Sample records for flame tube material

  1. Flaming on YouTube

    NARCIS (Netherlands)

    Moor, Peter J.; Heuvelman, A.; Verleur, R.


    In this explorative study, flaming on YouTube was studied using surveys of YouTube users. Flaming is defined as displaying hostility by insulting, swearing or using otherwise offensive language. Three general conclusions were drawn. First, although many users said that they themselves do not flame,

  2. Flaming on YouTube

    NARCIS (Netherlands)

    Moor, Peter J.; Heuvelman, Ard; Verleur, Ria


    In this explorative study, flaming on YouTube was studied using surveys of YouTube users. Flaming is defined as displaying hostility by insulting, swearing or using otherwise offensive language. Three general conclusions were drawn. First, although many users said that they themselves do not flame,

  3. Premixed flame propagation in vertical tubes

    CERN Document Server

    Kazakov, Kirill A


    Analytical treatment of premixed flame propagation in vertical tubes with smooth walls is given. Using the on-shell flame description, equations describing quasi-steady flame with a small but finite front thickness are obtained and solved numerically. It is found that near the limits of inflammability, solutions describing upward flame propagation come in pairs having close propagation speeds, and that the effect of gravity is to reverse the burnt gas velocity profile generated by the flame. On the basis of these results, a theory of partial flame propagation driven by the gravitational field is developed. A complete explanation is given of the intricate observed behavior of limit flames, including dependence of the inflammability range on the size of the combustion domain, the large distances of partial flame propagation, and the progression of flame extinction. The role of the finite front-thickness effects is discussed in detail. Also, various mechanisms governing flame acceleration in smooth tubes are ide...

  4. Premixed flame propagation in vertical tubes (United States)

    Kazakov, Kirill A.


    Analytical treatment of the premixed flame propagation in vertical tubes with smooth walls is given. Using the on-shell flame description, equations for a quasi-steady flame with a small but finite front thickness are obtained and solved numerically. It is found that near the limits of inflammability, solutions describing upward flame propagation come in pairs having close propagation speeds and that the effect of gravity is to reverse the burnt gas velocity profile generated by the flame. On the basis of these results, a theory of partial flame propagation driven by a strong gravitational field is developed. A complete explanation is given of the intricate observed behavior of limit flames, including dependence of the inflammability range on the size of the combustion domain, the large distances of partial flame propagation, and the progression of flame extinction. The role of the finite front-thickness effects is discussed in detail. Also, various mechanisms governing flame acceleration in smooth tubes are identified. Acceleration of methane-air flames in open tubes is shown to be a combined effect of the hydrostatic pressure difference produced by the ambient cold air and the difference of dynamic gas pressure at the tube ends. On the other hand, a strong spontaneous acceleration of the fast methane-oxygen flames at the initial stage of their evolution in open-closed tubes is conditioned by metastability of the quasi-steady propagation regimes. An extensive comparison of the obtained results with the experimental data is made.

  5. Analytical study in the mechanism of flame movement in horizontal tubes. II. Flame acceleration in smooth open tubes

    CERN Document Server

    Kazakov, Kirill A


    The problem of spontaneous acceleration of premixed flames propagating in open horizontal tubes with smooth walls is revisited. It is proved that in long tubes, this process can be considered quasi-steady, and an equation for the flame front position is derived using the on-shell description. Numerical solutions of this equation are found which show that as in the case of uniform flame movement, there are two essentially different regimes of flame propagation. In the type I regime, the flame speed and its acceleration are comparatively low, whereas the type II regime is characterized by significant flame acceleration that rapidly increases as the flame travels along the tube. A detailed comparison of the obtained results with the experimental data on flame acceleration in methane-air mixtures is given. In particular, it is confirmed that flames propagating in near-stoichiometric mixtures and mixtures near the limits of inflammability belong to the types II and I, respectively, whereas flames in transient mixt...

  6. Tulip flames: changes in shape of premixed flames propagating in closed tubes (United States)

    Dunn-Rankin, D.; Sawyer, R. F.

    The experimental results that are the subject of this communication provide high-speed schlieren images of the closed-tube flame shape that has come to be known as the tulip flame. The schlieren images, along with in-chamber pressure records, help demonstrate the effects of chamber length, equivalence ratio, and igniter geometry on formation of the tulip flame. The pressure/time records show distinct features which correlate with flame shape changes during the transition to tulip. The measurements indicate that the basic tulip flame formation is a robust phenomenon that depends on little except the overall geometry of the combustion vessel.

  7. The Rubens Tube: A Flaming Good Way to Teach Waves (United States)

    Sandoval, Christopher


    The Ruben Flame Tube is named after H. Ruben, who published the demonstration experiment in "Annalen der Physik" in 1905. This article presents one of the many demonstrations the author uses to engage, motivate, and challenge his students.

  8. Launch Pad Flame Trench Refractory Materials (United States)

    Calle, Luz M.; Hintze, Paul E.; Parlier, Christopher R.; Bucherl, Cori; Sampson, Jeffrey W.; Curran, Jerome P.; Kolody, Mark; Perusich, Steve; Whitten, Mary


    The launch complexes at NASA's John F. Kennedy Space Center (KSC) are critical support facilities for the successful launch of space-based vehicles. These facilities include a flame trench that bisects the pad at ground level. This trench includes a flame deflector system that consists of an inverted, V-shaped steel structure covered with a high temperature concrete material five inches thick that extends across the center of the flame trench. One side of the "V11 receives and deflects the flames from the orbiter main engines; the opposite side deflects the flames from the solid rocket boosters. There are also two movable deflectors at the top of the trench to provide additional protection to shuttle hardware from the solid rocket booster flames. These facilities are over 40 years old and are experiencing constant deterioration from launch heat/blast effects and environmental exposure. The refractory material currently used in launch pad flame deflectors has become susceptible to failure, resulting in large sections of the material breaking away from the steel base structure and creating high-speed projectiles during launch. These projectiles jeopardize the safety of the launch complex, crew, and vehicle. Post launch inspections have revealed that the number and frequency of repairs, as well as the area and size of the damage, is increasing with the number of launches. The Space Shuttle Program has accepted the extensive ground processing costs for post launch repair of damaged areas and investigations of future launch related failures for the remainder of the program. There currently are no long term solutions available for Constellation Program ground operations to address the poor performance and subsequent failures of the refractory materials. Over the last three years, significant liberation of refractory material in the flame trench and fire bricks along the adjacent trench walls following Space Shuttle launches have resulted in extensive investigations of

  9. Tulip flames: changes in shape of premixed propagating in closed tubes

    Energy Technology Data Exchange (ETDEWEB)

    Dunn-Rankin, D. [California Univ., Irvine, CA (United States). Dept. of Mechanical and Aerospace Engineering; Sawyer, R.F. [California Univ., Berkeley, CA (United States). Dept. of Mechanical Engineering


    The experimental results that are the subject of this communication provide high-speed schlieren images of the closed-tube flame shape that has come to be known as the tulip flame. The schlieren images, along with in-chamber pressure records, help demonstrate the effects of chamber length, equivalence ratio, and igniter geometry on formation of the tulip flame. The pressure/time records show distinct features which correlate with flame shape changes during the transition to tulip. The measurements indicate that the basic tulip flame formation is a robust phenomenon that depends on little except the overall geometry of the combustion vessel. (orig.) 32 refs.

  10. The experimental of methane-air flame propagation in the tube with quadrate cross section

    Institute of Scientific and Technical Information of China (English)

    GUO Zi-ru; SHEN Zhao-wu; LU Shou-xiang; ZHOU Ning


    The flame propagation of methane-air mixture with various methane concentrations was experimentally investigated at venting flame acceleration tube with quadrate cross section under different obstacles presented. The flame shape and propagation speed was observed by high-speed color video camera. The explosion pressure was determined by piezoelectricity pressure transducers. The results are: The flame propagates in the shape of a hemisphere before the flame reaches the first baffle and flame propagation speed is not more than 15 m/s. When the flame propagates across the baffle, the flame begins to accelerate due to turbulence induced by obstacle.Blockage ratio has relatively greater effect on the flame propagation speed than repeated baffle number does. The flame propagation speed and the pressure at different location along the tube are maximum when methane-air mixture is near the chemical stoichoimetric ratio. The pressure increases with the distance from ignition end at first and the maximum pressure was obtained at the middle of tube, but the pressure decreases and again increases at venting end.

  11. Analysis of flame acceleration induced by wall friction in open tubes

    CERN Document Server

    Akkerman, V'yacheslav; Bychkov, Vitaly; Eriksson, Lars-Erik; 10.1063/1.3425646


    Spontaneous flame acceleration leading to explosion triggering in open tubes/channels due to wall friction was analytically and computationally studied. It was first demonstrated that the acceleration is effected when the thermal expansion across the flame exceeds a critical value depending on the combustion configuration. For the axisymmetric flame propagation in cylindrical tubes with both ends open, a theory of the initial (exponential) stage of flame acceleration in the quasi-isobaric limit was developed and substantiated by extensive numerical simulation of the hydrodynamics and combustion with an Arrhenius reaction. The dynamics of the flame shape, velocity, and acceleration rate, as well as the velocity profile ahead and behind the flame, have been determined.

  12. Experimental study of limit lean methane/air flame in a standard flammability tube using particle image velocimetry method

    Energy Technology Data Exchange (ETDEWEB)

    Shoshin, Yuriy; Gorecki, Grzegorz; Jarosinski, Jozef; Fodemski, Tadeusz [Department of Heat Technology and Refrigeration, Technical University of Lodz, Lodz 90-924 (Poland)


    Lean limit methane/air flame propagating upward in a standard 50 mm diameter and 1.8 m length tube was studied experimentally using particle image velocimetry method. Local stretch rate along the flame front was determined by measured gas velocity distributions. It was found that local stretch rate is maximum at the flame leading point, which is in agreement with earlier theoretical results. Similar to earlier observations, extinction of upward propagating limit flame was observed to start from the flame top. It is stated that the observed behavior of the extinction of the lean limit methane/air flame can not be explained in terms of the coupled effect of flame stretch and preferential diffusion. To qualitatively explain the observed extinction behavior, it is suggested that the positive strain-induced flame stretch increases local radiation heat losses from the flame front. An experimental methodology for PIV measurements in a round tube is described. (author)

  13. Study on peak overpressure and flame propagation speed of gas deflagration in the tube with obstacles

    Institute of Scientific and Technical Information of China (English)


    The on-way peak overpressure and flame propagation speed of gas deflagration in the tube with obstacles are important data for process safety. Based on carbon monoxide deflagration experiments, the paper presents a multi-zone integration model for calculation of on-way peak overpressure, in which the tube with obstacles is considered as a series of venting explosion enclosures which link each others. The analysis of experimental data indicates that the on-way peak overpressure of gas deflagration can be correlated as an empirical formula with equivalence ratio of carbon monoxide oxidation, expansion ratio, flame path length, etc., and that the on-way peak overpressure exhibits a linear relationship with turbulence factor and flame propagation speed. An empirical formula of flame propagation speed is given.

  14. TG-FTIR characterization of flame retardant polyurethane foams materials (United States)

    Liu, W.; Tang, Y.; Li, F.; Ge, X. G.; Zhang, Z. J.


    Dimethyl methylphosphonate (DMMP) and trichloroethyl phosphtate (TCEP) have been used to enhance the flame retardancy of polyurethane foams materials (PUF). Flame retardancy and thermal degradation of PUF samples have been investigated by the LOI tests and thermal analysis. The results indicate that the excellent flame retardancy can be achieved due to the presence of the flame retardant system containing DMMP and TCEP. TG-FTIR reveals that the addition of DMMP/TCEP can not only improve the thermal stability of PUF samples but can also affect the gaseous phase at high temperature.

  15. Variation of pressure limits of flame propagation with tube diameter for various isooctane-oxygen-nitrogen mixtures (United States)

    Spakowski, Adolph, A; Belles, Frank E


    An investigation was made of the change in the pressure limits of flame propagation with tube diameter for various isooctane-oxygen-nitrogen mixtures. Pressure limits were measured in cylindrical glass tubes of four different inside diameters at six different oxygen-nitrogen ratios. Under the experimental conditions, flame propagation was found to be impossible in isooctane-oxygen mixtures with oxygen concentrations less than 11 to 12 percent. Critical tube diameters for flame propagation were calculated and the effect of pressure was determined and compared with the effect of pressure on quenching distance. Critical diameters were related to flame speeds for various isooctane-oxygen-nitrogen mixtures.


    Institute of Scientific and Technical Information of China (English)


    The fibred mangesiun hydroxide from the bracite was treated with a surface active agent. The modified fibred magesium hydroxide as f lame-retardant,boric acid, barium stearate, polydimethyl siloxane fluid,vinyltr iethoxysilane as synergists of the flame-retardant were added to polyene resin. The flame-resistance polyene material prepared meets the requirements of EWCZ -6287-1.

  17. Tube Formation in Nanoscale Materials

    Directory of Open Access Journals (Sweden)

    Yan Chenglin


    Full Text Available Abstract The formation of tubular nanostructures normally requires layered, anisotropic, or pseudo-layered crystal structures, while inorganic compounds typically do not possess such structures, inorganic nanotubes thus have been a hot topic in the past decade. In this article, we review recent research activities on nanotubes fabrication and focus on three novel synthetic strategies for generating nanotubes from inorganic materials that do not have a layered structure. Specifically, thermal oxidation method based on gas–solid reaction to porous CuO nanotubes has been successfully established, semiconductor ZnS and Nb2O5nanotubes have been prepared by employing sacrificial template strategy based on liquid–solid reaction, and an in situ template method has been developed for the preparation of ZnO taper tubes through a chemical etching reaction. We have described the nanotube formation processes and illustrated the detailed key factors during their growth. The proposed mechanisms are presented for nanotube fabrication and the important pioneering studies are discussed on the rational design and fabrication of functional materials with tubular structures. It is the intention of this contribution to provide a brief account of these research activities.

  18. Chemical kinetic simulation of kerosene combustion in an individual flame tube

    Directory of Open Access Journals (Sweden)

    Wen Zeng


    Full Text Available The use of detailed chemical reaction mechanisms of kerosene is still very limited in analyzing the combustion process in the combustion chamber of the aircraft engine. In this work, a new reduced chemical kinetic mechanism for fuel n-decane, which selected as a surrogate fuel for kerosene, containing 210 elemental reactions (including 92 reversible reactions and 26 irreversible reactions and 50 species was developed, and the ignition and combustion characteristics of this fuel in both shock tube and flat-flame burner were kinetic simulated using this reduced reaction mechanism. Moreover, the computed results were validated by experimental data. The calculated values of ignition delay times at pressures of 12, 50 bar and equivalence ratio is 1.0, 2.0, respectively, and the main reactants and main products mole fractions using this reduced reaction mechanism agree well with experimental data. The combustion processes in the individual flame tube of a heavy duty gas turbine combustor were simulated by coupling this reduced reaction mechanism of surrogate fuel n-decane and one step reaction mechanism of surrogate fuel C12H23 into the computational fluid dynamics software. It was found that this reduced reaction mechanism is shown clear advantages in simulating the ignition and combustion processes in the individual flame tube over the one step reaction mechanism.

  19. Sensitive Mid-IR Laser Sensor Development and Mass Spectrometric Measurements in Shock Tube and Flames

    KAUST Repository

    Alquaity, Awad


    With global emission regulations becoming stringent, development of new combustion technologies that meet future emission regulations is essential. In this vein, this dissertation presents the application of sensitive diagnostic tools to validate and improve chemical kinetic mechanisms that play a fundamental role in the design of new combustion technologies. First, a novel high sensitivity laser-based sensor with a wide frequency tuning range (900 – 1000 cm-1) was developed utilizing pulsed cavity ringdown spectroscopy (CRDS) technique. The novel laser-based sensor was illustrated by measuring trace amounts of multiple combustion intermediates, namely ethylene, propene, allene, and 1-butene in a static cell at ambient conditions. Subsequently, pulsed CRDS technique was utilized to develop an ultra-fast, high sensitivity diagnostic to monitor trace concentrations of ethylene in shock tube pyrolysis experiments. This diagnostic represented the first ever successful application of CRDS technique to transient species measurements in a shock tube. The high sensitivity and fast time response (10μs) diagnostic may be utilized for measuring other key neutrals and radicals which are crucial in the oxidation chemistry of practical fuels. Secondly, a quadrupole mass spectrometer (QMS) was employed to measure relative cation mole fractions in atmospheric and low-pressure (30 Torr) flames of methane/oxygen diluted in argon. Lean, stoichiometric and rich flames were 4 examined to evaluate the dependence of ion chemistry on flame stoichiometry. Spatial distribution of cations was compared with predictions of an existing ion chemistry model. Based on the extensive measurements carried out in this work, modifications were suggested to improve the ion chemistry model to enhance the fidelity of such mechanisms. In-depth understanding of flame ion chemistry is vital to model the interaction of flames with electric fields and thereby pave the way to enable active combustion control

  20. Effect of pressure on the lean limit flames of H2-CH4-air mixture in tubes

    KAUST Repository

    Zhou, Zhen


    The lean limit flames of H2-CH4-air mixtures stabilized inside tubes in a downward flow are experimentally and numerically investigated at elevated pressures ranging from 2 to 5 bar. For the shapes of lean limit flames, a change from ball-like flame to cap-like flame is experimentally observed with the increase of pressure. This experimentally observed phenomenon is qualitatively predicted by numerical simulations. The structure of ball-like and cap-like lean limit flames at all tested pressures is analysed in detail based on the numerical predictions. The results show that the lean limit flames are located inside a recirculation zone at all tested pressures. For the leading edges of the lean limit flames at all tested pressures, the fuel transport is controlled by both convection and diffusion. For the trailing edge of the ball-like lean limit flame at 2 bar, the fuel transport is dominated by diffusion. However, with increasing pressure, the transport contribution caused by convection in the trailing edges of the lean limit flames increases. Finally, the influence of transport and chemistry on the predicted ultra lean flames and lean flammability limit is analysed at elevated pressures.

  1. The behavior of fuel-lean premixed flames in a standard flammability limit tube under controlled gravity conditions (United States)

    Wherley, B. L.; Strehlow, R. A.


    Fuel-lean flames in methane-air mixtures from 4.90 to 6.20 volume percent fuel and propane-air mixtures from 1.90 to 3.00 volume percent fuel were studied in the vicinity of the limit for a variety of gravity conditions. The limits were determined and the behavior of the flames studied for one g upward, one g downward, and zero g propagation. Photographic records of all flammability tube firings were obtained. The structure and behavior of these flames were detailed including the variations of the curvature of the flame front, the skirt length, and the occurrence of cellular instabilities with varying gravity conditions. The effect of ignition was also discussed. A survey of flame speeds as a function of mixture strength was made over a range of lean mixture compositions for each of the fuels studied. The results were presented graphically with those obtained by other researchers. The flame speed for constant fractional gravity loadings were plotted as a function of gravity loadings from 0.0 up to 2.0 g's against flame speeds extracted from the transient gravity flame histories for corresponding gravity loadings. The effects of varying gravity conditions on the extinguishment process for upward and downward propagating flames were investigated.

  2. Effects of radiation losses on very lean methane/air flames propagating upward in a vertical tube


    Higuera Antón, Fco. Jose; Muntean, Victor


    The stationary upward propagation of a very lean methane/air flame in a long vertical tube open at the bottom and closed at the top is simulated numerically using a single overall chemical reaction to model combustion and assuming an optically thin gas and a transparent or non-reflecting tube wall to approximately account for radiation losses from CO2CO2 and H2OH2O. Buoyancy plays a dominant role in the propagation of these flames and causes a large region of low velocity of the burnt gas rel...

  3. Plasma-enhanced synthesis of green flame retardant cellulosic materials (United States)

    Totolin, Vladimir

    The natural fiber-containing fabrics and composites are more environmentally friendly, and are used in transportation (automobiles, aerospace), military applications, construction industries (ceiling paneling, partition boards), consumer products, etc. Therefore, the flammability characteristics of the composites based on polymers and natural fibers play an important role. This dissertation presents the development of plasma assisted - green flame retardant coatings for cellulosic substrates. The overall objective of this work was to generate durable flame retardant treatment on cellulosic materials. In the first approach sodium silicate layers were pre-deposited onto clean cotton substrates and cross linked using low pressure, non-equilibrium oxygen plasma. A statistical design of experiments was used to optimize the plasma parameters. The modified cotton samples were tested for flammability using an automatic 45° angle flammability test chamber. Aging tests were conducted to evaluate the coating resistance during the accelerated laundry technique. The samples revealed a high flame retardant behavior and good thermal stability proved by thermo-gravimetric analysis. In the second approach flame retardant cellulosic materials have been produced using a silicon dioxide (SiO2) network coating. SiO 2 network armor was prepared through hydrolysis and condensation of the precursor tetraethyl orthosilicate (TEOS), prior coating the substrates, and was cross linked on the surface of the substrates using atmospheric pressure plasma (APP) technique. Due to protection effects of the SiO2 network armor, the cellulosic based fibers exhibit enhanced thermal properties and improved flame retardancy. In the third approach, the TEOS/APP treatments were extended to linen fabrics. The thermal analysis showed a higher char content and a strong endothermic process of the treated samples compared with control ones, indicating a good thermal stability. Also, the surface analysis proved

  4. Post STS-135 Evaluation of Main Flame Deflector Witness Materials (United States)

    Long, Victoria


    NASA and USA design engineers submitted witness materials from the solid rocket booster (SRB) main flame deflector for evaluation after the launch of STS-135. The following items were submitted for analysis: HY-80 steel witnes rods, 304 sta inles steel caps, and tungsten pistons. All of the items were photographed in order to document their condition after the launch of STS-135. The submitted samples were dimensionally measured in order to determine the amount of material lost during launch. Microstructural changes were observed in the HY-80 witness rod metallographic samples due to the heat of the launch.

  5. Post STS-134 Evaluation of Main Flame Deflector Witness Materials (United States)

    Long, Victoria


    NASA and USA design engineers submitted witness materials from the solid rocket booster (SRB) main flame deflector for evaluation after the launch of STS-134. The following items were submitted for analysis: 1018 steel witness rods 304 stainless steel caps, tungsten pistons, and A-286 piston sleeves. All of the items were photographed in order to document their condition after the launch of STS-134. All of the items were dimensionally measured in order to determine the amount of material lost during launch. Microstructural changes were observed in the 1018 witness rod metallographic samples due to the heat of the launch

  6. Effects of Obstacles on Flame Propagation Behavior and Explosion Overpressure Development During Gas Explosions in a Large Closed Tube

    Institute of Scientific and Technical Information of China (English)

    LI Xiao-dong; BAI Chun-hua; LIU Qing-ming


    AutoReaGas was used for the simulations of premixed gas/air mixtures explosion characteristics in obstacle-filled tubes with a cross-section of 0.2 m×0.2 m and the length of 28 m. Numerical analyses provide a quantitative descripti on of dependence of flame propagation speed and explosion overpressure on obstacles number, blockage ratio and interval distance. Computational results indicate that the obstacles play a significant role in determining the flame transmission speed and explosion overpressure in gas explosions. With the increase of blockage ratio, the explosion overpressure gradually rises. Nevertheless, the flame speed does not always increase along with increasing blockage ratio, but subsequently begins to decrease as the blockage ratio increases to some extend. Also, the interval distance between obstacles strongly influences flame behavior and explosion overpressure. When the obstacle interval distance is equal to inner diameter of the tube, the average flame speed in the obstacle zone and the peak overp ressure in tube all reach maximum values.

  7. Refractory Materials for Flame Deflector Protection System Corrosion Control: Flame Deflector Protection System Life Cycle Cost Analysis Report (United States)

    Calle, Luz Marina; Hintze, Paul E.; Parlier, Christopher R.; Coffman, Brekke E.; Kolody, Mark R.; Curran, Jerome P.; Trejo, David; Reinschmidt, Ken; Kim, Hyung-Jin


    A 20-year life cycle cost analysis was performed to compare the operational life cycle cost, processing/turnaround timelines, and operations manpower inspection/repair/refurbishment requirements for corrosion protection of the Kennedy Space Center launch pad flame deflector associated with the existing cast-in-place materials and a newer advanced refractory ceramic material. The analysis compared the estimated costs of(1) continuing to use of the current refractory material without any changes; (2) completely reconstructing the flame trench using the current refractory material; and (3) completely reconstructing the flame trench with a new high-performance refractory material. Cost estimates were based on an analysis of the amount of damage that occurs after each launch and an estimate of the average repair cost. Alternative 3 was found to save $32M compared to alternative 1 and $17M compared to alternative 2 over a 20-year life cycle.

  8. Multi-tube thermal fuse for nozzle protection from a flame holding or flashback event (United States)

    Lacy, Benjamin Paul; Davis, Jr., Lewis Berkley; Johnson, Thomas Edward; York, William David


    A protection system for a pre-mixing apparatus for a turbine engine, includes: a main body having an inlet portion, an outlet portion and an exterior wall that collectively establish a fuel delivery plenum; and a plurality of fuel mixing tubes that extend through at least a portion of the fuel delivery plenum, each of the plurality of fuel mixing tubes including at least one fuel feed opening fluidly connected to the fuel delivery plenum; at least one thermal fuse disposed on an exterior surface of at least one tube, the at least one thermal fuse including a material that will melt upon ignition of fuel within the at least one tube and cause a diversion of fuel from the fuel feed opening to at least one bypass opening. A method and a turbine engine in accordance with the protection system are also provided.

  9. Built-up Effect of Core Material for Microencapsulated Flame Retardant Containing Dimethyl Methyl Phosphate

    Institute of Scientific and Technical Information of China (English)

    LIN Miao; DONG Kai; YANG Yong


    The flame retardants containing organophosphorus compounds have extensively been used inthe flame retarding of polymer materials.Among others,dimethyl methyl phosphate (DMMP) was applied in flame retarding of polyurethane owmg to its so much merit.However,the water-soluble property of DMMP restricted its application in textile fabric.The flame retardtag systemcontainirm DMMP will be microencapsulated to form a novel flame retardant that could be used in textiles.We have studied the builtup effect of DMMP with some inorganic compounds to improve the afterflame and afterglow suppression in the flame retarding system.The experimeatal data indicated that inorganic compounds containing various non-metal elements P,N,B and metal ions Mg2+,Al3+,Ca2+,Zn2+,Cu2+,Mn4+ could be applied in flame retarding systems as additives to effectively suppress afterflame or afterglow.

  10. Post STS-133 Evaluation of Main Flame Deflector Witness Materials (United States)

    Long, Victoria


    NASA and USA Structures engineers submitted main flame deflector witness materials for evaluation after the launch of STS-133. The following items were submitted for analysis: HY-80 steel witness rods, 304 stainless steel caps, tungsten pistons, 17-4 precipitation hardened (PH) stainless steel and A-286 piston sleeves, Medtherm Corporation calorimeters, and Nanmac Corporation thermocouples. All of the items were photographed in order to document their condition after the launch of STS-133, and before they were reinstalled at the launch pad for future launches. The HY -80 witness rods, 304 stainless steel caps, and the piston sleeves were dimensionally measured in order to determine the amount of material lost during launch. Microstructural changes were observed in the HY-80 witness rod and 304 stainless steel cap metallographic samples due to the heat of the launch.

  11. Numerical Simulation of 3—D Temperature Distribution of the Flame Tube of the Combustion Chamber with Air Film COoling

    Institute of Scientific and Technical Information of China (English)

    ChangHaiping; HuangTaiping; 等


    The wall temperature distribution of the flame tube of the combustion chamber is strongly affected by the combustion,radiation and flow.The interaction of these influential factors froms a coupling system.In this paper,a new method,which is different from the previous methods,has been developed for calcuating the temperature distribution of the flame tube wall together with the flow field inside and outside the flame tube,In the calculation.the combustion,heat radiation,cooling air film and injection stream mixing inside the flame tube as well as the secondary air flowing outside the flame tube have been simulated.The calculation,in this paper,uses the SIMPLE algorithm,the κ-εturbulence model and the auto-adjustable damping method .By using this method ,the 3-D temperature distribution of the floame tube wall of the combustion chamber of an aeroengine has been simulated successfully.The calculation results are compared to the experimetal data.The error of wall temperature is less than 10%.

  12. Methodology for full comparative assessment of direct gross glycerin combustion in a flame tube furnace

    Energy Technology Data Exchange (ETDEWEB)

    Maturana, Aymer Yeferson; Pagliuso, Josmar D. [Dept. of Mechanical Engineering. Sao Carlos School of Engineering. University of Sao Paulo, Sao Carlos, SP (Brazil)], e-mails:,


    This study is to develop a methodology to identify and evaluate the emissions and heat transfer associated to combustion of gross glycerin a by-product of the Brazilian biodiesel manufacture process as alternative energy source. It aims to increase the present knowledge on the matter and to contribute to the improvement of the economic and environmental perspective of biodiesel industry. This methodology was considered to be used for assessment of gross glycerin combustion from three different types of biodiesel (bovine tallow, palm and soy). The procedures for evaluation and quantification of emissions of sulphur and nitrogen oxides, total hydrocarbons, carbon monoxide, carbon dioxide, and acrolein were analyzed, described and standardized. Experimental techniques for mutagenic and toxic effects assessment of gases similarly were analyzed and standardized, as well as the calorific power, the associate heat transfer and fundamentals operational parameters. The methodology was developed, using a full-instrumented flame tube furnace, continuous gas analyzers, a chromatograph, automatic data acquisition systems and other auxiliary equipment. The mutagenic and toxic effects of the study was based on Tradescantia clone KU-20, using chambers of intoxication and biological analytical techniques previously developed and others were specially adapted. The benchmark for the initial set up was based on the performance evaluation of the previous equipment tested with diesel considering its behavior during direct combustion. Finally, the following factors were defined for the combustion of crude glycerin, configurations of equipment types, operational parameters such as air fuel ratio adiabatic temperature and other necessary aspect for successful application of the methodology. The developed and integrated methodology was made available to the concern industry, environmental authorities and researchers as procedures to access the viability of gross glycerin or similar fuels as

  13. Experimental investigation of syngas flame stability using a multi-tube fuel injector in a high pressure combustor (United States)

    Maldonado, Sergio Elzar

    Over 92% of the coal consumed by power plants is used to generate electricity in the United States (U.S.). The U.S. has the world's largest recoverable reserves of coal, it is estimated that reserves of coal will last more than 200 years based in current production and demand levels. Integrated Gasification Combined Cycle (IGCC) power plants aim to reduce the amount of pollutants by gasifying coal and producing synthesis gas. Synthesis gas, also known as syngas, is a product of coal gasification and can be used in gas turbines for energy production. Syngas is primarily a mixture of hydrogen and carbon monoxide and is produced by gasifying a solid fuel feedstock such as coal or biomass. The objective of the thesis is to create a flame stability map by performing various experiments using high-content hydrogen fuels with varying compositions of hydrogen representing different coal feedstocks. The experiments shown in this thesis were performed using the High-Pressure Combustion facility in the Center for Space Exploration Technology Research (CSETR) at the University of Texas at El Paso (UTEP). The combustor was fitted with a novel Multi-Tube fuel Injector (MTI) designed to improve flame stability. This thesis presents the results of testing of syngas fuels with compositions of 20, 30, and 40% hydrogen concentrations in mixtures with carbon monoxide. Tests were completed for lean conditions ranging from equivalence ratios between 0.6 and 0.9. The experimental results showed that at an equivalence ratio of 0.6, a stable flame was not achieved for any of the fuel mixtures tested. It was also observed that the stability region of the syngas flame increased as equivalence ratio and the hydrogen concentration in syngas fuel increases with the 40% hydrogen-carbon monoxide mixture demonstrating the greatest stability region. Design improvements to the MTI are also discussed as part of the future work on this topic.

  14. Determination of trace amount of cadmium using dispersive liquid-liquid microextraction-slotted quartz tube-flame atomic absorption spectrometry (United States)

    Fırat, Merve; Bakırdere, Sezgin; Fındıkoğlu, Maral Selin; Kafa, Emine Betül; Yazıcı, Elif; Yolcu, Melda; Büyükpınar, Çağdaş; Chormey, Dotse Selali; Sel, Sabriye; Turak, Fatma


    This study was performed to develop a sensitive analytical method for the determination of cadmium by slotted quartz tube-flame atomic absorption spectrometry (SQT-FAAS) after dispersive liquid-liquid microextraction (DLLME). The parameters affecting the cadmium complex formation and its extraction output were optimized to obtain high extraction efficiency. These included the pH and amount of the buffer solution, and the concentration of the ligand. The DLLME method was comprehensively optimized based on the type and amount of extraction solvent, dispersive solvent and salt. The type and period of mixing needed for a more effective extraction was also investigated. In order to further improve the sensitivity for the determination of cadmium, the flame atomic absorption spectrometry was fitted with a slotted quartz tube to increase the residence time of cadmium atoms in the pathway of incident light from a hollow cathode lamp. The limits of detection and quantitation (LOD and LOQ) for the FAAS were found to be 42 and 140 μg L- 1, respectively. Under the optimum conditions, LOD and LOQ of the FAAS after DLLME were calculated as 1.3 and 4.4 μg L- 1, respectively. Combining both optimized parameters of the DLLME and SQT-FAAS gave 0.5 and 1.5 μg L- 1 as LOD and LOQ, respectively. Accuracy of the method was also checked using a wastewater certified reference material (EU-L-2), and the result was in good agreement with the certified value.


    Directory of Open Access Journals (Sweden)



    Full Text Available The aim of this investigation is to comprehensively understand the polymeric composite behavior under direct fire sources. The synergistic effects of hybrid flame retardant material on inhabiting the pyrolysis of hybrid reinforced fibers, woven roving (0°- 45° carbon and kevlar (50/50 wt/wt, and an araldite resin composites were studied. The composites were synthesised and coated primarily by zinc borate (2ZnO.3B2O3.3.5H2O and modified by antimony trioxide (Sb2O3 with different amounts (10-30 wt% of flame retardant materials. In the experiments, the composite samples were exposed to a direct flame source generated by oxyacetylene flame (~3000ºC at variable exposure distances of 10-20 mm. The synergic flame retardants role of antimony trioxide and zinc borate on the composite surface noticeably improves the flame resistance of the composite which is attributed to forming a protective mass and heat barrier on the composite surface and increasing the melt viscosity.

  16. Cladding material, tube including such cladding material and methods of forming the same (United States)

    Garnier, John E.; Griffith, George W.


    A multi-layered cladding material including a ceramic matrix composite and a metallic material, and a tube formed from the cladding material. The metallic material forms an inner liner of the tube and enables hermetic sealing of thereof. The metallic material at ends of the tube may be exposed and have an increased thickness enabling end cap welding. The metallic material may, optionally, be formed to infiltrate voids in the ceramic matrix composite, the ceramic matrix composite encapsulated by the metallic material. The ceramic matrix composite includes a fiber reinforcement and provides increased mechanical strength, stiffness, thermal shock resistance and high temperature load capacity to the metallic material of the inner liner. The tube may be used as a containment vessel for nuclear fuel used in a nuclear power plant or other reactor. Methods for forming the tube comprising the ceramic matrix composite and the metallic material are also disclosed.

  17. Evaluation of quartz tubes as atomization cells for gold determination by thermospray flame furnace atomic absorption spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Morzan, Ezequiel; Piano, Ornela; Stripeikis, Jorge; Tudino, Mabel, E-mail:


    This work describes the development of a new analytical procedure able to determine gold by thermospray flame furnace atomic absorption spectrometry (TS-FF-AAS) using nickel tubes (NiT) and quartz tubes (QT) as atomization cells. Experiments involving changes in the flow injection operational parameters, reagent concentrations and sizes of the QT were performed in order to optimize sensitivity. Under the same operational conditions, it was observed that the employment of QT increases the sensitivity of gold determination when compared to the nickel tube. Since solutions of highly concentrated hydrochloric acid showed the best performance as carriers, quartz tubes were also preferred due to its greater tolerance to corrosion by mineral acids in comparison to NiT. In addition, changes in the internal diameter of the QT revealed an important improvement in sensitivity for smaller tubes. Under optimized conditions the main figures of merit showed values close to that of graphite furnace atomic absorption spectrometry with the addition of an excellent improvement of the sample throughput. They are: LOD (3 s): 0.004 {mu}g mL{sup -1}, sensitivity: 0.306 ({mu}g mL{sup -1}){sup -1}, RSD% (n = 10, 1 {mu}g mL{sup -1}): 2.5, linear range: 0.01-4 {mu}g mL{sup -1} and sample throughput: 72 h{sup -1}. This new method was employed for the determination of gold in homeopathic medicines with no need of sample digestion. Validation of the analytical results will be shown. A full discussion of the most relevant findings regarding the role of the atomization cell as a strategic key for improving sensitivity will be also provided. - Highlights: Black-Right-Pointing-Pointer Quartz tubes as furnaces in TS-FFAAS. Black-Right-Pointing-Pointer Small tubes for controlling radial dispersion. Black-Right-Pointing-Pointer Improved figures of merit for gold determination. Black-Right-Pointing-Pointer Analysis of homeopathic medicines.

  18. Effect of pointed and diffused air injection on premixed flame confined in a Rijke tube

    Directory of Open Access Journals (Sweden)

    Nilaj N. Deshmukh


    Full Text Available The coupling between pressure fluctuations and unsteady heat release in a combustion systems results in acoustic oscillations inside the combustion system. These acoustic oscillations, when grow sufficiently, may cause serious structural damage thereby reducing the lifespan of jet engines, gas turbines, and industrial burners. The aim of the first part of study is to define acoustically stable and unstable regions. The second part is focused on studying the effect of change in pressure field near the flame on the amplitude and frequency of the oscillations of instability. This study is carried out for three-burner positions and equivalence ratio of 0.7 by varying heat supply and total flow rate. The results show two acoustically unstable regions for 0.1 and 0.2 burner positions and only one acoustically unstable region for 0.25 burner position. The effect of pointed injection and diffused injection over a premixed flame on the sound pressure level was studied. The results show for burner position of x/L = 0.2 there is 25 dB suppression is possible using pointed injection at higher total flow rate. The experiment of diffused injection shows sound amplification more than 12 dB was observed.

  19. Refractory Materials for Flame Deflector Protection System Corrosion Control: Coatings Systems Literature Survey (United States)

    Calle, Luz M.; Hintze, Paul E.; Parlier, Christopher R.; Sampson, Jeffrey W.; Coffman, Brekke E.; Coffman, Brekke E.; Curran, Jerome P.; Kolody, Mark R.; Whitten, Mary; Perisich, Steven; Trejo, David


    When space vehicles are launched, extreme heat, exhaust, and chemicals are produced and these form a very aggressive exposure environment at the launch complex. The facilities in the launch complex are exposed to this aggressive environment. The vehicle exhaust directly impacts the flame deflectors, making these systems very susceptible to high wear and potential failure. A project was formulated to develop or identify new materials or systems such that the wear and/or damage to the flame deflector system, as a result of the severe environmental exposure conditions during launches, can be mitigated. This report provides a survey of potential protective coatings for the refractory concrete lining on the steel base structure on the flame deflectors at Kennedy Space Center (KSC).

  20. Material modeling for multistage tube hydroforming process simulation (United States)

    Saboori, Mehdi

    The Aerospace industries of the 21st century demand the use of cutting edge materials and manufacturing technology. New manufacturing methods such as hydroforming are relatively new and are being used to produce commercial vehicles. This process allows for part consolidation and reducing the number of parts in an assembly compared to conventional methods such as stamping, press forming and welding of multiple components. Hydroforming in particular, provides an endless opportunity to achieve multiple crosssectional shapes in a single tube. A single tube can be pre-bent and subsequently hydroformed to create an entire component assembly instead of welding many smaller sheet metal sections together. The knowledge of tube hydroforming for aerospace materials is not well developed yet, thus new methods are required to predict and study the formability, and the critical forming limits for aerospace materials. In order to have a better understanding of the formability and the mechanical properties of aerospace materials, a novel online measurement approach based on free expansion test is developed using a 3D automated deformation measurement system (AramisRTM) to extract the coordinates of the bulge profile during the test. These coordinates are used to calculate the circumferential and longitudinal curvatures, which are utilized to determine the effective stresses and effective strains at different stages of the tube hydroforming process. In the second step, two different methods, a weighted average method and a new hardening function are utilized to define accurately the true stress-strain curve for post-necking regime of different aerospace alloys, such as inconel 718 (IN 718), stainless steel 321 (SS 321) and titanium (Ti6Al4V). The flow curves are employed in the simulation of the dome height test, which is utilized for generating the forming limit diagrams (FLDs). Then, the effect of stress triaxiality, the stress concentration factor and the effective plastic

  1. Screening for halogenated flame retardants in European consumer products, building materials and wastes. (United States)

    Vojta, Šimon; Bečanová, Jitka; Melymuk, Lisa; Komprdová, Klára; Kohoutek, Jiří; Kukučka, Petr; Klánová, Jana


    To fulfill national and international fire safety standards, flame retardants (FRs) are being added to a wide range of consumer products and building materials consisting of flammable materials like plastic, wood and textiles. While the FR composition of some products and materials has been identified in recent years, the limited global coverage of the data and the large diversity in consumer products necessitates more information for an overall picture of the FR composition in common products/materials. To address this issue, 137 individual samples of various consumer products, building materials and wastes were collected. To identify and characterize potential sources of FRs in indoor environment, all samples were analyzed for content of polybrominated diphenyl ethers (PBDEs), hexabromocyclododecanes (HBCDDs) and novel flame retardants (NFRs). The most frequently detected were HBCDDs (85%), with the highest median concentration of Σ4HBCDDs of 300 mg kg(-1) in polystyrenes. The highest median concentration of Σ10PBDEs was found in recycled plastic materials, reaching 4 mg kg(-1). The lowest concentrations were observed for NFRs, where the median of Σ12NFRs reached 0.4 mg kg(-1) in the group of electrical & electronic equipment wastes. This suggests that for consumer products and building materials that are currently in-use, legacy compounds still contribute to the overall burden of FRs. Additionally, contrasting patterns of FR composition in recycled and virgin plastics, revealed using principle component analysis (PCA), suggest that legacy flame retardants are reentering the market through recycled products, perpetuating the potential for emissions to indoor environments and thus for human exposure. Copyright © 2016 Elsevier Ltd. All rights reserved.

  2. Combustion of porous energetic materials in the merged-flame regime

    Energy Technology Data Exchange (ETDEWEB)

    Margolis, S.B. [Sandia National Labs., Livermore, CA (United States). Combustion Research Facility; Williams, F.A.; Telengator, A.M. [Univ. of California, San Diego, La Jolla, CA (United States). Dept. of Applied Mechanics and Engineering Sciences


    The structure and burning rate of an unconfined deflagration propagating through a porous energetic material is analyzed in the limit of merged condensed and gas-phase reaction zones. A global two-step reaction mechanism, applicable to certain types of degraded nitramine propellants and consisting of sequential condensed and gaseous steps, is postulated. Taking into account important effects due to multiphase flow and exploiting the limit of large activation energies, a theoretical analysis based on activation energy asymptotics leads to explicit formulas for the deflagration velocity in a specifically identified regime that is consistent with the merged-flame assumption. The results clearly indicate the influences of two-phase flow and the multiphase, multi-step chemistry on the deflagration structure and the burning rate, and define conditions that support the intrusion of the primary gas flame into the two-phase condensed decomposition region at the propellant surface.

  3. 无卤阻燃电缆料的研究现状%Research Status of Halogen-free Flame Retardant Cable Material

    Institute of Scientific and Technical Information of China (English)

    关健; 虞鑫海


    主要从氢氧化物阻燃体系、磷系阻燃体系、膨胀型阻燃体系、有机硅阻燃体系、硼系阻燃体系和纳米阻燃体系等方面综述了无卤阻燃电缆料的研究与应用现状,并展望了电缆料无卤阻燃技术的发展方向。%The recent research and application status of halogen-free flame retardant cable material were reviewed from hydroxide flame retardant system, phosphorus flame retardant system, intumescent flame re-tardant system, silicone flame retardant system, boron flame retardant system and nano flame retardant system. The development direction of halogen-free flame retardant cable material was proposed.

  4. Lead determination at ng/mL level by flame atomic absorption spectrometry using a tantalum coated slotted quartz tube atom trap. (United States)

    Demirtaş, İlknur; Bakırdere, Sezgin; Ataman, O Yavuz


    Flame atomic absorption spectrometry (FAAS) still keeps its importance despite the relatively low sensitivity; because it is a simple and economical technique for determination of metals. In recent years, atom traps have been developed to increase the sensitivity of FAAS. Although the detection limit of FAAS is only at the level of µg/mL, with the use of atom traps it can reach to ng/mL. Slotted quartz tube (SQT) is one of the atom traps used to improve sensitivity. In atom trapping mode of SQT, analyte is trapped on-line in SQT for few minutes using ordinary sample aspiration, followed by the introduction of a small volume of organic solvent to effect the revolatilization and atomization of analyte species resulting in a transient signal. This system is economical, commercially available and easy to use. In this study, a sensitive analytical method was developed for the determination of lead with the help of SQT atom trapping flame atomization (SQT-AT-FAAS). 574 Fold sensitivity enhancement was obtained at a sample suction rate of 3.9 mL/min for 5.0 min trapping period with respect to FAAS. Organic solvent was selected as 40 µL of methyl isobutyl ketone (MIBK). To obtain a further sensitivity enhancement inner surface of SQT was coated with several transition metals. The best sensitivity enhancement, 1650 fold enhancement, was obtained by the Ta-coated SQT-AT-FAAS. In addition, chemical nature of Pb species trapped on quartz and Ta surface, and the chemical nature of Ta on quartz surface were investigated by X-ray photoelectron spectroscopy (XPS) and Raman Spectroscopy. Raman spectrometric results indicate that tantalum is coated on SQT surface in the form of Ta2O5. XPS studies revealed that the oxidation state of Pb in species trapped on both bare and Ta coated SQT surfaces is +2. For the accuracy check, the analyses of standard reference material were performed by use of SCP SCIENCE EnviroMAT Low (EU-L-2) and results for Pb were to be in good agreement with

  5. New Regenerator Materials for use in pulse tube coolers

    Energy Technology Data Exchange (ETDEWEB)

    A. Kashani; B.P.M. Helvensteijn; P. Kittel; K.A. Gschneidner,jr; V.K. Pecharsky; A.O. Pecharsky


    A two-stage pulse tube cooler driven by a linear compressor is being developed to provide cooling at 20 K. The first stage of the cooler will have the conventional stainless steel screen regenerator matrix. The matrix for the second stage regenerator (<60 K) will be made from a new class of Er based alloys which was recently developed at Ames Laboratory, in Ames, Iowa. These alloys exhibit heat capacities that exceed that of all other materials, including lead, over a Wide range in temperature (15 K < T C 85 K). The performance of one such alloy was shown to be better than lead when tested in a single-stage pulse tube cooler driven by a G-M compressor and operating at 2 Hz. An effort is underway to establish their suitability at frequencies above 40 IIZ. An approach to testing these alloys at low temperatures while using a low-power linear compressor is presented.

  6. Refractory Materials for Flame Deflector Protection System Corrosion Control: Refractory Ceramics Literature Survey (United States)

    Calle, Luz Marina; Hintze, Paul E.; Parlier, Christopher R.; Curran, Jerome P.; Kolody, Mark; Perusich, Stephen; Whitten, Mary C.; Trejo, David; Zidek, Jason; Sampson, Jeffrey W.; Coffman, Brekke E.


    Ceramics can be defmed as a material consisting of hard brittle properties produced from inorganic and nonmetallic minerals made by firing at high temperatures. These materials are compounds between metallic and nonmetallic elements and are either totally ionic, or predominately ionic but having some covalent character. This definition allows for a large range of materials, not all applicable to refractory applications. As this report is focused on potential ceramic materials for high temperature, aggressive exposure applications, the ceramics reviewed as part of this report will focus on refractory ceramics specifically designed and used for these applications. Ceramic materials consist of a wide variety of products. Callister (2000) 1 characterized ceramic materials into six classifications: glasses, clay products, refractories, cements, abrasives, and advanced ceramics. Figure 1 shows this classification system. This review will focus mainly on refractory ceramics and cements as in general, the other classifications are neither applicable nor economical for use in large structures such as the flame trench. Although much work has been done in advanced ceramics over the past decade or so, these materials are likely cost prohibitive and would have to be fabricated off-site, transported to the NASA facilities, and installed, which make these even less feasible. Although the authors reviewed the literature on advanced ceramic refractories 2 center dot 3 center dot 4 center dot 5 center dot 6 center dot 7 center dot 8 center dot 9 center dot 10 center dot 11 center dot 12 after the review it was concluded that these materials should not be ' the focus of this report. A review is in progress on materials and systems for prefabricated refractory ceramic panels, but this review is focusing more on typical refractory materials for prefabricated systems, which could make the system more economically feasible. Refractory ceramics are used for a wide variety of applications

  7. Mechanical Properties of Heat Exchanger Tube Materials at Elevated Temperatures (United States)

    Kahl, Sören; Zajac, Jozefa; Ekström, Hans-Erik

    Since automotive heat exchangers are operated at elevated temperatures and under varying pressures, both static and dynamic mechanical properties should be known at the relevant temperatures. We have collected elevated-temperature tensile test data, elevated-temperature stress amplitude-fatigue life data, and creep-rupture data in a systematic fashion over the past years. For thin, soft, and braze-simulated heat exchanger tube materials tested inside closed furnaces, none of the well-established methods for crack detection and observation can be applied. In our contribution, we present a simple statistical method to estimate the time required for crack initiation.

  8. Thermally-induced transformation of hexabromocyclo dodecanes and isobutoxypenta bromocyclododecanes in flame-proofed polystyrene materials. (United States)

    Heeb, Norbert V; Graf, Heidi; Schweizer, W Bernd; Lienemann, P


    Polystyrenes (PS) are produced in quantities exceeding 10 Mt y(-1). They are used for insulation and packaging materials, often in flame-proofed forms with hexabromocyclododecanes (HBCDs) added as flame retardants. Polystyrenes are also constituents of plastic debris found in the aquatic environment. HBCDs are now considered as persistent, bioaccumulative, and toxic compounds. Lately, we reported that isobutoxypenta bromocyclododecanes (iBPBCDs), a formerly unknown class of polybrominated compounds, are also present in flame-proofed polystyrenes. It is therefore likely that iBPBCDs are released along with HBCDs from these materials. Herein, we report on changes of the HBCD- and iBPBCD-patterns when exposing expanded (EPS) and extruded (XPS) polystyrenes at temperatures of 140-160 degrees C. Substantial transformation reactions were observed in EPS, which was rich in gamma-HBCDs and delta-, eta-, and theta-iBPBCDs at the beginning, but changed to materials rich in alpha-HBCDs and alpha-, beta-, epsilon-, and xi-iBPBCDs. Patterns of untreated XPS already resembled those of the thermally treated EPS. Upon thermal exposure, some further enrichment of alpha-HBCDs and alpha-, beta-, epsilon-, and xi-iBPBCDs was also noticed for the XPS samples, indicating similar transformation mechanisms. Comparable apparent first-order transformation rate constants (k(trans)) of -0.003, -0.008, and -0.020 min(-1) and -0.004, -0.009, and -0.019 min(-1) are found for gamma-HBCD- and delta-iBPBCD-conversion at 140, 150, and 160 degrees C, respectively. We conclude that a thermal treatment of flame-proofed polystyrenes alters their HBCD- and iBPBCD-patterns. Thus depending on the proportions of EPS and XPS materials reaching the environment, more of the lipophilic (late-eluting) or of the more polar (early-eluting) HBCD- and iBPBCD-stereoisomers will be released. Several properties such as partitioning coefficients, degradation rates, and bioaccumulation factors are stereoisomer

  9. Characterization of organophosphorus flame retardants' sorption on building materials and consumer products (United States)

    Liu, Xiaoyu; Allen, Matthew R.; Roache, Nancy F.


    Better understanding the transport mechanisms of organophosphorus flame-retardants (OPFRs) in the residential environment is important to more accurately estimate their indoor exposure and develop risk management strategies that protect human health. This study describes an improved dual small chamber testing method to characterize the sorption of OPFRs on indoor building materials and consumer products. The OPFRs studied were tris(2-chloroethyl) phosphate (TCEP), tris(1-chloro-2-propyl) phosphate (TCIPP), and tris(1,3-dichloro-2-propyl) phosphate (TDCIPP). The test materials and products used as sinks include concrete, ceiling tile, vinyl flooring, carpet, latex painted gypsum wallboard, open cell polyurethane foam, mattress pad and liner, polyester clothing, cotton clothing, and uniform shirt. During the tests, the amount of OPFRs absorbed by the materials at different exposure times was determined simultaneously. OPFRs air concentrations at the inlet and inside the test chamber were monitored. The data were used to rank the sorption strength of the OPFRs on different materials. In general, building materials exhibited relatively stronger sorption strength than clothing textiles. The material-air partition and material phase diffusion coefficients were estimated by fitting a sink model to the sorption concentration data for twelve materials with three OPFRs. They are in the range of 2.72 × 105 to 3.99 × 108 (dimensionless) for the material-air partition coefficients and 1.13 × 10-14 to 5.83 × 10-9 (m2/h) for the material phase diffusion coefficients.

  10. A Versatile and Scalable Approach toward Robust Superhydrophobic Porous Materials with Excellent Absorbency and Flame Retardancy (United States)

    Ruan, Changping; Shen, Mengxia; Ren, Xiaoyan; Ai, Kelong; Lu, Lehui


    The frequent oil spillages and the industrial discharge of organic contaminants have not only created severe environmental and ecological crises, but also cause a risk of fire and explosion. These environmental and safety issues emphasize the urgent need for materials that possess superior sorption capability and less flammability and thus can effectively and safely clean up the floating oils and water-insoluble organic compounds. Here we present the successful hydrophobic modification of the flame retardant melamine sponge with a commercial fluorosilicone, by using a facile one-step solvent-free approach and demonstrate that the resultant superhydrophobic sponge not only exhibits extraordinary absorption efficiency (including high capacity, superior selectivity, good recyclability, and simple recycling routes), but also retains excellent flame retardancy and robust stability. In comparison to conventional methods, which usually utilize massive organic solvents, the present approach does not involve any complicated process or sophisticated equipment nor generates any waste liquids, and thus is a more labor-saving, environment-friendly, energy-efficient and cost-effective strategy for the hydrophobic modification. Taking into account the critical role of hydrophobic porous materials, especially in the field of environmental remediation, the approach presented herein would be highly valuable for environmental remediation and industrial applications.

  11. Influence of radiation-crosslinking on flame retarded polymer materials-How crosslinking disrupts the barrier effect (United States)

    Sonnier, Rodolphe; Caro-Bretelle, Anne-Sophie; Dumazert, Loïc; Longerey, Marc; Otazaghine, Belkacem


    Fire behavior of flame retardant-free and flame retarded PP/PA6 blends was studied using pyrolysis-combustion flow calorimeter, cone calorimeter and epiradiator equipped with infrared camera and pyrometer. Blends were previously γ-irradiated in presence of crosslinking agents at various doses (up to 100 kGy) in order to assess the influence of irradiation crosslinking on flame retardancy. Crosslinked specimens exhibit a solid-like behavior under high temperature gradient in cone calorimeter and then distort considerably. The influence of such a behavior depends on the material properties. When the flame retardancy is provided by heat shielding effect, heat distortion disrupts the top protective layer leading to a substantial increase of peak of heat release rate (pHRR). The barrier layer is no longer able to prevent the heat transfer to the underlying condensed phase. In other cases (flame retardant-free blends or flame retardancy provided by other effects than heat shielding), heat distortion has negligible influence on heat release rate curves in cone calorimeter tests.

  12. Matrix effects on the determination of manganese in geological materials by atomic-absorption spectrophotometry under different flame conditions (United States)

    Sanzolone, R.F.; Chao, T.T.


    Suppression caused by five of the seven matrix elements studied (Si, Al, Fe, Ca and Mg) was observed in the atomic-absorption determination of manganese in geological materials, when synthetic solutions and the recommended oxidizing air-acetylene flame were used. The magnitude of the suppression effects depends on (1) the kind and concentration of the interfering elements, (2) the type of acid medium, and (3) the concentration of manganese to be determined. All interferences noted are removed or alleviated by using a reducing nitrous oxide-acetylene flame. The atomic-absorption method using this flame can be applied to the determination of total and extractable manganese in a wide range of geological materials without interferences. Analyses of six U.S. Geological Survey rock standards for manganese gave results in agreement with the reported values. ?? 1978.

  13. Cathode materials produced by spray flame synthesis for lithium ion batteries

    Energy Technology Data Exchange (ETDEWEB)

    Hamid, NoorAshrina Binti A.


    Lithium ion batteries are one of the most enthralling rechargeable energy storage systems for portable application due to their high energy density. Nevertheless, with respect to electromobility innovation towards better electrochemical properties such as higher energy and power density is required. Altering the cathode material used in Li-ion batteries is favorable since the mass- and volume performance is closely related to the cathode electrode mass. Instead of using LiCoO{sub 2} as cathode electrode, LiFePO{sub 4} has gained serious attention as this material owns a high theoretical capacity of 170 mAh g{sup -1}. It is non-toxic, cheap and consists of abundant materials but suffers from low electronic and ionic conductivity. Utilization of nanotechnology methods in combination with composite formation is known to cure this problem effectively. In this work, a new combination of techniques using highly scalable gas-phase synthesis namely spray-flame synthesis and subsequent solid-state reaction has been used to synthesize nanocomposite LiFePO{sub 4}/C. At first this work deals with the formation and characterization of nanosize FePO{sub 4} from a solution of iron(III)acetylacetonate and tributyl phosphate in toluene using spray-flame synthesis. It was shown that a subsequent solid state reaction with Li{sub 2}CO{sub 3} and glucose yielded a LiFePO{sub 4}/C nanocomposite with very promising electrochemical properties. Based on these initial findings the influence of two synthesis parameter - carbon content and annealing temperature - was investigated towards the physicochemical properties of LiFePO{sub 4}/C. It was shown that an annealing temperature of 700 C leads to high purity composite materials consisting of crystalline LiFePO{sub 4} with crystallite sizes well below 100 nm and amorphous carbon consisting of disordered and graphite-like carbon. Variation of glucose amount between 10 and 30 wt% resulted in carbon contents between 2.1 and 7.3 wt%. In parallel

  14. Design of water shock tube for testing shell materials


    Ji, Hongjuan; Mustafa, Mohamad; Khawaja, Hassan Abbas; Ewan, Bruce C.; Moatamedi, Mojtaba


    This paper presents design considerations for a shock tube experimental rig used to investigate the dynamic failure mechanisms of shell geometries subjected to water shock impact loading. In such setup, it is desirable that the drive pressure used within the tube can provide a wide range of impulsive loads on the test structures and some flexibility can be achieved on the applied pulse durations. With this aim a review of various existing shock tube experimental setup is presented and choi...

  15. Corrosion-resistant tube materials for extended life of openings in recovery boilers

    Energy Technology Data Exchange (ETDEWEB)

    Paul, L.D.; Danielson, M.J.; Harper, S.L. (Babcock and Wilcox Co., Alliance, OH (United States). Research and Development Div.); Barna, J.L. (Babcock and Wilcox Co., Barberton, OH (United States). Fossil Power Div.)


    The corrosive conditions causing rapid corrosion of Type 304L stainless steel in tube openings have been duplicated in the laboratory. Alternate materials also have been tested, and some show improved corrosion resistance over Type 304L. Alloy 825 and Alloy 625 composite tubing and Alloy 600 and Alloy 625 weld overlay materials all show promise as a replacement for Type 304L in tube openings. All recovery boilers designed or operated at 8.375 MPa (1,200 psi) and above should consider using these replacement materials for tube openings.

  16. Supplementary Material for: Measurements of Positively Charged Ions in Premixed Methane-Oxygen Atmospheric Flames

    KAUST Repository

    Alquaity, Awad B. S.


    Cations and anions are formed as a result of chemi-ionization processes in combustion systems. Electric fields can be applied to reduce emissions and improve combustion efficiency by active control of the combustion process. Detailed flame ion chemistry models are needed to understand and predict the effect of external electric fields on combustion plasmas. In this work, a molecular beam mass spectrometer (MBMS) is utilized to measure ion concentration profiles in premixed methane–oxygen argon burner-stabilized atmospheric flames. Lean and stoichiometric flames are considered to assess the dependence of ion chemistry on flame stoichiometry. Relative ion concentration profiles are compared with numerical simulations using various temperature profiles, and good qualitative agreement was observed for the stoichiometric flame. However, for the lean flame, numerical simulations misrepresent the spatial distribution of selected ions greatly. Three modifications are suggested to enhance the ion mechanism and improve the agreement between experiments and simulations. The first two modifications comprise the addition of anion detachment reactions to increase anion recombination at low temperatures. The third modification involves restoring a detachment reaction to its original irreversible form. To our knowledge, this work presents the first detailed measurements of cations and flame temperature in canonical methane–oxygen-argon atmospheric flat flames. The positive ion profiles reported here may be useful to validate and improve ion chemistry models for methane-oxygen flames.

  17. Crack resistance curves determination of tube cladding material (United States)

    Bertsch, J.; Hoffelner, W.


    Zirconium based alloys have been in use as fuel cladding material in light water reactors since many years. As claddings change their mechanical properties during service, it is essential for the assessment of mechanical integrity to provide parameters for potential rupture behaviour. Usually, fracture mechanics parameters like the fracture toughness KIC or, for high plastic strains, the J-integral based elastic-plastic fracture toughness JIC are employed. In claddings with a very small wall thickness the determination of toughness needs the extension of the J-concept beyond limits of standards. In the paper a new method based on the traditional J approach is presented. Crack resistance curves (J-R curves) were created for unirradiated thin walled Zircaloy-4 and aluminium cladding tube pieces at room temperature using the single sample method. The procedure of creating sharp fatigue starter cracks with respect to optical recording was optimized. It is shown that the chosen test method is appropriate for the determination of complete J-R curves including the values J0.2 (J at 0.2 mm crack length), Jm (J corresponding to the maximum load) and the slope of the curve.

  18. 汽车内饰材料的阻燃性研究现状%Flame Retardancy Research Status of Automotive Interior Materials

    Institute of Scientific and Technical Information of China (English)

    陈俊洁; 何勇; 黄胜; 梁列峰


    介绍了阻燃理论和国内外汽车内饰材料的阻燃研究现状,概述了汽车内饰阻燃材料、阻燃整理剂开发和阻燃整理等技术措施,以及汽车内饰材料阻燃研究发展方向。%The theory of flame retardant and domestic and international flame retardant research status of automotive interior material were introduced. The automotive interior fire-retardant materials, development of flame retardant and flame retardant finishing were summarized, and the development trends of automotive interior materials flame retardant in the future were proposed.

  19. Packaging material and flexible medical tubing containing thermally exfoliated graphite oxide (United States)

    Prud'homme, Robert K. (Inventor); Aksay, Ilhan A. (Inventor)


    A packaging material or flexible medical tubing containing a modified graphite oxide material, which is a thermally exfoliated graphite oxide with a surface area of from about 300 m.sup.2/g to 2600 m.sup.2/g.

  20. A Versatile and Scalable Approach toward Robust Superhydrophobic Porous Materials with Excellent Absorbency and Flame Retardancy

    National Research Council Canada - National Science Library

    Ruan, Changping; Shen, Mengxia; Ren, Xiaoyan; Ai, Kelong; Lu, Lehui


    ... oils and water-insoluble organic compounds. Here we present the successful hydrophobic modification of the flame retardant melamine sponge with a commercial fluorosilicone, by using a facile one-step solvent-free approach and demonstrate...

  1. The initial development of a tulip flame

    Energy Technology Data Exchange (ETDEWEB)

    Matalon, M.; Mcgreevy, J.L. [Northwestern Univ., Evanston, IL (United States)


    The initial development of a ``tulip flame``, often observed during flame propagation in closed tubes, is attributed to a combustion instability. The roles of hydrodynamic and of the diffusional-thermal processes on the onset of instability are investigated through a linear stability analysis in which the growth or decay of small disturbances, superimposed on an otherwise smooth and planar flame front, are followed. A range of the Markstein parameter, related to the mixture composition through an appropriately defined Lewis number, has been identified where a tulip flame could be observed. For a given value of the Markstein parameter within this range, a critical wavelength is identified as the most unstable mode. This wavelength is directly related to the minimal aspect ratio of the tube where a tulip flame could be observed. The time of onset of instability is identified as the time when the most unstable disturbance, associated with the critical wavelength, grows at a faster rate than the flame front itself and exceeds a certain threshold. This occurs after the flame has propagated a certain distance down the tube: a value which has been explicitly determined in terms of the relevant parameters. Experimental records on the tulip flame phenomenon support the finding of the analysis. That is, the tulip flame forms after the flame has traveled half the tube`s length, it does not form in short tubes, and its formation depends on the mixture composition and on the initial pressure in the tube.

  2. Study on High Temperature Regions of Annular Flame Tube and Flow Field of Near Wall Regions%火焰筒壁高温区与近壁区流场的数值模拟研究

    Institute of Scientific and Technical Information of China (English)

    杨芳芳; 吉洪湖; 郑妹; 张勃; 胡娅萍


    航空发动机火焰筒的大孔包括主燃孔和掺混孔,将多斜孔壁冷却方式应用到真实环形燃烧室的火焰筒壁上,运用CFD软件,通过数值模拟的方式,计算研究整个燃烧室的温度分布,特别考虑了火焰筒壁温的分布,对近壁区的流场进行计算研究.研究分析表明:内外环壁热侧大部分区域温度都保持在1 000 K~1 100K,在材料的长期许用温度范围内;同时针对外环壁主燃孔和掺混孔附近的局部高温点,提出冷却方案,改善了近壁区的流场分布,对改善高温点起到了很好的效果,最大幅度降低达13.2%,壁面温度更加均匀,对降低热应力水平,延长火焰筒使用寿命有利.%The big holes of Aero- engine combustor liner include primary holes and dilution holes,this paper applied the effusion- cooling method into the real annular flame tube. With the help of the CFD software , numerical simulation was carried out to investigate on the temperature distribution of the whole combustor, especially of the liners, including flow fields of near wall regions. The result shows that the temperature of most regions of outer and inner liners on the hot side is from 1 000 K to 1 100 K,which is in the material's long- term allowable temperature range. And cooling scheme was put forward considered on hot spots behind the primary holes and dilution holes on the outer liner, which changed the flow of the near wall regions,and effectively improved the hot spots. The most decreasing range of the highest temperature is 13.2% ,and more uniform wall temperature makes thermal stress level reduced and the service life of flame tubes extended.

  3. Nitrogen-doped carbon nanoparticles by flame synthesis as anode material for rechargeable lithium-ion batteries. (United States)

    Bhattacharjya, Dhrubajyoti; Park, Hyean-Yeol; Kim, Min-Sik; Choi, Hyuck-Soo; Inamdar, Shaukatali N; Yu, Jong-Sung


    Nitrogen-doped turbostratic carbon nanoparticles (NPs) are prepared using fast single-step flame synthesis by directly burning acetonitrile in air atmosphere and investigated as an anode material for lithium-ion batteries. The as-prepared N-doped carbon NPs show excellent Li-ion stoarage properties with initial discharge capacity of 596 mA h g(-1), which is 17% more than that shown by the corresponding undoped carbon NPs synthesized by identical process with acetone as carbon precursor and also much higher than that of commercial graphite anode. Further analysis shows that the charge-discharge process of N-doped carbon is highly stable and reversible not only at high current density but also over 100 cycles, retaining 71% of initial discharge capacity. Electrochemical impedance spectroscopy also shows that N-doped carbon has better conductivity for charge and ions than that of undoped carbon. The high specific capacity and very stable cyclic performance are attributed to large number of turbostratic defects and N and associated increased O content in the flame-synthesized N-doped carbon. To the best of our knowledge, this is the first report which demonstrates single-step, direct flame synthesis of N-doped turbostratic carbon NPs and their application as a potential anode material with high capacity and superior battery performance. The method is extremely simple, low cost, energy efficient, very effective, and can be easily scaled up for large scale production.

  4. Preparation and properties of flexible flame-retardant neutron shielding material based on methyl vinyl silicone rubber

    Energy Technology Data Exchange (ETDEWEB)

    Chai, Hao [Department of Nuclear Science & Engineering, Nanjing University of Aeronautics and Astronautics, Nanjing (China); Tang, Xiaobin, E-mail: [Department of Nuclear Science & Engineering, Nanjing University of Aeronautics and Astronautics, Nanjing (China); Jiangsu Key Laboratory of Nuclear Energy Equipment Materials Engineering (China); Ni, Minxuan; Chen, Feida; Zhang, Yun [Department of Nuclear Science & Engineering, Nanjing University of Aeronautics and Astronautics, Nanjing (China); Chen, Da [Department of Nuclear Science & Engineering, Nanjing University of Aeronautics and Astronautics, Nanjing (China); Jiangsu Key Laboratory of Nuclear Energy Equipment Materials Engineering (China); Qiu, Yunlong [ZhongXing Energy Equipment Co., LTD, Haimen Nantong (China)


    Flexible flame-retardant composites were prepared using high-functional methyl vinyl silicone rubber matrix with B{sub 4}C, hollow beads, and zinc borate (ZB) as filler materials. As filler content increased, the tensile strength, elongation, and tear strength of the composites initially increased and then decreased. The shore hardness of the composites increased with increasing filler content with a maximum value of 30 HA. The heat insulation properties of the composites with hollow beads were higher than that of the ordinary composites with the same filler mass fraction. When ZB content exceeded 12 wt%, the limit of oxygen index of the composites was higher than 27.1%. With Am–Be neutron as the test radiation source, the transmission of neutron for a 2 cm sample was only 47.8%. Powder surface modification improved the mechanical properties, thermal conductivity, flame retardancy, and neutron shielding performance of the composites, but did not affect shore hardness.

  5. Preparation and properties of flexible flame-retardant neutron shielding material based on methyl vinyl silicone rubber (United States)

    Chai, Hao; Tang, Xiaobin; Ni, Minxuan; Chen, Feida; Zhang, Yun; Chen, Da; Qiu, Yunlong


    Flexible flame-retardant composites were prepared using high-functional methyl vinyl silicone rubber matrix with B4C, hollow beads, and zinc borate (ZB) as filler materials. As filler content increased, the tensile strength, elongation, and tear strength of the composites initially increased and then decreased. The shore hardness of the composites increased with increasing filler content with a maximum value of 30 HA. The heat insulation properties of the composites with hollow beads were higher than that of the ordinary composites with the same filler mass fraction. When ZB content exceeded 12 wt%, the limit of oxygen index of the composites was higher than 27.1%. With Am-Be neutron as the test radiation source, the transmission of neutron for a 2 cm sample was only 47.8%. Powder surface modification improved the mechanical properties, thermal conductivity, flame retardancy, and neutron shielding performance of the composites, but did not affect shore hardness.

  6. In situ XANES study on TiO2-SiO2 aerogels and flame made materials

    DEFF Research Database (Denmark)

    Grunwaldt, J.D.; Beck, C.; Stark, W.;


    The structures of TiO2-SiO2 based aerogels and flame made particles, used as epoxidation catalysts, are compared by X-ray absorption near edge structure (XANES) spectroscopy and in situ XANES during dehydration of the calcined catalyst samples. The results are interpreted in terms of the titanium...... species present in the catalyst and the catalytic performance in the test reaction, the epoxidation of 2-cyclohexene-1-ol by tert butylhydroperoxide ( THBP) at 90degreesC. XANES shows that tetrahedral titanium sites are the favoured sites at low TiO2 concentrations (1-3.2 wt. % in this study......). The catalytic performance (turnover frequency, selectivity) of such aerogels or flame made materials with low TiO2 content is much better than that of corresponding samples with high TiO2 content. In aerogels, regardless of the TiO2 content, the amount of titanium with tetrahedral coordination increases...

  7. Research on Service Life of Flame Resistant Materials in the Exhibition Hall by the Use of Mechanical Method of the Meso Damage Mechanics

    Directory of Open Access Journals (Sweden)

    Zhang Junzhu


    Full Text Available The population in the exhibition hall is relatively dense, and fire incidents often occur, so the existence of flame resistant materials is very important. The flame resistant materials are used to analyze the museums, art galleries, science and technology museums and other exhibition halls. Taking two kinds of flame resistant materials, namely, Mg(OH2 and Al(OH3 as an example, this paper establishes a model of meso damage mechanics by the use of mechanical method of the meso damage mechanics, and researches the macro mechanical properties of the thermal insulation materials and decorative materials so as to predict its service life. This research finds that the use of two kinds of flame resistant materials, namely, Mg(OH2 and Al(OH3 can improve the elasticity modulus of the thermal insulation materials and decorative materials used in the construction, so that its macro mechanical properties can have a significant improvement, and its service life can also have a significant improvement after adding flame retardant materials.

  8. Investigation into the sorption of nitroglycerin and diazepam into PVC tubes and alternative tube materials during application. (United States)

    Treleano, Anna; Wolz, Gerd; Brandsch, Rainer; Welle, Frank


    Plastic bags and tubes are increasingly used for the storage and application of pharmaceutical formulations. The most common polymer material for drug application sets is plasticized poly(vinylchloride) (PVC). During application of pharmaceutical drug solution through PVC tubes, the polymer and the contact media interact which leads to leaching out of polymer additives or sorption of ingredients of the drug solution. Whereas the discussion of leaching of plasticizers is focussed on the toxicological properties of a drug packaging system, the sorption of drug formulation compounds has an influence on the dosage of the active pharmaceutical ingredient resulting in a reduced drug delivery to the patient. Therefore sorption has an influence on the effectiveness and success of the therapy. Within the study, the concentration profiles of nitroglycerin and diazepam solutions were determined after pumping the solutions through infusion administration sets. The study includes plasticized PVC tubes with different plasticizers (DEHP, DEHA, DEHT, TEHTM, DINCH, poly adipate), PVC (DEHP) tubes with different shore hardness as well as alternative polymer materials like EVA, TPE, PUR, silicone, LDPE and PP. From the experimental concentration curves it could be shown, that in the first minutes of the application of the drug solution the sorption of the active compound is at its maximum, resulting in the lowest concentration in the applied pharmaceutical solution. For a PVC tube with DEHP as plasticizer and a shore hardness of 80 only about 57% of the initial nitroglycerin concentration in the solution is applied to the patient in the first minutes of the application. For PVC tube (DEHP, shore 80) the experimental data were simulated using mathematical diffusion models. The concentration profiles during application could be well simulated using the partition coefficient K=50 (nitroglycerin) and K=300 (diazepam), respectively. However, the experimental results indicate, that the

  9. Deposition of Flame-generated Al2O3 Nano-particles on a Porous Surface

    DEFF Research Database (Denmark)

    Andersen, Sune Klint; Johannessen, Jens Tue; Wedel, Stig;


    When particles of catalytic materials become less than 50 nm they start toexhibit a stronger catalytic activity compared to their bulk counterparts. Nano-particles are thus good candidates for manufacture of highly activecatalysts. Nanometer sized particles of catalytic materials may be generated...... athigh temperatures in flames. The direct deposition from gas phase on a ceramicsubstrate tube of flame-generated particles leads to a uniform, porous layer ofsmall particles, masking the coarser structure of the substrate tube. The methodlooks promising for manufacture of catalytic filters and membranes....

  10. Evaluation on mechanical and corrosion properties of steam generator tubing materials

    Energy Technology Data Exchange (ETDEWEB)

    Kim, In Sup; Lee, Byong Whi; Lee, Sang Kyu; Lee, Young Ho; Kim, Jun Whan; Lee, Ju Seok; Kwon, Hyuk Sang; Kim, Su Jung [Korea Advanced Institute of Science and Technology, Taejon (Korea, Republic of)


    Steam generator is one of the major components of nuclear reactor pressure boundary. It's main function os transferring heat which generated in the reactor to turbine generator through steam generator tube. In these days, steam generator tubing materials of operating plant are used Inconel 600 alloys. But according to the operation time, there are many degradation phenomena which included mechanical damage due to flow induced vibration and corrosion damage due to PWSCC, IGA/SCC and pitting etc. Recently Inconel 690 alloys are selected as new and replacement steam generator tubes for domestic nuclear power plant. But there are few study about mechanical and corrosion properties of Inconel 600 and 690. The objectives of this study is to evaluate and compare mechanical and corrosion propertied of steam generator tube materials.

  11. Self-response multi-functional composite material base on carbon nanotube paper using deicing, flame retardancy, thermal insulation, and lightning-strike protection (United States)

    Chu, Hetao; Zhang, Zhichun; Liu, Yanju; Leng, Jinsong


    Carbon nanotube paper (CNP) based multi-functional composite material is an attractive candidate for deicing, flame retardancy, thermal insulation and lighting strike protection due to the excellent conductivity, light weight and thin dimensions. In this article, multi-functional carbon nanotube paper was fabricated successfully by using commercial carbon nanotube. As a deicing composite material, carbon nanotube was used directly without pretreatment in fabricating carbon nanotube paper. The conductivities of the carbon nanotube paper and deicing composite were 77.8S/cm and 64.9S/ respectively. Electrical heating and deicing performance were test by infrared camera with deicing time less than 220s and 450s to melt a certain amount of ice under different ambient condition. CNT was grafted by zirconium (IV) butoxide solution and dimethyl dichlorosilicane to form co-oligomers on the tube surface while oligomers decompose under a certain temperature to develop an inorganic layer of silicon zirconium oxide. The oxidizing temperature of carbon nanotube increases more than 20°C and the weight loss rate decreases 20% than the untreated carbon nanotube. Lightning protection material required high electro conductivity, due to the utmost high current in a short time. Therefore, silver nanoparticles were deposited on the surface of carbon nanotube with the diameter around 100nm. The conductivity increased sharply from 84s/cm to1756s/cm with the mount of 5.9wt% Ag of the modified carbon nanotube paper because the silver nanoparticles deposited on the surface. In addition, the silver modified also can be used as thermal insulation material decreasing the infrared radiation.

  12. In-vessel ITER tubing failure rates for selected materials and coolants

    Energy Technology Data Exchange (ETDEWEB)

    Marshall, T.D. [Rensselaer Polytechnic Institute, Troy, NY (United States); Cadwallader, L.C. [EG& G Idaho Inc., Idaho Falls, ID (United States)


    Several materials have been suggested for fabrication of ITER in-vessel coolant tubing: beryllium, copper, Inconel, niobium, stainless steel, titanium, and vanadium. This report generates failure rates for the materials to identify the best performer from an operational safety and availability perspective. Coolant types considered in this report are helium gas, liquid lithium, liquid sodium, and water. Failure rates for the materials are generated by including the influence of ITER`s operating environment and anticipated tubing failure mechanisms with industrial operating experience failure rates. The analyses define tubing failure mechanisms for ITER as: intergranular attack, flow erosion, helium induced swelling, hydrogen damage, neutron irradiation embrittlement, cyclic fatigue, and thermal cycling. K-factors, multipliers, are developed to model each failure mechanism and are applied to industrial operating experience failure rates to generate tubing failure rates for ITER. The generated failure rates identify the best performer by its expected reliability. With an average leakage failure rate of 3.1e-10(m-hr){sup {minus}1}and an average rupture failure rate of 3.1e-11(m-hr){sup {minus}1}, titanium proved to be the best performer of the tubing materials. The failure rates generated in this report are intended to serve as comparison references for design safety and optimization studies. Actual material testing and analyses are required to validate the failure rates.

  13. Thermal Response of UHMWPE Materials in a Flash Flame Test Environment (United States)


    garment , as well as differences in protection based on how the garments are worn. A cost -effective alternative to the manikin test for measuring FR fabric outer layer of Tencate Defender M. Prior to fabricating test garments , preliminary flash flame testing was conducted with a midscale...test setup, which guided the full-scale thermal manikin test plan. Test garments were fabricated for evaluation on the instrumented thermal test

  14. Traveling wave tube measurements for low-frequency properties of underwater acoustic materials

    Institute of Scientific and Technical Information of China (English)


    A traveling wave tube measurement technique for measuring acoustic properties of underwater acoustic materials was developed. Water temperature and pressure environments of the ocean can be simulated in a water-filled tube, and the acoustic parameters of samples of underwater acoustic materials are measured in the range of low-frequency. A tested sample is located at central position of the tube. A pair of projectors is separately located at both ends of the tube. Using an active anechoic technique, the sound wave transmitting the tested sample is hardly reflected by the surface of secondary transducer. So the traveling sound field is built up in the tube. By separately calculating the transfer functions of every pair of double hydrophones in the sound fields from the both sides of the sample, its reflection coefficients and transmission coefficients are obtained. In the measurement system, the inside diameter of the tube is Φ208 mm, the working frequency range is from 100 to 4000 Hz, the maximum pressure is 5 MPa. The reflection coefficients and transmission coefficients of a water layer and a stainless steel layer samples are measured actually and calculated theoretically. The results show that the measured values are in good agreement with the values calculated, and the measurement uncertainty is not greater than 1.5 dB.

  15. Development of suitable potting material for dispenser cathodes of a high power microwave tube

    Energy Technology Data Exchange (ETDEWEB)

    Pal, Kalyan S.; Ghosh, Sumana; Dandapat, Nandadulal [Bio-Ceramics and Coating Division, CSIR - Central Glass and Ceramic Research Institute, 196, Raja S.C. Mullick Road, Kolkata 700 032, West Bengal (India); Datta, Someswar, E-mail: [Bio-Ceramics and Coating Division, CSIR - Central Glass and Ceramic Research Institute, 196, Raja S.C. Mullick Road, Kolkata 700 032, West Bengal (India); Basu, Debabrata [Bio-Ceramics and Coating Division, CSIR - Central Glass and Ceramic Research Institute, 196, Raja S.C. Mullick Road, Kolkata 700 032, West Bengal (India); Raju, R.S. [Microwave Tubes Division, CSIR - Central Electronics Engineering Research Institute, Pilani 333031, Rajasthan (India)


    Highlights: Black-Right-Pointing-Pointer Potting material. Black-Right-Pointing-Pointer Doped alumina. Black-Right-Pointing-Pointer Non-shrinkable. Black-Right-Pointing-Pointer Dispenser cathode. Black-Right-Pointing-Pointer Microwave tube. - Abstract: The present study aims to develop suitable advanced potting material for modern high performance dispenser cathodes for high power microwave tube through refinement of the alumina microstructure by using suitable dopant. Calcium oxide was selected as a dopant material and the resultant materials were characterized by X-ray diffraction studies and the microstructure monitored by SEM study and EDX analysis. The shrinkage, thermal and electrical properties of the resultant material was evaluated to establish its suitability to function as an advanced potting material.

  16. Properties of the chalcogenide–carbon nano tubes and graphene composite materials

    Energy Technology Data Exchange (ETDEWEB)

    Singh, Abhay Kumar, E-mail: [Department of Physics, Indian Institute of Science, Bangalore 560012 (India); Department of Electronics Engineering, Incheon National University, Incheon 406-772 (Korea, Republic of); Department of Physics, Incheon National University, Incheon 406-772 (Korea, Republic of); Kim, JunHo [Department of Physics, Incheon National University, Incheon 406-772 (Korea, Republic of); Park, Jong Tae [Department of Electronics Engineering, Incheon National University, Incheon 406-772 (Korea, Republic of); Sangunni, K.S. [Department of Physics, Indian Institute of Science, Bangalore 560012 (India)


    Highlights: • Chalcogenides. • Melt quenched. • Composite materials. • Multi walled carbon nano tubes. • Bilayer graphene. - Abstract: Composite can deliver more than the individual elemental property of the material. Specifically chalcogenide- multi walled carbon nano tubes and chalcogenide- bilayer graphene composite materials could be interesting for the investigation, which have been less covered by the investigators. We describe micro structural properties of Se{sub 55}Te{sub 25}Ge{sub 20,} Se{sub 55}Te{sub 25}Ge{sub 20} + 0.025% multi walled carbon nano tubes and Se{sub 55}Te{sub 25}Ge{sub 20} + 0.025% bilayer graphene materials. This gives realization of the alloying constituents inclusion/or diffusion inside the multi walled carbon nano tubes and bilayer graphene under the homogeneous parent alloy configuration. Raman spectroscopy, X-ray photoelectron spectroscopy, UV/Visible spectroscopy and Fourier transmission infrared spectroscopy have also been carried out under the discussion. A considerable core energy levels peak shifts have been noticed for the composite materials by the X-ray photoelectron spectroscopy. The optical energy band gaps are measured to be varied in between 1.2 and 1.3 eV. In comparison to parent (Se{sub 55}Te{sub 25}Ge{sub 20}) alloy a higher infrared transmission has been observed for the composite materials. Subsequently, variation in physical properties has been explained on the basis of bond formation in solids.

  17. On the transition from a highly turbulent curved flame into a tulip flame

    Energy Technology Data Exchange (ETDEWEB)

    Kratzel, T.; Pantow, E.; Fischer, M. [German Aerospace Research Establishment, Stuttgart (Germany). Institute of Technical Thermodynamics


    Experimental and numerical investigations of premixed flame propagation behaviour associated with vortex interactions due to planar pressure waves crossing a curved flame front have been carried out. The resulting ``tulip flame`` formation in such a closed tube has been studied by Schlieren visualization. The ``tulip flame`` phenomenon was observed only closed tubes, while cellular flame fronts appeared in half-open tubes. A physical model has been developed and implemented in a discrete vortex method combined with a flame tracking algorithm. The numerical method has been applied to model and understand the processes that cause the flame to change from a curved to a tulip shape. The results of the simulation are in good agreement with the experimental observations. (author)

  18. Measurement with corrugated tubes of early-age autogenous shrinkage of cement-based material

    DEFF Research Database (Denmark)

    Tian, Qian; Jensen, Ole Mejlhede


    The use of a special corrugated mould enables transformation of volume strain into horizontal, linear strain measurement in the fluid stage. This allows continuous measurement of the autogenous shrinkage of cement-based materials since casting, and also effectively eliminates unwanted influence...... on the measuring results from gravity, temperature variation and mould restraint. In this paper the principle of the corrugated tube measurement is described. A systematic study was carried out on the influence on the measuring results of the material properties, size effects and encapsulated air in the corrugated...... tube. The experimental results show that there is a minor influence on the measuring results of the stiffness and size of the plastic tube as well as of the encapsulated air. However, the influence decreases with the hardening process and becomes negligible a few hours after final set....

  19. Development Study of Cartridge/Crucible Tube Materials (United States)

    McKechnie, Timothy N.; ODell, Scott J.


    The limitations of traditional alloys and the desire for improved performance for components is driving the increased utilization of refractory metals in tile space industry. From advanced propulsion systems to high temperature furnace components for microgravity processing, refractory metals are being used for their high melting temperatures and inherent chemical stability. Techniques have been developed to produce near net shape refractory metal components utilizing vacuum plasma spraying. Material utilization is very high, and laborious machining can be avoided. As-spray formed components have been tested and found to perform adequately. However, increased mechanical and thermal properties are needed. To improve these properties, post processing thermal treatments such as hydrogen sintering and vacuum annealing have been performed. Components formed from alloys of tungsten, rhenium, tantalum, niobium, and molybdenum are discussed and a metallurgical analyses detailing the results are presented. A qualitative comparison of mechanical properties is also included.

  20. Wear behavior of 2-1/4 Cr-1 Mo tubing against alloy 718 tube-support material in sodium-cooled steam generators

    Energy Technology Data Exchange (ETDEWEB)

    Wilson, W L


    A series of prototypic steam generator 2-{1/4} Cr-1 Mo tube/alloy 718 tube support plate wear tests were conducted in direct support of the Westinghouse Nuclear Components Division -- Breeder Reactor Components Project Large Scale steam Generator design. The initial objective was to verify the acceptable wear behavior of softer, over-aged'' alloy 718 support plate material. For all interfaces under all test conditions, resultant wear damage was adhesive in nature with varying amounts of 2-{1/4} Cr-1 Mo tube material being adhesively transferred to the alloy 718 tube supports. Maximum tube wear depths exceeded the initially established design allowable limit of 127 {mu}m (.005 in.) at 17 of the 18 interfaces tested. A decrease in contact stresses produced acceptable tube wear depths below a readjusted maximum design allowable value of 381 {mu}m (.015 in.). Additional conservatisms associated with the simulation of a 40-year lifetime of rubbing in a one-week laboratory test provided further confidence that the 381 {mu}m maximum tube wear allowance would not be exceeded in service. Softer, over-aged'' alloy 718 material was found to produce slightly less wear damage on 2-{1/4} Cr-1 Mo tubing than fully age hardened material. Also, air formed oxide films on the alloy 718 reduced initial tube wear and delayed the onset of adhesive surface damage. However, at high surface stress levels, these films were not sufficiently stable to provide adequate long term protection from adhesive wear. The results of the present work and those of previous test programs suggest that the successful in-sodium tribological performance of 2-{1/4} Cr-1 Mo/alloy 718 rubbing couples is dependent upon the presence of lubricative surface films, such as oxides and/or surface reaction or deposition products. 11 refs., 13 figs., 4 tabs.

  1. Producing of Impedance Tube for Measurement of Acoustic Absorption Coefficient of Some Sound Absorber Materials

    Directory of Open Access Journals (Sweden)

    R. Golmohammadi


    Full Text Available Introduction & Objective: Noise is one of the most important harmful agents in work environment. In spit of industrial improvements, exposure with over permissible limit of noise is counted as one of the health complication of workers. In Iran, do not exact information of the absorption coefficient of acoustic materials. Iranian manufacturer have not laboratory for measured of sound absorbance of their products, therefore using of sound absorber is limited for noise control in industrial and non industrial constructions. The goal of this study was to design an impedance tube based on pressure method for measurement of the sound absorption coefficient of acoustic materials.Materials & Methods: In this study designing of measuring system and method of calculation of sound absorption based on a available equipment and relatively easy for measurement of the sound absorption coefficient related to ISO10534-1 was performed. Measuring system consist of heavy asbestos tube, a pure tone sound generator, calibrated sound level meter for measuring of some commonly of sound absorber materials was used. Results: In this study sound absorption coefficient of 23 types of available acoustic material in Iran was tested. Reliability of results by three repeat of measurement was tested. Results showed that the standard deviation of sound absorption coefficient of study materials was smaller than .Conclusion: The present study performed a necessary technology of designing and producing of impedance tube for determining of acoustical materials absorption coefficient in Iran.

  2. Numerical simulation on heat transfer performance of vertical U-tube with different borehole fill materials

    Institute of Scientific and Technical Information of China (English)


    Heat exchange performance of vertical U-tube heat exchanger was studiedwith two different borehole fill materials and CFD software. Borehole surface temperature and water temperature distribution were simulated on the condition of continuous operation for 8 h in winter with inlet water temperature being 10 ℃. The results show that there is no obvious difference on heat exchanger performance between the two different borehole fill materials.

  3. Improving formability of tube bending for a copper material using finite element simulation

    Energy Technology Data Exchange (ETDEWEB)

    Nguyen, Duc Toan; Nnuyen, Dinh Thanh [Hungyen University of Technology and Education, Hungyen (Viet Nam); Kim, Young Suk [Kyungpook National University, Daegu (Korea, Republic of)


    Bending tubes are key products in many industries. The geometric parameters of the bending process are considered according to Taguchi's orthogonal array and then coupled with finite element simulation to predict and improve the formability of the tube bending process for copper JIS25A material. Three parameters, namely, mandrel diameter, distance between mandrel rings, and distance from the tip of the mandrel bar to the center of the base die, are selected to study their effects on the quality of the bending process. The variance analysis shows that the effect distribution of each parameter to bending quality is determined, and optimal conditions are adopted to conduct experiments.

  4. The Use of Nanoscaled Fibers or Tubes to Improve Biocompatibility and Bioactivity of Biomedical Materials

    Directory of Open Access Journals (Sweden)

    Xiaoming Li


    Full Text Available Nanofibers and nanotubes have recently gained substantial interest for potential applications in tissue engineering due to their large ratio of surface area to volume and unique microstructure. It has been well proved that the mechanical property of matrix could be largely enhanced by the addition of nanoscaled fibers or tubes. At present, more and more researches have shown that the biocompatibility and bioactivity of biomedical materials could be improved by the addition of nanofibers or nanotubes. In this review, the efforts using nanofibers and nanotubes to improve biocompatibility and bioactivity of biomedical materials, including polymeric nanofibers/nanotubes, metallic nanofibers/nanotubes, and inorganic nanofibers/nanotubes, as well as their researches related, are demonstrated in sequence. Furthermore, the possible mechanism of improving biocompatibility and bioactivity of biomedical materials by nanofibers or nanotubes has been speculated to be that the specific protein absorption on the nanoscaled fibers or tubes plays important roles.

  5. Global optimisation methods for poroelastic material characterisation using a clamped sample in a Kundt tube setup (United States)

    Vanhuyse, Johan; Deckers, Elke; Jonckheere, Stijn; Pluymers, Bert; Desmet, Wim


    The Biot theory is commonly used for the simulation of the vibro-acoustic behaviour of poroelastic materials. However, it relies on a number of material parameters. These can be hard to characterize and require dedicated measurement setups, yielding a time-consuming and costly characterisation. This paper presents a characterisation method which is able to identify all material parameters using only an impedance tube. The method relies on the assumption that the sample is clamped within the tube, that the shear wave is excited and that the acoustic field is no longer one-dimensional. This paper numerically shows the potential of the developed method. It therefore performs a sensitivity analysis of the quantification parameters, i.e. reflection coefficients and relative pressures, and a parameter estimation using global optimisation methods. A 3-step procedure is developed and validated. It is shown that even in the presence of numerically simulated noise this procedure leads to a robust parameter estimation.

  6. 酚醛建筑保温阻燃材料的研制%The Development of Phenolic Building Insulation Flame Retardant Materials

    Institute of Scientific and Technical Information of China (English)


    Along with the progress of people’s environmental protection consciousness and awareness of fire, insulation and flame retardant properties of building materials has been paid more and more at ention. But now a lot of building thermal insulation material has many problems in the flame retardant. This paper introduces to everybody a kind of excel ent flame retardant insulation building material——the phenolic building insulation flame retardant materials.%  随着人们环保意识和消防意识的进步,建筑材料的保温和阻燃性能越来越受到重视。但现在很多建筑保温材料在阻燃性上存在不少问题。本文向大家介绍一类具有优秀阻燃性的建筑保温材料——酚醛建筑保温阻燃材料。

  7. 阻燃EPDM电缆料的制备和力学性能%Preparation and mechanical properties of flame retardant EPDM cable materials

    Institute of Scientific and Technical Information of China (English)



    以三元乙丙橡胶(EPDM)为基相,白炭黑为补强剂,氢氧化镁和氢氧化铝为阻燃剂,制备阻燃EPDM电缆料.研究补强剂和阻燃剂的用量对EPDM性能的影响,通过对扯断伸长率、拉伸强度、邵氏A硬度、氧指数的测试和扫描电镜分析,研究其力学性能和形貌结构,其电缆料的最佳配方(质量份)为EPDM100、白炭黑45、氢氧化锾10、氢氧化铝90.%In this paper, the flame retardant EPDM cable materials was prepared by EPDM used as matrix, silica used as reinforcing agent, magnesium hydroxide and aluminum hydroxide used as flame retardant. The effect content of reinforcing agent and flame retardant on EPDM property was studied. Mechanical performance and morphology of flame retardant EPDM cable material were researched through testing elongation at break, tensile strength, shore A hardness, oxide index and analysis scanning electronic microscopy. The optimum formulation was l00phr EPDM, 45phr silica, l0phr magnesium hydroxide and 90phr aluminum hydroxide.

  8. Novel class of eco-flame retardants based on the renewable raw materials (United States)

    Sakharov, A. M.; Sakharov, P. A.; Lomakin, S. M.; Zaikov, G. E.


    The present study is focused on development of environmentally friendly intumescent/char forming coatings for wood and polymeric materials. For this purpose we have developed the method of oxidation of raw materials: polysaccharides, seeds and lignin by oxygen in the presence of catalyst. The main products of oxidation of such substrates are the salts of polyoxy- and polyphenoxy acids. The efficiency of fireproofing action of novel surface protecting intumescent coating for wood and polymeric materials based on modified renewable raw materials was studied. Flammability tests of wood and polymers samples treated by oxidized raw materials confirm their high-performance fire protection.

  9. Melting of Nanoprticle-Enhanced Phase Change Material inside Shell and Tube Heat Exchanger

    Directory of Open Access Journals (Sweden)

    Seiyed Mohammad Javad Hosseini


    Full Text Available This paper presents a numerical study of melting of Nanoprticle-Enhanced phase change material (NEPCM inside a shell and tube heat exchanger using RT50 and copper particles as base material and nanoparticle, respectively. In this study, the effects of nanoparticles dispersion (, 0.03, and 0.05 on melting time, liquid fraction, and penetration length are investigated. The results show that the melting time decreases to 14.6% and the penetration length increases to 146% with increasing volume fraction of nanoparticle up to .

  10. Long term testing of materials for tube shielding, stage 2; Laangtidsprovning av tubskyddsmaterial, etapp 2

    Energy Technology Data Exchange (ETDEWEB)

    Norling, Rikard; Hjoernhede, Anders; Mattsson, Mattias


    Circulating Fluidized Bed (CFB) boilers are commonly used for combustion of biomass and are used to some extent for Waste-to-Energy (WtE) plants as well. The superheaters of the latter are for obvious reasons more prone to suffer from high temperature corrosion caused by the corrosive species in the fuel, mainly chlorides. Frequently the final (hottest) superheater is positioned in the loop seal, where the circulating bed material is returned to the furnace after being separated from the flue gas by a cyclone. The environment in the loop seal is relatively free of chlorides, since these primarily follow the flue gas into the convection pass. Hence, higher steam temperature can be allowed without excessive damage to the final superheater. On the other hand the superheaters, which are located in the convection pass, are more exposed to the corrosive species of the flue gas. Further, they are eroded by particles entrained in the gas flow. Particles and condensing gaseous species are to a large extent deposited on the superheaters, which limits the heat transfer and promotes corrosion. The deposits are regularly removed e.g. by soot blowers. The pressurized steam from soot blowers causes additional erosion damage to that caused by entrained particles. It shall be noted that the actual damage is caused by a combined mechanism of erosion and corrosion denoted erosion-corrosion, which usually results in dramatically accelerated wear. To avoid excessive erosion damage on the superheater tubes the first tube row of each bundle is protected by tube shielding. In its simplest form the shields are made from a steel sheet that has been bent into a semi-circular half-cylinder shell. These shields are attached onto the wind-side of the tubes by hangers. A typical material for tube shielding is the austenitic high temperature resistant stainless steel 253MA. Life of tube shielding depends on numerous factors such as boiler design, superheater location, fuel and operating

  11. The discrete regime of flame propagation (United States)

    Tang, Francois-David; Goroshin, Samuel; Higgins, Andrew

    The propagation of laminar dust flames in iron dust clouds was studied in a low-gravity envi-ronment on-board a parabolic flight aircraft. The elimination of buoyancy-induced convection and particle settling permitted measurements of fundamental combustion parameters such as the burning velocity and the flame quenching distance over a wide range of particle sizes and in different gaseous mixtures. The discrete regime of flame propagation was observed by substitut-ing nitrogen present in air with xenon, an inert gas with a significantly lower heat conductivity. Flame propagation in the discrete regime is controlled by the heat transfer between neighbor-ing particles, rather than by the particle burning rate used by traditional continuum models of heterogeneous flames. The propagation mechanism of discrete flames depends on the spa-tial distribution of particles, and thus such flames are strongly influenced by local fluctuations in the fuel concentration. Constant pressure laminar dust flames were observed inside 70 cm long, 5 cm diameter Pyrex tubes. Equally-spaced plate assemblies forming rectangular chan-nels were placed inside each tube to determine the quenching distance defined as the minimum channel width through which a flame can successfully propagate. High-speed video cameras were used to measure the flame speed and a fiber optic spectrometer was used to measure the flame temperature. Experimental results were compared with predictions obtained from a numerical model of a three-dimensional flame developed to capture both the discrete nature and the random distribution of particles in the flame. Though good qualitative agreement was obtained between model predictions and experimental observations, residual g-jitters and the short reduced-gravity periods prevented further investigations of propagation limits in the dis-crete regime. The full exploration of the discrete flame phenomenon would require high-quality, long duration reduced gravity environment

  12. Heat release and flame structure measurements of self-excited acoustically-driven premixed methane flames

    Energy Technology Data Exchange (ETDEWEB)

    Kopp-Vaughan, Kristin M.; Tuttle, Steven G.; Renfro, Michael W. [Department of Mechanical Engineering, University of Connecticut, 191 Auditorium Rd, U-3139, Storrs, CT 06269 (United States); King, Galen B. [School of Mechanical Engineering, Purdue University, West Lafayette, IN 47907 (United States)


    An open-open organ pipe burner (Rijke tube) with a bluff-body ring was used to create a self-excited, acoustically-driven, premixed methane-air conical flame, with equivalence ratios ranging from 0.85 to 1.05. The feed tube velocities corresponded to Re = 1780-4450. Coupled oscillations in pressure, velocity, and heat release from the flame are naturally encouraged at resonant frequencies in the Rijke tube combustor. This coupling creates sustainable self-excited oscillations in flame front area and shape. The period of the oscillations occur at the resonant frequency of the combustion chamber when the flame is placed {proportional_to}1/4 of the distance from the bottom of the tube. In this investigation, the shape of these acoustically-driven flames is measured by employing both OH planar laser-induced fluorescence (PLIF) and chemiluminescence imaging and the images are correlated to simultaneously measured pressure in the combustor. Past research on acoustically perturbed flames has focused on qualitative flame area and heat release relationships under imposed velocity perturbations at imposed frequencies. This study reports quantitative empirical fits with respect to pressure or phase angle in a self-generated pressure oscillation. The OH-PLIF images were single temporal shots and the chemiluminescence images were phase averaged on chip, such that 15 exposures were used to create one image. Thus, both measurements were time resolved during the flame oscillation. Phase-resolved area and heat release variations throughout the pressure oscillation were computed. A relation between flame area and the phase angle before the pressure maximum was derived for all flames in order to quantitatively show that the Rayleigh criterion was satisfied in the combustor. Qualitative trends in oscillating flame area were found with respect to feed tube flow rates. A logarithmic relation was found between the RMS pressure and both the normalized average area and heat release rate

  13. Eigenvalue analysis and calculations for the deflagration of porous energetic materials in the merged-flame regime

    Energy Technology Data Exchange (ETDEWEB)

    Ilincic, N. [Univ. of California, La Jolla, CA (United States). Dept. of Applied Mechanics and Engineering Sciences; Margolis, S.B. [Sandia National Labs., Livermore, CA (United States)


    Analytical and numerical calculations of the structure and burning rate of a deflagrating porous energetic material are presented for the limiting case of merged condensed and gas-phase reaction zones. The reaction scheme is modeled by a global two-step mechanism, applicable to certain types of degraded nitramine propellants and consisting of sequential condensed and gaseous steps. Taking into account important effects due to multiphase flow and exploiting the limit of large activation energies, a theoretical analysis may be developed based on activation-energy asymptotics. For steady, planar deflagration, this leads to an eigenvalue problem for the inner reaction-zone, the solution of which determines the burning rate. Numerical solutions give a reasonably complete description of the dependence of the structure and burning rate on the various parameters in the problem, and show excellent agreement with analytical results that are obtained in a more limited parameter regime in which most of the heat release is produced by the condensed-phase reaction and the porosity of the solid is small. These calculations indicate the significant influences of two-phase flow and the multiphase, multi-step chemistry on the deflagration structure and the burning rate, and thus serve to define an important parameter regime that supports the intrusion of the primary gas flame into the two-phase condensed decomposition region at the propellant surface.

  14. A quality assessment of respiratory auscultation material on YouTube. (United States)

    Sunderland, Nicholas; Camm, Christian F; Glover, Katie; Watts, Anna; Warwick, Geoffrey


    YouTube contains a large volume of medical educational material. This study assessed the quality of respiratory auscultation videos contained in YouTube. Videos were searched for using the terms 'breath sounds', 'respiratory sounds', 'respiratory auscultation' and/or 'lung sounds'. In total, 6,022 videos were located, 36 of which were considered suitable for scoring for video accuracy, comprehensiveness and quality. The average score was 3.32/6 (55.3% ± 1.30). Video score correlated with time-adjusted YouTube metadata: hits per day (0.496, p=0.002) and likes per day (0.534, p=0.001). Video score also correlated with the first search page on which the video was located in the 'breath sounds' and 'lung sounds' searches (-0.571, p=0.001; -0.445, p=0.014, respectively). The quality of videos was variable. Correlation between video score and some metadata values suggests that there is value for their use in judging video quality. However, the large number of videos found and inability to filter these results quickly makes locating educational content difficult.

  15. Study on the flame retardation and properties of PVC/Wood composite material by inorganic flame retardant%无机阻燃剂对PVC/木粉复合材料性能的影响

    Institute of Scientific and Technical Information of China (English)

    李凯夫; 邓燕平; 徐开蒙


    Poly(vinyl chloride)-wood(PVC/wood) composite material was flame retarded using AI(OH)3, ZB and Sb203.And the effects of different flame retardant formulations and content on the mechanic property, flame retardancy of the PVC/wood composite material were studied. The result indicated that: the LOI of the composites increased with increasing content of AI(OH)3, ZB and Sb2O3. Sb2O3 has the most flame retarding efficiency. LOI can reach as much as 35.2% when the content of Sb2O3 was 9 phr. AI(OH)3、 ZB and Sb2O3 were all improved the tensile strength. However all of them were harmful to the unnotched izod impact strength of the composites.%分别采用A1(OH)3、ZB以及Sb2O3等无机阻燃剂对PVC/木粉复合材料改性,研究不同的阻燃剂配方及阻燃剂含量对PVC/木粉复合材料阻燃性能和力学性能的影响。结果表明:随着A1(OH)3,ZB以及Sb203添加量的增加,PVC/木粉复合材料的氧指数(LOI)呈逐渐增大的趋势。Sb2O3阻燃效率最高,当添加量为9份时,氧指数达到35.2%;无机阻燃剂的加入普遍降低了PVC/木粉复合材料的冲击韧性,但对拉伸强度起到了一定的增强作用。

  16. Effects of Hot Jet Ignition on Flame Propagation Characteristics in Multi-Cycle Detonation Tube%热射流点火对多循环爆震管内火焰传播特性的影响

    Institute of Scientific and Technical Information of China (English)

    赵炜; 韩启祥; 王家骅; 贾冰岳; 宫继双


    为研究热射流点火对多循环脉冲爆震特性的影响,在一台工作频率为20Hz的气动阀式PDE上开展了试验研究,重点分析了热射流点火位置与预燃室中敏感性气体的填充比对爆震管内初始火焰传播速度及压力特性的影响。研究结果表明:热射流点火的位置在爆震管头部回流区内,对爆震管内火焰传播速度影响较小,热射流点火位置在回流区外,随着离封闭距离的增加火焰传播速度减小;预燃室填充比从1.78增加到2.75,初始火焰平均速度从380m/s上升到420m/s左右,当填充比在2.75~3.45时,火焰传播速度基本保持不变。%In order to study the characteristics of multi-cycle pulse detonation with hot jet ignition,series of experiments were performed with an aero-valve pulse detonation engine at the operation frequency of 20Hz. The initial flame propagation velocity and pressure characteristics were analyzed with different hot jet ignition po⁃sitions and fill fraction of jet sub-chamber. The experimental results show that the hot jet slightly affects the ini⁃tial flame propagation velocity,which is located in the recirculating zone in the head of detonation tube. Howev⁃er,the initial flame velocity decreases as the distance between hot jet position and blind head increases,which is located outside the recirculating zone. The initial average flame velocity increases from 380m/s to 420m/s as the fill fraction increases from 1.78 to 2.75 and changes slightly for the fill fraction between 2.75 to 3.45.

  17. Associated-particle sealed-tube neutron probe: Detection of explosives, contraband, and nuclear materials

    Energy Technology Data Exchange (ETDEWEB)

    Rhodes, E.; Dickerman, C.E.


    Continued research and development of the APSTNG shows the potential for practical field use of this technology for detection of explosives, contraband, and nuclear materials. The APSTNG (associated-particle sealed-tube generator) inspects the item to be examined using penetrating 14-MeV neutrons generated by the deuterium-tritium reaction inside a compact accelerator tube. An alpha detector built into the sealed tube detects the alpha-particle associated with each neutron emitted in a cone encompassing the volume to be inspected. Penetrating high-energy gamma-rays from the resulting neutron reactions identify specific nuclides inside the volume. Flight-times determined from the detection times of gamma-rays and alpha-particles separate the prompt and delayed gamma-ray spectra and allow a coarse 3-D image to be obtained of nuclides identified in the prompt spectrum. The generator and detectors can be on the same side of the inspected object, on opposite sides, or with intermediate orientations. Thus, spaces behind walls and other confined regions can be inspected. Signals from container walls can be discriminated against using the flight-time technique. No collimators or shielding are required, the neutron generator is relatively small, and commercial-grade electronics are employed. The use of 14-MeV neutrons yields a much higher cross-section for detecting nitrogen than that for systems based on thermal-neutron reactions alone, and the broad range of elements with significant 14-MeV neutron cross-sections extends explosives detection to other elements including low-nitrogen compounds, and allows detection of many other substances. Proof-of-concept experiments have been successfully performed for conventional explosives, chemical warfare agents, cocaine, and fissionable materials.


    Energy Technology Data Exchange (ETDEWEB)

    Hillier, Andrew [Kwasan and Hida Observatories, Kyoto University, Kyoto (Japan); Van Ballegooijen, Adriaan [Harvard-Smithsonian Center for Astrophysics, Cambridge, MA 02138 (United States)


    The dense prominence material is believed to be supported against gravity through the magnetic tension of dipped coronal magnetic field. For quiescent prominences, which exhibit many gravity-driven flows, hydrodynamic forces are likely to play an important role in the determination of both the large- and small-scale magnetic field distributions. In this study, we present the first steps toward creating a three-dimensional magneto-hydrostatic prominence model where the prominence is formed in the dips of a coronal flux tube. Here 2.5D equilibria are created by adding mass to an initially force-free magnetic field, then performing a secondary magnetohydrodynamic relaxation. Two inverse polarity magnetic field configurations are studied in detail, a simple o-point configuration with a ratio of the horizontal field (B{sub x} ) to the axial field (B{sub y} ) of 1:2 and a more complex model that also has an x-point with a ratio of 1:11. The models show that support against gravity is either by total pressure or tension, with only tension support resembling observed quiescent prominences. The o-point of the coronal flux tube was pulled down by the prominence material, leading to compression of the magnetic field at the base of the prominence. Therefore, tension support comes from the small curvature of the compressed magnetic field at the bottom and the larger curvature of the stretched magnetic field at the top of the prominence. It was found that this method does not guarantee convergence to a prominence-like equilibrium in the case where an x-point exists below the prominence flux tube. The results imply that a plasma {beta} of {approx}0.1 is necessary to support prominences through magnetic tension.

  19. Up in flames: a flammability assessment of alcohol-based hand sanitizers on common perioperative materials


    Samuel Almengor; W. Patrick Monaghan; Jacksonville, FL


    Introduction: The objective of this study was to perform a flammability assessment of alcohol-based hand sanitizers on common perioperative materials. There is an estimated 550–650 surgical fires that occur nationally each year, an instance comparable to that of wrong-site surgery, yet only about 100 operating room fires are reported each year.  The median cost of an OR fire settlement claim is $120,166.  Generation of fire requires the presence of three components, known as the “fire triad”:...

  20. Flame Length (United States)

    Earth Data Analysis Center, University of New Mexico — Flame length was modeled using FlamMap, an interagency fire behavior mapping and analysis program that computes potential fire behavior characteristics. The tool...

  1. "Magic Eraser" Flame Tests (United States)

    Landis, Arthur M.; Davies, Malonne I.; Landis, Linda


    Cleaning erasers are used to support methanol-fueled flame tests. This safe demonstration technique requires only small quantities of materials, provides clean colors for up to 45 seconds, and can be used in the classroom or the auditorium. (Contains 1 note.)

  2. Modelling of flame temperature of solution combustion synthesis of nanocrystalline calcium hydroxyapatite material and its parametric optimization

    Indian Academy of Sciences (India)

    Samir K Ghosh; Sukhomay Pal; Sujit K Roy; Surjya K Pal; Debabrata Basu


    Hydroxyapatite (HAp), an important bio-ceramic was successfully synthesized by combustion in the aqueous system containing calcium nitrate-di-ammonium hydrogen orthophosphate-urea. The combustion flame temperature of solution combustion reaction depends on various process parameters, and it plays a significant role in the phase formation, phase stability and physical characteristics of calcium hydroxyapatite powder. In this work, an attempt has been made to evaluate the influence of each selected process parameters on the flame temperature as well as physical characteristics of powder, and to select an optimal parameters setting using Taguchi method. A regression model has also been developed to correlate the input parameters, viz. batch size, diluents, fuel to oxidizer ratio and initial furnace temperature, with flame temperature of the solution combustion reaction. The adequacy of the developed model has been checked using analysis of variance technique.

  3. Evaluation of the acoustic and non-acoustic properties of sound absorbing materials using a three-microphone impedance tube

    CERN Document Server

    Doutres, Olivier; Atalla, Noureddine; Panneton, Raymond; 10.1016/j.apacoust.2010.01.007


    This paper presents a straightforward application of an indirect method based on a three-microphone impedance tube setup to determine the non-acoustic properties of a sound absorbing porous material. First, a three-microphone impedance tube technique is used to measure some acoustic properties of the material (i.e., sound absorption coefficient, sound transmission loss, effective density and effective bulk modulus) regarded here as an equivalent fluid. Second, an indirect characterization allows one to extract its non-acoustic properties (i.e., static airflow resistivity, tortuosity, viscous and thermal characteristic lengths) from the measured effective properties and the material open porosity. The procedure is applied to four different sound absorbing materials and results of the characterization are compared with existing direct and inverse methods. Predictions of the acoustic behavior using an equivalent fluid model and the found non-acoustic properties are in good agreement with impedance tube measureme...

  4. 浅谈聚氨酯硬泡保温材料阻燃技术%Discussion on the Flame Retardant Technology of Polyurethane Thermal Insulation Materials

    Institute of Scientific and Technical Information of China (English)

    王新钢; 李风; 张泽江


    Rigid polyurethane foam insulation materials belonged to the organic polymer insulating material,and the thermal conductivity of insulation materials was the lowest of all and had the most superior thermal performance.The combustion process of polyurethane thermal insulation material was introduced,and the flame retardant methods of rigid polyurethane foam insulation materials and its development trend were elaborated.%聚氨酯硬泡保温材料属于有机高分子保温材料,其导热系数为所有保温材料中最低、热工性能最为优越的一类材料。介绍了聚氨酯硬泡保温材料的燃烧过程,阐述了聚氨酯硬泡保温材料的阻燃处理方法及其发展趋势。

  5. Development of a TenTorTube for blade tip mechanisms. Pt. 1: feasibility and material tests

    Energy Technology Data Exchange (ETDEWEB)

    Joosse, P.A. [Stork Product Engineering, Amsterdam (Netherlands); Berg, R.M. van der [Rotorline Blade Company, Heerhugowaard (Netherlands)


    For variable speed wind turbines it is possible to perform both a power control and a safety function using passive tips. A conventional tip mechanism, consisting of a metal screw cylinder and spring is heavy, expensive and maintenance critical. These problems can be solved with a TenTorTube: a long, slender tube made of composite material in which the anistropic behaviour of fibre reinforced material is used. The feasibility of such a tube made out of fibre reinforced plastic has been shown. To verify the assumptions and obtain reliable material design data static material properties have been measured of epoxy tubes, with different fibre reinforcements. Based on static test values an aramid-epoxy tube showed the highest potential. Following the static tests a torsion creep tests and fatigue tests are carried out with the aim of investigating how this behaviour would influence the feasibility. Present results indicate that an improvement of reliability and reduction of mass and costs of the mechanism is to be expected. (author)

  6. Associated-particle sealed-tube neutron probe for characterization of materials

    Energy Technology Data Exchange (ETDEWEB)

    Rhodes, E.; Dickerman, C.E. [Argonne National Lab., IL (United States); Peters, C.W. [5235 N. Whispering Hills Lane, Tucson, AZ (United States)


    A neutron diagnostic probe system has been developed that can identify and image most elements having a larger atomic number than boron. It can satisfy van-mobile and fixed-portal requirements for nondestructive detection of contraband drugs, explosives, and nuclear and chemical warfare weapon materials, and for treaty verification of sealed munitions and remediation of radioactive waste. The probe is based on a nonpulsed associated-particle sealed-tube neutron generator (APSTNG) that interrogates the object with a 14-MeV neutrons and detects alpha-particle associated with each neutron. Gamma-ray spectra of resulting neutron reactions (primarily inelastic scattering) identify nuclides associated with drugs, explosives, and other contraband. Flight times determined from detection times of gamma-rays and alpha-particles yield a separate coarse tomographic image of each identified nuclide. Chemical substances are identified and imaged by comparing relative spectra fine intensities with ratios of elements in reference compounds. The High-energy neutrons in gamma-rays will penetrate large objects and dense materials. The source and emission detection systems can be on the same side, allowing measurements with access to one side only. A high signal-to-background ratio is obtained and maximum information is extracted from each detected gamma-ray, yet high-bandwidth data acquisition is not required. The APSTNG also forms the basis for a compact fast-neutron transmission imaging system. No collimators are required, and only minimal shielding is needed. The small and relatively inexpensive neutron generator tube exhibits high reliability and can be quickly replaced. The detector arrays and associated electronics can be made reliable with low maintenance cost.

  7. Radiative Structures of Lycopodium-Air Flames in Low Gravity (United States)

    Berlad, A. L.; Tangirala, V.; Ross, H.; Facca, L.


    Initially uniform clouds of fuel particulates in air sustain processes which may lead to particle cloud nonuniformities. In low gravity, flame-induced Kundt's Tube phenomena are observed to form regular patterns of nonuniform particle concentrations. Irregular patterns of particle concentrations also are observed to result from selected nonuniform mixing processes. Low gravity flame propagation for each of these classes of particle cloud flames has been found to depend importantly on the flame-generated infrared radiative fields. The spatial structures of these radiative fields are described. Application is made for the observed clases of lycopodium-air flames.

  8. Flames in vortices & tulip-flame inversion (United States)

    Dold, J. W.

    This article summarises two areas of research regarding the propagation of flames in flows which involve significant fluid-dynamical motion [1]-[3]. The major difference between the two is that in the first study the fluid motion is present before the arrival of any flame and remains unaffected by the flame [1, 2] while, in the second study it is the flame that is responsible for all of the fluid dynamical effects [3]. It is currently very difficult to study flame-motion in which the medium is both highly disturbed before the arrival of a flame and is further influenced by the passage of the flame.

  9. Thermographic Imaging of Material Loss in Boiler Water-Wall Tubing by Application of Scanning Line Source (United States)

    Cramer, K. Elliott; Winfree, William P.


    Localized wall thinning due to corrosion in utility boiler water-wall tubing is a significant inspection concern for boiler operators. Historically, conventional ultrasonics has been used for inspection of these tubes. This technique has proven to be very manpower and time intensive. This has resulted in a spot check approach to inspections, documenting thickness measurements over a relatively small percentage of the total boiler wall area. NASA Langley Research Center has developed a thermal NDE technique designed to image and quantitatively characterize the amount of material thinning present in steel tubing. The technique involves the movement of a thermal line source across the outer surface of the tubing followed by an infrared imager at a fixed distance behind the line source. Quantitative images of the material loss due to corrosion are reconstructed from measurements of the induced surface temperature variations. This paper will present a discussion of the development of the thermal imaging system as well as the techniques used to reconstruct images of flaws. The application of the thermal line source coupled with the analysis technique represents a significant improvement in the inspection speed for large structures such as boiler water-walls. A theoretical basis for the technique will be presented which explains the quantitative nature of the technique. Further, a dynamic calibration system will be presented for the technique that allows the extraction of thickness information from the temperature data. Additionally, the results of applying this technology to actual water-wall tubing samples and in situ inspections will be presented.

  10. MH/ATH/纳米硅树脂阻燃电缆料的制备与研究%The Preparation and Research of MH/ATH/Nano Silicone Flame-Retardant Cable Material

    Institute of Scientific and Technical Information of China (English)

    金小荀; 王新龙


    以LDPE、EVA为基体,MH、ATH、纳米硅树脂粉为阻燃剂,通过挤出造粒、注塑成型制得高性能无卤少烟阻燃电缆料.通过极限氧指数、万能电子拉力机、热重分析、傅里叶红外等研究手段研究电缆料的阻燃性能、耐热性能及其力学耐油耐老化性能.结果表明:P2体系有较好的阻燃性、耐热性、耐油、耐老化以及良好的力学性能,适合用作对阻燃要求较高的阻燃电缆料.%The high-performance low smoke halogen-free flame retardant cable materials was prepared by extruder and injection machine using LDPE/EVA as base material, MH/ATH/nano-silicone as flame retardant. The flame-retardant performance, heat resistance, mechanical properties, oil resistance, aging resistance of the cable material were studied by LOI, universal electronic tensile machine, TC and FTIR. The result showed that system P2 had better flame resistance, heat resistance and good mechanical. It was suitable to use as high required flame-retardant cable materials.

  11. Numerical assessment of accurate measurements of laminar flame speed (United States)

    Goulier, Joules; Bizon, Katarzyna; Chaumeix, Nabiha; Meynet, Nicolas; Continillo, Gaetano


    In combustion, the laminar flame speed constitutes an important parameter that reflects the chemistry of oxidation for a given fuel, along with its transport and thermal properties. Laminar flame speeds are used (i) in turbulent models used in CFD codes, and (ii) to validate detailed or reduced mechanisms, often derived from studies using ideal reactors and in diluted conditions as in jet stirred reactors and in shock tubes. End-users of such mechanisms need to have an assessment of their capability to predict the correct heat released by combustion in realistic conditions. In this view, the laminar flame speed constitutes a very convenient parameter, and it is then very important to have a good knowledge of the experimental errors involved with its determination. Stationary configurations (Bunsen burners, counter-flow flames, heat flux burners) or moving flames (tubes, spherical vessel, soap bubble) can be used. The spherical expanding flame configuration has recently become popular, since it can be used at high pressures and temperatures. With this method, the flame speed is not measured directly, but derived through the recording of the flame radius. The method used to process the radius history will have an impact on the estimated flame speed. Aim of this work is to propose a way to derive the laminar flame speed from experimental recording of expanding flames, and to assess the error magnitude.

  12. Experimental Investigation on Regenerator Materials of Stirling-type Pulse-tube Refrigerator Working at 20 K (United States)

    Zhou, Qiang; Chen, Liubiao; Pan, Changzhao; Zhou, Yuan; Wang, Junjie

    This paper will introduce our recent experimental results of cryogenic regenerator materials employed in Stirling-type one-stage pulse-tube refrigerator for the use at liquid hydrogen temperature. Thermal diffusion coefficient, according to which we choose the suitable regenerator materials, will prove to be a useful reference. We will also discuss the impact of resistance of sphere regenerator materials on the performance of the refrigerator and the method to improve it. Take an overall consideration, suitable-size Er3Ni will be applied as the regenerator materials at the cold head and we achieve a remarkable 14.7 K no-load temperature.

  13. Viability of use of PVC tubes in solar collectors: an analysis of materials

    Directory of Open Access Journals (Sweden)

    Luiz Guillherme Meira de Souza


    Full Text Available This paper presents a study of the inherent degradations of PVC tubes due to the thermal effect and ultraviolet solar radiation. The approach relates its causes and its effect of use of the PVC tubes as elements to absorption, forming a coil, in solar collectors for water heating. It is demonstrated that such degradations can be burst through the use of an outflow and an appropriate regimen of work, as well as of a protective layer for the tubes, in this case black ink used to magnify its absorption. The results of the properties of tubes that had been exposed to the degradation effect for up to five years are presented. The viability of use of this type of collector is demonstrated through comparative analysis of tubes exposed and not exposed to the sun, concluding for the low cost, easy assembly and maintenance of the system.

  14. Tube failures due to cooling process problem and foreign materials in power plants

    Energy Technology Data Exchange (ETDEWEB)

    Ahmad, J. [Kapar Energy Ventures Sdn Bhd, Jalan Tok Muda, Kapar 42200 (Malaysia); Purbolaksono, J., E-mail: [Department of Mechanical Engineering, Universiti Tenaga Nasional, Km 7 Jalan Kajang-Puchong, Kajang 43009, Selangor (Malaysia); Beng, L.C. [Kapar Energy Ventures Sdn Bhd, Jalan Tok Muda, Kapar 42200 (Malaysia)


    Cooling process which uses water for heat transfer is an essential factor in coal-fired and nuclear plants. Loss of cooling upset can force the plants to shut down. In particular, this paper reports visual inspections and metallurgical examinations on the failed SA210-A1 right-hand side (RHS) water wall tube of a coal-fired plant. The water wall tube showed the abnormal outer surface colour and has failed with wide-open ductile rupture and thin edges indicating typical signs of short-term overheating. Metallurgical examinations confirmed the failed tube experiencing higher temperature operation. Water flow starvation due to restriction inside the upstream tube is identified as the main root cause of failure. The findings are important to take failure mitigation actions in the future operation. Discussion on the typical problems related to the cooling process in nuclear power plants is also presented.

  15. Preparation of Flame Retardant Modified with Titanate for Asphalt Binder

    Directory of Open Access Journals (Sweden)

    Bo Li


    Full Text Available Improving the compatibility between flame retardant and asphalt is a difficult task due to the complex nature of the materials. This study explores a low dosage compound flame retardant and seeks to improve the compatibility between flame retardants and asphalt. An orthogonal experiment was designed taking magnesium hydroxide, ammonium polyphosphate, and melamine as factors. The oil absorption and activation index were tested to determine the effect of titanate on the flame retardant additive. The pavement performance test was conducted to evaluate the effect of the flame retardant additive. Oxygen index test was conducted to confirm the effect of flame retardant on flame ability of asphalt binder. The results of this study showed that the new composite flame retardant is more effective in improving the compatibility between flame retardant and asphalt and reducing the limiting oxygen index of asphalt binder tested in this study.

  16. Determination of tellurium by hydride generation with in situ trapping flame atomic absorption spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Matusiewicz, H.; Krawczyk, M. [Politechn Poznanska, Poznan (Poland)


    The analytical performance of coupled hydride generation - integrated atom trap (HG-IAT) atomizer flame atomic absorption spectrometry (FAAS) system was evaluated for determination of Te in reference material (GBW 07302 Stream Sediment), coal fly ash and garlic. Tellurium, using formation of H{sub 2}Te vapors, is atomized in air-acetylene flame-heated IAT. A new design HG-IAT-FAAS hyphenated technique that would exceed the operational capabilities of existing arrangernents (a water-cooled single silica tube, double-slotted quartz tube or an 'integrated trap') was investigated. An improvement in detection limit was achieved compared with using either of the above atom trapping techniques separately. The concentration detection limit, defined as 3 times the blank standard deviation (3{sigma}), was 0.9 ng mL{sup -1} for Te. For a 2 min in situ preconcentration time (sample volume of 2 mL), sensitivity enhancement compared to flame AAS, was 222 fold, using the hydride generation atom trapping technique. The sensitivity can be further improved by increasing the collection time. The precision, expressed as RSD, was 7.0% (n = 6) for Te. The accuracy of the method was verified using a certified reference material (GBW 07302 Stream Sediment) by aqueous standard calibration curves. The measured Te contents of the reference material was in agreement with the information value. The method was successfully applied to the determination of tellurium in coal fly ash and garlic.

  17. Rechargeable Biofilm-Controlling Tubing Materials for Use in Dental Unit Water Lines


    Luo, Jie; Porteous, Nuala; Sun, Yuyu


    A simple and practical surface grafting approach was developed to introduce rechargeable N-halamine-based antimicrobial functionality onto the inner surfaces of continuous small-bore polyurethane (PU) dental unit waterline (DUWL) tubing. In this approach, tetrahydrofuran (THF) solution of a free-radical initiator, dicumyl peroxide (DCP), flowed through the PU tubing (inner diameter of 1/16 inch, or 1.6 mm) to diffuse DCP into the tube’s inner walls, which was used as initiator in the subseque...

  18. Flame assisted synthesis of catalytic ceramic membranes

    DEFF Research Database (Denmark)

    Johansen, Johnny; Mosleh, Majid; Johannessen, Tue


    technology it is possible to make supported catalysts, composite metal oxides, catalytically active surfaces, and porous ceramic membranes. Membrane layers can be formed by using a porous substrate tube (or surface) as a nano-particle filter. The aerosol gas from the flame is led through a porous substrate...

  19. Effects of extrusion-billet preheating on the microstructure and properties of Zr-2.5Nb pressure tube materials

    Energy Technology Data Exchange (ETDEWEB)

    Choubey, R.; Cann, C.D. [Atomic Energy of Canada Limited, Pinawa, Manitoba (Canada). Whiteshell Labs.; Aldridge, S.A. [Nu-Tech Precision Metals, Inc., Arnprior, Ontario (Canada); Theaker, J.R.; Coleman, C.E. [Atomic Energy of Canada Ltd., Chalk River, Ontario (Canada). Chalk River Labs.


    The effects of extrusion temperature and pre-heat soak time for billets on the mechanical properties of Zr-2.5Nb pressure tubes for CANDU reactors have been examined. The {beta}-quenched billets from a quadruple-melted ingot containing approximately 1,200 ppm of oxygen were extruded at 780, 815, and 850 C with pre-heat soak times of 15 to 300 min. The extruded hollows were finished by cold drawing (with a 28% reduction in area) and then stress relieving at 400 C. The {alpha}-phase grain structure, tensile strength, and fracture toughness properties were found to vary with the pre-heat temperature and soak time. All the materials were tough because embrittling impurities were absent. The tubes with 780 C preheat had a very fine and uniform {alpha}-grain structure, giving high strength and toughness at all soak times. The opposite was true for the 850 C soaks; the grain structure was coarse and inhomogeneous and the materials tended to be less strong and less touch. The tubes with the 815 C soaks showed intermediate values of strength and toughness. These variations in mechanical properties are discussed in terms of {alpha}-grain refinement and oxygen enrichment.

  20. Investigation of material specifications changes during laser tube bending and its influence on the modification and optimization of analytical modeling (United States)

    Imhan, Khalil Ibraheem; Baharudin, B. T. H. T.; Zakaria, Azmi; Ismail, Mohd Idris Shah B.; Alsabti, Nasseer Mahdi Hadi; Ahmad, Ahmad Kamal


    Nowadays, laser tube bending process has become commonly used in laser material processing and fabrication fields because of its ability to produce such forms and shapes that cannot be achieved by normal mechanical bending tools. The process can avoid and overcome most of bending defects like wall thinning, wrinkling, spring back and ovalization. This investigation focused on the experimental, analytical modeling, and numerical simulation to give more understanding of the process. In this work a high power pulsed Nd-Yag laser of maximum average power laser 300 (W) emitting at 1064 nm and fiber coupled has been used to irradiate stainless steel 304 tubes of diameter 12.7 mm, 0.6 mm thickness and 60 mm in length. An analytical model has been used to determine the bending angle by using Matlab program software. The changes of material specification during the laser tube bending process due to the temperature rise has been studied and the analytical model has been modified and enhanced. Particle Swarm Optimization (PSO) was used to optimize the analytical and experimental results and reduce the mean absolute error.

  1. Interaction of a flame front with its self-generated flow in an enclosure; The tulip flame phenomenon

    Energy Technology Data Exchange (ETDEWEB)

    Gonzalez, M.; Borghi, R.; Saouab, A. (Univ. de Rouen, Mont-Saint-Aignan (FR))


    This paper reports on the propagation of a flame front under nonturbulent condition in a closed tube ignited at one end which is numerically investigated using a computing procedure based on finite volumes technique and devoted to two-dimensional, compressible, reacting flows. A global one-step reaction for the chemical process and an Arrhenius law for fuel consumption are assumed. The detailed analysis of the results of computations in which wall friction, tube aspect ratio and initial flame configuration are varied allows to highlight the influence of different parameters and to get more insight into the tulip-shaped flame phenomenon. In particular, Darrieus-landau instability is examined by comparing the shape variations of an initially perturbed flat front in a tube closed at both ends to those in a tube in which the ignition end is open while the opposite one is closed. Attention is also given to the computed flame generated flowfield; the flame front-confined flow interaction is specially scrutinized. Furthermore, the oscillatory acoustic regime occurring during tulip flame appearance, as well as the collapse of the tulip shape in tubes of large aspect ratio, already experimentally put into evidence but never numerically addressed, have also been simulated and discussed.

  2. 24 CFR 3280.203 - Flame spread limitations and fire protection requirements. (United States)


    ... 24 Housing and Urban Development 5 2010-04-01 2010-04-01 false Flame spread limitations and fire... Fire Safety § 3280.203 Flame spread limitations and fire protection requirements. (a) Establishment of flame spread rating. The surface flame spread rating of interior-finish material must not exceed...

  3. Dithiocarbamate functionalized or surface sorbed Merrifield resin beads as column materials for on line flow injection-flame atomic absorption spectrometry determination of lead. (United States)

    Praveen, R S; Naidu, G R K; Prasada Rao, T


    This article describes the preparation of dithiocarbamate immobilized/functionalized and diethylammonium dithiocarbamate (DDTC) sorbed Merrifield Chloromethylated Resin (MCR) beads and comparison of these materials for on-line flow injection (FI)-flame atomic absorption spectrometry (FAAS) determination of lead. The above two materials enrich lead quantitatively over an identical optimal pH range (8.0-9.0), a preconcentration/loading time (up to 4 min) and elution with acidified methanol (a minimum of 0.01 molL(-1) HNO(3) in methanol). However, the detection limit for lead using dithiocarbamate functionalized MCR beads is 1.3 microgL(-1) compared to 3 microgL(-1) for DDTC sorbed MCR beads. Again, the sensitivity enhancement over direct FAAS signal is 48- and 27-fold, respectively. In addition, dithiocarbamate functionalized MCR beads offers better precision compared to DDTC sorbed MCR beads as the corresponding relative standard deviation (R.S.D.) values for five successive determinations of 0.20 microgmL(-1) are 1.44 and 4.36%, respectively. The accuracy of the developed on-line FI-FAAS procedure employing dithiocarbamate functionalized MCR beads as column material was tested by analyzing Certified Reference Material (CRM) of soil (IAEA soil-7) and marine sediment reference material (MESS-3) supplied by International Atomic Energy Agency (IAEA), Vienna and National Research Council (NRC), Canada, respectively. Furthermore, the developed procedure has been successfully tested for the analysis of surface, pond, ground and effluent water and soil samples collected from the vicinity of lead acid battery industry in India.

  4. Bifunctional thermoelectric tube made of tilted multilayer material as an alternative to standard heat exchangers. (United States)

    Takahashi, Kouhei; Kanno, Tsutomu; Sakai, Akihiro; Tamaki, Hiromasa; Kusada, Hideo; Yamada, Yuka


    Enormously large amount of heat produced by human activities is now mostly wasted into the environment without use. To realize a sustainable society, it is important to develop practical solutions for waste heat recovery. Here, we demonstrate that a tubular thermoelectric device made of tilted multilayer of Bi(0.5)Sb(1.5)Te3/Ni provides a promising solution. The Bi(0.5)Sb(1.5)Te3/Ni tube allows tightly sealed fluid flow inside itself, and operates in analogy with the standard shell and tube heat exchanger. We show that it achieves perfect balance between efficient heat exchange and high-power generation with a heat transfer coefficient of 4.0 kW/m(2)K and a volume power density of 10 kW/m(3) using low-grade heat sources below 100°C. The Bi(0.5)Sb(1.5)Te3/Ni tube thus serves as a power generator and a heat exchanger within a single unit, which is advantageous for developing new cogeneration systems in factories, vessels, and automobiles where cooling of excess heat is routinely carried out.

  5. Preparation and characterizations of flame retardant polyamide 66 fiber (United States)

    Li, Y. Y.; Liu, K.; Xiao, R.


    The polyamide 66 (PA66) is one of the most important thermoplastic materials, but it has the drawback of flammability. So the flame retardant PA66 was prepared by condensation polymerization using nylon salt and DOPO-based flame retardant in this paper. Then the flame retardant PA66 fiber was manufactured via melt spinning. The properties of flame retardant PA66 and flame retardant PA66 fiber were investigated by relative viscosity, differential scanning calorimetry (DSC), tensile test, vertical burning test (UL94) and limiting oxygen index (LOI) test. Although the loading of the DOPO-based flame retardant decreased the molecular weight, the melting temperature, the crystallinity and the mechanical properties of flame retardant PA66, the flame retardancy properties improved. The flame retardant PA66 loaded with 5.5 wt% of DOPO-based flame retardant can achieve a UL94 V-0 rating with a LOI value of 32.9%. The tenacity at break decreased from 4.51 cN·dtex-1 for PA66 fiber to 2.82 cN·dtex-1 for flame retardant PA66 fiber which still satisfied the requirements for fabrics. The flame retardant PA66 fiber expanded the application of PA66 materials which had a broad developing prospect.

  6. Modified Powder-in-Tube Technique Based on the Consolidation Processing of Powder Materials for Fabricating Specialty Optical Fibers

    Directory of Open Access Journals (Sweden)

    Jean-Louis Auguste


    Full Text Available The objective of this paper is to demonstrate the interest of a consolidation process associated with the powder-in-tube technique in order to fabricate a long length of specialty optical fibers. This so-called Modified Powder-in-Tube (MPIT process is very flexible and paves the way to multimaterial optical fiber fabrications with different core and cladding glassy materials. Another feature of this technique lies in the sintering of the preform under reducing or oxidizing atmosphere. The fabrication of such optical fibers implies different constraints that we have to deal with, namely chemical species diffusion or mechanical stress due to the mismatches between thermal expansion coefficients and working temperatures of the fiber materials. This paper focuses on preliminary results obtained with a lanthano-aluminosilicate glass used as the core material for the fabrication of all-glass fibers or specialty Photonic Crystal Fibers (PCFs. To complete the panel of original microstructures now available by the MPIT technique, we also present several optical fibers in which metallic particles or microwires are included into a silica-based matrix.

  7. Explosive-driven shock wave and vortex ring interaction with a propane flame (United States)

    Giannuzzi, P. M.; Hargather, M. J.; Doig, G. C.


    Experiments were performed to analyze the interaction of an explosively driven shock wave and a propane flame. A 30 g explosive charge was detonated at one end of a 3-m-long, 0.6-m-diameter shock tube to produce a shock wave which propagated into the atmosphere. A propane flame source was positioned at various locations outside of the shock tube to investigate the effect of different strength shock waves. High-speed retroreflective shadowgraph imaging visualized the shock wave motion and flame response, while a synchronized color camera imaged the flame directly. The explosively driven shock tube was shown to produce a repeatable shock wave and vortex ring. Digital streak images show the shock wave and vortex ring propagation and expansion. The shadowgrams show that the shock wave extinguishes the propane flame by pushing it off of the fuel source. Even a weak shock wave was found to be capable of extinguishing the flame.

  8. Dataset of Atmospheric Environment Publication in 2016, Characterization of organophosphorus flame retardants’ sorption on building materials and consumer products (United States)

    U.S. Environmental Protection Agency — The data presented in this data file is a product of a journal publication. The dataset contains OPFR sorption concentrations on building materials and consumer...

  9. Layer-by-Layer Assembly of Halogen-Free Polymeric Materials on Nylon/Cotton Blend for Flame Retardant Applications (United States)


    This is a reprinted professional journal article that originally appeared online in Fire and Materials on October 27, 2014 in Wiley Online Library ...intentionally left blank FIRE AND MATERIALS Fire Mater. (2014) Published online in Wiley Online Library ( DOI: 10.1002/ was searched using the NIST 2008 MS library and the CDS’s pyrolysis library.Copyright © 2014 John Wiley & Sons, Ltd. Fire Mater. (2014) DOI

  10. The electro-mechanical phase transition of Gent model dielectric elastomer tube with two material constants (United States)

    Liu, Liwu; Luo, Xiaojian; Fei, Fan; Wang, Yixing; Leng, Jinsong; Liu, Yanju


    Applied to voltage, a dielectric elastomer membrane may deform into a mixture of two states under certain conditions. One of which is the flat state and the other is the wrinkled state. In the flat state, the membrane is relatively thick with a small area, while on the contrary, in the wrinkled state, the membrane is relatively thin with a large area. The coexistence of these two states may cause the electromechanical phase transition of dielectric elastomer. The phase diagram of idea dielectric elastomer membrane under unidirectional stress and voltage inspired us to think about the liquid-to-vapor phase transition of pure substance. The practical working cycle of a steam engine includes the thermodynamical process of liquid-to-vapor phase transition, the fact is that the steam engine will do the maximum work if undergoing the phase transition process. In this paper, in order to consider the influence of coexistent state of dielectric elastomer, we investigate the homogeneous deformation of the dielectric elastomer tube. The theoretical model is built and the relationship between external loads and stretch are got, we can see that the elastomer tube experiences the coexistent state before reaching the stretching limit from the diagram. We think these results can guide the design and manufacture of energy harvesting equipments.

  11. Preparation of Flame Resistant CPE/EPDM Cable Materials%阻燃型 CPE/EPDM 电缆母料研制

    Institute of Scientific and Technical Information of China (English)

    王波; 汤粤豫; 杨金明


    CPE/EPDM cable materials were prepared with CPE and EPDM as raw ma-terials,dicumyl peroxide (DCP)and triallyl isocyanurate (TAIC)as curing agents,white carbon black as reinforcement agent,Al(OH)3 and Mg(OH)2 as flame retardant and with the right amount of plasticizer,stabilizer and age resister.The results show that the vol-ume resistivity of cable materials can be up to 8.843 × 10 1 4 Ω· cm, the breakdown strength is 36.5 kV/mm, the elongation at break is 230% and the tensile strength is 3.88 MPa.The indicators meet the requirements and the performance can meet the need of cable materials.%以氯化聚乙烯/三元乙丙橡胶(CPE/EPDM)作为电缆料的原料,以过氧化二异丙苯(DCP)/三烯丙基氰尿酸酯(TAIC)为硫化剂,白炭黑为补强剂,Al(OH)3和 Mg(OH)2作为阻燃剂,并配以适量的增塑剂、稳定剂和防老剂,制备阻燃绝缘电缆料。经测试,电缆料的体积电阻率可达到8.843×1014Ω·cm,击穿强度为36.5 kV/mm,断裂伸长率为230%,拉伸强度为3.88 MPa。各项指标达到要求,性能满足电缆料需要。

  12. Study on Reactive Flame Retardant Polyester Resin Composite Materials with Light Permeability%反应型阻燃树脂基透光复合材料的研究

    Institute of Scientific and Technical Information of China (English)



    以反应型阻燃不饱和聚酯树脂为基体材料,无碱玻璃纤维布为增强材料,制备了具有阻燃性的透光复合材料,探讨了其制备工艺、性能及影响因素。%This paper studies how to synthesize the flame retardant composite material with light permeability. It is based on the re active flame retardant unsaturated polyester resin and takes E-glass fiber as reinforced material. This paper also discusses its making technique quality and some effects on it.

  13. Flame structure of methane inverse diffusion flame

    KAUST Repository

    Elbaz, Ayman M.


    This paper presents high speed images of OH-PLIF at 10. kHz simultaneously with 2D PIV (particle image velocimetry) measurements collected along the entire length of an inverse diffusion flame with circumferentially arranged methane fuel jets. For a fixed fuel flow rate, the central air jet Re was varied, leading to four air to fuel velocity ratios, namely Vr = 20.7, 29, 37.4 and 49.8. A double flame structure could be observed composed of a lower fuel entrainment region and an upper mixing and intense combustion region. The entrainment region was enveloped by an early OH layer, and then merged through a very thin OH neck to an annular OH layer located at the shear layer of the air jet. The two branches of this annular OH layer broaden as they moved downstream and eventfully merged together. Three types of events were observed common to all flames: breaks, closures and growing kernels. In upstream regions of the flames, the breaks were counterbalanced by flame closures. These breaks in OH signal were found to occur at locations where locally high velocity flows were impinging on the flame. As the Vr increased to 37.4, the OH layers became discontinuous over the downstream region of the flame, and these regions of low or no OH moved upstream. With further increases in Vr, these OH pockets act as flame kernels, growing as they moved downstream, and became the main mechanism for flame re-ignition. Along the flame length, the direction of the two dimensional principle compressive strain rate axis exhibited a preferred orientation of approximately 45° with respect to the flow direction. Moreover, the OH zones were associated with elongated regions of high vorticity. © 2013 Elsevier Inc.

  14. Refractory Materials for Flame Deflector Protection System Corrosion Control: Similar Industries and/or Launch Facilities Survey (United States)

    Calle, Luz Marina; Hintze, Paul E.; Parlier, Christopher R.; Coffman, Brekke E.; Sampson, Jeffrey W.; Kolody, Mark R.; Curran, Jerome P.; Perusich, Stephen A.; Trejo, David; Whitten, Mary C.; Zidek, Jason


    A trade study and litera ture survey of refractory materials (fi rebrick. refractory concrete. and si licone and epoxy ablatives) were conducted to identify candidate replacement materials for Launch Complexes 39A and 398 at Kennedy Space Center (KSC). In addition, site vis its and in terviews with industry expens and vendors of refractory materials were conducted. As a result of the si te visits and interviews, several products were identified for launch applications. Firebrick is costly to procure and install and was not used in the si tes studied. Refractory concrete is gunnable. adheres well. and costs less 10 install. Martyte. a ceramic fi lled epoxy. can protect structural stccl but is costly. difficullto apply. and incompatible with silicone ablatives. Havanex, a phenolic ablative material, is easy to apply but is costly and requires frequent replacement. Silicone ablatives are ineJ[pensive, easy to apply. and perl'onn well outside of direct rocket impingement areas. but refractory concrete and epoxy ablatives provide better protection against direcl rocket exhaust. None of the prodUCIS in this trade study can be considered a panacea for these KSC launch complexes. but the refractory products. individually or in combination, may be considered for use provided the appropriate testing requirements and specifications are met.

  15. Flame Retardation Modification of Paper-Based PVC Wallcoverings

    Directory of Open Access Journals (Sweden)

    Lin Hui


    Full Text Available The flame-retarded paper-based polyvinyl chloride (PVC wallcoverings were successfully prepared, using plant fiber paper as base material and adding inorganic flame retardants and flame-retarded plasticizer as additives. Flame retardancy, thermostability, smoke suppression and mechanical properties were tested regarding to the prepared wallcoverings. The results showed that 2ZnO·3B2O3·3.5H2O could improve flame retardancy and thermostability of paper-based PVC wallcoverings; plasticizer tricresyl phosphate increased flame retardancy of the prepared materials auxiliarily. Also, flame-retarded paper-based PVC wallcoverings with higher flame retardancy, smoke suppression and mechanical property was prepared using plant fiber paper with fix quantity of 90 g/m3 as base material, using 2ZnO·3B2O3·3.5H2O as inorganic flame retardant, and using tricresyl phosphate as plasticizer. For the flame-retarded paper-based PVC wallcoverings in this study, the limit oxygen index (LOI reaches 32.3, maximal smoke density is 16.91 %, and the horizontal and longitudinal wet tensile strength reaches 1.38 kN·m−1 and 1.51 kN·m−1 respectively. Meanwhile, its flame retardancy meets the requirements about flame retardancy for material Class B1 listed in Chinese National Standards GB 8624-2012, Classification for burning behavior of building materials and products. This research creates an effective path to prepare paper-based PVC wallcoverings with high flame retardancy.

  16. Indoor Solar Thermal Energy Saving Time with Phase Change Material in a Horizontal Shell and Finned-Tube Heat Exchanger

    Directory of Open Access Journals (Sweden)

    S. Paria


    Full Text Available An experimental as well as numerical investigation was conducted on the melting/solidification processes of a stationary phase change material (PCM in a shell around a finned-tube heat exchanger system. The PCM was stored in the horizontal annular space between a shell and finned-tube where distilled water was employed as the heat transfer fluid (HTF. The focus of this study was on the behavior of PCM for storage (charging or melting and removal (discharging or solidification, as well as the effect of flow rate on the charged and discharged solar thermal energy. The impact of the Reynolds number was determined and the results were compared with each other to reveal the changes in amount of stored thermal energy with the variation of heat transfer fluid flow rates. The results showed that, by increasing the Reynolds number from 1000 to 2000, the total melting time decreases by 58%. The process of solidification also will speed up with increasing Reynolds number in the discharging process. The results also indicated that the fluctuation of gradient temperature decreased and became smooth with increasing Reynolds number. As a result, by increasing the Reynolds number in the charging process, the theoretical efficiency rises.

  17. Indoor solar thermal energy saving time with phase change material in a horizontal shell and finned-tube heat exchanger. (United States)

    Paria, S; Sarhan, A A D; Goodarzi, M S; Baradaran, S; Rahmanian, B; Yarmand, H; Alavi, M A; Kazi, S N; Metselaar, H S C


    An experimental as well as numerical investigation was conducted on the melting/solidification processes of a stationary phase change material (PCM) in a shell around a finned-tube heat exchanger system. The PCM was stored in the horizontal annular space between a shell and finned-tube where distilled water was employed as the heat transfer fluid (HTF). The focus of this study was on the behavior of PCM for storage (charging or melting) and removal (discharging or solidification), as well as the effect of flow rate on the charged and discharged solar thermal energy. The impact of the Reynolds number was determined and the results were compared with each other to reveal the changes in amount of stored thermal energy with the variation of heat transfer fluid flow rates. The results showed that, by increasing the Reynolds number from 1000 to 2000, the total melting time decreases by 58%. The process of solidification also will speed up with increasing Reynolds number in the discharging process. The results also indicated that the fluctuation of gradient temperature decreased and became smooth with increasing Reynolds number. As a result, by increasing the Reynolds number in the charging process, the theoretical efficiency rises.

  18. Development and Execution of a Large-scale DDT Tube Test for IHE Material Qualification

    Energy Technology Data Exchange (ETDEWEB)

    Parker, Gary Robert [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Broilo, Robert M. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Lopez-Pulliam, Ian Daniel [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Vaughan, Larry Dean [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)


    Insensitive High Explosive (IHE) Materials are defined in Chapter IX of the DOE Explosive Safety Standard (DOE-STD-1212-2012) as being materials that are massdetonable explosives that are so insensitive that the probability of accidental initiation or transition from burning to detonation is negligible1. There are currently a number of tests included in the standard that are required to qualify a material as IHE, however, none of the tests directly evaluate for the transition from burning to detonation (aka deflagration-to-detonation transition, DDT). Currently, there is a DOE complex-wide effort to revisit the IHE definition in DOE-STD-1212-2012 and change the qualification requirements. The proposal lays out a new approach, requiring fewer, but more appropriate tests, for IHE Material qualification. One of these new tests is the Deflagration-to-Detonation Test. According to the redefinition proposal, the purpose of the new deflagration-todetonation test is “to demonstrate that an IHE material will not undergo deflagration-to-detonation under stockpile relevant conditions of scale, confinement, and material condition. Inherent in this test design is the assumption that ignition does occur, with onset of deflagration. The test design will incorporate large margins and replicates to account for the stochastic nature of DDT events.” In short, the philosophy behind this approach is that if a material fails to undergo DDT in a significant over-test, then it is extremely unlikely to do so in realistic conditions. This effort will be valuable for the B61 LEP to satisfy their need qualify the new production lots of PBX 9502. The work described in this report is intended as a preliminary investigation to support the proposed design of an overly conservative, easily fielded DDT test for updated IHE Material Qualification standard. Specifically, we evaluated the aspects of confinement, geometry, material morphology and temperature. We also developed and tested a

  19. Development of Super Toughened Halogen-free Flame Retardant PA6 Riot Suit Special Material%超韧无卤阻燃尼龙6防暴服专用料的研制

    Institute of Scientific and Technical Information of China (English)

    刘志; 马璐; 宋航


    Super toughened halogen-free flame retardant nylon(PA) 6 flame was prepared by adding different components using twin-screw extrusion process. The effects of different viscosity nylon 6,toughening agents,flame retardants and processing technology on the material properties were studied. The results show that the material can obtain optimum impact resistance and processability by mixxing middle viscosity PA6 with low viscosity PA6;the toughening effect is the best when adding 15 parts POE-g-MAH;red phosphorus masterbatch of small size and high phosphorus content has good flame retardancy and less impact on the mechanical properties of the system;Mg(OH)2 has a good synergistic effect of flame and smoke,and the optimal content is three parts;appropriate screw combination can improve flame stability of the system.%采用双螺杆挤出加工工艺,通过添加不同组分制得超韧无卤阻燃尼龙(PA)6材料,比较了不同黏度PA6、增韧剂、阻燃剂及加工工艺对材料性能的影响。结果表明,中黏搭配低黏PA6材料可获得最佳的冲击性能和加工性能;在添加15份马来酸酐接枝乙烯–辛烯共聚物增韧剂时增韧效果最好;小粒径、高含量(红磷)红磷母粒的阻燃效果较好且对体系的力学性能影响较小;Mg(OH)2具有很好的协效阻燃和消烟作用,在添加量为3份时效果最佳;适当的螺杆组合可提高体系的阻燃稳定性。

  20. High-pressure {sup 4}He drift tubes for fissile material detection

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Zhehui, E-mail: [Los Alamos National Laboratory, Los Alamos, NM 87545 (United States); Morris, Christopher L. [Los Alamos National Laboratory, Los Alamos, NM 87545 (United States); Gray, F.E. [Regis University, Denver, CO 80221 (United States); Bacon, J.D.; Brockwell, M.I.; Chang, D.Y.; Chung, K.; Dai, W.G.; Greene, S.J.; Hogan, G.E.; Lisowski, P.W.; Makela, M.F.; Mariam, F.G.; McGaughey, P.L. [Los Alamos National Laboratory, Los Alamos, NM 87545 (United States); Mendenhall, M. [California Institute of Technology, Pasadena, CA 91125 (United States); Milner, E.C.; Miyadera, H.; Murray, M.M.; Perry, J.O.; Roybal, J.D. [Los Alamos National Laboratory, Los Alamos, NM 87545 (United States); and others


    A detector efficiency model based on energy extraction from neutrons is described and used to compare {sup 4}He detectors with liquid scintillators (EJ301/NE-213). Detector efficiency can be divided into three regimes: single neutron scattering, multiple neutron scattering, and a transition regime in-between. For an average fission neutron of 2 MeV, the amount of {sup 4}He needed would be about 1/4 of the amount of the mass of EJ301/NE-213 in the single-scattering regime. For about 50% neutron energy extraction (1 MeV out of 2 MeV), the two types of detectors ({sup 4}He in the transition regime, EJ301 still in the single-scattering regime) have comparable mass, but {sup 4}He detectors can be much larger depending on the number density. A six-tube 11-bar-pressure {sup 4}He detector prototype is built and tested. Individual electrical pulses from the detector are recorded using a 12-bit digitizer. Differences in pulse rise time and amplitudes, due to different energy loss of neutrons and gamma rays, are used for neutron/gamma separation. Several energy spectra are also obtained and analyzed.

  1. Atomic-absorption determination of mercury in geological materials by flame and carbon-rod atomisation after solvent extraction and using co-extracted silver as a matrix modifier (United States)

    Sanzolone, R.F.; Chao, T.T.


    Based on modifications and expansion of the original Tindall's solvent extraction flame atomic-absorption procedure, an atomic-absorption spectrophotometric method has been developed for the determination of mercury in geological materials. The sample is digested with nitric and hydrochloric acids in a boiling water-bath. The solution is made ammoniacal and potassium iodide and silver nitrate are added. The mercury is extracted into isobutyl methyl ketone as the tetraiodomercurate(ll). Added silver is co-extracted with mercury and serves as a matrix modifier in the carbon-rod atomiser. The mercury in the isobutyl methyl ketone extract may be determined by either the flame- or the carbon-rod atomisation method, depending on the concentration level. The limits of determination are 0.05-10 p.p.m. of mercury for the carbon-rod atomisation and 1 -200 p.p.m. of mercury for the flame atomisation. Mercury values for reference samples obtained by replicate analyses are in good agreement with those reported by other workers, with relative standard deviations ranging from 2.3 to 0.9%. Recoveries of mercury spiked at two levels were 93-106%. Major and trace elements commonly found in geological materials do not interfere.

  2. Combustion Characteristics for Turbulent Prevaporized Premixed Flame Using Commercial Light Diesel and Kerosene Fuels

    Directory of Open Access Journals (Sweden)

    Mohamed S. Shehata


    Full Text Available Experimental study has been carried out for investigating fuel type, fuel blends, equivalence ratio, Reynolds number, inlet mixture temperature, and holes diameter of perforated plate affecting combustion process for turbulent prevaporized premixed air flames for different operating conditions. CO2, CO, H2, N2, C3H8, C2H6, C2H4, flame temperature, and gas flow velocity are measured along flame axis for different operating conditions. Gas chromatographic (GC and CO/CO2 infrared gas analyzer are used for measuring different species. Temperature is measured using thermocouple technique. Gas flow velocity is measured using pitot tube technique. The effect of kerosene percentage on concentration, flame temperature, and gas flow velocity is not linearly dependent. Correlations for adiabatic flame temperature for diesel and kerosene-air flames are obtained as function of mixture strength, fuel type, and inlet mixture temperature. Effect of equivalence ratio on combustion process for light diesel-air flame is greater than for kerosene-air flame. Flame temperature increases with increased Reynolds number for different operating conditions. Effect of Reynolds number on combustion process for light diesel flame is greater than for kerosene flame and also for rich flame is greater than for lean flame. The present work contributes to design and development of lean prevaporized premixed (LPP gas turbine combustors.

  3. Thermal Stability and Material Balance of Nanomaterials in Waste Incineration (United States)

    Paur, H.-R.; Baumann, W.; Hauser, M.; Lang, I.; Teuscher, N.; Seifert, H.; Stapf, D.


    Nanostructured materials are widely used to improve the properties of consumer products such as tires, cosmetics, light weight equipment etc. Due to their complex composition these products are hardly recycled and thermal treatment is preferred. In this study we investigated the thermal stability and material balance of nanostructured metal oxides in flames and in an industrial waste incinerator. We studied the size distribution of nanostructured metal oxides (CeO2, TiO2, SiO2) in a flame reactor and in a heated reaction tube. In the premixed ethylene/air flame, nano-structured CeO2 partly evaporates forming a new particle mode. This is probably due to chemical reactions in the flame. In addition sintering of agglomerates takes place in the flame. In the electrically heated reaction tube however only sintering of the agglomerated nanomaterials is observed. Ceria has a low background in waste incinerators and is therefore a suitable tracer for investigating the fate of nanostructured materials. Low concentrations of Ceria were introduced by a two-phase nozzle into the post-combustion zone of a waste incinerator. By the incineration of coal dust in a burning chamber the Ceria nanoparticles are mainly found in the size range of the fly ash (1 - 10 µm) because of agglomeration. With gas as a fuel less agglomeration was observed and the Ceria nanoparticles were in the particle size range below 1 µm.

  4. Tratamento de superfície de tubos de poliamida 11 com chama para deposição de revestimento hidrofílico biomédico Flame surface treatment of polyamide 11 tubes for the deposition of biomedical hydrophilic coatings

    Directory of Open Access Journals (Sweden)

    Waldemar F. M. Martins


    Full Text Available O processo para obtenção de uma camada polimérica hidrofílica sobre um componente polimérico pode ser basicamente dividido em: tratamento de superfície do substrato, aplicação e cura do revestimento. O tratamento de superfície se faz necessário em função da grande diferença de polaridade comumente apresentada entre os materiais que compõem este conjunto e da baixa energia livre de superfície inerente aos principais materiais utilizados como substrato, fatores estes que dificultam a adesão entre eles. Neste trabalho foi avaliada a influência da técnica de tratamento de superfície através de exposição à chama sobre a tentativa de aumento da energia livre de superfície de tubos de poliamida 11. Amostras foram submetidas ao tratamento durante 5, 10, 20, 30 e 60 segundos, e posteriormente caracterizadas por goniometria, microscopia eletrônica de varredura, espectroscopia de infravermelho e resistência ao risco da camada depositada. Amostras não tratadas foram analisadas como parâmetro de controle das modificações. Os resultados mostraram um aumento da molhabilidade e rugosidade da superfície, além de uma melhoria na adesão da camada hidrofílica após o tratamento.The process of obtaining a hydrophilic polymer coating on a polymeric component or product can be basically divided into: the substrate surface treatment, the coating application and the cross-linking. The substrate surface treatment is crucial due to the possible large difference in polarity between the polymers and the substrate materials, which commonly have low free surface energy and may severely hamper adhesion. This study evaluated the influence of flame surface treatment for the attempt of increasing the free energy surface of polyamide 11 tubes. Samples were submitted to treatment for 5, 10, 20, 30 and 60 seconds, and subsequently characterized by goniometry, scanning electron microscopy, infrared spectroscopy and scratch resistance of the deposited

  5. Effect of electron beam irradiation and microencapsulation on the flame retardancy of ethylene-vinyl acetate copolymer materials during hot water ageing test (United States)

    Sheng, Haibo; Zhang, Yan; Wang, Bibo; Yu, Bin; Shi, Yongqian; Song, Lei; Kundu, Chanchal Kumar; Tao, Youji; Jie, Ganxin; Feng, Hao; Hu, Yuan


    Microencapsulated ammonium polyphosphate (MCAPP) in combination with polyester polyurethane (TPU) was used to flame retardant ethylene-vinyl acetate copolymer (EVA). The EVA composites with different irradiation doses were immersed in hot water (80 °C) to accelerate ageing process. The microencapsulation and irradiation dose ensured positive impacts on the properties of the EVA composites in terms of better dimensional stability and flame retardant performance. The microencapsulation of APP could lower its solubility in water and the higher irradiation dose led to the more MCAPP immobilized in three dimensional crosslinked structure of the EVA matrix which could jointly enhance the flame retardant and electrical insulation properties of the EVA composites. So, the EVA composites with 180 kGy irradiation dose exhibited better dimensional stability than the EVA composites with 120 kGy due to the higher crosslinking degree. Moreover, the higher irradiation dose lead to the more MCAPP immobilizated in crosslinked three-dimensional structure of EVA, enhancing the flame retardancy and electrical insulation properties of the EVA composites. After ageing test in hot water at 80 °C for 2 weeks, the EVA/TPU/MCAPP composite with 180 kGy could still maintain the UL-94 V-0 rating and the limiting oxygen index (LOI) value was as high as 30%. This investigation indicated the flame retardant EVA cable containing MCAPP could achieve stable properties and lower electrical fire hazard risk during long-term hot water ageing test.

  6. Effect of vorticity flip-over on the premixed flame structure: First experimental observation of type I inflection flames

    CERN Document Server

    El-Rabii, Hazem


    Premixed flames propagating in horizontal tubes are observed to take on shape convex towards the fresh mixture, which is commonly explained as a buoyancy effect. A recent rigorous analysis has shown, on the contrary, that this process is driven by the balance of vorticity generated by a curved flame front with the baroclinic vorticity, and predicted existence of a regime in which the leading edge of the flame front is concave. We report first experimental realization of this regime. Our experiments on ethane and n-butane mixtures with air show that flames with an inflection point on the front are regularly produced in lean mixtures, provided that a sufficiently weak ignition is used. The observed flame shape perfectly agrees with the theoretically predicted.

  7. Current status of materials development of nuclear fuel cladding tubes for light water reactors

    Energy Technology Data Exchange (ETDEWEB)

    Duan, Zhengang, E-mail: [Department of Quantum Science and Energy Engineering, Graduate School of Engineering, Tohoku University, Sendai, Miyagi 980-8577 (Japan); Yang, Huilong [Department of Nuclear Engineering, School of Engineering, The University of Tokyo, Nakagun, Ibaraki 319-1188 (Japan); Satoh, Yuhki [Institute for Materials Research, Tohoku University, Sendai, Miyagi 980-8577 (Japan); Murakami, Kenta; Kano, Sho; Zhao, Zishou; Shen, Jingjie [Department of Nuclear Engineering, School of Engineering, The University of Tokyo, Nakagun, Ibaraki 319-1188 (Japan); Abe, Hiroaki, E-mail: [Department of Nuclear Engineering, School of Engineering, The University of Tokyo, Nakagun, Ibaraki 319-1188 (Japan)


    Zirconium-based (Zr-based) alloys have been widely used as materials for the key components in light water reactors (LWRs), such as fuel claddings which suffer from waterside corrosion, hydrogen uptakes and strength loss at elevated temperature, especially during accident scenarios like the lost-of-coolant accident (LOCA). For the purpose of providing a safer, nuclear leakage resistant and economically viable LWRs, three general approaches have been proposed so far to develop the accident tolerant fuel (ATF) claddings: optimization of metallurgical composition and processing of Zr-based alloys, coatings on existing Zr-based alloys and replacement of current Zr-based alloys. In this manuscript, an attempt has been made to systematically present the historic development of Zr-based cladding, including the impacts of alloying elements on the material properties. Subsequently, the research investigations on coating layer on the surface of Zr-based claddings, mainly referring coating materials and fabrication methods, have been broadly reviewed. The last section of this review provides the introduction to alternative materials (Non-Zr) to Zr-based alloys for LWRs, such as advanced steels, Mo-based, and SiC-based materials.

  8. Candle flames in microgravity (United States)

    Dietrich, D. L.; Ross, H. D.; Tien, J. S.


    The candle flame in both normal and microgravity is non-propagating. In microgravity, however, the candle flame is also non-convective where (excepting Stefan flow) pure diffusion is the only transport mode. It also shares many characteristics with another classical problem, that of isolated droplet combustion. Given their qualitatively similar flame shapes and the required heat feedback to condensed-phase fuels, the gas-phase flow and temperature fields should be relatively similar for a droplet and a candle in reduced gravity. Unless the droplet diameter is maintained somehow through non-intrusive replenishment of fuel, the quasi-steady burning characteristics of a droplet can be maintained for only a few seconds. In contrast, the candle flame in microgravity may achieve a nearly steady state over a much longer time and is therefore ideal for examining a number of combustion-related phenomena. In this paper, we examine candle flame behavior in both short-duration and long-duration, quiescent, microgravity environments. Interest in this type of flame, especially 'candle flames in weightlessness', is demonstrated by very frequent public inquiries. The question is usually posed as 'will a candle flame burn in zero gravity', or, 'will a candle burn indefinitely (or steadily) in zero gravity in a large volume of quiescent air'. Intuitive speculation suggests to some that, in the absence of buoyancy, the accumulation of products in the vicinity of the flame will cause flame extinction. The classical theory for droplet combustion with its spherically-shaped diffusion flame, however, shows that steady combustion is possible in the absence of buoyancy if the chemical kinetics are fast enough. Previous experimental studies of candle flames in reduced and microgravity environments showed the flame could survive for at least 5 seconds, but did not reach a steady state in the available test time.

  9. A new certified reference material for benzene measurement in air on a sorbent tube: development and proficiency testing. (United States)

    Caurant, A; Lalère, B; Schbath, M-C; Stumpf, C; Sutour, C; Mace, T; Quisefit, J-P; Doussin, J-F; Vaslin-Reimann, S


    A certified matrix reference material (CRM) for the measurement of benzene in ambient air has been developed at Laboratoire National de Métrologie et d'Essais. The production of these CRMs was conducted using a gravimetric method fully traceable to the International System of Units. The CRMs were prepared by sampling an accurate mass of a gaseous primary reference material of benzene, using a high-precision laminar flowmeter and a mass flow controller, with a PerkinElmer sampler filled with Carbopack™ X sorbent. The relative standard deviations obtained for the preparation of a batch of 20 tubes loaded with 500 ng of benzene were below 0.2%. Each CRM is considered independent from the others and with its own certified value and an expanded uncertainty estimated to be within 0.5%, lower than the uncertainties of benzene CRMs already available worldwide. The stability of these materials was also established up to 12 months. These CRMs were implemented during proficiency testing, to evaluate the analytical performances of seven French laboratories involved in benzene air monitoring.

  10. Ear Tubes (United States)

    ... ENTCareers Marketplace Find an ENT Doctor Near You Ear Tubes Ear Tubes Patient Health Information News media ... and throat specialist) may be considered. What are ear tubes? Ear tubes are tiny cylinders placed through ...

  11. Flame Holder System (United States)

    Haskin, Henry H. (Inventor); Vasquez, Peter (Inventor)


    A flame holder system includes a modified torch body and a ceramic flame holder. Catch pin(s) are coupled to and extend radially out from the torch body. The ceramic flame holder has groove(s) formed in its inner wall that correspond in number and positioning to the catch pin(s). Each groove starts at one end of the flame holder and can be shaped to define at least two Each groove is sized to receive one catch pin therein when the flame holder is fitted over the end of the torch body. The flame holder is then manipulated until the catch pin(s) butt up against the end of the groove(s).

  12. High insulation foam glass material from waste cathode ray tube panel glass

    DEFF Research Database (Denmark)

    König, Jakob; Petersen, Rasmus Rosenlund; Yue, Yuanzheng

    . In general CRT consists of two types of glasses: barium/strontium containing glass (panel glass) and lead containing glass (funnel and panel glass). In this work we present the possibility to produce high performance insulation material from the recycled lead-free glass. We studied the influence of foaming...... parameters on the characteristics of foamed glass. CRT panel glass was crushed, milled and sieved below 63 m. Activated carbon used as a foaming agent and MnO2 as an ‘oxidizing’ agent were mixed with glass powders by means of a planetary ball mill. Foaming effect was observed in the temperature range...

  13. Carotid and cerebral CT angiography using low volume of iodinated contrast material and low tube voltage. (United States)

    Kayan, M; Demirtas, H; Türker, Y; Kayan, F; Çetinkaya, G; Kara, M; Orhan Çelik, A; Umul, A; Yılmaz, Ö; Recep Aktaş, A


    To evaluate image quality of carotid computed tomography angiography (CTA) using a low voltage (80kV) and low amount of iodinated contrast material. A total of 101 patients referred for carotid CTA were randomly assigned to receive a specific protocol. In group A patients received intravenous administration of contrast material at a dose of 1mL/kg and CTA examinations were performed at 100kV. In group B, patients received intravenous administration of contrast material at a dose of 0.5mL/kg and CTA examinations were performed at 80kV. The same nonionic iodinated contrast material containing 370mg of iodine per mL was used in both groups. Attenuation values were measured from the center of specific arterial segments using regions of interest. Attenuation values above 300HU were accepted as significant. Institutional review board approval was obtained. A total of 50 patients were included in group A (38 men, 12 women; mean age, 63.56 years±13.18 [SD]) and 51 patients in group B (33 men, 18 women; mean age, 59.60 years±16.63 [SD]). A total of 1615 arterial segments (1515 common carotid artery-middle cerebral artery and 101 aortic arches) were analyzed. Venous contamination was not observed in either group. The mean attenuation values of all arterial segments in both groups were greater than 300HU. Mean arterial attenuation value in group B (499.22HU±97.25 [SD]) was significantly greater than in group A (374.36HU±73.79 [SD]) (P70%) was detected in 2 segments in group A and in 3 segments in group B, while grade IV stenosis (occlusion) was detected in 2 segments in group B. Distal common carotid artery dissection was detected in 1 patient and aortic dissection was detected in 1 patient in group B. Total dose-length product (DLP) value was significantly greater in group A (225.74mGy·cm±21.80 [SD]) than in group B (116.60mGy·cm±21.22 [SD]) (Pmaterial. This provides good image quality with low radiation dose. Copyright © 2016 Editions françaises de radiologie

  14. Crack initiation at long radial hydrides in Zr-2. 5Nb pressure tube material at elevated temperatures

    Energy Technology Data Exchange (ETDEWEB)

    Choubey, R.; Puls, M.P. (AECL Research, Pinawa, Manitoba (Canada). Whiteshell Labs.)


    Crack initiation at hydrides in smooth tensile specimens of Zr-2.5Nb pressure tube material was investigated at elevated temperatures up to 300 C using an acoustic emission (AE) technique. The test specimens contained long, radial hydride platelets. These hydrides have their plate normals oriented in the applied stress direction. Below [approximately]100 C, widespread hydride cracking was initiated at stresses close to the yield stress. An estimate of the hydride's fracture strength from this data yielded a value of [approximately]520 MPa at 100 C. Metallography showed that up to this temperature, cracking occurred along the length of the hydrides. However, at higher temperatures, there was no clear evidence of lengthwise cracking of hydrides, and fewer of the total hydride population fractured during deformation, as indicated by the AE record and the metallography. Moreover, the hydrides showed significant plasticity by-being able to flow along with the matrix material and align themselves parallel to the applied stress direction without fracturing. Near the fracture surface of the specimen, transverse cracking of the flow-reoriented hydrides had occurred at various points along the lengths of the hydrides. These fractures appear to be the result of stresses produced by large plastic strains imposed by the surrounding matrix on the less ductile hydrides.

  15. Design and evaluation of synthetic silica-based monolithic materials in shrinkable tube for efficient protein extraction. (United States)

    Alzahrani, Eman; Welham, Kevin


    Sample pretreatment is a required step in proteomics in order to remove interferences and preconcentrate the samples. Much research in recent years has focused on porous monolithic materials since they are highly permeable to liquid flow and show high mass transport compared with more common packed beds. These features are due to the micro-structure within the monolithic silica column which contains both macropores that reduce the back pressure, and mesopores that give good interaction with analytes. The aim of this work was to fabricate a continuous porous silica monolithic rod inside a heat shrinkable tube and to compare this with the same material whose surface has been modified with a C(18) phase, in order to use them for preconcentration/extraction of proteins. The performance of the silica-based monolithic rod was evaluated using eight proteins; insulin, cytochrome C, lysozyme, myoglobin, β-lactoglobulin, ovalbumin, hemoglobin, and bovine serum albumin at a concentration of 60 μM. The results show that recovery of the proteins was achieved by both columns with variable yields; however, the C(18) modified silica monolith gave higher recoveries (92.7 to 109.7%) than the non-modified silica monolith (25.5 to 97.9%). Both silica monoliths can be used with very low back pressure indicating a promising approach for future fabrication of the silica monolith inside a microfluidic device for the extraction of proteins from biological media.

  16. Using a Homemade Flame Photometer to Measure Sodium Concentration in a Sports Drink (United States)

    LaFratta, Christopher N.; Jain, Swapan; Pelse, Ian; Simoska, Olja; Elvy, Karina


    The purpose of this experiment was to create a simple and inexpensive flame photometer to measure the concentration of sodium in beverages, such as Gatorade. We created a nebulizer using small tubing and sprayed the sample into the base of a Bunsen burner. Adjacent to the flame was a photodiode with a filter specific for the emission of the sodium…

  17. Using a Homemade Flame Photometer to Measure Sodium Concentration in a Sports Drink (United States)

    LaFratta, Christopher N.; Jain, Swapan; Pelse, Ian; Simoska, Olja; Elvy, Karina


    The purpose of this experiment was to create a simple and inexpensive flame photometer to measure the concentration of sodium in beverages, such as Gatorade. We created a nebulizer using small tubing and sprayed the sample into the base of a Bunsen burner. Adjacent to the flame was a photodiode with a filter specific for the emission of the sodium…

  18. Turbulent Flame Speeds and NOx Kinetics of HHC Fuels with Contaminants and High Dilution Levels

    Energy Technology Data Exchange (ETDEWEB)

    Peterson, Eric [Texas A & M Univ., College Station, TX (United States); Krejci, Michael [Texas A & M Univ., College Station, TX (United States); Mathieu, Olivier [Texas A & M Univ., College Station, TX (United States); Vissotski, Andrew [Texas A & M Univ., College Station, TX (United States); Ravi, Sankat [Texas A & M Univ., College Station, TX (United States); Plichta, Drew [Texas A & M Univ., College Station, TX (United States); Sikes, Travis [Texas A & M Univ., College Station, TX (United States); Levacque, Anthony [Texas A & M Univ., College Station, TX (United States); Camou, Alejandro [Texas A & M Univ., College Station, TX (United States); Aul, Christopher [Texas A & M Univ., College Station, TX (United States)


    This final report documents the technical results of the 3-year project entitled, “Turbulent Flame Speeds and NOx Kinetics of HHC Fuels with Contaminants and High Dilution Levels,” funded under the NETL of DOE. The research was conducted under six main tasks: 1) program management and planning; 2) turbulent flame speed measurements of syngas mixtures; 3) laminar flame speed measurements with diluents; 4) NOx mechanism validation experiments; 5) fundamental NOx kinetics; and 6) the effect of impurities on NOx kinetics. Experiments were performed using primary constant-volume vessels for laminar and turbulent flame speeds and shock tubes for ignition delay times and species concentrations. In addition to the existing shock- tube and flame speed facilities, a new capability in measuring turbulent flame speeds was developed under this grant. Other highlights include an improved NOx kinetics mechanism; a database on syngas blends for real fuel mixtures with and without impurities; an improved hydrogen sulfide mechanism; an improved ammonia kintics mechanism; laminar flame speed data at high pressures with water addition; and the development of an inexpensive absorption spectroscopy diagnostic for shock-tube measurements of OH time histories. The Project Results for this work can be divided into 13 major sections, which form the basis of this report. These 13 topics are divided into the five areas: 1) laminar flame speeds; 2) Nitrogen Oxide and Ammonia chemical kinetics; 3) syngas impurities chemical kinetics; 4) turbulent flame speeds; and 5) OH absorption measurements for chemical kinetics.

  19. EPDM-g-MAH对PP膨胀阻燃材料性能的影响%Effect of maleic anhydride grafted EPDM on properties of intumescent flame retardant PP materials

    Institute of Scientific and Technical Information of China (English)

    闫怀文; 危加丽; 尹波; 杨鸣波


    采用氮磷膨胀型阻燃剂制备了无卤阻燃聚丙烯(PP)材料,研究了马来酸酐(MAH)接枝三元乙丙橡胶(EPDM)(EPDM-g-MAH)对PP无卤阻燃材料性能的影响.结果表明:加入EPDM-g-MAH可提高阻燃剂和PP基体间的界面作用,降低试样在燃烧过程中的熔融滴落现象,且加入EPDM-g-MAH提高了阻燃PP的力学性能.此外,加入EPDM-g-MAH可提高PP无卤阻燃材料在高温(600~800℃)下的炭层热稳定性以及材料的最大热分解速率,但会降低材料的最大热分解温度.因此,少量的EPDM-g-MAH可以提高PP无卤阻燃材料的极限氧指数(LOI),但当w(EPDM-g-MAH)超过10%时,PP无卤阻燃材料的LOI下降,阻燃性能降低.%The authors prepared halogen-free flame retardant polypropylene (PP) by introducing intumescent flame retardant made from nitrogen phosphorus compound, and studied the effect of content of maleic anhydride grafted ethylene propylene diene monomer(EPDM-g-MAH) on properties of the PP materials. The results show that adding EPDM-g-MAH can enhance interfacial interaction between PP matrix and the flame retardant, reduce melt dripping of the specimens during combustion process and improve mechanical properties of the PP materials. The addition of EPDM-g-MAH can raise thermal stability of the carbon layer at high temperature (600-800 ℃) and the maximum thermal decomposition rate but lowers the maximum thermal decomposition temperature of the PP materials. As a result, adding a small quantity of EPDM-g-MAH can make the limited oxygen index (LOF) of the PP materials augment However, the LOI decreases and the flame retardancy of the PP material declines when the mass content of EPDM-g-MAH exceeds 10%.

  20. Flame Synthesis of Single- and Multi-Walled Carbon Nanotubes and Nanofibers (United States)

    VanderWal, R. L.; Ticich, Thomas M.


    Metal-catalyzed carbon nanotubes are highly sought for a diverse range of applications that include nanoelectronics, battery electrode material, catalysis, hydrogen storage media and reinforcing agents in polymer composites. These latter applications will require vast quantities of nanotubes at competitive prices to be economically feasible. Moreover, reinforcing applications may not require ultrahigh purity nanotubes. Indeed, functionalization of nanotubes to facilitate interfacial bonding within composites will naturally introduce defects into the tube walls, lessening their tensile strength. Current methods of aerosol synthesis of carbon nanotubes include laser ablation of composite targets of carbon and catalyst metal within high temperature furnaces and decomposition of a organometallics in hydrocarbons mixtures within a tube furnace. Common to each approach is the generation of particles in the presence of the reactive hydrocarbon species at elevated temperatures. In the laser-ablation approach, the situation is even more dynamic in that particles and nanotubes are borne during the transient cooling phase of the laser-induced plasma for which the temperature far exceeds that of the surrounding hot gases within the furnace process tube. A shared limitation is that more efficient methods of nanoparticle synthesis are not readily incorporated into these approaches. In contrast, combustion can quite naturally create nanomaterials such as carbon black. Flame synthesis is well known for its commercial scalability and energy efficiency. However, flames do present a complex chemical environment with steep gradients in temperature and species concentrations. Moreover, reaction times are limited within buoyant driven flows to tens of milliseconds. Therein microgravity can greatly lessen temperature and spatial gradients while allowing independent control of flame residence times. In preparation for defining the microgravity experiments, the work presented here focuses

  1. Low tube voltage and low contrast material volume cerebral CT angiography

    Energy Technology Data Exchange (ETDEWEB)

    Luo, Song [Medical School of Nanjing University, Department of Medical Imaging, Jinling Hospital, Nanjing, Jiangsu (China); Xuzhou Medical College, School of Medical Imaging, Xuzhou, Jiangsu (China); Zhang, Long Jiang; Lu, Guang Ming [Medical School of Nanjing University, Department of Medical Imaging, Jinling Hospital, Nanjing, Jiangsu (China); Meinel, Felix G.; McQuiston, Andrew D. [Medical University of South Carolina, Department of Radiology and Radiological Science, Charleston, SC (United States); Zhou, Chang Sheng; Qi, Li [Medical School of Nanjing University, Department of Medical Imaging, Jinling Hospital, Nanjing, Jiangsu (China); Schoepf, U.J. [Medical School of Nanjing University, Department of Medical Imaging, Jinling Hospital, Nanjing, Jiangsu (China); Medical University of South Carolina, Department of Radiology and Radiological Science, Charleston, SC (United States)


    To evaluate the image quality, radiation dose and diagnostic accuracy of low kVp and low contrast material volume cerebral CT angiography (CTA) in intracranial aneurysm detection. One hundred twenty patients were randomly divided into three groups (n = 40 for each): Group A, 70 ml iodinated contrast agent/120 kVp; group B, 30 ml/100 kVp; group C, 30 ml/80 kVp. The CT numbers, noise, signal-to-noise ratio (SNR) and contrast-to-noise ratio (CNR) were measured in the internal carotid artery (ICA) and middle cerebral artery (MCA). Subjective image quality was evaluated. For patients undergoing DSA, diagnostic accuracy of CTA was calculated with DSA as reference standard and compared. CT numbers of ICA and MCA were higher in groups B and C than in group A (P < 0.01). SNR and CNR in groups A and B were higher than in group C (both P < 0.05). There was no difference in subjective image quality among the three groups (P = 0.939). Diagnostic accuracy for aneurysm detection among these groups had no statistical difference (P = 1.00). Compared with group A, the radiation dose of groups B and C was decreased by 45 % and 74 %. Cerebral CTA at 100 or 80 kVp using 30 ml contrast agent can obtain diagnostic image quality with a low radiation dose while maintaining the same diagnostic accuracy for aneurysm detection. (orig.)

  2. Hi-tech Flame

    Institute of Scientific and Technical Information of China (English)


    Modern science plays a crucial role in lighting the Olympic flame on the world’s highest mountain when the world saw live telecasts of the Olympic flame burning onthe top of Mount Qomolangma(Mount Everest) at 9:17 on the morning of May 8, few realized the years of work and high level of technology that had

  3. Product engineering by high-temperature flame synthesis

    DEFF Research Database (Denmark)

    Johannessen, Tue; Johansen, Johnny; Mosleh, Majid;

    High-temperature flame processes can be applied as a tool for chemical product engineering. The general principle behind flame synthesis is the decomposition/oxidation of evaporated metal-precursors in a flame, thereby forming metal oxide monomers which nucleate, aggregate, and - to some extent...... product gas can be applied directly in additional product engineering concepts. A brief overview of on-going product developments and product engineering projects is outlined below. These projects, which are all founded on flame synthesis of nano-structured materials, include: • Preparation of catalyzed...

  4. Unsteady Flame Embedding

    KAUST Repository

    El-Asrag, Hossam A.


    Direct simulation of all the length and time scales relevant to practical combustion processes is computationally prohibitive. When combustion processes are driven by reaction and transport phenomena occurring at the unresolved scales of a numerical simulation, one must introduce a dynamic subgrid model that accounts for the multiscale nature of the problem using information available on a resolvable grid. Here, we discuss a model that captures unsteady flow-flame interactions- including extinction, re-ignition, and history effects-via embedded simulations at the subgrid level. The model efficiently accounts for subgrid flame structure and incorporates detailed chemistry and transport, allowing more accurate prediction of the stretch effect and the heat release. In this chapter we first review the work done in the past thirty years to develop the flame embedding concept. Next we present a formulation for the same concept that is compatible with Large Eddy Simulation in the flamelet regimes. The unsteady flame embedding approach (UFE) treats the flame as an ensemble of locally one-dimensional flames, similar to the flamelet approach. However, a set of elemental one-dimensional flames is used to describe the turbulent flame structure directly at the subgrid level. The calculations employ a one-dimensional unsteady flame model that incorporates unsteady strain rate, curvature, and mixture boundary conditions imposed by the resolved scales. The model is used for closure of the subgrid terms in the context of large eddy simulation. Direct numerical simulation (DNS) data from a flame-vortex interaction problem is used for comparison. © Springer Science+Business Media B.V. 2011.

  5. Phosphorus-based Flame Retardancy Mechanisms—Old Hat or a Starting Point for Future Development?

    Directory of Open Access Journals (Sweden)

    Bernhard Schartel


    Full Text Available Different kinds of additive and reactive flame retardants containing phosphorus are increasingly successful as halogen-free alternatives for various polymeric materials and applications. Phosphorus can act in the condensed phase by enhancing charring, yielding intumescence, or through inorganic glass formation; and in the gas phase through flame inhibition. Occurrence and efficiency depend, not only on the flame retardant itself, but also on its interaction with pyrolysing polymeric material and additives. Flame retardancy is sensitive to modification of the flame retardant, the use of synergists/adjuvants, and changes to the polymeric material. A detailed understanding facilitates the launch of tailored and targeted development.

  6. Development of Radiation Crosslinked,Heat Resistant and Flame Resistant Polyolefin Heat Shrinkable Material%辐射交联150℃阻燃聚烯烃热收缩材料的研制

    Institute of Scientific and Technical Information of China (English)



    The composition,preparing technology and properties of radiation crosslinked,heat resistant and flame resistant polyolefin heat shrinkable material were studied,and the polyolefin heat shrinkable material with heat resistance up to 150℃,the OI of which was 30,was prepared.The prepared material could be used at 150℃ for a long time,and was characterized by high temperature resistance,good mechanical and elecrical properties and flame resistance,and could be widely applied to aircrafts,architecture,atuomobiles,military wehicle and cable insulation.%本文介绍了一种辐射交联150℃阻燃聚烯烃热收缩材料的配方研究,制备工艺及性能,通过确定聚烯烃热收缩材料制备工艺,挤出温度、辐照剂量等,制备出耐温达150℃,氧指数达30的热收缩材料,此材料可在150℃温度下长期使用,具有耐高温、机械、电性能优异、阻燃性能好,可广泛使用在航天、航空、汽车、军工等线缆的绝缘保护。

  7. Numerical method and model for calculating thermal storage time for an annular tube with phase change material

    Institute of Scientific and Technical Information of China (English)

    刘泛函; 徐建新; 王辉涛; 王华


    For calculating the thermal storage time tor an annular tube with phase change material(PCM),a novel method is proposed.The method is suitable for either low-temperature PCM or high-temperature PCM whose initial temperature is near the melting point.The deviation fit is smaller than 8%when the time is below 2×10~4 s.Comparison between the predictions and the reported experimental data of thermal storage time at same conditions is investigated and good agreements have been got.Based on this method,the performance of the thermal storage unit and the role of natural convection are also investigated.Results show a linear relation between the maximum amount of stored heat and thermal storage time,and their ratio increases with the height of the thermal storage unit.As the thickness of the cavity increases,natural convection plays an increasingly important role in promoting the melting behavior of paraffin.When the thickness of the cavity is small,natural convection restrains the melting behavior of paraffin.

  8. An experimental investigation of shell and tube latent heat storage for solar dryer using paraffin wax as heat storage material

    Directory of Open Access Journals (Sweden)

    Ashish Agarwal


    Full Text Available In the presented study the shell and tube type latent heat storage (LHS has been designed for solar dryer and paraffin wax is used as heat storage material. In the first part of the study, the thermal and heat transfer characteristics of the latent heat storage system have been evaluated during charging and discharging process using air as heat transfer fluid (HTF. In the last section of the study the effectiveness of the use of an LHS for drying of food product and also on the drying kinetics of a food product has been determined. A series of experiments were conducted to study the effects of flow rate and temperature of HTF on the charging and discharging process of LHS. The temperature distribution along the radial and longitudinal directions was obtained at different time during charging process to analyze the heat transfer phenomenon in the LHS. Thermal performance of the system is evaluated in terms of cumulative energy charged and discharged, during the charging and discharging process of LHS, respectively. Experimental results show that the LHS is suitable to supply the hot air for drying of food product during non-sunshine hours or when the intensity of solar energy is very low. Temperature gain of air in the range of 17 °C to 5 °C for approximately 10 hrs duration was achieved during discharging of LHS.

  9. 46 CFR 151.03-25 - Flame screen. (United States)


    ... 46 Shipping 5 2010-10-01 2010-10-01 false Flame screen. 151.03-25 Section 151.03-25 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) CERTAIN BULK DANGEROUS CARGOES BARGES CARRYING BULK LIQUID HAZARDOUS MATERIAL CARGOES Definitions § 151.03-25 Flame screen. A fitted single screen...

  10. 49 CFR 195.438 - Smoking or open flames. (United States)


    ... 49 Transportation 3 2010-10-01 2010-10-01 false Smoking or open flames. 195.438 Section 195.438 Transportation Other Regulations Relating to Transportation (Continued) PIPELINE AND HAZARDOUS MATERIALS SAFETY... PIPELINE Operation and Maintenance § 195.438 Smoking or open flames. Each operator shall prohibit...

  11. 49 CFR 176.325 - Smoking or open flame and posting of warning signs. (United States)


    ... 49 Transportation 2 2010-10-01 2010-10-01 false Smoking or open flame and posting of warning signs... Smoking or open flame and posting of warning signs. (a) Smoking or the use of open flame is prohibited in... material. (b) A sign carrying the legend: FLAMMABLE VAPORS KEEP LIGHTS AND FIRE AWAY NO SMOKING must...

  12. 49 CFR 176.220 - Smoking or open flame and posting of warning signs. (United States)


    ... 49 Transportation 2 2010-10-01 2010-10-01 false Smoking or open flame and posting of warning signs... CARRIAGE BY VESSEL Detailed Requirements for Class 2 (Compressed Gas) Materials § 176.220 Smoking or open flame and posting of warning signs. (a) Smoking or the use of open flame is prohibited in any hold...

  13. Discussion on Selection of Crude Distillation Unit Hot Overhead Condenser Tube Bundle Material%浅谈常顶热交换器管束选材

    Institute of Scientific and Technical Information of China (English)

    刘洋; 高威


    炼油企业常减压装置中的常顶热交换器管束腐独问题一直比较突出,对常减压装置安稳长周期运行构成了严重威胁。通过查找近年来多套常减压装置常顶热交换器管束选材及使用情况,总结归纳了常用的3种常顶热交换器管束材质09Cr2AlMoRE、双相钢2205、钛在对应使用工况下的注意事项,经过对多套常减压装置常顶热交换器管束腐蚀情况的分析,列出了每种常减压装置常顶热交换器管束材质的腐蚀机理以及改进措施,对今后常减压装置常顶热交换器管束选材具有一定的参考意义。%The corrosion problem of crude distillation unit (CDU ) hot overhead condenser tube has been more prominent for many years ,this problem is a serious threat for long‐term operation constitutes of CDU .For finding CDU hot overhead condenser tubes material selection in several sets of CDU ,and using of CDU hot overhead condenser tube in each refinery after production op‐erations ,this article summarizes the notes of CDU hot overhead condenser tubes commonly used three types of material (09Cr2AlMoRE ,dual‐phase steel 2205 ,TA) under the corresponding use condition .By analysis of the corrosion of CDU hot overhead condenser tube in several sets of CDU ,CDU hot overhead condenser tubes corrosion mechanism and improvement measures of each type material were list in this text which has a certain reference significance in future for the CDU hot overhead condenser tube material selection in CDU .

  14. 无卤阻燃聚合物抑烟的研究进展%Research progress on smoke suppression of halogen free flame retardant polymer materials

    Institute of Scientific and Technical Information of China (English)

    贺春江; 张国文; 潘会鹏; 张宪清; 党佳; 陈传志


    综述了近10年来国内外关于无卤阻燃聚合物抑烟的研究进展。主要阐述了聚烯烃、环氧树脂、乙烯-乙酸乙烯共聚物、聚酯、聚氨酯及橡胶等聚合物在抑烟研究方面的最新进展。着重论述了膨胀阻燃剂、金属氢氧化物阻燃剂、实验室合成的新型抑烟剂、膨胀阻燃剂与金属氢氧化物协效阻燃体系,蒙脱土与膨胀阻燃剂协效阻燃体系,金属氧化物与膨胀阻燃剂协效阻燃体系等各组分用量及配比对聚合物烟密度的影响规律,并对它们的抑烟机理进行了讨论。结合目前研究中存在的问题,对无卤阻燃聚合物的抑烟研究方向进行了展望。%This paper reviews the research progress in the last10years on smoke suppression of halogen free flame retardant polymer which include polyolefin, epoxy resin, ethylene-vinyl acetate copolymer, polyester, polyurethane and rubber. The impact of component and ratio of the intumescent flame retardant, metal hydroxide, newly synthesized smoke suppression agents, synergistic system of intumescent flame retardant and metal hydroxide, synergistic system of montmorillonite and intumescent flame retardant, and synergistic system of metal oxide and intumescent flame retardant on the smoke density of these polymer systems are discussed along with the mechanism of smoke suppression. The future development of this technique is forecasted by reference to the issues within.

  15. photomultiplier tube

    CERN Multimedia

    photomultiplier tubes. A device to convert light into an electric signal (the name is often abbreviated to PM). Photomultipliers are used in all detectors based on scintillating material (i.e. based on large numbers of fibres which produce scintillation light at the passage of a charged particle). A photomultiplier consists of 3 main parts: firstly, a photocathode where photons are converted into electrons by the photoelectric effect; secondly, a multiplier chain consisting of a serie of dynodes which multiply the number of electron; finally, an anode, which collects the resulting current.

  16. photomultiplier tubes

    CERN Multimedia

    photomultiplier tubes. A device to convert light into an electric signal (the name is often abbreviated to PM). Photomultipliers are used in all detectors based on scintillating material (i.e. based on large numbers of fibres which produce scintillation light at the passage of a charged particle). A photomultiplier consists of 3 main parts: firstly, a photocathode where photons are converted into electrons by the photoelectric effect; secondly, a multiplier chain consisting of a serie of dynodes which multiply the number of electron; finally, an anode, which collects the resulting current.

  17. Sudden acceleration of flames in open channels driven by hydraulic resistance

    CERN Document Server

    Yanez, J; Bykov, V


    Hydrogen-air deflagrations with venting at the end of obstructed tubes are studied experimentally and numerically. A shockless transition to the so-called chocked regime of the flame propagation is reported. Mixtures with 13% vol. of hydrogen were ignited from the open end of the tube at the interface between fuel and the ambient air. Three venting ratios were selected, closed, 40% and 100%. In all cases the flame initially propagates without acceleration at a velocity close to the laminar flame speed. The flame configuration excludes most of conventionally acknowledged phenomena of the DDT, namely, volumetric explosions, igniting shock and shock waves interactions. However, after an induction period, of the order of 1 sec, the flame accelerates more than 100 times, within a period of 3-30 ms, until the steady-state choked regime is established. The mechanism of such rapid acceleration is investigated both numerically and analytically. A one dimensional reduced description was suggested and analyzed to model ...

  18. Influence of obstacle-produced turbulence on development of premixed flames

    Institute of Scientific and Technical Information of China (English)

    YU; Lixin(余立新); SUN; Wenchao(孙文超); WU; Chengkang(吴承康)


    An investigation into influence of obstructions on premixed flame propagation has been carried out in a semi-open tube.It is found that there exists flame acceleration and rising overpressure along the path of flame due to obstacles.According to the magnitude of flame speeds,the propagation of flame in the tube can be classified into three regimes:the quenching,the choking and the detonation regimes.In premixed flames near the flammability limits,the flame is observed first to accelerate and then to quench itself after propagating past a certain number of obstacles.In the choking regime,the maximum flame speeds are somewhat below the combustion product sound speeds,and insensitive to the blockage ratio.In the more sensitive mixtures,the transition to detonation (DDT) occurs when the equivalence ratio increases.The transition is not observed for the less sensitive mixtures.The dependence of overpressure on blockage ratio is not monotonous.Furthermore,a numerical study of flame acceleration and overpressure with the unsteady compressible flow model is performed,and the agreement between the simulation and measurements is good.``

  19. Parametric Erosion Investigation: Propellant Adiabatic Flame Temperature

    Directory of Open Access Journals (Sweden)

    P. J. Conroy


    Full Text Available The influence of quasi-independent parameters and their potential influence on erosion in guns have been investigated. Specifically, the effects of flame temperature and the effect of assuming that the Lewis number (ratio of mass-to-heat transport to the surface, Le = 1, has been examined. The adiabatic flame temperature for a propellant was reduced by the addition of a diluent from a high temperature of 3843 K (similar to that of M9 down to 3004 K, which is near the value for M30A1 propellant. Mass fractions of critical species at the surface with and without the assumption of Le = 1 are presented, demonstrating that certain species preferentially reach the surface providing varied conditions for the surface reactions. The results for gun tube bore surface regression qualitatively agree with previous studies and with current experimental data.

  20. Igniting the Paralympic Flame

    Institute of Scientific and Technical Information of China (English)


    Deaf-mute Jiang Xintian lights a small cauldron in the hands of wheelchairbound fencer Jin Jing at the Paralympic Flame Lighting Ceremony in Beijing’s symbolic Temple of Heaven on August 28. For nine days until September 6, when the 13th Paralympics opens in Beijing, a total of 850 torchbearers would relay the Paralympic flame along two routes through 11 Chinese provinces,

  1. Stress and integrity analysis of steam superheater tubes of a high pressure boiler

    Directory of Open Access Journals (Sweden)

    Neves Daniel Leite Cypriano


    Full Text Available Sources that can lead to deterioration of steam superheater tubes of a high pressure boiler were studied by a stress analysis, focused on internal pressure and temperature experienced by the material at real operating conditions. Loss of flame control, internal deposits and unexpected peak charge are factors that generate loads above the design limit of tube materials, which can be subjected to strain, buckling, cracks and finally rupture in service. To evaluate integrity and dependability of these components, the microstructure of selected samples along the superheater was studied by optical microscopy. Associated with this analysis, dimensional inspection, nondestructive testing, hardness measurement and deposit examination were made to determine the resultant material condition after twenty three years of operation.

  2. Selective molecularly imprinted polymer combined with restricted access material for in-tube SPME/UHPLC-MS/MS of parabens in breast milk samples

    Energy Technology Data Exchange (ETDEWEB)

    Souza, Israel D.; Melo, Lidervan P. [Departamento de Química, Faculdade de Filosofia Ciências e Letras de Ribeirão Preto, Universidade de São Paulo, Ribeirão Preto, SP (Brazil); Jardim, Isabel C.S.F. [Instituto de Química, Universidade Estadual de Campinas, Campinas, SP (Brazil); Monteiro, Juliana C.S.; Nakano, Ana Marcia S. [Escola de Enfermagem de Ribeirão Preto, Universidade de São Paulo, Ribeirão Preto, SP (Brazil); Queiroz, Maria Eugênia C., E-mail: [Departamento de Química, Faculdade de Filosofia Ciências e Letras de Ribeirão Preto, Universidade de São Paulo, Ribeirão Preto, SP (Brazil)


    A new molecularly imprinted polymer modified with restricted access material (a hydrophilic external layer), (MIP-RAM) was synthesized via polymerization in situ in an open fused silica capillary. This stationary phase was used as sorbent for in-tube solid phase microextraction (in-tube SPME) to determine parabens in breast milk samples by ultra-high-performance liquid chromatography-tandem mass spectrometry (UHPLC-MS/MS). Scanning electron micrographs (SEM) illustrate MIP surface modification after glycerol dimethacrylate (hydrophilic monomer) incorporation. The interaction between parabens and MIP-RAM was investigated by Fourier-transform infrared (FTIR) spectroscopy. The Scatchard plot for MIP-RAM presented two linear parts with different slopes, illustrating binding sites with high- and low-affinity. Endogenous compounds exclusion from the MIP-RAM capillary was demonstrated by in-tube SPME/LC-UV assays carried out with blank milk samples. The in-tube SPME/UHPLC-MS/MS method presented linear range from 10 ng mL{sup −1} (LLOQ) to 400 ng mL{sup −1} with coefficients of determination higher than 0.99, inter-assay precision with coefficient of variation (CV) values ranging from 2 to 15%, and inter-assay accuracy with relative standard deviation (RSD) values ranging from −1% to 19%. Analytical validation parameters attested that in-tube SPME/UHPLC-MS/MS is an appropriate method to determine parabens in human milk samples to assess human exposure to these compounds. Analysis of breast milk samples from lactating women demonstrated that the proposed method is effective. - Highlights: • Molecularly imprinted polymer modified with a hydrophilic external layer (RAM-MIP) was synthesized in a silica capillary. • RAM-MIP capillary, used as sorbent for in-tube SPME, established specific interaction with parabens present in milk samples. • The matrix components that interacted only with the hydrophilic external layer (non-adsorptive network) were excluded.

  3. Light Flame Retardant Insulation Foam Materials Preparation Modified with Lignin and Old Polyurethane%木质素废旧聚氨酯制备轻型阻燃保温材料试验

    Institute of Scientific and Technical Information of China (English)

    庞久寅; 姜贵全; 罗来朋; 陈浩


    According to the ratio of phenolic resin,flame retardant agent,foaming agent,emulsifier,alkali lignin, lignin liquefaction of waste polyurethane, the waste polyurethane was prepared. The results show that:with the increase of curing agent, the shortening of curing time, the increase of apparent density, the enhancement of compressive strength, foam quality is better;adding flame retardant aluminum hypophosphite and diethyl aluminum hypophosphite can significantly improve the retardancy of phenolic resin;the effect are the best adding 5g aluminum phosphate and two ethyl aluminum hypophosphite. The light flame retardant insulation material has advantages of phenolic resin foam, improves the flame retardancy due to the addition of lignin, and using polyurethane as additive can greatly reduce the cost of production, protect environment, improve the utilization rate of resources.%按配比加入酚醛树脂、阻燃剂、发泡剂、乳化剂、碱木质素、液化废旧聚氨酯,制成木质素废旧聚氨酯。试验结果表明:随着固化剂的增加,固化时间缩短,表观密度增加,抗压强度增强,泡沫质量较好;加入次磷酸铝和二乙基次磷酸铝能明显改善酚醛树脂的阻燃性,加入5g次磷酸铝和二乙基次磷酸铝时效果最好。这种轻型阻燃保温材料具有酚醛树脂泡沫的优点,同时由于添加了木质素提高了阻燃性。采用废旧聚氨酯作为添加成分,可以大大减少生产成本,保护环境,提高了资源的利用率。

  4. Brominated flame retardants and endocrine disruption

    NARCIS (Netherlands)

    Vos, J.G.; Becher, G.; Berg, van den M.; Boer, de J.; Leonards, P.E.G.


    From an environmental point of view, an increasing important group of organohalogen compounds are the brominated flame retardants (BFRs), which are widely used in polymers and textiles and applied in construction materials, furniture, and electronic equipment. BFRs with the highest production volume

  5. Effect of dosage of expandable graphite, dimethyl methylphosphonate, triethanolamine, and isocyanate on fluidity, mechanical, and flame retardant properties of polyurethane materials in coal reinforcement

    Institute of Scientific and Technical Information of China (English)

    Hu Xiangming; Wang Deming; Cheng Weimin


    In this study, orthogonal experiments were conducted to investigate the influence of expandable graphite (EG), dimethyl methylphosphonate (DMMP), triethanolamine (TEA), and isocyanate content on the com-pressive and bonding strengths, oxygen index, and fluidity of rigid polyurethane foam (RPUF). The results revealed that EG significantly increased the oxygen index of RPUF, enlarged the diameter of foam cells, and decreased the cell-closed content in foam;thus, leading to a pressure drop in RPUF. However, exces-sive EG was capable of reducing the fluidity of polyurethane slurry. TEA exhibited significant influence on the compressive strength of RPUF, which dropped initially, and then increased. DMMP had a remarkable effect on the flame retardant property and compressive strength of RPUF. Compressive strength of RPUF initially displayed an increase followed by a decrease with increasing dosage of DMMP, and achieved the maximum value at DMMP dosage of 4%. DMMP could effectively reduce the diameter of RPUF cells lead-ing to an increase in the percentage of close area in foam. DMMP displayed the flame-retardation effects mainly in the gas phase leading to a significant enhancement in the oxygen index of RPUF. Moreover, the compressive strength and bonding strength of RPUF decrease significantly with the increase of isocyanate content due to the increased blowing efficiency by the CO2. The oxygen index and flowing length of foam increased with the increase in isocyanate dosage.

  6. Cu/Al管气体火焰钎焊接头特征及热力学分析%Characteristics and thermodynamics analysis of oxyacetylene flame brazing joint of Cu/Al tubes

    Institute of Scientific and Technical Information of China (English)

    罗键; 赵国际; 王向杰; 孙玉


    Entropy changes in chemical reaction of Cu/Al intermetallic compounds formation in Cu/Al oxyacetylene flame brazing are calculated, and the tendency of Cu/Al intermetallic compounds form and transform to CuAl2 is analyzed with the method of chemical thermodynamics. The microstructure and characteristics of elements distribution and diffusion of the Cu/Al oxyacetylene flame brazing joint are analyzed by XRD, SEM and EDS. Results show that, under the condition of Cu/Al oxyacetylene flame brazing, the CuAl2 intermetallic compounds formed by the direct reaction of Cu&Al atoms and the sustained reaction of Cu/Al intermetallic compounds with Al atoms. CuAl has relatively strong independent transformation trend. The results of thermodynamics analysis and calculation are consistent with the XRD of joint. Brazing joint can be divided into three feature regions: the a-Al and binary eutectic (α-Al+CuAl2) region is near Al side with the width of about 30 μm; the fine multiple eutectic structure is formed in brazing seam center near Al side with the width of about 150 μm; and the region near Cu substrate with the width of about 120 μm, where Cu diffuses largely and reacts richly with Al and massive CuAl2 is formed like corals.%通过计算Cu/Al管氧乙炔气体火焰钎焊条件下形成金属间化合物的各化学反应的熵变,对Cu/Al金属间化合物的形成及向CuAl2转化的趋势进行了化学热力学分析;结合XRD、SEM、EDS研究了Cu/Al管氧乙炔气体火焰钎焊接头组织与元素分布特征.结果表明,Cu/Al管氧乙炔气体火焰钎焊条件下,接头中脆性金属间化合物CuAl2由Cu、Al原子的直接结合和其他Cu/Al金属间化合物与Al原子的继续反应生成,其中CuAl自主转化趋势较强;热力学计算分析与接头XRD分析结果一致.钎焊接头可分为3个特征区域:靠近Al基体侧形成了宽度约30μm的α-Al与α-Al+CuAl2二元共晶区;钎缝中心偏Al基体一侧形成了宽度约150

  7. Field survey and laboratory tests on composite materials case of GRP (Glass Fiber Reinforced Polyester tubes for water suply

    Directory of Open Access Journals (Sweden)

    Radu Hariga


    Full Text Available In the Moldova land, were made two lines of water adduction, having 6000 m length and 40 m slope, or 1/150 slope. The water supply component tubes were disposed under the plant: The tubes are made of glass – reinforced thermosetting plastics (GRP. After about 180 days of operation, one of the lines showed severe deterioration of the quality pipe components. This paper deals with some laboratory tests in order to detect the failure cases of the pipelines components.

  8. Numerical solution of an edge flame boundary value problem (United States)

    Shields, Benjamin; Freund, Jonathan; Pantano, Carlos


    We study edge flames for modeling extinction, reignition, and flame lifting in turbulent non-premixed combustion. An adaptive resolution finite element method is developed for solving a strained laminar edge flame in the intrinsic moving frame of reference of a spatially evolving shear layer. The variable-density zero Mach Navier-Stokes equations are used to solve for both advancing and retreating edge flames. The eigenvalues of the system are determined simultaneously (implicitly) with the scalar fields using a Schur complement strategy. A homotopy transformation over density is used to transition from constant- to variable-density, and pseudo arc-length continuation is used for parametric tracing of solutions. Full details of the edge flames as a function of strain and Lewis numbers will be discussed. This material is based upon work supported [in part] by the Department of Energy, National Nuclear Security Administration, under Award Number DE-NA0002374.

  9. Selective molecularly imprinted polymer combined with restricted access material for in-tube SPME/UHPLC-MS/MS of parabens in breast milk samples. (United States)

    Souza, Israel D; Melo, Lidervan P; Jardim, Isabel C S F; Monteiro, Juliana C S; Nakano, Ana Marcia S; Queiroz, Maria Eugênia C


    A new molecularly imprinted polymer modified with restricted access material (a hydrophilic external layer), (MIP-RAM) was synthesized via polymerization in situ in an open fused silica capillary. This stationary phase was used as sorbent for in-tube solid phase microextraction (in-tube SPME) to determine parabens in breast milk samples by ultra-high-performance liquid chromatography-tandem mass spectrometry (UHPLC-MS/MS). Scanning electron micrographs (SEM) illustrate MIP surface modification after glycerol dimethacrylate (hydrophilic monomer) incorporation. The interaction between parabens and MIP-RAM was investigated by Fourier-transform infrared (FTIR) spectroscopy. The Scatchard plot for MIP-RAM presented two linear parts with different slopes, illustrating binding sites with high- and low-affinity. Endogenous compounds exclusion from the MIP-RAM capillary was demonstrated by in-tube SPME/LC-UV assays carried out with blank milk samples. The in-tube SPME/UHPLC-MS/MS method presented linear range from 10 ng mL(-1) (LLOQ) to 400 ng mL(-1) with coefficients of determination higher than 0.99, inter-assay precision with coefficient of variation (CV) values ranging from 2 to 15%, and inter-assay accuracy with relative standard deviation (RSD) values ranging from -1% to 19%. Analytical validation parameters attested that in-tube SPME/UHPLC-MS/MS is an appropriate method to determine parabens in human milk samples to assess human exposure to these compounds. Analysis of breast milk samples from lactating women demonstrated that the proposed method is effective.

  10. Flame retardancy of paulownia wood and its mechanism



    Paulownia wood (Pauloumia tomentosa) is a special kind of wood material in that it has especially excellent flame retardancy. Using this property, it has been commonly used to make clothing wardrobes for a long time in Japan. In this research, the flame retardancy of paulownia wood has been verified by heating experiments and cone calorimeter testing. The structure and tissue of the material have been analyzed by scanning electron microscope and other methods. Moreover, the mechanism of the f...

  11. Effect of hydrogen isotope content on tensile flow behavior of Zr-2.5Nb pressure tube material between 25 and 300 °C

    Energy Technology Data Exchange (ETDEWEB)

    Bind, A.K. [Mechanical Metallurgy Division, Bhabha Atomic Research Centre, Trombay, Mumbai, 400085 (India); Homi Bhabha National Institute, Anushaktinagar, Mumbai, 400094 (India); Sunil, S. [Mechanical Metallurgy Division, Bhabha Atomic Research Centre, Trombay, Mumbai, 400085 (India); Singh, R.N., E-mail: [Mechanical Metallurgy Division, Bhabha Atomic Research Centre, Trombay, Mumbai, 400085 (India); Homi Bhabha National Institute, Anushaktinagar, Mumbai, 400094 (India)


    Tensile properties of autoclaved Zr-2.5Nb pressure tube material containing hydrogen isotope between 5 and 200 wppm were evaluated between 25 and 300 °C using specimens with its axis oriented along longitudinal direction of the tube. Analysis of tensile test results showed that both YS and UTS of this alloy decreased linearly with increasing test temperature. The uniform and total plastic strain decreased marginally with increase in test temperature. At all test temperatures, before necking tensile properties were unaffected by hydrogen isotope concentration whereas hydrogen isotope had clear effect on post-necking tensile properties especially at 25 and 100 °C. Post-necking ductility showed a transition behavior at 25 and 100 °C and it was able to capture the effect of hydride embrittlement in this material. - Highlights: • Tensile properties of Zr-2.5Nb pressure tube alloy were evaluated. • Effect of deuterium content and test temperature were studied. • Pre-necking tensile properties appeared to unaffected by the deuterium content. • Post-necking tensile properties captured the effect of hydride embrittlement.

  12. 光质对火焰无核葡萄胚挽救及试管苗生长发育的影响%Effect of light quality on embryo rescue and test-tube plantlets growth and development of Flame Seedless

    Institute of Scientific and Technical Information of China (English)

    李玉玲; 王勇; 郭平峰; 伍国红; 骆强伟


    以火焰无核自交胚珠为试材,研究了红光、蓝光、白光及暗处理对胚发育、胚萌发及试管苗生长发育的影响。结果表明:3种光质处理对胚发育均有一定促进作用,但与对照未达到显著性水平。在胚萌发阶段,红光对胚萌发有明显的促进作用。在试管苗发育成苗阶段,以蓝光处理的试管苗最为矮壮,红光下葡萄胚挽救苗试管苗节间最长,发育最高,叶绿素含量最低;各处理试管苗继代后移栽成活率均可达到90%以上。%The open pollination ovules from flame Seedless were used to investigate the effect of diffierent light quality on the proportion of embryo development and germination ,and test-tube plantlets growth and development in vitro, including red light, blue light, white light and dark condition. The results showed that three lights had positive effect on embryo during ovule development, but did not significantly; Red light could promote obsively embryo germination; the plantlets were the most stocky under blue light. Red light was favorable to the longitudinal growth of the test-tube Plantlets, Chlorophyll content were the lowest. Each treatment plantlets transplant survival rate could reach 90%.

  13. Synthesis of Antistatic Composite Based on Reaction Flame Retarding Unsaturated Polyester Resin

    Institute of Scientific and Technical Information of China (English)

    WANG Shui-ping; GONG Wen-hua; ZENG Jia


    The synthesis of reaction flame retarding unsaturated polyester resin and the flame retarding mechanism are investigated. By taking the synthesis flame retarding unsaturated polyester resin as a base material,glass fibers as reinforced material, under the condition of adding graphite or carbon black respectively, the composites were manufactured. The flame retarding and antistatic properties are also studied. In the experiment, bromidebearing flame retarding resin decomposed under a high temperature. Compound HBr was set out and retarded or stopped the flame. High concentration of HBr gas wall was formed between gas and solid phrases, which decreased flame. The results show that antistatic property of carbon black is higher than that of graphite. Adding a threshed value of 1% carbon black into composite, the antistatic property is at its highest value.

  14. Aryl Polyphosphonates: Useful Halogen-Free Flame Retardants for Polymers

    Directory of Open Access Journals (Sweden)

    Li Chen


    Full Text Available Aryl polyphosphonates (ArPPN have been demonstrated to function in wide applications as flame retardants for different polymer materials, including thermosets, polycarbonate, polyesters and polyamides, particularly due to their satisfactory thermal stability compared to aliphatic flame retardants, and to their desirable flow behavior observed during the processing of polymeric materials. This paper provides a brief overview of the main developments in ArPPN and their derivatives for flame-retarding polymeric materials, primarily based on the authors’ research work and the literature published over the last two decades. The synthetic chemistry of these compounds is discussed along with their thermal stabilities and flame-retardant properties. The possible mechanisms of ArPPN and their derivatives containing hetero elements, which exhibit a synergistic effect with phosphorus, are also discussed.

  15. Effect of the sequence of tube rolling in a tube bundle of a shell and tube heat exchanger on the stress-deformed state of the tube sheet (United States)

    Tselishchev, M. F.; Plotnikov, P. N.; Brodov, Yu. M.


    Rolling the tube sheet of a heat exchanger with U-shaped tubes, as exemplified by the vapor cooler GP-24, was simulated. The simulation was performed using the finite element method with account of elas- tic-plastic properties of the tube and tube sheet materials. The simulation consisted of two stages; at the first stage, maximum and residual contact stress in the conjunction of a separate tube and the tube sheet was determined using the "equivalent sleeve" model; at the second stage, the obtained contact stress was applied to the hole surface in the tube sheet. Thus, different tube rolling sequences were simulated: from the center to the periphery of the tube sheet and from the periphery to the center along a spiral line. The studies showed that the tube rolling sequence noticeably influences the value of the tube sheet residual deflection for the same rolling parameters of separate tubes. Residual deflection of the tube sheet in different planes was determined. It was established that the smallest residual deflection corresponds to the tube rolling sequence from the periphery to the center of the tube sheet. The following dependences were obtained for different rolling sequences: maximum deformation of the tube sheet as a function of the number of rolled tubes, residual deformation of the tube sheet along its surface, and residual deflection of the tube sheet as a function of the rotation angle at the periphery. The preferred sequence of tube rolling for minimizing the tube sheet deformation is indicated.

  16. Large Scale Flame Spread Environmental Characterization Testing (United States)

    Clayman, Lauren K.; Olson, Sandra L.; Gokoghi, Suleyman A.; Brooker, John E.; Ferkul, Paul V.; Kacher, Henry F.


    Under the Advanced Exploration Systems (AES) Spacecraft Fire Safety Demonstration Project (SFSDP), as a risk mitigation activity in support of the development of a large-scale fire demonstration experiment in microgravity, flame-spread tests were conducted in normal gravity on thin, cellulose-based fuels in a sealed chamber. The primary objective of the tests was to measure pressure rise in a chamber as sample material, burning direction (upward/downward), total heat release, heat release rate, and heat loss mechanisms were varied between tests. A Design of Experiments (DOE) method was imposed to produce an array of tests from a fixed set of constraints and a coupled response model was developed. Supplementary tests were run without experimental design to additionally vary select parameters such as initial chamber pressure. The starting chamber pressure for each test was set below atmospheric to prevent chamber overpressure. Bottom ignition, or upward propagating burns, produced rapid acceleratory turbulent flame spread. Pressure rise in the chamber increases as the amount of fuel burned increases mainly because of the larger amount of heat generation and, to a much smaller extent, due to the increase in gaseous number of moles. Top ignition, or downward propagating burns, produced a steady flame spread with a very small flat flame across the burning edge. Steady-state pressure is achieved during downward flame spread as the pressure rises and plateaus. This indicates that the heat generation by the flame matches the heat loss to surroundings during the longer, slower downward burns. One heat loss mechanism included mounting a heat exchanger directly above the burning sample in the path of the plume to act as a heat sink and more efficiently dissipate the heat due to the combustion event. This proved an effective means for chamber overpressure mitigation for those tests producing the most total heat release and thusly was determined to be a feasible mitigation

  17. Flame Stretch Analysis in Diffusion Flames with Inert Gas

    Institute of Scientific and Technical Information of China (English)

    Ay Su; Ying-Chieh Liu


    Experimental investigations of impinging flame with fuel mixed with non-reaction gas were conducted.According to the observations of combustion test and temperature measurement, the non-reaction gas might dilute the local concentration of fuel in the diffusion process. The shape of the flame was symmetrical due to the flame stretch force. Results show that the conical flame might be de-structured by the addition of inert gas in pure methane fuel. The impinging flame became shorter and bluer as nitrogen was added to the fuel. The conditions of N2/CH4 equal to 1/2 and 1/1 show a wider plane in the YZ plane. The effect of inert gas overcomes the flame stretch and destroys the symmetrical column flame as well as the cold flow. Nitrogen addition also enhances the diffusion rate and combustion efficiency.

  18. Propagation Limits of High Pressure Cool Flames (United States)

    Ju, Yiguang


    The flame speeds and propagation limits of premixed cool flames at elevated pressures with radiative heat loss are numerically modelled using dimethyl ether mixtures. The primary focus is paid on the effects of pressure, mixture dilution, flame size, and heat loss on cool flame propagation. The results showed that cool flames exist on both fuel lean and fuel rich sides and thus dramatically extend the lean and rich flammability limits. There exist three different flame regimes, hot flame, cool flame, and double flame. A new flame flammability diagram including both cool flames and hot flames is obtained at elevated pressure. The results show that pressure significantly changes cool flame propagation. It is found that the increases of pressure affects the propagation speeds of lean and rich cool flames differently due to the negative temperature coefficient effect. On the lean side, the increase of pressure accelerates the cool flame chemistry and shifts the transition limit of cool flame to hot flame to lower equivalence ratio. At lower pressure, there is an extinction transition from hot flame to cool flame. However, there exists a critical pressure above which the cool flame to hot flame transition limit merges with the lean flammability limit of the hot flame, resulting in a direct transition from hot flame to cool flame. On the other hand, the increase of dilution reduces the heat release of hot flame and promotes cool flame formation. Moreover, it is shown that a smaller flame size and a higher heat loss also extend the cool flame transition limit and promote cool flame formation.

  19. Molybdenum Tube Characterization report

    Energy Technology Data Exchange (ETDEWEB)

    Beaux II, Miles Frank [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Usov, Igor Olegovich [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)


    Chemical vapor deposition (CVD) techniques have been utilized to produce free-standing molybdenum tubes with the end goal of nuclear fuel clad applications. In order to produce tubes with properties desirable for this application, deposition rates were lowered requiring long deposition durations on the order of 50 hours. Standard CVD methods as well as fluidized-bed CVD (FBCVD) methods were applied towards these objectives. Characterization of the tubes produced in this manner revealed material suitable for fuel clad applications, but lacking necessary uniformity across the length of the tubes. The production of freestanding Mo tubes that possess the desired properties across their entire length represents an engineering challenge that can be overcome in a next iteration of the deposition system.

  20. Tracheostomy tubes. (United States)

    Hess, Dean R; Altobelli, Neila P


    Tracheostomy tubes are used to administer positive-pressure ventilation, to provide a patent airway, and to provide access to the lower respiratory tract for airway clearance. They are available in a variety of sizes and styles from several manufacturers. The dimensions of tracheostomy tubes are given by their inner diameter, outer diameter, length, and curvature. Differences in dimensions between tubes with the same inner diameter from different manufacturers are not commonly appreciated but may have important clinical implications. Tracheostomy tubes can be cuffed or uncuffed and may be fenestrated. Some tracheostomy tubes are designed with an inner cannula. It is important for clinicians caring for patients with a tracheostomy tube to appreciate the nuances of various tracheostomy tube designs and to select a tube that appropriately fits the patient. The optimal frequency of changing a chronic tracheostomy tube is controversial. Specialized teams may be useful in managing patients with a tracheostomy. Speech can be facilitated with a speaking valve in patients with a tracheostomy tube who are breathing spontaneously. In mechanically ventilated patients with a tracheostomy, a talking tracheostomy tube, a deflated cuff technique with a speaking valve, or a deflated cuff technique without a speaking valve can be used to facilitate speech. Copyright © 2014 by Daedalus Enterprises.

  1. Different stages of flame acceleration from slow burning to Chapman-Jouguet deflagration. (United States)

    Valiev, Damir M; Bychkov, Vitaly; Akkerman, V'yacheslav; Eriksson, Lars-Erik


    Numerical simulations of spontaneous flame acceleration are performed within the problem of flame transition to detonation in two-dimensional channels. The acceleration is studied in the extremely wide range of flame front velocity changing by 3 orders of magnitude during the process. Flame accelerates from realistically small initial velocity (with Mach number about 10(-3)) to supersonic speed in the reference frame of the tube walls. It is shown that flame acceleration undergoes three distinctive stages: (1) initial exponential acceleration in the quasi-isobaric regime, (2) almost linear increase in the flame speed to supersonic values, and (3) saturation to a stationary high-speed deflagration velocity. The saturation velocity of deflagration may be correlated with the Chapman-Jouguet deflagration speed. The acceleration develops according to the Shelkin mechanism. Results on the exponential flame acceleration agree well with previous theoretical and numerical studies. The saturation velocity is in line with previous experimental results. Transition of flame acceleration regime from the exponential to the linear one, and then to the constant velocity, happens because of gas compression both ahead and behind the flame front.

  2. Method for producing a tube (United States)

    Peterson, Kenneth A.; Rohde, Steven B.; Pfeifer, Kent B.; Turner, Timothy S.


    A method is described for producing tubular substrates having parallel spaced concentric rings of electrical conductors that can be used as the drift tube of an Ion Mobility Spectrometer (IMS). The invention comprises providing electrodes on the inside of a tube that are electrically connected to the outside of the tube through conductors that extend between adjacent plies of substrate that are combined to form the tube. Tubular substrates are formed from flexible polymeric printed wiring board materials, ceramic materials and material compositions of glass and ceramic, commonly known as Low Temperature Co-Fired Ceramic (LTCC). The adjacent plies are sealed together around the electrode.

  3. Microstructure, Tensile Adhesion Strength and Thermal Shock Resistance of TBCs with Different Flame-Sprayed Bond Coat Materials Onto BMI Polyimide Matrix Composite (United States)

    Abedi, H. R.; Salehi, M.; Shafyei, A.


    In this study, thermal barrier coatings (TBCs) composed of different bond coats (Zn, Al, Cu-8Al and Cu-6Sn) with mullite top coats were flame-sprayed and air-plasma-sprayed, respectively, onto bismaleimide matrix composites. These polyimide matrix composites are of interest to replace PMR-15, due to concerns about the toxicity of the MDA monomer from which PMR-15 is made. The results showed that pores and cracks appeared at the bond coat/substrate interface for the Al-bonded TBC because of its high thermal conductivity and diffusivity resulting in transferring of high heat flux and temperature to the polymeric substrate during top coat deposition. The other TBC systems due to the lower conductivity and diffusivity of bonding layers could decrease the adverse thermal effect on the polymer substrate during top coat deposition and exhibited adhesive bond coat/substrate interfaces. The tensile adhesion test showed that the adhesion strength of the coatings to the substrate is inversely proportional to the level of residual stress in the coatings. However, the adhesion strength of Al bond-coated sample decreased strongly after mullite top coat deposition due to thermal damage at the bond coat/substrate interface. TBC system with the Cu-6Sn bond coat exhibited the best thermal shock resistance, while Al-bonded TBC showed the lowest. It was inferred that thermal mismatch stresses and oxidation of the bond coats were the main factors causing failure in the thermal shock test.

  4. Power vacuum tubes handbook

    CERN Document Server

    Whitaker, Jerry


    Providing examples of applications, Power Vacuum Tubes Handbook, Third Edition examines the underlying technology of each type of power vacuum tube device in common use today. The author presents basic principles, reports on new development efforts, and discusses implementation and maintenance considerations. Supporting mathematical equations and extensive technical illustrations and schematic diagrams help readers understand the material. Translate Principles into Specific Applications This one-stop reference is a hands-on guide for engineering personnel involved in the design, specification,

  5. Porous Flame-retarded Asphalt Pavement for Highway Tunnel

    Institute of Scientific and Technical Information of China (English)

    HU Shuguang; HUANG Shaolong; Ding Qingjun


    A new way to improve the tunnel fire protection by using flame-retarded porous asphalt pavement containing ATH powders was introduced. Based on the miniature burning test designed and conducted, the burning time and temperature of porous asphalt (PA) and flame-retarded porous asphalt (FRPA) were studied comparing with cement concrete pavement, dense-graded HMA and S MA. Results of burning test and pavement performance test indicate that FRPA is appropriate and suitable as the pavement material of highway tunnel.

  6. Corrosion behaviour of a stream generator tube material in simulated steam generator feedwater containing chlorides and sulphates

    Energy Technology Data Exchange (ETDEWEB)

    Bojinov, M.; Kinnunen, P.; Laitinen, T.; Maekelae, K.; Saario, T.; Sirkiae, P.; Yliniemi, K. [VTT Manufacturing Technology, Espoo (Finland); Buddas, T.; Halin, M.; Tompuri, K. [Fortum Power and Heat Oy, Loviisa Power Plant (Finland)


    The goal of the present work has been to assess the effect of relatively high concentrations of anionic impurities (Cl{sup -}, SO{sub 4}{sup 2-}) on the corrosion behaviour of Ti-stabilised stainless steel SG tubes in simulated steam generator feed-water. The main observations of this work can be summarised as follows: Sulphate ions seem to be more aggressive than chloride ions towards the primary passive film on 08X18H10T stainless steel. The results may indicate that it is more important to have a low concentration of sulphate ions than of chloride ions in secondary side water when the effects of chemical conditions on tube degradation are considered. The presence of chloride ions seems to weaken the detrimental effect of sulphate ions on the stability of oxide films growing on 08X18H10T stainless steel. No localised corrosion features of 08X18H10T stainless steel were detected in the voltammetric and impedance measurements in solutions containing up to 5000 ppb sulphates, chlorides or both of the anions. (authors)

  7. The thermal tube

    Energy Technology Data Exchange (ETDEWEB)

    Semena, M.G.


    A thermal tube is proposed which contains a layer of dielectric, capillary porous material located on the internal surface of the body. To increase the heat transmitting capability, the layer of capillary porous material is made in the form of a felting, formed by hollow fibers from a non-alkaline, borosilicate glass.

  8. Comparative flame and furnace synthesis of single-walled carbon nanotubes (United States)

    Vander Wal, Randall L.; Ticich, Thomas M.


    In this Letter, results are reported for flame synthesis of single-walled carbon nanotubes. A pyrolysis flame of CO/H 2 is established with introduction of the nanocatalyst precursor particles as an aerosol created by drying a nebulized solution of iron or iron colloid (in the form of ferrofluid). Results are compared to those produced by entraining the same catalyst aerosol into a tube furnace. Optimum flame gas flows and overall gas composition are reported and interpreted in terms of temperature and particle residence time.

  9. Flame Retardant Applications in Camping Tents and Potential Exposure. (United States)

    Keller, Alexander S; Raju, Nikhilesh P; Webster, Thomas F; Stapleton, Heather M


    Concern has mounted over health effects caused by exposure to flame retardant additives used in consumer products. Significant research efforts have focused particularly on exposure to polybrominated diphenyl ethers (PBDEs) used in furniture and electronic applications. However, little attention has focused on applications in textiles, particularly textiles meeting a flammability standard known as CPAI-84. In this study, we investigated flame retardant applications in camping tents that met CPAI-84 standards by analyzing 11 samples of tent fabrics for chemical flame retardant additives. Furthermore, we investigated potential exposure by collecting paired samples of tent wipes and hand wipes from 27 individuals after tent setup. Of the 11 fabric samples analyzed, 10 contained flame retardant additives, which included tris(1,3-dichloroisopropyl) phosphate (TDCPP), decabromodiphenyl ether (BDE-209), triphenyl phosphate, and tetrabromobisphenol-A. Flame retardant concentrations were discovered to be as high as 37.5 mg/g (3.8% by weight) in the tent fabric samples, and TDCPP and BDE-209 were the most frequently detected in these samples. We also observed a significant association between TDCPP levels in tent wipes and those in paired hand wipes, suggesting that human contact with the tent fabric material leads to the transfer of the flame retardant to the skin surface and human exposure. These results suggest that direct contact with flame retardant-treated textiles may be a source of exposure. Future studies will be needed to better characterize exposure, including via inhalation and dermal sorption from air.

  10. Diffusion air effects on the soot axial distribution concentration in a premixed acetylene/air flame

    Energy Technology Data Exchange (ETDEWEB)

    Fassani, Fabio Luis; Santos, Alex Alisson Bandeira; Goldstein Junior, Leonardo [Universidade Estadual de Campinas, SP (Brazil). Faculdade de Engenharia Mecanica. Dept. de Engenharia Termica e de Fluidos]. E-mails:;;; Ferrari, Carlos Alberto [Universidade Estadual de Campinas, SP (Brazil). Inst. de Fisica. Dept. de Eletronica Quantica]. E-mail:


    Soot particles are produced during the high temperature pyrolysis or combustion of hydrocarbons. The emission of soot from a combustor, or from a flame, is determined by the competition between soot formation and its oxidation. Several factors affect these processes, including the type of fuel, the air-to-fuel ratio, flame temperature, pressure, and flow pattern. In this paper, the influence of the induced air diffusion on the soot axial distribution concentration in a premixed acetylene/air flame was studied. The flame was generated in a vertical axis burner in which the fuel - oxidant mixture flow was surrounded by a nitrogen discharge coming from the annular region between the burner tube and an external concentric tube. The nitrogen flow provided a shield that protected the flame from the diffusion of external air, enabling its control. The burner was mounted on a step-motor driven, vertical translation table. The use of several air-to-fuel ratios made possible to establish the sooting characteristics of this flame, by measuring soot concentration along the flame height with a non-intrusive laser light absorption technique. (author)

  11. Supplementary examination of alternative materials in a model steam generator: Volume 3, tube characterization by metallography and transmission electron microscopy: Final report

    Energy Technology Data Exchange (ETDEWEB)

    Krupowicz, J.J.; Stubbins, J.F.; Mehler, M.


    The microstructural characteristics of current and candidate alloys for steam generator heat transfer tubing were determined utilizing a variety of techniques. Mill annealed heats of Alloys 690 and 800NG were examined as well as heats of Alloy 600 in the mill annealed, process stabilized, sensitized and thermally treated conditions. Characterization included optical microscopy, transmission electron microscopy and scanning transmission electron microscopy of these materials in their pre- and post-test conditions (i.e., archive and exposure for 11,328 hours to 621/degree/F primary temperature). The results were utilized to elicit comparisons of these materials to stress corrosion cracking resistance in sulfate faulted secondary environments. 83 figs., 8 tabs.

  12. A solid-phase microextraction fiber with carbon nanoparticles as sorbent material prepared by a simple flame-based preparation process. (United States)

    Sun, Min; Feng, Juanjuan; Qiu, Huamin; Fan, Lulu; Li, Leilei; Luo, Chuannan


    A novel carbon nanoparticles-coated solid-phase microextraction (SPME) fiber was prepared via a simple and low-cost flame-based preparation process, with stainless steel wire as support. Surface characteristic of the fiber was studied with scanning electron microscope. A nano-scaled brushy structure was observed. Coupled to gas chromatography (GC), the fiber was used to extract phthalate esters (PAEs) and polycyclic aromatic hydrocarbons (PAHs) in aqueous samples. Analytical performances of the proposed method were investigated under the optimum extraction conditions (extraction temperature, 40°C; content of KCl, 30% (w/v); extraction time, 50min for PAEs and 40min for PAHs) and compared with other reports for the same analytes. Calibration ranges were 0.06-500μgL(-1) for di-n-butyl phthalate (DBP), and 0.1-300μgL(-1) for di-cyclohexyl phthalate (DCHP) and di-(2-ethyl-hexyl) phthalate (DEHP). For the eight PAHs, good linearity was obtained ranging from 0.01 to 150μgL(-1). Limits of detection were 0.005μgL(-1) for three PAEs and 0.001-0.003μgL(-1) for eight PAHs. The fiber exhibited excellent stability. It can be used for 100 times with RSDs of extraction efficiency less than 22.4%. The as-established SPME-GC method was applied to determine PAEs in food-wrap and PAHs in cigarette ash and snow water, and satisfactory results were obtained. The carbon nanoparticles-coated SPME fiber was efficient for sampling of organic compounds from aqueous samples.

  13. Synergistic Effect of Nanosilica Aerogel with Phosphorus Flame Retardants on Improving Flame Retardancy and Leaching Resistance of Wood

    Directory of Open Access Journals (Sweden)

    Xiaodan Zhu


    Full Text Available Nanosilica (Nano-SiO2 sol fabricated by a sol-gel process was introduced into wood modification with phosphorus flame retardants to improve the flame retardancy and leaching resistance of wood. The obtained materials were characterized by scanning electron microscopy and energy dispersive spectrometer (SEM-EDS, thermogravimetric analysis (TGA, cone calorimetric (CONE, and infrared spectroscopy (FT-IR. The residual rate of flame retardants before and after leaching was determinated by a leaching resistance. The results showed that the phosphorus flame retardants and SiO2 sol could reside in the poplar wood and are widely distributed in the vessels, pits, wood timber, and the spaces between wood cells of poplar substrate. TGA and CONE results indicated that the introduction of nano-SiO2 aerogel with phosphorus flame retardants had a significantly synergistic effect on improving the flame retardancy and inhibiting the release of smoke and toxic gases. In addition, the leaching resistance test, combined with infrared analysis and EDS analysis, confirmed that the phosphorus flame retardants were able to be fixed by SiO2 aerogel in the wood.

  14. Flame Retardant Epoxy Resins (United States)

    Thompson, C. M.; Smith, J. G., Jr.; Connell, J. W.; Hergenrother, P. M.; Lyon, R. E.


    As part of a program to develop fire resistant exterior composite structures for future subsonic commercial aircraft, flame retardant epoxy resins are under investigation. Epoxies and their curing agents (aromatic diamines) containing phosphorus were synthesized and used to prepare epoxy formulations. Phosphorus was incorporated within the backbone of the epoxy resin and not used as an additive. The resulting cured epoxies were characterized by thermogravimetric analysis, propane torch test, elemental analysis and microscale combustion calorimetry. Several formulations showed excellent flame retardation with phosphorous contents as low as 1.5% by weight. The fracture toughness of plaques of several cured formulations was determined on single-edge notched bend specimens. The chemistry and properties of these new epoxy formulations are discussed.

  15. Thermal Insulation System for Large Flame Buckets (United States)

    Callens, E. Eugene, Jr.; Gamblin, Tonya Pleshette


    The objective of this study is to investigate the use of thermal protection coatings, single tiles, and layered insulation systems to protect the walls of the flame buckets used in the testing of the Space Shuttle Main Engine, while reducing the cost and maintenance of the system. The physical behavior is modeled by a plane wall boundary value problem with a convective frontface condition and a backface condition designed to provide higher heat rates through the material.

  16. Antimony: a flame fighter (United States)

    Wintzer, Niki E.; Guberman, David E.


    Antimony is a brittle, silvery-white semimetal that conducts heat poorly. The chemical compound antimony trioxide (Sb2O3) is widely used in plastics, rubbers, paints, and textiles, including industrial safety suits and some children’s clothing, to make them resistant to the spread of flames. Also, sodium antimonate (NaSbO3) is used during manufacturing of high-quality glass, which is found in cellular phones.

  17. Preparation and mechanical properties of composite flexible-veneer with flame-retardant for adornment material%装饰材料用阻燃柔性复合薄木的制备及力学性能

    Institute of Scientific and Technical Information of China (English)

    夏龙坤; 于志明; 张扬


    以厚度为0.35~0.40 mm的榉木为薄木基材、棉网格布为增强材料和PES(聚醚砜)型HMA(热熔胶)为胶粘剂,选用BL-环保阻燃剂制备装饰材料用阻燃柔性复合薄木;然后以拉伸强度、剥离强力和表观性能为衡量指标,以热压压力、热压温度、含水率和胶膜厚度为试验因素,采用正交试验法优选制备柔性复合薄木的最优方案.结果表明:以PES型HMA作为薄木/棉网格布复合用环保型胶粘剂,其不仅与BL-环保阻燃剂有很好的相容性,而且可避免脲醛树脂胶粘剂的甲醛释放等问题;增强型薄木与非增强型薄木相比,前者的横纹拉伸强度显著提高,并且前者不再表现为脆性特征;柔性复合薄木热压工艺条件的最优方案为热压压力0.7 MPa、热压温度125℃、含水率12%和胶膜厚度0.10 mm.%With beech with thickness of 0.35-0.40 mm as veneer for base material, cotton mesh cloth as reinforcing material and PES(polyether sulphone) type HMA(hot melt adhesive) as adhesive,a composite flexible-veneer with flame -retardant for adornment material was prepared by adding BL -environment -friendly flame retardant. Then,with tensile strength,peeling strength and apparent property as evaluation indices,with hot-pressing pressure,hot-pressing temperature,moisture content and film thickness as experiment factors,an optimal project of preparing composite flexible-veneer was preferred by orthogonal experiment. The results showed that with PES type HMA as an environment-friendly adhesive for veneer/cotton mesh cloth composite, the HMA had not only good compatibility with BL-environment-friendly flame retardant, but could avoid releasing formaldehyde in urea formaldehyde resin adhesive. Compared the enhanced veneer with the un-enhanced veneer,the transverse tensile strength of the former was notably increased,and the former didn't have the characteristic of brittleness any longer. The optimal project of hot-pressing process

  18. A Contribution to Turbulent Combustion: Premixed Flames and Material Surfaces Une contribution à la combustion turbulente : flammes prémélangées et surfaces des matériaux

    Directory of Open Access Journals (Sweden)

    Nicolleau F.


    Full Text Available The behavior of premixed flames has been examined by many authors. In fact the problem of combustion which develops in a turbulent medium depends on two scalings. One makes reference to the scales of the flame the other one is related to the turbulent field. Comparisons between these two scalings allow us to identified what sort of regime is expected. In this paper we first study the development of a material surface which may be identify with a flame front under rather severe conditions. An analytical approach is first used. Hereafter a numerical simulation will be introduced. The role of a fine grained turbulence is more active on the extension of the surface than large structures. To a large extent big eddies convey the surface without distorting it. The risks of extinction are generally predicted by making comparisons between the scales of the flame and the scales of the turbulent field starting from a direct simulation. Poinçot et al show that the smallest structures are not responsible for the extinction : intermediate structures are more efficient than the smallest ones. In a previous paper the role of these structures was examined : the distorting mechanism are acting in a cumulative way. The life time of the smallest structures is too short to have them playing a decive role in the extinction process. Intermediate sized structures are less active but they strain the flame during a longer period. This idea requires a detailed description of the turbulent field. That is made possible by using the ß model which accounts for the location of turbulent structures whose ranks in the whole sequence is termed n . The cumulative role of the velocity gradients is given as a function of n . The influence of the intermediate structure on the extinction process is thereby emphasized. Finally the ß model is also used to describe the domain of distributed combustion zones. Flames propagate in limited regions of space. These regions are disconnected

  19. Fabrication and characterization of iron pnictide wires and bulk materials through the powder-in-tube method

    Energy Technology Data Exchange (ETDEWEB)

    Ma Yanwei, E-mail: [Key Laboratory of Applied Superconductivity, Institute of Electrical Engineering, Chinese Academy of Sciences, P.O. Box 2703, Beijing 100190 (China); Gao Zhaoshun; Qi Yanpeng; Zhang Xianping; Wang Lei; Zhang Zhiyu; Wang Dongliang [Key Laboratory of Applied Superconductivity, Institute of Electrical Engineering, Chinese Academy of Sciences, P.O. Box 2703, Beijing 100190 (China)


    The recent discovery of superconductivity in the iron-based superconductors with very high upper critical fields presents a new possibility for practical applications, but fabricating fine-wire is a challenge because of mechanically hard and brittle powders and the toxicity and volatility of arsenic. In this paper, we report the synthesis and the physical characterization of iron pnictide wires and bulks prepared by the powder-in-tube method (PIT). A new class of high-T{sub c} iron pnictide composite wires, such as LaFeAsO{sub 1-x}F{sub x}, SmFeAsO{sub 1-x}F{sub x} and Sr{sub 1-x}K{sub x}FeAs, has been fabricated by the in situ PIT technique using Fe, Ta and Nb tubes. Microscopy and X-ray analysis show that the superconducting core is continuous, and retains phase composition after wire drawing and heat treatment. Furthermore, the wires exhibit a very weak J{sub c}-field dependence behavior even at high temperatures. The upper critical field H{sub c2}(0) value can exceed 100 T, surpassing those of MgB{sub 2} and all the low temperature superconductors and indicating a strong potential for applications requiring very high field. These results demonstrate the feasibility of producing superconducting pnictide composite wire. We also applied the one-step PIT method to synthesize the iron-based bulks, due to its convenience and safety. In fact, by using this technique, we have successfully discovered superconductivity at 35 K and 15 K in Eu{sub 0.7}Na{sub 0.3}Fe{sub 2}As{sub 2} and SmCoFeAsO compounds, respectively. These clearly suggest that the one-step PIT technique is unique and versatile and hence can be tailored easily for other rare earth derivatives of novel iron-based superconductors.

  20. Fabrication and characterization of iron pnictide wires and bulk materials through the powder-in-tube method (United States)

    Ma, Yanwei; Gao, Zhaoshun; Qi, Yanpeng; Zhang, Xianping; Wang, Lei; Zhang, Zhiyu; Wang, Dongliang


    The recent discovery of superconductivity in the iron-based superconductors with very high upper critical fields presents a new possibility for practical applications, but fabricating fine-wire is a challenge because of mechanically hard and brittle powders and the toxicity and volatility of arsenic. In this paper, we report the synthesis and the physical characterization of iron pnictide wires and bulks prepared by the powder-in-tube method (PIT). A new class of high- Tc iron pnictide composite wires, such as LaFeAsO 1-xF x, SmFeAsO 1-xF x and Sr 1-xK xFeAs, has been fabricated by the in situ PIT technique using Fe, Ta and Nb tubes. Microscopy and X-ray analysis show that the superconducting core is continuous, and retains phase composition after wire drawing and heat treatment. Furthermore, the wires exhibit a very weak Jc-field dependence behavior even at high temperatures. The upper critical field Hc2(0) value can exceed 100 T, surpassing those of MgB 2 and all the low temperature superconductors and indicating a strong potential for applications requiring very high field. These results demonstrate the feasibility of producing superconducting pnictide composite wire. We also applied the one-step PIT method to synthesize the iron-based bulks, due to its convenience and safety. In fact, by using this technique, we have successfully discovered superconductivity at 35 K and 15 K in Eu 0.7Na 0.3Fe 2As 2 and SmCoFeAsO compounds, respectively. These clearly suggest that the one-step PIT technique is unique and versatile and hence can be tailored easily for other rare earth derivatives of novel iron-based superconductors.

  1. Monte Carlo Simulation of Nanoparticle Encapsulation in Flames (United States)

    Sun, Z.; Huertas, J. I.; Axelbaum, R. L.


    Gas-phase combustion (flame) synthesis has been an essential industrial process for producing large quantities of powder materials such as carbon black, titanium dioxide, and silicon dioxide. Flames typically produce simple oxides, with carbon black being the noted exception because the oxides of carbon are gaseous and are easily separated from the particulate matter that is formed during fuel pyrolysis. Furthermore, the powders produced in flames are usually agglomerated, nanometer-sized particles (nanoparticles). This composition and morphology is acceptable for many applications. However, the present interest in nanoparticles for advanced materials application has led to efforts to employ flames for the synthesis of unagglomerated nanoparticles (2 to 100 nm) of metals and non-oxide ceramics. Sodium-halide chemistry has proven to be viable for producing metals and non-oxide ceramics in flames. Materials that have been produced to date include Si (Calcote and Felder, 1993), TiN, TiB2, TiC, TiSi2, SiC, B4C (Glassman et al, 1993) Al, W, Ti, TiB2, AlN, and W-Ti and Al-AlN composites (DuFaux and Axelbaum, 1995, Axelbaum et al 1996,1997). Many more materials are possible. The main challenge that faces application of flame synthesis for advanced materials is overcoming formation of agglomerates in flames (Brezinsky, 1997). The high temperatures and high number densities in the flame environment favor the formation of agglomerates. Agglomerates must be avoided for many reasons. For example, when nanopowders are consolidated, agglomerates have a deleterious effect on compaction density, leading to voids in the final part. Efforts to avoid agglomeration in flames without substantially reducing particle number density and, consequently, production rate, have had limited success. Another critical challenge that faces all synthesis routes for nanopowders is ensuring that the powders are high purity and that the process is scaleable. Though the containerless, high temperature

  2. Dynamics of unconfined spherical flames

    CERN Document Server

    Leblanc, Louis; Dennis, Kadeem; Zhe,; Liang,; Radulescu, Matei I


    Using the soap bubble technique, we visualize the dynamics of unconfined hydrogen-air flames using high speed schlieren video. We show that for sufficiently weak mixtures, i.e., low flame speeds, buoyancy effects become important. Flame balls of a critical dimension begin to rise. The experiments are found in very good agreement with the scaling laws proposed by Zingale and Dursi. We report the results in a fluid dynamics video.

  3. Modiifcation of Flame Retardant Epoxy Resin as Electronic Encapsulating Material%环氧树脂电子封装材料的阻燃改性

    Institute of Scientific and Technical Information of China (English)



    在环氧树脂(EP)中添加氢氧化镁和氧化铝两种阻燃剂,研究了不同的阻燃剂对EP的阻燃性的影响。结果表明,当氢氧化镁的体积分数为15%时,EP复合材料的极限氧指数为35%,已达到极难燃塑料要求。当氢氧化镁的体积分数为15%时,EP复合材料的燃烧等级已达到UL 94 V–1级。当氢氧化镁和氧化铝添加的体积分数相同时,添加氢氧化镁的EP复合材料的LOI明显高于添加氧化铝的EP复合材料。纯EP的质量保持率为20%,加入氧化铝的EP复合材料的质量保持率为30%左右,加入氢氧化镁的EP复合材料的质量保持率为40%左右,氢氧化镁使EP的阻燃性能得到很大改善。%Alumina and magnesium hydroxide were added in epoxy resin. The effects of different flame retardant adding to epoxy resin (EP) were studied. The results show that when the volume fraction of magnesium hydroxide is 15%, the limitedoxygen index (LOI) of EP composites is 35% and EP composites combustion level is already UL 94 V–1,that reaches the requirements of high fire resistant plastic. When the volume fraction of magnesium hydroxide and alumina in epoxy resin is same,the LOI of magnesium hydroxide epoxy composites is significantly higher than that of alumina composite. The weight maintenance rate of pure epoxy,alumina composite and magnesium hydroxide epoxy composites respectively is 20%, 30%, 40%. The retardant performance of magnesium hydroxide epoxy composites is greatly improved.

  4. Experimental and numerical studies on interactions of a spherical flame with incident and reflected shocks

    Institute of Scientific and Technical Information of China (English)

    Mingyue Gui; Baochun Fan; Gang Dong; Jingfang Ye


    Observations are presented from experiments and calculations where a laminar spherical CH4/air flame is perturbed successively by incident and reflected shock waves.The experiments are performed in a standard shock tube arrangement, in which a high-speed shadowgraph imagingsystem is used to record evolutions of the flame. Numerical simulations are conducted by using second-order wave propagation algorithms, based on two-dimensional axisymmetric Navier-Stokes equations with detailed chemical reactions. Qualitative agreements are obtained between the experimental and numerical results. Under actions of incident shock waves, Richtmyer-Meshkov instability responsible for the flame deformation is induced in the flame, and the distorted flame takes a barrel shape. Then, under subsequent actions of the shock wave reflected from a planar wall, the flame takes an inclined non-symmetrical kidney shape in a symmetric cross section, which means a mushroom-like shape of the flame comes finally into being. The vorticity direction in the ring cap has been altered by the reflected shock's action, which makes the head of the mushroom-like flame extend quickly to the side wall.

  5. Oxide property of SG tube materials exposed to an alkaline environment as a secondary side of a PWR

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Dongjin; Mun, Byung Hak; Kim, Hong Pyo; Hwang, Seong Sik [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)


    Stress corrosion cracking (SCC) is an issue that should be overcome in nuclear power plants (NPP). Recognizing that cracks initiate and propagate through unavoidable breakdowns and alterations of the surface oxide on Alloy 600, the SCC behavior is closely related to the oxide property. Corrosion resistance against SCC, in particular, was improved through a newly developed heat treatment process from LTMA (low temperature mill annealed) Alloy 600 to HTMA (high temperature mill annealed) Alloy 600, and then TT (thermally treated) Alloy 600. Intra-granular carbide widely spread in LTMA Alloy 600 dissolves, and inter-granular carbide is then formed during high-temperature mill annealing and cooling, which leads to a great SCC resistance enhancement. Inter-granular carbide is well developed, healing chromium depletion at a grain boundary, and residual stress is removed during additional thermal treatment following mill annealing, which improves the SCC resistance more. In spite of this improvement of TT Alloy 600, Seabrook and Vogtle 1 in the US, using TT Alloy 600, also showed SCC due to a non-optimum microstructure, residual stress, Pb existence, and so on over a 20-year operation of an NPP even though SCC occurs less frequently than LTMA and (or) HTMA Alloy 600s. SCC has also occurred for TT Alloy 600 tubes in Korea, whose main causes resemble US cases. The pH at high temperature in the crevice of SG tubes distributes from acidic of 4 to alkaline above 10 at high temperature depending on the impurity concentration such as chloride and hydroxide ions including other corrosive impurities such as Pb known as very detrimental species even though the bulk pH of secondary water is a mild alkaline solution. Regarding the aggressiveness of Pb, even Alloy 690 is also susceptible to SCC in a strong alkaline solution with lead. Therefore, in the present work, the oxides were investigated in a leaded alkaline solution of pH(T) 9.9 at 315 .deg. C as a function of immersion time

  6. Composition of reaction intermediates for stoichiometric and fuel-rich dimethyl ether flames: flame-sampling mass spectrometry and modeling studies. (United States)

    Wang, Juan; Chaos, Marcos; Yang, Bin; Cool, Terrill A; Dryer, Fred L; Kasper, Tina; Hansen, Nils; Osswald, Patrick; Kohse-Höinghaus, Katharina; Westmoreland, Phillip R


    Molecular-beam synchrotron photoionization mass spectrometry and electron-ionization mass spectrometry are used for measurements of species mole fraction profiles for low-pressure premixed dimethyl ether (DME) flames with equivalence ratios ranging from near-stoichiometric conditions (Phi = 0.93) to fuel-rich flames near the limits of flat-flame stability (Phi = 1.86). The results are compared with predictions of a recently modified kinetic model for DME combustion [Zhao et al., Int. J. Chem. Kinet., 2008, 40, 1-18] that has been extensively tested against laminar flame speed measurements, jet-stirred reactor experiments, pyrolysis and oxidation experiments in flow reactors, species measurements for burner-stabilized flames and ignition delay measurements in shock tubes. The present comprehensive measurements of the composition of reaction intermediates over a broad range of equivalence ratios considerably extends the range of the previous experiments used for validation of this model and allows for an accurate determination of contributions of individual reactions to the formation or destruction of any given flame species. The excellent agreement between measurements and predictions found for all major and most intermediate species over the entire range of equivalence ratios provides a uniquely sensitive test of details of the kinetic model. The dependence on equivalence ratio of the characteristic reaction paths in DME flames is examined within the framework of reaction path analyses.

  7. Influence of Fe content on corrosion and hydrogen pick up behavior of Zr–2.5Nb pressure tube material

    Energy Technology Data Exchange (ETDEWEB)

    Choudhuri, Gargi, E-mail: [Quality Assurance Division, BARC, Mumbai 400 085 (India); Jagannath [Theoretical Physics Division, BARC, Mumbai 400 085 (India); Kiran Kumar, M.; Kain, V.; Srivastava, D. [Material Science Division, BARC, Mumbai 400 085 (India); Basu, S. [Solid State Physics Division, BARC, Mumbai 400 085 (India); Shah, B.K. [Quality Assurance Division, BARC, Mumbai 400 085 (India); Saibaba, N. [Nuclear Fuel Complex, Hyderabad 500 062 (India); Dey, G.K. [Material Science Division, BARC, Mumbai 400 085 (India)


    The effects of Fe addition in the range of 300–1250 ppm in cold worked stress-relieved Zr–2.5Nb pressure tube on oxidation and hydrogen pick up behavior have been studied after 415 °C steam autoclaving. Microstructure and micro-chemistry of second phase and precipitates were characterized using electron microscope. Addition of 800 ppm Fe in Zr–2.5Nb alloy led to better oxidation resistance. With further addition of Fe no significant improvement of oxidation resistance was observed but hydrogen-pickup was found to increase. Zr–Nb–Fe bearing precipitates were observed in Zr–2.5Nb alloy containing 800 ppm Fe. Further addition of Fe led to formation of Zr–Fe intermetallic. The chemical state of oxide has been determined by X-ray photo electron spectroscopy. Grazing Incidence X-ray Diffraction revealed that oxide in alloys with higher Fe, contained a higher fraction of tetragonal-Zirconia which is indicative of a protective oxide film and hence better oxidation resistance of the alloy.

  8. Formation of the preheated zone ahead of a propagating flame and the mechanism underlying the deflagration-to-detonation transition (United States)

    Liberman, M. A.; Kuznetsov, M.; Ivanov, A.; Matsukov, I.


    The Letter presents analytical, numerical and experimental studies of the mechanism underlying the deflagration-to-detonation transition (DDT). Insight into how, when, and where DDT occurs is obtained by analyzing analytically and by means of multidimensional numerical simulations dynamics of a flame accelerating in a tube with no-slip walls. It is shown that the deflagration-to-detonation transition exhibits three separate stages of evolution corroborating majority experimental observations. During the first stage flame accelerates and generates shocks far ahead of the flame front. During the second stage the flame slows down, shocks are formed in the immediate proximity of the flame front and the preheated zone ahead of the flame front is created. The third stage is self-restructuring of the steep temperature profile within the flame, formation of a reactivity gradient and the actual formation of the detonation wave itself. The mechanism for the detonation wave formation, given an appropriate formation of the preheated zone, seems to be universal and involves a reactivity gradient formed from the initially steep flame temperature profile in the presence of the preheated zone. The developed theory and numerical simulations are found to be well consistent with extensive experiments of the DDT in hydrogen-oxygen and ethylene-oxygen mixtures in tubes with smooth and rough walls.

  9. Solid Propellant Flame Spectroscopy (United States)


    400 jm to reach the maximum flame temperature, a distance that can be reduced by replacing the HTPB binder with a polyester or CMDB binder. The...the dark zone for propellants similar to HIX2 is 2-2.5 mm at 1.8 MPa (18 atm, 265 psia) (Ref. 22,187). In contrast, the dark zone for HMX CMDB ...propellants eliminates the dark zone is not surprising, since TMETN is a nitrate ester as was the double-base matrix of Kubota’s HMX CMDB propellant. A

  10. Dynamics and structure of stretched flames

    Energy Technology Data Exchange (ETDEWEB)

    Law, C.K. [Princeton Univ., NJ (United States)


    This program aims to gain fundamental understanding on the structure, geometry, and dynamics of laminar premixed flames, and relate these understanding to the practical issues of flame extinction and stabilization. The underlying fundamental interest here is the recent recognition that the response of premixed flames can be profoundly affected by flame stretch, as manifested by flow nonuniformity, flame curvature, and flame/flow unsteadiness. As such, many of the existing understanding on the behavior of premixed flames need to be qualitatively revised. The research program consists of three major thrusts: (1) detailed experimental and computational mapping of the structure of aerodynamically-strained planar flames, with emphasis on the effects of heat loss, nonequidiffusion, and finite residence time on the flame thickness, extent of incomplete reaction, and the state of extinction. (2) Analytical study of the geometry and dynamics of stretch-affected wrinkled flame sheets in simple configurations, as exemplified by the Bunsen flame and the spatially-periodic flame, with emphasis on the effects of nonlinear stretch, the phenomena of flame cusping, smoothing, and tip opening, and their implications on the structure and burning rate of turbulent flames. (3) Stabilization and blowoff of two-dimensional inverted premixed and stabilization and determining the criteria governing flame blowoff. The research is synergistically conducted through the use of laser-based diagnostics, computational simulation of the flame structure with detailed chemistry and transport, and mathematical analysis of the flame dynamics.

  11. Aeronautical tubes and pipes (United States)

    Beauclair, N.


    The main and subcomponent French suppliers of aircraft tubes and pipes are discussed, and the state of the industry is analyzed. Quality control is essential for tubes with regard to their i.d. and metallurgical compositions. French regulations do not allow welded seam tubes in hydraulic circuits unless no other form is available, and then rustproofed steel must be installed. The actual low level of orders for any run of tubes dictates that the product is only one of several among the manufacturers' line. Automation, both in NDT and quality control, assures that the tubes meet specifications. A total of 10 French companies participate in the industry, serving both civil and military needs, with some companies specializing only in titanium, steel, or aluminum materials. Concerns wishing to enter the market must upgrade their equipment to meet the higher aeronautical specifications and be prepared to furnish tubes and pipes that serve both functional and structural purposes simultaneously. Additionally, pipe-bending machines must also perform to tight specifications. Pipes can range from 0.2 mm exterior diameter to 40 mm, with wall thicknesses from 0.02 mm to 3 mm. A chart containing a list of manufacturers and their respective specifications and characteristics is presented, and a downtrend in production with reduction of personnel is noted.

  12. Effect of thermal conductivity of tube material on overall heat transfer coefficient of condenser, proposal for correction of HEI code

    Energy Technology Data Exchange (ETDEWEB)

    Banquet, F. [Electricite de France, Villeurbanne (France)


    The HEI code, 8th edition, addendum n{degrees}1, which was used for condenser design, makes no distinction between grade 2 titanium characteristics and those of 304L and 316L stainless steels. In 1993 the Electric Power Research Institute (EPRI) published the results of a study on a test condenser: these suggest that the overall heat transfer coefficient of a titanium bundle is substantially higher than that of the same bundle made from stainless steel. The EPRI study inspired the 9th edition of the HEI Standards. To form its own opinion, EDF conducted a study to compare these various design methods and, in particular, to evaluate the effect of the thermal conductivity of materials on the overall heat transfer coefficient; a two-dimensional thermohydraulic code was used, considering different condensers from EDF nuclear power plants. During the study EDF observed that the thermal conductivity values of materials varied greatly depending on the sources, mainly grade 2 titanium and, to a lesser extent, 304L and 316L. It had the thermal conductivity of these materials measured using a highly accurate method in a manufacturer-independent laboratory. In conclusion, EDF considers: The EPRI correction method is wholly acceptable, The HEI 9 code is acceptable on condition that the material correction factors are slightly modified. 5 refs., 11 tabs.

  13. Flame Retardant Exposure among Collegiate U.S. Gymnasts (United States)

    Carignan, Courtney C.; Heiger-Bernays, Wendy; McClean, Michael D.; Roberts, Simon C.; Stapleton, Heather M.; Sjödin, Andreas; Webster, Thomas F.


    Gymnastics training facilities contain large volumes of polyurethane foam, a material that often contains additive flame retardants such as PentaBDE. While investigations of human exposure to flame retardants have focused on the general population, potentially higher than background exposures may occur in gymnasts and certain occupational groups. Our objectives were to compare PentaBDE body burden among gymnasts to the general U.S. population and characterize flame retardants levels in gym equipment, air and dust. We recruited 11 collegiate female gymnasts (ages 18–22) from one gym in the Eastern U.S. The geometric mean (GM) concentration of BDE-153 in gymnast sera (32.5 ng/g lipid) was 4–6.5 times higher than general U.S. population groups. Median concentrations of PentaBDE, TBB and TBPH in paired handwipe samples were 2–3 times higher after practice compared to before, indicating the gymnasts contacted these flame retardants during practice. GM concentrations of PentaBDE, TBB and TBPH were 1-3 orders of magnitude higher in gym air and dust than in residences. Our findings suggest that these collegiate gymnasts experienced higher exposures to PentaBDE flame retardants compared to the general U.S. population and that gymnasts may also have increased exposure to other additive flame retardants used in polyurethane foam such as TBB and TBPH. PMID:24195753

  14. Flame retardant exposure among collegiate United States gymnasts. (United States)

    Carignan, Courtney C; Heiger-Bernays, Wendy; McClean, Michael D; Roberts, Simon C; Stapleton, Heather M; Sjödin, Andreas; Webster, Thomas F


    Gymnastics training facilities contain large volumes of polyurethane foam, a material that often contains additive flame retardants such as PentaBDE. While investigations of human exposure to flame retardants have focused on the general population, potentially higher than background exposures may occur in gymnasts and certain occupational groups. Our objectives were to compare PentaBDE body burden among gymnasts to the general United States population and characterize flame retardants levels in gym equipment, air, and dust. We recruited 11 collegiate female gymnasts (ages 18-22) from one gym in the eastern United States. The geometric mean (GM) concentration of BDE-153 in gymnast sera (32.5 ng/g lipid) was 4-6.5 times higher than in the general United States population groups. Median concentrations of PentaBDE, TBB, and TBPH in paired handwipe samples were 2-3 times higher after practice compared to before, indicating the gymnasts contacted these flame retardants during practice. GM concentrations of PentaBDE, TBB, and TBPH were 1-3 orders of magnitude higher in gym air and dust than in residences. Our findings suggest that these collegiate gymnasts experienced higher exposures to PentaBDE flame retardants compared to the general United States population and that gymnasts may also have increased exposure to other additive flame retardants used in polyurethane foam such as TBB and TBPH.

  15. Analysis of the step responses of laminar premixed flames to forcing by non-thermal plasma

    KAUST Repository

    Lacoste, Deanna A.


    The step responses of lean methane-air flames to non-thermal plasma forcing is reported. The experimental setup consists of an axisymmetric burner, with a nozzle made of a quartz tube. The equivalence ratio is 0.95, allowing stabilization of the flame in a V-shape or an M-shape geometry, over a central stainless steel rod. The plasma is produced by short pulses of 10-ns duration, 8-kV maximum voltage amplitude, applied at 10 kHz. The central rod is used as a cathode, while the anode is a stainless steel ring, fixed on the outer surface of the quartz tube. Plasma forcing is produced by positive or negative steps of plasma. The step response of the flame is investigated through heat release rate (HRR) fluctuations, to facilitate comparisons with flame response to acoustic perturbations. The chemiluminescence of CH* between two consecutive pulses was recorded using an intensified camera equipped with an optical filter to estimate the HRR fluctuations. First, the results show that the flame does not respond to each single plasma pulse, but is affected only by the average plasma power, confirming the step nature of the forcing. The temporal evolutions of HRR are analyzed and the flame transfer functions are determined. A forcing mechanism, as a local increase in the reactivity of the fluid close to the rod, is proposed and compared with numerical simulations. Experiments and numerical simulations are in good qualitative agreement. © 2016.

  16. Magnesium tube hydroforming

    Energy Technology Data Exchange (ETDEWEB)

    Liewald, M.; Pop, R. [Institute for Metal Forming Technology (IFU), Stuttgart (Germany)


    Magnesium alloys reveal a good strength-to-weight ratio in the family of lightweight metals and gains potential to provide up to 30% mass savings compared to aluminium and up to 75 % compared to steel. The use of sheet magnesium alloys for auto body applications is however limited due to the relatively low formability at room temperature. Within the scope of this paper, extruded magnesium tubes, which are suitable for hydroforming applications, have been investigated. Results obtained at room temperature using magnesium AZ31 tubes show that circumferential strains are limited to a maximal value of 4%. In order to examine the influence of the forming temperature on tube formability, investigations have been carried out with a new die set for hot internal high pressure (IHP) forming at temperatures up to 400 C. Earlier investigations with magnesium AZ31 tubes have shown that fractures occur along the welding line at tubes extruded over a spider die, whereby a non-uniform expansion at bursting with an elongation value of 24% can be observed. A maximum circumferential strain of approx. 60% could be attained when seamless, mechanically pre-expanded and annealed tubes of the same alloy have been used. The effect of annealing time on materials forming properties shows a fine grained structure for sufficient annealing times as well as deterioration with a large increase at same time. Hence, seamless ZM21 tubes have been used in the current investigations. With these tubes, an increased tensile fracture strain of 116% at 350 C is observed as against 19% at 20 C, obtained by tensile testing of milled specimens from the extruded tubes. This behaviour is also seen under the condition of tool contact during the IHP forming process. To determine the maximum circumferential strain at different forming temperatures and strain rates, the tubes are initially bulged in a die with square cross-section under plane stress conditions. Thereafter, the tubes are calibrated by using an

  17. Gastrostomy Tube (G-Tube) (United States)

    ... the recovery room, sometimes called the "post-op" (post-operative) room or PACU (post-anesthesia care unit), and ... site; discharge that's yellow, green, or foul-smelling; fever) excessive bleeding or drainage from the tube site ...

  18. Determinação de cálcio e de magnésio em plantas, por fotometria de chama de absorção Determination of calcium and magnesium in plant material, by absorption flame photometry

    Directory of Open Access Journals (Sweden)

    Ondino Cleante Bataglia


    Full Text Available As concentrações de cálcio e magnésio em extratos de plantas podem ser determinadas por fotometria de chama de absorção com a precisão e exatidão requeridas, mediante a adição de lantânio na concentração de 0,1 %,como agente protetor. Para obtenção dos dados utilizou-se um espectrofotômetro Perkin-Elmer, modelo 303, equipado com sistema digital de leitura.A method for determination of calcium and magnesium by absorption flame photometry was studied using a Perkin-Elmer model 303 spectrophotometer equiped with digital concentration readout model DCR1. The study of interferents was carried out with concentration usually present in plant material or even in higher concentrations to get information about the possibility of applying this method to other materials. Within the limits of concentration studied, it was observed that calcium determination was affected by the ions Fe 3+, Al3+ , Mn 2+, Si 4+, PO3-4 and SO2-4 . The ions Mg2+ , K+ , Na+ , Cu2+ , Zn2+ , CI- , NO-3 and ClO-4 had no interference. Magnesium determination was affected only by the presence of the ions Al3+ and Si4+. The use of 0.1% lanthanum solution suppressed the interference of 10 ppm of Al3+, Fe3+ or Mn2+, 50 ppm of Si4+ and 100 ppm of PO3-4 or SO2-4 on a 5 ppm calcium solution. It suppressed also the effect of 10 ppm of Al or 50 ppm of Si in the absorbance of 1 ppm magnesium solution. In the application of the method for calcium and magnesium in plant analysis, 0.200 g of dried plant material was digested with 1 ml of nitric acid and 0.5 ml percloric acid. The volume was completed to 50 ml with distilled water. A portion (2 to 10 ml was transfered to a 50 ml volumetric flask, lanthanum was added to a final concentration of 0.1% and the volume was taken to 50 ml. Calcium and magnesium in plant material were determined using calibration curves, obtained with calcium solutions varying from 0 to 10 ppm and magnesium solutions varying from 0 to 2 ppm (both had 0

  19. Tube-Super Dielectric Materials: Electrostatic Capacitors with Energy Density Greater than 200 J·cm−3

    Directory of Open Access Journals (Sweden)

    Francisco Javier Quintero Cortes


    Full Text Available The construction and performance of a second generation of super dielectric material based electrostatic capacitors (EC, with energy density greater than 200 J·cm−3, which rival the best reported energy density of electric double layer capacitors (EDLC, also known as supercapacitors, are reported. The first generation super dielectric materials (SDM are multi-material mixtures with dielectric constants greater than 1.0 × 105, composed of a porous, electrically insulating powder filled with a polarizable, ion-containing liquid. Second-generation SDMs (TSDM, introduced here, are anodic titania nanotube arrays filled with concentrated aqueous salt solutions. Capacitors using TiO2 based TSDM were found to have dielectric constants at ~0 Hz greater than 107 in all cases, a maximum operating voltage of greater than 2 volts and remarkable energy density that surpasses the highest previously reported for EC capacitors by approximately one order of magnitude. A simple model based on the classic ponderable media model was shown to be largely consistent with data from nine EC type capacitors employing TSDM.

  20. Subwoofer and nanotube butterfly acoustic flame extinction (United States)

    Aliev, Ali E.; Mayo, Nathanael K.; Baughman, Ray H.; Mills, Brent T.; Habtour, Ed


    Nonchemical flame control using acoustic waves from a subwoofer and a lightweight carbon nanotube thermoacoustic projector was demonstrated. The intent was to manipulate flame intensity, direction and propagation. The mechanisms of flame suppression using low frequency acoustic waves were discussed. Laminar flame control and extinction were achieved using a thermoacoustic ‘butterfly’ projector based on freestanding carbon nanotube sheets.

  1. Steam generator tube integrity program

    Energy Technology Data Exchange (ETDEWEB)

    Dierks, D.R.; Shack, W.J. [Argonne National Laboratory, IL (United States); Muscara, J.


    A new research program on steam generator tubing degradation is being sponsored by the U.S. Nuclear Regulatory Commission (NRC) at Argonne National Laboratory. This program is intended to support a performance-based steam generator tube integrity rule. Critical areas addressed by the program include evaluation of the processes used for the in-service inspection of steam generator tubes and recommendations for improving the reliability and accuracy of inspections; validation and improvement of correlations for evaluating integrity and leakage of degraded steam generator tubes, and validation and improvement of correlations and models for predicting degradation in steam generator tubes as aging occurs. The studies will focus on mill-annealed Alloy 600 tubing, however, tests will also be performed on replacement materials such as thermally-treated Alloy 600 or 690. An overview of the technical work planned for the program is given.

  2. Kinetics of thermal and photo-initiated release of tris (1,3-dichloro-2-propyl) phosphate (TDCP) flame retardant from polyurethane foam materials. (United States)

    Ghanem, Raed A


    Kinetics of thermal and photo-initiated release of Tris (1.3-dichloro-2-propyl) phosphate (TDCP) from the polyurethane foam (PUF) materials were studied using a validated chromatographic method with linear calibration curve in the range of 0.03-400 μg mL(-1). Time dependence of TDCP leaching from foam samples was found to follow first-order kinetics; with rate constants directly dependent on ageing temperatures and intensity of UV radiation, rate constants for the thermally and photo initiated were 3.6 × 10(-3), 1.03 × 10(-2), 3.6 × 10(-2) and 3.94 × 10(-2) day(-1), respectively. Migration of TDCP from foam samples simulating skin or oral exposure were observed from all samples regardless of their ageing history, the presence of biological fluids found to enhance the migration rate. Oral exposure to foam material contains TDCP, which was simulated using the Head-over-Heels test, reveals that an average amount of ∼ 1.7% wt./wt. of the total amount of TDCP was found to leach into biological fluids, and it significantly increased to ∼ 6.0% wt./wt. due to ageing conditions. Direct contact between foam material and skin simulated by using the Contact Blotting test reveals that TDCP is transferred from both aged and un-aged samples at different rates, due to the presence of biological fluids; the transferred amount is increased with ageing conditions.

  3. Recent Advances in Flame Tomographyt

    Institute of Scientific and Technical Information of China (English)

    闫勇; 邱天; 卢钢; M.M.Hossain; G.Gilabert; 刘石


    To reduce greenhouse gas emissions from fossil fuel fired power plants,a range of new combustion technologies are being developed or refined,including oxy-fuel combustion,co-firing biomass with coal and fluidized bed combustion.Flame characteristics under such combustion conditions are expected to be different from those in normal air fired combustion processes.Quantified flame characteristics such as temperature distribution,oscillation frequency,and ignition volume play an important part in the optimized design and operation of the environmentally friendly power generation systems.However,it is challenging to obtain such flame characteristics particularly through a three-dimensional and non-intrusive means.Various tomography methods have been proposed to visualize and characterize flames,including passive optical tomography,laser based tomography,and electrical tomography.This paper identifies the challenges in flame tomography and reviews existing techniques for the quantitative characterization of flames.Future trends in flame tomography for industrial applications are discussed.

  4. Turbulence in laminar premixed V-flames

    Institute of Scientific and Technical Information of China (English)

    ZHANG; Xiaoqian(张孝谦); LEI; Yu(雷宇); WANG; Baorui(王宝瑞); WANG; Yue(王岳); WEI; Minggang(韦明罡)


    Strong velocity fluctuations had been found in the laminar premixed V-flames. These velocity fluctuations are closely related to the chemical reaction. But the effects of the upstream combustible mixture velocity on the velocity fluctuations inside the flame are quite weak. The probability distribution function (PDF) of the velocity in the centre region of the flame appears "flat top" shaped. By analyzing the experiment results the flame-flow interactions are found to affect the flame not only at large scale in the flow field but also at small scale inside the flame. These effects will give rise to flame generated small scale turbulences.

  5. Mathematical treatment of melting and solidification of phase change materials between circumferentially finned tubes. Analytische Behandlung des Schmelzens und Erstarrens von Latentwaermespeichermaterialien in Rippenrohrgeometrien

    Energy Technology Data Exchange (ETDEWEB)

    Heinisch, M.


    The following study deals with the theoretical investigation of heat transfer in a latent heat store. The object of the investigation is a heat exchanger element with a circumferentially finned tube, in which the space between the fins is filled with storage material. An analytical method, employing Green's function, was developed for this arrangement in order to solve the two dimensional (r,z-coordinates) transient heat conduction in inhomogenous materials with simultaneous phase change. When compared with other well-known analytical methods, the most important advantages are that the Fourier heat conduction equation and the boundary conditions at the phase front are simultaneously fulfilled by the final solution, as well as the fact that the initial temperature is independent of a given phase change temperature. A fundamental advantage can also be seen in the very small number of time steps for calculating the transient charging/discharging processes and hence shorter calculation times. Two special extreme cases were designed where the results agree well with literature data. In comparison with the numerically calculated melting and solidification behaviour only small variations were observed.

  6. Advances in Tube Hydroforming - An Enabling Technology for Low-Mass Vehicle Manufacturing - Material, Lubrication,Loading, Simulation Issues, and Alternatives

    Institute of Scientific and Technical Information of China (English)

    Muammer Ko(c)


    The tube hydroforming process (THF) has recently found a wide application opportunity in the automotive industry, and is of increasing interest to other industries as well. The increased interest stems from the fact that, through the THF process, manufacturers are able to produce complex, consolidated, lightweight parts with reduced number of post-processing than through alternative metal forming techniques. In order to fully realize the benefits of this technology, various aspects have been under investigation in academia and industry world-wide. In this paper, effect of loading path, incoming material variation, and lubrication on the robustness of the hydroforming process and final part specifications are summarized based on previous experimental and computational work. In addition, the simulation of hydroforming and examples are presented in comparison with experimental findings. Briefly, results emphasized the importance of the loading path design whereas material variation within the experimentally tested range was not found to be significantly effective on the final part specifications. Selection of a lubricant for hydroforming of a frame rail part was presented demonstrating several aspects of lubrication selection methodology. Results of friction experiments show that only thickness, axial feeding, and force measurements are good indications of lubricant performance as these are found to be strongly discriminative.

  7. Soot Deposit Properties in Practical Flames

    Energy Technology Data Exchange (ETDEWEB)

    Preciado, Ignacio [University of Utah; Eddings, Eric G. [University of Utah; Sarofim, Adel F. [University of Utah; Dinwiddie, Ralph Barton [ORNL; Porter, Wallace D [ORNL; Lance, Michael J [ORNL


    Soot deposition from hydrocarbon flames was investigated in order to evaluate the evolution of the deposits during the transient process of heating an object that starts with a cold metal surface that is exposed to a flame. The study focused on the fire/metal surface interface and the critical issues associated with the specification of the thermal boundaries at this interface, which include the deposition of soot on the metal surface, the chemical and physical properties of the soot deposits and their subsequent effect on heat transfer to the metal surface. A laboratory-scale device (metallic plates attached to a water-cooled sampling probe) was designed for studying soot deposition in a laminar ethylene-air premixed flame. The metallic plates facilitate the evaluation of the deposition rates and deposit characteristics such as deposit thickness, bulk density, PAH content, deposit morphology, and thermal properties, under both water-cooled and uncooled conditions. Additionally, a non-intrusive Laser Flash Technique (in which the morphology of the deposit is not modified) was used to estimate experimental thermal conductivity values for soot deposits as a function of deposition temperature (water-cooled and uncooled experiments), location within the flame and chemical characteristics of the deposits. Important differences between water-cooled and uncooled surfaces were observed. Thermophoresis dominated the soot deposition process and enhanced higher deposition rates for the water-cooled experiments. Cooler surface temperatures resulted in the inclusion of increased amounts of condensable hydrocarbons in the soot deposit. The greater presence of condensable material promoted decreased deposit thicknesses, larger deposit densities, different deposit morphologies, and higher thermal conductivities.

  8. Effects of AC Electric Field on Small Laminar Nonpremixed Flames

    KAUST Repository

    Xiong, Yuan


    Electric field can be a viable method in controlling various combustion properties. Comparing to traditional actuators, an application of electric field requires very small power consumption. Especially, alternating current (AC) has received attention recently, since it could modulate flames appreciably even for the cases when direct current (DC) has minimal effects. In this study, the effect of AC electric fields on small coflow diffusion flames is focused with applications of various laser diagnostic techniques. Flow characteristics of baseline diffusion flames, which corresponds to stationary small coflow diffusion flames when electric field is not applied, were firstly investigated with a particular focus on the flow field in near-nozzle region with the buoyancy force exerted on fuels due to density differences among fuel, ambient air, and burnt gas. The result showed that the buoyancy force exerted on the fuel as well as on burnt gas significantly distorted the near-nozzle flow-fields. In the fuels with densities heavier than air, recirculation zones were formed very close to the nozzle exit. Nozzle heating effect influenced this near-nozzle flow-field particularly among lighter fuels. Numerical simulations were also conducted and the results showed that a fuel inlet boundary condition with a fully developed velocity profile for cases with long fuel tubes should be specified inside the fuel tube to obtain satisfactory agreement in both the flow and temperature fields with those from experiment. With sub-critical AC applied to the baseline flames, particle image velocimetry (PIV), light scattering, laser-induced incandescence (LII), and laser-induced fluores- cence (LIF) techniques were adopted to identify the flow field and the structures of OH, polycyclic aromatic hydrocarbons (PAHs), soot zone. Under certain AC condi- tions of applied voltage and frequency, the distribution of PAHs and the flow field near the nozzle exit were drastically altered from the

  9. The Influence of Flame Retardant Treated Timber Density on Combustibility

    Directory of Open Access Journals (Sweden)

    Zbignev Karpovič


    Full Text Available Timber is widely used as a construction material in the majority of countries. In most cases, timber is the main structural material. Timber and timber fabrics used in building structure elements have to fulfill the requirements of fire safety. This article presents factors affecting the combustibility of timber, mainly the influence of flame retardants on the combustion phase, timber density and moisture. The influence of flame retardant treated timber density on combustibility is analyzed in this paper. Research was performed according to the requirements of the standard LST ISO 5657:1999 “Reaction to fire tests – ignitibility of building products using a radiant heat source”. The influence of flame retardant treated timber density on combustibility is assessed according to duration up to the combustion of the specimen. Article in Lithuanian

  10. Electrical Aspects of Impinging Flames (United States)

    Chien, Yu-Chien

    This dissertation examines the use of electric fields as one mechanism for controlling combustion as flames are partially extinguished when impinging on nearby surfaces. Electrical aspects of flames, specifically, the production of chemi-ions in hydrocarbon flames and the use of convective flows driven by these ions, have been investigated in a wide range of applications in prior work but despite this fairly comprehensive effort to study electrical aspects of combustion, relatively little research has focused on electrical phenomena near flame extinguishment, nor for flames near impingement surfaces. Electrical impinging flames have complex properties under global influences of ion-driven winds and flow field disturbances from the impingement surface. Challenges of measurements when an electric field is applied in the system have limited an understanding of changes to the flame behavior and species concentrations caused by the field. This research initially characterizes the ability of high voltage power supplies to respond on sufficiently short time scales to permit real time electrical flame actuation. The study then characterizes the influence of an electric field on the impinging flame shape, ion current and flow field of the thermal plume associated with the flame. The more significant further examinations can be separated into two parts: 1) the potential for using electric fields to control the release of carbon monoxide (CO) from surface-impinging flames, and 2) an investigation of controlling electrically the heat transfer to a plate on which the flame impinges. Carbon monoxide (CO) results from the incomplete oxidation of hydrocarbon fuels and, while CO can be desirable in some syngas processes, it is usually a dangerous emission from forest fires, gas heaters, gas stoves, or furnaces where insufficient oxygen in the core reaction does not fully oxidize the fuel to carbon dioxide and water. Determining how carbon monoxide is released and how heat transfer

  11. A study on the Pb-SCC characteristics of Korean-made S/G tube materials

    Energy Technology Data Exchange (ETDEWEB)

    Park, I. G.; Lee, C. S. [Sunmoon Univ., Cheonan (Korea)


    Stress corrosion cracking(SCC) tests were performed using C-ring specimens for commercial and korean-made Alloys 600 and 690, in order to evaluate the SCC resistance in caustic environments with electrochemical potential of +125mV at 315 deg C for 480 hrs. Different cracking phenomenon was observed with NaOH concentrations. No SCC crack was observed in 4% and 50% NaOH solutions, while intergranular stress corrosion cracking(IGSCC) was found for commercial Alloy 600 MA in 10%, 20%, and 30% NaOH solutions. Caustic SCC was most severe in 30% NaOH solution. Interestingly, in 30% NaOH solution, transgranular stress corrosion cracking was detected from C690TT, contrary to the previous results. In case of two times duration(1,000 rs), transgranular stress corrosion cracking(TGSCC) was also detected. This crack nucleation stage of TGSCC has changed to the crack propagation stage of IGSCC in the longer immersion time of 3,000 hrs. SCC resistance of korean-made Alloy 690 TT was found out to be much superior to that of the other alloys. C-ring tests were also carried out to analyze the effect of Pb on SCC in 4% NaOH solution at 345 deg C with the variation of Pb concentration. It seemed that Pb-SCC occurred when Pb concentration was above at least 100 ppm. Pb-SCC resistance was increased with Cr concentration in alloy compositions. Korean-made materials were better than commercial materials for caustic SCC and Pb-SCC resistance. 54 refs., 28 figs., 11 tabs. (Author)

  12. Metallic iron nanoparticles: Flame synthesis, characterization and magnetic properties

    Institute of Scientific and Technical Information of China (English)

    Yunfeng Li; Yanjie Hu; Guangjian Huang; Chunzhong Li


    Metallic iron (Fe) nanoparticles (NPs) with a typical core-shell structure have been prepared by a simple and continuous flame spray pyrolysis (FSP) method,which are stabilized by the corresponding Fe3O4 shell with a thickness of 4-6 nm.The size of metallic Fe cores is about 30-80 nm.The core-shell structured iron NPs show an air stability as long as one month as a result of the protection of oxide shell.Through the control of the residence time of materials in flame and flame atmosphere,metallic Fe and iron oxides are obtained,showing a better external magnetic field responsibility.It is concluded that the evolution of morphology and composition of flame-made magnetic NPs could be attributed to the competition mechanism between reduction and oxidation reactions of in situ flame combustion,which offers more choices and better effective design strategy for the synthesis of advanced functional materials via FSP techniques.

  13. 含再生材料的PC/PET无卤阻燃合金加工稳定性%Processing Stability of Recycled Materials PC/PET Alloy Containing Halogen-Free Flame Retardant

    Institute of Scientific and Technical Information of China (English)

    高磊; 李强; 李文强; 罗明华


    通过对再生聚对苯二甲酸乙二酯(PET–R)的多次挤出,研究了扩链对PET–R稳定性的影响。同时,也通过多次挤出和多次注塑的Regrind实验,研究了丙烯腈–苯乙烯塑料接枝甲基丙烯酸缩水甘油酯(AS-g-GMA)加入后再生聚碳酸酯(PC)/PET体系的相容性和稳定性,以及熔体流动速率和冲击强度的变化。通过11个月内的生产数据反映出,经过扩链和稳定化处理后的含再生材料的PC/PET无卤阻燃合金具有很好的加工稳定性。%The influence of chain extending on the stability of recycled polyethylene terephthalate (PET–R) was studied by multi-extrusion experiment. Meanwhile the changes of compatibility, stability, melt flow rate and impact strength of recycled polycarbonate (PC–R)/PET–R alloy after adding acrylonitrile-styrene grafted glycidyl methacrylate (AS-g-GMA) was discussed through multi-extrusion and multi-injection Regrind experiments. The production data of eleven months indicates that after the process of chain extending and stabilizing, the halogen-free flame retardant PC/PET alloy containing recycled materials has better stabilization.

  14. In-situ tube burst testing and high-temperature deformation behavior of candidate materials for accident tolerant fuel cladding (United States)

    Gussev, M. N.; Byun, T. S.; Yamamoto, Y.; Maloy, S. A.; Terrani, K. A.


    One of the most essential properties of accident tolerant fuel (ATF) for maintaining structural integrity during a loss-of-coolant accident (LOCA) is high resistance of the cladding to plastic deformation and burst failure, since the deformation and burst behavior governs the cooling efficiency of flow channels and the process of fission product release. To simulate and evaluate the deformation and burst process of thin-walled cladding, an in-situ testing and evaluation method has been developed on the basis of visual imaging and image analysis techniques. The method uses a specialized optics system consisting of a high-resolution video camera, a light filtering unit, and monochromatic light sources. The in-situ testing is performed using a 50 mm long pressurized thin-walled tubular specimen set in a programmable furnace. As the first application, ten (10) candidate cladding materials for ATF, i.e., five FeCrAl alloys and five nanostructured steels, were tested using the newly developed method, and the time-dependent images were analyzed to produce detailed deformation and burst data such as true hoop stress, strain (creep) rate, and failure stress. Relatively soft FeCrAl alloys deformed and burst below 800 °C, while negligible strain rates were measured for higher strength alloys.

  15. Old and New Flavors of Flame (Furnace Atomic Absorption Spectrometry

    Directory of Open Access Journals (Sweden)

    Amália Geiza Gama Dionísio


    Full Text Available This paper presents some recent applications of Flame Atomic Absorption Spectrometry (FAAS to different matrices and samples. The time window selected was from 2006 up to March, 2011, and several aspects related to food, biological fluids, environmental, and technological samples analyses were reported and discussed. In addition, the chemometrics application for FAAS methods development was also taken into account, as well as the use of metal tube atomizers in air/acetylene flame. Preconcentration methods coupled to FAAS were discussed, and several approaches related to speciation, flotation, ionic liquids, among others were discussed. This paper can be interesting for researchers and FAAS users in order to see the state of the art of this technique.

  16. Cathode ray tube glass recycling: an example of clean technology. (United States)

    Andreola, Fernanda; Barbieri, Luisa; Corradi, Anna; Lancellotti, Isabella


    In this study the use of 'cleaned' end of life (EOL) cathode ray tube (CRT) glass as a raw material in ceramic glazes is described. At present, the recycling and industrial utilization of CRT, a glass material from TV and computer sets, is a subject of intense research with particular regard to the so-called open-loop recycling, namely cycles different from that of the origin. However, the use of CRT glass as a secondary raw material is strictly related to the demand of high-quality raw material. The good preliminary results reached by introducing clean TV and PC monitor panel and cone glass into ceramic glaze formulations pushed research toward the setting-up of a base glaze that is exploitable for the production of pigmented, silk-screened and flame-hardened glazes (products used industrially for coating floor tiles). The aesthetic and chemical characterization of the tiles glazed by this product showed an extremely similar behaviour to originals that did not contain CRT glass. The good technical results achieved have been supported by the life cycle assessment analysis, which has demonstrated a reduction of the environmental impact of the CRT glass-containing ceramic glaze with respect to the standard one.

  17. Role of flame generated flow in the formation of tulip flame

    Energy Technology Data Exchange (ETDEWEB)

    Jeung, I.S.; Cho, K.K.; Jeong, K.S.


    The role of flame generated flow during the laminar 'tulip' flame formation in a long rectangular combustion vessel was examined by laser Doppler velocimeter measurement, high speed schlieren photographic flame visualization, and combustion vessel pressure measurement. Results of these investigations showed the transition of convex-shaped flame to concave-shaped tulip flame and interactions between the flame shape and flame generated flow in a confined geometry, and gave physical understanding of flow field formation of tulip flame. 15 references.

  18. Cladding tube manufacturing technology

    Energy Technology Data Exchange (ETDEWEB)

    Hahn, R. [Kraftwerk Union AG, Mulheim (Germany); Jeong, Y.H.; Baek, B.J.; Kim, K.H.; Kim, S.J.; Choi, B.K.; Kim, J.M. [Korea Atomic Energy Research Institute, Taejon (Korea, Republic of)


    This report gives an overview of the manufacturing routine of PWR cladding tubes. The routine essentially consists of a series of deformation and annealing processes which are necessary to transform the ingot geometry to tube dimensions. By changing shape, microstructure and structure-related properties are altered simultaneously. First, a short overview of the basics of that part of deformation geometry is given which is related to tube reducing operations. Then those processes of the manufacturing routine which change the microstructure are depicted, and the influence of certain process parameters on microstructure and material properties are shown. The influence of the resulting microstructure on material properties is not discussed in detail, since it is described in my previous report 'Alloy Development for High Burnup Cladding.' Because of their paramount importance still up to now, and because manufacturing data and their influence on properties for other alloys are not so well established or published, the descriptions are mostly related to Zry4 tube manufacturing, and are only in short for other alloys. (author). 9 refs., 46 figs.

  19. Experimental Evaluation of a Paraffin as Phase Change Material for Thermal Energy Storage in Laboratory Equipment and in a Shell-and-Tube Heat Exchanger

    Directory of Open Access Journals (Sweden)

    Jaume Gasia


    Full Text Available The thermal behavior of a commercial paraffin with a melting temperature of 58 °C is analyzed as a phase change material (PCM candidate for industrial waste heat recovery and domestic hot water applications. A full and complete characterization of this PCM is performed based on two different approaches: a laboratory characterization (mass range of milligrams and an analysis in a pilot plant (mass range of kilograms. In the laboratory characterization, its thermal and cycling stability, its health hazard as well as its phase change thermal range, enthalpy and specific heat are analyzed using a differential scanning calorimeter, thermogravimetric analysis, thermocycling and infrared spectroscopy. Laboratory analyses showed its suitability up to 80 °C and for 1200 cycles. In the pilot plant analysis, its thermal behavior was analyzed in a shell-and-tube heat exchanger under different heat transfer fluid mass flow rates in terms of temperature, power and energy rates. Results from the pilot plant analysis allowed understanding the different methods of heat transfer in real charging and discharging processes as well as the influence of the geometry of the tank on the energy transferred and required time for charging and discharging processes.

  20. Experiments in the EMRP project KEY-VOCs: Adsorption/desorption effects of VOCs in different tubing materials and preparation and analysis of a zero gas (United States)

    Englert, Jennifer; Claude, Anja; Kubistin, Dagmar; Tensing, Erasmus; Michl, Katja; Plass-Duelmer, Christian


    Atmospheric chemistry and composition are influenced by volatile organic compounds (VOCs) emitted from natural and anthropogenic sources. Due to their toxicity and their crucial role in ozone and aerosol formation VOCs impact air quality and climate change and high quality observations are demanded. The European Metrology Research Programme (EMRP) project KEY-VOCs has targeted the improvement of VOC measurement capabilities with the focus on VOCs relevant for indoor air as well as for air quality and climate monitoring programmes. One major uncertainty is the influence of surface effects of the measurement devices. By developing a test system the adsorption/desorption effects of certain VOCs can be systematically examined. Different tubing materials e.g. stainless steel and PFA were analysed with the oxygenated VOC methanol and results of these experiments will be presented. In air quality monitoring very low levels of VOCs have to be measured. Purified air or nitrogen is widely used as a zero gas to characterize measurement systems and procedures as well as for instrument calibration. A high quality zero gas is an important contributor to the quality of the measurements and generally achieved by using state-of-the-art purification technologies. The efficiency of several air purifiers was assessed and the results have been analysed.

  1. Explosive welding of a tube into a tube sheet

    Energy Technology Data Exchange (ETDEWEB)

    Green, Sheryll C. (London, OH); Linse, Vonne D. (Columbus, OH)


    A cartridge containing an explosive charge is placed within a tube assembled within a tube sheet. The charge is detonated through use of a detonator cord containing a minimum but effective amount of explosive material. The cord is contained inside a tubular shield throughout most of its length within the cartridge. A small length of the cord extends beyond the tubular shield to contact and detonate the explosive charge in its rear portion near the cartridge base. The cartridge base is provided of substantial mass and thickness in respect to side and front walls of the cartridge to minimize bulging beyond the rear face of the tube sheet. For remote activation an electrically activated detonator of higher charge density than the cord is attached to the cord at a location spaced from the tube sheet, cartridge and tube.

  2. Explosive welding of a tube into a tube sheet

    Energy Technology Data Exchange (ETDEWEB)

    Green, S.C.; Linse, V.D.


    A cartridge containing an explosive charge is placed within a tube assembled within a tube sheet. The charge is detonated through use of a detonator cord containing a minimum but effective amount of explosive material. The cord is contained inside a tubular shield throughout most of its length within the cartridge. A small length of the cord extends beyond the tublar shield to contact and detonate the explosive charge in its rear portion near the cartridge base. The cartridge base is provided of substantial mass and thickness in respect to side and front walls of the cartridge to minimize bulging beyond the rear face of the tube sheet. For remote activation an electrically activated detonator of higher charge density than the cord is attached to the cord at a location spaced from the tube sheet, cartridge and tube.

  3. TiO2/Mg(OH)2新型抗菌阻燃复合材料的研究%Research on New Antibacterial Flame Retardant TiO2/Mg(OH)2 Composite Material

    Institute of Scientific and Technical Information of China (English)

    李雪; 李艳平; 杨鹏飞; 孟波; 刘云义


    采用氨气鼓泡法制备TiO2/Mg(OH)2多功能复合材料,其中以钛酸正丁酯为前躯体,硝酸铵和九水硝酸铁为氮、铁掺杂源,利用水热法制备了氮、铁共掺杂TiO2粉体.通过XRD、FE-SEM、FT-IR、TG等手段对所制备样品进行了表征,结果表明:75℃条件下,通氨时间为1h,产品粒度分散均匀,二次粒径为0.69μm;产品形貌为六方片状;其(001)面与(101)面特征衍射峰的强度比值I001/I101为0.71;在322 ~ 396℃的分解失重为24.9%,最高吸热温度为376.2℃,技术指标符合氢氧化镁阻燃剂的使用要求;对罗丹明b溶液的光降解率为56.3%.%A new TiO2/Mg(OH)2 multifunctional composite material was prepared by ammonia bubbling process. Nitrogen and iron codoped TiO2 powder were obtained by the hydrothermal method using titanium tetrabutoxide as precursor and ammonium nitrate and Iron( Ⅲ) nitrate nonahydrate as nitrogen and I-ron source. The composite material was characterized by XRD, FE-SEM, FT-IR and TG. The results indicate that at 75 ℃, the particle size distribute uniformly (D50 = 0. 69 μm) with ammonia feeding time for lh. SEM analysis shows that the flake-like hexagonal product is of good dispersibility. XRD analysis indicates that it'sI(001)/I(101) =0. 71. TG-DTA analysis indicates that the water loss was 24. 9% of the total weight between 322℃ and 396℃ with the highest endothermic temperature at 376. 2℃. The quality of samples could satisfy the demand of flame retardants. The photodegradation rate of the Rhodamine b is 56.3%.

  4. Single-tube-genotyping of gastric cancer related SNPs by directly using whole blood and paper-dried blood as starting materials

    Institute of Scientific and Technical Information of China (English)

    Huan Huang; Ying Bu; Guo-Hua Zhou


    AIM: To demonstrate an inexpensive method for typing gastric cancer related single nucleotide polymorphisms (SNPs) using whole blood or paper-dried blood as starting materials.METHODS: PCR amplification is directly carried out from the whole blood or paper-dried blood sample without any DNA extraction step. Before PCR, a blood sample, four primers, and all of biological reagents necessary for PCR were added at a time; After PCR, the amplified products were directly separated by slab gel electrophoresis or microchip CE without any purification. SNP typing was performed by tetra-primer PCR with two inner primers specific to each allele and two outer primers defining the length of allele-specific amplicons. Genotypes were directly discriminated by the size of amplicons specific to each allele, thereby avoiding any post-PCR process.RESULTS: Using a special PCR buffer, inhibitory substances in blood (including the anticoagulant in blood) and filter paper were effectively suppressed;a "true" single-tube-genotyping is thus realized. We successfully determined genotypes IL-1B-511 and IL-1B-31 polymorphisms at the gene IL-1B by using whole-blood and paper-dried blood samples as starting materials respectively. The method is so sensitive that 0.5-1.0 μL of blood sample is enough to give a satisfactory typing results. The genotyping results were confirmed by RFLP-PCR using purified genome DNA,indicating that amplification specificity was not affected by inhibitory components (including coagulants) in blood or filter paper.CONCLUSION: Compared with SNP typing methods based on purified DNA, the proposed method is laborsaving, simple, inexpensive, and less cross-contaminated.It is promising to use this method to type other SNPs.

  5. Flames of Transformation

    DEFF Research Database (Denmark)

    Sørensen, Tim Flohr; Bille, Mikkel


    This paper explores the transformative power of fire, its fundamental ability to change material worlds and affect our experience of its materiality. The paper examines material transformations related to death as a means of illustrating the powerful property of fire as a materially destructive y...

  6. Mechanistic aspects of ionic reactions in flames

    DEFF Research Database (Denmark)

    Egsgaard, H.; Carlsen, L.


    Some fundamentals of the ion chemistry of flames are summarized. Mechanistic aspects of ionic reactions in flames have been studied using a VG PlasmaQuad, the ICP-system being substituted by a simple quartz burner. Simple hydrocarbon flames as well as sulfur-containing flames have been investigated....... The simple hydrocarbon flames are dominated by a series of hydrocarbonic ions and, to a minor extent, protonated oxo-compounds. The introduction of sulfur to the flames leads to significant changes in the ion composition, as sulfur-containing species become dominant. The ability of the technique to study...

  7. Nanotechnology finding its way into flame retardancy

    Energy Technology Data Exchange (ETDEWEB)

    Schartel, Bernhard, E-mail: [BAM Federal Institute for Materials Research and Testing, Unter den Eichen 87, 12205 Berlin (Germany)


    Nanotechnology is one of the key technologies of the 21{sup st} century. The exploitation of 'new' effects that arise from materials structured on the nano-scale has also been proposed successfully for flame retardancy of polymers since the end of the 90s. Of all of the approaches these include, at this time the use of nanocomposites offers the best potential for industrial application, also some other ideas are sketched, such as using electrospun nanofibers mats or layer-by-layer deposits as protection coatings, as well as sub-micrometer multilayer coatings as effective IR-mirrors. The general phenomena, inducing a flow limit in the pyrolysing melt and changing the fire residue, are identified in nanocomposites. Key experiments are performed such as quasi online investigation of the protection layer formation to understand what is going on in detail. The flame retardancy mechanisms are discussed and their impact on fire behaviour quantified. With the latter, the presentation pushes forward the state of the art. For instance, the heat shielding is experimentally quantified for a layered silicate epoxy resin nanocomposite proving that it is the only import mechanism controlling the reduction in peak heat release rate in the investigated system for different irradiations. The flame retardancy performance is assessed comprehensively illuminating not only the strengths but also the weak points of the concepts. Guidelines for materials development are deduced and discussed. Apart from inorganic fillers (layered silicate, boehmite, etc.) not only carbon nanoobjects such as multiwall carbon nanotubes, multilayer graphene and graphene are investigated, but also nanoparticles that are more reactive and harbor the potential for more beneficial interactions with the polymer matrix.

  8. Chest tube insertion (United States)

    ... tube insertion; Insertion of tube into chest; Tube thoracostomy; Pericardial drain ... Kirsch TD, Sax J. Tube thoracostomy. In: Roberts JR, ed. Roberts and ... . 6th ed. Philadelphia, PA: Elsevier Saunders; 2014:chap 10.

  9. Jejunostomy feeding tube (United States)

    ... page: // Jejunostomy feeding tube To use the sharing features on this ... vomiting Your child's stomach is bloated Alternate Names Feeding - jejunostomy tube; G-J tube; J-tube; Jejunum ...

  10. Diffusion Combustion in a Tube-Nested Combustor


    Tetsuji, Seko; Ryosuke, Matsumoto; Yoshitomo, Shintani; Isao, Ishihara; Mamoru, Ozawa


    An advanced-type compact water-tube boiler has been designed on the basis of the new concept of cooling flame by water-tube bank in the furnace, and is referred to as "tube-nested combustor". It realized drastic reduction in boiler size as well as in the NO_x emission. In this present study, aiming at further improvement of boiler efficiency and reduction of NO_x emission, the combustion characteristics in the furnace were investigated by using the test boiler of 0.5t/h steam output. Experime...

  11. Migration of Organophosphate Flame Retardants from Closed Cell Foam to Settled Dust (United States)

    Many industrial and consumer products, such as electrical and electronic products, furniture, plastics, textile, and building materials are manufactured with organophosphorus flame retardants (OPFRs). OPFRs can leach or diffuse out of the products and are released to the surround...

  12. Migration of Organophorus Flame Retardants From Closed cell form to Settled Dust (United States)

    Many industrial and consumer products, such as electrical and electronic products, furniture, plastics, textile, and building materials are manufactured with organophosphorus flame retardants (OPFRs). OPFRs can leach or diffuse out of the products and are released to the surround...

  13. Migration of Organophosphate Flame Retardants from Closed Cell Foam to Settled Dust (United States)

    Many industrial and consumer products, such as electrical and electronic products, furniture, plastics, textile, and building materials are manufactured with organophosphorus flame retardants (OPFRs). OPFRs can leach or diffuse out of the products and are released to the surround...

  14. Migration of Organophorus Flame Retardants From Closed cell form to Settled Dust (United States)

    Many industrial and consumer products, such as electrical and electronic products, furniture, plastics, textile, and building materials are manufactured with organophosphorus flame retardants (OPFRs). OPFRs can leach or diffuse out of the products and are released to the surround...

  15. Potent competitive interactions of some brominated flame retardants and related compounds with human transthyretin in vitro

    NARCIS (Netherlands)

    Meerts, I.A.T.M.; Zanden, van J.J.; Luijks, E.A.C.; Leeuwen-Bol, van I.; Marsh, G.; Jakobsson, E.; Bergman, A.; Brouwer, A.


    Brominated flame retardants such as polybrominated diphenyl ethers (PBDEs), pentabromophenol (PBP), and tetrabromobisphenol A (TBBPA) are produced in large quantities for use in electronic equipment, plastics, and building materials. Because these compounds have some structural resemblance to the th

  16. Alternatives Assessment: Partnership to Evaluate Flame Retardants in Printed Circuit Boards (United States)

    The partnership project on flame retardants in printed circuit boards seeks to improve understanding of the environmental and human health impacts of new and current materials that can be used to meet fire safety standards

  17. Hybrid endotracheal tubes (United States)

    Sakezles, Christopher Thomas

    Intubation involves the placement of a tube into the tracheal lumen and is prescribed in any setting in which the airway must be stabilized or the patient anesthetized. The purpose of the endotracheal tube in these procedures is to maintain a viable airway, facilitate mechanical ventilation, allow the administration of anesthetics, and prevent the reflux of vomitus into the lungs. In order to satisfy these requirements a nearly airtight seal must be maintained between the tube and the tracheal lining. Most conventional endotracheal tubes provide this seal by employing a cuff that is inflated once the tube is in place. However, the design of this cuff and properties of the material are a source of irritation and injury to the tracheal tissues. In fact, the complication rate for endotracheal intubation is reported to be between 10 and 60%, with manifestations ranging from severe sore throat to erosion through the tracheal wall. These complications are caused by a combination of the materials employed and the forces exerted by the cuff on the tracheal tissues. In particular, the abrasive action of the cuff shears cells from the lining, epithelium adhering to the cuff is removed during extubation, and normal forces exerted on the basement tissues disrupt the blood supply and cause pressure necrosis. The complications associated with tracheal intubation may be reduced or eliminated by employing airway devices constructed from hydrogel materials. Hydrogels are a class of crosslinked polymers which swell in the presence of moisture, and may contain more than 95% water by weight. For the current study, several prototype airway devices were constructed from hydrogel materials including poly(vinyl alcohol), poly(hydroxyethyl methacrylate), and poly(vinyl pyrrolidone). The raw hydrogel materials from this group were subjected to tensile, swelling, and biocompatibility testing, while the finished devices were subjected to extensive mechanical simulation and animal trials

  18. Research on flame retardation of wool fibers

    Energy Technology Data Exchange (ETDEWEB)

    Enomoto, Ichiro; Ametani, Kazuo; Sawai, Takeshi (Tokyo Metropolitan Isotope Research Center (Japan))


    Flame retardant, vinyl phosphonate oligomer, was uniformly impregnated in wool fibers, and by irradiating low energy electron beam or cobalt-60 gamma ray, the flame retardation of fabrics was attempted, as the results, the following knowledges were obtained. At the rate of sticking of flame retardant lower than that in cotton fabrics, sufficient flame retarding property can be given. The flame retarding property withstands 30 times of washing. The lowering of strength due to the processing hardly arose. For the flame retardation, gamma-ray was more effective than electron beam. Since the accidents of burning clothes have occurred frequently, their flame retardation has been demanded. So far the flame retardation of cotton fabrics has been advanced, but this time the research on the flame retardation of wool fabrics was carried out by the same method. The experimental method is explained. As for the performance of the processed fabrics, the rate of sticking of the flame retardant, the efficiency of utilization, the flame retarding property, the endurance in washing and the tensile and tearing strength were examined. As the oxygen index was higher, the flame retarding property was higher, and in the case of the index being more than 27, the flame retarding property is sufficient, that is, the rate of sticking of 6% in serge and 5% in muslin. (K.I.).

  19. Probing the dynamics of nanoparticle growth in a flame using synchrotron radiation. (United States)

    Beaucage, Gregory; Kammler, Hendrik K; Mueller, Roger; Strobel, Reto; Agashe, Nikhil; Pratsinis, Sotiris E; Narayanan, Theyencheri


    Flame synthesis is one of the most versatile and promising technologies for large-scale production of nanoscale materials. Pyrolysis has recently been shown to be a useful route for the production of single-walled nanotubes, quantum dots and a wide variety of nanostructured ceramic oxides for catalysis and electrochemical applications. An understanding of the mechanisms of nanostructural growth in flames has been hampered by a lack of direct observations of particle growth, owing to high temperatures (2,000 K), rapid kinetics (submillisecond scale), dilute growth conditions (10(-6) volume fraction) and optical emission of synthetic flames. Here we report the first successful in situ study of nanoparticle growth in a flame using synchrotron X-ray scattering. The results indicate that simple growth models, first derived for colloidal synthesis, can be used to facilitate our understanding of flame synthesis. Further, the results indicate the feasibility of studies of nanometre-scale aerosols of toxicological and environmental concern.

  20. Fuel effects on the stability of turbulent flames with compositionally inhomogeneous inlets

    KAUST Repository

    Guiberti, T. F.


    This paper reports an analysis of the influence of fuels on the stabilization of turbulent piloted jet flames with inhomogeneous inlets. The burner is identical to that used earlier by the Sydney Group and employs two concentric tubes within the pilot stream. The inner tube, carrying fuel, can be recessed, leading to a varying degree of inhomogeneity in mixing with the outer air stream. Three fuels are tested: dimethyl ether (DME), liquefied petroleum gas (LPG), and compressed natural gas (CNG). It is found that improvement in flame stability at the optimal compositional inhomogeneity is highest for CNG and lowest for DME. Three possible reasons for this different enhancement in stability are investigated: mixing patterns, pilot effects, and fuel chemistry. Numerical simulations realized in the injection tube highlight similarities and differences in the mixing patterns for all three fuels and demonstrate that mixing cannot explain the different stability gains. Changing the heat release rates from the pilot affects the three fuels in similar ways and this also implies that the pilot stream is unlikely to be responsible for the observed differences. Fuel reactivity is identified as a key factor in enhancing stability at some optimal compositional inhomogeneity. This is confirmed by inference from joint images of PLIF-OH and PLIF-CHO, collected at a repetition rate of 10kHz in turbulent flames of DME, and from one-dimensional calculations of laminar flames using detailed chemistry for DME, CNG, and LPG.

  1. Role of the outer-edge flame on flame extinction in nitrogen-diluted non-premixed counterflow flames with finite burner diameters

    KAUST Repository

    Chung, Yong Ho


    This study of nitrogen-diluted non-premixed counterflow flames with finite burner diameters investigates the important role of the outer-edge flame on flame extinction through experimental and numerical analyses. It explores flame stability diagrams mapping the flame extinction response of nitrogen-diluted non-premixed counterflow flames to varying global strain rates in terms of burner diameter, burner gap, and velocity ratio. A critical nitrogen mole fraction exists beyond which the flame cannot be sustained; the critical nitrogen mole fraction versus global strain rate curves have C-shapes for various burner diameters, burner gaps, and velocity ratios. At sufficiently high strain-rate flames, these curves collapse into one curve; therefore, the flames follow the one-dimensional flame response of a typical diffusion flame. Low strain-rate flames are significantly affected by radial conductive heat loss, and therefore flame length. Three flame extinction modes are identified: flame extinction through shrinkage of the outer-edge flame with or without oscillations at the outer-edge flame prior to the extinction, and flame extinction through a flame hole at the flame center. The extinction modes are significantly affected by the behavior of the outer-edge flame. Detailed explanations are provided based on the measured flame-surface temperature and numerical evaluation of the fractional contribution of each term in the energy equation. Radial conductive heat loss at the flame edge to ambience is the main mechanism of extinction through shrinkage of the outer-edge flame in low strain-rate flames. Reduction of the burner diameter can extend the flame extinction mode by shrinking the outer-edge flame in higher strain-rate flames. © 2012 Elsevier Ltd. All rights reserved.

  2. Enhancement of turbulent flame speed of V-shaped flames in fractal-grid-generated turbulence

    NARCIS (Netherlands)

    Verbeek, A.A.; Willems, P.A.; Stoffels, G.G.M.; Geurts, B.J.; Meer, van der T.H.


    A variety of fractal grids is used to investigate how fractal-grid-generated turbulence affects the turbulent flame speed for premixed flames. The grids are placed inside a rectangular duct and a V-shaped flame is stabilized downstream of the duct, using a metal wire. This flame is characterized usi

  3. 33 CFR 154.822 - Detonation arresters, flame arresters, and flame screens. (United States)


    ... 33 Navigation and Navigable Waters 2 2010-07-01 2010-07-01 false Detonation arresters, flame arresters, and flame screens. 154.822 Section 154.822 Navigation and Navigable Waters COAST GUARD... BULK Vapor Control Systems § 154.822 Detonation arresters, flame arresters, and flame screens. (a)...

  4. Time-resolved PIV investigation of flashback in stratified swirl flames of hydrogen-rich fuel (United States)

    Ranjan, Rakesh; Clemens, Noel


    Hydrogen is one of the promising alternative fuels to achieve greener power generation. However, susceptibility of flashback in swirl flames of hydrogen-rich fuels acts as a major barrier to its adoption in gas turbine combustors. The current study seeks to understand the flow-flame interaction during the flashback of the hydrogen-rich flame in stratified conditions. Flashback experiments are conducted with a model combustor equipped with an axial swirler and a center-body. Fuel is injected in the main swirl flow via the fuel ports on the swirler vanes. To achieve mean radial stratification, these fuel ports are located at a radial location closer to the outer wall of the mixing tube. Stratification in the flow is assessed by employing Anisole PLIF imaging. Flashback is triggered by a rapid increase in the global equivalence ratio. The upstream propagation of the flame is investigated by employing time-resolved stereoscopic PIV and chemiluminescence imaging. Stratification leads to substantially different flame propagation behavior as well as increased flame surface wrinkling. We gratefully acknowledge the sponsorship by the DOE NETL under Grant DEFC2611-FE0007107.

  5. Effect of burner geometry on swirl stabilized methane/air flames: A joint LES/OH-PLIF/PIV study

    KAUST Repository

    Liu, X.


    Large eddy simulation (LES) using a transported PDF model and OH-PLIF/PIV experiments were carried out to investigate the quarl effects on the structures of swirl stabilized methane/air flames. Two different quarls were investigated, one straight cylindrical quarl and one diverging conical quarl. The experiments show that the flames are significantly different with the two quarls. With the straight cylindrical quarl a compact blue flame is observed while with the diverging conical quarl the flame appears to be long and yellow indicating a sooty flame structure. The PIV results show the formation of a stronger flow recirculation inside the diverging conical quarl than that in the straight quarl. LES results reveal further details of the flow and mixing process inside the quarl. The results show that with the diverging quarl vortex breakdown occurs much earlier towards the upstream of the quarl. As a result the fuel is convected into the air flow tube and a diffusion flame is stabilized inside the air flow tube upstream the quarl. With the straight quarl, vortex breakdown occurs at a downstream location in the quarl. The scalar dissipation rate in the shear layer of the fuel jet is high, which prevents the stabilization of a diffusion flame in the proximity of the fuel nozzle; instead, a compact partially premixed flame with two distinct heat release layers is stablized in a downstream region in the quarl, which allows for the fuel and air to mix in the quarl before combustion and a lower formation rate of soot. The results showed that the Eulerian Stochastic Fields transported PDF method can well predict the details of the swirl flame dynamics.

  6. Asymptotic analysis of outwardly propagating spherical flames

    Institute of Scientific and Technical Information of China (English)

    Yun-Chao Wu; Zheng Chen


    Asymptotic analysis is conducted for outwardly propagating spherical flames with large activation energy.The spherical flame structure consists of the preheat zone,reaction zone,and equilibrium zone.Analytical solutions are separately obtained in these three zones and then asymptotically matched.In the asymptotic analysis,we derive a correlation describing the spherical flame temperature and propagation speed changing with the flame radius.This correlation is compared with previous results derived in the limit of infinite value of activation energy.Based on this correlation,the properties of spherical flame propagation are investigated and the effects of Lewis number on spherical flame propagation speed and extinction stretch rate are assessed.Moreover,the accuracy and performance of different models used in the spherical flame method are examined.It is found that in order to get accurate laminar flame speed and Markstein length,non-linear models should be used.

  7. Flame Retardants Used in Flexible Polyurethane Foam (United States)

    The partnership project on flame retardants in furniture seeks to update the health and environmental profiles of flame-retardant chemicals that meet fire safety standards for upholstered consumer products with polyurethane foam

  8. Influence of electromagnetism field on the flame transmission and shock wave in gas explosion

    Energy Technology Data Exchange (ETDEWEB)

    Li Jing [Anhui University of Technology, Maanshan (China). College of Metallurgy and Resources


    The influence of electromagnetic field on flame transmission and explosion wave overpressure in gas explosions was investigated. The research results show that the velocity of flame propagation and the explosion wave overpressure in an electromagnetic field is much higher than that in plain tube, and the stronger the electromagnetic field, the greater the influence. Based on experimental results, the influence of electromagnetic field on gas explosion propagation was analyzed and a reasonable explanation was put forward. The influence of electromagnetic field is not equal to the sum of the electric field and the magnetic field. 7 refs., 4 figs., 2 tabs.

  9. Preparation of Nano-titanium Dioxide in Propane/Air Diffusion Flame

    Institute of Scientific and Technical Information of China (English)

    ZHANG Wei; SUN Xue; XIE Hongyong


    Titanium dioxide (TiO2) nanoparticles were synthesized by the oxidation of titanium tetrachloride (TiCl4), in propane/air diffusion flame. The propane/air diffusion flame is generated using a multi-port diffusion type burner composed of 4 concentric tubes. Flow rates of TiCl4 and combustion gases such as air, industrial propane and carrier gas were chosen as key experimental variables for the control of the particle size and morphology. Effects of propane/air mole ratio and precursor flow rate on particle size, morphology, structure and carbon dots of titanium dioxide particles were studied.

  10. Microgravity flame spread over thick solids in low velocity opposed flow (United States)

    Wang, Shuangfeng; Zhu, Feng


    Motivated primarily by fire safety of spacecraft, a renewed interest in microgravity flame spread over solid materials has arisen. With few exceptions, however, research on microgravity flame spread has been focused on thermally thin fuels due to the constraint on available test time. In this study, two sets of experiments are conducted to examine the flame spread and extinction behavior over thick PMMA in simulated and actual microgravity environments. The low-gravity flame spread environment is produced by a narrow channel apparatus in normal gravity. Extinction limits using flow velocity and oxygen concentration as coordinates are presented, and flame spread rates are determined as a function of the velocity and oxygen concentration of the gas flow. The microgravity experiments are also performed with varying low-velocity flow and varying ambient oxygen concentration. The important observations include flame behavior and appearance as a function of oxygen concentration and flow velocity, temperature variation in gas and solid phases, and flame spread rate. A comparison between simulated and actual microgravity data is made, and general agreement is found. Based on the experimental observations, mechanisms for flame spread and extinction in low velocity opposed flows are discussed.

  11. Feature of high velocity oxygen-fuel flame spraying; Kosoku flame yoshaho no tokucho to sono oyo

    Energy Technology Data Exchange (ETDEWEB)

    Shimizu, Y.; Sakaki, K. [Shinshu University, Nagano (Japan). Faculty of Engineering


    A description is given about the high velocity flame spraying method. In this method, fuel and oxygen under high pressure are supplied to a spraying gun, a supersonic stream of flame is jetted out of a fine nozzle, and spray particles are injected into the flame to impinge on the substrate surface at a very high speed for the formation of a coating. This method is advantageous in that the spray particles are higher in flying speed than in other spraying methods, that the produced coating is dense and close and excellent in adhesion, that the flame temperature is relatively low, and that the spray material is suppressed in terms of phase transformation, oxidation, and decomposition. This spraying technique is disadvantageous in that the spray materials that it can use are limited in variety because this method meets difficulties in spraying upon high melting-point metal or ceramics. This paper also outlines the spraying devices (chamber combustion type and throat combustion type) and the characteristics of produced coatings, and spray materials and their application (centering about carbide thermit spraying) are mentioned. 23 refs., 6 figs., 2 tabs.

  12. Microgravity Flame Spread in Exploration Atmospheres: Pressure, Oxygen, and Velocity Effects on Opposed and Concurrent Flame Spread (United States)

    Olson, Sandra L.; Ruff, Gary A.; Fletcher, J. Miller


    Microgravity tests of flammability and flame spread were performed in a low-speed flow tunnel to simulate spacecraft ventilation flows. Three thin fuels were tested for flammability (Ultem 1000 (General Electric Company), 10 mil film, Nomex (Dupont) HT90-40, and Mylar G (Dupont) and one fuel for flame spread testing (Kimwipes (Kimberly-Clark Worldwide, Inc.). The 1g Upward Limiting Oxygen Index (ULOI) and 1g Maximum Oxygen Concentration (MOC) are found to be greater than those in 0g, by up to 4% oxygen mole fraction, meaning that the fuels burned in 0g at lower oxygen concentrations than they did using the NASA Standard 6001 Test 1 protocol. Flame spread tests with Kimwipes were used to develop correlations that capture the effects of flow velocity, oxygen concentration, and pressure on flame spread rate. These correlations were used to determine that over virtually the entire range of spacecraft atmospheres and flow conditions, the opposed spread is faster, especially for normoxic atmospheres. The correlations were also compared with 1g MOC for various materials as a function of pressure and oxygen. The lines of constant opposed flow agreed best with the 1g MOC trends, which indicates that Test 1 limits are essentially dictated by the critical heat flux for ignition. Further evaluation of these and other materials is continuing to better understand the 0g flammability of materials and its effect on the oxygen margin of safety.

  13. Firefighters and flame retardant activism. (United States)

    Cordner, Alissa; Rodgers, Kathryn M; Brown, Phil; Morello-Frosch, Rachel


    In the past decade, exposure to flame retardant chemicals has become a pressing health concern and widely discussed topic of public safety for firefighters in the United States. Working through local, state, and national unions and independent health and advocacy organizations, firefighters have made important contributions to efforts to restrict the use of certain flame retardants. Firefighters are key members in advocacy coalitions dedicated to developing new environmental health regulations and reforming flammability standards to reflect the best available fire science. Their involvement has been motivated by substantiated health concerns and critiques of deceptive lobbying practices by the chemical industry. Drawing on observations and interviews with firefighters, fire safety experts, and other involved stakeholders, this article describes why firefighters are increasingly concerned about their exposure to flame retardant chemicals in consumer products, and analyzes their involvement in state and national environmental health coalitions.

  14. An Overview of Mode of Action and Analytical Methods for Evaluation of Gas Phase Activities of Flame Retardants

    Directory of Open Access Journals (Sweden)

    Khalifah A. Salmeia


    Full Text Available The latest techniques used to prove, describe and analyze the gas phase activity of a fire retardant used in polymeric materials are briefly reviewed. Classical techniques, such as thermogravimetric analysis or microscale combustion calorimetry, as well as complex and advanced analytical techniques, such as modified microscale combustion calorimeter (MCC, molecular beam mass spectroscopy and vacuum ultra violet (VUV photoionization spectroscopy coupled with time of flight MS (TOF-MS, are described in this review. The recent advances in analytical techniques help not only in determining the gas phase activity of the flame-retardants but also identify possible reactive species responsible for gas phase flame inhibition. The complete understanding of the decomposition pathways and the flame retardant activity of a flame retardant system is essential for the development of new eco-friendly-tailored flame retardant molecules with high flame retardant efficiency.

  15. Droplet and Supercritical Flame Dynamics in Propulsion (United States)


    In order to study the stability of a lifted jet flame by nozzle-generated vortexes, we have developed a chemical explosive mode analysis ( CEMA ) to...runaway can consequently be distinguished. CEMA of the lifted flame shows the existence of two premixed flame fronts, which are difficult to detect

  16. 30 CFR 14.20 - Flame resistance. (United States)


    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Flame resistance. 14.20 Section 14.20 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR TESTING, EVALUATION, AND APPROVAL OF... § 14.20 Flame resistance. Conveyor belts for use in underground coal mines must be flame-resistant...

  17. Acoustic power measurements of oscillating flames

    NARCIS (Netherlands)

    Valk, M.


    The acoustic power of an oscillating flame is measured. A turbulent premixed propane/air flame is situated near a pressure antinode of a standing wave in a laboratory combustion chamber. This standing wave is generated by a piston. The fluctuating heat release of the flame will supply acoustic power

  18. Hysteresis and transition in swirling nonpremixed flames

    NARCIS (Netherlands)

    Tummers, M.J.; Hübner, A.W.; Veen, van E.H.; Hanjalic, K.; Meer, van der Th.H.


    Strongly swirling nonpremixed flames are known to exhibit a hysteresis when transiting from an attached long, sooty, yellow flame to a short lifted blue flame, and vice versa. The upward transition (by increasing the air and fuel flow rates) corresponds to a vortex breakdown, i.e. an abrupt change f

  19. Acoustic power measurements of oscillating flames

    NARCIS (Netherlands)

    Valk, M.


    The acoustic power of an oscillating flame is measured. A turbulent premixed propane/air flame is situated near a pressure antinode of a standing wave in a laboratory combustion chamber. This standing wave is generated by a piston. The fluctuating heat release of the flame will supply acoustic power

  20. Environmental Considerations for Flame Resistant Textiles (United States)

    Virtually all common textiles will ignite and burn. There are mandatory and voluntary cigarette and open-flame ignition regulations to address unreasonable fire risks associated with textile products that require them to be treated with and/or contain flame retardant chemicals to make them flame res...

  1. Shock Tube/Laser Absorption Studies of Jet Fuels at Low Temperatures (600-1200K) (United States)


    measurements of methane, ethylene and carbon monoxide time-histories in DME pyrolysis, Combustion and Flame, (04 2013): 747. doi: 10.1016...Davidson and R.K. Hanson, “Shock Tube Measurements of Methane, Ethylene and Carbon Monoxide Time-Histories in DME Pyrolysis,” Combustion and Flame 160...Table 1 Previous experimental studies of pyrolysis of decalin Refs. Cis- or trans-decalin? T (K) P (atm) Product distribution? [19] cis- 973

  2. Cars Spectroscopy of Propellant Flames (United States)


    Harris, K. Aron, and J. Fendell "N2 and 00 Vibrational CARS and H2 Rotational CARS Spectroscopy of CHI/N20 Flames," Proceedings of the Nineteenth...JANNAF Combustion Meeting, CIIA Publication No. 366, 1982, p 123. 21. K. Aron, L. E. Harris, and J. Fendell , "N and CO Vibrational CARS and H2 Rotational...9 6 5 . p 3 8 4 . . . . . 23. J. Fendell , L. E, Harris, and K. Aron, "Theoretical Calculation of 11 CARS S-Branches for Propellant Flames

  3. Experimental characterization of methane inverse diffusion flame

    KAUST Repository

    Elbaz, Ayman M.


    This article presents 10-kHz images of OH-PLIF simultaneously with 2-D PIV measurements in an inverse methane diffusion flame. Under a constant fuel flow rate, the central air jet Re was varied, leading to air to fuel velocity ratio, Vr, to vary from 8.3 to 66.5. Starting from Vr = 20.7, the flame is commonly characterized by three distinct zones. The length of the lower fuel entrainment region is inversely proportional to Vr. The flames investigated resemble a string shear layer confining this zone, and converging into the second distinct region, the flame neck zone. The third region is the rest of the flame, which spreads in a jet-like manner. The inverse diffusion flames exhibit varying degrees of partial premixing, depending upon on the velocity ratio Vr, and this region of partial premixing evolves into a well-mixed reaction zone along the flame centerline. The OH distribution correlated with the changes in the mean characteristics of the flow through reduction in the local Reynolds number due to heat release. The existence of a flame suppresses or laminarizes the turbulence at early axial locations and promotes fluctuations at the flame tip for flames with Vr < 49.8. In addition, the flame jet width can be correlated to the OH distribution. In upstream regions of the flames, the breaks in OH are counterbalanced by flame closures and are governed by edge flame propagation. These local extinctions were found to occur at locations where large flow structures were impinging on the flame and are associated with a locally higher strain rate or correlated to the local high strain rates at the flame hole edges without this flow impinging. Another contributor to re-ignition was found to be growing flame kernels. As the flames approach global blow-off, these kernels become the main mechanism for re-ignition further downstream of the flames. At low Vr, laminarization within the early regions of the flame provides an effective shield, preventing the jet flow from

  4. Effects of pressure, oxygen concentration, and forced convection on flame spread rate of Plexiglas, Nylon and Teflon (United States)

    Notardonato, J. J.; Burkhardt, L. A.; Cochran, T. H.


    Experiments were conducted in which the burning of cylindrical materials in a flowing oxidant stream was studied. Plexiglas, Nylon, and Teflon fuel specimens were oriented such that the flames spread along the surface in a direction opposed to flowing gas. Correlations of flame spread rate were obtained that were power law relations in terms of pressure, oxygen concentration, and gas velocity.

  5. Two-Nozzle Flame Spray Pyrolysis (FSP) Synthesis of CoMo/Al2O3 Hydrotreating Catalysts

    DEFF Research Database (Denmark)

    Høj, Martin; Pham, David K.; Brorson, Michael


    Two-nozzle frame spray analysis (FSP) synthesis of CoMo/Al2O3 where Co and Al are sprayed in separate flames was applied to minimize the formation of CoAl2O4 observed in one-nozzle flame spray pyrolysis (FSP) synthesis and the materials were characterized by N2-adsorption (BET), X-ray diffraction...

  6. Aluminum hypophosphite microencapsulated to improve its safety and application to flame retardant polyamide 6

    Energy Technology Data Exchange (ETDEWEB)

    Ge, Hua [State Key Laboratory of Fire Science, University of Science and Technology of China, 96 Jinzhai Road, Hefei, Anhui 230026 (China); Tang, Gang [School of Architecture and Civil Engineering, Anhui University of Technology, 59 Hudong Road, Ma’anshan, Anhui 243002 (China); Hu, Wei-Zhao; Wang, Bi-Bo; Pan, Ying [State Key Laboratory of Fire Science, University of Science and Technology of China, 96 Jinzhai Road, Hefei, Anhui 230026 (China); Song, Lei, E-mail: [State Key Laboratory of Fire Science, University of Science and Technology of China, 96 Jinzhai Road, Hefei, Anhui 230026 (China); Hu, Yuan, E-mail: [State Key Laboratory of Fire Science, University of Science and Technology of China, 96 Jinzhai Road, Hefei, Anhui 230026 (China); Suzhou Key Laboratory of Urban Public Safety, Suzhou Institute for Advanced Study, University of Science and Technology of China, 166 Ren’ai Road, Suzhou, Jiangsu 215123 (China)


    Highlights: • MCAHP was prepared and applied in polyamide 6. • MCA as the capsule material can improve the fire safety of AHP. • Flame retardant polyamide 6 composites with MCAHP show good flame retardancy. - Abstract: Aluminum hypophosphite (AHP) is an effective phosphorus-containing flame retardant. But AHP also has fire risk that it will decompose and release phosphine which is spontaneously flammable in air and even can form explosive mixtures with air in extreme cases. In this paper, AHP has been microencapsulated by melamine cyanurate (MCA) to prepare microencapsulated aluminum hypophosphite (MCAHP) with the aim of enhancing the fire safety in the procedure of production, storage and use. Meanwhile, MCA was a nitrogen-containing flame retardant that can work with AHP via the nitrogen-phosphorus synergistic effect to show improved flame-retardant property than other capsule materials. After microencapsulation, MCA presented as a protection layer inhibit the degradation of AHP and postpone the generation of phosphine. Furthermore, the phosphine concentration could be effectively diluted by inert decomposition products of MCA. These nonflammable decomposition products of MCA could separate phosphine from air delay the oxidizing reaction with oxygen and decrease the heat release rate, which imply that the fire safety of AHP has been improved. Furthermore, MCAHP was added into polyamide 6 to prepare flame retardant polyamide 6 composites (FR-PA6) which show good flame retardancy.

  7. A tube-in-tube thermophotovoltaic generator

    Energy Technology Data Exchange (ETDEWEB)

    Ashcroft, J.; Campbell, B.; Depoy, D.


    A thermophotovoltaic device includes at least one thermal radiator tube, a cooling tube concentrically disposed within each thermal radiator tube and an array of thermophotovoltaic cells disposed on the exterior surface of the cooling tube. A shell having a first end and a second end surrounds the thermal radiator tube. Inner and outer tubesheets, each having an aperture corresponding to each cooling tube, are located at each end of the shell. The thermal radiator tube extends within the shell between the inner tubesheets. The cooling tube extends within the shell through the corresponding apertures of the two inner tubesheets to the corresponding apertures of the two outer tubesheets. A plurality of the thermal radiator tubes can be arranged in a staggered or an in-line configuration within the shell.

  8. Imaging Invisible Flames Without Additives (United States)

    Weiland, Karen J.


    Image intensifiers, video cameras, and image-data-processing computers used to study combustion. Possible to view and analyze methane, hydrogen, and other flames dim or invisible to human eye and difficult to image by use of conventional photographic and video cameras.

  9. Olympic Flame Burning In Athens

    Institute of Scientific and Technical Information of China (English)


    <正>At 6:00pm March 25 (Beijing time), 2004 Athens Olympic flame was lit in Greece’s ancient sanctuary, indicating that the torch relay started.The torch relay, established at the Berlin Games in 1936, will for the first time visit all five continents

  10. The VLT FLAMES Tarantula Survey

    NARCIS (Netherlands)

    Evans, C.; Taylor, W.; Sana, H.; Hénault-Brunet, V.; Bagnoli, T.; Bastian, N.; Bestenlehner, J.; Bonanos, A.; Bressert, E.; Brott, I.; Campbell, M.; Cantiello, M.; Carraro, G.; Clark, S.; Costa, E.; Crowther, P.; de Koter, A.; de Mink, S.; Doran, E.; Dufton, P.; Dunstall, P.; Garcia, M.; Gieles, M.; Gräfener, G.; Herrero, A.; Howarth, I.; Izzard, R.; Köhler, K.; Langer, N.; Lennon, D.; Maíz Apellániz, J.; Markova, N.; Najarro, P.; Puls, J.; Ramirez, O.; Sabín-Sanjulián, C.; Simón-Díaz, S.; Smartt, S.; Stroud, V.; van Loon, J.; Vink, J.S.; Walborn, N.


    We introduce the VLT FLAMES Tarantula Survey, an ESO Large Programme from which we have obtained optical spectroscopy of over 800 massive stars in the spectacular 30 Doradus region of the Large Magellanic Cloud. A key feature is the use of multi-epoch observations to provide strong constraints on

  11. Flame monitoring enhances burner management

    Energy Technology Data Exchange (ETDEWEB)

    Flynn, T.; Bailey, R.; Fuller, T.; Daw, S.; Finney, C.; Stallings, J. [Babcock & Wilcox Research Center (USA)


    A new burner monitoring and diagnostic system called Flame Doctor offers users a more precise and discriminating understanding of burner conditions. Alpha testing on Unit 4 at AmerenUE's Meramec power plant in St. Louis, MO, USA and Beta testing is underway at plants owned by Dynegy and Allegheny Energy. 6 refs., 3 figs.

  12. Enhancements of Impinging Flame by Pulsation

    Institute of Scientific and Technical Information of China (English)

    AySu; Ying-ChiehLiu


    Experimental investigations on the pulsating jet-impinging diffusion flame were executed.A soleoid valve was aligned upstream of the jet orifice and the methane fuel was controlled in open-closed cycles from 0 Hz to 20Hz.Results show that the open-closed cycles,indeed increase the fluctuations of the methane fuel obviously.The evolutions of pulsating flame therefore develop faster than the continuous impinging flame.The optimized pulating frequencies are near 9 to 11 hz from the Re=170 to 283.The temperature differences between that under optimized pulsating rate and full open condition(no pulsation)are ranging from 100 to 150 degree.The pulsating effect is more singnificant at low Reynolds number.The cross section of continuous impinging flame behaves as elliptic shape with axial ratio equals to 2/3.The tip of the impinging flame obviously crosses at 42mm above the impinging point.ecause of the phenomenon of pulsation flame,the flame sheet or flame front may not be identified clearly in the averaged temperature contours.Results shows that the averaged end-contour of pulsation flame rears at 38mm above the impinging point.By observation and experiment,the pulsating flame behaves more stable and efficient than the continuous impinging flame.

  13. Turbulent Oxygen Flames in Type Ia Supernovae

    CERN Document Server

    Aspden, A J; Woosley, S E; 10.1088/0004-637X/730/2/144


    In previous studies, we examined turbulence-flame interactions in carbon-burning thermonuclear flames in Type Ia supernovae. In this study, we consider turbulence-flame interactions in the trailing oxygen flames. The two aims of the paper are to examine the response of the inductive oxygen flame to intense levels of turbulence, and to explore the possibility of transition to detonation in the oxygen flame. Scaling arguments analogous to the carbon flames are presented and then compared against three-dimensional simulations for a range of Damk\\"ohler numbers ($\\Da_{16}$) at a fixed Karlovitz number. The simulations suggest that turbulence does not significantly affect the oxygen flame when $\\Da_{16}1$, turbulence enhances heat transfer and drives the propagation of a flame that is {\\em narrower} than the corresponding inductive flame would be. Furthermore, burning under these conditions appears to occur as part of a combined carbon-oxygen turbulent flame with complex compound structure. The simulations do not ...

  14. Sooting limit of a double diffusion flame

    Energy Technology Data Exchange (ETDEWEB)

    Kitano, Michio; Kobayashi, Hideaki; Nishiki, Nobuhiko (Tohoku Univ., Faculty of Engineering, Sendai, Japan Sony Corp., Tokyo (Japan))


    The soot exhaust from the flame of pot type burner for the domestic heating use was basically studied. Inside a fuel (secondary) diffusion flame in air atmosphere, which was an ordinary diffusion flame, an air (primary) diffusion flame in fuel atmosphere, which was reverse in relation between them, was formed by using propane fuel. For the sooting limit of that double diffusion flame, the effect of primary air ratio, distance between primary and secondary flames, thermal condition on wall surface and flow stretch being investigated by use of three different types of burner, the double diffusion flame method was studied in effectiveness on the soot exhaust and known to heighten the control against it, which heightening however depended in degree upon the locative relation between both the flames. The control was more heightened with a more lengthening in the secondary flame. Because the sooting limit is governed by the secondary flame temperature, the establishment of condition so as to heighten the flame temperature is necessary for the effective control against the soot exhaust. 11 refs., 11 figs.

  15. Flame Reconstruction Using Synthetic Aperture Imaging

    CERN Document Server

    Murray, Preston; Tree, Dale; Truscott, Tadd


    Flames can be formed by burning methane (CH4). When oxygen is scarce, carbon particles nucleate into solid particles called soot. These particles emit photons, making the flame yellow. Later, methane is pre-mixed with air forming a blue flame; burning more efficiently, providing less soot and light. Imaging flames and knowing their temperature are vital to maximizing efficiency and validating numerical models. Most temperature probes disrupt the flame and create differences leading to an inaccurate measurement of the flame temperature. We seek to image the flame in three dimensions using synthetic aperture imaging. This technique has already successfully measured velocity fields of a vortex ring [1]. Synthetic aperture imaging is a technique that views one scene from multiple cameras set at different angles, allowing some cameras to view objects that are obscured by others. As the resulting images are overlapped different depths of the scene come into and out of focus, known as focal planes, similar to tomogr...

  16. Flex-flame burner and combustion method (United States)

    Soupos, Vasilios; Zelepouga, Serguei; Rue, David M.; Abbasi, Hamid A.


    A combustion method and apparatus which produce a hybrid flame for heating metals and metal alloys, which hybrid flame has the characteristic of having an oxidant-lean portion proximate the metal or metal alloy and having an oxidant-rich portion disposed above the oxidant lean portion. This hybrid flame is produced by introducing fuel and primary combustion oxidant into the furnace chamber containing the metal or metal alloy in a substoichiometric ratio to produce a fuel-rich flame and by introducing a secondary combustion oxidant into the furnace chamber above the fuel-rich flame in a manner whereby mixing of the secondary combustion oxidant with the fuel-rich flame is delayed for a portion of the length of the flame.

  17. A flame particle tracking analysis of turbulence–chemistry interaction in hydrogen–air premixed flames

    KAUST Repository

    Uranakara, Harshavardhana A.


    Interactions of turbulence, molecular transport, and energy transport, coupled with chemistry play a crucial role in the evolution of flame surface geometry, propagation, annihilation, and local extinction/re-ignition characteristics of intensely turbulent premixed flames. This study seeks to understand how these interactions affect flame surface annihilation of lean hydrogen–air premixed turbulent flames. Direct numerical simulations (DNSs) are conducted at different parametric conditions with a detailed reaction mechanism and transport properties for hydrogen–air flames. Flame particle tracking (FPT) technique is used to follow specific flame surface segments. An analytical expression for the local displacement flame speed (Sd) of a temperature isosurface is considered, and the contributions of transport, chemistry, and kinematics on the displacement flame speed at different turbulence-flame interaction conditions are identified. In general, the displacement flame speed for the flame particles is found to increase with time for all conditions considered. This is because, eventually all flame surfaces and their resident flame particles approach annihilation by reactant island formation at the end of stretching and folding processes induced by turbulence. Statistics of principal curvature evolving in time, obtained using FPT, suggest that these islands are ellipsoidal on average enclosing fresh reactants. Further examinations show that the increase in Sd is caused by the increased negative curvature of the flame surface and eventual homogenization of temperature gradients as these reactant islands shrink due to flame propagation and turbulent mixing. Finally, the evolution of the normalized, averaged, displacement flame speed vs. stretch Karlovitz number are found to collapse on a narrow band, suggesting that a unified description of flame speed dependence on stretch rate may be possible in the Lagrangian description.

  18. Feeding tube - infants (United States)

    ... this page: // Feeding tube - infants To use the sharing features on this page, please enable JavaScript. A feeding tube is a small, soft, plastic tube placed ...

  19. Micro flame-based detector suite for universal gas sensing.

    Energy Technology Data Exchange (ETDEWEB)

    Hamilton, Thomas Warren; Washburn, Cody M.; Moorman, Matthew Wallace; Manley, Robert George; Lewis, Patrick Raymond; Miller, James Edward; Clem, Paul Gilbert; Shelmidine, Gregory J.; Manginell, Ronald Paul; Okandan, Murat


    A microflame-based detector suit has been developed for sensing of a broad range of chemical analytes. This detector combines calorimetry, flame ionization detection (FID), nitrogen-phosphorous detection (NPD) and flame photometric detection (FPD) modes into one convenient platform based on a microcombustor. The microcombustor consists in a micromachined microhotplate with a catalyst or low-work function material added to its surface. For the NPD mode a low work function material selectively ionizes chemical analytes; for all other modes a supported catalyst such as platinum/alumina is used. The microcombustor design permits rapid, efficient heating of the deposited film at low power. To perform calorimetric detection of analytes, the change in power required to maintain the resistive microhotplate heater at a constant temperature is measured. For FID and NPD modes, electrodes are placed around the microcombustor flame zone and an electrometer circuit measures the production of ions. For FPD, the flame zone is optically interrogated to search for light emission indicative of deexcitation of flame-produced analyte compounds. The calorimetric and FID modes respond generally to all hydrocarbons, while sulfur compounds only alarm in the calorimetric mode, providing speciation. The NPD mode provides 10,000:1 selectivity of nitrogen and phosphorous compounds over hydrocarbons. The FPD can distinguish between sulfur and phosphorous compounds. Importantly all detection modes can be established on one convenient microcombustor platform, in fact the calorimetric, FID and FPD modes can be achieved simultaneously on only one microcombustor. Therefore, it is possible to make a very universal chemical detector array with as little as two microcombustor elements. A demonstration of the performance of the microcombustor in each of the detection modes is provided herein.

  20. NR4.00002: Response of a laminar M-shaped premixed flame to plasma forcing

    KAUST Repository

    Lacoste, Deanna A.


    We report on the response of a lean methane-air flame to non-thermal plasma forcing. The set-up consists of an axisymmetric burner, with a nozzle made of a quartz tube of 7-mm inlet diameter. The equivalence ratio is 0.9 and the flame is stabilized in an M-shape morphology over a central stainless steel rod and the quartz tube. The plasma is produced by nanosecond pulses of 10 kV maximum voltage amplitude, applied at 10 kHz. The central rod is used as a cathode, while the anode is a stainless steel ring, fixed on the outer surface of the quartz tube. The plasma forcing is produced by bursts of plasma pulses of 1 s duration. The response of the flame is investigated through the heat release rate (HRR) fluctuations. The chemiluminescence of CH* between two consecutive pulses was recorded using an intensified camera with an optical filter to estimate the HRR fluctuations. The results show that, even though the plasma is located in the combustion area, the flame is not responding to each single plasma pulse, but is affected by the discharge burst. The plasma forcing can then be considered as a step of forcing: the beginning of a positive step corresponding to the first plasma pulse, and the beginning of a negative step corresponding to the end of the last pulse of the burst. The effects of both positive and negative steps were investigated. The response of the flame is then analyzed and viable mechanisms are discussed.

  1. Inorganic-organic hybrid coating material for the online in-tube solid-phase microextraction of monohydroxy polycyclic aromatic hydrocarbons in urine. (United States)

    Wang, ShuLing; Xu, Hui


    An inorganic-organic hybrid nanocomposite (zinc oxide/polypyrrole) that represents a novel kind of coating for in-tube solid-phase microextraction is reported. The composite coating was prepared by a facile electrochemical polymerization strategy on the inner surface of a stainless-steel tube. Based on the coated tube, a novel online in-tube solid-phase microextraction with liquid chromatography and mass spectrometry method was developed and applied for the extraction of three monohydroxy polycyclic aromatic hydrocarbons in human urine. The coating displayed good extraction ability toward monohydroxy polycyclic aromatic hydrocarbons. In addition, long lifespan, excellent stability, and good compression resistance were also obtained for the coating. The experimental conditions affecting the extraction were optimized systematically. Under the optimal conditions, the limits of detection and quantification were in the range of 0.039-0.050 and 0.130-0.167 ng/mL, respectively. Good linearity (0.2-100 ng/mL) was obtained with correlation coefficients larger than 0.9967. The repeatability, expressed as relative standard deviation, ranged between 2.5% and 9.4%. The method offered the advantage of process simplicity, rapidity, automation, and sensitivity in the analysis of human urinary monohydroxy polycyclic aromatic hydrocarbons in two different cities of Hubei province. An acceptable recovery of monohydroxy polycyclic aromatic hydrocarbons (64-122%) represented the additional attractive features of the method in real urine analysis.

  2. Tube-shape verifier (United States)

    Anderson, A. N.; Christ, C. R.


    Inexpensive apparatus checks accuracy of bent tubes. Assortment of slotted angles and clamps is bolted down to flat aluminum plate outlining shape of standard tube bent to desired configuration. Newly bent tubes are then checked against this outline. Because parts are bolted down, tubes can be checked very rapidly without disturbing outline. One verifier per tube-bending machine can really speed up production in tube-bending shop.

  3. Shuttle Environmental Assurance: Brominated Flame Retardants - Concerns, Drivers, Potential Impacts and Mitigation Strategies (United States)

    Clark-Ingram, Marceia


    Brominated Flame Retardants (BFRs) are widely used in the manufacture of electrical and electronic components and as additives in formulations for foams, plastics and rubbers. The United States (US) and the European Union (EU)have increased regulation and monitoring of of targeted BFRs, such as Polybrominated Diphenyl Ethers (PBDEs) due to the bioaccumulative effects in humans and animals. In response, manufacturers and vendors of BFR-containing materials are changing flame-retardant additives, sometimes without notifying BFR users. In some instances, Deca-bromodiphenylether (Deca-BDE) and other families of flame retardants are being used as replacement flame retardants for penta-BDE and octa-BDE. The reformulation of the BFR-containing material typically results in the removal of the targeted PBDE and replacement with a non-PBDE chemical or non-targeted PBDE. Many users of PBDE -based materials are concerned that vendors will perform reformulation and not inform the end user. Materials performance such as flammability, adhesion , and tensile strength may be altered due to reformulation. The requalification of newly formulated materials may be required, or replacement materials may have to be identified and qualified. The Shuttle Enviornmental Assurance (SEA) team indentified a risk to the Space Shuttle Program associated with the possibility that targeted PBDEs may be replaced without notification. Resultant decreases in flame retardancy, Liquid Oxygen (LOX) compatibility, or material performance could have serious consequences.

  4. Death in Flames

    DEFF Research Database (Denmark)

    Harvig, Lise; Kveiborg, Jacob; Lynnerup, Niels


    This paper presents osteoarchaeological analyses of the human skeletal material from a burnt down house in Jutland, Denmark, dated to the first century bc. We describe how the osteological analyses of this complex site were approached and illustrate how we reconstructed the death of the human...

  5. The FLAMES Tarantula Survey

    CERN Document Server

    Markova, N; Bastian, N; Beletsky, Y; Bestenlehner, J; Brott, I; Cantiello, M; Carraro, G; Clark, J; Crowther, P; de Koter, A; de Mink, S; Doran, E; Dufton, P; Dunstall, P; Gieles, M; Graefener, G; Henault-Brunet, V; Herrero, A; Howarth, I; Langer, N; Lennon, D; Apellaniz, J Maiz; Najarro, F; Puls, J; Sana, H; Simon-Diaz, S; Smartt, S; Stroud, V; Taylor, W; van Loon, J; Vink, J; Walborn, N


    The Tarantula survey is an ESO Large Programme which has obtained multi-epochs spectroscopy of over 800 massive stars in the 30 Dor region in the Large Magelanic Cloud. Here we briefly describe the main drivers of the survey and the observational material derived.

  6. Numerical simulation of tulip flame dynamics

    Energy Technology Data Exchange (ETDEWEB)

    Cloutman, L.D.


    A finite difference reactive flow hydrodynamics program based on the full Navier-Stokes equations was used to simulate the combustion process in a homogeneous-charge, constant-volume combustion bomb in which an oddly shaped flame, known as a ``tulip flame`` in the literature, occurred. The ``tulip flame`` was readily reproduced in the numerical simulations, producing good agreement with the experimental flame shapes and positions at various times. The calculations provide sufficient detail about the dynamics of the experiment to provide some insight into the physical mechanisms responsible for the peculiar flame shape. Several factors seem to contribute to the tulip formation. The most important process is the baroclinic production of vorticity by the flame front, and this rate of production appears to be dramatically increased by the nonaxial flow generated when the initial semicircular flame front burns out along the sides of the chamber. The vorticity produces a pair of vortices behind the flame that advects the flame into the tulip shape. Boundary layer effects contribute to the details of the flame shape next to the walls of the chamber, but are otherwise not important. 24 refs.

  7. Numerical simulation of tulip flame dynamics

    Energy Technology Data Exchange (ETDEWEB)

    Cloutman, L.D.


    A finite difference reactive flow hydrodynamics program based on the full Navier-Stokes equations was used to simulate the combustion process in a homogeneous-charge, constant-volume combustion bomb in which an oddly shaped flame, known as a tulip flame'' in the literature, occurred. The tulip flame'' was readily reproduced in the numerical simulations, producing good agreement with the experimental flame shapes and positions at various times. The calculations provide sufficient detail about the dynamics of the experiment to provide some insight into the physical mechanisms responsible for the peculiar flame shape. Several factors seem to contribute to the tulip formation. The most important process is the baroclinic production of vorticity by the flame front, and this rate of production appears to be dramatically increased by the nonaxial flow generated when the initial semicircular flame front burns out along the sides of the chamber. The vorticity produces a pair of vortices behind the flame that advects the flame into the tulip shape. Boundary layer effects contribute to the details of the flame shape next to the walls of the chamber, but are otherwise not important. 24 refs.

  8. Temperature measurement of axisymmetric partially premixed methane/air flame in a co-annular burner using Mach-Zehnder interferometry (United States)

    Irandoost, M. S.; Ashjaee, M.; Askari, M. H.; Ahmadi, S.


    In this paper partially premixed laminar methane/air co-flow flame is studied experimentally. Methane-air flame is established on an axisymmetric co-annular burner. The fuel-air jet flows from the central tube while the secondary air flows from the region between the inner and the outer tube. The aim is to investigate the flame characteristics for methane/air axisymmetric partially premixed flame using Mach-Zehnder interferometry. Different equivalence ratios (φ=1.4-2.2) and Reynolds numbers (Re=100-1200) are considered in the study. Flame generic visible appearance and the corresponding fringe map structures are also investigated. It is seen that the fringe maps are poorly influenced by equivalence ratio variations at constant Reynolds number but are significantly affected by Reynolds number variations in constant equivalence ratio. Temperatures obtained from optical techniques are compared with those obtained from thermocouples and good agreement is observed. It is concluded that the effect of Reynolds number increment on maximum flame temperature is negligible while equivalence ratio reduction increases maximum flame temperature substantially.

  9. Development boiling to sprinkled tube bundle

    Directory of Open Access Journals (Sweden)

    Kracík Petr


    Full Text Available This paper presents results of a studied heat transfer coefficient at the surface of a sprinkled tube bundle where boiling occurs. Research in the area of sprinkled exchangers can be divided into two major parts. The first part is research on heat transfer and determination of the heat transfer coefficient at sprinkled tube bundles for various liquids, whether boiling or not. The second part is testing of sprinkle modes for various tube diameters, tube pitches and tube materials and determination of individual modes’ interface. All results published so far for water as the falling film liquid apply to one to three tubes for which the mentioned relations studied are determined in rigid laboratory conditions defined strictly in advance. The sprinkled tubes were not viewed from the operational perspective where there are more tubes and various modes may occur in different parts with various heat transfer values. The article focuses on these processes. The tube is located in a low-pressure chamber where vacuum is generated using an exhauster via ejector. The tube consists of smooth copper tubes of 12 mm diameter placed horizontally one above another.

  10. Development boiling to sprinkled tube bundle (United States)

    Kracík, Petr; Pospíšil, Jiří


    This paper presents results of a studied heat transfer coefficient at the surface of a sprinkled tube bundle where boiling occurs. Research in the area of sprinkled exchangers can be divided into two major parts. The first part is research on heat transfer and determination of the heat transfer coefficient at sprinkled tube bundles for various liquids, whether boiling or not. The second part is testing of sprinkle modes for various tube diameters, tube pitches and tube materials and determination of individual modes' interface. All results published so far for water as the falling film liquid apply to one to three tubes for which the mentioned relations studied are determined in rigid laboratory conditions defined strictly in advance. The sprinkled tubes were not viewed from the operational perspective where there are more tubes and various modes may occur in different parts with various heat transfer values. The article focuses on these processes. The tube is located in a low-pressure chamber where vacuum is generated using an exhauster via ejector. The tube consists of smooth copper tubes of 12 mm diameter placed horizontally one above another.

  11. Effects of electric field on micro-scale flame properties of biobutanol fuel (United States)

    Xu, Tao; Chen, Qinglin; Zhang, Bingjian; Lu, Shushen; Mo, Dongchuan; Zhang, Zhengguo; Gao, Xuenong


    With the increasing need of smaller power sources for satellites, energy systems and engine equipment, microcombustion pose a potential as alternative power source to conventional batteries. As the substitute fuel source for gasoline, biobutanol shows more promising characteristics than ethanol. In this study, the diffusion microflame of liquid biobutanol under electric field have been examined through in-lab experiment and numerical simulation. It is found that traditional gas jet diffusion flame theory shows significant inconsistency with the experimental results of micro scale flame in electric field. The results suggest that with the increase of electric field intensity, the quenching flow rate decrease first and increase after it reach its minimum, while the flame height and highest flame temperature increase first and drop after its peak value. In addition, it was also observed that the flame height and highest temperature for smaller tube can reach its maximum faster. Therefore, the interaction between microscale effect and electric field plays a significant role on understanding the microcombustion of liquid fuel. Therefore, FLUENT simulation was adopted to understand and measure the impacts of microflame characteristic parameters. The final numerical results are consistent with the experimental data and show a high reliability.

  12. Soot Particle Size Distribution Functions in a Turbulent Non-Premixed Ethylene-Nitrogen Flame

    KAUST Repository

    Boyette, Wesley


    A scanning mobility particle sizer with a nano differential mobility analyzer was used to measure nanoparticle size distribution functions in a turbulent non-premixed flame. The burner utilizes a premixed pilot flame which anchors a C2H4/N2 (35/65) central jet with ReD = 20,000. Nanoparticles in the flame were sampled through a N2-filled tube with a 500- μm orifice. Previous studies have shown that insufficient dilution of the nanoparticles can lead to coagulation in the sampling line and skewed particle size distribution functions. A system of mass flow controllers and valves were used to vary the dilution ratio. Single-stage and two-stage dilution systems were investigated. A parametric study on the effect of the dilution ratio on the observed particle size distribution function indicates that particle coagulation in the sampling line can be eliminated using a two-stage dilution process. Carbonaceous nanoparticle (soot) concentration particle size distribution functions along the flame centerline at multiple heights in the flame are presented. The resulting distributions reveal a pattern of increasing mean particle diameters as the distance from the nozzle along the centerline increases.

  13. Inerting characteristics of entrained atomized water on premixed methane-air flame

    Institute of Scientific and Technical Information of China (English)

    Cai Feng; Wang Ping; Zhou Jiebo; Li Chao


    A combustion tube experiment platform was designed and used to study the inerting conditions and capacity of entrained atomized water on premixed methane–air flame. The structure of a laminar flame of premixed methane–air gas and the process of interaction between atomized water and flame was recorded, and the rules of combustion velocity, stability and strength rate of laminar flame were experi-mentally studied. The inerting process and mechanism was analyzed, and the characteristics of inerting premixed methane–air gas within explosion limits by atomized water were acquired. The research results show that:for the premixed methane–air gas with a concentration of 7%, the minimum inerting atomized water flux is 20.8 mL/(m2 min);for the premixed methane–air gas with a concentration of 9%, the mini-mum inerting atomized water flux is 32.9 mL/(m2 min);for the premixed methane–air gas with a concen-tration of 11%, the minimum inerting atomized water flux is 44.6 mL/(m2 min). The research results are significant for extinguishing methane flame and inhibiting of methane explosion using atomized water.

  14. Effects of electric field on micro-scale flame properties of biobutanol fuel (United States)

    Xu, Tao; Chen, Qinglin; Zhang, Bingjian; Lu, Shushen; Mo, Dongchuan; Zhang, Zhengguo; Gao, Xuenong


    With the increasing need of smaller power sources for satellites, energy systems and engine equipment, microcombustion pose a potential as alternative power source to conventional batteries. As the substitute fuel source for gasoline, biobutanol shows more promising characteristics than ethanol. In this study, the diffusion microflame of liquid biobutanol under electric field have been examined through in-lab experiment and numerical simulation. It is found that traditional gas jet diffusion flame theory shows significant inconsistency with the experimental results of micro scale flame in electric field. The results suggest that with the increase of electric field intensity, the quenching flow rate decrease first and increase after it reach its minimum, while the flame height and highest flame temperature increase first and drop after its peak value. In addition, it was also observed that the flame height and highest temperature for smaller tube can reach its maximum faster. Therefore, the interaction between microscale effect and electric field plays a significant role on understanding the microcombustion of liquid fuel. Therefore, FLUENT simulation was adopted to understand and measure the impacts of microflame characteristic parameters. The final numerical results are consistent with the experimental data and show a high reliability. PMID:27609428

  15. Flat-flame burner studies of pulverized-coal combustion. Experimental results on char reactivity

    Energy Technology Data Exchange (ETDEWEB)

    Peck, R.E.; Shi, L.


    Structure of laminar, premixed pulverized-coal flames in a 1-D reactor has been studied with emphasis on char reactivity. A 1.1-meter-long tube furnace accommodated high-temperature environments and long residence times for the laminar flames produced by a flat-flame, coal-dust burner. Experiments were conducted at different operating conditions (fuel type/size, fuel-air ratio). Measurements included solid sample composition, major gas species and hydrocarbon species concentrations, and gas- and particle-phase line-of-sight temperatures at different axial locations in flames. Degree of char burnout increased with coal volatiles content and decreased with coal particle size. Combustion in furnace was in oxidizer-deficient environment and higher burnout was achieved as the fuel-air ratio neared stoichiometric. For 0-45 {mu}m particles most of the fixed carbon mass loss occurred within 5 cm of the furnace inlet, and char reaction was slow downstream due to low oxidizer concentrations. Fixed carbon consumption of the 45-90 {mu}m particles generally was slower than for the small particles. About 40%-80% of the fixed carbon was oxidized in the furnace. Primary volatiles mass loss occurred within the first 4.5 cm, and more than 90% of the volatiles were consumed in the flames. The flames stabilized in the furnace produced less CH{sub 4} and H{sub 2} in the burnt gas than similar unconfined flames. NO concentrations were found to decrease along the furnace and to increase with decreasing fuel/air ratio. Temperature measurement results showed that gas-phase temperatures were higher than solid-phase temperatures. Temperatures generally decreased with decreasing volatiles content and increased as the equivalence ratio approached one. The results can be used to interpret thermochemical processes occurring in pulverized-coal combustion. (au) 15 refs.

  16. Flame Propagation Through Concentration Gradient

    Institute of Scientific and Technical Information of China (English)

    JunyaIINO; MitsuakiTANABE; 等


    The experiment was carried out in homogeneous propane-air mixture and in several concentration gradient of mixture.Igniter is put on the upper side of the combustion chamber,In concentration gradient experiment.ixture was ignited from lean side.An experimental study was conducted in a combustion chamber.The combustion chamber has glass windows for optical measurements at any side.For the measurement of distribution of fuel concentration,infraed absorption method using 3.39μm He-Ne laser was used,and for the observation of proagating flams,Schlieren method was employed.As a measurment result of flame propagation velocity and flammable limit,for a mixture of an identical local equivalence ratio.flame propagation velocity in concentration gradient is faster than that in homogeneous mixture,and rich flammable limit in concentration gradient shows a tendency to be higher than that in homogeneous mixture.


    Institute of Scientific and Technical Information of China (English)



    The present paper deals with the use of a new polymeric flame retardant material, polyphenylene sulphide (PPS) for plastics. Incorporation of 15 - 20% PPS into nylon-6 has provided UL V- 0 rating for the system and there is enhancement in tensile and flexural properties. The results obtained on the thermal, crystallization and flow characteristics of the nylon-PPS system uptoa loading of 40% PPS are also discussed.

  18. Hyperbranched Polyurethane Acrylate Applied to UV Curable Flame Retardant Coatings

    Institute of Scientific and Technical Information of China (English)


    @@ UV curable hyperbranched prepolymers based on amine-ester, ester-amide and ether-amide started with AB2-type monomers have been prepared by the authors[1~3]. A se-ries of work on allyl ether maleate hyperbranched polyesters for UV curing coatings by Hult and his colleagues has been reported[4]. However, the UV cured films from those materials are all flammable when attached to fire without addition of flame retardants.

  19. Flame spray technology method for production of nanopowders

    CERN Document Server

    Trommer, Rafael M


    This books presents a complete and updated overview of Flame Spray process, from its History to the Apparatus necessary for the synthesis of nanostructures. It addresses not only the materials produced by this technique, but also their properties, such as crystallinity and crystallite size, specific surface area, particle size and morphology. Also, the principles of nanoparticle formation are described. It is a useful read to all those interested in low cost synthesis of nanostructured powders and coatings.

  20. The Interaction of High-Speed Turbulence with Flames: Global Properties and Internal Flame Structure

    CERN Document Server

    Poludnenko, Alexei Y; 10.1016/j.combustflame.2009.11.018


    We study the dynamics and properties of a turbulent flame, formed in the presence of subsonic, high-speed, homogeneous, isotropic Kolmogorov-type turbulence in an unconfined system. Direct numerical simulations are performed with Athena-RFX, a massively parallel, fully compressible, high-order, dimensionally unsplit, reactive-flow code. A simplified reaction-diffusion model represents a stoichiometric H2-air mixture. The system being modeled represents turbulent combustion with the Damkohler number Da = 0.05 and with the turbulent velocity at the energy injection scale 30 times larger than the laminar flame speed. The simulations show that flame interaction with high-speed turbulence forms a steadily propagating turbulent flame with a flame brush width approximately twice the energy injection scale and a speed four times the laminar flame speed. A method for reconstructing the internal flame structure is described and used to show that the turbulent flame consists of tightly folded flamelets. The reaction zon...

  1. Heat and mass transfer in flames (United States)

    Faeth, G. M.


    Heat- and mass-transfer processes in turbulent diffusion flames are discussed, considering turbulent mixing and the structure of single-phase flames, drop processes in spray flames, and nonluminous and luminous flame radiation. Interactions between turbulence and other phenomena are emphasized, concentrating on past work of the author and his associates. The conserved-scalar formalism, along with the laminar-flamelet approximation, is shown to provide reasonable estimates of the structure of gas flames, with modest levels of empiricism. Extending this approach to spray flames has highlighted the importance of drop/turbulence interactions; e.g., turbulent dispersion of drops, modification of turbulence by drops, etc. Stochastic methods being developed to treat these phenomena are yielding encouraging results.

  2. Optimization of a Shell and Tube Condenser using Numerical Method

    Directory of Open Access Journals (Sweden)

    Pradeep Wagh


    Full Text Available The purpose of this study was to investigate the effect of installation of the tube external surfaces, their parameter and variable in a shell-and-tube condenser. Variation of heat transfer coefficient with each variable of shell and tube condenser was measured each test. The optimization tube outside diameter size was analyzed and use extended surface area attached tube with tube material and tube layout and arrangement (Number of tube a triangular or hexagonal arrangement on shell-and tube condenser. The computer programming was used to get faster output in less time. Results suggest that mean heat transfer coefficient in variable condition were mainly at velocity is fixed. And also average additional surfaces and tube layout and the arrangement comparison with the quantity of the heat transfer.

  3. Flame Suppression Agent, System and Uses (United States)

    Parrish, Clyde F. (Inventor)


    Aqueous droplets encapsulated in a flame retardant polymer are useful in suppressing combustion. Upon exposure to a flame, the encapsulated aqueous droplets rupture and vaporize, removing heat and displacing oxygen to retard the combustion process. The polymer encapsulant, through decomposition, may further add free radicals to the combustion atmosphere, thereby further retarding the combustion process. The encapsulated aqueous droplets may be used as a replacement to halon, water mist and dry powder flame suppression systems.

  4. Failure Analysis of Main Flame Deflector Nelson Studs (United States)

    Long, Victoria


    NASA Structures engineers submitted two Nelson refractory studs from the main flame deflector at Launch Complex (LC) 39 A for analysis when they were observed to be missing a significant amount of material after launch. The damaged stud and an unused comparative stud were analyzed by macroscopic and microscopic examination along with metallographic evaluation of the microstructure. The stud lost material due to a combination of erosion and corrosion. Plain carbon steel readily forms an oxide layer in the coastal launch environment at Kennedy Space Center. The blast during a launch removes this brittle oxide layer, which then forms again post-launch, thereby further removing material. No indications of melting were observed.

  5. Numerical modeling of turbulent combustion and flame spread

    Energy Technology Data Exchange (ETDEWEB)

    Yan Zhenghua


    Theoretical models have been developed to address several important aspects of numerical modeling of turbulent combustion and flame spread. The developed models include a pyrolysis model for charring and non-charring solid materials, a fast narrow band radiation property evaluation model (FASTNB) and a turbulence model for buoyant flow and flame. In the pyrolysis model, a completely new algorithm has been proposed, where a moving dual mesh concept was developed and implemented. With this new concept, it provides proper spatial resolution for both temperature and density and automatically considers the regression of the surface of the non-charring solid material during its pyrolysis. It is simple, very efficient and applicable to both charring and non-charring materials. FASTNB speeds up significantly the evaluation of narrow band spectral radiation properties and thus provides a potential of applying narrow band model in numerical simulations of practical turbulent combustion. The turbulence model was developed to improve the consideration of buoyancy effect on turbulence and turbulent transport. It was found to be simple, promising and numerically stable. It has been tested against both plane and axisymmetric thermal plumes and an axisymmetric buoyant diffusion flame. When compared with the widely used standard buoyancy-modified {kappa} - {epsilon} model, it gives significant improvement on numerical results. These developed models have been fully incorporated into CFD (Computational Fluid Dynamics) code and coupled with other CFD sub-models, including the DT (Discrete Transfer) radiation model, EDC (Eddy Dissipation Concept) combustion model, flamelet combustion model, various soot models and transpired wall function. Comprehensive numerical simulations have been carried out to study soot formation and oxidation in turbulent buoyant diffusion flames, flame heat transfer and flame spread in fires. The gas temperature and velocity, soot volume fraction, wall

  6. Comparative Analysis of Flame Characteristics of Castor Oil and ...

    African Journals Online (AJOL)

    Flame Retardants Used in Polyurethane Foam Systems. Polycarp .O. Ikeh ... such as ignition time, flame propagation rate, after glow, char rate, add-on and glow time. These properties .... hours before the flame test to ensure complete curing.

  7. Ablation behavior of monolayer and multilayer Ir coatings under carburizing and oxidizing oxyacetylene flames (United States)

    Wu, Wangping; Jiang, Jinjin; Chen, Zhaofeng


    Iridium is one of the most promising candidates for protective barrier of refractory materials to endure high service temperature. The multilayer iridium coating was produced by a double glow plasma process on the polished tungsten carbide substrates, compared with monolayer. The ablation behaviors of the monolayer on the unpolished and polished substrates were investigated under carburizing and oxidizing oxyacetylene flames, respectively, at the same time the multilayer coating ablated under oxidizing flames. Multilayer coating was a polycrystalline phase with the preferential (220) orientation. Monolayer on the unpolished substrate had fine coarse grains and some small microcracks were present. Multilayer consisted of columnar grains with some voids between the grains boundaries. The formation of a WIr phase in the as-deposited multilayer was attributed to high deposition temperature. The monolayer could endure high temperature up to 1800 °C in carburizing flame. The substrates could be protected more effectively by multilayer than monolayer at 2000- 2200 °C in oxidizing flame.

  8. Pole solutions for flame front propagation

    CERN Document Server

    Kupervasser, Oleg


    This book deals with solving mathematically the unsteady flame propagation equations. New original mathematical methods for solving complex non-linear equations and investigating their properties are presented. Pole solutions for flame front propagation are developed. Premixed flames and filtration combustion have remarkable properties: the complex nonlinear integro-differential equations for these problems have exact analytical solutions described by the motion of poles in a complex plane. Instead of complex equations, a finite set of ordinary differential equations is applied. These solutions help to investigate analytically and numerically properties of the flame front propagation equations.

  9. Soot zone structure and sooting limit in diffusion flames: Comparison of counterflow and co-flow flames

    Energy Technology Data Exchange (ETDEWEB)

    Kang, K.T.; Hwang, J.Y.; Chung, S.H. [Seoul National Univ. (Korea, Republic of). Dept. of Mechanical Engineering; Lee, W. [Dankook Univ., Seoul (Korea, Republic of). Dept. of Mechanical Engineering


    Soot zone structures of counterflow and co-flow diffusion flames have been studied experimentally using the soot extinction-scattering, polycyclic aromatic hydrocarbon fluorescence, and laser Doppler velocimetry measurements. The counterflow flame has been numerically modelled with detailed chemistry. Results show that two different categories of sooting flame structures can be classified depending on the relative transport of soot particles to flames. These are the soot formation-oxidation flame and the soot formation flame. The soot formation-oxidation flame characteristics are observed in counterflow flames when located on the fuel side and in normal co-flow flames. In this case, soot particles are transported toward the high temperature region or the flame and experience soot inception, coagulation-growth, and oxidation. The soot formation flame characteristics are observed in counterflow flames when located on the oxidizer side and in inverse co-flow flames. In this case, soot particles are transported away from the flame without experiencing oxidation and finally leak through the stagnation plane in counterflow flames or leave the flame in inverse co-flow flames. Sooting limit measurements in both flames also substantiate the two different sooting flame structures and their characteristics.

  10. 膨胀型阻燃剂的研究现状%The research status of Intumescent Flame Retardant

    Institute of Scientific and Technical Information of China (English)

    刘晓双; 张亮


    介绍了IFR的阻燃机理,着重对混合型膨胀型阻燃剂,聚磷酸铵膨胀阻燃体系等几种常见的阻燃膨胀体系进行了具体阐述,指出膨胀型阻燃剂必将会在火灾预防、室内装修材料阻燃等方面发挥巨大的作用。%This paper introduced the flame retardant mechanism of IFR, emphatically elaborated mixed type intumescent flame retardant, ammo nium polyphosphate intumescent flame retardant system and other common flame retardant intumescent systems, pointed OUt that the intumescent flame retardant would play a huge role in fire prevention, indoor decoration materials fire retardant and other aspects.

  11. Flame dynamics of a meso-scale heat recirculating combustor

    Energy Technology Data Exchange (ETDEWEB)

    Vijayan, V.; Gupta, A.K. [Department of Mechanical Engineering, University of Maryland, College Park, MD 20742 (United States)


    The dynamics of premixed propane-air flame in a meso-scale ceramic combustor has been examined here. The flame characteristics in the combustor were examined by measuring the acoustic emissions and preheat temperatures together with high-speed cinematography. For the small-scale combustor, the volume to surface area ratio is small and hence the walls have significant effect on the global flame structure, flame location and flame dynamics. In addition to the flame-wall thermal coupling there is a coupling between flame and acoustics in the case of confined flames. Flame-wall thermal interactions lead to low frequency flame fluctuations ({proportional_to}100 Hz) depending upon the thermal response of the wall. However, the flame-acoustic interactions can result in a wide range of flame fluctuations ranging from few hundred Hz to few kHz. Wall temperature distribution is one of the factors that control the amount of reactant preheating which in turn effects the location of flame stabilization. Acoustic emission signals and high-speed flame imaging confirmed that for the present case flame-acoustic interactions have more significant effect on flame dynamics. Based on the acoustic emissions, five different flame regimes have been identified; whistling/harmonic mode, rich instability mode, lean instability mode, silent mode and pulsating flame mode. (author)

  12. photomultiplier tube

    CERN Multimedia

    A device to convert light into an electric signal (the name is often abbreviated to PM). Photomultipliers are used in all detectors based on scintillating material (i.e. based on large numbers of fibres which produce scintillation light at the passage of a charged particle). A photomultiplier consists of 3 main parts: firstly, a photocathode where photons are converted into electrons by the photoelectric effect; secondly, a multiplier chain consisting of a serie of dynodes which multiply the number of electron; finally, an anode, which collects the resulting current.

  13. photomultiplier tube

    CERN Multimedia

    Philips. 150AVP. A device to convert light into an electric signal (the name is often abbreviated to PM). Photomultipliers are used in all detectors based on scintillating material (i.e. based on large numbers of fibres which produce scintillation light at the passage of a charged particle). A photomultiplier consists of 3 main parts: firstly, a photocathode where photons are converted into electrons by the photoelectric effect; secondly, a multiplier chain consisting of a serie of dynodes which multiply the number of electron; finally, an anode, which collects the resulting current.

  14. Unsteady planar diffusion flames: Ignition, travel, burnout (United States)

    Fendell, F.; Wu, F.


    In microgravity, a thin planar diffusion flame is created and thenceforth travels so that the flame is situated at all times at an interface at which the hydrogen and oxygen meet in stoichiometric proportion. If the initial amount of hydrogen is deficient relative to the initial amount of oxygen, then the planar flame will travel further and further into the half volume initially containing hydrogen, until the hydrogen is (virtually) fully depleted. Of course, when the amount of residual hydrogen becomes small, the diffusion flame is neither vigorous nor thin; in practice, the flame is extinguished before the hydrogen is fully depleted, owing to the finite rate of the actual chemical-kinetic mechanism. The rate of travel of the hydrogen-air diffusion flame is much slower than the rate of laminar flame propagation through a hydrogen-air mixture. This slow travel facilitates diagnostic detection of the flame position as a function of time, but the slow travel also means that the time to burnout (extinction) probably far exceeds the testing time (typically, a few seconds) available in earth-sited facilities for microgravity-environment experiments. We undertake an analysis to predict (1) the position and temperature of the diffusion flame as a function of time, (2) the time at which extinction of the diffusion flame occurs, and (3) the thickness of quench layers formed on side walls (i.e., on lateral boundaries, with normal vectors parallel to the diffusion-flame plane), and whether, prior to extinction, water vapor formed by burning will condense on these cold walls.

  15. Formation of Metal-Adducted Analyte Ions by Flame-Induced Atmospheric Pressure Chemical Ionization Mass Spectrometry. (United States)

    Cheng, Sy-Chyi; Wang, Chin-Hsiung; Shiea, Jentaie


    A flame-induced atmospheric pressure chemical ionization (FAPCI) source, consisting of a miniflame, nebulizer, and heated tube, was developed to ionize analytes. The ionization was performed by reacting analytes with a charged species generated in a flame. A stainless steel needle deposited with saturated alkali chloride solution was introduced into the mini oxyacetylene flame to generate alkali ions, which were reacted with analytes (M) generated in a heated nebulizer. The alkali-adducted 18-crown-6 ether ions, including (M + Li)(+), (M + Na)(+), (M + K)(+), (M + Rb)(+), and (M + Cs)(+), were successfully detected on the FAPCI mass spectra when the corresponding alkali chloride solutions were separately introduced to the flame. When an alkali chloride mixture was introduced, all alkali-adducted analyte ions were simultaneously detected. Their intensity order was as follows: (M + Cs)(+) > (M + Rb)(+) > (M + K)(+) > (M + Na)(+) > (M + Li)(+), and this trend agreed with the lattice energies of alkali chlorides. Besides alkali ions, other transition metal ions such as Ni(+), Cu(+), and Ag(+) were generated in a flame for analyte ionization. Other than metal ions, the reactive species generated in the fossil fuel flame could also be used to ionize analytes, which formed protonated analyte ions (M + H)(+) in positive ion mode and deprotonated analyte ions (M - H)(-) in negative ion mode.

  16. Engineering Biodegradable Flame Retardant Wood-Plastic Composites (United States)

    Zhang, Linxi

    Wood-plastic composites (WPCs), which are produced by blending wood and polymer materials, have attracted increasing attentions in market and industry due to the low cost and excellent performance. In this research, we have successfully engineered WPC by melt blending Polylactic Acid (PLA) and Poly(butylene adipate-co-terphthalate) (PBAT) with recycled wood flour. The thermal property and flammability of the composite are significantly improved by introducing flame retardant agent resorcinol bis(biphenyl phosphate) (RDP). The mechanical and morphological properties are also investigated via multiple techniques. The results show that wood material has increased toughness and impact resistance of the PLA/PBAT polymer matrix. SEM images have confirmed that PLA and PBAT are immiscible, but the incompatibility is reduced by the addition of wood. RDP is initially dispersed in the blends evenly. It migrates to the surface of the sample after flame application, and serves as a barrier between the fire and underlying polymers and wood mixture. It is well proved in the research that RDP is an efficient flame retardant agent in the WPC system.

  17. 21 CFR 872.6570 - Impression tube. (United States)


    ... DEVICES DENTAL DEVICES Miscellaneous Devices § 872.6570 Impression tube. (a) Identification. An impression... material, such as wax, the remaining end is slipped over the tooth to make the impression....

  18. 含磷环氧树脂固化剂的合成表征与环氧树脂复合材料阻燃性能的研究∗%Synthesis and characterization of phosphorous-containg epoxy resin curing agent and flame retarding performance of epoxy resin composite material

    Institute of Scientific and Technical Information of China (English)

    王刚; 唐禹; 何冬青; 朱思巧; 梁兵


    以季戊四醇(PER)、三氯氧磷(POCl3)和乙二胺(EDA)为原料合成了一种阻燃固化剂聚乙二胺季戊四醇螺磷酸酯(PES),并通过红外光谱(FT-IR),核磁共振(1 H NMR)、质谱(ESI-MS)和热重分析(TGA)对其结构和热性能进行了表征.并以PES和4,4-二氨基二苯砜(DDS)为固化剂,双酚 A 型环氧树脂(E-51)为基体树脂,制备了不同含磷量的阻燃环氧树脂复合材料.通过极限氧指数(LOI)和垂直燃烧(UL-94)实验表征了环氧树脂复合的阻燃性能,热重分析和扫描电镜研究了阻燃环氧树脂的热性能和残炭形貌.研究发现,随着磷含量增加,阻燃环氧树脂的初始分解温度逐渐降低,但与纯样相比,在600℃时的残炭量显著增加,且随着PES加入量的增大,SEM观察形成的炭层越致密.当磷含量为3.48%时,其LOI值可达28.9,并通过UL-94 V0级测试,拉伸强度和冲击强度分别达到了62.76 MPa和6.81 kJ/m2,表明PES是一种良好的环氧树脂阻燃剂.%With pentaerythritol (PER),phosphorus oxychloride (POCl3 )and ethylenediamine (EDA)as raw material synthesis a kind of flame retardant agent poly-ethylene diamine pentaerythritol screw phosphate (PES),which the chemical structure and thermal properties were characterized by fourier transform infrared spectrum (FT-IR),nuclear magnetic resonance (1 H NMR),mass spectrometry (ESI-MS)and thermogravime-tric analysis (TGA).With PES and 4,4-diamino diphenyl sulfone (DDS)as curing agent,bisphenol A type ep-oxy resin (E-51)as the matrix resin prepared different phosphorus flame retardant epoxy resin composite mate-rial.The flame retardant properties of epoxy resin composite was characterized by limiting oxygen index (LOI) and vertical (UL-94)experimental characterization of the combustion,TGA and SEM would study the thermal properties and the epoxy resin carbon residue morphology.The study found that with the increase of phosphorus content,the initial decomposition temperature of flame

  19. Impact of flame-wall interaction on premixed flame dynamics and transfer function characteristics

    KAUST Repository

    Kedia, K.S.


    In this paper, we numerically investigate the response of a perforated-plate stabilized laminar methane-air premixed flame to imposed inlet velocity perturbations. A flame model using detailed chemical kinetics mechanism is applied and heat exchange between the burner plate and the gas mixture is incorporated. Linear transfer functions, for low mean inlet velocity oscillations, are analyzed for different equivalence ratio, mean inlet velocity, plate thermal conductivity and distance between adjacent holes. The oscillations of the heat exchange rate at the top of the burner surface plays a critical role in driving the growth of the perturbations over a wide range of conditions, including resonance. The flame response to the perturbations at its base takes the form of consumption speed oscillations in this region. Flame stand-off distance increases/decreases when the flame-wall interaction strengthens/weakens, impacting the overall dynamics of the heat release. The convective lag between the perturbations and the flame base response govern the phase of heat release rate oscillations. There is an additional convective lag between the perturbations at the flame base and the flame tip which has a weaker impact on the heat release rate oscillations. At higher frequencies, the flame-wall interaction is weaker and the heat release oscillations are driven by the flame area oscillations. The response of the flame to higher amplitude oscillations are used to gain further insight into the mechanisms. © 2010 Published by Elsevier Inc. on behalf of The Combustion Institute. All rights reserved.

  20. Development of flame resistant treatment for Nomex fibrous structures (United States)

    Toy, M. S.


    Flame resistant fibrous materials for space shuttle application were developed through chemical modification of commercially available aromatic polyamide fibrous products. The new surface treatment was achieved in the laboratory by ultraviolet activation of the fabric in the presence of fluoroolefin monomers and a diluent gas. The monomers grafted under these conditions provide the improved properties of the fabric in flame resistance, chemical inertness, and nonwettability without the sacrifice of color or physical properties. The laboratory reaction vessel was scaled-up to a batch continuous process, which treats ten yards of the commercial width textiles. The treated commercial width Nomex (HT-10-41) from the scaled-up reactor is self-extinguishing in an oxygen-enriched environment, water-repellent, soft, silky, and improved in chemical resistance. Unlike most textile processes, the grafting unit operates under dry conditions and no chemical by-products have to be washed out of the finished product.

  1. Numerical Study on Laminar Burning Velocity and Flame Stability of Premixed Methane/Ethylene/Air Flames

    Institute of Scientific and Technical Information of China (English)

    陈珊珊; 蒋勇; 邱榕; 安江涛


    A numerical study on premixed methane/ethylene/air flames with various ethylene fractions and equivalence ratios was conducted at room temperature and atmospheric pressure. The effects of ethylene addition on laminar burning velocity, flame structure and flame stability under the condition of lean burning were investigated. The results show that the laminar burning velocity increases with ethylene fraction, especially at a large equivalence ratio. More ethylene addition gives rise to higher concentrations of H, O and OH radicals in the flame, which significantly promotes chemical reactions, and a linear correlation exists between the laminar burning velocity and the maximum H + OH concentration in the reaction zone. With the increase of ethylene fraction, the adiabatic flame temperature is raised, while the inner layer temperature becomes lower, contributing to the enhancement of combustion. Markstein length and Markstein number, representative of the flame stability, increase as more ethylene is added, indicating the tendency of flame stability to improve with ethylene addition.

  2. Monitoring Atmospheric Transmission with FLAME (United States)

    Zimmer, Peter C.; McGraw, J. T.; Zirzow, D. C.; Koppa, M.; Buttler-Pena, K.


    Calibration of ground-based observations in the optical and near-infrared requires precise and accurate understanding of atmospheric transmission, at least as precise and accurate as that required for the spectral energy distributions of science targets. Traditionally this has used the Langley extrapolation method, observing targets and calibrators over a range of airmass and extrapolating to zero airmass by assuming a plane-parallel homogeneous atmosphere. The technique we present uses direct measurements of the atmosphere to derive the transmission along the line of sight to science targets at a few well-chosen wavelengths. The Facility Lidar Atmospheric Monitor of Extinction (FLAME) is a 0.5m diameter three Nd:YAG wavelength (355nm, 532nm & 1064nm) elastic backscatter lidar system. Laser pulses are transmitted into the atmosphere in the direction of the science target. Photons scattered back toward the receiver by molecules, aerosols and clouds are collected and time-gated so that the backscatter intensity is measured as a function of range to the scattering volume. The system is housed in a mobile calibration lab, which also contains auxiliary instrumentation to provide a NIST traceable calibration of the transmitted laser power and receiver efficiency. FLAME was designed to create a million photons per minute signal from the middle stratosphere, where the atmosphere is relatively calm and dominated by molecules of the well-mixed atmosphere (O2 & N2). Routine radiosonde measurements of the density at these altitudes constrain the scattering efficiency in this region and, combined with calibration of the transmitter and receiver, the only remaining unknown quantity is the two-way transmission to the stratosphere. These measurements can inform atmospheric transmission models to better understand the complex and ever-changing observatory radiative transfer environment. FLAME is currently under active development and we present some of our ongoing measurements.

  3. Physical and Chemical Processing in Flames (United States)


    than the classical Troe formula, and the development of a Chemical Explosive Mode Analysis ( CEMA ) computation algorithm that allows on-the-fly...6-311++G(d,p) method. 3. Flame Stabilization and Chemical Explosive Mode Analysis ( CEMA ) Flame stabilization is essential in the understanding of

  4. Development of PIV for Microgravity Diffusion Flames (United States)

    Greenberg, Paul S.; Wernet, Mark P.; Yanis, William; Urban, David L.; Sunderland, Peter B.


    Results are presented from the application of Particle Image Velocimetry(PIV) to the overfire region of a laminar gas jet diffusion flame in normal gravity. A methane flame burning in air at 0.98 bar was considered. The apparatus demonstrated here is packaged in a drop rig designed for use in the 2.2 second drop tower.

  5. Chemical processes in the HNF flame

    NARCIS (Netherlands)

    Ermolin, N.E.; Zarko, V.E.; Keizers, H.L.J.


    Results of modeling the HNF flame structure are presented. From an analysis of literature data on the thermal decomposition and combustion of HNF, it is concluded that the dissociative vaporization of HNF proceeds via the route HNFliq → (N2H4)g + (HC(NO 2)3)g. The flame structure is modeled using a

  6. Flaming in CMC: Prometheus' Fire or Inferno's? (United States)

    Abrams, Zsuzsanna Ittzes


    Reports on a descriptive study with 75 intermediate college learners of German participating in two sessions of synchronous computer mediated communication during the course of a semester that investigated students' flaming behavior--aggressive interpersonal language and rude behavior. Shows that not only is flaming a very infrequent occurrence,…

  7. Flame retardant cotton barrier nonwovens for mattresses (United States)

    According to regulation CPSC 16 CFR 1633, every new residential mattress sold in the United States since July 2007 must resist ignition by open flame. An environmentally benign “green”, inexpensive way to meet this regulation is to use a low-cost flame retardant (FR) barrier fabric. In this study, a...

  8. Flame retardant cotton based highloft nonwovens (United States)

    Flame retardancy has been a serious bottleneck to develop cotton blended very high specific volume bulky High loft fabrics. Alternately, newer approach to produce flame retardant cotton blended High loft fabrics must be employed that retain soft feel characteristics desirable of furnishings. Hence, ...

  9. Flaming in CMC: Prometheus' Fire or Inferno's? (United States)

    Abrams, Zsuzsanna Ittzes


    Reports on a descriptive study with 75 intermediate college learners of German participating in two sessions of synchronous computer mediated communication during the course of a semester that investigated students' flaming behavior--aggressive interpersonal language and rude behavior. Shows that not only is flaming a very infrequent occurrence,…

  10. Physical and Chemical Processes in Turbulent Flames (United States)


    DISTRIBUTION A: Distribution approved for public release. AF Office Of Scientific Research (AFOSR)/ RTE Arlington, Virginia 22203 Air Force Research...two-year subject program, conducted through tight coupling between experiment, theory and computation, and reported in high impact journal articles ...The thrust for this program constitutes of three major areas of turbulent combustion: (1) Flame surface statistics , (2) Flame-turbulence interaction

  11. Simulations of flame generated particles

    KAUST Repository

    Patterson, Robert


    The nonlinear structure of the equations describing the evolution of a population of coagulating particles in a flame make the use of stochastic particle methods attractive for numerical purposes. I will present an analysis of the stochastic fluctuations inherent in these numerical methods leading to an efficient sampling technique for steady-state problems. I will also give some examples where stochastic particle methods have been used to explore the effect of uncertain parameters in soot formation models. In conclusion I will try to indicate some of the issues in optimising these methods for the study of uncertain model parameters.

  12. 30 CFR 7.407 - Test for flame resistance of electric cables and cable splices. (United States)


    ... 3 feet in length, by removing 5 inches of jacket material and 21/2 inches of conductor insulation... material and 21/2 inches of conductor insulation. The type, amperage, voltage rating, and construction of... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Test for flame resistance of electric...

  13. Brominated Flame Retardants and their metabolites: Novel insights into endocrine disruptive properties.

    NARCIS (Netherlands)

    Fernández Cantón, R.


    Brominated flame retardants (BFRs) are chemicals that are added to materials to inhibit or suppress ignition and are incorporated during the manufacture of e.g. electronic equipment, furniture, construction materials and textiles. BFRs have become an increasingly important group of organohalogen com

  14. Flame treatment of graphene oxides: cost-effective production of nanoporous graphene electrode for Lithium-ion batteries (United States)

    Jiang, Hao-Bo; Zhang, Yong-Lai; Zhang, Yi; Liu, Yan; Fu, Xiu-Yan; Liu, Yu-Qing; Wang, Chun-Dong; Sun, Hong-Bo


    A facile production of highly porous graphene foam by using flame treatment of graphene oxide (GO) is proposed. Highly porous architectures with randomly distributed micro-crack and micro-slit were produced due to the high temperature induced ruinous reduction and rapid expansion of GO. Synchronously, abundant oxygen-containing groups (OCGs) on GO sheets could be effectively removed after flame treatment, which renders significantly increased conductivity to the resultant flame reduced GO (FR-GO). The synergistic effect of micro/nanostructuring and the OCGs removal makes FR-GO a promising candidate for electrode materials. Compared with chemically reduced GO (CR-GO), FR-GO delivers much higher specific capacity. It gives us some hints that flame treatment of graphene-based material is a smart strategy for cost-effective production of anode materials for commercial application.

  15. Yielding Torque-Tube System Reduces Crash Injuries (United States)

    Mcsmith, D. G.


    Yielding torque-tube system minimizes injuries by limiting load transferred to occupant in crash. When properly integrated into seat structure, torque tube yields in plastic deformation stage of material and maintains a relatively constant resistance to applied torque for many degrees of rotation. Yielding torque-tube system is expected to find application in aircraft and automobile industries.

  16. Microstructural degradation in compound tubes

    Energy Technology Data Exchange (ETDEWEB)

    Salonen, J.; Auerkari, P. [VTT Manufacturing Technology, Espoo (Finland)


    In order to quantify microstructural degradation at high temperatures, samples of SA 210 / AISI 304 L compound tube material were annealed in the temperature range 540-720 deg C for 1 to 1 000 hours. The hardness of the annealed material was measured and the micro structure of the samples was investigated with optical and scanning electron microscopy. Microstructural degradation was characterised by the carbide structure in the ferritic-pearlitic base material and by the depth of decarburised and carburised zones of the compound tube interface. The observed changes were quantified in terms of their time and temperature dependence and diffusion coefficients of the process. The results can be used in estimating the extent of thermal exposure of high-temperature components after long-term service or after incidences of overheating. (orig.) (4 refs.)

  17. Edge Diffusion Flame Propagation and Stabilization Studied (United States)

    Takahashi, Fumiaki; Katta, Viswanath R.


    In most practical combustion systems or fires, fuel and air are initially unmixed, thus forming diffusion flames. As a result of flame-surface interactions, the diffusion flame often forms an edge, which may attach to burner walls, spread over condensed fuel surfaces, jump to another location through the fuel-air mixture formed, or extinguish by destabilization (blowoff). Flame holding in combustors is necessary to achieve design performance and safe operation of the system. Fires aboard spacecraft behave differently from those on Earth because of the absence of buoyancy in microgravity. This ongoing in-house flame-stability research at the NASA Glenn Research Center is important in spacecraft fire safety and Earth-bound combustion systems.

  18. Interaction Between Flames and Electric Fields Studied (United States)

    Yuan, Zeng-Guang; Hegde, Uday


    The interaction between flames and electric fields has long been an interesting research subject that has theoretical importance as well as practical significance. Many of the reactions in a flame follow an ionic pathway: that is, positive and negative ions are formed during the intermediate steps of the reaction. When an external electric field is applied, the ions move according to the electric force (the Coulomb force) exerted on them. The motion of the ions modifies the chemistry because the reacting species are altered, it changes the velocity field of the flame, and it alters the electric field distribution. As a result, the flame will change its shape and location to meet all thermal, chemical, and electrical constraints. In normal gravity, the strong buoyant effect often makes the flame multidimensional and, thus, hinders the detailed study of the problem.

  19. Research of A photovoltaic and Building cable in using flame weather type silane crosslinking Insulation material%一种光伏及建筑电缆用阻燃耐候型硅烷交联绝缘料的研究

    Institute of Scientific and Technical Information of China (English)

    张丽本; 陈敏; 顾金云; 邓之俊


    本文简述了电线电缆用阻燃耐候型硅烷交联聚乙烯绝缘料的交联原理、配方、工艺、分类、设备,并介绍了硅烷自然交联聚乙烯绝缘料在实际应用以及使用过程中呈现出的特征和该材料交联状况的影响因素。针对该材料对光伏与建筑电缆进行分析和探讨。%This paper describes the types of wire and cable flame retardant weather silane crosslinked polyethylene crosslinked insulation material principle, formula, process, classification, equip-ment, and introduced silane XLPE insulation material naturally pres-ent in the practical application and use of the process the characteris-tics and condition of the material cross-linked factors. The materials for the photovoltaic and building cables for analysis and discussion.

  20. Introduction to Physics and Chemistry of Combustion Explosion, Flame, Detonation

    CERN Document Server

    Liberman, Michael A


    Most of the material covered in this book deals with the fundamentals of chemistry and physics of key processes and fundamental mechanisms for various combustion and combustion related phenomena in gaseous combustible mixture. It provides the reader with basic knowledge of burning processes and mechanisms of reaction wave propagation. The combustion of a gas mixture (flame, explosion, detonation) is necessarily accompanied by motion of the gas. The process of combustion is therefore not only a chemical phenomenon but also one of gas dynamics. The material selection focuses on the gas phase and

  1. Cool Sooting Flames of Hydrocarbons

    Institute of Scientific and Technical Information of China (English)



    This paper presents the study of polycyclic aromatic hydrocarbons (PAH) and paramagnetism of soot particles sampled from cool sooting flames of methane and propane in a separately-heated two-sectional reactor under atmospheric pressure at the reactor temperatures of 670-1170 K. The temperature profiles of the flames were studied. The sampling was carried out with a quartz sampler and the samples were frozen with liquid nitrogen. A number of polyaromatic hydrocarbons such as pyrene, fluoranthene, coronene, anthanthrene, 1,12-benzperylene,were identified by spectroscopic methods in the extract of soot. The processes of soot formation at methaneoxygen mixture combustion in the electric field with applied potential changed from 0 to 2,2 kV at different polarity of electrodes have been investigated. It has been stated that at the electrical field application, an increase in soot particle sizes and soot yield occurs; besides, at the application of the field, speeding up the positively charged particles, the interplanar distance decreases. On the basis of investigation of soot particles paramagnetism, it was shown that initially soot particles have high carcinogetic activity and pollute the environment owing to a rapid decrease of the number of these radical centers. The reduction of the radical concentration is connected with radical recombination on soot.

  2. Experiment and Simulation of Autoignition in Jet Flames and its Relevance to Flame Stabilization and Structure

    KAUST Repository

    Al-Noman, Saeed M.


    Autoignition characteristics of pre-vaporized iso-octane, primary reference fuels, gasolines, and dimethyl ether (DME) have been investigated experimentally in a coflow with elevated temperature of air. With the coflow air at relatively low initial temperatures below autoignition temperature Tauto, an external ignition source was required to stabilize the flame. Non-autoignited lifted flames had tribrachial edge structures and their liftoff heights correlated well with the jet velocity scaled by the stoichiometric laminar burning velocity, indicating the importance of the edge propagation speed on flame stabilization balanced with local flow velocity. At high initial temperatures over Tauto, the autoignited flames were stabilized without requiring an external ignition source. The autoignited lifted flames exhibited either tribrachial edge structures or Mild combustion behaviors depending on the level of fuel dilution. For the iso-octane and n-heptane fuels, two distinct transition behaviors were observed in the autoignition regime from a nozzle-attached flame to a lifted tribrachial-edge flame and then a sudden transition to lifted Mild combustion as the jet velocity increased at a certain fuel dilution level. The liftoff data of the autoignited flames with tribrachial edges were analyzed based on calculated ignition delay times for the pre-vaporized fuels. Analysis of the experimental data suggested that ignition delay time may be much less sensitive to initial temperature under atmospheric pressure conditions as compared with predictions. For the gasoline fuels for advanced combustion engines (FACEs), and primary reference fuels (PRFs), autoignited liftoff data were correlated with Research Octane Number and Cetane Number. For the DME fuel, planar laser-induced fluorescence (PLIF) of formaldehyde (CH2O) and CH* chemiluminescence were visualized qualitatively. In the autoignition regime for both tribrachial structure and mild combustion, formaldehyde were found

  3. Flame Structure and Emissions of Strongly-Pulsed Turbulent Diffusion Flames with Swirl (United States)

    Liao, Ying-Hao

    This work studies the turbulent flame structure, the reaction-zone structure and the exhaust emissions of strongly-pulsed, non-premixed flames with co-flow swirl. The fuel injection is controlled by strongly-pulsing the fuel flow by a fast-response solenoid valve such that the fuel flow is completely shut off between pulses. This control strategy allows the fuel injection to be controlled over a wide range of operating conditions, allowing the flame structure to range from isolated fully-modulated puffs to interacting puffs to steady flames. The swirl level is controlled by varying the ratio of the volumetric flow rate of the tangential air to that of the axial air. For strongly-pulsed flames, both with and without swirl, the flame geometry is strongly impacted by the injection time. Flames appear to exhibit compact, puff-like structures for short injection times, while elongated flames, similar in behaviors to steady flames, occur for long injection times. The flames with swirl are found to be shorter for the same fuel injection conditions. The separation/interaction level between flame puffs in these flames is essentially governed by the jet-off time. The separation between flame puffs decreases as swirl is imposed, consistent with the decrease in flame puff celerity due to swirl. The decreased flame length and flame puff celerity are consistent with an increased rate of air entrainment due to swirl. The highest levels of CO emissions are generally found for compact, isolated flame puffs, consistent with the rapid quenching due to rapid dilution with excess air. The imposition of swirl generally results in a decrease in CO levels, suggesting more rapid and complete fuel/air mixing by imposing swirl in the co-flow stream. The levels of NO emissions for most cases are generally below the steady-flame value. The NO levels become comparable to the steady-flame value for sufficiently short jet-off time. The swirled co-flow air can, in some cases, increase the NO

  4. Process Design for Size-Controlled Flame Spray Synthesis of Li4Ti5O12 and Electrochemical Performance

    Directory of Open Access Journals (Sweden)

    Waser Oliver


    Full Text Available Inexpensive synthesis of electroceramic materials is required for efficient energy storage. Here the design of a scalable process, flame spray pyrolysis (FSP, for synthesis of size-controlled nanomaterials is investigated focusing on understanding the role of air entrainment (AE during their aerosol synthesis with emphasis on battery materials. The AE into the enclosed FSP reactor is analysed quantitatively by computational fluid dynamics (CFD and calculated temperatures are verified by Fourier transform infrared spectroscopy (FTIR. Various Li4Ti5O12 (LTO particle compositions are made and characterized by N2 adsorption, electron microscopy and X-ray diffraction while the electrochemical performance of LTO is tested at various charging rates. Increasing AE decreases recirculation in the enclosing tube leading to lower reactor temperatures and particle concentrations by air dilution as well as shorter and narrower residence time distributions. As a result, particle growth by coagulation - coalescence decreases leading to smaller primary particles that are mostly pure LTO exhibiting high C-rate performance with more than 120 mAh/g galvanostatic specific charge at 40C, outperforming commercial LTO. The effect of AE on FSP-made particle characteristics is demonstrated also in combustion synthesis of LiFePO4 and ZrO2.

  5. Feeding tube insertion - gastrostomy (United States)

    ... this page: // Feeding tube insertion - gastrostomy To use the sharing features on this page, please enable JavaScript. A gastrostomy feeding tube insertion is the placement of a feeding ...

  6. Neural Tube Defects (United States)

    Neural tube defects are birth defects of the brain, spine, or spinal cord. They happen in the ... that she is pregnant. The two most common neural tube defects are spina bifida and anencephaly. In ...

  7. Scaling of turbulent flame speed for expanding flames with Markstein diffusion considerations. (United States)

    Chaudhuri, Swetaprovo; Wu, Fujia; Law, Chung K


    In this paper we clarify the role of Markstein diffusivity, which is the product of the planar laminar flame speed and the Markstein length, on the turbulent flame speed and its scaling, based on experimental measurements on constant-pressure expanding turbulent flames. Turbulent flame propagation data are presented for premixed flames of mixtures of hydrogen, methane, ethylene, n-butane, and dimethyl ether with air, in near-isotropic turbulence in a dual-chamber, fan-stirred vessel. For each individual fuel-air mixture presented in this work and the recently published iso-octane data from Leeds, normalized turbulent flame speed data of individual fuel-air mixtures approximately follow a Re_{T,f}^{0.5} scaling, for which the average radius is the length scale and thermal diffusivity is the transport property of the turbulence Reynolds number. At a given Re_{T,f}^{}, it is experimentally observed that the normalized turbulent flame speed decreases with increasing Markstein number, which could be explained by considering Markstein diffusivity as the leading dissipation mechanism for the large wave number flame surface fluctuations. Consequently, by replacing thermal diffusivity with the Markstein diffusivity in the turbulence Reynolds number definition above, it is found that normalized turbulent flame speeds could be scaled by Re_{T,M}^{0.5} irrespective of the fuel, equivalence ratio, pressure, and turbulence intensity for positive Markstein number flames.

  8. Fire safety in space - Investigating flame spread interaction over wires (United States)

    Citerne, Jean-Marie; Dutilleul, Hugo; Kizawa, Koki; Nagachi, Masashi; Fujita, Osamu; Kikuchi, Masao; Jomaas, Grunde; Rouvreau, Sébastien; Torero, Jose L.; Legros, Guillaume


    A new rig for microgravity experiments was used for the study flame spread of parallel polyethylene-coated wires in concurrent and opposed airflow. The parabolic flight experiments were conducted at small length- and time scales, i.e. typically over 10 cm long samples for up to 20 s. For the first time, the influence of neighboring spread on the mass burning rate was assessed in microgravity. The observations are contrasted with the influence characterized in normal gravity. The experimental results are expected to deliver meaningful guidelines for future, planned experiments at a larger scale. Arising from the current results, the issue of the potential interaction among spreading flames also needs to be carefully investigated as this interaction plays a major role in realistic fire scenarios, and therefore on the design of the strategies that would allow the control of such a fire. Once buoyancy has been removed, the characteristic length and time scales of the different modes of heat and mass transfer are modified. For this reason, interaction among spreading flames may be revealed in microgravity, while it would not at normal gravity, or vice versa. Furthermore, the interaction may lead to an enhanced spread rate when mutual preheating dominates or, conversely, a reduced spread rate when oxidizer flow vitiation is predominant. In more general terms, the current study supports both the SAFFIRE and the FLARE projects, which are large projects with international scientific teams. First, material samples will be tested in a series of flight experiments (SAFFIRE 1-3) conducted in Cygnus vehicles after they have undocked from the ISS. These experiments will allow the study of ignition and possible flame spread in real spacecraft conditions, i.e. over real length scale samples within real time scales. Second, concomitant research conducted within the FLARE project is dedicated to the assessment of new standard tests for materials that a spacecraft can be composed of

  9. Flame spray deposition of porous catalysts on surfaces and in microsystems

    DEFF Research Database (Denmark)

    Thybo, Susanne; Jensen, Søren; Johansen, Johnny;


    . With shadow masks, porous catalyst layers can be deposited selectively into microchannels. Using Au/TiO$_2$ as test catalyst and CO-oxidation as test reaction, it is found that the apparent activation energy of the deposited catalyst is similar to what is normally seen for supported gold catalysts...... in the literature. The surface area of the deposited material is more than twice as large as when the flame-produced material is collected on a filter at the outlet of the flame reactor unit....

  10. Integrity Assessment of GOH Heater Tube

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Bong Sang; Hong, J. H.; Oh, Y. J.; Yoon, J. H.; Oh, J. M. [Korea Atomic Energy Research Institute, Taejon (Korea, Republic of)


    An assessment of structural integrity of ASTM A312-TP347 GOH heater tube was performed. The surface notches which had been produced during tube manufacturing process were analyzed microscopically. Chemical analysis, hardness tests, tensile tests, and J-Integral fracture resistance tests were carried out to compare the mechanical properties with those of the material specification and also with the other material of the same type. The test results showed the mechanical properties of the GOH tube material are within the specification range. An elastic-plastic fracture mechanics analysis based on the DPFAD method reveals the tube an appropriate safety margin for the normal operation. 13 refs., 5 tabs., 24 figs. (author)

  11. Laminar Soot Processes Experiment Shedding Light on Flame Radiation (United States)

    Urban, David L.


    The Laminar Soot Processes (LSP) experiment investigated soot processes in nonturbulent, round gas jet diffusion flames in still air. The soot processes within these flames are relevant to practical combustion in aircraft propulsion systems, diesel engines, and furnaces. However, for the LSP experiment, the flames were slowed and spread out to allow measurements that are not tractable for practical, Earth-bound flames.

  12. Flaming: More than a Necessary Evil for Academic Mailing Lists? (United States)

    Wang, Hongjie


    States that although Internet "gurus" advocate that users refrain from "flaming," in fact, flaming permeates the Internet. Explores the nature of flaming in its characteristics and forms as seen in academic discussion groups. Argues that flaming educates the ignorant, tames the uncouth, and promotes effective communication. (PA)

  13. A rapid, partial leach and organic separation for the sensitive determination of Ag, Bi, Cd, Cu, Mo, Pb, Sb, and Zn in surface geologic materials by flame atomic absorption (United States)

    Viets, J.G.; Clark, J.R.; Campbell, W.L.


    A solution of dilute hydrochloric acid, ascorbic acid, and potassium iodide has been found to dissolve weakly bound metals in soils, stream sediments, and oxidized rocks. Silver, Bi, Cd, Cu, Mo, Pb, Sb, and Zn are selectively extracted from this solution by a mixture of Aliquat 336 (tricaprylyl methyl ammonium chloride) and MIBK (methyl isobutyl ketone). Because potentially interfering major and minor elements do not extract, the organic separation allows interference-free determinations of Ag and Cd to the 0.05 ppm level, Mo, Cu, and Zn to 0.5 ppm, and Bi, Pb, and Sb to 1 ppm in the sample using flame atomic absorption spectroscopy. The analytical absorbance values of the organic solution used in the proposed method are generally enhanced more than threefold as compared to aqueous solutions, due to more efficient atomization and burning characteristics. The leaching and extraction procedures are extremely rapid; as many as 100 samples may be analyzed per day, yielding 800 determinations, and the technique is adaptable to field use. The proposed method was compared to total digestion methods for geochemical reference samples as well as soils and stream sediments from mineralized and unmineralized areas. The partial leach showed better anomaly contrasts than did total digestions. Because the proposed method is very rapid and is sensitive to pathfinder elements for several types of ore deposits, it should be useful for reconnaissance surveys for concealed deposits. ?? 1984.

  14. Improve seawater cooling with titanium finned tubes

    Energy Technology Data Exchange (ETDEWEB)

    O' Donnell J. (High Performance Tube, Inc., Warren, NJ (United States))


    Seawater offers an endless supply of cooling water for these coastal processing facilities. But users must address seawater's corrosive nature in selecting construction materials for heat exchangers. Copper-nickel or carbon steel tubing fails continually under seawater service. This paper reports that titanium tubes, once thought to be too expensive a material for heat exchanger tubing, offer a unique combination of high material strength, excellent resistance to corrosion, and endurance to erosion by seawater. Titanium's superior physical properties in combination with enhanced surface area of low finned tubing perform the same heat duty with half the lineal footage of traditional heat exchanger tubes. High density low finned tubes multiply heat transfer capacity by a factor of two compared to plain tube. The technology applies in retrofit and original equipment manufacture (OEM) situations. It works best when the ratio of heat transfer coefficients is 2:1 or higher between the seawater coolant and shellside flow being cooled.

  15. Flame retardants: Dust - And not food - Might be the risk. (United States)

    de Boer, J; Ballesteros-Gómez, A; Leslie, H A; Brandsma, S H; Leonards, P E G


    Flame retardants (FRs) are used to delay ignition of materials such as furniture and electric and electronic instruments. Many FRs are persistent and end up in the environment. Environmental studies on flame retardants (FRs) took off in the late 1990s. Polybrominated diphenylethers (PBDEs) appeared to be bioaccumulative and were found in many organisms all over the world. When PBDEs were banned or their production voluntarily terminated, alternatives appeared on the market that often had similar properties or were of more concern due to their toxicity such as halogenated phosphorus-based FRs. Here we show that in spite of the ban on PBDEs more brominated FRs are being produced, an increasing number of other FRs is being applied and FR levels in our homes are much higher than in the outdoor environment. While nowadays we live in better isolated houses and sit in front of the computer or television, on flame retarded upholstery, we are at risk due to the toxic effects of a suite of FRs. The high exposure to these substances indoors calls for better risk assessments that include mixture effects.

  16. Mapping physicochemical surface modifications of flame-treated polypropylene

    Directory of Open Access Journals (Sweden)

    S. Farris


    Full Text Available The aim of this work was to investigate how the surface morphology of polypropylene (PP is influenced by the surface activation mediated by a flame obtained using a mixture of air and propane under fuel-lean (equivalence ratio φ = 0.98 conditions. Morphological changes observed on flamed samples with smooth (S, medium (M, and high (H degree of surface roughness were attributed to the combined effect of a chemical mechanism (agglomeration and ordering of partially oxidized intermediate-molecular-weight material with a physical mechanism (flattening of the original roughness by the flame’s high temperature. After two treatments, the different behavior of the samples in terms of wettability was totally reset, which made an impressive surface energy of ~43 mJ•m–2 possible, which is typical of more hydrophilic polymers (e.g., polyethylene terephthalate – PET. In particular, the polar component was increased from 1.21, 0.08, and 0.32 mJ•m–2 (untreated samples to 10.95, 11.20, and 11.17 mJ•m–2 for the flamed samples S, M, and H, respectively, an increase attributed to the insertion of polar functional groups (hydroxyl and carbonyl on the C–C backbone, as demonstrated by the X-ray photoelectron spectroscopy results.

  17. Volumetric flame synthesis of well-defined molybdenum oxide nanocrystals. (United States)

    Merchan-Merchan, Wilson; Saveliev, Alexei V; Desai, Milind


    Well-defined faceted inorganic Mo oxide nanocrystals are synthesized in the gas phase using a solid-fed-precursor flame synthesis method. The solid crystals have rectangular cross-section with characteristic size of 10-20 nm and with lengths ranging from 50 nm to a few hundred nanometres. A 1 mm diameter high purity Mo probe introduced in the oxygen-rich part of the flame serves as the material source. A combination of the strong temperature gradient and varying chemical species concentrations within the flame volume provides the ideal conditions for the rapid and direct formation of these unique nanocrystals. Oxidation and evaporation of MoO3 in the oxygen-rich zone are followed by reduction to MoO2 in the lower temperature, more fuel-rich zone. The MoO3 vapours formed are pushed in the direction of the gas flow and transformed into mature well-defined convex polyhedron nanocrystals bounded with six faces resembling rectangular parallelepipeds.

  18. Volumetric flame synthesis of well-defined molybdenum oxide nanocrystals

    Energy Technology Data Exchange (ETDEWEB)

    Merchan-Merchan, Wilson; Desai, Milind [School of Aerospace and Mechanical Engineering, University of Oklahoma, Norman, OK 73019 (United States); Saveliev, Alexei V, E-mail: wmerchan-merchan@ou.ed [Department of Mechanical and Aerospace Engineering, North Carolina State University, Raleigh, NC 27695 (United States)


    Well-defined faceted inorganic Mo oxide nanocrystals are synthesized in the gas phase using a solid-fed-precursor flame synthesis method. The solid crystals have rectangular cross-section with characteristic size of 10-20 nm and with lengths ranging from 50 nm to a few hundred nanometres. A 1 mm diameter high purity Mo probe introduced in the oxygen-rich part of the flame serves as the material source. A combination of the strong temperature gradient and varying chemical species concentrations within the flame volume provides the ideal conditions for the rapid and direct formation of these unique nanocrystals. Oxidation and evaporation of MoO{sub 3} in the oxygen-rich zone are followed by reduction to MoO{sub 2} in the lower temperature, more fuel-rich zone. The MoO{sub 3} vapours formed are pushed in the direction of the gas flow and transformed into mature well-defined convex polyhedron nanocrystals bounded with six faces resembling rectangular parallelepipeds.

  19. Ignition, Flame Structure and Near-Wall Burning in Transverse Hydrogen Jets in Supersonic Crossflow (United States)

    Gamba, Mirko; Godfrey Mungal, M.; Hanson, Ronald K.


    The work aims at investigating near-wall ignition and flame structure in transverse underexpanded hydrogen jets in high-enthalpy supersonic crossflows generated in an expansion tube. Crossflow conditions are held fixed at M=2.4, p=40 kPa and T 1400 K, while jet-to-crossflow momentum flux ratios J in the range 0.3-5.0 are considered. Schlieren and OH^* chemiluminescence imaging are used to characterize flow structure, ignition and flame penetration, while the instantaneous reaction zone is identified with planar laser-induced fluorescence imaging of OH on side- and plan-view planes. The upstream separation length is found to scale as J^0.44D (D jet diameter). Similarly, the ignition point xig strongly depends on J: xig tends to a limiting value of ˜22D as J->0, and the flame is anchored in the upstream recirculation region and lee-side of the jet for J>3. Flame penetration is well described by the traditional form k(x/DJ)^m where both k and m are found to depend on J but these parameters reach a limiting value of k 1 and m 0.3 for J>2. The roles of the unsteady bow shock, the separation and recirculation regions on the near-wall ignition, stabilization and mixing at large J are discussed.

  20. Flame Atmospheric Pressure Chemical Ionization Coupled with Negative Electrospray Ionization Mass Spectrometry for Ion Molecule Reactions (United States)

    Cheng, Sy-Chyi; Bhat, Suhail Muzaffar; Shiea, Jentaie


    Flame atmospheric pressure chemical ionization (FAPCI) combined with negative electrospray ionization (ESI) mass spectrometry was developed to detect the ion/molecule reactions (IMRs) products between nitric acid (HNO3) and negatively charged amino acid, angiotensin I (AI) and angiotensin II (AII), and insulin ions. Nitrate and HNO3-nitrate ions were detected in the oxyacetylene flame, suggesting that a large quantity of nitric acid (HNO3) was produced in the flame. The HNO3 and negatively charged analyte ions produced by a negative ESI source were delivered into each arm of a Y-shaped stainless steel tube where they merged and reacted. The products were subsequently characterized with an ion trap mass analyzer attached to the exit of the Y-tube. HNO3 showed the strongest affinity to histidine and formed (Mhistidine-H+HNO3)- complex ions, whereas some amino acids did not react with HNO3 at all. Reactions between HNO3 and histidine residues in AI and AII resulted in the formation of dominant [MAI-H+(HNO3)]- and [MAII-H+(HNO3)]- ions. Results from analyses of AAs and insulin indicated that HNO3 could not only react with basic amino acid residues, but also with disulfide bonds to form [M-3H+(HNO3)n]3- complex ions. This approach is useful for obtaining information about the number of basic amino acid residues and disulfide bonds in peptides and proteins.

  1. The dilution effect on the extinction of wall diffusion flame

    Directory of Open Access Journals (Sweden)

    Ghiti Nadjib


    Full Text Available The dynamic process of the interaction between a turbulent jet diffusion methane flame and a lateral wall was experimentally studied. The evolution of the flame temperature field with the Nitrogen dilution of the methane jet flame was examined. The interaction between the diffusion flame and the lateral wall was investigated for different distance between the wall and the central axes of the jet flame. The dilution is found to play the central role in the flame extinction process. The flame response as the lateral wall approaches from infinity and the increasing of the dilution rate make the flame extinction more rapid than the flame without dilution, when the nitrogen dilution rate increase the flame temperature decrease.

  2. Structure of a poly(ethylene) opposed flow diffusion flame

    Energy Technology Data Exchange (ETDEWEB)

    Pitz, W.J.; Brown, N.J.; Sawyer, R.F.


    Structural measurements were obtained and compared with other investigations of diffusion flames. Departures from the commonly assumed collapsed flame model of laminar diffusion flames were observed in terms of excessive CO concentrations and oxygen penetration into the fuel side of the flame. An upper bound on the importance of oxygen diffusion to the fuel surface and subsequent surface oxidation was placed at 20% of the energy required for fuel pyrolysis, with the remainder of the energy being delivered to the surface from the flame through heat transfer processes. As the oxygen concentration in the oxidizer flow was decreased and extinction conditions approached, the CO/CO/sub 2/ ratio at the flame increased slightly, the oxygen concentration at the luminous flame zone decreased, the flame stand-off distance decreased, and the flame temperature decreased. Radial similarity in the composition and temperature profiles was established experimentally which confirms predictions and greatly simplifies the modeling of the opposed flow diffusion flame.

  3. Etude comparative de tubes en matériaux composites en vue de l'application à l'exploitation des hydrocarbures en mer profonde Comparative Study of Composite-Material Tubes with a View to Their Use for Deep Offshore Hydrocarbon Production

    Directory of Open Access Journals (Sweden)

    Bonavent G.


    Full Text Available Les prévisions de développement de la production pétrolière en mer profonde font apparaître de nouveaux besoins en tubes légers et à haute résistance pour les liaisons verticales entre les têtes de puits sous-marines et les plates-formes flottantes, et les conduites immergées par grand fond. Certains matériaux composites peuvent répondre à ces besoins et présentent en outre l'avantage d'une excellente résistance à la corrosion dans l'environnement marin. Toutefois, les choix sont imposés essentiellement par des contraintes d'ordre mécanique. On cherche ici à comparer, par rapport à l'acier, les avantages de deux types de matériaux composites - les composites acier-résine - les composites fibres-résine dont on résume les principales caractéristiques et les domaines d'applications possibles en fonction des spécifications pétrolières Development forecosts for deep offshore petroleum production bring out new needs for light tubes for vertlcaf linksbetween subsea wellheads and floating piatforms as well as for subsea pipelines ut great depths. Some composite materials moy meet such requirements while also hoving the advantoge of high résistance ta corrosion in a marine environment. However, the choices are mainly governed by stresses of a mechanical nature. Compared with steel, this article seeks ta describe the advantages of the following two types of composite materials : (il steel-resin composites, and (ii fiber-resin composites. The leading properties and the possible arecs of application are summed up as a function of petroleum specifications.

  4. 高温熔融盐壳管式相变换热器的传热特性%Heat Transfer Performances of High-Temperature Shell-Tube Heat Exchanger with Molten-Salt Phase Change Materials

    Institute of Scientific and Technical Information of China (English)

    左远志; 杨晓西; 丁静


    建立了高温熔融盐壳管式相变换热器的同心套管模型.采用Fluent软件,分析了在考虑相变区域自然对流条件下,熔融盐流体与相变材料的物性参数、内管进口温度与进口流向等因素对液相率与熔化时间的影响,并在熔融盐传热-蓄热实验平台上进行了试验研究.发现:考虑相变区域自然对流时,总的熔化时间减少16.2%;模拟得到的壳侧相变材料温度随时间的变化趋势与实验结果趋于一致.结果表明,可采用熔融盐相变区域特殊测点温度超过相变材料的熔点,并升至与内管流体进口温度相近时所耗费的时间作为壳管式相变换热器内相变材料完全熔化的判据.%In this paper, first, a concentric circular tube model for the shell-tube heat exchanger with molten-salt phase change materials (PCMs) is established. Then, the liquid fraction and the total melting time, which are affected by the thermal-physical parameters of the molten salt fluid and the PCMs as well as by the inlet velocity and the flow direction of the inner tube, are analyzed with Fluent, by taking into consideration the natural convection in the PCMs region. Finally, some experiments are carried out on a test platform of molten-salt heat transfer. The resuits show that the total melting time nearly decreases by 16. 2% considering the natural convection in the PCMs region, and that the simulated temperature of PCMs at the shell side varies with time,which has a tendency similar to that of the experimental results. Thus, it comes to the conclusion that, when the temperature of the specific measuring point in the PCMs region exceeds the melting point of PCMs and rises to the tube inlet temperature, the correspending time cost can be used as the criterion of melting ending of PCMs.

  5. Flame Retardant Effects of Nano-Clinoptilolite on AcrylonitrileButadiene-Styrene (ABS Nano-Composite

    Directory of Open Access Journals (Sweden)

    Aboulfazl Barati


    Full Text Available In recent years, intumescent technology has found a place in polymer science as a method of providing flame retardance to polymeric materials. On heating, fire-retardant intumescent material restricts the action of the heat flux or flame. The proposed mechanism is based on charred layer acting as physical barrier, which slows down heat and mass transfer between the gas and the condensed phases. In this paper, the flammability of intumescent fire-retardant acrylonitrile-butadiene-styrene (ABS matrix composites consisting of hydromagnesite (HMg as an acid source and blowing agent, pentaerythritol (PER as a carbonisation agent and natural zeolite (clinoptilolite rich, Kansar Shargh as a synergistic agent were examined. The flammability of composites was characterized by limiting oxygen index (LOI measurement and horizontal burning tests. A synergistic effect in flame retardancy was observed when natural zeolites were used in combination with HMg and PER.

  6. Analysis of Manufacturing Bimetallic Tubes by the Cold Drawing Process

    Directory of Open Access Journals (Sweden)

    Halaczek D.


    Full Text Available Drawing processes apply to obtain the bimetallic tubes from the different metals and alloys, combined in the solid state, which significantly affects the specificity of this process. The manufacturing of bimetallic tubes by drawing process depends on many factors which include: preparation of the surface of materials joined in the solid state, the geometric parameters of the working tool, technological parameters of the drawing process (drawing speed, type of lubricant, the use of back pull etc.. Generally, the cold drawing process of producing the bimetallic tubes refers to metals which have high ductility (copper, aluminum, etc.. The tube sinking (tube drawing without a mandrel of bimetallic tubes together with joining them at the interface of the two metal in the solid-state is applied for tubes of the diameter range between 6 to 20 mm and based on of the reducing the diameter of the tube. However, a slight increase of wall thickness ca. 0.05 ÷ 0.10 mm can appear, which is not dangerous phenomenon in case of producing the bimetallic tubes by joining in the solid-state. The aim of the research was to investigate the technology of tubes drawing process from non-ferrous metal, drawing process of bimetallic tubes and the production of bimetallic tubes in layers composition: cooper Cu-ETP - brass CuZn37 and CuZn37 brass - copper Cu-ETP in the tube sinking process. The research program included: production of bimetallic tubes with a different composition (Cu- ETP-CuZn37 and CuZn37-Cu-ETP and a different percentage of the cross-section components; analysis of changes of tube wall thickness and the layer composition of the bimetallic tube, based on measurements on the workshop microscope; analysis of the material flow in the process of the bimetallic tubes production based on the measurements results of a profilograph CP-200.

  7. Aromatics oxidation and soot formation in flames

    Energy Technology Data Exchange (ETDEWEB)

    Howard, J.B.; Pope, C.J.; Shandross, R.A.; Yadav, T. [Massachusetts Institute of Technology, Cambridge (United States)


    This project is concerned with the kinetics and mechanisms of aromatics oxidation and soot and fullerenes formation in flames. The scope includes detailed measurements of profiles of stable and radical species concentrations in low-pressure one-dimensional premixed flames. Intermediate species identifications and mole fractions, fluxes, and net reaction rates calculated from the measured profiles are used to test postulated reaction mechanisms. Particular objectives are to identify and to determine or confirm rate constants for the main benzene oxidation reactions in flames, and to characterize fullerenes and their formation mechanisms and kinetics.

  8. Systems and methods for controlling flame instability

    KAUST Repository

    Cha, Min Suk


    A system (62) for controlling flame instability comprising: a nozzle (66) coupled to a fuel supply line (70), an insulation housing (74) coupled to the nozzle, a combustor (78) coupled to the nozzle via the insulation housing, where the combustor is grounded (80), a pressure sensor (82) coupled to the combustor and configured to detect pressure in the combustor, and an instability controlling assembly coupled to the pressure sensor and to an alternating current power supply (86), where, the instability controlling assembly can control flame instability of a flame in the system based on pressure detected by the pressure sensor.

  9. Novel Flame-Based Synthesis of Nanowires for Multifunctional Application (United States)


    laser-based diagnostics for in-situ Raman characterization of as- synthesized nanomaterials, (iv) flame synthesis of graphene , (v) flame synthesis of...laser- based diagnostics for in-situ Raman characterization of as-synthesized nanomaterials, (iv) flame synthesis of graphene , (v) flame synthesis of...Stephen D. Tse, Manish Chhowalla, Bernard H. Kear. Role of substrate, temperature, and hydrogen on the flame synthesis of graphene films, Proceedings

  10. Acoustically Forced Coaxial Hydrogen / Liquid Oxygen Jet Flames (United States)


    visualized for both reacting and nonreacting cases. The jet flame was studied unforced, without acoustics , and forced, with transverse acoustic waves in...liquid rocket injector flames react to acoustic waves . In this study, a representative coaxial gaseous hydrogen / liquid oxygen (LOX) jet flame is...hydrogen / liquid oxygen (LOX) jet flame is visualized for both reacting and nonreacting cases. The jet flame was studied unforced, without acoustics , and

  11. Chemical milling of Zircaloy tubing to produce integral OD spiral finned tubes (AWBA development program)

    Energy Technology Data Exchange (ETDEWEB)

    Horwood, W.A.


    A detailed process description is provided for producing integral spiral fins on the outside surface of Zircaloy nuclear fuel cladding tubes by masking with pressure sensitive tape strips and then chemical milling (pickling) the tube wall between the tape strips to leave the fins in relief. Fins up to 0.020 inch high by 0.05 to 0.12 inch wide were consistently produced on tubes having wall thickness of 0.008 inch or greater after fin pickling. Wall thickness uniformity was excellent. Information is provided on tube surface preparation to maximize tape mask adhesion time during pickling, acid chemistry control to prevent local tube wall thinning near the fin, and pickling techniques to promote uniform material removal. Simple fixture designs are described for quickly and conveniently applying the tape strips to the tube wall in an accurate spiral. 13 figures, 4 tables.

  12. An investigation on SA 213-Tube to SA 387-Tube plate using friction welding process

    Energy Technology Data Exchange (ETDEWEB)

    Rajan, S. Pandia; Kumaraswamidhas, L. A. [Indian Institute of Technology, Jharkhand (India); Kumaran, S. Senthil [RVS School of Engineering and Technology, Tamil Nadu (India); Muthukumaran, S. [National Institute of Technology, Tamil Nadu (India)


    Friction welding of tube to tube plate using an external tool (FWTPET) is a relatively newer solid state welding process used for joining tube to tube plate of either similar or dissimilar materials with enhanced mechanical and metallurgical properties. In the present study, FWTPET has been used to weld SA 213 (Grade T12) tube with SA 387 (Grade 22) tube plate. The welded samples are found to have satisfactory joint strength and the Energy dispersive X-ray analysis (EDX), X-ray diffraction (XRD) study showed that inter metallic compound is absent in the weld zone. The different weld joints have been identified and the phase composition is found using EDX and XRD. Microstructures have been analyzed using optical and Scanning electron microscopy (SEM). The mechanical properties such as hardness, compressive shear strength and peel test for different weld conditions are studied and the hardness survey revealed that there is increase in hardness at the weld interface due to grain refinement. The corrosion behavior for different weld conditions have been analyzed and the weld zone is found to have better corrosion resistance due to the influence of the grain refinement after FWTPET welding process. Hence, the present investigation is carried out to study the behavior of friction welded dissimilar joints of SA 213 tube and SA 387 tube plate joints and the results are presented. The present study confirms that a high quality tube to tube plate joint can be achieved using FWTPET process at 1120 rpm.

  13. Gastrostomy Tube Placement Without Nasogastric Tube: A Retrospective Evaluation in 85 Patients

    Energy Technology Data Exchange (ETDEWEB)

    Heberlein, Wolf E., E-mail:; Goodwin, Whitney J.; Wood, Clint E.; Yousaf, Muhammad; Culp, William C. [University of Arkansas for Medical Sciences, Department of Radiology (United States)


    Purpose: Our study evaluated techniques for percutaneous gastrostomy (G)-tube placement without the use of a nasogastric (NG) tube. Instead, direct puncture of a physiologic air bubble or effervescent-enhanced gastric bubble distention was performed in patients with upper digestive tract obstruction (UDTO) or psychological objections to NG tubes. Materials and Methods: A total of 886 patients underwent G-tube placement in our department during a period of 7 years. We present our series of 85 (9.6%) consecutive patients who underwent percutaneous G-tube placement without use of an NG tube. Results: Of these 85 patients, fluoroscopic guided access was attempted by direct puncture of a physiologically present gastric air bubble in 24 (28%) cases. Puncture of an effervescent-induced large gastric air bubble was performed in 61 (72%) patients. Altogether, 82 (97%) of 85 G tubes were successfully placed in this fashion. The three failures comprised refusal of effervescent, vomiting of effervescent, and one initial tube misplacement when a deviation from our standard technique occurred. Conclusion: The described techniques compare favorably with published large series on G-tube placement with an NG tube in place. The techniques are especially suited for patients with UDTO due to head, neck, or esophageal malignancies, but they should be considered as an alternative in all patients. Direct puncture of effervescent-enhanced gastric bubble distention is a safe, patient-friendly and effective technique.

  14. Effect of heavy ion irradiation and α+β phase heat treatment on oxide of Zr-2.5Nb pressure tube material (United States)

    Choudhuri, Gargi; Mukherjee, P.; Gayathri, N.; Kain, V.; Kiran Kumar, M.; Srivastava, D.; Basu, S.; Mukherjee, D.; Dey, G. K.


    Effect of heavy-ion irradiation on the crystalline phase transformation of oxide of Zr-2.5Nb alloys has been studied. The steam-autoclaved oxide of pressure tube is irradiated with 306 KeV Ar+9 ions at a dose of 3 × 1019 Ar+9/m2. The damage profile has been estimated using ;Stopping and Range of Ions in Matter; computer program. The variation of the crystal structure along the depth of the irradiated oxide have been characterized non-destructively by Grazing Incidence X-ray Diffraction technique and compared with unirradiated-oxide. The effect of different base metal microstructures on the characteristic of oxide has also been studied. Base metal microstructure as well as the cross-sectional oxide have been characterized using transmission electron microscope. Heavy ion irradiation can significantly alter the distribution of phases in the oxide of the alloy. The difference in chemical state of alloying element has also been found between unirradiated-oxide with that of irradiated-oxide using X-ray photo electron spectroscopy. Chemical state of Nb in steam autoclaved oxide is also altered when the base metal is α + β heat treated.

  15. Direct numerical simulations of non-premixed ethylene-air flames: Local flame extinction criterion

    KAUST Repository

    Lecoustre, Vivien R.


    Direct Numerical Simulations (DNS) of ethylene/air diffusion flame extinctions in decaying two-dimensional turbulence were performed. A Damköhler-number-based flame extinction criterion as provided by classical large activation energy asymptotic (AEA) theory is assessed for its validity in predicting flame extinction and compared to one based on Chemical Explosive Mode Analysis (CEMA) of the detailed chemistry. The DNS code solves compressible flow conservation equations using high order finite difference and explicit time integration schemes. The ethylene/air chemistry is simulated with a reduced mechanism that is generated based on the directed relation graph (DRG) based methods along with stiffness removal. The numerical configuration is an ethylene fuel strip embedded in ambient air and exposed to a prescribed decaying turbulent flow field. The emphasis of this study is on the several flame extinction events observed in contrived parametric simulations. A modified viscosity and changing pressure (MVCP) scheme was adopted in order to artificially manipulate the probability of flame extinction. Using MVCP, pressure was changed from the baseline case of 1 atm to 0.1 and 10 atm. In the high pressure MVCP case, the simulated flame is extinction-free, whereas in the low pressure MVCP case, the simulated flame features frequent extinction events and is close to global extinction. Results show that, despite its relative simplicity and provided that the global flame activation temperature is correctly calibrated, the AEA-based flame extinction criterion can accurately predict the simulated flame extinction events. It is also found that the AEA-based criterion provides predictions of flame extinction that are consistent with those provided by a CEMA-based criterion. This study supports the validity of a simple Damköhler-number-based criterion to predict flame extinction in engineering-level CFD models. © 2014 The Combustion Institute.

  16. High pressure flame system for pollution studies with results for methane-air diffusion flames (United States)

    Miller, I. M.; Maahs, H. G.


    A high pressure flame system was designed and constructed for studying nitrogen oxide formation in fuel air combustion. Its advantages and limitations were demonstrated by tests with a confined laminar methane air diffusion flame over the pressure range from 1 to 50 atm. The methane issued from a 3.06 mm diameter port concentrically into a stream of air contained within a 20.5 mm diameter chimney. As the combustion pressure is increased, the flame changes in shape from wide and convex to slender and concave, and there is a marked increase in the amount of luminous carbon. The height of the flame changes only moderately with pressure.

  17. Intercostal drainage tube or intracardiac drainage tube?

    Directory of Open Access Journals (Sweden)

    N Anitha


    Full Text Available Although insertion of chest drain tubes is a common medical practice, there are risks associated with this procedure, especially when inexperienced physicians perform it. Wrong insertion of the tube has been known to cause morbidity and occasional mortality. We report a case where the left ventricle was accidentally punctured leading to near-exsanguination. This report is to highlight the need for experienced physicians to supervise the procedure and train the younger physician in the safe performance of the procedure.

  18. Disinfection of Biofilms in Tubes with Ultraviolet Light

    DEFF Research Database (Denmark)

    Bak, Jimmy; Begovic, Tanja


    Bacterial biofilms on long-term catheters are a major source of infection. We demonstrate here the potential of UVC light emitting diodes (LED) for disinfection purposes in catheter like tubes contaminated with biofilm. We show that UVC Light propagation is possible through teflon tubes using...... that the UVC light attenuation inside the tube can be described by an exponential function depending of tube length and various loss mechanisms. The disinfection efficiency of the UVC diodes is demonstrated on tubes contaminated artificially with a Pseudomonas aeruginosa biofilm. The tubes were connected...... the liquid light guiding principle. If the refractive index of the liquid is higher than that of the tube material light is guided inside the tube by internal reflections. To obtain a high refractive index of the liquid sodium chloride in high concentrations is added to the aqueous solution. It is shown...

  19. Numerical modeling for flame dynamics and combustion processes in a two-sectional porous burner with a detailed chemistry

    Energy Technology Data Exchange (ETDEWEB)

    Shin, Young Jun; Kim, Yong Mo [Hanyang University, Seoul (Korea, Republic of)


    A two-dimensional model with the detailed chemistry and variable transport properties has been applied to numerically investigate the combustion processes and flame dynamics in the bilayer porous burner. To account for the velocity transition and diffusion influenced by solid matrix, porosity terms are included in the governing equations. Heat transfer coefficient is calculated by Nusselt number to reflect the effect of gas velocity, pore diameter, and material properties. The detailed chemistry is based on GRI 2.11. Numerical results indicate that the present approach is capable of the essential features of the premixed combustion in the porous media in terms of the precise flame structure, pollutant formation, and stabilization characteristics. In this bilayer porous burner, the heat transferred from the downstream flame zone is conducted to the upstream flame region through the solid matrix. This heat transfer process through the solid matrix substantially influences the flame structure and stabilization characteristics in the porous media. The predicted results are compared with experimental data in terms of temperature for gaseous mixture and solid matrix, CO and NO emission level. Based on numerical results, a precise comparison has been made for the freely propagating premixed flames and the premixed flames with a porous media for various inlet velocities.

  20. Theory of DDT in unconfined flames

    CERN Document Server

    Khokhlov, A M; Wheeler, J C; Wheeler, J Craig


    This paper outlines a theoretical approach for predicting the onset of detonation in unconfined turbulent flames which is relevant both to problems of terrestrial combustion and to thermonuclear burning in Type Ia supernovae. Two basic assumuptions are made: 1) the gradient mechanism is the inherent mechanism that leads to DDT in unconfined conditions, and 2) the sole mechanism for preparing the gradient in induction time is by turbulent mixing and local flame quenching. The criterion for DDT is derived in terms of the one-dimensional detonation wave thickness, the laminar flame speed, and the laminar flame thickness in the reactive gas. This approach gives a lower-bound criterion for DDT for conditions where shock preheating, wall effects, and interactions with obstacles are absent. Regions in parameter space where unconfined DDT can and cannot occur are determined. A subsequent paper will address these issues specifically in the astrophysical context.

  1. Recycling of plastic waste: Screening for brominated flame retardants (BFRs). (United States)

    Pivnenko, K; Granby, K; Eriksson, E; Astrup, T F


    Flame retardants are chemicals vital for reducing risks of fire and preventing human casualties and property losses. Due to the abundance, low cost and high performance of bromine, brominated flame retardants (BFRs) have had a significant share of the market for years. Physical stability on the other hand, has resulted in dispersion and accumulation of selected BFRs in the environment and receiving biota. A wide range of plastic products may contain BFRs. This affects the quality of waste plastics as secondary resource: material recycling may potentially reintroduce the BFRs into new plastic product cycles and lead to increased exposure levels, e.g. through use of plastic packaging materials. To provide quantitative and qualitative data on presence of BFRs in plastics, we analysed bromophenols (tetrabromobisphenol A (TBBPA), dibromophenols (2,4- and 2,6-DBP) and 2,4,6-tribromophenol (2,4,6-TBP)), hexabromocyclododecane stereoisomers (α-, β-, and γ-HBCD), as well as selected polybrominated diphenyl ethers (PBDEs) in samples of household waste plastics, virgin and recycled plastics. A considerable number of samples contained BFRs, with highest concentrations associated with acrylonitrile butadiene styrene (ABS, up to 26,000,000ngTBBPA/g) and polystyrene (PS, up to 330,000ng∑HBCD/g). Abundancy in low concentrations of some BFRs in plastic samples suggested either unintended addition in plastic products or degradation of higher molecular weight BFRs. The presence of currently restricted flame retardants (PBDEs and HBCD) identified in the plastic samples illustrates that circular material flows may be contaminated for extended periods. The screening clearly showed a need for improved documentation and monitoring of the presence of BFRs in plastic waste routed to recycling. Copyright © 2017. Published by Elsevier Ltd.

  2. Working session 1: Tubing degradation

    Energy Technology Data Exchange (ETDEWEB)

    Kharshafdjian, G. [Atomic Energy of Canada, Mississauga, Ontario (Canada); Turluer, G. [IPSN, Fontenay-aux-Roses (France)


    A general introductory overview of the purpose of the group and the general subject area of SG tubing degradation was given by the facilitator. The purpose of the session was described as to {open_quotes}develop conclusions and proposals on regulatory and technical needs required to deal with the issues of SG tubing degradation.{close_quotes} Types, locations and characteristics of tubing degradation in steam generators were briefly reviewed. The well-known synergistic effects of materials, environment, and stress and strain/strain rate, subsequently referred to by the acronym {open_quotes}MESS{close_quotes} by some of the group members, were noted. The element of time (i.e., evolution of these variables with time) was emphasized. It was also suggested that the group might want to consider the related topics of inspection capabilities, operational variables, degradation remedies, and validity of test data, and some background information in these areas was provided. The presentation given by Peter Millet during the Plenary Session was reviewed; Specifically, the chemical aspects and the degradation from the secondary side of the steam generator were noted. The main issues discussed during the October 1995 EPRI meeting on secondary side corrosion were reported, and a listing of the potential SG tube degradations was provided and discussed.

  3. The Choking Game on YouTube

    Directory of Open Access Journals (Sweden)

    Ellen K. Defenderfer MS


    Full Text Available The choking game (TCG is an adolescent activity in which asphyxiation is used to obtain a “high,” occasionally resulting in seizures or death. A plethora of TCG information is available through YouTube, though this content has not been evaluated recently. The current study described TCG as portrayed in YouTube videos and compared views and ratings of TCG videos to unrelated videos. The TCG videos demonstrated diverse methods of asphyxiation, with a minority showing injury to the participants. TCG videos were less likely to be commented on or rated positively than non–choking game videos. TCG prevention videos differed significantly from actual TCG videos in the way they depicted the social context of TCG. Thus, TCG videos are accessible through YouTube, but the prevention materials available on YouTube are not accurate or representative. Accurate and educational online prevention materials should be created to decrease the occurrence of TCG.

  4. Pulse Tube Refrigerator (United States)

    Matsubara, Yoichi

    The pulse tube refrigerator is one of the regenerative cycle refrigerators such as Stirling cycle or Gifford-McMahon cycle which gives the cooling temperature below 150 K down to liquid helium temperature. In 1963, W. E. Gifford invented a simple refrigeration cycle which is composed of compressor, regenerator and simple tube named as pulse tube which gives a similar function of the expander in Stirling or Gifford-McMahon cycle. The thermodynamically performance of this pulse tube refrigerator is inferior to that of other regenerative cycles. In 1984, however, Mikulin and coworkers made a significant advance in pulse tube configuration called as orifice pulse tube. After this, several modifications of the pulse tube hot end configuration have been developed. With those modifications, the thermodynamic performance of the pulse tube refrigerator became the same order to that of Stirling and Gifford-McMahon refrigerator. This article reviews the brief history of the pulse tube refrigerator development in the view point of its thermodynamically efficiency. Simplified theories of the energy flow in the pulse tube have also been described.

  5. Noninflammatory fallopian tube pathology in children

    Energy Technology Data Exchange (ETDEWEB)

    Merlini, Laura; Anooshiravani, Mehrak; Hanquinet, Sylviane [University Hospital HUG, Unit of Pediatric Radiology, Geneva (Switzerland); Vunda, Aaron [University Hospital, Clinic of Pediatric Surgery, Geneva (Switzerland); Borzani, Irene; Napolitano, Marcello [Ospedale Buzzi, Pediatric Radiology, Milan (Italy)


    Noninflammatory tubal abnormalities are rare in children and usually not well covered by traditional educational material. The presenting symptoms are nonspecific and are common to many other conditions, so its preoperative diagnosis is rarely made. The purpose of this study was to review the hospital charts and imaging findings in children and sexually inactive adolescents who showed fallopian tube pathology. Understanding of the pertinent findings of previous imaging examinations might assist radiologists in making the correct preoperative diagnosis and increase the likelihood of preserving the fallopian tubes. The clinical entities described in this article include isolated tubal torsion, paratubal cysts, hydrosalpinx, undescended/ectopic fallopian tube, and tubal inguinal hernia. (orig.)

  6. Research on environmental impact assessment of flame oxyacetylene welding processes

    Directory of Open Access Journals (Sweden)

    Gh. Amza


    Full Text Available This paper presents the factors that may cause pollution of the work environment when working with the oxyacetylene flame welding process. Experiments were performed using an oven that allows the analysis of all gases resulted in the welding process, but also enables their monitoring using a video camera, and the resulting film was processed in that the frames for each second of experimentation were extracted. The materials used in the experiments were S235JR steel as the base material, and as filler materials, E70S. In order to assess the impact on the work environment of this welding process, the pollution coefficient CP was defined based on the equation of the material balance.

  7. Flaming Pear Creative Pack1.0

    Institute of Scientific and Technical Information of China (English)



    Flaming Pear是个一直给我留下深刻印象的软件开发公司。我以前评论过很多这个公司的插件,每一次都是不错的经历。同样的优良传统同样体现在Flaming Pear的新品Creative Pack1.0

  8. A simple method for preparing superconducting FeSe pellets without sealing in evacuated silica tubes

    DEFF Research Database (Denmark)

    Grivel, Jean-Claude


    Superconducting tetragonal FeSe pellets were made by reacting mixtures of elemental Fe and Se powders in argon atmosphere without sealing in evacuated silica tubes. A simple tube furnace has been used. Although the tube's material consisted of quartz, an alumina tube could be used as well. X...

  9. NO concentration imaging in turbulent nonpremixed flames

    Energy Technology Data Exchange (ETDEWEB)

    Schefer, R.W. [Sandia National Laboratories, Livermore, CA (United States)


    The importance of NO as a pollutant species is well known. An understanding of the formation characteristics of NO in turbulent hydrocarbon flames is important to both the desired reduction of pollutant emissions and the validation of proposed models for turbulent reacting flows. Of particular interest is the relationship between NO formation and the local flame zone, in which the fuel is oxidized and primary heat release occurs. Planar imaging of NO provides the multipoint statistics needed to relate NO formation to the both the flame zone and the local turbulence characteristics. Planar imaging of NO has been demonstrated in turbulent flames where NO was seeded into the flow at high concentrations (2000 ppm) to determine the gas temperature distribution. The NO concentrations in these experiments were significantly higher than those expected in typical hydrocarbon-air flames, which require a much lower detectability limit for NO measurements. An imaging technique based on laser-induced fluorescence with sufficient sensitivity to study the NO formation mechanism in the stabilization region of turbulent lifted-jet methane flames.

  10. Synthesis of Nano-Particles in Flames

    DEFF Research Database (Denmark)

    Johannessen, Tue

    The scope of this work is to investigate the synthesis of aluminum oxide particles in flames from the combustion of an aluminum alkoxide precursor.A general introduction to particles formation in the gas phase is presented with emphasis on the mechanisms that control the particle morphology after...... for the analysis of particle formation in flames. Good results for a wide range of operating conditions were obtained. Therefore, the method should be useful as a tool for the optimization and/or design of flame processes for particle production.......The scope of this work is to investigate the synthesis of aluminum oxide particles in flames from the combustion of an aluminum alkoxide precursor.A general introduction to particles formation in the gas phase is presented with emphasis on the mechanisms that control the particle morphology after...... flame burner and a premixed burner with a precursor jet. The experimental setups and results are shown and discussed in detail. Alumina powder with specific surface area between 45 m2/g and 190 m2/g was obtained.Temperature and flow fields of the flame processes are analysed by numerical simulations...

  11. Conical quarl swirl stabilized non-premixed flames: flame and flow field interaction

    KAUST Repository

    Elbaz, Ayman M.


    The flame-flow field interaction is studied in non-premixed methane swirl flames stabilized in quartz quarl via simultaneous measurements of the flow field using a stereo PIV and OH-PLIF at 5 KHz repetition rate. Under the same swirl intensity, two flames with different fuel jet velocity were investigated. The time-averaged flow field shows a unique flow pattern at the quarl exit, where two recirculation vortices are formed; a strong recirculation zone formed far from the quarl exit and a larger recirculation zone extending inside the quarl. However, the instantaneous images show that, the flow pattern near the quarl exit plays a vital role in the spatial location and structure of the reaction zone. In the low fuel jet velocity flame, a pair of vortical structures, located precisely at the corners of the quarl exit, cause the flame to roll up into the central region of low speed flow, where the flame sheet then tracks the axial velocity fluctuations. The vorticity field reveals a vortical structure surrounding the reaction zones, which reside on a layer of low compressive strain adjacent to that vortical structure. In the high fuel jet velocity flame, initially a laminar flame sheet resides at the inner shear layer of the main jet, along the interface between incoming fresh gas and high temperature recirculating gas. Further downstream, vortex breakdown alters the flame sheet path toward the central flame region. The lower reaction zones show good correlation to the regions of maximum vorticity and track the regions of low compressive strain associated with the inner shear layer of the jet flow. In both flames the reactions zones conform the passage of the large structure while remaining inside the low speed regions or at the inner shear layer.

  12. Unsaturated polyester/expanded polystyrene composite : thermal characteristics and flame retardancy effects (United States)

    Mohamed, R.; Syed Mustafa, S. A.; Norizan, Mohd N.; Amerudin, L. S.


    Panels for energy efficient buildings has to meet certain requirements such as low thermal conductivity and inherent flame retardancy characteristics, before being eligible for buildings and construction applications. Expanded Polystyrene (EPS) as waste material had been incorporated as filler in Unsaturated Polyester Resin (UPR) composites. The composite are fabricated as flat panel window or glazing to replace glass. In this study, different EPS content incorporated was found to affect flammability and thermal characteristics. Core additives such as Flame Retardant (FR) and Antioxidant (AO) were added to the composite for imparting flame retardancy and prevent aging of the composite. The result obtained via the comparison of the various composite systems studied had revealed that organic and metal oxide flame retardant (FR) additives imparts higher flame retardancy levels than others, but each type of additives had interacted with the polymeric matrixes differently. The thermal conductivity, k value, as measured from a handheld thermal probe had showed a minimum of ~0.124 W/m.K for the 1%wt zinc oxide sample, while the highest k value of ~0.280 W/m.K was exhibited by the 2%wt tin oxide sample. The first 1%wt of either metal oxide FR initially decreases both the thermal conductivity, k value; and volumetric specific heat, Cp,v of the samples. At 2%wt, increases in k value were obtained. The flammability was reduced with the use of organic Phosphate Ester FR, which had reduced the flame speed to about 37.1% of the original flame speed. With the equivalent mixture of all three organic FR system, the flammability reduced less than 30%, while the metal oxide FR additive doesn't reduces the flammability.


    Directory of Open Access Journals (Sweden)

    Yin Ling Lam


    Full Text Available Flammability properties of plasma pretreated cotton fabrics subjected to flame-retardant treatment were studied. Plasma pretreatment, using an atmospheric pressure plasma jet (APPJ, was applied to cotton fabrics to enhance material properties, while retaining inherent advantages of the substrates. An organic phosphorus compound (flame-retardant agent, FR together with a melamine resin (crosslinking agent, CL and phosphoric acid (catalyst, PA were used. Titanium dioxide (TiO2 or nano-TiO2 was used as a co-catalyst for cotton fabrics to improve treatment effectiveness and minimize side effects. Surface morphology of plasma pretreated cotton specimens subjected to flame-retardant treatment showed a roughened and wrinkled fabric surface with high deposition of the finishing agent, caused by an etching effect of plasma and attack of acidic FR. Combustibility of FR-CL-PA-TiO2 and FR-CL-PA-Nano-TiO2 treated fabrics was evaluated by a 45° flammability test. FR-CL-PA-treated specimens showed superior flame-retardancy, which was further improved by plasma pretreatment and addition of metal oxide as a co-catalyst. However, in comparison with the control sample, flame-retardant-treated cotton specimens had lower breaking load and tearing strength, resulting from side effects of the crosslinking agent used, while plasma pretreatment might compensate for the reduction in tensile strength caused by flame-retardant agents. In addition, both plasma pretreatment and metal oxide co-catalyst added in the flame-retardant finishing improved the crosslinking process between FR and cotton fabric, minimizing formation of free formaldehyde and allowing the use of FR in industry.

  14. Brominated and organophosphate flame retardants in selected consumer products on the Japanese market in 2008

    Energy Technology Data Exchange (ETDEWEB)

    Kajiwara, Natsuko, E-mail: [Research Center for Material Cycles and Waste Management, National Institute for Environmental Studies, 16-2 Onogawa, Tsukuba, Ibaraki 305-8506 (Japan); Noma, Yukio; Takigami, Hidetaka [Research Center for Material Cycles and Waste Management, National Institute for Environmental Studies, 16-2 Onogawa, Tsukuba, Ibaraki 305-8506 (Japan)


    Highlights: {yields} We examined the flame retardants in electronics, curtains, wallpaper and insulator. {yields} Use of alternative brominated and organophosphate flame retardants was suggested. {yields} All the products investigated also contained PBDEs, TBBPA and polybromophenols. {yields} Incorporation of recycled materials containing hazardous substance was suggested. - Abstract: The concentrations of traditional brominated flame retardants (BFRs) and organophosphate flame retardants (OPFRs) in new consumer products, including electronic equipment, curtains, wallpaper, and building materials, on the Japanese market in 2008 were investigated. Although some components of the electronic equipment contained bromine at concentrations on the order of percent by weight, as indicated by X-ray fluorescence analysis, the bromine content could not be fully accounted for by the BFRs analyzed in this study, which included polybrominated diphenylethers, decabromodiphenyl ethane, tetrabromobisphenol A, polybromophenols, and hexabromocyclododecanes. These results suggest the use of alternative BFRs such as newly developed formulations derived from tribromophenol, tetrabromobisphenol A, or both. Among the 11 OPFRs analyzed, triphenylphosphate was present at the highest concentrations in all the products investigated, which suggests the use of condensed-type OPFRs as alternative flame retardants, because they contain triphenylphosphate as an impurity. Tripropylphosphate was not detected in any samples; and trimethylphosphate, tributyl tris(2-butoxyethyl)phosphate, and tris(1,3-dichloro-2-propyl)phosphate were detected in only some components and at low concentrations. Note that all the consumer products evaluated in this study also contained traditional BFRs in amounts that were inadequate to impart flame retardancy, which implies the incorporation of recycled plastic materials containing BFRs that are of global concern.

  15. Morphological control of heterostructured nanowires synthesized by sol-flame method (United States)

    Luo, Runlai; Cho, In Sun; Feng, Yunzhe; Cai, Lili; Rao, Pratap M.; Zheng, Xiaolin


    Heterostructured nanowires, such as core/shell nanowires and nanoparticle-decorated nanowires, are versatile building blocks for a wide range of applications because they integrate dissimilar materials at the nanometer scale to achieve unique functionalities. The sol-flame method is a new, rapid, low-cost, versatile, and scalable method for the synthesis of heterostructured nanowires, in which arrays of nanowires are decorated with other materials in the form of shells or chains of nanoparticles. In a typical sol-flame synthesis, nanowires are dip-coated with a solution containing precursors of the materials to be decorated, then dried in air, and subsequently heated in the post-flame region of a flame at high temperature (over 900°C) for only a few seconds. Here, we report the effects of the precursor solution on the final morphology of the heterostructured nanowire using Co3O4 decorated CuO nanowires as a model system. When a volatile cobalt salt precursor is used with sufficient residual solvent, both solvent and cobalt precursor evaporate during the flame annealing step, leading to the formation of Co3O4 nanoparticle chains by a gas-solid transition. The length of the nanoparticle chains is mainly controlled by the temperature of combustion of the solvent. On the other hand, when a non-volatile cobalt salt precursor is used, only the solvent evaporates and the cobalt salt is converted to nanoparticles by a liquid-solid transition, forming a conformal Co3O4 shell. This study facilitates the use of the sol-flame method for synthesizing heterostructured nanowires with controlled morphologies to satisfy the needs of diverse applications.

  16. Flame Synthesis Of Single-Walled Carbon Nanotubes And Nanofibers (United States)

    Wal, Randy L. Vander; Berger, Gordon M.; Ticich, Thomas M.


    Carbon nanotubes are widely sought for a variety of applications including gas storage, intercalation media, catalyst support and composite reinforcing material [1]. Each of these applications will require large scale quantities of CNTs. A second consideration is that some of these applications may require redispersal of the collected CNTs and attachment to a support structure. If the CNTs could be synthesized directly upon the support to be used in the end application, a tremendous savings in post-synthesis processing could be realized. Therein we have pursued both aerosol and supported catalyst synthesis of CNTs. Given space limitations, only the aerosol portion of the work is outlined here though results from both thrusts will be presented during the talk. Aerosol methods of SWNT, MWNT or nanofiber synthesis hold promise of large-scale production to supply the tonnage quantities these applications will require. Aerosol methods may potentially permit control of the catalyst particle size, offer continuous processing, provide highest product purity and most importantly, are scaleable. Only via economy of scale will the cost of CNTs be sufficient to realize the large-scale structural and power applications on both earth and in space. Present aerosol methods for SWNT synthesis include laser ablation of composite metalgraphite targets or thermal decomposition/pyrolysis of a sublimed or vaporized organometallic [2]. Both approaches, conducted within a high temperature furnace, have produced single-walled nanotubes (SWNTs). The former method requires sophisticated hardware and is inherently limited by the energy deposition that can be realized using pulsed laser light. The latter method, using expensive organometallics is difficult to control for SWNT synthesis given a range of gasparticle mixing conditions along variable temperature gradients; multi-walled nanotubes (MWNTs) are a far more likely end products. Both approaches require large energy expenditures and

  17. Study on Thermo-Conductive Plastic Finned Tube Radiators

    Institute of Scientific and Technical Information of China (English)


    This paper discusses thermo-conductive plastic finned tube radiators used in water saving type power stations.First,the development of thermo-conductive plastics is introduced.Second,in order to determine the rational geometric dimensions of thermo-conductive plastic finned tubes,an objective function which takes the minimum volume of the consumed material for making finned tubes as an object is introduced.On the basis of the function,the economy comparison between thermo-conductive plastic finned tubes and metal finned tubes is conducted.

  18. Polybrominated diphenyl ethers listed as Stockholm Convention POPs, other brominated flame retardants and heavy metals in e-waste polymers in Nigeria. (United States)

    Sindiku, Omotayo; Babayemi, Joshua; Osibanjo, Oladele; Schlummer, Martin; Schluep, Mathias; Watson, Alan; Weber, Roland


    Polybrominated diphenyl ethers (PBDEs) were the first brominated persistent organic pollutants (POPs) listed in the Stockholm Convention. Parties to the convention are currently establishing inventories for developing action plans for the environmentally sound management of PBDE-containing materials. The major use of commercial octabromodiphenyl ether (c-OctaBDE) has been in casings from cathode ray tube (CRT) TVs and computer monitors. Large quantities of used e-waste and electronic equipment have been exported to developing countries with Nigeria being a major importer in Africa. The casings from 382 TVs and computers imported from major world regions to Nigeria were sampled in backyards and waste dumps. The samples were screened with X-ray flourescence (XRF) for bromine and analysed by gas chromatography/ electron capture detection (GC/ECD) for brominated flame retardants (BFRs). A high proportion of the CRT casings (61 %) contained more than 10,000 ppm bromine from BFRs. Decabromodiphenyl ether (DecaBDE) was the major flame retardant used in TV sets and tetrabromobisphenol A (TBBPA) for computer CRTs.The screening suggests that average PBDE levels (of c-OctaBDE + DecaBDE) in Nigerian-stockpiled CRT casings were 1.1 % for TV and 0.13 % for PC CRTs. These are above the Restriction of Hazardous Substances (RoHS) limit and should be separated for RoHS compliant recycling. The Nigerian e-waste inventory of 237,000 t of CRT plastic would therefore contain approx. 594 t c-OctaBDE and 1,880 t of DecaBDE. In Nigeria, as for most developing countries, there is currently no adequate e-waste management, plastic separation or destruction capacity. The data highlight the urgent need to develop environmentally sound management for this large material flow.

  19. Bio-based structural composite materials for aerospace applications

    CSIR Research Space (South Africa)

    Jacob John, Maya


    Full Text Available honeycomb cores were supplied by AIRBUS. 4. RESULTS AND DISCUSSION 4.1 Flame retardant treatment The most important regulation in aerospace applications is maintaining the fire, smoke and toxicity (FST) standards. Flax is a flammable material... compounds, generally have low toxicity, have been shown to be effective flame retardants and smoke suppressants for natural fibres and synthetic polymers4 and phosphates have long been used for flame retarding cellulosic materials2 In this study, a...

  20. 30 CFR 57.22104 - Open flames (I-C mines). (United States)


    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Open flames (I-C mines). 57.22104 Section 57.22104 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR METAL AND NONMETAL... mine opening is covered. The cover shall be a substantial material, such as metal or wood, topped...

  1. Heated Tube Facility (United States)

    Federal Laboratory Consortium — The Heated Tube Facility at NASA GRC investigates cooling issues by simulating conditions characteristic of rocket engine thrust chambers and high speed airbreathing...

  2. Fuel nozzle tube retention

    Energy Technology Data Exchange (ETDEWEB)

    Cihlar, David William; Melton, Patrick Benedict


    A system for retaining a fuel nozzle premix tube includes a retention plate and a premix tube which extends downstream from an outlet of a premix passage defined along an aft side of a fuel plenum body. The premix tube includes an inlet end and a spring support feature which is disposed proximate to the inlet end. The premix tube extends through the retention plate. The spring retention feature is disposed between an aft side of the fuel plenum and the retention plate. The system further includes a spring which extends between the spring retention feature and the retention plate.

  3. Autoignition and flame stabilisation processes in turbulent non-premixed hot coflow flames

    NARCIS (Netherlands)

    Oldenhof , E.


    This dissertation examines stabilisation processes in turbulent non-premixed jet flames, created by injecting gaseous fuel into a co-flowing stream of hot, low-oxygen combustion products. Being able to predict whether and how a flame achieves stable and reliable combustion is a matter of great pract

  4. On the dynamics of flame edges in diffusion-flame/vortex interactions

    Energy Technology Data Exchange (ETDEWEB)

    Hermanns, Miguel; Linan, Amable [Departamento de Motopropulsion y Termofluidodinamica, Universidad Politecnica de Madrid, Pza. Cardenal Cisneros 3, 28040 Madrid (Spain); Vera, Marcos [Area de Mecanica de Fluidos, Universidad Carlos III de Madrid, 28911 Leganes (Spain)


    We analyze the local flame extinction and reignition of a counterflow diffusion flame perturbed by a laminar vortex ring. Local flame extinction leads to the appearance of flame edges separating the burning and extinguished regions of the distorted mixing layer. The dynamics of these edges is modeled based on previous numerical results, with heat release effects fully taken into account, which provide the propagation velocity of triple and edge flames in terms of the upstream unperturbed value of the scalar dissipation. The temporal evolution of the mixing layer is determined using the classical mixture fraction approach, with both unsteady and curvature effects taken into account. Although variable density effects play an important role in exothermic reacting mixing layers, in this paper the description of the mixing layer is carried out using the constant density approximation, leading to a simplified analytical description of the flow field. The mathematical model reveals the relevant nondimensional parameters governing diffusion-flame/vortex interactions and provides the parameter range for the more relevant regime of local flame extinction followed by reignition via flame edges. Despite the simplicity of the model, the results show very good agreement with previously published experimental results. (author)

  5. Methane Formation by Flame-Generated Hydrogen Atoms in the Flame Ionization Detector

    DEFF Research Database (Denmark)

    Holm, Torkil; Madsen, Jørgen Øgaard


    The precombustion degradation of organic compounds in the flame ionization detector has been studied (1) by heating the additives in hydrogen in a quartz capillary and analyzing the reaction products by GC and (2) by following the degradation of the additives in a hydrogen flame, by means of a th...

  6. Modeling Candle Flame Behavior In Variable Gravity (United States)

    Alsairafi, A.; Tien, J. S.; Lee, S. T.; Dietrich, D. L.; Ross, H. D.


    The burning of a candle, as typical non-propagating diffusion flame, has been used by a number of researchers to study the effects of electric fields on flame, spontaneous flame oscillation and flickering phenomena, and flame extinction. In normal gravity, the heat released from combustion creates buoyant convection that draws oxygen into the flame. The strength of the buoyant flow depends on the gravitational level and it is expected that the flame shape, size and candle burning rate will vary with gravity. Experimentally, there exist studies of candle burning in enhanced gravity (i.e. higher than normal earth gravity, g(sub e)), and in microgravity in drop towers and space-based facilities. There are, however, no reported experimental data on candle burning in partial gravity (g model of the candle flame, buoyant forces were neglected. The treatment of momentum equation was simplified using a potential flow approximation. Although the predicted flame characteristics agreed well with the experimental results, the model cannot be extended to cases with buoyant flows. In addition, because of the use of potential flow, no-slip boundary condition is not satisfied on the wick surface. So there is some uncertainty on the accuracy of the predicted flow field. In the present modeling effort, the full Navier-Stokes momentum equations with body force term is included. This enables us to study the effect of gravity on candle flames (with zero gravity as the limiting case). In addition, we consider radiation effects in more detail by solving the radiation transfer equation. In the previous study, flame radiation is treated as a simple loss term in the energy equation. Emphasis of the present model is on the gas-phase processes. Therefore, the detailed heat and mass transfer phenomena inside the porous wick are not treated. Instead, it is assumed that a thin layer of liquid fuel coated the entire wick surface during the burning process. This is the limiting case that the mass

  7. Turbulence-flame interactions in DNS of a laboratory high Karlovitz premixed turbulent jet flame (United States)

    Wang, Haiou; Hawkes, Evatt R.; Chen, Jacqueline H.


    In the present work, direct numerical simulation (DNS) of a laboratory premixed turbulent jet flame was performed to study turbulence-flame interactions. The turbulent flame features moderate Reynolds number and high Karlovitz number (Ka). The orientations of the flame normal vector n, the vorticity vector ω and the principal strain rate eigenvectors ei are examined. The in-plane and out-of-plane angles are introduced to quantify the vector orientations, which also measure the flame geometry and the vortical structures. A general observation is that the distributions of these angles are more isotropic downstream as the flame and the flow become more developed. The out-of-plane angle of the flame normal vector, β, is a key parameter in developing the correction of 2D measurements to estimate the corresponding 3D quantities. The DNS results show that the correction factor is unity at the inlet and approaches its theoretical value of an isotropic distribution downstream. The alignment characteristics of n, ω and ei, which reflect the interactions of turbulence and flame, are also studied. Similar to a passive scalar gradient in non-reacting flows, the flame normal has a tendency to align with the most compressive strain rate, e3, in the flame, indicating that turbulence contributes to the production of scalar gradient. The vorticity dynamics are examined via the vortex stretching term, which was found to be the predominant source of vorticity generation balanced by dissipation, in the enstrophy transport equation. It is found that although the vorticity preferentially aligns with the intermediate strain rate, e2, the contribution of the most extensive strain rate, e1, to vortex stretching is comparable with that of the intermediate strain rate, e2. This is because the eigenvalue of the most extensive strain rate, λ1, is always large and positive. It is confirmed that the vorticity vector is preferentially positioned along the flame tangential plane, contributing

  8. Structure of Flame Balls at Low Lewis-Number (United States)

    Weiland, Karen J.; Ronney, Paul


    The Structure of Flame Balls at Low Lewis-Number (SOFBALL) experiment explored the behavior of a newly discovered flame phenomena called "flame balls." These spherical, stable, stationary flame structures, observed only in microgravity, provide a unique opportunity to study the interactions of the two most important processes necessary for combustion (chemical reaction and heat and mass transport) in the simplest possible configuration. The previously unobtainable experimental data provided a comparison with models of flame stability and flame propagation limits that are crucial both in assessing fire safety and in designing efficient, clean-burning combustion engines.

  9. Urinary biomarkers of flame retardant exposure among collegiate U.S. gymnasts. (United States)

    Carignan, Courtney C; Fang, Mingliang; Stapleton, Heather M; Heiger-Bernays, Wendy; McClean, Michael D; Webster, Thomas F


    Flame retardants are widely used in polyurethane foam materials including gymnastics safety equipment such as pit cubes and landing mats. We previously reported elevated concentrations of flame retardants in the air and dust of a U.S. gymnastics training facility and elevated PentaBDE in the serum of collegiate gymnasts. Our objective in this pilot study was to compare urinary biomarkers of exposure to other flame retardants and additives of polyurethane foam including tris(1,3-dichloro-2-propyl) phosphate (TDCIPP), triphenyl phosphate (TPHP) and 2-ethylhexyl- 2,3,4,5-tetrabromobenzoate (EH-TBB) in samples collected from 11 collegiate gymnasts before and after a gymnastics practice (n=53 urine samples total). We identified a 50% increase in the TPHP biomarker (p=0.03) from before to after practice, a non-significant 22% increase in the TDCIPP biomarker (p=0.14) and no change for the EH-TBB biomarker. These preliminary results indicate that the gymnastics training environment can be a source of recreational exposure to flame retardants. Such exposures are likely widespread, as we identified flame retardants in 89% of foam samples collected from gyms across the U.S.

  10. Preparation, characterization of microencapsulated ammonium polyphosphate and its flame retardancy in polyurethane composites

    Energy Technology Data Exchange (ETDEWEB)

    Shen, Ming-Yuan; Chen, Wei-Jen [Department of Aviation Mechanical Engineering, China University of Science and Technology, Hsinchu County, 303, Taiwan (China); Kuan, Chen-Feng; Kuan, Hsu-Chiang [Department of Computer Application Engineering, Far East University, Tainan, 744, Taiwan (China); Yang, Jia-Ming [Green Flame Retardant Material Research Laboratory, Department of Safety, Health and Environmental Engineering, Hung-Kuang University, Taichung, 433, Taiwan (China); Chiang, Chin-Lung, E-mail: [Green Flame Retardant Material Research Laboratory, Department of Safety, Health and Environmental Engineering, Hung-Kuang University, Taichung, 433, Taiwan (China)


    In this study, a novel microencapsulated flame retardant containing ammonium polyphosphate (APP) and an 4,4′-oxydianiline-formaldehyde (OF) resin as the core and shell material was synthesized using in situ polymerization technology. The structure and performance of OF microencapsulated APP (OFAPP) were characterized using Fourier transform infrared spectroscopy and scanning electron microscopy. The thermal properties of OFAPP were systematically analyzed through thermogravimetric analysis. Flame retardancy tests, such as limiting oxygen index (LOI) and UL-94, were conducted to evaluate the effect of varying the composition of APP and OFAPP in silanol-terminated polyurethane (Si-PU) composites. The results indicated that the microencapsulation of APP with the OF resin resulted in improved hydrophobicity. The results also revealed that the flame retardancy of the Si-PU/OFAPP composite (LOI = 37%) was higher than that of the Si-PU/APP composite (LOI = 23%) at the same additive loading. - Highlights: • A novel microencapsulated flame retardant was synthesized using in situ polymerization technology. • The microencapsulation of ammonium polyphosphate with the polymer resin resulted in improved hydrophobicity. • Polyurethane composites have excellent thermal stability and flame retardance.

  11. Flame Quenching Dynamics of High Velocity Flames in Rectangular Cross-section Channels

    KAUST Repository

    Mahuthannan, Ariff Magdoom


    Understanding flame quenching for different conditions is necessary to develop safety devices like flame arrestors. In practical applications, the speed of a deflagration in the lab-fixed reference frame will be a strong function of the geometry through which the deflagration propagates. This study reports on the effect of the flame speed, at the entrance of a quenching section, on the quenching distance. A 2D rectangular channel joining two main spherical vessels is considered for studying this effect. Two different velocity regimes are investigated and referred to as configurations A, and B. For configuration A, the velocity of the flame is 20 m/s, while it is about 100 m/s for configuration B. Methane-air stoichiometric mixtures at 1 bar and 298 K are used. Simultaneous dynamic pressure measurements along with schlieren imaging are used to analyze the quenching of the flame. Risk assessment of re-ignition is also reported and analyzed.

  12. Fabrication of Cellulose Nanofiber/AlOOH Aerogel for Flame Retardant and Thermal Insulation

    Directory of Open Access Journals (Sweden)

    Bitao Fan


    Full Text Available Cellulose nanofiber/AlOOH aerogel for flame retardant and thermal insulation was successfully prepared through a hydrothermal method. Their flame retardant and thermal insulation properties were investigated. The morphology image of the cellulose nanofiber/AlOOH exhibited spherical AlOOH with an average diameter of 0.5 μm that was wrapped by cellulose nanofiber or adhered to them. Cellulose nanofiber/AlOOH composite aerogels exhibited excellent flame retardant and thermal insulation properties through the flammability test, which indicated that the as-prepared composite aerogels would have a promising future in the application of some important areas such as protection of lightweight construction materials.

  13. Ceria Prepared by Flame Spray Pyrolysis as an Efficient Catalyst for Oxidation of Diesel Soot

    DEFF Research Database (Denmark)

    Christensen, Jakob Munkholt; Deiana, Davide; Grunwaldt, Jan-Dierk


    Ceria has been prepared by flame spray pyrolysis and tested for activity in catalytic soot oxidation. In tight contact with soot the oxidation activity (measured in terms of the temperature of maximal oxidation rate, Tmax) of the flame made ceria is among the highest reported for CeO2. This can...... to a significant degree be ascribed to the large surface area achieved with the flame spray pyrolysis method. The importance of the inherent soot reactivity for the catalytic oxidation was studied using various soot samples, and the reactivity of the soot was found to have a significant impact, as the Tmax......-value for oxidation in tight contact with a catalyst scaled linearly with the Tmax-value in non-catalytic soot oxidation. The Tmax-value in non-catalytic soot oxidation was in turn observed to scale linearly with the H/C ratio of the carbonaceous materials....

  14. Engineering Flame Retardant Biodegradable Nanocomposites (United States)

    He, Shan; Yang, Kai; Guo, Yichen; Zhang, Linxi; Pack, Seongchan; Davis, Rachel; Lewin, Menahem; Ade, Harald; Korach, Chad; Kashiwagi, Takashi; Rafailovich, Miriam


    Cellulose-based PLA/PBAT polymer blends can potentially be a promising class of biodegradable nanocomposites. Adding cellulose fiber reinforcement can improve mechanical properties of biodegradable plastics, but homogeneously dispersing hydrophilic cellulose in the hydrophobic polymer matrix poses a significant challenge. We here show that resorcinol diphenyl phosphates (RDP) can be used to modify the surface energy, not only reducing phase separation between two polymer kinds but also allowing the cellulose particles and the Halloysite clay to be easily dispersed within polymer matrices to achieve synergy effect using melt blending. Here in this study we describe the use of cellulose fiber and Halloysite clay, coated with RDP surfactant, in producing the flame retardant polymer blends of PBAT(Ecoflex) and PLA which can pass the stringent UL-94 V0 test. We also utilized FTIR, SEM and AFM nanoindentation to elucidate the role RDP plays in improving the compatibility of biodegradable polymers, and to determine structure property of chars that resulted in composites that could have optimized mechanical and thermal properties. Supported by Garcia Polymer Center and NSF Foundation.

  15. A, a Brominated Flame Retardant

    Directory of Open Access Journals (Sweden)

    Tomomi Takeshita


    Full Text Available Tetrabromobisphenol A (TBBPA, a brominated flame retardant, has been found to exacerbate pneumonia in respiratory syncytial virus- (RSV- infected mice. We examined the effect of Brazilian propolis (AF-08 on the exacerbation of RSV infection by TBBPA exposure in mice. Mice were fed a powdered diet mixed with 1% TBBPA alone, 0.02% AF-08 alone, or 1% TBBPA and 0.02% AF-08 for four weeks and then intranasally infected with RSV. TBBPA exposure increased the pulmonary virus titer and level of IFN-γ, a representative marker of pneumonia due to RSV infection, in the lungs of infected mice without toxicity. AF-08 was significantly effective in reducing the virus titers and IFN-γ level increased by TBBPA exposure. Also, AF-08 significantly reduced proinflammatory cytokine (TNF-α and IL-6 levels in the lungs of RSV-infected mice with TBBPA exposure, but Th2 cytokine (IL-4 and IL-10 levels were not evidently increased. Neither TBBPA exposure nor AF-08 treatment affected the anti-RSV antibody production in RSV-infected mice. In flow cytometry analysis, AF-08 seemed to be effective in reducing the ratio of pulmonary CD8a+ cells in RSV-infected mice with TBBPA exposure. TBBPA and AF-08 did not exhibit anti-RSV activity in vitro. Thus, AF-08 probably ameliorated pneumonia exacerbated by TBBPA exposure in RSV-infected mice by limiting excess cellular immune responses.

  16. Steam generator tube failures

    Energy Technology Data Exchange (ETDEWEB)

    MacDonald, P.E.; Shah, V.N.; Ward, L.W.; Ellison, P.G.


    A review and summary of the available information on steam generator tubing failures and the impact of these failures on plant safety is presented. The following topics are covered: pressurized water reactor (PWR), Canadian deuterium uranium (CANDU) reactor, and Russian water moderated, water cooled energy reactor (VVER) steam generator degradation, PWR steam generator tube ruptures, the thermal-hydraulic response of a PWR plant with a faulted steam generator, the risk significance of steam generator tube rupture accidents, tubing inspection requirements and fitness-for-service criteria in various countries, and defect detection reliability and sizing accuracy. A significant number of steam generator tubes are defective and are removed from service or repaired each year. This wide spread damage has been caused by many diverse degradation mechanisms, some of which are difficult to detect and predict. In addition, spontaneous tube ruptures have occurred at the rate of about one every 2 years over the last 20 years, and incipient tube ruptures (tube failures usually identified with leak detection monitors just before rupture) have been occurring at the rate of about one per year. These ruptures have caused complex plant transients which have not always been easy for the reactor operators to control. Our analysis shows that if more than 15 tubes rupture during a main steam line break, the system response could lead to core melting. Although spontaneous and induced steam generator tube ruptures are small contributors to the total core damage frequency calculated in probabilistic risk assessments, they are risk significant because the radionuclides are likely to bypass the reactor containment building. The frequency of steam generator tube ruptures can be significantly reduced through appropriate and timely inspections and repairs or removal from service.

  17. Sooting turbulent jet flame: characterization and quantitative soot measurements (United States)

    Köhler, M.; Geigle, K. P.; Meier, W.; Crosland, B. M.; Thomson, K. A.; Smallwood, G. J.


    Computational fluid dynamics (CFD) modelers require high-quality experimental data sets for validation of their numerical tools. Preferred features for numerical simulations of a sooting, turbulent test case flame are simplicity (no pilot flame), well-defined boundary conditions, and sufficient soot production. This paper proposes a non-premixed C2H4/air turbulent jet flame to fill this role and presents an extensive database for soot model validation. The sooting turbulent jet flame has a total visible flame length of approximately 400 mm and a fuel-jet Reynolds number of 10,000. The flame has a measured lift-off height of 26 mm which acts as a sensitive marker for CFD model validation, while this novel compiled experimental database of soot properties, temperature and velocity maps are useful for the validation of kinetic soot models and numerical flame simulations. Due to the relatively simple burner design which produces a flame with sufficient soot concentration while meeting modelers' needs with respect to boundary conditions and flame specifications as well as the present lack of a sooting "standard flame", this flame is suggested as a new reference turbulent sooting flame. The flame characterization presented here involved a variety of optical diagnostics including quantitative 2D laser-induced incandescence (2D-LII), shifted-vibrational coherent anti-Stokes Raman spectroscopy (SV-CARS), and particle image velocimetry (PIV). Producing an accurate and comprehensive characterization of a transient sooting flame was challenging and required optimization of these diagnostics. In this respect, we present the first simultaneous, instantaneous PIV, and LII measurements in a heavily sooting flame environment. Simultaneous soot and flow field measurements can provide new insights into the interaction between a turbulent vortex and flame chemistry, especially since soot structures in turbulent flames are known to be small and often treated in a statistical manner.

  18. Applicable methods for NDT of tubes

    Energy Technology Data Exchange (ETDEWEB)

    Pitkaenen, J.; Lipponen, A.; Kauppinen, P. [VTT Industrial Systems Espoo (Finland)


    For inside inspection of tubes, eddy current testing (ET) and internal rotating ultrasonic inspection (IRIS) are mainly used at the moment. Special eddy current method, remote field technique (RFEC) is being used to some extent, but normally only for ferritic tubes. This paper presents a review of techniques that can be used for internal inspections of tubes in boilers, heat exchangers and steam generators. Material affects the choice of the method, considering given defect type and detectability with the selected technique. In general ET methods are used for inspection of non- ferromagnetic tubes and IRIS and RFEC methods for inspection of ferromagnetic tubes. New techniques have been introduced, to determine the tube condition accurately. One of the developed techniques is for instance inspection of the internal surface by combination of dye penetrant and optical laser inspection. New applications of ultrasonic techniques include defect detection and characterisation by tip diffraction echoes, defect analysis by echo dynamics and the TOFD-technique for defect sizing. Ultrasonic guided waves have a great potential to increase inspection speed for defect detection, although sizing is still under development. For inspection of ferromagnetic tubes, a method based on magnetic flux leakage has been used. In addition to the basic techniques visualisation of the measured data is one of the. key factors for improved exploitation of the inspection results. (orig.)

  19. Extractable sulphate-sulphur, total sulphur and trace-element determinations in plant material by flow injection analysis

    Energy Technology Data Exchange (ETDEWEB)

    Heanes, D.L. (South Australian Department of Agriculture, Adelaide (Australia))


    A rapid, accurate and reproducible procedure for determining total sulphur(S) and trace elements (copper, zinc, manganese and iron) in plant material is described. Plant material is digested in culture tubes with a mixture of nitric and perchloric acids containing ammonium metavanadate and calcium chloride. In the acid digest, concentrations of total-S as sulphate are determined by turbidimetry and trace-elements by flame atomic absorption spectrophotometry using flow injection analysis. The results for a range of plant materials compare well with those obtained by conventional procedures for the same elements. The microprocessor controlled digestion and multielement assay procedure described here offers improved laboratory efficiencies in materials, time and cost effectiveness. The techniques should be particularly useful when plant tissues are in limited supply.

  20. Dynamic Response and Fracture of Composite Gun Tubes

    Directory of Open Access Journals (Sweden)

    Jerome T. Tzeng


    Full Text Available The fracture behavior due to dynamic response in a composite gun tube subjected to a moving pressure has been investigated. The resonance of stress waves result in very high amplitude and frequency strains in the tube at the instant and location of pressure front passage as the velocity of the projectile approaches a critical value. The cyclic stresses can accelerate crack propagation in the gun tube with an existing imperfection and significantly shorten the fatigue life of gun tubes. The fracture mechanism induced by dynamic amplification effects is particularly critical for composite overwrap barrels because of a multi-material construction, anisotropic material properties, and the potential of thermal degradation.

  1. Solid Phase Synthesis of Anhydrous Zinc Borate from Zinc and Boron Oxide and Utilization as a Flame Retardant in Dye and Textile


    AYAR, Barış; GÜRÜ, Metin; ÇAKANYILDIRIM, Çetin


    Durability of materials to flame and stability at high temperatures are very important in order to increase the field of use. Non-flammability is not the only requirement materials should not have toxic gas products during the burning, also. Anhydrous zinc borate was chosen as flame retardant due to its advantages, such as; light weight, high melting point, low thermal expansion, and intrinsic smoke suppressant and corrosion resistance properties. For the synthesis, metallic zinc and anhydrou...

  2. Hologram recording tubes (United States)

    Rajchman, J. H.


    Optical memories allow extremely large numbers of bits to be stored and recalled in a matter of microseconds. Two recording tubes, similar to conventional image-converting tubes, but having a soft-glass surface on which hologram is recorded, do not degrade under repeated hologram read/write cycles.

  3. Impact of the Flame-Holder Heat-Transfer Characteristics on the Onset of Combustion Instability

    KAUST Repository

    Hong, Seunghyuck


    In this article, we investigate the impact of heat transfer between the flame and the flameholder on the dynamic stability characteristics of a 50-kW backward-facing step combustor. We conducted a series of tests where two backward step blocks were used, made of ceramic and stainless steel, whose thermal conductivities are 1.06 and 12 W/m/K, respectively. Stability characteristics of the two flame-holder materials were examined using measurements of the dynamic pressure and flame chemiluminescence over a range of operating conditions. Results show that with the ceramic flameholder, the onset of instability is significantly delayed in time and, for certain operating conditions, disappears altogether, whereas with the higher conductivity material, the combustor becomes increasingly unstable over a range of operating conditions. We explain these trends using the heat flux through the flameholder and the change in the burning velocity near the step wall. Results suggest a potential approach using low-thermal-conductivity material near the flame-holder as passive dynamics suppression methods. Copyright © Taylor & Francis Group, LLC.

  4. Categorising YouTube

    DEFF Research Database (Denmark)

    Simonsen, Thomas Mosebo


    This article provides a genre analytical approach to creating a typology of the User Generated Content (UGC) of YouTube. The article investigates the construction of navigation processes on the YouTube website. It suggests a pragmatic genre approach that is expanded through a focus on YouTube’s...... technological affordances. Through an analysis of the different pragmatic contexts of YouTube, it is argued that a taxonomic understanding of YouTube must be analysed in regards to the vacillation of a user-driven bottom-up folksonomy and a hierarchical browsing system that emphasises a culture of competition...... and which favours the already popular content of YouTube. With this taxonomic approach, the UGC videos are registered and analysed in terms of empirically based observations. The article identifies various UGC categories and their principal characteristics. Furthermore, general tendencies of the UGC within...

  5. Wavy tube heat pumping

    Energy Technology Data Exchange (ETDEWEB)

    Haldeman, C. W.


    A PVC conduit about 4'' in diameter and a little more than 40 feet long is adapted for being seated in a hole in the earth and surrounds a coaxial copper tube along its length that carries Freon between a heat pump and a distributor at the bottom. A number of wavy conducting tubes located between the central conducting tube and the wall of the conduit interconnect the distributor with a Freon distributor at the top arranged for connection to the heat pump. The wavy conducting tubing is made by passing straight soft copper tubing between a pair of like opposed meshing gears each having four convex points in space quadrature separated by four convex recesses with the radius of curvature of each point slightly less than that of each concave recess.

  6. Chaotic radiation/turbulence interactions in flames

    Energy Technology Data Exchange (ETDEWEB)

    Menguec, M.P.; McDonough, J.M.


    In this paper, the authors present a review of their recent efforts to model chaotic radiation-turbulence interactions in flames. The main focus is to characterize soot volume fraction fluctuations in turbulent diffusion flames, as they strongly contribute to these interaction. The approach is based on the hypothesis that the fluctuations of properties in turbulent flames are deterministic in nature, rather than random. The authors first discuss the theoretical details and then they briefly outline the experiments conducted to measure the scattered light signals from fluctuating soot particles along the axis of an ethylene-air diffusion flame. They compare the power spectra and time series obtained from experiments against the ad-hoc and rigorous models derived using a series of logistic maps. These logistic maps can be used in simulation of the fluctuations in these type of flames, without extensive computational effort or sacrifice of physical detail. Availability of accurate models of these kinds allows investigation of radiation-turbulence interactions at a more fundamental level than it was previously possible.

  7. Second Law Analysis of Diffusion Flames

    Directory of Open Access Journals (Sweden)

    Yalcin Gogus


    Full Text Available The objective of this paper is to investigate the sources of volumetric irreversibilities in both laminar and turbulent diffusion flames. The theoretical background of analysis relies on the local exergy transport equation, which allows the microscopic formulation of the well-known Gouy-Stodola theorem. For laminar reacting flows, the volumetric entropy generation rate expression includes the viscous, thermal, diffusion and chemical components. Their expressions show that the corresponding irreversibilities are uncoupled if the combustion process occurs at constant pressure. The numerical simulation of a methane-air combustion process shows that the thermal, chemical and diffusive irreversibilities represent, in order of enumeration, the predominant irreversibilities in the laminar diffusion reacting flows. In the case of turbulent diffusion flames, the viscous, thermal, diffusion and chemical mean components have to be expressed in accordance with the combustion model. Two combustion models are used: the multi-species approach based on the eddy-break formulation of mean reaction rate, and the assumed probability density function for a conserved scalar that relies on the flame sheet model. For a diffusion methane-air jet flame, the distribution of mean irreversibility components is presented. Taking into account the technical importance of diffusion flames, the analysis could serve to improve the combustion geometry and the flow condition.

  8. Aromatics oxidation and soot formation in flames

    Energy Technology Data Exchange (ETDEWEB)

    Howard, J.B.; Pope, C.J.; Shandross, R.A.; Yadav, T.


    This project is concerned with the kinetics and mechanisms of aromatics oxidation and soot and fullerenes formation in flames. The scope includes detailed measurements of profiles of stable and radical species concentrations in low-pressure one-dimensional premixed flames. Intermediate species identifications and mole fractions, fluxes, and net reaction rates calculated from the measured profiles are used to test postulated reaction mechanisms. Particular objectives are to identify, and to confirm or determine rate constants for, the main benzene oxidation reactions in flames, and to characterize soot and fullerenes and their formation mechanisms and kinetics. Stable and radical species profiles in the aromatics oxidation study are measured using molecular beam sampling with on-line mass spectrometry. The rate of soot formation measured by conventional optical techniques is found to support the hypotheses that particle inception occurs through reactive coagulation of high molecular weight PAH in competition with destruction by OHattack, and that the subsequent growth of the soot mass occurs through addition reactions of PAH and C[sub 2]H[sub 2] with the soot particles. During the first year of this reporting period, fullerenes C[sub 60] and C[sub 70] in substantial quantities were found in the flames being studied. The fullerenes were recovered, purified and spectroscopically identified. The yields of C[sub 60] and C[sub 70] were then determined over ranges of conditions in low-pressure premixed flames of benzene and oxygen.

  9. Distributed Flames in Type Ia Supernovae

    CERN Document Server

    Aspden, A J; Woosley, S E; 10.1088/0004-637X/710/2/1654


    In the distributed burning regime, turbulence disrupts the internal structure of the flame, and so the idea of laminar burning propagated by conduction is no longer valid. The nature of the burning depends on the turbulent Damkohler number (Da), which steadily declines from much greater than one to less that one as the density decreases to a few 10^6 g/cc. Scaling arguments predict that the turbulent flame speed s, normalized by the turbulent intensity u, follows s/u=Da^1/2 for Da1, and that localized excursions to as much as five times u can occur. The lambda-flame speed and width can be predicted based on the turbulence in the star and the turbulent nuclear burning time scale of the fuel. We propose a practical method for measuring these based on the scaling relations and small-scale computationally-inexpensive simulations. This suggests that a simple turbulent flame model can be easily constructed suitable for large-scale distributed supernovae flames.

  10. Persistence, bioaccumulation, and toxicity of halogen-free flame retardants. (United States)

    Waaijers, Susanne L; Kong, Deguo; Hendriks, Hester S; de Wit, Cynthia A; Cousins, Ian T; Westerink, Remco H S; Leonards, Pim E G; Kraak, Michiel H S; Admiraal, Wim; de Voogt, Pim; Parsons, John R


    Polymers are synthetic organic materials having a high carbon and hydrogen content, which make them readily combustible. Polymers have many indoor uses and their flammability makes them a fire hazard. Therefore, flame retardants (FRs) are incorporated into these materials as a safety measure. Brominated flame retardants (BFRs), which accounted for about 21% of the total world market of FRs, have several unintended negative effects on the environment and human health. Hence, there is growing interest in finding appropriate alternative halogen-free flame retardants (HFFRs). Many of these HFFRs are marketed already, although their environ- mental behavior and toxicological properties are often only known to a limited extent, and their potential impact on the environment cannot yet be properly assessed. Therefore, we undertook this review to make an inventory of the available data that exists (up to September 2011) on the physical-chemical properties, pro- duction volumes, persistence, bioaccumulation, and toxicity (PBT) of a selection of HFFRs that are potential replacements for BFRs in polymers. Large data gaps were identified for the physical-chemical and the PBT properties of the reviewed HFFRs. Because these HFFRs are currently on the market, there is an urgent need to fill these data gaps. Enhanced transparency of methodology and data are needed to reevaluate certain test results that appear contradictory, and, if this does not provide new insights, further research should be performed. TPP has been studied quite extensively and it is clearly persistent, bioaccumulative, and toxic. So far, RDP and BDP have demonstrated low to high ecotoxicity and persistence. The compounds ATH and ZB exerted high toxicity to some species and ALPI appeared to be persistent and has low to moderate reported ecotoxicity. DOPO and MPP may be persistent, but this view is based merely on one or two studies, clearly indicating a lack of information. Many degradation studies have been

  11. Techniques for Thermal Damping in Tube Bundles

    Directory of Open Access Journals (Sweden)



    Full Text Available Flow-induced vibration in heat exchangers has been a source of concern in the process, power generation and nuclear industry for several decades. Damping has a major influence on the flow induced vibrations and is dependant on a variety of factors such as mechanical properties of the tube material, geometry of intermediate supports, the physical properties of shell-side fluid, type of tube motion, number of supports, tube frequency, shell-side temperature etc. Various damping mechanisms have been identified and quantified. Generally the effects of the higher operating temperatures on the various damping mechanisms are neglected in the general design procedure. This paper focuses on the thermal aspects of damping mechanisms subjected to single phase cross-flow in shell and tube heat exchanger and a comparison is carried out safer design based on experimental and empirical formulations.

  12. Pulsating instability and self-acceleration of fast turbulent flames

    CERN Document Server

    Poludnenko, A Y


    (Abridged) A series of three-dimensional numerical simulations is used to study the intrinsic stability of high-speed turbulent flames. Calculations model the interaction of a fully-resolved premixed flame with a highly subsonic, statistically steady, homogeneous, isotropic turbulence. We consider a wide range of turbulent intensities and system sizes, corresponding to the Damk\\"ohler numbers Da = 0.1-6.0. These calculations show that turbulent flames in the regimes considered are intrinsically unstable. In particular, we find three effects. 1) Turbulent flame speed develops pulsations with the observed peak-to-peak amplitude > 10 and a characteristic time scale close to a large-scale eddy turnover time. Such variability is caused by the interplay between turbulence, which continuously creates the flame surface, and highly intermittent flame collisions, which consume the flame surface. 2) Unstable burning results in the periodic pressure build-up and the formation of pressure waves or shocks, when the flame s...

  13. Beam steering effects in turbulent high pressure flames

    Energy Technology Data Exchange (ETDEWEB)

    Hemmerling, B.; Kaeppeli, B. [Paul Scherrer Inst. (PSI), Villigen (Switzerland)


    The propagation of a laser beam through a flame is influenced by variations of the optical density. Especially in turbulent high pressure flames this may seriously limit the use of laser diagnostic methods. (author) 1 fig., 2 refs.

  14. Daphnid life cycle response to new generation of flame retardants

    NARCIS (Netherlands)

    Waaijers, S.L.; Bleyenberg, T.E.; Dits, A; Schoorl, M.; Schütt, J; Kools, S.A.E.; de Voogt, P.; Admiraal, W.; Parsons, J.R.; Kraak, M.H.S.


    Relatively hazardous brominated flame retardants (BFRs) are currently substituted with halogen-free flame retardants (HFFRs). Consequently, information on their persistence, bioaccumulation and toxicity (PBT) is urgently needed. Therefore, we investigated the chronic toxicity to the water flea

  15. Visualization of ionic wind in laminar jet flames

    KAUST Repository

    Park, Daegeun


    Electric field, when it is applied to hydrocarbon flames, generates ionic wind due to the electric body force on charge carrying species. Ionic wind has been shown to influence soot emission, propagation speed, and stability of flames; however, a detailed behavior of ionic wind and its effects on flames is still not clear. Here, we investigated the dynamic behaviors of flames and ionic wind in the presence of direct current (DC) and alternating current (AC) electric fields in nonpremixed and premixed jet flames with a jet nozzle placed between two parallel electrodes. We observed a skewed flame toward a lower potential electrode with DC and lower frequency AC (e.g., 10Hz) and a steady flame with higher frequencies AC (1000Hz), while we found that the ionic wind blew toward both the anode and cathode regardless of flame type (nonpremixed or premixed) or the source of the electric field (DC and AC).

  16. Analytical Solution of Coupled Laminar Heat-Mass Transfer in a Tube with Uniform Heat Flux

    Institute of Scientific and Technical Information of China (English)


    Analytical solution is obtained of coupled laminar heat-mass transfer in a tube with uniform heat flux.This corresponds to the case when a layer of sublimable material is coated on the inner surface of a tube with its outer surface heated by uniform heat flux and this coated material will sublime as gas flows throught the tube.

  17. The Interaction of High-Speed Turbulence with Flames: Turbulent Flame Speed

    CERN Document Server

    Poludnenko, Alexei Y; 10.1016/j.combustflame.2010.09.002


    (Abridged) Direct numerical simulations of the interaction of a premixed flame with driven, subsonic, homogeneous, isotropic, Kolmogorov-type turbulence in an unconfined system are used to study the mechanisms determining the turbulent flame speed, S_T, in the thin reaction zone regime. High intensity turbulence is considered with the r.m.s. velocity 35 times the laminar flame speed, S_L, resulting in the Damkohler number Da = 0.05. Here we show that: (1) The flame brush has a complex internal structure, in which the isosurfaces of higher fuel mass fractions are folded on progressively smaller scales. (2) Global properties of the turbulent flame are best represented by the structure of the region of peak reaction rate, which defines the flame surface. (3) In the thin reaction zone regime, S_T is predominantly determined by the increase of the flame surface area, A_T, caused by turbulence. (4) The observed increase of S_T relative to S_L exceeds the corresponding increase of A_T relative to the surface area of...

  18. The structural stability of lunar lava tubes (United States)

    Blair, David M.; Chappaz, Loic; Sood, Rohan; Milbury, Colleen; Bobet, Antonio; Melosh, H. Jay; Howell, Kathleen C.; Freed, Andrew M.


    Mounting evidence from the SELENE, LRO, and GRAIL spacecraft suggests the presence of vacant lava tubes under the surface of the Moon. GRAIL evidence, in particular, suggests that some may be more than a kilometer in width. Such large sublunarean structures would be of great benefit to future human exploration of the Moon, providing shelter from the harsh environment at the surface-but could empty lava tubes of this size be stable under lunar conditions? And what is the largest size at which they could remain structurally sound? We address these questions by creating elasto-plastic finite element models of lava tubes using the Abaqus modeling software and examining where there is local material failure in the tube's roof. We assess the strength of the rock body using the Geological Strength Index method with values appropriate to the Moon, assign it a basaltic density derived from a modern re-analysis of lunar samples, and assume a 3:1 width-to-height ratio for the lava tube. Our results show that the stability of a lava tube depends on its width, its roof thickness, and whether the rock comprising the structure begins in a lithostatic or Poisson stress state. With a roof 2 m thick, lava tubes a kilometer or more in width can remain stable, supporting inferences from GRAIL observations. The theoretical maximum size of a lunar lava tube depends on a variety of factors, but given sufficient burial depth (500 m) and an initial lithostatic stress state, our results show that lava tubes up to 5 km wide may be able to remain structurally stable.

  19. What Are Neural Tube Defects? (United States)

    ... NICHD Research Information Clinical Trials Resources and Publications Neural Tube Defects (NTDs): Condition Information Skip sharing on social media links Share this: Page Content What are neural tube defects? Neural (pronounced NOOR-uhl ) tube defects are ...


    Directory of Open Access Journals (Sweden)

    Maroš Martinkovič


    Full Text Available Final properties of forming pieces are affected by production, at first conditions of mechanical working. Application of stereology methods to statistic reconstruction of three-dimensional plastic deformed material structure by bulk forming led to detail analysis of material structure changes. The microstructure of cold drawing tubes from STN 411353 steel was analyzed. Grain boundaries orientation was measured on perpendicular and parallel section of tubes with different degree of deformation. Macroscopic deformation leads to grain boundaries deformation and these ones were compared.

  1. Luminous Flame Temperature Distribution Measurement Using the Emission Method

    Institute of Scientific and Technical Information of China (English)


    Flame temperature distribution is one of the most important characteristic parameters in combustion research. The emission method is a good way to measure the luminous flame temperature field. The maximum entropy method is introduced to the temperature distribution measurement of a luminous flame using the emission method. A simplified mathematical model was derived by combining the thermal radiation theory, reconstruction algorithm and maximum entropy method. Suitable parameters were selected in the computing process. Good experimental results were obtained with pulverized coal flames.

  2. CARS Temperature Measurements in Sooting, Laminar Diffusion Flames. (United States)


    ethylene-air discussed above raise ques- tions about structure of a sooting flame and energy loss due to thermal radia- tion from soot. These questions do...certainly suggest that thermal radiation from soot may I, not be the only significant energy loss from a sooting flame . Nonluminous emission from CO2...CARS thermometry in a sooting flame . * Combust. Flame, 36, 87. Farrow, R. L., Lucht, R. P., Flower, W. L., and Palmer, R. E. (1984). Coherent anti

  3. Annealing effect and stability of carbon nanotubes in hydrogen flame

    Institute of Scientific and Technical Information of China (English)


    Annealing of carbon nanotubes (CNTs) by the hydrogen flame in air was investigated in this study. Raman spectroscopy and scanning electron microscopy were used to characterize the products. The peak width of Raman spectra decreased with the increase in the annealing time. The CNTs were not stable in the hydrogen flame and the etching rate of the CNTs by hydrogen flame was very high. The hydrogen flame annealing had some effects on improving the crystallinity of CNTs.

  4. The Influences of Electric Fields on Soot Formation and Flame Structure of Diffusion Flames

    Institute of Scientific and Technical Information of China (English)

    LinXie; TakeyukiKishi; 等


    The influences of DC and AC electric fields,at frequencies up to 1.48 MHz and the maximum strength of about 6 kV/cm,on soot formation and flame structure were investigated using a counterflow type acetylene diffusion flame.The distributioons of flame luminosity,soot volume fraction,Flame temperature and OH concentration in flame were measured by non-invasive detection methods.Under the influence of electric fields,the changes in distribution of the soot volume fraction were confirmed.Electric fields of high frequency and high intensity reduced the soot volume fraction.whereas other electric fields increased it.The maximum values of flame temperature and OH concentration decreased.In the relationship between the maximum value of the soot volume fraction and the maximum temperature,the maximum soot volum fraction showed toth increase and decrease with maximum temperatures depending on the frequencies and intensities of the electric fields,and both of them occurred at temperatures lower than 1990 K.The production of the incipient particles seemed to be the dominant process controlling the soot volume fraction due to the electric fields.The luminosity of a sooting diffusion flame was found to depend on the volume fraction and temperature of the soot particles in the flame,As for the behavior of the flame in the electric fields.the ionic wind effect was not found to be dominant in the present work,and the result of the precious simulation based on the ionic wind theory was not consistent with the present experimental results.

  5. The Flame Challenge and Communicating Science (United States)

    Ames, Ben


    When famed actor and science enthusiast Alan Alda was 11 years-old he was itching to know the science behind a flame. He asked his science teacher but her blunt response didn't exactly satisfy his curiosity. ``It's oxidation,'' she said. 65 years later, Alan Alda launched ``The Flame Challenge,'' an annual contest encouraging scientists to improve their communication to the general public. In this talk, last year's winner discusses his approach to successfully explaining the science behind a flame to a wide audience. Because communicating science is a pillar of the scientific method, he shares key elements of successful communication important for engaging funders, policy-makers, students, the general public, and even other scientists.

  6. Inhalation a significant exposure route for chlorinated organophosphate flame retardants. (United States)

    Schreder, Erika D; Uding, Nancy; La Guardia, Mark J


    Chlorinated organophosphate flame retardants (ClOPFRs) are widely used as additive flame retardants in consumer products including furniture, children's products, building materials, and textiles. Tests of indoor media in homes, offices, and other environments have shown these compounds are released from products and have become ubiquitous indoor pollutants. In house dust samples from Washington State, U.S.A., ClOPFRs were the flame retardants detected in the highest concentrations. Two ClOPFRs, tris(1,3-dichloro-2-propyl)phosphate (TDCPP or TDCIPP) and tris(2-chloroethyl)phosphate (TCEP), have been designated as carcinogens, and there is growing concern about the toxicity of the homologue tris(1-chloro-2-propyl)phosphate (TCPP or TCIPP). In response to concerns about exposure to these compounds, the European Union and a number of U.S. states have taken regulatory action to restrict their use in certain product categories. To better characterize exposure to ClOPFRs, inhalation exposure was assessed using active personal air samplers in Washington State with both respirable and inhalable particulate fractions collected to assess the likelihood particles penetrate deep into the lungs. Concentrations of ∑ClOPFRs (respirable and inhalable) ranged from 97.1 to 1190 ng m(-3) (mean 426 ng m(-3)), with TCPP detected at the highest concentrations. In general, higher levels were detected in the inhalable particulate fraction. Total intake of ClOPFRs via the inhalation exposure route was estimated to exceed intake via dust ingestion, indicating that inhalation is an important route that should be taken into consideration in assessments of these compounds.

  7. Performance Comparison Between Isolated Flame Retardant Cable and Other Flame Retardant Cables%隔离型阻燃电缆和其它阻燃电缆性能比较

    Institute of Scientific and Technical Information of China (English)



    This paper introduces the variation of classification standards for flame retardant cable , and the evolution and development of flame retardant materials used for flame retardant cable, and proposes advantages of applying isolated flame retardant cable in architectural engineering through introducing isolated flame retardant cable, describing its production process to meet level B1 burning behavior and comparing its performance with other types of flame retardant cables.%介绍阻燃电缆分级标准的变化和阻燃电缆阻燃材料的演变及发展,通过对隔离型阻燃电缆及其要达到的B1级燃烧性能阻燃电缆生产工艺的阐述及与其它类型阻燃电缆性能的比较,指出隔离型阻燃电缆在建筑工程中的应用优势。

  8. Front roughening of flames in discrete media (United States)

    Lam, Fredric; Mi, XiaoCheng; Higgins, Andrew J.


    The morphology of flame fronts propagating in reactive systems composed of randomly positioned, pointlike sources is studied. The solution of the temperature field and the initiation of new sources is implemented using the superposition of the Green's function for the diffusion equation, eliminating the need to use finite-difference approximations. The heat released from triggered sources diffuses outward from each source, activating new sources and enabling a mechanism of flame propagation. Systems of 40 000 sources in a 200 ×200 two-dimensional domain were tracked using computer simulations, and statistical ensembles of 120 realizations of each system were averaged to determine the statistical properties of the flame fronts. The reactive system of sources is parameterized by two nondimensional values: the heat release time (normalized by interparticle diffusion time) and the ignition temperature (normalized by adiabatic flame temperature). These two parameters were systematically varied for different simulations to investigate their influence on front propagation. For sufficiently fast heat release and low ignition temperature, the front roughness [defined as the root mean square deviation of the ignition temperature contour from the average flame position] grew following a power-law dependence that was in excellent agreement with the Kardar-Parisi-Zhang (KPZ) universality class (β =1 /3 ). As the reaction time was increased, lower values of the roughening exponent were observed, and at a sufficiently great value of reaction time, reversion to a steady, constant-width thermal flame was observed that matched the solution from classical combustion theory. Deviation away from KPZ scaling was also observed as the ignition temperature was increased. The features of this system that permit it to exhibit both KPZ and non-KPZ scaling are discussed.

  9. Numerical modelling of ion transport in flames

    KAUST Repository

    Han, Jie


    This paper presents a modelling framework to compute the diffusivity and mobility of ions in flames. The (n, 6, 4) interaction potential is adopted to model collisions between neutral and charged species. All required parameters in the potential are related to the polarizability of the species pair via semi-empirical formulas, which are derived using the most recently published data or best estimates. The resulting framework permits computation of the transport coefficients of any ion found in a hydrocarbon flame. The accuracy of the proposed method is evaluated by comparing its predictions with experimental data on the mobility of selected ions in single-component neutral gases. Based on this analysis, the value of a model constant available in the literature is modified in order to improve the model\\'s predictions. The newly determined ion transport coefficients are used as part of a previously developed numerical approach to compute the distribution of charged species in a freely propagating premixed lean CH4/O2 flame. Since a significant scatter of polarizability data exists in the literature, the effects of changes in polarizability on ion transport properties and the spatial distribution of ions in flames are explored. Our analysis shows that changes in polarizability propagate with decreasing effect from binary transport coefficients to species number densities. We conclude that the chosen polarizability value has a limited effect on the ion distribution in freely propagating flames. We expect that the modelling framework proposed here will benefit future efforts in modelling the effect of external voltages on flames. Supplemental data for this article can be accessed at © 2015 Taylor & Francis.

  10. 30 CFR 75.600-1 - Approved cables; flame resistance. (United States)


    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Approved cables; flame resistance. 75.600-1 Section 75.600-1 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR COAL MINE... cables; flame resistance. Cables shall be accepted or approved by MSHA as flame resistant....

  11. 30 CFR 56.6904 - Smoking and open flames. (United States)


    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Smoking and open flames. 56.6904 Section 56.6904 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR METAL AND NONMETAL... Requirements § 56.6904 Smoking and open flames. Smoking and use of open flames shall not be permitted within...

  12. Entrainment regimes and flame characteristics of wildland fires (United States)

    Ralph M. Nelson; Bret W. Butler; David R. Weise


    This paper reports results from a study of the flame characteristics of 22 wind-aided pine litter fires in a laboratory wind tunnel and 32 field fires in southern rough and litter-grass fuels. Flame characteristic and fire behaviour data from these fires, simple theoretical flame models and regression techniques are used to determine whether the data support the...

  13. Demonstration for the Applicability of the EPRI ETSS on the SG Tube Wear Defects Formed at the Tube Support Structure

    Energy Technology Data Exchange (ETDEWEB)

    Shin, Ki Seok; Cheon, Keun Young; Nam, Min Woo [Korea Hydro and Nuclear Power Co. Ltd, Daejeon (Korea, Republic of); Min, Kyong Mahn [Universal Monitoring and Inspection Inc., Daejeon (Korea, Republic of)


    In this paper, the authorized EPRI ETSS 27906.2 applied to the detection of tapered wear volumetric indications and depth sizing within the free span area, loose part not present was reviewed and applied to the site SG tubes for getting the actual value of the wear depth and providing structural integrity interpretation based on engineering evaluation. The experiment to demonstrate the applicability of EPRI ETSS was performed by the employment of the newly prepared STD tube and resulted in ensuring the effectiveness and equivalency of the EPRI ETSS as well. The authorized EPRI ETSS 27906.2 for getting the actual value of the wear depth and providing structural integrity interpretation based on engineering evaluation was reviewed and applied to the site SG tubes. The testing results were reviewed with the influences of SG tube material and the support structure. The impact of the tube materials was insignificant and that of the tube support structure showed somewhat conservative results. The testing resulted in successful demonstration of applicability of the EPRI ETSS on the SG tube wear defects at the tube support. One of the major flaw mechanisms detected in the currently operating domestic OPR-1000 pressurized water reactors(PWR's) steam generator(SG) tubes is wear defect. In general, wear defect has been constantly detected in the upper tube bundle imposed to the flow induced vibration interaction between tube and its support structure, and the quantity of the affected tubes has also shown the tendency to increase as plant operation life is added. In order to take appropriate measures and maintain the structural integrity for the SG tubes, wear defect is currently categorized as active damage mechanism and the tubes containing 40% or greater wear depth of the nominal tube wall thickness shall be plugged per SGMP(SG Management Program) Recently, a fairly large amplitude of wear defects on the Batwing(BW), one of the upper tube support structures in the SG

  14. Flame-Vortex Interactions Imaged in Microgravity - To Assess the Theory Flame Stretch (United States)

    Driscoll, James F.


    The goals of this research are to: 1) Assess the Theory of Flame Stretch by operating a unique flame-vortex experiment under microgravity conditions in the NASA Glenn 2.2 Second Drop Tower (drops to identify operating conditions have been completed); 2) Obtain high speed shadowgraph images (500-1000 frames/s) using the drop rig (images were obtained at one-g, and the NASA Kodak RO camera is being mounted on the drop rig); 3) Obtain shadowgraph and PIV images at 1-g while varying the effects of buoyancy by controlling the Froude number (completed); 4) Numerically model the inwardly-propagating spherical flame that is observed in the experiment using full chemistry and the RUN 1DL code (completed); 5) Send images of the flame shape to Dr. G. Patniak at NRL who is numerically simulating the entire flame-vortex interaction of the present experiment (data transfer completed); and 6) Assess the feasibility of obtaining PIV velocity field images in the drop rig, which would be useful (but not required) for our assessment of the Theory of Flame Stretch (PIV images were obtained at one-g using same low laser power that is available from fiber optic cable in drop tower). The motivation for the work is to obtain novel measurement needed to develop a physically accurate model of turbulent combustion that can help in the control of engine pollutants. The unique experiment allows, for the first time, the detailed study of a negatively-curved (negatively stretched) flame, which is one of the five fundamental types of premixed flames. While there have been studies of flat flames, positively-curved (outwardly-propagating) cases and positively-strained (counterflow) cases, this is the first detailed study of a negatively-curved (inwardly-propagating) flame. The first set of drops in the 2.2 Second Drop Tower showed that microgravity provides more favorable conditions for achieving inwardly-propagating flames (IPFs) than 1-g. A vortex interacts with a flame and creates a spherical

  15. Parametric Analysis of Composite Reinforced Wood Tubes Under Axial Compression


    Cabrero, J.; Heiduschke, A.; Haller, P. (P.)


    Wood tubes combine economy, an efficient use of the material and optimal structural performance. They can be optionally reinforced with technical fibers and/or textiles laminated to the outer wood surface. The paper presents the outcomes of a parametric study on the performance of wood reinforced tubes submitted to axial compression. Simple analytical models were applied to estimate the load-carrying capacity of the tubes and their failure mechanisms. Analytical and numerical models were deve...

  16. Computatonal and experimental study of laminar flames

    Energy Technology Data Exchange (ETDEWEB)

    Smooke, M.D.; Long, M.B. [Yale Univ., New Haven, CT (United States)


    This research has centered on an investigation of the effects of complex chemistry and detailed transport on the structure and extinction of hydrocarbon flames in counterflow, cylindrical and coflowing axisymmetric configurations. The authors have pursued both computational and experimental aspects of the research in parallel. The computational work has focused on the application of accurate and efficient numerical methods for the solution of the one and two-dimensional nonlinear boundary value problems describing the various reacting systems. Detailed experimental measurements were performed on axisymmetric coflow flames using two-dimensional imaging techniques. In particular, spontaneous Raman scattering and laser induced fluorescence were used to measure the temperature, major and minor species profiles.

  17. Pdf prediction of supersonic hydrogen flames (United States)

    Eifler, P.; Kollmann, W.


    A hybrid method for the prediction of supersonic turbulent flows with combustion is developed consisting of a second order closure for the velocity field and a multi-scalar pdf method for the local thermodynamic state. It is shown that for non-premixed flames and chemical equilibrium mixture fraction, the logarithm of the (dimensionless) density, internal energy per unit mass and the divergence of the velocity have several advantages over other sets of scalars. The closure model is applied to a supersonic non-premixed flame burning hydrogen with air supplied by a supersonic coflow and the results are compared with a limited set of experimental data.

  18. Isolated Fallopian Tube Torsion

    Directory of Open Access Journals (Sweden)

    S. Kardakis


    Full Text Available Isolated torsion of the Fallopian tube is a rare gynecological cause of acute lower abdominal pain, and diagnosis is difficult. There are no pathognomonic symptoms; clinical, imaging, or laboratory findings. A preoperative ultrasound showing tubular adnexal masses of heterogeneous echogenicity with cystic component is often present. Diagnosis can rarely be made before operation, and laparoscopy is necessary to establish the diagnosis. Unfortunately, surgery often is performed too late for tube conservation. Isolated Fallopian tube torsion should be suspected in case of acute pelvic pain, and prompt intervention is necessary.

  19. Evaluation of lithium determination in three analyzers: flame emission, flame atomic absorption spectroscopy and ion selective electrode

    Directory of Open Access Journals (Sweden)

    Mehri Aliasgharpour


    Full Text Available Background: Lithium carbonate salt has become an increasingly important substance in the treatment of manic depressive disorders, and its relatively narrow therapeutic range has caused laboratories to monitor the serum concentration carefully. In the present work we evaluated lithium measurement in 3 different analyzers. Methods & Materials: Three different analyzers including Flame Emission (FES, Flame Atomic Absorption Spectroscopy (FAAS, and Ion Selective Electrode (ISE were used. All chemicals had a grade suitable for trace metal analysis. Results: Within-day precision of CV was ≤ 1.5% for FES & FAAS, except for ISE (1.9% CV. Between-days precision of CV was less for FES than for FAAS and ISE (1.3% versus 2.2% & 2.3%. The percent recovery of added lithium in pooled patients’ serum was higher for ISE than for FASS and FES (103.4% versus 96.2% and 94.6%. We also obtained a higher average lithium concentration for patients’ serum samples (n=16 measured by ISE than for FAAS and FES (0.825±0.30 versus 0.704±0.26 & 0.735±0.19. Paired t-test results revealed a significant difference (p< 0.001 for patient sera analyzed with FAAS and ISE. Conclusion: We report higher results for ISE than the other two analyzers and conclude that the choice between the two flame methods for patients’ serum lithium determination is arbitrary and that FES analyzer is a more attractive routine alternative for lithium determination than FAAS because of its cost and ease of performance. In addition, the results obtained by ISE are precise. However, its accuracy may depend on other interfering factors.

  20. Organophosphate flame retardants in household dust before and after introduction of new furniture. (United States)

    Keimowitz, A R; Strunsky, N; Wovkulich, K


    Flame retardant compounds originating from household items collect in household dust, a reasonable proxy for human exposure. Contributions of specific items or behaviors to dust are difficult to separate. This study examined standardized college housing before and after the introduction of new, flame retardant couches in order to explore any effect that changing upholstered furniture may have on flame retardant concentrations in dust. Two contradictory hypotheses were posited: (1) that new furniture might increase flame retardant releases immediately after introduction due to initial off-gassing of new materials or (2) that older furniture would release more flame retardants due to mechanical breakdown of polyurethane foam. This study was designed to determine which of these processes dominated. Prior to the introduction of new furniture, TDCIPP was detected in 12/20 samples at a median concentration of 22 μg/g and TCEP was detected in 1/20 samples at a concentration of 16 μg/g. TDCIPP and TCEP were not detected in any samples (N = 29) after the introduction of new couches. TPHP was detected both before (in 11/20 samples) and after (in 5/29 samples) introduction of new couches; the median concentrations before and after were 63 ± 49 and 16 ± 11 μg/g (standard deviation shown). Introduced couches contained TDCIPP (and not TPHP) at ∼1.25% (w/w). These data support the second hypothesis and indicate that removal of older furniture decreases TDCIPP and TCEP concentrations in dust and may potentially reduce total flame retardant concentrations in dust, at least immediately after introduction of the new furniture.