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Sample records for film laminated leather

  1. Properties of Chitosan-Laminated Collagen Film

    Directory of Open Access Journals (Sweden)

    Vera Lazić

    2012-01-01

    Full Text Available The objective of this study is to determine physical, mechanical and barrier properties of chitosan-laminated collagen film. Commercial collagen film, which is used for making collagen casings for dry fermented sausage production, was laminated with chitosan film layer in order to improve the collagen film barrier properties. Different volumes of oregano essential oil per 100 mL of filmogenic solution were added to chitosan film layer: 0, 0.2, 0.4, 0.6 and 0.8 mL to optimize water vapour barrier properties. Chitosan layer with 0.6 or 0.8 % of oregano essential oil lowered the water vapour transmission rate to (1.85±0.10·10–6 and (1.78±0.03·10–6 g/(m2·s·Pa respectively, compared to collagen film ((2.51±0.05·10–6 g/(m2·s·Pa. However, chitosan-laminated collagen film did not show improved mechanical properties compared to the collagen one. Tensile strength decreased from (54.0±3.8 MPa of the uncoated collagen film to (36.3±4.0 MPa when the film was laminated with 0.8 % oregano essential oil chitosan layer. Elongation at break values of laminated films did not differ from those of collagen film ((18.4±2.7 %. Oxygen barrier properties were considerably improved by lamination. Oxygen permeability of collagen film was (1806.8±628.0·10–14 cm3/(m·s·Pa and values of laminated films were below 35·10–14 cm3/(m·s·Pa. Regarding film appearance and colour, lamination with chitosan reduced lightness (L and yellowness (+b of collagen film, while film redness (+a increased. These changes were not visible to the naked eye.

  2. Fabrication of alumina films with laminated structures by ac anodization

    Directory of Open Access Journals (Sweden)

    Hiroyo Segawa

    2014-01-01

    Full Text Available Anodization techniques by alternating current (ac are introduced in this review. By using ac anodization, laminated alumina films are fabricated. Different types of alumina films consisting of 50–200 nm layers were obtained by varying both the ac power supply and the electrolyte. The total film thickness increased with an increase in the total charge transferred. The thickness of the individual layers increased with the ac voltage; however, the anodization time had little effect on the film thickness. The laminated alumina films resembled the nacre structure of shells, and the different morphologies exhibited by bivalves and spiral shells could be replicated by controlling the rate of increase of the applied potentials.

  3. STRETCH FABRICS IN LEATHER MANUFACTURING: PERFORMANCE PROPERTIES OF STRECH LEATHERS

    Directory of Open Access Journals (Sweden)

    ORK Nilay

    2016-05-01

    Full Text Available Product variability of manufactured leather goods such as garment leathers could be closely related to the wear comfort because each material forming the garments are affected the comfort properties of the products. Considering the significant demand to elastic woven stretch fabrics and the advantages provided to leather goods like allowing easy body movements, well-fitting and keeping the shape make the use of stretch fabrics focus in interest. In this study, the performance properties of stretch leathers, leathers and spandex fabrics were presented and the differences between the characteristic properties of the leathers were described. For this purpose, physical characteristics of leathers were investigated in terms of thickness, weight, drape ability, stiffness, bending stiffness, air and water vapor permeability. The drape ability, stiffness and bending stiffness properties were significantly affected by the stretch fabrics laminated on the suede side of the leathers. The drape ability, stiffness and bending values were increased due to the implementation of stretch fabrics. There was no significant difference between the air permeability values of the leathers prior and after the implementation of stretch fabrics in contrast to water vapor permeability. The results of this study showed that the aesthetic behavior of clothing materials such as drape and stiffness properties as well as water vapor permeability was mainly affected from the implementation of the stretch fabrics.

  4. Bioinspired Transparent Laminated Composite Film for Flexible Green Optoelectronics.

    Science.gov (United States)

    Lee, Daewon; Lim, Young-Woo; Im, Hyeon-Gyun; Jeong, Seonju; Ji, Sangyoon; Kim, Yong Ho; Choi, Gwang-Mun; Park, Jang-Ung; Lee, Jung-Yong; Jin, Jungho; Bae, Byeong-Soo

    2017-07-19

    Herein, we report a new version of a bioinspired chitin nanofiber (ChNF) transparent laminated composite film (HCLaminate) made of siloxane hybrid materials (hybrimers) reinforced with ChNFs, which mimics the nanofiber-matrix structure of hierarchical biocomposites. Our HCLaminate is produced via vacuum bag compressing and subsequent UV-curing of the matrix resin-impregnated ChNF transparent paper (ChNF paper). It is worthwhile to note that this new type of ChNF-based transparent substrate film retains the strengths of the original ChNF paper and compensates for ChNF paper's drawbacks as a flexible transparent substrate. As a result, compared with high-performance synthetic plastic films, such as poly(ethylene terephthalate), poly(ether sulfone), poly(ethylene naphthalate), and polyimide, our HCLaminate is characterized to exhibit extremely smooth surface topography, outstanding optical clarity, high elastic modulus, high dimensional stability, etc. To prove our HCLaminate as a substrate film, we use it to fabricate flexible perovskite solar cells and a touch-screen panel. As far as we know, this work is the first to demonstrate flexible optoelectronics, such as flexible perovskite solar cells and a touch-screen panel, actually fabricated on a composite film made of ChNF. Given its desirable macroscopic properties, we envision our HCLaminate being utilized as a transparent substrate film for flexible green optoelectronics.

  5. Microwave Magnetic Properties of Laminates with Thin FeCoBSi Films

    Institute of Scientific and Technical Information of China (English)

    LU Haipeng; JIANG Yongjun; YANG Jing; DENG Longjiang

    2011-01-01

    The microwave permeability of laminated composites based on thin FeCoBSi films was unoer study.The level of permeability increased with increasing of the ferromagnetic inclusions in the laminates.The intrinsic permeability spectra of ferromagnetic inclusion are parametrically reconstructed.The obtained parameters of magnetic resonance were specially analyzed.To avoid the effect of eddy current and to obtain large-volume fractions of ferromagnetic constituent,laminates consisting of alternating FeCoBSi/SiO2 multilayers and mylar substrates were also investigated.For the same volume fractions of ferromagnetic constituent (8.7%),laminates based on multi-layered films are found to possess higher values of permeability than those based on one-layered films.

  6. In-situ lamination of starch-based baked foam articles with degradable films

    Science.gov (United States)

    A technique for making biodegradable food service packaging comprised of a starch/fiber core and a biodegradable film laminate is described. The biodegradable films were made of polylactic acid (PLA), polybutylenesuccinate/terephthalate (PBST), rubber latex and polybutyleneadipate/terephthalate (PB...

  7. Effect of oil lamination between plasticized starch layers on film properties.

    Science.gov (United States)

    Basiak, Ewelina; Debeaufort, Frédéric; Lenart, Andrzej

    2016-03-15

    To reduce the hygroscopic character of biodegradable starch-based films, rapeseed oil was incorporated by lamination (starch-oil-starch 3-layers technique). The lipid lamination followed by starch solution casting step induced an emulsion type structure of dried films. Composite films are more opalescent and glossier than fatty free starch films. For all the films, structure is heterogeneous in the cross-section only. Adding fat induced a twice decrease of the tensile strength. Thermal gravimetry analysis did not show differences between films with and without oil. Lipid reduced the moisture absorption particularly at higher RH as well as the surface swelling index, when water droplet contact occurred. Addition of lipids always decreases the contact angle for all liquid tested, except for water. Surface affinity of films for liquids less polar that water increased with rapeseed oil addition. The addition of rapeseed oil significantly reduces water vapour and oxygen permeability.

  8. Effects of lamination and coating with drying oils on tensile and barrier properties of zein films.

    Science.gov (United States)

    Rakotonirainy, A M; Padua, G W

    2001-06-01

    Zein films plasticized with oleic acid have been considered potentially useful for biodegradable packaging applications. However, moisture was found to affect their tensile and gas barrier properties. We investigated the effects of two converting processes, fusion lamination and coating with drying oils, on tensile properties and gas permeability of zein films. Zein films were laminated to 4-ply sheets in a Carver press and coated with tung oil, linseed oil, or a mixture of tung and soybean oils. Tensile properties and permeability to water vapor, oxygen, and carbon dioxide were measured according to ASTM methods. Laminated films were clearer, tougher, and more flexible, and had a smoother finish than nontreated sheets. Lamination decreased O(2) and CO(2) permeability by filling in voids and pinholes in the film structure. Coating increased tensile strength and elongation and decreased water vapor permeability. Coatings acted as a composite layer preventing crack propagation and increasing film strength. They also formed a highly hydrophobic surface that prevented film wetting.

  9. A laminate of ferromagnetic films with high effective permeability at high frequencies

    Directory of Open Access Journals (Sweden)

    I. T. Iakubov

    2014-10-01

    Full Text Available The paper reports on development of magnetodielectric material with high microwave permeability. The material is a laminate of multi-layer permalloy films deposited onto a thin mylar substrate by magnetron sputtering. The deposited films are arranged into a stack and glued together under pressure to obtain the laminate. With the content of ferromagnetic component in the laminate being 22 % vol., its measured quasistatic permeability is 60. The peak value of imaginary permeability attains 50 and the peak is located near 1 GHz. As compared with the multi-layer films, which the laminate is made of, it exhibits lower magnetic loss tangent at frequencies below the magnetic loss peak and may therefore be useful for many technical applications. Lower low-frequency loss may be attributed to pressing of the glued sample. This rectifies wrinkling appearing due to sputtering of rigid multi-layer film onto flexible mylar substrate and, therefore, makes the magnetic structure of the film more uniform.

  10. Natural rubber: leather composites

    OpenAIRE

    K. Ravichandran; N. Natchimuthu

    2005-01-01

    Leather is a fibrous protein consisting of collagen in a three dimensionally crosslinked network. Chrome tanning of leather improves the appearance of leather but at the same time emits both solid and liquid chrome leather wastes. Scrap rubber recycling using untreated and neutralized leather fibrous particles in natural rubber has been studied. Vulcanization, mechanical, morphological and swelling properties of the natural rubber - scrap rubber composites containing neutralized leather have ...

  11. Effect of Material Property of Interply Film on the Delamination in Laminated Composites 8

    Institute of Scientific and Technical Information of China (English)

    WeiFENG; QiaoHUANG

    1999-01-01

    The delamination is one of the main failure modes in laminated composites.In order to suppress and /or delay it,considerable research has been devoted to the reduction of the interlaminar stresses at the interfaces between two different plies.This paper studies the effect of isotropic layers placed at ply interface on the interlaminar behaviour of the angle-ply laminated composites.The results of the experiment and numerical analysis show that the material properties of interply film have strong influence on the interlaminar behaviour of laminated composites.In order to suppress delamination,the material of interply film has to been selected carefully due to the fact that different matrials have different results .SOme materials may increase the stress values at the interfaces.Some materials may reduce the stress concertration.

  12. Wood or Laminate?—Psychological Research of Customer Expectations

    National Research Council Canada - National Science Library

    Jiménez, Paul; Dunkl, Anita; Eibel, Kerstin; Denk, Elisabeth; Grote, Vincent; Kelz, Christina; Moser, Maximilian

    2016-01-01

    .... However, when investigating psychological differences, wood is usually compared to carpets, glass, leather, stone, or plastic but is not compared to a visually similar material such as laminate...

  13. Optimization of Multilayer Laminated Film and Absorbent of Vacuum Insulation Panel for Use at High Temperature

    Science.gov (United States)

    Araki, Kuninari; Echigoya, Wataru; Tsuruga, Toshimitsu; Kamoto, Daigorou; Matsuoka, Shin-Ichi

    For the energy saving regulation and larger capacity, Vacuum Insulation Panel (VIP) has been used in refrigerators with urethane foam in recent years. VIP for low temperature is constructed by laminated plastic film, using heat welding of each neighboring part for keeping vacuum, so that the performance decrement is very large under high temperature. But recently high efficiency insulation material is desired for high temperature water holding devices (automatic vending machine, heat pump water heater, electric hot-water pot water, etc.), and we especially focused on cost and ability of the laminated plastic film and absorbent for high temperature VIP. We measured the heatproof temperature of plastic films and checked the amount of water vapor and out coming gas on temperature-programmed adsorption in absorbent. These results suggest the suitable laminated film and absorbent system for VIP use at high temperature, and the long-term reliability was evaluated by measuring thermal conductivity of high temperature. As a result it was found that high-retort pouch of CPP (cast polypropylene film) and adding of aluminum coating are the most suitable materials for use in the welded layers of high-temperature VIPs (105°C).

  14. Efficiency loss of thin film Cu(InxGa1-x)Se(S) solar panels by lamination process

    Science.gov (United States)

    Xu, Li

    2017-04-01

    Efficiency loss of thin film Cu(InxGa1-x)Se(S) (CIGS) solar panels by lamination process has been compromising the final output power in commercial products of solar modules, but few reports have been published on such issue, as the majority of the investigation is focused on the efficiency at the circuit level, i.e., before lamination process. In this paper, we studied the effect of lamination process to the efficiency loss of thin film CIGS solar panels. It was observed that the fill factor degradation dominated the efficiency loss with the small change of Voc and Jsc. Experiments showed that neither the temperature nor the pressure, nor the two combined in the lamination process is the root cause of the efficiency loss; instead, the ethylene vinyl acetate (EVA) layer as the encapsulation material which directly contacts the solar cell devices was the major factor responsible for the efficiency loss. It was found that the gel content of the cured EVA film after lamination was highly correlated to the efficiency loss. The higher the gel content, the higher the efficiency loss. The mismatch of coefficient of thermal expansion between the EVA film and the CIGS thin film resulted in compressive stress in the device layer after lamination process. The compressive stress is speculated to affect the lattice defects, but need to be confirmed with the measurement of capacitance voltage (CV) and drive level capacitance profiling (DLCP). Three-day sun soak was then carried out and it was observed that the fill factor recovered significantly and so did the efficiency. Experiments also showed that there was no impact of chemical erosion on the front electrode of transparent conductive oxide (TCO) films by chemicals released from the EVA films during lamination.

  15. Strength of anisotropic wood and synthetic materials. [plywood, laminated wood plastics, glass fiber reinforced plastics, polymeric film, and natural wood

    Science.gov (United States)

    Ashkenazi, Y. K.

    1981-01-01

    The possibility of using general formulas for determining the strength of different anisotropic materials is considered, and theoretical formulas are applied and confirmed by results of tests on various nonmetallic materials. Data are cited on the strength of wood, plywood, laminated wood plastics, fiber glass-reinforced plastics and directed polymer films.

  16. Oxidation Resistance of Fe-13Cr Alloy with Micro-Laminated (ZrO2-Y2O3)/(Al2O3-Y2O3) Films

    Institute of Scientific and Technical Information of China (English)

    Yao Mingming; He Yedong; Wang Deren; Gao Wei

    2005-01-01

    The micro-laminated (ZrO2-Y2O3)/(Al2O3-Y2O3) composite films were prepared on the surface of Fe-13Cr alloy by an electrochemical process and a sintering process alternately. High-resolution field emission scanning electron microscopy (FE-SEM) was used to characterize the laminated films, indicating that the micro-laminated (ZrO2-Y2O3)/(Al2O3-Y2O3) films have nano-structures. SEM, EDS and mass gain measurement were adopted to study the oxidation resistance of films on Fe-13Cr alloy. It is proved that such micro-laminated films are more effective than ZrO2-Y2O3 or Al2O3-Y2O3 films to resist the oxidation of the alloy, and the oxidation resistance is increased with increasing layers in micro-laminated films. These beneficial effects can be contributed to the mechanism, by which such micro-laminated (ZrO2-Y2O3)/(Al2O3-Y2O3) composite film combines all the beneficial effects and overcomes all the disadvantages of both ZrO2-Y2O3 film and Al2O3-Y2O3 film during oxidation of alloy.

  17. Development of flexible plasmonic plastic sensor using nanograting textured laminating film

    Science.gov (United States)

    Kumari, Sudha; Mohapatra, Saswat; Moirangthem, Rakesh S.

    2017-02-01

    The work presented in this paper describes the development of a cost-effective, flexible plasmonic plastic sensor using gold-coated nanograting nanoimprinted on a laminating plastic. The fabrication of plasmonic plastic sensor involved the transfer of nanograting pattern from polydimethylsiloxane (PDMS) polymer stamp to laminating plastic via thermal nanoimprint lithography, and subsequent gold film deposition. Gold-coated nanograting sample acted as a plasmonic chip, which exhibited surface plasmon resonance (SPR) mode in reflectance spectra under the white light illumination. The theoretical calculation was performed to study and analyze the excited SPR mode on the plasmonic chip. Further, the bulk refractive index sensitivity was demonstrated with respect to changing surrounding dielectric medium giving a value about 800  ±  27 nm/RIU (refractive index unit). In addition, the surface binding sensitivity upon adsorption of bovine serum albumin protein on the sensor surface was approximately 4.605 nm/(ng/mm2).We believe that our proposed low-cost plastic based plasmonic sensing device could be a potential candidate for the label-free and high-throughput screening of biological molecules.

  18. Effects of laminating and co-firing conditions on the performance of anode-supported Ce0.8Sm0.201.9 film electrolyte

    Directory of Open Access Journals (Sweden)

    Li X.

    2011-01-01

    Full Text Available In order to evaluate the laminating and co-firing technique on the performance of anode-supported Ce0.8Sm0.2O1.9 (SDC film electrolyte and its single cell, NiO-YSZ and NiOSDC anode-supported SDC film electrolytes were fabricated by laminating 24 sheets of anode plus one sheet of electrolyte and co-firing. La0.4Sr0.6Co0.2Fe0.8O3-δ (LSCF-SDC cathode was coated on the SDC electrolytes to form a single cell. The lamination was tried at different laminating temperatures and pressures and the co-firing was carried out at different temperatures. The results showed that the laminating temperature should above the glass transition temperature (Tg of the binder. The laminating pressure of 70 MPa resulted in warp of the samples. The best co-firing temperature of the anode-supported SDC film electrolyte was 1400°C. The SDC film electrolyte formed well adherence to the anode. The NiO-YSZ anode had larger flexural strength than the NiO-SDC anode. The NiO-YSZ anode-supported SDC film electrolyte single cell had an open circuit voltage of 0.803 V and a maximum power density of 93.03 mW/cm2 with hydrogen as fuel at 800°C.

  19. Patulin in apple leather in Iran.

    Science.gov (United States)

    Montaseri, H; Eskandari, M H; Yeganeh, A T; Karami, S; Javidnia, K; Dehghanzadeh, G R; Mesbahi, G R; Niakousari, M

    2014-01-01

    Apple leather is made by dehydration of cooked fruit into leathery sheets. Mould growth and patulin production can occur in damaged apples or when fallen fruit is collected for apple leather processing. A survey was conducted to determine levels and dietary intake of patulin from apple leather marketed in Iran. Patulin was detected in all samples at concentrations ranging from leather.

  20. Realization of Al2O3/MgO laminated structure at low temperature for thin film encapsulation in organic light-emitting diodes.

    Science.gov (United States)

    Li, Min; Xu, Miao; Zou, Jianhua; Tao, Hong; Wang, Lei; Zhou, Zhongwei; Peng, Junbiao

    2016-12-09

    A laminated structure of Al2O3 and MgO deposited by atomic layer deposition (ALD) is used to realize a thin film encapsulation technology in organic light-emitting diodes (OLEDs). This film was targeted to achieve an excellent barrier performance. As the thickness of MgO layer increased from 0 nm to 20 nm, its physical properties transformed from the amorphous state into a crystalline state. The optimized cyclic ratio of ALD Al2O3 and MgO exhibited much lower water vapor transmission rate (WVTR) of 4.6 × 10(-6) gm(-2)/day evaluated by Calcium (Ca) corrosion at 60 °C&100% RH, owing to the formation of a terrific laminated structure. Top-emitting OLEDs encapsulated with laminated Al2O3/MgO show longer operating lifetime under rigorous environmental conditions. These improvements were attributed to the embedded MgO film that served as a modified layer to establish a laminated structure to obstruct gas permeation, as well as a scavenger to absorb water molecules, thus alleviating the hydrolysis of bulk Al2O3 material.

  1. The Degredation and Conservation of Leather

    OpenAIRE

    Vicki Dirksen

    1997-01-01

    This paper examines the tanning processes used in the manufacture of leather and the implications such processes have on the deterioration of aging leather. Improving the understanding of the processes used to create leather should result in a museum professional who is better able to address the conservation and care of leather artefacts. Present methods of leather conservation are examined with regard to the advantages and disadvantages of each method.

  2. Biodegradation of wet-white leather

    OpenAIRE

    Ollé Otero, Lluís; Jorba Rafart, Montse; Font Vallès, Joaquim; Shendrik, Alexander; Bacardit Dalmases, Anna

    2011-01-01

    This paper deals with the study of the physical, chemical and biological processes associated with the deterioration of wet-white leather. The samples of leather were exposed for eight months to outdoor weathering and then their properties were subsequently evaluated. The results indicate that resistance and dimensional stability of wet-white (THPS-syntan) leather is higher than that of chrometanned leather. The comparative work with chrome leather was described earlier.

  3. Development of chitosan-based antimicrobial leather coatings.

    Science.gov (United States)

    Fernandes, Isabel P; Amaral, Joana S; Pinto, Vera; Ferreira, Maria José; Barreiro, Maria Filomena

    2013-10-15

    The development of antimicrobial coatings for footwear components is of great interest both from industry and consumer's point of view. In this work, antimicrobial leather materials were developed taking advantage of chitosan intrinsic antimicrobial activity and film forming capacity. Considering the specificities of the leather tanning industry, different coating technologies, namely drum, calender and spray, were tested, being the best results achieved with the drum. This last approach was further investigated to assess the effect of chitosan content, type of solubilizing acid, and impregnation time on the achieved antimicrobial capacity. Considering chitosan price (economic reasons) and the obtained results (antimicrobial activity and coating effectiveness, as inspected by SEM), the impregnation in the drum using a chitosan content of 1% (w/v) in a formic acid solution during 2h, is proposed as the best option for obtaining leather with antimicrobial capacity.

  4. A magnetic atomic laminate from thin film synthesis: (Mo{sub 0.5}Mn{sub 0.5}){sub 2}GaC

    Energy Technology Data Exchange (ETDEWEB)

    Meshkian, R., E-mail: rahele.meshkian@liu.se; Ingason, A. S.; Lu, J.; Rosen, J. [Department of Physics, Chemistry, and Biology (IFM), Linköping University, SE-581 83 Linköping (Sweden); Arnalds, U. B. [Science Institute, University of Iceland, IS-107 Reykjavik (Iceland); Magnus, F. [Department of Physics and Astronomy, Uppsala University, Box 516, SE-516 Uppsala (Sweden)

    2015-07-01

    We present synthesis and characterization of a new magnetic atomic laminate: (Mo{sub 0.5}Mn{sub 0.5}){sub 2}GaC. High quality crystalline films were synthesized on MgO(111) substrates at a temperature of ∼530 °C. The films display a magnetic response, evaluated by vibrating sample magnetometry, in a temperature range 3-300 K and in a field up to 5 T. The response ranges from ferromagnetic to paramagnetic with change in temperature, with an acquired 5T-moment and remanent moment at 3 K of 0.66 and 0.35 μ{sub B} per metal atom (Mo and Mn), respectively. The remanent moment and the coercive field (0.06 T) exceed all values reported to date for the family of magnetic laminates based on so called MAX phases.

  5. Numerical solution for 5-layer laminate technique to determine saturation solubility of a drug in a thin film of pressure sensitive adhesive.

    Science.gov (United States)

    Bänsch, Eberhard; Reismann, Simone; Lee, Geoffrey

    2014-08-01

    A numerical solution of the one-dimensional diffusion equation is presented to describe the 5-layer laminate technique for estimating the saturation solubility of a drug in a thin polymer film. The boundary and initial conditions encompass a donor layer, a separating membrane, and an acceptor layer. Alteration of the drug's partition coefficient between donor and separating membrane has little influence on drug accumulation with the acceptor. The diffusivity in the separating membrane should be high to promote a short experimental time to achieve saturation equilibrium in the acceptor layer. The essential parameter to give rapid equilibrium is the thickness of the acceptor polymer film. For values of diffusivity typical for drugs of molecular weight around 500 an acceptor layer thickness of 10 µm-20 µm is required to achieve equilibrium within less than 10 d. These simulations allow the selection of suitable experimental conditions to make the 5-layer laminate technique a viable method for routine use.

  6. Penelitian kulit belahan (split leather untuk barang kulit atau atasan sepatu

    Directory of Open Access Journals (Sweden)

    Susilowati Susilowati

    1992-12-01

    Full Text Available The purpose of this research is to find upper leather from splitted leather with proportional ratio of impregnating agent. The raw material used were split hide, and subjected to combination tanning process, consisted of chrome, synthetic and extract mimosa tanning agent, to get crust leather, and than were impregnated with the ratio of film forming with penetrator agent and finally they were finished with top all of the treatments fulfill/conform the requirements of SII 0018-79. There is significance difference in physical testing results.

  7. Characterization and antimicrobial performance of nano silver coatings on leather materials

    OpenAIRE

    N. Lkhagvajav; Koizhaiganova,M.; Yasa, I.; Çelik, E.; Ö. Sari

    2015-01-01

    In this study, the characterization and the antimicrobial properties of nano silver (nAg) coating on leather were investigated. For this purpose, turbidity, viscosity and pH of nAg solutions prepared by the sol-gel method were measured. The formation of films from these solutions was characterized according to temperature by Differential Thermal Analysis-Thermogravimetry (DTA-TG) equipment. The surface morphology of treated leathers was observed using Scanning Electron Microscopy (SEM). The a...

  8. Characterization and antimicrobial performance of nano silver coatings on leather materials.

    Science.gov (United States)

    Lkhagvajav, N; Koizhaiganova, M; Yasa, I; Çelik, E; Sari, Ö

    2015-03-01

    In this study, the characterization and the antimicrobial properties of nano silver (nAg) coating on leather were investigated. For this purpose, turbidity, viscosity and pH of nAg solutions prepared by the sol-gel method were measured. The formation of films from these solutions was characterized according to temperature by Differential Thermal Analysis-Thermogravimetry (DTA-TG) equipment. The surface morphology of treated leathers was observed using Scanning Electron Microscopy (SEM). The antimicrobial performance of nAg coatings on leather materials to the test microorganisms as Escherichia coli , Staphylococcus aureus , Candida albicans and Aspergillius niger was evaluated by the application of qualitative (Agar overlay method) and quantitative (percentage of microbial reduction) tests. According to qualitative test results it was found that 20 μg/cm (2) and higher concentrations of nAg on the leather samples were effective against all microorganisms tested. Moreover, quantitative test results showed that leather samples treated with 20 μg/cm (2) of nAg demonstrated the highest antibacterial activity against E. coli with 99.25% bacterium removal, whereas a 10 μg/cm (2) concentration of nAg on leather was enough to exhibit the excellent percentage reduction against S. aureus of 99.91%. The results are promising for the use of colloidal nano silver solution on lining leather as antimicrobial coating.

  9. Characterization and antimicrobial performance of nano silver coatings on leather materials

    Directory of Open Access Journals (Sweden)

    N. Lkhagvajav

    2015-03-01

    Full Text Available In this study, the characterization and the antimicrobial properties of nano silver (nAg coating on leather were investigated. For this purpose, turbidity, viscosity and pH of nAg solutions prepared by the sol-gel method were measured. The formation of films from these solutions was characterized according to temperature by Differential Thermal Analysis-Thermogravimetry (DTA-TG equipment. The surface morphology of treated leathers was observed using Scanning Electron Microscopy (SEM. The antimicrobial performance of nAg coatings on leather materials to the test microorganisms as Escherichia coli, Staphylococcus aureus, Candida albicans and Aspergillius niger was evaluated by the application of qualitative (Agar overlay method and quantitative (percentage of microbial reduction tests. According to qualitative test results it was found that 20 μg/cm2 and higher concentrations of nAg on the leather samples were effective against all microorganisms tested. Moreover, quantitative test results showed that leather samples treated with 20 μg/cm2 of nAg demonstrated the highest antibacterial activity against E. coli with 99.25% bacterium removal, whereas a 10 μg/cm2 concentration of nAg on leather was enough to exhibit the excellent percentage reduction against S. aureus of 99.91%. The results are promising for the use of colloidal nano silver solution on lining leather as antimicrobial coating.

  10. Leather: an important material for defence

    Directory of Open Access Journals (Sweden)

    B. M. Das

    1954-07-01

    Full Text Available Many articles made of leather are required by the Armed Forces, the most important being army boots and sadlery. The kinds of leather needed for making them are the heavy leathers, viz., sole and harness and medium substance leather for army footwear uppers. The best available heavy buffalo and cow hides must be used, the former for making sole and harness and the latter for army footwear uppers. The techniques of manufacturing these leathers must also be of the highest possible order and the processes should be scientifically controlled.

  11. LEGISLATIVE ASPECTS CONCERNING THE LEATHER WASTES

    Directory of Open Access Journals (Sweden)

    TIMOFTE Claudia Simona

    2017-05-01

    Full Text Available This paper underlines the current legislation and compliance issues leather waste in different waste groups according to relevant legislation and shows that, although seemingly harmless waste of skin sometimes contain dangerous compounds. As presented risks to human health were some restricted substances in leather. Since 2001 Romania had preoccupation in national legislation on waste management, but some categories, such as leather waste are not framed to this category. Also, another goal is implementing the EU management/storage strategy of industrial waste. Unfortunately, Romania imports huge quantities of used clothing and shoes. Transport, storage and use of them are poor, and many of these are subsequently stored waste by the fact that it is even sometimes improperly discarded. The paper also shows the statistics on waste management in the Bihor County by activity of national economy and by activity of industry at level of CANE REV.2 Section. Analyzing the postings on Internet regarding the sale and purchase of leather wastes in Romania, it was found that there are the following 'categories' of wastes: leather goods, leather from coats, leather from footwear industry, suede, leather, leather resulting from the production of upholstery. It was found that most car buyers use waste leather upholstery. It is recommended that production companies to highlight more transparent their inventory textile and leather waste on types for those interested (including online can access/capitalize them.

  12. Thermal conductivity of graphene laminate.

    Science.gov (United States)

    Malekpour, H; Chang, K-H; Chen, J-C; Lu, C-Y; Nika, D L; Novoselov, K S; Balandin, A A

    2014-09-10

    We have investigated thermal conductivity of graphene laminate films deposited on polyethylene terephthalate substrates. Two types of graphene laminate were studied, as deposited and compressed, in order to determine the physical parameters affecting the heat conduction the most. The measurements were performed using the optothermal Raman technique and a set of suspended samples with the graphene laminate thickness from 9 to 44 μm. The thermal conductivity of graphene laminate was found to be in the range from 40 to 90 W/mK at room temperature. It was found unexpectedly that the average size and the alignment of graphene flakes are more important parameters defining the heat conduction than the mass density of the graphene laminate. The thermal conductivity scales up linearly with the average graphene flake size in both uncompressed and compressed laminates. The compressed laminates have higher thermal conductivity for the same average flake size owing to better flake alignment. Coating plastic materials with thin graphene laminate films that have up to 600× higher thermal conductivity than plastics may have important practical implications.

  13. Investigation of structure-dielectric property relationships in zirconium oxide, tantalum pentoxide, and oxide-polymer laminate films for high energy density capacitor applications

    Science.gov (United States)

    Sethi, Guneet

    Pulsed power applications involve transformation of electrical energy into high-peak power pulses through capacitors. There is an immediate need for fast-response capacitors with decreased volume, weight, and cost for pulsed power applications and power distribution systems. This research challenge is dominated by energy density. Energy density is directly related to dielectric properties such as dielectric polarization, conductivity and breakdown strength of the capacitor dielectric. This research work correlates processing and microstructure of single and multiple component dielectric films with their dielectric properties. The inorganic materials studied in this dissertation include zirconium oxide (ZrO2) and tantalum pentoxide (Ta 2O5) reactive sputtered films. Film crystallization & structure was studied as a function of sputtering growth variables such as sputtering power, sputtering pressure, source frequency, oxygen pressure, substrate temperature, substrate material, and post-deposition annealing temperature. Polycrystalline phase of ZrO2 and amorphous phase of Ta2O 5 were obtained for most sputtering growth variables. Although the amorphous films have lower permittivity (32 for amorphous & 51 for polycrystalline at 1 kHz), they also have lower AC and DC conductivities (3.4x10-8 S/m for amorphous & 12.2x10 -8 S/m for polycrystalline at 1 kHz), which result in high breakdown strength than polycrystalline films. Amorphous Ta2O5 films are found to be ideal for high-energy density capacitors with energy density of 14 J/cm3 because of their high permittivity, low leakage current density, and high dielectric breakdown strength. Oxide films were combined with different polymers (polyvinyldene flouride-triflouroethylene, polypropylene and polyethylene terephthalate) to produce two different kinds of laminate composites---oxide on polymer and polymer on oxide. Permittivity and conductivity differences in the polymer and oxide films result in an impedance contrast

  14. Thermal Properties of Anionic Polyurethane Composition for Leather Finishing

    Directory of Open Access Journals (Sweden)

    Olga KOVTUNENKO

    2016-09-01

    Full Text Available Thermal properties of anionic polyurethane composition mixed with collagen product and hydrophilic sodium form of montmorillonite for use in the finishing of leather were studied by thermogravimetric method. The thermal indices of processes of thermal and thermo-oxidative destruction depending on the polyurethane composition were determined. The influence of anionic polyurethane composition on thermal behavior of chromium tanned gelatin films that imitate the leather were studied. APU composition with natural compounds increases their thermal stability both in air and in nitrogen atmosphere due to the formation of additional bonds between active groups of APU, protein and chrome tanning agent as the result of chemical reactions between organic and inorganic parts with the new structure formation.DOI: http://dx.doi.org/10.5755/j01.ms.22.3.10043

  15. Thermal Properties of Anionic Polyurethane Composition for Leather Finishing

    Directory of Open Access Journals (Sweden)

    Olga KOVTUNENKO

    2016-09-01

    Full Text Available Thermal properties of anionic polyurethane composition mixed with collagen product and hydrophilic sodium form of montmorillonite for use in the finishing of leather were studied by thermogravimetric method. The thermal indices of processes of thermal and thermo-oxidative destruction depending on the polyurethane composition were determined. The influence of anionic polyurethane composition on thermal behavior of chromium tanned gelatin films that imitate the leather were studied. APU composition with natural compounds increases their thermal stability both in air and in nitrogen atmosphere due to the formation of additional bonds between active groups of APU, protein and chrome tanning agent as the result of chemical reactions between organic and inorganic parts with the new structure formation.DOI: http://dx.doi.org/10.5755/j01.ms.22.3.10043

  16. Biodegradation of Leather Waste by Enzymatic Treatment

    Institute of Scientific and Technical Information of China (English)

    2006-01-01

    The treatment of shavings, trimmings and splits of leather waste from tanneries has a potential to generate value-added products. In this study enzymatic treatment of leather waste was performed. This method utilizes alkaline protease produced by Bacillus subtilis in our laboratory by submerged fermentation. Optimum conditions of pH, time duration,temperature and concentration of enzyme were determined for maximum degradation of leather waste. The amount of degradation was measured by the release of amino acid hydroxyproline. Amino acid composition in the hydrolysate obtained by the enzyme hydrolysis was determined. This relative simple biotreatment of leather waste may provide a practical and economical solution.

  17. Characteristics of Al{sub 2}O{sub 3}/ZrO{sub 2} laminated films deposited by ozone-based atomic layer deposition for organic device encapsulation

    Energy Technology Data Exchange (ETDEWEB)

    Oh, Juhong; Shin, Seokyoon [Division of Materials Science and Engineering, Hanyang University, Seoul (Korea, Republic of); Park, Joohyun [Department of Nano-scale Semiconductor Engineering, Hanyang University, Seoul (Korea, Republic of); Ham, Giyul [Division of Materials Science and Engineering, Hanyang University, Seoul (Korea, Republic of); Jeon, Hyeongtag, E-mail: hjeon@hanyang.ac.kr [Division of Materials Science and Engineering, Hanyang University, Seoul (Korea, Republic of)

    2016-01-29

    We investigated the characteristics of 100 nm-thick Al{sub 2}O{sub 3}/ZrO{sub 2} laminated films grown by ozone (O{sub 3})-based atomic layer deposition (ALD) at low temperature (100 °C) as thin film encapsulation (TFE). Calcium (Ca) test was performed at a relative humidity (RH) of 50% with a temperature of 50 °C to derive the water vapor transmission rates (WVTRs) of aluminum oxide (Al{sub 2}O{sub 3})-, zirconium oxide (ZrO{sub 2})-, and Al{sub 2}O{sub 3}/ZrO{sub 2}-laminated films. Al{sub 2}O{sub 3}/ZrO{sub 2}-laminated films exhibited better permeation barrier properties than Al{sub 2}O{sub 3} or ZrO{sub 2} single layer films. In Al{sub 2}O{sub 3}/ZrO{sub 2} laminated films, permeation barrier properties improved as the number of alternating layers increased. Permeation barrier properties were closely related to the number of interfaces because of the ZrAl{sub x}O{sub y} phase that formed at the interface between the Al{sub 2}O{sub 3} and ZrO{sub 2} sublayers. The ZrAl{sub x}O{sub y} phase was denser than single layers of Al{sub 2}O{sub 3} and ZrO{sub 2} and had a homogeneous amorphous structure. The formation of a ZrAl{sub x}O{sub y} phase in Al{sub 2}O{sub 3}/ZrO{sub 2} laminated film effectively improved the permeation barrier properties of the film. - Highlights: • All films were deposited by ozone-based atomic layer deposition at 100 °C. • Al{sub 2}O{sub 3}/ZrO{sub 2}-laminated films showed better barrier properties than single films. • ZrAl{sub x}O{sub y} phase formed at the interface between Al{sub 2}O{sub 3} and ZrO{sub 2} sublayers. • The number of alternating layers of Al{sub 2}O{sub 3} and ZrO{sub 2} affected film properties.

  18. 图形转移制程中贴膜的干膜结合力分析与改善%Dry film combination analysis and improvement in the film lamination process of the image transition

    Institute of Scientific and Technical Information of China (English)

    黄立球; 张利华

    2013-01-01

    This thesis analyzed the film lamination process, and concluded the theoretical basis for the dry film combination. On the basis of the manufactruring status, the theortic of the dry film combination raising up was sumarized and how to increase the combination was also concluded. The theoretic was verified by the experiments and which then be prooofed correct .This thesis provided the theoretical base for the yield improcement and cost reducement by increase the combination of the dry film. The thesis can be a guide for the lamination process of the PCB industry and the lamination process improcement.%  文章先分析了图形转移中贴膜过程受力并从中总结出干膜结合力产生的理论基础,又从工艺上分析总结出提升合适干膜结合力的理论,接着从工艺流程上分析总结出如何实现提升合适干膜结合力的机理,再用实验验证了提升合适干膜结合力机理的正确性;通过提升合适干膜结合力,为PCB板制造过程提高板件良率和降低报废成本提供了控制的理论依据;本理论能指导PCB行业贴膜制作流程和提高贴膜制造技术。

  19. EXAMINING COMFORT PROPERTIES OF LEATHER and ARTIFICIAL LEATHER COVER MATERIALS

    Directory of Open Access Journals (Sweden)

    ÇETİN Münire Sibel

    2016-05-01

    Full Text Available The analysis and regulation of workplace, working instruments, the comfort of office chair, business environment (sound, lighting, climate, vibration, temperature, and humidity, work and break times, analysis and editing of the organization, are some of the topics of interest of ergonomics. Environmental impact and conditions have important role on the employee’s working comfortably and efficiently. Therefore these conditions need to be aligned to the human body nature. Unsuitable working conditions (noise, etc. cause additional load, which the human body endures, and this additional load reveals the signs of tiredness in the body. Even an office environment, unsuitable physical environment impairs health of workers and reduces the performance. Therefore, office climate, environmental factors such as lighting and noise must be harmonized with the employee’s body nature in all working environments. Seating comfort is one of the important factors affecting the performance of employees in the office environment. There are so many studies about chair dimensions and the disorders on human body which were caused by the inappropriate chair dimensions and sitting positions. However, there are a spot of studies about the surface of the chair and the discomfort caused by the chair cover and its negative performance effects. In this study, some results of seat cover analysis for the design of an ergonomic chair. Recently, ease of cleaning, low cost advantages caused the increasing of the use of artificial leather especially on the surface of the seat used in offices. The physical properties of natural leather and artificial leather were compared as the candidate covers to be used on the design of an ergonomic office chair.

  20. Collagen fibril diameter and leather strength.

    Science.gov (United States)

    Wells, Hannah C; Edmonds, Richard L; Kirby, Nigel; Hawley, Adrian; Mudie, Stephen T; Haverkamp, Richard G

    2013-11-27

    The main structural component of leather and skin is type I collagen in the form of strong fibrils. Strength is an important property of leather, and the way in which collagen contributes to the strength is not fully understood. Synchrotron-based small angle X-ray scattering (SAXS) is used to measure the collagen fibril diameter of leather from a range of animals, including sheep and cattle, that had a range of tear strengths. SAXS data were fit to a cylinder model. The collagen fibril diameter and tear strength were found to be correlated in bovine leather (r(2) = 0.59; P = 0.009), with stronger leather having thicker fibrils. There was no correlation between orientation index, i.e., fibril alignment, and fibril diameter for this data set. Ovine leather showed no correlation between tear strength and fibril diameter, nor was there a correlation across a selection of other animal leathers. The findings presented here suggest that there may be a different structural motif in skin compared with tendon, particularly ovine skin or leather, in which the diameter of the individual fibrils contributes less to strength than fibril alignment does.

  1. Research into the Properties of Leather.

    Science.gov (United States)

    Glenn, G. W.

    1982-01-01

    Describes experiments on properties of leather performed by a science teacher, assisted by senior science students. Concludes that the finish layer contributes a major part of the resistance to air passage, reducing permeability of leather. Flexing increases permeability and may, in its action, discriminate between finishes. (Author/JN)

  2. Biodegradability of leathers through anaerobic pathway.

    Science.gov (United States)

    Dhayalan, K; Fathima, N Nishad; Gnanamani, A; Rao, J Raghava; Nair, B Unni; Ramasami, T

    2007-01-01

    Leather processing generates huge amounts of both solid and liquid wastes. The management of solid wastes, especially tanned leather waste, is a challenging problem faced by tanners. Hence, studies on biodegradability of leather become imperative. In this present work, biodegradability of untanned, chrome tanned and vegetable tanned leather under anaerobic conditions has been addressed. Two different sources of anaerobes have been used for this purpose. The effect of detanning as a pretreatment method before subjecting the leather to biodegradation has also been studied. It has been found that vegetable tanned leather leads to more gas production than chrome tanned leather. Mixed anaerobic isolates when employed as an inoculum are able to degrade the soluble organics of vegetable tanned material and thus exhibit an increased level of gas production during the initial days, compared to the results of the treatments that received the anaerobic sludge. With chrome tanned materials, there was not much change in the volume of the gas produced from the two different sources. It has been found that detanning tends to improve the biodegradability of both types of leathers.

  3. Assessment of a five-layer laminate technique to measure the saturation solubility of drug in pressure-sensitive adhesive film.

    Science.gov (United States)

    Reismann, Simone; Lee, Geoffrey

    2012-07-01

    A five-layer laminate technique is used to determine the saturation solubility of a drug in a thin polymer film, c(p)(s), of pressure-sensitive adhesive (PSA) used to prepare transdermal patches. A drug-loaded donor polymer film is attached via a separating membrane to an initially drug-free acceptor polymer film. Diffusion of drug occurs into the acceptor up to saturation solubility equilibrium. This systematic study of the technique using the drug tamsulosin and the PSA Duro Tak 87-4098 was a kinetic analysis of the diffusion process. It was found that the technique gives an equilibrium value for c(p)(s) in a PSA polymer film in the presence of crystalline phase of the drug in the donor. A highly permeable Perthese-separating membrane caused overshoot in the acceptor, most likely induced by initial supersaturation of the donor. Change to a less-permeable ethylene-vinyl-acetate-separating membrane avoided overshoot, but gave a prolonged time, >300 days, to equilibrium. Preloading the acceptor accelerated the equilibration process to approximately 50 days with the Perthese. Suitable experimental conditions are identified that, if performed correctly, allow the technique to give an equilibrium value for c(p)(s).

  4. Impregnation of leather during "freeze-drying"

    DEFF Research Database (Denmark)

    Storch, Mikkel; Vestergaard Poulsen Sommer, Dorte; Hovmand, Ida

    2016-01-01

    Freeze-drying is a recognized method for the preservation of waterlogged objects. Naturally, freeze-drying has also been used for waterlogged archaeological leather often after treatment with Na2.EDTA and impregnation with PEG; but the treated leather sometimes suffers from “excessive drying......” becoming too stiff and brittle. The aim of this study was to examine the effect of a conventional freeze-drying method against an alternative freeze-drying method that preserves the natural moisture content of the leather. Both new and archaeological waterlogged leather were included in the study...... suggest that the process which takes place within the leather during the freeze-drying in not actual freeze-drying, but rather a sophisticated way of distributing the impregnating agent. The pure ice phase freezes out, but the impregnating agent remains liquid as the temperature does not become low enough...

  5. Manufacturing Of Novelty Leather From Cattle Stomach

    Directory of Open Access Journals (Sweden)

    Umme Habiba Bodrun Naher

    2015-08-01

    Full Text Available Abstract The objective of this study was to investigate the feasibility of turning cattle stomach into novelty leather and then leather product which would add value to end of cattle. Four pieces of green buffalo stomachs were taken through soaking liming deliming pickling tanning neutralization retanning dyeing and fat liquoring operation. Then mechanical operations like drying and staking operations were also done. Some physical tensile strength stitch tear strength and colour rub fastness and chemical chromic oxide content fat content and pH tests were accomplished .The results of physical tests were poor compared to the grain leather as the composition of raw outer coverings of animals and their stomachs are different. The stomach leathers could be used for making coin purse key case bracelet wrist watch belt ear-ring necklace hair band iPod case etc. as novelty leather product item.

  6. 21 CFR 573.540 - Hydrolyzed leather meal.

    Science.gov (United States)

    2010-04-01

    ... 21 Food and Drugs 6 2010-04-01 2010-04-01 false Hydrolyzed leather meal. 573.540 Section 573.540... Additive Listing § 573.540 Hydrolyzed leather meal. (a) Identity. Hydrolyzed leather meal is produced from leather scraps that are treated with steam for not less than 33 minutes at a pressure of not less than...

  7. Relative humidity effects on the surface electrical properties of resistive plate chamber melaminic laminates uncoated and coated with polymerized linseed oil film

    Science.gov (United States)

    Bearzotti, Andrea; Palummo, Lucrezia

    2007-09-01

    Relative humidity is an important quantity to control in many manufacturing environments such as semiconductor industry. Humidity and moisture can affect many electronic devices, generally rendering their operation worse. In this study we present results showing that in some specific applications, humidity can improve the performance of an electronic device. Resistive plate chambers are used as trigger detectors of the muon system in LHC (large hadron collider) experiments ATLAS (a toroidal LHC apparatus), CMS (compact muon solenoid) and ALICE (a large ion collider experiment) and as detector in cosmic rays experiment ARGO (astrophysical radiation with ground-based observatory). These detectors are made of phenolic-melaminic laminate electrodes, coated with a polymerized linseed oil film delimiting the gaseous sensitive volume. The loss of some of the detector capability can be progressive in time and due to the intrinsic limits of the detector materials. One of these effects is due to an increase of the total plate resistance, that is correlated to ion migration and relativity humidity phenomena. Our purpose is to understand the relative humidity (RH) influence on the conduction mechanisms on the electrodes surface. Results of amperometric measurements on laminate samples kept at a fixed temperature of 22°C, cycling RH between 10% and 90% are here presented.

  8. Compatibilized blends and value added products from leather industry waste

    Science.gov (United States)

    Sartore, Luciana; Di Landro, Luca

    2014-05-01

    Blends based on poly(ethylene-co-vinyl acetate) (EVA) and hydrolyzed proteins (IP), derived from waste products of the leather industry, have been obtained by reactive blending and their chemical physical properties as well as mechanical and rheological behavior were evaluated. The effect of vinyl acetate content and of transesterification agent addition to increase interaction between polymer and bio-based components were considered. These blends represent a new type of biodegradable material and resulted promising for industrial application in several fields such as packaging and agriculture as transplanting or mulching films with additional fertilizing action of IP.

  9. Flexible Lamination-Fabricated Ultra-High Frequency Diodes Based on Self-Supporting Semiconducting Composite Film of Silicon Micro-Particles and Nano-Fibrillated Cellulose

    Science.gov (United States)

    Sani, Negar; Wang, Xin; Granberg, Hjalmar; Andersson Ersman, Peter; Crispin, Xavier; Dyreklev, Peter; Engquist, Isak; Gustafsson, Göran; Berggren, Magnus

    2016-06-01

    Low cost and flexible devices such as wearable electronics, e-labels and distributed sensors will make the future “internet of things” viable. To power and communicate with such systems, high frequency rectifiers are crucial components. We present a simple method to manufacture flexible diodes, operating at GHz frequencies, based on self-adhesive composite films of silicon micro-particles (Si-μPs) and glycerol dispersed in nanofibrillated cellulose (NFC). NFC, Si-μPs and glycerol are mixed in a water suspension, forming a self-supporting nanocellulose-silicon composite film after drying. This film is cut and laminated between a flexible pre-patterned Al bottom electrode and a conductive Ni-coated carbon tape top contact. A Schottky junction is established between the Al electrode and the Si-μPs. The resulting flexible diodes show current levels on the order of mA for an area of 2 mm2, a current rectification ratio up to 4 × 103 between 1 and 2 V bias and a cut-off frequency of 1.8 GHz. Energy harvesting experiments have been demonstrated using resistors as the load at 900 MHz and 1.8 GHz. The diode stack can be delaminated away from the Al electrode and then later on be transferred and reconfigured to another substrate. This provides us with reconfigurable GHz-operating diode circuits.

  10. Flexible Lamination-Fabricated Ultra-High Frequency Diodes Based on Self-Supporting Semiconducting Composite Film of Silicon Micro-Particles and Nano-Fibrillated Cellulose.

    Science.gov (United States)

    Sani, Negar; Wang, Xin; Granberg, Hjalmar; Andersson Ersman, Peter; Crispin, Xavier; Dyreklev, Peter; Engquist, Isak; Gustafsson, Göran; Berggren, Magnus

    2016-01-01

    Low cost and flexible devices such as wearable electronics, e-labels and distributed sensors will make the future "internet of things" viable. To power and communicate with such systems, high frequency rectifiers are crucial components. We present a simple method to manufacture flexible diodes, operating at GHz frequencies, based on self-adhesive composite films of silicon micro-particles (Si-μPs) and glycerol dispersed in nanofibrillated cellulose (NFC). NFC, Si-μPs and glycerol are mixed in a water suspension, forming a self-supporting nanocellulose-silicon composite film after drying. This film is cut and laminated between a flexible pre-patterned Al bottom electrode and a conductive Ni-coated carbon tape top contact. A Schottky junction is established between the Al electrode and the Si-μPs. The resulting flexible diodes show current levels on the order of mA for an area of 2 mm(2), a current rectification ratio up to 4 × 10(3) between 1 and 2 V bias and a cut-off frequency of 1.8 GHz. Energy harvesting experiments have been demonstrated using resistors as the load at 900 MHz and 1.8 GHz. The diode stack can be delaminated away from the Al electrode and then later on be transferred and reconfigured to another substrate. This provides us with reconfigurable GHz-operating diode circuits.

  11. Analysis of theoretical premises for biodeterioration of leather materials and leather products

    OpenAIRE

    Козарь, Оксана Петрівна; Гречаник, Юлія Володимирівна; Петрус, Борис Борисович; Возняк, Богуслав

    2016-01-01

    The process of prodicing leather materials and products with predictable antimicrobial properties require science-based approach to finding new ways to protect materials during their production. Creating biocidal compounds for leather materials based on environmentally friendly natural minerals is actual scientific and practical problems.Mechanism of the influence of chemical composition, structure and leather production technology on microbiological stability of the finished product in this ...

  12. Reclamation treatment of the chrome leather scrap

    Institute of Scientific and Technical Information of China (English)

    2000-01-01

    A novel method to extract protein and Cr(III) from the chrome leather scrap discarded by leather industry is described.Chrome leather scarp was hydrolyzed under basic condition to remove chromium compound and extract protein. The extracted protein was mixed with substrate and used as feed protein after being dried and ground. The basic residue was treated with sulfuric acid to obtain chrome(III) sulfate which can be used as tanning agent again after adjusting pH with base. The acidic residue was processed and used as flower fertilizer. The safety of the protein powder produced has been by toxicology and nutriology test. This reclamation method has been industrialized.

  13. High performance flexible metal oxide/silver nanowire based transparent conductive films by a scalable lamination-assisted solution method

    Directory of Open Access Journals (Sweden)

    Hua Yu

    2017-03-01

    Full Text Available Flexible MoO3/silver nanowire (AgNW/MoO3/TiO2/Epoxy electrodes with comparable performance to ITO were fabricated by a scalable solution-processed method with lamination assistance for transparent and conductive applications. Silver nanoparticle-based electrodes were also prepared for comparison. Using a simple spin-coating and lamination-assisted planarization method, a full solution-based approach allows preparation of AgNW-based composite electrodes at temperatures as low as 140 °C. The resulting flexible AgNW-based electrodes exhibit higher transmittance of 82% at 550 nm and lower sheet resistance about 12–15 Ω sq−1, in comparison with the values of 68% and 22–25 Ω sq−1 separately for AgNP based electrodes. Scanning electron microscopy (SEM and Atomic force microscopy (AFM reveals that the multi-stacked metal-oxide layers embedded with the AgNWs possess lower surface roughness (<15 nm. The AgNW/MoO3 composite network could enhance the charge transport and collection efficiency by broadening the lateral conduction range due to the built of an efficient charge transport network with long-sized nanowire. In consideration of the manufacturing cost, the lamination-assisted solution-processed method is cost-effective and scalable, which is desire for large-area fabrication. While in view of the materials cost and comparable performance, this AgNW-based transparent and conductive electrodes is potential as an alternative to ITO for various optoelectronic applications.

  14. ATR FTIR Mapping of Leather Fiber Panels

    Science.gov (United States)

    Tondi, G.; Grünewald, T.; Petutschnigg, A.; Schnabel, T.

    2015-01-01

    Leather fiber panels are very promising materials for many applications, not only for the easy availability of the constituents but also for their outstanding fi re-retardant properties. These innovative composite panels can be an excellent material for building insulation, and in recent times, the interest of industries in this composite board has considerably arisen. For this reason the discrimination of the components in the leather fiber panels is becoming fundamental in order to ensure their homogeneous properties. A method to characterize the surface of these materials is then required. An ATR FTIR mapping system for the leather fiber panels has been performed with a Perkin-Elmer microscope coupled with a Frontier FTIR spectrometer. The system has successfully allowed transforming the optical image to a chemical one. This technique can be considered as a right tool for routine controls of the surface quality, especially when the leather shavings cannot be optically distinguished.

  15. Wettability of graphene-laminated micropillar structures

    Science.gov (United States)

    Bong, Jihye; Seo, Keumyoung; Park, Ji-Hoon; Ahn, Joung Real; Ju, Sanghyun

    2014-12-01

    The wetting control of graphene is of great interest for electronic, mechanical, architectural, and bionic applications. In this study, the wettability of graphene-laminated micropillar structures was manipulated by changing the height of graphene-laminated structures and employing the trichlorosilane (HDF-S)-based self-assembly monolayer. Graphene-laminated micropillar structures with HDF-S exhibited higher hydrophobicity (contact angle of 129.5°) than pristine graphene thin film (78.8°), pristine graphene-laminated micropillar structures (97.5°), and HDF-S self-assembled graphene thin film (98.5°). Wetting states of the graphene-laminated micropillar structure with HDF-S was also examined by using a urea solution, which flowed across the surface without leaving any residues.

  16. Wettability of graphene-laminated micropillar structures

    Energy Technology Data Exchange (ETDEWEB)

    Bong, Jihye; Seo, Keumyoung; Ju, Sanghyun, E-mail: jrahn@skku.edu, E-mail: shju@kgu.ac.kr [Department of Physics, Kyonggi University, Suwon, Gyeonggi-Do 443-760 (Korea, Republic of); Park, Ji-Hoon; Ahn, Joung Real, E-mail: jrahn@skku.edu, E-mail: shju@kgu.ac.kr [Department of Physics, Sungkyunkwan University, Suwon, Gyeonggi-Do 440-746 (Korea, Republic of)

    2014-12-21

    The wetting control of graphene is of great interest for electronic, mechanical, architectural, and bionic applications. In this study, the wettability of graphene-laminated micropillar structures was manipulated by changing the height of graphene-laminated structures and employing the trichlorosilane (HDF-S)-based self-assembly monolayer. Graphene-laminated micropillar structures with HDF-S exhibited higher hydrophobicity (contact angle of 129.5°) than pristine graphene thin film (78.8°), pristine graphene-laminated micropillar structures (97.5°), and HDF-S self-assembled graphene thin film (98.5°). Wetting states of the graphene-laminated micropillar structure with HDF-S was also examined by using a urea solution, which flowed across the surface without leaving any residues.

  17. Laminate article

    Science.gov (United States)

    Williams, Robert K.; Paranthaman, Mariappan; Chirayil, Thomas G.; Lee, Dominic F.; Goyal, Amit; Feenstra, Roeland

    2002-01-01

    A laminate article comprises a substrate and a biaxially textured (RE.sub.x A.sub.(1-x)).sub.2 O.sub.2-(x/2) buffer layer over the substrate, wherein 0article can include a layer of YBCO over the (RE.sub.x A.sub.(1-x)).sub.2 O.sub.2-(x/2) buffer layer. A layer of CeO.sub.2 between the YBCO layer and the (RE.sub.x A.sub.(1-x)).sub.2 O.sub.2-(x/2) buffer layer can also be include. Further included can be a layer of YSZ between the CeO.sub.2 layer and the (RE.sub.x A.sub.(1-x)).sub.2 O.sub.2-(x/2) buffer layer. The substrate can be a biaxially textured metal, such as nickel. A method of forming the laminate article is also disclosed.

  18. Develpoment of one-component waterborne polyurethane film-laminating adhesive%单组分水性聚氨酯复膜胶研制

    Institute of Scientific and Technical Information of China (English)

    吴明江; 丁温娜; 王雪琴; 蔡彦; 吴旭

    2012-01-01

    溶剂型复膜胶一般为双组分,使用不便,而且含大量有机溶剂影响安全和环保.在软包装等领域,已经越来越多地被水性复膜胶产品替代.水性聚氯酯胶粘剂(WPU)为单组分,性能优良.本课题在丙酮法合成水性聚氨酯的技术基础上,分别采用熔融分散法和预聚体分散法合成WPU复膜胶.通过综合比较,性价比较好的预聚体分散法是合成WPU复膜胶的理想方法.用MDI-2460和TDI的混合异氰酸酯、聚酯多元醇PD-56、中和前预聚体-NCO含量在2.5%~3.0%时,可合成出性能稳定、单组分,对透明PE/PE镀铝、PET镀铝/BOPP、透明PE/黑白膜等复合性能良好,初粘性可这2N/15mm以上的WPU,基本不用热化即可直接分切.%Generally.the solvent-based film-laminating adhesive are used in the form of two components,thus its j ues is inconvenient,meanwhile it brings some safe and environment friendly problems.By comparison to solvent-based j adhesivcs.the waterborne polyurethane (WPU) adhesives.as a environment-friendly material,are used widely in soft packing,which are used in the form of one component and has excellent performance.On the basis of warerbome polyurethane synthesized by acetone method,the one-component waterborne polyurethane was synthesized by prepolymer dispersing process and metl dispering process.Through comparisions of techniches,characters and productive efficiency,prepolymer dispersing process with excellent performance and low cost is superior to metl dispering process.The comprehesive comparison of cost performance indicated that the prepolyme dispersing method is a perfact method of synthesis of WPU film-laminating adhcsives.When the NCO group content of the prepolymer is 2.5% to 3% before neutralization the one-component WPU with stable performance and tackness of over 2N/15 mm can be synthesized with the mixture of MDI-2460 and TDI and the polyester polyol PD-56,which has excellent laminating performance for the films

  19. 包装复合膜用松香改性水性聚氨酯胶粘剂%Waterborne Polyurethane Adhesive Modified by Rosin for Laminated Package Films

    Institute of Scientific and Technical Information of China (English)

    郭文杰; 傅和青; 黄洪; 陈焕钦

    2007-01-01

    The waterborne polyurethane adhesive was modified by rosin. Effects of the amounts of DMPA,rosin, and NCO / OH value on the properties of the emulsion were studied. The adhesive property of modified and unmodified polyurethane for laminated package films was compared. And the experimental results showed that the modified waterborne polyurethane adhesive meets the need of laminated package films.%利用松香改性水性聚氨酯胶粘剂,研究了二羟甲基丙酸(DMPA)用量、NCO/OH值、松香用量对乳液性能的影响,比较了改性前后该胶粘荆对多种塑料薄膜的粘接性能.实验结果表明改性后的胶粘剂对多种塑料薄膜具有较强的粘接能力.

  20. Functional Leathers: Hydrophobic Leather%功能性皮革系列之疏水皮革

    Institute of Scientific and Technical Information of China (English)

    邢恩征; 王全杰

    2013-01-01

    详细介绍了皮革表面疏水的原理、影响皮革表面疏水性的因素、皮革表面疏水的处理方法、皮革表面疏水材料等,并对疏水表面皮革的发展做了一定的展望.%The hydrophobic properties of leather were introduced in detail, including principle of leather surface hydrophobic, the influence factors of leather surface hydrophobic, the treatment method of leather surface hydrophobic, leather surface hydro-phobic materials etc. The prospect of hydrophobic leather was proposed.

  1. Residual Chromium in Leather by Instrumental Neutron Activation Analysis

    OpenAIRE

    S. Okoh; I. O. Okunade; D. J. Adeyemo; Ahmed, Y A; A. A. Audu; E. Amali

    2012-01-01

    Problem statement: Most tanning processes employ the use of chromium sulphate. For chromium tanned leather, finished products may contain high amount of residual chromium. This may pose some health hazards, since chromium is known to be toxic at elevated concentration. This justifies the need for the study. Approach: Various samples of leather were collected from a tannery, a leather crafts market, a leather dump site and from local tanners all in Kano, Nigeria in 2009. The samples were irrad...

  2. Characterization of mechanical properties of leather with airborne ultrasonics

    Science.gov (United States)

    A nondestructive method to accurately evaluate the quality of hides and leather is urgently needed by leather and hide industries. We previously reported the research results for airborne ultrasonic (AU) testing using non-contact transducers to evaluate the quality of hides and leather. The abilit...

  3. Hybrid composite laminate structures

    Science.gov (United States)

    Chamis, C. C.; Lark, R. F. (Inventor)

    1977-01-01

    An invention which relates to laminate structures and specifically to essentially anisotropic fiber composite laminates is described. Metal foils are selectively disposed within the laminate to produce increased resistance to high velocity impact, fracture, surface erosion, and other stresses within the laminate.

  4. Otzi, the iceman and his leather clothes.

    Science.gov (United States)

    Püntener, Alois G; Moss, Serge

    2010-01-01

    Over 5000 years ago, a man climbed up to the icy heights of the glacier in South Tyrol, Italy and died. He was found by accident in 1991, with his clothes and equipment, mummified and frozen: an archaeological sensation and a unique snapshot of a Copper Age man. For several years highly specialised research teams have examined the mummy and all accompanying items. This paper describes how fur and leather clothes of the iceman could have been tanned. Details of the analytical tests undertaken on the 5000 year old leather samples and what they revealed are presented.

  5. Determination of heavy metal toxicity of finished leather solid waste.

    Science.gov (United States)

    Aslan, Ahmet

    2009-05-01

    This paper investigates the toxicity in leather products of heavy metals known to be detrimental to the ecosystem. Heavy metal concentrations in leather samples were identified with ICP-OES, and toxicity was determined using a MetPLATE bioassay. Chromium and aluminium were found to constitute 98% of the total concentration of heavy metals in finished leather tanned with chromium and aluminium salts, while in some vegetable-tanned leather, zirconium was the only heavy metal identified. The average inhibition values for chromium, aluminium and vegetable tanned leather were 98.08%, 97.04% and 62.36%, respectively.

  6. MANAGEMENT OF PROCESSING AND RECOVERY OF LEATHER WASTE

    Directory of Open Access Journals (Sweden)

    STAN Ovidiu Valentin

    2014-05-01

    Full Text Available The leather and leather goods industry development is conditioned by the development of the supply of raw materials - animal husbandry and chemical industries, sectors that tend to develop intensive on vertical - which causes a shortage of raw materials in relation with the market demand for quality products. The leather is the basic raw material of the leather and leather goods industry, this raw material is the most substantial contribution to downstream sectors, giving them a competitive advantage and it is known that the leather has the greatest potential to add value to the products in which it is incorporated. The advantages of using leather are many, the most important qualities are its hygienic properties, flexibility and adaptability to a wide variety of applications. Leather is manufactured on demand for each type of application, such as shoes, clothes, gloves, handbags, furniture upholstery or car interiors, yachts and planes. It requires better use of raw materials by using new technologies and manufacturing processes based on non-invasive methods on the environment leading to increase the product life cycle. The leather and leather goods industry is a supplier of large amounts of waste from the production cycle, waste that has the same properties and qualities as raw material used in the base product. Leather waste represents a loss for the companies, an additional cost related to storage and environmental protection.

  7. Consumer leather exposure: an unrecognized cause of cobalt sensitization

    DEFF Research Database (Denmark)

    Thyssen, J.P.; Johansen, Jeanne D.; Jellesen, Morten Stendahl

    2013-01-01

    BACKGROUND: A patient who had suffered from persistent generalized dermatitis for 7 years was diagnosed with cobalt sensitization, and his leather couch was suspected as the culprit, owing to the clinical presentation mimicking allergic chromium dermatitis resulting from leather furniture exposure....... MATERIALS AND METHODS: The cobalt spot test, X-ray fluorescence, inductively coupled plasma mass spectrometry and scanning electron microscopy were used to determine cobalt content and release from the leather couch that caused the dermatitis and from 14 randomly collected samples of furniture leather....... RESULTS: The sample from the patient's leather couch, but none of the 14 random leather samples, released cobalt in high concentrations. Dermatitis cleared when the patient stopped using his couch. CONCLUSIONS: Cobalt is used in the so-called pre-metallized dyeing of leather products. Repeated studies...

  8. [Determination of residual glycol ethers in leather and leather products by gas chromatography/mass spectrometry].

    Science.gov (United States)

    Wang, Ghengyun; Zhang, Weiya; Li, Lixia; Shen, Yalei; Lin, Junfeng; Xie, Tangtang; Chu, Naiqing

    2014-08-01

    An effective method was established for the simultaneous determination of residual glycol ethers in leather and leather products by gas chromatography/mass spectrometry. Glycol ethers in leather and leather products were ultrasonically extracted at 45 °C, using ethyl acetate as the extraction solvent. The extracts were purified by solid phase extraction (SPE) columns, and then analyzed by gas chromatography/mass spectrometry in selected ion monitoring mode. The content of each analyte was calibrated by external standard method. The limit of detection of ethylene glycol ethyl ether (EGEE) was 0. 10 mg/kg under the condition of signal to noise (S/N) of 3 and the limits of the other 11 glycol ethers were all less than 0.05 mg/kg. The spiked recoveries varied from 81. 2% to 95. 5% at three different spiked levels with the relative standard deviations (RSDs) ranged from 1.4% to 6. 6%. The proposed method is simple, rapid and accurate, with the limits of detection much less than the requirements of the Regulation Concerning Registration, Evaluation, Authorization and Restriction of Chemicals (REACH) of European Union. It is applicable to the determination of residual glycol ethers in leather and leather products, and provides a reference for the relevant testing standards.

  9. Marilyn Levine: "Brown Boots, Leather Laces."

    Science.gov (United States)

    Williams, Ray

    1988-01-01

    Presents a lesson plan which uses Marilyn Levine's "Brown Boots, Leather Laces" to introduce students in grades 10-12 to naturalistic representation and the "trompe l'oeil" artistic tradition. Discusses Levine's background. Includes instructional strategies and student objectives, as well as a photograph of the artwork. (GEA)

  10. Changes to collagen structure during leather processing.

    Science.gov (United States)

    Sizeland, Katie H; Edmonds, Richard L; Basil-Jones, Melissa M; Kirby, Nigel; Hawley, Adrian; Mudie, Stephen; Haverkamp, Richard G

    2015-03-11

    As hides and skins are processed to produce leather, chemical and physical changes take place that affect the strength and other physical properties of the material. The structural basis of these changes at the level of the collagen fibrils is not fully understood and forms the basis of this investigation. Synchrotron-based small-angle X-ray scattering (SAXS) is used to quantify fibril orientation and D-spacing through eight stages of processing from fresh green ovine skins to staked dry crust leather. Both the D-spacing and fibril orientation change with processing. The changes in thickness of the leather during processing affect the fibril orientation index (OI) and account for much of the OI differences between process stages. After thickness is accounted for, the main difference in OI is due to the hydration state of the material, with dry materials being less oriented than wet. Similarly significant differences in D-spacing are found at different process stages. These are due also to the moisture content, with dry samples having a smaller D-spacing. This understanding is useful for relating structural changes that occur during different stages of processing to the development of the final physical characteristics of leather.

  11. SOCIAL PREMISES FOR A SUSTAINABLE LEATHER INDUSTRY

    Directory of Open Access Journals (Sweden)

    Trandafir Nicoleta

    2014-07-01

    Full Text Available Sustainability is not any more a new and un-known subject in the leather business world. There is a certain reorientation and implementation tendency of its requirements at organization level, in the last years. However, there are still some ambiguities and uncertainties related on the approach and practice of all principles included in the concept. That’s why each organization tries to formulate winning strategies on long term, showing an equal importance for human resources, social balance and the environment. This work highlights the efficiency of the human resources in the leather industry’s sustainability, a study created by seven national associations representing the leather industry from Italy, Spain, France, Germany, UK, Sweden and Romania. The analysis of social indicators demonstrates that tanneries in Europe are increasingly committed to the ethical and social aspects of their business, and that, through continuous investments, they have been able to ensure substantial improvements in process efficiency and in pollution prevention and control. All the efforts made by European tanneries over the years have resulted in improving the sustainability of their production. The excellent results achieved deserve to be valued more by stakeholders and better incentivised through measures encouraging new and future investments. The environmental and social values demonstrated by European leather help to keep European tanners ahead of international competition.

  12. Properties of Whey-Protein-Coated Films and Laminates as Novel Recyclable Food Packaging Materials with Excellent Barrier Properties

    Directory of Open Access Journals (Sweden)

    Markus Schmid

    2012-01-01

    Full Text Available In case of food packaging applications, high oxygen and water vapour barriers are the prerequisite conditions for preserving the quality of the products throughout their whole lifecycle. Currently available polymers and/or biopolymer films are mostly used in combination with barrier materials derived from oil based plastics or aluminium to enhance their low barrier properties. In order to replace these non-renewable materials, current research efforts are focused on the development of sustainable coatings, while maintaining the functional properties of the resulting packaging materials. This article provides an introduction to food packaging requirements, highlights prior art on the use of whey-based coatings for their barriers properties, and describes the key properties of an innovative packaging multilayer material that includes a whey-based layer. The developed whey protein formulations had excellent barrier properties almost comparable to the ethylene vinyl alcohol copolymers (EVOH barrier layer conventionally used in food packaging composites, with an oxygen barrier (OTR of <2 [cm³(STP/(m²d bar] when normalized to a thickness of 100 μm. Further requirements of the barrier layer are good adhesion to the substrate and sufficient flexibility to withstand mechanical load while preventing delamination and/or brittle fracture. Whey-protein-based coatings have successfully met these functional and mechanical requirements.

  13. SEWABILITY PROPERTIES OF GARMENT LEATHERS TANNED WITH VARIOUS TANNING MATERIALS

    Directory of Open Access Journals (Sweden)

    ORK Nilay

    2016-05-01

    Full Text Available Chromium tannage is the most used technology in processing of garment leathers. Due to environmental requirements and demands on natural products there is an increasing interest on alternatives to chromium tannage especially on vegetable tanned leathers. Leather properties vary in a very wide range depending on the animal type it is obtained from and the process type and chemicals used in the manufacturing. In this study, the effect of various tanning materials to the sewability of garment leathers was investigated. For this purpose, vegetable, chromium and chromium-vegetable combination tanned garment leathers from the same animal origin were supplied from a garment leather manufacturing factory. Needle penetration force and the sewability values of these leathers were determined by using L&M Sewability Tester. It was found that material properties and sewing properties showed differences regarding to the tanning material used even in same type of raw material. Chromium tanned leathers had sewability values of 13.4% horizontal and 14.2% vertical which are considered good to fair. Vegetable tanned leathers and chromium-vegetable tanned leathers had sewability values of 38.2% horizontal, 49.2% vertical and 98% horizontal, 98.5% vertical respectively which are considered poor. The results of the study conclude that, there is a big difference in material properties when the tanning technology and material is changed which also affects the sewing properties.

  14. LEATHER WASTE VALORISATION THROUGH MATERIAL INNOVATION: SOME PROPERTIES OF LEATHER WOOD FIBREBOARD

    Directory of Open Access Journals (Sweden)

    Axel M. RINDLER

    2015-12-01

    Full Text Available Due to the ever-increasing scarcity of resources and raw materials in the wood panels industry, it is imperative to look for suitable alternatives to the established resources. Therefore a combination of the traditionally used and newly explored sources may reveal highly innovative ways. The objective of this study is to provide an insight into the behavior of the material and possible new applications of those fiber/particle wood and waste leather composites. For this reason exclusively fibers of spruce were used for the trials. Wet white (WW leather particles and wet blue (WB leather particles were mixed with the wooden materials for the production of high density fibreboards. Besides the mechanical properties such as the internal bond (IB the bending strength (MOR and modulus of elasticity (MOE was analyzed. Further physical property as thickness swelling after 24h watering was investigated. To analyze how the density influences the behavior under thermal conditions, fiberboards with the densities 500, 700 and 900 kg/m³ were tested. The results of the material properties were influenced by the leather content of the panels. The results for the UF-bonded HDF boards show enhancement of the transverse IB with increasing wet blue leather content, whereas the other mechanical properties decline meanwhile. The thickness swelling showed higher values compared to the wood fibreboard. The results of this study underline the usefulness of integrating leather shavings to HDF and give an overview of their influence in wood fiber materials. The combination of the natural resource wood fiber and the leather waste products (Wet Blue and Wet White gives a very interesting new material, its mechanical properties allow a variety of possible application in future applications.

  15. Natural leathers from natural materials: progressing toward a new arena in leather processing.

    Science.gov (United States)

    Saravanabhavan, Subramani; Thanikaivelan, Palanisamy; Rao, Jonnalagadda Raghava; Nair, Balachandran Unni; Ramasami, Thirumalachari

    2004-02-01

    Globally, the leather industry is currently undergoing radical transformation due to pollution and discharge legislations. Thus, the leather industry is pressurized to look for cleaner options for processing the raw hides and skins. Conventional methods of pre-tanning, tanning and post-tanning processes are known to contribute more than 98% of the total pollution load from the leather processing. The conventional method of the tanning process involves the "do-undo" principle. Furthermore, the conventional methods employed in leather processing subject the skin/ hide to a wide variation in pH (2.8-13.0). This results in the emission of huge amounts of pollution loads such as BOD, COD, TDS, TS, sulfates, chlorides and chromium. In the approach illustrated here, the hair and flesh removal as well as fiber opening have been achieved using biocatalysts at pH 8.0, pickle-free natural tanning employing vegetable tannins, and post-tanning using environmentally friendly chemicals. Hence, this process involves dehairing, fiber opening, and pickle-free natural tanning followed by ecofriendly post-tanning. It has been found that the extent of hair removal and opening up of fiber bundles is comparable to that of conventionally processed leathers. This has been substantiated through scanning electron microscopic analysis and softness measurements. Performance of the leathers is shown to be on par with conventionally chrome-tanned leathers through physical and hand evaluation. The process also exhibits zero metal (chromium) discharge and significant reduction in BOD, COD, TDS, and TS loads by 83, 69, 96, and 96%, respectively. Furthermore, the developed process seems to be economically viable.

  16. POTENTIAL USE OF COLLAGEN HYDROLYSATES FROM CHAMOIS LEATHER WASTE AS INGREDIENT IN LEATHER FINISHING FORMULATIONS

    Directory of Open Access Journals (Sweden)

    POPA Emil

    2016-05-01

    Full Text Available The aim of this paper is the obtaining of value-added products from the dust resulted from chamois leather buffering, a solid waste that raises serious disposal problems, due to its physical state and complex chemical composition. Starting from leather waste, an alkaline hydrolysis was performed followed by the chemical modification of the polypeptyde hydrolysate by polycondensation with dispersions of copolymers of vinyl acetate with acrylic esters and reticulation with glutaraldehyde in order to improve its hydrophobicity. The resulted product can be used/was tested as an ingredient in leather finishing formulations, as binder or carrier agent. In this paper, new finishing mixtures were prepared using pigments and obtained polypeptide hydrolysates as a substitute for casein in pigment pastes. By this method, there were obtained two experimental variants of brown and black pigment pastes which were compared to the pigment pastes with casein binder. Natural grain Box bovine leather samples coated with such admixtures were subjected to physico-mechanical resistance tests, in accordance with the standardized methods. Specific tests carried on finished leather – tensile strength, tear resistance, resistance to grain cracking, dry and wet rubbing fastness, flexural fatigue strength test, etc – showed values of this characteristics comparable to those obtained with casein conventional finishing.

  17. [Leather azo dyes: mutagenic and carcinogenic risks].

    Science.gov (United States)

    Clonfero, E; Venier, P; Granella, M; Levis, A G

    1990-01-01

    The paper reviews the carcinogenicity and mutagenicity data on azo dyes used in the leather industry. Two water soluble benzidine-based dyes were classified as "probably carcinogenic to humans" by the International Agency for Research on Cancer (IARC). No other dyes have been evaluated by the IARC. Of the 48 azo dyes assayed in the Salmonella/microsome test, 20 gave positive results. Attention is drawn to the important role of the in vivo metabolism of azo compounds, which includes a preliminary reduction of the azo bonds and subsequent release of the aromatic amines of the dye. A useful assay (Prival test) for evaluating the mutagenic properties of azo dyes involves a reductive step that permits the release of any genotoxic agents present in the compounds. A list of leather azo dyes is furnished that are considered as potentially harmful due to the presence of a carcinogenic aromatic amine (benzidine, p-aminobenzene and derivatives) in their formulae.

  18. Research on Design Information Management System for Leather Goods

    Science.gov (United States)

    Lu, Lei; Peng, Wen-li

    The idea of setting up a design information management system of leather goods was put forward to solve the problems existed in current information management of leather goods. Working principles of the design information management system for leather goods were analyzed in detail. Firstly, the acquiring approach of design information of leather goods was introduced. Secondly, the processing methods of design information were introduced. Thirdly, the management of design information in database was studied. Finally, the application of the system was discussed by taking the shoes products as an example.

  19. Modified silica sol coatings for surface enhancement of leather.

    Science.gov (United States)

    Mahltig, Boris; Vossebein, Lutz; Ehrmann, Andrea; Cheval, Nicolas; Fahmi, Amir

    2012-06-01

    The presented study reports on differently modified silica sols for coating applications on leather. Silica sols are prepared by acidic hydrolysis of tetraethoxysilane and modified by silane compounds with fluorinated and non-fluorinated alkylgroups. In contrast to many earlier investigations regarding sol-gel applications on leather, no acrylic resin is used together with the silica sols when applying on leather. The modified silica particles are supposed to aggregate after application, forming thus a modified silica coating on the leather substrate. Scanning electron microscopy investigation shows that the applied silica coatings do not fill up or close the pores of the leather substrate. However, even if the pores of the leather are not sealed by this sol-gel coating, an improvement of the water repellent and oil repellent properties of the leather substrates are observed. These improved properties of leather by application of modified silica sols can provide the opportunity to develop sol-gel products for leather materials present in daily life.

  20. Leather structure determination by small-angle X-ray scattering (SAXS): cross sections of ovine and bovine leather.

    Science.gov (United States)

    Basil-Jones, Melissa M; Edmonds, Richard L; Allsop, Timothy F; Cooper, Sue M; Holmes, Geoff; Norris, Gillian E; Cookson, David J; Kirby, Nigel; Haverkamp, Richard G

    2010-05-12

    SAXS has been applied to structural determination in leather. The SAXS beamline at the Australian Synchrotron provides 6 orders of magnitude dynamic range, enabling a rich source of structural information from scattering patterns of leather sections. SAXS patterns were recorded for q from 0.004 to 0.223 A(-1). Collagen d spacing varied across ovine leather sections from 63.8 nm in parts of the corium up to 64.6 nm in parts of the grain. The intensity of the collagen peak at q = 0.06 A(-1) varied by 1 order of magnitude across ovine leather sections with the high-intensity region in the corium and the low intensity in the grain. The degree of fiber orientation and the dispersion of the orientation has been quantified in leather. It is shown how the technique provides a wealth of useful information that may be used to characterize and compare leathers, skin, and connective tissue.

  1. Properties of wheat gluten/poly(lactic acid) laminates.

    Science.gov (United States)

    Cho, Sung-Woo; Gällstedt, Mikael; Hedenqvist, Mikael S

    2010-06-23

    Laminates of compression-molded glycerol-plasticized wheat gluten (WG) films surrounded and supported by poly(lactic acid) (PLA) films have been produced and characterized. The objective was to obtain a fully renewable high gas barrier film with sufficient mechanical integrity to function in, for example, extrusion-coating paper/board applications. It was shown that the lamination made it possible to make films with a broad range of glycerol contents (0-30 wt %) with greater strength than single unsupported WG films. The low plasticizer contents yielded laminates with very good oxygen barrier properties. In addition, whereas the unsupported WG films had an immeasurably high water vapor transmission rate (WVTR), the laminate showed values that were finite and surprisingly, in several cases, also lower than that of PLA. Besides being a mechanical support (as evidenced by bending and tensile data) and a shield between the WG and surrounding moisture, the PLA layer also prevented the loss of the glycerol plasticizer from the WG layer. This was observed after the laminate had been aged on an "absorbing" blotting paper for up to 17 weeks. The interlayer adhesion (peel strength) decreased with decreasing glycerol content and increasing WG film molding temperature (130 degrees C instead of 110 degrees C). The latter effect was probably due to a higher protein aggregation, as revealed by infrared spectroscopy. The lamination temperature (110-140 degrees C) did not, however, have a major effect on the final peel strength.

  2. Support Assembly for Composite Laminate Materials During Roll Press Processing

    Science.gov (United States)

    Catella, Luke A.

    2011-01-01

    A composite laminate material is supported during the roll press processing thereof by an assembly having: first and second perforated films disposed adjacent to first and second opposing surfaces of a mixture of uncured resin and fibers defining the composite laminate material, a gas permeable encasement surrounding the mixture and the first and second films, a gas impervious envelope sealed about the gas permeable encasement, and first and second rigid plates clamped about the gas impervious envelope.

  3. EXPLORING THE USE OF SUEDE DYE ON LEATHER

    African Journals Online (AJOL)

    User

    The indigenous leather tanners in Ghana lack access to variety in dyes and colourants, this lim- its the ability of their ... The popular, natural cream colour of leather is the basic colour ... the preparation of the dye from guinea-corn leaves and its ...

  4. MECHANICAL QUALITY OF LEATHER IN TEXEL LAMBS AND THEIR CROSSBREDS

    Directory of Open Access Journals (Sweden)

    Milena Fantová

    2015-06-01

    Full Text Available High quality leather of small ruminants is a valuable raw material for various industrial sectors. Sheep breeding system was significantly re-oriented and focused on meat breeds in the Czech Republic during last 15 years. Therefore, the objective of work was to evaluate effect of Texel blood share and body part on selected quality traits of sheep leather as an additional product of its breeding. A total of 10 leathers of purebred Texel lambs (T100 and 10 leathers of Merino x Texel crossbred (T50 were analysed. The basic indicators of leather quality namely leather thickness (LT, mm, yield strength (YS, μm, tensile strength (TS, MPa, and breaking point (BP, μm were measured and evaluated in relation to selected factors. LT of cross-breds with 50% share of Texel blood was by 0.1616 (P<0.001 mm thicker than in pure-bred Texel lambs. Body part of leather significantly (P<0.05-0.01 affected all characteristics evaluated except BP. Hypothesis stated was confirmed and initial results documented necessity of more detailed further research focusing on leather quality of meat breeds of sheep.

  5. Contact allergens in shoe leather among patients with foot eczema

    NARCIS (Netherlands)

    van Coevorden, AM; Coenraads, PJ; Pas, HH; van der Valk, PGM

    2002-01-01

    Some patients with relapsing foot eczema and a shoe leather allergy, who fail to show positive results with standard series and shoe wear screening tray patch testing, do not respond to the use of hypoallergenic shoe leather. We assume that relevant allergens are present in hypoallergenic shoe leath

  6. Recycling of Chrome Tanned Leather Dust in Acrylonitrile Butadiene Rubber

    Science.gov (United States)

    El-Sabbagh, Salwa H.; Mohamed, Ola A.

    2010-06-01

    Concerns on environmental waste problem caused by chrome tanned leather wastes in huge amount have caused an increasing interest in developing this wastes in many composite formation. This leather dust was used as filler in acrylonitrile butadiene rubber (NBR) before treatment and after treatment with ammonia solution and sod. formate. Different formulations of NBR/ leather dust (untreated-treated with ammonia solution—treated with sod. formate) composites are prepared. The formed composite exhibit a considerable improvement in some of their properties such as rheometric characteristics especially with composites loaded with treated leather dust. Tensile strength, modulus at 100% elongation, hardness and youngs modulus were improved then by further loading start to be steady or decrease. Cross linking density in toluene were increased by incorporation of leather dust treated or untreated resulting in decreases in equilibrium swelling. Distinct increase in the ageing coefficient of both treated and untreated leather with drop in NBR vulcanizates without leather dust. Addition of leather dust treated or untreated exhibit better thermal stability.

  7. Modification of Leather Split by In Situ Polymerization of Acrylates

    Directory of Open Access Journals (Sweden)

    Weixing Xu

    2016-01-01

    Full Text Available Leather split, the byproduct of leather manufacture, possesses low utility value because it has loose weave of collagen fibers and weak mechanical strengths. Herein, a practical and convenient method for increasing strengths of leather split was developed by one-step in situ polymerization. The structures and properties of polyacrylate/leather split composites were systematically investigated. The results suggested the monomers with an α-methyl and a proper straight-chain ester group, such as nBMA, can effectively modify the leather split. For leather split with a thickness of 1.6 mm, the rational processes for preparation of polyacrylate/leather split composite are that monomer and split were stirred in a drum for 4 hours for full permeation and then the split was heated in anaerobic condition at 45°C for 30 min. The tensile strength, tear strength, and elongation at break of the optimized PnBMA/split composite were 18.72 MPa, 62.73 N/mm, and 46.02%, respectively. With these mechanical properties, the split after modification can be well used as leather for making shoes, bags, gloves, and clothing.

  8. Green chemistry approaches to leather tanning process for making chrome-free leather by unnatural amino acids.

    Science.gov (United States)

    Krishnamoorthy, G; Sadulla, S; Sehgal, P K; Mandal, Asit Baran

    2012-05-15

    In the present study, green and sustainable method or eco-friendly approaches to tanning process based on unnatural D-amino acids (D-AA)-aldehyde (Ald) as a substitute for chrome-free tanning has been attempted. The distribution of optically active D-AA in tanned leather, the hydrothermal stability, the mechanical properties and resistance to collagenolytic activity of tanned leather, the evaluation of eco-friendly characteristics were investigated. Scanning electron microscopic (SEM) and Atomic force microscopic (AFM) analyses indicate the surface morphology and roughness, respectively, of the tanned leather collagen matrix. Shrinkage and Differential scanning calorimetric (DSC) analyses shows that the shrinkage temperature (T(s)) and denaturation temperature (T(d)) of tanned leather are related to the content of D-AA+Ald present in the leather matrix. It has been found that the T(s) of D-AA tanned leather is more than that of Ald tanned leather and also more or less equal to chrome tanned leather. Environmental impact assessment (EIA) shows that the developed process results in significant reduction in total solids content (TSC) and improves better biodegradability of organic compound present in the effluent compared to chrome tanning. Copyright © 2012 Elsevier B.V. All rights reserved.

  9. Nuclear lamins and neurobiology.

    Science.gov (United States)

    Young, Stephen G; Jung, Hea-Jin; Lee, John M; Fong, Loren G

    2014-08-01

    Much of the work on nuclear lamins during the past 15 years has focused on mutations in LMNA (the gene for prelamin A and lamin C) that cause particular muscular dystrophy, cardiomyopathy, partial lipodystrophy, and progeroid syndromes. These disorders, often called "laminopathies," mainly affect mesenchymal tissues (e.g., striated muscle, bone, and fibrous tissue). Recently, however, a series of papers have identified important roles for nuclear lamins in the central nervous system. Studies of knockout mice uncovered a key role for B-type lamins (lamins B1 and B2) in neuronal migration in the developing brain. Also, duplications of LMNB1 (the gene for lamin B1) have been shown to cause autosome-dominant leukodystrophy. Finally, recent studies have uncovered a peculiar pattern of nuclear lamin expression in the brain. Lamin C transcripts are present at high levels in the brain, but prelamin A expression levels are very low-due to regulation of prelamin A transcripts by microRNA 9. This form of prelamin A regulation likely explains why "prelamin A diseases" such as Hutchinson-Gilford progeria syndrome spare the central nervous system. In this review, we summarize recent progress in elucidating links between nuclear lamins and neurobiology.

  10. Wood or Laminate?—Psychological Research of Customer Expectations

    Directory of Open Access Journals (Sweden)

    Paul Jiménez

    2016-11-01

    Full Text Available Wood is generally associated with being practical, aesthetic and economy-friendly. Using wood in interior settings also can be based on psychological expectations and assumptions, as wood is attributed as warmer, more homely, more relaxing and more inviting. However, when investigating psychological differences, wood is usually compared to carpets, glass, leather, stone, or plastic but is not compared to a visually similar material such as laminate. The aim of this study is to analyze and compare the various psychological characteristics related to wooden and laminate materials in interior settings. The experimental design was a 2 × 2 design (material, sequence with repeated measures for material. Forty participants were asked to evaluate a framed piece of wood floor and a framed piece of laminate floor regarding technical, practical, and psychological aspects. Further, three questions about one’s purchase decision were asked. The results show that the wooden floor was evaluated significantly better than the laminate floor regarding “materials and processing”, “atmosphere”, and “values and symbolic functions”. For the criterion “health”, a tendency in favor of wood could be found. In addition, the participants would more likely recommend and purchase wooden products and also accept more deficiencies in wooden products.

  11. POTENTIAL USE OF BUFFALO SKIN AS A RAW MATERIAL FOR LEATHER TANNING INDUSTRY IN INDONESIA

    OpenAIRE

    2013-01-01

    Leather industry and leather goods industry in Indonesia reached the peak in1986-1996. Export of leather products (shoes, gloves, and jackets) contributed U.S. $ 2.4 billion to the government. Export of leather and leather products ranks third on the non-oil exports, the level after the export of textiles and wood. Since the economic crisis in Indonesia in 1997, nearly all industry sectors were collapsed, including the leather and leather products industry (Untari et al., 2009). The funda...

  12. Green chemistry approaches to leather tanning process for making chrome-free leather by unnatural amino acids

    Energy Technology Data Exchange (ETDEWEB)

    Krishnamoorthy, G.; Sadulla, S.; Sehgal, P.K. [Central Leather Research Institute, Council of Scientific and Industrial Research (CSIR), Adyar, Chennai 600 020 (India); Mandal, Asit Baran, E-mail: abmandal@hotmail.com [Central Leather Research Institute, Council of Scientific and Industrial Research (CSIR), Adyar, Chennai 600 020 (India)

    2012-05-15

    Highlights: Black-Right-Pointing-Pointer Unnatural D-AA assisted tanned leathers found soft and full possessing tight grain. Black-Right-Pointing-Pointer Increased hydrothermal stability of collagen via intra and inter molecular crosslink. Black-Right-Pointing-Pointer D-Ly+Ald tanned leathers revealed a properly oriented with well aligned structure. Black-Right-Pointing-Pointer D-AA in collagen creates new topologies inaccessible to homo chiral molecules. Black-Right-Pointing-Pointer Improves conventional tanning process, and reduce the total solid and liquid wastes. - Abstract: In the present study, green and sustainable method or eco-friendly approaches to tanning process based on unnatural D-amino acids (D-AA)-aldehyde (Ald) as a substitute for chrome-free tanning has been attempted. The distribution of optically active D-AA in tanned leather, the hydrothermal stability, the mechanical properties and resistance to collagenolytic activity of tanned leather, the evaluation of eco-friendly characteristics were investigated. Scanning electron microscopic (SEM) and Atomic force microscopic (AFM) analyses indicate the surface morphology and roughness, respectively, of the tanned leather collagen matrix. Shrinkage and Differential scanning calorimetric (DSC) analyses shows that the shrinkage temperature (T{sub s}) and denaturation temperature (T{sub d}) of tanned leather are related to the content of D-AA+Ald present in the leather matrix. It has been found that the T{sub s} of D-AA tanned leather is more than that of Ald tanned leather and also more or less equal to chrome tanned leather. Environmental impact assessment (EIA) shows that the developed process results in significant reduction in total solids content (TSC) and improves better biodegradability of organic compound present in the effluent compared to chrome tanning.

  13. Photovoltaic-Panel Laminator

    Science.gov (United States)

    Keenan, R.

    1985-01-01

    Two-piece unit heats and presses protective layers to form laminate. Rubber diaphragm between upper and lower vacuum chambers alternates between neutral position and one that presses against solar-cell array, supplying distributed force necessary to press layers of laminate together. Encapsulation helps to protect cells from environment and to ensure long panel life while allowing efficient generation of electricity from Sunlight.

  14. Hexavalent and trivalent chromium in leather: What should be done?

    Science.gov (United States)

    Moretto, Angelo

    2015-11-01

    Trivalent chromium compounds are used for leather tanning, and chromium may be released during use of leather goods. In certain instances, small amounts of hexavalent chromium can be formed and released. Both trivalent and hexavalent chromium can elicit allergic skin reaction in chromium sensitised subjects, the latter being significantly more potent. Induction of sensitisation only occurs after exposure to hexavalent chromium. A minority of subjects are sensitised to chromium, and in a fraction of these subjects allergic skin reaction have been described after wearing leather shoes or, less frequently, other leather goods. The evidence that in all these cases the reaction is related to hexavalent chromium is not always strong. The content of hexavalent chromium in leather is regulated in European Union, but rate of release rather than content is relevant for allergic skin reaction. The role of trivalent chromium appear much less relevant if at all. Modern tanning procedure do not pose significant risk due to either hexavalent or trivalent chromium. Dismissing bad quality and worn-off leather goods is relevant in reducing or eliminating the skin reaction. It should also be pointed out that shoe components or substances other than chromium in leather may cause allergic/irritative skin reactions.

  15. Cleaner production for solid waste management in leather industry ...

    African Journals Online (AJOL)

    Cleaner production for solid waste management in leather industry. ... are generated which include wastewater effluents, solid wastes, and hazardous wastes. ... industries discharge wastes into the environment without any proper treatment.

  16. Evaluation of fruit leather made from two cultivars of papaya

    Directory of Open Access Journals (Sweden)

    ZUHAIR RADHI ADDAI

    2016-03-01

    Full Text Available Two papaya cultivars were used to manufacture fruit leather. The objective of this study was to formulate papaya leather from locally grown papaya using natural ingredients like pectin, honey and citric acid. The fresh fruits were pureed and mix with natural ingredients, and dried in an oven at 60°C for 12 hours. The physicochemical properties and antioxidant activity were determined.The results showed that fruit leather made from Hongkong cultivar is significantly (P<0.05 higher in sensory parameters as well as physicochemical properties and antioxidant activity. The phenolics content and antioxidant activity increased by process of drying the fruit leather compared to fresh fruits in both papaya cultivars. Therefore, the consumer requirements for healthy and safe food products were respected.

  17. Association between cobalt allergy and dermatitis caused by leather articles

    DEFF Research Database (Denmark)

    Bregnbak, David; Thyssen, Jacob P; Zachariae, Claus

    2015-01-01

    BACKGROUND: Cobalt is a strong skin sensitizer and a prevalent contact allergen. Recent studies have recognized exposure to leather articles as a potential cause of cobalt allergy. OBJECTIVES: To examine the association between contact allergy to cobalt and a history of dermatitis resulting from ....... CONCLUSIONS: Our study suggests a positive association between cobalt allergy and a history of dermatitis caused by non-occupational exposure to leather articles.......BACKGROUND: Cobalt is a strong skin sensitizer and a prevalent contact allergen. Recent studies have recognized exposure to leather articles as a potential cause of cobalt allergy. OBJECTIVES: To examine the association between contact allergy to cobalt and a history of dermatitis resulting from...... as the most frequent exposure source causing dermatitis in the case group. Although the case group significantly more often reported non-occupational dermatitis caused by leather exposure (p

  18. Analyzing The Factors For Rejection Of Leather In Bangladesh

    Directory of Open Access Journals (Sweden)

    Md.Farhad Ali

    2015-08-01

    Full Text Available Abstract Leather plays a vital role in earning the foreign currency for Bangladesh. Export of finished leather and leather products have an important impact on the economy of Bangladesh. Mainly cow goat sheep and buffalo leathers are produced in this country. Different defects of leather due to numerous numbers of diseases of animals of poor management of people deteriorate the quality of leather which has negative impact in this sector. This paper analyses the magnitude and category of major defects in case of cow goat and buffalo of Bangladesh. We have studied in sixteen tanneries of Hazaribagh Dhaka where 95 tanneries of the whole country are situated. This study found that in case of cow skin hair slip parasitic skin diseases wound and pox are mainly responsible for the defects in leather in raw condition. Again in case of the wet blue leather of cow flay cut pox mark parasitic diseases growth mark wound sun burn scratch dark mole are responsible for the defects. Further for crust leather of cow flay cut parasitic diseases pox looseness for bating scratch wrinkle grain damage are found as the reason of defects. In case of goat parasitic diseases pox growth mark mole scratch flay cut hair slip were found responsible mostly for the defects in Bangladesh. Moreover parasite pox wound branding growth mark wrinkle jam wrinkle mole scratch flay cut curing have been detected for the defects of buffalo in this country. Again in this study it is found that average leather grade A-D is 15 E-F is 25 G-H is 30 HH is 12.5 and again the rejection is 18.43. It is observed that most of the defects occur during animal life period. The rest of the defects happen during slaughter flaying preservation and processing period of hides and skins into leather. By proper caring of the farm level and at the point of slaughter and flaying desired quality of hides and skins could be obtained.

  19. Chromed Leather Dyeing Peculiarities when Deliming with Peracetic Acid

    Directory of Open Access Journals (Sweden)

    Kęstutis BELEŠKA

    2013-05-01

    Full Text Available The research was aimed to investigate the influence of deliming with peracetic acid on leather dyeing kinetics. Hydrophobic C.I. Acid Red 213 and hydrophilic C.I. Acid Red 423 dyes were used. Sorption of dye depends on hydrophobicity/hydrophility of dye and dyeing temperature. Equilibrium of process is reached faster using hydrophobic C.I. Acid Red 213 at 45 ºC. However, both control and experimental leather fibres adsorb more hydrophilic dye C.I. Acid Red 423 and this fact does not depend on temperature. The diffusion coefficient of dye C.I. Acid Red 423 calculated according to Weisz model is higher when dyeing conventional leather. The change of deliming method has influence on chromed leather dyeing but this influence is not significant. The adsorption ability of control leather fibres at 30 ºC and 45 ºC is higher using both dyes as compared to the dyeing the experimental one. The increase of dyeing temperature increases the adsorption ability independently on the sort of leather fibres. Such dependence of the adsorption ability on the temperature shows that hydrophobic action and van der Waals forces prevail between dye and fibres during dyeing process. The Gibbs energy changes show that adsorption of both dyes by leather fibres independently on their sort is a spontaneous process. The affinity of both dyes to conventional leather fibres is higher comparing with experimental one. The change of enthalpy is positive in all cases, and it means that the driving force of the dyeing is the change of entropy.DOI: http://dx.doi.org/10.5755/j01.ms.19.2.4431

  20. Controlling mechanisms of moisture diffusion in convective drying of leather

    Science.gov (United States)

    Benmakhlouf, Naima; Azzouz, Soufien; Monzó-Cabrera, Juan; Khdhira, Hechmi; ELCafsi, Afif

    2017-04-01

    Leather manufacturing involves a crucial energy-intensive drying stage in the finishing process to remove its residual moisture. It occurs several times in the tanning course. As it is the target of this paper to depict an experimental way to determine moisture diffusion in the convective drying of leather. The effective diffusion coefficient is estimated by a method derived from Fick's law and by analytic method. The effective diffusion coefficients are obtained from drying tests and the diffusivity behaviour is studied versus the controlling parameter such as the convective airflow temperature. The experiments were conducted at hot air temperatures of 40, 45, 50, 55 and 60 °C and hot air speed of 1 m/s. The hot air temperature had significant effect on the effective moisture diffusivity of the leather sample. The average effective moisture diffusivity in rosehip ranged between 5.87 × 10-11 and 14.48 × 10-11 m2/s for leather at the temperatures studied. Activation energy for convective drying was found to be 38.46 kJ/mol for leather. The obtained results fully confirm the theoretical study in which an exponentially increasing relationship between effective diffusivity and temperature is predicted. The results of this study provide a better understanding of the drying mechanisms and may lead to a series of recommendations for leather drying optimization. It opens the possibility for further investigations on the description of drying conditions.

  1. Controlling mechanisms of moisture diffusion in convective drying of leather

    Science.gov (United States)

    Benmakhlouf, Naima; Azzouz, Soufien; Monzó-Cabrera, Juan; Khdhira, Hechmi; ELCafsi, Afif

    2016-08-01

    Leather manufacturing involves a crucial energy-intensive drying stage in the finishing process to remove its residual moisture. It occurs several times in the tanning course. As it is the target of this paper to depict an experimental way to determine moisture diffusion in the convective drying of leather. The effective diffusion coefficient is estimated by a method derived from Fick's law and by analytic method. The effective diffusion coefficients are obtained from drying tests and the diffusivity behaviour is studied versus the controlling parameter such as the convective airflow temperature. The experiments were conducted at hot air temperatures of 40, 45, 50, 55 and 60 °C and hot air speed of 1 m/s. The hot air temperature had significant effect on the effective moisture diffusivity of the leather sample. The average effective moisture diffusivity in rosehip ranged between 5.87 × 10-11 and 14.48 × 10-11 m2/s for leather at the temperatures studied. Activation energy for convective drying was found to be 38.46 kJ/mol for leather. The obtained results fully confirm the theoretical study in which an exponentially increasing relationship between effective diffusivity and temperature is predicted. The results of this study provide a better understanding of the drying mechanisms and may lead to a series of recommendations for leather drying optimization. It opens the possibility for further investigations on the description of drying conditions.

  2. Tannin Fingerprinting in Vegetable Tanned Leather by Solid State NMR Spectroscopy and Comparison with Leathers Tanned by Other Processes

    Directory of Open Access Journals (Sweden)

    Jan H. van der Westhuizen

    2011-01-01

    Full Text Available Solid state 13C-NMR spectra of pure tannin powders from four different sources – mimosa, quebracho, chestnut and tara – are readily distinguishable from each other, both in pure commercial powder form, and in leather which they have been used to tan.  Groups of signals indicative of the source, and type (condensed vs. hydrolyzable of tannin used in the manufacture are well resolved in the spectra of the finished leathers.  These fingerprints are compared with those arising from leathers tanned with other common tanning agents.  Paramagnetic chromium (III tanning causes widespread but selective disappearance of signals from the spectrum of leather collagen, including resonances from acidic aspartyl and glutamyl residues, likely bound to Cr (III structures. Aluminium (III and glutaraldehyde tanning both cause considerable leather collagen signal sharpening suggesting some increase in molecular structural ordering. The 27Al-NMR signal from the former material is consistent with an octahedral coordination by oxygen ligands. Solid state NMR thus provides easily recognisable reagent specific spectral fingerprints of the products of vegetable and some other common tanning processes. Because spectra are related to molecular properties, NMR is potentially a powerful tool in leather process enhancement and quality or provenance assurance.

  3. Tannin fingerprinting in vegetable tanned leather by solid state NMR spectroscopy and comparison with leathers tanned by other processes.

    Science.gov (United States)

    Romer, Frederik H; Underwood, Andrew P; Senekal, Nadine D; Bonnet, Susan L; Duer, Melinda J; Reid, David G; van der Westhuizen, Jan H

    2011-01-28

    Solid state ¹³C-NMR spectra of pure tannin powders from four different sources--mimosa, quebracho, chestnut and tara--are readily distinguishable from each other, both in pure commercial powder form, and in leather which they have been used to tan. Groups of signals indicative of the source, and type (condensed vs. hydrolyzable) of tannin used in the manufacture are well resolved in the spectra of the finished leathers. These fingerprints are compared with those arising from leathers tanned with other common tanning agents. Paramagnetic chromium (III) tanning causes widespread but selective disappearance of signals from the spectrum of leather collagen, including resonances from acidic aspartyl and glutamyl residues, likely bound to Cr (III) structures. Aluminium (III) and glutaraldehyde tanning both cause considerable leather collagen signal sharpening suggesting some increase in molecular structural ordering. The ²⁷Al-NMR signal from the former material is consistent with an octahedral coordination by oxygen ligands. Solid state NMR thus provides easily recognisable reagent specific spectral fingerprints of the products of vegetable and some other common tanning processes. Because spectra are related to molecular properties, NMR is potentially a powerful tool in leather process enhancement and quality or provenance assurance.

  4. Preparation, Characterization and Thermo-Chromic Properties of EVA/VO2 Laminate Films for Smart Window Applications and Energy Efficiency in Building

    Directory of Open Access Journals (Sweden)

    Onruthai Srirodpai

    2017-01-01

    Full Text Available Thermochromic films based on vanadium dioxide (VO2/ethylene vinyl acetate copolymer (EVA composite were developed. The monoclinic VO2 particles was firstly prepared via hydrothermal and calcination processes. The effects of hydrothermal time and tungsten doping agent on crystal structure and morphology of the calcined metal oxides were reported. After that, 1 wt % of the prepared VO2 powder was mixed with EVA compound, using two different mixing processes. It was found that mechanical properties of the EVA/VO2 films prepared by the melt process were superior to those of which prepared by the solution process. On the other hand, percentage visible light transmittance of the solution casted EVA/VO2 film was greater than that of the melt processed composite film. This was related to the different gel content of EVA rubber and state of dispersion and distribution of VO2 within the polymer matrix phase. Thermochromic behaviors and heat reflectance of the EVA/VO2 film were also verified. In overall, this study demonstrated that it was possible to develop a thermochromic film using the polymer composite approach. In this regard, the mixing condition was found to be one of the most important factors affecting morphology and thermo-mechanical properties of the films.

  5. Stability of laminated composites

    Energy Technology Data Exchange (ETDEWEB)

    Guz`, A.N.; Chekhov, V.N. [Inst. of Mechanics of the Academy of Sciences of the Ukrainian, Kiev (Ukraine)

    1992-02-01

    The characteristic special feature of deformation behavior of modern laminated composite materials and structural elements fabricated from these materials, at current levels of loading and operating conditions is the occurrence of the purely three-dimensional stress-deformed state. In this process some specific mechanical phenomena and effects may occur, which is impossible to describe within the framework of applied or approximate approaches existing currently in deformable solid body mechanics. The structure of massive laminated materials may be included in this class of phenomena when the critical parameters of the problem depend only on the ratio between mechanical and geometrical characteristics of single layers and are independent of the dimensions and the form of the total laminated body as a whole. Since this phenomenon may be the beginning of the process of fracture of these materials, and the loss of the load-carrying capacity of structure elements fabricated from them, we consider below, in three-dimensional formulation, the problem of the surface and internal instability in laminated composite materials under compressive surface loads. The classification of the existing types of stability problems is presented for laminated materials and approaches for their solution presented in the literature. On the basis of three-dimensional linearized stability theory, within the framework of the piecewise-homogeneous media model, the general formulation of the most characteristic classes of stability problems of laminated materials is given in Langrangian coordinates at small and finite, homogeneous and inhomogeneous precritical deformation. Analytic and variational methods of investigation of formulated problems are given with application to various models of laminated bodies models, in accordance with accepted stability criteria. The accuracy of these models is evaluated, based on th example of the solution of certain model problems.

  6. 75 FR 15740 - Gallery Leather Company, Inc., Trenton, ME; Notice of Termination of Investigation

    Science.gov (United States)

    2010-03-30

    ... From the Federal Register Online via the Government Publishing Office DEPARTMENT OF LABOR Employment and Training Administration Gallery Leather Company, Inc., Trenton, ME; Notice of Termination of... Leather Company, Inc., Trenton, Maine. The petitioner has requested that the petition be...

  7. Bioethanol Quality Improvement of Coffee Fruit Leather

    Directory of Open Access Journals (Sweden)

    Edahwati Luluk

    2016-01-01

    Full Text Available Recently, Indonesia’s dependence on petroleum is to be reduced and even eliminated. To overcome the problem of finding the needed alternative materials that can produce ethanol, in this case as a substitute material or a transport fuel mix, boosting the octane number, and gasoline ethanol (gasohol can be conducted. In the red coffee processing (cooking that will produce 65% and 35% of coffee beans, coffee leather waste is a source of organic material with fairly high cellulose content of 46.82%, 3.01% of pectin and 7.68% of lignin. In this case, its existence is abundant in Indonesia and optimally utilized. During the coffee fruit peeling, the peel waste is only used as a mixture of animal feed or simply left to rot. The purpose of this study was to produce and improve the quality of the fruit skin of bioethanol from coffee cellulose. However, to improve the quality of bioethanol, the production of the lignin content in the skin of the coffee fruit should be eliminated or reduced. Hydrolysis process using organosolve method is expected to improve the quality of bioethanol produced. In particular, the use of enzyme Saccharomyces and Zymmomonas will change the resulting sugar into bioethanol. On one hand, by using batch distillation process for 8 hours with Saccharomyces, bioethanol obtains high purity which is 39.79%; on the other hand, by using the same batch distillation process with Zymmomonas, the bioethanol obtains 38.78%.

  8. Low temperature conversion of sludge and shavings from leather industry.

    Science.gov (United States)

    Silveira, I C T; Rosa, D; Monteggia, L O; Romeiro, G A; Bayer, E; Kutubuddin, M

    2002-01-01

    Abstract Brazil has one of the largest herds of cattle in the world, with more than 170 million heads. Over 400 farms have exported more than 2,875 ton (in 1997) of leather to Europe. The wet blue tanning process uses chemicals such as chromium compounds and produces liquid wastes that must be treated by physicochemical and biological systems. About 15,000 ton per month of dewatering sludge with 24% solids content is disposed of into landfills. During the process, pre-tanned skins (wet blue leather) are shaved to the desired thickness and the shavings, like sludge, are among the wastes that must have special attention. The organic content and chromium concentration are high. About 12% of the leather production from cattle hides are shavings, and its chromium concentration ranges from 3.5 to 5.5% of dry matter. The Environmentally friendly leather project, a co-operation between Brazilian and German tanneries, universities and technical schools, is looking for process optimisation, waste minimisation and adequate treatment for solid and liquid wastes from the leather industry. This work presents results of Low Temperature Conversion of chrome-containing sludge and shavings in a laboratory batch reactor, offering a solution for these hazardous wastes, recovering the energy content and transforming metals in insoluble sulphides.

  9. A Variable Neighborhood Search Algorithm for the Leather Nesting Problem

    Directory of Open Access Journals (Sweden)

    Cláudio Alves

    2012-01-01

    Full Text Available The leather nesting problem is a cutting and packing optimization problem that consists in finding the best layout for a set of irregular pieces within a natural leather hide with an irregular surface and contour. In this paper, we address a real application of this problem related to the production of car seats in the automotive industry. The high quality requirements imposed on these products combined with the heterogeneity of the leather hides make the problem very complex to solve in practice. Very few results are reported in the literature for the leather nesting problem. Furthermore, the majority of the approaches impose some additional constraints to the layouts related to the particular application that is considered. In this paper, we describe a variable neighborhood search algorithm for the general leather nesting problem. To evaluate the performance of our approaches, we conducted an extensive set of computational experiments on real instances. The results of these experiments are reported at the end of the paper.

  10. Laser Cutting of Leather: Tool for Industry or Designers?

    Science.gov (United States)

    Stepanov, Alexander; Manninen, Matti; Pärnänen, Inni; Hirvimäki, Marika; Salminen, Antti

    Currently technologies which are applied for leather cutting include slitting knifes, die press techniques and manual cutting. Use of laser technology has grown significantly during recent years due to number of advantages over conventional cutting methods; flexibility, high production speed, possibility to cut complex geometries, easier cutting of customized parts, and less leftovers of leather makes laser cutting more and more economically attractive to apply for leather cutting. Laser technology provides advantages in cutting complex geometries, stable cutting quality and possibility to utilize leather material in economically best way. Constant quality is important in industrial processes and laser technology fulfills this requirement: properly chosen laser cutting parameters provides identical cuts. Additionally, laser technology is very flexible in terms of geometries: complex geometries, individual designs, prototypes and small scale products can be manufactured by laser cutting. Variety of products, which needed to be cut in small volumes, is also the application where laser cutting can be more beneficial due to possibility to change production from one product to another only by changing geometry without a need to change cutting tool. Disadvantages of laser processing include high initial investment costs and some running costs due to maintenance and required gas supply for the laser. Higher level of operator's expertise is required due to more complicated machinery in case of laser cutting. This study investigates advantages and disadvantages of laser cutting in different areas of application and provides comparison between laser cutting and mechanical cutting of leather.

  11. COMPOSITES FROM LEATHER INDUSTRY BUFFING DUST: A REVIEW

    Directory of Open Access Journals (Sweden)

    KILIÇ Eylem

    2017-05-01

    Full Text Available Leather buffing dust is a fine powder of collagen fibril waste from milling and buffing operations and constitutes an important part of solid wastes generated from chrome tanned leather production processes. It is one of the difficult tannery wastes to manage and current practice of its disposal includes its incineration and disposal in landfill. The scientific literature reports numerous studies on its utilization in composites formulations. Chrome tanned buffing dust has been used as filler for various polymeric matrices with the aim of producing leather-like composites for potential applications such as hand bags, wallets, key chain holder and purses and footwear products such as shoe soles, insole, heels etc. This paper compiles different research works done by researchers regarding composites made from leather industry buffing dust. The characteristics of composites are also presented by making use of previously published studies carried out with different polymer matrices. Reviewed studies reveal that fiber-reinforced composites utilizing buffing dust provide landfill avoidance, energy conservation, decrease depletion of virgin raw material, enable production of low cost composites with improved mechanical properties that can be used for multifunctional applications and moreover they provide solution to the environmental problems associated with the waste management of the leather industry.

  12. Hysteresis and Stress Relaxation Studies for a Fibrous Collagen Material: Chrome-free Leather

    Science.gov (United States)

    Animal hides are the most valuable coproduct of the meat industry, and most of those hides are converted into leather. Due to concerns over the use and disposal of chrome-tanned leather, the leather industry is now facing increasing scrutiny over its use of chrome as a tanning agent. The use of no...

  13. Mechanical properties and area retention of leather dried with biaxial stretching under vacuum

    Science.gov (United States)

    The conversion of animal hides to leather involves many complicated chemical and mechanical operations. Drying is one of the mechanical operations, and plays a key role in determining the physical properties of leather. It is where leather acquires its final texture, consistency and flexibility. ...

  14. 40 CFR 63.5400 - How do I measure the quantity of leather processed?

    Science.gov (United States)

    2010-07-01

    ... leather processed? 63.5400 Section 63.5400 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY... CATEGORIES National Emission Standards for Hazardous Air Pollutants for Leather Finishing Operations Testing and Initial Compliance Requirements § 63.5400 How do I measure the quantity of leather processed?...

  15. 19 CFR 10.198a - Duty reduction for certain leather-related articles.

    Science.gov (United States)

    2010-04-01

    ... 19 Customs Duties 1 2010-04-01 2010-04-01 false Duty reduction for certain leather-related... Basin Initiative § 10.198a Duty reduction for certain leather-related articles. Except as otherwise..., flat goods, work gloves, and leather wearing apparel that were not designated on August 5, 1983,...

  16. The Mod World of Leather I (Tentative Course Outline), Art Education.

    Science.gov (United States)

    Hilf, Anne C.

    A course, exploring leather skills and decorating techniques for grades 7-12, is presented. The Course Content includes Historical and cultural survey; Leather types; Definitions and application; Plan for working leather; and Tools and equipment. Upon completion of this course the student will be able to do the following: (1) Relate the research…

  17. Biomechanical performance of leather and modern football helmets.

    Science.gov (United States)

    Rowson, Steven; Daniel, Ray W; Duma, Stefan M

    2013-09-01

    With the increased national concern about concussions in football, recent research has focused on evaluating the impact performance of modern football helmets. Specifically, this technical note offers a biomechanical analysis of classic leather helmets compared with modern helmets. Furthermore, modern helmets were examined to illustrate the performance differences between the better- and worse-performing ones. A total of 1224 drop tests were performed from a range of drop heights and impact locations on 11 different helmet types (10 modern and 1 leather helmet model). The resulting head acceleration was used to assess the risk of concussion for each drop test. The results of this analysis demonstrate that modern helmets are significantly and substantially superior to leather helmets in all impact scenarios, and that notable differences exist among modern helmets.

  18. Extraction Of Chromium From Leather Chrome Shaving Dust.

    Directory of Open Access Journals (Sweden)

    Ashiqur Rahaman

    2015-08-01

    Full Text Available Leather processing involves transformation of putrescible animal hides and skin into non putrescible leather. Leather industry generates a huge amount of solid waste containing chromium. These solid wastes were disposed of through land filling which causes leaching out of in soil and water. Now a day increasing environmental legislations have encouraged tannery industry to develop a new technology. In this study we incinerated chrome shaving dust at 500oC to 7000C for chromium extraction. Various oxidizing acids with different concentration were used for chromium extraction. Extracted chromium was measured by Atomic Absorption Spectrometry. Recovery of chromium was in the range of 297 mgL to 222 mgL. Nitric acid extracted maximum amount of chromium while sulfuric acid extracted minimum amount of chromium.

  19. Progress and recent trends in biotechnological methods for leather processing.

    Science.gov (United States)

    Thanikaivelan, Palanisamy; Rao, Jonnalagadda R; Nair, Balachandran U; Ramasami, Thirumalachari

    2004-04-01

    Global environmental regulations are changing the leather-processing industry. Pre-tanning and tanning processes contribute 80-90% of the total pollution in the industry and generate noxious gases, such as hydrogen sulfide, as well as solid wastes, such as lime and chrome sludge. The use of enzyme-based products is currently being explored for many areas of leather making. Furthermore, enzymes are gaining increasing importance in the de-hairing process, eliminating the need for sodium sulfide. This review discusses emerging novel biotechnological methods used in leather processing. One significant achievement is the development of a bioprocess-based de-hairing and fiber-opening methodology to reduce toxic waste.

  20. Processing and Validation of Whey-Protein-Coated Films and Laminates at Semi-Industrial Scale as Novel Recyclable Food Packaging Materials with Excellent Barrier Properties

    Directory of Open Access Journals (Sweden)

    E. Bugnicourt

    2013-01-01

    Full Text Available A biopolymer coating for plastic films was formulated based on whey protein, and its potential to replace current synthetic oxygen barrier layers used in food packaging such as ethylene vinyl alcohol copolymers (EVOH was tested. The whey-coating application was performed at semi-industrial scale. High barrier to oxygen with transmission rate down to ranges of 1 cm3 (STP m−2 d−1 bar−1 at and 50% relative humidity (r.h. but interesting humidity barrier down to ranges of 3 g m−2 d−1 (both normalized to 100 μm thickness were reached, outperforming most existing biopolymers. Coated films were validated for storing various food products showing that the shelf life and sensory attributes were maintained similar to reference packaging films while complying with food safety regulations. The developed whey coating could be enzymatically removed within 2 hours and is therefore compatible with plastic recycling operations to allow multilayer films to become recyclable by separating the other combined layers. A life cycle assessment was performed showing a significant reduction in the environmental impact of the packaging thanks in particular to the possibility of recycling materials as opposed to incinerating those containing EVOH or polyamide (PA, but due to the use of biosourced raw materials.

  1. Tensile stress-strain behavior of hybrid composite laminates

    Science.gov (United States)

    Kennedy, J. M.

    1983-01-01

    A study was made of the stress-strain response of several hybrid laminates, and the damage was correlated with nonlinear stress-strain response and ultimate strength. The fibers used in the laminates were graphite, S-glass, and Kevlar. Some laminates with graphite fibers had perforated Mylar film between plies, which lowered the interlaminar bond strength. The laminate configurations were chosen to be like those of buffer strips in large panels and fracture coupons. Longitudinal and transverse specimens were loaded in tension to failure. Some specimens were radiographed to reveal damage due to edge effects. Stress-strain response is discussed in terms of damage shown by the radiographs. Ultimate strengths are compared with simple failure criteria, one of which account for damage.

  2. Progress in Polyimide Films for Two-Layer Type Flexible Copper Clad Laminate%二层型挠性覆铜板用聚酰亚胺的研究进展

    Institute of Scientific and Technical Information of China (English)

    刁恩晓; 李帆; 舒适; 肖炳瑞; 黄永发; 王平; 刘峰

    2015-01-01

    The fast development of electronic industry puts forward higher requirements for the property of flexible copper clad laminate (FCCL). The research progress of two-layer type FCCL, which using polyimide film as substract, was reviewed from improving the adhesive property, dielectric property and heat resistance, and the research directions of two-layer type FCCL were proposed.%电子行业的快速发展对二层型挠性覆铜板的性能提出了更高的要求,针对以聚酰亚胺薄膜为基底材料的二层型挠性覆铜板,分别从改善粘结性能、介电性能和耐热性能3个方面综述了二层型挠性覆铜板的研究进展,并展望了二层型挠性覆铜板的研究方向。

  3. 78 FR 12716 - Laminated Woven Sacks From the People's Republic of China: Negative Final Determination of...

    Science.gov (United States)

    2013-02-25

    ... method either to an exterior ply of plastic film such as biaxially-oriented polypropylene (``BOPP'') or...: Laminated Woven Sacks From the People's Republic of China, 73 FR 45941 (August 7, 2008); see also Laminated Woven Sacks From the People's Republic of China: Countervailing Duty Order, 73 FR 45955 (August 7,...

  4. 40 CFR Table 1 to Subpart Tttt of... - Leather Finishing HAP Emission Limits for Determining the Allowable HAP Loss

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 12 2010-07-01 2010-07-01 true Leather Finishing HAP Emission Limits... Leather Finishing Operations Pt. 63, Subpt. TTTT, Table 1 Table 1 to Subpart TTTT of Part 63—Leather...), you must meet the appropriate emission limits in the following table: Type of Leather Product...

  5. Comparison of Jacket Production Processes Designed by Fabric Materials and Leather

    Directory of Open Access Journals (Sweden)

    Emine Utkun

    2011-02-01

    Full Text Available Leather and leather products industry has shown a significant improvement in export area, as a result of intensive shuttle trades and demand that comes from crumbling Eastern Bloc countries in 1990's. This development has caused capacity increasing and thus makes large investments in this sector. Leather garment industry differs from woven or fabrics industry at various points. Differantation seems in raw materials features such as size, thickness, biological, chemical or physical homogenity. Due to the natural structure, leather shows different attributes in different regions. This study examines the diversity of production processes of leather and fabric designed jacket.

  6. Collagen orientation and leather strength for selected mammals.

    Science.gov (United States)

    Sizeland, Katie H; Basil-Jones, Melissa M; Edmonds, Richard L; Cooper, Sue M; Kirby, Nigel; Hawley, Adrian; Haverkamp, Richard G

    2013-01-30

    Collagen is the main structural component of leather, skin, and some other applications such as medical scaffolds. All of these materials have a mechanical function, so the manner in which collagen provides them with their strength is of fundamental importance and was investigated here. This study shows that the tear strength of leather across seven species of mammals depends on the degree to which collagen fibrils are aligned in the plane of the tissue. Tear-resistant material has the fibrils contained within parallel planes with little crossover between the top and bottom surfaces. The fibril orientation is observed using small-angle X-ray scattering in leather, produced from skin, with tear strengths (normalized for thickness) of 20-110 N/mm. The orientation index, 0.420-0.633, is linearly related to tear strength such that greater alignment within the plane of the tissue results in stronger material. The statistical confidence and diversity of animals suggest that this is a fundamental determinant of strength in tissue. This insight is valuable in understanding the performance of leather and skin in biological and industrial applications.

  7. Spatial Diffusion of Leather Industries (Case Study at Magetan District

    Directory of Open Access Journals (Sweden)

    Dilahur Dilahur

    2004-01-01

    Full Text Available After the rise and the fall of the tides and the change of the activities as the phenomena which happen in the daily life of sociaety, the hange of spacing or distributionn of industrial businesses becomes one of the new phenomena. The objective of this research is to know the process of the diffusion from leather industry in Magetan Subdistrict. This research uses secondary data analysis and direct observation. The result of this research shows that the change (the rise and fall of the tides in leather industry has producted the movement of distribution or spacing in which the center of the main production is declined and the new center may arise. In this movement, it seems that the existence of the specification on types of activity, like having similar leather, shoescraft, beltcraft, and sendalcraft become the serious phenomena. This kind of the change and its development is signed by the change of position from becoming employee to be new employer, having some employees that may become the employers at any time and so forth. The style of the diffusion which happen is the style of mixing diffusion in which the business on leather industry becomes wider reaching around the village while the original village (Kauman is still as the center of industry, although it has so limited activities because the business is always declined.

  8. Leather Industry Business Linkages (Case Study in District Magetan

    Directory of Open Access Journals (Sweden)

    Dilahur Dilahur

    2004-01-01

    Full Text Available Leather industry in Magetan covers two forms; they are tanning and leathercraft. During 1960 and 1970, the leather industry decreased in its production, but in 1990 Magetan becomes the center of leather industry. Its development appeals to be studied closely. The goals of this study are to know the relation between tanning and leathercraft, the connection between these industries and other economic ativities, and their connection with production factor. This study uses survey methhod. The respondents are taken proportionally from both of those leather industries. The data is obtained inetrviewing the respondents with questionnaire that related to the input and out put of the industry. The result of this study shows that there is no relationship between the kind of industries (small and household industry and its capital, especially in its raw material (44,44%. The relationship between tanning and leathercraft is low, because it is only 24,2% input of leathercraft which taken from output of tanning. The region relationship for tanning is larger, because the products that are sold to other regions are 97,22% for tanning and 68,29% for leathercraft. Its relationship to other sectors especially for labour supply is 56,48% from farming and trade sectors in marketing.

  9. ON THE THERMAL BEHAVIOR OF DIFFERENT TANNED BOVINE LEATHERS

    Directory of Open Access Journals (Sweden)

    VARGANICI Cristian-Dragoş

    2017-05-01

    Full Text Available Leather is one of the most globally spread biomaterial which is obtained by the processing of different animal skins. It encompasses a wide palette of applications, from footwear and clothing to upholsteries and different types of furniture [1], [2], [3]. The main constituent of animal skins is collagen, a supramolecular fibrillar protein in the form of a triple helix. This form endows leather with elasticity, good mechanical properties and softness. A major disadvantage resides in the inapplicability of raw animal hides, due to their microbiological instability and decay through rotting. Microbiological stability is obtained through the tanning process, characterized by protein crosslinking and drying afterwards. After tanning the leather exhibits the required properties for the desired specific applications in terms of aspect, availability and sustainability [4], [5]. The study aims to elucidate the thermal decomposition process of chrome-free tanned bovine hide (wet-white using a new product based on titanium and aluminium salts compared with the same hide tanned by chromium salts (wet-blue. The thermal behavior was studied by dynamic thermogravimetry in nitrogen atmosphere, up to 700 oC. A comparative thermal decomposition study between the different tanned bovine leathers was undertaken.

  10. STRUCTURAL ANALYSIS OF WOOD-LEATHER PANELS BY RAMAN SPECTROSCOPY

    Directory of Open Access Journals (Sweden)

    Tilman Grünewald,

    2012-02-01

    Full Text Available Besides other ligno-cellulosic materials such as straw, rice husks, or bagasse, wet blue particles from leather production are a promising new raw material stock for wood-based panels, as they offer not only a high availability, but increase the properties of the panel with regard to fire resistance or mechanical characteristics. A panel with a mixture of 42.5% wood fibers, 42.5% wet blue leather particles, and 15% lignin adhesive was produced, and an inhomogeneous sample was prepared. An area of 9 x 10 mm was rasterized and scanned by means of Raman Spectroscopy. Furthermore, the reference spectra of the constituents, i.e. wood fiber, wet blue leather particle, and lignin powder were recorded. The obtained data were treated and analyzed using chemometric methods (principal components analysis PCA and cluster analysis. An important finding was that the reference data were not directly represented in the panels’ spectra, and the correlation matrix of the PCA was not applicable to the panel data. This indicated that chemical changes might take place during the pressing. After processing the panel Raman spectra with the help of PCA and cluster analysis, three distinctive clusters were obtained, discriminating wood, leather, and mixed regions. With the assigned spectral information, it was possible to create a spectral image of the surface.

  11. Ultrasound assisted chrome tanning: Towards a clean leather production technology.

    Science.gov (United States)

    Mengistie, Embialle; Smets, Ilse; Van Gerven, Tom

    2016-09-01

    Nowadays, there is a growing demand for a cleaner, but still effective alternative for production processes like in the leather industry. Ultrasound (US) assisted processing of leather might be promising in this sense. In the present paper, the use of US in the conventional chrome tanning process has been studied at different pH, temperature, tanning time, chrome dose and US exposure time by exposing the skin before tanning and during tanning operation. Both prior exposure of the skin to US and US during tanning improves the chrome uptake and reduces the shrinkage significantly. Prior exposure of the skin to US increase the chrome uptake by 13.8% or reduces the chrome dose from 8% to 5% (% based on skin weight) and shorten the process time by half while US during tanning increases the chrome uptake by 28.5% or reduces the chrome dose from 8% to 4% (half) and the tanning time to one third compared to the control without US. Concomitantly, the resulting leather quality (measured as skin shrinkage) improved from 5.2% to 3.2% shrinkage in the skin exposed to US prior tanning and to 1.3% in the skin exposed to US during the tanning experiment. This study confirms that US chrome tanning is an effective and eco-friendly tanning process which can produce a better quality leather product in a shorter process time with a lower chromium dose.

  12. Coverage of Indian leather patents in chemical abstracts

    Science.gov (United States)

    Meenakshi; Amba

    2000-03-01

    Patent information is increasingly becoming important in the current context of international trade and commerce. The printed version of Chemical Abstracts still continues to be used heavily, and it was evaluated as the source of information on Indian patents using leather patents as a case study. The results of the study are given.

  13. 78 FR 13083 - Products Having Laminated Packaging, Laminated Packaging, and Components Thereof; Notice of...

    Science.gov (United States)

    2013-02-26

    ... COMMISSION Products Having Laminated Packaging, Laminated Packaging, and Components Thereof; Notice of... Commission has received a complaint entitled Products Having Laminated ] Packaging, Laminated Packaging, and Components Thereof, DN 2940; the Commission is soliciting comments on any public interest issues raised...

  14. 78 FR 19007 - Certain Products Having Laminated Packaging, Laminated Packaging, and Components Thereof...

    Science.gov (United States)

    2013-03-28

    ... COMMISSION Certain Products Having Laminated Packaging, Laminated Packaging, and Components Thereof... importation of certain products having laminated packaging, laminated packaging, and components thereof by... Investigation: Having considered the complaint, the U.S. International Trade Commission, on March 22,...

  15. Roles of Poly(propylene Glycol) During Solvent-Based Lamination of Ceramic Green Tapes

    Science.gov (United States)

    Suppakarn, Nitinat; Ishida, Hatsuo; Cawley, James D.; Levine, Stanley R. (Technical Monitor)

    2000-01-01

    Solvent lamination for alumina green tapes is readily accomplished using a mixture of ethanol, toluene and poly(propylene glycol). After lamination, the PPG is clearly present as a discrete film at the interface between the laminated tapes. This condition, however, does not generate delamination during firing. Systematic sets of experiments are undertaken to determine the role of PPG in the lamination process and, specifically, the mechanism by which it is redistributed during subsequent processing. PPG slowly diffuses through the organic binder film at room temperature. The PPG diffusion rapidly increases as temperature is increased to 80 C. The key to the efficiency of adhesives during green-tape lamination is mutual solubility of the nonvolatile component of the glue and the base polymeric binder.

  16. NEW ECO-EFFICIENT PRODUCTS USED IN LEATHER INDUSTRY

    Directory of Open Access Journals (Sweden)

    ROSU Dan

    2016-05-01

    Full Text Available In today's move to "sustainable production" the leather industry, as well as many other industries is recognized as a polluting one. Traditional chemical operations are polluting because of the levels of inorganic chemical waste. Process chemicals which are not consumed within the reactions necessary to convert collagen to leather are currently discharged to waste. These are usually applied during bulk production, such as inorganic agents from beam house and tanning processes, e.g. lime, sulphide, ammonium salts, sulphuric acid and sodium chloride, mineral tanning agents – mainly Cr(III and the less common Al(III, Zr(III, Ti(III, Fe(III salts -, whereas depending on the tanning process and the leather article produced organic chemical waste discharged comprises aldehydic and polyphenolic tanning products, bating enzymes, organic carboxylic acids and excess electrolyte stable synthetic fat liquors. It is rare for chemicals and water to be recovered for re-use from several of these process steps. Moreover, tanners worldwide are required to operate within strict legislative boundaries. Serious drawbacks continuously arise concerning the chrome–tanning process in leather industry and the environmental hazardous consequences of chromium containing effluents. In order to overcome this impediment, a great deal of research has been focused on developing chrome–free tanning methods in the past years, such as titanium tanning. In the present study, Ti–Al tanned bovine leather was characterized by means of SEM microscopy, EDAX elemental analysis, ATR–FTIR spectroscopy, thermogravimetry TGA, and differential scanning calorimetry DSC techniques.

  17. TANNED LEATHERS PROPERTIES MODIFICATION AS A RESULT OF ARTIFICIAL AGEING

    Directory of Open Access Journals (Sweden)

    ROŞU Dan

    2017-05-01

    Full Text Available Leather is a high tech material with different application fields, such as automotive, manufacturing of leatherwear articles or clothing and footwear. Leather is a biomaterial obtained by processing animal skins. Unfortunately, raw animal hides are practically inutilizable, due to their microbiological instability and are affected by rotting. Microbiological stability is achieved by tanning, when the protein is crosslinked, followed by drying. After crosslinking and drying, the new material shows the required properties of sustainability, availability and an esthetically pleasing aspect to the touch, making it available across its entire range of applications. From a structural point of view the animal skins are constituted of collagen, which is a fibrilar protein with a high degree of supramolecular organization in triple helix form that endows softness, elasticity and mechanical strength. High quality standards and lack of toxicity are required in all cases. Leather colour changes during exposure to light radiations are considered a consequence of the presence of some products with weak photochemical resistance during fabrication. The study aims to compare changes in properties of leathers obtained using mineral tanning agents such as Cr III salts and those obtained with the more environment-friendly technology using acid hydrolysis. Accelerated aging studies were conducted on tanned leathers by exposing the samples to UV radiation with different irradiation doses and two wavelengths (254 and 365 nm under controlled humidity and temperature conditions. Structural changes caused by irradiation were studied by FTIR. Colour changes on the sample surfaces were assessed during irradiation with the CIEL a*b* system. The colour parameters variation (L*, a*, b* and colour differences have been discussed in correlation with structural changes, tanning method and irradiation conditions.

  18. Collagen fibril orientation in ovine and bovine leather affects strength: a small angle X-ray scattering (SAXS) study.

    Science.gov (United States)

    Basil-Jones, Melissa M; Edmonds, Richard L; Cooper, Sue M; Haverkamp, Richard G

    2011-09-28

    There is a large difference in strength between ovine and bovine leather. The structure and arrangement of fibrous collagen in leather and the relationship between collagen structure and leather strength has until now been poorly understood. Synchrotron based SAXS is used to characterize the fibrous collagen structure in a series of ovine and bovine leathers and to relate it to tear strength. SAXS gives quantitative information on the amount of fibrous collagen, the orientation (direction and spread) of the collagen microfibrils, and the d-spacing of the collagen. The amount of collagen varies through the thickness of the leather from the grain to the corium, with a greater concentration of crystalline collagen measured toward the corium side. The orientation index (OI) is correlated strongly with strength in ovine leather and between ovine and bovine leathers. Stronger leather has the fibrils arranged mostly parallel to the plane of the leather surface (high OI), while weaker leather has more out-of-plane fibrils (low OI). With the measurement taken parallel to the animal's backbone, weak (19.9 N/mm) ovine leather has an OI of 0.422 (0.033), stronger (39.5 N/mm) ovine leather has an OI of 0.452 (0.033), and bovine leather with a strength of (61.5 N/mm) has an OI of 0.493 (0.016). The d-spacing profile through leather thickness also varies according to leather strength, with little variation being detected in weak ovine leather (average=64.3 (0.5) nm), but with strong ovine leather and bovine leather (which is even stronger) exhibiting a dip in d-spacing (from 64.5 nm at the edges dropping to 62 nm in the center). This work provides a clear understanding of a nanostructural characteristic of ovine and bovine leather that leads to differences in strength.

  19. The status and developments of leather solid waste treatment: A mini-review.

    Science.gov (United States)

    Jiang, Huiyan; Liu, Junsheng; Han, Wei

    2016-05-01

    Leather making is one of the most widespread industries in the world. The production of leather goods generates different types of solid wastes and wastewater. These wastes will pollute the environment and threat the health of human beings if they are not well treated. Consequently, the treatment of pollution caused by the wastes from leather tanning is really important. In comparison with the disposal of leather wastewater, the treatment of leather solid wastes is more intractable. Hence, the treatment of leather solid wastes needs more innovations. To keep up with the rapid development of the modern leather industry, various innovative techniques have been newly developed. In this mini-review article, the major achievements in the treatment of leather solid wastes are highlighted. Emphasis will be placed on the treatment of chromium-tanned solid wastes; some new approaches are also discussed. We hope that this mini-review can provide some valuable information to promote the broad understanding and effective treatment of leather solid wastes in the leather industry.

  20. Controlling Laminate Plate Elastic Behavior

    OpenAIRE

    Mareš, T.

    2004-01-01

    This paper aims to express the relation of a measure of laminate plate stiffness with respect to the fiber orientation of its plies. The inverse of the scalar product of the lateral displacement of the central plane and lateral loading of the plate is the measure of laminate plate stiffness. In the case of a simply supported rectangular laminate plate this measure of stiffness is maximized, and the optimum orientation of its plies is searched.

  1. The production and utilization of leather fertilizer manufactured from the leather solid waste%制革固态废料生产皮肥及其用途

    Institute of Scientific and Technical Information of China (English)

    邵泽恩; 解守岭; 李士英

    2001-01-01

    本文综述了制革固体废料制取皮肥的生产工艺和在农业上的应用。%The article describes the producing technology of leather fertilizer which made from the solid waste in leather industry, and its utilization in farming.

  2. Laminated active matrix organic light-emitting devices

    Science.gov (United States)

    Liu, Hongyu; Sun, Runguang

    2008-02-01

    Laminated active matrix organic light-emitting device (AMOLED) realizing top emission by using bottom-emitting organic light-emitting diode (OLED) structure was proposed. The multilayer structure of OLED deposited in the conventional sequence is not on the thin film transistor (TFT) backplane but on the OLED plane. The contact between the indium tin oxide (ITO) electrode of TFT backplane and metal cathode of OLED plane is implemented by using transfer electrode. The stringent pixel design for aperture ratio of the bottom-emitting AMOLED, as well as special technology for the top ITO electrode of top-emitting AMOLED, is unnecessary in the laminated AMOLED.

  3. Optimization of composite laminates

    Science.gov (United States)

    Gurdal, Zafer; Haftka, Raphael T.

    Design of composite structures can be viewed as a multi-faceted task, one which requires integration of issues related to composite mechanics, structural analysis, optimization, and manufacturing. The major coverage of the paper is on the issue of optimization, with special emphasis on the use of optimization for designing with discrete and integer valued variables required for the stacking-sequence optimization. Different techniques that can be used for stacking sequence optimization are introduced, and different aspects of their application are demonstrated for laminate buckling optimization.

  4. Internationalisation Barriers of Small and Medium-sized Manufacturing Enterprises in Ethiopia: Leather and Leather Products Industry in Focus

    Directory of Open Access Journals (Sweden)

    Yehualashet Demeke Lakew

    2015-11-01

    Full Text Available The purpose of this study was to examine internationalisation barriers of manufacturing SMEs operating in Leather and Leather Products Industry located in the capital city of Ethiopia. The small and medium sized enterprises (SMEs sector in Ethiopia is a significant group within the economy in terms of firm numbers and total employment. However, the SMEs sector’s share of exports is disproportionately small, which raised considerable research concerns. Firm export propensity was the dependent variable and internal and external export barrier factors were used as explanatory variables. The study was conducted through mixed research design of quantitative survey and case study. From the population of manufacturing SMEs operating in the Leather and Leather products Industry, a sample was selected through the use of stratified random sampling to ensure the effective representation of the population of exporting and non-exporting SMEs in the capital of Ethiopia. In order to complement survey results nine (4 exporting and 5 non-exporting SMEs were selected through critical case purposive sampling and an in-depth interviews were conducted. Statistical package for the social sciences (SPSS 20 was used to analyse the quantitative data whereas, qualitative data were analysed manually. Exploratory factor analysis with Varimax rotation and Binary logistic regression analysis are the analytical methods used. The statistical result showed that, logistics problem, insufficient finance, functional barriers, lack of export knowledge and information, procedural barriers and international trade barriers are the most significant obstacles of export trade in Ethiopia. The overall results revealed that explanatory variables used in the analysis significantly predict the dependent variable at 95% confidence level. Taken together, these results prompted the presentation of numerous implications for theory, practice, and future research. Finally, the paper recommended

  5. The Effect of Thermal Lamination Processes on Colorimetric Change in Spot Colours

    Directory of Open Access Journals (Sweden)

    Eduard Galić

    2015-03-01

    Full Text Available Understanding the effect of laminating processes on spot colours is of great importance in the offset printing process, especially given the application versatility of spot colours. Laminating process, as a very common process and one of the first in a sequence of finishing processes in graphics production, can affect print’s visual impression to varying degrees. Spot colours, as mixtures of different ratios of inks, are subject to a change due to matt or gloss lamination process. The research examined the impact of thermal lamination processes on printed spot colours on different printing substrates. The degree of change on prints caused by laminating films in the thermal process was determined using spectrophotometric and densitometric methods. Particular emphasis is placed on the spot colour because of its specific characteristics. Research results are shown in charts and they are showing clearly the modality and the extent laminating processes effect the colorimetric difference in laminated and non-laminated prints. This scientific research provides objective conclusions that help in predicting the possible variations within the usage of laminating processes.

  6. Molecular spectroscopic study for suggested mechanism of chrome tanned leather

    Science.gov (United States)

    Nashy, Elshahat H. A.; Osman, Osama; Mahmoud, Abdel Aziz; Ibrahim, Medhat

    2012-03-01

    Collagen represents the structural protein of the extracellular matrix, which gives strength of hides and/or skin under tanning process. Chrome tan is the most important tanning agent all over the world. The methods for production of leather evolved over several centuries as art and engineering with little understanding of the underlying science. The present work is devoted to suggest the most probable mechanistic action of chrome tan on hide proteins. First the affect of Cr upon hide protein is indicated by the studied mechanical properties. Then the spectroscopic characterization of the hide protein as well as chrome tanned leather was carried out with Horizontal Attenuated Total Reflection (HATR) FT-IR. The obtained results indicate how the chromium can attached with the active sites of collagen. Molecular modeling confirms that chromium can react with amino as well as carboxylate groups. Four schemes were obtained to describe the possible interactions of chrome tan with hide proteins.

  7. The Development of Laminated Armor

    Science.gov (United States)

    1948-09-27

    band saw, By using a piece of soft wood under the laminate while it was being cut, fraying of the edge was reduced to a minimum, especially in paneJs of...c. ’ LEGEND L LUMITE (SARAN) * ALL LAMINATE Rf RAYON (FQRTISAN) 20-30 OZ/FT 0-- Rc RAYON (CELANESE) ... 20-30...... X× GwLOss GLASS FLOSS Ir

  8. Self-Healing Laminate System

    Science.gov (United States)

    Beiermann, Brett A. (Inventor); Keller, Michael W. (Inventor); White, Scott R. (Inventor); Sottos, Nancy R. (Inventor)

    2016-01-01

    A laminate material may include a first flexible layer, and a self-healing composite layer in contact with the first flexible layer. The composite layer includes an elastomer matrix, a plurality of first capsules including a polymerizer, and a corresponding activator for the polymerizer. The laminate material may self-heal when subjected to a puncture or a tear.

  9. EXPERIMENTAL RESEARCH REGARDING LEATHER APPLICATIONS IN PRODUCT DESIGN

    Directory of Open Access Journals (Sweden)

    PRALEA Jeni

    2015-05-01

    Full Text Available This paper presents the role and importance of experimental research in design activity. The designer, as a researcher and a project manager, proposes to establish a relationship between functional-aesthetic-constructive-technological-economic,based on the aesthetic possibilities of the materials used for the experiments. With the aim to identify areas for the application of leather waste resulted from the production process, the paper presents experiments conducted with this material in combination with wood, by using different techniques that lead to different aesthetic effects. Identifying the areas to use and creating products from leather and/or wood waste, is based on the properties of these materials. Leather, the subject of these experiments, has the advantage that it can be used on both sides. Tactile differences of the two sides of this material has both aesthetical and functional advantages, which makes it suitable for applications on products that meet the requirements of "design for all". With differentiated tactile characteristics, in combination with other materials, for these experiments wood, easily "read touch" products can be generated to help people with certain disabilities. Thus, experiments presented in this paper allows the establishment of aesthetic schemes applicable to products that are friendly both with the environment (based on the reuse of wood and leather waste and with the users (can be used as applications, accessories and concepts of products for people with certain disabilities. The designer’s choices or decisions can be based on the results of this experiment. The experiment enables the designer to develop creative, innovative and environmentally friendly products.

  10. Study of the dechroming of tanned leather wastes

    OpenAIRE

    Botić Tatjana; Ilišković Nadežda V.; Drljača Dijana

    2004-01-01

    According to European legislation, it is not possible to dump any chromium-containing waste in Europe. The minimization of wastes is a key element in that strategy. It involves the application of clean technologies: low and non-waste technologies. The tanning industry generates substantial quantities of chromium-containing solid waste in the form of shavings and trimmings. The recycling and reuse of those wastes must be the primary target in optimizing processes of the leather industry. The p...

  11. Sono-leather technology with ultrasound: a boon for unit operations in leather processing - review of our research work at Central Leather Research Institute (CLRI), India.

    Science.gov (United States)

    Sivakumar, Venkatasubramanian; Swaminathan, Gopalaraman; Rao, Paruchuri Gangadhar; Ramasami, Thirumalachari

    2009-01-01

    Ultrasound is a sound wave with a frequency above the human audible range of 16 Hz to 16 kHz. In recent years, numerous unit operations involving physical as well as chemical processes are reported to have been enhanced by ultrasonic irradiation. There have been benefits such as improvement in process efficiency, process time reduction, performing the processes under milder conditions and avoiding the use of some toxic chemicals to achieve cleaner processing. These could be a better way of augmentation for the processes as an advanced technique. The important point here is that ultrasonic irradiation is physical method activation rather than using chemical entities. Detailed studies have been made in the unit operations related to leather such as diffusion rate enhancement through porous leather matrix, cleaning, degreasing, tanning, dyeing, fatliquoring, oil-water emulsification process and solid-liquid tannin extraction from vegetable tanning materials as well as in precipitation reaction in wastewater treatment. The fundamental mechanism involved in these processes is ultrasonic cavitation in liquid media. In addition to this there also exist some process specific mechanisms for the enhancement of the processes. For instance, possible real-time reversible pore-size changes during ultrasound propagation through skin/leather matrix could be a reason for diffusion rate enhancement in leather processing as reported for the first time. Exhaustive scientific research work has been carried out in this area by our group working in Chemical Engineering Division of CLRI and most of these benefits have been proven with publications in valued peer-reviewed international journals. The overall results indicate that about 2-5-fold increase in the process efficiency due to ultrasound under the given process conditions for various unit operations with additional benefits. Scale-up studies are underway for converting these concepts in to a real viable larger scale operation. In

  12. EVALUATION OF LEATHER QUALITY AND ECOTOXICITY IN SIMULATED TANNERY WASTEWATERS USING MIMOSA TANNIN

    Directory of Open Access Journals (Sweden)

    ÇELİK Cem

    2016-05-01

    Full Text Available The leather tanning industry is characterized by the production of different kinds of effluents, generated in each step of leather processing. These effluents have various chemical compounds which may cause toxicity and endocrine disruption and are thus known as endocrine disrupting chemicals (EDC. Tanning stabilizes the protein structure of the hide and imparts heat stability, enhanced tensile properties, and resistance to microbial degradation. Currently most high quality leather is "chrome-tanned," produced by treatment of the hide with salts of the mineral chromium. In this study, the wastewater characteristics and ecotoxicity before and after tanning and retanning processes using mimosa tannin are assessed. Vegetable leather production procedure was followed using one dose mimosa tannin. Leather quality was evaluated according to standard methods. Wastewater characteristics showed that mimosa contributed high organic content to the wastewater. Although vegetable tannin was used the effluent toxicity was observed in tanning and retanning effluents. The preliminary results also showed that leather quality tests failed or at minimum level to comply with the standard values indicating that there is still a need to optimize the procedure including mimosa dose. This study was designed to produce eco-friendly leather using mimosa in tanning and retanning processes. Leather quality and the ecotoxicity of each process during leather production was assessed according to standard methods.

  13. COMPARATIVE ADVANTAGE OF LEATHER INDUSTRY IN PAKISTAN WITH SELECTED ASIAN ECONOMIES

    Directory of Open Access Journals (Sweden)

    Sadaf Shahab

    2013-01-01

    Full Text Available The aim of this paper is to analyze the trade specialization in the leather products between some selected Asian economies, with particular focus on Pakistan. For which, a measure of Revealed Comparative Advantage (RCA Balassa Index is used. The analysis shows that Pakistan has a high comparative advantage in leather products over all the selected economies during the period of study. The paper highlights the problems faced by the leather industry and identifies some immediate policy action to be taken to improve the performance of the leather industry in the light of evidence.

  14. Effect of Finishing on Heat and Moisture Transfer Properties of Lining Leather for Shoes

    OpenAIRE

    角田, 由美子

    2016-01-01

      Leather lining for shoes was made from unfinished and pigment-finished glutaraldehyde-tanned leather and chrome-tanned leather prepared from pig skin. The effect of the different treatments on the heat and moisture transfer properties of the lining leather was investigated at 20℃ and 65% RH using an apparatus that simulates the microclimate of the shoes. The apparatus was developed by modeling the conditions expected during actual shoe wearing.  1. The water absorption, water vapour permeab...

  15. Finished leather waste chromium acid extraction and anaerobic biodegradation of the products.

    Science.gov (United States)

    Ferreira, Maria J; Almeida, Manuel F; Pinho, Sílvia C; Santos, Isabel C

    2010-06-01

    Due to the amounts of chromium in the leachate resulting from leather leaching tests, chromium sulfate tanned leather wastes are very often considered hazardous wastes. To overcome this problem, one option could be recovering the chromium and, consequently, lowering its content in the leather scrap. With this objective, chromium leather scrap was leached with sulfuric acid solutions at low temperature also aiming at maximizing chromium removal with minimum attack of the leather matrix. The effects of leather scrap dimension, sulfuric acid and sodium sulfate concentration in the solutions, as well as extraction time and temperature on chromium recovery were studied, and, additionally, organic matrix degradation was evaluated. The best conditions found for chromium recovery were leather scrap conditioning using 25mL of concentrated H(2)SO(4)/L solution at 293 or 313K during 3 or 6days. Under such conditions, 30-60+/-5% of chromium was recovered and as low as 3-6+/-1% of the leather total organic carbon (TOC) was dissolved. Using such treatment, the leather scrap area and volume are reduced and the residue is a more brittle material showing enhanced anaerobic biodegradability. Although good recovery results were achieved, due to the fact that the amount of chromium in eluate exceeded the threshold value this waste was still hazardous. Thus, it needs to be methodically washed in order to remove all the chromium de-linked from collagen.

  16. Pemanfaatan kulit belahan untuk leather goods dengan tipe finis “ fancy good”

    Directory of Open Access Journals (Sweden)

    Widari Widari

    1992-04-01

    Full Text Available The material used in this experimental was the cow hide splite, processed for leather goods. As a leather goods, the split must be have the certain requirements e.g. a good rubfastness and flexing. To reach this condition, one of the most important factors is good finishing application. To gain the leather goods from split with better in their performance and quality used “ Fancy Good” type finish. The testing result (organoleptic, physic and chemical fulfill the IIS 0018-79: The Quality and Testing of Box Leather.

  17. Analysis of transient temperature field of the laminate composite membrane in space environment

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    The on-orbit transient temperature of reflector laminate film was analyzed by using finite element method (FEM) . Numerical simulation was used by FEM software ANSYS. Results reveal that the temperature levels of the laminate composite membrane alternate greatly in the orbital period, which is about ±80℃. This range exceeds the material's operating temperature level. So it is necessary to put effective thermal control into effect to the laminate composite membrane. There is temperature gradient in the thickness direction of the laminate composite membrane: there is a light change in Kevlar/Epoxy layer. The temperature of the laminate composite membrane is obviously lower than the seam's temperature. Results provide reference to the thermal control of the inflatable reflector with high precision requirement.

  18. Assembly of lamins in vitro

    Institute of Scientific and Technical Information of China (English)

    MINGUNGWEI; XIANGJUNTONG; 等

    1996-01-01

    After lamins A,B and C were isolated and purified from rat liver,their assembly properties were examined by electron microscopy and scanning tunneling microscopy by electron microscopy and scanning tunneling microscopy using negative staining and the glycerol coating method,respectively.By varying the assembly time or the ionic conditions under which polymerization takes place,we have observed different stages of lamin assembly,which may provide clues on the structure of the 10 nm lamin filaments.At the first level of structural organization,two lamin polypeptides associate laterally into dimers with the two domains being parallel and in register.At the second level of structural organization,two dimers associate in a half-staggered and antiparallel fashion to form a tetramer 75 nm in length.At the third level of structural organization,4-10 lamin tetramers associate laterally in register to form 75 nm long 10nm filaments,which in turn combine head to head into long,fully assembled lamin filaments.The assembled lamin filaments are nonpolar.

  19. Graphite/epoxy Composite Laminates with Co-cured Interlaminar Damping Layers

    Science.gov (United States)

    Pereira, J. Michael

    1993-01-01

    Damped composite laminates were fabricated by co-curing viscoelastic damping film with graphite/epoxy prepreg plies. The dynamic response of the damped plates was measured using an impulse response technique and compared with the response of similar undamped laminates. Modal damping was computed from the frequency response data. Micrographs of the damped laminates showed that the damping layers retained their integrity during the fabrication process. The layers significantly increased the damping in the composite laminates. The use of the constrained viscoelastic film as an integral part of composite structures appears to be a feasible approach to passive vibration control. Composite plates manufactured with co-cured damping layers may have commercial applications in cases where light weight, strength, and vibration and noise reduction are important considerations.

  20. Use of high molecular weight biopolymers to improve the properties of chrome-free leather

    Science.gov (United States)

    In prior studies, we addressed the problems of poor leather quality, specifically “spring break” hides, by utilizing fillers produced from enzymatically-modified waste proteins, in particular those proteins from the leather and dairy industry (low quality gelatins and caseins or whey). In a more re...

  1. Fluctuations in the prevalence of chromate allergy in Denmark and exposure to chrome-tanned leather

    DEFF Research Database (Denmark)

    Carøe, Caroline; Andersen, Klaus E; Thyssen, Jacob P;

    2010-01-01

    A recent Danish study showed a significant increase in the prevalence of chromate contact allergy after the mid-1990s, probably as a result of exposure to leather products.......A recent Danish study showed a significant increase in the prevalence of chromate contact allergy after the mid-1990s, probably as a result of exposure to leather products....

  2. The Preservation of Leather Bindings: Background, Organization of a Project, and Procedures.

    Science.gov (United States)

    Brown, Meredith

    This manual, intended primarily for use by preservation supervisors, includes a discussion of basic leather preservation techniques, and a description of the entire leather book preservation program at Olin Library, Cornell University. Discussions of work flow, materials, treatment steps, schedulinq, and recruiting student assistants are included.…

  3. A STUDY ON USING 3D VISUALIZATION AND SIMULATION PROGRAM (OPTITEX 3D ON LEATHER APPAREL

    Directory of Open Access Journals (Sweden)

    Ork Nilay

    2016-05-01

    Full Text Available Leather is a luxury garment. Design, material, labor, fitting and time costs are very effective on the production cost of the consumer leather good. 3D visualization and simulation programs which are getting popular in textile industry can be used for material, labor and time saving in leather apparel. However these programs have a very limited use in leather industry because leather material databases are not sufficient as in textile industry. In this research, firstly material properties of leather and textile fabric were determined by using both textile and leather physical test methods, and interpreted and introduced in the program. Detailed measures of an experimental human body were measured from a 3D body scanner. An avatar was designed according to these measurements. Then a prototype dress was made by using Computer Aided Design-CAD program for designing the patterns. After the pattern making, OptiTex 3D visualization and simulation program was used to visualize and simulate the dresses. Additionally the leather and cotton fabric dresses were sewn in real life. Then the visual and real life dresses were compared and discussed. 3D virtual prototyping seems a promising potential in future manufacturing technologies by evaluating the fitting of garments in a simple and quick way, filling the gap between 3D pattern design and manufacturing, providing virtual demonstrations to customers.

  4. APPLICATION OF THE COLLAGENOUS FIBER FROM THE SOLID WASTES OF LEATHER FOR PAPERMAKING

    Institute of Scientific and Technical Information of China (English)

    Zhijie Wang; Jian Wang; Zhang Chuanbo; Hou Xiaodong

    2004-01-01

    The capability of pulping for the solid waste of leather was investigated. The properties of paper that made up of collagenous fiber and plant fiber were also analyzed. The result showed that by proper treatment, solid waste of leather could be made into collagen fiber for papermaking. The physical strength of paper can be enhanced by appending collagenous fiber in a proper propriety.

  5. Properties, performance and current status of the laminated electrochromic glass of Gesimat

    Energy Technology Data Exchange (ETDEWEB)

    Kraft, Alexander; Rottmann, Matthias [Gesimat GmbH, Koepenicker Str. 325, 12555 Berlin (Germany)

    2009-12-15

    In the last 10 years Gesimat has developed a large-area electrochromic glazing with an advanced polymer electrolyte and tungsten oxide and Prussian Blue as complementary electrochromic layers. This electrochromic glass has a switching range between 75% and 8% visible transmittance and between 56% and 6% solar transmittance. The polymer electrolyte is based on polyvinyl butyral (PVB), a polymer in use as an interlayer for laminated safety glass since more than 60 years. The electrochromic films are deposited by a new large-area electrodeposition process. For lamination the standard methods of laminated safety glass production can be used. (author)

  6. Leather Contains Cobalt and Poses a Risk of Allergic Contact Dermatitis

    DEFF Research Database (Denmark)

    Hamann, Dathan; Hamann, Carsten R; Kishi, Patrick

    2016-01-01

    BACKGROUND: Cobalt was recently identified in a leather couch responsible for dermatitis. Cobalt content/release in leather in the United States is unknown. We evaluated leather for cobalt content/release and investigated screening methods for identifying cobalt in leather. METHODS: One hundred...... thirty-one leather swatches were screened for cobalt content/release with X-ray fluorescence (XRF) spectrometry and cobalt indicator solution (CIS). Samples with positive screens and 1 negative control were analyzed using inductively-coupled plasma mass spectrometry (ICPMS). RESULTS: CIS showed that 5...... of 131 samples contained cobalt, subsequently found to be between 1 and 190 parts per million (ppm) when evaluated with ICPMS. The XRF analysis showed that 6 samples contained >5% cobalt, subsequently found to contain greater than 300 ppm cobalt by ICPMS. 7 of 12 tested swatches contained cobalt...

  7. Allergic contact dermatitis caused by cobalt in leather – clinical cases

    DEFF Research Database (Denmark)

    Bregnbak, David; Opstrup, Morten S.; Jellesen, Morten Stendahl

    2017-01-01

    In 2013, we raised suspicion that cobalt in leather could be responsible for hitherto unrecognized cases of allergic contact dermatitis. We saw a patient sensitized only to cobalt with clear long-term exposure to cobalt from a leather sofa, and observed resolution of dermatitis following avoidance...... [1]. In 2014, we performed a questionnaire study, which showed a positive and significant association between cobalt allergy and a history of dermatitis caused by non-occupational exposure to leather articles [2]. Recently, we published an article showing high amounts of cobalt in selected leather...... swatches from furniture [3]. Here, we report 2 additional cases of allergic cobalt dermatitis caused by consumer leather exposure, to increase awareness about this topic....

  8. Protein footprinting by pyrite shrink-wrap laminate.

    Science.gov (United States)

    Leser, Micheal; Pegan, Jonathan; El Makkaoui, Mohammed; Schlatterer, Joerg C; Khine, Michelle; Law, Matt; Brenowitz, Michael

    2015-04-07

    The structure of macromolecules and their complexes dictate their biological function. In "footprinting", the solvent accessibility of the residues that constitute proteins, DNA and RNA can be determined from their reactivity to an exogenous reagent such as the hydroxyl radical (·OH). While ·OH generation for protein footprinting is achieved by radiolysis, photolysis and electrochemistry, we present a simpler solution. A thin film of pyrite (cubic FeS2) nanocrystals deposited onto a shape memory polymer (commodity shrink-wrap film) generates sufficient ·OH via Fenton chemistry for oxidative footprinting analysis of proteins. We demonstrate that varying either time or H2O2 concentration yields the required ·OH dose-oxidation response relationship. A simple and scalable sample handling protocol is enabled by thermoforming the "pyrite shrink-wrap laminate" into a standard microtiter plate format. The low cost and malleability of the laminate facilitates its integration into high throughput screening and microfluidic devices.

  9. Film Piracy, Organized Crime, and Terrorism

    Science.gov (United States)

    2009-01-01

    produced locally in India, Hong Kong, Nigeria , Thailand, and elsewhere are also targets. In con- trast to Hollywood films, which may have broad appeal to...Armani suit instead of a leather jacket, and his best friend is his accountant, not his bodyguard.”4 “To put it crudely, once the bank-robber owns

  10. Semiautomatic machine for turning inside out industrial leather gloves

    Science.gov (United States)

    Aragón-Gonzalez, G.; Cano-Blanco, M.; León-Galicia, A.; Medrano-Sierra, L. F.; Morales-Gómez, J. R.

    2015-01-01

    The last step in the industrial leather gloves manufacturing is to turn the inside out so that the sewing be in the inside of the glove. This work presents the design and testing of a machine for that purpose. In order to quantify the relevant variables, testing was performed with a prototype glove. The employed devices and the testing proceeding were developed experimentally. The obtained information was used to build the turning inside out machine. This machine works with pneumatic power to carry the inside out turning by means of double effect lineal actuators. It has two independent work stations that could be operated simultaneously by two persons, one in each station or in single mode operating one station by one person. The turning inside out cycle is started by means of directional control valves operated with pedals. The velocity and developed force by the actuators is controlled with typical pneumatic resources. The geometrical dimensions of the machine are: 1.15 m length; 0.71 m width and 2.15 m high. Its approximated weight is 120 kg. The air consumption is 5.4 fps by each working station with 60 psig work pressure. The turning inside out operation is 40 s for each industrial leather glove.

  11. Study of the dechroming of tanned leather wastes

    Directory of Open Access Journals (Sweden)

    Botić Tatjana

    2004-01-01

    Full Text Available According to European legislation, it is not possible to dump any chromium-containing waste in Europe. The minimization of wastes is a key element in that strategy. It involves the application of clean technologies: low and non-waste technologies. The tanning industry generates substantial quantities of chromium-containing solid waste in the form of shavings and trimmings. The recycling and reuse of those wastes must be the primary target in optimizing processes of the leather industry. The problem is in a satisfying chromium separation from collagen fibers. Common hydrolysis processes-alkaline or acidic-give gelatins containing residual chromium (III. By using an oxidation agent (H2O2 before alkaline hydrolysis, in was demonstrated that chromium from chromium-containing leather wastes can be almost fully recovered by the previous oxidation of Cr(III to Cr(VI. This chromium can be reused in the tanning process. That would represent an economic saving. The best result of the dechroming process was a gelatin hydrolyzate with only 1.11 in respect to the initial amount.

  12. Fruit Leathers: Method of Preparation and Effect of Different Conditions on Qualities

    Science.gov (United States)

    Diamante, Lemuel M.; Bai, Xue; Busch, Janette

    2014-01-01

    Fruit leathers are dehydrated fruit products which are eaten as snacks or desserts. They are flexible sheets that have a concentrated fruit flavor and nutritional aspects. Most fruit leathers are prepared by mixing fruit puree and other additives like sugar, pectin, acid, glucose syrup, color, and potassium metabisulphite and then dehydrating them under specific conditions. Various drying systems including combined convective and far-infrared drying, hot air drying, microwave drying, solar drying, and sun drying have been used to make fruit leathers. Most fruit leathers are dried at 30 to 80°C for up to 24 hours until the target final moisture content (12–20%) has been reached. Research about fruit leathers began in the 1970s. This work has reviewed published papers on fruit leathers in order to summarize useful information about fruit leathers on methods of preparation, effects of drying condition, and effects of packaging and storage, which will be useful to many in the food industry and consumers who are health-conscious. PMID:26904618

  13. Determination of total chromium in tanned leather samples used in car industry.

    Science.gov (United States)

    Zeiner, Michaela; Rezić, Iva; Ujević, Darko; Steffan, Ilse

    2011-03-01

    Despite the high competition of synthetic fibers leather is nowadays still widely used for many applications. In order to ensure a sufficient stability of the skin matrix against many factors, such as microbial degradation, heat and sweat, a tanning process is indispensable. Using chromium (III) for this purpose offers a multitude of advantages, thus this way of tanning is widely applied. During the use of chromium tanned leather as clothing material as well as for decoration/covering purposes, chromium is extracted from the leather and may then cause nocuous effects to human skin, e.g. allergic reactions. Thus the knowledge of the total chromium content of leather samples expected to come into prolonged touch with human skin is very important. In car industry leather is used as cover for seats, steering wheel and gearshift lever The chromium contents often chromium tanned leather samples used in car industry were determined. First all samples were dried at 65 degrees C overnight and then cut in small pieces using a ceramic knife, weighed and analyzed by inductively coupled plasma--optical emission spectrometry (ICP-OES) after acidic microwave assisted digestion. The total chromium amounts found were in the range from 19 mg/g up to 32 mg/g. The extraction yield of chromium from leather samples in sweat is approximately 2-7%. Thus especially during long journeys in summer chromium can be extracted in amounts which may cause nocuous effects for example on the palm of the hands or on the back.

  14. Effect of Storage on the Physico-Chemical and Antioxidant Properties of Strawberry and Kiwi Leathers.

    Science.gov (United States)

    Concha-Meyer, Anibal A; D'Ignoti, Valeria; Saez, Barbara; Diaz, Ricardo I; Torres, Carolina A

    2016-03-01

    Strawberry and kiwi leathers were used to develop a new healthy and preservative-free fruit snack for new markets. Fruit puree was dehydrated at 60 °C for 20 h and subjected to accelerated storage. Soluble solids, titratable acidity, pH, water activity (aw ), total phenolic (TP), antioxidant activity (AOA) and capacity (ORAC), and color change (browning index) were measured in leathers, cooked, and fresh purees. An untrained panel was used to evaluate consumer acceptability. Soluble solids of fresh purees were 11.24 to 13.04 °Brix, whereas pH was 3.46 to 3.39. Leathers presented an aw of 0.59 to 0.67, and a moisture content of 21 kg water/100 kg. BI decreased in both leathers over accelerated storage period. TP and AOA were higher (P ≤ 0.05) in strawberry formulations. ORAC decreased 57% in strawberry and 65% in kiwi leathers when compared to fruit puree. TP and AOA increased in strawberries during storage. Strawberry and Kiwi leathers may be a feasible new, natural, high antioxidant, and healthy snack for the Chilean and other world markets, such as Europe, particularly the strawberry leather, which was preferred by untrained panelists.

  15. Thermal valorization of footwear leather wastes in bubbling fluidized bed combustion.

    Science.gov (United States)

    Bahillo, A; Armesto, L; Cabanillas, A; Otero, J

    2004-01-01

    Transformation of hide (animal skins) into leather is a complicated process during which significant amounts of wastes are generated. Footwear is the sector that consumes the major part of leather (60%). Logically, this industry is producing the largest quantity of leather wastes. The objective of this work was to demonstrate the technical feasibility of fluidized bed technology to recover the energy from burning footwear leather wastes. Considering the characteristics of leather waste, especially the heating value (12.5-21 MJ/kg), it can be considered a fairly good fuel. Moreover, leather waste has suitable characteristics for combustion, e.g., high volatile matter (76.5%) and low ash content (5.2%). Two factors deserve special attention: N3O and NOx emissions as a consequence of its unusual high nitrogen content (14.1%) and the chromium speciation because chromium is the main element of ash (3.2%) due to its use in leather tanning. A series of experiments has been carried out in a 0.1 MWt bubbling fluidized bed pilot plant. The combustion efficiency, flue gas composition and chromium speciation were investigated. Despite having high nitrogen content, a low conversion rate of fuel-N to NOx and N2O was attained. Chromium was concentrated in the solid streams and it was consistently found as Cr(III+); no presence of Cr(VI+) was detected.

  16. Fruit Leathers: Method of Preparation and Effect of Different Conditions on Qualities.

    Science.gov (United States)

    Diamante, Lemuel M; Bai, Xue; Busch, Janette

    2014-01-01

    Fruit leathers are dehydrated fruit products which are eaten as snacks or desserts. They are flexible sheets that have a concentrated fruit flavor and nutritional aspects. Most fruit leathers are prepared by mixing fruit puree and other additives like sugar, pectin, acid, glucose syrup, color, and potassium metabisulphite and then dehydrating them under specific conditions. Various drying systems including combined convective and far-infrared drying, hot air drying, microwave drying, solar drying, and sun drying have been used to make fruit leathers. Most fruit leathers are dried at 30 to 80°C for up to 24 hours until the target final moisture content (12-20%) has been reached. Research about fruit leathers began in the 1970s. This work has reviewed published papers on fruit leathers in order to summarize useful information about fruit leathers on methods of preparation, effects of drying condition, and effects of packaging and storage, which will be useful to many in the food industry and consumers who are health-conscious.

  17. Fruit Leathers: Method of Preparation and Effect of Different Conditions on Qualities

    Directory of Open Access Journals (Sweden)

    Lemuel M. Diamante

    2014-01-01

    Full Text Available Fruit leathers are dehydrated fruit products which are eaten as snacks or desserts. They are flexible sheets that have a concentrated fruit flavor and nutritional aspects. Most fruit leathers are prepared by mixing fruit puree and other additives like sugar, pectin, acid, glucose syrup, color, and potassium metabisulphite and then dehydrating them under specific conditions. Various drying systems including combined convective and far-infrared drying, hot air drying, microwave drying, solar drying, and sun drying have been used to make fruit leathers. Most fruit leathers are dried at 30 to 80°C for up to 24 hours until the target final moisture content (12–20% has been reached. Research about fruit leathers began in the 1970s. This work has reviewed published papers on fruit leathers in order to summarize useful information about fruit leathers on methods of preparation, effects of drying condition, and effects of packaging and storage, which will be useful to many in the food industry and consumers who are health-conscious.

  18. Lamin A, farnesylation and aging

    Energy Technology Data Exchange (ETDEWEB)

    Reddy, Sita [Department of Biochemistry and Molecular Biology, Institute for Genetic Medicine, Keck School of Medicine, University of Southern California, Los Angeles, CA 90033 (United States); Comai, Lucio, E-mail: comai@usc.edu [Department of Molecular Microbiology and Immunology, Institute for Genetic Medicine, Keck School of Medicine, University of Southern California, Los Angeles, CA 90033 (United States)

    2012-01-01

    Lamin A is a component of the nuclear envelope that is synthesized as a precursor prelamin A molecule and then processed into mature lamin A through sequential steps of posttranslational modifications and proteolytic cleavages. Remarkably, over 400 distinct point mutations have been so far identified throughout the LMNA gene, which result in the development of at least ten distinct human disorders, collectively known as laminopathies, among which is the premature aging disease Hutchinson-Gilford progeria syndrome (HGPS). The majority of HGPS cases are associated with a single point mutation in the LMNA gene that causes the production of a permanently farnesylated mutant lamin A protein termed progerin. The mechanism by which progerin leads to premature aging and the classical HGPS disease phenotype as well as the relationship between this disorder and the onset of analogous symptoms during the lifespan of a normal individual are not well understood. Yet, recent studies have provided critical insights on the cellular processes that are affected by accumulation of progerin and have suggested that cellular alterations in the lamin A processing pathway leading to the accumulation of farnesylated prelamin A intermediates may play a role in the aging process in the general population. In this review we provide a short background on lamin A and its maturation pathway and discuss the current knowledge of how progerin or alterations in the prelamin A processing pathway are thought to influence cell function and contribute to human aging.

  19. Near infrared reflectance spectroscopy as a tool for the control of sheep leather defatting.

    Science.gov (United States)

    Cantero, R; Canals, T; Iturriaga, H

    2007-03-15

    The fat content is one of the variables to be controlled by the tanning industry with a view to obtaining leather for various commercial purposes. Ensuring the production of quality leather products frequently entails using some defatting treatment, particularly when the raw skin is rich in natural fat. The official method for determining fat in leather, IUC 4, is rather slow; also, it uses polluting reagents and involves powdering samples for Soxhlet extraction with low-polarity solvents. The combination of NIR diffuse reflectance spectroscopy as implemented with a fibre-optic probe and multivariate calibration is probably the best choice for the direct determination of fat in leather and the monitoring of leather defatting. In this work, a method for the determination of fat in leather and the control of the defatting process in an expeditious manner and with no sample treatment was developed. Defatting tests were conducted on leather specimens from lambs of various breeds and origins in order to span as wide as possible a range of variability in their properties and natural fat content. The NIR spectra used to construct the calibration matrices were recorded directly on the leather samples prior to and after defatting. Fat contents were determined by partial least-squares regression (PLSR), using the values obtained with the official method as references. Notwithstanding the complex nature of leather, the calibration models used provided good external predictions: the largest overall relative error, obtained by using a single calibration matrix for natural and defatted specimens, was 10%. The proposed method is therefore an advantageous alternative to the official method.

  20. Basic forensic identification of artificial leather for hit-and-run cases.

    Science.gov (United States)

    Sano, Tetsuya; Suzuki, Shinichi

    2009-11-20

    Single fibers retrieved from a victim's garments and adhered to the suspect's automobile have frequently been used to prove the relationship between victim and suspect's automobile. Identification method for single fiber discrimination has already been conducted. But, a case was encountered requiring discrimination of artificial leather fragments retrieved from the victim's bag and fused fibers from the bumper of the suspect's automobile. In this report, basic studies were conducted on identification of artificial leathers and single fibers from leather materials. Fiber morphology was observed using scanning electron microscopy (SEM), color of these leather sheets was evaluated by microspectrophotometry (MSP), the leather components were measured by infrared micro spectrometry (micro-FT-IR) and the inorganic contents were ascertained by micro-X-ray fluorescence spectrometry (micro-XRF). These two methods contribute to other analytical methods too, in the case of utilized single fiber analytical methods. The combination of these techniques showed high potential of discrimination ability in forensic examinations of these artificial leather samples. In regard with smooth surface artificial leather sheet samples, a total of 182 sheets were obtained, including 177 colored sheets directly from 10 of 24 manufacturers in Japan, and five of them were purchased at retail circulation products. Nine samples of suede-like artificial leather were obtained, 6 of them were supplied from 2 manufacturers and 3 sheets were purchased as retailing product. Single fibers from the smooth surface artificial leather sheets showed characteristic for surface markings, and XRF could effectively discriminate between these sheets. The combination of results of micro-FT-IR, color evaluation by MSP and the contained inorganic elements by XRF enabled to discriminate about 92% of 15,576 pairs comparison. Five smooth surface samples form retailing products were discriminated by their chemical

  1. Hot Water Extract of Leather Carp (Cyprinus carpio nudus) Improves Exercise Performance in Mice.

    Science.gov (United States)

    Lee, Gong-Hyeon; Harwanto, Dicky; Park, Sun-Mee; Choi, Jae-Suk; Kim, Mi-Ryung; Hong, Yong-Ki

    2015-12-01

    The hot water extract of leather carp (Cyprinus carpio nudus) has been used as a nourishing tonic soup and as an aid for recovery from physical fatigue. In this study, we investigated the effect of leather carp extract on exercise performance in mice. Swimming endurance and forelimb grip strength were assessed following oral administration of the extract (once per day for 7 days) at a dose of 0.5 mg/10 μL/g body weight. After 7 days, mice given the leather carp extract had significantly greater swimming endurance [105±18 s (Pleather carp extract can improve physical exercise performance and prevent oxidative stress caused by exhaustive workouts.

  2. Using of Hyperbranched Poly(amidoamine as Pretanning Agent for Leather

    Directory of Open Access Journals (Sweden)

    Amal Amin Ibrahim

    2013-01-01

    Full Text Available Although chrome is considered as the major tanning agent in the production of all types of hides and leather worldwide, it represents a serious source of environmental pollution. Therefore, polyamidoamine hyperbranched polymer (HPAM was involved in pretanning of the depickled hides to enhance the chromium uptake during the tanning process. The key parameters which affect the exhaustion and fixation of chrome tan including shrinkage temperature of the tanned leather were studied. The results showed a significant improvement in the chrome exhaustion, the shrinkage temperature, and the texture and softness of the leather treated by HPAM.

  3. Optimization of Laminated Composite Structures

    DEFF Research Database (Denmark)

    Henrichsen, Søren Randrup

    Laminated composite materials are widely used in the design of light weight high performance structures like wind turbine blades and aeroplanes due to their superior stiffness and strength-to-weight-ratios compared to their metal counter parts. Furthermore, the use of laminated composite materials...... allows for a higher degree of tailoring of the resulting material. To enable better utilization of the composite materials, optimum design procedures can be used to assist the engineer. This PhD thesis is focused on developing numerical methods for optimization of laminated composite structures....... The first part of the thesis is intended as an aid to read the included papers. Initially the field of research is introduced and the performed research is motivated. Secondly, the state-of-the-art is reviewed. The review includes parameterizations of the constitutive properties, linear and geometrically...

  4. Impedances of Laminated Vacuum Chambers

    Energy Technology Data Exchange (ETDEWEB)

    Burov, A.; Lebedev, V.; /Fermilab

    2011-06-22

    First publications on impedance of laminated vacuum chambers are related to early 70s: those are of S. C. Snowdon [1] and of A. G. Ruggiero [2]; fifteen years later, a revision paper of R. Gluckstern appeared [3]. All the publications were presented as Fermilab preprints, and there is no surprise in that: the Fermilab Booster has its laminated magnets open to the beam. Being in a reasonable mutual agreement, these publications were all devoted to the longitudinal impedance of round vacuum chambers. The transverse impedance and the flat geometry case were addressed in more recent paper of K. Y. Ng [4]. The latest calculations of A. Macridin et al. [5] revealed some disagreement with Ref. [4]; this fact stimulated us to get our own results on that matter. Longitudinal and transverse impendances are derived for round and flat laminated vacuum chambers. Results of this paper agree with Ref. [5].

  5. Damage resistance of dispersed-ply laminates

    NARCIS (Netherlands)

    Sardar Abadi, P.M.; Jeliazkov, M.; Sebaey, T.A.; Lopes, C.S.; Abdalla, M.M.; Peeters, D.M.J.

    2015-01-01

    This paper presents the design procedure of a quasi-isotropic (QI) laminate employing dispersion of ply orientations. The goal is to improve damage resistance of a laminate under low velocity impact (LVI). The LVI is treated as a quasi-static loading and instead of a plate a laminated beam is

  6. Effects of endocrine disrupting chemicals from leather industry effluents on male reproductive system.

    Science.gov (United States)

    Kumar, Vikas; Majumdar, Chandrajeetbalo; Roy, Partha

    2008-09-01

    The leather tanning industry is characterized by the production of different kinds of effluents, generated in each step of leather processing. These effluents have various chemical compounds which may cause toxicity and endocrine disruption and are thus known as endocrine disrupting chemicals (EDC). This study was aimed to examine the androgenic potential of leather industry effluents collected from northern region of India. Hershberger assay data showed a significant increase (pGC-MS, it was found to contain various aromatic compounds (nonylphenol, hexaclrobenzene and several azo dyes) some of which independently demonstrated similar effects as shown by water samples. Our data suggests that the effluents from leather industry have potential EDC demonstrating androgenic activities.

  7. Experimental skin deposition of chromium on the hands following handling of samples of leather and metal

    DEFF Research Database (Denmark)

    Bregnbak, David; Thyssen, Jacob P.; Jellesen, Morten Stendahl

    2016-01-01

    Background: Chromium is an important skin sensitizer. Exposure to it has been regulated in cement, and recently in leather. Studies on the deposition of chromium ions on the skin as a result of handling different chromium-containing materials are sparse, but could improve the risk assessment...... of contact sensitization and allergic contact dermatitis caused by chromium. Objectives: To determine whether the handling of chromium-containing samples of leather and metal results in the deposition of chromium onto the skin. Methods: Five healthy volunteers participated. For 30 min, they handled samples...... of leather and metal known to contain and release chromium. Skin deposition of chromium was assessed with the acid wipe sampling technique. Results: Acid wipe sampling of the participants' fingers showed chromium deposition on the skin in all participants who had been exposed to leather (range 0.01–0.20 µg...

  8. Characteristics of chromium-allergic dermatitis patients prior to regulatory intervention for chromium in leather

    DEFF Research Database (Denmark)

    Bregnbak, David; Thyssen, Jacob P; Zachariae, Claus;

    2014-01-01

    BACKGROUND: Chromium-tanned leather articles currently constitute the most important cause of contact allergy to chromium in Denmark. A regulation on the content of hexavalent chromium in leather was adopted in November 2013 by the EU member states. OBJECTIVES: To characterize patients...... with chromium allergy and their disease, to serve as a baseline for future studies on the potential effect of the new regulation on chromium in leather. METHODS: A questionnaire case-control study was performed on 155 dermatitis patients with positive patch test reactions to potassium dichromate and a matched...... control group of 621 dermatitis patients. Comparisons were made by use of a χ(2) -test and the Mann-Whitney U-test. Logistic regression analyses were used to test for associations. RESULTS: Sixty-six per cent of chromium-allergic patients had a positive history of contact dermatitis caused by leather...

  9. Chromium in leather footwear-risk assessment of chromium allergy and dermatitis

    DEFF Research Database (Denmark)

    Thyssen, Jacob P; Strandesen, Maria; Poulsen, Pia B;

    2012-01-01

    Background. Chromium-tanned leather footwear, which releases >3 ppm hexavalent Cr(VI), may pose a risk of sensitizing and eliciting allergic dermatitis. Objectives. To determine the content and potential release of chromium in leather footwear and to discuss the prevention of chromium contact...... allergy and dermatitis. Methods. Sixty pairs of leather shoes, sandals and boots (20 children's, 20 men's, and 20 women's) were purchased in Copenhagen and examined with X-ray fluorescence spectroscopy. Chromium was extracted according to the International Standard, ISO 17075. The detection level for Cr......(VI) was 3 ppm. Results. Chromium was identified in 95% of leather footwear products, the median content being 1.7% (range 0-3.3%). No association with store category or footwear category was found. A tendency for there to be a higher chromium content in footwear with high prices was shown (p(trend) = 0...

  10. 人工皮革材质鉴定方法%Material Identification Method of Artificial Leather

    Institute of Scientific and Technical Information of China (English)

    段晓霞; 孙世彧; 黄仕明

    2012-01-01

    The material indentification method of artificial leather was researched. First, the cross section of artificial leather was observed by three-dimensional microscope in order to define the exact position of the base material of artificial leather, then the definite base material was analysed by infrared spectrum, last according to the test infrared spectrums and the characteristic absorption bands, the material of unknown artificial leather was identified.%研究了人工皮革材质鉴定方法.首先利用三维显微镜观察人工皮革的横截面,确定人工皮革基材的准确位置,然后对所确定的基材进行红外光谱分析,根据所测得的红外图谱中主要特征峰的归属,分析确定未知人工皮革材质的种类.

  11. Genetic Algorithms to the Nesting Problem in the Leather Manufacturing Industry

    Institute of Scientific and Technical Information of China (English)

    ZHANG Yu-ping; JIANG Shou-wei; YIN Zhong-wei

    2005-01-01

    The nesting problem in the leather manufacturing is the problem of placing a set of irregularly shaped pieces (called stencils) on a set of irregularly shaped surfaces (called leathers sheets). This paper presents a novel and promising processing approach. After the profile of leather sheets and stencils is obtained with digitizer, the discretization makes the processing independent of the specific geometrical information. The constraints of profile are regarded thoroughly. A heuristic bottom-left placement strategy is employed to sequentially locate stencils on sheets. The optimal placement sequence and rotation are deterimined by genetic algorithms (GA). A natural concise encoding method is developed to satisfy all the possible requirements of the leather nesting problem. The experimental results show that the proposed algorithm can not only be applied to the normal two-dimensional nesting problem, but also especially suitable for the placement of multiple twodimensional irregular stencils on multiple two-dimensional irregular sheets.

  12. Compact resonator on leather for nonradiative inductive power transfer and far-field data links

    Science.gov (United States)

    Monti, G.; Corchia, L.; De Benedetto, E.; Tarricone, L.

    2016-06-01

    In this paper, a wearable resonator suitable to be used for both power and data transmission is presented. The basic element is a complementary split ring resonator that has been optimized to operate both as a dipole-like antenna at 2.45 GHz and as the receiver of a resonant energy link operating at 915 MHz when coupled with an identical external resonator connected to a power source. Experimental data referring to a prototype fabricated by using a conductive adhesive fabric on a leather substrate are reported and discussed. With regard to the wireless resonant energy link (WREL), it is demonstrated that at 915 MHz, the RF-to-RF power transfer efficiency of the link is approximately 78.1%. As for the performance obtained when the resonator is used as an antenna, a gain of approximately -0.43 dB was obtained. Additionally, the performance of the proposed link when connected to a Power Management Unit (PMU) that converts the radio frequency (RF) energy received by the wearable resonator into DC energy that can be directly used for recharging a thin-film battery was also investigated. Experimental tests were performed in order to evaluate both the total efficiency of the wireless charger (i.e., the WREL link connected to the PMU) and the time necessary to recharge a THINERGY MEC201 battery. The obtained results demonstrate the feasibility of using the proposed WREL for implementing a battery charger; in particular, by providing an input power higher than 8 dBm, the time necessary to recharge the considered thin-film battery is shorter than 38 min.

  13. [Research on source profile of aerosol organic compounds in leather plant].

    Science.gov (United States)

    Wang, Bo-Guang; Zhou, Yan; Feng, Zhi-Cheng; Liu, Hui-Xuan

    2009-04-15

    Through investigating current air pollution condition for PM10 in every factories of different style leather plants in Pearl River Delta, characteristic profile of semi-volatile organic compounds in PM10 emitted from leather factories and their contents were researched by using ultrasonic and gas chromatography and mass spectrum technology. The 6 types of organic compounds containing 46 species in total were found in the collected samples, including phenyl compounds, alcohols, PAHs, acids, esters and amides. The concentrations of PM10 in leather tanning plant, leather dying plant and man-made leather plant were 678.5, 454.5, 498.6 microgm x m(-3) respectively, and concentration of organic compounds in PM10 were 10.04, 6.89, 14.21 microg x m(-3) in sequence. The more important type of pollutants in each leather plants had higher contribution to total organic mass as follows, esters and amides in tanning plants profile account for 43.47% and 36.51% respectively; esters and alcohols in dying plants profiles account for 52.52% and 16.16% respectively; esters and amide in man-made leather plant have the highest content and account for 57.07% and 24.17% respectively. In the aerosol organic source profiles of tested leather plants, 9-octadecenamide was the abundant important species with the weight of 26.15% in tanning plant, and Bis(2-ethylhexyl) phthalate was up to 44.19% in the dying plant, and Bis(2-ethylhexyl) maleate and 1-hydroxy-piperidine had obviously higher weight in man-made plant than the other two plants.

  14. Preparation and Application of a Nanocomposite (MPNS/SMA) in Leather Making

    Institute of Scientific and Technical Information of China (English)

    2005-01-01

    A nanocomposite of MPNS/(Styrene-maleic anhydride) was prepared by the polymerization of methacryloxypropyl nano SiO2 (MPNS), styrene (ST) and maleic anhydride (MA) with benzoyl peroxide (BPO) as initiator in toluene. The prepared samples were characterized by Fourier transform infrared spectroscopy (FT-IR) and transmission electron microscope (TEM). Meanwhile, the nanocomposite was applied as a tanning agent in leather making and the results showed that leather treated with MPNS/SMA nanocomposite has excellent quality.

  15. Characterization of dielectric constant of solid materials (Leather belt at X-Band

    Directory of Open Access Journals (Sweden)

    Ambika Singh

    2016-07-01

    Full Text Available This paper discusses the experimental measurement technique for dielectric constant (i.e.permittivity of leather belt at X-band. This measurement play selection of dielectric constant for antenna substrate. This leather can be used as flexible substrate of wearable microstrip antenna. This measurement system consist of solid state klystron power supply, isolator, VSWR meter, frequency meter, solid dielectric cell (XC-501. This data may be interested in flexibility wearable microstrip antenna studies.

  16. Design and development of LED-based irregular leather area measuring machine

    Science.gov (United States)

    Adil, Rehan; Khan, Sarah Jamal

    2012-01-01

    Using optical sensor array, a precision motion control system in a conveyer follows the irregular shaped leather sheet to measure its surface area. In operation, irregular shaped leather sheet passes on conveyer belt and optical sensor array detects the leather sheet edge. In this way outside curvature of the leather sheet is detected and is then feed to the controller to measure its approximate area. Such system can measure irregular shapes, by neglecting rounded corners, ellipses etc. To minimize the error in calculating surface area of irregular curve to the above mentioned system, the motion control system only requires the footprint of the optical sensor to be small and the distance between the sensors is to be minimized. In the proposed technique surface area measurement of irregular shaped leather sheet is done by defining velocity and detecting position of the move. The motion controller takes the information and creates the necessary edge profile on point-to-point bases. As a result irregular shape of leather sheet is mapped and is then feed to the controller to calculate surface area.

  17. EFFECTS OF FATLIQURING PROCESS ON LEATHERS COLOURED WITH IR REFLECTIVE DYES AND PIGMENTS

    Directory of Open Access Journals (Sweden)

    MUTLU Mehmet Mete

    2017-05-01

    Full Text Available Black coloured materials and consumer goods are known to be heating up more, because they absorb sun radiation more than light colours. This heating is a problem for the users for black automotive or motorcycle leathers and also for dark shoes and boots which are exposed to sun heat. Human vision system can distinguish visible colours between the wavelengths of 390-700 nm. So reflecting the sun radiation in the infrared area of radiation spectrum higher than 700nm, is a solution for heating problem without affecting the visible colour. For this reason IR reflective dyes and pigments are designed. A leading Leather Chemical Company has developed an IR reflecting dyeing system for leather keeping the dark coloured leathers cooler under sun radiation. Additionally in theory, fat and water content of leather affects its heating properties. In this study, effect of natural, synthetic and waterproof fatliquoring systems on heating properties of leathers coloured with IR reflective dyes and pigments are investigated.

  18. Association between cobalt allergy and dermatitis caused by leather articles--a questionnaire study.

    Science.gov (United States)

    Bregnbak, David; Thyssen, Jacob P; Zachariae, Claus; Menné, Torkil; Johansen, Jeanne D

    2015-02-01

    Cobalt is a strong skin sensitizer and a prevalent contact allergen. Recent studies have recognized exposure to leather articles as a potential cause of cobalt allergy. To examine the association between contact allergy to cobalt and a history of dermatitis resulting from exposure to leather. A questionnaire case-control study was performed: the case group consisted of 183 dermatitis patients with a positive patch test reaction to cobalt chloride and a negative patch test reaction to potassium dichromate; the control group consisted of 621 dermatitis patients who did not react to either cobalt or chromium in patch testing. Comparisons were made by use of a χ(2) -test, Fisher's exact, and the Mann-Whitney test. Logistic regression analyses were used to test for associations while taking confounding factors into consideration. Leather was observed as the most frequent exposure source causing dermatitis in the case group. Although the case group significantly more often reported non-occupational dermatitis caused by leather exposure (p cobalt allergy and dermatitis caused by work-related exposure to leather. Our study suggests a positive association between cobalt allergy and a history of dermatitis caused by non-occupational exposure to leather articles. © 2014 John Wiley & Sons A/S. Published by John Wiley & Sons Ltd.

  19. Residual stresses in angleplied laminates and their effects on laminate behavior

    Science.gov (United States)

    Chamis, C. C.

    1978-01-01

    NASA Lewis Research Center research in the field of composite laminate residual stresses is reviewed and summarized. The origin of lamination residual stresses, evidence of their presence, experimental methods for measuring them, and theoretical methods for predicting them are described. Typical results are presented which show the magnitudes of residual stresses in various laminates including hybrids and superhybrids, and in other complex composite components. Results are also presented which show the effects of lamination residual stresses on laminate warpage and on laminate mechanical properties including fracture stresses. Finally, the major findings and conclusions derived therefrom are summarized.

  20. Collagen fibril alignment and deformation during tensile strain of leather: a small-angle X-ray scattering study.

    Science.gov (United States)

    Basil-Jones, Melissa M; Edmonds, Richard L; Norris, Gillian E; Haverkamp, Richard G

    2012-02-08

    The distribution and effect of applied strain on the collagen fibrils that make up leather may have an important bearing on the ultimate strength and other physical properties of the material. While sections of ovine and bovine leather were being subjected to tensile strain up to rupture, synchrotron-based small-angle X-ray scattering (SAXS) spectra were recorded edge-on to the leather at points from the corium to the grain. Measurements of both fibril orientation and collagen d spacing showed that, initially, the fibers reorient under strain, becoming more aligned. As the strain increases (5-10% strain), further fibril reorientation diminishes until, at 37% strain, the d spacing increases by up to 0.56%, indicating that significant tensile forces are being transmitted to individual fibrils. These changes, however, are not uniform through the cross-section of leather and differ between leathers of different strengths. The stresses are taken up more evenly through the leather cross-section in stronger leathers in comparison to weaker leathers, where stresses tended to be concentrated during strain. These observations contribute to our understanding of the internal strains and structural changes that take place in leather under stress.

  1. Vibration damping characteristics of laminated steel sheet

    Science.gov (United States)

    Chen, Y. S.; Hsu, T. J.; Chen, S. I.

    1991-03-01

    The use of laminated steel sheets as vibration damping materials was studied. The laminate consisted of a viscoelastic layer which was sandwiched between two steel sheets. The study sought to identify parameters affecting the damping efficiency of the laminate. Two viscoelastic materials, a copolymer based on ethylene and acrylic acid (PEAA) and polyvinyl butyral (PVB), were used. A frequency analyzer was used to measure the loss factor of the laminates. A theoretical analysis of damping efficiency based on a model described by Ungar[2] was also carried out. The results showed that the loss factor of the PEAA-based laminates increased monotonically with increasing thickness of the viscoelastic layer and leveled off at 25.9 pct of total thickness. Ungar’s theory predicted a higher loss factor than the experimental data. This might have resulted from interfacial adhesive bonding, a nonuniform viscoelastic layer thickness, and the extrapolation of the rheological data from low to high frequencies. The loss factor of the laminate increased with increasing temperature, reached a maximum value, and then decreased. An optimum temperature for maximum damping was found for each laminate configuration. The PEAA-based laminates possessed higher damping efficiency than the PVB-based laminates at room temperature. The symmetric laminate (with the same steel sheet thickness) possessed a better damping efficiency than asymmetric laminates. The maximum damping peak of the laminates using a polymer blend, when compared to the laminates using unblended resin, exhibited a lower loss factor value, became broader, and occurred at a temperature between the T g’s of the individual components of the polymer blend.

  2. Valorization of titanium metal wastes as tanning agent used in leather industry

    Energy Technology Data Exchange (ETDEWEB)

    Crudu, Marian, E-mail: mariancrudu@yahoo.com [The National Research and Development Institute for Textiles and Leather – Division Leather and Footwear Research Institute, 93 Ion Minulescu Str., Bucharest (Romania); Deselnicu, Viorica, E-mail: viorica.deselnicu@icpi.ro [The National Research and Development Institute for Textiles and Leather – Division Leather and Footwear Research Institute, 93 Ion Minulescu Str., Bucharest (Romania); Deselnicu, Dana Corina, E-mail: d_deselnicu@yahoo.com [University Politehnica Bucharest, Splaiul Independentei Nr. 313, Sector 6, RO-060042 Bucharest (Romania); Albu, Luminita, E-mail: luminita.albu@gmail.com [The National Research and Development Institute for Textiles and Leather – Division Leather and Footwear Research Institute, 93 Ion Minulescu Str., Bucharest (Romania)

    2014-10-15

    Highlights: • Valorization of titanium wastes which cannot be recycled in metallurgical industry. • Transferring Ti waste into raw materials for obtaining Ti based tanning agent. • Characterization of new Ti based tanning agents and leather tanned with them. • Characterization of sewage waste water and sludge resulted from leather manufacture. • Analysis of the impact of main metal component of Ti waste. - Abstract: The development of new tanning agents and new technologies in the leather sector is required to cope with the increasingly higher environmental pressure on the current tanning materials and processes such as tanning with chromium salts. In this paper, the use of titanium wastes (cuttings) resulting from the process of obtaining highly pure titanium (ingots), for the synthesis of new tanning agent and tanning bovine hides with new tanning agent, as alternative to tanning with chromium salts are investigated. For this purpose, Ti waste and Ti-based tanning agent were characterized for metal content by inductively coupled plasma mass spectrometry (ICP-MS) and chemical analysis; the tanned leather (wet white leather) was characterized by Scanning Electron Microscope/Energy Dispersive Using X-ray (Analysis). SEM/EDX analysis for metal content; Differential scanning calorimetric (DSC), Micro-Hot-Table and standard shrinkage temperature showing a hydrothermal stability (ranged from 75.3 to 77 °C) and chemical analysis showing the leather is tanned and can be processed through the subsequent mechanical operations (splitting, shaving). On the other hand, an analysis of major minor trace substances from Ti-end waste (especially vanadium content) in new tanning agent and wet white leather (not detected) and residue stream was performed and showed that leachability of vanadium is acceptable. The results obtained show that new tanning agent obtained from Ti end waste can be used for tanning bovine hides, as eco-friendly alternative for chrome tanning.

  3. A thermally robust and thickness independent ferroelectric phase in laminated hafnium zirconium oxide

    Science.gov (United States)

    Riedel, S.; Polakowski, P.; Müller, J.

    2016-09-01

    Ferroelectric properties in hafnium oxide based thin films have recovered the scaling potential for ferroelectric memories due to their ultra-thin-film- and CMOS-compatibility. However, the variety of physical phenomena connected to ferroelectricity allows a wider range of applications for these materials than ferroelectric memory. Especially mixed HfxZr1-xO2 thin films exhibit a broad compositional range of ferroelectric phase stability and provide the possibility to tailor material properties for multiple applications. Here it is shown that the limited thermal stability and thick-film capability of HfxZr1-xO2 can be overcome by a laminated approach using alumina interlayers.

  4. Continuous jute fibre reinforced laminated paper composite and reinforcement-fibre free paper laminate

    Indian Academy of Sciences (India)

    B B Verma

    2009-12-01

    Plastic bags create a serious environmental problem. The proposed jute fibre reinforced laminated paper composite and reinforcement-fibre free paper laminate may help to combat the war against this pollutant to certain extent. The paper laminate, without reinforcement fibre, exhibited a few fold superiority in tensile properties than single paper strip. The studies further show that an appreciable improvement in tensile properties can be achieved by introducing continuous jute fibre in paper laminates.

  5. Operational Modal Analysis on laminated glass beams

    OpenAIRE

    López Aenlle, Manuel; Fernández, Pelayo; Villa García, Luis Manuel; Barredo Egusquiza, Josu; Hermanns, Lutz Karl Heinz; Fraile de Lerma, Alberto

    2011-01-01

    Laminated glass is a sandwich element consisting of two or more glass sheets, with one or more interlayers of polyvinyl butyral (PVB). The dynamic response of laminated glass beams and plates can be predicted using analytical or numerical models in which the glass and the PVB are usually modelled as linear-elastic and linear viscoelastic materials, respectively. In this work the dynamic behavior of laminated glass beams are predicted using a finite element model and the analytical model ...

  6. Embedded adhesive connection for laminated glass plates

    DEFF Research Database (Denmark)

    Hansen, Jens Zangenberg; Poulsen, S.H.; Bagger, A.

    2012-01-01

    The structural behavior of a new connection design, the embedded adhesive connection, used for laminated glass plates is investigated. The connection consists of an aluminum plate encapsulated in-between two adjacent triple layered laminated glass plates. Fastening between glass and aluminum...... usage in a design situation. The embedded connection shows promising potential as a future fastening system for load-carrying laminated glass plates....

  7. Terahertz spectroscopic investigations of leather in terahertz wave range

    Science.gov (United States)

    Song, Mei-jing; Li, Jiu-sheng

    2012-03-01

    Pulsed THz time-domain spectroscopy is a coherent technique, in which both the amplitude and the phase of a THz pulse are measured. Recently, material characterization using THz spectroscopy has been applied to biochemicals, pharmaceuticals, polymers and semiconductors and has given us important information. Moreover, THz imaging has progressed and is expected to be applicable for the identification of narcotics and explosives. The most important and characteristic point of THz spectroscopy is said to be its ability to observe intermolecular vibrations in contrast to infrared spectroscopy (IR), which observes intramolecular vibrations. Coherent detection enables direct calculations of both the imaginary and the real parts of the refractive index without using the Kramers-Kronig relations. Terahertz wave spectroscopy has been used to study the properties and absorption spectra characteristic of materials. In this paper, the spectral characteristics of cow skin, pig skin sheep skin, horse skin and deer skin have been measured with terahertz time-domain spectroscopy in the range of 0.1~2.0THz. The results show that THz-TDS technology provides an important tool for quality analysis and detection of leathers.

  8. Buckling analysis of a laminate plate

    Directory of Open Access Journals (Sweden)

    Mamuzić, I.

    2008-04-01

    Full Text Available The paper deals with a modeling of laminate plates and with their buckling analysis. To predict the inception of buckling for plates in plane resultant forces must be included. The buckling analysis is made by the help of finite element method in program COSMOS/M. For rectangular laminate plate consisting of 4 layers with symmetric and antisymmetric stacking sequence a buckling analysis is carried out. In the illustrative example there are depicted buckling modes for symmetric laminates [30/-30]s, [45/-45]s, [60/-60]s, [90/-90]s and results of the buckling analysis for the symmetric and antisymmetric laminates.

  9. The management of equine acute laminitis

    Directory of Open Access Journals (Sweden)

    Mitchell CF

    2014-12-01

    Full Text Available Colin F Mitchell, Lee Ann Fugler, Susan C Eades Veterinary Clinical Sciences, School of Veterinary Medicine, Louisiana State University, Baton Rouge, LA, USA Abstract: Laminitis is an extremely painful condition resulting in damage to the soft tissues anchoring the third phalanx to the hoof, which can result in life-threatening debilitation. Specific therapy is not available. The most important principles of therapy include aggressive nutritional and medical management of primary disease processes, cryotherapy, anti-inflammatory therapy, pain management, and biomechanical support. This review focuses on the principles of evidenced-based therapies. Keywords: laminitis treatment, laminitis biomechanics, laminitis pain

  10. 78 FR 48903 - Certain Products Having Laminated Packaging, Laminated Packaging, and Components Thereof...

    Science.gov (United States)

    2013-08-12

    ... infringement of certain claims of nine patents. 78 FR 19,007. The subject products are certain laminated... industry requirement.'' 78 FR 19,008. The ALJ conducted a hearing on the domestic-industry issue on May 16... COMMISSION Certain Products Having Laminated Packaging, Laminated Packaging, and Components...

  11. Leather waste--potential threat to human health, and a new technology of its treatment.

    Science.gov (United States)

    Kolomaznik, K; Adamek, M; Andel, I; Uhlirova, M

    2008-12-30

    In this paper, the authors deal with the problem of processing various types of waste generated by leather industry, with special emphasis to chrome-tanned waste. The agent that makes this waste potentially hazardous is hexavalent chromium. Its compounds can have negative effects on human health and some CrVI salts are considered carcinogens. The authors present the risks of spontaneous oxidization of CrIII to CrVI in the open-air dumps as well as the possible risks of wearing bad quality shoes, in which the chromium content is not controlled. There are several ways of handling primary leather waste, but no satisfactory technology has been developed for the secondary waste (manipulation waste, e.g. leather scraps and used leather products). In this contribution, a new three-step hybrid technology of processing manipulation waste is presented and tested under laboratory, pilot-scale and industrial conditions. The filtrate can be used as a good quality NPK fertilizer. The solid product, titanium-chromium sludge, can serve as an inorganic pigment in glass and ceramic industry. Further, the authors propose selective collection of used leather products (e.g. old shoes), the hydrolysable parts of which can be also processed by the new hybrid technology.

  12. POTENTIAL OF VEGETABLE TANNING MATERIALS AND BASIC ALUMINUM SULPHATE IN SUDANESE LEATHER INDUSTRY

    Directory of Open Access Journals (Sweden)

    MAHDI, HAROUN

    2009-03-01

    Full Text Available Ecological pressures on chromium have now forced the leather industry to look for possible alternatives. A vegetable- aluminum combination tannage has been studied, with special attention being given to intended final product. Aluminum is mineral tanning agents that are widely used to stabilize collagens in the leather industry. In this study, the crosslinking of vegetable and aluminum, with collagens, have been explored. This kind of chrome free tannage give us leathers with shrinkage temperature around 125oC, elongation at break 65.6%, tensile strength 38 N/mm2, and tear strength 98 N/mm. The chemical properties of the combination tanned leathers are found to be quite normal. Among the combination system evaluated, a vegetable pretannage followed by retannage with basic aluminum sulphate was found to produce stronger leather with the durable characteristics. In contrast, pre-tanning with aluminum possibly tightens the collagen fiber network, preventing high molecular weight vegetable tannins from interacting with collagen fibres. Optimal results were obtained when 10% (w/w vegetable tannins (garad and 2% Aluminum sulphate was used.

  13. Short term preservation of hide using vacuum: influence on properties of hide and of processed leather.

    Science.gov (United States)

    Gudro, Ilze; Valeika, Virgilijus; Sirvaitytė, Justa

    2014-01-01

    The objective of this work was to investigate vacuum influence on hide preservation time and how it affects hide structure. It was established that vacuum prolongs the storage time without hide tissue putrefaction up to 21 days when the storage temperature is 4°C. The microorganisms act for all storage times, but the action is weak and has no observable influence on the quality of hide during the time period mentioned. The hide shrinkage temperature decrease is negligible, which shows that breaking of intermolecular bonds does not occur. Optical microscopy, infrared spectroscopy and differential scanning calorimetry also did not show any structural changes which can influence the quality of leather produced from such hide. The qualitative indexes of wet blue processed under laboratory conditions and of leather produced during industrial trials are presented. Indexes such as chromium compounds exhaustion, content of chromium in leather, content of soluble matter in dichloromethane, strength properties, and shrinkage temperature were determined. Properties of the leather produced from vacuumed hide under industrial conditions conformed to the requirements of shoe upper leather.

  14. Preparation and characterization of hierarchical porous carbons derived from solid leather waste for supercapacitor applications.

    Science.gov (United States)

    Konikkara, Niketha; Kennedy, L John; Vijaya, J Judith

    2016-11-15

    Utilization of crust leather waste (CLW) as precursors for the preparation of hierarchical porous carbons (HPC) were investigated. HPCs were prepared from CLW by pre-carbonization followed by chemical activation using KOH at relatively high temperatures. Textural properties of HPC's showed an extent of micro-and mesoporosity with maximum BET surface area of 716m(2)/g. Inducements of graphitic planes in leather waste derived carbons were observed from X-ray diffraction and HR-TEM analysis. Microstructure, thermal behavior and surface functional groups were identified using FT-Raman, thermo gravimetric analysis and FT-IR techniques. HPCs were evaluated for electrochemical properties by cyclic voltammetry (CV), galvanostatic charge/discharge (GCD) and electrochemical impedance spectroscopy (EIS) by three electrode system. CLC9 sample showed a maximum capacitance of 1960F/g in 1M KCl electrolyte. Results achieved from rectangular curves of CV, GCD symmetric curves and Nyquist plots show that the leather waste carbon is suitable to fabricate supercapacitors as it possess high specific capacitance and electrochemical cycle stability. The present study proposes an effective method for solid waste management in leather industry by the way of converting toxic leather waste to new graphitic porous carbonaceous materials as a potential candidate for energy storage devices.

  15. Valorization of titanium metal wastes as tanning agent used in leather industry.

    Science.gov (United States)

    Crudu, Marian; Deselnicu, Viorica; Deselnicu, Dana Corina; Albu, Luminita

    2014-10-01

    The development of new tanning agents and new technologies in the leather sector is required to cope with the increasingly higher environmental pressure on the current tanning materials and processes such as tanning with chromium salts. In this paper, the use of titanium wastes (cuttings) resulting from the process of obtaining highly pure titanium (ingots), for the synthesis of new tanning agent and tanning bovine hides with new tanning agent, as alternative to tanning with chromium salts are investigated. For this purpose, Ti waste and Ti-based tanning agent were characterized for metal content by inductively coupled plasma mass spectrometry (ICP-MS) and chemical analysis; the tanned leather (wet white leather) was characterized by Scanning Electron Microscope/Energy Dispersive Using X-ray (Analysis). SEM/EDX analysis for metal content; Differential scanning calorimetric (DSC), Micro-Hot-Table and standard shrinkage temperature showing a hydrothermal stability (ranged from 75.3 to 77°C) and chemical analysis showing the leather is tanned and can be processed through the subsequent mechanical operations (splitting, shaving). On the other hand, an analysis of major minor trace substances from Ti-end waste (especially vanadium content) in new tanning agent and wet white leather (not detected) and residue stream was performed and showed that leachability of vanadium is acceptable. The results obtained show that new tanning agent obtained from Ti end waste can be used for tanning bovine hides, as eco-friendly alternative for chrome tanning.

  16. Ivermectin treatment of bovine psoroptic mange: effects on serum chemistry, hematology, organ weights, and leather quality.

    Science.gov (United States)

    Rehbein, S; Visser, M; Meyer, M; Lindner, T

    2016-04-01

    Psoroptic mange is a skin disease which may result in serious health and welfare problems and important economic losses. Apart from the effect on weight gain, little information is available concerning other responses of the organism consequent to the successful therapy of bovine psoroptic mange. Accordingly, serum chemistry, hematology, organ weights, and leather quality of young bulls with experimentally induced clinical Psoroptes ovis mange and treated with either ivermectin long-acting injection (IVM LAI; IVOMEC(®) GOLD, Merial) or saline (n = 16 each) were examined 8 weeks after treatment when all IVM LAI-treated bulls were free of live P. ovis mites while the saline-treated bulls maintained clinical mange. IVM LAI-treated bulls had higher (p leathers produced from the IVM LAI-treated bulls showed significantly (p leathers from the saline-treated bulls, and significantly (p leather from the IVM LAI-treated bulls was of usable quality than the size of leather from the saline-treated bulls. Overall, these findings provided evidence that many changes, which are indicative of impaired protein and energy metabolism, immune system function, and performance resultant from clinical psoroptic mange, improved substantially within 8 weeks of successful treatment with injectable ivermectin.

  17. 40 CFR 63.5350 - How do I distinguish between the water-resistant/specialty and nonwater-resistant leather product...

    Science.gov (United States)

    2010-07-01

    ...-resistant/specialty and nonwater-resistant leather product process operations? 63.5350 Section 63.5350... Hazardous Air Pollutants for Leather Finishing Operations Compliance Requirements § 63.5350 How do I distinguish between the water-resistant/specialty and nonwater-resistant leather product process...

  18. 78 FR 28833 - CE Leathers Company; Supplemental Notice That Initial Market-Based Rate Filing Includes Request...

    Science.gov (United States)

    2013-05-16

    ... From the Federal Register Online via the Government Publishing Office DEPARTMENT OF ENERGY Federal Energy Regulatory Commission CE Leathers Company; Supplemental Notice That Initial Market- Based Rate...-referenced proceeding of CE Leathers Company's application for market-based rate authority, with...

  19. ANNALS OF THE UNIVERSITY OF ORADEA FASCICLE OF TEXTILES, LEATHERWORK 133 DETERMINANTS TO THE CONSUMPTION OF LEATHER PRODUCTS

    Directory of Open Access Journals (Sweden)

    CARRIER Serge A.

    2014-05-01

    Full Text Available The current paper looks at some of the determinants in the consumption of leather fashion products by the 16-34 year old population of Québec. Although the Québec population presents some idiosyncrasies, we surmise that our results could probably be generalized to similarly aged population groups in the western world. Leather goods are now often considered as luxury it ems, a sub-sector of the fashion industry which has been outgrowing all others in the last few years. Yet leather is often seen as non-ethical, requiring the killing of animals, and non-ecological, since the production process is polluting. Those two opposing forces make the future of leather very uncertain. Surprisingly, very little literature has been written on the subject. This paper presents a survey in which the authors tried to identify the determinants to the consumption of leather in the 16-34 age groups, often referred to as Generation Y. Our findings reflect this dichotomy between the consumer’s interest for apparel and his or her negative reaction to some characteristics of leather. Although not as influenced as fur by ethical and ecological concerns, leather products the object of similar reactions. This paper concludes on some recommendations to participants in the leather industry who should note this trend and try to position their products in such a way as to minimize the negative elements and bank on the more positive aspects.

  20. The Ecological Aspects of Leather Manufacture(to be continued)%制革生态学(续六)

    Institute of Scientific and Technical Information of China (English)

    Gerhard Wolf; Brigitte Wegner

    2004-01-01

    4 Finishing The purpose of finishing leather is to improve its serviceability by protecting it from damage by water, soil and mechanical action. Finishing modifies the shade, gloss and handle of the leather, improves its physical properties such as its lightfasthess and rubfastness, and hides any defects and

  1. 40 CFR Table 2 to Subpart Tttt of... - Leather Finishing HAP Emission Limits for Determining the Allowable HAP Loss

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 12 2010-07-01 2010-07-01 true Leather Finishing HAP Emission Limits for Determining the Allowable HAP Loss 2 Table 2 to Subpart TTTT of Part 63 Protection of Environment... Leather Finishing Operations Pt. 63, Subpt. TTTT, Table 2 Table 2 to Subpart TTTT of Part...

  2. Rapid and Accurate Identification of Animal Species in Natural Leather Goods by Liquid Chromatography/Mass Spectrometry.

    Science.gov (United States)

    Izuchi, Yukari; Takashima, Tsuneo; Hatano, Naoya

    2016-01-01

    The demand for leather goods has grown globally in recent years. Industry revenue is forecast to reach $91.2 billion by 2018. There is an ongoing labelling problem in the leather items market, in that it is currently impossible to identify the species that a given piece of leather is derived from. To address this issue, we developed a rapid and simple method for the specific identification of leather derived from cattle, horses, pigs, sheep, goats, and deer by analysing peptides produced by the trypsin-digestion of proteins contained in leather goods using liquid chromatography/mass spectrometry. We determined species-specific amino acid sequences by liquid chromatography/tandem mass spectrometry analysis using the Mascot software program and demonstrated that collagen α-1(I), collagen α-2(I), and collagen α-1(III) from the dermal layer of the skin are particularly useful in species identification.

  3. Analysis of Selected Properties of Fibreboard Panels Manufactured from Wood and Leather Using the Near Infrared Spectroscopy

    Directory of Open Access Journals (Sweden)

    Kerstin Wagner

    2015-01-01

    Full Text Available This paper deals with the characterization of the properties of wood fibres leather shavings composite board by using the near infrared spectroscopy (NIRS and multivariate data analysis. In this study fibreboards were manufactured with different leather amounts by using spruce fibres, as well as vegetable and mineral tanned leather shavings (wet white and wet blue. The NIR spectroscopy was used to analyse the raw materials as well as the wood leather fibreboards. Moreover, the physical and mechanical features of the wood leather composite fibreboards were determined to characterize their properties for the further data analysis. The NIR spectra were analysed by univariate and multivariate methods using the Principal Component Analysis (PCA and the Partial Least Squares Regression (PLSR method. These results demonstrate the potential of FT-NIR spectroscopy to estimate the physical and mechanical properties (e.g., bending strength. This phenomenon provides a possibility for quality assurance systems by using the NIRS.

  4. A Rapid and Simple LC-MS Method Using Collagen Marker Peptides for Identification of the Animal Source of Leather.

    Science.gov (United States)

    Kumazawa, Yuki; Taga, Yuki; Iwai, Kenji; Koyama, Yoh-Ichi

    2016-08-03

    Identification of the animal source of leather is difficult using traditional methods, including microscopic observation and PCR. In the present study, a LC-MS method was developed for detecting interspecies differences in the amino acid sequence of type I collagen, which is a major component of leather, among six animals (cattle, horse, pig, sheep, goat, and deer). After a dechroming procedure and trypsin digestion, six tryptic peptides of type I collagen were monitored by LC-MS in multiple reaction monitoring mode for the animal source identification using the patterns of the presence or absence of the marker peptides. We analyzed commercial leathers from various production areas using this method, and found some leathers in which the commercial label disagreed with the identified animal source. Our method enabled rapid and simple leather certification and could be applied to other animals whether or not their collagen sequences are available in public databases.

  5. Chrome Tanning Leather of Giant Sea Perch Combined with Seed Extract Areca Nut on the Physical Characteristics

    Directory of Open Access Journals (Sweden)

    Bustami - Ibrahim

    2014-11-01

    Full Text Available Tanning is the process of converting raw hide protein to leather, which are stable, not easily decompose, and is suitable for a variety of uses. The use of vegetable based tanning materials in the leather tanning process has not been carried out. Vegetable based materials that were used are betel nuts. This plant contains tannin which is the main agent in the process of leather tanning. The aim of this study was to determine the physical characteristics of snapper leather treated with betel nut extract. Soxhlet extracting method with methanol as a solvent were used to obtain tannin from betel nuts. Tanned Snapper Leather were analyzed for physical quality, elongation strength, tensile strength, tear strength, and sewing strength. The result showed that methanol extracted betel nut with 10% concentration gives the optimum physical characteristics.Keywords: areca nut, chrome, snapper, snapper

  6. Variable resistance constant tension and lubrication device. [using oil-saturated leather wiper

    Science.gov (United States)

    Smith, H. J. (Inventor)

    1974-01-01

    A variable resistance device is described which includes a cylindrical housing having elongated resistance wires. A movable arm having a supporting block carried on the outer end is rotatably carried by the cylindrical housing. An arcuate steel spring member is pivotally supported by the movable arm. A leather wiper member is carried adjacent to one end of the spring steel member, and an electrically conductive surface is carried adjacent to the other end. The supporting block maintains the spring steel member in compression so that a constant pressure is applied to the conductive end of the spring steel member and the leather wiper. The leather wiper is saturated with a lubricating oil for maintaining the resistance wire clean as the movable arm is manipulated.

  7. Chromium(VI) release from leather and metals can be detected with a diphenylcarbazide spot test

    DEFF Research Database (Denmark)

    Bregnbak, David; Johansen, Jeanne D.; Jellesen, Morten Stendahl

    2015-01-01

    Along with chromium, nickel and cobalt are the clinically most important metal allergens. However, unlike for nickel and cobalt, there is no validated colorimetric spot test that detects chromium. Such a test could help both clinicians and their patients with chromium dermatitis to identify culprit...... exposures. To evaluate the use of diphenylcarbazide (DPC) as a spot test reagent for the identification of chromium(VI) release. A colorimetric chromium(VI) spot test based on DPC was prepared and used on different items from small market surveys. The DPC spot test was able to identify chromium(VI) release...... at 0.5 ppm without interference from other pure metals, alloys, or leather. A market survey using the test showed no chromium(VI) release from work tools (0/100). However, chromium(VI) release from metal screws (7/60), one earring (1/50), leather shoes (4/100) and leather gloves (6/11) was observed. We...

  8. Spatial Agglomeration and Productivity of Textile and Leather Manufacturing in the Punjab Province of Pakistan

    Directory of Open Access Journals (Sweden)

    Asim Iqba

    2013-05-01

    Full Text Available This study investigates whether spatial agglomeration of textile and leather industry facilitates to enhance its own productivity at establishment level in the Punjab province of Pakistan. The empirical analysis is based on the survey data for the years 1995-96, 2000-2001 and 2005-06 collected from the Punjab Bureau of Statistics (PBS. The production function framework has been utilized. The results of production function suggest that spatial agglomeration of textile and leather industry plays a vital role in determining the productivity of establishments. The impact of localization (specialization is positive and stronger than urbanization (diversification which implies that locating manufacturing establishments in a particular district leads to enhance the productivity of establishments. Therefore, government policy should be biased to promote localization of textile and leather industry.

  9. Penelitian finishing kulit lemas (softy leather dari kulit kambing untuk tas wanita

    Directory of Open Access Journals (Sweden)

    Widhiati

    1997-12-01

    Full Text Available This research is aimed at finding the competition of paint substance which optimal applied for softy sheep leather for lady’s bags manufacturing. Materials used in this study were 27 pieces of pickled sheep stock and simple factorial 3 x 3 was use for the research plan, the treatment of which is combination binder RU 3989 (150 gram, 200 gram, 250 gram and pigment (75 gram, 100 gram, 125 gram for 1,000 gram paint solution. The research result indicates that the proportion of paint substance composition optimal applied to sheep which are tanned to be softly leather for lady’s bags manufacturing is the combination of 250 gram binder RU 3989 and 75 gram pigment in 1,000 gram paint solution, and the test result fulfil the requirements of sheep garment leather quality.

  10. Activated carbon from leather shaving wastes and its application in removal of toxic materials.

    Science.gov (United States)

    Kantarli, Ismail Cem; Yanik, Jale

    2010-07-15

    In this study, utilization of a solid waste as raw material for activated carbon production was investigated. For this purpose, activated carbons were produced from chromium and vegetable tanned leather shaving wastes by physical and chemical activation methods. A detailed analysis of the surface properties of the activated carbons including acidity, total surface area, extent of microporosity and mesoporosity was presented. The activated carbon produced from vegetable tanned leather shaving waste produced has a higher surface area and micropore volume than the activated carbon produced from chromium tanned leather shaving waste. The potential application of activated carbons obtained from vegetable tanned shavings as adsorbent for removal of water pollutants have been checked for phenol, methylene blue, and Cr(VI). Adsorption capacities of activated carbons were found to be comparable to that of activated carbons derived from biomass.

  11. Negative refraction in a laminate

    Science.gov (United States)

    Willis, J. R.

    2016-12-01

    This work is concerned with the reflection and transmission of waves at a plane interface between a homogeneous elastic half-space and a half-space of elastic material that is periodically laminated. The lamination is always in the direction of the x1-coordinate axis and the displacement is always longitudinal shear, so that the only non-zero displacement component is u3(x1 ,x2 , t). After an initial discussion of Floquet-Bloch waves in the laminated material, brief consideration is given to the reflection-transmission problem, when the interface between the two media is the plane x1 = 0. Nothing unusual emerges: there are just a single reflected wave and a single transmitted wave, undergoing positive group-velocity refraction. Then, the problem is considered when the interface between the two media is the plane x2 = 0. The periodic structure of the interface induces an infinite set of reflected waves and an infinite set of transmitted waves. All need to be taken into account, but most decay exponentially away from the interface. It had previously been recognized that, if the incident wave had appropriate frequency and angle of incidence, a propagating transmitted wave would be generated that would undergo negative group-velocity refraction - behaviour usually associated with a metamaterial. It is established by an example in this work that there is, in addition, a propagating transmitted wave with smaller wavelength but larger group velocity that undergoes positive group-velocity refraction. The work concludes with a brief discussion of this finding, including its implications for the utility (or not) of "effective medium" theory.

  12. Zero discharge tanning: a shift from chemical to biocatalytic leather processing.

    Science.gov (United States)

    Thanikaivelan, Palanisamy; Rao, Jonnalagadda Raghava; Nair, Balachandran Unni; Ramasami, Thirumalachari

    2002-10-01

    Beam house processes (Beam house processes generally mean liming-reliming processes, which employ beam.) contribute more than 60% of the total pollution from leather processing. The use of lime and sodium sulfide is of environmental concern (1, 2). Recently, the authors have developed an enzyme-based dehairing assisted with a very low amount of sodium sulfide, which completely avoids the use of lime. However, the dehaired pelt requires opening up of fiber bundles for further processing, where lime is employed to achieve this through osmotic swelling. Huge amounts of lime sludge and total solids are the main drawbacks of lime. An alternative bioprocess, based on alpha-amylase for fiber opening, has been attempted after enzymatic unhairing. This totally eliminates the use of lime in leather processing. This method enables subsequent processes and operations in leather making feasible without a deliming process. A control experiment was run in parallel using conventional liming-reliming processes. It has been found that the extent of opening up of fiber bundles using alpha-amylase is comparable to that of the control. This has been substantiated through scanning electron microscopic, stratigraphic chrome distribution analysis, and softness measurements. Performance of the leathers is shown to be on a par with leathers produced by the conventional process through physical and hand evaluation. Importantly, softness of the leathers is numerically proven to be comparable with that of control. The process also demonstrates reduction in chemical oxygen demand load by 45% and total solids load by 20% compared to the conventional process. The total dry sludge from the beam house processes is brought down from 152 to 8 kg for processing 1 ton of raw hides.

  13. Biointervention makes leather processing greener: an integrated cleansing and tanning system.

    Science.gov (United States)

    Thanikaivelan, Palanisamy; Rao, Jonnalagadda Raghava; Nair, Balachandran Unni; Ramasami, Thirumalachari

    2003-06-01

    The do-undo methods adopted in conventional leather processing generate huge amounts of pollutants. In other words, conventional methods employed in leather processing subject the skin/hide to wide variations in pH. Pretanning and tanning processes alone contribute more than 90% of the total pollution from leather processing. Included in this is a great deal of solid wastes such as lime and chrome sludge. In the approach described here, the hair and flesh removal as well as fiber opening have been achieved using biocatalysts at pH 8.0 for cow hides. This was followed by a pickle-free chrome tanning, which does not require a basification step. Hence, this tanning technique involves primarily three steps, namely, dehairing, fiber opening, and tanning. It has been found that the extent of hair removal, opening up of fiber bundles, and penetration and distribution of chromium are comparable to that produced by traditional methods. This has been substantiated through scanning electron microscopic, stratigraphic chrome distribution analysis, and softness measurements. Performance of the leathers is shown to be on par with conventionally processed leathers through physical and hand evaluation. Importantly, softness of the leathers is numerically proven to be comparable with that of control. The process also demonstrates reduction in chemical oxygen demand load by 80%, total solids load by 85%, and chromium load by 80% as compared to the conventional process, thereby leading toward zero discharge. The input-output audit shows that the biocatalytic three-step tanning process employs a very low amount of chemicals, thereby reducing the discharge by 90% as compared to the conventional multistep processing. Furthermore, it is also demonstrated that the process is technoeconomically viable.

  14. Forming predictions of UD reinforced thermoplastic laminates

    NARCIS (Netherlands)

    Haanappel, S.P.; Thije, ten R.; Akkerman, R.

    2010-01-01

    A preliminary study was made of the thermoforming process of UD fibre reinforced thermoplastic laminates. Deformation mechanisms of the ply and the laminate were identified. Forming experiments were performed with a single dome to support this study. The experiments were also used to validate the fo

  15. Toughening of BMI Based Graphite Laminates by Ex-situ Concept

    Institute of Scientific and Technical Information of China (English)

    CHENG Qun-feng; XU Ya-hong; YI Xiao-su

    2006-01-01

    High-performance bismaleimdes (BMI) matrix composites reinforced by graphite fibers were prepared and toughened with a thermoplastic component (PAEK) by using the Ex-situ concept. Experimental matrix was designed for overall toughening of the base resin, periodically interleaving thermoplastic films into each plies (Ex-situ concept) and for varying the film compositions. The highest impact damage resistance characterized by compression after impact (CAI) was obtained for the laminates toughened on the Ex-situ concept, especially, when two-component cast films of a special ration of PAEK/BMI 60: 40 were interleaved though the thermoplastic concentration for the overall toughening, interleaving the pure thermoplastic films and the two-component films was comparable. There were two peaks found in the DSC trace of the laminates toughened implying a phase separation process occurred. The glass transition temperature of the laminates toughened was slightly reduced due to the low-temperature PAEK. Morphological study revealed a typical granular structure just in the interplay region as a result of spinodal decomposition and coarsening process. This was in agreement of the result of DSC investigation.

  16. CO2 Separation and Capture Properties of Porous Carbonaceous Materials from Leather Residues

    Directory of Open Access Journals (Sweden)

    Ana Arenillas

    2013-10-01

    Full Text Available Carbonaceous porous materials derived from leather skin residues have been found to have excellent CO2 adsorption properties, with interestingly high gas selectivities for CO2 (α > 200 at a gas composition of 15% CO2/85% N2, 273K, 1 bar and capacities (>2 mmol·g−1 at 273 K. Both CO2 isotherms and the high heat of adsorption pointed to the presence of strong binding sites for CO2 which may be correlated with both: N content in the leather residues and ultrasmall pore sizes.

  17. Speciation of Chromium in Bottom Ash Obtained by the Incineration of the Leather Waste Shavings

    Directory of Open Access Journals (Sweden)

    k. louhab

    2006-01-01

    Full Text Available The evolution of bottom ash morphology and chromium metals behavior during incineration of a leather waste shavings at different incineration temperature have been studied. The Cr, Ca, Mg, Cl rates in bottom ashes, flay ashes and emitted gases in different incineration temperature of the tannery wastes are also determined. The morphology of the bottom ashes obtained by incineration at different temperature from the leather waste shavings was examined by MEB. The result show that the temperature and the length of incineration influence on the structure of the bottom ash and on the chromium in the bottom ash.

  18. Lamins of the sea lamprey (Petromyzon marinus) and the evolution of the vertebrate lamin protein family.

    Science.gov (United States)

    Schilf, Paul; Peter, Annette; Hurek, Thomas; Stick, Reimer

    2014-07-01

    Lamin proteins are found in all metazoans. Most non-vertebrate genomes including those of the closest relatives of vertebrates, the cephalochordates and tunicates, encode only a single lamin. In teleosts and tetrapods the number of lamin genes has quadrupled. They can be divided into four sub-types, lmnb1, lmnb2, LIII, and lmna, each characterized by particular features and functional differentiations. Little is known when during vertebrate evolution these features have emerged. Lampreys belong to the Agnatha, the sister group of the Gnathostomata. They split off first within the vertebrate lineage. Analysis of the sea lamprey (Petromyzon marinus) lamin complement presented here, identified three functional lamin genes, one encoding a lamin LIII, indicating that the characteristic gene structure of this subtype had been established prior to the agnathan/gnathostome split. Two other genes encode lamins for which orthology to gnathostome lamins cannot be designated. Search for lamin gene sequences in all vertebrate taxa for which sufficient sequence data are available reveals the evolutionary time frame in which specific features of the vertebrate lamins were established. Structural features characteristic for A-type lamins are not found in the lamprey genome. In contrast, lmna genes are present in all gnathostome lineages suggesting that this gene evolved with the emergence of the gnathostomes. The analysis of lamin gene neighborhoods reveals noticeable similarities between the different vertebrate lamin genes supporting the hypothesis that they emerged due to two rounds of whole genome duplication and makes clear that an orthologous relationship between a particular vertebrate paralog and lamins outside the vertebrate lineage cannot be established. Copyright © 2014 Elsevier GmbH. All rights reserved.

  19. Steady compression characteristics of laminated MRE isolator

    Science.gov (United States)

    Wahab, N. A. A.; Mazlan, S. A.; Ubaidillah; Sharif, A. H. R.; Kamaruddin, S.

    2016-11-01

    This paper focused on an experimental setup on laminated magnetorheological elastomer (MRE) isolator under steady state compression test. An isotropic type natural rubber (NR) based MRE were fabricated and layered with a steel plate to form a multilayer sandwich structure adopted from the conventional laminated rubber bearing design. A set of static compression test was conducted to explore the potential of semi-active laminated MRE isolator in field-dependent stiffness properties. Stress versus strain relationship was assessed under different magnetic fields application. Based on the examination, the stress altered as the application of magnetic fields. Consequently, the effective stiffness of isolator also influenced by the magnetic fields induction. The experimental results show that the proposed laminated MRE isolator can effectively alter the compression stiffness up to the 14.56%. The preliminary results have confirmed the tunability of the semi-active laminated MRE isolator in which it would be beneficial for improving building isolator in general.

  20. Hard coating for polymer substrates through lamination and peeling of porous anodized zirconia.

    Science.gov (United States)

    Masheder, Benjamin

    2014-04-01

    Transparent and hard zirconia (ZrO2) films with thicknesses in the range of 1.5 to 1.8 microm were successfully formed on various polymer surfaces, i.e., polycarbonate (PC), polystyrene (PS), polyethylene terephthalate (PET) and polymethylmethacrylate (PMMA) with excellent adhesion and without cracking, while preserving their bulk properties. Our process is based on a lamination of porous anodized ZrO2 membranes (PAZMs) to the polymer surfaces through capillary action, followed by simple peeling with tweezers to remove the unanodized metal Zr foil. The resulting PAZM-laminated surfaces exhibited excellent surface chemical and physical durability. Our technique also allowed the reuse of a single Zr foil piece multiple times for several anodization and lamination cycles.

  1. Mechanical Behavior of Yttria-Stabilized Zirconia Aqueous Cast Tapes and Laminates

    Directory of Open Access Journals (Sweden)

    V. Moreno

    2014-01-01

    Full Text Available Aqueous tape casting was used to produce yttria-stabilized zirconia films for electrolyte-supported solid oxide fuel cell (SOFC. Tape casting slurries were prepared varying the binder content between 20 and 25 wt%. A commercial acrylic emulsion served as binder. Rheological measurements of the two slurries were performed. Both slurries showed a shear-thinning behavior. Tapes with 25 wt% binder exhibited adequate flexibility and a smooth and homogeneous surface, free of cracks and other defects. Suitable conditions of lamination were found and a theoretical density of 54% in the laminates was achieved. Laminated tapes showed higher tensile strength compared to single sheets. Tape orientation has a significant influence on the mechanical properties. Tensile strength, elongation to strain, and Young’s modulus measured in samples produced in the direction of casting showed higher property values.

  2. Improved Long-Term Stability of Transparent Conducting Electrodes Based on Double-Laminated Electrosprayed Antimony Tin Oxides and Ag Nanowires

    Directory of Open Access Journals (Sweden)

    Koo B.-R.

    2017-06-01

    Full Text Available We fabricated double-laminated antimony tin oxide/Ag nanowire electrodes by spin-coating and electrospraying. Compared to pure Ag nanowire electrodes and single-laminated antimony tin oxide/Ag nanowire electrodes, the double-laminated antimony tin oxide/Ag nanowire electrodes had superior transparent conducting electrode performances with sheet resistance ~19.8 Ω/□ and optical transmittance ~81.9%; this was due to uniform distribution of the connected Ag nanowires because of double lamination of the metallic Ag nanowires without Ag aggregation despite subsequent microwave heating at 250°C. They also exhibited excellent and superior long-term chemical and thermal stabilities and adhesion to substrate because double-laminated antimony tin oxide thin films act as the protective layers between Ag nanowires, blocking Ag atoms penetration.

  3. [Determination of short chain chlorinated paraffins in leather products by solid phase extraction coupled with gas chromatography-mass spectrometry].

    Science.gov (United States)

    Zhang, Weiya; Wan, Xin; Li, Lixia; Wang, Chengyun; Jin, Shupei; Xing, Jun

    2014-10-01

    The short chain chlorinated paraffins (SCCPs) are the additives frequently used in the leather production in China, but they have been put into the list of forbidden chemicals issued by European Union recently. In fact, there is not a commonly recognized method for the determination of the SCCPs in the leather products due to the serious matrix interferences from the leather products and the complex chemical structures of the SCCPs. A method of solid phase extraction coupled with gas chromatography-mass spectrometry (SPE-GC-MS) was established for the determination of the SCCPs in the leather products after the optimization of the SPE conditions. It was found that the interferences from the leather products were thor- oughly separated from the analyte of the SCCPs on a home-made solid phase extraction (SPE) column filled with silica packing while eluted with a mixed solvent of n-hexane-methylene chloride (2:1, v/v). With this method, the recoveries for the SCCPs spiked in the real leather samples varied from 90.47% to 99.00% with the relative standard deviations (RSDs) less than 6.7%, and the limits of detection (LODs) were between 0.069 and 0.110 mg/kg. This method is suitable for qualitative and quantitative analysis of SCCPs in the leather products.

  4. Use of ultrasound in leather processing industry: effect of sonication on substrate and substances--new insights.

    Science.gov (United States)

    Sivakumar, Venkatasubramanian; Swaminathan, Gopalaraman; Rao, Paruchuri Gangadhar; Muralidharan, Chellappa; Mandal, Asit Baran; Ramasami, Thirumalachari

    2010-08-01

    Influence of ultrasound (US) on various unit operations in leather processing has been studied with the aim to improve the process efficiency, quality, reduce process time and achieve near-zero discharge levels in effluent streams as a cleaner option. Effect of US on substrate (skin/leather) matrix as well as substances used in different unit operations have been studied and found to be useful in the processing. Absorption of US energy by leather in process vessel at different distances from US source has been measured and found to be significant. Effect of particle-size of different substances due to sonication indicates positive influence on the diffusion through the matrix. Our experimental results suggest that US effect is better realized for the cases with pronounced diffusion hindrance. Influence of US on bioprocessing of leather has been studied and found beneficial. Attempts have also been made to improve the US aided processing using external aids. Operating US in pulse mode operation could be useful in order to reduce the electrical energy consumption. Use of US has also been studied in the preparation of leather auxiliaries involving mass-transfer resistance. Preliminary cost analysis carried out for ultrasound-assisted leather-dyeing process indicates scale-up possibility. Therefore, US application provide improvement in process efficiency as well as making cleaner production methods feasible. Hence, overall results suggest that use of US in leather industry is imminent and potential viable option in near future.

  5. Direct Composite Laminate Veneers: Three Case Reports

    Directory of Open Access Journals (Sweden)

    Bora Korkut

    2013-05-01

    Full Text Available Re-establishing a patient’s lost dental esthetic appearance is one of the most important topics for contemporary dentistry. New treatment materials and methods have been coming on the scene, day by day, in order to achieve such an aim. Most dentists prefer more conservative and aesthetic approaches, such as direct and indirect laminate veneer restorations, instead of full-ceramic crowns for anteriors where aesthetics is really important. Laminate veneers are restorations which are envisioned to correct existing abnormalities, esthetic deficiencies and discolorations. Laminate veneer restorations may be processed in two different ways: direct or indirect. Direct laminate veneers have no need to be prepared in the laboratory and are based on the principle of application of a composite material directly to the prepared tooth surface in the dental clinic. Indirect laminate veneers may be produced from composite materials or ceramics, which are cemented to the tooth with an adhesive resin. In this case report, direct composite laminate veneer technique used for three patients with esthetic problems related to fractures, discolorations and an old prolapsed restoration, is described and six-month follow-ups are discussed. As a conclusion, direct laminate veneer restorations may be a treatment option for patients with the esthetic problems of anterior teeth in cases similar to those reported here.

  6. Direct composite laminate veneers: three case reports.

    Science.gov (United States)

    Korkut, Bora; Yanıkoğlu, Funda; Günday, Mahir

    2013-01-01

    Re-establishing a patient's lost dental esthetic appearance is one of the most important topics for contemporary dentistry. New treatment materials and methods have been coming on the scene, day by day, in order to achieve such an aim. Most dentists prefer more conservative and aesthetic approaches, such as direct and indirect laminate veneer restorations, instead of full-ceramic crowns for anteriors where aesthetics is really important. Laminate veneers are restorations which are envisioned to correct existing abnormalities, esthetic deficiencies and discolo-rations. Laminate veneer restorations may be processed in two different ways: direct or indirect. Direct laminate veneers have no need to be prepared in the laboratory and are based on the principle of application of a composite material directly to the prepared tooth surface in the dental clinic. Indirect laminate veneers may be produced from composite materials or ceramics, which are cemented to the tooth with an adhesive resin. In this case report, direct composite laminate veneer technique used for three patients with esthetic problems related to fractures, discolorations and an old prolapsed restoration, is described and six-month follow-ups are discussed. As a conclusion, direct laminate veneer restorations may be a treatment option for patients with the esthetic problems of anterior teeth in cases similar to those reported here.

  7. Multi-objective optimization in formation tasks of leather and fur materials

    Directory of Open Access Journals (Sweden)

    Ольга Викторовна Сангинова

    2014-09-01

    Full Text Available The comparative analysis of the efficiency of different ways to obtain a compromise solution in the multi-objective constrained optimization tasks has been conducted. The analysis was performed for a number of innovative technologies of leather and fur materials forming.

  8. Production of basic chromium sulfate by using recovered chromium from ashes of thermally treated leather.

    Science.gov (United States)

    Dettmer, Aline; Nunes, Keila Guerra Pacheco; Gutterres, Mariliz; Marcílio, Nilson Romeu

    2010-04-15

    Leather wastes tanned with chromium are generated during the production process of leather, hence the wastes from hand crafted goods and footwear industries are a serious environmental problem. The thermal treatment of leather wastes can be one of the treatment options because the wastes are rich in chromium and can be used as a raw material for sodium chromate production and further to obtain several chromium compounds. The objective of this study was to utilize the chromium from leather wastes via basic chromium sulfate production to be subsequently applied in a hide tanning. The obtained results have shown that this is the first successful attempt to achieve desired base properties of the product. The result was achieved when the following conditions were applied: a molar ratio between sodium sulfite and sodium dichromate equal to 6; reaction time equal to 5 min before addition of sulfuric acid; pH of sodium dichromate solution equal to 2. Summarizing, there is an opportunity to utilize the dangerous wastes and reused them in the production scheme by minimizing or annulling the environmental impact and to attend a sustainable process development concept.

  9. PEGylated chitosan protected silver nanoparticles as water-borne coating for leather with antibacterial property.

    Science.gov (United States)

    Liu, Gongyan; Li, Kaijun; Luo, Quanqing; Wang, Haibo; Zhang, Zongcai

    2017-03-15

    Development of eco-labeled and effectively antibacterial coatings for final leather products has been desiderated both by industry and by consumers. Herein, PEGylated chitosan modified silver nanoparticles (PEG-g-CS@AgNPs) were prepared and characterized by UV-vis spectroscopy, transmission electron microscopy and dynamic light scattering. The antimicrobial activity of such silver nanoparticles was investigated against Gram-negative Escherichia coli (E. coli) and Gram-positive Staphylococcus aureus (S. aureus), exhibiting much lower minimum inhibitory concentration (MIC) than chitosan or PEG-g-CS. Water-borne coating was formed by immobilizing the PEG-g-CS@AgNPs onto the leather surface through the electrostatic interaction between amino groups of chitosan and carboxyl groups of leather collagen. Scanning electron microscopy and water contact angle were employed to study the coating's morphology and hydrophilicity, respectively. After coating, leather samples showed significantly high bactericidal efficiency with reusability after release of dead cells from the coating by simply water washing. The excellent antibacterial property of PEG-g-CS@AgNPs coating was ascribed to the combination of bacteria-resistance and bacteria-release by PEGylation, and dual bacteria-killing based on chitosan and Ag(+) release.

  10. Leather material found on a 6th B.C. Chinese bronze sword: A technical study

    Science.gov (United States)

    Luo, Wugan; Si, Yi; Wang, Hongmin; Qin, Ying; Huang, Fengchun; Wang, Changsui

    2011-09-01

    During July to November, 2006, an important archaeological excavation was conducted in Yun country, Hubei province, southern China. Chinese archaeologists found some remnant of leather materials, covered with red pigments, on a 6th century B.C. Chinese bronze sword. To understand the technology/ies that may have been utilized for manufacturing the leathers, a combined of Raman spectroscopy, FT-IR and XRF was thus applied to the remnant of leather materials. Raman analyses showed that red pigment on the leather was cinnabar (HgS). FT-IR and XRF analyses indicated that the content of some elements, such as Ca (existing as CaCO 3) and Fe (existing as Fe 2O 3), were much higher than those in the surrounding grave soil. The results inferred an application of lime depilation and retting, and the Fe-Al compound salt as tanning agent. And it was furthermore implicated that the Fe-Al salt tanning technique had been developed in the middle and late Spring and Autumn Period of China.

  11. Nanomaterials for the cleaning and pH adjustment of vegetable-tanned leather

    Science.gov (United States)

    Baglioni, Michele; Bartoletti, Angelica; Bozec, Laurent; Chelazzi, David; Giorgi, Rodorico; Odlyha, Marianne; Pianorsi, Diletta; Poggi, Giovanna; Baglioni, Piero

    2016-02-01

    Leather artifacts in historical collections and archives are often contaminated by physical changes such as soiling, which alter their appearance and readability, and by chemical changes which occur on aging and give rise to excessive proportion of acids that promote hydrolysis of collagen, eventually leading to gelatinization and loss of mechanical properties. However, both cleaning and pH adjustment of vegetable-tanned leather pose a great challenge for conservators, owing to the sensitivity of these materials to the action of solvents, especially water-based formulations and alkaline chemicals. In this study, the cleaning of historical leather samples was optimized by confining an oil-in-water nanostructured fluid in a highly retentive chemical hydrogel, which allows the controlled release of the cleaning fluid on sensitive surfaces. The chemical gel exhibits optimal viscoelasticity, which facilitates its removal after the application without leaving residues on the object. Nanoparticles of calcium hydroxide and lactate, dispersed in 2-propanol, were used to adjust the pH up to the natural value of leather, preventing too high alkalinity which causes swelling of fibers and denaturation of the collagen. The treated samples were characterized using scanning electron microscopy, controlled environment dynamic mechanical analysis, and infrared spectroscopy. The analytical assessment validated the use of tools derived from colloid and materials science for the preservation of collagen-based artifacts.

  12. Utilization of agricultural by-products to supplement gelatin in preparation of products for leather

    Science.gov (United States)

    When polyphenolic-modified gelatin-products were used as fillers, improvements were seen in the subjective properties of the leather. When the treated samples were compared to control samples, there were no significant changes in mechanical properties. Gelatin is in high demand and short supply, a...

  13. Utilization of agricultural by-products to partially replace gelatin in preparation of products for leather

    Science.gov (United States)

    When polyphenolic-modified gelatin-products were used as fillers, improvements were seen in the subjective properties of the leather. When the treated samples were compared to control samples, there were no significant changes in mechanical properties. At the present time, gelatin is in short supp...

  14. Removal of organic dyes using Cr-containing activated carbon prepared from leather waste.

    Science.gov (United States)

    Oliveira, Luiz C A; Coura, Camila Van Zanten; Guimarães, Iara R; Gonçalves, Maraisa

    2011-09-15

    In this work, hydrogen peroxide decomposition and oxidation of organics in aqueous medium were studied in the presence of activated carbon prepared from wet blue leather waste. The wet blue leather waste, after controlled pyrolysis under CO(2) flow, was transformed into chromium-containing activated carbons. The carbon with Cr showed high microporous surface area (up to 889 m(2)g(-1)). Moreover, the obtained carbon was impregnated with nanoparticles of chromium oxide from the wet blue leather. The chromium oxide was nanodispersed on the activated carbon, and the particle size increased with the activation time. It is proposed that these chromium species on the carbon can activate H(2)O(2) to generate HO radicals, which can lead to two competitive reactions, i.e. the hydrogen peroxide decomposition or the oxidation of organics in water. In fact, in this work we observed that activated carbon obtained from leather waste presented high removal of methylene blue dye combining the adsorption and oxidation processes.

  15. Developing Status of Waxes for Leather%皮革用蜡发展现状

    Institute of Scientific and Technical Information of China (English)

    张建雨; 满杰; 冯跃跃; 杨顺立; 冯强; 阚冬梅

    2011-01-01

    The current developing situation of the waxes for leather both at home and abroad is introduced in this paper.The applications of synthetic wax, chloridized paraffin, emulsifying wax and micro-powder wax, etc.for leather are introduced.Many kinds of waxes for leather were analyzed in the current production situation and properties, such as the pull-up wax, white smog wax, charring wax, handle wax, luster wax, filling wax, and so on.And at the same time the suggestion about the domestic development of leather wax were pointed out.%本文综述了国内外皮革用蜡的发展现状.介绍了合成酯蜡、氯化石蜡、乳化蜡、微粉蜡等在皮革中的应用.分析了皮革变色蜡、皮革白雾蜡、皮革烧焦蜡、皮革手感蜡、皮革上光蜡、皮革填充蜡等皮革用蜡的生产现状及性能特点,并对我国发展皮革用蜡提出了几点意见.

  16. APPLICATION OF THE COLLAGENOUS FIBER FROM THE SOLID WASTES OF LEATHER FOR PAPERMAKING

    Institute of Scientific and Technical Information of China (English)

    ZhijieWang; JianWang; ZhangChuanbo; HouXiaodong

    2004-01-01

    The capability of pulping for the solid waste ofleather was investigated. The properties of paper thatmade up of collagenous fiber and plant fiber werealso analyzed. The result showed that by propertreatment, solid waste of leather could be made intocollagen fiber for papermaking. The physical strengthof paper can be enhanced by appending collagenousfiber in a proper propriety.

  17. A REVIEW ON HEAVY METALS CONTENTS IN HIDE, SKIN AND PROCESSED LEATHERS

    Directory of Open Access Journals (Sweden)

    KOIZHAIGANOVA Meruyert

    2016-05-01

    Full Text Available Heavy metals are metals with high atomic weight which can be deposited in soil, water, plants and animals. It is generally known that mammal tissues are good bioindicators of trace elements, including heavy metals. Heavy metal analysis serves to identify and quantify the elements that are a potential hazard to the consumer after varying levels of contact. Usage area of leather is increasingly expanding in these days and it has also become a material requested and demanded by effect of fashion. Leather must protect its appearance and physical stability and also be problem-free in ecological terms and harmless to human health. There is a lack of data concerning the content of toxic elements in raw hide and skin of animals. Mainly information concerning metals content, including toxic ones, in processed leathers may be found in the literature. The aim of the present study was to review and compare the content of some heavy metals in raw hide, skin and the processed leathers in order to evaluate their accumulation and transition to the end-up product.

  18. Effect of age on leather and skin traits of slaughter ostriches

    African Journals Online (AJOL)

    Schalk Cloete

    Little is known about the factors affecting leather and skin traits in ostriches. The effect of age on ... of the skin. It was contended that this measure was adopted to control an ..... Ph.D. dissertation, University of New England, Armidale, Australia.

  19. Meshfree modeling in laminated composites

    KAUST Repository

    Simkins, Daniel Craig

    2012-09-27

    A problem of increasing importance in the aerospace industry is in detailed modeling of explicit fracture in laminated composite materials. For design applications, the simulation must be capable of initiation and propagation of changes in the problem domain. Further, these changes must be able to be incorporated within a design-scale simulation. The use of a visibility condition, coupled with the local and dynamic nature of meshfree shape function construction allows one to initiate and explicitly open and propagate holes inside a previously continuous problem domain. The method to be presented naturally couples to a hierarchical multi-scale material model incorporating external knowldege bases to achieve the goal of a practical explicit fracture modeling capability for full-scale problems. © 2013 Springer-Verlag.

  20. Shielding Effectiveness of Laminated Shields

    Directory of Open Access Journals (Sweden)

    B. P. Rao

    2008-12-01

    Full Text Available Shielding prevents coupling of undesired radiated electromagnetic energy into equipment otherwise susceptible to it. In view of this, some studies on shielding effectiveness of laminated shields with conductors and conductive polymers using plane-wave theory are carried out in this paper. The plane wave shielding effectiveness of new combination of these materials is evaluated as a function of frequency and thickness of material. Conductivity of the polymers, measured in previous investigations by the cavity perturbation technique, is used to compute the overall reflection and transmission coefficients of single and multiple layers of the polymers. With recent advances in synthesizing stable highly conductive polymers these lightweight mechanically strong materials appear to be viable alternatives to metals for EM1 shielding.

  1. Flat laminated microbial mat communities

    Science.gov (United States)

    Franks, Jonathan; Stolz, John F.

    2009-10-01

    Flat laminated microbial mats are complex microbial ecosystems that inhabit a wide range of environments (e.g., caves, iron springs, thermal springs and pools, salt marshes, hypersaline ponds and lagoons, methane and petroleum seeps, sea mounts, deep sea vents, arctic dry valleys). Their community structure is defined by physical (e.g., light quantity and quality, temperature, density and pressure) and chemical (e.g., oxygen, oxidation/reduction potential, salinity, pH, available electron acceptors and donors, chemical species) parameters as well as species interactions. The main primary producers may be photoautotrophs (e.g., cyanobacteria, purple phototrophs, green phototrophs) or chemolithoautophs (e.g., colorless sulfur oxidizing bacteria). Anaerobic phototrophy may predominate in organic rich environments that support high rates of respiration. These communities are dynamic systems exhibiting both spatial and temporal heterogeneity. They are characterized by steep gradients with microenvironments on the submillimeter scale. Diel oscillations in the physical-chemical profile (e.g., oxygen, hydrogen sulfide, pH) and species distribution are typical for phototroph-dominated communities. Flat laminated microbial mats are often sites of robust biogeochemical cycling. In addition to well-established modes of metabolism for phototrophy (oxygenic and non-oxygenic), respiration (both aerobic and anaerobic), and fermentation, novel energetic pathways have been discovered (e.g., nitrate reduction couple to the oxidation of ammonia, sulfur, or arsenite). The application of culture-independent techniques (e.g., 16S rRNA clonal libraries, metagenomics), continue to expand our understanding of species composition and metabolic functions of these complex ecosystems.

  2. Supersonic Flutter of Laminated Curved Panels

    Directory of Open Access Journals (Sweden)

    M. Ganapathi

    1995-04-01

    Full Text Available Supersonic flutter analysis of laminated composite curved panels is investigated using doubly-curved, quadrilateral, shear flexible, shell element based on field-consistency approach. The formulation includes transverse shear deformation, in-plane and rotary inertias. The aerodynamic force is evaluated using two-dimensional static aerodynamic approximation for high supersonic flow. Initially, the model developed here is verified for the flutter analysis of flat plates. Numerical results are presented for isotropic, orthotropic and laminated anisotropic curved panels. A detailed parametric study is carried out to observe the effects of aspect and thickness ratios, number of layers, lamination scheme, and boundary conditions on flutter boundary.

  3. Advances in Emulsified Wax for Leather Finishes%皮革涂饰乳化蜡的研究进展

    Institute of Scientific and Technical Information of China (English)

    冯国琳

    2012-01-01

    The preparation method and action principle of emulsified wax for leather finishes were introduced,and then the research advances in emulsified wax for leather finishes at home and abroad were reviewed.Finally,some suggestions for developing emulsified wax for leather finishes were provided.%介绍了皮革涂饰乳化蜡的制备方法及作用原理,综述了国内外皮革涂饰乳化蜡的应用研究进展,对国内皮革涂饰乳化蜡的发展提了几点参考意见。

  4. Influence of bress laminate volume fraction on electromechanical properties of externally laminated coated conductor tapes

    Energy Technology Data Exchange (ETDEWEB)

    Bautista, Zhierwinjay M.; Shin, Hyung Seop [Dept. of Mechanical Design Engineering, Andong National University, Andong (Korea, Republic of); Lee, Jae Hun; Lee, Hun Ju; Moon, Seung Hyun [SuNAM Co Ltd., Anseong (Korea, Republic of)

    2016-09-15

    The enhancement of mechanical properties of coated conductor (CC) tapes in practical application are usually achieved by reinforcing through lamination or electroplating metal layers on either sides of the CC tape. Mechanical or electromechanical properties of the CC tapes have been largely affected by the lamination structure under various loading modes such as tension, bending or even cyclic. In this study, the influence of brass laminate volume fraction on electromechanical properties of RCE-DR processed Gadolinium-barium-copper-oxide (GdBCO) CC tapes was investigated. The samples used were composed of single-side and both-side laminate of brass layer to the Cu-stabilized CC tape and their Ic behaviors were compared to those of the Cu-stabilized CC tape without external lamination. The stress/strain dependences of Ic in laminated CC tapes under uniaxial tension were analyzed and the irreversible stress/strain limits were determined. As a result, the increase of brass laminate volume fraction initially increased the irreversible strain limit and became gradual. The corresponding irreversible stress limit, however, showed no difference even though the brass laminate volume fraction increased to 3.4. But the irreversible load limit linearly increased with the brass laminate volume fraction.

  5. Free edge effects in laminated composites

    Science.gov (United States)

    Herakovich, C. T.

    1989-01-01

    The fundamental mechanics of free-edge effects in laminated fiber-reinforced composites is examined, reviewing the results of recent experimental and analytical investigations. The derivation of the governing equations for the basic problem is outlined, including the equilibrium and mismatch conditions and the elasticity formulation, and experimental data on axial displacement and shear strain in angle-ply laminates are summarized. Numerical predictions of free-edge deformation and interlaminar and through-thickness stress distributions are presented for cross-ply, angle-ply, and quasi-isotropic laminates, and the mechanisms of edge damage and failure in angle-ply laminates are briefly characterized. Extensive diagrams, drawings, graphs, and photographs are provided.

  6. Pattern recognition of laminated sediments methodology

    Science.gov (United States)

    Barba-Rojo, Perla Karina; Solorza-Calderón, Selene; González-Fernández, Antonio

    2016-12-01

    This work presents a different aproach for laminae counting and thickness measurements on laminated sediment images. This is done by the use of morphological operations and minimum variance quantization.

  7. Oseledec multiplicative ergodic theorem for laminations

    CERN Document Server

    Nguyên, Viêt-Anh

    2017-01-01

    Given a n-dimensional lamination endowed with a Riemannian metric, the author introduces the notion of a multiplicative cocycle of rank d, where n and d are arbitrary positive integers. The holonomy cocycle of a foliation and its exterior powers as well as its tensor powers provide examples of multiplicative cocycles. Next, the author defines the Lyapunov exponents of such a cocycle with respect to a harmonic probability measure directed by the lamination. He also proves an Oseledec multiplicative ergodic theorem in this context. This theorem implies the existence of an Oseledec decomposition almost everywhere which is holonomy invariant. Moreover, in the case of differentiable cocycles the author establishes effective integral estimates for the Lyapunov exponents. These results find applications in the geometric and dynamical theory of laminations. They are also applicable to (not necessarily closed) laminations with singularities. Interesting holonomy properties of a generic leaf of a foliation are obtained...

  8. Laminate mechanics for balanced woven fabrics

    NARCIS (Netherlands)

    Akkerman, Remko

    2006-01-01

    Laminate mechanics equations are presented for composites with balanced woven fabric reinforcements. It is shown that mimicking these textile composites with equivalent transversely isotropic (‘unidirectional’) layers requires disputable manipulations. Various micromechanics predictions of textile

  9. Optimization of laminates subjected to failure criterion

    Directory of Open Access Journals (Sweden)

    E. Kormaníková

    2011-01-01

    Full Text Available The paper is aimed on laminate optimization subjected to maximum strain criterion. The optimization problem is based on the use of continuous design variables. The thicknesses of layers with the known orientation are used as design variables. The optimization problem with strain constraints are formulated to minimize the laminate weight. The design of the final thickness is rounded off to integer multiples of the commercially available layer thickness.

  10. Direct Composite Laminate Veneers: Three Case Reports

    OpenAIRE

    Korkut, Bora; Yanıkoğlu, Funda; GÜNDAY, Mahir

    2013-01-01

    Re-establishing a patient’s lost dental esthetic appearance is one of the most important topics for contemporary dentistry. New treatment materials and methods have been coming on the scene, day by day, in order to achieve such an aim. Most dentists prefer more conservative and aesthetic approaches, such as direct and indirect laminate veneer restorations, instead of full-ceramic crowns for anteriors where aesthetics is really important. Laminate veneers are restorations which are envisioned ...

  11. Laminopathy-inducing lamin A mutants can induce redistribution of lamin binding proteins into nuclear aggregates.

    Science.gov (United States)

    Hübner, S; Eam, J E; Hübner, A; Jans, D A

    2006-01-15

    Lamins, members of the family of intermediate filaments, form a supportive nucleoskeletal structure underlying the nuclear envelope and can also form intranuclear structures. Mutations within the A-type lamin gene cause a variety of degenerative diseases which are collectively referred to as laminopathies. At the molecular level, laminopathies have been shown to be linked to a discontinuous localization pattern of A-type lamins, with some laminopathies containing nuclear lamin A aggregates. Since nuclear aggregate formation could lead to the mislocalization of proteins interacting with A-type lamins, we set out to examine the effects of FLAG-lamin A N195K and R386K protein aggregate formation on the subnuclear distribution of the retinoblastoma protein (pRb) and the sterol responsive element binding protein 1a (SREBP1a) after coexpression as GFP-fusion proteins in HeLa cells. We observed strong recruitment of both proteins into nuclear aggregates. Nuclear aggregate recruitment of the NPC component nucleoporin NUP153 was also observed and found to be dependent on the N-terminus. That these effects were specific was implied by the fact that a number of other coexpressed karyophilic GFP-fusion proteins, such as the nucleoporin NUP98 and kanadaptin, did not coaggregate with FLAG-lamin A N195K or R386K. Immunofluorescence analysis further indicated that the precursor form of lamin A, pre-lamin A, could be found in intranuclear aggregates. Our results imply that redistribution into lamin A-/pre-lamin A-containing aggregates of proteins such as pRb and SREBP1a could represent a key aspect underlying the molecular pathogenesis of certain laminopathies.

  12. Soybean plant growth study conducted using purified protein hydrolysate-based fertilizer made from chrome-tanned leather waste.

    Science.gov (United States)

    Pati, Anupama; Chaudhary, Rubina

    2015-12-01

    Leather processing discharges enormous amount of chrome containing leather solid waste which creates a major disposal problem. Chrome-tanned leather solid waste is a complex of collagen and chromium. The presence of chromium limits protein application in fertilizer industry. The purified protein hydrolysate with zero chromium could be used as a nitrogen source for fertilizer formulation. In this study, an attempt has been made to employ purified protein hydrolysate derived from chrome-tanned leather shavings (CTLS) in formulation of fertilizer. The formulated fertilizer (1–3 t ha(-1)) is employed as nitrogen source in production of soybean. Plant growth study demonstrates that formulated fertilizer dosage 3 t ha(-1) produced similar effects of commercial fertilizer-treated plants. Application of formulated fertilizer yielded higher seed in plant than commercial fertilizer.

  13. The Review of Leather Wastes Recycling%革屑资源化利用研究进展

    Institute of Scientific and Technical Information of China (English)

    栾俊; 刁屾; 陈沛海; 王全杰

    2016-01-01

    The resource utilization of chrome-free leather wastes,chrome leather wastes and vegetable tanning leather wastes was reviewed in this paper.The directions of different kinds solid wastes's recycling and the high value transformation were carried out.and circular economy and green development of leather industry were realized.%综述了国内外制革固体废弃物中无铬革屑、含铬革屑以及植鞣革屑的资源化利用现状,提出不同种类固体废弃物的回收利用以及高值转化的方向,实现循环经济以及制革行业的绿色发展.

  14. Scarf Repair of Composite Laminates

    Directory of Open Access Journals (Sweden)

    Xie Zonghong

    2016-01-01

    Full Text Available The use of composite materials, such as carbon-fiber reinforced plastic (CFRP composites, aero-structures has led to an increased need of advanced assembly joining and repair technologies. Adhesive bonded repairs as an alternative to recover full or part of initial strength were investigated. Tests were conducted with the objective of evaluating the effectiveness of techniques used for repairing damage fiber reinforced laminated composites. Failure loads and failure modes were generated and compared with the following parameters: scarf angles, roughness of grind tool and number of external plies. Results showed that scarf angle was the critical parameter and the largest tensile strength was observed with the smallest scarf angle. Besides, the use of external plies at the outer surface could not increase the repairs efficiency for large scarf angle. Preparing the repair surfaces by sanding them with a sander ranging from 60 to 100 grit number had significant effect on the failure load. These results allowed the proposal of design principles for repairing CFRP structures.

  15. Effect of laminate edge conditions on the formation of microvoids in composite laminates

    Science.gov (United States)

    Anderson, J. P.; Altan, M. C.

    2015-05-01

    Manufacturing defects such as microvoids are common in thermoset composite components and are known to negatively affect their strength. The resin pressure developed in and the resin flow out from the laminates during cure have been reported to be the primary factors influencing the final void content of a composite component. In this work, the effect of laminate edge conditions during the cure process on the formation of microvoids was experimentally investigated. This was achieved by fabricating eight-ply laminates from TenCate® BT250/7781 prepreg in a hot-press at a constant cure pressure of 170 kPa while limiting the laminate perimeter available for resin flow by 0%, 25%, 50%, 75%, and 100%. The individual plies of these five laminates were conditioned at 99% relative humidity before curing to maximize the moisture present in the lay-up before fabrication. The presence of moisture in the lay-ups was expected to promote void formation and allow the effect of restricting flow at the edges of a laminate to be better identified. The restriction of resin outflow was found to cause the average characteristic void diameter to decrease by 17% and void content to rise by 33%. This phenomenon was identified to be a result of the outflow restriction increasing the number of voids trapped within the laminate and indicates that for laminates cured at low pressures resin outflow is the dominant mechanism for void reduction.

  16. The influence of Chromium supplied by tanning and wet finishing processes on the formation of cr(vi in leather

    Directory of Open Access Journals (Sweden)

    W. F. Fuck

    2011-06-01

    Full Text Available Chromium used in leather manufacturing can be oxidized from the trivalent to the hexavalent state, causing environmental concerns. In this study, the influence of Cr(III from tanning, deacidification pH, fatliquors, chrome retanning and vegetable retanning on the formation of Cr(VI in leather was analyzed by comparing natural and aged samples. In wet-blue leather, even after aging and in fatliquored leathers that did not suffer the aging process, the presence of Cr(VI was always below the detection limit of 3 mg/kg. Considering the presence of Cr(VI, the supply of chromium during the retanning step had a more significant effect than during the tanning. In the fatliquoring process with sulfites, fish and synthetic fatliquor leather samples contained Cr(VI when aged, and the highest concentration detected was 26.7 mg/kg. The evaluation of Cr(VI formation led to recommendations for regulation in the leather industry.

  17. Strength and fatigue life evaluation of composite laminate with embedded sensors

    Science.gov (United States)

    Rathod, Vivek T.; Hiremath, S. R.; Roy Mahapatra, D.

    2014-04-01

    Prognosis regarding durability of composite structures using various Structural Health Monitoring (SHM) techniques is an important and challenging topic of research. Ultrasonic SHM systems with embedded transducers have potential application here due to their instant monitoring capability, compact packaging potential toward unobtrusiveness and noninvasiveness as compared to non-contact ultrasonic and eddy current techniques which require disassembly of the structure. However, embedded sensors pose a risk to the structure by acting as a flaw thereby reducing life. The present paper focuses on the determination of strength and fatigue life of the composite laminate with embedded film sensors like CNT nanocomposite, PVDF thin films and piezoceramic films. First, the techniques of embedding these sensors in composite laminates is described followed by the determination of static strength and fatigue life at coupon level testing in Universal Testing Machine (UTM). Failure mechanisms of the composite laminate with embedded sensors are studied for static and dynamic loading cases. The coupons are monitored for loading and failure using the embedded sensors. A comparison of the performance of these three types of embedded sensors is made to study their suitability in various applications. These three types of embedded sensors cover a wide variety of applications, and prove to be viable in embedded sensor based SHM of composite structures.

  18. Ternary semitransparent organic solar cells with a laminated top electrode

    Science.gov (United States)

    Makha, Mohammed; Testa, Paolo; Anantharaman, Surendra Babu; Heier, Jakob; Jenatsch, Sandra; Leclaire, Nicolas; Tisserant, Jean-Nicolas; Véron, Anna C.; Wang, Lei; Nüesch, Frank; Hany, Roland

    2017-01-01

    Abstract Tinted and colour-neutral semitransparent organic photovoltaic elements are of interest for building-integrated applications in windows, on glass roofs or on facades. We demonstrate a semitransparent organic photovoltaic cell with a dry-laminated top electrode that achieves a uniform average visible transmittance of 51% and a power conversion efficiency of 3%. The photo-active material is based on a majority blend composed of a visibly absorbing donor polymer and a fullerene acceptor, to which a selective near-infrared absorbing cyanine dye is added as a minority component. Our results show that organic ternary blends are attractive for the fabrication of semitransparent solar cells in general, because a guest component with a complementary absorption can compensate for the inevitably reduced current generation capability of a high-performing binary blend when applied as a thin, semitransparent film. PMID:28179960

  19. Ternary semitransparent organic solar cells with a laminated top electrode.

    Science.gov (United States)

    Makha, Mohammed; Testa, Paolo; Anantharaman, Surendra Babu; Heier, Jakob; Jenatsch, Sandra; Leclaire, Nicolas; Tisserant, Jean-Nicolas; Véron, Anna C; Wang, Lei; Nüesch, Frank; Hany, Roland

    2017-01-01

    Tinted and colour-neutral semitransparent organic photovoltaic elements are of interest for building-integrated applications in windows, on glass roofs or on facades. We demonstrate a semitransparent organic photovoltaic cell with a dry-laminated top electrode that achieves a uniform average visible transmittance of 51% and a power conversion efficiency of 3%. The photo-active material is based on a majority blend composed of a visibly absorbing donor polymer and a fullerene acceptor, to which a selective near-infrared absorbing cyanine dye is added as a minority component. Our results show that organic ternary blends are attractive for the fabrication of semitransparent solar cells in general, because a guest component with a complementary absorption can compensate for the inevitably reduced current generation capability of a high-performing binary blend when applied as a thin, semitransparent film.

  20. Production of Leather Brown RH%皮革棕RH生产合成

    Institute of Scientific and Technical Information of China (English)

    宋内理

    2012-01-01

    The production process of leather brown RH was given. Diazotization and coupling reaction composition, pH value, time, temperature, reaction end point were stated in detail. And the performance index of products in leather application was pointed out.%主要论述了皮革棕RH产品,车间的生产工艺操作流程,对重氮化、偶合各反应组成,pH值、时间、温度、反应终点作了进一步的详细说明,最后论述了产品在皮革上的应用性能指标。

  1. Surface modification of polyester synthetic leather with tetramethylsilane by atmospheric pressure plasma

    Science.gov (United States)

    Kan, C. W.; Kwong, C. H.; Ng, S. P.

    2015-08-01

    Much works have been done on synthetic materials but scarcely on synthetic leather owing to its surface structures in terms of porosity and roughness. This paper examines the use of atmospheric pressure plasma (APP) treatment for improving the surface performance of polyester synthetic leather by use of a precursor, tetramethylsilane (TMS). Plasma deposition is regarded as an effective, simple and single-step method with low pollution. Scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS) and Fourier transform infrared spectroscopy (FTIR) confirm the deposition of organosilanes on the sample's surface. The results showed that under a particular combination of treatment parameters, a hydrophobic surface was achieved on the APP treated sample with sessile drop static contact angle of 138°. The hydrophobic surface is stable without hydrophilic recovery 30 days after plasma treatment.

  2. Treatment of leather industrial wastewater via combined advanced oxidation and membrane filtration.

    Science.gov (United States)

    Abdel-Shafy, Hussein I; El-Khateeb, Mohamed A; Mansour, Mona S M

    The liming/unhairing operation is among the important processes of the leather industry. It generates large amounts of effluent that are highly loaded with organic hazard wastes. Such effluent is considered one of the most obnoxious materials in the leather industry, causing serious environmental pollution and health risks. The effluent is characterized by high concentrations of the pollution parameters. Conventional chemical and/or biological treatment of such wastewater is inefficient to meet the required limits of standard specifications, due to the presence of resistant and toxic compounds. The present investigation deals with an effective treatment approach for the lime/unhair effluent using the Fenton reaction followed by membrane filtration. The experiment was extended to a laboratory pilot-scale in a continuous treatment study. In this study the raw wastewater was treated with the predetermined Fenton's optimum dose followed by membrane filtration. The wastewater was efficiently treated and the final effluent met the standards for unrestricted water reuse.

  3. Fitting Irregular Shape Figures into Irregular Shape Areas for the Nesting Problem in the Leather Industry

    Directory of Open Access Journals (Sweden)

    Guevara-Palma Luis

    2015-01-01

    Full Text Available The nesting problem of irregular shapes within irregular areas has been studied from several approaches due to their application in different industries. The particular case of cutting leather involves several restrictions that add complexity to this problem, it is necessary to generate products that comply with the quality required by customers This paper presents a methodology for the accommodation of irregular shapes in an irregular area (leather considering the constraints set by the footwear industry, and the results of this methodology when applied by a computer system. The scope of the system is to develop a working prototype that operates under the guidelines of a commercial production line of a sponsor company. Preliminary results got a reduction of 70% of processing time and improvement of 5% to 7% of the area usage when compared with manual accommodation.

  4. Speciation of chromium in soils near Sheba Leather Industry, Wukro Ethiopia.

    Science.gov (United States)

    Gitet, Hintsa; Subramanian, P A; Minilu, Daniel; Kiros, Teame; Hilawie, Masho; Gebremariam, Gebremedhin; Taye, Kebede

    2013-11-15

    A study on speciation of chromium in soils near Sheba Leather Industry was performed by Flame Atomic Absorption (FAAS) after selective extraction of Cr(VI) using the EPA 3060A method, and oxidizing the Cr(III) residue in the soils with HNO3 and H2O2. The extraction method was evaluated using the spiking method with satisfactory results (recoveries>95% and RSDssoil samples collected from a distance of about 2 km from the main Industry and effluent stream. The results indicate that higher total chromium content was observed in soils collected from the target area. Nevertheless, the maximum concentrations of Cr(VI) found in soil samples collected around Sheba Leather Industry was 9.9 µg g(-1) and are within the acceptable level of 10 µg g(-1) in accordance with the WHO. Copyright © 2013 Elsevier B.V. All rights reserved.

  5. Boots of Leather, Slippers of Gold: The History of a Lesbian Community

    Directory of Open Access Journals (Sweden)

    Maria Chiara Ferro

    2016-03-01

    Full Text Available Elizabeth Lapovsky Kennedy, Madeline D. Davis, Boots of Leather, Slippers of Gold: The History of a Lesbian Community (1993. New York: Routledge, 2014.   La recensione sottolinea la rilevanza del volume Boots of Leather, Slippers of Gold a vent’anni dalla pubblicazione, sia perché raccoglie e preserva testimonianze di butches e femmes degli anni ’40 e ’50, sia perché chiarisce il ruolo sociale della comunità butch-femme in quanto sede di resistenza pre-politica. Inoltre, si evidenzia l’utilità di modelli interpretativi informati dagli studi queer e transgender nell’ambito della ricerca storica su identità non normative come quelle butch e femme.

  6. Chromium Displacement in Subtropical Soils Fertilized with Hydrolysed Leather: A Laboratory Study.

    Science.gov (United States)

    Bavaresco, Jovana; Fink, Jessé R; Rodrigues, Maria Lucia K; Gianello, Clesio; Barrón, Vidal; Torrent, José

    2016-12-01

    Prolonged use of biosolids with high metal content may result in diffuse pollution across large regions, especially if such ions can move freely through the soil profile and reach underground water sources. The objective of this study was to verify whether Cr added to the soil surface in the form of hydrolysed leather or a soluble salt would migrate over significant distances in four subtropical soils differing in physical, chemical and mineralogical properties. Horizontal and vertical mobility were assessed in Petri dishes and small pots, respectively, using low (12 mg kg(-1) soil) and high Cr levels (150 mg kg(-1) soil) added to the soil surface. Irrespective of concentration, soluble Cr salts were found to move more easily in soils with low organic matter and clay content. Contrarily, Cr added as hydrolysed leather exhibited negligible mobility and tended to accumulate in the vicinity of application.

  7. [Leather dust and systematic research on occupational tumors: the national and regional registry TUNS].

    Science.gov (United States)

    Mensi, Carolina; Sieno, Claudia; Consonni, Dario; Riboldi, Luciano

    2012-01-01

    The sinonasal cancer (SNC) are a rare tumors characterized by high occupational etiologic fraction. For this reason their incidence and etiology can be actively monitored by a dedicated cancer registry. The National Registry of these tumours is situated at the Italian Institute for Occupational Safety and Prevention (ISPESL) and is based on Regional Operating Centres (ROCs). In Lombardy Region the ROC has been established at the end of 2007 with the purpose to make a systematic surveillance and therefore to support in the most suitable way the scientific research and the prevention actions in the high risk working sectors. The aims of this surveillance are: to estimate the regional incidence of SNC, to define different sources of occupational and environmental exposure both known (wood, leather, nickel, chromium) and unknown. The registry collects all the new incident cases of epithelial SNC occurring in residents in Lombardy Region since 01.01.2008. The regional Registry is managed according to National Guidelines. Until January 2010 we received 596 cases of suspected SNC; only 91 (15%) of these were actually incident cases according to the inclusion criteria of the Registry, and they were preferentially adenocarcinoma and squamous carcinoma. In 2008 the regional age-standardized incidence rate of SNC for males and females, respectively, is 0.8 and 0.5 per 100,000. Occupational or environmental exposure to wood or leather dust is ascertained in over the 50% of cases. The occupational exposure to leather dust was duo to work in shoe factories. Our preliminary findings confirm that occupational exposure to wood and leather dusts are the more relevant risk factors for SNC. The study of occupational sectors and job activity in cases without such exposure could suggest new etiologic hypothesis.

  8. Hydrolysis of tanned leather wastes under alkaline, acidic and oxidative conditions

    OpenAIRE

    Botić Tatjana; Ilišković Nadežda

    2006-01-01

    Different wastes in large quantities are the outcome or the by-product of processes in the tanning industry. The largest part of solid wastes is collagen based and obtained in the reprocessing steps of tanned and non-tanned products. The quality collagen substance obtained from wastes of the leather industry used as a supporting material in many reprocessing industries. Hydrolysis is the basic step of collagen processing, namely the shortening of its polypeptide chain. The main goal of this i...

  9. Effect of Solar Radiation on Viscoelastic Properties of Bovine Leather: Temperature and Frequency Scans

    Science.gov (United States)

    Nalyanya, Kallen Mulilo; Rop, Ronald K.; Onyuka, Arthur S.

    2017-04-01

    This work presents both analytical and experimental results of the effect of unfiltered natural solar radiation on the thermal and dynamic mechanical properties of Boran bovine leather at both pickling and tanning stages of preparation. Samples cut from both pickled and tanned pieces of leather of appropriate dimensions were exposed to unfiltered natural solar radiation for time intervals ranging from 0 h (non-irradiated) to 24 h. The temperature of the dynamic mechanical analyzer was equilibrated at 30°C and increased to 240°C at a heating rate of 5°C \\cdot Min^{-1}, while its oscillation frequency varied from 0.1 Hz to 100 Hz. With the help of thermal analysis (TA) control software which analyzes and generates parameter means/averages at temperature/frequency range, the graphs were created by Microsoft Excel 2013 from the means. The viscoelastic properties showed linear frequency dependence within 0.1 Hz to 30 Hz followed by negligible frequency dependence above 30 Hz. Storage modulus (E') and shear stress (σ ) increased with frequency, while loss modulus (E''), complex viscosity (η ^{*}) and dynamic shear viscosity (η) decreased linearly with frequency. The effect of solar radiation was evident as the properties increased initially from 0 h to 6 h of irradiation followed by a steady decline to a minimum at 18 h before a drastic increase to a maximum at 24 h. Hence, tanning industry can consider the time duration of 24 h for sun-drying of leather to enhance the mechanical properties and hence the quality of the leather. At frequencies higher than 30 Hz, the dynamic mechanical properties are independent of the frequency. The frequency of 30 Hz was observed to be a critical value in the behavior in the mechanical properties of bovine hide.

  10. Fracture behavior of hybrid composite laminates

    Science.gov (United States)

    Kennedy, J. M.

    1983-01-01

    The tensile fracture behavior of 15 center-notched hybrid laminates was studied. Three basic laminate groups were tested: (1) a baseline group with graphite/epoxy plies, (2) a group with the same stacking sequence but where the zero-deg plies were one or two plies of S-glass or Kevlar, and (3) a group with graphite plies but where the zero-deg plies were sandwiched between layers of perforated Mylar. Specimens were loaded linearly with time; load, far field strain, and crack opening displacement (COD) were monitored. The loading was stopped periodically and the notched region was radiographed to reveal the extent and type of damage (failure progression). Results of the tests showed that the hybrid laminates had higher fracture toughnesses than comparable all-graphite laminates. The higher fracture toughness was due primarily to the larger damage region at the ends of the slit; delamination and splitting lowered the stress concentration in the primary load-carrying plies. A linear elastic fracture analysis, which ignored delamination and splitting, underestimated the fracture toughness. For almost all of the laminates, the tests showed that the fracture toughness increased with crack length. The size of the damage region at the ends of the slit and COD measurements also increased with crack length.

  11. Lamin C and chromatin organization in Drosophila

    Indian Academy of Sciences (India)

    B. V. Gurudatta; L. S. Shashidhara; Veena K. Parnaik

    2010-04-01

    Drosophila lamin C (LamC) is a developmentally regulated component of the nuclear lamina. The lamC gene is situated in the fifth intron of the essential gene tout velu (ttv). We carried out genetic analysis of lamC during development. Phenotypic analyses of RNAi-mediated downregulation of lamC expression as well as targeted misexpression of lamin C suggest a role for lamC in cell survival. Of particular interest in the context of laminopathies is the caspase-dependent apoptosis induced by the overexpression of lamin C. Interestingly, misexpression of lamin C in the central nervous system, where it is not normally expressed, did not affect organization of the nuclear lamina. lamC mutant alleles suppressed position effect variegation normally displayed at near-centromeric and telomeric regions. Further, both downregulation and misexpression of lamin C affected the distribution of heterochromatin protein 1. Our results suggest that Drosophila lamC has a tissue-specific role during development and is required for chromatin organization.

  12. Post-Lamination Manufacturing Process Automation for Photovoltaic Modules; Annual Technical Progress Report: 15 June 1999--14 July 2000

    Energy Technology Data Exchange (ETDEWEB)

    Nowlan, M. J.; Murach, J. M.; Sutherland, S. F.; Lewis, E. R.; Hogan, S. J.

    2000-09-29

    Spire is addressing the PVMaT project goals of photovoltaic (PV) module cost reduction and improved module manufacturing process technology. New cost-effective automation processes are being developed for post-lamination PV module assembly, where post-lamination is defined as the processes after the solar cells are encapsulated. These processes apply to both crystalline and thin-film solar cell modules. Four main process areas are being addressed: (1) Module buffer storage and handling between steps; (2) Module edge trimming, edge sealing, and framing; (3) Junction-box installation; and (4) Testing for module performance, electrical isolation, and ground-path continuity.

  13. Mortality of chrome leather tannery workers and chemical exposures in tanneries.

    Science.gov (United States)

    Stern, F B; Beaumont, J J; Halperin, W E; Murthy, L I; Hills, B W; Fajen, J M

    1987-04-01

    A retrospective mortality analysis was conducted in a cohort of 9,365 individuals employed as of 1940 in two chrome leather tanneries in the United States and followed to the end of 1982. Vital status as of the closing date was determined for over 95% of the cohort. Potential hazardous workplace exposures varied with department and included nitrosamines, chromate pigments, benzidine-based direct dyestuffs, formaldehyde, leather dust, and aromatic organic solvents. Mortality from all causes combined was lower than expected for each tannery, the standardized mortality ratio being 81 for one and 93 for the other. Deaths from cancer of each site, including the lung, were also lower than expected compared to those of either the population of the United States or of local state rates. A significant excess of deaths was observed, however, due to accidental causes in one tannery and cirrhosis of the liver, suicide, and alcoholism in the other. These excesses did not appear to be causally associated with occupational exposures. The findings of this study are consistent with those of the only other mortality investigation of leather tannery employees.

  14. Surface modification of polyester synthetic leather with tetramethylsilane by atmospheric pressure plasma

    Energy Technology Data Exchange (ETDEWEB)

    Kan, C.W., E-mail: tccwk@polyu.edu.hk [Institute of Textiles and Clothing, The Hong Kong Polytechnic University, Hung Hom, Kowloon (Hong Kong); Kwong, C.H. [Institute of Textiles and Clothing, The Hong Kong Polytechnic University, Hung Hom, Kowloon (Hong Kong); Ng, S.P. [Hong Kong Community College, The Hong Kong Polytechnic University (Hong Kong)

    2015-08-15

    Highlights: • Atmospheric pressure plasma treatment improved surface performance of polyester synthetic leather with tetramethylsilane. • XPS and FTIR confirmed the deposition of organosilanes on the sample's surface. • Contact angle increases to 138° after plasma treatment. - Abstract: Much works have been done on synthetic materials but scarcely on synthetic leather owing to its surface structures in terms of porosity and roughness. This paper examines the use of atmospheric pressure plasma (APP) treatment for improving the surface performance of polyester synthetic leather by use of a precursor, tetramethylsilane (TMS). Plasma deposition is regarded as an effective, simple and single-step method with low pollution. Scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS) and Fourier transform infrared spectroscopy (FTIR) confirm the deposition of organosilanes on the sample's surface. The results showed that under a particular combination of treatment parameters, a hydrophobic surface was achieved on the APP treated sample with sessile drop static contact angle of 138°. The hydrophobic surface is stable without hydrophilic recovery 30 days after plasma treatment.

  15. Risk assessment of N,N-dimethylformamide on residents living near synthetic leather factories.

    Science.gov (United States)

    Zhang, Qingyu; Huang, Chanke; Wei, Yumei; Zhu, Qi; Tian, Weili; Wang, Cui

    2014-03-01

    Dimethylformamide (DMF) is a broad solvent used in the production of synthetic leather. Decades of year's research have been focused on workers in leather factories suffering from the release of DMF. However, little attention was paid on general population. Here, we examined the relationship between consistent DMF exposure and annual hospitalizations of local residents in Longwan, China, in 2008. We found a positive correlation with a relative risk (RR) increase of 1.110 for total hospitalizations. When the data were stratified by sex, we observed a higher correlation for female hospitalizations than for male hospitalizations, with RR values of 1.55 and 1.084, respectively. This might be attributed to the differences in genotypes of oxidant enzyme between gender. The significance of the correlations did not disappear after we excluded the extreme value of DMF or adjusted for SO2, NO2, and PM10. Population living near the leather factory has experienced almost constant DMF exposure, and real concern should be raised regarding such exposure. Governments should take responsibility for the protection of not only occupational workers but also residents, especially women.

  16. Leather Footwear from the Posad of Sviyazhsk: an Experience of Reconstrucion of Simple Porshni

    Directory of Open Access Journals (Sweden)

    Bogatova Lina F.

    2016-12-01

    Full Text Available The authors use simple porshni (one-piece leather-hide shoes from Sviyazhsk to test an approach to systemic classification of the late medieval leather footwear. They describe the main stages in restoration and reconstruction of archaeological finds, which make it possible to reproduce the cut of the parts. This approach enables examining such morphological and technological features as the cut and the assemblage, types of seams, method of decoration and ornamentation, and fastening of the shoes. It was interesting to discover traces of different mending activities on porshni, most likely meant to extend their durability. Measurements offered an approximate anthropometric profile of Sviyazhsk population. The reconstruction enabled distinguishing three types of simple porshni spread in Sviyazhsk in late 16th – early 18th centuries. Analogies helped establishing that the third version of the simple porshni from Sviyazhsk is a product of the local masters. Analysis of the raw material showed that this model used tannin leather, typical for shoe-shops.

  17. ROBUST OPTIMUM DESIGN OF LAMINATED COMPOSITE PLATES

    Institute of Scientific and Technical Information of China (English)

    WangXiangyang; ChenJianqiao

    2004-01-01

    A last-ply failure (LPF) analysis method for laminated composite plates is incorporated into the finite element code-ANSYS, and a robust optimum design method is presented. The composite structure is analyzed by considering both in-plane and out-of-plane loads. For a lamina,two major failure modes are considered: matrix failure and fiber breakage that axe characterized by the proper strength criteria in the literature. When a lamina has failed, the laminate stiffness is modified to reflect the damage, and stresses in the structure are re-analyzed. This procedure is repeatedly performed until the whole structure fails and thus the ultimate strength is determined.A structural optimization problem is solved with the fiber orientation and the lamina thickness as the design variables and the LPF load as the objective. Finally, the robust optimum design method for laminates is presented and discussed.

  18. Mechanical behaviors of notched composite laminates

    Institute of Scientific and Technical Information of China (English)

    2000-01-01

    Presents the study on the mechanical behaviors of composite laminates with both static and fatigue tests per formed with different notched specimens and concludes with experimental results that ultimate strength and initial stiff ness of various notched composite laminates is almost as same as un-notched ones but the fatigue life of notched speci mens is much higher than un-notched ones. Compared with metals, composite materials are notch insensitive. The properties measured by using bar type specimens can not represent the real properties of composite laminates. Notches on the free edge may be helpful to the structure. The fatigue life can be predicted through theoretical models estab lished using the residual stiffness model.

  19. Stochastic damage evolution in textile laminates

    Science.gov (United States)

    Dzenis, Yuris A.; Bogdanovich, Alexander E.; Pastore, Christopher M.

    1993-01-01

    A probabilistic model utilizing random material characteristics to predict damage evolution in textile laminates is presented. Model is based on a division of each ply into two sublaminas consisting of cells. The probability of cell failure is calculated using stochastic function theory and maximal strain failure criterion. Three modes of failure, i.e. fiber breakage, matrix failure in transverse direction, as well as matrix or interface shear cracking, are taken into account. Computed failure probabilities are utilized in reducing cell stiffness based on the mesovolume concept. A numerical algorithm is developed predicting the damage evolution and deformation history of textile laminates. Effect of scatter of fiber orientation on cell properties is discussed. Weave influence on damage accumulation is illustrated with the help of an example of a Kevlar/epoxy laminate.

  20. Coupled quasi-homogeneous orthotropic laminates

    Science.gov (United States)

    York, C. B.

    2011-09-01

    Laminate stacking sequence configurations with quasi-homogeneous properties are derived, whereby the inplane and out-of-plane stiffness properties are concomitant. The stacking sequence configurations contain equal-thickness layers and identical orthotropic properties, differing only by their orientations, which are represented by standard angle- and cross-ply combinations. These simplifying assumptions are in fact representative of the common design practice, but help one to identify and isolate a range of highly complex physical coupling responses, which continue to be referred to collectively in the literature as bending-extension coupling. Dimensionless parameters are developed from which the elements of the extensional, coupling, and bending stiffness matrices are readily calculated for any fibre/resin properties. Feasible domains of lamination parameters are also illustrated for each coupling response to complement abridged listings of stacking sequences. Finally, hygrothermally curvature-stable configurations with quasi-homogeneous properties are identified, thus simplifying the manufacture of laminate configurations possessing tailored mechanical coupling responses.

  1. Multifunctional Laminated Composite Materials for Protective Clothing

    Directory of Open Access Journals (Sweden)

    Nermin M. Aly

    2014-10-01

    Full Text Available Protective clothing performs a vital role in maintaining the safety of human in workplace. The developments in this field are proceeding to fulfill the needs with multifunctional materials at competitive costs. Recently, the protective clothing field introduces the usage of composite materials taking advantage of their outstanding properties. In this paper, the multifunctional performance of hybrid laminated composites (HLC was investigated aiming to be utilized in protective clothing. The influences of reinforcement and resin properties on the physical properties of the laminated composites and their resistance to puncture load and UV transmittance were studied. ANOVA test was used for the statistical analysis of the results. The results showed that, the reinforcement material and structure and the fiber/matrix interface have major influences on the laminated composites performance. It was revealed that, the HLC fabricated from (polyester/glass fabric with satin 4 structure and nonwoven glass fiber mat exhibited the best functional performance.

  2. Hybrid Laminates for Application in North Conditions

    Science.gov (United States)

    Antipov, V. V.; Oreshko, E. I.; Erasov, V. S.; Serebrennikova, N. Yu.

    2016-11-01

    A hybrid aluminum-lithium alloy/SIAL laminate as a possible material for application in structures operated in North conditions is considered. The finite-element method is used for a buckling stability analysis of hybrid panels, bars, and plates. A technique allowing one to compare the buckling stability of multilayered hybrid plates is offered. Compression tests were run on a hybrid laminate wing panel as a prototype of the top panel of TU-204SM airplane made from a high-strength B95T2 aluminum alloy. It turned out that the lighter composite panel had a higher load-carrying capacity than the aluminum one. Results of investigation into the properties the hybrid aluminum-lithium alloy/SIAL laminate and an analysis of scientific-technical data on this subject showed that this composite material could be used in the elements of airframes, including those operated in north conditions.

  3. Topology optimization of laminated plates with prestress

    DEFF Research Database (Denmark)

    Pedersen, Niels Leergaard

    2002-01-01

    Laminated plates with different prestress in the layers are topology optimized. The objectives are to minimize the deflection due to the prestress or to minimize ordinary compliance. The prestress is accounted for by including the force equivalent to the prestressing and adding the initial stress...... stiffness matrix to the structural stiffness. The calculations of sensitivities are complicated not only by the prestress but also because we are dealing with laminates. The topology optimization problem is solved using a new penalization scheme as an alternative to the SIMP (power law) approach...

  4. Energy Saving Glass Lamination via Selective Radio Frequency Heating

    Energy Technology Data Exchange (ETDEWEB)

    Allan, Shawn M.

    2012-02-27

    This project focused on advancing radio-frequency (RF) lamination technology closer to commercial implementation, in order to reduce the energy intensity of glass lamination by up to 90%. Lamination comprises a wide range of products including autoglass, architectural safety and innovative design glass, transparent armor (e.g. bullet proof glass), smart glass, mirrors, and encapsulation of photovoltaics. Lamination is also the fastest growing segment of glass manufacturing, with photovoltaics, architectural needs, and an anticipated transition to laminated side windows in vehicles. The state-of-the-art for glass lamination is to use autoclaves, which apply heat and uniform gas pressure to bond the laminates over the course of 1 to 18 hours. Laminates consist of layers of glass or other materials bonded with vinyl or urethane interlayers. In autoclaving, significant heat energy is lost heating the chamber, pressurized air, glass racks, and the glass. In RF lamination, the heat is generated directly in the vinyl interlayer, causing it to heat and melt quickly, in just 1 to 10 minutes, without significantly heating the glass or the equipment. The main purpose of this project was to provide evidence that low energy, rapid RF lamination quality met the same standards as conventionally autoclaved windows. The development of concepts for laminating curved glass with RF lamination was a major goal. Other primary goals included developing a stronger understanding of the lamination product markets described above, and to refine the potential benefits of commercial implementation. The scope of the project was to complete implementation concept studies in preparation for continuation into advanced development, pilot studies, and commercial implementation. The project consisted of 6 main tasks. The first dealt with lamination with poly-vinyl butyral (PVB) interlayers, which prior work had shown difficulties in achieving good quality laminates, working with Pilkington North

  5. Energy Saving Glass Lamination via Selective Radio Frequency Heating

    Energy Technology Data Exchange (ETDEWEB)

    Allan, Shawn M; Baranova, Inessa; Poley, Joseph; Reis, Henrique

    2012-02-27

    This project focused on advancing radio-frequency (RF) lamination technology closer to commercial implementation, in order to reduce the energy intensity of glass lamination by up to 90%. Lamination comprises a wide range of products including autoglass, architectural safety and innovative design glass, transparent armor (e.g. bullet proof glass), smart glass, mirrors, and encapsulation of photovoltaics. Lamination is also the fastest growing segment of glass manufacturing, with photovoltaics, architectural needs, and an anticipated transition to laminated side windows in vehicles. The state-of-the-art for glass lamination is to use autoclaves, which apply heat and uniform gas pressure to bond the laminates over the course of 1 to 18 hours. Laminates consist of layers of glass or other materials bonded with vinyl or urethane interlayers. In autoclaving, significant heat energy is lost heating the chamber, pressurized air, glass racks, and the glass. In RF lamination, the heat is generated directly in the vinyl interlayer, causing it to heat and melt quickly, in just 1 to 10 minutes, without significantly heating the glass or the equipment. The main purpose of this project was to provide evidence that low energy, rapid RF lamination quality met the same standards as conventionally autoclaved windows. The development of concepts for laminating curved glass with RF lamination was a major goal. Other primary goals included developing a stronger understanding of the lamination product markets described above, and to refine the potential benefits of commercial implementation. The scope of the project was to complete implementation concept studies in preparation for continuation into advanced development, pilot studies, and commercial implementation. The project consisted of 6 main tasks. The first dealt with lamination with poly-vinyl butyral (PVB) interlayers, which prior work had shown difficulties in achieving good quality laminates, working with Pilkington North

  6. Energy Saving Glass Lamination via Selective Radio Frequency Heating

    Energy Technology Data Exchange (ETDEWEB)

    Allan, Shawn M.

    2012-02-27

    This project focused on advancing radio-frequency (RF) lamination technology closer to commercial implementation, in order to reduce the energy intensity of glass lamination by up to 90%. Lamination comprises a wide range of products including autoglass, architectural safety and innovative design glass, transparent armor (e.g. bullet proof glass), smart glass, mirrors, and encapsulation of photovoltaics. Lamination is also the fastest growing segment of glass manufacturing, with photovoltaics, architectural needs, and an anticipated transition to laminated side windows in vehicles. The state-of-the-art for glass lamination is to use autoclaves, which apply heat and uniform gas pressure to bond the laminates over the course of 1 to 18 hours. Laminates consist of layers of glass or other materials bonded with vinyl or urethane interlayers. In autoclaving, significant heat energy is lost heating the chamber, pressurized air, glass racks, and the glass. In RF lamination, the heat is generated directly in the vinyl interlayer, causing it to heat and melt quickly, in just 1 to 10 minutes, without significantly heating the glass or the equipment. The main purpose of this project was to provide evidence that low energy, rapid RF lamination quality met the same standards as conventionally autoclaved windows. The development of concepts for laminating curved glass with RF lamination was a major goal. Other primary goals included developing a stronger understanding of the lamination product markets described above, and to refine the potential benefits of commercial implementation. The scope of the project was to complete implementation concept studies in preparation for continuation into advanced development, pilot studies, and commercial implementation. The project consisted of 6 main tasks. The first dealt with lamination with poly-vinyl butyral (PVB) interlayers, which prior work had shown difficulties in achieving good quality laminates, working with Pilkington North

  7. Energy Saving Glass Lamination via Selective Radio Frequency Heating

    Energy Technology Data Exchange (ETDEWEB)

    Allan, Shawn M; Baranova, Inessa; Poley, Joseph; Reis, Henrique

    2012-02-27

    This project focused on advancing radio-frequency (RF) lamination technology closer to commercial implementation, in order to reduce the energy intensity of glass lamination by up to 90%. Lamination comprises a wide range of products including autoglass, architectural safety and innovative design glass, transparent armor (e.g. bullet proof glass), smart glass, mirrors, and encapsulation of photovoltaics. Lamination is also the fastest growing segment of glass manufacturing, with photovoltaics, architectural needs, and an anticipated transition to laminated side windows in vehicles. The state-of-the-art for glass lamination is to use autoclaves, which apply heat and uniform gas pressure to bond the laminates over the course of 1 to 18 hours. Laminates consist of layers of glass or other materials bonded with vinyl or urethane interlayers. In autoclaving, significant heat energy is lost heating the chamber, pressurized air, glass racks, and the glass. In RF lamination, the heat is generated directly in the vinyl interlayer, causing it to heat and melt quickly, in just 1 to 10 minutes, without significantly heating the glass or the equipment. The main purpose of this project was to provide evidence that low energy, rapid RF lamination quality met the same standards as conventionally autoclaved windows. The development of concepts for laminating curved glass with RF lamination was a major goal. Other primary goals included developing a stronger understanding of the lamination product markets described above, and to refine the potential benefits of commercial implementation. The scope of the project was to complete implementation concept studies in preparation for continuation into advanced development, pilot studies, and commercial implementation. The project consisted of 6 main tasks. The first dealt with lamination with poly-vinyl butyral (PVB) interlayers, which prior work had shown difficulties in achieving good quality laminates, working with Pilkington North

  8. A thermally robust and thickness independent ferroelectric phase in laminated hafnium zirconium oxide

    Directory of Open Access Journals (Sweden)

    S. Riedel

    2016-09-01

    Full Text Available Ferroelectric properties in hafnium oxide based thin films have recovered the scaling potential for ferroelectric memories due to their ultra-thin-film- and CMOS-compatibility. However, the variety of physical phenomena connected to ferroelectricity allows a wider range of applications for these materials than ferroelectric memory. Especially mixed HfxZr1-xO2 thin films exhibit a broad compositional range of ferroelectric phase stability and provide the possibility to tailor material properties for multiple applications. Here it is shown that the limited thermal stability and thick-film capability of HfxZr1-xO2 can be overcome by a laminated approach using alumina interlayers.

  9. A review on management of chrome-tanned leather shavings: a holistic paradigm to combat the environmental issues.

    Science.gov (United States)

    Pati, Anupama; Chaudhary, Rubina; Subramani, Saravanabhavan

    2014-10-01

    Raw hide/skins come to the tanners as a by-product of meat industry which is converted into value-added leather as product for fashion market. Leather manufacturing is a chemical process of natural biological matrix. It employs a huge quantity of water and inorganic and organic chemicals for processing and thereby discharges solid and liquid wastes into the environment. One of the potential solid wastes generated from leather industry is chrome-tanned leather shavings (CTLSs), and its disposal is increasingly becoming a huge challenge on disposal to tanners due to presence of heavy metal chromium. Hence, finding a sustainable solution to the CTLS disposal problem is a prime challenge for global tanners and researchers. This paper aims to the deeper review of various disposal methods on CTLS such as protein, chromium, and energy recovery processes and its utilization methodologies. Sustainable technologies have been developed to overcome CTLS solid wastes emanating from leather processing operations. Further, this review paper brings a broader classification of developed methodologies for treatment of CTLSs.

  10. Extraction and Optimization of Natural Dye from Hambo Hambo (Cassia singueana Plant Used for Coloration of Tanned Leather Materials

    Directory of Open Access Journals (Sweden)

    Taame Berhanu

    2017-01-01

    Full Text Available This investigation was aimed at introducing natural dye extracted from the bark of Cassia Singueana plant for dyeing chrome tanned sheep skin crust leather. The colorant was extracted by aqueous extraction and its strength evaluated using UV-Visible spectroscopy. The extraction with the highest strength (3.9 at λmax of 400 nm was obtained at temperature of 95°C, concentration of 60 g/l, and time of 60 minutes. The possibility of using aloe vera juice and mango bark extract as natural mordants for leather coloration was investigated. Dyeing was conducted with and without mordant using different combinations of temperature, time, pH, and concentration of mordants. All three mordanting techniques were evaluated. The color strength (K/S, CIE L⁎a⁎b⁎ values, and fastness properties (light, rubbing, and perspiration of dyed leather samples were evaluated using appropriate instruments and according to international standards. Majority of samples exhibited that fastness result was in the range of good-excellent. Significantly better color fastness was obtained in case of leather samples premordanted with aloe vera. This study leads to the conclusion that dye extracted from bark of Cassia singueana can be used as colorant for tanned leather with the selected natural mordants.

  11. Study on hydrolysis of scrap leather stuff%废旧皮革制品水解工艺研究

    Institute of Scientific and Technical Information of China (English)

    王晓蒙; 梁卫士; 闫皓; 王天贵

    2015-01-01

    In order to address potential environmental contamination of scrap leather stuffs and make those be useful resources, orthogonal experiments were conducted by using a hydrothermal reactor to investigate the effect of temperature, time, ratio of liquid to solid, catalysts and their amount, on hydrolysis yield of the leather. Experimen-tal results show that the temperature, time and catalysts have substantial impact on the leather hydrolysis. Under optimal conditions, over 80 percent of the scrap leather can be hydrolyzed by oxalic acid catalysis and up to 76 percent of the scrap leather can be hydrolyzed by sodium hydroxide catalysis.%为了解决废旧皮革制品潜在的污染环境问题并使其资源化,采用正交实验的方法,利用水热反应釜通过加压水解研究了温度、时间、液固比、催化剂种类和用量对皮革水解率的影响。实验结果表明,温度、时间与催化剂都对水解率有较大影响。在最佳条件下,草酸催化废皮革水解率可达82%,NaOH催化废皮革水解率可达76%。

  12. Tropicalized Lambda Lengths, Measured Laminations and Convexity

    DEFF Research Database (Denmark)

    C. Penner, R.

    cell decomposition of a surface is discovered in the limit. Finally, the tropical analogue of the convex hull construction in Minkowski space is formulated as an explicit algorithm that serially simplifies a triangulation with respect to a fixed lamination and has its own independent applications....

  13. Computational modeling of failure in composite laminates

    NARCIS (Netherlands)

    Van der Meer, F.P.

    2010-01-01

    There is no state of the art computational model that is good enough for predictive simulation of the complete failure process in laminates. Already on the single ply level controversy exists. Much work has been done in recent years in the development of continuum models, but these fail to predict t

  14. Geometric approach to Ending Lamination Conjecture

    OpenAIRE

    Soma, Teruhiko

    2008-01-01

    We present a new proof of the bi-Lipschitz model theorem, which occupies the main part of the Ending Lamination Conjecture proved by Minsky and Brock-Canary-Minsky. Our proof is done by using techniques of standard hyperbolic geometry as much as possible.

  15. Tropicalized Lambda Lengths, Measured Laminations and Convexity

    DEFF Research Database (Denmark)

    C. Penner, R.

    This work uncovers the tropical analogue for measured laminations of the convex hull construction of decorated Teichmueller theory, namely, it is a study in coordinates of geometric degeneration to a point of Thurston's boundary for Teichmueller space. This may offer a paradigm for the extension...

  16. Lamb Wave Propagation in Laminated Composite Structures

    OpenAIRE

    Gopalakrishnan, S.

    2013-01-01

    Damage detection using guided Lamb waves is an important tool in Structural health Monitoring. In this paper, we outline a method of obtaining Lamb wave modes in composite structures using two dimensional Spectral Finite Elements. Using this approach, Lamb wave dispersion curves are obtained for laminated composite structures with different fibre orientation. These propagating Lamb wave modes are pictorially captured using tone burst signal.

  17. Constitutive modelling of UD reinforced thermoplastic laminates

    NARCIS (Netherlands)

    Haanappel, S.P.; Thije, ten R.; Akkerman, R.

    2010-01-01

    Intra-ply shear is an important mechanism in thermoforming processes of UD fibre reinforced thermoplastic laminates. Various methods have been developed to characterise this shear mechanism, but measured properties differ for several orders of magnitude. The potential of another technique is shown i

  18. Impermeable Robust Hydrogels via Hybrid Lamination.

    Science.gov (United States)

    Parada, German A; Yuk, Hyunwoo; Liu, Xinyue; Hsieh, Alex J; Zhao, Xuanhe

    2017-07-17

    Hydrogels have been proposed for sensing, drug delivery, and soft robotics applications, yet most of these materials suffer from low mechanical robustness and high permeability to small molecules, limiting their widespread use. This study reports a general strategy and versatile method to fabricate robust, highly stretchable, and impermeable hydrogel laminates via hybrid lamination of an elastomer layer bonded between hydrogel layers. By controlling the layers' composition and thickness, it is possible to tune the stiffness of the impermeable hydrogels without sacrificing the stretchability. These hydrogel laminates exhibit ultralow surface coefficients of friction and, unlike common single-material hydrogels, do not allow diffusion of various molecules across the structure due to the presence of the elastomer layer. This feature is then used to release different model drugs and, in a subsequent experiment, to sense different pH conditions on the two sides of the hydrogel laminate. A potential healthcare application is shown using the presented method to coat medical devices (catheter, tubing, and condom) with hydrogel, to allow for drug release and sensing of environmental conditions for gastrointestinal or urinary tract. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  19. Optimal Design of Laminated Composite Beams

    DEFF Research Database (Denmark)

    Blasques, José Pedro Albergaria Amaral

    . Furthermore, the devised beam model is able account for the different levels of anisotropic elastic couplings which depend on the laminate lay-up. An optimization model based on multi-material topology optimization techniques is described. The design variables represent the volume fractions of the different...

  20. Doped LZO buffer layers for laminated conductors

    Science.gov (United States)

    Paranthaman, Mariappan Parans [Knoxville, TN; Schoop, Urs [Westborough, MA; Goyal, Amit [Knoxville, TN; Thieme, Cornelis Leo Hans [Westborough, MA; Verebelyi, Darren T [Oxford, MA; Rupich, Martin W [Framingham, MA

    2010-03-23

    A laminated conductor includes a metallic substrate having a surface, a biaxially textured buffer layer supported by the surface of the substrate, the biaxially textured buffer layer comprising LZO and a dopant for mitigating metal diffusion through the LZO, and a biaxially textured conductor layer supported by the biaxially textured buffer layer.

  1. Preparation of ZrO2-Al2O3 micro-laminated coatings on stainless steel and their high temperature oxidation resistance

    Institute of Scientific and Technical Information of China (English)

    YAO Ming-ming; HE Ye-dong; GOU Ying-jun; GAO Wei

    2005-01-01

    Micro-laminated ZrO2-Al2O3 coatings were prepared by electrochemical depositing ZrO2 film and Al2O3 film alternatively in ethanol solutions containing aluminum nitrate and zirconium nitrate, with small amounts of yttrium nitrate added respectively into both solutions. The micro-laminated ZrO2-Al2O3 coating is of nanostructure. FE-SEM analyses show that the cross section of the micro-laminated coatings has alternate six-layer films of ZrO2 and Al2O3, with the thickness of each layer in the range of nanometer or submicron. The surface of the micro-laminated coatings is composed of nano-particles. SEM, XRD and mass gain measurement were adopted to study the oxidation resistance of coatings on stainless steel. It has been found that all the coatings are effective in protecting the substrate from oxidation, and micro-laminated coatings exhibit more excellent protectiveness performance. Mechanisms accounting for such effects have been discussed.

  2. Progressive delamination in polymer matrix composite laminates: A new approach

    Science.gov (United States)

    Chamis, C. C.; Murthy, P. L. N.; Minnetyan, L.

    1992-01-01

    A new approach independent of stress intensity factors and fracture toughness parameters has been developed and is described for the computational simulation of progressive delamination in polymer matrix composite laminates. The damage stages are quantified based on physics via composite mechanics while the degradation of the laminate behavior is quantified via the finite element method. The approach accounts for all types of composite behavior, laminate configuration, load conditions, and delamination processes starting from damage initiation, to unstable propagation, and to laminate fracture. Results of laminate fracture in composite beams, panels, plates, and shells are presented to demonstrate the effectiveness and versatility of this new approach.

  3. Fully Solution-Processed Inverted Polymer Solar Cells with Laminated Nanowire Electrodes

    KAUST Repository

    Gaynor, Whitney

    2010-01-26

    We demonstrate organic photovoltaic cells in which every layer is deposited by solution processing on opaque metal substrates, with efficiencies similar to those obtained in conventional device structures on transparent substrates. The device architecture is enabled by solution-processed, laminated silver nanowire films serving as the top transparent anode. The cells are based on the regioregular poly(3- hexylthiophene) and C 61 butyric acid methyl ester bulk heterojunction and reach an efficiency of 2.5% under 100 mW/cm 2 of AM 1.5G illumination. The metal substrates are adequate barriers to moisture and oxygen, in contrast to transparent plastics that have previously been used, giving rise to the possibility of roll-to-roll solutionprocessed solar cells that are packaged by lamination to glass substrates, combining the cost advantage of roll-toroll processing with the barrier properties of glass and metal foil. © 2010 American Chemical Society.

  4. Characterizing formation of interfacial domain wall and exchange coupling strength in laminated exchange coupled composites

    Science.gov (United States)

    Hou, H.-C.; Kirby, B. J.; Gao, K. Z.; Lai, C.-H.

    2013-04-01

    We have studied the N-dependent switching behavior of composite magnets, comprised of a hard CoPtCr-SiO2 (CPCS) film and a laminated soft [Pt/CPCS]N multilayer. First order reversal curve magnetometry provides evidence of interfacial domain wall (iDW) assisted reversal for N ≥ 5. The magnetic depth profiles determined from polarized neutron reflectometry (PNR) explicitly demonstrate that the composite magnets are more rigidly coupled for N = 3 than for N = 7, and suggest that for N = 7 reversal occurs via formation of iDW. By fitting the PNR profile into the energy surface calculations, we can further deduce the vertical coupling strength in the laminated soft layer.

  5. Novel Remanufacturing Process of Recycled Polytetrafluoroethylene(PTFE)/GF Laminate

    Science.gov (United States)

    Xi, Z.; Ghita, O. R.; Johnston, P.; Evans, K. E.

    2011-01-01

    Currently, the PTFE/GF laminate and PTFE PCB manufacturers are under considerable pressure to address the recycling issues due to Waste Electrical and Electronic Equipment (WEEE) Directive, shortage of landfill capacity and cost of disposal. This study is proposing a novel manufacture method for reuse of the mechanical ground PTFE/Glass fibre (GF) laminate and production of the first reconstitute PTFE/GF laminate. The reconstitute PTFE/GF laminate proposed here consists of a layer of recycled sub-sheet, additional layers of PTFE and PTFE coated glass cloth, also covered by copper foils. The reconstitute PTFE/GF laminate showed good dielectric properties. Therefore, there is potential to use the mechanical ground PTFE/GF laminate powder to produce reconstitute PTFE/GF laminate, for use in high frequencies PCB applications.

  6. Post-Lamination Manufacturing Process Automation for Photovoltaic Modules

    Energy Technology Data Exchange (ETDEWEB)

    Nowlan, M. J.; Murach, J. M.; McCormick, T. W.; Lewis, E. R.; Hogan, S. J. (Spire Corporation)

    1999-08-31

    This report describes work performed by Spire Corporation during Phase 1 of this three-phase PVMaT subcontract to develop new automated post-lamination processes for PV module manufacturing. These processes are applicable to a very broad range of module types, including those made with wafer-based and thin-film solar cells. No off-the-shelf automation was available for these processes prior to this program. Spire conducted a survey of PV module manufacturers to identify current industry practices and to determine the requirements for the automated systems being developed in this program. Spire also completed detailed mechanical and electrical designs and developed software for two prototype automation systems: a module buffer storage system, designated the SPI-BUFFER 350, and an integrated module testing system, designated the SPI-MODULE QA 350. Researchers fabricated, tested, and evaluated both systems with module components from several module manufacturers. A new size simulator , th e SPI-SUN SIMULATOR 350i, was designed with a test area that can handle most production modules without consuming excessive floor space. Spire's subcontractor, the Automation and Robotics Research Institute (ARRI) at the University of Texas, developed and demonstrated module edge trimming, edge sealing, and framing processes that are suitable for automation. The automated processes under development throughout this program are being designed to be combined together to create automated production lines. ARRI completed a cost study to determine the level of investment that can be justified by implementing automation for post-lamination assembly and testing processes. The study concluded that a module production line operating two shifts per day and producing 10 MW of modules per year can justify $2.37 million in capital equipment, assuming a 5-year payback period.

  7. Quantitative Percussion Diagnostics For Evaluating Bond Integrity Between Composite Laminates

    Science.gov (United States)

    Poveromo, Scott Leonard

    Conventional nondestructive testing (NDT) techniques used to detect defects in composites are not able to determine intact bond integrity within a composite structure and are costly to use on large and complex shaped surfaces. To overcome current NDT limitations, a new technology was utilized based on quantitative percussion diagnostics (QPD) to better quantify bond quality in fiber reinforced composite materials. Experimental results indicate that this technology is capable of detecting 'kiss' bonds (very low adhesive shear strength), caused by the application of release agents on the bonding surfaces, between flat composite laminates bonded together with epoxy adhesive. Specifically, the local value of the loss coefficient determined from quantitative percussion testing was found to be significantly greater for a release coated panel compared to that for a well bonded sample. Also, the local value of the probe force or force returned to the probe after impact was observed to be lower for the release coated panels. The increase in loss coefficient and decrease in probe force are thought to be due to greater internal friction during the percussion event for poorly bonded specimens. NDT standards were also fabricated by varying the cure parameters of an epoxy film adhesive. Results from QPD for the variable cure NDT standards and lap shear strength measurements taken of mechanical test specimens were compared and analyzed. Finally, experimental results have been compared to a finite element analysis to understand the visco-elastic behavior of the laminates during percussion testing. This comparison shows how a lower quality bond leads to a reduction in the percussion force by biasing strain in the percussion tested side of the panel.

  8. Effect of the Detoxification on the Shrinkage Temperature and pH of Chromium Leather Waste, Another Promising Way for the Tannery Pollution

    Directory of Open Access Journals (Sweden)

    A. Malek

    2008-01-01

    Full Text Available The leather tannery industry produces a significant amount of solid chromium waste. Environmental concerns and escalating landfill costs are becoming increasingly serious problems to the leather industry and alternative disposal methods are needed. This research describes the possibility of decrease of the shrinkage temperature and to increase the pH value of leather waste by detoxification treatment with use of tartrate potassium. Through this investigation, we have established that is more possible to reduce the shrinkage temperature and neutralizing the acidity of this waste without his degradation or digestion and with decreasing of his chromium content about 95%. The use of reaction time of 72 h generates the optimal decreasing of the shrinkage temperature of waste leather about 42°C close to the one of hide at native state (before tanning process which reveal another ecological and simple way for the treatment of the chromium containing leather waste.

  9. Process of Luggage Leather by Giant Salamander Skin%大鲵皮箱包革工艺技术

    Institute of Scientific and Technical Information of China (English)

    徐达宇; 雷明智; 周赟; 彭海蓉

    2012-01-01

    The manufacturing technology of luggage leather with giant salamander skin was introduced. The finished leather is soft and flexible with natural grains and primitive styles. It shows that after manufacture, the giant salamander skin could be made into high value added luggage leather.%利用大鲵皮试制出的箱包革等样品,既保存了大鲵皮的天然粒面和原始风格,又具有一定的柔软度和丰满性。试验表明大鲵皮经过科学加工,能够制造出具有较高经济价值的高档箱包皮革。

  10. Use of Ethylenediaminetetraacetic Acid as a Scavenger for Chromium from “Wet Blue” Leather Waste: Thermodynamic and Kinetics Parameters

    Directory of Open Access Journals (Sweden)

    José E. Resende

    2014-01-01

    Full Text Available One serious consequence of the current consumer society is the transformation of the environment into a waste receptacle arising from human activities. Because of the potential toxic effects of chromium solid waste containing this metal there are grounds for serious concern for the tanning and leather processing industry. The application of tannery waste as organic fertilizer has led to extensive contamination by chromium in agricultural areas and may cause the accumulation of this metal in soils and plants. This work evaluated the extraction of Cr+3 and Cr+6 contained in solid waste from the leather industry through density functional theory (DFT calculations. The Gibbs free energy calculations reveal that the chelator ethylenediaminetetraacetic acid (EDTA forms more stable complexes with metal ions of chromium compared with the structures of the complexes [Cr(NTA(H2O2] and [Cr-collagen], the latter used to simulate the protein bound chrome leather.

  11. New approach of depollution of solid chromium leather waste by the use of organic chelates: economical and environmental impacts.

    Science.gov (United States)

    Malek, Ammar; Hachemi, Messaoud; Didier, Villemin

    2009-10-15

    Herein, we describe an original novel method which allows the decontamination of the chromium-containing leather wastes to simplify the recovery of its considerable protein fractions. Organic salts and acids such as potassium oxalate, potassium tartrate, acetic and citric acids were tested for their efficiency to separate the chromium from the leather waste. Our investigation is based on the research of the total reversibility of the tanning process, in order to decontaminate the waste without its previous degradation or digestion. The effect of several influential parameters on the treatment process was also studied. Therefore, the action of chemical agents used in decontamination process seems very interesting. The optimal yield of chromium extraction about 95% is obtained. The aim of the present study is to define a preliminary processing of solid leather waste with two main impacts: Removing with reusing chromium in the tanning process with simple, ecological and economic treatment process and potential valorization of the organic matrix of waste decontaminated.

  12. Bio-mimetic mineralization potential of collagen hydrolysate obtained from chromium tanned leather waste

    Energy Technology Data Exchange (ETDEWEB)

    Banerjee, Pradipta; Madhu, S. [School of Bio Science and Technology, Vellore Institute of Technology University, Vellore 632014, Tamil Nadu (India); Chandra Babu, N.K. [Tannery Division, CSIR-Central Leather Research Institute, Chennai 600 020, Tamil Nadu (India); Shanthi, C., E-mail: cshanthi@vit.ac.in [School of Bio Science and Technology, Vellore Institute of Technology University, Vellore 632014, Tamil Nadu (India)

    2015-04-01

    Hydroxyapatite (HA) ceramics serve as an alternative to autogenous-free bone grafting by virtue of their excellent biocompatibility. However, chemically synthesized HA lacks the strong load-bearing capacity as required by bone. The bio-mimetic growth of HA crystals on collagen surface provides a feasible solution for synthesizing bone substitutes with the desired properties. This study deals with the utilization of the collagen hydrolysate recovered from leather waste as a substrate for promoting HA crystal growth. Bio-mimetic growth of HA was induced by subjecting the hydrolysate to various mineralization conditions. Parameters that would have a direct effect on crystal growth were varied to determine the optimal conditions necessary. Maximum mineralization was achieved with a combination of 10 mM of CaCl{sub 2}, 5 mM of Na{sub 2}HPO{sub 4}, 100 mM of NaCl and 0.575% glutaraldehyde at a pH of 7.4. The metal–protein interactions leading to formation of HA were identified through Fourier-transform infrared (FTIR) spectroscopy and x-ray diffraction (XRD) studies. The crystal dimensions were determined to be in the nanoscale range by atomic force microscopy (AFM) and scanning electron microscopy (SEM). The size and crystallinity of bio-mimetically grown HA indicate that hydrolysate from leather waste can be used as an ideal alternative substrate for bone growth. - Highlights: • Collagen hydrolysate, extracted from leather industry waste is subjected to biomineralization. • Optimal conditions required for HA growth are identified. • FTIR studies reveal higher Ca−COO{sup −} and low C−N stretch with higher HA formation. • AFM and SEM studies reveal nanometer ranged HA crystals.

  13. Leather Carving Art And Techniques to Explore%皮雕艺术及其技法探索

    Institute of Scientific and Technical Information of China (English)

    刘海燕

    2012-01-01

    作为一种艺术语言,皮雕艺术从草原中走来,追寻着皮革语言的表现性和外延性的无限可能,在不断的雕刻与敲打下塑造着自己的艺术灵魂。雕刻与敲打能赋予皮革以特殊的审美价值,赋予皮革艺术的生命与灵魂。雕刻的深浅、刀法的应运、敲打的方法都会给皮革造成不同的视觉图像,从而带来不同的美感,使人产生不同的情感效应。从皮雕的历史及工艺入手,梳理了皮雕工艺的发展脉络及基本工艺,解析拓展皮革雕刻、敲打的方式与方法,为皮雕艺术的表现提供更多的思考空间和创新的可能性。%As a kind of artistic language,leather sculpture art from prairie comes,searching for leather language expressivity and takes the infinite possibility.In the unceasing carvings and knock down resurrection of his own artistic soul.Carvings and knock can gift leather with special aesthetic value,gift leather art life and soul.Carving knife method of application,depth,knocking method would give leather caused by different visual image,thus to bring different aesthetic feeling,make the person produces different emotion effect.In this thesis,starting from the history and process of the leather carving,Comb the development context and process of the leather carving,collectively analytical and expand leather sculpture,knocking way and method,for the performance of art tapestries to provide more thinking space and innovate.

  14. Fatigue and fracture of fibre metal laminates

    CERN Document Server

    Alderliesten, René

    2017-01-01

    This book contributes to the field of hybrid technology, describing the current state of knowledge concerning the hybrid material concept of laminated metallic and composite sheets for primary aeronautical structural applications. It is the only book to date on fatigue and fracture of fibre metal laminates (FMLs). The first section of the book provides a general background of the FML technology, highlighting the major FML types developed and studied over the past decades in conjunction with an overview of industrial developments based on filed patents. In turn, the second section discusses the mechanical response to quasi-static loading, together with the fracture phenomena during quasi-static and cyclic loading. To consider the durability aspects related to strength justification and certification of primary aircraft structures, the third section discusses thermal aspects related to FMLs and their mechanical response to various environmental and acoustic conditions.

  15. Investigating Delamination Migration in Composite Tape Laminates

    Science.gov (United States)

    Ratcliffe, James G.; DeCarvalho, Nelson V.

    2014-01-01

    A modification to a recently developed test specimen designed to investigate migration of a delamination between neighboring ply interfaces in tape laminates is presented. The specimen is a cross-ply laminated beam consisting of 40 plies with a polytetrafluoroethylene insert spanning part way along its length. The insert is located between a lower 0-degree ply (specimen length direction) and a stack of four 90-degree plies (specimen width direction). The modification involved a stacking sequence that promotes stable delamination growth prior to migration, and included a relocation of the insert from the specimen midplane to the interface between plies 14 and 15. Specimens were clamped at both ends onto a rigid baseplate and loaded on their upper surface via a piano hinge assembly, resulting in a predominantly flexural loading condition. Tests were conducted with the load-application point positioned at various locations along a specimen's span. This position affected the sequence of damage events during a test.

  16. Macro fluid analysis of laminated fabric permeability

    Directory of Open Access Journals (Sweden)

    Qiu Li

    2016-01-01

    Full Text Available A porous jump model is put forward to predict the breathability of laminated fabrics by utilizing fluent software. To simplify the parameter setting process, the methods of determining the parameters of jump porous model by means of fabric layers are studied. Also, effects of single/multi-layer fabrics and thickness on breathability are analyzed, indicating that fabric breathability reduces with the increase of layers. Multi-layer fabric is simplified into a single layer, and the fabric permeability is calculated by proportion. Moreover, the change curve of fabric layer and face permeability, as well as the equation between the fabric layer and the face permeability are obtained. Then, face permeability and pressure-jump coefficient parameters setting of porous jump model could be integrated into single parameter (i. e. fabric layers, which simplifies the fluent operation process and realizes the prediction of laminated fabric permeability.

  17. Vibration analysis of bimodulus laminated cylindrical panels

    Science.gov (United States)

    Khan, K.; Patel, B. P.; Nath, Y.

    2009-03-01

    This paper deals with the flexural vibration behavior of bimodular laminated composite cylindrical panels with various boundary conditions. The formulation is based on first order shear deformation theory and Bert's constitutive model. The governing equations are derived using finite element method and Lagrange's equation of motion. An iterative eigenvalue approach is employed to obtain the positive and negative half cycle free vibration frequencies and corresponding mode shapes. A detailed parametric study is carried out to study the influences of thickness ratio, aspect ratio, lamination scheme, edge conditions and bimodularity ratio on the free vibration characteristics of bimodulus angle- and cross-ply composite laminated cylindrical panels. It is interesting to observe that there is a significant difference between the frequencies of positive and negative half cycles depending on the panel parameters. Through the thickness distribution of modal stresses for positive half cycle is significantly different from that for negative half cycle unlike unimodular case wherein the stresses at a particular location in negative half cycle would be of same magnitude but of opposite sign of those corresponding to positive half cycle. Finally, the effect of bimodularity on the steady state response versus forcing frequency relation is studied for a typical case.

  18. Superconductivity in Ca-doped graphene laminates

    Science.gov (United States)

    Chapman, J.; Su, Y.; Howard, C. A.; Kundys, D.; Grigorenko, A. N.; Guinea, F.; Geim, A. K.; Grigorieva, I. V.; Nair, R. R.

    2016-01-01

    Despite graphene’s long list of exceptional electronic properties and many theoretical predictions regarding the possibility of superconductivity in graphene, its direct and unambiguous experimental observation has not been achieved. We searched for superconductivity in weakly interacting, metal decorated graphene crystals assembled into so-called graphene laminates, consisting of well separated and electronically decoupled graphene crystallites. We report robust superconductivity in all Ca-doped graphene laminates. They become superconducting at temperatures (Tc) between ≈4 and ≈6 K, with Tc’s strongly dependent on the confinement of the Ca layer and the induced charge carrier concentration in graphene. We find that Ca is the only dopant that induces superconductivity in graphene laminates above 1.8 K among several dopants used in our experiments, such as potassium, caesium and lithium. By revealing the tunability of the superconducting response through doping and confinement of the metal layer, our work shows that achieving superconductivity in free-standing, metal decorated monolayer graphene is conditional on an optimum confinement of the metal layer and sufficient doping, thereby bringing its experimental realization within grasp. PMID:26979564

  19. Superconductivity in Ca-doped graphene laminates

    Science.gov (United States)

    Chapman, J.; Su, Y.; Howard, C. A.; Kundys, D.; Grigorenko, A. N.; Guinea, F.; Geim, A. K.; Grigorieva, I. V.; Nair, R. R.

    2016-03-01

    Despite graphene’s long list of exceptional electronic properties and many theoretical predictions regarding the possibility of superconductivity in graphene, its direct and unambiguous experimental observation has not been achieved. We searched for superconductivity in weakly interacting, metal decorated graphene crystals assembled into so-called graphene laminates, consisting of well separated and electronically decoupled graphene crystallites. We report robust superconductivity in all Ca-doped graphene laminates. They become superconducting at temperatures (Tc) between ≈4 and ≈6 K, with Tc’s strongly dependent on the confinement of the Ca layer and the induced charge carrier concentration in graphene. We find that Ca is the only dopant that induces superconductivity in graphene laminates above 1.8 K among several dopants used in our experiments, such as potassium, caesium and lithium. By revealing the tunability of the superconducting response through doping and confinement of the metal layer, our work shows that achieving superconductivity in free-standing, metal decorated monolayer graphene is conditional on an optimum confinement of the metal layer and sufficient doping, thereby bringing its experimental realization within grasp.

  20. Superconductivity in Ca-doped graphene laminates.

    Science.gov (United States)

    Chapman, J; Su, Y; Howard, C A; Kundys, D; Grigorenko, A N; Guinea, F; Geim, A K; Grigorieva, I V; Nair, R R

    2016-03-16

    Despite graphene's long list of exceptional electronic properties and many theoretical predictions regarding the possibility of superconductivity in graphene, its direct and unambiguous experimental observation has not been achieved. We searched for superconductivity in weakly interacting, metal decorated graphene crystals assembled into so-called graphene laminates, consisting of well separated and electronically decoupled graphene crystallites. We report robust superconductivity in all Ca-doped graphene laminates. They become superconducting at temperatures (Tc) between ≈4 and ≈6 K, with Tc's strongly dependent on the confinement of the Ca layer and the induced charge carrier concentration in graphene. We find that Ca is the only dopant that induces superconductivity in graphene laminates above 1.8 K among several dopants used in our experiments, such as potassium, caesium and lithium. By revealing the tunability of the superconducting response through doping and confinement of the metal layer, our work shows that achieving superconductivity in free-standing, metal decorated monolayer graphene is conditional on an optimum confinement of the metal layer and sufficient doping, thereby bringing its experimental realization within grasp.

  1. Production of Thermoalkaliphilic Lipase from Geobacillus thermoleovorans DA2 and Application in Leather Industry

    Directory of Open Access Journals (Sweden)

    Deyaa M. Abol Fotouh

    2016-01-01

    Full Text Available Thermophilic and alkaliphilic lipases are meeting a growing global attention as their increased importance in several industrial fields. Over 23 bacterial strains, novel strain with high lipolytic activity was isolated from Southern Sinai, Egypt, and it was identified as Geobacillus thermoleovorans DA2 using 16S rRNA as well as morphological and biochemical features. The lipase was produced in presence of fatty restaurant wastes as an inducing substrate. The optimized conditions for lipase production were recorded to be temperature 60°C, pH 10, and incubation time for 48 hrs. Enzymatic production increased when the organism was grown in a medium containing galactose as carbon source and ammonium phosphate as nitrogen source at concentrations of 1 and 0.5% (w/v, respectively. Moreover, the optimum conditions for lipase production such as substrate concentration, inoculum size, and agitation rate were found to be 10% (w/v, 4% (v/v, and 120 rpm, respectively. The TA lipase with Triton X-100 had the best degreasing agent by lowering the total lipid content to 2.6% as compared to kerosene (7.5% or the sole crude enzyme (8.9%. It can be concluded that the chemical leather process can be substituted with TA lipase for boosting the quality of leather and reducing the environmental hazards.

  2. Determination of free and ethoxylated alkylphenols in leather with gas chromatography-mass spectrometry.

    Science.gov (United States)

    Ma, He-Wei; Cheng, Ya

    2010-12-10

    An analytical approach was developed to determine nonylphenol (NP), octylphenol (OP), nonylphenol ethoxylates (NPEO(n)) and octylphenol ethoxylates (OPEO(n)) in leather samples involving the conversion of NPEO(n) and OPEO(n) into the corresponding NP and OP. The four targets were extracted from samples using ultrasonic-assisted acetonitrile extraction. NP and OP in the extracts were directly isolated with hexane and quantitatively determined with 4-n-nonylphenol as internal standard by gas chromatography-mass spectrometry (GC-MS). For NPEO(n) and OPEO(n) in the extracts, they were first converted into NP and OP with aluminum triiodide as cleavage agent, and the yielded NP and OP were determined by GC-MS. The contents of NPEO(n) and OPEO(n) were calculated by normalizing to NPEO(9) and OPEO(9), respectively. This method was properly validated and the real sample tests revealed the pollution significance of leather by NPEO(n) and OPEO(n).

  3. Hide unhairing and characterization of commercial enzymes used in leather manufacture

    Directory of Open Access Journals (Sweden)

    A Dettmer

    2011-09-01

    Full Text Available The enzymatic treatment of hides in tannery processes is a promising technology. However, the reaction kinetics of commercial enzymes available to the leather industry are not fully understood and their activities have been mainly determined with model proteins such as casein as substrate, which are not of direct relevance for cattle hides. Therefore, it is important to determine their activities on collagen and keratin, the main proteins of skin, in order to use these enzymes in leather processing. This work describes the study of five proteases, used commercially in tanneries, to assess their ability to act upon collagen and keratin and to determine their unhairing. Results showed that all commercial enzymes tested had more activity on collagen than on keratin. Unhairing was also tested and four out of the five enzymes tested showed some unhairing activity. Optima of the temperature and pH of the enzymes were very similar for all five enzymes, with maximal activities around 55ºC and pH 9 to 12, respectively.

  4. Chemical and biological treatment technologies for leather tannery chemicals and wastewaters: a review.

    Science.gov (United States)

    Lofrano, Giusy; Meriç, Sureyya; Zengin, Gülsüm Emel; Orhon, Derin

    2013-09-01

    Although the leather tanning industry is known to be one of the leading economic sectors in many countries, there has been an increasing environmental concern regarding the release of various recalcitrant pollutants in tannery wastewater. It has been shown that biological processes are presently known as the most environmental friendly but inefficient for removal of recalcitrant organics and micro-pollutants in tannery wastewater. Hence emerging technologies such as advanced oxidation processes and membrane processes have been attempted as integrative to biological treatment for this sense. This paper, as the-state-of-the-art, attempts to revise the over world trends of treatment technologies and advances for pollution prevention from tannery chemicals and wastewater. It can be elucidated that according to less extent advances in wastewater minimization as well as in leather production technology and chemicals substitution, biological and chemical treatment processes have been progressively studied. However, there has not been a full scale application yet of those emerging technologies using advanced oxidation although some of them proved good achievements to remove xenobiotics present in tannery wastewater. It can be noted that advanced oxidation technologies integrated with biological processes will remain in the agenda of the decision makers and water sector to apply the best prevention solution for the future tanneries.

  5. Production of Thermoalkaliphilic Lipase from Geobacillus thermoleovorans DA2 and Application in Leather Industry.

    Science.gov (United States)

    Abol Fotouh, Deyaa M; Bayoumi, Reda A; Hassan, Mohamed A

    2016-01-01

    Thermophilic and alkaliphilic lipases are meeting a growing global attention as their increased importance in several industrial fields. Over 23 bacterial strains, novel strain with high lipolytic activity was isolated from Southern Sinai, Egypt, and it was identified as Geobacillus thermoleovorans DA2 using 16S rRNA as well as morphological and biochemical features. The lipase was produced in presence of fatty restaurant wastes as an inducing substrate. The optimized conditions for lipase production were recorded to be temperature 60°C, pH 10, and incubation time for 48 hrs. Enzymatic production increased when the organism was grown in a medium containing galactose as carbon source and ammonium phosphate as nitrogen source at concentrations of 1 and 0.5% (w/v), respectively. Moreover, the optimum conditions for lipase production such as substrate concentration, inoculum size, and agitation rate were found to be 10% (w/v), 4% (v/v), and 120 rpm, respectively. The TA lipase with Triton X-100 had the best degreasing agent by lowering the total lipid content to 2.6% as compared to kerosene (7.5%) or the sole crude enzyme (8.9%). It can be concluded that the chemical leather process can be substituted with TA lipase for boosting the quality of leather and reducing the environmental hazards.

  6. Antimicrobial fabrication of cotton fabric and leather using green-synthesized nanosilver.

    Science.gov (United States)

    Velmurugan, Palanivel; Cho, Min; Lee, Sang-Myeong; Park, Jung-Hee; Bae, Sunyoung; Oh, Byung-Taek

    2014-06-15

    This study aims to investigate the green synthesis of silver nanoparticles (AgNPs) by Erigeron annuus (L.) pers flower extract as reducing and capping agent, and evaluation of their antibacterial activities for the first time. The obtained product was confirmed by UV-Vis spectrum, high resolution-transmission electron microscopy, energy-dispersive X-ray spectroscopy, Fourier transform infrared spectroscopy, and X-ray diffraction studies. The optimum AgNPs production was achieved at pH 7, metal silver (Ag(+) ion) concentration of 2.0mM, flower extract concentration 4%, and time 335 min. In addition, the antibacterial activity of cotton fabrics and tanned leather loaded with AgNPs, commercial AgNPs, flower extract, Ag(+) ion and blend of flower extract with AgNPs were evaluated against Gram-positive odor causing bacteria Brevibacterium linens and Staphylococcus epidermidis. The results showed maximum zone of inhibition (ZOI) by the cotton fabrics embedded with blend of flower extract and AgNPs against B. linens. The structure and morphology of cotton fabric and leather samples embedded with AgNPs, Ag(+) ion and blend of flower extract with AgNPs were examined under field emission scanning electron microscope.

  7. Bio-mimetic mineralization potential of collagen hydrolysate obtained from chromium tanned leather waste.

    Science.gov (United States)

    Banerjee, Pradipta; Madhu, S; Chandra Babu, N K; Shanthi, C

    2015-04-01

    Hydroxyapatite (HA) ceramics serve as an alternative to autogenous-free bone grafting by virtue of their excellent biocompatibility. However, chemically synthesized HA lacks the strong load-bearing capacity as required by bone. The bio-mimetic growth of HA crystals on collagen surface provides a feasible solution for synthesizing bone substitutes with the desired properties. This study deals with the utilization of the collagen hydrolysate recovered from leather waste as a substrate for promoting HA crystal growth. Bio-mimetic growth of HA was induced by subjecting the hydrolysate to various mineralization conditions. Parameters that would have a direct effect on crystal growth were varied to determine the optimal conditions necessary. Maximum mineralization was achieved with a combination of 10mM of CaCl2, 5mM of Na2HPO4, 100mM of NaCl and 0.575% glutaraldehyde at a pH of 7.4. The metal-protein interactions leading to formation of HA were identified through Fourier-transform infrared (FTIR) spectroscopy and x-ray diffraction (XRD) studies. The crystal dimensions were determined to be in the nanoscale range by atomic force microscopy (AFM) and scanning electron microscopy (SEM). The size and crystallinity of bio-mimetically grown HA indicate that hydrolysate from leather waste can be used as an ideal alternative substrate for bone growth.

  8. Vermicomposting as an advanced biological treatment for industrial waste from the leather industry.

    Science.gov (United States)

    Nunes, Ramom R; Bontempi, Rhaissa M; Mendonça, Giovane; Galetti, Gustavo; Rezende, Maria Olímpia O

    2016-01-01

    The leather industry (tanneries) generates high amounts of toxic wastes, including solid and liquid effluents that are rich in organic matter and mineral content. Vermicomposting was studied as an alternative method of treating the wastes from tanneries. Vermicompost was produced from the following tannery residues: tanned chips of wet-blue leather, sludge from a liquid residue treatment station, and a mixture of both. Five hundred earthworms (Eisenia fetida) were added to each barrel. During the following 135 days the following parameters were evaluated: pH, total organic carbon (TOC), organic matter (OM), cation exchange capacity (CEC), C:N ratio, and chromium content as Cr (III) and Cr (VI). The results for pH, TOC and OM contents showed decreases in their values during the composting process, whereas values for CEC and total nitrogen rose, indicating that the vermicompost reached maturity. For chromium, at 135 days, all values of Cr (VI) were below the detectable level. Therefore, the Cr (VI) content had probably been biologically transformed into Cr (III), confirming the use of this technique as an advanced biological treatment. The study reinforces the idea that vermicomposting could be introduced as an effective technology for the treatment of industrial tannery waste and the production of agricultural inputs.

  9. Gold nanoparticles mediated coloring of fabrics and leather for antibacterial activity.

    Science.gov (United States)

    Velmurugan, Palanivel; Shim, Jaehong; Bang, Keuk-Soo; Oh, Byung-Taek

    2016-07-01

    Metal gold nanoparticles (AuNPs) were synthesized in situ onto leather, silk and cotton fabrics by three different modules, including green, chemical, and a composite of green and chemical synthesis. Green synthesis was employed using Ginkgo biloba Linn leaf powder extract and HAuCl4 with the fabrics, and chemical synthesis was done with KBH4 and HAuCl4. For composite synthesis, G. biloba extract and KBH4 were used to color and embed AuNPs in the fabrics. The colored fabrics were tested for color coordination and fastness properties. To validate the green synthesis of AuNPs, various instrumental techniques were used including UV-Vis spectrophotometry, HR-TEM, FTIR, and XRD. The chemical and composite methods reduce Au(+) onto leather, silk and cotton fabrics upon heating, and alkaline conditions are required for bonding to fibers; these conditions are not used in the green synthesis protocol. FE-SEM image revealed the binding nature of the AuNPs to the fabrics. The AuNPs that were synthesized in situ on the fabrics were tested against a skin pathogen, Brevibacterium linens using LIVE/DEAD BacLight Bacterial Viability testing. This study represents an initial route for coloring and bio-functionalization of various fabrics with green technologies, and, accordingly, should open new avenues for innovation in the textile and garment sectors. Copyright © 2016 Elsevier B.V. All rights reserved.

  10. INFLUENCE OF REACTION CONDITIONS ON THE ALKALINE HYDROLYSIS OF CHAMOIS LEATHER WASTE

    Directory of Open Access Journals (Sweden)

    BĂLĂU MÎNDRU Tudorel

    2017-05-01

    Full Text Available The leather processing industry is known as an important source of environmental pollution, due to the large amount of waste generated. In this respect there are efforts concerning recovering and capitalizing of these wastes in order to subsequently use them in different applications. This work aimed to obtain collagen forms with convenient features starting from Chamois leather waste resulting from the buffing operation, by alkaline hydrolysis at different temperatures (60°C, 90°C, and 120°C and reaction time (4, 6 and 8 hours, in a solution of 30% NH4OH with a pH=11. The effects of the reaction conditions (temperature and reaction duration on the hydrolysis yield and molecular weight of the extracted polypeptides were investigated. The working version no. 8 (temperature = 1200C, and reaction time = 6h was chosen as optimal for obtaining a protein product suitable from the point of view of hydrolysis yield and molecular weight, respectively. For this sample no. 8, tests for checking physical-chemical characteristics were carried out, and also the influence of the hydrolysis upon certain structural changes caused by the reaction conditions was investigated by IR analysis. The reaction conditions led to obtaining polypeptide mixtures with different molecular weights and polydispersity that can be used as auxiliaries to obtain composite materials or as additives for new building materials.

  11. CONTRIBUTIONS TO CLASSIFICATION ZIPPERS USED IN INDUSTRY FOOTWEAR AND LEATHER GOODS

    Directory of Open Access Journals (Sweden)

    MALCOCI Marina

    2016-05-01

    Full Text Available Now customary accessory companies of all leather garments, zipper began to enjoy popularity only after 80 years of its invention. The first is considered the inventor of the zipper Elias Howe. Essentially involves fashion, change, innovation, originality, creativity and is defined as a succession of trends or fads, short. Create fashionable leather confections from home means accepting a contract with the producer and / or consumer, showing a profit motivating all at the right time. Continuous which require the exercise involves creative skills of fashion design, leading to a wide range of products. Current zipper is composed of: slider, teeth, strips shooter stops. Currently there is possibility to customize shooters to customer requirements, and even to form their own zippers. The present work presents the classification criteria zippers. They are after construction fastener after destination zippers, after the role they fulfill zippers, after the presentation at the procurement zippers, after finishing module of the metallic elements, as visibility zipper in the product, by type of teeth, by nature material strip zipper, after the type of materials they are made pullers, after the nature of the materials they are made of sliders and stops after the oxidation of metal components after finishing module teeth after shaped zipper, after slider type, by mode of ornamentation zippers. Knowing appearance zippers, elements of which it is composed, and their classification criteria allow us to correlate the shape of the product and destination.

  12. The molecular architecture of lamins in somatic cells.

    Science.gov (United States)

    Turgay, Yagmur; Eibauer, Matthias; Goldman, Anne E; Shimi, Takeshi; Khayat, Maayan; Ben-Harush, Kfir; Dubrovsky-Gaupp, Anna; Sapra, K Tanuj; Goldman, Robert D; Medalia, Ohad

    2017-03-09

    The nuclear lamina is a fundamental constituent of metazoan nuclei. It is composed mainly of lamins, which are intermediate filament proteins that assemble into a filamentous meshwork, bridging the nuclear envelope and chromatin. Besides providing structural stability to the nucleus, the lamina is involved in many nuclear activities, including chromatin organization, transcription and replication. However, the structural organization of the nuclear lamina is poorly understood. Here we use cryo-electron tomography to obtain a detailed view of the organization of the lamin meshwork within the lamina. Data analysis of individual lamin filaments resolves a globular-decorated fibre appearance and shows that A- and B-type lamins assemble into tetrameric filaments of 3.5 nm thickness. Thus, lamins exhibit a structure that is remarkably different from the other canonical cytoskeletal elements. Our findings define the architecture of the nuclear lamin meshworks at molecular resolution, providing insights into their role in scaffolding the nuclear lamina.

  13. Homogenized Creep Behavior of CFRP Laminates at High Temperature

    Science.gov (United States)

    Fukuta, Y.; Matsuda, T.; Kawai, M.

    In this study, creep behavior of a CFRP laminate subjected to a constant stress is analyzed based on the time-dependent homogenization theory developed by the present authors. The laminate is a unidirectional carbon fiber/epoxy laminate T800H/#3631 manufactured by Toray Industries, Inc. Two kinds of creep analyses are performed. First, 45° off-axis creep deformation of the laminate at high temperature (100°C) is analyzed with three kinds of creep stress levels, respectively. It is shown that the present theory accurately predicts macroscopic creep behavior of the unidirectional CFRP laminate observed in experiments. Then, high temperature creep deformations at a constant creep stress are simulated with seven kinds of off-axis angles, i.e., θ = 0°, 10°, 30°, 45°, 60°, 75°, 90°. It is shown that the laminate has marked in-plane anisotropy with respect to the creep behavior.

  14. Structural Intensity Characterization of Composite Laminates Subjected to Impact Load

    Institute of Scientific and Technical Information of China (English)

    WANG Dong-fang; HE Peng-fei; LIU Zi-shun

    2008-01-01

    Structural intensity (SI) characterization of composite laminates subjected to impact load was dis-cussed. The SI pattern of the laminates which have different fiber orientations and boundary conditions wasanalyzed. The resultant forces and velocities of the laminates were calculated, and the structural intensity wasevaluated. The SI streamlines of carbon fiber reinforced epoxy composite laminates and the steel plates werediscussed. The results show that the SI streamlines of the graphite/epoxy laminates are different from that ofthe steel plates, and the SI streamlines are influenced by the boundaries, the stacking sequence of the compositelaminates. The change of the historical central displacement of the graphite/epoxy laminates is fasten thanthat of the steel plates.

  15. LAMINATION METHOD OF FLOOD WADIS AND PROJECTION OF THE LAMINATED FLOOD HYDROGRAPH

    Directory of Open Access Journals (Sweden)

    M. Ladjel

    2016-01-01

    Full Text Available The catastrophic floods in semi-arid areas are often caused by floods storm that occur at any time during the year, including the hot season. The prevention of these floods could be done by the construction of small dam hills. This requires the control of theoretical concepts hydrological sizing, especially the hydrological structure to evacuate floods. We suggest a method to calculate the optimal regulation flow of the flood and also the development of a direct calculation formula of a laminated maximum flow. The analysis of the hydro graph’s analogy at the input and the output of the dam, allow searching the dependencies between their characteristics. knowing the characteristics of the hydrograph flood of the project and the reserved capacity for the amortization of the flood, we can directly determine the laminated maximum flow and project the hydrograph of the laminated flood.

  16. Research Progress on Waterborne Polyurethane Synthetic Leather Surface Treatment Agent%水性聚氨酯合成革表面处理剂研究进展

    Institute of Scientific and Technical Information of China (English)

    陈新; 杨明华; 沈秋仙

    2015-01-01

    水性聚氨酯具有环保、无毒等特性,将水性聚氨酯应用于合成革涂饰剂可以消除溶剂型合成革处理剂的环境污染问题。本文从合成革表面处理剂的应用现状、合成革用高物性水性聚氨酯研发现状、合成革用水性聚氨酯助剂以及水性聚氨酯合成革表面处理剂品种等几方面进行分析和探讨,指出水性聚氨酯合成革表面处理剂的研发方向。%With environmental and non-toxic characteristics , waterborne polyurethane applied to synthetic leather finishing agent can eliminate the environmental pollution problem of the solvent synthetic leather treatment agent .The present situation of the application of synthetic leather surface treatment agent , the present situation of research and development of waterborne polyurethane with high physical properties for synthetic leather , waterborne polyurethane additives for synthetic leather and waterborne polyurethane leather surface treating agent varieties were analyzed and discussed , and the direction of research and development of waterborne polyurethane synthetic leather surface treatment agent was pointed out.

  17. Fabrication and refinement of 6061(p)/6063 aluminum laminate by accumulative roll-bonding (ARB) process

    Energy Technology Data Exchange (ETDEWEB)

    Lee, S.-H.; Saito, Y.; Sakai, T.; Utsunomiya, H.; Tsuji, N. [Osaka Univ. (Japan). Dept. of Materials Sciences and Engineering

    2000-07-01

    A 6061 aluminum powder compact is fabricated by sheath rolling method using 6063 aluminum tube as a sheath. Accumulative roll-bonding (ARB) process is applied to the powder compact for improvement of its mechanical properties. The ARB process of 8 cycles is performed at ambient temperature under unlubricated conditions without removing the 6063 sheath. The ARB process of 6061 solid aluminum sheet is also performed for comparison to the 6061 powder compact. The tensile strength of the 6061(p)/6063 laminate increases almost linearly with the number of ARB cycles, and reached the maximum of 465MPa at the 6th cycle, which is 2.3 times higher than that of the initial. The elongation drops abruptly at the 1st cycle, and remains at a constant value (about 7%) from the 2nd cycle to the 5th cycle. Both the strength and the elongation decrease with the number of cycles above the 6th cycle. On the other hand, the tensile strength of 6061 sheet increases with the number of cycles gradually. The increase in tensile strength per cycle is greater in the 6061(p)/6063 laminate than that in the ARBed 6061 sheet. This strengthening is probably due to the fine dispersed oxide which was at first oxide film on aluminum. The ultra-fine grains less than 500nm in diameter are developed in the 6061(p)/6063 laminate fabricated by ARB process. (orig.)

  18. Optimum Design of Laminates with Aooroximate Fully Isotrooic Behaviors

    Institute of Scientific and Technical Information of China (English)

    潘星辰

    2001-01-01

    The paper presents an efficient stiffness optimization approach to fully isotropic laminates with approximate isotropic behaviors respect toboth extensional and bending stiffnesses. Based on the Integral global minimization method, the layer orientation angles andthe layer thickness ratios are chosen as design variablesand the lamination parameters are minimized to get theopthnal designs. Example of laminate with approximatefully isotropic behaviors is presented, which has lessthan one-third the number of plies of a fully isotropiclaminate.

  19. Methods for Preparing Nanoparticle-Containing Thermoplastic Composite Laminates

    Science.gov (United States)

    Gruber, Mark B. (Inventor); Jensen, Brian J. (Inventor); Cano, Roberto J. (Inventor)

    2016-01-01

    High quality thermoplastic composites and composite laminates containing nanoparticles and/or nanofibers, and methods of producing such composites and laminates are disclosed. The composites comprise a thermoplastic polymer and a plurality of nanoparticles, and may include a fibrous structural reinforcement. The composite laminates are formed from a plurality of nanoparticle-containing composite layers and may be fused to one another via an automated process.

  20. Energy Saving Glass Lamination via Selective Radio-Frequency Heating

    Energy Technology Data Exchange (ETDEWEB)

    Shulman, Holly S.; Allan, Shawn M.

    2009-11-11

    This Inventions and Innovations program supported the technical and commercial research and development needed to elevate Ceralink's energy saving process for flat glass lamination from bench scale to a self-supporting technology with significant potential for growth. Radio-frequency heating was any un-explored option for laminating glass prior to this program. With significant commercial success through time and energy savings in the wood, paper, and plastics industries, RF heating was found to have significant promise for the energy intensive glass lamination industry. A major technical goal of the program was to demonstrate RF lamination across a wide range of laminate sizes and materials. This was successfully accomplished, dispelling many skeptics' concerns about the abilities of the technology. Ceralink laminated panels up to 2 ft x 3 ft, with four sets processed simultaneously, in a 3 minute cycle. All major categories of interlayer materials were found to work with RF lamination. In addition to laminating glass, other materials including photovoltaic silicon solar cells, light emitting diodes, metallized glass, plastics (acrylic and polycarbonate), and ceramics (alumina) were found compatible with the RF process. This opens up a wide range of commercial opportunities beyond the initially targeted automotive industry. The dramatic energy savings reported for RF lamination at the bench scale were found to be maintained through the scale up of the process. Even at 2 ft x 3 ft panel sizes, energy savings are estimated to be at least 90% compared to autoclaving or vacuum lamination. With targeted promotion through conference presentations, press releases and internet presence, RF lamination has gained significant attention, drawing large audiences at American Ceramic Society meetings. The commercialization success of the project includes the establishment of a revenue-generating business model for providing process development and demonstrations for

  1. 40 CFR 63.5385 - How do I measure the quantity of finish applied to the leather?

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 12 2010-07-01 2010-07-01 true How do I measure the quantity of finish... CATEGORIES National Emission Standards for Hazardous Air Pollutants for Leather Finishing Operations Testing and Initial Compliance Requirements § 63.5385 How do I measure the quantity of finish applied to the...

  2. 40 CFR Figure 1 to Subpart Tttt of... - Example Logs for Recording Leather Finish Use and HAP Content

    Science.gov (United States)

    2010-07-01

    ... Finish Use and HAP Content 1 Figure 1 to Subpart TTTT of Part 63 Protection of Environment ENVIRONMENTAL... Finishing Operations Part 63, Subpt. TTTT, Fig. 1 Figure 1 to Subpart TTTT of Part 63—Example Logs for Recording Leather Finish Use and HAP Content Month:______Year:______ Finish Inventory Log Finish type Finish...

  3. Real-time monitoring of the penetration of amphiphilic acrylate copolymer in leather using a fluorescent copolymer as tracer.

    Science.gov (United States)

    Du, Jin-Xia; Shi, Lu; Peng, Bi-Yu

    2015-12-01

    A fluorescent tracer, poly (acrylic-co-stearyl acrylate-co-3-acryloyl fluorescein) [poly (AA-co-SA-co-Ac-Flu)], used for real-time monitoring the penetration of amphiphilic acrylate copolymer, poly (acrylic-co-stearyl acrylate) [poly (AA-co-SA)], in leather was synthesized by radical polymerization of acrylic, stearyl acrylate and fluorescent monomer, 3-acryloyl fluorescein (Ac-Flu). The structure, molecular weight, introduced fluorescent group content and fluorescent characteristics of the fluorescent tracer and target copolymer, amphiphilic acrylate copolymer, were also characterized. The results show that the tracer presents the similar structural characteristics to the target and enough fluorescence intensity with 1.68 wt % of the fluorescent monomer introduced amount. The vertical section of the leather treated with the target copolymer mixing with 7% of the tracer exhibits evident fluorescence, and the change of fluorescence intensity along with the vertical section with treating time increasing can reflect the penetration depth of the target copolymer. The introduction of the fluorescent group in polymer structure through copolymerization with a limited amount of fluorescent monomer, Ac-Flu, is an effective way to make a tracer to monitor the penetration of the target in leather, which provides a new thought for the penetration research of syntans such as vinyl copolymer materials in leather manufacture.

  4. [Determination of dimethyl fumarate in leather and textiles by gas chromatography-tandem mass spectrometry with solid phase extraction].

    Science.gov (United States)

    Zhao, Yang; Qi, Xiaoxia

    2010-01-01

    An effective method for the determination of dimethyl fumarate (DMF) in leather and textiles by gas chromatography-tandem mass spectrometry (GC-MS/MS) was developed. Samples of leather or textiles were extracted with ethyl acetate and concentrated, DMF was separated on a VF-5 ms column and analyzed by GC-MS/MS after solid phase extraction (SPE) process. The result shows that this method is sensitive, accurate and reliable. The linear relationship was perfect and the interference with background signal was further eliminated after pretreatment, SPE and GC-MS/MS analytical conditions were optimized. The average recoveries of DMF in leather and textiles at three levels ranged from 84% to 93%, the relative standard deviations (n = 6) were lower than 7.2%, the limits of detection in the range from 0.012 to 0.039 mg/kg (S/N = 3) , the correlation coefficient was 0.999 0 over the range 0.05 - 100 mg/L. It has been applied to routine determination of DMF in leather and textiles with satisfactory results.

  5. Analyzing the environmental impact of transportation in reengineered supply chains: a case study from a leather upholstery company

    NARCIS (Netherlands)

    Yazan, Devrim Murat; Yazan, Devrim; Petruzzelli, Antonio Messeni; Albino, Vito

    2011-01-01

    This paper examines the impact of process disaggregation and specialization on the environmental performance of the supply chain of a leather upholstery company. An enterprise input–output model that relates geographical information with production processes and transportation routes is developed.

  6. 制革生态学(续三)%The Ecological Aspects of Leather Manufacture(to be continued)

    Institute of Scientific and Technical Information of China (English)

    Gerhard Wolf; Brigitte Wegner

    2003-01-01

    @@ 3 Post-tanning treatment 3.1 Retanning A variety of different tanning agents are available which can be applied at the retanning stage in order to control the properties of the leather. The most important types of tanning agents are listed below.

  7. [Determination of tris (2-chloroethyl) phosphate in leather by gas chromatography-mass spectrometry coupled with mixed-mode sorbent solid phase extraction].

    Science.gov (United States)

    Zhang, Weiya; Zhu, Yuling; Wang, Chengyun; Li, Lixia; Zhang, Junqing; Xing, Jun

    2014-10-01

    Leather is one of the important exporting products to European Union (EU), and tris(2-chloroethyl) phosphate (TCEP) is a commonly used flame retardant in leather and leather products. Recently, TCEP has been classified as a kind of substance of very high concern (SVHC) by EU for its carcinogenicity and reproductive toxicity. But to date, there is not a recognized method for the determination of TCEP in leather and leather products due to the serious matrix interferences and relatively low recovery of TCEP. In this work, a home-made mixed-mode sorbent (Silica-WCX) with carboxyl and alkyl groups was tested as the sorbent of solid phase extraction (SPE) to extract TECP from leather. The results demonstrated that, making the carboxyl groups protonized under acidic condition, Silica-WCX exhibited better extraction performance towards TCEP over some frequently used commercial sorbents tested. After the optimization of the SPE conditions based on Silica-WCX, a method of gas chromatography/mass spectrometry (GC-MS) was established for the determination of TCEP in leather samples. The linear range for TCEP ranged from 0.10 to 100.0 μg/L and the limit of quantification (LOQ, S/N = 10) was 44.46 ng/kg. The recoveries of TCEP spiked in samples at varied levels were in the range of 91.45%-99.98% with the relative standard deviations (RSDs) of 4.33%-5.97%. The method is simple, sensitive and reliable for the analysis of TCEP in leather and leather products.

  8. Correlation between bulk- and surface chemistry of Cr-tanned leather and the release of Cr(III) and Cr(VI)

    Energy Technology Data Exchange (ETDEWEB)

    Hedberg, Yolanda S., E-mail: yolanda@kth.se [KTH Royal Institute of Technology, School of Chemical Science and Engineering, Department of Chemistry, Division of Surface and Corrosion Science, SE-10044 Stockholm (Sweden); Institute of Environmental Medicine, Karolinska Institutet, Box 210, SE-17177 Stockholm (Sweden); Lidén, Carola, E-mail: carola.liden@ki.se [Institute of Environmental Medicine, Karolinska Institutet, Box 210, SE-17177 Stockholm (Sweden); Odnevall Wallinder, Inger, E-mail: ingero@kth.se [KTH Royal Institute of Technology, School of Chemical Science and Engineering, Department of Chemistry, Division of Surface and Corrosion Science, SE-10044 Stockholm (Sweden)

    2014-09-15

    Graphical abstract: - Highlights: • Released reducing/complexing leather-specific species can reduce released Cr(VI). • No co-released species enable the formation of Cr(VI) in solution. • The major Cr species released from leather in phosphate buffer was Cr(III) (>82%). • No Cr(VI) was released into artificial sweat. - Abstract: About 1–3% of the adult general population in Europe is allergic to chromium (Cr). The assessment of the potential release of Cr(III) and Cr(VI) from leather is hence important from a human health and environmental risk perspective. The Cr(VI) content in leather was recently restricted in the European Union. The aim of this study was to assess possible correlations between the bulk and surface chemistry of leather, released Cr(III) and Cr(VI), and capacities of co-released leather specific species to reduce and complex released Cr. Four differently tanned leathers were characterized by scanning electron microscopy with energy dispersive spectroscopy, X-ray photoelectron spectroscopy, attenuated total reflectance Fourier transform infrared (ATR-FTIR) spectroscopy, and the diphenylcarbazide colorimetric method. Their characteristics were compared with results on Cr(III) and Cr(VI) release into artificial sweat (ASW, pH < 6.5) and phosphate buffer (PB, pH 7.5–8.0), measured by means of spectrophotometry and atomic absorption spectroscopy. Co-released leather-specific species were shown to reduce Cr(VI), both in ASW and in PB. Their reduction capacities correlated with findings of the surface content of Cr and of released Cr. Leather samples without this capacity, and with less aromatic surface groups visible by ATR-FTIR, revealed Cr(VI) both at the surface and in solution (PB)

  9. Detection of hazardous pollutants in chrome-tanned leather using locally developed laser-induced breakdown spectrometer.

    Science.gov (United States)

    Nasr, M M; Gondal, Mohammed Asharf; Seddigi, Z S

    2011-04-01

    Highly toxic contaminants like Cr, As, and Pb were detected in chrome-tanning process of animal skin to produce leather by applying locally developed laser-induced breakdown spectrometer. An Nd-YAG laser with 1,064 nm wavelength was focused on the surface of leather samples (natural and manufactured) to generate a plasma spark and spectrally resolved spectra were used for identification and quantification of contaminants. The leather samples were collected from a tannery located in industrial cities of Riyadh and Jeddah, Saudi Arabia. The study was carried out on fully, half manufactured (wet blue leather), and natural hide (skin). To the best of our knowledge, this is the first attempt where laser-induced breakdown spectroscopy (LIBS) technique has been applied for the analysis of leather before and after tanning process. The maximum concentration of different elements of environmental significance like chromium, lead, arsenic, sulfur, magnesium were 199, 289, 31, 38, and 39 ppm, respectively, in one of the manufactured leather samples. The limit of detection (LOD) of our LIBS system for chromium, lead, arsenic, sulfur, and magnesium were 2, 3, 1.5,7, and 3 ppm, respectively. The safe permissible limit for tanned leather for highly toxic elements like chromium, lead, and arsenic are 1, 0.5, 0.01 ppm, respectively, as prescribed in Environmental Regulation Standards for Saudi Industries set by Royal Commission Jubail, Saudi Arabia. The LIBS technique is superior to other conventional techniques like ICP or atomic absorption that a little or no sample preparation is required, no chemicals are needed, multi-elemental analysis is possible for all kinds of samples (natural and anthropogenic materials), microgram of sample is essential, and LIBS could be applied for remote analysis. It is highly selective and sensitivity higher than ICP, and as no sample and chemicals are required, it is cost effective for multi-sample analysis per unit time as compared with other

  10. An Elastic Model of Blebbing in Nuclear Lamin Meshworks

    Science.gov (United States)

    Funkhouser, Chloe; Sknepnek, Rastko; Shimi, Takeshi; Goldman, Anne; Goldman, Robert; Olvera de La Cruz, Monica

    2013-03-01

    A two-component continuum elastic model is introduced to analyze a nuclear lamin meshwork, a structural element of the lamina of the nuclear envelope. The main component of the lamina is a meshwork of lamin protein filaments providing mechanical support to the nucleus and also playing a role in gene expression. Abnormalities in nuclear shape are associated with a variety of pathologies, including some forms of cancer and Hutchinson-Gilford progeria syndrome, and are often characterized by protruding structures termed nuclear blebs. Nuclear blebs are rich in A-type lamins and may be related to pathological gene expression. We apply the two-dimensional elastic shell model to determine which characteristics of the meshwork could be responsible for blebbing, including heterogeneities in the meshwork thickness and mesh size. We find that if one component of the lamin meshwork, rich in A-type lamins, has a tendency to form a larger mesh size than that rich in B-type lamins, this is sufficient to cause segregation of the lamin components and also to form blebs rich in A-type lamins. The model produces structures with comparable morphologies and mesh size distributions as the lamin meshworks of real, pathological nuclei. Funded by US DoE Award DEFG02-08ER46539 and by the DDR&E and AFOSR under Award FA9550-10-1-0167; simulations performed on NU Quest cluster

  11. NMCP/LINC proteins: putative lamin analogs in plants?

    Science.gov (United States)

    Ciska, Malgorzata; Moreno Diaz de la Espina, Susana

    2013-01-01

    Lamins are the main components of the metazoan lamina, and while the organization of the nuclear lamina of metazoans and plants is similar, there are apparently no genes encoding lamins or most lamin-binding proteins in plants. Thus, the plant lamina is not lamin-based and the proteins that form this structure are still to be characterized. Members of the plant NMCP/LINC/CRWN protein family share the typical tripartite structure of lamins, although the 2 exhibit no sequence similarity. However, given the many similarities between NMCP/LINC/CRWN proteins and lamins (structural organization, position of conserved regions, sub-nuclear distribution, solubility, and pattern of expression), these proteins are good candidates to carry out the functions of lamins in plants. Moreover, functional analysis of NMCP/LINC mutants has revealed their involvement in maintaining nuclear size and shape, another activity fulfilled by lamins. This review summarizes the current understanding of NMCP/LINC proteins and discusses future studies that will be required to demonstrate definitively that these proteins are plant analogs of lamins.

  12. Impact damage resistance of thin stitched carbon/epoxy laminates

    Science.gov (United States)

    Francesconi, L.; Aymerich, F.

    2015-07-01

    The study examines the influence of through-thickness stitching on the damage response of thin cross-ply carbon/epoxy laminates subjected to low-velocity impacts. Instrumented impact tests were carried out on unstitched and polyethylene stitched laminates and the resulting damage was assessed in detail by X-radiography analyses. The results of the observations carried out during the experimental analyses are illustrated and discussed to identify the mechanical role played by through-thickness reinforcement and to highlight the influence of the laminate layup on the impact resistance of stitched laminates.

  13. Response of composite laminates on impact of high velocity projectiles

    Energy Technology Data Exchange (ETDEWEB)

    Siva Kumar, K.; Balakrishna Bhat, T. [Defence Metallurgical Research Lab., Hyderabad (India)

    1998-05-01

    Past work on damage of composites subjected to low velocity and hypervelocity impact has been briefly reviewed and some new results on the glass fibre reinforced plastic composite laminates impacted with high velocity projectiles are presented. The effect of thickness of the laminates and the angle of attack on the energy absorption by the composite laminates and the area of damage caused by impact are described. A correlation is made between the energy absorption and the area of damage. Also described is a new method called infiltration radiography useful for assessing the damage in laminated composites upon ballistic impact. (orig.) 28 refs.

  14. Stochastic analysis of laminated composite plate considering stochastic homogenization problem

    Institute of Scientific and Technical Information of China (English)

    S. SAKATA; K. OKUDA; K. IKEDA

    2015-01-01

    This paper discusses a multiscale stochastic analysis of a laminated composite plate consisting of unidirectional fiber reinforced composite laminae. In particular, influence of a microscopic random variation of the elastic properties of component materials on mechanical properties of the laminated plate is investigated. Laminated composites are widely used in civil engineering, and therefore multiscale stochastic analysis of laminated composites should be performed for reliability evaluation of a composite civil structure. This study deals with the stochastic response of a laminated composite plate against the microscopic random variation in addition to a random variation of fiber orientation in each lamina, and stochastic properties of the mechanical responses of the laminated plate is investigated. Halpin-Tsai formula and the homogenization theory-based finite element analysis are employed for estimation of effective elastic properties of lamina, and the classical laminate theory is employed for analysis of a laminated plate. The Monte-Carlo simulation and the first-order second moment method with sensitivity analysis are employed for the stochastic analysis. From the numerical results, importance of the multiscale stochastic analysis for reliability evaluation of a laminated composite structure and applicability of the sensitivity-based approach are discussed.

  15. Cloning and Characterization of Sf9 Cell Lamin and the Lamin Conformational Changes during Autographa californica multiple nucleopolyhedrovirus Infection

    OpenAIRE

    Wenqiang Wei; Hongju Wang; Xiaoya Li; Na Fang; Shili Yang; Hongyan Liu; Xiaonan Kang; Xiulian Sun; Shaoping Ji

    2016-01-01

    At present, the details of lamina alterations after baculovirus infection remain elusive. In this study, a lamin gene in the Sf9 cell line of Spodoptera frugiperda was cloned. The open reading frame (orf) of the Sf9 lamin was 1860 bp and encoded a protein with a molecular weight of 70 kDa. A transfection assay with a red fluorescence protein (rfp)-lamin fusion protein indicated that Sf9 lamin was localized in the nuclear rim. Transmission electron microscopy observations indicated that Autogr...

  16. The LMNA mutation p.Arg321Ter associated with dilated cardiomyopathy leads to reduced expression and a skewed ratio of lamin A and lamin C proteins

    DEFF Research Database (Denmark)

    Al-Saaidi, Rasha; Rasmussen, Torsten Bloch; Palmfeldt, Johan

    2013-01-01

    degraded. Furthermore, WB analysis showed that the expression of lamin C protein was reduced by the expected approximately 50%. Clearly decreased lamin A and lamin C levels were also observed by immunofluorescence microscopy analysis. However, results from both WB and nano-liquid chromatography....... The LMNA gene generates two major transcripts encoding the nuclear lamina major components lamin A and lamin C by alternative splicing. Both haploinsuffiency and dominant negative effects have been proposed as disease mechanism for premature termination codon (PTC) mutations in LMNA. These mechanisms....../mass spectrometry demonstrated that the levels of lamin A protein were more reduced suggesting an effect on expression of lamin A from the wild type allele. PCR analysis of the ratio of lamin A to lamin C transcripts showed unchanged relative amounts of lamin A transcript suggesting that the effect on the wild type...

  17. Strength and Stiffness of Small Glued-Laminated Beams with Different Qualities of Tension Laminations.

    Science.gov (United States)

    1981-05-01

    difference two of the Li DF-L tension lamina- other test material in this study and between the average of the unad - tions were chosen for that reason...MOE data, adjusted to a 12 per- of tension lamination had a signifi- should be combined to determine the cent moisture content, and the unad - cant

  18. Thermoelastic wave propagation in laminated composites plates

    Directory of Open Access Journals (Sweden)

    Verma K. L.

    2012-12-01

    Full Text Available The dispersion of thermoelastic waves propagation in an arbitrary direction in laminated composites plates is studied in the framework of generalized thermoelasticity in this article. Three dimensional field equations of thermoelasticity with relaxation times are considered. Characteristic equation is obtained on employing the continuity of displacements, temperature, stresses and thermal gradient at the layers’ interfaces. Some important particular cases such as of free waves on reducing plates to single layer and the surface waves when thickness tends to infinity are also discussed. Uncoupled and coupled thermoelasticity are the particular cases of the obtained results. Numerical results are also obtained and represented graphically.

  19. Nonlinear sequential laminates reproducing hollow sphere assemblages

    Science.gov (United States)

    Idiart, Martín I.

    2007-07-01

    A special class of nonlinear porous materials with isotropic 'sequentially laminated' microstructures is found to reproduce exactly the hydrostatic behavior of 'hollow sphere assemblages'. It is then argued that this result supports the conjecture that Gurson's approximate criterion for plastic porous materials, and its viscoplastic extension of Leblond et al. (1994), may actually yield rigorous upper bounds for the hydrostatic flow stress of porous materials containing an isotropic, but otherwise arbitrary, distribution of porosity. To cite this article: M.I. Idiart, C. R. Mecanique 335 (2007).

  20. COST REDUCTION STUDIES OF DECORATIVE LAMINATES

    OpenAIRE

    Dharm Dutt; Jain, R.K.; Anuj Maheshwari; Harjeet Kaur

    2011-01-01

    Barrier paper, which is made of bleached absorbent kraft pulp, is a significant layer of decorative laminates, since it controls the see-through of brown color of saturating kraft paper and its opacifying effect usually is achieved by a heavy loading of TiO2. The TiO2, due to its very small particle size, passes between the cellulosic fibers and drains into the white water. To overcome this problem, papermakers try to use various retention aids for improving overall retention of TiO2, but agg...

  1. Laminated composites modeling in ADAGIO/PRESTO.

    Energy Technology Data Exchange (ETDEWEB)

    Hammerand, Daniel Carl

    2004-05-01

    A linear elastic constitutive equation for modeling fiber-reinforced laminated composites via shell elements is specified. The effects of transverse shear are included using first-order shear deformation theory. The proposed model is written in a rate form for numerical evaluation in the Sandia quasi-statics code ADAGIO and explicit dynamics code PRESTO. The equation for the critical time step needed for explicit dynamics is listed assuming that a flat bilinear Mindlin shell element is used in the finite element representation. Details of the finite element implementation and usage are given. Finally, some of the verification examples that have been included in the ADAGIO regression test suite are presented.

  2. Effects of differently hardened brass foil laminate on the electromechanical property of externally laminated CC tapes

    Energy Technology Data Exchange (ETDEWEB)

    Bautista, Zhierwinjay; Shin, Hyung Seop [Dept. of Mechanical Design Engineering, Andong National University, Andong (Korea, Republic of); Mean, Byoung Jean; Lee, Jae Hun [SuNAM Co Ltd., Anseong (Korea, Republic of)

    2016-12-15

    The mechanical properties of REBCO coated conductor (CC) wires under uniaxial tension are largely determined by the thick component layers in the architecture, namely, the substrate and the stabilizer or even the reinforcement layer. Depending on device applications of the CC tapes, it is necessary to reinforce thin metallic foils externally to one-side or both sides of the CC tapes. Due to the external reinforcement of brass foils, it was found that this could increase the reversible strain limit from the Cu-stabilized CC tapes. In this study, the effects of differently hardened brass foil laminate on the electromechanical property of CC tapes were investigated under uniaxial tension loading. The tensile strain dependence of the critical current (I{sub c}) was measured at 77 K and self-field. Depending on whether the I{sub c} of CC tapes were measured during loading or after unloading, a reversible strain (or stress) limit could be determined, respectively. The both-sides of the Cu-stabilized CC tapes were laminated with brass foils with different hardness, namely 1/4H, 1H and EH. From the obtained results, it showed that the yield strength of the brass laminated CC tapes with EH brass foil laminate was comparable to the one of the Cu-stabilized CC tape due to its large yield strength even though its large volume fraction. It was found that the brass foil with different hardness was mainly sensitive on the stress dependence of I{sub c}, but not on the strain sensitivity due to the residual strain induced in the laminated CC tapes during unloading.

  3. Leather Work.

    Science.gov (United States)

    Greenup, Shirley

    Based on a minicourse taught by the author for students in grades 7 through 10 at the Mountain School (Lookout Mountain, Georgia), this curriculum guide provides for the integration of several curriculum areas into the teaching of leathercraft. Contents include (1) concepts and objectives for the course listed under the headings of language arts,…

  4. Bioproduction of hydrogen by Rhodobacter capsulatus KU002 isolated from leather industry effluents

    Energy Technology Data Exchange (ETDEWEB)

    Merugu, Ramchander; Girisham, S.; Reddy, S.M. [Department of Biochemistry and Microbiology, Kakatiya University, Warangal (India)

    2010-09-15

    A preliminary study on photoproduction of hydrogen by Rhodobacter capsulatus KU002 isolated from leather industry effluents under different cultural conditions with various carbon and nitrogen sources was investigated. Hydrogen production was measured using a Gas chromatograph. Lactate promoted more amounts of hydrogen production under anaerobic light conditions and aerobic light conditions. Cumulative hydrogen production by the organism was recorded at various time intervals. Incubation period of 120 h was optimum for production of hydrogen. pH 7.0 {+-} 0.2 was optimum for production of hydrogen by growing cells, while pH 7.5 {+-} 0.26 for resting cells. L-cystine was a good nitrogen source for production of hydrogen. Growing cells produced more amount of hydrogen than resting cells. Glutamine was a poor nitrogen source for hydrogen production by Rb. capsulatus. Significance of the above results in the presence of existing literature is discussed. (author)

  5. Simultaneous removal of chromium and leather dye from simulated tannery effluent by photoelectrochemistry

    Energy Technology Data Exchange (ETDEWEB)

    Monteiro Paschoal, Fabiana Maria [Departamento de Quimica Analitica, Instituto de Quimica, Universidade Estadual Paulista, Av. Prof. Francisco degni, s/n, C. P. 355 14801-970 Araraquara, SP (Brazil); Anderson, Marc A. [Environmental Chemistry and Technology Program, University of Wisconsin-Madison, 660N. Park Street, Madison, WI 53706 (United States); Zanoni, Maria Valnice B., E-mail: boldrinv@iq.unesp.br [Departamento de Quimica Analitica, Instituto de Quimica, Universidade Estadual Paulista, Av. Prof. Francisco degni, s/n, C. P. 355 14801-970 Araraquara, SP (Brazil)

    2009-07-15

    The feasibility of the photobleaching of a leather acid dye, acid red 151, simultaneously to degradation of anionic surfactant, Tamol, and reduction of Cr(VI) to the less toxic Cr(III) was investigated by photoelectrocatalytic oxidation. The best experimental conditions were found to be pH 2.0 and 0.1 mol L{sup -1} sodium sulfate when the nanoporous Ti/TiO{sub 2} photo anode was biased at +1.0 V and submitted to UV-irradiation. The photoelectrocatalytic oxidation promotes 100% discoloration, reducing around 98-100% of Cr(VI) and achieving an abatement of 95% of the original total organic carbon. The effect of pH, the applied potential, the Cr(VI) concentration and the complexation reaction between Cr(VI) and acid red dye were evaluated as to their effect on the kinetics of the reaction.

  6. Hydrolysis of tanned leather wastes under alkaline, acidic and oxidative conditions

    Directory of Open Access Journals (Sweden)

    Botić Tatjana

    2006-01-01

    Full Text Available Different wastes in large quantities are the outcome or the by-product of processes in the tanning industry. The largest part of solid wastes is collagen based and obtained in the reprocessing steps of tanned and non-tanned products. The quality collagen substance obtained from wastes of the leather industry used as a supporting material in many reprocessing industries. Hydrolysis is the basic step of collagen processing, namely the shortening of its polypeptide chain. The main goal of this investigation was to examine the influence of the following parameters on the extent of collagen hydrolysis: type and quantity of reagent used for hydrolysis temperature of hydrolysis, pH, duration of hydrolysis as well as the dimensions of the "shavings" samples. The change of molar mass during hydrolysis was monitored by UV-spectroscopy. Special attention was paid to the dechroming process of the collagen hydrolysate.

  7. Transesterification reaction of the fat originated from solid waste of the leather industry.

    Science.gov (United States)

    Işler, Asli; Sundu, Serap; Tüter, Melek; Karaosmanoğlu, Filiz

    2010-12-01

    The leather industry is an industry which generates a large amount of solid and liquid wastes. Most of the solid wastes originate from the pre-tanning processes while half of it comes from the fleshing step. Raw fleshing wastes which mainly consist of protein and fat have almost no recovery option and the disposal is costly. This study outlines the possibility of using the fleshing waste as an oil source for transesterification reaction. The effect of oil/alcohol molar ratio, the amount of catalyst and temperature on ester production was individually investigated and optimum reaction conditions were determined. The fuel properties of the ester product were also studied according to the EN 14214 standard. Cold filter plugging point and oxidation stability have to be improved in order to use the ester product as an alternative fuel candidate. Besides, this product can be used as a feedstock in lubricant production or cosmetic industry.

  8. Static and dynamic through thickness lamina properties of thick laminates

    NARCIS (Netherlands)

    Lahuerta, F.; Nijssen, R.P.L.; Van der Meer, F.P.; Sluys, L.J.

    2015-01-01

    Thick laminates are increasingly present in large composites structures such as wind turbine blades. Different factors are suspected to be involved in the decreased static and dynamic performance of thick laminates. These include the effect of self-heating, the scaling effect, and the manufacturing

  9. Numerical assessment of failure mechanisms in fibre metal laminates

    NARCIS (Netherlands)

    Hashagen, F.; De Borst, R.

    1998-01-01

    In this contribution numerical models are discussed for describing failure mechanisms in fibre metal laminates. Fibre metal laminates form a new class of materials which are considered for a possible application to the fuselage of future aircraft generations. The intensive experimental analyses of t

  10. Experimental Study on Penetration and Perforation of Laminated Kevlar

    Institute of Scientific and Technical Information of China (English)

    王元博; 王肖钧; 胡秀章; 孙宇新

    2004-01-01

    The penetration behavior and perforation characteristics of Kevlar/Epoxy laminates with various thickness in quasi-static and ballistic perforation penetrated by steel projectiles with different noses are investigated. Quasi-static tests are conducted on MTS810 testing system. The results indicate that global deformation is the major mechanism of energy absorption and woven laminates exhibit larger energy dissipation than that of angle-plied laminates. Therefore, the woven laminates have better quasi-static penetration resistance. Ballistic tests with velocity of 200-700 m/s are executed by using a powder gun with 7.62 mm barrel. Comparing ballistic experimental results with those under quasi-static condition, both the perforation performance and the failure modes are related closely to the speed of penetrator. Quite different from quasi-static tests, ballistic tests indicate that thick angle-plied laminate targets are even better than woven laminates in resisting ballistic impact. It is observed that the damage zone of the laminate is localized highly with the increasing of the impact velocity and correspondingly, the failure modes are more manifold. The shape of projectile noses affects the impact resistance of laminated Kevlar significantly in the range of velocity around the ballistic limit.

  11. Bayesian inference model for fatigue life of laminated composites

    DEFF Research Database (Denmark)

    Dimitrov, Nikolay Krasimirov; Kiureghian, Armen Der; Berggreen, Christian

    2016-01-01

    A probabilistic model for estimating the fatigue life of laminated composite plates is developed. The model is based on lamina-level input data, making it possible to predict fatigue properties for a wide range of laminate configurations. Model parameters are estimated by Bayesian inference...

  12. Morphing of Bistable Composite Laminates Using Distributed Piezoelectric Actuators

    Directory of Open Access Journals (Sweden)

    Marie-Laure Dano

    2012-01-01

    Full Text Available The use of bistable unsymmetric cross-ply laminates for morphing application has received growing attention in the last few years. So far, most studies use large rectangular piezoelectric Macro Fiber Composite (MFC patches bonded at the center of the laminate to induce snap-through. However, the use of large rectangular MFC patches bonded in the center of the laminates significantly influences the shape of the laminate by greatly reducing the curvature at the midsection of the laminate where the MFC patches are bonded. This paper presents a study where narrow cocured MFC strips distributed over the entire surface are used to induce snap-through of unsymmetric cross-ply laminates. This MFC configuration allows having a more uniform curvature in the laminate. Since the strips are bonded on both sides, reverse snap-through should be obtained. The study was both theoretical and experimental. A finite element nonlinear analysis was used to predict the two stable cylindrical configurations and the snap-through induced by MFC actuation. For the experimental study, a laminate-MFC structure was manufactured and tested. The shapes were measured using a 3D image correlation system as a function of applied voltage. Good correlations for the cylindrical shape and displacement field were observed.

  13. Laminated lumber may be more profitable than sawn lumber

    Science.gov (United States)

    P. Koch

    1976-01-01

    By laminating 1/4-in. rotary-cut veneer into structural lumber, manufacturers can expand lumber output by at least 30% without increasing volume logged. The idea merits intensive study. Manufacturing plus raw material costs should total about $142/Mbf; sales price for desirable widths and lengths of the strong laminated product should approach or exceed $200/Mbf.

  14. The supramolecular organization of the C. elegans nuclear lamin filament.

    Science.gov (United States)

    Ben-Harush, Kfir; Wiesel, Naama; Frenkiel-Krispin, Daphna; Moeller, Dorothee; Soreq, Eyal; Aebi, Ueli; Herrmann, Harald; Gruenbaum, Yosef; Medalia, Ohad

    2009-03-13

    Nuclear lamins are involved in most nuclear activities and are essential for retaining the mechano-elastic properties of the nucleus. They are nuclear intermediate filament (IF) proteins forming a distinct meshwork-like layer adhering to the inner nuclear membrane, called the nuclear lamina. Here, we present for the first time, the three-dimensional supramolecular organization of lamin 10 nm filaments and paracrystalline fibres. We show that Caenorhabditis elegans nuclear lamin forms 10 nm IF-like filaments, which are distinct from their cytoplasmic counterparts. The IF-like lamin filaments are composed of three and four tetrameric protofilaments, each of which contains two partially staggered anti-parallel head-to-tail polymers. The beaded appearance of the lamin filaments stems from paired globular tail domains, which are spaced regularly, alternating between 21 nm and 27 nm. A mutation in an evolutionarily conserved residue that causes Hutchison-Gilford progeria syndrome in humans alters the supramolecular structure of the lamin filaments. On the basis of our structural analysis, we propose an assembly pathway that yields the observed 10 nm IF-like lamin filaments and paracrystalline fibres. These results serve also as a platform for understanding the effect of laminopathic mutations on lamin supramolecular organization.

  15. Chapter 2: Manufacturing Cross-laminated timber manufacturing

    Science.gov (United States)

    Borjen Yeh; Dave Kretschmann; Brad (Jianhe) Wang

    2013-01-01

    Cross-laminated timber ( CLT) is defined as a prefabricated solid engineered wood product made of at least three orthogonally bonded layers of solid-sawn lumber or structural composite lumber (SCL) that are laminated by gluing oflongitudinal and transverse layers with structural adhesives to form a solid rectangular-shaped, straight, and plane timber intended for roof...

  16. Exact and Finite-Element Analysis of Laminated Shells.

    Science.gov (United States)

    1983-11-01

    developed by Stavsky [ 91 for laminated anisotropic plates to Donnell’s shallow shell theory (see Donnell C10]). Cheng and Ho [8] presented an analysis of...the shell reference surface. Dong, Pister, and Taylor [10] presented an extension of Donnell’s shallow shell theory [11] to thin laminated shells

  17. The strength of composite repair patches - A laminate analysis approach

    Science.gov (United States)

    Robson, J. E.; Matthews, F. L.; Kinloch, A. J.

    1992-07-01

    Some guidelines for the selection of extra plies for vacuum-pressure-cured composite repair patches are deduced by comparing the strength and stiffness of vacuum-cured materials with their autoclaved counterparts, using classical laminate analysis. The guidelines are based on the minimum number of extra plies needed to equal or exceed the stiffness or strength of an autoclave-cured laminate, when using vacuum curing methods. Strength and stiffness data are presented in tabular form for quasi-isotropic laminates, cross-ply laminates, and angle-ply laminates. The analysis does not take into account repair geometry, and is concerned with intrinsic laminate properties. It is found that adding extra plies to a laminate will never be detrimental to its strength and stiffness, but in order to be beneficial, the extra plies need to be aligned with a load direction. If a laminate is likely to be under a combination of loads it is important for a balance of strengths to be maintained.

  18. Improvement in surface hydrophilicity and resistance to deformation of natural leather through O2/H2O low-temperature plasma treatment

    Science.gov (United States)

    You, Xuewei; Gou, Li; Tong, Xingye

    2016-01-01

    The natural leather was modified through O2/H2O low-temperature plasma treatment. Surface morphology was characterized by scanning electron microscopy (SEM) and the results showed that the pores on the leather surface became deeper and larger with enhanced permeability of water and vapor. XPS and FTIR-ATR was performed to determine the chemical composition of natural leather surface. Oxygen-containing groups were successfully grafted onto the surface of natural leather and oxygen content increased with longer treatment time. After O2/H2O plasma treatment, initial water contact angle was about 21° and water contact angles were not beyond 55° after being stored for 3 days. Furthermore, the tensile test indicated that the resistance to deformation had a prominent transform without sacrificing the tensile strength.

  19. Research on the Dividing Line Design of Leather Clothing%皮革服装中分割线设计探讨

    Institute of Scientific and Technical Information of China (English)

    罗琴; 叶耀苏

    2014-01-01

    This article mainly discussed dividing line design features of leather clothing and seg-mentation techniques,influencing factors,the difference between the dividing line design of leather clothing and woven garments,and then summarized the unique feature of dividing line design of leather clothing,finally optimized design theory of leather clothing dividing line.%文章对皮革服装分割线设计特点,分割技巧、影响因素、皮革服装分割线设计与梭织服装分割线设计的区别进行探讨,从而总结皮革服装分割线设计的特有规律,完善对皮革服装分割线设计的理论研究。

  20. NONLINEAR THEORY OF DYNAMIC STABILITY FOR LAMINATED COMPOSITE CYLINDRICAL SHELLS

    Institute of Scientific and Technical Information of China (English)

    周承倜; 王列东

    2001-01-01

    Hamilton Principle was uaed to derive the general governing equations of nonlinear dynamic stability for laminated cylindrical shells in which, factors of nonlinear large deflection, transverse shear and longitudinal inertia force were concluded. Equations were solved by variational method. Analysis reveals that under the action of dynamic load,laminated cylindrical shells will fall into a state of parametric resonance and enter into the dynamic unstable region that causes dynamic instability of shells. Laminated shells of three typical composites were computed: i.e. T300/5 208 graphite epoxy E-glass epoxy, and ARALL shells. Results show that all factors will induce important influence for dynamic stability of laminated shells. So, in research of dynamic stability for laminated shells, to consider these factors is important.

  1. Measurable versions of the LS category on laminations

    CERN Document Server

    Meniño, Carlos

    2011-01-01

    We give two new versions of the LS category for the set-up of measurable laminations defined by Berm\\'udez. Both of these versions must be considered as "tangential categories". The first one, simply called (LS) category, is the direct analogue for measurable laminations of the tangential category of (topological) laminations introduced by Colman Vale and Mac\\'ias Virg\\'os. For the measurable lamination that underlies any lamination, our measurable tangential category is a lower bound of the tangential category. The second version, called the measured category, depends on the choice of a transverse invariant measure. We show that both of these "tangential categories" satisfy appropriate versions of some well known properties of the classical category: the homotopy invariance, a dimensional upper bound, a cohomological lower bound (cup length), and an upper bound given by the critical points of a smooth function.

  2. Residual stresses and their effects in composite laminates

    Science.gov (United States)

    Hahn, H. T.; Hwang, D. G.

    1983-01-01

    Residual stresses in composite laminates are caused by the anisotropy in expansional properties of constituent unidirectional plies. The effect of these residual stresses on dimensional stability is studied through the warping of unsymmetric (0 sub 4/90 sub 4)sub T graphite/epoxy laminates while their effect on ply failure is analyzed for (0/90)sub 2s Kevlar 49/epoxy laminate. The classical laminated plate theory is used to predict the warping of small and large panels. The change of warping does not indicate a noticeable stress relaxation at 75 C while it is very sensitive to moisture content and hence to environment. A prolonged gellation at the initial cure temperature reduces residual stresses while postcure does not. The matrix/interface cracking in dry (0/90)sub 2s Kevlar 49/epoxy laminate is shown to be the result of the residual stress exceeding the transverse strength.

  3. Fatigue Performance of Composite Laminates After Low-velocity Impact

    Directory of Open Access Journals (Sweden)

    LIANG Xiao-lin

    2016-12-01

    Full Text Available Compression-compression fatigue tests were carried out on T300/5405 composite laminates after low-velocity impact, compression performance of the laminates with different impact damages was studied together with its fatigue life and damage propagation under different stress levels, then the effects of impact energy, stress level and damage propagation on fatigue life of laminates were discussed. The results indicate that impact damage can greatly reduce the residual strength of laminates; under low fatigue load levels, the higher impact energy is, the shorter the fatigue life of laminates with impact damage will be; damage propagation undergoes two stages during the fatigue test, namely the steady propagation and the rapid propagation, accounting for 80% and 20% of the overall fatigue life, respectively; damage propagation rate decreases with the reduction of stress level.

  4. Flexural and Impact Resistance of FRC/Bamboo Laminate

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    The flexural and impact resistance of a newly developed FRC/bamboo laminate have been investigated. The laminate considered in this study was combined with reformed bamboo plate and extruded fiber reinforced cementitious (FRC)sheet. Innovated from the raw bamboo, reformed bamboo showed high tensile strength and high strength to weight ratio. It can not only remarkably strengthen the FRC sheet but also reduce the total weight of the laminate. Flexural and impact load, broken energy, deflection and duration were measured. Test results showed that the flexural strength value for the laminate can be improved to greater than 90 MPa, while the impact resistance is increased more than 10 times for the laminate when compared with the FRC sheet only.

  5. Ballistic Impact on Glass/Epoxy Composite Laminates

    Directory of Open Access Journals (Sweden)

    R. Velmurugan

    2014-07-01

    Full Text Available Glass/epoxy composite laminates are subjected to impact loading and the energy absorbing capacity of the laminates is studied. In the present study, laminates with four different orientations and thickness values are considered. Analytical study is carried out based on energy method and results are compared with FE results obtained from Abaqus/Explicit software. Results obtained from the analytical methods are showing good agreement with the FE results. It is found that cross-ply laminates are most efficient in ballistic resistance when compared with the laminates of other orientations. It is also noticed that the energy absorbing capacity is decreasing with increase in velocity of the projectile for a given lay-up and thickness value.Defence Science Journal, Vol. 64, No. 4, July 2014, pp. 393-399, DOI:http://dx.doi.org/10.14429/dsj.64.3882 

  6. The mechanical behavior of GLARE laminates for aircraft structures

    Science.gov (United States)

    Wu, Guocai; Yang, J.-M.

    2005-01-01

    GLARE (glass-reinforced aluminum laminate) is a new class of fiber metal laminates for advanced aerospace structural applications. It consists of thin aluminum sheets bonded together with unidirectional or biaxially reinforced adhesive prepreg of high-strength glass fibers. GLARE laminates offer a unique combination of properties such as outstanding fatigue resistance, high specific static properties, excellent impact resistance, good residual and blunt notch strength, flame resistance and corrosion properties, and ease of manufacture and repair. GLARE laminates can be tailored to suit a wide variety of applications by varying the fiber/resin system, the alloy type and thickness, stacking sequence, fiber orientation, surface pretreatment technique, etc. This article presents a comprehensive overview of the mechanical properties of various GLARE laminates under different loading conditions.

  7. Altering strength and plastic deformation behavior via alloying and laminated structure in nanocrystalline metals

    Energy Technology Data Exchange (ETDEWEB)

    Gu, C. [State Key Laboratory for Mechanical Behavior of Material, Xi' an Jiaotong University, Xi' an 710049 (China); Wang, F., E-mail: wangfei@mail.xjtu.edu.cn [State Key Laboratory for Strength and Vibration of Mechanical Structures, Xi' an Jiaotong University, Xi' an 710049 (China); Huang, P., E-mail: huangping@mail.xjtu.edu.cn [State Key Laboratory for Mechanical Behavior of Material, Xi' an Jiaotong University, Xi' an 710049 (China); Lu, T.J. [State Key Laboratory for Strength and Vibration of Mechanical Structures, Xi' an Jiaotong University, Xi' an 710049 (China); MOE Key Laboratory for Multifunctional Materials and Structures, Xi' an Jiaotong University, Xi' an 710049 (China); Xu, K.W. [State Key Laboratory for Mechanical Behavior of Material, Xi' an Jiaotong University, Xi' an 710049 (China)

    2015-07-29

    Nanoindentation and electron microscope techniques have been performed on sputtering deposited monolayered nanocrystalline CuNb and multilayered CuNb/Cu thin films. Microstructural features, hardness and surface morphologies of residual indentation have been evaluated to identify the effects of alloying and laminated structure on strength and plastic deformation behavior of nanocrystalline metals. By altering the content of Nb in CuNb alloy and adding crystalline Cu layers into CuNb alloy, the volume fraction of amorphous phase in CuNb alloy and interface structures changed dramatically, resulting in various trends that are related to hardness, indentation induced pileup and shear banding deformation. Based on the experimental results, the dominant deformation mechanisms of the CuNb and CuNb/Cu thin films with various Nb contents were proposed and extended to be discussed.

  8. High Pressure Laminates with Antimicrobial Properties

    Directory of Open Access Journals (Sweden)

    Sandra Magina

    2016-02-01

    Full Text Available High-pressure laminates (HPLs are durable, resistant to environmental effects and good cost-benefit decorative surface composite materials with special properties tailored to meet market demand. In the present work, polyhexamethylene biguanide (PHMB was incorporated for the first time into melamine-formaldehyde resin (MF matrix on the outer layer of HPLs to provide them antimicrobial properties. Chemical binding of PHMB to resin matrix was detected on the surface of produced HPLs by attenuated total reflection Fourier transform infrared spectroscopy (ATR-FTIR. Antimicrobial evaluation tests were carried out on the ensuing HPLs doped with PHMB against gram-positive Listeria innocua and gram-negative Escherichia coli bacteria. The results revealed that laminates prepared with 1.0 wt % PHMB in MF resin were bacteriostatic (i.e., inhibited the growth of microorganisms, whereas those prepared with 2.4 wt % PHMB in MF resin exhibited bactericidal activity (i.e., inactivated the inoculated microorganisms. The results herein reported disclose a promising strategy for the production of HPLs with antimicrobial activity without affecting basic intrinsic quality parameters of composite material.

  9. Geometrically nonlinear behavior of piezoelectric laminated plates

    Science.gov (United States)

    Rabinovitch, Oded

    2005-08-01

    The geometrically nonlinear behavior of piezo-laminated plates actuated with isotropic or anisotropic piezoelectric layers is analytically investigated. The analytical model is derived using the variational principle of virtual work along with the lamination and plate theories, the von Karman large displacement and moderate rotation kinematic relations, and the anisotropic piezoelectric constitutive laws. A solution strategy that combines the approach of the method of lines, the advantages of the finite element concept, and the variational formulation is developed. This approach yields a set of nonlinear ordinary differential equations with nonlinear boundary conditions, which are solved using the multiple-shooting method. Convergence and verification of the model are examined through comparison with linear and nonlinear results of other approximation methods. The nonlinear response of two active plate structures is investigated numerically. The first plate is actuated in bending using monolithic piezoceramic layers and the second one is actuated in twist using macro-fiber composites. The results quantitatively reveal the complicated in-plane stress state associated with the piezoelectric actuation and the geometrically nonlinear coupling of the in-plane and out-of-plane responses of the plate. The influence of the nonlinear effects ranges from significant stiffening in certain combinations of electrical loads and boundary conditions to amplifications of the induced deflections in others. The paper closes with a summary and conclusions.

  10. Delamination tolerance studies in laminated composite panels

    Indian Academy of Sciences (India)

    K L Singh; B Dattaguru; T S Ramamurthy; P D Mangalgiri

    2000-08-01

    Determination of levels of tolerance in delaminated composite panels is an important issue in composite structures technology. The primary intention is to analyse delaminated composite panels and estimate Strain Energy Release Rate (SERR) parameters at the delamination front to feed into acceptability criteria. Large deformation analysis is necessary to cater for excessive rotational deformations in the delaminated sublaminate. Modified Virtual Crack Closure Integral (MVCCI) is used to estimate all the three SERR components at the delamination front from the finite element output containing displacements, strains and stresses. The applied loading conditions are particularly critical and compressive loading on the panel could lead to buckling of the delaminated sublaminate and consequent growth of delamination. Numerical results are presented for circular delamination of varioussizes and delamination at various interfaces (varying depth-wise location) between the base- and the sub-laminates. Numerical data are also presented on the effect of bi-axial loading and in particular on compressive loading in both directions. The results can be used to estimate delamination tolerance at various depths (or at various interfaces) in the laminate.

  11. Correlation between bulk- and surface chemistry of Cr-tanned leather and the release of Cr(III) and Cr(VI).

    Science.gov (United States)

    Hedberg, Yolanda S; Lidén, Carola; Odnevall Wallinder, Inger

    2014-09-15

    About 1-3% of the adult general population in Europe is allergic to chromium (Cr). The assessment of the potential release of Cr(III) and Cr(VI) from leather is hence important from a human health and environmental risk perspective. The Cr(VI) content in leather was recently restricted in the European Union. The aim of this study was to assess possible correlations between the bulk and surface chemistry of leather, released Cr(III) and Cr(VI), and capacities of co-released leather specific species to reduce and complex released Cr. Four differently tanned leathers were characterized by scanning electron microscopy with energy dispersive spectroscopy, X-ray photoelectron spectroscopy, attenuated total reflectance Fourier transform infrared (ATR-FTIR) spectroscopy, and the diphenylcarbazide colorimetric method. Their characteristics were compared with results on Cr(III) and Cr(VI) release into artificial sweat (ASW, pHleather-specific species were shown to reduce Cr(VI), both in ASW and in PB. Their reduction capacities correlated with findings of the surface content of Cr and of released Cr. Leather samples without this capacity, and with less aromatic surface groups visible by ATR-FTIR, revealed Cr(VI) both at the surface and in solution (PB).

  12. Engineering interfacial properties of organic semiconductors through soft-contact lamination and surface functionalization

    Science.gov (United States)

    Shu, Andrew Leo

    Organic electronics is a topic of interest due to its potential for low temperature and solution processing for large area and flexible applications. Examples of organic electronic devices are already available on the market; however these are, in general, still rather expensive. In order to fully realize inexpensive and efficient organic electronics, the properties of organic films need to be understood and strategies developed to take advantage of these properties to improve device performance. This work focuses on two strategies that can be used to control charge transport at interfaces with active organic semiconducting thin films. These strategies are studied and verified with a range of photoemission spectroscopy, surface probe microscopy, and electrical measurements. Vacuum evaporated molecular organic devices have long used layer stacking of different materials as a method of dividing roles in a device and modifying energy level alignment to improve device performance and efficiency. Applying this type of architecture for solution-processed devices, on the other hand, is nontrivial, as an issue of removal of or mixing with underlying layers arises. We present and examine here soft-contact lamination as a viable technique for depositing solution-processed multilayer structures. The energetics at homojunctions of a couple of air-stable polymers is investigated. Charge transport is then compared between a two-layer film and a single-layer film of equivalent thicknesses. The interface formed by soft-contact lamination is found to be transparent with respect to electronic charge carriers. We also propose a technique for modifying electronic level alignment at active organic-organic heterojunctions using dipolar self-assembled monolayers (SAM). An ultra-thin metal oxide is first deposited via a gentle low temperature chemical vapor deposition as an adhesion layer for the SAM. The deposition is shown to be successful for a variety of organic films. A series of

  13. Electromagnetic characteristics of carbon nanotube film materials

    Directory of Open Access Journals (Sweden)

    Zhang Wei

    2015-08-01

    Full Text Available Carbon nanotube (CNT possesses remarkable electrical conductivity, which shows great potential for the application as electromagnetic shielding material. This paper aims to characterize the electromagnetic parameters of a high CNT loading film by using waveguide method. The effects of layer number of CNT laminate, CNT alignment and resin impregnation on the electromagnetic characteristics were analyzed. It is shown that CNT film exhibits anisotropic electromagnetic characteristic. Pristine CNT film shows higher real part of complex permittivity, conductivity and shielding effectiveness when the polarized direction of incident wave is perpendicular to the winding direction of CNT film. For the CNT film laminates, complex permittivity increases with increasing layer number, and correspondingly, shielding effectiveness decreases. The five-layer CNT film shows extraordinary shielding performance with shielding effectiveness ranging from 67 dB to 78 dB in X-band. Stretching process induces the alignment of CNTs. When aligned direction of CNTs is parallel to the electric field, CNT film shows negative permittivity and higher conductivity. Moreover, resin impregnation into CNT film leads to the decrease of conductivity and shielding effectiveness. This research will contribute to the structural design for the application of CNT film as electromagnetic shielding materials.

  14. Export Performance of SMEs in the Nigerian Leather Industry and the Mediating Effect of Perception of Export Difficulty

    Directory of Open Access Journals (Sweden)

    Abubakar Sambo Junaidu

    2012-10-01

    Full Text Available Even though a large amount of work has been carried out to research the factors that affect export performance, there is a seeming neglect of research about specific industries operating in developing countries like Nigeria. This paper presents a research into the factors that affect export performance of SMEs in the Nigerian leather industry. Based on the resource-based view, we posit that intangible resources (Knowledge, Image and marketing resources are all positively related to firm export performance. The study also hypothesizes that perception of export difficulty mediates the relationship between intangible resources barriers and export performance. Standard survey questionnaires were used to collect data from SMEs operating in the leather industry in North-Western Nigeria and multiple regression analysis was used for hypotheses testing. Findings from the data analysis provided support for the hypothesized relationships thus suggesting support for the theoretical model of the study.

  15. Transformation of collagen into gelatine in historical leather and parchment caused by natural deterioration and moist treatment

    DEFF Research Database (Denmark)

    Larsen, René

    2012-01-01

    The main constituent in leather and parchment is the fibrous protein collagen type I. Experiments and studies have shown that the chemical mechanisms causing deterioration of the collagen structure in these materials are acid hydrolysis and oxidation and that these can be correlated...... to the hydrothermal stability of the material. For parchment and leather tanned with condensed types of vegetable tannins stored under acid conditions, the chemical deterioration may lead to a transformation of the collagen into a gelatine-like substance that may dissolve in water even at ambient temperature....... This process follows certain typical denaturising patterns that can be observed as characteristic morphological transformations of the collagen fibre structure at the microscopic level. Moreover, this transformation process has shown to be the same as that taking place during measurement of the hydrothermal...

  16. Low cost and high performance screen laminate regenerator matrix

    Energy Technology Data Exchange (ETDEWEB)

    Bin-Nun, Uri; Manitakos, Dan [FLIR Systems, North Billerica, MA (United States)

    2004-08-01

    A laminate screen matrix regenerator with 47 elements has been designed, analyzed, fabricated and tested. The laminate was fabricated from stainless steel screen sheets that were stacked on top of each other at certain angular orientation and then bonded at high temperature and pressure environment utilizing a sintering process. This laminate is a porous structure media with highly repeatable properties that can be controlled by varying mesh size, weave type, wire size and laminate sheet to sheet orientation. The flow direction in relation to the weave plan can be varied by cutting a cylindrical or rectangular laminate element along or across the weave. The regenerator flow resistance, thermal conductance losses, dead volume, surface area and heat transfer coefficient are analyzed. Regenerator cost and performance comparison data between the conventional widely used method of stacked screens and the new stacked laminate matrix regenerator is discussed. Also, a square stainless steel screen laminate was manufactured in a way which permits gas to flow along the screen wire instead of across it. (Author)

  17. Role of nuclear Lamin A/C in cardiomyocyte functions.

    Science.gov (United States)

    Carmosino, Monica; Torretta, Silvia; Procino, Giuseppe; Gerbino, Andrea; Forleo, Cinzia; Favale, Stefano; Svelto, Maria

    2014-10-01

    Lamin A/C is a structural protein of the nuclear envelope (NE) and cardiac involvement in Lamin A/C mutations was one of the first phenotypes to be reported in humans, suggesting a crucial role of this protein in the cardiomyocytes function. Mutations in LMNA gene cause a class of pathologies generically named 'Lamanopathies' mainly involving heart and skeletal muscles. Moreover, the well-known disease called Hutchinson-Gilford Progeria Syndrome due to extensive mutations in LMNA gene, in addition to the systemic phenotype of premature aging, is characterised by the death of patients at around 13 typically for a heart attack or stroke, suggesting again the heart as the main site sensitive to Lamin A/C disfunction. Indeed, the identification of the roles of the Lamin A/C in cardiomyocytes function is a key area of exploration. One of the primary biological roles recently conferred to Lamin A/C is to affect contractile cells lineage determination and senescence. Then, in differentiated adult cardiomyocytes both the 'structural' and 'gene expression hypothesis' could explain the role of Lamin A in the function of cardiomyocytes. In fact, recent advances in the field propose that the structural weakness/stiffness of the NE, regulated by Lamin A/C amount in NE, can 'consequently' alter gene expression. © 2014 Société Française des Microscopies and Société de Biologie Cellulaire de France. Published by John Wiley & Sons Ltd.

  18. Low cost and high performance screen laminate regenerator matrix

    Science.gov (United States)

    Bin-Nun, Uri; Manitakos, Dan

    2004-06-01

    A laminate screen matrix regenerator with 47 elements has been designed, analyzed, fabricated and tested. The laminate was fabricated from stainless steel screen sheets that were stacked on top of each other at certain angular orientation and then bonded at high temperature and pressure environment utilizing a sintering process. This laminate is a porous structure media with highly repeatable properties that can be controlled by varying mesh size, weave type, wire size and laminate sheet to sheet orientation. The flow direction in relation to the weave plan can be varied by cutting a cylindrical or rectangular laminate element along or across the weave. The regenerator flow resistance, thermal conductance losses, dead volume, surface area and heat transfer coefficient are analyzed. Regenerator cost and performance comparison data between the conventional widely used method of stacked screens and the new stacked laminate matrix regenerator is discussed. Also, a square stainless steel screen laminate was manufactured in a way which permits gas to flow along the screen wire instead of across it.

  19. Stress analysis of laminated glass with different interlayer materials

    Directory of Open Access Journals (Sweden)

    Mostafa M. El-Shami

    2012-03-01

    Full Text Available The use of window glass in building design is becoming increasingly popular. Laminated glass has gained popularity as a suitable and practical alternative to monolithic and insulating glass in many design situations. Laminated glass plate performance is influenced by several factors such as glass thickness, glass type, temperature, aspect ratio, load duration, and hardness of the interlayer material. A new higher order finite element model (presented by the first two authors using 9-noded quadrilateral elements was applied to investigate laminated glass plates with both different interlayer materials. An experimental load-testing program is described. Two types of interlayer materials, regular polyvinyl butyral and strong formulation of polyvinyl butyral were used. First, simply supported rectangular laminated glass plates with regular polyvinyl butyral interlayer with aspect ratios 1–5 under different temperatures were tested. Second, one set of laminated glass plates with the strong formulation of polyvinyl butyral interlayer was tested under room temperature. The experimental and theoretical results are compared and discussed. In general, the performance of laminated glass with regular polyvinyl butyral interlayer is closer to that of layered glass at higher temperature. Also, laminated glass with strong formulation of polyvinyl butyral interlayer has a significantly larger load resistance than similar regular polyvinyl butyral samples.

  20. Mitotic lamin disassembly is triggered by lipid-mediated signaling.

    Science.gov (United States)

    Mall, Moritz; Walter, Thomas; Gorjánácz, Mátyás; Davidson, Iain F; Nga Ly-Hartig, Thi Bach; Ellenberg, Jan; Mattaj, Iain W

    2012-09-17

    Disassembly of the nuclear lamina is a key step during open mitosis in higher eukaryotes. The activity of several kinases, including CDK1 (cyclin-dependent kinase 1) and protein kinase C (PKC), has been shown to trigger mitotic lamin disassembly, yet their precise contributions are unclear. In this study, we develop a quantitative imaging assay to study mitotic lamin B1 disassembly in living cells. We find that CDK1 and PKC act in concert to mediate phosphorylation-dependent lamin B1 disassembly during mitosis. Using ribonucleic acid interference (RNAi), we showed that diacylglycerol (DAG)-dependent PKCs triggered rate-limiting steps of lamin disassembly. RNAi-mediated depletion or chemical inhibition of lipins, enzymes that produce DAG, delayed lamin disassembly to a similar extent as does PKC inhibition/depletion. Furthermore, the delay of lamin B1 disassembly after lipin depletion could be rescued by the addition of DAG. These findings suggest that lipins activate a PKC-dependent pathway during mitotic lamin disassembly and provide evidence for a lipid-mediated mitotic signaling event.

  1. Export Performance of SMEs in the Nigerian Leather Industry and the Mediating Effect of Perception of Export Difficulty

    OpenAIRE

    Abubakar Sambo Junaidu

    2012-01-01

    Even though a large amount of work has been carried out to research the factors that affect export performance, there is a seeming neglect of research about specific industries operating in developing countries like Nigeria. This paper presents a research into the factors that affect export performance of SMEs in the Nigerian leather industry. Based on the resource-based view, we posit that intangible resources (Knowledge, Image and marketing resources) are all positively related to firm expo...

  2. Application of solid-phase microextraction and gas chromatography-mass spectrometry for the determination of chlorophenols in leather.

    Science.gov (United States)

    de Souza Silveira, Cristine D; Martendal, Edmar; Soldi, Valdir; Carasek, Eduardo

    2012-02-01

    This paper proposes a new analytical procedure based on the headspace solid-phase microextraction (HS-SPME) technique and gas chromatography-selected ion monitoring-mass spectrometry (GC-SIM-MS) for the determination of 16 phenols extracted from leather samples. The optimized conditions for the HS-SPME were obtained through two experimental designs - a two-level fractional factorial design followed by a central composite design - using the commercial SPME fiber polyacrylate 85 μm (PA). The best extraction conditions were as follows: 200 μL of derivatizing agent (acetic anhydride), 20 mL of saturated aqueous NaCl solution and extraction time and temperature of 50 min and 75°C, respectively. All optimized conditions were obtained with fixed leather sample mass (250 mg), vial volume (40 mL) and phosphate buffer pH (12) and concentration (50 mmol/L). Detection limits ranging from 0.03 to 0.20 ng/g, and relative standard deviation (RSD) lower than 10.23% (n=6) for a concentration of 800 ng/g (chlorophenols) and 1325 ng/g (2-phenylphenol) in the splitless mode were obtained. The recovery was studied at three concentration levels by adding different amounts of phenols to the leather sample and excellent recoveries ranging from 90.0 to 107.2% were obtained. The validated method was shown to be suitable for the quantification of phenols in leather samples, as it is simple, relatively fast and sensitive.

  3. DESIGNTURKISASUJA AMMATTIMESSUILLE TURKKIIN : Case: FutureFURstudio-hanke IDF - Istanbul Leather Fair -messuilla vuosina 2012 ja 2013

    OpenAIRE

    Tapanainen, Aino

    2014-01-01

    Opinnäytetyön toimeksiantaja oli FutureFURstudio-hanke, jonka tavoite oli luoda Pohjanmaalle kansainvälisesti tunnettu turkisalan designkeskus koko turkistoimialalle. Hanke osallistui kutsuttuna näytteilleasettajana IDF - Istanbul Leather Fair nahka- ja turkisalan ammattimessuille vuosina 2012 ja 2013. Vuoden 2012 messuosallistuminen oli hankkeelle ensimmäinen markkinointitapahtuma Euroopan Unionin ulkopuolella. Opinnäytetyön tavoitteena oli hankkia sekä tietoa Turkista hankkeelle uutena...

  4. Poultry feed based on protein hydrolysate derived from chrome-tanned leather solid waste: creating value from waste.

    Science.gov (United States)

    Chaudhary, Rubina; Pati, Anupama

    2016-04-01

    Leather industry generates huge amount of chrome-containing leather solid waste which creates major environment problems to tanners worldwide. Chrome-tanned leather solid waste is primarily chromium complex of collagen protein. The presence of chromium limits its protein application in animal feed industry. The purified protein hydrolysate with zero chromium could be used in poultry feed. In this study, an attempt has been made to assess performance of poultry with purified protein hydrolysate as a feed derived from chrome-tanned leather waste as partial replacement of soyabean meal as a sole source of protein for growing broiler chickens. Growth study was conducted to evaluate the effect of feeding protein hydrolysate on performance and physiochemical characteristics of meat of broiler chickens. Two experimental diets containing various levels of protein hydrolysate (EI-20 % and EII-30 %) were evaluated. The comparative study was performed as control with soyabean meal. Daily feed intake, body weight gain and feed conversion ratio were measured from day 8 to day 35. At the end of the study, birds were randomly selected and slaughtered to evaluate for physiochemical characteristics of meat. Diet had significant effects on feed intake and body weight gain. Birds fed with 20 and 30 % protein hydrolysate consumed 9.5 and 17.5 % higher amount of feed and gained 6.5 and 16.6 % higher than soyabean meal-fed birds. The current study produced evidence that protein hydrolysate can replace up to 75 % of soyabean meal in broiler diets without affecting either growth performance or meat characteristics.

  5. Laser-drilled micro-hole arrays on polyurethane synthetic leather for improvement of water vapor permeability

    Energy Technology Data Exchange (ETDEWEB)

    Wu, Y. [State Key Laboratory of Material Processing and Die and Mould Technology, School of Materials Science and Engineering, Huazhong University of Science and Technology, Wuhan, 430074 (China); Wang, A.H., E-mail: ahwang@mail.hust.edu.cn [State Key Laboratory of Material Processing and Die and Mould Technology, School of Materials Science and Engineering, Huazhong University of Science and Technology, Wuhan, 430074 (China); Zheng, R.R. [State Key Laboratory of Material Processing and Die and Mould Technology, School of Materials Science and Engineering, Huazhong University of Science and Technology, Wuhan, 430074 (China); Tang, H.Q.; Qi, X.Y.; Ye, B. [Wuhan Huagong Laser Engineering CO., Ltd, Wuhan, 430223 (China)

    2014-06-01

    Three kinds of lasers at 1064, 532 and 355 nm wavelengths respectively were adopted to construct micro-hole arrays on polyurethane (PU) synthetic leather with an aim to improve water vapor permeability (WVP) of PU synthetic leather. The morphology of the laser-drilled micro-holes was observed to optimize laser parameters. The WVP and slit tear resistance of the laser-drilled leather were measured. Results show that the optimized pulse energy for the 1064, 532 and 355 nm lasers are 0.8, 1.1 and 0.26 mJ, respectively. The diameters of the micro-holes drilled with the optimized laser pulse energy were about 20, 15 and 10 μm, respectively. The depths of the micro-holes drilled with the optimized pulse energy were about 21, 60 and 69 μm, respectively. Compared with the untreated samples, the highest WVP growth ratio was 38.4%, 46.8% and 53.5% achieved by the 1064, 532 and 355 nm lasers, respectively. And the highest decreasing ratio of slit tear resistance was 11.1%, 14.8%, and 22.5% treated by the 1064, 532 and 355 nm lasers, respectively. Analysis of the interaction mechanism between laser beams at three kinds of laser wavelengths and the PU synthetic leather revealed that laser micro-drilling at 355 nm wavelength displayed both photochemical ablation and photothermal ablation, while laser micro-drilling at 1064 and 532 nm wavelengths leaded to photothermal ablation only.

  6. Transparent film with inverted conical microholes array for reflection enhancement

    Science.gov (United States)

    Lei, Biao; Liu, Hongzhong; Jiang, Weitao; Chen, Bangdao; Shi, Yongsheng; Yin, Lei; Liu, Xiaokang

    2016-04-01

    PDMS has been widely utilized for microfluidic chips and microchannel detections, as its good optical properties are the prerequisite to achieve accurate and efficient detection. However, it is difficult to obtain effective information for opaque liquids. With the development of microchannel detection for wider fields, it is imperative to obtain more comprehensive information of the observed objects by integrating high transmission with enhanced reflection. This article investigates reflection enhancement by Polydimethylsiloxane (PDMS) film with inverted conical microholes array. PDMS film with inverted conical microholes array is fabricated by replication from the silicon mold with inverted microcones array which is prepared by Inductively Coupled Plasma (ICP) etch tool. The monolayer PDMS film with inverted conical microholes array shows a two-fold effectively increase in reflection, approximately up to 15%, at a broad wavelength range of 637-1131 nm and 1214-1350 nm, compared with bare PDMS film. In addition, the reflection can be further enhanced by multilayered lamination of PDMS film with inverted conical microholes array, and the enhancement is also dependent on the lamination way, i.e., for bilayer laminations, the maximum reflection enhancement occurs when with face-to-back lamination, and 32.79% larger than that with back-to-face lamination. From the experiments, the maximum reflectivity of 8-layered PDMS films can obtain 64.4% while the maximum reflectivity of monolayer PDMS film barely has 17.5%. The transparent film with inverted conical microholes array for reflection enhancement may find a variety of applications in optical devices, microchips, and energy conservation technologies etc.

  7. Formaldehyde and TVOC emission behavior of laminate flooring by structure of laminate flooring and heating condition.

    Science.gov (United States)

    An, Jae-Yoon; Kim, Sumin; Kim, Hyun-Joong

    2011-03-15

    Formaldehyde was measured with a desiccator, a 20 L chamber and the FLEC method. The formaldehyde emission rate from laminate was the highest at 32 °C using the desiccator, which then decreased with time. The formaldehyde emission using the 20 L small chamber and FLEC showed a similar tendency. There was a strong correlation between the formaldehyde and total volatile organic compounds (TVOCs) with both types of floorings using the two different methods. The formaldehyde emission rate and TVOC results were higher when tested using the FLEC method than with the 20 L small chamber method. The emission rate was affected by the joint edge length in laminate flooring. Toluene, ethylbenzene and xylene were the main VOCs emitted from laminate flooring, and there were more unidentified VOCs emitted than identified VOCs. The samples heated with a floor heating system emitted more formaldehyde than those heated using an air circulation system due to the temperature difference between the bottom panel and flooring. The TVOC emission level of the samples was higher when an air circulation system was used than when a floor heating system was used due to the high ventilation rate.

  8. An advanced higher-order theory for laminated composite plates with general lamination angles

    Institute of Scientific and Technical Information of China (English)

    Zhen Wu; Hong Zhu; Wan-Ji Chen

    2011-01-01

    This paper proposes a higher-order shear deformation theory to predict the bending response of the laminated composite and sandwich plates with general lamination configurations.The proposed theory a priori satisfies the continuity conditions of transverse shear stresses at interfaces.Moreover,the number of unknown variables is independent of the number of layers.The first derivatives of transverse displacements have been taken out from the inplane displacement fields,so that the C0 shape functions are only required during its finite element implementation.Due to C0 continuity requirements,the proposed model can be conveniently extended for implementation in commercial finite element codes.To verify the proposed theory,the fournode C0 quadrilateral element is employed for the interpolation of all the displacement parameters defined at each nodal point on the composite plate.Numerical results show that following the proposed theory,simple C0 finite elements could accurately predict the interlaminar stresses of laminated composite and sandwich plates directly from a constitutive equation,which has caused difficulty for the other global higher order theories.

  9. Development and characterization of ordered, highly oriented, composite laminates using supercritical carbon dioxide

    Science.gov (United States)

    Caskey, Terrence Colin

    This thesis describes the development and subsequent characterization of a series of oriented, highly ordered laminated composite materials. These laminated composite materials all possess order over varying length-scales from angstrom level molecular chain orientation to macro-scale order in woven fabrics. In each case, supercritical carbon dioxide (SC CO2) is used as a unique reaction medium and processing aid allowing for the development of structures not previously attainable with standard techniques. The goal of this research is two-fold, the first goal involves the proof of concept, exhibiting the ability to attain novel composite structures using unique SC CO2 chemistries and processes. The second goal of this research is aimed at developing a thorough understanding of how these unique structures and morphologies translate into an overall mechanical response for the material. This work will be divided into three distinct but interrelated projects. The first project involves the development of a unique SC CO2 assisted solvent welding technique. This technique is then applied towards the fabrication of a quasi-isotropic laminate comprised of a series of solvent-welded uniaxially-oriented linear low density polyethylene films (LLDPE). The geometry of this laminate is designed to exploit the improved strength and rigidity of uniaxially oriented LLDPE films while suppressing undesireable transverse properties. The second project to be addressed in this project involves the development of fiber-reinforced composites with unique nano-scale morphologies. The long-range order in these composites has profound effects on both the individual fiber properties as well as the overall composite properties. The final project of interest in this work involves the development of intercalated silicate nano-composites with high clay content. In order to achieve the desired morphologies it is necessary to create polymer/clay nano-composites with very high clay content

  10. Reliability analysis of ceramic matrix composite laminates

    Science.gov (United States)

    Thomas, David J.; Wetherhold, Robert C.

    1991-01-01

    At a macroscopic level, a composite lamina may be considered as a homogeneous orthotropic solid whose directional strengths are random variables. Incorporation of these random variable strengths into failure models, either interactive or non-interactive, allows for the evaluation of the lamina reliability under a given stress state. Using a non-interactive criterion for demonstration purposes, laminate reliabilities are calculated assuming previously established load sharing rules for the redistribution of load as the failure of laminae occur. The matrix cracking predicted by ACK theory is modeled to allow a loss of stiffness in the fiber direction. The subsequent failure in the fiber direction is controlled by a modified bundle theory. Results using this modified bundle model are compared with previous models which did not permit separate consideration of matrix cracking, as well as to results obtained from experimental data.

  11. The Creep of Laminated Synthetic Resin Plastics

    Science.gov (United States)

    Perkuhn, H

    1941-01-01

    The long-time loading strength of a number of laminated synthetic resin plastics was ascertained and the effect of molding pressure and resin content determined. The best value was observed with a 30 to 40 percent resin content. The long-time loading strength also increases with increasing molding pressure up to 250 kg/cm(exp 2); a further rise in pressure affords no further substantial improvement. The creep strength is defined as the load which in the hundredth hour of loading produces a rate of elongation of 5 X 10(exp -4) percent per hour. The creep strength values of different materials were determined and tabulated. The effect of humidity during long-term tests is pointed out.

  12. Penetration of Projectiles in Composite Laminates

    Directory of Open Access Journals (Sweden)

    B. P. Patel

    2004-04-01

    Full Text Available This paper deals with the prediction of the penetration phenomenon of a cylindro-conical impactor on the ke;labepoxy-laminated composites using C eight-nded serendipity q&drilateral finite elementbased on first-order shear deformation theory (FSDT. Local as well as global deformations during impact is considered in the evaluation of indentation, penetration, and perforation phases. Local strainsduring impact have been evaluated using the hypothesis made from the available experimental observations of bulging during penetration. A detailed parametric study, considering various projectilesand target plate variables, has been carried out to find their effect on the response of the plate, and ballistic parameters, such as ballistic limit and absorbed energy.

  13. Box-Behnken methodology for Cr (VI) and leather dyes removal by an eco-friendly biosorbent: F. vesiculosus.

    Science.gov (United States)

    Cobas, M; Sanromán, M A; Pazos, M

    2014-05-01

    This study focused on leather industrial effluents treatment by biosorption using Fucus vesiculosus as low-cost adsorbent. These effluents are yellowish-brown color and high concentration of Cr (VI). Therefore, biosorption process was optimized using response surface methodology based on Box-Behnken design operating with a simulated leather effluent obtained by mixture of Cr (VI) solution and four leather dyes. The key variables selected were initial solution pH, biomass dosage and CaCl2 concentration in the pretreatment stage. The statistical analysis shows that pH has a negligible effect, being the biomass dosage and CaCl2 concentration the most significant variables. At optimal conditions, 98% of Cr (VI) and 88% of dyes removal can be achieved. Freundlich fitted better to the obtained equilibrium data for all studied systems than Temkin, Langmuir or D-R models. In addition, the use of the final biosorbent as support-substrate to grown of enzyme producer fungi, Pleurotus ostreatus, was also demonstrated.

  14. Anaerobic digestion of selected Italian agricultural and industrial residues (grape seeds and leather dust): combined methane production and digestate characterization.

    Science.gov (United States)

    Caramiello, C; Lancellotti, I; Righi, F; Tatàno, F; Taurino, R; Barbieri, L

    2013-01-01

    A combined experimental evaluation of methane production (obtained by anaerobic digestion) and detailed digestate characterization (with physical-chemical, thermo-gravimetric and mineralogical approaches) was conducted on two organic substrates, which are specific to Italy (at regional and national levels). One of the substrates was grape seeds, which have an agricultural origin, whereas the other substrate was vegetable-tanned leather dust, which has an industrial origin. Under the assumed experimental conditions of the performed lab-scale test series, the grape seed substrate exhibited a resulting net methane production of 175.0 NmL g volatile solids (VS)(-1); hence, it can be considered as a potential energy source via anaerobic digestion. Conversely, the net methane production obtained from the anaerobic digestion of the vegetable-tanned leather dust substrate was limited to 16.1 NmL gVS(-1). A detailed characterization of the obtained digestates showed that there were both nitrogen-containing compounds and complex organic compounds present in the digestate that was obtained from the mixture of leather dust and inoculum. As a general perspective of this experimental study, the application of diversified characterization analyzes could facilitate (1) a better understanding of the main properties of the obtained digestates to evaluate their potential valorization, and (2) a combination of the digestate characteristics with the corresponding methane productions to comprehensively evaluate the bioconversion process.

  15. Green Barriers to China Leather Trade%绿色壁垒与中国皮革贸易

    Institute of Scientific and Technical Information of China (English)

    章培昆; 刘健西

    2012-01-01

    绿色壁垒也称环境壁垒,是国际贸易中迅速发展的一种新非关税贸易保护措施,已逐渐成为发达国家实施贸易保护主义的主要手段和高级形式。简述了我国皮革行业面临的绿色壁垒现状,分析其对我国皮革制品贸易出口产生的深远影响,并提出我国可采取的积极应对措施。%Green barriers are known as environmental barriers to trade. They are a new kind of non-tariff trade protective measures, and now gradually become the primary means and advanced forms of trade protectionism in many developed countries. The emergence of Green barriers in international trade has generated the profound influence to the export of China’s leather and leather goods. Facing the grim challenge brought about by trade protectionism, some active and effective measures must be taken to our leather industry.

  16. Resource Utilization of Chromium Containing Leather Waste%含铬革屑的资源化利用

    Institute of Scientific and Technical Information of China (English)

    罗凤香

    2014-01-01

    Heavy metal chromium containing leather waste shavings, if not effectively treated, will cause environmental pollution and human health damage. In the increasingly serious environmental problems and increasingly scarce resource today, the resource utilization of above mentioned chrome tanned leather shavings has enormous environmental and economic value. This paper describes the methods to utilize chromium leather shavings in recent years.%含有重金属铬的含铬革屑制革废弃物,如果不能有效处理,将会造成环境污染及人类等健康损害。在环境问题日益严重和资源日趋贫乏的今天,对含铬革屑的资源化利用具有巨大的环境和经济价值。本文简述了近年来对含铬革屑的利用方法。

  17. 有机硅在皮革中的应用%Application of the Organic Silicone in Leather Industry

    Institute of Scientific and Technical Information of China (English)

    张建雨; 桑莹莹

    2011-01-01

    The characteristics and applications of organic silicone in leather industry were described. They were mainly used as waterproof agents, tanning agents, fatliquoring agents, finishing agents and so on. Main manufacturers and performance of organic silicone compounds used as leather chemical materials at home and abroad were reviewed. Finally, the suggestions about development of organic silicone leather chemical materials were pointed out and their applications in the future were prospected.%介绍了有机硅的特性及在皮革工业中的主要应用,其主要用作皮革防水剂、鞣剂、加脂剂、涂饰剂等.综述了国内外有机硅皮化材料的主要生产厂家及产品性能.对未来发展有机硅皮化材料提出了几点意见,并对其在皮革中的应用前景进行了展望.

  18. Complex coacervation of collagen hydrolysate extracted from leather solid wastes and chitosan for controlled release of lavender oil.

    Science.gov (United States)

    Ocak, Buğra

    2012-06-15

    In the world, approximately 600,000 metric tonnes of chromium-containing solid wastes are generated by the leather industry each year. Environmental concerns and escalating landfill costs are becoming increasingly serious problems to the leather industry and seeking solutions to these problems is a prime concern in much research today. In this study, solid collagen-based protein hydrolysate was isolated from chromium-tanned leather wastes and its chemical properties were determined. Microcapsules of collagen hydrolysate (CH) - chitosan (C) crosslinked with glutaraldehyde (GA) containing Lavender oil (LO) were prepared by complex coacervation method. The effects of various processing parameters, including the CH to C ratio, LO content, and GA, on the oil load (%), oil content (%), encapsulation efficiency (%) and release rate of LO from microcapsules were investigated. As the ratio of C present in the CH/C mixture and crosslinking density increased, the release rate of LO from microcapsules slowed down. Optical and scanning electron microscopy images illustrated that the LO microcapsules were spherical in shape. Fourier transform infrared spectroscopy (FTIR) studies confirmed that there was no significant interaction between CH/C complex and LO.

  19. Thermally-induced shapes of rigid FR-4 electrical laminates

    Science.gov (United States)

    Lyle, Phra Douglas

    In the process of a laminate cooling from the curing temperature to room temperature, a substantial level of thermal residual stresses develop. These residual thermal stresses arise due to the mismatch of the thermal expansion coefficient between lamina and between the reinforcing fibers and the matrix resin, generating warpage, or out of plane deformations, when the laminate is not symmetric about the midplane of the composite. Classical lamination theory has been used to predict the warped shape of an asymmetric laminate; this theory suggests that the cooled room temperature shape to be a stable anticlastic or saddle shape. In the 80s, nonlinear theories were developed in order to explain observations for (0/90) sbT cross-ply laminates that cool to a cylindrical shape and to predict the observed phenomena of an occasional "snap through" between two stable cylindrical shapes. Recently, the nonlinear approach has been successfully modified for the analysis of a square angle-ply laminate, allowing an even greater number of laminates to be evaluated. A rigid FR-4 electrical circuit board is a composite laminate that is designed to be symmetrical; however, after cooling from the press cycle or after cooling from other processing thermal excursions, warpage can occur. One potential cause for this warpage can be inadvertently introduced process or material nonuniformities. This investigation develops an FR-4 electrical laminate model that can transform selected material and process variations into input for the mechanical and thermal matrices required in the formulation of both classical lamination and the nonlinear theories. The output is the predicted warpage, for each theory, for each of the selected material and process variations. These warpage outputs are graphically displayed, quantified and compared for the classical lamination theory and for the four recent nonlinear theories. Also, the predicted warpage deformations are stack ranked in order to provide an

  20. Improved PMR Polyimides For Heat-Stable Laminates

    Science.gov (United States)

    Vannucci, R. D.; Malarik, D. C.; Papadapoulos, D. S.; Waters, John F.

    1994-01-01

    Second-generation PMR-type polyimides (PMR-II polyimides) of enhanced thermo-oxidative stability prepared by substitution of para-aminostyrene (PAS) end caps for nadic-ester (NE) end caps used in prior PMR-II polyimides. Laminates unidirectionally reinforced with graphite fibers and made with PAS-capped resins exhibited thermo-oxidative stabilities significantly greater than those of similar laminates made with NE-capped PMR-II resins. One new laminate exhibited high retention of weight and strength after 1,000 h of exposure to air at 371 degrees C.

  1. IMPACT OF LEATHER PROCESSING INDUSTRIES ON CHROMIUM CONCENTRATION IN GROUNDWATER SOUTH OF CHENNAI CITY, INDIA

    Science.gov (United States)

    Elango, L.; Brindha, K.; G. Rajesh, V.

    2009-12-01

    The groundwater quality is under threat due to disposal of effluents from a number of industries. Poor practice of treatment of wastes from tanning industries or leather processing industries lead to pollution of groundwater. This study was carried out with the objective of assessing the impact of tanneries on groundwater quality in Chromepet area which is a part of the metropolitan area of Chennai, Tamil Nadu, India. This area serves as the home town for a number of small and large scale tanning industries. People in certain parts of this area depend on the groundwater for their domestic needs as there is no piped drinking water supply system. Topographically this region is generally flat with gentle slope towards east and north east. The charnockite rocks occur as basement at the depth of about 15m from the surface of this area. Weathered charnockite rock occurs at the depth from 7m to 15m from the ground surface. The upper layer consists of loamy soil. Groundwater occurs in the unconfined condition at a depth from 0.5m to 5m. Thirty six groundwater samples were collected during March 2008 and the groundwater samples were analysed for their heavy metal (chromium) content using atomic absorption spectrophotometer. Bureau of Indian Standards (BIS) recommended the maximum permissible limit of chromium in drinking water as 0.05 mg/l. Considering this, it was found that 86% of the groundwater samples possessed concentration of chromium above the maximum permissible limit recommended by BIS. The tanneries use chrome sulphate to strengthen the leather and make it water repellent. The excess of chromium gets washed off and remains in the wastewater. This wastewater is disposed into open uncovered drains either untreated or after partial treatment. Thus the chromium leaches through the soil and reaches the groundwater table. Apart from this, there is also huge quantity of solid waste resulting from the hides and skins which are dumped off without suitable treatment. The

  2. Tungsten(VI) Oxide Flake-Wall Film Electrodes for Photoelectrochemical Oxygen Evolution from Water

    OpenAIRE

    Amano, Fumiaki; Li, Ding; Ohtani, Bunsho

    2010-01-01

    A vertically arrayed flake film, "flake-wall film", of monoclinic tungsten(VI) oxide (WO3) was prepared on a transparent conductive glass. The WO3 flake-wall film exhibited superior performance for photoelectrochemical water oxidation under visible-light irradiation compared to that of a film consisting of horizontally laminated WO3 flakes. The small difference between photocurrent densities under front-side irradiation and back-side irradiation indicates the excellent electron transport prop...

  3. Validation of formability of laminated sheet metal for deep drawing process using GTN damage model

    Energy Technology Data Exchange (ETDEWEB)

    Lim, Yongbin; Cha, Wan-gi; Kim, Naksoo [Department of Mechanical Engineering, Sogang University, 1 Sinsu-dong, Mapo-gu, Seoul, 121-742 (Korea, Republic of); Ko, Sangjin [Mold/die and forming technology team, Product prestige research lab, LG electronics, 222, LG-ro, Jinwi-myeon, Pyeongtaek-si, Gyeonggi-do, 451-713 (Korea, Republic of)

    2013-12-16

    In this study, we studied formability of PET/PVC laminated sheet metal which named VCM (Vinyl Coated Metal). VCM offers various patterns and good-looking metal steel used for appliances such as refrigerator and washing machine. But, this sheet has problems which are crack and peeling of film when the material is formed by deep drawing process. To predict the problems, we used finite element method and GTN (Gurson-Tvergaard-Needleman) damage model to represent damage of material. We divided the VCM into 3 layers (PET film, adhesive and steel added PVC) in finite element analysis model to express the crack and peeling phenomenon. The material properties of each layer are determined by reverse engineering based on tensile test result. Furthermore, we performed the simple rectangular deep drawing and simulated it. The simulation result shows good agreement with drawing experiment result in position, punch stroke of crack occurrence. Also, we studied the fracture mechanism of PET film on VCM by comparing the width direction strain of metal and PET film.

  4. Validation of formability of laminated sheet metal for deep drawing process using GTN damage model

    Science.gov (United States)

    Lim, Yongbin; Cha, Wan-gi; Ko, Sangjin; Kim, Naksoo

    2013-12-01

    In this study, we studied formability of PET/PVC laminated sheet metal which named VCM (Vinyl Coated Metal). VCM offers various patterns and good-looking metal steel used for appliances such as refrigerator and washing machine. But, this sheet has problems which are crack and peeling of film when the material is formed by deep drawing process. To predict the problems, we used finite element method and GTN (Gurson-Tvergaard-Needleman) damage model to represent damage of material. We divided the VCM into 3 layers (PET film, adhesive and steel added PVC) in finite element analysis model to express the crack and peeling phenomenon. The material properties of each layer are determined by reverse engineering based on tensile test result. Furthermore, we performed the simple rectangular deep drawing and simulated it. The simulation result shows good agreement with drawing experiment result in position, punch stroke of crack occurrence. Also, we studied the fracture mechanism of PET film on VCM by comparing the width direction strain of metal and PET film.

  5. Nuclear lamins during gametogenesis, fertilization and early development

    Science.gov (United States)

    Maul, G. G.; Schatten, G.

    1986-01-01

    The distribution of lamins (described by Gerace, 1978, as major proteins of nuclear envelope) during gametogenesis, fertilization, and early development was investigated in germ cells of a mouse (Mus musculus), an echinoderm (Lytechinus variegatus), and the surf clam (Spisula solidissima) was investigated in order to determine whether the differences detected could be correlated with differences in the function of cells in these stages of the germ cells. In order to monitor the behavior of lamins, the gametes and embryos were labeled with antibodies to lamins A, C, and B extracted from autoimmune sera of patients with scleroderma and Lupus erythematosus. Results indicated that lamin B could be identified in nuclear envelopes on only those nuclei where chromatin is attached and where RNA synthesis takes place.

  6. Characterization of delamination onset and growth in a composite laminate

    Science.gov (United States)

    Obrien, T. K.

    1981-01-01

    The onset and growth of delaminations in unnotched (+ or - 30/+ or - 30/90/90 bar) sub S graphite epoxy laminates is described quantitatively. These laminates, designed to delaminate at the edges under tensile loads, were tested and analyzed. Delamination growth and stiffness loss were monitored nondestructively. Laminate stiffness decreased linearly with delamination size. The strain energy release rate, G, associated with delamination growth, was calculated from two analyses. A critical G for delamination onset was determined, and then was used to predict the onset of delaminations in (+45 sub n/-45 sub n/o sub n/90 sub n) sub s (n=1,2,3) laminates. A delamination resistance curve (R curve) was developed to characterize the observed stable delamination growth under quasi static loading. A power law correlation between G and delamination growth rates in fatigue was established.

  7. Finite elements modeling of delaminations in composite laminates

    DEFF Research Database (Denmark)

    Gaiotti, m.; Rizzo, C.M.; Branner, Kim;

    2011-01-01

    The application of composite materials in many structures poses to engineers the problem to create reliable and relatively simple methods, able to estimate the strength of multilayer composite structures. Multilayer composites, like other laminated materials, suffer from layer separation, i.e., d...... by finite elements using different techniques. Results obtained with different finite element models are compared and discussed.......The application of composite materials in many structures poses to engineers the problem to create reliable and relatively simple methods, able to estimate the strength of multilayer composite structures. Multilayer composites, like other laminated materials, suffer from layer separation, i...... of the buckling strength of composite laminates containing delaminations. Namely, non-linear buckling and post-buckling analyses are carried out to predict the critical buckling load of elementary composite laminates affected by rectangular delaminations of different sizes and locations, which are modelled...

  8. Optimum design of laminated composite under axial compressive load

    Indian Academy of Sciences (India)

    N G R Iyengar; Nilesh Vyas

    2011-02-01

    In the present study optimal design of composite laminates, with and without rectangular cut-out, is carried out for maximizing the buckling load. Optimization study is carried out for obtaining the maximum buckling load with design variables as ply thickness, cut-out size and orientation of cut-out with respect to laminate. Buckling load is evaluated using a ‘simple higher order shear deformation theory’ based on four unknown displacements $u,v,w_b$ and $w_s$. A C1 continuous shear flexible finite element based on HSDT model is developed using Hermite cubic polynomial. It is observed that for thick anti-symmetric laminates, the non-dimensional buckling load decreases with increase in aspect ratio and increase in fibre orientation angle. There is a decrease in the non-dimensional buckling load of symmetric laminate in the presence of cut-out.

  9. Natural fabric sandwich laminate composites: development and investigation

    Indian Academy of Sciences (India)

    C K ARVINDA PANDIAN; H SIDDHI JAILANI; A RAJADURAI

    2017-02-01

    In this work, eco-friendly natural fabric sandwich laminate (NFSL) composites are formulated using jute and linen-fabric-reinforced epoxy with different layer ratios (5:0, 4:1, 3:2, 2:3, 1:4 and 0:5) by hand layup system. Different mechanical attributes (tensile, flexural and impact) of the NFSL composites are quantified. Thermal stability and water absorption behaviour of the NFSL composites are also assessed. A scanning electron microscope (SEM) and optical microscope are used for qualitative analysis of NFSL composites’ interfacial properties. Two layers of jute and three layers of linen sandwich laminate have registered peak values in tensile and impact properties. The five layers of linen laminate composite have exhibited high flexural strength, been proven to have good thermal stability and furthermore shown better water absorption behaviour than any other laminate composites.

  10. Lamin A-dependent nuclear defects in human aging.

    Science.gov (United States)

    Scaffidi, Paola; Misteli, Tom

    2006-05-19

    Mutations in the nuclear structural protein lamin A cause the premature aging syndrome Hutchinson-Gilford progeria (HGPS). Whether lamin A plays any role in normal aging is unknown. We show that the same molecular mechanism responsible for HGPS is active in healthy cells. Cell nuclei from old individuals acquire defects similar to those of HGPS patient cells, including changes in histone modifications and increased DNA damage. Age-related nuclear defects are caused by sporadic use, in healthy individuals, of the same cryptic splice site in lamin A whose constitutive activation causes HGPS. Inhibition of this splice site reverses the nuclear defects associated with aging. These observations implicate lamin A in physiological aging.

  11. Reliability Based Optimization of Composite Laminates for Frequency Constraint

    Institute of Scientific and Technical Information of China (English)

    Wu Hao; Yan Ying; Liu Yujia

    2008-01-01

    The reliability based optimization (RBO) issue of composite laminates under fundamental frequency constraint is studied. Considering the uncertainties of material properties, the frequency constraint reliability of the structure is evaluated by the combination of response surface method (RSM) and finite element method. An optimization algorithm is developed based on the mechanism of laminate frequency characteristics, to optimize the laminate in terms of the ply amount and orientation angles. Numerical examples of composite laminates and cylindrical shell illustrate the advantages of the present optimization algorithm on the efficiency and applicability respects.The optimal solutions of RBO are obviously different from the deterministic optimization results, and the necessity of considering material property uncertainties in the composite srtuctural frequency constraint optimization is revealed.

  12. Determination of fatigue cracking direction in composite laminates

    Institute of Scientific and Technical Information of China (English)

    DAI Yao; HAO Gui-xiang; LI Yong-dong; HE Jia-wen; CUI Jian-guo; LI Nian; FU Yong-hui; SUN Jun

    2005-01-01

    The interface plays the central role in the failure analysis of composite laminates, therefore, the interface material properties are taken as the independent parameters. A simple, universal and practicable criterion, i.e. a ratio criterion of strain energy release rate, is proposed to determine the growing direction of a fatigue crack in the composite laminates. The method of arbitrary lines, which is very effective to solve the problems with high gradient feature, is used to analyze the experimental results at the key moments when a crack kinks, turns into the interface,or bifurcates. An approximate method of computing the energy release rate is given. The fatigue fracture tests of composite laminates are carried out, and the numerical predictions of crack growing directions agree well with the experimental results. It is concluded that the methods suggested in this paper are effective to obtain the cracking history and the growing path of a fatigue crack in composite laminates.

  13. Design and Ballistic Performance of Hybrid Composite Laminates

    Science.gov (United States)

    Ćwik, Tomasz K.; Iannucci, Lorenzo; Curtis, Paul; Pope, Dan

    2016-10-01

    This paper presents an initial design assessment of a series of novel, cost-effective, and hybrid composite materials for applications involving high velocity impacts. The proposed hybrid panels were designed in order to investigate various physical phenomenon occurring during high velocity impact on compliant laminates from a previous study on Dyneema® and Spectra®. In the first, screening phase of the study twenty different hybrid composite laminates were impacted with 20 mm Fragment Simulating Projectiles at 1 km/s striking velocity. The best performing concepts were put forward to phase II with other hybrid concepts involving shear thickening fluids, commonly used in low velocity impacts. The results indicated that it is possible to design hybrid laminates of similar ballistic performance as the reference Dyneema® laminate, but with lower material costs. The optimal hybrid concept involves a fibre reinforced Polypropylene front and a Dyneema® backing.

  14. Vibration analysis of composite laminate plate excited by piezoelectric actuators.

    Science.gov (United States)

    Her, Shiuh-Chuan; Lin, Chi-Sheng

    2013-01-01

    Piezoelectric materials can be used as actuators for the active vibration control of smart structural systems. In this work, piezoelectric patches are surface bonded to a composite laminate plate and used as vibration actuators. A static analysis based on the piezoelectricity and elasticity is conducted to evaluate the loads induced by the piezoelectric actuators to the host structure. The loads are then employed to develop the vibration response of a simply supported laminate rectangular plate excited by piezoelectric patches subjected to time harmonic voltages. An analytical solution of the vibration response of a simply supported laminate rectangular plate under time harmonic electrical loading is obtained and compared with finite element results to validate the present approach. The effects of location and exciting frequency of piezoelectric actuators on the vibration response of the laminate plate are investigated through a parametric study. Numerical results show that modes can be selectively excited, leading to structural vibration control.

  15. Embossed Teflon AF Laminate Membrane Microfluidic Diaphragm Valves

    Science.gov (United States)

    Willis, Peter; Hunt, Brian; White,Victor; Grunthaner, Frank

    2008-01-01

    A microfluidic system has been designed to survive spaceflight and to function autonomously on the Martian surface. It manipulates microscopic quantities of liquid water and performs chemical analyses on these samples to assay for the presence of molecules associated with past or present living processes. This technology lies at the core of the Urey Instrument, which is scheduled for inclusion on the Pasteur Payload of the ESA ExoMars rover mission in 2013. Fabrication processes have been developed to make the microfabricated Teflon-AF microfluidic diaphragm pumps capable of surviving extreme temperature excursions before and after exposure to liquid water. Two glass wafers are etched with features and a continuous Teflon membrane is sandwiched between them (see figure). Single valves are constructed using this geometry. The microfabricated devices are then post processed by heating the assembled device while applying pneumatic pressure to force the Teflon diaphragm against the valve seat while it is softened. After cooling the device, the embossed membrane retains this new shape. This solves previous problems with bubble introduction into the fluid flow where deformations of the membrane at the valve seat occurred during device bonding at elevated temperatures (100-150 C). The use of laminated membranes containing commercial Teflon AF 2400 sheet sandwiched between spun Teflon AF 1600 layers performed best, and were less gas permeable than Teflon AF 1600 membranes on their own. Spinning Teflon AF 1600 solution (6 percent in FLOURINERT(Registered TradeMark) FC40 solvent, 3M Company) at 500 rpm for 1.5 seconds, followed by 1,000 rpm for 3 seconds onto Borofloat glass wafers, results in a 10-micron-thick film of extremely smooth Teflon AF. This spinning process is repeated several times on flat, blank, glass wafers in order to gradually build a thick, smooth membrane. After running this process at least five times, the wafer and Teflon coating are heated under vacuum

  16. Advanced Textile Laminates for Chemical Biological Protective Clothing

    Science.gov (United States)

    2008-12-01

    and were subjected to thermal calendering using a 2-roller B. F. Perkins thermal bonder with a 260 line/inch engraved calender roller. The...bonding ofthe laminate, the SB PP is being subjected to a second calendering process. In the first method, two laminates were prepared with both having a...were subjected to thermal calendering using a 2-roller B. F. Perkins thermal bonder at The University of Tennessee Nonwovens Research Laboratory

  17. Multi-material topology design of laminates with strength criteria

    DEFF Research Database (Denmark)

    Lund, Erik

    2012-01-01

    The objective of this paper is to present a novel approach for multi-material topology optimization of laminated composite structures where strength constraints are taken into account together with other global structural performance measures. The topology design problem considered contains very...... are illustrated for multi-material laminated design problems where the maximum failure index is minimized while compliance and mass constraints are taken into account....

  18. Porcelain laminate veneers: Clinical survey for evaluation of failure

    OpenAIRE

    Diemah F Alhekeir; Al-Sarhan, Rana A.; Al Mashaan, Abdulmohsen F.

    2014-01-01

    Objective: To investigate the association of the failure of porcelain laminate veneers with factors related to the patient, material, and operator. Methods: This clinical survey involved 29 patients (19 women and 10 men) and their dentists, including undergraduate and postgraduate dental students and dental interns. Two questionnaires were distributed to collect information from participants. All patients were clinically examined. Criteria for failure of the porcelain laminate veneers incl...

  19. Laminated microchannel devices, mixing units and method of making same

    Science.gov (United States)

    Bennett, Wendy D [Kennewick, WA; Hammerstrom, Donald J [West Richland, WA; Martin, Peter M [Kennewick, WA; Matson, Dean W [Kennewick, WA

    2002-10-17

    A laminated microchannel device is described in which there is a unit operation process layer that has longitudinal channel. The longitudinal channel is cut completely through the layer in which the unit process operation resides. Both the device structure and method of making the device provide significant advantages in terms of simplicity and efficiency. A static mixing unit that can be incorporated in the laminated microchannel device is also described.

  20. Analysis of lamination measurements for CERN's twin aperture quadrupoles

    CERN Document Server

    Clark, G S

    2002-01-01

    The European Organization for Nuclear Research (CERN) is constructing the Large Hadron Collider (LHC). The LHC's cleaning insertions require 48 twin aperture resistive quadrupoles. The laminations for these magnets are punched from low carbon steel sheet 1.5 mm thick. To check the quality of the laminations, samples are regularly collected and measured. This paper describes how these measurements are analyzed. This work is part of the Canadian contribution to the LHC. (5 refs).

  1. Review on antibacterial biocomposites of structural laminated veneer lumber

    Science.gov (United States)

    Chen, Zi-xiang; Lei, Qiong; He, Rui-lin; Zhang, Zhong-feng; Chowdhury, Ahmed Jalal Khan

    2015-01-01

    In this review, the characteristics and applications of structural laminated veneer lumber made from planted forest wood is introduced, and its preparation is explained, including various tree species and slab qualities, treatments for multiple effects and reinforced composites. The relevant factors in the bonding technology and pressing processes as well as the mechanical properties, research direction and application prospects of structural laminated veneer lumber made from planted forest wood are discussed. PMID:26858559

  2. Impact of aerobic stabilization on the characteristics of treatment sludge in the leather tanning industry.

    Science.gov (United States)

    Cokgor, Emine Ubay; Aydinli, Ebru; Tas, Didem Okutman; Zengin, Gulsum Emel; Orhon, Derin

    2014-01-01

    The efficiency of aerobic stabilization on the treatment sludge generated from the leather industry was investigated to meet the expected characteristics and conditions of sludge prior to landfill. The sludge types subjected to aerobic stabilization were chemical treatment sludge, biological excess sludge, and the mixture of both chemical and biological sludges. At the end of 23 days of stabilization, suspended solids, volatile suspended solids and total organic carbon removal efficiencies were determined as 17%, 19% and 23% for biological sludge 31%, 35% and 54% for chemical sludge, and 32%, 34% and 63% for the mixture of both chemical and biological sludges, respectively. Model simulations of the respirometric oxygen uptake rate measurements showed that the ratio of active biomass remained the same at the end of the stabilization for all the sludge samples. Although mixing the chemical and biological sludges resulted in a relatively effective organic carbon and solids removal, the level of stabilization achieved remained clearly below the required level of organic carbon content for landfill. These findings indicate the potential risk of setting numerical restrictions without referring to proper scientific support.

  3. Safe disposal of toxic chrome buffing dust generated from leather industries.

    Science.gov (United States)

    Swarnalatha, S; Srinivasulu, T; Srimurali, M; Sekaran, G

    2008-01-31

    The high concentration of trivalent chromium along with organic/inorganic compounds in chrome buffing dust (CBD), the solid waste discharged from leather industries, causes severe groundwater contamination on land co-disposal and chronic air pollution during thermal incineration. In the present investigation, CBD was subjected to starved air incineration (SAI) at 800 degrees C in a thermal incinerator under different flow rates of oxygen to optimize the oxygen required to incinerate the organic compounds and simultaneously preventing the conversion of Cr(3+) to Cr(6+). The energy audit of SAI of buffing dust under the external supply of oxygen was carried out under different incineration conditions. The bottom ash from SAI was effectively solidified/stabilized using Portland cement and fine aggregate. The solidified blocks were tested for unconfined compressive strength and heavy metal leaching. Unconfined compressive strength of the blocks was in the range of 120-180 kg/cm(2). The stabilization of chromium(III) in the cement gel matrix was confirmed using Scanning Electron Microscopy SEM, Electron Paramagnetic Resonance spectroscopy (EPR) and X-ray diffraction spectroscopy (XRD). Leachability studies through TCLP on solidified blocks were carried out to determine the degree of leaching of chromium and organic compounds (expressed as COD) under standard conditions.

  4. Spectrochemical Analysis of Soil around Leather Tanning Industry Using Laser Induced Breakdown Spectroscopy

    Directory of Open Access Journals (Sweden)

    Shakeel Ahmad Khan

    2013-01-01

    Full Text Available We report the use of laser induced breakdown spectroscopy (LIBS to determine the chromium contamination of soil due to effluents from leather tanning industry in Kasur District of Punjab (+31∘6′23.21″, +74∘27′16.29″ in Pakistan. Calibration curves were constructed by indigenously prepared standard sample and fitting of curves by linear regression. The limit of detection (LOD was found to be 23.71 mg kg−1. It has been found that the concentration of chromium in the soil is up to 839 mg kg−1 in vicinity of effluent drain and 1829 mg kg−1 in the area of old stagnant pool, which is much higher than the safe limits. Qualitative detection of other elements like Na, Cl, Fe, P, and Si was done from LIBS spectra. The leaching of soil contaminants due to seepage of industrial effluents from deteriorating brick lined drains in horizontal direction has also been observed.

  5. Effect of clay minerals and nanoparticles on chromium fractionation in soil contaminated with leather factory waste.

    Science.gov (United States)

    Taghipour, Marzieh; Jalali, Mohsen

    2015-10-30

    This study was conducted to investigate the effect of time, clay minerals and nanoparticles (NPs) on chromium (Cr) fractionation in a soil contaminated with leather factory waste (LFW). Soil was mixed with LFW, then, the contaminated soils were treated with clay minerals (bentonite and zeolite) and nanoparticles (MgO, TiO2 and ZnO) at 5% and 1%, respectively. The samples were incubated for 15-180 days at 25 °C and constant moisture. After incubation, Cr in control and treated soils was fractionated by the sequential extraction procedure. The distribution of various Cr fractions in control soil indicated that the greatest amounts of Cr were found in the residual fraction (RES) followed by the carbonate (CAR), organic matter (OM) and exchangeable (EXC) fractions. The addition of LFW in soils increased Cr concentration in all fractions. The higher proportion of EXC fraction in the soil treated with LFW indicates its higher potential of leaching and runoff transport. In all treated soils, the RES fraction was increased, while EXC and OM fractions were decreased during incubation. The results indicated that NPs are effective adsorbent for the removal of Cr ions from LFW treated soil, and they could be useful in reducing their environment risk.

  6. Application of lifetime analysis for the leather; Aplicacion del analisis del ciclo de vida al calzado

    Energy Technology Data Exchange (ETDEWEB)

    Mila, L.; Domenech, X.; Rieradevall, J. [Universitat Autonoma de Barcelona (Spain); Fullana, P. [Randa Group, s.A. (Spain); Puig, R. [Escola Universitaria d`Enginueria Tecnica Industrial, Iagualada. Barcelona (Spain)

    1997-12-31

    Life Cycle Assessment (LCA) has been applied to the leather footwear industry. Due the fact that the goal of the study is to point those steps in the footwear cycle which more contribute to the total environmental impact, only a simplified semi-quantitative methodology is use. background-data of all the inputs and outputs form the system have been inventoried. Impact assessment has been restricted to classification and characterisation. From the results of this LCA it has been concluded that energy consumption is an important impact generators phase, due to the characteristics of the electricity production in the studied area (Catalonia and the rest of Spain). A remarkable impacts is generated in the solid waste management phase, also due to its characteristics in the studied area. Another significant impact source is the cutting raising phase, where great values of Global Warming, Acidification and Eutrophication Potentials are estimated. At the tannery, a great value of water eutrophication potential is observed, and this phase is also important for its non renewable resources consumption. (Author) 22 refs.

  7. Evaluation of aquifer environment under Hazaribagh leather processing zone of Dhaka city

    Science.gov (United States)

    Zahid, Anwar; Balke, K.-D.; Hassan, M. Qumrul; Flegr, Matthias

    2006-07-01

    Hazaribagh is a densely populated area of Dhaka city where about 185 leather processing industries have been operating and discharging solid and liquid wastes directly to the low-lying areas, river and natural canals without proper treatment. The area is covered by alluvial deposits of Holocene age and is underlain by Pleistocene Madhupur clay. The Dupi Tila Formation of Mio-Pliocene age underlain by this yellowish gray to brick red clay bed serves as the main water-bearing aquifer of Dhaka city. To assess the environmental degradation as well as the groundwater environment, major anions, cations and heavy metals of water samples, heavy metals and organic carbon content of sediment samples were analyzed in this study. Analyses of tannery effluent detect high concentration of Na+, Mg2+, Cl- and SO{4/2-} followed by Ca2+, NH{4/+} and K+ with remarkable contents of some trace elements, mainly Cr, Fe, Mn, S, Ni and Pb. Higher accumulations of Cr, Al and Fe are observed in topsoil samples with significant amounts of Mn, Zn, Ni and Cu. Concentrations of ions and all the investigated trace elements of sampled groundwater were within the maximum allowable limit for drinking water of the Department of Environment, Bangladesh (DoE), and World Health Organization (WHO). However, excessive concentrations of Cr, Pb, etc., have already been reported in the shallow groundwater (10-20 m) of the area. Due to excessive withdrawal the vulnerability of groundwater contamination in deeper parts cannot be avoided for the future.

  8. Aluminothermic reduction of Cr2O3 contained in the ash of thermally treated leather waste

    Directory of Open Access Journals (Sweden)

    B. M. Wenzel

    2013-03-01

    Full Text Available In this study the viability of utilising ashes with high chromium oxide content, obtained by thermal treatment of footwear leather waste, in the production of low-carbon ferrochromium alloy (Fe-Cr-LC by aluminothermic reduction was investigated. The following key-factors were selected for process modelling: the quantity of aluminium (Al employed in the reaction, the iron amount added, the iron compound (Fe and/or Fe2O3 used, and the chromic acid addition. The process was investigated using a 2(4 full factorial design where the percentage of Cr2O3 reduced was used as the response. Variance analysis was employed to determine the significant effects and to validate the obtained model. The model was useful for finding the optimal operating conditions, including the maximisation of chromium conversion and the gross margin. Both resulted in similar process conditions, with 76.8±12.3% of chromium being reduced to the metallic phase, and 1.65±0.52 USD (kg ash-1 as the gross margin. The qualities of some alloys obtained were investigated by scanning electron microscopy coupled with energy dispersive X-ray spectroscopy analysis (SEM/EDS. The results showed that the main problem for these alloys in a standard specification was the P and S content, suggesting that a pre-treatment is required.

  9. In snow's footsteps: Commentary on shoe-leather and applied epidemiology.

    Science.gov (United States)

    Koo, Denise; Thacker, Stephen B

    2010-09-15

    The term shoe-leather epidemiology is often synonymous with field epidemiology or intervention epidemiology. All 3 terms imply investigations initiated in response to urgent public health problems and for which the investigative team does much of its work in the field (i.e., outside the office or laboratory). Alexander D. Langmuir is credited with articulating the concept of disease surveillance as it is applied to populations rather than individuals. He also founded the Epidemic Intelligence Service (EIS) Program in 1951, a 2-year training experience in applied epidemiology that places professionals in the field, domestically and internationally, in real-life situations. Today, 70-90 EIS officers are assigned each year to Centers for Disease Control and Prevention programs and to state and local health departments to meet the broad spectrum of challenges in chronic disease, injury prevention, violence, environmental health, occupational safety and health, and maternal and child health, as well as infectious diseases. Throughout their assignments, EIS officers are encouraged to strive for analytic rigor as well as public health consequence, which requires technical competence blended with good judgment and awareness of context. Effective applied epidemiologists must have skills beyond just epidemiology to improve a population's health; the field of applied epidemiology requires multiple team members, all having different but complementary skills, to be effective.

  10. The effects of drying conditions on moisture transfer and quality of pomegranate fruit leather (pestil

    Directory of Open Access Journals (Sweden)

    Fatih Mehmet Yılmaz

    2017-01-01

    Full Text Available Vacuum, cabinet and open air drying of pomegranate fruit leather were carried out at various drying conditions to monitor the drying kinetics together with bionutrient degradation of the product. Drying curves exhibited first order drying kinetics and effective moisture diffusivity values varied between 3.1 × 10−9 and 52.6 × 10−9 m2/s. The temperature dependence of the effective moisture diffusivity was satisfactorily described by an Arrhenius-type relationship. Drying conditions, product thickness and operation temperature had various effects on drying rate and final quality of the product. In terms of drying kinetics and final quality of product, vacuum drying had higher drying rate with higher conservation of phenolic, anthocyanin and ascorbic acid that is connected to faster drying condition and oxygen deficient medium. Anthocyanin content was significantly affected by drying method, drying temperature and product thickness. Scatter plot using principle component analysis enabled better understanding of moisture transfer rate and anthocyanin change under various drying conditions.

  11. The assembly of C. elegans lamins into macroscopic fibers.

    Science.gov (United States)

    Zingerman-Koladko, Irena; Khayat, Maayan; Harapin, Jan; Shoseyov, Oded; Gruenbaum, Yosef; Salman, Ahmad; Medalia, Ohad; Ben-Harush, Kfir

    2016-10-01

    Intermediate filament (IF) proteins are known mainly by their propensity to form viscoelastic filamentous networks within cells. In addition, IF-proteins are essential parts of various biological materials, such as horn and hagfish slime threads, which exhibit a range of mechanical properties from hard to elastic. These properties and their self-assembly nature made IF-proteins attractive building blocks for biomimetic and biological materials in diverse applications. Here we show that a type V IF-protein, the Caenorhabditis elegans nuclear lamin (Ce-lamin), is a promising building block for protein-based fibers. Electron cryo-tomography of vitrified sections enabled us to depict the higher ordered assembly of the Ce-lamin into macroscopic fibers through the creation of paracrystalline fibers, which are prominent in vitro structures of lamins. The lamin fibers respond to tensile force as other IF-protein-based fibers, i.e., hagfish slime threads, and possess unique mechanical properties that may potentially be used in certain applications. The self-assembly nature of lamin proteins into a filamentous structure, which is further assembled into a complex network, can be easily modulated. This knowledge may lead to a better understanding of the relationship in IF-proteins-based fibers and materials, between their hierarchical structures and their mechanical properties.

  12. The effect of lamination angle on polymer retention

    Energy Technology Data Exchange (ETDEWEB)

    Gao, H.W.

    1992-09-01

    Polymer retention may be affected by the reservoir geological structure due to lamination of the mineral surfaces. These laminae are very prevalent in Class I reservoirs. To account for the effect of lamination angle on polymer retention, several corefloods with three fired, rectangular, Berea sandstone cores were conducted. The three cores were cut at three different angles, 0, 30, and 90 degrees, with respect to the direction of laminations. A multiple slug retention method was used to determine the retention of a biopolymer in each core. Tracer tests were conducted before and after the biopolymer flow to determine how the retained biopolymer affected the fluid advance. A computed tomography (CT) scanning method was used to monitor the advance of the tracer. All corefloods and tracer tests were conducted at low flow rates similar to that in reservoirs. Coreflood tests revealed that polymer retention, which was mainly caused by mechanical entrapment, was higher in cores that had laminations parallel to the direction of flow than in cores that had crossbed laminae. In cores that had crossbed laminae, polymer retention increased with an increase in the lamination angle. Retained polymer is harmful to the stability of fluid front in cores that have laminations parallel to the direction of flow, but is helpful in cores that have crossbed laminae.

  13. Coupled actin-lamin biopolymer networks and protecting DNA

    Science.gov (United States)

    Zhang, Tao; Rocklin, D. Zeb; Mao, Xiaoming; Schwarz, J. M.

    The mechanical properties of cells are largely determined by networks of semiflexible biopolymers forming the cytoskeleton. Similarly, the mechanical properties of cell nuclei are also largely determined by networks of semiflexible biopolymers forming the nuclear cytoskeleton. In particular, a network of filamentous lamin sits just inside the inner nuclear membrane to presumably protect the heart of the cell nucleus--the DNA. It has been demonstrated over the past decade that the actin cytoskeletal biopolymer network and the lamin biopolymer network are coupled via a sequence of proteins bridging the outer and inner nuclear membranes, known as the LINC complex. We, therefore, probe the consequences of such a coupling in a model biopolymer network system via numerical simulations to understand the resulting deformations in the lamin network in response to perturbations in the actin cytoskeletal network. We find, for example, that the force transmission across the coupled system can depend sensitively on the concentration of LINC complexes. Such study could have implications for mechanical mechanisms of the regulation of transcription since DNA couples to lamin via lamin-binding domains so that deformations in the lamin network may result in deformations in the DNA.

  14. BioID Identification of Lamin-Associated Proteins.

    Science.gov (United States)

    Mehus, Aaron A; Anderson, Ruthellen H; Roux, Kyle J

    2016-01-01

    A- and B-type lamins support the nuclear envelope, contribute to heterochromatin organization, and regulate a myriad of nuclear processes. The mechanisms by which lamins function in different cell types and the mechanisms by which lamin mutations cause over a dozen human diseases (laminopathies) remain unclear. The identification of proteins associated with lamins is likely to provide fundamental insight into these mechanisms. BioID (proximity-dependent biotin identification) is a unique and powerful method for identifying protein-protein and proximity-based interactions in living cells. BioID utilizes a mutant biotin ligase from bacteria that is fused to a protein of interest (bait). When expressed in living cells and stimulated with excess biotin, this BioID-fusion protein promiscuously biotinylates directly interacting and vicinal endogenous proteins. Following biotin-affinity capture, the biotinylated proteins can be identified using mass spectrometry. BioID thus enables screening for physiologically relevant protein associations that occur over time in living cells. BioID is applicable to insoluble proteins such as lamins that are often refractory to study by other methods and can identify weak and/or transient interactions. We discuss the use of BioID to elucidate novel lamin-interacting proteins and its applications in a broad range of biological systems, and provide detailed protocols to guide new applications.

  15. Ceramic laminates with tailored residual stresses

    Directory of Open Access Journals (Sweden)

    Baudín, C.

    2009-12-01

    Full Text Available Severe environments imposed by new technologies demand new materials with better properties and ensured reliability. The intrinsic brittleness of ceramics has forced scientists to look for new materials and processing routes to improve the mechanical behaviour of ceramics in order to allow their use under severe thermomechanical conditions. The laminate approach has allowed the fabrication of a new family of composite materials with strength and reliability superior to those of monolithic ceramics with microstructures similar to those of the constituent layers. The different ceramic laminates developed since the middle 1970´s can be divided in two large groups depending on whether the development of residual stresses between layers is the main design tool. This paper reviews the developments in the control and tailoring of residual stresses in ceramic laminates. The tailoring of the thickness and location of layers in compression can lead to extremely performing structures in terms of strength values and reliability. External layers in compression lead to the strengthening of the structure. When relatively thin and highly compressed layers are located inside the material, threshold strength, crack bifurcation and crack arrest during fracture occur.

    Las severas condiciones de trabajo de las nuevas aplicaciones tecnológicas exigen el uso de materiales con mejores propiedades y alta fiabilidad. La potencialidad de uso de materiales frágiles, como los cerámicos, en estas aplicaciones exige el desarrollo de nuevos materiales y métodos de procesamiento que mejoren su comportamiento mecánico. El concepto de material laminado ha permitido la fabricación de una nueva familia de materiales con tensiones de fractura y fiabilidad superiores a las de materiales monolíticos con microestructuras similares a las de las láminas que conforman el laminado. Los distintos materiales laminados desarrollados desde mediados de los años 70 se pueden

  16. Snobs & clowns: Northamptonshire on film 1932-1989 [DVD

    OpenAIRE

    Wilczek, Emily

    2012-01-01

    Northamptonshire is well known for its shoemaking industry which grew from the rich local countryside that provided cattle for leather manufacturing. The importance of rural life in the county of “spires and squires” is shown in many of the films in this DVD compilation, from home movies made on a farm in the 1940s, to a thrilling aerial view of the county aboard a plane in 1964. Snobs and Clowns*, researched and edited by Emily Wilczek from the University of Lincoln’s School of Media, ch...

  17. Shape and vibration control of active laminated plates for RF and optical applications

    Science.gov (United States)

    Punhani, Amitesh; Washington, Gregory N.

    2006-03-01

    Active shape and vibration control of large structures have long been desired for many practical applications. PVDF being one of the most suitable materials for these applications due to its strong piezoelectric properties and availability in thin sheets has been the focal point of most researchers in this area. Most of the research has been done to find an open loop solution, which would be able to shape the structure as per the desired requirements in an ideal atmosphere. Unmodeled dynamics and external disturbances prevent the open loop (no feedback) solution from achieving the desired shape. This research develops a dynamic model of a laminated plate consisting of two layers of PVDF film joined with a layer of epoxy. The orthotropic properties of PVDF have been modeled and the epoxy layer is considered to be isotropic. A general control model is developed, which would work for most boundary conditions and developed for a simply supported beam with patch actuators. The methodology is then extended for a simply supported laminated plate. This model could be used for real time dynamic disturbance rejection and shape and vibration control of the structure.

  18. STUDY ON THE TENSILE FATIGUE DAMAGE OF QUASI-ISOTROPIC COMPOSITE LAMINATES

    Institute of Scientific and Technical Information of China (English)

    I.G.Kim; I.S.Kim; O.S.Kim; Yaragarra K.D.V. Prasad4

    2003-01-01

    Quasi-isotropic laminates have isotropic elastic properties in all in-plane directions.Therefore, this kind of laminate is widely used for structural elements. The simpleststacking sequence of quasi-isotropic laminates is [0/-60/60]s. When the direction ofapplied axial load to [0/-60/60]s laminate is inclined at a 30-degree angle, we havethe other quasi-isotropic laminate [30/-30/90]s under axial load. The failure mecha-nisms of these two laminates are, however, entirely different from each other becausethese two laminates have different distribution of the interlaminar stresses. It wasconfirmed by tensile fatigue tests that the [0/-60/60]s laminate does not show any vis-ible fatigue damage, but the [30/-30/90]s laminate develops edge-delamination duringcyclic loading. The analytical results were in good agreement with the experimental results.

  19. The impact properties of laminated composites containing ultrahigh carbon (UHC) steels

    Science.gov (United States)

    Kum, D. W.; Oyama, T.; Wadsworth, J.; Sherby, O. D.

    AN ULTRAHIGH carbon (UHC) steel/mild steel laminated composite and a UHC steel/UHC steel laminate have been successfully manufactured by a roll-bonding procedure. Impact properties of these laminates, as well as of monolithic samples of the steels contained in these laminates, have been determined in the crackarrestor orientation over the temperature range 25 to -196°C. Both notched and unnotched samples of the laminated composite and laminate have been tested. Extremely low ductile-to-brittle temperatures of -140°C, and very high shelf energies (>325 J), have been found both for the laminated composites and the laminates. This remarkably good behavior is shown to be a result of notch blunting by delamination within the laminates.

  20. A transparent conductive adhesive laminate electrode for high-efficiency organic-inorganic lead halide perovskite solar cells.

    Science.gov (United States)

    Bryant, Daniel; Greenwood, Peter; Troughton, Joel; Wijdekop, Maarten; Carnie, Mathew; Davies, Matthew; Wojciechowski, Konrad; Snaith, Henry J; Watson, Trystan; Worsley, David

    2014-11-26

    A self-adhesive laminate solar-cell electrode is presented based on a metal grid embedded in a polymer film (x-y conduction) and set in contact with the active layer using a pressure-sensitive adhesive containing a very low quantity (1.8%) of organic conductor, which self-organizes to provide z conduction to the grid. This ITO-free material performs in an identical fashion to evaporated gold in high-efficiency perovskite solar cells. © 2014 The Authors. Published by WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  1. Crush testing, characterizing, and modeling the crashworthiness of composite laminates

    Science.gov (United States)

    Garner, David Michael, Jr.

    Research in the field of crashworthiness of composite materials is presented. A new crush test method was produced to characterize the crush behavior of composite laminates. In addition, a model of the crush behavior and a method for rank ordering the energy absorption capability of various laminates were developed. The new crush test method was used for evaluating the crush behavior of flat carbon/epoxy composite specimens at quasi-static and dynamic rates. The University of Utah crush test fixture was designed to support the flat specimen against catastrophic buckling. A gap, where the specimen is unsupported, allowed unhindered crushing of the specimen. In addition, the specimen's failure modes could be clearly observed during crush testing. Extensive crush testing was conducted wherein the crush force and displacement data were collected to calculate the energy absorption, and high speed video was captured during dynamic testing. Crush tests were also performed over a range of fixture gap heights. The basic failure modes were buckling, crack growth, and fracture. Gap height variations resulted in poorly, properly, and overly constrained specimens. In addition, guidelines for designing a composite laminate for crashworthiness were developed. Modeling of the crush behavior consisted of the delamination and fracture of a single ply or group of like plies during crushing. Delamination crack extension was modeled using the mode I energy release rate, G lc, where an elastica approach was used to obtain the strain energy. Variations in Glc were briefly explored with double cantilever beam tests wherein crack extension occurred along a multidirectional ply interface. The model correctly predicted the failure modes for most of the test cases, and offered insight into how the input parameters affect the model. The ranking method related coefficients of the laminate and sublaminate stiffness matrices, the ply locations within the laminate, and the laminate thickness. The

  2. 基于GC-MS对皮革特征气味的分析与模拟%Leather Odors Analysis by GC- MS and Simulation

    Institute of Scientific and Technical Information of China (English)

    胡静; 肖作兵; 邓维钧; 刘万龙; 刘佳颖

    2012-01-01

    采用索氏提取法对不同种类皮革中的挥发性成分进行提取,结合气相色谱一质谱联用技术(GC-MS)分析其挥发性物质的主要组成。根据GC-MS测定结果,通过感官分析模拟具有皮革特征气味的香精。结果表明:未涂饰羊服装革、涂饰羊服装革、涂饰牛服装革和涂饰牛汽车坐垫革的特征气味中,挥发性物质种类繁多,包含烃类、酯类、醛类、酸类、醚类和酮类化合物,以烃类物质为主。根据GC-MS分析结果,结合调香实践经验,调配出香气饱满、逼真、协调的皮革特征气味的香精。%The volatile organic components of different leathers were extracted by Soxhlet extraction and determined with gas chromatography and mass spectrometry ( GC - MS). The leather fragrance was simulated by the sensor analysis based on the GC - MS results. The results show that there are many volatile organic components in the ordour of the unfinished arid finished sheep garment leathers, cow garment leather and cow ear seat leather. These components are hydrocarbons, esters, aldehydes, acids, aethers and ketones, etc. Based on the GC - MS results, the leather fragrance is further prepared.

  3. The Use Level of Chrome Tannage For Rabbit Fur Leather Observed on Tearing Strength, Stitch Tearing Strength, Water Absorption and Organoleptic

    Directory of Open Access Journals (Sweden)

    Mustakim Mustakim

    2012-02-01

    Full Text Available The purpose of this study was to find out the appropiate of chrome tannage level for rabbit fur leather quality. The result were expected to contribute information for many people who relate with tanning technology, especialy about the use level of chrome tannage for fur leather quality and could as patern to hold further research.The material that used were 12 pieces of three months of rabbit skin. The method is Completely Randomized Design, consist of three treatments of chrome tannage (Chromosal B, they were : B1 (Chromosal B 6%, B2 (Chromosal B 8%, and B3 (Chromosal B 10%. Each of treatment hold on four replications. The variables which measured are tearing strength, stitch teraing strength, water absorption and organoleptic consist of “kekuatan bulu”’ “kerataan bulu” and “kelemasan kulit” in fur leather. Data was analysed by analysis variance followed by Duncan’s Multiple Range Test. The result of this research show that the use level of chromosal B give very significant influence among tearing strength, stitch tearing strength and water absorption. It gave significant influence among the organoleptic test. Based on the result, can be concluded that 10 percent of chrome tannage (chromosal B, produce the best result on tearing strength, stitch tearing strength, water absorption and organoleptic for “kekuatan bulu” and “kerataan bulu”. The incrase of chrome tannage offer will decrease the “kelemasan kulit” in fur leather and the best “kelemasan kulit” produced by the lowest chrome tannage offer, that was 6 percent of Chromosal B. The best quality of rabbit fur leather produced by 10 percent of chrome tannage offer.   Keywords: chrome, tannage, fur leather

  4. Application of wide-angle scattering techniques using microfocus X-ray beam to investigate structural variation in polymer laminates

    Energy Technology Data Exchange (ETDEWEB)

    Bhagat, R

    1999-09-01

    Experiments have been conducted at the European Synchrotron Radiation Facility (ESRF) at Grenoble (France). The Synchrotron Radiation used provides a monochromatic X-ray beam with brilliance and flux density far greater than is attainable with a rotating anode laboratory source. In addition the glass capillary optics used, increases the flux density at the capillary exit as well as providing a sub-micron beam which coupled with the XYZ stage allows data to be collected at high spatial resolution. A Photonics Science CCD detector coupled to a frame grabber has permitted data to be collected at high temporal resolution (40ms) as well as displaying the data in real-time mode. Software used during analysis was used to reduce the amount of spurious signals due to background scatter as well as enable results to be calculated with a high degree of confidence. The aim of this research was to investigate the effect of industrial processing parameters in production of PET laminates and PEN films. Wide Angle X-ray Scattering (WAXS) patterns have been collected, using a beam size of 2.3 {mu}m at intervals of 1 {mu}m through the sample. Crystallite sizeand orientation analyses on patterns collected have been used as an indication of changes in the structural morphology through the thickness of the films. Data analyses of PET films show that biaxial stretching of films is very complex and depending on the parameters at each stage of the process, the final film has very different characteristics. It has been shown that the effects of draw ratio and draw temperature in the forward direction results in a range of crystallite sizes that lead to either crystal fracture or reorientation of the crystallites as the dominant process in the transverse draw. The effects of annealing can also lead to crystal welding or melting and re-crystallisation depending on the amount of time spent in the lamination process. Data analyses of PEN films show that the choice of parameters in biaxial

  5. Epidemiological investigation of an outbreak of acute diarrheal disease: A shoe leather epidemiology

    Directory of Open Access Journals (Sweden)

    Sandip Bharat Patil

    2011-01-01

    Full Text Available Background: Health care problems faced by migrant construction workers are always neglected. Fifteen patients were admitted with the complaints of loose motion and pain in the abdomen from a labor settlement at a construction site near our city. Three stool samples revealed darting motility. Objectives: To find out more number of cases, the source of infection and to recommend necessary actions to control the outbreak. Study Design: A cross-sectional epidemiological study. Materials and Methods: Pre-tested, pre-designed epidemiological case sheet was used. Sanitary survey and assessment of ecological correlation was also done. Stool samples of all the admitted patients and seven water samples from the site were collected for laboratory analysis. Results: Out of 99 inhabitants, 69 were suffering from the same complaints. Male sufferers were more in number. The age groups affected prominently were 1-4 years and 15-44 years. Peculiar epidemic curve with one peak was noted down. There was a history of heavy rains 2 days before the complaints had started. The construction site was situated on the plateau. The source of the water - dug well - was situated on a slope. The water from the site while moving along the slope was getting mixed into the well. Considering the person, time, place distribution and the peculiar symptoms, presumptive diagnosis of outbreak (point source of acute gastroenteritis was made. The well water was thought to be the source of infection. Three stool samples and three water samples including the sample from drinking well water grew Vibrio cholerae O1. These results support an earlier hypothesis. The timely interventions were done. Conclusion: The impending outbreak can be brought under control with the rapid and simple field epidemiological investigation (shoe leather epidemiology.

  6. Ozonation-based decolorization of food dyes for recovery of fruit leather wastes.

    Science.gov (United States)

    Zhu, Wenda; Koziel, Jacek A; Cai, Lingshuang; Brehm-Stecher, Byron F; Ozsoy, H Duygu; van Leeuwen, J Hans

    2013-08-28

    Commercial manufacture of fruit leathers (FL) usually results in a portion of the product that is out of specification. The disposition of this material poses special challenges in the food industry. Because the material remains edible and contains valuable ingredients (fruit pulp, sugars, acidulates, etc.), an ideal solution would be to recover this material for product rework. A key practical obstacle to such recovery is that compositing of differently colored wastes results in an unsalable gray product. Therefore, a safe and scalable method for decolorization of FL prior to product rework is needed. This research introduces a novel approach utilizing ozonation for color removal. To explore the use of ozonation as a decolorization step, we first applied it to simple solutions of the commonly used food colorants 2-naphthalenesulfonic acid (Red 40), tartrazine (Yellow 5), and erioglaucine (Blue 1). Decolorization was measured by UV/vis spectrometry at visible wavelengths and with a Hunter colorimeter. Volatile and semivolatile byproducts from ozone-based colorant decomposition were identified and quantified with solid phase microextraction coupled with gas chromatography-mass spectrometry (SPME-GC-MS). Removal of Yellow 5, Red 40 and Blue 1 of about 65%, 80%, and 90%, respectively, was accomplished with 70 g of ozone applied per 1 kg of redissolved and resuspended FL. Carbonyl compounds were identified as major byproducts from ozone-induced decomposition of the food colorants. A conservative risk assessment based on quantification results and published toxicity information of potentially toxic byproducts, determined that ozone-based decolorization of FL before recycling is acceptable from a safety standpoint. A preliminary cost estimate based on recycling of 1000 tons of FL annually suggests a potential of $275,000 annual profit from this practice at one production facility alone.

  7. Electrochemical treatment of evaporated residue of soak liquor generated from leather industry

    Energy Technology Data Exchange (ETDEWEB)

    Boopathy, R.; Sekaran, G., E-mail: ganesansekaran@gmail.com

    2013-09-15

    Highlights: • Electrochemical treatment of evaporated residue of soak liquor (ERSL) generated in Tannery. • Copper coating on electrode surface and horizontal mounting of electrodes for ERSL treatment. • Electrochemical oxidation of organic pollutants under high saline condition. • The treated solution may be evaporated to dryness to get NaCl salt for hide/skin preservation. -- Abstract: The organic and suspended solids present in soak liquor, generated from leather industry, demands treatment. The soak liquor is being segregated and evaporated in solar evaporation pans/multiple effect evaporator due to non availability of viable technology for its treatment. The residue left behind in the pans/evaporator does not carry any reuse value and also faces disposal threat due to the presence of high concentration of sodium chloride, organic and bacterial impurities. In the present investigation, the aqueous evaporated residue of soak liquor (ERSL) was treated by electrochemical oxidation. Graphite/graphite and SS304/graphite systems were used in electrochemical oxidation of organics in ERSL. Among these, graphite/graphite system was found to be effective over SS304/graphite system. Hence, the optimised conditions for the electrochemical oxidation of organics in ERSL using graphite/graphite system was evaluated by response surface methodology (RSM). The mass transport coefficient (k{sub m}) was calculated based on pseudo-first order rate kinetics for both the electrode systems (graphite/graphite and SS304/graphite). The thermodynamic properties illustrated the electrochemical oxidation was exothermic and non-spontaneous in nature. The calculated specific energy consumption at the optimum current density of 50 mA cm{sup −2} was 0.41 kWh m{sup −3} for the removal of COD and 2.57 kWh m{sup −3} for the removal of TKN.

  8. Full-scale co-composting of hair wastes from the leather manufacturing industry and sewage sludge

    OpenAIRE

    Barrena Gómez, Raquel; Pagans i Miró, Estel·la; Vázquez Lima, Felícitas; Artola Casacuberta, Adriana; Sánchez Ferrer, Antoni

    2007-01-01

    A full-scale cocomposting experiment using hair wastes from the leather manufacturing industry and sewage sludge as cosubstrates was carried out with the aim of producing compost that may be used as an organic amendment in agriculture. A 1:1 weight ratio of hair wastes and sewage sludge was used based on experiments at smaller-scale. The resulting mixture was then amended with pruning wastes acting as bulking agent in a 1:1 volumetric ratio (mixture:pruning wastes). The experiment was carried...

  9. 制革脱毛工艺的研究进展%Developing Research on Unhairing Process in Leather Manufacture

    Institute of Scientific and Technical Information of China (English)

    陶亮亮; 达超超; 马雄; 赵亚洲

    2012-01-01

    The unhairing process and traditional hair removal methods in leather manufacture were described. The application and the latest development of the cleaner unhairing technology were reviewed, including enzymatic removal method, the hair-saving method, depilate materials circulation and oxidation method.%介绍了制革生产过程中脱毛工艺和传统的脱毛方法,综述了酶脱毛法、保毛脱毛法、脱毛材料循环法、氧化脱毛等清洁脱毛方法的研究进展及应用。

  10. The Ecological Aspects of Leather Manufacture(to be continued)%制革生态学(续一)

    Institute of Scientific and Technical Information of China (English)

    GerhardWolf; BrigitteWegner

    2003-01-01

    @@ 1 Beamhouse 1.1 Soaking and liming 1.1.1 Soaking and liming auxiliaries The work performed in the beamhouse has a decisive effect on the quality of the finished leather. The tasks here are to remove the hair and to prepare the skin for tanning. At BASF, we have developed a range of auxiliaries for use in soaking and liming processes. They help to speed up these processes, and they produce very clean, smooth pelts with an open fiber structure, which respond very well to further processing.

  11. COST REDUCTION STUDIES OF DECORATIVE LAMINATES

    Directory of Open Access Journals (Sweden)

    Dharm Dutt

    2011-03-01

    Full Text Available Barrier paper, which is made of bleached absorbent kraft pulp, is a significant layer of decorative laminates, since it controls the see-through of brown color of saturating kraft paper and its opacifying effect usually is achieved by a heavy loading of TiO2. The TiO2, due to its very small particle size, passes between the cellulosic fibers and drains into the white water. To overcome this problem, papermakers try to use various retention aids for improving overall retention of TiO2, but agglomeration of TiO2 causes a decrease in light scattering efficiency of TiO2. During the subsequent saturation operation, the air in the voids is replaced by melamine formaldehyde, which has a refractive index close to that of cellulose. As a result, the sheet becomes translucent and poses 'see through' problem. Keeping this in view, anhydrous magnesium silicate is used as an extender with TiO2 because it effectively increases the overall filler retention, sheet brightness, opacity. The dispersed aqueous slurry of anhydrous magnesium silicate forms fine gel that entraps TiO2 in the wet web and prevents removal of fines and fillers. The addition of 25% TiO2, 7% micronized soapstone powder, 8% anhydrous magnesium silicate, 1% melamine formaldehyde, and 0.1% sodium hexameta-phosphate was found to improve the overall retention by 65.25% and to cut the manufacturing cost by US$ 546.00 per tonne of pulp without affecting the product quality.

  12. Analytical study for deformability of laminated sheet metal

    Directory of Open Access Journals (Sweden)

    Mohammed H. Serror

    2013-01-01

    Full Text Available While a freestanding high-strength sheet metal subject to tension will rupture at a small strain, it is anticipated that lamination with a ductile sheet metal will retard this instability to an extent that depends on the relative thickness, the relative stiffness, and the hardening exponent of the ductile sheet. This paper presents an analytical study for the deformability of such laminate within the context of necking instability. Laminates of high-strength sheet metal and ductile low-strength sheet metal are studied assuming: (1 sheets are fully bonded; and (2 metals obey the power law material model. The effect of hardening exponent, volume fraction and relative stiffness of the ductile component has been studied. In addition, stability of both uniform and nonuniform deformations has been investigated under plane strain condition. The results have shown the retardation of the high-strength layer instability by lamination with the ductile layer. This has been achieved through controlling the aforementioned key parameters of the ductile component, while the laminate exhibits marked enhancement in strength–ductility combination that is essential for metal forming applications.

  13. Glucocorticoid-induced laminitis with hepatopathy in a Thoroughbred filly.

    Science.gov (United States)

    Ryu, Seung Ho; Kim, Byung Sun; Lee, Chang Woo; Yoon, Junghee; Lee, Yonghoon Lyon

    2004-09-01

    A 3-year-old Thoroughbred filly was referred to the Equine Hospital, Korea Racing Association for evaluation of hematuria, inappetite, weight loss and depression. From 25 days prior to admission, the horse was treated for right carpal lameness with 20 mg intramuscular administration of triamcinolone acetonide per day for consecutive 10 days by a local veterinarian. Clinical and laboratory findings included vaginal hyperemia, flare in bladder wall, neutrophilia, lymphopenia, polyuria, polydipsia and laminitis in the end. High activities of aspartate transaminase and gamma glutamyltransferase and high concentration of total bilirubin indicated hepatopathy. Further hematology, serum biochemistry and urinalysis did not reveal any abnormalities. Medical history, physical and clinicopathologic findings suggest that the laminitis and hepatopathy in this horse were most likely induced by repeated administration of exogenous corticosteroid. However, guarded prognosis of treating laminitis undermined the benefit of improvement of hematuria following electroacupuncture stimulation. The combined stimulation of kidney related acupoints (Shen Peng, Shen Shu), lumber related acupoints (Yao Qian, Yao Zhong) and associate acupoints (Guan Yuan Shu, Bai Hui) at 5Hz, 1-2V, for 40 minutes was of value in the treatment of hematuria. This case shows that horses under steroids may exhibit laminitis and steroid hepatopathy. Early recognition and good management of laminitis are important in the limitation of complications.

  14. Tunable characteristics of bending resonance frequency in magnetoelectric laminated composites

    Institute of Scientific and Technical Information of China (English)

    Chen Lei; Li Ping; Wen Yu-Mei; Zhu Yong

    2013-01-01

    As the magnetoelectric (ME) effect in piezoelectric/magnetostrictive laminated composites is mediated by mechanical deformation,the ME effect is significantly enhanced in the vicinity of resonance frequency.The bending resonance frequency (fr) of bilayered Terfenol-D/PZT (MP) laminated composites is studied,and our analysis predicts that (i) the bending resonance frequency of an MP laminated composite can be tuned by an applied dc magnetic bias (Hdc) due to the △E effect; (ii) the bending resonance frequency of the MP laminated composite can be controlled by incorporating FeCuNbSiB layers with different thicknesses.The experimental results show that with Hdc increasing from 0Oe (1 Oe=79.5775 A/m)to 700 Oe,the bending resonance frequency can be shifted in a range of 32.68 kHz ≤ fr ≤ 33.96 kHz.In addition,with the thickness of the FeCuNbSiB layer increasing from 0 μm to 90 μm,the bending resonance frequency of the MP laminated composite gradually increases from 33.66 kHz to 39.18 kHz.This study offers a method of adjusting the strength of dc magnetic bias or the thicknesses of the FeCuNbSiB layer to tune the bending resonance frequency for ME composite,which plays a guiding role in the ME composite design for real applications.

  15. Development of solid state thick film zirconia oxygen gas sensors.

    OpenAIRE

    Ioannou, Andreas Stylianou

    1992-01-01

    Aspects relating to and including the development of thick film amperometric zirconia oxygen sensors were investigated. These devices, which were operated in the range 550-950°C, had a laminated structure in which a cathode, an electrolyte and an anode were printed, in that order, onto a planar alumina substrate. The anode and electrolyte were porous and during sensor Operation also acted as a diffusion barrier, restricting the rate of oxygen diffusion to the cathode. A thick film platinum he...

  16. 人造革和合成革中的邻苯二甲酸酯类增塑剂含量的检测方法研究%Determination of Phthalate Ester Plasticizer in Artificial Leather and Synthetic Leather

    Institute of Scientific and Technical Information of China (English)

    易碧华; 李天宝; 叶林; 李昊菁

    2012-01-01

    Phthalate ester plasticizer in artificial leather and synthetic leather was extracted by uhrasinic extraction method with hexane as the solvent, then the samples were purified by solid phase extraction (SPE), and finnally the phthalate content was determined and confirmend by gas chromatograph-mass se- lection detector (GC-MSD). The results indicated that the method was precise and reliable. This method provided recovery ratio of 90%, relative standard deviation of 5% and can meet the requirements of test,%采用超声波提取法,以正己烷为溶剂提取人造革合成革中的邻苯二甲酸酯类增塑剂。用固相萃取方法(sPE)净化样品,用GC-MS法测定人造革合成革中的邻苯二甲酸酯类增塑剂含量,外标法定量,选择离子检测进行阳性确证。实验表明:该方法快速准确可靠,重现性好,平均回收率达90%以上,相对偏差小于5%.可满足试验的要求。

  17. Flexible composite film for printed circuit board

    Science.gov (United States)

    Yabe, K.; Asakura, M.; Tanaka, H.; Soda, A.

    1982-01-01

    A flexible printed circuit for a printed circuit board in which layers of reaction product composed of a combination of phenoxy resin - polyisocyanate - brominated epoxy resin, and in which the equivalent ratio of those functional groups is hydroxyl group: isocyanate group: epoxy group - 1 : 0.2 to 2 : 0.5 to 3 are laminated on at least one side of saturated polyester film is discussed.

  18. 40 CFR 426.70 - Applicability; description of the automotive glass laminating subcategory.

    Science.gov (United States)

    2010-07-01

    ... automotive glass laminating subcategory. 426.70 Section 426.70 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) EFFLUENT GUIDELINES AND STANDARDS GLASS MANUFACTURING POINT SOURCE CATEGORY Automotive Glass Laminating Subcategory § 426.70 Applicability; description of the automotive...

  19. Cloning and Characterization of Sf9 Cell Lamin and the Lamin Conformational Changes during Autographa californica multiple nucleopolyhedrovirus Infection

    Directory of Open Access Journals (Sweden)

    Wenqiang Wei

    2016-05-01

    Full Text Available At present, the details of lamina alterations after baculovirus infection remain elusive. In this study, a lamin gene in the Sf9 cell line of Spodoptera frugiperda was cloned. The open reading frame (orf of the Sf9 lamin was 1860 bp and encoded a protein with a molecular weight of 70 kDa. A transfection assay with a red fluorescence protein (rfp-lamin fusion protein indicated that Sf9 lamin was localized in the nuclear rim. Transmission electron microscopy observations indicated that Autographa californica multiple nucleopolyhedrovirus (AcMNPV nucleocapsids may pass through the nuclear envelope. Immunofluorescence assay indicated that the lamina showed a ruffled staining pattern with the formation of invaginations in the Sf9 cells infected with AcMNPV, while it was evenly distributed at the nuclear periphery of mock-infected cells. Western blotting results indicated that the total amount of lamin in the baculovirus-infected Sf9 cells was significantly decreased compared with the mock-infected cells. These results imply that AcMNPV infection induces structural and biochemical rearrangements of lamina of Sf9 cells.

  20. Cloning and Characterization of Sf9 Cell Lamin and the Lamin Conformational Changes during Autographa californica multiple nucleopolyhedrovirus Infection.

    Science.gov (United States)

    Wei, Wenqiang; Wang, Hongju; Li, Xiaoya; Fang, Na; Yang, Shili; Liu, Hongyan; Kang, Xiaonan; Sun, Xiulian; Ji, Shaoping

    2016-05-07

    At present, the details of lamina alterations after baculovirus infection remain elusive. In this study, a lamin gene in the Sf9 cell line of Spodoptera frugiperda was cloned. The open reading frame (orf) of the Sf9 lamin was 1860 bp and encoded a protein with a molecular weight of 70 kDa. A transfection assay with a red fluorescence protein (rfp)-lamin fusion protein indicated that Sf9 lamin was localized in the nuclear rim. Transmission electron microscopy observations indicated that Autographa californica multiple nucleopolyhedrovirus (AcMNPV) nucleocapsids may pass through the nuclear envelope. Immunofluorescence assay indicated that the lamina showed a ruffled staining pattern with the formation of invaginations in the Sf9 cells infected with AcMNPV, while it was evenly distributed at the nuclear periphery of mock-infected cells. Western blotting results indicated that the total amount of lamin in the baculovirus-infected Sf9 cells was significantly decreased compared with the mock-infected cells. These results imply that AcMNPV infection induces structural and biochemical rearrangements of lamina of Sf9 cells.