WorldWideScience

Sample records for final groundwater remediation

  1. Groundwater remediation in the Straz leaching operation

    International Nuclear Information System (INIS)

    Novak, J.

    2001-01-01

    The locality affected by consequences of the chemical mining of the uranium during underground leaching 'in situ' is found in the area of the Czech Republic in the northeastern part of the Ceska Lipa district. In the contribution the complex groundwater remediation project is discussed. First, the risks of the current state are expressed. Then the alternatives of remediation of the both Cenomanian and Turonian aquifers are presented. Evaluation of the remediation alternatives with the view to the time-consumption, economy, ecology and the elimination of unacceptable risks for the population and environment is done. Finally, the present progress of remediation and the conception of remediation of chemical mining on deposit of Straz pod Ralskem are presented. (orig.)

  2. Hanford Sitewide Groundwater Remediation Strategy

    International Nuclear Information System (INIS)

    Knepp, A.J.; Isaacs, J.D.

    1997-09-01

    This document fulfills the requirements of the Hanford Federal Facility Agreement and Consent Order, Milestone M-13-81, to develop a concise statement of strategy that describe show the Hanford Site groundwater remediation will be accomplished. The strategy addresses objectives and goals, prioritization of activities, and technical approaches for groundwater cleanup. The strategy establishes that the overall goal of groundwater remediation on the Hanford Site is to restore groundwater to its beneficial uses in terms of protecting human health and the environment, and its use as a natural resource. The Hanford Future Site Uses Working Group established two categories for groundwater commensurate with various proposed landuses: (1) restricted use or access to groundwater in the Central Plateau and in a buffer zone surrounding it and (2) unrestricted use or access to groundwater for all other areas. In recognition of the Hanford Future Site Uses Working Group and public values, the strategy establishes that the sitewide approach to groundwater cleanup is to remediate the major plumes found in the reactor areas that enter the Columbia River and to contain the spread and reduce the mass of the major plumes found in the Central Plateau

  3. Development of a sitewide groundwater remediation strategy at the Hanford Site, Washington

    International Nuclear Information System (INIS)

    Goswami, D.

    1996-01-01

    Over 440 km 2 (170 mi 2 ) of groundwater beneath the Hanford Site are contaminated by hazardous and radioactive waste, out of which almost half is over state and federal drinking water standards. In addition to the complicated nature of these plumes, remediation is further obscured by limited application of available technologies and hydrogeologic information. This paper briefly describes the processes used by the Washington State Department of Ecology (Ecology), U.S. Environmental Protection Agency, and U.S. Department of Energy (USDOE) in developing a sitewide groundwater remediation strategy for Hanford and its outcome. As an initial approach to sitewide groundwater remediation, the strategy is to remediate the major plumes found in the reactor areas (100 Area) adjacent to the Columbia River and contain the major plumes found in the Central Plateau region (200 Area). This approach was based mainly on the qualitative risk, stakeholder's and tribe's values, and available technical feasibility. The strategy emphasizes the use of existing treatment and extraction technology for the remediation of groundwater in combination with proposed and existing site infrastructure. This work is being performed in parallel with ongoing risk and other feasibility activities. Under this strategy, innovative technologies being developed are in the areas of dense nonaqueous phase liquid identification and recovery, and problems associated with strontium-90, cesium-137, and plutonium in the vadose zone and groundwater. The final remediation strategy alternatives remain a product of risk assessment, technical feasibility, site use scenario, and cost consideration. In order to develop a strategy for the final cleanup, several issues such as aquifer restoration, natural attenuation, potential contamination of groundwater from the tank farms and from the existing contamination source in the vadose zone must be looked in detail in conjuction with public and stakeholder's values

  4. Engineering evaluation/conceptual plan for the 200-UP-1 groundwater operable unit interim remedial measure

    International Nuclear Information System (INIS)

    Myers, D.A.; Swanson, L.C.; Weeks, R.S.; Giacinto, J.; Gustafson, F.W.; Ford, B.H.; Wittreich, C.; Parnell, S.; Green, J.

    1995-04-01

    This report presents an engineering evaluation and conceptual plan for an interim remedial measure (ERM) to address a uranium and technetium-99 groundwater plume and an associated nitrate contamination plume in the 200-UP-1 Groundwater Operable Unit located in the 200 West Area of the Hanford Site. This report provides information regarding the need and potentially achievable objectives and goals for an IRM and evaluates alternatives to contain elevated concentrations of uranium, technetium-99, nitrate, and carbon tetrachloride and to obtain information necessary to develop final remedial actions for the operable unit

  5. Technical options for the remediation of contaminated groundwater

    Energy Technology Data Exchange (ETDEWEB)

    1999-06-01

    This report provides a description of the nature and extent of problems related to radioactive groundwater contamination by outlining the environmental impacts, the sources of contamination and the contaminants of concern radionuclides and their associated contaminants - the main exposure pathways and transport processes and the assessment of risks associated with contaminated groundwater. The main emphasis of this report is on methodologies used in groundwater remediation and available technologies. The methodology section outlines the importance of an initial scoping analysis including the evaluation of uncertainties of the available data and the necessity for defining clear objectives for data collection. This is then followed by comprehensive site characterization, setting of goals and developing alternatives which will be analysed in detail. Available technologies are grouped generally into in situ methods aiming at a containment of the contaminants in place and engineered treatment methods involving an alteration of groundwater flow, quantity and/or quality to achieve compliance with set goals. Groundwater remediation by natural flushing allows the natural groundwater movement and geochemical processes to decrease the contaminant concentrations to acceptable levels over a specified period of time. This method is increasingly accepted in areas where the use of groundwater can be temporarily restricted or engineered cleanup methods do not offer particular advantage over the natural processes. The application of technological methods for remediating contaminated groundwaters has to be considered in conjunction with management options such as diversion and development of alternative water sources. The experience with groundwater contamination accrued in IAEA Member States is concentrated in those countries with active uranium mining and milling facilities and nuclear energy programmes. This experience is reported in the Annexes, which include case studies. It

  6. Technical options for the remediation of contaminated groundwater

    International Nuclear Information System (INIS)

    1999-06-01

    This report provides a description of the nature and extent of problems related to radioactive groundwater contamination by outlining the environmental impacts, the sources of contamination and the contaminants of concern radionuclides and their associated contaminants - the main exposure pathways and transport processes and the assessment of risks associated with contaminated groundwater. The main emphasis of this report is on methodologies used in groundwater remediation and available technologies. The methodology section outlines the importance of an initial scoping analysis including the evaluation of uncertainties of the available data and the necessity for defining clear objectives for data collection. This is then followed by comprehensive site characterization, setting of goals and developing alternatives which will be analysed in detail. Available technologies are grouped generally into in situ methods aiming at a containment of the contaminants in place and engineered treatment methods involving an alteration of groundwater flow, quantity and/or quality to achieve compliance with set goals. Groundwater remediation by natural flushing allows the natural groundwater movement and geochemical processes to decrease the contaminant concentrations to acceptable levels over a specified period of time. This method is increasingly accepted in areas where the use of groundwater can be temporarily restricted or engineered cleanup methods do not offer particular advantage over the natural processes. The application of technological methods for remediating contaminated groundwaters has to be considered in conjunction with management options such as diversion and development of alternative water sources. The experience with groundwater contamination accrued in IAEA Member States is concentrated in those countries with active uranium mining and milling facilities and nuclear energy programmes. This experience is reported in the Annexes, which include case studies. It

  7. Application of ozone micro-nano-bubbles to groundwater remediation.

    Science.gov (United States)

    Hu, Liming; Xia, Zhiran

    2018-01-15

    Ozone is widely used for water treatment because of its strong oxidation ability. However, the efficiency of ozone in groundwater remediation is limited because of its relatively low solubility and rapid decomposition in the aqueous phase. Methods for increasing the stability of ozone within the subsurface are drawing increasing attention. Micro-nano-bubbles (MNBs), with diameters ranging from tens of nanometres to tens of micrometres, present rapid mass transfer rates, persist for a relatively long time in water, and transport with groundwater flow, which significantly improve gas concentration and provide a continuous gas supply. Therefore, MNBs show a considerable potential for application in groundwater remediation. In this study, the characteristics of ozone MNBs were examined, including their size distribution, bubble quantity, and zeta potential. The mass transfer rate of ozone MNBs was experimentally investigated. Ozone MNBs were then used to treat organics-contaminated water, and they showed remarkable cleanup efficiency. Column tests were also conducted to study the efficiency of ozone MNBs for organics-contaminated groundwater remediation. Based on the laboratory tests, field monitoring was conducted on a trichloroethylene (TCE)-contaminated site. The results showed that ozone MNBs can greatly improve remediation efficiency and represent an innovative technology for in situ remediation of organics-contaminated groundwater. Copyright © 2017 The Author(s). Published by Elsevier B.V. All rights reserved.

  8. Groundwater remediation from the past to the future: A bibliometric analysis.

    Science.gov (United States)

    Zhang, Shu; Mao, Guozhu; Crittenden, John; Liu, Xi; Du, Huibin

    2017-08-01

    Groundwater is an important component of terrestrial ecosystems and plays a role in geochemical cycling. Groundwater is also used for agricultural irrigation and for the domestic supply of drinking water in most nations. However, groundwater contamination has led to many research efforts on groundwater remediation technologies and strategies. This study evaluated a total of 5486 groundwater remediation-related publications from 1995 to 2015 using bibliometric technology and social network analysis, to provide a quantitative analysis and a global view on the current research trend and future research directions. Our results underline a strong research interest and an urgent need to remediate groundwater pollution due to the increasing number of both groundwater contamination and remediation publications. In the past two decades, the United States (U.S.) published 41.1% of the papers and it was the core country of the international collaboration network, cooperating with the other 19 most productive countries. Besides the active international collaboration, the funding agencies also played positive roles to foster the science and technology publications. With respect to the analysis of the distribution of funding agencies, the National Science Foundation of China sponsored most of the groundwater remediation research. We also identified the most productive journals, Environmental Science and Technology and Journal of Contaminant Hydrology, which published 334 and 259 scientific articles (including research articles and reviews) over the past 20 years, respectively. In addition to journal publications, a patent analysis was performed to show the impact of intellectual property protection on journal publications. Three major remediation technologies, including chemical oxidation, biodegradation and adsorption, have received increasing interest in both journal publication and patent development. Our results provide a valuable reference and global overview to identify

  9. Use of LCA as decision support for the selection of remedial strategies for remediation of contaminated soil and groundwater

    DEFF Research Database (Denmark)

    Lemming, Gitte; Hauschild, Michael Zwicky; Bjerg, Poul Løgstrup

    2009-01-01

    , there is a trade-off between obtaining local beneficial effects from the remediation and generating environmental impacts on the regional and global scale due to the remedial actions. Therefore there is a need for including the impact of soil contaminants that will potentially leach to the groundwater, e......Groundwater is the dominant source of drinking water in Denmark and the general policy is to maintain the groundwater as a clean source of drinking water. The risk of groundwater contamination is therefore often the prime reason for remediating a contaminated site. Chlorinated solvents are among...... the contaminants most frequently found to be threatening the groundwater quality in Denmark and worldwide. Life cycle assessment has recently been applied as part of decision support for contaminated site management and subsurface remediation techniques. Impacts in the groundwater compartment have only gained...

  10. Application of optimization modeling to groundwater remediation at US Department of Energy facilities

    International Nuclear Information System (INIS)

    Bakr, A.A.; Dal Santo, D.J.; Smalley, R.C.; Phillips, E.C.

    1988-01-01

    This paper outlines and explores the fundamentals of the current strategies for groundwater hydraulic and quality management modeling and presents a scheme for the application of such strategies to DOE facilities. The discussion focuses on the DOE-Savannah River Operations (DOE-SR) facility. Remediation of contaminated groundwater at active and abandoned waste disposal sites has become a major element of environmental programs. Traditional groundwater remediation programs (e.g., pumping and treatment) may not represent optimal water quality management strategies at sites to be remediated. Complex, interrelated environmental (geologic/geohydrologic), institutional, engineering, and economic conditions at a site may require a more comprehensive management strategy. Groundwater management models based on the principles of operations research have been developed and used to determine optimal management strategies for water resources needs and for hypothetical remediation programs. Strategies for groundwater remediation programs have ranged from the simple removal of groundwater to complex, hydraulic gradient control programs involving groundwater removal, treatment, and recharge

  11. Engineering evaluation/conceptual plan for the 200-UP-1 Groundwater Operable Unit interim remedial measure. Revision 2

    International Nuclear Information System (INIS)

    1996-03-01

    This report presents an engineering evaluation and conceptual plan for an interim remedial measure (IRM) to address a uranium and technetium-99 groundwater plume in the 200-UP-1 Groundwater Operable Unit located in the 200 West Area of the Hanford Site. This report provides information regarding the need for an IRM and its potentially achievable objectives and goals. The report also evaluates alternatives to contain elevated concentrations of uranium and technetium-99 and to obtain information necessary to develop final remedial actions for the operable unit

  12. Stochastic goal programming based groundwater remediation management under human-health-risk uncertainty

    International Nuclear Information System (INIS)

    Li, Jing; He, Li; Lu, Hongwei; Fan, Xing

    2014-01-01

    Highlights: • We propose an integrated optimal groundwater remediation design approach. • The approach can address stochasticity in carcinogenic risks. • Goal programming is used to make the system approaching to ideal operation and remediation effects. • The uncertainty in slope factor is evaluated under different confidence levels. • Optimal strategies are obtained to support remediation design under uncertainty. - Abstract: An optimal design approach for groundwater remediation is developed through incorporating numerical simulation, health risk assessment, uncertainty analysis and nonlinear optimization within a general framework. Stochastic analysis and goal programming are introduced into the framework to handle uncertainties in real-world groundwater remediation systems. Carcinogenic risks associated with remediation actions are further evaluated at four confidence levels. The differences between ideal and predicted constraints are minimized by goal programming. The approach is then applied to a contaminated site in western Canada for creating a set of optimal remediation strategies. Results from the case study indicate that factors including environmental standards, health risks and technical requirements mutually affected and restricted themselves. Stochastic uncertainty existed in the entire process of remediation optimization, which should to be taken into consideration in groundwater remediation design

  13. Electrochemical remediation technologies for soil and groundwater

    Energy Technology Data Exchange (ETDEWEB)

    Doering, F. [Electrochemical Processes I.I. c. Valley Forge, PA (United States)]|[P2 Soil Remediation, Inc. Stuttgart (Germany); Doering, N. [P2 Soil Remediation, Inc. Stuttgart (Germany)

    2001-07-01

    In Direct Current Technologies (DCTs) a direct current electricity is passed between at least two subsurface electrodes in order to effect the remediation of the groundwater and/or the soil. DCTs in line with the U.S.-terminology comprise of the ElectroChemical Remediation Technologies (ECRTs), and GeoKinetics. The primary distinction between ECRTs and ElectroKinetics are the power input, and the mode of operation, which are electrochemical reactions vs. mass transport. ECRTs combine phenomena of colloid (surface) electrochemistry with the phenomena of Induced Polarization (IP). This report focuses on ECRTs, comprising of the ElectroChemical GeoOxidation (ECGO) for the mineralization of organic pollutants to finally carbon dioxide and water, and Induced Complexation (IC), related to the electrochemical conversion of metals enhancing the mobilization and precipitation of heavy metals on both electrodes. Both technologies are based on reduction-oxidation (redox) reactions at the scale of the individual soil particles. (orig.)

  14. Remedial Investigation/Feasibility Study Work Plan for the 200-UP-1 Groundwater Operable Unit, Hanford Site, Richland, Washington

    International Nuclear Information System (INIS)

    1994-01-01

    This work plan identifies the objectives, tasks, and schedule for conducting a Remedial Investigation/Feasibility Study for the 200-UP-1 Groundwater Operable Unit in the southern portion of the 200 West Groundwater Aggregate Area of the Hanford Site. The 200-UP-1 Groundwater Operable Unit addresses contamination identified in the aquifer soils and groundwater within its boundary, as determined in the 200 West Groundwater Aggregate Area Management Study Report (AAMSR) (DOE/RL 1992b). The objectives of this work plan are to develop a program to investigate groundwater contaminants in the southern portion of the 200 West Groundwater Aggregate Area that were designated for Limited Field Investigations (LFIs) and to implement Interim Remedial Measures (IRMs) recommended in the 200 West Groundwater AAMSR. The purpose of an LFI is to evaluate high priority groundwater contaminants where existing data are insufficient to determine whether an IRM is warranted and collect sufficient data to justify and implement an IRM, if needed. A Qualitative Risk Assessment (QRA) will be performed as part of the LFI. The purpose of an IRM is to develop and implement activities, such as contaminant source removal and groundwater treatment, that will ameliorate some of the more severe potential risks of groundwater contaminants prior to the RI and baseline Risk Assessment (RA) to be conducted under the Final Remedy Selection (FRS) at a later date. This work plan addresses needs of a Treatability Study to support the design and implementation of an interim remedial action for the Uranium- 99 T c -Nitrate multi-contaminant IRM plume identified beneath U Plant

  15. Black Swans and the Effectiveness of Remediating Groundwater Contamination

    Science.gov (United States)

    Siegel, D. I.; Otz, M. H.; Otz, I.

    2013-12-01

    Black swans, outliers, dominate science far more than do predictable outcomes. Predictable success constitutes the Black Swan in groundwater remediation. Even the National Research Council concluded that remediating groundwater to drinking water standards has failed in typically complex hydrogeologic settings where heterogeneities and preferential flow paths deflect flow paths obliquely to hydraulic gradients. Natural systems, be they biological or physical, build upon a combination of large-scale regularity coupled to chaos at smaller scales. We show through a review of over 25 case studies that groundwater remediation efforts are best served by coupling parsimonious site characterization to natural and induced geochemical tracer tests to at least know where contamination advects with groundwater in the subsurface. In the majority of our case studies, actual flow paths diverge tens of degrees from anticipated flow paths because of unrecognized heterogeneities in the horizontal direction of transport, let alone the vertical direction. Consequently, regulatory agencies would better serve both the public and the environment by recognizing that long-term groundwater cleanup probably is futile in most hydrogeologic settings except to relaxed standards similar to brownfielding. A Black Swan

  16. Soil and groundwater remediation using dual-phase extraction technology

    International Nuclear Information System (INIS)

    Miller, A.W.; Gan, D.R.

    1995-01-01

    A gasoline underground storage tank (UST) was formerly used to fuel vehicles for a hospital in Madison, Wisconsin. Elevated concentrations of gasoline range organics (GRO) were observed in soils and groundwater at the site during the tank removal and a subsequent site investigation. Based on the extent of soil and groundwater contamination, a dual-phase extraction technology was selected as the most cost effective alternative to remediate the site. The dual-phase extraction system includes one extraction well functioning both as a soil vapor extraction (SVE) and groundwater recovery well. After six months of operation, samples collected from the groundwater monitoring wells indicated that the groundwater has been cleaned up to levels below the Wisconsin preventative action limits. The dual-phase extraction system effectively remediated the site in a short period of time, saving both operation and maintenance costs and overall project cost

  17. Alternative Endpoints and Approaches for the Remediation of Contaminated Groundwater at Complex Sites - 13426

    International Nuclear Information System (INIS)

    Deeb, Rula A.; Hawley, Elisabeth L.

    2013-01-01

    alternative endpoints for groundwater remediation at complex sites. A statistical analysis of Comprehensive Environmental Response, Compensation and Liability Act (CERCLA) sites receiving TI waivers will be presented as well as case studies of other types of alternative endpoints and alternative remedial strategies that illustrate the variety of approaches used at complex sites and the technical analyses used to predict and document cost, time frame, and potential remedial effectiveness. This presentation is intended to inform DOE program managers, state regulators, practitioners and other stakeholders who are evaluating technical cleanup challenges within their own programs, and establishing programmatic approaches to evaluating and implementing long-term management approaches. Case studies provide examples of long-term management designations and strategies to manage and remediate groundwater at complex sites. At least 13 states consider some designation for groundwater containment in their corrective action policies, such as groundwater management zones, containment zones, and groundwater classification exemption areas. Long-term management designations are not a way to 'do nothing' or walk away from a site. Instead, soil and groundwater within the zone is managed to be protective of human health and the environment. Understanding when and how to adopt a long-term management approach can lead to cost savings and the more efficient use of resources across DOE and at numerous other industrial and military sites across the U.S. This presentation provides context for assessing the use and appropriate role of alternative endpoints and supporting long-term management designations in final remedies. (authors)

  18. Alternative Endpoints and Approaches for the Remediation of Contaminated Groundwater at Complex Sites - 13426

    Energy Technology Data Exchange (ETDEWEB)

    Deeb, Rula A.; Hawley, Elisabeth L. [ARCADIS, U.S., 2000 Powell St., 7th Floor, Emeryville, California 94608 (United States)

    2013-07-01

    to evaluate alternative endpoints for groundwater remediation at complex sites. A statistical analysis of Comprehensive Environmental Response, Compensation and Liability Act (CERCLA) sites receiving TI waivers will be presented as well as case studies of other types of alternative endpoints and alternative remedial strategies that illustrate the variety of approaches used at complex sites and the technical analyses used to predict and document cost, time frame, and potential remedial effectiveness. This presentation is intended to inform DOE program managers, state regulators, practitioners and other stakeholders who are evaluating technical cleanup challenges within their own programs, and establishing programmatic approaches to evaluating and implementing long-term management approaches. Case studies provide examples of long-term management designations and strategies to manage and remediate groundwater at complex sites. At least 13 states consider some designation for groundwater containment in their corrective action policies, such as groundwater management zones, containment zones, and groundwater classification exemption areas. Long-term management designations are not a way to 'do nothing' or walk away from a site. Instead, soil and groundwater within the zone is managed to be protective of human health and the environment. Understanding when and how to adopt a long-term management approach can lead to cost savings and the more efficient use of resources across DOE and at numerous other industrial and military sites across the U.S. This presentation provides context for assessing the use and appropriate role of alternative endpoints and supporting long-term management designations in final remedies. (authors)

  19. The UMTRA PEIS: A strategy for groundwater remediation

    International Nuclear Information System (INIS)

    Burt, C.; Ulland, L.; Weston, R.F.; Metzler, D.

    1993-01-01

    A programmatic environmental impact statement (PEIS) was initiated in 1992 for the uranium mill tailings remedial action (UMTRA) program. The PEIS kicked off the groundwater restoration phase of UMTRA, a project involving remediation of 24 sites in ten states and tribal lands contaminated with tailings from uranium mining and milling operations. The U.S. Department of Energy (DOE) agreed, in early 1992, that a PEIS was an appropriate strategy to comply with the National Environmental Policy Act (NEPA) for this second, groundwater phase of the project. This decision recognized that although a parallel effort was being undertaken in preparing a PEIS for DOE's Environmental Restoration/Waste Management (ER/WM) program, characteristics and the maturity of the UMTRA project made it more appropriate to prepare a separate PEIS. The ER/WM PEIS is intended to examine environmental restoration and waste management issues from a very broad perspective. For UMTRA, with surface remediation completed or well under way at 18 of the 24 sites, a more focused programmatic approach for groundwater restoration is more effective than including the UMTRA project within the ER/WM environmental impact statements. A separate document allows a more focused and detailed analysis necessary to efficiently tier site-specific environmental assessments for groundwater restoration at each of the 24 UMTRA former processing sites

  20. ERC hazard classification matrices for above ground structures and groundwater and soil remediation activities

    International Nuclear Information System (INIS)

    Curry, L.R.

    1997-01-01

    This document provides the status of the preliminary hazard classification (PHC) process for the Environmental Restoration Contractor (ERC) above ground structures and groundwater and soil remediation activities currently underway for planned for fiscal year (FY) 1997. This classification process is based on current US Department of Energy (DOE), Richland Operations Office (RL) guidance for the classification of facilities and activities containing radionuclide and nonradiological hazardous material inventories. The above ground structures presented in the matrices were drawn from the Bechtel Hanford, Inc. (BHI) Decontamination and Decommissioning (D and D) Project Facility List (DOE 1996), which identifies the facilities in the RL-Environmental Restoration baseline contract in 1997. This document contains the following two appendices: (1) Appendix A, which consists of a matrix identifying PHC documents that have been issued for BHI's above ground structures and groundwater and soil remediation activities underway or planned for FY 1997, and (2) Appendix B, which consists of a matrix showing anticipated PHCs for above ground structures, and groundwater and soil remediation activities underway or planned for FY 1997. Appendix B also shows the schedule for finalization of PHCs for above ground structures with an anticipated classification of Nuclear

  1. In situ remediation of uranium contaminated groundwater

    International Nuclear Information System (INIS)

    Dwyer, B.P.; Marozas, D.C.

    1997-01-01

    In an effort to develop cost-efficient techniques for remediating uranium contaminated groundwater at DOE Uranium Mill Tailing Remedial Action (UMTRA) sites nationwide, Sandia National Laboratories (SNL) deployed a pilot scale research project at an UMTRA site in Durango, CO. Implementation included design, construction, and subsequent monitoring of an in situ passive reactive barrier to remove Uranium from the tailings pile effluent. A reactive subsurface barrier is produced by emplacing a reactant material (in this experiment various forms of metallic iron) in the flow path of the contaminated groundwater. Conceptually the iron media reduces and/or adsorbs uranium in situ to acceptable regulatory levels. In addition, other metals such as Se, Mo, and As have been removed by the reductive/adsorptive process. The primary objective of the experiment was to eliminate the need for surface treatment of tailing pile effluent. Experimental design, and laboratory and field results are discussed with regard to other potential contaminated groundwater treatment applications

  2. ALTERNATIVE REMEDIATION TECHNOLOGY STUDY FOR GROUNDWATER TREATMENT AT 200-PO-1 OPERABLE UNIT AT HANFORD SITE

    Energy Technology Data Exchange (ETDEWEB)

    DADO MA

    2008-07-31

    This study focuses on the remediation methods and technologies applicable for use at 200-PO-I Groundwater Operable Unit (OU) at the Hanford Site. The 200-PO-I Groundwater au requires groundwater remediation because of the existence of contaminants of potential concern (COPC). A screening was conducted on alternative technologies and methods of remediation to determine which show the most potential for remediation of groundwater contaminants. The possible technologies were screened to determine which would be suggested for further study and which were not applicable for groundwater remediation. COPCs determined by the Hanford Site groundwater monitoring were grouped into categories based on properties linking them by remediation methods applicable to each COPC group. The screening considered the following criteria. (1) Determine if the suggested method or technology can be used for the specific contaminants found in groundwater and if the technology can be applied at the 200-PO-I Groundwater au, based on physical characteristics such as geology and depth to groundwater. (2) Evaluate screened technologies based on testing and development stages, effectiveness, implementability, cost, and time. This report documents the results of an intern research project conducted by Mathew Dado for Central Plateau Remediation in the Soil and Groundwater Remediation Project. The study was conducted under the technical supervision of Gloria Cummins and management supervision of Theresa Bergman and Becky Austin.

  3. Case studies illustrating in-situ remediation methods for soil and groundwater contaminated with petrochemicals

    Energy Technology Data Exchange (ETDEWEB)

    Dixon, Robert A; Lance, P E; Downs, A; Kier, Brian P [EMCON Northwest Inc., Portland, OR (United States)

    1994-12-31

    Four case studies of successful in-situ remediation are summarized illustrating cost-effective methods to remediate soil and groundwater contaminated with volatile and non-volatile petrochemicals. Each site is in a different geologic environment with varying soil types and with and without groundwater impact. The methods described include vadose zone vapor extraction, high-vacuum vapor extraction combined with groundwater tab.le depression, air sparging with groundwater recovery and vapor extraction, and bio remediation of saturated zone soils using inorganic nutrient and oxygen addition

  4. Case studies illustrating in-situ remediation methods for soil and groundwater contaminated with petrochemicals

    Energy Technology Data Exchange (ETDEWEB)

    Dixon, Robert A.; Lance, P.E.; Downs, A.; Kier, Brian P. [EMCON Northwest Inc., Portland, OR (United States)

    1993-12-31

    Four case studies of successful in-situ remediation are summarized illustrating cost-effective methods to remediate soil and groundwater contaminated with volatile and non-volatile petrochemicals. Each site is in a different geologic environment with varying soil types and with and without groundwater impact. The methods described include vadose zone vapor extraction, high-vacuum vapor extraction combined with groundwater tab.le depression, air sparging with groundwater recovery and vapor extraction, and bio remediation of saturated zone soils using inorganic nutrient and oxygen addition

  5. A Sustainability Assessment Methodology for Prioritizing the Technologies of Groundwater Contamination Remediation

    DEFF Research Database (Denmark)

    An, Da; Xi, Beidou; Wang, Yue

    2016-01-01

    More and more groundwater has 23 been polluted recently, and technologies for groundwater contamination remediation are of vital importance; however, it is usually difficult for the users to select the most suitable technology among multiple alternatives. In order to address this, this study aims...... at developing a sustainability assessment framework for prioritizing the technologies for groundwater contamination remediation by combining the concept of sustainability and multi-criteria decision making (MCDM) method. A criterion system which consists of six criteria in three aspects has been proposed...... for sustainability assessment of technologies for groundwater contamination remediation, and a novel MCDM method by combining the logarithmic fuzzy preference programming based fuzzy analytic hierarchy process and the improved ELECTRE method has been developed for prioritizing the alternatives. In order...

  6. Groundwater Remediation in a Floodplain Aquifer at Shiprock, New Mexico

    Energy Technology Data Exchange (ETDEWEB)

    Peterson, Dave [Navarro Research and Engineering; Miller, David [Navarro Research and Engineering; Kautsky, Mark [U. S. Department of Energy, Office of Legacy Management; Dander, David [Navarro Research and Engineering; Nofchissey, Joni [Navajo Nation Division of Natural Resources

    2016-03-06

    A uranium- and vanadium-ore-processing mill operated from 1954 to 1968 within the Navajo Nation near Shiprock, New Mexico. By September 1986, all tailings and structures on the former mill property were encapsulated in a disposal cell built on top of two existing tailings piles on the Shiprock site (the site) [1]. Local groundwater was contaminated by multiple inorganic constituents as a result of the milling operations. The U.S. Department of Energy (DOE) took over management of the site in 1978 as part of the Uranium Mill Tailings Remedial Action (UMTRA) Project. The DOE Office of Legacy Management currently manages ongoing activities at the former mill facility, including groundwater remediation. Remediation activities are designed primarily to reduce the concentrations and total plume mass of the mill-related contaminants sulfate, uranium, and nitrate. In addition to contaminating groundwater in alluvial and bedrock sediments directly below the mill site, ore processing led to contamination of a nearby floodplain bordering the San Juan River. Groundwater in a shallow alluvial aquifer beneath the floodplain is strongly influenced by the morphology of the river channel as well as changing flows in the river, which provides drainage for regional runoff from the San Juan Mountains of Colorado. As part of a recent study of the floodplain hydrology, a revised conceptual model was developed for the alluvial aquifer along with an updated status of contaminant plumes that have been impacted by more than 10 years of groundwater pumping for site remediation purposes. Several findings from the recent study will be discussed here.

  7. Risk assessment guidance document for the UMTRA project groundwater remediation phase

    International Nuclear Information System (INIS)

    1992-05-01

    The purpose of the groundwater remedial activities at the Uranium Mill Tailings Remedial Action (UMTRA) sites is to reduce, control, or eliminate risks to human health and the environment. This is in accordance with Subpart B of 40 CFR 192. According to this regulation, the need for groundwater restoration is based upon US Environmental Protection Agency (EPA)-defined groundwater cleanup standards and must be consistent with the National Environmental Policy Act (NEPA) process. Risk assessments will be used in the UMTRA Groundwater Program to aid in the evaluation of sites. Risk assessments are conducted for four purposes: (1) Preliminary risk assessments are used to aid in prioritizing sites, scope data collection, end determine if a site presents immediate health risks. (2) Baseline risk assessments provide a comprehensive integration and interpretation of demographic, geographic, physical, chemical, and biological factors at a site to determine the extent of actual or potential harm. This information Is used to determine the need for remedial action. (3) Risk evaluation of remedial alternatives is performed to evaluate risks to humans or the environment associated with the various remedial strategies. (4) After remediation, an evaluation of residual risks is conducted. The information gathered for each of these risk evaluations is used to determine the need for subsequent evaluation. Several sites may be eliminated after a preliminary risk assessment if there is no current or future threat to humans or the environment. Likewise, much of the data from a baseline risk assessment can be used to support alternate concentration limits or supplemental standards demonstrations, or identify sensitive habitats or receptors that may be of concern in selecting a remedy

  8. Application of natural resource valuation concepts for development of sustainable remediation plans for groundwater.

    Science.gov (United States)

    Connor, John A; Paquette, Shawn; McHugh, Thomas; Gie, Elaine; Hemingway, Mark; Bianchi, Gino

    2017-12-15

    This paper explores the application of natural resource assessment and valuation procedures as a tool for developing groundwater remediation strategies that achieve the objectives for health and environmental protection, in balance with considerations of economic viability and conservation of natural resources. The natural resource assessment process, as applied under U.S. and international guidelines, entails characterization of groundwater contamination in terms of the pre-existing beneficial services of the impacted resource, the loss of these services caused by the contamination, and the measures and associated costs necessary to restore or replace the lost services. Under many regulatory programs, groundwater remediation objectives assume that the impacted groundwater may be used as a primary source of drinking water in the future, even if not presently in use. In combination with a regulatory preference for removal or treatment technologies, this assumed exposure, while protective of human health, can drive the remedy selection process toward remedies that may not be protective of the groundwater resource itself or of the other natural resources (energy, materials, chemicals, etc.) that may be consumed in the remediation effort. To achieve the same health and environmental protection goals under a sustainable remediation framework, natural resource assessment methods can be applied to restore the lost services and preserve the intact services of the groundwater so as to protect both current and future users of that resource. In this paper, we provide practical guidelines for use of natural resource assessment procedures in the remedy selection process and present a case study demonstrating the use of these protocols for development of sustainable remediation strategies. Copyright © 2017 The Authors. Published by Elsevier Ltd.. All rights reserved.

  9. Linking deposit morphology and clogging in subsurface remediation: Final Technical Report

    Energy Technology Data Exchange (ETDEWEB)

    Mays, David C. [University of Colorado Denver

    2013-12-11

    Groundwater is a crucial resource for water supply, especially in arid and semiarid areas of the United States west of the 100th meridian. Accordingly, remediation of contaminated groundwater is an important application of science and technology, particularly for the U.S. Department of Energy (DOE), which oversees a number of groundwater remediation sites from Cold War era mining. Groundwater remediation is complex, because it depends on identifying, locating, and treating contaminants in the subsurface, where remediation reactions depend on interacting geological, hydrological, geochemical, and microbiological factors. Within this context, permeability is a fundamental concept, because it controls the rates and pathways of groundwater flow. Colloid science is intimately related to permeability, because when colloids are present (particles with equivalent diameters between 1 nanometer and 10 micrometers), changes in hydrological or geochemical conditions can trigger a detrimental reduction in permeability called clogging. Accordingly, clogging is a major concern in groundwater remediation. Several lines of evidence suggest that clogging by colloids depends on (1) colloid deposition, and (2) deposit morphology, that is, the structure of colloid deposits, which can be quantified as a fractal dimension. This report describes research, performed under a 2-year, exploratory grant from the DOE’s Subsurface Biogeochemical Research (SBR) program. This research employed a novel laboratory technique to simultaneously measure flow, colloid deposition, deposit morphology, and permeability in a flow cell, and also collected field samples from wells at the DOE’s Old Rifle remediation site. Field results indicate that suspended solids at the Old Rifle site have fractal structures. Laboratory results indicate that clogging is associated with colloid deposits with smaller fractal dimensions, in accordance with previous studies on initially clean granular media. Preliminary

  10. HANFORD GROUNDWATER REMEDIATION

    Energy Technology Data Exchange (ETDEWEB)

    CHARBONEAU, B; THOMPSON, M; WILDE, R.; FORD, B.; GERBER, M.S.

    2006-02-01

    geographically dispersed community is united in its desire to protect the Columbia River and have a voice in Hanford's future. This paper presents the challenges, and then discusses the progress and efforts underway to reduce the risk posed by contaminated groundwater at Hanford. While Hanford groundwater is not a source of drinking water on or off the Site, there are possible near-shore impacts where it flows into the Columbia River. Therefore, this remediation is critical to the overall efforts to clean up the Site, as well as protect a natural resource.

  11. Colloid remediation in groundwater by polyelectrolyte capture

    International Nuclear Information System (INIS)

    Nuttall, H.E.; Rao, S.; Jain, R.

    1992-01-01

    This paper describes an ongoing study to characterize groundwater colloids, to understand the geochemical factors affecting colloid transport in groundwater, and to develop an in-situ colloid remediation process. The colloids and suspended particulate matter used in this study were collected from a perched aquifer site that has radiation levels several hundred times the natural background and where previous researchers have measured and reported the presence of radiocolloids containing plutonium and americium. At this site, radionuclides have spread over several kilometers. Inorganic colloids collected from water samples are characterized with respect to concentration, mineralogy, size distribution, electrophoretic mobility (zeta potential), and radioactivity levels. Presented are the methods used to investigate the physiochemical factors affecting colloid transport and the preliminary analytical results. Included below are a description of a colloid transport model and the corresponding computational code, water analyses, characterization of the inorganic colloids, and a conceptual description of a process for in-situ colloid remediation using the phenomenon of polyelectrolyte capture

  12. Hydrodynamic analysis application of contaminated groundwater remediation to oil hydrocarbons

    Directory of Open Access Journals (Sweden)

    Pajić Predrag R.

    2017-01-01

    Full Text Available In this paper, the application of the hydrodynamic analysis in the selected ‘pumping and treatment’ remediation method of groundwater hydrocarbon pollution in the case of the Pancevo oil refinery is examined. The applied hydrodynamic analysis represents a regular and necessary approach in modern hydrogeology. Previous chemical analysis of soil and groundwater samples at observation objects revealed their pollution by oil products. New researches included the constraction of 12 piezometric boreholes of varying depths, geoelectric soil sounding, ‘in situ’ measurement of the present contaminant, detected as a hydrophobic phase of LNAPL, chemical analysis of soil and groundwater samples with emphasis on total petroleum hydrocarbons (TPH content, total fats and mineral oils, mercury cations and other characteristic compounds, etc. These researches define the volume of contamination issued by the ‘light’ (LNAPL contamination phase. The selected remediation method for this type of pollution is the ‘Pump and Treat’ method, which implies the pumping of contaminated groundwater from aquifer and their subsequent treatment. A hydrodynamic method was used to select the optimal hydrotechnical solution for LNAPL extraction. On the mathematical model, the prediction calculations for two variant solutions were carried out (‘hydraulic isolation’ and complex for the application of groundwater contamination remediation characterized as front pollution substance (by extraction and injection wells or infiltration pool. By extraction wells performing, it would be possible to remove the LNAPL from the surface of the water with special pumps-skimmers. The importance of the hydrodynamic method application is, in addition to the hydrotechnical solution selection for the LNAPL drainage, the provision of quality basis for the dimensioning of these objects based on the results of the groundwater balance.

  13. Remediation of TCE-contaminated groundwater using nanocatalyst and bacteria.

    Science.gov (United States)

    Kang, Ser Ku; Seo, Hyunhee; Sun, Eunyoung; Kim, Inseon; Roh, Yul

    2011-08-01

    The objective of this study was to develop and evaluate the remediation of trichloroethene (TCE)-contaminated groundwater using both a nanocatalyst (bio-Zn-magnetite) and bacterium (similar to Clostridium quinii) in anoxic environments. Of the 7 nanocatalysts tested, bio-Zn-magnetite showed the highest TCE dechlorination efficiency, with an average of ca. 90% within 8 days in a batch experiment. The column tests confirmed that the application of bio-Zn-magnetite in combination with the bacterium achieved high degradation efficiency (ca. 90%) of TCE within 5 days compared to the nanocatalyst only, which degraded only 30% of the TCE. These results suggest that the application of a nanocatalyst and the bacterium have potential for the remediation of TCE-contaminated groundwater in subsurface environments.

  14. Technical approach to groundwater restoration

    International Nuclear Information System (INIS)

    1993-01-01

    The Technical Approach to Groundwater Restoration (TAGR) provides general technical guidance to implement the groundwater restoration phase of the Uranium Mill Tailings Remedial Action (UMTRA) Project. The TAGR includes a brief overview of the surface remediation and groundwater restoration phases of the UMTRA Project and describes the regulatory requirements, the National Environmental Policy Act (NEPA) process, and regulatory compliance. A section on program strategy discusses program optimization, the role of risk assessment, the observational approach, strategies for meeting groundwater cleanup standards, and remedial action decision-making. A section on data requirements for groundwater restoration evaluates the data quality objectives (DQO) and minimum data required to implement the options and comply with the standards. A section on sits implementation explores the development of a conceptual site model, approaches to site characterization, development of remedial action alternatives, selection of the groundwater restoration method, and remedial design and implementation in the context of site-specific documentation in the site observational work plan (SOWP) and the remedial action plan (RAP). Finally, the TAGR elaborates on groundwater monitoring necessary to evaluate compliance with the groundwater cleanup standards and protection of human health and the environment, and outlines licensing procedures

  15. Decision process for Hanford sitewide groundwater remediation

    International Nuclear Information System (INIS)

    Chiaramonte, G.R.

    1996-06-01

    This document describes a decision process for planning future investigations and remediating contaminated groundwater at the Hanford Site in Richland, Washington. This decision process details the following: identifies key decisions and activities; defines the criteria used in making each decision; and defines the logic that links the decisions and the activities in a stepwise manner

  16. Proceedings (of the) first annual groundwater and soil remediation R, D and D (research, development and demonstration) symposium

    Energy Technology Data Exchange (ETDEWEB)

    1991-01-01

    A symposium was held to present results of research on the remediation of contamination of groundwater and soils. Papers were presented on groundwater/soil remediation research and demonstration programs, in-situ bioremediation, remediation of groundwater contaminated by gasoline-derived aromatics, solvent extraction of petroleum hydrocarbons from soil, bioreactors for cleaning hydrocarbon- and salt-contaminated soils, in-situ volatilization technologies, evaluations of spill cleanup technologies, remediating subsurface contamination around sour gas processing plants, and the influence of gasoline oxygenates on the persistence of aromatics in groundwater. Separate abstracts have been prepared for 9 papers from this symposium.

  17. The impact of abandoned coal gasification plants on groundwater and remediation strategies

    International Nuclear Information System (INIS)

    Werner, P.; Stieber, M.

    1997-01-01

    Areas of abandoned coal gasification-, cokeovenplants and town gasworks normally contain hazardous contaminants as there are among others PAHs, cyanides, mono aromatic compounds and phenols. Therefore a strong impact on the groundwater can be expected. In the thousands of sites existing in Germany a complete remediation is almost impossible. Combustion is the only safe way to eliminate the contaminants by mineralization; but is to expensive and not applicable for the large amount of soil to be treated. Soil washing and bio-remediation is limited by the composition of the contaminants on the one side and by the soil structure on the other. Therefore the success of the mentioned remediation techniques is normally weak and only in some selected cases efficient enough. A combination of different methods according the site characteristics might help to increase the efficiency. On the other hand it it obvious, that there are natural barriers integrated between the contaminants and the groundwater as there are e.g solubility adsorbability and biodegradability of the hazardous compounds and the distance to the groundwater. Recently developed methods for downstream groundwater remediation are presented and discussed for the application in gas work contaminations. Those so called 'passive systems' are said to be very economic and might help to prevent further distribution of the contaminants into the environment. (au)

  18. Groundwater remediation at the Hanford site

    International Nuclear Information System (INIS)

    Fries, W.

    1993-01-01

    Ion exchange resin and adsorption technology has been used successfully to treat diversified types of toxic waste water for many years. Even though the Hanford Site presents many unique problems, the author believes these technologies can remediate the groundwater at this site. However, treatment of the sludge in tanks generally is beyond the pale of these technologies except for the possibility of experimental studies being performed at the University of Idaho (Troescher)

  19. Biosensor-based diagnostics of contaminated groundwater: assessment and remediation strategy

    International Nuclear Information System (INIS)

    Bhattacharyya, Jessica; Read, David; Amos, Sean; Dooley, Stephen; Killham, Kenneth; Paton, Graeme I.

    2005-01-01

    Shallow groundwater beneath a former airfield site in southern England has been heavily contaminated with a wide range of chlorinated solvents. The feasibility of using bacterial biosensors to complement chemical analysis and enable cost-effective, and focussed sampling has been assessed as part of a site evaluation programme. Five different biosensors, three metabolic (Vibrio fischeri, Pseudomonas fluorescens 10568 and Escherichia coli HB101) and two catabolic (Pseudomonas putida TVA8 and E. coli DH5α), were employed to identify areas where the availability and toxicity of pollutants is of most immediate environmental concern. The biosensors used showed different sensitivities to each other and to the groundwater samples tested. There was generally a good agreement with chemical analyses. The potential efficacy of remediation strategies was explored by coupling sample manipulation to biosensor tests. Manipulation involved sparging and charcoal treatment procedures to simulate remediative engineering solutions. Sparging was sufficient at most locations. - Luminescent bacteria complement chemical analysis and support remediation technology

  20. An introduction to geographic information systems as applied to a groundwater remediation program

    International Nuclear Information System (INIS)

    Hammock, J.K.; Lorenz, R.

    1989-01-01

    While the attention to environmental issues has grown over the past several years, so has the focus on groundwater protection. Addressing the task of groundwater remediation often involves a large-scale program with numerous wells and enormous amounts of data. This data must be manipulated and analyzed in an efficient manner for the remediation program to be truly effective. Geographic Information System's (GIS) have proven to be an extremely effective tool in handling and interpreting this type of groundwater information. The purpose of this paper is to introduce the audience to GIS technology, describe how it is being used at the Savannah River Site (SRS) to handle groundwater data and demonstrate how it may be used in the corporate Westinghouse environment

  1. Update on the National Groundwater and Soil Remediation Program (GASReP)

    International Nuclear Information System (INIS)

    Lye, A.

    1992-01-01

    The national Groundwater and Soil Remediation Program (GASReP), supported jointly by government and the petroleum industry, targets research on innovative ways to clean up groundwater and soil contaminated with petroleum hydrocarbons, and conducts technology transfer sessions. Within its broad context as an initiative for research, development and demonstration of innovative cleanup technologies, GASReP now targets basic applied research and/or technology development only. Industry partners and other government programs will be encouraged to extend GASReP research findings to the final stage of technology demonstration. During 1991-92 GASReP shifted its attention from starting new projects to evaluating the program, setting a new direction, and establishing a better way to seek ideas for projects. Unlike previous years, only three projects began during this period. Two technology development projects are iron and manganese pre-treatment for pump and treat clean-up systems, and surface bioreactor to clean soil/waste contaminated with petroleum hydrocarbons. The one technology assessment project dealt with a review of six technologies for in-situ bioremediation of BTEX (benzene, toluene, ethylbenzene, xylene) in groundwater. Current program direction, interests, and research needs are summarized, and candidate proposals for project selection in 1992-93 are listed

  2. Sustainable Remediation for Enhanced NAPL Recovery from Groundwater

    Science.gov (United States)

    Javaher, M.

    2012-12-01

    Sustainable remediation relates to the achievement of balance between environmental, social, and economic elements throughout the remedial lifecycle. A significant contributor to this balance is the use of green and sustainable technologies which minimize environmental impacts, while maximizing social and economic benefits of remedial implementation. To this end, a patented mobile vapor energy generation (VEG) technology has been developed targeting variable applications, including onsite soil remediation for unrestricted reuse and enhanced non-aqueous phase liquid (NAPL) recover at the water table. At the core of the mobile VEG technology is a compact, high efficiency vapor generator, which utilizes recycled water and propane within an entirely enclosed system to generate steam as high as 1100°F. Operating within a fully enclosed system and capturing all heat that is generated within this portable system, the VEG technology eliminates all emissions to the atmosphere and yields an undetected carbon footprint with resulting carbon dioxide concentrations that are below ambient levels. Introduction of the steam to the subsurface via existing wells results in a desired change in the NAPL viscosity and the interfacial tension at the soil, water, NAPL interface; in turn, this results in mobilization and capture of the otherwise trapped, weathered NAPL. Approved by the California Air Resources Control Board (and underlying Air Quality Management Districts) and applied in California's San Joaquin Valley, in-well heating of NAPLs trapped at the water table using the VEG technology has proven as effective as electrical resistivity heating (ERH) in changing the viscosity of and mobilizing NAPLs in groundwater in support of recovery, but has achieved these results while minimizing the remedial carbon footprint by 90%, reducing energy use by 99%, and reducing remedial costs by more than 95%. NAPL recovery using VEG has also allowed for completion of source removal historically

  3. Application of Fe-Cu/Biochar System for Chlorobenzene Remediation of Groundwater in Inhomogeneous Aquifers

    OpenAIRE

    Xu Zhang; Yanqing Wu; Pingping Zhao; Xin Shu; Qiong Zhou; Zichen Dong

    2017-01-01

    Chlorobenzene (CB), as a typical Volatile Organic Contaminants (VOC), is toxic, highly persistent and easily migrates in water, posing a significant risk to human health and subsurface ecosystems. Therefore, exploring effective approaches to remediate groundwater contaminated by CB is essential. As an enhanced micro-electrolysis system for CB-contaminated groundwater remediation, this study attempted to couple the iron-copper bimetal with biochar. Two series of columns using sands with differ...

  4. Hydrodynamic analysis application of contaminated groundwater remediation to oil hydrocarbons

    OpenAIRE

    Pajić Predrag R.; Čalenić Aleksandar I.; Polomčić Dušan M.; Bajić Dragoljub I.

    2017-01-01

    In this paper, the application of the hydrodynamic analysis in the selected ‘pumping and treatment’ remediation method of groundwater hydrocarbon pollution in the case of the Pancevo oil refinery is examined. The applied hydrodynamic analysis represents a regular and necessary approach in modern hydrogeology. Previous chemical analysis of soil and groundwater samples at observation objects revealed their pollution by oil products. New researches included the constraction of 12 piezometric bor...

  5. Remediating Contaminant Plumes in Groundwater with Shallow Excavations Containing Coarse Reactive Media.

    Science.gov (United States)

    Hudak, Paul F

    2018-02-01

    A groundwater flow and mass transport model tested the capability of shallow excavations filled with coarse, reactive media to remediate a hypothetical unconfined aquifer with a maximum saturated thickness of 5 m. Modeled as contaminant sinks, the rectangular excavations were 10 m downgradient of an initial contaminant plume originating from a source at the top of the aquifer. The initial plume was approximately 259 m long, 23 m wide, and 5 m thick, with a downgradient tip located approximately 100 m upgradient of the site boundary. The smallest trench capable of preventing offsite migration was 11 m long (measured perpendicular to groundwater flow), 4 m wide (measured parallel to groundwater flow), and 3 m deep. Results of this study suggest that shallow trenches filled with coarse filter media that partially penetrate unconfined aquifers may be a viable alternative for remediating contaminated groundwater at some sites.

  6. Laboratory study on sequenced permeable reactive barrier remediation for landfill leachate-contaminated groundwater

    International Nuclear Information System (INIS)

    Dong Jun; Zhao Yongsheng; Zhang Weihong; Hong Mei

    2009-01-01

    Permeable reactive barrier (PRB) was a promising technology for groundwater remediation. Landfill leachate-polluted groundwater riches in various hazardous contaminants. Two lab-scale reactors (reactors A and B) were designed for studying the feasibility of PRB to remedy the landfill leachate-polluted groundwater. Zero valent iron (ZVI) and the mixture of ZVI and zeolites constitute the first section of the reactors A and B, respectively; the second section of two reactors consists of oxygen releasing compounds (ORCs). Experimental results indicated that BOD 5 /COD increased from initial 0.32 up to average 0.61 and 0.6 through reactors A and B, respectively. Removal efficiency of mixed media for pollutants was higher than that of single media (ZVI only). Zeolites exhibited selective removal of Zn, Mn, Mg, Cd, Sr, and NH 4 + , and removal efficiency was 97.2%, 99.6%, 95.9%, 90.5% and 97.4%, respectively. The maximum DO concentration of reactors A and B were 7.64 and 6.78 mg/L, respectively, while the water flowed through the ORC. Therefore, sequenced PRB system was effective and was proposed as an alternative method to remedy polluted groundwater by landfill leachate

  7. Effect of heterogeneity on enhanced reductive dechlorination: Analysis of remediation efficiency and groundwater acidification

    Science.gov (United States)

    Brovelli, A.; Lacroix, E.; Robinson, C. E.; Gerhard, J.; Holliger, C.; Barry, D. A.

    2011-12-01

    Enhanced reductive dehalogenation is an attractive in situ treatment technology for chlorinated contaminants. The process includes two acid-forming microbial reactions: fermentation of an organic substrate resulting in short-chain fatty acids, and dehalogenation resulting in hydrochloric acid. The accumulation of acids and the resulting drop of groundwater pH are controlled by the mass and distribution of chlorinated solvents in the source zone, type of electron donor, alternative terminal electron acceptors available and presence of soil mineral phases able to buffer the pH (such as carbonates). Groundwater acidification may reduce or halt microbial activity, and thus dehalogenation, significantly increasing the time and costs required to remediate the aquifer. In previous work a detailed geochemical and groundwater flow simulator able to model the fermentation-dechlorination reactions and associated pH change was developed. The model accounts for the main processes influencing microbial activity and groundwater pH, including the groundwater composition, the electron donor used and soil mineral phase interactions. In this study, the model was applied to investigate how spatial variability occurring at the field scale affects dechlorination rates, groundwater pH and ultimately the remediation efficiency. Numerical simulations were conducted to examine the influence of heterogeneous hydraulic conductivity on the distribution of the injected, fermentable substrate and on the accumulation/dilution of the acidic products of reductive dehalogenation. The influence of the geometry of the DNAPL source zone was studied, as well as the spatial distribution of soil minerals. The results of this study showed that the heterogeneous distribution of the soil properties have a potentially large effect on the remediation efficiency. For examples, zones of high hydraulic conductivity can prevent the accumulation of acids and alleviate the problem of groundwater acidification. The

  8. In Situ Monitoring of Groundwater Contamination Using the Kalman Filter For Sustainable Remediation

    Science.gov (United States)

    Schmidt, F.; Wainwright, H. M.; Faybishenko, B.; Denham, M. E.; Eddy-Dilek, C. A.

    2017-12-01

    Sustainable remediation - based on less intensive passive remediation and natural attenuation - has become a desirable remediation alternative at contaminated sites. Although it has a number of benefits, such as reduced waste and water/energy usage, it carries a significant burden of proof to verify plume stability and to ensure insignificant increase of risk to public health. Modeling of contaminant transport is still challenging despite recent advances in numerical methods. Long-term monitoring has, therefore, become a critical component in sustainable remediation. However, the current approach, which relies on sparse groundwater sampling, is problematic, since it could miss sudden significant changes in plume behavior. A new method is needed to combine existing knowledge about contaminant behavior and latest advances in in situ groundwater sensors. This study presents an example of the effective use of the Kalman filter approach to estimate contaminant concentrations, based on in situ measured water quality parameters (e.g. electrical conductivity and pH) along with the results of sparse groundwater sampling. The Kalman filter can effectively couple physical models and data correlations between the contaminant concentrations and in situ measured variables. We aim (1) to develop a framework capable of integrating different data types to provide accurate contaminant concentration estimates, (2) to demonstrate that these results remain reliable, even when the groundwater sampling frequency is reduced, and (3) to evaluate the future efficacy of this strategy using reactive transport simulations. This framework can also serve as an early warning system for detecting unexpected plume migration. We demonstrate our approach using historical and current groundwater data from the Savannah River Site (SRS) F-Area Seepage Basins to estimate uranium and tritium concentrations. The results show that the developed method can provide reliable estimates of contaminant

  9. Soil and ground-water remediation techniques

    International Nuclear Information System (INIS)

    Beck, P.

    1996-01-01

    Urban areas typically contain numerous sites underlain by soils or ground waters which are contaminated to levels that exceed clean-up guidelines and are hazardous to public health. Contamination most commonly results from the disposal, careless use and spillage of chemicals, or the historic importation of contaminated fill onto properties undergoing redevelopment. Contaminants of concern in soil and ground water include: inorganic chemicals such as heavy metals; radioactive metals; salt and inorganic pesticides, and a range of organic chemicals included within petroleum fuels, coal tar products, PCB oils, chlorinated solvents, and pesticides. Dealing with contaminated sites is a major problem affecting all urban areas and a wide range of different remedial technologies are available. This chapter reviews the more commonly used methods for ground-water and soil remediation, paying particular regard to efficiency and applicability of specific treatments to different site conditions. (author). 43 refs., 1 tab., 27 figs

  10. ANNUAL REPORT FOR THE FINAL GROUNDWATER REMEDIATION, TEST AREA NORTH, OPERABLE UNIT 1-07B, FISCAL YEAR 2009

    Energy Technology Data Exchange (ETDEWEB)

    FORSYTHE, HOWARD S

    2010-04-14

    This Annual Report presents the data and evaluates the progress of the three-component remedy implemented for remediation of groundwater contamination at Test Area North, Operable Unit 1-07B, at the Idaho National Laboratory Site. Overall, each component is achieving progress toward the goal of total plume remediation. In situ bioremediation operations in the hot spot continue to operate as planned. Progress toward the remedy objectives is being made, as evidenced by continued reduction in the amount of accessible residual source and decreases in downgradient contaminant flux, with the exception of TAN-28. The injection strategy is maintaining effective anaerobic reductive dechlorination conditions, as evidenced by complete degradation of trichloroethene and ethene production in the biologically active wells. In the medial zone, the New Pump and Treat Facility operated in standby mode. Trichloroethene concentrations in the medial zone wells are significantly lower than the historically defined concentration range of 1,000 to 20,000 μg/L. The trichloroethene concentrations in TAN-33, TAN-36, and TAN-44 continue to be below 200 μg/L. Monitoring in the distal zone wells outside and downgradient of the plume boundary demonstrate that some plume expansion has occurred, but less than the amount allowed in the Record of Decision Amendment. Additional data need to be collected for wells in the monitored natural attenuation part of the plume to confirm that the monitored natural attenuation part of the remedy is proceeding as predicted in the modeling.

  11. Groundwater flow in the Venice lagoon and remediation of the Porto Marghera industrial area (Italy)

    Science.gov (United States)

    Beretta, Giovanni Pietro; Terrenghi, Jacopo

    2017-05-01

    This study aims to determine the groundwater flow in a large area of the Venice (northeast Italy) lagoon that is under great anthropogenic pressure, which is influencing the regional flow in the surficial aquifer (about 30 m depth). The area presents several elements that condition the groundwater flow: extraction by means of drainage pumps and wells; tidal fluctuation; impermeable barriers that define part of the coastline, rivers and artificial channels; precipitation; recharge, etc. All the elements were studied separately, and then they were brought together in a numerical groundwater flow model to estimate the impact of each one. Identification of the impact of each element will help to optimise the characteristics of the Porto Marghera remediation systems. Longstanding industrial activity has had a strong impact on the soil and groundwater quality, and expensive and complex emergency remediation measures in problematic locations have been undertaken to ensure the continuity of industrial and maritime activities. The land reclamation and remediation works withdraw 56-74% of the water budget, while recharge from the river accounts for about 21-48% of the input. Only 21-42% of groundwater in the modelled area is derived from natural recharge sources, untouched by human activity. The drop of the piezometric level due to the realization of the upgradient impermeable barrier can be counteracted with the reduction of the pumping rate of the remediation systems.

  12. Arsenic in the groundwater: Occurrence, toxicological activities, and remedies.

    Science.gov (United States)

    Jha, S K; Mishra, V K; Damodaran, T; Sharma, D K; Kumar, Parveen

    2017-04-03

    Arsenic (As) contamination in groundwater has become a geo-environmental as well as a toxicological problem across the globe affecting more than 100-million people in nearly 21 countries with its associated disease "arsenicosis." Arsenic poisoning may lead to fatal skin and internal cancers. In present review, an attempt has been made to generate awareness among the readers about various sources of occurrence of arsenic, its geochemistry and speciation, mobilization, metabolism, genotoxicity, and toxicological exposure on humans. The article also emphasizes the possible remedies for combating the problem. The knowledge of these facts may help to work on some workable remedial measure.

  13. A co-metabolic approach to groundwater remediation

    International Nuclear Information System (INIS)

    Palumbo, A.V.; Boerman, P.A.; Herbes, S.E.; White, D.C.; Strandberg, G.W.; Donaldson, T.L.; Lucero, A.J.; Jennings, H.L.; Phelps, T.J.; White, D.C.

    1991-01-01

    In support of the US Department of Energy's (DOE) Integrated Demonstration (Cleanup of Organics in Soils and Groundwater at Non-arid Sites) at the Savannah River Site (SRS), Oak Ridge National Laboratory (ORNL) and the University of Tennessee (UT) are involved in demonstrations of the use of methanotrophs in bioreactors for remediation of contaminated groundwater. In preparation for a field demonstration at ORNL's K-25 Site in Oak Ridge, Tennessee, ORNL is conducting batch experiments, is operating a number of bench-scale bioreactors, has designed pretreatment systems, and has modified a field-scale bioreactor provided by the Air Force Engineering and Services Center for use at the site. UT is operating benchscale bioreactors with the goal of determining the stability of a trichloroethylene-degrading methanotrophic consortia during shifts in operating conditions (e.g. pH, nutrient inputs, and contaminant mixtures). These activities are all aimed at providing the knowledge base necessary for successful treatment of contaminated groundwater at the SRS and K-25 sites as well as other DOE sites

  14. A co-metabolic approach to groundwater remediation

    International Nuclear Information System (INIS)

    Palumbo, A.V.; Boerman, P.A.; Strandberg, G.W.; Donaldson, T.L.; Jennings, H.L.; Lucero, A.J.; Herbes, S.E.; Phelps, T.J.; White, D.C.

    1991-01-01

    In support of the US Department of Energy's (DOE) Integrated Demonstration (Cleanup of Organics in Soils and Groundwater at Non-arid Sites) at the Savannah River Site (SRS), Oak Ridge National Laboratory (ORNL) and the University of Tennessee (UT) are involved in demonstrations of the use of methanotrophs in bioreactors for remediation of contaminated groundwater. In preparation for a field demonstration at ORNL's K-25 Site in Oak Ridge, Tennessee, ORNL is conducting batch experiments, is operating a number of bench-scale bioreactors, has designed pretreatment systems, and has modified a field-scale bioreactor provided by the Air Force Engineering and Services Center for use at the site. UT is operating bench-scale bioreactors with the goal of determining the stability of a trichloroethylene-degrading methanotrophic consortia during shifts in operating conditions (e.g. pH, nutrient inputs, and contaminant mixtures). These activities are all aimed at providing the knowledge base necessary for successful treatment of contaminated groundwater at the SRS and K-25 sites as well as other DOE sites. 18 refs., 1 fig. , 1 tab

  15. Carbon Nanotube Based Groundwater Remediation: The Case of Trichloroethylene

    Directory of Open Access Journals (Sweden)

    Kshitij C. Jha

    2016-07-01

    Full Text Available Adsorption of chlorinated organic contaminants (COCs on carbon nanotubes (CNTs has been gaining ground as a remedial platform for groundwater treatment. Applications depend on our mechanistic understanding of COC adsorption on CNTs. This paper lays out the nature of competing interactions at play in hybrid, membrane, and pure CNT based systems and presents results with the perspective of existing gaps in design strategies. First, current remediation approaches to trichloroethylene (TCE, the most ubiquitous of the COCs, is presented along with examination of forces contributing to adsorption of analogous contaminants at the molecular level. Second, we present results on TCE adsorption and remediation on pure and hybrid CNT systems with a stress on the specific nature of substrate and molecular architecture that would contribute to competitive adsorption. The delineation of intermolecular interactions that contribute to efficient remediation is needed for custom, scalable field design of purification systems for a wide range of contaminants.

  16. Carbon Nanotube Based Groundwater Remediation: The Case of Trichloroethylene.

    Science.gov (United States)

    Jha, Kshitij C; Liu, Zhuonan; Vijwani, Hema; Nadagouda, Mallikarjuna; Mukhopadhyay, Sharmila M; Tsige, Mesfin

    2016-07-21

    Adsorption of chlorinated organic contaminants (COCs) on carbon nanotubes (CNTs) has been gaining ground as a remedial platform for groundwater treatment. Applications depend on our mechanistic understanding of COC adsorption on CNTs. This paper lays out the nature of competing interactions at play in hybrid, membrane, and pure CNT based systems and presents results with the perspective of existing gaps in design strategies. First, current remediation approaches to trichloroethylene (TCE), the most ubiquitous of the COCs, is presented along with examination of forces contributing to adsorption of analogous contaminants at the molecular level. Second, we present results on TCE adsorption and remediation on pure and hybrid CNT systems with a stress on the specific nature of substrate and molecular architecture that would contribute to competitive adsorption. The delineation of intermolecular interactions that contribute to efficient remediation is needed for custom, scalable field design of purification systems for a wide range of contaminants.

  17. In-situ remediation of brine impacted soils and groundwater using hydraulic fracturing, desalinization and recharge wells

    Energy Technology Data Exchange (ETDEWEB)

    Robertson, C. [Wiebe Environmental Services Inc., Calgary, AB (Canada); Ratiu, I. [GeoGrid Environmental Inc., Calgary, AB (Canada)

    2006-07-01

    This conference presentation focused on the in-stu remediation of brine impacted soils and groundwater using hydraulic fracturing, desalinization and recharge wells. A former oil battery was established in the 1940s, decommissioned in the late 1960s with a reclamation certificate issued in 1972. The land owner reported poor vegetative growth in the former battery area. The purpose of the study was to investigate the cause of poor growth and delineate contaminants of concern and to remediate impacted soil and groundwater associated with the former battery site. The investigation involved agrological, geophysical and hydrogeological investigation into the extent of anthropogenic impacts as well as the development of remediation options and plans to deal with issues of concern. The presentation provided the results of the investigation, options identified, and discussed limitation on salt remediation and treatment of saline soils. Other topics included hydraulic fracturing, injection wells that were installed to re-circulate treated groundwater though the salt plume, desalinization processes, and next steps. figs.

  18. Feasibility study for the remediation of groundwater contaminated by organolead compounds

    International Nuclear Information System (INIS)

    Andreottola, Gianni; Dallago, Loris; Ferrarese, Elisa

    2008-01-01

    The aim of this research was to assess the effectiveness of chemical oxidation, Advanced Oxidation Processes (AOPs) and adsorption on granular activated carbon (GAC) for the ex situ remediation of a groundwater contaminated by organolead compounds, including tetraethyl lead (TEL), triethyl lead (TREL) and diethyl lead (DEL). The groundwater of concern was collected from the site of a former tetraalkyllead producing company in Trento (Italy), and showed an average total organic lead (TOL) content about 95.1 μg/L (TEL 0.5 μg/L, TREL 86.4 μg/L, DEL 8.3 μg/L). The main target of the study was to find out which method was more effective in reducing the pollutant content. For this purpose, several laboratory tests were performed, including chemical oxidation tests with different reactants (hydrogen peroxide, modified Fenton's reagent, potassium permanganate, activated potassium persulfate, oxygen and combinations of potassium permanganate and modified Fenton's reagent), AOPs with ozone, UV radiation and hydrogen peroxide and filtration on granular activated carbon. A combination of chemical and physical treatments was also tested, with GAC filtration followed by chemical oxidation. According to the results achieved, the treatments which showed the best remediation performances were: chemical oxidation with modified Fenton's reagent, AOPs with hydrogen peroxide and ozone (perozone), AOPs with hydrogen peroxide and UV radiation, and the combined treatment with activated carbon filtration followed by chemical oxidation with perozone. All these treatments showed a 90% TOL removal, with excellent removals of both TEL and TREL, and final DEL concentrations below 5 μg/L

  19. Feasibility study for the remediation of groundwater contaminated by organolead compounds

    Energy Technology Data Exchange (ETDEWEB)

    Andreottola, Gianni; Dallago, Loris [Universita degli Studi di Trento, Dipartimento di Ingegneria Civile e Ambientale, Via Mesiano 77, 38050 Trento (Italy); Ferrarese, Elisa [Universita degli Studi di Trento, Dipartimento di Ingegneria Civile e Ambientale, Via Mesiano 77, 38050 Trento (Italy)], E-mail: elisa.ferrarese@ing.unitn.it

    2008-08-15

    The aim of this research was to assess the effectiveness of chemical oxidation, Advanced Oxidation Processes (AOPs) and adsorption on granular activated carbon (GAC) for the ex situ remediation of a groundwater contaminated by organolead compounds, including tetraethyl lead (TEL), triethyl lead (TREL) and diethyl lead (DEL). The groundwater of concern was collected from the site of a former tetraalkyllead producing company in Trento (Italy), and showed an average total organic lead (TOL) content about 95.1 {mu}g/L (TEL 0.5 {mu}g/L, TREL 86.4 {mu}g/L, DEL 8.3 {mu}g/L). The main target of the study was to find out which method was more effective in reducing the pollutant content. For this purpose, several laboratory tests were performed, including chemical oxidation tests with different reactants (hydrogen peroxide, modified Fenton's reagent, potassium permanganate, activated potassium persulfate, oxygen and combinations of potassium permanganate and modified Fenton's reagent), AOPs with ozone, UV radiation and hydrogen peroxide and filtration on granular activated carbon. A combination of chemical and physical treatments was also tested, with GAC filtration followed by chemical oxidation. According to the results achieved, the treatments which showed the best remediation performances were: chemical oxidation with modified Fenton's reagent, AOPs with hydrogen peroxide and ozone (perozone), AOPs with hydrogen peroxide and UV radiation, and the combined treatment with activated carbon filtration followed by chemical oxidation with perozone. All these treatments showed a 90% TOL removal, with excellent removals of both TEL and TREL, and final DEL concentrations below 5 {mu}g/L.

  20. Fluoride in groundwater: toxicological exposure and remedies.

    Science.gov (United States)

    Jha, S K; Singh, R K; Damodaran, T; Mishra, V K; Sharma, D K; Rai, Deepak

    2013-01-01

    Fluoride is a chemical element that is found most frequently in groundwater and has become one of the most important toxicological environmental hazards globally. The occurrence of fluoride in groundwater is due to weathering and leaching of fluoride-bearing minerals from rocks and sediments. Fluoride when ingested in small quantities (dental health by reducing dental caries, whereas higher concentrations (>1.5 mg/L) may cause fluorosis. It is estimated that about 200 million people, from among 25 nations the world over, may suffer from fluorosis and the causes have been ascribed to fluoride contamination in groundwater including India. High fluoride occurrence in groundwaters is expected from sodium bicarbonate-type water, which is calcium deficient. The alkalinity of water also helps in mobilizing fluoride from fluorite (CaF2). Fluoride exposure in humans is related to (1) fluoride concentration in drinking water, (2) duration of consumption, and (3) climate of the area. In hotter climates where water consumption is greater, exposure doses of fluoride need to be modified based on mean fluoride intake. Various cost-effective and simple procedures for water defluoridation techniques are already known, but the benefits of such techniques have not reached the rural affected population due to limitations. Therefore, there is a need to develop workable strategies to provide fluoride-safe drinking water to rural communities. The study investigated the geochemistry and occurrence of fluoride and its contamination in groundwater, human exposure, various adverse health effects, and possible remedial measures from fluoride toxicity effects.

  1. Independent Technical Review of the X-740 Groundwater Remedy, Portsmouth, Ohio: Technical Evaluation and Recommendations

    International Nuclear Information System (INIS)

    Looney, B.; Rhia, B.; Jackson, D.; Eddy-Dilek, C.

    2010-01-01

    Two major remedial campaigns have been applied to a plume of trichloroethene (TCE) contaminated groundwater near the former X-740 facility at the Portsmouth Gaseous Diffusion Plant in Piketon Ohio. The two selected technologies, phytoremediation using a stand of hybrid poplar trees from 1999-2007 and in situ chemical oxidation using modified Fenton's Reagent from 2008-2009, have proven ineffective in achieving remedial action objectives (RAOs). The 'poor' performance of these technologies is a direct result of site specific conditions and the local contaminant hydrogeology. Key among these challenges is the highly heterogeneous subsurface geology with a thin contaminated aquifer zone (the Gallia) - the behavior of the contamination in the Gallia is currently dominated by slow release of TCE from the clay of the overlying Minford formation, from the sandstone of the underlying Berea formation, and from clayey layers within the Gallia itself. In response to the remediation challenges for the X-740 plume, the Portsmouth team (including the US Department of Energy (DOE), the site contractor (CDM), and the Ohio Environmental Protection Agency (OEPA)) is evaluating the feasibility of remediation at this site and identifying specific alternatives that are well matched to site conditions and that would maximize the potential for achieving RAOs. To support this evaluation, the DOE Office of Groundwater and Soil Remediation (EM-32) assembled a team of experts to serve as a resource and provide input and recommendations to Portsmouth. Despite the challenging site conditions and the failure of the previous two remediation campaigns to adequately move the site toward RAOs, the review team was unanimous in the conclusion that an effective combination of cost effective technologies can be identified. Further, the team expressed optimism that RAOs can be achieved if realistic timeframes are accepted by all parties. The initial efforts of the review team focused on reviewing the

  2. An Elitist Multiobjective Tabu Search for Optimal Design of Groundwater Remediation Systems.

    Science.gov (United States)

    Yang, Yun; Wu, Jianfeng; Wang, Jinguo; Zhou, Zhifang

    2017-11-01

    This study presents a new multiobjective evolutionary algorithm (MOEA), the elitist multiobjective tabu search (EMOTS), and incorporates it with MODFLOW/MT3DMS to develop a groundwater simulation-optimization (SO) framework based on modular design for optimal design of groundwater remediation systems using pump-and-treat (PAT) technique. The most notable improvement of EMOTS over the original multiple objective tabu search (MOTS) lies in the elitist strategy, selection strategy, and neighborhood move rule. The elitist strategy is to maintain all nondominated solutions within later search process for better converging to the true Pareto front. The elitism-based selection operator is modified to choose two most remote solutions from current candidate list as seed solutions to increase the diversity of searching space. Moreover, neighborhood solutions are uniformly generated using the Latin hypercube sampling (LHS) in the bounded neighborhood space around each seed solution. To demonstrate the performance of the EMOTS, we consider a synthetic groundwater remediation example. Problem formulations consist of two objective functions with continuous decision variables of pumping rates while meeting water quality requirements. Especially, sensitivity analysis is evaluated through the synthetic case for determination of optimal combination of the heuristic parameters. Furthermore, the EMOTS is successfully applied to evaluate remediation options at the field site of the Massachusetts Military Reservation (MMR) in Cape Cod, Massachusetts. With both the hypothetical and the large-scale field remediation sites, the EMOTS-based SO framework is demonstrated to outperform the original MOTS in achieving the performance metrics of optimality and diversity of nondominated frontiers with desirable stability and robustness. © 2017, National Ground Water Association.

  3. Evaluation of contaminated groundwater cleanup objectives

    International Nuclear Information System (INIS)

    Arquiett, C.; Gerke, M.; Datskou, I.

    1996-01-01

    The US Department of Energy's (DOE's) Environmental Restoration Program will be responsible for remediating the approximately 230 contaminated groundwater sites across the DOE Complex. A major concern for remediation is choosing the appropriate cleanup objective. The cleanup objective chosen will influence the risk to the nearby public during and after remediation; risk to remedial and non-involved workers during remediation; and the cost of remediation. This paper discusses the trends shown in analyses currently being performed at Oak Ridge National Laboratories' (ORNL's) Center for Risk Management (CRM). To evaluate these trends, CRM is developing a database of contaminated sites. This paper examines several contaminated groundwater sites selected for assessment from CRM's data base. The sites in this sample represent potential types of contaminated groundwater sites commonly found at an installation within DOE. The baseline risk from these sites to various receptors is presented. Residual risk and risk during remediation is reported for different cleanup objectives. The cost associated with remediating to each of these objectives is also estimated for each of the representative sites. Finally, the general trends of impacts as a function of cleanup objective will be summarized. The sites examined include the Savannah River site, where there was substantial ground pollution from radionuclides, oil, coal stockpiles, and other forms of groundwater contamination. The effects of various types of groundwater contamination on various types of future user is described. 4 refs., 3 figs., 2 tabs

  4. Soil and groundwater remediation through the program of energy research and development at Environment Canada

    International Nuclear Information System (INIS)

    Bacchus, P.

    2005-01-01

    Research and development in groundwater and soil remediation within the federal Program of Energy Research and Development (PERD) are conducted in the context of activities related to the oil and gas industry. Contamination of groundwater and soil by the oil and gas sector affects the health of ecosystems and the economic viability of impacted lands. This paper presented an outline of remediation research and development activities associated with PERD, as well as an overview of PERD's development of improved generic remediation technologies and approaches for use by industries. In addition, issues concerning the development of key guidelines, methods and protocols for use by regulators were discussed. Science and technology efforts within PERD contribute to the development of national standards and guidelines concerning public safety and environmental needs

  5. Optimal groundwater remediation using artificial neural networks and the genetic algorithm

    Energy Technology Data Exchange (ETDEWEB)

    Rogers, Leah L. [Stanford Univ., CA (United States)

    1992-08-01

    An innovative computational approach for the optimization of groundwater remediation is presented which uses artificial neural networks (ANNs) and the genetic algorithm (GA). In this approach, the ANN is trained to predict an aspect of the outcome of a flow and transport simulation. Then the GA searches through realizations or patterns of pumping and uses the trained network to predict the outcome of the realizations. This approach has advantages of parallel processing of the groundwater simulations and the ability to ``recycle`` or reuse the base of knowledge formed by these simulations. These advantages offer reduction of computational burden of the groundwater simulations relative to a more conventional approach which uses nonlinear programming (NLP) with a quasi-newtonian search. Also the modular nature of this approach facilitates substitution of different groundwater simulation models.

  6. Optimal groundwater remediation using artificial neural networks and the genetic algorithm

    International Nuclear Information System (INIS)

    Rogers, L.L.

    1992-08-01

    An innovative computational approach for the optimization of groundwater remediation is presented which uses artificial neural networks (ANNs) and the genetic algorithm (GA). In this approach, the ANN is trained to predict an aspect of the outcome of a flow and transport simulation. Then the GA searches through realizations or patterns of pumping and uses the trained network to predict the outcome of the realizations. This approach has advantages of parallel processing of the groundwater simulations and the ability to ''recycle'' or reuse the base of knowledge formed by these simulations. These advantages offer reduction of computational burden of the groundwater simulations relative to a more conventional approach which uses nonlinear programming (NLP) with a quasi-newtonian search. Also the modular nature of this approach facilitates substitution of different groundwater simulation models

  7. Groundwater re-injection at Fernald: Its role in accelerating the aquifer remedy

    International Nuclear Information System (INIS)

    Broberg, Kenneth A.; Janke, Robert

    2000-01-01

    A successful field-scale demonstration of the use of groundwater re-injection at the Fernald Environmental Management Project (FEMP) was recently completed, bringing the U.S. Department of Energy one step closer to achieving an accelerated site remediation. The demonstration marks the end of a several-year effort to evaluate (a) whether re-injection could be conducted efficiently at Fernald and (b) whether the approved aquifer remedy at Fernald would benefit from incorporating re-injection

  8. Petroleum hydrocarbon contaminated sites: a review of investigation and remediation regulations and processes

    Energy Technology Data Exchange (ETDEWEB)

    Epelbaum, Michel; Claudio, Jair R [Bureau Veritas do Brasil Sociedade Classificadora e Certificadora Ltda., Sao Paulo, SP (Brazil)

    1994-12-31

    This paper discusses alternatives on remediation of petroleum hydrocarbon contaminated sites which include groundwater remediation techniques and soil remediation techniques. Finally, the work points out some trends of sites remediation in Brazil and abroad. 6 refs., 1 fig., 7 tabs.

  9. Petroleum hydrocarbon contaminated sites: a review of investigation and remediation regulations and processes

    Energy Technology Data Exchange (ETDEWEB)

    Epelbaum, Michel; Claudio, Jair R. [Bureau Veritas do Brasil Sociedade Classificadora e Certificadora Ltda., Sao Paulo, SP (Brazil)

    1993-12-31

    This paper discusses alternatives on remediation of petroleum hydrocarbon contaminated sites which include groundwater remediation techniques and soil remediation techniques. Finally, the work points out some trends of sites remediation in Brazil and abroad. 6 refs., 1 fig., 7 tabs.

  10. Information needs for demonstrating compliance with groundwater aspects of 40 CFR 192 for uranium mill tailings remedial action programs

    International Nuclear Information System (INIS)

    Logsdon, M.J.; Verma, T.R.; Martin, D.E.

    1984-01-01

    Public Law 95-604, the Uranium Mill Tailings Radiation Control Act of 1978, provides the Department of Energy with authority to perform remedial actions at designated inactive uranium-mill sites. The Environmental Protection Agency promulgated radiological and non-radiological standards (40 CFR 192) for remedial actions at inactive uranium-mill sites. All remedial actions require the concurrence of the Nuclear Regulatory Commission. Subpart C of 40 CFR 192 addresses the control of pollutants in groundwater at sites for which remedial action is proposed pursuant to P.L 95-604. As the authors interpret the regulation, it is essentially an admonition to carefully evaluate what is useful and practicable to deal with existing contamination and to control potential future contamination. In reviewing groundwater aspects of Uranium Mill Tailings Remedial Action documents, current NRC experience shows that the reports should address the following information needs: (1) The need to identify the physical and chemical nature of the present groundwater flow system in sufficient detail to provide a reasonable expectation that the extent and value of the groundwater resource to be protected is understood adequately; (2) The need to identify reasonable foreseeable events, both natural and man-made, that could alter the present groundwater flow system and the effects of such changes on the definition of the protected zone; (3) The need to identify current groundwater use within the protected zone; (4) The need to identify site-specific models, boundary conditions, and representative values of system parameters to predict with reasonable assurance that the proposed actions will protect groundwater and surface water resources for the design period of 200 - 1000 years

  11. Soil and groundwater remediation guidelines for methanol

    International Nuclear Information System (INIS)

    2010-12-01

    Methanol is used by oil and gas operators to inhibit hydrate formation in the recovery of heavy oils, in natural gas production and transport, as well as in various other production applications. Emissions from methanol primary occur from miscellaneous solvent usage, methanol production, end-product manufacturing, and storage and handling losses. This document provided soil and groundwater remediation guidelines for methanol releases into the environment. The guidelines were consistent with the Alberta Environment tier 1 soil and groundwater framework. The chemical and physical properties of methanol were reviewed. The environmental fate and behavior of methanol releases was discussed, and the behaviour and effects of methanol in terrestrial and aquatic biota were evaluated. The toxicity of methanol and its effects in humans and mammalian species were reviewed. Soil quality and ground water quality guidelines were presented. Surface water and soil guideline calculation methods were provided, and ecological exposure and ground water pathways were discussed. Management limits for methanol concentrations were also provided. 162 refs., 18 tabs., 4 figs.

  12. Optimized remedial groundwater extraction using linear programming

    International Nuclear Information System (INIS)

    Quinn, J.J.

    1995-01-01

    Groundwater extraction systems are typically installed to remediate contaminant plumes or prevent further spread of contamination. These systems are expensive to install and maintain. A traditional approach to designing such a wellfield uses a series of trial-and-error simulations to test the effects of various well locations and pump rates. However, the optimal locations and pump rates of extraction wells are difficult to determine when objectives related to the site hydrogeology and potential pumping scheme are considered. This paper describes a case study of an application of linear programming theory to determine optimal well placement and pump rates. The objectives of the pumping scheme were to contain contaminant migration and reduce contaminant concentrations while minimizing the total amount of water pumped and treated. Past site activities at the area under study included disposal of contaminants in pits. Several groundwater plumes have been identified, and others may be present. The area of concern is bordered on three sides by a wetland, which receives a portion of its input budget as groundwater discharge from the pits. Optimization of the containment pumping scheme was intended to meet three goals: (1) prevent discharge of contaminated groundwater to the wetland, (2) minimize the total water pumped and treated (cost benefit), and (3) avoid dewatering of the wetland (cost and ecological benefits). Possible well locations were placed at known source areas. To constrain the problem, the optimization program was instructed to prevent any flow toward the wetland along a user-specified border. In this manner, the optimization routine selects well locations and pump rates so that a groundwater divide is produced along this boundary

  13. Electrical imaging of subsurface nanoparticle propagation for in-situ groundwater remediation

    Science.gov (United States)

    Flores Orozco, Adrián; Gallistl, Jakob; Schmid, Doris; Micic Batka, Vesna; Bücker, Matthias; Hofmann, Thilo

    2017-04-01

    Application of nanoparticles has emerged as a promising in situ remediation technology for the remediation of contaminated groundwater, particularly for areas difficult to access by other remediation techniques. The performance of nanoparticle injections, as a foremost step within this technology, is usually assessed through the geochemical analysis of soil and groundwater samples. This approach is not well suited for a real-time monitoring, and often suffers from a poor spatio-temporal resolution and only provides information from areas close to the sampling points. To overcome these limitations we propose the application of non-invasive Induced Polarization (IP) imaging, a geophysical method that provides information on the electrical properties of the subsurface. The analysis of temporal changes in the electrical images allows tracking the propagation of the injected nanoparticle suspension and detection of the induced bio-geochemical changes in the subsurface. Here, we present IP monitoring results for data collected during the injection of Nano-Goethite particles (NGP) used for simulation of biodegradation of a BTEX plume (i.e., benzene, toluene, ethylbenzene, and xylene) at the Spolchemie II site, CZ. Frequency-domain IP measurements were collected parallel to the groundwater flow direction and centred on the NGP injection point. Pre-injection imaging results revealed high electrical conductivities (> 10 S/m) and negligible polarization effects in the BTEX-contaminated part of the saturated zone (below 5 m depth). The apparently contradictory observation - BTEX compounds are poor electrical conductors - can be explained by the release of carbonic acids (a metabolic by-product of the biodegradation of hydrocarbons), which leads to an increase of the electrical conductivity. Post-injection images revealed a significant decrease (> 50%) of the electrical conductivity, with even larger changes in the proximity of the injection points, most likely due to the

  14. Grand challenge problems in environmental modeling and remediation: groundwater contaminant transport

    Energy Technology Data Exchange (ETDEWEB)

    Todd Arbogast; Steve Bryant; Clint N. Dawson; Mary F. Wheeler

    1998-08-31

    This report describes briefly the work of the Center for Subsurface Modeling (CSM) of the University of Texas at Austin (and Rice University prior to September 1995) on the Partnership in Computational Sciences Consortium (PICS) project entitled Grand Challenge Problems in Environmental Modeling and Remediation: Groundwater Contaminant Transport.

  15. An innovative funnel and gate approach to groundwater remediation

    International Nuclear Information System (INIS)

    Johnson, D.O.; Wilkey, M.L.; Willis, J.M.

    1996-01-01

    The US Department of Energy, office of Science and Technology (EM-50) sponsored a demonstration project of the Barrier Member Containment Corporation's patented EnviroWall trademark system at the Savannah River site. With this system, contaminated groundwater can be funneled into a treatment system without pumping the contaminated water to the surface. The EnviroWall trademark barrier and pass-through system, an innovative product of sic years of research and development, provides a means to enhance groundwater flow on the upgradient side of an impermeable wall and direct it to an in situ treatment system. The EnviroWall trademark system is adaptable to most site conditions. Remedial applications range form plume containment to more robust designs that incorporate groundwater manipulation coupled with in situ treatment. Several key innovations of the EnviroWall trademark system include the following: a method for guide box installation; a means for using interlocking seals at vertical seams; a down-hole video camera for inspecting seams and panels, installation of horizontal- and vertical-collection systems; installation of vertical monitoring wells and instrumentation on each side of the barrier; site-specific backfill design; and a pass-through system for funneling groundwater into a treatment system

  16. Groundwater remediation of hexavalent chromium along the Columbia River at the Hanford site in Washington state, USA - 59030

    International Nuclear Information System (INIS)

    Foss, Dyan L.; Charboneau, Briant L.

    2012-01-01

    The U.S. Department of Energy Hanford Site, formerly used for nuclear weapons production, encompasses 1500 square kilometers in southeast Washington State along the Columbia River. A principle threat to the river are the groundwater plumes of hexavalent chromium (Cr(VI)), which affect approximately 9.8 square kilometers, and 4.1 kilometers of shoreline. Cleanup goals are to stop Cr(VI) from entering the river by the end of 2012 and remediate the groundwater plumes to the drinking water standards by the end of 2020. Five groundwater pump-and-treat systems are currently in operation for the remediation of Cr(VI). Since the 1990's, over 13.6 billion L of groundwater have been treated; over 1, 435 kg of Cr(VI) have been removed. This paper describes the unique aspects of the site, its environmental setting, hydrogeology, groundwater-river interface, riverine hydraulic effects, remediation activities completed to date, a summary of the current and proposed pump-and-treat operations, the in situ redox manipulation barrier, and the effectiveness of passive barriers, resins, and treatability testing results of calcium polysulfide, bio-stimulation, and electrocoagulation, currently under evaluation. (authors)

  17. Permeable reactive barrier - innovative technology for ground-water remediation

    International Nuclear Information System (INIS)

    Vidic, D.R.

    2002-01-01

    Significant advances in the application of permeable reactive barriers (PRBs) for ground-water remediation have been witnessed in the last 5 years. From only a few full-scale systems and pilot-scale demonstrations, there are currently at least 38 full-scale PRBs using zero-valent iron (ZVI) as a reactive material. Of those, 26 are continuous reactive walls, 9 are funnel-and- gate systems and 3 are in situ reactive vessels. Most of the PRB systems have used granular iron media and have been applied to address the control of contamination caused by chlorinated volatile organic compounds or heavy metals. Many regulatory agencies have expressed interest in PRB systems and are becoming more comfortable in issuing permits. The main advantage of PRB systems is that the installation costs are comparable with those of other ground-water remediation technologies, while the O and M costs are significantly lower and are mostly due to monitoring requirements, which are required for all remediation approaches. In addition, the land use can resume after the installation of the PRB systems, since there are few visible signs of the installation above grounds except for the monitoring wells. It is difficult to make any definite conclusions about the long-term performance of PRB systems because there is no more than 5 years of the record of performance that can be used for such analysis. The two main challenges still facing this technology are: (1) evaluating the longevity (geochemistry) of a PRB; and (2) ensuring/verifying hydraulic performance. A number of public/private partnerships have been established in recent years that are working together to resolve some of these problems. This organized approach by combining the efforts of several government agencies and private companies will likely result in better understanding and, hopefully, better acceptance of this technology in the future. (author)

  18. Guidelines for active spreading during in situ chemical oxidation to remediate contaminated groundwater

    Science.gov (United States)

    The effectiveness of in situ chemical oxidation to remediate contaminated aquifers depends on the extent and duration of contact between the injected treatment chemical and the groundwater contaminant (the reactants). Techniques that inject and extract in the aquifer to ‘ac...

  19. Phase 1 remediation of jet fuel contaminated soil and groundwater at JFK International Airport using dual phase extraction and bioventing

    International Nuclear Information System (INIS)

    Roth, R.; Bianco, P. Rizzo, M.

    1995-01-01

    Soil and groundwater contaminated with jet fuel at Terminal One of the JFK International Airport in New York have been remediated using dual phase extraction (DPE) and bioventing. Two areas were remediated using 51 DPE wells and 20 air sparging/air injection wells. The total area remediated by the DPE wells is estimated to be 4.8 acres. Groundwater was extracted to recover nonaqueous phase and aqueous phase jet fuel from the shallow aquifer and treated above ground by the following processes; oil/water separation, iron-oxidation, flocculation, sedimentation, filtration, air stripping and liquid-phase granular activated carbon (LPGAC) adsorption. The extracted vapors were treated by vapor-phase granular activated carbon (VPGAC) adsorption in one area, and catalytic oxidation and VPGAC adsorption in another area. After 6 months of remediation, approximately 5,490 lbs. of volatile organic compounds (VOCs) were removed by soil vapor extraction (SVE), 109,650 lbs. of petroleum hydrocarbons were removed from the extracted groundwater, and 60,550 lbs. of petroleum hydrocarbons were biologically oxidized by subsurface microorganisms. Of these three mechanisms, the rate of petroleum hydrocarbon removal was the highest for biological oxidation in one area and by groundwater extraction in another area

  20. Consensus implementation of a groundwater remediation project at the Idaho National Engineering Laboratory

    International Nuclear Information System (INIS)

    Hastings, K.R.; Carlson, D.S.

    1996-01-01

    Because of significant characterization uncertainties existing when the Record of Decision was signed and the unfavorable national reputation of groundwater pump and treat remediation projects, the Test Area North (TAN) groundwater ROD includes the evaluation of five emerging technologies that show potential for treating the organic contamination in situ or reducing the toxicity of contaminants above ground. Treatability studies will be conducted to ascertain whether any may be suitable for implementation at TAN to yield more timely or cost effective restoration of the aquifer. The implementation approach established for the TAN groundwater project is a consensus approach, maximizing a partnership relation with stakeholders in constant, iterative implementation decision making

  1. Record of Decision Tank Farm Soil and INTEC Groundwater

    Energy Technology Data Exchange (ETDEWEB)

    L. S. Cahn

    2007-05-01

    This decision document presents the selected remedy for Operable Unit (OU) 3-14 tank farm soil and groundwater at the Idaho Nuclear Technology and Engineering Center (INTEC), which is located on the Idaho National Laboratory (INL) Site. The tank farm was initially evaluated in the OU 3-13 Record of Decision (ROD), and it was determined that additional information was needed to make a final decision. Additional information has been obtained on the nature and extent of contamination in the tank farm and on the impact of groundwater. The selected remedy was chosen in accordance with the Comprehensive Environmental Response, Liability and Compensation Act of 1980 (CERCLA) (42 USC 9601 et seq.), as amended by the Superfund Amendments and Reauthorization Act of 1986 (Public Law 99-499) and the National Oil and Hazardous Substances Pollution Contingency Plan (40 CFR 300). The selected remedy is intended to be the final action for tank far soil and groundwater at INTEC.

  2. Risk-based decision analysis for groundwater operable units

    International Nuclear Information System (INIS)

    Chiaramonte, G.R.

    1995-01-01

    This document proposes a streamlined approach and methodology for performing risk assessment in support of interim remedial measure (IRM) decisions involving the remediation of contaminated groundwater on the Hanford Site. This methodology, referred to as ''risk-based decision analysis,'' also supports the specification of target cleanup volumes and provides a basis for design and operation of the groundwater remedies. The risk-based decision analysis can be completed within a short time frame and concisely documented. The risk-based decision analysis is more versatile than the qualitative risk assessment (QRA), because it not only supports the need for IRMs, but also provides criteria for defining the success of the IRMs and provides the risk-basis for decisions on final remedies. For these reasons, it is proposed that, for groundwater operable units, the risk-based decision analysis should replace the more elaborate, costly, and time-consuming QRA

  3. Aquifer characterization and groundwater modeling in support of remedial actions at the Weldon Spring Site

    International Nuclear Information System (INIS)

    Durham, L.A.; Carman, J.D.

    1993-01-01

    Aquifer characterization studies were performed to develop a hydrogeologic understanding of an unconfined shallow aquifer at the Weldon Spring site west of St. Louis, Missouri. The 88-ha site became contaminated because of uranium and thorium processing and disposal activities that took place from the 1940s through the 1960s. Slug and pumping tests provided valuable information on the lateral distribution of hydraulic conductivities, and packer tests and lithologic information were used to determine zones of contrasting hydrologic properties within the aquifer. A three-dimensional, finite- element groundwater flow model was developed and used to simulate the shallow groundwater flow system at the site. The results of this study show that groundwater flow through the system is predominantly controlled by a zone of fracturing and weathering in the upper portion of the limestone aquifer. The groundwater flow model, developed and calibrated from field investigations, improved the understanding of the hydrogeology and supported decisions regarding remedial actions at the site. The results of this study illustrate the value, in support of remedial actions, of combining field investigations with numerical modeling to develop an improved understanding of the hydrogeology at the site

  4. Sustainable in-well vapor stripping: A design, analytical model, and pilot study for groundwater remediation

    Science.gov (United States)

    Sutton, Patrick T.; Ginn, Timothy R.

    2014-12-01

    A sustainable in-well vapor stripping system is designed as a cost-effective alternative for remediation of shallow chlorinated solvent groundwater plumes. A solar-powered air compressor is used to inject air bubbles into a monitoring well to strip volatile organic compounds from a liquid to vapor phase while simultaneously inducing groundwater circulation around the well screen. An analytical model of the remediation process is developed to estimate contaminant mass flow and removal rates. The model was calibrated based on a one-day pilot study conducted in an existing monitoring well at a former dry cleaning site. According to the model, induced groundwater circulation at the study site increased the contaminant mass flow rate into the well by approximately two orders of magnitude relative to ambient conditions. Modeled estimates for 5 h of pulsed air injection per day at the pilot study site indicated that the average effluent concentrations of dissolved tetrachloroethylene and trichloroethylene can be reduced by over 90% relative to the ambient concentrations. The results indicate that the system could be used cost-effectively as either a single- or multi-well point technology to substantially reduce the mass of dissolved chlorinated solvents in groundwater.

  5. Hanford Site Groundwater Monitoring for Fiscal Year 2005

    Energy Technology Data Exchange (ETDEWEB)

    Hartman, Mary J.; Morasch, Launa F.; Webber, William D.

    2006-02-28

    Recovery Act of 1976 groundwater monitoring continued at 25 waste management areas during fiscal year 2005: 15 under interim or final status detection programs and data indicate that they are not adversely affecting groundwater, 8 under interim status groundwater quality assessment programs to assess contamination, and 2 under final status corrective-action programs. During calendar year 2005, drillers completed 27 new monitoring wells, and decommissioned (filled with grout) 115 unneeded wells. Vadose zone monitoring, characterization, and remediation continued in fiscal year 2005. Remediation and associated monitoring continued at a soil-vapor extraction system in the 200 West Area, which removes gaseous carbon tetrachloride from the vadose zone. DOE uses geophysical methods to monitor potential movement of contamination beneath former waste sites.

  6. Status of remedial investigation activities in the Hanford Site 300 Area groundwater operable unit

    International Nuclear Information System (INIS)

    Hulstrom, L.C.; Innis, B.E.; Frank, M.A.

    1993-09-01

    The Phase 1 remedial investigation (RI) and Phase 1 and 2 feasibility studies (FS) for the 300-FF-5 groundwater operable unit underlying the 300 Area on the Hanford Site have been completed. Analysis and evaluation of soil, sediment, and surface water, and biotic sampling data, groundwater chemistry, and radiological data gathered over the past 3 years has been completed. Risk assessment calculations have been performed. Use of the data gathered, coupled with information from an automated water level data collection system, has enabled engineers to track three plumes that represent the most significant contamination of the groundwater

  7. Coordinating bifurcated remediation of soil and groundwater at sites containing multiple operable units

    International Nuclear Information System (INIS)

    Laney, D.F.

    1996-01-01

    On larger and/or more complex sites, remediation of soil and groundwater is sometimes bifurcated. This presents some unique advantages with respect to expedited cleanup of one medium, however, it requires skillful planning and significant forethought to ensure that initial remediation efforts do not preclude some long-term options, and/or unduly influence the subsequent selection of a technology for the other operable units and/or media. this paper examines how the decision to bifurcate should be approached, the various methods of bifurcation, the advantages and disadvantages of bifurcation, and the best methods to build flexibility into the design of initial remediation systems so as to allow for consideration of a fuller range of options for remediation of other operable units and/or media at a later time. Pollutants of concern include: metals; petroleum hydrocarbons; and chlorinated solvents

  8. Proposed plan for remedial action for the Groundwater Operable Unit at the Chemical Plant Area of the Weldon Spring Site, Weldon Spring, Missouri

    International Nuclear Information System (INIS)

    1999-01-01

    This Proposed Plan addresses the remediation of groundwater contamination at the chemical plant area of the Weldon Spring site in Weldon Spring, Missouri. The site is located approximately 48 km (30 mi) west of St. Louis in St. Charles County . Remedial activities at the site will be conducted in accordance with the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA). The U.S. Department of Energy (DOE), in conjunction with the U.S. Department of the Army (DA), conducted a joint remedial investigation/feasibility study (RI/FS) to allow for a comprehensive evaluation of groundwater conditions at the Weldon Spring chemical plant area and the Weldon Spring ordnance works area, which is an Army site adjacent to the chemical plant area. Consistent with DOE policy, National Environmental Policy Act (NEPA) values have been incorporated into the CERCLA process. That is, the analysis conducted and presented in the RVFS reports included an evaluation of environmental impacts that is comparable to that performed under NEPA. This Proposed Plan summarizes information about chemical plant area groundwater that is presented in the following documents: (1) The Remedial Investigation (RI), which presents information on the nature and extent of contamination; (2) The Baseline Risk Assessment (BRA), which evaluates impacts to human health and the environment that could occur if no cleanup action of the groundwater were taken (DOE and DA 1997a); and (3) The Feasibility Study (FS) and the Supplemental FS, which develop and evaluate remedial action alternatives for groundwater remediation

  9. The effect of remedial measures upon groundwater quality in connection with soil contamination by chlorinated hydrocarbons and the related costs - by example of the City of Hanover

    International Nuclear Information System (INIS)

    Mull, R.; Mull, J.; Pielke, M.

    1992-01-01

    The effectiveness of remedial actions on the groundwater quality was investigated in the aquifer of the City of Hannover. The improvement of groundwater quality was related to the costs for the remedial actions. The attention was focussed on groundwater pollution by chlorinated hydrocarbons as the most important contaminants of groundwater in urban areas. (orig.)

  10. A stochastic optimization model under modeling uncertainty and parameter certainty for groundwater remediation design-Part I. Model development

    Energy Technology Data Exchange (ETDEWEB)

    He, L., E-mail: li.he@ryerson.ca [Department of Civil Engineering, Faculty of Engineering, Architecture and Science, Ryerson University, 350 Victoria Street, Toronto, Ontario, M5B 2K3 (Canada); Huang, G.H. [Environmental Systems Engineering Program, Faculty of Engineering, University of Regina, Regina, Saskatchewan, S4S 0A2 (Canada); College of Urban Environmental Sciences, Peking University, Beijing 100871 (China); Lu, H.W. [Environmental Systems Engineering Program, Faculty of Engineering, University of Regina, Regina, Saskatchewan, S4S 0A2 (Canada)

    2010-04-15

    Solving groundwater remediation optimization problems based on proxy simulators can usually yield optimal solutions differing from the 'true' ones of the problem. This study presents a new stochastic optimization model under modeling uncertainty and parameter certainty (SOMUM) and the associated solution method for simultaneously addressing modeling uncertainty associated with simulator residuals and optimizing groundwater remediation processes. This is a new attempt different from the previous modeling efforts. The previous ones focused on addressing uncertainty in physical parameters (i.e. soil porosity) while this one aims to deal with uncertainty in mathematical simulator (arising from model residuals). Compared to the existing modeling approaches (i.e. only parameter uncertainty is considered), the model has the advantages of providing mean-variance analysis for contaminant concentrations, mitigating the effects of modeling uncertainties on optimal remediation strategies, offering confidence level of optimal remediation strategies to system designers, and reducing computational cost in optimization processes.

  11. The use of in-situ dual vacuum extraction for remediation of soil and groundwater

    International Nuclear Information System (INIS)

    Trowbridge, B.E.; Ott, D.E.

    1992-01-01

    Dual Extraction provides a rapid and cost-effective method of remediating soil and groundwater impacted by volatile organic compounds (VOC's). Dual Extraction is the removal of both water and vapors through the same borehole using entrainment. This technology provides for the remediation of the vadose zone, capillary fringe, smear zone, and existing water table. The effectiveness of this technology is shown in a case study. A release from an Underground Storage Tank (UST) was responsible for a hydrocarbon plume spreading over approximately 50,000 square feet. The release produced vadose zone contamination in the silty and sandy clays from 10 - 30 feet below ground surface with TPH concentrations up to 1,400 mg/kg. A layer of free floating liquid hydrocarbon was present on a shallow aquifer located at 30 feet bgs in thicknesses ranging from 0.5 feet to 3.0 feet. An in-situ dual-extraction system was installed to remediate the soils and groundwater to levels as required by the Los Angeles Regional Water Quality Control Board (RWQCB). The system operated 24 hours/day for 196 days with an operating efficiency of over 99%. After 196 days, over 17,000 pounds of hydrocarbons had been extracted from the soils. Seven confirmatory soil borings were advanced in the area of highest initial hydrocarbon concentrations and indicated that TPH and BTEX concentrations had decreased over 99% from initial soil concentrations. Three confirmatory groundwater samples were obtained from monitoring wells initially exhibiting up to 3 feet of floating product. Confirmatory samples exhibited non-detectable (ND) concentrations of TPH and BTEX. Based upon the positive confirmatory results, site closure was obtained from the RWQCB in May of 1991. In only 28 weeks of operation, the groundwater contamination was reduced from free floating product to non-detectable concentrations of TPH using Dual Vacuum Extraction

  12. A stochastic optimization model under modeling uncertainty and parameter certainty for groundwater remediation design--part I. Model development.

    Science.gov (United States)

    He, L; Huang, G H; Lu, H W

    2010-04-15

    Solving groundwater remediation optimization problems based on proxy simulators can usually yield optimal solutions differing from the "true" ones of the problem. This study presents a new stochastic optimization model under modeling uncertainty and parameter certainty (SOMUM) and the associated solution method for simultaneously addressing modeling uncertainty associated with simulator residuals and optimizing groundwater remediation processes. This is a new attempt different from the previous modeling efforts. The previous ones focused on addressing uncertainty in physical parameters (i.e. soil porosity) while this one aims to deal with uncertainty in mathematical simulator (arising from model residuals). Compared to the existing modeling approaches (i.e. only parameter uncertainty is considered), the model has the advantages of providing mean-variance analysis for contaminant concentrations, mitigating the effects of modeling uncertainties on optimal remediation strategies, offering confidence level of optimal remediation strategies to system designers, and reducing computational cost in optimization processes. 2009 Elsevier B.V. All rights reserved.

  13. Corrective measures evaluation report for technical area-v groundwater.

    Energy Technology Data Exchange (ETDEWEB)

    Witt, Johnathan L (North Wind, Inc., Idaho Falls, ID); Orr, Brennon R. (North Wind, Inc., Idaho Falls, ID); Dettmers, Dana L. (North Wind, Inc., Idaho Falls, ID); Hall, Kevin A. (North Wind, Inc., Idaho Falls, ID); Howard, Hope (North Wind, Inc., Idaho Falls, ID)

    2005-07-01

    This Corrective Measures Evaluation Report was prepared as directed by the Compliance Order on Consent issued by the New Mexico Environment Department to document the process of selecting the preferred remedial alternative for contaminated groundwater at Technical Area V. Supporting information includes background information about the site conditions and potential receptors and an overview of work performed during the Corrective Measures Evaluation. Evaluation of remedial alternatives included identification and description of four remedial alternatives, an overview of the evaluation criteria and approach, qualitative and quantitative evaluation of remedial alternatives, and selection of the preferred remedial alternative. As a result of the Corrective Measures Evaluation, it was determined that monitored natural attenuation of all contaminants of concern (trichloroethene, tetrachloroethene, and nitrate) was the preferred remedial alternative for implementation as the corrective measure to remediate contaminated groundwater at Technical Area V of Sandia National Laboratories/New Mexico. Finally, design criteria to meet cleanup goals and objectives and the corrective measures implementation schedule for the preferred remedial alternative are presented.

  14. Remedial design report and remedial action work plan for the 100-HR-3 and 100-KR-4 groundwater operable units' interim action

    International Nuclear Information System (INIS)

    1996-09-01

    This document is a combination remedial design report and remedial action work plan for the 100-HR-3 and 100-KR-4 Operable Units (located on the Hanford Site in Richland, Washington) interim action. The interim actions described in this document represent the first of an ongoing program to address groundwater contamination in each operable unit. This document describes the design basis, provides a description of the interim action, and identifies how they will meet the requirements set forth in the interim action Record of Decision

  15. Mechanisms of uranium interactions with hydroxyapatite: Implications for groundwater remediation

    Science.gov (United States)

    Fuller, C.C.; Bargar, J.R.; Davis, J.A.; Piana, M.J.

    2002-01-01

    The speciation of U(VI) sorbed to synthetic hydroxyapatite was investigated using a combination of U LIII-edge XAS, synchrotron XRD, batch uptake measurements, and SEM-EDS. The mechanisms of U(VI) removal by apatite were determined in order to evaluate the feasibility of apatitebased in-situ permeable reactive barriers (PRBs). In batch U(VI) uptake experiments with synthetic hydroxyapatite (HA), near complete removal of dissolved uranium (>99.5%) to use in development of PRBs for groundwater U(VI) remediation.

  16. REMEDIATION OF NITRATE-CONTAMINATED GROUNDWATER USING A BIOBARRIER

    International Nuclear Information System (INIS)

    STrietelmeir, B.

    2000-01-01

    A biobarrier system has been developed for use in remediating shallow alluvial groundwater. This barrier is made from highly porous materials that are relatively long-lasting, carbon-based (to supply a limiting nutrient in nitrate destruction, in most cases), and extremely inexpensive and easy to emplace. In a series of laboratory studies, we have determined the effectiveness of this barrier at destroying nitrate and perchlorate in groundwater from Mortandad Canyon at Los Alamos National Laboratory (LANL). This groundwater was obtained from a monitoring well, MCO-5, which is located in the flowpath of the discharge waters from the LANL Radioactive Liquid Waste Treatment Facility (RLWTF). Water with elevated nitrate levels has been discharged from this plant for many years, until recently when the nitrate levels have been brought under the discharge limits. However, the historical discharge has resulted in a nitrate plume in the alluvial groundwater in this canyon. The LANL Multi-Barrier project was initiated this past year to develop a system of barriers that would prevent the transport of radionuclides, metals, colloids and other contaminants, including nitrate and perchlorate, further down the canyon in order to protect populations down-gradient. The biobarrier. will be part of this Multi-Barrier system. We have demonstrated the destruction of nitrate at levels up to 6.5-9.7 mhl nitrate (400-600 mg/L), and that of perchlorate at levels of about 4.3 microM perchlorate (350 ppb). We have quantified the populations of microorganisms present in the biofilm that develops on the biobarrier. The results of this research will be discussed along with other potential applications of this system

  17. Pump-and-treat is not the only solution to aquifer remediation

    International Nuclear Information System (INIS)

    Odermatt, J.R.

    1994-01-01

    The Environmental Protection Agency (EPA) recently surveyed remediation technologies used at petroleum-contaminated sites in 22 states. About 96 percent of underground storage tank (UST) corrective action sites used some form of pump-and-treat technology to remediate contaminated groundwater. However, using only pump-and-treat technology is not a cost-effective approach to aquifer remediation. Pump-and-treat may be more appropriate for containing plumes or for use in initial emergency response actions at sites and massive NAPL releases to groundwater. As of 1990, 68 percent of Superfund records of decision selected pump-and-treat as the final remedy for aquifer remediation. However, of 13 sites where the remedial alternative objective was to restore the aquifer to health-based levels, only one pump-and-treat method has succeeded. Except in cases where human health and the environment are threatened, long-term active technologies, such as pump-and-treat, may not be warranted. Groundwater monitoring and possible wellhead treatment may be perceived as time-consuming processes; however, at many sites, this long-term approach may be far less costly and just as effective as other long-term strategies based on exclusive use of pump-and-treat technology

  18. Remedial action plan and site design for stabilization of the inactive uranium processing site at Naturita, Colorado. Appendix B of Attachment 3: Groundwater hydrology report, Attachment 4: Water resources protection strategy, Final

    Energy Technology Data Exchange (ETDEWEB)

    1994-03-01

    Attachment 3 Groundwater Hydrology Report describes the hydrogeology, water quality, and water resources at the processing site and Dry Flats disposal site. The Hydrological Services calculations contained in Appendix A of Attachment 3, are presented in a separate report. Attachment 4 Water Resources Protection Strategy describes how the remedial action will be in compliance with the proposed EPA groundwater standards.

  19. INDEPENDENT REVIEW OF THE X-701B GROUNDWATER REMEDY, PORTSMOUTH, OHIO: TECHNICAL EVALUATION AND RECOMMENDATIONS

    Energy Technology Data Exchange (ETDEWEB)

    Looney, B.; Eddy-Dilek, C.; Costanza, J.; Rossabi, J.; Early, T.; Skubal, K.; Magnuson, C.

    2008-12-15

    The Department of Energy Portsmouth Paducah Project Office requested assistance from Department of Energy Office of Environmental Management (EM-22) to provide independent technical experts to evaluate past and ongoing remedial activities at the Portsmouth facility that were completed to address TCE contamination associated with the X-701B groundwater plume and to make recommendations for future efforts. The Independent Technical Review team was provided with a detailed and specific charter. The charter requested that the technical team first review the past and current activities completed for the X-701B groundwater remedy for trichloroethene (TCE) in accordance with a Decision Document that was issued by Ohio EPA on December 8, 2003 and a Work Plan that was approved by Ohio EPA on September 22, 2006. The remedy for X-701B divides the activities into four phases: Phase I - Initial Source Area Treatment, Phase II - Expanded Source Area Treatment, Phase III - Evaluation and Reporting, and Phase IV - Downgradient Remediation and Confirmation of Source Area Treatment. Phase I of the remedy was completed during FY2006, and DOE has now completed six oxidant injection events within Phase II. The Independent Technical Review team was asked to evaluate Phase II activities, including soil and groundwater results, and to determine whether or not the criteria that were defined in the Work Plan for the Phase II end point had been met. The following criteria are defined in the Work Plan as an acceptable Phase II end point: (1) Groundwater samples from the identified source area monitoring wells have concentrations below the Preliminary Remediation Goal (PRG) for TCE in groundwater, or (2) The remedy is no longer effective in removing TCE mass from the source area. In addition, the charter specifies that if the Review Team determines that the Phase II endpoint has not been reached, then the team should address the following issues: (1) If additional injection events are

  20. Groundwater protection management program plan

    International Nuclear Information System (INIS)

    1992-06-01

    US Department of Energy (DOE) Order 5400.1 requires the establishment of a groundwater protection management program to ensure compliance with DOE requirements and applicable Federal, state, and local laws and regulations. The Uranium Mill Tailings Remedial Action (UMTRA) Project Office has prepared a ''Groundwater Protection Management Program Plan'' (groundwater protection plan) of sufficient scope and detail to reflect the program's significance and address the seven activities required in DOE Order 5400.1, Chapter 3, for special program planning. The groundwater protection plan highlights the methods designed to preserve, protect, and monitor groundwater resources at UMTRA Project processing and disposal sites. The plan includes an overview of the remedial action status at the 24 designated processing sites and identifies project technical guidance documents and site-specific documents for the UMTRA groundwater protection management program. In addition, the groundwater protection plan addresses the general information required to develop a water resources protection strategy at the permanent disposal sites. Finally, the plan describes ongoing activities that are in various stages of development at UMTRA sites (long-term care at disposal sites and groundwater restoration at processing sites). This plan will be reviewed annually and updated every 3 years in accordance with DOE Order 5400.1

  1. SAFETY IMPROVES DRAMATICALLY IN FLUOR HANFORD SOIL AND GROUNDWATER REMEDIATION PROJECT

    International Nuclear Information System (INIS)

    GERBER MS

    2007-01-01

    This paper describes dramatic improvements in the safety record of the Soil and Groundwater Remediation Project (SGRP) at the Hanford Site in southeast Washington state over the past four years. During a period of enormous growth in project work and scope, contractor Fluor Hanford reduced injuries, accidents, and other safety-related incidents and enhanced a safety culture that earned the SGRP Star Status in the Department of Energy's (DOE's) Voluntary Protection Program (VPP) in 2007. This paper outlines the complex and multi-faceted work of Fluor Hanford's SGRP and details the steps taken by the project's Field Operations and Safety organizations to improve safety. Holding field safety meetings and walkdowns, broadening safety inspections, organizing employee safety councils, intensively flowing down safety requirements to subcontractors, and adopting other methods to achieve remarkable improvement in safety are discussed. The roles of management, labor and subcontractors are detailed. Finally, SGRP's safety improvements are discussed within the context of overall safety enhancements made by Fluor Hanford in the company's 11 years of managing nuclear waste cleanup at the Hanford Site

  2. Groundwater Radioiodine: Prevalence, Biogeochemistry, And Potential Remedial Approaches

    International Nuclear Information System (INIS)

    Denham, M.; Kaplan, D.; Yeager, C.

    2009-01-01

    ) compile the background information necessary to understand behavior of 129 I in the environment, (2) discuss sustainable remediation approaches to 129 I contaminated groundwater, and (3) identify areas of research that will facilitate remediation of 129 I contaminated areas on DOE sites. Lines of scientific inquiry that would significantly advance the goals of basic and applied research programs for accelerating 129 I environmental remediation and reducing uncertainty associated with disposal of 129 I waste are: (1) Evaluation of amendments or other treatment systems that can sequester subsurface groundwater 129 I. (2) Develop analytical techniques for measurement of total 129 I that eliminate the necessity of collecting and shipping large samples of groundwater. (3) Develop and evaluate ways to manipulate areas with organic-rich soil, such as wetlands, to maximize 129 I sorption, minimizing releases during anoxic conditions. (4) Develop analytical techniques that can identify the various 129 I species in the subsurface aqueous and solid phases at ambient concentrations and under ambient conditions. (5) Identify the mechanisms and factors controlling iodine-natural organic matter interactions at appropriate environmental concentrations. (6) Understand the biological processes that transform iodine species throughout different compartments of subsurface waste sites and the role that these processes have on 129 I flux

  3. GROUNDWATER RADIOIODINE: PREVALENCE, BIOGEOCHEMISTRY, AND POTENTIAL REMEDIAL APPROACHES

    Energy Technology Data Exchange (ETDEWEB)

    Denham, M.; Kaplan, D.; Yeager, C.

    2009-09-23

    former Yucca Mountain disposal facilities. The objectives of this report are to: (1) compile the background information necessary to understand behavior of {sup 129}I in the environment, (2) discuss sustainable remediation approaches to {sup 129}I contaminated groundwater, and (3) identify areas of research that will facilitate remediation of {sup 129}I contaminated areas on DOE sites. Lines of scientific inquiry that would significantly advance the goals of basic and applied research programs for accelerating {sup 129}I environmental remediation and reducing uncertainty associated with disposal of {sup 129}I waste are: (1) Evaluation of amendments or other treatment systems that can sequester subsurface groundwater {sup 129}I. (2) Develop analytical techniques for measurement of total {sup 129}I that eliminate the necessity of collecting and shipping large samples of groundwater. (3) Develop and evaluate ways to manipulate areas with organic-rich soil, such as wetlands, to maximize {sup 129}I sorption, minimizing releases during anoxic conditions. (4) Develop analytical techniques that can identify the various {sup 129}I species in the subsurface aqueous and solid phases at ambient concentrations and under ambient conditions. (5) Identify the mechanisms and factors controlling iodine-natural organic matter interactions at appropriate environmental concentrations. (6) Understand the biological processes that transform iodine species throughout different compartments of subsurface waste sites and the role that these processes have on {sup 129}I flux.

  4. [Study on the groundwater petroleum contaminant remediation by air sparging].

    Science.gov (United States)

    Wang, Zhi-Qiang; Wu, Qiang; Zou, Zu-Guang; Chen, Hong; Yang, Xun-Chang; Zhao, Ji-Chu

    2007-04-01

    The groundwater petroleum contaminant remediation effect by air sparging was investigated in an oil field. The results show that the soil geological situation has great influence on the air distribution, and the shape of air distribution is not symmetrical to the air sparging (AS) well as axis. The influence distance in the left of AS well is 6 m, and only 4 m in the right. The petroleum removal rate can reach 70% in the zone with higher air saturation, but only 40% in the zone with lower air saturation, and the average petroleum removal rate reaches 60% in the influence zone for 40 days continuous air sparging. The petroleum components in groundwater were analyzed by GC/MS (gas chromatogram-mass spectrograph) before and after experiments, respectively. The results show that the petroleum removal rate has relationship with the components and their properties. The petroleum components with higher volatility are easily removed by volatilization, but those with lower volatility are difficult to remove, so a tailing effect of lingering residual contaminant exists when the air sparging technology is adopted to treat groundwater contaminated by petroleum products.

  5. Application of Fe-Cu/Biochar System for Chlorobenzene Remediation of Groundwater in Inhomogeneous Aquifers

    Directory of Open Access Journals (Sweden)

    Xu Zhang

    2017-12-01

    Full Text Available Chlorobenzene (CB, as a typical Volatile Organic Contaminants (VOC, is toxic, highly persistent and easily migrates in water, posing a significant risk to human health and subsurface ecosystems. Therefore, exploring effective approaches to remediate groundwater contaminated by CB is essential. As an enhanced micro-electrolysis system for CB-contaminated groundwater remediation, this study attempted to couple the iron-copper bimetal with biochar. Two series of columns using sands with different grain diameters were used, consisting of iron, copper and biochar fillings as the permeable reactive barriers (PRBs, to simulate the remediation of CB-contaminated groundwater in homogeneous and heterogeneous aquifers. Regardless of the presence of homogeneous or heterogeneous porous media, the CB concentrations in the effluent from the PRB columns were significantly lower than the natural sandy columns, suggesting that the iron and copper powders coupled with biochar particles could have a significant removal effect compared to the natural sand porous media in the first columns. CB was transported relatively quickly in the heterogeneous porous media, likely due to the fact that the contaminant residence time is proportional to the infiltration velocities in the different types of porous media. The average effluent CB concentrations from the heterogeneous porous media were lower than those from homogeneous porous media. The heterogeneity retarded the vertical infiltration of CB, leading to its extended lateral distribution. During the treatment process, benzene and phenol were observed as the products of CB degradation. The ultimate CB removal efficiency was 61.4% and 68.1%, demonstrating that the simulated PRB system with the mixture of iron, copper and biochar was effective at removing CB from homogeneous and heterogeneous aquifers.

  6. Case study of an approved corrective action integrating active remediation with intrinsic remediation

    International Nuclear Information System (INIS)

    Teets, D.B.; Guest, P.R.; Blicker, B.R.

    1996-01-01

    Parsons Engineering Science, Inc., performed UST removals and/or site assessments at UST system locations at a former US Air Force Base (AFB) in Denver, Colorado. Four UST systems, incorporating 17 USTs, were located within the petroleum, oils, and lubricants bulk storage yard (POL Yard) of the former AFB. During the tank removals and subsequent site investigations, petroleum hydrocarbon contamination was found in soils at each site. Significant releases from two of the UST systems resulted in a dissolved benzene, toluene, ethylbenzene, and xylenes (BTEX) plume in the groundwater, and smear-zone contamination of soils beneath the majority of the POL Yard. Because of the close proximity of the UST systems, and the presence of the groundwater plume beneath the POL Yard, a corrective action plan (CAP) was prepared that encompassed all four UST systems. An innovative, risk-based CAP integrated active remediation of petroleum-contaminated soils with intrinsic remediation of groundwater. A natural attenuation evaluation for the dissolved BTEX was performed to demonstrate that natural attenuation processes are providing adequate remediation of groundwater and to predict the fate of the groundwater plume. BTEX concentrations versus distance were regressed to obtain attenuation rates, which were then used to calculate BTEX degradation rates using a one-dimensional, steady-state analytical solution. Additionally, electron acceptor concentrations in groundwater were compared to BTEX concentrations to provide evidence that natural attenuation of BTEX compounds was occurring. The natural attenuation evaluation was used in the CAP to support the intrinsic remediation with long-term monitoring alternative for groundwater, thereby avoiding the installation of an expensive groundwater remediation system

  7. Tailings From Mining Activities, Impact on Groundwater, and Remediation

    Directory of Open Access Journals (Sweden)

    Khalid Al-Rawahy

    2001-12-01

    Full Text Available Effluent wastes from mining operations and beneficiation processes are comprized mostly of the following pollutants: total suspended solids (TTS, alkalinity or acidity (pH, settleable solids, iron in ferrous mining, and dissolved metals in nonferrous mining. Suspended solids consist of small particles of solid pollutants that resist separation by conventional means. A number of dissolved metals are considered toxic pollutants. The major metal pollutants present in ore mining and beneficiation waste waters include arsenic, cadmium, copper, lead, mercury, nickel, and zinc. Tailings ponds are used for both the disposal of solid waste and the treatment of waste-water streams. The supernatant decanted from these ponds contains suspended solids and, at times, process reagents introduced to the water during ore beneficiation. Leakage of material from tailings pond into groundwater is one possible source of water pollution in the mining industry. Percolation of waste-water from impoundment may occur if tailings ponds are not properly designed. This paper addresses potential groundwater pollution due to effluent from mining activities, and the possible remediation options.

  8. Particulate Pyrite Autotrophic Denitrification (PPAD) for Remediation of Nitrate-contaminated Groundwater

    Science.gov (United States)

    Tong, S.; Rodriguez-Gonzalez, L. C.; Henderson, M.; Feng, C.; Ergas, S. J.

    2015-12-01

    The rapid movement of human civilization towards urbanization, industrialization, and increased agricultural activities has introduced a large amount of nitrate into groundwater. Nitrate is a toxic substance discharged from groundwater to rivers and leads to decreased dissolved oxygen and eutrophication. For this experiment, an electron donor is needed to convert nitrate into non-toxic nitrogen gas. Pyrite is one of the most abundant minerals in the earth's crust making it an ideal candidate as an electron donor. The overall goal of this research was to investigate the potential for pyrite to be utilized as an electron donor for autotrophic denitrification of nitrate-contaminated groundwater. Batch studies of particulate pyrite autotrophic denitrification (PPAD) of synthetic groundwater (100 mg NO3--N L-1) were set up with varying biomass concentration, pyrite dose, and pyrite particle size. Reactors were seeded with mixed liquor volatile suspended solids (VSS) from a biological nitrogen removal wastewater treatment facility. PPAD using small pyrite particles (exhibited substantial nitrate removal rate, lower sulfate accumulation (5.46 mg SO42-/mg NO3--N) and lower alkalinity consumption (1.70 mg CaCO3/mg NO3--N) when compared to SOD (7.54 mg SO42-/mg NO3--N, 4.57 mg CaCO3/mg NO3--N based on stoichiometric calculation). This research revealed that the PPAD process is a promising technique for nitrate-contaminated groundwater treatment and promoted the utilization of pyrite in the field of environmental remediation.

  9. Numerical modeling of remediation of groundwater in a wellfield of in-situ leaching of uranium by pump-and-treat system

    International Nuclear Information System (INIS)

    Lv Junwen; Shi Wenge; Yang Yong

    2006-01-01

    Based on the hydrogeological conditions at the investigated site, the coupled mathematic model about the flow and the contaminant transportation in groundwater was established. The software Visual MODflow, the most popular simulation of groundwater flow and contaminant transportation, was used to study the contaminants distribution in groundwater during pumping at different pumping rates, and to determine the pumping well arrangement and optimal pumping rate, which directs the remediation of contaminated groundwater by the pump-and-treat system. (authors)

  10. Monitored Natural Attenuation as a Remediation Strategy for Nuclear Power Plant Applications

    Science.gov (United States)

    Kim, K.; Bushart, S.

    2009-12-01

    A NRC Information Notice (IN 2006-13) was produced to inform holders of nuclear operating licenses “of the occurrence of radioactive contamination of ground water at multiple facilities due to undetected leakage from facility structures, systems, or components (SSCs) that contain or transport radioactive fluids” so that they could consider actions, as appropriate, to avoid similar problems. To reinforce their commitment to environmental stewardship the nuclear energy industry has committed to improving management of situations that have the potential to lead to the inadvertent release of radioactive fluids. This Industry Groundwater Protection Initiative, finalized in June 2007 as [NEI 07-07], calls for implementation and improvement of on-site groundwater monitoring programs and enhanced communications with stakeholders and regulators about situations related to inadvertent releases. EPRI developed its Groundwater Protection Program to provide the nuclear energy industry with the technical support needed to implement the Industry Groundwater Initiative. An objective of the EPRI Groundwater Protection Program is to provide the nuclear industry with technically sound guidance for implementing and enhancing on-site groundwater monitoring programs. EPRI, in collaboration with the EPRI Groundwater Protection Committee of utility members, developed the EPRI Groundwater Protection Guidelines for Nuclear Power Plants (EPRI Report 1015118, November 2007), which provides site-specific guidance for implementing a technically sound groundwater monitoring program. The guidance applies a graded approach for nuclear plants to tailor a technically effective and cost efficient groundwater monitoring program to the site’s hydrogeology and risk for groundwater contamination. As part of the Groundwater Protection Program, EPRI is also investigating innovative remediation technologies for addressing low-level radioactive contamination in soils and groundwater at nuclear power

  11. Prioritization and accelerated remediation of groundwater contamination in the 200 Areas of the Hanford Site, Washington

    International Nuclear Information System (INIS)

    Wittreich, C.D.; Ford, B.H.

    1993-04-01

    The Hanford Site, operated by the US Department of Energy (DOE), occupies about 1,450 km 2 (560 mi 2 ) of the southeastern part of Washington State north of the confluence of the Yakima and Columbia Rivers. The Hanford Site is organized into numerically designated operational areas. The 200 Areas, located near the center of the Hanford Site, encompasses the 200 West, East and North Areas and cover an area of over 40 km 2 . The Hanford Site was originally designed, built, and operated to produce plutonium for nuclear weapons using production reactors and chemical reprocessing plants. Operations in the 200 Areas were mainly related to separation of special nuclear materials from spent nuclear fuel and contain related chemical and fuel processing and waste management facilities. Large quantities of chemical and radioactive waste associated with these processes were often disposed to the environment via infiltration structures such as cribs, ponds, ditches. This has resulted in over 25 chemical and radionuclide groundwater plumes, some of which have reached the Columbia River. An Aggregate Area Management Study program was implemented under the Hanford Federal Facility Agreement and Consent Order to assess source and groundwater contamination and develop a prioritized approach for managing groundwater remediation in the 200 Areas. This included a comprehensive evaluation of existing waste disposal and environmental monitoring data and the conduct of limited field investigations (DOE-RL 1992, 1993). This paper summarizes the results of groundwater portion of AAMS program focusing on high priority contaminant plume distributions and the groundwater plume prioritization process. The objectives of the study were to identify groundwater contaminants of concern, develop a conceptual model, refine groundwater contaminant plume maps, and develop a strategy to expedite the remediation of high priority contaminants through the implementation of interim actions

  12. An Integrated Simulation, Inference and Optimization Approach for Groundwater Remediation with Two-stage Health-Risk Assessment

    Directory of Open Access Journals (Sweden)

    Aili Yang

    2018-05-01

    Full Text Available In this study, an integrated simulation, inference and optimization approach with two-stage health risk assessment (i.e., ISIO-THRA is developed for supporting groundwater remediation for a petroleum-contaminated site in western Canada. Both environmental standards and health risk are considered as the constraints in the ISIO-THRA model. The health risk includes two parts: (1 the health risk during the remediation process and (2 the health risk in the natural attenuation period after remediation. In the ISIO-THRA framework, the relationship between contaminant concentrations and time is expressed through first-order decay models. The results demonstrate that: (1 stricter environmental standards and health risk would require larger pumping rates for the same remediation duration; (2 higher health risk may happen in the period of the remediation process; (3 for the same environmental standard and acceptable health-risk level, the remediation techniques that take the shortest time would be chosen. ISIO-THRA can help to systematically analyze interaction among contaminant transport, remediation duration, and environmental and health concerns, and further provide useful supportive information for decision makers.

  13. SAFETY IMPROVES DRAMATICALLY IN FLUOR HANFORD SOIL AND GROUNDWATER REMEDIATION PROJECT

    Energy Technology Data Exchange (ETDEWEB)

    GERBER MS

    2007-12-05

    This paper describes dramatic improvements in the safety record of the Soil and Groundwater Remediation Project (SGRP) at the Hanford Site in southeast Washington state over the past four years. During a period of enormous growth in project work and scope, contractor Fluor Hanford reduced injuries, accidents, and other safety-related incidents and enhanced a safety culture that earned the SGRP Star Status in the Department of Energy's (DOE's) Voluntary Protection Program (VPP) in 2007. This paper outlines the complex and multi-faceted work of Fluor Hanford's SGRP and details the steps taken by the project's Field Operations and Safety organizations to improve safety. Holding field safety meetings and walkdowns, broadening safety inspections, organizing employee safety councils, intensively flowing down safety requirements to subcontractors, and adopting other methods to achieve remarkable improvement in safety are discussed. The roles of management, labor and subcontractors are detailed. Finally, SGRP's safety improvements are discussed within the context of overall safety enhancements made by Fluor Hanford in the company's 11 years of managing nuclear waste cleanup at the Hanford Site.

  14. Speciation of As in calcite by micro-XAFS: Implications for remediation of As contamination in groundwater

    International Nuclear Information System (INIS)

    Yokoyama, Y; Takahashi, Y; Iwatsuki, T; Terada, Y

    2013-01-01

    To evaluate the role of calcite as a host phase of arsenic (As) in As-contaminated groundwater, distribution behavior of Asbetween natural calcite and groundwater in deep underground was investigated based on As oxidation state. Speciation analyses of As in natural calcite by μ-XRF-XAFS analyses showed (i) preferentialarsenate uptake by calcite, and (ii) promptness of arsenate uptake by minor iron (Fe) carbonate minerals coprecipitated with calcite. These findings suggest that the effect of calcite on As remediation of the As-contamination systems stronglydepends on arsenite to arsenate ratio (i.e., redox condition) in groundwater, and maybe governed bythe amount of Fe coprecipitated with calcite.

  15. Agar agar-stabilized milled zerovalent iron particles for in situ groundwater remediation

    Energy Technology Data Exchange (ETDEWEB)

    Velimirovic, Milica; Schmid, Doris; Wagner, Stephan; Micić, Vesna; Kammer, Frank von der; Hofmann, Thilo, E-mail: thilo.hofmann@univie.ac.at

    2016-09-01

    Submicron-scale milled zerovalent iron (milled ZVI) particles produced by grinding macroscopic raw materials could provide a cost-effective alternative to nanoscale zerovalent iron (nZVI) particles for in situ degradation of chlorinated aliphatic hydrocarbons in groundwater. However, the aggregation and settling of bare milled ZVI particles from suspension presents a significant obstacle to their in situ application for groundwater remediation. In our investigations we reduced the rapid aggregation and settling rate of bare milled ZVI particles from suspension by stabilization with a “green” agar agar polymer. The transport potential of stabilized milled ZVI particle suspensions in a diverse array of natural heterogeneous porous media was evaluated in a series of well-controlled laboratory column experiments. The impact of agar agar on trichloroethene (TCE) removal by milled ZVI particles was assessed in laboratory-scale batch reactors. The use of agar agar significantly enhanced the transport of milled ZVI particles in all of the investigated porous media. Reactivity tests showed that the agar agar-stabilized milled ZVI particles were reactive towards TCE, but that their reactivity was an order of magnitude less than that of bare, non-stabilized milled ZVI particles. Our results suggest that milled ZVI particles could be used as an alternative to nZVI particles as their potential for emplacement into contaminated zone, their reactivity, and expected longevity are beneficial for in situ groundwater remediation. - Highlights: • Rapid aggregation and sedimentation were observed in bare milled ZVI particles. • Agar agar improved the stability of milled ZVI particle suspensions. • Agar agar enhanced the transport of milled ZVI particles in heterogeneous sands. • Agar agar reduced the reactivity of milled ZVI particles towards TCE.

  16. Agar agar-stabilized milled zerovalent iron particles for in situ groundwater remediation

    International Nuclear Information System (INIS)

    Velimirovic, Milica; Schmid, Doris; Wagner, Stephan; Micić, Vesna; Kammer, Frank von der; Hofmann, Thilo

    2016-01-01

    Submicron-scale milled zerovalent iron (milled ZVI) particles produced by grinding macroscopic raw materials could provide a cost-effective alternative to nanoscale zerovalent iron (nZVI) particles for in situ degradation of chlorinated aliphatic hydrocarbons in groundwater. However, the aggregation and settling of bare milled ZVI particles from suspension presents a significant obstacle to their in situ application for groundwater remediation. In our investigations we reduced the rapid aggregation and settling rate of bare milled ZVI particles from suspension by stabilization with a “green” agar agar polymer. The transport potential of stabilized milled ZVI particle suspensions in a diverse array of natural heterogeneous porous media was evaluated in a series of well-controlled laboratory column experiments. The impact of agar agar on trichloroethene (TCE) removal by milled ZVI particles was assessed in laboratory-scale batch reactors. The use of agar agar significantly enhanced the transport of milled ZVI particles in all of the investigated porous media. Reactivity tests showed that the agar agar-stabilized milled ZVI particles were reactive towards TCE, but that their reactivity was an order of magnitude less than that of bare, non-stabilized milled ZVI particles. Our results suggest that milled ZVI particles could be used as an alternative to nZVI particles as their potential for emplacement into contaminated zone, their reactivity, and expected longevity are beneficial for in situ groundwater remediation. - Highlights: • Rapid aggregation and sedimentation were observed in bare milled ZVI particles. • Agar agar improved the stability of milled ZVI particle suspensions. • Agar agar enhanced the transport of milled ZVI particles in heterogeneous sands. • Agar agar reduced the reactivity of milled ZVI particles towards TCE.

  17. Simulant composition for the Mixed Waste Management Facility (MWMF) groundwater remediation project

    International Nuclear Information System (INIS)

    Siler, J.L.

    1992-01-01

    A project has been initiated at the request of ER to study and remediate the groundwater contamination at the Mixed Waste Management Facility (MWMF). This water contains a wide variety of both inorganics (e.g., sodium) and organics (e.g., benzene, trichloroethylene). Most compounds are present in the ppB range, and certain components (e.g., trichloroethylene, silver) are present at concentrations that exceed the primary drinking water standards (PDWS). These compounds must be reduced to acceptable levels as per RCRA and CERCLA orders. This report gives a listing of the important constituents which are to be included in a simulant to model the MWMF aquifer. This simulant will be used to evaluate the feasibility of various state of the art separation/destruction processes for remediating the aquifer

  18. Technologies for remediation of radioactively contaminated sites

    International Nuclear Information System (INIS)

    1999-06-01

    This report presents particulars on environmental restoration technologies (control and treatment) which can be applied to land based, radioactively contaminated sites. The media considered include soils, groundwater, surface water, sediments, air, and terrestrial and aquatic vegetation. The technologies addressed in this report can be categorized as follows: self-attenuation (natural restoration); in-situ treatment; removal of contamination; ex-situ treatment; and transportation and final disposal. The report provides also background information about and a general approach to remediation of radioactively contaminated sites as well as some guidance for the selection of a preferred remediation technology. Examples of remediation experience in Australia and Canada are given it annexes

  19. Technologies for remediation of radioactively contaminated sites

    Energy Technology Data Exchange (ETDEWEB)

    1999-06-01

    This report presents particulars on environmental restoration technologies (control and treatment) which can be applied to land based, radioactively contaminated sites. The media considered include soils, groundwater, surface water, sediments, air, and terrestrial and aquatic vegetation. The technologies addressed in this report can be categorized as follows: self-attenuation (natural restoration); in-situ treatment; removal of contamination; ex-situ treatment; and transportation and final disposal. The report provides also background information about and a general approach to remediation of radioactively contaminated sites as well as some guidance for the selection of a preferred remediation technology. Examples of remediation experience in Australia and Canada are given it annexes Refs, figs, tabs

  20. Numerical modeling analysis of VOC removal processes in different aerobic vertical flow systems for groundwater remediation

    NARCIS (Netherlands)

    De Biase, C.; Carminati, A.; Oswald, S.E.; Thullner, M.

    2013-01-01

    Vertical flow systems filled with porous medium have been shown to efficiently remove volatile organic contaminants (VOCs) from contaminated groundwater. To apply this semi-natural remediation strategy it is however necessary to distinguish between removal due to biodegradation and due to volatile

  1. Using the natural biodegradation potential of shallow soils for in-situ remediation of deep vadose zone and groundwater

    Energy Technology Data Exchange (ETDEWEB)

    Avishai, Lior; Siebner, Hagar; Dahan, Ofer, E-mail: odahan@bgu.ac.il; Ronen, Zeev, E-mail: zeevrone@bgu.ac.il

    2017-02-15

    Highlights: • Integrated in-situ remediation treatment for soil, vadose zone and groundwater. • Turning the topsoil into an efficient bioreactor for perchlorate degradation. • Treating perchlorate leachate from the deep vadose zone in the topsoil. • Zero effluents discharge from the remediation process. - Abstract: In this study, we examined the ability of top soil to degrade perchlorate from infiltrating polluted groundwater under unsaturated conditions. Column experiments designed to simulate typical remediation operation of daily wetting and draining cycles of contaminated water amended with an electron donor. Covering the infiltration area with bentonite ensured anaerobic conditions. The soil remained unsaturated, and redox potential dropped to less than −200 mV. Perchlorate was reduced continuously from ∼1150 mg/L at the inlet to ∼300 mg/L at the outlet in daily cycles. Removal efficiency was between 60 and 84%. No signs of bioclogging were observed during three operation months although occasional iron reduction observed due to excess electron donor. Changes in perchlorate reducing bacteria numbers were inferred from an increased in pcrA gene abundances from ∼10{sup 5} to 10{sup 7} copied per gram at the end of the experiment indicating the growth of perchlorate-reducing bacteria. We proposed that the topsoil may serve as a bioreactor to treat high concentrations of perchlorate from the contaminated groundwater. The treated water that infiltrates from the topsoil through the vadose zone could be used to flush perchlorate from the deep vadose zone into the groundwater where it is retrieved again for treatment in the topsoil.

  2. Using the natural biodegradation potential of shallow soils for in-situ remediation of deep vadose zone and groundwater

    International Nuclear Information System (INIS)

    Avishai, Lior; Siebner, Hagar; Dahan, Ofer; Ronen, Zeev

    2017-01-01

    Highlights: • Integrated in-situ remediation treatment for soil, vadose zone and groundwater. • Turning the topsoil into an efficient bioreactor for perchlorate degradation. • Treating perchlorate leachate from the deep vadose zone in the topsoil. • Zero effluents discharge from the remediation process. - Abstract: In this study, we examined the ability of top soil to degrade perchlorate from infiltrating polluted groundwater under unsaturated conditions. Column experiments designed to simulate typical remediation operation of daily wetting and draining cycles of contaminated water amended with an electron donor. Covering the infiltration area with bentonite ensured anaerobic conditions. The soil remained unsaturated, and redox potential dropped to less than −200 mV. Perchlorate was reduced continuously from ∼1150 mg/L at the inlet to ∼300 mg/L at the outlet in daily cycles. Removal efficiency was between 60 and 84%. No signs of bioclogging were observed during three operation months although occasional iron reduction observed due to excess electron donor. Changes in perchlorate reducing bacteria numbers were inferred from an increased in pcrA gene abundances from ∼10"5 to 10"7 copied per gram at the end of the experiment indicating the growth of perchlorate-reducing bacteria. We proposed that the topsoil may serve as a bioreactor to treat high concentrations of perchlorate from the contaminated groundwater. The treated water that infiltrates from the topsoil through the vadose zone could be used to flush perchlorate from the deep vadose zone into the groundwater where it is retrieved again for treatment in the topsoil.

  3. Feasibility study for remedial action for the groundwater operable units at the chemical plant area and the ordnance works area, Weldon Spring, Missouri

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-07-15

    The U.S. Department of Energy (DOE) and the U.S. Department of Army (DA) are conducting an evaluation to identify the appropriate response action to address groundwater contamination at the Weldon Spring Chemical Plant (WSCP) and the Weldon Spring Ordnance Works (WSOW), respectively. The two areas are located in St. Charles County, about 48 km (30 rni) west of St. Louis. The groundwater operable unit (GWOU) at the WSCP is one of four operable units being evaluated by DOE as part of the Weldon Spring Site Remedial Action Project (WSSRAP). The groundwater operable unit at the WSOW is being evaluated by the DA as Operable Unit 2 (OU2); soil and pipeline contamination are being managed under Operable Unit 1 (OU1). Remedial activities at the WSCP and the WSOW are being conducted in accordance with the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA). Consistent with DOE policy, National Environmental Policy Act (NEPA) values have been incorporated into the CERCLA process. A remedial investigation/feasibility study (RI/FS) work plan summarizing initial site conditions and providing site hydrogeological and exposure models was published in August of 1995 (DOE 1995). The remedial investigation (RI) and baseline risk assessment (BRA) have also recently been completed. The RI (DOE and DA 1998b) discusses in detail the nature, extent, fate, and transport of groundwater and spring water contamination. The BRA (DOE and DA 1998a) is a combined baseline assessment of potential human health and ecological impacts and provides the estimated potential health risks and ecological impacts associated with groundwater and springwater contamination if no remedial action were taken. This feasibility study (FS) has been prepared to evaluate potential options for addressing groundwater contamination at the WSCP and the WSOW. A brief description of the history and environmental setting of the sites is presented in Section 1.1, key information relative to the

  4. Liquid effluent retention facility final-status groundwater monitoring plan

    International Nuclear Information System (INIS)

    Sweeney, M.D.; Chou, C.J.; Bjornstad, B.N.

    1997-09-01

    The following sections describe the groundwater-monitoring program for the Liquid Effluent Retention Facility (LERF). The LERF is regulated under the Resource Conservation and Recovery Act of 1976 (RCRA). The LERF is included in the open-quotes Dangerous Waste Portion of the Resource Conservation and Recovery Act Permit for the Treatment, Storage, and Disposal of Dangerous Waste, Permit WA890008967close quotes, (referred to herein as the Permit) (Ecology 1994) and is subject to final-status requirements for groundwater monitoring (WAC 173-303-645). This document describes a RCRA/WAC groundwater detection-monitoring program for groundwater in the uppermost aquifer system at the LERF. This plan describes the LERF monitoring network, constituent list, sampling schedule, statistical methods, and sampling and analysis protocols that will be employed for the LERF. This plan will be used to meet the groundwater monitoring requirements from the time the LERF becomes part of the Permit and through the post-closure care period, until certification of final closure

  5. Interim action record of decision remedial alternative selection: TNX area groundwater operable unit

    International Nuclear Information System (INIS)

    Palmer, E.R.

    1994-10-01

    This document presents the selected interim remedial action for the TNX Area Groundwater Operable Unit at the Savannah River Site (SRS), which was developed in accordance with CERCLA of 1980, as amended by the Superfund Amendments and Reauthorization Act (SARA) of 1986, and to the extent practicable, the National Oil and Hazardous Substances Pollution contingency Plan (NCP). This decision is based on the Administrative Record File for this specific CERCLA unit

  6. Remedial Process Optimization and Green In-Situ Ozone Sparging for Treatment of Groundwater Impacted with Petroleum Hydrocarbons

    Science.gov (United States)

    Leu, J.

    2012-12-01

    A former natural gas processing station is impacted with TPH and BTEX in groundwater. Air sparging and soil vapor extraction (AS/AVE) remediation systems had previously been operated at the site. Currently, a groundwater extraction and treatment system is operated to remove the chemicals of concern (COC) and contain the groundwater plume from migrating offsite. A remedial process optimization (RPO) was conducted to evaluate the effectiveness of historic and current remedial activities and recommend an approach to optimize the remedial activities. The RPO concluded that both the AS/SVE system and the groundwater extraction system have reached the practical limits of COC mass removal and COC concentration reduction. The RPO recommended an in-situ chemical oxidation (ISCO) study to evaluate the best ISCO oxidant and approach. An ISCO bench test was conducted to evaluate COC removal efficiency and secondary impacts to recommend an application dosage. Ozone was selected among four oxidants based on implementability, effectiveness, safety, and media impacts. The bench test concluded that ozone demand was 8 to 12 mg ozone/mg TPH and secondary groundwater by-products of ISCO include hexavalent chromium and bromate. The pH also increased moderately during ozone sparging and the TDS increased by approximately 20% after 48 hours of ozone treatment. Prior to the ISCO pilot study, a capture zone analysis (CZA) was conducted to ensure containment of the injected oxidant within the existing groundwater extraction system. The CZA was conducted through a groundwater flow modeling using MODFLOW. The model indicated that 85%, 90%, and 95% of an injected oxidant could be captured when a well pair is injecting and extracting at 2, 5, and 10 gallons per minute, respectively. An ISCO pilot test using ozone was conducted to evaluate operation parameters for ozone delivery. The ozone sparging system consisted of an ozone generator capable of delivering 6 lbs/day ozone through two ozone

  7. Hanford sitewide grounwater remediation - supporting technical information

    International Nuclear Information System (INIS)

    Chiaramonte, G.R.

    1996-05-01

    The Hanford Sitewide Groundwater Remediation Strategy was issued in 1995 to establish overall goals for groundwater remediation on the Hanford Site. This strategy is being refined to provide more detailed justification for remediation of specific plumes and to provide a decision process for long-range planning of remediation activities. Supporting this work is a comprehensive modeling study to predict movement of the major site plumes over the next 200 years to help plan the remediation efforts. The information resulting from these studies will be documented in a revision to the Strategy and the Hanford Site Groundwater Protection Management Plan. To support the modeling work and other studies being performed to refine the strategy, this supporting technical information report has been produced to compile all of the relevant technical information collected to date on the Hanford Site groundwater contaminant plumes. The primary information in the report relates to conceptualization of the source terms and available history of groundwater transport, and description of the contaminant plumes. The primary information in the report relates to conceptualization of the source terms and available history of groundwater transport, description of the contaminant plumes, rate of movement based on the conceptual model and monitoring data, risk assessment, treatability study information, and current approach for plume remediation

  8. Grand challenge problems in environmental modeling and remediation: Groundwater contaminant transport. Final project report 1998

    International Nuclear Information System (INIS)

    1998-04-01

    The over-reaching goal of the Groundwater Grand Challenge component of the Partnership in Computational Science (PICS) was to develop and establish the massively parallel approach for the description of groundwater flow and transport and to address the problem of uncertainties in the data and its interpretation. This necessitated the development of innovative algorithms and the implementation of massively parallel computational tools to provide a suite of simulators for groundwater flow and transport in heterogeneous media. This report summarizes the activities and deliverables of the Groundwater Grand Challenge project funded through the High Performance Computing grand challenge program of the Department of Energy from 1995 through 1997

  9. Remediation of BTEX contaminated groundwater: best technology assessment between pump&treat and bioremediation by oxygen injection

    Directory of Open Access Journals (Sweden)

    Daniele Baldi

    2012-06-01

    Full Text Available The presence of benzene, toluene, ethylbenzene and xylene (BTEX dissolved in the groundwater and migrated from a light non-aqueous phase liquid (LNAPL source in an alluvial aquifer required a remedial action to be taken by the responsible party as established by the Italian regulation (Legislative Decree 152/06 and subsequent amendments. For such purpose, field investigations were conducted on site in order to define the site conceptual model and to identify the appropriate remediation technology to be applied. The remediation design was developed by means of a flow and reactive transport mathematical model, applied to saturated media, using the numerical codes MODFLOW and RT3D. Groundwater field observations showed evidence of occurring BTEX biodegradation processes by bacteria naturally present in the aquifer. Since such specific bacterial activity would be significantly enhanced by the injection of free oxygen in the aquifer, the performance of traditional pump and treat systems (P&T was assessed and compared with cost/efficiency of reactive oxygen bio-barrier technology (OD. The results showed a clear advantage in terms of cost/efficiency with the application of the OD. This presents an overall cost of about 30% of the P&T installation and maintenance, and it reaches remedial target in a shorter timeframe. Moreover, the system is also applicable as a bioremediation technology in case of Environmental Emergency Measures (MISE. The site examined is part of an industrial plant located in Central Italy.

  10. Hanford Site Groundwater Monitoring for Fiscal Year 1999

    Energy Technology Data Exchange (ETDEWEB)

    MJ Hartman; LF Morasch; WD Webber

    2000-05-10

    This report presents the results of groundwater and vadose zone monitoring and remediation for fiscal year 1999 on the US. Department of Energy's Hanford Site, Washington. Water-level monitoring was performed to evaluate groundwater flow directions, to track changes in water levels, and to relate such changes to evolving disposal practices. Measurements for site-wide maps were conducted in June in past years and are now measured in March to reflect conditions that are closer to average. Water levels over most of the Hanford Site continued to decline between June 1998 and March 1999. The most widespread radiological contaminant plumes in groundwater were tritium and iodine-129. Concentrations of carbon-14, strontium-90, technetium-99, and uranium also exceeded drinking water standards in smaller plumes. Cesium-137 and plutonium exceeded standards only near the 216-B-5 injection well. Derived concentration guide levels specified in US Department of Energy Order 5400.5 were exceeded for plutonium, strontium-90, tritium, and uranium in small plumes or single wells. Nitrate and carbon tetrachloride are the most extensive chemical contaminants. Chloroform, chromium, cis-1,2dichloroethylene, cyanide, fluoride, and trichloroethylene also were present in smaller areas at levels above their maximum contaminant levels. Metals such as aluminum, cadmium, iron, manganese, and nickel exceeded their maximum contaminant levels in filtered samples from numerous wells; however, in most cases, they are believed to represent natural components of groundwater. ''Resource Conservation and Recovery Act of 1976'' groundwater monitoring continued at 25 waste management areas during fiscal year 1999: 16 under detection programs and data indicate that they are not adversely affecting groundwater; 6 under interim status groundwater quality assessment programs to assess contamination; and 2 under final status corrective-action programs. Another site, the 120-D-1 ponds

  11. 1998 Comprehensive TNX Area Annual Groundwater and Effectiveness Monitoring Report

    Energy Technology Data Exchange (ETDEWEB)

    Chase, J.

    1999-06-02

    Shallow groundwater beneath the TNX Area at the Savannah River Site has been contaminated with chlorinated volatile organic compounds such as trichloroethylene and carbon tetrachloride. The Interim Action T-1 Air Stripper System began operation on September 16, 1996. A comprehensive groundwater monitoring program was initiated to measure the effectiveness of the system. The Interim Action is meeting its objectives and is capable of continuing to do so until the final groundwater remedial action is in place.

  12. A critical review of ferrate(VI)-based remediation of soil and groundwater.

    Science.gov (United States)

    Rai, Prabhat Kumar; Lee, Jechan; Kailasa, Suresh Kumar; Kwon, Eilhann E; Tsang, Yiu Fai; Ok, Yong Sik; Kim, Ki-Hyun

    2018-01-01

    Over the past few decades, diverse chemicals and materials such as mono- and bimetallic nanoparticles, metal oxides, and zeolites have been used for soil and groundwater remediation. Ferrate (Fe VI O 4 2- ) has been widely employed due to its high-valent iron (VI) oxo compound with high oxidation/reduction potentials. Ferrate has received attention for wide environmental applications including water purification and sewage sludge treatment. Ferrate provides great potential for diverse environmental applications without any environmental problems. Therefore, this paper provides comprehensive information on the recent progress on the use of (Fe VI O 4 2- ) as a green material for use in sustainable treatment processes, especially for soil and water remediation. We reviewed diverse synthesis recipes for ferrates (Fe VI O 4 2- ) and their associated physicochemical properties as oxidants, coagulants, and disinfectants for the elimination of a diverse range of chemical and biological species from water/wastewater samples. A summary of the eco-sustainable performance of ferrate(VI) in water remediation is also provided and the future of ferrate(VI) is discussed in this review. Copyright © 2017 Elsevier Inc. All rights reserved.

  13. MULTI-OBJECTIVE OPTIMAL DESIGN OF GROUNDWATER REMEDIATION SYSTEMS: APPLICATION OF THE NICHED PARETO GENETIC ALGORITHM (NPGA). (R826614)

    Science.gov (United States)

    A multiobjective optimization algorithm is applied to a groundwater quality management problem involving remediation by pump-and-treat (PAT). The multiobjective optimization framework uses the niched Pareto genetic algorithm (NPGA) and is applied to simultaneously minimize the...

  14. Least-cost groundwater remediation design using uncertain hydrogeological information. 1998 annual progress report

    International Nuclear Information System (INIS)

    Pinder, G.F.

    1998-01-01

    'The objective of the project is to formulate, test, and evaluate a new approach to the least-cost design of groundwater contamination containment and decontamination systems. The proposed methodology employs robust optimization, the outer-approximation method of non-linear programming, and groundwater flow and transport modeling to find the most cost-effective pump-and-treat design possible given the physical parameters describing the groundwater reservoir are known with uncertainty. The result is a methodology that will provide the least-cost groundwater remediation design possible given a specified set of design objectives and physical and sociological constraints. As of the end of the first year of this 3-year project the author has developed and tested the concept of robust optimization within the framework of least-cost groundwater-contamination-containment design. The outer-approximation method has been employed in this context for the relatively simple linear-constraint case associated with the containment problem. In an effort to enhance the efficiency and applicability of this methodology, a new strategy for selecting the various realizations arising out of the Monte-Carlo underpinnings of the robust-optimization technique has been developed and tested. Based upon observations arising out of this work a yet more promising approach has been discovered. The theoretical foundation for this most recent approach has been, and continues to be, the primary focus of the research.'

  15. Long-Term Groundwater Monitoring Optimization, Clare Water Supply Superfund Site, Permeable Reactive Barrier and Soil Remedy Areas, Clare, Michigan

    Science.gov (United States)

    This report contains a review of the long-term groundwater monitoring network for the Permeable Reactive Barrier (PRB) and Soil Remedy Areas at the Clare Water Supply Superfund Site in Clare, Michigan.

  16. Scientific Opportunity to Reduce Risk in Groundwater and Soil Remediation

    Energy Technology Data Exchange (ETDEWEB)

    Pierce, Eric M.; Freshley, Mark D.; Hubbard, Susan S.; Looney, Brian B.; Zachara, John M.; Liang, Liyuan; Lesmes, D.; Chamberlain, G. M.; Skubal, Karen L.; Adams, V.; Denham, Miles E.; Wellman, Dawn M.

    2009-08-25

    In this report, we start by examining previous efforts at linking science and DOE EM research with cleanup activities. Many of these efforts were initiated by creating science and technology roadmaps. A recurring feature of successfully implementing these roadmaps into EM applied research efforts and successful cleanup is the focus on integration. Such integration takes many forms, ranging from combining information generated by various scientific disciplines, to providing technical expertise to facilitate successful application of novel technology, to bringing the resources and creativity of many to address the common goal of moving EM cleanup forward. Successful projects identify and focus research efforts on addressing the problems and challenges that are causing “failure” in actual cleanup activities. In this way, basic and applied science resources are used strategically to address the particular unknowns that are barriers to cleanup. The brief descriptions of the Office of Science basic (Environmental Remediation Science Program [ERSP]) and EM’s applied (Groundwater and Soil Remediation Program) research programs in subsurface science provide context to the five “crosscutting” themes that have been developed in this strategic planning effort. To address these challenges and opportunities, a tiered systematic approach is proposed that leverages basic science investments with new applied research investments from the DOE Office of Engineering and Technology within the framework of the identified basic science and applied research crosscutting themes. These themes are evident in the initial portfolio of initiatives in the EM groundwater and soil cleanup multi-year program plan. As stated in a companion document for tank waste processing (Bredt et al. 2008), in addition to achieving its mission, DOE EM is experiencing a fundamental shift in philosophy from driving to closure to enabling the long-term needs of DOE and the nation.

  17. Hanford Site Groundwater Monitoring for Fiscal Year 2003

    Energy Technology Data Exchange (ETDEWEB)

    Hartman, Mary J.; Morasch, Launa F.; Webber, William D.

    2004-04-12

    tetrachloride and technetium-99/uranium plumes. ''Resource Conservation and Recovery Act'' groundwater monitoring continued at 24 waste management areas during fiscal year 2003: 15 under interim or final status detection programs and data indicate that they are not adversely affecting groundwater; 7 under interim status groundwater quality assessment programs to assess contamination; and 2 under final status corrective-action programs. During calendar year 2003, drillers completed seven new RCRA monitoring wells, nine wells for CERCLA, and two wells for research on chromate bioremediation. Vadose zone monitoring, characterization, and remediation continued in fiscal year 2003. Remediation and associated monitoring continued at a soil-vapor extraction system in the 200 West Area, which removes gaseous carbon tetrachloride from the vadose zone. Soil vapor also was sampled to locate carbon tetrachloride sites with the potential to impact groundwater in the future. DOE uses geophysical methods to monitor potential movement of contamination beneath single-shell tank farms. During fiscal year 2003, DOE monitored selected boreholes within each of the 12 single-shell tank farms. In general, the contaminated areas appeared to be stable over time. DOE drilled new boreholes at the T Tank Farm to characterize subsurface contamination near former leak sites. The System Assessment Capability is a set of computer modules simulating movement of contaminants from waste sites through the vadose zone and groundwater. In fiscal year 2003, it was updated with the addition of an atmospheric transport module and with newer versions of models including an updated groundwater flow and transport model.

  18. Natural Remediation at Savannah River Site

    International Nuclear Information System (INIS)

    Lewis, C. M.; Van Pelt, R.

    2002-01-01

    Natural remediation is a general term that includes any technology or strategy that takes advantage of natural processes to remediate a contaminated media to a condition that is protective of human health and the environment. Natural remediation techniques are often passive and minimally disruptive to the environment. They are generally implemented in conjunction with traditional remedial solutions for source control (i.e., capping, stabilization, removal, soil vapor extraction, etc.). Natural remediation techniques being employed at Savannah River Site (SRS) include enhanced bio-remediation, monitored natural attenuation, and phytoremediation. Enhanced bio-remediation involves making nutrients available and conditions favorable for microbial growth. With proper precautions and feeding, the naturally existing microbes flourish and consume the contaminants. Case studies of enhanced bio-remediation include surface soils contaminated with PCBs and pesticides, and Volatile Organic Compound (VOC) contamination in both the vadose zone and groundwater. Monitored natural attenuation (MNA) has been selected as the preferred alternative for groundwater clean up at several SRS waste units. Successful implementation of MNA has been based on demonstration that sources have been controlled, groundwater modeling that indicates that plumes will not expand or reach surface water discharge points at levels that exceed regulatory limits, and continued monitoring. Phytoremediation is being successfully utilized at several SRS waste units. Phytoremediation involves using plants and vegetation to uptake, break down, or manage contaminants in groundwater or soils. Case studies at SRS include managing groundwater plumes of tritium and VOCs with pine trees that are native to the area. Significant decreases in tritium discharge to a site stream have been realized in one phytoremediation project. Studies of other vegetation types, methods of application, and other target contaminants are

  19. Progress Toward Cleanup of Operable Unit 1 Groundwater at the US DOE Mound, Ohio, Site: Success of a Phase-Combined Remedy – 15310

    Energy Technology Data Exchange (ETDEWEB)

    Hooten, Gwendolyn [U.S. Department of Energy, Harrison, OH (United States). Office of Legacy Management; Cato, Rebecca [Stoller Newport News Nuclear Inc., Weldon Spring, MS (United States); Looney, Brian [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Huntsman, Brent [Terran Corporation, Beavercreek, OH (United States)

    2015-03-01

    Operable Unit 1 (OU-1) soil and groundwater have been affected by volatile organic compounds (VOC) Present groundwater remedy is collection, treatment, and disposal (pump and treat [P&T]) Several combinations of technologies were used to address soil and groundwater contamination Monitored natural attenuation (MNA) is a viable alternative Majority of source term has been excavated VOC concentrations in groundwater have decreased Attenuation mechanisms have been observed in the subsurface at OU-1

  20. Simulation–optimization model for groundwater contamination ...

    Indian Academy of Sciences (India)

    used techniques for groundwater remediation in which the contaminated groundwater is pumped ... ing the affected groundwater aquifer down to some drinking water standard. Several .... For simplicity, rectangular support domain is used in this study. Figure 1 ..... For PAT remediation system, decision variables include the.

  1. Subsurface Transport Behavior of Micro-Nano Bubbles and Potential Applications for Groundwater Remediation

    Directory of Open Access Journals (Sweden)

    Hengzhen Li

    2013-12-01

    Full Text Available Micro-nano bubbles (MNBs are tiny bubbles with diameters on the order of micrometers and nanometers, showing great potential in environmental remediation. However, the application is only in the beginning stages and remains to be intensively studied. In order to explore the possible use of MNBs in groundwater contaminant removal, this study focuses on the transport of MNBs in porous media and dissolution processes. The bubble diameter distribution was obtained under different conditions by a laser particle analyzer. The permeability of MNB water through sand was compared with that of air-free water. Moreover, the mass transfer features of dissolved oxygen in water with MNBs were studied. The results show that the bubble diameter distribution is influenced by the surfactant concentration in the water. The existence of MNBs in pore water has no impact on the hydraulic conductivity of sand. Furthermore, the dissolved oxygen (DO in water is greatly increased by the MNBs, which will predictably improve the aerobic bioremediation of groundwater. The results are meaningful and instructive in the further study of MNB research and applications in groundwater bioremediation.

  2. Proceedings of the remediation technologies symposium 2007

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2007-07-01

    This conference provided a forum to discuss the remediation of contaminated sites. It was attended by all industry sectors that have an interest in learning about technical issues in environmental remediation research and the latest innovations in soil and groundwater remediation and industrial pollutant treatments. Cost effective in-situ and ex-situ soil reclamation strategies were presented along with groundwater and surface water remediation strategies. The diversified sessions at this conference were entitled: regulatory update; Montreal Centre of Excellence in Brownfields Rehabilitation; soil and groundwater remediation through the Program of Energy Research and Development at Environment Canada; technology from the Netherlands; bioremediation; hydrocarbons; in-situ remediation; phytoremediation; salt management; unique locations; and, miscellaneous issues. Some areas and case studies covered in the presentations included: biological and non-biological treatments; thermal desorption; encapsulation; natural attenuation; multi-phase extraction; electrochemical remediation; and membrane technology. The conference featured 63 presentations, of which 23 have been catalogued separately for inclusion in this database. tabs., figs.

  3. Proceedings of the remediation technologies symposium 2007

    International Nuclear Information System (INIS)

    2007-01-01

    This conference provided a forum to discuss the remediation of contaminated sites. It was attended by all industry sectors that have an interest in learning about technical issues in environmental remediation research and the latest innovations in soil and groundwater remediation and industrial pollutant treatments. Cost effective in-situ and ex-situ soil reclamation strategies were presented along with groundwater and surface water remediation strategies. The diversified sessions at this conference were entitled: regulatory update; Montreal Centre of Excellence in Brownfields Rehabilitation; soil and groundwater remediation through the Program of Energy Research and Development at Environment Canada; technology from the Netherlands; bioremediation; hydrocarbons; in-situ remediation; phytoremediation; salt management; unique locations; and, miscellaneous issues. Some areas and case studies covered in the presentations included: biological and non-biological treatments; thermal desorption; encapsulation; natural attenuation; multi-phase extraction; electrochemical remediation; and membrane technology. The conference featured 63 presentations, of which 23 have been catalogued separately for inclusion in this database. tabs., figs

  4. Application of Biostimulation for Remediation of Sulfate-Contaminated Groundwater at a Mining Site

    Science.gov (United States)

    Miao, Z.; Carroll, K. C.; Carreon, C.; Brusseau, M. L.

    2011-12-01

    There is growing concern regarding sulfate contamination of groundwater. One innovative in-situ remediation option under investigation is biostimulation through addition of electron-donor amendments to enhance sulfate reduction. Two pilot-scale ethanol-injection tests were conducted at a former uranium mining site that is contaminated with sulfate and nitrate (with a lack of heavy metals), and for which there appears to be minimal natural attenuation of sulfate. The first test was a push-pull test that had a limited zone of influence, while the second test was a single-well injection test in which additional downgradient wells were monitored. For both tests, sulfate concentrations began to decline within a few weeks of injection, after nitrate concentrations were significantly reduced. Concomitantly, aqueous concentrations of manganese, iron, and hydrogen sulfide increased from background. Monitoring over many months revealed that the declines in sulfate concentration conformed to exponential decay, with first-order decay rates of approximately 0.01 /d. Analysis of sulfur stable isotope data indicated that the decrease in sulfate concentrations was microbially mediated. The results also indicated that sulfides formed during sulfate reduction may have undergone partial re-oxidation. This study illustrates the feasibility of using ethanol injection for remediation of sulfate-contaminated groundwater. However, re-oxidation of sulfides (both metal sulfide precipitates and hydrogen sulfide gas) is a potential issue of significance that would need to be addressed.

  5. GASReP/DESRT: Proceedings [of the] 2nd annual symposium on groundwater and soil remediation. Comptes rendus [de la] 2e symposium annuel sur la restauration des eaux souterraines et des sois contamines

    Energy Technology Data Exchange (ETDEWEB)

    1992-01-01

    A conference was held to discuss ground water and soil remediation with emphasis on the Canadian national Groundwater and Soil Remediation Program (GASReP) and the Development and Demonstration of Site Remediation Technology (DESRT) program. Papers were presented on the subjects of groundwater and soil remediation research projects, bioremediation, excavation and treatment, pumping and treatment/soil venting, and industry and government initiatives. Separate abstracts have been prepared for 15 papers from the conference.

  6. Remedial investigation work plan for the Groundwater Operable Unit at Oak Ridge National Laboratory, Oak Ridge, Tennessee

    Energy Technology Data Exchange (ETDEWEB)

    1994-03-01

    This Remedial Investigation (RI) Work Plan has been developed as part of the US Department of Energy`s (DOE`s) investigation of the Groundwater Operable Unit (GWOU) at Oak Ridge National Laboratory (ORNL) located near Oak Ridge, Tennessee. The first iteration of the GWOU RI Work Plan is intended to serve as a strategy document to guide the ORNL GWOU RI. The Work Plan provides a rationale and organization for groundwater data acquisition, monitoring, and remedial actions to be performed during implementation of environmental restoration activities associated with the ORNL GWOU. It Is important to note that the RI Work Plan for the ORNL GWOU is not a prototypical work plan. The RI will be conducted using annual work plans to manage the work activities, and task reports will be used to document the results of the investigations. Sampling and analysis results will be compiled and reported annually with a review of data relative to risk (screening level risk assessment review) for groundwater. This Work Plan outlines the overall strategy for the RI and defines tasks which are to be conducted during the initial phase of investigation. This plan is presented with the understanding that more specific addenda to the plan will follow.

  7. Remedial investigation work plan for the Groundwater Operable Unit at Oak Ridge National Laboratory, Oak Ridge, Tennessee

    International Nuclear Information System (INIS)

    1994-03-01

    This Remedial Investigation (RI) Work Plan has been developed as part of the US Department of Energy's (DOE's) investigation of the Groundwater Operable Unit (GWOU) at Oak Ridge National Laboratory (ORNL) located near Oak Ridge, Tennessee. The first iteration of the GWOU RI Work Plan is intended to serve as a strategy document to guide the ORNL GWOU RI. The Work Plan provides a rationale and organization for groundwater data acquisition, monitoring, and remedial actions to be performed during implementation of environmental restoration activities associated with the ORNL GWOU. It Is important to note that the RI Work Plan for the ORNL GWOU is not a prototypical work plan. The RI will be conducted using annual work plans to manage the work activities, and task reports will be used to document the results of the investigations. Sampling and analysis results will be compiled and reported annually with a review of data relative to risk (screening level risk assessment review) for groundwater. This Work Plan outlines the overall strategy for the RI and defines tasks which are to be conducted during the initial phase of investigation. This plan is presented with the understanding that more specific addenda to the plan will follow

  8. LCA of Soil and Groundwater Remediation

    DEFF Research Database (Denmark)

    Søndergaard, Gitte Lemming; Owsianiak, Mikolaj

    2018-01-01

    Today, there is increasing interest in applying LCA to support decision-makers in contaminated site management. In this chapter, we introduce remediation technologies and associated environmental impacts, present an overview of literature findings on LCA applied to remediation technologies...... and present methodological issues to consider when conducting LCAs within the area. Within the field of contaminated site remediation , a terminology distinguishing three types of environmental impacts: primary, secondary and tertiary, is often applied. Primary impacts are the site-related impacts due...... and efficiency of remediation, which are important for assessment or primary impacts; (ii) robust assessment of primary impacts using site-specific fate and exposure models; (iii) weighting of primary and secondary (or tertiary) impacts to evaluate trade-offs between life cycle impacts from remediation...

  9. The nanotoxicology of a newly developed zero-valent iron nanomaterial for groundwater remediation and its remediation efficiency assessment combined with in vitro bioassays for detection of dioxin-like environmental pollutants

    OpenAIRE

    Schiwy, Andreas Herbert

    2016-01-01

    The assessment of chemicals and new compounds is an important task of ecotoxicology. In this thesis a newly developed zero-valent iron material for nanoremediation of groundwater contaminations was investigated and in vitro bioassays for high throughput screening were developed. These two elements of the thesis were combined to assess the remediation efficiency of the nanomaterial on the groundwater contaminant acridine. The developed in vitro bioassays were evaluated for quantification of th...

  10. Use of a permeable biological reaction barrier for groundwater remediation at a uranium mill tailings remedial action (UMTRA) site

    International Nuclear Information System (INIS)

    Thombre, M.S.; Thomson, B.M.; Barton, L.L.

    1997-01-01

    Previous work at the University of New Mexico and elsewhere has shown that sulfate reducing bacteria are capable of reducing uranium from the soluble +6 oxidation state to the insoluble +4 oxidation state. This chemistry forms the basis of a proposed groundwater remediation strategy in which microbial reduction would be used to immobilize soluble uranium. One such system would consist of a subsurface permeable barrier which would stimulate microbial growth resulting in the reduction of sulfate and nitrate and immobilization of metals while permitting the unhindered flow of ground water through it. This research investigated some of the engineering considerations associated with a microbial reducing barrier such as identifying an appropriate biological substrate, estimating the rate of substrate utilization, and identifying the final fate of the contaminants concentrated in the barrier matrix. The performance of batch reactors and column systems that treated simulated plume water was evaluated using cellulose, wheat straw, alfalfa hay, sawdust, and soluble starch as substrates. The concentrations of sulfate, nitrate, and U(VI) were monitored over time. Precipitates from each system were collected and the precipitated U(IV) was determined to be crystalline UO 2 (s) by X-ray Diffraction. The results of this study support the proposed use of cellulosic substrates as candidate barrier materials

  11. Dynamic optimal control of groundwater remediation with management periods: Linearized and quasi-Newton approaches

    International Nuclear Information System (INIS)

    Culver, T.B.

    1991-01-01

    Several modifications of the linear-quadratic regulator (LQR) optimization algorithm are developed, and the computational efficiency of each algorithm with respect to groundwater remediation is evaluated. In each case, the optimization model is combined with a finite element groundwater flow and transport simulation model to determine the optimal time-varying pump-and-treat policy. The first modification of the LQR algorithm incorporated management periods, which are groups of simulation time steps during which the pumping policy remains constant. Management periods reduced the total computational demand, as measured by the CPU time, by as much as 85% compared to the time needed for the LQR solution without management periods. Complexity analysis revealed that computational savings of equal or greater magnitude can be expected in general for groundwater remediation applications and for many other applications of dynamic control. The LQR algorithm with management periods was further modified by assuming steady-state hydraulics within a management period (SSLQR), which simplifies the derivatives of the transition equation. A quasi-Newton differential dynamic programming (QNDDP) was formulated by approximating the complicated second derivatives of the transition equation using a Broyden rank-one approximation. QNDDP converged to the optimal policy for the test problem significantly faster than the LQR algorithm, requiring approximately half the computational time. With the test problem expanded to include the capacity of the treatment facility as a state variable, QNDDP with management periods can determine the optimal treatment facility capacity. With many management periods, the addition of the capital costs of the treatment facility changed the optimal policy so that the required treatment facility capacity was reduced

  12. IAEA Remediation Mission Issues Final Report

    International Nuclear Information System (INIS)

    2011-01-01

    Full text: A team of international experts today completed their assessment of the strategy and plans being considered by the Japanese authorities to remediate the areas off-site TEPCO's Fukushima Daiichi Nuclear Power Plant (NPP). Their Final Report, delivered to the Japanese authorities, is available here. ''A lot of good work, done at all levels, is on-going in Japan in the area of environmental remediation,'' said Juan Carlos Lentijo, Team Leader and General Director for Radiation Protection at Spain's nuclear regulatory authority. In the report, Japan is encouraged to continue its remediation efforts, taking into account the advice provided by the Mission. ''In the early phases of the Fukushima Daiichi accident, a very cautious approach was adopted by the Japanese authorities in terms of dealing with the handling of residue materials. It is considered right to do so,'' Lentijo said. ''However, at this point in time, we see that there is room to take a more balanced approach, focussing on the real priority areas, classifying residue materials and adopting appropriate remediation measures on the basis of the results of safety assessments for each specific situation.'' The IAEA stands ready to support Japan as it continues its efforts to remediate the environment in the area off-site the Fukushima Daiichi NPP. The IAEA sent the mission to Japan from 7 to 15 October 2011 following a request from the country's government. The mission, comprising 12 international and IAEA experts from several countries, visited numerous locations in the Fukushima Prefecture and conducted meetings in Tokyo and Fukushima with Japanese officials from several ministries and institutions. A Preliminary Summary Report was issued on 14 October. Background The accident at the Fukushima Daiichi NPP has led to elevated levels of radiation over large areas. The Government of Japan has been formulating a strategy and plans to implement countermeasures to remediate these areas. The IAEA

  13. Integrated remediation of soil and groundwater

    International Nuclear Information System (INIS)

    Dykes, R.S.; Howles, A.C.

    1992-01-01

    Remediation of sites contaminated with petroleum hydrocarbons and other organic chemicals frequently focuses on a single phase of the chemical in question. This paper describes an integrated approach to remediation involving selection of complimentary technologies designed to create a remedial system which achieves cleanup goals in affected media in the shortest possible time consistent with overall environmental protection

  14. Unintentional contaminant transfer from groundwater to the vadose zone during source zone remediation of volatile organic compounds.

    Science.gov (United States)

    Chong, Andrea D; Mayer, K Ulrich

    2017-09-01

    Historical heavy use of chlorinated solvents in conjunction with improper disposal practices and accidental releases has resulted in widespread contamination of soils and groundwater in North America and worldwide. As a result, remediation of chlorinated solvents is required at many sites. For source zone treatment, common remediation strategies include in-situ chemical oxidation (ISCO) using potassium or sodium permanganate, and the enhancement of biodegradation by primary substrate addition. It is well known that these remediation methods tend to generate gas (carbon dioxide (CO 2 ) in the case of ISCO using permanganate, CO 2 and methane (CH 4 ) in the case of bioremediation). Vigorous gas generation in the presence of chlorinated solvents, which are categorized as volatile organic contaminants (VOCs), may cause gas exsolution, ebullition and stripping of the contaminants from the treatment zone. This process may lead to unintentional 'compartment transfer', whereby VOCs are transported away from the contaminated zone into overlying clean sediments and into the vadose zone. To this extent, benchtop column experiments were conducted to quantify the effect of gas generation during remediation of the common chlorinated solvent trichloroethylene (TCE/C 2 Cl 3 H). Both ISCO and enhanced bioremediation were considered as treatment methods. Results show that gas exsolution and ebullition occurs for both remediation technologies. Facilitated by ebullition, TCE was transported from the source zone into overlying clean groundwater and was subsequently released into the column headspace. For the case of enhanced bioremediation, the intermediate degradation product vinyl chloride (VC) was also stripped from the treatment zone. The concentrations measured in the headspace of the columns (TCE ∼300ppm in the ISCO column, TCE ∼500ppm and VC ∼1380ppm in the bioremediation column) indicate that substantial transfer of VOCs to the vadose zone is possible. These findings

  15. Sanitary landfill in situ bioremediation optimization test. Final report

    International Nuclear Information System (INIS)

    1996-01-01

    This work was performed as part of a corrective action plan for the Savannah River Site Sanitary Landfill. This work was performed for the Westinghouse Savannah River Company Environmental Restoration Department as part of final implementation of a groundwater remediation system for the SRS Sanitary Landfill. Primary regulatory surveillance was provided by the South Carolina Department of Health and Environmental Control and the US Environmental Protection Agency (Region IV). The characterization, monitoring and remediation systems in the program generally consisted of a combination of innovative and baseline methods to allow comparison and evaluation. The results of these studies will be used to provide input for the full-scale groundwater remediation system for the SRS Sanitary Landfill. This report summarizes the performance of the Sanitary Landfill In Situ Optimization Test data, an evaluation of applicability, conclusions, recommendations, and related information for implementation of this remediation technology at the SRS Sanitary Landfill

  16. Innovative technology for expedited site remediation of extensive surface and subsurface contamination

    International Nuclear Information System (INIS)

    Audibert, J.M.E.; Lew, L.R.

    1994-01-01

    Large scale surface and subsurface contamination resulted from numerous releases of feed stock, process streams, waste streams, and final product at a major chemical plant. Soil and groundwater was contaminated by numerous compounds including lead, tetraethyl lead, ethylene dibromide, ethylene dichloride, and toluene. The state administrative order dictated that the site be investigated fully, that remedial alternative be evaluated, and that the site be remediated within a year period. Because of the acute toxicity and extreme volatility of tetraethyl lead and other organic compounds present at the site and the short time frame ordered by the regulators, innovative approaches were needed to carry out the remediation while protecting plant workers, remediation workers, and the public

  17. Risk-Based Management of Contaminated Groundwater: The Role of Geologic Heterogeneity, Exposure and Cancer Risk in Determining the Performance of Aquifer Remediation

    International Nuclear Information System (INIS)

    Maxwell, R.M.; Carle, S.F.; Tompson, A.F.B.

    2000-01-01

    The effectiveness of aquifer remediation is typically expressed in terms of a reduction in contaminant concentrations relative to a regulated maximum contaminant level (MCL), and is usually confined by sparse monitoring data and/or simple model calculations. Here, the effectiveness of remediation is examined from a risk-based perspective that goes beyond the traditional MCL concept. A methodology is employed to evaluate the health risk to individuals exposed to contaminated household water that is produced from groundwater. This approach explicitly accounts for differences in risk arising from variability in individual physiology and water use, the uncertainty in estimating chemical carcinogenesis for different individuals, and the uncertainties and variability in contaminant concentrations within groundwater. A hypothetical contamination scenario is developed as a case study in a saturated, alluvial aquifer underlying a real Superfund site. A baseline (unremediated) human exposure and health risk scenario, as induced by contaminated groundwater pumped from this site, is predicted and compared with a similar estimate based upon pump-and-treat exposure intervention. The predicted reduction in risk in the remediation scenario is not an equitable one-that is, it is not uniform to all individuals within a population and varies according to the level of uncertainty in prediction. The importance of understanding the detailed hydrogeologic connections that are established in the heterogeneous geologic regime between the contaminated source, municipal receptors, and remediation wells, and its relationship to this uncertainty is demonstrated. Using two alternative pumping rates, we develop cost-benefit curves based upon reduced exposure and risk to different individuals within the population, under the presence of uncertainty

  18. Feasibility study for remedial action for the groundwater operable units at the chemical plant area and the ordnance works area at the Weldon Spring Site, Weldon Spring, Missouri

    International Nuclear Information System (INIS)

    1999-01-01

    The U.S. Department of Energy (DOE) and the U.S. Department of Army (DA) are conducting an evaluation to identify the appropriate response action to address groundwater contamination at the Weldon Spring Chemical Plant (WSCP) and the Weldon Spring Ordnance Works (WSOW), respectively. The two areas are located in St. Charles County, about 48 km (30 rni) west of St. Louis. The groundwater operable unit (GWOU) at the WSCP is one of four operable units being evaluated by DOE as part of the Weldon Spring Site Remedial Action Project (WSSRAP). The groundwater operable unit at the WSOW is being evaluated by the DA as Operable Unit 2 (OU2); soil and pipeline contamination are being managed under Operable Unit 1 (OU1). Remedial activities at the WSCP and the WSOW are being conducted in accordance with the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA). Consistent with DOE policy, National Environmental Policy Act (NEPA) values have been incorporated into the CERCLA process. A remedial investigation/feasibility study (RI/FS) work plan summarizing initial site conditions and providing site hydrogeological and exposure models was published in August of 1995 (DOE 1995). The remedial investigation (RI) and baseline risk assessment (BRA) have also recently been completed. The RI (DOE and DA 1998b) discusses in detail the nature, extent, fate, and transport of groundwater and spring water contamination. The BRA (DOE and DA 1998a) is a combined baseline assessment of potential human health and ecological impacts and provides the estimated potential health risks and ecological impacts associated with groundwater and springwater contamination if no remedial action were taken. This feasibility study (FS) has been prepared to evaluate potential options for addressing groundwater contamination at the WSCP and the WSOW. A brief description of the history and environmental setting of the sites is presented in Section 1.1, key information relative to the

  19. Surface and subsurface cleanup protocol for radionuclides, Gunnison, Colorado, UMTRA project processing site: Final

    International Nuclear Information System (INIS)

    1994-01-01

    Thorium 230 (Th-230) at the Gunnison, Colorado processing site will require remediation, however, a seasonally fluctuating groundwater table at the site significantly complicates conventional remedial action with respect to cleanup. Therefore, to effectively remediate the site with respect to Radium 226 (Ra-226) and Th-230, the following supplemental standard is proposed: In situ Ra-26 will be remediated to the EPA soil cleanup standards independent of groundwater considerations. In situ Th-230 concentrations will be remediated in the region above the encountered water table so the 1000-year projected Ra-226 concentration complies with the EPA soil cleanup concentration limits. If elevated Th-230 persists to the water table, an additional foot of excavation will be performed and the grid will be backfilled. Excavated grids will be backfilled to the final remedial action grade with clean cobbly soil. Final grid verification that is required below the water table will be performed by extracting and analyzing a single bulk soil sample with the bucket of a backhoe. Modeled surface radon flux values will be estimated and documented. A recommendation will be made that land records should be annotated to identify the presence of residual Th-230

  20. Biochar- and phosphate-induced immobilization of heavy metals in contaminated soil and water: implication on simultaneous remediation of contaminated soil and groundwater.

    Science.gov (United States)

    Liang, Yuan; Cao, Xinde; Zhao, Ling; Arellano, Eduardo

    2014-03-01

    Long-term wastewater irrigation or solid waste disposal has resulted in the heavy metal contamination in both soil and groundwater. It is often separately implemented for remediation of contaminated soil or groundwater at a specific site. The main objective of this study was to demonstrate the hypothesis of simultaneous remediation of both heavy metal contaminated soil and groundwater by integrating the chemical immobilization and pump-and-treat methods. To accomplish the objective, three experiments were conducted, i.e., an incubation experiment was first conducted to determine how dairy-manure-derived biochar and phosphate rock tailing induced immobilization of Cd in the Cd-contaminated soils; second, a batch sorption experiment was carried out to determine whether the pre-amended contaminated soil still had the ability to retain Pb, Zn and Cd from aqueous solution. BCR sequential extraction as well as XRD and SEM analysis were conducted to explore the possible retention mechanism; and last, a laboratory-scale model test was undertaken by leaching the Pb, Zn, and Cd contaminated groundwater through the pre-amended contaminated soils to demonstrate how the heavy metals in both contaminated soil and groundwater were simultaneously retained and immobilized. The incubation experiment showed that the phosphate biochar were effective in immobilizing soil Cd with Cd concentration in TCLP (toxicity characteristics leaching procedure) extract reduced by 19.6 % and 13.7 %, respectively. The batch sorption experiment revealed that the pre-amended soil still had ability to retain Pb, Zn, and Cd from aqueous solution. The phosphate-induced metal retention was mainly due to the metal-phosphate precipitation, while both sorption and precipitation were responsible for the metal stabilization in the biochar amendment. The laboratory-scale test demonstrated that the soil amended with phosphate removed groundwater Pb, Zn, and Cd by 96.4 %, 44.6 %, and 49.2 %, respectively, and the

  1. Proceedings of the remediation technologies symposium 2006

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2006-07-01

    This conference provided an opportunity for industry, practitioners, researchers and regulators to discuss technical issues in environmental remediation research and the latest innovations in soil and groundwater remediation. Cost effective in-situ and ex-situ soil reclamation strategies were presented along with groundwater and surface water remediation strategies in 13 sessions entitled: hydrocarbon contamination; salt management; liability management; chemical oxidation; light non-aqueous phase liquids (LNAPL); Montreal Center of Excellence in Brownfields Rehabilitation; Alberta government updates; phytoremediation; natural attenuation; Lake Wabamun; ex-situ remediation; in-situ remediation; and, miscellaneous issues. Technological solutions for erosion control and water clarification were highlighted. The conference featured 52 presentations, of which 17 have been catalogued separately for inclusion in this database. tabs., figs.

  2. REMOVAL OF ADDED NITRATE IN COTTON BURR COMPOST, MULCH COMPOST, AND PEAT: MECHANISMS AND POTENTIAL USE FOR GROUNDWATER NITRATE REMEDIATION

    Science.gov (United States)

    We conducted batch tests on the nature and kinetics of removal of added nitrate in cotton burr compost, mulch compost, and sphagnum peat that may be potentially used in a permeable reactive barrier (PRB) for groundwater nitrate remediation. A rigorous steam autoclaving protocol (...

  3. In situ remediation of chlorinated solvent-contaminated groundwater using ZVI/organic carbon amendment in China: field pilot test and full-scale application.

    Science.gov (United States)

    Yang, Jie; Meng, Liang; Guo, Lin

    2018-02-01

    Chlorinated solvents in groundwater pose threats to human health and the environment due to their carcinogenesis and bioaccumulation. These problems are often more severe in developing countries such as China. Thus, methods for chlorinated solvent-contaminated groundwater remediation are urgently needed. This study presents a technique of in situ remediation via the direct-push amendment injection that enhances the reductive dechlorination of chlorinated solvents in groundwater in the low-permeability aquifer. A field-based pilot test and a following real-world, full-scale application were conducted at an active manufacturing facility in Shanghai, China. The chlorinated solvents found at the clay till site included 1,1,1-trichloroethane (1,1,1-TCA), 1,1-dichloroethane (1,1-DCA), 1,1-dichloroethylene (1,1-DCE), vinyl chloride (VC), and chloroethane (CA). A commercially available amendment (EHC ® , Peroxychem, Philadelphia, PA) combining zero-valent iron and organic carbon was used to treat the above pollutants. Pilot test results showed that direct-push EHC injection efficiently facilitated the in situ reductive remediation of groundwater contaminated with chlorinated solvents. The mean removal rates of 1,1,1-TCA, 1,1-DCA, and 1,1-DCE at 270 days post-injection were 99.6, 99.3, and 73.3%, respectively, which were obviously higher than those of VC and CA (42.3 and 37.1%, respectively). Clear decreases in oxidation-reduction potential and dissolved oxygen concentration, and increases in Fe 2+ and total organic carbon concentration, were also observed during the monitoring period. These indicate that EHC promotes the anaerobic degradation of chlorinated hydrocarbons primarily via long-term biological reductive dechlorination, with instant chemical reductive dechlorination acting as a secondary pathway. The optimal effective time of EHC injection was 0-90 days, and its radius of influence was 1.5 m. In full-scale application, the maximum concentrations of 1,1,1-TCA

  4. Cellulose nanocrystal zero-valent iron nanocomposites for groundwater remediation†

    Science.gov (United States)

    Bossa, Nathan; Carpenter, Alexis Wells; Kumar, Naresh; de Lannoy, Charles-François

    2018-01-01

    Zero-valent iron nanoparticles (nano-ZVIs) have been widely studied for in situ remediation of groundwater and other environmental matrices. Nano-ZVI particle mobility and reactivity are still the main impediments in achieving efficient in situ groundwater remediation. Compared to the nano-ZVI “coating” strategy, nano-ZVI stabilization on supporting material allows direct contact with the contaminant, reduces the electron path from the nano-ZVI to the target contaminant and increases nano-ZVI reactivity. Herein, we report the synthesis of nano-ZVI stabilized by cellulose nanocrystal (CNC) rigid nanomaterials (CNC-nano-ZVI; Fe/CNC = 1 w/w) with two different CNC functional surfaces (–OH and –COOH) using a classic sodium borohydride synthesis pathway. The final nanocomposites were thoroughly characterized and the reactivity of CNC-nano-ZVIs was assessed by their methyl orange (MO) dye degradation potential. The mobility of nanocomposites was determined in (sand/glass bead) porous media by utilizing a series of flowthrough transport column experiments. The synthesized CNC-nano-ZVI provided a stable colloidal suspension and demonstrated high mobility in porous media with an attachment efficiency (α) value of less than 0.23. In addition, reactivity toward MO increased up to 25% compared to bare ZVI. The use of CNC as a delivery vehicle shows promising potential to further improve the capability and applicability of nano-ZVI for in situ groundwater remediation and can spur advancements in CNC-based nanocomposites for their application in environmental remediation. PMID:29725541

  5. Full-scale testing and early production results from horizontal air sparging and soil vapor extraction wells remediating jet fuel in soil and groundwater at JFK International Airport, New York

    International Nuclear Information System (INIS)

    Roth, R.J.; Bianco, P.; Pressly, N.C.

    1996-01-01

    Jet fuel contaminated soil and groundwater contaminated at the International Arrivals Building (IAB) of the JFK International Airport in Jamaica, New York, are being remediated using soil vapor extraction (SVE) and air sparging (AS). The areal extent of the contaminated soil is estimated to be 70 acres and the volume of contaminated groundwater is estimated to be 2.3 million gallons. The remediation uses approximately 13,000 feet of horizontal SVE (HSVE) wells and 7,000 feet of horizontal AS (HAS) wells. The design of the HSVE and HAS wells was based on a pilot study followed by a full-scale test. In addition to the horizontal wells, 28 vertical AS wells and 15 vertical SVE wells are used. Three areas are being remediated, thus, three separate treatment systems have been installed. The SVE and AS wells are operated continuously while groundwater will be intermittently extracted at each HAS well, treated by liquid phase activated carbon and discharged into stormwater collection sewerage. Vapors extracted by the SVE wells are treated by vapor phase activated carbon and discharged into ambient air. The duration of the remediation is anticipated to be between two and three years before soil and groundwater are remediated to New York State cleanup criteria for the site. Based on the monitoring data for the first two months of operation, approximately 14,600 lbs. of vapor phase VOCs have been extracted. Analyses show that the majority of the VOCs are branched alkanes, branched alkenes, cyclohexane and methylated cyclohexanes

  6. Final Hazard Categorization for the Remediation of the 116-C-3 Chemical Waste Tanks

    Energy Technology Data Exchange (ETDEWEB)

    T. M. Blakley; W. D. Schofield

    2007-09-10

    This final hazard categorization (FHC) document examines the hazards, identifies appropriate controls to manage the hazards, and documents the commitments for the 116-C-3 Chemical Waste Tanks Remediation Project. The remediation activities analyzed in this FHC are based on recommended treatment and disposal alternatives described in the Engineering Evaluation for the Remediation to the 116-C-3 Chemical Waste Tanks (BHI 2005e).

  7. Permanganate gel (PG) for groundwater remediation: compatibility, gelation, and release characteristics.

    Science.gov (United States)

    Lee, Eung Seok; Olson, Pamela R; Gupta, Neha; Solpuker, Utku; Schwartz, Franklin W; Kim, Yongje

    2014-02-01

    Permanganate (MnO4(-)) is a strong oxidant that is widely used for treating chlorinated ethylenes in groundwater. This study aims to develop hyper-saline MnO4(-) solution (MnO4(-) gel; PG) that can be injected into aquifers via wells, slowly gelates over time, and slowly release MnO4(-) to flowing water. In this study, compatibility and miscibility of gels, such as chitosan, aluminosilicate, silicate, and colloidal silica gels, with MnO4(-) were tested. Of these gels, chitosan was reactive with MnO4(-). Aluminosilicates were compatible but not readily miscible with MnO4(-). Silicates and colloidal silica were both compatible and miscible with MnO4(-), and gelated with addition of KMnO4 granules. Colloidal silica has low initial viscosity (<15cP), exhibited delayed gelation characteristics with the lag times ranging from 0 to 200min. Release of MnO4(-) from the colloidal silica-based PG gel occurred in a delayed fashion, with maximum duration of 24h. These results suggested that colloidal silica can be used to create PG or delayed-gelling forms containing other oxidants which can be used for groundwater remediation. Copyright © 2013 Elsevier Ltd. All rights reserved.

  8. Remediation of the Highland Drive South Ravine, Port Hope, Ontario: Contaminated Groundwater Discharge Management Using Permeable Reactive Barriers and Contaminated Sediment Removal - 13447

    Energy Technology Data Exchange (ETDEWEB)

    Smyth, David; Roos, Gillian [Golder Associates Ltd., 2390 Argentia Road, Mississauga, ON L5N 5Z7 (Canada); Ferguson Jones, Andrea [MMM Group Ltd., 100 Commerce Valley Drive West, Thornhill, ON L3T 0A1 (Canada); Case, Glenn [AECL Port Hope Area Initiative Management Office, 115 Toronto Road, Port Hope, ON L1A 3S4 (Canada); Yule, Adam [Public Works and Government Services Canada, 4900 Yonge Street, 11th Floor, Toronto, ON, M2N 6A6 (Canada)

    2013-07-01

    The Highland Drive South Ravine (HDSR) is the discharge area for groundwater originating from the Highland Drive Landfill, the Pine Street North Extension (PSNE) roadbed parts of the Highland Drive roadbed and the PSNE Consolidation Site that contain historical low-level radioactive waste (LLRW). The contaminant plume from these LLRW sites contains elevated concentrations of uranium and arsenic and discharges with groundwater to shallow soils in a wet discharge area within the ravine, and directly to Hunt's Pond and Highland Drive South Creek, which are immediately to the south of the wet discharge area. Remediation and environmental management plans for HDSR have been developed within the framework of the Port Hope Project and the Port Hope Area Initiative. The LLRW sites will be fully remediated by excavation and relocation to a new Long-Term Waste Management Facility (LTWMF) as part of the Port Hope Project. It is projected, however, that the groundwater contaminant plume between the remediated LLRW sites and HDSR will persist for several hundreds of years. At the HDSR, sediment remediation within Hunt's Ponds and Highland Drive South Creek, excavation of the existing and placement of clean fill will be undertaken to remove current accumulations of solid-phase uranium and arsenic associated with the upper 0.75 m of soil in the wet discharge area, and permeable reactive barriers (PRBs) will be used for in situ treatment of contaminated groundwater to prevent the ongoing discharge of uranium and arsenic to the area in HDSR where shallow soil excavation and replacement has been undertaken. Bench-scale testing using groundwater from HDSR has confirmed excellent treatment characteristics for both uranium and arsenic using permeable reactive mixtures containing granular zero-valent iron (ZVI). A sequence of three PRBs containing ZVI and sand in backfilled trenches has been designed to intercept the groundwater flow system prior to its discharge to the ground

  9. Remediation of the Highland Drive South Ravine, Port Hope, Ontario: Contaminated Groundwater Discharge Management Using Permeable Reactive Barriers and Contaminated Sediment Removal - 13447

    International Nuclear Information System (INIS)

    Smyth, David; Roos, Gillian; Ferguson Jones, Andrea; Case, Glenn; Yule, Adam

    2013-01-01

    The Highland Drive South Ravine (HDSR) is the discharge area for groundwater originating from the Highland Drive Landfill, the Pine Street North Extension (PSNE) roadbed parts of the Highland Drive roadbed and the PSNE Consolidation Site that contain historical low-level radioactive waste (LLRW). The contaminant plume from these LLRW sites contains elevated concentrations of uranium and arsenic and discharges with groundwater to shallow soils in a wet discharge area within the ravine, and directly to Hunt's Pond and Highland Drive South Creek, which are immediately to the south of the wet discharge area. Remediation and environmental management plans for HDSR have been developed within the framework of the Port Hope Project and the Port Hope Area Initiative. The LLRW sites will be fully remediated by excavation and relocation to a new Long-Term Waste Management Facility (LTWMF) as part of the Port Hope Project. It is projected, however, that the groundwater contaminant plume between the remediated LLRW sites and HDSR will persist for several hundreds of years. At the HDSR, sediment remediation within Hunt's Ponds and Highland Drive South Creek, excavation of the existing and placement of clean fill will be undertaken to remove current accumulations of solid-phase uranium and arsenic associated with the upper 0.75 m of soil in the wet discharge area, and permeable reactive barriers (PRBs) will be used for in situ treatment of contaminated groundwater to prevent the ongoing discharge of uranium and arsenic to the area in HDSR where shallow soil excavation and replacement has been undertaken. Bench-scale testing using groundwater from HDSR has confirmed excellent treatment characteristics for both uranium and arsenic using permeable reactive mixtures containing granular zero-valent iron (ZVI). A sequence of three PRBs containing ZVI and sand in backfilled trenches has been designed to intercept the groundwater flow system prior to its discharge to the ground surface

  10. A stratigraphic model to support remediation of groundwater contamination in the southern San Francisco Bay area

    International Nuclear Information System (INIS)

    Steinpress, M.G.

    1993-01-01

    Some early regional studies in the southern San Francisco Bay Area applied the term 'older bay mud' to Wisconsin and older deposits thought to be estuarine in origin. This outdated interpretation has apparently contributed to an expectation of laterally-continuous aquifers and aquitards. In fact, heterogeneous alluvial deposits often create complex hydrogeologic settings that defy simple remedial approaches. A more useful stratigraphic model provides a foundation for conducting site investigations and assessing the feasibility of remediation. A synthesis of recent regional studies and drilling results at one site on the southwest margin of the Bay indicate that the upper quaternary stratigraphy consists of four primary units in the upper 200 feet of sediments (oldest to youngest): (1) Illinoian glacial-age alluvium (an important groundwater source); (2) Sangamon interglacial-age deposits, which include fine-grained alluvial deposits and estuarine deposits equivalent to the Yerba Buena Mud (a regional confining layer); (3) Wisconsin glacial-age alluvial fan and floodplain deposits; and (4) Holocene interglacial-age sediments, which include fine-grained alluvial and estuarine deposits equivalent to the 'younger bay mud'. Remedial investigations generally focus on groundwater contamination in the Wisconsin and Holocene alluvial deposits. Detailed drilling results indicate that narrow sand and gravel channels occur in anastomosing patterns within a Wisconsin to Holocene floodplain sequence dominated by interchannel silts and clays. The identification of these small-scale high-permeability conduits is critical to understanding and predicting contaminant transport on a local scale. Discontinuous site-specific aquitards do not provide competent separation where stacked channels occur and the correlation of aquitards over even small distance is often tenuous at best

  11. In-situ remediation system for groundwater and soils

    Science.gov (United States)

    Corey, John C.; Kaback, Dawn S.; Looney, Brian B.

    1993-01-01

    A method and system for in-situ remediation of contaminated groundwater and soil where the contaminants, such as toxic metals, are carried in a subsurface plume. The method comprises selection and injection into the soil of a fluid that will cause the contaminants to form stable, non-toxic compounds either directly by combining with the contaminants or indirectly by creating conditions in the soil or changing the conditions of the soil so that the formation of stable, non-toxic compounds between the contaminants and existing substances in the soil are more favorable. In the case of non-toxic metal contaminants, sulfides or sulfates are injected so that metal sulfides or sulfates are formed. Alternatively, an inert gas may be injected to stimulate microorganisms in the soil to produce sulfides which, in turn, react with the metal contaminants. Preferably, two wells are used, one to inject the fluid and one to extract the unused portion of the fluid. The two wells work in combination to create a flow of the fluid across the plume to achieve better, more rapid mixing of the fluid and the contaminants.

  12. Demonstrating practical application of soil and groundwater clean-up and recovery technologies at natural gas processing facilities: Bioventing, air sparging and wetlands remediation

    International Nuclear Information System (INIS)

    Moore, B.

    1996-01-01

    This issue of the project newsletter described the nature of bioventing, air sparging and wetland remediation. It reviewed their effectiveness in remediating hydrocarbon contaminated soil above the groundwater surface. Bioventing was described as an effective, low cost treatment in which air is pumped below ground to stimulate indigenous bacteria. The bacteria then use the oxygen to consume the hydrocarbons, converting them to CO 2 and water. Air sparging involves the injection of air below the groundwater surface. As the air rises, hydrocarbons are stripped from the contaminated soil and water. The advantage of air sparging is that it cleans contaminated soil and water from below the groundwater surface. Hydrocarbon contamination of wetlands was described as fairly common. Conventional remediation methods of excavation, trenching, and bellholes to remove contamination often cause extreme harm to the ecosystem. Recent experimental evidence suggests that wetlands may be capable of attenuating contaminated water through natural processes. Four hydrocarbon contaminated wetlands in Alberta are currently under study. Results to date show that peat's high organic content promotes sorption and biodegradation and that some crude oil spills can been resolved by natural processes. It was suggested that assuming peat is present, a good clean-up approach may be to contain the contaminant source, monitor the lateral and vertical extent of contamination, and wait for natural processes to resolve the problem. 3 figs

  13. Final audit report of remedial action construction at the UMTRA project site Rifle, Colorado. Rev. 1

    International Nuclear Information System (INIS)

    1997-01-01

    This final audit report summarizes the assessments performed by the U.S. Department of Energy (DOE) Environmental Restoration Division (ERD) and its Technical Assistance Contractor (TAC) of remedial action compliance with approved plans, specifications, standards, and 40 CFR Part 192 at the Rifle, Colorado, Uranium Mill Tailings Remedial Action (UMTRA) Project site. Remedial action construction was directed by the Remedial Action Contractor (RAC)

  14. Independent technical reviews for groundwater and soil remediation projects at US Department Of Energy sites - 59188

    International Nuclear Information System (INIS)

    Kaback, Dawn S.; Chamberlain, Grover; Morse, John G.; Petersen, Scott W.

    2012-01-01

    The US Department of Energy Office of Environmental Management has supported independent technical reviews of soil and groundwater projects at multiple DOE sites over the last 10 years. These reviews have resulted in significant design improvements to remedial plans that have accelerated cleanup and site closure. Many have also resulted in improved understanding of complex subsurface conditions, promoting better approaches to design and implementation of new technologies. Independent technical reviews add value, because they provide another perspective to problem solving and act as a check for especially challenging problems. By bringing in a team of independent experts with a broad experience base, alternative solutions are recommended for consideration and evaluation. In addition, the independence of the panel is significant, because it is able to address politically sensitive issues. The expert panel members typically bring lessons learned from other sites to help solve the DOE problems. In addition, their recommendations at a particular site can often be applied at other sites, making the review even more valuable. The review process can vary, but some common lessons ensure a successful review: - Use a multi-disciplinary broadly experienced team; - Engage the panel early and throughout the project; - Involve regulators and stakeholders in the workshop, if appropriate. - Provide sufficient background information; - Close the workshop with a debriefing followed by a written report. Many groundwater remediation challenges remain at DOE sites. Independent technical reviews have and will ensure that the best capabilities and experience are applied to reduce risks and uncertainties. Even though the groundwater remediation industry has developed significantly over the last twenty years, advancements are needed to address the complexities of the subsurface at the DOE sites. These advancements have tremendous potential to save millions of dollars and to accelerate the

  15. Pilot plant experiences using physical and biological treatment steps for the remediation of groundwater from a former MGP site

    Energy Technology Data Exchange (ETDEWEB)

    Wirthensohn, T. [University of Natural Resources and Applied Life Sciences-Vienna, Department of IFA-Tulln, Institute for Environmental Biotechnology, Konrad Lorenz Strasse 20, 3430 Tulln (Austria)], E-mail: thomas.wirthensohn@boku.ac.at; Schoeberl, P. [Wienenergie Gasnetz GmbH, Referat 17-Altlasten, Josefstaedterstrasse 10-12, 1080 Vienna (Austria); Ghosh, U. [Department of Civil and Environmental Engineering, University of Maryland Baltimore County, Baltimore, MD 21250 (United States); Fuchs, W. [University of Natural Resources and Applied Life Sciences-Vienna, Department of IFA-Tulln, Institute for Environmental Biotechnology, Konrad Lorenz Strasse 20, 3430 Tulln (Austria)

    2009-04-15

    The production of manufactured gas at a site in Vienna, Austria led to the contamination of soil and groundwater with various pollutants including PAHs, hydrocarbons, phenols, BTEX, and cyanide. The site needs to be remediated to alleviate potential impacts to the environment. The chosen remediation concept includes the excavation of the core contaminated site and the setup of a hydraulic barrier to protect the surrounding aquifer. The extracted groundwater will be treated on-site. To design the foreseen pump-and-treat system, a pilot-scale plant was built and operated for 6 months. The scope of the present study was to test the effectiveness of different process steps, which included an aerated sedimentation basin, a submerged fixed film reactor (SFFR), a multi-media filter, and an activated carbon filter. The hydraulic retention time (HRT) was 7.0 h during normal flow conditions and 3.5 h during high flow conditions. The treatment system was effective in reducing the various organic and inorganic pollutants in the pumped groundwater. However, it was also demonstrated that appropriate pre-treatment was essential to overcome problems with clogging due to precipitation of tar and sulfur compounds. The reduction of the typical contaminants, PAHs and BTEX, was more than 99.8%. All water quality parameters after treatment were below the Austrian legal requirements for discharge into public water bodies.

  16. Pilot plant experiences using physical and biological treatment steps for the remediation of groundwater from a former MGP site.

    Science.gov (United States)

    Wirthensohn, T; Schoeberl, P; Ghosh, U; Fuchs, W

    2009-04-15

    The production of manufactured gas at a site in Vienna, Austria led to the contamination of soil and groundwater with various pollutants including PAHs, hydrocarbons, phenols, BTEX, and cyanide. The site needs to be remediated to alleviate potential impacts to the environment. The chosen remediation concept includes the excavation of the core contaminated site and the setup of a hydraulic barrier to protect the surrounding aquifer. The extracted groundwater will be treated on-site. To design the foreseen pump-and-treat system, a pilot-scale plant was built and operated for 6 months. The scope of the present study was to test the effectiveness of different process steps, which included an aerated sedimentation basin, a submerged fixed film reactor (SFFR), a multi-media filter, and an activated carbon filter. The hydraulic retention time (HRT) was 7.0 h during normal flow conditions and 3.5h during high flow conditions. The treatment system was effective in reducing the various organic and inorganic pollutants in the pumped groundwater. However, it was also demonstrated that appropriate pre-treatment was essential to overcome problems with clogging due to precipitation of tar and sulfur compounds. The reduction of the typical contaminants, PAHs and BTEX, was more than 99.8%. All water quality parameters after treatment were below the Austrian legal requirements for discharge into public water bodies.

  17. Pilot plant experiences using physical and biological treatment steps for the remediation of groundwater from a former MGP site

    International Nuclear Information System (INIS)

    Wirthensohn, T.; Schoeberl, P.; Ghosh, U.; Fuchs, W.

    2009-01-01

    The production of manufactured gas at a site in Vienna, Austria led to the contamination of soil and groundwater with various pollutants including PAHs, hydrocarbons, phenols, BTEX, and cyanide. The site needs to be remediated to alleviate potential impacts to the environment. The chosen remediation concept includes the excavation of the core contaminated site and the setup of a hydraulic barrier to protect the surrounding aquifer. The extracted groundwater will be treated on-site. To design the foreseen pump-and-treat system, a pilot-scale plant was built and operated for 6 months. The scope of the present study was to test the effectiveness of different process steps, which included an aerated sedimentation basin, a submerged fixed film reactor (SFFR), a multi-media filter, and an activated carbon filter. The hydraulic retention time (HRT) was 7.0 h during normal flow conditions and 3.5 h during high flow conditions. The treatment system was effective in reducing the various organic and inorganic pollutants in the pumped groundwater. However, it was also demonstrated that appropriate pre-treatment was essential to overcome problems with clogging due to precipitation of tar and sulfur compounds. The reduction of the typical contaminants, PAHs and BTEX, was more than 99.8%. All water quality parameters after treatment were below the Austrian legal requirements for discharge into public water bodies

  18. ZVI-Clay remediation of a chlorinated solvent source zone, Skuldelev, Denmark: 2. Groundwater contaminant mass discharge reduction

    DEFF Research Database (Denmark)

    Fjordbøge, Annika Sidelmann; Lange, Ida Vedel; Bjerg, Poul Løgstrup

    2012-01-01

    The impact of source mass depletion on the down-gradient contaminant mass discharge was monitored for a 19-month period as a part of a field demonstration of the ZVI-Clay soil mixing remediation technology. Groundwater samples were collected from conventional monitoring wells (120 samples) and a ...... down-gradient contaminant mass discharge reduction (76%) for the parent compound (PCE), while the overall reduction of chlorinated ethenes was smaller (21%)....

  19. Case study: Free product recovery and site remediation using horizontal trenching, soil vapor treatment and groundwater extraction

    International Nuclear Information System (INIS)

    Sanderson, E.P.; Johnston, H.S. Jr.; Farrell, M.; Twedell, D.B.

    1993-01-01

    Sites with soil and groundwater impacted by petroleum hydrocarbons have been remediated using a variety of traditional techniques. However, when the site impacted lies within a very confined downtown area of an expanding metropolitan city, a more complex array of technologies must be considered. The Law Enforcement Center site is the City of Charlotte's worst known underground storage tank (UST) release to date. A cost effective free product recovery, soil vapor and groundwater extraction system is being piloted here using new horizontal trenching technology and state of the art equipment. On-site low permeability soil required that an alternative to standard recovery wells be developed for groundwater recovery and vapor extraction. Operation and maintenance (O and M) of the large number of recovery wells required would have been extremely costly over the expected lifetime of the project. Although horizontal trenching was the best solution to the O and M costs, many problems were encountered during their installation

  20. Sustainable remediation: electrochemically assisted microbial dechlorination of tetrachloroethene-contaminated groundwater.

    Science.gov (United States)

    Patil, Sayali S; Adetutu, Eric M; Rochow, Jacqueline; Mitchell, James G; Ball, Andrew S

    2014-01-01

    Microbial electric systems (MESs) hold significant promise for the sustainable remediation of chlorinated solvents such as tetrachlorethene (perchloroethylene, PCE). Although the bio-electrochemical potential of some specific bacterial species such as Dehalcoccoides and Geobacteraceae have been exploited, this ability in other undefined microorganisms has not been extensively assessed. Hence, the focus of this study was to investigate indigenous and potentially bio-electrochemically active microorganisms in PCE-contaminated groundwater. Lab-scale MESs were fed with acetate and carbon electrode/PCE as electron donors and acceptors, respectively, under biostimulation (BS) and BS-bioaugmentation (BS-BA) regimes. Molecular analysis of the indigenous groundwater community identified mainly Spirochaetes, Firmicutes, Bacteroidetes, and γ and δ-Proteobacteria. Environmental scanning electron photomicrographs of the anode surfaces showed extensive indigenous microbial colonization under both regimes. This colonization and BS resulted in 100% dechlorination in both treatments with complete dechlorination occurring 4 weeks earlier in BS-BA samples and up to 11.5 μA of current being generated. The indigenous non-Dehalococcoides community was found to contribute significantly to electron transfer with ∼61% of the current generated due to their activities. This study therefore shows the potential of the indigenous non-Dehalococcoides bacterial community in bio-electrochemically reducing PCE that could prove to be a cost-effective and sustainable bioremediation practice. © 2013 The Authors. Microbial Biotechnology published by John Wiley & Sons Ltd and Society for Applied Microbiology.

  1. Hanford statewide groundwater flow and transport model calibration report

    International Nuclear Information System (INIS)

    Law, A.; Panday, S.; Denslow, C.; Fecht, K.; Knepp, A.

    1996-04-01

    This report presents the results of the development and calibration of a three-dimensional, finite element model (VAM3DCG) for the unconfined groundwater flow system at the Hanford Site. This flow system is the largest radioactively contaminated groundwater system in the United States. Eleven groundwater plumes have been identified containing organics, inorganics, and radionuclides. Because groundwater from the unconfined groundwater system flows into the Columbia River, the development of a groundwater flow model is essential to the long-term management of these plumes. Cost effective decision making requires the capability to predict the effectiveness of various remediation approaches. Some of the alternatives available to remediate groundwater include: pumping contaminated water from the ground for treatment with reinjection or to other disposal facilities; containment of plumes by means of impermeable walls, physical barriers, and hydraulic control measures; and, in some cases, management of groundwater via planned recharge and withdrawals. Implementation of these methods requires a knowledge of the groundwater flow system and how it responds to remedial actions

  2. Innovative technologies for in-situ remediation

    International Nuclear Information System (INIS)

    Ragaini, R.; Aines, R.; Knapp, R.; Matthews, S.; Yow, J.

    1994-06-01

    LLNL is developing several innovative remediation technologies as long-term improvements to the current pump and treat approaches to cleaning up contaminated soils and groundwater. These technologies include dynamic underground stripping, in-situ microbial filters, and remediation using bremsstrahlung radiation. Concentrated underground organic contaminant plumes are one of the most prevalent groundwater contamination sources. The solvent or fuel can percolate deep into the earth, often into water-bearing regions. Collecting as a separate, liquid organic phase called dense non-aqueous-phase liquids (DNAPLs), or light NAPLs (LNAPLs), these contaminants provide a source term that continuously compromises surrounding groundwater. This type of spill is one of the most difficult environmental problems to remediate. Attempts to remove such material requires a huge amount of water which must be washed through the system to clean it, requiring decades. Traditional pump and treat approaches have not been successful. LLNL has developed several innovative technologies to clean up NAPL contamination. Detailed descriptions of these technologies are given

  3. Remedial investigation work plan for Bear Creek Valley Operable Unit 4 (shallow groundwater in Bear Creek Valley) at the Oak Ridge Y-12 Plant, Oak Ridge, Tennessee

    International Nuclear Information System (INIS)

    1993-07-01

    To effectively evaluate the cumulative impact of releases from multiple sources of contamination, a structured approach has been adopted for Oak Ridge Reservation (ORR) based on studies of the groundwater and surface water separate from studies of the sources. Based on the realization of the complexity of the hydrogeologic regime of the ORR, together with the fact that there are numerous sources contributing to groundwater contamination within a geographical area, it was agreed that more timely investigations, at perhaps less cost, could be achieved by separating the sources of contamination from the groundwater and surface water for investigation and remediation. The result will be more immediate attention [Records of Decision (RODs) for interim measures or removal actions] for the source Operable Units (OUs) while longer-term remediation investigations continue for the hydrogeologic regimes, which are labeled as integrator OUs. This remedial investigation work plan contains summaries of geographical, historical, operational, geological, and hydrological information specific to the unit. Taking advantage of the historical data base and ongoing monitoring activities and applying the observational approach to focus data gathering activities will allow the feasibility study to evaluate all probable or likely alternatives

  4. Remedial Investigation work plan for Bear Creek Valley Operable Unit 4 (shallow groundwater in Bear Creek Valley) at the Oak Ridge Y-12 Plant, Oak Ridge, Tennessee

    International Nuclear Information System (INIS)

    1993-09-01

    To effectively evaluate the cumulative impact of releases from multiple sources of contamination, a structured approach has been adopted for Oak Ridge Reservation (ORR) based on studies of the groundwater and surface water separate from studies of the sources. Based on the realization of the complexity of the hydrogeologic regime of the ORR, together with the fact that there are numerous sources contributing to groundwater contamination within a geographical area, it was agreed that more timely investigations, at perhaps less cost, could be achieved by separating the sources of contamination from the groundwater and surface water for investigation and remediation. The result will be more immediate attention [Records of Decision (RODS) for interim measures or removal actions] for the source Operable Units (OUs) while longer-term remediation investigations continue for the hydrogeologic regime's, which are labeled as integrator OUs. This Remedial Investigation work plan contains summaries of geographical, historical, operational, geological, and hydrological information specific to the unit. Taking advantage of the historical data base and ongoing monitoring activities and applying the observational approach to focus data gathering activities will allow the Feasibility Study to evaluate all probable or likely alternatives

  5. Remedial Investigation work plan for Bear Creek Valley Operable Unit 4 (shallow groundwater in Bear Creek Valley) at the Oak Ridge Y-12 Plant, Oak Ridge, Tennessee

    Energy Technology Data Exchange (ETDEWEB)

    1993-09-01

    To effectively evaluate the cumulative impact of releases from multiple sources of contamination, a structured approach has been adopted for Oak Ridge Reservation (ORR) based on studies of the groundwater and surface water separate from studies of the sources. Based on the realization of the complexity of the hydrogeologic regime of the ORR, together with the fact that there are numerous sources contributing to groundwater contamination within a geographical area, it was agreed that more timely investigations, at perhaps less cost, could be achieved by separating the sources of contamination from the groundwater and surface water for investigation and remediation. The result will be more immediate attention [Records of Decision (RODS) for interim measures or removal actions] for the source Operable Units (OUs) while longer-term remediation investigations continue for the hydrogeologic regime`s, which are labeled as integrator OUs. This Remedial Investigation work plan contains summaries of geographical, historical, operational, geological, and hydrological information specific to the unit. Taking advantage of the historical data base and ongoing monitoring activities and applying the observational approach to focus data gathering activities will allow the Feasibility Study to evaluate all probable or likely alternatives.

  6. Remedial investigation work plan for Bear Creek Valley Operable Unit 4 (shallow groundwater in Bear Creek Valley) at the Oak Ridge Y-12 Plant, Oak Ridge, Tennessee

    Energy Technology Data Exchange (ETDEWEB)

    1993-07-01

    To effectively evaluate the cumulative impact of releases from multiple sources of contamination, a structured approach has been adopted for Oak Ridge Reservation (ORR) based on studies of the groundwater and surface water separate from studies of the sources. Based on the realization of the complexity of the hydrogeologic regime of the ORR, together with the fact that there are numerous sources contributing to groundwater contamination within a geographical area, it was agreed that more timely investigations, at perhaps less cost, could be achieved by separating the sources of contamination from the groundwater and surface water for investigation and remediation. The result will be more immediate attention [Records of Decision (RODs) for interim measures or removal actions] for the source Operable Units (OUs) while longer-term remediation investigations continue for the hydrogeologic regimes, which are labeled as integrator OUs. This remedial investigation work plan contains summaries of geographical, historical, operational, geological, and hydrological information specific to the unit. Taking advantage of the historical data base and ongoing monitoring activities and applying the observational approach to focus data gathering activities will allow the feasibility study to evaluate all probable or likely alternatives.

  7. The Rush to Remediate: Long Term Performance Favors Passive Systems at SRS

    International Nuclear Information System (INIS)

    Hoffman, D.; Cauthen, K.; Beul, R. R.

    2003-01-01

    The purpose of this paper is to describe the long-term performance of groundwater remediation systems at SRS and compare active versus passive systems. The presentation will focus on the limited effectiveness of active pump and treat systems and share the experience with more passive and natural systems such as soil vapor extraction, barometric pumping, bioremediation, and phytoremediation. Three remediation projects are presented. In each case the waste source is capped with clay or synthetic barriers; however, extensive groundwater contamination remains. The first project features the cleanup of the largest plume in the United States. The second project entails solvent and vinyl chloride remediation of groundwater beneath a hazardous waste landfill. The third project discusses tritium containment from a 160-acre radioactive waste disposal area. Special emphasis is placed on performance data from alternate technology cleanup. The goals are to share remediation data, successes and lessons learned, while making a case for passive systems use in groundwater remediation

  8. A calcite permeable reactive barrier for the remediation of Fluoride from spent potliner (SPL) contaminated groundwater

    DEFF Research Database (Denmark)

    Turner, B.D.; Binning, Philip John; Sloan, S.W.

    2008-01-01

    The use of calcite (CaCO3) as a substrate for a permeable reactive barrier (PRB) for removing fluoride from contaminated groundwater is proposed and is illustrated by application to groundwater contaminated by spent potliner leachate (SPL), a waste derived from the aluminium smelting process...... leachate indicate that the complex chemical matrix of the SPL leachate can impact fluoride removal significantly. For SPL contaminant mixtures, fluoride removal is initially less than expected from idealized, pure, solutions. However, with time, the effect of other contaminants on fluoride removal...... diminishes. Column tests also show that pH control is important for optimizing fluoride removal with the mass removed increasing with decreasing pH. Barrier pH can be regulated by CO2 addition with the point of injection being critical for optimising the remediation performance. Experimental and model...

  9. Evaluation of Final Radiological Conditions at Areas of the Niagara Falls Storage Site Remediated under the Formerly Utilized Sites Remedial Action Program -12184

    Energy Technology Data Exchange (ETDEWEB)

    Clayton, Christopher [U.S Department of Energy Office of Legacy Management, Washington, DC; Kothari, Vijendra [U.S Department of Energy Office of Legacy Management, Morgantown, West Virginia; Starr, Ken [U.S Department of Energy Office of Legacy Management, Westminster, Colorado; Widdop, Michael; Gillespie, Joey [SM Stoller Corporation, Grand Junction, Colorado

    2012-02-26

    The U. S. Department of Energy (DOE) methods and protocols allow evaluation of remediation and final site conditions to determine if remediated sites remain protective. Two case studies are presented that involve the Niagara Falls Storage Site (NFSS) and associated vicinity properties (VPs), which are being remediated under the Formerly Utilized Sites Remedial Action Program (FUSRAP). These properties are a part of the former Lake Ontario Ordnance Works (LOOW). In response to stakeholders concerns about whether certain remediated NFSS VPs were putting them at risk, DOE met with stakeholders and agreed to evaluate protectiveness. Documentation in the DOE records collection adequately described assessed and final radiological conditions at the completed VPs. All FUSRAP wastes at the completed sites were cleaned up to meet DOE guidelines for unrestricted use. DOE compiled the results of the investigation in a report that was released for public comment. In conducting the review of site conditions, DOE found that stakeholders were also concerned about waste from the Separations Process Research Unit (SPRU) at the Knolls Atomic Power Laboratory (KAPL) that was handled at LOOW. DOE agreed to determine if SPRU waste remained at that needed to be remediated. DOE reviewed records of waste characterization, historical handling locations and methods, and assessment and remediation data. DOE concluded that the SPRU waste was remediated on the LOOW to levels that pose no unacceptable risk and allow unrestricted use and unlimited exposure. This work confirms the following points as tenets of an effective long-term surveillance and maintenance (LTS&M) program: Stakeholder interaction must be open and transparent, and DOE must respond promptly to stakeholder concerns. DOE, as the long-term custodian, must collect and preserve site records in order to demonstrate that remediated sites pose no unacceptable risk. DOE must continue to maintain constructive relationships with the U

  10. Source zone remediation by zero valent iron technologies

    DEFF Research Database (Denmark)

    Fjordbøge, Annika Sidelmann

    at a fifth of these contaminated sites. These source zones pose a serious threat to soil and groundwater quality. Remediation of the heterogeneous source zones is challenging due to irregular downwards migration patterns in the subsurface, low aqueous solubility and matrix diffusion. To protect the soil...... and groundwater resources from long-term deterioration, the development of in situ technologies suitable for remediation of DNAPL is warranted. Currently, an array of aggressive in situ remediation technologies remediation exists. These technologies may be suitable under various site specific conditions; however......, most of them are limited by subsurface heterogeneities and/or the risk of inadvertent DNAPL displacement during field application. This thesis presents the results of an investigation of the potential for remediation of chlorinated solvent source zones by emerging zero valent iron (ZVI) based...

  11. A Case Study of Using Zero-Valent Iron Nanoparticles for Groundwater Remediation

    Science.gov (United States)

    Xiong, Z.; Kaback, D.; Bennett, P. J.

    2011-12-01

    Zero-valent iron nanoparticle (nZVI) is a promising technology for rapid in situ remediation of numerous contaminants, including chlorinated solvents, in groundwater and soil. Because of the high specific surface area of nZVI particles, this technology achieves treatment rates that are significantly faster than micron-scale and granular ZVI. However, a key technical challenge facing this technology involves agglomeration of nZVI particles. To improve nZVI mobility/deliverability and reactivity, an innovative method was recently developed using a low-cost and bio-degradable organic polymer as a stabilizer. This nZVI stabilization strategy offers unique advantages including: (1) the organic polymer is cost-effective and "green" (completely bio-compatible), (2) the organic polymer is highly effective in stabilizing nZVI particles; and (3) the stabilizer is applied during particle preparation, making nZVI particles more stable. Through a funding from the U.S. Air Force Center for Engineering and the Environment (AFCEE), AMEC performed a field study to test the effectiveness of this innovative technology for degradation of chlorinated solvents in groundwater at a military site. Laboratory treatability tests were conducted using groundwater samples collected from the test site and results indicated that trichloroethene (main groundwater contaminant at the site) was completely degraded within four hours by nZVI particles. In March and May 2011, two rounds of nZVI injection were performed at the test site. Approximately 700 gallons of nZVI suspension with palladium as a catalyst were successfully prepared in the field and injected into the subsurface. Before injection, membrane filters with a pore size of 450 nm were used to check the nZVI particle size and it was observed that >85% of nZVI particles were passed through the filter based on total iron measurement, indicating particle size of <450 nm. During field injections, nZVI particles were observed in a monitoring well

  12. 200-UP-1 groundwater remedial design/remedial action work plan. Revision 1

    International Nuclear Information System (INIS)

    1997-07-01

    This 200-UP-1 remedial design report presents the objective and rationale developed for the design and implementation of the selected interim remedial measure for the 200-UP-1 Operable Unit, located in the 200 West Area of the Hanford Site

  13. Applicability of petroleum horizontal drilling technology to hazardous waste site characterization and remediation

    International Nuclear Information System (INIS)

    Goranson, C.

    1992-09-01

    Horizontal wells have the potential to become an important tool for use in characterization, remediation and monitoring operations at hazardous waste disposal, chemical manufacturing, refining and other sites where subsurface pollution may develop from operations or spills. Subsurface pollution of groundwater aquifers can occur at these sites by leakage of surface disposal ponds, surface storage tanks, underground storage tanks (UST), subsurface pipelines or leakage from surface operations. Characterization and remediation of aquifers at or near these sites requires drilling operations that are typically shallow, less than 500-feet in depth. Due to the shallow nature of polluted aquifers, waste site subsurface geologic formations frequently consist of unconsolidated materials. Fractured, jointed and/or layered high compressive strength formations or compacted caliche type formations can also be encountered. Some formations are unsaturated and have pore spaces that are only partially filled with water. Completely saturated underpressured aquifers may be encountered in areas where the static ground water levels are well below the ground surface. Each of these subsurface conditions can complicate the drilling and completion of wells needed for monitoring, characterization and remediation activities. This report describes some of the equipment that is available from petroleum drilling operations that has direct application to groundwater characterization and remediation activities. A brief discussion of petroleum directional and horizontal well drilling methodologies is given to allow the reader to gain an understanding of the equipment needed to drill and complete horizontal wells. Equipment used in river crossing drilling technology is also discussed. The final portion of this report is a description of the drilling equipment available and how it can be applied to groundwater characterization and remediation activities

  14. Rulison Site groundwater monitoring report. Fourth quarter, 1997

    International Nuclear Information System (INIS)

    1998-02-01

    This report summarizes the results of the fourth quarter 1997 groundwater sampling event for the Rulison Site, which is located approximately 65 kilometers (km) (40 miles [mi]) northeast of Grand Junction, Colorado. This is the eighth and final sampling event of a quarterly groundwater monitoring program implemented by the U.S. Department of Energy (DOE). This program monitored the effectiveness of remediation of a drilling effluent pond that had been used to store drilling mud during drilling of the emplacement hole for a 1969 gas stimulation test conducted by the U.S. Atomic Energy Commission (AEC) (the predecessor agency to the DOE) and Austral Oil Company (Austral)

  15. Y-12 Plant Remedial Action technology logic diagram. Volume I: Technology evaluation

    International Nuclear Information System (INIS)

    1994-09-01

    The Y-12 Plant Remedial Action Program addresses remediation of the contaminated groundwater, surface water and soil in the following areas located on the Oak Ridge Reservation: Chestnut Ridge, Bear Creek Valley, the Upper and Lower East Fork Popular Creek Watersheds, CAPCA 1, which includes several areas in which remediation has been completed, and CAPCA 2, which includes dense nonaqueous phase liquid wells and a storage facility. There are many facilities within these areas that are contaminated by uranium, mercury, organics, and other materials. This Technology Logic Diagram identifies possible remediation technologies that can be applied to the soil, water, and contaminants for characterization, treatment, and waste management technology options are supplemented by identification of possible robotics or automation technologies. These would facilitate the cleanup effort by improving safety, of remediation, improving the final remediation product, or decreasing the remediation cost. The Technology Logic Diagram was prepared by a diverse group of more than 35 scientists and engineers from across the Oak Ridge Reservation. Most are specialists in the areas of their contributions. 22 refs., 25 tabs

  16. Basin F Subregional Groundwater Model

    National Research Council Canada - National Science Library

    Mazion, Edward

    2001-01-01

    The groundwater flow system at Rocky Mountain Arsenal (RMA) is complex. To evaluate proposed remedial alternatives, interaction of the local groundwater flow system with the present contamination control systems must be understood...

  17. Developing a disposal and remediation plan

    International Nuclear Information System (INIS)

    Messier, T.S.

    1999-01-01

    The environmental release of wastes generated by the upstream oil and gas industry in Alberta can result in polluted soil and groundwater at several facilities across the province. Responsibility for decommissioning upstream oil and gas facilities falls under the jurisdiction of the Alberta Energy and Utilities Board (EUB) and Alberta Environmental Protection (AEP). This paper outlines a protocol that can serve as a framework for the development of a plan to dispose of oilfield waste and to remediate related contaminated soils. The components involved in developing a disposal and remediation plan for oilfield wastes are: (1) identifying the potential source of pollution and oilfield waste generation, (2) characterizing oilfield wastes, (3) determining the nature and extent of soil and groundwater pollution, (4) preparing a remedial action plan, (5) assessing the viability of various remediation options, and (6) preparing health and safety plan. 12 refs., 2 tabs., 2 figs

  18. Remediation Approach for the Integrated Facility Disposition Project at the Oak Ridge National Laboratory

    International Nuclear Information System (INIS)

    Kirk, P.G.; Stephens, Jr.J.M.

    2009-01-01

    The Integrated Facility Disposition Project (IFDP) is a multi-billion-dollar remediation effort being conducted by the U.S. Department of Energy (DOE) Office of Environmental Management in Oak Ridge, Tennessee. The scope of the IFDP encompasses remedial actions related to activities conducted over the past 65 years at the Oak Ridge National Laboratory (ORNL) and the Y-12 National Security Complex (Y-12). Environmental media and facilities became contaminated as a result of operations, leaks, spills, and past waste disposal practices. ORNL's mission includes energy, environmental, nuclear security, computational, and materials research and development. Remediation activities will be implemented at ORNL as part of IFDP scope to meet remedial action objectives established in existing and future decision documents. Remedial actions are necessary (1) to comply with environmental regulations to reduce human health and environmental risk and (2) to release strategic real estate needed for modernization initiatives at ORNL. The scope of remedial actions includes characterization, waste management, transportation and disposal, stream restoration, and final remediation of contaminated soils, sediments, and groundwater. Activities include removal of at or below-grade substructures such as slabs, underground utilities, underground piping, tanks, basins, pits, ducts, equipment housings, manholes, and concrete-poured structures associated with equipment housings and basement walls/floors/columns. Many interim remedial actions involving groundwater and surface water that have not been completed are included in the IFDP remedial action scope. The challenges presented by the remediation of Bethel Valley at ORNL are formidable. The proposed approach to remediation endeavors to use the best available technologies and technical approaches from EPA and other federal agencies and lessons learned from previous cleanup efforts. The objective is to minimize cost, maximize remedial

  19. Chance-constrained multi-objective optimization of groundwater remediation design at DNAPLs-contaminated sites using a multi-algorithm genetically adaptive method

    Science.gov (United States)

    Ouyang, Qi; Lu, Wenxi; Hou, Zeyu; Zhang, Yu; Li, Shuai; Luo, Jiannan

    2017-05-01

    In this paper, a multi-algorithm genetically adaptive multi-objective (AMALGAM) method is proposed as a multi-objective optimization solver. It was implemented in the multi-objective optimization of a groundwater remediation design at sites contaminated by dense non-aqueous phase liquids. In this study, there were two objectives: minimization of the total remediation cost, and minimization of the remediation time. A non-dominated sorting genetic algorithm II (NSGA-II) was adopted to compare with the proposed method. For efficiency, the time-consuming surfactant-enhanced aquifer remediation simulation model was replaced by a surrogate model constructed by a multi-gene genetic programming (MGGP) technique. Similarly, two other surrogate modeling methods-support vector regression (SVR) and Kriging (KRG)-were employed to make comparisons with MGGP. In addition, the surrogate-modeling uncertainty was incorporated in the optimization model by chance-constrained programming (CCP). The results showed that, for the problem considered in this study, (1) the solutions obtained by AMALGAM incurred less remediation cost and required less time than those of NSGA-II, indicating that AMALGAM outperformed NSGA-II. It was additionally shown that (2) the MGGP surrogate model was more accurate than SVR and KRG; and (3) the remediation cost and time increased with the confidence level, which can enable decision makers to make a suitable choice by considering the given budget, remediation time, and reliability.

  20. Remedial investigation concept plan for the groundwater operable units at the chemical plant area and the ordnance works area, Weldon Spring, Missouri

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-07-15

    The U.S. Department of Energy (DOE) and the U.S. Department of the Army (DA) are conducting cleanup activities at two properties--the DOE chemical plant area and the DA ordnance works area (the latter includes the training area)--located in the Weldon Spring area in St. Charles County, Missouri. These areas are on the National Priorities List (NPL), and cleanup activities at both areas are conducted in accordance with the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA), as amended. DOE and DA are conducting a joint remedial investigation (RI) and baseline risk assessment (BRA) as part of the remedial investigation/feasibility study (RI/FS) for the groundwater operable units for the two areas. This joint effort will optimize further data collection and interpretation efforts and facilitate overall remedial decision making since the aquifer of concern is common to both areas. A Work Plan issued jointly in 1995 by DOE and the DA discusses the results of investigations completed at the time of preparation of the report. The investigations were necessary to provide an understanding of the groundwater system beneath the chemical plant area and the ordnance works area. The Work Plan also identifies additional data requirements for verification of the evaluation presented.

  1. Remedial investigation concept plan for the groundwater operable units at the chemical plant area and the ordnance works area, Weldon Spring, Missouri

    International Nuclear Information System (INIS)

    1999-01-01

    The U.S. Department of Energy (DOE) and the U.S. Department of the Army (DA) are conducting cleanup activities at two properties--the DOE chemical plant area and the DA ordnance works area (the latter includes the training area)--located in the Weldon Spring area in St. Charles County, Missouri. These areas are on the National Priorities List (NPL), and cleanup activities at both areas are conducted in accordance with the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA), as amended. DOE and DA are conducting a joint remedial investigation (RI) and baseline risk assessment (BRA) as part of the remedial investigation/feasibility study (RI/FS) for the groundwater operable units for the two areas. This joint effort will optimize further data collection and interpretation efforts and facilitate overall remedial decision making since the aquifer of concern is common to both areas. A Work Plan issued jointly in 1995 by DOE and the DA discusses the results of investigations completed at the time of preparation of the report. The investigations were necessary to provide an understanding of the groundwater system beneath the chemical plant area and the ordnance works area. The Work Plan also identifies additional data requirements for verification of the evaluation presented

  2. Use of toxicity assays for evaluating the effectiveness of groundwater remediation with Fenton’s reagent

    DEFF Research Database (Denmark)

    Kusk, Kresten Ole; Bennedsen, Lars; Christophersen, Mette

    2011-01-01

    evaluates in situ chemical oxidation (ISCO) using modified Fenton’s reagent (H2O2 + chelated Fe2+) as a groundwater remedy. Three injections were performed over a period to test treatment efficacy. Performance monitoring samples were collected from two depths both prior to and during treatment, and analyzed...... treatment with Fenton’s reagent the toxicity had increased and now needed 7100 times dilution to reduce toxicity to the LC10 probably due to mobilization of metals. It is concluded that toxicity assay is a useful tool for evaluating samples from contaminated sites and that toxicity assays and chemical...

  3. Technical/ administrative options for managing tritium MCL exceedances in P-area groundwater and Steel Creek

    Energy Technology Data Exchange (ETDEWEB)

    Ross, J. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

    2017-04-01

    This white paper was requested by the Core Team (United States Department of Energy [USDOE], United States Environmental Protection Agency [USEPA], and South Carolina Department of Health and Environmental Control [SCDHEC]) at the P-Area Groundwater (PAGW) Operable Unit (OU) Scoping Meeting held in January 2017 to discuss recent data and potential alternatives in support of a focused Corrective Measures Study/Feasibility Study (CMS/FS). This white paper presents an overview of the problem, and a range of technical and administrative options for addressing the tritium contamination in groundwater and Steel Creek. As tritium cannot be treated practicably, alternatives are limited to media transfer, containment and natural attenuation principally relying on radioactive decay. Using other groundwater OU decisions involving tritium as precedent, Savannah River Nuclear Solutions (SRNS) recommends that final tritium alternatives be evaluated in a CMS/FS, understanding that the likely preferred remedy will include natural attenuation with land use controls (LUCs). This is based on the inability to significantly reduce tritium impact to Steel Creek using an engineered solution as compared to natural attenuation. The timing of this evaluation could be conducted concurrently with the final remedy evaluation for volatile organic compounds (VOCs).

  4. Development and applications of groundwater remediation technologies in the USA

    Science.gov (United States)

    Barcelona, Michael J.

    2005-03-01

    The future of the development and application of groundwater remediation technologies will unfold in an atmosphere of heightened public concern and attention. Cleanup policy will undergo incremental change towards more comprehensive efforts which account for the impact of remediation on nearby resources. Newly discovered contaminants will cause the re-examination of "mature" technologies since they may be persistent, mobile and difficult to treat in-situ. Evaluations of the effectiveness of remedial technologies will eventually include by-product formation, geochemical consequences and sustainability. Long-term field trials of remedial technologies alone can provide the data necessary to support claims of effectiveness. Dans le futur, le développement et les applications des technologies de traitement des eaux souterraines seront déroulés en tenant compte de l'inquiétude et l'attention croissante de l'opinion publique. La politique de nettoyage va subir un changement vers des efforts plus compréhensifs qui prendront en compte l'impact du traitement sur les ressources voisines. Les nouveaux contaminants seront persistants, mobiles et difficile de traiter in situ; par conséquence ils vont provoquer la reexamination des technologies consacrées. L'évaluation de l'efficacité des technologies de traitement doit considérer l'apparition des produits secondaires ainsi que les conséquences géochimiques et le développement durable. Seulement les essais in situ, pendant des longues périodes sur les technologies peuvent fournir les éléments nécessaires pour démontrer leur efficacité. El futuro del desarrollo y de la aplicación de las tecnologías para la recuperación del agua subterránea, se revelará en una atmósfera de gran atención e interés público elevado. La política de limpieza sufrirá un cambio adicional hacia esfuerzos más tangibles, los cuales incluyan el impacto de la recuperación en los recursos circundantes. Los contaminantes

  5. Policy and procedures for classification of Class III groundwater at UMTRA Project sites

    International Nuclear Information System (INIS)

    1989-03-01

    The US Environmental Protection Agency (EPA) has recently proposed groundwater regulations for the US Department of Energy's )DOE) Uranium Mill Tailings Remedial Action (UMTRA) Project. These regulations allow the application of supplemental standards at UMTRA Project sites in specific situations. The designation of groundwater as Class III permits the application of supplemental standards. This document discusses a final UMTRA Project policy and procedures for identifying Class III groundwater, including identification of a review area, definition of water quality, quantification of aquifer yield, and identification of methods reasonably employed for public water supply systems. These items, either individually or collectively, need to be investigated in order to determine if groundwaters at UMTRA Project sites are Class III. This document provides a framework for the DOE to determine Class III groundwaters

  6. Sealable joint steel sheet piling for groundwater control and remediation: Case histories

    International Nuclear Information System (INIS)

    Smyth, D.; Jowett, R.; Gamble, M.

    1997-01-01

    The Waterloo Barrier trademark steel sheet piling (patents pending) incorporates a cavity at each interlocking joint that is flushed clean and injected with sealant after the piles have been driven into the ground to form a vertical cutoff wall. The installation and sealing procedures allow for a high degree of quality assurance and control. Bulk wall hydraulic conductivities of 10 -8 to 10 -10 cm/sec have been demonstrated at field installations. Recent case histories are presented in which Waterloo Barrier trademark cutoff walls are used to prevent off-site migration of contaminated groundwater or soil gases to adjacent property and waterways. Full enclosures to isolate DNAPL source zones or portions of contaminated aquifers for pilot-scale remediation testing will also be described. Monitoring data will be used to demonstrate the effectiveness of the Waterloo Barrier trademark in these applications

  7. Planning risk communication for UMTRA project groundwater restoration

    Energy Technology Data Exchange (ETDEWEB)

    Hundertmark, Charles [Jacobs Engineering Group Inc. and University of Phoenix (United States); Hoopes, Jack [Jacobs Engineering Group Inc. (United States); Flowers, Len [Roy F. Weston Company (United States); Jackson, David G [U.S. Department of Energy (United States)

    1992-07-01

    The U.S. Department of Energy's (DOE) Uranium Mill Tailings Remedial Action (UMTRA) Project is entering a new phase in which groundwater contamination will become a growing focus as surface remedial action draws toward completion. Planning for risk communication associated with the groundwater project will be a major factor in the successful initiation of the program. (author)

  8. Planning risk communication for UMTRA project groundwater restoration

    International Nuclear Information System (INIS)

    Hundertmark, Charles; Hoopes, Jack; Flowers, Len; Jackson, David G.

    1992-01-01

    The U.S. Department of Energy's (DOE) Uranium Mill Tailings Remedial Action (UMTRA) Project is entering a new phase in which groundwater contamination will become a growing focus as surface remedial action draws toward completion. Planning for risk communication associated with the groundwater project will be a major factor in the successful initiation of the program. (author)

  9. Remediation in Situ of Hydrocarbons by Combined Treatment in a Contaminated Alluvial Soil due to an Accidental Spill of LNAPL

    Directory of Open Access Journals (Sweden)

    Ettore Trulli

    2016-10-01

    Full Text Available Soil contamination represents an environmental issue which has become extremely important in the last decades due to the diffusion of industrial activities. Accidents during transport of dangerous materials and fuels may cause severe pollution. The present paper describes the criteria of the actions which were operated to remediate the potential risk and observed negative effects on groundwater and soil originating from an accidental spill of diesel fuel from a tank truck. With the aim to evaluate the quality of the involved environmental matrices in the “emergency” phase, in the following “safety” operation and during the remediation action, a specific survey on hydrocarbons, light and heavy, was carried out in the sand deposits soil. Elaboration of collected data allows us to observe the movement of pollutants in the unsaturated soil. The remediation action was finalized to improve the groundwater and soil quality. The former was treated by a so called “pump and treat” system coupled with air sparging. A train of three different technologies was applied to the unsaturated soil in a sequential process: soil vapour extraction, bioventing and enhanced bioremediation. Results showed that the application of sequential remediation treatments allowed us to obtain a state of quality in unsaturated soil and groundwater as required by Italian law.

  10. Chance-constrained multi-objective optimization of groundwater remediation design at DNAPLs-contaminated sites using a multi-algorithm genetically adaptive method.

    Science.gov (United States)

    Ouyang, Qi; Lu, Wenxi; Hou, Zeyu; Zhang, Yu; Li, Shuai; Luo, Jiannan

    2017-05-01

    In this paper, a multi-algorithm genetically adaptive multi-objective (AMALGAM) method is proposed as a multi-objective optimization solver. It was implemented in the multi-objective optimization of a groundwater remediation design at sites contaminated by dense non-aqueous phase liquids. In this study, there were two objectives: minimization of the total remediation cost, and minimization of the remediation time. A non-dominated sorting genetic algorithm II (NSGA-II) was adopted to compare with the proposed method. For efficiency, the time-consuming surfactant-enhanced aquifer remediation simulation model was replaced by a surrogate model constructed by a multi-gene genetic programming (MGGP) technique. Similarly, two other surrogate modeling methods-support vector regression (SVR) and Kriging (KRG)-were employed to make comparisons with MGGP. In addition, the surrogate-modeling uncertainty was incorporated in the optimization model by chance-constrained programming (CCP). The results showed that, for the problem considered in this study, (1) the solutions obtained by AMALGAM incurred less remediation cost and required less time than those of NSGA-II, indicating that AMALGAM outperformed NSGA-II. It was additionally shown that (2) the MGGP surrogate model was more accurate than SVR and KRG; and (3) the remediation cost and time increased with the confidence level, which can enable decision makers to make a suitable choice by considering the given budget, remediation time, and reliability. Copyright © 2017 Elsevier B.V. All rights reserved.

  11. A Discovery-Based Experiment Illustrating How Iron Metal Is Used to Remediate Contaminated Groundwater

    Science.gov (United States)

    Balko, Barbara A.; Tratnyek, Paul G.

    2001-12-01

    In this article, we describe an experiment for undergraduate general chemistry in which students investigate the chemistry behind iron-permeable reactive barriers (iron PRBs), a new technology that is widely used to remediate contaminated groundwater. Contaminant remediation involving iron PRBs is a redox process: the iron metal undergoes oxidative dissolution while the contaminant is reduced. The reaction is complicated, however, by the fact that it involves a surface that changes owing to the development of a layer of rust (iron oxide) on the iron. In this experiment, students examine the iron PRB-contaminant reaction by characterizing the kinetics of the degradation of a dye (the model contaminant) in the presence of granular iron under various experimental conditions. Students can be asked to design their own experiments to investigate aspects of the degradation reaction that are of particular interest to them. The material covered in the lab includes oxidation-reduction reactions, pseudo first-order kinetics, spectrophotometry, and the application of chemistry to solving environmental problems. The experiment can also be used as a vehicle to introduce more advanced topics in chemistry such as heterogeneous reactions, corrosion, passive film growth, and mass transport.

  12. Multi-objective optimization of in-situ bioremediation of groundwater using a hybrid metaheuristic technique based on differential evolution, genetic algorithms and simulated annealing

    Directory of Open Access Journals (Sweden)

    Kumar Deepak

    2015-12-01

    Full Text Available Groundwater contamination due to leakage of gasoline is one of the several causes which affect the groundwater environment by polluting it. In the past few years, In-situ bioremediation has attracted researchers because of its ability to remediate the contaminant at its site with low cost of remediation. This paper proposed the use of a new hybrid algorithm to optimize a multi-objective function which includes the cost of remediation as the first objective and residual contaminant at the end of the remediation period as the second objective. The hybrid algorithm was formed by combining the methods of Differential Evolution, Genetic Algorithms and Simulated Annealing. Support Vector Machines (SVM was used as a virtual simulator for biodegradation of contaminants in the groundwater flow. The results obtained from the hybrid algorithm were compared with Differential Evolution (DE, Non Dominated Sorting Genetic Algorithm (NSGA II and Simulated Annealing (SA. It was found that the proposed hybrid algorithm was capable of providing the best solution. Fuzzy logic was used to find the best compromising solution and finally a pumping rate strategy for groundwater remediation was presented for the best compromising solution. The results show that the cost incurred for the best compromising solution is intermediate between the highest and lowest cost incurred for other non-dominated solutions.

  13. Technical framework for groundwater restoration

    International Nuclear Information System (INIS)

    1991-04-01

    This document provides the technical framework for groundwater restoration under Phase II of the Uranium Mill Tailings Remedial Action (UMTRA) Project. A preliminary management plan for Phase II has been set forth in a companion document titled ''Preplanning Guidance Document for Groundwater Restoration''. General principles of site characterization for groundwater restoration, restoration methods, and treatment are discussed in this document to provide an overview of standard technical approaches to groundwater restoration

  14. Remediation of arsenic-contaminated groundwater by in-situ stimulating biogenic precipitation of iron sulfides.

    Science.gov (United States)

    Pi, Kunfu; Wang, Yanxin; Xie, Xianjun; Ma, Teng; Liu, Yaqing; Su, Chunli; Zhu, Yapeng; Wang, Zhiqiang

    2017-02-01

    Severe health problems due to elevated arsenic (As) in groundwater have made it urgent to develop cost-effective technologies for As removal. This field experimental study tested the feasibility of in-situ As immobilization via As incorporation into newly formed biogenic Fe(II) sulfides in a typical As-affected strongly reducing aquifer at the central part of Datong Basin, China. After periodic supply of FeSO 4 into the aquifer for 25 d to stimulate microbial sulfate reduction, dissolved sulfide concentrations increased during the experiment, but the supplied Fe(II) reacted quickly with sulfide to form Fe(II)-sulfides existing majorly as mackinawite as well as a small amount of pyrite-like minerals in sediments, thereby restricting sulfide build-up in groundwater. After the completion of field experiment, groundwater As concentration decreased from an initial average value of 593 μg/L to 159 μg/L, with an overall As removal rate of 73%, and it further declined to 136 μg/L adding the removal rate up to 77% in 30 d after the experiment. The arsenite/As total ratio gradually increased over time, making arsenite to be the predominant species in groundwater residual As. The good correlations between dissolved Fe(II), sulfide and As concentrations, the increased abundance of As in newly-formed Fe sulfides as well as the reactive-transport modeling results all indicate that As could have been adsorbed onto and co-precipitated with Fe(II)-sulfide coatings once microbial sulfate reduction was stimulated after FeSO 4 supply. Under the strongly reducing conditions, sulfide may facilitate arsenate reduction into arsenite and promote As incorporation into pyrite or arsenopyrite. Therefore, the major mechanisms for the in-situ As-contaminated groundwater remediation can be As surface-adsorption on and co-precipitation with Fe(II) sulfides produced during the experimental period. Copyright © 2016. Published by Elsevier Ltd.

  15. A case study of risk assessment in contaminated site remediation in China

    Science.gov (United States)

    Ye, S.; Guo, J.; Wu, J.; Wang, J.; Chien, C.; Stahl, R.; Mack, E.; Grosso, N.

    2013-12-01

    A field site in Nanjing, China was selected for a case study of risk assessment in contaminated site remediation. This site is about 100m long and 100m wide. A chemical plant (1999-2010) at the site manufactured optical brightener PF, 2-Amino-4-methylphenol and 2-Nitro-4-methylphenol, totally three products. Soil and groundwater samples were collected and analyzed for PPL 126 (126 pollutants in the 'Priority Pollutants List' issued by US EPA). Values of the Dutch Standards were used as the screening criteria for soil and ground water. Low levels of ethylbenezene, chlorobenzene, 1,3-dichlorobenzene and 1,4- dichlorobenzene were detected in one soil sample. Concentrations above Dutch Target Value (DTV) of benzene, toluene, ethylbenzene, chlorobenzene, 1,2-dichlorobenzene, 1,3-dichlorobenzene, 1,4-dichlorobenzene, and/or 1,2,4-trichlorobenzene, phenol, and/or 2,4-dichlorophenol were exhibited in two groundwater samples. The ground water was especially highly impacted by bichlorobenzenes and trichlorobenzenes. The maximum concentration of impacts was 7.3 mg/L of 1,2,4-trichlorobenzene in groundwater which was 730 times higher than Dutch Intervention Values (DIV). Risk of soil and groundwater at this site was assessed according to the guidelines issued by Chinese MEP and US EPA, respectively. Finally, remedy techniques were selected according to the result of risk assessment and the characteristics of hydrogeology conditions and contaminants.

  16. Hanford Site Groundwater Monitoring for Fiscal Year 1998

    Energy Technology Data Exchange (ETDEWEB)

    Hartman, M.J. [and others

    1999-03-24

    wells; they are believed to represent natural components of groundwater. Resource Conservation and Recovery Act of 1976 groundwater monitoring continued at 25 waste management areas during FY 1998: 17 under detection programs and data indicate that they are not adversely affecting groundwater, 6 under interim-status groundwater-quality-assessment programs to assess possible contamination, and 2 under final-status corrective-action programs. Groundwater remediation in the 100 Areas continued to reduce the amount of strontium-90 (100-N) and chromium (100-K, D, and H) reaching the Columbia River. Two systems in the 200-West Area operated to prevent the spread of carbon tetrachloride and technetide uranium plumes. Groundwater monitoring continued at these sites and at other sites where there is no active remediation. A three-dimensional, numerical groundwater model was applied to simulate radionuclide movement from sources in the 200 Areas following site closure in 2050. Contaminants will continue to move toward the southeast and north (through Gable Gap), but the areas with levels exceeding drinking water standards will diminish.

  17. Corrective measures evaluation report for Tijeras Arroyo groundwater.

    Energy Technology Data Exchange (ETDEWEB)

    Witt, Johnathan L (North Wind, Inc., Idaho Falls, ID); Orr, Brennon R. (North Wind, Inc., Idaho Falls, ID); Dettmers, Dana L. (North Wind, Inc., Idaho Falls, ID); Hall, Kevin A. (North Wind, Inc., Idaho Falls, ID); Howard, M. Hope (North Wind, Inc., Idaho Falls, ID)

    2005-08-01

    This Corrective Measures Evaluation report was prepared as directed by a Compliance Order on Consent issued by the New Mexico Environment Department to document the process of selecting the preferred remedial alternative for Tijeras Arroyo Groundwater. Supporting information includes background concerning the site conditions and potential receptors and an overview of work performed during the Corrective Measures Evaluation. The evaluation of remedial alternatives included identifying and describing four remedial alternatives, an overview of the evaluation criteria and approach, comparing remedial alternatives to the criteria, and selecting the preferred remedial alternative. As a result of the Corrective Measures Evaluation, monitored natural attenuation of the contaminants of concern (trichloroethene and nitrate) is the preferred remedial alternative for implementation as the corrective measure for Tijeras Arroyo Groundwater. Design criteria to meet cleanup goals and objectives and the corrective measures implementation schedule for the preferred remedial alternative are also presented.

  18. Papers of the remediation technologies symposium 2005. CD-ROM ed.

    International Nuclear Information System (INIS)

    2005-01-01

    This conference was attended by over 500 delegates and provided an opportunity for industry, practitioners, researchers and regulators to discuss technical issues in environmental remediation research and recent innovations in soil and groundwater remediation. Sessions included presentations on in-situ, groundwater and surface water remediation. Issues concerning phytoremediation, natural attenuation, extraction and commercial redevelopment were examined. The aim of the conference was also to provide a forum for innovators in remediation to present new work. Topics included hydrocarbon and salt contamination; engineered soil cover for management of salt impacted sites; remediation and revegetation of tar sands composite tailings containing naphthenic acids; sorption of oil sands naphthenic acid mixtures; denitrification as a natural attenuation mechanism; sampling methodologies; variability assessments; stabilization treatment technologies; remediation of coal wastes; bioreactor landfills; well blowouts in Alberta; soil remediation in coarse gravelly soils; diesel-contaminated aquifers; gasoline spill remediation; soil vapour extraction systems; technological solutions for erosion control and water clarification; and cost-effective in-situ remediation strategies. Fifty-two technical presentations were given, of which 27 have been catalogued separately for inclusion in this database

  19. Papers of the remediation technologies symposium 2005. CD-ROM ed.

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2005-07-01

    This conference was attended by over 500 delegates and provided an opportunity for industry, practitioners, researchers and regulators to discuss technical issues in environmental remediation research and recent innovations in soil and groundwater remediation. Sessions included presentations on in-situ, groundwater and surface water remediation. Issues concerning phytoremediation, natural attenuation, extraction and commercial redevelopment were examined. The aim of the conference was also to provide a forum for innovators in remediation to present new work. Topics included hydrocarbon and salt contamination; engineered soil cover for management of salt impacted sites; remediation and revegetation of tar sands composite tailings containing naphthenic acids; sorption of oil sands naphthenic acid mixtures; denitrification as a natural attenuation mechanism; sampling methodologies; variability assessments; stabilization treatment technologies; remediation of coal wastes; bioreactor landfills; well blowouts in Alberta; soil remediation in coarse gravelly soils; diesel-contaminated aquifers; gasoline spill remediation; soil vapour extraction systems; technological solutions for erosion control and water clarification; and cost-effective in-situ remediation strategies. Fifty-two technical presentations were given, of which 27 have been catalogued separately for inclusion in this database. tabs., figs.

  20. Uranium mill tailings remedial action technology

    International Nuclear Information System (INIS)

    Hartley, J.N.; Gee, G.W.

    1984-01-01

    The uranium milling process involves the hydrometallurgical extraction of uranium from ores and the resultant generation of large quantities of waste referred to as tailings. Uranium mill tailings have been identified as requiring remediation because they contain residual radioactive material that is not removed in the milling process. Potential radiation exposure can result from direct contact with the tailings, from radon gas emitted by the tailings, and from radioactive contamination of groundwater. As a result, the technology developed under the US Department of Energy (DOE) Uranium Mill Tailings Remedial Action Project (UMTRAP) and the US Nuclear Regulatory Commission (NRC) Uranium Recovery Program have focused on radon control, groundwater contamination and the long-term protection of the containment system. This paper briefly summarizes the UMTRAP and NRC remedial action technology development. 33 references, 9 figures, 5 tables

  1. Adapting Advances in Remediation Science to Long-Term Surveillance

    International Nuclear Information System (INIS)

    Peterson, D.M.

    2006-01-01

    Several facets of groundwater remediation stand to gain from the advances made during recent years in disciplines that contribute to remediation science. Engineered remedies designed to aggressively remove subsurface contamination should benefit from this progress, and more passive cleanup methods and the long-term monitoring of such passive approaches may benefit equally well if not more. The U.S. Department of Energy Office of Legacy Management (LM) has adopted a strategic plan that is designed to take advantage of technological improvements in the monitoring and assessment of both active and passive groundwater remedies. Flexible adaptation of new technologies, as they become available, to long-term surveillance at LM sites is expected to reduce site stewardship costs while ensuring the future protection of human health and the environment. Some of the technologies are expected to come from government initiatives that focus on the needs of subsurface monitoring. Additional progress in monitoring science will likely result from continual improvements in our understanding of contaminant fate-and-transport processes in groundwater and the vadose zone. (authors)

  2. Adapting Advances in Remediation Science to Long-Term Surveillance

    Energy Technology Data Exchange (ETDEWEB)

    Peterson, Dave [S.M. Stoller Corporation

    2006-03-01

    Several facets of groundwater remediation stand to gain from the advances made during recent years in disciplines that contribute to remediation science. Engineered remedies designed to aggressively remove subsurface contamination should benefit from this progress, and more passive cleanup methods and the long-term monitoring of such passive approaches may benefit equally well if not more. The U.S. Department of Energy Office of Legacy Management (LM) has adopted a strategic plan that is designed to take advantage of technological improvements in the monitoring and assessment of both active and passive groundwater remedies. Flexible adaptation of new technologies, as they become available, to long-term surveillance at LM sites is expected to reduce site stewardship costs while ensuring the future protection of human health and the environment. Some of the technologies are expected to come from government initiatives that focus on the needs of subsurface monitoring. Additional progress in monitoring science will likely result from continual improvements in our understanding of contaminant fate-and-transport processes in the groundwater and the vadose zone.

  3. Biogeochemical dynamics of pollutants in Insitu groundwater remediation systems

    Science.gov (United States)

    Kumar, N.; Millot, R.; Rose, J.; Négrel, P.; Battaglia-Brunnet, F.; Diels, L.

    2010-12-01

    Insitu (bio) remediation of groundwater contaminants has been area of potential research interest in last few decades as the nature of contaminant encountered has also changed drastically. This gives tough challenge to researchers in finding a common solution for all contaminants together in one plume. Redox processes play significant role in pollutant dynamics and mobility in such systems. Arsenic particularly in reduced environments can get transformed into its reduced form (As3+), which is apparently more mobile and highly toxic. Also parallel sulfate reduction can lead to sulfide production and formation of thioarsenic species. On the other hand heavy metals (Zn, Fe, and Cd) in similar conditions will favour more stable metal sulfide precipitation. In the present work, we tested Zero Valent Iron (ZVI) in handling such issues and found promising results. Although it has been well known for contaminants like arsenic and chlorinated compounds but not much explored for heavy metals. Its high available surface area supports precipitation and co -precipitation of contaminants and its highly oxidizing nature and water born hydrogen production helps in stimulation of microbial activities in sediment and groundwater. These sulfate and Iron reducing bacteria can further fix heavy metals as stable metal sulfides by using hydrogen as potential electron donor. In the present study flow through columns (biotic and control) were set up in laboratory to understand the behaviour of contaminants in subsurface environments, also the impact of microbiology on performance of ZVI was studied. These glass columns (30 x 4cm) with intermediate sampling points were monitored over constant temperature (20°C) and continuous groundwater (up)flow at ~1ml/hr throughout the experiment. Simulated groundwater was prepared in laboratory containing sulfate, metals (Zn,Cd) and arsenic (AsV). While chemical and microbial parameters were followed regularly over time, solid phase has been

  4. Demonstration of risk-based decision analysis in remedial alternative selection and design

    International Nuclear Information System (INIS)

    Evans, E.K.; Duffield, G.M.; Massmann, J.W.; Freeze, R.A.; Stephenson, D.E.

    1993-01-01

    This study demonstrates the use of risk-based decision analysis (Massmann and Freeze 1987a, 1987b) in the selection and design of an engineering alternative for groundwater remediation at a waste site at the Savannah River Site, a US Department of Energy facility in South Carolina. The investigation focuses on the remediation and closure of the H-Area Seepage Basins, an inactive disposal site that formerly received effluent water from a nearby production facility. A previous study by Duffield et al. (1992), which used risk-based decision analysis to screen a number of ground-water remediation alternatives under consideration for this site, indicated that the most attractive remedial option is ground-water extraction by wells coupled with surface water discharge of treated effluent. The aim of the present study is to demonstrate the iterative use of risk-based decision analysis throughout the design of a particular remedial alternative. In this study, we consider the interaction between two episodes of aquifer testing over a 6-year period and the refinement of a remedial extraction well system design. Using a three-dimensional ground-water flow model, this study employs (1) geostatistics and Monte Carlo techniques to simulate hydraulic conductivity as a stochastic process and (2) Bayesian updating and conditional simulation to investigate multiple phases of aquifer testing. In our evaluation of a remedial alternative, we compute probabilistic costs associated with the failure of an alternative to completely capture a simulated contaminant plume. The results of this study demonstrate the utility of risk-based decision analysis as a tool for improving the design of a remedial alternative through the course of phased data collection at a remedial site

  5. Integrated phytobial remediation for sustainable management of arsenic in soil and water.

    Science.gov (United States)

    Roy, Madhumita; Giri, Ashok K; Dutta, Sourav; Mukherjee, Pritam

    2015-02-01

    Arsenic (As), cited as the most hazardous substance by the U.S. Agency for Toxic Substance and Disease Registry (ATSDR, 2005), is an ubiquitous metalloid which when ingested for prolonged periods cause extensive health effects leading to ultimate untimely death. Plants and microbes can help mitigate soil and groundwater As problem since they have evolved elaborate detoxification machineries against this toxic metalloid as a result of their coexistence with this since the origin of life on earth. Utilization of the phytoremediation and bioremediation potential of the plants and microbes, respectively, is now regarded as two innovative tools that encompass biology, geology, biotechnology and allied sciences with cutting edge applications for sustainable mitigation of As epidemic. Discovery of As hyperaccumulating plants that uptake and concentrate large amounts of this toxic metalloid in their shoots or roots offered new hope to As phytoremediation, solar power based nature's own green remediation. This review focuses on how phytoremediation and bioremediation can be merged together to form an integrated phytobial remediation which could synergistically achieve the goal of large scale removal of As from soil, sediment and groundwater and overcome the drawbacks of the either processes alone. The review also points to the feasibility of the introduction of transgenic plants and microbes that bring new hope for more efficient treatment of As. The review identifies one critical research gap on the importance of remediation of As contaminated groundwater not only for drinking purpose but also for irrigation purpose and stresses that more research should be conducted on the use of constructed wetland, one of the most suitable areas of application of phytobial remediation. Finally the review has narrowed down on different phytoinvestigation and phytodisposal methods, which constitute the most essential and the most difficult part of pilot scale and field scale applications

  6. Installation of reactive metals groundwater collection and treatment systems

    International Nuclear Information System (INIS)

    Hopkins, J.K.; Primrose, A.L.; Uhland, J.

    1998-01-01

    Three groundwater plumes contaminated with volatile organic compounds (VOCs) and radionuclides at the Rocky Flats Environmental Technology Site are scheduled for remediation by 1999 based on the Rocky Flats Cleanup Agreement (RFCA) (DOE, 1996). These three plumes are among the top 20 environmental cleanup sites at Rocky Flats. One of these plumes, the Mound Site Plume, is derived from a previous drum storage area, and daylights as seeps near the South Walnut Creek drainage. Final design for remediation of the Mound Site Plume has been completed based on use of reactive metals to treat the contaminated groundwater, and construction is scheduled for early 1998. The two other plumes, the 903 Pad/Ryan's Pit and the East Trenches Plumes, are derived from VOCs either from drums that leaked or that were disposed of in trenches. These two plumes are undergoing characterization and conceptual design in 1998 and construction is scheduled in 1999. The contaminants of concern in these plumes are tetrachloroethene, trichloroethene, carbon tetrachloride and low levels of uranium and americium

  7. Environmental assessment for 881 Hillside (High Priority Sites) interim remedial action

    International Nuclear Information System (INIS)

    1990-01-01

    This Environmental Assessment evaluates the impact of an interim remedial action proposed for the High Priority Sites (881 Hillside Area) at the Rocky Flats Plant (RFP). This interim action is to be conducted to minimize the release of hazardous substances from the 881 Hillside Area that pose a potential long-term threat to public health and the environment. This document integrates current site characterization data and environmental analyses required by the Comprehensive Environmental Response, Compensation and Liability Act (CERCLA) or ''Superfund'' process, into an environmental assessment pursuant to the National Environmental Policy Act (NEPA). Characterization of the 881 Hillside Area is continuing. Consequently, a final remedial action has not yet been proposed. Environmental impacts associated with the proposed interim remedial action and reasonable alternatives designed to remove organic and inorganic contaminants, including radionuclides, from alluvial groundwater in the 881 Hillside Area are addressed. 24 refs., 5 figs., 23 tabs

  8. DOE`s approach to groundwater compliance on the UMTRA project

    Energy Technology Data Exchange (ETDEWEB)

    Metzler, D. [Dept. of Energy, Washington, DC (United States); Gibb, J.P. [Geraghty and Miller, Inc. (United States); Glover, W.A. [Roy F. Weston, Inc. (United States)

    1993-03-01

    Compliance with the mandate of the Uranium Mill Tailings Radiation Control Act (UMTRCA) at Uranium Mill Tailings Remedial Action (UMTRA) Project sites requires implementation of a groundwater remedial action plan that meets the requirements of Subpart B of the US Environmental Protection Agency`s proposed groundwater protection standards (40 CFR 192). The UMTRA Groundwater Project will ensure that unacceptable current risk or potential risk to the public health, safety and the environment resulting from the groundwater contamination attributable to the UMTRA sites, is mitigated in a timely and cost-efficient manner. For each UMTRA processing site and vicinity property where contamination exists, a groundwater remedial action plan must be developed that identifies hazardous constituents and establishes acceptable concentration limits for the hazardous constituents as either (a) alternate concentration limits (ACL), (b) maximum concentration limits (MCLs), (c) supplemental standards, or (d) background groundwater quality levels. Project optimization is a strategy that will aggressively work within the current regulatory framework using all available options to meet regulatory requirements. This strategy is outlined within.

  9. Final Project Report, DE-SC0001280, Characterizing the Combined Roles of Iron and Transverse Mixing on Uranium Bioremediation in Groundwater using Microfluidic Devices

    Energy Technology Data Exchange (ETDEWEB)

    Finneran, Kevin [Clemson Univ., SC (United States); Werth, Charles [Univ. of Texas, Austin, TX (United States); Strathmann, Timothy [Univ. of Illinois, Urbana-Champaign, IL (United States)

    2015-01-10

    In situ bioremediation of U(VI) involves amending groundwater with an appropriate electron donor and limiting nutrients to promote biological reduction to the less soluble and mobile U(IV) oxidation state. Groundwater flow is laminar; mixing is controlled by hydrodynamic dispersion. Recent studies indicate that transverse dispersion along plume margins can limit mixing of the amended electron donor and accepter (such as U(VI) in remediation applications). As a result, microbial growth, and subsequently contaminant reaction, may be limited to these transverse mixing zones during bioremediation. The primary objective of this work was to characterize the combined effects of hydrology, geochemistry, and biology on the (bio)remediation of U(VI). Our underlying hypothesis was that U(VI) reaction in groundwater is controlled by transverse mixing with an electron donor along plume margins, and that iron bioavailability in these zones affects U(VI) reduction kinetics and U(IV) re-oxidation. Our specific objectives were to a) quantify reaction kinetics mediated by biological versus geochemical reactions leading to U(VI) reduction and U(IV) re-oxidation, b) understand the influence of bioavailable iron on U(VI) reduction and U(IV) re-oxidation along the transverse mixing zones, c) determine how transverse mixing limitations and the presence of biomass in pores affects these reactions, and d) identify how microbial populations that develop along transverse mixing zones are influenced by the presence of iron and the concentration of electron donor. In the completed work, transverse mixing zones along plume margins were re-created in microfluidic pore networks, referred to as micromodels. We conducted a series of experiments that allowed us to distinguish among the hydraulic, biological, and geochemical mechanisms that contribute to U(VI) reduction, U(IV) re-oxidation, and U(VI) abiotic reaction with the limiting biological nutrient HP042-. This systematic approach may lead to a

  10. Remediation challenges posed by the fate and transport properties of MTBE

    International Nuclear Information System (INIS)

    Day, M.J.

    2002-01-01

    Releases of fuel from underground tank systems have been a major source of groundwater contamination for several decades. The fate and transport characteristics of fuel components significantly influence the potential risk to groundwater supplies and the methodologies to manage and remediate contamination at fuel release sites. The recognition that MTBE can be more mobile in groundwater systems than other components of oxygenated fuels has put an increased emphasis on early detection and response to fuel leaks and spills. Remediation of oxygenated fuel releases usually follows a sequence of tasks: receptor protection, source control, residual and dissolved phase remediation, and monitored natural attenuation. Good characterization of hydrogeological and geochemical conditions is required because understanding the fate and transport of fuel components is critical to developing an appropriate management plan and an efficient remediation program. Understanding the specific site conditions allows appropriate selection and sequencing of remedial technologies. The physical and chemical characteristics of MTBE can result in a higher mobility in the subsurface, compared with the BTEX components of a gasoline release. These same characteristics make MTBE more readily extractable from the subsurface compared with BTEX. There is an impression that remediating gasoline releases containing MTBE requires costly, specialized technologies compared with those employed to deal with non-oxygenated fuel releases. However, the characteristics of MTBE are well suited to traditional, physical remedial approaches that have proven to be effective with the other components of gasoline. Technologies such as groundwater extraction, soil vapor extraction (SVE), and thermal desorption work exceptionally well with MTBE due to its low adsorptive and high vapor pressure characteristics. Similarly, recent studies have demonstrated that MTBE is biodegradable under a wide variety of conditions

  11. Hanford Site Groundwater Protection Management Program: Revision 1

    International Nuclear Information System (INIS)

    1993-11-01

    Groundwater protection is a national priority that is promulgated in a variety of environmental regulations at local, state, and federal levels. To effectively coordinate and ensure compliance with applicable regulations, the US Department of Energy has issued DOE Order 5400.1 (now under revision) that requires all US Department of Energy facilities to prepare separate groundwater protection program descriptions and plans. This document describes the Groundwater Protection Management Program for the Hanford Site located in the state of Washington. DOE Order 5400.1 specifies that the Groundwater Protection Management Program cover the following general topical areas: (1) documentation of the groundwater regime, (2) design and implementation of a groundwater monitoring program to support resource management and comply with applicable laws and regulations, (3) a management program for groundwater protection and remediation, (4) a summary and identification of areas that may be contaminated with hazardous waste, (5) strategies for controlling these sources, (6) a remedial action program, and (7) decontamination and decommissioning and related remedial action requirements. Many of the above elements are covered by existing programs at the Hanford Site; thus, one of the primary purposes of this document is to provide a framework for coordination of existing groundwater protection activities. Additionally, it describes how information needs are identified and can be incorporated into existing or proposed new programs. The Groundwater Protection Management Program provides the general scope, philosophy, and strategies for groundwater protection/management at the Hanford Site. Subtier documents provide the detailed plans for implementing groundwater-related activities and programs. Related schedule and budget information are provided in the 5-year plan for environmental restoration and waste management at the Hanford Site

  12. Horizontal wells in subsurface remediation

    International Nuclear Information System (INIS)

    Losonsky, G.; Beljin, M.S.

    1992-01-01

    This paper reports on horizontal wells which offer an effective alternative to vertical wells in various environmental remediation technologies. Hydrogeological advantages of horizontal wells over vertical wells include a larger zone of influence, greater screen length, higher specific capacity and lower groundwater screen entrance velocity. Because of these advantages, horizontal wells can reduce treatment time and costs of groundwater recovery (pump-and-treat), in situ groundwater aeration (sparging) and soil gas extraction (vacuum extraction). Horizontal wells are also more effective than vertical wells in landfill leachate collection (under-drains), bioremediation, and horizontal grout injection

  13. Tier 2 guidelines and remediation of Tebuthiuron on a native prairie site

    Energy Technology Data Exchange (ETDEWEB)

    Bessie, K.; Harckham, N.; Dance, T. [EBA Engineering Consultants Ltd., Calgary, AB (Canada); Burk, A. [EnCana Corp., Calgary, AB (Canada); Stephenson, G. [Stantec Consulting, Guelph, ON (Canada); Corbet, B. [Access Analytical Laboratories Inc., Calgary, AB (Canada)

    2009-10-01

    Tebuthiuron is a sterilant used to control vegetation at upstream and midstream petroleum sites. This article discussed the remediation processes used to reclaim a native prairie site contaminated with tebuthiuron. The site was located within a dry mixed grass natural area. A literature review was conducted to establish soil eco-contact guidelines specific to tebuthiuron. A site-specific ecotoxicity assessment was then conducted using a liquid chromatograph to detect tebuthiuron limits in the contaminated soils. A soil sampling technique was used to delineate the affected areas at the site. Site soils were spiked with various concentrations of tebuthiuron ranging from 0.00003 mg/kg to 3000 mg/kg. Test species included a Folsomia candida, an earthworm, and 4 plant species. The study showed that the invertebrate species were less sensitive to tebuthiuron than the plant species. A groundwater assessment showed that tebuthiuron levels exceeded Tier 1 groundwater remediation guidelines. A multilayer hydro-geological model showed that remediation guidelines were orders of magnitude greater than Tier 1 groundwater remediation. A thermal desorption technique was used to remediate the site. 7 refs., 8 figs.

  14. World-first PRB remediation system

    International Nuclear Information System (INIS)

    Mundle, Keely

    2013-01-01

    Full text: The permeable reactive barrier (PRB) project in question was a former waste control site at Bellevue in Western Australia, which burned down in 2001. The fire and the site's historic use as a liquid waste treatment plant created a plume of contaminated groundwater as well as a secondary offsite plume of chlorinated solvents. Damage from the fire and historical use caused the contamination to extend 200m downgradient of the site, under several nearby parcels of land and migrating in the direction of the nearby Helena River. Two areas of chlorinated solvents were identified as residual dense non-aqueous phase liquid (DNAPL) in the unsaturated zone, including concentrations of trichloroethene (TCE) at 1000 micrograms per litre (μg/L) in groundwater, which needed to be reduced to concentrations of around 330μg/L before the groundwater discharged into the river. Complete source removal of DNAPL contamination - such as TCE - in the environment can be difficult and costly. Partial source removal of the contamination may not have a significant impact on the extent of the plume but may reduce its longevity. Treatment of the contaminant plume is more achievable and allows for more time to develop an effective source remediation solution if it is required. Zero-valent iron (ZVI), a non-toxic granular material placed in PRBs, has been proven to be successful in removing a broad range of contaminants, including many chlorinated solvents such as TCE. In a ZVI-based PRB, the system uses the natural groundwater flow to channel contaminants to an engineered treatment area. As groundwater passes through the PRB, contaminants are treated in the barrier and remediated water flows out the other side. There are two primary pathways for the dechlorination of chlorinated ethenes in ZVI PRBs: beta-elimination and hydrogenolysis. Experiments have shown the dominant degradation pathway is p-elimination. This pathway is preferred as it results in the chlorinated ethene

  15. ELECTROCHEMICAL REMEDIATION OF ARSENIC-CONTAMINATED GROUNDWATER — RESULTS OF PROTOTYPE FIELD TESTS IN BANGLADESH

    Energy Technology Data Exchange (ETDEWEB)

    Kowolik, K; Addy, S.E.A.; Gadgil, A.

    2009-01-01

    According to the World Health Organization (WHO), more than 50 million people in Bangladesh drink arsenic-laden water, making it the largest case of mass poisoning in human history. Many methods of arsenic removal (mostly using chemical adsorbents) have been studied, but most of these are too expensive and impractical to be implemented in poor countries such as Bangladesh. This project investigates ElectroChemical Arsenic Remediation (ECAR) as an affordable means of removing arsenic. Experiments were performed on site in Bangladesh using a prototype termed “sushi”. This device consists of carbon steel sheets that serve as electrodes wrapped into a cylinder, separated by plastic mesh and surrounded by a tube-like container that serves as a holding cell in which the water is treated electrochemically. During the electrochemical process, current is applied to both electrodes causing iron to oxidize to various forms of iron (hydr)oxides. These species bind to arsenic(V) with very high affi nity. ECAR also has the advantage that As(III), the more toxic form of arsenic, oxidizes to As(V) in situ. Only As(V) is known to complex with iron (hydr)oxides. One of the main objectives of this research is to demonstrate the ability of the new prototype to reduce arsenic concentrations in Bangladesh groundwater from >200 ppb to below the WHO limit of 10 ppb. In addition, varying fl ow rate and dosage and the effect on arsenic removal was investigated. Experiments showed that ECAR reduced Bangladeshi water with an initial arsenic concentration as high as 250 ppb to below 10 ppb. ECAR proved to be effective at dosages as high as 810 Coulombs/Liter (C/L) and as low as 386 C/L (current 1 A, voltage 12 V). These results are encouraging and provide great promise that ECAR is an effi cient method in the remediation of arsenic from contaminated groundwater. A preliminary investigation of arsenic removal trends with varying Coulombic dosage, complexation time and fi ltration methods is

  16. Laboratory evaluation of the in situ chemical treatment approach to soil and groundwater remediation

    International Nuclear Information System (INIS)

    Thorton, E.C.; Trader, D.E.

    1993-10-01

    Results of initial proof of principle laboratory testing activities successfully demonstrated the viability of the in situ chemical treatment approach for remediation of soil and groundwater contaminated by hexavalent chromium. Testing activities currently in progress further indicate that soils contaminated with hexavalent chromium and uranium at concentrations of several hundred parts per million can be successfully treated with 100 ppM hydrogen sulfide gas mixtures. Greater than 90% immobilization of hexavalent chromium and 50% immobilization of uranium have been achieved in these tests after a treatment period of one day. Activities associated with further development and implementation of the in situ chemical treatment approach include conducting additional bench scale tests with contaminated geomedia, and undertaking scale-up laboratory tests and a field demonstration. This report discusses the testing and further development of this process

  17. Technical approach to finalizing sensible soil cleanup levels at the Fernald Environmental Management Project

    International Nuclear Information System (INIS)

    Carr, D.; Hertel, B.; Jewett, M.; Janke, R.; Conner, B.

    1996-01-01

    The remedial strategy for addressing contaminated environmental media was recently finalized for the US Department of Energy's (DOE) Fernald Environmental Management Project (FEMP) following almost 10 years of detailed technical analysis. The FEMP represents one of the first major nuclear facilities to successfully complete the Remedial Investigation/Feasibility Study (RI/FS) phase of the environmental restoration process. A critical element of this success was the establishment of sensible cleanup levels for contaminated soil and groundwater both on and off the FEMP property. These cleanup levels were derived based upon a strict application of Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) regulations and guidance, coupled with positive input from the regulatory agencies and the local community regarding projected future land uses for the site. The approach for establishing the cleanup levels was based upon a Feasibility Study (FS) strategy that examined a bounding range of viable future land uses for the site. Within each land use, the cost and technical implications of a range of health-protective cleanup levels for the environmental media were analyzed. Technical considerations in driving these cleanup levels included: direct exposure routes to viable human receptors; cross- media impacts to air, surface water, and groundwater; technical practicality of attaining the levels; volume of affected media; impact to sensitive environmental receptors or ecosystems; and cost. This paper will discuss the technical approach used to support the finalization of the cleanup levels for the site. The final cleanup levels provide the last remaining significant piece to the puzzle of establishing a final site-wide remedial strategy for the FEMP, and positions the facility for the expedient completion of site-wide remedial activities

  18. Screening Assessment of Radionuclide Migration in Groundwater from the “Dneprovskoe” Tailings Impoundment (Dneprodzerzhynsk City) and Evaluation of Remedial Options

    Energy Technology Data Exchange (ETDEWEB)

    Skalskyi, O.; Bugai, D. [Institute of Geological Sciences, National Academy of Sciences of Ukraine (Ukraine); Ryazantsev, V. [State Nuclear Regularity Committee of Ukraine, Kiev (Ukraine)

    2014-05-15

    The paper presents results of mathematical modeling of the hydrogeological conditions at the “Dneprovskoe” (“D”) tailings impoundment –object of the former industrial association of “Pridneprovsky Chemical Plant”, which contains uranium ore processing wastes. This radioactively polluted site is located in a densely populated region (at the outskirts of Dneprodzerginsk City) near the major watercourse of the Ukraine — Dnieper River.The mathematical modeling utilized Visual Modflow (for groundwater flow) and Ecolego (Facilia AB, Sweden) radioecology modeling software (for radionuclide transport).Modeling results indicate the possibility of essential radioactive contamination in future of the phreatic aquifer in alluvial deposits between the “D” tailings and the Dnieper River (mainly due to migration of uranium). Therefore long-term management strategies should preclude water usage from the aquifer in the zone of the in-fluence of the “D” tailings. Filtration discharge of uranium to the Dnepr River does not represent a significant risk due to large dilution by surface waters. The important modeling conclusion is that besides the uranium ore processing wastes inside the tailings, the major source of radionuclide migration to groundwater is represented by contaminated geological deposits below the tailings. This last source was formed due to leakage of wastewaters during the operational period of the “D” tailings (1954–1968). Therefore an exemption and re-disposal of wastes from the “D” tailings to a more safe storage location (proposed by some remedial plans) will not provide significant benefit from the viewpoint of minimizing of radionuclide transport to the groundwater and Dnieper River (especially in short-and medium-term perspective). The rational remedial strategy for the “D” tailings is conservation of tailing wastes in-situ by means of specially designed “zero flux” soil screen, which would minimize infiltration of

  19. Final audit report of remedial action construction at the UMTRA Project Mexican Hat, Utah -- Monument Valley, Arizona, sites

    International Nuclear Information System (INIS)

    1995-10-01

    The final audit report for remedial action at the Mexican Hat, Utah, Monument Valley, Arizona, Uranium Mill Tailings Remedial Action (UMTRA) Project sites consists of a summary of the radiological surveillances/audits, quality assurance (QA) in-process surveillances, and QA remedial action close-out inspections performed by the US Department of Energy (DOE) and the Technical Assistance Contractor (TAC); on-site construction reviews (OSCR) performed by the US Nuclear Regulatory Commission (NRC); and a surveillance performed by the Navajo Nation. This report refers to remedial action activities performed at the Mexican Hat, Utah--Monument Valley, Arizona, Uranium Mill Tailings Remedial Action (UMTRA) Project sites

  20. Evaluation of select trade-offs between ground-water remediation and waste minimization for petroleum refining industry

    International Nuclear Information System (INIS)

    Andrews, C.D.; McTernan, W.F.; Willett, K.K.

    1996-01-01

    An investigation comparing environmental remediation alternatives and attendant costs for a hypothetical refinery site located in the Arkansas River alluvium was completed. Transport from the land's surface to and through the ground water of three spill sizes was simulated, representing a base case and two possible levels of waste minimization. Remediation costs were calculated for five alternative remediation options, for three possible regulatory levels and alternative site locations, for four levels of technology improvement, and for eight different years. It is appropriate from environmental and economic perspectives to initiate significant efforts and expenditures that are necessary to minimize the amount and type of waste produced and disposed during refinery operations; or conversely, given expected improvements in technology, is it better to wait until remediation technologies improve, allowing greater environmental compliance at lower costs? The present work used deterministic models to track a light nonaqueous phase liquid (LNAPL) spill through the unsaturated zone to the top of the water table. Benzene leaching from LNAPL to the ground water was further routed through the alluvial aquifer. Contaminant plumes were simulated over 50 yr of transport and remediation costs assigned for each of the five treatment options for each of these years. The results of these efforts show that active remediation is most cost effective after a set point or geochemical quasi-equilibrium is reached, where long-term improvements in technology greatly tilt the recommended option toward remediation. Finally, the impacts associated with increasingly rigorous regulatory levels present potentially significant penalties for the remediation option, but their likelihood of occurrence is difficult to define

  1. Superfund Record of Decision (EPA Region 9): North Hollywood/Burbank Well Field Area 1, San Fernando Valley Site, California (first remedial action), September 1987. Final report

    Energy Technology Data Exchange (ETDEWEB)

    1987-09-24

    The North Hollywood - Burbank Well Field (NHBWF) is located within the San Fernando Valley Ground Water basin, which can provide drinking water for approximately 500,000 people residing in the San Fernando Valley and Los Angeles. In 1980 TCE and PCE were discovered in 25% of DWP's wells. In July 1981, DWP and the Southern California Association of Governments began a two-year study funded by EPA. The study revealed the occurrence of ground-water contamination plume patterns that are spreading toward the southeast. The primary contaminant of concern to the ground-water is TCE with PCE and other VOCs present. The selected remedial action for the site is ground-water pump and treatment using aeration and granular-activated-carbon - air-filtering units, with discharge to the DWP Pumping Station for chlorination and distribution. Spent carbon will be removed and replaced with fresh carbon, with the spent carbon scheduled either for disposal or regeneration. The estimated capital cost for this remedial action is $2,192,895 with present worth OandM of $2,284,105.

  2. Tank Waste Remediation System, Hanford Site, Richland, Washington. Final Environmental Impact Statement. Volume II

    International Nuclear Information System (INIS)

    1996-08-01

    This document, Volume 2, provides the inventory of waste addressed in this Final Environmental Impact Statement (EIS) for the Tank Waste Remediation System, Hanford Site, Richland, Washington. The inventories consist of waste from the following four groups: (1) Tank waste; (2) Cesium (Cs) and Strontium (Sr) capsules; (3) Inactive miscellaneous underground storage tanks (MUSTs); and (4) Anticipated future tank waste additions. The major component by volume of the overall waste is the tank waste inventory (including future tank waste additions). This component accounts for more than 99 percent of the total waste volume and approximately 70 percent of the radiological activity of the four waste groups identified previously. Tank waste data are available on a tank-by-tank basis, but the accuracy of these data is suspect because they primarily are based on historical records of transfers between tanks rather than statistically based sampling and analyses programs. However, while the inventory of any specific tank may be suspect, the overall inventory for all of the tanks combined is considered more accurate. The tank waste inventory data are provided as the estimated overall chemical masses and radioactivity levels for the single-shell tanks (SSTs) and double-shell tanks (DSTs). The tank waste inventory data are broken down into tank groupings or source areas that were developed for analyzing groundwater impacts

  3. An economic decision framework using modeling for improving aquifer remediation design

    International Nuclear Information System (INIS)

    James, B.R.; Gwo, J.P.; Toran, L.E.

    1995-11-01

    Reducing cost is a critical challenge facing environmental remediation today. One of the most effective ways of reducing costs is to improve decision-making. This can range from choosing more cost- effective remediation alternatives (for example, determining whether a groundwater contamination plume should be remediated or not) to improving data collection (for example, determining when data collection should stoop). Uncertainty in site conditions presents a major challenge for effective decision-making. We present a framework for increasing the effectiveness of remedial design decision-making at groundwater contamination sites where there is uncertainty in many parameters that affect remediation design. The objective is to provide an easy-to-use economic framework for making remediation decisions. The presented framework is used to 1) select the best remedial design from a suite of possible ones, 2) estimate if additional data collection is cost-effective, and 3) determine the most important parameters to be sampled. The framework is developed by combining elements from Latin-Hypercube simulation of contaminant transport, economic risk-cost-benefit analysis, and Regional Sensitivity Analysis (RSA)

  4. Challenges in subsurface in situ remediation of chlorinated solvents

    DEFF Research Database (Denmark)

    Broholm, Mette Martina; Fjordbøge, Annika Sidelmann; Christiansen, Camilla Maymann

    2014-01-01

    Chlorinated solvent source zones in the subsurface pose a continuous threat to groundwater quality at many sites worldwide. In situ remediation of these sites is particularly challenging in heterogeneous fractured media and where the solvents are present as DNAPL. In situ remediation by chemical...

  5. Rhizofiltration using sunflower (Helianthus annuus L.) and bean (Phaseolus vulgaris L. var. vulgaris) to remediate uranium contaminated groundwater

    International Nuclear Information System (INIS)

    Lee, Minhee; Yang, Minjune

    2010-01-01

    The uranium removal efficiencies of rhizofiltration in the remediation of groundwater were investigated in lab-scale experiments. Sunflower (Helianthus annuus L.) and bean (Phaseolus vulgaris L. var. vulgaris) were cultivated and an artificially uranium contaminated solution and three genuine groundwater samples were used in the experiments. More than 80% of the initial uranium in solution and genuine groundwater, respectively, was removed within 24 h by using sunflower and the residual uranium concentration of the treated water was lower than 30 μg/L (USEPA drinking water limit). For bean, the uranium removal efficiency of the rhizofiltration was roughly 60-80%. The maximum uranium removal via rhizofiltration for the two plant cultivars occurred at pH 3-5 of solution and their uranium removal efficiencies exceeded 90%. The lab-scale continuous rhizofiltration clean-up system delivered over 99% uranium removal efficiency, and the results of SEM and EDS analyses indicated that most uranium accumulated in the roots of plants. The present results suggested that the uranium removal capacity of two plants evaluated in the clean-up system was about 25 mg/kg of wet plant mass. Notably, the removal capacity of the root parts only was more than 500 mg/kg.

  6. Rhizofiltration using sunflower (Helianthus annuus L.) and bean (Phaseolus vulgaris L. var. vulgaris) to remediate uranium contaminated groundwater

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Minhee, E-mail: heelee@pknu.ac.kr [Department of Environmental Geosciences, Pukyong National University, 599-1 Daeyondong, Namgu, Busan 608-737 (Korea, Republic of); Yang, Minjune [Department of Environmental Geosciences, Pukyong National University, 599-1 Daeyondong, Namgu, Busan 608-737 (Korea, Republic of)

    2010-01-15

    The uranium removal efficiencies of rhizofiltration in the remediation of groundwater were investigated in lab-scale experiments. Sunflower (Helianthus annuus L.) and bean (Phaseolus vulgaris L. var. vulgaris) were cultivated and an artificially uranium contaminated solution and three genuine groundwater samples were used in the experiments. More than 80% of the initial uranium in solution and genuine groundwater, respectively, was removed within 24 h by using sunflower and the residual uranium concentration of the treated water was lower than 30 {mu}g/L (USEPA drinking water limit). For bean, the uranium removal efficiency of the rhizofiltration was roughly 60-80%. The maximum uranium removal via rhizofiltration for the two plant cultivars occurred at pH 3-5 of solution and their uranium removal efficiencies exceeded 90%. The lab-scale continuous rhizofiltration clean-up system delivered over 99% uranium removal efficiency, and the results of SEM and EDS analyses indicated that most uranium accumulated in the roots of plants. The present results suggested that the uranium removal capacity of two plants evaluated in the clean-up system was about 25 mg/kg of wet plant mass. Notably, the removal capacity of the root parts only was more than 500 mg/kg.

  7. Cavitational Hydrothermal Oxidation: A New Remediation Process - Final Report; FINAL

    International Nuclear Information System (INIS)

    Suslick, K. S.

    2001-01-01

    During the past year, we have continued to make substantial scientific progress on our understanding of cavitation phenomena in aqueous media and applications of cavitation to remediation processes. Our efforts have focused on three separate areas: sonoluminescence as a probe of conditions created during cavitational collapse in aqueous media, the use of cavitation for remediation of contaminated water, and an addition of the use of ultrasound in the synthesis of novel heterogeneous catalysts for hydrodehalogenation of halocarbons under mild conditions

  8. Record of Decision for Tank Farm Soil and INTEC Groundwater, Operable Unit 3-14

    Energy Technology Data Exchange (ETDEWEB)

    L. S. Cahn

    2007-05-16

    This decision document presents the selected remedy for Operable Unit (OU) 3-14 tank farm soil and groundwater at the Idaho Nuclear Technology and Engineering Center (INTEC), which is located on the Idaho National Laboratory (INL) Site. The tank farm was initially evaluated in the OU 3-13 Record of Decision (ROD), and it was determined that additional information was needed to make a final decision. Additional information has been obtained on the nature and extent of contamination in the tank farm and on the impact to groundwater. The selected remedy was chosen in accordance with the Comprehensive Environmental Response, Liability and Compensation Act of 1980 (CERCLA) (42 USC 9601 et seq.), as amended by the Superfund Amendments and Reauthorization Act of 1986 (Public Law 99-499) and the National Oil and Hazardous Substances Pollution Contingency Plan (40 CFR 300). The selected remedy is intended to be the final action for tank farm soil and groundwater at INTEC. The response action selected in this ROD is necessary to protect the public health, welfare, or the environment from actual or threatened releases of hazardous substances into the environment. Such a release or threat of release may present an imminent and substantial endangerment to public health, welfare, or the environment. The remedial actions selected in this ROD are designed to reduce the potential threats to human health and the environment to acceptable levels. In addition, DOE-ID, EPA, and DEQ (the Agencies) have determined that no action is necessary under CERCLA to protect public health, welfare, or the environment at 16 sites located outside the tank farm boundary. The purposes of the selected remedy are to (1) contain contaminated soil as the radionuclides decay in place, (2) isolate current and future workers and biological receptors from contact with contaminated soil, and (3) restore the portion of Snake River Plain Aquifer contaminated by INTEC releases to Idaho Ground Water Quality

  9. Necessary and Sufficient Standards Closure Process pilot: F- and H-Area groundwater remediation

    International Nuclear Information System (INIS)

    Bullington, M.

    1995-01-01

    The DOE Standards Committee's Necessary and Sufficient (N and S) Standards Closure Process was piloted at SRS on the F- and H- Area Seepage Basins Groundwater Remediation Project. For this existing Environmental Restoration project, the set of N and S standards for design and safety documentation were identified, independently confirmed and approved. Implementation of these standards on the project can lead to a $2.8 Million cost savings on the design, construction/installation, and safety documentation scope of $18 Million. These savings were primarily from site design of power distribution and piping for the water treatment units. Also contributing to the savings were a more appropriate level of safety documentation and the alternate ''commercial'' bids made by vendors in response to a request for proposals for water treatment units. The use of the N and S Process on an ER activity, details on the cost savings, lessons learned and recommendations for broader implementation of the N and S Process are described herein

  10. Technical assistance contractor Management Plan. Final [report

    Energy Technology Data Exchange (ETDEWEB)

    1993-09-01

    The Technical Assistance Contractor (TAC) for the Uranium Mill Tailings Remedial Action (UMTRA) Project comprises Jacobs Engineering Group Inc. (JEG) and its major teaming partners [Roy F. Weston, Inc. (RFW), Sergent, Hauskins & Beckwith Agra, Inc. (SHB Agra), and Geraghty & Miller, Inc. (G&M)]. The first three companies have worked together effectively on the UMTRA Project for more than 10 years. With the initiation of the UMTRA Groundwater Project in April 1991, a need arose to increase the TAC`s groundwater technical breadth and depth, so G&M was brought in to augment the team`s capabilities. The TAC contract`s scope is to provide technical, analytical, environmental, engineering, design, inspection, and management support services to the US Department of Energy (DOE) for both surface and groundwater projects. The TAC team continues to support the DOE in completing surface remedial actions and initiating groundwater remediation work for start-up, characterization, design, construction oversight, and remedial operations. A key feature of the TAC`s management approach is the extensive set of communication systems implemented for the UMTRA Project. These systems assist all functional disciplines in performing UMTRA Project tasks associated with management, technical support, administrative support, and financial/project controls.

  11. The 100-C-7 Remediation Project. An Overview of One of DOE's Largest Remediation Projects - 13260

    International Nuclear Information System (INIS)

    Post, Thomas C.; Strom, Dean; Beulow, Laura

    2013-01-01

    The U.S. Department of Energy Richland Operations Office (RL), U.S. Environmental Protection Agency (EPA) and Washington Closure Hanford LLC (WCH) completed remediation of one of the largest waste sites in the U.S. Department of Energy complex. The waste site, 100-C-7, covers approximately 15 football fields and was excavated to a depth of 85 feet (groundwater). The project team removed a total of 2.3 million tons of clean and contaminated soil, concrete debris, and scrap metal. 100-C-7 lies in Hanford's 100 B/C Area, home to historic B and C Reactors. The waste site was excavated in two parts as 100-C-7 and 100-C-7:1. The pair of excavations appear like pit mines. Mining engineers were hired to design their tiered sides, with safety benches every 17 feet and service ramps which allowed equipment access to the bottom of the excavations. The overall cleanup project was conducted over a span of almost 10 years. A variety of site characterization, excavation, load-out and sampling methodologies were employed at various stages of remediation. Alternative technologies were screened and evaluated during the project. A new method for cost effectively treating soils was implemented - resulting in significant cost savings. Additional opportunities for minimizing waste streams and recycling were identified and effectively implemented by the project team. During the final phase of cleanup the project team applied lessons learned throughout the entire project to address the final, remaining source of chromium contamination. The C-7 cleanup now serves as a model for remediating extensive deep zone contamination sites at Hanford. (authors)

  12. Effect of increased groundwater viscosity on the remedial performance of surfactant-enhanced air sparging

    Science.gov (United States)

    Choi, Jae-Kyeong; Kim, Heonki; Kwon, Hobin; Annable, Michael D.

    2018-03-01

    The effect of groundwater viscosity control on the performance of surfactant-enhanced air sparging (SEAS) was investigated using 1- and 2-dimensional (1-D and 2-D) bench-scale physical models. The viscosity of groundwater was controlled by a thickener, sodium carboxymethylcellulose (SCMC), while an anionic surfactant, sodium dodecylbenzene sulfonate (SDBS), was used to control the surface tension of groundwater. When resident DI water was displaced with a SCMC solution (500 mg/L), a SDBS solution (200 mg/L), and a solution with both SCMC (500 mg/L) and SDBS (200 mg/L), the air saturation for sand-packed columns achieved by air sparging increased by 9.5%, 128%, and 154%, respectively, (compared to that of the DI water-saturated column). When the resident water contained SCMC, the minimum air pressure necessary for air sparging processes increased, which is considered to be responsible for the increased air saturation. The extent of the sparging influence zone achieved during the air sparging process using the 2-D model was also affected by viscosity control. Larger sparging influence zones (de-saturated zone due to air injection) were observed for the air sparging processes using the 2-D model initially saturated with high-viscosity solutions, than those without a thickener in the aqueous solution. The enhanced air saturations using SCMC for the 1-D air sparging experiment improved the degradative performance of gaseous oxidation agent (ozone) during air sparging, as measured by the disappearance of fluorescence (fluorescein sodium salt). Based on the experimental evidence generated in this study, the addition of a thickener in the aqueous solution prior to air sparging increased the degree of air saturation and the sparging influence zone, and enhanced the remedial potential of SEAS for contaminated aquifers.

  13. ANALYSIS OF REMEDIATION PROCESS OF THE GROUDWATER COTAMINATION IN AN ILLEGAL DUMPING SITE

    Science.gov (United States)

    Nishida, Norikazu; Furuichi, Toru; Ishii, Kazuei

    Among on-site remediation technologies applied to illegal dumping sites, a technology to remedy contaminated groundwater without removal of the dumped waste is expected to provide a great opportunity to fulfill a societal need due to its economic advantage compared to removal of all waste. However heterogeneously-distributed waste makes the remedial process difficult. In this study, an in situflushing technology was applied to an illegal dumping site in Kuwana city, Mie, in order to remedy groundwater contaminated with several volatile organic compounds (VOCs) within five years. The key to successfully achieve the target was to conduct a series of advanced remediation processes; introducing a new indicator by which multiple VOCs can be estimated integratelly, monitoring the progress of remediation with a contour map of VOC concentration as well as the weighted averages of the concentration derived from the indicator, pinpointing residual contaminants area, reexamining the plan, and taking additional steps that promote further remediation.

  14. In situ bioremediation of Hanford groundwater

    International Nuclear Information System (INIS)

    Skeen, R.S.; Roberson, K.R.; Workman, D.J.; Petersen, J.N.; Shouche, M.

    1992-04-01

    Liquid wastes containing radioactive, hazardous, and regulated chemicals have been generated throughout the 40+ years of operations at the US Department of Energy's (DOE) Hanford Site. Some of these wastes were discharged to the soil column and many of the waste components, including nitrate, carbon tetrachloride (CCl 4 ), and several radionuclides, have been detected in the Hanford groundwater. Current DOE policy prohibits the disposal of contaminated liquids directly to the environment, and remediation of existing contaminated groundwaters may be required. In situ bioremediation is one technology currently being developed at Hanford to meet the need for cost effective technologies to clean groundwater contaminated with CCl 4 , nitrate, and other organic and inorganic contaminants. This paper focuses on the latest results of an on going effort to develop effective in situ remediation strategies through the use of predictive simulations

  15. In-situ treatment of hydrocarbons contamination through enhanced bio-remediation and two phase extraction system

    International Nuclear Information System (INIS)

    Aglietto, I.; Brunero Bronzin, M.

    2005-01-01

    It happens frequently to find industrial site affected by contamination of subsoil and groundwater with consequent presence of free phase product floating on the water table. The remediation technologies in this case shall be properly selected and coordinated in a way that the interactions between each activities will help to decontaminate the site. The case study deals with an industrial site located near Turin, in Italy, of about 50 hectares of extension where has been found an area of about 4000 square meters with contamination of subsoil and groundwater. The compounds with higher concentrations are petroleum hydrocarbons found both in soil and in groundwater. Another big problem is represented by the presence of a layer of free product floating on the water table with a maximum measured thickness of 70 cm; this situation can be considered in fact one of the major difficulty in management of selected remediation technologies because the complete recover of the free phase is a priority for any kind of remediation system to apply subsequently. The present work is based upon the selection and implementation of a multiple treatment for definitive remediation of subsoil and groundwater. Free product recovery has been faced with a two-phase extraction technology, then for the remediation of subsoil we implemented a bio-venting system to improve biodegradation processes and finally for groundwater treatment we apply an enhanced in situ bio-remediation injecting oxygen release compounds directly into the aquifer. To reach these choices we have to pass through a complex activity of investigation of the site made up of more than 40 sampling point, 8 monitoring wells, about 140 analysis on subsoil samples and 10 on groundwater samples and one well used for an aquifer test. The preliminary design of the remediation system was therefore based on an extensive site characterization that included geological and geochemical, microbiological and hydrological data, together with

  16. In Situ Remediation Integrated Program: Technology summary

    International Nuclear Information System (INIS)

    1994-02-01

    The In Situ Remediation Integrated Program (ISR IP) was instituted out of recognition that in situ remediation could fulfill three important criteria: significant cost reduction of cleanup by eliminating or minimizing excavation, transportation, and disposal of wastes; reduced health impacts on workers and the public by minimizing exposure to wastes during excavation and processing; and remediation of inaccessible sites, including: deep subsurfaces, in, under, and around buildings. Buried waste, contaminated soils and groundwater, and containerized wastes are all candidates for in situ remediation. Contaminants include radioactive wastes, volatile and non-volatile organics, heavy metals, nitrates, and explosive materials. The ISR IP intends to facilitate development of in situ remediation technologies for hazardous, radioactive, and mixed wastes in soils, groundwater, and storage tanks. Near-term focus is on containment of the wastes, with treatment receiving greater effort in future years. ISR IP is an applied research and development program broadly addressing known DOE environmental restoration needs. Analysis of a sample of 334 representative sites by the Office of Environmental Restoration has shown how many sites are amenable to in situ remediation: containment--243 sites; manipulation--244 sites; bioremediation--154 sites; and physical/chemical methods--236 sites. This needs assessment is focused on near-term restoration problems (FY93--FY99). Many other remediations will be required in the next century. The major focus of the ISR EP is on the long term development of permanent solutions to these problems. Current needs for interim actions to protect human health and the environment are also being addressed

  17. In Situ Remediation Integrated Program: Technology summary

    Energy Technology Data Exchange (ETDEWEB)

    1994-02-01

    The In Situ Remediation Integrated Program (ISR IP) was instituted out of recognition that in situ remediation could fulfill three important criteria: significant cost reduction of cleanup by eliminating or minimizing excavation, transportation, and disposal of wastes; reduced health impacts on workers and the public by minimizing exposure to wastes during excavation and processing; and remediation of inaccessible sites, including: deep subsurfaces, in, under, and around buildings. Buried waste, contaminated soils and groundwater, and containerized wastes are all candidates for in situ remediation. Contaminants include radioactive wastes, volatile and non-volatile organics, heavy metals, nitrates, and explosive materials. The ISR IP intends to facilitate development of in situ remediation technologies for hazardous, radioactive, and mixed wastes in soils, groundwater, and storage tanks. Near-term focus is on containment of the wastes, with treatment receiving greater effort in future years. ISR IP is an applied research and development program broadly addressing known DOE environmental restoration needs. Analysis of a sample of 334 representative sites by the Office of Environmental Restoration has shown how many sites are amenable to in situ remediation: containment--243 sites; manipulation--244 sites; bioremediation--154 sites; and physical/chemical methods--236 sites. This needs assessment is focused on near-term restoration problems (FY93--FY99). Many other remediations will be required in the next century. The major focus of the ISR EP is on the long term development of permanent solutions to these problems. Current needs for interim actions to protect human health and the environment are also being addressed.

  18. Bioremediation of Uranium-Contaminated Groundwater using Engineered Injection and Extraction

    Science.gov (United States)

    Greene, J. A.; Neupauer, R.; Ye, M.; Kasprzyk, J. R.; Mays, D. C.; Curtis, G. P.

    2017-12-01

    During in-situ remediation of contaminated groundwater, a treatment chemical is injected into the contaminated groundwater to react with and degrade the contaminant, with reactions occurring where the treatment chemical contacts the contaminant. Traditional in-situ groundwater remediation relies on background groundwater flow for spreading of treatment chemicals into contaminant plumes. Engineered Injection and Extraction (EIE), in which time-varying induced flow fields are used to actively spread the treatment chemical into the contaminant plume, has been developed to increase contact between the contaminant and treatment chemical, thereby enhancing contaminant degradation. EIE has been investigated for contaminants that degrade through irreversible bimolecular reaction with a treatment chemical, but has not been investigated for a contaminant governed by reversible reactions. Uranium primarily occurs in its aqueous, mobile form, U(VI), in the environment but can be bioreduced to its sparingly soluble, immobile form, U(IV), by iron reducing bacteria stimulated by an acetate amendment. In this study, we investigate the ability of EIE to facilitate and sustain favorable conditions to immobilize uranium during remediation, and to prevent re-mobilization of uranium into the aqueous phase after active remediation has ended. Simulations in this investigation are conducted using a semi-synthetic model based on physical and chemical conditions at the Naturita Uranium Mill Tailings Remedial Action (UMTRA) site in southwestern Colorado and the Old Rifle UMTRA site in western Colorado. The EIE design is optimized for the synthetic model using the Borg multi-objective evolutionary algorithm.

  19. Modeling groundwater flow at the chemical plant area of the Weldon Spring Site

    International Nuclear Information System (INIS)

    Durham, L.A.

    1992-10-01

    Groundwater flow in the shallow unconfined aquifer at the chemical plant area of the Weldon Spring site, St. Charles County, Missouri, was modeled with the Coupled Fluid, Energy, and Solute Transport (CFEST) groundwater flow and contaminant transport computer code. The modeling was performed in support of a hydrogeological characterization effort that is part of the remedial investigation/feasibility study-environmental impact statement process being carried out by the US Department of Energy at the site. This report presents the results of model development and calibration. In the calibration procedure, the range of field-measured hydrogeological parameters was tested to obtain the best match between model-predicted and measured groundwater elevations. After calibration, the model was used to evaluate whether the presence of an on-site disposal cell would impact the ability to remediate contaminated groundwater beneath the cell. The results of the numerical modeling, which were based on an evaluation of steady-state groundwater flow velocity plots, indicated that groundwater would flow beneath the disposal cell along natural gradients. The presence of a disposal cell would not significantly affect remediation capability for groundwater contamination

  20. Rate of Contamination Removal of Two Phyto-remediation Sites at the DOE Portsmouth Gaseous Diffusion Plant

    International Nuclear Information System (INIS)

    Lewis, A.C.; Baird, D.R.

    2006-01-01

    This paper describes applications of phyto-remediation at the Portsmouth Gaseous Diffusion Plant (PORTS), a Department of Energy (DOE) Facility that enriched uranium from the early 1950's until 2000. Phyto-remediation has been implemented to assist in the removal of TCE (trichloroethylene) in the groundwater at two locations at the PORTS facility: the X-740 area and the X-749/X-120 area. Phyto-remediation technology is based on the ability of certain plants species (in this case hybrid poplar trees) and their associated rhizo-spheric microorganisms to remove, degrade, or contain chemical contaminants located in the soil, sediment, surface water, groundwater, and possibly even the atmosphere. Phyto-remediation technology is a promising clean-up solution for a wide variety of pollutants and sites. Mature trees, such as the hybrid poplar, can consume up to 3,000 gallons of groundwater per acre per day. Organic compounds are captured in the trees' root systems. These organic compounds are degraded by ultraviolet light as they are transpired along with the water vapor through the leaves of the trees. The phyto-remediation system at the X-740 area encompasses 766 one-year old hybrid poplar trees (Populus nigra x nigra, Populus nigra x maximowiczii, and Populus deltoides x nigra) that were planted 10 feet apart in rows 10 feet to 20 feet apart, over an area of 2.6 acres. The system was installed to manage the VOC contaminant plume. At the X749/X-120 area, a phyto-remediation system of 2,640 hybrid poplar trees (Populus nigra x maximowiczii) was planted in seven areas/zones to manage the VOC contaminant plume. The objectives of these systems are to remove contamination from the groundwater and to prevent further migration of contaminants. The goal of these remediation procedures is to achieve completely mature and functional phyto-remediation systems within two years of the initial planting of the hybrid poplar trees at each planting location. There is a direct

  1. Remediation of sites with dispersed radioactive contamination

    International Nuclear Information System (INIS)

    2004-01-01

    To respond to the needs of Member States, the IAEA launched an environmental remediation project to deal with the problems of radioactive contamination worldwide. The IAEA environmental remediation project includes an IAEA Coordinated Research Project, as well as the participation of IAEA experts in concrete remediation projects when requested by individual Member States. The IAEA has prepared several documents dedicated to particular technical or conceptual areas, including documents on the characterization of contaminated sites, technical and non-technical factors relevant to the selection of a preferred remediation strategy and technique, overview of applicable techniques for environmental remediation,, options for the cleanup of contaminated groundwater and planning and management issues. In addition, a number of other IAEA publications dealing with related aspects have been compiled under different IAEA projects; these include TECDOCs on the remediation of uranium mill tailings, the decontamination of buildings and roads and the characterization of decommissioned sites. Detailed procedures for the planning and implementation of remedial measures have been developed over the past decade or so. A critical element is the characterization of the contamination and of the various environmental compartments in which it is found, in order to be able to evaluate the applicability of remediation techniques. The chemical or mineralogical form of the contaminant will critically influence the efficiency of the remediation technique chosen. Careful delineation of the contamination will ensure that only those areas or volumes of material that are actually contaminated are treated. This, in turn, reduces the amount of any secondary waste generated. The application of a remediation technique requires holistic studies examining the technical feasibility of the proposed measures, including analyses of their impact. Consequently, input from various scientific and engineering

  2. 200-ZP-1 phase 2 interim remedial measure quarterly report, August--October 1996

    International Nuclear Information System (INIS)

    Freeman-Pollard, J.R.; Jacques, I.D.; McMahon, W.J.; Singleton, K.M.; Strope, S.A.; Swanson, L.C.; Windmueller, C.R.

    1996-11-01

    A groundwater pump-and-treat system is being operated in the 200-ZP-1 Operable Unit under authority of the Hanford Federal Facility Agreement and Consent Order . The purpose of the pump-and-treat system is to accomplish the following: Minimize further migration of the high-concentration portion of the carbon tetrachloride plume and co-contaminants chloroform and trichlorethylene in the 200-ZP-1 Operable Unit Provide data for evaluation of final remedy selection. The 200-ZP-1 pump-and-treat operations were conducted as a pilot-scale treatability test and interim remedial measure treatment system between August 1994 and July 1996 to assess the effectiveness of liquid-phase granular activated carbon carbon tetrachloride removal. The pilot-scale treatability test's removal efficiently was determined to be 99.96% for carbon tetrachloride, chloroform, and trichloroethylene. This report summarizes and evaluates treatment, hydraulic, and hydrochemistry data collected for the 200-ZP-1 interim remedial measure from August through September 1996

  3. Supplemental Assessment of the Y-12 Groundwater Protection Program Using Monitoring and Remediation Optimization System Software

    Energy Technology Data Exchange (ETDEWEB)

    Elvado Environmental LLC; GSI Environmental LLC

    2009-01-01

    A supplemental quantitative assessment of the Groundwater Protection Program (GWPP) at the Y-12 National Security Complex (Y-12) in Oak Ridge, TN was performed using the Monitoring and Remediation Optimization System (MAROS) software. This application was previously used as part of a similar quantitative assessment of the GWPP completed in December 2005, hereafter referenced as the 'baseline' MAROS assessment (BWXT Y-12 L.L.C. [BWXT] 2005). The MAROS software contains modules that apply statistical analysis techniques to an existing GWPP analytical database in conjunction with hydrogeologic factors, regulatory framework, and the location of potential receptors, to recommend an improved groundwater monitoring network and optimum sampling frequency for individual monitoring locations. The goal of this supplemental MAROS assessment of the Y-12 GWPP is to review and update monitoring network optimization recommendations resulting from the 2005 baseline report using data collected through December 2007. The supplemental MAROS assessment is based on the findings of the baseline MAROS assessment and includes only the groundwater sampling locations (wells and natural springs) currently granted 'Active' status in accordance with the Y-12 GWPP Monitoring Optimization Plan (MOP). The results of the baseline MAROS assessment provided technical rationale regarding the 'Active' status designations defined in the MOP (BWXT 2006). One objective of the current report is to provide a quantitative review of data collected from Active but infrequently sampled wells to confirm concentrations at these locations. This supplemental MAROS assessment does not include the extensive qualitative evaluations similar to those presented in the baseline report.

  4. 200 Areas soil remediation strategy -- Environmental Restoration Program

    International Nuclear Information System (INIS)

    1996-09-01

    The remediation and waste management activities in the 200 Areas of the Hanford Site (located in Richland, Washington) currently range from remediating groundwater, remediating source units (contaminated soils), decontaminating and decommissioning of buildings and structures, maintaining facilities, managing transuranic, low-level and mixed waste, and operating tank farms that store high-level waste. This strategy focuses on the assessment and remediation of soil that resulted from the discharge of liquids and solids from processing facilities to the ground (e.g., ponds, ditches, cribs, burial grounds) in the 200 Areas and addresses only those waste sites assigned to the Environmental Restoration Program

  5. Using the natural biodegradation potential of shallow soils for in-situ remediation of deep vadose zone and groundwater.

    Science.gov (United States)

    Avishai, Lior; Siebner, Hagar; Dahan, Ofer; Ronen, Zeev

    2017-02-15

    In this study, we examined the ability of top soil to degrade perchlorate from infiltrating polluted groundwater under unsaturated conditions. Column experiments designed to simulate typical remediation operation of daily wetting and draining cycles of contaminated water amended with an electron donor. Covering the infiltration area with bentonite ensured anaerobic conditions. The soil remained unsaturated, and redox potential dropped to less than -200mV. Perchlorate was reduced continuously from ∼1150mg/L at the inlet to ∼300mg/L at the outlet in daily cycles. Removal efficiency was between 60 and 84%. No signs of bioclogging were observed during three operation months although occasional iron reduction observed due to excess electron donor. Changes in perchlorate reducing bacteria numbers were inferred from an increased in pcrA gene abundances from ∼10 5 to 10 7 copied per gram at the end of the experiment indicating the growth of perchlorate-reducing bacteria. We proposed that the topsoil may serve as a bioreactor to treat high concentrations of perchlorate from the contaminated groundwater. The treated water that infiltrates from the topsoil through the vadose zone could be used to flush perchlorate from the deep vadose zone into the groundwater where it is retrieved again for treatment in the topsoil. Copyright © 2016 Elsevier B.V. All rights reserved.

  6. Final report on Phase II remedial action at the former Middlesex Sampling Plant and associated properties. Volume 2

    International Nuclear Information System (INIS)

    1985-04-01

    Volume 2 presents the radiological measurement data taken after remedial action on properties surrounding the former Middlesex Sampling Plant during Phase II of the DOE Middlesex Remedial Action Program. Also included are analyses of the confirmatory radiological survey data for each parcel with respect to the remedial action criteria established by DOE for the Phase II cleanup and a discussion of the final status of each property. Engineering details of this project and a description of the associated health physics and environmental monitoring activities are presented in Volume 1

  7. Tank Waste Remediation System, Hanford Site, Richland, Washington. Final Environmental Impact Statement. Volume IV

    International Nuclear Information System (INIS)

    1996-08-01

    This document, Volume 4, describes the current safety concerns associated with the tank waste and analyzes the potential accidents and associated potential health effects that could occur under the alternatives included in this Tank Waste Remediation System (TWRS) Final Environmental Impact Statement (EIS) for the Hanford Site, Richland, Washington

  8. Groundwater well services site safety and health plan

    International Nuclear Information System (INIS)

    Tuttle, B.G.

    1996-08-01

    This Site Specific Health and Safety Plan covers well servicing in support of the Environmental Restoration Contractor Groundwater Project. Well servicing is an important part of environmental restoration activities supporting several pump and treat facilities and assisting in evaluation and servicing of various groundwater wells throughout the Hanford Site. Remediation of contaminated groundwater is a major part of the ERC project. Well services tasks help enhance groundwater extraction/injection as well as maintain groundwater wells for sampling and other hydrologic testing and information gathering

  9. Innovative reactive barrier technologies for regional contaminated groundwater

    NARCIS (Netherlands)

    Merkel, P.; Weiβ, H.; Teutsch, G.; Rijnaarts, H.H.M.

    2000-01-01

    At many industrial sites inadequate waste disposal, leakages and war damages have led to severe groundwater contamination on a regional scale. Standard hydraulic groundwater remediation methods, such as pump-and-treat, in most cases do not lead to satisfactory results, due to the persistence of

  10. Explanation of significant differences for the TNX groundwater operable unit

    International Nuclear Information System (INIS)

    Palmer, E.R.

    1997-01-01

    This Explanation of Significant Differences (ESD) is being issued by the Department of Energy (DOE), the lead agency for the Savannah River Site (SRS), with concurrence by the Environmental Protection Agency-Region IV (EPA) and South Carolina Department of Health and Environmental Control (SCDHEC) to announce changes in the interim remediation strategy selected for the TNX Groundwater Operable Unit. The TNX Area is located adjacent to the Savannah River in the southwestern portion of SRS. The remedy selected in the Interim Record of Decision (IROD) to achieve the interim action goals was the Hybrid Groundwater Corrective Action (HGCA). The HGCA consisted of a recirculation well system and an air stripper with a series of groundwater extraction wells. The original remediation strategy needs to be modified because the recirculation well system was determined to be ineffective in this area due to geological factors and the nature of the contamination

  11. Final remediation of the provisional storage near Zavratec

    International Nuclear Information System (INIS)

    Zeleznik, N.; Mele, I.

    2000-01-01

    In the Western part of Slovenia near the village of Zavratec radioactive waste from the decontamination of the Oncological Institute has been stored in an old abandoned military barracks for many decades. The ARAO Agency had been assigned to remediate this provisional storage. In 1996 the first phase of the remediation was concluded, in which the measurements, inventorying and repacking of radioactive waste were carried out. At the end of this phase the waste was restored. After three years of suspension, the remedial work continued in autumn 1999 with the separation of radioactive from non-radioactive waste and transportation of all radioactive waste to the Slovenian central storage for small producers near Ljubljana. At the beginning of the year 2000 the old storage near Zavratec was completely decontaminated to be released for unrestricted use. The preparation for and the implementation of remedial actions are presented in the paper. (author)

  12. The 100-C-7 Remediation Project. An Overview of One of DOE's Largest Remediation Projects - 13260

    Energy Technology Data Exchange (ETDEWEB)

    Post, Thomas C. [U.S. Department of Energy Richland Operations Office, Richland, WA 99352 (United States); Strom, Dean [Washington Closure Hanford LLC, 2620 Fermi Avenue, Richland, WA 99354 (United States); Beulow, Laura [U.S. Environmental Protection Agency, 309 Bradley Boulevard, Suite 115, Richland, WA 99352 (United States)

    2013-07-01

    The U.S. Department of Energy Richland Operations Office (RL), U.S. Environmental Protection Agency (EPA) and Washington Closure Hanford LLC (WCH) completed remediation of one of the largest waste sites in the U.S. Department of Energy complex. The waste site, 100-C-7, covers approximately 15 football fields and was excavated to a depth of 85 feet (groundwater). The project team removed a total of 2.3 million tons of clean and contaminated soil, concrete debris, and scrap metal. 100-C-7 lies in Hanford's 100 B/C Area, home to historic B and C Reactors. The waste site was excavated in two parts as 100-C-7 and 100-C-7:1. The pair of excavations appear like pit mines. Mining engineers were hired to design their tiered sides, with safety benches every 17 feet and service ramps which allowed equipment access to the bottom of the excavations. The overall cleanup project was conducted over a span of almost 10 years. A variety of site characterization, excavation, load-out and sampling methodologies were employed at various stages of remediation. Alternative technologies were screened and evaluated during the project. A new method for cost effectively treating soils was implemented - resulting in significant cost savings. Additional opportunities for minimizing waste streams and recycling were identified and effectively implemented by the project team. During the final phase of cleanup the project team applied lessons learned throughout the entire project to address the final, remaining source of chromium contamination. The C-7 cleanup now serves as a model for remediating extensive deep zone contamination sites at Hanford. (authors)

  13. Current Conditions Risk Assessment for the 300-FF-5 Groundwater Operable Unit

    Energy Technology Data Exchange (ETDEWEB)

    Miley, Terri B.; Bunn, Amoret L.; Napier, Bruce A.; Peterson, Robert E.; Becker, James M.

    2007-11-01

    This report updates a baseline risk assessment for the 300 Area prepared in 1994. The update includes consideration of changes in contaminants of interest and in the environment that have occurred during the period of interim remedial action, i.e., 1996 to the present, as well as the sub-regions, for which no initial risk assessments have been conducted. In 1996, a record of decision (ROD) stipulated interim remedial action for groundwater affected by releases from 300 Area sources, as follows: (a) continued monitoring of groundwater that is contaminated above health-based levels to ensure that concentrations continue to decrease, and (b) institutional controls to ensure that groundwater use is restricted to prevent unacceptable exposure to groundwater contamination. In 2000, the groundwater beneath the two outlying sub-regions was added to the operable unit. In 2001, the first 5-year review of the ROD found that the interim remedy and remedial action objectives were still appropriate, although the review called for additional characterization activities. This report includes a current conditions baseline ecological and human health risk assessment using maximum concentrations in the environmental media of the 300-FF-5 Operable Unit and downstream conditions at the City of Richland, Washington. The scope for this assessment includes only current measured environmental concentrations and current use scenarios. Future environmental concentrations and future land uses are not considered in this assessment.

  14. Groundwater monitoring for remedial investigation in the Oriskany-Whitestown Sand Plain, Oneida County, New York

    International Nuclear Information System (INIS)

    Kewer, R.P.; Birckhead, E.F.

    1992-01-01

    The 50-acre Whitestown Landfill is listed by NYSDEC as a Class 2 inactive hazardous waste disposal site. During Remedial Investigations, a 23-well groundwater monitoring system was installed, exploring Wisconsin age glaciofluvial deposits of the Oriskany-Whitestown sand plain. These were described in the late 19th century as deltaic sediments deposited in a proglacial lake. However, no recent studies and only limited subsurface data were available, prompting a two-phase installation program. The landfill is located above steep bluffs 70 feet above the Mohawk River and Oriskany Creek valleys. Beneath the landfill, Phase I identified a gradational sequence of coarse to fine deltaic sediments with glacial till. This sequence was partly eroded and overlain by alluvium and colluvium in the valleys. The landfill was constructed on surficial deposits of coarse fluviodeltaic gravel. These were underlain by deltaic deposits grading from sand to silt with depth, the lower silts comprising the uppermost aquifer. The silts made identification of the water table difficult during drilling and caused problems in meeting a stringent development criterion for turbidity. Phase I found that the saturated zone, up to 50 feet thick, is perched on glaciolacustrine clays and, locally, tills, which were the lower boundary of the system investigated. Partly influenced by the clays, groundwater and contaminant movement was to the adjoining valley, causing off-site impacts in the shallow alluvial/colluvial aquifer. Therefore, Phase 11 focused on characterizing flow and groundwater quality in the discharge area, particularly with respect to an adjacent residence and wetlands. Contamination was found to extend northward only as far as the Old Erie Canal, which parallels the base of the bluff. Only limited off-site involvement was documented which will be monitored in the post-closure period using the installed well system

  15. Hanford Site Groundwater Monitoring for Fiscal Year 2000

    Energy Technology Data Exchange (ETDEWEB)

    Hartman, Mary J.; Morasch, Launa F.; Webber, William D.

    2001-03-01

    This report presents the results of groundwater and vadose zone monitoring and remediation for fiscal year 2000 on the U.S. Department of Energy's Hanford Site, Washington. The most extensive contaminant plumes are tritium, iodine-129, and nitrate, which all had multiple sources and are very mobile in groundwater. Carbon tetrachloride and associated organic constituents form a relatively large plume beneath the central part of the Site. Hexavalent chromium is present in smaller plumes beneath the reactor areas along the river and beneath the central part of the site. Strontium-90 exceeds standards beneath each of the reactor areas, and technetium-99 and uranium are present in the 200 Areas. RCRA groundwater monitoring continued during fiscal year 2000. Vadose zone monitoring, characterization, remediation, and several technical demonstrations were conducted in fiscal year 2000. Soil gas monitoring at the 618-11 burial ground provided a preliminary indication of the location of tritium in the vadose zone and in groundwater. Groundwater modeling efforts focused on 1) identifying and characterizing major uncertainties in the current conceptual model and 2) performing a transient inverse calibration of the existing site-wide model. Specific model applications were conducted in support of the Hanford Site carbon tetrachloride Innovative Treatment Remediation Technology; to support the performance assessment of the Immobilized Low-Activity Waste Disposal Facility; and in development of the System Assessment Capability, which is intended to predict cumulative site-wide effects from all significant Hanford Site contaminants.

  16. Basewide Groundwater Operable Unit. Groundwater Operable Unit Remedial Investigation/Feasibility Study Report. Volume 1

    Science.gov (United States)

    1994-06-01

    units would be reused in the remedy. Contingency measures to be included in the remedy are potential metals removal prior to water end use, potential...onbase reuse of a portion of the water, and wellhead treatment on offbase supply wells. The contingency measures will only be implemented if necessary...94 LEGEND Ouatmar aluvi dposts agua Frmaion(cosoldatd aluval epoits W iead rdetilnsMhte omtin(neitccnlmeae ansoe9ndkeca F 70 Quvatei-lernayalvu e pk

  17. Some aspects of the state of the art of contaminated sites remediation in Italy

    Directory of Open Access Journals (Sweden)

    Giovanni Pietro Beretta

    2015-06-01

    Full Text Available The remediation of contaminated sites has been faced in Italy and elsewhere in the world with a series of works originated by the availability of specific technologies for the recovery of soils and groundwater quality, acting in accordance with the principle of sustainability. A framework of rules (target values and type of intervention and a summary of the quality of soil and groundwater in Italian contaminated sites must be mentioned first. The design of the remediation was also permitted by the improvement of the site characterization, with specific equipments addressed for example to identify the stratigraphy of the contaminants, the presence of volatile compounds, the sampling of water of significant groundwater quality, etc.. The text describes some interventions relating to physical and hydraulic barriers that involve substantial capital and O&M costs and also the consumption of natural resources. Subsequently they are also considered important in situ interventions that resulted in a reduction in the concentration and significant recovery of the pollutants mass. The evolution of the residual concentration in the groundwater must be considered by monitoring natural attenuation. Despite the recovery of the mass of pollutants even up to 90-99%, values of cleanup (expected concentrations of the order of μg/L which are established by national legislation have not been achieved. It can be stated that the scientific community is considering the new paradigm expressed by the “order of magnitude of the flow of pollutant mass” to replace the old paradigm consisting in the “limit value of final concentrations”.

  18. GROUDWATER REMEDIATION AT THE 100-HR-3 OPERABLE UNIT HANFORD, SITE WASHINGTON, USA - 11507

    International Nuclear Information System (INIS)

    Smoot, J.L.; Biebesheimer, F.H.; Eluskie, J.A.; Spiliotopoulos, A.; Tonkin, M.J.; Simpkin, T.

    2011-01-01

    The 100-HR-3 Groundwater Operable Unit (OU) at the Hanford Site underlies three former plutonium production reactors and the associated infrastructure at the 100-D and 100-H Areas. The primary contaminant of concern at the site is hexavalent chromium; the secondary contaminants are strontium-90, technetium-99, tritium, uranium, and nitrate. The hexavalent chromium plume is the largest plume of its type in the state of Washington, covering an area of approximately 7 km 2 (2.7 mi 2 ) with concentrations greater than 20 (micro)g/L. Concentrations range from 60,000 (micro)g/L near the former dichromate transfer station in the 100-D Area to large areas of 20 to 100 (micro)g/L across much of the plume area. Pump-and-treat operations began in 1997 and continued into 2010 at a limited scale of approximately 200 gal/min. Remediation of groundwater has been fairly successful in reaching remedial action objectives (RAOs) of 20 (micro)g/L over a limited region at the 100-H, but less effective at 100-D. In 2000, an in situ, permeable reactive barrier was installed downgradient of the hotspot in 100-D as a second remedy. The RAOs are still being exceeded over a large portion of the area. The CH2M HILL Plateau Remediation Company was awarded the remediation contract for groundwater in 2008 and initiated a remedial process optimization study consisting of modeling and technical studies intended to enhance the remediation. As a result of the study, 1,400 gal/min of expanded treatment capacity are being implemented. These new systems are designed to meet 2012 and 2020 target milestones for protection of the Columbia River and cleanup of the groundwater plumes.

  19. Re-injection accelerates groundwater clean up at Fernald, Fluor Fernald, Inc

    International Nuclear Information System (INIS)

    Dave Brettschneider; William Hertel; Ken Broberg

    2000-01-01

    A successful one year long, field scale demonstration of the use of groundwater re-infection at Fernald was recently completed bringing DOE one step closer to achieving an accelerated site remediation (DOE 2000). The demonstration marks the end of a several year effort to evaluate whether: re-injection could be conducted efficiently at Fernald, and if the approved aquifer remedy at Fernald would benefit by incorporating re-infection. Evaluation of re-injection technology involved not only technical considerations, but also participation and cooperation of regulators and stakeholders. The demonstration was considered to be unique in that it was integrated into the design of the current approved aquifer remedy and utilized the existing remediation infrastructure. Information collected during the demonstration indicated that re-injection wells could be operated efficiently at Fernald and that the current approved groundwater remedy should be modified to include the use of re-injection

  20. Remedial Investigation of Hanford Site Releases to the Columbia River

    International Nuclear Information System (INIS)

    Lerch, J.A.

    2009-01-01

    In south-central Washington State, the Columbia River flows through the U.S. Department of Energy Hanford Site. A primary objective of the Hanford Site cleanup mission is protection of the Columbia River, through remediation of contaminated soil and groundwater that resulted from its weapons production mission. Within the Columbia River system, surface water, sediment, and biota samples related to potential Hanford Site hazardous substance releases have been collected since the start of Hanford operations. The impacts of Hanford Site hazardous substance releases to the Columbia River in areas upstream, within, and downstream of the Hanford Site boundary have been previously investigated as mandated by the U.S. Department of Energy requirements under the Atomic Energy Act. The impacts are now being assessed under the Comprehensive Environmental Response, Compensation, and Liability Act of 1980 via a remedial investigation. The Remedial Investigation Work Plan for Hanford Site Releases to the Columbia River has been developed and issued to initiate the remedial investigation. The work plan establishes a phased approach to characterize contaminants, assess current risks, and determine whether or not there is a need for any cleanup actions. Field investigation activities began in October 2008 and are anticipated to continue into Fall 2009 over a 120 mile stretch of the Columbia River. Information gained from performing this remedial investigation will ultimately be used to help make final regulatory decisions for cleaning up Hanford Site contamination that exists in and along the Columbia River. (authors)

  1. Final audit report of remedial action construction at the UMTRA Project Ambrosia Lake, New Mexico, site

    International Nuclear Information System (INIS)

    1995-09-01

    The final audit report for remedial action at the Ambrosia Lake, New Mexico, Uranium Mill Tailings Remedial Action (UMTRA) Project site consists of a summary of the radiological surveillances/audits, quality assurance (QA) in-process surveillances, and a QA final closeout inspection performed by the US Department of Energy (DOE) and the Technical Assistance Contractor (TAC). One radiological surveillance and three radiological audits were performed at the Ambrosia Lake site. The surveillance was performed on 12--16 April 1993 (DOE, 1993d). The audits were performed on 26--29 July 1993 (DOE, 1993b); 21--23 March 1994 (DOE, 1994d); and 1--2 August 1994 (DOE, 1994d). The surveillance and audits resulted in 47 observations. Twelve of the observations raised DOE concerns that were resolved on site or through subsequent corrective action. All outstanding issues were satisfactorily closed out on 28 December 1994. The radiological surveillance and audits are discussed in this report. A total of seven QA in-process surveillances were performed at the Ambrosia Lake UMTRA site are discussed. The DOE/TAC Ambrosia Lake final remedial action close-out inspection was conducted on 26 July 1995 (DOE, 1995a). To summarize, a total of 155 observations were noted during DOE/TAC audit and surveillance activities. Follow-up to responses required from the RAC for the DOE/TAC surveillance and audit observations indicated that all issues related to the Ambrosia Lake site were resolved and closed to the satisfaction of the DOE

  2. Hanford Site Groundwater Monitoring for Fiscal Year 2006

    Energy Technology Data Exchange (ETDEWEB)

    Hartman, Mary J.; Morasch, Launa F.; Webber, William D.

    2007-03-01

    This report presents the results of groundwater monitoring for FY 2006 on DOE's Hanford Site. Results of groundwater remediation, vadose zone monitoring, and characterization are summarized. DOE monitors groundwater at the Hanford Site to fulfill a variety of state and federal regulations, including the Atomic Energy Act (AEA), the Resource Conservation and Recovery Act (RCRA), the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA), and Washington Administrative Code (WAC).

  3. Inducing mineral precipitation in groundwater by addition of phosphate

    Directory of Open Access Journals (Sweden)

    Hartmann Thomas

    2011-10-01

    Full Text Available Abstract Background Induced precipitation of phosphate minerals to scavenge trace elements from groundwater is a potential remediation approach for contaminated aquifers. The success of engineered precipitation schemes depends on the particular phases generated, their rates of formation, and their long term stability. The purpose of this study was to examine the precipitation of calcium phosphate minerals under conditions representative of a natural groundwater. Because microorganisms are present in groundwater, and because some proposed schemes for phosphate mineral precipitation rely on stimulation of native microbial populations, we also tested the effect of bacterial cells (initial densities of 105 and 107 mL-1 added to the precipitation medium. In addition, we tested the effect of a trace mixture of propionic, isovaleric, formic and butyric acids (total concentration 0.035 mM. Results The general progression of mineral precipitation was similar under all of the study conditions, with initial formation of amorphous calcium phosphate, and transformation to poorly crystalline hydroxylapatite (HAP within one week. The presence of the bacterial cells appeared to delay precipitation, although by the end of the experiments the overall extent of precipitation was similar for all treatments. The stoichiometry of the final precipitates as well as Rietveld structure refinement using x-ray diffraction data indicated that the presence of organic acids and bacterial cells resulted in an increasing a and decreasing c lattice parameter, with the higher concentration of cells resulting in the greatest distortion. Uptake of Sr into the solids was decreased in the treatments with cells and organic acids, compared to the control. Conclusions Our results suggest that the minerals formed initially during an engineered precipitation application for trace element sequestration may not be the ones that control long-term immobilization of the contaminants. In

  4. Engineered wetlands for on-site groundwater remediation

    International Nuclear Information System (INIS)

    Wallace, S.; Davis, B.M.

    2008-01-01

    Engineered wetlands have been touted as an emerging technology for the in situ remediation of hydrocarbon-contaminated soil and water. They incorporate a horizontal subsurface flow gravel bed reactor lined with impermeable liners, and are equipped with forced bed aeration systems that enhance oxygen delivery to the wetland's aerobic micro-organisms. Engineered wetlands generally emphasize specific characteristics of wetland ecosystems to improve treatment capacities. Design parameters include biodegradation rate coefficients, flowrate, hydraulic residence time plus influent and required effluent concentrations. This paper described the installation of an engineered wetland system at a former British Petroleum (BP) refinery in Wyoming where a pipeline terminal generated contact wastewater containing benzene, toluene, ethylbenzene and xylene (BTEX) and ammonia. The wetland treatment system was designed to treat 6000 m 3 of contaminated ground water per day and has been in operation since May 2003. It was concluded that engineered wetlands can offer long-term solutions to site remediation challenges. 16 refs., 3 tabs., 6 figs

  5. DOE groundwater protection strategy

    International Nuclear Information System (INIS)

    Lichtman, S.

    1988-01-01

    EH is developing a DOE-wide Groundwater Quality Protection Strategy to express DOE's commitment to the protection of groundwater quality at or near its facilities. This strategy responds to a September 1986 recommendation of the General Accounting Office. It builds on EPA's August 1984 Ground-Water Protection Strategy, which establishes a classification system designed to protect groundwater according to its value and vulnerability. The purposes of DOE's strategy are to highlight groundwater protection as part of current DOE programs and future Departmental planning, to guide DOE managers in developing site-specific groundwater protection practices where DOE has discretion, and to guide DOE's approach to negotiations with EPA/states where regulatory processes apply to groundwater protection at Departmental facilities. The strategy calls for the prevention of groundwater contamination and the cleanup of groundwater commensurate with its usefulness. It would require long-term groundwater protection with reliance on physical rather than institutional control methods. The strategy provides guidance on providing long-term protection of groundwater resources; standards for new remedial actions;guidance on establishing points of compliance; requirements for establishing classification review area; and general guidance on obtaining variances, where applicable, from regulatory requirements. It also outlines management tools to implement this strategy

  6. Selected remedy at the Queen City Farms superfund site: A risk management approach

    International Nuclear Information System (INIS)

    Weber, E.F.; Wilson, J.; Kirk, M.; Tochko, S.

    1994-01-01

    A risk management approach at a former industrial waste disposal site in western Washington resulted in a selected remedy that is cost-effective and that meets the CERCLA threshold criterion of protecting human health and the environment. The proposed remedy, which addresses contamination in soil and groundwater, does not require an ARARs waiver and received state and community acceptance. By analyzing the current and potential risk at the site, a proposed remedy was chosen that would control the source and naturally attenuate the groundwater plume. Source control will include removal and treatment of some light nonaqueous phase liquid (LNAPL) and some soil, followed by isolation of the remaining soil and LNAPL within a slurry wall and beneath a multilayer cap. A contingent groundwater extraction and treatment system was included to address uncertainty in the risk characterization. Implementing source control is predicted to result in a steady decline in volatile organic compound levels in the drinking water aquifer through adsorption, degradation, and dispersion. Exposure to groundwater during the period of natural attenuation will be controlled by monitoring, institutional controls, and a thorough characterization of the plume and receptors. 7 figs., 1 tab

  7. Tank Waste Remediation System, Hanford Site, Richland, Washington. Final Environmental Impact Statement. Volume I

    International Nuclear Information System (INIS)

    1996-08-01

    This document, Volume 1 of the Final Environmental Impact Statement, analyzes the potential environmental consequences related to the Hanford Site Tank Waste Remediation System (TWRS) alternatives for management and disposal of radioactive, hazardous, and mixed waste, and the management and disposal of approximately 1,930 cesium and strontium capsules located at the Hanford Site. This waste is currently or projected to be stored in 177 underground storage tanks and approximately 60 miscellaneous underground storage tanks. This document analyzes the following alternatives for remediating the tank waste: No Action, Long-Term Management, In Situ Fill and Cap, In Situ Vitrification, Ex Situ Intermediate Separations, Ex Situ No Separations, Ex Situ Extensive Separations, Ex Situ/In Situ Combination 1, and Ex Situ/In Situ Combination 2. This document also addresses a Phased Implementation alternative (the DOE and Ecology preferred alternative for remediation of tank waste). Alternatives analyzed for the cesium and strontium capsules include: No Action, Onsite Disposal, Overpack and Ship, and Vitrify with Tank Waste. The DOE and Ecology preferred alternative for the cesium and strontium capsules is the No Action alternative

  8. Use of Additives in Bioremediation of Contaminated Groundwater and Soil

    Science.gov (United States)

    This chapter reviews application of additives used in bioremediation of chlorinated solvents and fuels for groundwater and soil remediation. Soluble carbon substrates are applicable to most site conditions except aquifers with very high or very low groundwater flow. Slow-release ...

  9. Remediation of petroleum hydrocarbons by inoculation with laboratory-cultured microorganisms

    International Nuclear Information System (INIS)

    Maxwell, C.R.; Baqai, H.A.

    1995-01-01

    An unauthorized release of gasoline from an underground storage tank (UST) impacted the soil and groundwater beneath a maintenance and fueling capacity. The property owner attempted to remediate the site by inoculating wells screened within the unsaturated and saturated zones with laboratory-cultured microorganisms. The inoculation was a one-time event. No nutrients were added to the subsurface. Air was injected into all inoculation wells during the project to promote aerobic microbial activity. At the first groundwater sampling event after inoculation, concentrations of petroleum hydrocarbon constituents increased inoculation wells. Measurements of dissolved oxygen in the groundwater appeared to indicate that oxygen consumption, and thus hydrocarbon degradation, was not occurring. Visual and olfactory evidence of the groundwater indicated evidence of decaying organic matter. After approximately 1 year and a thorough purging of the inoculation wells, decaying matter disappeared and dissolved oxygen and hydrocarbon concentrations generally returned to preproject levels. Further contaminant reduction did not occur, indicating temporary degradation of water quality as a result of the project and unsuccessful remediation

  10. EM-54 Technology Development In Situ Remediation Integrated Program

    International Nuclear Information System (INIS)

    1993-08-01

    The Department of Energy (DOE) established the Office of Technology Development (EM-50) as an element of Environmental Restoration and Waste Management (EM) in November 1989. EM manages remediation of all DOE sites as well as wastes from current operations. The goal of the EM program is to minimize risks to human health, safety and the environment, and to bring all DOE sites into compliance with Federal, state, and local regulations by 2019. EM-50 is charged with developing new technologies that are safer, more effective and less expensive than current methods. The In Situ Remediation Integrated Program (the subject of this report) is part of EM-541, the Environmental Restoration Research and Development Division of EM-54. The In Situ Remediation Integrated Program (ISR IP) was instituted out of recognition that in situ remediation could fulfill three important criteria: Significant cost reduction of cleanup by eliminating or minimizing excavation, transportation, and disposal of wastes; reduced health impacts on workers and the public by minimizing exposure to wastes during excavation and processing; and remediation of inaccessible sites, including: deep subsurfaces; in, under, and around buildings. Buried waste, contaminated soils and groundwater, and containerized wastes are all candidates for in situ remediation. Contaminants include radioactive wastes, volatile and non-volatile organics, heavy metals, nitrates, and explosive materials. The ISR IP tends to facilitate development of in situ remediation technologies for hazardous, radioactive, and mixed wastes in soils, groundwater, and storage tanks. Near-term focus is on containment of the wastes, with treatment receiving greater effort in future years

  11. Hydrogeologic and geochemical studies of selected natural radioisotopes and barium in groundwater in Illinois. Final report

    International Nuclear Information System (INIS)

    Gilkeson, R.H.; Cartwright, K.; Cowart, J.B.; Holtzman, R.B.

    1983-05-01

    Dissolved concentrations of the natural radioisotopes 222 Rn, 226 Ra, 228 Ra, 230 Th, 232 Th, 234 U and 238 U and the element Ba 2+ were investigated in a study of high concentrations of 226 Ra, 228 Ra, and Ba 2+ in groundwater from the Cambrian and Ordovician bedrock of northern Illinois. The high radium and barium concentrations are naturally present in the major aquifers - the sandstone bedrock; therefore, remedial well construction measures will not lower the concentrations. The combined concentrations of 226 Ra and 228 Ra range from 2.3 to 50.2 pCi/L; the majority of analyses exceed the limit in the drinking water regulations of 5.0 pCi/L. The 226 Ra/ 228 Ra activity ratio ranges from 0.2 to 41.0; a 226 Ra analysis has no validity for predicting the 228 Ra concentration. Important controls on dissolved 226 Ra concentrations are secondary U on the sandstone matrix and the ionic strength of groundwater. The distribution of accessory minerals that contain 232 Th is believed to be an important control on dissolved 228 Ra concentrations. Locally the dissolved 226 Ra and 228 Ra concentrations are affected by dissolution-precipitation of secondary barite. Dissolved concentrations of 222 Rn and U are less than proposed drinking water regulations. The extreme enrichment in 234 U that occurs widespread in groundwater from the Cambrian and Ordovician bedrock is unique and problematic. The enrichment may reflect recharge of uranium to the bedrock by glacial processes. Dissolved Ba 2+ concentrations range from 2+ concentrations occur in groundwater that is depleted in dissolved SO 4 2- by anaerobic microbial reactions. A map presents the distribution of Ba 2+ in groundwater from the Cambrian and Ordovician bedrock in northeastern Illinois. 60 references, 13 figures, 3 tables

  12. PROBABILISTIC RISK ANALYSIS OF REMEDIATION EFFORTS IN NAPL SITES

    Science.gov (United States)

    Fernandez-Garcia, D.; de Vries, L.; Pool, M.; Sapriza, G.; Sanchez-Vila, X.; Bolster, D.; Tartakovsky, D. M.

    2009-12-01

    The release of non-aqueous phase liquids (NAPLs) such as petroleum hydrocarbons and chlorinated solvents in the subsurface is a severe source of groundwater and vapor contamination. Because these liquids are essentially immiscible due to low solubility, these contaminants get slowly dissolved in groundwater and/or volatilized in the vadoze zone threatening the environment and public health over a long period. Many remediation technologies and strategies have been developed in the last decades for restoring the water quality properties of these contaminated sites. The failure of an on-site treatment technology application is often due to the unnoticed presence of dissolved NAPL entrapped in low permeability areas (heterogeneity) and/or the remaining of substantial amounts of pure phase after remediation efforts. Full understanding of the impact of remediation efforts is complicated due to the role of many interlink physical and biochemical processes taking place through several potential pathways of exposure to multiple receptors in a highly unknown heterogeneous environment. Due to these difficulties, the design of remediation strategies and definition of remediation endpoints have been traditionally determined without quantifying the risk associated with the failure of such efforts. We conduct a probabilistic risk assessment of the likelihood of success of an on-site NAPL treatment technology that easily integrates all aspects of the problem (causes, pathways, and receptors). Thus, the methodology allows combining the probability of failure of a remediation effort due to multiple causes, each one associated to several pathways and receptors.

  13. Remediation of arsenic-contaminated soils and groundwaters

    Science.gov (United States)

    Peters, Robert W.; Frank, James R.; Feng, Xiandong

    1998-01-01

    An in situ method for extraction of arsenic contaminants from a soil medium and remediation of the medium including contacting the medium with an extractant solution, directing the solution within and through the medium, and collecting the solution and contaminants. The method can also be used for arsenate and/or arsenite removal.

  14. Installation of an innovative remedial technology

    International Nuclear Information System (INIS)

    Hines, B.

    1995-01-01

    The major goal of the Lasagna trademark project was to design, construct, install, and operate an in situ remediation system in low-permeability soil. A new technology--the Lasagna process--uses electro-osmosis to move contaminated groundwater through treatment zones. The treatment zones are installed in contaminated soils, thereby forming an integrated in situ remedial process. Electro-osmosis, well known for its effectiveness and extremely low power consumption, uses a direct current to cause Groundwater to travel through low-permeability soil. When a bench-scale version of the technology was 98 percent effective in removing contamination, an actual field test was the next step. The site chosen for this first field effort was the DOE-owned Paducah Gaseous Diffusion Plant located in Paducah, Kentucky. The target contaminant for this project was trichloroethylene (TCE) because it is found at many sites across the country and is present at approximately 60 percent of DOE's sites

  15. Proceedings of the 2010 PTAC soil and groundwater forum and poster session

    International Nuclear Information System (INIS)

    2010-01-01

    This conference focused on emerging environmental issues and advances in soil and groundwater remediation research. It provided a forum to discuss current research and environmental regulations pertaining to the remediation and reclamation of oil and gas production sites as well as soils along pipeline routes. Methods for accurately identifying the source of hydrocarbon contamination in soils and wetlands were also presented. Recent advances in technological solutions for soil and groundwater remediation were reviewed along with methods for addressing salts, petroleum hydrocarbons, and process chemicals. The conference featured 18 presentations, of which 3 have been catalogued separately for inclusion in this database. refs., tabs., figs.

  16. Permeable reactive barriers for the remediation of groundwater in a mining area: results for a pilot-scale project

    Science.gov (United States)

    Martinez-Sanchez, Maria Jose; Perez-Sirvent, Carmen; Garcia-Lorenzo, Maria Luz; Martinez-Lopez, Salvadora; Perez-Espinosa, Victor; Gonzalez-Ciudad, Eva; Belen Martinez-Martinez, Lucia; Hernandez, Carmen; Molina-Ruiz, Jose

    2017-04-01

    The Sierra Minera of Cartagena-La Union is located in the Region of Murcia, Southeast of Spain. This zone presents high levels of heavy metals due to natural, geogenic reasons. In addition, the prolonged mining activity, and subsequent abandonment of farms, has had consequences on the environment, including severe affectation of the groundwater in the area. To remediate this situation, the Permeable Reactive Barrier (PRB) technology was assayed, which required in addition to the hydro-geological study of the zone, a careful optimization study for the design and construction of PRBs. For such a purpose a pilot-scale project was developed, and this communication reports some of the most relevant findings obtained after a four-years monitorization period. The selected reactive material for the PRBs was limestone filler. The filler is a waste material produced in many factories in the zone. These residues have good adsorption properties, high alkalinity, low cost and high availability, which make them suitable for use in remediation. The PRB was constituted by a 50% limestone filler and 50% sand, a proportion optimized by means of independent batch experiments. A layer of gravel was placed at the top, and on it a layer of natural soil. The barrier was designed in the form of a continuous trench, because the level of the contaminated groundwater was not very deep. In this way, the barrier could be prepared with standard excavation equipment. Parallel to the barrier, 6 wells where arranged downstream for sample collection. The pH and conductivity of the samples was measured directly in situ, and the content of Zn, Cd, Cu, Fe, and Pb were analyzed in the laboratory. All the samples collected after the PRB was constructed had basic pH values between 7.5 and 8. The conductivity was between 5 and 11 mS / cm except for the well 4, which had a value of 3.70 mS / cm. The concentration values of trace elements were below the detection limit (atomic absorption measurement) in

  17. Mitigation action plan for 300-FF-1 remedial action

    International Nuclear Information System (INIS)

    Weiss, S.G.

    1996-10-01

    A record of decision was issued (dated July 1996), for remediation of waste sites in the 300-FF-1 Operable Unit in the 300 Area of the Hanford Site. The selected remedies for the 300-FF-1 and 300-FF-5 waste sites include selective excavation and disposal of contaminated soil and debris from the process waste units, excavation and removal of the 618-4 Burial Ground, and institutional controls for groundwater. This mitigation action plan explains how cultural resources will be managed and how revegetation for these remedial activities will be planned

  18. Air sparging of organic compounds in groundwater

    International Nuclear Information System (INIS)

    Hicks, P.M.

    1994-01-01

    Soils and aquifers containing organic compounds have been traditionally treated by excavation and disposal of the soil and/or pumping and treating the groundwater. These remedial options are often not practical or cost effective solutions. A more favorable alternative for removal of the adsorbed/dissolved organic compounds would be an in situ technology. Air sparging will remove volatile organic compounds from both the adsorbed and dissolved phases in the saturated zone. This technology effectively creates a crude air stripper below the aquifer where the soil acts as the ''packing''. The air stream that contacts dissolved/adsorbed phase organics in the aquifer induces volatilization. A case history illustrates the effectiveness of air sparging as a remedial technology for addressing organic compounds in soil and groundwater. The site is an operating heavy equipment manufacturing facility in central Florida. The soil and groundwater below a large building at the facility was found to contain primarily diesel type petroleum hydrocarbons during removal of underground storage tanks. The organic compounds identified in the groundwater were Benzene, Xylenes, Ethylbenzene and Toluenes (BTEX), Methyl tert-Butyl Ether (MTBE) and naphthalenes in concentrations related to diesel fuel

  19. Confirmatory radiological survey of the Grand Junction Projects Office Remedial Action Project exterior portions, 1989-1995

    International Nuclear Information System (INIS)

    Forbes, G.H.; Egidi, P.V.

    1997-04-01

    The purpose of this independent assessment was to provide the U.S. Department of Energy (DOE) with an independent verification (IV) that the soil at the Grand Junction Projects Office (GJPO) complies with applicable DOE guidelines. Oak Ridge National Laboratory/ Environmental Technology Section (ORNL/ETS) which is also located at the GJPO, was assigned by DOE as the Independent Verification Contractor (IVC). The assessment included reviews of the decontamination and decommissioning plan, annual environmental monitoring reports, data in the pre- and post-remedial action reports, reassessment reports and IV surveys. Procedures and field methods used during the remediation were reviewed, commented on, and amended as needed. The IV surveys included beta-gamma and gamma radiation scans, soil sampling and analyses. Based on the data presented in the post-remedial action report and the results of the IV surveys, the remediation of the outdoor portions of the GJPO has achieved the objectives. Residual deposits of uranium contamination may exist under asphalt because the original characterization was not designed to identify uranium and subsequent investigations were limited. The IVC recommends that this be addressed with the additional remediation. The IVC is working with the remedial action contractor (RAC) to assure that final documentation WM be sufficient for certification. The IVC will address additional remediation of buildings, associated utilities, and groundwater in separate reports. Therefore, this is considered a partial verification

  20. Tritium tracer movement as an analogy for pump and treat remediation

    International Nuclear Information System (INIS)

    1994-12-01

    There has been debate over effectiveness of groundwater pump and treat remediation. The goal of the following discussion is to present evidence from a tracer test that illustrates the difficulty in removing contaminants from fractured shale that is typical of portions of the DOE-Oak Ridge Reservation (ORR). This report provides a brief prelude to more detailed analysis that is in progress. Attempts to remediate groundwater contamination with pump and treat technology have been hampered by difficulties in removing contaminants in slow flow zones. There is interest in using this remediation method on the ORR because it is an existing technology. However, this setting provides a rather extreme contrast between fast flow zones (fractures) and slow flow zones (the matrix surrounding the fractures). Over the past few years, the authors have begun to develop an understanding of how contaminants move in fractures and how contaminant exchange between the fracture and matrix occurs. In particular, they have evidence from a long term tritium tracer test that has direct bearing on potential success or failure of pump and treat remediation in fractured rocks

  1. Final audit report of remedial action construction at the UMTRA Project Falls City, Texas, site

    International Nuclear Information System (INIS)

    1995-05-01

    This final audit report for the Falls City, Texas, Uranium Mill Tailings Remedial Action Project site summarizes the radiological audits and the quality assurance (QA) in-process surveillances, audits, and final close-out inspection performed by the U.S. Department of Energy (DOE) and Technical Assistance Contractor (TAC). It also summarizes U.S. Nuclear Regulatory Commission (NRC) surveillances. One radiological audit and three radiological surveillances were performed at the Falls City site. These surveillances and audit, which resulted in 31 observations, focused primarily on processing site activities and were performed on the following dates: 3-6 August 1992, 29-30 October 1992, 22-26 March 1993, and 1-3 November 1993. All outstanding radiological issues were closed out at the completion of the construction activities. Six QA in-process surveillances, which resulted in 71 observations, were performed at the Falls City site on the following dates: 22-24 July 1992, 23-25 November 1992, 17-19 May 1993, 16-18 August 1993, 13-15 October 1993, and 2-4 February 1994. All outstanding issues were closed out with the February surveillance on 3 March 1994. The DOE/TAC remedial action close-out inspections of the Falls City site, which resulted in 56 observations, were conducted 9-10 June 1994 and 26 July 1994. The inspections were closed out on 26 January 1995. The NRC performed three on-site construction reviews (OSCR), resulting in seven observations of remedial action construction activities that occurred during site visits. The OSCRs were performed 9 December 1992, 12 May 1993, and 25 October 1993. Since all audit and surveillance observations and recommendations have been closed out, this final audit report segment of the site certification process is complete

  2. Statistical analysis of ground-water contamination at the alert apron and northern landfill areas of Wurtsmith AFB, Michigan. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Hunter, P.; Naber, S.; Verducci, J.

    1988-07-01

    Two plumes of contamination are analyzed to determine their extent, composition, and movement. The large number of ground-water monitoring wells sampled over the past eight years at Wurtsmith AFB allow this analysis to be performed directly from empirical data, with minimal assumptions about solute transport mechanisms. Conclusions are drawn about the likely sources of contamination in the two plumes, the adequacy of the data for making risk assessments, and the likely consequences of alternative programs of remediation.

  3. Remediation of lead and cadmium from simulated groundwater in loess region in northwestern China using permeable reactive barrier filled with environmentally friendly mixed adsorbents.

    Science.gov (United States)

    Fan, Chunhui; Gao, Yalin; Zhang, Yingchao; Dong, Wanqing; Lai, Miao

    2018-01-01

    Permeable reactive barrier (PRB) is potentially effective for groundwater remediation, especially using environmentally friendly mixed fillers in representative areas, such as semi-arid loess region in northwestern China. The mixed materials, including corn straw (agricultural wastes), fly ash (industrial wastes), zeolite synthesized from fly ash (reutilized products), and iron-manganese nodule derived from loess (materials with regional characteristics) in northwestern China, were chosen as PRB media to reduce the contents of lead and cadmium in simulated groundwater. A series of lab-scale column experiments were investigated, and the response surface methodology (RSM) was used to optimize the working process; Fourier transform infrared spectroscopy (FT-IR) and scanning electron microscope (SEM) were applied to further reveal the reaction mechanism. It shows that the purification efficiencies are more acceptable when the concentrations of lead and cadmium are approximately 7 and 0.7 mg/L, respectively, at 25 °C in weakly acidic solution, and functional groups of -OH and C=C play an important role for contaminants removal. The mixed adsorbents used are effective to remove lead and cadmium in groundwater. This is the first report on the removal of lead and cadmium from groundwater in loess region in northwestern China using PRB filled with environmentally friendly mixed adsorbents.

  4. CENTRAL PLATEAU REMEDIATION

    International Nuclear Information System (INIS)

    ROMINE, L.D.

    2006-01-01

    A systematic approach to closure planning is being implemented at the Hanford Site's Central Plateau to help achieve the goal of closure by the year 2035. The overall objective of Central Plateau remediation is to protect human health and the environment from the significant quantity of contaminated material that resulted from decades of plutonium production in support of the nation's defense. This goal will be achieved either by removing contaminants or placing the residual contaminated materials in a secure configuration that minimizes further migration to the groundwater and reduces the potential for inadvertent intrusion into contaminated sites. The approach to Central Plateau cleanup used three key concepts--closure zones, closure elements, and closure process steps--to create an organized picture of actions required to complete remediation. These actions were merged with logic ties, constraints, and required resources to produce an integrated time-phased schedule and cost profile for Central Plateau closure. Programmatic risks associated with implementation of Central Plateau closure were identified and analyzed. Actions to mitigate the most significant risks are underway while high priority remediation projects continue to make progress

  5. 25 Years Of Environmental Remediation In The General Separations Area Of The Savannah River Site: Lessons Learned About What Worked And What Did Not Work In Soil And Groundwater Cleanup

    International Nuclear Information System (INIS)

    Blount, Gerald; Thibault, Jeffrey; Millings, Margaret; Prater, Phil

    2015-01-01

    The Savannah River Site (SRS) is owned and administered by the US Department of Energy (DOE). SRS covers an area of approximately 900 square kilometers. The General Separation Area (GSA) is located roughly in the center of the SRS and includes: radioactive material chemical separations facilities, radioactive waste tank farms, a variety of radioactive seepage basins, and the radioactive waste burial grounds. Radioactive wastes were disposed in the GSA from the mid-1950s through the mid-1990s. Radioactive operations at the F Canyon began in 1954; radioactive operations at H Canyon began in 1955. Waste water disposition to the F and H Seepage Basins began soon after operations started in the canyons. The Old Radioactive Waste Burial Ground (ORWBG) began operations in 1952 to manage solid waste that could be radioactive from all the site operations, and ceased receiving waste in 1972. The Mixed Waste Management Facility (MWMF) and Low Level Radioactive Waste Disposal Facility (LLRWDF) received radioactive solid waste from 1969 until 1995. Environmental legislation enacted in the 1970s, 1980s, and 1990s led to changes in waste management and environmental cleanup practices at SRS. The US Congress passed the Clean Air Act in 1970, and the Clean Water Act in 1972; the Resource Conservation and Recovery Act (RCRA) was enacted in 1976; the Comprehensive Environmental Response Compensation, and Liability Act (CERCLA) was enacted by Congress in 1980; the Federal Facilities Compliance Act (FFCA) was signed into law in 1992. Environmental remediation at the SRS essentially began with a 1987 Settlement Agreement between the SRS and the State of South Carolina (under the South Carolina Department of Health and Environmental Control - SCDHEC), which recognized linkage between many SRS waste management facilities and RCRA. The SRS manages several of the larger groundwater remedial activities under RCRA for facilities recognized early on as environmental problems. All subsequent

  6. Final audit report of remedial action construction at the UMTRA Project, Grand Junction, Colorado, processing site

    International Nuclear Information System (INIS)

    1995-02-01

    This final audit report (FAR) for remedial action at the Grand Junction, Colorado, Uranium Mill Tailings Remedial Action (UMTRA) Project processing site consists of a summary of the radiological surveillances/ audits, the quality assurance (QA) in-process surveillances, and the QA final close-out inspection performed by the US Department of Energy (DOE) and Technical Assistance Contractor (TAC). The FAR also summarizes other surveillances performed by the US Nuclear Regulatory Commission (NRC). To summarize, a total of one finding and 127 observations were noted during DOE/TAC audit and surveillance activities. The NRC noted general site-related observations during the OSCRs. Follow-up to responses required from MK-Ferguson for the DOE/TAC finding and observations indicated that all issues related to the Grand Junction processing site were resolved and closed out to the DOE's satisfaction. The NRC OSCRs resulted in no issues related to the Grand Junction processing site requiring a response from MK-Ferguson

  7. Advanced oxidation for groundwater remediation and for soil decontamination

    International Nuclear Information System (INIS)

    Gehringer, P.; Eschweiler, H.

    2001-01-01

    The advanced oxidation process (AOP) used in this paper is based on EB irradiation of water in the presence and absence of ozone. The paper describes two distinct sets of experiments, one dealing with groundwater contaminated with perchloroethylene (PCE) and some genotoxic compounds, and the other dealing with soil contaminated with polycyclic aromatic hydrocarbons (PAHs). The combination of ozone and EB irradiation has shown to be able to mineralize trace amounts of PCE contained in groundwater in a single stage process without formation of any by-product to be disposed of. Moreover, experiments performed with real groundwater have demonstrated that the combined ozone/EB irradiation process is also apt for total removal of some genotoxic compounds detected in groundwater contaminated with PCE. The design of an ozone/EB irradiation plant for treating 108 m 3 /h is presented. The issue concerning both the occurrences of genotoxic compounds in oxygen containing groundwater and possible processes for their removal is discussed. In the second part soil contaminated with PAHs has been treated in aqueous suspension using ozone and EB irradiation, respectively. Experiments were performed with low contaminated soil (total PAHs about 332 mg/kg soil). With an ozone consumption of 10 g C) 3 /kg soil a total PAH decomposition of about 21% was recorded. EB irradiation with a reasonable radiation dose of 100 kGy results in about 7% total PAH decomposition at room temperature and about 16%, respectively at 55-60 deg. C. It was recorded that almost no transfer of the PAH takes place from the soil into the water when soil is merely suspended in water. Ozone mainly attacked the high molecular fraction (i.e. consisting of 5 or 6 aromatic rings) of the PAHs investigated while EB irradiation of the aqueous soil suspension mostly decomposed the lower fraction (i.e. consisting up to 4 aromatic rings). (author)

  8. Lockheed Martin Energy Systems, Inc., Groundwater Program Office. Annual report for fiscal year 1994

    International Nuclear Information System (INIS)

    1994-01-01

    This edition of the Lockheed Martin Energy Systems, Inc., (Energy Systems) Groundwater Program Annual Report summarizes the work carried out by the Energy Systems Groundwater Program Office (GWPO) for fiscal year (FY) 1994. The GWPO is responsible for coordination and oversight for all components of the groundwater programs at the three Oak Ridge facilities [Oak Ridge National Laboratory (ORNL), the Oak Ridge Y-12 Plant, and the Oak Ridge K-25 Site], as well as the Paducah and Portsmouth Gaseous Diffusion Plants (PGDP and PORTS, respectively.) This report describes the administrative framework of the GWPO including staffing, organization, and funding sources. In addition, summaries are provided of activities involving the Technical Support staff at the five facilities. Finally, the results of basic investigations designed to improve our understanding of the major processes governing groundwater flow and contaminant migration on the Oak Ridge Reservation (ORR) are reported. These investigations are conducted as part of the Oak Ridge Reservation Hydrology and Geology Studies (ORRHAGS) program. The relevance of these studies to the overall remediation responsibilities of Energy Systems is discussed

  9. Transuranic chemical species in groundwater. Final report

    International Nuclear Information System (INIS)

    Cowan, C.E.; Jenne, E.A.; Robertson, D.E.; Nelson, D.M.; Abel, K.H.

    1985-02-01

    For the past several years, staff at Pacific Northwest Laboratory (PNL) have been studying the mobility of actinides, primarily plutonium, in the groundwater of a low-level disposal site. This research has provided valuable insights into the behavior of plutonium in the groundwater. Based on the analytical data and geochemical modeling, it appears that the plutonium that enters the trench, primarily in the higher oxidation states, Pu(V,VI), is rapidly reduced as the water migrates through the highly reducing sediments of the trench and is removed from the water by adsorption of the reduced plutonium, Pu(III,IV), onto the sediments. The Pu(V,VI) also appears to be reduced in the groundwater, although not as rapidly as in the trench sediments, and removed by adsorption. Because of the redox reduction that occurs during the migration of the groundwater, the system is not at redox equilibrium. Based on the discrepancies between the calculated and analytically determined redox distribution and charge-form speciation, the thermodynamic data bases for plutonium appear either to be missing or to contain incorrect thermodynamic data for several aqueous plutonium species, including the carbonate and organic complexes of plutonium. Further research is required to determine the kinetics of plutonium oxidation/reduction reactions in natural groundwater systems and to determine thermodynamic data for carbonate and organic complexes of plutonium. 52 references, 1 figure, 6 tables

  10. Assessment of international remedial technologies for application to Superfund sites

    International Nuclear Information System (INIS)

    Sanning, D.E.

    1990-01-01

    This paper presents some of the logical arguments for conducting research on remedial technologies for contaminated land and groundwater at an international level. It gives information on many of the international organizations that are involved in environmental programs, but it especially gives emphasis to the NATO-CCMS pilot study on Demonstration of Remedial Action Technologies for Contaminated Land and Groundwater. The purpose of the study is to field demonstrate and evaluate new/innovative technologies for remedial action at uncontrolled hazardous waste sites. This study is a logical international extension of the US EPA SITE program. It offers the opportunity to obtain a multiple data base on various remedial action unit processes without any single country having to commit a disproportionate amount of its internal resources to any specific activity. Each participating country provides the necessary resources for those demonstrations which they are contributing to the study. Sites are selected by a majority vote of all participating countries (no country is permitted to vote for its own sites). The study is a 5 year program with participants from Canada, Denmark, Federal Republic of Germany, France, Greece, Italy, Japan, the Netherlands, Norway, Spain, and the US. The need for cost-effective remedial action technologies for hazardous waste sites is a problem of all industrialized countries. The need to build a knowledge base of emerging remedial technologies was the impetus behind the USEPA's lead role and commitment to this pilot study

  11. In Situ Remediation Integrated Program: FY 1994 program summary

    International Nuclear Information System (INIS)

    1995-04-01

    The US Department of Energy (DOE) established the Office of Technology Development (EM-50) as an element of the Office of Environmental Management (EM) in November 1989. In an effort to focus resources and address priority needs, EM-50 introduced the concept of integrated programs (IPs) and integrated demonstrations (IDs). The In Situ Remediation Integrated Program (ISR IP) focuses research and development on the in-place treatment of contaminated environmental media, such as soil and groundwater, and the containment of contaminants to prevent the contaminants from spreading through the environment. Using in situ remediation technologies to clean up DOE sites minimizes adverse health effects on workers and the public by reducing contact exposure. The technologies also reduce cleanup costs by orders of magnitude. This report summarizes project work conducted in FY 1994 under the ISR IP in three major areas: treatment (bioremediation), treatment (physical/chemical), and containment technologies. Buried waste, contaminated soils and groundwater, and containerized waste are all candidates for in situ remediation. Contaminants include radioactive waste, volatile and nonvolatile organics, heavy metals, nitrates, and explosive materials

  12. In Situ Remediation Integrated Program: FY 1994 program summary

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-04-01

    The US Department of Energy (DOE) established the Office of Technology Development (EM-50) as an element of the Office of Environmental Management (EM) in November 1989. In an effort to focus resources and address priority needs, EM-50 introduced the concept of integrated programs (IPs) and integrated demonstrations (IDs). The In Situ Remediation Integrated Program (ISR IP) focuses research and development on the in-place treatment of contaminated environmental media, such as soil and groundwater, and the containment of contaminants to prevent the contaminants from spreading through the environment. Using in situ remediation technologies to clean up DOE sites minimizes adverse health effects on workers and the public by reducing contact exposure. The technologies also reduce cleanup costs by orders of magnitude. This report summarizes project work conducted in FY 1994 under the ISR IP in three major areas: treatment (bioremediation), treatment (physical/chemical), and containment technologies. Buried waste, contaminated soils and groundwater, and containerized waste are all candidates for in situ remediation. Contaminants include radioactive waste, volatile and nonvolatile organics, heavy metals, nitrates, and explosive materials.

  13. Hydrogeological and hydrogeochemical investigations in boreholes - Final report of the phase I geochemical investigations of the Stripa groundwaters

    International Nuclear Information System (INIS)

    Nordstroem, D.K.; Carlsson, L.; Fontes, J.C.; Frits, P.; Moser, H.; Olsson, T.

    1985-07-01

    The hydrogeochemical investigations of Phase I of the Stripa Project (1980-1984) have been completed, and the results are presented in this final report. All chemical and isotopic data on the groundwaters from the beginning to the Stripa Project to the present (1977-84) are tabulated an used in the final interpretations. The background geology and hydrology is summarized and updated along with new analyses of the Stripa grantie. Water-rock interactions form a basic framework for the changes in major-element chemistry with depth, including carbonate geochemistry, the fluid-inclusion hypothesis, redox processes, and mineral precipitation. The irregular distribution of chloride suggests channelling is occurring and the effect of thermomechanical perturbations on the groundwater chemistry is documented. Stable and radioactive isotpes provide information of the origin and evolution of the groundwater itself and of several elments within the groundwater. Subsurface production of radionuclides is documented in these investigations, and a general picture of uranium transformations during weathering is presented. One of the primary conclusions reached in these studies is that different dissolved constituents will provide different residence times because they have different origins and different evolutionary histories that may or may not be related to the overall evolution of the groundwater itself. (author)

  14. Remediation strategies for contaminated territories resulting from Chernobyl accident. Final report

    International Nuclear Information System (INIS)

    Jacob, P.; Fesenko, S.; Firsakova, S.K.

    2001-03-01

    The present report realizes a settlement specific approach to derive remediation strategies and generalizes the results to the whole affected area. The ultimate aim of the study is to prepare possible investment projects on remediation activities in the contaminated territories. Its current aim was to identify the areas and the remedial actions that should be primarily supported and their corresponding cost. The present report starts with an outline of the methodology of deriving remediation strategies, a description of data for 70 representative settlements and of parameters of the remedial actions considered, and a classification of the contaminated territory according to radiological criteria. After summarising aspects of the contamination situation and applications of remedial actions in the past, dose calculations and derived remediation strategies for the representative settlements are described. These are generalized to the total contaminated territory. Within the contaminated territory private produce is of main importance for the radionuclide intake. At the end of the report, radiological aspects of the produce of collective farms are described. (orig.)

  15. Performance assessment techniques for groundwater recovery and treatment systems

    Energy Technology Data Exchange (ETDEWEB)

    Kirkpatrick, G.L. [Environmental Resources Management, Inc., Exton, PA (United States)

    1993-03-01

    Groundwater recovery and treatment (pump and treat systems) continue to be the most commonly selected remedial technology for groundwater restoration and protection programs at hazardous waste sites and RCRA facilities nationwide. Implementing a typical groundwater recovery and treatment system includes the initial assessment of groundwater quality, characterizing aquifer hydrodynamics, recovery system design, system installation, testing, permitting, and operation and maintenance. This paper focuses on methods used to assess the long-term efficiency of a pump and treat system. Regulatory agencies and industry alike are sensitive to the need for accurate assessment of the performance and success of groundwater recovery systems for contaminant plume abatement and aquifer restoration. Several assessment methods are available to measure the long-term performance of a groundwater recovery system. This paper presents six assessment techniques: degree of compliance with regulatory agency agreement (Consent Order of Record of Decision), hydraulic demonstration of system performance, contaminant mass recovery calculation, system design and performance comparison, statistical evaluation of groundwater quality and preferably, integration of the assessment methods. Applying specific recovery system assessment methods depends upon the type, amount, and quality of data available. Use of an integrated approach is encouraged to evaluate the success of a groundwater recovery and treatment system. The methods presented in this paper are for engineers and corporate management to use when discussing the effectiveness of groundwater remediation systems with their environmental consultant. In addition, an independent (third party) system evaluation is recommended to be sure that a recovery system operates efficiently and with minimum expense.

  16. Case study: remediation of a former uranium mining/processing site in Hungary

    International Nuclear Information System (INIS)

    Csovari, M. et al.

    2004-01-01

    The Hungarian uranium mining activities near Pecs lasted from 1958 to 1997. Approximately 46 Mt of rock were mined, from which 18.8 Mt of upgraded ore were processed. Some ore had been exported prior to the construction of the processing plant at the site. Remediation of the former uranium-related industrial sites is being carried out by the Mecsek Ore Environment Ltd. and started in the 1990s. Today the former mines and their surroundings are rehabilitated, former heap piles and a number of smaller waste rock piles have been relocated to a more protected area (waste rock pile N 3). Ongoing core remediation activities are directed to the remediation of the tailings ponds, and also water treatment issues are most important. Three water treatment facilities are currently in operation: a mine water treatment system with the objective to remove uranium and gain a marketable by-product; a pump-and-treat system to restore the groundwater quality in the vicinity of the tailing ponds; a pilot-scale, experimental passive in-situ groundwater treatment system to avoid migration of uranium contaminated groundwater. Refs. 5 (author)

  17. Identification of manganese as a toxicant in a groundwater treatment system: Addressing naturally occurring toxicants

    International Nuclear Information System (INIS)

    Goodfellow, W. Jr.; Sohn, V.; Richey, M.; Yost, J.

    1995-01-01

    Effluent from a groundwater remediation system at a bulk oil storage and distribution terminal has been chronically toxic to Ceriodaphnia dubia. The remediation system was designed in response to a hydrocarbon plume in the area of the terminal. The remediation system consists of a series of groundwater recovery wells and groundwater intercept trench systems with groundwater treatment and phased-separated hydrocarbon recovery systems. The groundwater treatment and petroleum recovery systems consist of oil/water separators, product recovery tanks, air strippers, filters, and carbon adsorption units. The characteristics of this effluent are low total suspended solids, total dissolved solids, and hardness concentrations as well as meeting stringent NPDES permit requirements for lead, copper, zinc, mercury, total petroleum hydrocarbons, and BTEX. Additional priority pollutant evaluations revealed no compounds of concern. Performance of a Toxicity identification Evaluation (TIE) indicated that manganese was the principle toxicant in the effluent. Manganese is a naturally occurring constituent in this groundwater source and is not added to the treatment system. This paper will present the results of the TIE with a discussion of treatability/control options for manganese control at this facility. Recommendations for addressing naturally occurring toxicants that are not a result of the facility's operations will also be presented

  18. In-situ arsenic remediation in Carson Valley, Douglas County, west-central Nevada

    Science.gov (United States)

    Paul, Angela P.; Maurer, Douglas K.; Stollenwerk, Kenneth G.; Welch, Alan H.

    2010-01-01

    Conventional arsenic remediation strategies primarily involve above-ground treatment that include costs involved in the disposal of sludge material. The primary advantages of in-situ remediation are that building and maintaining a large treatment facility are not necessary and that costs associated with the disposal of sludge are eliminated. A two-phase study was implemented to address the feasibility of in-situ arsenic remediation in Douglas County, Nevada. Arsenic concentrations in groundwater within Douglas County range from 1 to 85 micrograms per liter. The primary arsenic species in groundwater at greater than 250 ft from land surface is arsenite; however, in the upper 150 ft of the aquifer arsenate predominates. Where arsenite is the primary form of arsenic, the oxidation of arsenite to arsenate is necessary. The results of the first phase of this investigation indicated that arsenic concentrations can be remediated to below the drinking-water standard using aeration, chlorination, iron, and pH adjustment. Arsenic concentrations were remediated to less than 10 micrograms per liter in groundwater from the shallow and deep aquifer when iron concentrations of 3-6 milligrams per liter and pH adjustments to less than 6 were used. Because of the rapid depletion of dissolved oxygen, the secondary drinking-water standards for iron (300 micrograms per liter) and manganese (100 micrograms per liter) were exceeded during treatment. Treatment was more effective in the shallow well as indicated by a greater recovery of water meeting the arsenic standard. Laboratory and field tests were included in the second phase of this study. Laboratory column experiments using aquifer material indicated the treatment process followed during the first phase of this study will continue to work, without exceeding secondary drinking-water standards, provided that groundwater was pre-aerated and an adequate number of pore volumes treated. During the 147-day laboratory experiment, no

  19. Monitoring remediation of trichloroethylene using a chemical fiber optic sensor: Field studies

    International Nuclear Information System (INIS)

    Colston, B.W.; Brown, S.B.; Langry, K.; Daley, P.; Milanovich, F.P.

    1994-06-01

    Current US Department of Energy (DOE) policy requires characterization and subsequent remediation of areas where trichloroethylene (TCE) has been discharged into the soil and groundwater. Technology that allows trace quantities of this contaminant to be measured in situ on a continuous basis is needed. Fiber optic chemical sensors offer a promising low cost solution. Field tests of such a fiber optic chemical sensor for TCE have recently been completed. Sensors have been used to measure TCE contamination at Savannah River Site (SRS) and Lawrence Livermore National Laboratory Site 300 (S300) in the groundwater and vadose zones. Both sites are currently undergoing remediation processes

  20. Waste management facility remediation and decommissioning at a national nuclear research site

    International Nuclear Information System (INIS)

    Cameron, D.J.; Dolinar, G.M.; Killey, R.W.D.

    1994-01-01

    Historic waste management practices at eight locations on AECL's Chalk River site have resulted in the formation of contaminated groundwater plumes, some of which have surfaced and contaminated surface materials. A priority setting process has been used to establish a plan of attack that will lead to the eventual decommissioning of these facilities. In general terms, the preferred approach is to install impermeable covers to prevent further leaching of waste sources and to prevent escape of leachate to the biosphere, followed by cleanup of surface contamination and remediation of aquifers. Final disposal of the waste sources would be delayed for perhaps 20 years. Substantial progress has been made in the treatment of contaminated groundwater, with one field installation in place and another under development. This paper describes how the prioritization task was tackled to produce a long term plan of action and describes initial interventions that have been attempted and their results. 4 refs., 3 tabs., 3 figs

  1. In situ groundwater bioremediation

    Energy Technology Data Exchange (ETDEWEB)

    Hazen, Terry C.

    2009-02-01

    In situ groundwater bioremediation of hydrocarbons has been used for more than 40 years. Most strategies involve biostimulation; however, recently bioaugmentation have been used for dehalorespiration. Aquifer and contaminant profiles are critical to determining the feasibility and strategy for in situ groundwater bioremediation. Hydraulic conductivity and redox conditions, including concentrations of terminal electron acceptors are critical to determine the feasibility and strategy for potential bioremediation applications. Conceptual models followed by characterization and subsequent numerical models are critical for efficient and cost effective bioremediation. Critical research needs in this area include better modeling and integration of remediation strategies with natural attenuation.

  2. Hanford well remediation and decommissioning plan

    International Nuclear Information System (INIS)

    Ledgerwood, R.K.

    1993-01-01

    Protection of Hanford Site groundwater resources and assessment of the effects of their use or contamination upon public safety are required by federal and state regulations and U.S. Department of Energy (DOE) policy, (DOE, 1989). Compliance with constraints applicable to the use of existing wells requires assessment as to the suitability for use and needs for rehabilitation, remediation or decommissioning of existing groundwater wells and other boreholes potentially affecting aquifers beneath the Hanford Site. Approximately 3,500 groundwater wells and vadose zone boreholes had been drilled on the Hanford Site prior to 1989, over 2,900 still exist. Most of these boreholes were drilled prior to 1987 and do not conform to presently accepted construction standards intended to protect groundwater resources. Approximately 260 wells have been installed since 1987. These wells were constructed to current standards for well construction which mandate seals between the permanent casing and the formation to prevent potential migration of contaminated liquid. Several programs presently construct and/or utilize existing and newly drilled wells to provide characterization and groundwater monitoring data. The programs are summarized

  3. Special study for the statistical evaluation of groundwater data trends. Final report

    International Nuclear Information System (INIS)

    1993-05-01

    Analysis of trends over time in the concentrations of chemicals in groundwater at Uranium Mill Tailings Remedial Action (UMTRA) Project sites can provide valuable information for monitoring the performance of disposal cells and the effectiveness of groundwater restoration activities. Random variation in data may obscure real trends or may produce the illusion of a trend where none exists, so statistical methods are needed to reliably detect and estimate trends. Trend analysis includes both trend detection and estimation. Trend detection uses statistical hypothesis testing and provides a yes or no answer regarding the existence of a trend. Hypothesis tests try to reach a balance between false negative and false positive conclusions. To quantify the magnitude of a trend, estimation is required. This report presents the statistical concepts that are necessary for understanding trend analysis. The types of patterns most likely to occur in UMTRA data sets are emphasized. Two general approaches to analyzing data for trends are proposed and recommendations are given to assist UMTRA Project staff in selecting an appropriate method for their site data. Trend analysis is much more difficult when data contain values less than the reported laboratory detection limit. The complications that arise are explained. This report also discusses the impact of data collection procedures on statistical trend methods and offers recommendations to improve the efficiency of the methods and reduce sampling costs. Guidance for determining how many sampling rounds might be needed by statistical methods to detect trends of various magnitudes is presented. This information could be useful in planning site monitoring activities

  4. Conceptual site models for groundwater contamination at 100-BC-5, 100-KR-4, 100-HR-3, and 100-FR-3 operable units

    International Nuclear Information System (INIS)

    Peterson, R.E.; Raidl, R.F.; Denslow, C.W.

    1996-09-01

    This document presents technical information on groundwater contamination in the 100-BC-5, 100-KR-4, 100-HR-3, and 100-FR-3 Operable Units on the Hanford Site in Richland, Washington. These operable units are defined for groundwater that underlies the retired plutonium production reactors and their associated support facilities. This technical information supports conceptual site models (CSM) for each operable unit. The goal in maintaining a CSM is to ensure that a reasonable understanding of contamination issues in each groundwater operable unit is available for selecting a final remediation alternative and for developing a record of decision. CSMs are developed for hazardous waste sites to help evaluate potential risks to human health and the environment from exposure to contamination

  5. Petrol contaminated groundwater treatment with air-stripper in Balassagyarmat, Hungary

    International Nuclear Information System (INIS)

    Szabo, Peter; Bernath, Balazs

    2005-01-01

    Hydrocarbon contaminated groundwater is a common environmental problem in Hungary. Leakage of underground storage tanks, pipe break or illegal tapping as well as lorry accidents can be mentioned as main reasons. MEGATERRA Ltd. elaborated, adopted and tested several groundwater clean-up methods. These methods are based on detailed survey and investigation, sampling and analysis, delineation of contaminated groundwater, risk assessment, establishment of monitoring wells, pumping tests and remediation action plan. One of these methods was implemented by MEGATERRA Ltd. in Balassagyarmat, Hungary. Contamination source was a 10 m 3 vol. simple wall underground fuel-storage tank, which had been emptied. When the remediation started in April 1998, the petrol had already been accumulated on the ground water table forming a 5-7 m wide and 10-15 m long plume being expanded to SSE-NNW direction. The area of the dissolved hydrocarbon contaminated groundwater-body was 1 000 m 2 and its concentration reached up to 30-40 mg/l TPH. The free-phase hydrocarbon layer was 10 cm thick. For the remediation of contaminated groundwater MEGATERRA Ltd. applied pump and treat method, namely groundwater pumping using extraction well, skimming of free-phase hydrocarbon, stripping of the contaminated ground water in air-stripper tower and draining of the treated groundwater into a drainage ditch. In the centre of the plume we established an extraction well with 300 mm diameter in a 500 mm borehole. Peristaltic skimmer pump was used inside the extraction well to remove the free phase petrol from the ground water surface.Because of the intense volatility of the pollutant we applied aeration (stripping) technology. The extracted contaminated groundwater was cleaned in air-stripper equipment being able to eliminate efficiently the volatile pollutants from the water. The aeration tower is a compact cylindrical shaped column with 650 mm in diameter. Its height depends on the pollutant's type The

  6. Soil and groundwater cleanup: benefits and limits of emerging technologies

    Energy Technology Data Exchange (ETDEWEB)

    Caliman, Florentina Anca; Robu, Brindusa Mihaela; Smaranda, Camelia; Pavel, Vasile Lucian; Gavrilescu, Maria [Technical University of Iasi, Department of Environmental Engineering and Management, Faculty of Chemical Engineering and Environmental Protection, Iasi (Romania)

    2011-04-15

    Contaminated soil and groundwater have been the subject of study and research, so that the field of remediation has grown and evolved, continually developing and adopting new technologies in attempts to improve the decontamination. The cleanup of environmental pollution involves a variety of techniques, ranging from simple biological processes to advanced engineering technologies. Cleanup activities may also address a wide range of contaminants. This article is a short analysis of the technologies for cleaning up groundwater and soil, highlighting knowledge and information gaps. Challenges and strategies for cleaning up different types of contaminants, mainly heavy metals and persistent organic compounds are described. Included are technologies that treat ground water contaminants in place in the subsurface and soil technologies that treat the soil either in place or on site in a treatment unit. Emerging technologies such as those based on oxidation-reduction, bioremediation, and nanotechnologies are covered. It is evident that for a good efficiency of remediation, techniques or even whole new technologies may be incorporated into an existing technology as a treatment train, improving its performance or overcome limitations. Several economic and decision-making elements are developed in the final part, based on the analysis carried out throughout the article. The work highlights the fact that excellence in research and technology progress could be attained by the development of technologies to deal more effectively and economically with certain toxic contaminants such as heavy metals, volatile organic compounds, and persistent organic pollutants, associated with optimization of technologies under field remediation conditions and requirements, improving capacity and yields, and reducing costs. Moreover, increasing knowledge of the scope and problem of equipment development could improve the benefits. (orig.)

  7. Remediation of groundwater contaminated with arsenic through enhanced natural attenuation: Batch and column studies.

    Science.gov (United States)

    Hafeznezami, Saeedreza; Zimmer-Faust, Amity G; Jun, Dukwoo; Rugh, Megyn B; Haro, Heather L; Park, Austin; Suh, Jae; Najm, Tina; Reynolds, Matthew D; Davis, James A; Parhizkar, Tarannom; Jay, Jennifer A

    2017-10-01

    Batch and column laboratory experiments were conducted on natural sediment and groundwater samples from a contaminated site in Maine, USA with the aim of lowering the dissolved arsenate [As(V)] concentrations through chemical enhancement of natural attenuation capacity. In batch factorial experiments, two levels of treatment for three parameters (pH, Ca, and Fe) were studied at different levels of phosphate to evaluate their impact on As(V) solubility. Results illustrated that lowering pH, adding Ca, and adding Fe significantly increased the sorption capacity of sediments. Overall, Fe amendment had the highest individual impact on As(V) levels. To provide further evidence for the positive impact of Ca on As(V) adsorption, isotherm experiments were conducted at three different levels of Ca concentrations. A consistent increase in adsorption capacity (26-37%) of sediments was observed with the addition of Ca. The observed favorable effect of Ca on As(V) adsorption is likely caused by an increase in the surface positive charges due to surface accumulation of Ca 2+ ions. Column experiments were conducted by flowing contaminated groundwater with elevated pH, As(V), and phosphate through both uncontaminated and contaminated sediments. Potential in-situ remediation scenarios were simulated by adding a chemical amendment feed to the columns injecting Fe(II) or Ca as well as simultaneous pH adjustment. Results showed a temporary and limited decrease in As(V) concentrations under the Ca treatment (39-41%) and higher levels of attenuation in Fe(II) treated columns (50-91%) but only after a certain number of pore volumes (18-20). This study illustrates the importance of considering geochemical parameters including pH, redox potential, presence of competing ions, and sediment chemical and physical characteristics when considering enhancing the natural attenuation capacity of sediments to mitigate As contamination in natural systems. Copyright © 2017 Elsevier Ltd. All rights

  8. FEASIBILITY STUDY REPORT FOR THE 200-ZP-1 GROUNDWATER OPERABLE UNIT

    Energy Technology Data Exchange (ETDEWEB)

    BYRNES ME

    2008-07-18

    , and to the extent practicable, the NCP. This FS conforms to the conditions set forth in the Hanford Federal Facility Agreement and Consent Order (Tri-Party Agreement) (Ecology et al. 2003) and amendments, signed by the Washington State Department of Ecology (Ecology), EPA, and DOE Richland Operations Office (RL). This also includes Tri-Party Agreement Milestone M-015-00C for completing all 200 Area non-tank farm OU pre-Record of Decision (ROD) documents on or before December 31, 2011. This FS supports the final remedy selection for the 200-ZP-1 OU, as described in the Remedial Investigation/Feasibility Study Work Plan for the 200-ZP-1 Groundwater Operable Unit (referred to as the 200-ZP-1 RI/FS work plan) (DOE/RL-2003-55), as agreed upon by RL and EPA. Tri-Party Agreement Milestone M-015-48B required Draft A of the 200-ZP-1 OU FS and proposed plan to be transmitted to EPA by September 30, 2007. As agreed to with EPA in the 200 Area Unit Managers Meeting Groundwater Operable Unit Status (FH-0503130), the baseline risk assessment (BRA) was delayed from inclusion in the remedial investigation (RI) report and is completed and documented in this FS. The Remedial Investigation Report for 200-ZP-1 Groundwater Operable Unit (referred to as the 200-ZP-1 RI report) (DOE/RL-2006-24) included an evaluation of human health and ecological risks and hazards. The RI report identified the radiological and chemical contaminants of potential concern (COPCs) that represent the primary risks to human health and the environment. The complete risk assessment in this FS incorporates additional analytical data from the unconfined aquifer that were obtained during or after preparation of the RI report, particularly for carbon tetrachloride and technetium-99. This FS also includes the initial results from an ongoing study of technetium-99 contamination near WMA-T, the sampling of new wells near the 216-W-LC laundry waste crib and T Plant, updated Hanford vadose zone fate and transport modeling

  9. Design requirements for ERD and ISCO: How close and how fast to achieve an effective remediation?

    DEFF Research Database (Denmark)

    Chambon, Julie Claire Claudia; Lemming, Gitte; Manoli, Gabriele

    2011-01-01

    Clayey tills contaminated with chlorinated solvents are a threat to groundwater and are difficult to remediate. Full scale Enhanced Reductive Dechlorination (ERD) and In-Situ Chemical Oxidation (ISCO) are promising remediation technologies for such sites, but the delivery of reactants...

  10. A Mathematical Model for Simulating Remediation of Groundwater Contaminated by Heavy Metals using Bio-Carriers with Dead Baccilus sp. B1 and Polysulfone

    Science.gov (United States)

    Seo, H.; Wang, S.; Lee, M.

    2010-12-01

    The remediation of groundwater contaminated by heavy metals, organic contaminants, etc. using various types of bio-carriers has been widely studied as a novel technology in the literature. In this study, a series of batch experiments were conducted to investigated the fundamental characteristics in the removal process using bio-carriers (beads) with dead Bacillus sp. B1 and polysulfone. Through equilibrium and kinetic sorption experiments, sorption efficiencies for lead and copper under various conditions such as pH, temperature, contaminant concentration, etc. were examined and sorption parameters including maximum sorption capacities were obtained for model applications. Experimental data showed that equilibrium sorption patterns for Pb2+and Cu2+on bio-carrier beads follows Langmuir sorption isotherm and that the sorption dynamics can be described with a pseudo-second-order kinetics. One dimensional advective-dispersive-reactive transport model was also developed for simulating and analyzing the remediation processes. The HSDM (homogeneous surface diffusion model) were incorporated in the model to take into account the mass transfer and sorption mechanisms around/inside the bio-carrier beads. Applying the proposed model, numerical column experiments were carried out and the simulation results reasonably described temporal and spatial distribution of Pb2+and Cu2+in a fixed-bed flow-through sorption column. Experimental and numerical results showed that the main mechanism of the bio-carrier to remove heavy metals is the sorption on/inside of the bio-carriers and the bio-carriers can function as excellent biosorbents for the removal of heavy metal ions from groundwater.

  11. NASA Remediation Technology Collaboration Development Task, Overview and Project Summaries

    Science.gov (United States)

    Romeo, James G.

    2014-01-01

    An overview presentation of NASA's Remediation Technology Collaboration Development Task including the following project summaries: in situ groundwater monitor, in situ chemical oxidation, in situ bioremediation, horizontal multi-port well, and high resolution site characterization.

  12. Remediation of arsenic-contaminated groundwater using media-injected permeable reactive barriers with a modified montmorillonite: sand tank studies.

    Science.gov (United States)

    Luo, Ximing; Liu, Haifei; Huang, Guoxin; Li, Ye; Zhao, Yan; Li, Xu

    2016-01-01

    A modified montmorillonite (MMT) was prepared using an acid activation-sodium activation-iron oxide coating method to improve the adsorption capacities of natural MMTs. For MMT, its interlamellar distance increased from 12.29 to 13.36 Å, and goethite (α-FeOOH) was intercalated into its clay layers. Two novel media-injected permeable reactive barrier (MI-PRB) configurations were proposed for removing arsenic from groundwater. Sand tank experiments were conducted to investigate the performance of the two MI-PRBs: Tank A was filled with quartz sand. Tank B was packed with quartz sand and zero-valent iron (ZVI) in series, and the MMT slurry was respectively injected into them to form reactive zones. The results showed that for tank A, total arsenic (TA) removal of 98.57% was attained within the first 60 mm and subsequently descended slowly to 88.84% at the outlet. For tank B, a similar spatial variation trend was observed in the quartz sand layer, and subsequently, TA removal increased to ≥99.80% in the ZVI layer. TA removal by MMT mainly depended on both surface adsorption and electrostatic adhesion. TA removal by ZVI mainly relied on coagulation/precipitation and adsorption during the iron corrosion. The two MI-PRBs are feasible alternatives for in situ remediation of groundwater with elevated As levels.

  13. The lost value of groundwater and its influence on environmental decision making.

    Science.gov (United States)

    Paleologos, Evan K

    2008-08-01

    A critical aspect in establishing environmental policies lies in the proper assessment of the value of the resource being affected. Standard risk assessment analyses calculate the cost of pollution as consisting, solely, of the cost to remediate a site. This traditional definition is extended here to include the lost value of groundwater. These concepts and their impact on decision-making analyses are illustrated through the case of municipal waste landfills. Based on data from existing polluting sites, a simple cost-benefit probabilistic analysis is conducted first, which equates, as is the practice, the cost of pollution to that of remediation. This leads rationally to selection of the lowest-protection technology. Using plausible arguments the reduction in value of groundwater from potable high-quality water to irrigation water, which is what is returned after remediation, is argued. The arguments consist of: (a) the ratio of the subsidized prices of drinking to irrigation water reflects the relative value of the use of water; (b) the amount paid for remediation, in each case, represents, at a minimum, the value of the water recovered; and (c) the lost value of groundwater equals the value of drinking water minus the value of irrigation water. Incorporation of this lost value of groundwater is sufficient to drastically alter the conclusions of the decision-making analysis and make the highest level technology the most rational and profitable alternative. The broader point of this article lies in that proper accounting of environmental costs is necessary in order to alter environmental policies and practices.

  14. Environmental impact of differently remediated hard coal overburden and tailings dumps a few decades after remediation

    International Nuclear Information System (INIS)

    Willscher, S.; Felix, M.; Sohr, A.

    2010-01-01

    Coal mining in the Saxony region of Germany has caused heavy metal and arsenic pollution in adjacent groundwater and surface waters. Coal waste dumping sites are leaching heavy metals and metalloids in the form of fine precipitates into local rivers. This paper studied the different remediation strategies used at 3 different dump sites in the area. The aim of the study was to determine the environmental impact of the dumps and evaluate the long-term effects of remediation measures. The dumps consisted of coarse to fine-grained materials from former processing activities, and contained pyrite in varying concentrations. Samples from different depth as well as groundwater samples were taken from the sites and investigated for their mechanical, geological, geochemical, biogeochemical, and physico-chemical characteristics. Seepage formation rates and contaminant loads at the dump sites were compared. The study showed that the revegetation of dump surfaces can help to prevent against erosion, but cannot prevent acid mine drainage (AMD) generation. The additional seals and covers placed at 2 of the dumps resulted in a high reduction of seepage waters, and almost no acidification of dump materials. 5 refs., 1 fig.

  15. Baseline risk assessment for groundwater contamination at the uranium mill tailings site near Monument Valley, Arizona

    International Nuclear Information System (INIS)

    1993-09-01

    This baseline risk assessment evaluates potential impact to public health or the environment resulting from groundwater contamination at the former uranium mill processing site near Monument Valley, Arizona. The tailings and other contaminated material at this site are being relocated and stabilized in a disposal cell at Mexican Hat, Utah, through the US Department of Energy (DOE) Uranium Mill Tailings Remedial Action (UMTRA) Project. The tailings removal is planned for completion by spring 1994. After the tailings are removed, groundwater contamination at the site will continue to be evaluated. This risk assessment is the first document specific to this site for the Groundwater Project. It will be used to assist in determining what remedial action is needed for contaminated groundwater at the site

  16. Summary report of Hanford Site well remediation and decommissioning activities for fiscal year 1994

    International Nuclear Information System (INIS)

    Reynolds, K.D.

    1994-01-01

    Remediation and decommissioning of Hanford Site wells has become an integral part of Hanford Site Environmental Restoration (ER) and Resource Conservation and Recovery Act of 1976 (RCRA) groundwater monitoring programs. A well remediation and decommissioning program was funded and implemented in fiscal year (FY) 1993 under the RCRA and Operational Monitoring (ROM) Program. Funding for this work increased in FY 1994. In FY 1994 well decommissioning activities conducted for the ROM program were centered around the 200 West Area; activities for the ER program were centered in the Fitzner/Eberhart Arid Land Ecology (ALE) (Reserve) unit and the Wahluke Slope (North Slope) area. A total of 116 wells and test borings were decommissioned between the two programs during FY 1994. Additionally, five wells were identified as in need of remediation and were successfully brought into compliance with regulatory requirements. As Hanford Site restoration and remediation efforts increase in scope, the well decommissioning program will remain dynamic. The program will aggressively seek to fulfill the needs of the various environmental cleanup and groundwater/vadose monitoring programs. Wells that do not meet regulatory requirements for preservation will continually be identified and remediated or decommissioned accordingly

  17. Permeable reactive barriers for pollutant removal from groundwater

    International Nuclear Information System (INIS)

    Simon, F.G.; Meggyes, T.

    2001-01-01

    The removal of pollutants from the groundwater using permeable reactive barriers is a novel in-situ groundwater remediation technology. The most relevant decontamination processes used are chemical reduction, oxidation, precipitation and sorption, for which examples are given. Some common organic pollutants are halogenated hydrocarbons, aromatic and nitroaromatic compounds which can be treated in reactive barriers successfully. Lead, chromium and, in particular, uranium are dealt with in great detail among inorganic pollutants because of their occurrence in many European countries. Construction methods for cut-off walls and reactive barriers exhibit similar features. Apart from conventional methods, drilling, deep soil mixing, jet technology, arrays of wells, injected systems and biobarriers are applied to construct permeable reactive barriers. Permeable reactive barriers bear great potential for the future in remediation engineering. (orig.)

  18. Groundwater Availability Within the Salton Sea Basin Final Report

    Energy Technology Data Exchange (ETDEWEB)

    Tompson, A; Demir, Z; Moran, J; Mason, D; Wagoner, J; Kollet, S; Mansoor, K; McKereghan, P

    2008-01-11

    It is widely recognized that increasing demands for water in Southern California are being affected by actions to reduce and redirect the amount of water imported from the Colorado River. In the Imperial Valley region, for example, import reductions will not only affect agricultural users but also could produce significant collateral impacts on the level and quality of water in the Salton Sea, its regional ecology, or even the long term air quality in the greater basin. The notion of using groundwater in the Imperial Valley as an additional source for agricultural or domestic needs, energy production, or Salton Sea restoration efforts, so as to offset reductions in imported water, is not a new concept. Even though it has been discussed recently (e.g., LLNL, 2002), the idea goes back, in part, to several studies performed by the US Department of Interior and other agencies that have indicated that there may be substantial, usable amounts of groundwater in some portions of the Imperial Valley. It has been estimated, for example, that between 1.1 and 3 billion acre-feet (AF) of groundwater lie within the extended, deep basin underlying the valley and Salton Sea region, even though much of it may be unrecoverable or too poor in its quality (Imperial County, 1997). This is a significant volume with respect to the total annual precipitation volume received in California, whose average is close to 200 million (or 0.2 billion) AF per year (DWR, 1998), and especially with respect to the total annual precipitation received in the Salton Sea watershed itself, which we estimate (Appendix A) to be approximately 2.5 million acre feet (MAF) per year. Clearly, a thorough appraisal of the groundwater resources in the Imperial Valley and Salton Sea region--i.e., an assessment of their overall physical availability--will be needed to determine how they can be used and managed to suit new or redirected demands in the region. Development of an improved or updated groundwater assessment

  19. Life cycle assessment of soil and groundwater remediation technologies: literature review

    DEFF Research Database (Denmark)

    Lemming, Gitte; Hauschild, Michael Zwicky; Bjerg, Poul Løgstrup

    2010-01-01

    Background, aim, and scope Life cycle assessment (LCA) is becoming an increasingly widespread tool in support systems for environmental decision-making regarding the cleanup of contaminated sites. In this study, the use of LCA to compare the environmental impacts of different remediation...... and scope definition and the applied impact assessment. The studies differ in their basic approach since some are prospective with focus on decision support while others are retrospective aiming at a more detailed assessment of a completed remediation project. Literature review The literature review showed...... scenarios in terms of their associated environmental burden. Main features An overview of the assessed remediation technologies and contaminant types covered in the literature is presented. The LCA methodologies of the 12 reviewed studies were compared and discussed with special focus on their goal...

  20. RFI to CMS: An Approach to Regulatory Acceptance of Site Remediation Technologies

    Science.gov (United States)

    Rowland, Martin A.

    2001-01-01

    Lockheed Martin made a smooth transition from RCRA Facility Investigation (RFI) at the National Aeronautics and Space Administrations'(NASA) Michoud Assembly Facility (MA-F) to its Corrective Measures Study (CMS) phase within the RCRA Corrective Action Process. We located trichloroethylene (TCE) contamination that resulted from the manufacture of the Apollo Program Saturn V rocket and the Space Shuttle External Tank, began the cleanup, and identified appropriate technologies for final remedies. This was accomplished by establishing a close working relationship with the state environmental regulatory agency through each step of the process, and resulted in receiving approvals for each of those steps. The agency has designated Lockheed Martin's management of the TCE-contamination at the MAF site as a model for other manufacturing sites in a similar situation. In February 1984, the Louisiana Department of Environmental Quality (LDEQ) issued a compliance order to begin the clean up of groundwater contaminated with TCE. In April 1984 Lockheed Martin began operating a groundwater recovery well to capture the TCE plume. The well not only removes contaminants, but also sustains an inward groundwater hydraulic gradient so that the potential offsite migration of the TCE plume is greatly diminished. This effort was successful, and for the agency to give orders and for a regulated industry to follow them is standard procedure, but this is a passive approach to solving environmental problems. The goal of the company thereafter was to take a leadership, proactive role and guide the MAF contamination clean up to its best conclusion at minimum time and lowest cost to NASA. To accomplish this goal, we have established a positive working relationship with LDEQ, involving them interactively in the implementation of advanced remedial activities at MAF as outlined in the following paragraphs.

  1. Environmental assessment of remedial action at the Naturita Uranium Processing Site near Naturita, Colorado

    International Nuclear Information System (INIS)

    1994-05-01

    The Uranium Mill Tailings Radiation Control Act (UMTRCA) of 1978, Public Law (PL) 95-604, authorized the US Department of Energy (DOE) to perform remedial action at the Naturita, Colorado, uranium processing site to reduce the potential health effects from the radioactive materials at the site and at vicinity properties associated with the site. The US Environmental Protection Agency (EPA) promulgated standards for the UMTRCA that contain measures to control the contaminated materials and to protect groundwater quality. Remedial action at the Naturita site must be performed in accordance with these standards and with the concurrence of the US Nuclear Regulatory Commission (NRC) and the state of Colorado. The proposed remedial action for the Naturita processing site is relocation of the contaminated materials and debris to either the Dry Flats disposal site, 6 road miles (mi) [10 kilometers (km)] to the southeast, or a licensed non-DOE disposal facility capable of handling RRM. At either disposal site, the contaminated materials would be stabilized and covered with layers of earth and rock. The proposed Dry Flats disposal site is on land administered by the Bureau of Land Management (BLM) and used primarily for livestock grazing. The final disposal site would cover approximately 57 ac (23 ha), which would be permanently transferred from the BLM to the DOE and restricted from future uses. The remedial action would be conducted by the DOE's Uranium Mill Tailings Remedial Action (UMTRA) Project. This report discusses environmental impacts associated with the proposed remedial action

  2. Coordination of groundwater activities in the 100 N Area

    International Nuclear Information System (INIS)

    Hartman, M.J.

    1995-09-01

    The initiation of the N Springs Expedited Response Action (ERA) in the 100 N Area will affect the groundwater monitoring networks of two Resource Conservation and Recovery Act of 1976 (RCRA) units. The 1301-N and 325-N facilities are treatment, storage, or disposal (TSD) units that have been monitored under RCRA since 1987. In September 1994, the Washington State Department of Ecology issued an action memorandum, instructing the US Department of Energy (DOE) to take the action. The planned pump-and-treat system will preclude meeting the specific objectives of interim-status RCRA groundwater monitoring representative samples and detect adverse impacts of the TSD units on. However, under RCRA final-status requirements, which will be implemented in 1999, corrective action for groundwater contamination will probably be required. The US Environmental Protection Agency (EPA) has declared parity between RCRA corrective action and Comprehensive Environmental Response, Compensation, and Liability Act of 1980 remedial action decisions. The 1301-N and 1325-N facilities are still in interim-status and therefore are not in the category of ''RCRA corrective action.'' However, DOE's position is that parity exists between RCRA and the ERA because RCRA corrective action will almost certainly be required in the future

  3. Groundwater colloids: Their mobilization from subsurface deposits. Final report

    International Nuclear Information System (INIS)

    1998-01-01

    The overall goal of this program has involved developing basic understandings of the mechanisms controlling the presence of colloidal phases in groundwaters. The presence of colloids in groundwater is extremely important in that they may enable the subsurface transport of otherwise immobile pollutants like plutonium or PCBs. The major findings of this work have included: (1) Sampling groundwaters must be performed with great care in order to avoid false positives; (2) Much of the colloidal load moving below ground derives from the aquifer solids themselves; and (3) The detachment of colloids from the aquifer solids occurs in response to changes in the groundwater solution chemistry

  4. Effect of groundwater geochemistry on pentachlorophenol remediation by smectite-templated nanosized Pd0/Fe0.

    Science.gov (United States)

    Jia, Hanzhong; Gu, Cheng; Li, Hui; Fan, Xiaoyun; Li, Shouzhu; Wang, Chuanyi

    2012-09-01

    Zero-valent iron holds great promise in treating groundwater, and its reactivity and efficacy depend on many surrounding factors. In the present work, the effects of solution chemistry such as pH, humic acid (HA), and inorganic ions on pentachlorophenol (PCP) dechlorination by smectite-templated Pd(0)/Fe(0) were systematically studied. Smectite-templated Pd(0)/Fe(0) was prepared by saturating the negatively charged sites of smectite clay with Fe(III) and a small amount of Pd(II), followed by borohydride reduction to convert Fe(III) and Pd(II) into zero-valent metal clusters. Batch experiments were conducted to investigate the effects of water chemistry on PCP remediation. The PCP dechlorination rate critically depends on the reaction pH over the range 6.0~10.0; the rate constant (k (obs)) increases with decreasing the reaction pH value. Also, the PCP remediation is inhibited by HA, which can be attributed to the electron competition of HA with H(+). In addition, the reduction of PCP can be accelerated by various anions, following the order: Cl(-) > HCO (3) (-) > SO (4) (2-) ~no anion. In the case of cations, Ca(2+) and Mg(2+) (10 mM) decrease the dechlorination rate to 0.7959 and 0.7798 from 1.315 h(-1), respectively. After introducing HA into the reaction systems with cations or/and anions, the dechlorination rates are similar to that containing HA alone. This study reveals that low pH and the presence of some anions such as Cl(-) facilitate the PCP dechlorination and induce the rapid consumption of nanosized zero-valent iron simultaneously. However, the dechlorination rate is no longer correlated to the inhibitory or accelerating effects by cations and anions in the presence of 10 mg/L HA.

  5. Arsenic speciation and uranium concentrations in drinking water supply wells in Northern Greece: Correlations with redox indicative parameters and implications for groundwater treatment

    International Nuclear Information System (INIS)

    Katsoyiannis, Ioannis A.; Hug, Stephan J.; Ammann, Adrian; Zikoudi, Antonia; Hatziliontos, Christodoulos

    2007-01-01

    The cities in the Aksios and Kalikratia areas in Northern Greece rely on arsenic contaminated groundwater for their municipal water supply. As remedial action strongly depends on arsenic speciation, the presence of other possible contaminants, and on the general water composition, a detailed study with samples from 21 representative locations was undertaken. Arsenic concentrations were typically 10-70 μg/L. In the groundwaters of the Aksios area with lower Eh values (87-172 mV), pH 7.5-8.2 and 4-6 mM HCO 3 alkalinity, As(III) predominated. Manganese concentrations were mostly above the EC standard of 0.05 mg/L (0.1-0.7 mg/L). In groundwaters of the Kalikratia area with higher Eh values (272-352 mV), pH 6.7-7.5 and 6-12 mM HCO 3 alkalinity, As(V) was the main species. Uranium in the groundwaters was also investigated and correlations with total arsenic concentrations and speciation were examined to understand more of the redox chemistry of the examined groundwaters. Uranium concentrations were in the range 0.01-10 μg/L, with the higher concentrations to occur in the oxidizing groundwaters of the Kalikratia area. Uranium and total arsenic concentrations showed no correlation, whereas uranium concentrations correlated strongly with As(III)/As(tot) ratios, depicting their use as a possible indicator of groundwater redox conditions. Finally, boron was found to exceed the EC drinking water standard of 1 mg/L in some wells in the Kalikratia area and its removal should also be considered in the design of a remedial action

  6. Groundwater contaminant plume ranking

    International Nuclear Information System (INIS)

    1988-08-01

    Containment plumes at Uranium Mill Tailings Remedial Action (UMTRA) Project sites were ranked to assist in Subpart B (i.e., restoration requirements of 40 CFR Part 192) compliance strategies for each site, to prioritize aquifer restoration, and to budget future requests and allocations. The rankings roughly estimate hazards to the environment and human health, and thus assist in determining for which sites cleanup, if appropriate, will provide the greatest benefits for funds available. The rankings are based on the scores that were obtained using the US Department of Energy's (DOE) Modified Hazard Ranking System (MHRS). The MHRS and HRS consider and score three hazard modes for a site: migration, fire and explosion, and direct contact. The migration hazard mode score reflects the potential for harm to humans or the environment from migration of a hazardous substance off a site by groundwater, surface water, and air; it is a composite of separate scores for each of these routes. For ranking the containment plumes at UMTRA Project sites, it was assumed that each site had been remediated in compliance with the EPA standards and that relict contaminant plumes were present. Therefore, only the groundwater route was scored, and the surface water and air routes were not considered. Section 2.0 of this document describes the assumptions and procedures used to score the groundwater route, and Section 3.0 provides the resulting scores for each site. 40 tabs

  7. Remedial action plan and site conceptual design for stabilization of the inactive uranium mill tailings sites at Rifle, Colorado. Appendix D, Final report

    International Nuclear Information System (INIS)

    1992-02-01

    This appendix assesses the present conditions and data gathered about the two designated inactive uranium mill tailings sites near Rifle, Colorado, and the proposed disposal site six miles north of Rifle in the area of Estes Gulch. It consolidates available engineering, radiological, geotechnical, hydrological, meteorological, and other information pertinent to the design of the Remedial Action Plan (RAP). The data characterize conditions at the mill, tailings, and disposal site so that the Remedial Action Contractor (RAC) may complete final designs for the remedial actions

  8. Remedial action plan and site conceptual design for stabilization of the inactive uranium mill tailings sites at Rifle, Colorado. Appendix D, Final report

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1992-02-01

    This appendix assesses the present conditions and data gathered about the two designated inactive uranium mill tailings sites near Rifle, Colorado, and the proposed disposal site six miles north of Rifle in the area of Estes Gulch. It consolidates available engineering, radiological, geotechnical, hydrological, meteorological, and other information pertinent to the design of the Remedial Action Plan (RAP). The data characterize conditions at the mill, tailings, and disposal site so that the Remedial Action Contractor (RAC) may complete final designs for the remedial actions.

  9. DOE-EMSP Final Report: Characterization of Changes in Colloid and DNAPL Affecting Surface Chemistry and Remediation

    Energy Technology Data Exchange (ETDEWEB)

    Susan E. Powers; Stefan J. Grimberg; Miles Denham

    2007-02-07

    The waste disposal to the M-area basin and A-14 outfall at the Savannah River Department of Energy facility in Aiken SC (USA) included a wide variety of inorganic aqueous flows and organic solvents in the form of dense non-aqueous phase liquids (DNAPL). The DNAPL has migrated through the subsurface resulting in widespread groundwater contamination. The goal of this research was to identify and quantify processes that could have affected the migration and remediation of the DNAPL in the subsurface. It was hypothesized that the variety of waste disposed at this site could have altered the mineral, microbial and DNAPL properties at this site relative to other DNAPL sites. The DNAPL was determined to have a very low interfacial tension and is suspected to be distributed in fine grained media, thereby reducing the effectiveness of soil vapor extraction remediation efforts. Although the DNAPL is primarily comprised of tetrachloroethene and trichloroethane, it also contains organic acids and several heavy metals. Experimental results suggest that iron from the aqueous and DNAPL phases undergoes precipitation and dechlorination reactions at the DNAPL-water interface, contributing to the low interfacial tension and acidity of the DNAPL. Biological activity in the contaminated region can also contribute to the low interfacial tension. PCE degrading bacteria produce biosurfactants and adhere to the DNAPL-water interface when stressed by high tetrachloroethene or low dissolved oxygen concentrations. The presence of iron can reduce the interfacial tension by nearly an order of magnitude, while the PCE degraders reduced the interfacial tension by nearly 50%. Abiotic changes in the mineral characteristics were not found to be substantially different between contaminated and background samples. The research completed here begins to shed some insight into the complexities of DNAPL fate and migration at sites where co-disposal of many different waste products occurred. Quantifying

  10. An integrated approach to risk-based remediation of a former bulk fuel storage facility adjacent a marine environment

    Energy Technology Data Exchange (ETDEWEB)

    Kemp, L.; Hers, I. [Golder Associates Ltd., Vancouver, BC (Canada)

    2006-07-01

    An integrated approach to risk-based remediation of a former bulk fuel storage facility adjacent to a marine environment was discussed. The presentation provided an introduction and illustration to the site location and history, located close to Skagway, Alaska and northwestern British Columbia. The site investigation and conceptual model were also presented. The remedial approach was also described with reference to a risk-based action approach, remedial objectives, soil vapour extraction (SVE)-bioventing, and air sparging-biosparging. The objectives were to minimize potential exposure to aquatic receptors by minimizing non-aqueous phase liquids (NAPL) mobility and dissolved transport of petroleum hydrocarbons. Groundwater modeling to assess the attenuation rate and to determine remedial targets was also discussed. Model validation and results of groundwater modeling as well as remediation system details and performance were then provided. It was determined that significant attenuation is occurring and that effective mass removal and concentrations have been decreasing over time. It was demonstrated that risk-based remedial goals and hydrogeology can change with land use/development. tabs., figs.

  11. Innovative technologies for groundwater cleanup

    International Nuclear Information System (INIS)

    Yow, J.L. Jr.

    1992-09-01

    These notes provide a broad overview of current developments in innovative technologies for groundwater cleanup. In this context, groundwater cleanup technologies include site remediation methods that deal with contaminants in ground water or that may move from the vadose zone into ground water. This discussion attempts to emphasize approaches that may be able to achieve significant improvements in groundwater cleanup cost or effectiveness. However, since data for quantitative performance and cost comparisons of new cleanup methods are scarce, preliminary comparisons must be based on the scientific approach used by each method and on the site-specific technical challenges presented by each groundwater contamination situation. A large number of technical alternatives that are now in research, development, and testing can be categorized by the scientific phenomena that they employ and by the site contamination situations that they treat. After reviewing a representative selection of these technologies, one of the new technologies, the Microbial Filter method, is discussed in more detail to highlight a promising in situ groundwater cleanup technology that is now being readied for field testing

  12. Applications of Ecological Engineering Remedies for Uranium Processing Sites, USA

    Energy Technology Data Exchange (ETDEWEB)

    Waugh, William [Navarro Research and Engineering

    2016-05-23

    The U.S. Department of Energy (USDOE) is responsible for remediation of environmental contamination and long-term stewardship of sites associated with the legacy of nuclear weapons production during the Cold War in the United States. Protection of human health and the environment will be required for hundreds or even thousands of years at many legacy sites. USDOE continually evaluates and applies advances in science and technology to improve the effectiveness and sustainability of surface and groundwater remedies (USDOE 2011). This paper is a synopsis of ecological engineering applications that USDOE is evaluating to assess the effectiveness of remedies at former uranium processing sites in the southwestern United States. Ecological engineering remedies are predicated on the concept that natural ecological processes at legacy sites, once understood, can be beneficially enhanced or manipulated. Advances in tools for characterizing key processes and for monitoring remedy performance are demonstrating potential. We present test cases for four ecological engineering remedies that may be candidates for international applications.

  13. Can nitrate contaminated groundwater be remediated by optimizing flood irrigation rate with high nitrate water in a desert oasis using the WHCNS model?

    Science.gov (United States)

    Liang, Hao; Qi, Zhiming; Hu, Kelin; Prasher, Shiv O; Zhang, Yuanpei

    2016-10-01

    Nitrate contamination of groundwater is an environmental concern in intensively cultivated desert oases where this polluted groundwater is in turn used as a major irrigation water resource. However, nitrate fluxes from root zone to groundwater are difficult to monitor in this complex system. The objectives of this study were to validate and apply the WHCNS (soil Water Heat Carbon Nitrogen Simulator) model to simulate water drainage and nitrate leaching under different irrigation and nitrogen (N) management practices, and to assess the utilization of groundwater nitrate as an approach to remediate nitrate contaminated groundwater while maintain crop yield. A two-year field experiment was conducted in a corn field irrigated with high nitrate groundwater (20 mg N L(-1)) in Alxa, Inner Mongolia, China. The experiment consisted of two irrigation treatments (Istd, standard, 750 mm per season; Icsv, conservation, 570 mm per season) factorially combined with two N fertilization treatments (Nstd, standard, 138 kg ha(-1); Ncsv, conservation, 92 kg ha(-1)). The validated results showed that the WHCNS model simulated values of crop dry matter, yield, soil water content and soil N concentration in soil profile all agreed well with the observed values. Compared to the standard water management (Istd), the simulated drainage and nitrate leaching decreased about 65% and 59%, respectively, under the conservation water management (Icsv). Nearly 55% of input N was lost by leaching under the IstdNstd and IstdNcsv treatments, compared to only 26% under the IcsvNstd and IcsvNcsv treatments. Simulations with more than 240 scenarios combing different levels of irrigation and fertilization indicated that irrigation was the main reason leading to the high risk of nitrate leaching, and the nitrate in irrigation groundwater can be best utilized without corn yield loss when the total irrigation was reduced from the current 750 mm to 491 mm. This reduced irrigation rate facilitated

  14. Characterization plan for the Oak Ridge National Laboratory Area-Wide Groundwater Program, Oak Ridge, Tennessee

    International Nuclear Information System (INIS)

    1994-08-01

    This characterization plan has been developed as part of the U.S. Department of Energy's (DOE's) investigation of the Groundwater Operable Unit (GWOU) at Oak Ridge National Laboratory (ORNL) located near Oak Ridge, Tennessee. The first iteration of the characterization plan is intended to serve as a strategy document to guide subsequent GWOU remedial investigations. The plan provides a rationale and organization for groundwater data acquisition, monitoring, and remedial actions to be performed during implementation of environmental restoration activities associated with the ORNL GWOU. It is important to note that the characterization plan for the ORNL GWOU is not a prototypical work plan. As such, remedial investigations will be conducted using annual work plans to manage the work activities, and task reports will be used to document the results of the investigations. Sampling and analysis results will be compiled and reported annually with a review of data relative to risk (screening level risk assessment review) for groundwater. This characterization plan outlines the overall strategy for the remedial investigations and defines tasks that are to be conducted during the initial phase of investigation. This plan is presented with the understanding that more specific addenda to the plan will follow

  15. Cavitational Hydrothermal Oxidation: A New Remediation Process - Final Report

    Energy Technology Data Exchange (ETDEWEB)

    Suslick, K. S.

    2001-07-05

    During the past year, we have continued to make substantial scientific progress on our understanding of cavitation phenomena in aqueous media and applications of cavitation to remediation processes. Our efforts have focused on three separate areas: sonoluminescence as a probe of conditions created during cavitational collapse in aqueous media, the use of cavitation for remediation of contaminated water, and an addition of the use of ultrasound in the synthesis of novel heterogeneous catalysts for hydrodehalogenation of halocarbons under mild conditions.

  16. Proceedings of the remediation technologies symposium, RemTech 2010

    International Nuclear Information System (INIS)

    2010-01-01

    In response to concerns regarding environmental impacts resulting from the extraction and production of fossil fuels, many oil and gas operators are seeking ways to reduce their environmental footprint and ensure the sustainable development of the industry. This symposium provided a forum to discuss innovations in soil and groundwater remediation. It highlighted recent work conducted in the field of contamination and remediation of industrial pollutant treatments. The conference technical sessions were entitled: British Columbia perspective; DND sites; hydrocarbons; oilfield remediation; Saskatchewan perspective; brownfields; miscellaneous; Quebec perspective; laboratory analysis and testing; landfill management and remediation; and, in-situ treatment methods. Some presentations also reviewed biological and non-biological treatment methods; thermal desorption; encapsulation; natural attenuation; multi-phase extraction; solar detoxification; electrochemical remediation; pre-treatment considerations; phytoremediation; and environmental management. The pre-conference workshop discussed methods of working with the federal government on future contaminated sites. The symposium featured 67 presentations, of which 26 have been catalogued separately for inclusion in this database

  17. Proceedings of the remediation technologies symposium, RemTech 2010

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2010-07-01

    In response to concerns regarding environmental impacts resulting from the extraction and production of fossil fuels, many oil and gas operators are seeking ways to reduce their environmental footprint and ensure the sustainable development of the industry. This symposium provided a forum to discuss innovations in soil and groundwater remediation. It highlighted recent work conducted in the field of contamination and remediation of industrial pollutant treatments. The conference technical sessions were entitled: British Columbia perspective; DND sites; hydrocarbons; oilfield remediation; Saskatchewan perspective; brownfields; miscellaneous; Quebec perspective; laboratory analysis and testing; landfill management and remediation; and, in-situ treatment methods. Some presentations also reviewed biological and non-biological treatment methods; thermal desorption; encapsulation; natural attenuation; multi-phase extraction; solar detoxification; electrochemical remediation; pre-treatment considerations; phytoremediation; and environmental management. The pre-conference workshop discussed methods of working with the federal government on future contaminated sites. The symposium featured 67 presentations, of which 26 have been catalogued separately for inclusion in this database. tabs., figs.

  18. Baseline risk assessment for groundwater contamination at the uranium mill tailings site near Monument Valley, Arizona. Draft

    Energy Technology Data Exchange (ETDEWEB)

    1993-09-01

    This baseline risk assessment evaluates potential impact to public health or the environment resulting from groundwater contamination at the former uranium mill processing site near Monument Valley, Arizona. The tailings and other contaminated material at this site are being relocated and stabilized in a disposal cell at Mexican Hat, Utah, through the US Department of Energy (DOE) Uranium Mill Tailings Remedial Action (UMTRA) Project. The tailings removal is planned for completion by spring 1994. After the tailings are removed, groundwater contamination at the site will continue to be evaluated. This risk assessment is the first document specific to this site for the Groundwater Project. It will be used to assist in determining what remedial action is needed for contaminated groundwater at the site.

  19. Strategic Considerations for the Sustainable Remediation of Nuclear Installations

    International Nuclear Information System (INIS)

    Miller, Susan; Wilson, Ian; Decung, Fabien; Ollivier Dehaye, Catherine; Pellenz, Gilles; Palut-Laurent, Odile; Nitzsche, Olaf; Rehs, Bernd; Altavilla, Massimo; Osimani, Celso; Florya, Sergey; Revilla, Jose-Luis; Efraimsson, Henrik; Baines, Kim; Clark, Anna; Cruickshank, Julian; Mitchell, Nick; Mobbs, Shelly; Orr, Peter; Abu-Eid, Rateb Boby; Durham, Lisa; Morse, John; Walker, Stuart; Weber, Inge; ); Monken-Fernandes, Horst; )

    2016-01-01

    Nuclear sites around the world are being decommissioned and remedial actions are being undertaken to enable sites, or parts of sites, to be reused. Although such activities are relatively straightforward for most sites, experience has suggested that preventative action is needed to minimise the impact of remediation activities on the environment and the potential burden to future generations. Removing all contamination in order to make a site suitable for any use generates waste and has associated environmental, social and economic drawbacks and benefits. Site remediation should thus be sustainable and result in an overall net benefit. This report draws on recent experience of NEA member countries in nuclear site remediation during decommissioning in order to identify strategic considerations for the sustainable remediation of subsurface contamination - predominantly contaminated soil and groundwater - to describe good practice, and to make recommendations for further research and development. It provides insights for the decision makers, regulators, implementers and stakeholders involved in nuclear site decommissioning so as to ensure the sustainable remediation of nuclear sites, now and in the future. (authors)

  20. Risk assessment of exposure to volatile organic compounds in groundwater in Taiwan

    Energy Technology Data Exchange (ETDEWEB)

    Fan Chihhao [Department of Safety, Health, and Environmental Engineering, Mingchi University of Technology, Taipei County, Taiwan (China); Wang, G.-S. [Department of Public Health, National Taiwan University, Taipei, Taiwan (China); Chen, Y.-C. [Energy and Environment Research Laboratories, Industrial Technology Research Institute, Hsinchu County, Taiwan (China); Ko, C.-H. [School of Forest and Resources Conservation, National Taiwan University, Taipei, Taiwan (China)], E-mail: chunhank@ntu.edu.tw

    2009-03-15

    The purpose of this study is to assess the risks from exposure to 14 volatile organic compounds (VOCs) in selected groundwater sites in Taiwan. The study employs the multimedia environment pollutant assessment system (MEPAS) model to calculate the specific non-cancer and cancer risks at an exposure level of 1 {mu}g/L of each VOC for a variety of exposure pathways. The results show that the highest specific non-cancer risk is associated with water ingestion of vinyl chloride (VC) and that the highest specific cancer risk is associated with indoor breathing of VC. The three most important exposure pathways for risk assessment for both non-cancer and cancer risks are identified as water ingestion, dermal absorption when showering, and indoor breathing. Excess tetrachloroethylene (PCE), trichloroethylene (TCE), dichloroethylene (DCE), and VC are detected in the groundwater aquifers of one dump site and one factory. However, the study suggests that the pollutants in the contaminated groundwater aquifers do not travel extensively with groundwater flow and that the resulting VOC concentrations are below detectable levels for most of the sampled drinking-water treatment plants. Nevertheless, the non-cancer and cancer risks resulting from use of the contaminated groundwater are found to be hundred times higher than the general risk guidance values. To ensure safe groundwater utilisation, remediation initiatives for soil and groundwater are required. Finally, the study suggests that the current criteria for VOCs in drinking water might not be capable of ensuring public safety when groundwater is used as the primary water supply; more stringent quality criteria for drinking water are proposed for selected VOCs.

  1. Non-attainment policy: A viable approach for groundwater remediation

    International Nuclear Information System (INIS)

    Javandel, I.

    1995-01-01

    The National Research Council recently completed a three-year study entitled open-quotes Alternatives for Groundwater Cleanupclose quotes. One of the conclusions of this study indicated that for sites with a complex geologic and hydrologic set up, existing technologies may not be able to restore contaminated aquifers to health-based standards. Therefore, the most logical approach in these cases, perhaps, could be to adopt the open-quotes non-attainment zoneclose quotes policy. The essence of this policy is to first contain the plume and stop any further migration of contaminated groundwater, and then to remove the source of contamination. This paper briefly discusses some of the problems encountered with this approach for a contaminated area at the US Department of Energy's Lawrence Berkely National Laboratory

  2. Using phytotechnologies to remediate brownfields, landfills, and other urban areas

    Science.gov (United States)

    R.S. Zalesny Jr.; Jill Zalesny

    2010-01-01

    Urban areas requiring remedial work has prompted the use of phytotechnologies to improve water quality, soil health, and biodiversity, as well as to achieve sustainable social and economic goals. Phytotechnologies directly use plants to clean up contaminated groundwater, soil, and sediment.

  3. Characterization of Uranium Contamination, Transport, and Remediation at Rocky Flats - Across Remediation into Post-Closure

    Science.gov (United States)

    Janecky, D. R.; Boylan, J.; Murrell, M. T.

    2009-12-01

    The Rocky Flats Site is a former nuclear weapons production facility approximately 16 miles northwest of Denver, Colorado. Built in 1952 and operated by the Atomic Energy Commission and then Department of Energy, the Site was remediated and closed in 2005, and is currently undergoing long-term surveillance and monitoring by the DOE Office of Legacy Management. Areas of contamination resulted from roughly fifty years of operation. Of greatest interest, surface soils were contaminated with plutonium, americium, and uranium; groundwater was contaminated with chlorinated solvents, uranium, and nitrates; and surface waters, as recipients of runoff and shallow groundwater discharge, have been contaminated by transport from both regimes. A region of economic mineralization that has been referred to as the Colorado Mineral Belt is nearby, and the Schwartzwalder uranium mine is approximately five miles upgradient of the Site. Background uranium concentrations are therefore elevated in many areas. Weapons-related activities included work with enriched and depleted uranium, contributing anthropogenic content to the environment. Using high-resolution isotopic analyses, Site-related contamination can be distinguished from natural uranium in water samples. This has been instrumental in defining remedy components, and long-term monitoring and surveillance strategies. Rocky Flats hydrology interlinks surface waters and shallow groundwater (which is very limited in volume and vertical and horizontal extent). Surface water transport pathways include several streams, constructed ponds, and facility surfaces. Shallow groundwater has no demonstrated connection to deep aquifers, and includes natural preferential pathways resulting primarily from porosity in the Rocky Flats alluvium, weathered bedrock, and discontinuous sandstones. In addition, building footings, drains, trenches, and remedial systems provide pathways for transport at the site. Removal of impermeable surfaces (buildings

  4. Remediating MGP brownfields

    International Nuclear Information System (INIS)

    Larsen, B.R.

    1997-01-01

    Before natural gas pipelines became widespread in this country, gas fuel was produced locally in more than 5,000 manufactured gas plants (MGPs). The toxic wastes from these processes often were disposed onsite and have since seeped into the surrounding soil and groundwater. Although the MGPs--commonly called gas plants, gas-works or town gas plants--have closed and most have been demolished, they have left a legacy of environmental contamination. At many MGP sites, underground storage tanks were constructed of wood or brick, with process piping and equipment which frequently leaked. Waste materials often were disposed onsite. Releases of coal tars, oils and condensates produced within the plants contributed to a wide range of contamination from polycyclic aromatic hydrocarbons, phenols, benzene and cyanide. Remediation of selected MGP sites has been sporadic. Unless the site has been identified as a Comprehensive Environmental Response, Compensation and Liability Information System (CERCLIS) Superfund site, the regulatory initiative to remediate often remains with the state in which the MGP is located. A number of factors are working to change that picture and to create a renewed interest in MGP site remediation. The recent Brownfield Initiative by the US Environmental Protection Agency (EPA) is such an example

  5. Annual status report on the Uranium Mill Tailings Remedial Action Program

    International Nuclear Information System (INIS)

    1992-12-01

    This fourteenth annual status report for the Uranium Mill Tailings Remedial Action (UMTRA) Project Office summarizes activities of the Uranium Mill Tailings Remedial Action Surface (UMTRA-Surface) and Uranium Mill Tailings Remedial Action Groundwater (UMTRA-Groundwater) Projects undertaken during fiscal year (FY) 1992 by the US Department of Energy (DOE) and other agencies. Project goals for FY 1993 are also presented. An annual report of this type was a statutory requirement through January 1, 1986, pursuant to the Uranium Mill Tailings Radiation Control Act (UMTRCA) of 1978, Public Law (PL) 95-604. The DOE will continue to submit annual reports to DOE-Headquarters, the states, tribes, and local representatives through Project completion in order to inform the public of the yearly Project status. The purpose of the remedial action is to stabilize and control the tailings and other residual radioactive material (RRM) located on the inactive uranium processing sites in a safe and environmentally sound manner, and to minimize or eliminate potential health hazards. Commercial and residential properties near designated processing sites that are contaminated with material from the sites, herein referred to as ''vicinity properties (VP),'' are also eligible for remedial action. Included in the UMTRA Project are 24 inactive uranium processing sites and associated VPs located in 10 states, and the VPs associated with the Edgemont, South Dakota, uranium mill currently owned by the Tennessee Valley Authority (TVA) (Figure A.1, Appendix A)

  6. Advances in vacuum extraction technology for effective subsurface remediation

    International Nuclear Information System (INIS)

    Dodson, M.E.; Pezzullo, J.A.; Piniewski, R.J.

    1994-01-01

    Vacuum extraction technology has become one of the most widely acclaimed methods for remediating soils contaminated by petroleum hydrocarbons and volatile organic compounds. Removal of the source of contamination in the soil is often the first step in effective control of groundwater contamination. Though originally thought effective only for removal of light-end hydrocarbons from permeable vadose-zone soils, vacuum extraction can now be adapted to address situations of low-permeable soils, heavier-end hydrocarbons and groundwater contamination. This paper reviews four innovative modifications to the vacuum extraction process and how they solve a wide variety of subsurface contamination problems. The modifications, or processes, reviewed include: vacuum-extraction-enhanced bioremediation, groundwater sparging, pneumatic soil fracturing, and soil heating

  7. Conservative strategy-based ensemble surrogate model for optimal groundwater remediation design at DNAPLs-contaminated sites

    Science.gov (United States)

    Ouyang, Qi; Lu, Wenxi; Lin, Jin; Deng, Wenbing; Cheng, Weiguo

    2017-08-01

    The surrogate-based simulation-optimization techniques are frequently used for optimal groundwater remediation design. When this technique is used, surrogate errors caused by surrogate-modeling uncertainty may lead to generation of infeasible designs. In this paper, a conservative strategy that pushes the optimal design into the feasible region was used to address surrogate-modeling uncertainty. In addition, chance-constrained programming (CCP) was adopted to compare with the conservative strategy in addressing this uncertainty. Three methods, multi-gene genetic programming (MGGP), Kriging (KRG) and support vector regression (SVR), were used to construct surrogate models for a time-consuming multi-phase flow model. To improve the performance of the surrogate model, ensemble surrogates were constructed based on combinations of different stand-alone surrogate models. The results show that: (1) the surrogate-modeling uncertainty was successfully addressed by the conservative strategy, which means that this method is promising for addressing surrogate-modeling uncertainty. (2) The ensemble surrogate model that combines MGGP with KRG showed the most favorable performance, which indicates that this ensemble surrogate can utilize both stand-alone surrogate models to improve the performance of the surrogate model.

  8. Isotope hydrology: Investigating groundwater contamination

    International Nuclear Information System (INIS)

    Dubinchuk, V.; Froehlich, K.; Gonfiantini, R.

    1989-01-01

    Groundwater quality has worsened in many regions, with sometimes serious consequences. Decontaminating groundwater is an extremely slow process, and sometimes impossible, because of the generally long residence time of the water in most geological formations. Major causes of contamination are poor groundwater management (often dictated by immediate social needs) and the lack of regulations and control over the use and disposal of contaminants. These types of problems have prompted an increasing demand for investigations directed at gaining insight into the behaviour of contaminants in the hydrological cycle. Major objectives are to prevent pollution and degradation of groundwater resources, or, if contamination already has occurred, to identify its origin so that remedies can be proposed. Environmental isotopes have proved to be a powerful tool for groundwater pollution studies. The IAEA has had a co-ordinated research programme since 1987 on the application of nuclear techniques to determine the transport of contaminants in groundwater. An isotope hydrology project is being launched within the framework of the IAEA's regional co-operative programme in Latin America (known as ARCAL). Main objectives are the application of environmental isotopes to problems of groundwater assessment and contamination in Latin America. In 1989, another co-ordinated research programme is planned under which isotopic and other tracers will be used for the validation of mathematical models in groundwater transport studies

  9. Environmental remediation of an Alstom grid industrial site (France) - 59270

    International Nuclear Information System (INIS)

    Romero, Stephanie

    2012-01-01

    ALSTOM Grid is the project owner of the remediation of a former industrial site, located in Saint-Ouen, north of Paris. The industrial activity (power transformer production) started in 1921 and stopped in 2006. The type of pollution is linked with the former activity. It's an organic pollution: hydrocarbon, PCB and chlorinated volatile organic compounds. The clean-up concerns soil and groundwater. The main specificity of the project is that the remediation is operated inside the existing industrial buildings which must be kept in place and restituted to the owner after the works. The treatment of soil requires excavating soil up to 9 m deep (1 m under the level of the groundwater) inside the buildings. As a consequence, some impressive devices were set up to ensure the stability of the buildings during the clean-up, like support structures of the foundations and strengthening of the building fronts. In the same time, it has to be pointed out that great diversity of clean-up actions is performed on the site: the soil is excavated to be treated on site (bioremediation or chemical treatment) or off site. The treatment of groundwater consists of pumping the oil staying on the surface and oxidizing the dissolved pollution. This project is probably the first experience of this scale in France with multi-contaminated soil and groundwater decontamination in keeping and reinforcing the existing buildings. (authors)

  10. Recommendations for computer modeling codes to support the UMTRA groundwater restoration project

    Energy Technology Data Exchange (ETDEWEB)

    Tucker, M.D. [Sandia National Labs., Albuquerque, NM (United States); Khan, M.A. [IT Corp., Albuquerque, NM (United States)

    1996-04-01

    The Uranium Mill Tailings Remediation Action (UMTRA) Project is responsible for the assessment and remedial action at the 24 former uranium mill tailings sites located in the US. The surface restoration phase, which includes containment and stabilization of the abandoned uranium mill tailings piles, has a specific termination date and is nearing completion. Therefore, attention has now turned to the groundwater restoration phase, which began in 1991. Regulated constituents in groundwater whose concentrations or activities exceed maximum contaminant levels (MCLs) or background levels at one or more sites include, but are not limited to, uranium, selenium, arsenic, molybdenum, nitrate, gross alpha, radium-226 and radium-228. The purpose of this report is to recommend computer codes that can be used to assist the UMTRA groundwater restoration effort. The report includes a survey of applicable codes in each of the following areas: (1) groundwater flow and contaminant transport modeling codes, (2) hydrogeochemical modeling codes, (3) pump and treat optimization codes, and (4) decision support tools. Following the survey of the applicable codes, specific codes that can best meet the needs of the UMTRA groundwater restoration program in each of the four areas are recommended.

  11. Recommendations for computer modeling codes to support the UMTRA groundwater restoration project

    International Nuclear Information System (INIS)

    Tucker, M.D.; Khan, M.A.

    1996-04-01

    The Uranium Mill Tailings Remediation Action (UMTRA) Project is responsible for the assessment and remedial action at the 24 former uranium mill tailings sites located in the US. The surface restoration phase, which includes containment and stabilization of the abandoned uranium mill tailings piles, has a specific termination date and is nearing completion. Therefore, attention has now turned to the groundwater restoration phase, which began in 1991. Regulated constituents in groundwater whose concentrations or activities exceed maximum contaminant levels (MCLs) or background levels at one or more sites include, but are not limited to, uranium, selenium, arsenic, molybdenum, nitrate, gross alpha, radium-226 and radium-228. The purpose of this report is to recommend computer codes that can be used to assist the UMTRA groundwater restoration effort. The report includes a survey of applicable codes in each of the following areas: (1) groundwater flow and contaminant transport modeling codes, (2) hydrogeochemical modeling codes, (3) pump and treat optimization codes, and (4) decision support tools. Following the survey of the applicable codes, specific codes that can best meet the needs of the UMTRA groundwater restoration program in each of the four areas are recommended

  12. Superfund record of decision (EPA Region 6): Oklahoma Refining Company, Cyril, OK. (First remedial action), June 1992. Final report

    International Nuclear Information System (INIS)

    1992-01-01

    The 160-acre Oklahoma Refining site is a petroleum refinery located on the eastern edge of Cyril, Oklahoma, in Caddo County. The facility included refinery process areas, bulk storage tanks, waste pits, wastewater treatment ponds, and a land treatment area. During the mid-1980's, EPA investigations revealed large-scale organic and heavy metal contamination of onsite soil and ground water. In 1990, EPA conducted a removal action, which included characterization and removal of drums, plugging wells, and wildlife protection measures. The ROD addresses the remediation of onsite contaminated soil, sediment, surface water, and ground water as a final remedy. The primary contaminants of concern affecting the soil, sediment, ground water, and surface water are VOCs, including benzene, toluene, and xylenes; other organics, including PAHs and phenols; and metals, including arsenic, chromium, and lead. The selected remedial action for the site is included

  13. Remedial action and waste disposal project -- 300-FF-1 remedial action readiness assessment plan

    International Nuclear Information System (INIS)

    April, J.G.; Carlson, R.A.; Greif, A.A.; Johnson, C.R.; Orewiler, R.I.; Perry, D.M.; Plastino, J.C.; Roeck, F.V.; Tuttle, B.G.

    1997-04-01

    This Readiness Assessment Plan presents the methodology used to assess the readiness of the 300-FF-1 Remedial Action Project. Remediation involves the excavation, treatment if applicable, and final disposal of contaminated soil and debris associated with the waste sites in the 300-FF-1 Operable Unit. The scope of the 300-FF-1 remediation is to excavate, transport, and dispose of contaminated solid from sites identified in the 300-FF-1 Operable Unit

  14. Analysis of Aquifer Response, Groundwater Flow, and PlumeEvolution at Site OU 1, Former Fort Ord, California

    Energy Technology Data Exchange (ETDEWEB)

    Jordan, Preston D.; Oldenburg, Curtis M.; Su, Grace W.

    2005-02-24

    This report presents a continuation from Oldenburg et al. (2002) of analysis of the hydrogeology, In-Situ Permeable Flow Sensor (ISPFS) results, aquifer response, and changes in the trichloroethylene (TCE) groundwater plume at Operational Unit 1 (OU 1) adjacent to the former Fritzsche Army Airfield at the former Fort Ord Army Base, located on Monterey Bay in northern Monterey County. Fuels and solvents were burned on a portion of OU 1 called the Fire Drill Area (FDA) during airport fire suppression training between 1962 and 1985. This activity resulted in soil and groundwater contamination in the unconfined A-aquifer. In the late 1980's, soil excavation and bioremediation were successful in remediating soil contamination at the site. Shortly thereafter, a groundwater pump, treat, and recharge system commenced operation. This system has been largely successful at remediating groundwater contamination at the head of the groundwater plume. However, a trichloroethylene (TCE) groundwater plume extends approximately 3000 ft (900 m) to the northwest away from the FDA. In the analyses presented here, we augment our prior work (Oldenburg et al., 2002) with new information including treatment-system totalizer data, recent water-level and chemistry data, and data collected from new wells to discern trends in contaminant migration and groundwater flow that may be useful for ongoing remediation efforts. Some conclusions from the prior study have been modified based on these new analyses, and these are pointed out clearly in this report.

  15. Baseline risk assessment of groundwater contamination at the Uranium Mill Tailings Site near Gunnison, Colorado

    Energy Technology Data Exchange (ETDEWEB)

    1993-12-01

    This Baseline Risk Assessment of Groundwater Contamination at the Uranium Mill Tailings Site Near Gunnison, Colorado evaluates potential impacts to public health or the environment resulting from groundwater contamination at the former uranium mill processing site. The tailings and other contaminated material at this site are being placed in an off-site disposal cell by the US Department of Energy`s (DOE) Uranium Mill Tailings Remedial Action (UMTRA) Project. Currently, the UMTRA Project is evaluating groundwater contamination. This is the second risk assessment of groundwater contamination at this site. The first risk assessment was performed primarily to evaluate existing domestic wells. This risk assessment evaluates the most contaminated monitor wells at the processing site. It will be used to assist in determining what remedial action is needed for contaminated groundwater at the site after the tailings are relocated. This risk assessment follows an approach outlined by the US Environmental Protection Agency (EPA). The first step is to evaluate groundwater data collected from monitor wells at the site. Evaluation of these data showed that the main contaminants in the groundwater are cadmium, cobalt, iron, manganese, sulfate, uranium, and some of the products of radioactive decay of uranium.

  16. Baseline risk assessment of groundwater contamination at the Uranium Mill Tailings Site near Gunnison, Colorado

    International Nuclear Information System (INIS)

    1993-12-01

    This Baseline Risk Assessment of Groundwater Contamination at the Uranium Mill Tailings Site Near Gunnison, Colorado evaluates potential impacts to public health or the environment resulting from groundwater contamination at the former uranium mill processing site. The tailings and other contaminated material at this site are being placed in an off-site disposal cell by the US Department of Energy's (DOE) Uranium Mill Tailings Remedial Action (UMTRA) Project. Currently, the UMTRA Project is evaluating groundwater contamination. This is the second risk assessment of groundwater contamination at this site. The first risk assessment was performed primarily to evaluate existing domestic wells. This risk assessment evaluates the most contaminated monitor wells at the processing site. It will be used to assist in determining what remedial action is needed for contaminated groundwater at the site after the tailings are relocated. This risk assessment follows an approach outlined by the US Environmental Protection Agency (EPA). The first step is to evaluate groundwater data collected from monitor wells at the site. Evaluation of these data showed that the main contaminants in the groundwater are cadmium, cobalt, iron, manganese, sulfate, uranium, and some of the products of radioactive decay of uranium

  17. Feasibility of phytoremediation for common soil and groundwater pollutants

    DEFF Research Database (Denmark)

    Clausen, Lauge Peter Westergaard

    During the past two to three decades numerous studies reporting highly efficient remediation of contaminated soil and groundwater by plants have been published. The promises of phytoremediation has been great but till now the technology has not been widely applied and recognized, commercially...... and in a regulatory context, on par with other conventional soil and groundwater remediation technologies. This thesis elucidates the field of phytoremediation and addresses the lack of recognition of the technology. It aims to assesses the overall feasibility of phytoremediation and identify obstacles within...... the field. Further, it provides examples and suggestions of how to overcome these obstacles. The first part of the thesis scrutinizes the literature for data and experiences regarding application of phytoremediation and uncovers potential barriers and where the existing knowledge is insufficient. Further...

  18. An early warning system for groundwater pollution based on the assessment of groundwater pollution risks.

    Science.gov (United States)

    Zhang, Weihong.; Zhao, Yongsheng; Hong, Mei; Guo, Xiaodong

    2009-04-01

    Groundwater pollution usually is complex and concealed, remediation of which is difficult, high cost, time-consuming, and ineffective. An early warning system for groundwater pollution is needed that detects groundwater quality problems and gets the information necessary to make sound decisions before massive groundwater quality degradation occurs. Groundwater pollution early warning were performed by considering comprehensively the current groundwater quality, groundwater quality varying trend and groundwater pollution risk . The map of the basic quality of the groundwater was obtained by fuzzy comprehensive evaluation or BP neural network evaluation. Based on multi-annual groundwater monitoring datasets, Water quality state in sometime of the future was forecasted using time-sequenced analyzing methods. Water quality varying trend was analyzed by Spearman's rank correlative coefficient.The relative risk map of groundwater pollution was estimated through a procedure that identifies, cell by cell,the values of three factors, that is inherent vulnerability, load risk of pollution source and contamination hazard. DRASTIC method was used to assess inherent vulnerability of aquifer. Load risk of pollution source was analyzed based on the potential of contamination and pollution degree. Assessment index of load risk of pollution source which involves the variety of pollution source, quantity of contaminants, releasing potential of pollutants, and distance were determined. The load risks of all sources considered by GIS overlay technology. Early warning model of groundwater pollution combined with ComGIS technology organically, the regional groundwater pollution early-warning information system was developed, and applied it into Qiqiha'er groundwater early warning. It can be used to evaluate current water quality, to forecast water quality changing trend, and to analyze space-time influencing range of groundwater quality by natural process and human activities. Keywords

  19. Source zone remediation by ZVI-clay soil-mixing: Reduction of tetrachloroethene mass and mass discharge at a Danish DNAPL site

    DEFF Research Database (Denmark)

    Fjordbøge, Annika Sidelmann; Lange, Ida Vedel; Binning, Philip John

    2012-01-01

    The presence of chlorinated solvent source zones in the subsurface pose a continuous threat to groundwater quality. The remediation of Dense Non-Aqueous Phase Liquid (DNAPL) sites is especially challenging and the development of innovative remediation technologies is needed. Zero-valent iron (ZVI......) technologies have proven effective for remediation of chlorinated compounds. ZVI-Clay soil-mixing is a new remediation technology, which combines abiotic degradation (via ZVI addition) and immobilization (via soil-mixing and clay addition), whereby a great potential for reduction of both contaminant mass....... The concentrations of chlorinated ethenes were monitored via soil sampling at the source zone and groundwater sampling at a control plane with multilevel samplers covering the entire contaminated plume down-gradient (3 m) of the source zone. The results showed a significant mass depletion of PCE (2-3 orders...

  20. TIE for cyanides in groundwater at a former coal gasification plant

    Energy Technology Data Exchange (ETDEWEB)

    McLeay, M.; Cameron, M. [Hemmeram, Vancouver, BC (Canada); Elphick, J. [Nautilus Environmental Co., Burnaby, BC (Canada)

    2010-07-01

    Groundwater remediation efforts are underway at a former coal gasification plant site in British Columbia because the concentrations of cyanide and other substances were found to exceed aquatic life guidelines. Hemmera and Nautilus Environmental examined whether that groundwater was toxic to a variety of sensitive marine aquatic life species, and whether cyanide was the primary toxicant. Untreated groundwater containing cyanide, weak acid dissociable cyanide and free cyanide was tested for toxicity on bivalve larval survival, kelp zoospore germination, sea urchin gamete fertilization, and larval topsmelt survival and growth. The untreated groundwater was found to be toxic to kelp zoospores and sea urchin gametes, but relatively non-toxic to bivalve larvae and topsmelt. The following 4 toxicity identification evaluation (TIE) treatments were conducted on site groundwater: (1) acidification/aeration of the sample, (2) filtration of the sample through anion exchange media, (3) filtration of the sample through activated carbon, and (4) exposure of the sample to UV light. Both the cyanide concentration and the toxicity to kelp decreased considerably when the anion exchange treatment was applied. The results suggest that the toxicity may be attributed to cyanides in the groundwater. The information obtained from this study will be used to plan excavation water treatment strategies during site remediation as part of an ecological risk assessment for the site.

  1. TIE for cyanides in groundwater at a former coal gasification plant

    International Nuclear Information System (INIS)

    McLeay, M.; Cameron, M.; Elphick, J.

    2010-01-01

    Groundwater remediation efforts are underway at a former coal gasification plant site in British Columbia because the concentrations of cyanide and other substances were found to exceed aquatic life guidelines. Hemmera and Nautilus Environmental examined whether that groundwater was toxic to a variety of sensitive marine aquatic life species, and whether cyanide was the primary toxicant. Untreated groundwater containing cyanide, weak acid dissociable cyanide and free cyanide was tested for toxicity on bivalve larval survival, kelp zoospore germination, sea urchin gamete fertilization, and larval topsmelt survival and growth. The untreated groundwater was found to be toxic to kelp zoospores and sea urchin gametes, but relatively non-toxic to bivalve larvae and topsmelt. The following 4 toxicity identification evaluation (TIE) treatments were conducted on site groundwater: (1) acidification/aeration of the sample, (2) filtration of the sample through anion exchange media, (3) filtration of the sample through activated carbon, and (4) exposure of the sample to UV light. Both the cyanide concentration and the toxicity to kelp decreased considerably when the anion exchange treatment was applied. The results suggest that the toxicity may be attributed to cyanides in the groundwater. The information obtained from this study will be used to plan excavation water treatment strategies during site remediation as part of an ecological risk assessment for the site.

  2. Final Hazard Categorization for the Remediation of Six 300-FF-2 Operable Unit Solid Waste Burial Grounds

    International Nuclear Information System (INIS)

    Ludowise, J.D.

    2006-01-01

    This report provides the final hazard categorization (FHC) for the remediation of six solid waste disposal sites (referred to as burial grounds) located in the 300-FF-2 Operable Unit (OU) on the Hanford Site. These six sites (618-1, 618-2, 618-3, 618-7, 618-8, and 618-13 Burial Grounds) were determined to have a total radionuclide inventory (WCH 2005a, WCH 2005d, WCH 2005e and WCH 2006b) that exceeds the DOE-STD-1027 Category 3 threshold quantity (DOE 1997) and are the subject of this analysis. This FHC document examines the hazards, identifies appropriate controls to manage the hazards, and documents the FHC and commitments for the 300-FF-2 Burial Grounds Remediation Project

  3. Final Hazard Categorization for the Remediation of Six 300-FF-2 Operable Unit Solid Waste Burial Grounds

    Energy Technology Data Exchange (ETDEWEB)

    J. D. Ludowise

    2006-12-12

    This report provides the final hazard categorization (FHC) for the remediation of six solid waste disposal sites (referred to as burial grounds) located in the 300-FF-2 Operable Unit (OU) on the Hanford Site. These six sites (618-1, 618-2, 618-3, 618-7, 618-8, and 618-13 Burial Grounds) were determined to have a total radionuclide inventory (WCH 2005a, WCH 2005d, WCH 2005e and WCH 2006b) that exceeds the DOE-STD-1027 Category 3 threshold quantity (DOE 1997) and are the subject of this analysis. This FHC document examines the hazards, identifies appropriate controls to manage the hazards, and documents the FHC and commitments for the 300-FF-2 Burial Grounds Remediation Project.

  4. Risk-based economic decision analysis of remediation options at a PCE-contaminated site

    DEFF Research Database (Denmark)

    Lemming, Gitte; Friis-Hansen, P.; Bjerg, Poul Løgstrup

    2010-01-01

    by the remediation activities. More attention is increasingly being given to these secondary environmental impacts when evaluating remediation options. This paper presents a methodology for an integrated economic decision analysis which combines assessments of remediation costs, health risk costs and potential...... at a downstream groundwater well. Potential environmental impacts on the local, regional and global scales due to the site remediation activities are evaluated using life cycle assessments (LCA). The potential impacts on health and environment are converted to monetary units using a simplified cost model. A case......Remediation methods for contaminated sites cover a wide range of technical solutions with different remedial efficiencies and costs. Additionally, they may vary in their secondary impacts on the environment i.e. the potential impacts generated due to emissions and resource use caused...

  5. Cost benefit analysis of remediation alternatives for controlling the flux of strontium-90 into the Columbia River

    International Nuclear Information System (INIS)

    Gustafson, F.W.; Todd, M.E.

    1993-09-01

    The release of large volumes of water to waste disposal cribs at the Hanford Site's 100-N Area caused contaminants, principally strontium-90, to be carried toward the Columbia River through the groundwater. Since shutdown of the N Reactor, these releases have been discontinued, although small water flows continue to be discharged to the 1325-N crib. Most of the contamination which is now transported to the river is occurring as a result of the natural groundwater movement. The contaminated groundwater at N Springs flows into the river through seeps and springs along the river's edge. An expedited response action (ERA) has been proposed to eliminate or restrict the flux of strontium-90 into the river. A cost benefit analysis of potential remedial alternatives was completed that recommends the alternative which best meets given selection criteria prescribed by the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA). The methodology used for evaluation, cost analysis, and alternative recommendation is the engineering evaluation/cost analysis (EE/CA). Complete remediation of the contaminated groundwater beneath 100-N Area was not a principal objective of the analysis. The objective of the cost benefit analysis was to identify a remedial alternative that optimizes the degree of benefit produced for the costs incurred

  6. Strategic planning for remediation projects

    International Nuclear Information System (INIS)

    Tapp, J.W.

    1995-01-01

    Remediation projects may range from a single leaking storage tank to an entire plant complex or producing oil and gas field. Strategic planning comes into play when the contamination of soil and groundwater is extensive. If adjacent landowners have been impacted or the community at large is concerned about the quality of drinking water, then strategic planning is even more important. (1) To manage highly complex interrelated issues--for example, the efforts expended on community relations can alter public opinion, which can impact regulatory agency decisions that affect cleanup standards, which can...and so on. (2) To ensure that all potential liabilities are managed--for example, preparation for the defense of future lawsuits is essential during site investigation and remediation. (3) To communicate with senior management--when the remediation team provides a strategic plan that includes both technical and business issues, senior management has the opportunity to become more involved and make sound policy decisions. The following discusses the elements of a strategic plan, who should participate in it, and the issues that should be considered

  7. Microbial Remediation of Metals in Soils

    Science.gov (United States)

    Hietala, K. A.; Roane, T. M.

    Of metal-contaminated systems, metal-contaminated soils present the greatest challenge to remediation efforts because of the structural, physical, chemical, and biological heterogeneities encountered in soils. One of the confounding issues surrounding metal remediation is that metals can be readily re-mobilized, requiring constant monitoring of metal toxicity in sites where metals are not removed. Excessive metal content in soils can impact air, surface water, and groundwater quality. However, our understanding of how metals affect organisms, from bacteria to plants and animals, and our ability to negate the toxicity of metals are in their infancies. The ubiquity of metal contamination in developing and industrialized areas of the world make remediation of soils via removal, containment, and/or detoxification of metals a primary concern. Recent examples of the health and environmental consequences of metal contamination include arsenic in drinking water (Wang and Wai 2004), mercury levels in fish (Jewett and Duffy 2007), and metal uptake by agricultural crops (Howe et al. 2005). The goal of this chapter is to summarize the traditional approaches and recent developments using microorganisms and microbial products to address metal toxicity and remediation.

  8. F/H seepage basin groundwater influent, effluent, precipitated sludge characterization task technical plan

    International Nuclear Information System (INIS)

    Siler, J.L.

    1993-01-01

    A treatability study to support the development of a remediation system which would reduce the contaminant levels in groundwater removed from the aquifers in the vicinity of the F/H seepage basins and southwest of the Mixed Waste Management Facility (MWMF) at the Savannah River facility was conducted. Proposed changes in the remediation system require an additional study to determine whether precipitated sludge generated from the proposed remediation system will be hazardous as defined by RCRA. Several contaminants, such as lead and mercury, are above the groundwater protection standards. The presence of radionuclides and other contaminants in the sludge does not present a problem provided that the sludge can pass the Toxicity Characteristic Leaching Procedure (TCLP) test. The study has been developed in such a manner as to cover the possible range of treatment options that may be used

  9. Development and implementation of a comprehensive groundwater protection program at the Savannah River Plant

    International Nuclear Information System (INIS)

    Gordon, D.E.

    1984-01-01

    The major goals of the groundwater protection program are to evaluate the impact on groundwater quality as a result of Savannah River Plant operations, to take corrective measures as required to restore or protect groundwater quality, and to ensure that future operations do not adversely affect the quality or availability of the groundwater resources at the site. The specific elements of this program include (1) continuation of an extensive groundwater monitoring program, (2) assessment of waste disposal sites for impacts on groundwater quality, (3) implementation of mitigative actions, as required, to restore or protect groundwater quality, (4) incorporation of groundwater protection concepts in the design of new production and waste management facilities, and (5) review of site utilization of groundwater resources to ensure compatibility with regional needs. The major focal points of the groundwater protection program are the assessment of waste disposal sites for impacts on groundwater quality and the implementation of remedial action projects. Many locations at SRP have been used as waste disposal sites for a variety of liquid and solid wastes. Field investigations are ongoing to determine the nature and extent of any contamination in the sediments and groundwater at these waste sites on a priority basis. Remedial action has been initiated. Certain aspects of the groundwater protection program have been identified as key to the success in achieving the desired objectives. Key elements of the program have included early identification of all the potential sources for groundwater contamination, development of an overall strategy for waste site assessment and mitigation, use of a flexible computerized system for data base management, and establishing good relationships with regulatory agencies. 10 references, 6 figures, 4 tables

  10. Compendium of ordinances for groundwater protection

    Energy Technology Data Exchange (ETDEWEB)

    1990-08-01

    Groundwater is an extremely important resource in the Tennessee Valley. Nearly two-thirds of the Tennessee Valley's residents rely, at least in part, on groundwater supplies for drinking water. In rural areas, approximately ninety-five percent of residents rely on groundwater for domestic supplies. Population growth and economic development increase the volume and kinds of wastes requiring disposal which can lead to groundwater contamination. In addition to disposal which can lead to groundwater contamination. In addition to disposal problems associated with increases in conventional wastewater and solid waste, technological advancements in recent decades have resulted in new chemicals and increased usage in agriculture, industry, and the home. Unfortunately, there has not been comparable progress in identifying the potential long-term effects of these chemicals, in managing them to prevent contamination of groundwater, or in developing treatment technologies for removing them from water once contamination has occurred. The challenge facing residence of the Tennessee Valley is to manage growth and economic and technological development in ways that will avoid polluting the groundwater resource. Once groundwater has been contaminated, cleanup is almost always very costly and is sometimes impractical or technically infeasible. Therefore, prevention of contamination -- not remedial treatment--is the key to continued availability of usable groundwater. This document discusses regulations to aid in this prevention.

  11. Tackling the Challenge of Deep Vadose Zone Remediation at the Hanford Site

    Science.gov (United States)

    Morse, J. G.; Wellman, D. M.; Gephart, R.

    2010-12-01

    The Central Plateau of the Hanford Site in Washington State contains some 800 waste disposal sites where 1.7 trillion liters of contaminated water was once discharged into the subsurface. Most of these sites received liquids from the chemical reprocessing of spent uranium fuel to recover plutonium. In addition, 67 single shell tanks have leaked or are suspected to have leaked 3.8 million liters of high alkali and aluminate rich cesium-contaminated liquids into the sediment. Today, this inventory of subsurface contamination contains an estimated 550,000 curies of radioactivity and 150 million kg (165,000 tons) of metals and hazardous chemicals. Radionuclides range from mobile 99Tc to more immobilized 137Cs, 241Am, uranium, and plutonium. A significant fraction of these contaminants likely remain within the deep vadose zone. Plumes of groundwater containing tritium, nitrate, 129I and other contaminants have migrated through the vadose zone and now extend outward from the Central Plateau to the Columbia River. During most of Hanford Site history, subsurface studies focused on groundwater monitoring and characterization to support waste management decisions. Deep vadose zone studies were not a priority because waste practices relied upon that zone to buffer contaminant releases into the underlying aquifer. Remediation of the deep vadose zone is now central to Hanford Site cleanup because these sediments can provide an ongoing source of contamination to the aquifer and therefore to the Columbia River. However, characterization and remediation of the deep vadose zone pose some unique challenges. These include sediment thickness; contaminant depth; coupled geohydrologic, geochemical, and microbial processes controlling contaminant spread; limited availability and effectiveness of traditional characterization tools and cleanup remedies; and predicting contaminant behavior and remediation performance over long time periods and across molecular to field scales. The U

  12. Ground-Water Protection and Monitoring Program

    Energy Technology Data Exchange (ETDEWEB)

    Dresel, P.E.

    1995-06-01

    This section of the 1994 Hanford Site Environmental Report summarizes the ground-water protection and monitoring program strategy for the Hanford Site in 1994. Two of the key elements of this strategy are to (1) protect the unconfined aquifer from further contamination, and (2) conduct a monitoring program to provide early warning when contamination of ground water does occur. The monitoring program at Hanford is designed to document the distribution and movement of existing ground-water contamination and provides a historical baseline for evaluating current and future risk from exposure to the contamination and for deciding on remedial action options.

  13. Ground-Water Protection and Monitoring Program

    International Nuclear Information System (INIS)

    Dresel, P.E.

    1995-01-01

    This section of the 1994 Hanford Site Environmental Report summarizes the ground-water protection and monitoring program strategy for the Hanford Site in 1994. Two of the key elements of this strategy are to (1) protect the unconfined aquifer from further contamination, and (2) conduct a monitoring program to provide early warning when contamination of ground water does occur. The monitoring program at Hanford is designed to document the distribution and movement of existing ground-water contamination and provides a historical baseline for evaluating current and future risk from exposure to the contamination and for deciding on remedial action options

  14. Enzymatic reduction of U(VI) in groundwaters

    International Nuclear Information System (INIS)

    Addelouas, A.; Gong, W.; Lutze, W.; Nuttall, E.; Fritz, B.; Crovisier, J.L.

    1999-01-01

    The use of enzymatic reduction of U(VI) in remediation of groundwater contaminated with U(VI) is receiving considerable attention. Certain strains of bacteria can combine the oxidation of an organic compound to the reduction of U(VI) to U(IV), which precipitates as uraninite. In the present study, we tested the reduction of U(VI) in groundwaters with various origins and compositions. In all groundwaters u(VI) was reduced by sulfate reducing bacteria that had been activated by ethanol and tri-metaphosphate. The reduction rate of U(VI) depends on sulfate concentration in water and the abundance of bacteria in the system. This work shows that bacteria capable of U(VI) reduction are ubiquitous in nature, and suggests the possibility of a large application of the enzymatic reduction of U(VI) for in situ clean up of groundwaters contaminated with uranium. (authors)

  15. Multi-phase flow modeling of soil contamination and soil remediation

    NARCIS (Netherlands)

    Dijke, van M.I.J.

    1997-01-01


    In this thesis multi-phase flow models are used to study the flow behavior of liquid contaminants in aquifers and of gases that are injected below the groundwater table for remediation purposes. Considered problems are redistribution of a lens of light nonaqueous phase

  16. Overview of Chromium Remediation Technology Evaluations At The Hanford Site, Richland Washington

    Science.gov (United States)

    Morse, J. G.; Hanson, J. P.

    2009-12-01

    This paper will present an overview of the different technologies and the results to date for optimizing and improving the remediation of Cr+6 in the soil and groundwater at the Hanford Site. The Hanford Site, par of the U.S. Department of Energy's (DOE)nuclear weapons complex, encompasses approximately 586 square miles in southeast Washington State. The Columbia River flows through the site (Hanford Reach.) Reactors were located along the Hanford Reach as part of the production process. Sodium dichromate was used as a corrosion inhibitor in the cooling water for the reactors. As a result chromium (Cr+6) is present in the soil and groundwater. Since the mid 90's interim groundwater pump and treat systems have been in place to try and contain or mitigate the migration of contaminated groundwater into the Columbia River. The primary concern being the protection of aquatic spawning habitat for salmon and other species. In order to improve the effectiveness of the remedial actions a number of different technologies have been evaluated and/or deployed. These include, permeable reactive barriers, in-situ bio-stimulation, in-situ chemical reduction, zero-valent iron injection and evaluation of improved above ground treatment technologies. An overview of the technologies and results to date are presented.

  17. Environmental assessment of remedial action at the Naturita Uranium Processing Site near Naturita, Colorado. Revision 4

    Energy Technology Data Exchange (ETDEWEB)

    1994-05-01

    The Uranium Mill Tailings Radiation Control Act (UMTRCA) of 1978, Public Law (PL) 95-604, authorized the US Department of Energy (DOE) to perform remedial action at the Naturita, Colorado, uranium processing site to reduce the potential health effects from the radioactive materials at the site and at vicinity properties associated with the site. The US Environmental Protection Agency (EPA) promulgated standards for the UMTRCA that contain measures to control the contaminated materials and to protect groundwater quality. Remedial action at the Naturita site must be performed in accordance with these standards and with the concurrence of the US Nuclear Regulatory Commission (NRC) and the state of Colorado. The proposed remedial action for the Naturita processing site is relocation of the contaminated materials and debris to either the Dry Flats disposal site, 6 road miles (mi) [10 kilometers (km)] to the southeast, or a licensed non-DOE disposal facility capable of handling RRM. At either disposal site, the contaminated materials would be stabilized and covered with layers of earth and rock. The proposed Dry Flats disposal site is on land administered by the Bureau of Land Management (BLM) and used primarily for livestock grazing. The final disposal site would cover approximately 57 ac (23 ha), which would be permanently transferred from the BLM to the DOE and restricted from future uses. The remedial action would be conducted by the DOE`s Uranium Mill Tailings Remedial Action (UMTRA) Project. This report discusses environmental impacts associated with the proposed remedial action.

  18. Microbial Assisted Phyto remediation Of Palm Oil Mill Final Discharge (POMFD) Wastewater

    International Nuclear Information System (INIS)

    Mohd Faizal Hamzah; Norjan Yusof; Hasimah Alimon

    2016-01-01

    This study assesses microbial assisted phyto remediation of palm oil mill final discharge (POMFD) wastewater using three local macrophyte species: Leersia oryzoides, Pistia stratiotes and Ludwigia peploides. It was found respectively that BOD 5 , COD, NH 3 -N removal efficiencies of 84.7 %, 22.3 %, and 73.5 % were achieved for P. stratiotes; 88.1 %, 18 % and 69.2 % for L. peploides; and 86.1 %, 11.7 % and 69.3 % for L. oryzoides. The level of C, H and N in the tissue were influenced by macrophyte species and organs (p < 0.05). The bioconcentration factors (BCF) of various metals such as Mg, Ca, K, Na, Fe and Zn of the three macrophyte were 10 -1 to 10 0 with Fe being highly accumulated in roots of all the macrophyte (BCF=10 2 ). The translocation factors (TF) of most metals from root to shoot tissues were in a range of 10 -3 to 10 0 . In comparison with other metals, K was capable to be efficiently translocated from root to shoots in all the macrophyte species (TF=10 0 ). In this study, Bacillus megaterium, Pseudomonas spp. and Bacillus cereus that are usually involved in denitrification were identified in P. stratiotes, L. pepoides and L. oryzoides roots respectively. This confirms the macrophyte-microorganism interaction in remediation of POMFD wastewater. (author)

  19. Remediation of Chlorinated Solvent Plumes Using In-Situ Air Sparging—A 2-D Laboratory Study

    Directory of Open Access Journals (Sweden)

    Jeffrey A. Adams

    2011-06-01

    Full Text Available In-situ air sparging has evolved as an innovative technique for soil and groundwater remediation impacted with volatile organic compounds (VOCs, including chlorinated solvents. These may exist as non-aqueous phase liquid (NAPL or dissolved in groundwater. This study assessed: (1 how air injection rate affects the mass removal of dissolved phase contamination, (2 the effect of induced groundwater flow on mass removal and air distribution during air injection, and (3 the effect of initial contaminant concentration on mass removal. Dissolved-phase chlorinated solvents can be effectively removed through the use of air sparging; however, rapid initial rates of contaminant removal are followed by a protracted period of lower removal rates, or a tailing effect. As the air flow rate increases, the rate of contaminant removal also increases, especially during the initial stages of air injection. Increased air injection rates will increase the density of air channel formation, resulting in a larger interfacial mass transfer area through which the dissolved contaminant can partition into the vapor phase. In cases of groundwater flow, increased rates of air injection lessened observed downward contaminant migration effect. The air channel network and increased air saturation reduced relative hydraulic conductivity, resulting in reduced groundwater flow and subsequent downgradient contaminant migration. Finally, when a higher initial TCE concentration was present, a slightly higher mass removal rate was observed due to higher volatilization-induced concentration gradients and subsequent diffusive flux. Once concentrations are reduced, a similar tailing effect occurs.

  20. Water use and groundwater contamination

    International Nuclear Information System (INIS)

    Elton, J.J.; Livingstone, B.

    1998-01-01

    A general review of the groundwater resources in Saskatchewan and their vulnerability to contamination was provided. In particular, the use of water and the effects on water by the oil and gas industry in Saskatchewan were discussed. It was suggested that public concerns over scarcity and contamination of water are gradually changing perceptions about Canada's abundance of water. Saskatchewan's surface water covers 12 per cent of the province. About 90 per cent of the rural populations and 80 per cent of municipalities depend on groundwater supplies. Regulations affecting oil and gas operations that could affect water resources have become more stringent. Techniques used in the detection and monitoring of groundwater affected by salt and petroleum hydrocarbons were described. Electromagnetic surveys are used in detecting salt-affected soils and groundwater. Laboratory analysis of chloride concentrations are needed to define actual chloride concentrations in groundwater. Wells and barriers can be installed to control and recover chloride plumes. Deep well injection and reverse osmosis are other methods, but there is no cheap or simple treatment or disposal method for salt-impacted groundwater. Spills or leaks of petroleum hydrocarbons from various sources can also lead to contamination of groundwater. Various assessment and remediation methods are described. Although there is no scarcity of techniques, all of them are difficult, costly, and may take several years to complete. 11 refs., 1 tab

  1. Characterization plan for the Oak Ridge National Laboratory Area-Wide Groundwater Program, Oak Ridge, Tennessee

    Energy Technology Data Exchange (ETDEWEB)

    1994-08-01

    This characterization plan has been developed as part of the U.S. Department of Energy`s (DOE`s) investigation of the Groundwater Operable Unit (GWOU) at Oak Ridge National Laboratory (ORNL) located near Oak Ridge, Tennessee. The first iteration of the characterization plan is intended to serve as a strategy document to guide subsequent GWOU remedial investigations. The plan provides a rationale and organization for groundwater data acquisition, monitoring, and remedial actions to be performed during implementation of environmental restoration activities associated with the ORNL GWOU. It is important to note that the characterization plan for the ORNL GWOU is not a prototypical work plan. As such, remedial investigations will be conducted using annual work plans to manage the work activities, and task reports will be used to document the results of the investigations. Sampling and analysis results will be compiled and reported annually with a review of data relative to risk (screening level risk assessment review) for groundwater. This characterization plan outlines the overall strategy for the remedial investigations and defines tasks that are to be conducted during the initial phase of investigation. This plan is presented with the understanding that more specific addenda to the plan will follow.

  2. GEOCHEMISTRY OF SUBSURFACE REACTIVE BARRIERS FOR REMEDIATION OF CONTAMINATED GROUND WATER

    Science.gov (United States)

    Reactive barriers that couple subsurface fluid flow with a passive chemical treatment zone are emerging, cost effective approaches for in-situ remediation of contaminated groundwater. Factors such as the build-up of surface precipitates, bio-fouling, and changes in subsurface tr...

  3. Remedial action and waste disposal project: 100-DR-1 remedial action readiness evaluation plan

    International Nuclear Information System (INIS)

    April, J.G.; Bryant, D.L.; Calverley, C.

    1996-08-01

    This plan presents the method used to assess the readiness of the 100- DR-1 Remedial Action Project. Remediation of the 100-D sites (located on the Hanford Site) involves the excavation (treatment if applicable) and final disposal of contaminated soil and debris associated with the high-priority waste sites in the 100 Areas

  4. Expediting Groundwater Sampling at Hanford and Making It Safer

    International Nuclear Information System (INIS)

    Connell, Carl W. Jr.; Carr, Jennifer S.; Hildebrand, R. Douglas; Schatz, Aaron L.; Conley, S. F.; Brown, W. L.

    2013-01-01

    The CH2M HILL Plateau Remediation Company (CHPRC) manages the groundwater monitoring programs at the Department of Energy's 586-square-mile Hanford site in southeastern Washington state. These programs are regulated by the Resource Conservation and Recovery Act (RCRA), the Comprehensive Environmental Response Compensation and Liability Act (CERCLA), and the Atomic Energy Act (AEA). The purpose of monitoring is to track existing groundwater contamination from past practices, as well as other potential contamination that might originate from RCRA treatment, storage, and disposal (TSD) facilities. An integral part of the groundwater-monitoring program involves taking samples of the groundwater and measuring the water levels in wells scattered across the site. Each year, more than 1,500 wells are accessed for a variety of reasons

  5. STEAM INJECTION REMEDIATION IN FRACTURED BEDROCK AT LORING AIR FORCE BASE

    Science.gov (United States)

    Contaminated groundwater occurs at many Superfund, RCRA, and Brownfields sites. Chlorinated solvents which can form a dense nonaqueous phase (DNAPL) when released to the subsurface can pose an extreme challenge for remediation, as DNAPLs are often difficult to locate and even ha...

  6. The Use of Bacteria for Remediation of Mercury Contaminated Groundwater

    Science.gov (United States)

    Many processes of mercury transformation in the environment are bacteria mediated. Mercury properties cause some difficulties of remediation of mercury contaminated environment. Despite the significance of the problem of mercury pollution, methods of large scale bioremediation ...

  7. Perspectives on innovative characterization and remediation technologies for contaminated sites

    International Nuclear Information System (INIS)

    Kovalick, W.W. Jr.

    2002-01-01

    Contaminated soil and groundwater have been the subject of legislative attention in the U.S. for about 20 years. Major strides in implementing cleanup programs have been accomplished. From complex abandoned hazardous waste sites to underground petroleum storage tanks to (more recently) Brownfields redevelopment, much assessment and remediation work have been carried out. This paper describes some of the data on the kinds of contamination, media, and technologies deployed to deal with problems at these sites. In addition, it highlights technology partnerships that have evolved to demonstrate and verify site measurement and clean-up technologies and to assure a more robust set of clean-up options. Finally, the advent of the Internet has increased access to a considerable body of publicly available information on the cost and performance of these technologies that might be of interest. (author)

  8. Mass Flux Measurements of Arsenic in Groundwater (Battelle Conference)

    Science.gov (United States)

    Concentration trends of arsenic are typically used to evaluate the performance of remediation efforts designed to mitigate arsenic contamination in groundwater. A complementary approach would be to track changes in mass flux of the contaminant through the subsurface, for exampl...

  9. Remedial Action Plan and site design for stabilization of the inactive uranium mill tailings site at Gunnison, Colorado

    International Nuclear Information System (INIS)

    1992-10-01

    To achieve compliance with the proposed US Environmental Protection Agency (EPA) groundwater protection standards the US Department of Energy (DOE) proposes to meet background concentrations or the EPA maximum concentration limits (MCLS) for hazardous constituents in groundwater in the uppermost aquifer at the point of compliance (POC) at the Gunnison Uranium Mill Tailings Remedial Action (UMTRA) Project disposal site near Gunnison, Colorado. The proposed remedial action will ensure protection of human health and the environment. A summary of the principal features of the water resources protection strategy for the Gunnison disposal site is included in this report

  10. Transport and fate of organic wastes in groundwater at the Stringfellow hazardous waste disposal site, southern California

    Science.gov (United States)

    Leenheer, J.A.; Hsu, J.; Barber, L.B.

    2001-01-01

    In January 1999, wastewater influent and effluent from the pretreatment plant at the Stringfellow hazardous waste disposal site were sampled along with groundwater at six locations along the groundwater contaminant plume. The objectives of this sampling and study were to identify at the compound class level the unidentified 40-60% of wastewater organic contaminants, and to determine what organic compound classes were being removed by the wastewater pretreatment plant, and what organic compound classes persisted during subsurface waste migration. The unidentified organic wastes are primarily chlorinated aromatic sulfonic acids derived from wastes from DDT manufacture. Trace amounts of EDTA and NTA organic complexing agents were discovered along with carboxylate metabolites of the common alkylphenolpolyethoxylate plasticizers and nonionic surfactants. The wastewater pretreatment plant removed most of the aromatic chlorinated sulfonic acids that have hydrophobic neutral properties, but the p-chlorobenzenesulfonic acid which is the primary waste constituent passed through the pretreatment plant and was discharged in the treated wastewaters transported to an industrial sewer. During migration in groundwater, p-chlorobenzenesulfonic acid is removed by natural remediation processes. Wastewater organic contaminants have decreased 3- to 45-fold in the groundwater from 1985 to 1999 as a result of site remediation and natural remediation processes. The chlorinated aromatic sulfonic acids with hydrophobic neutral properties persist and have migrated into groundwater that underlies the adjacent residential community. Copyright ?? 2001 .

  11. Modelling Technique for the Assessment of the Sub-Soil Drain for Groundwater Seepage Remediation

    Directory of Open Access Journals (Sweden)

    Tajul Baharuddin Mohamad Faizal

    2017-01-01

    Full Text Available Groundwater simulation technique was carried out for examining the performance of sub-soil drain at problematic site area. Subsoil drain was proposed as one of solution for groundwater seepage occurred at the slope face by reducing groundwater table at Taman Botani Park Kuala Lumpur. The simulation technique used Modular Three-Dimensional Finite Difference Groundwater Flow (MODFLOW software. In transient conditions, the results of simulation showed that heads increases surpass 1 to 2 m from the elevation level of the slope area that caused groundwater seepage on slope face. This study attempt to decrease the heads increase surpass by using different sub-soil drain size in simulation technique. The sub-soil drain capable to decline the heads ranges of 1 to 2 m.

  12. Evaluation of the proposed pilot groundwater pump and treat demonstration for the Paducah Gaseous Diffusion Plant

    International Nuclear Information System (INIS)

    Bodenstein, G.W.; Bonczek, R.R.; Early, T.O.; Hale, T.B.; Huff, D.D.; Nickelson, M.D.; Rightmire, C.T.

    1992-11-01

    This report contains the evaluation and recommendations of a Groundwater Corrective Actions Review Team. The primary goal is to evaluate the technical merit of and the need to implement a proposed groundwater pump-and-treat demonstration project for the Northwest contaminant plume at Paducah, Kentucky. A key distinction recognized by the review team is that the proposed project is intended to be a full-scale hydraulic containment of contaminants migrating from the sources of the plume, not plume remediation. The key questions incorporated into this plan are whether (1) dense, nonaqueous-phase liquids (DNAPLS) are present in the Regional Gravel Aquifer (RGA) at the source of the plume and (2) 99 Tc removal must be included as part of any groundwater treatment process. The first question cannot be answered until the contaminant sources are better defined; the second question requires further risk assessment and/or a policy decision by DOE. Technical evaluation by the review team suggests that the recommended course of action be to modify the proposed work plan to include accurate identification of the sources of contaminants and vertical distribution of contaminants within the Northwest plume before a decision is made on the preferred source-control option. If DNAPLs are not present in the RGA, removal or containment of the sources is recommended. If DNAPLs are present, then hydraulic containment will be required. Finally, the review team recognizes that it is necessary to initiate a more comprehensive analysis of sitewide remediation needs to create links between action taken for the Northwest plume and action taken for other contamination sites at PGPD

  13. Remediating sites contaminated with heavy metals

    International Nuclear Information System (INIS)

    Swartzbaugh, J.; Sturgill, J.; Cormier, B.; Williams, H.D.

    1992-01-01

    This article is intended to serve as a reference for decision makers who must choose an approach to remediate sites contaminated with heavy metals. Its purpose is to explain pertinent chemical and physical characteristics of heavy metals, how to use these characteristics to select remedial technologies, and how to interpret and use data from field investigations. Different metal species are typically associated with different industrial processes. The contaminant species behave differently in various media (i.e., groundwater, soils, air), and require different technologies for containment and treatment. We focus on the metals that are used in industries that generate regulated waste. These include steelmaking, paint and pigment manufacturing, metal finishing, leather tanning, papermaking, aluminum anodizing, and battery manufacturing. Heavy metals are also present in refinery wastes as well as in smelting wastes and drilling muds

  14. Remedial action plan and site design for stabilization of the inactive uranium mill tailings sites at Rifle, Colorado. Volume 2, Appendices D and E: Final report

    Energy Technology Data Exchange (ETDEWEB)

    1992-02-01

    This appendix assesses the present conditions and data gathered about the two inactive uranium mill tailings sites near Rifle, Colorado, and the designated disposal site six miles north of Rifle in the area of Estes Gulch. It consolidates available engineering, radiological, geotechnical, hydrological, meteorological, and other information pertinent to the design of the Remedial Action Plan (RAP). The data characterize conditions at the mill, tailings, and disposal site so that the Remedial Action Contractor (RAC) may complete final designs for the remedial actions.

  15. In-situ treatment of a mixed hydrocarbon plume through enhanced bio-remediation and a PRB system

    International Nuclear Information System (INIS)

    Aglietto, I.; Bargoni, G.; Bretti, L.L.

    2005-01-01

    Groundwater is frequently polluted with mixtures of contaminants that are amenable to different types of remediation. One example is the combination of petroleum hydrocarbons (BTEX) and chlorinated solvents (PCE, TCE, DCE, VC), as it occurs in the groundwater beneath the industrial site that is the objective of the present case study. The site is located in Italy near a main river (Arno), which is supposed to be the final recipient of the contamination and where a possible exposure might take place. The aim of the treatment is the plume containment within the site boundaries in order to avoid further migration of the contaminants towards the river. The design of the remediation system was based on an extensive site characterization that included - but was not limited to - the following information: geological and geochemical, microbiological and hydrological data, together with analytical data (i.e. contaminant concentrations). Pilot tests were also implemented in order to collect the necessary parameters for the full-scale treatment design and calibration. The monitoring of the site conditions was carried out throughout a period of several months, both with periodical measurements and sampling and with fixed monitoring probes, in order to record the aquifer changes (levels, concentrations, etc.) related both to seasonal variations and to the pilot tests. The groundwater is located in a highly heterogeneous aquifer, with a saturated thickness of 1.5 m and an average hydraulic conductivity of 2.5 x 10 -5 m/s. The seepage velocity is extremely low, with a mean value around 1.3 mm/d. This results in a long residence time and limited volumes per time unit to be treated. The site was contaminated by a mixed plume of more than 15 different contaminants, ranging from BTEX, to MTBE, to PAH, to chlorinated solvents. The concentration peaks were in the order of 1-100 mg/l for each contaminant. Petroleum hydrocarbons are quickly degradable through oxidative mechanisms

  16. In-situ treatment of a mixed hydrocarbon plume through enhanced bio-remediation and a PRB system

    Energy Technology Data Exchange (ETDEWEB)

    Aglietto, I.; Bargoni, G.; Bretti, L.L. [Studio aglietto s.r.l. (Italy)

    2005-07-01

    Groundwater is frequently polluted with mixtures of contaminants that are amenable to different types of remediation. One example is the combination of petroleum hydrocarbons (BTEX) and chlorinated solvents (PCE, TCE, DCE, VC), as it occurs in the groundwater beneath the industrial site that is the objective of the present case study. The site is located in Italy near a main river (Arno), which is supposed to be the final recipient of the contamination and where a possible exposure might take place. The aim of the treatment is the plume containment within the site boundaries in order to avoid further migration of the contaminants towards the river. The design of the remediation system was based on an extensive site characterization that included - but was not limited to - the following information: geological and geochemical, microbiological and hydrological data, together with analytical data (i.e. contaminant concentrations). Pilot tests were also implemented in order to collect the necessary parameters for the full-scale treatment design and calibration. The monitoring of the site conditions was carried out throughout a period of several months, both with periodical measurements and sampling and with fixed monitoring probes, in order to record the aquifer changes (levels, concentrations, etc.) related both to seasonal variations and to the pilot tests. The groundwater is located in a highly heterogeneous aquifer, with a saturated thickness of 1.5 m and an average hydraulic conductivity of 2.5 x 10{sup -5} m/s. The seepage velocity is extremely low, with a mean value around 1.3 mm/d. This results in a long residence time and limited volumes per time unit to be treated. The site was contaminated by a mixed plume of more than 15 different contaminants, ranging from BTEX, to MTBE, to PAH, to chlorinated solvents. The concentration peaks were in the order of 1-100 mg/l for each contaminant. Petroleum hydrocarbons are quickly degradable through oxidative mechanisms

  17. Lab-scale investigation on remediation of diesel-contaminated aquifer using microwave energy.

    Science.gov (United States)

    Falciglia, Pietro P; Maddalena, Riccardo; Mancuso, Giuseppe; Messina, Valeria; Vagliasindi, Federico G A

    2016-02-01

    Aquifer contamination with diesel fuel is a worldwide environmental problem, and related available remediation technologies may not be adequately efficient, especially for the simultaneous treatment of both solid and water phases. In this paper, a lab-scale 2.45 GHz microwave (MW) treatment of an artificially diesel-contaminated aquifer was applied to investigate the effects of operating power (160, 350 and 500 W) and time on temperature profiles and contaminant removal from both solid and water phases. Results suggest that in diesel-contaminated aquifer MW remediation, power significantly influences the final reachable temperature and, consequently, contaminant removal kinetics. A maximum temperature of about 120 °C was reached at 500 W. Observed temperature values depended on the simultaneous irradiation of both aquifer grains and groundwater. In this case, solid phase heating is limited by the maximum temperature that interstitial water can reach before evaporation. A minimal residual diesel concentration of about 100 mg kg(-1) or 100 mg L(-1) was achieved by applying a power of 500 W for a time of 60 min for the solid or water phase, respectively. Measured residual TPH fractions showed that MW heating resulted in preferential effects of the removal of different TPH molecular weight fractions and that the evaporation-stripping phenomena plays a major role in final contaminant removal processes. The power low kinetic equation shows an excellent fit (r(2) > 0.993) with the solid phase residual concentration observed for all the powers investigated. A maximum diesel removal of 88 or 80% was observed for the MW treatment of the solid or water phase, respectively, highlighting the possibility to successfully and simultaneously remediate both the aquifer phases. Consequently, MW, compared to other biological or chemical-physical treatments, appears to be a better choice for the fast remediation of diesel-contaminated aquifers. Copyright © 2015 Elsevier

  18. Waste minimization opportunities at the U.S. Uranium Mill Tailings Remedial Action (UMTRA) Project, Rifle, Colorado, site

    International Nuclear Information System (INIS)

    Hartmann, G.L.; Arp, S.; Hempill, H.

    1993-01-01

    At two uranium mill sites in Rifle, Colorado, the US Department of Energy (DOE) Uranium Mill Tailings Remedial Action (UMTRA) Project is removing uranium mill tailings and contaminated subgrade soils. This remediation activity will result in the production of groundwater contaminated with uranium, heavy metals, ammonia, sulfates, and total dissolved solids (TDS). The initial remediation plan called for a wastewater treatment plant for removal of the uranium, heavy metals, and ammonia, with disposal of the treated water, which still includes the sulfates and TDSS, to the Colorado River. The National Pollutant Discharge Elimination (NPDES) permit issued by the Colorado Department of Health for the two Rifle sites contained more restrictive discharge limits than originally anticipated. During the detailed review of alternate treatment systems to meet these more restrictive limits, the proposed construction procedures were reviewed emphasizing the methods to minimize groundwater production to reduce the size of the water treatment facility, or to eliminate it entirely. It was determined that with changes to the excavation procedures and use of the contaminated groundwater for use in dust suppression at the disposal site, discharge to the river could be eliminated completely

  19. Remediation in clay using two-phase vacuum extraction

    International Nuclear Information System (INIS)

    Lindhult, E.C.; Tarsavage, J.M.; Foukaris, K.A.

    1995-01-01

    Soil and groundwater contamination in a tight clay usually requires costly and/or time consuming remediation, due to the inherently low hydraulic conductivity of the soil. However, Dames and Moore is successfully using an innovative, cost-effective two-phase vacuum extraction (VE) technology at a former gasoline service station. Dramatic decreases in BTEX concentrations in onsite and downgradient monitoring wells are apparent

  20. Modifications to the Remedial Action Plan and site design for stabilization of the inactive uranium mill tailings site at Green River, Utah

    International Nuclear Information System (INIS)

    1991-10-01

    This modification to the Green River Final Remedial Action Plan (FRAP) represents the changes made to the document in accordance with a joint agreement between the US Department of Energy (DOE) and the US Nuclear Regulatory Commission (NRC) outlined in a letter dated August 7, 1991. As specified in this letter, methylene chloride will no longer be analyzed in groundwater samples collected from on-site monitor wells. All references to methylene chloride sampling have been deleted from the FRAP, as indicated by the pages in Section 2.0 of this document

  1. Evaluation of Phytoremediation for Management of Chlorinated Solvents in Soil and Groundwater

    Science.gov (United States)

    This document is intended to aid regulators, site owners, consultants, neighbors, and other stakeholders in understanding the proper application of planted systems to remediate groundwater contaminated with halogenated solvents.

  2. RCRA groundwater data analysis protocol for the Hanford Site, Washington

    International Nuclear Information System (INIS)

    Chou, C.J.; Jackson, R.L.

    1992-04-01

    The Resource Conservation and Recovery Act of 1976 (RCRA) groundwater monitoring program currently involves site-specific monitoring of 20 facilities on the Hanford Site in southeastern Washington. The RCRA groundwater monitoring program has collected abundant data on groundwater quality. These data are used to assess the impact of a facility on groundwater quality or whether remediation efforts under RCRA corrective action programs are effective. Both evaluations rely on statistical analysis of groundwater monitoring data. The need for information on groundwater quality by regulators and environmental managers makes statistical analysis of monitoring data an important part of RCRA groundwater monitoring programs. The complexity of groundwater monitoring programs and variabilities (spatial, temporal, and analytical) exhibited in groundwater quality variables indicate the need for a data analysis protocol to guide statistical analysis. A data analysis protocol was developed from the perspective of addressing regulatory requirements, data quality, and management information needs. This data analysis protocol contains four elements: data handling methods; graphical evaluation techniques; statistical tests for trend, central tendency, and excursion analysis; and reporting procedures for presenting results to users

  3. French uranium mining sites remediation

    International Nuclear Information System (INIS)

    Roche, M.

    2002-01-01

    Following a presentation of the COGEMA's general policy for the remediation of uranium mining sites and the regulatory requirements, the current phases of site remediation operations are described. Specific operations for underground mines, open pits, milling facilities and confining the milled residues to meet long term public health concerns are detailed and discussed in relation to the communication strategies to show and explain the actions of COGEMA. A brief review of the current remediation situation at the various French facilities is finally presented. (author)

  4. Pre- and post-remediation characterization of acid-generating fluvial tailings material

    Science.gov (United States)

    Smith, Kathleen S.; Walton-Day, Katherine; Hoal, Karin O.; Driscoll, Rhonda L.; Pietersen, K.

    2012-01-01

    The upper Arkansas River south of Leadville, Colorado, USA, contains deposits of fluvial tailings from historical mining operations in the Leadville area. These deposits are potential non-point sources of acid and metal contamination to surface- and groundwater systems. We are investigating a site that recently underwent in situ remediation treatment with lime, fertilizer, and compost. Pre- and post-remediation fluvial tailings material was collected from a variety of depths to examine changes in mineralogy, acid generation, and extractable nutrients. Results indicate sufficient nutrient availability in the post-remediation near-surface material, but pyrite and acid generation persist below the depth of lime and fertilizer addition. Mineralogical characterization performed using semi-quantitative X-ray diffraction and quantitative SEM-based micro-mineralogy (Mineral Liberation Analysis, MLA) reveal formation of gypsum, jarosite, and complex coatings surrounding mineral grains in post-remediation samples.

  5. Features of groundwater pollution and its relation to overexploitation of groundwater in Shijiazhuang city

    International Nuclear Information System (INIS)

    Guo Yonghai; Wang Zhiming; Liu Shufen; Li Ping

    2005-01-01

    The groundwater pollution in Shijiazhuang city is characterized by an excess of some components and parameters over permitted values. The main pollutants are originated from the city sewage which is quite typical for groundwater pollution in many cities of China. On the basis of agonizingly features of groundwater pollution, the relationship between the groundwater pollution and the groundwater overexploitation is discussed in this paper, and the mechanism of intensifying the pollution by overexploitation has been revealed. Finally, it is proposed that the overexploitation of groundwater is an important inducing factor leading to the groundwater pollution in cities. (authors)

  6. Inexact Socio-Dynamic Modeling of Groundwater Contamination Management

    Science.gov (United States)

    Vesselinov, V. V.; Zhang, X.

    2015-12-01

    Groundwater contamination may alter the behaviors of the public such as adaptation to such a contamination event. On the other hand, social behaviors may affect groundwater contamination and associated risk levels such as through changing ingestion amount of groundwater due to the contamination. Decisions should consider not only the contamination itself, but also social attitudes on such contamination events. Such decisions are inherently associated with uncertainty, such as subjective judgement from decision makers and their implicit knowledge on selection of whether to supply water or reduce the amount of supplied water under the scenario of the contamination. A socio-dynamic model based on the theories of information-gap and fuzzy sets is being developed to address the social behaviors facing the groundwater contamination and applied to a synthetic problem designed based on typical groundwater remediation sites where the effects of social behaviors on decisions are investigated and analyzed. Different uncertainties including deep uncertainty and vague/ambiguous uncertainty are effectively and integrally addressed. The results can provide scientifically-defensible decision supports for groundwater management in face of the contamination.

  7. Feasibility of phyto remediation of common soil and groundwater pollutants

    DEFF Research Database (Denmark)

    Trapp, Stefan; Rein, Arno; Clausen, Lauge Peter Westergaard

    to the two Timbre sites : Hunedoara (Romania) and Szprotawa (Poland). Phytoremediation is the technique to clean up (remediate) contaminated sites using plants, typically trees. The principles of the data were deta iled, with focus on obstacles (phytotoxicity) and factors stimulating success (degradation...

  8. Waste Area Group 10, Operable Unit 10-08, Remedial Investigation/Feasibility Study Annual Status Report for Fiscal Year 2006

    Energy Technology Data Exchange (ETDEWEB)

    R. P. Wells

    2007-05-09

    This report provides a status of the progress made in Fiscal Year 2006 on tasks identified in the Waste Area Group 10, Operable Unit 10-08, Remedial Investigation/Feasibility Study Work Plan. Major accomplishments include: (1) groundwater sampling and review of the groundwater monitoring data, (2) installation of a Sitewide groundwater-level monitoring network, (3) update of the Groundwater Monitoring and Field Sampling Plan of Operable Unit 10-08, (4) re-evaluation of the risk at Site TSF-08, (5) progress on the Operable Unit 10-08 Sitewide Groundwater Model.

  9. Hydrocarbon impacts and remedial action at an active service station

    Energy Technology Data Exchange (ETDEWEB)

    Haidar, S.A. [Keystone Environmental, Burnaby, BC (Canada); Linke, J. [Chevron Canada Ltd., Vancouver, BC (Canada)

    2006-07-01

    This presentation discussed a project that examined the hydrocarbon impacts and remedial action at an active service station. The presentation identified the project partners, discussed the background on the project and project goals. Chevron Canada was the site involved in the study and Keystone Environmental was responsible for testing soil samples, developing the detailed conceptual site model, and for conducting indoor air quality monitoring. The presentation also provided illustrations of the site layout, investigated areas, and soil and groundwater plume. The evaluation and selection of remedial options were also discussed as well as other project planning activities such as assembling the project team, obtaining agreement with stakeholders, and coordinating with the municipality, utility companies, residents, and neighbours. Remediation efforts that were described and illustrated in the presentation included: underpinning and shoring; excavation; and, barrier wall installation. Last, post remediation activities were identified including the installation of post remediation confirmatory wells; reinstating structures; reinstating rear yards, fences, and garages; reconnecting utilities; performance monitoring of barrier wall; and, preparing closure reports for certificates of compliance on off-site properties. 6 figs.

  10. The X-625 Groundwater Treatment Facility: A field-scale test of trichloroethylene dechlorination using iron filings for the X-120/X-749 groundwater plume

    International Nuclear Information System (INIS)

    Liang, L.; West, O.R.; Korte, N.E.

    1997-09-01

    The dehalogenation of chlorinated solvents by zero-valence iron has recently become the subject of intensive research and development as a potentially cost-effective, passive treatment for contaminated groundwater through reactive barriers. Because of its successful application in the laboratory and other field sites, the X-625 Groundwater Treatment Facility (GTF) was constructed to evaluate reactive barrier technology for remediating trichloroethylene (TCE)-contaminated groundwater at the Portsmouth Gaseous Diffusion Plant (PORTS). The X-625 GTF was built to fulfill the following technical objectives: (1) to test reactive barrier materials (e.g., iron filings) under realistic groundwater conditions for long term applications, (2) to obtain rates at which TCE degrades and to determine by-products for the reactive barrier materials tested, and (3) to clean up the TCE-contaminated water in the X-120 plume. The X-625 is providing important field-scale and long-term for the evaluation and design of reactive barriers at PORTS. The X-625 GTS is a unique facility not only because it is where site remediation is being performed, but it is also where research scientists and process engineers can test other promising reactive barrier materials. In addition, the data collected from X-625 GTF can be used to evaluate the technical and economic feasibility of replacing the activated carbon units in the pump-and-treat facilities at PORTS

  11. Remedial Action Plan and site design for stabilization of the inactive uranium mill tailings site at Durango, Colorado: Attachment 3, Groundwater hydrology report. Revised final report

    Energy Technology Data Exchange (ETDEWEB)

    1991-12-01

    The US Environmental Protection Agency (EPA) has established health and environmental protection regulations to correct and prevent groundwater contamination resulting from processing activities at inactive uranium milling sites. According to the Uranium Mill Tailings Radiation Control Act of 1978, (UMTRCA) the US Department of Energy (DOE) is responsible for assessing the inactive uranium processing sites. The DOE has determined this assessment shall include information on hydrogeologic site characterization. The water resources protection strategy that describes how the proposed action will comply with the EPA groundwater protection standards is presented in Attachment 4. Site characterization activities discussed in this section include: Characterization of the hydrogeologic environment; characterization of existing groundwater quality; definition of physical and chemical characteristics of the potential contaminant source; and description of local water resources.

  12. Groundwater quality assessment for the Bear Creek Hydrogeologic Regime at the Y-12 Plant: 1991 groundwater quality data and calculated rate of contaminant migration

    Energy Technology Data Exchange (ETDEWEB)

    1992-02-01

    The report contains groundwater and surface water quality data obtained during the 1991 calendar year at several hazardous and non- hazardous waste management facilities associated with the US Department of Energy (DOE) Y-12 Plant (Figure 1). These sites are southwest of the Y-12 Plant complex within the Bear Creek Hydrogeologic Regime (BCHR), which is one of three regimes defined for the purposes of groundwater and surface-water quality monitoring and remediation (Figure 2). The Environmental Management Department of the Y-12 Plant Health, Safety, Environment, and Accountability (HSEA) Division manages the monitoring activities in each regime as part of the Y-12 Plant Groundwater Protection Program (GWPP).

  13. Groundwater quality assessment for the Bear Creek Hydrogeologic Regime at the Y-12 Plant: 1991 groundwater quality data and calculated rate of contaminant migration

    International Nuclear Information System (INIS)

    1992-02-01

    The report contains groundwater and surface water quality data obtained during the 1991 calendar year at several hazardous and non- hazardous waste management facilities associated with the US Department of Energy (DOE) Y-12 Plant (Figure 1). These sites are southwest of the Y-12 Plant complex within the Bear Creek Hydrogeologic Regime (BCHR), which is one of three regimes defined for the purposes of groundwater and surface-water quality monitoring and remediation (Figure 2). The Environmental Management Department of the Y-12 Plant Health, Safety, Environment, and Accountability (HSEA) Division manages the monitoring activities in each regime as part of the Y-12 Plant Groundwater Protection Program (GWPP)

  14. TREATABILITY TEST PLAN FOR DEEP VADOSE ZONE REMEDIATION AT THE HANFORD'S SITE CENTRAL PLATEAU

    International Nuclear Information System (INIS)

    PETERSEN SW; MORSE JG; TRUEX MJ; LAST GV

    2007-01-01

    A treatability test plan has been prepared to address options for remediating portions of the deep vadose zone beneath a portion of the U.S. Department of Energy's (DOE's) Hanford Site. The vadose zone is the region of the subsurface that extends from the ground surface to the water table. The overriding objective of the treatability test plan is to recommend specific remediation technologies and laboratory and field tests to support the Comprehensive Environmental Response, Compensation, and Liability Act of 1980 and Resource Conservation and Recovery Act of 1976 remedial decision-making process in the Central Plateau of the Hanford Site. Most of the technologies considered involve removing water from the vadose zone or immobilizing the contaminants to reduce the risk of contaminating groundwater. A multi-element approach to initial treatability testing is recommended, with the goal of providing the information needed to evaluate candidate technologies. The proposed tests focus on mitigating two contaminants--uranium and technetium. Specific technologies are recommended for testing at areas that may affect groundwater in the future, but a strategy to test other technologies is also presented

  15. LCA of contaminated site remediation - integration of site-specific impact assessment of local toxic impacts

    DEFF Research Database (Denmark)

    Lemming, Gitte; Hauschild, Michael Zwicky; Chambon, Julie Claire Claudia

    2011-01-01

    impacts have typically been assessed using site-generic characterization models representing a continental scale and excluding the groundwater compartment. Soil contaminants have therefore generally been assigned as emissions to surface soil or surface water compartments. However, such site-generic...... assessments poorly reflect the fate of frequent soil contaminants such as chloroethenes as they exclude the groundwater compartment and assume that the main part escapes to the atmosphere. Another important limitation of the generic impact assessment models is that they do not include the formation......The environmental impacts from remediation can be divided into primary and secondary impacts. Primary impacts cover the local impacts associated with the on-site contamination, whereas the secondary impacts are impacts on the local, regional and global scale generated by the remediation activities...

  16. Baseline risk assessment of groundwater contamination at the Uranium Mill Tailings Site near Gunnison, Colorado

    International Nuclear Information System (INIS)

    1994-04-01

    This report evaluates potential impacts to public health or the environment resulting from groundwater contamination at the former uranium mill processing site. The tailings and other contaminated material at this site are being placed in an off-site disposal cell by the US Department of Energy's (DOE) Uranium Mill Tailings Remedial Action (UMTRA) Project. Currently, the UMTRA Project is evaluating groundwater contamination. This is the second risk assessment of groundwater contamination at this site. The first risk assessment was performed primarily to evaluate existing domestic wells to determine the potential for immediate human health and environmental impacts. This risk assessment evaluates the most contaminated groundwater that flows beneath the processing site towards the Gunnison River. The monitor wells that have consistently shown the highest concentration of most contaminants are used in this risk assessment. This risk assessment will be used in conjunction with additional activities and documents to assist in determining what remedial action is needed for contaminated groundwater at the site after the tailings are relocated. This risk assessment follows an approach outlined by the US Environmental Protection Agency (EPA). The first step is to evaluate groundwater data collected from monitor wells at the site. Evaluation of these data showed that the main contaminants in the groundwater are cadmium, cobalt, iron, manganese, sulfate, uranium, and some of the products of radioactive decay of uranium

  17. Wetlands for the remediation of BTEX [benzene, toluene, ethylbenzene, xylenes] contamination: Amalgamation of policy and technology

    International Nuclear Information System (INIS)

    Main, C.J.

    1993-01-01

    The fate and transport of benzene, toluene, ethylbenzene, and xylenes (BTEX) as they pass from a groundwater to a surface water environment was studied in three separate field experiments. The first examined the fate of BTEX from a spilled gasoline plume as it travelled vertically in the groundwater flow regime from a mineral soil unit through an organic soil unit to a surface wetland. The second considered surface water processes in the swamp that result in losses of BTEX concentrations. The final experiment evaluated the effects of seasonal and temporal changes on the processes occurring in the swamp that affect the fate and transport of BTEX under natural flow conditions. Significant reductions in BTEX were observed as the plume travelled vertically to reach the surface water. Reductions in contaminant levels were primarily due to sorption and biodegradation. On reaching the surface, overall reduction of compound concentration over 6 m of horizontal flow ranged from 92% for benzene to 85% for m-xylene. BTEX losses were mainly due to dilution, volatilization, and sorption. Limitations existing in the approach taken by present legislation and guidelines for wetland protection are discussed. Reactive legislation and guidelines should allow natural remediation of contamination in wetlands to be considered, especially when contaminant remediation requires alteration of the hydrologic flow regime or removal of contaminated material that may result in elimination of the wetland. 70 refs., 20 figs., 14 tabs

  18. Human health and other risk drivers to prioritize site remediation

    Energy Technology Data Exchange (ETDEWEB)

    McHugh, T.; Connor, J. [Groundwater Services Inc, Houston, TX (United States)

    2003-07-01

    Remedial actions at soil and groundwater cleanup sites have traditionally been addressed on an individual, case-by-case basis, as needed to address regulatory requirements. However, effective management of large portfolios of remediation sites (such as hundreds or thousands of underground storage tank sites owned by a single company) requires coordination and prioritisation of individual site response actions to optimise the degree of risk reduction achieved with available resources. To meet these management objectives, two new risk-based management tools have been developed and implemented by the authors: i) a simple risk-based classification system, that can be employed to prioritise response actions, identify key risk drivers, and measure risk reduction progress over time for the full site portfolio; and ii) a lifecycle cost management system that can be employed to forecast remediation spending and optimise risk reduction benefits. For use in prioritising response actions at remediation sites, 'risk' is defined as the negative consequence of no action. (orig.)

  19. In-situ treatment of a mixed hydrocarbon plume through a permeable reactive barrier and enhanced bio-remediation

    International Nuclear Information System (INIS)

    Aglietto, I.; Bretti, L.L.

    2005-01-01

    Groundwater is frequently polluted with mixtures of contaminants that are amenable to different types of remediation. One example is the combination of petroleum hydrocarbons (mostly BTEX) and chlorinated solvents (chlorinated ethenes and propanes), as it occurs in the groundwater beneath the industrial site that is the objective of the present case study. The site is located in Italy near a main river (Arno), which is supposed to be the final recipient of the contamination and where a possible exposure might take place. The aim of the treatment is the plume containment within the site boundaries in order to avoid further migration of the contaminants towards the river. The design of the remediation system was based on an extensive site characterization that included - but was not limited to - the following information: geological and geochemical, microbiological and hydrological data, together with analytical data (i.e. contaminant concentrations). Pilot tests were also implemented in order to collect the necessary parameters for the full-scale treatment design and calibration. The site was contaminated by a mixed plume of more than 30 different contaminants, ranging from BTEX, to MTBE, to PAH, to chlorinated solvents. The concentration peaks were in the order of 1-100 mg/l for each contaminant. Petroleum hydrocarbons are quickly degradable through oxidative mechanisms (especially aerobic biodegradation), whereas fully-chlorinated compounds are only degradable via reductive pathways. A mixed plume of both types of contaminants therefore requires a combined approach with the application of different treatment technologies. The remediation strategy elaborated combines a permeable reactive barrier (PRB) in a funnel and gate configuration for the down-gradient plume containment, with the enhanced bio-remediation of the contaminants for the control of the plume boundaries and for the abatement of the concentration peaks. Pilot tests were carried out in order to assess

  20. Microorganisms in heavy metal bioremediation: strategies for applying microbial-community engineering to remediate soils

    OpenAIRE

    Jennifer L. Wood; Caixian Tang; Ashley E. Franks; Wuxing Liu

    2016-01-01

    The remediation of heavy-metal-contaminated soils is essential as heavy metals persist and do not degrade in the environment. Remediating heavy-metal-contaminated soils requires metals to be mobilized for extraction whilst, at the same time, employing strategies to avoid mobilized metals leaching into ground-water or aquatic systems. Phytoextraction is a bioremediation strategy that extracts heavy metals from soils by sequestration in plant tissues and is currently the predominant bioremediat...

  1. Influence of physical factors and geochemical conditions on groundwater acidification during enhanced reductive dechlorination

    Science.gov (United States)

    Brovelli, A.; Barry, D. A.; Robinson, C.; Gerhard, J.

    2010-12-01

    Enhanced reductive dehalogenation is an attractive in situ treatment technology for chlorinated contaminants. The process includes two acid-forming microbial reactions: fermentation of an organic substrate resulting in short-chain fatty acids, and dehalogenation resulting in hydrochloric acid. The accumulation of acids and the resulting drop of groundwater pH are controlled by the mass and distribution of chlorinated solvents in the source zone, type of electron donor, availability of alternative terminal electron acceptors and presence of soil mineral phases able to buffer the pH (such as carbonates). Groundwater acidification may reduce or halt microbial activity, and thus dehalogenation, significantly increasing the time and costs required to remediate the aquifer. For this reason, research in this area is gaining increasing attention. In previous work (Robinson et al., 2009 407:4560, Sci. Tot. Environ, Robinson and Barry, 2009 24:1332, Environ. Model. & Software, Brovelli et al., 2010, submitted), a detailed geochemical and groundwater flow model able to predict the pH change occurring during reductive dehalogenation was developed. The model accounts for the main processes influencing groundwater pH, including the groundwater composition, the electron donor used and soil mineral phase interactions. In this study, the model was applied to investigate how spatial variability occurring at the field scale affects groundwater pH and dechlorination rates. Numerical simulations were conducted to examine the influence of heterogeneous hydraulic conductivity on the distribution of the injected, fermentable substrate and on the accumulation/dilution of the acidic products of reductive dehalogenation. The influence of the geometry of the DNAPL source zone was studied, as well as the spatial distribution of soil minerals. The results of this study showed that the heterogeneous distribution of the soil properties have a potentially large effect on the remediation efficiency

  2. ARSENIC INTERACTION WITH IRON (II, III) HYDROXYCARBONATE GREEN RUST: IMPLICATIONS FOR ARSENIC REMEDIATION

    Science.gov (United States)

    Zerovalent iron is being used in permeable reactive barriers (PRBs) to remediate groundwater arsenic contamination. Iron(II, III) hydroxycarbonate green rust is a major corrosion product of zerovalent iron under anaerobic conditions. The interaction between arsenic and this green...

  3. Natural radioactivity in groundwater--a review.

    Science.gov (United States)

    Dinh Chau, Nguyen; Dulinski, Marek; Jodlowski, Pawel; Nowak, Jakub; Rozanski, Kazimierz; Sleziak, Monika; Wachniew, Przemyslaw

    2011-12-01

    The issue of natural radioactivity in groundwater is reviewed, with emphasis on those radioisotopes which contribute in a significant way to the overall effective dose received by members of the public due to the intake of drinking water originating from groundwater systems. The term 'natural radioactivity' is used in this context to cover all radioactivity present in the environment, including man-made (anthropogenic) radioactivity. Comprehensive discussion of radiological aspects of the presence of natural radionuclides in groundwater, including an overview of current regulations dealing with radioactivity in drinking water, is provided. The presented data indicate that thorough assessments of the committed doses resulting from the presence of natural radioactivity in groundwater are needed, particularly when such water is envisaged for regular intake by infants. They should be based on a precise determination of radioactivity concentration levels of the whole suite of radionuclides, including characterisation of their temporal variability. Equally important is a realistic assessment of water intake values for specific age groups. Only such an evaluation may provide the basis for possible remedial actions.

  4. Technical and Economic Assessment of Solar Photovoltaic for Groundwater Extraction on the Hanford Site

    Energy Technology Data Exchange (ETDEWEB)

    Mackley, Rob D. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Anderson, David M. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Thomle, Jonathan N. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Strickland, Christopher E. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

    2015-09-01

    The overall goal of environmental remediation is to protect human health and the environment. Implementing renewable energy sources such as solar photovoltaic (PV) in groundwater extraction and pump-and-treat (P&T) systems may help minimize the environmental footprint of remediation efforts. The first step in considering solar PV for powering Hanford groundwater extraction is assessing the technical and economic feasibility and identifying potential target locations where implementation would be most successful. Accordingly, a techno-economic assessment of solar PV for Hanford groundwater extraction was completed in FY15. Multiple solar PV alternatives ranging in size from 1.2 to 22.4 kWp DC were evaluated and compared against traditional grid-powered systems. Results indicate that the degree to which solar PV alternatives are feasible is primarily a function of the distance of avoided power cable costs and the inclusion of an energy storage component. Standalone solar PV systems provide an energy source at the well and avoid the costs and logistics associated with running long lengths of expensive power cable to the well-head. When solar PV systems include a battery storage component, groundwater can be pumped continuously day and night in a year-round schedule. However, due to the high cost premium of the energy storage component, a fully solar-powered solution could not provide an economic direct replacement for line-powered pumping systems. As a result, the most ideal target locations for successful implementation of solar PV on the Hanford Site are remote or distant extraction wells where the primary remedial objective is contaminant mass removal (as opposed to hydraulic containment) and three-season (March through October) intermittent pumping is acceptable (e.g. remediation of hexavalent chromium in 200-UP-1).

  5. A new risk and stochastic analysis of monitoring and remediation in subsurface contamination

    Science.gov (United States)

    Papapetridis, K.; Paleologos, E.

    2012-04-01

    Sanitary landfills constitute the most widely used management approach for the disposal of solid wastes because of their simplicity and cost effectiveness. However, historical records indicate that landfills exhibit a high failure rate of groundwater contamination. Successful detection of aquifer contamination via monitoring wells is a complicated problem with many factors, such as the heterogeneity of the geologic environment, the dispersion of contamination into the geologic medium, the quantity and nature of the contaminants, the number and location of the monitoring wells, and the frequency of sampling, all contributing to the uncertainty of early detection. Detection of contaminants, of course, is of value if remedial actions follow as soon as possible, so that the volume of contaminated groundwater to be treated is minimized. Practically, there is always a time lag between contaminant detection and remedial action response. Administrative decisions and arrangements with local contractors initiate remedial procedures introduces a time lag between detection and remediation time. During this time lag a plume continues to move into an aquifer contaminating larger groundwater volumes. In the present study these issues are addressed by investigating the case of instantaneous leakage from a landfill facility into a heterogeneous aquifer. The stochastic Monte Carlo framework was used to address, in two dimensions, the problem of evaluating the effectiveness of contaminant detection in heterogeneous aquifers by linear networks of monitoring wells. Numerical experiments based on the random-walk tracking-particle method were conducted to determine the detection probabilities and to calculate contaminated areas at different time steps. Several cases were studied assuming different levels of geologic heterogeneity, contamination dispersion, detectable contamination limits and monitoring wells' sampling frequencies. A new perspective is introduced for the correction of

  6. Screening and comparison of remedial alternatives for the South Field and flyash piles at the Fernald site

    International Nuclear Information System (INIS)

    Bumb, A.C.; Jones, G.N.

    1996-05-01

    The South Field, the Inactive Flyash Pile, and the Active Flyash Pile are in close proximity to each other and are part of Operable Unit 2 (OU2) at the Fernald Environmental Management Project (FEMP). The baseline risk assessment indicated that the exposure pathways which pose the most significant risk are external radiation from radionuclides in surface soils and use of uranium contaminated groundwater. This paper presents screening and comparison of various remedial alternatives considered to mitigate risks from the groundwater pathway. Eight remedial alternatives were developed which consisted of consolidation and capping, excavation and off-site disposal with or without treatment, excavation and on-site disposal with or without treatment and combinations of these. Risk-based source (soil) preliminary remediation levels (PRLs) and waste acceptance criteria (WACs) were developed for consolidation and capping, excavation, and on-site disposal cell. The PRLs and WACs were developed using an integrated modeling tool consisting of an infiltration model, a surface water model, a vadose zone model, and a three-dimensional contaminant migration model in saturated media. The PRLs and WACs were then used to determine need for soil treatment, determine excavation volumes, and screen remedial alternatives. The selected remedial alternative consisted of excavation and on-site disposal with off-site disposal of the fraction exceeding the WAC

  7. Information for consideration in reviewing groundwater protection plans for uranium mill tailings sites

    International Nuclear Information System (INIS)

    Thorne, P.D.

    1992-05-01

    Guidelines and acceptance criteria were developed for reviewing certain aspects of groundwater protection plans for uranium mill tailing sites. The aspects covered include: (1) leaching and long-term releases of hazardous and radioactive constituents from tailings and other contaminated materials, (2) attenuation of hazardous and radioactive constituents in groundwater under saturated and unsaturated conditions, (3) design and implementation of groundwater monitoring programs, (4) design and construction of groundwater protection barriers, and (5) efficiency and effectiveness of groundwater cleanup programs. The objective of these guidelines is to assist the US Nuclear Regulatory Commission staff in reviewing Remedial Action Plans for inactive waste sites and licensing application documents for active commercial uranium and thorium mills

  8. Study on protection and reclamation for the groundwater resources in Busan area

    Energy Technology Data Exchange (ETDEWEB)

    Sung, Ig-Hwan; Cho, Byong-Wook; Lee, Byung-Dae [Korea Institute of Geology Mining and Materials, Taejon (KR)

    1999-12-01

    This research was carried out to investigate the protection of contaminated groundwater and reclamation in the Pusan area. Groundwater Busan city is highly subjected to groundwater contamination due to its unfavorable geographical features; it is located in the estuaries of the Nakdong river, most of the urban area are composed of highlands, and the large population resides in the downhill. Heavy pumping and deterioration of groundwater are currently found to be significant compared to other major cities, resulting in shortage of water resources and contamination of groundwater. The first step of the research aims at investigating hydrogeological features which includes analysis of climate and hydrologic data, investigation of geology and structural pattern, acquisition of hydrological data, inspection of wells, measurement of groundwater level, analysis of water samples, investigation of groundwater contamination, isotope analysis, and monitoring water level by automated data logger to identify seawater intrusion. The second step is to simulate the two-dimensional flow model after construction of the database. Aside from this, abandoned wells were transformed into observation wells. An effort for remedy of contaminated groundwater was made and the water quality was constantly monitored to improve the deteriorated water to the drinking water. Kriging analysis and geostatistical analysis were carried out in order to verify the effect of seawater intrusion, showing that there is no clear evidence of seawater intrusion. Instead, it is clear that groundwater in the inland district was preferentially contaminated by pollutants originated from human activities. Based on the two-dimensional flow model, only 0.021 m{sup 3} may be allocated to each person a day from public wells for emergency. In order to ensure that protection and remediation of groundwater of the Busan area are able to accomplish, well-controlled management of aquifer systems needs to be maintained and

  9. Final audit report of remedial action construction at the UMTRA Project Site, Gunnison, Colorado. Revision 0

    International Nuclear Information System (INIS)

    1996-01-01

    The final audit report for remedial action at the Gunnison, Colorado Uranium Mill Tailings Remedial Action (UMTRA) Project site consists of a summary of the radiological surveillances/audits, quality assurance (QA) in-process surveillances, and QA remedial action close-out inspections performed by the U.S. Department of Energy (DOE) and the Technical Assistance Contractor (TAC); and on-site construction reviews (OSCR) performed by the U.S. Nuclear Regulatory Commission (NRC). Two radiological surveillances and four radiological audits were performed at the Gunnison site. The surveillances were performed on 16 to 19 September 1992 and 28 June to 1 July 1993. The radiological audits were performed on 4 to 7 October 1993; 13 to 16 June 1994; 19 to 22 September 1994 and 10 to 12 July 1995. The surveillances and audits resulted in 79 observations. Thirty-four of the observations raised DOE concerns that were resolved on the site or through subsequent corrective action. All outstanding issues were closed on 12 July 1995. The radiological surveillances and audits are discussed in Section 2.0 of this report. Ten QA in-process surveillances were performed at the Gunnison UMTRA Project site. The surveillances were performed on 24 to 25 September 1992, 7 to 9 July 1993, 29 October 1993, 27 to 28 June 1994, 31 October to 1 November 1994, 19 to 20 June 1 995, 20 to 21 July 1995, 17 to 18 August 1995, 20 September 1995, and 11 to 13 October 1995. The surveillances resulted in 100 observations. Six observations contained recommendations that required responses from the Remedial Action Contractor (RAC). Ninety-five observations contained a recommendation that required no response. All outstanding issues were closed on 8 January 1996. The QA in-process surveillances are discussed in Section 3.0 of this report

  10. Regional groundwater flow model for C, K. L. and P reactor areas, Savannah River Site, Aiken, SC

    Energy Technology Data Exchange (ETDEWEB)

    Flach, G.P.

    2000-02-11

    A regional groundwater flow model encompassing approximately 100 mi2 surrounding the C, K, L, and P reactor areas has been developed. The reactor flow model is designed to meet the planning objectives outlined in the General Groundwater Strategy for Reactor Area Projects by providing a common framework for analyzing groundwater flow, contaminant migration and remedial alternatives within the Reactor Projects team of the Environmental Restoration Department. The model provides a quantitative understanding of groundwater flow on a regional scale within the near surface aquifers and deeper semi-confined to confined aquifers. The model incorporates historical and current field characterization data up through Spring 1999. Model preprocessing is automated so that future updates and modifications can be performed quickly and efficiently. The CKLP regional reactor model can be used to guide characterization, perform scoping analyses of contaminant transport, and serve as a common base for subsequent finer-scale transport and remedial/feasibility models for each reactor area.

  11. Regional groundwater flow model for C, K. L. and P reactor areas, Savannah River Site, Aiken, SC

    International Nuclear Information System (INIS)

    Flach, G.P.

    2000-01-01

    A regional groundwater flow model encompassing approximately 100 mi2 surrounding the C, K, L, and P reactor areas has been developed. The reactor flow model is designed to meet the planning objectives outlined in the General Groundwater Strategy for Reactor Area Projects by providing a common framework for analyzing groundwater flow, contaminant migration and remedial alternatives within the Reactor Projects team of the Environmental Restoration Department. The model provides a quantitative understanding of groundwater flow on a regional scale within the near surface aquifers and deeper semi-confined to confined aquifers. The model incorporates historical and current field characterization data up through Spring 1999. Model preprocessing is automated so that future updates and modifications can be performed quickly and efficiently. The CKLP regional reactor model can be used to guide characterization, perform scoping analyses of contaminant transport, and serve as a common base for subsequent finer-scale transport and remedial/feasibility models for each reactor area

  12. Superfund Record of Decision (EPA Region 6): United Nuclear Corporation, Mckinley County, New Mexico, ground-water operable unit (first remedial action) September 1988

    International Nuclear Information System (INIS)

    1988-01-01

    The United Nuclear Corporation (UNC) site is located approximately 17 miles northeast of Gallup, New Mexico in McKinley County. The site operated as a State-licensed uranium mill facility from June 1977 to May 1982. It includes an ore-processing mill (about 25 acres) and an unlined tailings pond area (about 100 acres). In July 1979, approximately 23 million gallons of tailings and pond water were released to a nearby river as a result of a dam breach in the tailings pond area. The site damage was repaired; however, attention was focused on ground-water contamination resulting from tailings seepage. Nevertheless, the offsite migration of radionuclides and chemical constituents from uranium milling byproduct materials into the ground water, as well as to surface water and air, are still principal threats at the site. The remedial action will address onsite ground water contamination. Source control and onsite surface reclamation will be implemented under the direction of the Nuclear Regulatory Commission and integrated with this ground water operable unit. The primary contaminants of concern affecting the ground water are metals including arsenic, and radioactive substances including radium-226/228 and gross alpha. The selected remedial action for the site is included

  13. Hanford Site Groundwater Monitoring for Fiscal Year 2002

    Energy Technology Data Exchange (ETDEWEB)

    Hartman, Mary J.; Morasch, Launa F.; Webber, William D.

    2003-02-28

    This report presents the results of groundwater and vadose zone monitoring and remediation for fiscal year 2002 on the U.S. Department of Energy's Hanford Site in Washington State. This report is written to meet the requirements in CERCLA, RCRA, the Atomic Energy Act of 1954, and Washington State Administrative Code.

  14. FIELD STUDY OF ARSENIC REMOVAL FROM GROUNDWATER BY ZEROVALENT IRON

    Science.gov (United States)

    Contamination of ground-water resources by arsenic is a widespread environmental problem; consequently, there is a need for developments and improvements of remedial technologies to effectively manage arsenic contamination in ground water and soils. In June 2005, a 7 m long, 14 ...

  15. Using simulation-optimization techniques to improve multiphase aquifer remediation

    Energy Technology Data Exchange (ETDEWEB)

    Finsterle, S.; Pruess, K. [Lawrence Berkeley Laboratory, Berkeley, CA (United States)

    1995-03-01

    The T2VOC computer model for simulating the transport of organic chemical contaminants in non-isothermal multiphase systems has been coupled to the ITOUGH2 code which solves parameter optimization problems. This allows one to use linear programming and simulated annealing techniques to solve groundwater management problems, i.e. the optimization of operations for multiphase aquifer remediation. A cost function has to be defined, containing the actual and hypothetical expenses of a cleanup operation which depend - directly or indirectly - on the state variables calculated by T2VOC. Subsequently, the code iteratively determines a remediation strategy (e.g. pumping schedule) which minimizes, for instance, pumping and energy costs, the time for cleanup, and residual contamination. We discuss an illustrative sample problem to discuss potential applications of the code. The study shows that the techniques developed for estimating model parameters can be successfully applied to the solution of remediation management problems. The resulting optimum pumping scheme depends, however, on the formulation of the remediation goals and the relative weighting between individual terms of the cost function.

  16. Screening of groundwater remedial alternatives for brownfield sites: a comprehensive method integrated MCDA with numerical simulation.

    Science.gov (United States)

    Li, Wei; Zhang, Min; Wang, Mingyu; Han, Zhantao; Liu, Jiankai; Chen, Zhezhou; Liu, Bo; Yan, Yan; Liu, Zhu

    2018-06-01

    Brownfield sites pollution and remediation is an urgent environmental issue worldwide. The screening and assessment of remedial alternatives is especially complex owing to its multiple criteria that involves technique, economy, and policy. To help the decision-makers selecting the remedial alternatives efficiently, the criteria framework conducted by the U.S. EPA is improved and a comprehensive method that integrates multiple criteria decision analysis (MCDA) with numerical simulation is conducted in this paper. The criteria framework is modified and classified into three categories: qualitative, semi-quantitative, and quantitative criteria, MCDA method, AHP-PROMETHEE (analytical hierarchy process-preference ranking organization method for enrichment evaluation) is used to determine the priority ranking of the remedial alternatives and the solute transport simulation is conducted to assess the remedial efficiency. A case study was present to demonstrate the screening method in a brownfield site in Cangzhou, northern China. The results show that the systematic method provides a reliable way to quantify the priority of the remedial alternatives.

  17. Recovery of light nonaqueous-phase liquids without groundwater pumping

    International Nuclear Information System (INIS)

    Markley, D.E.; Prince-Larsen, N.

    1995-01-01

    This paper outlines recovery of light nonaqueous-phase liquids (LNAPL) encountered in the subsurface at a remote natural gas facility. Remediation of LNAPL in the subsurface usually begins with dual pumping of LNAPL and groundwater. However, regulations required that only LNAPL be recovered. Methods were sought for recovering LNAPL from groundwater without pumping groundwater to the surface. Alternative methods of LNAPL recovery, using a variety of skimming pumps, included: LNAPL recovery from large-diameter wells; LNAPL recovery from trenches; LNAPL recovery from small-diameter wells; and vacuum-enhanced recovery of LNAPL while skimming with a belt skimmer. Based on the goals of the site owner and the costs associated with each alternative examined, the recommended method for recovering LNAPL without groundwater pumping was recovery of LNAPL while skimming with a belt skimmer. This paper discusses both the advantages and limitations of this technique

  18. Effects of microarrangement of solid particles on PCE migration and its remediation in porous media

    Science.gov (United States)

    Wu, Ming; Wu, Jianfeng; Wu, Jichun; Hu, Bill X.

    2018-02-01

    Groundwater can be stored abundantly in granula-composed aquifers with high permeability. The microstructure of granular materials has important effect on the permeability of aquifers and the contaminant migration and remediation in aquifers is also influenced by the characteristics of porous media. In this study, two different microscale arrangements of sand particles are compared to reveal the effects of microstructure on the contaminant migration and remediation. With the help of fractal theory, the mathematical expressions of permeability and entry pressure are conducted to delineate granular materials with regular triangle arrangement (RTA) and square pitch arrangement (SPA) at microscale. Using a sequential Gaussian simulation (SGS) method, a synthetic heterogeneous site contaminated by perchloroethylene (PCE) is then used to investigate the migration and remediation affected by the two different microscale arrangements. PCE is released from an underground storage tank into the aquifer and the surfactant is used to clean up the subsurface contamination. Results suggest that RTA can not only cause more groundwater contamination, but also make remediation become more difficult. The PCE remediation efficiency of 60.01-99.78 % with a mean of 92.52 and 65.53-99.74 % with a mean of 95.83 % is achieved for 200 individual heterogeneous realizations based on the RTA and SPA, respectively, indicating that the cleanup of PCE in aquifer with SPA is significantly easier. This study leads to a new understanding of the microstructures of porous media and demonstrates how microscale arrangements control contaminant migration in aquifers, which is helpful to design successful remediation scheme for underground storage tank spill.

  19. Groundwater arsenic remediation using zerovalent iron: Batch and column tests

    Science.gov (United States)

    Recently, increasing efforts have been made to explore the applicability and limitations of zerovalent iron (Fe0) for the treatment of arsenicbearing groundwater and wastewater. The experimental batch and column tests have demonstrated that arsenate and arsenite are removed effec...

  20. The Oak Ridge Field Research Center : Advancing Scientific Understanding of the Transportation, Fate, and Remediation of Subsurface Contamination Sources and Plumes

    International Nuclear Information System (INIS)

    David Watson

    2005-01-01

    Historical research, development, and testing of nuclear materials across this country resulted in subsurface contamination that has been identified at over 7,000 discrete sites across the U.S. Department of Energy (DOE) complex. With the end of the Cold War threat, DOE has shifted its emphasis to remediation, decommissioning, and decontamination of the immense volumes of contaminated groundwater, sediments, and structures at its sites. DOE currently is responsible for remediating 1.7 trillion gallons of contaminated groundwater, an amount equal to approximately four times the daily U.S. water consumption, and 40 million cubic meters of contaminated soil, enough to fill approximately 17 professional sports stadiums.* DOE also sponsors research intended to improve or develop remediation technologies, especially for difficult, currently intractable contaminants or conditions. The Oak Ridge FRC is representative of some difficult sites, contaminants, and conditions. Buried wastes in contact with a shallow water table have created huge reservoirs of contamination. Rainfall patterns affect the water table level seasonally and over time. Further, the hydrogeology of the area, with its fractures and karst geology, affects the movement of contaminant plumes. Plumes have migrated long distances and to surface discharge points through ill-defined preferred flowpaths created by the fractures and karst conditions. From the standpoint of technical effectiveness, remediation options are limited, especially for contaminated groundwater. Moreover, current remediation practices for the source areas, such as capping, can affect coupled processes that, in turn, may affect the movement of subsurface contaminants in unknown ways. Research conducted at the FRC or with FRC samples therefore promotes understanding of the processes that influence the transport and fate of subsurface contaminants, the effectiveness and long-term consequences of extant remediation options, and the

  1. Remedial action plan and site design for stabilization of the inactive uranium processing site at Naturita, Colorado

    International Nuclear Information System (INIS)

    1994-03-01

    Attachment 3 Groundwater Hydrology Report describes the hydrogeology, water quality, and water resources at the processing site and Dry Flats disposal site. The Hydrological Services calculations contained in Appendix A of Attachment 3, are presented in a separate report. Attachment 4 Water Resources Protection Strategy describes how the remedial action will be in compliance with the proposed EPA groundwater standards

  2. Evaluation of the proposed pilot groundwater pump and treat demonstration for the Paducah Gaseous Diffusion Plant

    Energy Technology Data Exchange (ETDEWEB)

    Bodenstein, G.W.; Bonczek, R.R.; Early, T.O.; Hale, T.B.; Huff, D.D.; Nickelson, M.D.; Rightmire, C.T.

    1992-11-01

    This report contains the evaluation and recommendations of a Groundwater Corrective Actions Review Team. The primary goal is to evaluate the technical merit of and the need to implement a proposed groundwater pump-and-treat demonstration project for the Northwest contaminant plume at Paducah, Kentucky. A key distinction recognized by the review team is that the proposed project is intended to be a full-scale hydraulic containment of contaminants migrating from the sources of the plume, not plume remediation. The key questions incorporated into this plan are whether (1) dense, nonaqueous-phase liquids (DNAPLS) are present in the Regional Gravel Aquifer (RGA) at the source of the plume and (2) [sup 99]Tc removal must be included as part of any groundwater treatment process. The first question cannot be answered until the contaminant sources are better defined; the second question requires further risk assessment and/or a policy decision by DOE. Technical evaluation by the review team suggests that the recommended course of action be to modify the proposed work plan to include accurate identification of the sources of contaminants and vertical distribution of contaminants within the Northwest plume before a decision is made on the preferred source-control option. If DNAPLs are not present in the RGA, removal or containment of the sources is recommended. If DNAPLs are present, then hydraulic containment will be required. Finally, the review team recognizes that it is necessary to initiate a more comprehensive analysis of sitewide remediation needs to create links between action taken for the Northwest plume and action taken for other contamination sites at PGPD.

  3. Remedial actions at the former Vitro Rare Metals plant site, Canonsburg, Washington County, Pennsylvania. Final Environmental Impact Statement. Volume II. Appendices

    Energy Technology Data Exchange (ETDEWEB)

    1983-07-01

    This report provides a summary of the conceptual design and other information necessary to understand the proposed remedial action at the expanded Canonsburg, Pennsylvania site. This design constitutes the current approach to stabilizing the radioactively contaminated materials in place in a manner that would fully protect the public health and environment. This summary is intended to provide sufficient detail for the reader to understand the proposed remedial action and the anticipated environmental impacts. The site conceptual design has been developed using available data. In some cases, elements of the design have not been developed fully and will be made final during the detailed design process.

  4. Remedial actions at the former Vitro Rare Metals plant site, Canonsburg, Washington County, Pennsylvania. Final Environmental Impact Statement. Volume II. Appendices

    International Nuclear Information System (INIS)

    1983-07-01

    This report provides a summary of the conceptual design and other information necessary to understand the proposed remedial action at the expanded Canonsburg, Pennsylvania site. This design constitutes the current approach to stabilizing the radioactively contaminated materials in place in a manner that would fully protect the public health and environment. This summary is intended to provide sufficient detail for the reader to understand the proposed remedial action and the anticipated environmental impacts. The site conceptual design has been developed using available data. In some cases, elements of the design have not been developed fully and will be made final during the detailed design process

  5. Biogeochemical Considerations Related To The Remediation Of I-129 Plumes

    Energy Technology Data Exchange (ETDEWEB)

    Kaplan, D. I. [Savannah River Site (SRS), Aiken, SC (United States); Yeager, C. [Los Alamos National Laboratory , Los Alamos, NM (United States); Denham, M. E. [Savannah River Site (SRS), Aiken, SC (United States); Zhang, S. [Texas A& amp; M University, Galveston, TX (United States); Xu, C. [Texas A& amp; M University, Galveston, TX (United States); Schwehr, K. A. [Texas A& amp; M University, Galveston, TX (United States); Li, H. P. [Texas A& amp; M University, Galveston, TX (United States); Brinkmeyer, R. [Texas A& amp; M University, Galveston, TX (United States); Santschi, P. H. [Texas A& amp; M University, Galveston, TX (United States)

    2012-09-24

    The objectives of this report were to: provide a current state of the science of radioiodine biogeochemistry relevant to its fate and transport at the Hanford Site; conduct a review of Hanford Site data dealing with groundwater {sup 129}I; and identify critical knowledge gaps necessary for successful selection, implementation, and technical defensibility in support of remediation decisions.

  6. LONG-TERM GEOCHEMICAL BEHAVIOR OF A ZEROVALENT IRON PERMEABLE REACTIVE BARRIER FOR THE TREATMENT OF HEXAVALENT CHROMIUM IN GROUNDWATER

    Science.gov (United States)

    Passive, in-situ reactive barriers have proven to be viable, cost-effective systems for the remediation of Cr-contaminated groundwater at some sites. Permeable reactive barriers (PRBs) are installed in the flow-path of groundwater, most typically as vertical treatment walls. Re...

  7. Laboratory/industry partnerships for environmental remediation

    International Nuclear Information System (INIS)

    Beskid, N.J.; Zussman, S.K.

    1994-01-01

    There are two measures of ''successful'' technology transfer in DOE's environmental restoration and waste management program. The first is remediation of DOE sites, and the second is commercialization of an environmental remediation process or product. The ideal case merges these two in laboratory/industry partnerships for environmental remediation. The elements to be discussed in terms of their effectiveness in aiding technology transfer include: a decision-m