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Sample records for flow injection solid

  1. FLOW DYNAMICS OF GAS-SOLID FLUIDIZED BEDS WITH EVAPORATIVE LIQUID INJECTION

    Institute of Scientific and Technical Information of China (English)

    Bing Du; W. Warsito; Liang-Shih Fan

    2006-01-01

    The electrical capacitance tomography (ECT) with neural network multi-criteria image reconstruction technique (NN-MOIRT) is developed for real time imaging of a gas-solid fluidized bed using FCC particles with evaporative liquid injection. Some aspects of the fundamental characteristics of the gas-solid flow with evaporative liquid injection,including real time and time averaged cross-sectional solids concentration distributions, the cross-sectional solids concentration fluctuations and the quasi-3D flow structures are studied. A two-region model and a direct image calculation are proposed to describe the dynamic behavior in both the bubble/void phase and the emulsion phase based on the tomographic images. Comparisons are made between the fundamental behaviors of the gas-solid flows with and without evaporative liquid injection for various gas velocities ranging from bubbling to turbulent fiuidization regimes. Significant differences are observed in the behavior of the gas-solid flow with the evaporative liquid injection compared to the fluidized bed without liquid injection.

  2. THE STUDY OF INTERACTION OF SOLID-LIQUID ADSORPTION SYSTEM BY USING THE FLOW INJECTION-SPECTROPHOTOMETRY SYSTEM

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    The flow injection analysis was firstly used for studying a solid-liquid adsorption system,and the dynamics process in the adsorption of dyestuff with regenerable chitin was traced by an online method of flow injection-spectrophotometry. Experimental results indicate that there is a linearization between the tested signals and the height of peaks with reciprocity coefficient 0.9999by using the flow injection-spectrophotometry system to study the dynamics adsorption process in solid-liquid system. The method shows a good stability and reproducibility. It provides a new method for the studies on adsorption dynamics in solid- liquid system.

  3. "Reagentless" flow injection determination of ammonia and urea using membrane separation and solid phase basification

    Science.gov (United States)

    Akse, J. R.; Thompson, J. O.; Sauer, R. L.; Atwater, J. E.

    1998-01-01

    Flow injection analysis instrumentation and methodology for the determination of ammonia and ammonium ions in an aqueous solution are described. Using in-line solid phase basification beds containing crystalline media. the speciation of ammoniacal nitrogen is shifted toward the un-ionized form. which diffuses in the gas phase across a hydrophobic microporous hollow fiber membrane into a pure-water-containing analytical stream. The two streams flow in a countercurrent configuration on opposite sides of the membrane. The neutral pH of the analytical stream promotes the formation of ammonium cations, which are detected using specific conductance. The methodology provides a lower limit of detection of 10 microgram/L and a dynamic concentration range spanning three orders of magnitude using a 315-microliters sample injection volume. Using immobilized urease to enzymatically promote the hydrolysis of urea to produce ammonia and carbon dioxide, the technique has been extended to the determination of urea.

  4. Determination of resveratrol in red wine by solid phase extraction-flow injection chemiluminescence method

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    A sensitive flow injection chemiluminescence method has been developed for the detection of resveratrol in red wine based on the fact that resveratrol can greatly enhance chemiluminescence reaction between KMnO4 and HCHO in sulfuric acid medium.Analytes were pre-concentrated on solid sorbents (C18 solid-phase extraction cartridges). Under the optimum conditions, the proposed method allows the measurement of resveratrol over the range of 1.32 × 10-s to 1.32 × 10-5 mol/L with a detection limit of 3.30 × 10-9 mol/L, and the relative standard deviation for 1.32 × 10-5 mol/L resveratrol (n = 11 ) is 3.8%. This method has been successfully applied for the determination of the resveratrol in red wine. Furthermore, the possible reaction mechanism was also discussed.

  5. Evaluation of Antibacterial Enrofloxacin in Eggs by Matrix Solid Phase Dispersion-Flow Injection Chemiluminescence

    Directory of Open Access Journals (Sweden)

    Xiaocui Duan

    2014-01-01

    Full Text Available The study based on the chemiluminescence (CL reaction of potassium ferricyanide and luminol in sodium hydroxide medium, enrofloxacin (ENRO could dramatically enhance CL intensities and incorporated with matrix solid-phase dispersion (MSPD technique (Florisil used as dispersant, dichloromethane eluted the target compounds. A simple flow injection chemiluminescence (FL-CL method with MSPD technique for determination of ENRO in eggs was described. Under optimal conditions, the CL intensities were linearly related to ENRO concentration ranging from 4.0×10-8 g.L−1 to 5.0×10-5 g.L−1, with a correlation coefficient of 0.9989 and detection limit of 5.0×10-9 g.L−1. The relative standard deviation was 3.6% at an ENRO concentration of 2.0×10-6 g.L−1. Our testing technique can help ensure food safety, and thus, protect public health.

  6. Determination of formaldehyde in Brazilian alcohol fuels by flow-injection solid phase spectrophotometry

    Energy Technology Data Exchange (ETDEWEB)

    Teixeira, Leonardo S.G.; Leao, Elsimar S.; Dantas, Alailson F.; Pinheiro, Heloisa L.C.; Costa, Antonio C.S.; De Andrade, Jailson B. [Instituto de Quimica-Universidade Federal da Bahia, Campus Universitario de Ondina, 40.170-280-Salvador, Bahia (Brazil)

    2004-10-20

    In this work, a solid phase spectrophotometric method in association with flow injection analysis for formaldehyde determination has been developed with direct measurement of light-absorption in C{sub 18} material. The 3,5-diacetyl-1,4-dihydrolutidine produced from the reaction between formaldehyde and fluoral P was quantitatively retained on C{sub 18} support and the spectrophotometric detection was performed simultaneously at 412nm. The retained complex was quickly eluted from C{sub 18} material with the eluent stream consisting of a 50% (v/v) ethanol solution. The results showed that the proposed method is simple, rapid and the analytical response is linear in the concentration range of 0.050-1.5mgL{sup -1}. The limit of detection was estimated as 30{mu}mgL{sup -1} and the R.S.D. 2.2% using a sample volume of 625{mu}mL. The system presented an analytical throughput of 20 determinations per hour. The method was successfully applied in the determination of formaldehyde in ethanol fuel.

  7. Determination of formaldehyde in Brazilian alcohol fuels by flow-injection solid phase spectrophotometry.

    Science.gov (United States)

    Teixeira, Leonardo S G; Leão, Elsimar S; Dantas, Alaílson F; Pinheiro, Heloísa L C; Costa, Antonio C S; de Andrade, Jailson B

    2004-10-20

    In this work, a solid phase spectrophotometric method in association with flow injection analysis for formaldehyde determination has been developed with direct measurement of light-absorption in C(18) material. The 3,5-diacetyl-1,4-dihydrolutidine produced from the reaction between formaldehyde and fluoral P was quantitatively retained on C(18) support and the spectrophotometric detection was performed simultaneously at 412nm. The retained complex was quickly eluted from C(18) material with the eluent stream consisting of a 50% (v/v) ethanol solution. The results showed that the proposed method is simple, rapid and the analytical response is linear in the concentration range of 0.050-1.5mgL(-1). The limit of detection was estimated as 30mugL(-1) and the R.S.D. 2.2% using a sample volume of 625muL. The system presented an analytical throughput of 20 determinations per hour. The method was successfully applied in the determination of formaldehyde in ethanol fuel.

  8. Determination of formaldehyde in Brazilian alcohol fuels by flow-injection solid phase spectrophotometry

    OpenAIRE

    Teixeira, Leonardo Sena Gomes; Leão, Elsimar S.; Dantas,Alailson Falcão; Pinheiro, Heloísa Lúcia C.; Costa, Antonio Celso Spinola; Andrade,Jailson Bittencourt de

    2004-01-01

    p. 711–715 In thiswork, a solid phase spectrophotometric method in association with flowinjection analysis for formaldehyde determination has been developed with direct measurement of light-absorption in C18 material. The 3,5-diacetyl-1,4-dihydrolutidine produced from the reaction between formaldehyde and fluoral P was quantitatively retained on C18 support and the spectrophotometric detection was performed simultaneously at 412 nm. The retained complex was quickly eluted from C18 mater...

  9. Flow injection on-line solid phase extraction for ultra-trace lead screening with hydride generation atomic fluorescence spectrometry.

    Science.gov (United States)

    Wan, Zhuo; Xu, Zhangrun; Wang, Jianhua

    2006-01-01

    A flow injection (FI) on-line solid phase extraction (SPE) procedure for ultra-trace lead separation and preconcentration was developed, followed by hydride generation and atomic fluorescence spectrometric (AFS) detection. Lead is retained on an iminodiacetate chelating resin packed microcolumn, and is afterward eluted with 2.5% (v/v) hydrochloric acid to facilitate the hydride generation by reaction with alkaline tetrahydroborate solution with 1% (m/v) potassium ferricyanide as an oxidizing (or sensitizing) reagent. The hydride was separated from the reaction medium in the gas-liquid separator and swept into the atomizer for quantification. The chemical variables and the FI flow parameters were carefully optimized. With a sample loading volume of 4.8 ml, quantitative retention of lead was obtained, along with an enrichment factor of 11.3 and a sampling frequency of 50 h(-1). A detection limit of 4 ng l(-1), defined as 3 times the blank standard deviation (3 sigma), was achieved along with a RSD value of 1.6% at the 0.4 microg l(-1) level. The procedure was validated by determining lead contents in two certified reference materials, and its practical applicability was further demonstrated by analysing a variety of biological and environmental samples.

  10. Flow Injection Analysis

    DEFF Research Database (Denmark)

    Hansen, Elo Harald

    2004-01-01

    This chapter provides an introduction to automated chemical analysis, which essentially can be divided into two groups: batch assays, where the solution is stationary while the container is moved through a number of stations where various unit operations performed; and continuous-flow procedures,......, but it permits thr execution of novel and unique analytical procedures which are difficult or even impossible by conventional means. The performance and applicability of FIA, SI and LOV are illustrated by a series of practical examples.......This chapter provides an introduction to automated chemical analysis, which essentially can be divided into two groups: batch assays, where the solution is stationary while the container is moved through a number of stations where various unit operations performed; and continuous-flow procedures......, where the system is stationary while the solution moves through a set of conduits in which all required manipulations are performed. Emphasis is placed on flow injection analysis (FIA) and its further developments, that is, sequential injection analysis (SIA) and the Lab-on-Valve (LOV) approach. Since...

  11. A flow injection system for the spectrophotometric determination of lead after preconcentration by solid phase extraction onto Amberlite XAD-4

    Directory of Open Access Journals (Sweden)

    Jintana Klamtet

    2008-07-01

    Full Text Available An on-line flow injection analysis (FIA system for determination of lead (II in water samples with a preconcentration step and spectrophotometric detection was investigated. The system is based on preconcentration of lead (II on a column packed with Amberlite XAD-4 resin and detection by means of 4-(2-pyridylazoresorcinol (PAR–lead complex formation with maximum absorption at 523 nm. Chemical and FIA variables influencing performance of the system were optimised. Two linear calibration curves with a range of 0.01 - 0.40 and 0.40 – 0.80 mg L-1 were obtained. The developed system allowed a throughput rate of 16 samples h-1 with a 9-fold enrichment factor and a detection limit of 7 µg L-1. Relative standard deviation for 10 replicated injections of 0.25 mg L-1 was 2.3%. Recoveries of the method were in the range of 80-94 %. The procedure was validated by analysis of lead (II in real water samples, and the results were statistically compared with those obtained by flame atomic absorption spectrophotometry (FAAS. The results obtained both by the proposed method and by FAAS were in good agreement.

  12. Flow Injection Analysis

    DEFF Research Database (Denmark)

    Hansen, Elo Harald

    1998-01-01

    Learning objectives:* To provide an introduction to automated assays* To describe the basic principles of FIA * To demonstrate the capabilities of FIA in relation to batch assays and conventional continuous flow systems* To show that FIA allows one to augment existing analytical techniques* To sh...

  13. Fluidized-Solid-Fuel Injection Process

    Science.gov (United States)

    Taylor, William

    1992-01-01

    Report proposes development of rocket engines burning small grains of solid fuel entrained in gas streams. Main technical discussion in report divided into three parts: established fluidization technology; variety of rockets and rocket engines used by nations around the world; and rocket-engine equation. Discusses significance of specific impulse and ratio between initial and final masses of rocket. Concludes by stating three important reasons to proceed with new development: proposed engines safer; fluidized-solid-fuel injection process increases variety of solid-fuel formulations used; and development of fluidized-solid-fuel injection process provides base of engineering knowledge.

  14. Solid Organic Deposition During Gas Injection Studies

    DEFF Research Database (Denmark)

    Dandekar, Abhijit Y.; Andersen, Simon Ivar; Stenby, Erling Halfdan

    2000-01-01

    Recently a series of first contact miscibility (swelling) experiments have been performed on undersaturated light and heavy oils using LPG rich and methane rich injection gases, in which solid organic deposition was observed. A compositional gradient in the oils during the gas injection process w...

  15. On-line dynamic fractionation and automatic determination of inorganic phosphorous in environmental solid substrates exploiting sequential injection microcolumn extraction and flow injection analysi

    DEFF Research Database (Denmark)

    Buanuam, Janya; Miró, Manuel; Hansen, Elo Harald

    2006-01-01

    -up was assembled with no need for either manifold re-configuration or modification of chemical composition of reagents. The mobilization of trace elements, such as Cd, often present in grazed pastures as a result of the application of phosphate fertilizers, was also explored in the HL fractions by electrothermal...... associations for phosphorus, that is, exchangeable, Al- and Fe-bound and Ca-bound fractions, were elucidated by accommodation in the flow manifold of the 3 steps of the Hietjles-Litjkema (HL) scheme involving the use of 1.0 M NH4Cl, 0.1 M NaOH and 0.5 M HCl, respectively, as sequential leaching reagents...

  16. On-line monitoring of the photocatalytic degradation of 2,4-D and dicamba using a solid-phase extraction-multisyringe flow injection system.

    Science.gov (United States)

    Chávez-Moreno, Carmín; Ferrer, Laura; Hinojosa-Reyes, Laura; Hernández-Ramírez, Aracely; Cerdà, Víctor; Guzmán-Mar, Jorge

    2013-11-15

    A fully automated on-line system for monitoring the photocatalytic degradation of herbicides was developed using multisyringe flow injection analysis (MSFIA) coupled to a solid phase extraction (SPE) unit with UV detection. The calibration curves were linear in the concentration range of 100-1000 μg L(-1) for 3,6-dichloro-2-methoxybenzoic acid (dicamba) and 500-3000 μg L(-1) for 2,4-dichlorophenoxyacetic acid (2,4-D), while the detection limits were 30 and 135 μg L(-1) for dicamba and 2,4-D, respectively. The monitoring of the photocatalytic degradation (TiO2 anatase/UV 254 nm) of these two herbicides was performed by MSFIA-SPE system using a small sample volume (2 mL) in a fully automated approach. The degradation was assessed in ultrapure and drinking water with initial concentrations of 1000 and 2000 μg L(-1) for dicamba and 2,4-D, respectively. Degradation percentages of approximately 85% were obtained for both herbicides in ultrapure water after 45 min of photocatalytic treatment. A similar degradation efficiency in drinking water was observed for 2,4-D, whereas dicamba exhibited a lower degradation percentage (75%), which could be attributed to the presence of inorganic species in this kind of water. Copyright © 2013 Elsevier Ltd. All rights reserved.

  17. On-line preconcentration and determination of tetracycline residues in milk using solid-phase extraction in conjunction with flow injection spectrophotometry

    Directory of Open Access Journals (Sweden)

    Prinya Masawat

    2008-07-01

    Full Text Available A simple, cheap and highly sensitive system with on-line preconcentration using solid-phase extraction in conjunction with flow injection spectrophotometry for the determination of tetracycline residues in milk samples is described. C18 was used as packing material in a designed minicolumn used for preconcentration of tetracyclines. Tetracycline standard or sample solutions were dissolved in a mixed buffer solution of pH 4.0 containing boric acid, citric acid and sodium phosphate, then loaded to the minicolumn for 6 min followed by elution with a solution containing methanol : mixed buffer solution (40:60 by volume of pH 6.5 The absorbance of the eluate was measured at 370 nm. The calibration graph was linear in the range of 0.20-1.00, 0.20-4.00, and 0.20-1.00 mg L-1 for tetracycline (TC, oxytetracycline (OTC, and chlortetracycline (CTC respectively. The limits of detection were 0.08, 0.10, and 0.09mg L-1 for TC, OTC, and CTC respectively. Relative standard deviations for 20 replicated determinations of 0.20, 0.40, and 0.60 mg L-1 of TC were 7.03, 7.23, and 6.55 % respectively. Per cent recoveries for four commercial types of milk: U.H.T., pasteurised, raw, and sterilised milk were in the range of 86–109 (TC, 90–109 (OTC, and 89–108 (CTC. The sample throughput was 6 h-1.

  18. Flow injection solid phase extraction electrothermal atomic absorption spectrometry for the determination of Cr(VI) by selective separation and preconcentration on a lab-made hybrid mesoporous solid microcolumn

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Manuela; Stripeikis, Jorge [Laboratorio de Analisis de Trazas, Departamento de Quimica Inorganica, Analitica y Quimica Fisica, INQUIMAE, Universidad de Buenos Aires, Pabellon 2, Ciudad Universitaria, (1428) Buenos Aires (Argentina); Tudino, Mabel [Laboratorio de Analisis de Trazas, Departamento de Quimica Inorganica, Analitica y Quimica Fisica, INQUIMAE, Universidad de Buenos Aires, Pabellon 2, Ciudad Universitaria, (1428) Buenos Aires (Argentina)], E-mail: tudino@qi.fcen.uba.ar

    2009-06-15

    A lab-made hybrid mesoporous solid was employed in a flow injection solid phase extraction electrothermal atomic absorption spectrometric (FI-SPE-ETAAS) system for the selective retention of Cr(VI). The solid was prepared by co-condensation of sodium tetraethylortosilicate and 3-aminopropyltriethoxysilane by sol-gel methodology and one-pot synthesis and characterized by Fourier transform infrared spectroscopy, X ray diffraction spectroscopy, and scanning electronic microscopy. Adsorption capacities at different pH values of both, Cr(VI) and Cr(III), were also measured in order to obtain the optimum retention for Cr(VI) with no interference of Cr(III). The maximum capacity of adsorption (4.35 mmol g{sup -} {sup 1}) was observed for pH values between 2-3, whilst Cr(III) was found to remain in solution (adsorption capacity = 0.007 mmol g{sup -} {sup 1}). Then, a microcolumn (bed volume: 7.9 {mu}L) was filled with the solid and inserted in the FI-ETAAS system for analytical purposes. Since the analyte was strongly retained by the filling in the anionic form, 0.1 mol L{sup -} {sup 1} hydroxylammonium chloride in 1 mol L{sup -} {sup 1} hydrochloric acid was selected as eluent due to its redox characteristics. In this way, the sorbed Cr(VI) was easily released in the cationic form. The enrichment factor (EF) was found as a compromise between sensitivity and sample throughput and a value of 27 was obtained under optimized conditions: pH 2, sample loading 2 mL min{sup -} {sup 1} (60 s), elution flow rate 0.5 ml min{sup -} {sup 1} (eluent volume: 75 {mu}L). Under optimized conditions the limit of detection for Cr(VI) was 1.2 ng L{sup -} {sup 1}, the precision, expressed as RSD was 2.5%, the sample throughput 21/h, and the microcolumn lifetime was over 300 adsorption/desorption cycles. Cr(III) determination was also performed by simply measuring its concentration at the end of the column and after Cr(VI) retention by the mesoporous solid. Applications of the methodology to

  19. Determination of As(III) and total inorganic As in water samples using an on-line solid phase extraction and flow injection hydride generation atomic absorption spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Sigrist, Mirna, E-mail: msigrist@fiq.unl.edu.ar [Laboratorio Central, Facultad de Ingenieria Quimica, Universidad Nacional del Litoral, Santiago del Estero 2654-Piso 6, (3000) Santa Fe (Argentina); Albertengo, Antonela; Beldomenico, Horacio [Laboratorio Central, Facultad de Ingenieria Quimica, Universidad Nacional del Litoral, Santiago del Estero 2654-Piso 6, (3000) Santa Fe (Argentina); Tudino, Mabel [Laboratorio de Analisis de Trazas, Departamento de Quimica Inorganica, Analitica y Quimica Fisica/INQUIMAE, Facultad de Ciencias Exactas y Naturales, Pabellon II, Ciudad Universitaria (1428), Buenos Aires (Argentina)

    2011-04-15

    A simple and robust on-line sequential injection system based on solid phase extraction (SPE) coupled to a flow injection hydride generation atomic absorption spectrometer (FI-HGAAS) with a heated quartz tube atomizer (QTA) was developed and optimized for the determination of As(III) in groundwater without any kind of sample pretreatment. The method was based on the selective retention of inorganic As(V) that was carried out by passing the filtered original sample through a cartridge containing a chloride-form strong anion exchanger. Thus the most toxic form, inorganic As(III), was determined fast and directly by AsH{sub 3} generation using 3.5 mol L{sup -1} HCl as carrier solution and 0.35% (m/v) NaBH{sub 4} in 0.025% NaOH as the reductant. Since the uptake of As(V) should be interfered by several anions of natural occurrence in waters, the effect of Cl{sup -}, SO{sub 4}{sup 2-}, NO{sub 3}{sup -}, HPO{sub 4}{sup 2-}, HCO{sub 3}{sup -} on retention was evaluated and discussed. The total soluble inorganic arsenic concentration was determined on aliquots of filtered samples acidified with concentrated HCl and pre-reduced with 5% KI-5% C{sub 6}H{sub 8}O{sub 6} solution. The concentration of As(V) was calculated by difference between the total soluble inorganic arsenic and As(III) concentrations. Detection limits (LODs) of 0.5 {mu}g L{sup -1} and 0.6 {mu}g L{sup -1} for As(III) and inorganic total As, respectively, were obtained for a 500 {mu}L sample volume. The obtained limits of detection allowed testing the water quality according to the national and international regulations. The analytical recovery for water samples spiked with As(III) ranged between 98% and 106%. The sampling throughput for As(III) determination was 60 samples h{sup -1}. The device for groundwater sampling was especially designed for the authors. Metallic components were avoided and the contact between the sample and the atmospheric oxygen was carried to a minimum. On-field arsenic species

  20. Preliminary results on the determination of ultratrace amounts of cadmium in tea samples using a flow injection on-line solid phase extraction separation and preconcentration technique to couple with a sequential injection hydride generation atomic fluorescence spectrometry.

    Science.gov (United States)

    Duan, Taicheng; Song, Xuejie; Jin, Dan; Li, Hongfei; Xu, Jingwei; Chen, Hangting

    2005-10-31

    In this work, a method was developed for determination of ultra-trace levels of Cd in tea samples by atomic fluorescence spectrometry (AFS). A flow injection solid phase extraction (FI-SPE) separation and preconcentration technique, to on-line couple with a sequential injection hydride generation (SI-HG) technique is employed in this study. Cd was preconcentrated on the SPE column, which was made from a neutral extractant named Cyanex 923, while other matrix ions or interfering ions were completely or mostly separated off. Conditions for the SPE separation and preconcentration, as well as conditions for the HG technique, were studied. Due to the separation of interfering elements, Cd hydride generation efficiency could be greatly enhanced with the sole presence of Co(2+) with a concentration of 200mugL(-1), which is much lower than those in other works previously reported. Interferences on both the Cd separation and preconcentration, and Cd hydride generation (HG) were investigated; it showed that both the separation and preconcentration system, and the HG system had a strong anti-interference ability. The SPE column could be repeatedly used at least 400 times, a R.S.D. of 0.97% was obtained for 6 measurements of Cd with 0.2mugL(-1) and a correlation coefficiency of 1.0000 was obtained for the measurement of a series of solutions with Cd concentrations from 0.1 to 2mugL(-1). The method has a low detection limit of 10.8ngL(-1) for a 25mL solution and was successfully validated by using two tea standard reference materials (GBW08513 and GBW07605).

  1. Recent advances in flow injection analysis.

    Science.gov (United States)

    Trojanowicz, Marek; Kołacińska, Kamila

    2016-04-07

    A dynamic development of methodologies of analytical flow injection measurements during four decades since their invention has reinforced the solid position of flow analysis in the arsenal of techniques and instrumentation of contemporary chemical analysis. With the number of published scientific papers exceeding 20,000, and advanced instrumentation available for environmental, food, and pharmaceutical analysis, flow analysis is well established as an extremely vital field of modern flow chemistry, which is developed simultaneously with methods of chemical synthesis carried out under flow conditions. This review work is based on almost 300 original papers published mostly in the last decade, with special emphasis put on presenting novel achievements from the most recent 2-3 years in order to indicate current development trends of this methodology. Besides the evolution of the design of whole measuring systems, and including especially new applications of various detections methods, several aspects of implications of progress in nanotechnology, and miniaturization of measuring systems for application in different field of modern chemical analysis are also discussed.

  2. Flow-injection spectrophotometric determination of captopril in pharmaceutical formulations using a new solid-phase reactor containing AgSCN immobilized in a polyurethane resin

    Directory of Open Access Journals (Sweden)

    Fernando Campanhã Vicentini

    2012-06-01

    Full Text Available A simple flow-injection analysis procedure was developed for determining captopril in pharmaceutical formulations employing a novel solid-phase reactor containing silver thiocyanate immobilized in a castor oil derivative polyurethane resin. The method was based on silver mercaptide formation between the captopril and Ag(I in the solid-phase reactor. During such a reaction, the SCN- anion was released and reacted with Fe3+, which generated the FeSCN2+ complex that was continuously monitored at 480 nm. The analytical curve was linear in the captopril concentration range from 3.0 × 10-4 mol L-1 to 1.1 × 10-3 mol L-1 with a detection limit of 8.0 × 10-5 mol L-1. Recoveries between 97.5% and 103% and a relative standard deviation of 2% for a solution containing 6.0 × 10-4 mol L-1 captopril (n = 12 were obtained. The sample throughput was 40 h-1 and the results obtained for captopril in pharmaceutical formulations using this procedure and those obtained using a pharmacopoeia procedure were in agreement at a 95% confidence level.Um procedimento simples de análise por injeção em fluxo foi desenvolvido para a determinação de captopril em formulações farmacêuticas empregando um novo reator em fase sólida contendo tiocianato de prata imobilizado em resina poliuretana obtida a partir de óleo de mamona. O método foi baseado na formação de um mercapto composto de prata, no reator em fase sólida, obtido entre o captopril e Ag (I imobilizada. Durante a reação, íons SCN- eram liberados e reagiam com Fe3+, gerando o complexo FeSCN2+, que foi continuamente monitorado em 480 nm. A curva analítica foi linear no intervalo de concentração de captopril entre 3,0 × 10-4 a 1,1 × 10-3 mol L-1 com um limite de detecção de 8,0 × 10-5 mol L-1. Recuperações entre 97,5-103% e desvio padrão relativo de 2% para uma solução contendo 6,0 × 10-4 mol L-1 de captopril (n = 12 foram obtidos. A frequência de amostragem foi de 40 h-1 e os resultados

  3. Flow Simulation of Solid Rocket Motors. 2; Sub-Scale Air Flow Simulation of Port Flows

    Science.gov (United States)

    Yeh, Y. P.; Ramandran, N.; Smith, A. W.; Heaman, J. P.

    2000-01-01

    The injection-flow issuing from a porous medium in the cold-flow simulation of internal port flows in solid rocket motors is characterized by a spatial instability termed pseudoturbulence that produces a rather non-uniform (lumpy) injection-velocity profile. The objective of this study is to investigate the interaction between the injection- and the developing axial-flows. The findings show that this interaction generally weakens the lumpy injection profile and affects the subsequent development of the axial flow. The injection profile is found to depend on the material characteristics, and the ensuing pseudoturbulence is a function of the injection velocity, the axial position and the distance from the porous wall. The flow transition (from laminar to turbulent) of the axial-flow is accelerated in flows emerging from smaller pores primarily due to the higher pseudoturbulence produced by the smaller pores in comparison to that associated with larger pores. In flows with rather uniform injection-flow profiles (weak or no pseudoturbulence), the axial and transverse velocity components in the porous duct are found to satisfy the sine/cosine analytical solutions derived from inviscid assumptions. The transition results from the present study are compared with previous results from surveyed literature, and detailed flow development measurements are presented in terms of the blowing fraction, and characterizing Reynolds numbers.

  4. The Three Generations of Flow Injection Analysis

    DEFF Research Database (Denmark)

    Hansen, Elo Harald; Wang, Jianhua

    2004-01-01

    The characteristics of the three generations of flow injection analysis, that is, FIA, sequential injection analysis (SIA), and bead injection-lab-on-valve (BI-LOV), are briefly outlined, their individual advantages and shortcomings are discussed, and selected practical applications are presented....

  5. Wet solids flow enhancemant

    Energy Technology Data Exchange (ETDEWEB)

    Caram, H.S.; Foster, N.; Wildman, D.J. [USDOE Pittsburgh Energy Technology Center, PA (United States)

    1996-12-31

    WE used glass beads of different sizes as.a model system to study the flow enhancing properties of Octadecyltrichlorosilane (OTS). 0TS provides Si(CH{sub 2}){sub 17}CH{sub 3} groups that bind with the surface hydrox groups to make it hydrophobic. Experimental data showed, indeed, that surface hydrophobicity promotes the flow of wet granular materials. Mixtures of different percentage of silanized/unsilanized particles were prepared for tensile strength measurements. The tensile strength decreased as more silanized particles were added to the samples. The relationship between dimensionless tensile strength and void fraction followed the correlation found by Pierrat (1994). Contact angles were larger for the silanized particles, as compared with unsilanized ones.

  6. Flow Injection Analysis in Industrial Biotechnology

    DEFF Research Database (Denmark)

    Hansen, Elo Harald; Miró, Manuel

    2009-01-01

    Flow injection analysis (FIA) is an analytical chemical continuous-flow (CF) method which in contrast to traditional CF-procedures does not rely on complete physical mixing (homogenisation) of the sample and the reagent(s) or on attaining chemical equilibria of the chemical reactions involved. Ex...

  7. Evaluation of the impact of viscosity, injection volume, and injection flow rate on subcutaneous injection tolerance

    Directory of Open Access Journals (Sweden)

    Berteau C

    2015-11-01

    Full Text Available Cecile Berteau,1 Orchidée Filipe-Santos,1 Tao Wang,2 Humberto E Rojas,2 Corinne Granger,1 Florence Schwarzenbach1 1Becton-Dickinson Medical Pharmaceutical Systems, Le Pont de Claix, France; 2Eli Lilly and Company, Indianapolis, IN, USA Aim: The primary objective of this study was to evaluate the impact of fluid injection viscosity in combination with different injection volumes and flow rates on subcutaneous (SC injection pain tolerance. Methods: The study was a single-center, comparative, randomized, crossover, Phase I study in 24 healthy adults. Each participant received six injections in the abdomen area of either a 2 or 3 mL placebo solution, with three different fluid viscosities (1, 8–10, and 15–20 cP combined with two different injection flow rates (0.02 and 0.3 mL/s. All injections were performed with 50 mL syringes and 27G, 6 mm needles. Perceived injection pain was assessed using a 100 mm visual analog scale (VAS (0 mm/no pain, 100 mm/extreme pain. The location and depth of the injected fluid was assessed through 2D ultrasound echography images. Results: Viscosity levels had significant impact on perceived injection pain (P=0.0003. Specifically, less pain was associated with high viscosity (VAS =12.6 mm than medium (VAS =16.6 mm or low (VAS =22.1 mm viscosities, with a significant difference between high and low viscosities (P=0.0002. Target injection volume of 2 or 3 mL was demonstrated to have no significant impact on perceived injection pain (P=0.89. Slow (0.02 mL/s or fast (0.30 mL/s injection rates also showed no significant impact on perceived pain during SC injection (P=0.79. In 92% of injections, the injected fluid was located exclusively in SC tissue whereas the remaining injected fluids were found located in SC and/or intradermal layers. Conclusion: The results of this study suggest that solutions of up to 3 mL and up to 15–20 cP injected into the abdomen within 10 seconds are well tolerated without pain. High

  8. Flow Injection will be 25 years

    DEFF Research Database (Denmark)

    Hansen, Elo Harald

    1999-01-01

    The article is a brief review of the first 25 years of Flow Injection Analysis (FIA), that is, from its conception and early development in the mid-70'es at the Department of Chemistry at DTU, yet it is particularly discussing why this analytical concept has had the impact that the ensuing 10...

  9. Evaluation of the impact of viscosity, injection volume, and injection flow rate on subcutaneous injection tolerance.

    Science.gov (United States)

    Berteau, Cecile; Filipe-Santos, Orchidée; Wang, Tao; Rojas, Humberto E; Granger, Corinne; Schwarzenbach, Florence

    2015-01-01

    The primary objective of this study was to evaluate the impact of fluid injection viscosity in combination with different injection volumes and flow rates on subcutaneous (SC) injection pain tolerance. The study was a single-center, comparative, randomized, crossover, Phase I study in 24 healthy adults. Each participant received six injections in the abdomen area of either a 2 or 3 mL placebo solution, with three different fluid viscosities (1, 8-10, and 15-20 cP) combined with two different injection flow rates (0.02 and 0.3 mL/s). All injections were performed with 50 mL syringes and 27G, 6 mm needles. Perceived injection pain was assessed using a 100 mm visual analog scale (VAS) (0 mm/no pain, 100 mm/extreme pain). The location and depth of the injected fluid was assessed through 2D ultrasound echography images. Viscosity levels had significant impact on perceived injection pain (P=0.0003). Specifically, less pain was associated with high viscosity (VAS =12.6 mm) than medium (VAS =16.6 mm) or low (VAS =22.1 mm) viscosities, with a significant difference between high and low viscosities (P=0.0002). Target injection volume of 2 or 3 mL was demonstrated to have no significant impact on perceived injection pain (P=0.89). Slow (0.02 mL/s) or fast (0.30 mL/s) injection rates also showed no significant impact on perceived pain during SC injection (P=0.79). In 92% of injections, the injected fluid was located exclusively in SC tissue whereas the remaining injected fluids were found located in SC and/or intradermal layers. The results of this study suggest that solutions of up to 3 mL and up to 15-20 cP injected into the abdomen within 10 seconds are well tolerated without pain. High viscosity injections were shown to be the most tolerated, whereas injection volume and flow rates did not impact perceived pain.

  10. Determination of propoxur in environmental samples by automated solid-phase extraction followed by flow-injection analysis with tris(2,2'-bipyridyl)ruthenium(II) chemiluminescence detection

    Energy Technology Data Exchange (ETDEWEB)

    Perez-Ruiz, Tomas [Department of Analytical Chemistry, Faculty of Chemistry, University of Murcia, 30071 Murcia (Spain)]. E-mail: tpr@um.es; Martinez-Lozano, Carmen [Department of Analytical Chemistry, Faculty of Chemistry, University of Murcia, 30071 Murcia (Spain); Garcia, Maria Dolores [Department of Analytical Chemistry, Faculty of Chemistry, University of Murcia, 30071 Murcia (Spain)

    2007-02-19

    A sensitive method for the analysis of propoxur in environmental samples has been developed. It involves an automated solid-phase extraction (SPE) procedure using a Gilson Aspec XLi and flow-injection analysis (FI) with chemiluminescence (CL) detection. The FI-CL system relies on the photolysis of propoxur by irradiation using a low-pressure mercury lamp (main spectral line 254 nm). The resultant methylamine is subsequently detected by CL using tris(2,2'-bipyridyl)ruthenium(III), which is on-line generated by photo-oxidation of the ruthenium(II) complex in the presence of peroxydisulfate. The linear concentration range of application was 0.05-5 {mu}g mL{sup -1} of propoxur, with a detection limit of 5 ng mL{sup -1}. The repeatability was 0.82% expressed as relative standard deviation (n = 10) and the reproducibility, studied on 5 consecutive days, was 2.1%. The sample throughput was 160 injection per hour. Propoxur residues below ng mL{sup -1} levels could be determined in environmental water samples when an SPE preconcentration device was coupled on-line with the FI system. This SPE-FI-CL arrangement provides a detection limit as low as 5 ng L{sup -1} using only 500 mL of sample. In the analysis of fruits and vegetables, the detection limit was about 10 {mu}g kg{sup -1}.

  11. Determination of propoxur in environmental samples by automated solid-phase extraction followed by flow-injection analysis with tris(2,2'-bipyridyl)ruthenium(II) chemiluminescence detection.

    Science.gov (United States)

    Pérez-Ruiz, Tomás; Martínez-Lozano, Carmen; García, María Dolores

    2007-02-19

    A sensitive method for the analysis of propoxur in environmental samples has been developed. It involves an automated solid-phase extraction (SPE) procedure using a Gilson Aspec XLi and flow-injection analysis (FI) with chemiluminescence (CL) detection. The FI-CL system relies on the photolysis of propoxur by irradiation using a low-pressure mercury lamp (main spectral line 254 nm). The resultant methylamine is subsequently detected by CL using tris(2,2'-bipyridyl)ruthenium(III), which is on-line generated by photo-oxidation of the ruthenium(II) complex in the presence of peroxydisulfate. The linear concentration range of application was 0.05-5 microg mL(-1) of propoxur, with a detection limit of 5 ng mL(-1). The repeatability was 0.82% expressed as relative standard deviation (n=10) and the reproducibility, studied on 5 consecutive days, was 2.1%. The sample throughput was 160 injection per hour. Propoxur residues below ng mL(-1) levels could be determined in environmental water samples when an SPE preconcentration device was coupled on-line with the FI system. This SPE-FI-CL arrangement provides a detection limit as low as 5 ng L(-1) using only 500 mL of sample. In the analysis of fruits and vegetables, the detection limit was about 10 microg kg(-1).

  12. Tracer injection techniques in flowing surface water

    Science.gov (United States)

    Wörman, A.

    2009-04-01

    Residence time distributions for flowing water and reactive matter are commonly used integrated properties of the transport process for determining technical issues of water resource management and in eco-hydrological science. Two general issues for tracer techniques are that the concentration-vs-time relation following a tracer injection (the breakthrough curve) gives unique transport information in different parts of the curve and separation of hydromechanical and reactive mechanisms often require simultaneous tracer injections. This presentation discusses evaluation methods for simultaneous tracer injections based on examples of tracer experiments in small rivers, streams and wetlands. Tritiated water is used as a practically inert substance to reflect the actual hydrodynamics, but other involved tracers are Cr(III)-51, P-32 and N-15. Hydromechanical, in-stream dispersion is reflected as a symmetrical spreading of the spatial concentration distribution. This requires that the transport distance over water depth is larger than about five times the flow Peclet number. Transversal retention of both inert and reactive solutes is reflected in terms of the tail of the breakthrough curve. Especially, reactive solutes can have a substantial magnification of the tailing behaviour depending on reaction rates or partitioning coefficients. To accurately discriminate between the effects of reactions and hydromechanical mixing its is relevant to use simultaneous injections of inert and reactive tracers with a sequential or integrated evaluation procedure. As an example, the slope of the P-32 tailing is consistently smaller than that of a simultaneous tritium injection in Ekeby wetland, Eskilstuna. The same applies to N-15 injected in the same experiment, but nitrogen is affected also by a systematic loss due to denitrification. Uptake in stream-bed sediments can be caused by a pumping effect arising when a variable pressure field is created on the stream bottom due to bed

  13. Uncertainty contributions to the measurement of dissolved Co, Fe, Pb and V in seawater using flow injection with solid phase preconcentration and detection by collision/reaction cell-quadrupole ICP-MS.

    Science.gov (United States)

    Clough, Robert; Sela, Hagit; Milne, Angela; Lohan, Maeve C; Tokalioglu, Serife; Worsfold, Paul J

    2015-02-01

    A flow injection manifold incorporating a solid phase chelating resin (Toyopearl AF-Chelate-650) is reported for the preconcentration of dissolved metals from seawater, with a focus on investigating the effect of the loading pH, wash solution composition and wash time. Cobalt, iron, lead and vanadium have been used as target analytes with contrasting oceanographic behaviour. Quadrupole ICP-MS has been used for detection to make the approach accessible to most laboratories and a collision/reaction cell has been incorporated to minimise polyatomic interferences. Results for the seawater CRM NASS-6 and two GEOTRACES reference materials were in good agreement with the certified/consensus values, demonstrating the suitability of the approach for the determination of trace metals in seawater. The experimental design used allowed a thorough investigation of the uncertainty contribution from each method parameter to the overall expanded uncertainty of the measurement. The results showed that the parameters making the largest contributions were the precision of the peak area measurement and the uncertainty associated with the slope of the calibration curve. Therefore, these are the critical parameters that should be targeted in order to reduce the overall measurement uncertainty. For iron, the wash blank also gave a measureable contribution.

  14. Immobilized Bioluminescent Reagents in Flow Injection Analysis.

    Science.gov (United States)

    Nabi, Abdul

    Available from UMI in association with The British Library. Bioluminescent reactions exhibits two important characteristics from an analytical viewpoint; they are selective and highly sensitive. Furthermore, bioluminescent emissions are easily measured with a simple flow-through detector based on a photomultiplier tube and the rapid and reproducible mixing of sample and expensive reagent is best achieved by a flow injection manifold. The two most important bioluminescent systems are the enzyme (luciferase)/substrate (luciferin) combinations extracted from fireflies (Photinus pyralis) and marine bacteria (Virio harveyi) which requires ATP and NAD(P)H respectively as cofactors. Reactions that generate or consume these cofactors can also be coupled to the bioluminescent reaction to provide assays for a wide range of clinically important species. A flow injection manifold for the study of bioluminescent reactions is described, as are procedures for the extraction, purification and immobilization of firefly and bacterial luciferase and oxidoreductase. Results are presented for the determination of ATP using firefly system and the determination of other enzymes and substrates participating in ATP-converting reactions e.g. creatine kinase, ATP-sulphurylase, pyruvate kinase, creatine phosphate, pyrophosphate and phophoenolypyruvate. Similarly results are presented for the determination of NAD(P)H, FMN, FMNH_2 and several dehydrogenases which produce NAD(P)H and their substrates, e.g. alcohol, L-lactate, L-malate, L-glutamate, Glucose-6-phosphate and primary bile acid.

  15. A CFD study of gas-solid jet in a CFB riser flow

    Energy Technology Data Exchange (ETDEWEB)

    Li, Tingwen; Guenther, Chris

    2012-03-01

    Three-dimensional high-resolution numerical simulations of a gas–solid jet in a high-density riser flow were conducted. The impact of gas–solid injection on the riser flow hydrodynamics was investigated with respect to voidage, tracer mass fractions, and solids velocity distribution. The behaviors of a gas–solid jet in the riser crossflow were studied through the unsteady numerical simulations. Substantial separation of the jetting gas and solids in the riser crossflow was observed. Mixing of the injected gas and solids with the riser flow was investigated and backmixing of gas and solids was evaluated. In the current numerical study, both the overall hydrodynamics of riser flow and the characteristics of gas–solid jet were reasonably predicted compared with the experimental measurements made at NETL.

  16. Solid reactors in sequential injection analysis: Recent trends in the environmental field

    DEFF Research Database (Denmark)

    Miró, Manuel; Hansen, Elo Harald

    2006-01-01

    /reagent consumption. A further noteworthy feature is the inherent versatility of the flow network to implement unit operations at will with no need for manifold re-configuration. The present review discusses the potential of SI to accommodate solid reactors and packed columns in the flow set-up for environmental......-bead injection (SI-BI), used in either the jet-ring or lab-on-valve configurations, is presented as a front-end to many detectors. This article also outlines recent trends focused on exploiting SI as an automated tool for handling solid samples of environmental concern and accommodating dynamic fractionation...

  17. Determination of ribavirin by flow injection chemiluminescence

    Institute of Scientific and Technical Information of China (English)

    Juqing Jin; Yuhai Tang; Langchong He; Hong Yao; Yuanyuan Sun

    2006-01-01

    Objective: To establish a rapid and precise continuous flow-injection chemiluminescence (CL) method to determine ribavirin. Methods: The ribavirin could restrain strongly CL reaction of luminol in sodium hydroxide (NaOH) solution with potassium chlorate(KClO3). The different experimental parameters affecting the CL intensity were studied carefully. Results:Under optimum conditions(The concentrations of luminol,KClO3, and NaOH were at 0.1 mmol/L,0.5 μmol/L,and 0.2 mol/L, respectively), the linear range of the working curves was 0.01-7.00 μg/ml with a detection limit of 0.004 μg/ml. Conclusion: The method is simple, rapid and sensitive, and successfully applied to the determination of ribavirin in pharmaceutical preparations and biological fluids.

  18. On-line solid-phase enrichment coupled to packed reactor flow injection analysis in a green analytical procedure to determine low levels of folic acid using fluorescence detection

    Directory of Open Access Journals (Sweden)

    Emara Samy

    2012-12-01

    Full Text Available Abstract Background Analysis of folic acid (FA is not an easy task because of its presence in lower concentrations, its lower stability under acidic conditions, and its sensitiveness against light and high temperature. The present study is concerned with the development and validation of an automated environmentally friendly pre-column derivatization combined by solid-phase enrichment (SPEn to determine low levels of FA. Results Cerium (IV trihydroxyhydroperoxide (CTH as a packed oxidant reactor has been used for oxidative cleavage of FA into highly fluorescent product, 2-amino-4-hydroxypteridine-6-carboxylic acid. FA was injected into a carrier stream of 0.04 M phosphate buffer, pH 3.4 at a flow-rate of 0.25 mL/min. The sample zone containing the analyte was passed through the CTH reactor thermostated at 40°C, and the fluorescent product was trapped and enriched on a head of small ODS column (10 mm x 4.6 mm i.d., 5 μm particle size. The enriched product was then back-flush eluted by column-switching from the small ODS column to the detector with a greener mobile phase consisting of ethanol and phosphate buffer (0.04M, pH 3.4 in the ratio of 5:95 (v/v. The eluent was monitored fluorimetrically at emission and excitation wavelengths of 463 and 367 nm, respectively. The calibration graph was linear over concentrations of FA in the range of 1.25-50 ng/mL, with a detection limit of 0.49 ng/mL. Conclusion A new simple and sensitive green analytical procedure including on-line pre-column derivatization combined by SPEn has been developed for the routine quality control and dosage form assay of FA at very low concentration level. The method was a powerful analytical technique that had excellent sensitivity, sufficient accuracy and required relatively simple and inexpensive instrumentation.

  19. Taylor-Couette flow with radial fluid injection

    Science.gov (United States)

    Wilkinson, Nikolas; Dutcher, Cari S.

    2017-08-01

    Taylor-Couette cells have been shown to improve a number of industrial processes due to the wide variety of hydrodynamic flow states accessible. Traditional designs, however, limit the ability to introduce new fluids into the annulus during device operation due to geometric confinement and complexity. In this paper, a co- and counter-rotating Taylor-Couette cell with radial fluid injection has been constructed. The incorporation of 16 ports in the inner cylinder enables radial fluid injection during rotation of both cylinders. The design is also capable of continuous axial flow, enabling large injection volumes. The new inner cylinder design does not modify the critical Re for flow instabilities and can precisely inject a desired mass at a desired flow rate. A range of injection rates and masses were explored to quantify the effect of radial injection on the stability of the turbulent Taylor vortex structure. Only the highest injection rate and total mass studied (5.9 g/s, 100 g) modified the turbulent Taylor vortex structure after injection for a sustained period. The post-injection vortices remained larger than the pre-injection vortices, whereas at lower injection rates or masses, the vortex structure quickly returned to the pre-injection structure. This new system allows for in situ study of hydrodynamic effects on fluid-fluid (gas and liquid) mixing and multiphase complexation, growth, and structure. We demonstrated this new design's potential for studying the flocculation of bentonite using cationic polyacrylamide for enhancing water treatment operations.

  20. Measurements of solids concentration and axial solids velocity in gas-solid two-phase flows.

    NARCIS (Netherlands)

    Nieuwland, J.J.; Meijer, R.; Kuipers, J.A.M.; Swaaij, van W.P.M.

    1996-01-01

    Several techniques reported in the literature for measuring solids concentration and solids velocity in (dense) gas-solid two-phase flow have been briefly reviewed. An optical measuring system, based on detection of light reflected by the suspended particles, has been developed to measure local soli

  1. Flow acoustics in solid-fluid structures

    DEFF Research Database (Denmark)

    Willatzen, Morten; Mads, Mikhail Vladimirovich Deryabin

    2008-01-01

    along the x direction. In the first part of the paper, the governing set of differential equations are derived as well as the imposed boundary conditions. Solutions are provided using Hamilton's equations for the wavenumber vs. frequency as a function of the number and thickness of solid layers....... A wavenumber condition for an arbitrary set of consecutive solid and fluid layers, involving four propagating waves in each solid region, is obtained again using the monodromy matrix method. Case examples are finally discussed.......The governing two-dimensional equations of a heterogeneous material composed of a fluid (allowed to flow in the absence of acoustic excitations) and a crystalline piezoelectric cubic solid stacked one-dimensionally (along the z direction) are derived and special emphasis is given to the discussion...

  2. Continuous, pulsed and stopped flow in a u-flow injection system (numerical vs experimental)

    NARCIS (Netherlands)

    van Akker, E.B.; Bos, M.; van der Linden, W.E.

    1999-01-01

    The effects of continuous, pulsed and stopped flow on the dispersion of a sample injected into a μ-flow injection system were studied. A channel with a volume of 1 μl was used to compare experimental results with numerical results. The injection was 0.067 μl of bromocresolgreen solution into a borax

  3. Continuous, pulsed and stopped flow in a μ-flow injection system (numerical vs experimental)

    NARCIS (Netherlands)

    Akker, van E.B.; Bos, M.; Linden, van der W.E.

    1999-01-01

    The effects of continuous, pulsed and stopped flow on the dispersion of a sample injected into a μ-flow injection system were studied. A channel with a volume of 1 μl was used to compare experimental results with numerical results. The injection was 0.067 μl of bromocresolgreen solution into a borax

  4. Gas and liquid fuel injection into an enclosed swirling flow

    Science.gov (United States)

    Ahmad, N. T.; Andrews, G. E.

    1984-06-01

    The use of swirler air for atomization has been tested with direct central propane injection and with direct central kerosene and gas oil injection, and its results have been compared with those for nonswirling flow systems under the same conditions. Direct propane injection results in a major extension of stability limits, by comparison to results for premixing, while with liquid fuel injection the stability limits are generally worse than for premixed fuel and air. This may be due to the action of the centrifugal forces on the liquid droplets in the swirl flow, which results in outer swirl flow vaporization and weaker mixtures in the core recirculation region than would be the case for propane injection. A comparison with nonswirling system performance indicated that all emission levels were higher with swirl for propane.

  5. Tre generationer af Flow Injection Analysis

    DEFF Research Database (Denmark)

    Hansen, Elo Harald; Chomchoei, Roongrat; Long, Xiangbao

    2004-01-01

    Siden introduktionen af FIA har en række videreudviklinger resulteret i Sequential Injection Analysis (SIA) og senest i Lab-on-Valve (LOV)-metodikken. Her beskrives disse, og der gives eksempler på, hvordan metoderne kan bruges til at bestemme sporstofkoncentrationer af metaller i komplekse...

  6. Longitudinal cross sectional mixing images of the pipe flow with periodical branching flow injections

    Science.gov (United States)

    Ueda, Toshihisa; Sunho, You; Higuchi, Naotaka

    2008-11-01

    Effect of periodical injection of branching flows on the mixing in a pipe flow is experimentally investigated. Glycerin is used as a working fluid. The glycerin flows in a steady state condition in the main flow pipe while the branching flow is injected periodically from three pipes equipped normal to the main flow pipe. The longitudinal cross sectional image of the mixing of main flow and branching flows is visualized by LIF method, inserting the Rodamine B in the first branching flow. When only one branching flow is periodically injected, the fluid injected from the side flow pipe is stretched and folded by the parabolic laminar flow velocity profile and then the length of the boundary increases linearly. When branching flow is injected from multiple side flow pipe, the mixing pattern becomes more complicated. As a result, the length of the boundary increases more rapidly compared to the linear increase. The results suggest that the multiple branching flow injection enhances the mixing although no element is inserted in the pipe.

  7. Unsteady transverse injection of kerosene into a supersonic flow

    Institute of Scientific and Technical Information of China (English)

    2000-01-01

    A shadowgraph and a new fuel injection system were used to study kerosene transversely injected into a supersonic flow. High pressure and velocity of injection can be attained. The pressure time histories were detected in oil-line and the shadowgraphs of the flow field were obtained at different time-delays. The inflow stagnation pressure was varied to change the local flow speed in test section. The results indicate that kerosene jet exhibits deep penetration and four regimes appear clearly during the fuel jet atomization in a high-speed flow. The jet disintegration is caused by surface waves propagating along the jet surface, and the breakup point is located at the wave trough. The surface waves are dominantly generated by aerodynamic force. The jet shock is close to windward surface of the jet. The shock reflects on and transmits in duct boundary layers. In the case of unsteady injection, the shock structure is very complicated and different from that of hydrogen injection. The results of kerosene injected into a quiescent gas and a subsonic flow are also provided for comparison.

  8. A volumetric flow sensor for automotive injection systems

    Science.gov (United States)

    Schmid, U.; Krötz, G.; Schmitt-Landsiedel, D.

    2008-04-01

    For further optimization of the automotive power train of diesel engines, advanced combustion processes require a highly flexible injection system, provided e.g. by the common rail (CR) injection technique. In the past, the feasibility to implement injection nozzle volumetric flow sensors based on the thermo-resistive measurement principle has been demonstrated up to injection pressures of 135 MPa (1350 bar). To evaluate the transient behaviour of the system-integrated flow sensors as well as an injection amount indicator used as a reference method, hydraulic simulations on the system level are performed for a CR injection system. Experimentally determined injection timings were found to be in good agreement with calculated values, especially for the novel sensing element which is directly implemented into the hydraulic system. For the first time pressure oscillations occurring after termination of the injection pulse, predicted theoretically, could be verified directly in the nozzle. In addition, the injected amount of fuel is monitored with the highest resolution ever reported in the literature.

  9. Parametric Studies of Flow Separation using Air Injection

    Science.gov (United States)

    Zhang, Wei

    2004-01-01

    Boundary Layer separation causes the airfoil to stall and therefore imposes dramatic performance degradation on the airfoil. In recent years, flow separation control has been one of the active research areas in the field of aerodynamics due to its promising performance improvements on the lifting device. These active flow separation control techniques include steady and unsteady air injection as well as suction on the airfoil surface etc. This paper will be focusing on the steady and unsteady air injection on the airfoil. Although wind tunnel experiments revealed that the performance improvements on the airfoil using injection techniques, the details of how the key variables such as air injection slot geometry and air injection angle etc impact the effectiveness of flow separation control via air injection has not been studied. A parametric study of both steady and unsteady air injection active flow control will be the main objective for this summer. For steady injection, the key variables include the slot geometry, orientation, spacing, air injection velocity as well as the injection angle. For unsteady injection, the injection frequency will also be investigated. Key metrics such as lift coefficient, drag coefficient, total pressure loss and total injection mass will be used to measure the effectiveness of the control technique. A design of experiments using the Box-Behnken Design is set up in order to determine how each of the variables affects each of the key metrics. Design of experiment is used so that the number of experimental runs will be at minimum and still be able to predict which variables are the key contributors to the responses. The experiments will then be conducted in the 1ft by 1ft wind tunnel according to the design of experiment settings. The data obtained from the experiments will be imported into JMP, statistical software, to generate sets of response surface equations which represent the statistical empirical model for each of the metrics as

  10. Electroosmotic flow and injection: application to conductimetry.

    Science.gov (United States)

    Tang, L; Huber, C O

    1994-10-01

    Electroosmotic solution propulsion and sample injection using fused silica tube was investigated. Capillary tube dimensions were 50-100 microm i.d. by 4-7 cm length with a break in the capillary wall near one end through which electrolytic contact with the capillary solution was established. The applied field was typically 150 V/cm. The voltage at the break in the column was monitored by potentiometry with a bridge configuration. Concentrations ranging from 10 microM to 100 mM were accommodated. The basis for high sensitivity, e.g. 70 mV/microM, together with low cell volume, e.g. 20 nl, was established. Tap water conductivity measurements were made using CaCl(2) reference solution.

  11. Numerical simulation of flow separation control by oscillatory fluid injection

    Science.gov (United States)

    Resendiz Rosas, Celerino

    2005-07-01

    In this work, numerical simulations of flow separation control are performed. The separation control technique studied is called "synthetic jet actuation". The developed code employs a cell centered finite volume scheme which handles viscous, steady and unsteady compressible turbulent flows. The pulsating zero mass jet flow is simulated by imposing a harmonically varying transpiration boundary condition on the airfoil's surface. Turbulence is modeled with the algebraic model of Baldwin and Lomax. The application of synthetic jet actuators is based in their ability to energize the boundary layer, thereby providing significant increase in the lift coefficient. This has been corroborated experimentally and it is corroborated numerically in this research. The performed numerical simulation investigates the flow over a NACA0015 airfoil. For this flow Re = 9 x 105 and the reduced frequency and momentum coefficient are F + = 1.1 and Cmu = 0.04 respectively. The oscillatory injection takes place at 12.27% chord from the leading edge. A maximum increase in the mean lift coefficient of 93% is predicted by the code. A discrepancy of approximately 10% is observed with corresponding experimental data from the literature. The general trend is, however, well captured. The discrepancy is attributed to the modeling of the injection boundary condition and to the turbulence model. A sensitivity analysis of the lift coefficient to different values of the oscillation parameters is performed. It is concluded that tangential injection, F+ ≈ O(1) and the utilized grid resolution around the site of injection are optimal. Streamline fields obtained for different angles of injection are analyzed. Flow separation and attachment as functions of the injection angle and of the velocity of injection can be observed. It is finally concluded that a reliable numerical tool has been developed which can be utilized as a support tool in the optimization of the synthetic jet operation and in the

  12. Solids flow rate measurement in dense slurries

    Energy Technology Data Exchange (ETDEWEB)

    Porges, K.G.; Doss, E.D.

    1993-09-01

    Accurate and rapid flow rate measurement of solids in dense slurries remains an unsolved technical problem, with important industrial applications in chemical processing plants and long-distance solids conveyance. In a hostile two-phase medium, such a measurement calls for two independent parameter determinations, both by non-intrusive means. Typically, dense slurries tend to flow in laminar, non-Newtonian mode, eliminating most conventional means that usually rely on calibration (which becomes more difficult and costly for high pressure and temperature media). These issues are reviewed, and specific solutions are recommended in this report. Detailed calculations that lead to improved measuring device designs are presented for both bulk density and average velocity measurements. Cross-correlation, chosen here for the latter task, has long been too inaccurate for practical applications. The cause and the cure of this deficiency are discussed using theory-supported modeling. Fluid Mechanics are used to develop the velocity profiles of laminar non-Newtonian flow in a rectangular duct. This geometry uniquely allows the design of highly accurate `capacitive` devices and also lends itself to gamma transmission densitometry on an absolute basis. An absolute readout, though of less accuracy, is also available from a capacitive densitometer and a pair of capacitive sensors yields signals suitable for cross-correlation velocity measurement.

  13. Injected power and entropy flow in a heated granular gas

    Science.gov (United States)

    Visco, P.; Puglisi, A.; Barrat, A.; Trizac, E.; van Wijland, F.

    2005-10-01

    Our interest goes to the power injected in a heated granular gas and to the possibility to interpret it in terms of entropy flow. We numerically determine the distribution of the injected power by means of Monte Carlo simulations. Then, we provide a kinetic-theory approach to the computation of such a distribution function. Finally, after showing why the injected power does not satisfy a fluctuation relation à la Gallavotti-Cohen, we put forward a new quantity which does fulfill such a relation, and is not only applicable in a variety of frameworks outside the granular world, but also experimentally accessible.

  14. Material flow data for numerical simulation of powder injection molding

    Science.gov (United States)

    Duretek, I.; Holzer, C.

    2017-01-01

    The powder injection molding (PIM) process is a cost efficient and important net-shape manufacturing process that is not completely understood. For the application of simulation programs for the powder injection molding process, apart from suitable physical models, exact material data and in particular knowledge of the flow behavior are essential in order to get precise numerical results. The flow processes of highly filled polymers are complex. Occurring effects are very hard to separate, like shear flow with yield stress, wall slip, elastic effects, etc. Furthermore, the occurrence of phase separation due to the multi-phase composition of compounds is quite probable. In this work, the flow behavior of a 316L stainless steel feedstock for powder injection molding was investigated. Additionally, the influence of pre-shearing on the flow behavior of PIM-feedstocks under practical conditions was examined and evaluated by a special PIM injection molding machine rheometer. In order to have a better understanding of key factors of PIM during the injection step, 3D non-isothermal numerical simulations were conducted with a commercial injection molding simulation software using experimental feedstock properties. The simulation results were compared with the experimental results. The mold filling studies amply illustrate the effect of mold temperature on the filling behavior during the mold filling stage. Moreover, the rheological measurements showed that at low shear rates no zero shear viscosity was observed, but instead the viscosity further increased strongly. This flow behavior could be described with the Cross-WLF approach with Herschel-Bulkley extension very well.

  15. Unsteady transverse injection of kerosene into a supersonic flow

    Institute of Scientific and Technical Information of China (English)

    徐胜利; R.D.Archer; B.E.Milton; 岳朋涛

    2000-01-01

    A shadowgraph and a new fuel injection system were used to study kerosene transversely injected into a supersonic flow. High pressure and velocity of injection can be attained. The pressure time histories were detected in oil-line and the shadowgraphs of the flow field were obtained at different time-delays. The inflow stagnation pressure was varied to change the local flow speed in test section. The results indicate that kerosene jet exhibits deep penetration and four regimes appear clearly during the fuel jet atomization in a high-speed flow. The jet disintegration is caused by surface waves propagating along the jet surface, and the breakup point is located at the wave trough. The surface waves are dominantly generated by aerodynamic force. The jet shock is close to windward surface of the jet. The shock reflects on and transmits in duct boundary layers. In the case of unsteady injection, the shock structure is very complicated and different from that of hydrogen injection. The results of kerosene inj

  16. The potentials of the third generation of flow injection analysis for nutrient monitoring and fractionation analysis

    DEFF Research Database (Denmark)

    Miró, Manuel; Hansen, Elo Harald; Buanuam, Janya

    2006-01-01

    In the present communication, the third generation of flow injection analysis, the so-called micro sequential-injection Laboratory-on-Valve (μSI-LOV), is presented as a miniaturized, automated approach for on-line monitoring of nutrients in different environmental compartments as effected under...... enclosed and strictly controlled conditions. Special emphasis is placed on coupling μSI-LOV on-line with a recently developed microcolumn to perform dynamic fractionation schemes for ascertaining the availability of phosphorous forms in solid substrates for biota uptake under simulated environmental...

  17. Sequential injection lab-on-valve: the third generation of flow injection analysis

    DEFF Research Database (Denmark)

    Wang, Jianhua; Hansen, Elo Harald

    2003-01-01

    Termed the third generation of flow injection analysis, sequential injection (SI)-lab-on-valve (LOV) has specific advantages and allows novel, unique applications - not least as a versatile front end to a variety of detection techniques. This review presents snd discusses progress to date of the SI......-LOV approach as well as its applications in the automation and micro-miniaturization of on-line sample pre-treatment. Special emphasis is placed on using SI-LOV in conjunction with bead injection (BI) for on-line separation and pre-concentration of ultra-trace levels of metals by exploiting the renewable micro...

  18. Flow improvers for water injection based on surfactants

    Energy Technology Data Exchange (ETDEWEB)

    Oskarsson, H.; Uneback, I.; Hellsten, M.

    2006-03-15

    In many cases it is desirable to increase the flow of injection water when an oil well deteriorates. It is very costly in offshore operation to lay down an additional water pipe to the injection site. Flow improvers for the injection water will thus be the most cost-effective way to increase the flow rate. During the last years water-soluble polymers have also been applied for this purpose. These drag-reducing polymers are however only slowly biodegraded which has been an incentive for the development of readily biodegradable surfactants as flow improvers for injection water. A combination of a zwitterionic and an anionic surfactant has been tested in a 5.5 inch, 700 m long flow loop containing sulphate brine with salinity similar to sea water. A drag reduction between 75 and 80% was achieved with 119 ppm in solution of the surfactant blend at an average velocity of 1.9 m/s and between 50 and 55% at 2.9 m/s. The surfactants in this formulation were also found to be readily biodegradable in sea water and low bio accumulating which means they have an improved environmental profile compared to the polymers used today. Due to the self-healing properties of the drag-reducing structures formed by surfactants, these may be added before the pump section - contrary to polymers which are permanently destroyed by high shear forces. (Author)

  19. Air Flow and Gassing Potential in Micro-injection Moulding

    DEFF Research Database (Denmark)

    Griffithsa, C.A.; Dimova, S.S.; Scholz, S.

    2011-01-01

    Process monitoring of micro injection moulding (μ-IM) is of crucial importance in understanding the effects of different parameter settings on the process, especially on its performance and consistency in regards to parts’ quality. Quality factors related to mould cavity air evacuation can provide...... valuable information about the process dynamics and also about the filling of a cavity by a polymer melt. In this paper, a novel experimental set-up is proposed to monitor maximum air flow and air flow work as an integral of the air flow over time by employing a MEMS gas sensor mounted inside the mould....... The influence of four μIM parameters, melt temperature, mould temperature, injection speed, and resistance to air evacuation, on two air flow-related output parameters is investigated by carrying out a design of experiment study. The results provide empirical evidence about the effects of process parameters...

  20. Immobilized enzymes in flow-injection analysis: present and trends.

    Science.gov (United States)

    Ruz, J; Lázaro, F; de Castro, M D

    1988-01-01

    An overview of the use of immobilized enzymes in flow-injection analysis (FIA) is presented. The joint use of FIA and immobilized enzymes means that analytical procedures are easily automated, analytical costs are reduced and methods are faster. The future possibilities for this combination are discussed.

  1. Flow Injection Analysis: A Revolution in Modern Analytical Chemistry

    DEFF Research Database (Denmark)

    Hansen, Elo Harald

    1996-01-01

    A review is made of the fundamentals of Flow Injection Analysis (FIA), and the versatility and applicability of this analytical concept is demonstrated by a series of examples, comprizing the use of different types of FIA-manifolds and various detection devices (optical and electrochemical). Emph...

  2. Tandem chemiluminescence-flow injection analysis for dimethoate determination.

    OpenAIRE

    Catalá Icardo, Mónica; López Paz, José Luis; CHOVES BARÓN, CRISTINA

    2010-01-01

    Ministry of Education and Science [CTM2006-11991] FEDER funds Catalá Icardo, M.; López Paz, JL.; Choves Barón, C. (2010). Tandem chemiluminescence-flow injection analysis for dimethoate determination. Luminescence. 25:235-236. doi:10.1002/bio.1217. Senia 235 236 25

  3. Resolution of an intense sweetener mixture by use of a flow injection sensor with on-line solid-phase extraction. Application to saccharin and aspartame in sweets and drinks.

    Science.gov (United States)

    Capitán-Vallvey, L F; Valencia, M C; Arana Nicolás, E; García-Jiménez, J F

    2006-05-01

    An integrated solid-phase spectrophotometry-FIA method is proposed for simultaneous determination of the mixture of saccharin (1,2-benzisothiazol-3(2H)-one-1,1-dioxide; E-954) (SA) and aspartame (N-L-alpha-aspartyl-L-phenylalanine-1-methyl ester; E-951) (AS). The procedure is based on on-line preconcentration of AS on a C18 silica gel minicolumn and separation from SA, followed by measurement, at lambda = 210 nm, of the absorbance of SA which is transiently retained on the adsorbent Sephadex G-25 placed in the flow-through cell of a monochannel FIA setup using pH 3.0 orthophosphoric acid-dihydrogen phosphate buffer, 3.75x10(-3) mol L(-1), as carrier. Subsequent desorption of AS with methanol enables its determination at lambda = 205 nm. With a sampling frequency of 10 h(-1), the applicable concentration range, the detection limit, and the relative standard deviation were from 1.0 to 200.0 microg mL(-1), 0.30 microg mL(-1), and 1.0% (80 microg mL(-1), n = 10), respectively, for SA and from 10.0 to 200.0 microg mL(-1), 1.4 microg mL(-1), and 1.6% (100 microg mL(-1), n = 10) for AS. The method was used to determine the amounts of aspartame and saccharin in sweets and drinks. Recovery was always between 99 and 101%. The method enabled satisfactory determination of blends of SA and AS in low-calorie and dietary products and the results were compared with those from an HPLC reference method.

  4. Flow Injection and Atomic Absorption Spectrometry (FI-AAS) -

    DEFF Research Database (Denmark)

    Hansen, Elo Harald

    1996-01-01

    One of the advantages of the flow injection (FI) concept is that it is compatible with virtually all detection techniques. Being a versatile vehicle for enhancing the performance of the individual detection devices, the most spectacular results have possibly been obtained in conjunction with atomic...... the point of sample injection/introduction to the point of detection. Hence, in FI-fAAS this feature allows not only to obtain improved repeatability but also improved accuracy, and because the wash to sample ratio is high it permits the handling of samples with elevated salt contents - which...

  5. Screen-printed sensor for batch and flow injection potentiometric chromium(VI) monitoring

    Energy Technology Data Exchange (ETDEWEB)

    Sanchez-Moreno, Raul A.; Gismera, M.J.; Sevilla, M.T.; Procopio, Jesus R. [Facultad de Ciencias, Universidad Autonoma de Madrid, Departamento de Quimica Analitica y Analisis Instrumental, Madrid (Spain)

    2010-05-15

    A disposable screen-printed electrode was designed and evaluated for direct detection of chromium(VI) in batch and flow analysis. The carbon screen-printed electrode was modified with a graphite-epoxy composite. The optimal graphite-epoxy matrix contains 37.5% graphite powder, 12.5% diphenylcarbohydrazide, a selective compound for chromium(VI), and 50% epoxy resin. The principal analytical parameters of the potentiometric response in batch and flow analysis were optimized and calculated. The screen-printed sensor exhibits a response time of 20 {+-} 1 s. In flow analysis, the analytical frequency of sampling is 70 injections per hour using 0.1 M NaNO{sub 3} solution at pH 3 as the carrier, a flow rate of 2.5 mL.min{sup -1}, and an injection sample volume of 0.50 mL. The sensor shows potentiometric responses that are very selective for chromium(VI) ions and optimal detection limits in both static mode (2.1 x 10{sup -7} M) and online analysis (9.4 x 10{sup -7} M). The disposable potentiometric sensor was employed to determine toxicity levels of chromium(VI) in mineral, tap, and river waters by flow-injection potentiometry and batch potentiometry. Chromium(VI) determination was also carried out with successful results in leachates from municipal solid waste landfills. (orig.)

  6. Tangential injection to a supersonic flow on a blunted nose

    Science.gov (United States)

    Chuvakhov, P. V.; Egorov, I. V.; Ezhov, I. V.; Ezhov, I. V.; Novikov, I. V.; Vasilevskiy, E. B.

    2017-06-01

    The flow pattern and the heat §ux to a body surface at a tangential gas injecting have been investigated. The cooling air was injected to a §ow through the tangential axisymmetric slot on the spherically blunted cylinder. The experiments were conducted at M∞ = 6, Re∞,Rw = 0.76 · 106, angle of attack α = 0°-30°, and the slot width hk/Rw = 0-0.021. The mass rate of the injecting gas was G∗ = gj/(πρ∞ u2∞w) = 0- 0.16. It has been shown that maximum of the heat §ux toward the sphere surface can be sufficiently decreased. Numerical investigations have been carried out using the solution of the Navier-Stokes equations for axisymmetric two-dimensional (2D) viscous compressible unsteady §ows at α = 0.

  7. Bone cement flow analysis by stepwise injection through medical cannulas.

    Science.gov (United States)

    Zderic, Ivan; Steinmetz, Philipp; Windolf, Markus; Richards, R Geoff; Boger, Andreas; Gueorguiev, Boyko

    2016-12-01

    Cement leakage is a serious adverse event potentially occurring during vertebroplasty. Pre-operative in-silico planning of the cement filling process can help reducing complication rates related to leakage. This requires a better understanding of the cement flow along the whole injection path. Therefore, the aim of the present study was to analyze bone cement flow behavior by stepwise injections through medical cannulas. Sixteen cannulas were assigned to four groups for stepwise injection of differently colored cement portions of 1ml volume. Each group differed in the amount of injected cement portions with a range of 1-4ml. After cement curing longitudinal cross-sections of the cannulas were performed and high-resolution pictures taken. Based on these pictures, quadratic polynomial interpolation was applied to the marked intersections between the last two injected cement portions to calculate the leading coefficients. Leading coefficients in the groups with three cement portions (0.287 ± 0.078), four portions (0.243 ± 0.041) and two portions (0.232 ± 0.050) were comparable and significantly higher than the group with one cement portion (0.0032 ± 0.0004), p ≤ 0.016. Based on these findings, cement flow through medical cannulas can be considered as predictable and can therefore be excluded as a source of risk for possible cement leakage complications during vertebroplasty procedures. Copyright © 2016 IPEM. Published by Elsevier Ltd. All rights reserved.

  8. Modeling and Design of Semi-Solid Flow Batteries

    Science.gov (United States)

    Brunini, Victor Eric

    A three-dimensional dynamic model of the recently introduced semi-solid flow battery system is developed and applied to address issues with important design and operation implications. Because of the high viscosity of semi-solid flow battery suspensions, alternative modes of operation not typically used in conventional redox flow battery systems must be explored to reduce pumping energy losses. Modeling results are presented .and compared to experimental observations to address important considerations for both stoichiometric and intermittent flow operation. The importance of active material selection, and its impact on efficient stoichiometric flow operation is discussed. Electrochemically active zone considerations relevant to intermittent flow operation of semi-solid flow batteries (or other potential electronically conductive flow battery systems) are addressed. Finally, the use of the model as a design tool for optimizing flow channel design to improve system level performance is demonstrated.(Copies available exclusively from MIT Libraries, libraries.mit.edu/docs - docs@mit.edu)

  9. Injection Induced Mixing in Flows Separating From Smooth Surfaces

    Science.gov (United States)

    Adamczyk, John J. (Technical Monitor); Wundrow, David W.

    2004-01-01

    An analytic model for predicting the effect of unsteady local surface injection on the flow separating from a streamlined body at angle of attack is proposed. The model uses the premise that separation control results from enhanced mixing along the shear layer that develops between the main stream and the fluid in the underlying recirculation zone. High-Reynolds-number asymptotic methods are used to connect the unsteady surface injection to an instability wave propagating on the separating shear layer and then to the large-scale coherent structures that produce the increased mixing. The results is a tool that can guide the choice of fluid-actuator parameters to maximize flow-control effectiveness and may also facilitate computer-based numerical experiments.

  10. Simulation and analysis of resin flow in injection machine screw

    Institute of Scientific and Technical Information of China (English)

    Ling-feng LI; Samir MEKID

    2008-01-01

    A method with simulation and analysis of the resin flow in a screw is presented to ease the control of some problems that may affect the efficiency and the quality of the product among existing screws in an injection machine. The physical model of a screw is established to represent the stress, the strain, the relationship between velocity and stress, and the temperature of the cells. In this paper, a working case is considered where the velocity and the temperature distributions at any section of the flow are obtained. The analysis of the computational results shows an ability to master various parameters depending on the specifications.

  11. Flow-Injection Responses of Diffusion Processes and Chemical Reactions

    DEFF Research Database (Denmark)

    Andersen, Jens Enevold Thaulov

    2000-01-01

    The technique of Flow-injection Analysis (FIA), now aged 25 years, offers unique analytical methods that are fast, reliable and consuming an absolute minimum of chemicals. These advantages together with its inherent feasibility for automation warrant the future applications of FIA as an attractive...... be used in the resolution of FIA profiles to obtain information about the content of interference’s, in the study of chemical reaction kinetics and to measure absolute concentrations within the FIA-detector cell....

  12. Determination of cyanide by a flow injection analysis-atomic absorption spectrometric method.

    Science.gov (United States)

    López Gómez, A V; Martínez Calatayud, J

    1998-10-01

    A new flow injection analysis (FIA) procedure is proposed for the indirect atomic absorption spectrometric determination of cyanide. The FIA manifold is based on the insertion of the sample into a distilled water carrier, then the sample flows through a solid-phase reactor filled with silver iodide entrapped in polymeric resin beads. The calibration graph is linear over the range 0.2-6.0 mg l-1 of cyanide (correlation coefficient 0.9974), the detection limit is 0.1 mg l-1, the sample throughput is 193 h-1 and the RSD is 0.8%. The method is simple, quick and more selective than other published FIA procedures. The reproducibility obtained by using different solid-phase reactors and solutions is in the range 2.2-3.1% (RSD). The method was applied to the determination of cyanide in commercial samples such as pharmaceutical formulations and industrial electrolytic baths.

  13. Entrained Flow Reactor Study of K-Capture by Solid Additives

    DEFF Research Database (Denmark)

    Wang, Guoliang; Jensen, Peter Arendt; Wu, Hao

    2016-01-01

    A method to simulate the reaction between gaseous K-species and solid additives, at suspension fired conditions has been developed, using an entrained flow reactor (EFR). A water slurry containing solid additives (kaolin or coal fly ash) and KCl, is injected into the EFR and the solid products...... are collected from the cyclone and filter. The K-capture reaction is evaluated by determining the fraction of water-insoluble K in the products. The results showed that KCl can effectively be captured by kaolin and coal fly ash, forming water-insoluble K-aluminosilicates. The amount of K, captured per gram...

  14. Chemiluminometric hydrogen peroxide sensor for flow injection analysis

    Energy Technology Data Exchange (ETDEWEB)

    Preuschoff, F. (Inst. fuer Biotechnologie, Halle Univ. (Germany)); Spohn, U. (Inst. fuer Biotechnologie, Halle Univ. (Germany)); Blankenstein, G. (Inst. fuer Enzymtechnologie am Forschungszentrum Juelich GmbH, Duesseldorf Univ., Juelich (Germany)); Mohr, K.H. (Inst. fuer Biotechnologie, Halle Univ. (Germany)); Kula, M.R. (Inst. fuer Enzymtechnologie am Forschungszentrum Juelich GmbH, Duesseldorf Univ., Juelich (Germany))

    1993-08-01

    A chemiluminometric hydrogen peroxide sensor was developed for fast flow injection analysis. Different peroxidases were covalently immobilized on affinity membranes and compared with respect to the catalytic luminol oxidation. A photomultiplier tube is connected with a fibre bundle to the flow cell. The small cell volume of 5-10 [mu]l allows sampling rates between 90 and 200/h, depending on the flow rate. The highest sensitivity and the best longterm stability can be achieved with microbial peroxidase. Hydrogen peroxide can be determined in the range between 10[sup -3] and 10[sup -8] mol/l with a precision of < 3% (n=6, [alpha] = 0.05). The operational stability of the sensor is longer than 10 weeks. (orig.)

  15. Formation dry-out from CO2 injection into saline aquifers: Part 1, Effects of solids precipitation and their mitigation

    Energy Technology Data Exchange (ETDEWEB)

    Pruess, Karsten; Muller, Nadja

    2009-02-01

    Injection of CO{sub 2} into saline aquifers may cause formation dry-out and precipitation of salt near the injection well, which may reduce formation porosity, permeability, and injectivity. This paper uses numerical simulation to explore the role of different processes and parameters in the salt precipitation process and to examine injection strategies that could mitigate the effects. The main physical mechanisms affecting the dry-out and salt precipitation process include (1) displacement of brine away from the injection well by injected CO{sub 2}, (2) dissolution (evaporation) of brine into the flowing CO{sub 2} stream, (3) upflow of CO{sub 2} due to gravity effects (buoyancy), (4) backflow of brine toward the injection point due to capillary pressure gradients that oppose the pressure gradient in the CO{sub 2}-rich ('gas') phase, and (5) molecular diffusion of dissolved salt. The different mechanisms operate on a range of spatial scales. CO{sub 2} injection at constant rate into a homogeneous reservoir with uniform initial conditions is simulated in 1-D radial geometry, to resolve multiscale processes by taking advantage of the similarity property, i.e., the evolution of system conditions as a function of radial distance R and time t depends only on the similarity variable R{sup 2}/t. Simulations in 2-D vertical cross sections are used to examine the role of gravity effects. We find that counterflow of CO{sub 2} and brine can greatly increase aqueous phase salinity and can promote substantial salt precipitation even in formations with low dissolved solids. Salt precipitation can accentuate effects of gravity override. We find that injecting a slug of fresh water prior to commencement of CO{sub 2} injection can reduce salt precipitation and permeability loss near the injection well.

  16. Multisyringe flow injection analysis of stable and radioactive strontium in samples of environmental interest.

    Science.gov (United States)

    Fajardo, Y; Gómez, E; Mas, F; Garcias, F; Cerdà, V; Casas, M

    2004-01-01

    A multisyringe flow injection (MSFIA) method for the determination of stable and radioactive strontium, using a solid phase resin (Sr-Resin), has been developed. Strontium concentrations are determined by atomic emission spectroscopy and by a low background proportional counter. The method has been applied to different samples (water, milk and soil) of environmental interest. The LLD of the stable and radioactive Sr were 10 microg/l and 0.01 Bq, respectively. The standard deviation of the separation procedure is 2% (n=10).

  17. DETERMINATION OF TETRACYCLINE AND OXYTETRACYCLINE BY FLOW-INJECTION CHEMILUMINESCENCE METHOD

    Institute of Scientific and Technical Information of China (English)

    2006-01-01

    Tetracycline and oxytetracycline are broad-spec-trumantibiotics.They are not only used in humanpathologies,but alsoin veterinary medicine,ani malnutrition and feed additives for cattle breeding.In the past few years,the deter mination meth-ods of tetracycline and oxytetracycline were repor-ted,which involved in difference spectrophotome-try[1],HPLC[2,3],spectrophotometry[4-7],HPLC-MS[8-9],spectrofluori metry[10],solid-phase extrac-tion[11]and kinetic methods.Recently,flow-injection CL method has beenpaid mo...

  18. Radial pressure profiles in a cold‐flow gas‐solid vortex reactor

    Science.gov (United States)

    Pantzali, Maria N.; Kovacevic, Jelena Z.; Marin, Guy B.; Shtern, Vladimir N.

    2015-01-01

    A unique normalized radial pressure profile characterizes the bed of a gas‐solid vortex reactor over a range of particle densities and sizes, solid capacities, and gas flow rates: 950–1240 kg/m3, 1–2 mm, 2 kg to maximum solids capacity, and 0.4–0.8 Nm3/s (corresponding to gas injection velocities of 55–110 m/s), respectively. The combined momentum conservation equations of both gas and solid phases predict this pressure profile when accounting for the corresponding measured particle velocities. The pressure profiles for a given type of particles and a given solids loading but for different gas injection velocities merge into a single curve when normalizing the pressures with the pressure value downstream of the bed. The normalized—with respect to the overall pressure drop—pressure profiles for different gas injection velocities in particle‐free flow merge in a unique profile. © 2015 The Authors AIChE Journal published by Wiley Periodicals, Inc. on behalf of American Institute of Chemical Engineers AIChE J, 61: 4114–4125, 2015 PMID:27667827

  19. Radial pressure profiles in a cold-flow gas-solid vortex reactor.

    Science.gov (United States)

    Pantzali, Maria N; Kovacevic, Jelena Z; Heynderickx, Geraldine J; Marin, Guy B; Shtern, Vladimir N

    2015-12-01

    A unique normalized radial pressure profile characterizes the bed of a gas-solid vortex reactor over a range of particle densities and sizes, solid capacities, and gas flow rates: 950-1240 kg/m(3), 1-2 mm, 2 kg to maximum solids capacity, and 0.4-0.8 Nm(3)/s (corresponding to gas injection velocities of 55-110 m/s), respectively. The combined momentum conservation equations of both gas and solid phases predict this pressure profile when accounting for the corresponding measured particle velocities. The pressure profiles for a given type of particles and a given solids loading but for different gas injection velocities merge into a single curve when normalizing the pressures with the pressure value downstream of the bed. The normalized-with respect to the overall pressure drop-pressure profiles for different gas injection velocities in particle-free flow merge in a unique profile. © 2015 The Authors AIChE Journal published by Wiley Periodicals, Inc. on behalf of American Institute of Chemical Engineers , 61: 4114-4125, 2015.

  20. Unsteady Tip Clearance Flow Pattern in an Isolated Axial Compressor Rotor with Micro Tip Injection

    Institute of Scientific and Technical Information of China (English)

    Shaojuan Geng; Hongwu Zhang; Jingyi Chen; Weiguang Huang

    2007-01-01

    A numerical study of the effect of discrete micro tip injection on unsteady tip clearance flow pattern in an isolated axial compressor rotor is presented, intending to better understand the flow mechanism behind stall control measures that act on tip clearance flow. Under the influence of injection the unsteadiness of self-induced tip clearance flow could be weakened. Also the radial migration of tip clearance vortex is confined to a smaller radial extent near the rotor tip and the trajectory of tip clearance flow is pushed more downstream. So the injection is beneficial to improve compressor stability and increase static pressure rise near rotor tip region. The results of injection with different injected mass flow rates show that for the special type of injector adopted in the paper the effect of injection on tip clearance flow may be different according to the relative strength between these two streams of flow. For a fixed injected mass flow rate, reducing the injector area to increase injection velocity can improve the effect of injection on tip clearance flow and thus the compressor stability. A comparison of calculations between single blade passage and multiple blade passages validates the utility of single passage computations to investigate the tip clearance flow for the case without injection and its interaction with injected flow for the case with tip injection.

  1. Modelling and Simulation of Structural Deformation of Isothermal Subsurface Flow and Carbon Dioxide Injection

    KAUST Repository

    El-Amin, Mohamed

    2011-05-15

    Injection of CO2 in hydrocarbon reservoir has double benefit. On the one hand, it is a profitable method due to issues related to global warming, and on the other hand it is an effective mechanism to enhance hydrocarbon recovery. Such injection associates complex processes involving, e.g., solute transport of dissolved materials, in addition to local changes in density of the phases. Also, increasing carbon dioxide injection may cause a structural deformation of the medium, so it is important to include such effect into the model. The structural deformation modelling in carbon sequestration is important to evaluate the medium stability to avoid CO2 leakage to the atmosphere. On the other hand, geologic formation of the medium is usually heterogeneous and consists of several layers of different permeability. In this work we conduct numerical simulation of two-phase flow in a heterogeneous porous medium domain with dissolved solute transport as well as structural deformation effects. The solute transport of the dissolved component is described by concentration equation. The structural deformation for geomechanics is derived from a general local differential balance equation with neglecting the local mass balance of solid phase and the inertial force term. The flux continuity condition is used at interfaces between different permeability layers of the heterogeneous medium. We analyze the vertical migration of a CO2 plume injected into a 2D layered reservoir. Analysis of distribution of flow field components such as saturation, pressures, velocities, and CO2 concentration are presented.

  2. Tracer-Encapsulated Solid Pellet (TESPEL) Injection System for the TJ-II Stellarator

    Energy Technology Data Exchange (ETDEWEB)

    Tamura, N. [National Institute for Fusion Science, Toki, Japan; McCarthy, K. J. [EURATOM-CIEMAT, Madrid, Spain; Hayashi, H. [National Institute for Fusion Science, Toki, Japan; Combs, Stephen Kirk [ORNL; Foust, Charles R [ORNL; Garcia, R. [Laboratory Nacional de Fusion, Madrid, Spain; Panadero, N. [CIEMAT, Laboratory Nacional de Fusion, Spain; Pawelec, E. [Opole University, Poland; Sanchez, J. Hernandez [Laboratory Nacional de Fusion, Madrid, Spain; Navarro, M. [CIEMAT, Laboratory Nacional de Fusion, Spain; Soleto, A. [CIEMAT, Laboratory Nacional de Fusion, Spain

    2016-01-01

    A tracer-encapsulated solid pellet (TESPEL) injection system for the TJ-II stellarator was recently developed. In order to reduce the time and cost for the development, we combined a TESPEL injector provided by National Institute for Fusion Science with an existing TJ-II cryogenic pellet injection system. Consequently, the TESPEL injection into the TJ-II plasma was successfully achieved, which was confirmed by several pellet diagnostics including a normal-incidence spectrometer for monitoring a tracer impurity behavior.

  3. Laser velocimeter measurements of multiphase flow of solids

    Energy Technology Data Exchange (ETDEWEB)

    Kadambi, J.R.; Chen, R.C.; Bhunia, S.

    1989-01-01

    A unique refractive index matched facility for studying solid-liquid multiphase flow has been developed. The refractive index matching of the solid and the liquid allows the use of non-intrusive Laser Doppler Velocimetry (LDV) to measure the solid and the liquid velocities. These measurements will be useful in developing a better understanding of solid-liquid flows, especially solid-liquid and solid-solid interactions. Silica gel and 50% sodium iodide solution in water (refractive index {approx}1.443) are used as the refractive index matched solid and liquid respectively. A two color back scatter mode LDV is used for making velocity measurements. Tests were conducted in solid-liquid slurries with volumetric solid concentration levels of 5% and 15% in the Reynolds number (Re) range of 400 to 9200. Silica gel particles of mean diameter 40 microns were used. Measurements included mapping of the solid and liquid velocities and obtaining the pressure drop data. Signal processing technique utilizing histogram of velocity measurements made at a point and signal amplitude discrimination was successfully used for differentiating between solid and liquid velocities. 34 refs., 61 figs., 5 tabs.

  4. Flow-injection Chemiluminescence Determination of Trace Calf Thymus DNA

    Institute of Scientific and Technical Information of China (English)

    Min ZHOU; Yong Jun MA; Xiao Yong JIN; Xiu Lan TENG; Zi Yu ZHANG; Hui CHEN

    2003-01-01

    A flow injection procedure for the determination of calf thymus DNA (CT DNA) overthe range 2.1x10-6~2.1×10-1 μg mL-1 is described, based on measurement of the enhancedchemiluminescence emission of rhodamine B-Ce(Ⅳ) system, activated by imidazole-HCl buffersolution. This method is highly sensitive, with the linearity range broadened to five orders ofmagnitude. It has been applied to determine CT DNA in synthetic sample with satisfactoryresults.

  5. Determination of uranium and zirconium by flow injection analysis

    Energy Technology Data Exchange (ETDEWEB)

    Sousa, Alvaro S.F. de; Domingues, Maria de L.F.; Rocha, Valeska P. de Araujo; Jesus, Camila S. de, E-mail: alvaro@ien.gov.br, E-mail: valeska@ien.gov.br, E-mail: luma@ien.gov.br, E-mail: camilasaj@gmail.com [Instituto de Engenharia Nuclear (IEN/CNEN-RJ), Rio de Janeiro, RJ (Brazil)

    2013-07-01

    As an integral part of chemical quality control of nuclear materials a method for determination of uranium and zirconium, in a mixture is presented. A simple, cheap, selective and quantitative Flow Injection Analysis (FIA) system was developed. Zirconium and uranium were determinate in presence of each other and no prior separation was needed. Arsenazo III was used as a colorimetric reagent and parameters such as acidity and reagents concentration were studied and optimized. An analytical throughput of 30 sample determination per hour was obtained. (author)

  6. FLOW CHARACTERISTICS OF TURBULENT JETS INJECTED OBLIQUELY IN CROSSFLOW

    Institute of Scientific and Technical Information of China (English)

    GUO Ting-ting; LI Shao-hua; XU Zhong

    2004-01-01

    Numerical simulation has been performed to investigate the characteristics of the turbulent jet issuing obliquely into a crossflow, at the injection angles of 90° and 60°. The SIMPLEC algorithm in the body-fitted coordinates and the wall-function method using the RNG k-ε turbulence model have been adopted to simulate this flow at two jet-to-crossflow velocity ratios, 2 and 4. The numerical results are good agreement with the experimental measurements, the jet trajectories have been given, the separation events in the lee of the jet exit have been found, and the forming mechanism has been analyzed.

  7. Aqueous semi-solid flow cell: demonstration and analysis

    Energy Technology Data Exchange (ETDEWEB)

    Li, Z; Smith, KC; Dong, YJ; Baram, N; Fan, FY; Xie, J; Limthongkul, P; Carter, WC; Chiang, YM

    2013-01-01

    An aqueous Li-ion flow cell using suspension-based flow electrodes based on the LiTi2(PO4)(3)-LiFePO4 couple is demonstrated. Unlike conventional flow batteries, the semi-solid approach utilizes fluid electrodes that are electronically conductive. A model of simultaneous advection and electrochemical transport is developed and used to separate flow-induced losses from those due to underlying side reactions. The importance of plug flow to achieving high energy efficiency in flow batteries utilizing highly non-Newtonian flow electrodes is emphasized.

  8. Subsurface injection of combustion power plant effluent as a solid-phase carbon dioxide storage strategy

    Science.gov (United States)

    Darnell, K. N.; Flemings, P. B.; DiCarlo, D.

    2017-06-01

    Long-term geological storage of CO2 may be essential for greenhouse gas mitigation, so a number of storage strategies have been developed that utilize a variety of physical processes. Recent work shows that injection of combustion power plant effluent, a mixture of CO2 and N2, into CH4 hydrate-bearing reservoirs blends CO2 storage with simultaneous CH4 production where the CO2 is stored in hydrate, an immobile, solid compound. This strategy creates economic value from the CH4 production, reduces the preinjection complexity since costly CO2 distillation is circumvented, and limits leakage since hydrate is immobile. Here we explore the phase behavior of these types of injections and describe the individual roles of H2O, CO2, CH4, and N2 as these components partition into aqueous, vapor, hydrate, and liquid CO2 phases. Our results show that CO2 storage in subpermafrost or submarine hydrate-forming reservoirs requires coinjection of N2 to maintain two-phase flow and limit plugging.

  9. Tetracycline, oxytetracycline and chlortetracycline determination by flow injection potentiometry.

    Science.gov (United States)

    Couto, C M; Lima, J L; Conceição, M; Montenegro, B S; Reis, S

    1998-12-01

    This paper describes tetracycline (TCH), oxytetracycline (OTCH) and chlortetracycline (CTCH) determination by flow injection potentiometry. In the flow system proposed TC samples are inserted in a carrier solution and converged with a Cu(II) solution of known concentration; the Cu(II) decrease due to its complexation with tetracyclines (TC) was monitored. The detector used was a homogeneous crystalline CuS/Ag2S double membrane tubular electrode with increased sensitivity. The present system allows tetracyclines determinations within a 48.1-4.8 x 10(3) ppm for TCH, 49.1-4.9 x 10(3) ppm for OTCH and 51.5-5.1 x 10(3) ppm for CTCH and a precision better than 0.4% for the three TC species. This procedure accomplishes 150-200 samples h(-1) with a Cu(II) consumption of about 13 microg determination(-1).

  10. Principles and Applications of Flow Injection Analysis in Biosensors

    DEFF Research Database (Denmark)

    Hansen, Elo Harald

    1996-01-01

    In practical applications biosensors are often forced to operate under less than optimal conditions. Because of their construction, and the physical processes and chemical reactions involved in their operation, compromise conditions are frequently required to synchronize all events taking place....... Therefore, and in order to implement functions such as periodic calibration, conditioning and possible regeneration of the biosensor, and, very importantly, to yield the freedom to select the optimum detection means, it is advantageous to use these devices in a flow-through mode, particularly by employing...... the flow injection (FI) approach. The capacity of FI, as offering itself as a complementary facility to augment the performance of biosensors, and in many cases as an attractive alternative, is demonstrated by reference to selected examples, comprising assays based on enzymatic procedures with optical...

  11. [Determination of lead with GFAAS using online flow injection].

    Science.gov (United States)

    Chen, Zhong-Lan

    2007-06-01

    A cheap, rapid and sensitive method for the determination of trace amount of lead in water samples by graphite furnace absorption spectrometry coupled with online flow injection preconcentration with ammonium pyrrolidine dithiocarboxylate chelating cellulose (CC-APDC) was developed. There were six steps in the preconcentration of flow injection: first, 0.15 mL nitric acid was used for a complete elution, which exceeded the volume of the graphite tube, so the 40 mL solution was removed before eluting. Secondly, 40 mL maximum concentration elution solution was added to GFAAS by fixed volume sampling to improve the accuracy. In addition, traditional stopping gas measurement was substituted with small flow gas atomization (30 mL x min(-1), preconcention for 1 min) during the removal of high memory effect for ashing stage in graphite furnace, which develops tail-out phenomenon and makes blank value low and steady. Various parameters affecting the adsorption and elution, such as pH of the solution, eluent concentration, sample flow rate etc, were optimized. If miniflow in atomization step was used, the memory effect in the determination of lead by GFAAS could be removed. The CC-APDC was used for preparation and preconcentration. A good precision (RSD = 1.4%, n = 10), high enrichment factor (15) and sample throughput (50 h) with detection limit 0.12 microg x L(-1) were obtained. This method has been successfully applied to the water sample for lead determination with a recovery of 95%-105%.

  12. Sensitive flow-injection spectrophotometric analysis of bromopride

    Science.gov (United States)

    Lima, Liliane Spazzapam; Weinert, Patrícia Los; Pezza, Leonardo; Pezza, Helena Redigolo

    2014-12-01

    A flow injection spectrophotometric procedure employing merging zones is proposed for direct bromopride determination in pharmaceutical formulations and biological fluids. The proposed method is based on the reaction between bromopride and p-dimethylaminocinnamaldehyde (p-DAC) in acid medium, in the presence of sodium dodecyl sulfate (SDS), resulting in formation of a violet product (λmax = 565 nm). Experimental design methodologies were used to optimize the experimental conditions. The Beer-Lambert law was obeyed in a bromopride concentration range of 3.63 × 10-7 to 2.90 × 10-5 mol L-1, with a correlation coefficient (r) of 0.9999. The limits of detection and quantification were 1.07 × 10-7 and 3.57 × 10-7 mol L-1, respectively. The proposed method was successfully applied to the determination of bromopride in pharmaceuticals and human urine, and recoveries of the drug from these media were in the ranges 99.6-101.2% and 98.6-102.1%, respectively. This new flow injection procedure does not require any sample pretreatment steps.

  13. Simple and clean determination of tetracyclines by flow injection analysis

    Science.gov (United States)

    Rodríguez, Michael Pérez; Pezza, Helena Redigolo; Pezza, Leonardo

    2016-01-01

    An environmentally reliable analytical methodology was developed for direct quantification of tetracycline (TC) and oxytetracycline (OTC) using continuous flow injection analysis with spectrophotometric detection. The method is based on the diazo coupling reaction between the tetracyclines and diazotized sulfanilic acid in a basic medium, resulting in the formation of an intense orange azo compound that presents maximum absorption at 434 nm. Experimental design was used to optimize the analytical conditions. The proposed technique was validated over the concentration range of 1 to 40 μg mL- 1, and was successfully applied to samples of commercial veterinary pharmaceuticals. The detection (LOD) and quantification (LOQ) limits were 0.40 and 1.35 μg mL- 1, respectively. The samples were also analyzed by an HPLC method, and the results showed agreement with the proposed technique. The new flow injection method can be immediately used for quality control purposes in the pharmaceutical industry, facilitating monitoring in real time during the production processes of tetracycline formulations for veterinary use.

  14. Characterization of Flow Behavior of Semi-Solid Slurries with Low Solid Fractions

    Science.gov (United States)

    Chucheep, Thiensak; Wannasin, Jessada; Canyook, Rungsinee; Rattanochaikul, Tanate; Janudom, Somjai; Wisutmethangoon, Sirikul; Flemings, Merton C.

    2013-10-01

    Semi-solid slurry casting is a metal-forming process that involves transforming liquid metal into slurry having a low solid fraction and then forming the slurry into solid parts. To successfully apply this slurry-forming process, it is necessary to fully understand the flow behavior of semi-solid slurries. This present work applied the rapid quenching method and the modified gravity fluidity casting to investigate the flow behavior, which involves characterizations of the initial solid fraction, fluidity, and microstructure of semi-solid slurries. Three commercial aluminum alloys were used in this study: 383 (Al-Si11Cu), 356 (Al-Si7MgFe), and 7075 (Al-Zn6MgCu) alloys. The results show that the initial solid fractions can be controlled by varying the rheocasting time. The rapid quenching mold can be used to determine the initial solid fractions. In this method, it is important to apply the correcting procedure to account for growth during quenching and to include all the solid phases. Results from the fluidity study of semi-solid slurries show that the fluidity decreases as the initial solid fraction increases. The decrease is relatively rapid near the low end of the initial solid fraction curves, but is quite slow near the high end of the curves. All the three alloys follow this trend. The results also demonstrate that the slurries that contain high solid fractions of up to 30 pct can still flow well. The microstructure characterization results show that the solid particles in the slurries flow uniformly in the channel. A uniform and fine microstructure with limited phase segregation is observed in the slurry cast samples.

  15. Assessing preferential flow by simultaneously injecting nanoparticle and chemical tracers

    KAUST Repository

    Subramanian, S. K.

    2013-01-01

    The exact manner in which preferential (e.g., much faster than average) flow occurs in the subsurface through small fractures or permeable connected pathways of other kinds is important to many processes but is difficult to determine, because most chemical tracers diffuse quickly enough from small flow channels that they appear to move more uniformly through the rock than they actually do. We show how preferential flow can be assessed by injecting 2 to 5 nm carbon particles (C-Dots) and an inert KBr chemical tracer at different flow rates into a permeable core channel that is surrounded by a less permeable matrix in laboratory apparatus of three different designs. When the KBr tracer has a long enough transit through the system to diffuse into the matrix, but the C-Dot tracer does not, the C-Dot tracer arrives first and the KBr tracer later, and the separation measures the degree of preferential flow. Tracer sequestration in the matrix can be estimated with a Peclet number, and this is useful for experiment design. A model is used to determine the best fitting core and matrix dispersion parameters and refine estimates of the core and matrix porosities. Almost the same parameter values explain all experiments. The methods demonstrated in the laboratory can be applied to field tests. If nanoparticles can be designed that do not stick while flowing through the subsurface, the methods presented here could be used to determine the degree of fracture control in natural environments, and this capability would have very wide ranging value and applicability.

  16. Characterization of the flow pattern of a gas/solids flow in a downer reactor

    Energy Technology Data Exchange (ETDEWEB)

    Lehner, P.; Wirth, K.E. [Erlangen-Nuernberg Univ., Erlangen (Germany). Lehrstuhl fuer Mechanische Verfahrenstechnik

    1999-07-01

    The downer reactor is discussed in literature as a new type of gas/solids reactor. Due to the cocurrent movement of gas and solids in direction of gravity, it is expected that a narrow residence time distribution and a flow regime close to plug flow can be established in this reactor. Recent studies show, that the gas/solids distributor on the top of the downer mainly influences the flow conditions. However, the influence of the physical properties of the solids and the plant setup on the flow behavior is still ambiguous. Therefore, experimental investigations concerning the local and cross-sectional solids distribution have been carried out under different operating conditions (variation of superficial gas velocity and solids circulation rate) and with different solids (glass beads, d{sub p}=60 {mu}m and d{sub p}=130 {mu}m). An X-ray computed tomography system has been used to obtain the solids concentration distribution in the entire cross-section at different axial positions of the downer. Pressure profiles can provide additional information about the overall behavior of the gas/solids flow. Results show a significant influence of the entrance conditions of the gas/solids flow on the flow pattern in the region below the gas/solids distributor. After a significant length, depending on solids properties and superficial gas velocity, similar flow behavior can be noticed for different entrance conditions. Superficial gas velocity not only influences the entrance length, but also the solids distribution in the entire cross-section of the downer. (orig.)

  17. Trends and perspectives of flow injection/sequential injection on-line sample-pretreatment schemes coupled to ETAAS

    DEFF Research Database (Denmark)

    Wang, Jianhua; Hansen, Elo Harald

    2005-01-01

    Flow injection (FI) analysis, the first generation of this technique, became in the 1990s supplemented by its second generation, sequential injection (SI), and most recently by the third generation (i.e.,Lab-on-Valve). The dominant role played by FI in automatic, on-line, sample pretreatments...

  18. Methanol synthesis in a countercurrent gas-solid-solid trickle flow reactor. An experimental study

    NARCIS (Netherlands)

    Kuczynski, M.; Oyevaar, M.H.; Pieters, R.T.; Westerterp, K.R.

    1987-01-01

    The synthesis of methanol from CO and H2 was executed in a gas-solid-solid trickle flow reactor. The reactor consisted of three tubular reactor sections with cooling sections in between. The catalyst was Cu on alumina, the adsorbent was a silica-alumina powder and the experimental range 498–523 K,

  19. Indications of Segmental Flow in Straight Pipes by Flow Injection with Spectrophotometric Detection

    DEFF Research Database (Denmark)

    Andersen, Jens Enevold Thaulov

    2000-01-01

    A procedure of spectrophotometric analysis of fluid flow in pipes is described and its performance is tested on three different dye compounds. The procedure follows measurement and mathematical de-convolution of the signal with an exponential function that is associated with molecular diffusion....... Evidence is provided for the presence of segmental flow and the three dye compounds, used as tracer molecules, indicate that the solute molecules gain velocity, predominantly in the streamwise direction, from the solvent flow rate. The additional velocity, as gained from the solvent flow rate, depends...... on a kinetic-diffusion constant and the internal friction of the system. The model allows a calculation of the flow-injection signal and serves as a tool for the investigation of properties of fluid dynamics....

  20. Determination of chlorogenic acid by flow injection irreversible biamperometry

    Institute of Scientific and Technical Information of China (English)

    Li Jun Li; Qi Feng Chen; Lai Bo Yu; Zhao Heng Zhong; Jun Feng; Hao Cheng; Hong Xing Kong; Jian Ling Wu

    2007-01-01

    A flow injection irreversible biamperometric method for the determination of chlorogenic acid is described. The proposed method is based on the electrochemical oxidation of chlorogenic acid at pretreated platinum electrode and the reduction of permanganate at another electrode to form an irreversible biamperometric detection system. Under the external potential difference(△E) of 0 V, in the 0.05 mol/L sulfuric acid, chlorogenic acid can be determined over the range 0.8-120 mg/L with a sample measurement frequency of 80 samples/h. The detection limit is 0.18 mg/L. The proposed method exhibits the satisfactory reproducibility with a relative standard derivation (R.S.D.) of 2.21% for 19 successive determinations of 40 mg/L.

  1. Review:Progress in research on mixing techniques for transverse injection flow fields in supersonic crossflows

    Institute of Scientific and Technical Information of China (English)

    Wei HUANG; Li YAN

    2013-01-01

    The transverse injection flow field has an important impact on the flowpath design of scramjet engines.At present a combination of the transverse injection scheme and any other flame holder has been widely employed in hypersonic propulsion systems to promote the mixing process between the fuel and the supersonic freestream;combustion efficiency has been improved thereby,as well as engine thrust.Research on mixing techniques for the transverse injection flow field is summarized from four aspects,namely the jet-to-crossflow pressure ratio,the geometric configuration of the injection port,the number of injection ports,and the injection angle.In conclusion,urgent investigations of mixing techniques of the transverse injection flow field are proposed,especially data mining in the quantitative analytical results for transverse injection flow field,based on results from multi-objective design optimization theory.

  2. Solid Lipid Nanoparticles Improve the Diclofenac Availability in Vitreous after Intraocular Injection

    Science.gov (United States)

    Abrishami, Majid; Vakili Ahrari Roodi, Mohammad

    2016-01-01

    Purpose. In order to improve the drug availability after intravitreal administration, solid lipid nanoparticles (SLNs) containing diclofenac were prepared. Methods. In this experimental study, 18 albino rabbits were included. In right and left eyes of all rabbits, SLNs containing diclofenac and commercial form of diclofenac (0.3 mg drug) were intravitreally injected, respectively. One, four, twelve, twenty-four, and forty-eight hours after injection, vitreous and aqueous humor samples were obtained in all cases. Then, the concentration of diclofenac sodium was evaluated in all samples. Results. Size of nanoparticles was around 170 nm after preparation. Drug concentration in eyes injected with SLNs was significantly higher than left eyes injected with commercial formulation up to 4 hours after intravitreal injection (p < 0.05). Diclofenac was quantified in samples up to 48 hours after intraocular injection. Four hours after intravitreal injection, the concentration of diclofenac in vitreous and aqueous humor of eyes receiving SLNs was, respectively, 2.5 and 6.5 times higher than eyes injected with commercial form of drug. Conclusions. Here, we demonstrate the potential of SLNs as a carrier of diclofenac for intraocular injection in order to prevent the systemic effects of the drug, increase the injection intervals, and improve the patient compliance. PMID:27803815

  3. The impact of interpreted flow regimes during constant head injection tests on the estimated transmissivity from injection tests and difference flow logging

    Energy Technology Data Exchange (ETDEWEB)

    Hjerne, Calle; Ludvigsson, Jan-Erik; Harrstroem, Johan [Geosigma AB, Uppsala (Sweden)

    2013-04-15

    A large number of constant head injection tests were carried out in the site investigation at Forsmark using the Pipe String System, PSS3. During the original evaluation of the tests the dominating transient flow regimes during both the injection and recovery period were interpreted together with estimation of hydraulic parameters. The flow regimes represent different flow and boundary conditions during the tests. Different boreholes or borehole intervals may display different distributions of flow regimes. In some boreholes good agreement was obtained between the results of the injection tests and difference flow logging with Posiva flow log (PFL) but in other boreholes significant discrepancies were found. The main objective of this project is to study the correlation between transient flow regimes from the injection tests and other borehole features such as transmissivity, depth, geology, fracturing etc. Another subject studied is whether observed discrepancies between estimated transmissivity from difference flow logging and injection tests can be correlated to interpreted flow regimes. Finally, a detailed comparison between transient and stationary evaluation of transmissivity from the injection tests in relation to estimated transmissivity from PFL tests in corresponding sections is made. Results from previous injection tests in 5 m sections in boreholes KFM04, KFM08A and KFM10A were used. Only injection tests above the (test-specific) measurement limit regarding flow rate are included in the analyses. For all of these tests transient flow regimes were interpreted. In addition, results from difference flow logging in the corresponding 5 m test sections were used. Finally, geological data of fractures together with rock and fracture zone properties have been used in the correlations. Flow regimes interpreted from the injection period of the tests are generally used in the correlations but deviations between the interpreted flow regimes from the injection and

  4. Injection Performance of a Gas-Solid Injector Based on the Particle Trajectory Model

    Directory of Open Access Journals (Sweden)

    Daolong Yang

    2015-01-01

    Full Text Available Gas-solid injectors are widely used feeding equipment in pneumatic conveying systems. The performance of a gas-solid injector has a significant influence on the type of application it can be employed for. To determine the key factors influencing the injection performance and address clogging problems in a gas-solid injector during a pneumatic conveying process, the particle trajectory model has been utilised as a means to perform simulations. In the particle trajectory model, the gas phase is treated as a continuous medium and the particle phase is treated as a dispersed phase. In this work, numerical and experimental studies were conducted for different nozzle positions in a gas-solid injector. A gas-solid injector test-bed was constructed based on the results of the simulations. The results show that the nozzle position is the key factor that affects the injection performance. The number of extrusive particles first increases and then decreases with the change in the nozzle position from left to right. Additionally, there is an optimum nozzle position that maximises the injection mass and minimises the number of particles remaining in the hopper. Based on the results of this work, the injection performance can be significantly increased and the clogging issues are effectively eliminated.

  5. Turbulent Flow over Small Amplitude Solid Waves

    Science.gov (United States)

    1984-01-01

    7. Annubar flow meter 8. Butterfly throttling valve 9. Removable blanking plate 10. Diaphragm valve 11. Small pump 12. By pass diaphragm valve...monitored by using an annubar connected to either a mercury or mirriam oil filled manometer. (b) Test Section 2 a A wave with a ratio of 0.014

  6. EFFECT OF NOZZLE FAN ANGLE ON SPRAYS IN GAS-SOLID RISER FLOW

    Institute of Scientific and Technical Information of China (English)

    Muhammad; M.; R.; Qureshi; Chao; Zhu; Chao-Hsin; Lin; Liang-Shih; Fan

    2006-01-01

    A three-dimensional simulation study is performed for investigating the hydrodynamic behaviors of a cross-flow liquid nitrogen spray injected into an air-fluidized catalytic cracking (FCC) riser of rectangular cross-section. Rectangular nozzles with a fixed aspect ratio but different fan angles are used for the spray feeding. While our numerical simulation reveals a generic three-phase flow structure with strong three-phase interactions under rapid vaporization of sprays, this paper tends to focus on the study of the effect of nozzle fan angle on the spray coverage as well as vapor flux distribution by spray vaporization inside the riser flow. The gas-solid (air-FCC) flow is simulated using the multi-fluid method while the evaporating sprays (liquid nitrogen) are calculated using the Lagrangian trajectory method, with a strong two-way coupling between the Eulerian gas-solid flow and the Lagrangian trajectories of spray. Our simulation shows that the spray coverage is basically dominated by the spray fan angle. The spray fan angle has a very minor effect on spray penetration. The spray vaporization flux per unit area of spray coverage is highly non-linearly distributed along the spray penetration. The convection of gas-solid flow in a riser leads to a significant downward deviation of vapor generated by droplet vaporization, causing a strong recirculating wake region in the immediate downstream area of the spray.

  7. All solid-state, injection-seeded Ti: sapphire ring laser

    Institute of Scientific and Technical Information of China (English)

    Ting Yu; Weibiao Chen; Jun Zhou; Jinzi Bi; Junwen Cui

    2005-01-01

    @@ In this letter, we present an all solid-state, injection-seeded Ti:sapphire laser. The laser is pumped by a laser diode pumped frequency-doubled Nd:YAG laser, and injection-seeded by an external cavity laser diode with the wavelength between 770 and 780 nm. The single longitude mode and the doubling efficiency of the laser are obtained after injection seeding. The experimental setup and relative results are reported.It is a good candidate laser source for mobile differential absorption lidar (DIAL) system.

  8. Numerical method for a moving solid object in flows.

    Science.gov (United States)

    Yokoi, Kensuke

    2003-04-01

    We propose a numerical method for dealing with a moving solid body that interacts with a complex liquid surface. The method is based on the level set method, the CIP method, and the ghost fluid method. The validity of the method was shown by applying it to Poiseuille and Couette flow problems. The method can precisely capture the boundary layer as well as a moving solid object.

  9. Instabilities in granular gas–solid flows

    Science.gov (United States)

    Gómez González, Rubén; Garzó, Vicente

    2017-04-01

    A linear stability analysis of the hydrodynamic equations with respect to the homogeneous cooling state is performed to study the conditions for stability of a suspension of solid particles immersed in a viscous gas. The dissipation in such systems arises from two different sources: inelasticity in particle collisions and viscous friction dissipation due to the influence of the gas phase on the solid particles. The starting point is a suspension model based on the (inelastic) Enskog kinetic equation. The effect of the interstitial gas phase on the dynamics of grains is modeled though a viscous drag force. The study is carried out in two different steps. First, the transport coefficients of the system are obtained by solving the Enskog equation by means of the Chapman–Enskog method up to first order in spatial gradients. Explicit expressions for the Navier–Stokes transport coefficients are obtained in terms of the volume fraction, the coefficient of restitution and the friction coefficient characterizing the amplitude of the external force. Once the transport properties are known, then the corresponding linearized hydrodynamic equations are solved to get the dispersion relations. In contrast to previous studies (Garzó et al 2016 Phys. Rev. E 93 012905), the hydrodynamic modes are analytically obtained as functions of the parameter space of the system. For a d-dimensional system, as expected linear stability shows d  ‑  1 transversal (shear) modes and a longitudinal ‘heat’ mode to be unstable with respect to long enough wavelength excitations. The results also show that the main effect of the gas phase is to decrease the value of the critical length L c (beyond which the system becomes unstable) with respect to its value for a dry granular fluid. Comparison with direct numerical simulations for L c shows a qualitative good agreement for conditions of practical interest.

  10. Orifice plate for controlling solids flow, methods of use thereof and articles comprising the same

    Energy Technology Data Exchange (ETDEWEB)

    Jukkola, Glen D.; Teigen, Bard C.

    2017-01-31

    Disclosed herein is an orifice plate comprising one or more plates having orifices disposed therein; the orifices being operative to permit the flow of solids from a moving bed heat exchanger to a solids flow control system; where the orifice plate is downstream of a tube bundle of the moving bed heat exchanger and upstream of the solids flow control system and wherein the orifice plate is operative to evenly distribute the flow of solids in the solids flow control system.

  11. Stock flow diagram analysis on solid waste management in Malaysia

    Science.gov (United States)

    Zulkipli, Faridah; Nopiah, Zulkifli Mohd; Basri, Noor Ezlin Ahmad; Kie, Cheng Jack

    2016-10-01

    The effectiveness on solid waste management is a major importance to societies. Numerous generation of solid waste from our daily activities has risked for our communities. These due to rapid population grow and advance in economic development. Moreover, the complexity of solid waste management is inherently involved large scale, diverse and element of uncertainties that must assist stakeholders with deviating objectives. In this paper, we proposed a system dynamics simulation by developing a stock flow diagram to illustrate the solid waste generation process and waste recycle process. The analysis highlights the impact on increasing the number of population toward the amount of solid waste generated and the amount of recycled waste. The results show an increment in the number of population as well as the amount of recycled waste will decrease the amount of waste generated. It is positively represent the achievement of government aim to minimize the amount of waste to be disposed by year 2020.

  12. Pulsating flows of solid/liquid suspensions

    Energy Technology Data Exchange (ETDEWEB)

    Round, G.F.; El-Sayed, E.

    1987-02-01

    Results are presented on the pulsed flow of coal/water suspensions of weight concentration, Cw=0-53.7%. The laboratory pipeline used was 35 m long with an I.D. of 5 cm. The coal used was a bituminous coal from Butler County, Pennsylvania. Its size ranged from 45 to 880 micrometer with a mean of 260 micrometers. The ranges of pulsing parameters studied were: velocity: 0-27 m/s; pulse amplitude: 0-80 mm; pulse frequency: 0-1.25 Hz. It was found that over most of the concentration range investigated there was a substantial energy saving measured in terms of an energy ratio Jp/Js, the ratio of total energy input in the pulsed state to that at steady state at the same volumetric flow rate. Minima over the entire velocity range occurred at a frequency of 0.3 Hz, with very little variation at different amplitudes. The weight concentration at which these occurred was Cw=20% with a corresponding energy saving which could be as much as 20%. 12 figs., 15 refs., 3 tabs.

  13. THEORY OF NONFLUIDIZED GAS SOLIDS FLOW AND ITS APPLICATION

    Institute of Scientific and Technical Information of China (English)

    Hongzhong Li

    2005-01-01

    A theory of nonfluidized gas-solids flow, which combines the theory of multiphase flow with the mechanics of particulate media, was proposed on the basis of understanding that the particles contact each other, solids and gas are in movement, and the drag force on the particles caused by interstitial gas flow is similar to gravity force having the property of mass force. Then this theory was verified by experiments on vertical and inclined moving beds, and was applied to calculation and design of equipment and devices with moving beds, such as pneumatic moving bed transport,dipleg, V-value, L-valve, orifice flow, and arching prevention. It can be used to guide the design and operation of moving beds and fixed beds.

  14. Unsaturated flow parameters of municipal solid waste.

    Science.gov (United States)

    Feng, Shi-Jin; Zheng, Qi-Teng; Chen, H X

    2017-05-01

    Leachate pollution/recirculation and landfill gas emission are the major environmental concerns in municipal solid waste (MSW) landfills. A good understanding and prediction of MSW unsaturated properties are critical for the design of piping systems and the control of these problems within landfills. This paper reviews the recent studies of unsaturated properties of MSW, including experimental methods, theoretical models and corresponding model parameters. For experimental methods, the sample size is a common and significant limitation and large test apparatuses (e.g., >80cm in diameter) are generally required and valuable. The theoretical models for MSW also have some limitations due to the changes in waste composition and particle size distribution caused by biodegradation. Thus, the available data of intrinsic permeabilities, water retention curves, relative permeabilities and anisotropy of MSW were summarized to investigate the influences of porosity, waste composition and particle size distribution. A series of estimation methods were subsequently proposed to determine the parameters of water retention curve like θLm, θLr, nv and α. The other parameters such as the pore connectivity term (l) and the degree of anisotropy (k) were significantly lacking data, thus only their relationships with porosity were proposed. The results show that it is possible to define the second order effects caused by variations in porosity, waste composition and particle size distribution. However, the estimation methods still need more experimental data for improvement, especially their dependence on waste composition and particle size distribution. Copyright © 2017 Elsevier Ltd. All rights reserved.

  15. Analytical Solution for Isentropic Flows in Solids

    Science.gov (United States)

    Heuzé, Olivier

    2009-12-01

    In the XIXth century, Riemann gave the equations system and the exact solution for the isentropic flows in the case of the ideal gas. But to our knowledge, nothing has been done to apply it to condensed media. Many materials of practical interest, for instance metals, obey to the linear law D = c+s u, where D is the shock velocity, u the particle velocity, and c and s properties of the material. We notice that s is strongly linked to the fundamental derivative. This means that the assumption of constant fundamental derivative is useful in this case, as it was with the isentropic gamma in the Riemann solution. Then we can apply the exact Riemann solution for these materials. Although the use of the hypergeometric function is complicated in this case, we obtain a very good approximation with the development in power series.

  16. Bienzymatic Biosensor for Rapid Detection of Aspartame by Flow Injection Analysis

    Directory of Open Access Journals (Sweden)

    Maria-Cristina Radulescu

    2014-01-01

    Full Text Available A rapid, simple and stable biosensor for aspartame detection was developed. Alcohol oxidase (AOX, carboxyl esterase (CaE and bovine serum albumin (BSA were immobilised with glutaraldehyde (GA onto screen-printed electrodes modified with cobalt-phthalocyanine (CoPC. The biosensor response was fast. The sample throughput using a flow injection analysis (FIA system was 40 h−1 with an RSD of 2.7%. The detection limits for both batch and FIA measurements were 0.1 µM for methanol and 0.2 µM for aspartame, respectively. The enzymatic biosensor was successfully applied for aspartame determination in different sample matrices/commercial products (liquid and solid samples without any pre-treatment step prior to measurement.

  17. Bienzymatic biosensor for rapid detection of aspartame by flow injection analysis.

    Science.gov (United States)

    Radulescu, Maria-Cristina; Bucur, Bogdan; Bucur, Madalina-Petruta; Radu, Gabriel Lucian

    2014-01-09

    A rapid, simple and stable biosensor for aspartame detection was developed. Alcohol oxidase (AOX), carboxyl esterase (CaE) and bovine serum albumin (BSA) were immobilised with glutaraldehyde (GA) onto screen-printed electrodes modified with cobalt-phthalocyanine (CoPC). The biosensor response was fast. The sample throughput using a flow injection analysis (FIA) system was 40 h⁻¹ with an RSD of 2.7%. The detection limits for both batch and FIA measurements were 0.1 µM for methanol and 0.2 µM for aspartame, respectively. The enzymatic biosensor was successfully applied for aspartame determination in different sample matrices/commercial products (liquid and solid samples) without any pre-treatment step prior to measurement.

  18. Highly sensitive flow-injection chemiluminescence determination of pyrogallol compounds

    Science.gov (United States)

    Kanwal, Shamsa; Fu, Xiaohong; Su, Xingguang

    2009-12-01

    A highly sensitive flow-injection chemiluminescent method for the direct determination of pyrogallol compounds has been developed. Proposed method is based on the enhanced effect of pyrogallol compounds on the chemiluminescence signals of KMnO 4-H 2O 2 system in slightly alkaline medium. Three important pyrogallol compounds, pyrogallic acid, gallic acid and tannic acid, have been detected by this method, and the possible mechanism of the CL reaction is also discussed. The proposed method is simple, convenient, rapid (60 samples h -1), and sensitive, has a linear range of 8 × 10 -10 mol L -1 to 1 × 10 -5 mol L -1, for pyrogallic acid, with a detection limit of 6 × 10 -11 mol L -1, 4 × 10 -8 mol L -1 to 5 × 10 -3 mol L -1 for gallic acid with a detection limit of 9 × 10 -10 mol L -1, and 8 × 10 -8 mol L -1 to 5 × 10 -2 mol L -1 for tannic acid, with a detection limit of 2 × 10 -9 mol L -1, respectively. The relative standard deviation (RSD, n = 15) was 0.8, 1.1 and 1.3% for 5 × 10 -6 mol L -1 pyrogallic acid, gallic acid and tannic acid, respectively. The proposed method was successfully applied to the determination of pyrogallol compounds in tea and coffee samples.

  19. Thermocapillary Flow and Aggregation of Bubbles on a Solid Wall

    Science.gov (United States)

    Kasumi, Hiroki; Solomentsev, Yuri E.; Guelcher, Scott A.; Anderson, John L.; Sides, Paul J.

    2000-01-01

    were equated by using a wall hindrance parameter q: U = qu [1] which shows the velocity of bubble is proportional to the entraining velocity. The hindrance parameter q can experimentally be measured independently. q can also be calculated by solving the equations of motion for a bubble translating parallel to a solid wall. The experimental cell is cylindrical with an ID of 10 cm and consists of a 1 cm deep main cell filled with silicone oil and flanked by two thermal reservoirs. The upper thermal reservoir was heated and the lower thermal reservoir was cooled so that the bubbles aggregate. Two types of silicone oil (eta = 0.02 and 0.50 Pa s) were used. Two equal sized air bubbles were injected into the cell with a syringe. The center-to-center distance of bubbles was observed through a microscope. Bubble radius ranged from 0.40 mm to 0.65 mm and the temperature gradients along with the cell ranged from 1400 to 5000 K/m. The bubbles aggregated when heat flows from the wall to the fluid. The velocities of bubbles were in the range of 1 - 10 microns/s. The separation r decreased more quickly when the temperature gradient was higher, bubble size was larger, and the oil viscosity was lower. r decreased more rapidly as the bubbles approached each other. Dimensionless time was arbitrarily set to be zero when the dimensionless center-to-center distance between the bubbles was 4. All the bubble trajectories fall onto one line, especially in the range of dimensionless distance from 4 to 3. This means the relative movement of the bubble pair is proportional to the temperature gradient and bubble size and it is inversely proportional to the viscosity of the oil. This result strongly suggests that the thermocapillary flow-based aggregation mechanism is correct. A value of q can be estimated by fitting the scaled data to Eq. [1]. A best fit value of q was obtained as q = 0.26 with a standard deviation of 0.03. Independent experimental results for q for a 0.5 mm radius bubble, give

  20. Numerical modeling of heat transfer and fluid flow in laser metal deposition by powder injection

    Science.gov (United States)

    Fan, Zhiqiang

    Laser metal deposition is an additive manufacturing technique which allows quick fabrication of fully-dense metallic components directly from Computer Aided Design (CAD) solid models. A self-consistent three-dimensional model was developed for the laser metal deposition process by powder injection, which simulates heat transfer, phase changes, and fluid flow in the melt pool. The governing equations for solid, liquid and gas phases in the calculation domain have been formulated using the continuum model. The free surface in the melt pool has been tracked by the Volume of Fluid (VOF) method, while the VOF transport equation was solved using the Piecewise Linear Interface Calculation (PLIC) method. Surface tension was modeled by taking the Continuum Surface Force (CSF) model combined with a force-balance flow algorithm. Laser-powder interaction was modeled to account for the effects of laser power attenuation and powder temperature rise during the laser metal deposition process. The governing equations were discretized in the physical space using the finite volume method. The advection terms were approximated using the MUSCL flux limiter scheme. The fluid flow and energy equations were solved in a coupled manner. The incompressible flow equations were solved using a two-step projection method, which requires a solution of a Poisson equation for the pressure field. The discretized pressure Poisson equation was solved using the ICCG (Incomplete Cholesky Conjugate Gradient) solution technique. The energy equation was solved by an enthalpy-based method. Temperature-dependent thermal-physical material properties were considered in the numerical implementation. The numerical model was validated by comparing simulations with experimental measurements.

  1. Creeping Viscous Flow around a Heat-Generating Solid Sphere

    DEFF Research Database (Denmark)

    Krenk, Steen

    1981-01-01

    The velocity field for creeping viscous flow around a solid sphere due to a spherically symmetric thermal field is determined and a simple thermal generalization of Stokes' formula is obtained. The velocity field due to an instantaneous heat source at the center of the sphere is obtained in close...... form and an application to the storage of heat-generating nuclear waste is discussed....

  2. White blood cell differentiation using a solid state flow cytometer

    NARCIS (Netherlands)

    Doornbos, R.M.P.; Hennink, E.J.; Putman, C.A.J.; Grooth, de Bart G.; Greve, Jan

    1993-01-01

    A flow cytometer using a solid state light source and detector was designed and built. For illumination of the sample stream two types of diode lasers (670 nm and 780 nm) were tested in a set-up designed to differentiate human leukocytes by means of light scattering. The detector is an avalanche pho

  3. The measurement of thermal stress distributions along the flow path in injection-molded flat plates

    NARCIS (Netherlands)

    Hastenberg, C.H.V.; Wildervanck, P.C.; Leenen, A.J.H.; Schennink, G.G.J.

    1992-01-01

    Internal stresses in injection-molded parts are the result of thermal, flow, and pressure histories. Internal stresses can be roughly divided into thermal and flow-induced stresses. In this paper, a modified layer-removal method is presented to determine thermal stress distributions in injection-mol

  4. White blood cell differentiation using a solid state flow cytometer

    OpenAIRE

    Doornbos, R.M.P.; Hennink, E J; Putman, C.A.J.; Grooth, de, Bart G.; Greve, Jan

    1993-01-01

    A flow cytometer using a solid state light source and detector was designed and built. For illumination of the sample stream two types of diode lasers (670 nm and 780 nm) were tested in a set-up designed to differentiate human leukocytes by means of light scattering. The detector is an avalanche photodiode, which was used to detect the weak scattered light in the orthogonal direction. The new flow cytometer set-up is very small, relatively cheap and yields similar results as a standard flow c...

  5. Rheological measurements of liquid-solid flows with inertia

    Science.gov (United States)

    Linares, Esperanza; Hunt, Melany; Zenit, Roberto

    2015-11-01

    This talk presents experimental measurements of effective viscosity for neutrally-buoyant suspensions in which the Reynolds numbers based on particle diameter varies from 1 to 1000 and for solid fractions from 10% to 50%. The measurements are conducted in a rough-walled, coaxial-cylinder rheometer. For Reynolds numbers from 1 to 100 and solid fractions less than 30%, the effective viscosities increase with Reynolds number and are comparable with recent numerical simulations found in the literature. For higher solid fractions, the effective viscosity shows shear thinning at the lowest shear rates, followed by thickening at higher shear rates. Over this range of Reynolds numbers for a pure fluid, the flow is laminar. At higher Reynolds numbers for a pure fluid, the flow transitions to turbulence. When particles are added under these flow conditions (particle Reynolds number greater than 100), the effective viscosity continues to increase with Reynolds number but with a greater magnitude. At the highest solid fractions, the effective viscosity is independent of shear rate.

  6. A frustrating problem: accelerated blood clearance of PEGylated solid lipid nanoparticles following subcutaneous injection in rats.

    Science.gov (United States)

    Zhao, Yongxue; Wang, Chunling; Wang, Long; Yang, Qiang; Tang, Wenya; She, Zhennan; Deng, Yihui

    2012-08-01

    Colloidal particles have preferential access to the lymphatic system following subcutaneous administration, achieving lymphatic targeting by drug accumulation in the regional lymph nodes. Moreover, the surface PEGylated colloidal particles have shown enhanced drainage into lymphatics and uptake by macrophages of the regional lymph nodes after subcutaneous injection. Nevertheless, it is reported that upon repeated intravenous injection, the PEG-specific IgM produced by the administration of the PEGylated colloidal particles markedly accelerates the clearance of subsequent doses of PEGylated particles. In this article, we report that the first subcutaneous injection of PEGylated solid lipid nanoparticles also induces the intravenously administered PEGylated particles to be cleared very rapidly from the circulation, and the "ABC index," a parameter for the intensity of accelerated blood clearance, for subcutaneous injection was equivalent to or even lower than that following the first intravenous injection. Moreover, the small quantities of distributed particles in the spleen after the first s.c. dose but the significantly higher elimination rate of the second i.v. dose, strongly suggest that, in addition to the spleen, the regional lymph nodes also play a promotive role in this phenomenon, although the exact lymphocytes causing this phenomenon remain unclear. Our observations may thus have important implications for considering combination therapy with PEGylated productions requiring different administration routes such as intravenous and subcutaneous injection, and great care is needed. Copyright © 2012 Elsevier B.V. All rights reserved.

  7. Numerical Study of Flow Characteristics in a Solid Particle Incinerator for Various Design Parameters of Injectors

    Energy Technology Data Exchange (ETDEWEB)

    Son, Jin Woo; Kim, Su Ho; Sohn, Chae Hoon [Sejong Univ., Seoul (Korea, Republic of)

    2013-12-15

    The flow characteristics in a solid particle incinerator are investigated numerically for high burning rate of wastes. The studied incinerator employs both a swirl flow used in the furnace of power plants and a design concept applied to a rocket combustor. As the first step, the non-reactive flow field is analyzed in the incinerator with primary and secondary injectors through which solid fuel and air are injected. The deflection angle of a primary injector, inclination angle of a secondary injector, and gap between the two types of injectors are selected as design parameters. The swirl number is adopted for evaluating the degree of swirl flow and estimated over wide ranges of three parameters. The swirl number increases with deflection angle, but it is affected little by inclination angle. Recirculation zones are formed near the injectors, and their size affects the swirl number. The swirl number decreases with the zonal size of recirculation. From the numerical results, the design points can be found with strong swirl flow.

  8. Radiation effect on temperature distribution in three-dimensional Couette flow with suction or injection

    Institute of Scientific and Technical Information of China (English)

    Bhupendra.Kumar Sharma; Mamta Agarwal; R.C.Chaudhary

    2007-01-01

    A theoretical analysis of three-dimensional Couette flow with radiation effect on temperature distribution has been analysed, when the injection of the fluid at the lower stationary plate is a transverse sinusoidal one and its corresponding removal by constant suction through the upper porous plate is in uniform motion. Due to this type of injection velocity, the flow becomes three-dimensional. The effect of Prandtl number,radiation parameter and injection parameter on rate of heat transfer has been examined by the help of graphs. The Prandtl number has a much greater effect on the temperature distribution than the injection or radiation parameter.

  9. Effects of Hot Steam Injection from the Slot at the Trailing Edge on Turbine Nozzle Vane Flow Field

    Institute of Scientific and Technical Information of China (English)

    Liang Xu; Peigang Yan; Hongyan Huang; Wanjin Han

    2008-01-01

    Moisture removal slot configurations with three different opening widths are in turn set at the trailing edges of a turbine hollow guide vane. The flow fields are analyzed by two-phase flow numerical simulation of solving the steady three dimensional Reynolds averaged Navier-Stokes equations on the basis of the real water vapor thermo-physical properties, and the blade temperature field is solved by the fluid-solid coupling. Exergy parame-ter is introduced as a measure to evaluate the economic cost of energy conversion process. The results indicate that the bigger slot allow lower quality of hot steam in the case of the equivalent injected quantity, while it has a higher exergy effective efficiency of the mixing process in the cascade channels. The hot steam injecting at the trailing edges has an optimal injected mass flow rate for a relatively large slot, on this point the exergy effective efficiency is the maximum, namely the flow loss is the minimum.

  10. Recent developments in automatic solid-phase extraction with renewable surfaces exploiting flow-based approaches

    DEFF Research Database (Denmark)

    Miró, Manuel; Hartwell, Supaporn Kradtap; Jakmunee, Jaroon

    2008-01-01

    Solid-phase extraction (SPE) is the most versatile sample-processing method for removal of interfering species and/or analyte enrichment. Although significant advances have been made over the past two decades in automating the entire analytical protocol involving SPE via flow-injection approaches......,on-line SPE assays performed in permanent mode lack sufficient reliability as a consequence of progressively tighter packing of the bead reactor, contamination of the solid surfaces and potential leakage of functional moieties. This article overviews the current state-of-the-art of an appealing tool...... chemical-derivatization reactions, and it pinpoints the most common instrumental detection techniques utilized. We present and discuss in detail relevant environmental and bioanalytical applications reported in the past few years....

  11. The heat-transfer performance of gas—solid trickle flow over a regularly stacked packing

    NARCIS (Netherlands)

    Verver, A.B.; Swaaij, van W.P.M.

    1986-01-01

    The heat-transfer behaviour of a countercurrent gas—solid trickle flow contactor is studied, using coarse sand particles as the solids phase. Experimental data on the overall heat-transfer rate constant between the gas flow and the solid particle flow were obtained in a 0.15 m square cross-section c

  12. Flowing Foam: T1 events and solid-liquid transitions.

    Science.gov (United States)

    Dennin, Michael

    2005-11-01

    Flowing aqueous foam is found in many applications ranging from oil recovery, to fire fighting, to spreading shaving cream. Aqueous foam consists of gas bubbles with liquid walls. One of the striking features of foam is that despite being composed entirely of fluids, its mechanical properties are either those of a solid (elastic response) or fluid (viscous flow), depending on the nature of the applied stress and strains. We study the transition between these two regimes using a model foam system: bubble rafts. Bubble rafts are a single layer of bubbles floating on the air-water surface. This allows us to track the motion of all the bubbles during flow. In this talk, we will present two main results. First, we will discuss the observation of the coexistence between a solid-like and fluid-like state during flow. Second, we will discuss the role played by nonlinear, topological rearrangements, known as T1 events, in determining the mechanical response of the system.

  13. Automated flow-injection method for cadmium determination with pre-concentration and reagent preparation on-line

    Directory of Open Access Journals (Sweden)

    María S. Di Nezio

    2005-02-01

    Full Text Available The spectrophotometric determination of Cd(II using a flow injection system provided with a solid-phase reactor for cadmium preconcentration and on-line reagent preparation, is described. It is based on the formation of a dithizone-Cd complex in basic medium. The calibration curve is linear between 6 and 300 µg L-1 Cd(II, with a detection limit of 5.4 µg L-1, an RSD of 3.7% (10 replicates in duplicate and a sample frequency of 11.4 h-1. The proposed method was satisfactorily applied to the determination of Cd(II in surface, well and drinking waters.

  14. Facility for cold flow testing of solid rocket motor models

    Science.gov (United States)

    Bacchus, D. L.; Hill, O. E.; Whitesides, R. Harold

    1992-02-01

    A new cold flow test facility was designed and constructed at NASA Marshall Space Flight Center for the purpose of characterizing the flow field in the port and nozzle of solid propellant rocket motors (SRM's). A National Advisory Committee was established to include representatives from industry, government agencies, and universities to guide the establishment of design and instrumentation requirements for the new facility. This facility design includes the basic components of air storage tanks, heater, submicron filter, quiet control valve, venturi, model inlet plenum chamber, solid rocket motor (SRM) model, exhaust diffuser, and exhaust silencer. The facility was designed to accommodate a wide range of motor types and sizes from small tactical motors to large space launch boosters. This facility has the unique capability of testing ten percent scale models of large boosters such as the new Advanced Solid Rocket Motor (ASRM), at full scale motor Reynolds numbers. Previous investigators have established the validity of studying basic features of solid rocket motor development programs include the acquisition of data to (1) directly evaluate and optimize the design configuration of the propellant grain, insulation, and nozzle; and (2) provide data for validation of the computational fluid dynamics, (CFD), analysis codes and the performance analysis codes. A facility checkout model was designed, constructed, and utilized to evaluate the performance characteristics of the new facility. This model consists of a cylindrical chamber and converging/diverging nozzle with appropriate manifolding to connect it to the facility air supply. It was designed using chamber and nozzle dimensions to simulate the flow in a 10 percent scale model of the ASRM. The checkout model was recently tested over the entire range of facility flow conditions which include flow rates from 9.07 to 145 kg/sec (20 to 320 Ibm/sec) and supply pressure from 5.17 x 10 exp 5 to 8.27 x 10 exp 6 Pa. The

  15. Protecting Coastal Areas from Flooding by Injecting Solids into the Subsurface

    Science.gov (United States)

    Germanovich, L. N.; Murdoch, L.

    2008-12-01

    Subsidence and sea level rise conspire to increase the risk of flooding in coastal cities throughout the world, and these processes were key contributors to the devastation of New Orleans by hurricane Katrina. Constructing levees and placing fill to raise ground elevations are currently the main options for reducing flooding risks in coastal areas, and both of these options have drawbacks. We suggest that hydromechanical injection of solid compounds suspended in liquid can be used to lift the ground surface and thereby expand the options for protecting such coastal cities as New Orleans, Venice, and Shanghai from flooding. These techniques are broadly related to hydraulic fracturing and compensation grouting, where solid compounds are injected as slurries and cause upward displacements at the ground surface. The equipment and logistics required for hydromechanical solid injection and ground lifting are readily available from current geotechnical and petroleum operations. Hydraulic fractures are routinely created in the upper tens of meters of sediments, where they are filled with a wide range of different proppants for environmental applications. At shallow depths, many of these fractures are sub-parallel to the ground surface and lift their overburden by a few mm to cm, although lifting is not the objective of these fractures. Much larger, vertical displacements, of the order of several meters, could be created in low-cohesion sediments over areas as large as square kilometers. This would be achieved as a result of multiple injections. Injecting solid particulates provides the benefits of a permanent displacement supported by the solids. We have demonstrated that hydraulic fractures will lift the ground surface at shallow depths in Texas near the Sabine River, where the geological setting is generally similar to that of New Orleans (and where, incidentally, hurricane Rita landed in 2005). In these regions, the soft surficial sediments are underlain by relatively

  16. Flow-injection analysis with multidetection as a useful technique for metal speciation.

    Science.gov (United States)

    Ruz, J; Rios, A; de Castro, M D; Valcarcel, M

    1986-03-01

    The analytical potential of a closed flow-injection system with multidetection by a single detector (for calculation of rate constants, reaction rate, dilution and amplification methods, etc.) is extended to simultaneous determinations for chromium speciation, with injection of the reagent(s) into the sample solution (which acts as the carrier).

  17. Micropolar boundary layer flow at a stagnation point on a moving wall with suction and injection

    Science.gov (United States)

    Hassanien, I. A.; Hady, F. M.

    1988-10-01

    The flow of a micropolar fluid at a two-dimensional stagnation point on a moving wall with suction and injection is studied. Numerical computations were carried out on a VME-2955 computer. The effects of the suction/injection parameter and dimensionless material parameters are discussed.

  18. Storage and flow of solids. Bulletin No. 123; Vol. 53, No. 26, November 1964

    Energy Technology Data Exchange (ETDEWEB)

    Jenike, A.W.

    1976-11-01

    Information is presented on: the concepts of flowability of bulk solids and of channels and the flow-no flow postulate; equipment and procedures for testing the flow of bulk solids; and bulk flow equipment design. This information should be sufficient to enable the engineer to design storage plants and flow channels for unobstructed bulk flow. Only an outline of the theory of flow is included. (LCL)

  19. An Inexpensive Detector for Absorbance Measurements in Flow-Injection Analysis

    Science.gov (United States)

    Hauser, Peter C.; Cates, Norman E.

    1996-02-01

    A photometric transducer for peak detection in flow-injection analysis is described. It relies on a light-emitting diode as the light source and a photodiode as the detector. A logarithmic amplifier is used in order to emulate Beer-Lambert's Law and to directly obtain absorbance readings. The performance has been tested with two commonly employed flow-injection procedures, but the device should be suitable for most methods that may be used in the teaching lab.

  20. Properties of autonomous and injection locked flux flow oscillators

    DEFF Research Database (Denmark)

    Mygind, Jesper; Koshelets, V. P.; Shchukin, A. V.;

    1995-01-01

    performed both for two autonomous FFOs and with one of the FFOs injection-locked to a narrow-band external microwave source. By beating the two autonomous FFOs an integral spectral linewidth as low as 750 kHz is measured at 280 GHz. Mechanisms leading to a broadening of the FFO linewidth are discussed...

  1. Dynamic flow-through approaches for metal fractionation in environmentally relevant solid samples

    DEFF Research Database (Denmark)

    Miró, Manuel; Hansen, Elo Harald; Chomchoei, Roongrat

    2005-01-01

    In the recent decades, batchwise equilibrium-based single or sequential extraction schemes have been consolidated as analytical tools for fractionation analyses to assess the ecotoxicological significance of metal ions in solid environmental samples. However, taking into account that naturally...... occurring processes always take place under dynamic conditions, recent trends have been focused on the development of alternative methods aimed at mimicking environmental events more correctly than their classical extraction counterparts. The present review details the state-of-the-art and the fundamental...... generations of flow-injection analysis. Special attention is also paid to a novel, robust, non-invasive approach for on-site continuous sampling of soil solutions, capitalizing on flow-through microdialysis, which presents itself as an appealing complementary approach to the conventional lysimeter experiments...

  2. Flow Injection/Sequential Injection Analysis Systems: Potential Use as Tools for Rapid Liver Diseases Biomarker Study

    Directory of Open Access Journals (Sweden)

    Supaporn Kradtap Hartwell

    2012-01-01

    Full Text Available Flow injection/sequential injection analysis (FIA/SIA systems are suitable for carrying out automatic wet chemical/biochemical reactions with reduced volume and time consumption. Various parts of the system such as pump, valve, and reactor may be built or adapted from available materials. Therefore the systems can be at lower cost as compared to other instrumentation-based analysis systems. Their applications for determination of biomarkers for liver diseases have been demonstrated in various formats of operation but only a few and limited types of biomarkers have been used as model analytes. This paper summarizes these applications for different types of reactions as a guide for using flow-based systems in more biomarker and/or multibiomarker studies.

  3. Improved optical techniques for studying sonic and supersonic injection into Mach 3 flow

    Science.gov (United States)

    Buggele, Alvin E.; Seasholtz, Richard G.

    1997-11-01

    Filtered Rayleigh Scattering and shadowgraph flow visualization were used to characterize the penetration of helium or moist air injected transversely at several pressures to a Mach 3 flow in the NASA Lewis 3.81 inch by 10 inch continuous flow supersonic wind tunnel. This work is in support of the LOX augmented nuclear thermal rocket program. The present study used an injection-seeded, frequency doubled Nd:YAG pulsed laser to illuminate a transverse section of the injectant plume. Rayleigh scattered light was passed through an iodine absorption cell to suppress stray laser light and was imaged onto a cooled CCD camera. The scattering was based on condensation of water vapor in the injectant flow. Results are presented for various configurations of sonic and supersonic injector designs mounted primarily in the floor of the tunnel. Injectors studied include a single 0.25 inch diameter hole, five 0.112 inch diameter holes on 0.177 inch spacing, and a 7 degree half angle wedge. High speed shadowgraph flow visualization images were obtained with several video camera systems. Roof and floor static pressure data are presented several ways for the three configurations of injection designs with and without helium and/or air injection into Mach 3 flow.

  4. Solid rocket booster internal flow analysis by highly accurate adaptive computational methods

    Science.gov (United States)

    Huang, C. Y.; Tworzydlo, W.; Oden, J. T.; Bass, J. M.; Cullen, C.; Vadaketh, S.

    1991-01-01

    The primary objective of this project was to develop an adaptive finite element flow solver for simulating internal flows in the solid rocket booster. Described here is a unique flow simulator code for analyzing highly complex flow phenomena in the solid rocket booster. New methodologies and features incorporated into this analysis tool are described.

  5. Holdup and Flow Behavior of Fluidized Solid Particles in a Liquid-Solid Circulating Fluidized Bed

    Energy Technology Data Exchange (ETDEWEB)

    Lim, Dae Ho; Lim, Ho; Jin, Hae Ryong; Kang, Yong [Chungnam National University, Daejeon (Korea, Republic of)

    2014-06-15

    Characteristics of holdup and flow behavior of fluidized solid particles were investigated in a liquid-solid circulating fluidized bed (0.102 m x 3.5 m). Effects of liquid velocity (U{sub L}), particle size (d{sub P}) and solid circulation rate (G{sub S}) on the solid holdup, overall particle rising velocity, slip velocity between liquid and particles and hydrodynamic energy dissipation rate in the riser were examined. The particle holdup increased with increasing d{sub P} or G{sub S} but decreased with increasing U{sub L}. The overall particle rising velocity increased with increasing U{sub L} or G{sub S} but decreased with increasing d{sub P}. The slip velocity increased with increasing U{sub L} or d{sub P} but did not change considerably with G{sub S}. The energy dissipation rate, which was found to be closely related to the contacting frequency of micro eddies, increased with increasing d{sub P}, G{sub S} or U{sub L}. The solid particle holdup was well correlated with operating variables such as U{sub L}, d{sub P} and G{sub S}.

  6. Preparation, in vitro release, and pharmacokinetics in rabbits of lyophilized injection of sorafenib solid lipid nanoparticles

    Directory of Open Access Journals (Sweden)

    Zhang H

    2012-06-01

    Full Text Available Hong Zhang, Fu-Ming Zhang, Shi-Jun YanDepartment of Pharmacy, Renmin Hospital of Wuhan University, Wuhan, People’s Republic of ChinaAbstract: Sorafenib solid lipid nanoparticles (S-SLN were prepared by emulsion evaporation–solidification at low temperature. Morphology was examined by transmission electron microscope. Particle size and zeta potential were determined by laser granularity equipment. Encapsulation efficiency (EE was detected by Sephadex gel chromatography and high-performance liquid chromatography (HPLC. The in vitro release profile of S-SLN was studied with dialysis technology. The lyophilized injection of S-SLN was prepared by freeze drying and analyzed by differential scanning calorimetry. The plasma concentration of sorafenib in blood was determined by HPLC. The solid lipid nanoparticles assumed a spherical shape with an even distribution of diameter and particle size 108.23 ± 7.01 nm (n = 3. The polydispersity index, zeta potential, and EE were determined to be 0.25 ± 0.02, -16.37 ± 0.65 mV, and 93.49% ± 1.87%, respectively (n = 3. The in vitro release accorded with the Weibull distribution model. An equal volume of 15% (w/v mannitol performed better as the protective agent for a lyophilized injection of S-SLN with a new material phase formation. The pharmacokinetic processes of sorafenib solution and lyophilized injection of S-SLN in vivo were in accordance with the two-compartment and one-compartment models, respectively. S-SLN nanoparticles are thus considered a promising drug-delivery system.Keywords: sorafenib, solid lipid nanoparticles, material phase analysis, HPLC, release profile, pharmacokinetics

  7. Lattice Solid/Boltzmann Microscopic Model to Simulate Solid/Fluid Systems-A Tool to Study Creation of Fluid Flow Networks for Viable Deep Geothermal Energy

    Institute of Scientific and Technical Information of China (English)

    Peter Mora; Yucang Wang; Fernando Alonso-Marroquin

    2015-01-01

    SUMMARY:Realizing the potential of geothermal energy as a cheap, green, sustainable resource to provide for the planet’s future energy demands that a key geophysical problem be solved first:how to develop and maintain a network of multiple fluid flow pathways for the time required to deplete the heat within a given region. We present the key components for micro-scale particle-based nu-merical modeling of hydraulic fracture, and fluid and heat flow in geothermal reservoirs. They are based on the latest developments of ESyS-Particle—the coupling of the lattice solid model (LSM) to simulate the nonlinear dynamics of complex solids with the lattice Boltzmann method (LBM) ap-plied to the nonlinear dynamics of coupled fluid and heat flow in the complex solid-fluid system. The coupled LSM/LBM can be used to simulate development of fracture systems in discontinuous media, elastic stress release, fluid injection and the consequent slip at joint surfaces, and hydraulic fractur-ing; heat exchange between hot rocks and water within flow pathways created through hydraulic fracturing;and fluid flow through complex, narrow, compact and gouge-or powder-filled fracture and joint systems. We demonstrate the coupled LSM/LBM to simulate the fundamental processes listed above, which are all components for the generation and sustainability of the hot-fractured rock geothermal energy fracture systems required to exploit this new green-energy resource.

  8. CHOOSING STRUCTURE-DEPENDENT DRAG COEFFICIENT IN MODELING GAS-SOLID TWO-PHASE FLOW

    Institute of Scientific and Technical Information of China (English)

    Ning Yang; Wei Wang; Wei Ge; Jinghai Li

    2003-01-01

    @@ Introduction Gas-solid two-phase flow is often encountered in chemical reactors for the process industry. For industrial users, design, scale-up, control and optimization for these reactors require a good understanding of the hydrodynamics of gas-solid two-phase flow. For researchers, exploration and prediction of the complex phenomena call for a good comprehension of the heterogeneous structure and of the dominant mechanisms of gas-solid and solid-solid interactions.

  9. Computer Simulations and Measurements of Radial Solid Flow Distribution in a Riser

    Institute of Scientific and Technical Information of China (English)

    LuHuilin; ZhaoGangbo; 等

    1998-01-01

    Comparisons between the numerical predictions from a two-phase model and the experimental hydrodynamic data have been performed in fully developed gas-solid flows for Fcc catalysts,The results suggested the existence of self-similar solid flux profiles at low solid fluxes.Non-uniformity in the radial solids fluxes was found with a high solid flowing aminly downward near the wall.The model predictions were reasonably caught up the experimental trends.

  10. Trajectory Analysis of Fuel Injection into Supersonic Cross Flow Based on Schlieren Method

    Institute of Scientific and Technical Information of China (English)

    YANG Hui; LI Feng; SUN Baigang

    2012-01-01

    Trajectory analysis of fuel injection into supersonic cross flow is studied in this paper.A directly-connected wind tunnel is constructed to provide stable supersonic freestream.Based on the test rig,the schlieren system is established to reveal the fuel injection process visually.Subsequently,the method of quantitative schlieren is adopted to obtain data of both fuel/air interface and bow shock with the aid of Photoshop and Origin.Finally,the mechanism based on two influential factors of fuel injection angle and fuel injection driven pressure,is researched by vector analysis.A dimensionless model is deduced and analyzed.The curve fitting result is achieved.The relationship between the data and the two influential factors is established.The results provide not only the quantitative characteristics of the fuel injection in supersonic cross flow but also the valuable reference for the future computational simulation.

  11. Influence analysis of flow rule in mine fire during injecting inert gases

    Institute of Scientific and Technical Information of China (English)

    NIU Hui-yong; WANG Hai-qiao

    2011-01-01

    According to the action law of gas flow during injecting inert gases as the research main line,and hydromechanics and thermodynamics theories,the characteristic of gas delamination that was caused by injecting inert gases to closed fire zone was analyzed.The criterion was brought forward,which could scale disappearing probability of turbulent state.Formation mechanism of gas layer in turbulent state was discussed primarily.Simultaneously,the condition was pointed out,which could make the gas in turbulent state by injecting different gases.The mathematical model about dynamic changes of oxygen and methane concentration in the process of injecting gases was erected.The mixture mechanism about injecting different flow inert gases and flammable gas layer in closed fire zone was revealed.

  12. VERTICAL FLOW OF GAS-LIQUID-SOLID PARTICLES SYSTEM

    OpenAIRE

    幡手, 泰雄; 野村, 博; 碇, 醇; ハタテ, ヤスオ; ノムラ, ヒロシ; イカリ, アツシ; HATATE, Yasuo; Nomura, Hiroshi; IKARI, Atsushi

    1983-01-01

    It is significant to know the hydrodynamic characteristics of the system in the design and scale-up of reactors containing gas-liquid-solid particles system. As a fundamental study of such a three-phase flow, the gas holdup and the pressure drop were measured in the vertical tubes, through which various mixtures of air, water, and fine glass-sphere, particles were passed. Three kinds of glass particles were used the average sizes of which were 30, 60 and 90 μm. Two kinds of tubes, 15 an...

  13. Study of the influence of the turbulent boundary conditions of a flow with parietal injection; Etude de l'influence des conditions aux limites turbulentes d'un ecoulement avec injection parietale

    Energy Technology Data Exchange (ETDEWEB)

    Chaouat, B.

    1998-07-01

    Numerical simulations of flows inside a solid propellant rocket engine with parietal injection are performed using the numerical resolution of Navier-Stokes equations in a k-{epsilon} turbulence model. Boundary conditions are defined considering laminar and turbulent fluid injections on the wall. In parallel, a Couette-type model is used to determine the velocity profile near the wall and the wall constraint for a laminar fluid injection. An analysis of simulations shows the influence of boundary conditions on the transition of the flow from the laminar to the turbulent regime, on the velocity profile near the wall, and on the evolution of Reynolds pressures. The average velocity profile is well reproduced but the first-order k-{epsilon} turbulence model shows limitations for the reproduction of turbulent pressure levels. A second-order Reynolds pressure model should be more appropriate. (J.S.)

  14. Flow regime analysis for fluid injection into a confined aquifer: implications for CO2 sequestration

    Science.gov (United States)

    Guo, B.; Zheng, Z.; Celia, M. A.; Stone, H.

    2015-12-01

    Carbon dioxide injection into a confined saline aquifer may be modeled as an axisymmetric two-phase flow problem. Assuming the two fluids segregate in the vertical direction due to strong buoyancy, and neglecting capillary pressure and miscibility, the lubrication approximation leads to a nonlinear advection-diffusion equation that describes the evolution of the sharp fluid-fluid interface. The flow behaviors in the system are controlled by two dimensionless groups: M, the viscosity ratio of the displaced fluid relative to injected fluid, and Γ , the gravity number, which represents the relative importance of buoyancy and fluid injection. Four different analytical solutions can be derived as the asymptotic approximations, representing specific values of the parameter pairs. The four solutions correspond to: (1) Γ 1; and (4) Γ >> 1, any M values. The first two of these solutions are new, while the third corresponds to the solution of Nordbotten and Celia (2006) for confined injections and the fourth corresponds to the solution of (Lyle et al., 2005) for gravity currents in an unconfined aquifer. Overall, the various axisymmetric flows can be summarized in a Γ-M regime diagram with five distinct dynamic behaviors including the four asymptotic regimes and an intermediate regime (Fig. 1). Data from a number of CO2 injection sites around the world can be used to compute the two dimensionless groups Γ and M associated with each injection. When plotted on the regime diagram, these values show the flow behavior for each injection and how the values vary from site to site. For all the CO2 injections, M is always larger than 1, while Γ can range from 0.01 up to 100. The pairs of (Γ, M) with lower Γ values correspond to solution (3), while the ones with higher Γ values can move up to the intermediate regime and the flow regime for solution (4). The higher values of Γ correspond to pilot-scale injections with low injection rates; most industrial-scale injection

  15. Flow-injection amperometric glucose biosensors based on graphene/Nafion hybrid electrodes

    Energy Technology Data Exchange (ETDEWEB)

    Choi, Bong Gill, E-mail: k1811@kaist.ac.kr [Department of Chemical and Biomolecular Engineering (BK21 Program), KAIST, Daejeon 305-701 (Korea, Republic of); Im, Jinkyu, E-mail: JINQ@paran.com [Department of Chemistry and Research Institute of Basic Sciences, Kyung Hee University, 1 Hoegidong, Dongdamoongu, Seoul (Korea, Republic of); Kim, Hoon Sik, E-mail: khs2004@khu.ac.kr [Department of Chemistry and Research Institute of Basic Sciences, Kyung Hee University, 1 Hoegidong, Dongdamoongu, Seoul (Korea, Republic of); Park, HoSeok, E-mail: phs0727@khu.ac.kr [Department of Chemical Engineering, College of Engineering, Kyung Hee University, 1 Seochon-dong, Giheung-gu, Youngin-si, Gyeonggi-do 446-701 (Korea, Republic of)

    2011-11-30

    Graphical abstract: Amperometric biosensors based on graphene hybrids showed the fast, sensitive, and stable amperometric responses in the flow injection system for automatically monitoring glucose. Display Omitted Highlights: > Flow-injection amperometric glucose biosensors were fabricated using reduced graphene oxide/Nafion hybrids. > The electrochemical kinetics of biosensors were comprehensively investigated by analysing electron transfer rate, charge transfer resistance, and ion diffusion coefficient, respectively. > The biosensors exhibited the fast, sensitive, and stable amperometric responses in the flow injection system for detecting glucose. - Abstract: In this research, we demonstrated the fabrication of flow-injection amperometric glucose biosensors based on RGO/Nafion hybrids. The nanohybridization of the reduced graphene oxide (RGO) by Nafion provided the fast electron transfer (ET) for the sensitive amperometric biosensor platforms. The ET rate (k{sub s}) and the charge transfer resistance (R{sub CT}) of GOx-RGO/Nafion hybrids were evaluated to verify the accelerated ET. Moreover, hybrid biosensors revealed a quasi-reversible and surface controlled process, as confirmed by the low peak-to-peak ({Delta}E{sub p}) and linear relations between I{sub p} and scan rate ({nu}). Hybrid biosensors showed the fast response time of {approx}3 s, the sensitivity of 3.8 {mu}A mM{sup -1} cm{sup -2}, the limit of detection of 170 {mu}M, and the linear detection range of 2-20 mM for the flow-injection amperometric detection of glucose. Furthermore, interference effect of oxidizable species such as ascorbic acid (AA) and uric acid (UA) on the performance of hybrid biosensors was prevented at the operating potential of -0.20 V even under the flow injection mode. Therefore, the fast, sensitive, and stable amperometric responses of hybrid biosensors in the flow injection system make it highly suitable for automatically monitoring glucose.

  16. Selective and Sensitive Chemiluminescence Determination of MCPB: Flow Injection and Liquid Chromatography.

    Science.gov (United States)

    Meseguer-Lloret, Susana; Torres-Cartas, Sagrario; Catalá-Icardo, Mónica; Gómez-Benito, Carmen

    2016-02-01

    Two new chemiluminescence (CL) methods are described for the determination of the herbicide 4-(4-chloro-o-tolyloxy) butyric acid (MCPB). First, a flow injection chemiluminescence (FI-CL) method is proposed. In this method, MCPB is photodegraded with an ultraviolet (UV) lamp and the photoproducts formed provide a great CL signal when they react with ferricyanide in basic medium. Second, a high-performance liquid chromatography chemiluminescence (HPLC-CL) method is proposed. In this method, before the photodegradation and CL reaction, the MCPB and other phenoxyacid herbicides are separated in a C18 column. The experimental conditions for the FI-CL and HPLC-CL methods are optimized. Both methods present good sensitivity, the detection limits being 0.12 µg L(-1) and 0.1 µg L(-1) (for FI-CL and HPLC-CL, respectively) when solid phase extraction (SPE) is applied. Intra- and interday relative standard deviations are below 9.9%. The methods have been satisfactorily applied to the analysis of natural water samples. FI-CL method can be employed for the determination of MCPB in simple water samples and for the screening of complex water samples in a fast, economic, and simple way. The HPLC-CL method is more selective, and allows samples that have not been resolved with the FI-CL method to be solved.

  17. Molecular dynamics of fluid flow at solid surfaces

    Science.gov (United States)

    Koplik, Joel; Banavar, Jayanth R.; Willemsen, Jorge F.

    1989-05-01

    Molecular dynamics techniques are used to study the microscopic aspects of several slow viscous flows past a solid wall, where both fluid and wall have a molecular structure. Systems of several thousand molecules are found to exhibit reasonable continuum behavior, albeit with significant thermal fluctuations. In Couette and Poiseuille flow of liquids it is found that the no-slip boundary condition arises naturally as a consequence of molecular roughness, and that the velocity and stress fields agree with the solutions of the Stokes equations. At lower densities slip appears, which can be incorporated into a flow-independent slip-length boundary condition. The trajectories of individual molecules in Poiseuille flow are examined, and it is also found that their average behavior is given by Taylor-Aris hydrodynamic dispersion. An immiscible two-fluid system is simulated by a species-dependent intermolecular interaction. A static meniscus is observed whose contact angle agrees with simple estimates and, when motion occurs, velocity-dependent advancing and receding angles are observed. The local velocity field near a moving contact line shows a breakdown of the no-slip condition and, up to substantial statistical fluctuations, is consistent with earlier predictions of Dussan [AIChE J. 23, 131 (1977)].

  18. Flow injection analysis with on-line nylon powder extraction for room-temperature phosphorescence determination of thiabendazole.

    Science.gov (United States)

    Piccirilli, G N; Escandar, G M

    2009-07-30

    A fast and very selective flow-through phosphorescence optosensor was designed and characterized for the determination of the fungicide thiabendazole in water samples. For the first time, thiabendazole was determined using a flow-through optosensor based on the phosphorescence signals obtained when it is retained in a solid support. While thiabendazole does not phosphoresce in packing materials commonly used to fill the flow-cell, significant emission signals are observed when it is retained on nylon powder in the presence of iodide and sulfite. The experimental set-up was based on a flow-injection manifold coupled to an on-line phosphorescence detector containing nylon powder packed in a conventional flow-cell. Potassium iodide and sodium sulfite were added to sample aliquots to improve the thiabendazole phosphorescence and injected in the flow manifold using water as carrier. After the phosphorescence emission was registered, the analyte was eluted from the packed nylon with a 65% (v/v) methanol-water mixture. Optimal instrumentation, experimental and flow conditions were evaluated. Using a sample volume of 2000 microL, the analytical signal showed a very good linearity in the range 12.9-110 ng mL(-1), with a detection limit of 4.5 ng mL(-1), and a sample throughput of about 14 samples per hour. The effects of the presence of concomitant species in the thiabendazole phosphorescence signal were studied, and a comparison with the fluorescence nylon-powder optosensor was carried out and discussed. Finally, the applicability of the proposed optosensor was tested in water samples, and satisfactory recoveries ranging between 97% and 105% were obtained.

  19. A review of interaction mechanisms in fluid-solid flows

    Energy Technology Data Exchange (ETDEWEB)

    Johnson, G.; Rajagopal, K.R. (Pittsburgh Univ., PA (USA). Dept. of Mechanical Engineering); Massoudi, M. (USDOE Pittsburgh Energy Technology Center, PA (USA))

    1990-09-01

    Multiphase flows have become the subject of considerable attention because of their importance in many industrial applications, such as fluidized beds, pneumatic transport of solids, coal combustion, etc. Fundamental research into the nature of pneumatic transport has made significant progress in identifying key parameters controlling the characteristics of these processes. The emphasis of this study is on a mixture composed of spherical particles of uniform size and a linearly viscous fluid. Section 1 introduces our approach and the importance of this study. In Section 2, the dynamics of a single particle as studied in classical hydrodynamics and fluid dynamics is presented. This has been a subject of study for more than 200 years. In Section 3, we review the literature for the constitutive relations as given in multiphase studies, i.e., generalization of single particle and as given in literature concerning the continuum theories of mixtures or multicomponent systems. In Section 4, a comparison between these representations and the earlier approach, i.e., forces acting on a single particle will be made. The importance of flow regimes, particle concentration, particle size and shape, rotation of the particle, effect of solid walls, etc. are discussed. 141 refs.

  20. Stability of Couette flow past a viscoelastic solid

    Science.gov (United States)

    Hess, Andrew; Gao, Tong

    2016-11-01

    Soft materials such as polymer gels have been widely used in engineering applications such as microfluidics, micro-optics, and active surfaces. It is important to obtain fundamental understandings of the dynamics of various soft materials when interacting with fluid. Here we investigate the material behavior of a viscoelastic solid film immersed in a simple Newtonian Couette flow. An Eulerian formulation of the Zener model is used to model the solid phase with the surface tension effect. A linear stability analysis is first performed to predict the material instabilities induced by the shear flow field, and provide an analytical basis to the numerical results. The nonlinear fluid/elastic structure interactions are further explored by using the direct numerical simulations. Phase tracking is accomplished through the use of a generalized Cahn-Hilliard model for the surface tension between the gel-like material and the ambient fluid. The coupled Cahn-Hilliard/Navier-Stokes/Zener equations are then solved on a staggered grid through a finite difference method. The results are compared with previous studies for both the hyperelastic and viscoelastic materials.

  1. Repeated injection of PEGylated solid lipid nanoparticles induces accelerated blood clearance in mice and beagles

    Directory of Open Access Journals (Sweden)

    Zhao Y

    2012-06-01

    Full Text Available Yongxue Zhao, Long Wang, Mina Yan, Yanling Ma, Guangxi Zang, Zhennan She, Yihui DengCollege of Pharmacy, Shenyang Pharmaceutical University, Shenyang, Liaoning, People’s Republic of ChinaAbstract: Surface modification of nanocarriers with amphiphilic polymer polyethylene glycol (PEG, known as PEGylation, is regarded as a major breakthrough in the application of nanocarriers. However, PEGylated nanocarriers (including liposomes and polymeric nanoparticles induce what is referred to as the “accelerated blood clearance (ABC phenomenon” upon repeated injection and consequently they lose their sustained circulation characteristics. Despite this, the present authors are not aware of any reports of accelerated clearance due to repeated injection for PEGylated solid lipid nanoparticles (SLNs, another promising nanocarrier. This study investigated the pharmacokinetics of PEGylated SLNs upon repeated administration in mice; moreover, the impact of circulation time on the induction of the ABC phenomenon was studied in beagles for the first time. The ABC index, selected as the ratio of the area under the concentration-time curve from time 0 to the last measured concentration of a second injection to that of the first injection, was used to evaluate the extent of this phenomenon. Results showed that the PEGylated SLNs exhibited accelerated clearance from systemic circulation upon repeated injection, both in mice and in beagles, and the ratio for the different time intervals, which showed that the ABC index exhibited significant difference within 30 minutes following the second injection, was good enough to evaluate the magnitude of ABC. This ABC index indicated that the 10 mol% PEG SLNs with a suitable prolonged circulation time induced the most marked ABC phenomenon in this research. This study demonstrated that, like PEGylated nanocarriers such as liposomes and polymeric nanoparticles, PEGylated SLNs induced the ABC phenomenon upon repeated injection

  2. Flame AAS determination of lead in water with flow-injection preconcentration and speciation using functionalized cellulose sorbent.

    Science.gov (United States)

    Naghmush, A M; Pyrzyńska, K; Trojanowicz, M

    1995-06-01

    The on-line solid phase extraction of trace amount of lead in flow-injection system with flame AAS detection was investigated using cellulose sorbents with phosphonic acid and carboxymethyl groups, C(18) sorbent non-modified and modified with Pyrocatechol Violet or 8-quinolinol, commercial chelating sorbents Chelex 100 and Spheron Oxin 1000, non-polar sorbent Amberlite XAD-2 modified with Pyrocatechol Violet and several cation-exchange resins. The best dynamic characteristics of retention were observed for functionalized cellulose sorbents. For Cellex P assumed as optimum sorbent, elution with a separate fractions of nitric acid and ethanol allows the differentiation between tetraalkyllead and sum of inorganic lead and organolead species of smaller number of alkyl groups. The detection limit for the determination of inorganic Pb(II) was estimated as 0.17 microg/l. at preconcentration from 50 ml sample at a flow rate of 7 ml/min.

  3. Internal flow measurements of drop impacting a solid surface

    Science.gov (United States)

    Kumar, S. Santosh; Karn, Ashish; Arndt, Roger E. A.; Hong, Jiarong

    2017-03-01

    Understanding the fundamental physical process involved in drop impacts is important for a variety of engineering and scientific applications. Despite exhaustive research efforts on the dynamics of drop morphology upon impact, very few studies investigate the fluid dynamics induced within a drop upon impact. This study employs planar particle image velocimetry (PIV) with fluorescent particles to quantify the internal flow field of a drop impact on a solid surface. The image distortion caused by the curved liquid-air interface at the drop boundary is corrected using a ray-tracing algorithm. PIV analysis using the corrected images has yielded interesting insights into the flow initiated within a drop upon impact. Depending on the pre-impact conditions, characterized by impact number, different vortex modes are observed in the recoil phase of the drop impact. Further, the strength of these vortices and the kinetic energy of the internal flow field have been quantified. Our studies show a consistent negative power law correlation between vortex strength, internal kinetic energy and the impact number.

  4. Local Gas Phase Flow Characteristics of a Gas—Liquid—Solid Three—Phase Reversed Flow Jet Loop Reactor

    Institute of Scientific and Technical Information of China (English)

    WENJianping; ChenYunlin; 等

    2002-01-01

    The local gas-phase flow characteristics such as local gas holdup (εg), local bubble velocity (Vb) and local bubble mean diameter(db) at a specified point in a gas-liquid-solid three-phase reversed flow jet loop reactor was experimentally investigated by a five-point conductivity probe. The effects of gas jet flow rate, liquid jet flow rate, solid loading, nozzle diameter and axial position on the local εg,Vb and db profiles were discussed. The presence of solids at low solid concentrations not only increased the local εg and Vb, but also decreased the local db. The optimum solid olading for the maximum local εg and Vb together with the minimum local db was 0.16×10-3m3, corresponding to a solid volume fraction,εS=2.5%.

  5. Flow injection method for sulphide determination using an organic mercury compound

    Energy Technology Data Exchange (ETDEWEB)

    Yaqoob, M.; Anwar, M.; Masood, A.S.; Masoom, M. (Univ. of Balochistan, Quetta (Pakistan))

    1991-04-01

    A simple flow injection analysis method is described for the determination of soluble sulfide, based on the complexation of sulfide with p-hydroxymercurbenzoic acid, in the presence of dithizone used as an indicator. The reaction is very rapid, with a sampling rate of 90/hr. and requires a very short length post injection reaction coil. The detection limit and precision are 0.01 mM and 0.7%, respectively.

  6. Injection of Nucleate-Boiling Slug Flows into a Heat Exchange Chamber in Microgravity

    Science.gov (United States)

    2015-06-01

    AFRL-AFOSR-UK-TR-2015-0029 Injection of nucleate- boiling slug flows into a heat exchange chamber in microgravity Jaume...2015 2. REPORT TYPE Final Report 3. DATES COVERED (From – To) 20 March 2012 – 19 March 2015 4. TITLE AND SUBTITLE Injection of nucleate- boiling ...method to produce controlled boiling through a localized nucleation cavity feeding a capillary crossflow forming regular trains of bubbles. The main

  7. Flow Injection Analysis of Acid and Base using Thermo-Sensitive Resistance Coils

    OpenAIRE

    1995-01-01

    A flow injection analysis of acid-base by detecting neutralization heat is proposed. A injected sample (acid or base), combined with a carrier (deionized water), was mixed with a reagent (base or acid) stream. A change in the solution temperature was detected by passing the solution, immediately after mixing, through a stainless steel capillary tube around which a thermo-sensitive resistance was coiled. The temperature of carrier was used as a reference Hydrochloric acid solutions of 0.003 to...

  8. Determinação turbidimétrica de dipirona em fluxo utilizando um reator contendo cloreto de prata imobilizado em resina poliéster Flow injection turbidimetric determination of dipyrone using a solid-phase reactor containing silver chloride immobilized in a polyester resin

    Directory of Open Access Journals (Sweden)

    Luiz H. Marcolino-Jr.

    2005-10-01

    Full Text Available A simple flow injection procedure was developed for determining dipyrone (1-phenyl-2,3-dimethyl-4-methylaminomethano-5-pyrazolone sodium, metamizol, analgin in pharmaceutical formulations. The determination is based on the reduction of Ag+ ions to Ag0 by dipyrone. A colloidal suspension of Ag0 produced was transported by carrier solution (0.01 mol L-1 NaOH and turbidimetrically detected at 425 nm. The analytical curve for dipyrone was linear in the range from 5.0 x 10-4 to 2.5 x 10-3 mol L-1 with a correlation coefficient of 0.9990. The detection limit was 1.3 x 10-4 mol L-1 (3sigmaB/slope. The relative standard deviation for ten successive measurements was 1.8% and an analytical frequency of 45 h-1 was obtained. The recovery values from three samples ranged from 96.0 to 102%.

  9. Magnetized plasma flow injection into tokamak and high-beta compact torus plasmas

    Science.gov (United States)

    Matsunaga, Hiroyuki; Komoriya, Yuuki; Tazawa, Hiroyasu; Asai, Tomohiko; Takahashi, Tsutomu; Steinhauer, Loren; Itagaki, Hirotomo; Onchi, Takumi; Hirose, Akira

    2010-11-01

    As an application of a magnetized coaxial plasma gun (MCPG), magnetic helicity injection via injection of a highly elongated compact torus (magnetized plasma flow: MPF) has been conducted on both tokamak and field-reversed configuration (FRC) plasmas. The injected plasmoid has significant amounts of helicity and particle contents and has been proposed as a fueling and a current drive method for various torus systems. In the FRC, MPF is expected to generate partially spherical tokamak like FRC equilibrium by injecting a significant amount of magnetic helicity. As a circumstantial evidence of the modified equilibrium, suppressed rotational instability with toroidal mode number n = 2. MPF injection experiments have also been applied to the STOR-M tokamak as a start-up and current drive method. Differences in the responses of targets especially relation with beta value and the self-organization feature will be studied.

  10. Numerical Simulation of Polymer Injection in Turbulent Flow Past a Circular Cylinder

    KAUST Repository

    Richter, David

    2011-01-01

    Using a code developed to compute high Reynolds number viscoelastic flows, polymer injection from the upstream stagnation point of a circular cylinder is modeled at Re = 3900. Polymer stresses are represented using the FENE-P constitutive equations. By increasing polymer injection rates within realistic ranges, significant near wake stabilization is observed. Rather than a turbulent detached shear layer giving way to a chaotic primary vortex (as seen in Newtonian flows at high Re), a much more coherent primary vortex is shed, which possesses an increased core pressure as well as a reduced level of turbulent energy. © 2011 American Society of Mechanical Engineers.

  11. On the possibility to improve the performance of flow injection analysis by deconvolution of spectrophotometric data

    DEFF Research Database (Denmark)

    Andersen, Jens Enevold Thanulov

    2001-01-01

    The concentration profile of chemical species pumped through a tubular system of 0.5 mm inner diameter is found to be trapezial shaped, as described theoretically by including the spatial resolution of the instrument, friction and diffusion. By applying the theory, which is based on the concept...... of segment flow, to experiments, it is shown that an injected segment of solute is diluted predominantly at the front and at the tail proportion of the segment in motion. A double-peaked structure in experiments of Flow-Injection Analysis (FIA) was identified and by including all the data...

  12. The effects of arbitrary injection angle and flow conditions on venturi-jet mixer

    Directory of Open Access Journals (Sweden)

    Sundararaj S.

    2012-01-01

    Full Text Available This paper describes the effect of jet injection angle, cross flow Reynolds number and velocity ratio on entrainment and mixing of jet with incompressible cross flow in venturi-jet mixer. Five different jet injection angles 45o, 60o, 90o, 125o, 135o are tested to evaluate the entrainment of jet and mixing performances of the mixer. Tracer concentration along the downstream of the jet injection, cross flow velocity, jet velocity and pressure drop across the mixer are determined experimentally to characterize the mixing performance of the mixer. The experiments show that the performance of a venturi-jet-mixer substantially improves at high injection angle and can be augmented still by increasing velocity ratio. The jet deflects much and penetrates less in the cross flow as the cross flow Reynolds number is increased. The effect could contribute substantially to the better mixing index with moderate pressure drop. Normalized jet profile, concentration decay, jet velocity profile are computed from equations of conservation of mass, momentum and concentration written in natural co-ordinate systems. The comparison between the experimental and numerical results confirms the accuracy of the simulations. Correlations for jet trajectory and entrainment ratio of the mixer are obtained by multivariate-linear regression analysis using power law.

  13. Modeling and flow analysis of pure nylon polymer for injection molding process

    Science.gov (United States)

    Nuruzzaman, D. M.; Kusaseh, N.; Basri, S.; Oumer, A. N.; Hamedon, Z.

    2016-02-01

    In the production of complex plastic parts, injection molding is one of the most popular industrial processes. This paper addresses the modeling and analysis of the flow process of the nylon (polyamide) polymer for injection molding process. To determine the best molding conditions, a series of simulations are carried out using Autodesk Moldflow Insight software and the processing parameters are adjusted. This mold filling commercial software simulates the cavity filling pattern along with temperature and pressure distributions in the mold cavity. In the modeling, during the plastics flow inside the mold cavity, different flow parameters such as fill time, pressure, temperature, shear rate and warp at different locations in the cavity are analyzed. Overall, this Moldflow is able to perform a relatively sophisticated analysis of the flow process of pure nylon. Thus the prediction of the filling of a mold cavity is very important and it becomes useful before a nylon plastic part to be manufactured.

  14. Study of Solid Particle Behavior in High Temperature Gas Flows

    Science.gov (United States)

    Majid, A.; Bauder, U.; Stindl, T.; Fertig, M.; Herdrich, G.; Röser, H.-P.

    2009-01-01

    The Euler-Lagrangian approach is used for the simulation of solid particles in hypersonic entry flows. For flow field simulation, the program SINA (Sequential Iterative Non-equilibrium Algorithm) developed at the Institut für Raumfahrtsysteme is used. The model for the effect of the carrier gas on a particle includes drag force and particle heating only. Other parameters like lift Magnus force or damping torque are not taken into account so far. The reverse effect of the particle phase on the gaseous phase is currently neglected. Parametric analysis is done regarding the impact of variation in the physical input conditions like position, velocity, size and material of the particle. Convective heat fluxes onto the surface of the particle and its radiative cooling are discussed. The variation of particle temperature under different conditions is presented. The influence of various input conditions on the trajectory is explained. A semi empirical model for the particle wall interaction is also discussed and the influence of the wall on the particle trajectory with different particle conditions is presented. The heat fluxes onto the wall due to impingement of particles are also computed and compared with the heat fluxes from the gas.

  15. Active control of flow around a square prism by slot jet injection

    Directory of Open Access Journals (Sweden)

    Hacıalioğulları M.

    2013-04-01

    Full Text Available The main aim of the experimental study is to determine both the most effective injection surface and rate in order to ensure minimum drag and fluctuating forces on a square prism subjected to crossflow. All predetermined jet injection surfaces i.e. front, side, and rear, tested separately for injection ratios of IR = 0, 1, 1.5, 2 at Reynolds number of Re = 16,000. Surface pressures were measured by differential pressure transducer whereas instantaneous velocity measurements were performed by using multichannel Constant Temperature Anemometer (CTA. It was concluded that jet injection, especially from the rear surface, brought noticeable improvements to the flow characteristics of a square prism. For rear jet configuration with IR = 1.5, the mean drag coefficient (CDT¯$overline {{C_{{m{DT}}}}} $ was reduced to 79.4% and CP RMS level on side surfaces was reduced to 20% of that of the single square prism. In addition, instantaneous flow visualization photographs and Strouhal number (St distribution across the injection ratio were also presented to identify the flow patterns and underlying mechanism of drag and fluctuating force reduction of square prism with rear jet configuration.

  16. Improvement of Power Flow Calculation with Optimization Factor Based on Current Injection Method

    Directory of Open Access Journals (Sweden)

    Lei Wang

    2014-01-01

    Full Text Available This paper presents an improvement in power flow calculation based on current injection method by introducing optimization factor. In the method proposed by this paper, the PQ buses are represented by current mismatches while the PV buses are represented by power mismatches. It is different from the representations in conventional current injection power flow equations. By using the combined power and current injection mismatches method, the number of the equations required can be decreased to only one for each PV bus. The optimization factor is used to improve the iteration process and to ensure the effectiveness of the improved method proposed when the system is ill-conditioned. To verify the effectiveness of the method, the IEEE test systems are tested by conventional current injection method and the improved method proposed separately. Then the results are compared. The comparisons show that the optimization factor improves the convergence character effectively, especially that when the system is at high loading level and R/X ratio, the iteration number is one or two times less than the conventional current injection method. When the overloading condition of the system is serious, the iteration number in this paper appears 4 times less than the conventional current injection method.

  17. Flow injection chemiluminescence determination of loxoprofen and naproxen with the acidic permanganate-sulfite system

    Institute of Scientific and Technical Information of China (English)

    Li-Juan Wang; Yu-Hai Tang; Yang-Hao Liu

    2011-01-01

    A novel flow injection chemiluminescence(CL)method for the determination of loxoprofen and naproxen was proposed based on the CL system of KMnO4 and Na2SO3 in acid media.The CL intensity of KMnO4-Na2SO3 was greatly enhanced in the presence of loxoprofen a

  18. Flow injection analysis using carbon film resistor electrodes for amperometric determination of ambroxol.

    Science.gov (United States)

    Felix, Fabiana S; Brett, Christopher M A; Angnes, Lúcio

    2008-06-30

    Flow injection analysis (FIA) using a carbon film sensor for amperometric detection was explored for ambroxol analysis in pharmaceutical formulations. The specially designed flow cell designed in the lab generated sharp and reproducible current peaks, with a wide linear dynamic range from 5x10(-7) to 3.5x10(-4) mol L(-1), in 0.1 mol L(-1) sulfuric acid electrolyte, as well as high sensitivity, 0.110 Amol(-1) L cm(-2) at the optimized flow rate. A detection limit of 7.6x10(-8) mol L(-1) and a sampling frequency of 50 determinations per hour were achieved, employing injected volumes of 100 microL and a flow rate of 2.0 mL min(-1). The repeatability, expressed as R.S.D. for successive and alternated injections of 6.0x10(-6) and 6.0x10(-5) mol L(-1) ambroxol solutions, was 3.0 and 1.5%, respectively, without any noticeable memory effect between injections. The proposed method was applied to the analysis of ambroxol in pharmaceutical samples and the results obtained were compared with UV spectrophotometric and acid-base titrimetric methods. Good agreement between the results utilizing the three methods and the labeled values was achieved, corroborating the good performance of the proposed electrochemical methodology for ambroxol analysis.

  19. Effect of gas field production and CO2 injection on brine flow and salt precipitation

    NARCIS (Netherlands)

    Loeve, D.; Tambach, T.J.; Hofstee, C.; Plug, W.J.; Maas, J.

    2012-01-01

    This paper reports modeling of gas field produc-tion and CO2 injection from a theoretical reser-voir based on characteristics of the P18 gas field in the Dutch offshore, which consists of four geological deposits with different petrophysical properties. We especially focus on the brine flow during

  20. Effect of CO2 injection on brine flow and salt precipitation after gas field production

    NARCIS (Netherlands)

    Tambach, T.J.; Loeve, D.; Hofstee, C.; Plug, W.J.; Maas, J.G.

    2014-01-01

    This paper reports modeling of gas field production and CO2 injection in a theoretical reservoir based on characteristics of the P18 gas field in the Dutch offshore, which consists of four geological deposits with different petrophysical properties. We especially focus on the brine flow during and

  1. Assessing cement injection behaviour in cancellous bone: an in vitro study using flow models.

    Science.gov (United States)

    Bou-Francis, Antony; López, Alejandro; Persson, Cecilia; Hall, Richard M; Kapur, Nikil

    2014-10-01

    Understanding the cement injection behaviour during vertebroplasty and accurately predicting the cement placement within the vertebral body is extremely challenging. As there is no standardized methodology, we propose a novel method using reproducible and pathologically representative flow models to study the influence of cement properties on injection behaviour. The models, confined between an upper glass window and a lower aluminium plate, were filled with bone marrow substitute and then injected (4, 6 and 8 min after cement mixing) with commercially available bone cements (SimplexP, Opacity+, OsteopalV and Parallax) at a constant flow rate (3 mL/min). A load cell was used to measure the force applied on the syringe plunger and calculate the peak pressure. A camera was used to monitor the cement flow during injection and calculate the following parameters when the cement had reached the boundary of the models: the time to reach the boundary, the filled area and the roundness. The peak pressure was comparable to that reported during clinical vertebroplasty and showed a similar increase with injection time. The study highlighted the influence of cement formulations and model structure on the injection behaviour and showed that cements with similar composition/particle size had similar flow behaviour, while the introduction of defects reduced the time to reach the boundary, the filled area and the roundness. The proposed method provides a novel tool for quick, robust differentiation between various cement formulations through the visualization and quantitative analysis of the cement spreading at various time intervals. © The Author(s) 2014 Reprints and permissions: sagepub.co.uk/journalsPermissions.nav.

  2. Laminar flow at a three-dimensional stagnation point with large rates of injection

    Science.gov (United States)

    Libby, P. A.

    1976-01-01

    Exact calculations of the titled flow are presented and compared to the predictions of an asymptotic analysis for large rates of injection. The inner layer of the boundary layer is found to involve outflow in both orthogonal directions whether the external flow along the y axis is inward or outward. As a result, the flow at a nearly two-dimensional stagnation point involves drastic changes as a weak outflow changes to a weak inflow. It is also found that the velocity profiles in the two directions in the inner layer are quite different.

  3. Linear stability analysis of Poiseuille flow in porous medium with small suction and injection

    CERN Document Server

    Hinvi, L A; Orou, J B Chabi

    2014-01-01

    We investigate the effect of small suction Reynolds number and permeability parameter on the stability of Poiseuille fluid flow in a porous medium between two parallel horizontal stationary porous plates . We have shown that the perturbed flow is governed by an equation named modified Orr-Sommerfeld equation. We find also that the normalization of the wall-normal velocity with characteristic small suction (or small injection) velocity is important for a perfect command of porous medium fluid flow stability analysis. The stabilizing effect of the parameters in general and small suction Reynolds number and permeability parameters in particular on the linear stability are found.

  4. Eulerian numerical simulation of gas-solid flows with several particles species; Modelisation numerique eulerienne des ecoulements gaz-solide avec plusieurs especes de particules

    Energy Technology Data Exchange (ETDEWEB)

    Patino-Palacios, G

    2007-11-15

    The simulation of the multiphase flows is currently an important scientific, industrial and economic challenge. The objective of this work is to improve comprehension via simulations of poly-dispersed flows and contribute the modeling and characterizing of its hydrodynamics. The study of gas-solid systems involves the models that takes account the influence of the particles and the effects of the collisions in the context of the momentum transfer. This kind of study is covered on the framework of this thesis. Simulations achieved with the Saturne-polyphasique-Tlse code, developed by Electricite de France and co-worked with the Institut de Mecanique des Fluides de Toulouse, allowed to confirm the feasibility of approach CFD for the hydrodynamic study of the injectors and dense fluidized beds. The stages of validation concern, on the one hand, the placement of the tool for simulation in its current state to make studies of validation and sensitivity of the models and to compare the numerical results with the experimental data. In addition, the development of new physical models and their establishments in the code Saturne will allow the optimization of the industrial process. To carry out this validation in a satisfactory way, a key simulation is made, in particular a monodisperse injection and the radial force of injection in the case of a poly-disperse flow, as well as the fluidization of a column made up of solid particles. In this last case, one approached three configurations of dense fluidized beds, in order to study the influence of the grid on simulations; then, one simulates the operation of a dense fluidized bed with which one characterizes the segregation between two various species of particles. The study of the injection of the poly-disperse flows presents two configurations; a flow Co-current gas-particle in gas (Case Hishida), and in addition, a poly-phase flow in a configuration of the jet type confined with zones of recirculation and stagnation (case

  5. From continuous flow analysis to programmable Flow Injection techniques. A history and tutorial of emerging methodologies.

    Science.gov (United States)

    Ruzicka, Jaromir Jarda

    2016-09-01

    Automation of reagent based assays, also known as Flow Analysis, is based on sample processing, in which a sample flows towards and through a detector for monitoring of its components. The Achilles heel of this methodology is that the majority of FA techniques use constant continuous forward flow to transport the sample - an approach which continually consumes reagents and generates chemical waste. Therefore the purpose of this report is to highlight recent developments of flow programming that not only save reagents, but also lead by means of advanced sample processing to selective and sensitive assays based on stop flow measurement. Flow programming combined with a novel approach to data harvesting yields a novel approach to single standard calibration, and avoids interference caused by refractive index. Finally, flow programming is useful for sample preparation, such as rapid, extensive sample dilution. The principles are illustrated by selected references to an available online tutorial http://www.flowinjectiontutorial,com/.

  6. On spurious water flow during numerical simulation of steam injection into water-saturated soil.

    Science.gov (United States)

    Gudbjerg, J; Trötschler, O; Färber, A; Sonnenborg, T O; Jensen, K H

    2004-12-01

    Numerical simulation of steam injection into a water-saturated porous medium may be hindered by unphysical behavior causing the model to slow down. We show how spurious water flow may arise on the boundary between a steam zone and a saturated zone, giving rise to dramatic pressure drops. This is caused by the discretization of the temperature gradient coupled with the direct relation between pressure and temperature in the steam zone. The problem may be a severe limitation to numerical modeling. A solution is presented where the spurious water flow is blocked and this widely enhances the performance of the model. This new method is applied to a previously reported example exhibiting numerical problems. Furthermore, it is applied to the simulation of 2-D sandbox experiments where LNAPL is remediated from a smearing zone by steam injection. These experiments would have been difficult to analyze numerically without the adjustment to prevent spurious flow.

  7. Decompositions of injection patterns for nodal flow allocation in renewable electricity networks

    Science.gov (United States)

    Schäfer, Mirko; Tranberg, Bo; Hempel, Sabrina; Schramm, Stefan; Greiner, Martin

    2017-08-01

    The large-scale integration of fluctuating renewable power generation represents a challenge to the technical and economical design of a sustainable future electricity system. In this context, the increasing significance of long-range power transmission calls for innovative methods to understand the emerging complex flow patterns and to integrate price signals about the respective infrastructure needs into the energy market design. We introduce a decomposition method of injection patterns. Contrary to standard flow tracing approaches, it provides nodal allocations of link flows and costs in electricity networks by decomposing the network injection pattern into market-inspired elementary import/export building blocks. We apply the new approach to a simplified data-driven model of a European electricity grid with a high share of renewable wind and solar power generation.

  8. Numerical Analysis of Mold Deformation Including Plastic Melt Flow During Injection Molding

    Energy Technology Data Exchange (ETDEWEB)

    Jung, Joon Tae; Lee, Bong-Kee [Chonnam National University, Gwangju (Korea, Republic of)

    2014-07-15

    In the present study, a numerical analysis of an injection molding process was conducted for predicting the mold deformation considering non-Newtonian flow, heat transfer, and structural behavior. The accurate prediction of mold deformation during the filling stage is important to successfully design and manufacture a precision injection mold. While the local mold deformation can be caused by various factors, a pressure induced by the polymer melt is considered to be one of the most significant ones. In this regard, the numerical simulation considering both the melt filling and the mold deformation was carried out. A mold core for a 2D axisymmetric center-gated disk was used for the demonstration of the present study. The flow behavior inside the mold cavity and temperature distribution were analyzed along with the core displacement. Also, a Taguchi method was employed to investigate the influence of the relevant parameters including flow velocity, mold core temperature, and melt temperature.

  9. Laminar flow across an unbounded square cylinder with suction or injection

    Science.gov (United States)

    Pantokratoras, Asterios

    2017-02-01

    The flow around a horizontal square cylinder with uniform suction or injection at the front and rear sides is considered in the present paper. The problem is investigated numerically with a finite volume method using the SIMPLE algorithm. This flow has been investigated in the past for Reynolds numbers greater than 70. In the present work, the investigation is extended to very low Reynolds numbers (up to 0.001, Stokes flow) including eight different cases concerning suction-injection at the two sides. It is found that the drag coefficient takes negative and zero values in many cases and varies linearly at low Re numbers. In all eight cases, the vortices around the cylinder have been calculated. It is found that at low Re numbers, some vortices are symmetrical both about the horizontal and vertical cylinder axes.

  10. Optimized and validated flow-injection spectrophotometric analysis of topiramate, piracetam and levetiracetam in pharmaceutical formulations.

    Science.gov (United States)

    Hadad, Ghada M; Abdel-Salam, Randa A; Emara, Samy

    2011-12-01

    Application of a sensitive and rapid flow injection analysis (FIA) method for determination of topiramate, piracetam, and levetiracetam in pharmaceutical formulations has been investigated. The method is based on the reaction with ortho-phtalaldehyde and 2-mercaptoethanol in a basic buffer and measurement of absorbance at 295 nm under flow conditions. Variables affecting the determination such as sample injection volume, pH, ionic strength, reagent concentrations, flow rate of reagent and other FIA parameters were optimized to produce the most sensitive and reproducible results using a quarter-fraction factorial design, for five factors at two levels. Also, the method has been optimized and fully validated in terms of linearity and range, limit of detection and quantitation, precision, selectivity and accuracy. The method was successfully applied to the analysis of pharmaceutical preparations.

  11. Thermo-economic analysis of a solid oxide fuel cell and steam injected gas turbine plant integrated with woodchips gasification

    DEFF Research Database (Denmark)

    Mazzucco, Andrea; Rokni, Masoud

    2014-01-01

    This paper presents a thermo-economic analysis of an integrated biogas-fueled solid oxide fuel cell (SOFC) system for electric power generation. Basic plant layout consists of a gasification plant (GP), an SOFC and a retrofitted steam-injected gas turbine (STIG). Different system configurations...

  12. Reaction kinetics of solid fuels during entrained flow gasification

    Energy Technology Data Exchange (ETDEWEB)

    Tremel, Alexander

    2012-10-24

    meet slag requirements. Simple empirical reaction rate models that are directly derived from the entrained flow experiments are used to evaluate larger scale entrained flow gasification of other fuels. The use of Lusatian lignite results in a comparable gasifier performance. The maximum CGE of the bituminous coal in a 500 MW gasifier is 82.5 %, but a larger gasifier size compared to the lignite gasifier is required. Also, the addition of steam to the burner is considered to reduce the flame temperature. The entrained flow gasification of biocoal is simulated for a thermal fuel input of 10 MW and for an operation pressure of 0.5 MPa. If the gasifier is operated above the ash melting temperature, a maximum cold gas efficiency of 78.9 % is achieved. The potential operation of the gasifier in a non-slagging mode improves the efficiency up to 82.0 %. The experience obtained during collecting the measurement sets and the theoretical background of the model development are then used to derive a test procedure for the evaluation of entrained flow reaction behaviour of unknown (coals, residuals) and alternative (biomass, waste) solid fuels. The test procedure consists of a limited number of measurements and leads to a comprehensive data set that enables the accurate prediction of fuel conversion in larger scale entrained flow gasifiers. This will enable significantly enhanced gasifier performance in the future.

  13. A Numerical study for the efficacy of flow injection on the diminution of rudder cavitation

    Science.gov (United States)

    Seo, Dae Won; Lee, Seung-Hee; Kim, Hyo Chul; Oh, Jung Keun

    2010-06-01

    The complete avoidance of cavitation, as a result of gap flow between the fixed and movable portion of a horn type rudder system, is difficult. To reduce gap flow, it is a common practice to attach a half round prismatic bar that protrudes beyond the concave surface of the horn facing the gap and laid along the centerplane of the rudder. However the employment of such a device does not always yield satisfactory results. Previously, the authors have shown that a pair of blocking bars, attached on the convex surface of the movable portion, better enhance the blocking ability of gap flow to that of a single centre bar installed on the concave surface. This also circumvents difficulties that might occur in practical applications. In the present study, a series of numerical computations show that flow injected into the gap of a rudder may also block the flow within, without employment of any physical devices, such as a half circular bar. This study also shows that the combination of flow injection and blocking bars may result in the synergic augmentation of blocking efficiency of gap flow, as demonstrated in computations for a three dimensional rudder system.

  14. Flow electrochemical biosensors based on enzymatic porous reactor and tubular detector of silver solid amalgam

    Energy Technology Data Exchange (ETDEWEB)

    Josypčuk, Bohdan, E-mail: josypcuk@jh-inst.cas.cz [J. Heyrovský Institute of Physical Chemistry of AS CR, v.v.i., Department of Biophysical Chemistry, Dolejskova 3, Prague (Czech Republic); Barek, Jiří [Charles University in Prague, Faculty of Science, University Center of Excellence UNCE “Supramolecular Chemistry”, Department of Analytical Chemistry, UNESCO Laboratory of Environmental Electrochemistry, Albertov 6, CZ-128 43 Prague 2 (Czech Republic); Josypčuk, Oksana [J. Heyrovský Institute of Physical Chemistry of AS CR, v.v.i., Department of Biophysical Chemistry, Dolejskova 3, Prague (Czech Republic); Charles University in Prague, Faculty of Science, University Center of Excellence UNCE “Supramolecular Chemistry”, Department of Analytical Chemistry, UNESCO Laboratory of Environmental Electrochemistry, Albertov 6, CZ-128 43 Prague 2 (Czech Republic)

    2013-05-17

    Graphical abstract: -- Highlights: •Flow amperometric enzymatic biosensor was constructed. •The biosensor is based on a reactor of a novel material – porous silver solid amalgam. •Tubular amalgam detector was used for determination of decrease of O{sub 2} concentration. •Covalent bonds amalgam−thiol−enzyme contributed to the sensor long-term stability. •LOD of glucose was 0.01 mmol L{sup −1} with RSD = 1.3% (n = 11). -- Abstract: A flow amperometric enzymatic biosensor for the determination of glucose was constructed. The biosensor consists of a flow reactor based on porous silver solid amalgam (AgSA) and a flow tubular detector based on compact AgSA. The preparation of the sensor and the determination of glucose occurred in three steps. First, a self-assembled monolayer of 11-mercaptoundecanoic acid (MUA) was formed at the porous surface of the reactor. Second, enzyme glucose oxidase (GOx) was covalently immobilized at MUA-layer using N-ethyl-N′-(3-dimethylaminopropyl) carboimide and N-hydroxysuccinimide chemistry. Finally, a decrease of oxygen concentration (directly proportional to the concentration of glucose) during enzymatic reaction was amperometrically measured on the tubular detector under flow injection conditions. The following parameters of glucose determination were optimized with respect to amperometric response: composition of the mobile phase, its concentration, the potential of detection and the flow rate. The calibration curve of glucose was linear in the concentration range of 0.02–0.80 mmol L{sup −1} with detection limit of 0.01 mmol L{sup −1}. The content of glucose in the sample of honey was determined as 35.5 ± 1.0 mass % (number of the repeated measurements n = 7; standard deviation SD = 1.2%; relative standard deviation RSD = 3.2%) which corresponds well with the declared values. The tested biosensor proved good long-term stability (77% of the current response of glucose was retained after 35 days)

  15. Flow rate dependent extra-column variance from injection in capillary liquid chromatography.

    Science.gov (United States)

    Aggarwal, Pankaj; Liu, Kun; Sharma, Sonika; Lawson, John S; Dennis Tolley, H; Lee, Milton L

    2015-02-01

    Efficiency and resolution in capillary liquid chromatography (LC) can be significantly affected by extra-column band broadening, especially for isocratic separations. This is particularly a concern in evaluating column bed structure using non-retained test compounds. The band broadening due to an injector supplied with a commercially available capillary LC system was characterized from experimental measurements. The extra-column variance from the injection valve was found to have an extra-column contribution independent of the injection volume, showing an exponential dependence on flow rate. The overall extra-column variance from the injection valve was found to vary from 34 to 23 nL. A new mathematical model was derived that explains this exponential contribution of extra-column variance on chromatographic performance. The chromatographic efficiency was compromised by ∼130% for a non-retained analyte because of injection valve dead volume. The measured chromatographic efficiency was greatly improved when a new nano-flow pumping system with integrated injection valve was used.

  16. Flow-induced birefringence: the hidden PSF killer in high performance injection-molded plastic optics

    Science.gov (United States)

    Chidley, Matthew D.; Tkaczyk, Tomasz; Kester, Robert; Descour, Michael R.

    2006-02-01

    A 7-mm OD, NA = 1 water immersion injection-molded plastic endoscope objective has been fabricated for a laser scanning fiber confocal reflectance microscope (FCRM) system specifically designed for in vivo detection of cervical and oral pre-cancers. Injection-molded optics was selected for the ability to incorporate aspheric surfaces into the optical design and its high volume capabilities. Our goal is high performance disposable endoscope probes. This objective has been built and tested as a stand-alone optical system, a Strehl ratio greater than 0.6 has been obtained. One of the limiting factors of optical performance is believed to be flow-induced birefringence. We have investigated different configurations for birefringence visualization and believe the circular polariscope is most useful for inspection of injection-molded plastic optics. In an effort to decrease birefringence effects, two experiments were conducted. They included: (1) annealing of the optics after fabrication and (2) modifying the injection molding prameters (packing pressures, injection rates, and hold time). While the second technique showed improvement, the annealing process could not improve quality without physically warping the lenses. Therefore, to effectively reduce flow-induced birefringence, molding conditions have to be carefully selected. These parameters are strongly connected to the physical part geometry. Both optical design and fabrication technology have to be considered together to deliver low birefringence while maintaining the required manufacturing tolerances. In this paper we present some of our current results that illustrate how flow-induced birefringence can degrade high performance injection-molded plastic optical systems.

  17. Computing equations of water hammer in pseudo-homogeneous solid-liquid flow and their verification

    Institute of Scientific and Technical Information of China (English)

    2000-01-01

    In engineering practice, single-phase water hammer models are still employed to analyze the water hammer of solid-liquid flow. According to the characteristics of solid-liquid flow, continuity equations and momentum equations of pseudo-homogeneous flows are deduced, and a pseudo-homogeneous water hammer model is thus built and verified with experiment results. The characteristics of solid-liquid flow's viscosity, resistance and wave velocity are considered in the model. Therefore, it has higher precision than a single-phase model.

  18. Gas-solid flows - 1986; Proceedings of the Fourth Fluid Mechanics, Plasma Dynamics, and Lasers Conference, Atlanta, GA, May 11-14, 1986

    Science.gov (United States)

    Jurewicz, J. T.

    Papers are presented on deposition and resuspension of gas-borne particles in recirculating turbulent flows, particle dispersion in decaying isotropic homogeneous turbulence, turbulent dispersion of droplets for air flow in a pipe, a comparison between Lagrangian and Eulerian model approaches to turbulent particle dispersion, and the effect of turbulent electrohydrodynamics on electrostatic precipitator efficiency. Also considered are errors due to turbidity in particle sizing using laser Doppler velocimetry, particle motion in a fluidically oscillating jet, high pressure steam/water jet measurements using a portable particle sizing laser Doppler system, the effect of particle shape on pressure drop in a turbulent gas/solid suspension, and the experimental study of gas solid flows in pneumatic conveying. Other topics include entropy production and pressure loss in gas-solid flows, a computational study of turbulent gas-particle flow in a Venturi, a numerical analysis of confined recirculating gas-solid turbulent flows, nozzle and free jet flows of gas particle mixtures, and particle separation in pulsed airflow. Papers are also presented on sampling of solid particles in clouds, particle motion near the inlet of a sampling probe, the effects of slot injection on blade erosion in direct coal-fueled gas turbines, bed diameter effects and incipient slugging in gas fluidized beds, and sedimentation of air fluidized fine graphite particles by methanol vapor.

  19. Flow Injection and Atomic Absorption Spectrometry - An Effective and Attractive Analytical Chemical Combination

    DEFF Research Database (Denmark)

    Hansen, Elo Harald; Nielsen, Steffen

    1998-01-01

    One of the advantages of the flow injection (FI) concept is that it is compatible with virtually all detection techniques. Being a versatile vehicle for enhancing the performance of the individual detection devices, the most spectacular results have possibly been obtained in conjunction with atomic...... is subjected to in FI from the point of injection/introduction to the point of detection, which in turn allows suitable on-line pretreatments to be effected. The present paper will - via a number of selected examples - point to some of the potentials at hand, encompassing the use of FI as a suitable vehicle...

  20. Determination of cyanide in microsamples by means of capillary flow injection analysis with amperometric detection

    Energy Technology Data Exchange (ETDEWEB)

    Backofen, U. [Leipzig Univ. (Germany). Sektion 8 - Chemie; Matysik, F.-M. [Department of Chemistry, University of Coimbra (Portugal); Werner, G. [Leipzig Univ. (Germany). Sektion 8 - Chemie

    1996-10-01

    A new approach for determining cyanide in microsamples is described. The method is based on capillary flow injection analysis (CFIA) with amperometric detection. The sensing electrode is a silver-plated microdisk electrode, where cyanide can react under formation of a dicyanoargentate complex. A remarkably low mass detection limit of 231 fmol cyanide is obtained for an injection volume of 60 nl. The sample throughput of the CFIA-arrangement is comparable with a conventional sized FIA-system. A practical application is given by analyzing the cyanide (amygdalin) concentration in apple kernels. (orig.). With 5 figs.

  1. Flow injection online spectrophotometric determination of uranium after preconcentration on XAD-4 resin impregnated with nalidixic acid.

    Science.gov (United States)

    Shahida, Shabnam; Ali, Akbar; Khan, Muhammad Haleem; Saeed, Muhammad Mufazzal

    2013-02-01

    In this work, spectrophotometer was used as a detector for the determination of uranium from water, biological, and ore samples with a flow injection system coupled with solid phase extraction. In order to promote the online preconcentration of uranium, a minicolumn packed with XAD-4 resin impregnated with nalidixic acid was utilized. The system operation was based on U(VI) ion retention at pH 6 in the minicolumn at flow rate of 15.2 mL min(-1). The uranium complex was removed from the resin by 0.1 mol dm(-3) HCl at flow rate of 3.2 mL min(-1) and was mixed with arsenazo III solution (0.05 % solution in 0.1 mol dm(-3) HCl, 3.2 mL min(-1)) and driven to flow through cell of spectrophotometer where its absorbance was measured at 651 nm. The influence of chemical (pH and HCl (as eluent and reagent medium) concentration) and flow (sample and eluent flow rate and preconcentration time) parameters that could affect the performance of the system as well as the possible interferents was investigated. At the optimum conditions for 60 s preconcentration time (15.2 mL of sample volume), the method presented a detection limit of 1.1 μg L(-1), a relative standard deviation (RSD) of 0.8 % at 100 μg L(-1), enrichment factor of 30, and a sample throughput of 42 h(-1), whereas for 300 s of the preconcentration time (76 mL of sample volume), a detection limit of 0.22 μg L(-1), a RSD of 1.32 % at 10 μg L(-1), enrichment factor of 150, and a sampling frequency of 11 h(-1) were reported.

  2. Parameters Relevant to Bubble Detachment when Gas-injecting into Polymer Melt Flow Field

    Institute of Scientific and Technical Information of China (English)

    CHEN Zailiang; CAI Yebin; GUO Mingcheng; PENG Yucheng

    2005-01-01

    The bubble deformation processes were reported when gas was injected into polymer melt flow field in another paper, the experiments showed that the deformation was severely affected by the volume of the bubble, and in turn, for the different bubbles, several different deformation processes were presented during their movement along the flow channel. In addition, we could find that the magnitude of the bubble volume was dependent upon the pressure difference of the gas injection pressure and the melt pressure. In this paper, more experimental conditions were changed to investigate the parameters relevant to the detachment of bubbles from the injection nozzle. The experimental results show that the pressure difference, the melt flow velocity as well as the melt pressure were all critical for the parameters, such as the bubble detachment time, the maximum bubble diameters and the magnitude of the bubble volume. The morphology changes of bubble were very large when the flow field was abruptly changed, and the situations were more complicated.

  3. Flow visualization study of the effect of injection hole geometry on an inclined jet in crossflow

    Science.gov (United States)

    Simon, Frederick F.; Ciancone, Michael L.

    A flow visualization was studied by using neutrally buoyant, helium-filled soap bubbles, to determine the effect of injection hole geometry on the trajectory of an air jet in a crossflow and to investigate the mechanisms involved in jet deflection. Experimental variables were the blowing rate, and the injection hole geometry cusp facing upstream (CUS), cusp facing downstream (CDS), round, swirl passage, and oblong. It is indicated that jet deflection is governed by both the pressure drag forces and the entrainment of free-stream fluid into the jet flow. For injection hole geometries with similar cross-sectional areas and similar mass flow rates, the jet configuration with the larger aspect ratio experienced a greater deflection. Entrainment arises from lateral shearing forces on the sides of the jet, which set up a dual vortex motion within the jet and thereby cause some of the main-stream fluid momentum to be swept into the jet flow. This additional momentum forces the jet nearer the surface. Of the jet configurations, the oblong, CDS, and CUS configurations exhibited the largest deflections. The results correlate well with film cooling effectiveness data, which suggests a need to determine the jet exit configuration of optimum aspect ratio to provide maximum film cooling effectiveness.

  4. Development of mediated BOD biosensor system of flow injection mode for shochu distillery wastewater.

    Science.gov (United States)

    Oota, Shinichi; Hatae, Yuta; Amada, Kei; Koya, Hidekazu; Kawakami, Mitsuyasu

    2010-09-15

    Although microbial biochemical oxygen demand (BOD) sensors utilizing redox mediators have attracted much attention as a rapid BOD measurement method, little attempts have been made to apply the mediated BOD biosensors to the flow injection analysis system. In this work, a mediated BOD sensor system of flow injection mode, constructed by combining an immobilized microbial reactor with an electrochemical flow cell of three electrodes configuration, has been developed to estimate BOD of shochu distillery wastewater (SDW). It was demonstrated consequently that the mediated sensing was realized by employing phosphate buffer containing potassium hexacyanoferrate as the carrier. The output current was found to yield a peak with a sample injection, and to result from reoxidation of reduced mediator at the electrode. By employing the peak area as the sensor response, the effects of flow rate and pH of the carrier on the sensitivity were investigated. The sensor system using a microorganism of high SDW-assimilation capacity showed good performance and proved to be available for estimation of BOD of SDW.

  5. RESEARCH ON METHOD TO CALCULATE VELOCITIES OF SOLID PHASE AND LIQUID PHASE IN DEBRIS FLOW

    Institute of Scientific and Technical Information of China (English)

    2006-01-01

    Velocities of solid phase and liquid phase in debris flow are one key problem to research on impact and abrasion mechanism of banks and control structures under action of debris flow. Debris flow was simplified as two-phase liquid composed of solid phase with the same diameter particles and liquid phase with the same mechanical features. Assume debris flow was one-dimension two-phase liquid moving to one direction,then general equations of velocities of solid phase and liquid phase were founded in twophase theory. Methods to calculate average pressures, volume forces and surface forces of debris flow control volume were established. Specially, surface forces were ascertained using Bingham's rheology equation of liquid phase and Bagnold's testing results about interaction between particles of solid phase. Proportional coefficient of velocities between liquid phase and solid phase was put forward, meanwhile, divergent coefficient between theoretical velocity and real velocity of solid phase was provided too. To state succinctly before, method to calculate velocities of solid phase and liquid phase was obtained through solution to general equations. The method is suitable for both viscous debris flow and thin debris flow. Additionally, velocities every phase can be identified through analyzing deposits in-situ after occurring of debris flow. It is obvious from engineering case the result in the method is consistent to that in real-time field observation.

  6. Flow injection fluorescence determination of dopamine using a photo induced electron transfer (PET) boronic acid derivative

    Energy Technology Data Exchange (ETDEWEB)

    Ebru Seckin, Z. [Department of Chemistry, Middle East Technical University, 06531 Ankara (Turkey); Volkan, Muervet [Department of Chemistry, Middle East Technical University, 06531 Ankara (Turkey)]. E-mail: murvet@metu.edu.tr

    2005-08-15

    An automated flow injection analysis system was developed for the fluorometric determination of dopamine in pharmaceutical injections. The method is based on the quenching effect of dopamine on m-dansylaminophenyl boronic acid (DAPB) fluorescence due to the reverse photo induced electron transfer (PET) mechanism. Effects of pH and interfering species on the determination of dopamine were examined. Calibration for dopamine, based on quenching data, was linear in the concentration range of 1.0 x 10{sup -5} to 1.0 x 10{sup -4} M. Detection limit (3 s) of the method was found to be 3.7 x 10{sup -6} M. Relative standard deviation of 1.2% (n = 10) was obtained with 1.0 x 10{sup -5} M dopamine standard solution. The proposed method was applied successfully for the determination of dopamine in pharmaceutical injection sample. The sampling rate was determined as 24 samples per hour.

  7. PIV MEASUREMENT OF THE GAS-SOLID FLOW PATTERN IN A CFB RISER

    Institute of Scientific and Technical Information of China (English)

    Shi Hui-xian; Wang Qin-hui; Wang Can-xing; Luo Zhong-yang; Cen Ke-fa

    2003-01-01

    Particle Imaging Velocimetry (PIV) is a valuable measuring tool for studying multiphase flows, such as liquid-gas and gas-solid flow. It can be used to carry out many hydrodynamic studies, in particular, to determine accurately the gas-solid flow structure in CFB (Circulating Fluidized Beds). In this paper, the technique characteristics was described in applying the PIV to measure the gas-solid flow in circulating fluidized beds. A primary experiment was completed on a CFB unit with the PIV, yielding the velocity vector fields of high-density particles for different gas-solid superficial velocities and solid recycle rates. Velocities of the transported particles were calculated with cross-correlation method. The major factors influencing the successful measurement of particle velocity with the PIV technique were also described.

  8. Water hammer in coarse-grained solid-liquid flows in hydraulic hoisting for ocean mining

    Institute of Scientific and Technical Information of China (English)

    韩文亮; 王光谦; 吴保生; 刘少军; 邹伟生

    2002-01-01

    The particles of polymetallic nodules in hydraulic hoisting flows that are used for mining in deep sea are rather coarse, therefore their flow velocity is smaller than that of the surrounding water. The characteristics of solid-liquid flows such as their density, concentration, elastic modulus and resistance were discussed. The wave propagation speed and the continuity and momentum equations of water hammer in coarse-grained solid-liquid flows were theoretically derived, and a water hammer model for such flows was developed.

  9. Testing and comparison of four ionic tracers to measure stream flow loss by multiple tracer injection

    Science.gov (United States)

    Zellweger, G.W.

    1994-01-01

    An injectate containing lithium, sodium, chloride and bromide was added continuously at five sites along a 507 m study reach of St Kevin Gulch, Lake County, Colorado to determine which sections of the stream were losing water to the stream bed and to ascertain how well the four tracers performed. The acidity of the stream (pH 3.6) made it possible for lithium and sodium, which are normally absorbed by ion exchange with stream bed sediment, to be used as conservative tracers. Net flow losses as low as 0.81 s-1, or 8% of flow, were calculated between measuring sites. By comparing the results of simultaneous injection it was determined whether subsections of the study reach were influent or effluent. Evaluation of tracer concentrations along 116 m of stream indicated that all four tracers behaved conservatively. Discharges measured by Parshall flumes were 4-18% greater than discharges measured by tracer dilution. -from Author

  10. Recent Development in Optical Chemical Sensors Coupling with Flow Injection Analysis

    Directory of Open Access Journals (Sweden)

    Fuensanta Sánchez Rojas

    2006-10-01

    Full Text Available Optical techniques for chemical analysis are well established and sensors based on thesetechniques are now attracting considerable attention because of their importance in applications suchas environmental monitoring, biomedical sensing, and industrial process control. On the other hand,flow injection analysis (FIA is advisable for the rapid analysis of microliter volume samples and canbe interfaced directly to the chemical process. The FIA has become a widespread automatic analyticalmethod for more reasons; mainly due to the simplicity and low cost of the setups, their versatility, andease of assembling. In this paper, an overview of flow injection determinations by using opticalchemical sensors is provided, and instrumentation, sensor design, and applications are discussed. Thiswork summarizes the most relevant manuscripts from 1980 to date referred to analysis using opticalchemical sensors in FIA.

  11. Irreversibility analysis of magneto-hydrodynamic nanofluid flow injected through a rotary disk

    Directory of Open Access Journals (Sweden)

    Rashidi Mohammad Mehdi

    2015-01-01

    Full Text Available The non-linear Navier-Stokes equations governed on the nanofluid flow injected through a rotary porous disk in the presence of an external uniform vertical magnetic field can be changed to a system of non-linear partial differential equations by applying similar parameter. In this study, partial differential equations are analytically solved by the modified differential transform method, Pade differential transformation method to obtain self-similar functions of motion and temperature. A very good agreement is observed between the obtained results of Pade differential transformation method and those of previously published ones. Then it has become possible to do a comprehensive parametric analysis on the entropy generation in this case to demonstrate the effects of physical flow parameters such as magnetic interaction parameter, injection parameter, nanoparticle volume fraction, dimensionless temperature difference, rotational Brinkman number and the type of nanofluid on the problem.

  12. Flow-Injection Amperometric Determination of Tacrine based on Ion Transfer across a Water–Plasticized Polymeric Membrane Interface

    OpenAIRE

    Rueda, C.; Joaquin A. Ortuño

    2007-01-01

    A flow-injection pulse amperometric method for determining tacrine, based on ion transfer across a plasticized poly(vinyl chloride) (PVC) membrane, was developed. A four-electrode potentiostat with ohmic drop compensation was used, while a flow-through cell incorporated the four electrodes and the membrane, which contained tetrabutylammonium tetraphenylborate. The influence of the applied potential and of the flow-injection variables on the determination of tacrine was studied. In the selecte...

  13. Fast Vortex Method for the Simulation of Flows Inside Channels With and Without Injection

    Institute of Scientific and Technical Information of China (English)

    YvesGAGNON; HUANGWeiguang

    1993-01-01

    A fast vortex method is presented for the simulation of fluid flows inside two-dimensional channels,The first channel studied is formed by two parallel walls simulating the entrance length of a developing flow.The second channel is similar to the first one but with an injection of a secondary fluid through a slot on one of its walls,In both cases,results are presented for flows at low Reynolds numbers and for flows at a high Reynolds number The numerical method used is based on the Random Vortex Method and on the Vortex-In-Cell Algorithm.Physical analyses of the numerical results are also presented.mostly in application to film cooling.

  14. Numerical Simulation of Magnetic Nanoparticles Injection into Two–phase Flow in a Porous Medium

    KAUST Repository

    El-Amin, Mohamed

    2017-06-09

    In this paper, the problem of magnetic nanoparticles injection into a water–oil two–phase flow under an external permanent magnetic field is investigated. The mathematical model of the problem under consideration has been developed. We treat the water-nanoparticles suspension as a miscible mixture while it is immiscible with the oil phase. The magnetized phase pressure includes an additional pressure term with the conventional thermodynamic pressure. The countercurrent imbibition flow problem is taken as an example. Physical variables including water–nanoparticles suspension saturation, nanoparticles concentration, and pore wall/throat deposited nanoparticles are investigated under the influence of the magnetic field.

  15. Determination of Ciprofloxacin by Flow Injection Analysis Based on Chemiluminescence System

    Institute of Scientific and Technical Information of China (English)

    2006-01-01

    A novel flow injection chemiluminescence (CL) method for the determination of ciprofloxacin (CPLX) was reported. The proposed method is based on luminescence produced by KMnO4-Na2S2O4-Tb3+-CPLX chemiluminescence (CL) system. The effects of some critical experimental conditions were discussed and the optimization of working condithe recoveries of real sample analyses were in the range from 110 ± 4 to 104 ± 4.

  16. Theoretical considerations of Flow Injection Analysis in the Absence of Chemical Reactions

    DEFF Research Database (Denmark)

    Andersen, Jens Enevold Thaulov

    2000-01-01

    The fundamental mechanism of flow injection analysis (FIA) is assumed to be simple dissusion and the response of the detector is included in a model description that provide information about the shape of the FIA peak in terms of, basically, five parameters. Two of the five parameters are associa...... that any deviation from the features of the present model and the results of a tentative chemical reaction with one of the test compounds, is related to chemical kinetics....

  17. Modulating flow and aerodynamic characteristics of a square cylinder in crossflow using a rear jet injection

    Science.gov (United States)

    Huang, Rong F.; Hsu, Ching M.; Chen, Yu T.

    2017-01-01

    The temporally evolved flow behaviors around a square cylinder subject to modulation of a planar jet issued from the cylinder's downstream surface into the wake were studied using the laser-assisted smoke flow visualization method and synchronized hot-wire anemometers. The drag force asserted on the square cylinder was obtained by measuring the surface pressures. Four characteristic flow modes (wake-dominated, transitional, critical, and jet-dominated) were observed in different regimes of freestream Reynolds number and jet injection ratio. In the wake-dominated mode, the jet swung periodically back and forth on the downstream surface due to the wake vortex shedding. In the transitional mode, the vortex shedding in the wake vanished so that the flow around the cylinder presented no periodic oscillations. In the critical mode, the wake width became smaller and therefore made the vortex shedding frequency larger than that observed in the wake dominated mode. In the jet-dominated mode, the jet had a large momentum that entrained wake fluids and therefore stabilized the instabilities of the wake, separated boundary layers on lateral surfaces, and stagnation point on the upstream surface. Two standing vortices appeared in the near wake beside the high-momentum jet. The width of the wake was decreased substantially by jet entrainment. The drag coefficient decreased with an increase in the jet injection ratio. The downstream surface jet injection caused the pressure coefficients to decrease at the upstream surface and to increase at the downstream surface. Therefore, the drag coefficients were decreased significantly by 26%, 33%, and 38% at the injection ratios of 0.5, 1.5, and 2.5, respectively.

  18. A lactose flow injection analysis biosensor system for monitoring and process control

    OpenAIRE

    2004-01-01

    In this work an enzymatic lactose biosensor composed of the immobilized enzymes E- galactosidase and glucose oxidase was developed. Oxygen consumption during the reaction catalyzed by these enzymes was detected. The biosensor was integrated into an FIA (flow injection analysis) system that allows measurement of lactose on-line in less than three minutes. This biosensor was used to monitor lactose concentration during the production of E-galactosidase by the yeast Kluyveromyces marxianus from ...

  19. Micelle-mediated methodology for the preconcentration of uranium prior to its determination by flow injection

    Energy Technology Data Exchange (ETDEWEB)

    Fernandez Laespada, M.E.; Perez Pavon, J.L.; Moreno Cordero, B. (Univ. de Salamanca (Spain). Dept. de Quimica Analitica, Nutricion y Bromatologia)

    1993-02-01

    Cloud point extraction has been used for the preconcentration of uranium, prior to its determination by flow injection. The non-ionic surfactant employed was Triton X-114 and the reagent chosen to form a hydrophobic chelate of uranium was 1-(2-pyridylazo)-2-naphthol. The optimum conditions for the preconcentration and determination of uranium have been studied. This methodology has been applied to the determination of trace amounts of uranium in tap and river waters from Salamanca. (Author).

  20. Direct microcomputer controlled determination of zinc in human serum by flow injection atomic absorption spectrometry

    DEFF Research Database (Denmark)

    Simonsen, Kirsten Wiese; Nielsen, Bent; Jensen, Arne

    1986-01-01

    A procedure is described for the direct determination of zinc in human serum by fully automated, microcomputer controlled flow injection atomic absorption spectrometry (Fl-AAS). The Fl system is pumpless, using the negative pressure created by the nebuliser. It only consists of a three-way valve......, programmable from the microcomputer, to control the sample volume. No pre-treatment of the samples is necessary. The limit of detection is 0.14 mg l–1, and only small amounts of serum (

  1. Potentiometric electronic tongue-flow injection analysis system for the monitoring of heavy metal biosorption processes.

    Science.gov (United States)

    Wilson, D; del Valle, M; Alegret, S; Valderrama, C; Florido, A

    2012-05-15

    An automated flow injection potentiometric (FIP) system with electronic tongue detection (ET) is used for the monitoring of biosorption processes of heavy metals on vegetable wastes. Grape stalk wastes are used as biosorbent to remove Cu(2+) ions in a fixed-bed column configuration. The ET is formed by a 5-sensor array with Cu(2+) and Ca(2+)-selective electrodes and electrodes with generic response to heavy-metals, plus an artificial neural network response model of the sensor's cross-response. The real-time monitoring of both the Cu(2+) and the cation exchanged and released (Ca(2+)) in the effluent solution is performed by using flow-injection potentiometric electronic tongue system. The coupling of the electronic tongue with automation features of the flow-injection system allows us to accurately characterize the Cu(2+) ion-biosorption process, through obtaining its breakthrough curves, and the profile of the Ca(2+) ion release. In parallel, fractions of the extract solution are analysed by spectroscopic techniques in order to validate the results obtained with the reported methodology. The sorption performance of grape stalks is also evaluated by means of well-established sorption models.

  2. Flow injection based microfluidic device with carbon nanotube electrode for rapid salbutamol detection.

    Science.gov (United States)

    Karuwan, Chanpen; Wisitsoraat, Anurat; Maturos, Thitima; Phokharatkul, Disayut; Sappat, Assawapong; Jaruwongrungsee, Kata; Lomas, Tanom; Tuantranont, Adisorn

    2009-09-15

    A microfabicated flow injection device has been developed for in-channel electrochemical detection (ECD) of a beta-agonist, namely salbutamol. The microfluidic system consists of PDMS (polydimethylsiloxane) microchannel and electrochemical electrodes formed on glass substrate. The carbon nanotube (CNT) on gold layer as working electrode, silver as reference electrode and platinum as auxiliary electrode were deposited on a glass substrate. Silver, platinum, gold and stainless steel catalyst layers were coated by DC-sputtering. CNTs were then grown on the glass substance by thermal chemical vapor deposition (CVD) with gravity effect and water-assisted etching. 100-microm-deep and 500-microm-wide PDMS microchannels fabricated by SU-8 molding and casting were then bonded on glass substrate by oxygen plasma treatment. Flow injection and ECD of salbutamol was performed with the amperometric detection mode for in-channel detection of salbutamol. The influences of flow rate, injection volume, and detection potential on the response of current signal were optimized. Analytical characteristics, such as sensitivity, repeatability and dynamic range have been evaluated. Fast and highly sensitive detection of salbutamol have been achieved. Thus, the proposed combination of the efficient CNT electrode and miniaturized lab-on-a-chip is a powerful platform for beta-agonists detection.

  3. Simulation model for jet flow in liquid injection system of CANDU-6 SDS 2

    Energy Technology Data Exchange (ETDEWEB)

    Che, K. M.; Yoo, S. Y. [Chungnam National Univ., Taejon (Korea, Republic of); Lee, B. W.; Choi, H. B. [KAERI, Taejon (Korea, Republic of)

    2000-10-01

    For the performance analysis of the secondary shutdown system (SDS-2), a computational fluid dynamics (CFD) model for the poison jet flow is being developed to analyze the flow and poison concentration fields formed inside the moderator tank. As the ratio between Calandria shell and the nozzle hole diameter of the injection system is so big as 1055, it is impractical to develop a full size model encompassing the whole Calandria tank. To reduce the model to a manageable size, a quarter of the five-lattice-pitch length segment of the tank was modeled by using the symmetric nature of the jet and the injected jet was treated as source term to remove the limit caused by the small diameter of the injection nozzle hole, when the grid of the calculation domain was generated. A half model calculation was performed to show the symmetricity of the quarter model. For the validation of the source treatment of the inlet flow condition, the simulation result was compared with the experimental data of the gas jet. The symmetricity was confirmed by the results of simulation the half model calculation on the symmetric line and the result of simulation for the source treatment well agreed with the experiment when a fine mesh grid structure was used near the inlet.

  4. Computing equations of water hammer in pseudo-homogeneous solid-liquid flow and their verification

    Institute of Scientific and Technical Information of China (English)

    韩文亮; 董曾南; 柴宏恩; 韩军

    2000-01-01

    In engineering practice, single-phase water hammer models are still employed to analyze the water hammer of solid-liquid flow. According to the characteristics of solid-liquid flow, continuity equations and momentum equations of pseudo-homogeneous flows are deduced, and a pseudo-homogeneous water hammer model is thus built and verified with experiment results. The characteristics of solid-liquid flow’s viscosity, resistance and wave velocity are considered in the model. Therefore, it has higher precision than a single-phase model.

  5. Study on characteristics of bias caused by FI-CE split flow electrokinetic injection

    Institute of Scientific and Technical Information of China (English)

    Luo Jinwen; Zhu Hailin; Li Huilin

    2006-01-01

    The characteristics of bias caused by split-flow electrokinetic injection(SEKI),a new type of sample injection method used in coupled flow injection-capillary electrophoresis system(FI-CE),was investigated using pseudoephedrine hydrochloride,a basic drug,and ibuprofen,an acidic drug,as model analytes.It was found that bias imposed by SEKI under the condition of continuous sample matrix/running buffer was similar to that done by electrokinetic injection(EKI).The linearity of calibration curve provided by SEKI was similar to that offered by non-bias hydrodynamic injection(HDI)but significantly better than that obtained by EKI.These features were exploited to improve analytical performances in simultaneous determination of the minor ingredient of pseudoephedrine hydrochloride and the major ingredient of ibuprofen in a pharmaceutical preparation.Detectability of 0.7 mg/l for pseudoephedrine hydrochloride was achieved at a sample throughput rate of 24 times per hour,which is 30%lower than that obtained by HDI-based conventional CE.Relative standard deviations(RSDs)of 2.8%for the minor ingredient and 1.2%for the major ingredient were produced in 11 runs of a test solution containing 13.1 mg/l pseudoephedrine hydrochloride and 81.4 mg/l ibuprofen.This is an improvement compared to that obtained by HDI-based conventional CE.Analytical results for two batches of compound ibuprofen tablets by the SEKI-based FI-CE approach were in good agreement with that obtained by a conventional high performance liquid chromatographic method.

  6. Development of a Computational Framework on Fluid-Solid Mixture Flow Simulations for the COMPASS Code

    Science.gov (United States)

    Zhang, Shuai; Morita, Koji; Shirakawa, Noriyuki; Yamamoto, Yuichi

    The COMPASS code is designed based on the moving particle semi-implicit method to simulate various complex mesoscale phenomena relevant to core disruptive accidents of sodium-cooled fast reactors. In this study, a computational framework for fluid-solid mixture flow simulations was developed for the COMPASS code. The passively moving solid model was used to simulate hydrodynamic interactions between fluid and solids. Mechanical interactions between solids were modeled by the distinct element method. A multi-time-step algorithm was introduced to couple these two calculations. The proposed computational framework for fluid-solid mixture flow simulations was verified by the comparison between experimental and numerical studies on the water-dam break with multiple solid rods.

  7. Flow Mapping in a Gas-Solid Riser via Computer Automated Radioactive Particle Tracking (CARPT)

    Energy Technology Data Exchange (ETDEWEB)

    Muthanna Al-Dahhan; Milorad P. Dudukovic; Satish Bhusarapu; Timothy J. O' hern; Steven Trujillo; Michael R. Prairie

    2005-06-04

    Statement of the Problem: Developing and disseminating a general and experimentally validated model for turbulent multiphase fluid dynamics suitable for engineering design purposes in industrial scale applications of riser reactors and pneumatic conveying, require collecting reliable data on solids trajectories, velocities ? averaged and instantaneous, solids holdup distribution and solids fluxes in the riser as a function of operating conditions. Such data are currently not available on the same system. Multiphase Fluid Dynamics Research Consortium (MFDRC) was established to address these issues on a chosen example of circulating fluidized bed (CFB) reactor, which is widely used in petroleum and chemical industry including coal combustion. This project addresses the problem of lacking reliable data to advance CFB technology. Project Objectives: The objective of this project is to advance the understanding of the solids flow pattern and mixing in a well-developed flow region of a gas-solid riser, operated at different gas flow rates and solids loading using the state-of-the-art non-intrusive measurements. This work creates an insight and reliable database for local solids fluid-dynamic quantities in a pilot-plant scale CFB, which can then be used to validate/develop phenomenological models for the riser. This study also attempts to provide benchmark data for validation of Computational Fluid Dynamic (CFD) codes and their current closures. Technical Approach: Non-Invasive Computer Automated Radioactive Particle Tracking (CARPT) technique provides complete Eulerian solids flow field (time average velocity map and various turbulence parameters such as the Reynolds stresses, turbulent kinetic energy, and eddy diffusivities). It also gives directly the Lagrangian information of solids flow and yields the true solids residence time distribution (RTD). Another radiation based technique, Computed Tomography (CT) yields detailed time averaged local holdup profiles at

  8. Numerical Modeling of Interstitial Fluid Flow Coupled with Blood Flow through a Remodeled Solid Tumor Microvascular Network.

    Directory of Open Access Journals (Sweden)

    M Soltani

    Full Text Available Modeling of interstitial fluid flow involves processes such as fluid diffusion, convective transport in extracellular matrix, and extravasation from blood vessels. To date, majority of microvascular flow modeling has been done at different levels and scales mostly on simple tumor shapes with their capillaries. However, with our proposed numerical model, more complex and realistic tumor shapes and capillary networks can be studied. Both blood flow through a capillary network, which is induced by a solid tumor, and fluid flow in tumor's surrounding tissue are formulated. First, governing equations of angiogenesis are implemented to specify the different domains for the network and interstitium. Then, governing equations for flow modeling are introduced for different domains. The conservation laws for mass and momentum (including continuity equation, Darcy's law for tissue, and simplified Navier-Stokes equation for blood flow through capillaries are used for simulating interstitial and intravascular flows and Starling's law is used for closing this system of equations and coupling the intravascular and extravascular flows. This is the first study of flow modeling in solid tumors to naturalistically couple intravascular and extravascular flow through a network. This network is generated by sprouting angiogenesis and consisting of one parent vessel connected to the network while taking into account the non-continuous behavior of blood, adaptability of capillary diameter to hemodynamics and metabolic stimuli, non-Newtonian blood flow, and phase separation of blood flow in capillary bifurcation. The incorporation of the outlined components beyond the previous models provides a more realistic prediction of interstitial fluid flow pattern in solid tumors and surrounding tissues. Results predict higher interstitial pressure, almost two times, for realistic model compared to the simplified model.

  9. Modeling of the flow continuum and optimal design of control-oriented injection systems in liquid composite molding processes

    Science.gov (United States)

    Gokce, Ali

    Several methodologies are presented in this dissertation that aim to ensure successful filling of the mold cavity consistently, during the mold filling stage of Liquid Composite Molding (LCM) processes such as Resin Transfer Molding (RTM), Vacuum Assisted Resin Transfer Molding (VARTM) and Seemann Composites Resin Infusion Molding (SCRIMP). Key parameters that affect the resin flow in the mold cavity can be divided into two main groups as continuum-related parameters and injection-related parameters. Flow continuum, which consists of all the spaces resin can reach in the mold cavity, has two major components: the porous medium, which is made up of the fiber reinforcements, and the flow channels that are introduced into the flow continuum unintentionally and offer an easy flow path to the resin. The properties that characterize the porous medium and the unintentional flow channels are continuum-related parameters. The injection-related parameters include resin injection locations (gates), resin injection conditions and air drainage locations (vents). Modeling the flow continuum is crucial in predicting the resin flow in the mold cavity. In this study, permeability, the key property of the porous medium, is predicted using the Method of Cells, a proven method to predict macroscopic properties of heterogeneous materials. Unintentional flow channels, which are also called racetracking channels, are modeled using a probabilistic approach. Injection-related parameters are the key tools to influence the resin flow in the mold cavity. In this study, Branch and Bound Search is modified for single gate optimization. Due to its pertinence to injection system design, the parameters that govern gate effectiveness in steering the resin advance are studied. A combinatorial search algorithm is proposed for vent optimization. Vent optimization and gate optimization algorithms are integrated for simultaneous gate and vent optimization. Overall, these methodologies reduce the cycle

  10. Approximate solutions for Forchheimer flow during water injection and water production in an unconfined aquifer

    Science.gov (United States)

    Mathias, Simon A.; Moutsopoulos, Konstantinos N.

    2016-07-01

    Understanding the hydraulics around injection and production wells in unconfined aquifers associated with rainwater and reclaimed water aquifer storage schemes is an issue of increasing importance. Much work has been done previously to understand the mathematics associated with Darcy's law in this context. However, groundwater flow velocities around injection and production wells are likely to be sufficiently large such as to induce significant non-Darcy effects. This article presents a mathematical analysis to look at Forchheimer's equation in the context of water injection and water production in unconfined aquifers. Three different approximate solutions are derived using quasi-steady-state assumptions and the method of matched asymptotic expansion. The resulting approximate solutions are shown to be accurate for a wide range of practical scenarios by comparison with a finite difference solution to the full problem of concern. The approximate solutions have led to an improved understanding of the flow dynamics. They can also be used as verification tools for future numerical models in this context.

  11. MHD flow over a permeable stretching/shrinking sheet of a nanofluid with suction/injection

    Directory of Open Access Journals (Sweden)

    Sandeep Naramgari

    2016-06-01

    Full Text Available In this study we analyzed the influence of thermal radiation and chemical reaction on two dimensional steady magnetohydrodynamic flow of a nanofluid past a permeable stretching/shrinking sheet in the presence of suction/injection. We considered nanofluid volume fraction on the boundary is submissive controlled, which makes the present study entirely different from earlier studies and physically more realistic. The equations governing the flow are solved numerically. Effects of non-dimensional governing parameters on velocity, temperature and concentration profiles are discussed and presented through graphs. Also, coefficient of skin friction and local Nusselt number is investigated for stretching/shrinking and suction/injection cases separately and presented through tables. Comparisons with existed results are presented. Present results have an excellent agreement with the existed studies under some special assumptions. Results indicate that the enhancement in Brownian motion and thermophoresis parameters depreciates the nanoparticle concentration and increases the mass transfer rate. Dual solutions exist only for certain range of stretching/shrinking and suction/injection parameters.

  12. Flow injection colorimetric method using acidic ceric nitrate as reagent for determination of ethanol.

    Science.gov (United States)

    Pinyou, Piyanut; Youngvises, Napaporn; Jakmunee, Jaroon

    2011-05-15

    Ceric ammonium nitrate has been used for qualitative analysis of ethanol. It forms an intensely colored unstable complex with alcohol. In this work, a simple flow injection (FI) colorimetric method was developed for the determination of ethanol, based on the reaction of ethanol with ceric ion in acidic medium to produce a red colored product having maximum absorption at 415 nm. Absorbance of this complex could be precisely measured in the FI system. A standard or sample solution was injected into a deionized water donor stream and flowed to a gas diffusion unit, where the ethanol diffused through a gas permeable membrane made of plumbing PTFE tape into an acceptor stream to react with ceric ammonium nitrate in nitric acid. Color intensity of the reddish product was monitored by a laboratory made LED based colorimeter and the signal was recorded on a computer as a peak. Peak height obtained was linearly proportional to the concentration of ethanol originally presented in the injected solution in the range of 0.1-10.0% (v/v) (r(2)=0.9993), with detection limit of 0.03% (v/v). With the use of gas diffusion membrane, most of the interferences could be eliminated. The proposed method was successfully applied for determination of ethanol in some alcoholic beverages, validating by gas chromatographic method.

  13. Flow and dynamo measurements during the coaxial helicity injection on HIST

    Science.gov (United States)

    Ando, K.; Higashi, T.; Nakatsuka, M.; Kikuchi, Y.; Fukumoto, N.; Nagata, M.

    2009-11-01

    The current drive by Coaxial Helicity Injection (CHI-CD) was performed on HIST in a wide range of configurations from high-q ST to low-q ST and spheromak generated by the utilization of the toroidal field. It is a key issue to investigate the dynamo mechanism required to maintain each configuration. To identify the detail mechanisms, it is needed to manifest a role of plasma flows in the CHI-CD. For this purpose, we have measured the ion flow and the dynamo electric field using an ion Doppler spectrometer (IDS) system, a Mach probe and a dynamo probe. The new dynamo probe consists of 3-axis Mach probes and magnetic pick-up coils. The flow measurements have shown that the intermittent generation of the flow is correlated to the fluctuation seen on the electron density and current signals during the driven phase. At this time, the toroidal direction of the ion flow in the central open flux column is opposite to that of the toroidal current there, i.e. the same direction as electrons. After the plasma enters to the resistive decay phase, the toroidal flow tends to reverse to the same direction as the toroidal current. The results are consistent with the model of the repetitive plasmoid ejection and coalescence proposed for CHI-CD. The plasma jet emanating from the gun source and magnetic field generations through reconnection during the driven phase is well reflected in the 3D MHD simulation.

  14. Visualization analysis of tiger-striped flow mark generation phenomena in injection molding

    Science.gov (United States)

    Owada, Shigeru; Yokoi, Hidetoshi

    2016-03-01

    The generation mechanism of tiger-striped flow marks of polypropylene (PP)/rubber/talc blends in injection molding was investigated by dynamic visualization analysis in a glass-inserted mold. The analysis revealed that the behavior of the melt flow front correlates with the flow mark generation. The cloudy part in the tiger-striped flow marks corresponded to the low transcription rate area of the melt diverging near the cavity wall, while the glossy part corresponded to the high transcription rate area of the melt converging toward the cavity wall side. The melt temperature at the high transcription rate area was slightly lower than that at the low transcription rate area. These phenomena resulted due to the difference in the temperature of the melt front that was caused by the asymmetric fountain flow. These results suggest the followings; At the moment when the melt is broken near the one side of cavity wall due to piling the extensional strains up to a certain level, the melt spurts out near the broken side. It results in generating asymmetric fountain flow temporarily to relax the extensional front surface, which moves toward the opposite side to form the high transcription area.

  15. National Combustion Code Validated Against Lean Direct Injection Flow Field Data

    Science.gov (United States)

    Iannetti, Anthony C.

    2003-01-01

    Most combustion processes have, in some way or another, a recirculating flow field. This recirculation stabilizes the reaction zone, or flame, but an unnecessarily large recirculation zone can result in high nitrogen oxide (NOx) values for combustion systems. The size of this recirculation zone is crucial to the performance of state-of-the-art, low-emissions hardware. If this is a large-scale combustion process, the flow field will probably be turbulent and, therefore, three-dimensional. This research dealt primarily with flow fields resulting from lean direct injection (LDI) concepts, as described in Research & Technology 2001. LDI is a concept that depends heavily on the design of the swirler. The LDI concept has the potential to reduce NOx values from 50 to 70 percent of current values, with good flame stability characteristics. It is cost effective and (hopefully) beneficial to do most of the design work for an LDI swirler using computer-aided design (CAD) and computer-aided engineering (CAE) tools. Computational fluid dynamics (CFD) codes are CAE tools that can calculate three-dimensional flows in complex geometries. However, CFD codes are only beginning to correctly calculate the flow fields for complex devices, and the related combustion models usually remove a large portion of the flow physics.

  16. Sequential injection system incorporating a micro extraction column for automatic fractionation of metal ions in solid samples

    DEFF Research Database (Denmark)

    Chomchoei, Roongrat; Miró, Manuel; Hansen, Elo Harald

    2005-01-01

    as to the kinetics of the leaching processes and chemical associations in different soil geological phases. Special attention is also paid to the potentials of the microcolumn flowing technique for automatic processing of solid materials with variable homogeneity, as demonstrated with the sewage amended CRM483 soil...

  17. Effect of Temperature Sensitivity and Plasticizer Diffusive Transport on Performance of Layered Solid Propellants under Electrothermal Plasma Injection

    National Research Council Canada - National Science Library

    Bourham, Mohamed

    2002-01-01

    .... The plasma jet velocity 2 inches from the source exit was found to be about 1300 m/s. Following characterization of the plasma-flow field, a set of experiments was conducted on JA-2 solid propellant with controlled bed temperature...

  18. Simultaneous Determination of Gold and Platinum by Double Artificial Neural Network Analysis with Flow-injection Chemiluminescence

    Institute of Scientific and Technical Information of China (English)

    Ming Yang LIU; Hai Tao ZHANG; Jun Feng LI; Shu Gui CHEN; Hong Yan WANG

    2006-01-01

    A highly sensitive double artificial neural network (DANN) analysis with flow-injection chemiluminescence (FI-CL) has been developed to simultaneously determine the trace amounts of the gold and platinum in simulated mixed samples, without the boring process.

  19. Bio-bar-code functionalized magnetic nanoparticle label for ultrasensitive flow injection chemiluminescence detection of DNA hybridization.

    Science.gov (United States)

    Bi, Sai; Zhou, Hong; Zhang, Shusheng

    2009-10-07

    A signal amplification strategy based on bio-bar-code functionalized magnetic nanoparticles as labels holds promise to improve the sensitivity and detection limit of the detection of DNA hybridization and single-nucleotide polymorphisms by flow injection chemiluminescence assays.

  20. A finite difference method for predicting supersonic turbulent boundary layer flows with tangential slot injection

    Science.gov (United States)

    Miner, E. W.; Lewis, C. H.

    1972-01-01

    An implicit finite difference method has been applied to tangential slot injection into supersonic turbulent boundary layer flows. In addition, the effects induced by the interaction between the boundary layer displacement thickness and the external pressure field are considered. In the present method, three different eddy viscosity models have been used to specify the turbulent momentum exchange. One model depends on the species concentration profile and the species conservation equation has been included in the system of governing partial differential equations. Results are compared with experimental data at stream Mach numbers of 2.4 and 6.0 and with results of another finite difference method. Good agreement was generally obtained for the reduction of wall skin friction with slot injection and with experimental Mach number and pitot pressure profiles. Calculations with the effects of pressure interaction included showed these effects to be smaller than effects of changing eddy viscosity models.

  1. Determination of Hypochlorite in Bleaching Products with Flower Extracts to Demonstrate the Principles of Flow Injection Analysis

    Science.gov (United States)

    Ramos, Luiz Antonio; Prieto, Katia Roberta; Carvalheiro, Eder Tadeu Gomes; Carvalheiro, Carla Cristina Schmitt

    2005-01-01

    The use of crude flower extracts to the principle of analytical chemistry automation, with the flow injection analysis (FIA) procedure developed to determine hypochlorite in household bleaching products was performed. The FIA comprises a group of techniques based on injection of a liquid sample into a moving, nonsegmented carrier stream of a…

  2. How Flow Injection Analysis (FIA) over the past 25 years has changed our way of performing chemical analyses

    DEFF Research Database (Denmark)

    Hansen, Elo Harald; Miró, Manuel

    2007-01-01

    Briefly looking back on the impact of flow injection analysis (FIA), as reflected in the rapid growth of publications in the scientific literature, and touching upon many of the novel and unique analytical chemical possibilities that FIA and its sequels, sequential injection analysis (SIA) and Lab-on-Valve...

  3. Photoelectrocatalytic determination of NADH in a flow injection system with electropolymerized methylene blue

    Energy Technology Data Exchange (ETDEWEB)

    Dilgin, Yusuf, E-mail: ydilgin@yahoo.co [Canakkale Onsekiz Mart University, Science and Art Faculty, Department of Chemistry, TR-17100 Canakkale (Turkey); Dilgin, Didem Giray [Canakkale Onsekiz Mart University, Biga Vocational College, TR-17200 Biga Canakkale (Turkey); Ege University, Science Faculty, Department of Chemistry, TR-35100 Bornova/Izmir (Turkey); Dursun, Zekerya; Goekcel, H. Ismet [Ege University, Science Faculty, Department of Chemistry, TR-35100 Bornova/Izmir (Turkey); Gligor, Delia [Department of Environmental Physics, Chemistry and Engineering, ' Babes-Bolyai' University, 30 Fantanele St., 400294 Cluj-Napoca (Romania); Bayrak, Burcu; Ertek, Bensu [Canakkale Onsekiz Mart University, Science and Art Faculty, Department of Chemistry, TR-17100 Canakkale (Turkey)

    2011-01-01

    It was firstly described that a glassy carbon electrode electropolymerized with methylene blue shows an efficient photoelectrocatalytic activity towards NADH oxidation in a phosphate buffer solution (pH 7.0). In order to perform the photoelectrocatalytic determination of NADH in a flow injection analysis (FIA) system, a home-made flow electrochemical cell with a suitable transparent window for the irradiation of the electrode surface was constructed. The currents obtained from the photoamperometric measurements in the FIA system at optimum conditions (flow rate of carrier solution, 1.3 mL min{sup -1}; transmission tubing length, 10 cm; injection volume, 100 {mu}L; and constant applied potential, +150 mV vs. Ag/AgCl) were linearly dependent on the NADH concentration and linear calibration curves were obtained in the range of 1.0 x 10{sup -7}-2.0 x 10{sup -4} M. The detection limit was found to be 4.0 x 10{sup -8} M for photoamperometric determination of NADH.

  4. Flow injection chemiluminescence determination of hydrazine by oxidation with chlorinated isocyanurates.

    Science.gov (United States)

    Safavi, Afsaneh; Karimi, Mohammad Ali

    2002-10-16

    A rapid and sensitive flow injection chemiluminescence (CL) method is described for the determination of hydrazine based on the CL generated during its reaction with either sodium dichloroisocyanurate (SDCC) or trichloroisocyanuric acid (TCCA) in alkaline medium. The emission intensity is greatly enhanced if dichlorofluorescein (DCF) as sensitizer is present in the reaction medium. The presence of citrate prevents the precipitation of some cations in the reaction medium and also causes an enhancement in emission intensity. The effect of analytical and flow injection variables on these CL systems and determination of hydrazine are discussed. The optimum parameters for the determination of hydrazine were studied and were found to be the following: SDCC and TCCA both 1x10(-3) M; NaOH, 2x10(-1) M; DCF, 5x10(-6) M; citrate, 1x10(-3) M and flow rate, 3.8 ml min(-1). The optimized method yielded 3sigma detection limits of 2x10(-7) and 3x10(-7) M for hydrazine with SDCC and TCCA oxidants, respectively. The method is simple, fast, sensitive, and precise and was applied to the determination of hydrazine in water samples.

  5. Droplet-based microfluidic flow injection system with large-scale concentration gradient by a single nanoliter-scale injection for enzyme inhibition assay.

    Science.gov (United States)

    Cai, Long-Fei; Zhu, Ying; Du, Guan-Sheng; Fang, Qun

    2012-01-03

    We described a microfluidic chip-based system capable of generating droplet array with a large scale concentration gradient by coupling flow injection gradient technique with droplet-based microfluidics. Multiple modules including sample injection, sample dispersion, gradient generation, droplet formation, mixing of sample and reagents, and online reaction within the droplets were integrated into the microchip. In the system, nanoliter-scale sample solution was automatically injected into the chip under valveless flow injection analysis mode. The sample zone was first dispersed in the microchannel to form a concentration gradient along the axial direction of the microchannel and then segmented into a linear array of droplets by immiscible oil phase. With the segmentation and protection of the oil phase, the concentration gradient profile of the sample was preserved in the droplet array with high fidelity. With a single injection of 16 nL of sample solution, an array of droplets with concentration gradient spanning 3-4 orders of magnitude could be generated. The present system was applied in the enzyme inhibition assay of β-galactosidase to preliminarily demonstrate its potential in high throughput drug screening. With a single injection of 16 nL of inhibitor solution, more than 240 in-droplet enzyme inhibition reactions with different inhibitor concentrations could be performed with an analysis time of 2.5 min. Compared with multiwell plate-based screening systems, the inhibitor consumption was reduced 1000-fold.

  6. Simple flow injection colorimetric system for determination of paraquat in natural water.

    Science.gov (United States)

    Chuntib, Prakit; Jakmunee, Jaroon

    2015-11-01

    A simple and low cost flow injection colorimetric system has been developed for determination of paraquat in natural water. The developed method is based on the reduction of paraquat by using sodium dithionite as a reducing agent in an alkaline medium to produce a blue free radical ion that can be detected by a simple light emitting diode-light dependent resistor (LED-LDR) colorimeter. The standard or sample solution was injected via a set of 3-way solenoid valves into a water carrier stream and flowed to merge with reagent to generate a colored product which is proportional to the concentration of paraquat ion in the solution. Under the optimum condition of the system, i.e., mixing coil length 30 cm, flow rate 2.0 mL min(-1), sample volume 100 μL, concentrations of dithionite 0.1% (w/v) and sodium hydroxide 0.06 mol L(-1), a linear calibration graph in the range of 0.2-10.0 mg L(-1) with a correlation coefficient of 0.9996, and a limit of detection of 0.15 mg L(-1) were achieved. Relative standard deviation for 9 replicate injections of 1 mg L(-1) paraquat is 3.7%. A sample throughput of 40 injections h(-1) was achieved. The limit of detection can be improved by off-line preconcentration of paraquat employing a column packed with Dowex 50WX8-100 (H) cation exchange resin and eluted with 10% (w/v) ammonium chloride in ammonium buffer solution pH 10. The eluting solution was then injected into the FI system for paraquat determination. The proposed system did not suffer from interferences of some possible ions in natural water and other herbicides. Recoveries obtained by spiking 0.5 and 5.0 mg L(-1) paraquat standard into water samples were in the range of 104-110% and 101-105%, respectively. The developed system can be conveniently applied for screening of paraquat contaminated in natural water.

  7. Sealpot and method for controlling a solids flow rate therethrough

    Energy Technology Data Exchange (ETDEWEB)

    Chiu, John H.; Teigen, Bard C.

    2015-10-20

    A sealpot for a combustion power plant includes a downcomer standpipe which receives solids of the combustion power plant, a bed including a first end and a second opposite end, the first end connected to the downcomer standpipe, a discharge standpipe disposed at the second opposite end of the bed, and an orifice plate disposed between the bed and the discharge standpipe separating the discharge standpipe from the bed. The orifice plate includes apertures disposed at a height above the bed which allow transport of fluidized solids and gas through the orifice plate.

  8. Determination of gallic acid with rhodanine by reverse flow injection analysis using simplex optimization.

    Science.gov (United States)

    Phakthong, Wilaiwan; Liawruangrath, Boonsom; Liawruangrath, Saisunee

    2014-12-01

    A reversed flow injection (rFI) system was designed and constructed for gallic acid determination. Gallic acid was determined based on the formation of chromogen between gallic acid and rhodanine, resulting in a colored product with a λmax at 520 nm. The optimum conditions for determining gallic acid were also investigated. Optimizations of the experimental conditions were carried out based on the so-call univariate method. The conditions obtained were 0.6% (w/v) rhodanine, 70% (v/v) ethanol, 0.9 mol L(-1) NaOH, 2.0 mL min(-1) flow rate, 75 μL injection loop and 600 cm mixing tubing length, respectively. Comparative optimizations of the experimental conditions were also carried out by multivariate or simplex optimization method. The conditions obtained were 1.2% (w/v) rhodanine, 70% (v/v) ethanol, 1.2 mol L(-1) NaOH, flow rate 2.5 mL min(-1), 75 μL injection loop and 600 cm mixing tubing length, respectively. It was found that the optimum conditions obtained by the former optimization method were mostly similar to those obtained by the latter method. The linear relationship between peak height and the concentration of gallic acid was obtained over the range of 0.1-35.0 mg L(-1) with the detection limit 0.081 mg L(-1). The relative standard deviations were found to be in the ranges 0.46-1.96% for 1, 10, 30 mg L(-1) of gallic acid (n=11). The method has the advantages of simplicity extremely high selectivity and high precision. The proposed method was successfully applied to the determination of gallic acid in longan samples without interferent effects from other common phenolic compounds that might be present in the longan samples collected in northern Thailand.

  9. On the effect of injection of gas in the numerical simulation of accretion flows

    Institute of Scientific and Technical Information of China (English)

    2010-01-01

    We investigate the effects of various ways of injection of gas at the outer boundary in the numerical simulations of non-viscous accretion flows.We study three models.In Model A,we inject material around the equatorial plane.In Models B and C,fullrange θ injection is used(we employ spherical coordinates).In all three models,the injected material has the same density distribution with polar angle θ.From the equatorial region to the polar regions,angular momentum of the injected material of Model B decreases faster than that in Model C.For all of the models,after a transient episode of infall at the beginning of the simulations,the gas piles up in the equatorial regions outside the black hole and forms a thick torus bounded by a centrifugal barrier.We find that the accretion rates of Models B and C are more than ten times higher than that in Model A.In Model A,there is weak accretion only in the torus and outflows are found on the surface of the torus.In Model B,we find strong inflows on the surface of its torus,and the accretion in the torus is weak.In Model C,strong inflows also occur on the surface of its torus,but the accretion regions are narrower and there are strong outflows in its torus.In all of our models,the time-averaged density,pressure and angular momentum in the equatorial region can be described by a radial power law,with P ∝r-3/2,P ∝r-2 and l∝r0.

  10. Optimally controlled heating of solid particles in a fluidised bed with a dispersive flow of the solid

    Directory of Open Access Journals (Sweden)

    Poświata Artur

    2016-03-01

    Full Text Available In this study the authors minimise the total process cost for the heating of solid particles in a horizontal fluidised bed by an optimal choice of the inlet heating gas temperature profile and the total gas flow. Solid particles flowed along the apparatus and were heated by a hot gas entering from the bottom of the fluidised apparatus. The hydrodynamics of the fluidised bed is described by a two-phase Kunii - Levenspiel model. We assumed that the gas was flowing only vertically, whereas solid particles were flowing horizontally and because of dispersion they could be additionally mixed up in the same direction. The mixing rate was described by the axial dispersion coefficient. As any economic values of variables describing analysing process are subject to local and time fluctuations, the accepted objective function describes the total cost of the process expressed in exergy units. The continuous optimisation algorithm of the Maximum Principle was used for calculations. A mathematical model of the process, including boundary conditions in a form convenient for optimisation, was derived and presented. The optimization results are presented as an optimal profile of inlet gas temperature. The influence of heat transfer kinetics and dispersion coefficients on optimal runs of the heating process is discussed. Results of this discussion constitute a novelty in comparison to information presented in current literature.

  11. Scale-up from batch to flow-through wet milling process for injectable depot formulation.

    Science.gov (United States)

    Lehocký, Róbert; Pěček, Daniel; Štěpánek, František

    2016-12-01

    Injectable depot formulations are aimed at providing long-term sustained release of a drug into systemic circulation, thus reducing plasma level fluctuations and improving patient compliance. The particle size distribution of the formulation in the form of suspension is a key parameter that controls the release rate. In this work, the process of wet stirred media milling (ball milling) of a poorly water-soluble substance has been investigated with two main aims: (i) to determine the parametric sensitivity of milling kinetics; and (ii) to develop scale-up methodology for process transfer from batch to flow-through arrangement. Ball milling experiments were performed in two types of ball mills, a batch mill with a 30ml maximum working volume, and a flow-through mill with a 250ml maximum working volume. Milling parameters were investigated in detail by methodologies of QbD to map the parametric space. Specifically, the effects of ball size, ball fill level, and rpm on the particle breakage kinetics were systematically investigated at both mills, with an additional parameter (flow-rate) in the case of the flow-through mill. The breakage rate was found to follow power-law kinetics with respect to dimensionless time, with an asymptotic d50 particle size in the range of 200-300nm. In the case of the flow-through mill, the number of theoretical passes through the mill was found to be an important scale-up parameter.

  12. Potentiometric electronic tongue-flow injection analysis system for the monitoring of heavy metal biosorption processes

    OpenAIRE

    2012-01-01

    An automated flow injection potentiometric (FIP) system with electronic tongue detection (ET) is used for the monitoring of biosorption processes of heavy metals on vegetable wastes. Grape stalk wastes are used as biosorbent to remove Cu2+ ions in a fixed-bed column configuration. The ET is formed by a 5-sensor array with Cu2+ and Ca2+-selective electrodes and electrodes with generic response to heavy-metals, plus an artificial neural network response model of the sensor's cross-response. The...

  13. Effects of Capillary Pressure on Multiphase Flow during CO2 Injection in Saline Aquifer

    Directory of Open Access Journals (Sweden)

    Pau J.S.

    2014-07-01

    Full Text Available This paper focused on supercritical CO2 injection into saline aquifer, in particular its capillarity’s effects on the plume migration, reservoir pressure alteration and CO2 flux density. The numerical method used to solve the incompressible two-phase flow equations is based on the mimetic method, which conserves the mass and fluxes simultaneously. The investigation showed that exclusion of capillarity can greatly underestimate the CO2 plume migration and resulted in distinctive reservoir pressure distribution. It is found that capillarity showed no significant effect on the flux intensity of CO2.

  14. Flow Injection Analysis of Histidine with Enhanced Electrogenerated Chemiluminescence of Luminol

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    A simple and sensitive flow injection method is presented for the determination of histidine based on its enhancement of electrogenerated chemiluminescence (ECL) of luminol. After optimization of the experimental parameters, the working range for histidine was in 1.0 x 10-6 to 1.0 x 10 -3 mol/L with a detection limit (S/N = 3) of 0.56 μmol/L. The relative standard deviation was 1.6% for 11 measurements of 5 x 10 -5 mol/L histidine solution. The proposed method has been successfully applied to the determination of histidine in real pharmaceutical preparation.

  15. Method for 236U Determination in Seawater Using Flow Injection Extraction Chromatography and Accelerator Mass Spectrometry

    DEFF Research Database (Denmark)

    Qiao, Jixin; Hou, Xiaolin; Steier, Peter;

    2015-01-01

    An automated analytical method implemented in a flow injection (FI) system was developed for rapid determination of 236U in 10 L seawater samples. 238U was used as a chemical yield tracer for the whole procedure, in which extraction chromatography (UTEVA) was exploited to purify uranium, after......, on the basis of studying the coprecipitation behavior of uranium with iron hydroxide. The analytical results indicate that the developed method is simple and robust, providing satisfactory chemical yields (80−100%) and high analysis speed (4 h/sample), which could be an appealing alternative to conventional...... manual methods for 236U determination in its tracer application....

  16. Chemiluminescence Determination of Molybdenum by on-Line Reduction with a Flow Injection System

    Institute of Scientific and Technical Information of China (English)

    2000-01-01

    The chemiluminescence (CL) reaction between lucigenin (Lu) and molybdenum (Ⅲ) produced by a Jones reductor was investigated using a flow injection system. On the basis of this, a novel method for the determination of trace amount of molybdenum has been established. The emission intensity was linear with molybdenum concentration in the range of 0.1-1000 ng/mL; the detection limit was 0.02 ng/mL molybdenum; the relative standard deviation was less than 2% for the determination of 0.1 ng/mL molybdenum (n=11). The method has been applied successfully to the analysis of trace molybdenum in water and steel samples.

  17. Flow-injection-enhanced chemiluminescence method for the determination of three β-blockers

    Institute of Scientific and Technical Information of China (English)

    2010-01-01

    Objective To develop a rapid,simple and sensitive chemiluminescence method for the determination of three β-blockers (bisoprolol,atenolol and propranolol). Methods The chemiluminescence of cerium (Ⅳ)-sulfite system was obviously sensitized by adding anyone of three β-blockers in acid media. A new chemiluminescence method was set up by combining with flow-injection technique and used to determine the three β-blockers. Results Good linear ranges were obtained at the concentrations of 2.0×10-7g/mL-4.0×10-5g/mL...

  18. Effect of particle loading on heat transfer enhancement in a gas-solid suspension cross flow

    Institute of Scientific and Technical Information of China (English)

    周劲松; 骆仲泱; 高翔; 倪明江; 岑可法

    2002-01-01

    Heat transfer between gas-solid multiphase flow and tubes occurs in many industry processes, such as circulating fluidized bed process, pneumatic conveying process, chemical process, drying process, etc. (This paper focuses on the influence of the presence of particles on the heat transfer between a tube and gas-solid sus-pension. The presence of particles causes positive enhancement of heat transfer in the case of high solid loading ratio, but heat transfer reduction has been found for in the case of very low soliding ratio (Ms of less than 0.05 kg/kg). A usefial correlation ineorpomting solid lolling ratio, particle size and flow Reytmlds number was derived from experimental data. In addition, the κ-ε two-equation model and the Fluctuation-Spectrum-Random-Trajectory Model (FSRT Model) are used to simulate the flow field and heat transit of the gas-phase and the solid-phase, respectively. Through coupling of the two phases the model can predict the local and total heat transfer characteristics of tube in gas-solid cross flow. For the total heat transfer enhancement due to particles loading the model predictions agreed well wih experimental data.

  19. Effect of particle loading on heat transfer enhancement in a gas-solid suspension cross flow

    Institute of Scientific and Technical Information of China (English)

    周劲松; 骆仲泱; 高翔; 倪明江; 岑可法

    2002-01-01

    Heat transfer between gas-solid multiphase flow and tubes occurs in m a ny industry processes, such as circulating fluidized bed process, pneumatic conv eying process, chemical process, drying process, etc. This paper focuses on the influence of the presence of particles on the heat transfer between a tube and g as-solid suspension. The presence of particles causes positive enhancement of h e at transfer in the case of high solid loading ratio, but heat transfer reduction has been found for in the case of very low solid loading ratio (Ms of les s than 0.05 kg/kg). A useful correlation incorporating solid loading ratio, particle s ize and flow Reynolds number was derived from experimental data. In addition, th e k-ε two-equation model and the Fluctuation-Spectrum- Random-Trajecto ry Model ( FSRT Model) are used to simulate the flow field and heat transfer of the gas-ph a se and the solid-phase, respectively. Through coupling of the two phases the mo d el can predict the local and total heat transfer characteristics of tube in gas - solid cross flow. For the total heat transfer enhancement due to particles loadi ng the model predictions agreed well with experimental data.

  20. Optimization of a new flow design for solid oxide cells using computational fluid dynamics modelling

    DEFF Research Database (Denmark)

    Duhn, Jakob Dragsbæk; Jensen, Anker Degn; Wedel, Stig;

    2016-01-01

    Design of a gas distributor to distribute gas flow into parallel channels for Solid Oxide Cells (SOC) is optimized, with respect to flow distribution, using Computational Fluid Dynamics (CFD) modelling. The CFD model is based on a 3d geometric model and the optimized structural parameters include...

  1. Internal Flow Simulation of High-Performance Solid Rockets using a k-ωTurbulence Model

    Institute of Scientific and Technical Information of China (English)

    V.R. SANAL KUMAR; H.D. KIM; B.N. RAGHUNANDAN; T. SETOGUCHI; S. RAGHUNATHAN

    2005-01-01

    @@ For technological reasons many high-performance solid rocket motors are made from segmented propellant grains with non-uniform port geometry. In this paper parametric studies have been carried out to examine the geometric dependence of transient flow features in solid rockets with non-uniform ports. Numerical computations have been carried out in an inert simulator of solid propellant rocket motor with the aid of a standard k-ω turbulence model. It was seen that the damping of the temperature fluctuation is faster in solid rocket with convergent port than with divergent port geometry. We inferred that the damping of the flow fluctuations using the port geometry is a meaningful objective for the suppression and control of the instability and/or pressure/thrust oscillations during the starting transient of solid rockets.

  2. Coupling Analysis of Fluid-Structure Interaction and Flow Erosion of Gas-Solid Flow in Elbow Pipe

    OpenAIRE

    Hongjun Zhu; Hongnan Zhao; Qian Pan; Xue Li

    2014-01-01

    A numerical simulation has been conducted to investigate flow erosion and pipe deformation of elbow in gas-solid two-phase flow. The motion of the continuous fluid phase is captured based on calculating three-dimensional Reynolds-averaged-Navier-Stokes (RANS) equations, while the kinematics and trajectory of the discrete particles are evaluated by discrete phase model (DPM), and a fluid-structure interaction (FSI) computational model is adopted to calculate the pipe deformation. The effects o...

  3. Flow Rates Measurement and Uncertainty Analysis in Multiple-Zone Water-Injection Wells from Fluid Temperature Profiles

    Directory of Open Access Journals (Sweden)

    José E. O. Reges

    2016-07-01

    Full Text Available This work is a contribution to the development of flow sensors in the oil and gas industry. It presents a methodology to measure the flow rates into multiple-zone water-injection wells from fluid temperature profiles and estimate the measurement uncertainty. First, a method to iteratively calculate the zonal flow rates using the Ramey (exponential model was described. Next, this model was linearized to perform an uncertainty analysis. Then, a computer program to calculate the injected flow rates from experimental temperature profiles was developed. In the experimental part, a fluid temperature profile from a dual-zone water-injection well located in the Northeast Brazilian region was collected. Thus, calculated and measured flow rates were compared. The results proved that linearization error is negligible for practical purposes and the relative uncertainty increases as the flow rate decreases. The calculated values from both the Ramey and linear models were very close to the measured flow rates, presenting a difference of only 4.58 m³/d and 2.38 m³/d, respectively. Finally, the measurement uncertainties from the Ramey and linear models were equal to 1.22% and 1.40% (for injection zone 1; 10.47% and 9.88% (for injection zone 2. Therefore, the methodology was successfully validated and all objectives of this work were achieved.

  4. Flow Rates Measurement and Uncertainty Analysis in Multiple-Zone Water-Injection Wells from Fluid Temperature Profiles.

    Science.gov (United States)

    Reges, José E O; Salazar, A O; Maitelli, Carla W S P; Carvalho, Lucas G; Britto, Ursula J B

    2016-07-13

    This work is a contribution to the development of flow sensors in the oil and gas industry. It presents a methodology to measure the flow rates into multiple-zone water-injection wells from fluid temperature profiles and estimate the measurement uncertainty. First, a method to iteratively calculate the zonal flow rates using the Ramey (exponential) model was described. Next, this model was linearized to perform an uncertainty analysis. Then, a computer program to calculate the injected flow rates from experimental temperature profiles was developed. In the experimental part, a fluid temperature profile from a dual-zone water-injection well located in the Northeast Brazilian region was collected. Thus, calculated and measured flow rates were compared. The results proved that linearization error is negligible for practical purposes and the relative uncertainty increases as the flow rate decreases. The calculated values from both the Ramey and linear models were very close to the measured flow rates, presenting a difference of only 4.58 m³/d and 2.38 m³/d, respectively. Finally, the measurement uncertainties from the Ramey and linear models were equal to 1.22% and 1.40% (for injection zone 1); 10.47% and 9.88% (for injection zone 2). Therefore, the methodology was successfully validated and all objectives of this work were achieved.

  5. Selective chlorine dioxide determination using gas-diffusion flow injection analysis with chemiluminescent detection

    Energy Technology Data Exchange (ETDEWEB)

    Hollowell, D.A.; Gord, J.R.; Gordon, G.; Pacey, G.E.

    1986-06-01

    An automated chemiluminescent technique has been developed utilizing the advantages of gas-diffusion flow injection analysis. A gas-diffusion membrane separates the donor (sampling) stream from the acceptor (detecting) stream and removes ionic interferences. A novel chemiluminescence flow-through detector cell is used to measure the concentration of chlorine dioxide as a function of the intensity of the chemiluminescence produced from its reaction with luminol. The chemiluminescent reagent merges with the analyte directly in front of the photomultiplier tube in order to maximize the sensitivity of the system. The detection limit for chlorine dioxide is approximately 5 ppb. The method is over 1500 times more selective for chlorine dioxide than for chlorine on a mole basis. This method eliminates interference from iron and manganese compounds, as well as other oxychlorinated compounds such as chlorite ion and chlorate ion.

  6. Flow injection analysis simulations and diffusion coefficient determination by stochastic and deterministic optimization methods

    Energy Technology Data Exchange (ETDEWEB)

    Kucza, Witold, E-mail: witek@agh.edu.pl

    2013-07-25

    Graphical abstract: -- Highlights: •Former random walk approach for FIA simulations has been improved. •Random walk and uniform dispersion models have been used for FIA simulations. •Diffusivities have been optimized by genetic and the Levenberg–Marquardt methods. •Both approaches have given similar results in agreement with experimental ones. -- Abstract: Stochastic and deterministic simulations of dispersion in cylindrical channels on the Poiseuille flow have been presented. The random walk (stochastic) and the uniform dispersion (deterministic) models have been used for computations of flow injection analysis responses. These methods coupled with the genetic algorithm and the Levenberg–Marquardt optimization methods, respectively, have been applied for determination of diffusion coefficients. The diffusion coefficients of fluorescein sodium, potassium hexacyanoferrate and potassium dichromate have been determined by means of the presented methods and FIA responses that are available in literature. The best-fit results agree with each other and with experimental data thus validating both presented approaches.

  7. [Determination of phenobarbital in human urine and serum using flow injection chemiluminescence].

    Science.gov (United States)

    Li, X; Niu, L C; He, X L; Song, Z H

    2012-01-01

    A sensitive chemiluminescence method, based on the enhancive effect of phenobarbital on the chemiluminescence reaction between luminol and dissolved oxygen in a flow injection system, was proposed for the determination of phenobarbital. The chemiluminescence intensity responded to the concentration of phenobarbital linearly ranging from 0.05 to 10 ng x ml(-1) with the detection limit of 0.02 ng x ml(-1) (3 sigma). At a flow rate of 2.0 ml x min(-1), a complete determination of phenobarbital, including sampling and washing, could be accomplished in 0.5 min, offering the sampling efficiency of 120 h(-1) accordingly. The method was applied successfully in an assay of PB for pharmaceutical preparations, human urine and serum without any pretreatment with recovery from 95.7 to 106.7% and RSDs of less than 3.0%.

  8. LDA measurements in a Mach 2 flow over a rearward facing step with staged transverse injection

    Science.gov (United States)

    Wang, J.-A.; Dancey, C. L.

    1992-01-01

    Measurements of the mean velocity field and selected turbulence statistics have been obtained via 2D LDA in a Mach 2 flow over a rearward facing step with downstream transverse injection. Axial mean velocity profiles, profiles of the axial and normal RMS levels, and the correlation coefficient between the axial and normal fluctuating components are presented for locations upstream of the step. These data, through comparison with other reported measurements in zero pressure gradient compressible boundary layers indicate that the boundary layers upstream of the step are consistent with 'quasi-equilibrium' turbulent boundary layers with the adiabatic wall boundary condition. Mean velocity field measurements on the symmetry plane of the tunnel are compared to laser induced iodine fluorescence measurements reported in the literature and obtained in the same facility. This comparison demonstrates the quality of the present LDA data set and shows that particle lag is not significant in the LDA measurements despite the complex nature of the downstream flow.

  9. Plasma heating, electric fields and plasma flow by electron beam ionospheric injection

    Science.gov (United States)

    Winckler, J. R.; Erickson, K. N.

    1990-01-01

    The electric fields and the floating potentials of a Plasma Diagnostics Payload (PDP) located near a powerful electron beam injected from a large sounding rocket into the auroral zone ionosphere have been studied. As the PDP drifted away from the beam laterally, it surveyed a region of hot plasma extending nearly to 60 m radius. Large polarization electric fields transverse to B were imbedded in this hot plasma, which displayed large ELF wave variations and also an average pattern which has led to a model of the plasma flow about the negative line potential of the beam resembling a hydrodynamic vortex in a uniform flow field. Most of the present results are derived from the ECHO 6 sounding rocket mission.

  10. LDA measurements in a Mach 2 flow over a rearward facing step with staged transverse injection

    Science.gov (United States)

    Wang, J.-A.; Dancey, C. L.

    1992-01-01

    Measurements of the mean velocity field and selected turbulence statistics have been obtained via 2D LDA in a Mach 2 flow over a rearward facing step with downstream transverse injection. Axial mean velocity profiles, profiles of the axial and normal RMS levels, and the correlation coefficient between the axial and normal fluctuating components are presented for locations upstream of the step. These data, through comparison with other reported measurements in zero pressure gradient compressible boundary layers indicate that the boundary layers upstream of the step are consistent with 'quasi-equilibrium' turbulent boundary layers with the adiabatic wall boundary condition. Mean velocity field measurements on the symmetry plane of the tunnel are compared to laser induced iodine fluorescence measurements reported in the literature and obtained in the same facility. This comparison demonstrates the quality of the present LDA data set and shows that particle lag is not significant in the LDA measurements despite the complex nature of the downstream flow.

  11. Rapid antioxidant capacity screening in herbal extracts using a simple flow injection-spectrophotometric system.

    Science.gov (United States)

    Mrazek, Nookrai; Watla-iad, Kanchana; Deachathai, Suwanna; Suteerapataranon, Siripat

    2012-05-01

    A simple flow injection (FI)-spectrophotometric system for the screening of antioxidant capacity in herbal extracts was developed. The analysis was based on the color disappearance due to the scavenging of 2,2-diphenyl-1-picrylhydrazyl (DPPH) radical by antioxidant compounds. DPPH and ascorbic acid were used as reagent and antioxidant standard, respectively. Effects of the DPPH concentration, DPPH flow rate, and reaction coil length on sensitivity were studied. The optimized condition provided the linear range of 0.010-0.300mM ascorbic acid with less than 5%RSD(n=10). Detection limit and quantitation limit were 0.004 and 0.013mM, respectively. Comparison of antioxidant capacity in some herbal extracts determined by the FI system and a standard method was carried out and no significant difference was obtained.

  12. The influence of boundary layers on supersonic inlet flow unstart induced by mass injection

    Science.gov (United States)

    Do, Hyungrok; Im, Seong-Kyun; Mungal, M. Godfrey; Cappelli, Mark A.

    2011-09-01

    A transverse jet is injected into a supersonic model inlet flow to induce unstart. Planar laser Rayleigh scattering from condensed CO2 particles is used to visualize flow dynamics during the unstart process, while in some cases, wall pressure traces are simultaneously recorded. Studies conducted over a range of inlet configurations reveal that the presence of turbulent wall boundary layers strongly affect the unstart dynamics. It is found that relatively thick turbulent boundary layers in asymmetric wall boundary layer conditions prompt the formation of unstart shocks; in symmetric boundary conditions lead to the propagation of pseudo-shocks; and in both cases facilitate fast inlet unstart, when compared with thin, laminar boundary layers. Incident shockwaves and associated reflections are found to affect the speed of pressure disturbances. These disturbances, which induce boundary layer separation, are found to precede the formation of unstart shocks. The results confirm the importance of and need to better understand shock-boundary layer interactions in inlet unstart dynamics.

  13. Interaction of a decaying vortex ring with a rotational background flow bounded by a solid wall

    Science.gov (United States)

    Ishii, K.; Liu, C. H.

    1987-01-01

    The interaction between a vortex ring of finite strength and an axisymmetric rotational background flow bounded by a solid wall is studied by a singular perturbation method. The analysis is carried out by combining a composite solution of a vortex ring and an unsteady Navier-Stokes solution for the background rotational flow. Using the method of averaging, numerical scheme is developed to obtain a Navier-Stokes solution in which the grid and time-step sizes depend solely on the length and velocity scales of the background flow. Numerical results are presented to illustrate the separation of the boundary layer on a solid wall and its interaction with the vortex ring.

  14. Performance analysis on solid-liquid mixed flow in a centrifugal pump

    Science.gov (United States)

    Ning, C.; Wang, Y.

    2016-05-01

    In order to study the solid-liquid mixed flow hydraulic characteristics of centrifugal pump, the Pro/E software was used for three-dimensional modeling of centrifugal pump chamber. By using the computational fluid dynamics software CFX, the numerical simulation calculation of solid-liquid two-phase flow within whole flow passage of centrifugal pump was conducted. Aim at different particle diameters, the Reynolds-averaged N-S equations with the RNG k-Ɛ turbulence model and SIMPLEC algorithm were used to simulate the two-phase flow respectively on the condition of different volume fraction. The influence of internal flow characteristic on pump performance was analyzed. On the conditions of different particle diameter and different volume fraction, the turbulence kinetic energy and particle concentration are analyzed. It can be found that the erosion velocity ratio on the flow channel wall increases along with the increasing of the volume fraction

  15. Effect of Trailing Edge Flow Injection on Fan Noise and Aerodynamic Performance

    Science.gov (United States)

    Fite, E. Brian; Woodward, Richard P.; Podboy, Gary G.

    2006-01-01

    An experimental investigation using trailing edge blowing for reducing fan rotor/guide vane wake interaction noise was completed in the NASA Glenn 9- by 15-foot Low Speed Wind Tunnel. Data were acquired to measure noise, aerodynamic performance, and flow features for a 22" tip diameter fan representative of modern turbofan technology. The fan was designed to use trailing edge blowing to reduce the fan blade wake momentum deficit. The test objective was to quantify noise reductions, measure impacts on fan aerodynamic performance, and document the flow field using hot-film anemometry. Measurements concentrated on approach, cutback, and takeoff rotational speeds as those are the primary conditions of acoustic interest. Data are presented for a 2% (relative to overall fan flow) trailing edge injection rate and show a 2 dB reduction in Overall Sound Power Level (OAPWL) at all fan test speeds. The reduction in broadband noise is nearly constant and is approximately 1.5 dB up to 20 kHz at all fan speeds. Measurements of tone noise show significant variation, as evidenced by reductions of up to 6 dB in the 2 BPF tone at 6700 rpm.: and increases of nearly 2 dB for the 4 BPF tone at approach speed. Aerodynamic performance measurements show the fan with 2 % injection has an overall efficiency that is comparable to the baseline fan and operates, as intended, with nearly the same pressure ratio and mass flow parameters. Hot-film measurements obtained at the approach operating condition indicate that mean blade wake filling in the tip region was not as significant as expected. This suggests that additional acoustic benefits could be realized if the trailing edge blowing could be modified to provide better filling of the wake momentum deficit. Nevertheless, the hot-film measurements indicate that the trailing edge blowing provided significant reductions in blade wake turbulence. Overall, these results indicate that further work may be required to fully understand the proper

  16. Two-phase flow effects on the CO2 injection pressure evolution and implications for the caprock geomechanical stability

    Directory of Open Access Journals (Sweden)

    Vilarrasa Víctor

    2016-01-01

    Full Text Available Geologic carbon storage is considered to be one of the main solutions to significantly reduce CO2 emissions to the atmosphere to mitigate climate change. CO2 injection in deep geological formations entails a two-phase flow, being CO2 the non-wetting phase. One of the main concerns of geologic carbon storage is whether the overpressure induced by CO2 injection may compromise the caprock integrity and faults stability. We numerically investigate the two-phase flow effects that govern the overpressure evolution generated by CO2 injection and how this overpressure affects the caprock geomechanical stability. We find that fluid pressure increases sharply at the beginning of injection because CO2 has to displace the brine that fills the pores around the injection well, which reduces the relative permeability. However, overpressure decreases subsequently because once CO2 fills the pores around the injection well, CO2 can flow easily due to its low viscosity and because the relative permeability to CO2 increases. Furthermore, the pressure drop that occurs in the capillary fringe due to two-phase flow interference decreases as the CO2 plume becomes larger. This overpressure evolution induced by CO2 injection, which remains practically constant with time after the initial peak, is very beneficial for maintaining caprock stability. Thus, the sealing capacity of the caprock will be maintained, preventing CO2 leakage to occur across the caprock.

  17. Numerical Simulation of Gas-Liquid-Solid Three-Phase Flow in Deep Wells

    OpenAIRE

    Xie, Jianyu; Yu, Bo; Zhang, Xinyu; Shao, Qianqian; Song, Xianzhi

    2013-01-01

    A gas-liquid-solid flow model which considers the effect of the cuttings on the pressure drop is established for the annulus flow in the deep wells in this paper, based on which a numerical code is developed to calculate the thermal and flow quantities such as temperature and pressure distributions. The model is validated by field data, and its performance is compared with several commercial software. The effects of some important parameters, such as well depth, gas kick, cuttings, and drilli...

  18. Numerical Simulation of Swirling Gas-solid Two Phase Flow through a Pipe Expansion

    Institute of Scientific and Technical Information of China (English)

    Jin Hanhui; Xia Jun; Fan Jianren; Cen Kefa

    2001-01-01

    A k- ε -kp multi-fluid model is stated and adopted to simulate swirling gas-solid two phase flow. A particle-laden flow from a center tube and a swirling air stream from the coaxial annular enter the test section. A series of numerical simulations of the two-phase flow are performed based on 30 μ m, 45 μ m, 60 μ m diameter particles respectively. The results fit well with published experimental data.

  19. NUMERICAL CALCULATION OF SOLID-LIQUID TWO PHASE FLOW BETWEEN STAY VANES IN HYDRAULIC TURBINE

    Institute of Scientific and Technical Information of China (English)

    2000-01-01

    In this paper, an energy equation of silt-laden water flow is educed based on the energy equation of continuum fluid flow. The dissipation functions of liquid phase and solid phase are presented respectively. Then the extremity law of energy dissipation rate is introduced for the research of the silt-laden water flow and a new mathematical model is developed. The corresponding procedure based on the finite difference method (FDM) is developed to calculate the two phase flow in hydraulic turbine. The method is applied to analyze the silt-laden water flow between stay vanes, and the numerical results are in good agreement with the experimental ones.

  20. Two-phase Flow of Liquid-gas in Diesel Fuel Injection System and Their Effect on Engine Performances

    Institute of Scientific and Technical Information of China (English)

    Yongling He; Zhihe Zhao; Jianxin Liu; Huiyong Du; Min Li; Yongping Zong

    2001-01-01

    In this paper, by using high-speed camera, CCD camera, signal and graph acquisition system, and other experimental instruments, investigation on liquid-gas two-phase flow in diesel fuel injection system and their effect on engine performances were made. Emerging and bursting of cavitation in the cavity above pump delivery valve, in injection pipe, and in fuel trough of injector of the fuel injection system were observed and mechanism of cavitation were discussed. Effects of liquid-gas two-phase flow on propagation velocity of pressure wave of the system and on irregular injection were analyzed. Two types of cavitation, long living time cavitation and short living time cavitation, in the cavity above pump delivery valve of diesel fuel injection system were observed.

  1. Development of a Fully Automated Flow Injection Analyzer Implementing Bioluminescent Biosensors for Water Toxicity Assessment

    Directory of Open Access Journals (Sweden)

    Constantinos Georgiou

    2010-07-01

    Full Text Available This paper describes the development of an automated Flow Injection analyzer for water toxicity assessment. The analyzer is validated by assessing the toxicity of heavy metal (Pb2+, Hg2+ and Cu2+ solutions. One hundred μL of a Vibrio fischeri suspension are injected in a carrier solution containing different heavy metal concentrations. Biosensor cells are mixed with the toxic carrier solution in the mixing coil on the way to the detector. Response registered is % inhibition of biosensor bioluminescence due to heavy metal toxicity in comparison to that resulting by injecting the Vibrio fischeri suspension in deionised water. Carrier solutions of mercury showed higher toxicity than the other heavy metals, whereas all metals show concentration related levels of toxicity. The biosensor’s response to carrier solutions of different pHs was tested. Vibrio fischeri’s bioluminescence is promoted in the pH 5–10 range. Experiments indicate that the whole cell biosensor, as applied in the automated fluidic system, responds to various toxic solutions.

  2. Flow injection analysis of ketoprofen based on the order transform second chemiluminescence reaction

    Science.gov (United States)

    Zhuang, Yafeng; Cao, Guiping; Ge, Chuanqin

    2012-01-01

    This paper explores an order-transform-second-chemiluminescence (OTSCL) method combining the flow injection technique for the determination of ketoprofen. When ketoprofen solution was injected into the mixture after the end of the reaction of alkaline luminol and sodium periodate or sodium periodate solution was injected into the reaction mixture of ketoprofen and alkaline luminol, a new chemiluminescence (CL) reaction was initiated and strong CL signal was detected. A mechanism for the OTSCL has been proposed on the basis of the chemiluminescence kinetic characteristic, UV-visible absorption and chemiluminescent spectra. Under optimal experimental conditions, the CL response is proportional to the concentration of ketoprofen over the range of 2.0 × 10 -7 to 1.0 × 10 -5 mol/L with a correlation coefficient of 0.9950 and a detection limit of 8.0 × 10 -9 mol/L (3 σ). The relative standard deviation for 11 repetitive determinations of 1.0 × 10 -6 mol/L ketoprofen is 2.9%. The utility of this method was demonstrated by determining ketoprofen in pharmaceutical formulations without interference from its potential impurities.

  3. Flow Injection Analysis with Chemiluminescence detection for Determination of Two Phenothiazines

    Directory of Open Access Journals (Sweden)

    Hijran S. Jabbar

    2015-03-01

    Full Text Available A new flow injection analysis-chemiluminescence (FIA-CL method for determination of two phenothiazine derivatives "chlorpromazine hydrochloride (CPZ and promethazine hydrochloride (PTZ" described. The redox reaction between Fe(III and phenothiazines was taken as a base of this new method. A well-defined volume of CPZ or PTZ and luminol solution is injected simultaneously by means of two injection valves in accordance with the merging zone principle. Calibration graphs were constructed in the range of (0.05 – 1.4μg/ml for CPZ with correlation coefficient of (0.9972 and in the range of (0.5 – 40μg/ml for PTZ with correlation coefficient of (0.9978. The precision and accuracy of the method were checked by calculation of relative standard deviation (RSD and relative error percentage (%E for two different levels of concentrations. The method was relatively free from common excipients and it is applied successfully for the determination of CPZ and PTZ in pharmaceutical formulations. The results obtained were in good agreement with those obtained by a reference method in British Pharmacopoeia.

  4. Flow injection analysis of picric acid explosive using a copper electrode as electrochemical detector.

    Science.gov (United States)

    Junqueira, João R C; de Araujo, William R; Salles, Maiara O; Paixão, Thiago R L C

    2013-01-30

    A simple and fast electrochemical method for quantitative analysis of picric acid explosive (nitro-explosive) based on its electrochemical reduction at copper surfaces is reported. To achieve a higher sample throughput, the electrochemical sensor was adapted in a flow injection system. Under optimal experimental conditions, the peak current response increases linearly with picric acid concentration over the range of 20-300 μmol L(-1). The repeatability of the electrode response in the flow injection analysis (FIA) configuration was evaluated as 3% (n=10), and the detection limit of the method was estimated to be 6.0 μmol L(-1) (S/N=3). The sample throughput under optimised conditions was estimated to be 550 samples h(-1). Peroxide explosives like triacetone triperoxide (TATP) and hexamethylene triperoxide diamine (HMTD) were tested as potential interfering substances for the proposed method, and no significant interference by these explosives was noticed. The proposed method has interesting analytical parameters, environmental applications, and low cost compared with other electroanalytical methods that have been reported for the quantification of picric acid. Additionally, the possibility to develop an in situ device for the detection of picric acid using a disposable sensor was evaluated.

  5. Speciation of mercury in fish samples by flow injection catalytic cold vapour atomic absorption spectrometry.

    Science.gov (United States)

    Zhang, Yanlin; Adeloju, Samuel B

    2012-04-01

    A rapid flow injection catalytic cold vapour atomic absorption spectrometric (FI-CCV-AAS) method is described for speciation and determination of mercury in biological samples. Varying concentrations of NaBH(4) were employed for mercury vapour generation from inorganic and mixture of inorganic and organic (total) Hg. The presence of Fe(3+), Cu(2+) and thiourea had catalytic effect on mercury vapour generation from methylmercury (MeHg) and, when together, Cu(2+) and thiourea had synergistic catalytic effect on the vapour generation. Of the two metal ions, Fe(3+) gave the best sensitivity enhancement, achieving the same sensitivity for MeHg and inorganic Hg(2+). Due to similarity of resulting sensitivity, Hg(2+) was used successfully as a primary standard for quantification of inorganic and total Hg. The catalysis was homogeneous in nature, and it was assumed that the breaking of the C-Hg bond was facilitated by the delocalization of the 5d electron pairs in Hg atom. The extraction of MeHg and inorganic mercury (In-Hg) in fish samples were achieved quantitatively with hydrochloric acid in the presence of thiourea and determined by FI-CCV-AAS. The application of the method to the quantification of mercury species in a fish liver reference material DOLT-4 gave 91.5% and 102.3% recoveries for total and methyl mercury, respectively. The use of flow injection enabled rapid analysis with a sample throughput of 180 h(-1).

  6. Application of flow-injection potentiometric system for determination of total concentration of aliphatic carboxylic acids.

    Science.gov (United States)

    Mroczkiewicz, Monika; Górski, Łukasz; Zamojska-Jaroszewicz, Anna; Szewczyk, Krzysztof W; Malinowska, Elżbieta

    2011-09-30

    In this work, flow-injection system with potentiometric detection was tested for determination of total carboxylic acid concentration. Detection part of the examined system consists of ion-selective electrodes (ISEs) with polymer membranes of different compositions. First electrode is based on Zr(IV)-tetraphenylporphyrin as ionophore selective towards carboxylic acid anions, the membrane of second one contains only liphophilic anion exchanger - tridodecylmethylammonium chloride. Final response of the system is a result of combination of EMF signals from both electrodes. Combination of two detectors enables significant decrease of differences between potentiometric signals induced by mixtures of studied anions of various concentrations as compared to results obtained only with metalloporphyrin-based ISE. The use of anion-exchanger based detector allows for elimination of the influence of aliphatic carboxylic acids lipophilicity. Proposed potentiometric flow-injection system was employed for determination of short-chain aliphatic carboxylic acids (so-called VFA - volatile fatty acids) in samples originating from an anaerobic digester. Results obtained for these relatively complicated samples are in good agreement with results obtained with the use of reference colorimetric method. Linear response towards carboxylic acids was observed in the concentration range of 10(-4) to 10(-2)mold m(-3), with the slopes in the range of -110 to -150 mV dec(-1) (for acetate(-) and butyrate(-), respectively). System enables for determination of about 6 samples per hour. Life time of ISEs average about 2 months.

  7. Sequential flow injection determination of chlorine species using a triiodide-selective electrode detector.

    Science.gov (United States)

    Saad, Bahruddin; Wai, Wan Tatt; Ali, Abdussalam Salhin M; Saleh, Muhammad Idiris

    2006-01-01

    A flow injection analysis (FIA) method for the determination of four residual chlorine species, namely combined available chlorine (CAC), free available chlorine (FAC), total available chlorine (TAC) and chlorite (ClO2-) was developed using a flow-through triiodide-selective electrode as a detector. An important strategy of speciation studies utilized the kinetic discrimination of reactions between the CAC and FAC with Fe2+, which was applied to the speciation of FAC, CAC and TAC. The speciation of available chlorine species and chlorite (an oxychlorine species) was achieved by using the same set-up, but using flow streams of different pH. The effects of the pH of the carrier stream, the flow rate and the sample volume were studied. The method exhibited linearity from 2.8 x 10(-6) to 2.8 x 10(-4) M active chlorine (expressed as OCl-) with a detection limit of 1.4 x 10(-6) M. The selectivity of the method was studied by examining the minimum pH for the oxidation of iodide by other oxidants, and also by assessing the potentiometric selectivity coefficients. The proposed method was successfully applied to the determination of chlorine species in tap water, and disinfecting formulations where good agreement occurred between the proposed and standard methods were found.

  8. Development of flow injection method for indirect copper determination with amperometric detection in drinking water samples

    Directory of Open Access Journals (Sweden)

    Nikolić-Mandić Snežana

    2012-01-01

    Full Text Available A gas-diffusion flow injection method with amperometric detection for indirect copper determination on a silver electrode is developed. The flow through system is equipped with two injection valves and a gas-diffusion unit. In the first step, a signal of cyanide solution was recorded. In the following step a signal of cyanide in the presence of copper was measured. Interferences (Cd(II, Co(II, Ag(I, Ni(II, Fe(III, Hg(II and Zn(II were investigated and successfully removed. The calibration graph is linear in the range 1-90 μmol dm-3 of copper, correlation coefficient is 0.993, the regression equation is I = (0.0455±0.0015c + (0.4611±0.0671, I is relative signal decrease in μA and c is concentration in μmol dm-3. Relative standard deviation for six consecutive injections of 30 μmol dm-3 copper(II was 1.47 % and for 1 μmol dm-3 copper(II was 3.40 %. The detection limit, calculated as 3 s/m (where s is a standard deviation of nine measurement of a reagent blank and m is the slope of the calibration curve, was 0.32 μmol dm-3, which corresponds to 2.44 ng of copper(II (loop volume was 0.12 cm3. The method enables 60 analyses per hour and it was successfully applied on determination of copper in drinking water samples. [Acknowledgements. The authors acknowledge the grant from the Ministry of Education and Science of the Republic of Serbia, Project number 172051

  9. Linear Stabily analysis of hydromagnetic Couette flow with small injection/suction through the modified Orr-Sommerfeld equation

    CERN Document Server

    Hinvi, L A; Orou, J B Chabi

    2013-01-01

    This paper analyses the effects of small injection/suction Reynolds number, Hartmann number, permeability parameter and wave number on a viscous incompressilbe electrically conduction fluid flow in a parallel porous channel. The plates of the channel with small constant injection/suction, have constant temperature. The upper plate is allowed to mouve in flow direction and the lower plate is kept at rest. A magnetic field of uniform strength is also applied normally to the plates what are parallel. The originality of the paper is to study the effect of the above parameter in temporal linear stabilty analysis of the flow throught the modified Orr-Sommerfeld equation.

  10. Flow injection preconcentration system using a new functionalized resin for determination of cadmium and nickel in tobacco samples

    Energy Technology Data Exchange (ETDEWEB)

    Lemos, Valfredo Azevedo [Laboratorio de Quimica Analitica (LQA), Universidade Estadual do Sudoeste da Bahia, Campus de Jequie, Jequie-BA 45206-190 (Brazil)], E-mail: vlemos@uesb.br; Novaes, Cleber Galvao; Lima, Adriana da Silva; Vieira, Daniel Rodrigues [Laboratorio de Quimica Analitica (LQA), Universidade Estadual do Sudoeste da Bahia, Campus de Jequie, Jequie-BA 45206-190 (Brazil)

    2008-06-30

    A solid-phase extraction method combined with flow injection (FI) on-line flame atomic absorption spectrometry (FAAS) for the determination of cadmium and nickel in tobacco samples is presented. The 2-aminothiophenol functionalized Amberlite XAD-4 (AT-XAD) resin was synthesized by covalent coupling of the ligand with the copolymer through a methylene group. A minicolumn packed with AT-XAD was connected into the automated on-line preconcentration system. Elution of metal ions from minicolumn can be made with 0.50 mol L{sup -1} hydrochloric acid solution. With a consumption of 21.0 mL of sample solution, detection limits (3 s) of 0.3 (Cd) and 0.8 {mu}g L{sup -1} (Ni) were achieved at a sample throughput of 18 h{sup -1}. Enrichment factors (EF) of 99 (cadmium) and 43 (nickel) were obtained compared with the slope of the linear portion of the calibration curves before and after preconcentration. The contents of Cd and Ni in a certified reference material (NIST 1570a, spinach leaves) determined by the present method was in good agreement with the certified value. The developed procedure was also successfully applied to the determination of Cd and Ni in local tobacco samples.

  11. Reactive Gas Solids Flow in Circulating Fluidised Beds

    DEFF Research Database (Denmark)

    Hjertager, Bjørn Helge; Solberg, Tron; Hansen, Kim Granly

    2005-01-01

    Progress in modelling and simulation of flow processes in gas/particle systems carried out at the authors? research group are presented. Emphasis is given to computational fluid dynamics (CFD) models that use the multi-dimensional multi fluid techniques. Turbulence modelling strategies for gas/pa...

  12. Effects of fuel injection on mixing and upstream interactions in supersonic flow

    Science.gov (United States)

    Tu, Qiuya

    Scramjet engine performance has been studied experimentally and computationally almost under steady-state conditions. Transients of the airflow and fueling in the scramjet's isolator or combustor create important fluid-dynamic/ combustion interactions. Spark schlieren photography was employed to study the effects of pressure rise in the combustion chamber on the isolator flow at three conditions with isolator entrance Mach number of 1.6, 1.9 and 2.5, covering the range of dual-mode combustion and transition to full scramjet operation. Heat release through combustion in the model scramjet was simulated by incrementally blocking the flow exit until upstream-interaction was induced and a shock train formed in the isolator. Theoretical predictions of the pressure rise in the isolator under separated flow conditions were calculated, which agreed well with the experimental data. The prediction is sensitive to the accurate modeling of the isolator inlet conditions and the correct selection of wall friction coefficient. Gaseous helium and argon have been transversely injected into a Mach 1.6 airflow simulating a light and a heavy fuel injection behind a thin triangular pylon placed upstream, in the isolator, which has a negligible impact on pressure losses. Planar laser-induced fluorescence (PLIF) was used to observe the penetration and mixing in the test section at three cross-sections including the recirculation region and beyond. Results were compared to the no-pylon cases, which showed the presence of the pylon resulted in improving both penetration and spreading of the jet. Simulation for shock wave/ boundary-layer interaction was conducted in Fluent for case of M=1.9 at 60% blockage by using k-ε RNG model with two different near wall treatments. In both cases, the shock ran out of isolator before the computation converged, this is different from experimental results. Proper actual wall friction force may have a very important effect on the computation, which needs

  13. Data uncertainties in material flow analysis: Municipal solid waste management system in Maputo City, Mozambique.

    Science.gov (United States)

    Dos Muchangos, Leticia Sarmento; Tokai, Akihiro; Hanashima, Atsuko

    2017-01-01

    Material flow analysis can effectively trace and quantify the flows and stocks of materials such as solid wastes in urban environments. However, the integrity of material flow analysis results is compromised by data uncertainties, an occurrence that is particularly acute in low-and-middle-income study contexts. This article investigates the uncertainties in the input data and their effects in a material flow analysis study of municipal solid waste management in Maputo City, the capital of Mozambique. The analysis is based on data collected in 2007 and 2014. Initially, the uncertainties and their ranges were identified by the data classification model of Hedbrant and Sörme, followed by the application of sensitivity analysis. The average lower and upper bounds were 29% and 71%, respectively, in 2007, increasing to 41% and 96%, respectively, in 2014. This indicates higher data quality in 2007 than in 2014. Results also show that not only data are partially missing from the established flows such as waste generation to final disposal, but also that they are limited and inconsistent in emerging flows and processes such as waste generation to material recovery (hence the wider variation in the 2014 parameters). The sensitivity analysis further clarified the most influencing parameter and the degree of influence of each parameter on the waste flows and the interrelations among the parameters. The findings highlight the need for an integrated municipal solid waste management approach to avoid transferring or worsening the negative impacts among the parameters and flows.

  14. Effects of Swirl Bubble Injection on Mass Transfer and Hydrodynamics for Bubbly Flow Reactors: A Concept Paper

    Directory of Open Access Journals (Sweden)

    Farooqi Ahmad Salam

    2017-01-01

    Full Text Available Bubble flow reactors (BFR are commonly used for various industrial processes in the field of oil and gas production, pharmaceutical industries, biochemical and environmental engineering etc. The operation and performance of these reactors rely heavily on a range of hydrodynamic parameters; prominent among them are geometric configurations including gas injection geometry, operating conditions, mass transfer etc. A huge body of literature is available to describe the optimum design and performance of bubbly flow reactors with conventional bubble injection. Attempts were made to modify gas injection for improved efficiency of BFR’s. However, here instead of modifying the geometry of the gas injection, an attempt has been made to generate swirl bubbles for gaining larger mass transfer between gas and liquid. Here an exceptionally well thought strategies have been used in our numerical simulations towards the design of swirl injection mechanism, whose paramount aspect is to inhibit the rotary liquid motion but facilitates the swirl movement for bubbles in nearly stationary liquid. Our comprehension here is that the swirl motion can strongly affect the performance of bubbly reactor by identifying the changes in hydrodynamic parameters as compared to the conventional bubbly flows. In order to achieve this bubbly flow, an experimental setup has been designed as well as computational fluid dynamic (CFD code was used with to highlight a provision of swirl bubble injection by rotating the sparger plate.

  15. PIV Measurements of Turbulent Flow in a Channel with Solid or Perforated Ribs

    DEFF Research Database (Denmark)

    Wang, Lei; Salewski, Mirko; Sundén, Bengt

    2011-01-01

    Particle image velocimetry measurements are performed in a channel with periodic ribs on one wall. We investigate the flow around two different rib configurations: solid and perforated ribs with a slit. The ribs obstruct the channel by 20% of its height and are arranged 10 rib heights apart....... For the perforated ribs, the slit height is 20% of the rib height, and the open-area ratio is 16%. We discuss the flow in terms of mean velocity, streamlines, vorticity, turbulence intensity, and Reynolds shear stress. We find that the recirculation bubbles after the perforated ribs are significantly smaller than...... those after the solid ribs. The reattachment length after perforated ribs is smaller by about 45% compared with the solid ribs. In addition, the Reynolds shear stresses around the perforated ribs are significantly smaller than in the solid rib case, leading to a reduction of the pressure loss...

  16. Lagrangian simulation of deposition of CO2 gas-solid sudden expansion flow

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    Freezing and blockage resulting from the deposition of solid CO2 formed because of sudden expansion of the downstream pipe during the release of CO2 through safety valves,will endanger the protected equipment.To overcome this problem,the characteristics of the CO2 gas-solid sudden expansion flow are studied by using the disperse Lagrangian model.A comparison of the calculated deposition of the solid CO2 with the experimental results shows that they are in reasonable agreement.The simulation results show that the size of the solid CO2 formed should not be in the range of 0.04-0.07 mm (St number 3.2-9.8).This can be achieved by using an appropriate flow cross section of the safety valve.

  17. Scaling laws for gas-solid riser flow through two-fluid model simulation

    Institute of Scientific and Technical Information of China (English)

    P.R. Naren; Vivek. V. Ranade

    2011-01-01

    Scale up of gas-solid circulating fluidized bed (CFB) risers poses many challenges to researchers. In this paper, CFD investigation of hydrodynamic scaling laws for gas-solid riser flow was attempted on the basis of two-fluid model simulations, in particular, the recently developed empirical scaling law of Qi, Zhu,and Huang (2008). A 3D computational model with periodic boundaries was used to perform numerical experiments and to study the effect of various system and operating parameters in hydrodynamic scaling of riser flow. The Qi scaling ratio was found to ensure similarity in global parameters like overall crosssectional average solid holdup or pressure drop gradient. However, similarity in local flow profiles was not observed for all the test cases. The present work also highlighted the significance of error bars in reporting experimental values.

  18. Numerical Simulation of Erosion-Corrosion in the Liquid Solid Two-Phase Flow

    Institute of Scientific and Technical Information of China (English)

    2000-01-01

    Erosion-corrosion of liquid-solid two-phase flow occurring in a pipe with sudden expansion in cross section is numerically simulated in this paper. The global model for erosion-corrosion process includes three main components: the liquid-solid two-phase flow model, erosion model and corrosion model. The Euierian-Lagranglan approach is used to simulate liquid-solid two-phase flow, while the stochastic trajectory model was adopted to obtain properties of particle phase. Two-way coupling effect between the fluid and the particle phase is considered in the model. The accuracy of the models is tested by the data in the reference. The comparison shows that the model is basically correct and feasible.

  19. CFD Simulations of Oscillating Flow around Solid and Perforated Plates

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    Damping plates have been used for truss spars in gulf of Mexico to reduce the heave motions. The plates are usually perforated with holes for the passage of marine risers, but the effects of the perforation have not been examined thoroughly. In the present study, a computational fluid dynamics investigation into the hydrodynamic forces is carried out by using FLUENT, which is on two-dimensional perforated plates with varying degrees of perforation in oscillating flow under small Keulegan-Carpenter (KC) number. The numerical results of the hydrodynamic coefficients are presented. The effects of both the perforation ratio (PR) and KC number on the hydrodynamic coefficients of the plates are discussed. Some results of the simulated flow patterns around the plates were also given and discussed.

  20. Determination of sulfate in the wet-process of phosphoric acid by reverse flow injection

    Directory of Open Access Journals (Sweden)

    Wenhui Shi

    2014-01-01

    Full Text Available An improved method based on reverse flow injection is proposed for determining sulfate concentration in the wet-process of phosphoric acid (WPA. The effect of reagent composition, flow rate, temperature, acid concentration, length of the reaction coil, and linear response range on the flow system is discussed in detail. Optimal conditions are established for determining sulfate in the WPA samples. Baseline drift is avoided by a periodic washing step with EDTA in an alkaline medium. A linear response is observed within a range of 20 - 360 mg L-1, given by the equation A = 0.0020C (mg L-1 + 0.0300, R² = 0.9991. The detection limit of the proposed method for sulfate analysis is 3 mg L-1, and the relative standard deviation (n = 12 of sulfate absorbance peak is less than 1.60%. This method has a rate of up to 29 samples per hour, and the results compare well with those obtained with gravimetric method.

  1. The discrete multi-hybrid system for the simulation of solid-liquid flows.

    Directory of Open Access Journals (Sweden)

    Alessio Alexiadis

    Full Text Available This study proposes a model based on the combination of Smoothed Particle Hydrodynamics, Coarse Grained Molecular Dynamics and the Discrete Element Method for the simulation of dispersed solid-liquid flows. The model can deal with a large variety of particle types (non-spherical, elastic, breakable, melting, solidifying, swelling, flow conditions (confined, free-surface, microscopic, and scales (from microns to meters. Various examples, ranging from biological fluids to lava flows, are simulated and discussed. In all cases, the model captures the most important features of the flow.

  2. A solid state paramagnetic maser device driven by electron spin injection

    NARCIS (Netherlands)

    Watts, S. M.; van Wees, B. J.

    2006-01-01

    In response to an external, microwave-frequency magnetic field, a paramagnetic medium will absorb energy from the field that drives the magnetization dynamics. Here we describe a new process by which an external spin-injection source, when combined with the microwave field spin pumping, can drive

  3. A solid state paramagnetic maser device driven by electron spin injection

    NARCIS (Netherlands)

    Watts, S. M.; van Wees, B. J.

    2006-01-01

    In response to an external, microwave-frequency magnetic field, a paramagnetic medium will absorb energy from the field that drives the magnetization dynamics. Here we describe a new process by which an external spin-injection source, when combined with the microwave field spin pumping, can drive th

  4. Mixed Model for Silt-Laden Solid-Liquid Two-Phase Flows

    Institute of Scientific and Technical Information of China (English)

    唐学林; 徐宇; 吴玉林

    2003-01-01

    The kinetic theory of molecular gases was used to derive the governing equations for dense solid-liquid two-phase flows from a microscopic flow characteristics viewpoint by multiplying the Boltzmann equation for each phase by property parameters and integrating over the velocity space. The particle collision term was derived from microscopic terms by comparison with dilute two-phase flow but with consideration of the collisions between particles for dense two-phase flow conditions and by assuming that the particle-phase velocity distribution obeys the Maxwell equations. Appropriate terms from the dilute two-phase governing equations were combined with the dense particle collision term to develop the governing equations for dense solid-liquid turbulent flows. The SIMPLEC algorithm and a staggered grid system were used to solve the discretized two-phase governing equations with a Reynolds averaged turbulence model. Dense solid-liquid turbulent two-phase flows were simulated for flow in a duct. The simulation results agree well with experimental data.

  5. The impact of flow injection on modem chemical analysis: has it fulfilled our expectations? And where are we going?

    DEFF Research Database (Denmark)

    Hansen, Elo Harald

    2004-01-01

    Presenting a condensation of the opening lecture of the 12th ICFIA conference, this communication presents a view of the impact that flow injection analysis (FIA) has had on modern analytical chemistry, evaluated both within the academic community and outside it, i.e., in “industry”. The ensuing ...... developments of FIA, encompassing sequential injection analysis (SIA) and bead injection lab-on-valve (BI-LOV), are described and their individual features discussed. Finally some recent results of the activities from the author’s own research group are briefly mentioned.......Presenting a condensation of the opening lecture of the 12th ICFIA conference, this communication presents a view of the impact that flow injection analysis (FIA) has had on modern analytical chemistry, evaluated both within the academic community and outside it, i.e., in “industry”. The ensuing...

  6. SPH-DCDEM model for arbitrary geometries in free surface solid-fluid flows

    Science.gov (United States)

    Canelas, Ricardo B.; Crespo, Alejandro J. C.; Domínguez, Jose M.; Ferreira, Rui M. L.; Gómez-Gesteira, Moncho

    2016-05-01

    A unified discretization of rigid solids and fluids is introduced, allowing for resolved simulations of fluid-solid phases within a meshless framework. The numerical solution, attained by Smoothed Particle Hydrodynamics (SPH) and a variation of Discrete Element Method (DEM), the Distributed Contact Discrete Element Method (DCDEM) discretization, is achieved by directly considering solid-solid and solid-fluid interactions. The novelty of the work is centred on the generalization of the coupling of the DEM and SPH methodologies for resolved simulations, allowing for state-of-the-art contact mechanics theories to be used in arbitrary geometries, while fluid to solid and vice versa momentum transfers are accurately described. The methods are introduced, analysed and discussed. Initial validations on the DCDEM and the fluid coupling are presented, drawing from test cases in the literature. An experimental campaign serves as a validation point for complex, large scale solid-fluid flows, where a set of blocks in several configurations is subjected to a dam-break wave. Blocks are tracked and positions are then compared between experimental data and the numerical solutions. A Particle Image Velocimetry (PIV) technique allows for the quantification of the flow field and direct comparison with numerical data. The results show that the model is accurate and is capable of treating highly complex interactions, such as transport of debris or hydrodynamic actions on structures, if relevant scales are reproduced.

  7. Selective determination of chlorine dioxide using gas diffusion flow injection analysis

    Energy Technology Data Exchange (ETDEWEB)

    Hollowell, D.A.; Pacey, G.E.; Gordon, G.

    1985-12-01

    An automated absorbance technique for the determination of aqueous chlorine dioxide has been developed by utilizing gas diffusion flow injection analysis. A gas diffusion membrane is used to separate the donor (sampling) stream from the acceptor (detecting) stream. The absorbance of chlorine dioxide is monitored at 359 nm. The first method uses distilled water as the acceptor stream and gives a detection limit of 0.25 mg/L chlorine dioxide. This system is over 550 times more selective for chlorine dioxide than chlorine. To further minimize chlorine interference, oxalic acid is used in the acceptor stream. The detection limit for this system is 0.45 mg/L chlorine dioxide. This second system is over 5400 times more selective for chlorine dioxide than chlorine. Both methods show excellent selectivity for chlorine dioxide over iron and manganese compounds, as well as other oxychlorinated compounds such as chlorite and perchlorate ions. 18 references, 7 figures, 3 tables.

  8. The Determination of Iodide Based on a Flow-injection Coupling Irreversible Biamperometry

    Institute of Scientific and Technical Information of China (English)

    Li Jun LI; Hao CHENG; Wen Yi HUANG; Hong Xing KONG; Jian Ling WU; Jian Ping LU; Wei GAO; Jun Feng SONG

    2005-01-01

    A novel flow-injection irreversible biamperometric method is described for the direct determination of iodide. The method is based on electrochemical oxidation of iodide at the gold electrode and the reduction of permanganate at the platinum electrode to form an irreversible biamperometric detection system. Under the applied potential difference of 0 V, in the 0.05mol/L sulfuric acid, iodide can be determined over the range 4.00×10-7-l.00×l0-5 mol/L with a sampling frequency of 120 samples per hour. The detection limit for Ⅰ- is 3.0× 10-7 mol/L and the RSD for 40 replicate determinations of 4.0×10-5 mol/L potassium iodide is 1.68%. The new method was applied to the analysis of iodide in table salt with satisfactory results.

  9. Selective spectrofluorimetric determination of zinc in biological samples by Flow Injection Analysis (FIA)

    Energy Technology Data Exchange (ETDEWEB)

    Fernandez, P.; Perez Conde, C.; Gutierrez, A.; Camara, C. (Universidad Complutense, Madrid (Spain). Dept. de Quimica Analitica)

    1992-03-01

    The automatization of a spectrofluorimetric method for the determination of zinc at trace level is described. It is based on the formation of the fluorescent complex Zn(II)-5,7-dibromo-8-quinolinol (Zn(II)-DBQ) followed by extraction into diethylether using flow injection analysis. The optimum fluorescent emission is reached in hexamethylenetetramine (H{sub 2}MTA{sup +}/HMTA) buffer pH 6.0. A membrane phase separator was used. The calibration graph is linear up to 1.5 {mu}g/ml of Zn(II). The proposed method (detection limit 3 ng/ml) is very selective and has been successfully applied to determine Zn(II) in biological samples, tap waters and various food items. (orig.).

  10. Filterless preconcentration, flow injection analysis and detection by inductively-coupled plasma mass spectrometry

    DEFF Research Database (Denmark)

    Andersen, Jens Enevold Thaulov

    The influence of interferences in the analysis of elements by inductively-coupled-plasma mass-spectrometry (ICP-MS) may be significantly diminished by utilising a protocol of flow-injection analysis (FIA). The method is based on filterless preconcentration of metallic elements at the walls...... of a knotted reactor that was made of nylon tubings. In the load mode, the preconcentration was accomplished by precipitation of metallic species in alkaline-buffered carriers onto the inner walls of the hydrofilic tube. After a preconcen-tration period of 40-120 seconds using sample volumes of 4-10 m......L, the analyte was transferred by a FIAS 400 system to the ICP-MS detector by dissolving the species in an acidic carrier. The magnitude of the enrichment factor largely depended on the time of preconcentration, on the pH-value of the preconcentration buffer and on the pH-value of the samples. Enrichment factors...

  11. Free-convection flow past a horizontal surface in a nanofluid with suction/injection

    Science.gov (United States)

    Adnan, Nurul Shahirah Mohd; Arifin, Norihan Md; Bachok, Norfifah; Nazar, Roslinda

    2017-08-01

    The present work deals with the steady free-convection boundary-layer flow past a horizontal permeable surface embedded in a porous medium filled with a nanofluid. The similarity transformation was applied to the governing equations to transform into a system of ordinary differential equations, which are then solved numerically using Runge-Kutta-Fehlberg fourth-fifth order (RKF45) method. Three types of nanoparticles which are titania (TiO2), alumina (Al2O3), and copper (Cu) in the based fluid of water are considered to investigate the effect of the nanoparticle volume fraction parameter, υ. Results are presented and discussed for the local Nusselt number, the surface velocity, the temperature profiles, and the velocity profile. It is found that the imposition of suction/injection has an impact on the velocity profiles and temperature profiles.

  12. Flow structure of conical distributed multiple gas jets injected into a water chamber

    Energy Technology Data Exchange (ETDEWEB)

    Zhao, Jiajun; Yu, Yonggang [Nanjing University of Science and Technology, Nanjing (China)

    2017-04-15

    Based on an underwater gun firing project, a mock bullet with several holes on the head was designed and experimented to observe the combustion gas injected into a cylindrical water chamber through this mock bullet. The combustion gas jets contain one vertical central jet and 4 to 8 slant lateral jets. A high speed camera system was used to record the expansion of gas jets in the experimental study. In numerical simulations, the Euler two-fluid model and volume of fluid method were adopted to describe the gas-liquid flow. The results show the backflow zone in lateral jet is the main factor influencing the gas-liquid turbulent mixing in downstream. On cross sections, the gas volume fraction increased with time but the growth rate decreased. With a change of nozzle structure, the gas fraction was more affected than the shock structure.

  13. Dissipation on Steady MHD Marangoni Convection Flow over a Flat Surface with Suction and Injection

    Directory of Open Access Journals (Sweden)

    S. Mohammed Ibrahim

    2013-01-01

    Full Text Available The combined effects of radiation and mass transfer on a steady MHD two-dimensional Marangoni convection flow over a flat surface in presence of Joule heating and viscous dissipation under influence of suction and injection is studied numerically. The general governing partial differential equations are transformed into a set of nonlinear ordinary differential equations by using unique similarity transformation. Numerical solutions of the similarity equations are obtained using the Runge-Kutta method along with shooting technique. The effects of governing parameters on velocity, temperature, and concentration as well as interface velocity, the surface temperature gradient, and the surface concentration gradient were presented in graphical and tabular forms. Comparisons with previously published work are performed and the results are found to be in excellent agreement.

  14. Preprocessing, classification modeling and feature selection using flow injection electrospray mass spectrometry metabolite fingerprint data.

    Science.gov (United States)

    Enot, David P; Lin, Wanchang; Beckmann, Manfred; Parker, David; Overy, David P; Draper, John

    2008-01-01

    Metabolome analysis by flow injection electrospray mass spectrometry (FIE-MS) fingerprinting generates measurements relating to large numbers of m/z signals. Such data sets often exhibit high variance with a paucity of replicates, thus providing a challenge for data mining. We describe data preprocessing and modeling methods that have proved reliable in projects involving samples from a range of organisms. The protocols interact with software resources specifically for metabolomics provided in a Web-accessible data analysis package FIEmspro (http://users.aber.ac.uk/jhd) written in the R environment and requiring a moderate knowledge of R command-line usage. Specific emphasis is placed on describing the outcome of modeling experiments using FIE-MS data that require further preprocessing to improve quality. The salient features of both poor and robust (i.e., highly generalizable) multivariate models are outlined together with advice on validating classifiers and avoiding false discovery when seeking explanatory variables.

  15. Numerical Computation of Flow and Heat Transfer from an Enclosed Rotating Disk with Suction and Injection

    Directory of Open Access Journals (Sweden)

    R. S. Agarwal

    1980-04-01

    Full Text Available The Newton Raphson technique has been employed to solve the set of non-linear equations governing the problem of flow and heat transfer from an enclosed rotating disc. /The disc called rotor is subjected to uniform injection while the top of the housing called stator, to an equal suction. The results for small Reynold numbers are found in good agreement to that obtained earlier by series solution. The radial and transverse velocity profiles for large Reynolds have been plotted in the regions of no recirculation. The effect of net radial inflow and outflow on temperature in the no-recirculation region has also been studied. The method is significant in this respect that it yields satisfactory results for large Reynolds numbers.

  16. Comparison of Uric Acid Quantity with Different Food in Human Urine by Flow Injection Chemiluminescence Analysis

    Directory of Open Access Journals (Sweden)

    Jiajia Wang

    2013-01-01

    Full Text Available Based on the inhibitory effect of uric acid (UA on luminol-Co2+ chemiluminescence (CL system, a sensitive method for the determination of UA at nanomolar level by flow injection (FI CL was proposed. The proposed method was successfully applied to real-time monitoring of UA excretion in human 24 h urine with different food intake, showing that meats, vegetables, and porridge intake caused differential UA excretions of 879, 798, and 742 mg, respectively. It was also found that UA concentrations in urine under the three kinds of food intake simultaneously reached maximum at 2 h after meals with the values of 417, 318, and 288 μg mL−1, respectively. The UA concentration in human serum was also determined by this approach, and the possible mechanism of luminol-Co2+-UA CL reaction was discussed in detail.

  17. Reversed flow injection spectrophotometric determination of low residuals of chlorine dioxide in water using chlorophenol red

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    A novel,simple,rapid,sensitive and highly selective flow injection procedure for the spectrophotometrie determination of chlorine dioxide in the presence of other chlorine species,viz,free chlorine,chlorite,chlorate and hypoehlorite,is developed.The method is based on the discoloration reaction between chlorine dioxide and chlorophenol red and can overcome the shortcomings existed in direct speetrophotometrie determination for chlorine dioxide owing to the serious interference of free and combined chlorine.The procedure gave a linear calibration graph over the range 0-0.71 mg/L of chlorine dioxide.With a detection limit of 0.024 mg/L and a sample throughput of 60 samples/h.

  18. Flow-injection chemiluminescence determination of tryptophan using galangin-potassium permanganate-polyphosphoric acid system

    Institute of Scientific and Technical Information of China (English)

    Hui Chen; Li Li; Min Zhou; Yong Jun Ma

    2008-01-01

    A high sensitive flow-injection chemiluminescence (FI-CL)method for the determination of tryptephan has been developed.The method is based on the chemiluminescence reaction of galangin-potassium perrnanganate-tryptophan in polyphosphoric acid (PPA)media.Under the optimized conditions,tryptophan was determined in the range 0.05-10 μg/mL with the detection limit (30)of 5.0× 10-3 μg/mL.The relative standard deviation (RSD)was 1.0% for 11 replicate determinations of 1.0 μg/mL tryptophan.Three synthetic samples were determined selectively with recoveries in the range from 99.6% to 102.0% in the presence of other amino acids.

  19. GAS-SOLIDS FLOW BEHAVIOR WITH A GAS VELOCITY CLOSE TO ZERO

    Institute of Scientific and Technical Information of China (English)

    H.; Zhang; J.-X.; Zhu

    2006-01-01

    In a 9.3 m high and 0.10 m i.d. gas-solids downflow fluidized bed (downer), the radial and axial distributions of the local solids holdups and particle velocities along the downer column were measured with the superficial gas velocity set to zero. A unique gas-solids flow structure was found in the downer system with zero gas velocity, which is completely different from that under conditions with higher gas velocities, in terms of its radial and axial flow structures as well as its micro flow structure. The gas-solids flow pattern under zero gas velocity conditions, together with that under low gas velocity conditions, can be considered as a special regime which differs from that under higher gas velocity conditions. According to the hydrodynamic properties of the two regimes, they can be named the "dense annulus" regime for the flow pattern under zero or low gas velocity conditions and the "dense core" regime for that under higher gas velocity conditions.

  20. Flow-injection Spectrophotometric Determination of Uric Acid in Urine via Prussian Blue Reaction

    Institute of Scientific and Technical Information of China (English)

    WASEEM Amir; YAQOOB Mohammad; NABI Abdul; MURTAZA Ghulam; HUSSAIN Izhar

    2011-01-01

    A simple and sensitive flow injection(FI)spectrophotometric method was reported for the determination of uric acid based on the reduction of Fe(Ⅲ)/ferricyanide in the presence of uric acid.The in situ reduced ions reacted with unreduced portion of ferricyanide/Fe(Ⅲ)to form soluble Prussian blue,which was monitored at an absorption wavelength of 735 nm.The optimized conditions allow a linear calibration graph in a concentration range of 1-100μmol/L.The relative standard deviation was in a range of 0.5%-2.5%,with a detection limit(3σ blank)of 0.3 μmol/L and a sampling frequency of 60 injection/h was obtained.The effect of common substances present in human physiological fluids on the determination of uric acid was examined.The method was applied to determining uric acid in human urine samples with the recoveries in a range of 96%-105%.The results agree well with those by spectrophotometric reference method at a confidence level of 95%.Spectrophotometric procedures for uric acid determination in clinical samples were reviewed briefly.

  1. Determination of arsenic in a nickel alloy by flow injection hydride generation atomic absorption spectrometry

    Science.gov (United States)

    Hanna, C. P.; Tyson, J. F.; Offley, S. G.

    1992-08-01

    The development of a method for the direct determination of trace arsenic quantities in nickel alloy digests, by flow injection hydride generation atomic absorption spectrometry, is described. An optimization study of the manifold and chemical parameters produced system performance, in terms of tolerance of the nickel matrix and sensitivity, such that matrix removal and pre-reduction of As(V) to As (III) prior to arsine generation were eliminated. Full recovery of the As(V) signal from a solution containing 5 ng ml -1 in the presence of 60 μg ml -1 nickel was obtained. Validation of the method was achieved by analyzing a British Chemical Standard (BCS) Certified Reference Material (CRM) #346 IN nickel alloy containing arsenic at a concentration of 50 μg g -1. Following dissolution in nitric and hydrofluoric acids by a microwave assisted procedure, the only subsequent preparation required was dilution by the appropriate factor. Up to 60 injections h -1 may be made, with a detection limit of 0.5 ng ml -1 arsenic (250 pg absolute) as As(V) in a 500 μl sample. The peak height characteristic concentration is 0.46 ng ml -1, with a relative standard deviation of 3.5% for a 10 ng ml -1 As(V) standard ( n = 6).

  2. Flow injection spectrophotometry using natural reagent from Morinda citrifolia root for determination of aluminium in tea.

    Science.gov (United States)

    Tontrong, Sopa; Khonyoung, Supada; Jakmunee, Jaroon

    2012-05-01

    A flow injection (FI) spectrophotometric method with using natural reagent extracted from Morinda citrifolia root has been developed for determination of aluminium. The extract contained anthraquinone compounds which could react with Al(3+) to form reddish complexes which had maximum absorption wavelength at 499.0nm. The extract could be used as a reagent in FI system without further purification to obtain pure compound. A sensitive method for determination of aluminium in concentration range of 0.1-1.0mgL(-1), with detection limit of 0.05mgL(-1) was achieved. Relative standard deviations of 1.2% and 1.7% were obtained for the determination of 0.1 and 0.6mgL(-1) Al(3+) (n=11). Sample throughput of 35h(-1) was achieved with the consumption of 3mL each of carrier and reagent solutions per injection. The developed method was successfully applied to tea samples, validated by the FAAS standard method. The method is simple, fast, economical and could be classified as a greener analytical method.

  3. Determination of Melatonin in Rat Pineal Gland and Drug with Flow-Injection Chemiluminescence

    Institute of Scientific and Technical Information of China (English)

    WEI,Shou-Lian; ZHAO,LI-Xia; CHENG,Xiang-Lei; LIN,Jin-Ming

    2007-01-01

    A flow-injection chemiluminescence(CL)method for the determination of melatonin based on the CL reaction of melatonin with hydrogen peroxide and sodium hypochlorite(NaOCl)in a basic alkaline solution was developed.The possible CL mechanism has been discussed,and a proposal for the reaction pathway was given that singlet oxygen was clarified to be produced in this reaction system and was responsible for the CL emission.Under the optimized conditions.the linear concentration range of application was 1.0 X 10-7-2.5×10-4 mol·L-1 with a detection Iimit of 5.0X 10-8 mol·L-1(S/N=3).The relative standard deviation for eight repeated measurements of 1.0×10-6 mol·L-1 melatonin was 2.8%.The interferences of several important biological substances.some indole compound,cations and anions were studied.No interference was found for the anions,glucose,starch,most of cations and low concentration(less than 3.0×10-6 mol·L-1)of some biological substances and indole compound.The method was applied to the determination of melatonin in rat pineal gland and drug with satisfactory results.The sample throughput was 90 injections per hour.

  4. Numerical investigation of scale effect of various injection diameters on interaction in cold kerosene-fueled supersonic flow

    Science.gov (United States)

    Zhu, Lin; Qi, Yin-Yin; Liu, Wei-Lai; Xu, Bao-Jian; Ge, Jia-Ru; Xuan, Xiang-Chun; Jen, Tien-Chien

    2016-12-01

    The incident shock wave generally has a strong effect on the transversal injection field in cold kerosene-fueled supersonic flow, possibly due to its affecting the interaction between incoming flow and fuel through various operation conditions. This study is to address scale effect of various injection diameters on the interaction between incident shock wave and transversal cavity injection in a cold kerosene-fueled scramjet combustor. The injection diameters are separately specified as from 0.5 to 1.5 mm in 0.5 mm increments when other performance parameters, including the injection angle, velocity and pressure drop are all constant. A combined three dimensional Couple Level Set & Volume of Fluids (CLSVOF) approach with an improved K-H & R-T model is used to characterize penetration height, span expansion area, angle of shock wave and sauter mean diameter (SMD) distribution of the kerosene droplets with/without considering evaporation. Our results show that the injection orifice surely has a great scale effect on the transversal injection field in cold kerosene-fueled supersonic flows. Our findings show that the penetration depth, span angle and span expansion area of the transverse cavity jet are increased with the injection diameter, and that the kerosene droplets are more prone to breakup and atomization at the outlet of the combustor for the orifice diameter of 1.5 mm. The calculation predictions are compared against the reported experimental measurements and literatures with good qualitative agreement. The simulation results obtained in this study can provide the evidences for better understanding the underlying mechanism of kerosene atomization in cold supersonic flow and scramjet design improvement.

  5. Espectrofotometria de zinco em fertilizantes em fluxo Flow injection spectrophotometry of zinc in mineral fertilizers

    Directory of Open Access Journals (Sweden)

    Arnaldo Antonio Rodella

    1999-07-01

    Full Text Available Um sistema de análise química por injeção em fluxo é proposto para a determinação espectrofotométrica de zinco em amostras de misturas de fertilizantes minerais, empregando-se zincon como reagente cromogênico. O procedimento analítico envolve redução de íons metálicos por ácido ascórbico, complexação com íon cianeto, seguindo-se a descomplexação seletiva do zinco com formaldeído, liberando-o para que reaja com o zincon formando um complexo azul. A aplicação do método proposto à extratos de mistura de fertilizantes indicou que a ação de interferentes pode ser contornada e que resultados comparáveis aos da espectrometria de absorção atômica são obtidos.A flow injection system for zinc analysis in mineral fertilizer mixtures is proposed using zincon as chromogenic reagent. The effect of interfering ions such as Cu2+, Fe3+, Mn2+ was eliminated by reduction (using ascorbic acid and complexation of these metal íons with cyanide, with zinc included. Zinc is allowed to react with zincon only after the destruction of the zinc cyano complex with formaldehyde. Flow injection analysis permitted efficient control of the reaction time so that only the zinc ion is set free to produce a blue complex with zincon. Zinc was determined in 16 fertilizer mixtures (3 replicates with precision and accuracy comparable to atomic absorption spectrometry.

  6. Use of flow injection mass spectrometric fingerprinting and chemometrics for differentiation of three black cohosh species

    Energy Technology Data Exchange (ETDEWEB)

    Huang, Huilian [Food Composition and Methods Development Laboratory, Beltsville Human Nutrition Research Center, Agricultural Research Service, U.S. Department of Agriculture, Beltsville, MD (United States); Key Laboratory of Modern Preparation of TCM, Jiangxi University of Traditional Chinese Medicine, Ministry of Education, Nanchang, Jiangxi Province (China); Sun, Jianghao [Food Composition and Methods Development Laboratory, Beltsville Human Nutrition Research Center, Agricultural Research Service, U.S. Department of Agriculture, Beltsville, MD (United States); McCoy, Joe-Ann [The North Carolina Arboretum Germplasm Repository, UNC Affiliate Campus, Asheville, NC (United States); Zhong, Haiyan [College of Food Science and Engineering, Central South University of Forestry and Technology, Changsha, Hunan Province (China); Fletcher, Edward J. [Strategic Sourcing, Inc., Banner Elk, NC 28604 (United States); Harnly, James, E-mail: harnly.james@ars.usda.gov [Food Composition and Methods Development Laboratory, Beltsville Human Nutrition Research Center, Agricultural Research Service, U.S. Department of Agriculture, Beltsville, MD (United States); Chen, Pei, E-mail: pei.chen@ars.usda.gov [Food Composition and Methods Development Laboratory, Beltsville Human Nutrition Research Center, Agricultural Research Service, U.S. Department of Agriculture, Beltsville, MD (United States)

    2015-03-01

    Flow injection mass spectrometry (FIMS) was used to provide chemical fingerprints of black cohosh (Actaea racemosa L.) in a manner of minutes by omitting the separation step. This method has proven to be a powerful tool for botanical authentication and in this study it was used to distinguish between three Actaea species prior to a more detailed chemical analysis using ultra high-performance liquid chromatography high-resolution mass spectrometry (UHPLC–HRMS). Black cohosh has become increasingly popular as a dietary supplement in the United States for the treatment of symptoms related to menopause. However, it has been known to be adulterated with the Asian Actaea dahurica (Turcz. ex Fisch. & C.A.Mey.) Franch. species (syn. Cimicifuga dahurica (Turcz.) Maxim). Existing methods for identification of black cohosh and differentiation of Actaea species are usually lengthy, laborious, and lack robustness, often based on the comparison of a few pre-selected components. Chemical fingerprints were obtained for 77 black cohosh samples and their related species using FIMS in the negative ion mode. The analysis time for each sample was less than 2 min. All data were processed using principal component analysis (PCA). FIMS fingerprints could readily differentiate all three species. Representative samples from each of the three species were further examined using UHPLC–MS to provide detailed profiles of the chemical differences between the three species and were compared to the PCA loadings. This study demonstrates a simple, fast, and easy analytical method that can be used to differentiate A. racemosa, Actaea podocarpa, and A. dahurica. - Highlights: • Flow injection mass spectrometry (FIMS) was used to provide chemical fingerprints of black cohosh (Actaea racemosa L.) in a manner of minutes by omitting the separation step. • FIMS can discriminate between A. dahurica, A. podocarpa, and A. racemosa. • FIMS is a valuable screening tool for authentication of botanicals.

  7. Charge Injection, Charge Trapping and Charge Transfer in Quantum-Dot Solids

    NARCIS (Netherlands)

    Boehme, S.C.

    2015-01-01

    This study reports on fundamental processes in Quantum-Dot Solids, after light absorption. Transient Absorption and Time-resolved Photoluminescence spectrocopy reveal the dynamics of charge transfer and charge trapping processes. Typically, both occur on a picosecond time scale and compete with each

  8. A 3-D nonisothermal flow simulation and pulling force model for injection pultrusion processes

    Science.gov (United States)

    Mustafa, Ibrahim

    1998-12-01

    Injected Pultrusion (IP) is an efficient way of producing high quality, low cost, high volume and constant cross-section polymeric composites. This process has been developed recently, and the efforts to optimize it are still underway. This work is related to the development of a 3-D non-isothermal flow model for the IP processes. The governing equations for transport of mass, momentum and, energy are formulated by using a local volume averaging approach, and the Finite Element/Control Volume method is used to solve the system of equations numerically. The chemical species balance equation is solved in the Lagrangian frame of reference whereas the energy equation is solved using Galerkin, SU (Streamline Upwind), and SUPG (Streamline Upwind Petrov Galerkin) approaches. By varying degrees of freedom and the flow rates of the resin, it is shown that at high Peclet numbers the SUPG formulation performs better than the SU and the Galerkin methods in all cases. The 3-D model predictions for degree of cure and temperature are compared with a one dimensional analytical solution and the results are found satisfactory. Moreover, by varying the Brinkman Number, it is shown that the effect of viscous dissipation is insignificant. The 3-D flow simulations have been carried out for both thin and thick parts and the results are compared with the 2-D model. It is shown that for thick parts 2-D simulations render erroneous results. The effect of changing permeability on the flow fronts is also addressed. The effect of increasing taper angle on the model prediction is also investigated. A parametric study is conducted to isolate optimum conditions for both isothermal and non-isothermal cases using a straight rectangular die and a die with a tapered inlet. Finally, a simple pulling force model is developed and the pulling force required to pull the carbon-epoxy fiber resin system is estimated for dies of varying tapered inlet.

  9. Phosphite determination in fertilizers after online sequential sample preparation in a flow injection system.

    Science.gov (United States)

    Dametto, Patrícia Roberta; Franzini, Vanessa Pezza; Gomes Neto, José Anchieta

    2007-07-25

    A flow injection spectrophotometric system is proposed for phosphite determination in fertilizers by the molybdenum blue method after the processing of each sample two times on-line without and with an oxidizing step. The flow system was designed to add sulfuric acid or permanganate solutions alternately into the system by simply displacing the injector-commutator from one resting position to another, allowing the determination of phosphate and total phosphate, respectively. The concentration of phosphite is obtained then by difference between the two measurents. The influence of flow rates, sample volume, and dimension of flow line connecting the injector-commutator to the main analytical channel was evaluated. The proposed method was applied to phosphite determination in commercial liquid fertilizers. Results obtained with the proposed FIA system were not statistically different from those obtained by titrimetry at the 95% confidence level. In addition, recoveries within 94 and 100% of spiked fertilizers were found. The relative standard deviation (n = 12) related to the phosphite-converted-phosphate peak alone was

  10. Numerical simulation of predicting and reducing solid particle erosion of solid-liquid two-phase flow in a choke

    Institute of Scientific and Technical Information of China (English)

    Li Guomei; Wang Yueshe; He Renyang; Cao Xuewen; Lin Changzhi; Meng Tao

    2009-01-01

    Chokes are one of the most important components of downhole flow-control equipment. The particle erosion mathematical model, which considers particle-particle interaction, was established and used to simulate solid particle movement as well as particle erosion characteristics of the solid-liquid two-phase flow in a choke. The corresponding erosion reduction approach by setting ribs on the inner wall of the choke was advanced. This mathematical model includes three parts: the flow field simulation of the continuous carrier fluid by an Eulerian approach, the particle interaction simulation using the discrete particle hard sphere model by a Lagrangian approach and calculation of erosion rate using semi-empirical correlations. The results show that particles accumulated in a narrow region from inlet to outlet of the choke and the dominating factor affecting particle motion is the fluid drag force. As a result, the optimization of rib geometrical parameters indicates that good anti-erosion performance can be achieved by four ribs, each of them with a height (H) of 3 mm and a width (B) of 5 mm equaling the interval between ribs (L).

  11. CFD Simulation of Liquid-solid Multiphase Flow in Mud Mixer

    Directory of Open Access Journals (Sweden)

    T.Y. Kim

    2016-08-01

    Full Text Available In the present study, a computational fluid dynamics (CFD simulation was performed to analyze the mixing phenomena associated with multi-phase flow in a mud mixing system. For the validation of CFD simulation, firstly a liquid-solid multiphase flow inside horizontal pipe was simulated and compared with the experiments and other numerical simulations. And then, the multiphase flow simulation was carried out for the mud mixer in the drilling handling system in order to understand mixing phenomena and predict the mixing efficiency. For the modeling and simulation, a commercial software, STAR-CCM+, based on a finite-volume method (FVM was adopted. The simulation results for liquid-solid flow inside the pipe shows a good agreement with the experimental data. With the same multiphase model, the simulation for mud mixer is performed under the generalized boundary condition and then pressure drop through the mud mixer will be discussed.

  12. Automatic flow injection based methodologies for determination of scavenging capacity against biologically relevant reactive species of oxygen and nitrogen.

    Science.gov (United States)

    Magalhães, Luís M; Lúcio, Marlene; Segundo, Marcela A; Reis, Salette; Lima, José L F C

    2009-06-15

    Redox reactions are the heart of numerous biochemical pathways found in cellular chemistry, generating reactive oxygen species (ROS) and reactive nitrogen species (RNS), that includes superoxide anion radical (O2-), hydrogen peroxide (H2O2), hydroxyl radical (HO), singlet oxygen ((1)O2), hypochlorite anion (OCl-), peroxynitrite anion (ONOO-) and nitric oxide radical (NO). The measurement of scavenging capacity against these reactive species presents new challenges, which can be met by flow injection analysis (FIA). In the present review several methods based on FIA and also on its predecessors computer-controlled techniques (sequential injection analysis, multisyringe flow injection analysis, multicommutated and multipumping flow systems) are critically discussed. The selectivity and applicability of the methodology, the generation and detection of the target reactive species, the benefits and limitations of automation when compared to batch methods are some of the issues addressed.

  13. An electron spin injection driven, paramagnetic solid-state MASER device

    OpenAIRE

    Watts, S. M.; van Wees, B. J.

    2006-01-01

    In response to an external, microwave-frequency magnetic field, a paramagnetic medium will absorb energy from the field that drives the magnetization dynamics. Here we describe a new process by which an external spin injection source, when combined with the microwave field spin-pumping, can drive the paramagnetic medium from one that absorbs microwave energy to one that emits microwave energy. We derive a simple condition for the crossover from absorptive to emissive behavior. Based on this p...

  14. On-line sample-pre-treatment schemes for trace-level determinations of metals by coupling flow injection or sequential injection with ICP-MS

    DEFF Research Database (Denmark)

    Wang, Jianhua; Hansen, Elo Harald

    2003-01-01

    for on-line matrix separation and pre-concentration of trace levels of metals with detection by ICP-MS. It highlights some of the frequently applied on-line, sample-pre-treatment schemes, including solid phase extraction (SPE), on-wall molecular sorption and precipitate/(co)-precipitate retention using...... a polytetrafluoroethylene (PTFE) knotted reactor (KR), solvent extraction-back extraction and hydride/vapor generation. It also addresses a novel, robust approach, whereby the protocol of SI-LOV-bead injection (BI) on-line separation and pre-concentration of ultra-trace levels of metals by a renewable microcolumn...

  15. Effect of botulinum toxin type A injection into human masseter muscle on stimulated parotid saliva flow rate.

    Science.gov (United States)

    Kwon, J S; Kim, S T; Jeon, Y M; Choi, J H

    2009-04-01

    Botulinum toxin type A (BTX-A) injection into the masseter muscles is used to treat masseteric hypertrophy. No serious side effects of BTX-A have been reported, but patients sometimes complain of xerostomia. The aim of this study was to evaluate the effect of injecting BTX-A into the masseter for the treatment of masseteric hypertrophy on the flow of saliva from the parotid gland. 34 volunteers enrolled in this study. A total of 25 units of BTX-A was injected into each side bilaterally at two points at the center of the lower third of the masseter muscle. Saliva was collected from the parotid gland over a period of 10 min to determine the flow rate for 18 weeks after injection. The flow rate was calculated by dividing the amount in milliliters by the collection time in minutes. There were no significant changes in the stimulated parotid saliva flow at 4, 8, 12 or 18 weeks compared with the baseline. Within this limited study, it can be concluded that BTX-A injection into the masseter does not cause any significant decrease in the production of saliva from the parotid gland.

  16. Two-phase flow effects on the CO2 injection pressure evolution and implications for the caprock geomechanical stability

    OpenAIRE

    Vilarrasa Víctor; Carrera Jesús; Olivella Sebastià

    2016-01-01

    Geologic carbon storage is considered to be one of the main solutions to significantly reduce CO2 emissions to the atmosphere to mitigate climate change. CO2 injection in deep geological formations entails a two-phase flow, being CO2 the non-wetting phase. One of the main concerns of geologic carbon storage is whether the overpressure induced by CO2 injection may compromise the caprock integrity and faults stability. We numerically investigate the two-phase flow effects that govern the overpr...

  17. Role of viscoelasticity in instability in plane shear flow over a deformable solid

    Indian Academy of Sciences (India)

    Paresh Chokshi

    2015-05-01

    The stability of the flow of a viscoelastic fluid over a deformable elastic solid medium is reviewed focusing on the role played by the fluid elasticity on the earlier known instability modes for the Newtonian fluids. In particular, two classes of modes are emphasized: the viscous mode for the creeping flow, and the wall mode for high Reynolds number flow. The flow geometry is restricted to plane Couette flow of fluid supported on elastic substrate of finite thickness. The viscoelastic fluid is described using the Oldroyd-B model and the dynamics of the deformable solid continuum is described by either Hookean or neo-Hookean elastic model. In the limit of $Re \\to 0$, the introduction of fluid elasticity delays the onset of instability and for sufficiently viscoelastic fluid with dilute polymer concentration, the instability is suppressed rendering the flow stable. For concentrated solution and polymer melt, the instability persists, but with higher value of critical shear rate than for the Newtonian fluid, indicating stabilizing role of fluid elasticity in creeping flow regime. However, for high Reynolds number flow of dilute polymer solution, the polymer addition plays a destabilizing role for wall modes, indicated by reduction in critical Reynolds number by an order of magnitude.

  18. Indirect flow-injection spectrophotometric determination of meloxicam, tenoxicam and piroxicam in pharmaceutical formulations.

    Science.gov (United States)

    Al-Momani, Idrees F

    2006-12-01

    A simple and sensitive indirect spectrophotometric method for the assay of meloxicam (MX), tenoxicam (TX) and piroxicam (PX) in pure and in pharmaceutical formulations by flow injection analysis (FIA) has been proposed. The method is based on the oxidation of these drugs by a known excess of N-bromosuccinimide (NBS) in an acidic medium, followed by a reaction of excess oxidant with chloranilic acid (CAA) to bleach its purple color. The absorbance values increased linearly with increasing concentrations of the drugs. Variables, such as the acidity, reagent concentrations, flow rate of reagents and other FI parameters were optimized to produce the most sensitive and reproducible results. The system obeyed Beer's low over concentration ranges of 10 - 160, 20 - 200 and 10 - 160 microg/ml for MX, TX and PX, respectively. The common excipients and additives did not interfere with their determinations. The method was successfully applied to the determinations of MX, TX and PX in various pharmaceutical preparations. The results obtained by the proposed method were found to be in good agreement with those found by the official HPLC methods.

  19. Ultra-sensitive Flow Injection Analysis (FIA) determination of calcium in ice cores at ppt level.

    Science.gov (United States)

    Traversi, R; Becagli, S; Castellano, E; Maggi, V; Morganti, A; Severi, M; Udisti, R

    2007-07-02

    A Flow Injection Analysis (FIA) spectrofluorimetric method for calcium determination in ice cores was optimised in order to achieve better analytical performances which would make it suitable for reliable calcium measurements at ppt level. The method here optimised is based on the formation of a fluorescent compound between Ca and Quin-2 in buffered environment. A careful evaluation of operative parameters (reagent concentration, buffer composition and concentration, pH), influence of interfering species possibly present in real samples and potential favourable effect of surfactant addition was carried out. The obtained detection limit is around 15 ppt, which is one order of magnitude lower than the most sensitive Flow Analysis method for Ca determination currently available in literature and reproducibility is better than 4% for Ca concentrations of 0.2 ppb. The method was validated through measurements performed in parallel with Ion Chromatography on 200 samples from an alpine ice core (Lys Glacier) revealing an excellent fit between the two chemical series. Calcium stratigraphy in Lys ice core was discussed in terms of seasonal pattern and occurrence of Saharan dust events.

  20. Successive determination of urinary bilirubin and creatinine employing simultaneous injection effective mixing flow analysis.

    Science.gov (United States)

    Ponhong, Kraingkrai; Teshima, Norio; Grudpan, Kate; Vichapong, Jitlada; Motomizu, Shoji; Sakai, Tadao

    2015-02-01

    A novel four-channel simultaneous injection effective mixing flow analysis (SIEMA) system has been assembled for successive determination of bilirubin and creatinine in urinary samples. The chemical variables and physical parameters in the flow system were optimized for the enhancement of successive analytical performances. The interferences from urine matrices on the determination of bilirubin and creatinine were eliminated to dilute urine samples. The calibration graphs with the optimum conditions were achieved to be in 0.024-5.0 mg L(-1) for bilirubin and 2-100 mg L(-1) for creatinine. The relative standard deviations (RSDs) at 3 mg L(-1) of bilirubin and at 50 mg L(-1) of creatinine for 11 runs were 1.5 and 1.0%, respectively. The limits of detections (3σ of blank) for bilirubin and creatinine were 7 µg L(-1) and 0.6 mg L(-1), respectively. The sample throughput for stepwise detection was 22 h(-1). The proposed method was applied to the successive determination of bilirubin and creatinine in urine samples.

  1. O-(β-hydroxyethylrutosides determination by micellar flow injection (FI-spectrofluorimetry

    Directory of Open Access Journals (Sweden)

    Cecilia Mariana Peralta

    2014-12-01

    Full Text Available A simple, eco-friendly, sensitive and economic flow injection spectrofluorimetric method was developed for the determination of O-(β-hydroxyethylrutosides. The procedure was based on the use of an anionic surfactant such as sodium dodecyl sulfate to provide an appreciable O-(β-hydroxyethylrutosides fluorescence enhancement, increasing considerably the sensitivity of detection. All the variables affecting the fluorescence intensity were studied and optimized. The flow rate was 5 mL/min with detection at 450 nm (after excitation at 346 nm. A linear correlation between drug amount and peak area was established for O-(β-hydroxyethylrutosides in the range of 0.01–200 µg/mL with a detection limit of 0.001 µg/mL (s/n=3. Validation processes were performed by recovering studies with satisfactory results. The new methodology can be employed for the routine analysis of O-(β-hydroxyethylrutosides in bulks as well as in commercial formulations.

  2. [Research on optimization of mathematical model of flow injection-hydride generation-atomic fluorescence spectrometry].

    Science.gov (United States)

    Cui, Jian; Zhao, Xue-Hong; Wang, Yan; Xiao, Ya-Bing; Jiang, Xue-Hui; Dai, Li

    2014-01-01

    Flow injection-hydride generation-atomic fluorescence spectrometry was a widely used method in the industries of health, environmental, geological and metallurgical fields for the merit of high sensitivity, wide measurement range and fast analytical speed. However, optimization of this method was too difficult as there exist so many parameters affecting the sensitivity and broadening. Generally, the optimal conditions were sought through several experiments. The present paper proposed a mathematical model between the parameters and sensitivity/broadening coefficients using the law of conservation of mass according to the characteristics of hydride chemical reaction and the composition of the system, which was proved to be accurate as comparing the theoretical simulation and experimental results through the test of arsanilic acid standard solution. Finally, this paper has put a relation map between the parameters and sensitivity/broadening coefficients, and summarized that GLS volume, carrier solution flow rate and sample loop volume were the most factors affecting sensitivity and broadening coefficients. Optimizing these three factors with this relation map, the relative sensitivity was advanced by 2.9 times and relative broadening was reduced by 0.76 times. This model can provide a theoretical guidance for the optimization of the experimental conditions.

  3. A Study of Damage on the Pipe Flow Materials Caused by Solid Particle Erosion

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Kyung-Hoon; Choi, Duk-Hyun; Kim, Hyung-Joon [Kyung Hee University, Yongin (Korea, Republic of)

    2014-08-15

    Wall thinning can be classified into three types: flow-accelerated corrosion, cavitation erosion and solid particle erosion. This article presents a study of solid particle erosion, which frequently causes damages to power plants' pipe system. Unlike previous studies, this study uses a mechanism to make solid particles in a fluid flow collide with pipe materials in underwater condition. Experiment is conducted in three cases of velocity according to solid-water ratio using the three types of the materials of A106B, SS400, and A6061. The experiments were performed for 30 days, and the surface morphology and hardness of the materials were examined for every 7 days. Based on the velocity change of the solid particles in a fluid flow, the surface changes, the change in the amount of erosion, the erosion rate and the variation in the hardness of carbon steel and aluminum family pipe materials can all be determined. In addition, factor based erosion rates are verified and a wall-thinning relation function is suggested for the pipe materials.

  4. Hydrodynamic behaviour of a gas—solid counter-current packed column at trickle flow

    NARCIS (Netherlands)

    Roes, A.W.M.; Swaaij, van W.P.M.

    1979-01-01

    Trickle flow of a more or less fluidized catalyst through a packed column is a promising new gas—solid counter-current operation. The hydrodynamic, behaviour of such a column, filled with dumped PALL rings, has been investigated, while some results have been obtained with RASCHIG rings and cylindric

  5. CO2 capture in a continuous gas–solid trickle flow reactor

    NARCIS (Netherlands)

    Veneman, Rens; Hilbers, T.J.; Brilman, Derk Willem Frederik; Kersten, Sascha R.A.

    2016-01-01

    This paper describes the selection, design and experimental validation of a gas–solid trickle flow adsorber for post-combustion CO2 capture using a supported amine sorbents (Lewatit® VP OC 1065). The experimental work presented here summarizes over 300 h of operating experience, which is equivalent

  6. Effects of solid inertial particles on the velocity and temperature statistics of wall bounded turbulent flow

    DEFF Research Database (Denmark)

    Nakhaei, Mohammadhadi; Lessani, B.

    2016-01-01

    The effect of solid inertial particles on the velocity and temperature statistics of a non-isothermal turbulentchannel flow is studied using direct numerical simulation. The particles inertia is varied by changingthe particles diameter. The density of particles is kept constant. A two-way coupled...

  7. Free surface modeling of contacting solid metal flows employing the ALE formulation

    NARCIS (Netherlands)

    Stelt, van der A.A.; Bor, T.C.; Geijselaers, H.J.M.; Akkerman, R.; Huetink, J.; Merklein, M.; Hagenah, H.

    2012-01-01

    In this paper, a numerical problem with contacting solid metal flows is presented and solved with an arbitrary Lagrangian-Eulerian (ALE) finite element method. The problem consists of two domains which mechanically interact with each other. For this simulation a new free surface boundary condition i

  8. Solids removal from a coldwater recirculating system - comparison of swirl separator and radial-flow settlers

    Science.gov (United States)

    Solids removal across two settling devices, i.e., a swirl separator and a radial-flow settler, and across a microscreen drum filter was evaluated in a fully recirculating system containing a single 150 m3 'Cornell-type' dual-drain tank during the production of food-size Arctic char and rainbow trout...

  9. IMPROVED SUBGRID SCALE MODEL FOR DENSE TURBULENT SOLID-LIQUID TWO-PHASE FLOWS

    Institute of Scientific and Technical Information of China (English)

    TANG Xuelin; QIAN Zhongdong; WU Yulin

    2004-01-01

    The dense solid-phase governing equations for two-phase flows are obtained by using the kinetic theory of gas molecules. Assuming that the solid-phase velocity distributions obey the Maxwell equations, the collision term for particles under dense two-phase flow conditions is also derived.In comparison with the governing equations of a dilute two-phase flow, the solid-particle's governing equations are developed for a dense turbulent solid-liquid flow by adopting some relevant terms from the dilute two-phase governing equations. Based on Cauchy-Helmholtz theorem and Smagorinsky model,a second-order dynamic sub-grid-scale (SGS) model, in which the sub-grid-scale stress is a function of both the strain-rate tensor and the rotation-rate tensor, is proposed to model the two-phase governing equations by applying dimension analyses. Applying the SIMPLEC algorithm and staggering grid system to the two-phase discretized governing equations and employing the slip boundary conditions on the walls, the velocity and pressure fields, and the volumetric concentration are calculated. The simulation results are in a fairly good agreement with experimental data in two operating cases in a conduit with a rectangular cross-section and these comparisons imply that these models are practical.

  10. Modulation on flow field by solid particles in gas-solid two-phase turbulent free shear flows

    Institute of Scientific and Technical Information of China (English)

    2003-01-01

    In order to understand the interaction between fluid and particles, a two-way coupled three-dimensional mixing layer laden with particles at a Stokes number of 5 with different mass loadings is numerically studied. The pseudospectral method is used for the flow fluid and the Lagrangian approach is used to trace particles. The concept of computational particles is introduced to vary the mass loading of particles. The momentum coupling effect introduced by a particle is approximated to the point force. The simulation results show that the coherent structures are still dominant in the mixing layer, but the flow field is modulated by particles. The addition of the particles enhances the energy of all the Fourier modes with non-zero spanwise wavenumber, and the enhancement increases with the augment of the mass loading. A higher mass loading results in a lower energy at fundamental wavenumber and streamwise subharmonic Fourier mode of the fluid in the phase of Kelvin-Helmholtz rolling up, but for large-scale vortex structures pairing, the energy of the fluid increases as the mass loading increases. Similar trends can also be found in the developments of the turbulent kinetic energy and the momentum thickness.

  11. A framework for coupling flow and deformation of the porous solid

    CERN Document Server

    Turner, D Z; Martinez, M J

    2013-01-01

    In this paper, we consider the flow of an incompressible fluid in a deformable porous solid. We present a mathematical model using the framework offered by the theory of interacting continua. In its most general form, this framework provides a mechanism for capturing multiphase flow, deformation, chemical reactions and thermal processes, as well as interactions between the various physics in a conveniently implemented fashion. To simplify the presentation of the framework, results are presented for a particular model than can be seen as an extension of Darcy's equation (which assumes that the porous solid is rigid) that takes into account elastic deformation of the porous solid. The model also considers the effect of deformation on porosity. We show that using this model one can recover identical results as in the framework proposed by Biot and Terzaghi. Some salient features of the framework are as follows: (a) It is a consistent mixture theory model, and adheres to the laws and principles of continuum therm...

  12. Solid state generator for powerful radio frequency ion sources in neutral beam injection systems

    Energy Technology Data Exchange (ETDEWEB)

    Kraus, W.; Fantz, U.; Heinemann, B.; Franzen, P.

    2015-02-15

    Radio frequency ion sources used in neutral beam injection systems (NBI) of fusion machines are currently supplied by self-excited RF generators. These generators have both a low power efficiency and a limited frequency stability, therefore transistorized amplifiers are being considered for the power supply of the next generation of RF sources. A 75 kW generator, originally designed for broadcasting, has been tested with a negative ion source. High operational reliability and a very good matching to the plasma load has been demonstrated. These results make this generator type a very promising candidate for future NBI systems.

  13. Numerical Simulation of Gas-Liquid-Solid Three-Phase Flow in Deep Wells

    Directory of Open Access Journals (Sweden)

    Jianyu Xie

    2013-01-01

    Full Text Available A gas-liquid-solid flow model which considers the effect of the cuttings on the pressure drop is established for the annulus flow in the deep wells in this paper, based on which a numerical code is developed to calculate the thermal and flow quantities such as temperature and pressure distributions. The model is validated by field data, and its performance is compared with several commercial software. The effects of some important parameters, such as well depth, gas kick, cuttings, and drilling fluid properties, on the temperature and pressure distributions are studied.

  14. Determination of Free and Total Sulfites in Wine using an Automatic Flow Injection Analysis System with Voltammetric Detection

    OpenAIRE

    Gonçalves, Luís Moreira; Pacheco, João Grosso; Magalhães, Paulo Jorge; Rodrigues, José António; Barros, Aquiles Araújo

    2009-01-01

    Abstract An automated Flow Injection Analysis (FIA) system based on a initial analyte separation by gas-diffusion and subsequent determination by square-wave voltammetry (SWV) in a flow cell is proposed for the determination of total and free content of sulphur dioxide (SO2) in wine. The proposed method was compared with two iodometric methodologies (the Ripper method and the simplified method commonly used by the wine industry). The developed method shown repeatability (RSD lower ...

  15. Numerical evaluation of turbulence models for dense to dilute gas-solid flows in vertical conveyor

    Institute of Scientific and Technical Information of China (English)

    Salar Azizi; Dariush Mowla; Goodarz Ahmadi

    2012-01-01

    A two-fluid model (TFM) of multiphase flows based on the kinetic theory and small frictional limit boundary condition of granular flow was used to study the behavior of dense to dilute gas-solid flows in vertical pneumatic conveyor.An axisymmetric 2-dimensional,vertical pipe with 5.6 m length and 0.01 m internal diameter was chosen as the computation domain,same to that used for experimentation in the literature.The chosen particles are spherical,of diameter 1.91 mm and density 2500 kg/m3.Turbulence interaction between the gas and particle phases was investigated by Simonin's and Ahmadi's models and their numerical results were validated for dilute to dense conveying of particles.Flow regimes transition and pressure drop were predicted.Voidage and velocity profiles of each phase were calculated in radial direction at different lengths of the conveying pipe.It was found that the voidage has a minimum,and gas and solid velocities have maximum values along the center line of the conveying pipe and pressure drop has a minimum value in transition from dense slugging to dilute stable flow regime.Slug length and pressure fluctuation reduction were predicted with increasing gas velocity,too.It is shown that solid phase turbulence plays a significant role in numerical prediction of hydrodynamics of conveyor and the capability of particles turbulence models depends on tuning parameters of slip-wall boundary condition.

  16. Combustion characteristics and turbulence modeling of swirling reacting flow in solid fuel ramjet

    Science.gov (United States)

    Musa, Omer; Xiong, Chen; Changsheng, Zhou

    2017-10-01

    This paper reviews the historical studies have been done on the solid-fuel ramjet engine and difficulties associated with numerical modeling of swirling flow with combustible gases. A literature survey about works related to numerical and experimental investigations on solid-fuel ramjet as well as using swirling flow and different numerical approaches has been provided. An overview of turbulence modeling of swirling flow and the behavior of turbulence at streamline curvature and system rotation are presented. A new and simple curvature/correction factor is proposed in order to reduce the programming complexity of SST-CC turbulence model. Finally, numerical and experimental investigations on the impact of swirling flow on SFRJ have been carried out. For that regard, a multi-physics coupling code is developed to solve the problems of multi-physics coupling of fluid mechanics, solid pyrolysis, heat transfer, thermodynamics, and chemical kinetics. The connected-pipe test facility is used to carry out the experiments. The results showed a positive impact of swirling flow on SFRJ along with, three correlations are proposed.

  17. Very-high-flow injection rate for upper abdominal CT angiography

    Energy Technology Data Exchange (ETDEWEB)

    Kimura, Masashi; Minamiguti, Hiroki; Hagihira, Takami; Kishi, Kazushi; Sato, Morio [Wakayama Medical Coll. (Japan); Shioyama, Yasukazu; Okumura, Toshiyuki; Yamada, Kouji; Kawashima, Michihisa [Central Hospital and Cancer Center of Ibaraki Prefecture, Tomobe (Japan)

    2002-06-01

    The purpose of this study was to compare a very-high-flow injection-rate method (group A) and a conventional injection-rate method (group B) for visualization of upper abdominal arteries by multidetector helical computed tomography (MDHCT). The subjects were 240 patients suspected to have abdominal lesions. They were randomly assigned to group A (120 patients) and group B (120 patients). In group A, the bilateral medial cubital veins were punctured, and contrast medium was infused at a rate of 8.6-9.6 ml/s. In group B, the unilateral medial cubital vein was punctured, and contrast medium was infused at a rate of 2.0-3.0 ml/s. The quality of vascular visualization was graded as poor, good, or excellent by three radiologists. All visualizations of the celiac trunk (CE) and superior mesenteric artery (SMA) were graded as excellent in both group A and group B. Visualization grades of the subsegmental branches of the hepatic artery (HA), right gastric artery (RGA), cystic artery, dorsal pancreatic artery (DPA), and superior pancreaticoduodenal artery (SPDA) were good or excellent in 75% (paging method)/53.3% (three-dimensional method), 85%/30%, 77.7%/18.3%, 76.7%/28.3%, and 88.3%/42.5%, respectively, in group A, and 33.3%/11.7%, 46.7%/3.4%, 41.6%/5%, 55%/4.2%, and 72.5%/14.2%, respectively, in group B. The appearance rate of intrahepatic portal branches was 28.3% in group A and 66.7% in group B in the arterial dominant phase. Group A showed better visualization results than Group B in upper abdominal arteries according to MDHCT. (author)

  18. Spectrophotometric detection of arsenic using flow-injection hydride generation following sorbent extraction preconcentration.

    Science.gov (United States)

    Neto, J A; Montes, R; Cardoso, A A

    1999-12-06

    An automated system with a C(18) bonded silica gel packed minicolumn is proposed for spectrophotometric detection of arsenic using flow-injection hydride generation following sorbent extraction preconcentration. Complexes formed between arsenic(III) and ammonium diethyl dithiophosphate (ADDP) are retained on a C(18) sorbent. The eluted As-DDP complexes are merged with a 1.5% (w/v) NaBH(4) and the resulting solution is thereafter injected into the hydride generator/gas-liquid separator. The arsine generated is carried out by a stream of N(2) and trapped in an alkaline iodine solution in which the analyte is determined by the arsenomolybdenum blue method. With preconcentration time of 120 s, calibration in the 5.00-50.0 mug As l(-1) range and sampling rate of about 20 samples h(-1) are achieved, corresponding to 36 mg ADDP plus 36 mg ammonium heptamolybdate plus 7 mg hydrazine sulfate plus 0.7 mg stannous chloride and about 7 ml sample consumed per determination. The detection limit is 0.06 mug l(-1) and the relative standard deviation (n=12) for a typical 17.0 mug As l(-1) sample is ca. 6%. The accuracy was checked for arsenic determination in plant materials from the NIST (1572 citrus leaves; 1573 tomato leaves) and the results were in agreement with the certified values at 95% confidence level. Good recoveries (94-104%) of spiked tap waters, sugars and synthetic mixtures of trivalent and pentavalent arsenic were also found.

  19. Numerical Simulation of 3D Solid-Liquid Turbulent Flow in a Low Specific Speed Centrifugal Pump: Flow Field Analysis

    Directory of Open Access Journals (Sweden)

    Baocheng Shi

    2014-06-01

    Full Text Available For numerically simulating 3D solid-liquid turbulent flow in low specific speed centrifugal pumps, the iteration convergence problem caused by complex internal structure and high rotational speed of pump is always a problem for numeral simulation researchers. To solve this problem, the combination of three measures of dynamic underrelaxation factor adjustment, step method, and rotational velocity control means according to residual curves trends of operating parameters was used to improve the numerical convergence. Numeral simulation of 3D turbulent flow in a low specific speed solid-liquid centrifugal pump was performed, and the results showed that the improved solution strategy is greatly helpful to the numerical convergence. Moreover, the 3D turbulent flow fields in pumps have been simulated for the bottom ash-particles with the volume fraction of 10%, 20%, and 30% at the same particle diameter of 0.1 mm. The two-phase calculation results are compared with those of single-phase clean water flow. The calculated results gave the main region of the abrasion of the impeller and volute casing and improve the hydraulic design of the impeller in order to decrease the abrasion and increase the service life of the pump.

  20. Critical Regimes of Two-Phase Flows with a Polydisperse Solid Phase

    CERN Document Server

    Barsky, Eugene

    2010-01-01

    This book brings to light peculiarities of the formation of critical regimes of two-phase flows with a polydisperse solid phase. A definition of entropy is formulated on the basis of statistical analysis of these peculiarities. The physical meaning of entropy and its correlation with other parameters determining two-phase flows are clearly defined. The interrelations and main differences between this entropy and the thermodynamic one are revealed. The main regularities of two-phase flows both in critical and in other regimes are established using the notion of entropy. This parameter serves as a basis for a deeper insight into the physics of the process and for the development of exhaustive techniques of mass exchange estimation in such flows. The book is intended for graduate and postgraduate students of engineering studying two-phase flows, and to scientists and engineers engaged in specific problems of such fields as chemical technology, mineral dressing, modern ceramics, microelectronics, pharmacology, po...

  1. Succeed escape: Flow shear promotes tumbling of Escherichia colinear a solid surface

    Science.gov (United States)

    Molaei, Mehdi; Sheng, Jian

    2016-10-01

    Understanding how bacteria move close to a surface under various stimuli is crucial for a broad range of microbial processes including biofilm formation, bacterial transport and migration. While prior studies focus on interactions between single stimulus and bacterial suspension, we emphasize on compounding effects of flow shear and solid surfaces on bacterial motility, especially reorientation and tumble. We have applied microfluidics and digital holographic microscopy to capture a large number (>105) of 3D Escherichia coli trajectories near a surface under various flow shear. We find that near-surface flow shear promotes cell reorientation and mitigates the tumble suppression and re-orientation confinement found in a quiescent flow, and consequently enhances surface normal bacterial dispersion. Conditional sampling suggests that two complimentary hydrodynamic mechanisms, Jeffrey Orbit and shear-induced flagella unbundling, are responsible for the enhancement in bacterial tumble motility. These findings imply that flow shear may mitigate cell trapping and prevent biofilm initiation.

  2. Numerical Simulation of a Dual Pulse Solid Rocket Motor Flow Field

    Directory of Open Access Journals (Sweden)

    Afroz Javed

    2012-11-01

    Full Text Available Numerical simulations are carried out for the internal flow field of a dual pulse solid rocket motor port to understand the flow behaviour. Three dimensional Reynolds Averaged Navier Stokes equations are solved alongwith shear stress transport turbulence model using commercial code. The combustion gas is assumed as a mixture of alumina and gases and single phase flow calculations are done with the thermo chemical properties provided for the mixture. The simulation captures all the essential features of the flow field. The flow accelerates through the pulse separation device (PSD port and high temperature and high velocity gas is seen to impinge the motor wall near the PSD port. The overall total pressure drop through motor port and through PSD is found to be moderate.Defence Science Journal, 2012, 62(6, pp.369-374, DOI:http://dx.doi.org/10.14429/dsj.62.1418

  3. A multisyringe flow injection method for the automated determination of sulfide in waters using a miniaturised optical fiber spectrophotometer.

    Science.gov (United States)

    Ferrer, Laura; de Armas, Graciela; Miró, Manuel; Estela, José Manuel; Cerdà, Víctor

    2004-12-15

    In this paper, a fully software-controlled multisyringe flow injection (MSFIA) spectrophotometric system is proposed for the determination of sulfide in environmental and waste waters. The implementation of ancillary solenoid valves into the flow network allows a multitude of injection modalities to be explored, the selected modality being directly dependent on the aim of the assays. The multicommuted sandwich-type approach is introduced in this work as an efficient means to warrant high sensitivity for the particular assay with excellent repeatabilities and a considerable reagent saving. Moreover, a high injection frequency may be easily attained by carrying out a multiple injection modality during a single forward displacement of the piston driver bar. The interfacing of the robust and versatile multisyringe piston pump with an optical fiber plug-in spectrophotometer furnished with a light emitting diode enables the miniaturization of the flow analyzer, which is thus readily adaptable to in-situ and real-time monitoring schemes. The flow method is based on the coupling Fischer's reaction of sulfide with N,N-dimethyl-p-phenylenediamine in the presence of Fe(III) as oxidizing reagent in a 0.7M HCl medium. Careful selection of the physical and chemical variables enabled coefficients of variations better than 1.5% (n = 10) at the 1mgl(-1) level for both injection modalities. Dynamic working ranges of 0.2-2.0 and 0.5-5mgl(-1) sulfide for sandwich and multiple injection techniques, and detection limits of 0.09 and 0.15mgl(-1), respectively, were obtained. Furthermore, the sandwich modality featured an average slope of 0.43 +/- 0.02lmg(-1) calculated from 10 day-to-day calibration plots. This result reveals better sensitivity than other flowing stream methods described in the literature. The multiple injection technique allowed an improvement of the injection throughput up to 80h(-1), although a decrease of sensitivity was concomitantly observed (average slope of 0

  4. Numerical Solution for the Effect of Suction or Injection on Flow of Nanofluids Past a Stretching Sheet

    Science.gov (United States)

    Abd Elazem, Nader Y.

    2016-06-01

    The flow of nanofluids past a stretching sheet has attracted much attention owing to its wide applications in industry and engineering. Numerical solution has been discussed in this article for studying the effect of suction (or injection) on flow of nanofluids past a stretching sheet. The numerical results carried out using Chebyshev collocation method (ChCM). Useful results for temperature profile, concentration profile, reduced Nusselt number, and reduced Sherwood number are discussed in tabular and graphical forms. It was also demonstrated that both temperature and concentration profiles decrease by an increase from injection to suction. Moreover, the numerical results show that the temperature profiles decrease at high values of Prandtl number Pr. Finally, the present results showed that the reduced Nusselt number is a decreasing function, whereas the reduced Sherwood number is an increasing function at fixed values of Prandtl number Pr, Lewis number Le and suction (or injection) parameter s for variation of Brownian motion parameter Nb, and thermophoresis parameter Nt.

  5. Thrust vectoring effects of a transverse gas injection into a supersonic cross flow of an axisymmetric convergent-divergent nozzle

    Science.gov (United States)

    Zmijanovic, V.; Lago, V.; Leger, L.; Depussay, E.; Sellam, M.; Chpoun, A.

    2013-03-01

    The transverse gas injection into the main supersonic flow of an axisymmetric convergent-divergent (C-D) propulsive nozzle is investigated for the fluidic thrust vectoring (FTV) possibilities as the segment part of the CNES "Perseus" project. Truncated ideal contour and conical C-D nozzles with different position and angle of the secondary circular injection port are selected as test models in the current numerical and experimental study. Analytical approach revealed parameters which affect the FTV efficiency, these criterions are further numerically explored and results data of the conical nozzle test cases are compared and coupled with the ones from experiments. It is found that upstream inclined injection has positive effect on vectoring capabilities and that with moderate secondary to primary mass-flow ratios, ranging around 5%, pertinent vector side force is possible to be achieved.

  6. Introduction of Hydrogen Peroxide as an Oxidant in Flow Injection Analysis: Speciation of Cr(III) and Cr(VI)

    DEFF Research Database (Denmark)

    Andersen, Jens Enevold Thaulov

    1998-01-01

    Hydrogen peroxide was used as an oxidant in Flow Injection Analysis (FIA). The formation of gaseous components during the analysis was suppressed by maintaining a concentration lower than 0.15% of hydrogen peroxide in 0.1 M NaOH. By this method Cr(III) was oxidised on-line to Cr(VI) which...

  7. Comparison of Flow Injection MS, NMR, and DNA Sequencing: Methods for Identification and Authentication of Black Cohosh (Actaea racemosa)

    Science.gov (United States)

    Flow injection mass spectrometry (FIMS) and proton nuclear magnetic resonance spectrometry (1H-NMR), two metabolic fingerprinting methods, and DNA sequencing were used to identify and authenticate Actaea species. Initially, samples of Actaea racemosa L. from a single source were distinguished from ...

  8. Rapid detection of pesticides not amenable to multi-residue methods by flow injection-tandem mass spectrometry

    NARCIS (Netherlands)

    Mol, J.G.J.; Dam, van R.C.J.

    2014-01-01

    Flow injection combined with tandem mass spectrometry (MS/MS) was investigated for the rapid detection of highly polar pesticides that are not amenable to multi-residue methods because they do not partition into organic solvents and require dedicated chromatographic conditions. The pesticides includ

  9. The influence of fuel injection and heat release on bulk flow structures in a direct-injection, swirl-supported diesel engine

    Science.gov (United States)

    Sterl, Andreas; van Oldenborgh, Geert Jan; Hazeleger, Wilco; Burgers, Gerrit

    2007-08-01

    Particle image velocimetry is applied to measure the vertical (r z) plane flow structures in a light-duty direct-injection diesel engine with a realistic piston geometry. The measurements are corrected for optical distortions due to the curved piston bowl walls and the cylindrical liner. Mean flow fields are presented and contrasted for operation both with and without fuel injection and combustion. For operation with combustion, the two-dimensional divergence of the measured mean velocity fields is employed as a qualitative indicator of the locations of mean heat release. In agreement with numerical simulations, dual-vortex, vertical plane mean flow structures that may enhance mixing rates are formed approximately mid-way through the combustion event. Late in the cycle a toroidal vortex forms outside the bowl mouth. Imaging studies suggest that soot and partially oxidized fuel trapped within this vortex are slow to mix with surrounding fluid; moreover, the vortex impedes mixing of fluid exiting the bowl with air within the squish volume.

  10. Numerical study of cavitation and pinning effects due to gas injection through a bed of particles: application to a radial-flow moving-bed reactor

    Science.gov (United States)

    Vinay, Guillaume; Vasquez, Felaurys; Richard, Florence; Applied Mechanics Team

    2016-11-01

    In the petroleum and chemical industries, radial-flow moving-bed reactors are used to carry out chemical reactions such as catalytic reforming. Radial-flow reactors provide high capacity without increased pressure drop or greatly increased vessel dimensions. This is done by holding the catalyst in a basket forming an annular bed, and causing the gas to flow radially between the outer annulus and the central tube. Catalyst enter the top of the reactor, move through the vessel by gravity to the bottom where it is removed and then regenerated. Within the catalytic bed, the combined effects of particles motion and radial injection of the gas may lead to cavitation and pinning phenomenon that may clearly damage the reactor. We study both cavitation and pinning effects using an in-house numerical software, named PeliGRIFF (www.peligriff.com/), designed to simulate particulate flows at different scales; from the particle scale, where fluid/particle interactions are directly solved, to the particles suspension scale where the fluid/solid interactions are modeled. In the past, theoretical and experimental studies have already been conducted in order to understand the way cavitation and pinning occur. Here, we performed simulations involving a few thousands of particles aiming at reproducing experimental experiments. We will present comparisons between our numerical results and experimental results in terms of pressure drop, velocity, porosity.

  11. Numerical Simulation of Combustion and Extinction of a Solid Cylinder in Low-Speed Cross Flow

    Science.gov (United States)

    Tien, J. S.; Yang, Chin Tien

    1998-01-01

    The combustion and extinction behavior of a diffusion flame around a solid fuel cylinder (PMMA) in low-speed forced flow in zero gravity was studied numerically using a quasi-steady gas phase model. This model includes two-dimensional continuity, full Navier Stokes' momentum, energy, and species equations with a one-step overall chemical reaction and second-order finite-rate Arrhenius kinetics. Surface radiation and Arrhenius pyrolysis kinetics are included on the solid fuel surface description and a parameter Phi, representing the percentage of gas-phase conductive heat flux going into the solid, is introduced into the interfacial energy balance boundary condition to complete the description for the quasi-steady gas-phase system. The model was solved numerically using a body-fitted coordinate transformation and the SIMPLE algorithm. The effects of varying freestream velocity and Phi were studied. These parameters have a significant effect on the flame structure and extinction limits. Two flame modes were identified: envelope flame and wake flame. Two kinds of flammability limits were found: quenching at low-flow speeds due to radiative loss and blow-off at high flow speeds due to insufficient gas residence time. A flammability map was constructed showing the existence of maximum Phi above which the solid is not flammable at any freestream velocity.

  12. Gas suspension flows of a moderately dense binary mixture of solid particles in vertical tubes

    Energy Technology Data Exchange (ETDEWEB)

    Zamankhan, P.; Huotari, J. [VTT Energy, Jyvaeskylae (Finland). Combustion and Conversion Lab.

    1996-12-01

    The turbulent, steady, fully-developed flow of a moderately dense (solid volume faction >>0.001) binary mixture of spherical particles in a gaseous carrier is investigated for the case of flow in a vertical riser. The suspended particles are considered to be in turbulent motion, driven by random aerodynamic forces acting between the particle and the gaseous carrier as well as particle-particle interactive forces. A model is constructed based on the combination of the time-averaged after volume-averaged conservation equations of mass, momentum and mechanical energy of the gas phase in the continuum theory and the corresponding equations for the solid particles obtained using the recently developed Enskog theory for dense multi-component mixtures of slightly inelastic spherical particles. The model properly takes into account the contributions of particle-particle collisions, as well as the fluid-dynamic fluctuating forces on individual particles. To demonstrate the validity of this approach, the fully-developed steady-state mean velocity and concentration distributions of a moderately dense binary mixture of solid particles in a turbulent vertical flow calculated by the present model are compared with available experimental measurements. The results provide a qualitative description of the experimentally observed motion of coarse particles in a fast bed of fine solids. (author)

  13. High-resolution quantitative metabolome analysis of urine by automated flow injection NMR.

    Science.gov (United States)

    Da Silva, Laeticia; Godejohann, Markus; Martin, François-Pierre J; Collino, Sebastiano; Bürkle, Alexander; Moreno-Villanueva, María; Bernhardt, Jürgen; Toussaint, Olivier; Grubeck-Loebenstein, Beatrix; Gonos, Efstathios S; Sikora, Ewa; Grune, Tilman; Breusing, Nicolle; Franceschi, Claudio; Hervonen, Antti; Spraul, Manfred; Moco, Sofia

    2013-06-18

    Metabolism is essential to understand human health. To characterize human metabolism, a high-resolution read-out of the metabolic status under various physiological conditions, either in health or disease, is needed. Metabolomics offers an unprecedented approach for generating system-specific biochemical definitions of a human phenotype through the capture of a variety of metabolites in a single measurement. The emergence of large cohorts in clinical studies increases the demand of technologies able to analyze a large number of measurements, in an automated fashion, in the most robust way. NMR is an established metabolomics tool for obtaining metabolic phenotypes. Here, we describe the analysis of NMR-based urinary profiles for metabolic studies, challenged to a large human study (3007 samples). This method includes the acquisition of nuclear Overhauser effect spectroscopy one-dimensional and J-resolved two-dimensional (J-Res-2D) (1)H NMR spectra obtained on a 600 MHz spectrometer, equipped with a 120 μL flow probe, coupled to a flow-injection analysis system, in full automation under the control of a sampler manager. Samples were acquired at a throughput of ~20 (or 40 when J-Res-2D is included) min/sample. The associated technical analysis error over the full series of analysis is 12%, which demonstrates the robustness of the method. With the aim to describe an overall metabolomics workflow, the quantification of 36 metabolites, mainly related to central carbon metabolism and gut microbial host cometabolism, was obtained, as well as multivariate data analysis of the full spectral profiles. The metabolic read-outs generated using our analytical workflow can therefore be considered for further pathway modeling and/or biological interpretation.

  14. Pharmacokinetic of pseudoephedrine in rat serum with luminol-pepsin chemiluminescence system by flow injection analysis.

    Science.gov (United States)

    Luo, Kai; Li, Yajuan; Zheng, Xiaohui; Song, Zhenghua

    2015-02-01

    Pepsin (Pep) accelerated the electron transferring rate of excited 3-aminophathlate and enhanced luminol-dissolved oxygen chemiluminescence (CL) intensity, and the flow injection (FI) luminol-Pep CL system was first developed. It was found that the CL intensity of luminol-Pep reaction could be remarkably inhibited by pseudoephedrine (PE); the decrement of CL intensity was linear to the logarithm of PE concentration in the range of 0.1∼100.0 nmol L(-1) with a detection limit of 0.03 nmol mL(-1) (3σ). At a flow rate of 2.0 mL min(-1), the complete process including washing and sampling was performed within 40 s, offering a sample throughput of 90 h(-1). This proposed method was successfully applied to determining PE in rat serum for 18 h after intragastric administration with the elimination ratio of 42.34 % and recoveries from 90.3 to 110.6 %. The pharmacokinetic results showed that PE could be rapidly absorbed into serum with peak concentration (C max) of 1.45 ± 0.18 g L(-1) at the time (T max) of 1.49 ± 0.02 h; the absorption half-life (0.35 ± 0.04 h), elimination half-life (1.86 ± 0.24 h), the area under curve (109.81 ± 6.03 mg L(-1) h(-1)), mean residence time (3.82 ± 0.27 h), and elimination rate constant (2.26 ± 0.23 L g(-1) h(-1)) in rats vivo were derived, respectively. The possible CL mechanism of luminol-Pep-PE reaction was discussed by FI-CL, fluorescence, and molecular docking (MD) methods.

  15. Flow structures in a lean-premixed swirl-stabilized combustor with microjet air injection

    KAUST Repository

    LaBry, Zachary A.

    2011-01-01

    The major challenge facing the development of low-emission combustors is combustion instability. By lowering flame temperatures, lean-premixed combustion has the potential to nearly eliminate emissions of thermally generated nitric oxides, but the chamber acoustics and heat release rate are highly susceptible to coupling in ways that lead to sustained, high-amplitude pressure oscillations, known as combustion instability. At different operating conditions, different modes of instability are observed, corresponding to particular flame shapes and resonant acoustic modes. Here we show that in a swirl-stabilized combustor, these instability modes also correspond to particular interactions between the flame and the inner recirculation zone. Two stable and two unstable modes are examined. At lean equivalence ratios, a stable conical flame anchors on the upstream edge of the inner recirculation zone and extends several diameters downstream along the wall. At higher equivalence ratios, with the injection of counter-swirling microjet air flow, another stable flame is observed. This flame is anchored along the upstream edge of a stronger recirculation zone, extending less than one diameter downstream along the wall. Without the microjets, a stationary instability coupled to the 1/4 wave mode of the combustor shows weak velocity oscillations and a stable configuration of the inner and outer recirculation zones. Another instability, coupled to the 3/4 wave mode of the combustor, exhibits periodic vortex breakdown in which the core flow alternates between a columnar mode and a vortex breakdown mode. © 2010 Published by Elsevier Inc. on behalf of The Combustion Institute. All rights reserved.

  16. Local Heat and Mass Transfer for Gas—Solid Two Phase Flow in CFB

    Institute of Scientific and Technical Information of China (English)

    FengLu; Ming-HengShi

    1994-01-01

    An experimental investigation on the flow characteristics and the local heat and mass transfer between coarse wet particles and hot gas in the circulaing fluidized bed(CFB) has been performed.A twothermocouple contrast method was developed to measure the local gas and solid temperature along the height of the bed.The influences of air superficial velocity,solid rate and initial moisture content on the local heat and mass transfer between gas and sloid were examined.The correlations of heat and mass transfer coefficients between gas and coarse wet particles in CFB were obtained.

  17. Nonaffine deformation under compression and decompression of a flow-stabilized solid

    Science.gov (United States)

    Ortiz, Carlos P.; Riehn, Robert; Daniels, Karen E.

    2016-08-01

    Understanding the particle-scale transition from elastic deformation to plastic flow is central to making predictions about the bulk material properties and response of disordered materials. To address this issue, we perform experiments on flow-stabilized solids composed of micron-scale spheres within a microfluidic channel, in a regime where particle inertia is negligible. Each solid heap exists within a stress field imposed by the flow, and we track the positions of particles in response to single impulses of fluid-driven compression or decompression. We find that the resulting deformation field is well-decomposed into an affine field, with a constant strain profile throughout the solid, and a non-affine field. The magnitude of this non-affine response decays with the distance from the free surface in the long-time limit, suggesting that the distance from jamming plays a significant role in controlling the length scale of plastic flow. Finally, we observe that compressive pulses create more rearrangements than decompressive pulses, an effect that we quantify using the D\\text{min}2 statistic for non-affine motion. Unexpectedly, the time scale for the compression response is shorter than for decompression at the same strain (but unequal pressure), providing insight into the coupling between deformation and cage-breaking.

  18. Method for (236)U Determination in Seawater Using Flow Injection Extraction Chromatography and Accelerator Mass Spectrometry.

    Science.gov (United States)

    Qiao, Jixin; Hou, Xiaolin; Steier, Peter; Nielsen, Sven; Golser, Robin

    2015-07-21

    An automated analytical method implemented in a flow injection (FI) system was developed for rapid determination of (236)U in 10 L seawater samples. (238)U was used as a chemical yield tracer for the whole procedure, in which extraction chromatography (UTEVA) was exploited to purify uranium, after an effective iron hydroxide coprecipitation. Accelerator mass spectrometry (AMS) was applied for quantifying the (236)U/(238)U ratio, and inductively coupled plasma mass spectrometry (ICPMS) was used to determine the absolute concentration of (238)U; thus, the concentration of (236)U can be calculated. The key experimental parameters affecting the analytical effectiveness were investigated and optimized in order to achieve high chemical yields and simple and rapid analysis as well as low procedure background. Besides, the operational conditions for the target preparation prior to the AMS measurement were optimized, on the basis of studying the coprecipitation behavior of uranium with iron hydroxide. The analytical results indicate that the developed method is simple and robust, providing satisfactory chemical yields (80-100%) and high analysis speed (4 h/sample), which could be an appealing alternative to conventional manual methods for (236)U determination in its tracer application.

  19. Determination of iodide using flow injection with acidic potassium permanganate chemiluminescence detection.

    Science.gov (United States)

    Yaqoob, Mohammad; Atiq-ur-Rehman; Waseem, Amir; Nabi, Abdul

    2006-01-01

    A simple and rapid flow-injection method is described for the determination of iodide, based on potassium permanganate chemiluminescence detection via oxidation of formaldehyde in aqueous hydrochloric acid. The calibration graph was linear over the range 1.0-12 x 10(-6) mol/L (r2 = 0.9955) with relative standard deviations (n = 4) in the range 1.0-3.5%. The detection limit (3sigma) was 1.0 x 10(-7) mol/L, with sample throughput of 120/h. The effect of interfering cations [Ca(II), Mg(II), Ni(II), Fe(II), Fe(III) and Pb(II)] and anions (Cl-, SO4(2-), PO4(3-), NO3-, NO2-, F- and SO3(2-)) were studied. The method was applied to iodized salt samples and the results obtained in the range 0.03 +/- 0.005 - 0.10 +/- 0.006 mg I/g were in reasonable agreement with the amount labelled. The method was statistically compared with the results obtained by titration; no significant disagreement at 95% confidence was observed.

  20. A spectrophotometric flow injection system for streptomycin determination in veterinary samples

    Science.gov (United States)

    Frugeri, Pedro Marcos; Lago, Ayla Campos do; Wisniewski, Célio; Luccas, Pedro Orival

    2014-01-01

    In this work a spectrophotometric flow injection analysis system for streptomycin determination in veterinary samples, is being proposed. The method is based on streptomycin alkaline hydrolysis that forms guanidine, followed by the reaction with Fe(II). The colored product has absorption peak at 520 nm. To evaluate and optimize the system parameters, chemometrics tools, such as factorial design, Pareto chart and Doelhert design, were used. The veterinary samples are diluted in water and introduced in the FIA system, therefore no sample preparation is required. The optimized system presented: linear range of 60 up to 1000 mg L-1, limit of detection of 18 mg L-1 and sampling rate of 36 readings per hour. The precision was checked and the CV for veterinary sample readings were always less than 6.5%. The accuracy was studied by comparison with chromatographic method, thus, five samples of pharmaceutical veterinary were determined by HPLC and by the proposed method, and the results are in agreement (t-test, p = 0.05).

  1. Spectrophotometric determination of phosphorus in iron alloys employing a flow injection system

    Directory of Open Access Journals (Sweden)

    Gervasio Ana P. G.

    2001-01-01

    Full Text Available A flow-injection procedure for spectrophotometric determination of phosphorus in electrolytic iron and iron alloys is proposed. The method is based on the ammonium molybdate reaction followed by stannous chloride reduction in acidic medium. In order to circumvent the severe interference caused by the major constituents such as Fe(III and Cr(III, a mini-column packed with AG50W-X8 resin was coupled to the manifold. A sample throughput of 40 determinations per hour, a dynamical range from P 0.25 to 6.00 mg L-1, a reagent consumption of 25 mg ammonium molybdate and 2 mg stannous chloride per determination, and a relative standard deviation < 1% (n = 10 for a typical sample with 2.20 mg L-1 P were achieved. Three different types of samples were used to evaluate system performance. Accuracy was assessed by comparing the results with certified values and no significant difference at 95 % confidence level was observed.

  2. The Two-Dimensional Supersonic Flow and Mixing with a Perpendicular Injection in a Scramjet Combustor

    Institute of Scientific and Technical Information of China (English)

    Mohammad Ali; S.Ahmed; A.K.M.Sadrul Islam

    2003-01-01

    A numerical investigation has been performed on supersonic mixing of hydrogen with air in a Scramjet(Supersonic Combustion Ramjet) combustor and its flame holding capability by solving Two-Dimensional full Navier-Stokes equations. The main flow is air entering through a finite width of inlet and gaseous hydrogen is injected perpendicularly from the side wall. An explicit Harten-Yee Non-MUSCL Modified-flux-type TVD scheme has been used to solve the system of equations, and a zero-equation algebraic turbulence model to calculate the eddy viscosity coefficient. In this study the enhancement of mixing and good flame holding capability of a supersonic combustor have been investigated by varying the distance of injector position from left boundary keeping constant the backward-facing step height and other calculation parameters. The results show that the configuration for small distance of injector position has high mixing efficiency but the upstream recirculation can not evolved properly which is an important factor for flame holding capability. On the other hand, the configuration for very long distance has lower mixing efficiency due to lower gradient of hydrogen mass concentration on the top of injector caused by the expansion of side jet in both upstream and downstream of injector. For moderate distance of injector position, large and elongated upstream recirculation can evolve which might be activated as a good flame holder.

  3. A Detailed Investigation of Staged Normal Injection into a Mach 2 Flow

    Science.gov (United States)

    Eklund, Dean R.; Northam, G. Burton; Hartfield, Roy J., Jr.

    1990-01-01

    A study of the staged injection of two jets of air behind a rearward facing step into a Mach 2 flow was performed using the SPARK 3-D Navier-Stokes code. Calculated mole fraction distributions were compared with an extensive set of planar mole fraction measurements made with a laser induced iodine fluorescence technique. A statistical measure, the standard deviation, was used to help assess agreement between calculation and experiment. Overall, good agreement was found between calculated and measured values. Generally, agreement was better in the far field of the injectors. The effect of grid resolution was investigated by calculating solutions on grids of 60,000, 200,000, and 450,000 points. Differences in the solutions on the two finer grids were small. However, the mole fraction distributions were distinguishable. The effect of turbulence modeling was investigated by employing three different algebraic models for the jet turbulence: the Baldwin-Lomax model, the Prandtl mixing length model, and the Eggers mixing length model. Overall, the Eggers mixing length model was found to be superior for this case. Finally, the effect of the jet exit conditions was examined. A recently proposed Mach number distribution at the jet exit was found to slightly improve agreement between measurement and calculation.

  4. Study on the interaction of catalase with pesticides by flow injection chemiluminescence and molecular docking.

    Science.gov (United States)

    Tan, Xijuan; Wang, Zhuming; Chen, Donghua; Luo, Kai; Xiong, Xunyu; Song, Zhenghua

    2014-08-01

    The interaction mechanisms of catalase (CAT) with pesticides (including organophosphates: disulfoton, isofenphos-methyl, malathion, isocarbophos, dimethoate, dipterex, methamidophos and acephate; carbamates: carbaryl and methomyl; pyrethroids: fenvalerate and deltamethrin) were first investigated by flow injection (FI) chemiluminescence (CL) analysis and molecular docking. By homemade FI-CL model of lg[(I0-I)/I]=lgK+nlg[D], it was found that the binding processes of pesticides to CAT were spontaneous with the apparent binding constants K of 10(3)-10(5) L mol(-1) and the numbers of binding sites about 1.0. The binding abilities of pesticides to CAT followed the order: fenvalerate>deltamethrin>disulfoton>isofenphos-methyl>carbaryl>malathion>isocarbophos>dimethoate>dipterex>acephate>methomyl>methamidophos, which was generally similar to the order of determination sensitivity of pesticides. The thermodynamic parameters revealed that CAT bound with hydrophobic pesticides by hydrophobic interaction force, and with hydrophilic pesticides by hydrogen bond and van der Waals force. The pesticides to CAT molecular docking study showed that pesticides could enter into the cavity locating among the four subdomains of CAT, giving the specific amino acid residues and hydrogen bonds involved in CAT-pesticides interaction. It was also found that the lgK values of pesticides to CAT increased regularly with increasing lgP, Mr, MR and MV, suggesting that the hydrophobicity and steric property of pesticide played essential roles in its binding to CAT.

  5. Flow injection-chemiluminescence determination of ascorbic acid based on luminol–ferricyanide–gold nanoparticles system

    Energy Technology Data Exchange (ETDEWEB)

    Dong, Yong Ping, E-mail: dongyp@ahut.edu.cn [School of chemistry and chemical engineering, Anhui University of Technology, Maanshan, China, 243002 (China); Gao, Ting Ting; Chu, Xiang Feng; Chen, Jun [School of chemistry and chemical engineering, Anhui University of Technology, Maanshan, China, 243002 (China); Wang, Cheng Ming, E-mail: chmwang@ustc.edu.cn [Hefei National Laboratory for Physical Science at the Microscale, University of Science and Technology of China, Hefei, China, 230026 (China)

    2014-10-15

    A novel flow-injection chemiluminescence (CL) method for the determination of ascorbic acid (AA) is proposed, based upon its enhancing effect on the CL reaction of luminol with ferricyanide catalyzed by gold nanoparticles in alkaline solution. Different sizes gold nanoparticles exhibited different catalyzing effect towards luminol CL and 38 nm gold nanoparticles exhibited the best enhancing effect. Under the optimal experimental conditions, a linear relationship was obtained between the CL intensity and the concentration of ascorbic acid in the range of 1.0×10{sup −10}–1.0×10{sup −6} mol L{sup −1}. The detection limit was 2.0×10{sup –11} mol {sup −1} and the relative standard deviation for 1.0×10{sup −6} mol L{sup −1} ascorbic acid was 0.71% (n=10). This method has been successfully applied in the determination of ascorbic acid in several real samples. - Highlights: • Gold nanoparticles could enhance luminol–K{sub 3}Fe(CN){sub 6} CL signal. • 38 nm gold nanoparticles exhibited the best catalyzing effect. • Ascorbic acid could further enhance luminol–K{sub 3}Fe(CN){sub 6}–gold nanoparticles CL. • Ascorbic acid could be detected sensitively based on its enhancing effect.

  6. Flow-injection determination of isoniazid using sodium dichloroisocyanurate- and trichloroisocyanuric acid-luminol chemiluminescence systems.

    Science.gov (United States)

    Safavi, A; Karimi, M A; Hormozi Nezhad, M R

    2004-06-01

    A chemiluminescent (CL) method for the determination of isoniazid is described. The method is based on the CL generated during the oxidation of luminol by sodium dichloroisocyanurate (SDCC) and trichloroisocyanuric acid (TCCA) in alkaline medium. It was found that isoniazid greatly enhances this CL intensity when present in the luminol solution. Based on this observation, a new flow-injection CL method for the determination of isoniazid has been proposed in this paper. The detection limits were 2 and 3 ng ml(-1) isoniazid for the SDCC-luminol and TCCA-luminol CL systems, respectively. The relative CL intensity was linear with the isoniazid concentration in the range of 4-100 and 100-200 ng ml(-1) for the SDCC-luminol CL system, and 6-200 and 200-1000 ng ml(-1) for the TCCA-luminol CL system. The results obtained for the assay of pharmaceutical preparations compared well with those obtained by the official methods and demonstrated good accuracy and precision.

  7. A new sensitive flow-injection chemiluminescence method for the determination of H(2)-receptor antagonists.

    Science.gov (United States)

    Tang, Yu-Hai; Wang, Nan-Nan; Xiong, Xun-Yu; Xiong, Feng-Mei; Sun, Si-Juan

    2007-01-01

    Based on the chemiluminescence (CL) intensity generated from the potassium ferricyanide [K(3)Fe(CN)(6)]-rhodamine 6G system in sodium hydroxide (NaOH) medium, a new sensitive flow-injection chemiluminescence (FI-CL) method has been developed, validated and applied for the determination of three kinds of H(2)-receptor antagonists: cimetidine (CIMT), ranitidine (RANT) hydrochloride and famotidine (FAMT). Under the optimum conditions, the linear range for the determination was 1.0 x 10(-9)-7.0 x 10(-5) g/ml for CIMT, 1.0 x 10(-9)-5.0 x 10(-5) g/mL for RANT hydrochloride and 5.0 x 10(-9)-7.0 x 10(-5) g/mL for FAMT. During 11 repeated measurements of 1.0 x 10(-6) g/mL sample solutions, the relative standard deviations (RSDs) were all <5%. The detection limit was 8.56 x 10(-10) g/mL for CIMT, 8.69 x 10(-10) g/mL for RANT hydrochloride and 2.35 x 10(-9) g/mL for FAMT (S:N = 3). This method has been successfully implemented for the analysis of H(2)-receptor antagonists in pharmaceuticals.

  8. Flow injection analysis of nitrate and nitrite in commercial baby foods.

    Science.gov (United States)

    Chetty, Adrian A; Prasad, Surendra

    2016-04-15

    Commercial baby foods are an easy alternative to home-made meals especially for working parents in a nuclear family therefore it is imperative to determine the nitrate and nitrite content in commercially available baby foods varieties marketed in Fiji. A total of 108 baby food samples were analyzed for nitrate and nitrite using our standardized flow injection analysis (FIA) technique with colorimetric detection technique employing sulfanilamide and N-(1-naphthyl)ethylenediamine dihydrochloride as color reagents where the samples throughput was 38 h(-1). The commercial baby food varieties chosen comprised of vegetables, cereals, fruits and milk. The study shows that the nitrate content of the baby foods studied ranges from 2.10 to 220.67 mg kg(-1) whereas the nitrite content ranges from 0.44 to 3.67 mg kg(-1). Typical recoveries of spiked nitrate residues ranged from 92% to 106%. The study shows that the average nitrate content of commercially available baby foods in Fiji descends below the maximum level proposed by the European Union Legislation. Copyright © 2015 Elsevier Ltd. All rights reserved.

  9. Screening and determination of sulphonamide residues in bovine milk samples using a flow injection system.

    Science.gov (United States)

    Fernandes, Flávio Cesar Bedatty; Silva, Aline Santana; Rufino, José Luiz; Pezza, Helena Redigolo; Pezza, Leonardo

    2015-01-01

    A new, simple, rapid and sensitive flow injection spectrophotometric method was developed for the screening and determination of sulphonamides in bovine milk samples. The method is based on the condensation of sulphathiazole, sulphamethazine, and sulphadimethoxine with p-dimethylaminobenzaldehyde (p-DAB) in acid medium, in the presence of sodium dodecyl sulphate (SDS), producing a yellow compound (λmax=465 nm). Optimisation of the experimental parameters was performed using a multivariate methodology. The linear range was 90-500 μg/L and the limits of detection and quantification were in the ranges 25-29 μg/L and 84-88 μg/L, respectively. The procedure was applied for the determination of sulphonamide antibiotics in bovine milk samples submitted to a prior extraction procedure based on QuEChERS (Quick, Easy, Cheap, Effective, Rugged and Safe) methodology. Recoveries of 60.5-70.5% were achieved for milk samples spiked with 0.09, 0.1, 0.2, and 0.3 μg/g of each sulphonamide.

  10. Determination of nabumetone in pharmaceutical formulation by flow injection analysis (FIA) with UV-detection.

    Science.gov (United States)

    Can, N O; Tuncel, M; Aboul-Enein, H Y

    2003-01-01

    A precise and accurate FIA method for the quantification of nabumetone (NAB) in pharmaceuticals is described. The best suitable carrier solvent system consisted of ethanol: water (30:70 v/v). Sample solution (4.7 x 10(-6) M NAB) was prepared in this solvent and injected to the instrumental system at a flow rate of 1.2 ml x min(-1). The signals were detected by a UV detector at 228.8 nm. The calibration curves of NAB was linear in the concentration range of 1.4 x 10(-6) M-2.8 x 10(-5) M. The intra- and inter-assay precision were less than 2.6%. The method exhibited a good linearity with the correlation coefficients. The LOD and LOQ values were found to be 4.4 x 10(-7) and 1.3 x 10(-6) M, respectively. The effects of the tablet excipients were insignificant at the 95% probability level. The calculated tablet content was 99% which is agreement with the ranges stated by pharmacopoeias.

  11. Flow injection analysis as a tool for enhancing oceanographic nutrient measurements--a review.

    Science.gov (United States)

    Worsfold, Paul J; Clough, Robert; Lohan, Maeve C; Monbet, Philippe; Ellis, Peter S; Quétel, Christophe R; Floor, Geerke H; McKelvie, Ian D

    2013-11-25

    Macronutrient elements (C, N and P) and micronutrient elements (Fe, Co, Cu, Zn and Mn) are widely measured in their various physico-chemical forms in open ocean, shelf sea, coastal and estuarine waters. These measurements help to elucidate the biogeochemical cycling of these elements in marine waters and highlight the ecological and socio-economic importance of the oceans. Due to the dynamic nature of marine waters in terms of chemical, biological and physical processes, it is advantageous to make these measurements in situ and in this regard flow injection analysis (FIA) provides a suitable shipboard platform. This review, therefore, discusses the role of FIA in the determination of macro- and micro-nutrient elements, with an emphasis on manifold design and detection strategies for the reliable shipboard determination of specific nutrient species. The application of various FIA manifolds to oceanographic nutrient determinations is discussed, with an emphasis on sensitivity, selectivity, high throughput analysis and suitability for underway analysis and depth profiles. Strategies for enhancing sensitivity and minimizing matrix effects, e.g. refractive index (schlieren) effects and the important role of uncertainty budgets in underpinning method validation and data quality are discussed in some detail.

  12. Management of solid wastes from the Limestone Injection Dry Scrubbing (LIDS) clean coal technology. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Musiol, W.F. Jr.; Czuczwa, J.M.

    1993-03-01

    The objectives of this project were to characterize by-products from a pilot Limestone Injection Dry Scrubbing (LIDS) process and to develop processes directed toward the safe and economic use or disposal of these wastes. Because LIDS is a developing Clean Coal technology, a database of chemical and physical characteristics of the by-product was first developed. During the course of this project, it was found that the waste alone did not form high-strength products sufficient for use in construction and engineering applications. Therefore, the project was redirected to evaluate the by-product as a soil-cement and Portland cement raw material, agricultural liming agent, backfill/landfill material component, and mine reclamation/neutralizing agent. Based on these evaluations, the most viable uses for the LIDS byproduct include use in mine reclamation or as a neutralization agent. If soluble sulfites can be minimized by avoiding a dolomitic LIDS reagent, use as an agricultural liming agent has promise. Interest from an Ohio utility in the LIDS process suggests possible application of results at the demonstration or commercial stages.

  13. Amsacrine analog-loaded solid lipid nanoparticle to resolve insolubility for injection delivery: characterization and pharmacokinetics

    Directory of Open Access Journals (Sweden)

    Fang YP

    2016-03-01

    Full Text Available Yi-Ping Fang,1 Chih-Hung Chuang,2 Pao-Chu Wu,1 Yaw-Bin Huang,1 Cherng-Chyi Tzeng,3 Yeh-Long Chen,3 Ya-Ting Liu,1 Yi-Hung Tsai,1 Ming-Jun Tsai4–6 1School of Pharmacy, College of Pharmacy, 2Department of Biomedical and Environment Biology, College of Life Science, 3School of Medicinal and Applied Chemistry, College of Life Science, Kaohsiung Medical University, Kaohsiung, 4Department of Neurology, China Medical University Hospital, 5School of Medicine, Medical College, China Medical University, Taichung, 6Department of Neurology, China Medical University An-Nan Hospital, Tainan, Taiwan Abstract: Amsacrine analog is a novel chemotherapeutic agent that provides potentially broad antitumor activity when compared to traditional amsacrine. However, the major limitation of amsacrine analog is that it is highly lipophilic, making it nonconductive to intravenous administration. The aim of this study was to utilize solid lipid nanoparticles (SLN to resolve the delivery problem and to investigate the biodistribution of amsacrine analog-loaded SLN. Physicochemical characterizations of SLN, including particle size, zeta potential, entrapment efficiency, and stability, were evaluated. In vitro release behavior was also measured by the dialysis method. In vivo pharmacokinetics and biodistribution behavior of amsacrine analog were investigated and incorporated with a non invasion in vivo imaging system to confirm the localization of SLN. The results showed that amsacrine analog-loaded SLN was 36.7 nm in particle size, 0.37 in polydispersity index, and 34.5±0.047 mV in zeta potential. More than 99% of amsacrine analog was successfully entrapped in the SLN. There were no significant differences in the physicochemical properties after storage at room temperature (25°C for 1 month. Amsacrine analog-loaded SLN maintained good stability. An in vitro release study showed that amsacrine analog-loaded SLN sustained a release pattern and followed the zero equation. An

  14. Three-dimensional analysis of internal flow characteristics in the injection nozzle tip of direct-injection diesel engines; Sanjigen suchi kaiseki ni yoru DI diesel kikan no nenryo funsha nozzle nai ryudo tokusei no kaimei

    Energy Technology Data Exchange (ETDEWEB)

    Ogawa, H.; Matsui, Y.; Kimura, S. [Nissan Motor Co. Ltd. Tokyo (Japan)

    1997-10-01

    To reduce the exhaust emissions and fuel consumption of direct-injection diesel engines, it is essential to optimize the fuel injection equipment closely related to combustion and emission characteristics. In this study, three-dimensional computation has been applied to investigate the effects of the injection nozzle specifications (e.g., sac volume, round shape at the inlet of the nozzle hole) and needle tip deviation on internal flow characteristics. The computational results revealed that the effects of the nozzle specifications and needle tip deviation with a smaller needle lift on internal flow characteristics and a general approach to optimize the injection nozzle specifications were obtained. 3 refs., 10 figs., 1 tab.

  15. A continuum theory for two-phase flows of particulate solids: application to Poiseuille flows

    Science.gov (United States)

    Monsorno, Davide; Varsakelis, Christos; Papalexandris, Miltiadis V.

    2015-11-01

    In the first part of this talk, we present a novel two-phase continuum model for incompressible fluid-saturated granular flows. The model accounts for both compaction and shear-induced dilatancy and accommodates correlations for the granular rheology in a thermodynamically consistent way. In the second part of this talk, we exercise this two-phase model in the numerical simulation of a fully-developed Poiseuille flow of a dense suspension. The numerical predictions are shown to compare favorably against experimental measurements and confirm that the model can capture the important characteristics of the flow field, such as segregation and formation of plug zones. Finally, results from parametric studies with respect to the initial concentration, the magnitude of the external forcing and the width of the channel are presented and the role of these physical parameters is quantified. Financial Support has been provided by SEDITRANS, an Initial Training Network of the European Commission's 7th Framework Programme

  16. Design and fabrication of novel anode flow-field for commercial size solid oxide fuel cells

    Science.gov (United States)

    Canavar, Murat; Timurkutluk, Bora

    2017-04-01

    In this study, nickel based woven meshes are tested as not only anode current collecting meshes but also anode flow fields instead of the conventional gas channels fabricated by machining. For this purpose, short stacks with different anode flow fields are designed and built by using different number of meshes with various wire diameters and widths of opening. A short stack with classical machined flow channels is also constructed. Performance and impedance measurements of the short stacks with commercial size cells of 81 cm2 active area are performed and compared. The results reveal that it is possible to create solid oxide fuel cell anode flow fields with woven meshes and obtain acceptable power with a proper selection of the mesh number, type and orientation.

  17. Determination of Zinc-Based Additives in Lubricating Oils by Flow-Injection Analysis with Flame-AAS Detection Exploiting Injection with a Computer-Controlled Syringe.

    Science.gov (United States)

    Pignalosa, Gustavo; Knochen, Moisés; Cabrera, Noel

    2005-01-01

    A flow-injection system is proposed for the determination of metal-based additives in lubricating oils. The system, operating under computer control uses a motorised syringe for measuring and injecting the oil sample (200 muL) in a kerosene stream, where it is dispersed by means of a packed mixing reactor and carried to an atomic absorption spectrometer which is used as detector. Zinc was used as model analyte. Two different systems were evaluated, one for low concentrations (range 0-10 ppm) and the second capable of providing higher dilution rates for high concentrations (range 0.02%-0.2% w/w). The sampling frequency was about 30 samples/h. Calibration curves fitted a second-degree regression model (r(2) = 0.996). Commercial samples with high and low zinc levels were analysed by the proposed method and the results were compared with those obtained with the standard ASTM method. The t test for mean values showed no significant differences at the 95% confidence level. Precision (RSD%) was better than 5% (2% typical) for the high concentrations system. The carryover between successive injections was found to be negligible.

  18. Effects of Injection Timing on Fluid Flow Characteristics of Partially Premixed Combustion Based on High-Speed Particle Image Velocimetry

    KAUST Repository

    Izadi Najafabadi, Mohammad

    2017-03-28

    Partially Premixed Combustion (PPC) is a promising combustion concept ,based on judicious tuning of the charge stratification, to meet the increasing demands of emission legislation and to improve fuel efficiency. Longer ignition delays of PPC in comparison with conventional diesel combustion provide better fuel/air mixture which decreases soot and NO emissions. Moreover, a proper injection timing and strategy for PPC can improve the combustion stability as a result of a higher level of fuel stratification in comparison with the Homogeneous Charge Compression Ignition (HCCI) concept. Injection timing is the major parameter with which to affect the level of fuel and combustion stratification and to control the combustion phasing and the heat release behavior. The scope of the present study is to investigate the fluid flow characteristics of PPC at different injection timings. To this end, high-speed Particle Image Velocimetry (PIV) is implemented in a light-duty optical engine to measure fluid flow characteristics, including the flow fields, mean velocity and cycle-resolved turbulence, inside the piston bowl as well as the squish region with a temporal resolution of 1 crank angle degree at 800 rpm. Two injectors, having 5 and 7 holes, were compared to see their effects on fluid flow and heat release behavior for different injection timings. Reactive and non-reactive measurements were performed to distinguish injection-driven and combustion-driven turbulence. Formation of vortices and higher turbulence levels enhance the air/fuel interaction, changing the level of fuel stratification and combustion duration. Results demonstrate clearly how turbulence level correlates with heat release behavior, and provide a quantitative dataset for validation of numerical simulations.

  19. Perspectives of advanced thermal management in solar thermochemical syngas production using a counter-flow solid-solid heat exchanger

    Science.gov (United States)

    Falter, Christoph; Sizmann, Andreas; Pitz-Paal, Robert

    2017-06-01

    A modular reactor model is presented for the description of solar thermochemical syngas production involving counter-flow heat exchangers that recuperate heat from the solid phase. The development of the model is described including heat diffusion within the reactive material as it travels through the heat exchanger, which was previously identified to be a possibly limiting factor in heat exchanger design. Heat transfer within the reactive medium is described by conduction and radiation, where the former is modeled with the three-resistor model and the latter with the Rosseland diffusion approximation. The applicability of the model is shown by the analysis of heat exchanger efficiency for different material thicknesses and porosities in a system with 8 chambers and oxidation and reduction temperatures of 1000 K and 1800 K, respectively. Heat exchanger efficiency is found to rise strongly for a reduction of material thickness, as the element mass is reduced and a larger part of the elements takes part in the heat exchange process. An increase of porosity enhances radiation heat exchange but deteriorates conduction. The overall heat exchange in the material is improved for high temperatures in the heat exchanger, as radiation dominates the energy transfer. The model is shown to be a valuable tool for the development and analysis of solar thermochemical reactor concepts involving heat exchange from the solid phase.

  20. Microgravity flame spread over thick solids in low velocity opposed flow

    Science.gov (United States)

    Wang, Shuangfeng; Zhu, Feng

    2016-07-01

    Motivated primarily by fire safety of spacecraft, a renewed interest in microgravity flame spread over solid materials has arisen. With few exceptions, however, research on microgravity flame spread has been focused on thermally thin fuels due to the constraint on available test time. In this study, two sets of experiments are conducted to examine the flame spread and extinction behavior over thick PMMA in simulated and actual microgravity environments. The low-gravity flame spread environment is produced by a narrow channel apparatus in normal gravity. Extinction limits using flow velocity and oxygen concentration as coordinates are presented, and flame spread rates are determined as a function of the velocity and oxygen concentration of the gas flow. The microgravity experiments are also performed with varying low-velocity flow and varying ambient oxygen concentration. The important observations include flame behavior and appearance as a function of oxygen concentration and flow velocity, temperature variation in gas and solid phases, and flame spread rate. A comparison between simulated and actual microgravity data is made, and general agreement is found. Based on the experimental observations, mechanisms for flame spread and extinction in low velocity opposed flows are discussed.

  1. Effect of particle inertia on fluid turbulence in gas-solid disperse flow

    Science.gov (United States)

    Mito, Yoichi

    2016-11-01

    The effect of particle inertia on the fluid turbulence in gas-solid disperse flow through a vertical channel has been examined by using a direct numerical simulation, to calculate the gas velocities seen by the particles, and a simplified non-stationary flow model, in which a uniform distribution of solid spheres of density ratio of 1000 are added into the fully-developed turbulent gas flow in an infinitely wide channel. The gas flow is driven downward with a constant pressure gradient. The frictional Reynolds number defined with the frictional velocity before the addition of particles, v0*, is 150. The feedback forces are calculated using a point force method. Particle diameters of 0.95, 1.3 and 1.9, which are made dimensionless with v0* and the kinematic viscosity, and volume fractions, ranging from 1 ×10-4 to 2 ×10-3 , in addition to the one-way coupling cases, are considered. Gravitational effect is not clearly seen where the fluid turbulence is damped by feedback effect. Gas flow rate increases with the decrease in particle inertia, that causes the increase in feedback force. Fluid turbulence decreases with the increase in particle inertia, that causes the increase in diffusivity of feedback force and of fluid turbulence. This work was supported by JSPS KAKENHI Grant Number 26420097.

  2. Study on flow characteristics of solid/liquid system in lysozyme crystal growth

    Institute of Scientific and Technical Information of China (English)

    CUI HaiLiang; YU Yong; CHEN WanChun; KANG Qi

    2007-01-01

    During the process of lysozyme protein crystallization with batch method, the macroscopic flow field of solid/liquid system was observed by particle image velocimetry (PIV). Furthermore, a normal growth rate of (110) face and local flow field around a single protein crystal were obtained by a long work distance microscope. The experimental results showed that the average velocity, the maximal velocity of macroscopic solid/liquid system and the velooity of local flow field around single protein crystal were fluctuant. The effective boundary layer thickness δeff, the concentration at the interface Gi and the characteristic velocity V were calculated using a convection-diffusion model. The results showed that the growth of lysozyme crystal in this experiment was dominated by interfacial kinetics rather than bulk transport, and the function of buoyancy-driven flow in bulk transport was small, however, the effect of bulk transport in crystal growth had a tendency to increase with the increase of lysozyme concentration. The calculated results also showed that the order of magnitude of shear force was about 10-21 N,which was much less than the bond force between the lysozyme molecules. Therefore the shear force induced by buoyancy-driven flows cannot remove the protein molecules from the interface of crystal.

  3. Liquid-gas-solid flows with lattice Boltzmann: Simulation of floating bodies

    CERN Document Server

    Bogner, Simon

    2012-01-01

    This paper presents a model for the simulation of liquid-gas-solid flows by means of the lattice Boltzmann method. The approach is built upon previous works for the simulation of liquid-solid particle suspensions on the one hand, and on a liquid-gas free surface model on the other. We show how the two approaches can be unified by a novel set of dynamic cell conversion rules. For evaluation, we concentrate on the rotational stability of non-spherical rigid bodies floating on a plane water surface - a classical hydrostatic problem known from naval architecture. We show the consistency of our method in this kind of flows and obtain convergence towards the ideal solution for the measured heeling stability of a floating box.

  4. Unsteady Stagnation Point Flow and Heat Transfer over a Stretching/Shrinking Sheet with Suction or Injection

    Directory of Open Access Journals (Sweden)

    M. Suali

    2012-01-01

    Full Text Available The unsteady stagnation point flow and heat transfer over a stretching/shrinking sheet with suction/injection is studied. The governing partial differential equations are converted into nonlinear ordinary differential equations using a similarity transformation and solved numerically. Both stretching and shrinking cases are considered. Results for the skin friction coefficient, local Nusselt number, velocity, and temperature profiles are presented for different values of the governing parameters. It is found that the dual solutions exist for the shrinking case, whereas the solution is unique for the stretching case. Numerical results show that the range of dual solutions increases with mass suction and decreases with mass injection.

  5. A rapid and accurate method for determining protein content in dairy products based on asynchronous-injection alternating merging zone flow-injection spectrophotometry.

    Science.gov (United States)

    Liang, Qin-Qin; Li, Yong-Sheng

    2013-12-01

    An accurate and rapid method and a system to determine protein content using asynchronous-injection alternating merging zone flow-injection spectrophotometry based on reaction between coomassie brilliant blue G250 (CBBG) and protein was established. Main merit of our approach is that it can avoid interferences of other nitric-compounds in samples, such as melamine and urea. Optimized conditions are as follows: Concentrations of CBBG, polyvinyl alcohol (PVA), NaCl and HCl are 150 mg/l, 30 mg/l, 0.1 mol/l and 1.0% (v/v), respectively; volumes of the sample and reagent are 150 μl and 30 μl, respectively; length of a reaction coil is 200 cm; total flow rate is 2.65 ml/min. The linear range of the method is 0.5-15 mg/l (BSA), its detection limit is 0.05 mg/l, relative standard deviation is less than 1.87% (n=11), and analytical speed is 60 samples per hour.

  6. Molecular dynamics study of solid-liquid heat transfer and passive liquid flow

    Science.gov (United States)

    Yesudasan Daisy, Sumith

    High heat flux removal is a challenging problem in boilers, electronics cooling, concentrated photovoltaic and other power conversion devices. Heat transfer by phase change is one of the most efficient mechanisms for removing heat from a solid surface. Futuristic electronic devices are expected to generate more than 1000 W/cm2 of heat. Despite the advancements in microscale and nanoscale manufacturing, the maximum passive heat flux removal has been 300 W/cm2 in pool boiling. Such limitations can be overcome by developing nanoscale thin-film evaporation based devices, which however require a better understanding of surface interactions and liquid vapor phase change process. Evaporation based passive flow is an inspiration from the transpiration process that happens in trees. If we can mimic this process and develop heat removal devices, then we can develop efficient cooling devices. The existing passive flow based cooling devices still needs improvement to meet the future demands. To improve the efficiency and capacity of these devices, we need to explore and quantify the passive flow happening at nanoscales. Experimental techniques have not advanced enough to study these fundamental phenomena at the nanoscale, an alternative method is to perform theoretical study at nanoscales. Molecular dynamics (MD) simulation is a widely accepted powerful tool for studying a range of fundamental and engineering problems. MD simulations can be utilized to study the passive flow mechanism and heat transfer due to it. To study passive flow using MD, apart from the conventional methods available in MD, we need to have methods to simulate the heat transfer between solid and liquid, local pressure, surface tension, density, temperature calculation methods, realistic boundary conditions, etc. Heat transfer between solid and fluids has been a challenging area in MD simulations, and has only been minimally explored (especially for a practical fluid like water). Conventionally, an

  7. Are Flow Injection-based Approaches Suitable for Automated Handling of Solid Samples?

    DEFF Research Database (Denmark)

    Miró, Manuel; Hansen, Elo Harald; Cerdà, Victor

    with the potential hyphenation with modern analytical instrumentation for automated monitoring of the content of targeted species in the on-line generated extracts [3,4]. [1] Z.-L. Zhi, A. Ríos, M. Valcárcel, Crit. Rev. Anal. Chem., 26 (1996) 239. [2] M. Miró, E.H. Hansen, R. Chomchoei, W. Frenzel, TRAC-Trends Anal...

  8. A Variational Model for Two-Phase Immiscible Electroosmotic Flow at Solid Surfaces

    KAUST Repository

    Shao, Sihong

    2012-01-01

    We develop a continuum hydrodynamic model for two-phase immiscible flows that involve electroosmotic effect in an electrolyte and moving contact line at solid surfaces. The model is derived through a variational approach based on the Onsager principle of minimum energy dissipation. This approach was first presented in the derivation of a continuum hydrodynamic model for moving contact line in neutral two-phase immiscible flows (Qian, Wang, and Sheng, J. Fluid Mech. 564, 333-360 (2006)). Physically, the electroosmotic effect can be formulated by the Onsager principle as well in the linear response regime. Therefore, the same variational approach is applied here to the derivation of the continuum hydrodynamic model for charged two-phase immiscible flows where one fluid component is an electrolyte exhibiting electroosmotic effect on a charged surface. A phase field is employed to model the diffuse interface between two immiscible fluid components, one being the electrolyte and the other a nonconductive fluid, both allowed to slip at solid surfaces. Our model consists of the incompressible Navier-Stokes equation for momentum transport, the Nernst-Planck equation for ion transport, the Cahn-Hilliard phase-field equation for interface motion, and the Poisson equation for electric potential, along with all the necessary boundary conditions. In particular, all the dynamic boundary conditions at solid surfaces, including the generalized Navier boundary condition for slip, are derived together with the equations of motion in the bulk region. Numerical examples in two-dimensional space, which involve overlapped electric double layer fields, have been presented to demonstrate the validity and applicability of the model, and a few salient features of the two-phase immiscible electroosmotic flows at solid surface. The wall slip in the vicinity of moving contact line and the Smoluchowski slip in the electric double layer are both investigated. © 2012 Global-Science Press.

  9. study of solid-liquid flow regimes in mining industry using gamma radiation

    Energy Technology Data Exchange (ETDEWEB)

    Salgado, Cesar M.; Brandao, Luis E.B.; Nunes, Rogerio C.; Nascimento, Ana C. de H., E-mail: otero@ien.gov.br, E-mail: brandao@ien.gov.br, E-mail: chaffin@ien.gov.br, E-mail: acris@ien.gov.br [Instituto de Engenharia Nuclear (IEN/CNEN-RJ), Rio de Janeiro, RJ (Brazil); Salgado, William L., E-mail: william.otero@hotmail.com [Instituto Federal do Rio de Janeiro (IFRJ), Nilopolis, RJ (Brazil)

    2013-07-01

    One of the most promising areas in the mining industry is the development of devices for measuring solid mass flowrate in pipelines, mainly in transportation of ore. These units are composed of interconnected pipes where transport of the material is accomplished by pumps capable of driving the ore pellets using water. One of the problems inherent in these systems is the stratification if a critical velocity is reached, the ore pellets begin to sediment at the bottom of the pipe and it may block the system. The solid phase displacement behavior depends on a number of factors (water flowrate, density, pipe diameter, average size of the pellet) which makes the flow regime knowledge essential to the appropriate operation of the system. An apparatus to evaluate the stratification level through of particle (ore pellets) spatial distributions inside the pipe is important because it increases the safety condition of pumping and transportation of solid phase. Therefore, this work presents a study to optimize the geometrical parameters for the identification of a possible stratification of the solid phase inside a pipeline. The detection system uses different NaI(Tl) detectors and gamma ray sources (fan beam geometry), adequately positioned in order to calculate transmitted and scattered beams. Additionally, theoretical models for different flow regimes (homogeneous and stratified) have been developed using MCNP-X mathematical code. (author)

  10. Numerically stable fluid–structure interactions between compressible flow and solid structures

    KAUST Repository

    Grétarsson, Jón Tómas

    2011-04-01

    We propose a novel method to implicitly two-way couple Eulerian compressible flow to volumetric Lagrangian solids. The method works for both deformable and rigid solids and for arbitrary equations of state. The method exploits the formulation of [11] which solves compressible fluid in a semi-implicit manner, solving for the advection part explicitly and then correcting the intermediate state to time tn+1 using an implicit pressure, obtained by solving a modified Poisson system. Similar to previous fluid-structure interaction methods, we apply pressure forces to the solid and enforce a velocity boundary condition on the fluid in order to satisfy a no-slip constraint. Unlike previous methods, however, we apply these coupled interactions implicitly by adding the constraint to the pressure system and combining it with any implicit solid forces in order to obtain a strongly coupled, symmetric indefinite system (similar to [17], which only handles incompressible flow). We also show that, under a few reasonable assumptions, this system can be made symmetric positive-definite by following the methodology of [16]. Because our method handles the fluid-structure interactions implicitly, we avoid introducing any new time step restrictions and obtain stable results even for high density-to-mass ratios, where explicit methods struggle or fail. We exactly conserve momentum and kinetic energy (thermal fluid-structure interactions are not considered) at the fluid-structure interface, and hence naturally handle highly non-linear phenomenon such as shocks, contacts and rarefactions. © 2011 Elsevier Inc.

  11. The aerodynamic effects of wheelspace coolant injection into the mainstream flow of a high pressure gas turbine

    Science.gov (United States)

    McLean, Christopher Elliot

    Modern gas turbine engines operate with mainstream gas temperatures exceeding 1450°C in the high-pressure turbine stage. Unlike turbine blades, rotor disks and other internal components are not designed to withstand the extreme temperatures found in mainstream flow. In modern gas turbines, cooling air is pumped into the wheelspace cavities to prevent mainstream gas ingestion and then exits through a seal between the rotor and the nozzle guide vane (NGV) thereby mixing with the mainstream flow. The primary purpose for the wheelspace cooling air is the cooling of the turbine wheelspace. However, secondary effects arise from the mixing of the spent cooling air with the mainstream flow. The exiting cooling air is mixed with the hot mainstream flow effecting the aerodynamic and performance characteristics of the turbine stage. The physics underlying this mixing process and its effects on stage performance are not yet fully understood. The relative aerodynamic and performance effects associated with rotor - NGV gap coolant injections were investigated in the Axial Flow Turbine Research Facility (AFTRF) of the Center for Gas Turbines and Power of The Pennsylvania State University. This study quantifies the secondary effects of the coolant injection on the aerodynamic and performance character of the turbines main stream flow for root injection, radial cooling, and impingement cooling. Measurement and analysis of the cooling effects were performed in both stationary and rotational frames of reference. The AFTRF is unique in its ability to perform long duration cooling measurements in the stationary and rotating frames. The effects of wheelspace coolant mixing with the mainstream flow on total-to-total efficiency, energy transport, three dimensional velocity field, and loading coefficient were investigated. Overall, it was found that a small quantity (1%) of cooling air can have significant effects on the performance character and exit conditions of the high pressure stage

  12. Control valve and control valve system for controlling solids flow, methods of manufacture thereof and articles comprising the same

    Energy Technology Data Exchange (ETDEWEB)

    Jukkola, Glen D.; Teigen, Bard C.

    2017-04-11

    Disclosed herein is a solids flow control valve comprising a standpipe; a shoe; and a transport pipe; wherein the standpipe is in operative communication with the shoe and lies upstream of the shoe; the standpipe comprising a first end and a second end, where the first end is in contact with a source that contains disposable solids and the second end is in fluid contact with the shoe; the shoe being operative to restrict the flow of the disposable solids; the transport pipe being disposed downstream of the shoe to receive and transport the solids from the shoe.

  13. Emerging flow injection mass spectrometry methods for high-throughput quantitative analysis.

    Science.gov (United States)

    Nanita, Sergio C; Kaldon, Laura G

    2016-01-01

    Where does flow injection analysis mass spectrometry (FIA-MS) stand relative to ambient mass spectrometry (MS) and chromatography-MS? Improvements in FIA-MS methods have resulted in fast-expanding uses of this technique. Key advantages of FIA-MS over chromatography-MS are fast analysis (typical run time quantitative screening of chemicals needs to be performed rapidly and reliably. The FIA-MS methods discussed herein have demonstrated quantitation of diverse analytes, including pharmaceuticals, pesticides, environmental contaminants, and endogenous compounds, at levels ranging from parts-per-billion (ppb) to parts-per-million (ppm) in very complex matrices (such as blood, urine, and a variety of foods of plant and animal origin), allowing successful applications of the technique in clinical diagnostics, metabolomics, environmental sciences, toxicology, and detection of adulterated/counterfeited goods. The recent boom in applications of FIA-MS for high-throughput quantitative analysis has been driven in part by (1) the continuous improvements in sensitivity and selectivity of MS instrumentation, (2) the introduction of novel sample preparation procedures compatible with standalone mass spectrometric analysis such as salting out assisted liquid-liquid extraction (SALLE) with volatile solutes and NH4(+) QuEChERS, and (3) the need to improve efficiency of laboratories to satisfy increasing analytical demand while lowering operational cost. The advantages and drawbacks of quantitative analysis by FIA-MS are discussed in comparison to chromatography-MS and ambient MS (e.g., DESI, LAESI, DART). Generally, FIA-MS sits 'in the middle' between ambient MS and chromatography-MS, offering a balance between analytical capability and sample analysis throughput suitable for broad applications in life sciences, agricultural chemistry, consumer safety, and beyond.

  14. Flow-injection spectrophotometric determination of cyanate in bioremediation processes by use of immobilised inducible cyanase

    Energy Technology Data Exchange (ETDEWEB)

    Luque-Almagro, V.M. [Department of Biochemistry and Molecular Biology, Edifice Severo Ochoa, Campus of Rabanales, University of Cordoba, 14071, Cordoba (Spain); Blasco, R. [Department of Biochemistry, Molecular Biology and Genetics, Veterinary School, University of Extremadura, 10071, Caceres (Spain); Fernandez-Romero, J.M.; Castro, M.D. Luque de [Department of Analytical Chemistry, Annex Edifice Marie Curie, Campus of Rabanales, University of Cordoba, 14071, Cordoba (Spain)

    2003-11-01

    A new flow injection (FI) method for photometric monitoring of cyanate in bioremediation processes using immobilised native cyanase is described. The method is based on the catalytic reaction between cyanate and bicarbonate to produce ammonia and carbon dioxide in the presence of an inducible native cyanase, immobilised in a reactor packed with glass beads. Two degrees of purification of the biocatalyst were used - heated cell-free extract and purified extract of cyanase from Pseudomonas pseudoalcaligenes CECT 5344. The ammonia produced by the enzymatic reaction is finally monitored photometrically at 700 nm using a modification of the conventional Berthelot method. The method furnishes different calibration curves depending on the degree of purification of the cyanase, with linear ranges between 1.23 and 616.50 {mu}mol L{sup -1} (r{sup 2}=0.9979, n=7) and between 1.07 and 308.25 {mu}mol L{sup -1} (r{sup 2}= 0.9992, n=7) for the heated cell-free extract and the purified cyanase extract, respectively. No statistically significant differences between the samples were found in the precision study evaluated at two cyanate concentration levels using one-way analysis of variance. A sampling frequency of 15 h{sup -1} was achieved. The method was used to monitor cyanate consumption in a cyanate bioremediation tank inoculated with Pseudomonas pseudoalcaligenes CECT 5344 strain. The correlation between cyanate degradation and ammonia production was tested using a conventional method. Finally, the method was applied to different samples collected from the bioremediation tank using the standard addition method; recoveries between 85.9 and 97.4% were obtained. (orig.)

  15. Flow-injection spectrophotometric determination of cyanate in bioremediation processes by use of immobilised inducible cyanase.

    Science.gov (United States)

    Luque-Almagro, V M; Blasco, R; Fernández-Romero, J M; de Castro, M D Luque

    2003-11-01

    A new flow injection (FI) method for photometric monitoring of cyanate in bioremediation processes using immobilised native cyanase is described. The method is based on the catalytic reaction between cyanate and bicarbonate to produce ammonia and carbon dioxide in the presence of an inducible native cyanase, immobilised in a reactor packed with glass beads. Two degrees of purification of the biocatalyst were used-heated cell-free extract and purified extract of cyanase from Pseudomonas pseudoalcaligenes CECT 5344. The ammonia produced by the enzymatic reaction is finally monitored photometrically at 700 nm using a modification of the conventional Berthelot method. The method furnishes different calibration curves depending on the degree of purification of the cyanase, with linear ranges between 1.23 and 616.50 micromol L(-1) ( r(2)=0.9979, n=7) and between 1.07 and 308.25 micro mol L(-1) ( r(2)= 0.9992, n=7) for the heated cell-free extract and the purified cyanase extract, respectively. No statistically significant differences between the samples were found in the precision study evaluated at two cyanate concentration levels using one-way analysis of variance. A sampling frequency of 15 h(-1) was achieved. The method was used to monitor cyanate consumption in a cyanate bioremediation tank inoculated with Pseudomonas pseudoalcaligenes CECT 5344 strain. The correlation between cyanate degradation and ammonia production was tested using a conventional method. Finally, the method was applied to different samples collected from the bioremediation tank using the standard addition method; recoveries between 85.9 and 97.4% were obtained.

  16. Flow injection assessment of nitrate contents in fresh and cooked fruits and vegetables grown in Fiji.

    Science.gov (United States)

    Prasad, Surendra; Chetty, Adrian A

    2011-10-01

    Nitrates form part of the essential chemistry of soils and plants. Thus, plant roots are able to absorb nitrate directly from the soil. It has been discovered that human nitrate intake is mainly from vegetables. Vegetables play an important role in human nutrition since they are an outstanding source for vitamins, minerals, and biologically active compounds. In risk assessment of nitrate contents, this study reports the nitrate levels of 8 commonly consumed fruits and vegetables grown in Fiji, tomato (Lycopersicon esculentum), eggplant (Solanum melongena), capsicum (Capsicum annuum var. grossum), breadfruit (Artocarpus altilis), long bean (Vigna sesquipedalis), jackfruit (A. heterophyllus), pumpkin (Cucurbita pepo), and cucumber (Cucumis sativus). The effects of different types of cooking methods, baking, boiling, and frying, have also been studied. The validated flow injection analysis technique has been used to quantify the nitrate-N levels in the chosen products following nitrate extraction using the activated carbon technique. The mean values of nitrate levels in fresh products ranged from 25.83 to 281.02 mg NO(3) (-) kg(-1) . The study shows that boiling reduced nitrate contents by 65.37% to 25.25%. The frying in soy bean oil elevated nitrate contents from 354.79% to 86.69%, but after baking, nitrate contents remained almost constant with slight increasing trend in the case of tomato (19.97%). The nitrate levels published in the literature for the same types of fruits and vegetables studied have also been reviewed and compared. The average nitrate-N values were comparable or lower than overseas data, but did not present unpredictably high values, that is, they were below the risk level. © 2011 Institute of Food Technologists®

  17. Metals, nutrients and total suspended solids discharged during different flow conditions in highly urbanised catchments.

    Science.gov (United States)

    Beck, Hayden J; Birch, Gavin F

    2012-01-01

    Stormwater discharged from highly urbanised catchments on the southern shore of Sydney estuary, Australia, has been identified as the primary source of contaminants responsible for ecological degradation and reduction in recreational value of the waterway. Effective management of this pollution requires knowledge of contaminant loads associated with various stormwater flow conditions in three highly urbanised catchments in Sydney estuary catchment. The majority (>90%) of metal (Cu, Pb and Zn) and total suspended solid annual loads were contributed during high-flow conditions (>50 mm rainfall day(t1)), whereas ≤55% of TN and ≤21% of total phosphorus were contributed to annual loading by dry weather base-flow conditions. All flow conditions posed an in-stream ecological threat because contaminant concentrations exceeded water quality guidelines for all analytes measured, except Pb. Irregular, temporal variability in contaminant concentrations associated with base-flow (within day and amongst days), high-flow (amongst events) and irregular discharges indicated that contaminant contributions in stormwater were strongly controlled by human activity in the three catchments. Significant variation in contaminant concentrations under all flow conditions revealed unique chemical signatures for each catchment despite similarities in land uses, location and geology amongst catchments. These characteristics indicate that assessment and management of stormwater pollution needs to be conducted on an individual-catchment basis for highly urbanised regions of Sydney estuary catchment.

  18. Advanced Multi-Phase Flow CFD Model Development for Solid Rocket Motor Flowfield Analysis

    Science.gov (United States)

    Liaw, Paul; Chen, Y. S.; Shang, H. M.; Doran, Denise

    1993-01-01

    It is known that the simulations of solid rocket motor internal flow field with AL-based propellants require complex multi-phase turbulent flow model. The objective of this study is to develop an advanced particulate multi-phase flow model which includes the effects of particle dynamics, chemical reaction and hot gas flow turbulence. The inclusion of particle agglomeration, particle/gas reaction and mass transfer, particle collision, coalescence and breakup mechanisms in modeling the particle dynamics will allow the proposed model to realistically simulate the flowfield inside a solid rocket motor. The Finite Difference Navier-Stokes numerical code FDNS is used to simulate the steady-state multi-phase particulate flow field for a 3-zone 2-D axisymmetric ASRM model and a 6-zone 3-D ASRM model at launch conditions. The 2-D model includes aft-end cavity and submerged nozzle. The 3-D model represents the whole ASRM geometry, including additional grain port area in the gas cavity and two inhibitors. FDNS is a pressure based finite difference Navier-Stokes flow solver with time-accurate adaptive second-order upwind schemes, standard and extended k-epsilon models with compressibility corrections, multi zone body-fitted formulations, and turbulence particle interaction model. Eulerian/Lagrangian multi-phase solution method is applied for multi-zone mesh. To simulate the chemical reaction, penalty function corrected efficient finite-rate chemistry integration method is used in FDNS. For the AL particle combustion rate, the Hermsen correlation is employed. To simulate the turbulent dispersion of particles, the Gaussian probability distribution with standard deviation equal to (2k/3)(exp 1/2) is used for the random turbulent velocity components. The computational results reveal that the flow field near the juncture of aft-end cavity and the submerged nozzle is very complex. The effects of the turbulent particles affect the flow field significantly and provide better

  19. New Development of Semi-solid Metallic Casting-Injection-Moulding%半固态金属铸造的新进展--注射成形

    Institute of Scientific and Technical Information of China (English)

    樊自田; 黄乃瑜; 罗吉荣; 吴树森

    2001-01-01

    Injection-moulding, the new developing tendency of semi-solid metallic casting, was introduced.The plastic injection moulding principle is applied to semi-solid metallic casting, integrating preparati on and transferring and forming of semi-solid metallic syrup, so as to better overcome the problems,including storage,transfer and control of semi-sol id syrup. The key and developing trend of engineering application of semi-solid metallic casting technology was narrated through briefly describing prin ciple and characteristics of some somi-solid metallic injection moulding ways.%介绍了半固态金属铸造的最新发展趋势--注射成形,它将塑料的注射成形原理应用于半固态金属铸造中,集半固态金属浆料的制备、输送、成 形等过程于一体,较好地解决了半固态金属浆料的保存输送和成形控制等问题。通过简述几 种半固态金属注射成形工艺方法的原理及特点,试图展示半固态金属铸造技术工程应用的关 键及发展方向。

  20. Solids flow diagram of a CFB riser using Geldart B-type powders

    Institute of Scientific and Technical Information of China (English)

    Shiva Mahmoudi; Chian Wen Chan; Anke Brems; Jonathan Seville; Jan Baeyens

    2012-01-01

    Riser operating modes are vital to designing a circulating fluidized bed (CFB) reactor for a required process of either a gas-solid or a gas-catalytic nature.Different operating modes provide different solids' residence times and mixing behaviors,which define the reactions' efficiency and yield.The literature demonstrates distinct operating modes resulting from observed differences in slip factors and the range of particle velocities and their associated residence time distribution.The present research uses positron emission particle tracking (PEPT) in a riser of B-type bed material to determine the different operating modes by measuring (i) particle velocities and residence time distribution,(ii) population densities of these particles in the cross-sectional area of the riser,and (iii) solids flow pattern at the bottom of the riser.Data treatment defines four distinct solids hold-up regimes in the riser and proposes a “phase diagram” depicting the existence of the different operating modes (dilute,dense,core-annulus and combined) as a function of the superficial gas velocity and solids circulation flux in the riser.The delineated regimes have good agreement with available literature data and known industrial operations.Comparison with literature data for risers using A-type powders is also fair.The diagram enables CFB designers to better delineate operating characteristics.

  1. Analysis of Flow Structure and Calculation of Drag Coefficient for Concurrent-up Gas-Solid Flow

    Institute of Scientific and Technical Information of China (English)

    杨宁; 王维; 等

    2003-01-01

    This study investigates the heterogeneous structure and its influence on drag coefficient for concurrent up gas-solid flow.The energy-minimization multi-scale (EMMS) model is modified to simulate the variation of structure parameters with solids concentration,showing the tendency for particles to aggregated to form clusters and for fluid to pass around clusters.The global drag coefficient is resolved into that for the dense phase,for the dilutephase and for the so-called inter-phase,all of which can be obtained from their respective phase-specific structure parameters.The computational results show that the drag coefficients of the different phases are quite different,and the global drag coefficient calculated from the EMMS approach is much lower than that from the correlation of Wen and Yu.The simulation results demonstrate that the EMMS approach can well describe the heterogeneous flow structure,and is very promising for incorporation into the two-fluid model or the discrete particle model as the closure law for drag coefficient.

  2. Investigation of SF6 injection during cyclic C2H2/SF6 flow for the formation of geometrically controlled carbon coils.

    Science.gov (United States)

    Jeon, Young-Chul; Park, Bitna; Park, Semi; Kim, Sung-Hoon

    2014-12-01

    Carbon coils could be synthesized using C2H2/H2 as source gases along with SF6 as an incorporated additive gas using a thermal chemical vapor deposition (CVD) system. To obtain geometrically controlled carbon coils, a cyclic process, namely the turning on and off of C2H2 or SF6 flow during the initial reaction stage, was carried out. According to the different reaction processes, different interruption/injection times of C2H2 or SF6 flow and different injection sequences of the gas flow were investigated while maintaining the identical overall injection time of C2H2 and/or SF6 flow. The formation of carbon microcoils (CMCs) is favored by the lowest interruption/injection time ratio of SF6 flow within one cycle. In addition, the injection of SF6 flow prior to the injection of C2H2 flow promotes the formation of CMCs. Based on these results we revealed the role of the SF6 flow injection for the enhanced formation of geometrically controlled CMCs. The etching of materials, thereby promoting an increase in the number of nucleation sites for the survived growth species to form CMCs, by the increased fluorine concentration, originating from the dominant SF6 influx, is understood to be the main cause for the exclusive CMCs formation.

  3. Short-term effects of intravitreal triamcinolone acetonide injection on ocular blood flow evaluated with color Doppler ultrasonography

    Institute of Scientific and Technical Information of China (English)

    Mustafa; Alpaslan; Anayol; Yasin; Toklu; Elif; Asik; Kamberoglu; Sabri; Raza; Hasan; Basri; Arifoglu; Huseyin; Simavli; Ayse; Gul; Kocak; Altintas; Saban; Simsek

    2014-01-01

    AIM:To evaluate the changes in ocular blood flow with color Doppler ultrasonography(CDU) after intravitreal triamcinolone acetonide(IVTA) injection.METHODS:A total of 46 patients who underwent IVTA(4 mg/0.1 mL) injection for diabetic macular edema(DME)(n =22), central retinal vein occlusion(CRVO)(n =12) and choroidal neovascular membrane(CNVM)(n =12) were included in the study. Peak systolic velocity(PSV), end diastolic velocity(EDV) and resistivity index(RI) were measured from the ophthalmic artery(OA), the central retinal artery(CRA) and the posterior ciliary artery(PCA)of each patient with CDU before, at the end of the first week and at the end of the first month following IVTA injection.RESULTS:In the DME group, PSV of OA at the first of the first month(mean ±SD)(37.48 ±10.87 cm/s) increased compared to pre-injection value(31.39 ±10.84 cm/s)(P =0.048). There was a statistically significant decrease(P =0.049) in PSV of CRA at the end of the first month(7.97±2.67 cm/s) compared to the pre-injection(9.47±3.37 cm/s).There was not any statistically significant difference onthe other parameters in the DME group. Also, there was not any statistically significant difference on the ocular blood flow values in the CRVO and CNVM groups.CONCLUSION:We observed that 4 mg/0.1 mL IVTA increased PSV of OA and decreased PSV of CRA in DME patients and did not have any effect on ocular blood flow values of CRVO and CNVM patients.

  4. Short-term effects of intravitreal triamcinolone acetonide injection on ocular blood flow evaluated with color Doppler ultrasonography

    Directory of Open Access Journals (Sweden)

    Mustafa Alpaslan Anayol

    2014-10-01

    Full Text Available AIM:To evaluate the changes in ocular blood flow with color Doppler ultrasonography (CDU after intravitreal triamcinolone acetonide (IVTA injection.METHODS: A total of 46 patients who underwent IVTA (4 mg/0.1 mL injection for diabetic macular edema (DME (n=22, central retinal vein occlusion (CRVO (n=12 and choroidal neovascular membrane (CNVM (n=12 were included in the study. Peak systolic velocity (PSV, end diastolic velocity (EDV and resistivity index (RI were measured from the ophthalmic artery (OA, the central retinal artery (CRA and the posterior ciliary artery (PCA of each patient with CDU before, at the end of the first week and at the end of the first month following IVTA injection.RESULTS:In the DME group, PSV of OA at the first of the first month (mean±SD (37.48±10.87 cm/s increased compared to pre-injection value (31.39±10.84 cm/s (P=0.048. There was a statistically significant decrease (P=0.049 in PSV of CRA at the end of the first month (7.97±2.67 cm/s compared to the pre-injection (9.47±3.37 cm/s. There was not any statistically significant difference on the other parameters in the DME group. Also, there was not any statistically significant difference on the ocular blood flow values in the CRVO and CNVM groups.CONCLUSION: We observed that 4 mg/0.1 mL IVTA increased PSV of OA and decreased PSV of CRA in DME patients and did not have any effect on ocular blood flow values of CRVO and CNVM patients.

  5. Salt precipitation due to supercritical gas injection: I. Capillary-driven flow in unimodal sandstone

    NARCIS (Netherlands)

    Ott, H.; Roels, S.M.; De Kloe, K.

    2015-01-01

    Drying and salt precipitation in geological formations can have serious consequences for upstream operations in terms of injectivity and productivity. Here we investigate the consequences of supercritical CO2 injection in sandstones. The reported findings are directly relevant for CO2 sequestration

  6. Navier-Stokes analysis of solid propellant rocket motor internal flows

    Science.gov (United States)

    Sabnis, J. S.; Gibeling, H. J.; Mcdonald, H.

    1989-01-01

    A multidimensional implicit Navier-Stokes analysis that uses numerical solution of the ensemble-averaged Navier-Stokes equations in a nonorthogonal, body-fitted, cylindrical coordinate system has been applied to the simulation of the steady mean flow in solid propellant rocket motor chambers. The calculation procedure incorporates a two-equation (k-epsilon) turbulence model and utilizes a consistently split, linearized block-implicit algorithm for numerical solution of the governing equations. The code was validated by comparing computed results with the experimental data obtained in cylindrical-port cold-flow tests. The agreement between the computed and experimentally measured mean axial velocities is excellent. The axial location of transition to turbulent flow predicted by the two-equation (k-epsilon) turbulence model used in the computations also agrees well with the experimental data. Computations performed to simulate the axisymmetric flowfield in the vicinity of the aft field joint in the Space Shuttle solid rocket motor using 14,725 grid points show the presence of a region of reversed axial flow near the downstream edge of the slot.

  7. Navier-Stokes analysis of solid propellant rocket motor internal flows

    Science.gov (United States)

    Sabnis, J. S.; Gibeling, H. J.; Mcdonald, H.

    1989-01-01

    A multidimensional implicit Navier-Stokes analysis that uses numerical solution of the ensemble-averaged Navier-Stokes equations in a nonorthogonal, body-fitted, cylindrical coordinate system has been applied to the simulation of the steady mean flow in solid propellant rocket motor chambers. The calculation procedure incorporates a two-equation (k-epsilon) turbulence model and utilizes a consistently split, linearized block-implicit algorithm for numerical solution of the governing equations. The code was validated by comparing computed results with the experimental data obtained in cylindrical-port cold-flow tests. The agreement between the computed and experimentally measured mean axial velocities is excellent. The axial location of transition to turbulent flow predicted by the two-equation (k-epsilon) turbulence model used in the computations also agrees well with the experimental data. Computations performed to simulate the axisymmetric flowfield in the vicinity of the aft field joint in the Space Shuttle solid rocket motor using 14,725 grid points show the presence of a region of reversed axial flow near the downstream edge of the slot.

  8. Partitioned fluid-solid coupling for cardiovascular blood flow: left-ventricular fluid mechanics.

    Science.gov (United States)

    Krittian, Sebastian; Janoske, Uwe; Oertel, Herbert; Böhlke, Thomas

    2010-04-01

    We present a 3D code-coupling approach which has been specialized towards cardiovascular blood flow. For the first time, the prescribed geometry movement of the cardiovascular flow model KaHMo (Karlsruhe Heart Model) has been replaced by a myocardial composite model. Deformation is driven by fluid forces and myocardial response, i.e., both its contractile and constitutive behavior. Whereas the arbitrary Lagrangian-Eulerian formulation (ALE) of the Navier-Stokes equations is discretized by finite volumes (FVM), the solid mechanical finite elasticity equations are discretized by a finite element (FEM) approach. Taking advantage of specialized numerical solution strategies for non-matching fluid and solid domain meshes, an iterative data-exchange guarantees the interface equilibrium of the underlying governing equations. The focus of this work is on left-ventricular fluid-structure interaction based on patient-specific magnetic resonance imaging datasets. Multi-physical phenomena are described by temporal visualization and characteristic FSI numbers. The results gained show flow patterns that are in good agreement with previous observations. A deeper understanding of cavity deformation, blood flow, and their vital interaction can help to improve surgical treatment and clinical therapy planning.

  9. A Clinical Study on the Effect of Injection Sites on Efficacy of Anesthesia and Pulpal Blood Flow in Carious Teeth.

    Science.gov (United States)

    Zheng, Q H; Hong, Q C; Zhang, L; Ye, L; Huang, D M

    2017-10-04

    This randomized clinical trial evaluated the efficiency of maxillary infiltration anesthesia in carious teeth at two different injection sites and their impact on the laser Doppler recordings of pulpal blood flow (PBF) during a caries excavation procedure. The null hypothesis tested was that there are no differences in the efficiency of anesthesia and PBF reduction between maxillary infiltrations at the two injection sites. One hundred twenty patients were divided into three groups according to the degree of carious lesion of their maxillary left central incisors (moderate caries, deep caries, or no caries). Forty patients in each group randomly received infiltrations over the root apex of maxillary left central incisors (site X) or over the midpoint of the line connecting the root apexes of both maxillary left central and lateral incisors (site Y) using 0.9 mL 2% lidocaine with 1:100,000 adrenaline. Teeth were pulp tested at five-minute intervals after injection except for the period of cavity cutting, which was done 12 minutes after injection. The PBF changes after injection were monitored by laser Doppler flowmetry. The observation period in this study was 60 minutes. Success of anesthesia was defined as no or mild pain on cavity cutting by visual analog scale recordings. Deep caries group showed significantly higher baseline PBF (p0.05). Subgroups that had the injection at site Y showed significantly less reduction of PBF (pcarious anterior teeth anesthetized by infiltration further from the apex had significantly less reduction on the pulpal blood flow compared with teeth anesthetized by infiltration at the apex.

  10. Geological Factors Affecting Flow Spatial Continuity in Water Injection of Units Operating in the LGITJ–0102 Ore Body

    Directory of Open Access Journals (Sweden)

    Ilver M. Soto-Loaiza

    2016-05-01

    Full Text Available The objective of the investigation was to identify the geological factors affecting the spatial continuity of the flow during the process of flank water injection in the units operating in the Lower Lagunilla Hydrocarbon Ore Body. This included the evaluation of the recovery factor, the petro-physic properties such as porosity, permeability, water saturation and rock type and quality in each flow unit. it was observed that the rock type of the geologic structure in the ore body is variable. The lowest values for the petro-physic properties were found in the southern area while a high variability of these parameters was observed in the northern and central areas. It was concluded that the northern area has a great potential for the development of new injection projects for petroleum recovery.

  11. Numerical Simulations of Two-Phase Reacting Flow in a Single-Element Lean Direct Injection (LDI) Combustor Using NCC

    Science.gov (United States)

    Liu, Nan-Suey; Shih, Tsan-Hsing; Wey, C. Thomas

    2011-01-01

    A series of numerical simulations of Jet-A spray reacting flow in a single-element lean direct injection (LDI) combustor have been conducted by using the National Combustion Code (NCC). The simulations have been carried out using the time filtered Navier-Stokes (TFNS) approach ranging from the steady Reynolds-averaged Navier-Stokes (RANS), unsteady RANS (URANS), to the dynamic flow structure simulation (DFS). The sub-grid model employed for turbulent mixing and combustion includes the well-mixed model, the linear eddy mixing (LEM) model, and the filtered mass density function (FDF/PDF) model. The starting condition of the injected liquid spray is specified via empirical droplet size correlation, and a five-species single-step global reduced mechanism is employed for fuel chemistry. All the calculations use the same grid whose resolution is of the RANS type. Comparisons of results from various models are presented.

  12. Electroanalysis of tetracycline using nickel-implanted boron-doped diamond thin film electrode applied to flow injection system.

    Science.gov (United States)

    Treetepvijit, Surudee; Chuanuwatanakul, Suchada; Einaga, Yasuaki; Sato, Rika; Chailapakult, Orawon

    2005-05-01

    The electrochemical analysis of tetracycline was investigated using nickel-implanted boron-doped diamond thin film electrode by cyclic voltammetry and amperometry with a flow injection system. Cyclic voltammetry was used to study the electrochemical oxidation of tetracycline. Comparison experiments were carried out using as-deposited boron-doped diamond thin film electrode (BDD). Nickel-implanted boron-doped diamond thin film electrode (Ni-DIA) provided well-resolved oxidation irreversible cyclic voltammograms. The current signals were higher than those obtained using the as-deposited BDD electrode. Results using nickel-implanted boron-doped diamond thin film electrode in flow injection system coupled with amperometric detection are presented. The optimum potential for tetracycline was 1.55 V versus Ag/AgCl. The linear range of 1.0 to 100 microM and the detection limit of 10 nM were obtained. In addition, the application for drug formulation was also investigated.

  13. A carbon-free lithium-ion solid dispersion redox couple with low viscosity for redox flow batteries

    Science.gov (United States)

    Qi, Zhaoxiang; Koenig, Gary M.

    2016-08-01

    A new type of non-aqueous redox couple without carbon additives for flow batteries is proposed and the target anolyte chemistry is demonstrated. The so-called "Solid Dispersion Redox Couple" incorporates solid electroactive materials dispersed in organic lithium-ion battery electrolyte as its flowing suspension. In this work, a unique and systematic characterization approach has been used to study the flow battery redox couple in half cell demonstrations relative to a lithium electrode. An electrolyte laden with Li4Ti5O12 (LTO) has been characterized in multiple specially designed lithium half cell configurations. The flow battery redox couple described in this report has relatively low viscosity, especially in comparison to other flow batteries with solid active materials. The lack of carbon additive allows characterization of the electrochemical properties of the electroactive material in flow without the complication of conductive additives and unambiguous observation of the electrorheological coupling in these dispersed particle systems.

  14. Flow velocity effect on the corrosion/erosion in water injection systems; Efecto de la velocidad de flujo en la corrosion/erosion en sistemas de inyeccion de agua

    Energy Technology Data Exchange (ETDEWEB)

    Jimenez, C.; Mendez, J. [PDVSA Exploracion y reduccion, Departamento de Ingenieria de Instalaciones, Torres Petroleras EX-MRV, Torre Lama, Piso No. 6, Zulia, Apartado 4013, Venezuela (Venezuela)

    1998-12-31

    The main causes of fails at water injection lines on the secondary petroleum recovery systems are related with corrosion/erosion problems which are influenced by the flow velocity, the presence of dissolved oxygen, solids in the medium and the microorganisms proliferation. So too, this corrosion process promotes the suspended solids generation which affects the water quality injected, causing wells tamponage and loss of injectivity, with the consequent decrease in the crude production. This situation has been impacted in meaning order at the production processes of an exploration enterprise which utilizes the Maracaibo lake as water resource for their injection by pattern projects. Stating that, it was developed a study for determining in experimental order the effect of flow velocity on the corrosion/erosion process joined to the presence of dissolved oxygen which allows to determine the optimum range of the said working velocity for the water injection systems. This range is defined by critical velocities of bio layers deposition and erosion. They were realized simulation pilot tests of the corrosion standard variables, concentration of dissolved oxygen and fluid velocity in the injection systems with filtered and non filtered water. For the development of these tests it was constructed a device which allows to install and expose cylindrical manometers of carbon steel according to predetermined conditions which was obtained the necessary information to make correlations the results of these variables. Additionally, they were determined the mathematical models that adjusts to dynamical behavior of the corrosion/erosion process, finding the optimum range of the flow velocity for the control of this process, being necessary to utilize the following techniques: Scanning Electron Microscopy (SEM), X-ray dispersion analysis (EDX) for encourage the surface studies. They were effected morphological analysis of the surfaces studies and the values were determined of

  15. Comparison of lead dioxide and cerium dioxide as mediators for carbon paste electrodes in flow injection-amperometric detection of hydrogen peroxide

    OpenAIRE

    Mihić-Necin, Bojana; Guzsvány, Valéria; Kalcher, Kurt

    2010-01-01

    Carbon paste electrodes (graphite / paraffin oil), bulk-modified with lead dioxide and cerium dioxide, were used as sensors for the amperometric determination of hydrogen peroxide in flow injection analysis. Experimental parameters, such as applied working potential, flow rate of the carrier and injection volume were optimized with a thin-layer flow-through cell. The method was validated with respect to calibration curve, linear dynamic range, detection limit, repeatability and...

  16. Urinary bladder blood flow. I. Comparison of clearance of locally injected 99mtechnetium pertechnate and radioactive microsphere technique in dogs

    DEFF Research Database (Denmark)

    Krøyer, Kristian; Bülow, J; Nielsen, S L

    1990-01-01

    The blood flow of the dog urinary bladder measured by radioactive microsphere technique was compared to the clearance of locally injected 99mTechnetium pertechnate (99mTc) in the bladder wall. In semilogarithmic plots the 99mTc washout curves showed a multiexponential course. From the initial...... slopes (median 5.7 min) the bladder blood flow was calculated to be only 30-62% of the results obtained from the radioactive microsphere technique (blood flow in the muscular layer 21.7-44.8 ml/100 g/min). These lower values imply that the rate of removal of the hydrophilic tracer 99mTc at these flow...

  17. A numerical study of cavitating flows in high-pressure diesel injection nozzle holes using a two-fluid model

    Institute of Scientific and Technical Information of China (English)

    WANG Xiang; SU WanHua

    2009-01-01

    Cavitating flows inside a diesel injection nozzle hole were simulated using a two-fluid model. Attention was focused on the complex cavitation processes and flow characteristics under constant inlet pres-sure and fluctuant inlet pressure modes. To validate the two-fluid model, model predictions were compared with the experimental data available in the literatures, and good agreement was achieved. The numerical results show that the appearance of supercavitation in the diesel nozzle hole induces obvious changes of flow field structures and exit flow conditions, The distributions of liquid phase turbulent kinetic energy and exit velocity profiles corresponding to the supercavitation regime indicate the potential for promoting the primary breakup of a diesel jet. Furthermore, the upstream pressure fluctuations significantly influence the cavitation processes. Both partial cavitation and supercavitation show unsteady behaviors as the rapid rise or fall of upstream pressure.

  18. Flow injection conductometric system with gas diffusion separation for the determination of Kjeldahl nitrogen in milk and chicken meat.

    Science.gov (United States)

    Junsomboon, Jaroon; Jakmunee, Jaroon

    2008-10-10

    A simple flow injection (FI) conductometric system with gas diffusion separation was developed for the determination of Kjeldahl nitrogen (or proteins) in milk and chicken meat. The sample was digested according to the Kjeldahl standard method and the digest was diluted and directly injected into the donor stream consisting of 4M NaOH. In alkaline medium, ammonium was converted to ammonia, which diffused through the PTFE membrane to dissolve in an acceptor stream (water). Dissociation of ammonia caused a change in conductance of the acceptor solution, which was linearly proportional to the concentration of ammonium originally present in the injected solution. A conductometric flow through cell and an amplifier circuit was fabricated, which helped improve sensitivity of the conductometric detection system. With using a plumbing Teflon tape as a gas diffusion membrane and without thermostating control of the system, a linear calibration graph in range of 10-100mgL(-1) N-NH(4) was obtained, with detection limit of 1mgL(-1) and good precision (relative standard deviation of 0.3% for 11 replicate injections of 50mgL(-1) N-NH(4)). The developed method was validated by the standard Kjeldahl distillation/titration method for the analysis of milk and chicken meat samples. The proposed system had sample throughput of 35h(-1) and consumed much smaller amounts of chemical than the standard method (275mg vs 17.5g of NaOH per analysis, respectively).

  19. Linear stability analysis of fluid flow between two parallel porous stationary plates with small suction and injection

    CERN Document Server

    Hinvi, L A; Orou, J B Chabi

    2013-01-01

    In this work, the linear stability of the viscous incompressible fluid flow between two parallel horizontal porous stationary plates with the assumption that there is a small constant suction at upper plate and a small constant injection at the lower plate is studied.The Navier-Stokes and continuous equations are reduced to an equation modified by the suction Reynolds number, which we call modified Orr-Sommerfeld equation. This equation is rewritten as an eigenvalue problem and is solved numerically using Matlab (Windows Version). The effect of small suction Reynolds number on the linear stability fluid flow is discussed.

  20. Feedback-amplified electrochemical dual-plate boron-doped diamond microtrench detector for flow injection analysis

    Science.gov (United States)

    Lewis, Grace E M; Gross, Andrew J; Kasprzyk-Hordern, Barbara; Lubben, Anneke T; Marken, Frank

    2015-01-01

    An electrochemical flow cell with a boron-doped diamond dual-plate microtrench electrode has been developed and demonstrated for hydroquinone flow injection electroanalysis in phosphate buffer pH 7. Using the electrochemical generator-collector feedback detector improves the sensitivity by one order of magnitude (when compared to a single working electrode detector). The diffusion process is switched from an analyte consuming “external” process to an analyte regenerating “internal” process with benefits in selectivity and sensitivity. PMID:25735831

  1. Investigation on Dynamic Calibration for an Optical-Fiber Solids Concentration Probe in Gas-Solid Two-Phase Flows

    OpenAIRE

    Changsui Zhao; Liu Shen; Pan Xu; Xiaoping Chen; Daoyin Liu; Cai Liang; Guiling Xu

    2013-01-01

    This paper presents a review and analysis of the research that has been carried out on dynamic calibration for optical-fiber solids concentration probes. An introduction to the optical-fiber solids concentration probe was given. Different calibration methods of optical-fiber solids concentration probes reported in the literature were reviewed. In addition, a reflection-type optical-fiber solids concentration probe was uniquely calibrated at nearly full range of the solids concentration from 0...

  2. Phase field modeling and simulation of three-phase flow on solid surfaces

    Science.gov (United States)

    Zhang, Qian; Wang, Xiao-Ping

    2016-08-01

    Phase field models are widely used to describe the two-phase system. The evolution of the phase field variables is usually driven by the gradient flow of a total free energy functional. The generalization of the approach to an N phase (N ≥ 3) system requires some extra consistency conditions on the free energy functional in order for the model to give physically relevant results. A projection approach is proposed for the derivation of a consistent free energy functional for the three-phase Cahn-Hilliard equations. The system is then coupled with the Navier-Stokes equations to describe the three-phase flow on solid surfaces with moving contact line. An energy stable scheme is developed for the three-phase flow system. The discrete energy law of the numerical scheme is proved which ensures the stability of the scheme. We also show some numerical results for the dynamics of triple junctions and four phase contact lines.

  3. Forecasting models for flow and total dissolved solids in Karoun river-Iran

    Science.gov (United States)

    Salmani, Mohammad Hassan; Salmani Jajaei, Efat

    2016-04-01

    Water quality is one of the most important factors contributing to a healthy life. From the water quality management point of view, TDS (total dissolved solids) is the most important factor and many water developing plans have been implemented in recognition of this factor. However, these plans have not been perfect and very successful in overcoming the poor water quality problem, so there are a good volume of related studies in the literature. We study TDS and the water flow of the Karoun river in southwest Iran. We collected the necessary time series data from the Harmaleh station located in the river. We present two Univariate Seasonal Autoregressive Integrated Movement Average (ARIMA) models to forecast TDS and water flow in this river. Then, we build up a Transfer Function (TF) model to formulate the TDS as a function of water flow volume. A performance comparison between the Seasonal ARIMA and the TF models are presented.

  4. Cavitating flow control through continuous tangential mass injection on a 2D hydrofoil at a small attack angle

    Directory of Open Access Journals (Sweden)

    Timoshevskiy Mikhail V.

    2016-01-01

    Full Text Available We studied cavitating flow over the suction side of a symmetric 2D foil – a scaled-down model of high-pressure hydroturbine guide vanes (GV – in different cavitation regimes at the attack angle of 3°. High-speed imaging was used to analyze spatial patterns and time dynamics of the gas-vapour cavities. A hydroacoustic pressure transducer was employed to register time-spectra of pressure fluctuations nearby the hydrofoil. A PIV technique was applied to measure the velocity fields and its fluctuations. The active flow control was implemented by means of a continuous liquid supply with different flow rates through a slot channel located in the GV surface. It was found that the active mass injection does not influence the primary flow upstream of the slot channel position. For the cavitation-free and cavitation inception cases, the injection was shown to make the turbulent wake past the GV section more intense. However, at the developed cavitation regimes the active flow management made it possible to reduce substantially the amplitude or even totally suppress the periodic cavity length oscillations and pressure pulsations associated with them.

  5. Flow injection spectrophotometry coupled with a crushed barium sulfate reactor column for the determination of sulfate ion in water samples

    OpenAIRE

    Burakham,Rodjana; Higuchi, Keiro; Oshima, Mitsuko; Grudpan, Kate; Motomizu, Shoji

    2004-01-01

    A new type of a reactor column, a crushed BaSO4 reactor column used for the flow injection spectrophotometric determination of sulfate ion using the exchange reaction of sulfate ion and barium-dimethylsulfonazo III is proposed. The column is very simple and economical. It can be continuously used for 8 h before washing with water for repeated usage of at least 1 month. The procedure is sensitive. Application to various water samples was demonstrated.

  6. Preconcentration and determination of trace silver ion using benzothiazole calix[4]arene modified silica by flow injection flame atomic absorption spectrometry.

    Science.gov (United States)

    Waluvanaruk, Jitwilai; Aeungmaitrepirom, Wanlapa; Tuntulani, Thawatchai; Ngamukot, Passapol

    2014-01-01

    The silica gel modified with benzothiazole calix[4]arene (APS-L1) via Schiff's base reaction was applied as a sorbent in an online system for preconcentration and determination of silver ion by flame atomic absorption spectrometry (FAAS). APS-L1 was used as an effective sorbent for solid phase extraction (SPE) of silver(I) ion in both batch and column methods. The optimum experimental parameters such as pH, eluent type, sample flow rate, eluent volume and eluent flow rate including the effect of interfering ions were investigated. Silver(I) ion was determined at pH 6-7. The capacity of APS-L1 sorbent was found to be 12.2 mg/g of sorbent. The high affinity was obtained without interference from the interfering ions. The optimum conditions of the online flow injection preconcentration coupled with the FAAS (FI-FAAS system) were evaluated. The sample flow rate was 3.0 mL min(-1) using sample volume of 5-10 mL. Elution was performed with 250 μL of 0.1 mol L(-1) thiosulfate at the flow rate of 1.5 mL min(-1). The analytical characteristics and performance of the FI-FAAS system were studied under optimum conditions using a solution spiked with standard silver(I) ion at 20 and 50 μg L(-1). The detection limit of 0.44 μg L(-1) was obtained. The accuracy of the proposed method was evaluated and percentages of recovery at 20 and 50 μg L(-1) were 100.2 and 99.5%, respectively. The percent relative standard deviations (%RSD) at 20 and 50 μg L(-1) were 6.1 and 3.3%, respectively. The developed method was successfully applied to determine trace silver(I) ion in drinking and tap water samples.

  7. MIXED CONVECTION BOUNDARY LAYER FLOW ON A VERTICAL SURFACE IN A POROUS MEDIUM SATURATED BY A NANOFLUID WITH SUCTION OR INJECTION

    Directory of Open Access Journals (Sweden)

    M. H.M. Yasin

    2013-01-01

    Full Text Available An analysis of the steady mixed convection boundary layer flow past a vertical permeable surface embedded in a porous medium saturated by a nanofluid is performed in this study. Numerical solutions of the similarity equations are obtained using the shooting method. Three types of metallic or nonmetallic nanoparticles, namely Copper (Cu, Alumina (Al2O3 and Titania (TiO2 are considered by using a water-based fluid to investigate the effect of the solid volume fraction or nanoparticle volume fraction parameter φ of the nanofluid. The numerical results of the skin friction coefficient and the velocity profiles are presented and discussed. It is found that the imposition of suction is to increase the velocity profiles and to delay the separation of boundary layer, while the injection parameter decreases the velocity profiles. On the other hand, the range of solutions for the injection case is largest for Al2O3 nanoparticles and smallest for Cu nanoparticles.

  8. Internal Flow Analysis of Large L/D Solid Rocket Motors

    Science.gov (United States)

    Laubacher, Brian A.

    2000-01-01

    Traditionally, Solid Rocket Motor (SRM) internal ballistic performance has been analyzed and predicted with either zero-dimensional (volume filling) codes or one-dimensional ballistics codes. One dimensional simulation of SRM performance is only necessary for ignition modeling, or for motors that have large length to port diameter ratios which exhibit an axial "pressure drop" during the early burn times. This type of prediction works quite well for many types of motors, however, when motor aspect ratios get large, and port to throat ratios get closer to one, two dimensional effects can become significant. The initial propellant grain configuration for the Space Shuttle Reusable Solid Rocket Motor (RSRM) was analyzed with 2-D, steady, axi-symmetric computational fluid dynamics (CFD). The results of the CFD analysis show that the steady-state performance prediction at the initial burn geometry, in general, agrees well with 1-D transient prediction results at an early time, however, significant features of the 2-D flow are captured with the CFD results that would otherwise go unnoticed. Capturing these subtle differences gives a greater confidence to modeling accuracy, and additional insight with which to model secondary internal flow effects like erosive burning. Detailed analysis of the 2-D flowfield has led to the discovery of its hidden 1-D isentropic behavior, and provided the means for a thorough and simplified understanding of internal solid rocket motor flow. Performance parameters such as nozzle stagnation pressure, static pressure drop, characteristic velocity, thrust and specific impulse are discussed in detail and compared for different modeling and prediction methods. The predicted performance using both the 1-D codes and the CFD results are compared with measured data obtained from static tests of the RSRM. The differences and limitations of predictions using ID and 2-D flow fields are discussed and some suggestions for the design of large L/D motors and

  9. Vortex Matter in Highly Strained Nb_{75}Zr_{25}: Analogy with Viscous Flow of Disordered Solids

    Science.gov (United States)

    Chandra, Jagdish; Manekar, Meghmalhar; Sharma, V. K.; Mondal, Puspen; Tiwari, Pragya; Roy, S. B.

    2017-01-01

    We present the results of magnetization and magneto-transport measurements in the superconducting state of an as-cast Nb_{75}Zr_{25} alloy. We also report the microstructure of our sample at various length scales by using optical, scanning electron and transmission electron microscopies. The information of microstructure is used to understand the flux pinning properties in the superconducting state within the framework of collective pinning. The magneto-transport measurements show a non-Arrhenius behaviour of the temperature- and field-dependent resistivity across the resistive transition and is understood in terms of a model for viscous flow of disordered solids which is popularly known as the `shoving model'. The activation energy for flux flow is assumed to be mainly the elastic energy stored in the flux-line lattice. The scaling of pinning force density indicates the presence of two pinning mechanisms of different origins. The elastic constants of the flux-line lattice are used to estimate the length scale of vortex lattice movement, or the volume displaced by the flux-line lattice. It appears that the vortex lattice displacement estimated from elastic energy considerations is of the same order of magnitude as that of the flux bundle hopping length during flux flow. Our results could provide possible directions for establishing a framework where vortex matter and glass-forming liquids or amorphous solids can be treated in a similar manner for understanding the phenomenon of viscous flow in disordered solids or more generally the pinning and depinning properties of elastic manifolds in random media. It is likely that the vortex molasses scenario is more suited to explain the vortex dynamics in conventional low-T_C superconductors.

  10. Design configurations affecting flow pattern and solids accumulation in horizontal free water and subsurface flow constructed wetlands.

    Science.gov (United States)

    Pedescoll, A; Sidrach-Cardona, R; Sánchez, J C; Carretero, J; Garfi, M; Bécares, E

    2013-03-01

    The aim of this study was to evaluate the effect of different horizontal constructed wetland (CW) design parameters on solids distribution, loss of hydraulic conductivity over time and hydraulic behaviour, in order to assess clogging processes in wetlands. For this purpose, an experimental plant with eight CWs was built at mesocosm scale. Each CW presented a different design characteristic, and the most common CW configurations were all represented: free water surface flow (FWS) with different effluent pipe locations, FWS with floating macrophytes and subsurface flow (SSF), and the presence of plants and specific species (Typha angustifolia and Phragmites australis) was also considered. The loss of the hydraulic conductivity of gravel was greatly influenced by the presence of plants and organic load (representing a loss of 20% and c.a. 10% in planted wetlands and an overloaded system, respectively). Cattail seems to have a greater effect on the development of clogging since its below-ground biomass weighed twice as much as that of common reed. Hydraulic behaviour was greatly influenced by the presence of a gravel matrix and the outlet pipe position. In strict SSF CW, the water was forced to cross the gravel and tended to flow diagonally from the top inlet to the bottom outlet (where the inlet and outlet pipes were located). However, when FWS was considered, water preferentially flowed above the gravel, thus losing half the effective volume of the system. Only the presence of plants seemed to help the water flow partially within the gravel matrix. Copyright © 2012 Elsevier Ltd. All rights reserved.

  11. A two-phase solid/fluid model for dense granular flows including dilatancy effects

    Science.gov (United States)

    Mangeney, Anne; Bouchut, Francois; Fernandez-Nieto, Enrique; Koné, El-Hadj; Narbona-Reina, Gladys

    2016-04-01

    Describing grain/fluid interaction in debris flows models is still an open and challenging issue with key impact on hazard assessment [{Iverson et al.}, 2010]. We present here a two-phase two-thin-layer model for fluidized debris flows that takes into account dilatancy effects. It describes the velocity of both the solid and the fluid phases, the compression/dilatation of the granular media and its interaction with the pore fluid pressure [{Bouchut et al.}, 2016]. The model is derived from a 3D two-phase model proposed by {Jackson} [2000] based on the 4 equations of mass and momentum conservation within the two phases. This system has 5 unknowns: the solid and fluid velocities, the solid and fluid pressures and the solid volume fraction. As a result, an additional equation inside the mixture is necessary to close the system. Surprisingly, this issue is inadequately accounted for in the models that have been developed on the basis of Jackson's work [{Bouchut et al.}, 2015]. In particular, {Pitman and Le} [2005] replaced this closure simply by imposing an extra boundary condition at the surface of the flow. When making a shallow expansion, this condition can be considered as a closure condition. However, the corresponding model cannot account for a dissipative energy balance. We propose here an approach to correctly deal with the thermodynamics of Jackson's model by closing the mixture equations by a weak compressibility relation following {Roux and Radjai} [1998]. This relation implies that the occurrence of dilation or contraction of the granular material in the model depends on whether the solid volume fraction is respectively higher or lower than a critical value. When dilation occurs, the fluid is sucked into the granular material, the pore pressure decreases and the friction force on the granular phase increases. On the contrary, in the case of contraction, the fluid is expelled from the mixture, the pore pressure increases and the friction force diminishes. To

  12. Numerical simulation of gas-liquid-solid flows using a combined front tracking and discrete particle method

    NARCIS (Netherlands)

    Sint Annaland, van M.; Deen, N.G.; Kuipers, J.A.M.

    2005-01-01

    In this paper a hybrid model is presented for the numerical simulation of gas¿liquid¿solid flows using a combined front tracking (FT) and discrete particle (DP) approach applied for, respectively, dispersed gas bubbles and solid particles present in the continuous liquid phase. The hard sphere DP mo

  13. Study on the luminescence behavior of lanthanide ions with luminol by flow injection chemiluminescence analysis

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Xiaoqing [College of Chemistry and Material Science, Northwest University, 710069 Xi' an (China); Wang, Zhuming [College of Earth Sciences and Land Resources, Chang' an University, 710054 Xi' an (China); Li, Yajuan [College of Chemistry and Material Science, Northwest University, 710069 Xi' an (China); Zhang, Yun [Department of pharmacy, Xi' an Medical University, 710021 Xi' an (China); Guo, Jie; Zhao, Jingchan [College of Chemistry and Material Science, Northwest University, 710069 Xi' an (China); Song, Zhenghua, E-mail: songzhenghua@hotmail.com [College of Chemistry and Material Science, Northwest University, 710069 Xi' an (China)

    2015-06-15

    This work first described the linear quenching of Ln{sup III} (including La{sup III}, Ce{sup III}, Pr{sup III}, Nd{sup III}, Sm{sup III}, Eu{sup III}, Gd{sup III}, Tb{sup III}, Dy{sup III}, Ho{sup III}, Er{sup III}, Tm{sup III}, Yb{sup III} and Lu{sup III}) on luminol–dissolved oxygen chemiluminescence system and possible quenching mechanism by flow injection analysis. The general equation of the decrement of CL intensity with Ln{sup III} concentration, ΔI=AlnC{sub Ln}+B, was given and the interaction model of Ln{sup III} with luminol, lg[(I{sub 0}−I)/I]=rlg[Ln]+lgK, was established. The sensitive factor A was found to be linear with the physical parameters (Z, γ{sub ±}, E{sup o} and ΔH{sub hyd}). By plotting A against Z, it could be seen light lanthanides (LL) and heavy lanthanides (HL) presented a good symmetry. The results showed that the reaction of Ln{sup III} with luminol was a spontaneous process by the electrostatic force with the association constants K at 10{sup 6}–10{sup 7} level. The binding constants K{sub D} (about 10{sup 4}–10{sup 5}) and the number of binding sites n (about 1) of Ln{sup III} (La{sup III}, Eu{sup III}, Gd{sup III}, Tb{sup III} and Lu{sup III}) to bovine serum albumin were first given by FI–CL, and the binding ability of Ln{sup III} followed the pattern: La{sup III}

  14. Investigation into the Flow Properties of Coarse Solid Fuels for Use in Industrial Feed Systems

    Directory of Open Access Journals (Sweden)

    James M. Craven

    2015-01-01

    Full Text Available Material feeding and handling systems have been cited as one of the most common causes of process downtime where thermochemical conversion processes are concerned. New and emerging fuels come in a variety of forms, and if such fuels are to be deployed widely it is imperative that material feeding and handling systems are designed appropriately. This study proposes an approach for designing material feeding and handling systems for use with coarse solid fuels. The data obtained from this study indicates particle size to be one of the key issues affecting the flowability of bulk solids further to the uniformity in particle shape. Coarse bulk solid samples were shown to flow more freely than their milled and pulverised counterparts, generating higher degrees of flowability. The results from this study were also applied to a new feed system used for feeding solid fuels to high pressure processes named the Hydraulic Lock Hopper. In this study the Hydraulic Lock Hopper demonstrated the feeding of wood pellets, torrefied spruce pellets, and ground anthracite coal grains against a pressure of 25 barg in two modes of operation. Energy savings compared to conventional lock hopper systems were recorded in the region of 80%.

  15. Dense Pellicular Agarose-Glass Beads for Expanded Bed Application: Flow Hydrodynamics and Solid Phase Classifications

    Institute of Scientific and Technical Information of China (English)

    周鑫; 史清洪; 白姝; 孙彦

    2004-01-01

    Two dense pellicular agarose-glass matrices of different sizes and densities, i.e., AG-S and AG-L, have been characterized for their bed expansion behavior, flow hydrodynamics and particle classifications in an expanded bed system. A 26 mm ID column with side ports was used for sampling the liquid-solid suspension during expanded bed operations. Measurements of the collected solid phase at different column positions yielded the particle size and density distribution data. It was found that the composite matrices showed particle size as well as density classifications along the column axis, i.e., both the size and density of each matrix decreased with increasing the axial bed height. Their axial classifications were expressed by a correlation related to both the particle size and density as a function of the dimensionless axial bed height. The correlation was found to fairly describe the solid phase classifications in the expanded bed system. Moreover, it can also be applied to other two commercial solid matrices designed for expanded bed applications.

  16. Flow visualization and simulation of the filling process during injection molding

    DEFF Research Database (Denmark)

    Guerrier, Patrick; Tosello, Guido; Hattel, Jesper Henri

    2017-01-01

    To directly compare experimental moldings from an injection molding machine with simulations, a special mold has been produced with a glass window. The injection plane is perpendicular to the opening and closing planes, in order for the 55. mm thick glass window to be easily visible from the side......, namely ABS and a high viscosity PC. Simulations were performed using the actual machine data as input, including the injection screw acceleration. Furthermore, the nozzle and barrel geometries were included as a hot runner to capture the effect of compressibility of the material in front of the screw....... These two had significant effects on the filling times and injection pressure calculated by the simulations. Other effects investigated included transient thermal management of the mold, pressure dependent viscosity and wall slip, but their effect were not remarkably large in this work. The obtained...

  17. Bifurcation Behaviour in the Reverse-Flow Boundary Layer with Special Injection or Suction

    Institute of Scientific and Technical Information of China (English)

    ZHENG Lian-Cun; ZHANG Xin-Xin; HE Ji-Cheng

    2003-01-01

    Bifurcation solutions are numerically presented for reverse Bow boundary layer equations with special suction/injection by utilizing similarity transformation and shooting technique. The results indicate that both superior solution and inferior solution are noticeable. The skin friction and shear stress for the superior solution decrease with the increases of the ratio of surface velocity to free stream velocity and suction/injection. The behaviour is opposite to that for the inferior solution. Both the skin frictions for the superior and inferior solutions decrease with increasing the power law parameter. The inferior solution approaches the superior solution with increasing the velocity ratio and suction/injection. When power law is unit and suction/injection is zero, the superior solution approaches the classical Blasius solution as the velocity ratio approaches zero.

  18. Development of a flow method for the determination of phosphate in estuarine and freshwaters-Comparison of flow cells in spectrophotometric sequential injection analysis

    Energy Technology Data Exchange (ETDEWEB)

    Mesquita, Raquel B.R. [CBQF/Escola Superior de Biotecnologia, Universidade Catolica Portuguesa, R. Dr. Antonio Bernardino de Almeida, 4200-072 Porto (Portugal); Laboratory of Hydrobiology, Institute of Biomedical Sciences Abel Salazar (ICBAS) and Institute of Marine Research (CIIMAR), Universidade do Porto, Lg. Abel Salazar 2, 4099-003 Porto (Portugal); Ferreira, M. Teresa S.O.B. [CBQF/Escola Superior de Biotecnologia, Universidade Catolica Portuguesa, R. Dr. Antonio Bernardino de Almeida, 4200-072 Porto (Portugal); Toth, Ildiko V. [REQUIMTE, Departamento de Quimica, Faculdade de Farmacia, Universidade de Porto, Rua Anibal Cunha, 164, 4050-047 Porto (Portugal); Bordalo, Adriano A. [Laboratory of Hydrobiology, Institute of Biomedical Sciences Abel Salazar (ICBAS) and Institute of Marine Research (CIIMAR), Universidade do Porto, Lg. Abel Salazar 2, 4099-003 Porto (Portugal); McKelvie, Ian D. [School of Chemistry, University of Melbourne, Victoria 3010 (Australia); Rangel, Antonio O.S.S., E-mail: aorangel@esb.ucp.pt [CBQF/Escola Superior de Biotecnologia, Universidade Catolica Portuguesa, R. Dr. Antonio Bernardino de Almeida, 4200-072 Porto (Portugal)

    2011-09-02

    Highlights: {yields} Sequential injection determination of phosphate in estuarine and freshwaters. {yields} Alternative spectrophotometric flow cells are compared. {yields} Minimization of schlieren effect was assessed. {yields} Proposed method can cope with wide salinity ranges. {yields} Multi-reflective cell shows clear advantages. - Abstract: A sequential injection system with dual analytical line was developed and applied in the comparison of two different detection systems viz; a conventional spectrophotometer with a commercial flow cell, and a multi-reflective flow cell coupled with a photometric detector under the same experimental conditions. The study was based on the spectrophotometric determination of phosphate using the molybdenum-blue chemistry. The two alternative flow cells were compared in terms of their response to variation of sample salinity, susceptibility to interferences and to refractive index changes. The developed method was applied to the determination of phosphate in natural waters (estuarine, river, well and ground waters). The achieved detection limit (0.007 {mu}M PO{sub 4}{sup 3-}) is consistent with the requirement of the target water samples, and a wide quantification range (0.024-9.5 {mu}M) was achieved using both detection systems.

  19. Magnetohydrodynamics effect on three-dimensional viscous incompressible flow between two horizontal parallel porous plates and heat transfer with periodic injection/suction

    Directory of Open Access Journals (Sweden)

    R. C. Chaudhary

    2004-11-01

    Full Text Available We investigate the hydromagnetic effect on viscous incompressible flow between two horizontal parallel porous flat plates with transverse sinusoidal injection of the fluid at the stationary plate and its corresponding removal by periodic suction through the plate in uniform motion. The flow becomes three dimensional due to this injection/suction velocity. Approximate solutions are obtained for the flow field, the pressure, the skin-friction, the temperature field, and the rate of heat transfer. The dependence of solution on M (Hartmann number and λ (injection/suction is investigated by the graphs and tables.

  20. Numerical Study on the Flow Length in an Injection Molding Process with an External Air-Heating Step

    Directory of Open Access Journals (Sweden)

    Thanh Trung Do

    2017-04-01

    Full Text Available In this study, an external gas-assisted mold temperature control combined with water cooling was applied to achieve rapid mold-surface temperature control for observing the melt flow length in the thin-wall injection molding process. Variable part-thickness values of 0.2 mm, 0.4 mm, and 0.6 mm were used. Through a simulation and experiment, the injection molding process was achieved by using ABS and stamp insert temperatures ranging from 30 to 150 °C. In the simulation, when the stamp temperature was raised from 90 to 150 °C with part thickness of 0.2 mm, 0.4 mm, and 0.6 mm, the melt flow length increased by approximately 25.0%, 19.6%, and 12.8%, respectively. When the stamp temperature was higher than the glass-transition temperature of ABS, the improvement in the melt flow length was clearer, especially in the thinner part. In the experiment, the positive effect of stamp temperature was demonstrated; however, the improvement in the melt flow length was slightly different compared with the simulation owing to the heat transfer between the hot stamp and the environment.

  1. A study of solid particle flow characterization in solar particle receiver

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Kibum [Mechanical Engineering Department, Hanyang University, 1271 Sa-3 dong, Sangnok-gu, Ansan, Kyeonggi-do, 426-791 (Korea); Siegel, Nathan; Kolb, Greg [Sandia National Laboratories Solar Technologies Department, P.O. Box 5800, Albuquerque, NM 87185-1127 (United States); Rangaswamy, Vijayarangan; Moujaes, Samir F [Mechanical Engineering Department, University of Nevada Las Vegas, 4505 Maryland Pkwy Las Vegas, NV 89154-4027 (United States)

    2009-10-15

    The solid particle receiver (SPR) is a direct absorption receiver in which solar energy heats a curtain of falling ceramic particle to a temperature in excess of 1000 C. A small scale test platform was built to investigate particle flow properties. The curtain was comprised of approximately 697 {mu}m ceramic particles that were dropped within the receiver cavity of the test platform. Tests were conducted to experimentally determine the distribution of particles velocity, curtain thickness, and curtain opacity along a drop length of approximately 3 m. Velocity data were measured using a high speed digital camera to obtain images of the particle flow at 1000 frames per second with an exposure time of 100 {mu}s. Five mass flow rates ranging from 1 kg/s-m to 22 kg/s-m were examined, and it was found that all flows approached a terminal velocity of about 6-7 m/s in a vertical drop distance of 3 m. The experimental results were validated with computational results and were found in excellent agreement with the simulation results. In addition, a similar study was performed with various sizes of the particles to better understand how the particle flow characteristics were affected by the size of the particles. (author)

  2. Mathematical Model of Two Phase Flow in Natural Draft Wet-Cooling Tower Including Flue Gas Injection

    Directory of Open Access Journals (Sweden)

    Hyhlík Tomáš

    2016-01-01

    Full Text Available The previously developed model of natural draft wet-cooling tower flow, heat and mass transfer is extended to be able to take into account the flow of supersaturated moist air. The two phase flow model is based on void fraction of gas phase which is included in the governing equations. Homogeneous equilibrium model, where the two phases are well mixed and have the same velocity, is used. The effect of flue gas injection is included into the developed mathematical model by using source terms in governing equations and by using momentum flux coefficient and kinetic energy flux coefficient. Heat and mass transfer in the fill zone is described by the system of ordinary differential equations, where the mass transfer is represented by measured fill Merkel number and heat transfer is calculated using prescribed Lewis factor.

  3. Determination of free and total sulfites in wine using an automatic flow injection analysis system with voltammetric detection.

    Science.gov (United States)

    Goncalves, Luis Moreira; Grosso Pacheco, Joao; Jorge Magalhaes, Paulo; Antonio Rodrigues, Jose; Araujo Barros, Aquiles

    2010-02-01

    An automated flow injection analysis (FIA) system, based on an initial analyte separation by gas-diffusion and subsequent determination by square-wave voltammetry (SWV) in a flow cell, was developed for the determination of total and free sulfur dioxide (SO(2)) in wine. The proposed method was compared with two iodometric methodologies (the Ripper method and a simplified method commonly used by the wine industry). The developed method displayed good repeatability (RSD lower than 6%) and linearity (between 10 and 250 mg l(-1)) as well as a suitable LOD (3 mg l(-1)) and LOQ (9 mg l(-1)). A major advantage of this system is that SO(2) is directly detected by flow SWV.

  4. Study on the Flow Injection Micro-Column Pre-Separation System Coupled With High Performance Liquid Chromatography for the Determination of Ecdysterone in Traditional Chinese Medicine

    Institute of Scientific and Technical Information of China (English)

    2000-01-01

    A flow injection (FI) micro-column system coupled with high performance liquid chromatography (HPLC) was proposed for the pre-separation and determination of active organic component (ecdysterone) in traditional Chinese medicine, Loulu. The factors influencing separation performance were investigated and optimized. Under the optimal conditions, the contents of ecdysterone in Loulu were determined by HPLC system using MeOH-H20 (40 : 60,V/V) as the mobile phase at a flow rate of 1.0 mL/min. The calibration curve was linear in the range of 0. 5~100 mg/L of ecdysterone concentrations. The detection limit of the analyte was 0. 11 μmoi/L(3σ) with a precision of 0. 38% RSD (n=7, c=10. 0 mg/L). The average recovery of the method was 98.7%. The proposed method has been applied to determine ecdysterone in practical samples, and the determined values by both external standard method and standard addition method were in good agreement. Compared to the traditional solid extraction method, the system proposed has the advantages of simple procedure, good reproducibility, minimum volume requirement, reduction of matrix interference and iow contamination risk.

  5. Effect of Molecular Interactions between the Solid Wall and Liquid on the Flow Properties in Microtubes

    Institute of Scientific and Technical Information of China (English)

    BAO Fu-Bing; LIN Jian-Zhong

    2009-01-01

    The flow properties in microtubes, such as velocity profiles and pressure distributions, are different from those in macrotubes. We attribute this phenomenon to the molecular interactions between the solid wall and inner liquid. The apparent viscosity, which takes into consideration the molecular interactions, is introduced in the present study and the Navier-Stokes equations are solved. Water is adopted in the calculation. For the hydrophilic material wall, the water is more like to adhere to the wall. The velocity near the wall is smaller than that of conventional theory, while the centerline velocity and pressure gradients are much larger. Such a phenomenon becomes much more obvious with the decrease in tube diameter.

  6. Numerical simulation of gas-solid flow in an interconnected fluidized bed

    Directory of Open Access Journals (Sweden)

    Canneto Giuseppe

    2015-01-01

    Full Text Available The gas-particles flow in an interconnected bubbling fluidized cold model is simulated using a commercial CFD package by Ansys. Conservation equations of mass and momentum are solved using the Eulerian granular multiphase model. Bubbles formation and their paths are analyzed to investigate the behaviour of the bed at different gas velocities. Experimental tests, carried out by the cold model, are compared with simulation runs to study the fluidization quality and to estimate the circulation of solid particles in the bed.

  7. Correlation dimension estimate and its potential use in analysis of gas-solid flows

    DEFF Research Database (Denmark)

    Yin, Chungen; Rosendahl, Lasse Aistrup; Kær, Søren Knudsen

    2005-01-01

    be reproduced from the state-space trajectory (i.e., attractor) reconstructed from the time series of one single measured parameter. This method is widely used in gas-solid flows in fluidized beds. However, there exist different results in literature for correlation dimension (a key parameter to describe......-estimated correlation dimension (a spatial dimension), is highlighted and a solution is given. The technique is demonstrated by analyzing absolute pressure fluctuations from a cold fluidized bed. Comparison of estimated correlation dimensions based on the same pressure fluctuations indicates excluding dynamical...

  8. Advanced Test Method of Solid Oxide Cells in a Plug-Flow Setup

    DEFF Research Database (Denmark)

    Jensen, Søren Højgaard; Hauch, Anne; Hendriksen, Peter Vang;

    2009-01-01

    This paper describes a case study of two electrolysis tests of solid oxide cells [Ni/yttria-stabilized zirconia (YSZ)-YSZ-lanthanum strontium manganite (LSM)/YSZ] tested in a plug-flow setup. An extensively instrumented cell test setup was used, and the tests involved measurements of the cell...... electrolysis conditions. From measurements of the in-plane voltages in the electrodes and impedance spectra obtained during the electrolysis operation, we derive information about the resistance distributions in the Ni electrodes and describe how these distributions evolve over time. Impedance spectra at open...

  9. Thermal-Flow Code for Modeling Gas Dynamics and Heat Transfer in Space Shuttle Solid Rocket Motor Joints

    Science.gov (United States)

    Wang, Qunzhen; Mathias, Edward C.; Heman, Joe R.; Smith, Cory W.

    2000-01-01

    A new, thermal-flow simulation code, called SFLOW. has been developed to model the gas dynamics, heat transfer, as well as O-ring and flow path erosion inside the space shuttle solid rocket motor joints by combining SINDA/Glo, a commercial thermal analyzer. and SHARPO, a general-purpose CFD code developed at Thiokol Propulsion. SHARP was modified so that friction, heat transfer, mass addition, as well as minor losses in one-dimensional flow can be taken into account. The pressure, temperature and velocity of the combustion gas in the leak paths are calculated in SHARP by solving the time-dependent Navier-Stokes equations while the heat conduction in the solid is modeled by SINDA/G. The two codes are coupled by the heat flux at the solid-gas interface. A few test cases are presented and the results from SFLOW agree very well with the exact solutions or experimental data. These cases include Fanno flow where friction is important, Rayleigh flow where heat transfer between gas and solid is important, flow with mass addition due to the erosion of the solid wall, a transient volume venting process, as well as some transient one-dimensional flows with analytical solutions. In addition, SFLOW is applied to model the RSRM nozzle joint 4 subscale hot-flow tests and the predicted pressures, temperatures (both gas and solid), and O-ring erosions agree well with the experimental data. It was also found that the heat transfer between gas and solid has a major effect on the pressures and temperatures of the fill bottles in the RSRM nozzle joint 4 configuration No. 8 test.

  10. Approximate Analysis of MHD Squeeze Flow between Two Parallel Disks with Suction or Injection by Homotopy Perturbation Method

    Directory of Open Access Journals (Sweden)

    G. Domairry

    2009-01-01

    Full Text Available An analysis has been performed to study magneto-hydrodynamic (MHD squeeze flow between two parallel infinite disks where one disk is impermeable and the other is porous with either suction or injection of the fluid. We investigate the combined effect of inertia, electromagnetic forces, and suction or injection. With the introduction of a similarity transformation, the continuity and momentum equations governing the squeeze flow are reduced to a single, nonlinear, ordinary differential equation. An approximate solution of the equation subject to the appropriate boundary conditions is derived using the homotopy perturbation method (HPM and compared with the direct numerical solution (NS. Results showing the effect of squeeze Reynolds number, Hartmann number and the suction/injection parameter on the axial and radial velocity distributions are presented and discussed. The approximate solution is found to be highly accurate for the ranges of parameters investigated. Because of its simplicity, versatility and high accuracy, the method can be applied to study linear and nonlinear boundary value problems arising in other engineering applications.

  11. The use of differential measurements with a glucose biosensor for interference compensation during glucose determinations by flow injection analysis.

    Science.gov (United States)

    McGrath, M J; Iwuoha, E I; Diamond, D; Smyth, M R

    1995-01-01

    A novel detection system for the determination of glucose in the presence of clinically important interferents, based on the use of dual sensors and flow-injection analysis (FIA), is described. The normalisation methodology involves measurement of the interference signal at a reference sensor; this signal can then be subtracted from the glucose sensor signal (post-run) to give a corrected measurement of the glucose concentration. The detection system consists of a thin layer with dual glassy carbon working electrodes. One electrode was surface modified to act as a glucose biosensor by immobilisation of glucose oxidase (GOx) (from Aspergillus niger) with 1% glutaraldehyde and bovine serum albumin. The second electrode (glucose oxidase omitted) was utilised to measure the interference signal responding only to electroactive species present in the injected sample. A computer controlled multichannel potentiostat was used for potential application and current monitoring duties. The sensor responses were saved in ASCII format to facilitate post-run analysis in Microsoft Excel. Cyclic voltammetry (CV) was utilised to investigate the manner in which the interference signal contributed to the total signal obtained at the biosensor in the presence of glucose. The kinetics parameters Imax and the apparent Michaelis-Menten constant, K'm, were calculated for the sensor operating under flow-injection conditions.

  12. An automatic, vigorous-injection assisted dispersive liquid-liquid microextraction technique for stopped-flow spectrophotometric detection of boron.

    Science.gov (United States)

    Alexovič, Michal; Wieczorek, Marcin; Kozak, Joanna; Kościelniak, Paweł; Balogh, Ioseph S; Andruch, Vasil

    2015-02-01

    A novel automatic vigorous-injection assisted dispersive liquid-liquid microextraction procedure based on the use of a modified single-valve sequential injection manifold (SV-SIA) was developed and applied for determination of boron in water samples. The major novelties in the procedure are the achieving of efficient dispersive liquid-liquid microextraction by means of single vigorous-injection (250 µL, 900 µL s(-1)) of the extraction solvent (n-amylacetate) into aqueous phase resulting in the effective dispersive mixing without using dispersive solvent and after self-separation of the phases, as well as forwarding of the extraction phase directly to a Z-flow cell (10 mm) without the use of a holding coil for stopped-flow spectrophotometric detection. The calibration working range was linear up to 2.43 mg L(-1) of boron at 426nm wavelength. The limit of detection, calculated as 3s of a blank test (n=10), was found to be 0.003 mg L(-1), and the relative standard deviation, measured as ten replicable concentrations at 0.41 mg L(-1) of boron was determined to be 5.6%. The validation of the method was tested using certified reference material.

  13. Investigation on transient flow of a centrifugal charging pump in the process of high pressure safety injection

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Fan, E-mail: zhangfan4060@gmail.com; Yuan, Shouqi; Fu, Qiang; Tao, Yi

    2015-11-15

    Highlights: • The transient flow characteristics of the charging pump with the first stage impeller in the HPSI process have been investigated numerically by CFD. • The hydraulic performance of the charging pump during the HPSI are discussed, andthe absolute errors between the simulated and measured results are analyzed in the paper. • Pressure fluctuation in the impeller and flow pattern in the impeller were studied in the HPSI process. It is influenced little at the beginning of the HPSI process while fluctuates strongly in the end of the HPSI process. - Abstract: In order to investigate the transient flow characteristics of the centrifugal charging pump during the transient transition process of high pressure safety injection (HPSI) from Q = 148 m{sup 3}/h to Q = 160 m{sup 3}/h, numerical simulation and experiment are implemented in this study. The transient flow rate, which is the most important factor, is obtained from the experiment and works as the boundary condition to accurately accomplish the numerical simulation in the transient process. Internal characteristics under the variable operating conditions are analyzed through the transient simulation. The results shows that the absolute error between the simulated and measured heads is less than 2.26% and the absolute error between the simulated and measured efficiency is less than 2.04%. Pressure fluctuation in the impeller is less influenced by variable flow rate in the HPSI process, while flow pattern in the impeller is getting better and better with the flow rate increasing. As flow rate increases, fluid blocks on the tongue of the volute and it strikes in this area at large flow rate. Correspondingly, the pressure fluctuation is intense and vortex occurs gradually during this period, which obviously lowers the efficiency of the pump. The contents of the current work can provide references for the design optimization and fluid control of the pump used in the transient process of variable operating

  14. On flow characteristics of liquid-solid mixed-phase nanofluid inside nanochannels

    Institute of Scientific and Technical Information of China (English)

    H AMINFAR; N RAZMARA; M MOHAMMADPOURFARD

    2014-01-01

    The atomic behavior of liquid-solid mixed-phase nanofluid flows inside nanochannels is investigated by a molecular dynamics simulation (MDS). The results of visual observation and statistic analysis show that when the nanoparticles reach near each other, the strong interatomic force will make them attach together. This aggrega-tion continues until all nanoparticles make a continuous cluster. The effect of altering the external force magnitude causes changes in the agglomeration rate and system enthalpy. The density and velocity profiles are shown for two systems, i.e., argon (Ar)-copper (Cu) nanofluid and simple Ar fluid between two Cu walls. The results show that using nanopar-ticles changes the base fluid particles ordering along the nanochannel and increases the velocity. Moreover, using nanoparticles in simple fluids can increase the slip length and push the near-wall fluid particles into the main flow in the middle of the nanochannel.

  15. Theoretical analysis and numerical computation of dilute solid/liquid two_phase pipe flow

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    Starting with the kinetic theory for dilute solid/liquid two_phase flow, a mathematical model is established to predict the flow in a horizontal square pipe and the predictions are compared with LDV measurements. The present model predicts correctly two types of patterns of the vertical distribution of particle concentration observed in experiments, and also gives different patterns of the distribution of particle fluctuating energy. In the core region of the pipe, the predicted mean velocity of particles is smaller than that of liquid, but near the pipe bottom the reverse case occurs. In addition, full attention is paid to the mechanism for the vertical distribution of the average properties of particles such as concentration and mean velocity. From the kinetic_theory point of view, the cause of formation for different patterns of the vertical concentration distribution is not only related to the lift force exerted on a particle, but also related to the distribution of particle fluctuating energy.

  16. Online solid-phase extraction with high-performance liquid chromatography and mass spectrometry for the determination of five tannins in traditional Chinese medicine injections.

    Science.gov (United States)

    Sun, Meng; Lin, Yuanyuan; Zhang, Jie; Zheng, Shaohua; Wang, Sicen

    2016-03-01

    A rapid analytical method based on online solid-phase extraction with high-performance liquid chromatography and mass spectrometry has been established and applied to the determination of tannin compounds that may cause adverse effects in traditional Chinese medicine injections. Different solid-phase extraction sorbents have been compared and the elution buffer was optimized. The performance of the method was verified by evaluation of recovery (≥40%), repeatability (RSD ≤ 6%), linearity (r(2) ≥ 0.993), and limit of quantification (≤0.35 μg/mL). Five tannin compounds, gallic acid, cianidanol, gallocatechin gallate, ellagic acid, and penta-O-galloylglucose, were identified with concentrations ranging from 3.1-37.4 μg/mL in the analyzed traditional Chinese medicine injections.

  17. Instability modes on a solid-body-rotation flow in a finite-length pipe

    Science.gov (United States)

    Feng, Chunjuan; Liu, Feng; Rusak, Zvi; Wang, Shixiao

    2017-09-01

    Numerical solutions of the incompressible Navier-Stokes equations are obtained to study the time evolution of both axisymmetric and three-dimensional perturbations to a base solid-body-rotation flow in a finite-length pipe with non-periodic boundary conditions imposed at the pipe inlet and outlet. It is found that for a given Reynolds number there exists a critical swirl number beyond which the initial perturbations grow, in contrast to the solid-body rotation flow in an infinitely-long pipe or a finite-length pipe with periodic inlet and exit boundary conditions for which the classical Kelvin analysis and Rayleigh stability criterion affirm neutrally stable for all levels of swirl. This paper uncovers for the first time the detailed evolution of the perturbations in both the axisymmetric and three-dimensional situations. The computations reveal a linear growth stage of the perturbations with a constant growth rate after a brief initial period of decay of the imposed initial perturbations. The fastest growing axisymmetric and three-dimensional instability modes and the associated growth rates are identified numerically for the first time. The computations show that the critical swirl number increases and the growth rate of instability decreases at the same swirl number with decreasing Reynolds number. The growth rate of the axisymmetric mode at high Reynolds number agrees well with previous stability theory for inviscid flow. More importantly, three-dimensional simulations uncover that the most unstable mode is the spiral type m = 1 mode, which appears at a lower critical swirl number than that for the onset of the axisymmetric mode. This spiral mode grows faster than the unstable axisymmetric mode at the same swirl. Moreover, the computations reveal that after the linear growing stage of the perturbation the flow continues to evolve nonlinearly to a saturated axisymmetric vortex breakdown state.

  18. Application of material flow analysis to municipal solid waste in Maputo City, Mozambique.

    Science.gov (United States)

    Dos Muchangos, Leticia Sarmento; Tokai, Akihiro; Hanashima, Atsuko

    2017-03-01

    Understanding waste flows within an urban area is important for identifying the main problems and improvement opportunities for efficient waste management. Assessment tools such as material flow analysis (MFA), an extensively applied method in waste management studies, provide a structured and objective evaluating process to characterize the waste management system best, to identify its shortcomings and to propose suitable strategies. This paper presents the application of MFA to municipal solid waste management (MSWM) in Maputo City, the capital of Mozambique. The results included the identification and quantification of the main input and output flows of the MSWM system in 2007 and 2014, from the generation, material recovery and collection, to final disposal and the unaccounted flow of municipal solid waste (MSW). We estimated that the waste generation increased from 397×10(3) tonnes in 2007 to 437×10(3) tonnes in 2014, whereas the total material recovery was insignificant in both years - 3×10(3) and 7×10(3) tonnes, respectively. As for collection and final disposal, the official collection of waste to the local dumpsite in the inner city increased about threefold, from 76×10(3) to 253×10(6) tonnes. For waste unaccounted for, the estimates indicated a reduction during the study period from 300×10(3) to 158×10(3) tonnes, due to the increase of collection services. The emphasized aspects include the need for practical waste reduction strategies, the opportunity to explore the potential for material recovery, careful consideration regarding the growing trend of illegal dumping and the urgency in phasing-out from the harmful practice of open dumping.

  19. Continuous-flow separation and pre-concentration coupled on-line to solid-surface fluorescence spectroscopy for the simultaneous determination of o-phenylphenol and thiabendazole.

    Science.gov (United States)

    García Reyes, J F; Llorent Martínez, E J; Ortega Barrales, P; Molina Díaz, A

    2004-01-01

    A novel and single flow-injection system combined with solid-surface fluorescence detection is proposed in this work for the resolution of a mixture of two widely used pesticides (o-phenylphenol and thiabendazole). The continuous-flow methodology is based on the implementation of on-line pre-concentration and separation of both analytes on the surface of C18 silica gel beads placed just inside the flow cell, implemented with gel-phase fluorimetric multi-wavelength detection (using 305/358 and 250/345 nm as excitation/emission wavelengths for thiabendazole and o-phenylphenol, respectively). The separation of the pesticides was possible owing to the different retention/desorption kinetics of their interactions with the solid support in the zone where the stream impinges on the solid material. No previous separation of the analytes before they reach the flow cell is needed thereby simplifying substantially both the procedure and the manifold. By using a sample volume of 2,600 microL, the system was calibrated in the range 0.5-16 and 5-120 ng mL(-1) with detection limits of 0.09 and 0.60 ng mL(-1) for thiabendazole and o-phenylphenol, respectively. The RSD values (n=10) were about 1% for both analytes. The proposed methodology was applied to environmental water samples and also to various commercial pesticide formulations containing both analytes. Recovery percentages were 97-103% and 98-102% for thiabendazole and o-phenylphenol, respectively.

  20. Direct Zinc Determination in Brazilian Sugar Cane Spirit by Solid-Phase Extraction Using Moringa oleifera Husks in a Flow System with Detection by FAAS

    Directory of Open Access Journals (Sweden)

    Vanessa N. Alves

    2011-01-01

    Full Text Available This paper reports a method for the determination of zinc in Brazilian sugar cane spirit, (cachaça in Portuguese, using solid-phase extraction with a flow injection analysis system and detection by FAAS. The sorbent material used was activated carbon obtained from Moringa oleifera husks. Flow and chemical variables of the proposed system were optimized through multivariate designs. The factors selected were sorbent mass, sample pH, sample flow rate, and eluent concentration. The optimum extraction conditions were obtained using a sample pH of 4.0, a sample flow rate of 6.0 mL min-1, 30.0 mg of sorbent mass, and 1.0 mol L-1 HNO3 as the eluent at a flow rate of 4.0 mL min-1. The limit of detection for zinc was 1.9 μg L-1, and the precision was below 0.82% (20.0 μg L-1, n=7. The analytical curve was linear from 2 to 50 μg L-1, with a correlation coefficient of 0.9996. The method developed was successfully applied to spiked Brazilian sugar cane spirit, and accuracy was assessed through recovery tests, with results ranging from 83% to 100%.

  1. Characterization of Solids Collected from H-Area Injection Wells and Injection Tank Chemistry from both F- and H-Area Water Treatment Units (WTUs)

    Energy Technology Data Exchange (ETDEWEB)

    Serkiz, S.M.

    1999-04-15

    This study suggests that a strong poitential exists for both chemical and biological fouling of the injection wells at the F- and H Area remediation systems. To further the potential, an evaluation of WTU process chemistry, characterization of the natural groundwater geochemistry, and analysis of microbiological activity should be performed. This report summarizes the results.

  2. Subcutaneous Injections

    DEFF Research Database (Denmark)

    Thomsen, Maria

    This thesis is about visualization and characterization of the tissue-device interaction during subcutaneous injection. The tissue pressure build-up during subcutaneous injections was measured in humans. The insulin pen FlexTouchr (Novo Nordisk A/S) was used for the measurements and the pressure...... build-up was evaluated indirectly from the changes in the flow rate between subcutaneous injections and air injections. This method enabled the tissue counter pressure to be evaluated without a formal clinical study approval. The measurements were coupled to a model for the pressure evolution...... in subcutaneous tissue, based on mass conservation and flow in a porous medium. From the measurements the flow permeability and bulk modulus of the tissue were determined. In the adipose tissue the drug forms a bolus from where it is absorbed by the blood capillaries. The spatial distribution of the injected...

  3. An investigation of particle behavior in gas-solid horizontal pipe flow by an extended LDA technique

    Energy Technology Data Exchange (ETDEWEB)

    Yong Lu; Donald H. Glass; William J. Easson [University of Edinburgh, Edinburgh (United Kingdom). Institute for Materials and Processes

    2009-12-15

    An extended Laser Doppler Anemometry (LDA) technique has been developed to measure the distributions of particle velocities and particle number rates over a whole pipe cross-section in a dilute pneumatic conveying system. The first extension concentrates on the transform matrix for predicting the laser beams' cross point in a pipe according to the shift coordinate of the 3D computer-controlled traverse system on which the probes of the LDA system were mounted. The second focuses on the proper LDA sample rate for the measurement of gas-solid pipe flow with polydisperse particles. A suitable LDA sample rate should ensure that enough data is recorded in the measurement interval to precisely calculate the particle mean velocity or other statistical values at every sample point. The present study explores the methodology as well as the fundamentals of measurements, using a laser facility, of the cross-sectional distributions of solid phase. In the horizontal gas-solid pipe flow (glass beads less than 110 {mu}m), the experimental data show that the cross-sectional flow patterns of the solid phase can be classified by annulus-like flow describing the axial particle velocity contours and stratified flow characterising particle number rate distribution over a cross-section. Thus, the cross-sectional flow pattern of the solid phase in a horizontal pipe may be annular or stratified dependent on whether the axial particle velocity or particle number rate is the phenomenon studied. 13 refs., 16 figs., 1 tab.

  4. Discharge flow of granular media from silos with a lateral orifice and injection of air

    Directory of Open Access Journals (Sweden)

    Aussillous Pascale

    2017-01-01

    Full Text Available Few studies concern the prediction of the mass flow rate of a granular media discharged from a silo with a lateral orifice. However, this situation can have pratical interest considering a tank of granular material with a leak on its side. We studied experimentally the discharge of a vertical silo filled by spherical glass beads. We consider rectangular silos with a rectangular orifice. The impact of size, aspect ratio and position of the orifice and the effect of an additional air flow were studied. The measured parameters are the mass flow rate and the pressure along the silo, whereas the controlled parameters are the size of particles, and the flow rate of air. We identified two regimes of discharge according to the aspect ratio (of width to height of the rectangular orifice. Increasing the air flow rate induces an increase of the granular media flow rate. Using a simple physical model to describe the grains and gas flow, we put in evidence the role played by the air pressure gradient at the outlet. Then we compared the experimental results with continuum Navier-Stokes simulations with the granular μ(I-rheology. We showed that the continuum μ(I-rheology describes well our discharge flow of granular media from silos, taking into account the effect of the position of the orifice as well as the coupling with the gas flow.

  5. The Clustering Instability in Rapid Granular and Gas-Solid Flows

    Science.gov (United States)

    Fullmer, William D.; Hrenya, Christine M.

    2017-01-01

    Flows of solid particles are known to exhibit a clustering instability—dynamic microstructures characterized by a dense region of highly concentrated particles surrounded by a dilute region with relatively few particles—that has no counterpart in molecular fluids. Clustering is pervasive in rapid flows. Its presence impacts momentum, heat, and mass transfer, analogous to how turbulence affects single-phase flows. Yet predicting clustering is challenging, again analogous to the prediction of turbulent flows. In this review, we focus on three key areas: (a) state-of-the-art mathematical tools used to study clustering, with an emphasis on kinetic theory–based continuum models, which are critical to the prediction of the larger systems found in nature and industry, (b) mechanisms that give rise to clustering, most of which are explained via linear stability analyses of kinetic theory–based models, and (c) a critical review of validation studies of kinetic theory–based models to highlight the accuracies and limitations of such theories.

  6. Effect of viscous dissipation and suction/injection on MHD nanofluid flow over a wedge with porous medium and slip

    Directory of Open Access Journals (Sweden)

    Alok Kumar Pandey

    2016-12-01

    Full Text Available The purpose of present study is to identify the effects of viscous dissipation and suction/injection on MHD flow of a nanofluid past a wedge with convective surface in the appearance of slip flow and porous medium. The basic non-linear PDEs of flow and energy are altered into a set of non-linear ODEs using auxiliary similarity transformations. The system of equations together with coupled boundary conditions have been solved numerically by applying Runge-Kutta-Fehlberg procedure via shooting scheme. The influence of relevant parameters on non-dimensional velocity and temperature profiles are depicted graphically and investigated in detail. The results elucidate that as enhance in the Eckert number, the skin friction coefficient increases, while heat transfer rate decreases. The outcomes also specify that thermal boundary layer thickness declines with an increase in suction parameter. Moreover, it is accelerated with augment in injection parameter. The results are analogized with the study published earlier and it creates a fine concord.

  7. Chemically prepared silver electrode for determination of N-acetyl-L-cysteine by flow-injection potentiometry.

    Science.gov (United States)

    Kolar, M; Dobcnik, D

    2003-01-01

    This paper describes the use of the silver electrode by means of chemical pretreatment of the electrode surface with mercuric(II) chloride solution and potassium iodide solution in flow injection analysis (FIA). The electrode is used as a potentiometric sensor for the indirect determination of NAC in a carrier stream containing iodine. A one-channel flow system that consists of a peristaltic pump, injection valve, a silver wire electrode and a saturated calomel reference electrode (SCE) was used. Some typical FIA parameters such as flow rate, tube length and composition of the carrier stream were varied. The electrode is further characterised by a constant linear response within the concentration range for NAC between 4.0 x 10(-6) and 1.0 x 10(-3) M at the slope of 60.6 +/- 1.0 mV/p(NAC). Some pharmaceutical products containing NAC were also tested. These results can be compared to the results obtained by the direct potentiometric titrations with silver nitrate and are also in good agreement with values declared by pharmaceutical manufacturers.

  8. Design of fan beam optical sensor and its application in mass flow rate measurement of pneumatically conveyed solids

    Institute of Scientific and Technical Information of China (English)

    LI Yang; ZHENG Ying-na; YUE Hong-wei

    2005-01-01

    The fan-beam optical sensor is made up of many semiconductor lasers and detectors fixed around the wall alternately at a cross section of pneumatically conveying pipe. When the sensor works, a scanning light source emits a 50° lamellar fan-beam through the gas-solid two phase flow, and the projection data resulting extinction effect of solid particles are detected at the same time. With the projection data, the flow rate mass can be calculated, and then the flow image can be reconstructed. In this paper, the design of the sensor including spatial arrangement of the structural parts, basic principle and measurement sensitivity distribution are introduced. The mathematical measurement model of solid mass flow rate is presented together with the testing results.

  9. Effect of surface chemistry on the behaviour of solid particles in multiphase flow

    Energy Technology Data Exchange (ETDEWEB)

    Gulbrandsen, Egil; Pedersen, Anette

    2006-03-15

    The surface chemical properties of solids particles strongly influence their behaviour in multiphase flow, e.g. their tendency to be transported by the oil or water phase, their tendency to stick to the oil-water interfaces, or their tendency to aggregate. The behaviour of the solid particles may influence various processes such as emulsion breakdown, oil-water separation, or sedimentation of solids in a pipeline, and thereby issues as erosion, and corrosion under deposits. These issues were addressed in the present laboratory study. The reported results focus on behaviour of sand in a simple oil-water system in presence of a model corrosion inhibitor compound, cetyltrimethylammonium bromide. A refined oil was used in the tests. The system was studied by various methods like zeta-potential measurements, assessment of wetting properties and tendency of aggregation and sedimentation in oil-water system. It was found that surface-active corrosion inhibitor could strongly influence the wetting of the sand. By addition of the corrosion inhibitor, the sand changed from water wet to oil wet. This change induced a tendency to aggregation of the sand grains. The aggregation led to sticky deposits of sand. This may have an impact on under deposit corrosion phenomena. (Author)

  10. A hybrid DEM/CFD approach for solid-liquid flows

    Institute of Scientific and Technical Information of China (English)

    QIU Liu-chao; WU Chuan-yu

    2014-01-01

    A hybrid scheme coupling the discrete element method (DEM) with the computational fluid dynamics (CFD) is developed to model solid-liquid flows. Instead of solving the pressure Poisson equation, we use the compressible volume-averaged continuity and momentum equations with an isothermal stiff equation of state for the liquid phase in our CFD scheme. The motion of the solid phase is obtained by using the DEM, in which the particle-particle and particle-wall interactions are modelled by using the theoretical contact mechanics. The two phases are coupled through the Newton’s third law of motion. To verify the proposed method, the sedi-mentation of a single spherical particle is simulated in water, and the results are compared with experimental results reported in the literature. In addition, the drafting, kissing, and tumbling (DKT) phenomenon between two particles in a liquid is modelled and rea-sonable results are obtained. Finally, the numerical simulation of the density-driven segregation of a binary particulate suspension in-volving 10 000 particles in a closed container is conducted to show that the presented method is potentially powerful to simulate real particulate flows with large number of moving particles.

  11. Motion of a distant solid particle in a shear flow along a porous slab

    Science.gov (United States)

    Khabthani, S.; Sellier, A.; Feuillebois, F.

    2013-12-01

    The motion of a solid and no-slipping particle immersed in a shear flow along a sufficiently porous slab is investigated. The fluid flow outside and inside of the slab is governed by the Stokes and Darcy equations, respectively, and the so-called Beavers and Joseph slip boundary conditions are enforced on the slab surface. The problem is solved for a distant particle with length scale a in terms of the small parameter a/ d where d designates the large particle-slab separation. This is achieved by asymptotically inverting a relevant boundary-integral equation on the particle surface, which has been recently proposed for any particle location (distant or close particle) in Khabthani et al. (J Fluid Mech 713:271-306, 2012). It is found that at order O( a/ d) the slab behaves for any particle shape as a solid plane no-slip wall while the slab properties (thickness, permeability, associated slip length) solely enter at O(( a/ d)2). Moreover, for a spherical particle, the numerical results published in Khabthani et al. (J Fluid Mech 713:271-306, 2012) perfectly agree with the present asymptotic analysis.

  12. Three-dimensional numerical modeling of an induction heated injection molding tool with flow visualization

    DEFF Research Database (Denmark)

    Guerrier, Patrick; Tosello, Guido; Nielsen, Kaspar Kirstein

    2016-01-01

    Using elevated mold temperature is known to have a positive influence of final injection molded parts. Induction heating is a method that allow obtaining a rapid thermal cycle, so the overall molding cycle time is not increased. In the present research work, an integrated multi-turn induction hea...

  13. A New Method for Measurement of Local Solid Flux in Gas-Solid Two-phase Flow

    Institute of Scientific and Technical Information of China (English)

    鄂承林; 卢春善; 徐春明; 高金森; 时铭显

    2003-01-01

    Previous works have shown that the suction probe cannot be used to accurately measure the upward and downward particle fluxes independently. A new method using a single optical probe to measure the local solid flux is presented. The measurement of upward, downward and net solid fluxes was carried out in a cold model circulating fluidized bed (CFB) unit. The result shows that the profile of the net solid flux is in good agreement with the previous experimental data measured with a suction probe. The comparison between the average solid flux determined with the optical measuring system and the external solid flux was made, and the maximum deviationturned out to be 22%, with the average error being about 6.9%. These confirm that the optical fiber system can be successfully used to measure the upward, downward and net solid fluxes simultaneously by correctly processing the sampling signals obtained from the optical measuring system.

  14. Flow regime effects on non-cavitating injection nozzles over spray behavior

    Energy Technology Data Exchange (ETDEWEB)

    Payri, R., E-mail: rpayri@mot.upv.e [CMT-Motores Termicos, Universidad Politecnica de Valencia, Camino de Vera s/n, Valencia E-46022 (Spain); Salvador, F.J.; Gimeno, J.; Novella, R. [CMT-Motores Termicos, Universidad Politecnica de Valencia, Camino de Vera s/n, Valencia E-46022 (Spain)

    2011-02-15

    This paper deals with the influence of flow regime (laminar, transition or turbulent) on the internal flow behavior, and how it affects the spray development in diesel nozzles. In particular, the research described here aims at studying and quantifying the internal flow regime effects on the spray behavior. With this purpose, internal flow results, based on mass flow rate and momentum flux measurements performed on three different tapered nozzles and which helped to determine the flow regime, has been taken into account as a point of departure for the spray behavior analysis. Thus, in this work, spray macroscopic visualization tests have been performed and analyzed which clearly revealed a change in the behavior of the angle and penetration of the spray related to the change of the flow nature. Moreover, with all the experimental data available, it has been possible to relate macroscopic parameters of the spray with those describing the internal flow (momentum and effective velocity) or the geometry of the nozzle (length or diameter) through correlations.

  15. Numerical Simulations of Liquid-Gas-Solid Three-Phase Flows in Microgravity

    Directory of Open Access Journals (Sweden)

    Xinyu Zhang

    2012-03-01

    Full Text Available Three-phase liquid-gas-solid flows under microgravity condition are studied. An Eulerian-Lagrangian computational model was developed and used in the simulations. In this approach, the liquid flow was modeled by a volume-averaged system of governing equations, whereas motions of particles and bubbles were evaluated using the Lagrangian trajectory analysis procedure. It was assumed that the bubbles remained spherical, and their shape variations were neglected. The bubble-liquid, particle-liquid and bubbl-particle two-way interactions were accounted for in the analysis. The discrete phase equations used included drag, lift, buoyancy, and virtual mass forces. Particle-particle interactions and bubble-bubble interactions were accounted for by the hard sphere model. Bubble coalescence was also included in the model. The transient flow characteristics of the three-phase flow were studied; and the effects of gravity, inlet bubble size and g-jitter acceleration on variation of flow characteristics were discussed. The low gravity simulations showed that most bubbles are aggregated in the inlet region. Also, under microgravity condition, bubble transient time is much longer than that in normal gravity. As a result, the Sauter mean bubble diameter, which is proportional to the transient time of the bubble, becomes rather large, reaching to more than 9 mm. The bubble plume in microgravity exhibits a plug type flow behavior. After the bubble plume reaches the free surface, particle volume fraction increases along the height of the column. The particles are mainly located outside the bubble plume, with very few particles being retained in the plume. In contrast to the normal gravity condition, the three phases in the column are poorly mixed under microgravity conditions. The velocities of the three phases were also found to be of the same order. Bubble size significantly affects the characteristics of the three-phase flows under microgravity conditions. For

  16. Numerical simulation of flow hydrodynamics of struvite pellets in a liquid-solid fluidized bed.

    Science.gov (United States)

    Ye, Xin; Chu, Dongyuan; Lou, Yaoyin; Ye, Zhi-Long; Wang, Ming Kuang; Chen, Shaohua

    2017-07-01

    Phosphorus recovery in the form of struvite has been aroused in recent decades for its dual advantages in eutrophication control and resource protection. The usage of the struvite products is normally determined by the size which is largely depended on the hydrodynamics. In this study, flow behavior of struvite pellets was simulated by means of Eulerian-Eulerian two-fluid model combining with kinetic theory of granular flow in a liquid-solid fluidized bed reactor (FBR). A parametric study including the mesh size, time step, discretization strategy, turbulent model and drag model was first developed, followed by the evaluations of crucial operational conditions, particle characteristics and reactor shapes. The results showed that a cold model with the mesh resolution of 16×240, default time step of 0.001sec and first order discretization scheme was accurate enough to describe the fluidization. The struvite holdup profile using Syamlal-O'Brien drag model was best fitted to the experimental data as compared with other drag models and the empirical Richardson-Zaki equation. Regarding the model evaluation, it showed that liquid velocity and particle size played important roles on both solid holdups and velocities. The reactor diameter only influenced the solid velocity while the static bed height almost took no effect. These results are direct and can be applied to guide the operation and process control of the struvite fluidization. Moreover, the model parameters can also be used as the basic settings in further crystallization simulations. Copyright © 2016. Published by Elsevier B.V.

  17. Reagent-free determination of amikacin content in amikacin sulfate injections by FTIR derivative spectroscopy in a continuous flow system

    Institute of Scientific and Technical Information of China (English)

    José F. Ovalles; Máximo Gallignani; María R. Brunetto; Rebeca A. Rondón; Carlos Ayala

    2014-01-01

    The quantitative estimation of amikacin (AMK) in AMK sulfate injection samples is reported using FTIR-derivative spectrometric method in a continuous flow system. Fourier transform of mid-IR spectra were recorded without any sample pretreatment. A good linear calibration (r40.999, %RSDo 2.0) in the range of 7.7-77.0 mg/mL was found. The results showed a good correlation with the manufacturer's and overall they all fell within acceptable limits of most pharmacopoeial monographs on AMK sulfate.

  18. Method for the simultaneous determination of total polyphenol and anthocyan indexes in red wines using a flow injection approach

    OpenAIRE

    2002-01-01

    A simultaneous and fast method for the determination of total polyphenol index (t.p.i.) and total anthocyan index (t.a.i.) has been developed by a flow injection approach and a diode array spectrophotometer for monitoring at 280 nm and 520 nm, respectively. Linear ranges were obtained from 20 to 70 index units and from 20 to 500 mg l-1 for t.p.i. and t.a.i., respectively. The results provided by the proposed method agree with those obtained using the polyphenol index at 280 nm and the Riberea...

  19. Reagent-free determination of amikacin content in amikacin sulfate injections by FTIR derivative spectroscopy in a continuous flow system

    Directory of Open Access Journals (Sweden)

    José F. Ovalles

    2014-04-01

    Full Text Available The quantitative estimation of amikacin (AMK in AMK sulfate injection samples is reported using FTIR-derivative spectrometric method in a continuous flow system. Fourier transform of mid-IR spectra were recorded without any sample pretreatment. A good linear calibration (r>0.999, %RSD<2.0 in the range of 7.7–77.0 mg/mL was found. The results showed a good correlation with the manufacturer's and overall they all fell within acceptable limits of most pharmacopoeial monographs on AMK sulfate.

  20. CSCM Navier-Stokes thermal/aerodynamic analysis of hypersonic nozzle flows with slot injection and wall cooling

    Science.gov (United States)

    Codding, William H.; Lombard, C. K.; Yang, J. Y.

    1988-01-01

    The Conservative Supra-Characteristic Method (CSCM) Navier-Stokes solver is applied to ascertain the problems inherent in the design of a nominal Mach 14 nozzle for NASA-Ames' 3.5-ft Hypersonic Wind Tunnel; attention is given to the effects of boundary layer cooling systems on the aerodynamic redesign of the nozzle throat region. Complete nozzle flowfields are calculated with and without slot injection of either hot or cold fluid into the boundary layer just upstream of the throat, as well as with alternatively adiabatic and cold walls. The CSCM method is capable of resolving subtle differences in the flows.