Study of residue type defect formation mechanism and the effect of advanced defect reduction (ADR) rinse process

Science.gov (United States)

Arima, Hiroshi; Yoshida, Yuichi; Yoshihara, Kosuke; Shibata, Tsuyoshi; Kushida, Yuki; Nakagawa, Hiroki; Nishimura, Yukio; Yamaguchi, Yoshikazu

2009-03-01

Residue type defect is one of yield detractors in lithography process. It is known that occurrence of the residue type defect is dependent on resist development process and the defect is reduced by optimized rinsing condition. However, the defect formation is affected by resist materials and substrate conditions. Therefore, it is necessary to optimize the development process condition by each mask level. Those optimization steps require a large amount of time and effort. The formation mechanism is investigated from viewpoint of both material and process. The defect formation is affected by resist material types, substrate condition and development process condition (D.I.W. rinse step). Optimized resist formulation and new rinse technology significantly reduce the residue type defect.

Thermodynamics and kinetics of vesicles formation processes.

Science.gov (United States)

Guida, Vincenzo

2010-12-15

Vesicles are hollow aggregates, composed of bilayers of amphiphilic molecules, dispersed into and filled with a liquid solvent. These aggregates can be formed either as equilibrium or as out of equilibrium meta-stable structures and they exhibit a rich variety of different morphologies. The surprising richness of structures, the vast range of industrial applications and the presence of vesicles in a number of biological systems have attracted the interest of numerous researchers and scientists. In this article, we review both the thermodynamics and the kinetics aspects of the phenomena of formation of vesicles. We start presenting the thermodynamics of bilayer membranes formation and deformation, with the aim of deriving the conditions for the existence of equilibrium vesicles. Specifically, we use the results from continuum thermodynamics to discuss the possibility of formation of stable equilibrium vesicles, from both mixed amphiphiles and single component systems. We also link the bilayer membrane properties to the molecular structure of the starting amphiphiles. In the second part of this article, we focus on the dynamics and kinetics of vesiculation. We review the process of vesicles formation both from planar lamellar phase under shear and from isotropic micelles. In order to clarify the physical mechanisms of vesicles formation, we continuously draw a parallel between emulsification and vesiculation processes. Specifically, we compare the experimental results, the driving forces and the relative scaling laws identified for the two processes. Describing the dynamics of vesicles formation, we also discuss why non equilibrium vesicles can be formed by kinetics control and why they are meta-stable. Understanding how to control the properties, the stability and the formation process of vesicles is of fundamental importance for a vast number of industrial applications. Copyright © 2009. Published by Elsevier B.V.

[The ethic dimension of daily tasks in the formation process of nurses].

Science.gov (United States)

Fernandes, Josicélia Dumêt; Rosa, Darci de Oliveira Santa; Vieira, Therezinha Teixeira; Sadigursky, Dora

2008-06-01

This theoretical article had as its object of study the ethic dimension of the formation process of nurses taking in consideration the National Curricular Directives for Nursing Courses. It was based on the presuppositions of ethics and their relationship with the implementation of changes in the formation process of nurses, using as reference elements of ethical behavior in the formation and attempting to bring the reflection to current times and thus contribute to define a direction to Nursing education. It was concluded that the ethical dimension in the formation of nurses involves values that permeate the relations between the subjects of this process and nature itself. The study points out the need to transform the practices of students and teachers and change the current curriculum framework, highlighting elements that indicate that the concern with ethics when developing the curriculum framework is not limited to how a discipline is taught, but pass through as practices that take place in the education process.

Destruction and formation of organic micropollutants in incineration process

International Nuclear Information System (INIS)

Mascolo, G.; Bagnuolo, G.; Lotito, V.; Spinosa, L.; Mininni, G.

2001-01-01

In this paper are presented the results obtained from a lab-scale investigation carried out with a system for Thermal Diagnostic Studies (STDS) aimed to study the effect of some process variables during incineration. The study has been focused on (I) gas phase dioxins formation during precursors thermal degradation, (II) thermal degradation of toxic organic compounds, (III) products of incomplete combustion (PICs) formation during thermal degradation of urban sludge spiked with toxic organics, (IV) PICs formation during process failure modes, (V) polynuclear aromatic hydrocarbons (PAHs) formation during urban sludge thermal degradation and (VI) influence of conditioning polymer on PICs emission during sludge incineration. The study about gas phase dioxins formation during precursors thermal degradation has been carried out with 2, 4, 6-trichloro- and 2, 4, 6 -tribromo-phenol that were thermal degraded at temperatures between 300 and 800 0 C in an air atmosphere. Both phenols showed the formation of the same tetra-halo-dioxin isomers that were further degraded at higher temperature. Furthermore, chlorine-containing dioxins showed higher thermal stability than bromine-containing dioxins. The study about thermal degradation of toxic organic compounds has been carried out with chlorobenzene, tetrachloroethylene and toluene that were thermal degraded at temperatures between 300 and 1000 0 C in an inert as well as air atmosphere. Results show that in all experimental conditions tetrachloroethylene and toluene are the most and less thermal stable compounds respectively. Also, all compounds are more thermal resistant during pyrolytic experiments and less thermal resistant when they are treated as a whole mixture. The study about PICs formation during thermal degradation of urban sludge spiked with toxic organics has been carried out by thermally degrading urban sludge alone or spiked with the above reported three organics at different conditions of temperature and oxygen

THE FEATURES OF PROCESSES OF SKILLS (SPECIAL COMPETENCIES FORMATION

Directory of Open Access Journals (Sweden)

A. N. Pechnikov

2018-01-01

Full Text Available Introduction. The present article continues a series of the authors’ publications devoted to key problems of a modern educational process organization and ensuring its efficiency. A starting point of the latest investigation stage has been a gap between the available models of formation and diagnostics of special competencies and the tasks for predicting a degree of success of development student’s skills in order to take adequate decisions on managing the process.The aim of the article is justification of a new methodological approach to formation of skills (special competencies of students.Methodology and research methods. The methods of analysis and synthesis; fundamental principles of didactics, qualimetry, the efficiency theory and the decision-making theory were used.Results and scientific novelty. The theoretical bases of evaluation procedures of pupils’ skills created during training are stated. Reference points for the choice of learning process characteristics are designated; by following those characteristics it is possible to provide better development of skills. The tasks of analysis of the studied problem, information acquisition and modeling of the “situation mechanism” of special competencies formation are considered. It is proved that for educational process management optimization it is necessary to evaluate not only its result, but also its quality process, as well its quality system that provides the organization process. The combination of factors to exert the dominating influence over educational process effectiveness are singled out: a type of the applied pedagogical influence; a type of the realized didactic system; a set of personal trainee characteristics which include levels of his/her educational motivation, learning ability, creativity and enables to model and predict training results. It is shown that each of possible combinations of the leading factors represents separate version of a solution to the

Development of simulator for studying formation process of crustal structure. 1; Chikaku kozo keisei simulator no kaihatsu. 1

Energy Technology Data Exchange (ETDEWEB)

Matsushima, J. [The University of Tokyo, Tokyo (Japan). Faculty of Engineering; Murakami, Y.; Okubo, Y.; Matsubayashi, O.; Tanaka, A.; Nakajima, Y.; Morijiri, R. [Geological Survey of Japan, Tsukuba (Japan); Rokugawa, S. [The University of Tokyo, Tokyo (Japan)

1997-05-27

The purpose of this study is to combine seismic activity and volcanic activity by reproducing the formation process of the crustal structure from a physical viewpoint or developing as its extension a numerical simulator which can predict the future. The phenomenon to which attention is especially paid at present is a relation between the dynamic process and the thermal process in the domain including the crust or the upper mantle. Namely, to elucidate the formation process of the crust structure, diastrophism also including seismic activity, igneous activity, etc., it is important to evaluate effects of the behavior of heat supplied from the deep on the dynamic process. In the finite element method, it is not easy to make the effect of gravity reflect to the calculation for boundary conditions. Accordingly, it is general to pay attention to stress difference, considering that stress by gravity is in proportion to static rock pressure stress. Further, to realize interaction between the thermal process and the dynamic process, effects of thermal stress are expressed combining the heat conducting analysis and the plastic flow analysis. 3 refs., 7 figs.

Evaluating evaluation as a communication process. What role for formative evaluation in ICT-based knowledge acquisition?

Directory of Open Access Journals (Sweden)

USEILLE Philippe

2005-10-01

Full Text Available This article examines how formative evaluation as a communication process contributes to knowledge acquisition in using ICT (Information and Communication Technologies. Previous studies, especially in the field of education and training, have shown that formative evaluation plays a crucial part in the learning process because it contributes to learning to learn. Through formative evaluation, the learner becomes aware of errors and can adjust learning strategies to the situation. In addition, formative evaluation provides the teaching side with significant and useful information. Consequently, ICT researches have developed a wide range of solutions for this specific purpose. It is however difficult to check the efficiency of these tools by considering the effects of ICT in the knowledge acquisition process. I suggest that formative evaluation includes also a communication system that has an effect on the learning process. This study tackles the issue by proposing an alternative approach to formative evaluation that considers it as both a learning and a communication process. The study is based on SADT (Structure Analysis and Design Technique that provides a suitable description for the whole complex communication process. It allows a rigorous understanding and identification of the variables of evaluation as a communication process in order to take care of an ICT frame. Finally, this article outlines a multidisciplinary method to evaluate formative evaluation by focusing on the validity facets of the communication process. Keywords: formative evaluation, communication process, validity criteria, ICT training context.

TRACKING THE PROCESSES OF MELANODIN FORMATION IN COFFEE

Directory of Open Access Journals (Sweden)

Snezhana Ivanova

2017-06-01

Full Text Available Melanoidins are high molecular brown colored substances and products of sugar-amine reaction of Maillard. They are formed during roasting a green coffee beans under different thermal regimes of heat treatment. In the technological production of different types coffee beverages, the coffee powder is subjected to after-heat treatment. In these additional operations again become active processes of melanoidin formation and their changing their structures. This is changes of the Melanoidins have different effects on human health. It is therefore important to know their chemical structures and changes. Previous studies have shown that polysaccharides, proteins and chlorogenic acids are included in the formation of these melanoidins. However, the precise structures of coffee melanoidins and mechanisms involved in the formation are not yet clarified. This article systematize available information and provides an overview of research obtained so far on the structure of coffee melanoidins and mechanisms of their formation and potential health effects.

New Particle Formation Study Final Campaign Report

Energy Technology Data Exchange (ETDEWEB)

Smith, JN; McMurry, PH [University of Minnesota

2015-01-01

The scientific foci of the New Particle Formation Study were the formation and evolution of atmospheric aerosols and the impacts of newly formed particles on cloud processes. Specifically, we planned to: (1) to identify the species and mechanisms responsible for the initial steps of new particle formation, i.e., the formation of thermodynamically stable clusters; (2) investigate the role of acid-base chemistry in new particle growth through measurements of ammonia and amines as well as organic and inorganic acids in both atmospheric nanoparticles and the gas phase; (3) investigate the contribution of other surface area or volume-controlled processes to nanoparticle formation and growth; (4) create a comprehensive dataset related to new particle formation and growth that can be used as input for our own thermodynamic models as well as the modeling efforts by our Department of Energy (DOE) Aerosol Life Cycle working group collaborators; (5) characterize the increase of the number and activity of cloud condensation nuclei (CCN) due to particle formation and growth; (6) determine the regional extent of new particle formation to address the role that atmospheric transport plays in determining the impacts, if any, of new particle formation on cloud number and properties.

Process Approach to Formation of the Strategy of Innovation Development of Enterprises

Directory of Open Access Journals (Sweden)

Yukhymenko Vita V.

2013-12-01

Full Text Available The article considers the process of formation of the strategy of innovation development on the basis of the process approach. The author studies and identifies the most significant cause-effect interrelations between the factors that influence efficiency of the process of formation of the strategy of innovation development of enterprises and their consequences. The article offers a process approach to building the K. Ishikawa diagram based on empirical assessment of management of business processes at railway engineering enterprises. The author’s approach would help solving multiple problems of railway engineering and also could be used in other sectors of economy.

On the ENDF Formats and Data Processing

International Nuclear Information System (INIS)

Trkov, Andrej

2012-01-01

The ENDF formats have served the community of nuclear data users from different fields of applications quite well for decades. Enormous effort has been devoted to the development and validation of the processing codes. Although there is no urgent need for a rapid transition to something completely new, there are signs that the current ENDF format is being pushed close to its limits. The time is right to look for a modern replacement, with due consideration for the following: - Development of data processing capabilities, starting from the data in the new format. - Backward compatibility through robust translation codes between the new and the old format until the majority of processing tools have been adequately validated. - Standardisation of the format features on the international level to maintain the possibility of easy data comparison and exchange. The NJOY Data Processing System is the most versatile and widely used code system for generating application libraries. The AMPX system is mainly used for generating libraries for codes from Oak Ridge. The Pre-Pro codes are found to be very robust, but their main purpose is data verification, validation and display. These codes do a good job for the present scope of applications, but current trend rely heavily on Monte Carlo simulations and sensitivity/uncertainty calculations. Further developments in the data processing tools should reflect these trends, focusing on the following: - Further verification and validation of covariance processing methods. - Development of a common tool for generating a global covariance matrix of nuclear data, including all available cross-reaction and cross-material correlations. - Consider if we can move away from histogram covariance representation into a piecewise linear domain. - Having a 'global' covariance matrix (that can include the covariance matrix of the resonance parameters), pursue the development of a common tool for statistical sampling of the cross sections and other

Real-time nonlinear feedback control of pattern formation in (bio)chemical reaction-diffusion processes: a model study.

Science.gov (United States)

Brandt-Pollmann, U; Lebiedz, D; Diehl, M; Sager, S; Schlöder, J

2005-09-01

Theoretical and experimental studies related to manipulation of pattern formation in self-organizing reaction-diffusion processes by appropriate control stimuli become increasingly important both in chemical engineering and cellular biochemistry. In a model study, we demonstrate here exemplarily the application of an efficient nonlinear model predictive control (NMPC) algorithm to real-time optimal feedback control of pattern formation in a bacterial chemotaxis system modeled by nonlinear partial differential equations. The corresponding drift-diffusion model type is representative for many (bio)chemical systems involving nonlinear reaction dynamics and nonlinear diffusion. We show how the computed optimal feedback control strategy exploits the system inherent physical property of wave propagation to achieve desired control aims. We discuss various applications of our approach to optimal control of spatiotemporal dynamics.

Processes Leading to Beaded Channels Formation in Central Yakutia

Science.gov (United States)

Tarbeeva, A. M.; Lebedeva, L.; Efremov, V. S.; Krylenko, I. V.; Surkov, V. V.

2017-12-01

Beaded channels, consisting of deepened and widened pools and connecting narrow runs, are common fluvial forms in permafrost regions. Recent studies have shown that beaded channels are very important for connecting alluvial rivers with headwater lakes allowing fish passage and foraging habitats, as well as regulating river runoff. Beaded channels are known as typical thermokarst landforms; however, there is no evidence of their origin and formative processes. Geomorphological analyzes of beaded channels have been completed in several permafrost regions including field observations of Shestakovka River in Central Yakutia. The study aims to recognize the modern exogenic processes and formative mechanisms of beaded river channels. We show that beaded channel of Shestakovka River form in the perennially frozen sand with low ice content, leading us to hypothesize that thermokarst is not the main process of formation. Due to the significant volume of water, the pools don't freeze over entirely during winters, even under harsh climatic conditions. As a result, lenses of pressurized water remain under surface ice underlain by perennially thawed sediments. The presence of thawed sediments under the pools and frozen sediments under the runs leads to uneven thermoerosion of the riverbed during floods, providing the beaded form of the channel. In addition, freezing of pools during winter leads to pressure increasing under ice cover and formation of ice mounds, which crack several times during winter leading to disturbance of riverbanks. Many 1st to 3rd order streams have a specific transitional meandering-to-beaded form resembling the shape of unconfined meandering rivers, but consisting of pools and runs. However, such channels exhibit no evidences of present-day erosion of concave banks and sediment accumulation at the convex banks as typically being observed in normally meandering rivers. Such forms of channels indicates that their formation occurred by the greater channel

Satisfaction Formation Processes in Library Users: Understanding Multisource Effects

Science.gov (United States)

Shi, Xi; Holahan, Patricia J.; Jurkat, M. Peter

2004-01-01

This study explores whether disconfirmation theory can explain satisfaction formation processes in library users. Both library users' needs and expectations are investigated as disconfirmation standards. Overall library user satisfaction is predicted to be a function of two independent sources--satisfaction with the information product received…

Laboratory Studies Of Circumstellar Carbonaceous Grain Formation

Science.gov (United States)

Contreras, Cesar; Sciamma-O'Brien, Ella; Salama, Farid

2014-06-01

The study of the formation processes of dust is essential to understand the budget of extraterrestrial organic molecules. Although dust with all its components plays an important role in the evolution of interstellar (IS) chemistry and in the formation of organic molecules, little is known on the formation processes of carbonaceous dust. We report the progress that was recently achieved in this domain using NASA Ames’ COSmIC facility (Contreras & Salama 2013, ApJS, 208, 6). PAHs are important chemical building blocks of IS dust. They are detected in IDPs and in meteoritic samples. Additionally, observational, laboratory, and theoretical studies have shown that PAHs are an important, ubiquitous component of the ISM. The formation of PAHs from smaller molecules has not been extensively studied. Therefore, we have performed laboratory experiments to study the dynamic processes of carbon grain formation, starting from the smallest hydrocarbon molecules into the formation of larger PAH and further into nanograins. Studies of IS dust analogs formed from a variety of PAH and hydrocarbon precursors as well as species that include the atoms O, N, and S, have recently been performed in our laboratory using the COSmIC facility to provide conditions that simulate IS and circumstellar environments. The species formed in the COSmiC chamber through a pulsed discharge nozzle plasma source are detected and characterized with a cavity ringdown spectrometer coupled to a time-of-flight mass spectrometer, thus providing both spectroscopic and ion mass information in-situ. Analysis of solid soot particles was also conducted using scanning electron microscopy at the UCSC/NASA Ames’ MACS facility. The SEM analysis of the deposition of soot from methane and acetylene precursors seeded in argon plasmas provide examples on the types of nanoparticles and micrograins that are produced in these gas mixtures under our experimental conditions. From these measurements, we derive information on

Microemulsions and Aggregation Formation in Extraction Processes for Used Nuclear Fuel: Thermodynamic and Structural Studies

International Nuclear Information System (INIS)

Nilsson, Mikael

2016-01-01

Advanced nuclear fuel cycles rely on successful chemical separation of various elements in the used fuel. Numerous solvent extraction (SX) processes have been developed for the recovery and purification of metal ions from this used material. However, the predictability of process operations has been challenged by the lack of a fundamental understanding of the chemical interactions in several of these separation systems. For example, gaps in the thermodynamic description of the mechanism and the complexes formed will make predictions very challenging. Recent studies of certain extraction systems under development and a number of more established SX processes have suggested that aggregate formation in the organic phase results in a transformation of its selectivity and efficiency. Aggregation phenomena have consistently been interfering in SX process development, and have, over the years, become synonymous with an undesirable effect that must be prevented. This multiyear, multicollaborative research effort was carried out to study solvation and self-organization in non-aqueous solutions at conditions promoting aggregation phenomena. Our approach to this challenging topic was to investigate extraction systems comprising more than one extraction reagent where synergy of the metal ion could be observed. These systems were probed for the existence of stable microemulsions in the organic phase, and a number of high-end characterization tools were employed to elucidate the role of the aggregates in metal ion extraction. The ultimate goal was to find connections between synergy of metal ion extraction and reverse micellar formation. Our main accomplishment for this project was the expansion of the understanding of metal ion complexation in the extraction system combining tributyl phosphate (TBP) and dibutyl phosphoric acid (HDBP). We have found that for this system no direct correlation exists for the metal ion extraction and the formation of aggregates, meaning that the

Microemulsions and Aggregation Formation in Extraction Processes for Used Nuclear Fuel: Thermodynamic and Structural Studies

Energy Technology Data Exchange (ETDEWEB)

Nilsson, Mikael [Univ. of California, Irvine, CA (United States)

2016-05-04

Advanced nuclear fuel cycles rely on successful chemical separation of various elements in the used fuel. Numerous solvent extraction (SX) processes have been developed for the recovery and purification of metal ions from this used material. However, the predictability of process operations has been challenged by the lack of a fundamental understanding of the chemical interactions in several of these separation systems. For example, gaps in the thermodynamic description of the mechanism and the complexes formed will make predictions very challenging. Recent studies of certain extraction systems under development and a number of more established SX processes have suggested that aggregate formation in the organic phase results in a transformation of its selectivity and efficiency. Aggregation phenomena have consistently been interfering in SX process development, and have, over the years, become synonymous with an undesirable effect that must be prevented. This multiyear, multicollaborative research effort was carried out to study solvation and self-organization in non-aqueous solutions at conditions promoting aggregation phenomena. Our approach to this challenging topic was to investigate extraction systems comprising more than one extraction reagent where synergy of the metal ion could be observed. These systems were probed for the existence of stable microemulsions in the organic phase, and a number of high-end characterization tools were employed to elucidate the role of the aggregates in metal ion extraction. The ultimate goal was to find connections between synergy of metal ion extraction and reverse micellar formation. Our main accomplishment for this project was the expansion of the understanding of metal ion complexation in the extraction system combining tributyl phosphate (TBP) and dibutyl phosphoric acid (HDBP). We have found that for this system no direct correlation exists for the metal ion extraction and the formation of aggregates, meaning that the

Cloud processing of organic compounds: Secondary organic aerosol and nitrosamine formation

Science.gov (United States)

Hutchings, James W., III

Cloud processing of atmospheric organic compounds has been investigated through field studies, laboratory experiments, and numerical modeling. Observational cloud chemistry studies were performed in northern Arizona and fog studies in central Pennsylvania. At both locations, the cloud and fogs showed low acidity due to neutralization by soil dust components (Arizona) and ammonia (Pennsylvania). The field observations showed substantial concentrations (20-5500 ng•L -1) of volatile organic compounds (VOC) in the cloud droplets. The potential generation of secondary organic aerosol mass through the processing of these anthropogenic VOCs was investigated through laboratory and modeling studies. Under simulated atmospheric conditions, in idealized solutions, benzene, toluene, ethylbenzene, and xylene (BTEX) degraded quickly in the aqueous phase with half lives of approximately three hours. The degradation process yielded less volatile products which would contribute to new aerosol mass upon cloud evaporation. However, when realistic cloud solutions containing natural organic matter were used in the experiments, the reaction kinetics decreased with increasing organic carbon content, resulting in half lives of approximately 7 hours. The secondary organic aerosol (SUA) mass formation potential of cloud processing of BTEX was evaluated. SOA mass formation by cloud processing of BTEX, while strongly dependent on the atmospheric conditions, could contribute up to 9% of the ambient atmospheric aerosol mass, although typically ˜1% appears realistic. Field observations also showed the occurrence of N-nitrosodimethylamine (NDMA), a potent carcinogen, in fogs and clouds (100-340 ng•L -1). Laboratory studies were conducted to investigate the formation of NDMA from nitrous acid and dimethylamine in the homogeneous aqueous phase within cloud droplets. While NDMA was produced in the cloud droplets, the low yields (NDMA with partitioning to droplet must be the source of aqueous

Utilizing Stable Isotopes and Isotopic Anomalies to Study Early Solar System Formation Processes

Science.gov (United States)

Simon, Justin

2017-01-01

Chondritic meteorites contain a diversity of particle components, i.e., chondrules and calcium-, aluminum-rich refractory inclusions (CAIs), that have survived since the formation of the Solar System. The chemical and isotopic compositions of these materials provide a record of the conditions present in the protoplanetary disk where they formed and can aid our understanding of the processes and reservoirs in which solids formed in the solar nebula, an important step leading to the accretion of planetesimals. Isotopic anomalies associated with nucleosynthetic processes are observed in these discrete materials, and can be compared to astronomical observations and astrophysical formation models of stars and more recently proplyds. The existence and size of these isotopic anomalies are typically thought to reflect a significant state of isotopic heterogeneity in the earliest Solar System, likely left over from molecular cloud heterogeneities on the grain scale, but some could also be due to late stellar injection. The homogenization of these isotopic anomalies towards planetary values can be used to track the efficiency and timescales of disk wide mixing,

Energy consumption estimation for greenhouse gas separation processes by clathrate hydrate formation

International Nuclear Information System (INIS)

Tajima, Hideo; Yamasaki, Akihiro; Kiyono, Fumio

2004-01-01

The process energy consumption was estimated for gas separation processes by the formation of clathrate hydrates. The separation process is based on the equilibrium partition of the components between the gaseous phase and the hydrate phase. The separation and capturing processes of greenhouse gases were examined in this study. The target components were hydrofluorocarbon (HFC-134a) from air, sulfur hexafluoride (SF 6 ) from nitrogen, and CO 2 from flue gas. Since these greenhouse gases would form hydrates under much lower pressure and higher temperature conditions than the accompanying components, the effective capturing of the greenhouse gases could be achieved by using hydrate formation. A model separation process for each gaseous mixture was designed from the basis of thermodynamics, and the process energy consumption was estimated. The obtained results were then compared with those for conventional separation processes such as liquefaction separation processes. For the recovery of SF 6 , the hydrate process is preferable to liquefaction process in terms of energy consumption. On the other hand, the liquefaction process consumes less energy than the hydrate process for the recovery of HFC-134a. The capturing of CO 2 by the hydrate process from a flue gas will consume a considerable amount of energy; mainly due to the extremely high pressure conditions required for hydrate formation. The influences of the operation conditions on the heat of hydrate formation were elucidated by sensitivity analysis. The hydrate processes for separating these greenhouse gases were evaluated in terms of reduction of global warming potential (GWP)

A linear process-algebraic format for probabilistic systems with data

NARCIS (Netherlands)

Katoen, Joost P.; van de Pol, Jan Cornelis; Stoelinga, Mariëlle Ida Antoinette; Timmer, Mark; Gomes, L.; Khomenko, V.; Fernandes, J.M.

This paper presents a novel linear process algebraic format for probabilistic automata. The key ingredient is a symbolic transformation of probabilistic process algebra terms that incorporate data into this linear format while preserving strong probabilistic bisimulation. This generalises similar

Fast processing of digital imaging and communications in medicine (DICOM) metadata using multiseries DICOM format.

Science.gov (United States)

Ismail, Mahmoud; Philbin, James

2015-04-01

The digital imaging and communications in medicine (DICOM) information model combines pixel data and its metadata in a single object. There are user scenarios that only need metadata manipulation, such as deidentification and study migration. Most picture archiving and communication system use a database to store and update the metadata rather than updating the raw DICOM files themselves. The multiseries DICOM (MSD) format separates metadata from pixel data and eliminates duplicate attributes. This work promotes storing DICOM studies in MSD format to reduce the metadata processing time. A set of experiments are performed that update the metadata of a set of DICOM studies for deidentification and migration. The studies are stored in both the traditional single frame DICOM (SFD) format and the MSD format. The results show that it is faster to update studies' metadata in MSD format than in SFD format because the bulk data is separated in MSD and is not retrieved from the storage system. In addition, it is space efficient to store the deidentified studies in MSD format as it shares the same bulk data object with the original study. In summary, separation of metadata from pixel data using the MSD format provides fast metadata access and speeds up applications that process only the metadata.

Moessbauer study on the formation process of Fe-K composition in iron-based catalyst for dehydrogenation of ethylbenzene

International Nuclear Information System (INIS)

Jiang Keyu; Zhao Zhenjie; Yang Xielong

2001-01-01

Fe-K spinel structure is the predecessor of active phase of potassium promoted iron-based catalyst for dehydrogenation of ethylbenzene. Moessbauer spectroscopy has been used to study the formation process of Fe-K spinel structure which depends on the catalyst composition and preparing condition. The results may prove useful for production of industrial catalyst

Simulating the formation of keratin filament networks by a piecewise-deterministic Markov process.

Science.gov (United States)

Beil, Michael; Lück, Sebastian; Fleischer, Frank; Portet, Stéphanie; Arendt, Wolfgang; Schmidt, Volker

2009-02-21

Keratin intermediate filament networks are part of the cytoskeleton in epithelial cells. They were found to regulate viscoelastic properties and motility of cancer cells. Due to unique biochemical properties of keratin polymers, the knowledge of the mechanisms controlling keratin network formation is incomplete. A combination of deterministic and stochastic modeling techniques can be a valuable source of information since they can describe known mechanisms of network evolution while reflecting the uncertainty with respect to a variety of molecular events. We applied the concept of piecewise-deterministic Markov processes to the modeling of keratin network formation with high spatiotemporal resolution. The deterministic component describes the diffusion-driven evolution of a pool of soluble keratin filament precursors fueling various network formation processes. Instants of network formation events are determined by a stochastic point process on the time axis. A probability distribution controlled by model parameters exercises control over the frequency of different mechanisms of network formation to be triggered. Locations of the network formation events are assigned dependent on the spatial distribution of the soluble pool of filament precursors. Based on this modeling approach, simulation studies revealed that the architecture of keratin networks mostly depends on the balance between filament elongation and branching processes. The spatial distribution of network mesh size, which strongly influences the mechanical characteristics of filament networks, is modulated by lateral annealing processes. This mechanism which is a specific feature of intermediate filament networks appears to be a major and fast regulator of cell mechanics.

Study on Formation Mechanism of Fayalite (Fe2SiO4) by Solid State Reaction in Sintering Process

Science.gov (United States)

Wang, Zhongbing; Peng, Bing; Zhang, Lifeng; Zhao, Zongwen; Liu, Degang; Peng, Ning; Wang, Dawei; He, Yinghe; Liang, Yanjie; Liu, Hui

2018-04-01

The sintering behaviors among SiO2, FeS and Fe3O4 were detected to reveal the formation mechanism of Fe2SiO4. The results indicated that the formation mechanism is divided into five steps: (1) migration of O2- induced by S2- under a reducing atmosphere; (2) formation of Fe3O4- β ; (3) migration of Fe(II) into a ferrite cluster structure to gain oxygen and form Fe3- x O4; (4) Fe(II) invaded the silicon atomic position and released Si(IV); and (5) formation of the stable structure of Fe2SiO4 through chemical diffusion between cations of Fe(II) and Si(IV). These findings can provide theoretical support for controlling the process of the recovery of valuable metals in copper slag through the combined roasting modification-magnetic separation process.

Study of the sintering process and the formation of a (Th, U) O2 solid solution

International Nuclear Information System (INIS)

Tomasi, Roberto

1979-01-01

The effect of some variables in the (Th, U) O 2 sintering process and solid solution formation was studied. ThO 2 , U 3 O 8 and UO 2 powder were prepared. The ThO 2 powders were obtained by calcination of thorium at 500 and 750 deg C; the U 3 O 8 powders were derived from the calcination of ADU at 660 and 750 deg C; the UO 2 powder were prepared from ADU and from ATCU. The different characteristics of these materials were determined by measurements of surface area, by scanning electron microscopy, tap density tests, X-ray diffractometry and by measurements of the O/U ratios. The oxide mixtures were chosen in order to produce a final composition with 10 w/o of UO 2 . A mixture of thorium oxalate and ADU was also prepared by calcining these salts in air at 700 deg C, in order to obtain certain amount of solid solution prior to sintering. The sintering operations were developed in an argon atmosphere at temperatures between 1400 and 1700 deg C, during interval varying from 1 to 4 hours. The effect of the mixture characteristics on the sintering process and solid solution formation were studied considering the results of densification, microstructure development and X-ray diffractometry. The ThO 2 powder characteristics have a main effect on the mixtures compactability and sinterability, the higher calcining temperatures increasing the green density, but decreasing the final density of the sintered pellets. In the sintering of mixtures containing U 3 O 3 , this oxide is reduced to UO 2 and it is possible to obtain pellets with density and microstructures similar to those produced from mixtures containing UO 2 . But if oxygen in excess is present during sintering, the process is affected, occurring exaggerated grain growth. The densification results were related to the Coble's kinetics equation for second stage of sintering, valid for bulk diffusion, grain boundary acting as vacancy sinks. The sintering activation energy is independent from the powder starting

Dual-process theory and consumer response to front-of-package nutrition label formats.

Science.gov (United States)

Sanjari, S Setareh; Jahn, Steffen; Boztug, Yasemin

2017-11-01

Nutrition labeling literature yields fragmented results about the effect of front-of-package (FOP) nutrition label formats on healthy food choice. Specifically, it is unclear which type of nutrition label format is effective across different shopping situations. To address this gap, the present review investigates the available nutrition labeling literature through the prism of dual-process theory, which posits that decisions are made either quickly and automatically (system 1) or slowly and deliberately (system 2). A systematically performed review of nutrition labeling literature returned 59 papers that provide findings that can be explained according to dual-process theory. The findings of these studies suggest that the effectiveness of nutrition label formats is influenced by the consumer's dominant processing system, which is a function of specific contexts and personal variables (eg, motivation, nutrition knowledge, time pressure, and depletion). Examination of reported findings through a situational processing perspective reveals that consumers might prefer different FOP nutrition label formats in different situations and can exhibit varying responses to the same label format across situations. This review offers several suggestions for policy makers and researchers to help improve current FOP nutrition label formats. © The Author(s) 2017. Published by Oxford University Press on behalf of the International Life Sciences Institute. All rights reserved. For Permissions, please e-mail: journals.permissions@oup.com.

Structural modification of silicon during the formation process of porous silicon

International Nuclear Information System (INIS)

Martin-Palma, R.J.; Pascual, L.; Landa-Canovas, A.R.; Herrero, P.; Martinez-Duart, J.M.

2005-01-01

Direct examination of porous silicon (PS) by the use of high resolution transmission electron microscopy (HRTEM) allowed us to perform a deep insight into the formation mechanisms of this material. In particular, the structure of the PS/Si interface and that of the silicon nanocrystals that compose porous silicon were analyzed in detail. Furthermore, image processing was used to study in detail the structure of PS. The mechanism of PS formation and lattice matching between the PS layer and the Si substrate is analyzed and discussed. Finally, a formation mechanism for PS based on the experimental observations is proposed

Membrane formation : diffusion induced demixing processes in ternary polymeric systems

NARCIS (Netherlands)

Reuvers, Albertus Johannes

1987-01-01

In this thesis the mechanism of membrane formation by means of immersion precipitation is studied. Immersion of a concentrated polymer solution film into a nonsolvent bath induces an exchange of solvent and nonsolvent in the film by means of diffusion. This process results in an asymmetric polymer

Hydrothermally processed 1D hydroxyapatite: Mechanism of formation and biocompatibility studies

Energy Technology Data Exchange (ETDEWEB)

Stojanović, Zoran S.; Ignjatović, Nenad [Centre for Fine Particles Processing and Nanotechnologies, Institute of Technical Sciences of the Serbian Academy of Sciences and Arts, Knez Mihailova 35/4, 11000 Belgrade (Serbia); Wu, Victoria [Advanced Materials and Nanobiotechnology Laboratory, Department of Bioengineering, University of Illinois, 851 South Morgan Street, Chicago, IL 60607-7052 (United States); Žunič, Vojka [Advanced Materials Department, Jožef Stefan Institute, Jamova cesta 39, 1000 Ljubljana (Slovenia); Veselinović, Ljiljana [Centre for Fine Particles Processing and Nanotechnologies, Institute of Technical Sciences of the Serbian Academy of Sciences and Arts, Knez Mihailova 35/4, 11000 Belgrade (Serbia); Škapin, Srečo [Advanced Materials Department, Jožef Stefan Institute, Jamova cesta 39, 1000 Ljubljana (Slovenia); Miljković, Miroslav [Laboratory for Electron Microscopy, Faculty of Medicine University of Niš, Dr. Zoran Đinđić Boulevard 81, 18 000 Niš (Serbia); Uskoković, Vuk [Advanced Materials and Nanobiotechnology Laboratory, Department of Bioengineering, University of Illinois, 851 South Morgan Street, Chicago, IL 60607-7052 (United States); Department of Biomedical and Pharmaceutical Sciences, School of Pharmacy, Chapman University, 9401 Jeronimo Road, Irvine, CA 92618-1908 (United States); and others

2016-11-01

Recent developments in bone tissue engineering have led to an increased interest in one-dimensional (1D) hydroxyapatite (HA) nano- and micro-structures such as wires, ribbons and tubes. They have been proposed for use as cell substrates, reinforcing phases in composites and carriers for biologically active substances. Here we demonstrate the synthesis of 1D HA structures using an optimized, urea-assisted, high-yield hydrothermal batch process. The one-pot process, yielding HA structures composed of bundles of ribbons and wires, was typified by the simultaneous occurrence of a multitude of intermediate reactions, failing to meet the uniformity criteria over particle morphology and size. To overcome these issues, the preparation procedure was divided to two stages: dicalcium phosphate platelets synthesized in the first step were used as a precursor for the synthesis of 1D HA in the second stage. Despite the elongated particle morphologies, both the precursor and the final product exhibited excellent biocompatibility and caused no reduction of viability when tested against osteoblastic MC3T3-E1 cells in 2D culture up to the concentration of 2.6 mg/cm{sup 2}. X-ray powder diffraction combined with a range of electron microscopies and laser diffraction analyses was used to elucidate the formation mechanism and the microstructure of the final particles. The two-step synthesis involved a more direct transformation of DCP to 1D HA with the average diameter of 37 nm and the aspect ratio exceeding 100:1. The comparison of crystalline domain sizes along different crystallographic directions showed no signs of significant anisotropy, while indicating that individual nanowires are ordered in bundles in the b crystallographic direction of the P6{sub 3/m} space group of HA. Intermediate processes, e.g., dehydration of dicalcium phosphate, are critical for the formation of 1D HA alongside other key aspects of this phase transformation, it must be investigated in more detail in the

Fuzzy social choice models explaining the government formation process

CERN Document Server

C Casey, Peter; A Goodman, Carly; Pook, Kelly Nelson; N Mordeson, John; J Wierman, Mark; D Clark, Terry

2014-01-01

This book explores the extent to which fuzzy set logic can overcome some of the shortcomings of public choice theory, particularly its inability to provide adequate predictive power in empirical studies. Especially in the case of social preferences, public choice theory has failed to produce the set of alternatives from which collective choices are made.  The book presents empirical findings achieved by the authors in their efforts to predict the outcome of government formation processes in European parliamentary and semi-presidential systems.  Using data from the Comparative Manifesto Project (CMP), the authors propose a new approach that reinterprets error in the coding of CMP data as ambiguity in the actual political positions of parties on the policy dimensions being coded. The range of this error establishes parties’ fuzzy preferences. The set of possible outcomes in the process of government formation is then calculated on the basis of both the fuzzy Pareto set and the fuzzy maximal set, and the pre...

Emptiness formation probability of XX-chain in diffusion process

International Nuclear Information System (INIS)

Ogata, Yoshiko

2004-01-01

We study the distribution of emptiness formation probability of XX-model in the diffusion process. There exits a Gaussian decay as well as an exponential decay. The Gaussian decay is caused by the existence of zero point in the Fermi distribution function. The correlation length for each point of scaling factor varies up to the initial condition, monotonically or non-monotonically

Comparison of different procedures to stabilize biogas formation after process failure in a thermophilic waste digestion system: Influence of aggregate formation on process stability

International Nuclear Information System (INIS)

Kleyböcker, A.; Liebrich, M.; Kasina, M.; Kraume, M.; Wittmaier, M.; Würdemann, H.

2012-01-01

Highlights: ► Mechanism of process recovery with calcium oxide. ► Formation of insoluble calcium salts with long chain fatty acids and phosphate. ► Adsorption of VFAs by the precipitates resulting in the formation of aggregates. ► Acid uptake and phosphate release by the phosphate-accumulating organisms. ► Microbial degradation of volatile fatty acids in the aggregates. - Abstract: Following a process failure in a full-scale biogas reactor, different counter measures were undertaken to stabilize the process of biogas formation, including the reduction of the organic loading rate, the addition of sodium hydroxide (NaOH), and the introduction of calcium oxide (CaO). Corresponding to the results of the process recovery in the full-scale digester, laboratory experiments showed that CaO was more capable of stabilizing the process than NaOH. While both additives were able to raise the pH to a neutral milieu (pH > 7.0), the formation of aggregates was observed particularly when CaO was used as the additive. Scanning electron microscopy investigations revealed calcium phosphate compounds in the core of the aggregates. Phosphate seemed to be released by phosphorus-accumulating organisms, when volatile fatty acids accumulated. The calcium, which was charged by the CaO addition, formed insoluble salts with long chain fatty acids, and caused the precipitation of calcium phosphate compounds. These aggregates were surrounded by a white layer of carbon rich organic matter, probably consisting of volatile fatty acids. Thus, during the process recovery with CaO, the decrease in the amount of accumulated acids in the liquid phase was likely enabled by (1) the formation of insoluble calcium salts with long chain fatty acids, (2) the adsorption of volatile fatty acids by the precipitates, (3) the acid uptake by phosphorus-accumulating organisms and (4) the degradation of volatile fatty acids in the aggregates. Furthermore, this mechanism enabled a stable process performance

A high yield process for hydrate formation

Energy Technology Data Exchange (ETDEWEB)

Giavarini, C.; Maccioni, F. [Univ. of Roma La Sapienza, Roma (Italy). Dept. of Chemical Engineering

2008-07-01

Due to the large quantities of natural gas stored in deep ocean hydrates, hydrate reservoirs are a substantial energy resource. Hydrates concentrate methane by as much as a factor of 164. As such, several natural gas transportation and storage systems using gas hydrates have been studied, and many of them are nearing practical use. In these systems, the hydrate is produced as a slurry by a spray process at approximately 7 megapascal (MPa), and then shaped into pellets. The use of a spray process, instead of a conventional stirred vessel is necessary in order to reach high hydrate concentrations in the hydrate-ice system. This paper presented a new procedure to produce a bulk of concentrated methane hydrate in a static traditional reactor at moderate pressure, controlling pressure and temperature in the interval between ice melting and the hydrate equilibrium curve. This paper discussed the experimental procedure which included formation of methane hydrate at approximately 5 MPa and 2 degrees Celsius in a reaction calorimeter at a volume of two liters. Results were also discussed. It was concluded that the procedure seemed suitable for the development of a gas hydrate storage and transport technology. It was found that the spray procedure took more time, but could be sped up and made continuous by using two vessels, one for hydrate formation and the other for hydrate concentration. The advantage was the production of a concentrated hydrate, using a simpler equipment and working at lower pressures respect to the spray process. 9 refs., 5 figs.

Uranium in a recent phosphorite formation process

Energy Technology Data Exchange (ETDEWEB)

Baturin, G N; Dubinchuk, V I; Kochenov, A V

1986-01-01

Uranium behaviour in the process of nowadays phosphorite formation in the sediments of Namibia shelf is considered. The material collected during the 3-d trip of the research vessel ''Akademik Kurchatov'' and 26-th trip of the research vessel ''Mikhail Lomonosov'' is used. The samples from three geological stations 2046, 2047 and 2048 from the depths of 78-87 m have been investigated. Each sample (mass from 0.2 to 0.3 kg) is composed of several samples representing unified genetic series: holocene diatomic silts enclosing phosphorites - phosphatized silts - phosphorite concretions. Uranium has been determined by the X-ray spectral method; phosphorus, organic carbon and other components - by the chemical analysis. Uranium forms investigated by the combination of methods of electron microscopy, microdiffraction, microradioautography and microsounding. Uranium content in nowadays phosphorites at the shelf is 3-106 g/t. Uranium accumulation in phosphorites at the initial stages of their formation is controlled by its content in host sediments. In the course of litification of diagenetic phosphate concretions the uranium content in them varies from 40 to 80 g/t. The uranium concentration process in phosphorites is accompanied by formation of independent mineral phases of uranium oxide and ningyoite type.

Polycyclic aromatic hydrocarbons' formation and occurrence in processed food.

Science.gov (United States)

Singh, Lochan; Varshney, Jay G; Agarwal, Tripti

2016-05-15

Polycyclic aromatic hydrocarbons (PAHs) emerged as an important contaminant group in a gamut of processed food groups like dairy, nuts, herbs, beverages, meat products etc. Different cooking processes and processing techniques like roasting, barbecuing, grilling, smoking, heating, drying, baking, ohmic-infrared cooking etc. contribute towards its formation. The level of PAHs depends on factors like distance from heat source, fuel used, level of processing, cooking durations and methods, whereas processes like reuse, conching, concentration, crushing and storage enhance the amount of PAHs in some food items. This review paper provides insight into the impact of dietary intake of PAHs, its levels and formation mechanism in processed food items and possible interventions for prevention and reduction of the PAHs contamination. The gaps and future prospects have also been assessed. Copyright © 2015 Elsevier Ltd. All rights reserved.

A study of liposome formation using a solution (isoperibol) calorimeter.

Science.gov (United States)

Barriocanal, L; Taylor, K M G; Buckton, G

2004-12-09

A solution (isoperibol) calorimeter has been employed to study the process of formation of phospholipid vesicles from natural and synthetic phospholipid films. Phospholipid films were hydrated in the solution calorimeter at temperatures exceeding the main phospholipid phase transition temperature, with continuous agitation to ensure conversion of the hydrating bilayers into multilamellar liposomes. It was seen that retention of chloroform in phospholipid films altered the apparent enthalpy change of vesicle formation to a far greater extent than would be expected from the contribution of the enthalpy of solution of chloroform; this indicates that chloroform alters the hydration process of the lipid. The overall measured enthalpy change for the formation of egg phosphatidylcholine vesicles was exothermic, whilst that for dimyristoylphosphatidylcholine was endothermic. This difference, it is suggested, results from the influence of the hydrocarbon chains mostly on the hydration process and also on the process of vesicle formation.

Effects of pretreatment processes on improving the formation of ultrananocrystalline diamond

International Nuclear Information System (INIS)

Chen, Li-Ju; Tai, Nyan-Hwa; Lee, Chi-Young; Lin, I-Nan.

2007-01-01

Effects of pretreatment on the nuclei formation of ultrananocrystalline diamond (UNCD) on Si substrates were studied. Either precoating a thin layer of titanium (∼400 nm) or ultrasonication pretreatment using diamond and titanium mixed powder (D and T process) enhances the nucleation process on Si substrates markedly, and the UNCD nuclei formed and fully covered the Si substrate, when deposition was processed using the microwave-plasma-enhanced chemical-vapor deposition process for 10 min. In contrast, during the same period, ultrasonication pretreatment using diamond powders (D process) can only form large UNCD clusters, which were scarcely distributed on Si substrates. The analyses using x-ray diffractometer, secondary ion mass spectroscopy, and electron spectroscopy for chemical analysis reveal that the titanium layer reacted with carbon species in the plasma, forming crystalline TiC phase, which facilitates the subsequent formation of UNCD nuclei. The beneficial effect of Ti layer on enhancing the nucleation of UNCD is presumably owing to high solubility and high diffusivity of carbon species in Ti materials, as compared with those of Si materials

Thermal physics of gas-thermal coatings formation processes. State of investigations

International Nuclear Information System (INIS)

Fialko, N.M.; Prokopov, V.G.; Meranova, N.O.; Borisov, Yu.S.; Korzhik, V.N.; Sherenkovskaya, G.P.; AN Ukrainskoj SSR, Kiev

1993-01-01

The analysis of state of investigations of gas-thermal coatings formation processes in presented. Classification of approaches to mathematical simulation of thermal phenomena studies is offered. The general characteristics of three main approaches to the analysis of heat transport processes is given. Some problems of mathematical simulation of single particle thermal interaction with solid surface are considered in details. The main physical assumptions are analysed

Level of processing modulates the neural correlates of emotional memory formation

OpenAIRE

Ritchey, Maureen; LaBar, Kevin S.; Cabeza, Roberto

2010-01-01

Emotion is known to influence multiple aspects of memory formation, including the initial encoding of the memory trace and its consolidation over time. However, the neural mechanisms whereby emotion impacts memory encoding remain largely unexplored. The present study employed a levels-of-processing manipulation to characterize the impact of emotion on encoding with and without the influence of elaborative processes. Participants viewed emotionally negative, neutral, and positive scenes under ...

Profiles of the stochastic star formation process in spiral galaxies

International Nuclear Information System (INIS)

Comins, N.

1981-01-01

The formation of spiral arms in disc galaxies is generally attributed to the effects of spiral density waves. These relatively small (i.e. 5 per cent) non-axisymmetric perturbations of the interstellar medium cause spiral arms highlighted by O and B type stars to be created. In this paper another mechanism for spiral arm formation, the stochastic self-propagating star formation (SSPSF) process is examined. The SSPSF process combines the theory that shock waves from supernovae will compress the interstellar medium to create new stars, some of which will be massive enough to also supernova, with a disc galaxy's differential rotation to create spiral arms. The present work extends this process to the case where the probability of star formation from supernova shocks decreases with galactic radius. Where this work and previous investigations overlap (namely the uniform probability case), the agreement is very good, pretty spirals with various numbers of arms are generated. The decreasing probability cases, taken to vary as rsup(-j), still form spiral arms for 0 1.5 the spiral structure is essentially non-existent. (author)

Becoming a psychiatric/mental health nurse in the UK: a qualitative study exploring processes of identity formation.

Science.gov (United States)

Hurley, John; Lakeman, Richard

2011-01-01

Identity studies are well established across the social science literature with mental health nursing beginning to offer evidenced insights into what may, or may not, constitute key identity performances. For mental health nursing these performances remain contested, both from within the profession and from international contexts that favour generic constructions of mental health. This paper offers findings from a qualitative study that focused upon the process of how mental health nursing identity development is influenced, rather than what that identity may or may not be. These findings highlight that mental health nurses (MHNs) not only form their identity around service user centred education and training, but that many also use the education as a means to leave the profession. Through highlighting the impact of informal education (i.e., through work), formal education, and training upon the formation of mental health nursing identity, nurses are potentially alerted to the importance of clinically focussed mental health being prominent within curricula, rewarding mental health nursing skills specialisation, and the importance of the role of the service user in mental health nurse education and, hence, identity formation.

Family physicians' professional identity formation: a study protocol to explore impression management processes in institutional academic contexts.

Science.gov (United States)

Rodríguez, Charo; Pawlikowska, Teresa; Schweyer, Francois-Xavier; López-Roig, Sofia; Bélanger, Emmanuelle; Burns, Jane; Hugé, Sandrine; Pastor-Mira, Maria Ángeles; Tellier, Pierre-Paul; Spencer, Sarah; Fiquet, Laure; Pereiró-Berenguer, Inmaculada

2014-09-06

Despite significant differences in terms of medical training and health care context, the phenomenon of medical students' declining interest in family medicine has been well documented in North America and in many other developed countries as well. As part of a research program on family physicians' professional identity formation initiated in 2007, the purpose of the present investigation is to examine in-depth how family physicians construct their professional image in academic contexts; in other words, this study will allow us to identify and understand the processes whereby family physicians with an academic appointment seek to control the ideas others form about them as a professional group, i.e. impression management. The methodology consists of a multiple case study embedded in the perspective of institutional theory. Four international cases from Canada, France, Ireland and Spain will be conducted; the "case" is the medical school. Four levels of analysis will be considered: individual family physicians, interpersonal relationships, family physician professional group, and organization (medical school). Individual interviews and focus groups with academic family physicians will constitute the main technique for data generation, which will be complemented with a variety of documentary sources. Discourse techniques, more particularly rhetorical analysis, will be used to analyze the data gathered. Within- and cross-case analysis will then be performed. This empirical study is strongly grounded in theory and will contribute to the scant body of literature on family physicians' professional identity formation processes in medical schools. Findings will potentially have important implications for the practice of family medicine, medical education and health and educational policies.

In-situ observation of structure formation in polymer processing

International Nuclear Information System (INIS)

Murase, Hiroki

2009-01-01

In-situ X-ray scattering in polymer processing is a crucial method to elucidate the mechanism of structure formation in the process. Fiber spinning is one such process primarily imposing extensional deformation on polymeric melt at the spin-line during rapid cooling. In-situ small-angle X-ray scattering using synchrotron radiation on the spinning process allows direct observation of the transient structure developing in the process. (author)

A study of the formation processes of the 2212 phase in the Bi-based superconductor systems. [BiSrCaCuO

Energy Technology Data Exchange (ETDEWEB)

Wai, Lo; Glowacki, B A [Interdisciplinary Research Centre in Superconductivity, Univ. of Cambridge (United Kingdom)

1992-04-15

A study towards the identification of the reactions contributing to and accompanying the formation of the 2212 phase from oxides and carbonates by solid state reaction processes was conducted. The formation processes were investigated by thermal analysis, powder X-ray diffractometry and AC magnetic susceptometry. The 2212 phase was found to form from reactions between the 2201 phases (the non-superconducting pseudo-tetragonal and the superconducting monoclinic phases), Bi{sub 6}Ca{sub 7}O{sub 16}, CuO and SrCO{sub 3}. The 2201 phases were produced by the reactions of Bi-Sr-Cu-O or Bi-Sr-O compounds with SrCO{sub 3} or CuO. The 2201 phases could also be formed through the direct reaction between Bi{sub 2}CuO{sub 4} and SrCO{sub 3}. (orig.).

Microbial processes in banded iron formation deposition

DEFF Research Database (Denmark)

Posth, Nicole; Konhauser, Kurt; Kappler, Andreas

2013-01-01

, remains unresolved. Evidence of an anoxic Earth with only localized oxic areas until the Great Oxidation Event ca 2·45 to 2·32 Ga makes the investigation of O2-independent mechanisms for banded iron formation deposition relevant. Recent studies have explored the long-standing proposition that Archean......Banded iron formations have been studied for decades, particularly regarding their potential as archives of the Precambrian environment. In spite of this effort, the mechanism of their deposition and, specifically, the role that microbes played in the precipitation of banded iron formation minerals...... banded iron formations may have been formed, and diagenetically modified, by anaerobic microbial metabolisms. These efforts encompass a wide array of approaches including isotope, ecophysiological and phylogeny studies, molecular and mineral marker analysis, and sedimentological reconstructions. Herein...

A linear process-algebraic format for probabilistic systems with data (extended version)

NARCIS (Netherlands)

Katoen, Joost P.; van de Pol, Jan Cornelis; Stoelinga, Mariëlle Ida Antoinette; Timmer, Mark

2010-01-01

This paper presents a novel linear process-algebraic format for probabilistic automata. The key ingredient is a symbolic transformation of probabilistic process algebra terms that incorporate data into this linear format while preserving strong probabilistic bisimulation. This generalises similar

A study on frost formation

OpenAIRE

青木, 和夫

1986-01-01

When humid air is exposed to a cold surface whose temperature is below 0 \\C\\, frost deposition occurs and continues to accumulate on the surface. Frost deposition is an important phenomenon in cryogenic industries for use in air conditioners, refrigerators and freeze-out purification, because it causes the drop of thermal efficiency on heat exchangers.This paper presented a review of our previous studies on frost formation with emphasis on the frost growth process, the frost structure, the gr...

Level of Processing Modulates the Neural Correlates of Emotional Memory Formation

Science.gov (United States)

Ritchey, Maureen; LaBar, Kevin S.; Cabeza, Roberto

2011-01-01

Emotion is known to influence multiple aspects of memory formation, including the initial encoding of the memory trace and its consolidation over time. However, the neural mechanisms whereby emotion impacts memory encoding remain largely unexplored. The present study used a levels-of-processing manipulation to characterize the impact of emotion on…

Numerical study on formation process of helical nonneutral plasmas using electron injection from outside magnetic surfaces

International Nuclear Information System (INIS)

Nakamura, Kazutaka; Himura, Haruhiko; Masamune, Sadao; Sanpei, Akio; Isobe, Mitsutaka

2009-01-01

In order to investigate the formation process of helical nonneutral plasmas, we calculate the orbits of electron injected in the stochastic magnetic field when the closed helical magnetic surfaces is correspond with the equipotential surfaces. Contrary to the experimental observation, there are no electrons inward penetrating. (author)

The actor set-up of TV advertising. A new process for hybrid formats

OpenAIRE

von Rimscha, M Bjørn; Rademacher, Patrick

2008-01-01

The paper introduces a basic description of the advertising process in TV advertising and discusses how this process might be altered when 30 second spots are replaced by hybrid advertising formats such as sponsoring and placements. For each actor in the process the potential benefit of hybrid advertising is identified and the respective interest in changing the process is deduced. A qualitative interview study with representatives from each actor in the process is used to illustrate that con...

Effect of pores formation process and oxygen plasma treatment to hydroxyapatite formation on bioactive PEEK prepared by incorporation of precursor of apatite.

Science.gov (United States)

Yabutsuka, Takeshi; Fukushima, Keito; Hiruta, Tomoko; Takai, Shigeomi; Yao, Takeshi

2017-12-01

When bioinert substrates with fine-sized pores are immersed in a simulated body fluid (SBF) and the pH value or the temperature is increased, fine particles of calcium phosphate, which the authors denoted as 'precursor of apatite' (PrA), are formed in the pores. By this method, hydroxyapatite formation ability can be provided to various kinds of bioinert materials. In this study, the authors studied fabrication methods of bioactive PEEK by using the above-mentioned process. First, the fine-sized pores were formed on the surface of the PEEK substrate by H 2 SO 4 treatment. Next, to provide hydrophilic property to the PEEK, the surfaces of the PEEK were treated with O 2 plasma. Finally, PrA were formed in the pores by the above-mentioned process, which is denoted as 'Alkaline SBF' treatment, and the bioactive PEEK was obtained. By immersing in SBF with the physiological condition, hydroxyapatite formation was induced on the whole surface of the substrate within 1day. The formation of PrA directly contributed to hydroxyapatite formation ability. By applying the O 2 plasma treatment, hydroxyapatite formation was uniformly performed on the whole surface of the substrate. The H 2 SO 4 treatment contributed to a considerable enhancement of adhesive strength of the formed hydroxyapatite layer formed in SBF because of the increase of surface areas of the substrate. As a comparative study, the sandblasting method was applied as the pores formation process instead of the H 2 SO 4 treatment. Although hydroxyapatite formation was provided also in this case, however, the adhesion of the formed hydroxyapatite layer to the substrate was not sufficient even if the O 2 plasma treatment was conducted. This result indicates that the fine-sized pores should be formed on the whole surface of the substrate uniformly to achieve high adhesive strength of the hydroxyapatite layer. Therefore, it is considered that the H 2 SO 4 treatment before the O 2 plasma and the 'Alkaline SBF' treatment

Formation of low-dimensional crystalline nucleus region during insulin amyloidogenesis process

International Nuclear Information System (INIS)

Amdursky, Nadav; Gazit, Ehud; Rosenman, Gil

2012-01-01

Highlights: ► We observe lag-phase crystallization process in insulin. ► The crystallization is a result of the formation of higher order oligomers. ► The crystallization also changes the secondary structure of the protein. ► The spectroscopic signature can be used for amyloid inhibitors assay. -- Abstract: Insulin, as other amyloid proteins, can form amyloid fibrils at certain conditions. The self-assembled aggregation process of insulin can result in a variety of conformations, starting from small oligomers, going through various types of protofibrils, and finishing with bundles of fibrils. One of the most common consensuses among the various self-assembly processes that are suggested in the literature is the formation of an early stage nucleus conformation. Here we present an additional insight for the self-assembly process of insulin. We show that at the early lag phase of the process (prior to fibril formation) the insulin monomers self-assemble into ordered nanostructures. The most notable feature of this early self-assembly process is the formation of nanocrystalline nucleus regions with a strongly bound electron–hole confinement, which also change the secondary structure of the protein. Each step in the self-assembly process is characterized by an optical spectroscopic signature, and possesses a narrow size distribution. By following the spectroscopic signature we can measure the potency of amyloid fibrils inhibitors already at the lag phase. We further demonstrate it by the use of epigallocatechin gallate, a known inhibitor for insulin fibrils. The findings can result in a spectroscopic-based application for the analysis of amyloid fibrils inhibitors.

Investigation of complex formation processes of hydroxypropylmethylcellulose and polymethacrylic acid in aqueous solutions

OpenAIRE

M. Katayeva; R. Mangazbayeva; R. Abdykalykova

2012-01-01

The complex formation process of hydroxypropylcellulose (HPC) with polymethacrylic acid (PMA) have been studied using methods of turbidimetric and viscosimetric titration. Position of maximum depending on polymer concentration and molecular mass of polysaccharide have different values.

Deciphering the influence of the thermal processes on the early passive margins formation

Science.gov (United States)

Bousquet, Romain; Nalpas, Thierry; Ballard, Jean-François; Ringenbach, Jean-Claude; Chelalou, Roman; Clerc, Camille

2015-04-01

Many large-scale dynamic processes, from continental rifting to plate subduction, are intimately linked to metamorphic reactions. This close relation between geodynamic processes and metamorphic reactions is, in spite of appearances, yet poorly understood. For example, during extension processes, rocks will be exposed to important temperature, pressures and stress changes. Meanwhile less attention has been paid to other important aspects of the metamorphic processes. When reacting rocks expand and contract, density and volume changes will set up in the surrounding material. While several tectonic models are proposed to explain the formation of extensive basins and passive margins ( simple shear detachment mantle exhumation .... ) a single thermal model (McKenzie , 1978), as a dogma, is used to understanding and modeling the formation and evolution of sedimentary basins . This model is based on the assumption that the extension is only by pure shear and it is instantaneous. Under this approach, the sedimentary deposits occur in two stages. i) A short step , 1 to 10 Ma , controlled by tectonics. ii) A longer step , at least 50 Ma as a result of the thermal evolution of the lithosphere.
However, most stratigraphic data indicate that less thermal model can account for documented vertical movements. The study of the thermal evolution , coupled with other tectonic models , and its consequences have never been studied in detail , although the differences may be significant and it is clear that the petrological changes associated with changes in temperature conditions , influence changes reliefs.
In addition, it seems that the relationship between basin formation and thermal evolution is not always the same:
- Sometimes the temperature rise above 50 to 100 Ma tectonic extension. In the Alps, a significant rise in geothermal gradient Permo -Triassic followed by a "cold" extension , leading to the opening of the Ligurian- Piedmont ocean, from the Middle Jurassic .�

Grain processes in massive star formation

International Nuclear Information System (INIS)

Wolfire, M.G.; Cassinelli, J.P.

1986-01-01

Observational evidence suggests that stars greater than 100 M(solar) exist in the Galaxy and Large Magellanic Cloud (LMC), however classical star formation theory predicts stellar mass limits of only approx. 60 M(solar). A protostellar accretion flow consists of inflowing gas and dust. Grains are destroyed as they are near the central protostar creating a dust shell or cocoon. Radiation pressure acting on the grain can halt the inflow of material thereby limiting the amount of mass accumulated by the protostar. We first consider rather general constraints on the initial grain to gas ratio and mass accretion rates that permit inflow. We further constrain these results by constructing a numerical model. Radiative deceleration of grains and grain destruction processes are explicitly accounted for in an iterative solution of the radiation-hydrodynamic equations. Findings seem to suggest that star formation by spherical accretion requires rather extreme preconditioning of the grain and gas environment

Numerical investigation of micro-pore formation during substrate impact of molten droplets in spraying processes

International Nuclear Information System (INIS)

Liu, H.; Lavernia, E.J.; Rangel, R.H.; Muehlberger, E.; Sickinger, A.

1994-01-01

The porosity that is commonly associated with discrete droplet processes, such as plasma spraying and spray deposition, effectively degrades the quality of the sprayed material. In the present study, micro-pore formation during the deformation and interaction of molten tungsten droplets impinging onto a flat substrate in spraying processes is numerically investigated. The numerical simulation is accomplished on the basis of the full Navier-Stokes equations and the Volume Of Fluid (VOF) function by using a 2-domain method for the thermal field and solidification problem and a two-phase flow continuum model for the flow problem with a growing solid layer. The possible mechanisms governing the formation of micro-pores are discussed. The effects of important processing parameters, such as droplet impact velocity, droplet temperature, substrate temperature, and droplet viscosity, on the micro-pore formation are addressed

The ethical formation process of the learners who study Marxism-leninism and History. Particularities o f this process in Rafael Maria de Mendive teachers training university

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Norma Cabrera Domínguez

2014-03-01

Full Text Available The article reveals the systematization of the work of different authors about the theme discussed and the analysis made by the author according to the characteristics of the process of ethic formation of the students form the Marxism Leninism and History carrer during the initial formation stage, centred in an interdisciplinary perspective in ̈Rafael Maria de Mendive ̈ University of Pedagogical Sciences ̈ form Pinar del Rio. This work takes as a starting point the materialistic and dialectical method, in the relation man-society, in the Pedagogy and General Didactics and in the current situation of this process.

The formation of educators: a study on PNAIC

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Maria Elizabete Souza Couto

2016-01-01

Full Text Available This paper has the aim to analyze the process of the formation of educator teachers (Study advisors that assume the responsibility of the literacy teachers’ education and how they build knowledge to contribute in the education of literacy teachers. The research is of qualitative nature and for data collection we used a questionnaire that was answered by 49 educator teachers. When analyzing data, we understood that the formation of educators is still a little studied and explored field. The educators pointed out the construction and the mobilization of a necessary knowledge base to develop the area and, consequently, the construction of the educating process to educate literacy teachers, (reconstituting situations that are theoretical and practical, mobilizing knowledge that refer, for instance, to planning, reading, writing, speaking. Thus, the educators are enlarging their knowledge repertoire and helping the literacy teachers to build knowledge in the literacy area.

Investigation of complex formation processes of hydroxypropylmethylcellulose and polymethacrylic acid in aqueous solutions

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M. Katayeva

2012-12-01

Full Text Available The complex formation process of hydroxypropylcellulose (HPC with polymethacrylic acid (PMA have been studied using methods of turbidimetric and viscosimetric titration. Position of maximum depending on polymer concentration and molecular mass of polysaccharide have different values.

Rationalization of specific structure formation in electrospinning process: Study on nano-fibrous PCL- and PLGA-based scaffolds.

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Saeed, Mahdi; Mirzadeh, Hamid; Zandi, Mojgan; Irani, Shiva; Barzin, Jalal

2015-12-01

Formation of specific structures on poly-ɛ-caprolactone (PCL) and poly lactide-co-glycolide (PLGA) based electrospun mats is rationalized and the effect of interactive parameters; high voltage and flow rate on unique surface topography is evaluated. By increasing the collecting time in electrospinning process and enhancing fiber to fiber repulsion, surface characteristics of mats changes from nano- to micro-topography. In this study surface topography of the fabricated mats based on PCL and PLGA were assessed using AFM and SEM techniques to display the distinct phenomenon occurs on collected random fibers. In this research the rationale behind the formation of bump and flower like structures on fibrous mats was discussed. Because of great potential application of the fabricated substrates in the fields of medical purposes, cell-matrix interaction was evaluated and in vitro biological test with human dermal fibroblast and mouse L929 fibroblast cells was performed to study the cell responses to different roughness of nano-fibers collected at different time intervals. Our results show that after 7 days, cell proliferation is improved on PCL collected at 40 min in the case of human fibroblast cells and on PCL collected in 70 min in the case of L929 mouse fibroblast cells. © 2015 Wiley Periodicals, Inc.

Galaxy formation: internal mechanisms and cosmological processes

International Nuclear Information System (INIS)

Martig, Marie

2010-01-01

This thesis is devoted to galaxy formation and evolution in a cosmological context. Cosmological simulations have unveiled two main modes of galaxy growth: hierarchical growth by mergers and accretion of cold gas from cosmic filaments. However, these simulations rarely take into account small scale mechanisms, that govern internal evolution and that are a key ingredient to understand galaxy formation and evolution. Thanks to a new simulation technique that I have developed, I first studied the colors of galaxies, and in particular the reddening of elliptical galaxies. I showed that the gas disk in an elliptical galaxy could be stabilized against star formation because of the galaxy's stellar component being within a spheroid instead of a disk. This mechanism can explain the red colors of some elliptical galaxies that contain a gas disk. I also studied the formation of spiral galaxies: most cosmological simulations cannot explain the formation of Milky Way-like galaxies, i.e. with a large disk and a small bulge. I showed that this issue could be partly solved by taking into account in the simulations the mass loss from evolved stars through stellar winds, planetary nebulae and supernovae explosions. (author) [fr

Haze Formation and Behavior in Liquid-Liquid Extraction Processes

International Nuclear Information System (INIS)

Arm, Stuart T.; Jenkins, J. A.

2006-01-01

Aqueous haze formation and behavior was studied in the liquid-liquid system tri-n-butyl phosphate in odorless kerosene and 3M nitric acid with uranyl nitrate and cesium nitrate representing the major solute and an impurity, respectively. A pulsed column, mixer-settler and centrifugal contactor were chosen to investigate the effect of different turbulence characteristics on the manifestation of haze since these contactors exhibit distinct mixing phenomena. The dispersive processes of drop coalescence and breakage, and water precipitation in the organic phase were observed to lead to the formation of haze drops of ∼1 um in diameter. The interaction between the haze and primary drops of the dispersion was critical to the separation efficiency of the liquid-liquid extraction equipment. Conditions of high power input and spatially homogeneous mixing enabled the haze drops to become rapidly assimilated within the dispersion to maximize the scrub performance and separation efficiency of the equipment

Precooking as a Control for Histamine Formation during the Processing of Tuna: An Industrial Process Validation.

Science.gov (United States)

Adams, Farzana; Nolte, Fred; Colton, James; De Beer, John; Weddig, Lisa

2018-02-23

An experiment to validate the precooking of tuna as a control for histamine formation was carried out at a commercial tuna factory in Fiji. Albacore tuna ( Thunnus alalunga) were brought on board long-line catcher vessels alive, immediately chilled but never frozen, and delivered to an on-shore facility within 3 to 13 days. These fish were then allowed to spoil at 25 to 30°C for 21 to 25 h to induce high levels of histamine (>50 ppm), as a simulation of "worst-case" postharvest conditions, and subsequently frozen. These spoiled fish later were thawed normally and then precooked at a commercial tuna processing facility to a target maximum core temperature of 60°C. These tuna were then held at ambient temperatures of 19 to 37°C for up to 30 h, and samples were collected every 6 h for histamine analysis. After precooking, no further histamine formation was observed for 12 to 18 h, indicating that a conservative minimum core temperature of 60°C pauses subsequent histamine formation for 12 to 18 h. Using the maximum core temperature of 60°C provided a challenge study to validate a recommended minimum core temperature of 60°C, and 12 to 18 h was sufficient to convert precooked tuna into frozen loins or canned tuna. This industrial-scale process validation study provides support at a high confidence level for the preventive histamine control associated with precooking. This study was conducted with tuna deliberately allowed to spoil to induce high concentrations of histamine and histamine-forming capacity and to fail standard organoleptic evaluations, and the critical limits for precooking were validated. Thus, these limits can be used in a hazard analysis critical control point plan in which precooking is identified as a critical control point.

Concept formation: a supportive process for early career nurses.

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Thornley, Tracey; West, Sandra

2010-09-01

Individuals come to understand abstract constructs such as that of the 'expert' through the formation of concepts. Time and repeated opportunity for observation to support the generalisation and abstraction of the developing concept are essential if the concept is to form successfully. Development of an effective concept of the 'expert nurse' is critical for early career nurses who are attempting to integrate theory, values and beliefs as they develop their clinical practice. This study explores the use of a concept development framework in a grounded theory study of the 'expert nurse'. Qualitative. Using grounded theory methods for data collection and analysis, semi-structured interviews were conducted with registered nurses. The participants were asked to describe their concept of the 'expert nurse' and to discuss their experience of developing this. Participants reported forming their concept of the 'expert nurse', after multiple opportunities to engage with nurses identified as 'expert'. This identification did not necessarily relate to the designated position of the 'expert nurse' or assigned mentors. When the early career nurse does not successfully form a concept of the 'expert nurse', difficulties in personal and professional development including skill/knowledge development may arise. To underpin development of their clinical practice effectively, early career nurses need to be provided with opportunities that facilitate the purposive formation of their own concept of the 'expert nurse'. Formation of this concept is not well supported by the common practice of assigning mentors. Early career nurses must be provided with the time and the opportunity to individually develop and refine their concept of the 'expert nurse'. To achieve this, strategies including providing opportunities to engage with expert nurses and discussion of the process of concept formation and its place in underpinning personal judgments may be of assistance. © 2010 Blackwell Publishing

Study of aroma formation and transformation during the manufacturing process of Biluochun green tea in Yunnan Province by HS-SPME and GC-MS.

Science.gov (United States)

Wang, Chen; Lv, Shidong; Wu, Yuanshuang; Lian, Ming; Gao, Xuemei; Meng, Qingxiong

2016-10-01

Biluochun is a typical non-fermented tea and is also famous for its unique aroma in China. Few studies have been performed to evaluate the effect of the manufacturing process on the formation and content of its aroma. The volatile components were extracted at different manufacturing process steps of Biluochun green tea using fully automated headspace solid-phase microextraction (HS-SPME) and further characterised by gas chromatography-mass spectrometry (GC-MS). Among 67 volatile components collected, the fractions of linalool oxides, β-ionone, phenylacetaldehyde, aldehydes, ketones, and nitrogen compounds were increased while alcohols and hydrocarbons declined during the manufacturing process. The aroma compounds decreased the most during the drying steps. We identified a number of significantly changed components that can be used as markers and quality control during the producing process of Biluochun. The drying step played a major role in the aroma formation of green tea products and should be the most important step for quality control. © 2016 Society of Chemical Industry. © 2016 Society of Chemical Industry.

Laboratory Studies of the Formation of Carbonaceous Cosmic Dust from PAH Precursors

Science.gov (United States)

Salama, Farid; Contreras, C. S.

2012-05-01

The study of the formation and destruction processes of cosmic dust is essential to understand and to quantify the budget of extraterrestrial organic molecules. Although dust with all its components plays an important role in the evolution of interstellar chemistry and in the formation of organic molecules, little is known on the formation and destruction processes of carbonaceous dust. PAHs are important chemical building blocks of interstellar dust. They are detected in interplanetary dust particles and in meteoritic samples and are an important, ubiquitous component of the interstellar medium. The formation of PAHs from smaller molecules has not been extensively studied. Therefore, it is imperative that laboratory experiments be conducted to study the dynamic processes of carbon grain formation from PAH precursors. Studies of interstellar dust analogs formed from a variety of PAH and hydrocarbon precursors as well as species that include O, N, and S, have recently been performed using the COSmIC facility in our laboratory under conditions that simulate interstellar and circumstellar environments. The species formed in the pulsed discharge nozzle (PDN) plasma source are detected and characterized with high-sensitivity cavity ringdown spectroscopy coupled to a Reflectron time-of-flight mass spectrometer (ReTOF-MS), thus providing both spectroscopic and ion mass information in-situ. We report the measurements obtained in these experiments. Studies with hydrocarbon precursors show the feasibility of specific molecules to form PAHs, while studies with carbon ring systems (benzene and derivatives, PAHs) precursors provide information on pathways toward larger carbonaceous molecules. From these unique measurements, we derive information on the size and the structure of interstellar dust grain particles, the growth and the destruction processes of interstellar dust and the resulting budget of extraterrestrial organic molecules. Acknowledgements: This research is

Spilitization processes in the Proterozoic Ongeluk Andesite Formation in Griqualand West, South Africa

International Nuclear Information System (INIS)

Schuette, S.S.; Cornell, D.H.

1990-01-01

The Ongeluk Formation is a thick succession of lavas which crops out over a large portion of the region. The formation thickness is poorly constrained and considered to be equivalent to the Hekpoort Basalts in the Transvaal, but large facies changes in the sedimentary formations obscure the correlation. At least two alteration events can be recognized in the Ongeluk Lava: a spilitization process, and a locally restricted hydrothermal event and oxidation process which obscures the spilitization process. The Ongeluk lavas probably covered a much greater area of Griqualand West than at present and could have provided a significant source of manganese, deposited in the Kalahari Manganese Field. A connection between the volcanic origin and alteration of the Ongeluk Formation and the Kalahari Manganese-type mineralization is demonstrated by Gresens' equations. 2 figs., 1 tab

Investigating the Formation Process of Sn-Based Lead-Free Nanoparticles with a Chemical Reduction Method

International Nuclear Information System (INIS)

Zhang, W.; Zhao, B.; Gao, Y.; Zhang, W.; Zhao, B.; Zou, Ch.; Zhai, Q.; Gao, Y.; Gao, Y.; Acquah, S.F.A.

2013-01-01

Nanoparticles of a promising lead-free solder alloy (Sn 3.5 Ag (wt.%, Sn Ag) and Sn 3.0 Ag 0.5 Cu (wt.%, SAC)) were synthesized through a chemical reduction method by using anhydrous ethanol and 1,10-phenanthroline as the solvent and surfactant, respectively. To illustrate the formation process of Sn-Ag alloy based nanoparticles during the reaction, X-ray diffraction (XRD) was used to investigate the phases of the samples in relation to the reaction time. Different nucleation and growth mechanisms were compared on the formation process of the synthesized nanoparticles. The XRD results revealed different reaction process compared with other researchers. There were many contributing factors to the difference in the examples found in the literature, with the main focus on the formation mechanism of crystal nuclei, the solubility and ionizability of metal salts in the solvent, the solid solubility of Cu in Ag nuclei, and the role of surfactant on the growth process. This study will help define the parameters necessary for the control of both the composition and size of the nanoparticles

Adjusting to bodily change following stoma formation: a phenomenological study.

Science.gov (United States)

Thorpe, Gabrielle; Arthur, Antony; McArthur, Maggie

2016-09-01

Scant research has been undertaken to explore in-depth the meaning of bodily change for individuals following stoma formation. The aim of this study was to understand the experience of living with a new stoma, with a focus on bodily change. The study adopted a longitudinal phenomenological approach. Purposeful sampling was used to recruit 12 participants who had undergone faecal stoma-forming surgery. In-depth, unstructured interviews were conducted at 3, 9 and 15 months following surgery. A five-stage framework facilitated iterative data analysis. Stoma formation altered the taken-for-granted relationship individuals had with their bodies in terms of appearance, function and sensation, undermining the unity between body and self. Increasing familiarity with and perceived control over their stoma over time diminished awareness of their changed body, facilitating adaptation and self-acceptance. Stoma formation can undermine an individual's sense of embodied self. A concept of embodiment is proposed to enable the experience of living with a new stoma to be understood as part of a wider process of re-establishing a unity between body, self and world. In defining a framework of care, individuals with a new stoma can be assisted to adapt to and accept a changed sense of embodied self. Implications for Rehabilitation Awareness and understanding of the diverse ways in which stoma formation disrupts the unconscious relationship between body and self can help clinicians to provide responsive, person-centred care. Supporting strategies that facilitate bodily mastery following stoma formation will facilitate rehabilitation and promote adjustment and self-acceptance. A concept of embodiment can help clinicians to deepen their understanding of the experiences of people living with a new stoma and the support they may require during the rehabilitation process. This paper provides clinicians with actionable insight that allows them to better support patients to a smoother

Raman and terahertz spectroscopical investigation of cocrystal formation process of piracetam and 3-hydroxybenzoic acid

Science.gov (United States)

Du, Yong; Zhang, Huili; Xue, Jiadan; Fang, Hongxia; Zhang, Qi; Xia, Yi; Li, Yafang; Hong, Zhi

2015-03-01

Cocrystallization can improve physical and chemical properties of active pharmaceutical ingredient, and this feature has great potential in pharmaceutical development. In this study, the cocrystal of piracetam and 3-hydroxybenzoic acid under grinding condition has been characterized by Raman and terahertz spectroscopical techniques. The major vibrational modes of individual starting components and cocrystal are obtained and assigned. Spectral results show that the vibrational modes of the cocrystal are different from those of the corresponding parent materials. The dynamic process of such pharmaceutical cocrystal formation has also been monitored directly with Raman and THz spectra. The formation rate is pretty fast in first several 20 min grinding time, and then it becomes slow. After ∼35 min, such process has been almost completed. These results offer us the unique means and benchmark for characterizing the cocrystal conformation from molecule-level and also provide us rich information about the reaction dynamic during cocrystal formation process in pharmaceutical fields.

Angular scattering in electron capture and loss D- beam formation processes

International Nuclear Information System (INIS)

Coggiola, M.J.; Hodges, R.V.; Huestis, D.L.; Peterson, J.R.

1980-01-01

The development of high energy (> 150 keV) neutral beams for heating and fueling magnetic fusion devices depends on the ability to produce well-collimated negative ion beams. The double capture charge-exchange technique is a known, scalable method. In order to maximize the overall efficiency of the process and to achieve the desired beam characteristics, it is necessary to examine the optical qualities of the beams as well as the total efficiency of beam production. A combined modeling and experimental study of the angular scattering effects in negative ion formation and loss processes has therefore been undertaken

Modeling Coupled Processes in Clay Formations for Radioactive Waste Disposal

Energy Technology Data Exchange (ETDEWEB)

Liu, Hui-Hai; Rutqvist, Jonny; Zheng, Liange; Sonnenthal, Eric; Houseworth, Jim; Birkholzer, Jens

2010-08-31

As a result of the termination of the Yucca Mountain Project, the United States Department of Energy (DOE) has started to explore various alternative avenues for the disposition of used nuclear fuel and nuclear waste. The overall scope of the investigation includes temporary storage, transportation issues, permanent disposal, various nuclear fuel types, processing alternatives, and resulting waste streams. Although geologic disposal is not the only alternative, it is still the leading candidate for permanent disposal. The realm of geologic disposal also offers a range of geologic environments that may be considered, among those clay shale formations. Figure 1-1 presents the distribution of clay/shale formations within the USA. Clay rock/shale has been considered as potential host rock for geological disposal of high-level nuclear waste throughout the world, because of its low permeability, low diffusion coefficient, high retention capacity for radionuclides, and capability to self-seal fractures induced by tunnel excavation. For example, Callovo-Oxfordian argillites at the Bure site, France (Fouche et al., 2004), Toarcian argillites at the Tournemire site, France (Patriarche et al., 2004), Opalinus clay at the Mont Terri site, Switzerland (Meier et al., 2000), and Boom clay at Mol site, Belgium (Barnichon et al., 2005) have all been under intensive scientific investigations (at both field and laboratory scales) for understanding a variety of rock properties and their relations with flow and transport processes associated with geological disposal of nuclear waste. Clay/shale formations may be generally classified as indurated and plastic clays (Tsang et al., 2005). The latter (including Boom clay) is a softer material without high cohesion; its deformation is dominantly plastic. For both clay rocks, coupled thermal, hydrological, mechanical and chemical (THMC) processes are expected to have a significant impact on the long-term safety of a clay repository. For

Modeling Coupled Processes in Clay Formations for Radioactive Waste Disposal

International Nuclear Information System (INIS)

Liu, Hui-Hai; Rutqvist, Jonny; Zheng, Liange; Sonnenthal, Eric; Houseworth, Jim; Birkholzer, Jens

2010-01-01

As a result of the termination of the Yucca Mountain Project, the United States Department of Energy (DOE) has started to explore various alternative avenues for the disposition of used nuclear fuel and nuclear waste. The overall scope of the investigation includes temporary storage, transportation issues, permanent disposal, various nuclear fuel types, processing alternatives, and resulting waste streams. Although geologic disposal is not the only alternative, it is still the leading candidate for permanent disposal. The realm of geologic disposal also offers a range of geologic environments that may be considered, among those clay shale formations. Figure 1-1 presents the distribution of clay/shale formations within the USA. Clay rock/shale has been considered as potential host rock for geological disposal of high-level nuclear waste throughout the world, because of its low permeability, low diffusion coefficient, high retention capacity for radionuclides, and capability to self-seal fractures induced by tunnel excavation. For example, Callovo-Oxfordian argillites at the Bure site, France (Fouche et al., 2004), Toarcian argillites at the Tournemire site, France (Patriarche et al., 2004), Opalinus clay at the Mont Terri site, Switzerland (Meier et al., 2000), and Boom clay at Mol site, Belgium (Barnichon et al., 2005) have all been under intensive scientific investigations (at both field and laboratory scales) for understanding a variety of rock properties and their relations with flow and transport processes associated with geological disposal of nuclear waste. Clay/shale formations may be generally classified as indurated and plastic clays (Tsang et al., 2005). The latter (including Boom clay) is a softer material without high cohesion; its deformation is dominantly plastic. For both clay rocks, coupled thermal, hydrological, mechanical and chemical (THMC) processes are expected to have a significant impact on the long-term safety of a clay repository. For

THE EFFECTS OF BANKRUPTCY ON THE PREDICTABILITY OF PRICE FORMATION PROCESSES ON WARSAW’S STOCK MARKET

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Paweł Fiedor

2016-07-01

Full Text Available In this study we investigate how bankruptcy affects the market behaviour of prices of stocks on Warsaw’s Stock Exchange. As the behaviour of prices can be seen in a myriad of ways, we investigate a particular aspect of this behaviour, namely the predictability of these price formation processes. We approximate their predictability as the structural complexity of logarithmic returns. This method of analysing predictability of price formation processes using information theory follows closely the mathematical definition of predictability, and is equal to the degree to which redundancy is present in the time series describing stock returns. We use Shannon’s entropy rate (approximating Kolmogorov-Sinai entropy to measure this redundancy, and estimate it using the Lempel-Ziv algorithm, computing it with a running window approach over the entire price history of 50 companies listed on the Warsaw market which have gone bankrupt in the last few years. This enables us not only to compare the differences between predictability of price formation processes before and after their filing for bankruptcy, but also to compare the changes in predictability over time, as well as divided into different categories of companies and bankruptcies. There exists a large body of research analysing the efficiency of the whole market and the predictability of price changes enlarge, but only a few detailed studies analysing the influence of external stimulion the efficiency of price formation processes. This study fills this gap in the knowledge of financial markets, and their response to extreme external events.

The Policy Formation Process: A Conceptual Framework for Analysis. Ph.D. Thesis

Science.gov (United States)

Fuchs, E. F.

1972-01-01

A conceptual framework for analysis which is intended to assist both the policy analyst and the policy researcher in their empirical investigations into policy phenomena is developed. It is meant to facilitate understanding of the policy formation process by focusing attention on the basic forces shaping the main features of policy formation as a dynamic social-political-organizational process. The primary contribution of the framework lies in its capability to suggest useful ways of looking at policy formation reality. It provides the analyst and the researcher with a group of indicators which suggest where to look and what to look for when attempting to analyze and understand the mix of forces which energize, maintain, and direct the operation of strategic level policy systems. The framework also highlights interconnections, linkage, and relational patterns between and among important variables. The framework offers an integrated set of conceptual tools which facilitate understanding of and research on the complex and dynamic set of variables which interact in any major strategic level policy formation process.

Ketene Formation in Interstellar Ices: A Laboratory Study

Science.gov (United States)

Hudson, Reggie L.; Loeffler, Mark Josiah

2013-01-01

The formation of ketene (H2CCO, ethenone) in polar and apolar ices was studied with in situ 0.8 MeV proton irradiation, far-UVphotolysis, and infrared spectroscopic analyses at 10-20 K. Using isotopically enriched reagents, unequivocal evidencewas obtained for ketene synthesis in H2O-rich and CO2-rich ices, and several reaction products were identified. Results from scavenging experiments suggested that ketene was formed by free-radical pathways, as opposed to acid-base processes or redox reactions. Finally, we use our results to draw conclusions about the formation and stability of ketene in the interstellar medium.

Hydraulic experimental investigation on spatial distribution and formation process of tsunami deposit on a slope

Science.gov (United States)

Harada, K.; Takahashi, T.; Yamamoto, A.; Sakuraba, M.; Nojima, K.

2017-12-01

An important aim of the study of tsunami deposits is to estimate the characteristics of past tsunamis from the tsunami deposits found locally. Based on the tsunami characteristics estimated from tsunami deposit, it is possible to examine tsunami risk assessment in coastal areas. It is considered that tsunami deposits are formed based on the dynamic correlation between tsunami's hydraulic values, sediment particle size, topography, etc. However, it is currently not enough to evaluate the characteristics of tsunamis from tsunami deposits. This is considered to be one of the reasons that the understanding of the formation process of tsunami deposits is not sufficiently understood. In this study, we analyze the measurement results of hydraulic experiment (Yamamoto et al., 2016) and focus on the formation process and distribution of tsunami deposits. Hydraulic experiment was conducted with two-dimensional water channel with a slope. Tsunami was inputted as a bore wave flow. The moving floor section was installed as a seabed slope connecting to shoreline and grain size distribution was set some cases. The water level was measured using ultrasonic displacement gauges, and the flow velocity was measured using propeller current meters and an electromagnetic current meter. The water level and flow velocity was measured at some points. The distribution of tsunami deposit was measured from shoreline to run-up limit on the slope. Yamamoto et al. (2016) reported the measurement results on the distribution of tsunami deposit with wave height and sand grain size. Therefore, in this study, hydraulic analysis of tsunami sediment formation process was examined based on the measurement data. Time series fluctuation of hydraulic parameters such as Froude number, Shields number, Rouse number etc. was calculated to understand on the formation process of tsunami deposit. In the front part of the tsunami, the flow velocity take strong flow from shoreline to around the middle of slope. From

Other factors to consider in the formation of chloropropandiol fatty esters in oil processes.

Science.gov (United States)

Ramli, Muhamad Roddy; Siew, Wai Lin; Ibrahim, Nuzul Amri; Kuntom, Ainie; Abd Razak, Raznim Arni

2015-01-01

This paper examines the processing steps of extracting palm oil from fresh fruit bunches in a way that may impact on the formation of chloropropandiol fatty esters (3-MCPD esters), particularly during refining. Diacylglycerols (DAGs) do not appear to be a critical factor when crude palm oils are extracted from various qualities of fruit bunches. Highly hydrolysed oils, in spite of the high free fatty acid (FFA) contents, did not show exceptionally high DAGs, and the oils did not display a higher formation of 3-MCPD esters upon heat treatment. However, acidity measured in terms of pH appears to have a strong impact on 3-MCPD ester formation in the crude oil when heated at high temperatures. The differences in the extraction process of crude palm oil from current commercial processes and that from a modified experimental process showed clearly the effect of acidity of the oil on the formation of 3-MCPD esters. This paper concludes that the washing or dilution step in palm oil mills removes the acidity of the vegetative materials and that a well-optimised dilution/washing step in the extraction process will play an important role in reducing formation of 3-MCPD esters in crude palm oil upon further heat processing.

Restoring formation after leaching process

International Nuclear Information System (INIS)

Barrett, R.B.

1983-01-01

A method of restoring a formation which had uranium and other mineral values extracted by an alkaline lixiviant comprises introducing a source of phosphate in an amount sufficient to lower the level of soluble uranium compounds below that previously existing in the formation by the formation of insoluble uranium phosphate compounds

Processing biological literature with customizable Web services supporting interoperable formats.

Science.gov (United States)

Rak, Rafal; Batista-Navarro, Riza Theresa; Carter, Jacob; Rowley, Andrew; Ananiadou, Sophia

2014-01-01

Web services have become a popular means of interconnecting solutions for processing a body of scientific literature. This has fuelled research on high-level data exchange formats suitable for a given domain and ensuring the interoperability of Web services. In this article, we focus on the biological domain and consider four interoperability formats, BioC, BioNLP, XMI and RDF, that represent domain-specific and generic representations and include well-established as well as emerging specifications. We use the formats in the context of customizable Web services created in our Web-based, text-mining workbench Argo that features an ever-growing library of elementary analytics and capabilities to build and deploy Web services straight from a convenient graphical user interface. We demonstrate a 2-fold customization of Web services: by building task-specific processing pipelines from a repository of available analytics, and by configuring services to accept and produce a combination of input and output data interchange formats. We provide qualitative evaluation of the formats as well as quantitative evaluation of automatic analytics. The latter was carried out as part of our participation in the fourth edition of the BioCreative challenge. Our analytics built into Web services for recognizing biochemical concepts in BioC collections achieved the highest combined scores out of 10 participating teams. Database URL: http://argo.nactem.ac.uk. © The Author(s) 2014. Published by Oxford University Press.

Oxytocin promotes bone formation during the alveolar healing process in old acyclic female rats.

Science.gov (United States)

Colli, Vilma Clemi; Okamoto, Roberta; Spritzer, Poli Mara; Dornelles, Rita Cássia Menegati

2012-09-01

OT was reported to be a direct regulator of bone mass in young rodents, and this anabolic effect on bone is a peripheral action of OT. The goal of this study was to investigate the peripheral action of oxytocin (OT) in the alveolar healing process in old female rats. Females Wistar rats (24-month-old) in permanent diestrus phase, received two ip (12h apart) injections of saline (NaCl 0.15M - control group) or OT (45μg/rat - treated group). Seven days later, the right maxillary incisor was extracted and analyses were performed up to 28 days of the alveolar healing process (35 days after saline or OT administration). Calcium and phosphorus plasma concentrations did not differ between the groups. The plasma biochemical bone formations markers, alkaline phosphatase (ALP) and osteocalcin were significantly higher in the treated group. Histomorphometric analyses confirmed bone formation as the treated group presented the highest mean value of post-extraction bone formation. Tartrate-resistant acid phosphatase (TRAP) was significantly reduced in the treated group indicating an anti-resorptive effect of OT. Immunohistochemistry reactions performed in order to identify the presence of osteocalcin and TRAP in the bone cells of the dental socket confirmed these outcomes. OT was found to promote bone formation and to inhibit bone resorption in old acyclic female rats during the alveolar healing process. Published by Elsevier Ltd.

Case studies on the formation of chalcogenide self-assembled monolayers on surfaces and dissociative processes

Directory of Open Access Journals (Sweden)

Yongfeng Tong

2016-02-01

Full Text Available This report examines the assembly of chalcogenide organic molecules on various surfaces, focusing on cases when chemisorption is accompanied by carbon–chalcogen atom-bond scission. In the case of alkane and benzyl chalcogenides, this induces formation of a chalcogenized interface layer. This process can occur during the initial stages of adsorption and then, after passivation of the surface, molecular adsorption can proceed. The characteristics of the chalcogenized interface layer can be significantly different from the metal layer and can affect various properties such as electron conduction. For chalcogenophenes, the carbon–chalcogen atom-bond breaking can lead to opening of the ring and adsorption of an alkene chalcogenide. Such a disruption of the π-electron system affects charge transport along the chains. Awareness about these effects is of importance from the point of view of molecular electronics. We discuss some recent studies based on X-ray photoelectron spectroscopy that shed light on these aspects for a series of such organic molecules.

A review of biostratigraphic studies in the olistostrome deposits of Karangsambung Formation

Science.gov (United States)

Hendrizan, Marfasran

2018-02-01

Planktonic foraminifera is widely used for marine sediment biostratigraphy. Foraminiferal biostratigraphy of Karangsambung Formation is relatively rare to be investigated by previous researchers. A review of foraminiferal biostratigraphy is expected to be early work to perform a research about the ages of Tertiary rock formations in Karangsambung. The research area is formed by olistostrome process; a sedimentary slide deposit characterized by bodies of harder rock mixed and dispersed in a matrix. Biostratigraphic studies based on foraminifera and nannoplankton in Karangsambung Formation are still qualitative analysis using fossils biomarker. However, the age of this formation is still debatable based on foraminifera and nannofossil analysis. Two explanations of debatable ages in Karangsambung Formation that is possibly developed in Karangsambung area: firstly, Karangsambung Formation is characterized by normal sedimentation in some places and other regions such Kali Welaran and Clebok, Village as a product of olistostrome, and secondly, Karangsambung Formation is olistostrome deposit. However, micropaleontology sampling and analysis in matrix clays from olistostrome were ignored causing biostratigraphical results in those matrix clays occurred in normal sedimentation process and achieving the age of middle Eocene to Oligocene. We suppose previous authors picked samples in matrix of Karangsambung Formation from several river sections, which will make misinterpretation of the age of Karangsambung Formation. The age of middle to late Eocene probably is the dates of the older sediment that was reworked by sliding and sampling process and accumulated in Karangsambung Formation. The date of Karangsambung Fm is in Oligocene period based on a finding of several calcareous nannofossils. Detailed micropaleontological analysis of olistostrome deposits in Karangsambung Formation should be reevaluated for new finding of the accurate dating. Re-evaluation should start from

Star & Planet Formation Studies and Opportunities with SOFIA

Science.gov (United States)

Smith, Kimberly Ennico

2018-01-01

Star formation, the most fundamental process in the universe, is linked to planet formation and thus to the origin and evolution of life. We have a general outline of how planets and stars form, yet unraveling the details of the physics and chemistry continues to challenge us. The infrared and submillimeter part of the spectrum hold the most promise for studying the beginnings of star formation. The observational landscape recently shaped by Spitzer, Herschel and ALMA, continues to challenge our current theories. SOFIA, the Stratospheric Observatory for Infrared Astronomy, equipped with state-of-the-art infrared instrumentation to a vantage point at 45,000 feet (13.7 kilometers) flight altitude that is above 99.9 percent of the Earth's water vapor, enables observations in the infrared through terahertz frequencies not possible from the ground. SOFIA is a community observatory, about to start its sixth annual observing cycle. My talk will focus on recent results in advancing star and planet formation processes using SOFIA's imaging and polarimetric capabilities, and the upcoming science enabled by the 3rd generation instrument High-Resolution Mid-Infrared Spectrometer (HIRMES) to be commissioned in 2019. I will show how mid-infrared imaging is used to test massive star formation theories, how far-infrared polarimetry on sub-parsec scales is directly testing the role of magnetic fields in molecular clouds, and how velocity-resolved high-resolution spectroscopy will push forward our understanding of proto-planetary disk science. I will also summarize upcoming opportunities with the SOFIA observatory. For the latest news about your flying observatory, see https://sofia.usra.edu/.

Isotope-labeling studies on the formation pathway of acrolein during heat processing of oils.

Science.gov (United States)

Ewert, Alice; Granvogl, Michael; Schieberle, Peter

2014-08-20

Acrolein (2-propenal) is classified as a foodborne toxicant and was shown to be present in significant amounts in heated edible oils. Up to now, its formation was mainly suggested to be from the glycerol part of triacylglycerides, although a clear influence of the unsaturation of the fatty acid moiety was also obvious in previous studies. To unequivocally clarify the role of the glycerol and the fatty acid parts in acrolein formation, two series of labeled triacylglycerides were synthesized: [(13)C(3)]-triacylglycerides of stearic, oleic, linoleic, and linolenic acid and [(13)C(54)]-triacylglycerides with labeled stearic, oleic, and linoleic acid, but with unlabeled glycerol. Heating of each of the seven intermediates singly in silicon oil and measurement of the formed amounts of labeled and unlabeled acrolein clearly proved the fatty acid backbone as the key precursor structure. Enzymatically synthesized pure linoleic acid and linolenic acid hydroperoxides were shown to be the key intermediates in acrolein formation, thus allowing the discussion of a radical-induced reaction pathway leading to the formation of the aldehyde. Surprisingly, although several oils contained high amounts of acrolein after heating, deep-fried foods themselves, such as donuts or French fries, were low in the aldehyde.

Investigation of the gas formation in dissolution process of nuclear reactor fuel

International Nuclear Information System (INIS)

Zhang Qinfen; Liao Yuanzhong; Chen Yongqing; Sun Shuyun; Fan Yincheng

1987-12-01

The gas formation in dissolution process of two kinds of nuclear fuels was studied. The results shows that the maximum volume flow released from dissolution system is composed of two parts. One of them is air remained in dissolver and pushed out by acid vapor. The other is produced in dissolution reaction. The procedure of calculating the gas amount produced in dissolution process has been given. It is based on variation of components of dissolution solution. The gas amount produced in dissolution process of spent UO 2 fuel elements was calculated. The condenser system and loading volume of disposal system of tail gas of dissolution of spent fuel were discussed

Types of tectonic structures, sedimentary volcanogenetic formations of a mantle, favourable processes for exogenetic and polygenetic uranium deposits formation

International Nuclear Information System (INIS)

Danchev, V.I.; Komarnitskij, G.M.; Levin, V.N.; Shumlyanskij, V.A.

1985-01-01

Factors, affecting mineralization processes are considered. Characteristic features of uranium-bearing provinces are as follows: the presence of crust of continental type; deep-seated tectonic structures-rises and saggings, roofs, gneiss domes, rift zones and transform fractures; specialization for uranium of sedimentary and magmatic formations; the presence of manifestation regions of deep thermal and gaseous flow, etc. In uranium-bearing provinces territories favourable for the manifestation of different types of uranium mineralization: metamorphogenetic, polygenetic and exogenetic ones, are singled out. Different epochs of uranium ore formation are established. In sedimentary masses tectonic regime and climate are of special importance, and for epigenetic deposits, formed with an aid of underground waters-hydrogeological conditions. In the limits of the main structural elements of the Earth crust and geotectonic structures of higher orders the following types of sedimentary and volcanic formations can be singled out: 1-formations with exogenous uranium mineralization; 2-formations, accumulated in the epochs of epigenous ore formation; 3-formations fav ourable for epigenous uranium deposit formation; 4-formations unfavourable for the formation and localization of uranium mineralization

Modern limnology, sediment accumulation and varve formation processes in Lake Żabińskie, northeastern Poland: comprehensive process studies as a key to understand the sediment record

Directory of Open Access Journals (Sweden)

Alicja Bonk

2014-12-01

Full Text Available Reconstructions of paleoclimatic and paleoenvironmental data from sediment records require a thorough knowledge of the physical, chemical and biological factors that influence sediment-formation processes and signal preservation in lake sediments. Lake Żabińskie, an eutrophic hardwater lake located in northeastern Poland (Masurian Lake District, provides an unique environment for the investigation of processes that lead to the varve formation. During a two-year long observation period we investigated limnological and hydrochemical conditions within the water column, recent sediment fluxes and laminations preserved in the sediments of this lake to understand the relationship between the lake water properties and the sediment formation processes. We demonstrate that different mixing patterns may occur in Lake Żabińskie, from dimictic to meromictic depending on the meteorological conditions. Regardless of the water mixing pattern, the lake was stratified during much of the year which led to significant differences between surface and near-bottom water environments. The hypolimnion was characterized by higher conductivity and anoxic conditions with only short periods of better oxygenation, which created conditions ideal for the formation and preservation of biogenic varves. The material collected from the sediment trap revealed notable changes in sediment fluxes with characteristic spring maxima and, optionally, a second late fall maxima. Considerable variability was also observed for the fluxes of total organic carbon, biogenic silica and calcite. Microscopic investigation of the topmost sediments revealed a complex structure of the varves showing a distinct spring calcite lamina followed by several fine calcite laminae interbedded with diatom-rich laminae and, finally, by an organic-rich lamina with minerogenic admixtures deposited during winter. This seasonal variability was also reflected in the chemical composition inferred from high

KETENE FORMATION IN INTERSTELLAR ICES: A LABORATORY STUDY

Energy Technology Data Exchange (ETDEWEB)

Hudson, Reggie L.; Loeffler, Mark J., E-mail: Reggie.Hudson@NASA.gov [Astrochemistry Laboratory, NASA Goddard Space Flight Center, Greenbelt, MD 20771 (United States)

2013-08-20

The formation of ketene (H{sub 2}CCO, ethenone) in polar and apolar ices was studied with in situ 0.8 MeV proton irradiation, far-UV photolysis, and infrared spectroscopic analyses at 10-20 K. Using isotopically enriched reagents, unequivocal evidence was obtained for ketene synthesis in H{sub 2}O-rich and CO{sub 2}-rich ices, and several reaction products were identified. Results from scavenging experiments suggested that ketene was formed by free-radical pathways, as opposed to acid-base processes or redox reactions. Finally, we use our results to draw conclusions about the formation and stability of ketene in the interstellar medium.

The Gas-Phase Formation of Methyl Formate in Hot Molecular Cores

Science.gov (United States)

Horn, Anne; Møllendal, Harald; Sekiguchi, Osamu; Uggerud, Einar; Roberts, Helen; Herbst, Eric; Viggiano, A. A.; Fridgen, Travis D.

2004-08-01

Methyl formate, HCOOCH3, is a well-known interstellar molecule prominent in the spectra of hot molecular cores. The current view of its formation is that it occurs in the gas phase from precursor methanol, which is synthesized on the surfaces of grain mantles during a previous colder era and evaporates while temperatures increase during the process of high-mass star formation. The specific reaction sequence thought to form methyl formate, the ion-molecule reaction between protonated methanol and formaldehyde followed by dissociative recombination of the protonated ion [HCO(H)OCH3]+, has not been studied in detail in the laboratory. We present here the results of both a quantum chemical study of the ion-molecule reaction between [CH3OH2]+ and H2CO as well as new experimental work on the system. In addition, we report theoretical and experimental studies for a variety of other possible gas-phase reactions leading to ion precursors of methyl formate. The studied chemical processes leading to methyl formate are included in a chemical model of hot cores. Our results show that none of these gas-phase processes produces enough methyl formate to explain its observed abundance.

Tube formation by complex cellular processes in Ciona intestinalis notochord.

Science.gov (United States)

Dong, Bo; Horie, Takeo; Denker, Elsa; Kusakabe, Takehiro; Tsuda, Motoyuki; Smith, William C; Jiang, Di

2009-06-15

In the course of embryogenesis multicellular structures and organs are assembled from constituent cells. One structural component common to many organs is the tube, which consists most simply of a luminal space surrounded by a single layer of epithelial cells. The notochord of ascidian Ciona forms a tube consisting of only 40 cells, and serves as a hydrostatic "skeleton" essential for swimming. While the early processes of convergent extension in ascidian notochord development have been extensively studied, the later phases of development, which include lumen formation, have not been well characterized. Here we used molecular markers and confocal imaging to describe tubulogenesis in the developing Ciona notochord. We found that during tubulogenesis each notochord cell established de novo apical domains, and underwent a mesenchymal-epithelial transition to become an unusual epithelial cell with two opposing apical domains. Concomitantly, extracellular luminal matrix was produced and deposited between notochord cells. Subsequently, each notochord cell simultaneously executed two types of crawling movements bi-directionally along the anterior/posterior axis on the inner surface of notochordal sheath. Lamellipodia-like protrusions resulted in cell lengthening along the anterior/posterior axis, while the retraction of trailing edges of the same cell led to the merging of the two apical domains. As a result, the notochord cells acquired endothelial-like shape and formed the wall of the central lumen. Inhibition of actin polymerization prevented the cell movement and tube formation. Ciona notochord tube formation utilized an assortment of common and fundamental cellular processes including cell shape change, apical membrane biogenesis, cell/cell adhesion remodeling, dynamic cell crawling, and lumen matrix secretion.

Geochemical of clay formations : study of Spanish clay REFERENCE

International Nuclear Information System (INIS)

Turrero, M. J.; Pena, J.

2003-01-01

Clay rocks are investigated in different international research programs in order to assess its feasibility for the disposal of high level radioactive wastes. This is because different sepcific aspects: they have low hydraulic conductivity (10''-11-10''-15 m/s), a high sorption capacity, self-sealing capacity of facults and discontinuities and mechanical resistance. Several research programs on clay formations are aimed to study the chemistry of the groundwater and the water-rock reactions that control it: e. g. Boom Clay (Mol, Belgium), Oxford Clay /Harwell, United Kingdom), Toarcian Clay (Tournemire, France), Palfris formation (Wellenberg, Switzerland), Opalinus Clay (Bure, France). Based on these studies, considerable progress in the development of techniques for hydrologic, geochemical and hydrogeochemical characterization of mudstones has been accomplished (e. g. Beaufais et al. 1994, De Windt el al. 1998. Thury and Bossart 1999, Sacchi and Michelot 2000) with important advances in the knowledge of geochemical process in these materials (e. g. Reeder et al. 1993, Baeyens and Brandbury 1994, Beaucaire et al. 2000, Pearson et al., 2003).Furtermore, geochemical modeling is commonly used to simulate the evolution of water chemistry and to understand quantitatively the processes controlling the groundwater chemistry (e. g. Pearson et al. 1998, Tempel and Harrison 2000, Arcos et al., 2001). The work presented here is part of a research program funded by Enresa in the context of its R and D program. It is focused on the characterization of a clay formation (reference Argillaceous Formation, RAF) located within the Duero Basin (north-centralSpain). The characterisation of th ephysical properties,, fluid composition, mineralogy, water-rock reaction processes, geochemical modelling and sorption properties of the clays from the mentioned wells is the main purpose of this work. (Author)

Technetium electrodeposition from aqueous formate solutions at graphite electrode: electrochemical study

International Nuclear Information System (INIS)

Maslennikov, A.; Peretroukhine, V.; Masson, M.; Lecomte, M.

1999-01-01

Recovery of technetium from aqueous formate buffer solutions of ionic strength μ = 1.0 was studied in the pH interval from 1.6 to 7.5 at graphite cathode in an electrolytic cell with separated compartments was studied, using cyclic voltammetry (CV) and inverse stripping voltammetry (ISV) techniques. It has been shown that Tc electrodeposition process becomes possible at the potentials of graphite cathode E cath. 1/2 = -0.72±0.02 V/SCE and was pH independent in the interval pH = 3.46-7.32. Mechanism of electrodeposition, including Tc(VII)/Tc(IV) reduction in the solution followed by Tc(IV) hydrolysis at the electrode surface with formation of hydrated Tc oxide cathodic deposit has been proposed. The further precision of the Tc(VII) electrochemical reduction mechanism in formate buffer media and optimization of the electrodeposition process seems to be possible using additional analytical facilities except electrochemical methods. (orig.)

Study Tranport Barrier Formation using Bi- Stable Sandpile Model

International Nuclear Information System (INIS)

Kitpitak, B.; Kanjanaput, W.; Poolyarat, N.; Picha, R; Onjun, T.

2014-01-01

The formation of plasma transport barrier in Tokamak is an important issue for achieving high energy confinement and sufficient fusion performance. The simulation using in this experiment simulates cycles of dropping grains in a sandpile with two stable and two unstable slope regimes which share the same characteristic as the formation of pedestal and there are several parameters used, including stable boundaries, grains in a toppling, relax process iterations per cycle, grains in a drop and number of drops per cycle. By using this simulation, the effects of the relaxation times and number of trooping grain (the number of collapsing grain in the relaxation process) can be investigated. It is found in the simulations that the pedestal region can be observed only when the number of deposited grain exceeds a critical value which is related to number of relaxation times and number of allowed trooping grain. In another words, the pedestal formation occurs when the particle deposition rate is higher than the average diffusion rate. In addition, altering amount of trooping grain can lead to remarkable effects on slope and height of the profiles. In order to achieve better energy confinement, further study of formation of plasma transport barrier is needed.

COMMUNICATION COMPONENT FORMATION OF TEACHERS’ COMPETENCE IN THE MENTORING PROCESS

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Vera T. Sopegina

2016-01-01

Full Text Available The aim of this article is to present the integration process and special pedagogical competence in solving production and pedagogical challenges in the educational organizations and production enterprises engaged in the training of mentors.Methods. The methods involve the analysis of psycho-pedagogical and methodological literature on the issue; analysis of the Federal State Educational Standards and professional standards; modeling of processes.Results and scientific novelty. The problems of formation of communicative competence in the preparation of teachers are considered. The characteristic of the formation levels of mentoring such as «mentor-formal»; «mentor-theoretician», a «mentor-coach»; «mentor-adviser»; «mentor-professional» are given. The pedagogical potential of the phenomenon of «mentoring» is disclosed; an innovative way of mentoring within the competence approach is shown. The integrative activity of the teacher in solving production and pedagogical problems is analysed.Practical significance. The results can be used by trainers and mentors in the formation of communicative competence of students. The implementation of integration model of pedagogical and production tasks will provide the formation of communicative competence as part of vocational training. Using the obtained results can improve the effectiveness of vocational teacher education.

Accretion Processes in Star Formation

DEFF Research Database (Denmark)

Küffmeier, Michael

for short-lived radionuclides that enrich the cloud as a result of supernova explosions of the massive stars allows us to analyze the distribution of the short-lived radionuclides around young forming stars. In contradiction to results from highly-idealized models, we find that the discrepancy in 26 Al...... that the accretion process of stars is heterogeneous in space, time and among different protostars. In some cases, disks form a few thousand years after stellar birth, whereas in other cases disk formation is suppressed due to efficient removal of angular momentum. Angular momentum is mainly transported outward...... with potentially observable fluctuations in the luminosity profile that are induced by variations in the accretion rate. Considering that gas inside protoplanetary disks is not fully ionized, I implemented a solver that accounts for nonideal MHD effects into a newly developed code framework called dispatch...

Review of the investigation of mixture formation and combustion process using rapid compression machine and direct visualization system

Science.gov (United States)

Jaat, M.; Khalid, Amir; Manshoor, B.; Ramsy, Him

2013-12-01

This paper reviews of some applications of optical visualization systems to compute the fuel-air mixing process during early stage of mixture formation in Diesel Combustion Engines. A number of studies have contributed to the understanding of fuel air mixing in DI diesel engine. This review has shown that the mixture formation process affects initial flame development. The review also found that injection pressure has a great effect on the mixture formation then the flame development and combustion characteristics. The method of the simulation of real phenomenon of diesel combustion with optical access rapid compression machine is also reviewed and experimental results are presented. The application of these methods to the investigation of diesel sprays highlights mechanisms which govern propagation and distribution of the formation of a combustible fuel-air mixture. A summary of the implementation of constant volume chamber and optical visualization system are shown in the accompanying tables and figures. The visualization of the formation process of diesel spray and its combustion in the diesel combustion chamber of diesel engine has been recognized as one of the best ways to understand the characteristics of the mixture formation.

Bromate formation from the oxidation of bromide in the UV/chlorine process with low pressure and medium pressure UV lamps.

Science.gov (United States)

Fang, Jingyun; Zhao, Quan; Fan, Chihhao; Shang, Chii; Fu, Yun; Zhang, Xiangru

2017-09-01

When a bromide-containing water is treated by the ultraviolet (UV)/chlorine process, hydroxyl radicals (HO) and halogen radicals such as Cl or Br are formed due to the UV photolysis of free halogens. These reactive species may induce the formation of bromate, which is a probable human carcinogen. Bromate formation in the UV/chlorine process using low pressure (LP) and medium pressure (MP) lamps in the presence of bromide was investigated in the present study. The UV/chlorine process significantly enhanced bromate formation as compared to dark chlorination. The bromate formation was elevated with increasing UV fluence, bromide concentration, and pH values under both LP and MP UV irradiations. It was significantly enhanced at pH 9 compared to those at pH 6 and 7 with MP UV irradiation, while it was slightly enhanced at pH 9 with LP UV. The formation by UV/chlorine process started with the formation of free bromine (HOBr/OBr - ) through the reaction of chlorine and bromide, followed by a subsequent oxidation of free bromine and formation of BrO and bromate by reacting with radicals. Copyright © 2017 Elsevier Ltd. All rights reserved.

Exercise habit formation in new gym members: a longitudinal study.

Science.gov (United States)

Kaushal, Navin; Rhodes, Ryan E

2015-08-01

Reasoned action approaches have primarily been applied to understand exercise behaviour for the past three decades, yet emerging findings in unconscious and Dual Process research show that behavior may also be predicted by automatic processes such as habit. The purpose of this study was to: (1) investigate the behavioral requirements for exercise habit formation, (2) how Dual Process approach predicts behaviour, and (3) what predicts habit by testing a model (Lally and Gardner in Health Psychol Rev 7:S137-S158, 2013). Participants (n = 111) were new gym members who completed surveys across 12 weeks. It was found that exercising for at least four bouts per week for 6 weeks was the minimum requirement to establish an exercise habit. Dual Process analysis using Linear Mixed Models (LMM) revealed habit and intention to be parallel predictors of exercise behavior in the trajectory analysis. Finally, the habit antecedent model in LLM showed that consistency (β = .21), low behavioral complexity (β = .19), environment (β = .17) and affective judgments (β = .13) all significantly (p < .05) predicted changes in habit formation over time. Trainers should keep exercises fun and simple for new clients and focus on consistency which could lead to habit formation in nearly 6 weeks.

Controlling the formation process and atomic structures of single pyrazine molecular junction by tuning the strength of the metal-molecule interaction.

Science.gov (United States)

Kaneko, Satoshi; Takahashi, Ryoji; Fujii, Shintaro; Nishino, Tomoaki; Kiguchi, Manabu

2017-04-12

The formation process and atomic structures were investigated for single pyrazine molecular junctions sandwiched by three different Au, Ag, and Cu electrodes using a mechanically controllable break junction technique in ultrahigh vacuum conditions at 300 K. We demonstrated that the formation process of the single-molecule junction crucially depended on the choice of the metal electrodes. While single-molecule junction showing two distinct conductance states were found for the Au electrodes, only the single conductance state was evident for the Ag electrodes, and there was no junction formation for the Cu electrodes. These results suggested that metal-molecule interaction dominates the formation process and probability of the single-molecule junction. In addition to the metal-molecule interaction, temperature affected the formation process of the single-molecule junction. The single pyrazine molecular junction formed between Au electrodes exhibited significant temperature dependence where the junction-formation probability was about 8% at 300 K, while there was no junction-formation at 100 K. Instead of the junction formation, an Au atomic wire was formed at the low temperature. This study provides insight into the tuning of the junction-forming process for single-molecule junctions, which is needed to construct device structures on a single molecule scale.

MODELING THE FORMATION OF GIANT PLANET CORES. I. EVALUATING KEY PROCESSES

International Nuclear Information System (INIS)

Levison, Harold F.; Thommes, Edward; Duncan, Martin J.

2010-01-01

One of the most challenging problems we face in our understanding of planet formation is how Jupiter and Saturn could have formed before the solar nebula dispersed. The most popular model of giant planet formation is the so-called core accretion model. In this model a large planetary embryo formed first, mainly by two-body accretion. This is then followed by a period of inflow of nebular gas directly onto the growing planet. The core accretion model has an Achilles heel, namely the very first step. We have undertaken the most comprehensive study of this process to date. In this study, we numerically integrate the orbits of a number of planetary embryos embedded in a swarm of planetesimals. In these experiments, we have included a large number of physical processes that might enhance accretion. In particular, we have included (1) aerodynamic gas drag, (2) collisional damping between planetesimals, (3) enhanced embryo cross sections due to their atmospheres, (4) planetesimal fragmentation, and (5) planetesimal-driven migration. We find that the gravitational interaction between the embryos and the planetesimals leads to the wholesale redistribution of material-regions are cleared of material and gaps open near the embryos. Indeed, in 90% of our simulations without fragmentation, the region near those embryos is cleared of planetesimals before much growth can occur. Thus, the widely used assumption that the surface density distribution of planetesimals is smooth can lead to misleading results. In the remaining 10% of our simulations, the embryos undergo a burst of outward migration that significantly increases growth. On timescales of ∼10 5 years, the outer embryo can migrate ∼6 AU and grow to roughly 30 M + . This represents a largely unexplored mode of core formation. We also find that the inclusion of planetesimal fragmentation tends to inhibit growth except for a narrow range of fragment migration rates.

Processes governing pinch formation in diodes

International Nuclear Information System (INIS)

Blaugrund, A.E.; Cooperstein, G.; Goldstein, S.A.

1975-01-01

The process of pinch formation in large aspect ratio diodes has been studied by means of streak photography and time-resolved x-ray detectors. A tight pinch is formed at the anode center by a collapsing thin hollow electron beam. The collapse velocity depends, among other things, on the type of material in the top 1 μm layer of the anode. In a tentative model it is assumed that an anode plasma is at least partially created from gases released from the surface layer of the anode by the heating action of the beam. These gases are ionized by primary, backscattered, and secondary electrons. Ions emitted from this plasma modify the electron trajectories in the diode leading to a radial collapse of the hollow electron beam. The observed monotonic dependence of the collapse velocity on the atomic number of the anode material can be explained by the smooth dependence on Z of both the specific heat and the electron backscatter coefficient. In the case of high-Z anodes the ion expansion time appears to be the factor limiting the collapse velocity. Detailed experimental data are presented

The Formation of Data on Nanotechnological Processes

Directory of Open Access Journals (Sweden)

Oleynik Olga Stepanovna

2015-05-01

Full Text Available The article presents the statistical monitoring of the main trends of nanotechnology development in Russia, as well as the review of the modern programs and documents devoted to urgent issues of nanotechnology development. The formation of system of statistical monitoring of nanotechnologies development in the Russian Federation includes the development of methodology and tools of statistical supervision over creation, commercialization, the use of nanotechnologies, and also the nanotechnological production. The authors carry out the analysis of the main directions and structure of co-funding of “The Program of nanotech industry development in the Russian Federation till 2015”. The sources of official statistical data on nanotechnologies in Russia are considered. The purpose of forming this essentially new direction of statistics consists in the creation of system of collecting, processing and submission of the regular, systematized and complex data which are adequately reflecting the state, the level of development and the prospects of nanotechnological sphere capacity which provide informational support to state policy and adoption of reasonable administrative decisions. The authors describe the system of statistical observations in the sphere of nanotechnologies. Today the statistics of nanotechnologies in Russia remains at the stage of formation and modernization according to the international standards, being supplemented every year with the new indicators which allow investigating different sides and tendencies of nanotech industry development. Nowadays the following aspects of the activity connected with nanotechnologies have already being studied by means of statistical methods: scientific research and developments; creation and use of nanotechnologies; demand for staff; production, including the innovative one.

Managing fear in public health campaigns: a theory-based formative evaluation process.

Science.gov (United States)

Cho, Hyunyi; Witte, Kim

2005-10-01

The HIV/AIDS infection rate of Ethiopia is one of the world's highest. Prevention campaigns should systematically incorporate and respond to at-risk population's existing beliefs, emotions, and perceived barriers in the message design process to effectively promote behavior change. However, guidelines for conducting formative evaluation that are grounded in proven risk communication theory and empirical data analysis techniques are hard to find. This article provides a five-step formative evaluation process that translates theory and research for developing effective messages for behavior change. Guided by the extended parallel process model, the five-step process helps message designers manage public's fear surrounding issues such as HIV/AIDS. An entertainment education project that used the process to design HIV/AIDS prevention messages for Ethiopian urban youth is reported. Data were collected in five urban regions of Ethiopia and analyzed according to the process to develop key messages for a 26-week radio soap opera.

Multi-format all-optical processing based on a large-scale, hybridly integrated photonic circuit.

Science.gov (United States)

Bougioukos, M; Kouloumentas, Ch; Spyropoulou, M; Giannoulis, G; Kalavrouziotis, D; Maziotis, A; Bakopoulos, P; Harmon, R; Rogers, D; Harrison, J; Poustie, A; Maxwell, G; Avramopoulos, H

2011-06-06

We investigate through numerical studies and experiments the performance of a large scale, silica-on-silicon photonic integrated circuit for multi-format regeneration and wavelength-conversion. The circuit encompasses a monolithically integrated array of four SOAs inside two parallel Mach-Zehnder structures, four delay interferometers and a large number of silica waveguides and couplers. Exploiting phase-incoherent techniques, the circuit is capable of processing OOK signals at variable bit rates, DPSK signals at 22 or 44 Gb/s and DQPSK signals at 44 Gbaud. Simulation studies reveal the wavelength-conversion potential of the circuit with enhanced regenerative capabilities for OOK and DPSK modulation formats and acceptable quality degradation for DQPSK format. Regeneration of 22 Gb/s OOK signals with amplified spontaneous emission (ASE) noise and DPSK data signals degraded with amplitude, phase and ASE noise is experimentally validated demonstrating a power penalty improvement up to 1.5 dB.

Study of Different Argillaceous Formations Performed in the Context of the FUNMIG project

Energy Technology Data Exchange (ETDEWEB)

Fernandez, A. M.; Melon, A.; Sanchez, D. M.; Gaucher, E.; Tournassat, C.; Altmann, S.C.; Vinsot, A.; Maes, N.; Craen, M. de; Leupin, O.; Wersin, P.; Astudillo, J.

2010-07-01

Argillaceous Rock Formations of low permeability have been selected in several countries as potential geological host rock for the disposal of high level radioactive wastes (HLRW). The general barrier function of the host rock is to retard and attenuate the migration of radionuclides to the biosphere, and the properties of clay minerals sustain this barrier functions. Nowadays, a number of Underground Research Laboratories (URL) have been constructed for a more in depth investigation of the indurated as well as plastic clay rock formations indifferent countries. The HADES under ground research facility (URF) was constructed at Mol (Belgium), where the Boom Clay formation is being studied as a reference host rock formation. The Opalinus Clay formation has been studied in the Mont Terri Rock Laboratory (Switzerland). The Callovo- Oxfordian clayrock is being characterised in the Meuse/Haute-Marne Site at Bure (France). The Boda Claystone is being analysed at Mecsek in Hungary. The knowledge on biogeochemical processes which affect the transport of radionuclides through the geosphere is a key parameter for the safety case of a HLRW repository, which was the aim of the EC Project FUNMIG: Fundamental Processes of Radionuclide Migration. The main factors controlling the mobility of the radionuclides are the chemistry of the pore water, the chemical reactions involving the radionuclides and the sorption processes on clay minerals. There fore, the pore water chemistry plays an important role in determining radionuclide migration characteristics in clay-rock formations. (Author)

Methods for Characterization of the Diesel Combustion and Emission Formation Processes

Energy Technology Data Exchange (ETDEWEB)

Lindstroem, Mikael

2011-07-01

In this thesis various aspects of the diesel engine fuel injection, combustion and emission formation processes have been evaluated. Several types of evaluation tools and methods have been applied. Fuel spray momentum was used to characterize injection rate and hole-to-hole variations in fuel injectors. Using both instantaneous fuel impulse rates and instantaneous mass flow measurements, spray velocity and nozzle flow parameters were evaluated. Several other hole-to-hole resolved injector characterization methods were used to characterize a set of fuel injectors subjected to long term testing. Fuel injector nozzle hole-to-hole variations were found to have a large influence on engine efficiency and emissions. The degree of hole-to-hole variations for an injector has been shown to correlate well with the performance deterioration of that injector. The formation and atomization of fuel sprays, ignition onset and the development of diffusion flames were studied using an optical engine. Flame temperature evaluations have been made using two different methods. NO-formation depends strongly on flame temperature. By applying a NO-formation evaluation method based on both heat release rate and flame and gas temperature it was possible to achieve a reasonable degree of correlation with measured exhaust emissions for very varying operating conditions. The prediction capability of the NO-formation evaluation method was utilized to evaluate spatially and temporally resolved NO-formation from flame temperature distributions. This made it possible to pinpoint areas with a high degree of NO-formation. It was found that small hot zones in the flames can be responsible for a large part of the total amount of NO that is produced, especially in combustion cases where no EGR is used to lower the flame temperature. By applying optical diagnostics methods the combustion and emission formation phenomena encountered during production engine transients were evaluated. The transient

"Formative ""Use"" of Assessment Information: It's a Process, so Let's Say What We Mean"

Directory of Open Access Journals (Sweden)

Robert Good

2011-02-01

Full Text Available The term formative assessment is often used to describe a type of assessment. The purpose of this paper is to challenge the use of this phrase given that formative assessment as a noun phrase ignores the well-established understanding that it is a process more than an object. A model that combines content, context, and strategies is presented as one way to view the process nature of assessing formatively. The alternate phrase formative use of assessment information is suggested as a more appropriate way to describe how content, context, and strategies can be used together in order to close the gap between where a student is performing currently and the intended learning goal.

Formation process of Malaysian modern architecture under influence of nationalism

OpenAIRE

宇高, 雄志; 山崎, 大智

2001-01-01

This paper examines the Formation Process of Malaysian Modern Architecture under Influence of Nationalism,through the process of independence of Malaysia. The national style as "Malaysian national architecture" which hasengaged on background of political environment under the post colonial situation. Malaysian urban design is alsodetermined under the balance of both of ethnic culture and the national culture. In Malaysia, they decided to choosethe Malay ethnic culture as the national culture....

Kinetic modeling studies of SOA formation from α-pinene ozonolysis

Science.gov (United States)

Gatzsche, Kathrin; Iinuma, Yoshiteru; Tilgner, Andreas; Mutzel, Anke; Berndt, Torsten; Wolke, Ralf

2017-11-01

This paper describes the implementation of a kinetic gas-particle partitioning approach used for the simulation of secondary organic aerosol (SOA) formation within the SPectral Aerosol Cloud Chemistry Interaction Model (SPACCIM). The kinetic partitioning considers the diffusion of organic compounds into aerosol particles and the subsequent chemical reactions in the particle phase. The basic kinetic partitioning approach is modified by the implementation of chemical backward reaction of the solute within the particle phase as well as a composition-dependent particle-phase bulk diffusion coefficient. The adapted gas-phase chemistry mechanism for α-pinene oxidation has been updated due to the recent findings related to the formation of highly oxidized multifunctional organic compounds (HOMs). Experimental results from a LEAK (Leipziger Aerosolkammer) chamber study for α-pinene ozonolysis were compared with the model results describing this reaction system.The performed model studies reveal that the particle-phase bulk diffusion coefficient and the particle-phase reactivity are key parameters for SOA formation. Using the same particle-phase reactivity for both cases, we find that liquid particles with higher particle-phase bulk diffusion coefficients have 310 times more organic material formed in the particle phase compared to higher viscous semi-solid particles with lower particle-phase bulk diffusion coefficients. The model results demonstrate that, even with a moderate particle-phase reactivity, about 61 % of the modeled organic mass consists of reaction products that are formed in the liquid particles. This finding emphasizes the potential role of SOA processing. Moreover, the initial organic aerosol mass concentration and the particle radius are of minor importance for the process of SOA formation in liquid particles. A sensitivity study shows that a 22-fold increase in particle size merely leads to a SOA increase of less than 10 %.Due to two additional

TRACKING THE PROCESSES OF MELANODIN FORMATION IN COFFEE

OpenAIRE

Snezhana Ivanova

2017-01-01

Melanoidins are high molecular brown colored substances and products of sugar-amine reaction of Maillard. They are formed during roasting a green coffee beans under different thermal regimes of heat treatment. In the technological production of different types coffee beverages, the coffee powder is subjected to after-heat treatment. In these additional operations again become active processes of melanoidin formation and their changing their structures. This is changes of the Melanoidins have ...

Process of film formation by anodizing AZ91D magnesium alloy

Energy Technology Data Exchange (ETDEWEB)

Qian Jiangang; Li Di; Zhang Feng [School of Materials Science and Engineering, Beijing Univ. of Aeronautics and Astronautics (China)

2005-07-01

The kinetics of film-forming process by anodizing AZ91D Mg alloy has been studied by ways of voltage-time and thickness-time curve, and the surface morphology, structure, composition and valence of element, phase constituent of anodic films have been analyzed by SEM, EDS, XPS and XRD respectively. The results show that the film-forming course can be divided into four stages. Formation of dense layer before sparking is the first stage. Formation of porous layer accompanied with a bit of small sparking is the second stage. Porous layer fast growth along with middle sparking is the third stage. Porous layer slowly-growth along with bigger sparking is the fourth stage. The anodic films contains approximately Mg,O,Si and B, which is composed mainly of MgO, MgSiO{sub 3} and Mg{sub 3}B{sub 2}O{sub 6}. (orig.)

Amorphous Calcium Phosphate Formation and Aggregation Process Revealed by Light Scattering Techniques

Directory of Open Access Journals (Sweden)

Vida Čadež

2018-06-01

Full Text Available Amorphous calcium phosphate (ACP attracts attention as a precursor of crystalline calcium phosphates (CaPs formation in vitro and in vivo as well as due to its excellent biological properties. Its formation can be considered to be an aggregation process. Although aggregation of ACP is of interest for both gaining a fundamental understanding of biominerals formation and in the synthesis of novel materials, it has still not been investigated in detail. In this work, the ACP aggregation was followed by two widely applied techniques suitable for following nanoparticles aggregation in general: dynamic light scattering (DLS and laser diffraction (LD. In addition, the ACP formation was followed by potentiometric measurements and formed precipitates were characterized by Fourier transform infrared spectroscopy (FTIR, powder X-ray diffraction (PXRD, transmission electron microscopy (TEM, and atomic force microscopy (AFM. The results showed that aggregation of ACP particles is a process which from the earliest stages simultaneously takes place at wide length scales, from nanometers to micrometers, leading to a highly polydisperse precipitation system, with polydispersity and vol. % of larger aggregates increasing with concentration. Obtained results provide insight into developing a way of regulating ACP and consequently CaP formation by controlling aggregation on the scale of interest.

Local Cloudiness Development Forecast Based on Simulation of Solid Phase Formation Processes in the Atmosphere

Science.gov (United States)

Barodka, Siarhei; Kliutko, Yauhenia; Krasouski, Alexander; Papko, Iryna; Svetashev, Alexander; Turishev, Leonid

2013-04-01

Nowadays numerical simulation of thundercloud formation processes is of great interest as an actual problem from the practical point of view. Thunderclouds significantly affect airplane flights, and mesoscale weather forecast has much to contribute to facilitate the aviation forecast procedures. An accurate forecast can certainly help to avoid aviation accidents due to weather conditions. The present study focuses on modelling of the convective clouds development and thunder clouds detection on the basis of mesoscale atmospheric processes simulation, aiming at significantly improving the aeronautical forecast. In the analysis, the primary weather radar information has been used to be further adapted for mesoscale forecast systems. Two types of domains have been selected for modelling: an internal one (with radius of 8 km), and an external one (with radius of 300 km). The internal domain has been directly applied to study the local clouds development, and the external domain data has been treated as initial and final conditions for cloud cover formation. The domain height has been chosen according to the civil aviation forecast data (i.e. not exceeding 14 km). Simulations of weather conditions and local clouds development have been made within selected domains with the WRF modelling system. In several cases, thunderclouds are detected within the convective clouds. To specify the given category of clouds, we employ a simulation technique of solid phase formation processes in the atmosphere. Based on modelling results, we construct vertical profiles indicating the amount of solid phase in the atmosphere. Furthermore, we obtain profiles demonstrating the amount of ice particles and large particles (hailstones). While simulating the processes of solid phase formation, we investigate vertical and horizontal air flows. Consequently, we attempt to separate the total amount of solid phase into categories of small ice particles, large ice particles and hailstones. Also, we

Influence of California-style black ripe olive processing on the formation of acrylamide.

Science.gov (United States)

Charoenprasert, Suthawan; Mitchell, Alyson

2014-08-27

Methods used in processing California-style black ripe olives generate acrylamide. California-style black ripe olives contain higher levels of acrylamide (409.67 ± 42.60-511.91 ± 34.08 μg kg(-1)) as compared to California-style green ripe olives (44.02 ± 3.55-105.79 ± 22.01 μg kg(-1)), Greek olives (influenced the formation of acrylamide in a time-dependent manner. Acrylamide increased during the first 30 days of storage. Longer brine storage times (>30 days) result in lower acrylamide levels in the finished product. The presence of calcium ions in the preprocessing brining solution results in higher levels of acrylamide in finished products. Air oxidation during lye processing and the neutralization of olives prior to sterilization significantly increase the formation of acrylamide in the finished products. Conversely, lye-processing decreases the levels of acrylamide in the final product. These results indicate that specific steps in the California-style black ripe olive processing may be manipulated to mitigate the formation of acrylamide in finished products.

Influence of calcination process on the formation of selected air pollutants

Directory of Open Access Journals (Sweden)

Wydrych Jacek

2017-01-01

Full Text Available The subject of the study is to analyze the phenomena of thermal flow in the precalcinator chamber of the exchanger's furnace tower including the combustion of coal dust and decarbonisation of raw lime powder. During the research were provided development of a mathematical model of particulate solid fuels combustion, calcining the raw material, NOx and COx formation. Moreover conducting the number for the current and the upgraded design of the precalcinator and analysis of the results. In this study, a mathematical model based on Euler's method to describe the motion of the gas phase and the Lagrange method to describe the motion of particles [1-4]. In the calculations there were assumed fractional particles raw material and fuel, and the following processes: flow of exhaust gases from the rotary kiln through the precalcinator chamber, heat exchange between the particles of raw material and exhaust gases, the additional fuel combustion in the precalcinator, the process of raw material calcination, transformation of gaseous substances, effect of the additional (tertiary air delivery on the processes in the chamber.

Level of processing modulates the neural correlates of emotional memory formation.

Science.gov (United States)

Ritchey, Maureen; LaBar, Kevin S; Cabeza, Roberto

2011-04-01

Emotion is known to influence multiple aspects of memory formation, including the initial encoding of the memory trace and its consolidation over time. However, the neural mechanisms whereby emotion impacts memory encoding remain largely unexplored. The present study used a levels-of-processing manipulation to characterize the impact of emotion on encoding with and without the influence of elaborative processes. Participants viewed emotionally negative, neutral, and positive scenes under two conditions: a shallow condition focused on the perceptual features of the scenes and a deep condition that queried their semantic meaning. Recognition memory was tested 2 days later. Results showed that emotional memory enhancements were greatest in the shallow condition. fMRI analyses revealed that the right amygdala predicted subsequent emotional memory in the shallow more than deep condition, whereas the right ventrolateral PFC demonstrated the reverse pattern. Furthermore, the association of these regions with the hippocampus was modulated by valence: the amygdala-hippocampal link was strongest for negative stimuli, whereas the prefrontal-hippocampal link was strongest for positive stimuli. Taken together, these results suggest two distinct activation patterns underlying emotional memory formation: an amygdala component that promotes memory during shallow encoding, especially for negative information, and a prefrontal component that provides extra benefits during deep encoding, especially for positive information.

Level of processing modulates the neural correlates of emotional memory formation

Science.gov (United States)

Ritchey, Maureen; LaBar, Kevin S.; Cabeza, Roberto

2010-01-01

Emotion is known to influence multiple aspects of memory formation, including the initial encoding of the memory trace and its consolidation over time. However, the neural mechanisms whereby emotion impacts memory encoding remain largely unexplored. The present study employed a levels-of-processing manipulation to characterize the impact of emotion on encoding with and without the influence of elaborative processes. Participants viewed emotionally negative, neutral, and positive scenes under two conditions: a shallow condition focused on the perceptual features of the scenes and a deep condition that queried their semantic meaning. Recognition memory was tested 2 days later. Results showed that emotional memory enhancements were greatest in the shallow condition. FMRI analyses revealed that the right amygdala predicted subsequent emotional memory in the shallow more than deep condition, whereas the right ventrolateral prefrontal cortex demonstrated the reverse pattern. Furthermore, the association of these regions with the hippocampus was modulated by valence: the amygdala-hippocampal link was strongest for negative stimuli, whereas the prefrontal-hippocampal link was strongest for positive stimuli. Taken together, these results suggest two distinct activation patterns underlying emotional memory formation: an amygdala component that promotes memory during shallow encoding, especially for negative information, and a prefrontal component that provides extra benefits during deep encoding, especially for positive information. PMID:20350176

Flame experiments at the advanced light source: new insights into soot formation processes.

Science.gov (United States)

Hansen, Nils; Skeen, Scott A; Michelsen, Hope A; Wilson, Kevin R; Kohse-Höinghaus, Katharina

2014-05-26

The following experimental protocols and the accompanying video are concerned with the flame experiments that are performed at the Chemical Dynamics Beamline of the Advanced Light Source (ALS) of the Lawrence Berkeley National Laboratory(1-4). This video demonstrates how the complex chemical structures of laboratory-based model flames are analyzed using flame-sampling mass spectrometry with tunable synchrotron-generated vacuum-ultraviolet (VUV) radiation. This experimental approach combines isomer-resolving capabilities with high sensitivity and a large dynamic range(5,6). The first part of the video describes experiments involving burner-stabilized, reduced-pressure (20-80 mbar) laminar premixed flames. A small hydrocarbon fuel was used for the selected flame to demonstrate the general experimental approach. It is shown how species' profiles are acquired as a function of distance from the burner surface and how the tunability of the VUV photon energy is used advantageously to identify many combustion intermediates based on their ionization energies. For example, this technique has been used to study gas-phase aspects of the soot-formation processes, and the video shows how the resonance-stabilized radicals, such as C3H3, C3H5, and i-C4H5, are identified as important intermediates(7). The work has been focused on soot formation processes, and, from the chemical point of view, this process is very intriguing because chemical structures containing millions of carbon atoms are assembled from a fuel molecule possessing only a few carbon atoms in just milliseconds. The second part of the video highlights a new experiment, in which an opposed-flow diffusion flame and synchrotron-based aerosol mass spectrometry are used to study the chemical composition of the combustion-generated soot particles(4). The experimental results indicate that the widely accepted H-abstraction-C2H2-addition (HACA) mechanism is not the sole molecular growth process responsible for the formation

Post-adsorption process of Yb phosphate nano-particle formation by Saccharomyces cerevisiae

Science.gov (United States)

Jiang, MingYu; Ohnuki, Toshihiko; Tanaka, Kazuya; Kozai, Naofumi; Kamiishi, Eigo; Utsunomiya, Satoshi

2012-09-01

In this study, we have investigated the post-adsorption process of ytterbium (Yb) phosphate nano-particle formation by Saccharomyces cerevisiae (yeast). The yeast grown in P-rich medium were exposed to 1.44 × 10-4 mol/L Yb(III) solution for 2-120 h, and 2 months at 25 ± 1 °C at an initial pH of 3, 4, or 5, respectively. Ytterbium concentrations in solutions decreased as a function of exposure time. Field-emission scanning electron microscopy equipped with energy-dispersive X-ray spectroscopy (FESEM), transmission electron microscopy (TEM), and synchrotron-based extended X-ray absorption fine structure (EXAFS) analyses revealed that nano-sized blocky Yb phosphate with an amorphous phase formed on the yeast cells surfaces in the solutions with Yb. These nano-sized precipitates that formed on the cell surfaces remained stable even after 2 months of exposure at 25 ± 1 °C around neutral pHs. The EXAFS data revealed that the chemical state of the accumulated Yb on the cell surfaces changed from the adsorption on both phosphate and carboxyl sites at 30 min to Yb phosphate precipitates at 5 days, indicating the Yb-phosphate precipitation as a major post-adsorption process. In addition, the precipitation of Yb phosphate occurred on cell surfaces during 7 days of exposure in Yb-free solution after 2 h of exposure (short-term Yb adsorption) in Yb solution. These results suggest that the released P from the inside of yeast cells reacted with adsorbed Yb on cell surfaces, resulting in the formation of Yb precipitates, even though no P was added to the exposure solution. In an abiotic system, the EXAFS data showed that the speciation of sorbed Yb on the reference materials, carboxymethyl cellulose and Ln resin, did not change even when the Yb was exposed to P solution, without forming Yb phosphate precipitates. This result strongly suggests that the cell surface of the yeast plays an important role in the Yb-phosphate precipitation process, not only as a carrier of the

Modelling dewatering behaviour through an understanding of solids formation processes. Part II--solids separation considerations.

Science.gov (United States)

Dustan, A C; Cohen, B; Petrie, J G

2005-05-30

An understanding of the mechanisms which control solids formation can provide information on the characteristics of the solids which are formed. The nature of the solids formed in turn impacts on dewatering behaviour. The 'upstream' solids formation determines a set of suspension characteristics: solids concentration, particle size distribution, solution ionic strength and electrostatic surface potential. These characteristics together define the suspension's rheological properties. However, the complicated interdependence of these has precluded the prediction of suspension rheology from such a fundamental description of suspension characteristics. Recent shear yield stress models, applied in this study to compressive yield, significantly reduce the empiricism required for the description of compressive rheology. Suspension compressibility and permeability uniquely define the dewatering behaviour, described in terms of settling, filtration and mechanical expression. These modes of dewatering may be described in terms of the same fundamental suspension mechanics model. In this way, it is possible to link dynamically the processes of solids formation and dewatering of the resultant suspension. This, ultimately, opens the door to improved operability of these processes. In part I of this paper we introduced an integrated system model for solids formation and dewatering. This model was demonstrated for the upstream processes using experimental data. In this current paper models of colloidal interactions and dewatering are presented and compared to experimental results from batch filtration tests. A novel approach to predicting suspension compressibility and permeability using a single test configuration is presented and tested.

Computational Study of Thrombus Formation and Clotting Factor Effects under Venous Flow Conditions

Science.gov (United States)

2016-04-26

domain used in our thrombus formation simulations. Fig. 2 B shows the 3D geometry of the flow-chamber section consisting of two channels measuring 250 60...ArticleComputational Study of Thrombus Formation and Clotting Factor Effects under Venous Flow ConditionsVijay Govindarajan,1 Vineet Rakesh,1 Jaques...understanding of thrombus formation as a physicochemical process that has evolved to protect the integrity of the human vasculature is critical to our ability to

EXPERIENCE OF INTRODUCTION IN EDUCATIONAL PROCESS OF COMPUTER SYSTEMS FOR FORMATION OF ACTIVE MATHEMATICAL ACTIVITY

Directory of Open Access Journals (Sweden)

L. Shishko

2012-03-01

Full Text Available Annotation In this article is described the information an experience of introduction in educational process of pedagogical program systems of support of practical activities for example pedagogical software "Algebra, 8 class" and also aspect of formation of mathematical activity during algebra studying.

Interspecies interactions result in enhanced biofilm formation by co-cultures of bacteria isolated from a food processing environment

DEFF Research Database (Denmark)

Røder, Henriette Lyng; Raghupathi, Prem Krishnan; Herschend, Jakob

2015-01-01

Bacterial attachment and biofilm formation can lead to poor hygienic conditions in food processing environments. Furthermore, interactions between different bacteria may induce or promote biofilm formation. In this study, we isolated and identified a total of 687 bacterial strains from seven......-culture biofilm production with high relevance for food safety and food production facilities....

Mass spectrometric studies of the cluster formation of radon progeny

Energy Technology Data Exchange (ETDEWEB)

Gong, S L [Toronto Univ., ON (Canada). Dept. of Chemical Engineering and Applied Chemistry

1994-12-31

A new experimental system is developed to study the cluster formation of radon progeny with neutral molecules in the environment, which includes a modified mass spectrometer and a surface barrier detector. With the system, the cluster research is carried out at molecular level at which the mass of individual cluster formed is measured. A theory is also proposed to treat the cluster formation as a discrete process based on the ion-dipole and dipole-dipole interactions. Comparison between the theory and experiment is given. (author). 16 refs., 6 figs.

Mass spectrometric studies of the cluster formation of radon progeny

International Nuclear Information System (INIS)

Gong, S.L.

1993-01-01

A new experimental system is developed to study the cluster formation of radon progeny with neutral molecules in the environment, which includes a modified mass spectrometer and a surface barrier detector. With the system, the cluster research is carried out at molecular level at which the mass of individual cluster formed is measured. A theory is also proposed to treat the cluster formation as a discrete process based on the ion-dipole and dipole-dipole interactions. Comparison between the theory and experiment is given. (author). 16 refs., 6 figs

E-cadherin junction formation involves an active kinetic nucleation process

Science.gov (United States)

Biswas, Kabir H.; Hartman, Kevin L.; Yu, Cheng-han; Harrison, Oliver J.; Song, Hang; Smith, Adam W.; Huang, William Y. C.; Lin, Wan-Chen; Guo, Zhenhuan; Padmanabhan, Anup; Troyanovsky, Sergey M.; Dustin, Michael L.; Shapiro, Lawrence; Honig, Barry; Zaidel-Bar, Ronen; Groves, Jay T.

2015-01-01

Epithelial (E)-cadherin-mediated cell−cell junctions play important roles in the development and maintenance of tissue structure in multicellular organisms. E-cadherin adhesion is thus a key element of the cellular microenvironment that provides both mechanical and biochemical signaling inputs. Here, we report in vitro reconstitution of junction-like structures between native E-cadherin in living cells and the extracellular domain of E-cadherin (E-cad-ECD) in a supported membrane. Junction formation in this hybrid live cell-supported membrane configuration requires both active processes within the living cell and a supported membrane with low E-cad-ECD mobility. The hybrid junctions recruit α-catenin and exhibit remodeled cortical actin. Observations suggest that the initial stages of junction formation in this hybrid system depend on the trans but not the cis interactions between E-cadherin molecules, and proceed via a nucleation process in which protrusion and retraction of filopodia play a key role. PMID:26290581

Energy-saving management modelling and optimization for lead-acid battery formation process

Science.gov (United States)

Wang, T.; Chen, Z.; Xu, J. Y.; Wang, F. Y.; Liu, H. M.

2017-11-01

In this context, a typical lead-acid battery producing process is introduced. Based on the formation process, an efficiency management method is proposed. An optimization model with the objective to minimize the formation electricity cost in a single period is established. This optimization model considers several related constraints, together with two influencing factors including the transformation efficiency of IGBT charge-and-discharge machine and the time-of-use price. An example simulation is shown using PSO algorithm to solve this mathematic model, and the proposed optimization strategy is proved to be effective and learnable for energy-saving and efficiency optimization in battery producing industries.

Bane of Hydrogen-Bond Formation on the Photoinduced Charge-Transfer Process in Donor–Acceptor Systems

KAUST Repository

Alsam, Amani Abdu

2017-03-14

Controlling the ultrafast dynamical process of photoinduced charge transfer at donor acceptor interfaces remains a major challenge for physical chemistry and solar cell communities. The process is complicated by the involvement of other complex dynamical processes, including hydrogen bond formation, energy transfer, and solvation dynamics occurring on similar time scales. In this study, we explore the remarkable impact of hydrogen-bond formation on the interfacial charge transfer between a negatively charged electron donating anionic porphyrin and a positively charged electron accepting pi-conjugated polymer, as a model system in solvents with different polarities and capabilities for hydiogen bonding using femtosecond transient absorption spectroscopy. Unlike the conventional understanding of the key role of hydrogen bonding in promoting the charge-transfer process, our steadystate and time-resolved results reveal that the intervening hydrogen-bonding environment and, consequently, the probable longer spacing between the donor and acceptor molecules significantly hinders the charge-transfer process between them. These results show that site-specific hydrogen bonding and geometric considerations between donor and acceptor can be exploited to control both the charge-transfer dynamics and its efficiency not only at donor acceptor interfaces but also in complex biological systems.

Formation of solid solution during mutual diffusion of tungsten and molybdenum in the process of sintering

International Nuclear Information System (INIS)

Timofeeva, A.A.; Bulat, I.B.; Voronin, Yu.V.; Fedoseev, G.K.; Karasev, V.M.

1984-01-01

A process of a solid solution homogenization during sintering of W-15Mo and W-5Mo alloys is studied by the methods of density measurements, analysis of the X-ray lines physical broadening and determination of crystalline lattice constant. Study of the process of solid solution formation under conditions of powder composite sintering is shown to be conducted with account of peculiarities of tungsten and molybdenum mutual diffusion in the investigated temperature range of concentrations

FORMATION PROCESS AND HISTORICAL FUNCTIONS OF OLD AKIHA ROAD

Science.gov (United States)

Nakane, Yoji; Okuda, Masao; Kani, Yukihiko; Hayakawa, Kiyoshi; Matsui, Tamotsu

An object of this study is the old Akiha road located along the southern parts of the Akaishi Mountains in Sizuoka Prefecture. The old Akiha road between Hamamatsu city in Enshu and Iida city in Shinshu had been utilized by people for the purposes of making a pilgrimage, megalithic faith, transporting obsidian since the primitive age, practicing the mountaineering asceticism, operating the military activities in the warlike age, transporting salt from coastal area to mountainous area and so on. Through the investigation of literature, site reconnaissance and hearing, the formation process and the historical functions of the old Akiha road were studied, including the situation in medieval times or before. As the results, it was elucidated that the oldest road between two cities had located over the Hyoukoshi Pass, the road routes had the lowering trend from mountainside to riverside, and the historical functions of old Akiha road were the passage for transportation of various kinds of goods and human being, faith and culture.

Neural Correlates of Auditory Processing, Learning and Memory Formation in Songbirds

Science.gov (United States)

Pinaud, R.; Terleph, T. A.; Wynne, R. D.; Tremere, L. A.

Songbirds have emerged as powerful experimental models for the study of auditory processing of complex natural communication signals. Intact hearing is necessary for several behaviors in developing and adult animals including vocal learning, territorial defense, mate selection and individual recognition. These behaviors are thought to require the processing, discrimination and memorization of songs. Although much is known about the brain circuits that participate in sensorimotor (auditory-vocal) integration, especially the ``song-control" system, less is known about the anatomical and functional organization of central auditory pathways. Here we discuss findings associated with a telencephalic auditory area known as the caudomedial nidopallium (NCM). NCM has attracted significant interest as it exhibits functional properties that may support higher order auditory functions such as stimulus discrimination and the formation of auditory memories. NCM neurons are vigorously dr iven by auditory stimuli. Interestingly, these responses are selective to conspecific, relative to heterospecific songs and artificial stimuli. In addition, forms of experience-dependent plasticity occur in NCM and are song-specific. Finally, recent experiments employing high-throughput quantitative proteomics suggest that complex protein regulatory pathways are engaged in NCM as a result of auditory experience. These molecular cascades are likely central to experience-associated plasticity of NCM circuitry and may be part of a network of calcium-driven molecular events that support the formation of auditory memory traces.

Formation of a Methodological Approach to Evaluating the State of Management of Enterprise Flow Processes

Directory of Open Access Journals (Sweden)

Dzobko Iryna P.

2016-02-01

Full Text Available The formation of a methodological approach to evaluating management of the state of enterprise flow processes has been considered. Proceeding from the developed and presented in literary sources theoretical propositions on organization of management of enterprise flow processes, the hypothesis of the study is correlation of quantitative and qualitative evaluations of management effectiveness and formation of the integral index on their basis. The article presents stages of implementation of a methodological approach to evaluating the state of management of enterprise flow processes, which implies indicating the components, their characteristics and methods of research. The composition of indicators, on the basis of which it is possible to evaluate effectiveness of management of enterprise flow processes, has been determined. Grouping of such indicators based on the flow nature of enterprise processes has been performed. The grouping of indicators is justified by a pairwise determination of canonical correlations between the selected groups (the obtained high correlation coefficients confirmed the author’s systematization of indicators. It is shown that a specificity of the formation of a methodological approach to evaluating the state of management of enterprise flow processes requires expansion in the direction of aggregation of the results and determination of factors that influence effectiveness of flow processes management. The article carries out such aggregation using the factor analysis. Distribution of a set of objects into different classes according to the results of the cluster analysis has been presented. To obtain an integral estimation of effectiveness of flow processes management, the taxonomic index of a multidimensional object has been built. A peculiarity of the formed methodological approach to evaluating the state of management of enterprise flow processes is in the matrix correlation of integral indicators calculated on

Features of destruction of solids by laser radiation in process of formation of multiply charged ions

International Nuclear Information System (INIS)

Bedilov, R.M.; Bedilov, M.R.; Sabitov, M.M.; Matnazarov, A.; Niyozov, B.

2004-01-01

Full text: It is known, under interaction of laser radiation with solid surface a power density q > 0.01 W/cm 2 are observed destruction of a solid and issue of electrons, ions, neutrals, neutrons, plasmas, and also radiation in a wide ranges of a spectra. Despite of a plenty of works, devoted to study of processes of interaction, the studies of feature of destruction of solids by laser beam in process of formation multiply charged ions are insufficiently investigated. The results of study feature of destruction of solids by laser radiation in process of formation multiply charged ions are given in this work. In our experiments, we used the mass spectrometer with single-channel laser radiation. The laser installation had the following parameters: a power density of laser radiation q=(0.1-50) GW/cm 2 ; the angle of incidence a=18 deg. to the target surface Al, (W). It was obtained experimentally dynamics of morphology of destruction and also mass - charge and energy spectra of multiply charged ions formed under interaction of laser radiation with Al (W) in the intensity range q=(0.1-50) GW/cm 2 . These studies showed features of destruction Al(W) by laser radiation, i.e. invariable of value evaporation mass from a surface of a solid increase as the laser intensity q. But thus temperature a pair increases in accordance with increase of flow density of a laser radiation. Increase of temperature the pair gives in formation of multiply charged plasma. It is typical that, as q of the laser increases the maximum charge number of ions in laser plasma considerably increase and their energy spectra extend toward higher energies. For example, under q=0.1 GW/cm 2 and 50 GW/cm 2 the maximum charge number of ions Al (W) are equal to Z max = 1 and 7, respectively. From the experimental data obtained, we can conclude that, the formed multiply charged plasma practically completely absorption laser radiation and 'shielding' a target surface for various metals at power densities

TEACHER ROLE IN FORMATION POLITENESS OF STUDENT LEARNING PROCESS

Directory of Open Access Journals (Sweden)

Wahyuni Oktavia

2016-09-01

Full Text Available Language as a communication tool has an important role in human interaction. Language can be used to convey ideas, ideas, feelings, desires, and so forth to others. To be able to communicate well certainly should be able to adjust the language used. One of the main functions of communication is to maintain the continuity of the relationship between the narrator and hearer. Language is an important pillar in the formation of character, in addition to religious education and moral education. In education, teachers must have pedagogical, professional, personal, and social. Teachers who have a good competence speech acts certainly have a good and well mannered to students. In the learning process, teachers and students communicate in give and receive course materials. The learning process is certainly not only provides knowledge alone, but give the values of character to students. In this case, the teacher must have a principle that must be controlled properly, correctly and precisely. Thus, teachers are expected to master the communication and understanding the principles of politeness in speaking well and correctly. The goal is a description of a form of politeness in the learning process. This research is a descriptive study which seeks to describe a form of politeness in the learning process. Data collection method used is the method refer to the data collection techniques are 1 recording technique using a tape recorder, and 2 technical note on the data card. Furthermore, methods of data analysis using pragmatic frontier.

A green non-acid-catalyzed process for direct N=N-C group formation: comprehensive study, modeling, and optimization.

Science.gov (United States)

Khakyzadeh, Vahid; Zolfigol, Mohammad Ali; Derakhshan-Panah, Fatemeh; Jafarian, Majid; Miri, Mir Vahid; Gilandoust, Maryam

2018-01-04

The aim of this work is to introduce, model, and optimize a new non-acid-catalyzed system for a direct N[Formula: see text]N-C bond formation. By reacting naphthols or phenol with anilines in the presence of the sodium nitrite as nitrosonium ([Formula: see text] source and triethylammonium acetate (TEAA), a N[Formula: see text]N-C group can be formed in non-acid media. Modeling and optimization of the reaction conditions were investigated by response surface method. Sodium nitrite, TEAA, and water were chosen as variables, and reaction yield was also monitored. Analysis of variance indicates that a second-order polynomial model with F value of 35.7, a P value of 0.0001, and regression coefficient of 0.93 is able to predict the response. Based on the model, the optimum process conditions were introduced as 2.2 mmol sodium nitrite, 2.2 mL of TEAA, and 0.5 mL [Formula: see text] at room temperature. A quadratic (second-order) polynomial model, by analysis of variance, was able to predict the response for a direct N=N-C group formation. Predicted response values were in good agreement with the experimental values. Electrochemistry studies were done to introduce new Michael acceptor moieties. Broad scope, high yields, short reaction time, and mild conditions are some advantages of the presented method.

[Study on formation process of honeycomb pattern in dielectric barrier discharge by optical emission spectrum].

Science.gov (United States)

Dong, Li-Fang; Zhu, Ping; Yang, Jing; Zhang, Yu

2014-04-01

The authors report on the first investigation of the variations in the plasma parameters in the formation process of the honeycomb pattern in a dielectric barrier discharge by optical emission spectrum in argon and air mixture. The discharge undergoes hexagonal lattice, concentric spot-ring pattern and honeycomb pattern with the applied voltage increasing. The molecular vibration temperature, electron excitation temperature and electronic density of the three kinds of patterns were investigated by the emission spectra of nitrogen band of second positive system (C3pi(u) --> B3 pi(g)), the relative intensity ratio method of spectral lines of Ar I 763.51 nm (2P(6) --> 1S(5)) and Ar I 772.42 nm (2P(2) -->1S(3)) and the broadening of spectral line 696.5 nm respectively. It was found that the molecular vibration temperature and electron excitation temperature of the honeycomb pattern are higher than those of the hexagonal lattice, but the electron density of the former is lower than that of the latter. The discharge powers of the patterns were also measured with the capacitance method. The discharge power of the honeycomb pattern is much higher than that of the hexagonal lattice. These results are of great importance to the formation mechanism of the patterns in dielectric barrier discharge.

Study on the formation of ozone gas in industrial irradiation process

Energy Technology Data Exchange (ETDEWEB)

Uzueli, Daniel H., E-mail: daniel.uzueli@usp.br [Universidade de Sao Paulo (USP), Sao Paulo, SP (Brazil). Centro de Medicina Nuclear. Hospital das Clinicas; Rela, Paulo R.; Vasquez, Pablo A.S.; Hamada, Margarida M.; Costa, Fabio E. da, E-mail: fecosta@ipen.br [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil)

2013-07-01

In industrial irradiators, the generated electromagnetic radiation or particles, such as gamma or X rays and electrons interact with air during the irradiation of products. In this gas layer, these effects cause the radiolysis in the constituent atoms, affecting mainly the oxygen atoms. This interaction is similar to what occurs in the stratosphere, when the diatomic molecule of oxygen (O{sub 2}) absorbs ultraviolet radiation from the sun, breaking the connection and separating it into two highly reactive atoms, which combined with another molecule of oxygen produce ozone (O{sub 3}). Ozone, at high altitudes, is beneficial and protects us from ultraviolet radiation. At low altitudes, it is a highly oxidizing gas and harmful to living beings. Aiming to study the formation and behavior of this gas in gamma irradiators, the measurements were made at a Multipurpose Gamma Facility from IPEN / CNEN-SP, which has cobalt-60 sources with a total activity of 5.22 PBq. (author)

Study on the formation of ozone gas in industrial irradiation process

International Nuclear Information System (INIS)

Uzueli, Daniel H.

2013-01-01

In industrial irradiators, the generated electromagnetic radiation or particles, such as gamma or X rays and electrons interact with air during the irradiation of products. In this gas layer, these effects cause the radiolysis in the constituent atoms, affecting mainly the oxygen atoms. This interaction is similar to what occurs in the stratosphere, when the diatomic molecule of oxygen (O 2 ) absorbs ultraviolet radiation from the sun, breaking the connection and separating it into two highly reactive atoms, which combined with another molecule of oxygen produce ozone (O 3 ). Ozone, at high altitudes, is beneficial and protects us from ultraviolet radiation. At low altitudes, it is a highly oxidizing gas and harmful to living beings. Aiming to study the formation and behavior of this gas in gamma irradiators, the measurements were made at a Multipurpose Gamma Facility from IPEN / CNEN-SP, which has cobalt-60 sources with a total activity of 5.22 PBq. (author)

chemical kinetic study of nitrogen oxides formation in methane flameless combustion

International Nuclear Information System (INIS)

Alvarado T, Pedro N; Cadavid S, Francisco; Mondragon, P Fanor; Ruiz, Wilson

2009-01-01

The present paper deals with the nitrogen oxides formation in a flameless combustion process characterized for using air highly diluted and preheated at high temperatures. The combustion model used in this study was the one dimensional counterflow methane air diffusion flame. The NOx production rate analysis showed that the thermal and prompt mechanisms are the most important for the formation and consumption of NO under dilution conditions for the oxidant in N 2 and combustion products. These mechanisms are related since the starting reaction for NO formation (N2 molecular dissociation) belongs to the prompt mechanism while the NO formation is reported mainly for the thermal mechanism reactions. On the other hand, the NO - NO 2 equilibrium showed that the reaction rates are comparable to that obtained by the thermal and prompt mechanisms, but its global contribution to NO formation are almost insignificant due to the oxidation reaction with radicals HO 2 .

Secondary organic aerosol formation through cloud processing of aromatic VOCs

Science.gov (United States)

Herckes, P.; Hutchings, J. W.; Ervens, B.

2010-12-01

Field observations have shown substantial concentrations (20-5,500 ng L-1) of aromatic volatile organic compounds (VOC) in cloud droplets. The potential generation of secondary organic aerosol mass through the processing of these anthropogenic VOCs was investigated through laboratory and modeling studies. Under simulated atmospheric laboratory conditions, in idealized solutions, benzene, toluene, ethylbenzene, and xylene (BTEX) degraded quickly in the aqueous phase. The degradation process yielded less volatile products which would contribute to new aerosol mass upon cloud evaporation. However, when realistic cloud solutions containing natural organic matter were used in the experiments, the reaction rates decreased with increasing organic carbon content. Kinetic data derived from these experiments were used as input to a multiphase box model in order to evaluate the secondary organic aerosol (SOA) mass formation potential of cloud processing of BTEX. Model results will be presented that quantify the SOA amounts from these aqueous phase pathways. The efficiency of this multiphase SOA source will be compared to SOA yields from the same aromatics as treated in traditional SOA models that are restricted to gas phase oxidation and subsequent condensation on particles.

The Mediating Role of Psychosocial Benefits in the Satisfaction Formation Process

NARCIS (Netherlands)

O. Prevo; P. Leunisse; H. Roest (Henk)

1999-01-01

textabstractIn this paper we investigate the mediating role of psychosocial benefits in the customer satisfaction/dissatisfaction formation process. Most research on this subject deals with the causality direction of psychosocial benefits and satisfaction, sometimes preceded by an overall functional

Carbon formation and metal dusting in advanced coal gasification processes

Energy Technology Data Exchange (ETDEWEB)

DeVan, J.H.; Tortorelli, P.F.; Judkins, R.R.; Wright, I.G.

1997-02-01

The product gases generated by coal gasification systems contain high concentrations of CO and, characteristically, have relatively high carbon activities. Accordingly, carbon deposition and metal dusting can potentially degrade the operation of such gasifier systems. Therefore, the product gas compositions of eight representative gasifier systems were examined with respect to the carbon activity of the gases at temperatures ranging from 480 to 1,090 C. Phase stability calculations indicated that Fe{sub 3}C is stable only under very limited thermodynamic conditions and with certain kinetic assumptions and that FeO and Fe{sub 0.877}S tend to form instead of the carbide. As formation of Fe{sub 3}C is a necessary step in the metal dusting of steels, there are numerous gasifier environments where this type of carbon-related degradation will not occur, particularly under conditions associated with higher oxygen and sulfur activities. These calculations also indicated that the removal of H{sub 2}S by a hot-gas cleanup system may have less effect on the formation of Fe{sub 3}C in air-blown gasifier environments, where the iron oxide phase can exist and is unaffected by the removal of sulfur, than in oxygen-blown systems, where iron sulfide provides the only potential barrier to Fe{sub 3}C formation. Use of carbon- and/or low-alloy steels dictates that the process gas composition be such that Fe{sub 3}C cannot form if the potential for metal dusting is to be eliminated. Alternatively, process modifications could include the reintroduction of hydrogen sulfide, cooling the gas to perhaps as low as 400 C and/or steam injection. If higher-alloy steels are used, a hydrogen sulfide-free gas may be processed without concern about carbon deposition and metal dusting.

Atomistic study on the interaction of nitrogen and Mg lattice and the nitride formation in nanocrystalline Mg alloys synthesized using cryomilling process

International Nuclear Information System (INIS)

Nezafati, Marjan; Giri, Anit; Hofmeister, Clara; Cho, Kyu; Schneider, Matthew M.; Zhou, Le; Sohn, Yongho; Kim, Chang-Soo

2016-01-01

Cryomilling is a broadly applied technique to synthesize nanostructured alloys and composites through powder metallurgy (PM) processing. Understanding the interactions between liquid nitrogen and the nanostructured metal powder is important as it can potentially impact the mechanical performance of these materials. In this study, we performed a series of ab initio density functional theory (DFT) computations to examine the interactions of liquid nitrogen and Mg-based matrices and the formation of Mg-nitrides. The diffusion energy barriers of nitrogen in the Mg and/or Mg-Al alloys were systematically quantified by calculating the transition state (TS) for the displacement of nitrogen between two neighboring equivalent positions. The TS calculation results indicate that diffusion of N atoms is much easier than that of N 2  molecule in the Mg matrix. It is predicted that at least ∼0.4 eV is required to overcome the diffusion energy barrier in the Mg matrix. We also quantified the formation energy of Mg nitride in the matrix. The presence of Mg nitride was demonstrated experimentally using transmission electron microscopy (TEM) and electron energy-loss spectroscopy (EELS). In conjunction with the DFT computations and TEM/EELS analysis, we performed analytical calculations for the strain energy introduced during cryomilling to examine the impacts of processing parameters.

Enhancing and accelarating flavour formation by salt-tolerant yeasts in Japanese soy-sauce processes

NARCIS (Netherlands)

Sluis, van der C.; Tramper, J.; Wijffels, R.H.

2001-01-01

In soy-sauce processes salt-tolerant yeasts are very important for the flavour formation. This flavour formation is, however, slow and poorly understood. In the last decades, a concerted research effort has increased the understanding and resulted in the derivation of mutants with an enhanced

Researching International Processes of Education Policy Formation: Conceptual and Methodological Considerations

Science.gov (United States)

Edwards, D. Brent, Jr.

2012-01-01

This article elaborates one approach to conceptualizing and investigating international processes of education policy formation (IPEPF), which are dynamic, multi-level and processual in nature. This contribution is important because, although research is increasingly conducted on phenomena with such characteristics, extended discussions of how…

Influence of osmotic processes on the excess-hydraulic head measured in the Toarcian/Domerian argillaceous formation of Tournemire

International Nuclear Information System (INIS)

Tremosa, J.

2010-01-01

In the framework of the studies dealing on ability to store radioactive wastes in argillaceous formations, signification of interstitial pressures is an important point to understand water and solutes transport. In very low permeability argillaceous formations, like those studied in the Callovo-Oxfordian of the Paris basin by ANDRA, pore pressure is frequently higher than the theoretical hydrostatic pressure or than the pressure in the surrounding aquifers. Such an overpressure is also measured in the Toarcian/Domerian argillaceous formation (k = 10 -21 m 2 ), studied by the IRSN in the underground research laboratory of Tournemire (Aveyron, France). The hydraulic head profile has been specified in this manuscript and found to present a 30 ±10 m excess head. This excess-head can be due to compaction disequilibrium of the argillaceous formation, diagenetic evolution of the rock, tectonic compression, changes in hydrodynamic boundary conditions or osmotic processes. Amongst these potential causes, chemical osmosis and thermo-osmosis, a fluid flow under a chemical concentration and a temperature gradient, respectively, are expected to develop owing to the small pore size and the electrostatic interactions related to the charged surface of clay minerals. The goal of the work presented here was to study and quantify the contribution of each cause to the measured excess-head. Chemo-osmotic and thermo-osmotic permeabilities were obtained by experiments and using theoretical models. Theoretical models are based on the reproduction of the interactions occurring between the charged surface of clay minerals and pore solution and their up-scaling at the representative elementary volume macroscopic scale. Chemical osmosis phenomenon is related to anionic exclusion and the determination of the chemo-osmotic efficiency requires the resolution of an electrical interactions model. A triple-layer-model which considers diffuse layers overlapping was improved during this thesis to be

Formation of Nb3Al in powder processed Nb-Al superconductors

International Nuclear Information System (INIS)

Johnson, P.E.

1987-05-01

In high magnetic fields, the critical current density is strongly dependent on the upper critical field, which is determined primarily by the stoichiometry of the Nb 3 Al. The critical temperature (T/sub c/), like the upper critical field, is considered to be a measure of the ''intrinsic'' quality of the superconductor, indicating the stoichiometry, order, and strain. If the A15 phase is stoichiometric and well ordered, a high T/sub c/ (and high H/sub C 2 /) is expected, regardless of the volume fraction of superconductor. On the other hand, if sigma phase is present with the A15, the resultant composition gradient across the sigma-A15 interface(s) requires that some of the A15 be off-stoichiometric, and therefore that the T/sub c/ (and H/sub C 2 /) be low. Thus the extent of the A15 (Nb 3 Al) reaction and the quality of the A15 formed are interdependent. This work focuses on the factors that control the extent of Nb 3 Al formation in Nb/Al powder wires. The morphology and content of the reacted and unreacted wires are studied in optical, SEM, and TEM micrographs. Critical current density data and its dependence on processing are explained in terms of the unreacted microstructure and its effect on the extent of Nb 3 Al formation. As a method of improving the critical current density, a new variation of the conventional powder process for wire manufacturing is developed and tested

Merging constitutional and motional covalent dynamics in reversible imine formation and exchange processes.

Science.gov (United States)

Kovaříček, Petr; Lehn, Jean-Marie

2012-06-06

The formation and exchange processes of imines of salicylaldehyde, pyridine-2-carboxaldehyde, and benzaldehyde have been studied, showing that the former has features of particular interest for dynamic covalent chemistry, displaying high efficiency and fast rates. The monoimines formed with aliphatic α,ω-diamines display an internal exchange process of self-transimination type, inducing a local motion of either "stepping-in-place" or "single-step" type by bond interchange, whose rate decreases rapidly with the distance of the terminal amino groups. Control of the speed of the process over a wide range may be achieved by substituents, solvent composition, and temperature. These monoimines also undergo intermolecular exchange, thus merging motional and constitutional covalent behavior within the same molecule. With polyamines, the monoimines formed execute internal motions that have been characterized by extensive one-dimensional, two-dimensional, and EXSY proton NMR studies. In particular, with linear polyamines, nondirectional displacement occurs by shifting of the aldehyde residue along the polyamine chain serving as molecular track. Imines thus behave as simple prototypes of systems displaying relative motions of molecular moieties, a subject of high current interest in the investigation of synthetic and biological molecular motors. The motional processes described are of dynamic covalent nature and take place without change in molecular constitution. They thus represent a category of dynamic covalent motions, resulting from reversible covalent bond formation and dissociation. They extend dynamic covalent chemistry into the area of molecular motions. A major further step will be to achieve control of directionality. The results reported here for imines open wide perspectives, together with other chemical groups, for the implementation of such features in multifunctional molecules toward the design of molecular devices presenting a complex combination of

EXPERIMENTAL AND COMPUTATIONAL STUDIES OF THE FORMATION MECHANISM OF PROTONATED INTERSTELLAR DIAZINES

Energy Technology Data Exchange (ETDEWEB)

Wang, Zhe-Chen; Cole, Callie A.; Bierbaum, Veronica M. [Department of Chemistry and Biochemistry, University of Colorado, Boulder, CO 80309 (United States); Snow, Theodore P., E-mail: zhwa4666@colorado.edu [Department of Astrophysical and Planetary Sciences, University of Colorado, Boulder, CO 80309 (United States)

2015-01-10

Studies of interstellar chemistry have grown in number and complexity by both observations and laboratory measurements, and nitrogen-containing aromatics have been implicated as important interstellar molecules. In this paper, the gas-phase collision induced dissociation (CID) processes of protonated pyridazine (1,2-diazine), pyrimidine (1,3-diazine), and pyrazine (1,4-diazine) cations (C{sub 4}H{sub 5}N{sub 2} {sup +}) are investigated in detail both experimentally and theoretically. The major neutral loss for all three CID processes is HCN, leading to the formation of C{sub 3}H{sub 4}N{sup +} isomers; our density functional theory (DFT) calculations support and elucidate our experimental results. The formation of C{sub 3}H{sub 4}N{sup +} isomers from the reaction of abundant interstellar acrylonitrile (CH{sub 2}CHCN) and H{sup +}is also studied employing DFT calculations. Our results lead to a novel mechanism for interstellar protonated diazine formation from the consecutive reactions of CH{sub 2}CHCN+ H{sup +} + HCN. Moreover, our results motivate the continuing search for interstellar C{sub 3}H{sub 4}N{sup +} isomers as well as polycyclic aromatic N-containing hydrocarbons (PANHs)

3. The Formation of Musical Competences: Methodological Approachesin the Process of Artistic-Aesthetic Acquisition

Directory of Open Access Journals (Sweden)

Crişciuc Viorica

2016-03-01

Full Text Available The article hereby includes conceptual aspects of the musical competences formation. It describes the realization of this process operating with the concepts of well-known occidental, Russian and local researchers. One of the ideas characteristic to the researchers’ pedagogical thinking is that, during the process of musical competence formation through art, the acquisition process mechanism is happening. For integrity in insuring the practical realization at of a musical education, the methodology we propose is based on research, an imposing theoretical network of successful pedagogical practices of remarkable scientists from all over the world. The analyzed theories are a source of inspiration and constitute the theoretical universe which contributes to as truthful as possible musical education.

Spiral Structure and Global Star Formation Processes in M 51

Science.gov (United States)

Gruendl, Robert A.

1994-12-01

The nearby grand design spiral galaxy, M 51, is an obvious proving ground for studies of spiral structure and large scale star formation processes. New near--infrared observations of M 51 made with COB (Cryogenic Optical Bench) on the Kitt Peak 1.3m allow us to examine the stellar distribution and the young star formation regions as well as probe regions of high extinction such as dust lanes. We also present an analysis of the kinematics of the ionized gas observed with the Maryland--Caltech Imaging Fabry Perot. The color information we derive from the near--infrared bands provides a more accurate tracer of extinction than optical observations. We find that the dust extinction and CO emission in the arms are well correlated. Our kinematic data show unambiguously that these dense gas concentrations are associated with kinematic perturbations. In the inner disk, these perturbations are seen to be consistent with the streaming motions predicted by classical density wave theory. The dust lanes, and presumably the molecular arms, form a narrow ridge that matches these velocity perturbations wherever the viewing angle is appropriate. This interpretation requires that the corotation radius be inward of the outer tidal arms. The outer tidal arms however show streaming velocities of the sign that would be expected interior to the corotation point. This can be reconciled if the outer arms are part of a second spiral pattern, most likely due to the interaction with the companion NGC 5195. The near--infrared observations also show emission from the massive star forming regions. These observations are less affected by extinction than optical observations of H II regions and show clearly that the sites of massive star formation are correlated with but downstream from the concentrations of dense molecular material. This provides clear evidence that the ISM has been organized by the streaming motions which have in turn triggered massive star formation.

Studies on uranium ore processing

International Nuclear Information System (INIS)

Suh, I.S.; Chun, J.K.; Park, S.W.; Choi, S.J.; Lee, C.H.; Chung, M.K.; Lim, J.K.

1983-01-01

For the exploitation of domestic uranium ore deposit, comprehensive studies on uranium ore processing of the Geum-San pit ore are carried out. Physical and chemical characteristics of the Geum-San ore are similar to those of Goe-San ore and the physical beneficiation could not be applicable. Optimum operating conditions such as uranium leaching, solid-liquid separation, solvent extraction and precipitation of yellow cake are found out and the results are confirmed by the continous operation of the micro-plant with the capacity of 50Kg, ore/day. In order to improve the process of ore milling pilot plant installed recently, the feasibility of raffinate-recycle and the precipitation methods of yellow cake are intensively examined. It was suggested that the raffinate-recycle in the leaching of filtering stage could be reduced the environmental contamination and the peroxide precipitation technique was applicable to improve the purity of yellow cake. The mechanism and conditions the third phase formation are thoroughly studied and confirmed by chemical analysis of the third phase actually formed during the operation of pilot plant. The major constituents of the third phase are polyanions such as PMosub(12)Osub(40)sup(3-) or SiMosub(12)Osub(40)sup(4-). And the formation of these polyanions could be reduced by the control of redox potential and the addition of modifier. (Author)

The role of the dinuclear system in the processes of nuclear fusion, quasi-fission, fission and cluster formation

International Nuclear Information System (INIS)

Volkov, V.V.

1999-01-01

The nuclear fusion, quasi-fission, fission and cluster formation in an excited nucleus are considered as the processes of the formation and evolution of the dinuclear system. This approach allows one to reveal new aspects of nuclear fusion, to show that quasi-fission plays an important role in nuclear reactions used to synthesise superheavy elements. A qualitative picture is given of the fission process of an excited nucleus and an important role of cluster formation in this process is shown

First-principles study of the formation of glycine-producing radicals from common interstellar species

Science.gov (United States)

Sato, Akimasa; Kitazawa, Yuya; Ochi, Toshiro; Shoji, Mitsuo; Komatsu, Yu; Kayanuma, Megumi; Aikawa, Yuri; Umemura, Masayuki; Shigeta, Yasuteru

2018-03-01

Glycine, the simplest amino acid, has been intensively searched for in molecular clouds, and the comprehensive clarification of the formation path of interstellar glycine is now imperative. Among all the possible glycine formation pathways, we focused on the radical pathways revealed by Garrod (2013). In the present study, we have precisely investigated all the chemical reaction steps related to the glycine formation processes based on state-of-the-art density functional theory (DFT) calculations. We found that two reaction pathways require small activation barriers (ΔE‡ ≤ 7.75 kJ mol-1), which demonstrates the possibility of glycine formation even at low temperatures in interstellar space if the radical species are generated. The origin of carbon and nitrogen in the glycine backbone and their combination patterns are further discussed in relation to the formation mechanisms. According to the clarification of the atomic correspondence between glycine and its potential parental molecules, it is shown that the nitrogen and two carbons in the glycine can originate in three common interstellar molecules, methanol, hydrogen cyanide, and ammonia, and that the source molecules of glycine can be described by any of their combinations. The glycine formation processes can be categorized into six patterns. Finally, we discussed two other glycine formation pathways expected from the present DFT calculation results.

Mössbauer spectroscopy study of surfactant sputtering induced Fe silicide formation on a Si surface

Energy Technology Data Exchange (ETDEWEB)

Beckmann, C.; Zhang, K. [2nd Institute of Physics, University of Göttingen, Friedrich-Hund-Platz 1, 37077 Göttingen (Germany); Hofsäss, H., E-mail: hans.hofsaess@phys.uni-goettingen.de [2nd Institute of Physics, University of Göttingen, Friedrich-Hund-Platz 1, 37077 Göttingen (Germany); Brüsewitz, C.; Vetter, U. [2nd Institute of Physics, University of Göttingen, Friedrich-Hund-Platz 1, 37077 Göttingen (Germany); Bharuth-Ram, K. [Physics Department, Durban University of Technology, Durban 4001 (South Africa)

2015-12-01

Highlights: • We study the formation of self-organized nanoscale dot and ripple patterns on Si. • Patterns are created by keV noble gas ion irradiation and simultaneous {sup 57}Fe co-deposition. • Ion-induced phase separation and the formation of a-FeSi{sub 2} is identified as relevant process. - Abstract: The formation of Fe silicides in surface ripple patterns, generated by erosion of a Si surface with keV Ar and Xe ions and simultaneous co-deposition of Fe, was investigated with conversion electron Mössbauer spectroscopy, atomic force microscopy and Rutherford backscattering spectrometry. For the dot and ripple patterns studied, we find an average Fe concentration in the irradiated layer between 6 and 25 at.%. The Mössbauer spectra clearly show evidence of the formation of Fe disilicides with Fe content close to 33 at.%, but very little evidence of the formation of metallic Fe particles. The results support the process of ion-induced phase separation toward an amorphous Fe disilicide phase as pattern generation mechanism. The observed amorphous phase is in agreement with thermodynamic calculations of amorphous Fe silicides.

Experimental demonstration of a format-flexible single-carrier coherent receiver using data-aided digital signal processing.

Science.gov (United States)

Elschner, Robert; Frey, Felix; Meuer, Christian; Fischer, Johannes Karl; Alreesh, Saleem; Schmidt-Langhorst, Carsten; Molle, Lutz; Tanimura, Takahito; Schubert, Colja

2012-12-17

We experimentally demonstrate the use of data-aided digital signal processing for format-flexible coherent reception of different 28-GBd PDM and 4D modulated signals in WDM transmission experiments over up to 7680 km SSMF by using the same resource-efficient digital signal processing algorithms for the equalization of all formats. Stable and regular performance in the nonlinear transmission regime is confirmed.

Self-organization processes and nanocluster formation in crystal lattices by low-energy ion irradiation

International Nuclear Information System (INIS)

Tereshko, I.; Abidzina, V.; Tereshko, A.; Glushchenko, V.; Elkin, I.

2007-01-01

The goal of this paper is to study self-organization processes that cause nanostructural evolution in nonlinear crystal media. The subjects of the investigation were nonlinear homogeneous and heterogeneous atom chains. The method of computer simulation was used to investigate the interaction between low-energy ions and crystal lattices. It was based on the conception of three-dimensional lattice as a nonlinear atom chain system. We showed that that in homogeneous atom chains critical energy needed for self-organization processes development is less than for nonlinear atom chain with already embedded clusters. The possibility of nanostructure formation was studied by a molecular dynamics method of nonlinear oscillations in atomic oscillator systems of crystal lattices after their low-energy ion irradiation. (authors)

Formation of porous surface layers in reaction bonded silicon nitride during processing

Science.gov (United States)

Shaw, N. J.; Glasgow, T. K.

1979-01-01

Microstructural examination of reaction bonded silicon nitride (RBSN) has shown that there is often a region adjacent to the as-nitrided surfaces that is even more porous than the interior of this already quite porous material. Because this layer of large porosity is considered detrimental to both the strength and oxidation resistance of RBSN, a study was undertaken to determine if its formation could be prevented during processing. All test bars studied were made from a single batch of Si powder which was milled for 4 hours in heptane in a vibratory mill using high density alumina cylinders as the grinding media. After air drying the powder, bars were compacted in a single acting die and hydropressed.

Cartilaginous Metabolomic Study Reveals Potential Mechanisms of Osteophyte Formation in Osteoarthritis.

Science.gov (United States)

Xu, Zhongwei; Chen, Tingmei; Luo, Jiao; Ding, Shijia; Gao, Sichuan; Zhang, Jian

2017-04-07

Osteophyte is one of the inevitable consequences of progressive osteoarthritis with the main characteristics of cartilage degeneration and endochondral ossification. The pathogenesis of osteophyte formation is not fully understood to date. In this work, metabolomic approaches were employed to explore potential mechanisms of osteophyte formation by detecting metabolic variations between extracts of osteophyte cartilage tissues (n = 32) and uninvolved control cartilage tissues (n = 34), based on the platform of ultraperformance liquid chromatography tandem quadrupole time-of-flight mass spectrometry, as well as the use of multivariate statistic analysis and univariate statistic analysis. The osteophyte group was significantly separated from the control group by the orthogonal partial least-squares discriminant analysis models, indicating that metabolic state of osteophyte cartilage had been changed. In total, 28 metabolic variations further validated by mass spectrum (MS) match, tandom mass spectrum (MS/MS) match, and standards match mainly included amino acids, sulfonic acids, glycerophospholipids, and fatty acyls. These metabolites were related to some specific physiological or pathological processes (collagen dissolution, boundary layers destroyed, self-restoration triggered, etc.) which might be associated with the procedure of osteophyte formation. Pathway analysis showed phenylalanine metabolism (PI = 0.168, p = 0.004) was highly correlative to this degenerative process. Our findings provided a direction for targeted metabolomic study and an insight into further reveal the molecular mechanisms of ostophyte formation.

Formation and filtration characteristics of solids generated in a high level liquid waste treatment process. Solids formation behavior from simulated high level liquid waste

International Nuclear Information System (INIS)

Kondo, Y.; Kubota, M.

1997-01-01

The solids formation behavior in a simulated high level liquid waste (HLLW) was experimentally examined, when the simulated HLLW was treated in the ordinary way of actual HLLW treatment process. Solids formation conditions and mechanism were closely discussed. The solids formation during a concentration step can be explained by considering the formation of zirconium phosphate, phosphomolybdic acid and precipitation of strontium and barium nitrates and their solubilities. For the solids formation during the denitration step, at least four courses were observed; formation of an undissolved material by a chemical reaction with each other of solute elements (zirconium, molybdenum, tellurium) precipitation by reduction (platinum group metals) formation of hydroxide or carbonate compounds (chromium, neodymium, iron, nickel, strontium, barium) and a physical adsorption to stable solid such as zirconium molybdate (nickel, strontium, barium). (author)

HPDB-Haskell library for processing atomic biomolecular structures in Protein Data Bank format.

Science.gov (United States)

Gajda, Michał Jan

2013-11-23

Protein DataBank file format is used for the majority of biomolecular data available today. Haskell is a lazy functional language that enjoys a high-level class-based type system, a growing collection of useful libraries and a reputation for efficiency. I present a fast library for processing biomolecular data in the Protein Data Bank format. I present benchmarks indicating that this library is faster than other frequently used Protein Data Bank parsing programs. The proposed library also features a convenient iterator mechanism, and a simple API modeled after BioPython. I set a new standard for convenience and efficiency of Protein Data Bank processing in a Haskell library, and release it to open source.

[The effect of encoding on false memory: examination on levels of processing and list presentation format].

Science.gov (United States)

Hamajima, Hideki

2004-04-01

Using the Deese/Roediger-McDermott paradigm, the effects of lists presentation format (blocked/random) and levels of processing of critical nonpresented lures were examined. A levels-of-processing effect in a blocked presentation order was not observed for lures. Rates of false recognition and remember judgments for lures in a shallow level of processing were significantly lower than those in a deep level of processing when items from various themes were inter-mixed instead of blocked. Results showed an interaction between levels of processing and list presentation format. It is thus concluded that encoding of each word and whole list should be both considered in understanding false memory.

Various processes occurring in strong interactions between heavy ions: Compound nucleus formation, incomplete fusion, and quasifission

International Nuclear Information System (INIS)

Lefort, M.

1975-01-01

This paper deals with the problem of various deep processes occurring when two complex nuclei enter in collision. It is suggested that very deep inelastic processes may lead to either a compound nucleus or a composite system which shortly decays into two fission fragments (quasifission process). Particularly for heavy projectiles and targets, the predominant Coulomb potential inhibits the compound nucleus formation for low l waves. Then a critical angular momentum can be defined as the limit below which both processes (quasifission and compound nucleus formation) occur. For the heaviest nuclei, nearly all l waves below l) contribute to the quasifission phenomenon

Television Format As a Site of Cultural Negotiation: Studying the Structures, Agencies and Practices of Format Adaptation

NARCIS (Netherlands)

Keinonen, Heidi

2016-01-01

abstractDespite the growing number of publications on television formats, specific theorisations regarding formats and format adaptation, in particular, are still rare. In this article, I introduce a synthesizing approach for studying format appropriation. Drawing on format study, media industry

Patterning nanostructures to study magnetization processes

International Nuclear Information System (INIS)

Atkinson, D

2005-01-01

Lithography techniques such as electron-beam lithography and focused-ion-beam milling are widely used to fabricate structures with dimensions well below 1 μm. These techniques have been used to produce planar magnetic structures with sub-micrometer dimensions and well controlled geometry. This has allowed the study of basic magnetic behaviour and the development of structures with potential for applications in magnetic recording and magnetic logic devices. The techniques of electron beam lithography and focused-ion-beam milling for the fabrication of magnetic nanostructures are outlined here. These techniques have been used to fabricate ribbon-like planar nanowires to study the behaviour of the individual magnetic domain walls which mediate the reversal process in such elongated structures. These methods allow the production of structures in which the location of domain wall formation and position can be controlled, allowing separation and study of the domain wall nucleation and propagation processes. Domain wall injection and domain wall propagation behaviour are investigated and shown to be stochastic processes

Microstructures and formation mechanism of hypoeutectic white cast iron by isothermal electromagnetic rheocast process

Directory of Open Access Journals (Sweden)

Zhang Wanning

2010-05-01

Full Text Available An investigation was made on the evolution of microstructures of hypoeutectic white cast iron slurry containing 2.5wt.%C and 1.8wt.%Si produced by rheocasting in which the solidifying alloy was vigorously agitated by electromagnetic stirrer during isothermal cooling processes. The results indicated that under the proper agitating temperatures and speeds applied, the dendrite structures in white cast iron slurry were gradually evolved into spherical structures during a certain agitating time. It also revealed that the bent dendrites were formed by either convection force or by the growth of the dendrites themselves in the bending direction; then, as they were in solidifying, they were gradually being alternated into separated particles and into more spherical structures at the end of the isothermal cooling process. Especially, the dendrites were granulated as the bending process proceeding, which suggested that they were caused by unwanted elements such as sulfur and phosphor usually contained in engineering cast iron. Convective flow of the melt caused corrosion on the dendritic segments where they were weaker in strength and lower in melting temperature because of higher concentration of sulfur or phosphor. And the granulation process for such dendrites formed in the melt became possible under the condition. Certainly, dendrite fragments are another factors considerable to function for spherical particles formation. A new mechanism, regarding to the rheocast structure formation of white cast iron, was suggested based on the structural evolution observed in the study.

Finite element simulation of dynamic wetting flows as an interface formation process

KAUST Repository

Sprittles, J.E.; Shikhmurzaev, Y.D.

2013-01-01

A mathematically challenging model of dynamic wetting as a process of interface formation has been, for the first time, fully incorporated into a numerical code based on the finite element method and applied, as a test case, to the problem

Carbon Disulfide (CS2) Mechanisms in Formation of Atmospheric Carbon Dioxide (CO2) Formation from Unconventional Shale Gas Extraction and Processing Operations and Global Climate Change.

Science.gov (United States)

Rich, Alisa L; Patel, Jay T

2015-01-01

Carbon disulfide (CS2) has been historically associated with the production of rayon, cellophane, and carbon tetrachloride. This study identifies multiple mechanisms by which CS2 contributes to the formation of CO2 in the atmosphere. CS2 and other associated sulfide compounds were found by this study to be present in emissions from unconventional shale gas extraction and processing (E&P) operations. The breakdown products of CS2; carbonyl sulfide (COS), carbon monoxide (CO), and sulfur dioxide (SO2) are indirect greenhouse gases (GHGs) that contribute to CO2 levels in the atmosphere. The heat-trapping nature of CO2 has been found to increase the surface temperature, resulting in regional and global climate change. The purpose of this study is to identify five mechanisms by which CS2 and the breakdown products of CS2 contribute to atmospheric concentrations of CO2. The five mechanisms of CO2 formation are as follows: Chemical Interaction of CS2 and hydrogen sulfide (H2S) present in natural gas at high temperatures, resulting in CO2 formation;Combustion of CS2 in the presence of oxygen producing SO2 and CO2;Photolysis of CS2 leading to the formation of COS, CO, and SO2, which are indirect contributors to CO2 formation;One-step hydrolysis of CS2, producing reactive intermediates and ultimately forming H2S and CO2;Two-step hydrolysis of CS2 forming the reactive COS intermediate that reacts with an additional water molecule, ultimately forming H2S and CO2. CS2 and COS additionally are implicated in the formation of SO2 in the stratosphere and/or troposphere. SO2 is an indirect contributor to CO2 formation and is implicated in global climate change.

Power characteristics of the metal compounds formation process during the friction stir welding

Directory of Open Access Journals (Sweden)

Rzaev Radmir

2017-01-01

Full Text Available An influence of the power characteristics on the formation process of the uniform metals compound during the welding with friction stirringis being examined in this article.A dependency between the machine-tool engine power input and the instrument tilt during the FSW for the aluminum alloy AD31, copper alloy M1, titanium alloy OT4-1 and steel St-3 low-alloyed has been explored. A question of the stabilization of power consumption process while the establishment of superplastic condition of welded metal during the FSW has also been reviewed. A dependency revealed between the power characteristics, the geometry of the formation, the rotation speeds, the longitudinal displacement of the tool and its dimensions for fixed values of the parameters during the FSW.

Heuristic Task Analysis on E-Learning Course Development: A Formative Research Study

Science.gov (United States)

Lee, Ji-Yeon; Reigeluth, Charles M.

2009-01-01

Utilizing heuristic task analysis (HTA), a method developed for eliciting, analyzing, and representing expertise in complex cognitive tasks, a formative research study was conducted on the task of e-learning course development to further improve the HTA process. Three instructional designers from three different post-secondary institutions in the…

Are amphitheater headed canyons indicative of a particular formative process?

Science.gov (United States)

Ryan, A. J.; Whipple, K. X.; Johnson, J. P.

2012-12-01

Tributary canyons with amphitheater-shaped heads have previously been interpreted as evidence for groundwater seepage erosion, particularly in environments where fluvial processes are assumed to be negligible. However, some have questioned whether this canyon morphology is truly diagnostic of a particular formative process. We seek to determine the relative roles of fluvial and groundwater-related processes and the strength of stratigraphic control on the Colorado Plateau through a combination of fieldwork and GIS analysis. Amphitheater valleys may have overhanging or steep-sided headwalls with a semicircular plan-view pattern. It is reasonable to assume that this form is a result of focused erosion at the base of the headwall (i.e. sapping). Two frequently cited agents may lead to undermining: plunge-pool scour at the base of waterfalls and seepage induced weathering and erosion where the groundwater table intersects the land surface. Both processes are enhanced where weaker, less permeable layers underlie stronger cap rock. We conducted preliminary fieldwork in two locations on the Colorado Plateau, where there are many classic examples of amphitheater headed canyons. The Escalante River landscape is highly variable with a range of canyon and valley-head forms, many of which cut through the thick Navajo Sandstone into the underlying shale and sand of the Kayenta Formation. Northeast of Escalante National Monument, at the base of the Henry Mountains, is Tarantula Mesa. The canyons there are also considerably variable, with nearly all containing at least one abrupt amphitheater knickpoint at the valley head or farther downstream. Our observations are presented here with an analysis of the canyon profiles, surrounding topography, and potential structural controls. We have found that nearly all amphitheaters in both locales show signs of groundwater seepage weathering and plausibly seepage erosion. However, many also contain plunge pools and evidence of substantial

Processing of evaluated neutron data files in ENDF format on personal computers

International Nuclear Information System (INIS)

Vertes, P.

1991-11-01

A computer code package - FDMXPC - has been developed for processing evaluated data files in ENDF format. The earlier version of this package is supplemented with modules performing calculations using Reich-Moore and Adler-Adler resonance parameters. The processing of evaluated neutron data files by personal computers requires special programming considerations outlined in this report. The scope of the FDMXPC program system is demonstrated by means of numerical examples. (author). 5 refs, 4 figs, 4 tabs

Genes involved in Listeria monocytogenes biofilm formation at a simulated food processing plant temperature of 15 °C

DEFF Research Database (Denmark)

Piercey, Marta J.; Hingston, Patricia A.; Hansen, Lisbeth Truelstrup

2016-01-01

proteins. Deficient mutants (n=5) contained interruptions in genes related to peptidoglycan,teichoic acid, or lipoproteins. Enhanced mutants produced significantly (p b 0.05) higher cell densities in biofilm formed on stainless steel (SS) coupons at 15 °C (48 h) than deficient mutants, which were also more......Listeria monocytogenes is a pathogenic foodborne bacterium whose persistence in food processing environments is in part attributed to its biofilm formation. Most biofilm studies have been carried out at 30–37 °C rather than at temperatures found in the food processing plants (i.e., 10–20 °C......). The objective of the present study was to mine for novel genes that contribute to L. monocytogenes biofilm formation at 15 °C using the random insertional mutagenesisapproach. A library of 11,024 L. monocytogenes 568 (serotype 1/2a) Himar1 insertional mutants wascreated. Mutants with reduced or enhanced biofilm...

The Methodology of the Process of Formation of Innovation Management of Enterprises’ Development

Directory of Open Access Journals (Sweden)

Prokhorova Viktoriia V.

2017-12-01

Full Text Available The article is aimed at forming the methodology of process of innovation management of enterprises’ development in modern conditions. A study on formation of the essence of methodology was carried out, the stages of development of methods and means of scientific cognition were analyzed. The basic components of formation of methodology of innovation management of development of enterprises have been defined, i.e.: methods, types, principles, components, systematized aggregate. The relations of empirical and theoretical methods of scientific cognition were considered and defined. It has been determined that the increase of the volume and scope of scientific views, as well as the deepening of scientific knowledge in the disclosure of laws and regularities of functioning of real natural and social world, lead to the objective fact that is the desire of scientists to analyze methods and means by which modern innovative knowledge and views in the enterprise management system can be acquired and formed.

Interpersonal processes affecting early alliance formation in experiential therapy for depression.

Science.gov (United States)

Wong, Karen; Pos, Alberta E

2014-01-01

This study examined the effects of in-session interpersonal process and pre-therapy interpersonal problems on session-one alliance formation for 32 clients who received short-term experiential therapy for depression. Interpersonal behavior measured by the Structural Analysis of Social Behavior, as well as clients' pre-therapy reports of interpersonal problems significantly related to session-one alliance scores. Greater client disclosure independently predicted a stronger session-one bond with the therapist. Both greater client disclosure (positively) and pre-therapy Social Inhibition (negatively) independently predicted early goal agreement. Findings suggest that client disclosure is a marker of early engagement in experiential therapy, as well as support this model's mandate to form interpersonally safe therapeutic environments from the first moments of therapy.

Particle Formation by Supercritical Fluid Extraction and Expansion Process

Directory of Open Access Journals (Sweden)

Sujuan Pan

2013-01-01

Full Text Available Supercritical fluid extraction and expansion (SFEE patented technology combines the advantages of both supercritical fluid extraction (SFE and rapid expansion of supercritical solution (RESS with on-line coupling, which makes the nanoparticle formation feasible directly from matrix such as Chinese herbal medicine. Supercritical fluid extraction is a green separation technology, which has been developed for decades and widely applied in traditional Chinese medicines or natural active components. In this paper, a SFEE patented instrument was firstly built up and controlled by LABVIEW work stations. Stearic acid was used to verify the SFEE process at optimized condition; via adjusting the preexpansion pressure and temperature one can get different sizes of particles. Furthermore, stearic acid was purified during the SFEE process with HPLC-ELSD detecting device; purity of stearic acid increased by 19%, and the device can purify stearic acid.

The Process of Word Formation and Phrase Structure of Android Application Names

OpenAIRE

Handayani, Heny

2013-01-01

Android is an operating system for mobile device, such as smartphones and tablet computers that was developed by Google. In this era, android is a popular operating system that is searched by people because of necessary of information. The process and structure of android application names are interesting to be analyzed since they have different structure of words in general. The purpose research is to describe and explain which word formation processes and phrase structure that are commonly ...

Full characterization of the photorefractive bright soliton formation process using a digital holographic technique

International Nuclear Information System (INIS)

Merola, F; Miccio, L; Paturzo, M; Ferraro, P; De Nicola, S

2009-01-01

An extensive characterization of the photorefractive bright soliton writing process in a lithium niobate crystal is presented. An interferometric approach based on a digital holographic technique has been used to reconstruct the complex wavefield at the exit face of the crystal. Temporal evolution of both intensity and phase profile of the writing beam has been analysed. The effective changes of the refractive index of the medium during the writing process and after the soliton formation are determined from the optical phase distribution. This method provides a reliable way to observe the process of soliton formation, whereas the determination of the intensity distribution of the output beam does not show clearly whether the soliton regime has been achieved or not. Furthermore, a detailed analysis of the soliton in a steady-state situation and under different writing conditions is presented and discussed

Numerical study on drop formation through a micro nozzle

International Nuclear Information System (INIS)

Kim, Sung Il; Son, Gi Hun

2005-01-01

The drop ejection process from a micro nozzle is investigated by numerically solving the conservation equations for mass and momentum. The liquid-gas interface is tracked by a level set method which is extended for two-fluid flows with irregular solid boundaries. Based on the numerical results, the liquid jet breaking and droplet formation behavior is found to depend strongly on the pulse type of forcing pressure and the contact angle at the gas-liquid-solid interline. The negative pressure forcing can be used to control the formation of satelite droplets. Also, various nozzle shapes are tested to investigate their effect on droplet formation

Modelling de-novo formation of dioxins in the effluent gas cleaning tract of a zinc recycling process

Energy Technology Data Exchange (ETDEWEB)

Nordsieck, H.; Peche, R.

2002-07-01

Dioxins as well as other chloroaromatics are an unwanted by-product of most metallurgical processes, both in primary metal production and in recycling, such as at the re-use of high-zinc steel dust, as obtained in the second steel melting process using in electric arc furnaces, by extracting the included zinc. for achieving this purpose, the steel dust is treated in a rotary kiln. This resulting zinc oxide is offered to metal working companies in form of fine powder where it is used for galvanizing of components, for example, or for converting the powder pure metal. In the framework of the MINIDIP-project (Minimization of Dioxins in Thermal Industrial Processes: Mechanisms, Monitoring, Abatement) the formation of dioxins was studied as a function of temperature, time, oxygen, and inhibitor addition. The resulting kinetic data are introduced into a computational fluid dynamics (CFD) model, featuring geometric representations of the effluent gas cleaning tract components and the temperature and gas flow field as well as the trajectories and destination of particles different sizes calculated. This CFD model is used to estimate the de-novo formation of dioxins from the moment the gas leaves the rotary kiln until its cleaning, in order to define the role of this part of the plant in the formation of dioxins, as well as the identification and extent of possibilities for minimizing dioxin emissions. (Author)

ION-INDUCED PROCESSING OF COSMIC SILICATES: A POSSIBLE FORMATION PATHWAY TO GEMS

Energy Technology Data Exchange (ETDEWEB)

Jäger, C.; Sabri, T. [Max Planck Institute for Astronomy, Heidelberg, Laboratory Astrophysics and Cluster Physics Group, Institute of Solid State Physics, Friedrich Schiller University Jena, Helmholtzweg 3, D-07743 Jena (Germany); Wendler, E. [Institute of Solid State Physics, Friedrich Schiller University Jena, Helmholtzweg 3, D-07743 Jena (Germany); Henning, Th., E-mail: cornelia.jaeger@uni-jena.de [Max Planck Institute for Astronomy, Königstuhl 17, D-69117 Heidelberg (Germany)

2016-11-01

Ion-induced processing of dust grains in the interstellar medium and in protoplanetary and planetary disks plays an important role in the entire dust cycle. We have studied the ion-induced processing of amorphous MgFeSiO{sub 4} and Mg{sub 2}SiO{sub 4} grains by 10 and 20 keV protons and 90 keV Ar{sup +} ions. The Ar{sup +} ions were used to compare the significance of the light protons with that of heavier, but chemically inert projectiles. The bombardment was performed in a two-beam irradiation chamber for in situ ion-implantation at temperatures of 15 and 300 K and Rutherford Backscattering Spectroscopy to monitor the alteration of the silicate composition under ion irradiation. A depletion of oxygen from the silicate structure by selective sputtering of oxygen from the surface of the grains was observed in both samples. The silicate particles kept their amorphous structure, but the loss of oxygen caused the reduction of ferrous (Fe{sup 2+}) ions and the formation of iron inclusions in the MgFeSiO{sub 4} grains. A few Si inclusions were produced in the iron-free magnesium silicate sample pointing to a much less efficient reduction of Si{sup 4+} and formation of metallic Si inclusions. Consequently, ion-induced processing of magnesium-iron silicates can produce grains that are very similar to the glassy grains with embedded metals and sulfides frequently observed in interplanetary dust particles and meteorites. The metallic iron inclusions are strong absorbers in the NIR range and therefore a ubiquitous requirement to increase the temperature of silicate dust grains in IR-dominated astrophysical environments such as circumstellar shells or protoplanetary disks.

THE ALLIANCE FORMATION PROCESS

OpenAIRE

Whipple, Judith M.; Frankel, Robert

1998-01-01

While interest in developing strategic alliances within the food system continues to increase, there remains considerable risk when firms adopt such a cooperative strategy. The risk is due in part to the lack of concrete guidelines that illustrate the steps or stages of alliance development and the important strategic and operational decisions required at each stage. The existence of such guidelines would facilitate alliance formation and enable managers and researchers to better understand a...

The Role of Relative Sea Level Changes in Diagenetic Processes and Stacking Pattern of Kangan Formation Sediments in one of the Persian Gulf Fields

Directory of Open Access Journals (Sweden)

حسن اشراقی

2016-01-01

Full Text Available The Lower to Middle Triassic aged Kangan Formation is one of the most significant carbonate gas reservoirs in Iranian territory. In this study, thin sections data were used to recognize microfacies, sedimentary environments and the interaction between diagenetic processes and facies stacking pattern in a sequence stratigraphic framework. Petrographic studies leaded to recognition of eight microfacies related to three facies belts including tidal flat, lagoon and shoal. Moreover, the observed microfacies patterns indicate a ramp carbonate platform as depositional environment for this carbonate succession. The main diagenetic processes of Kangan Formation include micritization, isopachous and fibrous cements (primary marine diagenesis, dissolution and moldic porosity (meteoric diagenesis, compaction and stylolitization (secondary diagenesis. Based on facies changes, two third-order sequences were specified, each of which could be divided into two systems tracts including transgressive systems tract (TST and highstand systems tract (HST. In addition, sequence boundaries were identified with bedded, massive and nodular anhydrite. These facies, that are indicative of maximum sea level fall, were deposited in hypersaline lagoons. There is a close association between diagenetic processes and relative sea level changes of Kangan Formation, so that diagenetic processes of studied succession have been controlled by sediments stacking patterns during transgression and regression of sea level. During the transgression, the main diagenetic processes in shoal facies are marine cementation and dolomitization in lagoon and tidal flat facies. However, during the sea level fall, these processes include dissolution in shoal facies and dolomitization, anhydrite nodule formation and cementation in lagoon and tidal flat settings.

Planet formation in Binaries

OpenAIRE

Thebault, Ph.; Haghighipour, N.

2014-01-01

Spurred by the discovery of numerous exoplanets in multiple systems, binaries have become in recent years one of the main topics in planet formation research. Numerous studies have investigated to what extent the presence of a stellar companion can affect the planet formation process. Such studies have implications that can reach beyond the sole context of binaries, as they allow to test certain aspects of the planet formation scenario by submitting them to extreme environments. We review her...

Logic of historical development of the formation process of architectural and construction solutions

Directory of Open Access Journals (Sweden)

Baranov Valeriy Aleksandrovich

2014-05-01

Full Text Available In research field of development processes of architectural and construction decisions (ACD there is already very considerable scientific, normative and technical material. And still in the end of the research boom in this area (the 90th many authors stated their weak return in practical design. High methodological potential gives understanding of the act of ACD formation as a special kind of activity, and its structure - as historical phenomenon that allows to put two main methodological principles in the basis of the research: the principle of activity and the principle of level organization of historically formed objects. As a result it was succeeded to reveal 6 main stages of historical development of ACD formation process and 6 levels of its modern organization. Origin stage - is the transition from animal to human construction and emergence of the first stage of ACD formation - a measurement. The reproductive stage is characterized by centuries-old reproduction of steady volume forms of constructions. At a composite stage professional presentation detaches external form of a construction from architectural and construction actions and techniques. There occurs transformation into a subject of architectural and construction activity and creation of a method of composition on this basis. At a constructive stage engineers are involved in construction process, there is a change of style of thinking, emergence of construction designs and emergence of a new function of ACD means of configuration, and, at last, final allocation and separation of architectural and construction design from construction. Technological stage is a product of industrialization of construction on which systematization is carried out not only on the level of subject, but also in respect to the operational contents that leads to emergence of ACD program formation. At the sixth, methodological stage of development of ASP, a leading way change of the ACD formation becomes a

Dislocation processes in quasicrystals-Kink-pair formation control or jog-pair formation control

International Nuclear Information System (INIS)

Takeuchi, Shin

2005-01-01

A computer simulation of dislocation in a model quasiperiodic lattice indicates that the dislocation feels a large Peierls potential when oriented in particular directions. For a dislocation with a high Peierls potential, the glide velocity and the climb velocity of the dislocation can be described almost in parallel in terms of the kink-pair formation followed by kink motion and the jog-pair formation followed by jog motion, respectively. The activation enthalpy of the kink-pair formation is the sum of the kink-pair formation enthalpy and the atomic jump activation enthalpy, while the activation enthalpy of the jog-pair formation involves the jog-pair enthalpy and the self-diffusion enthalpy. Since the kink-pair energy can be considerably larger than the jog-pair energy, the climb velocity can be faster than the glide velocity, so that the plastic deformation of quasicrystals can be brought not by dislocation glide but by dislocation climb at high temperatures

An experimental study on atomizing formation process of diesel spray

International Nuclear Information System (INIS)

Kim, Ki Bong

2000-02-01

In this study, the experiment has, been conducted to investigate the spray characteristics under the parameter of an ambient pressure with a single hole nozzle having aspect ratio(L/D) of 5 and diameter of 0.45mm. Under the condition of the injection pressure of 14Mpa, the initial disintegrating process of a diesel spray is investigated and analysized according to change of the ambient pressures, 0.1, 1, 2 and 3Mpa. The double flash method has been employed to visualize the process of the diesel sprays. The results obtained in this study are as follows: 1) After spray starts, the spray is shown as non-disturbance liquid column within about 1∼2mm from the nozzle tip, whose diameter is similar to that of a nozzle. For the same injection pressure, the increase of the ambient pressure makes the length of the non-disturbance liquid column become short. 2) Due to the surface wave, ligaments of the shape thread appear at the boundary of liquid column right after spray. The more developed wave together the progress of spray transforms ligaments into droplets that have generally the uniformed size. 3) In case spraying into chambers having different ambient pressures, 1, 2, and 3Mpa, the spray tip velocities reach up to 1.5, 1.2, and 0.6ms, respectively, and decrease with lapse of time. The spray angle keeps increasing for 0.6, 1.2, and 1.4ms after spray under the various ambient pressures, 3, 2, and 1Mpa, respectively, and begins to decrease and maintains the constant value. Therefore, the transition points appear near the point where the velocity decreases and the spray angle increases, simultaneously. The higher ambient pressure leads to fast appearance of transition under the same spray pressure. 4) The disintegrating mechanism of the liquid spray is two combined effects: a) friction forces between the surface waves generated at the surface of the liquid column and the ambient gas, b) the collisions of liquid droplets and ligaments by spray were overtaking

The information technologies in the initial formation process of the professional of education.

Directory of Open Access Journals (Sweden)

Oliurca Padilla García

2012-12-01

Full Text Available Universities should give the students methods, aids and ways to obtain knowledge, in correspondence with the scientific development reached, so that they can assume a transformer position in the different acting contexts. In this sense, the information technologies not only provide the student with tools and resources of information, but also propitiate an environment that promotes interactions and educative exchange experiences between the students and teachers. Deepening about the role these resources play in the educational environment is of great importance to get its integration in a systematic and systemic way to the initial formation process of the professional of education so, its application in their formation surpasses the traditional concept of using de aims, and becomes an element that significantly strikes in a new configuration of the didactic approach of the process in the nowadays conditions.

NJOY99, Data Processing System of Evaluated Nuclear Data Files ENDF Format

International Nuclear Information System (INIS)

2000-01-01

1 - Description of program or function: The NJOY nuclear data processing system is a modular computer code used for converting evaluated nuclear data in the ENDF format into libraries useful for applications calculations. Because the Evaluated Nuclear Data File (ENDF) format is used all around the world (e.g., ENDF/B-VI in the US, JEF-2.2 in Europe, JENDL-3.2 in Japan, BROND-2.2 in Russia), NJOY gives its users access to a wide variety of the most up-to-date nuclear data. NJOY provides comprehensive capabilities for processing evaluated data, and it can serve applications ranging from continuous-energy Monte Carlo (MCNP), through deterministic transport codes (DANT, ANISN, DORT), to reactor lattice codes (WIMS, EPRI). NJOY handles a wide variety of nuclear effects, including resonances, Doppler broadening, heating (KERMA), radiation damage, thermal scattering (even cold moderators), gas production, neutrons and charged particles, photo-atomic interactions, self shielding, probability tables, photon production, and high-energy interactions (to 150 MeV). Output can include printed listings, special library files for applications, and Postscript graphics (plus color). More information on NJOY is available from the developer's home page at http://t2.lanl.gov/tour/tourbus.html. Follow the Tourbus section of the Tour area to find notes from the ICTP lectures held at Trieste in March 2000 on the ENDF format and on the NJOY code. NJOY contains the following modules: NJOY directs the flow of data through the other modules and contains a library of common functions and subroutines used by the other modules. RECONR reconstructs pointwise (energy-dependent) cross sections from ENDF resonance parameters and interpolation schemes. BROADR Doppler broadens and thins pointwise cross sections. UNRESR computes effective self-shielded pointwise cross sections in the unresolved energy range. HEATR generates pointwise heat production cross sections (KERMA coefficients) and radiation

STRUCTURAL ELEMENTS OF THE PROCESS OF BUSINESS ENGLISH SKILLS FORMATION IN FUTURE DOCTORS

Directory of Open Access Journals (Sweden)

Людмила Русалкіна

2015-05-01

Full Text Available The article is devoted to the structure and organization of medical students’ business English teaching process. The main attention is spared to the problem of creation of the experimental model of future doctors’ business English skills formation. The suggested model is aimed at productive mastering of lexical and grammar communicative skills, at formation of business English communicative abilities of students-medics; it has communicative direction and is professionally oriented. The exercises correspond to English language knowledge of the future doctors and are set in sequence of increasing complexity.

Analysis of the hydrolysis process in the formation of supergene zone mining areas

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Sherstjuk N.P.

2010-06-01

Full Text Available The analysis of processes of hydrolysis of silicates and alumosilicat which arrive in a landscape from tails of enrichment of iron ore is carried out. Assessment and forecast formation of minerals zone hipcrhenezu iron deposits was carried out.

The Professional Competence Formation in the Training Process in Higher Educational Institution

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Burganova, Roza I.; Abdugalina, Sairan E.; Shaiheslyamova, Kazyna O.

2016-01-01

The article is devoted to the problem of professional competence formation in the specialists' training process at the university in contemporary socio-economic and socio-cultural conditions originating in the Republic of Kazakhstan. The emphasis is laid on new scientific and pedagogical approaches to its solution. Special attention is paid to the…

An integrated system for dissolution studies and magnetic resonance imaging of controlled release, polymer-based dosage forms-a tool for quantitative assessment of hydrogel formation processes.

Science.gov (United States)

Kulinowski, Piotr; Dorozyński, Przemysław; Jachowicz, Renata; Weglarz, Władysław P

2008-11-04

Controlled release (CR) dosage forms are often based on polymeric matrices, e.g., sustained-release tablets and capsules. It is crucial to visualise and quantify processes of the hydrogel formation during the standard dissolution study. A method for imaging of CR, polymer-based dosage forms during dissolution study in vitro is presented. Imaging was performed in a non-invasive way by means of the magnetic resonance imaging (MRI). This study was designed to simulate in vivo conditions regarding temperature, volume, state and composition of dissolution media. Two formulations of hydrodynamically balanced systems (HBS) were chosen as model CR dosage forms. HBS release active substance in stomach while floating on the surface of the gastric content. Time evolutions of the diffusion region, hydrogel formation region and "dry core" region were obtained during a dissolution study of L-dopa as a model drug in two simulated gastric fluids (i.e. in fed and fasted state). This method seems to be a very promising tool for examining properties of new formulations of CR, polymer-based dosage forms or for comparison of generic and originator dosage forms before carrying out bioequivalence studies.

Oil formation in the process of lithogenesis in the light of the systems approach

Energy Technology Data Exchange (ETDEWEB)

Lopatin, N.V.

1977-03-01

It is suggested that systems analysis techniques be used to reproduce the actual historical process of oil formation as a part of the overall system of a sedimentary rock basin, in order to determine the conditions of transition of one stage of development of the object to another, determine interrelationships between elements of the system and peculiarities of its functioning, provide a detailed description of the mature stage of the process, the primary phase of oil formation, by partial solution of the problem and formulate the new problem of recognition of oil formation, closely related to the search for deposits of oil. The systems approach is a modern methodological orientation which, though it does not guarantee the production of true knowledge, since a great deal is determined by the reliability of the empirical basis of data, skill of the researcher and even such materialistic factors as intuition and creative imagination, does provide the possibility for creation of a single theoretical picture and development of mathematically founded concepts in this area of research.

Star formation: study of the collapse of pre-stellar dense cores

International Nuclear Information System (INIS)

Commercon, Benoit

2009-01-01

One of the priorities of contemporary astrophysics remains to understand the mechanisms which lead to star formation. In the dense cores where star formation occurs, temperature, pressure, etc... are such that it is impossible to reproduce them in the laboratory. Numerical calculations remain the only mean to study physical phenomena that are involved in the star formation process. The focus of this thesis has been on the numerical methods that are used in the star formation context to describe highly non-linear and multi-scale phenomena. In particular, I have concentrated my work on the first stages of the pre-stellar dense cores collapse. This work is divided in 4 linked part. In a first study, I use a 1D Lagrangian code in spherical symmetry (Audit et al. 2002) to compare three models that incorporate radiative transfer and matter-radiation interactions. This comparison was based on simple gravitational collapse calculations which lead to the first Larson core formation. It was found that the Flux Limited Diffusion model is appropriate for star formation calculations. I also took benefit from this first work to study the properties of the accretion shock on the first Larson core. We developed a semi-analytic model based on well-known assumptions, which reproduces the jump properties at the shock. The second study consisted in implementing the Flux Limited Diffusion model with the radiation-hydrodynamics equations in the RAMSES code (Teyssier 2002). After a first step of numerical tests that validate the scheme, we used RAMSES to perform the first multidimensional collapse calculations that combine magnetic field and radiative transfer effects at small scales with a high numerical resolution. Our results show that the radiative transfer has a significant impact on the fragmentation in the collapse of pre-stellar dense cores. I also present a comparison we made between the RAMSES code (Eulerian approach) and the SPH code DRAGON (Goodwin 2004, Lagrangian approach

Stages of ores formation

International Nuclear Information System (INIS)

Khasanov, A.Kh.

1988-01-01

Deposit formation (especially endogenous) is the complicated, multi-stage and long process. Establishment of deposit formation succession, age-specific correlations of minerals and aggregates have a high importance at solving genetic questions. Studying of minerals correlations and mineral aggregates, succession of their crystallization and other observations let restore the history of deposit formation, pick up in it different on duration and physical and chemical conditions stages

Feedback in formative OSCEs: comparison between direct observation and video-based formats

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Junod Perron, Noëlle; Louis-Simonet, Martine; Cerutti, Bernard; Pfarrwaller, Eva; Sommer, Johanna; Nendaz, Mathieu

2016-01-01

Introduction Medical students at the Faculty of Medicine, University of Geneva, Switzerland, have the opportunity to practice clinical skills with simulated patients during formative sessions in preparation for clerkships. These sessions are given in two formats: 1) direct observation of an encounter followed by verbal feedback (direct feedback) and 2) subsequent review of the videotaped encounter by both student and supervisor (video-based feedback). The aim of the study was to evaluate whether content and process of feedback differed between both formats. Methods In 2013, all second- and third-year medical students and clinical supervisors involved in formative sessions were asked to take part in the study. A sample of audiotaped feedback sessions involving supervisors who gave feedback in both formats were analyzed (content and process of the feedback) using a 21-item feedback scale. Results Forty-eight audiotaped feedback sessions involving 12 supervisors were analyzed (2 direct and 2 video-based sessions per supervisor). When adjusted for the length of feedback, there were significant differences in terms of content and process between both formats; the number of communication skills and clinical reasoning items addressed were higher in the video-based format (11.29 vs. 7.71, p=0.002 and 3.71 vs. 2.04, p=0.010, respectively). Supervisors engaged students more actively during the video-based sessions than during direct feedback sessions (self-assessment: 4.00 vs. 3.17, p=0.007; active problem-solving: 3.92 vs. 3.42, p=0.009). Students made similar observations and tended to consider that the video feedback was more useful for improving some clinical skills. Conclusion Video-based feedback facilitates discussion of clinical reasoning, communication, and professionalism issues while at the same time actively engaging students. Different time and conceptual frameworks may explain observed differences. The choice of feedback format should depend on the educational

Feedback in formative OSCEs: comparison between direct observation and video-based formats

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Noëlle Junod Perron

2016-11-01

Full Text Available Introduction: Medical students at the Faculty of Medicine, University of Geneva, Switzerland, have the opportunity to practice clinical skills with simulated patients during formative sessions in preparation for clerkships. These sessions are given in two formats: 1 direct observation of an encounter followed by verbal feedback (direct feedback and 2 subsequent review of the videotaped encounter by both student and supervisor (video-based feedback. The aim of the study was to evaluate whether content and process of feedback differed between both formats. Methods: In 2013, all second- and third-year medical students and clinical supervisors involved in formative sessions were asked to take part in the study. A sample of audiotaped feedback sessions involving supervisors who gave feedback in both formats were analyzed (content and process of the feedback using a 21-item feedback scale. Results: Forty-eight audiotaped feedback sessions involving 12 supervisors were analyzed (2 direct and 2 video-based sessions per supervisor. When adjusted for the length of feedback, there were significant differences in terms of content and process between both formats; the number of communication skills and clinical reasoning items addressed were higher in the video-based format (11.29 vs. 7.71, p=0.002 and 3.71 vs. 2.04, p=0.010, respectively. Supervisors engaged students more actively during the video-based sessions than during direct feedback sessions (self-assessment: 4.00 vs. 3.17, p=0.007; active problem-solving: 3.92 vs. 3.42, p=0.009. Students made similar observations and tended to consider that the video feedback was more useful for improving some clinical skills. Conclusion: Video-based feedback facilitates discussion of clinical reasoning, communication, and professionalism issues while at the same time actively engaging students. Different time and conceptual frameworks may explain observed differences. The choice of feedback format should depend on

Curcumin complexation with cyclodextrins by the autoclave process: Method development and characterization of complex formation.

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Hagbani, Turki Al; Nazzal, Sami

2017-03-30

One approach to enhance curcumin (CUR) aqueous solubility is to use cyclodextrins (CDs) to form inclusion complexes where CUR is encapsulated as a guest molecule within the internal cavity of the water-soluble CD. Several methods have been reported for the complexation of CUR with CDs. Limited information, however, is available on the use of the autoclave process (AU) in complex formation. The aims of this work were therefore to (1) investigate and evaluate the AU cycle as a complex formation method to enhance CUR solubility; (2) compare the efficacy of the AU process with the freeze-drying (FD) and evaporation (EV) processes in complex formation; and (3) confirm CUR stability by characterizing CUR:CD complexes by NMR, Raman spectroscopy, DSC, and XRD. Significant differences were found in the saturation solubility of CUR from its complexes with CD when prepared by the three complexation methods. The AU yielded a complex with expected chemical and physical fingerprints for a CUR:CD inclusion complex that maintained the chemical integrity and stability of CUR and provided the highest solubility of CUR in water. Physical and chemical characterizations of the AU complexes confirmed the encapsulated of CUR inside the CD cavity and the transformation of the crystalline CUR:CD inclusion complex to an amorphous form. It was concluded that the autoclave process with its short processing time could be used as an alternate and efficient methods for drug:CD complexation. Copyright © 2017 Elsevier B.V. All rights reserved.

Iron behaviour in the process of stratum-infiltration uranium ore formation

International Nuclear Information System (INIS)

Shmariovich, E.M.; Golubev, V.S.

1980-01-01

Investigated has been the behaviour of iron in the process of stratum infiltration uranium mineralization. Iron is partially avacuated from the forward part of the stratum oxidation zone during the development of infiltration uranium mineralization in pyritiferous rocks. This phenomenon is characterized quantitatively and described on the basis of equations of physical chemistry and dynamics of geochemical processes. Local regions of epigenetic ferruginization caused by opposite diffusion of iron and its precipitation in oxygenous conditions often occur at the sections of sharp moderation of limonitization zone advance. Formation of similar ferruginous margins takes place in a very short geological period (less than thousand years)

EFFECT OF FEEDBACK IN FORMATIVE ASSESSMENT IN THE STUDENT LEARNING ACTIVITIES ON CHEMICAL COURSE TO THE FORMATION OF HABITS OF MIND

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Nahadi -

2015-04-01

Full Text Available The aim of this study was to find the impact of feedback in formative assessment in the learning process activity and students learning outcomes on learning chemistry. The method used on this study was quasi experiment research with non-equivalent control group design. The result showed that the application of feedback in formative assessment has a positive impact toward students learning process activity. Students become more enthusiastic, motivated, and more active on the learning process. Thus in this study can be conclude that feedback in formative assessment have a positive impact toward the learning process activity to form a habits of mind.

The method of predicting the process of condensation of moisture and hydrate formation in the gas pipeline

OpenAIRE

Хвостова, Олена Вікторівна

2014-01-01

The problem of ensuring the required value of one of the natural gas quality indicators during its transportation to the consumer - moisture content is considered in the paper. The method for predicting possible moisture condensation and hydrate formation processes in gas pipelines considering mixing gas flows with different moisture content was developed.Predicting the moisture condensation and hydrate formation in gas pipelines is an actual task since a timely prevention of these processes ...

Bromate Formation Characteristics of UV Irradiation, Hydrogen Peroxide Addition, Ozonation, and Their Combination Processes

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Naoyuki Kishimoto

2012-01-01

Full Text Available Bromate formation characteristics of six-physicochemical oxidation processes, UV irradiation, single addition of hydrogen peroxide, ozonation, UV irradiation with hydrogen peroxide addition (UV/H2O2, ozonation with hydrogen peroxide addition (O3/H2O2, and ozonation with UV irradiation (O3/UV were investigated using 1.88 μM of potassium bromide solution with or without 6.4 μM of 4-chlorobenzoic acid. Bromate was not detected during UV irradiation, single addition of H2O2, and UV/H2O2, whereas ozone-based treatments produced . Hydroxyl radicals played more important role in bromate formation than molecular ozone. Acidification and addition of radical scavengers such as 4-chlorobenzoic acid were effective in inhibiting bromate formation during the ozone-based treatments because of inhibition of hydroxyl radical generation and consumption of hydroxyl radicals, respectively. The H2O2 addition was unable to decompose 4-chlorobenzoic acid, though O3/UV and O3/H2O2 showed the rapid degradation, and UV irradiation and UV/H2O2 showed the slow degradation. Consequently, if the concentration of organic contaminants is low, the UV irradiation and/or UV/H2O2 are applicable to organic contaminants removal without bromate formation. However, if the concentration of organic contaminants is high, O3/H2O2 and O3/UV should be discussed as advanced oxidation processes because of their high organic removal efficiency and low bromate formation potential at the optimum condition.

Formation of extracellular polymeric substances from acidogenic sludge in H2-producing process.

Science.gov (United States)

Sheng, Guo-Ping; Yu, Han-Qing

2007-02-01

In this study, the formation of extracellular polymeric substances (EPS) and surface characteristics of an acidogenic sludge in anaerobic H(2)-producing process was investigated. Results show that carbohydrates, proteins, and humic substances were the dominant components in bound EPS (BEPS), while in soluble EPS (SEPS), carbohydrates were the main component. The total content of BEPS initially increased but then kept almost unchanged during fermentation from 25 to 35 h; after that, it slightly decreased. The total content of SEPS increased to 172.5 +/- 0.05 mg C g(-1) volatile suspended solid with the time that increased to 23.5 h, and then rapidly decreased until 43 h; thereafter, it kept almost unchanged. The SEPS had good correlations with the specific H(2) production rate, substrate degradation rate, and specific aqueous products formation rate, but the BEPS seemed to have no such correlations with these specific rates. Results also confirm that part of EPS could be utilized by the H(2)-producing sludge. As the substrate was in short supply, the EPS would be hydrolyzed to sever as carbon and energy source.

Biogeochemical processes controlling authigenic carbonate formation within the sediment column from the Okinawa Trough

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Li, Jiwei; Peng, Xiaotong; Bai, Shijie; Chen, Zhiyan; Van Nostrand, Joy D.

2018-02-01

Authigenic carbonates are one type of conspicuous manifestation in seep environments that can provide long-term archives of past seepage activity and methane cycling in the oceans. Comprehensive investigations of the microbial community functional structure and their roles in the process of carbonate formation are, however, lacking. In this study, the mineralogical, geochemical, and microbial functional composition were examined in seep carbonate deposits collected from the west slope of the northern section of the Okinawa Trough (OT). The aim of this work was to explore the correspondence between the mineralogical phases and microbial metabolism during carbonate deposit formation. The mineralogical analyses indicated that authigenic carbonate minerals (aragonite, magnesium-rich calcite, dolomite, ankerite and siderite) and iron-bearing minerals (limonite, chlorite, and biotite) were present in these carbonate samples. The carbon and oxygen isotopic values of the carbonate samples varied between -51.1‰ to -4.7‰ and -4.8‰ to 3.7‰, respectively. A negative linear correlation between carbon and oxygen isotopic compositions was found, indicating a mixture of methane-derived diagenetic (low δ13C/high 18O) carbonates and detrital origin (high δ13C/low 18O) carbonates at the OT. GeoChip analyses suggested that various metabolic activities of microorganisms, including methanogenesis, methane oxidation, sulfite oxidation, sulfate reduction, and metal biotransformations, all occurred during the formation process. On the basis of these findings, the following model for the methane cycle and seep carbonate deposit formation in the sediment column at the OT is proposed: (1) in the upper oxidizing zone, aerobic methane oxidation was the main way of methane consumption; (2) in the sulfate methane transition zone, sulfate-dependent AOM (anaerobic oxidation of methane) consumes methane, and authigenic minerals such as aragonite, magnesium-calcite, and sulfide minerals

Risk communication formats for low probability events: an exploratory study of patient preferences

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Iadarola Stephen

2008-04-01

Full Text Available Abstract Background Clear communication about the possible outcomes of proposed medical interventions is an integral part of medical care. Despite its importance, there have been few studies comparing different formats for presenting probabilistic information to patients, especially when small probabilities are involved. The purpose of this study was to explore the potential usefulness of several new small-risk graphic communication formats. Methods Information about the likelihoods of cancer and cancer prevention associated with two hypothetical cancer screening programs were used to create an augmented bar chart, an augmented grouped icon display, a flow chart, and three paired combinations of these formats. In the study scenario, the baseline risk of cancer was 53 per 1,000 (5.3%. The risk associated with cancer screening option A was 38 per 1,000 (3.8% and the risk associated with screening option B was 29 per 1,000 (2.9%. Both the augmented bar chart and the augmented grouped icon display contained magnified views of the differences in cancer risk and cancer prevention associated with the screening programs. A convenience sample of 29 subjects (mean age 56.4 years; 76% men used the Analytic Hierarchy Process (AHP to indicate their relative preferences for the six formats using 15 sequential paired comparisons. Results The most preferred format was the combined augmented bar chart + flow diagram (mean preference score 0.43 followed by the combined augmented icon + augmented bar chart format (mean preference score 0.22. The overall differences among the six formats were statistically significant: Kruskal-Wallis Chi Square = 141.4, p Conclusion These findings suggest that patients may prefer combined, rather than single, graphic risk presentation formats and that augmented bar charts and icon displays may be useful for conveying comparative information about small risks to clinical decision makers. Further research to confirm and extend these

Formation process of lamella structures by deformation in an Fe-Mn-Si-Cr-Ni shape memory alloy

International Nuclear Information System (INIS)

Kikuchi, T.; Kajiwara, S.; Tomota, Y.

1995-01-01

For Fe-Mn-Si-Cr-Ni shape memory alloys, it was previously found by HREM study that the formation of the nanometric lamella structures consisting of f.c.c. and h.c.p. phase is very important to exhibit good shape memory effect. In the present work, the formation process of such lamella structures has been studied in detail. The results are as follows. The transformation is initiated by random formation of extremely thin martensite plates with 1-2 nm width and then these plates are clustered and some of them coalesce to form thicker martensite plates with increasing deformation. The clustered regions are 400-600 nm wide and will correspond to the above mentioned lamella structures. These clustered regions are considered also to correspond to the thinnest martensite plate observable with optical microscope. In the optical microscopic scale, the thin martenite plates with the smallest width are formed rather uniformly in an austenite grain, and with further increasing deformation, they are clustered and coalesce into thicker plates with 3-8 μm width. (orig.)

Educational process their different contents, singularities to the sculpture the Formation integral in university students

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Laura Margarita Fernández-Martínez

2018-03-01

Full Text Available Presently article is approached important relating theoretical the in artistic education, that facilitate the formation integral in university students, the educational process their different contents, singularities to the sculpture artistic manifestation, with which one works methodologically. However, it is necessary to establish a methodological theoretical position in this respect to be able to evidence the relationship education-culture the understanding of the artistic education in that relationship and their contribution to the formation integral. From the didactic point of view, it is sustained in the basics of the teaching-learning process, related with the Didactics of the Superior Education and in the analysis and valuation of the components of the process of teaching learning where the dynamics of the relationships is revealed among these that it is constituted in a dialectical process where starting from the created conditions the fellow appropriates of the necessary tools for interaction with the reality.

Star Formation Studies in the SPICA/SAFARI Era

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Sibthorpe, Bruce; Goicoechea, Javier

2013-07-01

The Japanese JAXA SPICA space observatory, due for launch in 2022, will provide astronomers with a long awaited new window on the universe. Having a large cold telescope, cooled to only 6K above absolute zero, SPICA will provide a unique environment in which instruments are limited only by the cosmic background itself. A consortium of European and Canadian institutes has been established to design and implement the SpicA FAR infrared Instrument, SAFARI, an imaging FTS spectrometer designed to fully exploit this extremely low far infrared background environment provided by the SPICA observatory. With SAFARI it will be possible to obtain continuous spectra spanning 34 -\\ 210 um within an instantaneous 2'x2' field-of-view, at spectral resolutions of up to R = 2000 @ 100um (4000 @ 50um), within a single telescope pointing. This capability, coupled with the exquisite sensitivity provided by the cold SPICA telescope, makes SAFARI the ideal instrument to perform large area spectroscopic mapping surveys in the far-infrared. SPICA/SFARI will provide new insights into a range of astronomical sources. By obtaining spectra for large, statistically significant samples, we can obtain a fundamental understanding of their chemistry and physical processes, and thereby characterise and understand the nature of these sources. Moreover, with the high sensitivity of SAFARI, it will be possible to extend current far-infrared studies of star formation processes to nearby galaxies, thereby putting our current understanding in a wider, universal, context. This poster provides a description of the SAFARI instrument and its capabilities. A brief representative sample of the contribution SAFARI can make in the field of star formation studies is also given, and compared to similar observations made using the Herschel-PACS instrument.

Study of carbonate concretions using imaging spectroscopy in the Frontier Formation, Wyoming

Science.gov (United States)

de Linaje, Virginia Alonso; Khan, Shuhab D.; Bhattacharya, Janok

2018-04-01

Imaging spectroscopy is applied to study diagenetic processes of the Wall Creek Member of the Cretaceous Frontier Formation, Wyoming. Visible Near-Infrared and Shortwave-Infrared hyperspectral cameras were used to scan near vertical and well-exposed outcrop walls to analyze lateral and vertical geochemical variations. Reflectance spectra were analyzed and compared with high-resolution laboratory spectral and hyperspectral imaging data. Spectral Angle Mapper (SAM) and Mixture Tuned Matched Filtering (MTMF) classification algorithms were applied to quantify facies and mineral abundances in the Frontier Formation. MTMF is the most effective and reliable technique when studying spectrally similar materials. Classification results show that calcite cement in concretions associated with the channel facies is homogeneously distributed, whereas the bar facies was shown to be interbedded with layers of non-calcite-cemented sandstone.

Numerical analysis of the formation process of aerosols in the alveoli

Science.gov (United States)

Haslbeck, Karsten; Seume, Jörg R.

2008-11-01

For a successful diagnosis of lung diseases through an analysis of non-volatile molecules in the exhaled breath, an exact understanding of the aerosol formation process is required. This process is modeled using Computational Fluid Dynamics (CFD). The model shows the interaction of the boundary surface between the streamed airway and the local epithelial liquid layer. A 2-D volume mesh of an alveolus is generated by taking into account the connection of the alveoli with the sacculi alveolares (SA). The Volume of Fluid (VOF) Method is used to model the interface between the gas and the liquid film. The non-Newtonian flow is modeled by the implementation of the Ostwald de Waele model. Surface tension is a function of the surfactant concentration. The VOF-Method allows the distribution of the concentration of the epithelial liquid layer at the surface to be traced in a transient manner. The simulations show the rupturing of the liquid film through the drop formation. Aerosol particles are ejected into the SA and do not collide with the walls. The quantity, the geometrical size as well as the velocity distributions of the generated aerosols are determined. The data presented in the paper provide the boundary conditions for future CFD analysis of the aerosol transport through the airways up to exhalation.

The relationship between level of processing and hippocampal-cortical functional connectivity during episodic memory formation in humans.

Science.gov (United States)

Schott, Björn H; Wüstenberg, Torsten; Wimber, Maria; Fenker, Daniela B; Zierhut, Kathrin C; Seidenbecher, Constanze I; Heinze, Hans-Jochen; Walter, Henrik; Düzel, Emrah; Richardson-Klavehn, Alan

2013-02-01

New episodic memory traces represent a record of the ongoing neocortical processing engaged during memory formation (encoding). Thus, during encoding, deep (semantic) processing typically establishes more distinctive and retrievable memory traces than does shallow (perceptual) processing, as assessed by later episodic memory tests. By contrast, the hippocampus appears to play a processing-independent role in encoding, because hippocampal lesions impair encoding regardless of level of processing. Here, we clarified the neural relationship between processing and encoding by examining hippocampal-cortical connectivity during deep and shallow encoding. Participants studied words during functional magnetic resonance imaging and freely recalled these words after distraction. Deep study processing led to better recall than shallow study processing. For both levels of processing, successful encoding elicited activations of bilateral hippocampus and left prefrontal cortex, and increased functional connectivity between left hippocampus and bilateral medial prefrontal, cingulate and extrastriate cortices. Successful encoding during deep processing was additionally associated with increased functional connectivity between left hippocampus and bilateral ventrolateral prefrontal cortex and right temporoparietal junction. In the shallow encoding condition, on the other hand, pronounced functional connectivity increases were observed between the right hippocampus and the frontoparietal attention network activated during shallow study processing. Our results further specify how the hippocampus coordinates recording of ongoing neocortical activity into long-term memory, and begin to provide a neural explanation for the typical advantage of deep over shallow study processing for later episodic memory. Copyright © 2011 Wiley Periodicals, Inc.

Investigation on the asymmetry of thermal condition and grain defect formation in the customary directional solidification process

International Nuclear Information System (INIS)

Ma, D; Wu, Q; Hollad, S; Bührig-Polaczek, A

2012-01-01

In the present study, the non-uniformity of the thermal condition and the corresponding grain defect formation in the customary Bridgman process were investigated. The casting clusters in radial alignment were directionally solidified in a Bridgman furnace. It was found that in the casting cluster, the shadow side facing the central rod was ineffectively heated in the hot zone and ineffectively cooled in the cooling zone during withdrawal, compared with the heater side facing the furnace heater. The metallographic examination of the simplified turbine blades exhibited that the platforms on the shadow side are very prone to stray grain formation, while the heater side reveals a markedly lower tendency for that. The asymmetric thermal condition causes the asymmetrical formation of these grain defects. This non-uniformity of the thermal condition should be minimized as far as possible, in order to effectively optimize the quality of the SC superalloy components.

Micro/nanostructures formation by femtosecond laser surface processing on amorphous and polycrystalline Ni{sub 60}Nb{sub 40}

Energy Technology Data Exchange (ETDEWEB)

Peng, Edwin, E-mail: edwin.peng@huskers.unl.edu [Department of Mechanical and Materials Engineering, University of Nebraska-Lincoln, Lincoln, NE 68588 (United States); Tsubaki, Alfred; Zuhlke, Craig A. [Department of Electrical and Computer Engineering, University of Nebraska-Lincoln, Lincoln, NE 68588 (United States); Wang, Meiyu [Department of Mechanical and Materials Engineering, University of Nebraska-Lincoln, Lincoln, NE 68588 (United States); Bell, Ryan [Department of Electrical and Computer Engineering, University of Nebraska-Lincoln, Lincoln, NE 68588 (United States); Lucis, Michael J. [Department of Mechanical and Materials Engineering, University of Nebraska-Lincoln, Lincoln, NE 68588 (United States); Anderson, Troy P.; Alexander, Dennis R. [Department of Electrical and Computer Engineering, University of Nebraska-Lincoln, Lincoln, NE 68588 (United States); Gogos, George; Shield, Jeffrey E. [Department of Mechanical and Materials Engineering, University of Nebraska-Lincoln, Lincoln, NE 68588 (United States)

2017-02-28

Highlights: • Femtosecond laser processing of glass-forming Ni{sub 60}Nb{sub 40} produce surface structures. • Cross sectioning, imaging, & TEM sample preparation with dual-beam SEM. • Low laser fluence surface structures’ form by ablation. • High laserfluence surface structures form by ablation and fluid flow. - Abstract: Femtosecond laser surface processing is a technology that can be used to functionalize many surfaces, imparting specialized properties such as increased broadband optical absorption or superhydrophilicity/superhydrophobicity. In this study, two unique classes of surface structures, below surface growth (BSG) and above surface growth (ASG) mounds, were formed by femtosecond laser surface processing on amorphous and polycrystalline Ni{sub 60}Nb{sub 40} with two different grain sizes. Cross sectional imaging of these mounds revealed thermal evidence of the unique formation processes for each class of surface structure. BSG mounds formed on all three substrates using the same laser parameters had similar surface morphology. The microstructures in the mounds were unaltered compared with the substrate before laser processing, suggesting their formation was dominated by preferential valley ablation. ASG mounds had similar morphology when formed on the polycrystalline Ni{sub 60}Nb{sub 40} substrates with 100 nm and 2 μm grain size. However, the ASG mounds had significantly wider diameter and higher peak-to-valley heights when the substrate was amorphous Ni{sub 60}Nb{sub 40}. Hydrodynamic melting was primarily responsible for ASG mound formation. On amorphous Ni{sub 60}Nb{sub 40} substrates, the ASG mounds are most likely larger due to lower thermal diffusivity. There was clear difference in growth mechanism of femtosecond laser processed BSG and ASG mounds, and grain size does not appear to be a factor.

Positronium formation studies in crystalline molecular complexes: Triphenylphosphine oxide - Acetanilide

Science.gov (United States)

Oliveira, F. C.; Denadai, A. M. L.; Guerra, L. D. L.; Fulgêncio, F. H.; Windmöller, D.; Santos, G. C.; Fernandes, N. G.; Yoshida, M. I.; Donnici, C. L.; Magalhães, W. F.; Machado, J. C.

2013-04-01

Hydrogen bond formation in the triphenylphosphine oxide (TPPO), acetanilide (ACN) supramolecular heterosynton system, named [TPPO0.5·ACN0.5], has been studied by Positron Annihilation Lifetime Spectroscopy (PALS) and supported by several analytical techniques. In toluene solution, Isothermal Titration Calorimetry (ITC) presented a 1:1 stoichiometry and indicated that the complexation process is driven by entropy, with low enthalpy contribution. X-ray structure determination showed the existence of a three-dimensional network of hydrogen bonds, allowing also the confirmation of the existence of a 1:1 crystalline molecular complex in solid state. The results of thermal analysis (TGA, DTA and DSC) and FTIR spectroscopy showed that the interactions in the complex are relatively weaker than those found in pure precursors, leading to a higher positronium formation probability at [TPPO0.5·ACN0.5]. These weak interactions in the complex enhance the possibility of the n- and π-electrons to interact with positrons and consequently, the probability of positronium formation is higher. Through the present work is shown that PALS is a sensible powerful tool to investigate intermolecular interactions in solid heterosynton supramolecular systems.

Formation of iron nanoparticles and increase in iron reactivity in mineral dust during simulated cloud processing.

Science.gov (United States)

Shi, Zongbo; Krom, Michael D; Bonneville, Steeve; Baker, Alex R; Jickells, Timothy D; Benning, Liane G

2009-09-01

The formation of iron (Fe) nanoperticles and increase in Fe reactivity in mineral dust during simulated cloud processing was investigated using high-resolution microscopy and chemical extraction methods. Cloud processing of dust was experimentally simulated via an alternation of acidic (pH 2) and circumneutral conditions (pH 5-6) over periods of 24 h each on presieved (formation of Fe-rich nanoparticle aggregates, which were not found initially. Similar Fe-rich nanoparticles were also observed in wet-deposited Saharen dusts from the western Mediterranean but not in dry-deposited dust from the eastern Mediterranean. Sequential Fe extraction of the soil samples indicated an increase in the proportion of chemically reactive Fe extractable by an ascorbate solution after simulated cloud processing. In addition, the sequential extractions on the Mediterranean dust samples revealed a higher content of reactive Fe in the wet-deposited dust compared to that of the dry-deposited dust These results suggestthat large variations of pH commonly reported in aerosol and cloud waters can trigger neo-formation of nanosize Fe particles and an increase in Fe reactivity in the dust

RELABEL2007, Labels FORTRAN Statements in ENDF Format Processing Programs

International Nuclear Information System (INIS)

2007-01-01

1 - Description of program or function: RELABEL labels a ENDF/B pre-processing program so that statement labels are in increasing order in increments of 10 within each routine, and cards are identified in columns 73-80 by three alphanumeric characters in columns 73-75 and sequence numbers in columns 76-80 in increments of 10. IAEA1314/10: This version include the updates up to January 30, 2007. Changes in ENDF/B-VII Format and procedures, as well as the evaluations themselves, make it impossible for versions of the ENDF/B pre-processing codes earlier than PREPRO 2007 (2007 Version) to accurately process current ENDF/B-VII evaluations. The present code can handle all existing ENDF/B-VI evaluations through release 8, which will be the last release of ENDF/B-VI. Modifications from previous versions: Relabel VERS. 2007-1 (JAN. 2007): No change since March 2004 version 2 - Method of solution: 3 - Restrictions on the complexity of the problem: RELABEL is designed to maintain ENDF/B processing programs which use a restricted set of FORTRAN statements. As such, this program is not completely general

PSEUDOBULGE FORMATION AS A DYNAMICAL RATHER THAN A SECULAR PROCESS

Energy Technology Data Exchange (ETDEWEB)

Guedes, Javiera; Mayer, Lucio; Carollo, Marcella [Institute for Astronomy, ETH Zuerich, Wolgang-Pauli-Strasse 27, 8093 Zurich (Switzerland); Madau, Piero [Department of Astronomy and Astrophysics, University of California, 1156 High Street, Santa Cruz, CA 95064 (United States)

2013-07-20

We investigate the formation and evolution of the pseudobulge in 'Eris', a high-resolution N-body + smoothed particle hydrodynamic cosmological simulation that successfully reproduces a Milky-Way-like massive late-type spiral in an cold dark matter universe. At the present epoch, Eris has a virial mass M{sub vir} {approx_equal} 8 Multiplication-Sign 10{sup 11} M{sub Sun }, a photometric stellar mass M{sub *} = 3.2 Multiplication-Sign 10{sup 10} M{sub Sun }, a bulge-to-total ratio B/T = 0.26, and a weak nuclear bar. We find that the bulk of the pseudobulge forms quickly at high redshift via a combination of non-axisymmetric disk instabilities and tidal interactions or mergers, both occurring on dynamical timescales, not through slow secular processes at lower redshift. Its subsequent evolution is not strictly secular either, and is closely intertwined with the evolution of the stellar bar. In fact, the structure that we recognize as a pseudobulge today evolved from a stellar bar that formed at high redshift due to tidal interactions with satellites, was destroyed by minor mergers at z {approx} 3, re-formed shortly after, and weakened again following a steady gas inflow at z {approx}< 1. The gradual dissolution of the bar ensued at z {approx} 1 and continues until the present without increasing the stellar velocity dispersion in the inner regions. In this scenario, the pseudobulge is not a separate component from the inner disk in terms of formation path; rather, it is the first step in the inside-out formation of the baryonic disk, in agreement with the fact that pseudobulges of massive spiral galaxies typically have a dominant old stellar population. If our simulations do indeed reproduce the formation mechanisms of massive spirals, then the progenitors of late-type galaxies should have strong bars and small photometric pseudobulges at high redshift.

Reflections about the mathematics teachers' formation

Directory of Open Access Journals (Sweden)

Maria José de Freitas Mendes

2010-06-01

Full Text Available This paper brings some reflections about the formation of the math teacher that made part of my marsters paper and that aimed to investigate the process of formation of the math teacher. The focus of this study incided at the contributions of teaching practice in the teacher's formation above the new paradigms of formation, as a professional development and as a reflexive teacher. These reflections, from the learning and teaching process and from the meaning of form a teacher analyse the crisis and the restructuration of the teacher's formation and conclude being necessary that in the graduation courses there's a character more practice to the pedagogical formation, making possible for the future teacher to develop attitudes of autonomy, reflexion and investigation

Cosmochemical evidence for astrophysical processes during the formation of our solar system.

Science.gov (United States)

MacPherson, Glenn J; Boss, Alan

2011-11-29

Through the laboratory study of ancient solar system materials such as meteorites and comet dust, we can recognize evidence for the same star-formation processes in our own solar system as those that we can observe now through telescopes in nearby star-forming regions. High temperature grains formed in the innermost region of the solar system ended up much farther out in the solar system, not only the asteroid belt but even in the comet accretion region, suggesting a huge and efficient process of mass transport. Bi-polar outflows, turbulent diffusion, and marginal gravitational instability are the likely mechanisms for this transport. The presence of short-lived radionuclides in the early solar system, especially (60)Fe, (26)Al, and (41)Ca, requires a nearby supernova shortly before our solar system was formed, suggesting that the Sun was formed in a massive star-forming region similar to Orion or Carina. Solar system formation may have been "triggered" by ionizing radiation originating from massive O and B stars at the center of an expanding HII bubble, one of which may have later provided the supernova source for the short-lived radionuclides. Alternatively, a supernova shock wave may have simultaneously triggered the collapse and injected the short-lived radionuclides. Because the Sun formed in a region where many other stars were forming more or less contemporaneously, the bi-polar outflows from all such stars enriched the local region in interstellar silicate and oxide dust. This may explain several observed anomalies in the meteorite record: a near absence of detectable (no extreme isotopic properties) presolar silicate grains and a dichotomy in the isotope record between (26)Al and nucleosynthetic (nonradiogenic) anomalies.

Stereological analysis of structure formation for solid WC-Co alloys in the process of carbide powder consolidation

Energy Technology Data Exchange (ETDEWEB)

Chernyavskij, K S

1986-03-01

Evolution of particle size distribution in carbide powders of different technological prehistory is studied in the process of their consolidation as a hard alloy. A successive estimate on identical preparations is used to study a structural powder->alloy transition. Temperature dependences of integral measures of the consolidated structure and characteristics of its heterogeneity are studied. It is shown that all studied structural rearrangements: formation of regular alternation of carbide and binding phases, development of particle-phase interfaces, change in size distribution - more intensely proceed in the high-temperature carbide base alloy.

Comparative study of the formation of brominated disinfection byproducts in UV/persulfate and UV/H2O2 oxidation processes in the presence of bromide.

Science.gov (United States)

Wang, Lu; Ji, Yuefei; Lu, Junhe; Kong, Deyang; Yin, Xiaoming; Zhou, Quansuo

2017-10-01

The objective of this research was to compare the transformation of Br - and formation of brominated byproducts in UV/persulfate (PS) and UV/H 2 O 2 processes. It was revealed that Br - was efficiently transformed to free bromine which reacted with humic acid (HA) or dihydroxybenzoic acid resulting in the formation of brominated byproducts such as bromoacetic acids (BAAs) in UV/PS system. In contrast, no free bromine and brominated byproducts could be detected in UV/H 2 O 2 system, although the oxidization of Br - was evident. We presumed that the oxidation of Br - by hydroxyl radicals led to the formation of bromine radicals. However, the bromine radical species could be immediately reduced back to Br - by H 2 O 2 before coupling to each other to form free bromine, which explains the undetection of free bromine and BAAs in UV/H 2 O 2 . In addition to free bromine, we found that the phenolic functionalities in HA molecules, which served as the principal reactive sites for free chlorine attack, could be in situ generated when HA was exposed to free radicals. This study demonstrates that UV/H 2 O 2 is more suitable than UV/PS for the treatment of environmental matrices containing Br - . Graphical abstract Graphical abstract.

Thermal Diffusion Processes in Metal-Tip-Surface Interactions: Contact Formation and Adatom Mobility

DEFF Research Database (Denmark)

Sørensen, Mads Reinholdt; Jacobsen, Karsten Wedel; Jonsson, Hannes

1996-01-01

and the surface can occur by a sequence of atomic hop and exchange processes which become active on a millisecond time scale when the tip is about 3-5 Angstrom from the surface. Adatoms on the surface are stabilized by the presence of the tip and energy barriers for diffusion processes in the region under the tip......We have carried out computer simulations to identify and characterize various thermally activated atomic scale processes that can play an important role in room temperature experiments where a metal tip is brought close to a metal surface. We find that contact formation between the tip...

Genes involved in Listeria monocytogenes biofilm formation at a simulated food processing plant temperature of 15 °C.

Science.gov (United States)

Piercey, Marta J; Hingston, Patricia A; Truelstrup Hansen, Lisbeth

2016-04-16

Listeria monocytogenes is a pathogenic foodborne bacterium whose persistence in food processing environments is in part attributed to its biofilm formation. Most biofilm studies have been carried out at 30-37 °C rather than at temperatures found in the food processing plants (i.e., 10-20 °C). The objective of the present study was to mine for novel genes that contribute to L. monocytogenes biofilm formation at 15 °C using the random insertional mutagenesis approach. A library of 11,024 L. monocytogenes 568 (serotype 1/2a) Himar1 insertional mutants was created. Mutants with reduced or enhanced biofilm formation at 15 °C were detected in microtiter plate assays with crystal violet and safranin staining. Fourteen mutants expressed enhanced biofilm phenotypes, and harbored transposon insertions in genes encoding cell wall biosynthesis, motility, metabolism, stress response, and cell surface associated proteins. Deficient mutants (n=5) contained interruptions in genes related to peptidoglycan, teichoic acid, or lipoproteins. Enhanced mutants produced significantly (pbiofilm formed on stainless steel (SS) coupons at 15 °C (48 h) than deficient mutants, which were also more sensitive to benzalkonium chloride. All biofilm deficient mutants and four enhanced mutants in the microtiter plate assay (flaA, cheR, lmo2563 and lmo2488) formed no biofilm in a peg lid assay (Calgary biofilm device) while insertions in lmo1224 and lmo0543 led to excess biofilm in all assays. Two enhanced biofilm formers were more resistant to enzymatic removal with DNase, proteinase K or pectinase than the parent strain. Scanning electron microscopy of individual biofilms made by five mutants and the parent on SS surfaces showed formation of heterogeneous biofilm with dense zones by immotile mutants, while deficient mutants exhibited sparse growth. In conclusion, interruptions of 9 genes not previously linked to biofilm formation in L. monocytogenes (lmo2572, lmo2488 (uvrA), lmo1224, lmo0434

Simulation of the Processes of Formation of a Dust Cloud in a Vacuum and in the Absence of Gravitation

Science.gov (United States)

Avdeev, A. V.; Boreisho, A. S.; Ivakin, S. V.; Moiseev, A. A.; Savin, A. V.; Sokolov, E. I.; Smirnov, P. G.

2018-01-01

This article is devoted to the simulation of the processes of formation of dust clouds in the absence of gravitation, which is necessary for understanding the processes proceeding in dust clusters in outer space, upper planetary atmosphere, and on the surface of space objects, as well as for evaluating the possibilities of creating disperse structures with given properties. The chief aim of the simulation is to determine the general laws of the dynamics of the dust cloud at the initial stage of its formation. With the use of the original approach based on the particle-in-cell method that permits investigating the mechanics of large ensembles of particles on contemporary computational platforms, we consider the mechanics of a dusty medium in the process of its excitation in a closed container due to the vibration of the walls, and then in the process of particle scattering when the container opens in outer space. The main formation mechanisms of a dust formation have been elucidated, and the possibilities of mathematical simulation for predicting spatial and time characteristics of disperse structures have been shown.

A new approach to global health institutions? A case study of new vaccine introduction and the formation of the GAVI Alliance.

Science.gov (United States)

Sandberg, Kristin Ingstad; Andresen, Steinar; Bjune, Gunnar

2010-10-01

There is an emerging research agenda to analyse empirically the forces driving changes in global health governance. This study applies analytical tools from international relations research to explain the formation of international health regimes. The study utilizes two explanatory perspectives: individual leadership, and the interests of key non-state actors in the formation process, using the case of the formation of the Global Alliance for Vaccines and Immunization (GAVI) from 1995 to 1999. The case study is based on material from interviews with key actors, an archival review of documents from the Children's Vaccine Initiative (CVI), and published literature. Findings show that the regime formation process was initiated by individuals who were primarily affiliated to scientific communities and who led to the World Bank and the Gates Foundation becoming champions of a new coordinating mechanism for new vaccine introduction. Negotiations in the regime formation process were between a small group of founding agencies with divergent interests regarding immunization priorities. The case also sheds light on the authority of the WHO and the resources of the Gates Foundation in driving the process towards the final structure of the alliance. The paper discusses the potential contribution of the international relations approach compared to policy research as a way of understanding the institutional dynamics of global health, particularly in respect of relations between countries and non-state actors.

Evaluation of trace organic contaminants in ultra-pure water production processes by measuring total organic halogen formation potential

International Nuclear Information System (INIS)

Urano, Kohei; Iwase, Yoko

1984-01-01

A new procedure for the determination of organic substances in water with high accuracy and high sensitivity was proposed, in which a hypochlorite is added to water, and the resultant total amount of organic halogen compounds (TOX formation potential) was measured, and it was applied to the evaluation of trace organic contaminants in ultra-pure water production process. In this investigation, the TOX formation potential of the raw water which was to be used for the ultra-pure water production process, intermediately treated water and ultra-pure water was measured to clarify the behavior of organic substances in the ultra-pure water production process and to demonstrate the usefulness of this procedure to evaluate trace organic contaminants in water. The measurement of TOX formation potential requires no specific technical skill, and only a short time, and gives accurate results, therefore, it is expected that the water quality control in the ultra-pure water production process can be performed more exactly by applying this procedure. (Yoshitake, I.)

Standard format and content of license applications for plutonium processing and fuel fabrication plants

International Nuclear Information System (INIS)

1976-01-01

The standard format suggested for use in applications for licenses to possess and use special nuclear materials in Pu processing and fuel fabrication plants is presented. It covers general description of the plant, summary safety assessment, site characteristics, principal design criteria, plant design, process systems, waste confinement and management, radiation protection, accident safety analysis, conduct of operations, operating controls and limits, and quality assurance

Control of aliphatic halogenated DBP precursors with multiple drinking water treatment processes: Formation potential and integrated toxicity.

Science.gov (United States)

Zhang, Yimeng; Chu, Wenhai; Yao, Dechang; Yin, Daqiang

2017-08-01

The comprehensive control efficiency for the formation potentials (FPs) of a range of regulated and unregulated halogenated disinfection by-products (DBPs) (including carbonaceous DBPs (C-DBPs), nitrogenous DBPs (N-DBPs), and iodinated DBPs (I-DBPs)) with the multiple drinking water treatment processes, including pre-ozonation, conventional treatment (coagulation-sedimentation, pre-sand filtration), ozone-biological activated carbon (O 3 -BAC) advanced treatment, and post-sand filtration, was investigated. The potential toxic risks of DBPs by combing their FPs and toxicity values were also evaluated. The results showed that the multiple drinking water treatment processes had superior performance in removing organic/inorganic precursors and reducing the formation of a range of halogenated DBPs. Therein, ozonation significantly removed bromide and iodide, and thus reduced the formation of brominated and iodinated DBPs. The removal of organic carbon and nitrogen precursors by the conventional treatment processes was substantially improved by O 3 -BAC advanced treatment, and thus prevented the formation of chlorinated C-DBPs and N-DBPs. However, BAC filtration leads to the increased formation of brominated C-DBPs and N-DBPs due to the increase of bromide/DOC and bromide/DON. After the whole multiple treatment processes, the rank order for integrated toxic risk values caused by these halogenated DBPs was haloacetonitriles (HANs)≫haloacetamides (HAMs)>haloacetic acids (HAAs)>trihalomethanes (THMs)>halonitromethanes (HNMs)≫I-DBPs (I-HAMs and I-THMs). I-DBPs failed to cause high integrated toxic risk because of their very low FPs. The significant higher integrated toxic risk value caused by HANs than other halogenated DBPs cannot be ignored. Copyright © 2017. Published by Elsevier B.V.

Monitoring alloy formation during mechanical alloying process by x-ray diffraction techniques

International Nuclear Information System (INIS)

Abdul Kadir Masrom; Noraizam Md Diah; Mazli Mustapha

2002-01-01

Monitoring alloying (MA) is a novel processing technique that use high energy impact ball mill to produce alloys with enhanced properties and microscopically homogeneous materials starting from various powder mixtures. Mechanical alloying process was originally developed to produce oxide dispersion strengthened nickel superalloys. In principal, in high-energy ball milling process, alloy is formed by the result of repeated welding, fracturing and rewelding of powder particles in a high energy ball mill. In this process a powder mixture in a ball mill is subjected to high-energy collisions among balls. MA has been shown to be capable of synthesizing a variety of materials. It is known to be capable to prepare equilibrium and non-equilibrium phases starting from blended elemental or prealloyed powders. The process ability to produce highly metastable materials such as amorphous alloys and nanostructured materials has made this process attractive and it has been considered as a promising material processing technique that could be used to produce many advanced materials at low cost. The present study explores the conditions under which aluminum alloys formation occurs by ball milling of blended aluminum and its alloying elements powders. In this work, attempt was made in producing aluminum 2024 alloys by milling of blended elemental aluminum powder of 2024 composition in a stainless steel container under argon atmosphere for up to 210 minutes. X-ray diffraction together with thermal analysis techniques has been used to monitor phase changes in the milled powder. Results indicate that, using our predetermined milling parameters, alloys were formed after 120 minutes milling. The thermal analysis data was also presented in this report. (Author)

Galaxy Formation

DEFF Research Database (Denmark)

Sparre, Martin

Galaxy formation is an enormously complex discipline due to the many physical processes that play a role in shaping galaxies. The objective of this thesis is to study galaxy formation with two different approaches: First, numerical simulations are used to study the structure of dark matter and how...... galaxies form stars throughout the history of the Universe, and secondly it is shown that observations of gamma-ray bursts (GRBs) can be used to probe galaxies with active star formation in the early Universe. A conclusion from the hydrodynamical simulations is that the galaxies from the stateof...... is important, since it helps constraining chemical evolution models at high redshift. A new project studying how the population of galaxies hosting GRBs relate to other galaxy population is outlined in the conclusion of this thesis. The core of this project will be to quantify how the stellar mass function...

Understanding the process of social network evolution: Online-offline integrated analysis of social tie formation.

Science.gov (United States)

Kwak, Doyeon; Kim, Wonjoon

2017-01-01

It is important to consider the interweaving nature of online and offline social networks when we examine social network evolution. However, it is difficult to find any research that examines the process of social tie formation from an integrated perspective. In our study, we quantitatively measure offline interactions and examine the corresponding evolution of online social network in order to understand the significance of interrelationship between online and offline social factors in generating social ties. We analyze the radio signal strength indicator sensor data from a series of social events to understand offline interactions among the participants and measure the structural attributes of their existing online Facebook social networks. By monitoring the changes in their online social networks before and after offline interactions in a series of social events, we verify that the ability to develop an offline interaction into an online friendship is tied to the number of social connections that participants previously had, while the presence of shared mutual friends between a pair of participants disrupts potential new connections within the pre-designed offline social events. Thus, while our integrative approach enables us to confirm the theory of preferential attachment in the process of network formation, the common neighbor theory is not supported. Our dual-dimensional network analysis allows us to observe the actual process of social network evolution rather than to make predictions based on the assumption of self-organizing networks.

Understanding the process of social network evolution: Online-offline integrated analysis of social tie formation.

Directory of Open Access Journals (Sweden)

Doyeon Kwak

Full Text Available It is important to consider the interweaving nature of online and offline social networks when we examine social network evolution. However, it is difficult to find any research that examines the process of social tie formation from an integrated perspective. In our study, we quantitatively measure offline interactions and examine the corresponding evolution of online social network in order to understand the significance of interrelationship between online and offline social factors in generating social ties. We analyze the radio signal strength indicator sensor data from a series of social events to understand offline interactions among the participants and measure the structural attributes of their existing online Facebook social networks. By monitoring the changes in their online social networks before and after offline interactions in a series of social events, we verify that the ability to develop an offline interaction into an online friendship is tied to the number of social connections that participants previously had, while the presence of shared mutual friends between a pair of participants disrupts potential new connections within the pre-designed offline social events. Thus, while our integrative approach enables us to confirm the theory of preferential attachment in the process of network formation, the common neighbor theory is not supported. Our dual-dimensional network analysis allows us to observe the actual process of social network evolution rather than to make predictions based on the assumption of self-organizing networks.

The study of ikaite formation in sea ice

Science.gov (United States)

Hu, Y.; Nehrke, G.; Dieckmann, G.; Völker, C.; Wolf-Gladrow, D.

2012-04-01

Ikaite (CaCO3.6H2O) is a metastable mineral of calcium carbonate, which is usually found in environments characterized by low temperature (below 5° C), high pH, high alkalinity, high concentration of phosphate and organic matter. Although synthetic CaCO3.6H2O was already known from laboratory studies in 1865, ikaite was first observed in nature in 1963. Recently, Dieckmann et al. (2008, 2010) discovered this mineral in sea ice, which at the same time, was the first direct proof of CaCO3 precipitation in sea ice. However, little is known about the mechanism of ikaite formation in sea ice. Our study focuses on how physico-chemical processes in sea ice affect the formation of ikaite. Experiments were set up at pH ranging from 8.5 to 9.0, and salinity ranging from 0 to 105 at 0 ° C, in order to examine the effect of pH, salinity and also phosphate on the formation of ikaite. Preliminary results read: (1) Experiments show that ikaite can form at different pH levels (8.5~9.0). At high pH, the induction time (the time when the crystals start to precipitate) is shorter which means high pH favours the formation of ikaite. This might be expected given higher CO32- concentrations and thus higher saturation levels for ikaite with increasing pH. (2) The results of experiments with different salinities show that ikaite can form over wide range of salinities from 0 to 105 both in Artificial Sea Water (ASW) and NaCl solution in the presence of phosphate. In ASW, the induction time increases with salinity from S = 0 to S =105; while in NaCl solution, the induction time first increases with salinity and then decreases with the further increase of salinity. Salinity plays both positive and negative roles in the formation of ikaite. On the one hand, the increase in salinity will increase the fraction of CO32- in DIC. On the other hand, the increase in salinity means more ions are involved in the solution, which will reduce the activities of Ca2+ and CO32-by forming ion pairs with

Can Process Understanding Help Elucidate The Structure Of The Critical Zone? Comparing Process-Based Soil Formation Models With Digital Soil Mapping.

Science.gov (United States)

Vanwalleghem, T.; Román, A.; Peña, A.; Laguna, A.; Giráldez, J. V.

2017-12-01

There is a need for better understanding the processes influencing soil formation and the resulting distribution of soil properties in the critical zone. Soil properties can exhibit strong spatial variation, even at the small catchment scale. Especially soil carbon pools in semi-arid, mountainous areas are highly uncertain because bulk density and stoniness are very heterogeneous and rarely measured explicitly. In this study, we explore the spatial variability in key soil properties (soil carbon stocks, stoniness, bulk density and soil depth) as a function of processes shaping the critical zone (weathering, erosion, soil water fluxes and vegetation patterns). We also compare the potential of traditional digital soil mapping versus a mechanistic soil formation model (MILESD) for predicting these key soil properties. Soil core samples were collected from 67 locations at 6 depths. Total soil organic carbon stocks were 4.38 kg m-2. Solar radiation proved to be the key variable controlling soil carbon distribution. Stone content was mostly controlled by slope, indicating the importance of erosion. Spatial distribution of bulk density was found to be highly random. Finally, total carbon stocks were predicted using a random forest model whose main covariates were solar radiation and NDVI. The model predicts carbon stocks that are double as high on north versus south-facing slopes. However, validation showed that these covariates only explained 25% of the variation in the dataset. Apparently, present-day landscape and vegetation properties are not sufficient to fully explain variability in the soil carbon stocks in this complex terrain under natural vegetation. This is attributed to a high spatial variability in bulk density and stoniness, key variables controlling carbon stocks. Similar results were obtained with the mechanistic soil formation model MILESD, suggesting that more complex models might be needed to further explore this high spatial variability.

Theoretical study of C-C bond formation in the methanol to gasoline process

NARCIS (Netherlands)

Blaszkowski, S.R.; Santen, van R.A.

1997-01-01

Density functional theory is used to study one of the most successful routes to the production of synthetic fuels, the conversion of methanol to gasoline (MTG process) with an acidic zeolite. With our calculations we have determined transition states and adsorption complexes of reactants,

Kinetics of the process of formation and high-temperature oxidation of electrospark coatings on steel

International Nuclear Information System (INIS)

Verkhoturov, A.D.; Chiplik, V.N.; Egorov, F.F.; Lavrenko, V.A.; Podchernyaeva, I.A.; Shemet, V.Z.

1986-01-01

This work is a study of the kinetics of formation and of the heat resistance of electrospark coatings based on the composite TiB 2 -Mo with varying molybdenum content. In the process of electrospark alloying they measured the specific erosion of the anode and the increase in weight of the cathode with an accuracy not worse than 5%. Electrospark coatings of TiB 2 -Mo on steel 45 are marked by improved scaling resistance at temperatures above 900 C. Their scaling resistance and also the effectiveness of the process of electrospark alloying increase with increasing content of the phase B-MoB in the coating because molybdenum borate forms during its high-temperature oxidation. Illustrations and table are included

Hyper-massive cloud, shock and stellar formation efficiency

International Nuclear Information System (INIS)

Louvet, Fabien

2014-01-01

O and B types stars are of paramount importance in the energy budget of galaxies and play a crucial role enriching the interstellar medium. However, their formation, unlike that of solar-type stars, is still subject to debate, if not an enigma. The earliest stages of massive star formation and the formation of their parent cloud are still crucial astrophysical questions that drew a lot of attention in the community, both from the theoretical and observational perspective, during the last decade. It has been proposed that massive stars are born in massive dense cores that form through very dynamic processes, such as converging flows of gas. During my PhD, I conducted a thorough study of the formation of dense cores and massive stars in the W43-MM1 supermassive structure, located at 6 kpc from the sun. At first, I showed a direct correlation between the star formation efficiency and the volume gas density of molecular clouds, in contrast with scenarios suggested by previous studies. Indeed, the spatial distribution and mass function of the massive dense cores currently forming in W43-MM1 suggests that this supermassive filament is undergoing a star formation burst, increasing as one approaches its center. I compared these observational results with the most recent numerical and analytical models of star formation. This comparison not only provides new constraints on the formation of supermassive filaments, but also suggests that understanding star formation in high density, extreme ridges requires a detailed portrait of the structure of these exceptional objects. Second, having shown that the formation of massive stars depends strongly on the properties of the ridges where they form, I studied the formation processes of these filaments, thanks of the characterization of their global dynamics. Specifically, I used a tracer of shocks (SiO molecule) to disentangle the feedback of local star formation processes (bipolar jets and outflows) from shocks tracing the pristine

Spiritual formation and the nurturing of creative spirituality: A case study in Proverbs

Directory of Open Access Journals (Sweden)

Anneke Viljoen

2016-03-01

Full Text Available The article is positioned in the interface between Old Testament scholarship and the discipline of spiritual direction of which spiritual formation is a component. The contribution that a Ricoeurian hermeneutic may make in unlocking the potential which an imaginal engagement with the book of Proverbs may hold for the discipline of spiritual formation was explored. Specifically three aspects of the text of Proverbs illustrated the creative process at work in the text, and how it converges with the concept of spiritual formation and the nurturing of creative spirituality. These aspects were, the development in Lady Wisdom�s discourses, the functional definition of the fear of Yahweh (illustrated from Proverbs 10:1�15:33, and the paradigmatic character of the book of Proverbs.Intradisciplinary and/or interdisciplinary implications: The research is positioned in the interface between Old Testament studies and Practical Theology. The research results in the enhancement of the interdisciplinary dialogue and interchange of resources between the named disciplines with regard to the interest in formation of persons that the biblical book of Proverbs and the discipline of spiritual formation shares.Keywords: Spiritual formation; fear of Yahweh; Proverbs; Wisdom; Hermeneutics; Paul Ricoeur; Symbolic world; Textual reference

Dynamics of ordering processes in annealed dilute systems: Island formation, vacancies at domain boundaries, and compactification

DEFF Research Database (Denmark)

Shah, Peter Jivan; Mouritsen, Ole G.

1990-01-01

The dynamics of the ordering processes in two-dimensional lattice models with annealed vacancies and nonconserved order parameter is studied as a function of temperature and vacancy concentration by means of Monte Carlo temperature-quenching simulations. The models are Ising antiferromagnets...... with couplings leading to twofold-degenerate as well as fourfold-degenerate ordering. The models are quenched into a phase-separation region, which makes it possible for both types of ordering to observe the following scenario of ordering processes: (i) early-time nucleation and growth of ordered domains, (ii......) intermediate-time trapping of the mobile vacancies at the domain boundaries, and (iii) late-time diffusion of vacancies along the domain-boundary network towards the surface. In the case of high dilution, the ordering processes correspond to early-time island formation and late-time coarsening...

NJOY. A comprehensive system for the processing of ENDF formatted nuclear data

International Nuclear Information System (INIS)

Muir, D.W.

1990-07-01

An introduction to the program system NJOY is given which processes data files of evaluated neutron nuclear data coded in ENDF format. NJOY is primarily used for neutron and photon transport calculations for nuclear power reactor design. The NJOY code is not available from the IAEA Nuclear Data Section but may be obtained from the Reactor Shielding Information Center, Oak Ridge, USA. (author). 10 refs, 1 fig

Drebrin controls neuronal migration through the formation and alignment of the leading process.

Science.gov (United States)

Dun, Xin-peng; Bandeira de Lima, Tiago; Allen, James; Geraldo, Sara; Gordon-Weeks, Phillip; Chilton, John K

2012-03-01

Formation of a functional nervous system requires neurons to migrate to the correct place within the developing brain. Tangentially migrating neurons are guided by a leading process which extends towards the target and is followed by the cell body. How environmental cues are coupled to specific cytoskeletal changes to produce and guide leading process growth is unknown. One such cytoskeletal modulator is drebrin, an actin-binding protein known to induce protrusions in many cell types and be important for regulating neuronal morphology. Using the migration of oculomotor neurons as a model, we have shown that drebrin is necessary for the generation and guidance of the leading process. In the absence of drebrin, leading processes are not formed and cells fail to migrate although axon growth and pathfinding appear grossly unaffected. Conversely, when levels of drebrin are elevated the leading processes turn away from their target and as a result the motor neuron cell bodies move along abnormal paths within the brain. The aberrant trajectories were highly reproducible suggesting that drebrin is required to interpret specific guidance cues. The axons and growth cones of these neurons display morphological changes, particularly increased branching and filopodial number but despite this they extend along normal developmental pathways. Collectively these results show that drebrin is initially necessary for the formation of a leading process and subsequently for this to respond to navigational signals and grow in the correct direction. Furthermore, we have shown that the actions of drebrin can be segregated within individual motor neurons to direct their migration independently of axon guidance. Copyright © 2012 Elsevier Inc. All rights reserved.

Clinical Study on the Etiology of Postthyroidectomy Skin Sinus Formation

Directory of Open Access Journals (Sweden)

Shan Jin

2017-01-01

Full Text Available Background. Thyroidectomy is one of the most frequently performed surgical procedures worldwide. Despite technical advances and high experience of thyroidectomy of specialized centers, it is still burdened by a significant rate of postoperative complications. Among them, the skin sinus formation is an extremely rare postthyroidectomy complication. Here, we first report the incidence of the skin sinus formation after thyroidectomy to identify the causes for skin sinus formation after thyroidectomy and to discuss its prevention and treatment options. Methods. A retrospective analysis was carried out of patients who underwent excision operation of fistula for postthyroidectomy skin sinus formation. Data were retrieved from medical records department of the Affiliated Hospital of Inner Mongolia Medical University. Results. Of the 5,686 patients who underwent thyroid surgery, only 5 patients (0.088% had developed skin sinus formation. All 5 patients successfully underwent complete excision of fistula. Conclusion. Infection, foreign body, thyroid surgery procedure, combined disease, and iatrogenic factors may be related with skin sinus formation after thyroidectomy. To reduce the recurrence of postoperative infections and sinus formation, intra- and postoperative compliance with aseptic processing, intraoperative use absorbable surgical suture/ligature, repeated irrigation and drainage, and postoperative administration of anti-inflammatory treatment are to be followed.

The formation and the evolution process of the Jilin meteorite

International Nuclear Information System (INIS)

Duyang, Z.Y.

1983-01-01

Based on the data from an integrated study by a multidisciplinary group on the Jilin meteorite, we discuss the following aspects concerning its formation and evolution: (1) The fractionation-condensation of the solar nebula was examined based on the condensation and solidification age and the mineral composition of the Jilin meteorite. (2) The thermometamorphic history of the Jilin parent body was discussed based on the data on the loss of rare gases, the chemical composition of the whole rock, the self-purification of rare-earth elements and the composition stability of olivine and orthopyroxene. (3) The cooling process of the Jilin parent body was analyzed according to the Ni content and the width of taenite, and the retentivity of argon and fission tracks in the minerals. (4) The breakup of the Jilin parent body and its cosmic ray irradiation history: Based on the measurements of the cosmogenic nuclides as He 3 , Ne/sup 20,21,22/, Ar 38 , Na 22 , Al 26 , Mn 54 , Mn 53 , Co 60 etc., a two-stage model of the irradiation history of the Jilin meteorite was proposed. From the data on the Jilin meteorite parent body of the first stage (the age = 10--11 MY and r = 10 m) and that of the second stage (the age = 0.3--0.5 MY and r = 80--90 cm). The relative positions of samples in the parent body, their burial depths as well as the post-atmospheric loss by ignition were determined. (5) The falling process of the Jilin meteorite: The orbits of the Jilin meteor in the solar system and in the atmosphere, and its falling process were discussed

hPDB – Haskell library for processing atomic biomolecular structures in protein data bank format

OpenAIRE

Gajda, Michał Jan

2013-01-01

Background Protein DataBank file format is used for the majority of biomolecular data available today. Haskell is a lazy functional language that enjoys a high-level class-based type system, a growing collection of useful libraries and a reputation for efficiency. Findings I present a fast library for processing biomolecular data in the Protein Data Bank format. I present benchmarks indicating that this library is faster than other frequently used Protein Data Bank parsing programs. The propo...

Galaxy formation-a condensation process just after recombination

International Nuclear Information System (INIS)

Lessner, G.

1998-01-01

A scenario of galaxy formation is put forward which is a process of sudden condensation just after recombination. It is essentially based on the fact that the cosmic-matter gas after recombination is a general relativistic Boltzmann gas which runs within a few 10 6 years into a tate very close to collision-dominated equilibrium. The mass spectrum of axially symmetric condensation 'drops' extends from the lower limit M ≅ 10 5 M to the upper limit M ≅ 10 12 M. The lower-limit masses are spheres whereas the upper-limit masses are thin pancakes. These pancakes contract within a time of about 2.5 · 10 9 y to rotating spiral galaxies with ordinary proportions. In this final state they have a redshift z ≅ 3. At an earlier time during their contraction they are highly active and are observed with a redshift z ≅ 5

Biogenic amine formation and nitrite reactions in meat batter as affected by high-pressure processing and chilled storage.

Science.gov (United States)

Ruiz-Capillas, C; Aller-Guiote, P; Carballo, J; Colmenero, F Jiménez

2006-12-27

Changes in biogenic amine formation and nitrite depletion in meat batters as affected by pressure-temperature combinations (300 MPa/30 min/7, 20, and 40 degrees C), cooking process (70 degrees C/30 min), and storage (54 days/2 degrees C) were studied. Changes in residual nitrite concentration in raw meat batters were conditioned by the temperature and not by the pressure applied. Cooking process decreased (P nitrite concentration in all samples. High-pressure processing and cooking treatment increased (P nitrite concentration decreased with pressure processing, no effect was observed with the heating process of meat batters. High-pressure processing conditions had no effect on the rate of residual nitrite loss throughout the storage. The application of high pressure decreased (P processing conditions, generally, throughout storage biogenic amine levels did not change or increased, although quantitatively this effect was not very important.

Contribution of l-theanine to the formation of 2,5-dimethylpyrazine, a key roasted peanutty flavor in Oolong tea during manufacturing processes.

Science.gov (United States)

Guo, Xiangyang; Song, Chuankui; Ho, Chi-Tang; Wan, Xiaochun

2018-10-15

l-Theanine, the most abundant amino acid in tea, is widely believed to be associated with the tea taste, however, its contribution to the formation of tea aroma is still unknown. Volatiles were determined and nitrogen-containing compounds formed during manufacturing processes were quantified. Lower levels of total sugar and l-theanine were detected in the Oolong tea product undergoing full fire processing (FFOT) suggesting that l-theanine probably involved in the volatile formation during manufacturing processes. Methylpyrazine and 2,5-dimethylpyrazine, two newly formed compounds in FFOT, together with other volatiles were successfully detected in a model thermal reaction of d-glucose and l-theanine (GT-MTR) but not detectable in thermal reactions with single d-glucose (G-MTR) or l-theanine (T-MTR). The concentration of 2,5-dimethylpyrazine increased significantly by adding additional l-theanine to 2nd roasted tea. Our study demonstrated that l-theanine, at least partly, contributed to the formation of 2,5-dimethylpyrazine, a key roasted peanutty flavor in Oolong tea. Copyright © 2018. Published by Elsevier Ltd.

TRANSFORMATION THE ROLE OF THINK TANKS IN THE PROCESS OF GOVERNMENT POLICY FORMATION IN THE CONTEXT OF WORLD FINANCIAL CRISIS IN 2008-2010

Directory of Open Access Journals (Sweden)

Barsukov Anton Yuryevich

2013-04-01

Full Text Available The study is dedicated to the evolution of think tanks role as a political tool of government policy formation in the context of world financial crisis. The main purpose of the study was the description of such evolution, revealing of the basic differences with the analytical centers, founded before 2008 in China, and finding-out of think tank’ role in the process of anticrisis campaign. The actuality of the study is obvious, proceeding from there are not any other study dedicated to the Chinese “new type” think tanks in Russian politologycal science. The appearance of “new type” think tanks in the PRC is mentioned in the study. The special meaning devoted to the increasing of returnees’ role in the process of government policy formation. The author makes the conclusion that “new type” think tanks have a very important meaning just as in the process of anticrisis campaign so in the public life. “New type” think tanks have more independence from the official authorities.

76 FR 40379 - New Proposed Collection; Comment Request; Study Logistic Formative Research Methodology Studies...

Science.gov (United States)

2011-07-08

...; Comment Request; Study Logistic Formative Research Methodology Studies for the National Children's Study... Collection Title: Study Logistics Formative Research Methodology Studies for the National Children's Study... national longitudinal study of environmental influences (including physical, chemical, biological, and...

Formation of Large-scale Coronal Loops Interconnecting Two Active Regions through Gradual Magnetic Reconnection and an Associated Heating Process

Science.gov (United States)

Du, Guohui; Chen, Yao; Zhu, Chunming; Liu, Chang; Ge, Lili; Wang, Bing; Li, Chuanyang; Wang, Haimin

2018-06-01

Coronal loops interconnecting two active regions (ARs), called interconnecting loops (ILs), are prominent large-scale structures in the solar atmosphere. They carry a significant amount of magnetic flux and therefore are considered to be an important element of the solar dynamo process. Earlier observations showed that eruptions of ILs are an important source of CMEs. It is generally believed that ILs are formed through magnetic reconnection in the high corona (>150″–200″), and several scenarios have been proposed to explain their brightening in soft X-rays (SXRs). However, the detailed IL formation process has not been fully explored, and the associated energy release in the corona still remains unresolved. Here, we report the complete formation process of a set of ILs connecting two nearby ARs, with successive observations by STEREO-A on the far side of the Sun and by SDO and Hinode on the Earth side. We conclude that ILs are formed by gradual reconnection high in the corona, in line with earlier postulations. In addition, we show evidence that ILs brighten in SXRs and EUVs through heating at or close to the reconnection site in the corona (i.e., through the direct heating process of reconnection), a process that has been largely overlooked in earlier studies of ILs.

Laboratory Studies of the Role of Amines in Particle Formation, Growth and Climate

Energy Technology Data Exchange (ETDEWEB)

Finlayson-Pitts, Barbara J. [Univ. of California, Irvine, CA (United States)

2015-02-07

Organosulfur compounds have a variety of sources, particularly biological processes in the oceans. Their oxidation in air forms sulfur dioxide, which is further oxidized to sulfuric acid, as well as methanesulfonic acid (MSA). While sulfuric acid is a well known precursor to particles in air, MSA had not been regarded as a source of new particle formation. Laboratory studies were carried out under this project that showed MSA forms new particles quite efficiently in the presence of amines and water vapor. The data could be reproduced with a relatively simple kinetics model representing cluster formation and growth, which is promising for representing this chemistry in global climate models. The initial steps in the kinetics scheme are based on quantum chemical calculations of likely clusters. The organosulfur chemistry was introduced into an atmospheric model for southern California and used to predict the impact of going to a fossil-fuel free world in which anthropogenic emissions of SO₂ are removed, but the natural processes remain.

Interstellar Medium and Star Formation Studies with the Square

Indian Academy of Sciences (India)

2Indian Institute of Space Science and Technology, Valiamala,. Thiruvananthapuram ... which describes the details of the processes that drive formation of stars ..... This is primarily because, most of the commonly used direct observational ... tive spectral indices will allow us to infer the energy spectrum of the population of.

Gas hydrate formation process for pre-combustion capture of carbon dioxide

International Nuclear Information System (INIS)

Lee, Hyun Ju; Lee, Ju Dong; Linga, Praveen; Englezos, Peter; Kim, Young Seok; Lee, Man Sig; Kim, Yang Do

2010-01-01

In this study, gas hydrate from CO 2 /H 2 gas mixtures with the addition of tetrahydrofuran (THF) was formed in a semi-batch stirred vessel at various pressures and temperatures to investigate the CO 2 separation/recovery properties. This mixture is of interest to CO 2 separation and recovery from Integrated Gasification Combine Cycle (IGCC) power plants. During hydrate formation the gas uptake was determined and composition changes in the gas phase were obtained by gas chromatography. The impact of THF on hydrate formation from the CO 2 /H 2 was observed. The addition of THF significantly reduced the equilibrium formation conditions. 1.0 mol% THF was found to be the optimum concentration for CO 2 capture based on kinetic experiments. The present study illustrates the concept and provides thermodynamic and kinetic data for the separation/recovery of CO 2 (pre-combustion capture) from a fuel gas (CO 2 /H 2 ) mixture.

Effects of Fuel Quantity on Soot Formation Process for Biomass-Based Renewable Diesel Fuel Combustion

KAUST Repository

Jing, Wei; Wu, Zengyang; Roberts, William L.; Fang, Tiegang

2016-01-01

Soot formation process was investigated for biomass-based renewable diesel fuel, such as biomass to liquid (BTL), and conventional diesel combustion under varied fuel quantities injected into a constant volume combustion chamber. Soot measurement

Process for recovering oil from subterranean formations

International Nuclear Information System (INIS)

Knight, B.; Gogarty, W.B.

1978-01-01

Improved flooding of oil-bearing formations is obtained by injecting and displacing through the formation a saline solution containing a water-soluble, substantially linear, high molecular weight polymer obtained by irradiating an aqueous solution of an ethylenically unsaturated monomer and a water-soluble salt under controlled conditions of concentration, radiation intensity, conversion, and total radiation dose. The saline water can contain at least 15,000 ppm of TDS (total dissolved solids) and at least 50 ppm and preferably 300 ppm of polyvalent cations. (Auth.)

Seminary Formation: A Case Study from the Pontifical Beda College, Rome

Science.gov (United States)

Strange, Roderick

2015-01-01

This case study account reviews issues related to seminary formation and education at the Beda College, Rome, including Fundamentals of Formation, Community Life, Organizing Formation, Intellectual Formation, Spiritual Formation, Pastoral Formation, and the challenges arising in these fields.

Preliminary study on aerobic granular biomass formation with aerobic continuous flow reactor

Science.gov (United States)

Yulianto, Andik; Soewondo, Prayatni; Handajani, Marissa; Ariesyady, Herto Dwi

2017-03-01

A paradigm shift in waste processing is done to obtain additional benefits from treated wastewater. By using the appropriate processing, wastewater can be turned into a resource. The use of aerobic granular biomass (AGB) can be used for such purposes, particularly for the processing of nutrients in wastewater. During this time, the use of AGB for processing nutrients more reactors based on a Sequencing Batch Reactor (SBR). Studies on the use of SBR Reactor for AGB demonstrate satisfactory performance in both formation and use. SBR reactor with AGB also has been applied on a full scale. However, the use use of SBR reactor still posses some problems, such as the need for additional buffer tank and the change of operation mode from conventional activated sludge to SBR. This gives room for further reactor research with the use of a different type, one of which is a continuous reactor. The purpose of this study is to compare AGB formation using continuous reactor and SBR with same operation parameter. Operation parameter are Organic Loading Rate (OLR) set to 2,5 Kg COD/m3.day with acetate as substrate, aeration rate 3 L/min, and microorganism from Hospital WWTP as microbial source. SBR use two column reactor with volumes 2 m3, and continuous reactor uses continuous airlift reactor, with two compartments and working volume of 5 L. Results from preliminary research shows that although the optimum results are not yet obtained, AGB can be formed on the continuous reactor. When compared with AGB generated by SBR, then the characteristics of granular diameter showed similarities, while the sedimentation rate and Sludge Volume Index (SVI) characteristics showed lower yields.

Dense CO2 as a Solute, Co-Solute or Co-Solvent in Particle Formation Processes: A Review

Directory of Open Access Journals (Sweden)

Ana V. M. Nunes

2011-11-01

Full Text Available The application of dense gases in particle formation processes has attracted great attention due to documented advantages over conventional technologies. In particular, the use of dense CO2 in the process has been subject of many works and explored in a variety of different techniques. This article presents a review of the current available techniques in use in particle formation processes, focusing exclusively on those employing dense CO2 as a solute, co-solute or co-solvent during the process, such as PGSS (Particles from gas-saturated solutions®, CPF (Concentrated Powder Form®, CPCSP (Continuous Powder Coating Spraying Process, CAN-BD (Carbon dioxide Assisted Nebulization with a Bubble Dryer®, SEA (Supercritical Enhanced Atomization, SAA (Supercritical Fluid-Assisted Atomization, PGSS-Drying and DELOS (Depressurization of an Expanded Liquid Organic Solution. Special emphasis is given to modifications introduced in the different techniques, as well as the limitations that have been overcome.

BIOFILM FORMATION OF Vibrio cholerae ON STAINLESS STEEL USED IN FOOD PROCESSING

Directory of Open Access Journals (Sweden)

Milagro FERNÁNDEZ-DELGADO

2016-01-01

Full Text Available Vibrio cholerae represents a significant threat to human health in developing countries. This pathogen forms biofilms which favors its attachment to surfaces and its survival and transmission by water or food. This work evaluated the in vitro biofilm formation of V. cholerae isolated from clinical and environmental sources on stainless steel of the type used in food processing by using the environmental scanning electron microscopy (ESEM. Results showed no cell adhesion at 4 h and scarce surface colonization at 24 h. Biofilms from the environmental strain were observed at 48 h with high cellular aggregations embedded in Vibrio exopolysaccharide (VPS, while less confluence and VPS production with microcolonies of elongated cells were observed in biofilms produced by the clinical strain. At 96 h the biofilms of the environmental strain were released from the surface leaving coccoid cells and residual structures, whereas biofilms of the clinical strain formed highly organized structures such as channels, mushroom-like and pillars. This is the first study that has shown the in vitro ability of V. cholerae to colonize and form biofilms on stainless steel used in food processing.

BIOFILM FORMATION OF Vibrio cholerae ON STAINLESS STEEL USED IN FOOD PROCESSING.

Science.gov (United States)

Fernández-Delgado, Milagro; Rojas, Héctor; Duque, Zoilabet; Suárez, Paula; Contreras, Monica; García-Amado, M Alexandra; Alciaturi, Carlos

2016-01-01

Vibrio cholerae represents a significant threat to human health in developing countries. This pathogen forms biofilms which favors its attachment to surfaces and its survival and transmission by water or food. This work evaluated the in vitro biofilm formation of V. cholerae isolated from clinical and environmental sources on stainless steel of the type used in food processing by using the environmental scanning electron microscopy (ESEM). Results showed no cell adhesion at 4 h and scarce surface colonization at 24 h. Biofilms from the environmental strain were observed at 48 h with high cellular aggregations embedded in Vibrio exopolysaccharide (VPS), while less confluence and VPS production with microcolonies of elongated cells were observed in biofilms produced by the clinical strain. At 96 h the biofilms of the environmental strain were released from the surface leaving coccoid cells and residual structures, whereas biofilms of the clinical strain formed highly organized structures such as channels, mushroom-like and pillars. This is the first study that has shown the in vitro ability of V. cholerae to colonize and form biofilms on stainless steel used in food processing.

Formation of soap bubbles by gas jet

Science.gov (United States)

Zhou, Maolei; Li, Min; Chen, Zhiyuan; Han, Jifeng; Liu, Dong

2017-12-01

Soap bubbles can be easily generated by various methods, while their formation process is complicated and still worth studying. A model about the bubble formation process was proposed in the study by Salkin et al. [Phys. Rev. Lett. 116, 077801 (2016)] recently, and it was reported that the bubbles were formed when the gas blowing velocity was above one threshold. However, after a detailed study of these experiments, we found that the bubbles could be generated in two velocity ranges which corresponded to the laminar and turbulent gas jet, respectively, and the predicted threshold was only effective for turbulent gas flow. The study revealed that the bubble formation was greatly influenced by the aerodynamics of the gas jet blowing to the film, and these results will help to further understand the formation mechanism of the soap bubble as well as the interaction between the gas jet and the thin liquid film.

Salta’s elite during the state´s formation process, 1850-1880. Regional trade and land distribution

Directory of Open Access Journals (Sweden)

Juan Ignacio Quintián

2012-11-01

Full Text Available The following paper analyzes cadastres and provincial census taken between 1856 and 1875 to identify the salteño landowning elite. The study begins with the synthesis of the intraregional trade involving the landowning elite of Salta; the study describes the new tax structure created in 1855 to characterize wealthy families of the province. The analysis combines the detailed description of the sources used with the narrative of some facts that contribute to understand the complex relationship between the landowning elite and the state-formation process

THE LINK BETWEEN RARE-EARTH PEAK FORMATION AND THE ASTROPHYSICAL SITE OF THE R PROCESS

Energy Technology Data Exchange (ETDEWEB)

Mumpower, Matthew R. [Theory Division, Los Alamos National Laboratory, Los Alamos, NM 87544 (United States); McLaughlin, Gail C. [Department of Physics, North Carolina State University, Raleigh, NC 27695 (United States); Surman, Rebecca [Department of Physics, University of Notre Dame, Notre Dame, IN 46556 (United States); Steiner, Andrew W., E-mail: matthew@mumpower.net [Department of Physics and Astronomy, University of Tennessee, Knoxville, TN 37996 (United States)

2016-12-20

The primary astrophysical source of the rare-earth elements is the rapid neutron capture process ( r process). The rare-earth peak that is seen in the solar r -process residuals has been proposed to originate as a pile-up of nuclei during the end of the r process. We introduce a new method utilizing Monte Carlo studies of nuclear masses in the rare-earth region, that includes self-consistently adjusting β -decay rates and neutron capture rates, to find the mass surfaces necessary for the formation of the rare-earth peak. We demonstrate our method with two types of astrophysical scenario, one corresponding to conditions typical of hot winds from core-collapse supernovae and stellar-mass accretion disks, and one corresponding to conditions typical of the ejection of the material from the tidal tails of neutron star mergers. In each type of astrophysical condition, this method successfully locates a region of enhanced stability in the mass surface that is responsible for the rare-earth peak. For each scenario, we find that the change in the mass surface has qualitatively different features, thus future measurements can shed light on the type of environment in which the r process occurred.

THE LINK BETWEEN RARE-EARTH PEAK FORMATION AND THE ASTROPHYSICAL SITE OF THE R PROCESS

International Nuclear Information System (INIS)

Mumpower, Matthew R.; McLaughlin, Gail C.; Surman, Rebecca; Steiner, Andrew W.

2016-01-01

The primary astrophysical source of the rare-earth elements is the rapid neutron capture process ( r process). The rare-earth peak that is seen in the solar r -process residuals has been proposed to originate as a pile-up of nuclei during the end of the r process. We introduce a new method utilizing Monte Carlo studies of nuclear masses in the rare-earth region, that includes self-consistently adjusting β -decay rates and neutron capture rates, to find the mass surfaces necessary for the formation of the rare-earth peak. We demonstrate our method with two types of astrophysical scenario, one corresponding to conditions typical of hot winds from core-collapse supernovae and stellar-mass accretion disks, and one corresponding to conditions typical of the ejection of the material from the tidal tails of neutron star mergers. In each type of astrophysical condition, this method successfully locates a region of enhanced stability in the mass surface that is responsible for the rare-earth peak. For each scenario, we find that the change in the mass surface has qualitatively different features, thus future measurements can shed light on the type of environment in which the r process occurred.

Formation and relaxation processes of photoinduced defects in a Ge-doped SiO2 glass

International Nuclear Information System (INIS)

Yamaguchi, M.; Saito, K.; Ikushima, A.J.

2002-01-01

The defect centers induced by ArF laser irradiation in Ge-doped SiO 2 have been investigated by the electron-spin resonance method. In order to observe formation and relaxation processes of the defects, step annealing has been carried out after the irradiation at 77 K. The thermally induced decay of the self-trapped hole (STH) and formation of the so-called Ge(2) centers have been observed with increasing temperature. The result suggests that the holes are transferred from the STH to the Ge(2)

THEORETICAL ANALYSIS STUDY OF FORMATION OF FUTURE LEGAL LAWYERS

Directory of Open Access Journals (Sweden)

Eugene Stepanovich Shevlakov

2015-09-01

Full Text Available The article deals with topical issues of formation of legal consciousness of future lawyers in high school. Obtained kinds of legal consciousness of future lawyers, determined its structure. Dedicated components of justice are mutually reinforcing, and provide an opportunity for further development of the personality of the future specialist, their personal growth.The purpose: to carry out theoretical analysis of the problem of formation of legal consciousness of future lawyers.The novelty is based. On the analysis of theoretical appro-aches of pedagogy, psychology, law, the notion of «lawfulness of the future of the law student», which is regarded as a form of social consciousness, which is a set of legal views and feelings, expressing the attitude to the law and legal phenomena that have regulatory in character and which includes know-ledge of legal phenomena and their evaluation from the point of view of fairness and justice, formed in the process of studying in the University.Results: this article analyzes different approaches to understanding the content and essence of the concept of legal consciousness of the legal profession. Define the types and structure of legal consciousness of future lawyers.

Essential processes for cognitive behavioral clinical supervision: Agenda setting, problem-solving, and formative feedback.

Science.gov (United States)

Cummings, Jorden A; Ballantyne, Elena C; Scallion, Laura M

2015-06-01

Clinical supervision should be a proactive and considered endeavor, not a reactive one. To that end, supervisors should choose supervision processes that are driven by theory, best available research, and clinical experience. These processes should be aimed at helping trainees develop as clinicians. We highlight 3 supervision processes we believe should be used at each supervision meeting: agenda setting, encouraging trainee problem-solving, and formative feedback. Although these are primarily cognitive-behavioral skills, they can be helpful in combination with other supervision models. We provide example dialogue from supervision exchanges, and discuss theoretical and research support for these processes. Using these processes not only encourages trainee development but also models for them how to use the same processes and approaches with clients. (c) 2015 APA, all rights reserved).

International Processes of Education Policy Formation: An Analytic Framework and the Case of Plan 2021 in El Salvador

Science.gov (United States)

Edwards, D. Brent, Jr.

2013-01-01

This article uses multiple perspectives to frame international processes of education policy formation and then applies the framework to El Salvador's Plan 2021 between 2003 and 2005. These perspectives are policy attraction, policy negotiation, policy imposition, and policy hybridization. Research reveals that the formation of Plan 2021 was the…

The study of interrelationship between raw water quality parameters, chlorine demand and the formation of disinfection by-products

Science.gov (United States)

Abdullah, Md. Pauzi; Yee, Lim Fang; Ata, Sadia; Abdullah, Abass; Ishak, Basar; Abidin, Khairul Nidzham Zainal

Disinfection is the most crucial process in the treatment of drinking water supply and is the final barrier against bacteriological impurities in drinking water. Chlorine is the primary disinfectant used in the drinking water treatment process throughout Malaysia. However, the occurrence of various disinfection by-products such as trihalomethanes (THM) and haloacetic acids created a major issue on the potential health hazards which may pose adverse health effects in both human and animals. To simulate real water treatment conditions and to represent the conditions inherent in a tropical country, this study was performed at an urbanized water treatment plant with a daily production of about 549,000 m 3 of treated water. The purpose of this work is to examine the relationship between the water quality parameters in the raw water with chlorine demand and the formation of disinfection by-products. This study also investigated the possibility of the statistical model applications for the prediction of chlorine demand and the THM formation. Two models were developed to estimate the chlorine demand and the THM formation. For the statistical evaluation, correlation and simple linear regression analysis were conducted using SPSS. The results of Kolmogorov-Smirnov test for the estimation of goodness-of-fit of the dependent variables of the models to the normal distribution showed that all the dependent variables followed the normal distribution at significance level of 0.05. Good linear correlations were observed between the independent parameters and formation of THM and the chlorine demand. This study also revealed that ammonia and the specific ultraviolet absorbent (SUVA) were the function of chlorine consumption in the treatment process. Chlorine dosage and SUVA increase the yield of THM. Chlorine demand and THM formation was moderately sensitive, but significant to the pH. The level of significance ( α) for the statistical tests and the inclusion of a variable in the

Two-craft Coulomb formation study about circular orbits and libration points

Science.gov (United States)

Inampudi, Ravi Kishore

This dissertation investigates the dynamics and control of a two-craft Coulomb formation in circular orbits and at libration points; it addresses relative equilibria, stability and optimal reconfigurations of such formations. The relative equilibria of a two-craft tether formation connected by line-of-sight elastic forces moving in circular orbits and at libration points are investigated. In circular Earth orbits and Earth-Moon libration points, the radial, along-track, and orbit normal great circle equilibria conditions are found. An example of modeling the tether force using Coulomb force is discussed. Furthermore, the non-great-circle equilibria conditions for a two-spacecraft tether structure in circular Earth orbit and at collinear libration points are developed. Then the linearized dynamics and stability analysis of a 2-craft Coulomb formation at Earth-Moon libration points are studied. For orbit-radial equilibrium, Coulomb forces control the relative distance between the two satellites. The gravity gradient torques on the formation due to the two planets help stabilize the formation. Similar analysis is performed for along-track and orbit-normal relative equilibrium configurations. Where necessary, the craft use a hybrid thrusting-electrostatic actuation system. The two-craft dynamics at the libration points provide a general framework with circular Earth orbit dynamics forming a special case. In the presence of differential solar drag perturbations, a Lyapunov feedback controller is designed to stabilize a radial equilibrium, two-craft Coulomb formation at collinear libration points. The second part of the thesis investigates optimal reconfigurations of two-craft Coulomb formations in circular Earth orbits by applying nonlinear optimal control techniques. The objective of these reconfigurations is to maneuver the two-craft formation between two charged equilibria configurations. The reconfiguration of spacecraft is posed as an optimization problem using the

Postgraduate education and research in Brazil: regulation and reconfiguration processes of academic work formation and production

Directory of Open Access Journals (Sweden)

João Ferreira de Oliveira

2015-07-01

Full Text Available This text analyses some of the processes of formation and production regulation and reconfiguration of the scholarly work in Brazil. Initially we examine the context and meaning of knowledge production in times of flexible accumulation, as well as the current landscape of Postgraduate education in the country. We seek to understand how public policies in the area, particularly the actions of evaluation and promotion, and the new modus operandi of the Postgraduate study and research organization have been reconfiguring the work production of teaching and students within the programs, especially in education. Above all, we seek to highlight the role of promotion and evaluation agencies, increasingly committed to a vision of expansion that drives the production of knowledge associated with demands of economic-productivity, rather than a consistent formative project that would result in a significant advancement in the production and dissemination of knowledge in the different areas.

Study on the Formation and Initial Transport for Non-Homogeneous Debris Flow

Directory of Open Access Journals (Sweden)

An Ping Shu

2017-04-01

Full Text Available Non-homogeneous debris flows generally occur during the rainy seasons in Southwest China, and have received considerable attention in the literature. Regarding the complexity in debris flow dynamics, experimental approaches have proven to be effective in revealing the formative mechanism for debris flow, and quantifying the relations between the various influencing factors with debris-flow formation and subsequent transport processes. Therefore, a flume-based and experimental study was performed at the Debris Flow Observation and Research Station of Jiangjia Gully in Yunnan Province, to theoretically analyze favorable conditions for debris-flow formation and initial transport by selecting the median particle size d50, flow rate Q, vertical grading coefficient ψ, slopes S, and the initial soil water contents W as the five variables for investigation. To achieve this, an optimal combination of these variables was made through an orthogonal experimental design to determine their relative importance upon the occurrence and initial mobilization behavior of a debris flow and to further enhance our insight into debris-flow triggering and transport mechanisms.

Experimental investigation on the weld pool formation process in plasma keyhole arc welding

Science.gov (United States)

Van Anh, Nguyen; Tashiro, Shinichi; Van Hanh, Bui; Tanaka, Manabu

2018-01-01

This paper seeks to clarify the weld pool formation process in plasma keyhole arc welding (PKAW). We adopted, for the first time, the measurement of the 3D convection inside the weld pool in PKAW by stereo synchronous imaging of tungsten tracer particles using two sets of x-ray transmission systems. The 2D convection on the weld pool surface was also measured using zirconia tracer particles. Through these measurements, the convection in a wide range of weld pools from the vicinity of the keyhole to the rear region was successfully visualized. In order to discuss the heat transport process in a weld pool, the 2D temperature distribution on the weld pool surface was also measured by two-color pyrometry. The results of the comprehensive experimental measurement indicate that the shear force due to plasma flow is found to be the dominant driving force in the weld pool formation process in PKAW. Thus, heat transport in a weld pool is considered to be governed by two large convective patterns near the keyhole: (1) eddy pairs on the surface (perpendicular to the torch axis), and (2) eddy pairs on the bulk of the weld pool (on the plane of the torch). They are formed with an equal velocity of approximately 0.35 m s-1 and are mainly driven by shear force. Furthermore, the flow velocity of the weld pool convection becomes considerably higher than that of other welding processes, such as TIG welding and GMA welding, due to larger plasma flow velocity.

Study of organic chlorine in soils and formation in biotic and abiotic conditions

International Nuclear Information System (INIS)

Osswald, Aurelie

2016-01-01

Chlorine has long been considered as the predominantly chlorine form present in the environment. However, recent studies have shown that chlorine is retained in the soil as an organic form and is formed by a natural process of chlorination mainly from the microbial activity of the soil still poorly documented. The aim of this study is to estimate the organic and inorganic forms of chlorine in contrasting soil and highlight the evolution of these forms according to certain environmental parameters or terms of incubations and to the activity of microorganisms. For this, the organo-mineral horizons of contrasting soil were studied (i) in situ: The amounts of chlorine and physico-chemical and microbiological parameters of soil were measured; (ii) in two experimental devices incubations under different conditions. Measurements of chlorine levels between the beginning and the end of the first experiment were measured by AOX analyzer. For the second experiment, the soil was previously enriched with Na 37 Cl and 37 Cl levels were measured by HR ICP MS. Soil samples from these incubations were analyzed by Xanes spectrometry to identify the speciation of chlorine forms in soils. Soil non-extractable organic chlorine contents represent almost all of the chlorine. The parameters that influence the distribution of chlorine contents in soils correspond to vegetation cover, pH, organic carbon content and quantities of microorganisms. The chlorine contents measured by AOX analyzer and by HR ICP MS highlight an organic chlorine formation over time in relation to the microorganisms in the soil. The measures carried out by HR ICP MS show also an organic chlorine formation in abiotic conditions. Conversely, XANES spectrometry measurements have shown any organic chlorine formation. In conclusion, the parameters that influence the distribution of chlorine contents in soils have been targeted. Similarly, the microbial origin of the chlorination process has been demonstrated, although a

N-nitrosamines in processed meat products – analysis, occurrence, formation, mitigation and exposure

DEFF Research Database (Denmark)

Herrmann, Susan Strange

and NVNA in meat. Secondly data on the occurrence of VNA and NVNA in processed meat products on the Danish market were to be generated and used for an evaluation of the exposure level resulting from consumption of processed meat products. A method allowing for the simultaneous determination of both VNA......, NPIP, NTCA and NMTCA were inversely related to the amount of erythorbic acid (396-1104 mg kg-1). The levels of the individual NA were reduced with up to 20 to 75%. No additional protection against NA formation was obtained by also adding ascorbyl palmitate, a fat soluble antioxidant. Sodium chloride...

TRANSFORMATION THE ROLE OF THINK TANKS IN THE PROCESS OF GOVERNMENT POLICY FORMATION IN THE CONTEXT OF WORLD FINANCIAL CRISIS IN 2008-2010

Directory of Open Access Journals (Sweden)

Антон Юрьевич Барсуков

2013-05-01

Full Text Available The study is dedicated to the evolution of think tanks role as a political tool of government policy formation in the context of world financial crisis. The main purpose of the study was the description of such evolution, revealing of the basic differences with the analytical centers, founded before 2008 in China, and finding-out of think tank’ role in the process of anticrisis campaign.The actuality of the study is obvious, proceeding from there are not any other study dedicated to the Chinese “new type” think tanks in Russian politologycal science.The appearance of “new type” think tanks in the PRC is mentioned in the study. The special meaning devoted to the increasing of returnees’ role in the process of government policy formation. The author makes the conclusion that “new type” think tanks have a very important meaning just as in the process of anticrisis campaign so in the public life. “New type” think tanks have more independence from the official authorities. DOI: http://dx.doi.org/10.12731/2218-7405-2013-4-38

THE ROLE OF CRYOGENIC PROCESSES IN THE FORMATION OF LOESS DEPOSITS

Directory of Open Access Journals (Sweden)

Vyacheslav N. Konishchev

2015-01-01

Full Text Available The paper describes a new approach to the analysis of the genetic nature of mineral substances in loess deposits. In permafrost under the influence of multiple alternate freezing and thawing in dispersed deposits, quartz particles accumulate the 0.05-0.01 mm fraction, while feldspars are crushed to a coarse fraction of 0.1-0.05 mm. In dispersed sediments formed in temperate and warm climatic zones, the granulometric spectrum of quartz and feldspar has the opposite pattern. The proposed methodology is based on a differential analysis of the distribution of these minerals by the granulometric spectrum. We have proposed two criteria - the coefficient of cryogenic contrast (CCC and the coefficient of distribution of heavy minerals, which allow determination of the degree of participation of cryogenic processes in the formation of loess sediments and processes of aeolian or water sedimentation.

The influence of Chromium supplied by tanning and wet finishing processes on the formation of cr(vi in leather

Directory of Open Access Journals (Sweden)

W. F. Fuck

2011-06-01

Full Text Available Chromium used in leather manufacturing can be oxidized from the trivalent to the hexavalent state, causing environmental concerns. In this study, the influence of Cr(III from tanning, deacidification pH, fatliquors, chrome retanning and vegetable retanning on the formation of Cr(VI in leather was analyzed by comparing natural and aged samples. In wet-blue leather, even after aging and in fatliquored leathers that did not suffer the aging process, the presence of Cr(VI was always below the detection limit of 3 mg/kg. Considering the presence of Cr(VI, the supply of chromium during the retanning step had a more significant effect than during the tanning. In the fatliquoring process with sulfites, fish and synthetic fatliquor leather samples contained Cr(VI when aged, and the highest concentration detected was 26.7 mg/kg. The evaluation of Cr(VI formation led to recommendations for regulation in the leather industry.

BIOFILM FORMATION OF Vibrio cholerae ON STAINLESS STEEL USED IN FOOD PROCESSING

OpenAIRE

FERNÁNDEZ-DELGADO, Milagro; ROJAS, Héctor; DUQUE, Zoilabet; SUÁREZ, Paula; CONTRERAS, Monica; GARCÍA-AMADO, M. Alexandra; ALCIATURI, Carlos

2016-01-01

Vibrio cholerae represents a significant threat to human health in developing countries. This pathogen forms biofilms which favors its attachment to surfaces and its survival and transmission by water or food. This work evaluated the in vitro biofilm formation of V. cholerae isolated from clinical and environmental sources on stainless steel of the type used in food processing by using the environmental scanning electron microscopy (ESEM). Results showed no cell adhesion at 4 h and scarce sur...

Formation of Globular Clusters with Internal Abundance Spreads in r -Process Elements: Strong Evidence for Prolonged Star Formation

Energy Technology Data Exchange (ETDEWEB)

Bekki, Kenji [ICRAR, M468, University of Western Australia, 35 Stirling Highway, Crawley, Western Australia, 6009 (Australia); Tsujimoto, Takuji [National Astronomical Observatory of Japan, Mitaka-shi, Tokyo 181-8588 (Japan)

2017-07-20

Several globular clusters (GCs) in the Galaxy are observed to show internal abundance spreads in r -process elements (e.g., Eu). We propose a new scenario that explains the origin of these GCs (e.g., M5 and M15). In this scenario, stars with no/little abundance variations first form from a massive molecular cloud (MC). After all of the remaining gas of the MC is expelled by numerous supernovae, gas ejected from asymptotic giant branch stars can be accumulated in the central region of the GC to form a high-density intracluster medium (ICM). Merging of neutron stars then occurs to eject r -process elements, which can be efficiently trapped in and subsequently mixed with the ICM. New stars formed from the ICM can have r -process abundances that are quite different from those of earlier generations of stars within the GC. This scenario can explain both (i) why r -process elements can be trapped within GCs and (ii) why GCs with internal abundance spreads in r -process elements do not show [Fe/H] spreads. Our model shows (i) that a large fraction of Eu-rich stars can be seen in Na-enhanced stellar populations of GCs, as observed in M15, and (ii) why most of the Galactic GCs do not exhibit such internal abundance spreads. Our model demonstrates that the observed internal spreads of r -process elements in GCs provide strong evidence for prolonged star formation (∼10{sup 8} yr).

Rates of star formation

International Nuclear Information System (INIS)

Larson, R.B.

1977-01-01

It is illustrated that a theoretical understanding of the formation and evolution of galaxies depends on an understanding of star formation, and especially of the factors influencing the rate of star formation. Some of the theoretical problems of star formation in galaxies, some approaches that have been considered in models of galaxy evolution, and some possible observational tests that may help to clarify which processes or models are most relevant are reviewed. The material is presented under the following headings: power-law models for star formation, star formation processes (conditions required, ways of achieving these conditions), observational indications and tests, and measures of star formation rates in galaxies. 49 references

Picture versus words: A comparison of pictorial and verbal informed assent formats

Directory of Open Access Journals (Sweden)

Siddharth Dutt

2018-01-01

Full Text Available Background for the Study: Informed consent is a process of obtaining permission from the participant to participate in research. Involving children in a research requires them to give their “assent” for participation. Informed assent is obtained from children even after their guardians have given consent for participation. Studies have shown that children have difficulty understanding the key elements of research process such as right to withdraw from the study or the meaning of “harm” involved in the research process. Further, the studies have also propounded that using child-friendly methods such as using pictures and simple language would facilitate children's understanding. Objectives: In this study, pictorial and verbal assent formats were compared find out which format is suitable for children's understanding of informed assent with respect to research. Methods: A sample of 389 school going children and adolescents of both the gender, ranging from 7 to 16 years were considered for the study. The sample was randomly divided into two groups, where for one group (n = 197, pictorial assent format was administered and another group (n = 192, verbal assent format was administered. The pictorial assent format was developed for the study by the corresponding author. Results and Conclusions: Analysis revealed that there was a significant level of interaction between gender and the two assent formats. Males were able to understand pictorial assent format better compared to the females, whereas females were able to understand verbal assent format better than the males, when age and education were considered as covariates. Further, it was found that as age increases there is better understanding of research processes in both the formats. Hence, while the process of obtaining assent for participation in research, age of child must be considered and with respect to gender differences males tend to prefer pictorial formats whereas females tend to

Pump-probe study of the formation of rubidium molecules by ultrafast photoassociation of ultracold atoms

Science.gov (United States)

McCabe, David J.; England, Duncan G.; Martay, Hugo E. L.; Friedman, Melissa E.; Petrovic, Jovana; Dimova, Emiliya; Chatel, Béatrice; Walmsley, Ian A.

2009-09-01

An experimental pump-probe study of the photoassociative creation of translationally ultracold rubidium molecules is presented together with numerical simulations of the process. The formation of loosely bound excited-state dimers is observed as a first step toward a fully coherent pump-dump approach to the stabilization of Rb2 into its lowest ground vibrational states. The population that contributes to the pump-probe process is characterized and found to be distinct from a background population of preassociated molecules.

The role of reconsolidation and the dynamic process of long-term memory formation and storage

Directory of Open Access Journals (Sweden)

Cristina M Alberini

2011-03-01

Full Text Available It is becoming increasingly clear that the processes of memory formation and storage are exquisitely dynamic. Elucidating the nature and temporal evolution of the biological changes that accompany encoding, storage and retrieval is key to understand memory formation. For explicit or medial temporal lobe-dependent memories that form after a discrete event and are stored for a long time, the physical changes underlying the encoding and processing of the information (memory trace or engram remain in a fragile state for some time. However, over time, the new memory becomes increasingly resistant to disruption until it is consolidated. Retrieval or reactivation of an apparently consolidated memory can render the memory labile again, and reconsolidation is the process that occurs to mediate its restabilization. Reconsolidation also evolves with the age of the memory: Young memories are sensitive to postreactivation disruption, but older memories are more resistant. Why does a memory become labile again if it is retrieved or reactivated? Here I suggest that the main function of reconsolidation is to contribute to the lingering consolidation process and mediate memory strengthening. I also discuss the literature and results regarding the influence of the passage of time on the reconsolidation of memory. These points have important implications for the use of reconsolidation in therapeutic settings.

Dynamics of the accumulation process of the Earth group of planets: Formation of the reverse rotation of Venus

Science.gov (United States)

Koslov, N. N.; Eneyev, T. M.

1979-01-01

A numerical simulation of the process of formation of the terrestrial planets is carried within the framework of a new theory for the accumulation of planetary and satellite systems. The numerical simulation permitted determining the parameters of the protoplanetary disk from which Mercury, Venus and the Earth were formed as result of the evolution. The acquisition of a slow retrograde rotation for Venus was discovered during the course of the investigation, whereas Mercury and the Earth acquired direct rotation about their axes. Deviations of the semimajor axes of these three planets as well as the masses of the Earth and Venus from the true values are small as a rule (l 10%). It is shown that during the accumulation of the terrestrial planets, there existed a profound relationship between the process of formation of the orbits and masses of the planet and the process of formation of their rotation about their axes. Estimates are presented for the radii of the initial effective bodies and the time of evolution for the terrestrial accumulation zone.

Transfer process studies through a toarcian argilite

International Nuclear Information System (INIS)

Boisson, J.Y.

1996-01-01

Concerning long lived and high level radioactive wastes, the French Wastes Management Research Act (30th December 1991) has set three ways to be studied: separation and/or transmutation, conditioning processes and volumes reduction, and feasibility of geological disposal. ANDRA, in charge of this last point; has the responsibility to create and develop underground laboratories, to elaborate and propose the concept of the future disposal installations with safety demonstration, to be submitted to the French safety governmental authorities (Direction de la Surete des Installations Nucleaires). In order to asses these safety demonstrations, to build up its judgement, DSIN will ask technical advice, from Institut de Protection et de Surete Nucleaire (IPSN). To be able to meet these requirements, IPSN is developing, in the framework of its research and development safety programs, in situ research concerning the confining properties of geological formations. In order to perform experiments in representative conditions concerning mainly geotechnical and hydrogeological properties of very low permeability rocks, appropriate underground sites have been selected in the past in granite and shale formations. IPSN activities at the Tournemire site are the most important activities regarding specifically research about characterization of transfers through an argilite formation. This programme is developed in the framework of a cost sharing research contract between IPSN and EC. (author)

Impedimetric quantification of the formation process and the chemosensitivity of cancer cell colonies suspended in 3D environment.

Science.gov (United States)

Lei, Kin Fong; Wu, Zong-Ming; Huang, Chia-Hao

2015-12-15

In cancer research, colony formation assay is a gold standard for the investigation of the development of early tumors and the effects of cytotoxic agents on tumors in vitro. Quantification of cancer cell colonies suspended in hydrogel is currently achieved by manual counting under microscope. It is challenging to microscopically quantify the colony number and size without subjective bias. In this work, impedimetric quantification of cancer cell colonies suspended in hydrogel was successfully developed and provides a quantitative and objective method to describe the colony formation process and the development of colony size during the culture course. A biosensor embedded with a pair of parallel plate electrodes was fabricated for the impedimetric quantification. Cancer cell (cell line: Huh-7) were encapsulated in methyl cellulose hydrogel and cultured to gradually form cancer cell colonies suspended in 3D environment. At pre-set schedule during the culture course, small volume (50 μL) of colonies/MC hydrogel was collected, mixed with measurement hydrogel, and loaded to the biosensor for measurement. Hence, the colony formation process could be quantitatively represented by a colony index and a colony size index calculated from electrical impedance. Based on these developments, chemosensitivity of cancer cell colonies under different concentrations of anti-cancer drug, i.e., doxorubicin, was quantitatively investigated to study the efficacy of anti-cancer drug. Also, dose-response curve was constructed to calculate the IC50 value, which is an important indicator for chemosensitivity assay. These results showed the impedimetric quantification is a promising technique for the colony formation assay. Copyright © 2015 Elsevier B.V. All rights reserved.

Chlorination and chloramines formation

International Nuclear Information System (INIS)

Yee, Lim Fang; Mohd Pauzi Abdullah; Sadia Ata; Abbas Abdullah; Basar IShak; Khairul Nidzham

2008-01-01

Chlorination is the most important method of disinfection in Malaysia which aims at ensuring an acceptable and safe drinking water quality. The dosing of chlorine to surface water containing ammonia and nitrogen compounds may form chloramines in the treated water. During this reaction, inorganic and organic chloramines are formed. The recommended maximum acceptable concentration (MAC) for chloramines in drinking water is 3000 μg/L. The production of monochloramine, dichloramine and trichloramine is highly dependent upon pH, contact time and the chlorine to ammonia molar ratio. The purpose of this study is to examine the formation of chloramines that occur upon the chlorination during the treatment process. Chloramines were determined using the N,N-diethyl-p-phenylenediamine (DPD) colorimetric method. The influences of ammonia, pH and chlorine dosage on the chloramines formation were also studied. This paper presents a modeling approach based on regression analysis which is designed to estimate the formation of chloramines. The correlation between the concentration of chloramines and the ammonia, pH and chlorine dosage was examined. In all cases, the quantity of chloramines formed depended linearly upon the amount of chlorine dosage. On the basis of this study it reveals that the concentration of chloramines is a function of chlorine dosage and the ammonia concentration to the chlorination process. PH seems to not significantly affect the formation of chloramines. (author)

Studies of Heterogeneous and Diffusion-Influenced Nucleation for Improved Processing of Nanostructural Materials

National Research Council Canada - National Science Library

Kellon, Kenneth F; Buhro, William E

2005-01-01

.... The purpose of this grant was to identify a suitable glass for studies of the nucleation processes leading to nanostructure formation and to investigate the possibility of using TiB2 for enhanced...

Aggregate formation in 3D turbulent-like flows

NARCIS (Netherlands)

Dominguez, A.; Clercx, H.J.H.

2006-01-01

Aggregate formation is an important process in industrial and environmental turbulent flows. In oceans turbulence play an important role on Marine Snow (aggregate) formation. For a proper description, the study of aggregate formation in turbulent flows requires a particle based model i.e. following

Using Clumped Isotopes to Understand Early Diagenetic Processes in Carbonate Microbialites of Mid-Cretaceous Codó Formation, NE Brazil

Science.gov (United States)

Bahniuk, A. M.; Vasconcelos, C.; McKenzie, J. A.; Franca, A. B.; Matsuda, N.; Eiler, J.

2010-12-01

Recent studies of the sedimentological, stratigraphic and geochemical aspects of carbonate microbialites have been carried out to characterize the paleoenvironmental and hydrological conditions of deposition for the Aptian Codó Formation (Parnaíba Basin) and the time-equivalent Santana Formation (Araripe Basin). This environmental interpretation is of interest because these sediments record the early stages of the opening of the Equatorial Atlantic Ocean, as well as being potentially important reservoir rock. Specifically, clumped isotope thermometry has been applied to evaluate the growth temperatures of carbonate components in selected samples from both outcrop and drill core. Preliminary results of clumped isotope measurements provide paleotemperatures derived for dense stromatolitic fabrics drilled from outcrop samples of the Codó Formation which vary between 29 and 33°C. In contrast, the micritic matrix of the drill core samples of the Codó Formation indicates a temperature range from 30 to 48°C. The lower values for the outcrop samples may represent a primary or early diagenetic temperature signal preserved in the rock. Moreover, the micritic matrix from the Santana Formation drill core samples indicates paleotemperatures ranging from 40 to 68°C, which are slightly higher than those for all measured samples of the Codó Formation. We propose that the higher paleotemperatures for all drill core samples denote a diagenetic effect that occurred with sediment lithification processes during burial; that is, isotopic reequilibration at depth is reflected in the higher measured paleotemperatures. Increased paleotemperatures are probably present in some carbonate fabrics of the outcrop samples of the Codo Formation, which also underwent lithification, but this signal was missed by our inability to micro-sample primary or early diagenetic stromatolitic fabrics. Assuming that the outcrop samples of the Codó Formation preserve an original stable isotope signal

Development direction of the soil-formation processes for reclaimed soda solonetz-solonchak soils of the Ararat valley during their cultivation

Directory of Open Access Journals (Sweden)

R.R. Manukyan

2018-03-01

Full Text Available The data of the article show that the long-term cultivation of reclaimed sodium solonetz-solonchak soils entails to further improvement of their properties and in many parameters of chemical compositions of soil solution and soil-absorbing complex they come closer to irrigated meadow-brown soils in the period of 15–20 years of agricultural development. The analysis of the experimental research by the method of non-linear regression shows, that for the enhancement of some yield determining parameters to the level of irrigated meadow-brown soils, a time period of 30–40 years of soil-formation processes is needed and longer time is necessary for humidification. The forecast of soil-formation processes for the long-term period, allows to reveal the intensity and orientation of development of the specified processes and to develop the scientifically-justified actions for their further improvement. Keywords: Soil-formation processes, Reclaimed soda solonetz-solonchaks, Irrigated meadow-brown soils, Multi-year cultivation, Improvement, Forecasting

POX 186: A Dwarf Galaxy in the Process of Formation?

Science.gov (United States)

Corbin, Michael R.; Vacca, William D.

2002-12-01

We present deep U-, V-, and I-band images of the ``ultracompact'' blue dwarf galaxy POX 186 obtained with the Planetary Camera 2 of the Hubble Space Telescope. We have also obtained a near-ultraviolet spectrum of the object with the Space Telescope Imaging Spectrograph and combine this with a new ground-based optical spectrum. The images confirm the galaxy to be extremely small, with a maximum extent of only 300 pc, a luminosity of ~10-4L*, and an estimated mass of ~107 Msolar. Its morphology is highly asymmetric, with a tail of material on its western side that may be tidal in origin. The U-band image shows this tail to be part of a stream of material in which stars have recently formed. Most of the star formation in the galaxy is, however, concentrated in a central, compact (d~10-15 pc) star cluster. We estimate this cluster to have a total mass of ~105 Msolar, to be forming stars at a rate of less than 0.05 yr-1, and to have a maximum age of a few million years. The outer regions of the galaxy are significantly redder than the cluster, with V-I colors consistent with a population dominated by K and M stars. From our analysis of the optical spectrum we find the galaxy to have a metallicity Z~=0.06 Zsolar and to contain a significant amount of internal dust [E(B-V)~=0.28] both values agree with previous estimates. While these results rule out earlier speculation that POX 186 is a protogalaxy, its morphology, mass, and active star formation suggest that it represents a recent (within ~108 yr) collision between two clumps of stars of subgalactic size (~100 pc). POX 186 may thus be a very small dwarf galaxy that, dynamically speaking, is still in the process of formation. This interpretation is supported by the fact that it resides in a void, so its morphology cannot be explained as the result of an encounter with a more massive galaxy. Clumps of stars this small may represent the building blocks required by hierarchical models of galaxy formation, and these results

Physical phenomena stipulating nucleus formation, growth and structure films

Energy Technology Data Exchange (ETDEWEB)

Aleksandrov, L N [AN SSSR, Novosibirsk. Inst. Fiziki Poluprovodnikov

1975-03-01

This review is concerned with the physical phenomena responsible for the nucleation, growth and structure of films. Emphasis is placed on the study of films of solid-metal systems, semiconductors (In, As, Cd, Se, CdS), and dielectrics. The following problems are discussed in the paper: general regularities of the thermodynamics and kinetics of film formation, methods of obtaining a solid film, the process of film formation, the rate of growth of individual grains. The critical film thickness and its measurement are also considered. The results of investigating the process of formation of mono- and polycrystalline films are discussed. It is concluded, on the basis of studies into the relaxation processes accompanying the growth of films, that an insight into these processes will permits improving film properties.

DBP formation from degradation of DEET and ibuprofen by UV/chlorine process and subsequent post-chlorination.

Science.gov (United States)

Aghdam, Ehsan; Xiang, Yingying; Sun, Jianliang; Shang, Chii; Yang, Xin; Fang, Jingyun

2017-08-01

The formation of disinfection by-products (DBPs) from the degradation of N,N-diethyl-3-methyl benzoyl amide (DEET) and ibuprofen (IBP) by the ultraviolet irradiation (UV)/chlorine process and subsequent post-chlorination was investigated and compared with the UV/H 2 O 2 process. The pseudo first-order rate constants of the degradation of DEET and IBP by the UV/chlorine process were 2 and 3.1 times higher than those by the UV/H 2 O 2 process, respectively, under the tested conditions. This was due to the significant contributions of both reactive chlorine species (RCS) and hydroxyl radicals (HO) in the UV/chlorine process. Trichloromethane, 1,1,1-trichloro-2-propanone and dichloroacetic acid were the major known DBPs formed after 90% of both DEET and IBP that were degraded by the UV/chlorine process. Their yields increased by over 50% after subsequent 1-day post-chlorination. The detected DBPs after the degradation of DEET and IBP comprised 13.5% and 19.8% of total organic chlorine (TOCl), respectively, and the proportions increased to 19.8% and 33.9% after subsequent chlorination, respectively. In comparison to the UV/H 2 O 2 process accompanied with post-chlorination, the formation of DBPs and TOCl in the UV/chlorine process together with post-chlorination was 5%-63% higher, likely due to the generation of more DBP precursors from the attack of RCS, in addition to HO. Copyright © 2017. Published by Elsevier B.V.

Anodic processes in the chemical and electrochemical etching of Si crystals in acid-fluoride solutions: Pore formation mechanism

Energy Technology Data Exchange (ETDEWEB)

Ulin, V. P.; Ulin, N. V.; Soldatenkov, F. Yu., E-mail: f.soldatenkov@mail.ioffe.ru [Ioffe Physical–Technical Institute (Russian Federation)

2017-04-15

The interaction of heavily doped p- and n-type Si crystals with hydrofluoric acid in the dark with and without contact with metals having greatly differing work functions (Ag and Pd) is studied. The dependences of the dissolution rates of Si crystals in HF solutions that contain oxidizing agents with different redox potentials (FeCl{sub 3}, V{sub 2}O{sub 5} and CrO{sub 3}) on the type and level of silicon doping are determined. Analysis of the experimental data suggests that valence-band holes in silicon are not directly involved in the anodic reactions of silicon oxidation and dissolution and their generation in crystals does not limit the rate of these processes. It is also shown that the character and rate of the chemical process leading to silicon dissolution in HF-containing electrolytes are determined by the interfacial potential attained at the semiconductor–electrolyte interface. The mechanism of electrochemical pore formation in silicon crystals is discussed in terms of selfconsistent cooperative reactions of nucleophilic substitution between chemisorbed fluorine anions and coordination- saturated silicon atoms in the crystal subsurface layer. A specific feature of these reactions for silicon crystals is that vacant nonbonding d{sup 2}sp{sup 3} orbitals of Si atoms, associated with sixfold degenerate states corresponding to the Δ valley of the conduction band, are involved in the formation of intermediate complexes. According to the suggested model, the pore-formation process spontaneously develops in local regions of the interface under the action of the interfacial potential in the adsorption layer and occurs as a result of the detachment of (SiF{sub 2}){sub n} polymer chains from the crystal. Just this process leads to the preferential propagation of pores along the <100> crystallographic directions. The thermodynamic aspects of pore nucleation and the effect of the potential drop across the interface, conduction type, and free-carrier concentration

Effect of Processing Methods on Cholesterol Contents and Cholesterol Oxides Formation in Some Dairy Products

International Nuclear Information System (INIS)

AlRowaily, Meshref A

2008-01-01

The effects of pasteurization, boiling, microwaving, processing and storage of milk and some locally produced dairy products on cholesterol contents and cholesterol oxides formation were studied and evaluated. The 7-ketocholesterol were not detected (ND) in all raw milk samples. On the contrary, heating of milk led to formation of cholesterol oxidation products (COPs), mostly, 7- ketocholesterol in different quantities. No significant effect of heating of milk on cholesterol level was observed with the exception of the ultra-high temperature (UHT) milk prepared from milk powder heated at 140 + - 1.0 degree C for 4 sec showed the highest value of 7-ketocholesterol (80.97 mgg-1), followed by microwave heated milk for 5 min (31.29 mgg-1), whereas the lowest value was in milk pasteurized at 85 + - 1.0 degree C for 16 sec (3.125 mgg-1). Commercial storage showed no significant effect on cholesterol and 7-ketocholestrol but lowered cholesterol concentration and increased 7-ketocholestrol level of UHT reconstituted milk. Cholesterol content of both yogurt and labaneh strained by centrifugal separator showed significant decrease while 7-ketochostrol level was increased significantly with refrigerated storage. The findings are discussed in the context with the results of previous similar studies. (author)

Modern Processes of Hydrocarbon Migration and Re-Formation of Oil and Gas Fields (Based on the Results of Monitoring and Geochemical Studies)

Science.gov (United States)

Plotnikova, Irina; Salakhidinova, Gulmira; Nosova, Fidania; Pronin, Nikita; Ostroukhov, Sergey

2015-04-01

Special geochemical studies of oils allowed to allocate a movable migration component of oils in the industrial oil deposits. In the field the migration component of oils varies in different parts of the field. The largest percentage of the light migration component (gas condensate of the oil) was detected in the central part of the Kama-Kinel troughs system. Monitoring of the composition of water, oil and gas (condensate light oil component) in the sedimentary cover and ni crystalline basement led to the conclusion of modern migration of hydrocarbons in sedimentary cover. This proves the existence of the modern processes of formation and reformation of oil and gas fields. This presentation is dedicated to the problem of definition of geochemical criteria of selection of hydrocarbons deposit reformation zone in the sample wells of Minibaevskaya area of Romashkinskoye field. While carrying out this work we examined 11 samples of oil from the Upper Devonian Pashiysky horizon. Four oil samples were collected from wells reckoned among the "anomalous" zones that were marked out according to the results of geophysical, oil field and geological research. Geochemical studies of oils were conducted in the laboratory of geochemistry of the Kazan (Volga-region) Federal University. The wells where the signs of hydrocarbons influx from the deep zones of the crust were recorded are considered to be "anomalous". A number of scientists connect this fact to the hypothesis about periodic influx of deep hydrocarbons to the oil deposits of Romashkinskoye field. Other researchers believe that the source rocks of the adjacent valleys sedimentary cover generate gases when entering the main zone of gas formation, which then migrate up the section and passing through the previously formed deposits of oil, change and "lighten" their composition. Regardless of the point of view on the source of the hydrocarbons, the study of the process of deposits refilling with light hydrocarbons is an

Effect of Type of Food on the Trans Fatty Acids Formation and Characteristic of Oil during Frying Process

International Nuclear Information System (INIS)

Atta, N.M.M.; Esmail, A.E.; Shams El Din, N.M.M.

2010-01-01

This study was carried out to investigate the physical and chemical changes which take place in blended oil (sunflower oil: soy bean oil 75: 25 w/w), therefore frying different types of food, such as fresh foods (potatoes, falafel, fish, meat and chicken) and semi-fried Foods (chicken bites koki (nuggets), shish pan koki and farm frites potato) during frying process for 20, 40 and 60 minutes at (180±5 degree C), also studying the effect of different types of food on the oil uptake and formation of trans fatty acids in oils during frying process. The obtained results as follows: the color (red unit), viscosity, acidity and peroxide value of investigated oils were increased during frying all foods (fresh and semi-fried foods), but the increase was more pronounced in case of frying semi-fried foods, while the refractive index of frying oil of semi-fried foods was decreased compared with control oil and frying oils of fresh food. The results indicated that a considerable range of oil uptake quantities during frying as a result of variation type of foods, among all food, finger potato extensive absorption of the frying oil during frying process compared with the other fresh foods, as a results the semi-fried foods will contain a higher percent of oil included the oil of its formation, that during its frying, it was absorbed a few amount of oil. These results indicated that, the percentage of formation trans fatty acid (eliadic acid) in frying oils after 20 and 60 minutes during frying semi-fried foods was more that than frying fresh foods. Also, the results observed that, the percentage of eliadic acid in frying oil of fresh potato was lower than the other frying oils of fresh food, additionally the quality of frying oil of fresh potato finger was the best compared to frying oil of the other food material

An Action Research Study of High School English Language Arts, Intensive Reading, and Formative Assessment Principles

Science.gov (United States)

Welch, Karen P.

2017-01-01

Formative assessment has been identified as an effective pedagogical practice in the field of education, where teachers and students engage daily in an interactive process to gather evidence of the students' proficiency of a specific learning goal. The evidence collected by the teacher and a student during the formative assessment process allows…

The study of membrane formation via phase inversion method by cloud point and light scattering experiment

Science.gov (United States)

Arahman, Nasrul; Maimun, Teuku; Mukramah, Syawaliah

2017-01-01

The composition of polymer solution and the methods of membrane preparation determine the solidification process of membrane. The formation of membrane structure prepared via non-solvent induced phase separation (NIPS) method is mostly determined by phase separation process between polymer, solvent, and non-solvent. This paper discusses the phase separation process of polymer solution containing Polyethersulfone (PES), N-methylpirrolidone (NMP), and surfactant Tetronic 1307 (Tet). Cloud point experiment is conducted to determine the amount of non-solvent needed on induced phase separation. Amount of water required as a non-solvent decreases by the addition of surfactant Tet. Kinetics of phase separation for such system is studied by the light scattering measurement. With the addition of Tet., the delayed phase separation is observed and the structure growth rate decreases. Moreover, the morphology of fabricated membrane from those polymer systems is analyzed by scanning electron microscopy (SEM). The images of both systems show the formation of finger-like macrovoids through the cross-section.

How does School Experience Relate to Adolescent Identity Formation Over Time? Cross-Lagged Associations between School Engagement, School Burnout and Identity Processing Styles.

Science.gov (United States)

Erentaitė, Rasa; Vosylis, Rimantas; Gabrialavičiūtė, Ingrida; Raižienė, Saulė

2018-04-01

The existing research findings still do not provide a clear understanding of the links between adolescent school experience and their identity formation. To address this gap, we analyzed the dynamic links between adolescent school experiences and identity formation by exploring the cross-lagged associations between school engagement, school burnout and identity processing styles (information-oriented, normative and diffuse-avoidant) over a 2-year period during middle-to-late adolescence. The sample of this school-based study included 916 adolescents (51.4% females) in the 9th to 12th grades from diverse socio-economic and family backgrounds. The results from the cross-lagged analyses with three time points revealed that (a) school engagement positively predicted information-oriented identity processing over a 2-year period; (b) school burnout positively predicted the reliance on normative and diffuse-avoidant identity styles across the three measurements; (c) the effects were stable over the three time points and across different gender, grade, and socio-economic status groups. The unidirectional effects identified in our study support the general prediction that active engagement in learning at school can serve as a resource for adolescent identity formation, while school burnout, in contrast, can hinder the formation of adolescent identity. This points to the importance of taking developmental identity-related needs of adolescents into account when planning the school curriculum.

SAUDI TEACHERS’ PRACTICES OF FORMATIVE ASSESSMENT: A QUALITATIVE STUDY

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Saeed Almuntasheri

2016-12-01

Full Text Available Shifting from teacher-centred to student-centred practices requires teachers to understand strategies to interact with students in science classes. Formative assessment strategies are very critical component of classroom interaction where teachers obtain information about student learning wherever possible. Traditionally, however, teachers ask questions and evaluate student responses but without investigating student contributions to the classroom interaction. This qualitative study aimed at developing teachers’ knowledge of formative assessment strategies when teaching science-based inquiry in Saudi Arabia. 12 teachers were observed when teaching science and details of one teachers’ practices of formative assessment is presented in this study. Formative assessment framework that describes assessment conversations is used and modified to observe teachers’ assessment practices. Assessment conversation consists of four-step cycles, where the teacher elicits information from students through questioning, the student responds, the teacher recognizes the student’s response, and then uses the information to develop further inquiry. Findings indicate that teachers ask questions and receive responses but rarely allow students to share their own ideas or discuss their own thinking. The study underlines the importance of integrating formative assessment strategies during scientific inquiry teaching for professional development as a way to increase student participation and allow opportunities for students’ inquiry in science classes.

Superconductivity optimization and phase formation kinetics study of internal-Sn Nb3Sn superconducting wires

International Nuclear Information System (INIS)

Zhang, Chaowu

2007-07-01

Superconductors Nb 3 Sn wires are one of the most applicable cryogenic superconducting materials and the best choice for high-field magnets exceeding 10 T. One of the most significant utilization is the ITER project which is regarded as the hope of future energy source. The high-Cu composite designs with smaller number of sub-element and non-reactive diffusion barrier, and the RRP (Restacked Rod Process) internal-Sn technology are usually applied for the wire manufacturing. Such designed and processed wires were supplied by MSA/Alstom and WST/NIN in this research. The systematic investigation on internal-Sn superconducting wires includes the optimization of heat treatment (HT) conditions, phase formation and its relation with superconductivity, microstructure analysis, and the phase formation kinetics. Because of the anfractuosity of the configuration design and metallurgical processing, the MF wires are not sufficient for studying a sole factor effect on superconductivity. Therefore, four sets of mono-element (ME) wires with different Sn ratios and different third-element addition were designed and fabricated in order to explore the relationship between phase formation and superconducting performances, particularly the A15 layer growth kinetics. Different characterization technic have been used (magnetization measurements, neutron diffraction and SEM/TEM/EDX analysis). The A15 layer thicknesses of various ME samples were measured and carried out linear and non-linear fits by means of two model equations. The results have clearly demonstrated that the phase formation kinetics of Nb 3 Sn solid-state reaction is in accordance with an n power relation and the n value is increased with the increase of HT temperature and the Sn ratio in the wire composite. (author)

Numerical analysis of the influence of particle charging on the fume formation process in arc welding

International Nuclear Information System (INIS)

Tashiro, Shinichi; Matsui, Sho; Tanaka, Manabu; Murphy, Anthony B

2013-01-01

In order to clarify the influence of electrostatic forces caused by charging of particles on the coagulation process in fume formation in arc welding, a previously developed fume formation model is modified to consider the influence of charging, for both local thermodynamic equilibrium (LTE) and non-LTE conditions. The model takes into account formation of the particles from metal vapour by nucleation, growth of the particles by condensation of metal vapour and coagulation of the particles by collisions to form secondary particles. Results are obtained for both ballistic and Brownian motion of the particles. It is found that the growth of secondary particles is suppressed when the average particle charge becomes significant, because charging of the particle hinders collisions among secondary particles through the strong repulsive electrostatic force. Furthermore, deviations from LTE strongly affect the coagulation process, because the increased electron density at a given gas temperature increases the charging of particles. Brownian motion leads to larger secondary particles, since the average particle speed is increased. The influence of Brownian motion and particle charging cancel each other to a large extent, particularly when deviations from LTE are considered. (paper)

The Racial and Ethnic Identity Formation Process of Second-Generation Asian Indian Americans: A Phenomenological Study.

Science.gov (United States)

Iwamoto, Derek Kenji; Negi, Nalini Junko; Partiali, Rachel Negar; Creswell, John W

2013-10-01

This phenomenological study elucidates the identity development processes of 12 second-generation adult Asian Indian Americans. The results identify salient sociocultural factors and multidimensional processes of racial and ethnic identity development. Discrimination, parental, and community factors seemed to play a salient role in influencing participants' racial and ethnic identity development. The emergent Asian Indian American racial and ethnic identity model provides a contextualized overview of key developmental periods and turning points within the process of identity development.

Formation of Poultry Meat Flavor by Heating Process and Lipid Oxidation

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Maijon Purba

2014-09-01

Full Text Available Flavor is an important factor in the acceptance of food. Flavor of poultry meat is naturally formed through a specific process of heating, where various chemical reactions complex occurred among nonvolatile precursors in fatty tissue or in lean tissue. The main flavor in the form of volatile and nonvolatile components play a major influence on the acceptance of various processed meat, especially the taste. Removal of sulfur components decreases meat flavor (meaty, while removal of carbonyl compounds decrease the specific flavor and increases common flavor of the meat. Poultry meat has a fairly high fat content that easily generates lipid oxidation. Lipid oxidation in poultry meat is a sign that the meat was damaged and caused off odor. Addition of antioxidants in the diet can inhibit lipid oxidation in the meat. Lipids interaction with proteins and carbohydrates is unavoidable during the thermal processing of food, causing the appearance of volatile components. The main reaction in meat flavor formation mechanism is Maillard reaction followed by Stecker reaction and degradation of lipids and thiamine. They involve in the reaction between carbonyl and amine components to form flavor compounds, which enhance the flavor of poultry meat.

The Process of Pedagogical Culture Formation in the Future Social Worker

Science.gov (United States)

Minzhanov, Nurlan A.; Ertysbaeva, Gaukhar N.

2016-01-01

The paper is aimed at studying the features of pedagogical culture formation in future social workers and developing methods to improve the professional and pedagogical preparation quality of students in the "Social work" specialty. In the study, a survey of students in the "Social work" specialty (n = 400), and a standardized…

A review on the formation, causes, measurement, implications and reduction of neps during cotton processing

CSIR Research Space (South Africa)

Van der Sluijs, MHJ

2016-12-01

Full Text Available and processing as far back as the late 1700s, no comprehensive review has been published on the formation, composition, measurement, consequences and ways to reduce the effects of neps, only a limited review has been published in 1999 [1 M.H.J. van der Sluijs...

Petrophysical study of Szolnok Formation, Endrod gas field,

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Abdel Moktader A. El Sayed

2017-03-01

Full Text Available Results of both porosity and permeability can be used by geologists, petrophysicists, and petroleum engineers to evaluate reservoir rock, heterogeneity, and pore space history through the time of deposition and lithifaction. On the other hand, reservoir quality as well as reservoir classification could be performed based on these data correlation. The Szolnok Formation is composed mainly of turbidity elastic deposits while siltstones are intercalated by sandstone beds and streaks of marls. In the present study, 213 core samples are obtained from the Szolnok Formation of the Great Hungarian plain, Hungary. Both horizontal and vertical permeability are measured. The Szolnok Formation has two main lithologic groups: 1. clean sandstone (141 samples and 2. siltstone – marl (72 samples, it can easily differentiate between good, intermediate or even bad reservoirs. Acoustic laboratory measurements have been carried out for only 30 sandstone rock samples parallel to the bedding plane (horizontal. This paper aims to evaluate some petrophysical relationships. On the other hand, both Wyllie and Raymer models were applied for porosity estimation from seismic velocity. It is worthy to mention that reservoir diagnosis of the Szolnok Formation was our target as well. Both the porosity and permeability variation range characterizing the detected lithologic facies of the Szolnok Formation are useful for reservoir zonation. The relationship between helium and mercury porosity for whole studied samples and sandstone samples as well, are supported by a high correlation coefficient and allow its application for prediction of porosity while it reduces costs and time of laboratory measurements. The evaluation of different calculated equations for porosity from compressional wave velocity data of the Szolnok Formation are studied and the relationship between velocity and porosity displays a clear inverse trend. The comparison between laboratory porosity and sonic

Acrylamide: inhibition of formation in processed food and mitigation of toxicity in cells, animals, and humans.

Science.gov (United States)

Friedman, Mendel

2015-06-01

Potentially toxic acrylamide is largely derived from the heat-inducing reactions between the amino group of the amino acid asparagine and carbonyl groups of glucose and fructose in plant-derived foods including cereals, coffees, almonds, olives, potatoes, and sweet potatoes. This review surveys and consolidates the following dietary aspects of acrylamide: distribution in food, exposure and consumption by diverse populations, reduction of the content in different food categories, and mitigation of adverse in vivo effects. Methods to reduce acrylamide levels include selecting commercial food with a low acrylamide content, selecting cereal and potato varieties with low levels of asparagine and reducing sugars, selecting processing conditions that minimize acrylamide formation, adding food-compatible compounds and plant extracts to food formulations before processing that inhibit acrylamide formation during processing of cereal products, coffees, teas, olives, almonds, and potato products, and reducing multiorgan toxicity (antifertility, carcinogenicity, neurotoxicity, teratogenicity). The herein described observations and recommendations are of scientific interest for food chemistry, pharmacology, and toxicology, but also have the potential to benefit nutrition, food safety, and human health.

No effect of steroids on seroma formation after mastectomy

DEFF Research Database (Denmark)

Okholm, Mette; Axelsson, Christen Kirk

2011-01-01

Seroma formation is a common problem after breast surgery. Studies indicate that seroma formation is a result of the postoperative inflammatory process. Glucocorticoid inhibits the inflammatory response....

Understanding the formation process of the liquid slug in a hilly-terrain wet natural gas pipeline

DEFF Research Database (Denmark)

Yang, Yan; Li, Jingbo; Wang, Shuli

2017-01-01

condition on the liquid slug formation is discussed including pipe diameter, inclination angle, gas superficial velocity and liquid holdup. The results show that the pipe is blocked by the liquid slug at the moment of slug formed. The pipe pressure suddenly increases, and then decreases gradually...... in the process of liquid slug formation and motion. The pipe pressure drop and liquid holdup decrease along with the increasing inclination angle of ascending pipe. On the contrary, they rise with the increase of the inclination angle of descending pipe. Higher gas superficial velocity and liquid holdup result...

Glass transition and relaxation processes of polymers studied by positron annihilation

Energy Technology Data Exchange (ETDEWEB)

Uedono, Akira; Tanigawa, Shoichiro [Tsukuba Univ., Ibaraki (Japan). Inst. of Materials Science

1996-10-01

The glass transition and relaxation processes of polymers were studied by the positron annihilation technique. A positron implanted into polymers might annihilate from positronium (Ps) states in open spaces. Ps is a bound state between a positron and an electron, and its nonrelativistic quantum mechanics is practically identical to that of a hydrogen atom. The lifetime of Ps can be associated with the size of the open spaces, and the formation probability of Ps provides information of motions of molecules. Since the glass transition or relaxation processes affect behavior of open spaces, one can study these phenomena through the detection of the open spaces using the positron annihilation technique. In the present paper, we report studies of the glass transition and relaxation processes in polyethylene, polypropylene, and polystyrene by measurements of lifetime spectra of positrons and those of Doppler broadening profiles of the annihilation radiation. For these specimens, by measurements of the lifetime of Ps, {tau}{sub 3}, as a function of temperature, the glass transition temperature, T{sub g}, was determined as an onset temperature of the increase in the temperature coefficient of {tau}{sub 3}. Below T{sub g}, local motions of molecules were detected by measurements of the formation probability of Ps. The positron annihilation as a tool for the characterization of polymers was discussed. (author). 51 refs.

Using binary statistics in Taurus-Auriga to distinguish between brown dwarf formation processes

Science.gov (United States)

Marks, M.; Martín, E. L.; Béjar, V. J. S.; Lodieu, N.; Kroupa, P.; Manjavacas, E.; Thies, I.; Rebolo López, R.; Velasco, S.

2017-08-01

Context. One of the key questions of the star formation problem is whether brown dwarfs (BDs) form in the manner of stars directly from the gravitational collapse of a molecular cloud core (star-like) or whether BDs and some very low-mass stars (VLMSs) constitute a separate population that forms alongside stars comparable to the population of planets, for example through circumstellar disk (peripheral) fragmentation. Aims: For young stars in Taurus-Auriga the binary fraction has been shown to be large with little dependence on primary mass above ≈ 0.2 M⊙, while for BDs the binary fraction is computations. A small amount of dynamical processing of the stellar component was accounted for as appropriate for the low-density Taurus-Auriga embedded clusters. Results: The binary fraction declines strongly in the transition region between star-like and peripheral formation, exhibiting characteristic features. The location of these features and the steepness of this trend depend on the mass limits for star-like and peripheral formation. Such a trend might be unique to low density regions, such as Taurus, which host binary populations that are largely unprocessed dynamically in which the binary fraction is large for stars down to M-dwarfs and small for BDs. Conclusions: The existence of a strong decline in the binary fraction - primary mass diagram will become verifiable in future surveys on BD and VLMS binarity in the Taurus-Auriga star-forming region. The binary fraction - primary mass diagram is a diagnostic of the (non-)continuity of star formation along the mass scale, the separateness of the stellar and BD populations, and the dominant formation channel for BDs and BD binaries in regions of low stellar density hosting dynamically unprocessed populations.

Study of the aroma formation and transformation during the manufacturing process of oolong tea by solid-phase micro-extraction and gas chromatography-mass spectrometry combined with chemometrics.

Science.gov (United States)

Ma, Chengying; Li, Junxing; Chen, Wei; Wang, Wenwen; Qi, Dandan; Pang, Shi; Miao, Aiqing

2018-06-01

Oolong tea is a typical semi-fermented tea and is famous for its unique aroma. The aim of this study was to compare the volatile compounds during manufacturing process to reveal the formation of aroma. In this paper, a method was developed based on head-space solid phase microextraction/gas chromatography-mass spectrometry (HS-SPME/GC-MS) combined with chemometrics to assess volatile profiles during manufacturing process (fresh leaves, sun-withered leaves, rocked leaves and leaves after de-enzyming). A total of 24 aroma compounds showing significant differences during manufacturing process were identified. Subsequently, according to these aroma compounds, principal component analysis and hierarchical cluster analysis showed that the four samples were clearly distinguished from each other, which suggested that the 24 identified volatile compounds can represent the changes of volatile compounds during the four steps. Additionally, sun-withering, rocking and de-enzyming can influence the variations of volatile compounds in different degree, and we found the changes of volatile compounds in withering step were less than other two manufacturing process, indicating that the characteristic volatile compounds of oolong tea might be mainly formed in rocking stage by biological reactions and de-enzyming stage through thermal chemical transformations rather than withering stage. This study suggested that HS-SPME/GC-MS combined with chemometrics methods is accurate, sensitive, fast and ideal for rapid routine analysis of the aroma compounds changes in oolong teas during manufacturing processing. Copyright © 2018 Elsevier Ltd. All rights reserved.

Cement Formation

DEFF Research Database (Denmark)

Telschow, Samira; Jappe Frandsen, Flemming; Theisen, Kirsten

2012-01-01

Cement production has been subject to several technological changes, each of which requires detailed knowledge about the high multiplicity of processes, especially the high temperature process involved in the rotary kiln. This article gives an introduction to the topic of cement, including...... an overview of cement production, selected cement properties, and clinker phase relations. An extended summary of laboratory-scale investigations on clinkerization reactions, the most important reactions in cement production, is provided. Clinker formations by solid state reactions, solid−liquid and liquid......−liquid reactions are discussed, as are the influences of particles sizes on clinker phase formation. Furthermore, a mechanism for clinker phase formation in an industrial rotary kiln reactor is outlined....

A study on the formation of fouling in a heat exchanging system for Han-river water as cooling water

International Nuclear Information System (INIS)

Sung, Sun Kyung; Suh, Sang Ho; Rho, Hyung Woon; Cho, Young Il

2003-01-01

Scale is formed when hard water is heated or cooled in heat transfer equipments such as heat exchangers, condensers, evaporators, cooling towers, boilers, and pipe walls. When scale deposits in a heat exchanger surface, it is traditionally called fouling. The objective of the present study is to investigate the formation of fouling in a heat exchanging system. A lab-scale heat exchanging system is built-up to observe and measure the formation of fouling experimentally. Water analyses are conducted to obtain the properties of Han river water. In the present study a microscopic observation is conducted to visualize the process of scale formation. Hardness of Han-river water is higher than that of tap water in Seoul

Using Automated Processes to Generate Test Items And Their Associated Solutions and Rationales to Support Formative Feedback

Directory of Open Access Journals (Sweden)

Mark Gierl

2015-08-01

Full Text Available Automatic item generation is the process of using item models to produce assessment tasks using computer technology. An item model is similar to a template that highlights the elements in the task that must be manipulated to produce new items. The purpose of our study is to describe an innovative method for generating large numbers of diverse and heterogeneous items along with their solutions and associated rationales to support formative feedback. We demonstrate the method by generating items in two diverse content areas, mathematics and nonverbal reasoning

Selection of Sustainable Processes using Sustainability Footprint Method: A Case Study of Methanol Production from Carbon Dioxide

Science.gov (United States)

Chemical products can be obtained by process pathways involving varying amounts and types of resources, utilities, and byproduct formation. When such competing process options such as six processes for making methanol as are considered in this study, it is necessary to identify t...

Chemical composition, source, and process of urban aerosols during winter haze formation in Northeast China.

Science.gov (United States)

Zhang, Jian; Liu, Lei; Wang, Yuanyuan; Ren, Yong; Wang, Xin; Shi, Zongbo; Zhang, Daizhou; Che, Huizheng; Zhao, Hujia; Liu, Yanfei; Niu, Hongya; Chen, Jianmin; Zhang, Xiaoye; Lingaswamy, A P; Wang, Zifa; Li, Weijun

2017-12-01

The characteristics of aerosol particles have been poorly evaluated even though haze episodes frequently occur in winter in Northeast China. OC/EC analysis, ion chromatography, and transmission electron microscopy (TEM) were used to investigate the organic carbon (OC) and elemental carbon (EC), and soluble ions in PM 2.5 and the mixing state of individual particles during a severe wintertime haze episode in Northeast China. The organic matter (OM), NH 4 + , SO 4 2- , and NO 3 - concentrations in PM 2.5 were 89.5 μg/m 3 , 24.2 μg/m 3 , 28.1 μg/m 3 , and 32.8 μg/m 3 on the haze days, respectively. TEM observations further showed that over 80% of the haze particles contained primary organic aerosols (POAs). Based on a comparison of the data obtained during the haze formation, we generate the following synthetic model of the process: (1) Stable synoptic meteorological conditions drove the haze formation. (2) The early stage of haze formation (light or moderate haze) was mainly caused by the enrichment of POAs from coal burning for household heating and cooking. (3) High levels of secondary organic aerosols (SOAs), sulfates, and nitrates formation via heterogeneous reactions together with POAs accumulation promoted to the evolution from light or moderate to severe haze. Compared to the severe haze episodes over the North China Plain, the PM 2.5 in Northeast China analyzed in the present study contained similar sulfate, higher SOA, and lower nitrate contents. Our results suggest that most of the POAs and secondary particles were likely related to emissions from coal-burning residential stoves in rural outskirts and small boilers in urban areas. The inefficient burning of coal for household heating and cooking should be monitored during wintertime in Northeast China. Copyright © 2017 Elsevier Ltd. All rights reserved.

Shewanella putrefaciens Adhesion and Biofilm Formation on Food Processing Surfaces

Science.gov (United States)

Bagge, Dorthe; Hjelm, Mette; Johansen, Charlotte; Huber, Ingrid; Gram, Lone

2001-01-01

Laboratory model systems were developed for studying Shewanella putrefaciens adhesion and biofilm formation under batch and flow conditions. S. putrefaciens plays a major role in food spoilage and may cause microbially induced corrosion on steel surfaces. S. putrefaciens bacteria suspended in buffer adhered readily to stainless steel surfaces. Maximum numbers of adherent bacteria per square centimeter were reached in 8 h at 25°C and reflected the cell density in suspension. Numbers of adhering bacteria from a suspension containing 108 CFU/ml were much lower in a laminar flow system (modified Robbins device) (reaching 102 CFU/cm2) than in a batch system (reaching 107 CFU/cm2), and maximum numbers were reached after 24 h. When nutrients were supplied, S. putrefaciens grew in biofilms with layers of bacteria. The rate of biofilm formation and the thickness of the film were not dependent on the availability of carbohydrate (lactate or glucose) or on iron starvation. The number of S. putrefaciens bacteria on the surface was partly influenced by the presence of other bacteria (Pseudomonas fluorescens) which reduced the numbers of S. putrefaciens bacteria in the biofilm. Numbers of bacteria on the surface must be quantified to evaluate the influence of environmental factors on adhesion and biofilm formation. We used a combination of fluorescence microscopy (4′,6′-diamidino-2-phenylindole staining and in situ hybridization, for mixed-culture studies), ultrasonic removal of bacteria from surfaces, and indirect conductometry and found this combination sufficient to quantify bacteria on surfaces. PMID:11319118

FORMATION OF TOILET HABITS IN CHILDREN IN MOSCOW. RETROSPECTIVE STUDY RESULTS. PART II

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G. A. Karkashadze

2013-01-01

Full Text Available The results of the first Russian study of toilet habits formation in children have been obtained. The article was planned to be published in 2 subsequent parts due to the extensiveness of the material. This article is the 2nd part*. It presents and comments on the remaining part of results in the form of the connection between main parameters and characteristics of toilet habits training processes and physiological, psychological and social factors; it also presents the discussion and conclusions. Comparative data (with foreign studies is given. A multitude of both physiological and social factors affect the process of children’s toilet habits training. The following physiological factors have been revealed: stool frequency, physiological involuntary night urination, peculiarities of falling asleep and pernicious habits – processes, which reflect the intestinal motility regulation and defecation states, urination control and neuropsychic activity. The selected training strategy and tactics, style of communication with a child also affect the training process. The most influential family-social factors in terms of toilet habits training processes are: two- or one-parent family, mother’s education and twins in the family. 

InAs/InP(001) quantum dots and quantum sticks grown by MOVPE: shape, anisotropy and formation process

International Nuclear Information System (INIS)

Michon, A.; Patriarche, G.; Sagnes, I.; Beaudoin, G.; Saint-Girons, G.

2006-01-01

This contribution presents a thermodynamical analysis of the formation process of InAs/InP(001) quantum dots (QDs) or quantum sticks (QSs) grown by metalorganic vapor phase epitaxy. This study, based on an analytical model of Tersoff et al. adapted to our QD geometry, describes the origin of QD shape anisotropy and size dispersion. It also explains the shape transition from QDs to QSs under As-poor growth conditions. (copyright 2006 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

Comprehensive modelling study on observed new particle formation at the SORPES station in Nanjing, China

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X. Huang

2016-03-01

Full Text Available New particle formation (NPF has been investigated intensively during the last 2 decades because of its influence on aerosol population and the possible contribution to cloud condensation nuclei. However, intensive measurements and modelling activities on this topic in urban metropolitan areas in China with frequent high-pollution episodes are still very limited. This study provides results from a comprehensive modelling study on the occurrence of NPF events in the western part of the Yangtze River Delta (YRD region, China. The comprehensive modelling system, which combines the WRF-Chem (the Weather Research and Forecasting model coupled with Chemistry regional chemical transport model and the MALTE-BOX sectional box model (the model to predict new aerosol formation in the lower troposphere, was shown to be capable of simulating atmospheric nucleation and subsequent growth. Here we present a detailed discussion of three typical NPF days, during which the measured air masses were notably influenced by either anthropogenic activities, biogenic emissions, or mixed ocean and continental sources. Overall, simulated NPF events were generally in good agreement with the corresponding measurements, enabling us to get further insights into NPF processes in the YRD region. Based on the simulations, we conclude that biogenic organic compounds, particularly monoterpenes, play an essential role in the initial condensational growth of newly formed clusters through their low-volatility oxidation products. Although some uncertainties remain in this modelling system, this method provides a possibility to better understand particle formation and growth processes.

Shewanella putrefaciens adhesion and biofilm formation on food processing surfaces

DEFF Research Database (Denmark)

Bagge, Dorthe; Hjelm, M.; Johansen, C.

2001-01-01

Laboratory model systems were developed for studying Shewanella putrefaciens adhesion and biofilm formation under batch and flow conditions. S. putrefaciens plays a major role in food spoilage and may cause microbially induced corrosion on steel surfaces. S. putrefaciens bacteria suspended in buf...... from surfaces, and indirect conductometry and found this combination sufficient to quantify bacteria on surfaces...

Effect of Process Parameters on Flow Length and Flash Formation in Injection Moulding of High Aspect Ratio Polymeric Micro Features

Directory of Open Access Journals (Sweden)

Abdelkhalik Eladl

2018-01-01

Full Text Available This paper reports an investigation of the effects of process parameters on the quality characteristics of polymeric parts produced by micro injection moulding (μIM with two different materials. Four injection moulding process parameters (injection velocity, holding pressure, melt temperature and mould temperature were investigated using Polypropylene (PP and Acrylonitrile Butadiene Styrene (ABS. Three key characteristics of the mouldings were evaluated with respect to process settings and the material employed: part mass, flow length and flash formation. The experimentation employs a test part with four micro fingers with different aspect ratios (from 21 up to 150 and was carried out according to the Design of Experiments (DOE statistical technique. The results show that holding pressure and injection velocity are the most influential parameters on part mass with a direct effect for both materials. Both parameters have a similar effect on flow length for both PP and ABS at all aspect ratios and have higher effects as the feature thickness decreased below 300 μm. The study shows that for the investigated materials the injection speed and packing pressure were the most influential parameters for increasing the amount of flash formation, with relative effects consistent for both materials. Higher melt and mould temperatures settings were less influential parameters for increasing the flash amount when moulding with both materials. Of the two investigated materials, PP was the one exhibiting more flash formation as compared with ABS, when corresponding injection moulding parameters settings for both materials were considered.

Glyoxal processing by aerosol multiphase chemistry: towards a kinetic modeling framework of secondary organic aerosol formation in aqueous particles

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B. Ervens

2010-09-01

Full Text Available This study presents a modeling framework based on laboratory data to describe the kinetics of glyoxal reactions that form secondary organic aerosol (SOA in aqueous aerosol particles. Recent laboratory results on glyoxal reactions are reviewed and a consistent set of empirical reaction rate constants is derived that captures the kinetics of glyoxal hydration and subsequent reversible and irreversible reactions in aqueous inorganic and water-soluble organic aerosol seeds. Products of these processes include (a oligomers, (b nitrogen-containing products, (c photochemical oxidation products with high molecular weight. These additional aqueous phase processes enhance the SOA formation rate in particles and yield two to three orders of magnitude more SOA than predicted based on reaction schemes for dilute aqueous phase (cloud chemistry for the same conditions (liquid water content, particle size.

The application of the new module including detailed chemical processes in a box model demonstrates that both the time scale to reach aqueous phase equilibria and the choice of rate constants of irreversible reactions have a pronounced effect on the predicted atmospheric relevance of SOA formation from glyoxal. During day time, a photochemical (most likely radical-initiated process is the major SOA formation pathway forming ∼5 μg m⁻³ SOA over 12 h (assuming a constant glyoxal mixing ratio of 300 ppt. During night time, reactions of nitrogen-containing compounds (ammonium, amines, amino acids contribute most to the predicted SOA mass; however, the absolute predicted SOA masses are reduced by an order of magnitude as compared to day time production. The contribution of the ammonium reaction significantly increases in moderately acidic or neutral particles (5 < pH < 7.

Glyoxal uptake into ammonium sulfate seed under dark conditions can be represented with a single reaction parameter k_effupt that does not depend

Experimental study of collective processes in REB

Energy Technology Data Exchange (ETDEWEB)

Bogdanov, L Yu; Sominskij, G G [St. Petersburg Technical University (Russian Federation)

1997-12-31

The role of collective processes at relativistic electron beam formation and transportation was studied experimentally by using new low-disturbing techniques. In particular, local mirror-like enhancements of the external magnetic field were introduced and their influence of the beam space charge oscillations was investigated. The amplitude-frequency characteristics of the space charge oscillations in different parts of the drift channel were measured by a set of high-frequency probes. On the base of the collected experimental data two possible mechanisms of development of the beam space charge oscillations are discussed: the two-stream instability and the diocotron instability. (J.U.). 2 figs., 4 refs.

Why adult formation

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Andrej Justinek

1997-01-01

Full Text Available The article argues that the primary aim of adult formation is comprehensive personality development which is supposed to ensure quality existence in modern world. The article also suggests that formarion is a permanent process. Justinek puts special emphasis on adult formation methodology and defines fundamental formation styles which encourage independent action in individuals. Justinek differentiates between formation and education. methods and concludes that formation methods are related to the emotional sphere of personality, and education methods mostly to the rational. Justinek believes that formation of adults is based primarily on appropriate formation methodology.

Formation of hydrocarbons in irradiated Brazilian beans: gas chromatographic analysis to detect radiation processing

International Nuclear Information System (INIS)

Villavicencio, A.L.C.H.; Mancini-Filho, J.; Hartmann, M.; Ammon, J.; Delincee, H.

1997-01-01

Radiation processing of beans, which are a major source of dietary protein in Brazil, is a valuable alternative to chemical fumigation to combat postharvest losses due to insect infestation. To ensure free consumer choice, irradiated food will be labeled as such, and to enforce labeling, analytical methods to detect the irradiation treatment in the food product itself are desirable. In two varieties of Brazilian beans, Carioca and Macacar beans, the radiolytic formation of hydrocarbons formed after alpha and beta cleavage, with regard to the carbonyl group in triglycerides, have been studied. Using gas chromatographic analysis of these radiolytic hydrocarbons, different yields per precursor fatty acid are observed for the two types of beans. However, the typical degradation pattern allows the identification of the irradiation treatment in both bean varieties, even after 6 months of storage

Formation of soap bubbles by gas jet

OpenAIRE

Zhou, M. L.; Li, M.; Chen, Z. Y.; Han, J. F.; Liu, D.

2017-01-01

Soap bubbles can be easily generated by varies methods, while their formation process is complicated and still worth study. A model about the bubble formation process was proposed in Phys. Rev. Lett. 116, 077801 recently, and it was reported that the bubbles were formed when the gas blowing velocity was above one threshold. However, after repeating these experiments, we found the bubbles could be generated in two velocities ranges which corresponded to laminar and turbulent gas jet respective...

Photo-assisted Fenton type processes for the degradation of phenol: A kinetic study

International Nuclear Information System (INIS)

Kusic, Hrvoje; Koprivanac, Natalija; Bozic, Ana Loncaric; Selanec, Iva

2006-01-01

In this study the application of advanced oxidation processes (AOPs), dark Fenton and photo-assisted Fenton type processes; Fe 2+ /H 2 O 2 , Fe 3+ /H 2 O 2 , Fe 0 /H 2 O 2 , UV/Fe 2+ /H 2 O 2 , UV/Fe 3+ /H 2 O 2 and UV/Fe 0 /H 2 O 2 , for degradation of phenol as a model organic pollutant in the wastewater was investigated. A detail kinetic modeling which describes the degradation of phenol was performed. Mathematical models which predict phenol decomposition and formation of primary oxidation by-products: catechol, hydroquinone and benzoquinone, by applied processes were developed. The study also consist the modeling of mineralization kinetic of the phenol solution by applied AOPs. This part, besides well known reactions of Fenton and photo-Fenton chemistry, involves additional reactions which describe removal of iron from catalytic cycle through formation of ferric complexes and its regeneration induced by UV radiation. Phenol decomposition kinetic was monitored by HPLC analysis and total organic carbon content measurements (TOC). Complete phenol removal was obtained by all applied processes. Residual TOC by applied Fenton type processes ranged between 60.2 and 44.7%, while the efficiency of those processes was significantly enhanced in the presence of UV light, where residual TOC ranged between 15.2 and 2.4%

Formation and magic number characteristics of clusters formed during solidification processes

International Nuclear Information System (INIS)

Liu Rangsu; Dong Kejun; Tian Zean; Liu Hairong; Peng Ping; Yu Aibing

2007-01-01

A molecular dynamics simulation study has been performed for a large-sized system consisting of 10 6 liquid metal Al atoms to investigate the formation and magic number characteristics of various clusters formed during solidification processes. The cluster-type index method (CTIM) is adopted to describe various types of cluster by basic clusters. It is demonstrated that the icosahedral cluster (12 0 12 0) is the most important basic cluster, and that it plays a critical role in the microstructure transition. A new statistical method has been proposed to classify the clusters as some group levels according to the numbers of basic clusters contained in each cluster. The magic numbers can be determined by the respective peak value positions of different group levels of clusters, and the magic number sequence in the system is 13, 19, 25(27), 31(33), 38(40), 42(45), 48(51), 55(59), 61(65), 67,... the numbers in the brackets are the second magic number of the corresponding group levels of clusters. This magic number sequence is in good agreement with the experimental results obtained by Schriver and Harris et al, and the experimental results can be reasonably well explained

Hydrate formation during wet granulation studied by spectroscopic methods and multivariate analysis

DEFF Research Database (Denmark)

Jørgensen, Anna; Rantanen, Jukka; Karjalainen, Milja

2002-01-01

PURPOSE: The aim was to follow hydrate formation of two structurally related drugs, theophylline and caffeine, during wet granulation using fast and nondestructive spectroscopic methods. METHODS: Anhydrous theophylline and caffeine were granulated with purified water. Charge-coupled device (CCD......) Raman spectroscopy was compared with near-infrared spectroscopy (NIR) in following hydrate formation of drugs during wet granulation (off-line). To perform an at-line process analysis, the effect of water addition was monitored by NIR spectroscopy and principal components analysis (PCA). The changes...

The mechanism of nickel ferrite formation by glow discharge effect

Science.gov (United States)

Frolova, L. A.

2018-04-01

The influence of various factors on the formation of nickel ferrite by the glow discharge effect has been studied. The ferritization process in the system FeSO4-NiSO4-NaOH-H2O has been studied by the methods of potentiometric titration, measurement of electrical conductivity, residual concentrations and apparent sediment volume. It has been established that the process proceeds in a multistage fashion at pH 11-12 with the formation of polyhydroxo complexes, an intermediate compound and the ferrite formation by its oxidation with active radicals.

Formation Number Of Laminar Vortex Rings. Numerical Simulations

International Nuclear Information System (INIS)

Rosenfeld, M.; Rambod, E.; Gharib, M.

1998-01-01

The formation time scale of axisymmetric vortex rings is studied numerically for relatively long discharge times. Experimental findings on the existence and universality of a formation time scale, referred to as the formation number, are confirmed. The formation number is indicative of the time a vortex ring acquires its maximal circulation. For vortex rings generated by impulsive motion of a piston, the formation number was found experimentally to be approximately 4. Numerical extension of the experimental study to thick shear layers indicates that the scaled circulation of the pinched-off vortex is relatively insensitive of the details of the formation process, such as the velocity program, velocity profile or vortex generator geometry. In contrast, the formation number does depend on the velocity profile

Tritiated ammonia formation

International Nuclear Information System (INIS)

Heung, L.K.

1995-01-01

When nitrogen was selected as the glovebox atmosphere for the Replacement Tritium Facility (RTF) at the Savannah River Site (SRS), a concern was raised as to the possibility of tritiated ammonia formation in the gloveboxes. Experimental data were produced to study the tritiated ammonia formation rate in a tritium and nitrogen mixture. A rate equation that closely simulates the experimental data was developed. This rate equation can be used to calculate the formation of tritiated ammonia from different concentrations of tritium and nitrogen. The reaction of T 2 and N 2 to form NT 3 is a slow process, particularly when the tritium concentration is low. The reaction requires weeks or months to reach radiochemical equilibrium dependent on the concentrations of the reactants. 4 refs., 6 figs., 1 tab

Pulsed electric field and combination processing of mango nectar: effect on volatile compounds and HMF formation

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A. S. Bawa

2015-01-01

Full Text Available Mango nectar is a commercially familiar and preferred product. The traditional processing of mango nectar has been by thermal processing which resulted in the alteration of the flavour of the product due to the effect of high temperature. The thermal processing of the nectar also resulted in the production of byproducts of non-enzymatic browning such as 5- hydroxy methyl furfural (HMF. These process induced effects, affect both the nutritive and sensory attributes of the fruit product, making it less preferable. With the growing interest and awareness about the benefits of alternative non-thermal technologies, such as pulsed electric field (PEF, the present work was proposed to use PEF to minimize the loss of volatiles and formation of HMF. The study involves thermal (96 ºC for 300 s and 600 s, PEF (24 µs, 120 Hz and 38 kV/cm and combination processing (PEF + Thermal (96 ºC for 90 s of mango nectar. The effect of these treatments on the volatile composition of mango nectar has been analysed using GC-MS technique. The reduction in the volatile compounds was significant (p 0.05 different from unprocessed sample, proving the fresh-like character of the product.

The formation of PSB-like shear bands in cyclically deformed ultrafine grained copper processed by ECAP

Energy Technology Data Exchange (ETDEWEB)

Wu, S.D.; Wang, Z.G.; Jiang, C.B.; Li, G.Y.; Alexandrov, I.V.; Valiev, R.Z

2003-06-15

Cyclic deformation was performed on ultrafine grained copper processed by ECAP. Shear bands (SBs) and adjacent microstructures were investigated using electron channeling contrast in scanning electron microscope. The possible formation mechanism of SB was discussed based on the characteristic distribution of defects introduced by ECAP.

Superconductivity optimization and phase formation kinetics study of internal-Sn Nb{sub 3}Sn superconducting wires

Energy Technology Data Exchange (ETDEWEB)

Zhang, Chaowu

2007-07-15

Superconductors Nb{sub 3}Sn wires are one of the most applicable cryogenic superconducting materials and the best choice for high-field magnets exceeding 10 T. One of the most significant utilization is the ITER project which is regarded as the hope of future energy source. The high-Cu composite designs with smaller number of sub-element and non-reactive diffusion barrier, and the RRP (Restacked Rod Process) internal-Sn technology are usually applied for the wire manufacturing. Such designed and processed wires were supplied by MSA/Alstom and WST/NIN in this research. The systematic investigation on internal-Sn superconducting wires includes the optimization of heat treatment (HT) conditions, phase formation and its relation with superconductivity, microstructure analysis, and the phase formation kinetics. Because of the anfractuosity of the configuration design and metallurgical processing, the MF wires are not sufficient for studying a sole factor effect on superconductivity. Therefore, four sets of mono-element (ME) wires with different Sn ratios and different third-element addition were designed and fabricated in order to explore the relationship between phase formation and superconducting performances, particularly the A15 layer growth kinetics. Different characterization technic have been used (magnetization measurements, neutron diffraction and SEM/TEM/EDX analysis). The A15 layer thicknesses of various ME samples were measured and carried out linear and non-linear fits by means of two model equations. The results have clearly demonstrated that the phase formation kinetics of Nb{sub 3}Sn solid-state reaction is in accordance with an n power relation and the n value is increased with the increase of HT temperature and the Sn ratio in the wire composite. (author)

A review on granules initiation and development inside UASB Reactor and the main factors affecting granules formation process

Energy Technology Data Exchange (ETDEWEB)

Habeeb, S.A.; Latiff, Ab Aziz Bin Abdul; Daud, Zawawi Bin; Ahmad, Zulkifli Bin [Civil and Environmental Engineering, University Tun Hussein Onn Malaysia (Malaysia)

2011-07-01

Decades of investigations and explorations in the field of anaerobic wastewater treatment have resulted in significant indications about the role importance of sludge granules in biodegradation anaerobic process. It is believed that the development of anaerobic granules is reflecting an important role on the performance of reactor. An overview on the concept of up-flow anaerobic sludge bed (UASB) reactor operation as well as the main parts that reactor consists of is briefly explained in this paper, whereas the major theories of anaerobic granules formation are listed by related researchers. The correlations and compositions of such sludge granule have been specifically explained. It is believed that the extracellular polymer (ECP) is totally responsible of bacterial cell correlations and the formation of bacterial communities in the form of granules. In addition, the dependable factors for the performance of anaerobic granules formation process e.g. temperature, organic loading rate, pH, and alkalinity, nutrients, and cations and heavy metals have been discussed in this paper. Strong evidences proved that the process of gas production in the form of biogas is related to the methanogens activities, which are practically found in the core of granules. The aim of this review is to explore and assess the mechanisms of granules initiation and development inside UASB reactor.

A Study of Two Dwarf Irregular Galaxies with Asymmetrical Star Formation Distributions

Science.gov (United States)

Hunter, Deidre A.; Gallardo, Samavarti; Zhang, Hong-Xin; Adamo, Angela; Cook, David O.; Oh, Se-Heon; Elmegreen, Bruce G.; Kim, Hwihyun; Kahre, Lauren; Ubeda, Leonardo; Bright, Stacey N.; Ryon, Jenna E.; Fumagalli, Michele; Sacchi, Elena; Kennicutt, R. C.; Tosi, Monica; Dale, Daniel A.; Cignoni, Michele; Messa, Matteo; Grebel, Eva K.; Gouliermis, Dimitrios A.; Sabbi, Elena; Grasha, Kathryn; Gallagher, John S., III; Calzetti, Daniela; Lee, Janice C.

2018-03-01

Two dwarf irregular galaxies, DDO 187 and NGC 3738, exhibit a striking pattern of star formation: intense star formation is taking place in a large region occupying roughly half of the inner part of the optical galaxy. We use data on the H I distribution and kinematics and stellar images and colors to examine the properties of the environment in the high star formation rate (HSF) halves of the galaxies in comparison with the low star formation rate halves. We find that the pressure and gas density are higher on the HSF sides by 30%–70%. In addition we find in both galaxies that the H I velocity fields exhibit significant deviations from ordered rotation and there are large regions of high-velocity dispersion and multiple velocity components in the gas beyond the inner regions of the galaxies. The conditions in the HSF regions are likely the result of large-scale external processes affecting the internal environment of the galaxies and enabling the current star formation there.

Matrix density alters zyxin phosphorylation, which limits peripheral process formation and extension in endothelial cells invading 3D collagen matrices.

Science.gov (United States)

Abbey, Colette A; Bayless, Kayla J

2014-09-01

This study was designed to determine the optimal conditions required for known pro-angiogenic stimuli to elicit successful endothelial sprouting responses. We used an established, quantifiable model of endothelial cell (EC) sprout initiation where ECs were tested for invasion in low (1 mg/mL) and high density (5 mg/mL) 3D collagen matrices. Sphingosine 1-phosphate (S1P) alone, or S1P combined with stromal derived factor-1α (SDF) and phorbol ester (TPA), elicited robust sprouting responses. The ability of these factors to stimulate sprouting was more effective in higher density collagen matrices. S1P stimulation resulted in a significant increase in invasion distance, and with the exception of treatment groups containing phorbol ester, invasion distance was longer in 1mg/mL compared to 5mg/mL collagen matrices. Closer examination of cell morphology revealed that increasing matrix density and supplementing with SDF and TPA enhanced the formation of multicellular structures more closely resembling capillaries. TPA enhanced the frequency and size of lumen formation and correlated with a robust increase in phosphorylation of p42/p44 Erk kinase, while S1P and SDF did not. Also, a higher number of significantly longer extended processes formed in 5mg/mL compared to 1mg/mL collagen matrices. Because collagen matrices at higher density have been reported to be stiffer, we tested for changes in the mechanosensitive protein, zyxin. Interestingly, zyxin phosphorylation levels inversely correlated with matrix density, while levels of total zyxin did not change significantly. Immunofluorescence and localization studies revealed that total zyxin was distributed evenly throughout invading structures, while phosphorylated zyxin was slightly more intense in extended peripheral processes. Silencing zyxin expression increased extended process length and number of processes, while increasing zyxin levels decreased extended process length. Altogether these data indicate that ECs

Factor analysis of processes of corporate culture formation at industrial enterprises of Ukraine

Directory of Open Access Journals (Sweden)

Illiashenko Sergii

2016-06-01

Full Text Available Authors have analyzed and synthesized the features of formation and development of the corporate culture at industrial enterprises of Ukraine and on this basis developed recommendations for application in the management of strategic development. During the research authors used the following general scientific methods: at research of patterns of interaction national culture, corporate culture and the culture of the individual authors used logical generalization method; for determining factors influencing corporate culture formation with the level of occurrence authors used factor analysis; for trend analysis of the corporate culture development at appropriate levels authors used comparative method. Results of the analysis showed that macro- and microfactors are external and mezofaktors (adaptability of business and corporate governance, corporate ethics, corporate social responsibility and personnel policies, corporate finance are internal for an enterprise. Authors have identified areas for each of the factors, itemized obstacles to the establishment and development of corporate culture at Ukrainian industrial enterprises and proposed recommendations for these processes management.

Studies of phase formation in CoSi2 buried layers fabricated using ion implantation

International Nuclear Information System (INIS)

Galaev, A.A.; Parkhomenko, Yu.N.; Podgornyi, D.A.; Shcherbachev, K.D.

1998-01-01

The processes of the formation of cobalt disilicide buried layers in silicon are studied under different conditions of implantation with Co. In particular, the effects of the implantation dose and the postimplantation annealing temperature on the state of the Co-implanted layer are considered. Two types of heteroepitaxial Si/CoSi 2 /Si structures are obtained with the conducting layers of thicknesses 70 and 90 nm buried at the depths 80 and 10 nm, respectively

Experimental and theoretical investigations on the carbon dioxide gas hydrate formation kinetics at the onset of turbidity regarding CO2 capture and sequestration processes

International Nuclear Information System (INIS)

ZareNezhad, Bahman; Mottahedin, Mona; Varaminian, Farshad

2013-01-01

The carbon dioxide gas hydrate formation kinetics at the onset of turbidity is experimentally and theoretically investigated. It is shown that the time-dependent heterogeneous nucleation and growth kinetics are simultaneously governing the hydrate formation process at the onset of turbidity. A new approach is also presented for determination of gas hydrate-liquid interfacial tension. The CO 2 hydrate-liquid interfacial tension according to the suggested heterogeneous nucleation mechanism is found to be about 12.7 mJ/m 2 . The overall average absolute deviation between predicted and measured CO 2 molar consumption is about 0.61%, indicating the excellent accuracy of the proposed model for studying the hydrate-based CO 2 capture and sequestration processes over wide ranges of pressures and temperatures

Processes Underlying Developmental Reversals in False-Memory Formation: Comment on Brainerd, Reyna, and Ceci (2008)

Science.gov (United States)

Ghetti, Simona

2008-01-01

C. J. Brainerd, V. F. Reyna, and S. J. Ceci (2008) reviewed compelling evidence of developmental reversals in false-memory formation (i.e., younger children exhibit lower false-memory rates than do older children and adults) and proposed that this phenomenon depends on the development of gist processing (i.e., the ability to identify and process…

Observations and Simulations of Formation of Broad Plasma Depletions Through Merging Process

Science.gov (United States)

Huang, Chao-Song; Retterer, J. M.; Beaujardiere, O. De La; Roddy, P. A.; Hunton, D.E.; Ballenthin, J. O.; Pfaff, Robert F.

2012-01-01

Broad plasma depletions in the equatorial ionosphere near dawn are region in which the plasma density is reduced by 1-3 orders of magnitude over thousands of kilometers in longitude. This phenomenon is observed repeatedly by the Communication/Navigation Outage Forecasting System (C/NOFS) satellite during deep solar minimum. The plasma flow inside the depletion region can be strongly upward. The possible causal mechanism for the formation of broad plasma depletions is that the broad depletions result from merging of multiple equatorial plasma bubbles. The purpose of this study is to demonstrate the feasibility of the merging mechanism with new observations and simulations. We present C/NOFS observations for two cases. A series of plasma bubbles is first detected by C/NOFS over a longitudinal range of 3300-3800 km around midnight. Each of the individual bubbles has a typical width of approx 100 km in longitude, and the upward ion drift velocity inside the bubbles is 200-400 m/s. The plasma bubbles rotate with the Earth to the dawn sector and become broad plasma depletions. The observations clearly show the evolution from multiple plasma bubbles to broad depletions. Large upward plasma flow occurs inside the depletion region over 3800 km in longitude and exists for approx 5 h. We also present the numerical simulations of bubble merging with the physics-based low-latitude ionospheric model. It is found that two separate plasma bubbles join together and form a single, wider bubble. The simulations show that the merging process of plasma bubbles can indeed occur in incompressible ionospheric plasma. The simulation results support the merging mechanism for the formation of broad plasma depletions.

Sedimentary processes in the Carnot Formation (Central African Republic) related to the palaeogeographic framework of Central Africa

Science.gov (United States)

Censier, Claude; Lang, Jacques

1999-08-01

The depositional environment, provenance and processes of emplacement of the detrital material of the Mesozoic Carnot Formation are defined, by bedding and sedimentological analysis of its main facies, and are reconstructed within the palaeogeographic framework of Central Africa. The clastic material was laid down between probably the Albian and the end of the Cretaceous, in a NNW-oriented braided stream fluvial system that drained into the Doba Trough (Chad) and probably also into the Touboro Basin (Cameroon). The material was derived from weathering of the underlying Devonian-Carboniferous Mambéré Glacial Formation and of the Precambrian schist-quartzite complex located to the south of the Carnot Formation. These results provide useful indications as to the provenance of diamonds mined in the southwest Central African Republic.

The effect of ethanol blending on mixture formation, combustion and soot emission studied in an optical DISI engine

International Nuclear Information System (INIS)

Storch, Michael; Hinrichsen, Florian; Wensing, Michael; Will, Stefan; Zigan, Lars

2015-01-01

Highlights: • Catalyst heating points were analyzed using optical measurement techniques. • E20 shows stronger soot radiation and higher soot concentration as isooctane. • Different mixing formation of isooctane and E20 was determined. • Strong mixture stratification was identified for both fuels. • Remaining droplets and fuel rich regions are the main source for soot formation. - Abstract: In various research studies, ethanol blended fuels have shown reduced particulate matter (PM) emissions in comparison to gasoline and its surrogate fuels in direct-injection spark-ignition (DISI) engines. However, there are also studies reporting increased particulate concentration for fuels with low ethanol content. In this work the mixture formation and sooting combustion behavior of isooctane and the mixture E20 (20 vol% of ethanol in isooctane) is analyzed for catalyst heating operation. These operating conditions are critical as they strongly contribute to overall soot emissions in driving cycles. Simultaneous high speed imaging of OH ∗ –chemiluminescence and natural soot luminosity measurements are performed in combination with primary particle concentration measurements using a laser induced incandescence (LII) sensor in the engine exhaust duct. At these operating conditions E20 exhibits a higher sooting tendency as compared to isooctane. In order to identify the reason for increased soot formation, the mixture formation process is analyzed by planar laser induced fluorescence (LIF) measurements. The results show that soot was formed in fuel rich regions with incomplete evaporated fuel droplets remaining from the injection event. A different evaporation process of E20 fuel spray and mixing behavior is indicated showing a more compact rich mixture cloud with surrounding lean areas near the spark plug region. This mixture stratification is characterized by higher cyclic variations and constitutes a significant source of soot formation

Formation of semisolid, oligomerized aqueous SOA: lab simulations of cloud processing.

Science.gov (United States)

Hawkins, Lelia N; Baril, Molly J; Sedehi, Nahzaneen; Galloway, Melissa M; De Haan, David O; Schill, Gregory P; Tolbert, Margaret A

2014-02-18

Glyoxal, methylglyoxal, glycolaldehyde, and hydroxyacetone form N-containing and oligomeric compounds during simulated cloud processing with small amines. Using a novel hygroscopicity tandem differential mobility analysis (HTDMA) system that allows varied humidification times, the hygroscopic growth (HG) of each of the resulting products of simulated cloud processing was measured. Continuous water uptake (gradual deliquescence) was observed beginning at ∼ 40% RH for all aldehyde-methylamine products. Particles containing ionic reaction products of either glyoxal or glycine were most hygroscopic, with HG between 1.16 and 1.20 at 80% RH. Longer humidification times (up to 20 min) produced an increase in growth factors for glyoxal-methylamine (19% by vol) and methylglyoxal-methylamine (8% by vol) aerosol, indicating that unusually long equilibration times can be required for HTDMA measurements of such particles. Glyoxal- and methylglyoxal-methylamine aerosol particles shattered in Raman microscopy impact-flow experiments, revealing that the particles were semisolid. Similar experiments on glycolaldehyde- and hydroxyacetone-methylamine aerosol found that the aerosol particles were liquid when dried for glyoxal > glycolaldehyde = hydroxyacetone, likely caused by the speed of oligomer formation in each system.

Blistering and bubble formation

International Nuclear Information System (INIS)

Roth, J.

1976-01-01

Blister formation in metals has been observed during bombardment with inert-gas ions in the energy range between 1 and 2000 keV at doses of about 10 17 to 10 19 cm -2 . The changes in surface topography and the erosion yields were mainly studied in the scanning electron microscope (SEM). Additionally the release of the implanted gas during blister formation was observed. Recently measurements on single crystals were performed determining simultaneously the implantation profile, the total amount of trapped ions, the depth distribution of the induced lattice damage and the thickness of the covers of the blisters. In several stages of the formation process of blisters the implanted layer was observed in the transmission electron microscope (TEM) showing the formation of gas bubbles. Using the results of all these measurements in this review an attempt is made to develop a model of blister formation combining the effects of hydrostatic pressure in the gas bubbles and lateral stress due to volume swelling. (author)

Understanding Educational Policy Formation: The Case of School Violence Policies in Israel

Science.gov (United States)

Fast, Idit

2016-01-01

This study explores mechanisms underlying processes of educational policy formation. Previous studies have given much attention to processes of diffusion when accounting for educational policy formation. Less account has been given to the day-to-day institutional dynamics through which educational policies develop and change. Building on extensive…

Forces in strategy formation

DEFF Research Database (Denmark)

Steensen, Elmer Fly; Sanchez, Ron

2008-01-01

This chapter proposes that organizational strategy formation should be characterized theoretically as a process that is subject to several interacting forces, rather than represented by separate discrete decisionmodels or theoretic perspectives, as is commonly done in the strategic management...... literature. Based on an extensive review of relevant theory and empirical work in strategic decision-making, organizational change theory, cognitive and social psychology, and strategy processes, seven kinds of ''forces'' - rational, imposed, teleological, learning, political, heuristic, and social...... - are identified as interacting in and having significant influence on the strategy formation process. It is further argued that by applying a holistic ''forces-view'' of the significant and interacting influences on strategy formation, we can better understand the dynamics and challenges in managing the process...

Brittle fracture in viscoelastic materials as a pattern-formation process

Science.gov (United States)

Fleck, M.; Pilipenko, D.; Spatschek, R.; Brener, E. A.

2011-04-01

A continuum model of crack propagation in brittle viscoelastic materials is presented and discussed. Thereby, the phenomenon of fracture is understood as an elastically induced nonequilibrium interfacial pattern formation process. In this spirit, a full description of a propagating crack provides the determination of the entire time dependent shape of the crack surface, which is assumed to be extended over a finite and self-consistently selected length scale. The mechanism of crack propagation, that is, the motion of the crack surface, is then determined through linear nonequilibrium transport equations. Here we consider two different mechanisms, a first-order phase transformation and surface diffusion. We give scaling arguments showing that steady-state solutions with a self-consistently selected propagation velocity and crack shape can exist provided that elastodynamic or viscoelastic effects are taken into account, whereas static elasticity alone is not sufficient. In this respect, inertial effects as well as viscous damping are identified to be sufficient crack tip selection mechanisms. Exploring the arising description of brittle fracture numerically, we study steady-state crack propagation in the viscoelastic and inertia limit as well as in an intermediate regime, where both effects are important. The arising free boundary problems are solved by phase field methods and a sharp interface approach using a multipole expansion technique. Different types of loading, mode I, mode III fracture, as well as mixtures of them, are discussed.

A Conceptual Discussion of the Strategy Process in Organizations: Formulation and Formation of StrategyHttp://Dx.Doi.Org/10.5585/Riae.V10i1.1711

Directory of Open Access Journals (Sweden)

Mônica Külkamp Beppler

2011-06-01

Full Text Available This article aims to address the strategy process within organizations, in light of the terminologies of strategic formulation and formation. The purpose is to elucidate the understanding of persistently used terms, occasionally causing a lack of interpretation of what is actually exposed about the strategy process, i.e., the variations between adopting i classic strategies, which call for different stages of formulation and implementation, and ii emerging strategies, or those having a procedural nature, performed in response to environmental changes. The present article also targets clarifying the characteristics of each approach through the theoretical construct of authors. This research is characterized as a descriptive study, predominantly qualitative and where the collected data were obtained through a literature review. Through analysis of the most prominent authors on strategy, it was found that the differences between strategic formulation and formation are not limited to the used terminology. Said approaches have significant differences within the entire strategy process, differing mainly in how they occur within organizations: in strategic formulation, there is a prescriptive, deliberate and rational process, whereas in strategic formation, emphasis on description exists, and the strategy is an emergent, unintentional process, consolidated by a series of patterns of decisions over time. Finally, perceiving the distinction between the two approaches is considered fundamental for the understanding of strategy in organizations, especially in regard to variables potentially influencing its process.

Synthesis of molecules in interstellar clouds and star formation

International Nuclear Information System (INIS)

Ghosh, K.K.; Ghosh, S.N.

1981-01-01

Study of the formation and destruction processes of interstellar molecules may throw certain light on interstellar medium. Formation and destruction processes of some interstellar molecules are proposed on the basis of laboratory data. The abundances of these molecules are calculated under steady-state condition. The calculated values are then compared with the observed values, obtained by different investigators. It appears that gas phase ion-neutral reactions are capable of synthesizing most interstellar molecules. The role of ion-neutral reactions to star formation has also been discussed. (author)

Topography Battles Surface Texture: An Experimental Study of Pool-riffle Formation

Science.gov (United States)

Chartrand, S. M.; Hassan, M. A.; Jellinek, M.

2016-12-01

Pool-riffles are perhaps the most common streambed shape found in streams and rivers, and not surprisingly, they are essential to salmon ecology, and are a central focus of many restoration actions. Yet, when an applied earth scientist or engineer is faced with developing a pool-riffle design, there is a lack of clear and rigorously developed design guidelines. Given the volumes of money spent annually within the restoration industry, this is a real problem. Recognition of this problem is growing, however, and an increasing level of attention has been directed to questions of pool-riffle formation in the past decade. At this point and given certain landscape characteristics, it is well established that streamwise gradients in channel width are associated with pool-riffles. Specifically, pools are associated with negative gradients in width, and riffles with positive gradients. Importantly, these associations have now been documented from field-derived data, as well as via experimental and numerical investigations. There is much to build from the present knowledge base, and central to this are questions related to (a) how pool-riffles evolve during the formative process, (b) what are the basic set of ingredients necessary for pool-riffle formation within systems characterized by relatively non-erodible channel margins, and (c) do pool-riffles persist, once formed, under a broad range of forcing conditions? We have completed four physical experiments examining the process and evolution of pool-riffle formation under a large range of upstream boundary, as well as physical channel conditions. We will report on two of the completed experiments. Our work will highlight two new non-dimensional channel evolution numbers, derived to help describe and characterize bedform development, as well as response to perturbations from near-equilibrium conditions. The channel evolution numbers lay the foundation for development of a new regime diagram, which quantifies the basic

Study of gel formation in polypropylene modified by gamma irradiation

International Nuclear Information System (INIS)

Oliani, W.L.; Parra, D.F.; Fermino, D.M.; Lima, L.F.C.P.; Lugao, A.B.; Riella, H.G.

2010-01-01

The linearity of the chains of iPP (isotactic polypropylene) confers to this, low melt strength. This fact limits the use of iPP in processes that demand high stretching. The graft of branches confers improvements in its extensional viscosity, resulting in Polypropylene with High Melt Strength (HMS-PP). Preparation process of the HMS-PP, included iPP in pellets, conditioned in plastic container containing acetylene under pressure of 110 kPa and radiation with γ source of 60 Co in the doses of 5, 12.5 and 20 kGy. The gel fraction of the samples was determined by the extraction of soluble components in xylene under boiling for 12 hours at 138 deg C. The soluble part of the samples was decanted with the total volatilization of the xylene to the room temperature (25 deg C) and deposition in glass blades. These samples had been characterized by Optic Microscopy, Scanning Electron Microscopy and Infrared Spectroscopy. In this study of the morphology, we obtained the formation of gel and microgel of polypropylene with higher incidence in HMS-PP 20 kGy. (author)

Facilitating participation in formative evaluation supported by effect map

DEFF Research Database (Denmark)

Granlien, Maren Sander

2009-01-01

It has been suggested that formative evaluation should be an integrated part of system implementation in order to improve the outcome of system use. In a design project an approach combining participatory design (PD) and formative evaluation has shown a great potential for improving the design of...... map is applied in an action research study in the Danish health care sector aiming at improving the medication process and the use of the electronic medication record supporting the medication process. ...... designed effect map. The purpose of the effect map is twofold: a) To encourage user participation in the early activities of formative evaluation b) The effects specified can be used as formative evaluation measures and guidance in the process of improving the system. The evaluation approach and the effect...

The formation of transnational elite as a factor of modern globalization processes

Directory of Open Access Journals (Sweden)

M. A. Artemenko

2014-10-01

Full Text Available This article deals with the characteristics of the formation of transnational elite and its influence on contemporary political and economic processes in the world, the problems of existence and communication with the Ukrainian national elite. The emergence of transnational elites due to the logic of globalization –transformation of the world in a certain social integrity. In this context, there is a loss of current national elites completeness of legitimacy and the emergence of new transnational subject of history, extending its authority throughout the world space and creates a new format of authority. The author gives his own definition of this phenomenon and proposes to consider the transnational elite association as the most influential members of certain 3 classes. In this article are identified the determinants of the formation of a transnational elite, as well as the basic platforms of its interaction (World Economic Forum, the Bilderberg Group, the Asian forum, and so on. Particular attention is paid to the analysis of communication transnational elite with the Ukrainian national elite, which is directly linked to the future political development of Ukraine, forced to adapt to the challenges of globalization and seek answers to them. In this context, the author notes the importance of the Yalta European Strategy, which is a platform of convergence Ukrainian elite with the worldwide elite. In the article is also reviewed the program «promoting democracy» as an example of conscious realization different political and economic projects around the world by transnational elite.

Study of the Influence of Key Process Parameters on Furfural Production.

Science.gov (United States)

Fele Žilnik, Ljudmila; Grilc, Viktor; Mirt, Ivan; Cerovečki, Željko

2016-01-01

The present work reports the influence of key process variables on the furfural formation from leached chestnut-wood chips in a pressurized reactor. Effect of temperature, pressure, type and concentration of the catalyst solution, the steam flow rate or stripping module, the moisture content of the wood particles and geometric characteristics such as size and type of the reactor, particle size and bed height were considered systematically. One stage process was only taken into consideration. Lab-scale and pilot-scale studies were performed. The results of the non-catalysed laboratory experiments were compared with an actual non-catalysed (auto-catalysed) industrial process and with experiments on the pilot scale, the latter with 28% higher furfural yield compared to the others. Application of sulphuric acid as catalyst, in an amount of 0.03-0.05 g (H2SO4 100%)/g d.m. (dry material), enables a higher production of furfural at lower temperature and pressure of steam in a shorter reaction time. Pilot scale catalysed experiments have revealed very good performance for furfural formation under less severe operating conditions, with a maximum furfural yield as much as 88% of the theoretical value.

The conception of administrators regarding the formation of a healthcare consortium in Pernambuco, Brazil: a case study.

Science.gov (United States)

e Silva, Keila S Brito; Bezerra, Adriana Falangola B

2011-01-01

The formation of healthcare consortia is a management strategy adopted by a number of cities in Brazil in order to minimize the difficulties the population has in access to services of greater technological complexity. As administrators are the main governmental actors in the promotion of this strategy, the aim of the present study was to identify the motives, expectations and difficulties faced by the mayors, and secretaries of health that make up a healthcare consortium undergoing a formation process in the rural, coastal zone of the state of Pernambuco. A descriptive, qualitative, case study was conducted. Data collection was carried out through semi-structured interviews held with mayors and secretaries of health of the municipalities participating in the consortium. Data were analyzed by means of content analysis, using the NVivo 2.0 software program. The administrators cited difficulty in access to specialized services and the high cost of transporting patients to distant locations for treatment as motives for the formation of the consortium. With the implantation of this healthcare strategy, the expectations are a reduction in costs regarding patient transportation, an increase in access to services of greater complexity, and negotiations with other spheres of government. The main difficulties faced are political-partisan conflicts and excessive bureaucracy. Although there were no considerable divergences in the administrators' perceptions, it was evident that those who initiated the formation of the consortium offered a deeper, more detailed discourse, thereby demonstrating greater involvement when compared to those who offered continuity to the process. Copyright © 2010 John Wiley & Sons, Ltd.

NEPHELINE FORMATION STUDY FOR SLUDGE BATCH 4: PHASE 3 EXPERIMENTAL RESULTS

International Nuclear Information System (INIS)

Fox, K

2006-01-01

This Phase 3 study was undertaken to complement the previous phases of the nepheline formation studies1, 2 by continuing the investigation into the ability of the nepheline discriminator to predict the occurrence of nepheline crystallization in Sludge Batch 4 (SB4) glasses and into the impact of such phases on the durability of the SB4 glasses. The Phase 3 study had two primary objectives. The first was to continue to demonstrate the ability of the discriminator value to adequately predict the nepheline formation potential for specific glass systems of interest. The second was to generate additional data that have a high probability of supporting the SB4 variability study. To support these two objectives, sixteen glasses were selected based on the most recent SB4 compositional projection, Case 15C Blend 1.3 Four different frits were included, based on previous assessments of projected operating windows and melt rate,4, 5 with four WLs selected for each frit. Eight of these frit-sludge combinations covered WLs which tightly bound the nepheline discriminator value of 0.62, with the intent of refining this value to a level of confidence where it can be incorporated into offline administrative controls and/or the Process Composition Control System (PCCS) to support Slurry Mix Evaporator (SME) acceptability decisions. The remaining eight frit-sludge combinations targeted lower WLs (35 and 40%) and were prepared and analyzed to contribute needed data to the ComPro database6 to support a potential variability study for SB4

Theory of aurora formation

International Nuclear Information System (INIS)

Hasegawa, Akira.

1975-04-01

A new theory of aurora formation is presented based on Alfven wave-electron interaction. The theory explains consistently 1) the electron acceleration process, 2) the formation of auroral layers and 3) the long wave formation in the longitudinal direction. (auth.)

Pore Formation Process of Porous Ti3SiC2 Fabricated by Reactive Sintering

Directory of Open Access Journals (Sweden)

Huibin Zhang

2017-02-01

Full Text Available Porous Ti3SiC2 was fabricated with high purity, 99.4 vol %, through reactive sintering of titanium hydride (TiH2, silicon (Si and graphite (C elemental powders. The reaction procedures and the pore structure evolution during the sintering process were systematically studied by X-ray diffraction (XRD and scanning electron microscope (SEM. Our results show that the formation of Ti3SiC2 from TiH2/Si/C powders experienced the following steps: firstly, TiH2 decomposed into Ti; secondly, TiC and Ti5Si3 intermediate phases were generated; finally, Ti3SiC2 was produced through the reaction of TiC, Ti5Si3 and Si. The pores formed in the synthesis procedure of porous Ti3SiC2 ceramics are derived from the following aspects: interstitial pores left during the pressing procedure; pores formed because of the TiH2 decomposition; pores formed through the reactions between Ti and Si and Ti and C powders; and the pores produced accompanying the final phase synthesized during the high temperature sintering process.

Exploring the influence of encoding format on subsequent memory.

Science.gov (United States)

Turney, Indira C; Dennis, Nancy A; Maillet, David; Rajah, M Natasha

2017-05-01

Distinctive encoding is greatly influenced by gist-based processes and has been shown to suffer when highly similar items are presented in close succession. Thus, elucidating the mechanisms underlying how presentation format affects gist processing is essential in determining the factors that influence these encoding processes. The current study utilised multivariate partial least squares (PLS) analysis to identify encoding networks directly associated with retrieval performance in a blocked and intermixed presentation condition. Subsequent memory analysis for successfully encoded items indicated no significant differences between reaction time and retrieval performance and presentation format. Despite no significant behavioural differences, behaviour PLS revealed differences in brain-behaviour correlations and mean condition activity in brain regions associated with gist-based vs. distinctive encoding. Specifically, the intermixed format encouraged more distinctive encoding, showing increased activation of regions associated with strategy use and visual processing (e.g., frontal and visual cortices, respectively). Alternatively, the blocked format exhibited increased gist-based processes, accompanied by increased activity in the right inferior frontal gyrus. Together, results suggest that the sequence that information is presented during encoding affects the degree to which distinctive encoding is engaged. These findings extend our understanding of the Fuzzy Trace Theory and the role of presentation format on encoding processes.

Formation of metal and dielectric liners using a solution process for deep trench capacitors.

Science.gov (United States)

Ham, Yong-Hyun; Kim, Dong-Pyo; Baek, Kyu-Ha; Park, Kun-Sik; Kim, Moonkeun; Kwon, Kwang-Ho; Shin, Hong-Sik; Lee, Kijun; Do, Lee-Mi

2012-07-01

We demonstrated the feasibility of metal and dielectric liners using a solution process for deep trench capacitor application. The deep Si trench via with size of 10.3 microm and depth of 71 microm were fabricated by Bosch process in deep reactive ion etch (DRIE) system. The aspect ratio was about 7. Then, nano-Ag ink and poly(4-vinylphenol) (PVPh) were used to form metal and dielectric liners, respectively. The thicknesses of the Ag and PVPh liners were about 144 and 830 nm, respectively. When the curing temperature of Ag film increased from 120 to 150 degrees C, the sheet resistance decreased rapidly from 2.47 to 0.72 Omega/sq and then slightly decreased to 0.6 Omega/sq with further increasing the curing temperature beyond 150 degrees C. The proposed liner formation method using solution process is a simple and cost effective process for the high capacity of deep trench capacitor.

Theoretical study of the possibility of glycin with thiotriazoline complexes formation

Directory of Open Access Journals (Sweden)

L. I. Kucherenko

2017-10-01

Full Text Available Brain strokes are widely spread all over the world and are among the most dangerous for the population. Often it leads to death, complete or partial loss of ability to work. The correction of imbalance of Excitatory and inhibitory neurotransmitter systems by activation of natural inhibitory processes is a promising direction of primary neuroprotection in cerebral ischemia. Particular attention is drawn to the natural inhibitory neurotransmitter – glycine and its role in the mechanisms of acute cerebral ischemia. There are data on the ability of the thiotriazoline antioxidant to potentiate the therapeutic effect of neurometabolic cerebroprotectors. Therefore, the creation of new combined preparation based on glycine with thiotriazoline is important today. Objective: to study the structure, and estimate the energy of formation and geometric characteristics of the intermolecular hydrogen bonds for complexes which are formed with glycine, 3-methyl-1,2,4-triazolyl-5-thioacetate (MTTA and morpholine. Method of calculation. The initial approximation to the structure of the complexes was obtained with the help of molecular docking procedure using the AutoDock Vina program. The resulting three-component complexes were preliminarily optimized by the semiempirical PM7 method, taking into account the outward influences, which was simulated by the COSMO method. The calculations were carried out using the MOPAC2012 program. The complexes were optimized using the density functional method with the empirical dispersion correction B97-D3/SVP+COSMO (Water using geometric correction for the incompleteness of the gCP basic set. A more accurate calculation of the solvation energy was carried out by SMD method. Calculations by the density functional method were carried out using the ORCA 3.0.3 program. The energy of formation of complexes in solution was calculated as the difference between the free Gibbs energies of the solvated complex and its individual solvated

Optimization of palm oil physical refining process for reduction of 3-monochloropropane-1,2-diol (3-MCPD) ester formation.

Science.gov (United States)

Zulkurnain, Musfirah; Lai, Oi Ming; Tan, Soo Choon; Abdul Latip, Razam; Tan, Chin Ping

2013-04-03

The reduction of 3-monochloropropane-1,2-diol (3-MCPD) ester formation in refined palm oil was achieved by incorporation of additional processing steps in the physical refining process to remove chloroester precursors prior to the deodorization step. The modified refining process was optimized for the least 3-MCPD ester formation and acceptable refined palm oil quality using response surface methodology (RSM) with five processing parameters: water dosage, phosphoric acid dosage, degumming temperature, activated clay dosage, and deodorization temperature. The removal of chloroester precursors was largely accomplished by increasing the water dosage, while the reduction of 3-MCPD esters was a compromise in oxidative stability and color of the refined palm oil because some factors such as acid dosage, degumming temperature, and deodorization temperature showed contradictory effects. The optimization resulted in 87.2% reduction of 3-MCPD esters from 2.9 mg/kg in the conventional refining process to 0.4 mg/kg, with color and oil stability index values of 2.4 R and 14.3 h, respectively.

A Study of the Effect of Interrupted Quenches on a Thermomechanically Processed High Carbon Steel.

Science.gov (United States)

1982-10-01

steel . Successful martempering requires a cooling rate sufficient to avoid the nose of the C- curve and thus prevent significant bainite formation. When...STUDY OF THE EFFECT OF INTERRUPTED QUENCHES ON A THERMONECHANICALLY PROCESSED HIGH CARBON STEEL by Steven A. Barton October 1982 Thesis Advisor: T.R...unlimited. A Study of the Effect of Interrupted Quenches on a Thermomechanically Processed High Carbon Steel by Steven A. Barton Lieutenant, United

Optical study of the ultrasonic formation process of noble metal nanoparticles dispersed inside the pores of monolithic mesoporous silica

CERN Document Server

Fu Gan Hua; Kan Cai Xia; Li Cun Cheng; Fang Qi

2003-01-01

Gold nanoparticles dispersed inside the pores of monolithic mesoporous silica were prepared by soaking the silica in a gold (III) ion solution and subsequent ultrasound irradiation. The formation process of gold nanoparticles in the pores of mesoporous silica was investigated based on optical measurements of wrapped and naked soaked silica after ultrasonic irradiation, and the reduction rate effect in solution and pre-soaking effect. It has been shown that acoustic cavitation cannot occur in nano-sized pores. The gold nanoparticles in silica are not formed in situ within the pores but produced mainly by diffusion of the gold clusters formed in the solution during irradiation into the pores. The radicals formed in solution are exhausted before entering the pores of silica. There exists a critical reduction rate in solution, at which the yield of gold nanoparticles in silica reaches a maximum, and above which there is a decrease in the yield. This is attributed to too quick a growth or aggregation of gold clust...

Signal Formation Processes in Micromegas Detectors and Quality Control for large size Detector Construction for the ATLAS New Small Wheel

CERN Document Server

AUTHOR|(INSPIRE)INSPIRE-00387450; Rembser, Christoph

2017-08-04

The Micromegas technology is one of the most successful modern gaseous detector concepts and widely utilized in nuclear and particle physics experiments. Twenty years of R & D rendered the technology sufficiently mature to be selected as precision tracking detector for the New Small Wheel (NSW) upgrade of the ATLAS Muon spectrometer. This will be the first large scale application of Micromegas in one of the major LHC experiments. However, many of the fundamental microscopic processes in these gaseous detectors are still not fully understood and studies on several detector aspects, like the micromesh geometry, have never been addressed systematically. The studies on signal formation in Micromegas, presented in the first part of this thesis, focuses on the microscopic signal electron loss mechanisms and the amplification processes in electron gas interaction. Based on a detailed model of detector parameter dependencies, these processes are scrutinized in an iterating comparison between exper- imental result...

Processing and thin film formation of TiO{sub 2}-Pt nanocomposites

Energy Technology Data Exchange (ETDEWEB)

Es-Souni, M.; Kartopu, G.; Habouti, S.; Piorra, A.; Solterbeck, C.H. [Institute for Materials and Surface Technology, Kiel University of Applied Sciences, Grenzstr. 3, 24149 Kiel (Germany); Es-Souni, Mar.; Brandies, H.F. [Faculty of Dentistry, Christian-Albrecht University, Kiel (Germany)

2008-02-15

Thin films of TiO{sub 2}-Pt nanocomposites containing 4 at% Pt have been processed via spin-coating. Film characterization involved XRD, Raman as well as XPS and scanning surface potential microscopy (SSPM). After annealing at 500 C the thin films consisted of nanocrystalline anatase and a few nm Pt nanoclusters. Annealing at 600 C resulted in the formation of a high volume fraction of rutile, {proportional_to}70%, and a coarsening of the microstructure, including Pt nanoparticles which attained a mean particle size of up to 11 nm. These results contrasted with those of pure TiO{sub 2} films obtained at 600 C which showed only a limited amount of rutile formation, namely 9%. Raman spectra of Pt-containing samples exhibited a fluorescence emission, as background to the Raman features, which was attributed to photoinduced luminescence from Pt nanoparticles supported by their surface plasmon resonance. Emission intensity being much higher in 600 C film indicated a difference between the two films in terms of the (Pt) particle size and crystallinity, in agreement with the XRD results. XPS investigations revealed different oxidation states of Pt at the surface and in the film interior. The spectra suggested a slight oxidation of Pt at the surface while mainly metallic Pt was revealed in the film interior. The morphology and distribution of the Pt nanoparticles in the films annealed at 600 C were investigated using SSPM. Discrete Pt nanoparticles, mainly distributed in the vicinity of TiO{sub 2} grain boundaries were revealed. Nanocomposite film formation, Pt distribution and morphology are explained in terms of the limited solubility of Pt in the TiO{sub 2} lattice and its higher surface energy in comparison to that of TiO{sub 2}. Both effects are believed to lead to the formation of Pt nanoparticles at the (anatase or rutile) grain boundaries. (copyright 2008 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

Experimental study upon the effect of irradiation on callus formation of fracture. Observation of vascular alteration and callus formation

Energy Technology Data Exchange (ETDEWEB)

Saigusa, F [Nippon Dental Coll., Tokyo

1981-02-01

Irradiation effects on callus formation after bone fracture were studied in rats with fractured right lower extremity. Follow-up study was continued for 112 days since 3000 rad was irradiated to the fractured site 3 days after bone fracture. Callus formation was noted in both of the outer and inner part (bone marrow) of the diaphysis before 14 days after bone fracture, but it was slow and sparse compared with that of non-irradiated group. Callus formation tended to disappear gradually from the outside of the diaphysis after 28 days after bone fracture. Strong disturbance was found in the surrounding vascular system at this time. Inside of the diaphysis, callus formation was restricted the end of the fracture, where lamellar calluses fused together. Changes in vascular system remained until 56 days after bone fracture. Vascular distribution was most dense 28 days after bone fracture. In many of the calluses which have established fusion, findings suggested excessive calcification in the trabeculae. Vascular distribution at this time was sparse, vascular formation was markedly suppressed in the bone marrow, and very little vascular formation was found in the fractured edges of the bone.

Calcium manganese oxides as oxygen evolution catalysts: O2 formation pathways indicated by 18O-labelling studies.

Science.gov (United States)

Shevela, Dmitriy; Koroidov, Sergey; Najafpour, M Mahdi; Messinger, Johannes; Kurz, Philipp

2011-05-02

Oxygen evolution catalysed by calcium manganese and manganese-only oxides was studied in (18)O-enriched water. Using membrane-inlet mass spectrometry, we monitored the formation of the different O(2) isotopologues (16)O(2), (16)O(18)O and (18)O(2) in such reactions simultaneously with good time resolution. From the analysis of the data, we conclude that entirely different pathways of dioxygen formation catalysis exist for reactions involving hydrogen peroxide (H(2)O(2)), hydrogen persulfate (HSO(5)(-)) or single-electron oxidants such as Ce(IV) and [Ru(III) (bipy)(3)](3+) . Like the studied oxide catalysts, the active sites of manganese catalase and the oxygen-evolving complex (OEC) of photosystem II (PSII) consist of μ-oxido manganese or μ-oxido calcium manganese sites. The studied processes show very similar (18)O-labelling behaviour to the natural enzymes and are therefore interesting model systems for in vivo oxygen formation by manganese metalloenzymes such as PSII. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Cluster ion formation during sputtering processes: a complementary investigation by ToF-SIMS and plasma ion mass spectrometry

International Nuclear Information System (INIS)

Welzel, T; Ellmer, K; Mändl, S

2014-01-01

Plasma ion mass spectrometry using a plasma process monitor (PPM) and time-of-flight secondary ion mass spectrometry (ToF-SIMS) have been complementarily employed to investigate the sputtering and ion formation processes of Al-doped zinc oxide. By comparing the mass spectra, insights on ion formation and relative cross-sections have been obtained: positive ions as measured during magnetron sputtering by PPM are originating from the plasma while those in SIMS start at the surface leading to large differences in the mass spectra. In contrast, negative ions originating at the surface will be accelerated through the plasma sheath. They arrive at the PPM after traversing the plasma nearly collisionless as seen from the rather similar spectra. Hence, it is possible to combine the high mass resolution of ToF-SIMS to obtain insight for separating cluster ions, e.g. Zn x and ZnO y , and the energy resolution of PPM to find fragmentation patterns for negative ions. While the ion formation processes during both experiments can be assumed to be similar, differences may arise due to the lower volume probed by SIMS. In the latter case, there is a chance of small target inhomogeneities being able to be enhanced and lower surface temperatures leading to less outgassing and, thus, retention of volatile compounds. (paper)

Analysis on the Word-formation of English Netspeak Neologism

Directory of Open Access Journals (Sweden)

Wei Liu

2014-12-01

Full Text Available The emergence of computer-mediated communication provides a resourceful database for language researchers as well as learners. This study focuses on the Internet neologisms, a derivative of new media age, which in many ways affects the netizens in terms of communication. The collected data are examined empirically to figure out the characteristics of netspeak neologisms and their patterns of formation. It suggests that the most frequently occurring word-formation process of netspeak neologisms is compounding, subsequently, blending, affixation, old words with new meaning, acronyms, conversion, and clipping. Through probing into each process, the examples are illustrated and sub-categories are listed in terms of blending for further understanding. This study has proven that the diversity of word-formation processes of English netspeak neologism and may shed light on the creativity of language in the online context.

Modeling biological gradient formation: combining partial differential equations and Petri nets.

Science.gov (United States)

Bertens, Laura M F; Kleijn, Jetty; Hille, Sander C; Heiner, Monika; Koutny, Maciej; Verbeek, Fons J

2016-01-01

Both Petri nets and differential equations are important modeling tools for biological processes. In this paper we demonstrate how these two modeling techniques can be combined to describe biological gradient formation. Parameters derived from partial differential equation describing the process of gradient formation are incorporated in an abstract Petri net model. The quantitative aspects of the resulting model are validated through a case study of gradient formation in the fruit fly.

Ancient Martian aeolian processes and palaeomorphology reconstructed from the Stimson formation on the lower slope of Aeolis Mons, Gale crater, Mars

Science.gov (United States)

Banham, Steve G.; Gupta, Sanjeev; Rubin, David M.; Watkins, Jessica A.; Sumner, Dawn Y.; Edgett, Kenneth S.; Grotzinger, John P.; Lewis, Kevin W.; Edgar, Lauren; Stack, Kathryn M.; Barnes, Robert; Bell, Jame F. III; Day, Mackenzie D.; Ewing, Ryan C.; Lapotre, Mathieu G.A.; Stein, Nathan T.; Rivera-Hernandez, Frances; Vasavada, Ashwin R.

2018-01-01

Reconstruction of the palaeoenvironmental context of Martian sedimentary rocks is central to studies of ancient Martian habitability and regional palaeoclimate history. This paper reports the analysis of a distinct aeolian deposit preserved in Gale crater, Mars, and evaluates its palaeomorphology, the processes responsible for its deposition, and its implications for Gale crater geological history and regional palaeoclimate. Whilst exploring the sedimentary succession cropping out on the northern flank of Aeolis Mons, Gale crater, the Mars Science Laboratory rover Curiosity encountered a decametre‐thick sandstone succession, named the Stimson formation, unconformably overlying lacustrine deposits of the Murray formation. The sandstone contains sand grains characterized by high roundness and sphericity, and cross‐bedding on the order of 1 m in thickness, separated by sub‐horizontal bounding surfaces traceable for tens of metres across outcrops. The cross‐beds are composed of uniform thickness cross‐laminations interpreted as wind‐ripple strata. Cross‐sets are separated by sub‐horizontal bounding surfaces traceable for tens of metres across outcrops that are interpreted as dune migration surfaces. Grain characteristics and presence of wind‐ripple strata indicate deposition of the Stimson formation by aeolian processes. The absence of features characteristic of damp or wet aeolian sediment accumulation indicate deposition in a dry aeolian system. Reconstruction of the palaeogeomorphology suggests that the Stimson dune field was composed largely of simple sinuous crescentic dunes with a height of ca10 m, and wavelengths of ca 150 m, with local development of complex dunes. Analysis of cross‐strata dip‐azimuths indicates that the general dune migration direction and hence net sediment transport was towards the north‐east. The juxtaposition of a dry aeolian system unconformably above the lacustrine Murray formation represents starkly

Effect of low molecular fraction of thymus humoral factor on blood formation processes of irradiated mice

International Nuclear Information System (INIS)

Stolyarova, T.V.; Skobel'tsyna, E.S.; Grinberg, S.M.; Kruglikov, I.L.; Korotaev, G.K.; Tepelina, O.M.; Il'ina, T.I.

1982-01-01

The effect of low-molecular fraction of thymus humoral factor on blood formation in mice irradiated at 4 Gy was studied. It is shown that injection of low-molecular fraction of thymus hymoral factor to irradiated animals affects proliferative processes in spleen and bone marrow, however the degree of the effect depends on the injection scheme of the preparation. Application of mathematical planning methods of the experiment enables to analyze various injection schemes of low-molecular fraction of thymus humoral factor on the investigated indices. The optimal scheme of preparation injection is determined: 1st injection with the dose of 10 mkg/kg following 4 hour after irradiation, 2d injection - with the same dose in 7-21 days

Study of spin-polaron formation in 1D systems

International Nuclear Information System (INIS)

Arredondo, Y.; Navarro, O.; Vallejo, E.

2014-01-01

We study numerically the formation of spin-polarons in low-dimensional systems. We consider a ferromagnetic Kondo lattice model with Hund coupling J H and localized spins interacting antiferromagnetically with coupling constant J. We investigate the ground state phase diagram as a function of the exchange couplings J H and J and as a function of the band filling, since it has been observed that doping either on the ferromagnetic or antiferromagnetic regime lead to formation of magnetic domains [1]. We explore the quasi-particle formation and phase separation using the density-matrix renormalization group method, which is a highly efficient method to investigate quasi-one-dimensional strongly correlated systems

Experimental studies of radioactive new formations of object 'Shelter'

International Nuclear Information System (INIS)

Vishnevskij, A.S.; Kuz'mina, I.E.; Tkach, V.N.; Tokarevskij, V.V.

1996-01-01

Chemical and phase composition of radioactive new-formations of object 'Shelter ' have been experimentally studied by the X-ray and local electronic probe methods of the substance analysis. Leaching of uranium is shown to be a result of attack by alkali-carbonate solutions, migration of uranium take place in the form of double alkali-carbonate system Na 4 [U O 2 (CO 3 ) 3 ]. Carbonates, sulphates, halite and probably sulphates-carbonates were found in the mineral association of new-formations. A hypothesis of formation of sodium uranyltetracarbonate Na 6 (U O 2 )(CO 3 ) 4 , under conditions of object 'Shelter' which was not described in scientific literature before has been advanced

Formative assessment in teacher talk during lesson studies

NARCIS (Netherlands)

van Halem, Nicolette; Goei, Sui Lin; Akkerman, Sanne F.

2016-01-01

Purpose: The purpose of this paper is to evaluate the extent of systematic examination of students’ educational (support) needs by teachers participating in lesson study (LS) meetings within a framework of formative assessment (FA). Design/methodology/approach: The study took place in the context of

Scaling studies of spheromak formation and equilibrium

International Nuclear Information System (INIS)

Geddes, C.G.; Kornack, T.W.; Brown, M.R.

1998-01-01

Formation and equilibrium studies have been performed on the Swarthmore Spheromak Experiment (SSX). Spheromaks are formed with a magnetized coaxial plasma gun and equilibrium is established in both small (d small =0.16 m) and large (d large =3d small =0.50 m) copper flux conservers. Using magnetic probe arrays it has been verified that spheromak formation is governed solely by gun physics (in particular the ratio of gun current to flux, μ 0 I gun /Φ gun ) and is independent of the flux conserver dimensions. It has also been verified that equilibrium is well described by the force free condition ∇xB=λB (λ=constant), particularly early in decay. Departures from the force-free state are due to current profile effects described by a quadratic function λ=λ(ψ). Force-free SSX spheromaks will be merged to study magnetic reconnection in simple magnetofluid structures. copyright 1998 American Institute of Physics

Evaluating the influence of process parameters on soluble microbial products formation using response surface methodology coupled with grey relational analysis.

Science.gov (United States)

Xu, Juan; Sheng, Guo-Ping; Luo, Hong-Wei; Fang, Fang; Li, Wen-Wei; Zeng, Raymond J; Tong, Zhong-Hua; Yu, Han-Qing

2011-01-01