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Sample records for fine structure investigation

  1. Extended X-ray absorption fine structure investigation of nitrogen stabilized expanded austenite

    DEFF Research Database (Denmark)

    Oddershede, Jette; Christiansen, Thomas; Ståhl, Kenny

    2010-01-01

    As-delivered austenitic stainless steel and nitrogen stabilized expanded austenite, both fully nitrided and denitrided (in H2), were investigated with Cr, Fe and Ni extended X-ray absorption fine structure. The data shows pronounced short-range ordering of Cr and N. For the denitrided specimen...

  2. Complementary information on CdSe/ZnSe quantum dot local structure from extended X-ray absorption fine structure and diffraction anomalous fine structure measurements

    International Nuclear Information System (INIS)

    Piskorska-Hommel, E.; Holý, V.; Caha, O.; Wolska, A.; Gust, A.; Kruse, C.; Kröncke, H.; Falta, J.; Hommel, D.

    2012-01-01

    The extended X-ray absorption fine structure (EXAFS) and diffraction anomalous fine structure (DAFS) have been applied to investigate a local structure for the CdSe/ZnSe quantum dots grown by molecular beam epitaxy (MBE) and migration-enhanced epitaxy (MEE). The aim was to study the intermixing of Cd and Zn atoms, chemical compositions and strain induced by cap-layer. The EXAFS at the Cd K-edge and DAFS at the Se K-edge proved the intermixing of Cd and Zn atoms. The distances Cd–Se (2.61 Å) found from EXAFS and DAFS analysis for h 1 region is closer to that in bulk CdSe (2.62 Å). The DAFS analysis revealed the differences in the local structure in two investigated regions (i.e. different iso-strain volumes) on the quantum dots. It was found that the investigated areas differ in the Cd concentration. To explain the experimental results the theoretical calculation based on a full valence-force field (VFF) model was performed. The theoretical VFF model fully explains the experimental data.

  3. Investigation on the fine structure of sea-breeze during ESCOMPTE experiment

    Science.gov (United States)

    Puygrenier, V.; Lohou, F.; Campistron, B.; Saïd, F.; Pigeon, G.; Bénech, B.; Serça, D.

    2005-03-01

    Surface and remote-sensing instruments deployed during ESCOMPTE experiment over the Marseille area, along the Mediterranean coast, were used to investigate the fine structure of the atmospheric boundary layer (ABL) during sea-breeze circulation in relation to pollutant transport and diffusion. Six sea-breeze events are analyzed with a particular focus on 25 June 2001. Advection of cool and humid marine air over land has a profound influence on the daytime ABL characteristics. This impact decreases rapidly with the inland distance from the sea. Nearby the coast (3 km inland), the mixing height Zi rises up to 750 m and falls down after 15:00 (UT) when the breeze flow reaches its maximum intensity. A more classical evolution of the ABL is observed at only 11-km inland where Zi culminates in the morning and stabilizes in the afternoon at about 1000 m height. Fine inspection of the data revealed an oscillation of the sea-breeze with a period about 2 h 47 min. This feature, clearly discernable for 3 days at least, is present in several atmospheric variables such as wind, temperature, not only at the ground but also aloft in the ABL as observed by sodar/RASS and UHF wind profilers. In particular, the mixing height Zi deduced from UHF profilers observations is affected also by the same periodicity. This pulsated sea-breeze is observed principally above Marseille and, at the northern and eastern shores of the Berre pond. In summary, the periodic intrusion over land of cool marine air modifies the structure of the ABL in the vicinity of the coast from the point of view of stability, turbulent motions and pollutants concentration. An explanation of the source of this pulsated sea-breeze is suggested.

  4. Fine- and hyperfine structure investigations of the even-parity configuration system of the atomic holmium

    Science.gov (United States)

    Stefanska, D.; Ruczkowski, J.; Elantkowska, M.; Furmann, B.

    2018-04-01

    In this work new experimental results concerning the hyperfine structure (hfs) for the even-parity level system of the holmium atom (Ho I) were obtained; additionally, hfs data obtained recently as a by-product in investigations of the odd-parity level system were summarized. In the present work the values of the magnetic dipole and the electric quadrupole hfs constants A and B were determined for 24 even-parity levels, for 14 of them for the first time. On the basis of these results, as well as on available literature data, a parametric study of the fine structure and the hyperfine structure for the even-parity configurations of atomic holmium was performed. A multi-configuration fit of 7 configurations was carried out, taking into account second-order of the perturbation theory. For unknown electronic levels predicted values of the level energies and hfs constants are given, which can facilitate further experimental investigations.

  5. An Einstein-Cartan Fine Structure Constant Definition

    Directory of Open Access Journals (Sweden)

    Stone R. A. Jr.

    2010-01-01

    Full Text Available The fine structure constant definition given in Stone R.A. Jr. Progress in Physics, 2010, v.1, 11-13 is compared to an Einstein-Cartan fine structure constant definition. It is shown that the Einstein-Cartan definition produces the correct pure theory value, just not the measure value. To produce the measured value, the pure theory Einstein-Cartan fine structure constant requires only the new variables and spin coupling of the fine structure constant definition in [1].

  6. Atomic fine structure in a space of constant curvature

    International Nuclear Information System (INIS)

    Bessis, N.; Bessis, G.; Shamseddine, R.

    1982-01-01

    As a contribution to a tentative formulation of atomic physics in a curved space, the determination of atomic fine structure energies in a space of constant curvature is investigated. Starting from the Dirac equation in a curved space-time, the analogue of the Pauli equation in a general coordinate system is derived. The theoretical curvature induced shifts and splittings of the fine structure energy levels are put in evidence and examined for the particular case of the hydrogenic n=2 levels. (author)

  7. The Fine Structure Constant

    Indian Academy of Sciences (India)

    IAS Admin

    The article discusses the importance of the fine structure constant in quantum mechanics, along with the brief history of how it emerged. Al- though Sommerfelds idea of elliptical orbits has been replaced by wave mechanics, the fine struc- ture constant he introduced has remained as an important parameter in the field of ...

  8. Diffraction anomalous fine structure using X-ray anomalous dispersion

    International Nuclear Information System (INIS)

    Soejima, Yuji; Kuwajima, Shuichiro

    1998-01-01

    A use of X-ray anomalous dispersion effects for structure investigation has recently been developed by using synchrotron radiation. One of the interesting method is the observation of anomalous fine structure which arise on diffraction intensity in energy region of incident X-ray at and higher than absorption edge. The phenomenon is so called Diffraction Anomalous Fine Structure (DAFS). DAFS originates in the same physical process an that of EXAFS: namely photoelectric effect at the corresponding atom and the interaction of photoelectron waves between the atom and neighboring atoms. In contrast with EXAFS, the method is available for only the crystalline materials, but shows effective advantages of the structure investigations by a use of diffraction: one is the site selectivity and the other is space selectivity. In the present study, demonstrations of a use of X-ray anomalous dispersion effect for the superstructure determination will be given for the case of PbZrO 3 , then recent trial investigations of DAFS in particular on the superlattice reflections will be introduced. In addition, we discuss about Forbidden Reflection near Edge Diffraction (FRED) which is more recently investigated as a new method of the structure analysis. (author)

  9. A study of human DPOAE fine structure

    DEFF Research Database (Denmark)

    Reuter, Karen; Hammershøi, Dorte

    height and ripple prevalence. Temporary changes of the DPOAE fine structure are analyzed by measuring DPOAE both before and after exposing some of the subjects to an intense sound. The characteristic patterns of fine structure can be found in the DPOAE of all subjects, though they are individual and vary...... fine structures are obtained from 74 normalhearing humans using primary levels of L1/L2=65/45 dB. The subjects belong to groups with different age and exposure history. A classification algorithm is developed, which quantifies the fine structure by the parameters ripple place, ripple width, ripple...

  10. Fine structure studies of terbium atoms

    International Nuclear Information System (INIS)

    Abhay Kumar; Bandyopadhyay, Krishnanath; Niraj Kumar

    2012-01-01

    Terbium (Z = 65) is a typical rare-earth element. Fine structure of spectural lines of terbium (Tb) are presented using the laser optogalvanic spectroscopic technique. Altogether eighty transitions in the 5686-6367 A range have been observed in the fine structure spectrum of 159 Tb. Wavelengths of all the observed transitions have been determined. Out of 80 transitions of Tb, a total of 59 transitions are being reported for the first time. Classifications of 39 new transitions have been provided using the known energy levels, Doppler-limited optogalvanic spectroscopic technique is employed to study the fine structure (fs) 159 Tb. (author)

  11. Temperature-dependent fine structure splitting in InGaN quantum dots

    Science.gov (United States)

    Wang, Tong; Puchtler, Tim J.; Zhu, Tongtong; Jarman, John C.; Kocher, Claudius C.; Oliver, Rachel A.; Taylor, Robert A.

    2017-07-01

    We report the experimental observation of temperature-dependent fine structure splitting in semiconductor quantum dots using a non-polar (11-20) a-plane InGaN system, up to the on-chip Peltier cooling threshold of 200 K. At 5 K, a statistical average splitting of 443 ± 132 μeV has been found based on 81 quantum dots. The degree of fine structure splitting stays relatively constant for temperatures less than 100 K and only increases above that temperature. At 200 K, we find that the fine structure splitting ranges between 2 and 12 meV, which is an order of magnitude higher than that at low temperatures. Our investigations also show that phonon interactions at high temperatures might have a correlation with the degree of exchange interactions. The large fine structure splitting at 200 K makes it easier to isolate the individual components of the polarized emission spectrally, increasing the effective degree of polarization for potential on-chip applications of polarized single-photon sources.

  12. The electronic fine structure of 4-nitrophenyl functionalized single-walled carbon nanotubes

    International Nuclear Information System (INIS)

    Chakraborty, Amit K; Coleman, Karl S; Dhanak, Vinod R

    2009-01-01

    Controlling the electronic structure of carbon nanotubes (CNTs) is of great importance to various CNT based applications. Herein the electronic fine structure of single-walled carbon nanotube films modified with 4-nitrophenyl groups, produced following reaction with 4-nitrobenzenediazonium tetrafluoroborate, was investigated for the first time. Various techniques such as x-ray and ultra-violet photoelectron spectroscopy, and near edge x-ray absorption fine structure studies were used to explore the electronic structure, and the results were compared with the measured electrical resistances. A reduction in number of the π electronic states in the valence band consistent with the increased resistance of the functionalized nanotube films was observed.

  13. Edge separation using diffraction anomalous fine structure

    International Nuclear Information System (INIS)

    Ravel, B.; Bouldin, C.E.; Renevier, H.; Hodeau, J.L.; Berar, J.F.

    1999-01-01

    We exploit the crystallographic sensitivity of the Diffraction Anomalous Fine-Structure (DAFS) measurement to separate the fine structure contributions of different atomic species with closely spaced resonant energies. In BaTiO 3 the Ti K edge and Ba Lm edges are separated by 281 eV, or about 8.2 Angstrom -1 ), thus severely limiting the information content of the Ti K edge signal. Using the site selectivity of DAFS we can separate the two fine structure spectra using an iterative Kramers-Kronig method, thus extending the range of the Ti K edge spectrum. This technique has application to many rare earth/transition metal compounds, including many magnetic materials of technological significance for which K and L edges overlap in energy. (au)

  14. Fine structure and analytical quantum-defect wave functions

    International Nuclear Information System (INIS)

    Kostelecky, V.A.; Nieto, M.M.; Truax, D.R.

    1988-01-01

    We investigate the domain of validity of previously proposed analytical wave functions for atomic quantum-defect theory. This is done by considering the fine-structure splitting of alkali-metal and singly ionized alkaline-earth atoms. The Lande formula is found to be naturally incorporated. A supersymmetric-type integer is necessary for finite results. Calculated splittings correctly reproduce the principal features of experimental values for alkali-like atoms

  15. Fine structure of the exciton electroabsorption in semiconductor superlattices

    Energy Technology Data Exchange (ETDEWEB)

    Monozon, B.S., E-mail: borismonozon@mail.ru [Physics Department, Marine Technical University, 3 Lotsmanskaya Str., 190008 St.Petersburg (Russian Federation); Schmelcher, P. [Zentrum für Optische Quantentechnologien, The Hamburg Centre for Ultrafast Imaging, Universität Hamburg, Luruper Chaussee 149, 22761 Hamburg (Germany)

    2017-02-15

    Wannier-Mott excitons in a semiconductor layered superlattice (SL) are investigated analytically for the case that the period of the superlattice is much smaller than the 2D exciton Bohr radius. Additionally we assume the presence of a longitudinal external static electric field directed parallel to the SL axis. The exciton states and the optical absorption coefficient are derived in the tight-binding and adiabatic approximations. Strong and weak electric fields providing spatially localized and extended electron and hole states, respectively, are studied. The dependencies of the exciton states and the exciton absorption spectrum on the SL parameters and the electric field strength are presented in an explicit form. We focus on the fine structure of the ground quasi-2D exciton level formed by the series of closely spaced energy levels adjacent from the high frequencies. These levels are related to the adiabatically slow relative exciton longitudinal motion governed by the potential formed by the in-plane exciton state. It is shown that the external electric fields compress the fine structure energy levels, decrease the intensities of the corresponding optical peaks and increase the exciton binding energy. A possible experimental study of the fine structure of the exciton electroabsorption is discussed.

  16. Acoustic fine structure may encode biologically relevant information for zebra finches.

    Science.gov (United States)

    Prior, Nora H; Smith, Edward; Lawson, Shelby; Ball, Gregory F; Dooling, Robert J

    2018-04-18

    The ability to discriminate changes in the fine structure of complex sounds is well developed in birds. However, the precise limit of this discrimination ability and how it is used in the context of natural communication remains unclear. Here we describe natural variability in acoustic fine structure of male and female zebra finch calls. Results from psychoacoustic experiments demonstrate that zebra finches are able to discriminate extremely small differences in fine structure, which are on the order of the variation in acoustic fine structure that is present in their vocal signals. Results from signal analysis methods also suggest that acoustic fine structure may carry information that distinguishes between biologically relevant categories including sex, call type and individual identity. Combined, our results are consistent with the hypothesis that zebra finches can encode biologically relevant information within the fine structure of their calls. This study provides a foundation for our understanding of how acoustic fine structure may be involved in animal communication.

  17. Fine structure transitions in Fe XIV

    Science.gov (United States)

    Nahar, Sultana N.

    2013-07-01

    Results are reported for Fe XIV energy levels and transitions obtained from the ab initio relativistic Breit-Pauli R-matrix (BPRM) method. BPRM method developed under the Iron Project is capable of calculating very large number of fine structure energy levels and corresponding transitions. However, unlike in the atomic structure calculations, where levels are identified spectroscopically based on the leading percentage contributions of configurations, BPRM is incapable of such identification of the levels and hence the transitions. The main reason for it is that the percentage contributions can not be determined exactly from the large number of channels in the R-matrix space. The present report describes an identification method that uses considerations of quantum defects of channels, contributions of channel from outer regions, Hund's rule, and angular momenta algebra for addition and completeness of fine structure components. The present calculations are carried out using a close coupling wave function expansion that included 26 core excitations from configurations 2s22p63s2, 2s22p63s3p,2s22p63p2,2s22p63s3d, and 2s22p63p3d. A total of 1002 fine structure levels with n ⩽ 10, l⩽9, and 0.5 ⩽J⩽ 9.5 with even and odd parities and the corresponding 130,520 electric dipole allowed (E1) fine structure transitions, a most complete set for astrophysical modelings of spectral analysis and opacities, is presented. Large number of new energy levels are found and identified. The energies agree very well, mostly in less than 1% with the highest being 1.9%, with the 68 observed fine structure levels. While the high lying levels may have some uncertainty, an overall accuracy of energy levels should be within 10%. BPRM transitions have been benchmarked with the existing most accurate calculated transition probabilities with very good agreement for most cases. Based on the accuracy of the method and comparisons, most of the transitions can be rated with A (⩽10%) to C (

  18. The fine-structure constant before quantum mechanics

    International Nuclear Information System (INIS)

    Kragh, Helge

    2003-01-01

    This paper focuses on the early history of the fine-structure constant, largely the period until 1925. Contrary to what is generally assumed, speculations concerning the interdependence of the elementary electric charge and Planck's constant predated Arnold Sommerfeld's 1916 discussion of the dimensionless constant. This paper pays particular attention to a little known work from 1914 in which G N Lewis and E Q Adams derived what is effectively a numerical expression for the fine-structure constant

  19. Fine structure of charge exchange lines observed in laboratory plasmas

    Energy Technology Data Exchange (ETDEWEB)

    Ida, K.; Nishimura, S. [National Inst. for Fusion Science, Nagoya (Japan); Kondo, K.

    1997-01-01

    The influence of the fine structure of charge exchange lines appears only at the plasma edge or in the recombining phase where the ion temperature is low enough. The observed spectra in Li III and C VI are consistent with the sum of fine-structure components populated by statistical weights (assuming complete l-mixing) not by direct charge exchange cross sections. Some discrepancy was observed in the intensity ratio of fine-structure components between the observation and calculation for C VI in the recombining phase. The fine-structure of charge exchange lines gives an apparent Doppler shift in plasma rotation velocity measurement using charge exchange spectroscopy. (author)

  20. Berry's Phase and Fine Structure

    CERN Document Server

    Binder, B

    2002-01-01

    Irrational numbers can be assigned to physical entities based on iterative processes of geometric objects. It is likely that iterative round trips of vector signals include a geometric phase component. If so, this component will couple back to the round trip frequency or path length generating an non-linear feedback loop (i.e. induced by precession). In this paper such a quantum feedback mechanism is defined including generalized fine structure constants in accordance with the fundamental gravitomagnetic relation of spin-orbit coupling. Supported by measurements, the general relativistic and topological background allows to propose, that the deviation of the fine structure constant from 1/137 could be assigned to Berry's phase. The interpretation is straightforward: spacetime curvature effects can be greatly amplified by non-linear phase-locked feedback-loops adjusted to single-valued phase relationships in the quantum regime.

  1. The origin of fine structure in near-field scanning optical lithography of an electroactive polymer

    International Nuclear Information System (INIS)

    Cotton, Daniel V; Belcher, Warwick J; Dastoor, Paul C; Fell, Christopher J

    2008-01-01

    Near-field scanning optical lithography (NSOL) has been used to produce arbitrary structures of the electroactive polymer polyphenylenevinylene at sizes comparable to optical wavelengths, which are of interest for integrated optical devices. The structures are characterized using AFM and SEM and exhibit interesting fine structure. The characteristic size and shape of the lithographic features and their associated fine structure have been examined in the context of the electric field distribution at the near-field scanning optical microscope tip. In particular, the Bethe-Bouwkamp model for electric field distribution at an aperture has been used in combination with a recently developed model for precursor solubility dependence on UV energy dose to predict the characteristics of lithographic features produced by NSOL. The fine structure in the lithographic features is also investigated and explained. Suggestions for the further improvement of the technique are made.

  2. Ordinary mode auroral kilometric radiation fine structure observed by DE 1

    International Nuclear Information System (INIS)

    Benson, R.F.; Mellott, M.M.; Huff, R.L.; Gurnett, D.A.

    1988-01-01

    The fine structure observed with intense right-hand extraordinary (R-X) mode auroral kilometric radiation (AKR) has received major theoretical attention. Data from the Dynamics Explorer 1 plasma wave instrument indicate that left-hand ordinary (L-O) mode AKR posses similar fine structure. Several theories have been proposed to explain the fine structure of the R-X mode AKR. In order to account for the L-O mode fine structure, these theories will have to be modified to produce the L-O mode directly or will have to rely on mode conversion processes from the R-X to the L-O mode

  3. Cosmological constraints on variations of the fine structure constant at the epoch of recombination

    International Nuclear Information System (INIS)

    Menegoni, E; Galli, S; Archidiacono, M; Calabrese, E; Melchiorri, A

    2013-01-01

    In this brief work we investigate any possible variation of the fine structure constant at the epoch of recombination. The recent measurements of the Cosmic Microwave Background anisotropies at arcminute angular scales performed by the ACT and SPT experiments are probing the damping regime of Cosmic Microwave Background fluctuations. We study the role of a mechanism that could affect the shape of the Cosmic Microwave Background angular fluctuations at those scales, namely a change in the recombination process through variations in the fine structure constant α

  4. Pulsed EM Field Response of a Thin, High-Contrast, Finely Layered Structure With Dielectric and Conductive Properties

    NARCIS (Netherlands)

    De Hoop, A.T.; Jiang, L.

    2009-01-01

    The response of a thin, high-contrast, finely layered structure with dielectric and conductive properties to an incident, pulsed, electromagnetic field is investigated theoretically. The fine layering causes the standard spatial discretization techniques to solve Maxwell's equations numerically to

  5. Revisit to diffraction anomalous fine structure

    International Nuclear Information System (INIS)

    Kawaguchi, T.; Fukuda, K.; Tokuda, K.; Shimada, K.; Ichitsubo, T.; Oishi, M.; Mizuki, J.; Matsubara, E.

    2014-01-01

    The diffraction anomalous fine structure method has been revisited by applying this measurement technique to polycrystalline samples and using an analytical method with the logarithmic dispersion relation. The diffraction anomalous fine structure (DAFS) method that is a spectroscopic analysis combined with resonant X-ray diffraction enables the determination of the valence state and local structure of a selected element at a specific crystalline site and/or phase. This method has been improved by using a polycrystalline sample, channel-cut monochromator optics with an undulator synchrotron radiation source, an area detector and direct determination of resonant terms with a logarithmic dispersion relation. This study makes the DAFS method more convenient and saves a large amount of measurement time in comparison with the conventional DAFS method with a single crystal. The improved DAFS method has been applied to some model samples, Ni foil and Fe 3 O 4 powder, to demonstrate the validity of the measurement and the analysis of the present DAFS method

  6. Fine Structure of 211 Po Alpha Decay

    International Nuclear Information System (INIS)

    Mirea, M.

    2000-01-01

    Recently, a theory based on the Landau-Zener effect was developed intending to describe quantitatively the cluster decay fine structure phenomenon. It was claimed that the same promotion effect can also govern the fine structure in the case of α-decay. This formalism intends to explain the fine structure of α-decay by considering single-particle transitions due to the radial and the rotational couplings. The levels with the same good quantum numbers associated to some symmetries of the system cannot in general intersect, but exhibit quasi-crossings, or pseudo-crossings, or avoided level crossings. The system is characterised by an axial symmetry, therefore the good quantum numbers are the projections of the nucleon spin Ω. The radial coupling causes transitions of the unpaired nucleon near the avoided level crossings. True crossings can also be obtained between levels characterized by different quantum numbers. Generally, the rotational coupling has a maximum strength in the vicinity of the true crossings. Transitions due to both couplings are taken into account in order to explain the excitations of the unpaired nucleon. For a tunnelling velocity of 9 x 10 6 fm/fs, the ratio between the intensity for transitions to the first excited state and to the ground state was found to be 0.0071 and the obtained ratio of the same parameter between the second excited state and the ground state was 0.0062, in good agreement with experimental data. These calculations suggest that the α-decay fine structure phenomenon can be explained quantitatively by describing the decaying system with molecular models and it can be stated that the quantitative characteristics of this phenomenon are ruled by dynamical effects. (author)

  7. Study of fine structure of deformed hafnium

    International Nuclear Information System (INIS)

    Voskresenskaya, L.A.; Petukhova, A.S.; Kovalev, K.S.

    1978-01-01

    Variations in the hafnium fine structure following the cold plastic deformation have been studied. The fine structure condition has been studied through the harmonic analysis of the profile of the X-ray diffraction line, obtained at the DRON-I installation. Received has been the dependence of the crystal lattice microdistortions value on the deformation extent for hafnium. This dependence is compared with the corresponding one for zirconium. It is found out that at all the deformations the microdistortion distribution is uniform. The microdistortion value grows with the increase in the compression. During the mechanical impact higher microdistortions of the crystal lattice occur in the hafnium rather than in zirconium

  8. Looking inside giant resonance fine structure

    International Nuclear Information System (INIS)

    Ponomarev, V.Yu.; Voronov, V.V.

    1993-01-01

    Microscopic calculations of the fine structure of giant resonances for spherical nuclei are presented. Excited states are treated by wave function which takes into account coupling of simple one-phonon configurations with more complex ones. Nuclear structure calculations are applied to the description of the γ-decay of resonances into the ground and low-lying excited states. 16 refs.; 4 figs

  9. On a fine structure of a primary impulse of a magnetic storm sudden commencement

    International Nuclear Information System (INIS)

    Parkhomov, V.A.

    1985-01-01

    A fine structure of a primary reverse impulse of a sudden commencement (SSC*) of a magnetic storm is analyzed. 200 cases of SSC* recorded in 1965-79 have been chosen for the investigation. It is shown that the preliminary impulse of the sudden copmencement of magnetic storms has a fine structure in the form of the train of damped oscillations in Pc2-3 range of < or approximately 2 min durations. The excitation of oscillations is related with the propagation of the fast magnetoacoustic wave which is generated during interaction of the interplanetary shock wave with the earth magnetosphere

  10. Distortion product otoacoustic emission fine structure as an early hearing loss predictor

    DEFF Research Database (Denmark)

    Reuter, Karen; Hammershøi, Dorte

    2006-01-01

    height, and ripple prevalence. Temporary changes of the DPOAE fine structure are analyzed by measuring DPOAE both before and after exposing some of the subjects to an intense sound. The characteristic patterns of fine structure can be found in the DPOAE of all subjects, though they are individual...... fine structures are obtained from 74 normal-hearing humans using primary levels of L1/L2=65/45 dB. The subjects belong to groups with different ages and exposure histories. A classification algorithm is developed, which quantifies the fine structure by the parameter's ripple place, ripple width, ripple...

  11. Electronic fine structure and recombination dynamics in single InAs quantum dots

    Energy Technology Data Exchange (ETDEWEB)

    Seguin, R.

    2008-01-28

    In the work at hand single InAs/GaAs quantum dots (QDs) are examined via cathodoluminescence spectroscopy. A thorough analysis of the spectra leads to an unambiguous assignment of the lines to the decay of specific excitonic complexes. A special aspect of the Coulomb interaction, the exchange interaction, gives rise to a fine structure in the initial and final states of an excitonic decay. This leads to a fine structure in the emission spectra that again is unique for every excitonic complex. The exchange interaction is discussed in great detail in this work.QDs of different sizes are investigated and the influence on the electronic properties is monitored. Additionally, the structure is modified ex situ by a thermal annealing process. The changes of the spectra under different annealing temperatures are traced. Finally, recombination dynamics of different excitonic complexes are examined by performing time-resolved cathodoluminescence spectroscopy. (orig.)

  12. Electronic fine structure and recombination dynamics in single InAs quantum dots

    International Nuclear Information System (INIS)

    Seguin, R.

    2008-01-01

    In the work at hand single InAs/GaAs quantum dots (QDs) are examined via cathodoluminescence spectroscopy. A thorough analysis of the spectra leads to an unambiguous assignment of the lines to the decay of specific excitonic complexes. A special aspect of the Coulomb interaction, the exchange interaction, gives rise to a fine structure in the initial and final states of an excitonic decay. This leads to a fine structure in the emission spectra that again is unique for every excitonic complex. The exchange interaction is discussed in great detail in this work.QDs of different sizes are investigated and the influence on the electronic properties is monitored. Additionally, the structure is modified ex situ by a thermal annealing process. The changes of the spectra under different annealing temperatures are traced. Finally, recombination dynamics of different excitonic complexes are examined by performing time-resolved cathodoluminescence spectroscopy. (orig.)

  13. The influence of common stimulus parameters on distortion product otoacoustic emission fine structure.

    Science.gov (United States)

    Johnson, Tiffany A; Baranowski, Lauren G

    2012-01-01

    To determine whether common approaches to setting stimulus parameters influence the depth of fine structure present in the distortion product otoacoustic emission (DPOAE) response. Because the presence of fine structure has been suggested as a possible source of errors, if one of the common parametric approaches results in reduced fine-structure depth, it may be preferred over other approaches. DPOAE responses were recorded in a group of 21 subjects with normal hearing for 1/3-octave intervals surrounding 3 f2s (1, 2, and 4 kHz) at three L2s (30, 45, and 55 dB SPL). For each f2 and L2 combination, L1 and f2/f1 were set according to three commonly used parametric approaches. These included a simple approach, the approach recommended by Kummer et al., and the approach described by Johnson et al. These three approaches primarily differ in the recommended relationship between L1 and L2. For each parametric approach, DPOAE fine structure was evaluated by varying f2 in small steps. Differences in DPOAE level and DPOAE fine-structure depth across f2, L2, and the various stimulus parameters were evaluated using repeated-measures analysis of variance. As expected, significant variations in DPOAE level were observed across the three parametric approaches. For stimulus levels #45 dB SPL, the simple stimuli resulted in lower DPOAE levels than were observed for other approaches. An unexpected finding was that stimulus parameters developed by Johnson et al., which were believed to produce higher DPOAE levels than other approaches, produced the lowest DPOAE levels of the three approaches when f2 = 4 kHz. Significant differences in fine-structure depth were also observed. Greater fine-structure depth was observed with the simple parameters, although this effect was restricted to L2 # 45 dB SPL. When L2 = 55 dB SPL, all three parametric approaches resulted in equivalent fine-structure depth. A significant difference in fine-structure depth across the 3 f2s was also observed. The

  14. Spin fine structure of optically excited quantum dot molecules

    Science.gov (United States)

    Scheibner, M.; Doty, M. F.; Ponomarev, I. V.; Bracker, A. S.; Stinaff, E. A.; Korenev, V. L.; Reinecke, T. L.; Gammon, D.

    2007-06-01

    The interaction between spins in coupled quantum dots is revealed in distinct fine structure patterns in the measured optical spectra of InAs/GaAs double quantum dot molecules containing zero, one, or two excess holes. The fine structure is explained well in terms of a uniquely molecular interplay of spin-exchange interactions, Pauli exclusion, and orbital tunneling. This knowledge is critical for converting quantum dot molecule tunneling into a means of optically coupling not just orbitals but also spins.

  15. Electronic structure study of Co doped CeO2 nanoparticles using X-ray absorption fine structure spectroscopy

    International Nuclear Information System (INIS)

    Kumar, Shalendra; Gautam, Sanjeev; Song, T.K.; Chae, Keun Hwa; Jang, K.W.; Kim, S.S.

    2014-01-01

    Highlights: • The electronic structural of Co–CeO 2 nanoparticles is investigated using XAFS. • Ce M 5,4 , Ce L 3 and O K edge NEXAFS reveal that the Ce-ions are in +4 valence state. • The NEXAFS spectrum performed at Co L3,2-edge confirms Co-ion in 2+ state. • The EXAFS analysis also show that Co ions are occupying Ce position in doped CeO 2 . • The distances between Ce–O and Ce–Ce/Co in all shells decreases with Co doping. - Abstract: We investigated the electronic structure of well characterized Co doped CeO 2 nanoparticles using X-ray absorption fine structure (XAFS) spectroscopy. Near edge X-ray absorption fine structure (NEXAFS) spectra at Ce M 5,4 , Ce L 3 and O K-edge conclude that the Ce-ions are in +4 valence state in pure as well as in Co doped CeO 2 nanoparticles. The local structure around Ce-atom in Co doped CeO 2 nanoparticles was also determined using extended X-ray absorption fine structure (EXAFS) spectroscopy at Ce L 3 edge. The EXAFS analysis suggest that the inter-atomic distance of Ce–O, Ce–Ce/Co decreases with Co doping, which indicate a contraction of the lattice. The decease in Ce–O distance also reflect that there is a formation of oxygen vacancies in CeO 2 matrix. The Debye–Waller factor also shows the consistent behaviour for all the coordination shells. The atomic multiplet calculations for Co L 3,2 -edge was performed to determine the valence state, symmetry and field splitting, which reflect that Co-ions are in 2+ state and substituted at Ce-site with crystal field splitting of 10Dq=-0.57eV. The XAFS measurements reveal that the Co-ions occupy the Ce position in the CeO 2 host matrix and create a oxygen vacancy

  16. Fine structure of synapses on dendritic spines

    Directory of Open Access Journals (Sweden)

    Michael eFrotscher

    2014-09-01

    Full Text Available Camillo Golgi’s Reazione Nera led to the discovery of dendritic spines, small appendages originating from dendritic shafts. With the advent of electron microscopy (EM they were identified as sites of synaptic contact. Later it was found that changes in synaptic strength were associated with changes in the shape of dendritic spines. While live-cell imaging was advantageous in monitoring the time course of such changes in spine structure, EM is still the best method for the simultaneous visualization of all cellular components, including actual synaptic contacts, at high resolution. Immunogold labeling for EM reveals the precise localization of molecules in relation to synaptic structures. Previous EM studies of spines and synapses were performed in tissue subjected to aldehyde fixation and dehydration in ethanol, which is associated with protein denaturation and tissue shrinkage. It has remained an issue to what extent fine structural details are preserved when subjecting the tissue to these procedures. In the present review, we report recent studies on the fine structure of spines and synapses using high-pressure freezing (HPF, which avoids protein denaturation by aldehydes and results in an excellent preservation of ultrastructural detail. In these studies, HPF was used to monitor subtle fine-structural changes in spine shape associated with chemically induced long-term potentiation (cLTP at identified hippocampal mossy fiber synapses. Changes in spine shape result from reorganization of the actin cytoskeleton. We report that cLTP was associated with decreased immunogold labeling for phosphorylated cofilin (p-cofilin, an actin-depolymerizing protein. Phosphorylation of cofilin renders it unable to depolymerize F-actin, which stabilizes the actin cytoskeleton. Decreased levels of p-cofilin, in turn, suggest increased actin turnover, possibly underlying the changes in spine shape associated with cLTP. The findings reviewed here establish HPF as

  17. An Investigation of the Fine Spatial Structure of Meteor Streams Using the Relational Database ``Meteor''

    Science.gov (United States)

    Karpov, A. V.; Yumagulov, E. Z.

    2003-05-01

    We have restored and ordered the archive of meteor observations carried out with a meteor radar complex ``KGU-M5'' since 1986. A relational database has been formed under the control of the Database Management System (DBMS) Oracle 8. We also improved and tested a statistical method for studying the fine spatial structure of meteor streams with allowance for the specific features of application of the DBMS. Statistical analysis of the results of observations made it possible to obtain information about the substance distribution in the Quadrantid, Geminid, and Perseid meteor streams.

  18. Impaired perception of temporal fine structure and musical timbre in cochlear implant users.

    Science.gov (United States)

    Heng, Joseph; Cantarero, Gabriela; Elhilali, Mounya; Limb, Charles J

    2011-10-01

    Cochlear implant (CI) users demonstrate severe limitations in perceiving musical timbre, a psychoacoustic feature of sound responsible for 'tone color' and one's ability to identify a musical instrument. The reasons for this limitation remain poorly understood. In this study, we sought to examine the relative contributions of temporal envelope and fine structure for timbre judgments, in light of the fact that speech processing strategies employed by CI systems typically employ envelope extraction algorithms. We synthesized "instrumental chimeras" that systematically combined variable amounts of envelope and fine structure in 25% increments from two different source instruments with either sustained or percussive envelopes. CI users and normal hearing (NH) subjects were presented with 150 chimeras and asked to determine which instrument the chimera more closely resembled in a single-interval two-alternative forced choice task. By combining instruments with similar and dissimilar envelopes, we controlled the valence of envelope for timbre identification and compensated for envelope reconstruction from fine structure information. Our results show that NH subjects utilize envelope and fine structure interchangeably, whereas CI subjects demonstrate overwhelming reliance on temporal envelope. When chimeras were created from dissimilar envelope instrument pairs, NH subjects utilized a combination of envelope (p = 0.008) and fine structure information (p = 0.009) to make timbre judgments. In contrast, CI users utilized envelope information almost exclusively to make timbre judgments (p < 0.001) and ignored fine structure information (p = 0.908). Interestingly, when the value of envelope as a cue was reduced, both NH subjects and CI users utilized fine structure information to make timbre judgments (p < 0.001), although the effect was quite weak in CI users. Our findings confirm that impairments in fine structure processing underlie poor perception of musical timbre in CI

  19. Derivation of the fine-structure constant

    International Nuclear Information System (INIS)

    Samec, A.

    1980-01-01

    The fine-structure constant is derived as a dynamical property of quantum electrodynamics. Single-particle solutions of the coupled Maxwell and Dirac equations have a physical charge spectrum. The solutions are used to construct lepton-and quark-like particles. The strong, weak, electromagnetic, and gravitational forces are described as the interactions of complex charges in multiple combinations

  20. METHODS OF RECEIVING OF FINE-GRAINED STRUCTURE OF CASTINGS AT CRYSTALLIZATION

    Directory of Open Access Journals (Sweden)

    N. K. Tolochko

    2012-01-01

    Full Text Available The article deals with methods for fine-grained structure of ingots during crystallization depending on the used foundry technologies. It is shown that by using modern scientific and technological advances may improve the traditional and the development of new casting processes, providing production of cast parts with over fine-grained structure and enhanced properties.

  1. Structure of Co-Doped Alq3 thin films investigated by grazing incidence X-ray absorption fine structure and Fourier transform infrared spectroscopy.

    Science.gov (United States)

    Lin, Liang; Pang, Zhiyong; Fang, Shaojie; Wang, Fenggong; Song, Shumei; Huang, Yuying; Wei, Xiangjun; Yu, Haisheng; Han, Shenghao

    2011-02-10

    The structural properties of Co-doped tris(8-hydroxyquinoline)aluminum (Alq(3)) have been studied by grazing incidence X-ray absorption fine structure (GIXAFS) and Fourier transform infrared spectroscopy (FTIR). GIXAFS analysis suggests that there are multivalent Co-Alq(3) complexes and the doped Co atoms tend to locate at the attraction center with respect to N and O atoms and bond with them. The FTIR spectra indicate that the Co atoms interact with the meridional (mer) isomer of Alq(3) rather than forming inorganic compounds.

  2. Fine defective structure of silicon carbide powders obtained from different starting materials

    Directory of Open Access Journals (Sweden)

    Tomila T.V.

    2006-01-01

    Full Text Available The fine defective structure of silicon carbide powders obtained from silicic acid-saccharose, aerosil-saccharose, aerosil-carbon black, and hydrated cellulose-silicic acid gel systems was investigated. The relation between IR absorption characteristics and the microstructure of SiC particles obtained from different starting materials was established. The numerical relationship between the lattice parameter a and the frequency νTO is presented.

  3. Fine structure study on low concentration zinc substituted hydroxyapatite nanoparticles

    International Nuclear Information System (INIS)

    Hu, Wei; Ma, Jun; Wang, Jianglin; Zhang, Shengmin

    2012-01-01

    The fine structure of zinc substituted hydroxyapatite was studied using experimental analysis and first-principles calculations. The synthetic hydroxyapatite nanoparticles containing low Zn concentration show rod-like morphology. The crystallite sizes and unit-cell volumes tended to decrease with the increased Zn concentration according to X-ray diffraction patterns. The Zn K-edge X-ray absorption spectra and fitting results suggest that the hydroxyapatite doped with 0.1 mole% zinc is different in the zinc coordination environments compared with that containing more zinc. The density function theory calculations were performed on zinc substituted hydroxyapatite. Two mechanisms included replacing calcium by zinc and inserting zinc along the hydroxyl column and were investigated, and the related substitution energies were calculated separately. It is found that the substitution energies are negative and lowest for inserting zinc between the two oxygen atoms along the hydroxyl column (c-axis). Combined with the spectral analysis, it is suggested that the inserting mechanism is favored for low concentration zinc substituted hydroxyapatite. Highlights: ► We investigate the fine structure of hydroxyapatite with low content of Zn. ► XANES spectra are similar but a little different at low zinc content. ► Zinc ions influence hydroxyapatite crystal formation and lattice parameters. ► Formation energies are calculated according to plane-wave density function theory. ► Low content of zinc prefers to locate at hydroxyl column in hydroxyapatite lattice.

  4. Analysis of the local structure of AlN:Mn using X-ray absorption fine structure measurements

    Energy Technology Data Exchange (ETDEWEB)

    Miyajima, Takao [Materials Laboratories, Sony Corporation, 4-14-1 Asahi-cho, Atsugi-shi, Kanagawa 243-0014 (Japan); Kudo, Yoshihiro [Materials Analysis Lab., Sony Corporation, 4-18-1 Okada, Atsugi-shi, Kanagawa 243-0021 (Japan); Uruga, Tomoya [Japan Synchrotron Radiation Institute, 1-1-1 Kouto, Mikazuki-cho, Sayo-gun, Hyogo 679-5198 (Japan); Hara, Kazuhiko [Research Inst. of Electronics, Shizuoka Univ., 3-5-1 Johoku, Hamamatsu, Shizuoka 432-8011 (Japan)

    2006-06-15

    The local structure around the Mn atoms in MOCVD-grown AlN:Mn films which show Mn-related red-orange photoluminescence with a 600nm-peak at room temperature was investigated using the X-ray absorption fine structure (XAFS) measurements. We found that Mn atoms occupy Al lattice sites in the AlN film and that the Mn ions have a charge between +2 and +3. From these results, we think that the red-orange luminescence is caused by the transition of d-electrons in the Mn ions. (copyright 2006 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

  5. Theoretical approaches to x-ray absorption fine structure

    International Nuclear Information System (INIS)

    Rehr, J. J.; Albers, R. C.

    2000-01-01

    Dramatic advances in the understanding of x-ray absorption fine structure (XAFS) have been made over the past few decades, which have led ultimately to a highly quantitative theory. This review covers these developments from a unified multiple-scattering viewpoint. The authors focus on extended x-ray absorption fine structure (EXAFS) well above an x-ray edge, and, to a lesser extent, on x-ray absorption near-edge structure (XANES) closer to an edge. The discussion includes both formal considerations, derived from a many-electron formulation, and practical computational methods based on independent-electron models, with many-body effects lumped into various inelastic losses and energy shifts. The main conceptual issues in XAFS theory are identified and their relative importance is assessed; these include the convergence of the multiple-scattering expansion, curved-wave effects, the scattering potential, inelastic losses, self-energy shifts, and vibrations and structural disorder. The advantages and limitations of current computational approaches are addressed, with particular regard to quantitative experimental comparisons. (c) 2000 The American Physical Society

  6. Local hydrated structure of an Fe2+/Fe3+ aqueous solution: an investigation using a combination of molecular dynamics and X-ray absorption fine structure methods

    International Nuclear Information System (INIS)

    Ye Qing; Zhou Jing; Zhao Haifeng; Chen Xing; Chu Wangsheng; Zheng Xusheng; Marcelli, Augusto; Wu Ziyu

    2013-01-01

    The hydrated shell of both Fe 2+ and Fe 3+ aqueous solutions are investigated by using the molecular dynamics (MD) and X-ray absorption structure (XAS) methods. The MD simulations show that the first hydrated shells of both Fe 2+ and Fe 3+ are characterized by a regular octahedron with an Fe-O distance of 2.08Å for Fe 2+ and 1.96Å for Fe 3+ , and rule out the occurrence of a Jahn-Teller distortion in the hydrated shell of an Fe 2+ aqueous solution. The corresponding X-ray absorption near edge fine structure (XANES) calculation successfully reproduces all features in the XANES spectra in Fe 2+ and Fe 3+ aqueous solution. A feature that is located at energy 1 eV higher than the white line (WL) in an Fe 3+ aqueous solution may be assigned to the contribution of the charge transfer. (authors)

  7. Molecular Eigensolution Symmetry Analysis and Fine Structure

    Directory of Open Access Journals (Sweden)

    William G. Harter

    2013-01-01

    Full Text Available Spectra of high-symmetry molecules contain fine and superfine level cluster structure related to J-tunneling between hills and valleys on rovibronic energy surfaces (RES. Such graphic visualizations help disentangle multi-level dynamics, selection rules, and state mixing effects including widespread violation of nuclear spin symmetry species. A review of RES analysis compares it to that of potential energy surfaces (PES used in Born-Oppenheimer approximations. Both take advantage of adiabatic coupling in order to visualize Hamiltonian eigensolutions. RES of symmetric and D2 asymmetric top rank-2-tensor Hamiltonians are compared with Oh spherical top rank-4-tensor fine-structure clusters of 6-fold and 8-fold tunneling multiplets. Then extreme 12-fold and 24-fold multiplets are analyzed by RES plots of higher rank tensor Hamiltonians. Such extreme clustering is rare in fundamental bands but prevalent in hot bands, and analysis of its superfine structure requires more efficient labeling and a more powerful group theory. This is introduced using elementary examples involving two groups of order-6 (C6 and D3~C3v, then applied to families of Oh clusters in SF6 spectra and to extreme clusters.

  8. Renal fine structures detected by NMR imaging

    International Nuclear Information System (INIS)

    Zilch, H.G.

    1986-01-01

    A significantly improved image quality is achieved by the technique described, as compared to the magnetic resonance data obtained so far. The detailed analysis of the kidney goes as deep as into anatomic fine structures, and there is reason to hope for far better diagnostic details. (orig.) [de

  9. [The role of temporal fine structure in tone recognition and music perception].

    Science.gov (United States)

    Zhou, Q; Gu, X; Liu, B

    2017-11-07

    The sound signal can be decomposed into temporal envelope and temporal fine structure information. The temporal envelope information is crucial for speech perception in quiet environment, and the temporal fine structure information plays an important role in speech perception in noise, Mandarin tone recognition and music perception, especially the pitch and melody perception.

  10. Fine structural dependence of ultraviolet reflections in the King Penguin beak horn.

    Science.gov (United States)

    Dresp, Birgitta; Langley, Keith

    2006-03-01

    The visual perception of many birds extends into the near-ultraviolet (UV) spectrum and ultraviolet is used by some to communicate. The beak horn of the King Penguin (Aptenodytes patagonicus) intensely reflects in the ultraviolet and this appears to be implicated in partner choice. In a preliminary study, we recently demonstrated that this ultraviolet reflectance has a structural basis, resulting from crystal-like photonic structures, capable of reflecting in the near-UV. The present study attempted to define the origin of the photonic elements that produce the UV reflectance and to better understand how the UV signal is optimized by their fine structure. Using light and electron microscopic analysis combined with new spectrophotometric data, we describe here in detail the fine structure of the entire King Penguin beak horn in addition to that of its photonic crystals. The data obtained reveal a one-dimensional structural periodicity within this tissue and demonstrate a direct relationship between its fine structure and its function. In addition, they suggest how the photonic structures are produced and how they are stabilized. The measured lattice dimensions of the photonic crystals, together with morphological data on its composition, permit predictions of the wavelength of reflected light. These correlate well with experimentally observed values. The way the UV signal is optimized by the fine structure of the beak tissue is discussed with regard to its putative biological role.

  11. System of an analysis of a fine time structure of X-ray solar flares in the RGS-1M spectrometer

    International Nuclear Information System (INIS)

    Lazutkov, V.P.

    1980-01-01

    The possibilities of RGS-1M spectral equipment intended for determination of more detailed data on the solar flare structure are discussed. Spectrometer modernization permits to record the fine time structure of solar events in the hard X-ray range (50-90 keV). The main requirement for fine time analysis of nonstationary processes is determination of the maximum possible resolution at the maximum available length of the signal under investigation. The scheme of the time analyzer of splash events with the time resolution Δt=62.5 ms and the length of the range processed T=27.6 s is given and described. Operation of the spectrometer telemetric apparatus is considered in detail. The fine solar flare structure occurred on 14.04.79 with visually chosen periodic structure is shown as an example [ru

  12. Directional fine structure in absorption of white x rays: A tomographic interpretation

    International Nuclear Information System (INIS)

    Korecki, P.; Szymonski, M.; Tolkiehn, M.; Novikov, D. V.; Materlik, G.

    2006-01-01

    We discuss directional fine structure in absorption of white x rays for tomographic imaging of crystal structure at the atomic level. The interference between a direct x-ray beam and the secondary waves coherently scattered inside a specimen modifies the total wave field at the position of the absorbing atoms. For a white x-ray beam, the wave field variations cancel out by energy integration for all directions, except for the near forward scattering components, coinciding with the incident beam. Therefore, two-dimensional patterns of the angular-dependent fine structure in absorption of white x rays can be interpreted as real-space projections of atomic structure. In this work, we present a theory describing the directional fine structure in white x-ray absorption and a tomographic approach for crystal structure retrieval developed on its basis. The tomographic algorithm is applied to the experimental x-ray absorption data recorded for GaP crystals

  13. Monte Carlo Simulations of Electron Energy-Loss Spectra with the Addition of Fine Structure from Density Functional Theory Calculations.

    Science.gov (United States)

    Attarian Shandiz, Mohammad; Guinel, Maxime J-F; Ahmadi, Majid; Gauvin, Raynald

    2016-02-01

    A new approach is presented to introduce the fine structure of core-loss excitations into the electron energy-loss spectra of ionization edges by Monte Carlo simulations based on an optical oscillator model. The optical oscillator strength is refined using the calculated electron energy-loss near-edge structure by density functional theory calculations. This approach can predict the effects of multiple scattering and thickness on the fine structure of ionization edges. In addition, effects of the fitting range for background removal and the integration range under the ionization edge on signal-to-noise ratio are investigated.

  14. Extended X-ray absorption fine structure (EXAFS) studies of supported catalysts

    International Nuclear Information System (INIS)

    Joyner, R.W.

    1979-01-01

    Since the rebirth of interest in extended X-ray absorption fine structure there have been several studies of systems of catalytic interest. This note is a preliminary account of an investigation of supported platinum catalysts and NiO/Al 2 O 3 catalysts. Experiments were performed on pressed disc samples at the DESY synchrotron, Hamburg, using the EXAFS spectrometer. The synchrotron operated at 7 GeV energy with a circulating current of approximately 4 mA; spectrum accumulation time was typically 45 minutes. (author)

  15. Connecting traces of galaxy evolution: the missing core mass-morphological fine structure relation

    Science.gov (United States)

    Bonfini, P.; Bitsakis, T.; Zezas, A.; Duc, P.-A.; Iodice, E.; González-Martín, O.; Bruzual, G.; González Sanoja, A. J.

    2018-01-01

    Deep exposure imaging of early-type galaxies (ETGs) are revealing the second-order complexity of these objects, which have been long considered uniform, dispersion-supported spheroidals. `Fine structure' features (e.g. ripples, plumes, tidal tails, rings) as well as depleted stellar cores (i.e. central light deficits) characterize a number of massive ETG galaxies, and can be interpreted as the result of galaxy-galaxy interactions. We discuss how the time-scale for the evolution of cores and fine structures are comparable, and hence it is expected that they develop in parallel after the major interaction event which shaped the ETG. Using archival data, we compare the `depleted stellar mass' (i.e. the mass missing from the depleted stellar core) against the prominence of the fine structure features, and observe that they correlate inversely. This result confirms our expectation that, while the supermassive black hole (SMBH) binary (constituted by the SMBHs of the merger progenitors) excavates the core via three-body interactions, the gravitational potential of the newborn galaxy relaxes, and the fine structures fade below detection levels. We expect the inverse correlation to hold at least within the first Gyr from the merger which created the SMBH binary; after then, the fine structure evolves independently.

  16. Single-particle effects in fine structure of super-asymmetric fission

    International Nuclear Information System (INIS)

    Mirea, M.

    1999-01-01

    Energy spectrum measurements concerning the 14 C decay from 223 Ra revealed a fine structure with an intense branch on the excited state of the daughter 209 Pb. Apart the great number of microscopic--macroscopic attempts of different authors in describing this behavior (compiled recently), this phenomenon was explained quantitatively using the Landau--Zener effect, i.e., the promotion mechanism of a unpaired nucleon between two levels characterised by the same quantum numbers connected to some symmetries of the nuclear system in the region where an avoided level crossing is exhibited. The adiabatic levels during the super-asymmetric fission process were determined with a new version of the two--centre shell model especially constructed for very large mass--asymmetries. The half--lives are obtained in the framework of the Wentzel--Kramers--Brillouin approximation. The amount of the variation of the barrier height in the excited channels was estimated accounting the specialization energy which can be interpreted as the excess of the energy of a nucleon with a given spin over the energy for the same spin nucleon state of lowest energy. It is evidenced that the fine structure of cluster decay is due to two competitive effects: the Landau--Zener effect which enhances the probability to have an excited daughter in the final channel and the specialization energy which increases the potential barrier and therefore leads to a diminution of the penetrability. This formalism was used for predictions of the fine structure in the case of 14 C decay of 225 Ac and to explain the fine structure of alpha decay. (author)

  17. Structure analysis of InN film using extended X-ray absorption fine structure method

    Energy Technology Data Exchange (ETDEWEB)

    Miyajima, T.; Kobayashi, T.; Hirata, S. [Core Technology Development Center, Core Technology and Network Company, Sony Corporation, 4-14-1 Asahi-cho, Atsugi, Kanagawa 243-0014 (Japan); Kudo, Y.; Liu, K.L. [Technology Solutions Center, Sony Corporation, 4-16-1 Okata, Atsugi, Kanagawa 243-0021 (Japan); Uruga, T.; Honma, T. [Japan Synchrotron Radiation Research Institute, Mikazuki-cho, Hyogo 679-5198 (Japan); Saito, Y.; Hori, M.; Nanishi, Y. [Department of Photonics, Ritsumeikan University, 1-1-1 Noji-Higashi, Kusatsu, Shiga 525-8577 (Japan)

    2002-12-01

    We investigated the local atomic structure around In atoms of MBE-grown InN which has a direct bandgap energy of 0.8 eV, using extended X-ray absorption fine structure (EXAFS) oscillation of In K-edge. The signals from the first-nearest neighbor atoms (N) and second-nearest atoms (In) from In atoms were clearly observed and the atomic bond length of In-N and In-In was estimated to be d{sub In-N}=0.215 nm and d{sub In-In}=0.353 nm, respectively. The In-N bond length of d{sub In-In}=0.353 nm was closed to the a-axis lattice constant of a=0.3536 nm, which was determined using X-ray diffraction measurements. The obtained local atomic structure agreed with the calculated ideal structure. We conclude, therefore, that the InN film with a bandgap energy of 0.8 eV has a high structural symmetry in the range of a few A around In atoms. (Abstract Copyright [2002], Wiley Periodicals, Inc.)

  18. Structure analysis of InN film using extended X-ray absorption fine structure method

    International Nuclear Information System (INIS)

    Miyajima, T.; Kobayashi, T.; Hirata, S.; Kudo, Y.; Liu, K.L.; Uruga, T.; Honma, T.; Saito, Y.; Hori, M.; Nanishi, Y.

    2002-01-01

    We investigated the local atomic structure around In atoms of MBE-grown InN which has a direct bandgap energy of 0.8 eV, using extended X-ray absorption fine structure (EXAFS) oscillation of In K-edge. The signals from the first-nearest neighbor atoms (N) and second-nearest atoms (In) from In atoms were clearly observed and the atomic bond length of In-N and In-In was estimated to be d In-N =0.215 nm and d In-In =0.353 nm, respectively. The In-N bond length of d In-In =0.353 nm was closed to the a-axis lattice constant of a=0.3536 nm, which was determined using X-ray diffraction measurements. The obtained local atomic structure agreed with the calculated ideal structure. We conclude, therefore, that the InN film with a bandgap energy of 0.8 eV has a high structural symmetry in the range of a few A around In atoms. (Abstract Copyright [2002], Wiley Periodicals, Inc.)

  19. Fine structure of 25 extragalactic radio sources

    International Nuclear Information System (INIS)

    Wittels, J.J.; Knight, C.A.; Shapiro, I.I.; Hinteregger, H.F.; Rogers, A.E.E.; Whitney, A.R.; Clark, T.A.; Hutton, L.K.; Marandino, G.E.; Neill, A.E.; Ronnang, B.G.; Rydbeck, O.E.H.; Klemperer, W.K.; Warnock, W.W.

    1975-01-01

    Between 1972 April and 1973 May, 25 extragalactic radio sources were observed interferometrically at 7.8 GHz(lambdaapprox. =3.8 cm) with five pairings of antennas. These sources exhibit a broad variety of fine structures from very simple to complex. Although the structure and the total power of some of these sources have remained unchanged within the sensitivity of our measurements during the year of observations, both the total flux and the correlated flux of others have undergone large changes in a few weeks

  20. The Fine Structure of Equity-Index Option Dynamics

    DEFF Research Database (Denmark)

    Andersen, Torben G.; Bondarenko, Oleg; Todorov, Viktor

    We analyze the high-frequency dynamics of S&P 500 equity-index option prices by constructing an assortment of implied volatility measures. This allows us to infer the underlying fine structure behind the innovations in the latent state variables driving the movements of the volatility surface...

  1. Spectral fine structure effects on material and doppler reactivity worth

    International Nuclear Information System (INIS)

    Greenspan, E.; Karni, Y.

    1975-01-01

    New formulations concerning the fine structure effects on the reactivity worth of resonances are developed and conclusions are derived following the extension to more general types of perturbations which include: the removal of resonance material at finite temperatures and the temperature variation of part of the resonance material. It is concluded that the flux method can overpredict the reactivity worth of resonance materials more than anticipated. Calculations on the Doppler worth were carried out; the results can be useful for asessing the contribution of the fine structure effects to the large discrepancy that exists between the calculated and measured small sample Doppler worths. (B.G.)

  2. Angle-resolved photoemission extended fine structure

    International Nuclear Information System (INIS)

    Barton, J.J.

    1985-03-01

    Measurements of the Angle-Resolved Photoemission Extended Fine Structure (ARPEFS) from the S(1s) core level of a c(2 x 2)S/Ni(001) are analyzed to determine the spacing between the S overlayer and the first and second Ni layers. ARPEFS is a type of photoelectron diffraction measurement in which the photoelectron kinetic energy is swept typically from 100 to 600 eV. By using this wide range of intermediate energies we add high precision and theoretical simplification to the advantages of the photoelectron diffraction technique for determining surface structures. We report developments in the theory of photoelectron scattering in the intermediate energy range, measurement of the experimental photoemission spectra, their reduction to ARPEFS, and the surface structure determination from the ARPEFS by combined Fourier and multiple-scattering analyses. 202 refs., 67 figs., 2 tabs

  3. Fine Structure in Helium-like Fluorine by Fast-Beam Laser Spectroscopy

    Science.gov (United States)

    Myers, E. G.; Thompson, J. K.; Silver, J. D.

    1998-05-01

    With the aim of providing an additional precise test of higher-order corrections to high precision calculations of fine structure in helium and helium-like ions(T. Zhang, Z.-C. Yan and G.W.F. Drake, Phys. Rev. Lett. 77), 1715 (1996)., a measurement of the 2^3P_2,F - 2^3P_1,F' fine structure in ^19F^7+ is in progress. The method involves doppler-tuned laser spectroscopy using a CO2 laser on a foil-stripped fluorine ion beam. We aim to achieve a higher precision, compared to an earlier measurement(E.G. Myers, P. Kuske, H.J. Andrae, I.A. Armour, H.A. Klein, J.D. Silver, and E. Traebert, Phys. Rev. Lett. 47), 87 (1981)., by using laser beams parallel and anti-parallel to the ion beam, to obtain partial cancellation of the doppler shift(J.K. Thompson, D.J.H. Howie and E.G. Myers, Phys. Rev. A 57), 180 (1998).. A calculation of the hyperfine structure, allowing for relativistic, QED and nuclear size effects, will be required to obtain the ``hyperfine-free'' fine structure interval from the measurements.

  4. Local Fine Structural Insight into Mechanism of Electrochemical Passivation of Titanium.

    Science.gov (United States)

    Wang, Lu; Yu, Hongying; Wang, Ke; Xu, Haisong; Wang, Shaoyang; Sun, Dongbai

    2016-07-20

    Electrochemically formed passive film on titanium in 1.0 M H2SO4 solution and its thickness, composition, chemical state, and local fine structure are examined by Auger electron spectroscopy (AES), X-ray photoelectron spectroscopy (XPS), and X-ray absorption fine structure. AES analysis reveals that the thickness and composition of oxide film are proportional to the reciprocal of current density in potentiodynamic polarization. XPS depth profiles of the chemical states of titanium exhibit the coexistence of various valences cations in the surface. Quantitative X-ray absorption near edge structure analysis of the local electronic structure of the topmost surface (∼5.0 nm) shows that the ratio of [TiO2]/[Ti2O3] is consistent with that of passivation/dissolution of electrochemical activity. Theoretical calculation and analysis of extended X-ray absorption fine structure spectra at Ti K-edge indicate that both the structures of passivation and dissolution are distorted caused by the appearance of two different sites of Ti-O and Ti-Ti. And the bound water in the topmost surface plays a vital role in structural disorder confirmed by XPS. Overall, the increase of average Ti-O coordination causes the electrochemical passivation, and the dissolution is due to the decrease of average Ti-Ti coordination. The structural variations of passivation in coordination number and interatomic distance are in good agreement with the prediction of point defect model.

  5. 2fl-f2 DPOAE fine structure for 12 symphony orchestra musicians before and after rehearsal

    DEFF Research Database (Denmark)

    Reuter, Karen; Hammershøi, Dorte

    2005-01-01

    The distortion product otoacoustic emission (DPOAE) fine structure is revealed, when measuring DPOAE with a very fine frequency resolution. It is characterized by consistent maxima and minima with notches of up to 20 dB depth. The fine structure is known also from absolute hearing thresholds...

  6. In situ X-ray absorption fine structure studies on the structure of nickel phosphide catalyst supported on K-USY

    CERN Document Server

    Kawai, T; Suzuki, S

    2003-01-01

    Local structure around Ni in a nickel phosphide catalyst supported on K-USY was investigated by an situ X-ray absorption fine structure (XAFS) method during the reduction process of the catalyst and the hydrodesulfurization (HDS) reaction of thiophene. In the passivated sample, Ni phosphide was partially oxidized but after the reduction, 1.1 nm diameter Ni sub 2 P particles were formed with Ni-P and Ni-Ni distances at 0.218 and 0.261 nm, respectively, corresponding to those of bulk Ni sub 2 P. In situ XAFS cleary revealed that the Ni sub 2 P structure was stable under reaction conditions and was an active structure for the HDS process.

  7. Measurement of the fine-structure constant as a test of the Standard Model

    Science.gov (United States)

    Parker, Richard H.; Yu, Chenghui; Zhong, Weicheng; Estey, Brian; Müller, Holger

    2018-04-01

    Measurements of the fine-structure constant α require methods from across subfields and are thus powerful tests of the consistency of theory and experiment in physics. Using the recoil frequency of cesium-133 atoms in a matter-wave interferometer, we recorded the most accurate measurement of the fine-structure constant to date: α = 1/137.035999046(27) at 2.0 × 10‑10 accuracy. Using multiphoton interactions (Bragg diffraction and Bloch oscillations), we demonstrate the largest phase (12 million radians) of any Ramsey-Bordé interferometer and control systematic effects at a level of 0.12 part per billion. Comparison with Penning trap measurements of the electron gyromagnetic anomaly ge ‑ 2 via the Standard Model of particle physics is now limited by the uncertainty in ge ‑ 2; a 2.5σ tension rejects dark photons as the reason for the unexplained part of the muon’s magnetic moment at a 99% confidence level. Implications for dark-sector candidates and electron substructure may be a sign of physics beyond the Standard Model that warrants further investigation.

  8. A study of the fine structure, enzyme activities and pattern of 14CO2 ...

    African Journals Online (AJOL)

    A detailed study of selected grasses has been made with respect to fine structures characteristics, enzyme activities associated with C-4 and C-3 pathway photosynthesis, and short term carbon dioxide-14 incorporation experiments. A good correlation was obtained between the fine structure, the carbon pathway and the ...

  9. X-ray absorption fine structure (XAFS) studies of cobalt silicide thin films

    International Nuclear Information System (INIS)

    Naftel, S.J.; Coulthard, I.; Hu, Y.; Sham, T.K.; Zinke-Allmang, M.

    1998-01-01

    Cobalt silicide thin films, prepared on Si(100) wafers, have been studied by X-ray absorption near edge structures (XANES) at the Si K-, L 2,3 - and Co K-edges utilizing both total electron (TEY) and fluorescence yield (FLY) detection as well as extended X-ray absorption fine structure (EXAFS) at the Co K-edge. Samples made using DC sputter deposition on clean Si surfaces and MBE were studied along with a bulk CoSi 2 sample. XANES and EXAFS provide information about the electronic structure and morphology of the films. It was found that the films studied have essentially the same structure as bulk CoSi 2 . Both the spectroscopy and materials characterization aspects of XAFS (X-ray absorption fine structures) are discussed

  10. Fine structure of the isoscalar giant quadrupole resonance in 40Ca due to Landau damping?

    International Nuclear Information System (INIS)

    Usman, I.; Buthelezi, Z.; Carter, J.; Cooper, G.R.J.; Fearick, R.W.; Foertsch, S.V.; Fujita, H.; Fujita, Y.; Kalmykov, Y.; Neumann-Cosel, P. von; Neveling, R.; Papakonstantinou, P.; Richter, A.; Roth, R.; Shevchenko, A.; Sideras-Haddad, E.; Smit, F.D.

    2011-01-01

    The fragmentation of the Isoscalar Giant Quadrupole Resonance (ISGQR) in 40 Ca has been investigated in high energy-resolution experiments using proton inelastic scattering at E p =200 MeV. Fine structure is observed in the region of the ISGQR and its characteristic energy scales are extracted from the experimental data by means of a wavelet analysis. The experimental scales are well described by Random Phase Approximation (RPA) and second-RPA calculations with an effective interaction derived from a realistic nucleon-nucleon interaction by the Unitary Correlation Operator Method (UCOM). In these results characteristic scales are already present at the mean-field level pointing to their origination in Landau damping, in contrast to the findings in heavier nuclei and also to SRPA calculations for 40 Ca based on phenomenological effective interactions, where fine structure is explained by the coupling to two-particle-two-hole (2p-2h) states.

  11. QED Based Calculation of the Fine Structure Constant

    Energy Technology Data Exchange (ETDEWEB)

    Lestone, John Paul [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

    2016-10-13

    Quantum electrodynamics is complex and its associated mathematics can appear overwhelming for those not trained in this field. Here, semi-classical approaches are used to obtain a more intuitive feel for what causes electrostatics, and the anomalous magnetic moment of the electron. These intuitive arguments lead to a possible answer to the question of the nature of charge. Virtual photons, with a reduced wavelength of λ, are assumed to interact with isolated electrons with a cross section of πλ2. This interaction is assumed to generate time-reversed virtual photons that are capable of seeking out and interacting with other electrons. This exchange of virtual photons between particles is assumed to generate and define the strength of electromagnetism. With the inclusion of near-field effects the model presented here gives a fine structure constant of ~1/137 and an anomalous magnetic moment of the electron of ~0.00116. These calculations support the possibility that near-field corrections are the key to understanding the numerical value of the dimensionless fine structure constant.

  12. FINE-SCALE STRUCTURES OF FLUX ROPES TRACKED BY ERUPTING MATERIAL

    Energy Technology Data Exchange (ETDEWEB)

    Li Ting; Zhang Jun, E-mail: liting@nao.cas.cn, E-mail: zjun@nao.cas.cn [Key Laboratory of Solar Activity, National Astronomical Observatories, Chinese Academy of Sciences, Beijing 100012 (China)

    2013-06-20

    We present Solar Dynamics Observatory observations of two flux ropes tracked out by material from a surge and a failed filament eruption on 2012 July 29 and August 4, respectively. For the first event, the interaction between the erupting surge and a loop-shaped filament in the east seems to 'peel off' the filament and add bright mass into the flux rope body. The second event is associated with a C-class flare that occurs several minutes before the filament activation. The two flux ropes are, respectively, composed of 85 {+-} 12 and 102 {+-} 15 fine-scale structures, with an average width of about 1.''6. Our observations show that two extreme ends of the flux rope are rooted in opposite polarity fields and each end is composed of multiple footpoints (FPs) of fine-scale structures. The FPs of the fine-scale structures are located at network magnetic fields, with magnetic fluxes from 5.6 Multiplication-Sign 10{sup 18} Mx to 8.6 Multiplication-Sign 10{sup 19} Mx. Moreover, almost half of the FPs show converging motion of smaller magnetic structures over 10 hr before the appearance of the flux rope. By calculating the magnetic fields of the FPs, we deduce that the two flux ropes occupy at least 4.3 Multiplication-Sign 10{sup 20} Mx and 7.6 Multiplication-Sign 10{sup 20} Mx magnetic fluxes, respectively.

  13. The connection between the electromagnetic fine structure constant α-bar0 and the monster Lie algebra

    International Nuclear Information System (INIS)

    Marek-Crnjac, L.

    2008-01-01

    The essay gives arguments for deriving the electromagnetic fine structure constant from maximally symmetric spaces. A connection between the order of some subgroups of the monster simple group, the ratio of the proton mass to the electron mass and the fine structure constant is found. A derivation of the fine structure constant from the number of elements in the Cristoffel symbol and the order of the reflection group F 4 is given

  14. Recovering the fine structures in solar images

    Science.gov (United States)

    Karovska, Margarita; Habbal, S. R.; Golub, L.; Deluca, E.; Hudson, Hugh S.

    1994-01-01

    Several examples of the capability of the blind iterative deconvolution (BID) technique to recover the real point spread function, when limited a priori information is available about its characteristics. To demonstrate the potential of image post-processing for probing the fine scale and temporal variability of the solar atmosphere, the BID technique is applied to different samples of solar observations from space. The BID technique was originally proposed for correction of the effects of atmospheric turbulence on optical images. The processed images provide a detailed view of the spatial structure of the solar atmosphere at different heights in regions with different large-scale magnetic field structures.

  15. Fine-structure energy levels, oscillator strengths and lifetimes of ...

    Indian Academy of Sciences (India)

    with the experimental results compiled in the NIST Data Base. Many new ... Keywords. Relativistic fine-structure levels; oscillator strengths; lifetimes. ... have calculated oscillator strengths and lifetimes using the Briet–Pauli R-Matrix ..... [2] The Opacity Project Team, The Opacity Project (Institute of Physics Publishing,. Bristol ...

  16. Strained spiral vortex model for turbulent fine structure

    Science.gov (United States)

    Lundgren, T. S.

    1982-01-01

    A model for the intermittent fine structure of high Reynolds number turbulence is proposed. The model consists of slender axially strained spiral vortex solutions of the Navier-Stokes equation. The tightening of the spiral turns by the differential rotation of the induced swirling velocity produces a cascade of velocity fluctuations to smaller scale. The Kolmogorov energy spectrum is a result of this model.

  17. Investigation of finely dispersed grind of magnetically hard SmCo5 and Nd2Fe14B alloys

    International Nuclear Information System (INIS)

    Balalaev, Yu.N.; Kosobudskij, I.D.

    2000-01-01

    Possibility of preparation of finely dispersed powders of SmCo 5 and Nd 2 Fe 14 B allays investigated and comparison of different types of grinding processes is conducted. Results of comparison of the processes in vibrational mills and disintegrators permit to conclude that density and structure of grindable materials effect on the rate and quality of grinding of magnetically hard alloys [ru

  18. Fine Structure of Plasmaspheric Hiss

    Science.gov (United States)

    Summers, D.; Omura, Y.; Nakamura, S.; Kletzing, C.

    2014-12-01

    Plasmaspheric hiss plays a key role in controlling the structure and dynamics of Earth's radiation belts.The quiet time slot region between the inner and outer belts can be explained as a steady-state balance between earthward radial diffusion and pitch-angle scattering loss of energetic electrons to the atmosphere induced by plasmaspheric hiss. Plasmaspheric hiss can also induce gradual precipitation loss of MeV electrons from the outer radiation belt. Plasmaspheric hiss has been widely regarded as a broadband,structureless,incoherent emission. Here, by examining burst-mode vector waveform data from the EMFISIS instrument on the Van Allen Probes mission,we show that plasmaspheric hiss is a coherent emission with complex fine structure. Specifically, plasmaspheric hiss appears as discrete rising tone and falling tone elements. By means of waveform analysis we identify typical amplitudes,phase profiles,and sweep rates of the rising and falling tone elements. The new observations reported here can be expected to fuel a re-examination of the properties of plasmaspheric hiss, including a further re-analysis of the generation mechanism for hiss.

  19. Fine-structural changes in the midgut of old Drosophila melanogaster

    Science.gov (United States)

    Anton-Erxleben, F.; Miquel, J.; Philpott, D. E.

    1983-01-01

    Senescent fine-structural changes in the midgut of Drosophila melanogaster are investigated. A large number of midgut mitochondria in old flies exhibit nodular cristae and a tubular system located perpendicular to the normal cristae orientation. Anterior intestinal cells show a senescent accumulation of age pigment, either with a surrounding two-unit membrane or without any membrane. The predominant localization of enlarged mitochondria and pigment in the luminal gut region may be related to the polarized metabolism of the intestinal cells. Findings concur with previous observations of dense-body accumulations and support the theory that mitochondria are involved in the aging of fixed post-mitotic cells. Demonstrated by statistical analyses is that mitochondrial size increase is related to mitochondrial variation increase.

  20. The prediction and discovery of Rayleigh line fine structure

    International Nuclear Information System (INIS)

    Fabelinskii, Immanuil L

    2000-01-01

    The history of the theoretical prediction and experimental discovery of the Rayleigh line fine structure (which belongs to one of the most important phenomena in optics and physics of condensed matter) is discussed along with the history of first publications concerning this topic. (from the history of physics)

  1. Helium induced fine structure in the electronic spectra of anthracene derivatives doped into superfluid helium nanodroplets

    International Nuclear Information System (INIS)

    Pentlehner, D.; Slenczka, A.

    2015-01-01

    Electronic spectra of organic molecules doped into superfluid helium nanodroplets show characteristic features induced by the helium environment. Besides a solvent induced shift of the electronic transition frequency, in many cases, a spectral fine structure can be resolved for electronic and vibronic transitions which goes beyond the expected feature of a zero phonon line accompanied by a phonon wing as known from matrix isolation spectroscopy. The spectral shape of the zero phonon line and the helium induced phonon wing depends strongly on the dopant species. Phonon wings, for example, are reported ranging from single or multiple sharp transitions to broad (Δν > 100 cm −1 ) diffuse signals. Despite the large number of example spectra in the literature, a quantitative understanding of the helium induced fine structure of the zero phonon line and the phonon wing is missing. Our approach is a systematic investigation of related molecular compounds, which may help to shed light on this key feature of microsolvation in superfluid helium droplets. This paper is part of a comparative study of the helium induced fine structure observed in electronic spectra of anthracene derivatives with particular emphasis on a spectrally sharp multiplet splitting at the electronic origin. In addition to previously discussed species, 9-cyanoanthracene and 9-chloroanthracene will be presented in this study for the first time

  2. Simple Model with Time-Varying Fine-Structure ``Constant''

    Science.gov (United States)

    Berman, M. S.

    2009-10-01

    Extending the original version written in colaboration with L.A. Trevisan, we study the generalisation of Dirac's LNH, so that time-variation of the fine-structure constant, due to varying electrical and magnetic permittivities is included along with other variations (cosmological and gravitational ``constants''), etc. We consider the present Universe, and also an inflationary scenario. Rotation of the Universe is a given possibility in this model.

  3. Simulations of fine structures on the zero field steps of Josephson tunnel junctions

    DEFF Research Database (Denmark)

    Scheuermann, M.; Chi, C. C.; Pedersen, Niels Falsig

    1986-01-01

    Fine structures on the zero field steps of long Josephson tunnel junctions are simulated for junctions with the bias current injected into the junction at the edges. These structures are due to the coupling between self-generated plasma oscillations and the traveling fluxon. The plasma oscillations...... are generated by the interaction of the bias current with the fluxon at the junction edges. On the first zero field step, the voltages of successive fine structures are given by Vn=[h-bar]/2e(2omegap/n), where n is an even integer. Applied Physics Letters is copyrighted by The American Institute of Physics....

  4. Effects of proton irradiation on structure of NdFeB permanent magnets studied by X-ray diffraction and X-ray absorption fine structure

    International Nuclear Information System (INIS)

    Yang, L.; Zhen, L.; Xu, C.Y.; Sun, X.Y.; Shao, W.Z.

    2011-01-01

    The effects of proton irradiation on the structure of NdFeB permanent magnet were investigated by X-ray diffraction and X-ray absorption fine structure (XAFS). The results reveal that proton irradiation has no effect on the long-range structure, but significantly affects the atomic local structure of the NdFeB magnet. The alignment degree of the magnet decreases and the internal stress of the lattice increases after proton irradiation. XAFS results show that the coordination number of Fe-Nd in the first neighboring coordination shell of the Fe atoms decreases and the disorder degree increases.

  5. Effects of proton irradiation on structure of NdFeB permanent magnets studied by X-ray diffraction and X-ray absorption fine structure

    Energy Technology Data Exchange (ETDEWEB)

    Yang, L. [School of Materials Science and Engineering, Harbin Institute of Technology, Harbin 150001 (China); Zhen, L., E-mail: lzhen@hit.edu.c [School of Materials Science and Engineering, Harbin Institute of Technology, Harbin 150001 (China); Xu, C.Y.; Sun, X.Y.; Shao, W.Z. [School of Materials Science and Engineering, Harbin Institute of Technology, Harbin 150001 (China)

    2011-01-15

    The effects of proton irradiation on the structure of NdFeB permanent magnet were investigated by X-ray diffraction and X-ray absorption fine structure (XAFS). The results reveal that proton irradiation has no effect on the long-range structure, but significantly affects the atomic local structure of the NdFeB magnet. The alignment degree of the magnet decreases and the internal stress of the lattice increases after proton irradiation. XAFS results show that the coordination number of Fe-Nd in the first neighboring coordination shell of the Fe atoms decreases and the disorder degree increases.

  6. Fine structure in plasma waves and radiation near the plasma frequency in Earth's foreshock

    Science.gov (United States)

    Cairns, Iver H.

    1994-01-01

    Novel observations are presented of intrunsic fine structure in the frequency spectrum of electomagnetic (EM) radiation and plasma waves near the electron plasma frequency f(sub p) during a period of unusually high interplanetary magnetic field strength. Measured using the wideband receiver on the International Sun-Earth Explorer (ISEE) 1 spacecraft, fine-structured emissions are observed both in the solar wind and the foreshock, The fine structure is shown to correspond to emissions spaced above f(sub p) near half harmonies of the electon cyclotron frequency f(sub ce), i.e., near f(sub p) + nf(sub ce)/2. These appear to be the first space physics observations of emissions spaced by f(sub ce)/2. Indirect but strong arguments are used to discriminate between EM and electrostatic (ES) signals, to identify whether ISEE 1 is in the solar wind or the foreshock, and to determine the relative frequencies of the emissions and the local f(sub p). The data are consistent with generation of the ES and EM emissions in the foreshock, with subsequent propagation of the EM emissions into the solar wind. It remains possible that some emissions currently identified as ES have significant EM character. The ES and EM emisions often merge into one another with minimal changes in frequency, arguing that their source regions and generation mechanisms are related and imposing significant constraints on theories. The f(sub ce)/2 ES and EM fine structures observed may be intrinsic to the emission mechanisms or to superposition of two series of signals with f(sub ce) spacing that differ in starting frequency by f(sub ce)/2. Present theories for nonlinear wave coupling processes, cyclotron maser emission, and other linear instability processes are all unable to explain multiple EM and/or ES components spaced by approximately f(sub ce)/2 above f(sub p) for f(sub p)/f(sub ce) much greater than 1 and typical for shock beams parameters. Suitable avenues for further theoretical research are

  7. Fine structure of fields in 2D photonic crystal waveguides

    DEFF Research Database (Denmark)

    Lavrinenko, Andrei; Volkov, V. S.; Bozhevolnyi, S. I.

    2006-01-01

    We resolve fine structure of fields in a single-row missing photonic crystal waveguide by finite-difference time-domain modelling and SNOM measurements. Both linear dispersion and slow-light regimes in proximity of the cutoff are addressed in the analysis....

  8. A preliminary investigation of fine sediment dynamics in Cumbarjua canal, Goa

    Digital Repository Service at National Institute of Oceanography (India)

    Mehta, A; Nayak, B.U.; Hayter, E

    A preliminary field investigation was carried out in a 10 km reach of Cumbarjua Canal, Goa, India, where the sediment is in the fine size range, and the flow is primarily tide-induced. Results based on observations made during February, 1980...

  9. Big bang nucleosynthesis with a varying fine structure constant and nonstandard expansion rate

    International Nuclear Information System (INIS)

    Ichikawa, Kazuhide; Kawasaki, Masahiro

    2004-01-01

    We calculate the primordial abundances of light elements produced during big bang nucleosynthesis when the fine structure constant and/or the cosmic expansion rate take nonstandard values. We compare them with the recent values of observed D, 4 He, and 7 Li abundances, which show a slight inconsistency among themselves in the standard big bang nucleosynthesis scenario. This inconsistency is not solved by considering either a varying fine structure constant or a nonstandard expansion rate separately but solutions are found by their simultaneous existence

  10. A tale of two pectins: Diverse fine structures can result from identical processive PME treatments on similar high DM subtrates

    Science.gov (United States)

    The effects of a processive pectin-methylesterase treatment on two different pectins, both possessing a high degree of methylesterification, were investigated. While the starting samples were purportedly very similar in fine structure, and even though the sample-averaged degree of methylesterificati...

  11. Fine surface structure of unfixed and hydrated macrophages observed by laser-plasma x-ray contact microscopy

    International Nuclear Information System (INIS)

    Yamamoto, Yoshimasa; Friedman, Herman; Yoshimura, Hideyuki; Kinjo, Yasuhito; Shioda, Seiji; Debari, Kazuhiro; Shinohara, Kunio; Rajyaguru, Jayshree; Richardson, Martin

    2000-01-01

    A compact, high-resolution, laser-plasma, x-ray contact microscope using a table-top Nd:glass laser system has been developed and utilized for the analysis of the surface structure of live macrophages. Fine fluffy surface structures of murine peritoneal macrophages, which were live, hydrolyzed and not sliced and stained, were observed by the x-ray microscope followed by analysis using an atomic force microscopy. In order to compare with other techniques, a scanning electron microscopy (SEM) was utilized to observe the surface structure of the macrophages. The SEM offered a fine whole cell image of the same macrophages, which were fixed and dehydrated, but the surfaces were ruffled and different from that of x-ray images. A standard light microscope was also utilized to observe the shape of live whole macrophages. Light microscopy showed some fluffy surface structures of the macrophages, but the resolution was too low to observe the fine structures. Thus, the findings of fine fluffy surface structures of macrophages by x-ray microscopy provide valuable information for studies of phagocytosis, cell spreading and adherence, which are dependent on the surface structure of macrophages. Furthermore, the present study also demonstrates the usefulness of x-ray microscopy for analysis of structures of living cells

  12. Development of a fine and ultra-fine group cell calculation code SLAROM-UF for fast reactor analyses

    International Nuclear Information System (INIS)

    Hazama, Taira; Chiba, Go; Sugino, Kazuteru

    2006-01-01

    A cell calculation code SLAROM-UF has been developed for fast reactor analyses to produce effective cross sections with high accuracy in practical computing time, taking full advantage of fine and ultra-fine group calculation schemes. The fine group calculation covers the whole energy range in a maximum of 900-group structure. The structure is finer above 52.5 keV with a minimum lethargy width of 0.008. The ultra-fine group calculation solves the slowing down equation below 52.5 keV to treat resonance structures directly and precisely including resonance interference effects. Effective cross sections obtained in the two calculations are combined to produce effective cross sections over the entire energy range. Calculation accuracy and improvements from conventional 70-group cell calculation results were investigated through comparisons with reference values obtained with continuous energy Monte Carlo calculations. It was confirmed that SLAROM-UF reduces the difference in k-infinity from 0.15 to 0.01% for a JOYO MK-I fuel subassembly lattice cell calculation, and from - 0.21% to less than a statistical uncertainty of the reference calculation of 0.03% for a ZPPR-10A core criticality calculation. (author)

  13. High-resolution x-ray spectroscopy of coherent bremsstrahlung fine structure

    International Nuclear Information System (INIS)

    Lund, M.W.

    1989-01-01

    The aim of this research was to provide experimental evidence for fine structure due to umklapp by distinct reciprocal lattice vectors in coherent bremsstrahlung spectra. The spontaneous emission of photons by relativistic electrons transversing thin crystals is made possible by recoil of the crystal, which absorbs momentum in multiples of ℎG where G is a reciprocal lattice vector. Previous work in the MeV-GeV beam energy range used detectors whose energy resolution was greater than 10%. By fitting a Johann wavelength dispersive spectrometer to a transmission electron microscope the author obtained coherent bremsstrahlung spectra of very high quality with energy resolution of 1%. Important to this result were also the fine angular collimation, small energy width of the electron beam in the microscope, and the accurate control of crystal orientation possible in a modern goniometer stage. The theory of the design of bent crystal x-ray spectrometers is extended to include effects of defocus and aberrations. The theory for diffraction from a stationary three dimensional grating due to a dipole radiator moving at relativistic speeds is derived as well as several other broadening mechanisms stemming from experimental variables. This dissertation provides the first experimental observations and corresponding theoretical background for the fine structure of coherent bremsstrahlung due to umklapp by different G-vectors in the same reciprocal lattice plane

  14. Fine tuning of work practices of common radiological investigations performed using computed radiography system

    International Nuclear Information System (INIS)

    Livingstone, Roshan S.; Timothy Peace, B.S.; Sunny, S.; Victor Raj, D.

    2007-01-01

    Introduction: The advent of the computed radiography (CR) has brought about remarkable changes in the field of diagnostic radiology. A relatively large cross-section of the human population is exposed to ionizing radiation on account of common radiological investigations. This study is intended to audit radiation doses imparted to patients during common radiological investigations involving the use of CR systems. Method: The entrance surface doses (ESD) were measured using thermoluminescent dosimeters (TLD) for various radiological investigations performed using the computed radiography (CR) systems. Optimization of radiographic techniques and radiation doses was done by fine tuning the work practices. Results and conclusion: Reduction of radiation doses as high as 47% was achieved during certain investigations with the use of optimized exposure factors and fine-tuned work practices

  15. Relativistic corrections to fine structure of positronium

    International Nuclear Information System (INIS)

    Martynenko, A.P.; Faustov, R.N.

    1997-01-01

    On the basis of the quasipotential method, we have calculated the relativistic corrections in the positronium fine structure intervals 2 3 S 1 -2 3 P J . The contributions of order of mα 6 for the positronium S-levels were obtained from the one-photon, two-photon interactions and the second-order perturbation theory. We have obtained also the contribution of the two-photon annihilation diagrams to the interaction operator of the P-wave positronium. The corrections of order of α 5 R ∞ and α 5 1nαR ∞ to the P-wave energy levels of positronium were calculated

  16. Grazing incidence x-ray diffraction at free-standing nanoscale islands: fine structure of diffuse scattering

    International Nuclear Information System (INIS)

    Grigoriev, D; Hanke, M; Schmidbauer, M; Schaefer, P; Konovalov, O; Koehler, R

    2003-01-01

    We have investigated the x-ray intensity distribution around 220 reciprocal lattice point in case of grazing incidence diffraction at SiGe nanoscale free-standing islands grown on Si(001) substrate by LPE. Experiments and computer simulations based on the distorted wave Born approximation utilizing the results of elasticity theory obtained by FEM modelling have been carried out. The data reveal fine structure in the distribution of scattered radiation with well-pronounced maxima and complicated fringe pattern. Explanation of the observed diffraction phenomena in their relation to structure and morphology of the island is given. An optimal island model including its shape, size and Ge spatial distribution was elaborated

  17. A Preliminary Experimental Investigation of Wet Fine Erosion in Two-Phase Flow

    Science.gov (United States)

    Ya, H. H.; Luthfi, Haziq; Ngo, Nguyet-Tran; Hassan, Suhaimi; Pao, William

    2018-03-01

    Solid particles below 62 μm is classified as fine. In oil producing operation, the most commonly used downhole sand screen can only capture solid particles of 140 μm and above. Most predictive erosion model is limited to particle size of 100 μm with single phase flow assumption because it is commonly believed that erosion due to particles below 100 μm is insignificant and typically ignored by oil and gas consultants when proposing facilities design. The objective of this paper is to investigate the impact of fines particle on mild steel plate in two-phase flow at different collision angles. A two phase flow loop was set up. The average size of fine particle was 60 μm, mixed with water with sand to water ratio at 1:65 wt/wt. The mild steel plates were oriented at three different impact angles which are -30°, 30° and 90°, with respect to the horizon. Scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDX), surface roughness and Vickers micro hardness techniques were used to quantify the effects of fine particle on the exposed surface.

  18. Fine structure of the mineralized teeth of the chiton Acanthopleura echinata (Mollusca: Polyplacophora).

    Science.gov (United States)

    Wealthall, Rosamund J; Brooker, Lesley R; Macey, David J; Griffin, Brendan J

    2005-08-01

    The major lateral teeth of the chiton Acanthopleura echinata are composite structures composed of three distinct mineral zones: a posterior layer of magnetite; a thin band of lepidocrocite just anterior to this; and apatite throughout the core and anterior regions of the cusp. Biomineralization in these teeth is a matrix-mediated process, in which the minerals are deposited around fibers, with the different biominerals described as occupying architecturally discrete compartments. In this study, a range of scanning electron microscopes was utilized to undertake a detailed in situ investigation of the fine structure of the major lateral teeth. The arrangement of the organic and biomineral components of the tooth is similar throughout the three zones, having no discrete borders between them, and with crystallites of each mineral phase extending into the adjacent mineral zone. Along the posterior surface of the tooth, the organic fibers are arranged in a series of fine parallel lines, but just within the periphery their appearance takes on a "fish scale"-like pattern, reflective of the cross section of a series of units that are overlaid, and offset from each other, in adjacent rows. The units are approximately 2 microm wide and 0.6 microm thick and comprise biomineral plates separated by organic fibers. Two types of subunits make up each "fish scale": one is elongate and curved and forms a trough, in which the other, rod-like unit, is nestled. Adjacent rod and trough units are aligned into large sheets that define the fracture plane of the tooth. The alignment of the plates of rod-trough units is complex and exhibits extreme spatial variation within the tooth cusp. Close to the posterior surface the plates are essentially horizontal and lie in a lateromedial plane, while anteriorly they are almost vertical and lie in the posteroanterior plane. An understanding of the fine structure of the mineralized teeth of chitons, and of the relationship between the organic and

  19. Structure of bimetallic clusters. Extended x-ray absorption fine structure (EXAFS) studies of Rh--Cu clusters

    International Nuclear Information System (INIS)

    Meitzner, G.; Via, G.H.; Lytle, F.W.; Sinfelt, J.H.

    1983-01-01

    An investigation of the structure of the bimetallic clusters present in rhodium--copper catalysts was conducted with the use of extended x-ray absorption fine structure (EXAFS) measurements. Two catalysts were studied, both employing silica as a support for the clusters and both containing 1 wt. % rhodium. In one catalyst the Cu:Rh atomic ratio was 1:2 and in the other 1:1. Studies were made of the EXAFS associated with the K absorption edges of the rhodium and copper. The results of the EXAFS studies indicate that copper concentrates at the surface of the rhodium--copper clusters. In this regard the results are similar to our earlier reported results on ruthenium--copper clusters. However, the extent of surface segregation of the copper appears to be less pronounced for rhodium--copper clusters. This result is reasonable on the basis that rhodium and copper, unlike ruthenium and copper, exhibit at least some miscibility in the bulk

  20. Charge neutrality of fine particle (dusty) plasmas and fine particle cloud under gravity

    Energy Technology Data Exchange (ETDEWEB)

    Totsuji, Hiroo, E-mail: totsuji-09@t.okadai.jp

    2017-03-11

    The enhancement of the charge neutrality due to the existence of fine particles is shown to occur generally under microgravity and in one-dimensional structures under gravity. As an application of the latter, the size and position of fine particle clouds relative to surrounding plasmas are determined under gravity. - Highlights: • In fine particle (dusty) plasmas, the charge neutrality is much enhanced by the existence of fine particles. • The enhancement of charge neutrality generally occurs under microgravity and gravity. • Structure of fine particle clouds under gravity is determined by applying the enhanced charge neutrality.

  1. On the value of the fine structure constant

    International Nuclear Information System (INIS)

    Bosi, L.

    1997-01-01

    The fine structure constant can be approximately expressed as α = (20 var-phi 4 ) -1 where var-phi is the golden ratio (1 + √5)/2: the discrepancy between the present and the true value of α -1 is lower than 3.4· 10 -4 . This simple occurrence would be not fortuitous, thus suggesting a hidden physical meaning. A tentative and qualitative explanation is proposed which is based only on symmetry considerations involving both the Von Klitzing resistance and the vacuum impedance

  2. Simple surface structure determination from Fourier transforms of angle-resolved photoemission extended fine structure

    Energy Technology Data Exchange (ETDEWEB)

    Zheng, Y. [Pennsylvania State Univ., University Park, PA (United States)]|[Lawrence Berkeley Lab., CA (United States); Shirley, D.A. [Pennsylvania State Univ., University Park, PA (United States)

    1995-02-01

    The authors show by Fourier analyses of experimental data, with no further treatment, that the positions of all the strong peaks in Fourier transforms of angle-resolved photoemission extended fine structure (ARPEFS) from adsorbed surfaces can be explicitly predicted from a trial structure with an accuracy of about {+-} 0.3 {angstrom} based on a single-scattering cluster model together with the concept of a strong backscattering cone, and without any additional analysis. This characteristic of ARPEFS Fourier transforms can be developed as a simple method for determining the structures of adsorbed surfaces to an accuracy of about {+-} 0.1 {angstrom}.

  3. Fine structure of cluster decays

    International Nuclear Information System (INIS)

    Dumitrescu, O.

    1993-07-01

    Within the one level R-matrix approach the hindrance factors of the radioactive decays in which are emitted α and 14 C - nuclei are calculated. The generalization to radioactive decays in which are emitted heavier clusters such as e.g. 20 O, 24 Ne, 25 Ne, 28 Mg. 30 Mg, 32 Si and 34 Si is straightforward. The interior wave functions are supposed to be given by the shell model with effective residual interactions (e.g. the large scale shell model code-OXBASH - in the Michigan State University version for nearly spherical nuclei or by the enlarged superfluid model - ESM - recently proposed for deformed nuclei). The exterior wave functions are calculated from a cluster - nucleus double - folding model potential obtained with the M3Y interaction. As examples of the cluster decay fine structure we analyzed the particular cases of α - decay of 241 Am and 14 C -decay of 233 Ra. Good agreement with the experimental data is obtained. (author). 78 refs, 2 figs, 6 tabs

  4. Rotational and fine structure of open-shell molecules in nearly degenerate electronic states

    Science.gov (United States)

    Liu, Jinjun

    2018-03-01

    An effective Hamiltonian without symmetry restriction has been developed to model the rotational and fine structure of two nearly degenerate electronic states of an open-shell molecule. In addition to the rotational Hamiltonian for an asymmetric top, this spectroscopic model includes the energy separation between the two states due to difference potential and zero-point energy difference, as well as the spin-orbit (SO), Coriolis, and electron spin-molecular rotation (SR) interactions. Hamiltonian matrices are computed using orbitally and fully symmetrized case (a) and case (b) basis sets. Intensity formulae and selection rules for rotational transitions between a pair of nearly degenerate states and a nondegenerate state have also been derived using all four basis sets. It is demonstrated using real examples of free radicals that the fine structure of a single electronic state can be simulated with either a SR tensor or a combination of SO and Coriolis constants. The related molecular constants can be determined precisely only when all interacting levels are simulated simultaneously. The present study suggests that analysis of rotational and fine structure can provide quantitative insights into vibronic interactions and related effects.

  5. An estimation of the fine structure constant using fiber bundles

    International Nuclear Information System (INIS)

    Ross, D.K.

    1986-01-01

    Ross calculates g 0 /e, where g 0 is the strength of an elementary magnetic monopole and e is the charge on the electron, in terms of a ratio of loop sizes in the twisted and untwisted principal fiber bundles with U (1) the structure group and R 3 -(0) the base space. The result involves the present distance around the U (1) space and, rather surprisingly, the structure of the quantum gravitational vacuum. Combining this result with the expression for eg 0 from the Dirac quantization conditions gives a final estimate for the fine structure constant, alpha, near 1/100

  6. The impact of mating systems and dispersal on fine-scale genetic structure at maternally, paternally and biparentally inherited markers.

    Science.gov (United States)

    Shaw, Robyn E; Banks, Sam C; Peakall, Rod

    2018-01-01

    For decades, studies have focused on how dispersal and mating systems influence genetic structure across populations or social groups. However, we still lack a thorough understanding of how these processes and their interaction shape spatial genetic patterns over a finer scale (tens-hundreds of metres). Using uniparentally inherited markers may help answer these questions, yet their potential has not been fully explored. Here, we use individual-level simulations to investigate the effects of dispersal and mating system on fine-scale genetic structure at autosomal, mitochondrial and Y chromosome markers. Using genetic spatial autocorrelation analysis, we found that dispersal was the major driver of fine-scale genetic structure across maternally, paternally and biparentally inherited markers. However, when dispersal was restricted (mean distance = 100 m), variation in mating behaviour created strong differences in the comparative level of structure detected at maternally and paternally inherited markers. Promiscuity reduced spatial genetic structure at Y chromosome loci (relative to monogamy), whereas structure increased under polygyny. In contrast, mitochondrial and autosomal markers were robust to differences in the specific mating system, although genetic structure increased across all markers when reproductive success was skewed towards fewer individuals. Comparing males and females at Y chromosome vs. mitochondrial markers, respectively, revealed that some mating systems can generate similar patterns to those expected under sex-biased dispersal. This demonstrates the need for caution when inferring ecological and behavioural processes from genetic results. Comparing patterns between the sexes, across a range of marker types, may help us tease apart the processes shaping fine-scale genetic structure. © 2017 John Wiley & Sons Ltd.

  7. Fine structure in deformed proton emitting nuclei

    International Nuclear Information System (INIS)

    Sonzogni, A. A.; Davids, C. N.; Woods, P. J.; Seweryniak, D.; Carpenter, M. P.; Ressler, J. J.; Schwartz, J.; Uusitalo, J.; Walters, W. B.

    1999-01-01

    In a recent experiment to study the proton radioactivity of the highly deformed 131 Eu nucleus, two proton lines were detected. The higher energy one was assigned to the ground-state to ground-state decay, while the lower energy, to the ground-state to the 2 + state decay. This constitutes the first observation of fine structure in proton radioactivity. With these four measured quantities, proton energies, half-life and branching ratio, it is possible to determine the Nilsson configuration of the ground state of the proton emitting nucleus as well as the 2 + energy and nuclear deformation of the daughter nucleus. These results will be presented and discussed

  8. Extended x-ray absorption fine structure study of MnFeP0.56Si0.44 compound

    International Nuclear Information System (INIS)

    Li Ying-Jie; Haschaolu W; Wurentuya; Song Zhi-Qiang; Ou Zhi-Qiang; Tegus O; Nakai Ikuo

    2015-01-01

    The MnFeP 0.56 Si 0.44 compound is investigated by x-ray diffraction, magnetic measurements, and x-ray absorption fine structure spectroscopy. It crystallizes in Fe 2 P-type structure with the lattice parameters a = b = 5.9823(0) Å and c = 3.4551(1) Å and undergoes a first-order phase transition at the Curie temperature of 255 K. The Fe K edge and Mn K edge x-ray absorption fine structure spectra show that Mn atoms mainly reside at 3g sites, while 3f sites are occupied by Fe atoms. The distances between the absorbing Fe atom and the first and second nearest neighbor Fe atoms in a 3f-layer shift from 2.65 Å and 4.01 Å in the ferromagnetic state to 2.61 Å and 3.96 Å in the paramagnetic phase. On the other hand, the distance between the 3g-layer and 3f-layer changes a little as 2.66 Å–2.73 Å below the Curie temperature and 2.68 Å–2.75 Å above it. (paper)

  9. Relativistic corrections to the fine structure of positronium

    International Nuclear Information System (INIS)

    Faustov, R. N.; Martynenko, A. P.

    1997-01-01

    The quasipotential method is used to calculate relativistic corrections in the positronium-fine-structure intervals 2 3 S 1 -2 3 P J . From analysis of one- and two-photon interactions, corrections of order mα 6 are found for positronium S states in the second order of perturbation theory. The contribution of the two-photon annihilation diagrams to the interaction operator for P-wave positronium is determined, and corrections of orders α 5 R ∞ and α 5 ln αR ∞ to the P-wave levels of positronium are calculated

  10. The architecture and fine structure of gill filaments in the brown ...

    African Journals Online (AJOL)

    The architecture and fine structure of gill filaments in the brown mussel, Perna perna. MA Gregory' ... exhibit many of the characteristics which are widely sought in sentinel ... tion surveys (Gardner, Connell, Eagle, Moldan, Oliff, Orren ..... From the undifferentiated cell/lateral cell interface to the cen- .... amorphous material.

  11. Fine structure of Tibetan kefir grains and their yeast distribution, diversity, and shift.

    Directory of Open Access Journals (Sweden)

    Man Lu

    Full Text Available Tibetan kefir grains (TKGs, a kind of natural starter for fermented milk in Tibet, China, host various microorganisms of lactic acid bacteria, yeasts, and occasionally acetic acid bacteria in a polysaccharide/protein matrix. In the present study, the fine structure of TKGs was studied to shed light on this unusual symbiosis with stereomicroscopy and thin sections. The results reveal that TKGs consist of numerous small grain units, which are characterized by a hollow globular structure with a diameter between 2.0 and 9.0 mm and a wall thickness of approximately 200 µm. A polyhedron-like net structure, formed mainly by the bacteria, was observed in the wall of the grain units, which has not been reported previously to our knowledge. Towards the inside of the grain unit, the polyhedron-like net structures became gradually larger in diameter and fewer in number. Such fine structures may play a crucial role in the stability of the grains. Subsequently, the distribution, diversity, and shift of yeasts in TKGs were investigated based on thin section, scanning electron microscopy, cloning and sequencing of D1/D2 of the 26S rRNA gene, real-time quantitative PCR, and in situ hybridization with specific fluorescence-labeled oligonucleotide probes. These show that (i yeasts appear to localize on the outer surface of the grains and grow normally together to form colonies embedded in the bacterial community; (ii the diversity of yeasts is relatively low on genus level with three dominant species--Saccharomyces cerevisiae, Kluyveromyces marxianus, and Yarrowia lipolytica; (iii S. cerevisiae is the stable predominant yeast species, while the composition of Kluyveromyces and Yarrowia are subject to change over time. Our results indicate that TKGs are relatively stable in structure, and culture conditions to some extent shape the microbial community and interaction in kefir grains. These findings pave the way for further study of the specific symbiotic

  12. Fine Structure of Tibetan Kefir Grains and Their Yeast Distribution, Diversity, and Shift

    Science.gov (United States)

    Lu, Man; Wang, Xingxing; Sun, Guowei; Qin, Bing; Xiao, Jinzhou; Yan, Shuling; Pan, Yingjie; Wang, Yongjie

    2014-01-01

    Tibetan kefir grains (TKGs), a kind of natural starter for fermented milk in Tibet, China, host various microorganisms of lactic acid bacteria, yeasts, and occasionally acetic acid bacteria in a polysaccharide/protein matrix. In the present study, the fine structure of TKGs was studied to shed light on this unusual symbiosis with stereomicroscopy and thin sections. The results reveal that TKGs consist of numerous small grain units, which are characterized by a hollow globular structure with a diameter between 2.0 and 9.0 mm and a wall thickness of approximately 200 µm. A polyhedron-like net structure, formed mainly by the bacteria, was observed in the wall of the grain units, which has not been reported previously to our knowledge. Towards the inside of the grain unit, the polyhedron-like net structures became gradually larger in diameter and fewer in number. Such fine structures may play a crucial role in the stability of the grains. Subsequently, the distribution, diversity, and shift of yeasts in TKGs were investigated based on thin section, scanning electron microscopy, cloning and sequencing of D1/D2 of the 26S rRNA gene, real-time quantitative PCR, and in situ hybridization with specific fluorescence-labeled oligonucleotide probes. These show that (i) yeasts appear to localize on the outer surface of the grains and grow normally together to form colonies embedded in the bacterial community; (ii) the diversity of yeasts is relatively low on genus level with three dominant species – Saccharomyces cerevisiae, Kluyveromyces marxianus, and Yarrowia lipolytica; (iii) S. cerevisiae is the stable predominant yeast species, while the composition of Kluyveromyces and Yarrowia are subject to change over time. Our results indicate that TKGs are relatively stable in structure, and culture conditions to some extent shape the microbial community and interaction in kefir grains. These findings pave the way for further study of the specific symbiotic associations between S

  13. Fine-Scale Genetic Structure in Finland

    Directory of Open Access Journals (Sweden)

    Sini Kerminen

    2017-10-01

    Full Text Available Coupling dense genotype data with new computational methods offers unprecedented opportunities for individual-level ancestry estimation once geographically precisely defined reference data sets become available. We study such a reference data set for Finland containing 2376 such individuals from the FINRISK Study survey of 1997 both of whose parents were born close to each other. This sampling strategy focuses on the population structure present in Finland before the 1950s. By using the recent haplotype-based methods ChromoPainter (CP and FineSTRUCTURE (FS we reveal a highly geographically clustered genetic structure in Finland and report its connections to the settlement history as well as to the current dialectal regions of the Finnish language. The main genetic division within Finland shows striking concordance with the 1323 borderline of the treaty of Nöteborg. In general, we detect genetic substructure throughout the country, which reflects stronger regional genetic differences in Finland compared to, for example, the UK, which in a similar analysis was dominated by a single unstructured population. We expect that similar population genetic reference data sets will become available for many more populations in the near future with important applications, for example, in forensic genetics and in genetic association studies. With this in mind, we report those extensions of the CP + FS approach that we found most useful in our analyses of the Finnish data.

  14. Fine structure transition cross sections for several alkali+rare gas systems

    International Nuclear Information System (INIS)

    Olson, R.E.

    1975-01-01

    The energy dependence E(cm) 2 P1/2→ 2 P3/2 fine structure transition of the lowest excited states of the alkali are calculated for the following systems: Na, K, Rb+He, Ne, Ar and Cs+He. Encouraging agreement between theory and experiment is obtained [fr

  15. Topological map of the Hofstadter butterfly: Fine structure of Chern numbers and Van Hove singularities

    International Nuclear Information System (INIS)

    Naumis, Gerardo G.

    2016-01-01

    The Hofstadter butterfly is a quantum fractal with a highly complex nested set of gaps, where each gap represents a quantum Hall state whose quantized conductivity is characterized by topological invariants known as the Chern numbers. Here we obtain simple rules to determine the Chern numbers at all scales in the butterfly fractal and lay out a very detailed topological map of the butterfly by using a method used to describe quasicrystals: the cut and projection method. Our study reveals the existence of a set of critical points that separates orderly patterns of both positive and negative Cherns that appear as a fine structure in the butterfly. This fine structure can be understood as a small tilting of the projection subspace in the cut and projection method and by using a Chern meeting formula. Finally, we prove that the critical points are identified with the Van Hove singularities that exist at every band center in the butterfly landscape. - Highlights: • Use a higher dimensional approach to build a topological map of the Hofstadter butterfly. • There is a fine structure of Chern numbers around each rational flux. • Van Hove singularities are limiting points for topological sequences of the fine flux.

  16. Topological map of the Hofstadter butterfly: Fine structure of Chern numbers and Van Hove singularities

    Energy Technology Data Exchange (ETDEWEB)

    Naumis, Gerardo G., E-mail: naumis@fisica.unam.mx [Departamento de Física–Química, Instituto de Física, Universidad Nacional Autónoma de México (UNAM), Apartado Postal 20-364, 01000 México, Distrito Federal (Mexico); Department of Physics and Astronomy, George Mason University, Fairfax, VA 22030 (United States); Escuela Superior de Física y Matemáticas, ESIA-Zacatenco, Instituto Politécnico Nacional, México D.F. (Mexico)

    2016-04-29

    The Hofstadter butterfly is a quantum fractal with a highly complex nested set of gaps, where each gap represents a quantum Hall state whose quantized conductivity is characterized by topological invariants known as the Chern numbers. Here we obtain simple rules to determine the Chern numbers at all scales in the butterfly fractal and lay out a very detailed topological map of the butterfly by using a method used to describe quasicrystals: the cut and projection method. Our study reveals the existence of a set of critical points that separates orderly patterns of both positive and negative Cherns that appear as a fine structure in the butterfly. This fine structure can be understood as a small tilting of the projection subspace in the cut and projection method and by using a Chern meeting formula. Finally, we prove that the critical points are identified with the Van Hove singularities that exist at every band center in the butterfly landscape. - Highlights: • Use a higher dimensional approach to build a topological map of the Hofstadter butterfly. • There is a fine structure of Chern numbers around each rational flux. • Van Hove singularities are limiting points for topological sequences of the fine flux.

  17. Determining biological fine structure by differential absorption of soft x-rays

    International Nuclear Information System (INIS)

    Panessa-Warren, B.J.; Warren, J.B.

    1979-06-01

    The use of soft x-ray contact microscopy in examining histochemically treated human tissue embedded in plastic and exposed as unstained thin sections is demonstrated. When our preliminary data revealed that we could clearly image not only the histochemical reaction product, but the unstained biological fine structure of the surrounding tissues, we decided to test our hypothesis further and see if we could image unstained biological molecular aggregates as well. For this part of the investigation, we chose to examine hydrated proteoglycan aggregates. Proteoglycans are an essential component of the organic matrix of cartilage, and play a primary role in the retention and maintenance of extracellular water. To avoid any artifacts due to the introduction of exogeneous materials, and examine the proteoglycan aggregates in their hydrated, natural configuration, we made contact x-ray images of isolated proteoglycan aggregates in water

  18. Structural investigation of spherical hollow excipient Mannit Q by X-ray microtomography.

    Science.gov (United States)

    Kajihara, Ryusuke; Noguchi, Shuji; Iwao, Yasunori; Yasuda, Yuki; Segawa, Megumi; Itai, Shigeru

    2015-11-10

    The structure of Mannit Q particles, an excipient made by spray-drying a d-mannitol solution, and Mannit Q tablets were investigated by synchrotron X-ray microtomography. The Mannit Q particles had a spherical shape with a hollow core. The shells of the particles consisted of fine needle-shaped crystals, and columnar crystals were present in the hollows. These structural features suggested the following formation mechanism for the hollow particles:during the spray-drying process, the solvent rapidly evaporated from the droplet surface, resulting in the formation of shells made of fine needle-shaped crystals.Solvent remaining inside the shells then evaporated slowly and larger columnar crystals grew as the hollows formed. Although most of the Mannit Q particles were crushed on tableting, some of the particles retained their hollow structures, probably because the columnar crystals inside the hollows functioned as props. This demonstrated that the tablets with porous void spaces may be readily manufactured using Mannit Q. Copyright © 2015 Elsevier B.V. All rights reserved.

  19. Towards atomically resolved EELS elemental and fine structure mapping via multi-frame and energy-offset correction spectroscopy.

    Science.gov (United States)

    Wang, Yi; Huang, Michael R S; Salzberger, Ute; Hahn, Kersten; Sigle, Wilfried; van Aken, Peter A

    2018-01-01

    Electron energy-loss spectroscopy and energy-dispersive X-ray spectroscopy are two of the most common means for chemical analysis in the scanning transmission electron microscope. The marked progress of the instrumentation hardware has made chemical analysis at atomic resolution readily possible nowadays. However, the acquisition and interpretation of atomically resolved spectra can still be problematic due to image distortions and poor signal-to-noise ratio of the spectra, especially for investigation of energy-loss near-edge fine structures. By combining multi-frame spectrum imaging and automatic energy-offset correction, we developed a spectrum imaging technique implemented into customized DigitalMicrograph scripts for suppressing image distortions and improving the signal-to-noise ratio. With practical examples, i.e. SrTiO 3 bulk material and Sr-doped La 2 CuO 4 superlattices, we demonstrate the improvement of elemental mapping and the EELS spectrum quality, which opens up new possibilities for atomically resolved EELS fine structure mapping. Copyright © 2017 The Authors. Published by Elsevier B.V. All rights reserved.

  20. A Nonlinear Transmission Line Model of the Cochlea With Temporal Integration Accounts for Duration Effects in Threshold Fine Structure

    DEFF Research Database (Denmark)

    Verhey, Jesko L.; Mauermann, Manfred; Epp, Bastian

    2017-01-01

    For normal-hearing listeners, auditory pure-tone thresholds in quiet often show quasi periodic fluctuations when measured with a high frequency resolution, referred to as threshold fine structure. Threshold fine structure is dependent on the stimulus duration, with smaller fluctuations for short...... than for long signals. The present study demonstrates how this effect can be captured by a nonlinear and active model of the cochlear in combination with a temporal integration stage. Since this cochlear model also accounts for fine structure and connected level dependent effects, it is superior...

  1. Effect of electron correlations and Breit interactions on ground-state fine-structures along the nitrogen-like isoelectronic sequence

    International Nuclear Information System (INIS)

    Wang Xiaolu; Lu Wenlai; Gao Xiang; Li Jiaming

    2009-01-01

    The accurate atomic data of nitrogen and nitrogen-like ions have an importance role in fusion plasma studies and astrophysics studies. The precise calculation of fine-structures is required to obtain such atomic data. Along the whole nitrogen isoelectronic sequence, the contributions of the electron correlations, the Breit interactions and the quantum electrodynamics corrections on the ground-state fine-structures are elucidated. When Z is low, the electron correlations are important, and the Breit interactions, which cannot be neglected cause interesting anomalous fine-structure splittings. When Z is high, the electron correlations are less important, and the Breit interactions are important in addition to spin-orbit interactions for precise calculations. (authors)

  2. Influence of musical training on sensitivity to temporal fine structure.

    Science.gov (United States)

    Mishra, Srikanta K; Panda, Manasa R; Raj, Swapna

    2015-04-01

    The objective of this study was to extend the findings that temporal fine structure encoding is altered in musicians by examining sensitivity to temporal fine structure (TFS) in an alternative (non-Western) musician model that is rarely adopted--Indian classical music. The sensitivity to TFS was measured by the ability to discriminate two complex tones that differed in TFS but not in envelope repetition rate. Sixteen South Indian classical (Carnatic) musicians and 28 non-musicians with normal hearing participated in this study. Musicians have significantly lower relative frequency shift at threshold in the TFS task compared to non-musicians. A significant negative correlation was observed between years of musical experience and relative frequency shift at threshold in the TFS task. Test-retest repeatability of thresholds in the TFS tasks was similar for both musicians and non-musicians. The enhanced performance of the Carnatic-trained musicians suggests that the musician advantage for frequency and harmonicity discrimination is not restricted to training in Western classical music, on which much of the previous research on musical training has narrowly focused. The perceptual judgments obtained from non-musicians were as reliable as those of musicians.

  3. Lack of sex-biased dispersal promotes fine-scale genetic structure in alpine ungulates

    Science.gov (United States)

    Gretchen H. Roffler; Sandra L. Talbot; Gordon Luikart; George K. Sage; Kristy L. Pilgrim; Layne G. Adams; Michael K. Schwartz

    2014-01-01

    Identifying patterns of fine-scale genetic structure in natural populations can advance understanding of critical ecological processes such as dispersal and gene flow across heterogeneous landscapes. Alpine ungulates generally exhibit high levels of genetic structure due to female philopatry and patchy configuration of mountain habitats. We assessed the spatial scale...

  4. Fine reservoir structure modeling based upon 3D visualized stratigraphic correlation between horizontal wells: methodology and its application

    Science.gov (United States)

    Chenghua, Ou; Chaochun, Li; Siyuan, Huang; Sheng, James J.; Yuan, Xu

    2017-12-01

    As the platform-based horizontal well production mode has been widely applied in petroleum industry, building a reliable fine reservoir structure model by using horizontal well stratigraphic correlation has become very important. Horizontal wells usually extend between the upper and bottom boundaries of the target formation, with limited penetration points. Using these limited penetration points to conduct well deviation correction means the formation depth information obtained is not accurate, which makes it hard to build a fine structure model. In order to solve this problem, a method of fine reservoir structure modeling, based on 3D visualized stratigraphic correlation among horizontal wells, is proposed. This method can increase the accuracy when estimating the depth of the penetration points, and can also effectively predict the top and bottom interfaces in the horizontal penetrating section. Moreover, this method will greatly increase not only the number of points of depth data available, but also the accuracy of these data, which achieves the goal of building a reliable fine reservoir structure model by using the stratigraphic correlation among horizontal wells. Using this method, four 3D fine structure layer models have been successfully built of a specimen shale gas field with platform-based horizontal well production mode. The shale gas field is located to the east of Sichuan Basin, China; the successful application of the method has proven its feasibility and reliability.

  5. Characterization of self-organized InGaN/GaN quantum dots by Diffraction Anomalous Fine Structure (DAFS)

    International Nuclear Information System (INIS)

    Piskorska, E.; Holy, V.; Siebert, M.; Schmidt, Th.; Falta, J.; Yamaguchi, T.; Hommel, D.; Renevier, H.

    2006-01-01

    The local chemical composition of InGaN quantum dots grown by a MBE method on GaN virtual substrates was investigated by x-ray diffraction anomalous fine-structure method. From the detailed numerical analysis of the data we were able to reconstruct the local neighborhood of Ga atoms at different positions in the dots. Using this approach, we found that the In content increases from 20% at the dot base to 40-50% at the top. (author) [pl

  6. Measurement of the fine structure in 33P helium

    International Nuclear Information System (INIS)

    Yang, D.

    1985-01-01

    The author measured two positions of the Zeeman level crossing between the (J,M) = (2,2) and (0,0) and between the (J,M) = (1,1) and (0,0) sublevels of the 3 3 P state in helium. The zero field fine structure splittings were calculated from these two measured values. These splittings are of interest for a precision test of quantum electrodynamics and giving an independent contribution to fine structure constant determination. This experiment uses time resolved level crossing spectroscopy. A pulsed beam of helium 2 3 S metastables is excited by a pulse of 388.9 nm dye laser light to the 3 3 P state in a dc magnetic field interaction region. After a certain delay time, a 532 nm laser pulse ionizes the atoms from the 3 3 P state. The photoelectrons are detected by a microchannel plate. The magnetic field is in the z direction, while the atomic beam and the two laser beams are in the xy plane. These two laser beams couterpropagate at a 45 0 angle for the atomic beam for convenience. The photoionization signal is recorded as a function of magnetic field near each of the two crossing positions. Results for these two crossing positions are in agreement with, but more precise than, the previously reported results

  7. Atomic oxygen fine-structure splittings with tunable far-infrared spectroscopy

    Science.gov (United States)

    Zink, Lyndon R.; Evenson, Kenneth M.; Matsushima, Fusakazu; Nelis, Thomas; Robinson, Ruth L.

    1991-01-01

    Fine-structure splittings of atomic oxygen (O-16) in the ground state have been accurately measured using a tunable far-infrared spectrometer. The 3P0-3pl splitting is 2,060,069.09 (10) MHz, and the 3Pl-3P2 splitting is 4,744,777.49 (16) MHz. These frequencies are important for measuring atomic oxygen concentration in earth's atmosphere and the interstellar medium.

  8. Fine- and hyperfine-structure effects in molecular photoionization. I. General theory and direct photoionization

    Energy Technology Data Exchange (ETDEWEB)

    Germann, Matthias; Willitsch, Stefan, E-mail: stefan.willitsch@unibas.ch [Department of Chemistry, University of Basel, Klingelbergstrasse 80, 4056 Basel (Switzerland)

    2016-07-28

    We develop a model for predicting fine- and hyperfine intensities in the direct photoionization of molecules based on the separability of electron and nuclear spin states from vibrational-electronic states. Using spherical tensor algebra, we derive highly symmetrized forms of the squared photoionization dipole matrix elements from which we derive the salient selection and propensity rules for fine- and hyperfine resolved photoionizing transitions. Our theoretical results are validated by the analysis of the fine-structure resolved photoelectron spectrum of O{sub 2} reported by Palm and Merkt [Phys. Rev. Lett. 81, 1385 (1998)] and are used for predicting hyperfine populations of molecular ions produced by photoionization.

  9. Fine- and hyperfine-structure effects in molecular photoionization. I. General theory and direct photoionization.

    Science.gov (United States)

    Germann, Matthias; Willitsch, Stefan

    2016-07-28

    We develop a model for predicting fine- and hyperfine intensities in the direct photoionization of molecules based on the separability of electron and nuclear spin states from vibrational-electronic states. Using spherical tensor algebra, we derive highly symmetrized forms of the squared photoionization dipole matrix elements from which we derive the salient selection and propensity rules for fine- and hyperfine resolved photoionizing transitions. Our theoretical results are validated by the analysis of the fine-structure resolved photoelectron spectrum of O2 reported by Palm and Merkt [Phys. Rev. Lett. 81, 1385 (1998)] and are used for predicting hyperfine populations of molecular ions produced by photoionization.

  10. Acclimation of fine root respiration to soil warming involves starch deposition in very fine and fine roots: a case study in Fagus sylvatica saplings.

    Science.gov (United States)

    Di Iorio, Antonino; Giacomuzzi, Valentino; Chiatante, Donato

    2016-03-01

    Root activities in terms of respiration and non-structural carbohydrates (NSC) storage and mobilization have been suggested as major physiological roles in fine root lifespan. As more frequent heat waves and drought periods within the next decades are expected, to what extent does thermal acclimation in fine roots represent a mechanism to cope with such upcoming climatic conditions? In this study, the possible changes in very fine (diameter respiration rate and NSC [soluble sugars (SS) and starch] concentrations, were investigated on 2-year-old Fagus sylvatica saplings subjected to a simulated long-lasting heat wave event and to co-occurring soil drying. For both very fine and fine roots, soil temperature (ST) resulted inversely correlated with specific root length, respiration rates and SSs concentration, but directly correlated with root mass, root tissue density and starch concentration. In particular, starch concentration increased under 28 °C for successively decreasing under 21 °C ST. These findings showed that thermal acclimation in very fine and fine roots due to 24 days exposure to high ST (∼ 28 °C), induced starch accumulation. Such 'carbon-savings strategy' should bear the maintenance costs associated to the recovery process in case of restored favorable environmental conditions, such as those occurring at the end of a heat wave event. Drought condition seems to affect the fine root vitality much more under moderate than high temperature condition, making the temporary exposure to high ST less threatening to root vitality than expected. © 2015 Scandinavian Plant Physiology Society.

  11. Fine-structure energy levels, oscillator strengths and transition probabilities in Ni XVI

    International Nuclear Information System (INIS)

    Deb, N.C.; Msezane, A.Z.

    2001-01-01

    Fine-structure energy levels relative to the ground state, oscillator strengths and transition probabilities for transitions among the lowest 40 fine-structure levels belonging to the configurations 3s 2 3p, 3s3p 2 , 3s 2 3d, 3p 3 and 3s3p3d of Ni XVI are calculated using a large scale CI in program CIV3 of Hibbert. Relativistic effects are included through the Breit-Pauli approximation via spin-orbit, spin-other-orbit, spin-spin, Darwin and mass correction terms. The existing discrepancies between the calculated and measured values for many of the relative energy positions are resolved in the present calculation which yields excellent agreement with measurement. Also, many of our oscillator strengths for allowed and intercombination transitions are in very good agreement with the recommended data by the National Institute of Standard and Technology (NIST). (orig.)

  12. On the relationship between multi-channel envelope and temporal fine structure

    DEFF Research Database (Denmark)

    Søndergaard, Peter Lempel; Decorsiere, Remi Julien Blaise; Dau, Torsten

    2011-01-01

    The envelope of a signal is broadly defined as the slow changes in time of the signal, where as the temporal fine structure (TFS) are the fast changes in time, i.e. the carrier wave(s) of the signal. The focus of this paper is on envelope and TFS in multi-channel systems. We discuss the differenc...

  13. Wavelength dispersive X-ray absorption fine structure imaging by parametric X-ray radiation

    International Nuclear Information System (INIS)

    Inagaki, Manabu; Sakai, Takeshi; Sato, Isamu; Hayakawa, Yasushi; Nogami, Kyoko; Tanaka, Toshinari; Hayakawa, Ken; Nakao, Keisuke

    2008-01-01

    The parametric X-ray radiation (PXR) generator system at Laboratory for Electron Beam Research and Application (LEBRA) in Nihon University is a monochromatic and coherent X-ray source with horizontal wavelength dispersion. The energy definition of the X-rays, which depends on the horizontal size of the incident electron beam on the generator target crystal, has been investigated experimentally by measuring the X-ray absorption near edge structure (XANES) spectra on Cu and CuO associated with conventional X-ray absorption imaging technique. The result demonstrated the controllability of the spectrum resolution of XANES by adjusting of the horizontal electron beam size on the target crystal. The XANES spectra were obtained with energy resolution of several eV at the narrowest case, which is in qualitative agreement with the energy definition of the PXR X-rays evaluated from geometrical consideration. The result also suggested that the wavelength dispersive X-ray absorption fine structure measurement associated with imaging technique is one of the promising applications of PXR. (author)

  14. Full-potential theoretical investigations of electron inelastic mean free paths and extended x-ray absorption fine structure in molybdenum

    International Nuclear Information System (INIS)

    Chantler, C T; Bourke, J D

    2014-01-01

    X-ray absorption fine structure (XAFS) spectroscopy is one of the most robust, adaptable, and widely used structural analysis tools available for a range of material classes from bulk solids to aqueous solutions and active catalytic structures. Recent developments in XAFS theory have enabled high-accuracy calculations of spectra over an extended energy range using full-potential cluster modelling, and have demonstrated particular sensitivity in XAFS to a fundamental electron transport property—the electron inelastic mean free path (IMFP). We develop electron IMFP theory using a unique hybrid model that simultaneously incorporates second-order excitation losses, while precisely accounting for optical transitions dictated by the complex band structure of the solid. These advances are coupled with improved XAFS modelling to determine wide energy-range absorption spectra for molybdenum. This represents a critical test case of the theory, as measurements of molybdenum K-edge XAFS represent the most accurate determinations of XAFS spectra for any material. We find that we are able to reproduce an extended range of oscillatory structure in the absorption spectrum, and demonstrate a first-time theoretical determination of the absorption coefficient of molybdenum over the entire extended XAFS range utilizing a full-potential cluster model. (paper)

  15. Experimental studies of the refined structure within oxide UO{sub 2} clusters (1983); Etudes experimentales de structure fine a l'interieur de grappes d'oxyde UO{sub 2} (1963)

    Energy Technology Data Exchange (ETDEWEB)

    Palmedo, P F [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1963-07-01

    General measurements of neutron fine structure in various UO{sub 2} clusters are described. The experimental techniques that were found useful are presented, as well as the methods of experimental analysis. The results are given in detail. A semi-empirical relation for the fine structure in clusters is suggested and is compared with the various results. (author) [French] Plusieurs experiences de structure fine de la densite neutronique dans diverses grappes de UO{sub 2} sont decrites. On presente les techniques qui ont ete jugees les plus appropriees pour ce genre de mesure, les methodes d'analyae des experiences, et les resultats detailles. Une expression semi-empirique de la structure fine dans de telles grappes est donnee et elle est comparee avec les divers reaultats obtenue. (auteur)

  16. New analysis methods for skin fine-structure via optical image and development of 3D skin Cycloscan(™).

    Science.gov (United States)

    Han, J Y; Nam, G W; Lee, H K; Kim, M J; Kim, E J

    2015-11-01

    This study was conducted to develop methods for measuring skin fine-structure via optical image and apparatus for photographing to analyze efficacy of anti-aging. We developed an apparatus named 3D Skin CycloScan(™) to evaluate the efficacy of cosmetics by imagification of skin fine-structure such as wrinkles, pores, and skin texture. The semi-sphere shaped device has 12 different sequential flashing light sources captures optical image simultaneously in one second to exclude the influence of the subject's movement. The normal map that is extracted through shape from shading method is composed of face contour and skin fine-structure parts. When the low-frequency component which is the result of the Gaussian Filter application is eliminated, we can get only skin fine-structure. In this normal map, it is possible to extract two-dimensional vector map called direction map and we can regulate the intensity of the image of wrinkles, pores, and skin texture after filtering the direction map. We performed a clinical study to apply this new apparatus and methods to evaluate an anti-aging efficacy of cosmetics visually and validate with other conventional methods. After using anti-aging cream including 2% adenosine for 8 weeks, the total amount of fine wrinkle around eye area detected via 3D Skin CycloScan(™) was reduced by 12.1%. Also, wrinkles on crow's feet measured by PRIMOS COMPACT(®) (GFMesstechnik GmbH, Germany) reduced 11.7%. According to an aspect of the present study, by changing the direction of the lights toward to subject's skin, we can obtain the information about the fine structures present on the skin such as wrinkles, pores, or skin texture and represent it as an image. © 2015 John Wiley & Sons A/S. Published by John Wiley & Sons Ltd.

  17. Determining the Velocity Fine Structure by a Laser Anemometer with Fixed Orientation

    DEFF Research Database (Denmark)

    Kristensen, Leif; Kirkegaard, Peter; Mikkelsen, Torben

    We have studied the velocity structure functions and spectra which can be determined by a CW-laser anemometer and a (pulsed) lidar anemometer. We have found useful theoretical expressions for both types of anemometers and compared their filtering of the alongbeam turbulent velocity. The purpose h...... been to establish a basis for remote determining of turbulence fine-structure in terms of the rate of dissipation of specific kinetic energy in the atmospheric boundary layer....

  18. Demonstrating the Uneven Importance of Fine-Scale Forest Structure on Snow Distributions using High Resolution Modeling

    Science.gov (United States)

    Broxton, P. D.; Harpold, A. A.; van Leeuwen, W.; Biederman, J. A.

    2016-12-01

    Quantifying the amount of snow in forested mountainous environments, as well as how it may change due to warming and forest disturbance, is critical given its importance for water supply and ecosystem health. Forest canopies affect snow accumulation and ablation in ways that are difficult to observe and model. Furthermore, fine-scale forest structure can accentuate or diminish the effects of forest-snow interactions. Despite decades of research demonstrating the importance of fine-scale forest structure (e.g. canopy edges and gaps) on snow, we still lack a comprehensive understanding of where and when forest structure has the largest impact on snowpack mass and energy budgets. Here, we use a hyper-resolution (1 meter spatial resolution) mass and energy balance snow model called the Snow Physics and Laser Mapping (SnowPALM) model along with LIDAR-derived forest structure to determine where spatial variability of fine-scale forest structure has the largest influence on large scale mass and energy budgets. SnowPALM was set up and calibrated at sites representing diverse climates in New Mexico, Arizona, and California. Then, we compared simulations at different model resolutions (i.e. 1, 10, and 100 m) to elucidate the effects of including versus not including information about fine scale canopy structure. These experiments were repeated for different prescribed topographies (i.e. flat, 30% slope north, and south-facing) at each site. Higher resolution simulations had more snow at lower canopy cover, with the opposite being true at high canopy cover. Furthermore, there is considerable scatter, indicating that different canopy arrangements can lead to different amounts of snow, even when the overall canopy coverage is the same. This modeling is contributing to the development of a high resolution machine learning algorithm called the Snow Water Artificial Network (SWANN) model to generate predictions of snow distributions over much larger domains, which has implications

  19. New Tests for Variations of the Fine Structure Constant

    Science.gov (United States)

    Prestage, John D.

    1995-01-01

    We describe a new test for possible variations of the fine structure constant, by comparisons of rates between clocks based on hyperfine transitions in alkali atomos with different atomic number Z. H- maser, Cs and Hg+ clocks have a different dependence on ia relativistic contributions of order (Z. Recent H-maser vs Hg+ clock comparison data improves laboratory limits on a time variation by 100-fold to giveFuture laser cooled clocks (Be+, Rb, Cs, Hg+, etc.), when compared, will yield the most senstive of all tests for.

  20. X-ray absorption fine structure (XAFS) spectroscopy: a tool for structural studies in material sciences (abstract)

    International Nuclear Information System (INIS)

    Akhtar, M.J.

    2011-01-01

    XAFS spectroscopy has revealed itself as a powerful technique for structural characterization of the local atomic environment of individual atomic species, including bond distances, coordination numbers and type of nearest neighbors surrounding the central atom. This technique is particularly useful for materials that show considerable structural and chemical disorder. XAFS spectroscopy has found extensive applications in determining the local atomic and electronic structure of the absorbing centers (atoms) in the materials science, physics, chemistry, biology and geophysics. X-ray absorption edges contain a variety of information on the chemical state and the local structure of the absorbing atom. On the higher energy side of an absorption edge fine structure is observed due to backscattering of the emitted photoelectron. The post-edge region can be divided into two parts. The X-ray Absorption Near Edge Structure (XANES) which extends up to 50 eV of an absorption edge, the spectrum is interpreted in terms of the appropriate components of the local density of states, which would be expected to be sensitive to the valence state of the atom. The intensity, shape and location of the absorption edge features provide information on the valence state, electronic structure and coordination geometry of the absorbing atom.The Extended X-ray Absorption Fine Structure (EXAFS) region is dominated by the single scattering processes and extends up to 1000 eV above the edge and provides information on the radial distribution (coordination number, radial distance and type of neighboring atoms) around the central atom. The results on perovskite based and spinel ferrites systems will be presented, where valence state and cation distributions are determined; the present study will show focus on SrFeO/sub 3/, MnFe/sub 2/O/sub 4/ and Zn/sub 1-x/Ni/sub x/Fe/sub 2/O/sub 4/ materials. (author)

  1. Determining the velocity fine structure by a laser anemometer with fixed orientation

    Energy Technology Data Exchange (ETDEWEB)

    Kristensen, Leif; Kirkegaard, P.; Mikkelsen, Torben

    2011-02-15

    We have studied the velocity structure functions and spectra which can be determined by a CW-laser anemometer and a (pulsed) lidar anemometer. We have found useful theoretical expressions for both types of anemometers and compared their filtering of the along-beam turbulent velocity. The purpose has been to establish a basis for remote determining of turbulence fine-structure in terms of the rate of dissipation of specific kinetic energy in the atmospheric boundary layer. (Author)

  2. Exploring the fine structure at the limb in coronal holes

    Science.gov (United States)

    Karovska, Magarita; Blundell, Solon F.; Habbal, Shadia Rifai

    1994-01-01

    The fine structure of the solar limb in coronal holes is explored at temperatures ranging from 10(exp 4) to 10(exp 6) K. An image enhancement algorithm orignally developed for solar eclipse observations is applied to a number of simultaneous multiwavelength observations made with the Harvard Extreme Ultraviolet Spectrometer experiment on Skylab. The enhanced images reveal the presence of filamentary structures above the limb with a characteristic separation of approximately 10 to 15 sec . Some of the structures extend from the solar limb into the corona to at least 4 min above the solar limb. The brightness of these structures changes as a function of height above the limb. The brightest emission is associated with spiculelike structures in the proximity of the limb. The emission characteristic of high-temperature plasma is not cospatial with the emission at lower temperatures, indicating the presence of different temperature plasmas in the field of view.

  3. State of the art in the determination of the fine structure constant: test of Quantum Electrodynamics and determination of h/mu

    International Nuclear Information System (INIS)

    Bouchendira, Rym; Clade, Pierre; Nez, Francois; Biraben, Francois; Guellati-Khelifa, Saida

    2013-01-01

    The fine structure constant α has a particular status in physics. Its precise determination is required to test the quantum electrodynamics (QED) theory. The constant α is also a keystone for the determination of other fundamental physical constants, especially the ones involved in the framework of the future International System of units. This paper presents Paris experiment, where the fine structure constant is determined by measuring the recoil velocity of a rubidium atom when it absorbs a photon. The impact of the recent improvement of QED calculations of the electron moment anomaly and the recent measurement of the cesium atom recoil at Berkeley will be discussed. The opportunity to provide a precise value of the ratio h/m u between the Planck constant and the atomic mass constant will be investigated. (copyright 2013 by WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  4. Astrophysical extended X-ray absorption fine-structure analysis

    International Nuclear Information System (INIS)

    Woo, J.W.; Forrey, R.C.; Cho, K.; Department of Physics and Division of Applied Sciences, Harvard University)

    1997-01-01

    We present an astrophysical extended X-ray absorption fine-structure (EXAFS) analysis (AEA) tool. The AEA tool is designed to generate a numerical model of the modification to the X-ray absorption coefficient due to the EXAFS phenomenon. We have constructed a complete database (elements up to the atomic number 92) of EXAFS parameters: central atom phase shift (2δ 1 ), backscattering phase shift (φ b ), and backscattering amplitude (F). Using the EXAFS parameter data base, the AEA tool can generate a numerical model of any compound when the atomic numbers of neighboring atoms and their distances to the central X-ray-absorbing atom are given. copyright 1997 The American Astronomical Society

  5. Clonal growth and fine-scale genetic structure in tanoak (Notholithocarpus densiflorus: Fagaceae)

    Science.gov (United States)

    Richard S. Dodd; Wasima Mayer; Alejandro Nettel; Zara Afzal-Rafii

    2013-01-01

    The combination of sprouting and reproduction by seed can have important consequences on fine-scale spatial distribution of genetic structure (SGS). SGS is an important consideration for species’ restoration because it determines the minimum distance among seed trees to maximize genetic diversity while not prejudicing locally adapted genotypes. Local environmental...

  6. Structure and properties of permeable fine-fibrous materials fabricated of powders

    Energy Technology Data Exchange (ETDEWEB)

    Fedorchenko, I M; Kostornov, A G; Kirichenko, O V; Guzhva, N S [AN Ukrainskoj SSR, Kiev. Inst. Problem Materialovedeniya

    1982-09-01

    Effect of main structural characteristics of fine fibrous materials (FFM) of nickel and Ni-Cr, Ni-Mo, Ni-Cr-Mo, Ni-Fe-Cr, Ni-Fe alloys on their hydraulic and mechanical properties was studied. FFM was produced by sintering of polymer fibers filled with metal powders and converted to felts. It was shown, that the level of permeable material properties increases with reduction of filament diameter.

  7. Structure and properties of permeable fine-fibrous materials fabricated of powders

    International Nuclear Information System (INIS)

    Fedorchenko, I.M.; Kostornov, A.G.; Kirichenko, O.V.; Guzhva, N.S.

    1982-01-01

    Effect of main structural characteristicf of fine fibrous materials (FFM) of nickel and Ni-Cr, Ni-Mo, Ni-Cr-Mo, Ni-Fe-Cr, Ni-Fe alloys on their hydraulic and mechanical properties was studied. FFM was produced by sintering of polymer fibers filled with metal powders and converted to felts. It was shown, that the level of permeable material properties increases with reduction of filament diameter

  8. Dispersal, mating events and fine-scale genetic structure in the lesser flat-headed bats.

    Science.gov (United States)

    Hua, Panyu; Zhang, Libiao; Guo, Tingting; Flanders, Jon; Zhang, Shuyi

    2013-01-01

    Population genetic structure has important consequences in evolutionary processes and conservation genetics in animals. Fine-scale population genetic structure depends on the pattern of landscape, the permanent movement of individuals, and the dispersal of their genes during temporary mating events. The lesser flat-headed bat (Tylonycteris pachypus) is a nonmigratory Asian bat species that roosts in small groups within the internodes of bamboo stems and the habitats are fragmented. Our previous parentage analyses revealed considerable extra-group mating in this species. To assess the spatial limits and sex-biased nature of gene flow in the same population, we used 20 microsatellite loci and mtDNA sequencing of the ND2 gene to quantify genetic structure among 54 groups of adult flat-headed bats, at nine localities in South China. AMOVA and F(ST) estimates revealed significant genetic differentiation among localities. Alternatively, the pairwise F(ST) values among roosting groups appeared to be related to the incidence of associated extra-group breeding, suggesting the impact of mating events on fine-scale genetic structure. Global spatial autocorrelation analyses showed positive genetic correlation for up to 3 km, indicating the role of fragmented habitat and the specialized social organization as a barrier in the movement of individuals among bamboo forests. The male-biased dispersal pattern resulted in weaker spatial genetic structure between localities among males than among females, and fine-scale analyses supported that relatedness levels within internodes were higher among females than among males. Finally, only females were more related to their same sex roost mates than to individuals from neighbouring roosts, suggestive of natal philopatry in females.

  9. Dispersal, mating events and fine-scale genetic structure in the lesser flat-headed bats.

    Directory of Open Access Journals (Sweden)

    Panyu Hua

    Full Text Available Population genetic structure has important consequences in evolutionary processes and conservation genetics in animals. Fine-scale population genetic structure depends on the pattern of landscape, the permanent movement of individuals, and the dispersal of their genes during temporary mating events. The lesser flat-headed bat (Tylonycteris pachypus is a nonmigratory Asian bat species that roosts in small groups within the internodes of bamboo stems and the habitats are fragmented. Our previous parentage analyses revealed considerable extra-group mating in this species. To assess the spatial limits and sex-biased nature of gene flow in the same population, we used 20 microsatellite loci and mtDNA sequencing of the ND2 gene to quantify genetic structure among 54 groups of adult flat-headed bats, at nine localities in South China. AMOVA and F(ST estimates revealed significant genetic differentiation among localities. Alternatively, the pairwise F(ST values among roosting groups appeared to be related to the incidence of associated extra-group breeding, suggesting the impact of mating events on fine-scale genetic structure. Global spatial autocorrelation analyses showed positive genetic correlation for up to 3 km, indicating the role of fragmented habitat and the specialized social organization as a barrier in the movement of individuals among bamboo forests. The male-biased dispersal pattern resulted in weaker spatial genetic structure between localities among males than among females, and fine-scale analyses supported that relatedness levels within internodes were higher among females than among males. Finally, only females were more related to their same sex roost mates than to individuals from neighbouring roosts, suggestive of natal philopatry in females.

  10. The variation of the fine-structure constant from disformal couplings

    Energy Technology Data Exchange (ETDEWEB)

    De Bruck, Carsten van; Mifsud, Jurgen [Consortium for Fundamental Physics, School of Mathematics and Statistics, University of Sheffield, Hounsfield Road, Sheffield S3 7RH (United Kingdom); Nunes, Nelson J., E-mail: c.vandebruck@sheffield.ac.uk, E-mail: jmifsud1@sheffield.ac.uk, E-mail: njnunes@fc.ul.pt [Instituto de Astrofísica e Ciências do Espaço, Faculdade de Ciências da Universidade de Lisboa, Campo Grande, PT1749-016 Lisboa (Portugal)

    2015-12-01

    We study a theory in which the electromagnetic field is disformally coupled to a scalar field, in addition to a usual non-minimal electromagnetic coupling. We show that disformal couplings modify the expression for the fine-structure constant, α. As a result, the theory we consider can explain the non-zero reported variation in the evolution of α by purely considering disformal couplings. We also find that if matter and photons are coupled in the same way to the scalar field, disformal couplings itself do not lead to a variation of the fine-structure constant. A number of scenarios are discussed consistent with the current astrophysical, geochemical, laboratory and the cosmic microwave background radiation constraints on the cosmological evolution of α. The models presented are also consistent with the current type Ia supernovae constraints on the effective dark energy equation of state. We find that the Oklo bound in particular puts strong constraints on the model parameters. From our numerical results, we find that the introduction of a non-minimal electromagnetic coupling enhances the cosmological variation in α. Better constrained data is expected to be reported by ALMA and with the forthcoming generation of high-resolution ultra-stable spectrographs such as PEPSI, ESPRESSO, and ELT-HIRES. Furthermore, an expected increase in the sensitivity of molecular and nuclear clocks will put a more stringent constraint on the theory.

  11. The variation of the fine-structure constant from disformal couplings

    International Nuclear Information System (INIS)

    De Bruck, Carsten van; Mifsud, Jurgen; Nunes, Nelson J.

    2015-01-01

    We study a theory in which the electromagnetic field is disformally coupled to a scalar field, in addition to a usual non-minimal electromagnetic coupling. We show that disformal couplings modify the expression for the fine-structure constant, α. As a result, the theory we consider can explain the non-zero reported variation in the evolution of α by purely considering disformal couplings. We also find that if matter and photons are coupled in the same way to the scalar field, disformal couplings itself do not lead to a variation of the fine-structure constant. A number of scenarios are discussed consistent with the current astrophysical, geochemical, laboratory and the cosmic microwave background radiation constraints on the cosmological evolution of α. The models presented are also consistent with the current type Ia supernovae constraints on the effective dark energy equation of state. We find that the Oklo bound in particular puts strong constraints on the model parameters. From our numerical results, we find that the introduction of a non-minimal electromagnetic coupling enhances the cosmological variation in α. Better constrained data is expected to be reported by ALMA and with the forthcoming generation of high-resolution ultra-stable spectrographs such as PEPSI, ESPRESSO, and ELT-HIRES. Furthermore, an expected increase in the sensitivity of molecular and nuclear clocks will put a more stringent constraint on the theory

  12. Black Holes and Quantum Theory: The Fine Structure Constant Connection

    Directory of Open Access Journals (Sweden)

    Cahill R. T.

    2006-10-01

    Full Text Available The new dynamical theory of space is further confirmed by showing that the effective “black hole” masses M BH in 19 spherical star systems, from globular clusters to galaxies, with masses M , satisfy the prediction that M BH = α 2 M , where α is the fine structure constant. As well the necessary and unique generalisations of the Schr ̈ odinger and Dirac equations permit the first derivation of gravity from a deeper theory, showing that gravity is a quantum effect of quantum matter interacting with the dynamical space. As well the necessary generalisation of Maxwell’s equations displays the observed light bending effects. Finally it is shown from the generalised Dirac equation where the spacetime mathematical formalism, and the accompanying geodesic prescription for matter trajectories, comes from. The new theory of space is non-local and we see many parallels between this and quantum theory, in addition to the fine structure constant manifesting in both, so supporting the argument that space is a quantum foam system, as implied by the deeper information-theoretic theory known as Process Physics. The spatial dynamics also provides an explanation for the “dark matter” effect and as well the non-locality of the dynamics provides a mechanism for generating the uniformity of the universe, so explaining the cosmological horizon problem.

  13. Titanium dioxide fine structures by RF magnetron sputter method deposited on an electron-beam resist mask

    Science.gov (United States)

    Hashiba, Hideomi; Miyazaki, Yuta; Matsushita, Sachiko

    2013-09-01

    Titanium dioxide (TiO2) has been draw attention for wide range of applications from photonic crystals for visible light range by its catalytic characteristics to tera-hertz range by its high refractive index. We present an experimental study of fabrication of fine structures of TiO2 with a ZEP electron beam resist mask followed by Ti sputter deposition techniques. A TiO2 thin layer of 150 nm thick was grown on an FTO glass substrate with a fine patterned ZEP resist mask by a conventional RF magnetron sputter method with Ti target. The deposition was carried out with argon-oxygen gases at a pressure of 5.0 x 10 -1 Pa in a chamber. During the deposition, ratio of Ar-O2 gas was kept to the ratio of 2:1 and the deposition ratio was around 0.5 Å/s to ensure enough oxygen to form TiO2 and low temperature to avoid deformation of fine pattern of the ZPU resist mask. Deposited TiO2 layers are white-transparent, amorphous, and those roughnesses are around 7 nm. Fabricated TiO2 PCs have wider TiO2 slabs of 112 nm width leaving periodic 410 x 410 nm2 air gaps. We also studied transformation of TiO2 layers and TiO2 fine structures by baking at 500 °C. XRD measurement for TiO2 shows that the amorphous TiO2 transforms to rutile and anatase forms by the baking while keeping the same profile of the fine structures. Our fabrication method can be one of a promising technique to optic devices on researches and industrial area.

  14. Experimental investigation on improving the removal effect of WFGD system on fine particles by heterogeneous condensation

    Energy Technology Data Exchange (ETDEWEB)

    Bao, Jingjing; Yang, Linjun; Yan, Jinpei; Xiong, Guilong; Shen, Xianglin [Southeast Univ., Nanjing (China). School of Energy and Environment

    2013-07-01

    Heterogeneous condensation of water vapor as a preconditioning technique for the removal of fine particles from flue gas was investigated experimentally in a wet flue gas desulfurization (WFGD) system. A supersaturated vapor phase, necessary for condensational growth of fine particles, was achieved in the SO{sub 2} absorption zone and at the top of the wet FGD scrubber by adding steam in the gas inlet and above the scrubbing liquid inlet of the scrubber, respectively. The condensational grown droplets were then removed by the scrubbing liquid and a high-efficiency demister. The results show that the effectiveness of the WFGD system for removal of fine particles is related to the SO{sub 2} absorbent and the types of scrubber employed. Despite a little better effectiveness for the removal of fine particles in the rotating-stream-tray scrubber at the same liquid-to-gas ratio, The similar trends are obtained between the spray scrubber and rotating-stream-tray scrubber. Due to the formation of aerosol particles in the limestone and ammonia-based FGD processes, the fine particle removal efficiencies are lower than those for Na{sub 2}CO{sub 3} and water. The performance of the WFGD system for removal of fine particles can be significantly improved for both steam addition cases, for which the removal efficiency increases with increasing amount of added steam. A high liquid to gas ratio is beneficial for efficient removal of fine particles by heterogeneous condensation of water vapor.

  15. Photoionization modeling of the LWS fine-structure lines in IR bright galaxies

    Science.gov (United States)

    Satyapal, S.; Luhman, M. L.; Fischer, J.; Greenhouse, M. A.; Wolfire, M. G.

    1997-01-01

    The long wavelength spectrometer (LWS) fine structure line spectra from infrared luminous galaxies were modeled using stellar evolutionary synthesis models combined with photoionization and photodissociation region models. The calculations were carried out by using the computational code CLOUDY. Starburst and active galactic nuclei models are presented. The effects of dust in the ionized region are examined.

  16. Experimental determination of the relativistic fine structure splitting in a pionic atom

    International Nuclear Information System (INIS)

    Wang, K.-C.; Boehm, F.; Hahn, A.A.; Henrikson, H.E.; Miller, J.P.; Powers, R.J.; Vogel, P.; Vuilleumier, J.-L.; Kunselman, R.

    1978-01-01

    Using a high-resolution crystal spectrometer, the authors have measured the energy splitting of the pionic 5g-4f and 5f-4d transitions in Ti. The observed fine structure splitting agrees, within the experimental error of 3%, with the splitting arising from the calculated relativistic term and other small corrections for spinless particles. (Auth.)

  17. Renal fine structures detected by NMR imaging. First communication concerning an optimized technique

    Energy Technology Data Exchange (ETDEWEB)

    Zilch, H.G.

    1986-11-01

    A significantly improved image quality is achieved by the technique described, as compared to the magnetic resonance data obtained so far. The detailed analysis of the kidney goes as deep as into anatomic fine structures, and there is reason to hope for far better diagnostic details.

  18. Alpha-decay fine structure versus electromagnetic transitions

    International Nuclear Information System (INIS)

    Peltonen, S.

    2003-01-01

    Alpha decay of even-even Rn isotopes is studied microscopically along the lines of Phys. Rev. C 64, 302 (2001). The results are compared against experimental fine-structure hindrance factors (HFs). We consider problems related to reproducing observed HFs with nuclear models, especially in case of the collective 2 + - excitations. We use the QRPA model with isovector SDI interaction in order to systematically evaluate theoretical HFs. Pairing gaps and the experimental energy of the 2 + - state fix all interaction parameters except the ratio between the isovector and isoscalar interaction strengths that is used as an additional free parameter of the model. Correlation between the electromagnetic E2-strength and HFs is observed, depending both on the isotope and the excitation energy. The choice of the single particle basis appears to affect strongly the theoretical HFs. Further and even more systematical studies are required in order explain this behaviour. (author)

  19. Correlative Structural Biology: How to Investigate the Fine Details of Viral Structure

    Directory of Open Access Journals (Sweden)

    Elizabeth R. Wright

    2010-01-01

    Full Text Available Commentary on Byeon, I.J.; Meng, X.; Jung, J.; Zhao, G.; Yang, R.; Ahn, J.; Shi, J.; Concel, J.; Aiken, C.; Zhang, P.; Gronenborn, A.M. Structural convergence between Cryo-EM and NMR reveals intersubunit interactions critical for HIV-1 capsid function. Cell 2009, 139, 780-790.

  20. Short-range order structures of self-assembled Ge quantum dots probed by multiple-scattering extended x-ray absorption fine structure

    International Nuclear Information System (INIS)

    Sun Zhihu; Wei Shiqiang; Kolobov, A.V.; Oyanagi, H.; Brunner, K.

    2005-01-01

    Multiple-scattering extended x-ray absorption fine structure (MS-EXAFS) has been used to investigate the local structures around Ge atoms in self-assembled Ge-Si quantum dots (QDs) grown on Si(001) substrate. The MS effect of Ge QDs is dominated by the scattering path Ge 0 →B 1 →B 2 →Ge 0 (DS2), which contributes a signal destructively interfering with that of the second shell single-scattering path (SS2). MS-EXAFS analysis reveals that the degree of Ge-Si intermixing for Ge-Si QDs strongly depends on the temperature at which the silicon cap layer is overgrown. It is found that the interatomic distances (R Ge-Ge and R Ge-Si ) within the third nearest-neighbor shells in Ge-Si QDs indicate the compressively strained nature of QDs. The present study demonstrates that the MS-EXAFS provides detailed information on the QDs strain and the Ge-Si mixing beyond the nearest neighbors

  1. Fine structures of atomic excited states: precision atomic spectroscopy and electron-ion collision process

    International Nuclear Information System (INIS)

    Gao Xiang; Cheng Cheng; Li Jiaming

    2011-01-01

    Scientific research fields for future energies such as inertial confinement fusion researches and astrophysics studies especially with satellite observatories advance into stages of precision physics. The relevant atomic data are not only enormous but also of accuracy according to requirements, especially for both energy levels and the collision data. The fine structure of high excited states of atoms and ions can be measured by precision spectroscopy. Such precision measurements can provide not only knowledge about detailed dynamics of electron-ion interactions but also a bench mark examination of the accuracy of electron-ion collision data, especially incorporating theoretical computations. We illustrate that by using theoretical calculation methods which can treat the bound states and the adjacent continua on equal footing. The precision spectroscopic measurements of excited fine structures can be served as stringent tests of electron-ion collision data. (authors)

  2. Origin of fine structure of the giant dipole resonance in s d -shell nuclei

    Science.gov (United States)

    Fearick, R. W.; Erler, B.; Matsubara, H.; von Neumann-Cosel, P.; Richter, A.; Roth, R.; Tamii, A.

    2018-04-01

    A set of high-resolution zero-degree inelastic proton scattering data on 24Mg, 28Si, 32S, and 40Ca provides new insight into the long-standing puzzle of the origin of fragmentation of the giant dipole resonance (GDR) in s d -shell nuclei. Understanding is achieved by comparison with random phase approximation calculations for deformed nuclei using for the first time a realistic nucleon-nucleon interaction derived from the Argonne V18 potential with the unitary correlation operator method and supplemented by a phenomenological three-nucleon contact interaction. A wavelet analysis allows one to extract significant scales both in the data and calculations characterizing the fine structure of the GDR. The fair agreement for scales in the range of a few hundred keV supports the surmise that the fine structure arises from ground-state deformation driven by α clustering.

  3. Determination of 114Pd cumulative yield and investigation of the fine-structure at light peak in mass distribution of 252Cf spontaneous fission

    International Nuclear Information System (INIS)

    Yu Runlan; Li Xueliang; Cui Anzhi; Guo Jingru; Yan Shuhen; Tang Peijia; Liu Daming

    1991-07-01

    A rapid radiochemical procedure for Pd separation was developed. It was the first time to use radiochemical techniques to determine 114 Pd cumulative yield (2.50 ± 0.14)% in 252 Cf spontaneous fission. The cumulative yields of (3.50 ± 0.13)% and (3.70 ± 0.11)% for 112 Pd and 113g Ag were also obtained. These are in agreement with Skovorodkin's results. The cumulative yields determined show that there is a fine-structure at light peak of mass number A = 113 in the mass distribution of 252 Cf spontaneous fission

  4. Fine structure and spectral index measurements in natural uranium - graphite lattices; Mesures fines dans des reseaux a graphite

    Energy Technology Data Exchange (ETDEWEB)

    Cogne, F; Journet, J [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1964-07-01

    The experiments described in this report have been carried out for the most part in the critical facility MARIUS, and a few during the start up of the EDF-1 power reactor. The first part deals with the fine structure measurements made in various lattices and with their analysis. Integration over the neutron spectrum of the mono-kinetic disadvantage factor derived by the A.B.H method yields results in good agreement with the experiments. The second part deals with spectral indexes measurements (Pu/U, In/Mn) made at room temperature in MARIUS. Comparison are made of experiments with calculations using various thermalization models. Experiments carried out at higher temperatures in EDF-1 are also described. (authors) [French] Les mesures decrites dans ce rapport ont ete faites pour la plupart dans l'empilement critique MARIUS sur des reseaux a graphite-uranium naturel. Une premiere partie traite des mesures de structure fine faites dans differents reseaux et de leur interpretation. On montre en particulier qu'une integration sur le spectre d'un calcul monocinetique type A.B.H. rend bien compte des experiences. Dans une deuxieme partie, on donne les resultats de mesures d'indices de spectre Pu/U et In/Mn faites sur des reseaux froids a MARIUS et leur comparaison avec les differents modeles de calculs de thermalisation. On donne egalement les resultats de quelques mesures en temperature effectuees lors du demarrage du reacteur EDF-1. (auteurs)

  5. STM study on surface relief, ultra-fine structure and transformation mechanism of bainite in steels

    International Nuclear Information System (INIS)

    Fang, H.S.; Yang, Z.G.; Wang, J.J.; Zheng, Y.K.

    1995-01-01

    The surface reliefs accompanying lower bainite transformation in steels have been studied by scanning tunneling microscopy (STM). With the exclusive vertical resolution of STM, we observed that the surface relief associated with bainite is a group of surface reliefs related to subplates, subunits and sub-subunits. From the bainite plate to the sub-subunit in it, the reliefs are in a tent shape, not of invariant plane strain (IPS) type. The fine structure of bainite in a steel has also been shown by STM and TEM that bainite plate is composed of subplates, subunits and sub-subunits. On the basis of the fine structure inside a bainitic ferrite plate observed under STM, sympathetic-ledgewise mechanism of bainite formation is proposed. (orig.)

  6. Reduced fine-scale spatial genetic structure in grazed populations of Dianthus carthusianorum.

    Science.gov (United States)

    Rico, Y; Wagner, H H

    2016-11-01

    Strong spatial genetic structure in plant populations can increase homozygosity, reducing genetic diversity and adaptive potential. The strength of spatial genetic structure largely depends on rates of seed dispersal and pollen flow. Seeds without dispersal adaptations are likely to be dispersed over short distances within the vicinity of the mother plant, resulting in spatial clustering of related genotypes (fine-scale spatial genetic structure, hereafter spatial genetic structure (SGS)). However, primary seed dispersal by zoochory can promote effective dispersal, increasing the mixing of seeds and influencing SGS within plant populations. In this study, we investigated the effects of seed dispersal by rotational sheep grazing on the strength of SGS and genetic diversity using 11 nuclear microsatellites for 49 populations of the calcareous grassland forb Dianthus carthusianorum. Populations connected by rotational sheep grazing showed significantly weaker SGS and higher genetic diversity than populations in ungrazed grasslands. Independent of grazing treatment, small populations showed significantly stronger SGS and lower genetic diversity than larger populations, likely due to genetic drift. A lack of significant differences in the strength of SGS and genetic diversity between populations that were recently colonized and pre-existing populations suggested that populations colonized after the reintroduction of rotational sheep grazing were likely founded by colonists from diverse source populations. We conclude that dispersal by rotational sheep grazing has the potential to considerably reduce SGS within D. carthusianorum populations. Our study highlights the effectiveness of landscape management by rotational sheep grazing to importantly reduce genetic structure at local scales within restored plant populations.

  7. Extended x-ray absorption fine structure (EXAFS): a novel probe for local structure of glassy solids

    International Nuclear Information System (INIS)

    Wong, J.

    1979-01-01

    The extended x-ray absorption fine structure (EXAFS) is the oscillation in the absorption coefficient extending a few hundred eVs on the high energy side of an x-ray absorption edge. This mode of spectroscopy has recently been realized to be a powerful tool in probing the local atomic structure of all states of matter, particularly with the advent of intense synchrotron radiation. More importantly is the unique ability of EXAFS to probe the structure and dynamics around individual atomic species in a multi-atomic system. In this paper, the physical processes associated with the EXAFS phenomenon will be discussed. Experimental results obtained at the Stanford Synchrotron Radiation Laboratory on some oxide and metallic glasses will be presented. The local structure in these materials are elucidated using a Fourier transform technique

  8. Fine structure and function of the alimentary epithelium in Artemia salina nauplii

    Energy Technology Data Exchange (ETDEWEB)

    Hootman, S R; Conte, F P

    1974-01-01

    The fine structure of the alimentary tract in the second instar nauplius of the brine shrimp, Artemia salina, has been described. The foregut and hindgut of the larva are composed of cuboidal epithelium which is cuticularized. The epithelium of the midgut and gastric caeca is columnar and is characterized by apical microvilli, basal membrane infolds, and abundant mitochondria. The structural characteristics of the midgut cells correlate with previous physiological and biochemical evidence on both adult and larval brine shrimp which indicates that the midgut plays an important role in absorption and osmoregulation in these animals.

  9. QUIESCENT PROMINENCES IN THE ERA OF ALMA: SIMULATED OBSERVATIONS USING THE 3D WHOLE-PROMINENCE FINE STRUCTURE MODEL

    Energy Technology Data Exchange (ETDEWEB)

    Gunár, Stanislav; Heinzel, Petr [Astronomical Institute, The Czech Academy of Sciences, 25165 Ondřejov (Czech Republic); Mackay, Duncan H. [School of Mathematics and Statistics, University of St Andrews, North Haugh, St Andrews KY16 9SS (United Kingdom); Anzer, Ulrich [Max-Planck-Institut für Astrophysik, Karl-Schwarzschild-Str. 1, D-85740 Garching bei München (Germany)

    2016-12-20

    We use the detailed 3D whole-prominence fine structure model to produce the first simulated high-resolution ALMA observations of a modeled quiescent solar prominence. The maps of synthetic brightness temperature and optical thickness shown in the present paper are produced using a visualization method for synthesis of the submillimeter/millimeter radio continua. We have obtained the simulated observations of both the prominence at the limb and the filament on the disk at wavelengths covering a broad range that encompasses the full potential of ALMA. We demonstrate here extent to which the small-scale and large-scale prominence and filament structures will be visible in the ALMA observations spanning both the optically thin and thick regimes. We analyze the relationship between the brightness and kinetic temperature of the prominence plasma. We also illustrate the opportunities ALMA will provide for studying the thermal structure of the prominence plasma from the cores of the cool prominence fine structure to the prominence–corona transition region. In addition, we show that detailed 3D modeling of entire prominences with their numerous fine structures will be important for the correct interpretation of future ALMA observations of prominences.

  10. Solution spectroelectrochemical cell for in situ X-ray absorption fine structure

    International Nuclear Information System (INIS)

    Antonio, M.R.; Soderholm, L.

    1995-01-01

    A purpose-built spectroelectrochemical cell for in situ fluorescence XAFS (X-ray Absorption Fine Structure) measurements of bulk solution species during constant-potential electrolysis is described. The cell performance was demonstrated by the collection of europium L 3 -edge XANES (X-ray Absorption Near Edge Structure) throughout the course of electrolysis of an aqueous solution of EuCl 3 ·6H 2 O in 1 M H 2 SO 4 . The europium L 3 -edge resonances reported here for the Eu III and Eu II ions demonstrate that their 2p 3/2 → 5d electronic transition probabilities are not the same

  11. Detection of Propagating Fast Sausage Waves through Detailed Analysis of a Zebra-pattern Fine Structure in a Solar Radio Burst

    Science.gov (United States)

    Kaneda, K.; Misawa, H.; Iwai, K.; Masuda, S.; Tsuchiya, F.; Katoh, Y.; Obara, T.

    2018-03-01

    Various magnetohydrodynamic (MHD) waves have recently been detected in the solar corona and investigated intensively in the context of coronal heating and coronal seismology. In this Letter, we report the first detection of short-period propagating fast sausage mode waves in a metric radio spectral fine structure observed with the Assembly of Metric-band Aperture Telescope and Real-time Analysis System. Analysis of Zebra patterns (ZPs) in a type-IV burst revealed a quasi-periodic modulation in the frequency separation between the adjacent stripes of the ZPs (Δf ). The observed quasi-periodic modulation had a period of 1–2 s and exhibited a characteristic negative frequency drift with a rate of 3–8 MHz s‑1. Based on the double plasma resonance model, the most accepted generation model of ZPs, the observed quasi-periodic modulation of the ZP can be interpreted in terms of fast sausage mode waves propagating upward at phase speeds of 3000–8000 km s‑1. These results provide us with new insights for probing the fine structure of coronal loops.

  12. Lack of sex-biased dispersal promotes fine-scale genetic structure in alpine ungulates

    Science.gov (United States)

    Roffler, Gretchen H.; Talbot, Sandra L.; Luikart, Gordon; Sage, George K.; Pilgrim, Kristy L.; Adams, Layne G.; Schwartz, Michael K.

    2014-01-01

    Identifying patterns of fine-scale genetic structure in natural populations can advance understanding of critical ecological processes such as dispersal and gene flow across heterogeneous landscapes. Alpine ungulates generally exhibit high levels of genetic structure due to female philopatry and patchy configuration of mountain habitats. We assessed the spatial scale of genetic structure and the amount of gene flow in 301 Dall’s sheep (Ovis dalli dalli) at the landscape level using 15 nuclear microsatellites and 473 base pairs of the mitochondrial (mtDNA) control region. Dall’s sheep exhibited significant genetic structure within contiguous mountain ranges, but mtDNA structure occurred at a broader geographic scale than nuclear DNA within the study area, and mtDNA structure for other North American mountain sheep populations. No evidence of male-mediated gene flow or greater philopatry of females was observed; there was little difference between markers with different modes of inheritance (pairwise nuclear DNA F ST = 0.004–0.325; mtDNA F ST = 0.009–0.544), and males were no more likely than females to be recent immigrants. Historical patterns based on mtDNA indicate separate northern and southern lineages and a pattern of expansion following regional glacial retreat. Boundaries of genetic clusters aligned geographically with prominent mountain ranges, icefields, and major river valleys based on Bayesian and hierarchical modeling of microsatellite and mtDNA data. Our results suggest that fine-scale genetic structure in Dall’s sheep is influenced by limited dispersal, and structure may be weaker in populations occurring near ancestral levels of density and distribution in continuous habitats compared to other alpine ungulates that have experienced declines and marked habitat fragmentation.

  13. Fine structure of V2+ energy levels in CsCaF3:V2+

    International Nuclear Information System (INIS)

    Avram, C.N.; Brik, M.G.

    2004-01-01

    Theoretical investigations of the fine structure of the lasing 4 T 2g level in a CsCaF 3 :V 2+ crystal were carried out. The spin-orbit splitting of the 4 T 2g term in the static low crystal field was obtained from the Eisenstein matrices and using parameters (Dq, B, C, ζ SO ) appropriate for the 4 T 2g - 4 A 2g zero-phonon line. The 4 T 2g spinor splitting has been modeled by the second-order spin-orbit Hamiltonian. The effect of the dynamical Jahn-Teller interaction on the spin-orbit splitting of the 4 T 2g term was taken into account; the Jahn-Teller stabilization energy, ZPL splitting and the Huang-Rhys parameter for the e g normal mode were all evaluated

  14. Fine structure of the stimulated Raman spectrum in compressed hydrogen. The relaxation-oscillation mode of backscattered Stokes emission

    International Nuclear Information System (INIS)

    Bespalov, V.G.; Efimov, Yu.N.; Staselko, D.I.

    1992-01-01

    This paper studies the emission spectra of backscattered stimulated Raman scattering (SRS) in compressed hydrogen in the relaxation-oscillation mode and the compression SRS mode for the minimum width of the spontaneous scattering spectrum (in the region of the Dicke dip). It is shown that the generation of a train of Stokes-emission subpulses results in the appearance of fine structure in the backscattered SRS spectrum. The influence of the temporal structure of reflected Stokes pulses on this spectrum and on the appearance of fine structure in it is analyzed. The conditions for generating spectrally limited (without phase modulation), extremely coherent Stokes pulses are explained. 18 refs., 3 figs

  15. Atlas of fine structures of dynamic spectra of solar type IV-dm and some type II radio bursts

    International Nuclear Information System (INIS)

    Slottje, C.

    1982-01-01

    The author presents an atlas of spectral fine structures of solar radio bursts of types IV and II around 1 m wavelength, as obtained with a multichannel spectrograph at Dwingeloo. The structures form largely a collection of observations of these events during late 1968 through 1974, thus covering almost entirely the declining branch of solar cycle 20. The spectrograph has an extra enhanced contrast output with properties quite different from those of the commonly used swept frequency spectrographs. The corresponding instrumental characteristics and effects are discussed. A classification of fine structures and an analysis of their statistical properties and of those of the pertinent radio events are also given. (Auth.)

  16. Fine-scale crustal structure of the Azores Islands from teleseismic receiver functions

    Science.gov (United States)

    Spieker, K.; Rondenay, S.; Ramalho, R. S.; Thomas, C.; Helffrich, G. R.

    2016-12-01

    The Azores plateau is located near the Mid-Atlantic Ridge (MAR) and consists of nine islands, most of which lie east of the MAR. Various methods including seismic reflection, gravity, and passive seismic imaging have been used to investigate the crustal thickness beneath the islands. They have yielded thickness estimates that range between roughly 10 km and 30 km, but until now models of the fine-scale crustal structure have been lacking. A comparison of the crustal structure beneath the islands that lie west and east of the MAR might give further constraints on the evolution of the islands. For example, geochemical studies carried out across the region predict the existence of volcanic interfaces that should be detected seismically within the shallow crust of some of the islands. In this study, we use data from ten seismic stations located on the Azores Islands to investigate the crustal structure with teleseismic P-wave receiver functions. We query our resulting receiver functions for signals associated with the volcanic edifice, the crust-mantle boundary, and potential underplated layers beneath the various islands. The islands west of the MAR have a crustal structure comprising two discontinuities - an upper one at 1-2 km depth marking the base of the volcanic edifice, and a lower one at 10 km depth that we interpret as crust-mantle boundary. The islands east of the MAR can be subdivided into two groups. The central islands that are closer to the MAR exhibit a crustal structure similar to that of the western islands, with a volcanic edifice reaching a depth of 2 km and an average crust-mantle boundary at around 12 km depth. The easternmost islands, located on the oldest lithosphere, exhibit a more complex crustal structure with evidence for a mid-crustal interface and an underplated layer, yielding an effective crust-mantle boundary at >15 km depth. The difference in structure between proximal and distal islands might be related to the age of the plate at the

  17. Fine structure and optical properties of biological polarizers in crustaceans and cephalopods

    Science.gov (United States)

    Chiou, Tsyr-Huei; Caldwell, Roy L.; Hanlon, Roger T.; Cronin, Thomas W.

    2008-04-01

    The lighting of the underwater environment is constantly changing due to attenuation by water, scattering by suspended particles, as well as the refraction and reflection caused by the surface waves. These factors pose a great challenge for marine animals which communicate through visual signals, especially those based on color. To escape this problem, certain cephalopod mollusks and stomatopod crustaceans utilize the polarization properties of light. While the mechanisms behind the polarization vision of these two animal groups are similar, several distinctive types of polarizers (i.e. the structure producing the signal) have been found in these animals. To gain a better knowledge of how these polarizers function, we studied the relationships between fine structures and optical properties of four types of polarizers found in cephalopods and stomatopods. Although all the polarizers share a somewhat similar spectral range, around 450- 550 nm, the reflectance properties of the signals and the mechanisms used to produce them have dramatic differences. In cephalopods, stack-plates polarizers produce the polarization patterns found on the arms and around their eyes. In stomatopods, we have found one type of beam-splitting polarizer based on photonic structures and two absorptive polarizer types based on dichroic molecules. These stomatopod polarizers may be found on various appendages, and on the cuticle covering dorsal or lateral sides of the animal. Since the efficiencies of all these polarizer types are somewhat sensitive to the change of illumination and viewing angle, how these animals compensate with different behaviors or fine structural features of the polarizer also varies.

  18. Sample-angle feedback for diffraction anomalous fine-structure spectroscopy

    International Nuclear Information System (INIS)

    Cross, J.O.; Elam, W.T.; Harris, V.G.; Kirkland, J.P.; Bouldin, C.E.; Sorensen, L.B.

    1998-01-01

    Diffraction anomalous fine-structure (DAFS) experiments measure Bragg peak intensities as continuous functions of photon energy near a core-level excitation. Measuring the integrated intensity at each energy makes the experiments prohibitively slow; however, in many cases DAFS can be collected quickly by measuring only the peak intensity at the center of the rocking curve. A piezoelectric-actuator-driven stage has been designed and tested as part of a sample-angle feedback circuit for locking onto the maximum of the rocking curve while the energy is scanned. Although software peak-tracking requires only a simple calculation of diffractometer angles, it is found that the additional hardware feedback dramatically improves the reproducibility of the data

  19. Ultra-Fine Scale Spatially-Integrated Mapping of Habitat and Occupancy Using Structure-From-Motion.

    Directory of Open Access Journals (Sweden)

    Philip McDowall

    Full Text Available Organisms respond to and often simultaneously modify their environment. While these interactions are apparent at the landscape extent, the driving mechanisms often occur at very fine spatial scales. Structure-from-Motion (SfM, a computer vision technique, allows the simultaneous mapping of organisms and fine scale habitat, and will greatly improve our understanding of habitat suitability, ecophysiology, and the bi-directional relationship between geomorphology and habitat use. SfM can be used to create high-resolution (centimeter-scale three-dimensional (3D habitat models at low cost. These models can capture the abiotic conditions formed by terrain and simultaneously record the position of individual organisms within that terrain. While coloniality is common in seabird species, we have a poor understanding of the extent to which dense breeding aggregations are driven by fine-scale active aggregation or limited suitable habitat. We demonstrate the use of SfM for fine-scale habitat suitability by reconstructing the locations of nests in a gentoo penguin colony and fitting models that explicitly account for conspecific attraction. The resulting digital elevation models (DEMs are used as covariates in an inhomogeneous hybrid point process model. We find that gentoo penguin nest site selection is a function of the topography of the landscape, but that nests are far more aggregated than would be expected based on terrain alone, suggesting a strong role of behavioral aggregation in driving coloniality in this species. This integrated mapping of organisms and fine scale habitat will greatly improve our understanding of fine-scale habitat suitability, ecophysiology, and the complex bi-directional relationship between geomorphology and habitat use.

  20. Fine-structured aluminium products with controllable texture by selective laser melting of pre-alloyed AlSi10Mg powder

    International Nuclear Information System (INIS)

    Thijs, Lore; Kempen, Karolien; Kruth, Jean-Pierre; Van Humbeeck, Jan

    2013-01-01

    Graphical abstract: -- Abstract: This study shows that AlSi10Mg parts with an extremely fine microstructure and a controllable texture can be obtained through selective laser melting (SLM). Selective laser melting creates complex functional products by selectively melting powder particles of a powder bed layer after layer using a high-energy laser beam. The high-energy density applied to the material and the additive character of the process result in a unique material structure. To investigate this material structure, cube-shaped SLM parts were made using different scanning strategies and investigated by microscopy, X-ray diffraction and electron backscattered diffraction. The experimental results show that the high thermal gradients occurring during SLM lead to a very fine microstructure with submicron-sized cells. Consequently, the AlSi10Mg SLM products have a high hardness of 127 ± 3 Hv0.5 even without the application of a precipitation hardening treatment. Furthermore, due to the unique solidification conditions and the additive character of the process, a morphological and crystallographic texture is present in the SLM parts. Thanks to the knowledge gathered in this paper on how this texture is formed and how it depends on the process parameters, this texture can be controlled. A strong fibrous 〈1 0 0〉 texture can be altered into a weak cube texture along the building and scanning directions when a rotation of 90° of the scanning vectors within or between the layers is applied

  1. Clonal diversity and fine-scale genetic structure in a high andean treeline population

    Czech Academy of Sciences Publication Activity Database

    Peng, Y.; Macek, P.; Macková, Jana; Romoleroux, K.; Hensen, I.

    2015-01-01

    Roč. 47, č. 1 (2015), s. 59-65 ISSN 0006-3606 Grant - others:GA AV ČR(CZ) IAA601110702; GA MŠk(CZ) LM2010009 Program:IA Institutional support: RVO:60077344 Keywords : AFLP * clonal diversity * clonal propagation * fine-scale genetic structure * Polylepis reticulata * treeline Subject RIV: EB - Genetics ; Molecular Biology Impact factor: 1.944, year: 2015

  2. Fine structure of the CCl3 UV absorption spectrum and CCl3 kinetics

    DEFF Research Database (Denmark)

    Ellermann, T.

    1992-01-01

    The UV gas-phase spectrum of CCl3 was recorded in the range 220-300 nm using pulse radiolysis of CHCl3/SF6 or CCl4/Ar gas mixtures. The UV spectrum exhibits a pronounced vibrational fine structure which is assigned to transition into the (C2A1'(3s)) Rydberg state. The vibronic progression has...

  3. Evolution of the fine-structure constant in runaway dilaton models

    Energy Technology Data Exchange (ETDEWEB)

    Martins, C.J.A.P., E-mail: Carlos.Martins@astro.up.pt [Centro de Astrofísica, Universidade do Porto, Rua das Estrelas, 4150-762 Porto (Portugal); Instituto de Astrofísica e Ciências do Espaço, CAUP, Rua das Estrelas, 4150-762 Porto (Portugal); Vielzeuf, P.E., E-mail: pvielzeuf@ifae.es [Institut de Física d' Altes Energies, Universitat Autònoma de Barcelona, E-08193 Bellaterra (Barcelona) (Spain); Martinelli, M., E-mail: martinelli@thphys.uni-heidelberg.de [Institute for Theoretical Physics, University of Heidelberg, Philosophenweg 16, 69120, Heidelberg (Germany); Calabrese, E., E-mail: erminia.calabrese@astro.ox.ac.uk [Sub-department of Astrophysics, University of Oxford, Keble Road, Oxford OX1 3RH (United Kingdom); Pandolfi, S., E-mail: stefania@dark-cosmology.dk [Dark Cosmology Centre, Niels Bohr Institute, University of Copenhagen, Juliane Maries Vej 30, DK-2100 Copenhagen (Denmark)

    2015-04-09

    We study the detailed evolution of the fine-structure constant α in the string-inspired runaway dilaton class of models of Damour, Piazza and Veneziano. We provide constraints on this scenario using the most recent α measurements and discuss ways to distinguish it from alternative models for varying α. For model parameters which saturate bounds from current observations, the redshift drift signal can differ considerably from that of the canonical ΛCDM paradigm at high redshifts. Measurements of this signal by the forthcoming European Extremely Large Telescope (E-ELT), together with more sensitive α measurements, will thus dramatically constrain these scenarios.

  4. Evolution of the fine-structure constant in runaway dilaton models

    International Nuclear Information System (INIS)

    Martins, C.J.A.P.; Vielzeuf, P.E.; Martinelli, M.; Calabrese, E.; Pandolfi, S.

    2015-01-01

    We study the detailed evolution of the fine-structure constant α in the string-inspired runaway dilaton class of models of Damour, Piazza and Veneziano. We provide constraints on this scenario using the most recent α measurements and discuss ways to distinguish it from alternative models for varying α. For model parameters which saturate bounds from current observations, the redshift drift signal can differ considerably from that of the canonical ΛCDM paradigm at high redshifts. Measurements of this signal by the forthcoming European Extremely Large Telescope (E-ELT), together with more sensitive α measurements, will thus dramatically constrain these scenarios

  5. Distortion product otoacoustic emission fine structure of symphony orchestra musicians

    DEFF Research Database (Denmark)

    Reuter, Karen; Hammershøi, Dorte

    2006-01-01

    Otoacoustic emissions (OAE) are sounds produced by the healthy inner ear. They can be measured as low-level signals in the ear canal and are used to monitor the functioning of outer hair cells.Several studies indicate that OAE might be a more sensitive measure to detect early noise-induced hearing...... losses than puretone audiometry. The distortion product otoacoustic emission (DPOAE) fine structure is obtained when the ear is stimulated by dual tone stimuli using a high frequency resolution. It is characterized by quasi-periodic variations across frequency, as it can be observed in the hearing...

  6. Atomistic theory of excitonic fine structure in InAs/InP nanowire quantum dot molecules

    Science.gov (United States)

    Świderski, M.; Zieliński, M.

    2017-03-01

    Nanowire quantum dots have peculiar electronic and optical properties. In this work we use atomistic tight binding to study excitonic spectra of artificial molecules formed by a double nanowire quantum dot. We demonstrate a key role of atomistic symmetry and nanowire substrate orientation rather than cylindrical shape symmetry of a nanowire and a molecule. In particular for [001 ] nanowire orientation we observe a nonvanishing bright exciton splitting for a quasimolecule formed by two cylindrical quantum dots of different heights. This effect is due to interdot coupling that effectively reduces the overall symmetry, whereas single uncoupled [001 ] quantum dots have zero fine structure splitting. We found that the same double quantum dot system grown on [111 ] nanowire reveals no excitonic fine structure for all considered quantum dot distances and individual quantum dot heights. Further we demonstrate a pronounced, by several orders of magnitude, increase of the dark exciton optical activity in a quantum dot molecule as compared to a single quantum dot. For [111 ] systems we also show spontaneous localization of single particle states in one of nominally identical quantum dots forming a molecule, which is mediated by strain and origins from the lack of the vertical inversion symmetry in [111 ] nanostructures of overall C3 v symmetry. Finally, we study lowering of symmetry due to alloy randomness that triggers nonzero excitonic fine structure and the dark exciton optical activity in realistic nanowire quantum dot molecules of intermixed composition.

  7. `Fingerprint' Fine Structure in the Solar Decametric Radio Spectrum Solar Physics

    Science.gov (United States)

    Zlotnik, E. Y.; Zaitsev, V. V.; Melnik, V. N.; Konovalenko, A. A.; Dorovskyy, V. V.

    2015-07-01

    We study a unique fine structure in the dynamic spectrum of the solar radio emission discovered by the UTR-2 radio telescope (Kharkiv, Ukraine) in the frequency band of 20 - 30 MHz. The structure was observed against the background of a broadband type IV radio burst and consisted of parallel drifting narrow bands of enhanced emission and absorption on the background emission. The observed structure differs from the widely known zebra pattern at meter and decimeter wavelengths by the opposite directions of the frequency drift within a single stripe at a given time. We show that the observed properties can be understood in the framework of the radiation mechanism by virtue of the double plasma resonance effect in a nonuniform coronal magnetic trap. We propose a source model providing the observed frequency drift of the stripes.

  8. Band-Edge Exciton Fine Structure and Recombination Dynamics in InP/ZnS Colloidal Nanocrystals.

    Science.gov (United States)

    Biadala, Louis; Siebers, Benjamin; Beyazit, Yasin; Tessier, Mickaël D; Dupont, Dorian; Hens, Zeger; Yakovlev, Dmitri R; Bayer, Manfred

    2016-03-22

    We report on a temperature-, time-, and spectrally resolved study of the photoluminescence of type-I InP/ZnS colloidal nanocrystals with varying core size. By studying the exciton recombination dynamics we assess the exciton fine structure in these systems. In addition to the typical bright-dark doublet, the photoluminescence stems from an upper bright state in spite of its large energy splitting (∼100 meV). This striking observation results from dramatically lengthened thermalization processes among the fine structure levels and points to optical-phonon bottleneck effects in InP/ZnS nanocrystals. Furthermore, our data show that the radiative recombination of the dark exciton scales linearly with the bright-dark energy splitting for CdSe and InP nanocrystals. This finding strongly suggests a universal dangling bonds-assisted recombination of the dark exciton in colloidal nanostructures.

  9. Behavior of heptavalent technetium in concentrated triflic acid under alpha-irradiation. Technetium-triflate complex characterized by X-ray absorption fine structure spectroscopy and DFT

    Energy Technology Data Exchange (ETDEWEB)

    Denden, Ibtihel; Blain, Guillaume; Fattahi, Massoud [SUBATECH Laboratory, Nantes (France); Roques, Jerome [Paris Sud Univ., Orsay (France). IPN Orsay; Poineau, Frederic [Nevada Univ., Las Vegas, NV (United States). Dept. of Chemistry and Biochemistry; Solari, Pier Lorenzo [CEA, Gif-sur-Yvette (France). DEN/DPC/SEARS; Schlegel, Michel L. [Synchrotron SOLEIL, Gif-sur-Yvette (France)

    2017-04-01

    The nature of the Tc species produced after the alpha-irradiation of Tc(VII) in concentrated triflic acid has been investigated by X-ray absorption fine structure (XAFS) spectroscopy and first principles calculations. Experimental and theoretical results are consistent with the formation of Tc{sup (V)}O(F{sub 3}CSO{sub 3}){sub 2}(H{sub 2}O){sub 2}{sup +}.

  10. Near-edge X-ray absorption fine structure studies of Cr{sub 1−x}M{sub x}N coatings

    Energy Technology Data Exchange (ETDEWEB)

    Mahbubur Rahman, M. [School of Engineering and Information Technology, Murdoch University, Murdoch, WA 6150 (Australia); Department of Physics, Jahangirnagar University, Savar, Dhaka 1342 (Bangladesh); Duan, Alex [School of Chemistry, The University of Melbourne, Parkville, VIC 3010 (Australia); Jiang, Zhong-Tao, E-mail: Z.Jiang@murdoch.edu.au [School of Engineering and Information Technology, Murdoch University, Murdoch, WA 6150 (Australia); Xie, Zonghan [School of Mechanical Engineering, University of Adelaide, SA 5005 (Australia); School of Engineering, Edith Cowan University, WA 6027 (Australia); Wu, Alex [School of Chemistry, The University of Melbourne, Parkville, VIC 3010 (Australia); Amri, Amun [Department of Chemical Engineering, Riau University, Pekanbaru (Indonesia); Cowie, Bruce [Australian Synchrotron, 800 Blackburn Rd., Clayton, VIC 3168 (Australia); Yin, Chun-Yang [Chemical and Analytical Sciences, Murdoch University, Murdoch, WA 6150 (Australia)

    2013-11-25

    Highlights: •Al or Si is doped on CrN and AlN coatings using magnetron sputtering system. •NEXAFS analysis is conducted to measure the Al and Si K-edges, and chromium L-edge. •Structural evolution of CrN matrix with addition of Al or Si element is investigated. -- Abstract: Cr{sub 1−x}M{sub x}N coatings, with doping concentrations (Si or Al) varying from 14.3 to 28.5 at.%, were prepared on AISI M2 tool steel substrates using a TEER UDP 650/4 closed field unbalanced magnetron sputtering system. Near-edge X-ray absorption fine structure (NEXAFS) characterization was carried out to measure the aluminum and silicon K-edges, as well as chromium L-edge, in the coatings. Two soft X-ray techniques, Auger electron yield (AEY) and total fluorescence yield (TFY), were employed to investigate the surface and inner structural properties of the materials in order to understand the structural evolution of CrN matrix with addition of Al (or Si) elements. Investigations on the local bonding states and grain boundaries of the coatings, using NEXAFS technique, provide significant information which facilitates understanding of the local electronic structure of the atoms and shed light on the origins of the high mechanical strength and oxidation resistance of these technologically important coatings.

  11. Fine structure of the isoscalar giant quadrupole resonance from high-resolution inelastic proton scattering experiments

    International Nuclear Information System (INIS)

    Shevchenko, A.

    2005-02-01

    In the present work the phenomenon of fine structure in the region of the isoscalar giant quadrupole resonance in a number of heavy and medium-heavy nuclei is systematically investigated for the first time. High energy-resolution inelastic proton scattering experiments were carried out in September-October 2001 and in October 2003 at the iThemba LABS cyclotron facility in South Africa with an incident proton energy of 200 MeV. The obtained data with the energy resolution of triangle E 58 Ni, 89 Y, 90 Zr, 120 Sn, 142 Nd, 166 Er, 208 Pb), thereby establishing the global character of this phenomenon. Fine structure can be described using characteristic energy scales, appearing as a result of the decay of collective modes towards the compound nucleus through a hierarchy of couplings to complex degrees of freedom. For the extraction of the characteristic energy scales from the spectra an entropy index method and a novel technique based on the wavelet analysis are utilized. The global analysis of available data shows the presence of three groups of scales, according to their values. To the first group belong the scales with the values around and below 100 keV, which were detected in all the nuclei studied. The second group contains intermediate scales in the range of 100 keV to 1 MeV. These scales show large variations depending on the nuclear structure of the nucleus. The largest scales above 1 MeV are classified to the third group, describing the global structure of the resonance (the width). The interpretation of the observed scales is realized via the comparison with microscopic model calculations including the coupling of the initial one-particle-one-hole excitations to more complex configurations. A qualitative agreement of the experimentally observed scales with those obtained from the theoretical predictions supports the suggestion of the origin of fine structure from the coupling to the two-particle-two-hole states. However, quantitatively, large deviations are

  12. Portable ultrahigh-vacuum sample storage system for polarization-dependent total-reflection fluorescence x-ray absorption fine structure spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Watanabe, Yoshihide, E-mail: e0827@mosk.tytlabs.co.jp; Nishimura, Yusaku F.; Suzuki, Ryo; Beniya, Atsushi; Isomura, Noritake [Toyota Central R& D Labs., Inc., Yokomichi 41-1, Nagakute, Aichi 480-1192 (Japan); Uehara, Hiromitsu; Asakura, Kiyotaka; Takakusagi, Satoru [Catalysis Research Center, Hokkaido University, Kita 21-10, Sapporo, Hokkaido 001-0021 (Japan); Nimura, Tomoyuki [AVC Co., Ltd., Inada 1450-6, Hitachinaka, Ibaraki 312-0061 (Japan)

    2016-03-15

    A portable ultrahigh-vacuum sample storage system was designed and built to investigate the detailed geometric structures of mass-selected metal clusters on oxide substrates by polarization-dependent total-reflection fluorescence x-ray absorption fine structure spectroscopy (PTRF-XAFS). This ultrahigh-vacuum (UHV) sample storage system provides the handover of samples between two different sample manipulating systems. The sample storage system is adaptable for public transportation, facilitating experiments using air-sensitive samples in synchrotron radiation or other quantum beam facilities. The samples were transferred by the developed portable UHV transfer system via a public transportation at a distance over 400 km. The performance of the transfer system was demonstrated by a successful PTRF-XAFS study of Pt{sub 4} clusters deposited on a TiO{sub 2}(110) surface.

  13. Investigations on the effects of polychlorinated biphenyls on the function and structure of the thyroid gland of adult and perinatal rats

    International Nuclear Information System (INIS)

    Collins, W.T. Jr.

    1979-01-01

    Recent evidence indicates that PCB may cause alterations in thyroid structure and thyroxine metabolism. The administration of PCB to rats results in an enlargement of the thyroid gland, lowered serum thyroxine concentration, and increased conjugation and excretion of thyroxine-glucuronide in the bile. These findings suggest that some of the metabolic alterations produced by intoxication with PCB may be related to alterations in thyroid structure and function. Therefore, the objectives of this investigation were: (a) to evaluate the acute, subchronic and delayed effects of PCB on the structure and function of the thyroid gland in adult Osborne-Mendel rats; (b) to compare the changes produced by PCB with those produced by iodide excess and deficiency, and thyrotropin and thyroxine administration; (c) to investigate the fine structural changes and hormonal alterations in thyroid glands of perinatal rats exposed in utero and by the milk to PCB; and (d) to determine the alterations in the biliary excretion of 125 I-thyroxine and fine structural changes in thyroid glands of the glucuronyltransferase deficient homozygous Gunn rat exposed to PCB

  14. Evidence from n=2 fine structure transitions for the production of fast excited state positronium

    International Nuclear Information System (INIS)

    Ley, R.; Niebling, K.D.; Schwarz, R.; Werth, G.

    1990-01-01

    Fine structure transitions in the first excited state of positronium (Ps) have been measured using 'Backscatter Ps' production on a Mo surface by observation of a change in the emitted Lyman-α intensity under resonant microwave irradiation. Production, fine structure transitions and Lyman-α decay of the Ps atoms took place inside a waveguide designed to transmit the microwave frequencies of 8.6, 13.0 and 18.5 GHz for the transitions from the 2 3 S 1 state to the 2 3 P J , J=2, 1, 0, states, respectively. In the presence of a magnetic field, all transitions observed show a shift to higher frequencies, compared with earlier calculations and measurements in zero magnetic field. The deviations exceed the expected Zeeman shift significantly but may be explained by assuming a motional Stark effect for Ps with kinetic energies of several eV. (author)

  15. Diffraction anomalous fine-structure study of strained Ga1-xInxAs on GaAs(001)

    International Nuclear Information System (INIS)

    Woicik, J.C.; Cross, J.O.; Bouldin, C.E.; Ravel, B.; Pellegrino, J.G.; Steiner, B.; Bompadre, S.G.; Sorensen, L.B.; Miyano, K.E.; Kirkland, J.P.

    1998-01-01

    Diffraction anomalous fine-structure measurements performed at both the Ga and As K edges have determined the Ga-As bond length to be 2.442±0.005thinsp Angstrom in a buried, 213-Angstrom-thick Ga 0.785 In 0.215 As layer grown coherently on GaAs(001). This bond length corresponds to a strain-induced contraction of 0.013±0.005thinsp Angstrom relative to the Ga-As bond length in bulk Ga 1-x In x As of the same composition. Together with recent extended x-ray-absorption fine-structure measurements performed at the In K edge [Woicik et al., Phys. Rev. Lett. 79, 5026 (1997)], excellent agreement is found with the uniform bond-length distortion model for strained-layer semiconductors on (001) substrates. copyright 1998 The American Physical Society

  16. Production of fine structures in type III solar radio bursts due to turbulent density profiles

    International Nuclear Information System (INIS)

    Loi, Shyeh Tjing; Cairns, Iver H.; Li, Bo

    2014-01-01

    Magnetic reconnection events in the corona release energetic electron beams along open field lines, and the beams generate radio emission at multiples of the electron plasma frequency f p to produce type III solar radio bursts. Type III bursts often exhibit irregularities in the form of flux modulations with frequency and/or local temporal advances and delays, and a type IIIb burst represents the extreme case where a type III burst is fragmented into a chain of narrowband features called striae. Remote and in situ spacecraft measurements have shown that density turbulence is ubiquitous in the corona and solar wind, and often exhibits a Kolmogorov power spectrum. In this work, we numerically investigate the effects of one-dimensional macroscopic density turbulence (along the beam direction) on the behavior of type III bursts, and find that this turbulence produces stria-like fine structures in the dynamic spectra of both f p and 2 f p radiation. Spectral and temporal fine structures in the predicted type III emission are produced by variations in the scattering path lengths and group speeds of radio emission, and in the locations and sizes of emitting volumes. Moderate turbulence levels yield flux enhancements with much broader half-power bandwidths in f p than 2 f p emission, possibly explaining the often observed type IIIb-III harmonic pairs as being where intensifications in 2 f p radiation are not resolved observationally. Larger turbulence levels producing trough-peak regions in the plasma density profile may lead to broader, resolvable intensifications in 2 f p radiation, which may account for the type IIIb-IIIb pairs that are sometimes observed.

  17. Cultural transmission of tool use combined with habitat specializations leads to fine-scale genetic structure in bottlenose dolphins

    NARCIS (Netherlands)

    Kopps, Anna M.; Ackermann, Corinne Y.; Sherwin, William B.; Allen, Simon J.; Bejder, Lars; Kruetzen, Michael

    2014-01-01

    Socially learned behaviours leading to genetic population structure have rarely been described outside humans. Here, we provide evidence of fine-scale genetic structure that has probably arisen based on socially transmitted behaviours in bottlenose dolphins (Tursiops sp.) in western Shark Bay,

  18. Extended x-ray absorption fine structure: Studies of zinc-neutralized sulfonated polystyrene ionomers

    International Nuclear Information System (INIS)

    Ding, Y.S.; Yarusso, D.J.; Pan, H.K.D.; Cooper, S.L.

    1984-01-01

    Extended x-ray absorption fine structure (EXAFS) measurements were performed on a series of zinc-neutralized sulfonated polystyrene ionomers and the local structure around the zinc atom was determined. An interference effect in the EXAFS signal between sulfur and oxygen atoms was found to be significant in these materials. A model for the local structure in the zinc-neutralized sulfonated polystyrene ionomers is proposed which suggests a highly ordered tetrahedral coordination of oxygen around the zinc atoms at a distance of 1.97 +- 0.02 A. In addition there are four sulfur atoms and four oxygen atoms at a distance of 3.15 +- 0.05 A. No zinc-zinc coordination within 5 A was detected in this study

  19. Fine Structure of Glycosaminoglycans from Fresh and Decellularized Porcine Cardiac Valves and Pericardium

    Directory of Open Access Journals (Sweden)

    Antonio Cigliano

    2012-01-01

    Full Text Available Cardiac valves are dynamic structures, exhibiting a highly specialized architecture consisting of cells and extracellular matrix with a relevant proteoglycan and glycosaminoglycan content, collagen and elastic fibers. Biological valve substitutes are obtained from xenogenic cardiac and pericardial tissues. To overcome the limits of such non viable substitutes, tissue engineering approaches emerged to create cell repopulated decellularized scaffolds. This study was performed to determine the glycosaminoglycans content, distribution, and disaccharides composition in porcine aortic and pulmonary valves and in pericardium before and after a detergent-based decellularization procedure. The fine structural characteristics of galactosaminoglycans chondroitin sulfate and dermatan sulfate were examined by FACE. Furthermore, the mechanical properties of decellularized pericardium and its propensity to be repopulated by in vitro seeded fibroblasts were investigated. Results show that galactosaminoglycans and hyaluronan are differently distributed between pericardium and valves and within heart valves themselves before and after decellularization. The distribution of glycosaminoglycans is also dependent from the vascular district and topographic localization. The decellularization protocol adopted resulted in a relevant but not selective depletion of galactosaminoglycans. As a whole, data suggest that both decellularized porcine heart valves and bovine pericardium represent promising materials bearing the potential for future development of tissue engineered heart valve scaffolds.

  20. Fine structure and immunocytochemistry of a new chemosensory system in the Chiton larva (Mollusca: Polyplacophora)

    DEFF Research Database (Denmark)

    Haszprunar, Gerhard; Friedrich, Stefan; Wanninger, Andreas

    2002-01-01

    symmetrically situated pairs lying dorsolaterally and ventrolaterally in the pretrochal part of the trochophore-like larva and they send axons into the cerebral commissure. They are lost at metamorphosis. The fine structure of these cells strongly resembles that of so-called "ampullary cells" known from various...

  1. Investigating the Relationships between Canopy Characteristics and Snow Depth Distribution at Fine Scales: Preliminary Results from the SnowEX TLS Campaign

    Science.gov (United States)

    Glenn, N. F.; Uhlmann, Z.; Spaete, L.; Tennant, C.; Hiemstra, C. A.; McNamara, J.

    2017-12-01

    Predicting changes in forested seasonal snowpacks under altered climate scenarios is one of the most pressing hydrologic challenges facing today's society. Airborne- and satellite-based remote sensing methods hold the potential to transform measurements of terrestrial water stores in snowpack, improve process representations of snowpack accumulation and ablation, and to generate high quality predictions that inform potential strategies to better manage water resources. While the effects of forest on snowpack are well documented, many of the fine-scale processes influenced by the forest-canopy are not directly accounted for because most snow models don't explicitly represent canopy structure and canopy heterogeneity. This study investigates the influence of forest canopy on snowpack distribution at fine scales and quantifies the influence of canopy heterogeneity on snowpack accumulation and ablation processes. We use terrestrial laser scanning (TLS) data collected during the SnowEX campaign to discover how the relationships between canopy and snow distributions change across scales. Our sample scales range from individual trees to patches of trees across the Grand Mesa, CO, SnowEx site.

  2. Fine-scale population structure and the era of next-generation sequencing.

    Science.gov (United States)

    Henn, Brenna M; Gravel, Simon; Moreno-Estrada, Andres; Acevedo-Acevedo, Suehelay; Bustamante, Carlos D

    2010-10-15

    Fine-scale population structure characterizes most continents and is especially pronounced in non-cosmopolitan populations. Roughly half of the world's population remains non-cosmopolitan and even populations within cities often assort along ethnic and linguistic categories. Barriers to random mating can be ecologically extreme, such as the Sahara Desert, or cultural, such as the Indian caste system. In either case, subpopulations accumulate genetic differences if the barrier is maintained over multiple generations. Genome-wide polymorphism data, initially with only a few hundred autosomal microsatellites, have clearly established differences in allele frequency not only among continental regions, but also within continents and within countries. We review recent evidence from the analysis of genome-wide polymorphism data for genetic boundaries delineating human population structure and the main demographic and genomic processes shaping variation, and discuss the implications of population structure for the distribution and discovery of disease-causing genetic variants, in the light of the imminent availability of sequencing data for a multitude of diverse human genomes.

  3. Estimation of non-linear effective permeability of magnetic materials with fine structure

    International Nuclear Information System (INIS)

    Waki, H.; Igarashi, H.; Honma, T.

    2006-01-01

    This paper describes a homogenization method for magnetic materials with fine structure. In this method, the structures of the magnetic materials are assumed to be periodic, and the unit cell is defined. The effective permeability is determined on the basis of magnetic energy balance in the unit cell. This method can be applied not only for linear problems but also for non-linear ones. In this paper, estimation of the effective permeability of non-linear magnetic materials by using the homogenization method is described in detail, and then the validity for the non-liner problems is tested for two-dimensional problems. It is shown that this homogenization method gives accurate non-linear effective permeability

  4. X-ray photoemission spectroscopy (XPS) and extended x-ray absorption fine structure (EXAFS) studies of silicate based glasses

    International Nuclear Information System (INIS)

    Karim, D.; Lam, D.J.

    1979-01-01

    The application of the x-ray photoemission spectroscopy (XPS) technique to study the electronic structure and bonding of heavy metal oxides in alkali- and alkali-earth-silicate glasses had been demonstrated. The bonding characteristics of the iron oxide and uranium oxide in sodium silicate glasses were deduced from the changes in the oxygen 1s levels and the heavy metal core levels. It is reasonable to expect that the effect of leaching on the heavy metal ions can be monitored using the appropriate core levels of these ions. To study the effect of leaching on the glass forming network, the valence band structure of the bridging and nonbridging oxygens in sodium silicate glasses were investigated. The measurement of extended x-ray absorption fine-structure (EXAFS) is a relatively new analytical technique for obtaining short range (<5 A) structural information around atoms of a selected species in both solid and fluid systems. Experiments have recently begun to establish the feasibility of using EXAFS to study the bonding of actinides in silicate glasses. Because of the ability of EXAFS to yield specific structural data even in complex multicomponent systems, it could prove to be an invaluable tool in understanding glass structure

  5. Dopant activation mechanism of Bi wire-δ-doping into Si crystal, investigated with wavelength dispersive fluorescence x-ray absorption fine structure and density functional theory.

    Science.gov (United States)

    Murata, Koichi; Kirkham, Christopher; Shimomura, Masaru; Nitta, Kiyofumi; Uruga, Tomoya; Terada, Yasuko; Nittoh, Koh-Ichi; Bowler, David R; Miki, Kazushi

    2017-04-20

    We successfully characterized the local structures of Bi atoms in a wire-δ-doped layer (1/8 ML) in a Si crystal, using wavelength dispersive fluorescence x-ray absorption fine structure at the beamline BL37XU, in SPring-8, with the help of density functional theory calculations. It was found that the burial of Bi nanolines on the Si(0 0 1) surface, via growth of Si capping layer at 400 °C by molecular beam epitaxy, reduced the Bi-Si bond length from [Formula: see text] to [Formula: see text] Å. We infer that following epitaxial growth the Bi-Bi dimers of the nanoline are broken, and the Bi atoms are located at substitutional sites within the Si crystal, leading to the shorter Bi-Si bond lengths.

  6. Temporal Fine-Structure Coding and Lateralized Speech Perception in Normal-Hearing and Hearing-Impaired Listeners

    DEFF Research Database (Denmark)

    Locsei, Gusztav; Pedersen, Julie Hefting; Laugesen, Søren

    2016-01-01

    This study investigated the relationship between speech perception performance in spatially complex, lateralized listening scenarios and temporal fine-structure (TFS) coding at low frequencies. Young normal-hearing (NH) and two groups of elderly hearing-impaired (HI) listeners with mild or moderate...... hearing loss above 1.5 kHz participated in the study. Speech reception thresholds (SRTs) were estimated in the presence of either speech-shaped noise, two-, four-, or eight-talker babble played reversed, or a nonreversed two-talker masker. Target audibility was ensured by applying individualized linear...... threshold nor the interaural phase difference threshold tasks showed a correlation with the SRTs or with the amount of masking release due to binaural unmasking, respectively. The results suggest that, although HI listeners with normal hearing thresholds below 1.5 kHz experienced difficulties with speech...

  7. Multiwavelength anomalous diffraction and diffraction anomalous fine structure to study composition and strain of semiconductor nano structures

    International Nuclear Information System (INIS)

    Favre-Nicolin, V.; Proietti, M.G.; Leclere, C.; Renevier, H.; Katcho, N.A.; Richard, M.I.

    2012-01-01

    The aim of this paper is to illustrate the use of Multi-Wavelength Anomalous Diffraction (MAD) and Diffraction Anomalous Fine Structure (DAFS) spectroscopy for the study of structural properties of semiconductor nano-structures. We give a brief introduction on the basic principles of these techniques providing a detailed bibliography. Then we focus on the data reduction and analysis and we give specific examples of their application on three different kinds of semiconductor nano-structures: Ge/Si nano-islands, AlN capped GaN/AlN Quantum Dots and AlGaN/AlN Nano-wires. We show that the combination of MAD and DAFS is a very powerful tool to solve the structural problem of these materials of high technological impact. In particular, the effects of composition and strain on diffraction are disentangled and composition can be determined in a reliable way, even at the interface between nano-structure and substrate. We show the great possibilities of this method and give the reader the basic tools to undertake its use. (authors)

  8. Investigation of the hyperfine structure of Praseodymium-transitions using laser spectroscopy

    International Nuclear Information System (INIS)

    Shamim Khan

    2011-01-01

    A comprehensive knowledge of the electron levels in an atom is one of the prerequisite for understanding the electron-electron and electron-nucleus interactions inside an atom and for the classification of the atomic spectrum of an element. The spin-orbit interaction is the largest relativistic effect and is responsible for the fine structure splitting in an atom. The hyperfine structure splitting of the fine structure atomic energy levels arise as a result of the interaction between spinning and orbiting electrons and electromagnetic multipole nuclear moments. The electronic ground state configuration of praseodymium 59 Pr 141 is [Xe] 4f 3 6s 2 , with ground state level 4 I 9/2 . Because of its 5 outer electrons Praseodymium has a high density of energy levels which give rise to an extremely line rich emission spectrum. Due to this fact praseodymium serves as an efficient testing ground for hyperfine structure studies. The thesis is mainly devoted to the finding of previously unknown energy levels by the investigation of spectral lines and their hyperfine structures. In a hollow cathode discharge lamp praseodymium atoms and ions in ground and excited states are excited to high lying states by laser light. The excitation source is a tunable ring-dye laser system, operated with Stilbene 3, Rhodamine 6G, Kiton Red, DCM and LD 700. A high resolution Fourier Transform spectrum is used for extracting excitation wavelengths. Then the laser wavelength is tuned to a strong hyperfine component of the spectral line to be investigated, and a search for fluorescence from excited levels is performed. From the observed hyperfine structure pattern, J-values and hyperfine interaction constants A of the combining levels are determined. This information, together with excitation and fluorescence wavelengths, allows us to find the energies of the involved levels. During the course of this dissertation 313 new energy levels of Pr I and 4 new energy levels of Pr II were discovered

  9. Fine structure in the cluster decays of the translead nuclei

    International Nuclear Information System (INIS)

    Dumitrescu, O.; Cioaca, C.

    1994-06-01

    Within the one level R-matrix approach several hindrance factors for the radioactive decays in which are emitted α and other nuclei (such as 14 C and 20 O) are calculated. The interior wave functions are supposed to be given by the shell model with effective residual interactions. The exterior wave functions are calculated from a cluster - nucleus double - folding model potential with the M3Y interaction. As examples of the cluster decay fine structure we analyzed the particular cases of α - decay of 255 Fm, 14 C - decay of 223 Ra and 20 O - decay of 229 Th and 225 Fm. Good agreement with the experimental data is obtained. (author). 38 refs, 6 tabs

  10. [Correlation of fine structures of distributions of amplitudes of a photomultiplier dark current fluctuations with the Earth rotations about its axis].

    Science.gov (United States)

    Fedorov, M V; Belousov, L V; Voeĭkov, V L; Zenchenko, K I; Zenchenko, T A; Konradov, A A; Shnol', S E

    2001-01-01

    The fine structures of distributions of photomultiplier dark current fluctuations measured in two laboratories 2000 km distant from other: in the international Institute of Biophysics (Neuss, Germany) and in the Moscow State University (Moscow, Russia) were compared. It is shown that similar forms of appropriate histograms are apparently more often realized at both locations at the same local time. This confirms the previous conclusion that the fine structure of distributions correlates with rotation of the Earth about its axis.

  11. Fine structure of the giant M1 resonance in 90Zr.

    Science.gov (United States)

    Rusev, G; Tsoneva, N; Dönau, F; Frauendorf, S; Schwengner, R; Tonchev, A P; Adekola, A S; Hammond, S L; Kelley, J H; Kwan, E; Lenske, H; Tornow, W; Wagner, A

    2013-01-11

    The M1 excitations in the nuclide 90Zr have been studied in a photon-scattering experiment with monoenergetic and linearly polarized beams from 7 to 11 MeV. More than 40 J(π)=1+ states have been identified from observed ground-state transitions, revealing the fine structure of the giant M1 resonance with a centroid energy of 9 MeV and a sum strength of 4.17(56) μ(N)(2). The result for the total M1 strength and its fragmentation are discussed in the framework of the three-phonon quasiparticle-phonon model.

  12. Exciton fine structure in CdSe nanoclusters

    International Nuclear Information System (INIS)

    Leung, K.; Pokrant, S.; Whaley, K.B.

    1998-01-01

    The fine structure in the CdSe nanocrystal absorption spectrum is computed by incorporating two-particle electron-hole interactions and spin-orbit coupling into a tight-binding model, with an expansion in electron-hole single-particle states. The exchange interaction and spin-orbit coupling give rise to dark, low-lying states that are predominantly triplet in character, as well as to a manifold of exciton states that are sensitive to the nanocrystal shape. Near the band gap, the exciton degeneracies are in qualitative agreement with the effective mass approximation (EMA). However, instead of the infinite lifetimes for dark states characteristic of the EMA, we obtain finite radiative lifetimes for the dark states. In particular, for the lowest, predominantly triplet, states we obtain radiative lifetimes of microseconds, in qualitative agreement with the experimental measured lifetimes. The resonant Stokes shifts obtained from the splitting between the lowest dark and bright states are also in good agreement with experimental values for larger crystallites. Higher-lying states exhibit significantly more complex behavior than predicted by EMA, due to extensive mixing of electron-hole pair states. copyright 1998 The American Physical Society

  13. Fine-scale genetic structure and cryptic associations reveal evidence of kin-based sociality in the African forest elephant.

    Science.gov (United States)

    Schuttler, Stephanie G; Philbrick, Jessica A; Jeffery, Kathryn J; Eggert, Lori S

    2014-01-01

    Spatial patterns of relatedness within animal populations are important in the evolution of mating and social systems, and have the potential to reveal information on species that are difficult to observe in the wild. This study examines the fine-scale genetic structure and connectivity of groups within African forest elephants, Loxodonta cyclotis, which are often difficult to observe due to forest habitat. We tested the hypothesis that genetic similarity will decline with increasing geographic distance, as we expect kin to be in closer proximity, using spatial autocorrelation analyses and Tau K(r) tests. Associations between individuals were investigated through a non-invasive genetic capture-recapture approach using network models, and were predicted to be more extensive than the small groups found in observational studies, similar to fission-fusion sociality found in African savanna (Loxodonta africana) and Asian (Elephas maximus) species. Dung samples were collected in Lopé National Park, Gabon in 2008 and 2010 and genotyped at 10 microsatellite loci, genetically sexed, and sequenced at the mitochondrial DNA control region. We conducted analyses on samples collected at three different temporal scales: a day, within six-day sampling sessions, and within each year. Spatial autocorrelation and Tau K(r) tests revealed genetic structure, but results were weak and inconsistent between sampling sessions. Positive spatial autocorrelation was found in distance classes of 0-5 km, and was strongest for the single day session. Despite weak genetic structure, individuals within groups were significantly more related to each other than to individuals between groups. Social networks revealed some components to have large, extensive groups of up to 22 individuals, and most groups were composed of individuals of the same matriline. Although fine-scale population genetic structure was weak, forest elephants are typically found in groups consisting of kin and based on matrilines

  14. Fine-scale population structure of Malays in Peninsular Malaysia and Singapore and implications for association studies.

    Science.gov (United States)

    Hoh, Boon-Peng; Deng, Lian; Julia-Ashazila, Mat Jusoh; Zuraihan, Zakaria; Nur-Hasnah, Ma'amor; Nur-Shafawati, Ab Rajab; Hatin, Wan Isa; Endom, Ismail; Zilfalil, Bin Alwi; Khalid, Yusoff; Xu, Shuhua

    2015-07-22

    Fine scale population structure of Malays - the major population in Malaysia, has not been well studied. This may have important implications for both evolutionary and medical studies. Here, we investigated the population sub-structure of Malay involving 431 samples collected from all states from peninsular Malaysia and Singapore. We identified two major clusters of individuals corresponding to the north and south peninsular Malaysia. On an even finer scale, the genetic coordinates of the geographical Malay populations are in correlation with the latitudes (R(2) = 0.3925; P = 0.029). This finding is further supported by the pairwise FST of Malay sub-populations, of which the north and south regions showed the highest differentiation (FST [North-south] = 0.0011). The collective findings therefore suggest that population sub-structure of Malays are more heterogenous than previously expected even within a small geographical region, possibly due to factors like different genetic origins, geographical isolation, could result in spurious association as demonstrated in our analysis. We suggest that cautions should be taken during the stage of study design or interpreting the association signals in disease mapping studies which are expected to be conducted in Malay population in the near future.

  15. Fine structure of spermatogenesis in polyopisthocotylid monogeneans (Protomicrocotyle ivoriensis, Gastrocotyle sp.).

    Science.gov (United States)

    Schmahl, G; Obiekezie, A

    1991-01-01

    The development of spermatozoa in the polyopisthocotylean fish-gill flukes Protomicrocotyle ivoriensis and Gastrocotyle sp. was investigated by light and transmission electron microscopy. In both species the spermatogonia were undifferentiated cells, the cytoplasm of which contained numerous free ribosomes, and successive mitoses gave rise to primary spermatocytes, which are clearly identified by the presence of synaptonemal complexes in their nuclei. As compared with that of the spermatogonia, the cytoplasm of the primary spermatocytes contained an increased number of ribosomes. Golgi complexes were frequently seen in the spermatocytes of P. ivoriensis but not in Gastrocotyle sp. In P. ivoriensis the secondary spermatocytes were separated by interspaces between the irregularly shaped cell surfaces. In both species a syncytial mass of spermatids developed, which gave rise to 64 spermatozoa. Cross sections of the mature spermatozoa of both species revealed the presence of numerous submembranous microtubules and two axonemes showing a pattern of 9 doublet peripheral microtubules plus a central one. In contrast to microtubules plus a central one. In contrast to P. ivoriensis, in Gastrocotyle sp. the axonemes originated from different places at the axis of the spermatozoon. With respect to the other results obtained, the spermiogenesis and the fine structure of spermatozoa of both species studied were similar to previous findings in other polyopisthocotyleans.

  16. Content and structure of future teachers’ aesthetic perception of fine and decorative applied art creations

    Directory of Open Access Journals (Sweden)

    Liudmyla Lisunova

    2017-03-01

    Full Text Available The content and structure of future teachers’ aesthetic perception of fine and decorativeapplied art creations in the system of professional training are delivered in this article. Thestructural components and stages (phases of aesthetic perception process are determined, therole of art as the most powerful source of reality in the process of future teachers’ aestheticperception of art are revealed.Key words: contents and structure of aesthetic perception, future teachers of art, fineand decorative applied art creations

  17. On the origin of fine structure in the photoluminescence spectra of the β-sialon:Eu2+ green phosphor

    Directory of Open Access Journals (Sweden)

    Kohsei Takahashi, Ken-ichi Yoshimura, Masamichi Harada, Yoshitaka Tomomura, Takashi Takeda, Rong-Jun Xie and Naoto Hirosaki

    2012-01-01

    Full Text Available The photoluminescence (PL and PL excitation (PLE spectra of Si6−zAlzOzN8−z (β-sialon:Eu2+ phosphors with small z values (z=0.025–0.24 were studied at room temperature and 6 K. The PL and PLE spectra exhibit fine structure with the PL lines being as sharp as 45–55 nm even at room temperature; this fine structure was enhanced by decreasing the z value. These results can be used for expanding the color gamut of liquid crystal displays, particularly in the blue–green region. From low-temperature measurements, the fine PLE structure was ascribed to discrete energy levels of 7FJ states. The 4f65d excited states of Eu2+ are considered to be localized near the 4f orbital. This is because the bonding of Eu2+ with surrounding atoms is ionic rather than covalent. Lattice phonon absorptions were also observed in the PLE spectrum, revealing that the optically active Eu2+ ions are located in the β-sialon crystal. The PL spectrum of the sample with the smallest z value (0.025 consists of a sharp zero-phonon line and lattice phonon replicas, which results in a sharp and asymmetric spectral shape.

  18. On the effects of the two-body non-fine-structure operators of the Breit-Pauli Hamiltonian

    International Nuclear Information System (INIS)

    Badnell, N.R.

    1997-01-01

    We have incorporated the two-body non-fine-structure operators of the Breit-Pauli Hamiltonian, namely contact spin-spin, two-body Darwin and orbit-orbit, into the program AUTOSTRUCTURE. Illustrative results are presented, including some for reactions involving the process of autoionization. (author)

  19. The structure of hydrate bearing fine grained marine sediments

    Energy Technology Data Exchange (ETDEWEB)

    Priest, J.; Kingston, E.; Clayton, C. [Southampton Univ., Highfield (United Kingdom). School of Civil Engineering and the Environment; Schultheiss, P.; Druce, M. [Geotek Ltd., Daventry (United Kingdom)

    2008-07-01

    This paper discussed the structure of naturally occurring methane gas hydrates in fine-grained sediments from core samples recovered using in situ pressures from the eastern margin of the Indian Ocean. High resolution X-ray computed tomography (CT) images were taken of gas hydrate cores. The hydrate structure was examined and comparisons were made between low resolution X-ray images obtained on the cores prior to sub-sectioning and depressurization procedures. The X-ray images showed the presence of high-angle, sub-parallel veins within the recovered sediments. The scans indicated that the hydrates occurred as fracture filing veins throughout the core. Fracture orientation was predominantly sub-vertical. Thick millimetric hydrate veins were composed of sub-millimetric veins with variations in fracture angle. The analysis indicated that hydrate formation was episodic in nature and subject to changes in the stress regime. Results of the study showed that depressurization and subsequent freezing alter the structure of the sediment even when the gas hydrate has not been altered. A large proportion of the hydrate survived when outside of its stability region. The self-preserving behaviour of the hydrate was attributed to the endothermic nature of gas hydrate dissociation. It was concluded that the accurate physical characterization of gas hydrates can only be conducted when the core section remains under in situ stress conditions. 13 refs., 9 figs.

  20. The Low Pitch of High-Frequency Complex Tones Relies on Temporal Fine Structure Information

    DEFF Research Database (Denmark)

    Santurette, Sébastien; Dau, Torsten

    2010-01-01

    High-frequency complex tones containing only unresolved harmonic components with a frequency spacing Δf usually evoke a low pitch equal to Δf. However, for inharmonic components, the low pitch is often found to deviate slightly from Δf. Whether this pitch shift relies exclusively on temporal fine...... structure (TFS) cues has been a matter of debate. It is also controversial up to which frequency TFS information remains available, and to what extent envelope cues become dominant as frequency increases. Using a pitch-matching paradigm, this study investigated whether the pitch of transposed tones.......5]. All stimuli were presented at 50 dB SPL in broadband pink-noise (13.5 dB/Hz at 1 kHz), and 40 matches per condition were obtained. For fenv = fc/11.5, the results favored hypothesis A for all values of fc, indicating that TFS cues are available and used for pitch extraction, up to at least 7 k...

  1. Fine structures and magnetic properties of FeCo granular thin films with plasma polymerized (C4F8) n matrix

    International Nuclear Information System (INIS)

    Kakizaki, K.; Yasoshima, S.; Choi, K.-K.; Kamishima, K.; Hiratsuka, N.

    2007-01-01

    In this paper a method for polymerization of fluorocarbon gas in argon plasma to obtain a novel granular structure was reported. We prepared granular films where FeCo fine particles were distributed in plasma-polymerized fluorocarbon matrix by a facing-targets RF magnetron sputtering method, and investigated the correlation between their structures and magnetic properties. The magnetization of the films prepared with the partial pressure of fluorocarbon gas between 0 and 1.0 mTorr decreased linearly, because the FeCo content in a unit volume of a film decreased when a polymerized material was used as the matrix. However, the coercivity of the films decreased drastically with increasing the partial pressure of fluorocarbon gas above 0.4 mTorr. This is because the magnetic anisotropy of FeCo particles is decreased by the decrease of grain size. It was confirmed by a TEM observation that the FeCo-(C 4 F 8 ) n films had the granular structure which was constituted by the very fine FeCo particles and the plasma-polymerized fluorocarbon matrix. For the film deposited at the partial pressure of fluorocarbon gas of 0.4 mTorr, the size of FeCo magnetic particles is about 20 nm. On the other hand, the size of FeCo particles is decreased to about 8 nm when the film deposited at the partial pressure of fluorocarbon gas of 0.8 mTorr and its distribution is small

  2. Fine-scale population structure and riverscape genetics of brook trout (Salvelinus fontinalis) distributed continuously along headwater channel networks

    Science.gov (United States)

    Kanno, Yoichiro; Vokoun, Jason C.; Letcher, Benjamin H.

    2011-01-01

    Linear and heterogeneous habitat makes headwater stream networks an ideal ecosystem in which to test the influence of environmental factors on spatial genetic patterns of obligatory aquatic species. We investigated fine-scale population structure and influence of stream habitat on individual-level genetic differentiation in brook trout (Salvelinus fontinalis) by genotyping eight microsatellite loci in 740 individuals in two headwater channel networks (7.7 and 4.4 km) in Connecticut, USA. A weak but statistically significant isolation-by-distance pattern was common in both sites. In the field, many tagged individuals were recaptured in the same 50-m reaches within a single field season (summer to fall). One study site was characterized with a hierarchical population structure, where seasonal barriers (natural falls of 1.5–2.5 m in height during summer base-flow condition) greatly reduced gene flow and perceptible spatial patterns emerged because of the presence of tributaries, each with a group of genetically distinguishable individuals. Genetic differentiation increased when pairs of individuals were separated by high stream gradient (steep channel slope) or warm stream temperature in this site, although the evidence of their influence was equivocal. In a second site, evidence for genetic clusters was weak at best, but genetic differentiation between individuals was positively correlated with number of tributary confluences. We concluded that the population-level movement of brook trout was limited in the study headwater stream networks, resulting in the fine-scale population structure (genetic clusters and clines) even at distances of a few kilometres, and gene flow was mitigated by ‘riverscape’ variables, particularly by physical barriers, waterway distance (i.e. isolation-by-distance) and the presence of tributaries.

  3. Usage of Crushed Concrete Fines in Decorative Concrete

    Science.gov (United States)

    Pilipenko, Anton; Bazhenova, Sofia

    2017-10-01

    The article is devoted to the questions of usage of crushed concrete fines from concrete scrap for the production of high-quality decorative composite materials based on mixed binder. The main problem in the application of crushed concrete in the manufacture of decorative concrete products is extremely low decorative properties of crushed concrete fines itself, as well as concrete products based on them. However, crushed concrete fines could have a positive impact on the structure of the concrete matrix and could improve the environmental and economic characteristics of the concrete products. Dust fraction of crushed concrete fines contains non-hydrated cement grains, which can be opened in screening process due to the low strength of the contact zone between the hydrated and non-hydrated cement. In addition, the screening process could increase activity of the crushed concrete fines, so it can be used as a fine aggregate and filler for concrete mixes. Previous studies have shown that the effect of the usage of the crushed concrete fines is small and does not allow to obtain concrete products with high strength. However, it is possible to improve the efficiency of the crushed concrete fines as a filler due to the complex of measures prior to mixing. Such measures may include a preliminary mechanochemical activation of the binder (cement binder, iron oxide pigment, silica fume and crushed concrete fines), as well as the usage of polycarboxylate superplasticizers. The development of specific surface area of activated crushed concrete fines ensures strong adhesion between grains of binder and filler during the formation of cement stone matrix. The particle size distribution of the crushed concrete fines could achieve the densest structure of cement stone matrix and improve its resistance to environmental effects. The authors examined the mechanisms of structure of concrete products with crushed concrete fines as a filler. The results of studies of the properties of

  4. The fine structure of the sperm of the round goby (Neogobius melanostomus)

    Science.gov (United States)

    Allen, Jeffrey D.; Walker, Glenn K.; Nichols, Susan J.; Sorenson, Dorothy

    2004-01-01

    The fine structural details of the spermatozoon of the round goby are presented for the first time in this study. Scanning and transmission electron microscopic examination of testis reveals an anacrosomal spermatozoon with a slightly elongate head and uniformly compacted chromatin. The midpiece contains a single, spherical mitochondrion. Two perpendicularly oriented centrioles lie in a deep, eccentric nuclear fossa with no regularly observed connection to the nucleus. The flagellum develops bilateral fins soon after emerging from the fossa; each extends approximately 1 A?m from the axoneme and persists nearly the length of the flagellum.

  5. EXANA, a program for analysing EXtended energy loss fine structures, EXELFS spectra

    International Nuclear Information System (INIS)

    Tafreshi, M.A.; Bohm, C.; Csillag, S.

    1992-09-01

    This paper is a users guide and reference manual for the EXANA, an IBM or IBM compatible PC-based program used for analysing extended fine structures occurring on the high energy side of the ionisation edges. The RDF (Radial Distance Function) obtained from this analysis contains information about the number, distance, and type of the nearby atoms, as well as the inelastic mean free path and disorder in distances from the centre atom to the atoms in a atomic shell around it. The program can be made available on request. (au)

  6. New Constraints on Spatial Variations of the Fine Structure Constant from Clusters of Galaxies

    Directory of Open Access Journals (Sweden)

    Ivan De Martino

    2016-12-01

    Full Text Available We have constrained the spatial variation of the fine structure constant using multi-frequency measurements of the thermal Sunyaev-Zeldovich effect of 618 X-ray selected clusters. Although our results are not competitive with the ones from quasar absorption lines, we improved by a factor 10 and ∼2.5 previous results from Cosmic Microwave Background power spectrum and from galaxy clusters, respectively.

  7. Fusion reaction yield in focused discharges with variable energy and plasma fine structure

    International Nuclear Information System (INIS)

    Bortolotti, A.; Brzosko, J.S.; Chiara, P. De; Kilic, H.; Mezzetti, F.; Nardi, V.; Powell, C.; Wang, J.

    1992-01-01

    The same linear correlation between the distribution parameters (ΔT and Max ΔV) of the radial current density J between electrodes and the fusion reaction yield per pulse, Y, in the plasma focus (PF) pinch was quantitatively determined from different PF machines. Contact prints of current-sheath fragments (CSF) ejected from the pinch are obtained from 2.5-MeV-D + ions. CSF's show the same submillimetric fine structure of the pinch. (author) 3 refs., 2 tabs

  8. Polarized fine structure in the excitation spectrum of a negatively charged quantum dot

    OpenAIRE

    Ware, M. E.; Stinaff, E. A.; Gammon, D.; Doty, M. F.; Bracker, A. S.; Gershoni, D.; Korenev, V. L.; Badescu, S. C.; Lyanda-Geller, Y.; Reinecke, T. L.

    2005-01-01

    We report polarized photoluminescence excitation spectroscopy of the negative trion in single charge tunable InAs/GaAs quantum dots. The spectrum exhibits a p-shell resonance with polarized fine structure arising from the direct excitation of the electron spin triplet states. The energy splitting arises from the axially symmetric electron-hole exchange interaction. The magnitude and sign of the polarization are understood from the spin character of the triplet states and a small amount of qua...

  9. The 16th International Conference on X-ray Absorption Fine Structure (XAFS16)

    Science.gov (United States)

    Grunwaldt, J.-D.; Hagelstein, M.; Rothe, J.

    2016-05-01

    This preface of the proceedings volume of the 16th International Conference on X- ray Absorption Fine Structure (XAFS16) gives a glance on the five days of cutting-edge X-ray science which were held in Karlsruhe, Germany, August 23 - 28, 2015. In addition, several satellite meetings took place in Hamburg, Berlin and Stuttgart, a Sino-German workshop, three data analysis tutorials as well as special symposia on industrial catalysis and XFELs were held at the conference venue.

  10. Galaxy clusters, type Ia supernovae and the fine structure constant

    Energy Technology Data Exchange (ETDEWEB)

    Holanda, R.F.L. [Departamento de Física, Universidade Estadual da Paraíba, street Baraúnas, Campina Grande, PB, 58429-500 (Brazil); Busti, V.C. [Departamento de Física Matemática, Instituto de Física, Universidade de São Paulo, CP 66318, São Paulo, SP, CEP 05508-090 Brazil (Brazil); Colaço, L.R. [Departamento de Física, Universidade Federal de Campina Grande, street Aprígio Veloso, Campina Grande, PB, 58429-900 (Brazil); Alcaniz, J.S. [Observatório Nacional, Street José Cristino, Rio de Janeiro, RJ, 20921-400 (Brazil); Landau, S.J., E-mail: holanda@uepb.edu.br, E-mail: viniciusbusti@gmail.com, E-mail: colacolrc@gmail.com, E-mail: alcaniz@on.br, E-mail: slandau@df.uba.ar [Departamento de Física, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Viamonte, Buenos Aires, 1053 Argentina (Argentina)

    2016-08-01

    As is well known, measurements of the Sunyaev-Zeldovich effect can be combined with observations of the X-ray surface brightness of galaxy clusters to estimate the angular diameter distance to these structures. In this paper, we show that this technique depends on the fine structure constant, α. Therefore, if α is a time-dependent quantity, e.g., α = α{sub 0}φ( z ), where φ is a function of redshift, we argue that current data do not provide the real angular diameter distance, D {sub A}( z ), to the cluster, but instead D {sub A}{sup data}( z ) = φ( z ){sup 2} D {sub A}( z ). We use this result to derive constraints on a possible variation of α for a class of dilaton runaway models considering a sample of 25 measurements of D {sub A}{sup data}( z ) in redshift range 0.023 < z < 0.784 and estimates of D {sub A}( z ) from current type Ia supernovae observations. We find no significant indication of variation of α with the present data.

  11. Chromospheric counterparts of solar transition region unresolved fine structure loops

    Science.gov (United States)

    Pereira, Tiago M. D.; Rouppe van der Voort, Luc; Hansteen, Viggo H.; De Pontieu, Bart

    2018-04-01

    Low-lying loops have been discovered at the solar limb in transition region temperatures by the Interface Region Imaging Spectrograph (IRIS). They do not appear to reach coronal temperatures, and it has been suggested that they are the long-predicted unresolved fine structures (UFS). These loops are dynamic and believed to be visible during both heating and cooling phases. Making use of coordinated observations between IRIS and the Swedish 1-m Solar Telescope, we study how these loops impact the solar chromosphere. We show for the first time that there is indeed a chromospheric signal of these loops, seen mostly in the form of strong Doppler shifts and a conspicuous lack of chromospheric heating. In addition, we find that several instances have a inverse Y-shaped jet just above the loop, suggesting that magnetic reconnection is driving these events. Our observations add several puzzling details to the current knowledge of these newly discovered structures; this new information must be considered in theoretical models. Two movies associated to Fig. 1 are available at http://https://www.aanda.org

  12. Evidence for the distortion product frequency place as a source of distribution product otoacoustic emission (DPOAE) fine structure in humans : I. Fine structure and higher-order DPOAE as a function of the frequency ratio f2/f1

    NARCIS (Netherlands)

    Mauermann, M; Uppenkamp, S; van Hengel, P.W.J.; Kollmeier, B

    1999-01-01

    Critical experiments were performed in order to validate the two-source hypothesis of distortion product otoacoustic emissions (DPOAE) generation. Measurements of the spectral fine structure of DPOAE in response to stimulation with two sinusoids have been:performed with normal-hearing subjects. The

  13. The importance of source positions during radio fine structure observations

    International Nuclear Information System (INIS)

    Chernov, Guennadi P.; Yan Yi-Hua; Fu Qi-Jun

    2014-01-01

    The measurement of positions and sizes of radio sources in the observations of the fine structure of solar radio bursts is a determining factor for the selection of the radio emission mechanism. The identical parameters describing the radio sources for zebra structures (ZSs) and fiber bursts confirm there is a common mechanism for both structures. It is very important to measure the size of the source in the corona to determine if it is distributed along the height or if it is point-like. In both models of ZSs (the double plasma resonance (DPR) and the whistler model) the source must be distributed along the height, but by contrast to the stationary source in the DPR model, in the whistler model the source should be moving. Moreover, the direction of the space drift of the radio source must correlate with the frequency drift of stripes in the dynamic spectrum. Some models of ZSs require a local source, for example, the models based on the Bernstein modes, or on explosive instability. The selection of the radio emission mechanism for fast broadband pulsations with millisecond duration also depends on the parameters of their radio sources. (mini-volume: solar radiophysics — recent results on observations and theories)

  14. Revised description of the fine structure of in situ "zooxanthellae" genus Symbiodinium.

    Science.gov (United States)

    Wakefield, T S; Farmer, M A; Kempf, S C

    2000-08-01

    The fine structure of the symbiotic dinoflagellate genus Symbiodinium has been well described. All of the published descriptions are based on tissue that was fixed in standard aldehyde and osmium fixatives and dehydrated in an ethanol series before embedding. When the technique of freeze-substitution was used to fix tissue from Cassiopeia xamachana, Aiptasia pallida, and Phyllactis flosculifera and prepare it for embedding, thecal vesicles were revealed within the in situ symbionts of all three species. Although these structures have been identified in cultured symbionts, they have never been described in the in situ symbionts. A review of the literature has revealed several instances where thecal vesicles were either overlooked or identified incorrectly. Thus the formal description of the genus Symbiodinium, which describes the in situ symbionts, contains information that is based on artifact and should be revised. A revision of the genus is suggested, and the true nature of these structures and their significance in the symbiotic association are discussed.

  15. Fine--Mesh Photodetectors for CMS Endcap Electromagnetic Calorimeter

    CERN Document Server

    Bajanov, N A; Golubev, Nikolai; Gusev, Yuri; Kachanov, Vassili; Klechneva, T Y; Kovalev, A I; Levtchenko, L A; Lukyanov, Valery; Mamaeva, Galina; Moroz, Feodor; Prilutskaya, D M; Seliverstov, Dmitry; Blinnikov, Yuri

    1998-01-01

    The behaviour of fine-mesh vacuum phototetrodes and phototriodes ( VPTs) in an axial magnetic field of ( 0 -- 4)T has been investigated. The measured VPT parameters are: fine-mesh cell dimensions, the photocathode sensitivity and its homogenity, the gain in zero and 4T magnetic field at tilt angles corresponding to the rapidity range of CMS ECAL Endcap 1.479 -- 3.0 and excess noise factor. Measurements have been performed on 21 and 30 mm diameter photodetectors with different fine-mesh structures: 30, 60 and 100 lines per mm under different types of photocathode illumination by green LED. Phototriodes with 30 or 60 lines per mm and an external diameter of 21 mm are found to be the best candidates for the CMS environment with the initial size of PWO crystals proposed to be used in the Endcap, by comparison with phototetrodes. They provide a gain of the order of 6 -- 8 in 4T magnetic field and an excess noise factor of 2 under full photocathode illumination.

  16. Investigation of electronic lattice structure by positron annihilation in some insulators

    International Nuclear Information System (INIS)

    Coussot, Gerard

    1970-01-01

    The angular distribution of gamma quanta resulting from positron annihilation in single insulator crystals was measured with long slit geometry apparatus for intense positron sources ( 64 Cu ≅ 1 Ci). Two new phenomena were observed in the angular correlation curves. In the f. c. c. MgO, UO 2 , CaF 2 crystals, modulations appeared at angles corresponding to the limit of the first Brillouin zone in relation to the crystallographic direction studied. In SiO 2 , F 2 Mg, F 2 Mn crystals, a narrow peak at 0 mrad and a fine structure superimposed on the broad distribution, were resolved. The fine structure which is correlated with the narrow component is characterized by modulations appearing at angles corresponding to the projection of reciprocal lattice vectors along the crystallographic direction investigated. The narrow peak at p ≅ 0 suggests the formation of a bound state (positron-electron). If this bound state is described by a Bloch wave, the modulations observed correspond to the Fourier components which contribute to every reciprocal lattice vector p = G ('Umklapp' process). This model predicts that the 'Umklapp' process in polycrystals must produce a change in slope which can be experimentally observed. A systematic research of optimal observation conditions shows that the intensity of the narrow component is closely correlated with the purity and the perfection of the crystal where p-Ps is presumably formed as suggested by magnetic experiments. (author) [fr

  17. Synchrotron light techniques for the investigation of advanced nuclear reactor structural materials

    International Nuclear Information System (INIS)

    Pouchon, M.A.; Froideval, A.; Degueldre, C.; Gavillet, D.; Hoffelner, W.

    2008-01-01

    In the frame of the Generation IV initiative, different structural material candidates are investigated at the Paul Scherrer Institute. These are oxide dispersion strengthened (ODS) steels, intermetallic materials and ceramic composite materials. The response of the material to different potential loads (irradiation, temperature...) is addressed in a multi-scale approach, both, modelling wise and also experimentally. The investigation of each scale delivers at least a qualitative understanding of possibly evolving damage in the material and also delivers a validation of the corresponding scale on the modelling side. From the experimental side, the lower end of the scale, the atomistic and structural level, can be investigated by conventional techniques, as for example transmission electron microscopy (TEM) and X-ray diffraction (XRD). However, the use of synchrotron radiation techniques offers an ideal, complementary way to investigate the material structure and other properties. This paper presents applications in the field of the ODS research, where the structural behaviour of the nano-scopic dispersoids can selectively be investigated, although only being present with roughly 5 wt % in the matrix. A study showing the structural behaviour of these oxide particles as a function of irradiation illustrates the potential of the extended X-ray absorption fine structure (EXAFS) technique. Using X-ray magnetic circular dichroism (XMCD), which is a difference-signal of two X-ray absorption spectra recorded for positive and negative helicities of the beam, the magnetic structure and some magnetic parameters, can be resolved. An example shows, how this can be applied to understand (Fe,Cr) systems, which is the base alloy of the investigated ODS steel. The results deliver an important cross-check for modelling. Beside the presentation of these techniques, this paper shows how beamline techniques can serve nuclear research, with possibly activated materials. At the Paul

  18. Effects of aspirin on distortion product fine structure: interpreted by the two-source model for distortion product otoacoustic emissions generation.

    Science.gov (United States)

    Rao, Aparna; Long, Glenis R

    2011-02-01

    Distortion product otoacoustic emission (DPOAE) fine structure is due to the interaction of two major components coming from different places in the cochlea. One component is generated from the region of maximal overlap of the traveling waves generated by the two primaries and is attributed to nonlinear distortion (nonlinear component). The other component arises predominantly from the tonotopic region of the distortion product and is attributed to linear coherent reflection (reflection component). Aspirin (salicylate) ototoxicity can cause reversible hearing loss and reduces otoacoustic emission generation in the cochlea. The two components are expected to be affected differentially by cochlear health. Changes in DPOAE fine structure were recorded longitudinally in three subjects before, during, and after aspirin consumption. Full data sets were analyzed for two subjects, but only partial data could be analyzed from the third subject. Resulting changes in the two components of DPOAE fine structure revealed variability among subjects and differential effects on the two components. For low-intensity primaries, both components were reduced with the reflection component being more vulnerable. For high-intensity primaries, the nonlinear component showed little or no change, but the reflection component was always reduced.

  19. Time variation of the fine structure constant driven by quintessence

    International Nuclear Information System (INIS)

    Anchordoqui, Luis; Goldberg, Haim

    2003-01-01

    There are indications from the study of quasar absorption spectra that the fine structure constant α may have been measurably smaller for redshifts z>2. Analyses of other data ( 149 Sm fission rate for the Oklo natural reactor, variation of 187 Re β-decay rate in meteorite studies, atomic clock measurements) which probe variations of α in the more recent past imply much smaller deviations from its present value. In this work we tie the variation of α to the evolution of the quintessence field proposed by Albrecht and Skordis, and show that agreement with all these data, as well as consistency with Wilkinson Microwave Anisotropy Probe observations, can be achieved for a range of parameters. Some definite predictions follow for upcoming space missions searching for violations of the equivalence principle

  20. Fine-structure energy levels and radiative lifetime in Mo XIV

    International Nuclear Information System (INIS)

    Wang Xiaodong; Pei Dong; Jiang Renbin; Wang Wanjue

    2002-01-01

    Energy levels, radiative lifetime and various transition parameters for allowed transitions among the 1508 fine-structure levels belong to the (1s 2 2s 2 2p 6 3s 2 3p 6 ) 3d 10 4l, 3d 9 4l 2 , 3d 10 5l, 3d 9 4l4m, 3d 10 6l, 3d 10 7l and so on configurations of the Cu-like ions Mo XIV have been calculated by using the expanded fully relativistic GRASP code. The results are compared with those available in the literature, and the accuracy of the present data is assessed. Energy levels are expected to be accurate to within 0.81%. The authors have found some long lifetime levels

  1. New algorithm improves fine structure of the barley consensus SNP map

    Directory of Open Access Journals (Sweden)

    Endelman Jeffrey B

    2011-08-01

    Full Text Available Abstract Background The need to integrate information from multiple linkage maps is a long-standing problem in genetics. One way to visualize the complex ordinal relationships is with a directed graph, where each vertex in the graph is a bin of markers. When there are no ordering conflicts between the linkage maps, the result is a directed acyclic graph, or DAG, which can then be linearized to produce a consensus map. Results New algorithms for the simplification and linearization of consensus graphs have been implemented as a package for the R computing environment called DAGGER. The simplified consensus graphs produced by DAGGER exactly capture the ordinal relationships present in a series of linkage maps. Using either linear or quadratic programming, DAGGER generates a consensus map with minimum error relative to the linkage maps while remaining ordinally consistent with them. Both linearization methods produce consensus maps that are compressed relative to the mean of the linkage maps. After rescaling, however, the consensus maps had higher accuracy (and higher marker density than the individual linkage maps in genetic simulations. When applied to four barley linkage maps genotyped at nearly 3000 SNP markers, DAGGER produced a consensus map with improved fine structure compared to the existing barley consensus SNP map. The root-mean-squared error between the linkage maps and the DAGGER map was 0.82 cM per marker interval compared to 2.28 cM for the existing consensus map. Examination of the barley hardness locus at the 5HS telomere, for which there is a physical map, confirmed that the DAGGER output was more accurate for fine structure analysis. Conclusions The R package DAGGER is an effective, freely available resource for integrating the information from a set of consistent linkage maps.

  2. The Charge-Mass-Spin Relation of Clifford Polyparticles, Kerr-Newman Black Holes and the Fine Structure Constant

    CERN Document Server

    Castro, C

    2003-01-01

    A Clifford-algebraic interpretation is proposed of the charge, mass, spin relationship found recently by Cooperstock and Faraoini which was based on the Kerr-Newman metric solutions of the Einstein-Maxwell equations. The components of the polymomentum associated with a Clifford polyparticle in four dimensions provide for such a charge, mass, spin relationship without the problems encountered in Kaluza-Klein compactifications which furnish an unphysically large value for the electron charge. A physical reasoning behind such charge, mass, spin relationship is provided, followed by a discussion on the geometrical derivation of the fine structure constant by Wyler, Smith, Gonzalez-Martin and Smilga. To finalize, the renormalization of electric charge is discussed and some remarks are made pertaining the modifications of the charge-scale relationship, when the spin of the polyparticle changes with scale, that may cast some light into the alleged Astrophysical variations of the fine structure constant.

  3. Polarization-dependent pump-probe studies in atomic fine-structure levels: towards the production of spin-polarized electrons

    International Nuclear Information System (INIS)

    Sokell, E.; Zamith, S.; Bouchene, M.A.; Girard, B.

    2000-01-01

    The precession of orbital and spin angular momentum vectors has been observed in a pump-probe study of the 4P fine-structure states of atomic potassium. A femtosecond pump pulse prepared a coherent superposition of the two fine-structure components. A time-delayed probe pulse then ionized the system after it had been allowed to evolve freely. Oscillations recorded in the ion signal reflect the evolution of the orientation of the orbital and spin angular momentum due to spin-orbit coupling. This interpretation gives physical insight into the cause of the half-period phase shift observed when the relative polarizations of the laser pulses were changed from parallel to perpendicular. Finally, it is shown that these changes in the orientation of the spin momentum vector of the system can be utilized to produce highly spin-polarized free electrons on the femtosecond scale. (author)

  4. Use of Unprocessed Coal Bottom Ash as Partial Fine Aggregate ...

    African Journals Online (AJOL)

    2012r

    transportation applications such as structural fill, road base material, and as snow ... normal fine particles resulting in weak porous paste, modulus of elasticity is ..... with the porous structure and high absorptivity of fine particles of bottom ash.

  5. Development of solar flares and features of the fine structure of solar radio emission

    Science.gov (United States)

    Chernov, G. P.; Fomichev, V. V.; Yan, Y.; Tan, B.; Tan, Ch.; Fu, Q.

    2017-11-01

    The reason for the occurrence of different elements of the fine structure of solar radio bursts in the decimeter and centimeter wavelength ranges has been determined based on all available data from terrestrial and satellite observations. In some phenomena, fast pulsations, a zebra structre, fiber bursts, and spikes have been observed almost simultaneously. Two phenomena have been selected to show that the pulsations of radio emission are caused by particles accelerated in the magnetic reconnection region and that the zebra structure is excited in a source, such as a magnetic trap for fast particles. The complex combination of unusual fiber bursts, zebra structure, and spikes in the phenomenon on December 1, 2004, is associated with a single source, a magnetic island formed after a coronal mass ejection.

  6. Fine structure and optical pumping of spins in individual semiconductor quantum dots

    Science.gov (United States)

    Bracker, Allan S.; Gammon, Daniel; Korenev, Vladimir L.

    2008-11-01

    We review spin properties of semiconductor quantum dots and their effect on optical spectra. Photoluminescence and other types of spectroscopy are used to probe neutral and charged excitons in individual quantum dots with high spectral and spatial resolution. Spectral fine structure and polarization reveal how quantum dot spins interact with each other and with their environment. By taking advantage of the selectivity of optical selection rules and spin relaxation, optical spin pumping of the ground state electron and nuclear spins is achieved. Through such mechanisms, light can be used to process spins for use as a carrier of information.

  7. Fine structure and optical pumping of spins in individual semiconductor quantum dots

    International Nuclear Information System (INIS)

    Bracker, Allan S; Gammon, Daniel; Korenev, Vladimir L

    2008-01-01

    We review spin properties of semiconductor quantum dots and their effect on optical spectra. Photoluminescence and other types of spectroscopy are used to probe neutral and charged excitons in individual quantum dots with high spectral and spatial resolution. Spectral fine structure and polarization reveal how quantum dot spins interact with each other and with their environment. By taking advantage of the selectivity of optical selection rules and spin relaxation, optical spin pumping of the ground state electron and nuclear spins is achieved. Through such mechanisms, light can be used to process spins for use as a carrier of information

  8. Search for shape coexistence in {sup 188,190}Pb via fine structure in the alpha decay of {sup 192,194}Po

    Energy Technology Data Exchange (ETDEWEB)

    Ahmad, I.; Davids, C.; Janssens, R.V.F. [and others

    1995-08-01

    The interaction between coexisting shapes in nuclei near closed shells was of great interest in the past decade. Excited 0{sup +} states at low energy can often be identified as the bandheads of structures with differing shapes built on those states, These structures were identified in {sup 190-198}Pb via beta decay and alpha decay {open_quotes}fine structure{close_quotes} studies. Coexistence of different shapes in Pb nuclei was predicted by Nilsson-Strutinsky calculations, in which both the oblate and prolate minima were predicted to have excitation energies near 1 MeV. It was our intention to continue the systematic study of the Pb nuclides by searching for excited O{sup +} states in {sup 188}Pb by observing the fine structure in the alpha decay of {sup 192}Po.

  9. Stabilization of high-temperature antimony oxide with molybdenum incorporation. Structure of Mo-doped Sb2O4 by powder neutron diffraction and extended X-ray absorption fine structure spectroscopy

    International Nuclear Information System (INIS)

    Teller, R.G.; Antonio, M.R.; Brazdil, J.F.; Mehicic, M.; Grasselli, R.K.

    1985-01-01

    It has been discovered that the presence of MoO 3 lowers the α-β transition in Sb 2 O 4 from 935 to 850 0 C with concurrent dissolution of Mo in the high-temperature (β) form. The structure of Mo-doped β-Sb 2 O 4 has been investigated by powder neutron diffraction, extended X-ray absorption fine structure (EXAFS) and Raman spectroscopies, and scanning-electron microscopy (SEM). Cell parameters: a = 12.0571 (12) A, b = 4.8335 (1) A, c = 5.3838 (6) A, β = 105.579 (5) 0 , monoclinic, space group C2/c, Z = 4. Combining the results of these techniques leads to the hypothesis that Mo is located interstitially within channels of electron density in the Sb 2 O 4 structure with concurrent vacancy of two Sb/sup III/ atoms. There is no apparent oxygen deficiency in the resulting structure. 25 references, 6 figures, 3 tables

  10. 5 K extended X-ray absorption fine structure and 40 K 10-s resolved extended X-ray absorption fine structure studies of photolyzed carboxymyoglobin

    International Nuclear Information System (INIS)

    Teng, T.Y.; Huang, H.W.; Olah, G.A.

    1987-01-01

    A previous extended X-ray absorption fine structure (EXAFS) study of photolyzed carboxymyoglobin (MbCO) has provoked much discussion on the heme structure of the photoproduct (Mb*CO). The EXAFS interpretation that the Fe-Co distance increases by no more than 0.05 A following photodissociation has been regarded as inconsistent with optical, infrared, and magnetic susceptibility studies. The present experiment was performed with well-characterized dry film samples in which MbCO molecules were embedded in a poly(vinyl alcohol) matrix. The sample had a high protein concentration (12 mM) to yield adequate EXAFS signals but was very thin (40 μm) so that complete photolysis could be easily achieved by a single flash from a xenon lamp. Although the electronic state of Mb*CO resembles that of deoxymyoglobin (deoxy-Mb), direct comparison of EXAFS spectra indicates that structurally Mb*CO is much closer to MbCO than to deoxy-Mb. Our EXAFS analysis shows that photolysis of MbCO at 5 K leads to a stable intermediate state in which CO has moved away from iron by a distance of 0.27-0.45 A, but the 5-coordinate heme structure is strained in a form similar to that of MbCO; the resolution of the CO position depends on the structure parameters of MbCO which we use as a reference for the analysis of Mb*CO. At 40 K, from 1 to 10 s after photolysis, 42% of the photoproduct has relaxed to the ground state, and the EXAFS spectrum of the remaining photoproduct is indistinguishable from that of the 5 K photoproduct

  11. Solvation structure determination of nickel(II) ion in six nitriles using extended X-ray absorption fine structure spectroscopy

    International Nuclear Information System (INIS)

    Inada, Yasuhiro; Funahashi, Shigenobu

    1997-01-01

    The solvation structures of the nickel(II) ion in six nitriles have been determined using X-ray absorption fine structure spectroscopy. The coordination number and the Ni-N bond length are 6 and 206.9 ± 0.6 pm in acetonitrile, 5.9 ± 0.2 and 206.9 ± 0.6 pm in propionitrile, 6.0 ± 0.2 and 206.8 ± 0.6 pm in butyronitrile, 6.0 ± 0.2 and 206.8 ± 0.6 pm in isobutyronitrile, 6.0 ± 0.2 and 206.8 ± 0.6 pm in valeronitrile, and 6.0 ± 0.2 and 206.5 ± 0.7 pm in benzonitrile, respectively. The structure parameters around the nickel(II) ion in all the nitriles are not affected by the bulkiness of the nitrile molecules. On the basis of the obtained structure parameters, we have discussed the structural characteristics around the nickel(II) ion with nitrogen and oxygen donor solvents and the reaction mechanisms for nitrile exchange on the nickel(II) ion. (author)

  12. Constraining spatial variations of the fine-structure constant in symmetron models

    Directory of Open Access Journals (Sweden)

    A.M.M. Pinho

    2017-06-01

    Full Text Available We introduce a methodology to test models with spatial variations of the fine-structure constant α, based on the calculation of the angular power spectrum of these measurements. This methodology enables comparisons of observations and theoretical models through their predictions on the statistics of the α variation. Here we apply it to the case of symmetron models. We find no indications of deviations from the standard behavior, with current data providing an upper limit to the strength of the symmetron coupling to gravity (log⁡β2<−0.9 when this is the only free parameter, and not able to constrain the model when also the symmetry breaking scale factor aSSB is free to vary.

  13. Damping Properties vs. Structure Fineness of the High-zinc Aluminum Alloys

    Directory of Open Access Journals (Sweden)

    W.K. Krajewski

    2012-09-01

    Full Text Available The subject of this study is the presentation of relation between the degree of structure fineness and ultrasonic wave dampingcoefficient for the high-zinc aluminium alloys represented in this study by the sand mould cast alloy Al - 20 wt% Zn (AlZn20. Thestudied alloy was refined with a modifying (Al,Zn-Ti3 ternary master alloy, introducing Ti in the amount of 400 pm into metal. Based on the analysis of the initial and modified alloy macrostructure images and ultrasonic testing, it was found that the addition of (Al,Zn-Ti3 master alloy, alongside a significant fragmentation of grains, does not reduce the coefficient of ultrasonic waves with a frequency of 1 MHz.

  14. Coupling Fine-Scale Root and Canopy Structure Using Ground-Based Remote Sensing

    Directory of Open Access Journals (Sweden)

    Brady S. Hardiman

    2017-02-01

    Full Text Available Ecosystem physical structure, defined by the quantity and spatial distribution of biomass, influences a range of ecosystem functions. Remote sensing tools permit the non-destructive characterization of canopy and root features, potentially providing opportunities to link above- and belowground structure at fine spatial resolution in functionally meaningful ways. To test this possibility, we employed ground-based portable canopy LiDAR (PCL and ground penetrating radar (GPR along co-located transects in forested sites spanning multiple stages of ecosystem development and, consequently, of structural complexity. We examined canopy and root structural data for coherence (i.e., correlation in the frequency of spatial variation at multiple spatial scales ≤10 m within each site using wavelet analysis. Forest sites varied substantially in vertical canopy and root structure, with leaf area index and root mass more becoming even vertically as forests aged. In all sites, above- and belowground structure, characterized as mean maximum canopy height and root mass, exhibited significant coherence at a scale of 3.5–4 m, and results suggest that the scale of coherence may increase with stand age. Our findings demonstrate that canopy and root structure are linked at characteristic spatial scales, which provides the basis to optimize scales of observation. Our study highlights the potential, and limitations, for fusing LiDAR and radar technologies to quantitatively couple above- and belowground ecosystem structure.

  15. Regulation of the demographic structure in isomorphic biphasic life cycles at the spatial fine scale.

    Directory of Open Access Journals (Sweden)

    Vasco Manuel Nobre de Carvalho da Silva Vieira

    Full Text Available Isomorphic biphasic algal life cycles often occur in the environment at ploidy abundance ratios (Haploid:Diploid different from 1. Its spatial variability occurs within populations related to intertidal height and hydrodynamic stress, possibly reflecting the niche partitioning driven by their diverging adaptation to the environment argued necessary for their prevalence (evolutionary stability. Demographic models based in matrix algebra were developed to investigate which vital rates may efficiently generate an H:D variability at a fine spatial resolution. It was also taken into account time variation and type of life strategy. Ploidy dissimilarities in fecundity rates set an H:D spatial structure miss-fitting the ploidy fitness ratio. The same happened with ploidy dissimilarities in ramet growth whenever reproductive output dominated the population demography. Only through ploidy dissimilarities in looping rates (stasis, breakage and clonal growth did the life cycle respond to a spatially heterogeneous environment efficiently creating a niche partition. Marginal locations were more sensitive than central locations. Related results have been obtained experimentally and numerically for widely different life cycles from the plant and animal kingdoms. Spore dispersal smoothed the effects of ploidy dissimilarities in fertility and enhanced the effects of ploidy dissimilarities looping rates. Ploidy dissimilarities in spore dispersal could also create the necessary niche partition, both over the space and time dimensions, even in spatial homogeneous environments and without the need for conditional differentiation of the ramets. Fine scale spatial variability may be the key for the prevalence of isomorphic biphasic life cycles, which has been neglected so far.

  16. Measurement of the 22S1/2-22P3/2 fine structure interval in muonium

    International Nuclear Information System (INIS)

    Kettell, S.H.

    1990-08-01

    The (2 2 S 1/2 - 2 2 P 3/2 ) fine structure transition in muonium has been observed for the first time. The measured value is 9895 -30 +35 MHz. This measurement, when included with the theoretical value for the 2 2 P 1/2 - 2 2 P 3/2 fine structure interval, gives a value for the Lamb shift (2 2 S 1/2 - 2 2 P 1/2 ) independent of previous direct measurements. From the theoretical value for the fine structure interval, 10921.833(3) MHz, the value for the Lamb shift determined from this experiment is 1027 -35 +30 MHz and is in agreement with the prediction of quantum electrodynamics (QED) of 1047.5(3) MHz. Previous experimental values for the Lamb shift (2 2 S 1/2 -2 2 P 1/2 ) in muonium are 1070 -15 + 12 MHz and 1042 -23 +21 MHz. Combining this result with these previous results gives a new experimental value of 1058 -12 +10 for the Lamb shift in muonium. Muonium, the bound state of two structureless leptons (μ + e - ), is an ideal system for testing bound state QED because of the lack of hadronic structure as exists in the hydrogen system. The measurement makes use of the techniques of atomic beam microwave spectroscopy. Muonium atoms (μ + e - ) in the 2S states are produced by the beam-foil technique at the Clinton P. Anderson Meson Physics Facility with a low momentum, sub-surface muon beam. A variable frequency microwave field is applied to drive the atoms from the 2S to the 2P states, with the subsequent observation of the Lyman alpha photon from the decay of the 2P state to the 1S ground state. The frequency is varied from 9.0--11.0 GHz, driving the F = 0 → F = 1, F = 1, F = 1 and F = 1 → F = 2 transitions

  17. Fine-scale genetic structure and cryptic associations reveal evidence of kin-based sociality in the African forest elephant.

    Directory of Open Access Journals (Sweden)

    Stephanie G Schuttler

    Full Text Available Spatial patterns of relatedness within animal populations are important in the evolution of mating and social systems, and have the potential to reveal information on species that are difficult to observe in the wild. This study examines the fine-scale genetic structure and connectivity of groups within African forest elephants, Loxodonta cyclotis, which are often difficult to observe due to forest habitat. We tested the hypothesis that genetic similarity will decline with increasing geographic distance, as we expect kin to be in closer proximity, using spatial autocorrelation analyses and Tau K(r tests. Associations between individuals were investigated through a non-invasive genetic capture-recapture approach using network models, and were predicted to be more extensive than the small groups found in observational studies, similar to fission-fusion sociality found in African savanna (Loxodonta africana and Asian (Elephas maximus species. Dung samples were collected in Lopé National Park, Gabon in 2008 and 2010 and genotyped at 10 microsatellite loci, genetically sexed, and sequenced at the mitochondrial DNA control region. We conducted analyses on samples collected at three different temporal scales: a day, within six-day sampling sessions, and within each year. Spatial autocorrelation and Tau K(r tests revealed genetic structure, but results were weak and inconsistent between sampling sessions. Positive spatial autocorrelation was found in distance classes of 0-5 km, and was strongest for the single day session. Despite weak genetic structure, individuals within groups were significantly more related to each other than to individuals between groups. Social networks revealed some components to have large, extensive groups of up to 22 individuals, and most groups were composed of individuals of the same matriline. Although fine-scale population genetic structure was weak, forest elephants are typically found in groups consisting of kin and

  18. Visualization of Wave Propagation and Fine Structure in Frictional Motion of Unconstrained Soft Microstructured Tapes

    DEFF Research Database (Denmark)

    Heepe, Lars; Filippov, Alexander E.; Kovalev, Alexander E.

    2017-01-01

    from previous friction tests of microstructured elastomers fixed onto a rigid support, allowing only for shear deformations of surface microstructures and the backing layer, but not for stretching of the entire sample. Three different types of microstructured tapes were tested and their frictional...... behavior compared to results from numerical simulations. In both experimental and numerical cases, visualization of wave propagation and fine structure in friction is obtained....

  19. WAVELENGTH ACCURACY OF THE KECK HIRES SPECTROGRAPH AND MEASURING CHANGES IN THE FINE STRUCTURE CONSTANT

    International Nuclear Information System (INIS)

    Griest, Kim; Whitmore, Jonathan B.; Wolfe, Arthur M.; Prochaska, J. Xavier; Howk, J. Christopher; Marcy, Geoffrey W.

    2010-01-01

    We report on an attempt to accurately wavelength calibrate four nights of data taken with the Keck HIRES spectrograph on QSO PHL957, for the purpose of determining whether the fine structure constant was different in the past. Using new software and techniques, we measured the redshifts of various Ni II, Fe II, Si II, etc. lines in a damped Lyα system at z = 2.309. Roughly half the data were taken through the Keck iodine cell which contains thousands of well calibrated iodine lines. Using these iodine exposures to calibrate the normal Th-Ar Keck data pipeline output, we found absolute wavelength offsets of 500 m s -1 to 1000 m s -1 with drifts of more than 500 m s -1 over a single night, and drifts of nearly 2000 m s -1 over several nights. These offsets correspond to an absolute redshift of uncertainty of about Δz ∼ 10 -5 (Δλ ∼ 0.02 A), with daily drifts of around Δz ∼ 5 x 10 -6 (Δλ ∼ 0.01 A), and multiday drifts of nearly Δz ∼ 2 x 10 -5 (∼0.04 A). The causes of the wavelength offsets are not known, but since claimed shifts in the fine structure constant would result in velocity shifts of less than 100 m s -1 , this level of systematic uncertainty may make it difficult to use Keck HIRES data to constrain the change in the fine structure constant. Using our calibrated data, we applied both our own fitting software and standard fitting software to measure Δα/α, but discovered that we could obtain results ranging from significant detection of either sign, to strong null limits, depending upon which sets of lines and which fitting method were used. We thus speculate that the discrepant results on Δα/α reported in the literature may be due to random fluctuations coming from underestimated systematic errors in wavelength calibration and fitting procedure.

  20. On the fine structure of the Vavilov-Cherenkov radiation

    International Nuclear Information System (INIS)

    Afanas'ev, G.N.; Kartavenko, V.G.; Zrelov, V.P.

    2003-01-01

    The aim of this paper is to study the fine structure of the Cherenkov rings. We analyze Zrelov's experiments in which the Cherenkov radiation was detected without using the special focusing devices. The broad Cherenkov ring was observed in the plane perpendicular to the motion axis. Using the exact and approximate formulae, we investigate how a charge uniformly moving in a medium radiates in a finite space interval. The formulae obtained describe the radiation intensity in the whole space interval, inside and outside the Cherenkov ring. In the plane perpendicular to the motion axis, the radiation fills mainly the finite ring. Its width, proportional to the motion interval, and the energy released in this ring do not depend on the position of the observation plane. Outside the Cherenkov ring, the radiation intensity suddenly drops. Inside it, the radiation intensity exhibits small oscillations which are due to the interference of the Vavilov-Cherenkov radiation and bremsstrahlung. The increase in the radiation intensity at the ends of the Cherenkov ring is associated with the shock waves arising at the beginning and the end of the charge motion and at the moments when the charge velocity coincides with the light velocity in a medium. For the chosen motion interval, the well-known Tamm formula does not describe the radiation intensity inside the Cherenkov ring for any position of the observation plane. Outside the Cherenkov ring, the Tamm formula is valid only at very large observation distances. Theoretical calculations are in satisfactory agreement with experimental data. Thus, the combined experimental and theoretical study of the unfocused Cherenkov rings allows one to obtain information on the physical processes accompanying the Cherenkov radiation (bremsstrahlung, transition of the light velocity barrier, etc.)

  1. Microwave spectroscopy of the 1 s n p P3J fine structure of high Rydberg states in 4He

    Science.gov (United States)

    Deller, A.; Hogan, S. D.

    2018-01-01

    The 1 s n p P3J fine structure of high Rydberg states in helium has been measured by microwave spectroscopy of single-photon transitions from 1 s n s S31 levels in pulsed supersonic beams. For states with principal quantum numbers in the range from n =34 to 36, the J =0 →2 and J =1 →2 fine structure intervals were both observed. For values of n between 45 and 51 only the larger J =0 →2 interval was resolved. The experimental results are in good agreement with theoretical predictions. Detailed characterization of residual uncanceled electric and magnetic fields in the experimental apparatus and calculations of the Stark and Zeeman structures of the Rydberg states in weak fields were used to quantify systematic contributions to the uncertainties in the measurements.

  2. A correlational method to concurrently measure envelope and temporal fine structure weights: effects of age, cochlear pathology, and spectral shaping.

    Science.gov (United States)

    Fogerty, Daniel; Humes, Larry E

    2012-09-01

    The speech signal may be divided into spectral frequency-bands, each band containing temporal properties of the envelope and fine structure. This study measured the perceptual weights for the envelope and fine structure in each of three frequency bands for sentence materials in young normal-hearing listeners, older normal-hearing listeners, aided older hearing-impaired listeners, and spectrally matched young normal-hearing listeners. The availability of each acoustic property was independently varied through noisy signal extraction. Thus, the full speech stimulus was presented with noise used to mask six different auditory channels. Perceptual weights were determined by correlating a listener's performance with the signal-to-noise ratio of each acoustic property on a trial-by-trial basis. Results demonstrate that temporal fine structure perceptual weights remain stable across the four listener groups. However, a different weighting typography was observed across the listener groups for envelope cues. Results suggest that spectral shaping used to preserve the audibility of the speech stimulus may alter the allocation of perceptual resources. The relative perceptual weighting of envelope cues may also change with age. Concurrent testing of sentences repeated once on a previous day demonstrated that weighting strategies for all listener groups can change, suggesting an initial stabilization period or susceptibility to auditory training.

  3. Studies on the visualization of the fine relief of the colon

    International Nuclear Information System (INIS)

    Persigehl, M.; Niemann, G.; Klose, K.C.

    1983-01-01

    The possibility of visualizing the fine relief of the colon was examined by studying human intestinal segments removed post mortem. The visualization depends, among other things, on the extent of expansion of the colon wall. The visualization of the fine relief structure becomes progressively poorer, the greater the extension of the wall. This might indicate that fold formation of the mucosa through a state of contraction of the tunica mucosa is done of the responsible factors for the visualization of the fine relief structures. The article discusses, apart from this factor, the course of the vessels as an anatomical basic pattern determining the manifestation of the fine relief structure; for this purpose, the course of the vessels in the intestine of the dog was visualized by intra-arterial contrast medium injection and then compared with the human fine relief. (orig.) [de

  4. Polarizability of Kr6+ from high-L Kr5+ fine-structure measurements

    International Nuclear Information System (INIS)

    Lundeen, S. R.; Fehrenbach, C. W.

    2007-01-01

    The transition between n=55 and n=109 Rydberg levels of Kr 5+ has been studied at high resolution using the resonant excitation stark ionization spectroscopy method. Resolved excitation of L=6, 7, 8, and 9 levels in n=55 lead to a determination of the fine-structure energies of these levels. Interpreted with the long-range polarization model, this leads to a measurement of the dipole polarizabilities of Zn-like Kr 6+ , α d =2.69(4)a 0 3 . Obtaining a value of the quadrupole polarizability from the data will require additional theoretical input. Factors contributing to the signal and noise levels in measurements of this type are discussed

  5. Local Structure of Mn in (La1-xHox)2/3Ca1/3MnO3 Studied by X-ray Absorption Fine Structure

    International Nuclear Information System (INIS)

    Pietnoczka, A.; Bacewicz, R.; Antonowicz, J.; Zalewski, W.; Pekala, M.; Drozd, V.; Fagnard, J.F.; Vanderbemden, P.

    2010-01-01

    Results of X-ray absorption fine structure measurements in manganites (La 1-x Ho x ) 2/3 Ca 1/3 MnO 3 with 0.15 3 is doped with a divalent element such as Ca 2+ , substituting for La 3+ , holes are induced in the filled Mn d orbitals. This leads to a strong ferromagnetic coupling between Mn sites. Ca ions in La 1-x Ca x MnO 3 introduce a distortion of the crystal lattice and mixed valence Mn ions (Mn 3+ and Mn 4+ ). On the other hand, in manganites (La 1-x Ho x ) 2/3 Ca 1/3 MnO 3 the substitution of La for Ho causes a lattice distortion and induces a disorder, which reduces a magnetic interaction. The ferromagnetic transition temperature and conductivity decrease very quickly with increasing x. The magnetic and transport properties of compounds depend on the local atomic structure around Mn ions. The information on the bond lengths and Debye-Waller factor are obtained from the extended X-ray absorption fine structure (EXAFS) data analysis. The charge state of Mn is determined from the position of the absorption edge in X-ray absorption near edge structure (XANES) data. XAFS results are in good agreement with magnetic characteristics of the studied materials. (authors)

  6. Measurement of the electron affinity of As and the fine structure of As- using infrared threshold photodetachment spectroscopy

    International Nuclear Information System (INIS)

    Walter, C W; Gibson, N D; Field, R L III; Snedden, A P; Shapiro, J Z; Janczak, C M; Hanstorp, D

    2009-01-01

    The negative ion As - has been investigated using infrared threshold photodetachment spectroscopy. The relative cross section for neutral atom production was measured with a crossed OPO-ion beam apparatus over selected photon energy ranges between 0.63 - 0.82 eV. s-wave thresholds were observed for detachment from As - (4p 4 3 P 0,1,2 ) to the As (4p 3 4 S 3/2 ) ground state. The measurements yield preliminary values for the electron affinity of As (0.8048(2)) eV) and the fine structure intervals of As - (0.1276(2) eV for 3 P 1 - 3 P 2 and 0.1643(10) eV for 3 P 0 - 3 P 2 ). The present results substantially reduce the uncertainties in these quantities.

  7. [Study on the fine structure of K-feldspar of Qichun granite].

    Science.gov (United States)

    Du, Deng-Wen; Hong, Han-Lie; Fan, Kan; Wang, Chao-Wen; Yin, Ke

    2013-03-01

    Fine structure of K-feldspar from the Qichun granite was investigated using X-ray diffraction (XRD), Fourier infrared absorption spectroscopy (FTIR), and inductively coupled plasma mass spectrometry methods to understand the evolution of the granitic magmatism and its correlation to molybdenite mineralization. The XRD results showed that K-feldspar of the potassic alteration veins has higher ordering index and triclinicity and is namely microcline with triclinic symmetry. K-feldspar of the early cretaceous granite has relatively lower ordering index and has widening [131] peak and is locally triclinic ordering. K-feldspar of the late cretaceous granite has lowest ordering index and sharp [131] peak and is honiogeneously monoclinic. The FTIR results showed that the IR spectra of the Qichun K-feldspar are similar to that of orthoclase reported by Farmer (1974). The 640 cm-1 absorption band increases while the 540 cm-' absorption band decreases with increase in K-feldspar ordering index, also, the 1,010 cm-1 absorption band separates into 1,010 and 1,046 cm-1 absorption bands, with a change in the band shape from widening to sharp outline. The ICP-MS results suggested that K-feldspar of the early cretaceous granite has relatively higher metal elements and rare earth elements, and the granite exhibits better mineralization background, K-feldspar of the potassic alteration veins has markedly lower Sr and Ba, indicating that the alteration fluid originated from the granitic magmatism, and hence, potassic alteration is a good indicator for molybdenite exploration.

  8. Sulfur X-ray absorption fine structure in porous Li–S cathode films measured under argon atmospheric conditions

    International Nuclear Information System (INIS)

    Müller, Matthias; Choudhury, Soumyadip; Gruber, Katharina; Cruz, Valene B.; Fuchsbichler, Bernd; Jacob, Timo; Koller, Stefan; Stamm, Manfred; Ionov, Leonid; Beckhoff, Burkhard

    2014-01-01

    In this paper we present the first results for the characterization of highly porous cathode materials with pore sizes below 1 μm for Lithium Sulfur (Li–S) batteries by Near Edge X-ray Absorption Fine Structure (NEXAFS) spectroscopy. A novel cathode material of porous carbon films fabricated with colloidal array templates has been investigated. In addition, an electrochemical characterization has been performed aiming on an improved correlation of physical and chemical parameters with the electrochemical performance. The performed NEXAFS measurements of cathode materials allowed for a chemical speciation of the sulfur content inside the cathode material. The aim of the presented investigation was to evaluate the potential of the NEXAFS technique to characterize sulfur in novel battery material. The long term goal for the characterization of the battery materials is the sensitive identification of undesired side reactions, such as the polysulfide shuttle, which takes place during charging and discharging of the battery. The main drawback associated with the investigation of these materials is the fact that NEXAFS measurements can usually only be performed ex situ due to the limited in situ instrumentation being available. For Li–S batteries this problem is more pronounced because of the low photon energies needed to study the sulfur K absorption edge at 2472 eV. We employed 1 μm thick Si 3 N 4 windows to construct sealed argon cells for NEXAFS measurements under ultra high vacuum (UHV) conditions as a first step towards in situ measurements. The cells keep the sample under argon atmosphere at any time and the X-ray beam passes mainly through vacuum which enables the detection of the low energy X-ray emission of sulfur. Using these argon cells we found indications for the presence of lithium polysulfides in the cathode films whereas the correlations to the offline electrochemical results remain somewhat ambiguous. As a consequence of these findings one may

  9. The fine structure of human germ layers in vivo: clues to the early differentiation of embryonic stem cells in vitro.

    Science.gov (United States)

    Sathananthan, Henry; Selvaraj, Kamala; Clark, Joan

    2011-08-01

    The fine structure of the three germ layers in human ectopic embryos (stage 7) have been documented by digital light and electron microscopy. The formation of ectoderm, endoderm and mesoderm and notochordal cells, and also the extraembryonic membranes, amnion and yolk sac, are imaged. The germ layers give rise to all the cells and tissues of the human body. Possible clues to the early differentiation of embryonic stem cells (ESC) in vitro were obtained, since these events are more or less mimicked in cultures of ESC derived from the inner cell mass of human blastocysts. The findings are discussed with reference to previous studies on the fine structure of ESC using the same technique. Copyright © 2011. Published by Elsevier Ltd.

  10. Standard model and fine structure constant at Planck distances in the Bennett-Brene-Nielsen-Picek random dynamics

    International Nuclear Information System (INIS)

    Laperashvili, L.V.

    1994-01-01

    The first part of the present paper contains a review of papers by Nielsen, Bennett, Brene and Picek which underly the model called random dynamics. The second part of the paper is devoted to calculating the fine structure constant by means of the path integration in the U(1)-lattice gauge theory

  11. Pyrimidine and halogenated pyrimidines near edge x-ray absorption fine structure spectra at C and N K-edges: experiment and theory

    International Nuclear Information System (INIS)

    Bolognesi, P.; O'Keeffe, P.; Ovcharenko, Y.; Coreno, M.; Avaldi, L.; Feyer, V.; Plekan, O.; Prince, K. C.; Zhang, W.; Carravetta, V.

    2010-01-01

    The inner shell excitation of pyrimidine and some halogenated pyrimidines near the C and N K-edges has been investigated experimentally by near edge x-ray absorption fine structure spectroscopy and theoretically by density functional theory calculations. The selected targets, 5-Br-pyrimidine, 2-Br-pyrimidine, 2-Cl-pyrimidine, and 5-Br-2-Cl-pyrimidine, allow the effects of the functionalization of the pyrimidine ring to be studied either as a function of different halogen atoms bound to the same molecular site or as a function of the same halogen atom bound to different molecular sites. The results show that the individual characteristics of the different spectra of the substituted pyrimidines can be rationalized in terms of variations in electronic and geometrical structures of the molecule depending on the localization and the electronegativity of the substituent.

  12. Surface geometry of BaO on W(100): A surface-extended x-ray-absorption fine-structure study

    International Nuclear Information System (INIS)

    Shih, A.; Hor, C.; Elam, W.; Kirkland, J.; Mueller, D.

    1991-01-01

    A surface-extended x-ray-absorption fine-structure study of ordered monolayers of coadsorbed barium and oxygen on a single-crystal W(100) surface is described. A (√2 x √2 )R45 degree structure with a stoichiometric barium-to-oxygen ratio, and a (2 √2 x √2 )R45 degree structure with a nearly 1:2 barium-to-oxygen atomic ratio both form on W(100). The surface-extended x-ray-absorption fine-structure results indicate that all the barium and oxygen atoms are nearly coplanar in the (√2 x √2 )R45 degree overlayer. The Ba-to-O distance in this overlayer is 3.20 ±0.05 A and β=82 degree ±5 degree, where β is the angle between the Ba-O internuclear axis and the surface normal. For the (2 √2 x √2 )R45 degree overlayer, there are two types of oxygen sites. Oxygen atoms nearly coplanar with the barium atoms are also present in these films with a Ba-to-O distance of 3.27±0.05 A and β=75±4 degree. Additional oxygen atoms lie outside the barium plane at a distance 2.03±0.05 A and β=23±10 degree from the nearest barium atoms

  13. DNA analysis of soil extracts can be used to investigate fine root depth distribution of trees

    Science.gov (United States)

    Bithell, Sean L.; Tran-Nguyen, Lucy T. T.; Hearnden, Mark N.; Hartley, Diana M.

    2015-01-01

    Understanding the root distribution of trees by soil coring is time-consuming as it requires the separation of roots from soil and classification of roots into particular size classes. This labour-intensive process can limit sample throughput and therefore sampling intensity. We investigated the use of quantitative polymerase chain reaction (qPCR) on soil DNA extractions to determine live fine root DNA density (RDD, mg DNA m−2) for mango (Mangifera indica) trees. The specificity of the qPCR was tested against DNA extracted from 10 mango cultivars and 14 weed species. All mango cultivars and no weeds were detected. Mango DNA was successfully quantified from control soil spiked with mango roots and weed species. The DNA yield of mango root sections stored in moist soil at 23–28 °C declined after 15 days to low concentrations as roots decayed, indicating that dead root materials in moist soil would not cause false-positive results. To separate large roots from samples, a root separation method for field samples was used to target the root fragments remaining in sieved (minimum 2 mm aperture) soil for RDD comparisons. Using this method we compared the seasonal RDD values of fine roots for five mango rootstock cultivars in a field trial. The mean cultivar DNA yields by depth from root fragments in the sieved soil samples had the strongest relationship (adjusted multiple R2 = 0.9307, P < 0.001) with the dry matter (g m−2) of fine (diameter <0.64 mm) roots removed from the soil by sieving. This method provides a species-specific and rapid means of comparing the distribution and concentration of live fine roots of trees in orchards using soil samples up to 500 g. PMID:25552675

  14. Astronomical constraints on the cosmic evolution of the fine structure constant and possible quantum dimensions.

    Science.gov (United States)

    Carilli, C L; Menten, K M; Stocke, J T; Perlman, E; Vermeulen, R; Briggs, F; de Bruyn , A G; Conway, J; Moore, C P

    2000-12-25

    We present measurements of absorption by the 21 cm hyperfine transition of neutral hydrogen toward radio sources at substantial look-back times. These data are used in combination with observations of rotational transitions of common interstellar molecules to set limits on the evolution of the fine structure constant: alpha/ alphatheory, the limit on the secular evolution of the scale factor of the compact dimensions, R, is &Rdot/ Rbig bang, of DeltaR /R<10(-5).

  15. Sensitivity of ultracold-atom scattering experiments to variation of the fine-structure constant

    International Nuclear Information System (INIS)

    Borschevsky, A.; Beloy, K.; Flambaum, V. V.; Schwerdtfeger, P.

    2011-01-01

    We present numerical calculations for cesium and mercury to estimate the sensitivity of the scattering length to the variation of the fine-structure constant α. The method used follows the ideas of Chin and Flambaum [Phys. Rev. Lett. 96, 230801 (2006)], where the sensitivity to the variation of the electron-to-proton mass ratio β was considered. We demonstrate that for heavy systems, the sensitivity to the variation of α is of the same order of magnitude as to the variation of β. Near narrow Feshbach resonances, the enhancement of the sensitivity may exceed nine orders of magnitude.

  16. Grazing incidence diffraction anomalous fine structure of self-assembled semiconductor nanostructures

    International Nuclear Information System (INIS)

    Grenier, S.; Letoublon, A.; Proietti, M.G.; Renevier, H.; Gonzalez, L.; Garcia, J.M.; Priester, C.; Garcia, J.

    2003-01-01

    We have studied self-organized quantum wires of InAs, grown by molecular beam epitaxy onto a InP(0 0 1) substrate, by means of grazing incidence diffraction anomalous fine structure (DAFS). The equivalent quantum wires thickness is 2.5 monolayers. We measured the (4 4 0) and (4 2 0) GIDAFS spectra, at the As K-edge, keeping the incidence and exit angles close to the InP critical angle. The analysis of both the smooth and oscillatory contributions of the DAFS spectrum, provide valuable information about composition and strain inside the quantum wires and close to the interface. We also show preliminary results on InAs wires encapsulated by a 40 A thick InP capping layer, suggesting the DAFS capability of probing different iso-strain regions of the wires

  17. Outlier SNP markers reveal fine-scale genetic structuring across European hake populations (Merluccius merluccius)

    DEFF Research Database (Denmark)

    Milano, I.; Babbucci, M.; Cariani, A.

    2014-01-01

    fishery. Analysis of 850 individuals from 19 locations across the entire distribution range showed evidence for several outlier loci, with significantly higher resolving power. While 299 putatively neutral SNPs confirmed the genetic break between basins (FCT = 0.016) and weak differentiation within basins...... even when neutral markers provide genetic homogeneity across populations. Here, 381 SNPs located in transcribed regions were used to assess largeand fine-scale population structure in the European hake (Merluccius merluccius), a widely distributed demersal species of high priority for the European...

  18. Direct Observation of the M1 Transition between the Ground Term Fine Structure Levels of W VIII

    Directory of Open Access Journals (Sweden)

    Momoe Mita

    2017-03-01

    Full Text Available We present a direct observation of the M1 transition between the fine structure splitting in the 4 f 13 5 s 2 5 p 6 2 F ground term of W VIII. The spectroscopic data of few-times ionized tungsten ions are important for the future ITER diagnostics, but there is a serious lack of data. The present study is part of an ongoing effort to solve this problem. Emission from the tungsten ions produced and trapped in a compact electron beam ion trap is observed with a Czerny–Turner visible spectrometer. Spectra in the EUV range are also observed at the same time to help identify the previously-unreported visible lines. The observed wavelength 574.47 ± 0.03 nm (air, which corresponds to the fine structure splitting of 17,402.5 ± 0.9 cm − 1 , shows reasonable agreement with the previously reported value 17,410 ± 5 cm − 1 obtained indirectly through the analysis of EUV spectra [Ryabtsev et al., Atoms 3 (2015 273].

  19. Synchrotron x-ray fluorescence and extended x-ray absorption fine structure analysis

    International Nuclear Information System (INIS)

    Chen, J.R.; Gordon, B.M.; Hanson, A.L.; Jones, K.W.; Kraner, H.W.; Chao, E.C.T.; Minkin, J.A.

    1984-01-01

    The advent of dedicated synchrotron radiation sources has led to a significant increase in activity in many areas of science dealing with the interaction of x-rays with matter. Synchrotron radiation provides intense, linearly polarized, naturally collimated, continuously tunable photon beams, which are used to determine not only the elemental composition of a complex, polyatomic, dilute material but also the chemical form of the elements with improved accuracy. Examples of the application of synchrotron radiation include experiments in synchrotron x-ray fluorescence (SXRF) analysis and extended x-ray absorption fine structure (EXAFS) analysis. New synchrotron radiation x-ray microprobes for elemental analysis in the parts per billion range are under construction at several laboratories. 76 references, 24 figures

  20. New constraints on variations of the fine structure constant from CMB anisotropies

    International Nuclear Information System (INIS)

    Menegoni, Eloisa; Melchiorri, Alessandro; Galli, Silvia; Bartlett, James G.; Martins, C. J. A. P.

    2009-01-01

    We demonstrate that recent measurements of cosmic microwave background temperature and polarization anisotropy made by the ACBAR, QUAD, and BICEP experiments substantially improve the cosmological constraints on possible variations of the fine structure constant in the early universe. This data, combined with the five year observations from the WMAP mission, yield the constraint α/α 0 =0.987±0.012 at 68% C.L. The inclusion of the new Hubble Space Telescope constraints on the Hubble constant further increases the accuracy to α/α 0 =1.001±0.007 at 68% C.L., bringing possible deviations from the current value below the 1% level and improving previous constraints by a factor of ∼3.

  1. Breed locally, disperse globally: Fine-scale genetic structure despite landscape-scale panmixia in a fire-specialist

    Science.gov (United States)

    Jennifer C. Pierson; Fred W. Allendorf; Pierre Drapeau; Michael K. Schwartz

    2013-01-01

    An exciting advance in the understanding of metapopulation dynamics has been the investigation of how populations respond to ephemeral patches that go 'extinct' during the lifetime of an individual. Previous research has shown that this scenario leads to genetic homogenization across large spatial scales. However, little is known about fine-scale genetic...

  2. Angle-resolved photoemission extended fine structure: Multiple layers of emitters and multiple initial states

    International Nuclear Information System (INIS)

    Huff, W.R.A.; Kellar, S.A.; Moler, E.J.; California Univ., Berkeley, CA; Chen, Y.; Wu, H.; Shirley, D.A.; Hussain, Z.

    1995-01-01

    Recently, angle-resolved photoemission extended fine structure (ARPEFS) has been applied to experimental systems involving multiple layers of emitters and non-s core-level photoemission in an effort to broaden the utility of the technique. Most of the previous systems have been comprised of atomic or molecular overlayers adsorbed onto a single-crystal, metal surface and the photoemission data were taken from an s atomic core-level in the overlayer. For such a system, the acquired ARPEFS data is dominated by the p o final state wave backscattering from the substrate atoms and is well understood. In this study, we investigate ARPEFS as a surface-region structure determination technique when applied to experimental systems comprised of multiple layers of photoemitters and arbitrary initial state core-level photoemission. Understanding the data acquired from multiple layers of photoemitters is useful for studying multilayer interfaces, ''buried'' surfaces, and clean crystals in ultra- high vacuum. The ability to apply ARPEFS to arbitrary initial state core-level photoemission obviously opens up many systems to analysis. Efforts have been ongoing to understand such data in depth. We present clean Cu(111) 3s, 3p, and 3d core-level, normal photoemission data taken on a high resolution soft x-ray beamline 9.3.2 at the Advanced Light Source in Berkeley, California and clean Ni(111) 3p normal photoemission data taken at the National Synchrotron Light Source in Upton, New York, USA

  3. Fine structure characterization of zero-valent iron nanoparticles for decontamination of nitrites and nitrates in wastewater and groundwater

    Directory of Open Access Journals (Sweden)

    Kuen-Song Lin et al

    2008-01-01

    Full Text Available The main objectives of the present study were to investigate the chemical reduction of nitrate or nitrite species by zero-valent iron nanoparticle (ZVIN in aqueous solution and related reaction kinetics or mechanisms using fine structure characterization. This work also exemplifies the utilization of field emission-scanning electron microscope (FE–SEM, transmission electron microscopy (TEM, and x-ray diffraction (XRD to reveal the speciation and possible reaction pathway in a very complex adsorption and redox reaction process. Experimentally, ZVIN of this study was prepared by sodium borohydride reduction method at room temperature and ambient pressure. The morphology of as-synthesized ZVIN shows that the nearly ball and ultrafine particles ranged of 20–50 nm were observed with FE–SEM or TEM analysis. The kinetic model of nitrites or nitrates reductive reaction by ZVIN is proposed as a pseudo first-order kinetic equation. The nitrite and nitrate removal efficiencies using ZVIN were found 65–83% and 51–68%, respectively, based on three different initial concentrations. Based on the XRD pattern analyses, it is found that the quantitative relationship between nitrite and Fe(III or Fe(II is similar to the one between nitrate and Fe(III in the ZVIN study. The possible reason is due to the faster nitrite reduction by ZVIN. In fact, the occurrence of the relative faster nitrite reductive reaction suggested that the passivation of the ZVIN have a significant contribution to iron corrosion. The extended x-ray absorption fine structure (EXAFS or x-ray absorption near edge structure (XANES spectra show that the nitrites or nitrates reduce to N2 or NH3 while oxidizing the ZVIN to Fe2O3 or Fe3O4 electrochemically. It is also very clear that decontamination of nitrate or nitrite species in groundwater via the in-situ remediation with a ZVIN permeable reactive barrier would be environmentally attractive.

  4. Laboratory-based recording of holographic fine structure in X-ray absorption anisotropy using polycapillary optics

    Energy Technology Data Exchange (ETDEWEB)

    Dabrowski, K.M. [Institute of Physics, Jagiellonian University, Reymonta 4, 30-059 Krakow (Poland); Korecki, P., E-mail: pawel.korecki@uj.edu.pl [Institute of Physics, Jagiellonian University, Reymonta 4, 30-059 Krakow (Poland)

    2012-08-15

    Highlights: Black-Right-Pointing-Pointer Holographic fine structures in X-ray absorption recorded using a tabletop setup. Black-Right-Pointing-Pointer Setup based on polycapillary collimating optics and an HOPG crystal. Black-Right-Pointing-Pointer Demonstration of element sensitivity by detection of X-ray fluorescence. Black-Right-Pointing-Pointer Potential of laboratory-based experiments for heavily doped crystals and thin films. - Abstract: A tabletop setup composed of a collimating polycapillary optics and a highly oriented pyrolytic graphite monochromator (HOPG) was characterized and used for recording two-dimensional maps of X-ray absorption anisotropy (XAA). XAA originates from interference of X-rays directly inside the sample. Depending on experimental conditions, fine structures in XAA can be interpreted in terms of X-ray holograms or X-ray standing waves and can be used for an element selective atomic-resolved structural analysis. The implementation of polycapillary optics resulted in a two-order of magnitude gain in the radiant intensity (photons/s/solid angle) as compared to a system without optics and enabled efficient recording of XAA with a resolution of 0.15 Degree-Sign for Mo K{alpha} radiation. Element sensitivity was demonstrated by acquisition of distinct XAA signals for Ga and As atoms in a GaAs (1 1 1) wafer by using X-ray fluorescence as a secondary signal. These results indicate the possibility of performing laboratory-based XAA experiments for heavily doped single crystals or thin films. So far, because of the weak holographic modulation of XAA, such experiments could be only performed using synchrotron radiation.

  5. Nine years of irrigation cause vegetation and fine root shifts in a water-limited pine forest.

    Directory of Open Access Journals (Sweden)

    Claude Herzog

    Full Text Available Scots pines (Pinus sylvestris L. in the inner-Alpine dry valleys of Switzerland have suffered from increased mortality during the past decades, which has been caused by longer and more frequent dry periods. In addition, a proceeding replacement of Scots pines by pubescent oaks (Quercus pubescens Willd. has been observed. In 2003, an irrigation experiment was performed to track changes by reducing drought pressure on the natural pine forest. After nine years of irrigation, we observed major adaptations in the vegetation and shifts in Scots pine fine root abundance and structure. Irrigation permitted new plant species to assemble and promote canopy closure with a subsequent loss of herb and moss coverage. Fine root dry weight increased under irrigation and fine roots had a tendency to elongate. Structural composition of fine roots remained unaffected by irrigation, expressing preserved proportions of cellulose, lignin and phenolic substances. A shift to a more negative δ13C signal in the fine root C indicates an increased photosynthetic activity in irrigated pine trees. Using radiocarbon (14C measurement, a reduced mean age of the fine roots in irrigated plots was revealed. The reason for this is either an increase in newly produced fine roots, supported by the increase in fine root biomass, or a reduced lifespan of fine roots which corresponds to an enhanced turnover rate. Overall, the responses belowground to irrigation are less conspicuous than the more rapid adaptations aboveground. Lagged and conservative adaptations of tree roots with decadal lifespans are challenging to detect, hence demanding for long-term surveys. Investigations concerning fine root turnover rate and degradation processes under a changing climate are crucial for a complete understanding of C cycling.

  6. Experimental determination of the relativistic fine-structure splitting in pionic Ti and Fe atoms

    International Nuclear Information System (INIS)

    Wang, K.; Boehm, F.; Bovet, E.; Hahn, A.A.; Henrikson, H.E.; Miller, J.P.; Powers, R.J.; Vogel, P.; Vuilleumier, J.; Kunselman, A.R.

    1980-01-01

    Using a high-resolution crystal spectrometer we have measured the relativistic angular-momentum splittings of the 5g-4f and 5f-4d transitions in pionic Ti and Fe atoms. The observed fine-structure splittings of 85.3 +- 3.0 eV in π - Ti and 158.5 +- 7.8 eV in π - Fe agree with the calculated splittings of 88.5 and 167.6 eV, respectively, arising from the Klein-Gordon equation and from small corrections due to vacuum polarization, strong interaction, and electron screening

  7. Surface extended x-ray absorption fine structure of low-Z absorbates using fluorescence detection

    International Nuclear Information System (INIS)

    Stoehr, J.; Kollin, E.B.; Fischer, D.A.; Hastings, J.B.; Zaera, F.; Sette, F.

    1985-05-01

    Comparison of x-ray fluorescence yield (FY) and electron yield surface extended x-ray absorption fine structure spectra above the S K-edge for c(2 x 2) S on Ni(100) reveals an order of magnitude higher sensitivity of the FY technique. Using FY detection, thiophene (C 4 H 4 S) chemisorption on Ni(100) is studied with S coverages down to 0.08 monolayer. The molecule dissociates at temperatures as low as 100K by interaction with fourfold hollow Ni sites. Blocking of these sites by oxygen leaves the molecule intact

  8. Polarized Fine Structure in the Photoluminescence Excitation Spectrum of a Negatively Charged Quantum Dot

    Science.gov (United States)

    Ware, M. E.; Stinaff, E. A.; Gammon, D.; Doty, M. F.; Bracker, A. S.; Gershoni, D.; Korenev, V. L.; Bădescu, Ş. C.; Lyanda-Geller, Y.; Reinecke, T. L.

    2005-10-01

    We report polarized photoluminescence excitation spectroscopy of the negative trion in single charge-tunable InAs/GaAs quantum dots. The spectrum exhibits a p-shell resonance with polarized fine structure arising from the direct excitation of the electron spin triplet states. The energy splitting arises from the axially symmetric electron-hole exchange interaction. The magnitude and sign of the polarization are understood from the spin character of the triplet states and a small amount of quantum dot asymmetry, which mixes the wave functions through asymmetric e-e and e-h exchange interactions.

  9. Absolute transition probabilities in the NeI 3p-3s fine structure by beam-gas-dye laser spectroscopy

    International Nuclear Information System (INIS)

    Hartmetz, P.; Schmoranzer, H.

    1983-01-01

    The beam-gas-dye laser two-step excitation technique is further developed and applied to the direct measurement of absolute atomic transition probabilities in the NeI 3p-3s fine-structure transition array with a maximum experimental error of 5%. (orig.)

  10. Contribution to the study of the {alpha} spectrometry by the impulse ionization chamber. Application to the study of the beam fine structure of some heavy nuclei; Contribution a l'etude de la spectrometrie {alpha} par la chambre d'ionisation a impulsion. Application a l'etude de la structure fine du rayonnement de quelques noyaux lourds

    Energy Technology Data Exchange (ETDEWEB)

    Valladas, G [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1954-05-15

    In the first part, it studies an impulse spectrometer of which the resolution and stability have been pushed to their maximum possibilities. It uses an ionization chamber because of its simple and steady functioning. The general characteristics and building of the ionization chamber are described. The electronic devices are described as well as the recording system. The theoretical study of the amplifier has allowed to reduce the amplitude dispersion from electronic devices as background noise. The resolution in energy of an {alpha} spectrometer using an impulse ionization chamber is studied and results are discussed. The spectral lines display of the fine structure under the effect of conversion electrons emitted by coincidence in the ionization chamber is studied. Finally, the detection possibilities of very low intensity spectral lines of fine structure of detection are considered. In the second part, the {alpha} emission of fine structure of {sup 230}Th, {sup 234}U and {sup 238}U nuclei is studied. (M.P.)

  11. EXAFS as a tool for investigation of the local environment of Ge atoms in buried low-dimensional structures

    International Nuclear Information System (INIS)

    Demchenko, I.N.; Lawniczak-Jablonska, K.; Liliental-Weber, Z.; Zakharov, D.N.; Zhuravlev, K.S.

    2005-01-01

    In spite of large number of articles dedicated to the investigation of GeSi islands, a lot of problems concerning growth mechanism and island composition, as well as elastic strains inside the QDs, are still unsolved. To solve such problems, the GeSi low dimensional structures were studied by Extended X-Ray Absorption Fine Structure (EXAFS). The aim of this investigation was to get knowledge about the local structure around Ge atoms inside formed quantum dots. The paper presents a series of measurements performed for a single Ge layer buried in the silicon matrix at A1 station at the HASYLAB/DESY (Germany) with the angle of 45 o between the incident beam and sample surface. The fluorescence, total electron yield and the transmission modes of detection were used. To confirm the EXAFS analysis conclusion more measurements were performed using transmission electron microscopy (TEM). The low temperature samples with 8-20 ML of Ge were investigated by cross-section and plan-view TEM. The reported results of TEM studies of the local structure of germanium quantum dots (QDs) in Si/Ge/Si '' sandwich '' structures are in good correlation with EXAFS conclusion

  12. Mechanical Behavior Analysis of Y-Type S-SRC Column in a Large-Space Vertical Hybrid Structure Using Local Fine Numerical Simulation Method

    Directory of Open Access Journals (Sweden)

    Jianguang Yue

    2018-01-01

    Full Text Available In a large spatial structure, normally the important members are of special type and are the safety key for the global structure. In order to study the mechanical behavior details of the local member, it is difficult for the common test method to realize the complex spatial loading state of the local member. Therefore, a local-fine finite element model was proposed and a large-space vertical hybrid structure was numerically simulated. The seismic responses of the global structure and the Y-type S-SRC column were analyzed under El Centro seismic motions with the peak acceleration of 35 gal and 220 gal. The numerical model was verified with the results of the seismic shaking table test of the structure model. The failure mechanism and stiffness damage evolution of the Y-type S-SRC column were analyzed. The calculated results agreed well with the test results. It indicates that the local-fine FEM could reflect the mechanical details of the local members in a large spatial structure.

  13. Fine-structural effects of 1200-R abdominal x irradiation on rat intestinal epithelium

    International Nuclear Information System (INIS)

    Lieb, R.J.; McDonald, T.F.; McKenney, J.R.

    1977-01-01

    Male Charles River CD rats were shielded from the xiphoid process cranially with lead and were exposed to 1200-R abdominal x irradiation. Animals were sacrificed at 1 through 4 days following irradiation and tissues from both ileum and jejunum were prepared for electron microscopic examination. At the fine-structural level early changes were confined to a proliferation and dilation of smooth endoplasmic reticulum and to an increase in the number of lysosomes. At 4 days postirradiation, cells covering the villi were cuboidal rather than columnar and appeared to be immature crypt-type cells. The appearance of these cells was coincident with the onset of diarrhea in these animals

  14. Representations of U(2∞ and the Value of the Fine Structure Constant

    Directory of Open Access Journals (Sweden)

    William H. Klink

    2005-12-01

    Full Text Available A relativistic quantum mechanics is formulated in which all of the interactions are in the four-momentum operator and Lorentz transformations are kinematic. Interactions are introduced through vertices, which are bilinear in fermion and antifermion creation and annihilation operators, and linear in boson creation and annihilation operators. The fermion-antifermion operators generate a unitary Lie algebra, whose representations are fixed by a first order Casimir operator (corresponding to baryon number or charge. Eigenvectors and eigenvalues of the four-momentum operator are analyzed and exact solutions in the strong coupling limit are sketched. A simple model shows how the fine structure constant might be determined for the QED vertex.

  15. Tape cast isotropic, fine-grained tungsten for thermo-cyclic loading applications

    Energy Technology Data Exchange (ETDEWEB)

    Sommerer, Mathias, E-mail: Mathias.Sommerer@tum.de [Lehrstuhl für Werkstoffkunde und Werkstoffmechanik, Technische Universität München, Boltzmannstr. 15, 85748 Garching (Germany); Li, Muyuan [Max-Planck-Institut für Plasma Physik, Boltzmannstraße 2, 85748 Garching (Germany); Werner, Ewald [Lehrstuhl für Werkstoffkunde und Werkstoffmechanik, Technische Universität München, Boltzmannstr. 15, 85748 Garching (Germany); Dewitz, Hubertus von; Walter, Steffen; Lampenscherf, Stefan [Siemens AG, Corporate Technology, Otto-Hahn-Ring 6, 81730 München (Germany); Arnold, Thomas [Siemens Healthcare GmbH, Henkestr. 127, 91052 Erlangen (Germany)

    2016-04-15

    Highlights: • The tape casting process for tungsten is described. • A set-up of a HHF test facility for standing anodes is presented. • The thermo-cyclic behavior of tape cast tungsten and a reference is investigated. • The evolution of crack patterns is described in dependency of HHF-loadings. • The surface roughness of X-ray anodes is related to the microstructural evolution. - Abstract: This paper introduces tape casting as a new route for the production of isotropic and fine-grained tungsten components. Microstructural and thermal properties of tape cast tungsten samples are determined. Thermal shock behavior according to the thermo-cyclic loading of standing X-ray anodes is investigated and compared to the behavior of a rolled tungsten grade. The development of surface roughness during the thermal shock loading is discussed in relation to the development of the grain structure and crack pattern. The fine-grained and stable microstructure of the tape cast material exhibits less roughening under such test conditions.

  16. Fine-structure processing, frequency selectivity and speech perception in hearing-impaired listeners

    DEFF Research Database (Denmark)

    Strelcyk, Olaf; Dau, Torsten

    2008-01-01

    Hearing-impaired people often experience great difficulty with speech communication when background noise is present, even if reduced audibility has been compensated for. Other impairment factors must be involved. In order to minimize confounding effects, the subjects participating in this study...... consisted of groups with homogeneous, symmetric audiograms. The perceptual listening experiments assessed the intelligibility of full-spectrum as well as low-pass filtered speech in the presence of stationary and fluctuating interferers, the individual's frequency selectivity and the integrity of temporal...... modulation were obtained. In addition, these binaural and monaural thresholds were measured in a stationary background noise in order to assess the persistence of the fine-structure processing to interfering noise. Apart from elevated speech reception thresholds, the hearing impaired listeners showed poorer...

  17. an investigation into the use of groundnut shell as fine aggregate

    African Journals Online (AJOL)

    2013-03-01

    Mar 1, 2013 ... Groundnut Shell Use as Fine Aggregate Replacement. 55. (a) Plate A. (b) Plate B ... as a waste from a household which uses groundnut for oil making. ..... Analysis of Cement and Aggregate Replacement Ma- terials. Nigerian ...

  18. Logarithmic contributions in the particle-mass ratio to the fine shift of S energy levels of hydrogen-like atoms in the fifth order in the fine-structure constant

    International Nuclear Information System (INIS)

    Boikova, N.A.; Kleshchevskaya, S.V.; Tyukhtyaev, Yu.N.; Faustov, R.N.

    2004-01-01

    A high-precision investigation of a logarithmic contribution in the particle-mass ratio to the fine shift of the S energy levels of hydrogen-like atoms from the exchange of a Coulomb photon is performed. It is shown that diagrams describing the exchange of one transverse photon and two Coulomb photons do not make such contributions

  19. Landscape-Level and Fine-Scale Genetic Structure of the Neo tropical Tree Protium spruceanum (Burseraceae)

    International Nuclear Information System (INIS)

    Vieira, F.D.A.; Fajardo, C.G.; De Souza, A.M.; Dulciniea De Carvalho, D.

    2010-01-01

    Knowledge of genetic structure at different scales and correlation with the current landscape is fundamental for evaluating the importance of evolutionary processes and identifying conservation units. Here, we used allozyme loci to examine the spatial genetic structure (SGS) of 230 individuals of Protium spruceanum, a native canopy-emergent in five fragments of Brazilian Atlantic forest (1 to 11.8 ha), and four ecological corridors (460 to 1000 m length). Wright's FST statistic and Mantel tests revealed little evidence of significant genetic structure at the landscape-scale (FST=0.027; rM=-0.051, P=.539). At fine-scale SGS, low levels of relatedness within fragments and corridors (Sp=0.008, P>.05) were observed. Differences in the levels and distribution of the SGS at both spatial scales are discussed in relation to biological and conservation strategies of corridors and forest fragments.

  20. Fine-structure excitation of Fe II and Fe III due to collisions with electrons

    Science.gov (United States)

    Wan, Yier; Qi, Yueying; Favreau, Connor; Loch, Stuart; Stancil, P.; Ballance, Connor; McLaughlin, Brendan

    2018-06-01

    Atomic data of iron peak elements are of great importance in astronomical observations. Among all the ionization stages of iron, Fe II and Fe III are of particular importance because of the high cosmic abundance, relatively low ionization potential and complex open d-shell atomic structure. Fe II and Fe III emission are observed from nearly all classes of astronomical objects over a wide spectral range from the infrared to the ultraviolet. To meaningfully interpret these spectra, astronomers have to employ highly complex modeling codes with reliable collision data to simulate the astrophysical observations. The major aim of this work is to provide reliable atomic data for diagnostics. We present new collision strengths and effective collisions for electron impact excitation of Fe II and Fe III for the forbidden transitions among the fine-structure levels of the ground terms. A very fine energy mesh is used for the collision strengths and the effective collision strengths are calculated over a wide range of electron temperatures of astrophysical importance (10-2000 K). The configuration interaction state wave functions are generated with a scaled Thomas-Fermi-Dirac-Amaldi (TFDA) potential, while the R-matrix plus intermediate coupling frame transformation (ICFT), Breit-Pauli R-matrix and Dirac R-matrix packages are used to obtain collision strengths. Influences of the different methods and configuration expansions on the collisional data are discussed. Comparison is made with earlier theoretical work and differences are found to occur at the low temperatures considered here.This work was funded by NASA grant NNX15AE47G.

  1. Preferred Compression Speed for Speech and Music and Its Relationship to Sensitivity to Temporal Fine Structure

    OpenAIRE

    Moore, Brian C. J.; S?k, Aleksander

    2016-01-01

    Multichannel amplitude compression is widely used in hearing aids. The preferred compression speed varies across individuals. Moore (2008) suggested that reduced sensitivity to temporal fine structure (TFS) may be associated with preference for slow compression. This idea was tested using a simulated hearing aid. It was also assessed whether preferences for compression speed depend on the type of stimulus: speech or music. Twenty-two hearing-impaired subjects were tested, and the stimulated h...

  2. Self-compacting fine-grained concretes with compensated shrinkage

    Directory of Open Access Journals (Sweden)

    Alimov Lev

    2017-01-01

    Full Text Available This paper substantiates the efficiency of application of fine-grained concrete for erection of cast-in-place concrete and reinforced concrete structures of different purpose. On the basis of analysis of experimental research results it was established that the introduction of microfillers with expansion effect to composite binder allows not only improving the rheological properties of fine-grained concrete, but also decreasing of value of shrinkage strain and improving of concrete crack resistance and durability. The analysis of the results of industrial use of fine-grained concretes with compensated shrinkage is given.

  3. Coherent fine scale eddies in turbulence transition of spatially-developing mixing layer

    International Nuclear Information System (INIS)

    Wang, Y.; Tanahashi, M.; Miyauchi, T.

    2007-01-01

    To investigate the relationship between characteristics of the coherent fine scale eddy and a laminar-turbulent transition, a direct numerical simulation (DNS) of a spatially-developing turbulent mixing layer with Re ω,0 = 700 was conducted. On the onset of the transition, strong coherent fine scale eddies appears in the mixing layer. The most expected value of maximum azimuthal velocity of the eddy is 2.0 times Kolmogorov velocity (u k ), and decreases to 1.2u k , which is an asymptotic value in the fully-developed state, through the transition. The energy dissipation rate around the eddy is twice as high compared with that in the fully-developed state. However, the most expected diameter and eigenvalues ratio of strain rate acting on the coherent fine scale eddy are maintained to be 8 times Kolmogorov length (η) and α:β:γ = -5:1:4 in the transition process. In addition to Kelvin-Helmholtz rollers, rib structures do not disappear in the transition process and are composed of lots of coherent fine scale eddies in the fully-developed state instead of a single eddy observed in early stage of the transition or in laminar flow

  4. (1,3;1,4)-β-Glucan Biosynthesis by the CSLF6 Enzyme: Position and Flexibility of Catalytic Residues Influence Product Fine Structure.

    Science.gov (United States)

    Dimitroff, George; Little, Alan; Lahnstein, Jelle; Schwerdt, Julian G; Srivastava, Vaibhav; Bulone, Vincent; Burton, Rachel A; Fincher, Geoffrey B

    2016-04-05

    Cellulose synthase-like F6 (CslF6) genes encode polysaccharide synthases responsible for (1,3;1,4)-β-glucan biosynthesis in cereal grains. However, it is not clear how both (1,3)- and (1,4)-linkages are incorporated into a single polysaccharide chain and how the frequency and arrangement of the two linkage types that define the fine structure of the polysaccharide are controlled. Through transient expression in Nicotiana benthamiana leaves, two CSLF6 orthologs from different cereal species were shown to mediate the synthesis of (1,3;1,4)-β-glucans with very different fine structures. Chimeric cDNA constructs with interchanged sections of the barley and sorghum CslF6 genes were developed to identify regions of the synthase enzyme responsible for these differences. A single amino acid residue upstream of the TED motif in the catalytic region was shown to dramatically change the fine structure of the polysaccharide produced. The structural basis of this effect can be rationalized by reference to a homology model of the enzyme and appears to be related to the position and flexibility of the TED motif in the active site of the enzyme. The region and amino acid residue identified provide opportunities to manipulate the solubility of (1,3;1,4)-β-glucan in grains and vegetative tissues of the grasses and, in particular, to enhance the solubility of dietary fibers that are beneficial to human health.

  5. Updated constraints on spatial variations of the fine-structure constant

    Directory of Open Access Journals (Sweden)

    A.M.M. Pinho

    2016-05-01

    Full Text Available Recent work by Webb et al. has provided indications of spatial variations of the fine-structure constant, α, at a level of a few parts per million. Using a dataset of 293 archival measurements, they further show that a dipole provides a statistically good fit to the data, a result subsequently confirmed by other authors. Here we show that a more recent dataset of dedicated measurements further constrains these variations: although there are only 10 such measurements, their uncertainties are considerably smaller. We find that a dipolar variation is still a good fit to the combined dataset, but the amplitude of such a dipole must be somewhat smaller: 8.1±1.7 ppm for the full dataset, versus 9.4±2.2 ppm for the Webb et al. data alone, both at the 68.3% confidence level. Constraints on the direction on the sky of such a dipole are also significantly improved. On the other hand the data can't yet discriminate between a pure spatial dipole and one with an additional redshift dependence.

  6. Fine structure near the starting frequency of solar type III radio bursts

    Energy Technology Data Exchange (ETDEWEB)

    Benz, A.O.; Zlobec, P.; Jaeggi, M.

    1982-06-01

    We have systematically analyzed the period in time and frequency adjacent to the beginning of type III bursts digitally recorded at Bleien during the second half of 1980. A surprisingly high percentage (10%, possibly more than 20%) of the type III bursts show fine structure in the form of narrow-banded spikes of 0.05 s and less duration, which form clusters of relatively large bandwidth. These spikes are not totally polarized (contrary to claims in the literature) and they are uniformly distributed over the disk. Individual spikes often show highly variable polarization, which may even change sense. The average degree of polarization of the clouds has a wider distribution than that of the associated type III bursts, but generally the same sign. Spikes are considerably different from type I bursts.

  7. Higher-order Stark effect on magnetic fine structure of the helium atom

    Energy Technology Data Exchange (ETDEWEB)

    Magunov, A.; Pal' chikov, V.; Pivovarov, V. [National Research Inst. for Physical-Technical and Radiotechnical Measurements (VNIIFTRI), Mendeleevo, Moscow Region (Russian Federation); Ovsiannikov, V. [Dept. of Physics, Voronezh State Univ. (Russian Federation); Oppen, G. von [Inst. fuer Analytische und Atomare Physik at Technische Univ. Berlin (Germany)

    2001-07-01

    We have calculated the scalar and tensor dipole polarizabilities ({beta}) and hyperpolarizabilities ({gamma}) of excited 1s2p {sup 3}P{sub 0}, 1s2p {sup 3}P{sub 2}- states of helium. Our theory includes fine structure of triplet sublevels. Semiempirical and accurate electron-correlated wave functions have been used to determine the static values of {beta} and {gamma}. Numerical calculations are carried out using sums of oscillator strengths and, alternatively, with the Green function for the excited valence electron. Specifically, we present results for the integral over the continuum, for second- and fourth-order matrix elements. The corresponding estimations indicate that these corrections are of the order of 23% for the scalar part of polarizability and only of the order of 3% for the tensor part.

  8. Fine structure and ionization energy of the 1s2s2p 4P state of the helium negative ion He-.

    Science.gov (United States)

    Wang, Liming; Li, Chun; Yan, Zong-Chao; Drake, G W F

    2014-12-31

    The fine structure and ionization energy of the 1s2s2p (4)P state of the helium negative ion He(-) are calculated in Hylleraas coordinates, including relativistic and QED corrections up to O(α(4)mc(2)), O((μ/M)α(4)mc(2)), O(α(5)mc(2)), and O((μ/M)α(5)mc(2)). Higher order corrections are estimated for the ionization energy. A comparison is made with other calculations and experiments. We find that the present results for the fine structure splittings agree with experiment very well. However, the calculated ionization energy deviates from the experimental result by about 1 standard deviation. The estimated theoretical uncertainty in the ionization energy is much less than the experimental accuracy.

  9. The morphodynamics and internal structure of intertidal fine-gravel dunes: Hills Flats, Severn Estuary, UK

    Science.gov (United States)

    Carling, P. A.; Radecki-Pawlik, A.; Williams, J. J.; Rumble, B.; Meshkova, L.; Bell, P.; Breakspear, R.

    2006-01-01

    In the macrotidal Severn estuary, UK, the dynamics of intertidal fine-gravel dunes were investigated. These dunes are migrating across a bedrock platform. Systematic observations were made of hydraulic climate, geometry, migration rates and internal sedimentary structures of the dunes. During spring tides, the ebb flow is dominant, dunes grow in height and have ebb orientated geometry with bedrock floors in the troughs. During neap tides, a weak flood flow may dominate. Dunes then are flood orientated or symmetrical. Neap dune heights decrease and the eroded sediment is stored in the dune troughs where the bedrock becomes blanketed by muddy gravel. During spring tides, instantaneous bed shear stresses reach 8 N m - 2 , sufficient to disrupt a 9 mm-gravel armour layer. However, a sustained bed shear stress of 4 N m - 2 is required to initiate dune migration at which time the critical depth-mean velocity is 1 m s - 1 . Ebb and flood inequalities in the bed shear stress explain the changes in dune asymmetry and internal structures. During flood tides, the crests of the dunes reverse such that very mobile sedimentary 'caps' overlie a more stable dune 'core'. Because ebb tides dominate, internal structures of the caps often are characterised by ebb orientated steep open-work foresets developed by strong tidal currents and some lower angle crossbeds deposited as weaker currents degrade foresets. The foresets forming the caps may be grouped into cosets (tidal bundles) and are separated from mud-infused cores of crossbeds that lie below, by reactivation and erosion surfaces blanketed by discontinuous mud drapes. The cores often exhibit distinctive muddy toe sets that define the spacing of tidal cosets.

  10. Electron-beam induced amorphization of stishovite: Silicon-coordination change observed using Si K-edge extended electron energy-loss fine structure

    International Nuclear Information System (INIS)

    Aken, P.A. van; Sharp, T.G.; Seifert, F.

    1998-01-01

    The analysis of the extended energy-loss fine structure (EXELFS) of the Si K-edge for sixfold-coordinated Si in synthetic stishovite and fourfold-coordinated Si in natural α-quartz is reported by using electron energy-loss spectroscopy (EELS) in combination with transmission electron microscopy (TEM). The stishovite Si K-edge EXELFS spectra were measured as a time-dependent series to document irradiation-induced amorphization. The amorphization was also investigated through the change in Si K- and O K-edge energy-loss near edge structure (ELNES). For α-quartz, in contrast to stishovite, electron irradiation-induced vitrification, produced no detectable changes of the EXELFS. The Si K-edge EXELFS were analysed with the classical extended X-ray absorption fine structure (EXAFS) treatment and compared to ab initio curve-waved multiple-scattering (MS) calculations of EXAFS spectra for stishovite and α-quartz. Highly accurate information on the local atomic environment of the silicon atoms during the irradiation-induced amorphization of stishovite is obtained from the EXELFS structure parameters The mean Si-O bond distance R and mean Si coordination number N changes from R=0.1775 nm and N=6 for stishovite through a disordered intermediate state (R∼0.172 nm and N∼5) to R∼0.167 nm and N∼4.5 for a nearly amorphous state similar to α-quartz (R=0.1609 nm and N=4). During the amorphization process, the Debye-Waller factor (DWF) passes through a maximum value of σ N 2 ∼83.8pm 2 as it changes from σ st 2 =51.8pm 2 for sixfold to σ qu 2 =18.4pm 2 for fourfold coordination of Si. This increase in Debye-Waller factor indicates an increase in mean-square relative displacement (MSRD) between the central silicon atom and its oxygen neighbours. Using the EXELFS data for amorphization, a new method is developed to derive the relative amounts of Si coordinations in high-pressure minerals with mixed coordination. For the radiation-induced amorphization process of

  11. Pelletization of fine coals. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Sastry, K.V.S.

    1995-12-31

    Coal is one of the most abundant energy resources in the US with nearly 800 million tons of it being mined annually. Process and environmental demands for low-ash, low-sulfur coals and economic constraints for high productivity are leading the coal industry to use such modern mining methods as longwall mining and such newer coal processing techniques as froth flotation, oil agglomeration, chemical cleaning and synthetic fuel production. All these processes are faced with one common problem area--fine coals. Dealing effectively with these fine coals during handling, storage, transportation, and/or processing continues to be a challenge facing the industry. Agglomeration by the unit operation of pelletization consists of tumbling moist fines in drums or discs. Past experimental work and limited commercial practice have shown that pelletization can alleviate the problems associated with fine coals. However, it was recognized that there exists a serious need for delineating the fundamental principles of fine coal pelletization. Accordingly, a research program has been carried involving four specific topics: (i) experimental investigation of coal pelletization kinetics, (ii) understanding the surface principles of coal pelletization, (iii) modeling of coal pelletization processes, and (iv) simulation of fine coal pelletization circuits. This report summarizes the major findings and provides relevant details of the research effort.

  12. Structural investigations of sodium caseinate micelles in complex environments

    International Nuclear Information System (INIS)

    Huck Iriart, C.; Herrera, M.L.; Candal, R.; Oliveira, C.L.P.; Torriani, I.

    2012-01-01

    Full text: The most frequent destabilization mechanisms in Sodium Caseinate (NaCas) emulsions are creaming and flocculation. Coarse or fine emulsions with low protein con- tent destabilize mainly by creaming. If migration mechanism is suppressed, flocculation may become the main mechanism of destabilization. Small Angle X-Ray Scattering (SAXS) technique was applied to investigate sodium caseinate micelles structure in different environments. As many natural products, Sodium Caseinate samples have large polydisperse size distribution. The experimental data was analyzed using advanced modeling approaches. The Form Factor for the Caseinate micelle subunits was described by an ellipsoidal core shell model and the structure factor was split into two contributions, one corresponding to the particle-particle interactions and another one for the long range correlation of the subunits in the supramolecular structure. For the first term the hard sphere structure factor using the Percus-Yevick approximation for closure relation was used and for the second term a fractal model was applied. Three concentrations of sodium Caseinate (2, 5 and 7.5 %wt.) were measured in pure water, sugar solutions (20 %wt.) and in three different lipid phase emulsions containing 10 %wt. sunflower seed, olive and fish oils. Data analysis provided an average casein subunit radius of 4 nm, an average distance between the subunits of around 20nm and a fractal dimension value of around 3 for all samples. As indicated by the values of the correlation lengths for the set of studied samples, the casein aggregation is strongly affected by simple sugar additions and it is enhanced by emulsion droplets hydrophobic interaction. As will be presented, these nanoscale structural results provided by scattering experiments is consistent with macroscopic results obtained from several techniques, providing a new understanding of NaCas emulsions. (author)

  13. Structural investigations of sodium caseinate micelles in complex environments

    Energy Technology Data Exchange (ETDEWEB)

    Huck Iriart, C.; Herrera, M.L.; Candal, R. [Universidad de Buenos Aires, Buenos Aires (Argentina); Oliveira, C.L.P. [Universidade de Sao Paulo (USP), Sao Paulo, SP (Brazil); Torriani, I. [Laboratorio Nacional de Luz Sincrotron (LNLS), Campinas, SP (Brazil)

    2012-07-01

    Full text: The most frequent destabilization mechanisms in Sodium Caseinate (NaCas) emulsions are creaming and flocculation. Coarse or fine emulsions with low protein con- tent destabilize mainly by creaming. If migration mechanism is suppressed, flocculation may become the main mechanism of destabilization. Small Angle X-Ray Scattering (SAXS) technique was applied to investigate sodium caseinate micelles structure in different environments. As many natural products, Sodium Caseinate samples have large polydisperse size distribution. The experimental data was analyzed using advanced modeling approaches. The Form Factor for the Caseinate micelle subunits was described by an ellipsoidal core shell model and the structure factor was split into two contributions, one corresponding to the particle-particle interactions and another one for the long range correlation of the subunits in the supramolecular structure. For the first term the hard sphere structure factor using the Percus-Yevick approximation for closure relation was used and for the second term a fractal model was applied. Three concentrations of sodium Caseinate (2, 5 and 7.5 %wt.) were measured in pure water, sugar solutions (20 %wt.) and in three different lipid phase emulsions containing 10 %wt. sunflower seed, olive and fish oils. Data analysis provided an average casein subunit radius of 4 nm, an average distance between the subunits of around 20nm and a fractal dimension value of around 3 for all samples. As indicated by the values of the correlation lengths for the set of studied samples, the casein aggregation is strongly affected by simple sugar additions and it is enhanced by emulsion droplets hydrophobic interaction. As will be presented, these nanoscale structural results provided by scattering experiments is consistent with macroscopic results obtained from several techniques, providing a new understanding of NaCas emulsions. (author)

  14. A search for fine structure of the time-of-flight spectrum of the fission neutrons of 252Cf

    International Nuclear Information System (INIS)

    Scobie, J.; Scott, R.D.; Feather, N.; Vass, D.G.

    1977-01-01

    A standard time-of-flight arrangement, in which start pulses were supplied by fission fragments and stop pulses by neutrons, has been employed in an attempt to check recent claims of the existence of fine structures in the time-of-flight spectrum of the fission neutrons of 252 Cf. This structure, in the form of spikes with tails towards longer times, has been attributed to the emission of neutrons of short delay (with half-lives of a few to a hundred or so nanoseconds) in the fission process. It has not been possible to find any convincing evidence for the existence of such structure. (author)

  15. Fine-structure constant: Is it really a constant

    International Nuclear Information System (INIS)

    Bekenstein, J.D.

    1982-01-01

    It is often claimed that the fine-structure ''constant'' α is shown to be strictly constant in time by a variety of astronomical and geophysical results. These constrain its fractional rate of change alpha-dot/α to at least some orders of magnitude below the Hubble rate H 0 . We argue that the conclusion is not as straightforward as claimed since there are good physical reasons to expect alpha-dot/α 0 . We propose to decide the issue by constructing a framework for a variability based on very general assumptions: covariance, gauge invariance, causality, and time-reversal invariance of electromagnetism, as well as the idea that the Planck-Wheeler length (10 -33 cm) is the shortest scale allowable in any theory. The framework endows α with well-defined dynamics, and entails a modification of Maxwell electrodynamics. It proves very difficult to rule it out with purely electromagnetic experiments. In a cosmological setting, the framework predicts an alpha-dot/α which can be compatible with the astronomical constraints; hence, these are too insensitive to rule out α variability. There is marginal conflict with the geophysical constraints: however, no firm decision is possible because of uncertainty about various cosmological parameters. By contrast the framework's predictions for spatial gradients of α are in fatal conflict with the results of the Eoetvoes-Dicke-Braginsky experiments. Hence these tests of the equivalence principle rule out with confidence spacetime variability of α at any level

  16. A numerical investigation of fine sediment resuspension in the wave boundary layer - effect of hindered settling and bedforms

    Science.gov (United States)

    Hsu, T. J.; Cheng, Z.; Yu, X.

    2016-02-01

    The wave bottom boundary layer is a major conduit delivering fine terrestrial sediments to the continental margin. Hence, studying the fine sediment resuspension in the wave boundary layer is crucial to the understanding of various components of the earth system, such as carbon cycle. By assuming the settling velocity to be a constant in each simulation, previous turbulence-resolving numerical simulations reveal the existence of three transport modes in the wave boundary layer associated with the sediment availability. As the sediment availability and hence the sediment-induced stable stratification increase, a sequence of transport modes, namely, (I) well-mixed transport, (II) formulation of lutocline resembling a two-layer system, and (III) completely laminarized transport are observed. In general, the settling velocity is a flow variable due to the floc dynamics and hindered settling. This study further investigate the effect of hindered settling. Particularly, for flocs with lower gelling concentrations, the hindered settling effect can play a key role in sustaining large amount of suspended sediment load and results in the laminarized transport (III). For the simulation with a very significant hindered settling effect due to a low gelling concentration, results also indicate the occurrence of gelling ignition, a state in which the erosion rate is always higher than the deposition rate. A condition for the occurrence of gelling ignition is proposed for a range of wave intensities as a function of sediment/floc properties and erodibility parameters. These aforementioned studies are limited to fine sediment transport over a flat bed. However, recent field and laboratory observation show that a small amount of sand fraction can lead to the formation of small bedforms, which can armor the bed while in the meantime enhance near bed turbulence. Preliminary investigation on the effect of bedforms on the resulting transport modes will also be presented.

  17. Coupled channels description of the α-decay fine structure

    Science.gov (United States)

    Delion, D. S.; Ren, Zhongzhou; Dumitrescu, A.; Ni, Dongdong

    2018-05-01

    We review the coupled channels approach of α transitions to excited states. The α-decaying states are identified as narrow outgoing Gamow resonances in an α-daughter potential. The real part of the eigenvalue corresponds to the Q-value, while the imaginary part determines the half of the total α-decay width. We first review the calculations describing transitions to rotational states treated by the rigid rotator model, in even–even, odd-mass and odd–odd nuclei. It is found that the semiclassical method overestimates the branching ratios to excited 4+ for some even–even α-emitters and fails in explaining the unexpected inversion of branching ratios of some odd-mass nuclei, while the coupled-channels results show good agreement with the experimental data. Then, we review the coupled channels method for α-transitions to 2+ vibrational and transitional states. We present the results of the Coherent State Model that describes in a unified way the spectra of vibrational, transitional and rotational nuclei. We evidence general features of the α-decay fine structure, namely the linear dependence between α-intensities and excitation energy, the linear correlation between the strength of the α-core interaction and spectroscopic factor, and the inverse correlation between the nuclear collectivity, given by electromagnetic transitions, and α-clustering.

  18. X-ray Absorption Fine Structure (XAFS) Studies of Oxide Glasses—A 45-Year Overview

    Science.gov (United States)

    Zanotto, Edgar Dutra

    2018-01-01

    X-ray Absorption Fine Structure (XAFS) spectroscopy has been widely used to characterize the short-range order of glassy materials since the theoretical basis was established 45 years ago. Soon after the technique became accessible, mainly due to the existence of Synchrotron laboratories, a wide range of glassy materials was characterized. Silicate glasses have been the most studied because they are easy to prepare, they have commercial value and are similar to natural glasses, but borate, germanate, phosphate, tellurite and other less frequent oxide glasses have also been studied. In this manuscript, we review reported advances in the structural characterization of oxide-based glasses using this technique. A focus is on structural characterization of transition metal ions, especially Ti, Fe, and Ni, and their role in different properties of synthetic oxide-based glasses, as well as their important function in the formation of natural glasses and magmas, and in nucleation and crystallization. We also give some examples of XAFS applications for structural characterization of glasses submitted to high pressure, glasses used to store radioactive waste and medieval glasses. This updated, comprehensive review will likely serve as a useful guide to clarify the details of the short-range structure of oxide glasses. PMID:29382102

  19. Molybdenum reduction in a sulfidic lake: Evidence from X-ray absorption fine-structure spectroscopy and implications for the Mo paleoproxy

    DEFF Research Database (Denmark)

    Dahl, T. W.; Chappaz, A.; Fitts, J. P.

    2013-01-01

    and the ultimate Mo host in euxinic sediments are not well understood. We used X-ray absorption fine structure (XAFS) spectroscopy to determine the oxidation state and the molecular coordination environment of pristine, solid phase Mo in sediments from permanently euxinic Lake Cadagno, Switzerland. Samples were...

  20. Relations between Playing Activities and Fine Motor Development

    Science.gov (United States)

    Suggate, Sebastian; Stoeger, Heidrun; Pufke, Eva

    2017-01-01

    Children's fine motor skills (FMS) are being increasingly recognized as an important aspect of preschool development; yet, we know very little about the experiences that foster their development. We utilized a parent-administered children's fine and gross motor activities questionnaire (MAQ) to investigate links with FMS. We recruited a sample of…

  1. Extended x-ray absorption fine structure study of arsenic in HgCdTe: p-type doping linked to nonsubstitutional As incorporation in an unknown AsHg8 structure

    International Nuclear Information System (INIS)

    Biquard, X.; Alliot, I.; Ballet, P.

    2009-01-01

    An extended x-ray absorption fine structure (EXAFS) investigation has been carried out on arsenic-doped Hg 70 Cd 30 Te samples. The incorporation of atomic arsenic has been achieved using a nonconventional radio-frequency plasma source in a molecular beam epitaxy reactor. Two samples from the same epitaxial wafer have been studied. One underwent a 400 deg. C activation annealing under Hg pressure, leading to n to p-type conversion. In the commonly admitted scenario, this conversion is associated with the annealing-induced migration of As from a Hg site to a Te site. This study shows that this is not the case. Before annealing, As is found to be involved in noncrystalline structures: 50% inside an As 2 Te 3 chalcogenide glass and 50% inside a new AsHg 8 compact structure. After annealing, the As 2 Te 3 chalcogenide glass disappears, 31% of As occupies Hg sites and 69% incorporates inside this new AsHg 8 compact structure that occupies Te sites. The EXAFS results are in excellent agreement with 77 K Hall-effect measurements. The new AsHg 8 structure is found to have an acceptor behavior. Overall, this study provides an entirely new vision of extrinsic p-type doping of HgCdTe as well as the first experimental evidence of As site transfer induced by annealing.

  2. Handwriting and fine motor problems after treatment for acute lymphoblastic leukemia

    NARCIS (Netherlands)

    Reinders-Messelink, H.A.; Schoemaker, M.M.; Goeken, L.N H; van den Briel, M.M.; Kamps, W.A; Simner, M L; Leedham, C G; Thomassen, A J W M

    1996-01-01

    Fine motor skills and handwriting performance were investigated in 17 children at least two years after treatment for acute lymphoblastic leukemia. It was hypothesized that as a late effect of vincristine neuropathy, children would still have fine motor and/or handwriting problems. Gross and fine

  3. Local atomic structure of Zr-Cu and Zr-Cu-Al amorphous alloys investigated by EXAFS method

    International Nuclear Information System (INIS)

    Antonowicz, J.; Pietnoczka, A.; Zalewski, W.; Bacewicz, R.; Stoica, M.; Georgarakis, K.; Yavari, A.R.

    2011-01-01

    Research highlights: → Coordination number, interatomic distances and mean square atomic displacement in Zr-Cu and Zr-Cu-Al glasses. → Icosahedral symmetry in local atomic structure. → Deviation from random mixing behavior resulting from Al addition. - Abstract: We report on extended X-ray absorption fine structure (EXAFS) study of rapidly quenched Zr-Cu and Zr-Cu-Al glassy alloys. The local atomic order around Zr and Cu atoms was investigated. From the EXAFS data fitting the values of coordination number, interatomic distances and mean square atomic displacement were obtained for wide range of compositions. It was found that icosahedral symmetry rather than that of corresponding crystalline analogs dominates in the local atomic structure of Zr-Cu and Zr-Cu-Al amorphous alloys. Judging from bonding preferences we conclude that addition of Al as an alloying element results in considerable deviation from random mixing behavior observed in binary Zr-Cu alloys.

  4. Bloch oscillations of ultracold atoms and measurement of the fine structure constant; Oscillations de Bloch d'atomes ultrafroids et mesure de la constante de structure fine

    Energy Technology Data Exchange (ETDEWEB)

    Clade, P

    2005-10-15

    From a measurement of the recoil velocity of an atom absorbing a photon, it is possible to deduce a determination of the ratio h/m between the Planck constant and the mass of the atoms and then to deduce a value of the fine structure constant alpha. To do this measurement, we use the technique of Bloch oscillations, which allows us to transfer a large number of recoils to atoms. A velocity sensor, based on velocity selective Raman transition, enables us to measure the momentum transferred to the atoms. A measurement with a statistical uncertainty of 4.4 10{sup -9}, in conjunction with a careful study of systematic effects (5 10{sup -9}), has led us to a determination of alpha with an uncertainty of 6.7 10{sup -9}: {alpha}{sup -1}(Rb) = 137.03599878 (91). This uncertainty is similar to the uncertainty of the best determinations of alpha based on atom interferometry. (author)

  5. Electron-beam induced amorphization of stishovite: Silicon-coordination change observed using Si K-edge extended electron energy-loss fine structure

    Science.gov (United States)

    van Aken, P. A.; Sharp, T. G.; Seifert, F.

    The analysis of the extended energy-loss fine structure (EXELFS) of the Si K-edge for sixfold-coordinated Si in synthetic stishovite and fourfold-coordinated Si in natural α-quartz is reported by using electron energy-loss spectroscopy (EELS) in combination with transmission electron microscopy (TEM). The stishovite Si K-edge EXELFS spectra were measured as a time-dependent series to document irradiation-induced amorphization. The amorphization was also investigated through the change in Si K- and O K-edge energy-loss near edge structure (ELNES). For α-quartz, in contrast to stishovite, electron irradiation-induced vitrification, verified by selected area electron diffraction (SAED), produced no detectable changes of the EXELFS. The Si K-edge EXELFS were analysed with the classical extended X-ray absorption fine structure (EXAFS) treatment and compared to ab initio curve-waved multiple-scattering (MS) calculations of EXAFS spectra for stishovite and α-quartz. Highly accurate information on the local atomic environment of the silicon atoms during the irradiation-induced amorphization of stishovite is obtained from the EXELFS structure parameters (Si-O bond distances, coordination numbers and Debye-Waller factors). The mean Si-O bond distance R and mean Si coordination number N changes from R=0.1775 nm and N=6 for stishovite through a disordered intermediate state (R 0.172 nm and N 5) to R 0.167 nm and N 4.5 for a nearly amorphous state similar to α-quartz (R=0.1609 nm and N=4). During the amorphization process, the Debye-Waller factor (DWF) passes through a maximum value of as it changes from for sixfold to for fourfold coordination of Si. This increase in Debye-Waller factor indicates an increase in mean-square relative displacement (MSRD) between the central silicon atom and its oxygen neighbours that is consistent with the presence of an intermediate structural state with fivefold coordination of Si. The distribution of coordination states can be estimated by

  6. Fine motor skills development of children with autism sepctrum disorder.

    OpenAIRE

    Marešová, Petra

    2010-01-01

    My diploma thesis topic is Fine motor skills development of children with autism spectrum disorder. The objective of this document is to create a well arranged group of exercises and structured tasks aimed to develop fine motor skills of children at pre-school age with autism spectrum disorder. Theoretical part of this diploma thesis contains basic information related to autism and various details about motor skills. Practical section describes individual jobs and structured tasks used for fi...

  7. Fluorescence extended X-ray absorption fine structure analysis of half-metallic ferromagnet 'zinc-blende CrAs' grown on GaAs by molecular beam epitaxy

    CERN Document Server

    Ofuchi, H; Ono, K; Oshima, M; Akinaga, H; Manago, T

    2003-01-01

    In this work, geometric structures for a half-metallic ferromagnet 'zinc-blende CrAs', which showed ferromagnetic behavior beyond room temperature, were investigated using fluorescence extended X-ray absorption fine structure (EXAFS) measurement. The EXAFS measurements revealed that As atoms around Cr atoms in the 2 nm CrAs film grown on a GaAs(0 0 1) substrate were coordinated tetrahedrally, indicating formation of zinc-blende CrAs. The Cr-As bond length in the zinc-blende CrAs is 2.49 A. This value is close to that which was estimated from the lattice constant (5.82 A) of ferromagnetic zinc-blende CrAs calculated by full-potential linearized augmented-plane wave method. The EXAFS analysis show that the theoretically predicted zinc-blende CrAs can be fabricated on GaAs(0 0 1) substrate by low-temperature molecular-beam epitaxy.

  8. Fluorescence extended X-ray absorption fine structure analysis of half-metallic ferromagnet 'zinc-blende CrAs' grown on GaAs by molecular beam epitaxy

    International Nuclear Information System (INIS)

    Ofuchi, H.; Mizuguchi, M.; Ono, K.; Oshima, M.; Akinaga, H.; Manago, T.

    2003-01-01

    In this work, geometric structures for a half-metallic ferromagnet 'zinc-blende CrAs', which showed ferromagnetic behavior beyond room temperature, were investigated using fluorescence extended X-ray absorption fine structure (EXAFS) measurement. The EXAFS measurements revealed that As atoms around Cr atoms in the 2 nm CrAs film grown on a GaAs(0 0 1) substrate were coordinated tetrahedrally, indicating formation of zinc-blende CrAs. The Cr-As bond length in the zinc-blende CrAs is 2.49 A. This value is close to that which was estimated from the lattice constant (5.82 A) of ferromagnetic zinc-blende CrAs calculated by full-potential linearized augmented-plane wave method. The EXAFS analysis show that the theoretically predicted zinc-blende CrAs can be fabricated on GaAs(0 0 1) substrate by low-temperature molecular-beam epitaxy

  9. Development of Ultra-Fine-Grained Structure in AISI 321 Austenitic Stainless Steel

    Science.gov (United States)

    Tiamiyu, A. A.; Szpunar, J. A.; Odeshi, A. G.; Oguocha, I.; Eskandari, M.

    2017-12-01

    Ultra-fine-grained (UFG) structure was developed in AISI 321 austenitic stainless steel (ASS) using cryogenic rolling followed by annealing treatments at 923 K, 973 K, 1023 K, and 1073 K (650 °C, 700 °C, 750 °C, and 800 °C) for different lengths of time. The α'-martensite to γ-austenite reversion behavior and the associated texture development were analyzed in the cryo-rolled specimens after annealing. The activation energy, Q, required for the reversion of α'-martensite to γ-austenite in the steel was estimated to be 80 kJ mol-1. TiC precipitates and unreversed triple junction α'-martensite played major roles in the development of UFG structure through the Zener pinning of grain boundaries. The optimum annealing temperature and time for the development of UFG structure in the cryo-rolled AISI 321 steel are (a) 923 K (650 °C) for approximately 28800 seconds and (b) 1023 K (750 °C) for 600 seconds, with average grain sizes of 0.22 and 0.31 µm, respectively. Annealing at 1023 K (750 °C) is considered a better alternative since the volume fraction of precipitated carbides in specimens annealed at 1023 K (750 °C) are less than those annealed at 923 K (650 °C). More so, the energy consumption during prolonged annealing time to achieve an UFG structure at 923 K (650 °C) is higher due to low phase reversion rate. The hardness of the UFG specimens is 195 pct greater than that of the as-received steel. The higher volume fraction of TiC precipitates in the UFG structure may be an additional source of hardening. Micro and macrotexture analysis indicated {110}〈uvw〉 as the major texture component of the austenite grains in the UFG structure. Its intensity is stronger in the specimen annealed at low temperatures.

  10. The Fine Art in Structure of John Fowles’ Novel “The French Lieutenant’s Woman”

    Directory of Open Access Journals (Sweden)

    Oksana Levytska

    2013-12-01

    Full Text Available The article deals with the role of descriptive context in the structure of John Fowles’ novel “The French Lieutenant’s Woman”. Based on the intermedial analysis there was analyzed the semiotics of fine art in the novel, in particular an appeal to the Pre-Raphaelite art and the Renaissance painting. It was found that John Fowles’ works tend to use the poetics of different kinds of arts: the writer appeals to painting, operates its sign system, recodes signs of visual art by the language of a literary text, expanding the context of its understanding, interpretation and reception. There were studied intermedial connections of the novel with other works of arts. It was found that in the writer’s novels and stories were presented the most clearly visual arts in terms of their classification for the form of sensory perception. Among the arts in relation to time and space are dominated spatial arts: painting, sculpture, architecture, photography, decorative arts. The study focuses on the fine art, especially painting. The descriptive context is multivariation and multifunctional, it has manifestations on a level with the intermedial citation of painting, ekphrasis in landscape or portrait sketches, paintings of visualizing of characters’ imagination, allusions to works of art, etc., explicitly and implicitly represented in the texts. Intermedial analysis allows us to see the relationship of John Fowles’ novel with the Pre-Raphaelite art. In the character context the descriptive component increases literary, cultural and historical contextual characteristics. Introduced in the structure of a literary text the descriptive context on the semiotic level forms the axiological context. The system of ethical and aesthetic values of different cultural eras is extrapolated through the artistic context. So, the article studies the intermedial novel connections with other works of art. The descriptive context of the novel is manifested at

  11. Graphene directed architecture of fine engineered nanostructures with electrochemical applications

    DEFF Research Database (Denmark)

    Hou, Chengyi; Zhang, Minwei; Halder, Arnab

    2017-01-01

    , and polymers has led to the possibility to create new electroactive and multifunctional nanostructures, which can serve as promising material platforms for electrochemical purposes. However, the precise control and fine-tuning of material structures and properties are still challenging and in demand...... classified nanostructures, including metallic nanostructures, self-assembled organic and supramolecular structures, and fine engineered metal oxides. In these cases, graphene templates either sacrificed during templating synthesis or retained as support for final products. We also discuss remained challenges....... In this review, we aim to highlight some recent efforts devoted to rational design, assembly and fine engineering of electrochemically active nanostructures using graphene or/and its derivatives as soft templates for controlled synthesis and directed growth. We organize the contents according to the chemically...

  12. Electron impact excitation of fine-structure levels of neon-like titanium (Ti XIII)

    International Nuclear Information System (INIS)

    Gupta, G.P.; Deb, N.C.; Msezane, A.Z.

    1999-01-01

    The authors present results of a Breit-Pauli R-matrix calculation for the electron impact excitation of neon-like titanium, in which the 27 lowest fine-structure target levels arising out of the 4 lowest configurations 2s 2 2p 6 , 2s 2 2p 5 3s, 2s 2 2p 5 3p, and 2s 2 2p 5 3d are included. These target levels are represented by configuration interaction wave functions using the 1s, 2s, 2p, 3s, 3p, and 3d basic orbitals. The relativistic effects are included in the Breit-Pauli approximation via one-body mass correction, Darwin, and spin-orbit interaction terms in the scattering equations. For many transitions, complex resonance structures are found in the excitation cross sections. The excitation cross sections are integrated over a Maxwellian distribution of electron energies to give electron excitation rate coefficients over a wide temperature range from 150 to 600 eV. The relative populations for different electron densities and temperatures are also presented

  13. PROPERTIES AND MODELING OF UNRESOLVED FINE STRUCTURE LOOPS OBSERVED IN THE SOLAR TRANSITION REGION BY IRIS

    Energy Technology Data Exchange (ETDEWEB)

    Brooks, David H. [College of Science, George Mason University, 4400 University Drive, Fairfax, VA 22030 (United States); Reep, Jeffrey W.; Warren, Harry P. [Space Science Division, Naval Research Laboratory, Washington, DC 20375 (United States)

    2016-08-01

    Recent observations from the Interface Region Imaging Spectrograph ( IRIS ) have discovered a new class of numerous low-lying dynamic loop structures, and it has been argued that they are the long-postulated unresolved fine structures (UFSs) that dominate the emission of the solar transition region. In this letter, we combine IRIS measurements of the properties of a sample of 108 UFSs (intensities, lengths, widths, lifetimes) with one-dimensional non-equilibrium ionization simulations, using the HYDRAD hydrodynamic model to examine whether the UFSs are now truly spatially resolved in the sense of being individual structures rather than being composed of multiple magnetic threads. We find that a simulation of an impulsively heated single strand can reproduce most of the observed properties, suggesting that the UFSs may be resolved, and the distribution of UFS widths implies that they are structured on a spatial scale of 133 km on average. Spatial scales of a few hundred kilometers appear to be typical for a range of chromospheric and coronal structures, and we conjecture that this could be an important clue for understanding the coronal heating process.

  14. Comparison of spermatozoa parameters, fine structures, and energy-related factors among tetraploid, hyper-tetraploid, and hyper-triploid loaches (Misgurnus anguillicaudatus).

    Science.gov (United States)

    Zhao, Yan; Saito, Taiju; Pšenička, Martin; Fujimoto, Takafumi; Arai, Katsutoshi

    2014-04-01

    To evaluate the influence of ploidy elevation and aneuploidy on spermatozoa in the loach Misgurnus anguillicaudatus, we investigated some parameters (motility, concentration, and viability), fine structures (gross morphology, head size, and flagellum length), and energy-related biochemical factors (volume of mitochondrial mass per cell and ATP content) in diploid, hyper-diploid, and hexaploid-range spermatozoa produced in natural tetraploid, hyper-tetraploid, and hyper-triploid male loaches, respectively. Diploid spermatozoa exhibited vigorous movement and sufficient duration of motility similar to those in haploid spermatozoa. They had longer flagella, higher numbers and larger volume of mitochondria, and higher ATP content than haploid spermatozoa of wild-type diploids. No differences were observed in parameters and morphological characteristics between diploid and hyper-diploid spermatozoa. In contrast, the hexaploid-range spermatozoa of hyper-triploid males exhibited poor progressive motility in spite of a higher ATP content of spermatozoa. Spermatozoa with no flagella (36.0%) or multiple flagella (18.6%) were also observed in hyper-triploids. Ratios of head to flagellum length in hexaploid-range spermatozoa were significantly different from those of haploid spermatozoa. In addition to the normal 9+2 microtubule structure of the flagellum, an abnormal 9+1 microtubule structure was also observed in the spermatozoa of hyper-triploids. © 2014 Wiley Periodicals, Inc.

  15. HIGH-QUALITY ORNAMENTAL FINE CONCRETES MODIFIED BY NANOPARTICLES OF TITANIUM DIOXIDE

    Directory of Open Access Journals (Sweden)

    Bazhenov Yuriy Mikhaylovich

    2012-10-01

    Full Text Available Ultrasonic method of generation of a stable suspension of nano-particles of titanium dioxide and the strengthening properties of the ornamental fine concrete that contains cement binders with a nano-dispersed additive constitute the subject of the research covered by the authors. Nanoparticles react with the basic chemical elements that compose the concrete and act as crystallization centres. Therefore, the concrete porosity is reduced, while physical and technology-related properties of the ornamental fine concrete are improved. The authors have proven that the application of the nano-dispersed additive that contains titanium dioxide influences the processes of the structure formation in respect of fine ornamental concretes and improves the strength, as well as the water and cold resistance of fine concretes. The improvement is attributed to the dense concrete structure and strong adhesion between cement grains and between the cement and the aggregate. This conclusion is based on the data obtained through the employment of an electronic microscope used to identify the porosity of fine concretes.

  16. Structural study on Ni nanowires in an anodic alumina membrane by using in situ heating extended x-ray absorption fine structure and x-ray diffraction techniques

    International Nuclear Information System (INIS)

    Cai Quan; Chen Xing; Chen Zhongjun; Wang Wei; Mo Guang; Wu Zhonghua; Zhang Junxi; Zhang Lide; Pan Wei

    2008-01-01

    Polycrystalline Ni nanowires have been prepared by electrochemical deposition in an anodic alumina membrane template with a nanopore size of about 60 nm. In situ heating extended x-ray absorption fine structure and x-ray diffraction techniques are used to probe the atomic structures. The nanowires are identified as being mixtures of nanocrystallites and amorphous phase. The nanocrystallites have the same thermal expansion coefficient, of 1.7 x 10 -5 K -1 , as Ni bulk; however, the amorphous phase has a much larger thermal expansion coefficient of 3.5 x 10 -5 K -1 . Details of the Ni nanowire structures are discussed in this paper

  17. Radiation effects in fine metal media

    International Nuclear Information System (INIS)

    Zaikin, Yu. A.; Aliev, A.B.

    1999-01-01

    The report discusses condition and perspectives of theoretical and experimental research of metal powder material radiation processing influence on their caking, recrystallization and formation of metal and alloy structure obtained by powder metallurgy methods. Radiation processing of metal powders under determined modes causes forming of homogeneous fine metal structure and helps to considerably improve their running abilities (strength, endurance, corrosion resistance) and caking technological conditions

  18. Investigation and Estimation of Structure of Web from Electro spun Nano fibres

    International Nuclear Information System (INIS)

    Malasauskiene, J.; Milasius, R.

    2013-01-01

    During the electro spinning process the web of nano fibres is manufactured by means of electrostatic forces between two electrodes. The diameters of nano fibres usually differ and they depend on various parameters. The different fineness of fibres influences the structure of the web and herewith the end-use properties of such kind of nano material. Analysis of nano fibres diameters distribution also shows big differences; even more, the distributions are not spread along the normal distribution. Understanding the influence of electro spinning parameters and the reason why the shapes of distributions are so sophisticated is very important. The goal of this paper is to analyse the distribution of diameter and to propose the new criterion for nano fibres diameter comparison and web of nano fibres estimation. In this paper the influence of covering time of support material on structure of PA6.6 nano fibre web has been investigated. It was estimated that this parameter does not have a significant influence on the average diameter of nano fibres, and only the structure of web has been influenced by the changes in covering time. According to the results provided the phenomena of nano fibres sticking on the support material at the time of electro spinning can be proved and explained.

  19. Tensile properties and fracture of (α+γ) two phase stainless steel with fine grained microstructure

    International Nuclear Information System (INIS)

    Ogiyama, Hiroyuki; Tsukuda, Hitoshi; Soyama, Yoshiro

    1989-01-01

    The tensile properties and fracture of the (α+γ) two phase stainless steel with very fine γ grains were investigated. Two different microstructures with very fine γ grains can be obtianed by the thermomechanical treatments; One has both very fine γ and α grains, and the other has very fine γ and large α grains. The specimens were prepared in quenched and aged (475degC) conditions. The results obtained are as follows. The 0.2 % proof stress and tensile strength increase with the aging at 475degC for all specimens. The refinement of the γ grains plays an important role for the increase of strength in both quenched and aged conditions, and also for the ductility in the quenched condition. The refinement of α grains, however, contributes to the increase of the ductility in the aged condition. Accordingly, it is found that very good combinations of tensile strength and ductility can be achieved by the aging and the refinement of the γ and α grains (micro duplex structure). (author)

  20. Two different zinc sites in bovine 5-aminolevulinate dehydratase distinguished by extended x-ray absorption fine structure

    International Nuclear Information System (INIS)

    Dent, A.J.; Hasnain, S.S.; Beyersmann, D.; Block, C.

    1990-01-01

    The zinc coordination in 5-aminolevulinate dehydratase was investigated by extended x-ray absorption fine structure (EXAFS) associated with the zinc K-edge. The enzyme binds 8 mol of zinc/mol of octameric protein, but only four zinc ions seem sufficient for full activity. The authors have undertaken a study on four forms of the enzyme: (a) the eight-zinc native enzyme; (b) the enzyme with only the four zinc sites necessary for full activation occupied; (c) the enzyme with the vacant sites of (b) occupied by four lead ions; (d) the product complex between (b) and porphobilinogen. They have shown that two structurally distinct types of zinc sites are available in the enzyme. The site necessary for activity has an average zinc environment best described by two/three histidines and one/zero oxygen from a group such as tyrosine or a solvent molecule at 2.06 ± 0.02 angstrom, one tyrosine or aspartate at 1.91 ± 0.03 angstrom, and one cysteine sulfur at 2.32 ± 0.03 angstrom with a total coordination of five ligands. The unoccupied site in (b) is dominated by a single contribution of four cysteinyl sulfur atoms at 2.28 ± 0.02 angstrom. Spectra from samples (c) and (d) show only small changes from that of (b), reflecting a slight rearrangement of the ligands around the zinc atom

  1. R-matrix calculations for electron-impact excitation of C(+), N(2+), and O(3+) including fine structure

    Science.gov (United States)

    Luo, D.; Pradhan, A. K.

    1990-01-01

    The new R-matrix package for comprehensive close-coupling calculations for electron scattering with the first three ions in the boron isoelectronic sequence, the astrophysically significant C(+), N(2+), and O(3+), is presented. The collision strengths are calculated in the LS coupling approximation, as well as in pair-coupling scheme, for the transitions among the fine-structure sublevels. Calculations are carried out at a large number of energies in order to study the detailed effects of autoionizing resonances.

  2. Higher fine-scale genetic structure in peripheral than in core populations of a long-lived and mixed-mating conifer--eastern white cedar (Thuja occidentalis L.).

    Science.gov (United States)

    Pandey, Madhav; Rajora, Om P

    2012-04-05

    Fine-scale or spatial genetic structure (SGS) is one of the key genetic characteristics of plant populations. Several evolutionary and ecological processes and population characteristics influence the level of SGS within plant populations. Higher fine-scale genetic structure may be expected in peripheral than core populations of long-lived forest trees, owing to the differences in the magnitude of operating evolutionary and ecological forces such as gene flow, genetic drift, effective population size and founder effects. We addressed this question using eastern white cedar (Thuja occidentalis) as a model species for declining to endangered long-lived tree species with mixed-mating system. We determined the SGS in two core and two peripheral populations of eastern white cedar from its Maritime Canadian eastern range using six nuclear microsatellite DNA markers. Significant SGS ranging from 15 m to 75 m distance classes was observed in the four studied populations. An analysis of combined four populations revealed significant positive SGS up to the 45 m distance class. The mean positive significant SGS observed in the peripheral populations was up to six times (up to 90 m) of that observed in the core populations (15 m). Spatial autocorrelation coefficients and correlograms of single and sub-sets of populations were statistically significant. The extent of within-population SGS was significantly negatively correlated with all genetic diversity parameters. Significant heterogeneity of within-population SGS was observed for 0-15 m and 61-90 m between core and peripheral populations. Average Sp, and gene flow distances were higher in peripheral (Sp = 0.023, σg = 135 m) than in core (Sp = 0.014, σg = 109 m) populations. However, the mean neighborhood size was higher in the core (Nb = 82) than in the peripheral (Nb = 48) populations. Eastern white cedar populations have significant fine-scale genetic structure at short distances. Peripheral populations have several

  3. Formation of fine aggregate structure by solid-state displacement reaction of Ti with CoO or NiO. CoO oyobi NiO to Ti kan no koso chikan hanno ni yoru bisai fukugo soshiki no seisei

    Energy Technology Data Exchange (ETDEWEB)

    Taimatsu, H; Kaneko, H [Akita Univ., Akita (Japan). Mining College; Wada, K [Akita Univ., Akita (Japan). Graduate School

    1992-09-20

    As a result of search for systems which have aggregate structures, the displacement reaction products of Ti with CoO or NiO are found to have aggregate structures in which the produced oxides and metals are entangled with each other. The displacement reaction of Ti with CoO or NiO is investigated at the temperature of 1273K. In the reaction of either couple, aggregate products are produced, and reacted layer is observed in the TiO2 matrix wherein Co or Ni phases are three dimensionally entangled in finely dispersed state of micron order. 2 layers of cavitated and dense TiO2 layers are found in the reacted layer. The thicknesses of the reacted layer are not constant according to locations, but thick portions are grown obeying the parabolic rate law. As a result of the study on the possibility of fabricating cermet by the reaction between powders, finely mixed characteristic structures are found to be easily obtained using systems which can produce aggregate structures. 24 refs., 9 figs.

  4. Fine structure characterization of martensite/austenite constituent in low-carbon low-alloy steel by transmission electron forward scatter diffraction.

    Science.gov (United States)

    Li, C W; Han, L Z; Luo, X M; Liu, Q D; Gu, J F

    2016-11-01

    Transmission electron forward scatter diffraction and other characterization techniques were used to investigate the fine structure and the variant relationship of the martensite/austenite (M/A) constituent of the granular bainite in low-carbon low-alloy steel. The results demonstrated that the M/A constituents were distributed in clusters throughout the bainitic ferrite. Lath martensite was the main component of the M/A constituent, where the relationship between the martensite variants was consistent with the Nishiyama-Wassermann orientation relationship and only three variants were found in the M/A constituent, suggesting that the variants had formed in the M/A constituent according to a specific mechanism. Furthermore, the Σ3 boundaries in the M/A constituent were much longer than their counterparts in the bainitic ferrite region. The results indicate that transmission electron forward scatter diffraction is an effective method of crystallographic analysis for nanolaths in M/A constituents. © 2016 The Authors Journal of Microscopy © 2016 Royal Microscopical Society.

  5. Annealing induced atomic rearrangements on (Ga,In) (N,As) probed by hard X-ray photoelectron spectroscopy and X-ray absorption fine structure.

    Science.gov (United States)

    Ishikawa, Fumitaro; Higashi, Kotaro; Fuyuno, Satoshi; Morifuji, Masato; Kondow, Masahiko; Trampert, Achim

    2018-04-13

    We study the effects of annealing on (Ga 0.64 ,In 0.36 ) (N 0.045 ,As 0.955 ) using hard X-ray photoelectron spectroscopy and X-ray absorption fine structure measurements. We observed surface oxidation and termination of the N-As bond defects caused by the annealing process. Specifically, we observed a characteristic chemical shift towards lower binding energies in the photoelectron spectra related to In. This phenomenon appears to be caused by the atomic arrangement, which produces increased In-N bond configurations within the matrix, as indicated by the X-ray absorption fine structure measurements. The reduction in the binding energies of group-III In, which occurs concomitantly with the atomic rearrangements of the matrix, causes the differences in the electronic properties of the system before and after annealing.

  6. Fine-scale spatial genetic structure in predominantly selfing plants with limited seed dispersal: A rule or exception?

    Directory of Open Access Journals (Sweden)

    Sergei Volis

    2016-04-01

    Full Text Available Gene flow at a fine scale is still poorly understood despite its recognized importance for plant population demographic and genetic processes. We tested the hypothesis that intensity of gene flow will be lower and strength of spatial genetic structure (SGS will be higher in more peripheral populations because of lower population density. The study was performed on the predominantly selfing Avena sterilis and included: (1 direct measurement of dispersal in a controlled environment; and (2 analyses of SGS in three natural populations, sampled in linear transects at fixed increasing inter-plant distances. We found that in A. sterilis major seed dispersal is by gravity in close (less than 2 m vicinity of the mother plant, with a minor additional effect of wind. Analysis of SGS with six nuclear SSRs revealed a significant autocorrelation for the distance class of 1 m only in the most peripheral desert population, while in the two core populations with Mediterranean conditions, no genetic structure was found. Our results support the hypothesis that intensity of SGS increases from the species core to periphery as a result of decreased within-population gene flow related to low plant density. Our findings also show that predominant self-pollination and highly localized seed dispersal lead to SGS at a very fine scale, but only if plant density is not too high.

  7. Structural investigations of LiFePO4 electrodes and in situ studies by Fe X-ray absorption spectroscopy

    International Nuclear Information System (INIS)

    Deb, Aniruddha; Bergmann, Uwe; Cramer, S.P.; Cairns, Elton J.

    2005-01-01

    Fe K-edge X-ray absorption near edge spectroscopy (XANES) and extended X-ray absorption fine structure (EXAFS) have been performed on electrodes containing LiFePO 4 to determine the local atomic and electronic structure and their stability with electrochemical cycling. A versatile electrochemical in situ cell has been constructed for long-term soft and hard X-ray experiments for the structural investigation on battery electrodes during the lithium-insertion/extraction processes. The device is used here for an X-ray absorption spectroscopic study of lithium insertion/extraction in a LiFePO 4 electrode, where the electrode contained about 7.7 mg of LiFePO 4 on a 20 μm thick Al-foil. Fe K-edge X-ray absorption near edge spectroscopy (XANES) and extended X-ray absorption fine structure (EXAFS) have been performed on this electrode to determine the local atomic and electronic structure and their stability with electrochemical cycling. The initial state (LiFePO 4 ) showed iron to be in the Fe 2+ state corresponding to the initial state (0.0 mAh) of the cell, whereas in the delithiated state (FePO 4 ) iron was found to be in the Fe 3+ state corresponding to the final charged state (3 mAh). XANES region of the XAS spectra revealed a high spin configuration for the two states (Fe (II), d 6 and Fe (III), d 5 ). The results confirm that the olivine structure of the LiFePO 4 and FePO 4 is retained by the electrodes in agreement with the XRD observations reported previously. These results confirm that LiFePO 4 cathode material retains good structural short-range order leading to superior cycling capability

  8. Sequence of structures in fine-grained turbidites: Comparison of recent deep-sea and ancient flysch sediments

    Science.gov (United States)

    Stow, Dorrik A. V.; Shanmugam, Ganapathy

    1980-01-01

    A comparative study of the sequence of sedimentary structures in ancient and modern fine-grained turbidites is made in three contrasting areas. They are (1) Holocene and Pleistocene deep-sea muds of the Nova Scotian Slope and Rise, (2) Middle Ordovician Sevier Shale of the Valley and Ridge Province of the Southern Appalachians, and (3) Cambro-Ordovician Halifax Slate of the Meguma Group in Nova Scotia. A standard sequence of structures is proposed for fine-grained turbidites. The complete sequence has nine sub-divisions that are here termed T 0 to T 8. "The lower subdivision (T 0) comprises a silt lamina which has a sharp, scoured and load-cast base, internal parallel-lamination and cross-lamination, and a sharp current-lineated or wavy surface with 'fading-ripples' (= Type C etc. …)." (= Type C ripple-drift cross-lamination, Jopling and Walker, 1968). The overlying sequence shows textural and compositional grading through alternating silt and mud laminae. A convolute-laminated sub-division (T 1) is overlain by low-amplitude climbing ripples (T 2), thin regular laminae (T 3), thin indistinct laminae (T 4), and thin wipsy or convolute laminae (T 5). The topmost three divisions, graded mud (T 6), ungraded mud (T 7) and bioturbated mud (T 8), do not have silt laminae but rare patchy silt lenses and silt pseudonodules and a thin zone of micro-burrowing near the upper surface. The proposed sequence is analogous to the Bouma (1962) structural scheme for sandy turbidites and is approximately equivalent to Bouma's (C)DE divisions. The repetition of partial sequences characterizes different parts of the slope/base-of-slope/basin plain environment, and represents deposition from different stages of evolution of a large, muddy, turbidity flow. Microstructural detail and sequence are well preserved in ancient and even slightly metamorphosed sediments. Their recognition is important for determining depositional processes and for palaeoenvironmental interpretation.

  9. Fine resolution mapping of population age-structures for health and development applications.

    Science.gov (United States)

    Alegana, V A; Atkinson, P M; Pezzulo, C; Sorichetta, A; Weiss, D; Bird, T; Erbach-Schoenberg, E; Tatem, A J

    2015-04-06

    The age-group composition of populations varies considerably across the world, and obtaining accurate, spatially detailed estimates of numbers of children under 5 years is important in designing vaccination strategies, educational planning or maternal healthcare delivery. Traditionally, such estimates are derived from population censuses, but these can often be unreliable, outdated and of coarse resolution for resource-poor settings. Focusing on Nigeria, we use nationally representative household surveys and their cluster locations to predict the proportion of the under-five population in 1 × 1 km using a Bayesian hierarchical spatio-temporal model. Results showed that land cover, travel time to major settlements, night-time lights and vegetation index were good predictors and that accounting for fine-scale variation, rather than assuming a uniform proportion of under 5 year olds can result in significant differences in health metrics. The largest gaps in estimated bednet and vaccination coverage were in Kano, Katsina and Jigawa. Geolocated household surveys are a valuable resource for providing detailed, contemporary and regularly updated population age-structure data in the absence of recent census data. By combining these with covariate layers, age-structure maps of unprecedented detail can be produced to guide the targeting of interventions in resource-poor settings.

  10. Simulation of Probe Position-Dependent Electron Energy-Loss Fine Structure

    Energy Technology Data Exchange (ETDEWEB)

    Oxley, M. P.; Kapetanakis, M. D.; Prange, Micah P.; Varela, M.; Pennycook, Stephen J.; Pantelides, Sokrates T.

    2014-03-31

    We present a theoretical framework for calculating probe-position-dependent electron energy-loss near-edge structure for the scanning transmission electron microscope by combining density functional theory with dynamical scattering theory. We show how simpler approaches to calculating near-edge structure fail to include the fundamental physics needed to understand the evolution of near-edge structure as a function of probe position and investigate the dependence of near-edge structure on probe size. It is within this framework that density functional theory should be presented, in order to ensure that variations of near-edge structure are truly due to local electronic structure and how much from the diffraction and focusing of the electron beam.

  11. A cell for extended x-ray absorption fine structure studies of oxygen sensitive products of redox reactions

    International Nuclear Information System (INIS)

    Furenlid, L.R.; Renner, M.W.; Fajer, J.

    1990-01-01

    We describe a cell suitable for extended x-ray absorption fine structure (EXAFS) studies of oxygen and/or water sensitive products of redox reactions. The cell utilizes aluminized Mylar windows that are transparent to x rays, provide low gas permeability, and allow vacuum to be maintained in the cell. The windows are attached to the glassware with an epoxy that resists attack by common organic solvents. Additional side arms allow multiple spectroscopic probes of the same sample under anaerobic and anhydrous conditions

  12. Applications of x ray absorption fine structure to the in situ study of the effect of cobalt in nickel hydrous oxide electrodes for fuel cells and rechargeable batteries

    Science.gov (United States)

    Kim, Sunghyun; Tryk, Donald A.; Scherson, Daniel A.; Antonio, Mark R.

    1993-01-01

    Electronic and structural aspects of composite nickel-cobalt hydrous oxides have been examined in alkaline solutions using in situ X-ray absorption fine structure (XAFS). The results obtained have indicated that cobalt in this material is present as cobaltic ions regardless of the oxidation state of nickel in the lattice. Furthermore, careful analysis of the Co K-edge Extended X-ray absorption fine structure data reveals that the co-electrodeposition procedure generates a single phase, mixed metal hydrous oxide, in which cobaltic ions occupy nickel sites in the NiO2 sheet-like layers and not two intermixed phases each consisting of a single metal hydrous oxide.

  13. Fine structure of dielectric function of cadmium fluoride

    International Nuclear Information System (INIS)

    Kalugin, A.I.; Sobolev, V.V.

    2005-01-01

    Full text : The electric structure of solids has been extensively investigated for several decades within the density functional theory. However many problems are appeared. One of them, the problem of correct calculation of the transition matrix elements, is very important to calculate the optical properties of crystals. In many papers the results are obtained without taking into account the probabilities of transitions. The goal of this work is the calculation of spectrum with and without taking into account the matrix elements influence of matrix elements on the optical properties of cadmium fluoride. Also localizations of transitions in Brillouin Zone (BZ) were calculated. This work contains interesting information about the electronic structure of cadmium fluoride

  14. Early age shrinkage pattern of concrete on replacement of fine aggregate with industrial by-product

    Directory of Open Access Journals (Sweden)

    R.K. Mishra

    2016-10-01

    Full Text Available This is an experimental work carried out to investigate early age shrinkage pattern of concrete, prepared, on 50% replacement of industrial by-product (like pond ash and granulated blast furnace slag as fine aggregate using OPC, PPC and PSC as a binder. This is to observe the effect of pond ash and slag as they are having some cementitious properties and effect of cement type is also discussed. All the mixes were prepared keeping in view of pumpable concrete without any super plasticizers. Higher shrinkage value indicates the presence of more bleed water or internal moisture. It is concluded that slag is the best option for fine aggregate replacement for concrete making and durable structure.

  15. Size-dependent binding energies and fine-structure splitting of excitonic complexes in single InAs/GaAs quantum dots

    International Nuclear Information System (INIS)

    Rodt, S.; Seguin, R.; Schliwa, A.; Guffarth, F.; Poetschke, K.; Pohl, U.W.; Bimberg, D.

    2007-01-01

    A systematic study of excitonic complexes confined in single InAs/GaAs quantum dots is presented. Emphasis is placed on the recombination energies of the excitonic complexes and on the fine-structure splitting of the bright exciton ground state. The values depend in a characteristic way on the size of the respective quantum dot which controls the number of bound hole states and the piezoelectric potential

  16. Performance of concrete with partial replacement of fine aggregates ...

    African Journals Online (AJOL)

    The study investigated the level of replacement of fine aggregate with waste glass that will result in optimal compressive strength. A total of 36 cubes were cast. 6 cubes without waste glass (control) and 30 cubes containing waste glass as partial replacement for fine aggregates at 15%, 25%, 35%, 45%, and 50%.

  17. Fine-Scale Human Population Structure in Southern Africa Reflects Ecogeographic Boundaries.

    Science.gov (United States)

    Uren, Caitlin; Kim, Minju; Martin, Alicia R; Bobo, Dean; Gignoux, Christopher R; van Helden, Paul D; Möller, Marlo; Hoal, Eileen G; Henn, Brenna M

    2016-09-01

    Recent genetic studies have established that the KhoeSan populations of southern Africa are distinct from all other African populations and have remained largely isolated during human prehistory until ∼2000 years ago. Dozens of different KhoeSan groups exist, belonging to three different language families, but very little is known about their population history. We examine new genome-wide polymorphism data and whole mitochondrial genomes for >100 South Africans from the ≠Khomani San and Nama populations of the Northern Cape, analyzed in conjunction with 19 additional southern African populations. Our analyses reveal fine-scale population structure in and around the Kalahari Desert. Surprisingly, this structure does not always correspond to linguistic or subsistence categories as previously suggested, but rather reflects the role of geographic barriers and the ecology of the greater Kalahari Basin. Regardless of subsistence strategy, the indigenous Khoe-speaking Nama pastoralists and the N|u-speaking ≠Khomani (formerly hunter-gatherers) share ancestry with other Khoe-speaking forager populations that form a rim around the Kalahari Desert. We reconstruct earlier migration patterns and estimate that the southern Kalahari populations were among the last to experience gene flow from Bantu speakers, ∼14 generations ago. We conclude that local adoption of pastoralism, at least by the Nama, appears to have been primarily a cultural process with limited genetic impact from eastern Africa. Copyright © 2016 by the Genetics Society of America.

  18. Bloch oscillations of ultracold atoms and measurement of the fine structure constant

    International Nuclear Information System (INIS)

    Clade, P.

    2005-10-01

    From a measurement of the recoil velocity of an atom absorbing a photon, it is possible to deduce a determination of the ratio h/m between the Planck constant and the mass of the atoms and then to deduce a value of the fine structure constant alpha. To do this measurement, we use the technique of Bloch oscillations, which allows us to transfer a large number of recoils to atoms. A velocity sensor, based on velocity selective Raman transition, enables us to measure the momentum transferred to the atoms. A measurement with a statistical uncertainty of 4.4 10 -9 , in conjunction with a careful study of systematic effects (5 10 -9 ), has led us to a determination of alpha with an uncertainty of 6.7 10 -9 : α -1 (Rb) = 137.03599878 (91). This uncertainty is similar to the uncertainty of the best determinations of alpha based on atom interferometry. (author)

  19. Fine-structure resolved rotational transitions and database for CN+H2 collisions

    Science.gov (United States)

    Burton, Hannah; Mysliwiec, Ryan; Forrey, Robert C.; Yang, B. H.; Stancil, P. C.; Balakrishnan, N.

    2018-06-01

    Cross sections and rate coefficients for CN+H2 collisions are calculated using the coupled states (CS) approximation. The calculations are benchmarked against more accurate close-coupling (CC) calculations for transitions between low-lying rotational states. Comparisons are made between the two formulations for collision energies greater than 10 cm-1. The CS approximation is used to construct a database which includes highly excited rotational states that are beyond the practical limitations of the CC method. The database includes fine-structure resolved rotational quenching transitions for v = 0 and j ≤ 40, where v and j are the vibrational and rotational quantum numbers of the initial state of the CN molecule. Rate coefficients are computed for both para-H2 and ortho-H2 colliders. The results are shown to be in good agreement with previous calculations, however, the rates are substantially different from mass-scaled CN+He rates that are often used in astrophysical models.

  20. Formation of cellular structure in beryllium at plastic working

    International Nuclear Information System (INIS)

    Papirov, I.I.; Nikolaenko, A.A.; Shokurov, V.S.; Pikalov, A.I.

    2013-01-01

    Conditions of cellular structure formation are investigated at various kinds of deformation and heat treatment of beryllium ingots. It is shown that the cellular structure plays the important role in formation of complex of physical mechanical properties of beryllium. Influence of impurity, various conditions of deformation (temperature, squeezing degree) and heat treatments on substructure, texture and mechanical properties of metal is investigated. Optimum conditions of rolling and heat treatments of beryllium are defined. The way of sign-variable cyclic deformation of beryllium ingots is offered for reception quasi-isotropic fine-grained metal. Physical-mechanical properties of ultra fine-grained metal are studied

  1. Origin of fine oscillations in the photoluminescence spectrum of 2-dimensional electron gas formed in AlGaN/GaN high electron mobility transistor structures

    Energy Technology Data Exchange (ETDEWEB)

    Jana, Dipankar, E-mail: dip2602@gmail.com; Porwal, S.; Oak, S. M.; Sharma, T. K., E-mail: tarun@rrcat.gov.in [Semiconductor Physics and Devices Laboratory, Raja Ramanna Centre for Advanced Technology, Indore 452013, Madhya Pradesh (India); Jain, Anubha [Solid State Physics Laboratory, Lucknow Road, New Delhi 110054 (India)

    2015-10-28

    An unambiguous identification of the fine oscillations observed in the low temperature photoluminescence (PL) spectra of AlGaN/GaN based high electron mobility transistor (HEMT) structures is carried out. In literature, such oscillations have been erroneously identified as the sub-levels of 2-dimensional electron gas (2DEG) formed at AlGaN/GaN heterointerface. Here, the origin of these oscillations is probed by performing the angle dependent PL and reflectivity measurements under identical conditions. Contrary to the reports available in literature, we find that the fine oscillations are not related to 2DEG sub-levels. The optical characteristics of these oscillations are mainly governed by an interference phenomenon. In particular, peculiar temperature dependent redshift and excitation intensity dependent blueshift, which have been interpreted as the characteristics of 2DEG sub-levels in HEMT structures by other researchers, are understood by invoking the wavelength and temperature dependence of the refractive index of GaN within the framework of interference phenomenon. The results of other researchers are also consistently explained by considering the fine oscillatory features as the interference oscillations.

  2. Apparent wavelength shifts of H-like ions caused by the spectral fine structure observed in CHS plasmas

    International Nuclear Information System (INIS)

    Nishimura, Shin; Ida, Katsumi

    1998-01-01

    A new charge exchange spectroscopy (CXS) system viewing the plasma from the upside and the downside simultaneously was installed on the Compact Helical System (CHS) to detect the absolute value of Doppler shift due to poloidal rotation velocity ( i ∼ 100 eV) and in the after-glow recombining phase (T i ∼ 30 eV). The apparent Doppler shift is always red-shift regardless the direction of plasma rotation and is explained as the effect of the spectral fine structure of hydrogen-like ions. (author)

  3. Near-Edge X-ray Absorption Fine Structure Spectroscopy of Diamondoid Thiol Monolayers on Gold

    Energy Technology Data Exchange (ETDEWEB)

    Willey, T M; Fabbri, J; Lee, J I; Schreiner, P; Fokin, A A; Tkachenko, B A; Fokina, N A; Dahl, J; Carlson, B; Vance, A L; Yang, W; Terminello, L J; van Buuren, T; Melosh, N

    2007-11-27

    Diamondoids, hydrocarbon molecules with cubic-diamond-cage structures, have unique properties with potential value for nanotechnology. The availability and ability to selectively functionalize this special class of nanodiamond materials opens new possibilities for surface-modification, for high-efficiency field emitters in molecular electronics, as seed crystals for diamond growth, or as robust mechanical coatings. The properties of self-assembled monolayers (SAMs) of diamondoids are thus of fundamental interest for a variety of emerging applications. This paper presents the effects of thiol substitution position and polymantane order on diamondoid SAMs on gold using near-edge X-ray absorption fine structure spectroscopy (NEXAFS) and X-ray photoelectron spectroscopy (XPS). A framework to determine both molecular tilt and twist through NEXAFS is presented and reveals highly ordered diamondoid SAMs, with the molecular orientation controlled by the thiol location. C 1s and S 2p binding energies are lower in adamantane thiol than alkane thiols on gold by 0.67 {+-} 0.05 eV and 0.16 {+-} 0.04 eV respectively. These binding energies vary with diamondoid monolayer structure and thiol substitution position, consistent with different amounts of steric strain and electronic interaction with the substrate. This work demonstrates control over the assembly, in particular the orientational and electronic structure, providing a flexible design of surface properties with this exciting new class of diamond clusters.

  4. The Fine Transverse Structure of a Vortex Flow Beyond the Edge of a Disc Rotating in a Stratified Fluid

    Science.gov (United States)

    Chashechkin, Yu. D.; Bardakov, R. N.

    2018-02-01

    By the methods of schlieren visualization, the evolution of elements of the fine structure of transverse vortex loops formed in the circular vortex behind the edge of a disk rotating in a continuously stratified fluid is traced for the first time. An inhomogeneous distribution of the density of a table-salt solution in a basin was formed by the continuous-squeezing method. The development of periodic perturbations at the outer boundary of the circular vortex and their transformation at the vortex-loop vertex are traced. A slow change in the angular size of the structural elements in the supercritical-flow mode is noted.

  5. Higher fine-scale genetic structure in peripheral than in core populations of a long-lived and mixed-mating conifer - eastern white cedar (Thuja occidentalis L.)

    Science.gov (United States)

    2012-01-01

    Background Fine-scale or spatial genetic structure (SGS) is one of the key genetic characteristics of plant populations. Several evolutionary and ecological processes and population characteristics influence the level of SGS within plant populations. Higher fine-scale genetic structure may be expected in peripheral than core populations of long-lived forest trees, owing to the differences in the magnitude of operating evolutionary and ecological forces such as gene flow, genetic drift, effective population size and founder effects. We addressed this question using eastern white cedar (Thuja occidentalis) as a model species for declining to endangered long-lived tree species with mixed-mating system. Results We determined the SGS in two core and two peripheral populations of eastern white cedar from its Maritime Canadian eastern range using six nuclear microsatellite DNA markers. Significant SGS ranging from 15 m to 75 m distance classes was observed in the four studied populations. An analysis of combined four populations revealed significant positive SGS up to the 45 m distance class. The mean positive significant SGS observed in the peripheral populations was up to six times (up to 90 m) of that observed in the core populations (15 m). Spatial autocorrelation coefficients and correlograms of single and sub-sets of populations were statistically significant. The extent of within-population SGS was significantly negatively correlated with all genetic diversity parameters. Significant heterogeneity of within-population SGS was observed for 0-15 m and 61-90 m between core and peripheral populations. Average Sp, and gene flow distances were higher in peripheral (Sp = 0.023, σg = 135 m) than in core (Sp = 0.014, σg = 109 m) populations. However, the mean neighborhood size was higher in the core (Nb = 82) than in the peripheral (Nb = 48) populations. Conclusion Eastern white cedar populations have significant fine-scale genetic structure at short distances. Peripheral

  6. Higher fine-scale genetic structure in peripheral than in core populations of a long-lived and mixed-mating conifer - eastern white cedar (Thuja occidentalis L.

    Directory of Open Access Journals (Sweden)

    Pandey Madhav

    2012-04-01

    Full Text Available Abstract Background Fine-scale or spatial genetic structure (SGS is one of the key genetic characteristics of plant populations. Several evolutionary and ecological processes and population characteristics influence the level of SGS within plant populations. Higher fine-scale genetic structure may be expected in peripheral than core populations of long-lived forest trees, owing to the differences in the magnitude of operating evolutionary and ecological forces such as gene flow, genetic drift, effective population size and founder effects. We addressed this question using eastern white cedar (Thuja occidentalis as a model species for declining to endangered long-lived tree species with mixed-mating system. Results We determined the SGS in two core and two peripheral populations of eastern white cedar from its Maritime Canadian eastern range using six nuclear microsatellite DNA markers. Significant SGS ranging from 15 m to 75 m distance classes was observed in the four studied populations. An analysis of combined four populations revealed significant positive SGS up to the 45 m distance class. The mean positive significant SGS observed in the peripheral populations was up to six times (up to 90 m of that observed in the core populations (15 m. Spatial autocorrelation coefficients and correlograms of single and sub-sets of populations were statistically significant. The extent of within-population SGS was significantly negatively correlated with all genetic diversity parameters. Significant heterogeneity of within-population SGS was observed for 0-15 m and 61-90 m between core and peripheral populations. Average Sp, and gene flow distances were higher in peripheral (Sp = 0.023, σg = 135 m than in core (Sp = 0.014, σg = 109 m populations. However, the mean neighborhood size was higher in the core (Nb = 82 than in the peripheral (Nb = 48 populations. Conclusion Eastern white cedar populations have significant fine-scale genetic structure at short

  7. Fine Structure of the Core of the Blazar OJ 287-I

    Science.gov (United States)

    Matveyenko, L. I.; Sivakon', S. S.

    2017-12-01

    The fine structure of the active region, the bulge, of the blazar OJ 287 has been investigated with a resolution of 20 μas (0.1 pc) at a wavelength of 7 mm, the epochs of 2007-2017. The structure and kinematics correspond to a vortex nature. The surrounding matter, the plasma, is transferred to the center along two arms from opposite directions. The emerging excess angular momentum is carried away along the rotation axis by bipolar outflows, rotating coaxial tubes, in a direction X ≈ -120° in the plane of the sky as it is accumulated. The central high-velocity bipolar outflow has a helical shape. The diameters of the low-velocity flows are ø1 ≈ 0.3 and ø2 ≈ 0.65 mas, or 1.4 and 3 pc, respectively. Ring currents whose tangential directions are observed as parallel chains of components are excited in the flow walls. The peak brightness temperature of the nozzle reaches Tb ≈ 1012-1013 K. A "disk" with a diameter ø ≈ 0.5 mas (≈2.2 pc) is observed by the absorption of synchrotron radiation. The disk is inclined to the plane of the sky at an angle of 60° in the jet direction. The fragments are seen from a distance of ˜0.2 mas outside the absorption zone. The jet sizes exceed considerably the counterjet ones. An enhanced supply of plasma from the northern arm gives rise to an independent vortex 0.2 mas away from the central one in the NW direction. As in the first case, the helical central bipolar outflow is surrounded by a low-velocity component ø ≈ 0.28 mas in diameter with built-in ring currents. The jet is ejected in the direction X = -50° in the plane of the sky. The jet orientation changes, X = -130° at a distance of 1 mas. A high activity of the central and two side nozzles spaced 0.22 mas apart in the direction X = -40° is occasionally observed simultaneously. The active region of the blazar is observed through an ionized medium, a screen, whose influence is significant even at a wavelength of 7 mm. The absorption and refraction of the

  8. Probing the KII 3p54p fine structure by photoelectron spectroscopy of laser-excited potassium

    International Nuclear Information System (INIS)

    Meyer, M; Cubaynes, D; Wuilleumier, F J; Heinecke, E; Richter, T; Zimmermann, P; Strakhova, S I; Grum-Grzhimailo, A N

    2006-01-01

    Photoelectron spectra of atomic potassium excited by laser optical pumping into the 3p 6 4p 2 P 1/2 and 2 P 3/2 states are measured with high-energy resolution. The relative intensities of the 3p 5 4p fine-structure lines depend strongly on the initial excitation to one of the 4p spin-orbit components. Similar to the case of sodium, dynamically and quasiforbidden transitions are observed in the photoelectron spectra of potassium. The theoretical predictions of the generalized geometrical model are in excellent agreement with the experimental data. (letter to the editor)

  9. On mill flow rate and fineness control in cement grinding circuits: instability and delayed measurements

    International Nuclear Information System (INIS)

    Lepore, R.; Boulvin, M.; Renotte, C.; Remy, M.

    1999-01-01

    A control structure for the mill flow rate and the product fineness is designed, with the feed flow rate and the classifier characteristic as the manipulated variables. Experimental results from a plant highlight the instability of the grinding circuit. A model previously developed by the authors stresses the major influence of the classifier nonlinearities onto this instability. A cascade control structure has been designed and implemented on site. The measurements of the product fineness, sensitive to material grindability fluctuations, are randomly time-delayed. The control structure uses a fineness estimator based on an adaptive scheme and a time delay compensator. (author)

  10. Compressive strength and resistance to chloride ion penetration and carbonation of recycled aggregate concrete with varying amount of fly ash and fine recycled aggregate.

    Science.gov (United States)

    Sim, Jongsung; Park, Cheolwoo

    2011-11-01

    Construction and demolition waste has been dramatically increased in the last decade, and social and environmental concerns on the recycling have consequently been increased. Recent technology has greatly improved the recycling process for waste concrete. This study investigates the fundamental characteristics of concrete using recycled concrete aggregate (RCA) for its application to structural concrete members. The specimens used 100% coarse RCA, various replacement levels of natural aggregate with fine RCA, and several levels of fly ash addition. Compressive strength of mortar and concrete which used RCA gradually decreased as the amount of the recycled materials increased. Regardless of curing conditions and fly ash addition, the 28 days strength of the recycled aggregate concrete was greater than the design strength, 40 MPa, with a complete replacement of coarse aggregate and a replacement level of natural fine aggregate by fine RCA up to 60%. The recycled aggregate concrete achieved sufficient resistance to the chloride ion penetration. The measured carbonation depth did not indicate a clear relationship to the fine RCA replacement ratio but the recycled aggregate concrete could also attain adequate carbonation resistance. Based on the results from the experimental investigations, it is believed that the recycled aggregate concrete can be successfully applied to structural concrete members. Copyright © 2011 Elsevier Ltd. All rights reserved.

  11. Ultra-fine structures of Pd-Ag-HAp nanoparticle deposition on protruded TiO2 barrier layer for dental implant

    Science.gov (United States)

    Jang, Jae-Myung; Kim, Seung-Dai; Park, Tae-Eon; Choe, Han-Cheol

    2018-02-01

    The biocompatibility structure of an implant surface is of great importance to the formation of new bone tissue around the dental implant and also has a significant chemical reaction in the osseointegration process. Thus, ultra-fine Pd-Ag-HAp nanoparticles have been electrodeposited on protruded TiO2 barrier layer in mixed electrolyte solutions. Unusual protrusions patterns, which are assigned to Pd-Ag-HAp nanoparticles, can be clearly differentiated from a TiO2 nanotube oxide layer formed by an anodizing process. In the chemical bonding state, the surface characteristics of Pd/Ag/HAp compounds have been investigated by FE-SEM, EDS mapping analysis, and XPS analysis. The mapping dots of the elements including Ti, Ca, Pd, Ag, and P showed a homogeneous distribution throughout the entire surface when deposited onto the protruded TiO2 barrier layer. The XPS spectra of Ti-2p, O-1S, Pd-3d, and Ag-3d have been investigated, with the major XPS peak indicating Pd-3d. The Ag-3d level was clearly observed with further scanning of the Ca-2p region. Based on the results of the chemical states, the structural properties of the protrusion patterns were also examined after being deposited onto the barrier oxide film, resulting in the representative protrusion patterns being mainly composed of Pd-Ag-HAp compounds. The results of the soaking evaluation showed that the protrusion patterns and the protruded TiO2 barrier layer were all effective in regards to biocompatibility.

  12. Fine Structure Intervals ‎ ‎-‎ ‎ , ‎ ‎-‎ ‎ and ‎Electric Dipole Transition Rate ‎ ‎-‎ ‎ in ‎Phosphorus Isoelectronic Sequence ‎ ‎ ‎And Phosphorus Ions

    Directory of Open Access Journals (Sweden)

    Adnan Yousif Hussein

    2017-11-01

    Full Text Available A systematic study for the calculation of the fine structure intervals -  and -   for the ground configuration 3s23p3 and the excited configuration 3s23p24s respectively, and electric dipole transition rate -  as well as transition energy form the excited configuration 3s23p24s to the ground configuration 3s23p3 in Phosphorus isoelectronic sequence by applying multi-configuration Dirac-Fock (MCDF method. The effect of Breit interaction, QED and correlation on the fine structure interval and the gauge invariance effect on the transition probability are studied. Also the fine structure intervals for the phosphorus ions from Piii to Pxv are calculated and are compared with the available experimental data and gives good consistent

  13. Fine structure of excitons and electron-hole exchange energy in polymorphic CsPbBr3 single nanocrystals.

    Science.gov (United States)

    Ramade, Julien; Andriambariarijaona, Léon Marcel; Steinmetz, Violette; Goubet, Nicolas; Legrand, Laurent; Barisien, Thierry; Bernardot, Frédérick; Testelin, Christophe; Lhuillier, Emmanuel; Bramati, Alberto; Chamarro, Maria

    2018-04-05

    All inorganic CsPbX3 (X = Cl, Br, I) nanocrystals (NCs) belong to the novel class of confined metal-halide perovskites which are currently arousing enthusiasm and stimulating huge activity across several fields of optoelectronics due to outstanding properties. A deep knowledge of the band-edge excitonic properties of these materials is thus crucial to further optimize their performances. Here, high-resolution photoluminescence (PL) spectroscopy of single bromide-based NCs reveals the exciton fine structure in the form of sharp peaks that are linearly polarized and grouped in doublets or triplets, which directly mirror the adopted crystalline structure, tetragonal (D4h symmetry) or orthorhombic (D2h symmetry). Intelligible equations are found that show how the fundamental parameters (spin-orbit coupling, ΔSO, crystal field term, T, and electron-hole exchange energy, J) rule the energy spacings in doublets and triplets. From experimental data, fine estimations of each parameter are obtained. The analysis of the absorption spectra of an ensemble of NCs with a "quasi-bulk" behavior leads to ΔSO = 1.20 ± 0.06 eV and T = -0.34 ± 0.05 eV in CsPbBr3. The study of individual luminescence responses of NCs having sizes comparable to the exciton Bohr diameter, 7 nm, allows us to estimate the value of J to be around ≈3 meV in both tetragonal and orthorhombic phases. This value is already enhanced by confinement.

  14. Fine-structure relaxation of O(3P) induced by collisions with He, H and H2

    Science.gov (United States)

    Lique, F.; Kłos, J.; Alexander, M. H.; Le Picard, S. D.; Dagdigian, P. J.

    2018-02-01

    The excitation of fine-structure levels of O(3P) by collisions is an important cooling process in the interstellar medium (ISM). We investigate here spin-orbit (de-)excitation of O(3Pj, j = 0, 1, 2) induced by collisions with He, H and H2 based on quantum scattering calculations of the relevant rate coefficients in the 10-1000 K temperature range. The underlying potential energy surfaces are derived from highly correlated abinitio calculations. Significant differences were found with the rate coefficients currently used in astrophysical applications. In particular, our new rate coefficients for collisions with H are up to a factor of 5 lower. Radiative transfer computations allow the assessment of the astrophysical impact of these new rate coefficients. In the case of molecular clouds, the new data are found to increase slightly the flux of the 3P1 → 3P2, while decreasing the flux of the 3P0 → 3P1 line. In the case of atomic clouds, the flux of both lines is predicted to decrease. The new rate coefficients are expected to impact significantly the modelling of cooling in astrophysical environments while also allowing new insights into oxygen chemistry in the ISM.

  15. Universal fine structure of the specific heat at the critical λ-point for an ideal Bose gas in an arbitrary trap

    International Nuclear Information System (INIS)

    Tarasov, S V; Kocharovsky, Vl V; Kocharovsky, V V

    2014-01-01

    We analytically find the universal fine structure of the noted discontinuity in the value and/or derivative of the specific heat of an ideal Bose gas in an arbitrary trap in the whole critical region around the λ-point of the Bose–Einstein condensation. The result reveals a remarkable dependence of the λ-point structure on the trap's form and boundary conditions, even for a macroscopically large system. We suggest measuring this strong effect in the experiments with a controllable trap potential. (paper)

  16. Taking action: A cross-modal investigation of discourse structure

    Directory of Open Access Journals (Sweden)

    Elsi eKaiser

    2012-06-01

    Full Text Available Segmenting stimuli into events and understanding the relations between those events is crucial for understanding the world. For example, on the linguistic level, successful language use requires the ability to recognize semantic coherence relations between events (e.g. causality, similarity. However, relatively little is known about the mental representation of discourse structure. We report two experiments that used a cross-modal priming paradigm to investigate how humans represent the relations between events. Participants repeated a motor action modeled by the experimenter (e.g. rolled a ball towards mini bowling pins to knock them over, and then completed an unrelated sentence-continuation task (e.g. provided a continuation for Peter scratched John. …. In two experiments, we tested whether and how the coherence relations represented by the motor actions (e.g., causal events vs. non-causal events influence participants’ performance in the linguistic task. Our analyses focused on the coherence relations between the prompt sentences and participants’ continuations, as well as the referential shifts in the continuations. As a whole, the results suggest that the mental representations activated by motor actions overlap with the mental representations used during linguistic discourse-level processing, but nevertheless contain fine-grained information about sub-types of causality (reaction vs. consequence. In addition, the findings point to parallels between shifting one’s attention from one event to another and shifting one’s attention from one referent to another, and indicate that the event structure of causal sequences is conceptualized more like single events than like two distinct events. As a whole, the results point towards common representations activated by motor sequences and discourse-semantic relations, and further our understanding of the mental representation of discourse structure, an area that is still not yet well-understood.

  17. Investigation of the possibility to use a fine-mesh solver for resolving coupled neutronics and thermal-hydraulics

    International Nuclear Information System (INIS)

    Jareteg, K.; Vinai, P.; Demaziere, C.

    2013-01-01

    The development of a fine-mesh coupled neutronic/thermal-hydraulic solver is touched upon in this paper. The reported work investigates the feasibility of using finite volume techniques to discretize a set of conservation equations modeling neutron transport, fluid dynamics, and heat transfer within a single numerical tool. With the long-term objective of developing fine-mesh computing capabilities for a few selected fuel assemblies in a nuclear core, this preliminary study considers an infinite array of a single fuel assembly having a finite height. Thermal-hydraulic conditions close to the ones existing in PWRs are taken as a first test case. The neutronic modeling relies on the diffusion approximation in a multi-energy group formalism, with cross-sections pre-calculated and tabulated at the sub-pin level using a Monte Carlo technique. The thermal-hydraulics is based on the Navier-Stokes equations, complemented by an energy conservation equation. The non-linear coupling terms between the different conservation equations are fully resolved using classical iteration techniques. Early tests demonstrate that the numerical tool provides an unprecedented level of details of the coupled solution estimated within the same numerical tool and thus avoiding any external data transfer, using fully consistent models between the neutronics and the thermal-hydraulics. (authors)

  18. Sahara Coal: the fine art of collecting fines for profit

    Energy Technology Data Exchange (ETDEWEB)

    Schreckengost, D.; Arnold, D.

    1984-09-01

    A considerable increase in the volume of fines in rom coal caused Sahara Coal in Illinois to redesign the fine coal system in their Harrisburg preparation plant. Details of the new design, and particularly the fine refuse system which dewaters and dries 28 mesh x O clean coal, are given. Results have exceeded expectations in reducing product losses, operating costs and slurry pond cleaning costs.

  19. Fine structure of the epidermal Leydig cells in the axolotl Ambystoma mexicanum in relation to their function.

    Science.gov (United States)

    Jarial, M S

    1989-01-01

    The fine structure of the Leydig cells in the epidermis of the strictly aquatic adult axolotl Ambystoma mexicanum resembles that of similar cells in larval salamanders. The major finding of this study is that the mucous secretion of the Leydig cells is released into the intercellular spaces from which it is discharged through pores onto the surface of the epidermis where it forms a mucous layer to protect the skin. Images Figs. 1-2 Fig. 3 Fig. 4 Fig. 5 Fig. 6 Fig. 7 Fig. 8 Fig. 9 Fig. 10 Figs. 11-13 PMID:2630544

  20. Ecosystem structure and function in the SPRUCE chambers at fine resolution

    Science.gov (United States)

    Glenn, N. F.; Graham, J.; Spaete, L.; Hanson, P. J.

    2017-12-01

    The Spruce and Peatland Responses Under Climatic and Environmental change (SPRUCE; operated by DOE's Oak Ridge National Laboratory) aims to assess biological and ecological responses in a peat bog to a range of increased temperatures and the presence of elevated atmospheric CO2 concentrations. We are using terrestrial laser scanning (TLS) to monitor vegetation productivity and hummock-hollow structure at cm-scale in the SPRUCE plots to complement in-situ measurements of gross and net primary production. The hummock-hollow peatland microtopography is associated with fluctuating water levels and sphagnum mosses, and ultimately controls C and methane cycling. We estimate tree growth by calculating increases in tree height and canopy voxel volume between years with the TLS data. Microtopography is also characterized over time with TLS but by using gridded cells to classify regions into hummocks or hollows. Spectroscopy to quantify water content in the sphagnum is used to further classify these microtopographic regions. As multiple years of data collection occur, we will couple our fine-scale remote sensing measurements with in-situ measurements of CO2 and CH4 flux measures to capture species-specific productivity responses to warming and increased CO2.

  1. The running fine structure constant α(E) via the Adler function

    International Nuclear Information System (INIS)

    Jegerlehner, F.

    2008-06-01

    We present an up-to-date analysis for a precise determination of the effective fine structure constant and discuss the prospects for future improvements. We advocate to use a determination monitored by the Adler function which allows us to exploit perturbative QCD in an optimal well controlled way. Together with a long term program of hadronic cross section measurements at energies up to a few GeV, a determination of α(M Z ) at a precision comparable to the one of the Z mass M Z should be feasible. Presently α(E) at E >1 GeV is the least precisely known of the fundamental parameters of the SM. Since, in spite of substantial progress due to new BaBar exclusive data, the region 1.4 to 2.4 GeV remains the most problematic one a major step in the reduction of the uncertainties are expected from VEPP-2000 and from a possible ''high-energy'' option DAFNE-2 at Frascati. The up-to-date evaluation reads Δ (5) had (M 2 Z )=0.027515±0.000149 or α -1 (M 2 Z )=128.957±0.020. (orig.)

  2. Adsorption of s-triazines onto polybenzimidazole: A quantitative structure-property relationship investigation

    Energy Technology Data Exchange (ETDEWEB)

    D' Archivio, Angelo Antonio, E-mail: angeloantonio.darchivio@univaq.it [Dipartimento di Chimica, Ingegneria Chimica e Materiali, Universita degli Studi dell' Aquila, Via Vetoio, 67010 Coppito, L' Aquila (Italy); Incani, Angela; Mazzeo, Pietro; Ruggieri, Fabrizio [Dipartimento di Chimica, Ingegneria Chimica e Materiali, Universita degli Studi dell' Aquila, Via Vetoio, 67010 Coppito, L' Aquila (Italy)

    2009-09-21

    The adsorption of 25 symmetric triazines (s-triazines) on polybenzimidazole (PBI) beads is investigated under equilibrium (batch) conditions. The observed adsorption isotherms of the selected compounds are accurately described by the Freundlich model, while the agreement between the Langmuir model and the experimental data is moderately worse, which seems to reflect the heterogeneous meso- and micro-porosity of PBI and polydispersion in the interaction mechanism. Methylthio- and methoxytriazines exhibit a greater adsorption tendency as compared with chlorotriazines, moreover, progressive dealkylation of amino groups results in a progressive increase of triazine uptake on PBI. Based on these evidences, the adsorption mechanism seems to be governed by a combination of {pi}-{pi} and hydrogen-bonding interactions. Genetic algorithm (GA) variable selection and multilinear regression (MLR) are combined in order to describe the effect of triazine structure on the extraction performance of PBI according to the quantitative structure-property relationship (QSPR) method. q{sub max}, the amount of triazine adsorbed per weight unit of PBI assuming homogeneous monolayer (Langmuir) mechanism, exhibits a great variability within the set of investigated triazines and is the quantity here modelled by QSPR. On the other hand, the Freundlich constant, K{sub F}, which expresses the adsorption efficiency under multilayer heterogeneous conditions, even if markedly increases passing from chloro- to methylthio- or methoxytriazines, is less noticeably affected by the fine details of the adsorbate structure, as the number or nature of alkyl fragments bound to the amino groups. To quantitatively relate q{sub max} with the triazine structure GA-MLR analysis is performed on the set of 1664 theoretical molecular descriptors provided by the software Dragon. Finally, a four-dimensional QSPR model is selected based on leave-one-out cross-validation and its prediction ability is further tested on

  3. Adsorption of s-triazines onto polybenzimidazole: A quantitative structure-property relationship investigation

    International Nuclear Information System (INIS)

    D'Archivio, Angelo Antonio; Incani, Angela; Mazzeo, Pietro; Ruggieri, Fabrizio

    2009-01-01

    The adsorption of 25 symmetric triazines (s-triazines) on polybenzimidazole (PBI) beads is investigated under equilibrium (batch) conditions. The observed adsorption isotherms of the selected compounds are accurately described by the Freundlich model, while the agreement between the Langmuir model and the experimental data is moderately worse, which seems to reflect the heterogeneous meso- and micro-porosity of PBI and polydispersion in the interaction mechanism. Methylthio- and methoxytriazines exhibit a greater adsorption tendency as compared with chlorotriazines, moreover, progressive dealkylation of amino groups results in a progressive increase of triazine uptake on PBI. Based on these evidences, the adsorption mechanism seems to be governed by a combination of π-π and hydrogen-bonding interactions. Genetic algorithm (GA) variable selection and multilinear regression (MLR) are combined in order to describe the effect of triazine structure on the extraction performance of PBI according to the quantitative structure-property relationship (QSPR) method. q max , the amount of triazine adsorbed per weight unit of PBI assuming homogeneous monolayer (Langmuir) mechanism, exhibits a great variability within the set of investigated triazines and is the quantity here modelled by QSPR. On the other hand, the Freundlich constant, K F , which expresses the adsorption efficiency under multilayer heterogeneous conditions, even if markedly increases passing from chloro- to methylthio- or methoxytriazines, is less noticeably affected by the fine details of the adsorbate structure, as the number or nature of alkyl fragments bound to the amino groups. To quantitatively relate q max with the triazine structure GA-MLR analysis is performed on the set of 1664 theoretical molecular descriptors provided by the software Dragon. Finally, a four-dimensional QSPR model is selected based on leave-one-out cross-validation and its prediction ability is further tested on four

  4. Measure theory and fine properties of functions

    CERN Document Server

    Evans, Lawrence Craig

    2015-01-01

    Measure Theory and Fine Properties of Functions, Revised Edition provides a detailed examination of the central assertions of measure theory in n-dimensional Euclidean space. The book emphasizes the roles of Hausdorff measure and capacity in characterizing the fine properties of sets and functions. Topics covered include a quick review of abstract measure theory, theorems and differentiation in ℝn, Hausdorff measures, area and coarea formulas for Lipschitz mappings and related change-of-variable formulas, and Sobolev functions as well as functions of bounded variation.The text provides complete proofs of many key results omitted from other books, including Besicovitch's covering theorem, Rademacher's theorem (on the differentiability a.e. of Lipschitz functions), area and coarea formulas, the precise structure of Sobolev and BV functions, the precise structure of sets of finite perimeter, and Aleksandrov's theorem (on the twice differentiability a.e. of convex functions).This revised edition includes countl...

  5. Permeability of Granite Including Macro-Fracture Naturally Filled with Fine-Grained Minerals

    Science.gov (United States)

    Nara, Yoshitaka; Kato, Masaji; Niri, Ryuhei; Kohno, Masanori; Sato, Toshinori; Fukuda, Daisuke; Sato, Tsutomu; Takahashi, Manabu

    2018-03-01

    Information on the permeability of rock is essential for various geoengineering projects, such as geological disposal of radioactive wastes, hydrocarbon extraction, and natural hazard risk mitigation. It is especially important to investigate how fractures and pores influence the physical and transport properties of rock. Infiltration of groundwater through the damage zone fills fractures in granite with fine-grained minerals. However, the permeability of rock possessing a fracture naturally filled with fine-grained mineral grains has yet to be investigated. In this study, the permeabilities of granite samples, including a macro-fracture filled with clay and a mineral vein, are investigated. The permeability of granite with a fine-grained mineral vein agrees well with that of the intact sample, whereas the permeability of granite possessing a macro-fracture filled with clay is lower than that of the macro-fractured sample. The decrease in the permeability is due to the filling of fine-grained minerals and clay in the macro-fracture. It is concluded that the permeability of granite increases due to the existence of the fractures, but decreases upon filling them with fine-grained minerals.

  6. INJECTING FASTENING LOESS SOILS GROZNY FINE PARTICULATE MATTER SUCH AS «MIKRODUR»

    Directory of Open Access Journals (Sweden)

    S-A. Y. Murtazaev

    2014-01-01

    Full Text Available The paper is devoted to the actual problem of development and implementation of effective ways to increase the bearing capacity of foundations of buildings and structures by impregnating the soil very finely dispersed binders such as "Mikrodur", turning it into a constructive element of the structure.The article shows that the use of a fine binder improves impervious properties strengthened by arrays, resistance to aggressive influences, hardening in a negative temperature, the strength development, etc. 

  7. Optimum conditions for the determination of ionization potentials, appearance potentials and fine structure in ionization efficiency curves using edd technique

    International Nuclear Information System (INIS)

    Selim, Ezzat T.; El-Kholy, S.B.; Zahran, Nagwa F.

    1978-01-01

    The optimum conditions for determining ionization potentials as well as fine structure in electron impact ionization efficiency curves are studied using energy distribution difference technique. Applying these conditions to Ar + , Kr + , CO + 2 and N + from N 2 , very good agreement is obtained when compared with results determined by other techniques including UV spectroscopy. The merits and limitation of the technique are also discussed

  8. Fine-tuning of electronic properties in donor-acceptor conjugated polymers based on oligothiophenes

    Science.gov (United States)

    Imae, Ichiro; Sagawa, Hitoshi; Harima, Yutaka

    2018-03-01

    A novel series of donor-acceptor conjugated polymers having oligothiophenes with well-defined structures were synthesized and their optical, electrochemical, and photovoltaic properties were investigated. It was found that the absorption bands of polymers were red-shifted with increasing number of ethylenedioxy groups added to each oligothiophene unit and that their band edges reached over 1000 nm. The systematical fine-tuning of the electronic properties was achieved using the chemical structures of oligothiophene units. Photovoltaic cells based on polymer/(6,6)-phenyl C61 butyric acid methyl ester (PC61BM) exhibited power conversion efficiencies in the range from 0.004 to 1.10%, reflecting the electronic properties of the polymers.

  9. Studies on fire and explosion hazards of zircaloy fines

    International Nuclear Information System (INIS)

    Andriessen, H.; Kroebel, R.; Bereznai, T.; Wurtz, R.; Hattwig, M.; Hensel, W.; Osswald, R.

    1987-01-01

    To promote the safe handling of the Zry-fines arising in a reprocessing plant, an experimental program was conducted under which the fire and explosion hazards were assessed. In order to evaluate the effect of irradiation on the ignition and explosion properties, irradiated and unirradiated Zry-fines, generated with the same tool, were investigated and compared which each other. Irradiated Zry-fines exhibit a higher fire and explosion hazard than non-irradiated fines passing the same sieve. These differences are caused mainly by the irradiation induced embrittlement and hardening of the Zry-hulls. On account of these different physical properties the generated fines have got a finer grain size due to a more spherical shape resulting in a higher bulk density and a lower mean value. These secondary irradiation effects seem to determine the lower minimum ignition temperatures and the higher values for the maximum explosion pressure and rate of pressure rise

  10. Effect of diurnal photosynthetic activity on the fine structure of amylopectin from normal and waxy barley starch

    DEFF Research Database (Denmark)

    Goldstein, Avi; Annor, George; Blennow, Andreas

    2017-01-01

    growing conditions. The amylopectin fine structures were analysed by characterizing its unit chain length profiles after enzymatic debranching as well as its φ,β-limit dextrins and its clusters and building blocks after their partial and complete hydrolysis with α-amylase from Bacillus amyloliquefaciens...... density and longer average chain lengths than clusters derived from plants grown under constant light conditions. Amylopectin clusters from diurnally grown plants also consisted of a greater number of building blocks, and shorter inter-block chain lengths compared to clusters derived from plants grown......, respectively. Regardless of lighting conditions, no structural effects were found when comparing both the amylopectin side-chain distribution and the internal chain fragments of these amylopectins. However, the diurnally grown NBS and WBS both showed larger amylopectin clusters and these had lower branching...

  11. Metal induced crystallization of amorphous silicon thin films studied by x-ray absorption fine structure spectroscopy

    International Nuclear Information System (INIS)

    Naidu, K Lakshun; Mohiddon, Md Ahamad; Dalba, G; Krishna, M Ghanashyam; Rocca, F

    2013-01-01

    The role of thin metallic layer (Chromium or Nickel) in the crystallization of a-Si film has been studied using X-ray absorption fine structure spectroscopy (XAFS). The films were grown at different substrate temperatures in two different geometrical structures : (a) a 200 nm metal layer (Cr or Ni) was deposited on fused silica (FS) followed by 400 nm of a-Si and (b) the 400 nm a-Si layer was deposited on FS followed by 200 nm of metal layer. XAFS measurements at Cr K-edge and Ni K-edge were done at BM08 – GILDA beamline of the European Synchrotron Research Facility (ESRF, Grenoble, F) in fluorescence mode. To understand the evolution of the local structure of Cr/Ni diffusing from bottom to top and from top to bottom, total reflection and higher incidence angles were employed. The relative content of metal, metal oxide and metal silicides compounds on the upper surface and/or in the bulk of different films has been evaluated as a function of thermal treatment.

  12. Ultrasound guided percutaneous fine needle aspiration biopsy ...

    African Journals Online (AJOL)

    )-guided percutaneous fine needle aspiration biopsy (PFNAB)/US-guided percutaneous needle core biopsy (PNCB) of abdominal lesions is efficacious in diagnosis, is helpful in treatment choice, to evaluate whether various other investigations ...

  13. Structural control of ultra-fine CoPt nanodot arrays via electrodeposition process

    Energy Technology Data Exchange (ETDEWEB)

    Wodarz, Siggi [Department of Applied Chemistry, Waseda University, Shinjuku, Tokyo 169-8555 (Japan); Hasegawa, Takashi; Ishio, Shunji [Department of Materials Science, Akita University, Akita City 010-8502 (Japan); Homma, Takayuki, E-mail: t.homma@waseda.jp [Department of Applied Chemistry, Waseda University, Shinjuku, Tokyo 169-8555 (Japan)

    2017-05-15

    CoPt nanodot arrays were fabricated by combining electrodeposition and electron beam lithography (EBL) for the use of bit-patterned media (BPM). To achieve precise control of deposition uniformity and coercivity of the CoPt nanodot arrays, their crystal structure and magnetic properties were controlled by controlling the diffusion state of metal ions from the initial deposition stage with the application of bath agitation. Following bath agitation, the composition gradient of the CoPt alloy with thickness was mitigated to have a near-ideal alloy composition of Co:Pt =80:20, which induces epitaxial-like growth from Ru substrate, thus resulting in the improvement of the crystal orientation of the hcp (002) structure from its initial deposition stages. Furthermore, the cross-sectional transmission electron microscope (TEM) analysis of the nanodots deposited with bath agitation showed CoPt growth along its c-axis oriented in the perpendicular direction, having uniform lattice fringes on the hcp (002) plane from the Ru underlayer interface, which is a significant factor to induce perpendicular magnetic anisotropy. Magnetic characterization of the CoPt nanodot arrays showed increase in the perpendicular coercivity and squareness of the hysteresis loops from 2.0 kOe and 0.64 (without agitation) to 4.0 kOe and 0.87 with bath agitation. Based on the detailed characterization of nanodot arrays, the precise crystal structure control of the nanodot arrays with ultra-high recording density by electrochemical process was successfully demonstrated. - Highlights: • Ultra-fine CoPt nanodot arrays were fabricated by electrodeposition. • Crystallinity of hcp (002) was improved with uniform composition formation. • Uniform formation of hcp lattices leads to an increase in the coercivity.

  14. The role of temporal fine structure information for the low pitch of high-frequency complex tones

    DEFF Research Database (Denmark)

    Santurette, Sébastien; Dau, Torsten

    2011-01-01

    The fused low pitch evoked by complex tones containing only unresolved high-frequency components demonstrates the ability of the human auditory system to extract pitch using a temporal mechanism in the absence of spectral cues. However, the temporal features used by such a mechanism have been...... amplitude fluctuations, or temporal fine structure (TFS), of the conveyed signal can be processed. Using a pitch-matching paradigm, the present study found that the low pitch of inharmonic transposed tones with unresolved components was consistent with the timing between the most prominent TFS maxima...... coding as such, and that TFS representation might persist at higher frequencies than previously thought....

  15. New Equations for Calculating Principal and Fine-Structure Atomic Spectra for Single and Multi-Electron Atoms

    Energy Technology Data Exchange (ETDEWEB)

    Surdoval, Wayne A. [National Energy Technology Lab. (NETL), Pittsburgh, PA, (United States); Berry, David A. [National Energy Technology Lab. (NETL), Morgantown, WV (United States); Shultz, Travis R. [National Energy Technology Lab. (NETL), Morgantown, WV (United States)

    2018-03-09

    A set of equations are presented for calculating atomic principal spectral lines and fine-structure energy splits for single and multi-electron atoms. Calculated results are presented and compared to the National Institute of Science and Technology database demonstrating very good accuracy. The equations do not require fitted parameters. The only experimental parameter required is the Ionization energy for the electron of interest. The equations have comparable accuracy and broader applicability than the single electron Dirac equation. Three Appendices discuss the origin of the new equations and present calculated results. New insights into the special relativistic nature of the Dirac equation and its relationship to the new equations are presented.

  16. Fine Structure in Proton Emission from the Deformed 141g.sHo and 141mHo

    International Nuclear Information System (INIS)

    Karny, M.; Rykaczewski, Krzysztof Piotr; Grzywacz, R.; Batchelder, J.C.; Bingham, C.R.; Goodin, C. T.; Gross, Carl J.; Hamilton, J.H.; Korgul, A.; Krolas, W.; Liddick, S. N.; Li, K.; Maier, Karl; Mazzocchi, C.; Piechaczek, A.; Shapira, Dan; Simpson, D.; Tantawy, M.N.; Winger, J.A.; Yu, Chang-Hong; Zganjar, E. F.

    2007-01-01

    Fine structure in proton emission from the deformed states 141g.s Ho (T 1/2 = 4.1 ms) and 141 mHo (T 1/2 = 7.4 (micro)s) has been discovered at Oak Ridge by detecting fusion evaporation residues with the Recoil Mass Spectrometer, Si-detectors and digital signal processing electronics. The branching ratios to the first 2 + excited state in 140 Dy were measured to be I p g.s. (2 + ) = 0.9±0.1% and I p m (2 + ) = 1.7±0.5%. A comparison of the available calculations to the experimental values calls for further development of the theoretical models

  17. Optimal Design of Experiments by Combining Coarse and Fine Measurements

    Science.gov (United States)

    Lee, Alpha A.; Brenner, Michael P.; Colwell, Lucy J.

    2017-11-01

    In many contexts, it is extremely costly to perform enough high-quality experimental measurements to accurately parametrize a predictive quantitative model. However, it is often much easier to carry out large numbers of experiments that indicate whether each sample is above or below a given threshold. Can many such categorical or "coarse" measurements be combined with a much smaller number of high-resolution or "fine" measurements to yield accurate models? Here, we demonstrate an intuitive strategy, inspired by statistical physics, wherein the coarse measurements are used to identify the salient features of the data, while the fine measurements determine the relative importance of these features. A linear model is inferred from the fine measurements, augmented by a quadratic term that captures the correlation structure of the coarse data. We illustrate our strategy by considering the problems of predicting the antimalarial potency and aqueous solubility of small organic molecules from their 2D molecular structure.

  18. Finite difference method calculations of X-ray absorption fine structure for copper

    Energy Technology Data Exchange (ETDEWEB)

    Bourke, J.D. [School of Physics, University of Melbourne, Parkville, Vic 3010 (Australia); Chantler, C.T. [School of Physics, University of Melbourne, Parkville, Vic 3010 (Australia)]. E-mail: chantler@physics.unimelb.edu.au; Witte, C. [School of Physics, University of Melbourne, Parkville, Vic 3010 (Australia)

    2007-01-15

    The finite difference method is extended to calculate X-ray absorption fine structure (XAFS) for solid state copper. These extensions include the incorporation of a Monte Carlo frozen phonon technique to simulate the effect of thermal vibrations under a correlated Debye-Waller model, and the inclusion of broadening effects from inelastic processes. Spectra are obtained over an energy range in excess of 300 eV above the K absorption edge-more than twice the greatest energy range previously reported for a solid state calculation using this method. We find this method is highly sensitive to values of the photoelectron inelastic mean free path, allowing us to probe the accuracy of current models of this parameter, particularly at low energies. We therefore find that experimental data for the photoelectron inelastic mean free path can be obtained by this method. Our results compare favourably with high precision measurements of the X-ray mass attenuation coefficient for copper, reaching agreement to within 3%, and improving previous results using the finite difference method by an order of magnitude.

  19. Effect of Grinding Fineness of Fly Ash on the Properties of Geopolymer Foam

    Directory of Open Access Journals (Sweden)

    Szabó R.

    2017-06-01

    Full Text Available Present paper deals with the development of geopolymer foam prepared from ground F class power station fly ash. The effect of the fly ash fineness on the rheology of the geopolymer paste and the foam properties have been investigated. The raw fly ash was ground in a ball mill for various duration, 5, 10, 20, 30, 60 and 120 min. Geopolymer paste was prepared from the raw and ground fly ash with NaOH – sodium silicate mixture as alkaline activator. Geopolymer foam production was made using H2O2 as foaming agent. Additionally, the geopolymer material structure was investigated by Fourier transform infrared spectrometer, the foam cell structure was monitored using optical microscopy. The rheological behaviour of the geopolymer paste changed due to the grinding of fly ash (from Bingham plastic to Newtonian liquid. Grinding of fly ash has a significant effect on the physical properties as well as on the cell structure of the geopolymer foam.

  20. Significance of Fines in Hot Mix Asphalt Synthesis

    Directory of Open Access Journals (Sweden)

    Kalaitzaki Elvira

    2017-07-01

    Full Text Available According to their size, aggregates are classified in coarse grained, fine grained, and fines. The determination of fines content in aggregate materials is very simple and is performed through the aggregate washing during the sieving procedure to define the gradation curve. The very fine material consists of grains having a size lower than 63 μm. The presence of fines directly influences the composition and performance of concrete and asphalt mixtures (e.g. asphalt content, elasticity, fracture. The strength and load carrying capacity of hot mix asphalt (HMA results from the aggregate framework created through particle-particle contact and interlock. Fines or mineral filler have a role in HMA. The coarse aggregate framework is filled by the sand-sized material and finally by the mineral filler. At some point, the smallest particles lose contact becoming suspended in the binder not having the particle-particle contact that is created by the larger particles. The overall effect of mineral filler in hot mix asphalt specimens has been investigated through a series of laboratory tests. It is clear that a behaviour influenced by the adherence of fines to asphalt film has been developed. The optimum bitumen content requirement in case of stone filler is almost the same as that for fly ash. It has been found that the percentage of fly ash filler is crucial if it exceeds approximately a value of 4%.

  1. A study of the Nb3Ge system by Ge K-edge extended x-ray absorption fine structure and x-ray absorption near-edge structure spectroscopy

    International Nuclear Information System (INIS)

    Saini, N L; Filippi, M; Wu Ziyu; Oyanagi, H; Ihara, H; Iyo, A; Agrestini, S; Bianconi, A

    2002-01-01

    The local structure of Nb 3 Ge intermetallic superconductor has been studied by Ge K-edge absorption spectroscopy. Extended x-ray absorption fine structure (EXAFS) experiments show two Ge-Nb distances. In addition to the crystallographic distance of ∼2.87 A, there exists a second Ge-Nb distance, shorter than the first by ∼0.2 A, assigned to a phase with short-range symmetry related to local displacements in the Nb-Nb chains. The x-ray absorption near-edge structure (XANES) spectrum has been simulated by full multiple-scattering calculations considering the local displacements determined by the EXAFS analysis. The XANES spectrum has been well reproduced by considering a cluster of 99 atoms within a radius of about 7 A from the central Ge atom and introducing determined local displacements

  2. Enhanced sensitivity to the time variation of the fine-structure constant and mp/me in diatomic molecules: A closer examination of silicon monobromide

    International Nuclear Information System (INIS)

    Beloy, K.; Borschevsky, A.; Schwerdtfeger, P.; Flambaum, V. V.

    2010-01-01

    Recently it was pointed out that transition frequencies in certain diatomic molecules have an enhanced sensitivity to variations in the fine-structure constant α and the proton-to-electron mass ratio m p /m e due to a near cancellation between the fine structure and vibrational interval in a ground electronic multiplet [V. V. Flambaum and M. G. Kozlov, Phys. Rev. Lett. 99, 150801 (2007)]. One such molecule possessing this favorable quality is silicon monobromide. Here we take a closer examination of SiBr as a candidate for detecting variations in α and m p /m e . We analyze the rovibronic spectrum by employing the most accurate experimental data available in the literature and perform ab initio calculations to determine the precise dependence of the spectrum on variations in α. Furthermore, we calculate the natural linewidths of the rovibronic levels, which place a fundamental limit on the accuracy to which variations may be determined.

  3. X-ray absorption fine structure spectroscopic determination of plutonium speciation at the Rocky Flats Environmental Technology Site

    International Nuclear Information System (INIS)

    Lezama-pacheco, Juan S.; Conradson, Steven D.; Clark, David L.

    2008-01-01

    X-ray Absorption Fine Structure spectroscopy was used to probe the speciation of the ppm level Pu in thirteen soil and concrete samples from the Rocky Flats Environmental Technology Site in support of the site remediation effort that has been successfully completed since these measurements. In addition to X-ray Absorption Near Edge Spectra, two of the samples yielded Extended X-ray Absorption Fine Structure spectra that could be analyzed by curve-fits. Most of these spectra exhibited features consistent with PU(IV), and more specificaJly, PuO 2+x -type speciation. Two were ambiguous, possibly indicating that Pu that was originally present in a different form was transforming into PuO 2+x , and one was interpreted as demonstrating the presence of an unusual Pu(VI) compound, consistent with its source being spills from a PUREX purification line onto a concrete floor and the resultant extreme conditions. These experimental results therefore validated models that predicted that insoluble PuO 2+x would be the most stable form of Pu in equilibrium with air and water even when the source terms were most likely Pu metal with organic compounds or a Pu fire. A corollary of these models' predictions and other in situ observations is therefore that the minimal transport of Pu that occurred on the site was via the resuspension and mobilization of colloidal particles. Under these conditions, the small amounts of diffusely distributed Pu that were left on the site after its remediation pose only a negligible hazard.

  4. Thermal expansion behavior study of Co nanowire array with in situ x-ray diffraction and x-ray absorption fine structure techniques

    Science.gov (United States)

    Mo, Guang; Cai, Quan; Jiang, Longsheng; Wang, Wei; Zhang, Kunhao; Cheng, Weidong; Xing, Xueqing; Chen, Zhongjun; Wu, Zhonghua

    2008-10-01

    In situ x-ray diffraction and x-ray absorption fine structure techniques were used to study the structural change of ordered Co nanowire array with temperature. The results show that the Co nanowires are polycrystalline with hexagonal close packed structure without phase change up until 700 °C. A nonlinear thermal expansion behavior has been found and can be well described by a quadratic equation with the first-order thermal expansion coefficient of 4.3×10-6/°C and the second-order thermal expansion coefficient of 5.9×10-9/°C. The mechanism of this nonlinear thermal expansion behavior is discussed.

  5. Micro-mechanical investigation of the effect of fine content on mechanical behavior of gap graded granular materials using DEM

    Directory of Open Access Journals (Sweden)

    Taha Habib

    2017-01-01

    Full Text Available In this paper, we present a micro-mechanical study of the effect of fine content on the behavior of gap graded granular samples by using numerical simulations performed with the Discrete Element Method. Different samples with fine content varied from 0% to 30% are simulated. The role of fine content in reinforcing the granular skeleton and in supporting the external deviatoric stress is then brought into the light.

  6. Electronic structure and optical properties of CdS{sub x}Se{sub 1−x} solid solution nanostructures from X-ray absorption near edge structure, X-ray excited optical luminescence, and density functional theory investigations

    Energy Technology Data Exchange (ETDEWEB)

    Murphy, M. W. [DESY (Deutsches Elektronen-Synchrotron), FS-PEX, Notkestrasse 85, 22607 Hamburg (Germany); Yiu, Y. M., E-mail: yyiu@uwo.ca; Sham, T. K. [Department of Chemistry, University of Western Ontario, London, ON N6A5B7 (Canada); Ward, M. J. [Cornell High Energy Synchrotron Source (CHESS), Cornell University, Ithaca, NY 14853 (United States); Liu, L. [Institute of Functional Nano and Soft Materials (FUNSOM) and Soochow University-Western University Center for Synchrotron Radiation Research, Soochow University, Suzhou, Jiangsu, 215123 (China); Hu, Y. [Canadian Light Source, University of Saskatchewan, Saskatoon, SK S7N2V3 (Canada); Zapien, J. A. [Center Of Super-Diamond and Advanced Films (COSDAF) and Department of Physics and Materials Science, City University of Hong Kong, Hong Kong SAR (China); Liu, Yingkai [Institute of Physics and Electronic Information, Yunnan Normal University, Kunming, Yunnan, 650500 (China)

    2014-11-21

    The electronic structure and optical properties of a series of iso-electronic and iso-structural CdS{sub x}Se{sub 1−x} solid solution nanostructures have been investigated using X-ray absorption near edge structure, extended X-ray absorption fine structure, and X-ray excited optical luminescence at various absorption edges of Cd, S, and Se. It is found that the system exhibits compositions, with variable local structure in-between that of CdS and CdSe accompanied by tunable optical band gap between that of CdS and CdSe. Theoretical calculation using density functional theory has been carried out to elucidate the observations. It is also found that luminescence induced by X-ray excitation shows new optical channels not observed previously with laser excitation. The implications of these observations are discussed.

  7. Extended x-ray absorption fine structure in Ga1-xMnxN/SiC films with high Mn content

    Science.gov (United States)

    Sancho-Juan, O.; Martínez-Criado, O.; Cantarero, A.; Garro, N.; Salomé, M.; Susini, J.; Olguín, D.; Dhar, S.; Ploog, K.

    2011-05-01

    In this study, the local atomic structure of highly homogeneous Ga1-xMnxN alloy films (0.03fine structure measurements. From the curve fitting, the structural parameters corresponding to the first two atomic shells surrounding both Ga and Mn atoms are reported. In the Ga1-xMnxN films, grown by molecular beam epitaxy, the Mn atoms are in tetrahedral configuration, independent of the Mn concentration; that is, they are in a substitutional site, MnGa, in the wurtzite structure. A small increase in the interatomic distances has been found with increasing Mn content. The Debye-Waller factor does not show a significant trend as Mn content increases, which suggests the presence of short-range disorder in the GaN lattice. Ab initio calculations of the structural parameter for two different Mn concentrations are consistent with the experimental results.

  8. One-loop corrections of orders (Zα)6m1/m2 and (Zα)7 to the fine structure of muonium

    International Nuclear Information System (INIS)

    Martynenko, A.P.; Faustov, R.N.

    2003-01-01

    Corrections of orders (Zα) 6 m 1 /m 2 and (Zα) 7 from one-loop two-photon amplitudes to the energy spectra of hydrogen-like atoms are calculated by expanding the relevant integrand in a Taylor series. A method for averaging the resulting quasipotential in the d-dimensional coordinate representation is formulated. Numerical values are obtained for the corresponding contributions to the fine structure of the muonium, hydrogen, and positronium atoms

  9. Fine structure and development of the collar enamel in gars, Lepisosteus oculatus, Actinopterygii

    Science.gov (United States)

    Sasagawa, Ichiro; Ishiyama, Mikio; Yokosuka, Hiroyuki; Mikami, Masato

    2008-06-01

    The fine structure of collar enamel and the cells constituting the enamel organ during amelogenesis in Lepisosteus oculatus was observed by light, scanning electron and transmission electron microscopy. In the enamel, slender crystals were arranged perpendicular to the surface and the stripes that were parallel to the surface were observed, suggesting that the enamel in Lepisosteus shares common morphological features with that in sarcopterygian fish and amphibians. Ameloblasts containing developed Golgi apparatus, rough endoplasmic reticulum (rER) and secretory granules were found in the secretory stage. In the maturation stage, a ruffled border was not seen at the distal end of the ameloblasts, while many mitochondria and lysosome-like granules were obvious in the distal cytoplasm. The enamel organ consisted of the outer dental epithelial cells, stratum reticulum cells and ameloblasts, but there was no stratum intermedium. It is likely that the ameloblasts have less absorptive function in comparison with the inner dental epithelial cells facing cap enameloid.

  10. Insight into the biological effects of acupuncture points by X-ray absorption fine structure.

    Science.gov (United States)

    Liu, Chenglin; Liu, Qinghua; Zhang, Dongming; Liu, Wei; Yan, Xiaohui; Zhang, Xinyi; Oyanagi, Hiroyuki; Pan, Zhiyun; Hu, Fengchun; Wei, Shiqiang

    2018-06-02

    Exploration of the biological effects of transition metal ions in acupuncture points is essential to clarify the functional mechanism of acupuncture treatment. Here we show that in the SP6 acupuncture point (Sanyinjiao) the Fe ions are in a high-spin state of approximately t 2g 4.5 e g 1.5 in an Fe-N(O) octahedral crystal field. The Fe K-edge synchrotron radiation X-ray absorption fine structure results reveal that the Fe-N and Fe-O bond lengths in the SP6 acupuncture point are 2.05 and 2.13 Å, respectively, and are 0.05-0.10 Å longer than those in the surrounding tissue. The distorted atomic structure reduces the octahedral symmetry and weakens the crystal field around the Fe ions by approximately 0.3 eV, leading to the high-spin configuration of the Fe ions, which is favorable for strengthening the magnetotransport and oxygen transportation properties in the acupuncture point by the enhanced spin coherence. This finding might provide some insight into the microscopic effect of the atomic and electronic interactions of transition metal ions in the acupuncture point. Graphical Abstract ᅟ.

  11. Constraints on a possible variation of the fine structure constant from galaxy cluster data

    Energy Technology Data Exchange (ETDEWEB)

    Holanda, R.F.L. [Departamento de Física, Universidade Estadual da Paraíba, 58429-500, Campina Grande – PB (Brazil); Landau, S.J.; Sánchez G, I.E. [Departamento de Física, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, and IFIBA, CONICET, Ciudad Universitaria – PabI, Buenos Aires 1428 (Argentina); Alcaniz, J.S. [Departamento de Astronomia, Observatório Nacional, 20921-400, Rio de Janeiro – RJ (Brazil); Busti, V.C., E-mail: holanda@uepb.edu.br, E-mail: slandau@df.uba.ar, E-mail: alcaniz@on.br, E-mail: isg.cos@gmail.com, E-mail: vinicius.busti@astro.iag.usp.br [Departamento de Física Matemática, Instituto de Física, Universidade de São Paulo, CP 66318, 05508-090, São Paulo – SP (Brazil)

    2016-05-01

    We propose a new method to probe a possible time evolution of the fine structure constant α from X-ray and Sunyaev-Zel'dovich measurements of the gas mass fraction ( f {sub gas}) in galaxy clusters. Taking into account a direct relation between variations of α and violations of the distance-duality relation, we discuss constraints on α for a class of dilaton runaway models. Although not yet competitive with bounds from high- z quasar absorption systems, our constraints, considering a sample of 29 measurements of f {sub gas}, in the redshift interval 0.14 < z < 0.89, provide an independent estimate of α variation at low and intermediate redshifts. Furthermore, current and planned surveys will provide a larger amount of data and thus allow to improve the limits on α variation obtained in the present analysis.

  12. Atomic structure of glassy Mg60Cu30Y10 investigated with EXAFS, x-ray and neutron diffraction, and reverse Monte Carlo simulations

    DEFF Research Database (Denmark)

    Jovari, P.; Saksl, K.; Pryds, Nini

    2007-01-01

    Short range order of amorphous Mg60Cu30Y10 was investigated by x-ray and neutron diffraction, Cu and Y K-edge x-ray absorption fine structure measurements, and the reverse Monte Carlo simulation technique. We found that Mg-Mg and Mg-Cu nearest neighbor distances are very similar to values found...... in crystalline Mg2Cu. The Cu-Y coordination number is 1.1 +/- 0.2, and the Cu-Y distance is similar to 4% shorter than the sum of atomic radii, suggesting that attraction between Cu and Y plays an important role in stabilizing the glassy state. Thermal stability and structure evolution upon annealing were also...

  13. The structural and phase state formed in construction titanium alloy by radial forging

    Energy Technology Data Exchange (ETDEWEB)

    Shlyakhova, Galina V.; Danilov, Vladimir I.; Orlova, Dina V.; Zuev, Lev B. [Institute of Strength Physics and Materials Science SB RAS, Tomsk (Russian Federation); Zavodchikov, Aleksandr S. [Perm State Technical University, Perm (Russian Federation)

    2011-07-01

    The feasibility of rod manufacture from construction titanium alloy using radial forging on a high duty machine SXK16 was investigated. The investigations were carried on for titanium rod samples using the methods of metallography, electron transmission microscophy and X-ray analysis. The results obtained are described herein. It is found that radial forging results in the formation of homogeneous fine-grained structure.Using radial forging process, high-quality items are produced. As-worked material has submicrocrystalline globular structure and an optimal α:β phase ratio. Besides, the technology is more cost-effective relative to conventional flow charts. Key words: forging, titanium alloy, fine-grain structure, substructure, pore size.

  14. Temperature dependent evolution of the local electronic structure of atmospheric plasma treated carbon nanotubes: Near edge x-ray absorption fine structure study

    International Nuclear Information System (INIS)

    Roy, S. S.; Papakonstantinou, P.; Okpalugo, T. I. T.; Murphy, H.

    2006-01-01

    Near edge x-ray absorption fine structure (NEXAFS) spectroscopy has been employed to obtain the temperature dependent evolution of the electronic structure of acid treated carbon nanotubes, which were further modified by dielectric barrier discharge plasma processing in an ammonia atmosphere. The NEXAFS studies were performed from room temperature up to 900 deg. C. The presence of oxygen and nitrogen containing functional groups was observed in C K edge, N K edge, and O K edge NEXAFS spectra of the multiwalled carbon nanotubes. The N K edge spectra revealed three types of π* features, the source of which was decisively identified by their temperature dependent evolution. It was established that these features are attributed to pyridinelike, NO, and graphitelike structures, respectively. The O K edge indicated that both carbonyl (C=O), π*(CO), and ether C-O-C, σ*(CO), functionalities were present. Upon heating in a vacuum to 900 deg. C the π*(CO) resonances disappeared while the σ*(CO) resonances were still present confirming their higher thermal stability. Heating did not produce a significant change in the π* feature of the C K edge spectrum indicating that the tabular structure of the nanotubes is essentially preserved following the thermal decomposition of the functional groups on the nanotube surface

  15. The effect of limited availability of N or water on C allocation to fine roots and annual fine root turnover in Alnus incana and Salix viminalis.

    Science.gov (United States)

    Rytter, Rose-Marie

    2013-09-01

    The effect of limited nitrogen (N) or water availability on fine root growth and turnover was examined in two deciduous species, Alnus incana L. and Salix viminalis L., grown under three different regimes: (i) supply of N and water in amounts which would not hamper growth, (ii) limited N supply and (iii) limited water supply. Plants were grown outdoors during three seasons in covered and buried lysimeters placed in a stand structure and filled with quartz sand. Computer-controlled irrigation and fertilization were supplied through drip tubes. Production and turnover of fine roots were estimated by combining minirhizotron observations and core sampling, or by sequential core sampling. Annual turnover rates of fine roots water availability. Fine root production (treatments in Salix; i.e., absolute length and biomass production increased in the order: water limited treatment effects were detected for fine roots 1-2 mm. Proportionally more C was allocated to fine roots (≤2 mm) in N or water-limited Salix; 2.7 and 2.3 times the allocation to fine roots in the unlimited regime, respectively. Estimated input to soil organic carbon increased by ca. 20% at N limitation in Salix. However, future studies on fine root decomposition under various environmental conditions are required. Fine root growth responses to N or water limitation were less pronounced in Alnus, thus indicating species differences caused by N-fixing capacity and slower initial growth in Alnus, or higher fine root plasticity in Salix. A similar seasonal growth pattern across species and treatments suggested the influence of outer stimuli, such as temperature and light.

  16. Characterization of Functionalized Self-Assembled Monolayers and Surface-Attached Interlocking Molecules Using Near-Edge X-ray Absorption Fine Structure Spectroscopy

    International Nuclear Information System (INIS)

    Willey, T; Willey, T

    2004-01-01

    Quantitative knowledge of the fundamental structure and substrate binding, as well as the direct measurement of conformational changes, are essential to the development of self-assembled monolayers (SAMs) and surface-attached interlocking molecules, catenanes and rotaxanes. These monolayers are vital to development of nano-mechanical, molecular electronic, and biological/chemical sensor applications. This dissertation investigates properties of functionalized SAMs in sulfur-gold based adsorbed molecular monolayers using quantitative spectroscopic techniques including near-edge x-ray absorption fine structure spectroscopy (NEXAFS) and x-ray photoelectron spectroscopy (XPS). The stability of the gold-thiolate interface is addressed. A simple model SAM consisting of dodecanethiol adsorbed on Au(111) degrades significantly in less than 24 hours under ambient laboratory air. S 2p and O 1s XPS show the gold-bound thiolates oxidize to sulfinates and sulfonates. A reduction of organic material on the surface and a decrease in order are observed as the layer degrades. The effect of the carboxyl vs. carboxylate functionalization on SAM structure is investigated. Carboxyl-terminated layers consisting of long alkyl-chain thiols vs. thioctic acid with short, sterically separated, alkyl groups are compared and contrasted. NEXAFS shows a conformational change, or chemical switchability, with carboxyl groups tilted over and carboxylate endgroups more upright. Surface-attached loops and simple surface-attached rotaxanes are quantitatively characterized, and preparation conditions that lead to desired films are outlined. A dithiol is often insufficient to form a molecular species bound at each end to the substrate, while a structurally related disulfide-containing polymer yields surface-attached loops. Similarly, spectroscopic techniques show the successful production of a simple, surface-attached rotaxane that requires a ''molecular riveting'' step to hold the mechanically attached

  17. Alfvénic Dynamics and Fine Structuring of Discrete Auroral Arcs: Swarm and e-POP Observations

    Science.gov (United States)

    Miles, D.; Mann, I. R.; Pakhotin, I.; Burchill, J. K.; Howarth, A. D.; Knudsen, D. J.; Wallis, D. D.; Yau, A. W.; Lysak, R. L.

    2017-12-01

    The electrodynamics associated with dual discrete arc aurora with anti-parallel flow along the arcs were observed nearly simultaneously by the enhanced Polar Outflow Probe (e-POP) and the Swarm A and C spacecraft. Auroral imaging from e-POP reveal 1-10 km structuring of the arcs, which move and evolve on second timescales and confound the traditional single-spacecraft field-aligned current algorithms. High-cadence magnetic data from e-POP shows 1-10 Hz, presumably Alfvénic perturbations co-incident with and at the same scale size as the observed dynamic auroral fine structures. High-cadence electric and magnetic field data from Swarm A reveals non-stationary electrodynamics involving reflected and interfering Alfvén waves and signatures of modulation consistent with trapping in the Ionospheric Alfvén Resonator (IAR). Together, these observations suggest a role for Alfven waves, perhaps also the IAR, in discrete arc dynamics on 0.2 - 10s timescales and 1-10 km spatial scales.

  18. Collisional radiative model for Ar-O2 mixture plasma with fully relativistic fine structure cross sections

    Science.gov (United States)

    Priti, Gangwar, Reetesh Kumar; Srivastava, Rajesh

    2018-04-01

    A collisional radiative (C-R) model has been developed to diagnose the rf generated Ar-O2 (0%-5%) mixture plasma at low temperatures. Since in such plasmas the most dominant process is an electron impact excitation process, we considered several electron impact fine structure transitions in an argon atom from its ground as well as excited states. The cross-sections for these transitions have been obtained using the reliable fully relativistic distorted wave theory. Processes which account for the coupling of argon with the oxygen molecules have been further added to the model. We couple our model to the optical spectroscopic measurements reported by Jogi et al. [J. Phys. D: Appl. Phys. 47, 335206 (2014)]. The plasma parameters, viz. the electron density (ne) and the electron temperature (Te) as a function of O2 concentration have been obtained using thirteen intense emission lines out of 3p54p → 3p54s transitions observed in their spectroscopic measurements. It is found that as the content of O2 in Ar increases from 0%-5%, Te increases in the range 0.85-1.7 eV, while the electron density decreases from 2.76 × 1012-2.34 × 1011 cm-3. The Ar-3p54s (1si) fine-structure level populations at our extracted plasma parameters are found to be in very good agreement with those obtained from the measurements. Furthermore, we have estimated the individual contributions coming from the ground state, 1si manifolds and cascade contributions to the population of the radiating Ar-3p54p (2pi) states as a function of a trace amount of O2. Such information is very useful to understand the importance of various processes occurring in the plasma.

  19. Get out of Fines Free: Recruiting Student Usability Testers via Fine Waivers

    Science.gov (United States)

    Hockenberry, Benjamin; Blackburn, Kourtney

    2016-01-01

    St. John Fisher College's Lavery Library's Access Services and Systems departments began a pilot project in which students with overdue fines tested usability of library Web sites in exchange for fine waivers. Circulation staff promoted the program and redeemed fine waiver vouchers at the Checkout Desk, while Systems staff administered testing and…

  20. Can temporal fine structure represent the fundamental frequency of unresolved harmonics?

    Science.gov (United States)

    Oxenham, Andrew J; Micheyl, Christophe; Keebler, Michael V

    2009-04-01

    At least two modes of pitch perception exist: in one, the fundamental frequency (F0) of harmonic complex tones is estimated using the temporal fine structure (TFS) of individual low-order resolved harmonics; in the other, F0 is derived from the temporal envelope of high-order unresolved harmonics that interact in the auditory periphery. Pitch is typically more accurate in the former than in the latter mode. Another possibility is that pitch can sometimes be coded via the TFS from unresolved harmonics. A recent study supporting this third possibility [Moore et al. (2006a). J. Acoust. Soc. Am. 119, 480-490] based its conclusion on a condition where phase interaction effects (implying unresolved harmonics) accompanied accurate F0 discrimination (implying TFS processing). The present study tests whether these results were influenced by audible distortion products. Experiment 1 replicated the original results, obtained using a low-level background noise. However, experiments 2-4 found no evidence for the use of TFS cues with unresolved harmonics when the background noise level was raised, or the stimulus level was lowered, to render distortion inaudible. Experiment 5 measured the presence and phase dependence of audible distortion products. The results provide no evidence that TFS cues are used to code the F0 of unresolved harmonics.

  1. Theory and Examples of Mathematical Modeling for Fine Weave Pierced Fabric

    Directory of Open Access Journals (Sweden)

    ZHOU Yu-bo

    2017-04-01

    Full Text Available A mathematical abstraction and three-dimensional modeling method of three-dimensional woven fabric structure was developed for the fine weave pierced fabric, taking parametric continuity splines as the track function of tow. Based on the significant parameters of fine weave pierced fabric measured by MicroCT, eight kinds of the three-dimensional digital models of the fabric structure were established with two kinds of tow sections and four kinds of tow trajectory characteristic functions. There is a good agreement between the three-dimensional digital models and real fabric by comparing their structures and porosities. This mathematical abstraction and three-dimensional modeling method can be applied in micro models for sub unit cell and macro models for macroscopic scale fabrics, with high adaptability.

  2. Role of short-time acoustic temporal fine structure cues in sentence recognition for normal-hearing listeners.

    Science.gov (United States)

    Hou, Limin; Xu, Li

    2018-02-01

    Short-time processing was employed to manipulate the amplitude, bandwidth, and temporal fine structure (TFS) in sentences. Fifty-two native-English-speaking, normal-hearing listeners participated in four sentence-recognition experiments. Results showed that recovered envelope (E) played an important role in speech recognition when the bandwidth was > 1 equivalent rectangular bandwidth. Removing TFS drastically reduced sentence recognition. Preserving TFS greatly improved sentence recognition when amplitude information was available at a rate ≥ 10 Hz (i.e., time segment ≤ 100 ms). Therefore, the short-time TFS facilitates speech perception together with the recovered E and works with the coarse amplitude cues to provide useful information for speech recognition.

  3. Distribution spatiale intra-urbaine des particules fines : monitoring ...

    African Journals Online (AJOL)

    SARAH

    30 sept. 2014 ... En outre, l'accumulation des particules fines est faible pendant un mois pluvieux par rapport à un mois sec ..... benjamina, et la structure (tige, branches) des arborées ... par Zhang et al., (2006) sur des feuilles de Pinus pumila.

  4. Extended x-ray absorption fine structure studies of amorphous and crystalline Si-Ge alloys with synchrotron radiation

    International Nuclear Information System (INIS)

    Kajiyama, Hiroshi

    1988-01-01

    Extended X-ray absorption fine structure (EXAFS) is a powerful probe to study the local structure around the atom of a specific element. In conventional EXAFS analysis, it has been known that reliable structures are obtained with the different values of absorption edge energy for different neighboring atoms. It is shown in this study that the Ge-K edge EXAFS resulting from the Ge-Ge and Ge-Si bonds in hydrogenated amorphous Si-Ge alloys was able to be excellently explained by a unique absorption edge energy value, provided that a newly developed formula based on the spherical wave function of photoelectrons is used. The microscopic structures of hydrogenated amorphous Si-Ge alloys and crystalline Si-Ge alloys have been determined using the EXAFS method. The lengths of Ge-Ge and Ge-Si bonds were constant throughout their entire composition range, and it was found that the length of Ge-Si bond was close to the average value of the bond lengths of both Ge and Si crystals. In crystalline Si-Ge alloys, it has been shown that the bonds relaxed completely, while the lattice constant varied monotonously with the composition. (Kako, I.)

  5. Fine structure of striations observed in barium plasma injections in the magnetospheric cleft

    International Nuclear Information System (INIS)

    Simons, D.J.; Eastman, T.E.; Pongratz, M.B.

    1976-01-01

    In January and November of 1975, the Los Alamos Scientific Laboratory sponsored four high altitude shaped charge barium plasma injections in the magnetospheric cleft region. These experiments were TORDO UNO (January 6), TORDO DOS (January 11), PERIQUITO UNO (November 25), and PERIQUITO DOS (November 28). All four injections took place near 500 km altitude, and optical data were taken from two aircraft and a ground station. The TORDO DOS and the PERIQUITO experiments showed rapid formation of striations (within one minute after injection), and fast horizontal spreading in contrast with TORDO UNO. In PERIQUITO DOS, the debris cloud spread magnetically east-west with a small net northerly motion. TORDO UNO shows very rapid poleward motion, and the remaining two events resulted in magnetically east-west horizontal spreading, with no noticeable poleward motion. Striations observed in the PERIQUITO DOS experiment separate in opposite directions with relative velocities of up to 3 km/sec. These field-aligned structures appear to form in sheets of approximately constant magnetic latitude. Significant spatial variations occur on a scale of less than 200 meters. Spatial frequency power spectra across these striations have been determined at various times. Observations of the debris cloud and the fast barium streak show strong field-aligned coherency of striation fine structure, indicating a field line mapping of transverse electric fields and gradients

  6. Compressive behavior of fine sand.

    Energy Technology Data Exchange (ETDEWEB)

    Martin, Bradley E. (Air Force Research Laboratory, Eglin, FL); Kabir, Md. E. (Purdue University, West Lafayette, IN); Song, Bo; Chen, Wayne (Purdue University, West Lafayette, IN)

    2010-04-01

    The compressive mechanical response of fine sand is experimentally investigated. The strain rate, initial density, stress state, and moisture level are systematically varied. A Kolsky bar was modified to obtain uniaxial and triaxial compressive response at high strain rates. A controlled loading pulse allows the specimen to acquire stress equilibrium and constant strain-rates. The results show that the compressive response of the fine sand is not sensitive to strain rate under the loading conditions in this study, but significantly dependent on the moisture content, initial density and lateral confinement. Partially saturated sand is more compliant than dry sand. Similar trends were reported in the quasi-static regime for experiments conducted at comparable specimen conditions. The sand becomes stiffer as initial density and/or confinement pressure increases. The sand particle size become smaller after hydrostatic pressure and further smaller after dynamic axial loading.

  7. Anne Fine

    Directory of Open Access Journals (Sweden)

    Philip Gaydon

    2015-04-01

    Full Text Available An interview with Anne Fine with an introduction and aside on the role of children’s literature in our lives and development, and our adult perceptions of the suitability of childhood reading material. Since graduating from Warwick in 1968 with a BA in Politics and History, Anne Fine has written over fifty books for children and eight for adults, won the Carnegie Medal twice (for Goggle-Eyes in 1989 and Flour Babies in 1992, been a highly commended runner-up three times (for Bill’s New Frock in 1989, The Tulip Touch in 1996, and Up on Cloud Nine in 2002, been shortlisted for the Hans Christian Andersen Award (the highest recognition available to a writer or illustrator of children’s books, 1998, undertaken the positon of Children’s Laureate (2001-2003, and been awarded an OBE for her services to literature (2003. Warwick presented Fine with an Honorary Doctorate in 2005. Philip Gaydon’s interview with Anne Fine was recorded as part of the ‘Voices of the University’ oral history project, co-ordinated by Warwick’s Institute of Advanced Study.

  8. 3-Space In-Flow Theory of Gravity: Boreholes, Blackholes and the Fine Structure Constant

    Directory of Open Access Journals (Sweden)

    Cahill R. T.

    2006-04-01

    Full Text Available A theory of 3-space explains the phenomenon of gravity as arising from the time-dependence and inhomogeneity of the differential flow of this 3-space. The emergent theory of gravity has two gravitational constants: G - Newton's constant, and a dimensionless constant alpha. Various experiments and astronomical observations have shown that alpha is the fine structure constant ~1/137. Here we analyse the Greenland Ice Shelf and Nevada Test Site borehole g anomalies, and confirm with increased precision this value of alpha. This and other successful tests of this theory of gravity, including the supermassive black holes in globular clusters and galaxies, and the "dark-matter" effect in spiral galaxies, shows the validity of this theory of gravity. This success implies that the non-relativistic Newtonian gravity was fundamentally flawed from the beginning, and that this flaw was inherited by the relativistic General Relativity theory of gravity.

  9. Fisher matrix forecasts for astrophysical tests of the stability of the fine-structure constant

    Directory of Open Access Journals (Sweden)

    C.S. Alves

    2017-07-01

    Full Text Available We use Fisher Matrix analysis techniques to forecast the cosmological impact of astrophysical tests of the stability of the fine-structure constant to be carried out by the forthcoming ESPRESSO spectrograph at the VLT (due for commissioning in late 2017, as well by the planned high-resolution spectrograph (currently in Phase A for the European Extremely Large Telescope. Assuming a fiducial model without α variations, we show that ESPRESSO can improve current bounds on the Eötvös parameter—which quantifies Weak Equivalence Principle violations—by up to two orders of magnitude, leading to stronger bounds than those expected from the ongoing tests with the MICROSCOPE satellite, while constraints from the E-ELT should be competitive with those of the proposed STEP satellite. Should an α variation be detected, these measurements will further constrain cosmological parameters, being particularly sensitive to the dynamics of dark energy.

  10. Inelastic electron scattering, fine structure of M1 giant resonances and Gamow-Teller states

    International Nuclear Information System (INIS)

    Richter, A.

    1983-01-01

    Recent progress in obtaining detailed fine structure distributions of magnetic giant resonances in nuclei using high resolution inelastic electron scattering at low energy is discussed. Specific examples chosen are the medium heavy nuclei 40 42 44 48 Ca in which M1 excitations are due to neutron spin-flip transitions and the N=28 isotones 50 Ti, 52 Cr and 54 Fe where in addition also proton excitations contribute to the measured M1 strength. It is found that the M1 strength is very fragmented and considerably quenched in comparison to predictions of shell model calculations in a model space that includes up to 2p-2h excitations. Finally, the old problem of M1 strength in 208 Pb is revisited and the results of a form factor measurement of a recently discovered low lying Jsup(π)=1 + state by nuclear resonance fluorescence are presented. (Auth.)

  11. Utilisation of Waste Marble Dust as Fine Aggregate in Concrete

    Science.gov (United States)

    Vigneshpandian, G. V.; Aparna Shruthi, E.; Venkatasubramanian, C.; Muthu, D.

    2017-07-01

    Concrete is the important construction material and it is used in the construction industry due to its high compressive strength and its durability. Now a day’s various studies have been conducted to make concrete with waste material with the intention of reducing cost and unavailability of conventional materials. This paper investigates the strength properties of concrete specimens cast using waste marble dust as replacement of fine aggregate. The marble pieces are finely crushed to powdered and the gradation is compared with conventional fine aggregate. Concrete specimen were cast using wmd in the laboratory with different proportion (25%, 50% and 100%) by weight of cement and from the studies it reveals that addition of waste marble dust as a replacement of fine aggregate marginally improves compressive, tensile and flexural strength in concrete.

  12. Flotation mechanisms of molybdenite fines by neutral oils

    Science.gov (United States)

    Lin, Qing-quan; Gu, Guo-hua; Wang, Hui; Liu, You-cai; Fu, Jian-gang; Wang, Chong-qing

    2018-01-01

    The flotation mechanisms of molybdenite fines by neutral oils were investigated through microflotation test, turbidity measurements, infrared spectroscopy, and interfacial interaction calculations. The results of the flotation test show that at pH 2-11, the floatability of molybdenite fines in the presence of transformer oil is markedly better than that in the presence of kerosene and diesel oil. The addition of transformer oil, which enhances the floatability of molybdenite fines, promotes the aggregation of molybdenite particles. Fourier transform infrared measurements illustrate that physical interaction dominates the adsorption mechanism of neutral oil on molybdenite. Interfacial interaction calculations indicate that hydrophobic attraction is the crucial force that acts among the oil collector, water, and molybdenite. Strong hydrophobic attraction between the oily collector and water provides the strong dispersion capability of the collector in water. Furthermore, the dispersion capability of the collector, not the interaction strength between the oily collectors and molybdenite, has a highly significant role in the flotation system of molybdenite fines. Our findings provide insights into the mechanism of molybdenite flotation.

  13. Transition from two-dimensional photonic crystals to dielectric metasurfaces in the optical diffraction with a fine structure

    Science.gov (United States)

    Rybin, Mikhail V.; Samusev, Kirill B.; Lukashenko, Stanislav Yu.; Kivshar, Yuri S.; Limonov, Mikhail F.

    2016-01-01

    We study experimentally a fine structure of the optical Laue diffraction from two-dimensional periodic photonic lattices. The periodic photonic lattices with the C4v square symmetry, orthogonal C2v symmetry, and hexagonal C6v symmetry are composed of submicron dielectric elements fabricated by the direct laser writing technique. We observe surprisingly strong optical diffraction from a finite number of elements that provides an excellent tool to determine not only the symmetry but also exact number of particles in the finite-length structure and the sample shape. Using different samples with orthogonal C2v symmetry and varying the lattice spacing, we observe experimentally a transition between the regime of multi-order diffraction, being typical for photonic crystals to the regime where only the zero-order diffraction can be observed, being is a clear fingerprint of dielectric metasurfaces characterized by effective parameters. PMID:27491952

  14. Fine structures in 14C emission of 223Ra and 224Ra

    International Nuclear Information System (INIS)

    Hourani, E.; Rosier, L.; Berrier-Ronsin, G.; Elayi, A.; Mueller, A.C.; Rappenecker, G.; Rotbard, G.; Renou, G.; Liebe, A.; Stab, L.

    1991-01-01

    The measurement of the energy spectrum of 14 C nuclei emitted in the spontaneous radioactivity from 223 Ra and 224 Ra has been carried out, using thin and intense sources (480 MBq for 223 Ra and 3550 MBq for 224 Ra). The sources were obtained by implanting mass-separated beams from ISOLDE (CERN) into Al and vitreous C catchers. The measurement was performed with the supraconducting solenoidal spectrometer SOLENO installed at Orsay. The discovery, of a fine structure in the energy spectrum of 14 C emission from 223 Ra, which is analogous to the one known for α emission, is confirmed. Only 13% of the branching ratio in 14 C decay leads to the ground state of the residual nucleus, while 8l% to the first excited state. For 14 C emission of 224 Ra, a lower limit of 2 for the hindrance factor has been measured for the transition to the first excited state in the residual nucleus. Also, a precise identification in Z with a E·ΔE telescope has been performed for the radiation from the 223 Ra source. (author) 22 refs., 11 figs., 1 tab

  15. X ray absorption fine structure of systems in the anharmonic limit

    Science.gov (United States)

    Mustredeleon, J.; Conradson, S. D.; Batistic, I.; Bishop, A. R.; Raistrick, I.; Jackson, W. E.; Brown, G. E.

    A new approach to the analysis of x-ray absorption fine structure (XAFS) data is presented. It is based on the use of radial distribution functions directly calculated from a single-particle ion Hamiltonian containing model potentials. The starting point of this approach is the statistical average of the XAFS for an atomic pair. This average can be computed using a radial distribution function (RDF), which can be expressed in terms of the eigenvalues and wavefunctions associated with the model potential. The pair potential describing the ionic motion is then expressed in terms of parameters that are determined by fitting this statistical average to the experimental XAFS spectrum. This approach allows the use of XAFS as a tool for mapping near-neighbor interatomic potentials, and allows the treatment of systems which exhibit strongly anharmonic potentials which can be treated by perturbative methods. Using this method we have analyzed the high temperature behavior of the oxygen contributions to the Fe K-edge XAFS in the ferrosilicate minerals andradite (Ca3Fe2Si3O12) and magnesiowustite (Mg(0.9)Fe(0.1)O). Using a temperature dependent anharmonic correction derived from these model compounds, we have found evidence for a local structural change in the Fe-O coordination environment upon melting of the geologically important mineral fayalite (Fe2SiO4). We have also employed this method to the study of the axial oxygen contributions to the polarized Cu K-edge XAFS on oriented samples of YBa2Cu3O7 and related compounds. From this study we find evidence for an axial oxygen-centered lattice distortion accompanying the superconducting phase transition and a correlation between this distortion and Tc. The relation of the observed lattice distortion to mechanisms of superconductivity is discussed.

  16. X-ray absorption fine structure of systems in the anharmonic limit

    International Nuclear Information System (INIS)

    Mustre de Leon, J.; Conradson, S.D.; Batistic, I.; Bishop, A.R.; Raistrick, I.; Jackson, W.E.; Brown, G.E.

    1991-01-01

    A new approach to the analysis of x-ray absorption fine structure (XAFS) data is presented. It is based on the use of radial distribution functions directly calculated from a single-particle ion hamiltonian containing model potentials. The starting point of this approach is the statistical average of the XAFS for an atomic pair. This average can be computed using a radial distribution function (RDF), which can be expressed in terms of the eigenvalues and wavefunctions associated with the model potential. The pair potential describing the ionic motion is then expressed in terms of parameters that are determined by fitting this statistical average to the experimental XAFS spectrum. This approach allow the use of XAFS as a tool for mapping near-neighbor interatomic potentials, and allows the treatment of systems which exhibit strongly anharmonic potentials which can be treated by perturbative methods. Using this method we have analyzed the high temperature behavior of the oxygen contributions to the Fe K-edge XAFS in the ferrosilicate minerals andradite (Ca 3 Fe 2 Si 3 O 12 ) and magnesiowustite (Mg 0.9 Fe 0.1 O). Using a temperature dependent anharmonic correction derived from these model compounds, we have found evidence for a local structural change in the Fe-O coordination environment upon melting of the geologically important mineral fayalite (Fe 2 SiO 4 ). We have also employed this method to the study of the axial oxygen contributions to the polarized Cu K-edge XAFS on oriented samples of YBa 2 Cu 3 O 7 and related compounds. From this study we find evidence for an axial oxygen-centered lattice distortion accompanying the superconducting phase transition and a correlation between this distortion and T c . The relation of the observed lattice distortion to mechanisms of superconductivity is discussed. 33 refs., 6 figs

  17. Effects of fines content on hydraulic conductivity and morphology of laterite soil as hydraulic barrier

    Science.gov (United States)

    Bello Yamusa, Yamusa; Yunus, Nor Zurairahetty Mohd; Ahmad, Kamarudin; Rahman, Norhan Abd; Sa'ari, Radzuan

    2018-03-01

    Laterite soil was investigated to find out the effects of fines content and to identify the micro-structural and molecular characteristics to evaluate its potentiality as a compacted soil landfill liner material. Tests were carried out on natural soil and reconstituted soil by dry weight of soil samples to determine the physical and engineering properties of the soil. All tests were carried out on the samples by adopting the British Standard 1377:1990. The possible mechanisms that contributed to the clay mineralogy were analyzed using spectroscopic and microscopic techniques such as field emission scanning electron microscopy (FESEM), energy-dispersive X-ray (EDX) and X-ray diffractometry (XRD). The laterite soil was found to contain kaolinite as the major clay minerals. A minimum of 50% fines content of laterite soil met the required result for hydraulic barriers in waste containment facilities.

  18. Screening preschool children for fine motor skills: environmental influence.

    Science.gov (United States)

    Comuk-Balci, Nilay; Bayoglu, Birgul; Tekindal, Agah; Kerem-Gunel, Mintaze; Anlar, Banu

    2016-03-01

    [Purpose] The aim of this study was to investigate the influence of gender and family factors on performance in the fine motor domain of the Denver II developmental screening test. [Subjects and Methods] Data were obtained from 2038 healthy children, 999 boys (49%) and 1039 girls (51%) in four age groups: 0-24 months (57%), 25-40 months (21.1%), 41-56 months (10.4%), and 57-82 months (11.5%). [Results] Female gender, higher maternal age, especially in children older than 24 months, and higher maternal education were associated with earlier accomplishment of fine motor items. Higher socioeconomic status was correlated with fine motor skills more noticeably at young ages. [Conclusion] The results of this study support the role of environmental factors in the interpretation of fine motor test results and point to target groups for intervention, such as infants in the low socioeconomic group and preschool children of less educated mothers. Studies in different populations may reveal particular patterns that affect child development.

  19. Efficiency of Micro-fine Cement Grouting in Liquefiable Sand

    International Nuclear Information System (INIS)

    Mirjalili, Mojtaba; Mirdamadi, Alireza; Ahmadi, Alireza

    2008-01-01

    In the presence of strong ground motion, liquefaction hazards are likely to occur in saturated cohesion-less soils. The risk of liquefaction and subsequent deformation can be reduced by various ground improvement methods including the cement grouting technique. The grouting method was proposed for non-disruptive mitigation of liquefaction risk at developed sites susceptible to liquefaction. In this research, a large-scale experiment was developed for assessment of micro-fine cement grouting effect on strength behavior and liquefaction potential of loose sand. Loose sand samples treated with micro-fine grout in multidirectional experimental model, were tested under cyclic and monotonic triaxial loading to investigate the influence of micro-fine grout on the deformation properties and pore pressure response. The behavior of pure sand was compared with the behavior of sand grouted with a micro-fine cement grout. The test results were shown that cement grouting with low concentrations significantly decreased the liquefaction potential of loose sand and related ground deformation

  20. The standard model and the fine structure constant at Planck distances in Bennet-Brene-Nielsen-Picek random dynamics

    International Nuclear Information System (INIS)

    Laperashvili, L.V.

    1994-01-01

    An overview of papers by Nielson, Bennet, Brene, and Picek, forming the basis of the model called random dynamics, is given in the first part of this work. The fine structure constant is calculated in the second part of this work by using the technique of path integration in the U(1) lattice gauge theory. It is shown that α U(1),crit -1 ∼ 19.8. This value is in agreement with the prediction of random dynamics. The obtained results are compared with the results of Monte Carlo simulations. 20 refs., 3 figs., 1 tab

  1. Tackling The Dragon: Investigating Lensed Galaxy Structure

    Science.gov (United States)

    Fortenberry, Alexander; Livermore, Rachael

    2018-01-01

    Galaxies have been seen to have a rapid decrease in star formation beginning at a redshift of around 1-2 up to the present day. To understand the processes underpinning this change, we need to observe the inner structure of galaxies and understand where and how the stellar mass builds up. However, at high redshifts our observable resolution is limited, which hinders the accuracy of the data. The lack of resolution at high redshift can be counteracted with the use of gravitational lensing. The magnification provided by the gravitational lens between us and the galaxies in question enables us to see extreme detail within the galaxies. To begin fine-tuning this process, we used Hubble data of Abell 370, a galaxy cluster, which lenses a galaxy know as “The Dragon” at z=0.725. With the increased detail proved by the gravitational lens we provide a detailed analysis of the galaxy’s spatially resolved star formation rate, stellar age, and masses.

  2. Hyperfine structure of six low-lying fine structure levels of 191Ir and 193Ir and the 191Δs193 hyperfine anomaly

    International Nuclear Information System (INIS)

    Buettgenbach, S.; Dicke, R.; Gebauer, H.; Kuhnen, R.; Traeber, F.

    1978-01-01

    The hyperfine interaction constants A and B of six low-lying metastable fine structure states of the two iridium isotopes 191 Ir and 193 Ir and the electronic g-factors of these levels have been measured using the atomic-beam magnetic-resonance method. From the values of the magnetic-dipole interaction constants A, corrected for off-diagonal perturbations, we extracted the hyperfine anomaly of a pure 6s-electron state: 191 Δs 193 = 0.64(7)%. Using nonrelativistic approximations for the effective radial parameters the nuclear electric-quadrupole moments were obtained: Q( 191 Ir) = 0.81(21)b, Q( 193 Ir) = 0.73(19)b (corrected for Sternheimer shielding effects). (orig.) [de

  3. Fine Resolution Termohaline Structure Of The Yuctatan Coastal Sea

    Science.gov (United States)

    Marino-Tapia, I.; Enriquez-Ortiz, C.; Capurro, L.; Euan-Avila, J.

    2007-05-01

    In the Yucatan peninsula there are a variety processes that drastically affect the thermohaline structure of the coastal seas. Some of these include hyperhaline lagoons that export salt to the ocean, upwelling events that propagate to the coast, persistent submarine groundwater discharges, and very high evaporation rates caused by the intense solar radiation. On July 2006 a fine resolution oceanographic campaign was performed on the Yucatan coast to study the detailed structure of thermohaline processes and currents from the shore to the 10 m isobath. A total of sixty nine transects that cover the entire northern stretch of the Yucatan coast were made. The transects extend seven kilometers in the offshore direction and have an alongshore spacing of 5 km. The temperature and salinity characteristics of the water column were monitored with a SEABIRD SBE 19 CTD performing profiles every 500 m along each transect. Ocean currents were measures along the same transect using a 1.5 MHz Acoustic Doppler Profiler (Sontek). The results clearly show the effects of coastal lagoons on the adjoining sea, with net salt export associated with hyperhaline lagoons (e.g. Ria Lagartos) or more estuarine influence of lagoons such as Celestun, where groundwater discharges play the role of rivers on the estuary. An assessment of this influence on the coastal ocean will be presented. It is well known the meteor impact at the end of the Cretacic era at Chicxulub, Yucatan, generated a crater with multiple rings which is evident from horizontal gravity gradients of the Yucatan mainland, and that associated with the outer ring there is a high concentration of cenotes (sinkholes) (Pope et al. 1991; Hildebrand, et al. 1995). It has also been shown that groundwater flows along this cenote ring towards the ocean, and the zones where the ring intersects the coast (Celestun and Dzilam Bravo) have impressive geologic features known as `submarine water springs' where freshwater springs as a fountain

  4. Finite difference method calculations of long-range X-ray absorption fine structure for copper over k∼20A-1

    International Nuclear Information System (INIS)

    Bourke, J.D.; Chantler, C.T.

    2010-01-01

    X-ray Absorption Fine Structure (XAFS) is calculated for copper using the cluster based Finite Difference Method for Near-Edge Structure (FDMNES). This approach is conventionally used to produce high accuracy XAFS theory in the near edge region, however, we demonstrate that it can be readily extended to encompass an energy range of more than 1.5 keV (k∼20A -1 ) from the K absorption edge. Such calculations require extensions to FDMNES to account for thermal effects, in addition to broadening effects due to inelastic processes. Extended calculations beyond the range of near-edge structure also require consideration of technical constraints such as cluster sizes and densities. We find that with our approach, we are able to produce accurate theory ranging from the absorption edge to the smooth atom-like region at high energies, with a single consistent model that is free from any fitting parameters.

  5. Fine Structure in Quasar Flows Revealed by Lens-Aided Multi-Angle Spectroscopy (LAMAS)

    Science.gov (United States)

    Green, Paul J.

    2006-09-01

    Spectral differences between lensed quasar image components are common. Since lensing is intrinsically achromatic, these differences are typically explained as the effect of either microlensing, or as light path time delays sampling intrinsic quasar spectral variability. In some cases, neither explanation seems sufficient. Here we advance a novel third hypothesis: some spectral differences are due to small line-of- sight differences through quasar disk wind outflows, taking the widest separation lens SDSSJ1004+4112 as a key example. We show that small changes in sightline may traverse streams with significantly differing columns. The implications are many. Fine structure in these outflows may change the observed spectra on arcsec scales. Though difficult to detect observationally, high ionization, high velocity-width streams may sculpt the optical and X-ray spectra of most quasars. We discuss existing multi-epoch optical/UV spectroscopy and results from X-ray observations both by Chandra and XMM in this context, and sketch further possible tests. The author gratefully acknowledges support through NASA contract NAS8-03060 (CXC).

  6. Representation of complex vocalizations in the Lusitanian toadfish auditory system: evidence of fine temporal, frequency and amplitude discrimination

    Science.gov (United States)

    Vasconcelos, Raquel O.; Fonseca, Paulo J.; Amorim, M. Clara P.; Ladich, Friedrich

    2011-01-01

    Many fishes rely on their auditory skills to interpret crucial information about predators and prey, and to communicate intraspecifically. Few studies, however, have examined how complex natural sounds are perceived in fishes. We investigated the representation of conspecific mating and agonistic calls in the auditory system of the Lusitanian toadfish Halobatrachus didactylus, and analysed auditory responses to heterospecific signals from ecologically relevant species: a sympatric vocal fish (meagre Argyrosomus regius) and a potential predator (dolphin Tursiops truncatus). Using auditory evoked potential (AEP) recordings, we showed that both sexes can resolve fine features of conspecific calls. The toadfish auditory system was most sensitive to frequencies well represented in the conspecific vocalizations (namely the mating boatwhistle), and revealed a fine representation of duration and pulsed structure of agonistic and mating calls. Stimuli and corresponding AEP amplitudes were highly correlated, indicating an accurate encoding of amplitude modulation. Moreover, Lusitanian toadfish were able to detect T. truncatus foraging sounds and A. regius calls, although at higher amplitudes. We provide strong evidence that the auditory system of a vocal fish, lacking accessory hearing structures, is capable of resolving fine features of complex vocalizations that are probably important for intraspecific communication and other relevant stimuli from the auditory scene. PMID:20861044

  7. Vortex Filaments in Grids for Scalable, Fine Smoke Simulation.

    Science.gov (United States)

    Meng, Zhang; Weixin, Si; Yinling, Qian; Hanqiu, Sun; Jing, Qin; Heng, Pheng-Ann

    2015-01-01

    Vortex modeling can produce attractive visual effects of dynamic fluids, which are widely applicable for dynamic media, computer games, special effects, and virtual reality systems. However, it is challenging to effectively simulate intensive and fine detailed fluids such as smoke with fast increasing vortex filaments and smoke particles. The authors propose a novel vortex filaments in grids scheme in which the uniform grids dynamically bridge the vortex filaments and smoke particles for scalable, fine smoke simulation with macroscopic vortex structures. Using the vortex model, their approach supports the trade-off between simulation speed and scale of details. After computing the whole velocity, external control can be easily exerted on the embedded grid to guide the vortex-based smoke motion. The experimental results demonstrate the efficiency of using the proposed scheme for a visually plausible smoke simulation with macroscopic vortex structures.

  8. Changes in fine structure of pericytes and novel desmin-immunopositive perivascular cells during postnatal development in rat anterior pituitary gland.

    Science.gov (United States)

    Jindatip, Depicha; Fujiwara, Ken; Horiguchi, Kotaro; Tsukada, Takehiro; Kouki, Tom; Yashiro, Takashi

    2013-09-01

    Pericytes are perivascular cells associated with capillaries. We previously demonstrated that pericytes, identified by desmin immunohistochemistry, produce type I and III collagens in the anterior pituitary gland of adult rats. In addition, we recently used desmin immunoelectron microscopy to characterize a novel type of perivascular cell, dubbed a desmin-immunopositive perivascular cell, in the anterior pituitary. These two types of perivascular cells differ in fine structure. The present study attempted to characterize the morphological features of pituitary pericytes and novel desmin-immunopositive perivascular cells during postnatal development, in particular their role in collagen synthesis. Desmin immunostaining revealed numerous perivascular cells at postnatal day 5 (P5) and P10. Transmission electron microscopy showed differences in the fine structure of the two cell types, starting at P5. Pericytes had well-developed rough endoplasmic reticulum and Golgi apparatus at P5 and P10. The novel desmin-immunopositive perivascular cells exhibited dilated cisternae of rough endoplasmic reticulum at P5-P30. In addition, during early postnatal development in the gland, a number of type I and III collagen-expressing cells were observed, as were high expression levels of these collagen mRNAs. We conclude that pituitary pericytes and novel desmin-immunopositive perivascular cells contain well-developed cell organelles and that they actively synthesize collagens during the early postnatal period.

  9. [A technological study on the extraction of ultra-fine powder of Panax notoginsen].

    Science.gov (United States)

    Huang, Yaohai; Huang, Mingqing; Zeng, Huifang; Guo, Wei; Xi, Ping

    2005-12-01

    To investigate the extraction of ultra-fine powder Panax notoginsen. The extraction rate of ginseng saponin Rg1, Re, Rb1, notoginseng saponin R1 and filtrated time were determined by alcoholic and aqueous extraction of Panax notoginsen in tablet, coarse powder, ultra-fine powder and recostitution granules of ultra-fine powder. The filtered time of ultra-fine powder of Panax notoginsen extraction and that of the tablet of Panax notoginsen extraction were similar, while the extraction rates of various saponins of it were high. The method of aqueous extrction in ltra-fine powder of Panax notoginsen is easy in filtrationer, higher in extraction rate of Panax notoginsen and lower in production cost.

  10. Granulation of coke breeze fine for using in the sintering process

    Directory of Open Access Journals (Sweden)

    Mohamed F.M.

    2010-01-01

    Full Text Available Coke breeze is the main fuel used in the sintering process. The value of -3+1 mm. represents the most favorable particle size for coke breeze in the sintering process. About 20% of total coke fines (-0.5 mm are produced during different steps of preparation. Introducing these fines during the sintering process proves to be very harmful for different operating parameters. Thus ,this study aims at investigating the production of granules resulting from these fines using molasses as organic binder and its application in sintering of an iron ore. The results showed that the granules having the highest mechanical properties were obtained with 14.5 wt % molasses addition. The sintering experiments were performed by using coke breeze in different shapes (-3+1 mm in size, coke breeze without sieving and coke breeze granules -3+1 mm. The reduction experiments, microscopic structure and X-ray analysis for the produced sinter were carried out. The results revealed that, all sinter properties (such as shatter test, productivity of sinter machine and blast furnace, reduction time and chemical composition for produced sinter by using coke breeze with size -3+1 mm and coke breeze granules were almost the same. The iron ore sinter which was produced by using coke breeze without sieving yielded low productivity for both sinter machine and blast furnace. Furthermore, using coke breeze without sieving in sintering of an iron ore decreases the vertical velocity of sinter machine and increases the reduction time.

  11. Role of fine needle aspiration cytology in the preoperative investigation of branchial cysts.

    Science.gov (United States)

    Slater, Jacqueline; Serpell, Jonathan W; Woodruff, Stacey; Grodski, Simon

    2012-01-01

    Successful preoperative diagnosis of a branchial cyst requires a systematic approach. The aim of this study was to evaluate methods of investigation of a lateral neck swelling suspicious for a branchial cyst, and to highlight cases where a less benign cause for the swelling should be suspected and therefore management altered appropriately. A retrospective case study of 24 patients with presumed branchial cysts managed operatively was undertaken. Demographic, clinical, imaging, cytology and histopathological data were analysed to formulate an approach to the work-up of a lateral neck swelling suspected to be a branchial cyst. All 24 patients presented with a lateral neck mass thought to be a branchial cyst preoperatively underwent preoperative fine-needle aspiration cytology. The overall accuracy of cytology in predicting a benign branchial cyst histopathologically was 83.3% (20 out of 24). Successful preoperative diagnosis of a branchial cyst requires a combination of imaging and cytology. If there is concern that a lateral neck swelling is not a branchial cyst on clinical, imaging or cytological features, then a full preoperative work-up, including computed tomography scan of the neck and upper aero-digestive tract endoscopy should be performed, prior to an excisional biopsy. © 2011 The Authors. ANZ Journal of Surgery © 2011 Royal Australasian College of Surgeons.

  12. Effect of repressing of briquettes at high hydrostatic pressures on fine structure of carbide fraction in compacts and sintered BK10 alloy

    International Nuclear Information System (INIS)

    Chernyj, Yu.F.; Mikhajlenko, G.P.; Labinskaya, N.G.; Vangengeim, S.D.; Fal'kovskij, V.A.; Lavrukhina, L.I.

    1977-01-01

    The effect was studied of the repressing at high hydrostatic pressures of preforms of hard alloy powder mixture with different degree of fineness on changes in fine structure of the carbide phase of compacts and the VK10 sintered alloy. X-ray diffraction method was used. Sufficient widening of diffraction lines of the WC phase in compacts and in a sintered alloy with the increase in hydrostatic pressure testifies to the fact of the production of more inperfect carbide substructure mainly due to fragmentation subgrains. The effect of processing pressure manifests itself to a greater extent in compacts of the coarse-ground mixture; in the sintered alloy the repressing pressure effect ''is being smoothed'' to some extent. The density of dislocation in the compacts and the sintered alloy were evaluated quantatively depending on the hydrostatic pressure values during processing of preforms

  13. 3-Space In-Flow Theory of Gravity: Boreholes, Blackholes and the Fine Structure Constant

    Directory of Open Access Journals (Sweden)

    Cahill R. T.

    2006-04-01

    Full Text Available A theory of 3-space explains the phenomenon of gravity as arising from the time-dependence and inhomogeneity of the differential flow of this 3-space. The emergent theory of gravity has two gravitational constants: GN — Newton’s constant, and a dimensionless constant α. Various experiments and astronomical observations have shown that α is the fine structure constant ≈ 1/137. Here we analyse the Greenland Ice Shelf and Nevada Test Site borehole g anomalies, and confirm with increased precision this value of α. This and other successful tests of this theory of gravity, including the supermassive black holes in globular clusters and galaxies, and the “dark-matter” effect in spiral galaxies, shows the validity of this theory of gravity. This success implies that the non-relativistic Newtonian gravity was fundamentally flawed from the beginning, and that this flaw was inherited by the relativistic General Relativity theory of gravity.

  14. Fine crystalline powders. Analysis of scientific and technical literature

    International Nuclear Information System (INIS)

    Denisenko, Eh.T.; Kulik, O.P.; Eremina, T.V.

    1983-01-01

    The state of development and studies of fine crystalline powders for recent five years is reviewed in the paper. Based on data available in literature, the most significant methods for fine metal and alloy powder production are considered and physicochemical properties of ultrafine particles are discussed from the standpoint of their interrelation with promising techniques for powder production. It is stated that the most important feature of ultrafine powder production technique at the present stage is a transition from the stage of data accumulation to that of controlled production of ultrafine structures of various metals and alloys under controllable conditions

  15. Positioning performance of a maglev fine positioning system

    Energy Technology Data Exchange (ETDEWEB)

    Wronosky, J.B.; Smith, T.G.; Jordan, J.D.; Darnold, J.R.

    1996-12-01

    A wafer positioning system was recently developed by Sandia National Laboratories for an Extreme Ultraviolet Lithography (EUVL) research tool. The system, which utilizes a magnetically levitated fine stage to provide ultra-precise positioning in all six degrees of freedom, incorporates technological improvements resulting from four years of prototype development experience. System enhancements, implemented on a second generation design for an ARPA National Center for Advanced Information Component Manufacturing (NCAICM) project, introduced active structural control for the levitated structure of the system. Magnetic levitation (maglev) is emerging as an important technology for wafer positioning systems in advanced lithography applications. The advantages of maglev stem from the absence of physical contact. The resulting lack of friction enables accurate, fast positioning. Maglev systems are mechanically simple, accomplishing full six degree-of-freedom suspension and control with a minimum of moving parts. Power-efficient designs, which reduce the possibility of thermal distortion of the platen, are achievable. Manufacturing throughput will be improved in future systems with the addition of active structural control of the positioning stages. This paper describes the design, implementation, and functional capability of the maglev fine positioning system. Specifics regarding performance design goals and test results are presented.

  16. Adsorption site and structure determination of c(2x2) N{sub 2}/Ni(100) using angle-resolved photoemission extended fine structure

    Energy Technology Data Exchange (ETDEWEB)

    Moler, E.J.; Kellar, S.A.; Huff, W.R.A. [Lawrence Berkeley National Lab., CA (United States)] [and others

    1997-04-01

    The authors have determined the atomic spatial structure of c(2x2) N2Ni(100) with Angle-Resolved Photoemission Extended Fine Structure (ARPEFS) from the nitrogen 1s core level using monochromatized x-rays from beamline 6.1 at SSRL and beamline 9.3.2 at the ALS. The chemically shifted N 1s peak intensities were summed together to obtain ARPEFS curves for both nitrogen atoms in the molecule. They used a new, highly-optimized program based on the Rehr-Albers scattering matrix formalism to find the adsorption site and to quantitatively determine the bond-lengths. The nitrogen molecule stands upright at an atop site, with a N-Ni bond length of 2.25(1) {angstrom}, a N-N bond length of 1.10(7) {angstrom}, and a first layer Ni-Ni spacing of 1.76(4) {angstrom}. The shake-up peak shows an identical ARPEFS diffraction pattern, confirming its intrinsic nature and supporting a previous use of this feature to decompose the peak into contributions from the chemically inequivalent nitrogen atoms. Comparison to a previously published theoretical treatment of N-N-Ni and experimental structures of analogous adsorbate systems demonstrates the importance of adsorbate-adsorbate interactions in weakly chemisorbed systems.

  17. X-ray-absorption fine structure determination of pressure-induced bond-angle changes in ReO3

    International Nuclear Information System (INIS)

    Houser, B.; Ingalls, R.

    2000-01-01

    We report here on a Marquardt-type method to fit the x-ray absorption fine structure (XAFS) of ReO 3 . We find that, when the ambient-pressure structure of ReO 3 is used as a starting point, the pressure dependence of the angle of the Re-O-Re bond in ReO 3 is fairly straightforwardly and robustly determined using FEFF curved-wave, multiple-scattering programs and is accurate to about ±1.5 degree sign or better. We present an argument that XAFS and scattering experiments fundamentally differ in what they measure in the case of nearly linear atomic bridges. Focussed multiple-scattering paths involving the Re-O-Re bridge make a contribution to the XAFS spectrum that is sensitive to the rms deviation of oxygen from the [100]-type directions. Fits to simulated spectra back up our contention that for XAFS experiments the effective position of the oxygen atom is its rms displacement whether the average displacement is zero or not. (c) 2000 The American Physical Society

  18. Certain peculiarities of structural inheritance in phase recrystallization of steel

    International Nuclear Information System (INIS)

    Mukhamedov, A.A.

    1978-01-01

    The structural inheritance in phase recrystallization of previously overheated to various temperatures industrially melted 40Kh steel and of Armco-iron has been investigated. The steels have been heated to 100O, 11O0, 1200 and 1260 deg C and cooled in the air, and in some instances, hardened (quenched) in water. The physical broadening of X-ray lines points to a nonmonotonous variation of fine structure parameters as a function of the temperature and the heating time. The inheritance effect of fine structure defects affects the steel properties obtained in a final heat treatment. The structural inheritance effect has an important bearing upon the wear resistance of steel. A purpose-oriented use of the structural inheritance effect can enhance service properties of steel parts

  19. Controlled agglomeration of Tb-doped Y2O3 nanocrystals studied by x-ray absorption fine structure, x-ray excited luminescence, and photoluminescence

    International Nuclear Information System (INIS)

    Soo, Y.L.; Huang, S.W.; Kao, Y.H.; Chhabra, V.; Kulkarni, B.; Veliadis, J.V.; Bhargava, R.N.

    1999-01-01

    Local environment surrounding Y atoms in Y 2 O 3 :Tb nanocrystals under various heat treatment conditions has been investigated by using the extended x-ray absorption fine structure (EXAFS) technique. X-ray excited luminescence (XEL) with the incident x-ray energy near Y K edge and Tb L edges has also been measured to investigate the mechanisms of x-ray-to-visible down conversion in these doped nanoparticles. The observed changes in EXAFS, XEL, and photoluminescent data can be explained on the basis of increased average size of the nanoparticles as confirmed by transmission electron microscopy studies. Our results thus demonstrate that the doped nanoparticles can agglomerate to a controllable degree by varying the heat treatment temperature. At higher temperatures, the local environment surrounding Y atoms in the nanoparticles is found to become similar to that in bulk Y 2 O 3 while the XEL output still shows the characteristics of nanocrystals. These results indicate that appropriate heat treatment can afford an effective means to control the intensity and signal-to-background ratio of green luminescence output of these doped nanocrystal phosphors, potentially useful for some device applications. copyright 1999 American Institute of Physics

  20. Fine-grained sheet silicate rocks

    International Nuclear Information System (INIS)

    Weaver, C.E.

    1977-09-01

    Considerable interest has been shown in the possibility of using shales as repositories for radioactive waste and a variety of other waste products, and it appears that over the next few years much money and effort will be expended to investigate and test a wide variety of shales. If shales are to be studied in detail by a large number of investigators, it is important that all concerned have the same concept of what constitutes a shale. The term shale and other terms for fine-grained rocks have been used for many years and have been continually redefined. Most definitions predate the development of modern instrumentation and are based on field observations and intuition; however, the main problem is the diversity of definitions. An attempt is made here to develop a simple, rational classification of fine-grained sediments, and it is hoped that this classification will eliminate some of the present ambiguity. In order that the classification be pertinent, mineral composition and textural data were compiled and evaluated. The data on unconsolidated and consolidated sediments were contrasted and the effects of burial diagenesis assessed. It was found necessary to introduce a new term, physil, to describe all sheet silicate minerals. In contrast to the term clay mineral, the term physil has no size connotation. A simple classification is proposed that is based on the percentage of physils and grain size. In Part II the fine-grained physil rocks are classified on the basis of physil type, non-physil minerals, and texture. Formations are listed which have the mineral and textural characteristics of the most important rock types volumetrically. Selected rock types, and the formations in which they can be found, are recommended for laboratory study to determine their suitability for the storage of high-level radioactive waste

  1. Analyses of fine paste ceramics

    International Nuclear Information System (INIS)

    Sabloff, J.A.

    1980-01-01

    Four chapters are included: history of Brookhaven fine paste ceramics project, chemical and mathematical procedures employed in Mayan fine paste ceramics project, and compositional and archaeological perspectives on the Mayan fine paste ceramics

  2. Stokes shift and fine structure splitting in composition-tunable Zn{sub x}Cd{sub 1−x}Se nanocrystals: Atomistic tight-binding theory

    Energy Technology Data Exchange (ETDEWEB)

    Sukkabot, Worasak, E-mail: w.sukkabot@gmail.com

    2017-02-01

    I report on the atomistic correlation of the structural properties and excitonic splitting of ternary alloy Zn{sub x}Cd{sub 1−x}Se wurtzite nanocrystals using the sp{sup 3}s* empirical tight-binding method with the description of the first nearest neighbouring interaction and bowing effect. Based on a successful model, the computations are presented under various Zn compositions (x) and diameters of alloy Zn{sub x}Cd{sub 1−x}Se nanocrystals with the experimentally synthesized compositions and sizes. With increasing Zn contents (x), the optical band gaps and electron-hole coulomb energies are improved, while ground electron-hole wave function overlaps, electron-hole exchange energies, stokes shift and fine structure splitting are reduced. A composition-tunable emission from blue to yellow wavelength is obviously demonstrated. The optical band gaps, ground electron-hole wave function overlaps, electron-hole interactions, stokes shift and fine structure splitting are progressively decreased with the increasing diameters. Alloy Zn{sub x}Cd{sub 1−x}Se nanocrystal with Zn rich and large diameter is the best candidate to optimistically be used as a source of entangled photon pairs. The agreement with the experimental data is remarkable. Finally, the present systematic study on the structural properties and excitonic splitting predominantly opens a new perspective to understand the size- and composition-dependent properties of Zn{sub x}Cd{sub 1−x}Se nanocrystals with a comprehensive strategy to design the optoelectronic devices.

  3. Size-dependent characteristics of ultra-fine oxygen-enriched nanoparticles in austenitic steels

    Energy Technology Data Exchange (ETDEWEB)

    Miao, Yinbin, E-mail: ymiao@anl.gov [Argonne National Laboratory, Lemont, IL 60439 (United States); University of Illinois at Urbana-Champaign, Urbana, IL 61801 (United States); Mo, Kun [Argonne National Laboratory, Lemont, IL 60439 (United States); Zhou, Zhangjian [University of Science and Technology Beijing, Beijing 100082 (China); Liu, Xiang; Lan, Kuan-Che [University of Illinois at Urbana-Champaign, Urbana, IL 61801 (United States); Zhang, Guangming [University of Illinois at Urbana-Champaign, Urbana, IL 61801 (United States); University of Science and Technology Beijing, Beijing 100082 (China); Miller, Michael K.; Powers, Kathy A. [Oak Ridge National Laboratory, Oak Ridge, TN 37830 (United States); Stubbins, James F. [University of Illinois at Urbana-Champaign, Urbana, IL 61801 (United States); International Institute for Carbon-Neutral Energy Research (I2CNER), Kyushu University, Fukuoka 819-0395 (Japan)

    2016-11-15

    Here, a coordinated investigation of the elemental composition and morphology of ultra-fine-scale nanoparticles as a function of size within a variety of austenitic oxide dispersion-strengthened (ODS) steels is reported. Atom probe tomography was utilized to evaluate the elemental composition of these nanoparticles. Meanwhile, the crystal structures and orientation relationships were determined by high-resolution transmission electron microscopy. The nanoparticles with sufficient size (>4 nm) to maintain a Y{sub 2}Ti{sub 2−x}O{sub 7−2x} stoichiometry were found to have a pyrochlore structure, whereas smaller Y{sub x}Ti{sub y}O{sub z} nanoparticles lacked a well-defined structure. The size-dependent characteristics of the nanoparticles in austenitic ODS steels differ from those in ferritic/martensitic ODS steels. - Highlights: • The structural and chemical characteristics of nanoparticles are revealed. • Nanoparticles' crystal structure and elemental composition are size-dependent. • Characteristics of austenitic ODS steels are compared to that of an F/M ODS steel. • Hypothesis about the formation mechanism of nanoparticles is proposed accordingly.

  4. Analyses of fine paste ceramics

    Energy Technology Data Exchange (ETDEWEB)

    Sabloff, J A [ed.

    1980-01-01

    Four chapters are included: history of Brookhaven fine paste ceramics project, chemical and mathematical procedures employed in Mayan fine paste ceramics project, and compositional and archaeological perspectives on the Mayan fine paste ceramics. (DLC)

  5. Asymmetric larval head and mandibles of Hydrophilus acuminatus (Insecta: Coleoptera, Hydrophilidae): Fine structure and embryonic development.

    Science.gov (United States)

    Sato, Shun'ichi; Inoda, Toshio; Niitsu, Shuhei; Kubota, Souichirou; Goto, Yuji; Kobayashi, Yukimasa

    2017-11-01

    The larvae of a water scavenger beetle, Hydrophilus acuminatus, have strongly asymmetric mandibles; the right one is long and slender, whereas the left one is short and stout. The fine structure and embryonic development of the head capsule and mandibles of this species were examined using light and scanning electron microscopy, and asymmetries in shape were detected in these structures applying an elliptic Fourier analysis. The larval mandibles are asymmetric in the following aspects: whole length, the number, structure and arrangement of retinacula (inner teeth), and size and shape of both the molar and incisor regions. The larval head is also asymmetric; the left half of the head capsule is larger than the right, and the left adductor muscle of the mandible is much thicker than the right. The origin and developmental process of asymmetric mandibles were traced in developing embryos whose developmental period is about 270 h and divided into 10 stages. Mandibular asymmetries are produced by the cumulative effects of six stepwise modifications that occur from about 36% of the total developmental time onward. The significance of these modifications was discussed with respect to the functional advantages of asymmetries and the phylogeny of members of the Hydrophilidae. Copyright © 2017 Elsevier Ltd. All rights reserved.

  6. The Effects of Different Fine Recycled Concrete Aggregates on the Properties of Mortar

    Science.gov (United States)

    Fan, Cheng-Chih; Huang, Ran; Hwang, Howard; Chao, Sao-Jeng

    2015-01-01

    The practical use of recycled concrete aggregate produced by crushing concrete waste reduces the consumption of natural aggregate and the amount of concrete waste that ends up in landfills. This study investigated two methods used in the production of fine recycled concrete aggregate: (1) a method that produces fine as well as coarse aggregate, and (2) a method that produces only fine aggregate. Mortar specimens were tested using a variety of mix proportions to determine how the characteristics of fine recycled concrete aggregate affect the physical and mechanical properties of the resulting mortars. Our results demonstrate the superiority of mortar produced using aggregate produced using the second of the two methods. Nonetheless, far more energy is required to render concrete into fine aggregate than is required to produce coarse as well as fine aggregate simultaneously. Thus, the performance benefits of using only fine recycled concrete aggregate must be balanced against the increased impact on the environment.

  7. Genome-wide survey of single-nucleotide polymorphisms reveals fine-scale population structure and signs of selection in the threatened Caribbean elkhorn coral, Acropora palmata

    Directory of Open Access Journals (Sweden)

    Meghann K. Devlin-Durante

    2017-11-01

    Full Text Available The advent of next-generation sequencing tools has made it possible to conduct fine-scale surveys of population differentiation and genome-wide scans for signatures of selection in non-model organisms. Such surveys are of particular importance in sharply declining coral species, since knowledge of population boundaries and signs of local adaptation can inform restoration and conservation efforts. Here, we use genome-wide surveys of single-nucleotide polymorphisms in the threatened Caribbean elkhorn coral, Acropora palmata, to reveal fine-scale population structure and infer the major barrier to gene flow that separates the eastern and western Caribbean populations between the Bahamas and Puerto Rico. The exact location of this break had been subject to discussion because two previous studies based on microsatellite data had come to differing conclusions. We investigate this contradiction by analyzing an extended set of 11 microsatellite markers including the five previously employed and discovered that one of the original microsatellite loci is apparently under selection. Exclusion of this locus reconciles the results from the SNP and the microsatellite datasets. Scans for outlier loci in the SNP data detected 13 candidate loci under positive selection, however there was no correlation between available environmental parameters and genetic distance. Together, these results suggest that reef restoration efforts should use local sources and utilize existing functional variation among geographic regions in ex situ crossing experiments to improve stress resistance of this species.

  8. Genome-wide survey of single-nucleotide polymorphisms reveals fine-scale population structure and signs of selection in the threatened Caribbean elkhorn coral, Acropora palmata.

    Science.gov (United States)

    Devlin-Durante, Meghann K; Baums, Iliana B

    2017-01-01

    The advent of next-generation sequencing tools has made it possible to conduct fine-scale surveys of population differentiation and genome-wide scans for signatures of selection in non-model organisms. Such surveys are of particular importance in sharply declining coral species, since knowledge of population boundaries and signs of local adaptation can inform restoration and conservation efforts. Here, we use genome-wide surveys of single-nucleotide polymorphisms in the threatened Caribbean elkhorn coral, Acropora palmata , to reveal fine-scale population structure and infer the major barrier to gene flow that separates the eastern and western Caribbean populations between the Bahamas and Puerto Rico. The exact location of this break had been subject to discussion because two previous studies based on microsatellite data had come to differing conclusions. We investigate this contradiction by analyzing an extended set of 11 microsatellite markers including the five previously employed and discovered that one of the original microsatellite loci is apparently under selection. Exclusion of this locus reconciles the results from the SNP and the microsatellite datasets. Scans for outlier loci in the SNP data detected 13 candidate loci under positive selection, however there was no correlation between available environmental parameters and genetic distance. Together, these results suggest that reef restoration efforts should use local sources and utilize existing functional variation among geographic regions in ex situ crossing experiments to improve stress resistance of this species.

  9. IR-spectroscopical investigations on the glass structure of porous and sintered compacts of colloidal silica gels

    Science.gov (United States)

    Clasen, Rolf; Hornfeck, M.; Theiss, Wolfgang

    1991-08-01

    The forming and sintering of fumed silica powders is an interesting route for the preparation of large, very pure or doped silica glasses with a precise geometry. The processing from the shaping of a porous compact to the sintering of transparent silica glass can be successfully investigated with optical spectroscopy. As only the dielectric function DF (a dielectric function is the square root of the complex refractive index) characterizes the material, the vibrational bands were calculated from reflectance measurements. In compacts of fine particles, the topology cannot be neglected. Therefore, the models describing topological effects are briefly reviewed. With these model calculations it could be proven that new bands in the compacts and the significant shifts in the reflectance spectra during sintering are mainly caused by topological effects and that changes in the glass structure play only a secondary role.

  10. Local vibrational dynamics of hematite (α-Fe{sub 2}O{sub 3}) studied by extended x-ray absorption fine structure and molecular dynamics

    Energy Technology Data Exchange (ETDEWEB)

    Sanson, A., E-mail: andrea.sanson@unipd.it [Dipartimento di Fisica e Astronomia - Università di Padova, Padova (Italy); Mathon, O.; Pascarelli, S. [ESRF - European Synchrotron Radiation Facility, Grenoble (France)

    2014-06-14

    The local vibrational dynamics of hematite (α-Fe{sub 2}O{sub 3}) has been investigated by temperature-dependent extended x-ray absorption fine structure spectroscopy and molecular dynamics simulations. The local dynamics of both the short and long nearest-neighbor Fe–O distances has been singled out, i.e., their local thermal expansion and the parallel and perpendicular mean-square relative atomic displacements have been determined, obtaining a partial agreement with molecular dynamics. No evidence of the Morin transition has been observed. More importantly, the strong anisotropy of relative thermal vibrations found for the short Fe–O distance has been related to its negative thermal expansion. The differences between the local dynamics of short and long Fe–O distances are discussed in terms of projection and correlation of atomic motion. As a result, we can conclude that the short Fe–O bond is stiffer to stretching and softer to bending than the long Fe–O bond.

  11. Recycling of PET bottles as fine aggregate in concrete

    International Nuclear Information System (INIS)

    Frigione, Mariaenrica

    2010-01-01

    An attempt to substitute in concrete the 5% by weight of fine aggregate (natural sand) with an equal weight of PET aggregates manufactured from the waste un-washed PET bottles (WPET), is presented. The WPET particles possessed a granulometry similar to that of the substituted sand. Specimens with different cement content and water/cement ratio were manufactured. Rheological characterization on fresh concrete and mechanical tests at the ages of 28 and 365 days were performed on the WPET/concretes as well as on reference concretes containing only natural fine aggregate in order to investigate the influence of the substitution of WPET to the fine aggregate in concrete. It was found that the WPET concretes display similar workability characteristics, compressive strength and splitting tensile strength slightly lower that the reference concrete and a moderately higher ductility.

  12. Hydrological modelling of fine sediments in the Odzi River, Zimbabwe

    African Journals Online (AJOL)

    Hydrological modelling of fine sediments in the Odzi River, Zimbabwe. ... An analysis of the model structure and a comparison with the rating curve function ... model validation through split sample and proxy basin comparison was performed.

  13. EXAFS investigation on microstructure of La-based alloy deuteride

    CERN Document Server

    Chen Bo Fei; Xie Chao Mei; Chen Xi Ping; Liu Li Juan; Xie Ya Ning; Hu Tian Dou; Zhang Jing

    2002-01-01

    Extended X-ray absorption fine structure (EXAFS) spectra were measured to investigate the microstructure of La-based alloy deuteride. The radial structural functions of LaNi sub 4 sub . sub 2 sub 5 Al sub 0 sub . sub 7 sub 5 D sub x samples were obtained and the comparisons among different samples were performed. The results show that removal of deuterium is fast in La-Ni-Al hydrogen storage alloys under non-airtight condition

  14. Atomic transition energies and the variation of the fine-structure constant α

    International Nuclear Information System (INIS)

    Borschevsky, Anastasia; Eliav, Ephraim; Ishikawa, Yasuyuki; Kaldor, Uzi

    2006-01-01

    Relativistic energy shifts of atomic excitation energies, showing the dependence of these energies on the value of the fine-structure constant α, are needed to extract past changes in α from spectra of distant quasars. These shifts are calculated by the Fock-space coupled cluster method and its extrapolated intermediate Hamiltonian extension, which allow high-accuracy treatment of electron correlation. The accuracy of the method is tested by comparing 33 transition energies in heavy atoms (obtained with the laboratory α) with experiment; the average error is 258 cm -1 , and the largest error is 711 cm -1 . This may be compared with an average error of 432 cm -1 and a maximum error of 2150 cm -1 in the work of Dzuba et al., who reported most of the available energy shift calculations. The enhanced accuracy is due to more extensive inclusion of electron correlation. To obtain the energy shifts, we repeated the calculations with different values of α (within 0.1% of the current value). Our shifts differ by up to 30% from the values given by Dzuba et al., with an average difference of 9%. Based on the better quality of the present-day excitation energies, we believe the energy shifts reported here are more accurate than earlier work

  15. Sahara Coal: the fine art of collecting fines for profit

    Energy Technology Data Exchange (ETDEWEB)

    Schreckengost, D.; Arnold, D.

    1984-09-01

    Because of a change in underground mining methods that caused a considerable increase in the amount of fine sizes in the raw coal, Sahara Coal Co. designed and constructed a unique and simple fine coal system at their Harrisburg, IL prep plant. Before the new system was built, the overload of the fine coal circuit created a cost crunch due to loss of salable coal to slurry ponds, slurry pond cleaning costs, and operating and maintenance costs--each and every one excessive. Motivated by these problems, Sahara designed a prototype system to dewater the minus 28 mesh refuse. The success of the idea permitted fine refuse to be loaded onto the coarse refuse belt. Sahara also realized a large reduction in pond cleaning costs. After a period of testing, an expanded version of the refuse system was installed to dewater and dry the 28 mesh X 0 clean coal. Clean coal output increased about 30 tph. Cost savings justified the expenditures for the refuse and clean coal systems. These benefits, combined with increased coal sales revenue, paid back the project costs in less than a year.

  16. Geotechnical field investigation of the rapid densification phenomenon in oil sands mature fine tailings

    Energy Technology Data Exchange (ETDEWEB)

    Guo, C.; Chalaturnyk, R.J.; Scott, J.D.; Cyre, G. [Alberta Univ., Edmonton, AB (Canada). Dept. of Civil and Environmental Engineering; MacKinnon, M. [Syncrude Canada Ltd., Edmonton, AB (Canada). Edmonton Research Centre

    2002-07-01

    The Mildred Lake Settling Basin (MLSB) is an oil sand tailings pond with a water area of about 11 square km and a maximum depth of mature fine tailings (MFT) of about 50 m, rendering it Syncrude's largest disposal site for tailings. Syncrude began storing the MFT in 1978 but in recent years there has been a sharp increase in the consolidation of the fine tailings, creating pumping challenges in the transfer of tailings from the MLSB for the creation of composite tailings. This paper presents preliminary results of field and laboratory study which have been launched to better manage the rapid densification of fine tailings. The study involves sampling, field vane tests, cone penetration tests, steel plate penetration tests and earth pressure measurements. Methane producing microorganisms have become very active in the part of the pond that is experiencing rapid densification. The objective of the study was to determine the inventory and distribution of high strength MFT in current storage ponds and to assess whether geotechnical properties are enough to support direct loading with solids such as sand, clay or coke. The cause of the phenomena was also examined along with ways to possibly enhance MFT development through microbial, physical or chemical treatments. Results show that the accumulation of methane gas may have reached a critical state in some parts of the pond. The densification phenomenon at the southern pond is more significant compared to the northern pond. Earth pressure measurements indicate that the earth pressure cell has good sensitivity and that the coefficient of earth pressure at rest is approximately one. Good agreement was reached between different testing methods used to determine geotechnical properties of MFT. 5 refs., 4 tabs., 14 figs.

  17. Dispersibility of lactose fines as compared to API in dry powders for inhalation.

    Science.gov (United States)

    Thalberg, Kyrre; Åslund, Simon; Skogevall, Marcus; Andersson, Patrik

    2016-05-17

    This work investigates the dispersion performance of fine lactose particles as function of processing time, and compares it to the API, using Beclomethasone Dipropionate (BDP) as model API. The total load of fine particles is kept constant in the formulations while the proportions of API and lactose fines are varied. Fine particle assessment demonstrates that the lactose fines have higher dispersibility than the API. For standard formulations, processing time has a limited effect on the Fine Particle Fraction (FPF). For formulations containing magnesium stearate (MgSt), FPF of BDP is heavily influenced by processing time, with an initial increase, followed by a decrease at longer mixing times. An equation modeling the observed behavior is presented. Surprisingly, the dispersibility of the lactose fines present in the same formulation remains unaffected by mixing time. Magnesium analysis demonstrates that MgSt is transferred to the fine particles during the mixing process, thus lubrication both BDP and lactose fines, which leads to an increased FPF. Dry particle sizing of the formulations reveals a loss of fine particles at longer mixing times. Incorporation of fine particles into the carrier surfaces is believed to be behind this, and is hence a mechanism of importance as regards the dispersion performance of dry powders for inhalation. Copyright © 2016 Elsevier B.V. All rights reserved.

  18. Investigation of the milling capabilities of the F10 Fine Grind mill using Box-Behnken designs.

    Science.gov (United States)

    Tan, Bernice Mei Jin; Tay, Justin Yong Soon; Wong, Poh Mun; Chan, Lai Wah; Heng, Paul Wan Sia

    2015-01-01

    Size reduction or milling of the active is often the first processing step in the design of a dosage form. The ability of a mill to convert coarse crystals into the target size and size distribution efficiently is highly desirable as the quality of the final pharmaceutical product after processing is often still dependent on the dimensional attributes of its component constituents. The F10 Fine Grind mill is a mechanical impact mill designed to produce unimodal mid-size particles by utilizing a single-pass two-stage size reduction process for fine grinding of raw materials needed in secondary processing. Box-Behnken designs were used to investigate the effects of various mill variables (impeller, blower and feeder speeds and screen aperture size) on the milling of coarse crystals. Response variables included the particle size parameters (D10, D50 and D90), span and milling rate. Milled particles in the size range of 5-200 μm, with D50 ranging from 15 to 60 μm, were produced. The impeller and feeder speeds were the most critical factors influencing the particle size and milling rate, respectively. Size distributions of milled particles were better described by their goodness-of-fit to a log-normal distribution (i.e. unimodality) rather than span. Milled particles with symmetrical unimodal distributions were obtained when the screen aperture size was close to the median diameter of coarse particles employed. The capacity for high throughput milling of particles to a mid-size range, which is intermediate between conventional mechanical impact mills and air jet mills, was demonstrated in the F10 mill. Prediction models from the Box-Behnken designs will aid in providing a better guide to the milling process and milled product characteristics. Copyright © 2014 Elsevier B.V. All rights reserved.

  19. An Investigation of Porous Structure of TiNi-Based SHS-Materials Produced at Different Initial Synthesis Temperatures

    Science.gov (United States)

    Khodorenko, V. N.; Anikeev, S. G.; Kokorev, O. V.; Yasenchuk, Yu. F.; Gunther, V. É.

    2018-02-01

    An investigation of structural characteristics and behavior of TiNi-based pore-permeable materials manufactured by the methods of selfpropagating high-temperature synthesis (SHS) at the initial synthesis temperatures T = 400 and 600°C is performed. It is shown that depending on the temperature regime, the resulting structure and properties of the material can differ. It is found out that the SHS-material produced at the initial synthesis temperature T = 400°C possesses the largest number of micropores in the pore wall surface structure due to a high phase inhomogeneity of the alloy. The regime of structure optimization of the resulting materials is described and the main stages of formation of the pore wall microporous surfaces are revealed. It is demonstrated that after optimization of the surface structure of a TiNi-based fine-pore alloy by its chemical etching, the fraction of micropores measuring in size less than 50 nm increased from 59 to 68%, while the number of pores larger than 1 μm increased twofold from 11 to 22%. In addition, peculiar features of interaction between certain cell cultures with the surface of the SHS-material manufactured at different initial synthesis temperatures are revealed. It is found out that the dynamics of the cell material integration depends on the pore wall surface morphology and dimensions of macropores.

  20. Phenotypic plasticity of fine root growth increases plant productivity in pine seedlings

    Directory of Open Access Journals (Sweden)

    Grissom James E

    2004-09-01

    Full Text Available Abstract Background The plastic response of fine roots to a changing environment is suggested to affect the growth and form of a plant. Here we show that the plasticity of fine root growth may increase plant productivity based on an experiment using young seedlings (14-week old of loblolly pine. We use two contrasting pine ecotypes, "mesic" and "xeric", to investigate the adaptive significance of such a plastic response. Results The partitioning of biomass to fine roots is observed to reduce with increased nutrient availability. For the "mesic" ecotype, increased stem biomass as a consequence of more nutrients may be primarily due to reduced fine-root biomass partitioning. For the "xeric" ecotype, the favorable influence of the plasticity of fine root growth on stem growth results from increased allocation of biomass to foliage and decreased allocation to fine roots. An evolutionary genetic analysis indicates that the plasticity of fine root growth is inducible, whereas the plasticity of foliage is constitutive. Conclusions Results promise to enhance a fundamental understanding of evolutionary changes of tree architecture under domestication and to design sound silvicultural and breeding measures for improving plant productivity.

  1. Mechanical strength development of mortars containing volcanic scoria-based binders with different fineness

    Directory of Open Access Journals (Sweden)

    Aref M. al-Swaidani

    2016-06-01

    Full Text Available The benefits of using natural pozzolan as cement replacement are often associated with shortcomings such as the need to moist-curing for longer time and a reduction of strength at early ages. The objective of the study is to investigate the influence of binder fineness on the mechanical strength development of scoria-based binder mortars. In the study, mortar specimens have been produced with four types of binder: one plain Portland cement (control and three scoria-based binders with three replacement levels: 25%, 30% and 35%, respectively. All scoria-based binders have been inter-ground into four different Blaine fineness: 2400, 3200, 4200 and 5100 cm2/g. The development of the compressive and flexural tensile strength of all mortar specimens with curing time has been investigated. The effects of the Blaine fineness of the scoria-based blended cement on the compressive and flexural strengths of mortar have been evaluated at curing ages of 2, 7, 28 and 90 days, respectively. Particle size distribution measured by a laser diffractometer has been considered in the study. Test results revealed that there is a decrease in strength with increasing amounts of scoria. In addition, there was found an increase in strength with increasing the Blaine fineness values. No direct relationship between Blaine and particle size distribution was observed. Effects of Blaine fineness on some physical properties of blended cements such as water demand, setting times and soundness have also been investigated. Further, an estimation equation for strength development incorporating the effects of fineness measured either by Blaine or by particle size distribution has been derived by the authors.

  2. Burrowing inhibition by fine textured beach fill: Implications for recovery of beach ecosystems

    Science.gov (United States)

    Viola, Sloane M.; Hubbard, David M.; Dugan, Jenifer E.; Schooler, Nicholas K.

    2014-10-01

    Beach nourishment is often considered the most environmentally sound method of maintaining eroding shorelines. However, the ecological consequences are poorly understood. Fill activities cause intense disturbance and high mortality and have the potential to alter the diversity, abundance, and distribution of intertidal macroinvertebrates for months to years. Ecological recovery following fill activities depends on successful recolonization and recruitment of the entire sandy intertidal community. The use of incompatible sediments as fill material can strongly affect ecosystem recovery. We hypothesized that burrowing inhibition of intertidal animals by incompatible fine fill sediments contributes to ecological impacts and limits recovery in beach ecosystems. We experimentally investigated the influence of intertidal zone and burrowing mode on responses of beach invertebrates to altered sediment texture (28-38% fines), and ultimately the potential for colonization and recovery of beaches disturbed by beach filling. Using experimental trials in fill material and natural beach sand, we found that the mismatched fine fill sediments significantly inhibited burrowing of characteristic species from all intertidal zones, including sand crabs, clams, polychaetes, isopods, and talitrid amphipods. Burrowing performance of all five species we tested was consistently reduced in the fill material and burrowing was completely inhibited for several species. The threshold for burrowing inhibition by fine sediment content in middle and lower beach macroinvertebrates varied by species, with highest sensitivity for the polychaete (4% fines, below the USA regulatory limit of 10% fines), followed by sand crabs and clams (20% fines). These results suggest broader investigation of thresholds for burrowing inhibition in fine fill material is needed for beach animals. Burrowing inhibition caused by mismatched fill sediments exposes beach macroinvertebrates to stresses, which could depress

  3. Exploratory analysis of fines for water pollution in Bangladesh

    Directory of Open Access Journals (Sweden)

    Nabil Haque

    2017-12-01

    Full Text Available As a consequence of rapid industrialization, the waterbodies of Bangladesh have transformed into seasonal dead zones from the ensuing pollution. Despite having environmental regulations to control industrial pollution, lack of effective enforcement has jeopardized environmental quality. Evaluation of enforcement mechanisms have not gained attention from researchers until recently. This qualitative and descriptive analysis illustrates the current enforcement regime for environmental compliance in Bangladesh focusing on fines levied on polluters. Although there are no official guidelines for fines based on type of violation, this paper identified that there are differences of fines among violation based on historical data. It was also found that textile factories are not penalized heavily compared to non-textile factories. Repeat offenders were found to be penalized at the same rate. This study can be used to design appropriate penalty structure based on violation types, and reform the enforcement system so that polluters pay principle is actually implemented.

  4. Peculiarities Of The Chemical Bond In Thorium Compounds And Fine X-Ray Photoelectron And O4,5(Th) Emission Spectral Structure

    International Nuclear Information System (INIS)

    Teterin, Yu.A.; Teterin, A.Yu.; Utkin, I.O.; Ivanov, K.E.; Terehov, V.A.; Ryzhkovc, M.V.; Vukchevich, L.J.

    2002-01-01

    On the basis of the XPS (0 - -1000 eV), x-ray 04 5(Th) low-energy (0 - 50eV) emission fine spectral structure parameters, and theoretical calculations results for electronic structure of Th, ThO 2 , and ThF 4 , the study of the Th6p-,5f- electronic states was carried out. As a result, despite the absence of the Th5f electrons in atomic Th, the Th5f atomic orbitals were established to be able to participate in the molecular orbital formation in thorium dioxide and tetrafluoride. In the MOLCAO approximation it enabled to suggest that the filled Th5f states exist in thorium compounds

  5. Fine scale microstructure in cast and aged duplex stainless steels investigated by small angle neutron scattering

    International Nuclear Information System (INIS)

    Epperson, J.E.; Lin, J.S.; Spooner, S.

    1986-02-01

    Small angle neutron scattering (SANS) allows clustering phenomena to be studied in systems for which the constituent atoms do not differ greatly in atomic number. This investigation used SANS to characterize the fine scale microstructure in two cast and aged duplex stainless steels; aging times extended up to eight years. The steels differed in ferrite content by about a factor of two. The scattering at lowest q was dominated by magnetic scattering effects associated with the ferrite phase. In the range 0.025 less than or equal to q less than or equal to 0.2A -1 , additional scattering due to a precipitating phase rich in Ni and Si was observed. This scattering was rather intense and revealed a volume fraction of precipitate, in the ferrite, estimated to be 12 to 18% after long time aging. After about 70,000 hours at 400 0 C, there were about 10 18 precipitate particles per cm 3 some 50A in mean diameter, and they were distributed in a nonrandom manner, i.e., spatially, short-range-ordered. This investigation suggests that after aging some 70,000 hours at 400 0 C, the precipitate in the ferrite phase is undergoing Ostwald ripening. The present data are insufficient to indicate at what time this ripening process began

  6. Micro Fine Sized Palm Oil Fuel Ash Produced Using a Wind Tunnel Production System

    Directory of Open Access Journals (Sweden)

    R. Ahmadi

    2016-01-01

    Full Text Available Micro fine sized palm oil fuel ash (POFA is a new supplementary cementitious material that can increase the strength, durability, and workability of concrete. However, production of this material incurs high cost and is not practical for the construction industry. This paper investigates a simple methodology of producing micro fine sized POFA by means of a laboratory scale wind tunnel system. The raw POFA obtained from an oil palm factory is first calcined to remove carbon residue and then grinded in Los Angeles abrasion machine. The grinded POFA is then blown in the fabricated wind tunnel system for separation into different ranges of particle sizes. The physical, morphological, and chemical properties of the micro fine sized POFA were then investigated using Laser Particle Size Analyser (PSA, nitrogen sorption, and Scanning Electron Microscopy with Energy Dispersive X-Ray (SEM-EDX. A total of 32.1% micro fine sized POFA were collected from each sample blown, with the size range of 1–10 micrometers. The devised laboratory scale of wind tunnel production system is successful in producing micro fine sized POFA and, with modifications, this system is envisaged applicable to be used to commercialize micro fine sized POFA production for the construction industry.

  7. Recycling of PET bottles as fine aggregate in concrete.

    Science.gov (United States)

    Frigione, Mariaenrica

    2010-06-01

    An attempt to substitute in concrete the 5% by weight of fine aggregate (natural sand) with an equal weight of PET aggregates manufactured from the waste un-washed PET bottles (WPET), is presented. The WPET particles possessed a granulometry similar to that of the substituted sand. Specimens with different cement content and water/cement ratio were manufactured. Rheological characterization on fresh concrete and mechanical tests at the ages of 28 and 365days were performed on the WPET/concretes as well as on reference concretes containing only natural fine aggregate in order to investigate the influence of the substitution of WPET to the fine aggregate in concrete. It was found that the WPET concretes display similar workability characteristics, compressive strength and splitting tensile strength slightly lower that the reference concrete and a moderately higher ductility. Copyright 2010 Elsevier Ltd. All rights reserved.

  8. Multiscale pore structure and constitutive models of fine-grained rocks

    Science.gov (United States)

    Heath, J. E.; Dewers, T. A.; Shields, E. A.; Yoon, H.; Milliken, K. L.

    2017-12-01

    A foundational concept of continuum poromechanics is the representative elementary volume or REV: an amount of material large enough that pore- or grain-scale fluctuations in relevant properties are dissipated to a definable mean, but smaller than length scales of heterogeneity. We determine 2D-equivalent representative elementary areas (REAs) of pore areal fraction of three major types of mudrocks by applying multi-beam scanning electron microscopy (mSEM) to obtain terapixel image mosaics. Image analysis obtains pore areal fraction and pore size and shape as a function of progressively larger measurement areas. Using backscattering imaging and mSEM data, pores are identified by the components within which they occur, such as in organics or the clastic matrix. We correlate pore areal fraction with nano-indentation, micropillar compression, and axysimmetic testing at multiple length scales on a terrigenous-argillaceous mudrock sample. The combined data set is used to: investigate representative elementary volumes (and areas for the 2D images); determine if scale separation occurs; and determine if transport and mechanical properties at a given length scale can be statistically defined. Clear scale separation occurs between REAs and observable heterogeneity in two of the samples. A highly-laminated sample exhibits fine-scale heterogeneity and an overlapping in scales, in which case typical continuum assumptions on statistical variability may break down. Sandia National Laboratories is a multimission laboratory managed and operated by National Technology and Engineering Solutions of Sandia LLC, a wholly owned subsidiary of Honeywell International Inc. for the U.S. Department of Energy's National Nuclear Security Administration under contract DE-NA0003525.

  9. Electrosmotic conductivity in fine grained soils; Permeabilita' elettroosmotica in terreni a grana fine

    Energy Technology Data Exchange (ETDEWEB)

    Fava, G.; Giaco' , A.; Pasqualini, E.; Sani, D. [Ancona Univ., Ancona (Italy). Dipt. di Scienze dei Materiali e della Terra

    1999-10-01

    In this work, aspects relating to the process of mass and energy flows in fine grained soil under an electrical field are considered. A suitable apparatus for the study of electrokinetic phenomena and the measure of electrosmotic conductivity coefficients is projected and constructed. The obtained results are reliable and in accord with the common literature data. The values of the electrosmotic conductivity obtained depend on the cation exchange capacity of utilised soils and on the effective porosity of investigated samples. [Italian] Nel presente lavoro sono presi in esame gli aspetti generali relativi ai processi che regolano i flussi di materia e di energia nei terreni a grana fine in presenza di un campo elettrico. Vengono presentati i risultati di una sperimentazione su di un dispositivo appositamente progettato e realizzato per la misura della permeabilita' elettroosmotica e lo studio del trasporto elettrocinetico. I dati ottenuti sono risultati ripetibili e confrontabili con valori di letteratura consolidati. E' stato riscontrato che i coefficienti di permeabilita' elettroosmotica dipendono dalla capacita' di scambio cationico del terreno selezionato e dalla porosita' efficace dei campioni.

  10. Lattice distortions in TlInSe{sub 2} thermoelectric material studied by X-ray absorption fine structure

    Energy Technology Data Exchange (ETDEWEB)

    Hosokawa, Shinya; Stellhorn, Jens Ruediger [Department of Physics, Kumamoto University, Kumamoto (Japan); Ikemoto, Hiroyuki [Department of Physics, University of Toyama, Toyama (Japan); Mimura, Kojiro [Department of Mathematical Sciences, Graduate School of Engineering, Osaka Prefecture University, Sakai (Japan); Wakita, Kazuki [Faculty of Engineering, Chiba Institute of Technology, Narashino (Japan); Mamedov, Nazim [Institute of Physics, Azerbaijan National Academy of Sciences, Baku (Azerbaijan)

    2018-01-15

    Tl L{sub II} and In K X-ray absorption fine structure (XAFS) measurements were performed on a TlInSe{sub 2} thermoelectric material in the temperature range of 25-300 K including the incommensurate-commensurate phase transition temperature of about 135 K. Most of the bond lengths obtained from the present XAFS measurements are in good agreement with existing X-ray diffraction data at room temperature, while only the Tl-Tl correlation shows inconsistent values indicating the commensurate properties of the Tl chains expected from the thermodynamic properties. The present XAFS data clearly support positional fluctuations of the Tl atoms found in three-dimensional atomic images reconstructed from X-ray fluorescence holography. (copyright 2017 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  11. Frequency-comb based collinear laser spectroscopy of Be for nuclear structure investigations and many-body QED tests

    CERN Document Server

    Krieger, A

    2017-01-01

    Absolute transition frequencies of the $2s\\,^2{\\rm{S}}_{1/2}$ $\\rightarrow$ $2p\\,^2{\\rm{P}}_{1/2,3/2}$ transitions in Be$^+$ were measured with a frequency comb in stable and short-lived isotopes at ISOLDE (CERN) using collinear laser spectroscopy. Quasi-simultaneous measurements in copropagating and counterpropagating geometry were performed to become independent from acceleration voltage determinations for Doppler-shift corrections of the fast ion beam. Isotope shifts and fine structure splittings were obtained from the absolute transition frequencies with accuracies better than 1\\,MHz and led to a precise determination of the nuclear charge radii of $^{7,10-12}$Be relative to the stable isotope $^9$Be. Moreover, an accurate determination of the $2p$ fine structure splitting allowed a test of high-precision bound-state QED calculations in the three-electron system. Here, we describe the laser spectroscopic method in detail, including several tests that were carried out to determine or estimate systematic un...

  12. Biological effects of long term fine limestone tailings discharge in a fjord ecosystem.

    Science.gov (United States)

    Brooks, Lucy; Melsom, Fredrik; Glette, Tormod

    2015-07-15

    Benthic infaunal data collected from 1993 to 2010 were analysed to examine the effect of long term discharge of fine limestone tailings on macrofaunal species assemblages in a fjord. Relative distance from the outfall and proportion of fine tailings in the sediment were correlated with benthic community structure. Diversity decreased with increasing proportion of fine tailings. Biological Traits Analysis (BTA) was used to explore the temporal and spatial effects of the tailings gradient on macrofaunal functional attributes. BTA revealed that all stations along a pressure gradient of fine limestone tailings were dominated by free-living species. As the proportion of fine tailings in the sediment increased, there was an increase in fauna that were smaller, highly mobile, living on or nearer the surface sediment, with shorter lifespans. There was a decrease in permanent tube dwellers, those fauna with low or no mobility, that live deeper in the sediment and have longer lifespans (>5 yrs). Copyright © 2015 Elsevier Ltd. All rights reserved.

  13. An investigation of fine structure of the bursts produced by muons in the rock

    International Nuclear Information System (INIS)

    Higashi, S.; Kajino, F.; Nakashita, M.; Osaki, S.; Takahashi, T.; Yamamoto, S.

    1981-01-01

    Two dimensional lateral structures of the shower particles in the bursts, produced by high energy muons in the rock, have been studied by using the four layers of proportional counters. The mean lateral distributions measured fit well to those of Monte Carlo simulation of electromagnetic cascade showers. The distributions of reduced chi 2 which correspond to the fluctuations of each lateral distribution from the mean value show that the rates of the events giving high chi 2 for the data are somewhat greater than those expected from the simulation. The rates of these excesses to the total events are about 10% in the burst size range 578 - 8277 particles which are induced by the muons in the energy range 714 - 9900 GeV. These excesses could be explained by the contributions from the muon nuclear interactions in the rock

  14. Preparation, microstructure and degradation performance of biomedical magnesium alloy fine wires

    Directory of Open Access Journals (Sweden)

    Jing Bai

    2014-10-01

    Full Text Available With the development of new biodegradable Mg alloy implant devices, the potential applications of biomedical Mg alloy fine wires are realized and explored gradually. In this study, we prepared three kinds of Mg alloy fine wires containing 4 wt% RE(Gd/Y/Nd and 0.4 wt% Zn with the diameter less than 0.4 μm through casting, hot extruding and multi-pass cold drawing combined with intermediated annealing process. Their microstructures, mechanical and degradation properties were investigated. In comparison with the corresponding as-extruded alloy, the final fine wire has significantly refined grain with an average size of 3–4 μm, and meanwhile shows higher yield strength but lower ductility at room temperature. The degradation tests results and surface morphologies observations indicate that Mg–4Gd–0.4Zn and Mg–4Nd–0.4Zn fine wires have similar good corrosion resistance and the uniform corrosion behavior in SBF solution. By contrast, Mg–4Y–0.4Zn fine wire shows a poor corrosion resistance and the pitting corrosion behavior.

  15. Structural investigation of biogenic ferrihydrite nanoparticles dispersion

    International Nuclear Information System (INIS)

    Balasoiu, M.; Ishchenko, L.A.; Stolyar, S.V.; Iskhakov, R.S.; Rajkher, Yu.L.; Kuklin, A.I.; Solov'ev, D.V.; Arzumanyan, G.M.; Kurkin, T.S.; Aranghel, D.

    2010-01-01

    Structural properties of biogenic ferrihydrite nanoparticles produced by bacteria Klebsiella oxytoca are investigated. Investigations of morphology and size of particles dispersed in water by means of high-resolution transmission electron microscopy and small angle X-ray scattering measurements were performed. By model calculations followed by fitting procedure the structural parameters of a cylinder of radius R = (4.87 ± 0.02) nm and height L = (2.12 ± 0.04) nm are obtained

  16. The effect of amblyopia on fine motor skills in children.

    Science.gov (United States)

    Webber, Ann L; Wood, Joanne M; Gole, Glen A; Brown, Brian

    2008-02-01

    In an investigation of the functional impact of amblyopia in children, the fine motor skills of amblyopes and age-matched control subjects were compared. The influence of visual factors that might predict any decrement in fine motor skills was also explored. Vision and fine motor skills were tested in a group of children (n = 82; mean age, 8.2 +/- 1.7 [SD] years) with amblyopia of different causes (infantile esotropia, n = 17; acquired strabismus, n = 28; anisometropia, n = 15; mixed, n = 13; and deprivation n = 9), and age-matched control children (n = 37; age 8.3 +/- 1.3 years). Visual motor control (VMC) and upper limb speed and dexterity (ULSD) items of the Bruininks-Oseretsky Test of Motor Proficiency were assessed, and logMAR visual acuity (VA) and Randot stereopsis were measured. Multiple regression models were used to identify the visual determinants of fine motor skills performance. Amblyopes performed significantly poorer than control subjects on 9 of 16 fine motor skills subitems and for the overall age-standardized scores for both VMC and ULSD items (P multiple regression model that took into account the intercorrelation between visual characteristics, poorer fine motor skills performance was associated with strabismus (F(1,75) = 5.428; P = 0.022), but not with the level of binocular function, refractive error, or visual acuity in either eye. Fine motor skills were reduced in children with amblyopia, particularly those with strabismus, compared with control subjects. The deficits in motor performance were greatest on manual dexterity tasks requiring speed and accuracy.

  17. Limited Effects of Variable-Retention Harvesting on Fungal Communities Decomposing Fine Roots in Coastal Temperate Rainforests.

    Science.gov (United States)

    Philpott, Timothy J; Barker, Jason S; Prescott, Cindy E; Grayston, Sue J

    2018-02-01

    Fine root litter is the principal source of carbon stored in forest soils and a dominant source of carbon for fungal decomposers. Differences in decomposer capacity between fungal species may be important determinants of fine-root decomposition rates. Variable-retention harvesting (VRH) provides refuge for ectomycorrhizal fungi, but its influence on fine-root decomposers is unknown, as are the effects of functional shifts in these fungal communities on carbon cycling. We compared fungal communities decomposing fine roots (in litter bags) under VRH, clear-cut, and uncut stands at two sites (6 and 13 years postharvest) and two decay stages (43 days and 1 year after burial) in Douglas fir forests in coastal British Columbia, Canada. Fungal species and guilds were identified from decomposed fine roots using high-throughput sequencing. Variable retention had short-term effects on β-diversity; harvest treatment modified the fungal community composition at the 6-year-postharvest site, but not at the 13-year-postharvest site. Ericoid and ectomycorrhizal guilds were not more abundant under VRH, but stand age significantly structured species composition. Guild composition varied by decay stage, with ruderal species later replaced by saprotrophs and ectomycorrhizae. Ectomycorrhizal abundance on decomposing fine roots may partially explain why fine roots typically decompose more slowly than surface litter. Our results indicate that stand age structures fine-root decomposers but that decay stage is more important in structuring the fungal community than shifts caused by harvesting. The rapid postharvest recovery of fungal communities decomposing fine roots suggests resiliency within this community, at least in these young regenerating stands in coastal British Columbia. IMPORTANCE Globally, fine roots are a dominant source of carbon in forest soils, yet the fungi that decompose this material and that drive the sequestration or respiration of this carbon remain largely

  18. Fatigue and creep–fatigue deformation of an ultra-fine precipitate strengthened advanced austenitic alloy

    International Nuclear Information System (INIS)

    Carroll, M.C.; Carroll, L.J.

    2012-01-01

    An advanced austenitic alloy, HT-UPS (high-temperature ultrafine-precipitation-strengthened), has been identified as an ideal candidate material for the structural components of fast reactors and energy-conversion systems. HT-UPS alloys demonstrate improved creep resistance relative to 316 stainless steel (SS) through additions of Ti and Nb, which precipitate to form a widespread dispersion of stable nanoscale metallic carbide (MC) particles in the austenitic matrix. To investigate the behavior in more representative conditions than are offered by uniaxial creep tests, the low-cycle continuous fatigue and combined creep–fatigue response of an HT-UPS alloy have been investigated at 650 °C and 1.0% total strain, with an R-ratio of −1 and hold times at peak tensile strain of up to 150 min. The cyclic deformation response of HT-UPS is directly compared to that of standard 316 SS. The measured values for total cycles to failure between the two alloys are similar, despite differences in peak stress profiles and in qualitative observations of the deformed microstructures. Crack propagation is primarily transgranular in both fatigue and creep–fatigue of each alloy at the investigated conditions. Internal grain boundary damage in the form of fine cracks resulting from the tensile hold is present following the application of hold times of 60 min and longer, and considerably more internal cracks are quantifiable in 316 SS than in HT-UPS. The dislocation substructures observed in the deformed material differ substantially; an equiaxed cellular structure is observed in the microstructure of 316 SS, whereas HT-UPS exhibits widespread and relatively homogenous tangles of dislocations pinned by the nanoscale MC precipitates. The significant effect of the fine distribution of precipitates on observed fatigue and creep–fatigue response is described in three distinct behavioral regions as the microstructure evolves with continued cycling.

  19. Fatigue and creep-fatigue deformation of an ultra-fine precipitate strengthened advanced austenitic alloy

    Energy Technology Data Exchange (ETDEWEB)

    Carroll, M.C., E-mail: Mark.Carroll@INL.gov [Idaho National Laboratory, 1955 Fremont, PO Box 1625, Idaho Falls, ID 83415-2218 (United States); Carroll, L.J. [Idaho National Laboratory, 1955 Fremont, PO Box 1625, Idaho Falls, ID 83415-2218 (United States)

    2012-10-30

    An advanced austenitic alloy, HT-UPS (high-temperature ultrafine-precipitation-strengthened), has been identified as an ideal candidate material for the structural components of fast reactors and energy-conversion systems. HT-UPS alloys demonstrate improved creep resistance relative to 316 stainless steel (SS) through additions of Ti and Nb, which precipitate to form a widespread dispersion of stable nanoscale metallic carbide (MC) particles in the austenitic matrix. To investigate the behavior in more representative conditions than are offered by uniaxial creep tests, the low-cycle continuous fatigue and combined creep-fatigue response of an HT-UPS alloy have been investigated at 650 Degree-Sign C and 1.0% total strain, with an R-ratio of -1 and hold times at peak tensile strain of up to 150 min. The cyclic deformation response of HT-UPS is directly compared to that of standard 316 SS. The measured values for total cycles to failure between the two alloys are similar, despite differences in peak stress profiles and in qualitative observations of the deformed microstructures. Crack propagation is primarily transgranular in both fatigue and creep-fatigue of each alloy at the investigated conditions. Internal grain boundary damage in the form of fine cracks resulting from the tensile hold is present following the application of hold times of 60 min and longer, and considerably more internal cracks are quantifiable in 316 SS than in HT-UPS. The dislocation substructures observed in the deformed material differ substantially; an equiaxed cellular structure is observed in the microstructure of 316 SS, whereas HT-UPS exhibits widespread and relatively homogenous tangles of dislocations pinned by the nanoscale MC precipitates. The significant effect of the fine distribution of precipitates on observed fatigue and creep-fatigue response is described in three distinct behavioral regions as the microstructure evolves with continued cycling.

  20. Fine- and hyperfine-structure effects in molecular photoionization. II. Resonance-enhanced multiphoton ionization and hyperfine-selective generation of molecular cations

    Energy Technology Data Exchange (ETDEWEB)

    Germann, Matthias; Willitsch, Stefan, E-mail: stefan.willitsch@unibas.ch [Department of Chemistry, University of Basel, Klingelbergstrasse 80, 4056 Basel (Switzerland)

    2016-07-28

    Resonance-enhanced multiphoton ionization (REMPI) is a widely used technique for studying molecular photoionization and producing molecular cations for spectroscopy and dynamics studies. Here, we present a model for describing hyperfine-structure effects in the REMPI process and for predicting hyperfine populations in molecular ions produced by this method. This model is a generalization of our model for fine- and hyperfine-structure effects in one-photon ionization of molecules presented in Paper I [M. Germann and S. Willitsch, J. Chem. Phys. 145, 044314 (2016)]. This generalization is achieved by covering two main aspects: (1) treatment of the neutral bound-bound transition including the hyperfine structure that makes up the first step of the REMPI process and (2) modification of our ionization model to account for anisotropic populations resulting from this first excitation step. Our findings may be used for analyzing results from experiments with molecular ions produced by REMPI and may serve as a theoretical background for hyperfine-selective ionization experiments.