cern

    CERN Multimedia

    2007-01-01

    pour les professions d’électronicien(ne) et de laborantin(e) en physique L’apprentissage au CERN est régi par les lois, règlements et contrats en vigueur dans le canton de Genève. En cas de réussite à l’examen de fin d’apprentissage, les apprentis obtiennent le Certificat fédéral de capacité suisse (CFC). 6 places au total sont ouvertes au recrutement pour les deux professions. L’apprentissage dure 4 ans. Minima requis pour faire acte de candidature : avoir au moins 15 ans et moins de 21 ans à la date de début de l’apprentissage ; avoir terminé la scolarité obligatoire, au minimum 9e du Cycle d’orientation genevois (3e en France) ; être ressortissant d’un pays membre du CERN (Allemagne, Autriche, Belgique, Bulgarie, Danemark, Espagne, Finlande, France, Grèce, Hongrie, Italie, Norvège, Pays-Bas, Pologne, Portugal, Royaume-Uni, République tchèque, République slovaque , Suède, Suisse) ; pour les résidents en Suisse : être ressortissant su...

  7. Determination of Organophosphorous Pesticides in Environmental Water Samples Using Surface-Engineered C18 Functionalized Silica-Coated Core-Shell Magnetic Nanoparticles-Based Extraction Coupled with GC-MS/MS Analysis.

    Science.gov (United States)

    Srivastava, Neha; Kumari, Supriya; Nair, Kishore; Alam, Samsul; Raza, Syed K

    2017-05-01

    The present paper depicts a novel method based on magnetic SPE (MSPE) for the determination of organophosphorus pesticides (OPs) such as phorate, malathion, and chlorpyrifos in environmental water samples. In this study, C18 functionalized silica-coated core-shell iron oxide magnetic nanoparticles (MNPs) were used as a surface-engineered magnetic sorbent for the selective extraction of pesticides from aqueous samples, followed by GC-MS and GC-tandem MS analysis for confirmative determination of the analytes. Various important method parameters, including quantity of MNP adsorbent, volume of sample, effective time for extraction, nature of the desorbing solvent, and pH of the aqueous sample, were investigated and optimized to obtain maximum method performance. Under the optimized instrumental analysis conditions, good linearity (r2 value ≥0.994) was achieved at the concentration range of 0.5-500 μg/L. Recoveries were in the range of 79.2-96.3 and 80.4-97.5% in selective-ion monitoring and multiple reaction monitoring (MRM) modes, respectively, at the spiking concentrations of 1, 5, and 10 μg/L. MRM mode showed better sensitivity, selectivity, and low-level detection (0.5 μg/L) of analytes. The novel MSPE method is a simple, cheap, rapid, and eco-friendly method for the determination of OPs in environmental water samples.

  8. Evaluation of F-18-labeled amino acid derivatives and [18F]FDG as PET probes in a brain tumor-bearing animal model

    International Nuclear Information System (INIS)

    Wang, H.-E.; Wu, S.-Y.; Chang, C.-W.; Liu, R.-S.; Hwang, L.-C.; Lee, T.-W.; Chen, J.-C.; Hwang, J.-J.

    2005-01-01

    2-Deoxy-2-[ 18 F]fluoro-D-glucose ([ 18 F]FDG) has been extensively used as positron emission tomography (PET) tracer in clinical tumor imaging. This study compared the pharmacokinetics of two 18 F-labeled amino acid derivatives, O-2-[ 18 F]fluoroethyl-L-tyrosine (L-[ 18 F]FET) and 4-borono-2-[ 18 F]fluoro-L-phenylalanine-fructose (L-[ 18 F]FBPA-Fr), to that of [ 18 F]FDG in an animal brain tumor model. Methods: A self-modified automated PET tracer synthesizer was used to produce no-carrier-added (nca) L-[ 18 F]FET. The cellular uptake, biodistribution, autoradiography and microPET imaging of L-[ 18 F]FET, L-[ 18 F]FBPA-Fr and [ 18 F]FDG were performed with F98 glioma cell culture and F98 glioma-bearing Fischer344 rats. Results: The radiochemical purity of L-[ 18 F]FET was >98% and the radiochemical yield was 50% in average of 16 runs. The uptake of L-[ 18 F]FET and L-[ 18 F]FBPA-Fr in the F98 glioma cells increased rapidly for the first 5 min and reached a steady-state level after 10 min of incubation, whereas the cellular uptake of [ 18 F]FDG kept increasing during the study period. The biodistribution of L-[ 18 F]FET, L-[ 18 F]FBPA-Fr and [ 18 F]FDG in the brain tumors was 1.26±0.22, 0.86±0.08 and 2.77±0.44 %ID/g at 60 min postinjection, respectively, while the tumor-to-normal brain ratios of L-[ 18 F]FET (3.15) and L-[ 18 F]FBPA-Fr (3.44) were higher than that of [ 18 F]FDG (1.44). Both microPET images and autoradiograms of L-[ 18 F]FET and L-[ 18 F]FBPA-Fr exhibited remarkable uptake with high contrast in the brain tumor, whereas [ 18 F]FDG showed high uptake in the normal brain and gave blurred brain tumor images. Conclusion: Both L-[ 18 F]FET and L-[ 18 F]FBPA-Fr are superior to [ 18 F]FDG for the brain tumor imaging as shown in this study with microPET

  9. Au-Pt-Au nanoraspberry structures used for mercury ion detection

    Science.gov (United States)

    Huang, Jiang-Hao; Huang, Shuai; Wen, Xiaoyan; Li, Min; Lu, Haifei

    2017-12-01

    Detection of Hg2+ with high sensitivity is of great significance in the biochemical sensing field. Quantitative of Hg2+ was realized based on the influence of Hg2+ on the UV-vis absorption performance of Au-Pt-Au core-shell nanoraspberry (APA)-rhodamine-6G (R6G) structure. First, APA sol was added into R6G indicator solution and the UV-vis absorption signal intensity of R6G was evidently promoted. The signal intensity monotonously increased as more APA sol was added. However, when HgCl2 solution was introduced, the signal intensity declined. A linear relationship between Hg2+ concentration and signal intensity at 527 nm was revealed, based on which quantitative determination of Hg2+ could be realized. Hg2+ detection sensitivity was measured to be 0.031 a.u./M with a limit of detection of 10-7 M and the response time was 20 s. A high Hg2+ detection selectivity over Cu2+, Na+, Li+, and K+ was demonstrated. Due to its simplicity and high sensitivity, the proposed method could find an extensive application prospect in the Hg2+ detection field.

  10. La Cyberdépendance: Cas de l’addiction au réseau social Facebook

    Directory of Open Access Journals (Sweden)

    Houssem Edine Nasr

    2015-09-01

    Full Text Available La démocratisation de l’internet et la forte pénétration des réseaux sociaux dans la vie de tous les jours des internautes a montré un comportement d’addiction au réseau social Facebook. Malgré l’importance de ce phénomène, très peu de recherches en marketing se sont intéressées à son étude. La présente recherche a pour objectif de mesurer l’addiction des internautes aux réseaux sociaux et d’en déterminer les antécédents. La revue de la littérature relative à l’internet a mis en relief que l’estime de soi et la personnalité sont des antécédents psychologiques de l’addiction. L’enquête par questionnaire que nous avons menée sur Facebook auprès d’un échantillon de convenance de 252 internautes a révélé que trois dimensions sur cinq de la personnalité à savoir l’ouverture aux expériences, l’agréabilité et le névrosisme, sont en relation faible avec la cyberdépendance au réseau social Facebook. Par ailleurs, la variable âge et le nombre d’amis sur Facebook sont en corrélation avec la cyberdépendance à ce réseau social.

  11. Electrochemical Impedance Study of Reduction Kinetics of the Pesticide Vinclozoline

    Czech Academy of Sciences Publication Activity Database

    Pospíšil, Lubomír; Sokolová, Romana; Colombini, M. P.; Giannarelli, S.; Fuoco, R.

    2000-01-01

    Roč. 67, - (2000), s. 305-312 ISSN 0026-265X R&D Projects: GA MŠk OC D15.10; GA ČR GA203/97/1048 Institutional research plan: CEZ:AV0Z4040901 Keywords : electrochemical impedance * pesticide s * vinclozoline Subject RIV: CG - Electrochemistry Impact factor: 0.884, year: 2000

  12. 18 Étude pour synchronisation des réseaux électriques de la ...

    African Journals Online (AJOL)

    Alex KPODE

    au même résultat. Quant à HAMMOUD Asif, dans ses travaux de recherche « Etude des convertisseurs haute tension pour la protection et la coordination des réseaux de distribution » [5], il a surtout mos l'accent sur la protection lors de couplage des deux réseaux. Dans son mémoire intitulé « la conception, la modélisation ...

  13. Perspectives d'introduction d'un marketing des services au sein des banques publiques Algériennes : Cas de la B.A.D.R.

    OpenAIRE

    Lachachi-taleb, Meriem

    2014-01-01

    Le premier chapitre présente les fondements théoriques relatifs au marketing des services ainsi qu'au concept de servuction et enfin au marketing mix des services dans le deuxiéme chapitre.Le troisiéme chapitre est consacré au marketing bancaire et au plan marketing dans le chapitre suivant, une étude de cas au sein de la B.A.D.R.Banque.

  14. Power-law cosmic expansion in f(R) gravity models

    International Nuclear Information System (INIS)

    Goheer, Naureen; Larena, Julien; Dunsby, Peter K. S.

    2009-01-01

    We show that within the class of f(R) gravity theories, Friedmann-Lemaitre-Robertson-Walker power-law perfect fluid solutions only exist for R n gravity. This significantly restricts the set of exact cosmological solutions which have similar properties to what is found in standard general relativity.

  15. Niveaux de résidus de pesticides organochlorés dans les produits ...

    African Journals Online (AJOL)

    L'objectif de cette étude est de déterminer le contenu en résidus de quelques pesticides organochlorés du cacao masse, des tourteaux et du beurre de cacao. Pour se faire, 75 échantillons de fèves de cacao ont été prélevés auprès des planteurs et coopératives du département d'Agboville et des exportateurs des ports de ...

  16. SERS-active Ag, Au and Ag–Au alloy nanoparticles obtained by laser ablation in liquids for sensing methylene blue

    Energy Technology Data Exchange (ETDEWEB)

    Olea-Mejía, Oscar, E-mail: oleaoscar@yahoo.com.mx [Centro Conjunto de Investigación en Química Sustentable UAEM-UNAM, Universidad Autónoma del Estado de México, km 14.5 Carretera Toluca-Atlacomulco, San Cayetano 50200, México (Mexico); Fernández-Mondragón, Mariana; Rodríguez-de la Concha, Gabriela [Centro Conjunto de Investigación en Química Sustentable UAEM-UNAM, Universidad Autónoma del Estado de México, km 14.5 Carretera Toluca-Atlacomulco, San Cayetano 50200, México (Mexico); Camacho-López, Marco [Laboratorio de Investigación y Desarrollo de Materiales Avanzados, Universidad Autónoma del Estado de México, Km 14.5 Carretera Toluca-Atlacomulco, San Cayetano 50925, México (Mexico)

    2015-09-01

    Highlights: • We synthesized Ag/Au nanoparticles by laser ablation in liquids. • We characterized such particles by UV–vis, TEM and EDS/STEM. • The SERS effect was studied for the obtained nanoparticles. • Pure silver nanoparticles showed the highest SERS signals. • We can sense methylene blue at a concentration of 10{sup −10} mole/L. - Abstract: We have synthesized Ag–Au nanoparticles by laser ablation in liquids using five different targets: 100% Ag, 80%Ag/20%Au, 50%Ag/50%Au, 20%Ag/80%Au and 100% Au (weight percentages). We used ethanol and methylene blue solutions in ethanol as the liquid media. The nanoparticles were mostly spherical with diameters 15, 19, 18, 23 and 11 nm, respectively. When alloyed targets were used, the resulting nanoparticles were completely alloyed forming solid solutions as evidenced by UV–vis Spectroscopy and Scanning Transmission Electron Microscopy. The obtained nanoparticles were employed to study the SERS effect of the methylene blue molecule. All the samples showed good SERS activity, however the ones composed of pure silver showed the greatest Raman signal enhancement. Finally, pure Ag nanoparticles were used for sensing methylene blue at different concentrations. While almost no signal can be discerned from the Raman spectrum when no particles are used at a concentration of methylene blue of 1 × 10{sup −2} M (∼3000 ppm), when Ag nanoparticles are used one can observe the characteristic peak of the molecule at concentrations as low as 1 × 10{sup −10} M (∼3 × 10{sup −5} ppm)

  17. Fate of 14 C Labelled fungicides maneb and mancozeb during processing of contaminated soybean oil

    International Nuclear Information System (INIS)

    Zayed, S.M.A.D.; Hegazi, B.

    1991-01-01

    Soybeans from plants previously treated with 14 C-maneb and 14 C-mancozeb contain 0.62% and 3.15% of the applied dose, respectively. Crude soybean soil extracted from seeds was subjected to different refining processes. The effect of commercial refining processes, namely: alkali treatment, bleacking, winterization and deoderization on the nature and magnitude of the original residues was investigated. A high percentage of the residues was eliminated by alkali refining and deoderization processes. Analysis of residues after each step showed the ETU, ETM and ETD, in addition to two unknowns where the main 14 C-residues present in the oil. The refined oil contains around 1% of the residues originally present in the crude soybean oil.4 tab

  18. Pesticide Applicator Profiling: Using Polycom[R] Distance Delivery for Continuing Education and Characterizing Florida's Licensed Applicators

    Science.gov (United States)

    Fishel, Fred; Langeland, Ken

    2011-01-01

    The University of Florida offers continuing education units (CEUs) via distance technology using Polycom[R] to meet requirements for applicators of pesticides to renew their licenses. A large statewide event conducted in 2010 also included a needs assessment of this group concerning CEUs. Results indicate that these applicators strongly prefer…

  19. The simplest non-minimal matter-geometry coupling in the f(R, T) cosmology

    Energy Technology Data Exchange (ETDEWEB)

    Moraes, P.H.R.S. [ITA - Instituto Tecnologico de Aeronautica, Departamento de Fisica, Sao Paulo (Brazil); Sahoo, P.K. [Birla Institute of Technology and Science-Pilani, Department of Mathematics, Hyderabad (India)

    2017-07-15

    f(R, T) gravity is an extended theory of gravity in which the gravitational action contains general terms of both the Ricci scalar R and the trace of the energy-momentum tensor T. In this way, f(R, T) models are capable of describing a non-minimal coupling between geometry (through terms in R) and matter (through terms in T). In this article we construct a cosmological model from the simplest non-minimal matter-geometry coupling within the f(R, T) gravity formalism, by means of an effective energy-momentum tensor, given by the sum of the usual matter energy-momentum tensor with a dark energy contribution, with the latter coming from the matter-geometry coupling terms. We apply the energy conditions to our solutions in order to obtain a range of values for the free parameters of the model which yield a healthy and well-behaved scenario. For some values of the free parameters which are submissive to the energy conditions application, it is possible to predict a transition from a decelerated period of the expansion of the universe to a period of acceleration (dark energy era). We also propose further applications of this particular case of the f(R, T) formalism in order to check its reliability in other fields, rather than cosmology. (orig.)

  20. The simplest non-minimal matter-geometry coupling in the f(R, T) cosmology

    International Nuclear Information System (INIS)

    Moraes, P.H.R.S.; Sahoo, P.K.

    2017-01-01

    f(R, T) gravity is an extended theory of gravity in which the gravitational action contains general terms of both the Ricci scalar R and the trace of the energy-momentum tensor T. In this way, f(R, T) models are capable of describing a non-minimal coupling between geometry (through terms in R) and matter (through terms in T). In this article we construct a cosmological model from the simplest non-minimal matter-geometry coupling within the f(R, T) gravity formalism, by means of an effective energy-momentum tensor, given by the sum of the usual matter energy-momentum tensor with a dark energy contribution, with the latter coming from the matter-geometry coupling terms. We apply the energy conditions to our solutions in order to obtain a range of values for the free parameters of the model which yield a healthy and well-behaved scenario. For some values of the free parameters which are submissive to the energy conditions application, it is possible to predict a transition from a decelerated period of the expansion of the universe to a period of acceleration (dark energy era). We also propose further applications of this particular case of the f(R, T) formalism in order to check its reliability in other fields, rather than cosmology. (orig.)

  1. Camps de réfugiés et environnement au Kenya : enjeux et contradictions

    OpenAIRE

    Cambrézy, Luc

    2001-01-01

    Dans les camps de réfugiés de Dadaab, au Kenya, un programme de protection environnementale et de réhabilitation du couvert végétal a été mis en place plusieurs années avant tout réel diagnostic sur l'ampleur et l'origine réelle des dégradations constatées. Des études ultérieures ont montré que les auréoles de dégradation autour des camps semblent essentiellement imputables aux besoins ligneux pour la construction et la maintenance des nombreuses infrastructures et non pas à la collecte de bo...

  2. Mouline Nabil, Le califat imaginaire d’Ahmad al-Mansûr. Pouvoir et diplomatie au Maroc au xvie siècle, PUF, Proche-Orient, Paris, 2009, 371 p.

    Directory of Open Access Journals (Sweden)

    Halima Ferhat

    2010-09-01

    Full Text Available Au lendemain de la bataille des Trois Rois, plus connue au Maroc sous le nom de Ouad al Makhazin, de redoutables acteurs s’affrontent : les Habsbourgs d’Espagne et leurs ennemis protestants aux Pays Bas, l’Angleterre, le Portugal dont l’autonomie est désormais remise en question, ainsi que de multiples petits princes locaux et les maîtres des zaouyas sans oublier les corsaires qui, il faut le rappeler, forment un réseau qui n’est pas toujours à l’ordre d’un pays. Plusieurs excellents livres r...

  3. Study of the effect of an increase in phosphorus content on the corrosion resistance of austenitic stainless steels type 18-10

    International Nuclear Information System (INIS)

    Charbonnier, J.C.; Thomas, B.

    1982-01-01

    The work is carried out on Z 6 CN 18-10 steels with P concentrations in the range of 0.004 to 0.127%, to examine intercrystalline corrosion, pitting corrosion and cavern corrosion. It is concluded that a slight increase in the P content above 0.04% is compatible with an acceptable corrosion behaviour [fr

  4. Faut-il réformer la caisse de compensation au Maroc ?

    OpenAIRE

    Tarbalouti, Mr

    2014-01-01

    Faut-il réformer la caisse de compensation au Maroc? Par Essaid Tarbalouti Version, Mars 2014 The debate on the efficiency of the subsidy of the prices of foodstuffs granted by the policy of compensation and his reform are deeply livened up between the government and the opposition in terms of its cost and its ineffectiveness. This debate concentrate on the social earnings to replace this mechanism of assistant by the granting of a minimum income to the poor people. We...

  5. Microstructures and coherent phase diagram for the pseudobinary system (AuCu)1-xPd x with x ≤ 0.10

    International Nuclear Information System (INIS)

    Luciano, Rhodora H.; Shiraishi, Takanobu; Udoh, Koh-ichi; Tanaka, Yasuhiro; Hisatsune, Kunihiro

    2005-01-01

    A coherent phase diagram for the pseudobinary system (AuCu) 1-x Pd x with x ≤ 0.10 was constructed based on phase identification and microstructural analysis by transmission electron microscopy. It was confirmed that the addition of palladium exceeding 1.0 at.% to the equiatomic AuCu eliminated the AuCu II long-period superstructure from the phase equilibria and stabilized the AuCu I superstructure. The AuCu-0.5 at.% Pd and AuCu-1.0 at.% Pd alloys isothermally aged for long time at temperatures ranging from 380 to 420 deg. C exhibited seven distinguishable regions; a single-phase region of disordered solid solution (α); a single-phase region of AuCu I ordered phase; a single-phase region of AuCu II ordered phase; a region of the coexisting AuCu I and AuCu II ordered phases; a region of the coexisting AuCu I ordered and α phases; a region of the coexisting AuCu II ordered and α phases; and a region of the coexisting AuCu I and AuCu II ordered and α phases

  6. Compact stars in f(R, T) gravity

    Energy Technology Data Exchange (ETDEWEB)

    Das, Amit; Guha, B.K. [Indian Institute of Engineering Science and Technology, Department of Physics, Howrah, West Bengal (India); Rahaman, Farook [Jadavpur University, Department of Mathematics, Kolkata, West Bengal (India); Ray, Saibal [Government College of Engineering and Ceramic Technology, Department of Physics, Kolkata, West Bengal (India)

    2016-12-15

    In the present paper we generate a set of solutions describing the interior of a compact star under f(R, T) theory of gravity which admits conformal motion. An extension of general relativity, the f(R, T) gravity is associated to Ricci scalar R and the trace of the energy-momentum tensor T. To handle the Einstein field equations in the form of differential equations of second order, first of all we adopt the Lie algebra with conformal Killing vectors (CKV) which enable one to get a solvable form of such equations and second we consider the equation of state (EOS) p = ωρ with 0 < ω < 1 for the fluid distribution consisting of normal matter, ω being the EOS parameter. We therefore analytically explore several physical aspects of the model to represent behavior of the compact stars such as - energy conditions, TOV equation, stability of the system, Buchdahl condition, compactness and redshift. It is checked that the physical validity and the acceptability of the present model within the specified observational constraint in connection to a dozen of the compact star candidates are quite satisfactory. (orig.)

  7. Fréjus – Chemins de Valescure

    OpenAIRE

    Cotto, Kelig-Yann

    2013-01-01

    Identifiant de l'opération archéologique : 8306 Date de l'opération : 2007 (EX) Inventeur(s) : Ctto Kelig-Yann (COL) La Société d’économie mixte « Fréjus-Aménagement » ayant en projet la construction d’une vaste zone de logements au lieu-dit Chemins de Valescure, elle a, en 2007, saisi la DRAC d’une demande anticipée de réalisation de diagnostic. Celui-ci a porté sur une surface d’environ 3 ha. Seule la partie sud s’est révélée positive, permettant la mise au jour d’une vaste zone archéologiq...

  8. Brane f(R) gravity and the dark side of the universe

    International Nuclear Information System (INIS)

    Borzou, A.; Sepangi, H. R.; Shahidi, S.; Yousefi, R.

    2009-01-01

    We consider a brane world scenario in which the bulk action is assumed to have the form of a generic function of the Ricci scalar f(R) and derive the resulting Einstein field equation on the brane. In a constant curvature bulk a conserved geometric quantity appears in the field equations which can be associated with matter. We present spherically symmetric solutions which account for galaxy rotation curves in a specific form. Then cosmological solutions by assuming a specific form for f(R) are derived which can explain an accelerated expanding universe.

  9. English for au pairs the au pair's guide to learning English

    CERN Document Server

    Curtis, Lucy

    2014-01-01

    English for Au Pairs has interlinked stories about a group of au pairs new to England. Marta, an 18-year-old from Poland arrives in the UK to work as an au pair. Throughout her year-long stay she has many different experiences - some bad, some good - but with the support of her host family she finds new friends and improves her English. English for Au Pairs offers insight into the joys and difficulties of being an au pair while at the same time reinforcing English language learning through grammar explanations and exercises.

  10. Study of some chaotic inflationary models in f(R) gravity

    Science.gov (United States)

    Sharif, M.; Nawazish, Iqra

    2018-04-01

    In this paper, we discuss an inflationary scenario via scalar field and fluid cosmology for an anisotropic homogeneous universe model in f(R) gravity. We consider an equation of state which corresponds to a quasi-de Sitter expansion and investigate the effect of the anisotropy parameter for different values of the deviation parameter. We evaluate potential models like linear, quadratic and quartic models which correspond to chaotic inflation. We construct the observational parameters for a power-law model of f(R) gravity and construct the graphical analysis of tensor-scalar ratio and spectral index which indicates the consistency of these parameters with Planck 2015 data.

  11. Volume 9 No. 4 2009 August 2009 1191 GENOTOXIC EFFECTS OF ...

    African Journals Online (AJOL)

    pollutants, three doses each of the pesticides, dithane (0.196, 0.391, 0.782 % solution) ... disease causing organisms and by acting against pests in the field and during storage ..... Mancozeb is not taken up from the soil by plants. [26].

  12. Revisiting van der Waals like behavior of f(R AdS black holes via the two point correlation function

    Directory of Open Access Journals (Sweden)

    Jie-Xiong Mo

    2017-05-01

    Full Text Available Van der Waals like behavior of f(R AdS black holes is revisited via two point correlation function, which is dual to the geodesic length in the bulk. The equation of motion constrained by the boundary condition is solved numerically and both the effect of boundary region size and f(R gravity are probed. Moreover, an analogous specific heat related to δL is introduced. It is shown that the T−δL graphs of f(R AdS black holes exhibit reverse van der Waals like behavior just as the T−S graphs do. Free energy analysis is carried out to determine the first order phase transition temperature T⁎ and the unstable branch in T−δL curve is removed by a bar T=T⁎. It is shown that the first order phase transition temperature is the same at least to the order of 1010 for different choices of the parameter b although the values of free energy vary with b. Our result further supports the former finding that charged f(R AdS black holes behave much like RN-AdS black holes. We also check the analogous equal area law numerically and find that the relative errors for both the cases θ0=0.1 and θ0=0.2 are small enough. The fitting functions between log⁡|T−Tc| and log⁡|δL−δLc| for both cases are also obtained. It is shown that the slope is around 3, implying that the critical exponent is about 2/3. This result is in accordance with those in former literatures of specific heat related to the thermal entropy or entanglement entropy.

  13. Association of Paraoxonase-1 Q192R (rs662 Single Nucleotide Variation with Cardiovascular Risk in Coffee Harvesters of Central Colombia

    Directory of Open Access Journals (Sweden)

    Fernando Siller-López

    2017-01-01

    Full Text Available Paraoxonase 1 (PON1, a high-density lipoprotein-associated antioxidant enzyme, hydrolyzes several organophosphate pesticides and oxidized lipids. The PON1 Q192R polymorphism affects the catalytic efficiency and is considered a risk factor for pesticide intoxication and cardiovascular disease (CVD but the association is not consistent between individuals or populations. We aimed to study the association of PON1 Q192R polymorphism with CVD risk in coffee harvesters of central Colombia. Demographics were collected from 205 subjects via standardized questionnaires. Lipid profiles and serum butyrylcholinesterase (BChE were measured by standard procedures. The calculated 10-year atherosclerotic CVD (ASCVD risk was used as the cardiovascular risk estimate. Q192R genotype was determined by real-time PCR. Prevalence of hypertension, hypercholesterolemia, and the 10-year ASCVD risk was 33%, 62%, and 22%, respectively. BChE levels were no indicative of recent pesticide exposure, although a positive correlation was observed with BChE and hypercholesterolemia. The Q192R genotype frequencies were 38% (QQ, 44% (QR, and 18% (RR. We found an association of the 192Q genotype with hypertension. The results of this study signal the importance to evaluate the influence and potential interactions of BChE and PON1 192Q allele with known genetic and environmental factors implicated in the pathogenesis of CVD.

  14. Evaluating item endorsement rates for the MMPI-2-RF F-r and Fp-r scales across ethnic, gender, and diagnostic groups with a forensic inpatient sample.

    Science.gov (United States)

    Glassmire, David M; Jhawar, Amandeep; Burchett, Danielle; Tarescavage, Anthony M

    2017-05-01

    The Minnesota Multiphasic Personality Inventory-2 (MMPI-2) F(p) (Infrequency-Psychopathology) scale was developed to measure overreporting in a manner that was minimally confounded by genuine psychopathology, which was a problem with using the MMPI-2 F (Infrequency) scale among patients with severe mental illness. Although revised versions of both of these scales are included on the MMPI-2-Restructured Form and used in a forensic context, no item-level research has been conducted on their sensitivity to genuine psychopathology among forensic psychiatric inpatients. Therefore, we examined the psychometric properties of the scales in a sample of 438 criminally committed forensic psychiatric inpatients who were adjudicated as not guilty by reason of insanity and had no known incentive to overreport. We found that 20 of the 21 Fp-r items (95.2%) demonstrated endorsement rates ≤ 20%, with 14 of the items (66.7%) endorsed by less than 10% of the sample. Similar findings were observed across genders and across patients with mood and psychotic disorders. The one item endorsed by more than 20% of the sample had a 23.7% overall endorsement rate and significantly different endorsement rates across ethnic groups, with the highest endorsements occurring among Hispanic/Latino (43.3% endorsement rate) patients. Endorsement rates of F-r items were generally higher than for Fp-r items. At the scale level, we also examined correlations with the Restructured Clinical Scales and found that Fp-r demonstrated lower correlations than F-r, indicating that Fp-r is less associated with a broad range of psychopathology. Finally, we found that Fp-r demonstrated slightly higher specificity values than F-r at all T score cutoffs. (PsycINFO Database Record (c) 2017 APA, all rights reserved).

  15. Importprocessen för inrednings- och gåvoartiklar från USA till Finland : En handbok för företagaren

    OpenAIRE

    Smeds, Desiré; Backlund, Johanna

    2016-01-01

    Det här examensarbetet handlar om import från USA med fokus på inrednings- och gåvoartiklar. I arbetet lyfter vi steg för steg fram de delar som utgör importprocessen hela vägen från hur man hittar en pålitlig leverantör till förtullningen av produkterna här i Finland. Syftet med arbetet är att det skall kunna fungera som en handbok för företag som vill starta en småskalig importverksamhet av inrednings- och gåvoartiklar. Vi tar även upp information om import och internationell handel i a...

  16. De l’acceptabilité sociale au développement local résilient

    OpenAIRE

    Raufflet, Emmanuel

    2014-01-01

    Au cours des dernières années, les enjeux liés à l’acceptabilité sociale des activités économiques, en particulier dans le secteur extractif, se sont imposées comme des enjeux significatifs tant pour les entreprises, en tant qu’investisseurs directs et opérateurs des projets que pour les pouvoirs publics, comme promoteurs de projets de développement économique local et régional. Notre argument principal est que le mode de pensée vers le développement local résilient devrait remplacer celui pr...

  17. Wormholes in viable f(R) modified theories of gravity and weak energy condition

    Energy Technology Data Exchange (ETDEWEB)

    Pavlovic, Petar [Universitaet Hamburg, II. Institut fuer Theoretische Physik, Hamburg (Germany); Sossich, Marko [University of Zagreb, Department of Physics, Faculty of Electrical Engineering and Computing, Zagreb (Croatia)

    2015-03-01

    In this work wormholes in viable f(R) gravity models are analyzed. We are interested in exact solutions for stress-energy tensor components depending on different shape and redshift functions. Several solutions of gravitational equations for different f(R) models are examined. The solutions found imply no need for exotic material, while this need is implied in the standard general theory of relativity. A simple expression for weak energy condition (WEC) violation near the throat is derived and analyzed. High curvature regime is also discussed, as well as the question of the highest possible values of the Ricci scalar for which the WEC is not violated near the throat, and corresponding functions are calculated for several models. The approach here differs from the one that has been common since no additional assumptions to simplify the equations have been made, and the functions in f(R) models are not considered to be arbitrary functions, but rather a feature of the theory that has to be evaluated on the basis of consistency with observations for the Solar System and cosmological evolution. Therefore in this work we show that the existence of wormholes without exotic matter is not only possible in simple arbitrary f(R) models, but also in models that are in accordance with empirical data. (orig.)

  18. 75 FR 56105 - Pesticide Products; Registration Applications

    Science.gov (United States)

    2010-09-15

    ... Products, Inc., 2625 South 158th Plaza, Omaha, NE 68130. Active ingredient: Bifenthrin. Proposed uses: Dogs... ENVIRONMENTAL PROTECTION AGENCY [EPA-HQ-OPP-2010-0008; FRL-8843-5] Pesticide Products... announces receipt of applications to register new uses for pesticide products containing currently...

  19. The effect of perinatal exposure to ethinyl oestradiol or a mixture of endocrine disrupting pesticides on kisspeptin neurons in the rat hypothalamus

    DEFF Research Database (Denmark)

    Overgaard, Agnete; Holst, Klaus; Mandrup, Karen

    2013-01-01

    Early life exposure to endocrine disruptors is considered to disturb normal development of hormone sensitive parameters and contribute to advanced puberty and reduced fecundity in humans. Kisspeptin is a positive regulator of the hypothalamic–pituitary–gonadal axis, and plays a key role in the in......Early life exposure to endocrine disruptors is considered to disturb normal development of hormone sensitive parameters and contribute to advanced puberty and reduced fecundity in humans. Kisspeptin is a positive regulator of the hypothalamic–pituitary–gonadal axis, and plays a key role.......We find that perinatal EE2 exposure did not affect Kiss1 mRNA expression in this study designed to model human exposure to estrogenic compounds, and we find only minor effects on puberty onset. Further, the Kiss1 system does not exhibit persistent changes and puberty onset is not affected after perinatal...... exposure to a pesticide mixture in this experimental setting. However, we find that the pesticide mancozeb tends to increase Kiss1 expression in the ARC, presumably through neurotoxic mechanisms rather than via classical endocrine disruption, calling for increased awareness that Kiss1 expression can...

  20. PON1Q192R genetic polymorphism modifies organophosphorous pesticide effects on semen quality and DNA integrity in agricultural workers from southern Mexico

    International Nuclear Information System (INIS)

    Perez-Herrera, N.; Polanco-Minaya, H.; Salazar-Arredondo, E.; Solis-Heredia, M.J.; Hernandez-Ochoa, I.; Rojas-Garcia, E.; Alvarado-Mejia, J.; Borja-Aburto, V.H.; Quintanilla-Vega, B.

    2008-01-01

    Pesticide exposure, including organophosphorous (OP) insecticides, has been associated with poor semen quality, and paraoxonase (PON1), an enzyme involved in OP deactivation, may have a role on their susceptibility, due to PON1 polymorphisms. Our objective was to evaluate the role of PON1Q192R polymorphism on the susceptibility to OP toxicity on semen quality and DNA integrity in agricultural workers. A cross-sectional study was conducted in farmers with Mayan ascendancy from southeastern Mexico chronically exposed to pesticides; mostly OP. Fifty four agricultural workers (18-55 years old) were included, who provided semen and blood samples. Semen quality was evaluated according to WHO, sperm DNA damage by in situ-nick translation (NT-positive cells), PON1Q192R polymorphism by real-time PCR and serum PON1 activity by using phenylacetate and paraoxon. Two OP exposure indexes were created: at the month of sampling and during 3 months before sampling, representing the exposure to spermatids-spermatozoa and to cells at one spermatogenic cycle, respectively. PON1 192R and 192Q allele frequencies were 0.54 and 0.46, respectively. Significant associations were found between OP exposure at the month of sampling and NT-positive cells and sperm viability in homozygote 192RR subjects, and dose-effect relationships were observed between OP exposure during 3 months before sampling and sperm quality parameters and NT-positive cells in homozygote 192RR farmers. This suggests that cells at all stages of spermatogenesis are target of OP, and that there exists an interaction between OP exposure and PON1Q192R polymorphism on these effects; farmers featuring the 192RR genotype were more susceptible to develop reproductive toxic effects by OP exposure

  1. Labourer: Globalement plus néfaste sur la vie du sol que les pesticides

    DEFF Research Database (Denmark)

    Hupin, Frédérique; Petersen, Søren O.; Krogh, Paul Henning

    2017-01-01

    Danemark ont étudié ces interactions pendant deux ans. Le rapport vient d’être publié au Danemark. Les résultats confirment que les effets des pesticides sur la vie du sol sont assez fortement influen-cés par le type de travail du sol et le type de fertilisation. Dans quelle mesure, dans quel sens, quels......Quels sont les impacts de l’application de produits phytosanitaires sur les populations de vers de terre et des autres organismes du sol ? Ces impacts sont-ils simples et directs ? Ou sont-ils influencés par le travail du sol et la fertilisation ? Des recherches menées à l’université d’Aarhus au...... sont les organismes affectés ? TCS a contacté pour vous les deux principaux protagonistes de l’étude : les chercheurs Danois Søren Petersen et Paul Henning Krogh. What are the impacts of the application of plant protection products on earthworms and other soil organisms? Are these impacts simple...

  2. Intoxicações e uso de pesticidas por agricultores do Município de Paty do Alferes, Rio de Janeiro, Brasil Pesticide use and poisoning among farmers from the county of Paty do Alferes, Rio de Janeiro, Brazil

    Directory of Open Access Journals (Sweden)

    Isabella Fernandes Delgado

    2004-02-01

    Full Text Available Este trabalho é parte de um estudo mais amplo sobre as conseqüências para a saúde da exposição a pesticidas. Em 1997, no Município de Paty do Alferes, Rio de Janeiro, 55 agricultores foram entrevistados sobre o uso de pesticidas, equipamentos de proteção e medidas de higiene, ocorrência de intoxicações, destino das embalagens vazias e o tipo de orientação técnica recebida pelos usuários destes produtos. Os pesticidas mais usados foram inseticidas como a abamectina, os compostos organofosforados e os piretróides, e os fungicidas como o mancozeb, o clorotalonil e produtos à base de cobre. Entre os trabalhadores envolvidos no preparo e/ou aplicação de pesticidas, 92% informaram não usar qualquer tipo de equipamento de proteção individual. 62% dos agricultores entrevistados informaram já ter "passado mal" ao preparar ou aplicar pesticidas. Os sintomas mais freqüentemente citados foram dor de cabeça, enjôo, vômitos, vertigem, irritação da pele e visão embaçada. Destes agricultores, 21% necessitaram de assistência médica e em mais da metade dos casos (51%, em que os lavradores identificaram os pesticidas que usavam quando "passaram mal", foram citados inseticidas organofosforados da classe toxicológica I.This survey is part of a more comprehensive study on the health consequences of pesticide exposure. In the county (municipality of Paty do Alferes, Rio de Janeiro State, Brazil, 55 agricultural workers were interviewed on the use of pesticides, use of personal protective equipment, data on health status, and symptoms related to pesticide exposure, disposal of agrochemical containers, and technical assistance. The most widely used pesticides were insecticides such as abamectin, organophosphate compounds, and pyrethroids, and fungicides such as mancozeb, chlorothalonil, and copper products. As a rule, pesticides are handled carelessly, and 92% of workers involved in the mixing, loading, and spraying of insecticides and

  3. De la parcelle au bassin versant : quelles données pour la modélisation du transfert des pesticides ?

    OpenAIRE

    Queyrel, Wilfried; Schott, Céline; Habets, Florence; Ripoche, Dominique; Launay, Marie; Tallec, Gaëlle; Ansart , P.; Blanchoud, Hélène

    2015-01-01

    La Directive Cadre sur l'Eau suppose la mise en œuvre par les pays membres de l'union européenne de la préservation ou la restauration d'une eau de "bonne qualité" pour les grandes masses d'eau. Cependant, les études réalisées sur le transfert des pesticides restent encore insuffisantes pour évaluer la vulnérabilité des eaux de surface et souterraines. La difficulté réside dans la diversité des molécules utilisées et de leurs propriétés physico-chimiques qui imposent que chaque substance acti...

  4. Familial ring (18) mosaicism in a 23-year-old young adult with 46,XY,r(18) (::p11→q21::)/46,XY karyotype, intellectual disability, motor retardation and single maxillary incisor and in his phenotypically normal mother, karyotype 47,XX,+r(18)(::p11→q21::)/46,XX.

    Science.gov (United States)

    Balci, Sevim; Tümer, Celal; Karaca, Ciğdem; Bartsch, Oliver

    2011-05-01

    We report on a 23-year-old man with craniofacial findings of the holoprosencephaly spectrum disorder (microcephaly, hypotelorism, depressed nasal bridge, single median maxillary central incisor), fusion of C2-C3 vertebrae, intellectual disability, and severe sleep apnea. Chromosome analysis of blood lymphocytes showed 75% ring (18) cells and 25% normal cells, karyotype mos 46,XY,r(18)(::p11→q21::)[75]/46,XY[25]. His mother was phenotypically normal except for a double ureter and bifid renal pelvis as in his son. She had a supernumerary ring (18) in 10% of blood lymphocytes, karyotype mos 47,XX,+r(18)(::p11→q21::)[10]/46,XX[90]. Familial ring (18) is a rare cytogenetic abnormality. This is the first report of a mother with a supernumerary ring (18) and a son with ring (18) mosaicism. Interestingly, the son showed a true mosaicism (mixoploidy) of ring (18) and normal cells. The mother's 46,XX cells could be easily explained by mitotic instability and ring loss during cell division. However, the coexistence of ring (18) and normal cells in the son is unusual. Possibly, during early postzygotic divisions of a 47,XY,+r(18) zygote, two (possibly subsequent) genetic events could have occurred, one when one normal chromosome 18 was lost (resulting in a cell line with ring 18), and one when the ring 18 was lost (resulting in a cell line without ring, "escape to normal"). Alternatively, the zygote of the son could have been 46,XY,r(18), and postzygotic loss of the ring 18 could have resulted in monosomy 18 cells followed by duplication of chromosome 18 in these cells (a rare mechanism for cell survival previously described as "compensatory" isodisomy). Copyright © 2011 Wiley-Liss, Inc.

  5. Apprentissages techniques : L'apprentissage au CERN

    CERN Multimedia

    2004-01-01

    APPRENTISSAGES TECHNIQUES GESTION ET DEVELOPPEMENT DU PERSONNEL HR/PMD L'APPRENTISSAGE AU CERN pour les professions d'électronicien(ne) et de laborantin(e) en physique L'apprentissage au CERN est régi par les lois, règlements et contrats en vigueur dans le Canton de Genève. En cas de réussite à l'examen de fin d'apprentissage, les apprentis obtiennent le Certificat Fédéral de Capacité Suisse (CFC). 7 places au total sont ouvertes au recrutement pour les deux professions. L'apprentissage dure 4 ans. Minima requis pour faire acte de candidature : • avoir au moins 15 ans et moins de 21 ans à la date de début de l'apprentissage • avoir terminé la scolarité obligatoire, au minimum 9ème du Cycle d'orientation genevois (3ème en France) • être ressortissant d'un pays membre du CERN (Allemagne, Autriche, Belgiqu...

  6. Etude séro-épidémiologique de la leishmaniose canine au centre du Maroc

    Science.gov (United States)

    Fellah, Hajiba; Doughmi, Oursula; Maniar, Saâd; Lalami, Abdelhakim El Ouali

    2014-01-01

    Dans le monde, la leishmaniose viscérale humaine est connue pour avoir comme principale source d'infection les Canidés domestiques et sauvages. Au centre du Maroc, les données épidémiologiques, cliniques et parasitologiques sur la leishmaniose canine, sont quasiment inexistantes. Ce travail traite une étude prospective au cours de laquelle 61 sérums canins ont été analysés par un test rapide et par l'immunofluorescence indirecte. La sensibilité du test rapide par rapport à celle de l'immunofluorescence indirecte (IFI) est de 33,33%. La fréquence de la maladie chez les chiens s’élève à 9,83% (Test Rapide) et 24,59% (IFI). 73,33% des cas canins positifs à la sérologie sont asymptomatiques. Ce sont les jeunes chiens de moins de 5 ans qui sont les plus fréquemment atteints avec une sensibilité de la race Berger Allmand à l'infection. Cette étude a permis de mettre en évidence la présence de chiens leishmaniens (15 chiens séropositifs parmi 61) et de prouver l'existence du réservoir canin. Une stratégie de prévention active doit être mise en place. PMID:25852791

  7. Voyager observations of solar wind proton temperature - 1-10 AU

    Science.gov (United States)

    Gazis, P. R.; Lazarus, A. J.

    1982-01-01

    Simultaneous measurements are made of the solar wind proton temperatures by the Voyager 1 and 2 spacecraft, far from earth, and the IMP 8 spacecraft in earth orbit. This technique permits a separation of radial and temporal variations of solar wind parameters. The average value of the proton temperature between 1 and 9 AU is observed to decrease as r (the heliocentric radius) to the -(0.7 + or - 0.2). This is slower than would be expected for adiabatic expansion. A detailed examination of the solar wind stream structure shows that considerable heating occurs at the interface between high and low speed streams.

  8. Agricultural expansion as risk to endangered wildlife: Pesticide exposure in wild chimpanzees and baboons displaying facial dysplasia.

    Science.gov (United States)

    Krief, Sabrina; Berny, Philippe; Gumisiriza, Francis; Gross, Régine; Demeneix, Barbara; Fini, Jean Baptiste; Chapman, Colin A; Chapman, Lauren J; Seguya, Andrew; Wasswa, John

    2017-11-15

    Prenatal exposure to environmental endocrine disruptors can affect development and induce irreversible abnormalities in both humans and wildlife. The northern part of Kibale National Park, a mid-altitude rainforest in western Uganda, is largely surrounded by industrial tea plantations and wildlife using this area (Sebitoli) must cope with proximity to human populations and their activities. The chimpanzees and baboons in this area raid crops (primarily maize) in neighboring gardens. Sixteen young individuals of the 66 chimpanzees monitored (25%) exhibit abnormalities including reduced nostrils, cleft lip, limb deformities, reproductive problems and hypopigmentation. Each pathology could have a congenital component, potentially exacerbated by environmental factors. In addition, at least six of 35 photographed baboons from a Sebitoli troop (17%) have similar severe nasal deformities. Our inquiries in villages and tea factories near Sebitoli revealed use of eight pesticides (glyphosate, cypermethrin, profenofos, mancozeb, metalaxyl, dimethoate, chlorpyrifos and 2,4-D amine). Chemical analysis of samples collected from 2014 to 2016 showed that mean levels of pesticides in fresh maize stems and seeds, soils, and river sediments in the vicinity of the chimpanzee territory exceed recommended limits. Notably, excess levels were found for total DDT and its metabolite pp'-DDE and for chlorpyrifos in fresh maize seeds and in fish from Sebitoli. Imidacloprid was detected in coated maize seeds planted at the edge the forest and in fish samples from the Sebitoli area, while no pesticides were detected in fish from central park areas. Since some of these pesticides are thyroid hormone disruptors, we postulate that excessive pesticide use in the Sebitoli area may contribute to facial dysplasia in chimpanzees and baboons through this endocrine pathway. Chimpanzees are considered as endangered by IUCN and besides their intrinsic value and status as closely related to humans, they

  9. 78 FR 6274 - Withdrawal of Pesticide Petitions for Residues of Pesticide Chemicals in or on Various Commodities

    Science.gov (United States)

    2013-01-30

    ... announced the filing of pesticide petition (PP 4F4281) by Bayer CropScience, Research Triangle Park, North...-imidazolidinecarboxamide in or on the food commodity rapeseed (canola) at 1.0 ppm. On March 7, 2012, Bayer Crop Science... or on cucurbits (crop group 9) at 0.05 parts per million (ppm) and fruiting vegetables (crop group 8...

  10. Biotransformation of pesticides in saturated-zone materials

    Science.gov (United States)

    Hoyle, Blythe L.; Arthur, Ellen L.

    Many studies have been conducted to evaluate pesticide contamination of groundwater in the United States, but investigations of pesticide biotransformation in saturated zones are much less numerous than in surface soils. Because results of studies using soils are not directly applicable to the subsurface, the purpose of this paper is to illustrate examples of pesticide biotransformation in saturated-zone materials. Although it must be considered with caution, the US Environmental Protection Agency's (EPA) "Pesticides in Ground Water Database" was used to focus the discussion on the biotransformation potential of dibromoethane (EDB), atrazine, acetanilide herbicides, and aldicarb, all of which have been detected in groundwater in the United States. Results of more than two dozen studies indicate that a biotransformation potential for these pesticides exists in saturated-zone materials, although for any given pesticide substantial differences in biotransformation occurred. These variations were due both to differences in experimental methods and to heterogeneities in the subsurface materials under investigation. However, because biotransformation mechanisms were not well investigated, it is generally not possible to extrapolate predictions of biotransformation potential beyond the specific sites investigated. These results highlight the need to better understand microbial genetic regulation of biotransformation processes so that genetic information may be effectively incorporated into future investigations of biotransformation potential in the subsurface. Résumé De nombreuses études ont été réalisées pour évaluer le degré de pollution des aquifères par les pesticides aux États-Unis, mais les recherches concernant la biotransformation des pesticides dans les eaux souterraines sont beaucoup moins nombreuses que dans les sols. Du fait que les résultats des études concernant les sols ne sont pas directement applicables au milieu souterrain, le propos de cet

  11. In-plane and out-of-plane emission of nuclear matter in Au+Au collisions

    International Nuclear Information System (INIS)

    Bastid, N.; Dupieux, P.; Ramillien, V.; Alard, J.P.; Amouroux, V.; Berger, L.; Boussange, S.; Fraysse, L.; Ibnouzahir, M.; Montarou, G.

    1995-01-01

    Collective flow effects in Au (E/A = 150 to 800 MeV) on Au collisions measured with the phase I setup of the FOPI detector at GSI - Darmstadt are presented. Directed side ward flow is studied, by the mean transverse momentum in the reaction plane x (y)>, without reaction plane reconstruction. A more quantitative measurement of the global amount of directed side ward flow is also made and some comparisons with the predictions of different QMD versions are given. Experimental results concerning the preferential emission of particles in a direction perpendicular to the reaction plane are also presented. Azimuthal distributions of fragments around the beam axis, with respect to the reaction plane are studied in the mid-rapidity region and the associated R N (out-of-plane/in-plane ratios) are extracted. The dependence of R N upon transverse momentum, centrality, fragment charge and bombarding energy is studied. (authors). 24 refs., 10 figs., 1 tab

  12. 77 FR 74003 - Pesticides; Draft Guidance for Pesticide Registrants on Antimicrobial Pesticide Products With...

    Science.gov (United States)

    2012-12-12

    ... Insecticide, Fungicide, and Rodenticide Act (FIFRA) or are required to register pesticides. The following list... remediation, on nonporous and porous surfaces, for residual activity, for mold prevention, and in heating...

  13. CERN : Nouveaux records lors d'une période d'exploitation au PS/SPS ; Un nouveau rôle pour les ISR ; Deuxième région d'intersection pour le système pp du SPS ; Détermination de la durée de vie du charme ; Calcul en Sicile et au CERN

    CERN Multimedia

    1979-01-01

    CERN : Nouveaux records lors d'une période d'exploitation au PS/SPS ; Un nouveau rôle pour les ISR ; Deuxième région d'intersection pour le système pp du SPS ; Détermination de la durée de vie du charme ; Calcul en Sicile et au CERN

  14. Pesticides in rain in four agricultural watersheds in the United States

    Science.gov (United States)

    Vogel, J.R.; Majewski, M.S.; Capel, P.D.

    2008-01-01

    Rainfall samples were collected during the 2003 and 2004 growing seasons at four agricultural locales across the USA in Maryland, Indiana, Nebraska, and California. The samples were analyzed for 21 insecticides, 18 herbicides, three fungicides, and 40 pesticide degradates. Data from all sites combined show that 7 of the 10 most frequently detected pesticides were herbicides, with atrazine (70%) and metolachlor (83%) detected at every site. Dacthal, acetochlor, simazine, alachlor, and pendimethalin were detected in more than 50% of the samples. Chlorpyrifos, carbaryl, and diazinon were the only insecticides among the 10 most frequently detected compounds. Of the remaining pesticide parent compounds, 18 were detected in fewer than 30% of the samples, and 13 were not detected. The most frequently detected degradates were deethylatrazine; the oxygen analogs (OAs) of the organophosphorus insecticides chlorpyrifos, diazinon, and malathion; and 1-napthol (degradate of carbaryl). Deethylatrazine was detected in nearly 70% of the samples collected in Maryland, Indiana, and Nebraska but was detected only once in California. The OAs of chlorpyrifos and diazinon were detected primarily in California. Degradates of the acetanilide herbicides were rarely detected in rain, indicating that they are not formed in the atmosphere or readily volatilized from soils. Herbicides accounted for 91 to 98% of the total pesticide mass deposited by rain except in California, where insecticides accounted for 61% in 2004. The mass of pesticides deposited by rainfall was estimated to be less than 2% of the total applied in these agricultural areas. Copyright ?? 2008 by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America. All rights reserved.

  15. Aerial pesticide application causes DNA damage in pilots from Sinaloa, Mexico.

    Science.gov (United States)

    Martínez-Valenzuela, C; Waliszewski, S M; Amador-Muñoz, O; Meza, E; Calderón-Segura, M E; Zenteno, E; Huichapan-Martínez, J; Caba, M; Félix-Gastélum, R; Longoria-Espinoza, R

    2017-01-01

    The use of pesticides in agricultural production originates residues in the environment where they are applied. Pesticide aerial application is a frequent source of exposure to pesticides by persons dedicated to agricultural practices and those living in neighboring communities of sprayed fields. The aim of the study was to assess the genotoxic effects of pesticides in workers occupationally exposed to these chemicals during their aerial application to agricultural fields of Sinaloa, Mexico. The study involved 30 pilots of airplanes used to apply pesticides via aerial application and 30 unexposed controls. Damage was evaluated through the micronucleus assay and by other nuclear abnormalities in epithelial cells of oral mucosa. The highest frequency ratios (FR) equal to 269.5 corresponded to binucleated cells followed by 54.2, corresponding to cells with pyknotic nuclei, 45.2 of cells with chromatin condensation, 3.7 of cells with broken-egg, 3.6 of cells with micronucleus, and 2.0 of karyolytic cells. Age, worked time, smoking, and alcohol consumption did not have significant influence on nuclear abnormalities in the pilots studied. Pesticide exposure was the main factor for nuclear abnormality results and DNA damage. Marked genotoxic damage was developed even in younger pilots with 2 years of short working period, caused by their daily occupational exposure to pesticides.

  16. Bazı pestisitlerin sebzelerdeki kalıntı davranışlarının belirlenmesi üzerine çalışmalar

    OpenAIRE

    CÖNGER, Ergün; AKSU, Pelin; YİGİT, Nuran; DOKUMACI, Suna; BALOĞLU, Zehra; BURÇAK, A.

    2012-01-01

    In this study, residue trials for some pesticides on tomatoes, green peppers and cucumbers were established in Ayaş, Nallıhan and Çubuk districts of Ankara province for a period of two years. Plant protection products containing chlorpyriphos, chlorothalonil and lambda-cyhalothrin on tomatoes; chlorpyriphos and metalaxyl-m+mancozeb on cucumbers; cyprodinil+fludioxonil, acetamiprid and chlorpyriphos on green peppers were used. Pesticide residue analysis of samples, that were periodically taken...

  17. Rhombic Coulomb diamonds in a single-electron transistor based on an Au nanoparticle chemically anchored at both ends.

    Science.gov (United States)

    Azuma, Yasuo; Onuma, Yuto; Sakamoto, Masanori; Teranishi, Toshiharu; Majima, Yutaka

    2016-02-28

    Rhombic Coulomb diamonds are clearly observed in a chemically anchored Au nanoparticle single-electron transistor. The stability diagrams show stable Coulomb blockade phenomena and agree with the theoretical curve calculated using the orthodox model. The resistances and capacitances of the double-barrier tunneling junctions between the source electrode and the Au core (R1 and C1, respectively), and those between the Au core and the drain electrode (R2 and C2, respectively), are evaluated as 4.5 MΩ, 1.4 aF, 4.8 MΩ, and 1.3 aF, respectively. This is determined by fitting the theoretical curve against the experimental Coulomb staircases. Two-methylene-group short octanedithiols (C8S2) in a C8S2/hexanethiol (C6S) mixed self-assembled monolayer is concluded to chemically anchor the core of the Au nanoparticle at both ends between the electroless-Au-plated nanogap electrodes even when the Au nanoparticle is protected by decanethiol (C10S). This is because the R1 value is identical to that of R2 and corresponds to the tunneling resistances of the octanedithiol chemically bonded with the Au core and the Au electrodes. The dependence of the Coulomb diamond shapes on the tunneling resistance ratio (R1/R2) is also discussed, especially in the case of the rhombic Coulomb diamonds. Rhombic Coulomb diamonds result from chemical anchoring of the core of the Au nanoparticle at both ends between the electroless-Au-plated nanogap electrodes.

  18. Pärimuslik ajalugu ja Fr. R. Kreutzwald / Tiiu Jaago

    Index Scriptorium Estoniae

    Jaago, Tiiu, 1960-

    2005-01-01

    Pärimuslik ajalugu kui rahvapärane ajalookäsitus, mida saab uurida folkloorse jutustamise kaudu. Fr. R. Kreutzwaldi ja F. K. H. Kruse sõnavõttudest Aruküla koobaste päritolu kohta ajakirjas "Das Inland" aastast 1844

  19. Spatial distribution of organic pollutants (PAHs and polar pesticides) in the floodplain of the Ohře (Eger) River, Czech Republic

    Czech Academy of Sciences Publication Activity Database

    Fikarová, J.; Kříženecká, S.; Elznicová, J.; Faměra, Martin; Lelková, T.; Matkovič, J.; Matys Grygar, Tomáš

    2018-01-01

    Roč. 18, č. 1 (2018), s. 259-275 ISSN 1439-0108 R&D Projects: GA ČR(CZ) GA15-00340S Institutional support: RVO:61388980 Keywords : Chemostratigraphy * Floodplain architecture * Organic pollutants * PAH * Pesticides Subject RIV: DD - Geochemistry OBOR OECD: Environmental sciences (social aspects to be 5.7) Impact factor: 2.522, year: 2016

  20. Dynamical analysis of cylindrically symmetric anisotropic sources in f(R, T) gravity

    Energy Technology Data Exchange (ETDEWEB)

    Zubair, M.; Azmat, Hina [COMSATS Institute of Information Technology, Department of Mathematics, Lahore (Pakistan); Noureen, Ifra [University of Management and Technology, Department of Mathematics, Lahore (Pakistan)

    2017-03-15

    In this paper, we have analyzed the stability of cylindrically symmetric collapsing object filled with locally anisotropic fluid in f(R, T) theory, where R is the scalar curvature and T is the trace of stress-energy tensor of matter. Modified field equations and dynamical equations are constructed in f(R, T) gravity. The evolution or collapse equation is derived from dynamical equations by performing a linear perturbation on them. The instability range is explored in both the Newtonian and the post-Newtonian regimes with the help of an adiabatic index, which defines the impact of the physical parameters on the instability range. Some conditions are imposed on the physical quantities to secure the stability of the gravitating sources. (orig.)

  1. 75 FR 16109 - Antimicrobial Pesticide Products; Registration Applications

    Science.gov (United States)

    2010-03-31

    ... ENVIRONMENTAL PROTECTION AGENCY [EPA-HQ-OPP-2009-0936; FRL-8806-9] Antimicrobial Pesticide...: This notice announces receipt of applications to register new antimicrobial pesticide products... identified. II. Registration Applications EPA received applications as follows to register new antimicrobial...

  2. Appui au réseautage et au renforcement des télécentres ...

    International Development Research Centre (IDRC) Digital Library (Canada)

    En Afrique de l'Ouest francophone, les télécentres luttent pour atteindre la viabilité financière tout en demeurant au diapason des collectivités, une situation qui tient au fait qu'ils ont accès à un moins grand nombre de ressources en ligne et à une communauté d'utilisateurs plus restreinte que les télécentres anglophones.

  3. Measurement of hepatic blood flow in the unanesthetized rabbit using 198Au and 125I rose bengal clearance technique

    International Nuclear Information System (INIS)

    Balabaud, C.; Roche, M.-C.; Dangoumau, Jacques

    1975-01-01

    Hepatic blood flow was measured in the unanesthetized rabbit using the clearance technique of 198 Au and 125 I RB. The values are: 71.82+-16.24ml.min -1 .kg -1 for 198 Au, and 60.21+-9.94ml.min -1 .kg -1 for 125 I RB (P 198 Au [fr

  4. Analysis of Dithiocarbamate Fungicides in Vegetable Matrices Using HPLC-UV Followed by Atomic Absorption Spectrometry.

    Science.gov (United States)

    Al-Alam, Josephine; Bom, Laura; Chbani, Asma; Fajloun, Ziad; Millet, Maurice

    2017-04-01

    A simple method combining ion-pair methylation, high-performance liquid chromatography (HPLC) analysis with detection at 272 nm and atomic absorption spectrometry was developed in order to determine 10 dithiocarbamate fungicides (Dazomet, Metam-sodium, Ferbam, Ziram, Zineb, Maneb, Mancozeb, Metiram, Nabam and Propineb) and distinguish ethylenbisdithiocarbamates (EBDTCs) Zineb, Maneb and Mancozeb in diverse matrices. This method associates reverse phase analysis by HPLC analysis with detection at 272 nm, with atomic absorption spectrometry in order to distinguish, with the same extraction protocol, Maneb, Mancozeb and Zineb. The limits of detection (0.4, 0.8, 0.5, 1.25 and 1.97) and quantification (1.18, 2.5, 1.52, 4.2 and 6.52) calculated in injected nanogram, respectively, for Dazomet, Metam-Na, dimethyldithiocarbamates (DMDTCs), EBDTCs and propylenebisdithiocarbamates (PBDTCs) justify the sensitivity of the method used. The coefficients of determination R2 were 0.9985, 0.9978, 0.9949, 0.988 and 0.9794, respectively, for Dazomet, Metam-Na, DMDTCs, EBDTCs and PBDTCs, and the recovery from fortified apple and leek samples was above 90%. Results obtained with the atomic absorption method in comparison with spectrophotometric analysis focus on the importance of the atomic absorption as a complementary specific method for the distinction between different EBDTCs fungicides. © The Author 2016. Published by Oxford University Press. All rights reserved. For Permissions, please email: journals.permissions@oup.com.

  5. A Sustainable Nanocomposite Au(Salen)@CC for Catalytic Degradation of Eosin Y and Chromotrope 2R Dyes.

    Science.gov (United States)

    Mayani, Vishal J; Mayani, Suranjana V; Kim, Sang Wook

    2017-08-03

    Up to now, a very few catalysts have been developed approaching the heterogeneous catalytic degradation of Eosin Y and Chromotrope 2R dyes (Acid Red 29). The present study provides a complete perspective of recyclable nanocomposite Au(Salen)@CC for catalytic degradation of hazardous water pollutant dyes viz., Eosin Y & Chromotrope 2R using mild reaction conditions. New gold Salen complex doped carbon nanocomposite Au(Salen)@CC was developed by easy methodology using nano carbon cage (CC) prepared from low-priced Pyrolysis fuel oil (PFO) residue based Pitch. The UV-Vis adsorption spectroscopy results of Eosin Y and Chromotrope 2R dyes indicated complete degradation into acidic compounds which can be further mineralized to CO 2 and H 2 O under mild reaction conditions. The heterogeneous catalyst recycled and reused successfully for four repeated experiments without loss in its adequate performance. This new sustainable and eco-friendly catalyst delivered significant degradation activity compared to existing reports and it can be further utilized for new multifunctional applications such as, radiopharmaceutical activities, heterogeneous catalysis and chiral resolution.

  6. 75 FR 30829 - Antimicrobial Pesticide Products; Registration Applications

    Science.gov (United States)

    2010-06-02

    ... ENVIRONMENTAL PROTECTION AGENCY [EPA-HQ-OPP-2010-0325; FRL-8824-2] Antimicrobial Pesticide...: This notice announces receipt of an application to register new antimicrobial pesticide products... telephone number is (703) 305-5805. FOR FURTHER INFORMATION CONTACT: Demson Fuller, Antimicrobials Division...

  7. Le travail des femmes à Frías: modèle andin et variante régionale

    Directory of Open Access Journals (Sweden)

    1993-01-01

    Full Text Available À Frías, dans les Andes de Piura, les femmes sont absentes des tâches de production agricole au sens strict. Une comparaison avec des études menées dans d’autres régions montre en quoi cette organisation diffère d’un modèle andin. Mais ce modèle est trompeur. Il recouvre une grande variété de situations. Entre autres facteurs, la reconstitution du passé d’un système de production est nécessaire pour comprendre son orientation actuelle. EL TRABAJO DE LAS MUJERES EN FRÍAS: MODELO ANDINO Y VARIANTE REGIONAL. En Frías, en la sierra de Piura, las mujeres no participan en las tareas de producción agrícola en el sentido estricto. Una comparación con estudios realizados en otras regiones indica cómo esta organización difiere de un modelo andino. Pero, este modelo, que hemos construido, encubre una gran diversidad de casos. Entre otros factores, la reconstitución del pasado de un sistema de producción es necesaria para entender su orientación actual. WOMEN’ S WORK: ANDEAN PATTERN AND LOCAL VARIATION. Women are not present in agricultural working stricto sensu in Frías, in the Piura highlands. A comparison of the pattern of organization with case studies in other regions of Peru shows differences with the Andean pattern. But the pattern described here covers a great diversity of situations. Among many factors, the historical reconstitution of a farming system is necessary to understand its current orientation.

  8. Från outsiderfilmmakare till etablerad indieregissör : David Lynch, Jim Jarmusch och Steven Soderbergh

    OpenAIRE

    Simberg, Maximilian

    2014-01-01

    Det här arbetet behandlar kreativ frihet och konstnärligt oberoende i filmskapande, utgående från begreppet independent film och regissörerna David Lynch, Jim Jarmusch och Steven Soderbergh. Den centrala frågeställningen är hur det har varit möjligt för en filmkonstnär att uppnå konstnärligt oberoende och samtidigt ha en långlivad och framgångsrik karriär. Arbetets fokus ligger på de tre regissörernas genombrottsfilmer; Eraserhead, Stranger Than Paradise och sex, lies, and videotape, och förs...

  9. Radial and latitudinal dependencies of discontinuities in the solar wind between 0.3 and 19 AU and −80° and +10°

    Directory of Open Access Journals (Sweden)

    A. Söding

    2001-07-01

    Full Text Available Directional discontinuities (DD from 5 missions at 7 different locations between 0.3 and 19 AU and −80° and +10° in the 3D heliosphere are investigated during minimum solar activity. The data are surveyed using the identification criteria of Burlaga (1969 (B and Tsurutani and Smith (1979 (TS. The rate of occurrence depends linearly on the solar wind velocity caused by the geometric effect of investigating a larger plasma volume if the solar wind velocity νsw increases. The radial dependence is proportional to r–0.78 (TS criterion and r–1.28 (B criterion, respectively. This dependence is not only due to an increasing miss rate with increasing distance. The DDs must be unstable or some other physical effect must exist. After normalization of the daily rates to 400 km/s and 1 AU, no dependence on heliographic latitude or on solar wind structures is observable. This means that the DDs are uniformly distributed on a spherical shell. Normalized 64 DD per day are identified with both criteria. But large variations of the daily rate still occur, indicating that other influences must exist. The ratio of the rates of rotational (RDs and tangential discontinuities (TDs depends on the solar wind structures. In high speed streams, relatively more RDs exist than in low speed streams. In the inner heliosphere (r < 10 AU, no radial or latitudinal dependence of the portions of the DD types occur. 55% clear RDs, 10% clear TDs and 33% EDs (either discontinuities are observed, but the portions differ with regard to the criteria used. In the middle heliosphere (10 AU< r < 40 AU, the DD types are more uniformly distributed. The distribution of the directional change ω over the transition evolves to an increase of smaller ω with increasing distance from the sun. The evolution is yielded by the anisotropic RDs with small ω. The spatial thickness dkm in kilometers increases with distance. The thickness drg normalized to the proton gyro radius decreases by a

  10. New proposal for non-linear ghost-free massive F(R) gravity: Cosmic acceleration and Hamiltonian analysis

    International Nuclear Information System (INIS)

    Klusoň, Josef; Nojiri, Shin'ichi; Odintsov, Sergei D.

    2013-01-01

    We propose new version of massive F(R) gravity which is natural generalization of convenient massive ghost-free gravity. Its Hamiltonian formulation in scalar-tensor frame is developed. We show that such F(R) theory is ghost-free. The cosmological evolution of such theory is investigated. Despite the strong Bianchi identity constraint the possibility of cosmic acceleration (especially, in the presence of cold dark matter) is established. Ghost-free massive F(R,T) gravity is also proposed

  11. Evolution de certains composés volatils du bois de chêne au cours de son séchage premiers résultats

    Directory of Open Access Journals (Sweden)

    Pascal Chatonnet

    1994-12-01

    Full Text Available Pendant le séchage des merrains sur parc à l'air libre, on assiste à une profonde modification de la composition chimique et du profil aromatique du bois de chêne. La teneur en eugénol, en aldéhydes phénols et en Β-méthyl-y-octalactone augmente régulièrement pendant le vieillissement du bois. Principalement sous forme trans au début du séchage, la Β-méthyl-y-octalactone s'accumule finalement sous la forme cis plus aromatique. Dans le même temps, on observe également une accumulation importante du précurseur inodore de Β-méthyl-y-octalactone. L'intervention des micro-organismes fréquemment isolés sur le bois en cours de séchage naturel sur la formation de composés aromatiques a été étudiée. La culture de diverses moisissures isolées de bois en cours de séchage naturel sur extraits de bois et directement sur sciure de chêne aboutit dans tous les cas à une forte diminution des teneurs en aldéhydes phénols, notamment de la vanilline. En effet, tous les micro-organismes étudiés (Penicilium sp., Trichoderma sp., Aureobasidium sp. sont incapables de dégrader la lignine car ils ne possèdent pas d'activité ligninase. En revanche, ces champignons possèdent une forte activité oxydo-réductase capable de réduire la vanilline en alcool vanillique inodore. En conséquence, les aldéhydes phénols apparaissant au cours du séchage naturel du merrain ne dérivent pas d'une attaque enzymatique mais plus vraisemblablementde l'acidolyse et de l'oxydation chimique de la lignine du bois. Le stockage du bois à l'air libre en présence d'eau et d'oxygène doit permettre une évolution favorable de son potentiel aromatique tant que la vanilline et la cis Β-méthyly-octalactone s'accumulent.

  12. PHENIX results on jets in d + Au

    Energy Technology Data Exchange (ETDEWEB)

    Hanks, J. Ali

    2016-12-15

    We present recently published results [A. Adare, et al., (arXiv:1509.04657)] on fully reconstructed R=0.3 anti-k{sub t} jets measured in p+p and d+Au collisions at 200 GeV center-of-mass energy. The jet yields for four centrality classes along with the p+p reference are presented, as well as both the minimum bias R{sub dAu} and centrality dependent R{sub dAu} and R{sub CP}. We find that while the minimum bias R{sub dA} is consistent with unity, providing a strong constraint on models including cold-nuclear-matter effects or energy loss in small systems, the centrality dependent R{sub dAu} show a striking variation which presents a challenge to models attempting to describe the interplay between soft and hard processes in these systems.

  13. Stream dynamics between 1 AU and 2 AU: a detailed comparison of observations and theory

    International Nuclear Information System (INIS)

    Burlaga, L.; Pizzo, V.; Lazarus, A.; Gazis, P.

    1984-04-01

    A radial alignment of three solar wind stream structures observed by IMP-7 and -8 (at 1.0 AU) and Voyager 1 and 2 (in the range 1.4 to 1.8 AU) in late 1977 is presented. It is demonstrated that several important aspects of the observed dynamical evolution can be both qualitatively and quantitatively described with a single-fluid 2-D MHD numerical model of quasi-steady corotating flow, including accurate prediction of: (1) the formation of a corotating shock pair at 1.75 AU in the case of a simple, quasi-steady stream; (2) the coalescence of the thermodynamic and magnetic structures associated with the compression regions of two neighboring, interacting, corotating streams; and (3) the dynamical destruction of a small (i.e., low velocity-amplitude, short spatial-scale) stream by its overtaking of a slower moving, high-density region associated with a preceding transient flow. The evolution of these flow systems is discussed in terms of the concepts of filtering and entrainment

  14. Solar System constraints on a cosmologically viable f(R) theory

    Energy Technology Data Exchange (ETDEWEB)

    Bisabr, Yousef, E-mail: y-bisabr@srttu.ed [Department of Physics, Shahid Rajaee Teacher Training University, Lavizan, Tehran 16788 (Iran, Islamic Republic of)

    2010-01-18

    Recently, a model f(R) theory is proposed (Miranda et al. (2009)) which is cosmologically viable and distinguishable from LAMBDACDM. We use chameleon mechanism to investigate viability of the model in terms of Solar System experiments.

  15. Tier I Rice Model - Version 1.0 - Guidance for Estimating Pesticide Concentrations in Rice Paddies

    Science.gov (United States)

    Describes a Tier I Rice Model (Version 1.0) for estimating surface water exposure from the use of pesticides in rice paddies. The concentration calculated can be used for aquatic ecological risk and drinking water exposure assessments.

  16. 75 FR 13284 - Pesticide Program Dialogue Committee; Request for Nominations to the Pesticide Program Dialogue...

    Science.gov (United States)

    2010-03-19

    ... particular interest to persons who work in agricultural settings or persons who are concerned about... entities may include, but are not limited to: Agricultural workers and farmers; pesticide industry and... and special ecosystems from potential risks posed by pesticides. The Charter for EPA's PPDC was...

  17. Triangular Zn{sub 3} and Ga{sub 3} units in Sr{sub 2}Au{sub 6}Zn{sub 3}, Eu{sub 2}Au{sub 6}Zn{sub 3}, Sr{sub 2}Au{sub 6}Ga{sub 3}, and Eu{sub 2}Au{sub 6}Ga{sub 3}. Structure, magnetism, {sup 151}Eu Moessbauer and {sup 69;71}Ga solid state NMR spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Gerke, Birgit; Niehaus, Oliver; Poettgen, Rainer [Muenster Univ. (Germany). Inst. fuer Anorganische und Analytische Chemie; Korthaus, Alexander; Haarmann, Frank [RWTH Aachen Univ. (Germany). Inst. fuer Anorganische Chemie

    2016-08-01

    The gold-rich intermetallic compounds Sr{sub 2}Au{sub 6}Zn{sub 3}, Eu{sub 2}Au{sub 6}Zn{sub 3}, Sr{sub 2}Au{sub 6}Ga{sub 3}, and Eu{sub 2}Au{sub 6}Ga{sub 3} were synthesized from the elements in sealed tantalum ampoules in induction or muffle furnaces. The europium compounds are reported for the first time and their structures were refined from single crystal X-ray diffractometer data: Sr{sub 2}Au{sub 6}Zn{sub 3} type, R anti 3c, a = 837.7(1), c = 2184.5(4) pm, wR2 = 0.0293, 572 F{sup 2} values for Eu{sub 2}Au{sub 6.04}Zn{sub 2.96} and a = 838.1(2), c = 2191.7(5) pm, wR2 = 0.0443, 513 F{sup 2} values for Eu{sub 2}Au{sub 6.07}Ga{sub 2.93} with 20 variables per refinement. The structures consist of a three-dimensional gold network with a 6R stacking sequence, similar to the respective diamond polytype. The cavities of the network are filled in a ratio of 2:1 by strontium (europium) atoms and Ga{sub 3} (Zn{sub 3}) triangles in an ordered manner. Sr{sub 2}Au{sub 6}Zn{sub 3} and Sr{sub 2}Au{sub 6}Ga{sub 3} are diamagnetic with room temperature susceptibilities of -3.5 x 10{sup -4} emu mol{sup -1}. Temperature dependent susceptibility and {sup 151}Eu Moessbauer spectroscopic measurements show a stable divalent ground state for both europium compounds. Eu{sub 2}Au{sub 6}Zn{sub 3} and Eu{sub 2}Au{sub 6}Ga{sub 3} order antiferromagnetically below Neel temperatures of 16.3 and 12.1 K, respectively. Anisotropic electrical conductivity of Sr{sub 2}Au{sub 6}Ga{sub 3} is proven by an alignment of the crystallites in the magnetic field. Orientation-dependent {sup 69;71}Ga NMR experiments combined with quantum mechanical calculations (QM) give evidence for a highly anisotropic charge distribution of the Ga atoms.

  18. Study of Antigravity in an F(R) Model and in Brans-Dicke Theory with Cosmological Constant

    OpenAIRE

    Oikonomou, V. K.; Karagiannakis, N.

    2014-01-01

    We study antigravity, that is having an effective gravitational constant with a negative sign, in scalar-tensor theories originating from $F(R)$-theory and in a Brans-Dicke model with cosmological constant. For the $F(R)$ theory case, we obtain the antigravity scalar-tensor theory in the Jordan frame by using a variant of the Lagrange multipliers method and we numerically study the time dependent effective gravitational constant. As we shall demonstrate by using a specific $F(R)$ model, altho...

  19. La fibrillation atriale, fréquence, facteurs étiologiques, évolution et traitement dans un service de cardiologie de Dakar, Sénégal

    Directory of Open Access Journals (Sweden)

    Kane Abdoul

    2010-09-01

    Full Text Available INTRODUCTION: La fibrillation atriale est le trouble du rythme cardiaque soutenu le plus fréquent. Les objectifs de ce travail étaient d’étudier la fréquence, les facteurs étiologiques, l’évolution et le traitement de la fibrillation atriale dans un service de cardiologie de Dakar au Sénégal. METHODES: Il s’agit d’une étude rétrospective réalisée sur cinq ans et portant sur l’analyse de 150 dossiers de patients hospitalisés pour une fibrillation atriale. RESULTATS: La fréquence de la fibrillation atriale était de 5,35 % et représentait 66% des troubles du rythme cardiaque avec une prédominance féminine (sex-ratio H/F = 0,45 et un âge moyen de 57,06 ± 18,64 ans. L’origine de la fibrillation était valvulaire dans 36,7% des cas. Les complications thromboemboliques étaient plus fréquentes dans la fibrillation atriale non valvulaire (p=0,006, chez les sujets d’âge > 50 ans (p=0,01 et en cas de dilatation de l’oreillette gauche (p=0,05. Une anticoagulation par anti-vitamine K était instaurée dans 62% des cas et un traitement de contrôle de la fréquence cardiaque dans 87,33%. CONCLUSION: La fibrillation atriale est fréquente en milieu hospitalier africain et concerne des sujets relativement jeunes. L’hypertension artérielle et les valvulopathies rhumatismales sont les principaux facteurs étiologiques. Le traitement reste essentiellement médicamenteux par contrôle de la fréquence cardiaque.

  20. Solar System constraints on a cosmologically viable f(R) theory

    International Nuclear Information System (INIS)

    Bisabr, Yousef

    2010-01-01

    Recently, a model f(R) theory is proposed (Miranda et al. (2009)) which is cosmologically viable and distinguishable from ΛCDM. We use chameleon mechanism to investigate viability of the model in terms of Solar System experiments.

  1. Facile synthesis of amine-functional reduced graphene oxides as modified quick, easy, cheap, effective, rugged and safe adsorbent for multi-pesticide residues analysis of tea.

    Science.gov (United States)

    Ma, Guicen; Zhang, Minglu; Zhu, Li; Chen, Hongping; Liu, Xin; Lu, Chengyin

    2018-01-05

    Amine-functional reduced graphene oxide (amine-rGO) with different carbon chain length amino groups were successfully synthesized. The graphene oxides (GO) reduction as well as amino grafting were achieved simultaneously in one step via a facile solvothermal synthetic strategy. The obtained materials were characterized by X-ray diffraction, Raman spectroscopy, Fourier-transform infrared spectrometry and X-ray photoelectron spectroscopy to confirm the modification of GO with different amino groups. The adsorption performance of catechins and caffeine from tea acetonitrile extracts on different amine functional rGO samples were evaluated. It was found that tributylamine-functional rGO (tri-BuA-rGO) exhibited the highest adsorption ability for catechins and caffeine compared to GO and other amino group functional rGO samples. It was worth to note that the adsorption capacity of catechins on tri-BuA-rGO was 11 times higher than that of GO (203.7mgg -1 vs 18.7mgg -1 ). Electrostatic interaction, π-π interaction and surface hydrophilic-hydrophobic properties of tri-BuA-rGO played important roles in the adsorption of catechins as well as caffeine. The gravimetric analysis confirmed that the tri-BuA-rGO achieved the highest efficient cleanup preformance compared with traditional dispersive solid phase extraction (dSPE) adsorbents like primary-secondary amine (PSA), graphitized carbon black (GCB) or C18. A multi-pesticides analysis method based on tri-BuA-rGO is validated on 33 representative pesticides in tea using gas chromatography coupled to tandem mass spectrometry or high-performance liquid chromatography coupled with tandem mass spectrometry. The analysis method gave a high coefficient of determination (r 2 >0.99) for each pesticide and satisfactory recoveries in a range of 72.1-120.5%. Our study demonstrated that amine functional rGO as a new type of QuEChERS adsorbent is expected to be widely applied for analysis of pesticides at trace levels. Copyright © 2017

  2. 75 FR 74713 - Product Cancellation Order for Certain Pesticide Registrations; Correction

    Science.gov (United States)

    2010-12-01

    ... Sergeant's Pet Care Products' pesticide product, EPA Reg. No. 2517-79. FOR FURTHER INFORMATION CONTACT: Maia Tatinclaux, Pesticide Re- evaluation Division (7508P), Office of Pesticide Programs, Environmental... hard copy, at the Office of Pesticide Programs (OPP) Regulatory Public Docket in Rm. S- 4400, One...

  3. Observation of Au + AuAu + Au + ρ0 and Au + AuAu* + Au* + ρ0 with STAR

    International Nuclear Information System (INIS)

    Spencer, K.

    2002-01-01

    First observation of the reactions Au + AuAu + Au + ρ 0 and Au + AuAu* + Au* + ρ 0 with the STAR detector are reported. The ρ are produced at small perpendicular momentum, as expected if they couple coherently to both nuclei. Models of vector meson production and the correlation with nuclear breakup are discussed, as well as a fundamental test of quantum mechanics that is possible with the system. (author)

  4. 78 FR 26935 - Data Requirements for Antimicrobial Pesticides

    Science.gov (United States)

    2013-05-08

    ... pesticides used in conjunction with the manufacturing and processing of foods, at that time, were regulated....S.C. 136 et seq., and section 408 of the Federal Food, Drug, and Cosmetic Act (FFDCA), 21 U.S.C.... Antimicrobial pesticides are used to control microbiological contamination in healthcare applications, and...

  5. 10 Contribution à la régulation de la température au sein d'un ...

    African Journals Online (AJOL)

    ALI

    Cette dégradation est influencée par plusieurs facteurs tels que : le pH, la température, la teneur en eau, etc. [2]. La température au ... Le digesteur étudié est de type batch, rempli à moitié dont l'autre moitié sert pour contenir le gaz produit. Le substrat utilisé .... coefficient d'absorption de la plaque; G éclairement solaire;.

  6. Nouvel institut de recherche au Liban pour répondre aux priorités en ...

    International Development Research Centre (IDRC) Digital Library (Canada)

    3 oct. 2017 ... L'Université américaine de Beyrouth (AUB) a annoncé la création d'un institut de la santé mondiale (The Global Health Institute) afin d'offrir une plateforme régionale à la recherche interdisciplinaire et au renforcement des capacités en santé mondiale. D'importantes crises humanitaires changent la nature ...

  7. Evolved pesticide tolerance in amphibians: Predicting mechanisms based on pesticide novelty and mode of action

    International Nuclear Information System (INIS)

    Hua, Jessica; Jones, Devin K.; Mattes, Brian M.; Cothran, Rickey D.; Relyea, Rick A.; Hoverman, Jason T.

    2015-01-01

    We examined 10 wood frog populations distributed along an agricultural gradient for their tolerance to six pesticides (carbaryl, malathion, cypermethrin, permethrin, imidacloprid, and thiamethoxam) that differed in date of first registration (pesticide novelty) and mode-of-action (MOA). Our goals were to assess whether: 1) tolerance was correlated with distance to agriculture for each pesticide, 2) pesticide novelty predicted the likelihood of evolved tolerance, and 3) populations display cross-tolerance between pesticides that share and differ in MOA. Wood frog populations located close to agriculture were more tolerant to carbaryl and malathion than populations far from agriculture. Moreover, the strength of the relationship between distance to agriculture and tolerance was stronger for older pesticides compared to newer pesticides. Finally, we found evidence for cross-tolerance between carbaryl and malathion (two pesticides that share MOA). This study provides one of the most comprehensive approaches for understanding patterns of evolved tolerance in non-pest species. - Highlights: • We explored patterns of tolerance to six insecticides across 10 wood frog populations. • We found evidence that wood frogs have evolved tolerance to carbaryl and malathion. • The likelihood of evolved tolerance was stronger for older compared to newer pesticides. • We found evidence for cross-tolerance between carbaryl and malathion. • This is one of the most comprehensive approaches studying evolved tolerance in a non-pest species. - Using 10 wood frog populations, we detected evidence for evolved tolerance, found that the evolved tolerance depends on insecticide novelty, and found evidence for cross-tolerance.

  8. Enhanced middle-infrared light transmission through Au/SiO(x)N(y)/Au aperture arrays.

    Science.gov (United States)

    Xiao, Gongli; Yao, Xiang; Ji, Xinming; Zhou, Jia; Bao, Zongming; Huang, Yiping

    2011-12-01

    The enhanced middle-infrared light transmission through Au/SiO(x)N(y)/Au aperture arrays by changing the refractive index and the thickness of a dielectric layer was studied experimentally. The results indicated that the transmission spectra was highly dependent on the refractive index and the thickness of SiO(x)N(y). We found that the transmission peaks redshifted regularly along with the refractive index from 1.6 to 1.8, owing to the role of surface plasmon polaritons (SPP) coupling in the Au/SiO(x)N(y)/Au cascaded metallic structure. Simultaneously, a higher transmission efficiency and narrower transmission peak was obtained in Au/SiO2.1N0.3/Au cascaded metallic structure with small refractive index (1.6) than in Au/SiO0.6N1/Au cascaded metallic structure with large refractive index (1.8). When the thickness of SiO(x)N(y) changes from 0.2 to 0.4 microm, the shape of transmission spectra exhibits a large change. It was found that a higher transmission efficiency and narrower transmission peak was obtained in Au/SiO(x)N(y)/Au cascaded metallic structure with a thin dielectric film (0.2 microm), with the increase of SiO(x)N(y) film's thickness, the transmission peak gradually widened and disappeared finally. This effect is useful in applications of biochemical sensing and tunable integrated plasmonic devices in the middle-infrared region.

  9. Influence de l'usage préventif des pesticides sur les acariens Tetranychus urticae et Phytoseiulus persimilis (Acari : Tetranychidae, Phytoseiidae présents en cultures de fraisiers du Nord du Maroc

    Directory of Open Access Journals (Sweden)

    Lagziri, M.

    2015-01-01

    Full Text Available Influence of previous pesticide use on Tetranychus urticae and Phytoseiulus persimilis (Acari: Tetranychidae, Phytoseiidae from strawberry crops in the north of Morocco. Description of the subject. Effects of recommended doses of five common pesticides in the strawberries of Loukkos area (Morocco were tested on the two-spotted spider mite Tetranychus urticae and its predatory mite Phytoseiulus persimilis. Laboratory study assessed the contact toxicity of one avermectin miticide (abamectin, two pyrethrinoid insecticide-acaricides (bifenthrin and lambda-cyalothrin, and two fungicides: firstly, mancozeb, which belongs to the dithiocarbamates family of chemicals and secondly, hexaconazole, of the triazole family. Objectives. The aim of the present study was to test in laboratory conditions the effect of five pesticides on the two-spotted spider mite, T. urticae and its predatory mite, P. persimilis. The five pesticides tested were those most frequently applied for at least two years on strawberries at the experimental site. Method. Bioassays were performed with populations of mites originating from different plots with various crop protection backgrounds. The first group of plots had been repeatedly treated with the five tested pesticides during a two-year period, the second group had been moderately treated, and the third had been treated once with the tested pesticides. Results. Our results showed that the tested pesticides provided effective control of T. urticae but that they were not compatible with use on the predatory mite P. persimilis, as these particular mites did not usually come into contact with these products. On the other hand, in plots where pesticides had been used for a long time, the susceptibility of P. persimilis populations to these products was significantly reduced. Conclusions. If the tested pesticides are to be considered for integrated pest control programs in plots where they have been used for a long time and where P

  10. Les représentations sociales liées au lieu de résidence au sein du parc de Bercy

    Directory of Open Access Journals (Sweden)

    Teddy Arrif

    2009-04-01

    Full Text Available Notre recherche se propose d’analyser les représentations et les pratiques spatiales des usagers du parc de Bercy situé dans le 12ème arrondissement de Paris. La littérature nous a conduit à poser l’hypothèse d’un lien fort entre ces représentations et pratiques d’une part, et la proximité résidentielle. L’enquête menée auprès des usagers du parc de Bercy a confirmé au moins partiellement notre hypothèse. Elle a permis également de pointer l’importance de l’accessibilité au parc notamment pour les usagers résidant hors de l’arrondissement. Enfin, elle confirme la nécessité de prendre en compte les pratiques et les représentations des habitants dans l’aménagement des parcs publics parisiens.Our research aims to analyze performances and practice space users Parc de Bercy in the 12th arrondissement of Paris. The literature has led us to ask the assumption of a strong link between these representations and practices on the one hand, and the nearby residential. The survey of users of the Parc de Bercy confirmed at least partially our hypothesis. It has also point to the importance of accessibility to the park especially for users outside the borough. Finally, it confirms the need to take into account the practices and representations of residents in the management of public parks in Paris.

  11. Le rôle de paysans mieux informés au Bénin | CRDI - Centre de ...

    International Development Research Centre (IDRC) Digital Library (Canada)

    10 déc. 2010 ... Le défi : faire face au chaos climatique. Au Bénin, le secteur agricole constitue environ 36 % du PIB et représente près de 88 % des recettes d'exportation, en plus de satisfaire à la demande locale. Cependant, ce secteur est menacé. Loin d'être la seule cause du sous-développement, les bouleversements ...

  12. In situ STM imaging of the structures of pentacene molecules adsorbed on Au(111).

    Science.gov (United States)

    Pong, Ifan; Yau, Shuehlin; Huang, Peng-Yi; Chen, Ming-Chou; Hu, Tarng-Shiang; Yang, Yawchia; Lee, Yuh-Lang

    2009-09-01

    In situ scanning tunneling microscope (STM) was used to examine the spatial structures of pentacene molecules adsorbed onto a Au(111) single-crystal electrode from a benzene dosing solution containing 16-400 microM pentacene. Molecular-resolution STM imaging conducted in 0.1 M HClO(4) revealed highly ordered pentacene structures of ( radical31 x radical31)R8.9 degrees , (3 x 10), ( radical31 x 10), and ( radical7 x 2 radical7)R19.1 degrees adsorbed on the reconstructed Au(111) electrode dosed with different pentacene solutions. These pentacene structures and the reconstructed Au(111) substrate were stable between 0.2 and 0.8 V [vs reversible hydrogen electrode, RHE]. Increasing the potential to E > 0.8 V lifted the reconstructed Au(111) surface and disrupted the ordered pentacene adlattices simultaneously. Ordered pentacene structures could be restored by applying potentials negative enough to reinforce the reconstructed Au(111). At potentials negative of 0.2 V, the adsorption of protons became increasingly important to displace adsorbed pentacene admolecules. Although the reconstructed Au(111) structure was not essential to produce ordered pentacene adlayers, it seemed to help the adsorption of pentacene molecules in a long-range ordered pattern. At room temperature (25 degrees C), approximately 100 pentacene molecules seen in STM images could rotate and align themselves to a neighboring domain in 10 s, suggesting that pentacene admolecules could be mobile on Au(111) under the STM imaging conditions of -150 mV in bias voltage and 1 nA in feedback current.

  13. Influence of f(R) models on the existence of anisotropic self-gravitating systems

    Energy Technology Data Exchange (ETDEWEB)

    Yousaf, Z.; Sharif, M.; Bhatti, M.Z. [University of the Punjab, Department of Mathematics, Lahore (Pakistan); Ilyas, M. [University of the Punjab, Centre for High Energy Physics, Lahore (Pakistan)

    2017-10-15

    This paper aims to explore some realistic configurations of anisotropic spherical structures in the background of metric f(R) gravity, where R is the Ricci scalar. The solutions obtained by Krori and Barua are used to examine the nature of particular compact stars with three different modified gravity models. The behavior of material variables is analyzed through plots and the physical viability of compact stars is investigated through energy conditions. We also discuss the behavior of different forces, equation of state parameter, measure of anisotropy and Tolman-Oppenheimer-Volkoff equation in the modeling of stellar structures. The comparison from our graphical representations may provide evidence for the realistic and viable f(R) gravity models at both theoretical and the astrophysical scale. (orig.)

  14. 78 FR 36778 - Pesticide Program Dialogue Committee; Notice of Public Meeting

    Science.gov (United States)

    2013-06-19

    ... associations; environmental, consumer, and farm worker groups; pesticide users and growers; animal rights... animal rights groups; farm worker organizations; pesticide industry and trade associations; pesticide...

  15. Constraining models of f(R) gravity with Planck and WiggleZ power spectrum data

    International Nuclear Information System (INIS)

    Dossett, Jason; Parkinson, David; Hu, Bin

    2014-01-01

    In order to explain cosmic acceleration without invoking ''dark'' physics, we consider f(R) modified gravity models, which replace the standard Einstein-Hilbert action in General Relativity with a higher derivative theory. We use data from the WiggleZ Dark Energy survey to probe the formation of structure on large scales which can place tight constraints on these models. We combine the large-scale structure data with measurements of the cosmic microwave background from the Planck surveyor. After parameterizing the modification of the action using the Compton wavelength parameter B 0 , we constrain this parameter using ISiTGR, assuming an initial non-informative log prior probability distribution of this cross-over scale. We find that the addition of the WiggleZ power spectrum provides the tightest constraints to date on B 0 by an order of magnitude, giving log 10 (B 0 ) < −4.07 at 95% confidence limit. Finally, we test whether the effect of adding the lensing amplitude A Lens and the sum of the neutrino mass ∑m ν is able to reconcile current tensions present in these parameters, but find f(R) gravity an inadequate explanation

  16. Bi induced step-flow growth in the homoepitaxial growth of Au(1 1 1)

    International Nuclear Information System (INIS)

    Kamiko, M.; Mizuno, H.; Chihaya, H.; Xu, J.-H.; Kojima, I.; Yamamoto, R.

    2005-01-01

    Homoepitaxial growth of Au on Bi-covered Au(1 1 1) was studied at room temperature using reflection high-energy electron diffraction (RHEED) and Auger electron spectroscopy (AES). From observations of RHEED it is found that the Au(1 1 1) (23 x 1) reconstruction structure changes to a (1 x 1) by about 0.16-0.5 ML deposition of Bi and to a (2√3 x 2√3)R30 deg by about 1.0 ML deposition of Bi, respectively. The surface morphology evolution by Bi deposition leads to a change of Au homoepitaxial growth behavior from layer-by-layer to step flow. This indicates that the surface diffusion distance of Au atoms on the Bi-precovered (1 x 1) and (2√3 x 2√3)R30 deg surfaces is longer than that on the Au(1 1 1) (23 x 1) clean surfaces. A strong surface segregation of Bi was found at top of surface. It is concluded that Bi atoms acted as an effective surfactant in the Au homoepitaxial growth by promoting Au intralayer mass transport

  17. Interfon

    CERN Multimedia

    Interfon

    2011-01-01

    Assemblée générale de la Coopérative Mardi 21 juin 2011 à 18h00 au Siège Social Technoparc - 60, rue Clément Ader - 01630 St-Genis-Pouilly Ordre du jour : Election du président de séance Approbation des C.R. des A.G. du 22.06.2010 Rapport moral de l’activité 2010 Présentation des comptes de l’année 2010 Renouvellement du tiers sortant Questions diverses. Fioul domestique Prix promotionnels durant toute la semaine du 06 au 12 juin 2010 (prix réduits par rapport au cours du jour) Passez vos commandes aux bureaux Interfon ou par mail sur notre site www.interfon.fr  * * * * * * * Sera présent d...

  18. Pesticide Degrading Bacteria in Aquatic Environment: Bioprospecting and Evaluation of Biotechnological Potential

    Directory of Open Access Journals (Sweden)

    Daniel Rodrigues dos Santos

    2016-07-01

    Full Text Available Pesticides play an important role in the increase of productivity in agro-industry and the extensive use of these substances cause environmental, economic and social damage in time. Microbial activity is an essential part in the dynamics and the destination of pesticides in the environment. This research focuses in prospecting and characterizing bacterial strains which are potentially able to degrade/tolerate Atrazine, Chlorpyrifos, Methyl parathion and Picloram. Bacteria were isolated from water samples collected according to the degree of salinity along the Pacoti River's estuary (Ceara, located in the semi-arid region of northeastern Brazil. A total of 49 bacterial strains were isolated, all of which tolerated/ downgraded concentrations up to 200mg/L of picloram, atrazine and methyl parathion. Tested in pesticide mixtures, the percentage and tolerance level showed that 73% grew in concentrations up to 200mg/L, 17,4% tolerated/ downgraded up to 150ml/L and the remainder only grew in concentrations under 100ml/L. The strains which had the best performance against pesticides, by points, were P1 (13Db e 14D; P2 (10E; P3 (2M, 9M, 10M, 12Mb, 14M, 17M 18Mp 19M e 20M. A high percentage of isolates (67% expressed luminescence when exposed to the pesticides atrazine and methyl parathion in concentrations between 150 and 200ml/L. DOI: http://dx.doi.org/10.17807/orbital.v8i4.748

  19. Unified cosmic history in modified gravity: From F(R) theory to Lorentz non-invariant models

    Science.gov (United States)

    Nojiri, Shin'Ichi; Odintsov, Sergei D.

    2011-08-01

    The classical generalization of general relativity is considered as the gravitational alternative for a unified description of the early-time inflation with late-time cosmic acceleration. The structure and cosmological properties of a number of modified theories, including traditional F(R) and Hořava-Lifshitz F(R) gravity, scalar-tensor theory, string-inspired and Gauss-Bonnet theory, non-local gravity, non-minimally coupled models, and power-counting renormalizable covariant gravity are discussed. Different representations of and relations between such theories are investigated. It is shown that some versions of the above theories may be consistent with local tests and may provide a qualitatively reasonable unified description of inflation with the dark energy epoch. The cosmological reconstruction of different modified gravities is provided in great detail. It is demonstrated that eventually any given universe evolution may be reconstructed for the theories under consideration, and the explicit reconstruction is applied to an accelerating spatially flat Friedmann-Robertson-Walker (FRW) universe. Special attention is paid to Lagrange multiplier constrained and conventional F(R) gravities, for latter F(R) theory, the effective ΛCDM era and phantom divide crossing acceleration are obtained. The occurrences of the Big Rip and other finite-time future singularities in modified gravity are reviewed along with their solutions via the addition of higher-derivative gravitational invariants.

  20. [Situation analysis and standard formulation of pesticide residues in traditional Chinese medicines].

    Science.gov (United States)

    Yang, Wan-Zhen; Kang, Chuan-Zhi; Ji, Rui-Feng; Zhou, L I; Wang, Sheng; Li, Zhen-Hao; Ma, Zhong-Hua; Guo, Lan-Ping

    2017-06-01

    Chinese Pharmacopoeia provides nine pesticide Maximum Residual Limits(MRLs) of traditional Chinese medicines(TCMs), The number of pesticides used in production are far more than those listed in pharmacopoeia. The lack of the standards make it's hard to reflect the real situation of pesticide residues in TCMs correctly. The paper is aimed to analyze the data of pesticide residues in TCMs from 7 089 items in 140 reports, and judging the exceedance rate of pesticides in TCMs using the MRLs of European pharmacopoeia,which is widely accepted in many countries. The results show that:①Pesticide residues in 18 kinds of TCMs are higher than MRLs,while in 137 kinds are below MRLs, such as Atractylodis Macrocephalae Rhizoma, Menthae Haplocalycis Herba and Fritillariae Thunbergii Bulbus. The average exceedance rate of all TCMs is 1.72%. The average exceedance rates of organochlorine, organophosphorus and pyrethroid are 2.26%, 1.51%, 0.37%,respectively. ②The average exceedance rate of pesticides is 2.00%, and the exceedance rate is more than 5%, accounting for 8.33%, the exceedance rate is between 1%-5%, accounting for 18.75%. the exceedance rate is between 0%-1%, accounting for 18.75%. The remaining 29 kinds of pesticides were not exceeded, accounting for 60.42%.Some reports like Greenpeace's organization exaggerated the pesticide residues in TCMs.But the pesticide residue question is still worthy of attention, so we proposed to amend the Chinese Pharmacopoeia pesticide residues standards, to increase the pesticide species of traditional Chinese medicine in production on the basis of retaining the existing types of pesticide residues, to strengthen the system research of pesticide residues in TCMs, providing a basis for making standard and promoting import and export trade in TCMs. Copyright© by the Chinese Pharmaceutical Association.

  1. Gravitational radiation in quadratic f(R) gravity

    International Nuclear Information System (INIS)

    Naef, Joachim; Jetzer, Philippe

    2011-01-01

    We investigate the gravitational radiation emitted by an isolated system for gravity theories with Lagrange density f(R)=R+aR 2 . As a formal result, we obtain leading order corrections to the quadrupole formula in general relativity. We make use of the analogy of f(R) theories with scalar-tensor theories, which in contrast to general relativity feature an additional scalar degree of freedom. Unlike general relativity, where the leading order gravitational radiation is produced by quadrupole moments, the additional degree of freedom predicts gravitational radiation of all multipoles, in particular, monopoles and dipoles, as this is the case for the most alternative gravity theories known today. An application to a hypothetical binary pulsar moving in a circular orbit yields the rough limit a 17 m 2 by constraining the dipole power to account at most for 1% of the quadrupole power as predicted by general relativity.

  2. Le paludisme grave d’importation chez l’adulte: étude rétrospective de treize cas admis en réanimation à Marrakech

    Science.gov (United States)

    El Mezouari, El Mostafa; Belhadj, Ayoub; Ziani, Mohamed; Boughanem, Mohamed; Moutaj, Redouane

    2016-01-01

    Le paludisme d’importation est une affection de plus en plus fréquente en zone non endémique. Les formes graves représentent 10 % des cas de paludisme à Plasmodium falciparum. Au Maroc, plus de 50 cas de paludisme sont enregistrés chaque année dont 83 % à P. falciparum. Ont été inclus dans l’étude tous les patients ayant développé un paludisme grave, admis au service de réanimation durant la période comprise entre le 1er Novembre 2009 et le 31 décembre 2015. Les principales données épidémiologiques, les motifs d’admission, la prise en charge et l’évolution ont été étudiés. Treize patients sont retenus. L’âge moyen est de 31 ans. Tous les patients ont séjourné en afrique subsaharienne et étaient non-immuns. La chimioprophylaxie était adéquate dans 33% des cas. Le délai moyen entre le début des symptômes et l’instauration du traitement était de six jours. La parasitémie moyenne initiale était de 12 %. Les motifs d’admission en réanimation étaient un coma (15%), une convulsion (07%), une détresse respiratoire (07%), une prostration (07%), une insuffisance rénale (07%), un choc associé à un ictère et une acidose (07%) et enfin une insuffisance rénale conjuguée à un coma (07%). Tous les patients ont reçu un traitement par la quinine intraveineuse avec une dose de charge dans 100 % des cas. Le taux de mortalité était de 23 %. Les causes du décès étaient dues à la défaillance multi viscérale et au syndrome de détresse respiratoire aigu. La mortalité des formes graves du paludisme reste élevée. L’adéquation de la chimioprophylaxie associée à la précocité du diagnostic et du traitement permettrait d’améliorer significativement le pronostic de cette parasitose. PMID:28292141

  3. Light induced heterogeneous ozone processing on the pesticides adsorbed on silica particles

    Science.gov (United States)

    Socorro, J.; Désert, M.; Quivet, E.; Gligorovski, S.; Wortham, H.

    2013-12-01

    In France, in 2010, the sales of pesticides reached 1.8 billion euros for 61 900 tons of active ingredients, positioning France as a first European consumer of pesticides, as reported by the European Crop Protection Association. About 19 million hectares of crops are sprayed annually with pesticides, i.e., 35% of the total surface area of France. This corresponds to an average pesticide dose of 3.2 kg ha-1. The consumption of herbicide and fungicide is favoured in comparison to the use of insecticides in France and the other European countries, as well. The partitioning of pesticides between the gas and particulate phases influences the atmospheric fate of these compounds such as their photo-chemical degradation. There is much uncertainty concerning the behavior of the pesticides in the atmosphere. Especially, there is a gap of knowledge concerning the degradation of the pesticides induced by heterogeneous reactions in absence and especially in presence of solar light. Considering that most of the pesticides currently used are semi-volatile, it is of crucial importance to investigate the heterogeneous reactivity of particulate pesticides with light and with atmospheric oxidants such as ozone and OH radical. The aim of the present work is to evaluate the light induced heterogeneous ozonation of suspended pesticide particles. 8 pesticides (cyprodinil, deltamethrin, difenoconazole, fipronil, oxadiazon, pendimethalin, permethrin and tetraconazole) were chosen for their physico-chemical properties and their concentration levels in the PACA (Région Provence-Alpes-Côte d'Azur) region, France. Silica particles with well-known properties were chosen as model particles of atmospheric relevance. Kinetic rate constants were determined to allow estimate the atmospheric lifetimes relating to ozone. The rate constants were determined as follows: k = (6.6 × 0.2) 10-19, (7.2 × 0.3) 10-19, (5.1 × 0.5) 10-19, (3.9 × 0.3) 10-19 [cm3 molecules-1 s-1] for Cyprodinil

  4. Solar system and equivalence principle constraints on f(R) gravity by the chameleon approach

    International Nuclear Information System (INIS)

    Capozziello, Salvatore; Tsujikawa, Shinji

    2008-01-01

    We study constraints on f(R) dark energy models from solar system experiments combined with experiments on the violation of the equivalence principle. When the mass of an equivalent scalar field degree of freedom is heavy in a region with high density, a spherically symmetric body has a thin shell so that an effective coupling of the fifth force is suppressed through a chameleon mechanism. We place experimental bounds on the cosmologically viable models recently proposed in the literature that have an asymptotic form f(R)=R-λR c [1-(R c /R) 2n ] in the regime R>>R c . From the solar system constraints on the post-Newtonian parameter γ, we derive the bound n>0.5, whereas the constraints from the violations of the weak and strong equivalence principles give the bound n>0.9. This allows a possibility to find the deviation from the Λ-cold dark matter (ΛCDM) cosmological model. For the model f(R)=R-λR c (R/R c ) p with 0 -10 , which shows that this model is hardly distinguishable from the ΛCDM cosmology

  5. Clinical significance of determination of changes of gingival crevicular fluid IL-10, IL-18 and IFN-γLevels in patients periodontitis

    International Nuclear Information System (INIS)

    Chao Rei

    2009-01-01

    Objective: To explore the clinical significance of changes of gingival crevicular fluid levels of interleukin-10 (IL-10), interleukin-18 (IL-18) and interferon-γ were determined with RIA in 42 patients with periodontitis both before and after trentment as well as in 30 controls. Results: Before treatment, the gingival crevicular fluid level of IL-18 and IFN-γ in the patients were significant higher than those in controls (P 0.05). After one month of treatment, the gingival crevigcular fluid levels of IL-18 and IFN-γ were markedly dropped, but remained significantly higher than those in controls (P<0.05). The gingival crevicular fluid levels of IL-10 were markedly dropped, but remained significantly higher than those in controls (P<0.05). The gingival crevicular fluid levels of IL-10 were significant higher than those in controls (P<0.01). The gingival fluid contents of IL-10 and IL-18 were positively correlated with the depth of periodontal pouch and looseness of attachment (r= 0.2617, r= 0.2802, P<0.05) but the interferon-γ contents were negatively correlated (r= -0.1743, P<0.05). Conclusion: The changes of gingival carvacrol fluid levels of interleukin-10, interleukin-18 and If-γ in patients with periodontics suggested that there were disturbances of immunomodulation. (authors)

  6. Preparation, Spectroscopic Characterization, and Frontier MO Study of the Heteronuclear Luminescent [Pt(2)Au(2)(dmb)(2)(PPh(3))(4)](PF(6))(2) Cluster (dmb = 1,8-Diisocyano-p-menthane). A Cluster with a Formal Au(0)-Au(0) Bond Encapsulated inside a "Pt(2)(dmb)(2)(2+) " Fragment.

    Science.gov (United States)

    Zhang, Tianle; Drouin, Marc; Harvey, Pierre D.

    1999-11-01

    The title compound is prepared from the direct reaction of Pt(2)(dba)(3) (dba = dibenzylideneacetone) and [Au(PPh(3))(2)](PF(6)) in the presence of 1,8-diisocyano-p-methane (dmb), with Pt(2)(dmb)(2)Cl(2), [Pt(4)(dmb)(4)(PPh(3))(2)](PF(6))(2), and (PPh(3))AuCl being formed as parallel products. X-ray crystallography reveals the presence of a quasi-linear PPh(3)Au-AuPPh(3) fragment encapsulated inside a "Pt(2)(dmb)(2)(2+)" ring which is axially coordinated with two PPh(3) ligands. The d(AuAu) is 2.5977(6) Å and is indicative of a strong Au-Au single bond. The IR nu(CN) data reveal that the Pt oxidation state is I, which places the Au oxidation state at 0. The PtAu distances are 2.8422(5) and 2.8082(5) Å. The Raman-active nu(Au(2)), nu(PtAu) (b(2g) + a(g)), nu(PtP), nu(AuP), and nu(PtC) are found at 121.2, approximately 100, 85.5, 162.1, 183.1, and 457.2, and 440.9 cm(-)(1), respectively. The PtAu (0.67 mdyn Å(-)(1)) and Au(2) (1.21 mdyn Å(-)(1)) force constants (F) confirm the presence of medium PtAu and strong Au(2) bonding interactions. The absorption spectra are characterized by strong bands at lambda(max) (epsilon, M(-1) cm(-1)) at 316 (32 300), 366 (37 800), and 418 nm (21 500) and lower intensity features at 516 (2860) and 655 nm (834). The cluster is luminescent at low temperatures (solid and frozen glasses), and in the solid state at room temperature, and exhibits an emission band at approximately 875 nm, and an emission lifetime, tau(e), of 4.4 +/- 0.4 ns (solvent = butyronitrile, T = 77 K).

  7. 10 CFR 605.18 - National security.

    Science.gov (United States)

    2010-01-01

    ... 10 Energy 4 2010-01-01 2010-01-01 false National security. 605.18 Section 605.18 Energy DEPARTMENT... PROGRAM § 605.18 National security. Activities under ER's Financial Assistance Program shall not involve classified information (i.e., Restricted Data, formerly Restricted Data, National Security Information...

  8. 18 CFR 34.10 - Reports.

    Science.gov (United States)

    2010-04-01

    ... 18 Conservation of Power and Water Resources 1 2010-04-01 2010-04-01 false Reports. 34.10 Section 34.10 Conservation of Power and Water Resources FEDERAL ENERGY REGULATORY COMMISSION, DEPARTMENT OF... SECURITIES OR THE ASSUMPTION OF LIABILITIES § 34.10 Reports. The applicant must file reports under § 131.43...

  9. Détermination de quelques paramètres hématologiques chez les agriculteurs exposés aux pesticides dans la région de Tlemcen

    OpenAIRE

    SAIDI, Fatima Zohra

    2015-01-01

    Résumé Les pesticides représentent une large gamme de produits utilisés de façon très variable. Les agriculteurs sont aujourd'hui le groupe le plus exposé aux risques de contact avec les pesticides. L'objectif de notre travail consiste à mettre en évidence les altérations hématologiques chez les hommes agriculteurs disposés aux pesticides comparés aux hommes témoins. Un prélèvement sanguin est réalisé afin de déterminer quelques paramètres hématologiques (FNS, numérations cellu...

  10. Rate Processes in Dissipative Systems: 50 Years After Kramers, Discussion Meeting Held in Tutzing (Germany, F.R.) on 10-13 September 1990

    Science.gov (United States)

    1990-09-13

    Chem. Soc., Faraday Trans. [5] S. T. Abdel-Halim, M. H. Abdel-Kader, and U. E. Steiner , J. 2, 83, 1941 (1987), Phys. Chem 92, 4324 (1988). [29] W...December 5th, 1990) Zusammensetzung, Eigenschaften und Anwendungen Mesomorpher Tensidphasen RUDOLF HEUSCH Leverkusen, Paul-Klee-StraBe 85 (Received on...Institut f~r Anorganisehe Chemnie der Universitiit Rudower Chaussee 5, 0-1199 Physikalisehe Chemie) Rudolf - Bern, Freie Stra~e 3, CH-3000 Bern, be- Berlin

  11. Método analítico para la determinación de etilentiourea (etu subproducto del Mancozeb en un Andisol del Oriente Antioqueño

    Directory of Open Access Journals (Sweden)

    María Carolina Domínguez

    2009-01-01

    Full Text Available El Mancozeb (etilenbisditiocarbamato de cinc y manganeso es uno de los fungicidas de mayor uso en Colombia, y esta clasificado en la categoría toxicológica IV. La etilentiourea (ETU es el principal producto de degradación del Mancozeb, estando clasificada en la categoría toxicológica I debido a que es carcinogénico y mutagénico, lo que lo convierte en un compuesto de alto riesgo para la salud de las personas. En el presente trabajo se validó un método de análisis de la ETU utilizando la cromatografía de líquidos (CL con detector de arreglo de diodos (DAD, el cual se usó para la cuantificación de la ETU en suelos del municipio de Marinilla (Oriente de Antioquia. El suelo usado en el análisis de la ETU se determinó como un Acrudoxic Fulvudand medial arcilloso mezclado, isomésico; estos suelos son los más utilizados para la agricultura en el Departamento de Antioquia y en Colombia. El límite de detección del análisis fue 0,00046 mg/L, el límite de cuantificación fue 0,0015 mg/L y el porcentaje de recuperación en el suelo fue 93%.

  12. Monomers, dimers, and trimers of [Au(CN2]− in a Ba(diaza-18-crown-62+ coordination polymer

    Directory of Open Access Journals (Sweden)

    2009-03-01

    Full Text Available The structure of the title compound, poly[triaquatetra-μ-cyanido-tetracyanidobis(1,4,10,13-tetraoxa-7,16-diazacyclooctadecanedibarium(IItetragold(I], [Au4Ba2(CN8(C12H26N2O42(H2O3]n, displays O—H...N hydrogen bonding between water molecules and cyano ligands and an unusual pattern of aurophilic interactions that yields a monomer, dimer, and trimer of [Au(CN2]− within the same crystal structure. In two of the five Au positions, the atom resides on a center of inversion. The overall arrangement is that of a coordination polymer assisted by aurophilic and hydrogen-bonded interactions.

  13. Environnement politique et réglementaire des pharmacultures au Canada : la contamination pharmaceutique à l’horizon ?

    OpenAIRE

    Bacon, Marie-Hélène

    2009-01-01

    Depuis les années 1980, le gouvernement canadien a misé sur le développement des biotechnologies dans l’intention de faire du pays un "chef de file" dans ce secteur. Plusieurs programmes ainsi que des mesures réglementaires et financières ont été mis de l’avant afin d’atteindre cet objectif. Le Canada se situe donc aujourd’hui parmi les premiers pays au monde en termes de cultures d’organismes génétiquement modifiés (OGM) à visé agroalimentaire. Au sein des nombreux champs d’OGM canadiens se...

  14. Assessment of pesticide residues in some fruits using gas chromatography coupled with micro electron capture detector

    International Nuclear Information System (INIS)

    Latif, Y.; Sherazi, S.T.H.; Bhanger, M.I.

    2011-01-01

    A very sensitive analytical method for the determination of 26 pesticides in some fruits based on solid phase extraction (SPE) cleanup was developed using gas chromatography (GC) coupled with micro electron capture detector (mu ECD). The identity of the pesticides was confirmed by gas chromatography mass spectroscopy (GC-MS) using selected ion monitoring (SIM) mode. Ethyl acetate was used as a solvent for the extraction of pesticide residues with assistance of sonication. For cleanup an octadecyl, C18 SPE column was used. A linear response of mu ECD was observed for all pesticides with good correlation coefficients (>0.9992). Proposed method was successfully applied for the determination of pesticide residues in the orange, apple, and grape fruits. Average recoveries achieved for all of the pesticides at fortification levels of 0.05, 1.0 and 2.0 mu g g/sup -1/ in analyzed fruits were above 90% with relative standard deviations (RSD) less than 6%. (author)

  15. Assessment of Pesticide Residues in Some Fruits Using Gas Chromatography Coupled with Micro Electron Capture Detector

    Directory of Open Access Journals (Sweden)

    M. I. Bhanger

    2011-12-01

    Full Text Available A very sensitive analytical method for the determination of 26 pesticides in some fruits based on solid phase extraction (SPE cleanup was developed using gas chromatography (GC coupled with micro electron capture detector (μECD. The identity of the pesticides was confirmed by gas chromatography mass spectroscopy (GC-MS using selected ion monitoring (SIM mode. Ethyl acetate was used as a solvent for the extraction of pesticide residues with assistance of sonication. For cleanup an octadecyl, C18 SPE column was used. A linear response of μECD was observed for all pesticides with good correlation coefficients (>0.9992. Proposed method was successfully applied for the determination of pesticide residues in the orange, apple, and grape fruits. Average recoveries achieved for all of the pesticides at fortification levels of 0.05, 1.0 and 2.0 μg g-1 in analyzed fruits were above 90% with relative standard deviations (RSD less than 6

  16. Nanosensing of Pesticides by Zinc Oxide Quantum Dot: An Optical and Electrochemical Approach for the Detection of Pesticides in Water.

    Science.gov (United States)

    Sahoo, Dibakar; Mandal, Abhishek; Mitra, Tapas; Chakraborty, Kaushik; Bardhan, Munmun; Dasgupta, Anjan Kumar

    2018-01-17

    Present study reveals the low concentrations (∼4 ppm) of pesticide sensing vis-à-vis degradation of pesticides with the help of nontoxic zinc oxide quantum dots (QD). In our study, we have taken four different pesticides viz., aldrin, tetradifon, glyphosate, and atrazine, which are widely used in agriculture and have structural dissimilarities/diversity. By using optical sensing techniques such as steady state and time-resolved fluorescence, we have analyzed the detailed exciton dynamics of QD in the presence of different pesticides. It has been found that the pesticide containing good leaving groups (-Cl) can interact with QD promptly and has high binding affinity (∼10 7 M -1 ). The different binding signatures of QD with different pesticides enable us to differentiate between the pesticides. Time resolved fluorescence spectroscopy provides significant variance (∼150-300 ns) for different pesticides. Furthermore, a large variation (10 5 Ω to 7 × 10 4 Ω) in the resistance of QD in the presence of different pesticides was revealed by electrochemical sensing technique. Moreover, during the interaction with pesticides, QD can also act as a photocatalyst to degrade pesticides. Present investigation explored the fact that the rate of degradation is positively affected by the binding affinity, i.e., the greater the binding, the greater is the degradation. What is more, both optical and electrochemical measurements of QD, in tandem, as described in our study could be utilized as the pattern recognition sensor for detection of several pesticides.

  17. 3He induced reactions on natAg and 197Au at 1.8, 3.6 and 4.8 GeV

    International Nuclear Information System (INIS)

    Brzychczyk, J.; Jagiellonian Univ., Krakow; Pollacco, E.C.; Volant, C.; Legrain, R.; Kwiatkowski, K.; Morley, K.B.; Renshaw-Foxford, E.; Bracken, D.S.; Viola, V.E.; Yoder, N.R.

    1995-03-01

    The 3 He induced reactions on Ag and Au are studied using a large solid angle and low energy threshold detector array. The data show consistency with intranuclear cascade and expanding emitting source description. Charge moment analysis is presented. (author). 18 refs., 8 figs

  18. 75 FR 51043 - Pesticide Experimental Use Permit; Receipt of Application; Comment Request

    Science.gov (United States)

    2010-08-18

    ... Pollution Prevention Division (7511P), Office of Pesticide Programs, Environmental Protection Agency, 1200... tests on 10 acres or more of land or one acre or more of water. Pursuant to 40 CFR 172.11(a), the Agency..., Kansas, Kentucky, Louisiana, Maryland, Missouri, Mississippi, New Mexico, North Carolina, Oklahoma Puerto...

  19. La réflexion stratégique, objet et outil de recherche pour le management stratégique ?

    OpenAIRE

    Torset, Christophe

    2005-01-01

    International audience; La littérature sur la formation de la stratégie utilise fréquemment l'expression « réflexion stratégique ». Cette notion est susceptible de faciliter l'analyse des processus en favorisant une démarche plus systémique, capable de regrouper et prendre en considération différents niveaux organisationnels et différentes formes de genèse des idées stratégiques. Cette communication propose une revue des caractéristiques de la notion de réflexion stratégique, au regard notamm...

  20. Measurement of the 19F(n,2n)18F cross section from 18 to 27 MeV

    International Nuclear Information System (INIS)

    Hartmann, C.L.; DeLuca, P.M. Jr.

    1990-01-01

    the 19 F(n,2n) 18 F cross section was measured at neutron energies of 18, 21, 23, and 27 MeV. Nearly monoenergetic neutrons bombarded teflon (CF 2 ), Zr, and Au samples. 19 F(n,2n) 18 F cross section values were determined relative to nat Zr(n,xn) 89 Zr and 197 Au(n,2n) 196 Au from measurements of the 18 F, 89 Zr, and 196 Au activities. Our results are in agreement with previous measurements below 20 MeV and extend the usefulness of this reaction to 27 MeV. 22 refs., 1 fig., 2 tabs

  1. 78 FR 24094 - Azoxystrobin; Pesticide Tolerances

    Science.gov (United States)

    2013-04-24

    ... Statistics Service (USDA/NASS), proprietary market surveys, and the National Pesticide Use Database for the... 1 to the table in paragraph (a)(1); and 0 e. Revise the introductory text of paragraph (a)(2) The...

  2. Atmospheric pressure gas chromatography quadrupole-time-of-flight mass spectrometry for simultaneous determination of fifteen organochlorine pesticides in soil and water.

    Science.gov (United States)

    Cheng, Zhipeng; Dong, Fengshou; Xu, Jun; Liu, Xingang; Wu, Xiaohu; Chen, Zenglong; Pan, Xinglu; Zheng, Yongquan

    2016-02-26

    In this study, the application of atmospheric pressure gas chromatography quadrupole-time-of-flight mass spectrometry (APGC-QTOF-MS) has been investigated for simultaneous determination of fifteen organochlorine pesticides in soil and water. Soft ionization of atmospheric pressure gas chromatography was evaluated by comparing with traditional more energetic electron impact ionization (EI). APGC-QTOF-MS showed a sensitivity enhancement by approximately 7-305 times. The QuEChERs (Quick, Easy, Cheap, Effective, Rugged, and Safe) method was used to pretreat the soil samples and solid phase extraction (SPE) cleanup was used for water samples. Precision, accuracy and stability experiments were undertaken to evaluate the feasibility of the method. The results showed that the mean recoveries for all the pesticides from the soil samples were 70.3-118.9% with 0.4-18.3% intra-day relative standard deviations (RSD) and 1.0-15.6% inter-day RSD at 10, 50 and 500 μg/L levels, while the mean recoveries of water samples were 70.0-118.0% with 1.1-17.8% intra-day RSD and 0.5-12.2% inter-day RSD at 0.1, 0.5 and 1.0 μg/L levels. Excellent linearity (0.9931 ≦ r(2)≤ 0.9999) was obtained for each pesticides in the soil and water matrix calibration curves within the range of 0.01-1.0mg/L. The limits of detection (LOD) for each of the 15 pesticides was less than 3.00 μg/L, while the limit of quantification (LOQ) was less than 9.99 μg/L in soil and water. Furthermore, the developed method was successfully applied to monitor the targeted pesticides in real soil and water samples. Copyright © 2016 Elsevier B.V. All rights reserved.

  3. L'APPRENTISSAGE AU CERN - French version only

    CERN Multimedia

    Roland GAY

    2002-01-01

    APPRENTISSAGES TECHNIQUES FORMATION ET DEVELOPPEMENT HR/TD/AP L'APPRENTISSAGE AU CERN pour les professions d'électronicien(ne) et de laborant(ine) en physique L'apprentissage au CERN est régi par les lois, règlements et contrats en vigueur dans le Canton de Genève. En cas de réussite à l'examen de fin d'apprentissage, les apprentis obtiennent le Certificat Fédéral de Capacité Suisse (CFC). 7 places au total sont ouvertes au recrutement pour les deux professions. L'apprentissage dure 4 ans. Minima requis pour faire acte de candidature :   avoir terminé la scolarité obligatoire être ressortissant d'un pays membre du CERN (Allemagne, Autriche, Belgique, Bulgarie, Danemark, Espagne, Finlande, France, Grèce, Hongrie, Italie, Norvège, Pays-Bas, Pologne, Portugal, République slovaque, République tchèque, Royaume-Uni, Su&a...

  4. Datation de la grossesse en pratique courante au Cameroun: fiabilité de la date de dernières règles

    Science.gov (United States)

    Ngowa, Jean Dupont Kemfang; Mando, Emmanuel; Guegang, Emilienne; Ngassam, Anny; Kasia, Jean Marie

    2014-01-01

    Introduction La détermination précise de l’âge gestationnel (AG) est essentielle pour un suivi adapté de la grossesse. La date de dernières règles (DDR) et l’échographie de datation du premier trimestre sont les moyens habituels de datation de la grossesse. La DDR est souvent imprécise du fait des erreurs de rappel ou d'un trouble du cycle menstruel. Cette étude transversale et descriptive avait pour objectif d’évaluer la fiabilité de la DDR dans la datation de la grossesse en pratique courante à Yaoundé. Méthodes Etude transversale et descriptive réalisée dans deux hôpitaux universitaires de Yaoundé du 15 décembre 2012 au 15 avril 2013. La collecte des données était effectuée par un interrogatoire des femmes enceintes au cours de la consultation prénatale et l'examen de leur dossier médical. Les femmes enceintes présentant une complication du premier trimestre (menace d'avortement, grossesse arrêtée ou extra-utérine, grossesse molaire) et celles ne se rappelant pas de leur DDR ont été exclues de l’étude. Les données étaient saisies dans Epi-Data 3.1 et analysées dans le logiciel SPSS. 21. Résultats Cinq cent huit femmes enceintes ont été enrôlées dans cette étude, 267(52,56%) d'entre elles avaient noté leur DDR sur un support tandis que 241(47,44%) utilisaient leur mémoire pour se rappeler leur DDR. Cent dix-sept (23,03%) femmes enceintes avait réalisé une échographie de datation du premier trimestre et parmi elles, 50 (42,70%) avaient une discordance des âges gestationnels théorique et échographique. Le rappel de la DDR par la mémoire (OR. 3,46; IC: 1,59-7,53), le cycle irrégulier (OR. 6,15; IC: 1,24-30,4) et le doute sur la DDR communiquée (OR. 31,06; IC: 3.95-244) étaient les facteurs significativement associés à la discordance des AG théorique et échographique. Conclusion La DDR utilisée pour la datation de la grossesse en pratique courante à Yaoundé est fréquemment imprécise. PMID:25309664

  5. Pesticides residue levels in selected fruits from some Ghanaian markets

    International Nuclear Information System (INIS)

    Bempah, K.C.

    2009-02-01

    The amount of some pesticide residues in fruits was monitored at five (5) Accra Metropolis markets. Locally produced fruits (pawpaw and tomato) and imported apples were purchased from two supermarkets and three urban markets in Accra metropolis and analyzed by gas chromatography equipped with electron capture detector for pesticide residues. A total of 220 samples of fruits were extracted and analyzed for pesticide residues, mainly organochlorines (γ-HCH, δ-HCH, aldrin, heptachlor, γ-chlordane, heptachlor epoxide, α-endosulfan, p,p'-DDE, endrin, β-endosulfan, o,p'-DDT, endrin aldehyde, p,p'- DDT, endrin ketone and methoxychlor). The data showed that most of the fruit samples analyzed contain residues of the monitored pesticides above the accepted maximum residue limit (MRL) as adopted by the FAO/WHO Codex Alimentarius Commission (CAC). The results obtained showed that 38.6 % fruit samples showed results above the MRL, 48.7 % were below the MRL and 12.7 % contained no detectable level of the monitored pesticides. Data analysis of health risk estimates indicated that, particularly γ-HCH, δ-HCH, o,p'-DDT, p,p'-DDE or p,p'-DDT do not pose a direct hazard to human health, although present in the three fruits (pawpaw, tomato and apple). However, heptachlor, heptachlor epoxide, endrin aldehyde, and endrin ketone levels exceeded the reference dose, indicating a great potential for systemic toxicity, especially in children who are considered to be the most vulnerable population subgroup. Lastly, the public is aware of pesticide residues in fruits and advocates for the curtailing of pesticide use on horticulture produce or strong educational programmes for farmers on control and safer use of pesticides. (au)

  6. pesticide residues in water from tpc sugarcane plantations

    African Journals Online (AJOL)

    ABSTRACT. We report herein, the analysis of water samples collected from TPC Sugarcane Plantation and its environs in Kilimanjaro region, which is the earliest intensive user of pesticides in Tanzania. A total of 50 water samples collected from 18 sampling sites between 2000 and 2001 were analyzed for pesticide ...

  7. Reliability of concentrations of organophosphate pesticide metabolites in serial urine specimens from pregnancy in the Generation R study

    Science.gov (United States)

    Spaan, Suzanne; Pronk, Anjoeka; Koch, Holger M.; Jusko, Todd A.; Jaddoe, Vincent W.V.; Shaw, Pamela A.; Tiemeier, Henning M.; Hofman, Albert; Pierik, Frank H.; Longnecker, Matthew P.

    2014-01-01

    The widespread use of organophosphate (OP) pesticides has resulted in ubiquitous exposure in humans, primarily through their diet. Exposure to OP pesticides may have adverse health effects, including neurobehavioral deficits in children. The optimal design of new studies requires data on the reliability of urinary measures of exposure. In the present study, urinary concentrations of six dialkyl phosphate (DAP) metabolites, the main urinary metabolites of OP pesticides, were determined in 120 pregnant women participating in the Generation R Study in Rotterdam. Intra-class correlation coefficients (ICCs) across serial urine specimens taken at 25 weeks of pregnancy were determined to assess reliability. Geometric mean total DAP metabolite concentrations were 229 (GSD 2.2), 240 (GSD 2.1), and 224 (GSD 2.2) nmol/g creatinine across the three periods of gestation. Metabolite concentrations from the serial urine specimens in general correlated moderately. The ICCs for the six DAP metabolites ranged from 0.14 to 0.38 (0.30 for total DAPs), indicating weak to moderate reliability. Although the DAP metabolite levels observed in this study are slightly higher and slightly more correlated than in previous studies, the low to moderate reliability indicates a high degree of within-person variability, which presents challenges for designing well-powered epidemiologic studies. PMID:25515376

  8. Pesticide Use and Asthma in Alberta Grain Farmers

    Directory of Open Access Journals (Sweden)

    Nicola Cherry

    2018-03-01

    Full Text Available A study of the respiratory health of grain farmers in Alberta, Canada was carried out in March 2002. Two populations were identified: members, in 1983, of a province-wide farm organisation, and grain farmers registered with the provincial agriculture department. A telephone interview addressed pesticide use (using pre-circulated trade names, chronic disease and respiratory symptoms. Pesticide ingredients were identified from provincial crop protection guides. Total years of use were calculated for seven chemical groups. Consent for linkage to administrative health records was obtained in 2009. A likelihood score (Lscore is computed, relating symptoms to asthma diagnosis. Self-reported asthma and the Lscore are examined against duration of pesticide exposures. Of the 10,767 farmers listed, 2426 were still living, had farmed grain and were interviewed; 1371 were re-contacted and matched to health records. After allowance for confounders, years of exposure to phenoxy compounds are related to self-reported asthma and Lscore. Compared to no exposure, the adjusted odds ratios (95% Confidence Intervals for self-reported asthma for short, medium and long exposure to phenoxy compounds are 1.29 (0.66–2.52, 2.52 (1.25–5.09, and 3.18 (1.54–6.58, and for Lscore are 1.19 (0.91–1.55, 1.50 (1.13–1.99, and 1.58 (1.18–2.12. We conclude that lifetime exposure to phenoxy herbicides is associated with an increased risk of asthma.

  9. The adsorption of Tl(I), Au(III), Cu(II) and the separation of 199Tl from alpha bombardment of gold target with PDB-18C6

    International Nuclear Information System (INIS)

    Zhou Dehai; Zhou Jimeng

    1989-01-01

    The adsorptive behavior of polymer of methyl aldehyde of dibenzo-18-crown-6 (PDB-18C6) in hydrochloric acid medium is studied and it is shown that the adsorption of T1(I), Au(III), and Cu(II) depends on the particle size of the crown ether resins, hydrochloric acid concentration and amount of the crown ether resins used. The difference in the adsorption behavior of different particle sizes of crown ether resins may be used for separating Tl(I), Au(III), and Cu(II) ions. The best eluant of Tl(I) and Au(III) is 0.4 mol/l perchloric acid and 2-ethoxy-ethanol. The recovery for Tl(I) is 82-98.8%. The gold target is bombarded in a 1.2 m cyclotron with 25-27 MeV α-particle with a cumulative beam intensities of 27μA·h, and 199 Tl is separated from the gold target with PDB-18C6. γ-spectrometry has shown that the Tl obtained is 199 Tl of high purity containing only about 0.50% 200 Tl

  10. Monte Carlo determinations of the functions Λ(r, Z), G(r, θ), g(R) and F(r, θ) for Amersham CDCS-M-type 137Cs source

    International Nuclear Information System (INIS)

    Valdez, F. Roberto Fragoso; Alvarez Romero, J. Trinidad

    2001-01-01

    The functions Λ(r, z), G(r, θ), g(r) and F(r, θ) were calculated for Amersham model CDCS-M-type 137 Cs source by means of Monte Carlo simulation using the algorithm PENELOPE. These functions are required to verify and/or to feed planning systems or directly as entrance data for the manual planning of the distribution of absorbed dose according with the recommendations of the TG 43, [1]. The values of the constant Λ (r, Z) were determined as the quotient of absorbed dose rate distribution in water and air kerma strength in 'free air' S k . The values obtained for Λ (r, Z) differ up to 3% of those reported in the literature, being very sensitive to the cutoff energy for the electrons in the interface of the source's encapsulated and water

  11. Analytical Diagnostics of Non-Optimal Use of Pesticides and Health Hazards for Vegetable Pickers

    International Nuclear Information System (INIS)

    Zafar, M.; Mehmood, T.; Baig, I. A.; Saboor, A.; Sadiq, S.; Mahmood, K.

    2016-01-01

    Economically pesticides are meant to control pests in the fields. Up to certain optimal use of a typical pesticide, it enhances the yield of crops and vegetables. But, eventually amplified use of pesticides results in contamination of environment (water, soil, and air) and increase the health cost of vegetable pickers. The purpose of this study is to estimate the excessive use of pesticides and economic cost of health hazards for the vegetable pickers in district Vehari. Data from 90 respondents were collected and analyzed. The most common health problems identified during the survey were headache, eye irritation, skin infection, cough and shortness of breath. Health cost consists of costs related to precautionary measure, medication, traveling, the opportunity cost of attended persons and productivity loss. The mean health cost of vegetable pickers in the study area was about Rs. 385 per picker per year. Health cost model was used to measure the health cost of vegetable pickers. The regression results showed that pesticides were being applied non-optimally in the study area i.e., number of pesticide applications for vegetables (7-31) were substantially higher than the recommended dose. Health cost function was significantly different from zero as indicated by F-stat (32.18) and it is also supported by R/sup 2/ that about 70 percent variation in health cost is explained by medication accompanied by productivity loss (Rs. 223), precautionary measure (Rs. 134), attended person cost (Rs. 14) and traveling expenditures (Rs. 16). Hence, strict legislation is required to overcome the availability of hazardous pesticides and to keep the vegetable pickers aware of the optimal use of pesticides through appropriate extension services. (author)

  12. L'APPRENTISSAGE AU CERN - French version only

    CERN Multimedia

    Roland Gay

    2002-01-01

    APPRENTISSAGES TECHNIQUES FORMATION ET DEVELOPPEMENT HR/TD/AP L'apprentissage au CERN est régi par les lois, règlements et contrats en vigueur dans le Canton de Genève. En cas de réussite à l'examen de fin d'apprentissage, les apprentis obtiennent le Certificat Fédéral de Capacité Suisse (CFC). 7 places au total sont ouvertes au recrutement pour les deux professions. L'apprentissage dure 4 ans. Minima requis pour faire acte de candidature :   avoir terminé la scolarité obligatoire être ressortissant d'un pays membre du CERN (Allemagne, Autriche, Belgique, Bulgarie, Danemark, Espagne, Finlande, France, Grèce, Hongrie, Italie, Norvège, Pays-Bas, Pologne, Portugal, République slovaque, République tchèque, Royaume-Uni, Suède, Suisse) avoir au moins 15 ans et moins de 21 ans à la date de début de ...

  13. Reduced Graphene Oxide/Au Nanocomposite for NO2 Sensing at Low Operating Temperature

    Directory of Open Access Journals (Sweden)

    Hao Zhang

    2016-07-01

    Full Text Available A reduced grapheme oxide (rGO/Au hybrid nanocomposite has been synthesized by hydrothermal treatment using graphite and HAuCl4 as the precursors. Characterization, including X-ray diffraction (XRD, Raman spectra, X-ray photoelecton spectroscopy (XPS and transmission electron microscopy (TEM, indicates the formation of rGO/Au. A gas sensor fabricated with rGO/Au nanocomposite was applied for NO2 detection at 50 °C. Compared with pure rGO, rGO/Au nanocomposite exhibits higher sensitivity, a more rapid response–recovery process and excellent reproducibility.

  14. Du type au stéréotype : analyse des modalités d’insertion des stéréotypes des physiologies dans Bouvard et Pécuchet

    Directory of Open Access Journals (Sweden)

    Vincent Stohler

    2011-01-01

    Full Text Available Cette analyse a pour but d’exposer la manière dont Flaubert récupère les stéréotypes présents dans les physiologies, genre littéraire à la mode dans la première moitié du XIXe siècle, en définissant leurs différentes modalités d’insertion dans Bouvard et Pécuchet. Après s’être interrogée sur le statut particulier des physiologies, l’étude montre que les différents types qu’elles mettent en scène, et plus particulièrement celui du « bourgeois », fournissent à Flaubert un matériel discursif stéréotypé qui lui sert de base de composition à l’ensemble de son texte : composition des personnages (traits physiques, caractériels, axiologiques, etc., composition structurelle du roman, etc. La démonstration attire ainsi l’attention sur ce qui paraît être l’une des lignes de force de l’écriture flaubertienne : l’amenuisement au sein de l’espace romanesque du langage de l’auteur au profit d’un langage stéréotypé, venu d’ailleurs.

  15. L'APPRENTISSAGE AU CERN - French version only

    CERN Multimedia

    2003-01-01

    APPRENTISSAGES TECHNIQUES FORMATION ET DEVELOPPEMENT HR/TD/AP L'APPRENTISSAGE AU CERN pour les professions d'électronicien(ne) et de laborantin(e) en physique L'apprentissage au CERN est régi par les lois, règlements et contrats en vigueur dans le Canton de Genève. En cas de réussite à l'examen de fin d'apprentissage, les apprentis obtiennent le Certificat Fédéral de Capacité Suisse (CFC). 7 places au total sont ouvertes au recrutement pour les deux professions. L'apprentissage dure 4 ans. Minima requis pour faire acte de candidature : - avoir terminé la scolarité obligatoire - être ressortissant d'un pays membre du CERN (Allemagne, Autriche, Belgique, Bulgarie, Danemark, Espagne, Finlande, France, Grèce, Hongrie, Italie, Norvège, Pays-Bas, Pologne, Portugal, République slovaque, République tchèque, Royaume-Uni, Suède, Suisse) - avoir au moins 15 ans et moins de 21 ans à la date de début de l'apprentissage - avoir un niveau scolaire correspondant à la 9ème générale ou moderne...

  16. Nonlinear evolution of f(R) cosmologies. II. Power spectrum

    International Nuclear Information System (INIS)

    Oyaizu, Hiroaki; Hu, Wayne; Lima, Marcos

    2008-01-01

    We carry out a suite of cosmological simulations of modified action f(R) models where cosmic acceleration arises from an alteration of gravity instead of dark energy. These models introduce an extra scalar degree of freedom which enhances the force of gravity below the inverse mass or Compton scale of the scalar. The simulations exhibit the so-called chameleon mechanism, necessary for satisfying local constraints on gravity, where this scale depends on environment, in particular, the depth of the local gravitational potential. We find that the chameleon mechanism can substantially suppress the enhancement of power spectrum in the nonlinear regime if the background field value is comparable to or smaller than the depth of the gravitational potentials of typical structures. Nonetheless power spectrum enhancements at intermediate scales remain at a measurable level for models even when the expansion history is indistinguishable from a cosmological constant, cold dark matter model. Simple scaling relations that take the linear power spectrum into a nonlinear spectrum fail to capture the modifications of f(R) due to the change in collapsed structures, the chameleon mechanism, and the time evolution of the modifications.

  17. 76 FR 5704 - Sulfentrazone; Pesticide Tolerances

    Science.gov (United States)

    2011-02-02

    ... sulfentrazone, citing the cruelty of animal testing as the main source of opposition. The Agency has received... (NAICS code 111). Animal production (NAICS code 112). Food manufacturing (NAICS code 311). Pesticide...). UFA = extrapolation from animal to human (interspecies). UFH = potential variation in sensitivity...

  18. 78 FR 33736 - Imidacloprid; Pesticide Tolerances

    Science.gov (United States)

    2013-06-05

    ... exposure assessments of pesticides found in swimming pools and spas and EPA's Risk Assessment Guidance for... during recreational swimming, or in the case of subsistence fishermen or local Native American tribes... Order 13211, entitled ``Actions Concerning Regulations That Significantly Affect Energy Supply...

  19. 77 FR 42433 - Difenoconazole; Pesticide Tolerances

    Science.gov (United States)

    2012-07-19

    ... characteristics of difenoconazole. Further information regarding EPA drinking water models used in pesticide... exposures for which there is reliable information.'' This includes exposure through drinking water and in... States Department of Agriculture (USDA) 1994-1996 and 1998 Nationwide Continuing Surveys of Food Intake...

  20. Anticonvulsant and reproductive toxicological studies of the imidazole-based histamine H3R antagonist 2-18 in mice

    Directory of Open Access Journals (Sweden)

    Bastaki SM

    2018-01-01

    Full Text Available Salim M Bastaki,1 Yousef M Abdulrazzaq,2 Mohamed Shafiullah,1 Małgorzata Więcek,3 Katarzyna Kieć-Kononowicz,3 Bassem Sadek1 1Department of Pharmacology and Therapeutics, College of Medicine and Health Science, United Arab Emirates University, Al Ain, 2Department of Medical Education, Dubai Health Authority, Dubai, UAE; 3Department of Technology and Biotechnology of Drugs, Faculty of Pharmacy, Jagiellonian University Medical College, Medyczna, Kraków, Poland Abstract: The imidazole-based H3R antagonist 2-18 with high in vitro H3R antagonist affinity, excellent in vitro selectivity profile, and high in vivo H3R antagonist potency was tested for its anticonvulsant effect in maximal electroshock (MES-induced convulsions in mice having valproic acid (VPA as a reference antiepileptic drug (AED. Additionally, H3R antagonist 2-18 was evaluated for its reproductive toxicity in the same animal species. The results show that acute systemic administration (intraperitoneal; i.p. of H3R antagonist 2-18 (7.5, 15, 30, and 60 mg/kg, i.p. significantly and dose dependently protected male as well as female mice against MES-induced convulsion. The protective action observed for H3R antagonist 2-18 in both mice sexes was comparable to that of VPA and was reversed when mice were pretreated with the selective H3R agonist (R-alpha-methylhistamine (RAMH, 10 mg/kg, i.p.. Moreover, the results show that acute systemic administration of single (7.5, 15, 30, or 60 mg/kg, i.p. or multiple doses (15×3 mg/kg, i.p. of H3R antagonist 2-18 on gestation day (GD 8 or 13 did not affect the maternal body weight of mice when compared with the control group. Furthermore, no significant differences were observed in the average number of implantations and resorptions between the control and H3R antagonist 2-18-treated group at the early stages of gestation and the organogenesis period. However, oral treatment with H3R antagonist 2-18 (15 mg/kg on GD 8 induced a reduced number of

  1. Travailler avec Windows 7 au CERN (FR)

    CERN Multimedia

    CERN. Geneva

    2010-01-01

    Vue d'ensemble des nouveaux concepts et des changements dans l'interface utilisateur survenus dans Windows 7 depuis les versions antérieures de Windows (XP ou Vista). La mise à disposition de Windows 7 au CERN et son intégration dans l’infrastructure de Windows au CERN seront présentées.

  2. Spherically Symmetric Geometries in f(T) and f(R) Gravitational Theories

    International Nuclear Information System (INIS)

    Nashed, Gamal G. L.

    2015-01-01

    Using the well know relation between Ricci scalar, R, and torsion scalar, T, that is, R=-T-2∇_αT"α, we show that, for any spherically symmetric spacetime whose (i) scalar torsion vanishing, that is, T=T_μ_ν"αS_α"μ"ν=0 or (ii) total derivative term, that is, ∇_αT"α with T"α is the contraction of the torsion, vanishing, or (iii) the combination of scalar torsion and total derivative term vanishing, could be solution for f(T) and f(R) gravitational theories.

  3. Cupriphication of gold to sensitize d10–d10 metal–metal bonds and near-unity phosphorescence quantum yields

    Science.gov (United States)

    Galassi, Rossana; Ghimire, Mukunda M.; Otten, Brooke M.; Ricci, Simone; McDougald, Roy N.; Almotawa, Ruaa M.; Alhmoud, Dieaa; Ivy, Joshua F.; Rawashdeh, Abdel-Monem M.; Nesterov, Vladimir N.; Reinheimer, Eric W.; Daniels, Lee M.; Burini, Alfredo; Omary, Mohammad A.

    2017-01-01

    Outer-shell s0/p0 orbital mixing with d10 orbitals and symmetry reduction upon cupriphication of cyclic trinuclear trigonal-planar gold(I) complexes are found to sensitize ground-state Cu(I)–Au(I) covalent bonds and near-unity phosphorescence quantum yields. Heterobimetallic Au4Cu2 {[Au4(μ-C2,N3-EtIm)4Cu2(µ-3,5-(CF3)2Pz)2], (4a)}, Au2Cu {[Au2(μ-C2,N3-BzIm)2Cu(µ-3,5-(CF3)2Pz)], (1) and [Au2(μ-C2,N3-MeIm)2Cu(µ-3,5-(CF3)2Pz)], (3a)}, AuCu2 {[Au(μ-C2,N3-MeIm)Cu2(µ-3,5-(CF3)2Pz)2], (3b) and [Au(μ-C2,N3-EtIm)Cu2(µ-3,5-(CF3)2Pz)2], (4b)} and stacked Au3/Cu3 {[Au(μ-C2,N3-BzIm)]3[Cu(µ-3,5-(CF3)2Pz)]3, (2)} form upon reacting Au3 {[Au(μ-C2,N3-(N-R)Im)]3 ((N-R)Im = imidazolate; R = benzyl/methyl/ethyl = BzIm/MeIm/EtIm)} with Cu3 {[Cu(μ-3,5-(CF3)2Pz)]3 (3,5-(CF3)2Pz = 3,5-bis(trifluoromethyl)pyrazolate)}. The crystal structures of 1 and 3a reveal stair-step infinite chains whereby adjacent dimer-of-trimer units are noncovalently packed via two Au(I)⋯Cu(I) metallophilic interactions, whereas 4a exhibits a hexanuclear cluster structure wherein two monomer-of-trimer units are linked by a genuine d10–d10 polar-covalent bond with ligand-unassisted Cu(I)–Au(I) distances of 2.8750(8) Å each—the shortest such an intermolecular distance ever reported between any two d10 centers so as to deem it a “metal–metal bond” vis-à-vis “metallophilic interaction.” Density-functional calculations estimate 35–43 kcal/mol binding energy, akin to typical M–M single-bond energies. Congruently, FTIR spectra of 4a show multiple far-IR bands within 65–200 cm−1, assignable to vCu-Au as validated by both the Harvey–Gray method of crystallographic-distance-to-force-constant correlation and dispersive density functional theory computations. Notably, the heterobimetallic complexes herein exhibit photophysical properties that are favorable to those for their homometallic congeners, due to threefold-to-twofold symmetry reduction, resulting in cuprophilic

  4. La violence sexuelle envers les enfants est-elle en baisse au Canada? Résultats d’enquêtes rétrospectives représentatives à l’échelle nationale

    Directory of Open Access Journals (Sweden)

    M. Shields

    2016-01-01

    Full Text Available Introduction : Selon de nombreuses sources de données, la violence sexuelle envers les enfants (VSE est en baisse aux États-Unis depuis le début des années 1990. Il semble par ailleurs qu’elle ait connu une hausse après la Seconde Guerre mondiale. Cette étude a pour but de faire l’examen des estimations de prévalence des cas de violence sexuelle durant l’enfance (VSdE signalés rétrospectivement dans le cadre de deux enquêtes nationales représentatives menées auprès de la population canadienne. Méthodologie : Les données proviennent de 13 931 répondants de 18 à 76 ans interrogés dans le cadre de l’enquête GENACIS (Gender, Alcohol and Culture: An International Study – Canada de 2004-2005 et de 22 169 résidents âgés de 18 ans et plus ayant participé à l’Enquête sur la santé dans les collectivités canadiennes – Santé mentale (ESCC – Santé mentale de 2012. Nous présentons des comparaisons de la prévalence de la VSdE par sexe et par groupe d’âge à la fois entre ces deux enquêtes et au sein de chacune. Résultats : Les résultats des deux enquêtes indiquent une baisse de la VSE depuis 1993, qui va de pair avec la baisse observée aux États-Unis. Il ressort également des résultats que le risque de VSE était plus élevé entre 1946 et 1992 qu’avant 1946. Les données sont plus solides pour les femmes. Conclusion : Constater une baisse de la VSE au Canada depuis le début des années 1990 est encourageant, étant donné les effets débilitants à long terme qui sont associés à la VSE. Une surveillance continue est essentielle. Ces effets négatifs à long terme sont la preuve de l’importance de poursuivre sur cette lancée, pour passer d’un risque faible à un risque nul.

  5. Pesticide exposure and lymphohaematopoietic cancers: a case-control study in an agricultural region (Larissa, Thessaly, Greece).

    Science.gov (United States)

    Kokouva, Maria; Bitsolas, Nikolaos; Hadjigeorgiou, Georgios M; Rachiotis, George; Papadoulis, Nikolaos; Hadjichristodoulou, Christos

    2011-01-04

    The causality of lymphohaematopoietic cancers (LHC) is multifactorial and studies investigating the association between chemical exposure and LHC have produced variable results. The aim of this study was to investigate the relationships between exposure to pesticides and LHC in an agricultural region of Greece. A structured questionnaire was employed in a hospital-based case control study to gather information on demographics, occupation, exposure to pesticides, agricultural practices, family and medical history and smoking. To control for confounders, backward conditional and multinomial logistic regression analyses were used. To assess the dose-response relationship between exposure and disease, the chi-square test for trend was used. Three hundred and fifty-four (354) histologically confirmed LHC cases diagnosed from 2004 to 2006 and 455 sex- and age-matched controls were included in the study. Pesticide exposure was associated with total LHC cases (OR 1.46, 95% CI 1.05-2.04), myelodysplastic syndrome (MDS) (OR 1.87, 95% CI 1.00-3.51) and leukaemia (OR 2.14, 95% CI 1.09-4.20). A dose-response pattern was observed for total LHC cases (P = 0.004), MDS (P = 0.024) and leukaemia (P = 0.002). Pesticide exposure was independently associated with total LHC cases (OR 1.41, 95% CI 1.00 - 2.00) and leukaemia (OR 2.05, 95% CI 1.02-4.12) after controlling for age, smoking and family history (cancers, LHC and immunological disorders). Smoking during application of pesticides was strongly associated with total LHC cases (OR 3.29, 95% CI 1.81-5.98), MDS (OR 3.67, 95% CI 1.18-12.11), leukaemia (OR 10.15, 95% CI 2.15-65.69) and lymphoma (OR 2.72, 95% CI 1.02-8.00). This association was even stronger for total LHC cases (OR 18.18, 95% CI 2.38-381.17) when eating simultaneously with pesticide application. Lymphohaematopoietic cancers were associated with pesticide exposure after controlling for confounders. Smoking and eating during pesticide application were identified as

  6. Local structure of disordered Au-Cu and Au-Ag alloys

    International Nuclear Information System (INIS)

    Frenkel, A. I.; Machavariani, V. Sh.; Rubshtein, A.; Rosenberg, Yu.; Voronel, A.; Stern, E. A.

    2000-01-01

    X-ray-absorption fine structure (XAFS) and x-ray-diffraction (XRD) measurements of disordered alloys Au x Cu 1-x and Au 0.5 Ag 0.5 prepared by melt spinning were performed. In the Au 0.5 Ag 0.5 alloy, no significant local deviations of the atoms from the average fcc lattice were detected while in Au x Cu 1-x alloys, significant deviations of atoms from the average fcc lattice were found. Mean-square vibrations of the Cu-Cu distances revealed by the XAFS in Au x Cu 1-x alloys indicate the weakening of contact between Cu atoms in the dilute limit. Our computer simulation for Au x Cu 1-x clusters of 10 5 atoms reproduces the main features of both the XAFS and XRD data

  7. Faire du business au bas de la pyramide : la réalité des marches émergents

    Directory of Open Access Journals (Sweden)

    Reuben Abraham

    2012-01-01

    Full Text Available Le rôle du business a été traditionnellement ignoré dans les débats internationaux portant sur le développement économique et la lutte contre la pauvreté. Toutefois, le succès mondial récent du secteur de la téléphonie mobile et son essor rapide sur les marchés émergents au cours des deux dernières décennies ont imposé une remise en question. Au lieu de stratégies de développement descendantes, orientées sur l’aide, les débats portent à présent davantage sur la fourniture de biens et de services rentables à la base de la pyramide économique (BOP, comme le font les entreprises de téléphonie mobile. Des équipes de recherche du CEMS (Centre for Emerging Markets Solutions  ont découvert que, bien qu’il soit possible de desservir de façon rentable les marchés BOP, cela exige de s’écarter des stratégies préconisées dans les publications ordinaires sur la BOP. Cette approche oblige notamment à aborder des questions liées au climat macroéconomique et commercial du pays, aux erreurs d’appréciation du risque, à l’esprit d’entreprise. Elle implique également une réorientation, afin de s'éloigner des multinationales et de se rapprocher du secteur des petites entreprises, avec les coûts de transaction qui le minent. Ce document examine également quelques modèles d’entreprise durables qui ont fonctionné sur ces marchés et analyse quelques secteurs que les capitaux commerciaux trouveront extrêmement intéressants et dignes d’investissements. Enfin, nous étudierons comment structurer et exploiter les énormes opportunités commerciales générées par le traitement du manque d'organisation des marchés BOP, à l’aide d’une combinaison de modèles d’entreprise innovants (en particulier autour de structures à coût réduit, de recherche, d’esprit d’entreprise et de capitaux patients.

  8. Polymorphisms of ST2-IL18R1-IL18RAP gene cluster: a new risk for autoimmune thyroid diseases.

    Science.gov (United States)

    Wang, X; Zhu, Y F; Li, D M; Qin, Q; Wang, Q; Muhali, F S; Jiang, W J; Zhang, J A

    2016-02-01

    Interleukin 33 (IL33) / ST2 pathway and ST2-interlukin18 receptor1-interlukin18 receptor accessory protein (ST2-IL18R1-IL18RAP) gene cluster have been involved in many autoimmune diseases but few report in autoimmune thyroid diseases (AITD). In this study, we investigated whether polymorphisms of IL33, ST2, IL18R1, and IL18RAP are associated with Graves' disease (GD) and Hashimoto's thyroiditis (HT), two major forms of AITD, among a Chinese population. A total of 11 SNPs were explored in a case-control study including 417 patients with GD, 250 HT patients and 301 controls, including rs1929992, rs10975519, rs10208293, rs6543116, rs1041973, rs3732127, rs11465597, rs1035130, rs2293225, rs1035127, rs917997 of IL 33, ST2-IL18R1-IL18RAP gene cluster. Genotyping of these SNPs was performed using matrix-assisted laser desorption / ionization-time-of-flight mass spectrometer (MALDI-TOF-MS) platform from Sequenom. The frequencies of allele A and AA+AG genotype of rs6543116 (ST2) in HT patients were significantly increased compared with those of the controls (P = 0.029/0.021, OR = 1.31/1.62). And in another SNP rs917997, AA+AG genotype presented an increased frequency in HT subjects compared with controls (P = 0.046, OR = 1.53). Furthermore, the haplotype GAGCCCG from ST2-IL18R1-IL18RAP gene cluster (rs6543116, rs1041973, rs1035130, rs3732127, rs1035127, rs2293225, rs917997) was associated with increased susceptibility to GD with an OR of 2.03 (P = 0.022, 95% CI = 1.07-3.86). Some SNPs of ST2-IL18R1-IL18RAP gene cluster might increase the risk of susceptibility of HT and GD in Chinese Han population. © 2015 John Wiley & Sons Ltd.

  9. Reduction of substituted benzonitrile pesticides

    Czech Academy of Sciences Publication Activity Database

    Sokolová, Romana; Hromadová, Magdaléna; Fiedler, Jan; Pospíšil, Lubomír; Giannarelli, S.; Valášek, Michal

    2008-01-01

    Roč. 622, č. 2 (2008), s. 211-218 ISSN 1572-6657 R&D Projects: GA AV ČR IAA400400505; GA MŠk OC 140; GA MŠk LC510 Institutional research plan: CEZ:AV0Z40400503; CEZ:AV0Z40550506 Keywords : benzonitrile pesticides * polarography * voltammetry Subject RIV: CG - Electrochemistry Impact factor: 2.484, year: 2008

  10. The effects of carbamate pesticide on fish in freshwater ecosystems ...

    African Journals Online (AJOL)

    The effects of carbamate pesticide on fish in freshwater ecosystems: A review. ... organisms associated with uncontrolled use of pesticides in agriculture and other ... 85R and used in controlling soil insects and many insect pests of cash crops.

  11. Compatibilidad in vitro de Isaria fumosorosea (Wize Brown y Smith (Hypocreales: Clavicipitaceae con plaguicidas comerciales

    Directory of Open Access Journals (Sweden)

    Érika Paola Grijalba Bernal

    2014-01-01

    Full Text Available Los agricultores colombianos utilizan productos químicos con categorías toxicológicas I, II y III para el control de insectos como la mosca blanca Bemisia tabaci (Gennadius, 1889 (Hemiptera: Aleyrodidae; pero su uso indiscriminado genera un riesgo para la salud y el medio ambiente. El control microbiológico con hongos entomopatógenos surge como alternativa de control ambientalmente sostenible. No obstante, su empleo exitoso dentro de una estrategia de manejo integrado de plagas (MIP depende, en gran parte, del efecto de los productos químicos sobre el bioplaguicida. El objetivo del presente trabajo fue determinar la compatibilidad in vitro de un bioplaguicida con base en el hongo Isaria fumosorosea formulado como polvo mojable con cuatro fungicidas y cinco insecticidas comerciales. Para esto, se evaluó el efecto de tres concentraciones de los productos químicos: FR = dosis recomendada en campo, 0.5 x FR y 0.25 x FR sobre la germinación de los conidios y el número de unidades formadoras de colonia UFC/g de I. fumosorosea. Los cuatro fungicidas (Benlate, Carboxin Captan, Metalaxil-Mancozeb y Mancozeb en las tres dosis evaluadas fueron incompatibles con el bioplaguicida, mientras que el insecticida Thiametoxam fue compatible cuando se utilizó la dosis de 0.25 x FR.

  12. Generic f(R) theories and classicality of their scalarons

    Energy Technology Data Exchange (ETDEWEB)

    Gannouji, Radouane [Department of Physics, Faculty of Science, Tokyo University of Science, 1-3, Kagurazaka, Shinjuku-ku, Tokyo 162-8601 (Japan); Sami, M., E-mail: samijamia@gmail.com [Kobayashi-Maskawa Institute for the Origin of Particles and the Universe, Nagoya University, Nagoya 464-8602 (Japan); Thongkool, I. [Harish-Chandra Research Institute, Chhatnag Road, Jhusi, Allahabad-211019 (India)

    2012-09-19

    We study quantum stability bound on the mass of scalaron in generic theories of f(R) gravity. We show that in these scenarios, the scalaron mass increases faster with local density of the environment than one-loop quantum correction to it thereby leading to violation of quantum bound on the chameleon mass. The introduction of quadratic curvature corrections in the action are shown to stabilize the model.

  13. 78 FR 40017 - Ethalfluralin; Pesticide Tolerances

    Science.gov (United States)

    2013-07-03

    ... (NAICS code 112). Food manufacturing (NAICS code 311). Pesticide manufacturing (NAICS code 32532). B. How... system. Additionally, ethalfluralin does not belong to a class of chemicals (e.g., the organotins, heavy... Alimentarius is a joint United Nations Food and Agriculture Organization/World Health Organization food...

  14. 75 FR 17566 - Flutolanil; Pesticide Tolerances

    Science.gov (United States)

    2010-04-07

    ... ppm, and the greater tolerance value is needed to accommodate indirect residues from soybean..., and soybean hay at 2.5 ppm are being revoked since the same tolerance values are being established...; Pesticide Tolerances AGENCY: Environmental Protection Agency (EPA). ACTION: Final rule. SUMMARY: This...

  15. 77 FR 73951 - Pyriproxyfen; Pesticide Tolerances

    Science.gov (United States)

    2012-12-12

    ... and was negative in the dermal sensitization study in guinea pigs. Based on repeated dose studies in... determine whether this document applies to them. Potentially affected entities may include: Crop production (NAICS code 111). Animal production (NAICS code 112). Food manufacturing (NAICS code 311). Pesticide...

  16. Household pesticide usage in the United States.

    Science.gov (United States)

    Savage, E P; Keefe, T J; Wheeler, H W; Mounce, L; Helwic, L; Applehans, F; Goes, E; Goes, T; Mihlan, G; Rench, J; Taylor, D K

    1981-01-01

    A total of 10,000 U.S. households in 25 standard metropolitan statistical areas and 25 counties were included in the United States. More than 8,200 households granted an interview. Nine of every ten households in the United States used some types of pesticide in their house, garden, or yard. Households in the southeastern United States used the most pesticides. Although more than 500 different pesticide formulations were used by the sampled households, 15 pesticides accounted for 65.5% of all pesticides reported in this study. Thirteen of these 15 pesticides were insecticides, one was a herbicide, and one was a rodenticide.

  17. Radio observations reveal a smooth circumstellar environment around the extraordinary type Ib supernova 2012au

    Energy Technology Data Exchange (ETDEWEB)

    Kamble, Atish; Soderberg, Alicia M.; Margutti, Raffaella; Milisavljevic, Dan; Chakraborti, Sayan; Dittmann, Jason; Drout, Maria; Sanders, Nathan [Harvard-Smithsonian Center for Astrophysics, 60 Garden Street, Cambridge, MA 02138 (United States); Chomiuk, Laura [Department of Physics and Astronomy, Michigan State University, East Lansing, MI 48824 (United States); Medvedev, Mikhail [The Department of Physics and Astronomy, University of Kansas, Lawrence, KS 66045 (United States); Chevalier, Roger [Department of Astronomy, University of Virginia, P.O. Box 400325, Charlottesville, VA 22904-4325 (United States); Chugai, Nikolai [Institute of Astronomy, Russian Academy of Sciences, Pyatnitskaya 48, 109017 Moscow (Russian Federation); Fransson, Claes [Department of Astronomy, The Oskar Klein Centre, Stockholm University, AlbaNova University Centre, SE-106 91 Stockholm (Sweden); Nakar, Ehud, E-mail: atish.vyas@gmail.com [Raymond and Beverly Sackler School of Physics and Astronomy, Tel Aviv University, Tel Aviv 69978 (Israel)

    2014-12-10

    We present extensive radio and X-ray observations of SN 2012au, an energetic, radio-luminous supernova of Type Ib that exhibits multi-wavelength properties bridging subsets of hydrogen-poor superluminous supernovae, hypernovae, and normal core-collapse supernovae. The observations closely follow models of synchrotron emission from a shock-heated circumburst medium that has a wind density profile (ρ∝r {sup –2}). We infer a sub-relativistic velocity for the shock wave v ≈ 0.2 c and a radius of r ≈ 1.4 × 10{sup 16}cm at 25 days after the estimated date of explosion. For a wind velocity of 1000 km s{sup –1}, we determine the mass-loss rate of the progenitor to be M-dot =3.6×10{sup −6} M{sub ⊙} yr{sup −1}, consistent with the estimates from X-ray observations. We estimate the total internal energy of the radio-emitting material to be E ≈ 10{sup 47} erg, which is intermediate to SN 1998bw and SN 2002ap. The evolution of the radio light curve of SN 2012au is in agreement with its interaction with a smoothly distributed circumburst medium and the absence of stellar shells ejected from previous outbursts out to r10{sup 17} cm from the supernova site. We conclude that the bright radio emission from SN 2012au was not dissimilar from other core-collapse supernovae despite its extraordinary optical properties, and that the evolution of the SN 2012au progenitor star was relatively quiet, marked with a steady mass loss, during the final years preceding explosion.

  18. 76 FR 63298 - Pesticide Products; Registration Applications

    Science.gov (United States)

    2011-10-12

    ... each contact person is: Biopesticides and Pollution Prevention Division, Office of Pesticide Programs...: October 3, 2011. Keith A Matthews, Director, Biopesticides and Pollution Prevention Division, Office of...

  19. 75 FR 6656 - Pesticide Product; Registration Application

    Science.gov (United States)

    2010-02-10

    ... (703) 305-5805. FOR FURTHER INFORMATION CONTACT: Shanaz Bacchus, Biopesticides and Pollution Prevention... protection, Pesticides and pests. Dated: January 29, 2010. Keith A. Matthews, Acting Director, Biopesticides...

  20. 18 CFR 33.10 - Additional information.

    Science.gov (United States)

    2010-04-01

    ... 18 Conservation of Power and Water Resources 1 2010-04-01 2010-04-01 false Additional information. 33.10 Section 33.10 Conservation of Power and Water Resources FEDERAL ENERGY REGULATORY COMMISSION... § 33.10 Additional information. The Director of the Office of Energy Market Regulation, or his designee...

  1. Envenimation scorpionique compliqué d'un accident vasculaire cérébral ischemique

    Science.gov (United States)

    Bibiche, Youssef; Berdai, Adnan; Labib, Smael; Harandou, Mustapha

    2015-01-01

    Les piqûres de scorpion sont dans un certain nombre de pays, un accident fréquemment rencontré, et un risque grave. Au Maroc, les données épidémiologiques établies par le centre anti-poison (CAPM) montrent que les piqûres scorpioniques se placent en tête de toutes les intoxications relevées par le centre (60%). Les envenimations scorpioniques posent un grand problème de santé publique. L'apparition de signes neurologiques lors d'une envenimation scorpionique témoigne d'une envenimation grave et correspond au stade III de l’échelle de sévérité. Nous rapportons le cas d'une envenimation scorpionique compliqué d'un Accident vasculaire cérébral ischémique (AVCI) chez un enfant. PMID:26175806

  2. 10 CFR 440.18 - Allowable expenditures.

    Science.gov (United States)

    2010-01-01

    ... part for labor, weatherization materials, and related matters for a renewable energy system, shall not... beginning in calendar year 2010 and the $3,000 average for renewable energy systems will be adjusted... 10 Energy 3 2010-01-01 2010-01-01 false Allowable expenditures. 440.18 Section 440.18 Energy...

  3. Organic amendments for risk mitigation of organochlorine pesticide residues in old orchard soils

    Science.gov (United States)

    Centofantia, Tiziana; McConnell, Laura L.; Chaney, Rufus L.; Beyer, W. Nelson; Andradea, Natasha A.; Hapeman, Cathleen J.; Torrents, Alba; Nguyen, Anh; Anderson, Marya O.; Novak, J. M.; Jackson, Dana

    2015-01-01

    Performance of compost and biochar amendments for in situ risk mitigation of aged DDT, DDE and dieldrin residues in an old orchard soil was examined. The change in bioavailability of pesticide residues to Lumbricus terrestris L. relative to the unamended control soil was assessed using 4-L soil microcosms with and without plant cover in a 48-day experiment. The use of aged dairy manure compost and biosolids compost was found to be effective, especially in the planted treatments, at lowering the bioavailability factor (BAF) by 18–39%; however, BAF results for DDT in the unplanted soil treatments were unaffected or increased. The pine chip biochar utilized in this experiment was ineffective at lower the BAF of pesticides in the soil. The US EPA Soil Screening Level approach was used with our measured values. Addition of 10% of the aged dairy manure compost reduced the average hazard quotient values to below 1.0 for DDT + DDE and dieldrin. Results indicate this sustainable approach is appropriate to minimize risks to wildlife in areas of marginal organochlorine pesticide contamination. Application of this remediation approach has potential for use internationally in areas where historical pesticide contamination of soils remains a threat to wildlife populations.

  4. Using Noether symmetries to specify f(R) gravity

    International Nuclear Information System (INIS)

    Paliathanasis, Andronikos

    2013-01-01

    A detailed study of the modified gravity, f(R) models is performed, using the fact that the Noether point symmetries of these models are geometric symmetries of the mini su-perspace of the theory. It is shown that the requirement that the field equations admit Noether point symmetries selects definite models in a self-consistent way. As an application in Cosmology we consider the Friedman -Robertson-Walker spacetime and show that the only cosmological model which is integrable via Noether point symmetries is the (R b − 2Λ) c model, which generalizes the Lambda Cosmology. Furthermore using the corresponding Noether integrals we compute the analytic form of the main cosmological functions

  5. Les coûts du diabète sur 10 ans au Canada : intégration des coûts en soins de santé imputables au diabète à un modèle de prédiction de son incidence

    Directory of Open Access Journals (Sweden)

    Anja Bilandzic

    2017-01-01

    Full Text Available Introduction : Notre objectif était d’estimer les coûts de santé directs liés au traitement du diabète au Canada sur 10 ans, à l’aide de données de sondages nationaux et d’un outil de prévision du risque de diabète, ainsi que les coûts par personne. Méthodologie : Nous avons utilisé le Diabetes Population Risk Tool pour estimer le nombre de nouveaux cas de diabète chez les personnes âgées de 20 ans et plus sur 10 ans (jusqu'en 2022 à l’aide des données de 2011 et de 2012 de l’Enquête sur la santé dans les collectivités canadiennes. Nous avons évalué les coûts liés au diabète à partir d’une étude de cohorte faisant appel à l’appariement par score de propension, en utilisant la base de données sur le diabète de l’Ontario ainsi que d’autres données administratives. Nous avons calculé les coûts totaux en utilisant les coûts associés aux nouveaux cas, en tenant compte du sexe, de l’année du diagnostic et des taux de mortalité annuels dus à la maladie. Résultats : D'après nos calculs, le risque de développer le diabète sur 10 ans s’élevait pour la population canadienne en 2011-2012 à 9,98 %, soit 2,16 millions de nouveaux cas. Les coûts totaux en soins de santé imputables au diabète pendant cette période sont de 15,36 milliards (7,55 milliards pour les femmes et 7,81 milliards pour les hommes. Ce sont les hospitalisations de courte durée qui constituent la majeure partie de ces coûts (43,2 %. Des interventions menées au sein de la population entraînant une perte de poids de 5 % au sein de la population permettraient de réduire les coûts des soins de santé de 2,03 milliards de dollars. Une réduction du risque de 30 % obtenue grâce à des interventions auprès des personnes à plus haut risque de développer le diabète (c.-à-d. les 10 % au sommet du groupe à risque le plus élevé entraînerait des économies de l’ordrede 1,48 million de dollars. Conclusion : D'ici 2022

  6. The comparison of 18C(n; γ)19C and 18C(α; n)21O reaction rates: consequences for the r-process

    International Nuclear Information System (INIS)

    Dan, M.; Singh, G.; Chatterjee, R.; Shubhchintak

    2017-01-01

    Neutron rich light and medium mass nuclei play a major role in determining the reaction flow towards the r-process seed nuclei production. In this text, we calculate the neutron capture rate of 18 C and compare it with that of α-capture by the same nucleus in the temperature range T 9 = 0:1 - 10. This temperature range roughly equals to an energy range of 1 keV to 1 MeV in centre of mass frame, where it is very difficult to perform direct reaction experiments. Further, the theoretical construction of 18 C-n continuum state for the 18 C(n; γ) 19 C direct reaction is a tedious job

  7. Cardiopathies congénitales: aspects épidémiologiques et échocardiographies à propos de 109 cas au centre hospitalier universitaire pédiatrique Charles de Gaulle (CHUP-CDG) de Ouagadougou, Burkina Faso

    Science.gov (United States)

    Kinda, Georges; Millogo, Georges Rosario Christian; Koueta, Fla; Dao, Lassina; Talbousouma, Sollimy; Cissé, Hassane; Djiguimdé, Aristide; Yé, Diarra; Sorgho, Claudine Lougue

    2015-01-01

    Notre travail avait pour objectif d’étudier les aspects épidémiologiques et écho-cardiographiques des cardiopathies congénitales au CHUP-CDG afin d'y faire l’état des lieux. Pour se faire, nous avons mené sur une période de 27 mois d'aout 2009 à mai 2010 et d'octobre 2011 à décembre 2011, une étude rétrospective des comptes rendus d’échocardiographies Doppler des patients admis dans le service d'imagerie médicale. Nous avons utilisé une sonde cardiaque de 5MHz sur appareil Aloka Prosound 4000 Plus. Durant la période d’étude, 380 examens écho-cardiographiques ont été réalisés et ont permis de mettre en évidence 109 cas de cardiopathies congénitales avec 138 entités nosologiques différentes. Les cardiopathies congénitales représentaient 0,98% des 11169 entrées. Les souffles étaient au premier rang des motifs de demande de l’échographie Doppler cardiaque (121 cas sur 380) soit 39,53%. Les CIV étaient au premier plan des cardiopathies congénitales (28,26%), suivies des CIA (23,19%), des sténoses pulmonaires (19,57%), des Tétralogie de Fallot (9,42%). Dans leur forme isolée, les CIA étaient les plus fréquentes avec 21,95% des cas, suivies des CIV avec 20,73%. Sur 138 cas de cardiopathies congénitales (chez 109 enfants), 53 cas ont été observés chez des enfants de sexe féminin et 56 cas chez des enfants de sexe masculin soit un sexe ration de 1,1. La tranche d’âge présentant une fréquence élevée de cardiopathie congénitale est celle de 1mois- 30 mois avec 55% des cas. Les cardiopathies congénitales de l'enfant sont une réalité en Afrique, leurs fréquences dans toutes les séries rapportées sont certainement sous estimées en raison de l'inaccessibilité de l’échocardiographie doppler. PMID:26090039

  8. AZO/Au/AZO tri-layer thin films for the very low resistivity transparent electrode applications

    Energy Technology Data Exchange (ETDEWEB)

    Chu, Chien-Hsun [Department of Materials Science and Engineering, National Cheng Kung University, Tainan 70101, Taiwan (China); Wu, Hung-Wei, E-mail: hwwu@mail.ksu.edu.tw [Department of Computer and Communication, Kun Shan University, Tainan 71003, Taiwan (China); Huang, Jow-Lay [Department of Materials Science and Engineering, National Cheng Kung University, Tainan 70101, Taiwan (China); Department of Chemical and Materials Engineering, National University of Kaohsiung, Kaohsiung 81148, Taiwan (China); Research Center for Energy Technology and Strategy, National Cheng Kung University, Tainan 70101, Taiwan (China)

    2014-08-01

    Highlights: • High-quality Al-doped ZnO (AZO)/Au/AZO transparent conducting oxide films. • AZO films (30 nm) made by RF sputtering; ion sputtering for Au film (5–20 nm). • Effects of Au thickness on optical and electrical properties were analyzed. • The resistivity of 9 × 10{sup −5} Ω cm and the transmittance of 86.2% of the multilayer films were obtained in this study. - Abstract: Aluminum-doped ZnO (AZO)/gold/AZO tri-layer structures with very low resistivity and high transmittance are prepared by simultaneous RF magnetron sputtering (for AZO) and ion sputtering (for Au). The properties of the tri-layer films are investigated at different Au layer thicknesses (5–20 nm). The effects of Au layer thickness and the role of Au on the transmission properties of the tri-layer films were investigated. The very low resistivity of 1.01 × 10{sup −5} Ω cm, mobility of 27.665 cm{sup 2} V{sup −1} s{sup −1}, and carrier concentration of 4.563 × 10{sup 22} cm{sup −3} were obtained at an Au layer thickness of 20 nm. The peak transmittance of 86.18% at 650-nm wavelength was obtained at an Au layer thickness of 8 nm. These results show the films to be a good candidate for high-quality electrode scheme in various display applications.

  9. 77 FR 59114 - Cyazofamid; Pesticide Tolerances

    Science.gov (United States)

    2012-09-26

    ..., sod farms, seed farms, college and professional sports fields, residential and commercial lawns, and.../pesticides/trac/science/trac6a05.pdf . 4. Cumulative effects from substances with a common mechanism of... Chemistry Branch, Environmental Science Center, 701 Mapes Rd., Ft. Meade, MD 20755-5350; telephone number...

  10. 77 FR 73940 - Flubendiamide; Pesticide Tolerances

    Science.gov (United States)

    2012-12-12

    ... irritant and it is not a skin sensitizer under the conditions of the guinea pig maximization test. In the... determine whether this document applies to them. Potentially affected entities may include: Crop production (NAICS code 111). Animal production (NAICS code 112). Food manufacturing (NAICS code 311). Pesticide...

  11. Laboratory bioassays to estimate the lethal and sublethal effects of various insecticides and fungicides on Deraeocoris brevis (Hemiptera: Miridae).

    Science.gov (United States)

    Amarasekare, K G; Shearer, P W

    2013-04-01

    This laboratory bioassay focused on lethal and sublethal effects of five insecticides (chlorantraniliprole, cyantraniliprole, spinetoram, novaluron, and lambda-cyhalothrin) and two fungicide treatments (sulfur and a mixture of copper hydroxide and mancozeb) on the predatory mired bug, Deraeocoris brevis (Uhler) (Hemiptera: Miridae) using second instars and adult males and females. Formulated pesticides were tested using concentrations that were equivalent to the high label rate (1x) (high rate) and 1/10th of that amount (0.1x) (low rate) dissolved in 378.5 liters of water. Lambda-cyhalothrin was highly toxic to D. brevis nymphs and adults at both rates, whereas both rates of novaluron were highly toxic to nymphs. Cyantraniliprole, chlorantraniliprole, and novaluron were less toxic to adults, and chlorantraniliprole and spinetoram were less toxic to nymphs. Both rates of spinetoram caused significant mortality to adults. Fecundity of adult females was affected negatively by the high rates of either novaluron or spinetoram, whereas the fertility was affected only by the high rate of novaluron. The high rate of spinetoram reduced survival of nymphs. Adults treated with spinetoram had reduced longevity. Cyantraniliprole caused some mortality to nymphs and affected their survival. Both rates of sulfur were toxic to nymphs and affected emergence to adults. The mixture of copper hydroxide and mancozeb was less toxic to D. brevis. Neither adult longevity nor sex ratio was affected by the fungicides. The r values for D. brecis treated with lambda-cyhalothrin, novaluron, spinetoram, and sulfur were low, indicating that these products may have negative impact on population growth.

  12. [Rapid screening and confirmation of 205 pesticide residues in rice by QuEChERS and liquid chromatography-mass spectrometry].

    Science.gov (United States)

    Chen, Xi; Cheng, Lei; Qu, Shichao; Huang, Daliang; Liu, Jiacheng; Cui, Han; Jia, Yanbo; Ji, Mingshan

    2015-10-01

    A method for rapid screening and confirmation of 205 pesticide residues in rice was developed by combining QuEChERS and high performance liquid chromatography-triple quadrupole-linear ion trap mass spectrometry (LC-Q-TRAP/MS). The rice samples were extracted with acetonitrile, and then cleaned up with primary secondary amine (PSA), anhydrous magnesium sulfate (MgSO4) and C18 adsorbent. Finally, the samples were detected by LC-Q-TRAP/MS in multiple reaction monitoring with information-dependent acquisition of enhanced product ion (MRM-IDA-EPI) mode followed with database searching. A total of 205 pesticide residues were confirmed by retention times, ion pairs and the database searching using EPI library, and quantified by external standard method. All the pesticides showed good linearities with linear correlation coefficients all above 0.995. The limits of quantification (LOQs) for the 205 pesticides were 0.5-10.0 μg/kg. The average recoveries of the 205 pesticides ranged from 62.4% to 127.1% with the relative standard deviations (RSDs) of 1.0% - 20.0% at spiked levels of 10 μg/kg and 50 μg/kg, and only 20 min were needed for the analysis of an actual rice sample. In brief, the method is fast, accurate and highly sensitive, and is suitable for the screening and confirmation of pesticide residues in rice.

  13. Composite particle production in relativistic Au+Au collisions at AGS: First results from the E866 forward spectrometer at sign 2, 4, and 10.8 A·GeV

    International Nuclear Information System (INIS)

    Ashktorab, K.

    1996-01-01

    Particle spectra were measured for Au + Au collisions at 2, 4, and 10. 8 A·GeV using the E866 spectrometers. Recent results on proton emission and composite particle production form the E866 forward spectrometer data taken in 1994 together with the first results from the 1995/6 AGS running period are presented. Preliminary results indicate a decrease in the coalescence scaling coefficient with increasing projectile energy and centrality

  14. Prenatal pesticide exposure and PON1 genotype associated with adolescent body fat distribution evaluated by dual X-ray absorptiometry (DXA)

    DEFF Research Database (Denmark)

    Tinggaard, Jeanette; Wohlfahrt-Veje, C.; Husby, S

    2016-01-01

    ) at age 10-15. Prenatal pesticide exposure was associated with increased total, android, and gynoid fat% (DXA) at age 10-15 years after adjustment for sex, socioeconomic status, and puberty (all β = 0.5 standard deviation score (SDS) p ... (total fat: β = 0.7 SDS, android-gynoid ratio: β = 0.1, both p ... circumference were found. Prenatal pesticide exposure was associated with higher adolescent body fat content, including android fat deposition, independent of puberty. Girls appeared more susceptible than boys. Furthermore, the association depended on maternal and child PON1 Q192R genotype....

  15. Ultra-relativistic Au+Au and d+Au collisions:

    Science.gov (United States)

    Back, B. B.; Baker, M. D.; Ballintijn, M.; Barton, D. S.; Betts, R. R.; Bickley, A. A.; Bindel, R.; Budzanowski, A.; Busza, W.; Carroll, A.; Chai, Z.; Decowski, M. P.; García, E.; Gburek, T.; George, N.; Gulbrandsen, K.; Gushue, S.; Halliwell, C.; Hamblen, J.; Hauer, M.; Heintzelman, G. A.; Henderson, C.; Hofman, D. J.; Hollis, R. S.; Hołyński, R.; Holzman, B.; Iordanova, A.; Johnson, E.; Kane, J. L.; Katzy, J.; Khan, N.; Kucewicz, W.; Kulinich, P.; Kuo, C. M.; Lin, W. T.; Manly, S.; McLeod, D.; Mignerey, A. C.; Nouicer, R.; Olszewski, A.; Pak, R.; Park, I. C.; Pernegger, H.; Reed, C.; Remsberg, L. P.; Reuter, M.; Roland, C.; Roland, G.; Rosenberg, L.; Sagerer, J.; Sarin, P.; Sawicki, P.; Seals, H.; Sedykh, I.; Skulski, W.; Smith, C. E.; Stankiewicz, M. A.; Steinberg, P.; Stephans, G. S. F.; Sukhanov, A.; Tang, J.-L.; Tonjes, M. B.; Trzupek, A.; Vale, C.; van Nieuwenhuizen, G. J.; Vaurynovich, S. S.; Verdier, R.; Veres, G. I.; Wenger, E.; Wolfs, F. L. H.; Wosiek, B.; Woźniak, K.; Wuosmaa, A. H.; Wysłouch, B.

    In this talk I will review PHOBOS data on charged particle multiplicities, obtained in Au+Au and d+Au collisions at RHIC. The general features of the Au+Au pseudorapidity distributions results will be discussed and compared to those of /line{p}p collisions. The total charged particle multiplicity, scaled by the number of participant pairs, is observed to be about 40% higher in Au+Au collisions than in /line{p}p and d+Au systems, but, surprisingly at the same level of e+e- collisions. Limiting fragmentation scaling is seen to be obeyed in Au+Au collisions.

  16. 19 CFR 10.18 - Valuation of assembled articles.

    Science.gov (United States)

    2010-04-01

    ... 19 Customs Duties 1 2010-04-01 2010-04-01 false Valuation of assembled articles. 10.18 Section 10... THE TREASURY ARTICLES CONDITIONALLY FREE, SUBJECT TO A REDUCED RATE, ETC. General Provisions Articles Assembled Abroad with United States Components § 10.18 Valuation of assembled articles. As in the case of...

  17. [Determination of 250 pesticide residues in vegetables using QuEChERS-ultra performance liquid chromatography-tandem mass spectrometry].

    Science.gov (United States)

    Zhang, Aizhi; Wang, Quanlin; Cao, Lili; Li, Yu; Shen, Hao; Shen, Jian; Zhang, Shufen; Man, Zhengyin

    2016-02-01

    A multiresidue analytical method for the determination of 250 pesticide residues in vegetables was developed by using QuEChERS-ultra performance liquid chromatography-tandem mass spectrometry (UPLC-MS/MS). The target compounds were extracted with acetonitrile containing 1% (v/v) acetic acid, purified by a mixed sorbent of MgSO4, primary secondary amine (PSA), graphitized carbon black (GCB) and C18, separated on a Waters ACQUITY™ UPLC BEH C18 column (100 mm x 2. 1 mm, 1.7 µm) and detected by UPLC-MS/MS. Anhydrous magnesium sulfate was used as a dewatering agent. The effects of the amounts of MgSO4, PSA, GCB and C18 added on the recoveries of 250 pesticides were investigated. The results showed that the purification effect was best when 300 mg MgSO4, 200 mg PSA, 10 mg GCB and 100 mg C18 in 2 mL of the extract were added. For the 250 pesticide residues, the limits of detection (LODs) of the method were from 0. 01 to 50. 00 g/kg. The recoveries obtained ranged from 60. 1% to 120% at three spiked levels in Chinese chives with the relative standard deviations between 3. 5% and 19. 5% using matrix matched external standard method. The results showed that the method is able to meet requirements of the multiresidue detection of the 250 pesticides in vegetable. The method has the advantages of rapidity, simplicity, high sensitivity and better purification effect. It is suitable for the rapid determination of the common pesticides in vegetables, and it provides a strong guarantee for the risk assessments of the quality and safety of vegetables.

  18. Efeito de produtos fitossanitários utilizados na cultura do tomateiro (Lycopersicon esculentum Mill. sobre Trichogramma pretiosum Riley, 1879 nas gerações F1 e F2 em ovos de Anagasta kuehniella (Zeller, 1879 Effect of pesticides used on tomato crop (Lycopersicon esculentum Mill. on Trichogramma pretiosum Riley, 1879 in F1 and F2 generations on Anagasta kuehniella (Zeller, 1879 eggs

    Directory of Open Access Journals (Sweden)

    Geraldo Andrade Carvalho

    2003-04-01

    Full Text Available Duas populações de Trichogramma pretiosum Riley, 1879, provenientes de Alegre, ES = L9 e Venda Nova do Imigrante, ES = L10, foram submetidas aos principais produtos fitossanitários utilizados na cultura do tomateiro, após serem multiplicadas em ovos de Anagasta kuehniella (Zeller. Os ovos desse hospedeiro foram tratados e oferecidos ao parasitismo decorridas 0, 24 e 48 horas após o tratamento, e mantidos em câmaras climáticas a 25 ± 2ºC, UR de 60 ± 10% e fotofase de 14 horas. Os inseticidas deltametrina, abamectin e metamidofós, independentemente da linhagem de T. pretiosum, reduziram a longevidade de fêmeas da geração maternal. Triflumuron, clorfluazuron, benomil, clorotalonil, Bacillus thuringiensis, mancozeb, dimetomorf, tebufenozide, teflubenzuron, acefato, pirimicarbe, iprodiona, metamidofós e ciromazina não afetaram a capacidade de parasitismo de T. pretiosum na geração F1, independentemente da origem da população, e não afetaram a porcentagem de emergência dos indivíduos da geração F2, das duas linhagens.Two Trichogramma pretiosum Riley, 1879 populations from Alegre ES = L9 and Venda Nova do Imigrante, ES = L10 (Brazil were treated with the main pesticides used on tomato crop after reared on Anagasta kuehniella (Zeller eggs. The eggs were treated and submitted to parasitism on 0, 24 and 48 hours and kept in climatic chambers at 25 ± 2 ºC, 60 ± 10% RH and 14 hours photophase. The longevity of T. pretiosum (mother females, independently of strain, was decreased for insecticides deltamethrin, abamectin and methamidophos. No influence was detected in the parasitism capacity in F1 generation of T. pretiosum with the products triflumuron, chlorfluazuron, benomyl, chlorotalonil, Bacillus thuringiensis, mancozeb, dimetomorf, tebufenozide, teflubenzuron, acefate, pirimicarb, iprodione, methamidophos and ciromazine, and these compounds did not effected the emergence in F2 generation of this parasitoid, independently of

  19. A Au82Si18 liquid metal field-ion emitter for the production of Si ions: fundamental properties and mechanisms

    International Nuclear Information System (INIS)

    Bischoff, L.; Mair, G.L.R.; Aidinis, C.J.; Londos, C.A.; Akhmadaliev, C.; Ganetsos, Th.

    2004-01-01

    Focused silicon beams are useful for direct write applications, e.g., lithography on silicon without the undesirable effect of substrate contamination. However, since pure silicon is not amenable to liquid metal ion source (LMIS) manufacture, a suitable alloy containing silicon has to be produced. This paper covers almost all fundamental aspects of a Au 82 Si 18 eutectic, including the most detailed beam mass spectra reported to date of a AuSi source. A finding worthy of note in this investigation, manifested in the behaviour of the ion extraction voltage with temperature, is the abnormal behaviour of the surface tension coefficient of the alloy with temperature. An important deduction from this work, however, concerns the mechanisms responsible for the creation of doubly charged ions: reasons of self-consistency indicate that while Si 2+ is directly field evaporated, Au 2+ must form by the post-ionization of Au + . Finally, two different mechanisms seem to co-exist, as far as the production of cluster ions is concerned. While for cluster ions containing only a few atoms some sort of surface field-ionization mechanism might be responsible for their creation, for larger clusters, a droplet break-up mechanism, possibly by ion capture, seems very likely

  20. miR-10 in development and cancer

    DEFF Research Database (Denmark)

    Lund, Anders Henrik

    2010-01-01

    The microRNA (miRNA) miR-10 family has attracted attention because of its conservation and the position of the miR-10 genes within the Hox clusters of developmental regulators. In several species, miR-10 is coexpressed with a set of Hox genes and has been found to regulate the translation of Hox ...... function to the miRNA repertoire.Cell Death and Differentiation advance online publication, 22 May 2009; doi:10.1038/cdd.2009.58....

  1. Model methodology for estimating pesticide concentration extremes based on sparse monitoring data

    Science.gov (United States)

    Vecchia, Aldo V.

    2018-03-22

    This report describes a new methodology for using sparse (weekly or less frequent observations) and potentially highly censored pesticide monitoring data to simulate daily pesticide concentrations and associated quantities used for acute and chronic exposure assessments, such as the annual maximum daily concentration. The new methodology is based on a statistical model that expresses log-transformed daily pesticide concentration in terms of a seasonal wave, flow-related variability, long-term trend, and serially correlated errors. Methods are described for estimating the model parameters, generating conditional simulations of daily pesticide concentration given sparse (weekly or less frequent) and potentially highly censored observations, and estimating concentration extremes based on the conditional simulations. The model can be applied to datasets with as few as 3 years of record, as few as 30 total observations, and as few as 10 uncensored observations. The model was applied to atrazine, carbaryl, chlorpyrifos, and fipronil data for U.S. Geological Survey pesticide sampling sites with sufficient data for applying the model. A total of 112 sites were analyzed for atrazine, 38 for carbaryl, 34 for chlorpyrifos, and 33 for fipronil. The results are summarized in this report; and, R functions, described in this report and provided in an accompanying model archive, can be used to fit the model parameters and generate conditional simulations of daily concentrations for use in investigations involving pesticide exposure risk and uncertainty.

  2. Effects of three pesticides on superoxide dismutase and glutathione-S-transferase activities and reproduction of Daphnia magna

    Directory of Open Access Journals (Sweden)

    Song Yuzhi

    2017-03-01

    Full Text Available Applying pesticides to crops is one of the causes of water pollution by surface runoff, and chlorpyrifos, trifluralin and chlorothalonil are used respectively as insecticide, herbicide and fungicide for crop plants widely. To explore effects of three pesticides on aquatic organisms, superoxide dismutase (SOD and glutathione S-transferase (GST activities were determined after 24 h and 48 h exposure of D. magna with ages of 6–24 h to several low concentrations of chlorpyrifos (0.36, 0.72, 1.43, 2.86, 5.72 μg∙L−1, trifluralin (0.17, 0.33, 0.66, 1.33, 2.65 mg∙L−1 and chlorothalonil (0.09, 0.18, 0.36, 0.72, 1.43 mg∙L−1 respectively. Main reproductive parameters including first pregnancy time, first brood time, the number of first brood and total fecundity after 21 d exposures at the same concentrations of pesticides as described above were also measured. The results showed that the activities of GST increased in lower concentrations and decreased in higher concentrations after 24 h exposure to three pesticides, respectively. The activities of SOD showed the same changes after 48 h exposure. With the time prolonged, the activities of GST decreased while the activities of SOD increased. After 21 d exposure, the first pregnancy time and first brood time were delayed, while the number of the first brood and total fecundity per female decreased with increasing concentrations. These results corroborated that GST activity was more sensitive to those pesticides than SOD activity, and there was a significant relationship between total fecundity and pesticides-dose(r>0.94, n=6, GST activity after 48 h exposure and total fecundity after 21 d exposure (r>0.92, n=6.

  3. Thick brane in f(R) gravity with Palatini dynamics

    International Nuclear Information System (INIS)

    Bazeia, D.; Losano, L.; Menezes, R.; Olmo, Gonzalo J.; Rubiera-Garcia, D.

    2015-01-01

    This work deals with modified gravity in five-dimensional space-time. We study a thick Palatini f(R) brane, that is, a braneworld scenario described by an anti-de Sitter warped geometry with a single extra dimension of infinite extent, sourced by a real scalar field under the Palatini approach, where the metric and the connection are regarded as independent degrees of freedom. We consider a first-order framework which we use to provide exact solutions for the scalar field and warp factor. We also investigate a perturbative scenario such that the Palatini approach is implemented through a Lagrangian f(R)=R+ϵR n , where the small parameter ϵ controls the deviation from the standard thick brane case. In both cases it is found that the warp factor tends to localize the extra dimension due to the nonlinear corrections

  4. Thick brane in f(R) gravity with Palatini dynamics

    Energy Technology Data Exchange (ETDEWEB)

    Bazeia, D., E-mail: bazeia@fisica.ufpb.br; Losano, L., E-mail: losano@fisica.ufpb.br [Departamento de Física, Universidade Federal da Paraíba, 58051-900, João Pessoa, PB (Brazil); Menezes, R., E-mail: rmenezes@dce.ufpb.br [Departamento de Ciências Exatas, Universidade Federal da Paraíba, 58297-000, Rio Tinto, PB (Brazil); Departamento de Física, Universidade Federal de Campina Grande, 58109-970, Campina Grande, PB (Brazil); Olmo, Gonzalo J., E-mail: gonzalo.olmo@csic.es [Departamento de Física, Universidade Federal da Paraíba, 58051-900, João Pessoa, PB (Brazil); Departamento de Física Teórica, IFIC, Centro Mixto Universidad de Valencia-CSIC, Universidad de Valencia, 46100, Burjassot, Valencia (Spain); Rubiera-Garcia, D., E-mail: drgarcia@fc.ul.pt [Departamento de Física, Universidade Federal da Paraíba, 58051-900, João Pessoa, PB (Brazil); Faculdade de Ciências, Instituto de Astrofísica e Ciências do Espaço, Universidade de Lisboa, Campo Grande, 1749-016, Lisbon (Portugal); Department of Physics, Center for Field Theory and Particle Physics, Fudan University, 220 Handan Road, 200433, Shanghai (China)

    2015-11-30

    This work deals with modified gravity in five-dimensional space-time. We study a thick Palatini f(R) brane, that is, a braneworld scenario described by an anti-de Sitter warped geometry with a single extra dimension of infinite extent, sourced by a real scalar field under the Palatini approach, where the metric and the connection are regarded as independent degrees of freedom. We consider a first-order framework which we use to provide exact solutions for the scalar field and warp factor. We also investigate a perturbative scenario such that the Palatini approach is implemented through a Lagrangian f(R)=R+ϵR{sup n}, where the small parameter ϵ controls the deviation from the standard thick brane case. In both cases it is found that the warp factor tends to localize the extra dimension due to the nonlinear corrections.

  5. Effects of currently used pesticides in the AhR-CALUX assay: comparison between the human TV101L and the rat H4IIE cell line

    DEFF Research Database (Denmark)

    Long, M.; Laier, Peter; Vinggaard, Anne

    2003-01-01

    TV101L hepatoma cell lines. In comparison the results indicated that the rat H4IIE cell line is more sensitive than the human TV101L for detection of TCDD inducing AhR-CALUX activity. The pesticides iprodione, chlorpyrifos and prochloraz showed dose-dependent AhR agonistic effects in both cell lines...

  6. Inhibition of quorum sensing-mediated virulence in Serratia marcescens by Bacillus subtilis R-18.

    Science.gov (United States)

    Devi, Kannan Rama; Srinivasan, Subramaniyan; Ravi, Arumugam Veera

    2018-04-13

    Serratia marcescens is an opportunistic human pathogen causing various nosocomial infections, most importantly urinary tract infections (UTIs). It exhibits increased resistance towards the conventional antibiotics. This study was aimed to evaluate the anti-virulence effect of a rhizosphere soil bacterium Bacillus subtilis strain R-18 against the uropathogen S. marcescens. First, the bacterial cell-free culture supernatant (CFCS) of B. subtilis strain R-18 was evaluated for its quorum sensing inhibitory (QSI) potential against biomarker strain Chromobacterium violaceum and the test pathogen S. marcescens. The B. subtilis R-18 CFCS effectively inhibited the quorum sensing (QS)-mediated violacein pigment production in C. violaceum and prodigiosin pigment production in S. marcescens. Furthermore, B. subtilis R-18 CFCS was successively extracted with different solvent systems. Of these solvents, B. subtilis R-18 petroleum ether (PE) extract showed inhibition in biofilm formation, protease, lipase, and hemolysin productions in S. marcescens. Fourier transform infrared spectroscopic (FT-IR) analysis revealed the alterations in the cellular components of bacterial cell pellets obtained from B. subtilis R-18 PE extract treated and untreated S. marcescens. The differential gene expression study further validated the downregulation of virulence-associated genes. Characterization of the active principle in B. subtilis R-18 PE extract by gas chromatography-mass spectrometry (GC-MS) analysis showed the presence of multiple compounds with therapeutic values, which could possibly reduce the QS-dependent phenotypes in S. marcescens. Copyright © 2018. Published by Elsevier Ltd.

  7. pH-Induced transformation of ligated Au25 to brighter Au23 nanoclusters.

    Science.gov (United States)

    Waszkielewicz, Magdalena; Olesiak-Banska, Joanna; Comby-Zerbino, Clothilde; Bertorelle, Franck; Dagany, Xavier; Bansal, Ashu K; Sajjad, Muhammad T; Samuel, Ifor D W; Sanader, Zeljka; Rozycka, Miroslawa; Wojtas, Magdalena; Matczyszyn, Katarzyna; Bonacic-Koutecky, Vlasta; Antoine, Rodolphe; Ozyhar, Andrzej; Samoc, Marek

    2018-05-01

    Thiolate-protected gold nanoclusters have recently attracted considerable attention due to their size-dependent luminescence characterized by a long lifetime and large Stokes shift. However, the optimization of nanocluster properties such as the luminescence quantum yield is still a challenge. We report here the transformation of Au25Capt18 (Capt labels captopril) nanoclusters occurring at low pH and yielding a product with a much increased luminescence quantum yield which we have identified as Au23Capt17. We applied a simple method of treatment with HCl to accomplish this transformation and we characterized the absorption and emission of the newly created ligated nanoclusters as well as their morphology. Based on DFT calculations we show which Au nanocluster size transformations can lead to highly luminescent species such as Au23Capt17.

  8. 77 FR 66723 - Fluazinam; Pesticide Tolerances

    Science.gov (United States)

    2012-11-07

    ... included changes in clinical chemistry (increased serum alkaline phosphatase and aspartate aminotransferase... white matter of the central nervous system was observed in subchronic and chronic studies in mice and..., including adults, youth (11 to http://www.epa.gov/pesticides/trac/science/trac6a05.pdf . 4. Cumulative...

  9. 77 FR 43524 - Acetamiprid; Pesticide Tolerances

    Science.gov (United States)

    2012-07-25

    ... the oral route of exposure and is minimally toxic via the dermal and inhalation routes of exposure. It... rats); the effects were considered to be adaptive. Other effects observed in the oral studies include... to the presence of any pesticide residues on food. The Agency understands the commenter's concerns...

  10. 10 CFR 436.18 - Measuring cost-effectiveness.

    Science.gov (United States)

    2010-01-01

    ... 10 Energy 3 2010-01-01 2010-01-01 false Measuring cost-effectiveness. 436.18 Section 436.18 Energy... Procedures for Life Cycle Cost Analyses § 436.18 Measuring cost-effectiveness. (a) In accordance with this section, each Federal agency shall measure cost-effectiveness by combining cost data established under...

  11. Propiedades estructurales y magnéticas de nanopartículas de Co2Au10

    OpenAIRE

    García Mayo, Sara

    2017-01-01

    Hemos llevado a cabo una búsqueda del estado fundamental de la nanoaleación Co2Au10, que hemos comprobado que puede ser vista como un dímero de Co recubierto por diez átomos de Au, con vistas a encontrar un bit magnético estable en el límite de la miniaturización, y hemos estudiado sus propiedades estructurales y magnéticas desde una aproximación relativista escalar. Los cálculos se han realizado empleando el código VASP (Vienna Ab initio Simulation Package), que es una impleme...

  12. 12 CFR 725.18 - Creditworthiness.

    Science.gov (United States)

    2010-01-01

    ... UNION ADMINISTRATION CENTRAL LIQUIDITY FACILITY § 725.18 Creditworthiness. (a) Prior to Facility... advances for its liquidity needs. [44 FR 49437, Aug. 23, 1979, as amended at 69 FR 27829, May 17, 2004] ...

  13. 77 FR 49732 - Cyprodinil; Pesticide Tolerances

    Science.gov (United States)

    2012-08-17

    .../puree (1x) and lemon/lime juice (1x) were used to modify the tolerance values. iii. Cancer. Based on the... the tolerance necessitate a higher value. Additionally, Codex has an established MRL on grape at 3 ppm...; Pesticide Tolerances AGENCY: Environmental Protection Agency (EPA). ACTION: Final rule. SUMMARY: This...

  14. La question de la langue dans les milieux des savants grecs au xixe siecle : projets linguistiques et réformes

    Directory of Open Access Journals (Sweden)

    Petros Diatsentos

    2010-06-01

    Full Text Available Thèse en Histoire et Civilisation soutenue le 15 mai 2009 sous la direction de Georges Dertilis Membres du jury : Monsieur Sylvain Auroux, Directeur de recherche au CNRS (Laboratoire d’histoire des théories linguistiques, Rapporteur,Monsieur Georges Drettas, Directeur de recherche au CNRS (Laboratoire de langues et civilisations à tradition orale, Examinateur, Madame Marie - Elisabeth Mitsou, Professeur à l'Université de Munich (Institut für Byzantinistik, Byzantinische Kunstgeschichte und ...

  15. Organochlorine Pesticides in the Ferruginous Pygmy Owl (Glaucidium brasilianum) in Chiapas, Mexico.

    Science.gov (United States)

    Arrona-Rivera, Alicia E; Enríquez, Paula L; García-Feria, Luis M; Orellana, Sergio Alvarado; von Osten, Jaime Rendón

    2016-09-01

    Concentrations of organochlorine pesticides were quantified in samples of feathers (n = 17) and blood (n = 15) of the ferruginous pygmy owl (Glaucidium brasilianum). The individuals were captured near the Protected Natural Area Cerro Sonsonate, Chiapas, Mexico, between February and June 2014. In both tissues, pesticides belonging to seven organochlorine chemical families were detected. However, the organochlorine pesticide concentrations differed between feathers and blood. The highest concentrations of hexachlorocyclohexanes were found in feathers (0.63 ± 0.89 μg/g), whereas the highest concentrations of ΣDrines were found in blood (0.31 ± 0.47 μg/mL). By using the summed concentrations for each of the seven families of pesticides found in feathers, we did not find any significant correlation between the pesticides and pectoral muscle or body weight (p > 0.15). The ΣDDT group was the only pesticide family that showed a positive correlation with owl body weight (r = 0.60, p = 0.05); the concentrations of these pesticides were also high in feather and blood tissues (r = 0.87, p = 0.02). Our results confirm that ferruginous pygmy owls in the study area are exposed to these pesticides.

  16. Fabrication of Au_n_a_n_o_p_a_r_t_i_c_l_e@mSiO_2@Y_2O_3:Eu nanocomposites with enhanced fluorescence

    International Nuclear Information System (INIS)

    Li, Huiqin; Kang, Jianmiao; Yang, Jianhui; Wu, Biao

    2016-01-01

    Herein, Au_n_a_n_o_p_a_r_t_i_c_l_e@mSiO_2@Y_2O_3:Eu nanocomposites are synthesized through layer-by-layer assembly technology. Au_n_a_n_o_p_a_r_t_i_c_l_e@mSiO_2 core–shell nanospheres were prepared at first in the presence of CTAB in aqueous solution system by the modified one-pot method. A chemical precipitation method and a succeeding calcination process were adopted to the growth of Y_2O_3:Eu shells on the surfaces of Au_n_a_n_o_p_a_r_t_i_c_l_e@mSiO_2 core–shell nanospheres. The structure, morphology and composition of the nanocomposites were confirmed by XRD, TEM and UV–vis absorption spectrum. The prepared Au_n_a_n_o_p_a_r_t_i_c_l_e@mSiO_2@Y_2O_3:Eu nanocomposites have showed the emission intensity enhances to 6.23 times at 30 nm thickness of the silica spacer between the core of Au nanoparticle and the shell of Y_2O_3:Eu. According to the observations of fluorescent lifetime and the modeling of local electric field, the metal-enhanced and quenched fluorescence is closely related with the enhancement of excitation and radiative decay rate and the quenching by NRET comes as a result of competition between the distance-dependent mechanisms. This kind of multifunctional inorganic material will be widely used in electronics, biology and medical drug loading, etc. - Highlights: • Fabrication of Au_n_a_n_o_p_a_r_t_i_c_l_e@mSiO_2@Y_2O_3:Eu nanocomposites with core-spacer-shell structure. • The controllable fluorescence is achieved by adjusting the spacer thickness of silica. • The fluorescence enhancement is 6.23-fold at an optimal spacer thickness about 30 nm. • The metal-enhanced fluorescence mechanism is proposed.

  17. Les complications chirurgicales de la transplantation rénale à partir du donneur vivant: expérience du CHU Ibn Sina de Rabat

    Directory of Open Access Journals (Sweden)

    Intissar Haddiya

    2010-09-01

    Full Text Available INTRODUCTION: La transplantation rénale (TR est actuellement considérée comme un traitement de choix de l’insuffisance rénale chronique terminale (IRCT. Ses résultats se sont améliorés au cours des dernières années. Cependant, les complications chirurgicales demeurent graves car elles touchent un rein unique et surviennent sur un terrain fragilisé par l’insuffisance rénale et l’immunosuppression. L’objectif de ce travail est d’évaluer la fréquence des complications chirurgicales lors de l’activité de TR au CHU Ibn Sina de Rabat, et de dégager les facteurs ayant influé l’apparition de ces complications. METHODES: Étude rétrospective des patients transplantés rénaux à partir de donneurs vivants apparentés (DVA de Juin 1999 à Décembre 2008 dans notre centre hospitalo-universitaire. Nous avons recensé les caractéristiques propres au receveur, au prélèvement, au donneur ainsi qu’au greffon. Les complications chirurgicales ont été colligées ainsi que leur prise en charge et évolution. RESULTATS: Soixante sept dossiers ont été analysés avec un suivi moyen de 55 +/- 28 mois. 38 complications chirurgicales ont été recensées : sténose des artères rénales (38,7%, lymphocèle (21%, hématome (12,7%, thrombose vasculaire (7,8%, reflux vésico-urétéral (4,8%, rupture du greffon (3,2%, calcul (1 cas, éventration (1 cas, L’analyse statistique de notre série n’a pas mis en évidence de facteurs de risque significatifs semblant influer sur l’incidence des complications chirurgicales. CONCLUSION: La morbidité liée aux complications chirurgicales de la TR reste élevée nécessitant un diagnostic et un traitement adéquat afin d’éviter les répercussions sur la survie des patients et des greffons.

  18. Three-particle correlations from parton cascades in Au+Au collisions

    International Nuclear Information System (INIS)

    Ma, G.L.; Ma, Y.G.; Zhang, S.; Cai, X.Z.; Chen, J.H.; He, Z.J.; Huang, H.Z.; Long, J.L.; Shen, W.Q.; Shi, X.H.; Zhong, C.; Zuo, J.X.

    2007-01-01

    We present a study of three-particle correlations among a trigger particle and two associated particles in Au+Au collisions at s NN =200 GeV using a multi-phase transport model (AMPT) with both partonic and hadronic interactions. We found that three-particle correlation densities in different angular directions with respect to the triggered particle ('center', 'cone', 'deflected', 'near' and 'near-away') increase with the number of participants. The ratio of 'deflected' to 'cone' density approaches to 1.0 with the increasing of number of participants, which indicates that partonic Mach-like shock waves can be produced by strong parton cascades in central Au+Au collisions

  19. 10 CFR 1008.18 - Accounting for disclosures.

    Science.gov (United States)

    2010-01-01

    ... 10 Energy 4 2010-01-01 2010-01-01 false Accounting for disclosures. 1008.18 Section 1008.18 Energy... Parties § 1008.18 Accounting for disclosures. (a) For each disclosure of information contained in a system... accounting of: (1) The date, nature, and purposes of each disclosure of a record made to any person or to...

  20. etude de la résistance au flétrissement bactérien de lignées inter

    African Journals Online (AJOL)

    Administrator

    4p. Mew, T. W., Vera Cruz, C. M. and Reyes, R. C.. 1992. Interaction of Xanthomonas campestris pv. oryzae and a resistance Rice Cultivar. Phytopathology 72: 786-789. Ouedraogo, S. L. Somda, I. Boro, F. et Seré, Y. 2004 Détection et caractérisation des bactéries phytopathogènes transmises par les semences du riz au ...

  1. Characterization of pesticide exposure in a sample of pregnant women in Ecuador

    Science.gov (United States)

    Handal, Alexis J.; Hund, Lauren; Páez, Maritza; Bear, Samantha; Greenberg, Carolyn; Fenske, Richard A.; Barr, Dana Boyd

    2015-01-01

    Background Few studies have detailed the prenatal pesticide exposure levels of women employed in or residing near large-scale agricultural industries. This study reports pesticide metabolite levels during and shortly after pregnancy in a pilot study of workers in Ecuador. Methods Urine samples were collected for 16 rose workers and 10 non-agricultural workers enrolled into the study in early pregnancy. We measured six nonspecific organophosphate dialkylphosphate (DAP) pesticide metabolites, two alkylenebis-dithiocarbamate pesticide metabolites (ethylene thiourea [ETU] and propylene thiourea [PTU]), 3,5,6-trichloro-2-pyridinol [TCPy], malathion dicarboxylic acid, and two pyrethroid metabolites (2,2-dimethylcyclopropanecarboxylic acid and 3-phenooxybenzoic acid). Results We collected 141 urine samples (mean: 5.4 per woman). We observed high detection frequencies for five DAP metabolites and ETU, PTU, and TCPy. We report elevated levels of ETU in the entire sample (median 4.24 ng/mL, IQR 2.23, 7.18), suggesting other possible non-occupational pathways of exposure. We found no statistical differences in pesticide levels by current employment status, though the highest pesticide levels were among rose workers. We observed within-woman correlation in TCPy and PTU levels, but not in ETU or DAP levels. Conclusions The present study is the first to characterize prenatal pesticide exposure levels among working women in Ecuador. Limitations include a small sample size and use of a convenience sample. Strengths include a longitudinal design and multiple urine samples per woman. Results provide an initial characterization of prenatal pesticide exposure levels and how these levels vary over pregnancy in a community impacted by agricultural industry and will inform further studies in the region. PMID:26311023

  2. Investigating the little rip and other future singularities of the universe, and validity of the second law of thermodynamics in F(R theory

    Directory of Open Access Journals (Sweden)

    M Aghaei Abchouyeh

    2015-01-01

    Full Text Available The future singularities are possible in a universe that is described by F(R theory. In previous studies the occurrence of the singularities in F(R theory have been considered by using a special function for the Hubble parameter and calculating the F(R function for each of the singularities. Using the specified Hubble parameter causes some difficulties in the study of the second law of thermodynamics. In this paper by using the scale factor, the behavior of F(R function near each type of the singularities is considered. We can check the validity of the second law of thermodynamics near the singularities. At first we study the Little Rip and then the other types of singularities are considered. The results show that the second law of thermodynamics is satisfied near the singularity type (I with some special conditions and is violated with some other conditions. it is satisfied near the Little Rip, type (II, (III and (IV singularities

  3. 75 FR 13277 - Notice of Receipt of Several Pesticide Petitions Filed for Residues of Pesticide Chemicals in or...

    Science.gov (United States)

    2010-03-19

    ... pesticide manufacturer. Potentially affected entities may include, but are not limited to: Crop production (NAICS code 111). Animal production (NAICS code 112). Food manufacturing (NAICS code 311). Pesticide... compound, in or on onion, bulb, subgroup 3-07A at 0.2 ppm; onion, green, subgroup 3-07B at 9.0 ppm...

  4. A Distinct Inhibitory Function for miR-18a in Th17 Cell Differentiation.

    Science.gov (United States)

    Montoya, Misty M; Maul, Julia; Singh, Priti B; Pua, Heather H; Dahlström, Frank; Wu, Nanyan; Huang, Xiaozhu; Ansel, K Mark; Baumjohann, Dirk

    2017-07-15

    Th17 cell responses orchestrate immunity against extracellular pathogens but also underlie autoimmune disease pathogenesis. In this study, we uncovered a distinct and critical role for miR-18a in limiting Th17 cell differentiation. miR-18a was the most dynamically upregulated microRNA of the miR-17-92 cluster in activated T cells. miR-18a deficiency enhanced CCR6 + RAR-related orphan receptor (ROR)γt + Th17 cell differentiation in vitro and increased the number of tissue Th17 cells expressing CCR6, RORγt, and IL-17A in airway inflammation models in vivo. Sequence-specific miR-18 inhibitors increased CCR6 and RORγt expression in mouse and human CD4 + T cells, revealing functional conservation. miR-18a directly targeted Smad4 , Hif1a , and Rora , all key transcription factors in the Th17 cell gene-expression program. These findings indicate that activating signals influence the outcome of Th cell differentiation via differential regulation of mature microRNAs within a common cluster. Copyright © 2017 by The American Association of Immunologists, Inc.

  5. Pesticides are Associated with Allergic and Non-Allergic Wheeze among Male Farmers

    Science.gov (United States)

    Hoppin, Jane A.; Umbach, David M.; Long, Stuart; London, Stephanie J.; Henneberger, Paul K.; Blair, Aaron; Alavanja, Michael; Freeman, Laura E. Beane; Sandler, Dale P.

    2016-01-01

    Background: Growing evidence suggests that pesticide use may contribute to respiratory symptoms. Objective: We evaluated the association of currently used pesticides with allergic and non-allergic wheeze among male farmers. Methods: Using the 2005–2010 interview data of the Agricultural Health Study, a prospective study of farmers in North Carolina and Iowa, we evaluated the association between allergic and non-allergic wheeze and self-reported use of 78 specific pesticides, reported by ≥ 1% of the 22,134 men interviewed. We used polytomous regression models adjusted for age, BMI, state, smoking, and current asthma, as well as for days applying pesticides and days driving diesel tractors. We defined allergic wheeze as reporting both wheeze and doctor-diagnosed hay fever (n = 1,310, 6%) and non-allergic wheeze as reporting wheeze but not hay fever (n = 3,939, 18%); men without wheeze were the referent. Results: In models evaluating current use of specific pesticides, 19 pesticides were significantly associated (p pyraclostrobin) had significantly different associations for allergic and non-allergic wheeze. In exposure–response models with up to five exposure categories, we saw evidence of an exposure–response relationship for several pesticides including the commonly used herbicides 2,4-D and glyphosate, the insecticides permethrin and carbaryl, and the rodenticide warfarin. Conclusions: These results for farmers implicate several pesticides that are commonly used in agricultural and residential settings with adverse respiratory effects. Citation: Hoppin JA, Umbach DM, Long S, London SJ, Henneberger PK, Blair A, Alavanja M, Beane Freeman LE, Sandler DP. 2017. Pesticides are associated with allergic and non-allergic wheeze among male farmers. Environ Health Perspect 125:535–543; http://dx.doi.org/10.1289/EHP315 PMID:27384423

  6. Multifamily determination of pesticide residues in soya-based nutraceutical products by GC/MS-MS.

    Science.gov (United States)

    Páleníková, Agneša; Martínez-Domínguez, Gerardo; Arrebola, Francisco Javier; Romero-González, Roberto; Hrouzková, Svetlana; Frenich, Antonia Garrido

    2015-04-15

    An analytical method based on a modified QuEChERS extraction coupled with gas chromatography-tandem mass spectrometry (GC-MS/MS) was evaluated for the determination of 177 pesticides in soya-based nutraceutical products. The QuEChERS method was optimised and different extraction solvents and clean-up approaches were tested, obtaining the most efficient conditions with a mixture of sorbents (PSA, C18, GBC and Zr-Sep(+)). Recoveries were evaluated at 10, 50 and 100 μg/kg and ranged between 70% and 120%. Precision was expressed as relative standard deviation (RSD), and it was evaluated for more than 160 pesticides as intra and inter-day precision, with values always below 20% and 25%, respectively. Limits of detection (LODs) ranged from 0.1 to 10 μg/kg, whereas limits of quantification (LOQs) from 0.5 to 20 μg/kg. The applicability of the method was proved by analysing soya-based nutraceuticals. Two pesticides were found in these samples, malathion and pyriproxyfen, at 11.1 and 1.5 μg/kg respectively. Copyright © 2014 Elsevier Ltd. All rights reserved.

  7. Energy Lossand Flow of Heavy Quarks in Au+Au Collisions at root-s=200GeV

    Energy Technology Data Exchange (ETDEWEB)

    Soltz, R; Klay, J; Enokizono, A; Newby, J; Heffner, M; Hartouni, E

    2007-02-26

    The PHENIX experiment at the Relativistic Heavy Ion Collider (RHIC) has measured electrons with 0.3 < p{sub rmT} < 9 GeV/c at midrapidity (|y| < 0.35) from heavy flavor (charm and bottom) decays in Au+Au collisions at {radical}s{sub NN} = 200 GeV. The nuclear modification factor R{sub AA} relative to p+p collisions shows a strong suppression in central Au+Au collisions, indicating substantial energy loss of heavy quarks in the medium produced at RHIC energies. A large azimuthal anisotropy, v{sub 2}, with respect to the reaction plane is observed for 0.5 < p{sub rmT} < 5 GeV/c indicating non-zero heavy flavor elliptic flow. A simultaneous description of R{sub AA}(p{sub rmT}) and v{sub 2}(p{sub rmT}) constrains the existing models of heavy-quark rescattering in strongly interacting matter and provides information on the transport properties of the produced medium. In particular, a viscosity to entropy density ratio close to the conjectured quantum lower bound, i.e. near a perfect fluid, is suggested.

  8. 76 FR 61587 - Prothioconazole; Pesticide Tolerances

    Science.gov (United States)

    2011-10-05

    ... class of pesticides. Although conazoles act similarly in plants (fungi) by inhibiting ergosterol... barley at 0.2 ppm; oats, rye, and wheat at 0.05 ppm each; in the fodder (dry) of cereal grains at 5 ppm..., including barley (0.35 ppm), wheat (0.07 ppm). Harmonization of the proposed tolerances with the existing...

  9. Stability Studies of a New Design Au/Pt Thermocouple Without a Strain Relieving Coil

    Science.gov (United States)

    Jahan, Ferdouse; Ballico, Mark

    2007-12-01

    The performance of a simple, new design Au/Pt thermocouple developed by NMIA is assessed. This thermocouple is proposed as a more accurate replacement, over the temperature range from 0 to 1,000°C, for the commonly used Type R and S industrial transfer standards, in a robust form familiar to industrial calibration laboratories. Due to the significantly different thermal expansions of the Au and Pt thermoelements, reported designs of the Au/Pt thermocouple incorporate a strain-relieving coil or bridge at the thermocouple junction. As the strain relieving coil is mechanically delicate, these thermocouples are usually mounted in a protective quartz tube assembly, like a standard platinum resistance thermometer (SPRT). Although providing uncertainties at the mK level, they are more delicate than the commonly used Type R and S thermocouples. A new and simple design of the Au/Pt thermocouple was developed in which the differential thermal expansion between Au and Pt is accommodated in the thermocouple leads, facilitated by a special head design. The resulting thermocouple has the appearance and robustness of the traditional Type R and S thermocouples, while retaining stability better than 10 mK up to 961°C. Three thermocouples of this design were calibrated at fixed points and by comparison to SPRTs in a stirred salt bath. In order to assess possible impurity migration, strain effects, and mechanical robustness, sequences of heat treatment up to a total of 500 h together with over 50 thermal cycles from 900°C to ambient were performed. The effect of these treatments on the calibration was assessed, demonstrating the sensors to be robust and stable to better than 10 mK. The effects on the measured inhomogeneity of the thermocouple were assessed using the NMIA thermocouple scanning bath.

  10. Comparative study on cleanup procedures for the determination of organophosphorus pesticides in vegetables

    International Nuclear Information System (INIS)

    Alvin, Chai Lian Kuet; Lau, Seng

    2008-01-01

    A study was carried out to compare the cleanup procedures for the determination of organophosphorus pesticides in vegetables. Eleven organophosphorus pesticides were extracted with acetone and methylene chloride. Extracts were cleanup by solid-phase extraction (SPE) mixed-mode column using quaternary amine and aminopropyl (SAX/ NH 2 ) or octadecyl (C 18 ) sorbents. The pesticides were determined by gas chromatography with flame photometric detector. The recovery results obtained from the SPE SAX/ NH 2 and C 18 cleanups in carrot, cucumber and green mustard samples were in the range of 71.0 % to 115 %. Lower recoveries were obtained for polar pesticides, methamidophos and dimethoate. These results were compared to the method currently used in the laboratory which does not include any cleanup. (author)

  11. The wild flora biodiversity in pesticide free bufferzones along old hedgerows

    DEFF Research Database (Denmark)

    Andresen, Louise C.; Nothlev, J.; Kristensen, K.

    2012-01-01

    The natural field margin ecotone from the field border and into a cropped field hosts a diversity of plant species. In conventional cropped fields, biodiversity suffers from fertilizer and pesticide application. In our study at Danish conventional spring-barley fields, we laid out bufferzones...... with no pesticide application spraying after sowing, with the widths: 24, 12, 6 and 4 m (and control) to the field edge hedgerow. Through one season: plant species number, biodiversity and evenness for each bufferzone at the distances: 18, 9, 5, 2 and 0 m from the hedgerow were significantly affected by distance...... the bufferzone widths provided smaller biodiversity and larger evenness of plants at distances larger than the buffer width: the distance at which diversity (Shannons) was reduced by half the difference between hedge- and field diversity was 1.2, 3.1, 6.7, 10.8 and 10.9 m in bufferwidth treatments of 0, 4, 6, 12...

  12. Semiconducting La2AuP3, the metallic conductor Ce2AuP3, and other rare-earth gold phosphides Ln2AuP3 with two closely related crystal structures

    International Nuclear Information System (INIS)

    Eschen, M.; Kotzyba, G.; Kuennen, B.; Jeitschko, W.

    2001-01-01

    The compounds Ln 2 AuP 3 were synthesized by reaction of the elemental components in evacuated silica tubes. Their crystal structures were determined from single-crystal diffractometer data. The compounds with Ln = La, Ce, and Pr crystallize with an orthorhombic U 2 NiC 3 type structure (Pnma, Z = 4). The structure refinement for Ce 2 AuP 3 resulted in a = 774.14(6) pm, b = 421.11(4) pm, c = 1612.3(1) pm, R = 0.019 for 1410 structure factors and 38 variable parameters. For Pr 2 AuP 3 a residual of R = 0.024 was obtained. Nd 2 AuP 3 crystallizes with a monoclinic distortion of this structure: P2 1 /c, Z = 4, a = 416.14(4) pm, b = 768.87(6) pm, c = 1647.1(2) pm, β = 104.06(1) , R = 0.022 for 1361 F values and 56 variables. The near-neighbor coordinations of the two structures are nearly the same. In both structures the gold and phosphorus atoms form two-dimensionally infinite nets, where the gold atoms are tetrahedrally coordinated by phosphorus atoms with Au-P distances varying between 245.8 and 284.2 pm. Two thirds of the phosphorus atoms form pairs with single-bond distances varying between 217.7 and 218.9 pm. Thus, using oxidation numbers the structures can be rationalized with the formulas (Ln +3 ) 2 [AuP 3 ] -6 and (Ln +3 ) 2 Au +1 (P 2 ) -4 P -3 . Accordingly, La 2 AuP 3 is a diamagnetic semiconductor. Pr 2 AuP 3 is semi-conducting with an antiferromagnetic ground state, showing metamagnetism with a critical field of B c = 0.5(±0.1) T. In contrast, the cerium compound is a metallic conductor, even though its cell volume indicates that the cerium atoms are essentially trivalent, as is also suggested by the ferro- or ferrimagnetic behavior of the compound. (orig.)

  13. 75 FR 16100 - Antimicrobial Pesticide Registration Review Dockets Opened for Review and Comment

    Science.gov (United States)

    2010-03-31

    ... ENVIRONMENTAL PROTECTION AGENCY [EPA-HQ-OPP-2010-0032; FRL-8810-1] Antimicrobial Pesticide.... for the pesticide of interest. For general information contact: Lance Wormell, Antimicrobials Division... have been completed. List of Subjects Environmental protection, Antimicrobials, Pesticides and pests...

  14. Diagnostic tardif d'une hyperoxalurie primitive au stade d'insuffisance rénale chronique terminale avec hypoparathyroïdie sévère

    Science.gov (United States)

    El Ghali, Zineb; Lahcen, Zineb Ait; Fadili, Wafaa; Kaitouni, Abderrahim Idrissi; Hakkou, Mohamed; Hamdaoui, Abderrachid; Laouad, Inass

    2014-01-01

    L'hyperoxalurie primitive est une anomalie métabolique congénitale rare caractérisée par un excès de production avec accumulation d'oxalate secondaire à un déficit enzymatique hépatique. Nous rapportons le cas d'un patient de 18 ans qui avait comme antécédent des lithiases rénales récidivantes depuis l'enfance évoluant vers l'insuffisance rénale chronique terminale, mis en hémodialyse périodique depuis 4 ans avec apparition d'une anémie résistante à l’érythropoïétine pour laquelle il a été multitransfusé et qui était admis pour prise en charge de douleurs osseuses invalidantes d'aggravation progressive associées à un syndrome tumoral fait d'adénopathies périphériques et de splénomégalie avec dyspnée et altération de l’état général. Le bilan réalisé avait objectivé de multiples images lytiques lacunaires et condensantes au niveau des poignets et des mains avec des petits reins calcifiés, une pleurésie avec péricardite de grande abondance drainée, une ascite de moyenne abondance avec splénomégalie homogène, une anémie normochrome normocytaire à 7.2 g/dl avec hyperferritinémie à 1129 μg/l et un syndrome inflammatoire biologique. La calcémie était spontanément normale à 97 mg/l avec hyperphosphorémie à 83 mg/l et hypoparathyroïdie à 74,85 pg/ml. Les PAL étaient à 136 UI/l, l'aluminium sérique à 13μg/l et la Vitamine D native à 20,87ng/ml. Le diagnostic d'hyperoxalurie a été retenu sur les données de la biopsie ostéomédullaire objectivant des dépôts de cristaux d'oxalate de calcium avec fibrose médullaire et réaction macrophagique à corps étranger. L’évolution a été marquée par la survenue de fractures spontanées récidivantes au niveau de l’épaule et des 2 hanches. PMID:25328593

  15. Assessment of herbicides and organochlorine pesticides contamination in agricultural soils using gas chromatography-mass spectrometry.

    Science.gov (United States)

    Wang, Wan-Hong; Wang, Shi-Cheng; Wang, Yan-Hong

    2008-01-01

    A rapid multi-residue method for the simultaneous analysis of 3 herbicides and 8 organochlorine pesticides (OCPs) in agricultural soils has been developed, using ultrasonic solvent extraction coupled with gas chromatography-mass spectrometry (GC-MS). The recoveries ranged from 81% to 117% with a relative standard deviation (R.S.D) lower than 15%. The limits of quantification (LOQs) ranged from 0.03 to 1.06 microg x kg(-1) dry weight for different pesticides studied. The proposed method has been applied to investigate the 11 pesticide residues in agricultural soils collected from Liaoning Province, northeast of China. 3 OCPs and 3 herbicides were identified. Acetochlor, atrazine, butachtor were measured in the relatively high level with values ranging from 0.53 to 203.18 microg x kg(-1), 0.14 to 21.20 microg x kg(-1), pesticides in this study was compared with the date of other countries reported and the corresponding limiting values used in Netherland, USA, Canada, Vietnam and Thailand. Among the herbicide residues, there was a significant relativity between soil utilizing types and their residue concentration. It seems that the monitoring action for soil contamination caused by commonly-used herbicides should be enhanced according to soil utilizing types, especially acetochlor in maize field.

  16. Enhanced magneto-plasmonic effect in Au/Co/Au multilayers caused by exciton–plasmon strong coupling

    Energy Technology Data Exchange (ETDEWEB)

    Hamidi, S.M., E-mail: m_hamidi@sbu.ac.ir; Ghaebi, O.

    2016-09-15

    In this paper, we have investigated magneto optical Kerr rotation using the strong coupling of exciton–plasmon. For this purpose, we have demonstrated strong coupling phenomenon using reflectometry measurements. These measurements revealed the formation of two split polaritonic extrema in reflectometry as a function of wavelength. Then we have shown exciton–plasmon coupling in dispersion diagram which presented an anti-crossing between the polaritonic branches. To assure the readers of strong coupling, we have shown an enhanced magneto-optical Kerr rotation by comparing the reflectometry results of strong coupling of surface Plasmon polariton of Au/Co/Au multilayer and R6G excitons with surface Plasmon polariton magneto-optical kerr effect experimental setup. - Highlights: • The magneto optical Kerr rotation has been investigated by using the strong coupling of exciton–plasmon. • We have shown exciton–plasmon coupling in dispersion diagram which presented an anti-crossing between the polaritonic branches. • Strong coupling of surface plasmon polariton and exciton have been yielded to the enhanced magneto-optical Kerr effect. • Plasmons in Au/Co/Au multilayer and exciton in R6G have been coupled to enhance magneto-optical activity.

  17. Measurements of jet quenching with semi-inclusive hadron+jet distributions in Au+Au collisions at √{sN N}=200 GeV

    Science.gov (United States)

    Adamczyk, L.; Adkins, J. K.; Agakishiev, G.; Aggarwal, M. M.; Ahammed, Z.; Ajitanand, N. N.; Alekseev, I.; Anderson, D. M.; Aoyama, R.; Aparin, A.; Arkhipkin, D.; Aschenauer, E. C.; Ashraf, M. U.; Attri, A.; Averichev, G. S.; Bai, X.; Bairathi, V.; Behera, A.; Bellwied, R.; Bhasin, A.; Bhati, A. K.; Bhattarai, P.; Bielcik, J.; Bielcikova, J.; Bland, L. C.; Bordyuzhin, I. G.; Bouchet, J.; Brandenburg, J. D.; Brandin, A. V.; Brown, D.; Bunzarov, I.; Butterworth, J.; Caines, H.; Calderón de la Barca Sánchez, M.; Campbell, J. M.; Cebra, D.; Chakaberia, I.; Chaloupka, P.; Chang, Z.; Chankova-Bunzarova, N.; Chatterjee, A.; Chattopadhyay, S.; Chen, X.; Chen, J. H.; Chen, X.; Cheng, J.; Cherney, M.; Christie, W.; Contin, G.; Crawford, H. J.; Das, S.; De Silva, L. C.; Debbe, R. R.; Dedovich, T. G.; Deng, J.; Derevschikov, A. A.; Didenko, L.; Dilks, C.; Dong, X.; Drachenberg, J. L.; Draper, J. E.; Dunkelberger, L. E.; Dunlop, J. C.; Efimov, L. G.; Elsey, N.; Engelage, J.; Eppley, G.; Esha, R.; Esumi, S.; Evdokimov, O.; Ewigleben, J.; Eyser, O.; Fatemi, R.; Fazio, S.; Federic, P.; Federicova, P.; Fedorisin, J.; Feng, Z.; Filip, P.; Finch, E.; Fisyak, Y.; Flores, C. E.; Fulek, L.; Gagliardi, C. A.; Garand, D.; Geurts, F.; Gibson, A.; Girard, M.; Grosnick, D.; Gunarathne, D. S.; Guo, Y.; Gupta, A.; Gupta, S.; Guryn, W.; Hamad, A. I.; Hamed, A.; Harlenderova, A.; Harris, J. W.; He, L.; Heppelmann, S.; Heppelmann, S.; Hirsch, A.; Hoffmann, G. W.; Horvat, S.; Huang, T.; Huang, B.; Huang, X.; Huang, H. Z.; Humanic, T. J.; Huo, P.; Igo, G.; Jacobs, P. M.; Jacobs, W. W.; Jentsch, A.; Jia, J.; Jiang, K.; Jowzaee, S.; Judd, E. G.; Kabana, S.; Kalinkin, D.; Kang, K.; Kauder, K.; Ke, H. W.; Keane, D.; Kechechyan, A.; Khan, Z.; Kikoła, D. P.; Kisel, I.; Kisiel, A.; Kochenda, L.; Kocmanek, M.; Kollegger, T.; Kosarzewski, L. K.; Kraishan, A. F.; Kravtsov, P.; Krueger, K.; Kulathunga, N.; Kumar, L.; Kvapil, J.; Kwasizur, J. H.; Lacey, R.; Landgraf, J. M.; Landry, K. D.; Lauret, J.; Lebedev, A.; Lednicky, R.; Lee, J. H.; Li, X.; Li, C.; Li, W.; Li, Y.; Lidrych, J.; Lin, T.; Lisa, M. A.; Liu, H.; Liu, P.; Liu, Y.; Liu, F.; Ljubicic, T.; Llope, W. J.; Lomnitz, M.; Longacre, R. S.; Luo, S.; Luo, X.; Ma, G. L.; Ma, L.; Ma, Y. G.; Ma, R.; Magdy, N.; Majka, R.; Mallick, D.; Margetis, S.; Markert, C.; Matis, H. S.; Meehan, K.; Mei, J. C.; Miller, Z. W.; Minaev, N. G.; Mioduszewski, S.; Mishra, D.; Mizuno, S.; Mohanty, B.; Mondal, M. M.; Morozov, D. A.; Mustafa, M. K.; Nasim, Md.; Nayak, T. K.; Nelson, J. M.; Nie, M.; Nigmatkulov, G.; Niida, T.; Nogach, L. V.; Nonaka, T.; Nurushev, S. B.; Odyniec, G.; Ogawa, A.; Oh, K.; Okorokov, V. A.; Olvitt, D.; Page, B. S.; Pak, R.; Pandit, Y.; Panebratsev, Y.; Pawlik, B.; Pei, H.; Perkins, C.; Pile, P.; Pluta, J.; Poniatowska, K.; Porter, J.; Posik, M.; Poskanzer, A. M.; Pruthi, N. K.; Przybycien, M.; Putschke, J.; Qiu, H.; Quintero, A.; Ramachandran, S.; Ray, R. L.; Reed, R.; Rehbein, M. J.; Ritter, H. G.; Roberts, J. B.; Rogachevskiy, O. V.; Romero, J. L.; Roth, J. D.; Ruan, L.; Rusnak, J.; Rusnakova, O.; Sahoo, N. R.; Sahu, P. K.; Salur, S.; Sandweiss, J.; Saur, M.; Schambach, J.; Schmah, A. M.; Schmidke, W. B.; Schmitz, N.; Schweid, B. R.; Seger, J.; Sergeeva, M.; Seyboth, P.; Shah, N.; Shahaliev, E.; Shanmuganathan, P. V.; Shao, M.; Sharma, A.; Sharma, M. K.; Shen, W. Q.; Shi, Z.; Shi, S. S.; Shou, Q. Y.; Sichtermann, E. P.; Sikora, R.; Simko, M.; Singha, S.; Skoby, M. J.; Smirnov, N.; Smirnov, D.; Solyst, W.; Song, L.; Sorensen, P.; Spinka, H. M.; Srivastava, B.; Stanislaus, T. D. S.; Strikhanov, M.; Stringfellow, B.; Sugiura, T.; Sumbera, M.; Summa, B.; Sun, Y.; Sun, X. M.; Sun, X.; Surrow, B.; Svirida, D. N.; Tang, A. H.; Tang, Z.; Taranenko, A.; Tarnowsky, T.; Tawfik, A.; Thäder, J.; Thomas, J. H.; Timmins, A. R.; Tlusty, D.; Todoroki, T.; Tokarev, M.; Trentalange, S.; Tribble, R. E.; Tribedy, P.; Tripathy, S. K.; Trzeciak, B. A.; Tsai, O. D.; Ullrich, T.; Underwood, D. G.; Upsal, I.; Van Buren, G.; van Nieuwenhuizen, G.; Vasiliev, A. N.; Videbæk, F.; Vokal, S.; Voloshin, S. A.; Vossen, A.; Wang, G.; Wang, Y.; Wang, F.; Wang, Y.; Webb, J. C.; Webb, G.; Wen, L.; Westfall, G. D.; Wieman, H.; Wissink, S. W.; Witt, R.; Wu, Y.; Xiao, Z. G.; Xie, W.; Xie, G.; Xu, J.; Xu, N.; Xu, Q. H.; Xu, Y. F.; Xu, Z.; Yang, Y.; Yang, Q.; Yang, C.; Yang, S.; Ye, Z.; Ye, Z.; Yi, L.; Yip, K.; Yoo, I.-K.; Yu, N.; Zbroszczyk, H.; Zha, W.; Zhang, Z.; Zhang, X. P.; Zhang, J. B.; Zhang, S.; Zhang, J.; Zhang, Y.; Zhang, J.; Zhang, S.; Zhao, J.; Zhong, C.; Zhou, L.; Zhou, C.; Zhu, X.; Zhu, Z.; Zyzak, M.; STAR Collaboration

    2017-08-01

    The STAR Collaboration reports the measurement of semi-inclusive distributions of charged-particle jets recoiling from a high transverse momentum hadron trigger, in central and peripheral Au +Au collisions at √{sNN}=200 GeV. Charged jets are reconstructed with the anti-kT algorithm for jet radii R between 0.2 and 0.5 and with low infrared cutoff of track constituents (pT>0.2 GeV / c ). A novel mixed-event technique is used to correct the large uncorrelated background present in heavy ion collisions. Corrected recoil jet distributions are reported at midrapidity, for charged-jet transverse momentum pT,jet ch<30 GeV / c . Comparison is made to similar measurements for Pb +Pb collisions at √{s }=2.76 TeV, to calculations for p +p collisions at √{s }=200 GeV based on the pythia Monte Carlo generator and on a next-to-leading order perturbative QCD approach, and to theoretical calculations incorporating jet quenching. The recoil jet yield is suppressed in central relative to peripheral collisions, with the magnitude of the suppression corresponding to medium-induced charged energy transport out of the jet cone of 2.8 ±0.2 (stat )±1.5 (sys ) GeV /c , for 10 R =0.5 . No medium-induced change in jet shape is observed for R <0.5 . The azimuthal distribution of low-pT,jet ch recoil jets may be enhanced at large azimuthal angles to the trigger axis, due to scattering off quasiparticles in the hot QCD medium. Measurement of this distribution gives a 90% statistical confidence upper limit to the yield enhancement at large deflection angles in central Au +Au collisions of 50 ±30 (sys )% of the large-angle yield in p +p collisions predicted by pythia.

  18. 78 FR 38328 - Registration Review; Pesticide Dockets Opened for Review and Comment; Announcement of...

    Science.gov (United States)

    2013-06-26

    .... Environmental justice. EPA seeks to achieve environmental justice, the fair treatment and meaningful involvement... high and adverse human health impacts or environmental effects from exposure to the pesticide(s... registrations of pesticides are to be reviewed every 15 years. Under FIFRA, a pesticide product may be...

  19. Marées et touristes au Mont-Saint-Michel

    Directory of Open Access Journals (Sweden)

    Fernand Verger

    2001-09-01

    Full Text Available L’imaginaire collectif fait la plus grande place au phénomène des grandes marées dans la baie du Mont-Saint-Michel, mais la fréquentation touristique n’est que faiblement déterminée par l’occurrence des grandes marées, malgré l’existence d’un public spécifique, relativement peu nombreux, attiré par le spectacle du mascaret.

  20. The influence of farmer perception on pesticide usage for ...

    African Journals Online (AJOL)

    A case study conducted in eastern Uganda revealed that: (a) pesticide usage depended on farmer production goal, (b) change from one pesticide to another depended on ... Ces résults ont fermément montré que les recommendations de la gestion des pestes aux fermiers doivent prendre en considération la perception des ...

  1. Pesticides in the propolis at São Saulo State, Brazil - doi: 10.4025/actascianimsci.v34i4.15859 Pesticides in the propolis at São Saulo State, Brazil - doi: 10.4025/actascianimsci.v34i4.15859

    Directory of Open Access Journals (Sweden)

    Samir Moura Kadri

    2012-10-01

    Full Text Available The increasing demand for propolis has caused a raise in its production. However, an increasingly pesticide-dependent agriculture is a great concern with regard to bees, their produce and environmental contamination. Current analysis evaluates the presence of pesticides (organochlorines, organophosphates, pyrethroids, carbamates, herbicides, fungicides and acaricides in samples of propolis from the state of São Paulo, Brazil. Beekeepers from several localities in the state provided samples of propolis (50, which were collected, stored in non-toxic plastic bags and maintained in a freezer for analyses. Possible pesticide residues were examined by gas chromatography method but no pesticide residues were detected in the examined propolis samples. Propolis analyzed in the state of São Paulo did not show any pesticide contamination. The increasing demand for propolis has caused a raise in its production. However, an increasingly pesticide-dependent agriculture is a great concern with regard to bees, their produce and environmental contamination. Current analysis evaluates the presence of pesticides (organochlorines, organophosphates, pyrethroids, carbamates, herbicides, fungicides and acaricides in samples of propolis from the state of São Paulo, Brazil. Beekeepers from several localities in the state provided samples of propolis (50, which were collected, stored in non-toxic plastic bags and maintained in a freezer for analyses. Possible pesticide residues were examined by gas chromatography method but no pesticide residues were detected in the examined propolis samples. Propolis analyzed in the state of São Paulo did not show any pesticide contamination.

  2. 1025-IJBCS-Article-Gbaguidi A N Magloire

    African Journals Online (AJOL)

    DR GATSING

    Evaluation quantitative des résidus de pyréthrinoïdes, d'aminophosphate et de triazines en ..... Tableau 1 : types et quantité de pesticides utilisés en agriculture au Bénin de 1999 à 2008. Campagnes ..... coagulation-floculation au sulfate.

  3. 77 FR 68771 - Pesticide Program Dialogue Committee; Notice of Public Meeting

    Science.gov (United States)

    2012-11-16

    ... growers; animal rights groups; pest consultants; State, local, and tribal governments; academia; public.... The following sectors are represented on the current PPDC: Environmental/public interest and animal rights groups; farm worker organizations; pesticide industry and trade associations; pesticide user...

  4. 75 FR 74673 - Pesticides; Regulation To Clarify Labeling of Pesticides for Export; Notification to the...

    Science.gov (United States)

    2010-12-01

    ...., Washington DC 20460- 0001; telephone number: (703) 308-9069; e-mail address: au.vera@ [email protected] listed in the index, some information is not publicly available, e.g., Confidential Business Information... number is (703) 305-5805. FOR FURTHER INFORMATION CONTACT: Vera Au, Field & External Affairs Division...

  5. 75 FR 23759 - Pesticide Products; Registration Applications

    Science.gov (United States)

    2010-05-04

    ... classification/Use: Terrestrial food use for brassica leafy vegetables, bulb vegetables, cucurbit vegetables...%. Proposed classification/Use: Terrestrial food use for brassica leafy vegetables, bulb vegetables, cucurbit... potentially affected by this action if you are an agricultural producer, food manufacturer, or pesticide...

  6. Efficacy of Combined Formulations of Fungicides with Different Modes of Action in Controlling Botrytis Gray Mold Disease in Chickpea

    Science.gov (United States)

    Rashid, M. H.; Hossain, M. Ashraf; Kashem, M. A.; Kumar, Shiv; Rafii, M. Y.; Latif, M. A.

    2014-01-01

    Botrytis gray mold (BGM) caused by Botrytis cinerea Pers. Ex. Fr. is an extremely devastating disease of chickpea (Cicer arietinum L.) and has a regional as well as an international perspective. Unfortunately, nonchemical methods for its control are weak and ineffective. In order to identify an effective control measure, six fungicides with different modes of action were evaluated on a BGM susceptible chickpea variety BARIchhola-1 at a high BGM incidence location (Madaripur) in Bangladesh for three years (2008, 2009, and 2010). Among the six fungicides tested, one was protectant [Vondozeb 42SC, a.i. mancozeb (0.2%)], two systemic [Bavistin 50 WP, a.i. carbendazim (0.2%), and Protaf 250EC, propiconazole (0.05%)], and three combination formulations [Acrobat MZ690, dimethomorph 9% + mancozeb 60%, (0.2%); Secure 600 WG, phenomadone + mancozeb (0.2%); and Companion, mancozeb 63% + carbendazim 12% (0.2%)]. The results showed superiority of combination formulations involving both protectant and systemic fungicides over the sole application of either fungicide separately. Among the combination fungicides, Companion was most effective, resulting in the lowest disease severity (3.33 score on 1–9 scale) and the highest increase (38%) of grain yield in chickpea. Therefore, this product could be preferred over the sole application of either solo protectant or systemic fungicides to reduce yield losses and avoid fungicide resistance. PMID:24723819

  7. Efficacy of Combined Formulations of Fungicides with Different Modes of Action in Controlling Botrytis Gray Mold Disease in Chickpea

    Directory of Open Access Journals (Sweden)

    M. H. Rashid

    2014-01-01

    Full Text Available Botrytis gray mold (BGM caused by Botrytis cinerea Pers. Ex. Fr. is an extremely devastating disease of chickpea (Cicer arietinum L. and has a regional as well as an international perspective. Unfortunately, nonchemical methods for its control are weak and ineffective. In order to identify an effective control measure, six fungicides with different modes of action were evaluated on a BGM susceptible chickpea variety BARIchhola-1 at a high BGM incidence location (Madaripur in Bangladesh for three years (2008, 2009, and 2010. Among the six fungicides tested, one was protectant [Vondozeb 42SC, a.i. mancozeb (0.2%], two systemic [Bavistin 50 WP, a.i. carbendazim (0.2%, and Protaf 250EC, propiconazole (0.05%], and three combination formulations [Acrobat MZ690, dimethomorph 9% + mancozeb 60%, (0.2%; Secure 600 WG, phenomadone + mancozeb (0.2%; and Companion, mancozeb 63% + carbendazim 12% (0.2%]. The results showed superiority of combination formulations involving both protectant and systemic fungicides over the sole application of either fungicide separately. Among the combination fungicides, Companion was most effective, resulting in the lowest disease severity (3.33 score on 1–9 scale and the highest increase (38% of grain yield in chickpea. Therefore, this product could be preferred over the sole application of either solo protectant or systemic fungicides to reduce yield losses and avoid fungicide resistance.

  8. MiR-18a regulates the proliferation, migration and invasion of human glioblastoma cell by targeting neogenin

    International Nuclear Information System (INIS)

    Song, Yichen; Wang, Ping; Zhao, Wei; Yao, Yilong; Liu, Xiaobai; Ma, Jun; Xue, Yixue; Liu, Yunhui

    2014-01-01

    MiR-17-92 cluster has recently been reported as an oncogene in some tumors. However, the association of miR-18a, an important member of this cluster, with glioblastoma remains unknown. Therefore, this study aims to investigate the expression of miR-18a in glioblastoma and its role in biological behavior of U87 and U251 human glioblastoma cell lines. Quantitative RT-PCR results showed that miR-18a was highly expressed in glioblastoma tissues and U87 and U251 cell lines compared with that in human brain tissues and primary normal human astrocytes, and the expression levels were increased along with the rising pathological grades of glioblastoma. Neogenin was identified as the target gene of miR-18a by dual-luciferase reporter assays. RT-PCR and western blot results showed that its expression levels were decreased along with the rising pathological grades of glioblastoma. Inhibition of miR-18a expression was established by transfecting exogenous miR-18a inhibitor into U87 and U251 cells, and its effects on the biological behavior of glioblastoma cells were studied using CCK-8 assay, transwell assay and flow cytometry. Inhibition of miR-18a expression in U87 and U251 cells significantly up-regulated neogenin, and dramatically suppressed the abilities of cell proliferation, migration and invasion, induced cell cycle arrest and promoted cellular apoptosis. Collectively, these results suggest that miR-18a may regulate biological behavior of human glioblastoma cells by targeting neogenin, and miR-18a can serve as a potential target in the treatment of glioblastoma. - Highlights: • MiR-18a was highly expressed in glioblastoma tissues and U87 and U251 cell lines. • Neogenin was identified as the target gene of miR-18a. • Neogenin expressions were decreased along with the rising pathological grades of glioblastoma. • Inhibition of miR-18a suppressed biological behavior of glioma cells by up-regulating neogenin

  9. MiR-18a regulates the proliferation, migration and invasion of human glioblastoma cell by targeting neogenin

    Energy Technology Data Exchange (ETDEWEB)

    Song, Yichen, E-mail: jeff200064017@163.com [Department of Neurosurgery, Shengjing Hospital of China Medical University, Shenyang 110004 (China); Wang, Ping, E-mail: pingwang8000@163.com [Department of Neurobiology, College of Basic Medicine, China Medical University, Shenyang 110001 (China); Institute of Pathology and Pathophysiology, China Medical University, Shenyang 110001 (China); Zhao, Wei, E-mail: 15669746@qq.com [Department of Neurobiology, College of Basic Medicine, China Medical University, Shenyang 110001 (China); Institute of Pathology and Pathophysiology, China Medical University, Shenyang 110001 (China); Yao, Yilong, E-mail: yaoyilong_322@163.com [Department of Neurosurgery, Shengjing Hospital of China Medical University, Shenyang 110004 (China); Liu, Xiaobai, E-mail: paganizonda1991@qq.com [The 96th Class, 7-year Program, China Medical University, Shenyang, Liaoning Province 110001 (China); Ma, Jun, E-mail: majun_724@163.com [Department of Neurobiology, College of Basic Medicine, China Medical University, Shenyang 110001 (China); Institute of Pathology and Pathophysiology, China Medical University, Shenyang 110001 (China); Xue, Yixue, E-mail: xueyixue888@163.com [Department of Neurobiology, College of Basic Medicine, China Medical University, Shenyang 110001 (China); Institute of Pathology and Pathophysiology, China Medical University, Shenyang 110001 (China); Liu, Yunhui, E-mail: liuyh@sj-hospital.org [Department of Neurosurgery, Shengjing Hospital of China Medical University, Shenyang 110004 (China)

    2014-05-15

    MiR-17-92 cluster has recently been reported as an oncogene in some tumors. However, the association of miR-18a, an important member of this cluster, with glioblastoma remains unknown. Therefore, this study aims to investigate the expression of miR-18a in glioblastoma and its role in biological behavior of U87 and U251 human glioblastoma cell lines. Quantitative RT-PCR results showed that miR-18a was highly expressed in glioblastoma tissues and U87 and U251 cell lines compared with that in human brain tissues and primary normal human astrocytes, and the expression levels were increased along with the rising pathological grades of glioblastoma. Neogenin was identified as the target gene of miR-18a by dual-luciferase reporter assays. RT-PCR and western blot results showed that its expression levels were decreased along with the rising pathological grades of glioblastoma. Inhibition of miR-18a expression was established by transfecting exogenous miR-18a inhibitor into U87 and U251 cells, and its effects on the biological behavior of glioblastoma cells were studied using CCK-8 assay, transwell assay and flow cytometry. Inhibition of miR-18a expression in U87 and U251 cells significantly up-regulated neogenin, and dramatically suppressed the abilities of cell proliferation, migration and invasion, induced cell cycle arrest and promoted cellular apoptosis. Collectively, these results suggest that miR-18a may regulate biological behavior of human glioblastoma cells by targeting neogenin, and miR-18a can serve as a potential target in the treatment of glioblastoma. - Highlights: • MiR-18a was highly expressed in glioblastoma tissues and U87 and U251 cell lines. • Neogenin was identified as the target gene of miR-18a. • Neogenin expressions were decreased along with the rising pathological grades of glioblastoma. • Inhibition of miR-18a suppressed biological behavior of glioma cells by up-regulating neogenin.

  10. Thin-shell wormholes with charge in F(R) gravity

    Energy Technology Data Exchange (ETDEWEB)

    Eiroa, Ernesto F. [Instituto de Astronomia y Fisica del Espacio (IAFE, CONICET-UBA), Buenos Aires (Argentina); Universidad de Buenos Aires, Departamento de Fisica, Facultad de Ciencias Exactas y Naturales, Buenos Aires (Argentina); Figueroa Aguirre, Griselda [Instituto de Astronomia y Fisica del Espacio (IAFE, CONICET-UBA), Buenos Aires (Argentina)

    2016-03-15

    In this article, we construct a class of constant curvature and spherically symmetric thin-shell Lorentzian wormholes in F(R) theories of gravity and we analyze their stability under perturbations preserving the symmetry. We find that the junction conditions determine the equation of state of the matter at the throat. As a particular case, we consider configurations with mass and charge. We obtain that stable static solutions are possible for suitable values of the parameters of the model. (orig.)

  11. Thin-shell wormholes with charge in F(R) gravity

    International Nuclear Information System (INIS)

    Eiroa, Ernesto F.; Figueroa Aguirre, Griselda

    2016-01-01

    In this article, we construct a class of constant curvature and spherically symmetric thin-shell Lorentzian wormholes in F(R) theories of gravity and we analyze their stability under perturbations preserving the symmetry. We find that the junction conditions determine the equation of state of the matter at the throat. As a particular case, we consider configurations with mass and charge. We obtain that stable static solutions are possible for suitable values of the parameters of the model. (orig.)

  12. Soutien institutionnel au Centre for Population and Environmental ...

    International Development Research Centre (IDRC) Digital Library (Canada)

    Le Centre for Population and Environmental Development (CPED), établi au Nigeria, est un organisme indépendant à but non lucratif qui a été constitué officiellement en 1998. Il se consacre à la recherche-action sur la réduction de la pauvreté et le développement durable au Nigeria en général et dans la région du delta ...

  13. 75 FR 6656 - SFIREG Pesticide Operations and Management Working Committee Meeting

    Science.gov (United States)

    2010-02-10

    ... Evaluation Group (SFIREG), Pesticide Operations and Management (POM) Working Committee will hold a 2-day... ENVIRONMENTAL PROTECTION AGENCY [EPA-HQ-OPP-2010-0001; FRL-8811-3] SFIREG Pesticide Operations and Management Working Committee Meeting AGENCY: Environmental Protection Agency (EPA). ACTION: Notice. SUMMARY...

  14. Intoxication aiguë sévère par les pesticides organophosphorés: à propos de 28 cas

    Directory of Open Access Journals (Sweden)

    Ali Derkaoui

    2011-03-01

    Full Text Available Les pesticides organophosphorés (POP sont des pesticides organiques de synthèse, largement utilisés en agriculture essentiellement comme insecticide, nemacide ou acaricide. Ce sont les produits agricoles, les plus incriminés dans les intoxications dans notre contexte. L’objectif de ce travail était de déterminer les caractéristiques cliniques, paracliniques, et évolutives de cette intoxication en milieu de réanimation. étude rétrospective portant sur les cas admis en réanimation (2003-2010. Les critères d’inclusion étaient d’ordre clinique, para clinique, thérapeutique et évolutif. 28 cas ont été recensés : 19 femmes et 9 hommes, âge moyen = 24,5 plus or minus 11 ans. La tentative de suicide était le principal motif d’intoxication (19cas. Le Glasgow coma score était en moyenne de 11 plus or minus 4. Le syndrome central, était présent chez 78% de nos patients, suivi du syndrome muscarinique 71% et le syndrome nicotinique dans 53% des cas. La prise en charge thérapeutique a consisté à la ventilation mécanique dans 50% des cas, l’usage des drogues vasoactives dans 14% des cas et l’administration d’un traitement antidotique dans 64% des cas. La mortalité globale était de 25%. Les pesticides organophosphorés sont les toxiques agricoles, le plus souvent incriminés dans notre contexte. Les symptômes résultent d’une importante accumulation d’Acétyle-choline (Ach dans l’organisme ; responsable de l’apparition des trois syndromes caractéristiques. Le diagnostic biologique se fait par le dosage de l’activité cholinestérasique dans le plasma. Le traitement associe des mesures symptomatiques qui reposent essentiellement sur la réanimation respiratoire et neurologique au traitement antidotique. L’évolution clinique dans ce type d’intoxication, est généralement favorable sous traitement avec régression des signes en quelques jours. Le décès est essentiellement, le fait d

  15. The combined antiandrogenic effects of five commonly used pesticides

    DEFF Research Database (Denmark)

    Kjærstad, Mia Birkhøj; Nellemann, Christine Lydia; Jarfelt, Kirsten

    2004-01-01

    In this study, mixture effects of five dissimilarly acting pesticides were analyzed for antiandrogenic effects in vitro and in vivo. Deltamethrin, methiocarb, prochloraz, simazine, and tribenuron-methyl are all commonly used for agricultural and horticultural purposes. Concentration-response curves...... for the inhibition of R1881-induced transcriptional activity of the androgen receptor (AR) in vitro of each pesticide alone and in an equimolar mixture were obtained. The IC25 values for deltamethrin, methiocarb, prochloraz, and the mixture were 5.8, 5.8, 3.5, and 7.5 muM, respectively. Simazine and tribenuron...... of the pesticides in vitro. In vivo, each of the five pesticides and a mixture of the pesticides were tested for antiandrogenic effects in castrated testosterone-treated Wistar rats. The mixture induced a significant change of weights of the levator ani/bulbocavernosus muscle and adrenal glands. Changes in gene...

  16. Preharvest Interval Periods and their relation to fruit growth stages and pesticide formulations.

    Science.gov (United States)

    Alister, Claudio; Araya, Manuel; Becerra, Kevin; Saavedra, Jorge; Kogan, Marcelo

    2017-04-15

    The aim of this study was to evaluate the effect of pesticide formulations and fruit growth stages on the Pre-harvest Interval Period (PHI). Results showed that pesticide formulations did not affect the initial deposit and dissipation rate. However, the fruit growth stage at the application time showed a significant effect on the above-mentioned parameters. Fruit diameter increases in one millimeter pesticide dissipation rates were reduced in -0.033mgkg -1 day -1 (R 2 =0.87; p<0.001) for grapes and -0.014mgkg -1 day -1 (R 2 =0.85; p<0.001) for apples. The relation between solar radiation, air humidity and temperature, and pesticide dissipation rates were dependent on fruit type. PHI could change according to the application time, because of the initial amount of pesticide deposit in the fruits and change in the dissipation rates. Because Maximum Residue Level are becoming more restrictive, it is more important to consider the fruit growth stage effects on pesticide when performing dissipation studies to define PHI. Copyright © 2016. Published by Elsevier Ltd.

  17. Multiple stressors and amphibian declines: dual impacts of pesticides and fish on yellow-legged frogs.

    Science.gov (United States)

    Davidson, Carlos; Knapp, Roland A

    2007-03-01

    More than 40% of Earth's 5700+ amphibian species have undergone recent declines. Despite the likely involvement of multiple factors in driving these declines, most studies continue to focus on single stressors. In California (USA), separate studies have implicated either introduced fish or pesticides as causal agents. To date, however, no study has simultaneously evaluated the respective roles of these two potential stressors nor attempted to assess their relative importance, information critical for the development of effective conservation efforts and environmental policies. We examined the role and relative effect of fish and pesticides on the mountain yellow-legged frog (Rana muscosa) using unusually detailed data sets for a large portion of R. muscosa's historic range in California's Sierra Nevada. Habitat characteristics and presence/absence of R. muscosa and fish were quantified at each of 6831 sites during field surveys. Pesticide use upwind of each site was calculated from pesticide application records and predominant wind directions. Using generalized additive models, we found that, after accounting for habitat effects, the probability of R. muscosa presence was significantly reduced by both fish and pesticides, with the landscape-scale effect of pesticides much stronger than that of fish. The degree to which a site was sheltered from the predominant wind (and associated pesticides) was also a significant predictor of R. muscosa presence. Taken together, these results represent the strongest evidence to date that windborne pesticides are contributing to amphibian declines in pristine locations. Our results suggest that amphibian declines may have complex multi-factorial causes, and caution that single-factor studies that demonstrate the importance of one factor should not be used as evidence against the importance of other factors.

  18. Acute Pesticide Poisoning in Children: Hospital Review in Selected Hospitals of Tanzania

    Directory of Open Access Journals (Sweden)

    Elikana Lekei

    2017-01-01

    Full Text Available Background. Acute pesticide poisoning (APP is a serious problem worldwide. Because the burden of childhood APP is unknown in Tanzania, this study describes the distribution, circumstances, and patterns of APP involving children under 18 years in Tanzania. Methodology. A 12-month prospective study was conducted in 10 Tanzanian healthcare facilities in 2006 using a data collection tool for surveillance. Results. Of 53 childhood poisoning cases identified, 56.6% were female. The most common poisoning circumstances were accidents (49.1% and suicide (30.2%. The most vulnerable children were 16-17 years old (30.2%. Suicide was significantly more common in females (PRR females/males = 1.66; 95% CI = 1.03–2.68 and accidental cases were more common in children aged 10 years or younger. Suicide was concentrated in children over 10 years, comprising 53% of cases in this age group. Organophosphates (OPs, zinc phosphide, and endosulfan were common amongst reported poisoning agents. The annual APP incidence rate was 1.61/100,000. Conclusion. APP is common among children in this region of Tanzania. Prevention of suicide in older children should address mental health issues and control access to toxic pesticides. Prevention of accidents in younger children requires safer storage and hygiene measures. Diverse interventions are needed to reduce pesticide poisoning among children in Tanzania.

  19. 75 FR 17571 - Pendimethalin; Pesticide Tolerances

    Science.gov (United States)

    2010-04-07

    ... Enforcement Methodology Adequate enforcement methodology, using liquid chromatography/mass spectrometry... Order Reviews This final rule establishes tolerances under section 408(d) of FFDCA in response to a... actions from review under Executive Order 12866, entitled Regulatory Planning and Review (58 FR 51735...

  20. Organic amendments for risk mitigation of organochlorine pesticide residues in old orchard soils

    International Nuclear Information System (INIS)

    Centofanti, Tiziana; McConnell, Laura L.; Chaney, Rufus L.; Beyer, W. Nelson; Andrade, Natasha A.; Hapeman, Cathleen J.; Torrents, Alba; Nguyen, Anh; Anderson, Marya O.; Novak, Jeffrey M.

    2016-01-01

    Performance of compost and biochar amendments for in situ risk mitigation of aged DDT, DDE and dieldrin residues in an old orchard soil was examined. The change in bioavailability of pesticide residues to Lumbricus terrestris L. relative to the unamended control soil was assessed using 4-L soil microcosms with and without plant cover in a 48-day experiment. The use of aged dairy manure compost and biosolids compost was found to be effective, especially in the planted treatments, at lowering the bioavailability factor (BAF) by 18–39%; however, BAF results for DDT in the unplanted soil treatments were unaffected or increased. The pine chip biochar utilized in this experiment was ineffective at lower the BAF of pesticides in the soil. The US EPA Soil Screening Level approach was used with our measured values. Addition of 10% of the aged dairy manure compost reduced the average hazard quotient values to below 1.0 for DDT + DDE and dieldrin. Results indicate this sustainable approach is appropriate to minimize risks to wildlife in areas of marginal organochlorine pesticide contamination. Application of this remediation approach has potential for use internationally in areas where historical pesticide contamination of soils remains a threat to wildlife populations. - Highlights: • Historical applications of organochlorine pesticides are a risk to local ecosystems. • Low cost and sustainable mitigation measures are needed to reduce risks. • Organic matter rich amendments were added to contaminated soil. • Earthworms microcosms were used to measure bioaccumulation factors. • Aged composts were most effective at mitigating risks to ecosystems. - Incorporation of aged dairy manure and biosolids compost amendments is an effective, low cost approach to mitigate risks to terrestrial wildlife from organochlorine pesticides in soils.

  1. Bans of WHO Class I Pesticides in Bangladesh—suicide prevention without hampering agricultural output

    Science.gov (United States)

    Chowdhury, Fazle Rabbi; Dewan, Gourab; Verma, Vasundhara R; Knipe, Duleeka W; Isha, Ishrat Tahsin; Faiz, M Abul; Gunnell, David J; Eddleston, Michael

    2018-01-01

    Abstract Background Pesticide self-poisoning is a major problem in Bangladesh. Over the past 20-years, the Bangladesh government has introduced pesticide legislation and banned highly hazardous pesticides (HHPs) from agricultural use. We aimed to assess the impacts of pesticide bans on suicide and on agricultural production. Methods We obtained data on unnatural deaths from the Statistics Division of Bangladesh Police, and used negative binomial regression to quantify changes in pesticide suicides and unnatural deaths following removal of WHO Class I toxicity HHPs from agriculture in 2000. We assessed contemporaneous trends in other risk factors, pesticide usage and agricultural production in Bangladesh from 1996 to 2014. Results Mortality in hospital from pesticide poisoning fell after the 2000 ban: 15.1% vs 9.5%, relative reduction 37.1% [95% confidence interval (CI) 35.4 to 38.8%]. The pesticide poisoning suicide rate fell from 6.3/100 000 in 1996 to 2.2/100 000 in 2014, a 65.1% (52.0 to 76.7%) decline. There was a modest simultaneous increase in hanging suicides [20.0% (8.4 to 36.9%) increase] but the overall incidence of unnatural deaths fell from 14.0/100 000 to 10.5/100 000 [25.0% (18.1 to 33.0%) decline]. There were 35 071 (95% CI 25 959 to 45 666) fewer pesticide suicides in 2001 to 2014 compared with the number predicted based on trends between 1996 to 2000. This reduction in rate of pesticide suicides occurred despite increased pesticide use and no change in admissions for pesticide poisoning, with no apparent influence on agricultural output. Conclusions Strengthening pesticide regulation and banning WHO Class I toxicity HHPs in Bangladesh were associated with major reductions in deaths and hospital mortality, without any apparent effect on agricultural output. Our data indicate that removing HHPs from agriculture can rapidly reduce suicides without imposing substantial agricultural costs. PMID:29024951

  2. Bans of WHO Class I Pesticides in Bangladesh-suicide prevention without hampering agricultural output.

    Science.gov (United States)

    Chowdhury, Fazle Rabbi; Dewan, Gourab; Verma, Vasundhara R; Knipe, Duleeka W; Isha, Ishrat Tahsin; Faiz, M Abul; Gunnell, David J; Eddleston, Michael

    2018-02-01

    Pesticide self-poisoning is a major problem in Bangladesh. Over the past 20-years, the Bangladesh government has introduced pesticide legislation and banned highly hazardous pesticides (HHPs) from agricultural use. We aimed to assess the impacts of pesticide bans on suicide and on agricultural production. We obtained data on unnatural deaths from the Statistics Division of Bangladesh Police, and used negative binomial regression to quantify changes in pesticide suicides and unnatural deaths following removal of WHO Class I toxicity HHPs from agriculture in 2000. We assessed contemporaneous trends in other risk factors, pesticide usage and agricultural production in Bangladesh from 1996 to 2014. Mortality in hospital from pesticide poisoning fell after the 2000 ban: 15.1% vs 9.5%, relative reduction 37.1% [95% confidence interval (CI) 35.4 to 38.8%]. The pesticide poisoning suicide rate fell from 6.3/100 000 in 1996 to 2.2/100 000 in 2014, a 65.1% (52.0 to 76.7%) decline. There was a modest simultaneous increase in hanging suicides [20.0% (8.4 to 36.9%) increase] but the overall incidence of unnatural deaths fell from 14.0/100 000 to 10.5/100 000 [25.0% (18.1 to 33.0%) decline]. There were 35 071 (95% CI 25 959 to 45 666) fewer pesticide suicides in 2001 to 2014 compared with the number predicted based on trends between 1996 to 2000. This reduction in rate of pesticide suicides occurred despite increased pesticide use and no change in admissions for pesticide poisoning, with no apparent influence on agricultural output. Strengthening pesticide regulation and banning WHO Class I toxicity HHPs in Bangladesh were associated with major reductions in deaths and hospital mortality, without any apparent effect on agricultural output. Our data indicate that removing HHPs from agriculture can rapidly reduce suicides without imposing substantial agricultural costs. © The Author 2017. Published by Oxford University Press on behalf of the International

  3. PET imaging evaluation of [{sup 18}F]DBT-10, a novel radioligand specific to α{sub 7} nicotinic acetylcholine receptors, in nonhuman primates

    Energy Technology Data Exchange (ETDEWEB)

    Hillmer, Ansel T.; Zheng, Ming-Qiang; Li, Songye; Lin, Shu-fei; Holden, Daniel; Labaree, David; Ropchan, Jim; Carson, Richard E.; Huang, Yiyun [Yale University, PET Center, 801 Howard Ave, PO Box 208048, New Haven, CT (United States); Scheunemann, Matthias; Teodoro, Rodrigo; Deuther-Conrad, Winnie; Brust, Peter [Helmholtz-Zentrum Dresden-Rossendorf, Institute of Radiopharmaceutical Cancer Research, Leipzig (Germany)

    2016-03-15

    Positron emission tomography (PET) radioligands specific to α{sub 7} nicotinic acetylcholine receptors (nAChRs) afford in vivo imaging of this receptor for neuropathologies such as Alzheimer's disease, schizophrenia, and substance abuse. This work aims to characterize the kinetic properties of an α{sub 7}-nAChR-specific radioligand, 7-(1,4-diazabicyclo[3.2.2]nonan-4-yl)-2-[{sup 18}F]-fluorodibenzo[b,d]thiophene 5,5-dioxide ([{sup 18}F]DBT-10), in nonhuman primates. [{sup 18}F]DBT-10 was produced via nucleophilic substitution of the nitro-precursor. Four Macaca mulatta subjects were imaged with [{sup 18}F]DBT-10 PET, with measurement of [{sup 18}F]DBT-10 parent concentrations and metabolism in arterial plasma. Baseline PET scans were acquired for all subjects. Following one scan, ex vivo analysis of brain tissue was performed to inspect for radiolabeled metabolites in brain. Three blocking scans with 0.69 and 1.24 mg/kg of the α{sub 7}-nAChR-specific ligand ASEM were also acquired to assess dose-dependent blockade of [{sup 18}F]DBT-10 binding. Kinetic analysis of PET data was performed using the metabolite-corrected input function to calculate the parent fraction corrected total distribution volume (V{sub T}/f{sub P}). [{sup 18}F]DBT-10 was produced within 90 min at high specific activities of 428 ± 436 GBq/μmol at end of synthesis. Metabolism of [{sup 18}F]DBT-10 varied across subjects, stabilizing by 120 min post-injection at parent fractions of 15-55 %. Uptake of [{sup 18}F]DBT-10 in brain occurred rapidly, reaching peak standardized uptake values (SUVs) of 2.9-3.7 within 30 min. The plasma-free fraction was 18.8 ± 3.4 %. No evidence for radiolabeled [{sup 18}F]DBT-10 metabolites was found in ex vivo brain tissue samples. Kinetic analysis of PET data was best described by the two-tissue compartment model. Estimated V{sub T}/f{sub P} values were 193-376 ml/cm{sup 3} across regions, with regional rank order of thalamus > frontal cortex > striatum

  4. Residential agricultural pesticide exposures and risks of selected birth defects among offspring in the San Joaquin Valley of California.

    Science.gov (United States)

    Carmichael, Suzan L; Yang, Wei; Roberts, Eric; Kegley, Susan E; Brown, Timothy J; English, Paul B; Lammer, Edward J; Shaw, Gary M

    2016-01-01

    We examined associations of birth defects with residential proximity to commercial agricultural pesticide applications in California. Subjects included 367 cases representing five types of birth defects and 785 nonmalformed controls born 1997 to 2006. Associations with any versus no exposure to physicochemical groups of pesticides and specific chemicals were assessed using logistic regression adjusted for covariates. Overall, 46% of cases and 38% of controls were classified as exposed to pesticides within a 500 m radius of mother's address during a 3-month periconceptional window. We estimated odds ratios (ORs) for 85 groups and 95 chemicals with five or more exposed cases and control mothers. Ninety-five percent confidence intervals (CI) excluded 1.0 for 11 ORs for groups and 22 ORs for chemicals, ranging from 1.9 to 3.1 for groups and 1.8 to 4.9 for chemicals except for two that were <1 (noted below). For groups, these ORs were for anotia/microtia (n = 95 cases) and dichlorophenoxy acids/esters and neonicotinoids; anorectal atresia/stenosis (n = 77) and alcohol/ethers and organophosphates (these ORs were < 1.0); transverse limb deficiencies (n = 59) and dichlorophenoxy acids/esters, petroleum derivatives, and triazines; and craniosynostosis (n = 79) and alcohol/ethers, avermectins, neonicotinoids, and organophosphates. For chemicals, ORs were: anotia/microtia and five pesticides from the groups dichlorophenoxy acids/esters, copper-containing compounds, neonicotinoids, organophosphates, and triazines; transverse limb deficiency and six pesticides - oxyfluorfen and pesticides from the groups copper-containing compounds, 2,6-dinitroanilines, neonicotinoids, petroleum derivatives and polyalkyloxy compounds; craniosynostosis and 10 pesticides - oxyfluorfen and pesticides from the groups alcohol/ethers, avermectins, n-methyl-carbamates, neonicotinoids, ogranophosphates (two chemicals), polyalkyloxy compounds (two chemicals), and pyrethroids; and

  5. Collective flow measurements with HADES in Au+Au collisions at 1.23A GeV

    Science.gov (United States)

    Kardan, Behruz; Hades Collaboration

    2017-11-01

    HADES has a large acceptance combined with a good mass-resolution and therefore allows the study of dielectron and hadron production in heavy-ion collisions with unprecedented precision. With the statistics of seven billion Au-Au collisions at 1.23A GeV recorded in 2012, the investigation of higher-order flow harmonics is possible. At the BEVALAC and SIS18 directed and elliptic flow has been measured for pions, charged kaons, protons, neutrons and fragments, but higher-order harmonics have not yet been studied. They provide additional important information on the properties of the dense hadronic medium produced in heavy-ion collisions. We present here a high-statistics, multidifferential measurement of v1 and v2 for protons in Au+Au collisions at 1.23A GeV.

  6. Evaluation of two fast and easy methods for pesticide residue analysis in fatty food matrixes.

    Science.gov (United States)

    Lehotay, Steven J; Mastovská, Katerina; Yun, Seon Jong

    2005-01-01

    Two rapid methods of sample preparation and analysis of fatty foods (e.g., milk, eggs, and avocado) were evaluated and compared for 32 pesticide residues representing a wide range of physicochemical properties. One method, dubbed the quick, easy, cheap, effective, rugged, and safe (QuEChERS) method for pesticide residue analysis, entailed extraction of 15 g sample with 15 mL acetonitrile (MeCN) containing 1% acetic acid followed by addition of 6 g anhydrous magnesium sulfate and 1.5 g sodium acetate. After centrifugation, 1 mL of the buffered MeCN extract underwent a cleanup step (in a technique known as dispersive solid-phase extraction) using 50 mg each of C18 and primary secondary amine sorbents plus 150 mg MgSO4. The second method incorporated a form of matrix solid-phase dispersion (MSPD), in which 0.5 g sample plus 2 g C18 and 2 g anhydrous sodium sulfate was mixed in a mortar and pestle and added above a 2 g Florisil column on a vacuum manifold. Then, 5 x 2 mL MeCN was used to elute the pesticide analytes from the sample into a collection tube, and the extract was concentrated to 0.5 mL by evaporation. Extracts in both methods were analyzed concurrently by gas chromatography/mass spectrometry and liquid chromatography/tandem mass spectrometry. The recoveries of semi-polar and polar pesticides were typically 100% in both methods (except that basic pesticides, such as thiabendazole and imazalil, were not recovered in the MSPD method), but recovery of nonpolar pesticides decreased as fat content of the sample increased. This trend was more pronounced in the QuEChERS method, in which case the most lipophilic analyte tested, hexachlorobenzene, gave 27 +/- 1% recovery (n=6) in avocado (15% fat) with a<10 ng/g limit of quantitation.

  7. Anchoring of Ag-Au alloy nanoparticles on reduced graphene oxide sheets for the reduction of 4-nitrophenol

    Energy Technology Data Exchange (ETDEWEB)

    Hareesh, K., E-mail: appi.2907@gmail.com [Department of Physics, Savitribai Phule Pune University, Pune 411007 (India); Joshi, R.P. [Department of Physics, Savitribai Phule Pune University, Pune 411007 (India); Sunitha, D.V. [School of Physics, Reva University, Bangalore 560064 (India); Bhoraskar, V.N. [Department of Physics, Savitribai Phule Pune University, Pune 411007 (India); Dhole, S.D., E-mail: sanjay@physics.unipune.ac.in [Department of Physics, Savitribai Phule Pune University, Pune 411007 (India)

    2016-12-15

    Highlights: • Ag-Au-rGO nanocomposite was synthesized by gamma radiation assisted method. • Ag-Au nanoparticles of size (5–19) nm were decorated on rGO. • Ag-Au-rGO showed enhanced catalytic activity for reduction of 4-Nitrophenol. - Abstract: One-step gamma radiation assisted method has been used for the synthesis of Silver-Gold (Ag-Au) alloy nanoparticles with simultaneous reduction of graphene oxide (GO). UV–vis spectroscopic results along with X-ray diffraction analysis, X-ray Photoelectron spectroscopy and Transmission electron microscopy confirmed the decoration face centered cubic structured Ag-Au nanoparticles of size (5–19) nm on reduced graphene oxide (rGO) sheets. The increase in disorder parameter in Raman spectroscopy indicates the formation of more number of small sp{sup 2} domains. The synthesized Ag-Au-rGO nanocomposite showed enhanced catalytic activity towards the reduction of 4-Nitrophenol compared to individual Ag-Au and rGO components.

  8. Effects of chemical and biological pesticides on plant growth parameters and rhizospheric bacterial community structure in Vigna radiata

    Energy Technology Data Exchange (ETDEWEB)

    Singh, Sunil; Gupta, Rashi; Sharma, Shilpi, E-mail: shilpi@dbeb.iitd.ac.in

    2015-06-30

    Highlights: • Non-target effects of pesticides employing qualitative and quantitative approaches. • Qualitative shifts in resident and active bacterial community structure. • Abundance of 16S rRNA gene and transcripts were reduced significantly. • Effects of biological pesticide similar to chemical pesticides on rhizospheric bacteria. - Abstract: With increasing application of pesticides in agriculture, their non-target effects on soil microbial communities are critical to soil health maintenance. The present study aimed to evaluate the effects of chemical pesticides (chlorpyrifos and cypermethrin) and a biological pesticide (azadirachtin) on growth parameters and the rhizospheric bacterial community of Vigna radiata. Qualitative and quantitative analysis by PCR-denaturing gradient gel electrophoresis (DGGE) and q-PCR, respectively, of the 16S rRNA gene and transcript were performed to study the impact of these pesticides on the resident and active rhizospheric bacterial community. While plant parameters were not affected significantly by the pesticides, a shift in the bacterial community structure was observed with an adverse effect on the abundance of 16S rRNA gene and transcripts. Chlorpyrifos showed almost complete degradation toward the end of the experiment. These non-target impacts on soil ecosystems and the fact that the effects of the biopesticide mimic those of chemical pesticides raise serious concerns regarding their application in agriculture.

  9. Effects of chemical and biological pesticides on plant growth parameters and rhizospheric bacterial community structure in Vigna radiata

    International Nuclear Information System (INIS)

    Singh, Sunil; Gupta, Rashi; Sharma, Shilpi

    2015-01-01

    Highlights: • Non-target effects of pesticides employing qualitative and quantitative approaches. • Qualitative shifts in resident and active bacterial community structure. • Abundance of 16S rRNA gene and transcripts were reduced significantly. • Effects of biological pesticide similar to chemical pesticides on rhizospheric bacteria. - Abstract: With increasing application of pesticides in agriculture, their non-target effects on soil microbial communities are critical to soil health maintenance. The present study aimed to evaluate the effects of chemical pesticides (chlorpyrifos and cypermethrin) and a biological pesticide (azadirachtin) on growth parameters and the rhizospheric bacterial community of Vigna radiata. Qualitative and quantitative analysis by PCR-denaturing gradient gel electrophoresis (DGGE) and q-PCR, respectively, of the 16S rRNA gene and transcript were performed to study the impact of these pesticides on the resident and active rhizospheric bacterial community. While plant parameters were not affected significantly by the pesticides, a shift in the bacterial community structure was observed with an adverse effect on the abundance of 16S rRNA gene and transcripts. Chlorpyrifos showed almost complete degradation toward the end of the experiment. These non-target impacts on soil ecosystems and the fact that the effects of the biopesticide mimic those of chemical pesticides raise serious concerns regarding their application in agriculture

  10. Growth and structure of Co/Au magnetic thin films; Croissance et structure des couches minces magnetiques Co/Au

    Energy Technology Data Exchange (ETDEWEB)

    Marsot, N

    1999-01-14

    We have studied the growth and the crystallographic structure of magnetic ultra thin cobalt/gold films (Co/Au), in order to investigate the correlations between their magnetic and structural properties. Room temperature (R.T.) Co growth on Au (111) proceeds in three stages. Up to 2 Co monolayers (ML), a bilayer island growth mode is observed. Between 2 and 5 ML, coalescence of the islands occurs, covering the substrate surface and a Co/Au mixing is observed resulting from the de-construction of the Herringbone reconstruction. Finally, beyond 5 ML, the CoAu mixing is buried and the Co growth continues in a 3-D growth. Annealing studies at 600 K on this system show a smoothing effect of the Co film, and at the same time, segregation of Au atoms. The quality of the Co/Au interface (sharpness) is not enhanced by the annealing. The local order was studied by SEXAFS and the long range order by GIXRD showing that the Co film has a hexagonal close packed structure, with an easy magnetization axis perpendicular to the surface. From a local order point of view, the Co grows with an incoherent epitaxy and keeps its own bulk parameters. The GIXRD analysis shows a residual strain in the Co film of 4%. The difference observed between the local order analysis and the long range order results is explained in terms of the low dimensions of the diffracting domains. The evolution of film strains, as a function of the Co coverage, shows a marked deviation from the elastic strain theory. Modification of the strain field in the Co film as a function of the Au coverage is studied by GIXRD analysis. The Au growth study, at R.T., shows no evidence of a Au/Co mixing in the case of the Au/Co interface. The Au overlayer adopts a twinned face centred cubic structure on the rough Co film surface. (author)

  11. Dynamique de fréquentation des grands mammifères dans une ...

    African Journals Online (AJOL)

    SARAH

    31 juil. 2016 ... RÉSUMÉ. Objectifs : Dans le but de connaitre les animaux fréquentant les clairières (ou Baï) forestières au Gabon, une étude sur la fréquentation du Baï de Momba par les grands mammifères a été conduite durant la petite saison des pluies pendant deux mois du 19 février au 13 mars 2012. Méthodologie ...

  12. Au@AuPt nanoparticles embedded in B-doped graphene: A superior electrocatalyst for determination of rutin

    Energy Technology Data Exchange (ETDEWEB)

    Chen, Xianlan; Yang, Guangming; Feng, Shaoping; Shi, Ling; Huang, Zhaolong [School of Science, Honghe University (China); Key Laboratory of Natural Pharamaceutical & Chemical Biology of Yunnan Province Mengzi, Yunnan 661100 (China); Pan, Haibo [Fujian Key Lab of Medical Instrument & Pharmaceutical Technology, Yishan Campus, Fuzhou University, Fuzhou, Fujian 350002 (China); Liu, Wei, E-mail: liuwei4728@126.com [School of Science, Honghe University (China); Key Laboratory of Natural Pharamaceutical & Chemical Biology of Yunnan Province Mengzi, Yunnan 661100 (China)

    2017-04-30

    Highlights: • The formation of B-doped graphene (BG) with high content of a total B species use hydrothermal method with B{sub 2}O{sub 3} as reducing agent and boron source. • BG was exfoliated into monolayer nanosheet impregnated by Au@AuPt NPs because B atom creates a net positive charge to facilitate NPs adsorption. • The dispersed carboxyl units of BG can form hydrogen bonding with the phenolic hydroxyl groups of rutin, making more rutin participate in reaction. • Au@AuPt NPs can form charge accumulation or valence change on prominent part of the surface, improving the catalytic effect to rutin. • More electroactive sites were generated by doping B atoms into graphene structures, which act as multidimensional electron transport pathways. - Abstract: A hydrothermal approach was used to prepare B-doped graphene with B{sub 2}O{sub 3} as reductant and boron source. Results reveal that the boron atoms have been successfully embedded into graphene with a high content of a total B species (2.85 at.%). Then, B-doped graphene was exfoliated further into monolayer nanosheet by impregnating Au@AuPt core-shell nanoparticles (Au@AuPt NPs) because boron atom creates a net positive charge, which facilitates Au@AuPt NPs adsorption to form Au@AuPt NPs/B-doped graphene hybrid nanocatalysts. After that, the Au@AuPt NPs/B-doped hybrid suspension was dropped on glassy carbon electrode for sensing rutin. In this way, the dispersed carboxyl units of B-doped graphene can form hydrogen bonding with the phenolic hydroxyl groups of rutin, making rutin enrich easily on modified electrode surface to enhance the electrochemical response. At the same time, its electrochemical mechanism on the modified electrode was elucidated using cyclic voltammetry. It was found that its electrochemical behavior on modified electrode surface was a surface-controlled quasi-reversible process, and the charge transfer coefficient (α) and electron transfer number (n) were 0.296 and 2, respectively

  13. Strange and multistrange particle production in Au plus Au collisions at root s(NN)=62.4 GeV

    Czech Academy of Sciences Publication Activity Database

    Aggarwal, M. M.; Ahammed, Z.; Alakhverdyants, A. V.; Alekseev, I.; Bielčík, J.; Bielčíková, Jana; Chaloupka, Petr; Chung, P.; Kapitán, Jan; Kouchpil, V.; Rusnak, J.; Šumbera, Michal

    2011-01-01

    Roč. 83, č. 2 (2011), 024901/1-024901/15 ISSN 0556-2813 R&D Projects: GA MŠk LA09013 Institutional research plan: CEZ:AV0Z10480505 Keywords : ENERGY-DEPENDENCE * HADRON-PRODUCTION * AU+AU COLLISIONS Subject RIV: BG - Nuclear, Atomic and Molecular Physics, Colliders Impact factor: 3.308, year: 2011

  14. Spontaneous decoration of Au nanoparticles on micro-patterned reduced graphene oxide shaped by focused laser beam

    International Nuclear Information System (INIS)

    Wan, Y. C.; Tok, E. S.; Teoh, H. F.; Sow, C. H.

    2015-01-01

    We report a facile, two-step method for the micro-landscaping of Au nanoparticles(NPs) on reduced graphene oxide (rGO) film en route to micro-patterned Au(NPs)-rGO hybrid functional materials. This method employs a focused laser beam to first locally convert GO to rGO before immersing the micro-patterned GO-rGO film into HAuCl 4 solution. The rGO micro-pattern, shaped by the focused laser beam, serves as nucleation sites for the reduction of Au ions. The reduction mechanism that governs the decoration of Au NPs on rGO films is akin to electroless deposition process. In this instance, surface charges that are formed during laser reduction of GO to rGO provide active nucleation sites for Au 3+ ions to form Au NPs when HAuCl 4 solution is introduced. The number density, the size, and size distribution of the Au NPs can thus be directly tuned and preferentially anchored onto the rGO micro-pattern by varying the incident laser power, the scanning speed of the laser, or the concentration of HAuCl 4 . The resulting hybrid materials can be used as a substrate for Surface Enhanced Raman Spectroscopy (SERS). Using Rhodamine 6G as the test subject, we found an improvement of SERS enhancement over bare rGO of up to four times, depending on the size of the Au NPs

  15. Spontaneous decoration of Au nanoparticles on micro-patterned reduced graphene oxide shaped by focused laser beam

    Energy Technology Data Exchange (ETDEWEB)

    Wan, Y. C.; Tok, E. S. [Department of Physics, National University of Singapore, 2 Science Drive 3, Singapore 117542 (Singapore); Teoh, H. F. [Graduate School of Integrative Sciences and Engineering, National University of Singapore, 28 Medical Drive, Singapore 117456 (Singapore); Sow, C. H. [Department of Physics, National University of Singapore, 2 Science Drive 3, Singapore 117542 (Singapore); Graduate School of Integrative Sciences and Engineering, National University of Singapore, 28 Medical Drive, Singapore 117456 (Singapore)

    2015-02-07

    We report a facile, two-step method for the micro-landscaping of Au nanoparticles(NPs) on reduced graphene oxide (rGO) film en route to micro-patterned Au(NPs)-rGO hybrid functional materials. This method employs a focused laser beam to first locally convert GO to rGO before immersing the micro-patterned GO-rGO film into HAuCl{sub 4} solution. The rGO micro-pattern, shaped by the focused laser beam, serves as nucleation sites for the reduction of Au ions. The reduction mechanism that governs the decoration of Au NPs on rGO films is akin to electroless deposition process. In this instance, surface charges that are formed during laser reduction of GO to rGO provide active nucleation sites for Au{sup 3+} ions to form Au NPs when HAuCl{sub 4} solution is introduced. The number density, the size, and size distribution of the Au NPs can thus be directly tuned and preferentially anchored onto the rGO micro-pattern by varying the incident laser power, the scanning speed of the laser, or the concentration of HAuCl{sub 4}. The resulting hybrid materials can be used as a substrate for Surface Enhanced Raman Spectroscopy (SERS). Using Rhodamine 6G as the test subject, we found an improvement of SERS enhancement over bare rGO of up to four times, depending on the size of the Au NPs.

  16. The effect of Au amount on size uniformity of self-assembled Au nanoparticles

    Energy Technology Data Exchange (ETDEWEB)

    Chen, S-H; Wang, D-C; Chen, G-Y; Chen, K-Y [Graduate School of Engineering Science and Technology, National Yunlin University of Science and Technology, Taiwan (China)

    2008-03-15

    The self-assembled fabrication of nanostructure, a dreaming approach in the area of fabrication engineering, is the ultimate goal of this research. A finding was proved through previous research that the size of the self-assembled gold nanoparticles could be controlled with the mole ratio between AuCl{sub 4}{sup -} and thiol. In this study, the moles of Au were fixed, only the moles of thiol were adjusted. Five different mole ratios of Au/S with their effect on size uniformity were investigated. The mole ratios were 1:1/16, 1:1/8, 1:1, 1:8, 1:16, respectively. The size distributions of the gold nanoparticles were analyzed by Mac-View analysis software. HR-TEM was used to derive images of self-assembled gold nanoparticles. The result reached was also the higher the mole ratio between AuCl{sub 4}{sup -} and thiol the bigger the self-assembled gold nanoparticles. Under the condition of moles of Au fixed, the most homogeneous nanoparticles in size distribution derived with the mole ratio of 1:1/8 between AuCl{sub 4}{sup -} and thiol. The obtained nanoparticles could be used, for example, in uniform surface nanofabrication, leading to the fabrication of ordered array of quantum dots.

  17. Pesticide uptake in potatoes: model and field experiments.

    Science.gov (United States)

    Juraske, Ronnie; Vivas, Carmen S Mosquera; Velásquez, Alexander Erazo; Santos, Glenda García; Moreno, Mónica B Berdugo; Gomez, Jaime Diaz; Binder, Claudia R; Hellweg, Stefanie; Dallos, Jairo A Guerrero

    2011-01-15

    A dynamic model for uptake of pesticides in potatoes is presented and evaluated with measurements performed within a field trial in the region of Boyacá, Colombia. The model takes into account the time between pesticide applications and harvest, the time between harvest and consumption, the amount of spray deposition on soil surface, mobility and degradation of pesticide in soil, diffusive uptake and persistence due to crop growth and metabolism in plant material, and loss due to food processing. Food processing steps included were cleaning, washing, storing, and cooking. Pesticide concentrations were measured periodically in soil and potato samples from the beginning of tuber formation until harvest. The model was able to predict the magnitude and temporal profile of the experimentally derived pesticide concentrations well, with all measurements falling within the 90% confidence interval. The fraction of chlorpyrifos applied on the field during plant cultivation that eventually is ingested by the consumer is on average 10(-4)-10(-7), depending on the time between pesticide application and ingestion and the processing step considered.

  18. Preparation of Pt Au/C and Pt Au Bi/C electrocatalysts using electron beam irradiation for ethanol electro-oxidation in alkaline medium

    International Nuclear Information System (INIS)

    Silva, Dionisio F.; Geraldes, Adriana N.; Cardoso, Elisangela S.Z.; Gomes, Thiago B.; Linardi, Marcelo; Oliveira Neto, Almir; Spinace, Estevam V.

    2011-01-01

    Pt Au/C (50:50) and PtAuBi/C electrocatalysts with Pt:Au:Bi atomic ratios of 50:40:10, 50:30:20 and 50:10:40 were prepared in water/2-propanol using electron beam irradiation. The materials were characterized by X-ray diffraction (XRD) and the electro-oxidation of ethanol was studied by chronoamperometry at room temperature. The X-ray diffraction measurements for all electrocatalysts prepared showed four peaks, which are associated with the planes of the face-centered cubic (fcc) structure characteristic of Pt and Pt alloys. For PtAuBi/C it was also observed the presence of a mixture of BiPt alloys and bismuth phases. The average crystallite sizes for Pt/C, PtAu/C, PtAuBi/C (50:40:10), PtAuBi/C (50:30:20) and PtAuBi/C (50:10:40) were in the range of 2.0 - 4.0 nm. The activity of the electrocatalysts for ethanol oxidation in alkaline medium showed that PtAuBi/C (50:40:10) had a higher performance for ethanol oxidation compared to others electrocatalysts prepared. (author)

  19. Preparation of Pt Au/C and Pt Au Bi/C electrocatalysts using electron beam irradiation for ethanol electro-oxidation in alkaline medium

    Energy Technology Data Exchange (ETDEWEB)

    Silva, Dionisio F.; Geraldes, Adriana N.; Cardoso, Elisangela S.Z.; Gomes, Thiago B.; Linardi, Marcelo; Oliveira Neto, Almir; Spinace, Estevam V., E-mail: dfsilva@ipen.b [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil)

    2011-07-01

    Pt Au/C (50:50) and PtAuBi/C electrocatalysts with Pt:Au:Bi atomic ratios of 50:40:10, 50:30:20 and 50:10:40 were prepared in water/2-propanol using electron beam irradiation. The materials were characterized by X-ray diffraction (XRD) and the electro-oxidation of ethanol was studied by chronoamperometry at room temperature. The X-ray diffraction measurements for all electrocatalysts prepared showed four peaks, which are associated with the planes of the face-centered cubic (fcc) structure characteristic of Pt and Pt alloys. For PtAuBi/C it was also observed the presence of a mixture of BiPt alloys and bismuth phases. The average crystallite sizes for Pt/C, PtAu/C, PtAuBi/C (50:40:10), PtAuBi/C (50:30:20) and PtAuBi/C (50:10:40) were in the range of 2.0 - 4.0 nm. The activity of the electrocatalysts for ethanol oxidation in alkaline medium showed that PtAuBi/C (50:40:10) had a higher performance for ethanol oxidation compared to others electrocatalysts prepared. (author)

  20. Introduction au dossier « Mutations de l’accompagnement dans les formations en ligne »

    OpenAIRE

    Simonian, Stephane; Savarieau, Béatrice

    2016-01-01

    Suite au colloque organisé par le laboratoire CIVIIC (Centre interdisciplinaire de recherches sur les valeurs, les idées, les identités et les compétences) qui s’est tenu à Rouen du 8 au 10 octobre 2014 intitulé « Mutations de l’accompagnement dans les formations en ligne », il nous est apparu intéressant – bien que risqué – de traiter d’un sujet pouvant être considéré comme un point aveugle lié à l’accompagnement de la rédaction de mémoires dans le cas des formations à distance ou hybrides. ...

  1. N-body simulations for f(R) gravity using a self-adaptive particle-mesh code

    Science.gov (United States)

    Zhao, Gong-Bo; Li, Baojiu; Koyama, Kazuya

    2011-02-01

    We perform high-resolution N-body simulations for f(R) gravity based on a self-adaptive particle-mesh code MLAPM. The chameleon mechanism that recovers general relativity on small scales is fully taken into account by self-consistently solving the nonlinear equation for the scalar field. We independently confirm the previous simulation results, including the matter power spectrum, halo mass function, and density profiles, obtained by Oyaizu [Phys. Rev. DPRVDAQ1550-7998 78, 123524 (2008)10.1103/PhysRevD.78.123524] and Schmidt [Phys. Rev. DPRVDAQ1550-7998 79, 083518 (2009)10.1103/PhysRevD.79.083518], and extend the resolution up to k˜20h/Mpc for the measurement of the matter power spectrum. Based on our simulation results, we discuss how the chameleon mechanism affects the clustering of dark matter and halos on full nonlinear scales.

  2. Assessment of R18, COG1410, and APP96-110 in excitotoxicity and traumatic brain injury

    Directory of Open Access Journals (Sweden)

    Chiu Li Shan

    2017-11-01

    Full Text Available Cationic arginine-rich and poly-arginine peptides (referred to as CARPs have potent neuroprotective properties in in vitro excitotoxicity and in vivo models of stroke. Traumatic brain injury (TBI shares many pathophysiological processes as stroke, including excitotoxicity. Therefore, we evaluated our lead peptide, poly-arginine R18, with the COG1410 and APP96-110 peptides, which have neuroprotective actions following TBI. In an in vitro cortical neuronal glutamic acid excitotoxicity injury model, R18 was highly neuroprotective and reduced neuronal calcium influx, while COG1410 and APP96-110 displayed modest neuroprotection and were less effective at reducing calcium influx. In an impact-acceleration closed-head injury model (Marmarou model, R18, COG1410, and APP96-110 were administered intravenously (300 nmol/kg at 30 minutes after injury in male Sprague-Dawley rats. When compared to vehicle, no peptide significantly improved functional outcomes, however the R18 and COG1410 treatment groups displayed positive trends in the adhesive tape test and rotarod assessments. Similarly, no peptide had a significant effect on hippocampal neuronal loss, however a significant reduction in axonal injury was observed for R18 and COG1410. In conclusion, this study has demonstrated that R18 is significantly more effective than COG1410 and APP96-110 at reducing neuronal injury and calcium influx following excitotoxicity, and that both R18 and COG1410 reduce axonal injury following TBI. Additional dose response and treatment time course studies are required to further assess the efficacy of R18 in TBI.

  3. Cube-like Fe3O4@SiO2@Au@Ag magnetic nanoparticles: a highly efficient SERS substrate for pesticide detection

    Science.gov (United States)

    Sun, Mei; Zhao, Aiwu; Wang, Dapeng; Wang, Jin; Chen, Ping; Sun, Henghui

    2018-04-01

    As a novel surface-enhanced Raman spectroscopic (SERS) nanocomposite, cube-like Fe3O4@SiO2@Au@Ag magnetic nanoparticles (NPs) were synthesized for the first time. Cube-like α-Fe2O3 NPs with uniform size were achieved by optimizing reaction temperature and time. Firstly, the cube-like Fe3O4@SiO2 with good dispersity was achieved by calcining α-Fe2O3@SiO2 NPs in hydrogen atmosphere at 360 °C for 2.5 h, followed by self-assembling a PEI shell via sonication. Furthermore, the Au@Ag particles were densely assembled on the Fe3O4@SiO2 NPs to form the Fe3O4@SiO2@Au@Ag composite structure via strong Ag-N interaction. The obtained nanocomposites exhibited an excellent SERS behavior, reflected by the low detection of limit (p-ATP) at the 5 × 10-14 M level. Moreover, these nanocubes were used for the detection of thiram, and the detection limit can reach 5 × 10-11 M. Meanwhile, the U.S. Environmental Protection Agency specifies that the residue in fruit must be lower than 7 ppm. Hence, the resulting substrate with high SERS activity has great practical potential applications in the rapid detection of chemical, biological, and environment pollutants with a simple portable Raman instrument at trace level.

  4. 78 FR 18504 - Emamectin Benzoate; Pesticide Tolerance

    Science.gov (United States)

    2013-03-27

    ... availability and use of monitoring data and food preparation-reduction factors for washing, cooking, etc. may... Federal Food, Drug, and Cosmetic Act (FFDCA). DATES: This regulation is effective March 27, 2013... affected by this action if you are an agricultural producer, food manufacturer, or pesticide manufacturer...

  5. 75 FR 22240 - Cyprodinil; Pesticide Tolerances

    Science.gov (United States)

    2010-04-28

    ... commodities. In addition, a high performance liquid chromatography with mass spectrometry (HPLC/MS) method... Executive Order Reviews This final rule establishes tolerances under section 408(d) of FFDCA in response to... types of actions from review under Executive Order 12866, entitled Regulatory Planning and Review (58 FR...

  6. Lung clearance of polydispersed colloidal 198Au particles

    International Nuclear Information System (INIS)

    D'Addabbo, A.; Fanfani, G.

    1975-01-01

    Lung clearance was studied on a group of subjects over 65 years old and on subjects aged between 30 and 40. A slowing down of material deposited in the bronchial tubes (polydispersed colloidal 198 Au particles) was observed in the senile subjects. This phenomenon is apparently related not only to a reduced activity of the vibratile ciliae, in connection with the frequent metaplasia of the bronchial cylindrical epithelium, but also to a quantitative and qualitative change in the mucopolysaccharides forming the mucus secretion [fr

  7. Pesticides in Brazilian freshwaters: a critical review.

    Science.gov (United States)

    Albuquerque, A F; Ribeiro, J S; Kummrow, F; Nogueira, A J A; Montagner, C C; Umbuzeiro, G A

    2016-07-13

    The widespread use of pesticides in agriculture can lead to water contamination and cause adverse effects on non-target organisms. Brazil has been the world's top pesticide market consumer since 2008, with 381 approved pesticides for crop use. This study provides a comprehensive literature review on the occurrence of pesticide residues in Brazilian freshwaters. We searched for information in official agency records and peer-reviewed scientific literature. Risk quotients were calculated to assess the potential risk posed to aquatic life by the individual pesticides based on their levels of water contamination. Studies about the occurrence of pesticides in freshwaters in Brazil are scarce and concentrated in few sampling sites in 5 of the 27 states. Herbicides (21) accounted for the majority of the substances investigated, followed by fungicides (11), insecticides (10) and plant growth regulators (1). Insecticides are the class of major concern. Brazil would benefit from the implementation of a nationwide pesticide freshwater monitoring program to support preventive, remediation and enforcement actions.

  8. 75 FR 6112 - Approval and Promulgation of Air Quality Implementation Plans; Georgia: Update to Materials...

    Science.gov (United States)

    2010-02-08

    ...) Incinerators........ 6/15/98 12/2/99, 64 FR 67491 391-3-1-.02(2)(d) Fuel-burning 1/17/79 9/18/79, 44 FR 54047...-.02(2)(aa) VOC Emissions from 1/9/91 10/13/92, 57 FR 46780 Wire Coating. 391-3-1-.02(2)(bb) Petroleum...)(lll) NOX Emissions from 2/16/00 7/10/01, 66 FR 35906 Fuel-burning Equipment. 391-3-1-.02(2)(mmm) NOX...

  9. Direct virtual photon production in Au plus Au collisions at root s(NN)=200 GeV STAR Collaboration

    Czech Academy of Sciences Publication Activity Database

    Adamczyk, L.; Bielčík, J.; Bielčíková, Jana; Chaloupka, P.; Federič, Pavol; Federičová, P.; Harlenderová, A.; Kocmánek, Martin; Kvapil, J.; Lidrych, J.; Rusňák, Jan; Rusňáková, O.; Šaur, Miroslav; Šimko, Miroslav; Šumbera, Michal; Trzeciak, B. A.

    2017-01-01

    Roč. 770, JUL (2017), s. 451-458 ISSN 0370-2693 R&D Projects: GA MŠk LG15001; GA MŠk LM2015054 Institutional support: RVO:61389005 Keywords : STAR collaboration * transverse mementum * Au Au collisions Subject RIV: BG - Nuclear, Atomic and Molecular Physics, Colliders OBOR OECD: Nuclear physics Impact factor: 4.807, year: 2016

  10. Indication of pesticide effects and recolonization in streams.

    Science.gov (United States)

    Knillmann, Saskia; Orlinskiy, Polina; Kaske, Oliver; Foit, Kaarina; Liess, Matthias

    2018-07-15

    The agricultural use of pesticides leads to environmentally relevant pesticide concentrations that cause adverse effects on stream ecosystems. These effects on invertebrate community composition can be identified by the bio-indicator SPEAR pesticides . However, refuge areas have been found to partly confound the indicator. On the basis of three monitoring campaigns of 41 sites in Central Germany, we identified 11 refuge taxa. The refuge taxa, mainly characterized by dispersal-based resilience, were observed only nearby uncontaminated stream sections and independent of the level of pesticide pressure. Through incorporation of this information into the revised SPEAR pesticides indicator, the community structure specifically identified the toxic pressure and no longer depended on the presence of refuge areas. With regard to ecosystem functions, leaf litter degradation was predicted by the revised SPEAR pesticides and the median water temperature at a site (R 2  = 0.38, P = 0.003). Furthermore, we designed the bio-indicator SPEAR refuge to quantify the magnitude of general recolonization at a given stream site. We conclude that the taxonomic composition of aquatic invertebrate communities enables a specific indication of anthropogenic stressors and resilience of ecosystems. Copyright © 2018 Elsevier B.V. All rights reserved.

  11. Ponction biopsies rénales dans le Service de Néphrologie de Fès: indications et résultats: à propos de 522 cas

    Science.gov (United States)

    Mbarki, Houda; Belghiti, Khadija Alaoui; Harmouch, Taoufiq; Najdi, Adil; Arrayhani, Mohamed; Sqalli, Tarik

    2016-01-01

    L'apport de la ponction biopsie rénale (PBR) dans le diagnostic, le choix thérapeutique et l’évaluation pronostique des néphropathies est considérable. Aucune étude marocaine n'a évalué la pratique et l'apport de la PBR. Notre objectif est d’étudier les indications de la PBR, déterminer la fréquence des maladies rénales identifiées par PBR dans notre région et de faire une confrontation entre les données clinico-biologiques et le diagnostic historique. Notre étude menée entre Janvier 2009 et Décembre 2012, est rétrospective. Nous avons inclus tous les patients du service de Néphrologie du CHU Hassan II de Fès ayant bénéficié d'une biopsie de reins natifs. 522 PBR ont été réalisées. Nous avons exclu 8 biopsies devant le manque de renseignements et avons donc retenu 514. L’âge moyen des patients au moment de la PBR est de 39 ±17 ans (3-82 ans). Le sex ratio est de 0,9. Le syndrome néphrotique est le diagnostic clinique le plus fréquent à tous les âges (58,2%). Les néphropathies glomérulaires représentent 94,2% des maladies rénales diagnostiquées, leur distribution varie selon l’âge des patients. La PBR a confirmé le premier diagnostic suspecté cliniquement dans 40,65% des cas, alors qu'elle a révélé un diagnostic inattendu chez 22,5% d'entre eux. Le diagnostic syndromique permet d'orienter vers la maladie rénale la plus probable et de guider les thérapeutiques urgentes en attendant les résultats de la PBR. Mais il ne peut en aucun remplacer la PBR qui reste le gold standard. PMID:27583085

  12. Aspects descriptifs du VIH/SIDA chez les sujets âgés de 50 ans et plus suivis au Centre de Traitement Agréé de Bafoussam - Cameroun

    Science.gov (United States)

    Mbopi-Kéou, François-Xavier; Djomassi, Lucienne Dempouo; Monebenimp, Francisca

    2012-01-01

    Introduction La littérature scientifique dispose de très peu de données relatives à l’épidémiologie du VIH chez les sujets âgés en Afrique subsaharienne. Au Cameroun, les caractéristiques épidémiologiques de l'infection par le VIH chez les sujets âgés de 50 ans et plus ne sont pas documentées. Méthodes Dans une étude de cohorte rétrospective et une enquête transversale, nous avons comparé les caractéristiques clinico-biologiques et la survie post thérapeutique des patients âgés de 50 ans et plus, sous traitement antirétroviral au Centre de Traitement Agrée de Bafoussam - Cameroun, aux adultes plus jeunes. Résultats L’âge moyen était de 39 ans, les extrêmes étant 17 et 88 ans. Les sujets âgés de 50 ans et plus représentaient 14,1% des cas. Les plus âgés étaient moins bien informés sur les modes de transmission du virus (p = 0,04). Leur séropositivité au VIH était le plus souvent découverte au décours d'une infection opportuniste (p = 0,02). La fréquence de comorbidité était significativement plus élevée chez les personnes âgées de 50 ans et plus (p VIH. La promotion du dépistage et les programmes d’éducation sanitaire relatifs au VIH/SIDA devraient être renforcés au sein de cette communauté déjà affaiblie par le poids de l’âge, afin de réduire l'incidence du SIDA et de leur assurer prise en charge précoce. PMID:23133707

  13. Substrate-dependent Au{sub x} cluster: A new insight into Au{sub x}/CeO{sub 2}

    Energy Technology Data Exchange (ETDEWEB)

    Zhu, Kong-Jie; Yang, Yan-Ju [School of Chemistry and Life Science, Zhejiang Normal University, Jinhua 321004 (China); Lang, Jia-Jian [School of Chemistry and Life Science, Zhejiang Normal University, Jinhua 321004 (China); Engineering Laboratory of Specialty Fibers and Nuclear Energy Materials, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo, Zhejiang 315201 (China); Teng, Bo-Tao, E-mail: tbt@zjnu.cn [School of Chemistry and Life Science, Zhejiang Normal University, Jinhua 321004 (China); Wu, Feng-Min [School of Chemistry and Life Science, Zhejiang Normal University, Jinhua 321004 (China); Du, Shi-Yu [Engineering Laboratory of Specialty Fibers and Nuclear Energy Materials, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo, Zhejiang 315201 (China); Wen, Xiao-Dong, E-mail: wxd@sxicc.ac.cn [State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001 (China)

    2016-11-30

    Graphical abstract: 2D Au{sub x} (x < 10) on CeO{sub 2}(110) are more stable than 3D ones, while the stability trend changes for x ≥ 10; Au{sub x} (x ≤ 4) prefer to monatomically disperse on CeO{sub 2}(100) and aggregate to 3D clusters for x > 4. - Highlights: • The stable structures of Au{sub x}/CeO{sub 2} are dependent of index surfaces of CeO{sub 2}. • Au{sub x} prefers to monatomically disperse on CeO{sub 2}(100) at low coverage. • Au{sub x} aggregates to 3D clusters on CeO{sub 2}(100) at high coverage. • 2D Au{sub x} (x < 10) are more stable than the 3D ones on CeO{sub 2}(110). • The effects on the stability of Au{sub x}/CeO{sub 2} are systematically discussed. - Abstract: To theoretically study the structures of metal clusters on oxides is very important and becomes one of the most challenging works in computational heterogeneous catalysis since many factors affect their structures and lead to various possibilities. In this work, it is very interesting to find that the stable structures and stability evolution of Au{sub x} clusters on ceria are varied with different index surfaces of CeO{sub 2}. The corresponding reasons in chemical, geometric and electronic properties are systematically explored. Au{sub x} (x = 1–4) clusters prefer to separately disperse at the O-O bridge sites on CeO{sub 2}(100) due to the low coordination number of surface O; while aggregate due to the strong Au–Au attractions when x is larger than 4. Owing to the uniform distribution of O-O bridge sites on CeO{sub 2}(111) and (100), the most stable configurations of Au{sub x} are 3D structures with bottom atoms more than top ones when x is larger than 4. However, 2D configurations of Au{sub x}/CeO{sub 2}(110) (x < 10) are more stable than the corresponding 3D structures due to the particular O-O arrangement on CeO{sub 2}(110). 3D Au{sub x} clusters across O-O-Y lines are suggested as the most stable configurations for Au{sub x}/CeO{sub 2}(110) (x ≥ 10). The present

  14. [FR] Le developpment du Travail Social et le pluralisme au Québec

    Directory of Open Access Journals (Sweden)

    André Jacob

    2011-06-01

    Full Text Available Normal 0 21 false false false ES X-NONE X-NONE MicrosoftInternetExplorer4 Au Canada et au Québec, traiter des questions liées à la diversité culturelle et au racisme a été un défi pour les gouvernements depuis les années soixante. Auparavant et jusqu'à présent, une grande partie des responsabilités en termes de développement ethnoculturel sensible des services publics (services sociaux, des programmes de formation en travail social, etc. ont été laissés aux mains d’organismes de charité non-lucratifs. Cependant, peu à peu, depuis les années soixante, le gouvernement fédéral et le gouvernement provincial, ont dû développer des politiques et des programmes d'action. Au Québec, le travail social a fait partie du débat face à deux grands courants politiques, l’un canadien basé sur le multiculturalisme, et l’autre québécois basé sur l'interculturalisme. L'article vise à donner une perspective historique 10pt; font-family: "Arial","sans-serif"; color: black;

  15. Observation of a flare-generated shock wave at 9.7 AU by Pioneer 10

    International Nuclear Information System (INIS)

    Dryer, M.; Shea, M.A.; Smart, D.F.; Collard, H.R.; Mihalov, J.D.; Wolfe, J.H.; Warwick, J.W.

    1978-01-01

    The period March 15 to May 15, 1976, was declared in advance to be the internationally recognized Study of Traveling Interplanetary Phenomena Interval II. A variety of ground- and space-based equipment was requested to make coordinated studies during this part of the minimum of solar cycle 20. Following an absence of solar activity for a long period, several type II radio bursts on March 20, 1976, produced by two solar flares behind the east limb heralded a series of solar interplanetary, and terrestrial events. These solar radio astronomical observations were followed by non-Io-associated radio emission from Jupiter and solar wind plasma detection at Pioneer 10 at 9.7 AU of an apparent shock wave on March 30 and April 9, 1976, respectively. In view of the fact that the solar flares on March 20 were essentially at central meridian with respect to Jupiter and Pioneer 10 and also that the sun was extremely inactive prior to that date we consider the circumstantial evidence that at least one solar-flare-generated shock wave propagated to the position of Pioneer 10. The average velocities of this shock wave, together with the inferred type II velocity, support previous observations and theory concerning the rapid deceleration and survival of interplanetary shock waves to distances at least as large as approx.10 AU. It is therefore believed that dissipation (other than that within shocks themselves) plays an insignificant role in shock wave dynamics within the solar wind

  16. Karyotypes, heterochromatin, and physical mapping of 18S-26S rDNA in Cactaceae.

    Science.gov (United States)

    Las Peñas, M L; Urdampilleta, J D; Bernardello, G; Forni-Martins, E R

    2009-01-01

    Karyotype analyses in members of the four Cactaceae subfamilies were performed. Numbers and karyotype formula obtained were: Pereskioideae = Pereskiaaculeata(2n = 22; 10 m + 1 sm), Maihuenioideae = Maihuenia patagonica (2n = 22, 9 m + 2 sm; 2n = 44, 18 m + 4 sm), Opuntioideae = Cumulopuntia recurvata(2n = 44; 20 m + 2 sm), Cactoideae = Acanthocalycium spiniflorum (2n = 22; 10 m + 1 sm),Echinopsis tubiflora (2n = 22; 10 m + 1 sm), Trichocereus candicans (2n = 22, 22 m). Chromosomes were small, the average chromosome length was 2.3 mum. Diploid species and the tetraploid C. recurvata had one terminal satellite, whereas the remaining tetraploid species showed four satellited chromosomes. Karyotypes were symmetrical. No CMA(-)/DAPI(+) bands were detected, but CMA(+)/DAPI(-) bands associated with NOR were always found. Pericentromeric heterochromatin was found in C. recurvata, A. spiniflorum, and the tetraploid cytotype of M. patagonica. The locations of the 18S-26S rDNA sites in all species coincided with CMA(+)/DAPI(-) bands; the same occurred with the sizes and numbers of signals for each species. This technique was applied for the first time in metaphase chromosomes in cacti. NOR-bearing pair no.1 may be homeologous in all species examined. In Cactaceae, the 18S-26S loci seem to be highly conserved. Copyright 2009 S. Karger AG, Basel.

  17. Development and application of freshwater sediment-toxicity benchmarks for currently used pesticides

    Science.gov (United States)

    Nowell, Lisa H.; Norman, Julia E.; Ingersoll, Christopher G.; Moran, Patrick W.

    2016-01-01

    Sediment-toxicity benchmarks are needed to interpret the biological significance of currently used pesticides detected in whole sediments. Two types of freshwater sediment benchmarks for pesticides were developed using spiked-sediment bioassay (SSB) data from the literature. These benchmarks can be used to interpret sediment-toxicity data or to assess the potential toxicity of pesticides in whole sediment. The Likely Effect Benchmark (LEB) defines a pesticide concentration in whole sediment above which there is a high probability of adverse effects on benthic invertebrates, and the Threshold Effect Benchmark (TEB) defines a concentration below which adverse effects are unlikely. For compounds without available SSBs, benchmarks were estimated using equilibrium partitioning (EqP). When a sediment sample contains a pesticide mixture, benchmark quotients can be summed for all detected pesticides to produce an indicator of potential toxicity for that mixture. Benchmarks were developed for 48 pesticide compounds using SSB data and 81 compounds using the EqP approach. In an example application, data for pesticides measured in sediment from 197 streams across the United States were evaluated using these benchmarks, and compared to measured toxicity from whole-sediment toxicity tests conducted with the amphipod Hyalella azteca (28-d exposures) and the midge Chironomus dilutus (10-d exposures). Amphipod survival, weight, and biomass were significantly and inversely related to summed benchmark quotients, whereas midge survival, weight, and biomass showed no relationship to benchmarks. Samples with LEB exceedances were rare (n = 3), but all were toxic to amphipods (i.e., significantly different from control). Significant toxicity to amphipods was observed for 72% of samples exceeding one or more TEBs, compared to 18% of samples below all TEBs. Factors affecting toxicity below TEBs may include the presence of contaminants other than pesticides, physical

  18. Development and application of freshwater sediment-toxicity benchmarks for currently used pesticides

    Energy Technology Data Exchange (ETDEWEB)

    Nowell, Lisa H., E-mail: lhnowell@usgs.gov [U.S. Geological Survey, California Water Science Center, Placer Hall, 6000 J Street, Sacramento, CA 95819 (United States); Norman, Julia E., E-mail: jnorman@usgs.gov [U.S. Geological Survey, Oregon Water Science Center, 2130 SW 5" t" h Avenue, Portland, OR 97201 (United States); Ingersoll, Christopher G., E-mail: cingersoll@usgs.gov [U.S. Geological Survey, Columbia Environmental Research Center, 4200 New Haven Road, Columbia, MO 65021 (United States); Moran, Patrick W., E-mail: pwmoran@usgs.gov [U.S. Geological Survey, Washington Water Science Center, 934 Broadway, Suite 300, Tacoma, WA 98402 (United States)

    2016-04-15

    Sediment-toxicity benchmarks are needed to interpret the biological significance of currently used pesticides detected in whole sediments. Two types of freshwater sediment benchmarks for pesticides were developed using spiked-sediment bioassay (SSB) data from the literature. These benchmarks can be used to interpret sediment-toxicity data or to assess the potential toxicity of pesticides in whole sediment. The Likely Effect Benchmark (LEB) defines a pesticide concentration in whole sediment above which there is a high probability of adverse effects on benthic invertebrates, and the Threshold Effect Benchmark (TEB) defines a concentration below which adverse effects are unlikely. For compounds without available SSBs, benchmarks were estimated using equilibrium partitioning (EqP). When a sediment sample contains a pesticide mixture, benchmark quotients can be summed for all detected pesticides to produce an indicator of potential toxicity for that mixture. Benchmarks were developed for 48 pesticide compounds using SSB data and 81 compounds using the EqP approach. In an example application, data for pesticides measured in sediment from 197 streams across the United States were evaluated using these benchmarks, and compared to measured toxicity from whole-sediment toxicity tests conducted with the amphipod Hyalella azteca (28-d exposures) and the midge Chironomus dilutus (10-d exposures). Amphipod survival, weight, and biomass were significantly and inversely related to summed benchmark quotients, whereas midge survival, weight, and biomass showed no relationship to benchmarks. Samples with LEB exceedances were rare (n = 3), but all were toxic to amphipods (i.e., significantly different from control). Significant toxicity to amphipods was observed for 72% of samples exceeding one or more TEBs, compared to 18% of samples below all TEBs. Factors affecting toxicity below TEBs may include the presence of contaminants other than pesticides, physical/chemical characteristics

  19. Development and application of freshwater sediment-toxicity benchmarks for currently used pesticides

    International Nuclear Information System (INIS)

    Nowell, Lisa H.; Norman, Julia E.; Ingersoll, Christopher G.; Moran, Patrick W.

    2016-01-01

    Sediment-toxicity benchmarks are needed to interpret the biological significance of currently used pesticides detected in whole sediments. Two types of freshwater sediment benchmarks for pesticides were developed using spiked-sediment bioassay (SSB) data from the literature. These benchmarks can be used to interpret sediment-toxicity data or to assess the potential toxicity of pesticides in whole sediment. The Likely Effect Benchmark (LEB) defines a pesticide concentration in whole sediment above which there is a high probability of adverse effects on benthic invertebrates, and the Threshold Effect Benchmark (TEB) defines a concentration below which adverse effects are unlikely. For compounds without available SSBs, benchmarks were estimated using equilibrium partitioning (EqP). When a sediment sample contains a pesticide mixture, benchmark quotients can be summed for all detected pesticides to produce an indicator of potential toxicity for that mixture. Benchmarks were developed for 48 pesticide compounds using SSB data and 81 compounds using the EqP approach. In an example application, data for pesticides measured in sediment from 197 streams across the United States were evaluated using these benchmarks, and compared to measured toxicity from whole-sediment toxicity tests conducted with the amphipod Hyalella azteca (28-d exposures) and the midge Chironomus dilutus (10-d exposures). Amphipod survival, weight, and biomass were significantly and inversely related to summed benchmark quotients, whereas midge survival, weight, and biomass showed no relationship to benchmarks. Samples with LEB exceedances were rare (n = 3), but all were toxic to amphipods (i.e., significantly different from control). Significant toxicity to amphipods was observed for 72% of samples exceeding one or more TEBs, compared to 18% of samples below all TEBs. Factors affecting toxicity below TEBs may include the presence of contaminants other than pesticides, physical/chemical characteristics

  20. Search for anomalously interacting stable particles in the mass range from 1.0 to 1.8 GeV/c2

    International Nuclear Information System (INIS)

    Abramov, V.V.; Arbuzov, V.A.; Baldin, B.Yu.

    1986-01-01

    A search for stable (r > 10 -8 s) anomalously interacting particles with the charge Z=±1 has been performed in the mass range from 1.0 to 1.8 GeV/c 2 . Secondary positive and negative particles with mean transverse momentum of 3 GeV/c produced in the collision of 70 GeV protons with the lead target have been investigated. Upper limits for invariant differential production cross-sections of anomalously interacting particles (1.8x10 -33 -9.5x10 -32 cm 2 xGeV -2 ) per lead nucleus have been obtained at the 90 % considence level