Exploration of faint absorption bands in the reflectance spectra of the asteroids by method of optimal smoothing: Vestoids

Science.gov (United States)

Shestopalov, D. I.; McFadden, L. A.; Golubeva, L. F.

2007-04-01

An optimization method of smoothing noisy spectra was developed to investigate faint absorption bands in the visual spectral region of reflectance spectra of asteroids and the compositional information derived from their analysis. The smoothing algorithm is called "optimal" because the algorithm determines the best running box size to separate weak absorption bands from the noise. The method is tested for its sensitivity to identifying false features in the smoothed spectrum, and its correctness of forecasting real absorption bands was tested with artificial spectra simulating asteroid reflectance spectra. After validating the method we optimally smoothed 22 vestoid spectra from SMASS1 [Xu, Sh., Binzel, R.P., Burbine, T.H., Bus, S.J., 1995. Icarus 115, 1-35]. We show that the resulting bands are not telluric features. Interpretation of the absorption bands in the asteroid spectra was based on the spectral properties of both terrestrial and meteorite pyroxenes. The bands located near 480, 505, 530, and 550 nm we assigned to spin-forbidden crystal field bands of ferrous iron, whereas the bands near 570, 600, and 650 nm are attributed to the crystal field bands of trivalent chromium and/or ferric iron in low-calcium pyroxenes on the asteroids' surface. While not measured by microprobe analysis, Fe 3+ site occupancy can be measured with Mössbauer spectroscopy, and is seen in trace amounts in pyroxenes. We believe that trace amounts of Fe 3+ on vestoid surfaces may be due to oxidation from impacts by icy bodies. If that is the case, they should be ubiquitous in the asteroid belt wherever pyroxene absorptions are found. Pyroxene composition of four asteroids of our set is determined from the band position of absorptions at 505 and 1000 nm, implying that there can be orthopyroxenes in all range of ferruginosity on the vestoid surfaces. For the present we cannot unambiguously interpret of the faint absorption bands that are seen in the spectra of 4005 Dyagilev, 4038

Quantitative interpretations of Visible-NIR reflectance spectra of blood.

Science.gov (United States)

Serebrennikova, Yulia M; Smith, Jennifer M; Huffman, Debra E; Leparc, German F; García-Rubio, Luis H

2008-10-27

This paper illustrates the implementation of a new theoretical model for rapid quantitative analysis of the Vis-NIR diffuse reflectance spectra of blood cultures. This new model is based on the photon diffusion theory and Mie scattering theory that have been formulated to account for multiple scattering populations and absorptive components. This study stresses the significance of the thorough solution of the scattering and absorption problem in order to accurately resolve for optically relevant parameters of blood culture components. With advantages of being calibration-free and computationally fast, the new model has two basic requirements. First, wavelength-dependent refractive indices of the basic chemical constituents of blood culture components are needed. Second, multi-wavelength measurements or at least the measurements of characteristic wavelengths equal to the degrees of freedom, i.e. number of optically relevant parameters, of blood culture system are required. The blood culture analysis model was tested with a large number of diffuse reflectance spectra of blood culture samples characterized by an extensive range of the relevant parameters.

Visible and near-infrared (0.4-2.5 μm) reflectance spectra of playa evaporite minerals

Science.gov (United States)

Crowley, James K.

1991-01-01

Visible and near-infrared (VNIR; 0.4–2.4 μm) reflectance spectra were recorded for 35 saline minerals that represent the wide range of mineral and brine chemical compositions found in playa evaporite settings. The spectra show that many of the saline minerals exhibit diagnostic near-infrared absorption bands, chiefly attributable to vibrations of hydrogen-bonded structural water molecules. VNIR reflectance spectra can be used to detect minor hydrate phases present in mixtures dominated by anhydrous halite or thenardite, and therefore will be useful in combination with X ray diffraction data for characterizing natural saline mineral assemblages. In addition, VNIR reflectance spectra are sensitive to differences in sample hydration state and should facilitate in situ studies of minerals that occur as fragile, transitory dehydration products in natural salt crusts. The use of spectral reflectance measurements in playa studies should aid in mapping evaporite mineral distributions and may provide insight into the geochemical and hydrological controls on playa mineral and brine development.

Quantum synchrotron spectra from semirelativistic electrons in teragauss magnetic fields

International Nuclear Information System (INIS)

Brainerd, J.J.

1987-01-01

Synchrotron spectra are calculated from quantum electrodynamic transition rates for thermal and power-law electron distributions. It is shown that quantum effects appear in thermal spectra when the photon energy is greater than the electron temperature, and in power-law spectra when the electron energy in units of the electron rest mass times the magnetic field strength in units of the critical field strength is of order unity. These spectra are compared with spectra calculated from the ultrarelativistic approximation for synchrotron emission. It is found that the approximation for the power-law spectra is good, and the approximation for thermal spectra produces the shape of the spectrum accurately but fails to give the correct normalization. Single photon pair creation masks the quantum effects for power-law distributions, so only modifications to thermal spectra are important for gamma-ray bursts. 13 references

Observations of discrete energy loss effects in spectra of positrons reflected from solid surfaces

International Nuclear Information System (INIS)

Dale, J.M.; Hulett, L.D.; Pendyala, S.

1980-01-01

Surfaces of tungsten and silicon have been bombarded with monoenergetic beams of positrons and electrons. Spectra of reflected particles show energy loss tails with discrete peaks at kinetic energies about 15 eV lower than that of the elastic peaks. In the higher energy loss range for tungsten, positron spectra show fine structure that is not apparent in the electron spectra. This suggests that the positrons are losing energy through mechanisms different from that of the electrons

Crustal geomagnetic field - Two-dimensional intermediate-wavelength spatial power spectra

Science.gov (United States)

Mcleod, M. G.

1983-01-01

Two-dimensional Fourier spatial power spectra of equivalent magnetization values are presented for a region that includes a large portion of the western United States. The magnetization values were determined by inversion of POGO satellite data, assuming a magnetic crust 40 km thick, and were located on an 11 x 10 array with 300 km grid spacing. The spectra appear to be in good agreement with values of the crustal geomagnetic field spatial power spectra given by McLeod and Coleman (1980) and with the crustal field model given by Serson and Hannaford (1957). The spectra show evidence of noise at low frequencies in the direction along the satellite orbital track (N-S). indicating that for this particular data set additional filtering would probably be desirable. These findings illustrate the value of two-dimensional spatial power spectra both for describing the geomagnetic field statistically and as a guide for diagnosing possible noise sources.

Secondary graviton spectra and waterfall-like fields

OpenAIRE

Giovannini, Massimo

2010-01-01

The secondary spectra of the gravitons induced by a waterfall-like field are computed and the general bounds on the spectral energy density of the tensor modes of the geometry are translated into explicit constraints on the amplitude and slope of the waterfall spectrum. The obtained results are compared with the primary gravitational wave spectra of the concordance model and of its neighboring extensions as well as with the direct Ligo/Virgo bounds on stochastic backgrounds of relic gravitons...

Reconstruction of fiber grating refractive-index profiles from complex bragg reflection spectra.

Science.gov (United States)

Huang, D W; Yang, C C

1999-07-20

Reconstruction of the refractive-index profiles of fiber gratings from their complex Bragg reflection spectra is experimentally demonstrated. The amplitude and phase of the complex reflection spectrum were measured with a balanced Michelson interferometer. By integrating the coupled-mode equations, we built the relationship between the complex coupling coefficient and the complex reflection spectrum as an iterative algorithm for reconstructing the index profile. This method is expected to be useful for reconstructing the index profiles of fiber gratings with any apodization, chirp, or dc structures. An apodized chirped grating and a uniform grating with a depression of index modulation were used to demonstrate the technique.

Simulation of attenuated total reflection infrared absorbance spectra: applications to automotive clear coat forensic analysis.

Science.gov (United States)

Lavine, Barry K; Fasasi, Ayuba; Mirjankar, Nikhil; Nishikida, Koichi; Campbell, Jay

2014-01-01

Attenuated total reflection (ATR) is a widely used sampling technique in infrared (IR) spectroscopy because minimal sample preparation is required. Since the penetration depth of the ATR analysis beam is quite shallow, the outer layers of a laminate or multilayered paint sample can be preferentially analyzed with the entire sample intact. For this reason, forensic laboratories are taking advantage of ATR to collect IR spectra of automotive paint systems that may consist of three or more layers. However, the IR spectrum of a paint sample obtained by ATR will exhibit distortions, e.g., band broadening and lower relative intensities at higher wavenumbers, compared with its transmission counterpart. This hinders library searching because most library spectra are measured in transmission mode. Furthermore, the angle of incidence for the internal reflection element, the refractive index of the clear coat, and surface contamination due to inorganic contaminants can profoundly influence the quality of the ATR spectrum obtained for automotive paints. A correction algorithm to allow ATR spectra to be searched using IR transmission spectra of the paint data query (PDQ) automotive database is presented. The proposed correction algorithm to convert transmission spectra from the PDQ library to ATR spectra is able to address distortion issues such as the relative intensities and broadening of the bands, and the introduction of wavelength shifts at lower frequencies, which prevent library searching of ATR spectra using archived IR transmission data.

FT-IR reflection spectra of single crystals: resolving phonons of different symmetry without using polarised radiation

Directory of Open Access Journals (Sweden)

METODIJA NAJDOSKI

2000-07-01

Full Text Available Fourier-transform infrared (FT-IR reflection spectra, asquired at nearnormal incidence, were recorded from single crystals belonging to six crystal systems: CsCr(SO42.12H2O (alum, cubic, K2CuCl2·2H2O (Mitscherlichite, tetragonal, CaCO3 (calcite, hexagonal, KHSO4 (mercallite, orthorhombic, CaSO4·2H2O (gypsum, monoclinic and CuSO4·5H2O (chalcantite, triclinic. The acquired IR reflection spectra were further transformed into absorption spectra, employing the Kramers-Kronig transformation. Except for the cubic alums, the spectra strongly depend on the crystal face from which they were recorded; this is a consequence of anisotropy. Phonons of a given symmetry (E-species, in tetragonal/hexagonal and B-species, in monoclinic crystals may be resolved without using a polariser. The spectrum may be simplified in the case of an orthorhombic crystal, as well. The longitudinal-optical (LO and transversal-optical (TO mode frequencies were calculated in the case of optically isotropic and the simplified spectra of optically uniaxial crystals.

Variable valence ion spectra in a crystal field

International Nuclear Information System (INIS)

Ghiordanescu, V.

1979-01-01

Using the Cadmium chloride as a host lattice, the optical spectra and RES of Mnsup(2+) were studied and the following results were obtained: a) By controlled dopings, the absorbtion and excitation spectra of ion Mnsup(2+) in CdCl 2 within the concentration range between 0.01 M and 25 M were plotted. Thus, the band structure for small concentrations was pointed out to differ from the structure observed for high concentrations. In the literature, this effect has not been observed on similar compounds, due to the small intensity values of the absorbtion spectra. b) Considering that for CdCl 2 :Mnsup(2+) 0.1 M, the optical spectra correspond to the isolated ion in the lattice, the energy levels were evaluated using electrostatic and spin-orbit terms in a perturbation calculation of the crystal field approximation. c) The calculation of parameter a which represents the effect of the cubic field in the spjn Hamiltonian of Mnsup(2+), is closer to the experjmental value -0.5.10 -4 cm -1 of the crystal field Dq and zeta parameters are used, respectively, parameters of the spin-orbit interaction obtained under b). d) The coupling effects of spins into more concentrated crystals with Mn 2+ are a function of temperature. The emjssion yield was given a quasi-cantitative evaluation in thjs paper as a function of temperature and concentratjon on the basis of which the isolated centers of Mn 2+ were found to display ectra whose intensity vary with temperature according to the Laporte forbidden transitions and spin rule theory, and the clusters including Mn 2+ - Mn 2+ pairs provide spectra whose intensity vary with the strength of the spin-spin coupling. (author)

Reflections on Conformal Spectra

CERN Multimedia

CERN. Geneva

2015-01-01

We use modular invariance and crossing symmetry of conformal field theory to reveal approximate reflection symmetries in the spectral decompositions of the partition function in two dimensions in the limit of large central charge and of the four-point function in any dimension in the limit of large scaling dimensions Δ0 of external operators. We use these symmetries to motivate universal upper bounds on the spectrum and the operator product expansion coefficients, which we then derive by independent techniques. Some of the bounds for four-point functions are valid for finite Δ0 as well as for large Δ0. We discuss a similar symmetry in a large spacetime dimension limit. Finally, we comment on the analogue of the Cardy formula and sparse light spectrum condition for the four-point function. (based on 1510.08772 with Kim & Ooguri). This seminar will be given via videolink

Iron oxide bands in the visible and near-infrared reflectance spectra of primitive asteroids

Science.gov (United States)

Jarvis, Kandy S.; Vilas, Faith; Gaffey, Michael J.

1993-01-01

High resolution reflectance spectra of primitive asteroids (C, P, and D class and associated subclasses) have commonly revealed an absorption feature centered at 0.7 microns attributed to an Fe(2+)-Fe(3+) charge transfer transition in iron oxides and/or oxidized iron in phyllosilicates. A smaller feature identified at 0.43 microns has been attributed to an Fe(3+) spin-forbidden transition in iron oxides. In the spectra of the two main-belt primitive asteroids 368 Haidea (D) and 877 Walkure (F), weak absorption features which were centered near the location of 0.60-0.65 microns and 0.80-0.90 microns prompted a search for features at these wavelengths and an attempt to identify their origin(s). The CCD reflectance spectra obtained between 1982-1992 were reviewed for similar absorption features located near these wavelengths. The spectra of asteroids in which these absorption features have been identified are shown. These spectra are plotted in order of increasing heliocentric distance. No division of the asteroids by class has been attempted here (although the absence of these features in the anhydrous S-class asteroids, many of which have presumably undergone full heating and differentiation should be noted). For this study, each spectrum was treated as a continuum with discrete absorption features superimposed on it. For each object, a linear least squares fit to the data points defined a simple linear continuum. The linear continuum was then divided into each spectrum, thus removing the sloped continuum and permitting the intercomparison of residual spectral features.

Plant phenolics and absorption features in vegetation reflectance spectra near 1.66 μm

Science.gov (United States)

Kokaly, Raymond F.; Skidmore, Andrew K

2015-01-01

Past laboratory and field studies have quantified phenolic substances in vegetative matter from reflectance measurements for understanding plant response to herbivores and insect predation. Past remote sensing studies on phenolics have evaluated crop quality and vegetation patterns caused by bedrock geology and associated variations in soil geochemistry. We examined spectra of pure phenolic compounds, common plant biochemical constituents, dry leaves, fresh leaves, and plant canopies for direct evidence of absorption features attributable to plant phenolics. Using spectral feature analysis with continuum removal, we observed that a narrow feature at 1.66 μm is persistent in spectra of manzanita, sumac, red maple, sugar maple, tea, and other species. This feature was consistent with absorption caused by aromatic C-H bonds in the chemical structure of phenolic compounds and non-hydroxylated aromatics. Because of overlapping absorption by water, the feature was weaker in fresh leaf and canopy spectra compared to dry leaf measurements. Simple linear regressions of feature depth and feature area with polyphenol concentration in tea resulted in high correlations and low errors (% phenol by dry weight) at the dry leaf (r2 = 0.95, RMSE = 1.0%, n = 56), fresh leaf (r2 = 0.79, RMSE = 2.1%, n = 56), and canopy (r2 = 0.78, RMSE = 1.0%, n = 13) levels of measurement. Spectra of leaves, needles, and canopies of big sagebrush and evergreens exhibited a weak absorption feature centered near 1.63 μm, short ward of the phenolic compounds, possibly consistent with terpenes. This study demonstrates that subtle variation in vegetation spectra in the shortwave infrared can directly indicate biochemical constituents and be used to quantify them. Phenolics are of lesser abundance compared to the major plant constituents but, nonetheless, have important plant functions and ecological significance. Additional research is needed to advance our understanding of the

Secondary graviton spectra and waterfall-like fields

CERN Document Server

Giovannini, Massimo

2010-01-01

The secondary spectra of the gravitons induced by a waterfall-like field are computed and the general bounds on the spectral energy density of the tensor modes of the geometry are translated into explicit constraints on the amplitude and slope of the waterfall spectrum. The obtained results are compared with the primary gravitational wave spectra of the concordance model and of its neighboring extensions as well as with the direct Ligo/Virgo bounds on stochastic backgrounds of relic gravitons. Space-borne interferometers (such as Lisa, Bbo, Decigo) seem to be less relevant but their potential implications are briefly outlined.

Response of exciton polariton spectra and electric fields to different additional boundary conditions

International Nuclear Information System (INIS)

Nkoma, J.S.

1982-08-01

The effects of three additional boundary conditions (ABC's) on the reflection and transmission spectra for exciton polaritons propagating in a spatially dispersive media are studied for both p and s configurations. An investigation of the ratios of the electric field amplitudes associated with the normal modes in these media is carried out. There is qualitative agreement among the predictions of the different ABC's, but there are significant quantitative differences, especially in the longitudinal polariton spike excited only in the p-geometry. Contact with formulations not using the ABC approach is made. The results are illustrated by parameters modelling the 1s exciton of PbI 2 . (author)

Influence of magnetic and ultrasonic fields on coefficient of reflectivity of GaAs, GaSb and InAs crystals

International Nuclear Information System (INIS)

Zaveryukhin, B.N.; Zaveryukhina, N.N.; Zaveryukhina, E.V.; Volodarskiy, V.V.

2007-01-01

Full text: Previously we demonstrated for the first time in the world that ultrasonic waves of the megahertz range can change the transport properties and a structure of semiconductors. In this work we have experimentally studied the influence of ultrasonic treatment on the spectral coefficients of reflection R in the magnetic fields of the samples of GaAs-, GaSb- and InAs-crystals. The reflectance spectra in the magnetic field of the samples before and after the ultrasonic treatment (UST) for a certain time were measured in a broad wavelength range including ultraviolet, visible, and infrared spectral regions. The semi-insulating GaAs-crystals had a thickness d=100 μm and a working area S of up to 3sm 2 . The p-GaSb- crystals had an area of S=0.25sm 2 and d =250 μm. The base p-GaSb-layers possessed the concentration N=2·10 17 sm 3 and n-GaSb-layers with a thickness of 0.5 m were created by diffusion doping with phosphorus. Besides, the experiments were performed also for of the n-InAs-crystals. The samples of the InAs-n crystals had a thickness of 100 μm an area S = 0.25 sm 2 . Some remains of sulfuric (S) were discovered in InAs-samples. As could was see from the experiments, all the initial IR spectra measured for the samples with various dopant concentrations NP exhibit maximums (peaks) for 0.2 μm and minimum (holes) for. The reflectance spectra measured after UST for time of t > l hour clearly reveal a shift of the R minima toward longer wavelengths and a general decrease in the reflectance of each sample. The shift of the R is unambiguous evidence of the acoustically stimulated diffusion of impurity (phosphorus) inward of the samples. Discovered peaks and holes slitted and changed their sizes in the magnetic fields. It should be emphasized that behavior of the R spectra of the GaAs-, In As- and GaSb- samples is determined by the same mechanisms. Changes of the R spectra after the UST are explained by acoustically stimulated diffusion of the dopant inward

LO-TO splittings, effective charges and interactions in electro-optic meta-nitroaniline crystal as studied by polarized IR reflection and transmission spectra

Science.gov (United States)

Szostak, M. M.; Le Calvé, N.; Romain, F.; Pasquier, B.

1994-10-01

The polarized IR reflection spectra of the meta-nitroaniline ( m-NA) single crystal along the a, b and c crystallographic axes as well as the b and c polarized transmission spectra have been measured in the 100-400 cm -1 region. The LO-TO splitting values have been calculated from the reflection spectra by fitting them with the four parameter dielectric function. The dipole moment derivatives, relevant to dynamic effective charges, of the vibrations have also been calculated and used to check the applicability of the oriented gas model (OGM) to reflection spectra. The discrepancies from the OGM have been discussed in terms of vibronic couplings, weak hydrogen bondings (HB) and intramolecular charge transfer.

Constrained energy minimization applied to apparent reflectance and single-scattering albedo spectra: a comparison

Science.gov (United States)

Resmini, Ronald G.; Graver, William R.; Kappus, Mary E.; Anderson, Mark E.

1996-11-01

Constrained energy minimization (CEM) has been applied to the mapping of the quantitative areal distribution of the mineral alunite in an approximately 1.8 km2 area of the Cuprite mining district, Nevada. CEM is a powerful technique for rapid quantitative mineral mapping which requires only the spectrum of the mineral to be mapped. A priori knowledge of background spectral signatures is not required. Our investigation applies CEM to calibrated radiance data converted to apparent reflectance (AR) and to single scattering albedo (SSA) spectra. The radiance data were acquired by the 210 channel, 0.4 micrometers to 2.5 micrometers airborne Hyperspectral Digital Imagery Collection Experiment sensor. CEM applied to AR spectra assumes linear mixing of the spectra of the materials exposed at the surface. This assumption is likely invalid as surface materials, which are often mixtures of particulates of different substances, are more properly modeled as intimate mixtures and thus spectral mixing analyses must take account of nonlinear effects. One technique for approximating nonlinear mixing requires the conversion of AR spectra to SSA spectra. The results of CEM applied to SSA spectra are compared to those of CEM applied to AR spectra. The occurrence of alunite is similar though not identical to mineral maps produced with both the SSA and AR spectra. Alunite is slightly more widespread based on processing with the SSA spectra. Further, fractional abundances derived from the SSA spectra are, in general, higher than those derived from AR spectra. Implications for the interpretation of quantitative mineral mapping with hyperspectral remote sensing data are discussed.

Angular Spectra of Polarized Galactic Foregrounds

OpenAIRE

Cho, Jung; Lazarian, A.

2003-01-01

It is believed that magnetic field lines are twisted and bend by turbulent motions in the Galaxy. Therefore, both Galactic synchrotron emission and thermal emission from dust reflects statistics of Galactic turbulence. Our simple model of Galactic turbulence, motivated by results of our simulations, predicts that Galactic disk and halo exhibit different angular power spectra. We show that observed angular spectra of synchrotron emission are compatible with our model. We also show that our mod...

Exploring H2O Prominence in Reflection Spectra of Cool Giant Planets

Science.gov (United States)

MacDonald, Ryan J.; Marley, Mark S.; Fortney, Jonathan J.; Lewis, Nikole K.

2018-05-01

The H2O abundance of a planetary atmosphere is a powerful indicator of formation conditions. Inferring H2O in the solar system giant planets is challenging, due to condensation depleting the upper atmosphere of water vapor. Substantially warmer hot Jupiter exoplanets readily allow detections of H2O via transmission spectroscopy, but such signatures are often diminished by the presence of clouds composed of other species. In contrast, highly scattering water clouds can brighten planets in reflected light, enhancing molecular signatures. Here, we present an extensive parameter space survey of the prominence of H2O absorption features in reflection spectra of cool (T eff clouds brighten the planet: T eff ∼ 150 K, g ≳ 20 ms‑2, f sed ≳ 3, m ≲ 10× solar. In contrast, planets with g ≲ 20 ms‑2 and T eff ≳ 180 K display substantially prominent H2O features embedded in the Rayleigh scattering slope from 0.4 to 0.73 μm over a wide parameter space. High f sed enhances H2O features around 0.94 μm, and enables these features to be detected at lower temperatures. High m results in dampened H2O absorption features, due to water vapor condensing to form bright, optically thick clouds that dominate the continuum. We verify these trends via self-consistent modeling of the low-gravity exoplanet HD 192310c, revealing that its reflection spectrum is expected to be dominated by H2O absorption from 0.4 to 0.73 μm for m ≲ 10× solar. Our results demonstrate that H2O is manifestly detectable in reflected light spectra of cool giant planets only marginally warmer than Jupiter, providing an avenue to directly constrain the C/O and O/H ratios of a hitherto unexplored population of exoplanetary atmospheres.

Secondary graviton spectra and waterfall-like fields

International Nuclear Information System (INIS)

Giovannini, Massimo

2010-01-01

The secondary spectra of the gravitons induced by a waterfall-like field are computed and the general bounds on the spectral energy density of the tensor modes of the geometry are translated into explicit constraints on the amplitude and slope of the waterfall spectrum. The obtained results are compared with the primary gravitational wave spectra of the concordance model and of its neighboring extensions as well as with the direct LIGO/Virgo bounds on stochastic backgrounds of relic gravitons. Space-borne interferometers [such as LISA (Laser Interferometer Space Antenna), BBO (Big Bang Observer), and DECIGO (Deci-hertz Interferometer Gravitational Wave Observatory)] seem to be less relevant but their potential implications are briefly outlined.

Secondary graviton spectra and waterfall-like fields

Science.gov (United States)

Giovannini, Massimo

2010-10-01

The secondary spectra of the gravitons induced by a waterfall-like field are computed and the general bounds on the spectral energy density of the tensor modes of the geometry are translated into explicit constraints on the amplitude and slope of the waterfall spectrum. The obtained results are compared with the primary gravitational wave spectra of the concordance model and of its neighboring extensions as well as with the direct LIGO/Virgo bounds on stochastic backgrounds of relic gravitons. Space-borne interferometers [such as LISA (Laser Interferometer Space Antenna), BBO (Big Bang Observer), and DECIGO (Deci-hertz Interferometer Gravitational Wave Observatory)] seem to be less relevant but their potential implications are briefly outlined.

Mössbauer forward scattering spectra of ferromagnets in radio-frequency magnetic field

Directory of Open Access Journals (Sweden)

A. Ya. Dzyublik

2012-03-01

Full Text Available The transmission of Mössbauer radiation through a thick ferromagnetic crystal, subjected to the radio-frequency (rf magnetic field, is studied. A quantum-mechanical dynamical scattering theory is developed, taking into account both the periodical reversals of the magnetic field at the nuclei and their coherent vibrations. The Mössbauer forward scattering (FS spectra of the weak ferromagnet FeBO3 exposed to the rf field are measured. It is discovered that the coherent gamma wave in the crystal, interacting with Mössbauer nuclei, absorbs or emits only couples of the rf photons. As a result, the FS spectra consist of equidistant lines spaced by twice the frequency of the rf field in contrast to the absorption spectra. Our experimental data and calculations well agree if we assume that the hyperfine field at the nuclei in FeBO3 periodically reverses and there are no coherent vibrations.

Reflectance spectra characteristics from an SPR grating fabricated by nano-imprint lithography technique for biochemical nanosensor applications

Science.gov (United States)

Setiya Pradana, Jalu; Hidayat, Rahmat

2018-04-01

In this paper, we report our research work on developing a Surface Plasmon Resonance (SPR) element with sub-micron (hundreds of nanometers) periodicity grating structure. This grating structure was fabricated by using a simple nano-imprint lithography technique from an organically siloxane polymers, which was then covered by nanometer thin gold layer. The formed grating structure was a very well defined square-shaped periodic structure. The measured reflectance spectra indicate the SPR wave excitation on this grating structure. For comparison, the simulations of reflectance spectra have been also carried out by using Rigorous Coupled-Wave Analysis (RCWA) method. The experimental results are in very good agreement with the simulation results.

Principal component analysis for the forensic discrimination of black inkjet inks based on the Vis-NIR fibre optics reflection spectra.

Science.gov (United States)

Gál, Lukáš; Oravec, Michal; Gemeiner, Pavol; Čeppan, Michal

2015-12-01

Nineteen black inkjet inks of six different brands were examined by fibre optics reflection spectroscopy in Visible and Near Infrared Region (Vis-NIR FORS) directly on paper with a view to achieving good resolution between them. These different inks were tested on nineteen different inkjet printers from three brands. Samples were obtained from prints by reflection probe. Processed reflection spectra in the range 500-1000 nm were used as samples in principal component analysis. Variability between spectra of the same ink obtained from different prints, as well as between spectra of square areas and lines was examined. For both spectra obtained from square areas and lines reference, Principal Component Analysis (PCA) models were created. According to these models, the inkjet inks were divided into clusters. PCA method is able to separate inks containing carbon black as main colorant from the other inks using other colorants. Some spectra were recorded from another piece of printer and used as validation samples. Spectra of validation samples were projected onto reference PCA models. According to position of validation samples in score plots it can be concluded that PCA based on Vis-NIR FORS can reliably differentiate inkjet inks which are included in the reference database. The presented method appears to be a suitable tool for forensic examination of questioned documents containing inkjet inks. Inkjet inks spectra were obtained without extraction or cutting sample with possibility to measure out of the laboratory. Copyright © 2015 Elsevier Ireland Ltd. All rights reserved.

Strong-field ionization of linear molecules by a bicircular laser field: Symmetry considerations

Science.gov (United States)

Gazibegović-Busuladžić, A.; Busuladžić, M.; Hasović, E.; Becker, W.; Milošević, D. B.

2018-04-01

Using the improved molecular strong-field approximation, we investigate (high-order) above-threshold ionization [(H)ATI] of various linear polyatomic molecules by a two-color laser field of frequencies r ω and s ω (with integer numbers r and s ) having coplanar counter-rotating circularly polarized components (a so-called bicircular field). Reflection and rotational symmetries for molecules aligned in the laser-field polarization plane, analyzed for diatomic homonuclear molecules in Phys. Rev. A 95, 033411 (2017), 10.1103/PhysRevA.95.033411, are now considered for diatomic heteronuclear molecules and symmetric and asymmetric linear triatomic molecules. There are additional rotational symmetries for (H)ATI spectra of symmetric linear molecules compared to (H)ATI spectra of the asymmetric ones. It is shown that these symmetries manifest themselves differently for r +s odd and r +s even. For example, HATI spectra for symmetric molecules with r +s even obey inversion symmetry. For ATI spectra of linear molecules, reflection symmetry appears only for certain molecular orientation angles ±90∘-j r 180∘/(r +s ) (j integer). For symmetric linear molecules, reflection symmetry appears also for the angles -j r 180∘/(r +s ) . For perpendicular orientation of molecules with respect to the laser-field polarization plane, the HATI spectra are very similar to those of the atomic targets, i.e., both spectra are characterized by the same type of the (r +s )-fold symmetry.

SU-E-T-432: Field Size Influence On the Electron and Photon Spectra Within Small MV Field Detectors

Energy Technology Data Exchange (ETDEWEB)

Benmakhlouf, H; Andreo, P [Department of Medical Physics, Karolinska University Hospital, Stockholm and Department of Physics, Medical Radiation Physics, Stockholm University (Sweden)

2015-06-15

Purpose: To investigate the influence of photon field size on the electron and photon fluence spectra in the active volume of small field detectors. Methods: The PENELOPE MC system based usercode PenEasy was used to calculate the material influence on the spectra by scoring the differential fluence in inserts of silicon, carbon, phosphorus and aluminium having 3 mm diameter and height. The spectra were then calculated inside the active volume of eleven detectors (ion chambers and solid-state detectors) whose geometry was simulated with great detail. The inserts/detectors were placed at 10 cm depth in a 30 cm x 30 cm x 30 cm water phantom and irradiated with 2.5 MeV photons and Varian Clinac 6 MV beams of small, medium and large size. Results: For all configurations, photon spectra in the scoring volume were similar to that in a small water volume except for additional characteristic x-ray peaks resulting from the material itself and from the materials surrounding the detectors (i.e. high-Z shielding the silicon). Electron fluence calculated in the inserts were up to 60% larger than in water; the difference increased with material density and decreasing field size. MC-calculated doses were compared to analytically determined collision kerma and restricted cema (cut-off=15keV). For the inserts, with large and medium fields K-col agreed with MC-dose, but K-col overestimated the dose for small fields due to lack of lateral CPE. For the detectors, up to 15% differences between K-col and the MC-dose were found. For all configurations the C-delta and MC-dose agreed within ±2%. Conclusion: The most relevant findings were that shielding affects substantially the photon spectra and material conditions the electron spectra, their field size dependence varying with the geometry configuration. These affect the values of factors entering into relative dosimetry.

VNIR Reflectance and MIR Emissivity Spectra of Ordinary Chondrite Meteorites Under Simulated Asteroid Surface Conditions

Science.gov (United States)

Gemma, M.; Shirley, K.; Glotch, T. D.; Ebel, D. S. S.

2017-12-01

Recent missions have revealed much about the nature of many Near-Earth asteroids, including the NEAR-Shoemaker target 433 Eros and Hayabusa target 25142 Itokawa. Both asteroids appear to have mineralogy consistent with ordinary chondrite meteorites. Laboratory spectral analysis of well-constrained meteorite samples can be employed as a reference tool to characterize and constrain data from current and future asteroid studies. A sample set of ordinary chondrite meteorites was chosen from the collection at the American Museum of Natural History. Six meteorites, spanning groups H, L, and LL, were prepared at four different size fractions (25-63 μm, 63-90 μm, 90-125 μm, 125-250 μm) in an attempt to mimic regolith known to exist on asteroids such as 433 Eros and 25142 Itokawa. At the Center for Planetary Exploration at Stony Brook University, spectra of the ordinary chondrite material were measured under simulated asteroid surface conditions ( 10-6 mbar, 150 K chamber temperature, low intensity illumination). The samples were used in two experiments: one measuring visible and near-infrared (VNIR) reflectance spectra at a series of temperatures, and the other measuring mid-infrared (MIR) emissivity spectra. The emissivity measurements require accurate simulation of the thermal environment within asteroid regolith, achieved by inducing a thermal gradient within the sample that results in a surface brightness temperature around 323 K (similar to the surface of 25142 Itokawa). Mid-IR emissivity spectra were collected for each sample at a surface temperature of 323 K, and reflectance spectra were collected in increments of 10 K, over the range 283 K to 373 K. Preliminary VNIR spectra show spreads similar to those seen in Hinrichs and Lucey (2002). Preliminary MIR emissivity spectra suggest that under asteroid surface conditions, the position of the Christiansen feature shifts to shorter wavelengths and emissivity is lower in the Reststrahlen bands when compared to

Three-dimensional electromagnetic strong turbulence. I. Scalings, spectra, and field statistics

International Nuclear Information System (INIS)

Graham, D. B.; Robinson, P. A.; Cairns, Iver H.; Skjaeraasen, O.

2011-01-01

The first fully three-dimensional (3D) simulations of large-scale electromagnetic strong turbulence (EMST) are performed by numerically solving the electromagnetic Zakharov equations for electron thermal speeds ν e with ν e /c≥0.025. The results of these simulations are presented, focusing on scaling behavior, energy density spectra, and field statistics of the Langmuir (longitudinal) and transverse components of the electric fields during steady-state strong turbulence, where multiple wave packets collapse simultaneously and the system is approximately statistically steady in time. It is shown that for ν e /c > or approx. 0.17 strong turbulence is approximately electrostatic and can be explained using the electrostatic two-component model. For v e /c > or approx. 0.17 the power-law behaviors of the scalings, spectra, and field statistics differ from the electrostatic predictions and results because ν e /c is sufficiently high to allow transverse modes to become trapped in density wells. The results are compared with those of past 3D electrostatic strong turbulence (ESST) simulations and 2D EMST simulations. For number density perturbations, the scaling behavior, spectra, and field statistics are shown to be only weakly dependent on ν e /c, whereas the Langmuir and transverse scalings, spectra, and field statistics are shown to be strongly dependent on ν e /c. Three-dimensional EMST is shown to have features in common with 2D EMST, such as a two-component structure and trapping of transverse modes which are dependent on ν e /c.

Polarization of electron cyclotron emission spectra in LHD

International Nuclear Information System (INIS)

Vries, P.C. de; Nagayama, Y.; Kawahata, K.; Inagaki, S.; Sasao, H.; Nagasaki, K.

1999-07-01

Electron cyclotron emission (ECE) can be used to determine the electron temperature profile in magnetized plasmas. The complex structure of the magnetic field configuration in the Large Helical Device (LHD), which has a large shear, complicates the analysis of the ECE spectrum. In a sheared magnetic field the propagation of X and O-mode polarization through the plasma are coupled, causing mode conversion and polarization rotation. Mode scrambling is also caused by wall reflections. In this report, this mode conversion in LHD is numerically analyzed. It was found that at low density mode conversion scrambles the ECE spectra. However, at higher density (n eo > 1.0·10 19 m -3 ) the polarization mode is found to rotate with the sheared magnetic field, yielding only a negligible mode conversion. Wall reflections are found to depolarize the ECE spectrum. Notwithstanding the LHD magnetic configuration, it is shown that temperature profiles could be revealed from the ECE spectra. (author)

Effects of mercury on visible/near-infrared reflectance spectra of mustard spinach plants (Brassica rapa P.)

International Nuclear Information System (INIS)

Dunagan, Sarah C.; Gilmore, Martha S.; Varekamp, Johan C.

2007-01-01

Mustard spinach plants were grown in mercury-spiked and contaminated soils collected in the field under controlled laboratory conditions over a full growth cycle to test if vegetation grown in these soils has discernible characteristics in visible/near-infrared (VNIR) spectra. Foliar Hg concentrations (0.174-3.993 ppm) of the Mustard spinach plants were positively correlated with Hg concentration of soils and varied throughout the growing season. Equations relating foliar Hg concentration to spectral reflectance, its first derivative, and selected vegetation indices were generated using stepwise multiple linear regression. Significant correlations are found for limited wavelengths for specific treatments and dates. Ratio Vegetation Index (RVI) and Red Edge Position (REP) values of plants in Hg-spiked and field-contaminated soils are significantly lower relative to control plants during the early and middle portions of the growth cycle which may be related to lower chlorophyll abundance or functioning in Hg-contaminated plants. - Some spectral characteristics of leaves of Brassica rapa P. may be associated with foliar mercury content

Manifestation of Crystal Lattice Distortions in the IR Reflection Spectra of Abrasion-Treated ZnSe Ceramics

Science.gov (United States)

Sitnikova, V. E.; Dunaev, A. A.; Mamalimov, R. I.; Pakhomov, P. M.; Khizhnyak, S. D.; Chmel, A. E.

2017-07-01

The Fourier IR reflection spectra of ZnSe ceramics prepared by hot pressing (HP), physical vapor deposition (PVD), and PVD combined with hot isostatic pressing (HIP) are presented. The optical constants of polished and dry-ground specimens were used for comparison. The grinding treatment simulated the erosion of the outer surface of optical elements made of zinc selenide under the influence of solid dust particles and deposits. In the polished specimens residual stresses showed up in the IR reflection spectra of the ZnSePVD and ZnSeHIP ceramics, which had well-defined orientation of grains, but were not present in the spectra of the ZnSeHIP ceramics as a result of mutual compensation of the stresses in the randomly oriented grains of the material. The stresses, which appeared as a shift of the absorption bands calculated by the Kramers-Kronig method, increased significantly after abrasive treatment of the specimens. For all the treated ceramics the intensity of the absorption bands resulting from the anharmonicity of the vibrations in the distorted crystal lattice increased by several times. The last effect also depends on the production prehistory of the ceramics.

Reconstruction of structural damage based on reflection intensity spectra of fiber Bragg gratings

International Nuclear Information System (INIS)

Huang, Guojun; Wei, Changben; Chen, Shiyuan; Yang, Guowei

2014-01-01

We present an approach for structural damage reconstruction based on the reflection intensity spectra of fiber Bragg gratings (FBGs). Our approach incorporates the finite element method, transfer matrix (T-matrix), and genetic algorithm to solve the inverse photo-elastic problem of damage reconstruction, i.e. to identify the location, size, and shape of a defect. By introducing a parameterized characterization of the damage information, the inverse photo-elastic problem is reduced to an optimization problem, and a relevant computational scheme was developed. The scheme iteratively searches for the solution to the corresponding direct photo-elastic problem until the simulated and measured (or target) reflection intensity spectra of the FBGs near the defect coincide within a prescribed error. Proof-of-concept validations of our approach were performed numerically and experimentally using both holed and cracked plate samples as typical cases of plane-stress problems. The damage identifiability was simulated by changing the deployment of the FBG sensors, including the total number of sensors and their distance to the defect. Both the numerical and experimental results demonstrate that our approach is effective and promising. It provides us with a photo-elastic method for developing a remote, automatic damage-imaging technique that substantially improves damage identification for structural health monitoring. (paper)

Remote sensing reflectance simulation of coastal optical complex water in the East China Sea

Science.gov (United States)

He, Shuo; Lou, Xiulin; Zhang, Huaguo; Zheng, Gang

2018-02-01

In this work, remote sensing reflectance (Rrs) spectra of the Zhejiang coastal water in the East China Sea (ECS) were simulated by using the Hydrolight software with field data as input parameters. The seawater along the Zhejiang coast is typical Case II water with complex optical properties. A field observation was conducted in the Zhejiang coastal region in late May of 2016, and the concentration of ocean color constituents (pigment, SPM and CDOM), IOPs (absorption and backscattering coefficients) and Rrs were measured at 24 stations of 3 sections covering the turbid to clear inshore coastal waters. Referring to these ocean color field data, an ocean color model suitable for the Zhejiang coastal water was setup and applied in the Hydrolight. A set of 11 remote sensing reflectance spectra above water surface were modeled and calculated. Then, the simulated spectra were compared with the filed measurements. Finally, the spectral shape and characteristics of the remote sensing reflectance spectra were analyzed and discussed.

Predicting ambient aerosol Thermal Optical Reflectance (TOR) measurements from infrared spectra: organic carbon

Science.gov (United States)

Dillner, A. M.; Takahama, S.

2014-11-01

Organic carbon (OC) can constitute 50% or more of the mass of atmospheric particulate matter. Typically, the organic carbon concentration is measured using thermal methods such as Thermal-Optical Reflectance (TOR) from quartz fiber filters. Here, methods are presented whereby Fourier Transform Infrared (FT-IR) absorbance spectra from polytetrafluoroethylene (PTFE or Teflon) filters are used to accurately predict TOR OC. Transmittance FT-IR analysis is rapid, inexpensive, and non-destructive to the PTFE filters. To develop and test the method, FT-IR absorbance spectra are obtained from 794 samples from seven Interagency Monitoring of PROtected Visual Environment (IMPROVE) sites sampled during 2011. Partial least squares regression is used to calibrate sample FT-IR absorbance spectra to artifact-corrected TOR OC. The FTIR spectra are divided into calibration and test sets by sampling site and date which leads to precise and accurate OC predictions by FT-IR as indicated by high coefficient of determination (R2; 0.96), low bias (0.02 μg m-3, all μg m-3 values based on the nominal IMPROVE sample volume of 32.8 m-3), low error (0.08 μg m-3) and low normalized error (11%). These performance metrics can be achieved with various degrees of spectral pretreatment (e.g., including or excluding substrate contributions to the absorbances) and are comparable in precision and accuracy to collocated TOR measurements. FT-IR spectra are also divided into calibration and test sets by OC mass and by OM / OC which reflects the organic composition of the particulate matter and is obtained from organic functional group composition; this division also leads to precise and accurate OC predictions. Low OC concentrations have higher bias and normalized error due to TOR analytical errors and artifact correction errors, not due to the range of OC mass of the samples in the calibration set. However, samples with low OC mass can be used to predict samples with high OC mass indicating that the

Localization and mass spectra of various matter fields on Weyl thin brane

Energy Technology Data Exchange (ETDEWEB)

Sui, Tao-Tao; Zhao, Li; Zhang, Yu-Peng [Lanzhou University, Institute of Theoretical Physics, Lanzhou (China); Xie, Qun-Ying [Lanzhou University, School of Information Science and Engineering, Lanzhou (China)

2017-06-15

It has been shown that the thin brane model in a five-dimensional Weyl gravity can deal with the wrong-signed Friedmann-like equation in the Randall-Sundrum-1 (RS1) model. In the Weyl brane model, there are also two branes with opposite brane tensions, but the four-dimensional graviton (the gravity zero mode) is localized near the negative tension brane, while our four-dimensional universe is localized on the positive tension brane. In this paper, we consider the mass spectra of various bulk matter fields (i.e., scalar, vector, and fermion fields) on the Weyl brane. It is shown that the zero modes of those matter fields can be localized on the positive tension brane under some conditions. The mass spectra of the bulk matter fields are equidistant for the higher excited states, and relatively sparse for the lower excited states. The size of the extra dimension determines the gap of the mass spectra. We also consider the correction to the Newtonian potential in this model and it is proportional to 1/r{sup 3}. (orig.)

Reflections on the Field.

Science.gov (United States)

Kauffman, James M.

2003-01-01

Reflections on the field of special education offer six ideas: (1) the value of science; (2) the continuing value of separate and special education for some students; (3) the continuing importance of prevention; (4) the importance of academic instruction; (5) the importance of social justice for the poor; and (6) a renewed emphasis on human…

Far-UV, visible, and near-IR reflectance spectra of frosts of H2O, CO2, NH3 and SO2

Science.gov (United States)

Hapke, B.; Wells, E.; Wagner, J.; Partlow, W.

1981-01-01

Measurements in the 0.1-2.5 micron range are presented for the reflectance spectra of the frosts of several volatiles pertinent to the study of comet nuclei. The frost spectra have distinctive features permitting their identification by spectroscopic reflectance remote sensing, notably in the far UV. It is found that: (1) H2O has a minimum at 0.16 microns and a maximum at 0.13 microns; (2) CO2 has minima near 0.21, 0.18 and 0.125 microns, with maxima at 0.19, 0.135 and 0.120 microns; (3) NH3 is bright at wavelengths longer than 0.21 microns, where reflectance drops to a value of only a few per cent at shorter wavelengths; (4) SO2 has a sharp drop at 0.32 microns, with a minimum at 0.18 microns and a maximum at 0.13 microns. The features in the frost spectra largely correspond to absorption line bands in the gas phase.

SPEXTRA: Optimal extraction code for long-slit spectra in crowded fields

Science.gov (United States)

Sarkisyan, A. N.; Vinokurov, A. S.; Solovieva, Yu. N.; Sholukhova, O. N.; Kostenkov, A. E.; Fabrika, S. N.

2017-10-01

We present a code for the optimal extraction of long-slit 2D spectra in crowded stellar fields. Its main advantage and difference from the existing spectrum extraction codes is the presence of a graphical user interface (GUI) and a convenient visualization system of data and extraction parameters. On the whole, the package is designed to study stars in crowded fields of nearby galaxies and star clusters in galaxies. Apart from the spectrum extraction for several stars which are closely located or superimposed, it allows the spectra of objects to be extracted with subtraction of superimposed nebulae of different shapes and different degrees of ionization. The package can also be used to study single stars in the case of a strong background. In the current version, the optimal extraction of 2D spectra with an aperture and the Gaussian function as PSF (point spread function) is proposed. In the future, the package will be supplemented with the possibility to build a PSF based on a Moffat function. We present the details of GUI, illustrate main features of the package, and show results of extraction of the several interesting spectra of objects from different telescopes.

Crystal field influence on vibration spectra: anhydrous uranyl chloride and dihydroxodiuranyl chloride tetrahydrate

International Nuclear Information System (INIS)

Perrin, Andre; Caillet, Paul

1976-01-01

Vibrational spectra of anhydrous uranyl chloride UO 2 Cl 2 and so called basic uranyl chloride: dihydroxodiuranyl chloride tetrahydrate /UO 2 (OH) 2 UO 2 /Cl 2 (H 2 O) 4 are reported. Factor group method analysis leads for the first time to complete and comprehensive interpretation of their spectra. Two extreme examples of crystal field influence on vibrational spectra are pointed out: for UO 2 Cl 2 , one is unable to explain spectra without taking into account all the elements of primitive crystalline cell, whilst for dihydroxodiuranyl dichloride tetrahydrate the crystal packing has very little effect on vibrational spectra [fr

Particle reflection along the magnetic field in nonlinear magnetosonic pulses

Science.gov (United States)

Ohsawa, Yukiharu

2017-11-01

Reflection of electrons and positrons in oblique, nonlinear magnetosonic pulses is theoretically analyzed. With the use of the parallel pseudo potential F, which is the integral of the parallel electric field along the magnetic field, a simple equation for reflection conditions is derived, which shows that reflection along the magnetic field is caused by two forces: one arising from the parallel pseudo potential multiplied by the particle charge and the other from the magnetic mirror effect. The two forces push electrons in the opposite directions. In compressive solitons, in which the magnetic field is intensified, electrons with large magnetic moments can be reflected by the magnetic mirror effect, whereas in rarefactive solitons, in which the magnetic field is weaker than outside, electrons with small magnetic moments can be reflected by the parallel pseudo potential. Although F is basically positive and large in shock waves, it occasionally becomes negative in some regions behind the shock front in nonstationary wave evolution. These negative spikes of F can reflect electrons. In contrast to the case of electrons, the two forces push positrons in the same direction. For this reason, compressive solitons in an electron-positron-ion plasma reflect a large fraction of positrons compared with electrons, whereas rarefactive solitons will reflect no positrons. A shock wave can reflect a majority of positrons with its large F. However, in a pure electron-positron plasma, in which F becomes zero, positron reflection will rarely occur.

Library of Giant Planet Reflection Spectra for WFirst and Future Space Telescopes

Science.gov (United States)

Smith, Adam J. R. W.; Fortney, Jonathan; Morley, Caroline; Batalha, Natasha E.; Lewis, Nikole K.

2018-01-01

Future large space space telescopes will be able to directly image exoplanets in optical light. The optical light of a resolved planet is due to stellar flux reflected by Rayleigh scattering or cloud scattering, with absorption features imprinted due to molecular bands in the planetary atmosphere. To aid in the design of such missions, and to better understand a wide range of giant planet atmospheres, we have built a library of model giant planet reflection spectra, for the purpose of determining effective methods of spectral analysis as well as for comparison with actual imaged objects. This library covers a wide range of parameters: objects are modeled at ten orbital distances between 0.5 AU and 5.0 AU, which ranges from planets too warm for water clouds, out to those that are true Jupiter analogs. These calculations include six metalicities between solar and 100x solar, with a variety of different cloud thickness parameters, and across all possible phase angles.

Manifestation of surface phonons in far infrared reflectivity of diamond-type semiconductors

Energy Technology Data Exchange (ETDEWEB)

Perez-Sanchez, F.L.; Perez-Rodriguez, F. [Instituto de Fisica, Universidad Autonoma de Puebla, Apdo. Post. J-48, Puebla, Pue. 72570 (Mexico)

2004-11-01

The coupling of surface phonons with light at (001) surfaces of diamond-structure crystals and its manifestation in far-infrared anisotropy spectra are theoretically studied. We apply the adiabatic bond charge model to describe short-range mechanical interactions together with long-range Coulomb forces and radiation fields, and we solve the corresponding system of coupled equations for the electromagnetic field and the lattice vibrations. We calculate far-infrared normal reflectance spectra of (001) surfaces of semi-infinite diamond-type crystals. In particular, we analyse reflectance spectra for the Si(001) (2 x 1) surface, which exhibit a resonance structure associated with the excitation of surface phonon modes. (copyright 2004 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

Exclusion Statistics in Conformal Field Theory Spectra

International Nuclear Information System (INIS)

Schoutens, K.

1997-01-01

We propose a new method for investigating the exclusion statistics of quasiparticles in conformal field theory (CFT) spectra. The method leads to one-particle distribution functions, which generalize the Fermi-Dirac distribution. For the simplest SU(n) invariant CFTs we find a generalization of Gentile parafermions, and we obtain new distributions for the simplest Z N -invariant CFTs. In special examples, our approach reproduces distributions based on 'fractional exclusion statistics' in the sense of Haldane. We comment on applications to fractional quantum Hall effect edge theories. copyright 1997 The American Physical Society

Predicting ambient aerosol thermal-optical reflectance (TOR) measurements from infrared spectra: organic carbon

Science.gov (United States)

Dillner, A. M.; Takahama, S.

2015-03-01

Organic carbon (OC) can constitute 50% or more of the mass of atmospheric particulate matter. Typically, organic carbon is measured from a quartz fiber filter that has been exposed to a volume of ambient air and analyzed using thermal methods such as thermal-optical reflectance (TOR). Here, methods are presented that show the feasibility of using Fourier transform infrared (FT-IR) absorbance spectra from polytetrafluoroethylene (PTFE or Teflon) filters to accurately predict TOR OC. This work marks an initial step in proposing a method that can reduce the operating costs of large air quality monitoring networks with an inexpensive, non-destructive analysis technique using routinely collected PTFE filter samples which, in addition to OC concentrations, can concurrently provide information regarding the composition of organic aerosol. This feasibility study suggests that the minimum detection limit and errors (or uncertainty) of FT-IR predictions are on par with TOR OC such that evaluation of long-term trends and epidemiological studies would not be significantly impacted. To develop and test the method, FT-IR absorbance spectra are obtained from 794 samples from seven Interagency Monitoring of PROtected Visual Environment (IMPROVE) sites collected during 2011. Partial least-squares regression is used to calibrate sample FT-IR absorbance spectra to TOR OC. The FTIR spectra are divided into calibration and test sets by sampling site and date. The calibration produces precise and accurate TOR OC predictions of the test set samples by FT-IR as indicated by high coefficient of variation (R2; 0.96), low bias (0.02 μg m-3, the nominal IMPROVE sample volume is 32.8 m3), low error (0.08 μg m-3) and low normalized error (11%). These performance metrics can be achieved with various degrees of spectral pretreatment (e.g., including or excluding substrate contributions to the absorbances) and are comparable in precision to collocated TOR measurements. FT-IR spectra are also

Dependence of EIA spectra on mutual coherence between coupling and probe fields in Cs atomic vapors

Energy Technology Data Exchange (ETDEWEB)

Kwon, Mi Rang; Kim, Kyoung Dae; Park, Hyun Deok; Kim, Jung Bog [Korea National University of Education, Chungwon (Korea, Republic of); Moon, Han Seb [Korea Research Institute of the Standards and Science, Taejon (Korea, Republic of)

2002-03-01

We observed the dependence of EIA spectra on the mutual coherence between the coupling and the probe fields in the D{sub 2}F{sub 9} = 4 {r_reversible} F{sub e} = 5 transition of Cs vapors at room temperature where the coupling and the probe fields were made from one laser source or two independent laser sources. By using one source having a high mutual coherence, we found EIA spectra linewidths much narrower than 0.1 {gamma} on the weak coupling field and the transparent spectra with linewidths narrower than 1 MHz within subnatural absorption on the strong coupling field. On the other hand, where the two sources which were nearly incoherent with each other were used, the absorption profiles showed the same dependence on the coupling power as the spectra for the one source, but their linewidths were broad, on the order of the natural linewidth.

Study of optical and electronic properties of nickel from reflection electron energy loss spectra

Science.gov (United States)

Xu, H.; Yang, L. H.; Da, B.; Tóth, J.; Tőkési, K.; Ding, Z. J.

2017-09-01

We use the classical Monte Carlo transport model of electrons moving near the surface and inside solids to reproduce the measured reflection electron energy-loss spectroscopy (REELS) spectra. With the combination of the classical transport model and the Markov chain Monte Carlo (MCMC) sampling of oscillator parameters the so-called reverse Monte Carlo (RMC) method was developed, and used to obtain optical constants of Ni in this work. A systematic study of the electronic and optical properties of Ni has been performed in an energy loss range of 0-200 eV from the measured REELS spectra at primary energies of 1000 eV, 2000 eV and 3000 eV. The reliability of our method was tested by comparing our results with the previous data. Moreover, the accuracy of our optical data has been confirmed by applying oscillator strength-sum rule and perfect-screening-sum rule.

Berlin Reflectance Spectral Library (BRSL)

Science.gov (United States)

Henckel, D.; Arnold, G.; Kappel, D.; Moroz, L. V.; Markus, K.

2017-09-01

The Berlin Reflectance Spectral Library (BRSL) provides a collection of reflectance spectra between 0.3 and 17 µm. It was originally dedicated to support space missions to small solar system bodies. Meanwhile the library includes selections of biconical reflectance spectra for spectral data analysis of other planetary bodies as well. The library provides reference spectra of well-characterized terrestrial analogue materials and meteorites for interpretation of remote sensing reflectance spectra of planetary surfaces. We introduce the BRSL, summarize the data available, and access to use them for further relevant applications.

Distinguishing nitrogen fertilization levels in field corn (Zea mays L.) with actively induced fluorescence and passive reflectance measurements

International Nuclear Information System (INIS)

McMurtrey, J.E. III; Chappelle, E.W.; Kim, M.S.; Meisinger, J.J.; Corp, L.A

1994-01-01

Laser-induced fluorescence (LIF) is an active sensing technique capable of capturing immediate and specific indications of changes in plant physiology and metabolism as they relate to the concentration and photosynthetic activity of the plant pigments. Reflectance is a passive sensing technique that can capture differences in the concentration of the primary plant pigments. Fluorescence and reflectance were compared for their ability to measure levels of plant stress that are of agronomic importance in corn (Zea mays L.) crops. Laboratory LIF and reflectance spectra were made on excised leaves from field grown corn. Changes in the visible region of the spectrum were compared between groups of plants fertilized with seven different levels of nitrogen (N) fertilization. A pulsed nitrogen laser emitting photons at a wavelength of 337 nm was used as a fluorescence excitation source. Differences in maximum intensity of fluorescence occurred at 440 nm, 525 nm, 685 nm, and 740 nm. Significant separations were found between levels of N fertilization at several LIF wavelength ratios. Several reflectance algorithms also produced significant separations between certain levels of N fertilization

Alfven Wave Reflection Model of Field-Aligned Currents at Mercury

Science.gov (United States)

Lyatsky, Wladislaw; Khazanov, George V.; Slavin, James

2010-01-01

An Alfven Wave Reflection (AWR) model is proposed that provides closure for strong field-aligned currents (FACs) driven by the magnetopause reconnection in the magnetospheres of planets having no significant ionospheric and surface electrical conductance. The model is based on properties of the Alfven waves, generated at high altitudes and reflected from the low-conductivity surface of the planet. When magnetospheric convection is very slow, the incident and reflected Alfven waves propagate along approximately the same path. In this case, the net field-aligned currents will be small. However, as the convection speed increases. the reflected wave is displaced relatively to the incident wave so that the incident and reflected waves no longer compensate each other. In this case, the net field-aligned current may be large despite the lack of significant ionospheric and surface conductivity. Our estimate shows that for typical solar wind conditions at Mercury, the magnitude of Region 1-type FACs in Mercury's magnetosphere may reach hundreds of kilo-Amperes. This AWR model of field-aligned currents may provide a solution to the long-standing problem of the closure of FACs in the Mercury's magnetosphere. c2009 Elsevier Inc. All rights reserved.

Hyperspectral optical imaging of human iris in vivo: characteristics of reflectance spectra

Science.gov (United States)

Medina, José M.; Pereira, Luís M.; Correia, Hélder T.; Nascimento, Sérgio M. C.

2011-07-01

We report a hyperspectral imaging system to measure the reflectance spectra of real human irises with high spatial resolution. A set of ocular prosthesis was used as the control condition. Reflectance data were decorrelated by the principal-component analysis. The main conclusion is that spectral complexity of the human iris is considerable: between 9 and 11 principal components are necessary to account for 99% of the cumulative variance in human irises. Correcting image misalignments associated with spontaneous ocular movements did not influence this result. The data also suggests a correlation between the first principal component and different levels of melanin present in the irises. It was also found that although the spectral characteristics of the first five principal components were not affected by the radial and angular position of the selected iridal areas, they affect the higher-order ones, suggesting a possible influence of the iris texture. The results show that hyperspectral imaging in the iris, together with adequate spectroscopic analyses provide more information than conventional colorimetric methods, making hyperspectral imaging suitable for the characterization of melanin and the noninvasive diagnosis of ocular diseases and iris color.

Catheter based mid-infrared reflectance and reflectance generated absorption spectroscopy

Science.gov (United States)

Holman, Hoi-Ying N

2013-10-29

A method of characterizing conditions in a tissue, by (a) providing a catheter that has a light source that emits light in selected wavenumbers within the range of mid-IR spectrum; (b) directing the light from the catheter to an area of tissue at a location inside a blood vessel of a subject; (c) collecting light reflected from the location and generating a reflectance spectra; and (d) comparing the reflectance spectra to a reference spectra of normal tissue, whereby a location having an increased number of absorbance peaks at said selected wavenumbers indicates a tissue inside the blood vessel containing a physiological marker for atherosclerosis.

Polarization resolved imaging with a reflection near-field optical microscope

DEFF Research Database (Denmark)

Bozhevolnyi, Sergey I.; Xiao, Mufei; Hvam, Jørn Märcher

1999-01-01

Using a rigorous microscopic point-dipole description of probe-sample interactions, we study imaging with a reflection scanning near-field optical microscope. Optical content, topographical artifacts, sensitivity window-i.e., the scale on which near-field optical images represent mainly optical...... configuration is preferable to the cross-linear one, since it ensures more isotropic (in the surface plane) near-field imaging of surface features. The numerical results are supported with experimental near-field images obtained by using a reflection microscope with an uncoated fiber tip....

Line broadening interference for high-resolution nuclear magnetic resonance spectra under inhomogeneous magnetic fields

International Nuclear Information System (INIS)

Wei, Zhiliang; Yang, Jian; Lin, Yanqin; Chen, Zhong; Chen, Youhe

2015-01-01

Nuclear magnetic resonance spectroscopy serves as an important tool for analyzing chemicals and biological metabolites. However, its performance is subject to the magnetic-field homogeneity. Under inhomogeneous fields, peaks are broadened to overlap each other, introducing difficulties for assignments. Here, we propose a method termed as line broadening interference (LBI) to provide high-resolution information under inhomogeneous magnetic fields by employing certain gradients in the indirect dimension to interfere the magnetic-field inhomogeneity. The conventional spectral-line broadening is thus interfered to be non-diagonal, avoiding the overlapping among adjacent resonances. Furthermore, an inhomogeneity correction algorithm is developed based on pattern recognition to recover the high-resolution information from LBI spectra. Theoretical deductions are performed to offer systematic and detailed analyses on the proposed method. Moreover, experiments are conducted to prove the feasibility of the proposed method for yielding high-resolution spectra in inhomogeneous magnetic fields

Integral parameters of crystal field for RE spectra

International Nuclear Information System (INIS)

Kustov, E.F.; Maketov, T.K.; Prgevudsky, A.K.; Steczko, G.

1980-01-01

The integral parameters of the crystal field are introduced for the interpretation of the spectra of RE ions in various crystals. The main formula of the method, the expression of the parameters for various states of Ce, Pr, Nd, Eu, Tb, Er, Tu, and Yb are determined. Integral parameters of A 2 , A 4 , A 6 and parameter of the spin-orbit interaction xi are calculated for 40 laser crystals with Nd, Er. An interpretation of the symmetry of the Eu 3+ centres of the NaBaZn silicate glass is given using integral parameters A 2 , A 4 . (author)

Single-particle spectra and magnetic field effects within precursor superconductivity

International Nuclear Information System (INIS)

Pieri, P.; Pisani, L.; Strinati, G.C.; Perali, A.

2004-01-01

We study the single-particle spectra below the superconducting critical temperature from weak to strong coupling within a precursor superconductivity scenario. The spectral-weight function is obtained from a self-energy that includes pairing-fluctuations within a continuum model representing the hot spots of the Brillouin zone. The effects of strong magnetic fields on the pseudogap temperature are also discussed within the same scenario

Quantitative analysis of reflection electron energy loss spectra to determine electronic and optical properties of Fe–Ni alloy thin films

International Nuclear Information System (INIS)

Tahir, Dahlang; Oh, Sukh Kun; Kang, Hee Jae; Tougaard, Sven

2016-01-01

Highlights: • Electronic and optical properties of Fe-Ni alloy thin films grown on Si (1 0 0) were studied via quantitative analyses of reflection electron energy loss spectra (REELS). • The energy loss functions (ELF) are dominated by a plasmon peak at 23.6 eV for Fe and moves gradually to lower energies in Fe-Ni alloys towards the bulk plasmon energy of Ni at 20.5 eV. • Fe has a strong effect on the dielectric and optical properties of Fe-Ni alloy thin films even for an alloy with 72% Ni. Electronic and optical properties of Fe-Ni alloy thin films grown on Si (1 0 0) were studied via quantitative analyses of reflection electron energy loss spectra (REELS). - Abstract: Electronic and optical properties of Fe–Ni alloy thin films grown on Si (1 0 0) by ion beam sputter deposition were studied via quantitative analyses of reflection electron energy loss spectra (REELS). The analysis was carried out by using the QUASES-XS-REELS and QUEELS-ε(k,ω)-REELS softwares to determine the energy loss function (ELF) and the dielectric functions and optical properties by analyzing the experimental spectra. For Ni, the ELF shows peaks around 3.6, 7.5, 11.7, 20.5, 27.5, 67 and 78 eV. The peak positions of the ELF for Fe_2_8Ni_7_2 are similar to those of Fe_5_1Ni_4_9, even though there is a small peak shift from 18.5 eV for Fe_5_1Ni_4_9 to 18.7 eV for Fe_2_8Ni_7_2. A plot of n, k, ε_1, and ε_2 shows that the QUEELS-ε(k,ω)-REELS software for analysis of REELS spectra is useful for the study of optical properties of transition metal alloys. For Fe–Ni alloy with high Ni concentration (Fe_2_8Ni_7_2), ε_1, and ε_2 have strong similarities with those of Fe. This indicates that the presence of Fe in the Fe–Ni alloy thin films has a strong effect.

The effect of work function changes on secondary ion energy spectra

International Nuclear Information System (INIS)

Wittmaack, K.

1983-01-01

The effect of work function changes on experimental secondary ion energy spectra is discussed. In agreement with theory the measured ion intensities frequently exhibit an exponential work function dependence. However, the predicted velocity dependence is only observed at fairly high secondary ion energies. In the absence of a velocity dependence of the degree of ionization measured shifts of energy spectra reflect work function changes directly. Various instrumental problems are shown to aggravate a detailed comparison between experiment and theory. Significant artefacts must be expected if the extraction field is of the order of or less than the lateral field induced by a work function difference between the bombarded spot and the surrounding sample surface. (Auth.)

Integrating Field Spectra and Worldview-2 Data for Grapevine Productivity in Different Irrigation Treatments

Science.gov (United States)

Maimaitiyiming, M.; Bozzolo, A.; Wulamu, A.; Wilkins, J. L.

2015-12-01

Precision farming requires high spectral, spatial and temporal resolution remote sensing data to detect plant physiological changes. The higher spatial resolution is particularly as important as the spectral resolution for crop monitoring. It is important to develop data integration techniques between field or airborne hyperspectral data with spaceborne broad band multispectral images for plant productivity monitoring. To investigate varying rootstock and irrigation interactions, different irrigation treatments are implemented in a vineyard experimental site either i) unirrigated ii) full replacement of evapotranspiration (ET) iii) irrigated at 50 % of the potential ET. In summer 2014, we collected leaf and canopy spectra of the vineyard using field spectroscopy along with other plant physiological and nutritional variables. In this contribution, we integrate the field spectra and the spectral wavelengths of WorldView-2 to develop a predictive model for plant productivity,i.e., fruit quality and yield. First, we upscale field and canopy spectra to WorldView-2 spectral bands using radiative transfer simulations (e.g., MODTRAN). Then we develop remote sensing techniques to quantify plant productivity in different scenarios water stress by identifying the most effective and sensitive wavelengths, and indices that are capable of early detection of plant health and estimation of crop nutrient status. Finally we present predictive models developed from partial least square regression (PLSR) for plant productivity using spectral wavelengths and indices derived from integrated field and satellite remote sensing data.

Predicting ambient aerosol thermal-optical reflectance measurements from infrared spectra: elemental carbon

Science.gov (United States)

Dillner, A. M.; Takahama, S.

2015-10-01

Elemental carbon (EC) is an important constituent of atmospheric particulate matter because it absorbs solar radiation influencing climate and visibility and it adversely affects human health. The EC measured by thermal methods such as thermal-optical reflectance (TOR) is operationally defined as the carbon that volatilizes from quartz filter samples at elevated temperatures in the presence of oxygen. Here, methods are presented to accurately predict TOR EC using Fourier transform infrared (FT-IR) absorbance spectra from atmospheric particulate matter collected on polytetrafluoroethylene (PTFE or Teflon) filters. This method is similar to the procedure developed for OC in prior work (Dillner and Takahama, 2015). Transmittance FT-IR analysis is rapid, inexpensive and nondestructive to the PTFE filter samples which are routinely collected for mass and elemental analysis in monitoring networks. FT-IR absorbance spectra are obtained from 794 filter samples from seven Interagency Monitoring of PROtected Visual Environment (IMPROVE) sites collected during 2011. Partial least squares regression is used to calibrate sample FT-IR absorbance spectra to collocated TOR EC measurements. The FT-IR spectra are divided into calibration and test sets. Two calibrations are developed: one developed from uniform distribution of samples across the EC mass range (Uniform EC) and one developed from a uniform distribution of Low EC mass samples (EC < 2.4 μg, Low Uniform EC). A hybrid approach which applies the Low EC calibration to Low EC samples and the Uniform EC calibration to all other samples is used to produce predictions for Low EC samples that have mean error on par with parallel TOR EC samples in the same mass range and an estimate of the minimum detection limit (MDL) that is on par with TOR EC MDL. For all samples, this hybrid approach leads to precise and accurate TOR EC predictions by FT-IR as indicated by high coefficient of determination (R2; 0.96), no bias (0.00 μg m-3, a

Study of the photoexcited carrier dynamics in InP:Fe using time-resolved reflection and photoluminescence spectra

International Nuclear Information System (INIS)

Huang Shihua; Li Xi; Lu Fang

2004-01-01

The photoexcited carrier dynamics and photoluminescence of the undoped InP and Fe implanted InP was studied by time-resolved reflection and photoluminescence spectra. The decay times of reflection recovery and the radiative recombination for Fe implanted InP are shorter than those of undoped InP. Considering the surface recombination, a model was developed to simulate the reflection recovery dynamics, it agrees with the experimental results very well. Moreover, we obtained the ambipolar diffusion coefficient and the surface recombination velocity by using the model. For Fe-doped InP, the surface recombination velocity is much larger than that for the undoped InP, which is probably due to Fe 2+/3+ trapping centers and the large surface band bending. The PL decay time for Fe implanted InP is shorter than that for undoped InP, which is ascribed to the capture centers introduced by metallic precipitates

Compilation of neutron flux density spectra and reaction rates in different neutron fields

International Nuclear Information System (INIS)

Ertek, C.

1979-07-01

Upon the recommendation of International Working Group of Reactor Radiation Measurements (IWGRRM), the compilation of neutron flux density spectra and the reaction rates obtained by activation and fission foils in different neutron fields is presented. The neutron fields considered are as follows: 1/E; iron block; LWR core and pressure vessel; LMFBR core and blanket; CTR first wall and blanket; fission spectrum

Room-temperature near-field reflection spectrocopy of semiconductor nanostructures

DEFF Research Database (Denmark)

Langbein, Wolfgang; Hvam, Jørn Märcher; Madsen, Steen

1999-01-01

We investigate the properties of near-field reflection spectroscopy in different polarization and detection modes using uncoated fiber probes. The results show, that cross-polarized detection suppresses to a large extent far-field contributions. Using the fiber dithering as a modulation source fo...

Visible Wavelength Reflectance Spectra and Taxonomies of Near-Earth Objects from Apache Point Observatory

Science.gov (United States)

Hammergren, Mark; Brucker, Melissa J.; Nault, Kristie A.; Gyuk, Geza; Solontoi, Michael R.

2015-11-01

Near-Earth Objects (NEOs) are interesting to scientists and the general public for diverse reasons: their impacts pose a threat to life and property; they present important albeit biased records of the formation and evolution of the Solar System; and their materials may provide in situ resources for future space exploration and habitation.In January 2015 we began a program of NEO astrometric follow-up and physical characterization using a 17% share of time on the Astrophysical Research Consortium (ARC) 3.5-meter telescope at Apache Point Observatory (APO). Our 500 hours of annual observing time are split into frequent, short astrometric runs (see poster by K. A. Nault et. al), and half-night runs devoted to physical characterization (see poster by M. J. Brucker et. al for preliminary rotational lightcurve results). NEO surface compositions are investigated with 0.36-1.0 μm reflectance spectroscopy using the Dual Imaging Spectrograph (DIS) instrument. As of August 25, 2015, including testing runs during fourth quarter 2014, we have obtained reflectance spectra of 68 unique NEOs, ranging in diameter from approximately 5m to 8km.In addition to investigating the compositions of individual NEOs to inform impact hazard and space resource evaluations, we may examine the distribution of taxonomic types and potential trends with other physical and orbital properties. For example, the Yarkovsky effect, which is dependent on asteroid shape, mass, rotation, and thermal characteristics, is believed to dominate other dynamical effects in driving the delivery of small NEOs from the main asteroid belt. Studies of the taxonomic distribution of a large sample of NEOs of a wide range of sizes will test this hypothesis.We present a preliminary analysis of the reflectance spectra obtained in our survey to date, including taxonomic classifications and potential trends with size.Acknowledgements: Based on observations obtained with the Apache Point Observatory 3.5-meter telescope, which

A theoretical and experimental analysis of modulated laser fields and power spectra

DEFF Research Database (Denmark)

Olesen, Henning; Jacobsen, G.

1982-01-01

A general theoretical description of modulated laser fields and power spectra for a current modulated single-mode laser is derived, taking into account both the intensity and frequency modulation (IM and FM) of the emitted light. The theory relies on an explicit knowledge of the modulus as well...

Blue-green fluorescence and visible-infrared reflectance of corn (Zea mays L.) grain for in situ field detection of nitrogen supply

International Nuclear Information System (INIS)

McMurtrey, J.E. III; Chappelle, E.W.; Kim, M.S.; Corp, L.A.; Daughtry, C.S.T.

1996-01-01

The sensing of spectral attributes of corn (Zea mays L.) grain from site specific areas of the field during the harvest process may be useful in managing agronomic inputs and production practices on those areas of the field in subsequent growing seasons. Eight levels of nitrogen (N) fertilization were applied to field grown corn at Beltsville, Maryland. These N treatments produced a range of chlorophyll levels, biomass and physiological condition in the live plant canopies. After harvest, spectra were obtained in the laboratory on whole grain samples. Fluorescence emissions were acquired from 400 to 600 nm and percent reflectance were measured in the visible (VIS) near infrared (NIR) and mid-infrared (MIR) regions from 400 nm to 2400 nm. A ultraviolet (UV) excitation band centered at 385 nm was the most effective in producing fluorescence emission differences in the blue-green region of the fluorescence spectrum with maxima centered from 430-470nm in the blue and with an intense shoulder centered at around 530-560 nm in the green region. Reflectance showed the most spectral differences in the NIR and MIR (970-2330 nm) regions

The influence of magnetic field geometry on magnetars X-ray spectra

International Nuclear Information System (INIS)

Viganò, D; Pons, J A; Miralles, J A; Parkins, N; Zane, S; Turolla, R

2012-01-01

Nowadays, the analysis of the X-ray spectra of magnetically powered neutron stars or magnetars is one of the most valuable tools to gain insight into the physical processes occurring in their interiors and magnetospheres. In particular, the magnetospheric plasma leaves a strong imprint on the observed X-ray spectrum by means of Compton up-scattering of the thermal radiation coming from the star surface. Motivated by the increased quality of the observational data, much theoretical work has been devoted to develop Monte Carlo (MC) codes that incorporate the effects of resonant Compton scattering (RCS) in the modeling of radiative transfer of photons through the magnetosphere. The two key ingredients in this simulations are the kinetic plasma properties and the magnetic field (MF) configuration. The MF geometry is expected to be complex, but up to now only mathematically simple solutions (self-similar solutions) have been employed. In this work, we discuss the effects of new, more realistic, MF geometries on synthetic spectra. We use new force-free solutions [14] in a previously developed MC code [9] to assess the influence of MF geometry on the emerging spectra. Our main result is that the shape of the final spectrum is mostly sensitive to uncertain parameters of the magnetospheric plasma, but the MF geometry plays an important role on the angle-dependence of the spectra.

Mineralogy and chemistry of Ti-bearing lunar soils: Effects on reflectance spectra and remote sensing observations

Science.gov (United States)

Coman, Ecaterina O.; Jolliff, Bradley L.; Carpenter, Paul

2018-05-01

This paper presents results of coordinated ultraviolet and visible wavelength reflectance measurements, X-ray diffraction analyses of mineral components, and micro X-ray fluorescence analyses of Ti concentrations of 13 lunar soil samples (Lunar Reconnaissance Orbiter (LRO) Wide Angle Camera (WAC) spectral data for the 321/415 ratio of Apollo ground-truth sites. The correlation between lab-derived 321/415 ratios and TiO2 content for measured samples improves when low-maturity samples are excluded from the dataset, implying that the LROC WAC spectra at 400 m/pix spatial resolution senses mostly mature soil.

Improving the performance of infrared reflective night curtains for warming field plots

DEFF Research Database (Denmark)

Bruhn, Dan; Larsen, Klaus S.; de Dato, Giovanbattista D.

2013-01-01

Infrared reflective (IR) curtains have been widely used to obtain passive nighttime warming in field ecosystem experiments in order to simulate and study climate warming effects on ecosystems. For any field installation with IR-reflective curtains in an ecosystem the achieved heating effect depen...

Plasmonic properties of gold nanoparticles on silicon substrates: Understanding Fano-like spectra observed in reflection

Science.gov (United States)

Bossard-Giannesini, Léo; Cruguel, Hervé; Lacaze, Emmanuelle; Pluchery, Olivier

2016-09-01

Gold nanoparticles (AuNPs) are known for their localized surface plasmon resonance (LSPR) that can be measured with UV-visible spectroscopy. AuNPs are often deposited on silicon substrates for various applications, and the LSPR is measured in reflection. In this case, optical spectra are measured by surface differential reflectance spectroscopy (SDRS) and the absorbance exhibits a negative peak. This article studies both experimentally and theoretically on the single layers of 16 nm diameter spherical gold nanoparticles (AuNPs) grafted on silicon. The morphology and surface density of AuNPs were investigated by atomic force microscopy (AFM). The plasmon response in transmission on the glass substrate and in reflection on the silicon substrate is described by an analytical model based on the Fresnel equations and the Maxwell-Garnett effective medium theory (FMG). The FMG model shows a strong dependence to the incidence angle of the light. At low incident angles, the peak appears negatively with a shallow intensity, and at angles above 30°, the usual positive shape of the plasmon is retrieved. The relevance of the FMG model is compared to the Mie theory within the dipolar approximation. We conclude that no Fano effect is responsible for this derivative shape. An easy-to-use formula is derived that agrees with our experimental data.

Properties of spectra of the reflected and transmitted radiation during propagation of relativistically strong laser pulses in underdense plasmas

International Nuclear Information System (INIS)

Bulanov, S.V.; Esirkepov, T.Z.; Naumova, N.M.

1996-01-01

Particle-in-cell simulation has been performed to study the spatial-temporal evolution of the pulse propagating in an underdense plasma. The spectra both of the reflected and transmitted radiation are investigated. The spectrum structure of the reflected radiation is due to the backward stimulated Raman scattering meanwhile the transmitted radiation structure is mainly due to the nonlinear self-phase-modulation. The influence of the pulse shape on the transmitted radiation spectrum is revealed. The dependence of the main features of the spectrum and the self-consistent pulse distortion is found. The pulse distortion is accompanied by the relativistic electrons generation. copyright 1996 American Institute of Physics

Infrared reflection spectra of multilayer epitaxial heterostructures with embedded InAs and GaAs layers

International Nuclear Information System (INIS)

Seredin, P. V.; Domashevskaya, E. P.; Lukin, A. N.; Arsent'ev, I. N.; Vinokurov, D. A.; Tarasov, I. S.

2008-01-01

The effect of the thickness of embedded InAs and GaAs layers on the infrared reflection spectra of lattice vibrations for AlInAs/InAs/AlInAs, InGaAs/GaAs/InGaAs, and AlInAs/InGaAs/GaAs/InGaAs/AlInAs multilayer epitaxial heterostructures grown by MOC hydride epitaxy on InP (100) substrates is studied. Relative stresses emerging in the layers surrounding the embedded layers with variation in the number of monolayers from which the quantum dots are formed and with variation the thickness of the layers themselves surrounding the embedded layers are evaluated.

The effect of electric field maximum on the Rabi flopping and generated higher frequency spectra

International Nuclear Information System (INIS)

Niu Yueping; Cui Ni; Xiang Yang; Li Ruxin; Gong Shangqing; Xu Zhizhan

2008-01-01

We investigate the effect of the electric field maximum on the Rabi flopping and the generated higher frequency spectra properties by solving Maxwell-Bloch equations without invoking any standard approximations. It is found that the maximum of the electric field will lead to carrier-wave Rabi flopping (CWRF) through reversion dynamics which will be more evident when the applied field enters the sub-one-cycle regime. Therefore, under the interaction of sub-one-cycle pulses, the Rabi flopping follows the transient electric field tightly through the oscillation and reversion dynamics, which is in contrast to the conventional envelope Rabi flopping. Complete or incomplete population inversion can be realized through the control of the carrier-envelope phase (CEP). Furthermore, the generated higher frequency spectra will be changed from distinct to continuous or irregular with the variation of the CEP. Our results demonstrate that due to the evident maximum behavior of the electric field, pulses with different CEP give rise to different CWRFs, and then different degree of interferences lead to different higher frequency spectral features.

Predicting ambient aerosol Thermal Optical Reflectance (TOR) measurements from infrared spectra: elemental carbon

Science.gov (United States)

Dillner, A. M.; Takahama, S.

2015-06-01

Elemental carbon (EC) is an important constituent of atmospheric particulate matter because it absorbs solar radiation influencing climate and visibility and it adversely affects human health. The EC measured by thermal methods such as Thermal-Optical Reflectance (TOR) is operationally defined as the carbon that volatilizes from quartz filter samples at elevated temperatures in the presence of oxygen. Here, methods are presented to accurately predict TOR EC using Fourier Transform Infrared (FT-IR) absorbance spectra from atmospheric particulate matter collected on polytetrafluoroethylene (PTFE or Teflon) filters. This method is similar to the procedure tested and developed for OC in prior work (Dillner and Takahama, 2015). Transmittance FT-IR analysis is rapid, inexpensive, and non-destructive to the PTFE filter samples which are routinely collected for mass and elemental analysis in monitoring networks. FT-IR absorbance spectra are obtained from 794 filter samples from seven Interagency Monitoring of PROtected Visual Environment (IMPROVE) sites collected during 2011. Partial least squares regression is used to calibrate sample FT-IR absorbance spectra to collocated TOR EC measurements. The FTIR spectra are divided into calibration and test sets. Two calibrations are developed, one which is developed from uniform distribution of samples across the EC mass range (Uniform EC) and one developed from a~uniform distribution of low EC mass samples (EC < 2.4 μg, Low Uniform EC). A hybrid approach which applies the low EC calibration to low EC samples and the Uniform EC calibration to all other samples is used to produces predictions for low EC samples that have mean error on par with parallel TOR EC samples in the same mass range and an estimate of the minimum detection limit (MDL) that is on par with TOR EC MDL. For all samples, this hybrid approach leads to precise and accurate TOR EC predictions by FT-IR as indicated by high coefficient of variation (R2; 0.96), no

Fundamental quantification procedure for total reflection X-ray fluorescence spectra analysis and elements determination

International Nuclear Information System (INIS)

Wegrzynek, D.; Holynska, B.

1997-01-01

A method for the determination of the concentrations of elements in particulate-like samples measured in total reflection geometry is proposed. In the proposed method the fundamental parameters are utilized for calculating the sensitivities of elements and an internal standard is used to account for the unknown mass per unit area of a sample and geometrical constant of the spectrometer. The modification of the primary excitation spectrum on its way to a sample has been taken into consideration. The concentrations of the elements to be determined are calculated simultaneously with the spectra deconvolution procedure. In the process of quantitative analysis the intensities of all X-ray peaks corresponding to K and L-series lines present in the analyzed spectrum are taken into account. (Author)

Statistical Analysis of the Reflectivity of a Heliostats Field. Application to the CRS Heliostats Field of the Plataforma Solar de Almeria

International Nuclear Information System (INIS)

Fernandez Reche, J.

2003-01-01

Reflectivity measuring in a heliostats field of a solar central tower is a task that should be performed periodically. The reflectivity of the field is a value that should be known to evaluate the system, moreover it plays an important role in several simulation codes which are useful for the daily operation of the system. When the size of the heliostats field increases (tens of heliostats) it is necessary to find a method, due to operability reasons, that allows us to offer a reflectivity value measuring only in few facets guaranteeing that the statistical error of this value is within a reasonable range. In this report a statistical analysis of the reflectivity in a heliostats field is presented. The analysis was particularized for the CRS heliostats field of the Plataforma Solar de Almeria. The results of the present study allow us to guarantee a reflectivity value of the heliostats field with a statistical error below 1% measuring only 12 facets (instead of the 1116 facets that compose the field). (Author) 6 refs

Ultraviolet spectra of field horizontal-branch A-type stars. II

International Nuclear Information System (INIS)

Philip, A.G.D.; Hayes, D.S.; Adelman, S.J.

1990-01-01

The spectra of six additional A-type stars have been obtained at low resolution between 1200 and 1900 A with the IUE. The energy distributions of four of the stars match that of the field horizontal branch (FHB) distribution in Huenemoerder et al. (1984) while those of the other two do not. Three of the FHB stars fall above a line in the C(19 - V)0 vs. (b-y)0 diagram; however, HD 60825 is anomalously blue for its C(19 - V) color. 7 refs

Photoabsorption spectra in the perturbative regime for atoms in crossed electric and magnetic fields

International Nuclear Information System (INIS)

Marxer, H.; Moser, I.; O'Mahony, P.F.; Mota-Furtado, F.

1994-01-01

We calculate photoabsorption spectra of atoms in crossed electric and magnetic fields using a truncated basis of Coulomb eigenfunctions. The method yields spectra in the regime where inter-n-mixing is not dominant and allows for the treatment of non-hydrogenic atoms via a simple recourse to quantum defects. We compare results for hydrogen to those obtained in second order perturbation theory where the residual degeneracy left in first order perturbation theory is completely lifted and we show that only a very small basis size is needed to achieve convergence to within the accuracy of second order perturbation theory. In the case of lithium the coupling of an incomplete hydrogen-like manifold to states with non-negligible quantum defects substantially modifies the spectra obtained in comparison to the purely hydrogenic spectra. In the inter-n-mixing regime we also compare our convoluted results directly with an experimental spectrum for hydrogen and find good agreement below the saddle point. (Author)

Can a one-layer optical skin model including melanin and inhomogeneously distributed blood explain spatially resolved diffuse reflectance spectra?

Science.gov (United States)

Karlsson, Hanna; Pettersson, Anders; Larsson, Marcus; Strömberg, Tomas

2011-02-01

Model based analysis of calibrated diffuse reflectance spectroscopy can be used for determining oxygenation and concentration of skin chromophores. This study aimed at assessing the effect of including melanin in addition to hemoglobin (Hb) as chromophores and compensating for inhomogeneously distributed blood (vessel packaging), in a single-layer skin model. Spectra from four humans were collected during different provocations using a twochannel fiber optic probe with source-detector separations 0.4 and 1.2 mm. Absolute calibrated spectra using data from either a single distance or both distances were analyzed using inverse Monte Carlo for light transport and Levenberg-Marquardt for non-linear fitting. The model fitting was excellent using a single distance. However, the estimated model failed to explain spectra from the other distance. The two-distance model did not fit the data well at either distance. Model fitting was significantly improved including melanin and vessel packaging. The most prominent effect when fitting data from the larger separation compared to the smaller separation was a different light scattering decay with wavelength, while the tissue fraction of Hb and saturation were similar. For modeling spectra at both distances, we propose using either a multi-layer skin model or a more advanced model for the scattering phase function.

Entanglement characteristics of subharmonic modes reflected from a cavity for type-II second-harmonic generation

International Nuclear Information System (INIS)

Zhai Zehui; Li Yongming; Gao Jiangrui

2004-01-01

Quantum fluctuation and quantum entanglement of the pump fields reflected from an optical cavity for type-II second-harmonic generation are theoretically analyzed. The correlation spectra of quadrature components between the reflected subharmonic fields are interpreted in terms of pump parameter, intracavity losses, and normalized frequency. High correlation of both amplitude and phase quadratures can be accessed in a triple resonant cavity before the pitchfork bifurcation occurs. The two reflected subharmonic fields are in an entangled state with quantum correlation of phase quadratures and anticorrelation of amplitude quadratures. The proposed system can be exploited as a source for generating entangled states of continuous variables

Analyzing asteroid reflectance spectra with numerical tools based on scattering simulations

Science.gov (United States)

Penttilä, Antti; Väisänen, Timo; Markkanen, Johannes; Martikainen, Julia; Gritsevich, Maria; Muinonen, Karri

2017-04-01

We are developing a set of numerical tools that can be used in analyzing the reflectance spectra of granular materials such as the regolith surface of atmosphereless Solar system objects. Our goal is to be able to explain, with realistic numerical scattering models, the spectral features arising when materials are intimately mixed together. We include the space-weathering -type effects in our simulations, i.e., mixing host mineral locally with small inclusions of another material in small proportions. Our motivation for this study comes from the present lack of such tools. The current common practice is to apply a semi-physical approximate model such as some variation of Hapke models [e.g., 1] or the Shkuratov model [2]. These models are expressed in a closed form so that they are relatively fast to apply. They are based on simplifications on the radiative transfer theory. The problem is that the validity of the model is not always guaranteed, and the derived physical properties related to particle scattering properties can be unrealistic [3]. We base our numerical tool into a chain of scattering simulations. Scattering properties of small inclusions inside an absorbing host matrix can be derived using exact methods solving the Maxwell equations of the system. The next step, scattering by a single regolith grain, is solved using a geometrical optics method accounting for surface reflections, internal absorption, and possibly the internal diffuse scattering. The third step involves the radiative transfer simulations of these regolith grains in a macroscopic planar element. The chain can be continued next with shadowing simulation over the target surface elements, and finally by integrating the bidirectional reflectance distribution function over the object's shape. Most of the tools in the proposed chain already exist, and one practical task for us is to tie these together into an easy-to-use toolchain that can be publicly distributed. We plan to open the

Influence of hurricane wind field in the structure of directional wave spectra

Science.gov (United States)

Esquivel-Trava, Bernardo; Ocampo-Torres, Francisco J.; Osuna, Pedro

2015-04-01

Extensive field measurements of wind waves in deep waters in the Gulf of Mexico and Caribbean Sea, have been analyzed to describe the spatial structure of directional wave spectra during hurricane conditions. Following Esquivel-Trava et al. (2015) this analysis was made for minor hurricanes (categories 1 and 2) and major hurricanes (categories 3, 4 and 5). In both cases the directionality of the energy wave spectrum is similar in all quadrants. Some differences are observed however, and they are associated with the presence and the shape of swell energy in each quadrant. Three numerical experiments using the spectral wave prediction model SWAN were carried out to gain insight into the mechanism that controls the directional and frequency distributions of hurricane wave energy. The aim of the experiments is to evaluate the effect of the translation speed of the hurricane and the presence of concentric eye walls, on both the wave growth process and the shape of the directional wave spectrum. The HRD wind field of Hurricane Dean on August 20 at 7:30 was propagated at two different velocities (5 and 10 m/s). An idealized concentric eye wall (a Gaussian function that evolve in time along a path in the form of an Archimedean spiral) was imposed to the wind field. The white-capping formulation of Westhuysen et al. (2007) was selected. The wave model represents fairly well the directionality of the energy and the shape of the directional spectra in the hurricane domain. The model results indicate that the forward movement of the storm influences the development of the waves, consistent with field observations. This work has been supported by CONACYT scholarship 164510 and projects RugDisMar (155793), CB-2011-01-168173 and the Department of Physical Oceanography of CICESE. References Esquivel-Trava, B., Ocampo-Torres, F. J., & Osuna, P. (2015). Spatial structure of directional wave spectra in hurricanes. Ocean Dynam., 65(1), 65-76. doi:10.1007/s10236-014-0791-9 Van der

Spectral analysis and classification of igneous and metamorphic rocks of Hamedan region for remote sensing studies; using laboratory reflectance spectra (350-2500 nm)

International Nuclear Information System (INIS)

Rangzan, K.; Saki, A.; Hassanshahi, H.; Mojaradi, B.

2012-01-01

Reflectance spectrometry techniques with the integration of remote sensing data help us in identifying and mapping the phenomena on the earth. Using these techniques to discriminate the petrologic units independently and without knowing the spectral behavior of rocks along the electromagnetic wavelengths can not be so much useful. For the purposes of this study, 65 samples of igneous and metamorphic rocks from Hamedan region were collected and their spectra were measured using Fieldspec3 device in laboratory. The spectra were analyzed on the basis of absorption, position and shape. Petrographic analyses were used to interpret the absorption patterns as well. Then the spectra were classified according to spectral patterns. This measurement was done on both freshly cut and exposed surfaces of the samples and except a few samples, the two sets of spectra did not differ significantly. Finally, to evaluate the possibility of recognition of these targets, the responses of two hyper spectral and multispectral sensors were simulated from spectra representative of the spectral classes, showing that significant identification and classification of well exposed rocks are potentially possible using remote instruments providing high quality spectra. Also Aster simulation showed that a preliminary gross discrimination of rocks was however possible.

Portable instrument that integrates irradiation with fluorescence and reflectance spectroscopies during clinical photodynamic therapy of cutaneous disease

Science.gov (United States)

Cottrell, W. J.; Oseroff, A. R.; Foster, T. H.

2006-06-01

We report a portable clinical instrument for delivering photodynamic therapy (PDT) while performing noninvasive spectroscopic monitoring in vivo. Using an off-surface probe, the instrument delivers the treatment beam to a user-defined field on the skin and performs reflectance and fluorescence spectroscopies at two regions within this field. The instrument is being used to monitor photosensitizer fluorescence photobleaching, fluorescent photoproduct kinetics, blood volume, and hemoglobin oxygen saturation during a pilot clinical trial of 5-aminolevulinic acid-PDT treatment of superficial basal cell carcinoma (BCC). Protoporphyrin IX and photoproduct fluorescence excited by the 633nm PDT treatment laser is collected between 655 and 800nm. During a series of brief treatment interruptions at programable time points, white light reflectance spectra between 475 and 800nm are acquired. Fluorescence spectra are corrected for the effects of absorption and scattering, informed by the reflectance measurements, and then decomposed into known fluorophore contributions in real time using a robust singular value decomposition fitting routine. Reflectance spectra additionally provide information on blood volume and hemoglobin oxygen saturation. Monitoring blood oxygenation and implicit dose metrics such as photosensitizer photobleaching during PDT allows the improved interpretation of clinical results and is helping to guide the treatment protocol for an anticipated low-irradiance PDT clinical trial of BCC.

Automated Endmember Selection for Nonlinear Unmixing of Lunar Spectra

Science.gov (United States)

Felder, M. P.; Grumpe, A.; Wöhler, C.; Mall, U.

2013-09-01

An important aspect of the analysis of remotely sensed lunar reflectance spectra is their decomposition into intimately mixed constituents. While some methods rely on unmixing of the observed reflectance spectra [1] or on the identification of minerals by extracting the depths and positions of mineral-specific absorption troughs [2, 3], these approaches do not allow for an automated selection of the (a priori unknown) endmembers from a large set of possible constituents. In this study, a non-linear spectral unmixing approach combined with an automated endmember selection scheme is proposed. This method is applied to reflectance spectra of the SIR-2 point spectrometer [4] carried by the Chandrayaan-1 spacecraft.

Frustrated antiferromagnets at high fields: Bose-Einstein condensation in degenerate spectra

International Nuclear Information System (INIS)

Jackeli, G.; Zhitomirsky, M.E.

2004-01-01

Quantum phase transition at the saturation field is studied for a class of frustrated quantum antiferromagnets. The considered models include (i) the J 1 -J 2 frustrated square-lattice antiferromagnet with J 2 =(1/2)J 1 and (ii) the nearest-neighbor Heisenberg antiferromagnet on a face centered cubic lattice. In the fully saturated phase the magnon spectra for the two models have lines of degenerate minima. Transition into a partially magnetized state is treated via a mapping to a dilute gas of hard-core bosons and by complementary spin-wave calculations. Momentum dependence of the exact four-point boson vertex removes the degeneracy of the single-particle excitation spectra and selects the ordering wave vectors at (π,π) and (π,0,0) for the two models. We predict a unique form for the magnetization curve ΔM=S-M≅μ (d-1)/2 (logμ) (d-1) , where μ is a distance from the quantum critical point

Comparison of Measurements and FluorMOD Simulations for Solar Induced Chlorophyll Fluorescence and Reflectance of a Corn Crop under Nitrogen Treatments [SIF and Reflectance for Corn

Science.gov (United States)

Middleton, Elizabeth M.; Corp, Lawrence A.; Campbell, Petya K. E.

2007-01-01

The FLuorescence Explorer (FLEX) satellite concept is one of six semifinalist mission proposals selected in 2006 for pre-Phase studies by the European Space Agency (ESA). The FLEX concept proposes to measure passive solar induced chlorophyll fluorescence (SIF) of terrestrial ecosystems. A new spectral vegetation Fluorescence Model (FluorMOD) was developed to include the effects of steady state SIF on canopy reflectance. We used our laboratory and field measurements previously acquired from foliage and canopies of corn (Zea mays L.) under controlled nitrogen (N) fertilization to parameterize and evaluate FluorMOD. Our data included biophysical properties, fluorescence (F) and reflectance spectra for leaves; reflectance spectra of canopies and soil; solar irradiance; plot-level leaf area index; and canopy SIF emissions determined using the Fraunhofer Line Depth principal for the atmospheric telluric oxygen absorption features at 688 nm (O2-beta) and 760 nm (O2-alpha). FluorMOD simulations implemented in the default "look-up-table" mode did not reproduce the observed magnitudes of leaf F, canopy SIF, or canopy reflectance. However, simulations for all of these parameters agreed with observations when the default FluorMOD information was replaced with measurements, although N treatment responses were underestimated. Recommendations were provided to enhance FluorMOD's potential utility in support of SIF field experiments and studies of agriculture and ecosystems.

The effects of pseudo magnetic fields in molecular spectra and scattering

International Nuclear Information System (INIS)

Kendrick, B.K.

1996-01-01

Pseudo magnetic fields appear in the Born-Oppenheimer method for molecules when conical intersections or electronic angular momenta are taken into account. These fields are not real magnetic fields but they have the same mathematical properties and can lead to real observable effects in the dynamics of molecules. A general vector potential (gauge theory) approach for including these field effects in the Born-Oppenheimer method is introduced and applied to H + O 2 scattering and the vibrational spectrum of Na 3 (X) for zero total angular momentum (J = 0). The scattering results for HO 2 show significant shifts in the resonance energies and lifetimes due to a magnetic solenoid type field originating from the C 2v conical intersection in HO 2 . Significant changes in the state-to-state transition probabilities are also observed. The non-degenerate A 1 and A 2 vibrational spectra of Na 3 (X) show significant shifts in the energy levels due to a magnetic solenoid type field originating from the D 3h conical intersection in Na 3 . These two examples show that the effects of pseudo magnetic fields can be significant and in many cases they must be included in order to obtain agreement between theory and experiment. The newly developed gauge theory techniques for treating pseudo magnetic fields are also relevant for including the effects of real magnetic fields

Research advances in reflectance spectra of plant leafs

Science.gov (United States)

Zhu, Taotao; Yang, Ting; Guo, Yanxin; Xu, Jingqi; Chang, Wandong; Fang, Siyi; Zhu, Kangkang; Xu, Tingyan

2018-02-01

Leaves are an important factor when we study plants because their water content, pigment content and nutrient content of leaves can reflect the current growth status of the whole plant. The methods of spectral diagnosis technology or image technology mainly are the pre-detection technique which can be used to invert the color, texture and spectral reflectance of the leaves. From this we can obtain the changes of the internal components and the external morphological characteristics of the plant leaves in different states changes. In this paper, the reflection spectral response mechanism of plant water content, pigment and nutrient elements at domestic and overseas are reviewed and compared.

Compilation of neutron flux density spectra and reaction rates in different neutron fields. V.3

International Nuclear Information System (INIS)

Ertek, C.

1980-04-01

Upon the recommendation of the International Working Group of Reactor Radiation Measurements (IWGRRM) a compilation of documents containing neutron flux density spectra and the reaction rates obtained by activiation and fission foils in different neutron fields is presented

Ar 3p photoelectron sideband spectra in two-color XUV + NIR laser fields

Science.gov (United States)

Minemoto, Shinichirou; Shimada, Hiroyuki; Komatsu, Kazma; Komatsubara, Wataru; Majima, Takuya; Mizuno, Tomoya; Owada, Shigeki; Sakai, Hirofumi; Togashi, Tadashi; Yoshida, Shintaro; Yabashi, Makina; Yagishita, Akira

2018-04-01

We performed photoelectron spectroscopy using femtosecond XUV pulses from a free-electron laser and femtosecond near-infrared pulses from a synchronized laser, and succeeded in measuring Ar 3p photoelectron sideband spectra due to the two-color above-threshold ionization. In our calculations of the first-order time-dependent perturbation theoretical model based on the strong field approximation, the photoelectron sideband spectra and their angular distributions are well reproduced by considering the timing jitter between the XUV and the NIR pulses, showing that the timing jitter in our experiments was distributed over the width of {1.0}+0.4-0.2 ps. The present approach can be used as a method to evaluate the timing jitter inevitable in FEL experiments.

Interference spectra induced by a bichromatic field in the excited state of a three-level atom

International Nuclear Information System (INIS)

Mavroyannis, C.

1998-01-01

The interference spectra for the excited state of a three-level atom have been considered, where the strong and the weak atomic transitions leading to an electric dipole allowed excited state and to a metastable excited state are driven by resonant and nonresonant laser fields, respectively. In the low intensity limit of the strong laser field, there are two short lifetime excitations, the spontaneous one described by the weak signal field and the one induced by the strong laser field, both of which appear at the same frequency, and a long lifetime excitation induced by the weak laser field. The maximum intensities (heights) of the two peaks describing the short lifetime excitations take equal positive and negative values and, therefore, cancel each other out completely, while the long lifetime excitation dominates. This indicates the disappearance of the short lifetime excitations describing the strong atomic transition for a period equal to the lifetime of the long lifetime excitation, which is roughly equal to half of the lifetime of the metastable state. The computed spectra have been graphically presented and discussed at resonance and for finite detunings. (Copyright (c) 1998 Elsevier Science B.V., Amsterdam. All rights reserved.)

Low-energy photons in high-energy photon fields--Monte Carlo generated spectra and a new descriptive parameter.

Science.gov (United States)

Chofor, Ndimofor; Harder, Dietrich; Willborn, Kay; Rühmann, Antje; Poppe, Björn

2011-09-01

The varying low-energy contribution to the photon spectra at points within and around radiotherapy photon fields is associated with variations in the responses of non-water equivalent dosimeters and in the water-to-material dose conversion factors for tissues such as the red bone marrow. In addition, the presence of low-energy photons in the photon spectrum enhances the RBE in general and in particular for the induction of second malignancies. The present study discusses the general rules valid for the low-energy spectral component of radiotherapeutic photon beams at points within and in the periphery of the treatment field, taking as an example the Siemens Primus linear accelerator at 6 MV and 15 MV. The photon spectra at these points and their typical variations due to the target system, attenuation, single and multiple Compton scattering, are described by the Monte Carlo method, using the code BEAMnrc/EGSnrc. A survey of the role of low energy photons in the spectra within and around radiotherapy fields is presented. In addition to the spectra, some data compression has proven useful to support the overview of the behaviour of the low-energy component. A characteristic indicator of the presence of low-energy photons is the dose fraction attributable to photons with energies not exceeding 200 keV, termed P(D)(200 keV). Its values are calculated for different depths and lateral positions within a water phantom. For a pencil beam of 6 or 15 MV primary photons in water, the radial distribution of P(D)(200 keV) is bellshaped, with a wide-ranging exponential tail of half value 6 to 7 cm. The P(D)(200 keV) value obtained on the central axis of a photon field shows an approximately proportional increase with field size. Out-of-field P(D)(200 keV) values are up to an order of magnitude higher than on the central axis for the same irradiation depth. The 2D pattern of P(D)(200 keV) for a radiotherapy field visualizes the regions, e.g. at the field margin, where changes of

Intrinsic dendritic filtering gives low-pass power spectra of local field potentials

DEFF Research Database (Denmark)

Lindén, Henrik; Pettersen, Klas H; Einevoll, Gaute T

2010-01-01

of contributions to the LFP from a single layer-5 pyramidal neuron and a single layer-4 stellate neuron receiving synaptic input. An intrinsic dendritic low-pass filtering effect of the LFP signal, previously demonstrated for extracellular signatures of action potentials, is seen to strongly affect the LFP power...... spectra, even for frequencies as low as 10 Hz for the example pyramidal neuron. Further, the LFP signal is found to depend sensitively on both the recording position and the position of the synaptic input: the LFP power spectra recorded close to the active synapse are typically found to be less low......The local field potential (LFP) is among the most important experimental measures when probing neural population activity, but a proper understanding of the link between the underlying neural activity and the LFP signal is still missing. Here we investigate this link by mathematical modeling...

Stationary bound-state massive scalar field configurations supported by spherically symmetric compact reflecting stars

Energy Technology Data Exchange (ETDEWEB)

Hod, Shahar [The Ruppin Academic Center, Emeq Hefer (Israel); The Hadassah Academic College, Jerusalem (Israel)

2017-12-15

It has recently been demonstrated that asymptotically flat neutral reflecting stars are characterized by an intriguing no-hair property. In particular, it has been proved that these horizonless compact objects cannot support spatially regular static matter configurations made of scalar (spin-0) fields, vector (spin-1) fields and tensor (spin-2) fields. In the present paper we shall explicitly prove that spherically symmetric compact reflecting stars can support stationary (rather than static) bound-state massive scalar fields in their exterior spacetime regions. To this end, we solve analytically the Klein-Gordon wave equation for a linearized scalar field of mass μ and proper frequency ω in the curved background of a spherically symmetric compact reflecting star of mass M and radius R{sub s}. It is proved that the regime of existence of these stationary composed star-field configurations is characterized by the simple inequalities 1 - 2M/R{sub s} < (ω/μ){sup 2} < 1. Interestingly, in the regime M/R{sub s} << 1 of weakly self-gravitating stars we derive a remarkably compact analytical equation for the discrete spectrum {ω(M,R_s, μ)}{sup n=∞}{sub n=1} of resonant oscillation frequencies which characterize the stationary composed compact-reflecting-star-linearized-massive-scalar-field configurations. Finally, we verify the accuracy of the analytically derived resonance formula of the composed star-field configurations with direct numerical computations. (orig.)

Reflectance Spectra Diversity of Silica-Rich Materials: Sensitivity to Environment and Implications for Detections on Mars

Science.gov (United States)

Rice, M. S.; Cloutis, E. A.; Bell, J. F., III; Bish, D. L.; Horgan, B. H.; Mertzman, S. A.; Craig, M. A.; Renault, R. W.; Gautason, B.; Mountain, B.

2013-01-01

Hydrated silica-rich materials have recently been discovered on the surface of Mars by the Mars Exploration Rover (MER) Spirit, the Mars Reconnaissance Orbiter (MRO) Compact Reconnaissance Imaging Spectrometer for Mars (CRISM), and the Mars Express Observatoire pour la Mineralogie, l'Eau, les Glaces, et l'Activite'(OMEGA) in several locations. Having been interpreted as hydrothermal deposits and aqueous alteration products, these materials have important implications for the history of water on the martian surface. Spectral detections of these materials in visible to near infrared (Vis NIR) wavelengths have been based on a H2O absorption feature in the 934-1009 nm region seen with Spirit s Pancam instrument, and on SiOH absorption features in the 2.21-2.26 micron range seen with CRISM. Our work aims to determine how the spectral reflectance properties of silica-rich materials in Vis NIR wavelengths vary as a function of environmental conditions and formation. Here we present laboratory reflectance spectra of a diverse suite of silica-rich materials (chert, opal, quartz, natural sinters and synthetic silica) under a range of grain sizes and temperature, pressure, and humidity conditions. We find that the H2O content and form of H2O/OH present in silica-rich materials can have significant effects on their Vis NIR spectra. Our main findings are that the position of the approx.1.4 microns OH feature and the symmetry of the approx.1.9 microns feature can be used to discern between various forms of silica-rich materials, and that the ratio of the approx.2.2 microns (SiOH) and approx.1.9 microns (H2O) band depths can aid in distinguishing between silica phases (opal-A vs. opal-CT) and formation conditions (low vs. high temperature). In a case study of hydrated silica outcrops in Valles Marineris, we show that careful application of a modified version of these spectral parameters to orbital near-infrared spectra (e.g., from CRISM and OMEGA) can aid in characterizing the

Field-scale sensitivity of vegetation discrimination to hyperspectral reflectance and coupled statistics

DEFF Research Database (Denmark)

Manevski, Kiril; Jabloun, Mohamed; Gupta, Manika

2016-01-01

a more powerful input to a nonparametric analysis for discrimination at the field scale, when compared with unaltered reflectance and parametric analysis. However, the discrimination outputs interact and are very sensitive to the number of observations - an important implication for the design......Remote sensing of land covers utilizes an increasing number of methods for spectral reflectance processing and its accompanying statistics to discriminate between the covers’ spectral signatures at various scales. To this end, the present chapter deals with the field-scale sensitivity...... of the vegetation spectral discrimination to the most common types of reflectance (unaltered and continuum-removed) and statistical tests (parametric and nonparametric analysis of variance). It is divided into two distinct parts. The first part summarizes the current knowledge in relation to vegetation...

Scientific information repository assisting reflectance spectrometry in legal medicine.

Science.gov (United States)

Belenki, Liudmila; Sterzik, Vera; Bohnert, Michael; Zimmermann, Klaus; Liehr, Andreas W

2012-06-01

Reflectance spectrometry is a fast and reliable method for the characterization of human skin if the spectra are analyzed with respect to a physical model describing the optical properties of human skin. For a field study performed at the Institute of Legal Medicine and the Freiburg Materials Research Center of the University of Freiburg, a scientific information repository has been developed, which is a variant of an electronic laboratory notebook and assists in the acquisition, management, and high-throughput analysis of reflectance spectra in heterogeneous research environments. At the core of the repository is a database management system hosting the master data. It is filled with primary data via a graphical user interface (GUI) programmed in Java, which also enables the user to browse the database and access the results of data analysis. The latter is carried out via Matlab, Python, and C programs, which retrieve the primary data from the scientific information repository, perform the analysis, and store the results in the database for further usage.

Spectral reflectance properties of carbonaceous chondrites: 1. CI chondrites

Science.gov (United States)

Cloutis, E. A.; Hiroi, T.; Gaffey, M. J.; Alexander, C. M. O.'D.; Mann, P.

2011-03-01

Existing reflectance spectra of CI chondrites (18 spectra of 3 CIs) have been augmented with new (18 spectra of 2 CIs) reflectance spectra to ascertain the spectral variability of this meteorite class and provide insights into their spectral properties as a function of grain size, composition, particle packing, and viewing geometry. Particle packing and viewing geometry effects have not previously been examined for CI chondrites. The current analysis is focused on the 0.3-2.5 μm interval, as this region is available for the largest number of CI spectra. Reflectance spectra of powdered CI1 chondrites are uniformly dark (IOM), as no other CI opaque phase appears able to produce concurrent darkening and bluing. Magnetite can also explain the presence of an absorption feature near 1 μm in some CI spectra. The most blue-sloped spectra are generally associated with the larger grain size samples. For incidence and emission angles <60°, increasing phase angle results in darker and redder spectra, particularly below ∼1 μm. At high incidence angles (60°), increasing emission angle results in brighter and redder spectra. More densely packed samples and underdense (fluffed) samples show lower overall reflectance than normally packed and flat-surface powdered samples. Some B-class asteroids exhibit selected spectral properties consistent with CI chondrites, although perfect spectral matches have not been found. Because many CI chondrite spectra exhibit absorption features that can be related to specific mineral phases, the search for CI parent bodies can fruitfully be conducted using such parameters.

Mercury's Surface Magnetic Field Determined from Proton-Reflection Magnetometry

Science.gov (United States)

Winslow, Reka M.; Johnson, Catherine L.; Anderson, Brian J.; Gershman, Daniel J.; Raines, Jim M.; Lillis, Robert J.; Korth, Haje; Slavin, James A.; Solomon, Sean C.; Zurbuchen, Thomas H.;

Multiplexing 32,000 spectra onto 8 detectors: the HARMONI field splitting, image slicing, and wavelength selecting optics

Science.gov (United States)

Tecza, Matthias; Thatte, Niranjan; Clarke, Fraser; Freeman, David; Kosmalski, Johan

2012-09-01

HARMONI, the High Angular Resolution Monolithic Optical & Near-infrared Integral field spectrograph is one of two first-light instruments for the European Extremely Large Telescope. Over a 256x128 pixel field-of-view HARMONI will simultaneously measure approximately 32,000 spectra. Each spectrum is about 4000 spectral pixels long, and covers a selectable part of the 0.47-2.45 μm wavelength range at resolving powers of either R≍4000, 10000, or 20000. All 32,000 spectra are imaged onto eight HAWAII4RG detectors using a multiplexing scheme that divides the input field into four sub-fields, each imaged onto one image slicer that in turn re-arranges a single sub-field into two long exit slits feeding one spectrograph each. In total we require eight spectrographs, each with one HAWAII4RG detector. A system of articulated and exchangeable fold-mirrors and VPH gratings allows one to select different spectral resolving powers and wavelength ranges of interest while keeping a fixed geometry between the spectrograph collimator and camera avoiding the need for an articulated grating and camera. In this paper we describe both the field splitting and image slicing optics as well as the optics that will be used to select both spectral resolving power and wavelength range.

Scaling plant ultraviolet spectral responses from laboratory action spectra to field spectral weighting factors

International Nuclear Information System (INIS)

Flint, S.D.; Caldwell, M.M.

1996-01-01

Biological spectral weighting functions (BSWF) play a key role in calculating the increase of biologically effective solar ultraviolet-B radiation (UV-BBE) due to ozone reduction, assessing current latitudinal gradients of UV-B BE . and comparing solar UV-B BE with that from lamps and filters in plant experiments. Plant UV action spectra (usually determined with monochromatic radiation in the laboratory with exposure periods on the order of hours) are often used as BSWF. The realism of such spectra for plants growing day after day in polychromatic solar radiation in the field is questionable. We tested the widely used generalized plant action spectrum since preliminary data from an action spectrum being developed with monochromatic radiation for a cultivated oat variety indicate reasonable agreement with the generalized spectrum. These tests involved exposing plants to polychromatic radiation either from a high-pressure xenon arc lamp in growth chambers or in the field under solar radiation with supplemental UV-B lamps. Different broad-spectrum combinations were achieved by truncating the spectrum at successively longer UV wavelengths with various filters. In the growth chamber experiments, the generalized plant spectrum appeared to predict plant growth responses at short (<310nm) wavelengths but not at longer wavelengths. The field experiment reinforced these conclusions, showing (in addition to the expected direct UV-B effects) both direct UV-A effects and UV-A mitigation of UV-B effects. (author)

Reconstruction of signals with unknown spectra in information field theory with parameter uncertainty

International Nuclear Information System (INIS)

Ensslin, Torsten A.; Frommert, Mona

2011-01-01

The optimal reconstruction of cosmic metric perturbations and other signals requires knowledge of their power spectra and other parameters. If these are not known a priori, they have to be measured simultaneously from the same data used for the signal reconstruction. We formulate the general problem of signal inference in the presence of unknown parameters within the framework of information field theory. To solve this, we develop a generic parameter-uncertainty renormalized estimation (PURE) technique. As a concrete application, we address the problem of reconstructing Gaussian signals with unknown power-spectrum with five different approaches: (i) separate maximum-a-posteriori power-spectrum measurement and subsequent reconstruction, (ii) maximum-a-posteriori reconstruction with marginalized power-spectrum, (iii) maximizing the joint posterior of signal and spectrum, (iv) guessing the spectrum from the variance in the Wiener-filter map, and (v) renormalization flow analysis of the field-theoretical problem providing the PURE filter. In all cases, the reconstruction can be described or approximated as Wiener-filter operations with assumed signal spectra derived from the data according to the same recipe, but with differing coefficients. All of these filters, except the renormalized one, exhibit a perception threshold in case of a Jeffreys prior for the unknown spectrum. Data modes with variance below this threshold do not affect the signal reconstruction at all. Filter (iv) seems to be similar to the so-called Karhune-Loeve and Feldman-Kaiser-Peacock estimators for galaxy power spectra used in cosmology, which therefore should also exhibit a marginal perception threshold if correctly implemented. We present statistical performance tests and show that the PURE filter is superior to the others, especially if the post-Wiener-filter corrections are included or in case an additional scale-independent spectral smoothness prior can be adopted.

On the tunneling of full-vector X-Waves through a slab under frustrated total reflection condition

KAUST Repository

Salem, Mohamed; Bagci, Hakan

2012-01-01

Tunneling of full-vector X-Waves through a dielectric slab under frustrated total reflection condition is investigated. Full-vector X-Waves are obtained by superimposing transverse electric and magnetic polarization components, which are derived from the scalar X-Wave solution. The analysis of reflection and transmission at the dielectric interfaces is carried out analytically in a straightforward fashion using vector Bessel beam expansion. Investigation of the fields propagating away from the farther end of the slab (transmitted fields) shows an advanced (superluminal) transmission of the X-Wave peak. Additionally, a similar advanced reflection is also observed. The apparent tunneling of the peak is shown to be due to the phase shift in the fields' spectra and not to be causally related to the incident peak. © 2012 IEEE.

On the tunneling of full-vector X-Waves through a slab under frustrated total reflection condition

KAUST Repository

Salem, Mohamed

2012-07-01

Tunneling of full-vector X-Waves through a dielectric slab under frustrated total reflection condition is investigated. Full-vector X-Waves are obtained by superimposing transverse electric and magnetic polarization components, which are derived from the scalar X-Wave solution. The analysis of reflection and transmission at the dielectric interfaces is carried out analytically in a straightforward fashion using vector Bessel beam expansion. Investigation of the fields propagating away from the farther end of the slab (transmitted fields) shows an advanced (superluminal) transmission of the X-Wave peak. Additionally, a similar advanced reflection is also observed. The apparent tunneling of the peak is shown to be due to the phase shift in the fields\\' spectra and not to be causally related to the incident peak. © 2012 IEEE.

Combined reflection and transmission microscope for telemedicine applications in field settings

OpenAIRE

Biener, Gabriel; Greenbaum, Alon; Isikman, Serhan O.; Lee, Kelvin; Tseng, Derek; Ozcan, Aydogan

2011-01-01

We demonstrate a field-portable upright and inverted microscope that can image specimens in both reflection and transmission modes. This compact and cost-effective dual-mode microscope weighs only ~135 grams (

Clinical system model for monitoring the physiological status of jaundice by extracting bilirubin components from skin diffuse reflectance spectra

Science.gov (United States)

Kumar, Alla S.; Clark, Joseph; Beyette, Fred R., Jr.

2009-02-01

Neonatal jaundice is a medical condition which occurs in newborns as a result of an imbalance between the production and elimination of bilirubin. The excess bilirubin in the blood stream diffuses into the surrounding tissue leading to a yellowing of the skin. As the bilirubin levels rise in the blood stream, there is a continuous exchange between the extra vascular bilirubin and bilirubin in the blood stream. Exposure to phototherapy alters the concentration of bilirubin in the vascular and extra vascular regions by causing bilirubin in the skin layers to be broken down. Thus, the relative concentration of extra vascular bilirubin is reduced leading to a diffusion of bilirubin out of the vascular region. Diffuse reflectance spectra from human skin contains physiological and structural information of the skin and nearby tissue. A diffuse reflectance spectrum must be captured before and after blanching in order to isolate the intravascular and extra vascular bilirubin. A new mathematical model is proposed with extra vascular bilirubin concentration taken into consideration along with other optical parameters in defining the diffuse reflectance spectrum from human skin. A nonlinear optimization algorithm has been adopted to extract the optical properties (including bilirubin concentration) from the skin reflectance spectrum. The new system model and nonlinear algorithm have been combined to enable extraction of Bilirubin concentrations within an average error of 10%.

Maturation of EEG Power Spectra in Early Adolescence: A Longitudinal Study

Science.gov (United States)

Cragg, Lucy; Kovacevic, Natasa; McIntosh, Anthony Randal; Poulsen, Catherine; Martinu, Kristina; Leonard, Gabriel; Paus, Tomas

2011-01-01

This study investigated the fine-grained development of the EEG power spectra in early adolescence, and the extent to which it is reflected in changes in peak frequency. It also sought to determine whether sex differences in the EEG power spectra reflect differential patterns of maturation. A group of 56 adolescents were tested at age 10 years and…

A singularity extraction technique for computation of antenna aperture fields from singular plane wave spectra

DEFF Research Database (Denmark)

Cappellin, Cecilia; Breinbjerg, Olav; Frandsen, Aksel

2008-01-01

An effective technique for extracting the singularity of plane wave spectra in the computation of antenna aperture fields is proposed. The singular spectrum is first factorized into a product of a finite function and a singular function. The finite function is inverse Fourier transformed...... numerically using the Inverse Fast Fourier Transform, while the singular function is inverse Fourier transformed analytically, using the Weyl-identity, and the two resulting spatial functions are then convolved to produce the antenna aperture field. This article formulates the theory of the singularity...

Pedagogical Souvenirs: An Art Educator's Reflections on Field Trips as Professional Development

Science.gov (United States)

Kushins, Jodi

2015-01-01

This essay explores the nature and importance of field trips as sites for artistic development, intellectual fulfillment, and pedagogical inspiration. The author weaves personal reflections from a professional field trip and experience teaching art education online with creative and pedagogical references to make a case for experiential learning…

Near-field/far-field array manifold of an acoustic vector-sensor near a reflecting boundary.

Science.gov (United States)

Wu, Yue Ivan; Lau, Siu-Kit; Wong, Kainam Thomas

2016-06-01

The acoustic vector-sensor (a.k.a. the vector hydrophone) is a practical and versatile sound-measurement device, with applications in-room, open-air, or underwater. It consists of three identical uni-axial velocity-sensors in orthogonal orientations, plus a pressure-sensor-all in spatial collocation. Its far-field array manifold [Nehorai and Paldi (1994). IEEE Trans. Signal Process. 42, 2481-2491; Hawkes and Nehorai (2000). IEEE Trans. Signal Process. 48, 2981-2993] has been introduced into the technical field of signal processing about 2 decades ago, and many direction-finding algorithms have since been developed for this acoustic vector-sensor. The above array manifold is subsequently generalized for outside the far field in Wu, Wong, and Lau [(2010). IEEE Trans. Signal Process. 58, 3946-3951], but only if no reflection-boundary is to lie near the acoustic vector-sensor. As for the near-boundary array manifold for the general case of an emitter in the geometric near field, the far field, or anywhere in between-this paper derives and presents that array manifold in terms of signal-processing mathematics. Also derived here is the corresponding Cramér-Rao bound for azimuth-elevation-distance localization of an incident emitter, with the reflected wave shown to play a critical role on account of its constructive or destructive summation with the line-of-sight wave. The implications on source localization are explored, especially with respect to measurement model mismatch in maximum-likelihood direction finding and with regard to the spatial resolution between coexisting emitters.

Analysis of Electric Field Propagation in Anisotropically Absorbing and Reflecting Waveplates

Science.gov (United States)

Carnio, B. N.; Elezzabi, A. Y.

2018-04-01

Analytical expressions are derived for half-wave plates (HWPs) and quarter-wave plates (QWPs) based on uniaxial crystals. This general analysis describes the behavior of anisotropically absorbing and reflecting waveplates across the electromagnetic spectrum, which allows for correction to the commonly used equations determined assuming isotropic absorptions and reflections. This analysis is crucial to the design and implementation of HWPs and QWPs in the terahertz regime, where uniaxial crystals used for waveplates are highly birefringent and anisotropically absorbing. The derived HWP equations describe the rotation of linearly polarized light by an arbitrary angle, whereas the QWP analysis focuses on manipulating a linearly polarized electric field to obtain any ellipticity. The HWP and QWP losses are characterized by determining equations for the total electric field magnitude transmitted through these phase-retarding elements.

Testing electric field models using ring current ion energy spectra from the Equator-S ion composition (ESIC instrument

Directory of Open Access Journals (Sweden)

L. M. Kistler

Full Text Available During the main and early recovery phase of a geomagnetic storm on February 18, 1998, the Equator-S ion composition instrument (ESIC observed spectral features which typically represent the differences in loss along the drift path in the energy range (5–15 keV/e where the drift changes from being E × B dominated to being gradient and curvature drift dominated. We compare the expected energy spectra modeled using a Volland-Stern electric field and a Weimer electric field, assuming charge exchange along the drift path, with the observed energy spectra for H⁺ and O⁺. We find that using the Weimer electric field gives much better agreement with the spectral features, and with the observed losses. Neither model, however, accurately predicts the energies of the observed minima.

Key words. Magnetospheric physics (energetic particles trapped; plasma convection; storms and substorms

SVBRDF-Invariant Shape and Reflectance Estimation from a Light-Field Camera.

Science.gov (United States)

Wang, Ting-Chun; Chandraker, Manmohan; Efros, Alexei A; Ramamoorthi, Ravi

2018-03-01

Light-field cameras have recently emerged as a powerful tool for one-shot passive 3D shape capture. However, obtaining the shape of glossy objects like metals or plastics remains challenging, since standard Lambertian cues like photo-consistency cannot be easily applied. In this paper, we derive a spatially-varying (SV)BRDF-invariant theory for recovering 3D shape and reflectance from light-field cameras. Our key theoretical insight is a novel analysis of diffuse plus single-lobe SVBRDFs under a light-field setup. We show that, although direct shape recovery is not possible, an equation relating depths and normals can still be derived. Using this equation, we then propose using a polynomial (quadratic) shape prior to resolve the shape ambiguity. Once shape is estimated, we also recover the reflectance. We present extensive synthetic data on the entire MERL BRDF dataset, as well as a number of real examples to validate the theory, where we simultaneously recover shape and BRDFs from a single image taken with a Lytro Illum camera.

Minimal BRDF Sampling for Two-Shot Near-Field Reflectance Acquisition

DEFF Research Database (Denmark)

Xu, Zexiang; Nielsen, Jannik Boll; Yu, Jiyang

2016-01-01

We develop a method to acquire the BRDF of a homogeneous flat sample from only two images, taken by a near-field perspective camera, and lit by a directional light source. Our method uses the MERL BRDF database to determine the optimal set of lightview pairs for data-driven reflectance acquisition...

Polarised Multiangular Reflectance Measurements Using the Finnish Geodetic Institute Field Goniospectrometer

Directory of Open Access Journals (Sweden)

Jouni Peltoniemi

2009-05-01

Full Text Available The design, operation, and properties of the Finnish Geodetic Institute Field Goniospectrometer (FIGIFIGO are presented. FIGIFIGO is a portable instrument for the measurement of surface Bidirectional Reflectance Factor (BRF for samples with diameters of 10 – 50 cm. A set of polarising optics enable the measurement of linearly polarised BRF over the full solar spectrum (350 – 2,500 nm. FIGIFIGO is designed mainly for field operation using sunlight, but operation in a laboratory environment is also possible. The acquired BRF have an accuracy of 1 – 5% depending on wavelength, sample properties, and measurement conditions. The angles are registered at accuracies better than 2°. During 2004 – 2008, FIGIFIGO has been used in the measurement of over 150 samples, all around northern Europe. The samples concentrate mostly on boreal forest understorey, snow, urban surfaces, and reflectance calibration surfaces.

Investigating the optical modes of InxGa1xN alloy and In0.5Ga0.5N/GaN MQW in far-infrared reflectivity spectra

International Nuclear Information System (INIS)

Mirjalili, G.; Amraei, R.

2006-01-01

Optical properties of In x Ga 1 x N alloy and In 0 .5Ga 0 .5N/GaN multi quantum wells have been investigated in the region of far infrared. Far-IR reflectivity spectra of In 0 .5Ga 0 .5N/GaN multi quantum wells on GaAs substrate have been obtained by oblique incidence p- and s- polarization light using effective medium approximation. The spectra and the dielectric functions response give a good information about the phonon and plasmon contribution in doped MQW as well as the mole fraction of compounds in the alloys. The changes in position of optical modes are good tools for measurement of the amount of free carrier and the amount of mole fraction in the samples. During study of In x Ga 1 x N reflectivity spectra, two distinct reststrahl bands with frequency near those of pure InN and GaN were observed over entire composition range. Each band shifts to lower frequencies and decreases in amplitude as the concentration of corresponding compound in alloy decreased. Analysis of dielectric function gives the TO-like and LO-like mode frequencies. The changes in LO mode frequencies, due to coupling of phonon-plasmon, have been observed

Full-field transmission-type angle-deviation optical microscope with reflectivity-height transformation.

Science.gov (United States)

Chiu, Ming-Hung; Tan, Chen-Tai; Tsai, Ming-Hung; Yang, Ya-Hsin

2015-10-01

This full-field transmission-type three-dimensional (3D) optical microscope is constructed based on the angle deviation method (ADM) and the algorithm of reflectivity-height transformation (RHT). The surface height is proportional to the deviation angle of light passing through the object. The angle deviation and surface height can be measured based on the reflectivity closed to the critical angle using a parallelogram prism and two CCDs.

DEPENDENCE OF SOLAR-WIND POWER SPECTRA ON THE DIRECTION OF THE LOCAL MEAN MAGNETIC FIELD

International Nuclear Information System (INIS)

Podesta, J. J.

2009-01-01

Wavelet analysis can be used to measure the power spectrum of solar-wind fluctuations along a line in any direction (θ, φ) with respect to the local mean magnetic field B 0 . This technique is applied to study solar-wind turbulence in high-speed streams in the ecliptic plane near solar minimum using magnetic field measurements with a cadence of eight vectors per second. The analysis of nine high-speed streams shows that the reduced spectrum of magnetic field fluctuations (trace power) is approximately azimuthally symmetric about B 0 in both the inertial range and dissipation range; in the inertial range the spectra are characterized by a power-law exponent that changes continuously from 1.6 ± 0.1 in the direction perpendicular to the mean field to 2.0 ± 0.1 in the direction parallel to the mean field. The large uncertainties suggest that the perpendicular power-law indices 3/2 and 5/3 are both consistent with the data. The results are similar to those found by Horbury et al. at high heliographic latitudes. Comparisons between solar-wind observations and the theories of strong incompressible MHD turbulence developed by Goldreich and Sridhar and Boldyrev are not rigorously justified because these theories only apply to turbulence with vanishing cross-helicity although the normalized cross-helicity of solar-wind turbulence is not negligible. Assuming these theories can be generalized in such a way that the three-dimensional wavevector spectra have similar functional forms when the cross-helicity is nonzero, then for the interval of Ulysses data analyzed by Horbury et al. the ratio of the spectra perpendicular and parallel to B 0 is more consistent with the Goldreich and Sridhar scaling P perpendicular /P || ∝ ν 1/3 than with the Boldyrev scaling ν 1/2 . The analysis of high-speed streams in the ecliptic plane does not yield a reliable measurement of this scaling law. The transition from a turbulent MHD-scale energy cascade to a kinetic Alfven wave (KAW

Longitudinal correlation properties of an optical field with broad angular and frequency spectra and their manifestation in interference microscopy

International Nuclear Information System (INIS)

Lyakin, D V; Ryabukho, V P

2013-01-01

The results of theoretical and experimental studies of the longitudinal correlation properties of an optical field with broad angular and frequency spectra and manifestations of these properties in interference microscopy are presented. The joint and competitive influence of the angular and frequency spectra of the object-probing field on the longitudinal resolution and on the amplitude of the interference microscope signals from the interfaces between the media inside a multilayer object is demonstrated. The method of compensating the so-called defocusing effect that arises in the interference microscopy using objectives with a large numerical aperture is experimentally demonstrated, which consists in using as a light source in the interference microscope an illuminating interferometer with a frequency-broadband light source. This method of compensation may be used as the basis of simultaneous determination of geometric thickness and refractive index of media forming a multilayer object. (optical fields)

Crystallographically-based analysis of the NMR spectra of maghemite

International Nuclear Information System (INIS)

Spiers, K.M.; Cashion, J.D.

2012-01-01

All possible iron environments with respect to nearest neighbour vacancies in vacancy-ordered and vacancy-disordered maghemite have been evaluated and used as the foundation for a crystallographically-based analysis of the published NMR spectra of maghemite. The spectral components have been assigned to particular configurations and excellent agreement obtained in comparing predicted spectra with published spectra taken in applied magnetic fields. The broadness of the published NMR lines has been explained by calculations of the magnetic dipole fields at the various iron sites and consideration of the supertransferred hyperfine fields. - Highlights: ► Analysis of 57 Fe NMR of maghemite based on vacancy ordering and nearest neighbour vacancies. ► Assignment of NMR spectral components based on crystallographic analysis of unique iron sites. ► Strong agreement between predicted spectra and published spectra taken in applied magnetic fields. ► Maghemite NMR spectral broadening due to various iron sites and supertransferred hyperfine field.

Remote compositional analysis of lunar olivine-rich lithologies with Moon Mineralogy Mapper (M3) spectra

Science.gov (United States)

Isaacson, P.J.; Pieters, C.M.; Besse, S.; Clark, R.N.; Head, J.W.; Klima, R.L.; Mustard, J.F.; Petro, N.E.; Staid, M.I.; Sunshine, J.M.; Taylor, L.A.; Thaisen, K.G.; Tompkins, S.

2011-01-01

A systematic approach for deconvolving remotely sensed lunar olivine-rich visible to near-infrared (VNIR) reflectance spectra with the Modified Gaussian Model (MGM) is evaluated with Chandrayaan-1 Moon Mineralogy Mapper (M 3) spectra. Whereas earlier studies of laboratory reflectance spectra focused only on complications due to chromite inclusions in lunar olivines, we develop a systematic approach for addressing (through continuum removal) the prominent continuum slopes common to remotely sensed reflectance spectra of planetary surfaces. We have validated our continuum removal on a suite of laboratory reflectance spectra. Suites of olivine-dominated reflectance spectra from a small crater near Mare Moscoviense, the Copernicus central peak, Aristarchus, and the crater Marius in the Marius Hills were analyzed. Spectral diversity was detected in visual evaluation of the spectra and was quantified using the MGM. The MGM-derived band positions are used to estimate the olivine's composition in a relative sense. Spectra of olivines from Moscoviense exhibit diversity in their absorption features, and this diversity suggests some variation in olivine Fe/Mg content. Olivines from Copernicus are observed to be spectrally homogeneous and thus are predicted to be more compositionally homogeneous than those at Moscoviense but are of broadly similar composition to the Moscoviense olivines. Olivines from Aristarchus and Marius exhibit clear spectral differences from those at Moscoviense and Copernicus but also exhibit features that suggest contributions from other phases. If the various precautions discussed here are weighed carefully, the methods presented here can be used to make general predictions of absolute olivine composition (Fe/Mg content). Copyright ?? 2011 by the American Geophysical Union.

Vibronic spectra of Gd3+ in metaphosphate glasses: Comparison with Raman and infrared spectra

International Nuclear Information System (INIS)

Hall, D.W.; Brawer, S.A.; Weber, M.J.

1982-01-01

Vibronic sidebands associated with the 6 P/sub 7/2/→ 8 S/sub 7/2/ transition of Gd 3+ -doped metaphosphate glasses are observed using line-narrowed fluorescence techniques. Glasses having metal cations of different mass and charge (La,Al,Mg,Ba) are examined. Vibronic spectra, which probe vibrations about the rare-earth element site, are compared with polarized Raman scattering data and the infrared dielectric constant obtained from near-normal reflectance measurements. Results indicate that in metaphosphate glasses vibronic selection rules are similar to HV (vertical height) Raman selection rules. The wavelengths and relative intensities of peaks in the high-frequency portion of the vibronic spectra change with respect to corresponding peaks in the Raman spectra when the mass and/or charge of Gd 3+ differs significantly from that of the metal cation

Refractive index dependence of Papilio Ulysses butterfly wings reflectance spectra

Science.gov (United States)

Isnaeni, Muslimin, Ahmad Novi; Birowosuto, Muhammad Danang

2016-02-01

We have observed and utilized butterfly wings of Papilio Ulysses for refractive index sensor. We noticed this butterfly wings have photonic crystal structure, which causes blue color appearance on the wings. The photonic crystal structure, which consists of cuticle and air void, is approximated as one dimensional photonic crystal structure. This photonic crystal structure opens potential to several optical devices application, such as refractive index sensor. We have utilized small piece of Papilio Ulysses butterfly wings to characterize refractive index of several liquid base on reflectance spectrum of butterfly wings in the presence of sample liquid. For comparison, we simulated reflectance spectrum of one dimensional photonic crystal structure having material parameter based on real structure of butterfly wings. We found that reflectance spectrum peaks shifted as refractive index of sample changes. Although there is a slight difference in reflectance spectrum peaks between measured spectrum and calculated spectrum, the trend of reflectance spectrum peaks as function of sample's refractive index is the similar. We assume that during the measurement, the air void that filled by sample liquid is expanded due to liquid pressure. This change of void shape causes non-similarity between measured spectrum and calculated spectrum.

Foliar Reflectance and Fluorescence Responses for Corn and Soybean Plants Under Nitrogen Stress

Science.gov (United States)

Middleton, E. M.; Campbell, P. K. Entcheva; Corp, L. A.; Butcher, L. M.; McMurtrey, J. E.

2003-01-01

We are investigating the use of spectral indices derived from actively induced fluorescence spectra and passive optical spectra. We examined the influence of photosynthetic pigment, carbon (C) and nitrogen (N) content on the spectral fluorescence and passive optical property characteristics of mature, upper leaves from plants provided different N fertilizer application rates: 20%, 50%, 100% and 150% of recommended N levels. A suite of optical, fluorescence, and biophysical measurements were collected on leaves from field grown corn (Zea mays L.) and soybean plants (Glycine max L.) grown in pots (greenhouse + ambient sunlight. Steady state laser-induced fluorescence emission spectra (5 nm resolution) were obtained from adaxial and abaxial surfaces resulting from excitation at single wavelengths (280, 380 or 360, and 532 nm). For emission spectra produced by each of these excitation wavelengths, ratios of emission peaks were calculated, including the red far-red chlorophyll fluorescence (ChlF) ratio (F685/F740) and the far-red/green (F740/F525) ratio. High resolution (< 3 nm) optical spectra (350-2500 nm) of reflectance, transmittance, and absorptance were also acquired for both adaxial and abaxial leaf surfaces. Species differences were demonstrated for several optical parameters. A 'red edge' derivative ratio determined from transmittance spectra [as the maximum first deivative, between 650-750 nm, normalized to the value at 744 nm, or Dmax/D744], was strongly associated with the C/N ratio (r(exp 2) = 0.90, P +/- 0.001). This ratio, calculated from reflectance spectra, was inversely related to chlorophyll b content (r(exp 2) = 0.91, P +/- 0.001) as was the ChlF (F685/F740) ratio obtained with 532 nm excitation (r(exp 2) = 0.76, P +/- 0.01). Discrimination of N treatment groups was possible with specific fluorescence band ratios (e.g., F740/F525 obtained with 380 nm excitation). Higher ChlF and blue-green emissions were measured from the abaxial leaf surfaces

Mapping SOC in a river catchment by integrating laboratory spectra wavelength with remote sensing spectra

DEFF Research Database (Denmark)

Peng, Yi; Xiong, Xiong; Knadel, Maria

There is potential to use soil ·-proximal and remote sensing derived spectra concomitantly to develop soil organic carbon (SOC) models. Yet mixing spectral data from different sources and technologies to improve soil models is still in its infancy. The objective of this study was to incorporate...... soil spectral features indicative of SOC from laboratory visible near-infrared reflectance (vis-NlR) spectra and incorporate them with remote sensing (RS) images to improve predictions of top SOC in the Skjem river catchment, Denmark. The secondary objective was to improve prediction results...

Properties of interstellar dust in reflection nebulae

International Nuclear Information System (INIS)

Sellgren, K.

1988-01-01

Observations of interstellar dust in reflection nebulae are the closest analog in the interstellar medium to studies of cometary dust in our solar system. The presence of a bright star near the reflection nebula dust provides the opportunity to study both the reflection and emission characteristics of interstellar dust. At 0.1 to 1 micrometer, the reflection nebula emission is due to starlight scattered by dust. The albedo and scattering phase function of the dust is determined from observations of the scattered light. At 50 to 200 micrometers, thermal emission from the dust in equilibrium with the stellar radiation field is observed. The derived dust temperature determines the relative values of the absorption coefficient of the dust at wavelengths where the stellar energy is absorbed and at far infrared wavelengths where the absorbed energy is reradiated. These emission mechanisms directly relate to those seen in the near and mid infrared spectra of comets. In a reflection nebula the dust is observed at much larger distances from the star than in our solar system, so that the equilibrium dust temperature is 50 K rather than 300 K. Thus, in reflection nebulae, thermal emission from dust is emitted at 50 to 200 micrometer

Study of the EPR and Moessbauer spectra of iron phosphites

International Nuclear Information System (INIS)

Ebert, M.; Kavan, L.

1978-01-01

The EPR and Moessbauer spectra of polycrystalline samples of ferrous phosphites FeHPO 3 .3H 2 O, FeH 2 P 2 O 5 , FeH 4 P 2 O 6 .1/2H 2 O, FeH 10 P 4 O 12 .4H 2 O and ferric phosphites Fe 2 (HPO 3 ) 3 .9h 2 O, FeH 3 P 2 O 6 .3H 2 O and Fe 4 H 33 P 15 O 45 .6H 2 O were studied. The hydrogen bonds present in hydrogen phosphite anions (polyorthophosphites) produce a decrease in the electron density on the oxygen atom in the anion and thus also a decrease in the crystal field strength with an increasing P/Fe ratio. These changes are reflected not only in the Dq values but also in the g-factors, Moessbauer isomeric shifts and quadropole splitting values. The Moessbauer spectra were measured at laboratory temperature with a Co-57/Pd source (the time for measuring one sample was about 24 hrs) and evaluated on a Hewlett-Packard computer. The EPR spectra of the polycristalline samples were measured at laboratory temperature in the 3 cm region. (T.I.)

Visible and Near-IR Reflectance Spectra of Smectite Acquired Under Dry Conditions for Interpretation of Martian Surface Mineralogy

Science.gov (United States)

Morris, Richard V.; Achilles, Cherie N; Archer, Paul D.; Graff, Trevor G.; Agresti, David G.; Ming, Douglas W; Golden, Dadi C.; Mertzman, Stanley A.

2011-01-01

Visible and near-IR (VNIR) spectra from the MEx OMEGA and the MRO CRISM hyper-spectral imaging instruments have spectral features associated with the H2O molecule and M OH functional groups (M = Mg, Fe, Al, and Si). Mineralogical assignments of martian spectral features are made on the basis of laboratory VNIR spectra, which were often acquired under ambient (humid) conditions. Smectites like nontronite, saponite, and montmorillionite have interlayer H2O that is exchangeable with their environment, and we have acquired smectite reflectance spectra under dry environmental conditions for interpretation of martian surface mineralogy. We also obtained chemical, Moessbauer (MB), powder X-ray diffraction (XRD), and thermogravimetric (TG) data to understand variations in spectral properties. VNIR spectra were recorded in humid lab air at 25-35C, in a dynamic dry N2 atmosphere (50-150 ppmv H2O) after exposing the smectite samples (5 nontronites, 3 montmorillionites, and 1 saponite) to that atmosphere for up to approximately l000 hr each at 25-35C, approximately 105C, and approximately 215C, and after re-exposure to humid lab air. Heating at 105C and 215C for approximately 1000 hr is taken as a surrogate for geologic time scales at lower temperatures. Upon exposure to dry N2, the position and intensity of spectral features associated with M-OH were relatively insensitive to the dry environment, and the spectral features associated with H2O (e.g., approximately 1.90 micrometers) decreased in intensity and are sometimes not detectable by the end of the 215C heating step. The position and intensity of H2O spectral features recovered upon re-exposure to lab air. XRD data show interlayer collapse for the nontronites and Namontmorillionites, with the interlayer remaining collapsed for the latter after re-exposure to lab air. The interlayer did not collapse for the saponite and Ca-montmorillionite. TG data show that the concentration of H2O derived from structural OH was invariant

Reflected ray retrieval from radio occultation data using radio holographic filtering of wave fields in ray space

Science.gov (United States)

Gorbunov, Michael E.; Cardellach, Estel; Lauritsen, Kent B.

2018-03-01

Linear and non-linear representations of wave fields constitute the basis of modern algorithms for analysis of radio occultation (RO) data. Linear representations are implemented by Fourier Integral Operators, which allow for high-resolution retrieval of bending angles. Non-linear representations include Wigner Distribution Function (WDF), which equals the pseudo-density of energy in the ray space. Representations allow for filtering wave fields by suppressing some areas of the ray space and mapping the field back from the transformed space to the initial one. We apply this technique to the retrieval of reflected rays from RO observations. The use of reflected rays may increase the accuracy of the retrieval of the atmospheric refractivity. Reflected rays can be identified by the visual inspection of WDF or spectrogram plots. Numerous examples from COSMIC data indicate that reflections are mostly observed over oceans or snow, in particular over Antarctica. We introduce the reflection index that characterizes the relative intensity of the reflected ray with respect to the direct ray. The index allows for the automatic identification of events with reflections. We use the radio holographic estimate of the errors of the retrieved bending angle profiles of reflected rays. A comparison of indices evaluated for a large base of events including the visual identification of reflections indicated a good agreement with our definition of reflection index.

Reflected ray retrieval from radio occultation data using radio holographic filtering of wave fields in ray space

Directory of Open Access Journals (Sweden)

M. E. Gorbunov

2018-03-01

Full Text Available Linear and non-linear representations of wave fields constitute the basis of modern algorithms for analysis of radio occultation (RO data. Linear representations are implemented by Fourier Integral Operators, which allow for high-resolution retrieval of bending angles. Non-linear representations include Wigner Distribution Function (WDF, which equals the pseudo-density of energy in the ray space. Representations allow for filtering wave fields by suppressing some areas of the ray space and mapping the field back from the transformed space to the initial one. We apply this technique to the retrieval of reflected rays from RO observations. The use of reflected rays may increase the accuracy of the retrieval of the atmospheric refractivity. Reflected rays can be identified by the visual inspection of WDF or spectrogram plots. Numerous examples from COSMIC data indicate that reflections are mostly observed over oceans or snow, in particular over Antarctica. We introduce the reflection index that characterizes the relative intensity of the reflected ray with respect to the direct ray. The index allows for the automatic identification of events with reflections. We use the radio holographic estimate of the errors of the retrieved bending angle profiles of reflected rays. A comparison of indices evaluated for a large base of events including the visual identification of reflections indicated a good agreement with our definition of reflection index.

Classification of sugar beet and volunteer potato reflection spectra with a neural network and statistical discriminant analysis to select discriminative wavelengths

NARCIS (Netherlands)

Nieuwenhuizen, A.T.; Hofstee, J.W.; Zande, van de J.C.; Meuleman, J.; Henten, van E.J.

2010-01-01

The objectives of this study were to determine the reflectance properties of volunteer potato and sugar beet and to assess the potential of separating sugar beet and volunteer potato at different fields and in different years, using spectral reflectance characteristics. With the ImspectorMobile,

Evaluating Leaf and Canopy Reflectance of Stressed Rice Plants to Monitor Arsenic Contamination

Directory of Open Access Journals (Sweden)

Varaprasad Bandaru

2016-06-01

Full Text Available Arsenic contamination is a serious problem in rice cultivated soils of many developing countries. Hence, it is critical to monitor and control arsenic uptake in rice plants to avoid adverse effects on human health. This study evaluated the feasibility of using reflectance spectroscopy to monitor arsenic in rice plants. Four arsenic levels were induced in hydroponically grown rice plants with application of 0, 5, 10 and 20 µmol·L−1 sodium arsenate. Reflectance spectra of upper fully expanded leaves were acquired over visible and infrared (NIR wavelengths. Additionally, canopy reflectance for the four arsenic levels was simulated using SAIL (Scattering by Arbitrarily Inclined Leaves model for various soil moisture conditions and leaf area indices (LAI. Further, sensitivity of various vegetative indices (VIs to arsenic levels was assessed. Results suggest that plants accumulate high arsenic amounts causing plant stress and changes in reflectance characteristics. All leaf spectra based VIs related strongly with arsenic with coefficient of determination (r2 greater than 0.6 while at canopy scale, background reflectance and LAI confounded with spectral signals of arsenic affecting the VIs’ performance. Among studied VIs, combined index, transformed chlorophyll absorption reflectance index (TCARI/optimized soil adjusted vegetation index (OSAVI exhibited higher sensitivity to arsenic levels and better resistance to soil backgrounds and LAI followed by red edge based VIs (modified chlorophyll absorption reflectance index (MCARI and TCARI suggesting that these VIs could prove to be valuable aids for monitoring arsenic in rice fields.

Determining the band gap and mean kinetic energy of atoms from reflection electron energy loss spectra

International Nuclear Information System (INIS)

Vos, M.; Marmitt, G. G.; Finkelstein, Y.; Moreh, R.

2015-01-01

Reflection electron energy loss spectra from some insulating materials (CaCO 3 , Li 2 CO 3 , and SiO 2 ) taken at relatively high incoming electron energies (5–40 keV) are analyzed. Here, one is bulk sensitive and a well-defined onset of inelastic excitations is observed from which one can infer the value of the band gap. An estimate of the band gap was obtained by fitting the spectra with a procedure that includes the recoil shift and recoil broadening affecting these measurements. The width of the elastic peak is directly connected to the mean kinetic energy of the atom in the material (Doppler broadening). The experimentally obtained mean kinetic energies of the O, C, Li, Ca, and Si atoms are compared with the calculated ones, and good agreement is found, especially if the effect of multiple scattering is taken into account. It is demonstrated experimentally that the onset of the inelastic excitation is also affected by Doppler broadening. Aided by this understanding, we can obtain a good fit of the elastic peak and the onset of inelastic excitations. For SiO 2 , good agreement is obtained with the well-established value of the band gap (8.9 eV) only if it is assumed that the intensity near the edge scales as (E − E gap ) 1.5 . For CaCO 3 , the band gap obtained here (7 eV) is about 1 eV larger than the previous experimental value, whereas the value for Li 2 CO 3 (7.5 eV) is the first experimental estimate

Effects of Space Weathering on Reflectance Spectra of Ureilites: A Proof-of-Concept Study

Science.gov (United States)

Goodrich, C. A.; Gillis-Davis, J.; Cloutis, E.; Applin, D.; Hibbits, C.; Klima, R.; Christoffersen, R.; Fries, M.; Decker, S.

2017-07-01

Space weathering and spectral studies of three ureilitic samples show that space weathering causes significant changes in UV-VIS-IR spectra and Raman spectra. Changes due to amorphization of carbon could disguise ureilitic asteroids as CC-like.

Macroscopic self-consistent model for external-reflection near-field microscopy

International Nuclear Information System (INIS)

Berntsen, S.; Bozhevolnaya, E.; Bozhevolnyi, S.

1993-01-01

The self-consistent macroscopic approach based on the Maxwell equations in two-dimensional geometry is developed to describe tip-surface interaction in external-reflection near-field microscopy. The problem is reduced to a single one-dimensional integral equation in terms of the Fourier components of the field at the plane of the sample surface. This equation is extended to take into account a pointlike scatterer placed on the sample surface. The power of light propagating toward the detector as the fiber mode is expressed by using the self-consistent field at the tip surface. Numerical results for trapezium-shaped tips are presented. The authors show that the sharper tip and the more confined fiber mode result in better resolution of the near-field microscope. Moreover, it is found that the tip-surface distance should not be too small so that better resolution is ensured. 14 refs., 10 figs

Exciton spectra of mixed LiH1-xDx crystals

International Nuclear Information System (INIS)

Plekhanov, V.G.

1989-01-01

The results of low-tempertaure experimental investigation of exciton spectra of pure surface of mixed crystals LiH 1-x d x forming the continuous series of a solved solution are presented. The long-wave reflection spectra is formed, as in pure crystals, by excitons of a large radius. The developed structure of spectra of exciton luminiscence consisting mainly of LO-lines, testifies to the intraband Frelich mechanism of free exciton scattering by LO-phonos, playing the considerable role in renormalization of the exciton Rydberg and the energy of interband transitions. Increase of the concentration of deuterium in mixed crystals causes a short-wave shift in the reflection spectrum and luminescence and continuous decrease of LO-phonon energy together with the increase of Rydberg exciton

Exciton spectra and energy band structure of Cu{sub 2}ZnSiSe{sub 4}

Energy Technology Data Exchange (ETDEWEB)

Guc, M., E-mail: gmax@phys.asm.md [Institute of Applied Physics, Academy of Sciences of Moldova, Academiei Str. 5, Chisinau MD 2028, Republic of Moldova (Moldova, Republic of); Levcenko, S. [Helmholtz Zentrum Berlin für Materialien und Energie GmbH, Hahn-Meitner-Platz 1, D-14109 Berlin (Germany); Dermenji, L. [Institute of Applied Physics, Academy of Sciences of Moldova, Academiei Str. 5, Chisinau MD 2028, Republic of Moldova (Moldova, Republic of); Gurieva, G. [Helmholtz Zentrum Berlin für Materialien und Energie GmbH, Hahn-Meitner-Platz 1, D-14109 Berlin (Germany); Schorr, S. [Helmholtz Zentrum Berlin für Materialien und Energie GmbH, Hahn-Meitner-Platz 1, D-14109 Berlin (Germany); Free University Berlin, Institute of Geological Sciences, Malteserstr. 74-100, Berlin (Germany); Syrbu, N.N. [Technical University of Moldova, Chisinau MD-2004, Republic of Moldova (Moldova, Republic of); Arushanov, E. [Institute of Applied Physics, Academy of Sciences of Moldova, Academiei Str. 5, Chisinau MD 2028, Republic of Moldova (Moldova, Republic of)

2014-02-25

Highlights: • Reflection spectra of Cu{sub 2}ZnSiSe{sub 4} were studied for E ⊥ c and E || c light polarizations. • Four excitonic series are revealed in the reflection spectra at 10 K. • Model of exciton dispersion and the presence of a dead-layer. • Exciton Rydberg energies and free carriers effective masses were calculated. • Reflectivity for E ⊥ c and E || c were analyzed in the region 3–6 eV at 300 K. -- Abstract: Exciton spectra are studied in Cu{sub 2}ZnSiSe{sub 4} single crystals at 10 and 300 K by means of reflection spectroscopy. The exciton parameters, dielectric constant and free carriers effective masses are deduced from experimental spectra by calculations in the framework of a model taking into account the spatial dispersion and the presence of a dead-layer. The structure found in the reflectivity was analyzed and related to the theoretical electronic band structure of close related Cu{sub 2}ZnSiS{sub 4} semiconductor.

Portable instrument for measuring neutron energy spectra and neutron dose in a mixed n-γ field

International Nuclear Information System (INIS)

Daniels, C. J.; Silberberg, J. L.

1980-01-01

A portable high-speed neutron spectrometer consists of an organic scintillator, a true zero-crossing pulse shape discriminator, a 1 MHZ conversion-rate multichannel analyzer, an 8-bit microcomputer, and appropriate displays. The device can be used to measure neutron energy spectra and kerma rate in intense n- gamma radiation fields in which the neutron energy is from 5 to 15 MEV

Correcting attenuated total reflection-fourier transform infrared spectra for water vapor and carbon dioxide

DEFF Research Database (Denmark)

Bruun, Susanne Wrang; Kohler, Achim; Adt, Isabelle

2006-01-01

an absorption band from either water vapor or CO(2). From two calibration data sets, gas model spectra were estimated in each of the four spectral regions, and these model spectra were applied for correction of gas absorptions in two independent test sets (spectra of aqueous solutions and a yeast biofilm (C...... of the growing yeast biofilm, the gas correction revealed otherwise hidden variations of relevance for modeling the growth dynamics. As the presented method improved the interpretation of the principle component analysis (PCA) models, it has proven to be a valuable tool for filtering atmospheric variation in ATR...

An efficient approach for computing the geometrical optics field reflected from a numerically specified surface

Science.gov (United States)

Mittra, R.; Rushdi, A.

1979-01-01

An approach for computing the geometrical optic fields reflected from a numerically specified surface is presented. The approach includes the step of deriving a specular point and begins with computing the reflected rays off the surface at the points where their coordinates, as well as the partial derivatives (or equivalently, the direction of the normal), are numerically specified. Then, a cluster of three adjacent rays are chosen to define a 'mean ray' and the divergence factor associated with this mean ray. Finally, the ampilitude, phase, and vector direction of the reflected field at a given observation point are derived by associating this point with the nearest mean ray and determining its position relative to such a ray.

Polarization contrast in reflection near-field optical microscopy with uncoated fibre tips

DEFF Research Database (Denmark)

Bozhevolnyi, Sergey I.; Langbein, Wolfgang; Hvam, Jørn Märcher

1999-01-01

Using cross-hatched, patterned semiconductor surfaces and round 20-nm-thick gold pads on semiconductor wafers, we investigate the imaging characteristics of a reflection near-field optical microscope with an uncoated fibre tip for different polarization configurations and light wavelengths....... Is is shown that cross-polarized detection allows one to effectively suppress far-field components in the detected signal and to realise imaging of optical contrast on the sub-wavelength scale. The sensitivity window of our microscope, i.e. the scale on which near-field optical images represent mainly optical...

Reflectance spectroscopy of pigmented cutaneous benign and malignant lesions

Science.gov (United States)

Borisova, E.; Jeliazkova, Al.; Pavlova, E.; Troyanova, P.; Kundurdjiev, T.; Pavlova, P.; Avramov, L.

2014-10-01

For the DRS measurements of skin benign, dysplastic and malignant lesions in vivo we applied halogen lamp (LS-1, OceanOptics Inc, Dunedin, Fl, USA) as a continuous light source in the region of 400-900 nm, optical probe (6+1 fibers) for the delivery of illumination and diffuse reflected light from the skin investigated and microspectrometer USB4000 (OceanOptics Inc., Dunedin, Fl, USA) for a storage and display of the spectra detected. As a diffuse reflectance standard Spectralon® plate was used to calibrate the spectrometer. The reflectance spectra obtained from normal skin in identical anatomic sites of different patients have similar spectral shape features, slightly differ by the reflectance intensity at different wavelengths, depending on the particular patient' skin phototype. One could find diagnostically important spectral features, related to specific intensity changes for a given wavelength due to specific pigments appearance, slope changes by value and sign for the reflectance spectra curves in a specific spectral range, disappearance or manifestation of minima, related to hemoglobin absorption at 410-420 nm, 543, 575 nm. Based on the observed peculiarities multispectral analysis of the reflectance spectra of the different lesions was used and diagnostically specific features are found. Discrimination using the DRS data obtained between benign compound and dermal nevi (45 cases), dysplastic nevi (17 cases) and pigmented malignant melanoma (41 cases) lesions is achieved with a diagnostic accuracy of 96 % for the benign nevi vs. MM, and 90 % for the dysplastic nevi vs. MM.

Fluorescence spectra of benign and malignant prostate tissues

International Nuclear Information System (INIS)

AlSalhi, M S; Masilamani, V; Atif, M; Farhat, K; Rabah, D; Al Turki, M R

2012-01-01

In this study, fluorescence emission spectrum (FES), Stokes' shift spectrum (SSS), and reflectance spectrum (RS) of benign (N = 12) and malignant prostate tissues (N = 8) were investigated to discriminate the two types of tissues. The FES was done with the excitation at 325 nm only; SSS with Δλ = 70 and Δλ = 0, the latter being equivalent to reflectance spectra. Of the three modes of spectra, SSS with Δλ = 70 nm showed the best discrimination. There were four important bands, one at 280 nm (due to tryptophan); 320 nm (due to elastin and tryptophan); 355 and 385 (due to NADH) and 440 nm (due to flavin). From the relative intensities of these bands, three ratios were evaluated. Similarly another two ratios were obtained from reflectance spectra and one more from FES. Thus, there are 6 ratio parameters which represent the relative concentration of tryptophan, elastin, nicotinamide adenine dinucleotide (NADH), and flavin. A statistical analysis showed that benign and malignant tissues could be classified with accuracy greater than 90%. This report is only for in vitro analysis; but employing optical fiber, this can be extended to in vivo analysis too, so that benign tumor could be distinguished without surgery

Library of UV-Vis-NIR reflectance spectra of modern organic dyes from historic pattern-card coloured papers.

Science.gov (United States)

Montagner, Cristina; Bacci, Mauro; Bracci, Susanna; Freeman, Rachel; Picollo, Marcello

2011-09-01

An accurate characterisation of the organic dyes used in artworks, especially those made of paper, is an important factor in designing safe conservation treatments. In the case of synthetic organic dyes used in modern works of art, for example, one frequently encountered difficulty is that some of these dyes are not still commercially available. Recognizing this problem, the authors of this paper present the results of an analysis of UV-Vis-NIR fibre optic reflectance spectra of 82 samples of dyed paper prepared with 41 dyes. The samples come from a historic book, The Dyeing of Paper in the Pulp, which was published by Interessen-Gemeinschaft (I.G.) Farbenindustrie in 1925. The dyes used in the paper pulp belong to the azo compounds, acridine, anthraquinone, azine, diphenylmethane, indigoid, methine, nitro, quinoline, thiazine, triphenylmethane, sulphur and xanthene classes. Copyright © 2011 Elsevier B.V. All rights reserved.

Determining the band gap and mean kinetic energy of atoms from reflection electron energy loss spectra

Energy Technology Data Exchange (ETDEWEB)

Vos, M. [Atomic and Molecular Physics Laboratories, Research School of Physics and Engineering, Australian National University, Canberra ACT (Australia); Marmitt, G. G. [Atomic and Molecular Physics Laboratories, Research School of Physics and Engineering, Australian National University, Canberra ACT (Australia); Instituto de Fisica da Universidade Federal do Rio Grande do Sul, Avenida Bento Goncalves 9500, 91501-970 Porto Alegre, RS (Brazil); Finkelstein, Y. [Nuclear Research Center — Negev, Beer-Sheva 84190 (Israel); Moreh, R. [Physics Department, Ben-Gurion University of the Negev, Beer-Sheva 84105 (Israel)

2015-09-14

Reflection electron energy loss spectra from some insulating materials (CaCO{sub 3}, Li{sub 2}CO{sub 3}, and SiO{sub 2}) taken at relatively high incoming electron energies (5–40 keV) are analyzed. Here, one is bulk sensitive and a well-defined onset of inelastic excitations is observed from which one can infer the value of the band gap. An estimate of the band gap was obtained by fitting the spectra with a procedure that includes the recoil shift and recoil broadening affecting these measurements. The width of the elastic peak is directly connected to the mean kinetic energy of the atom in the material (Doppler broadening). The experimentally obtained mean kinetic energies of the O, C, Li, Ca, and Si atoms are compared with the calculated ones, and good agreement is found, especially if the effect of multiple scattering is taken into account. It is demonstrated experimentally that the onset of the inelastic excitation is also affected by Doppler broadening. Aided by this understanding, we can obtain a good fit of the elastic peak and the onset of inelastic excitations. For SiO{sub 2}, good agreement is obtained with the well-established value of the band gap (8.9 eV) only if it is assumed that the intensity near the edge scales as (E − E{sub gap}){sup 1.5}. For CaCO{sub 3}, the band gap obtained here (7 eV) is about 1 eV larger than the previous experimental value, whereas the value for Li{sub 2}CO{sub 3} (7.5 eV) is the first experimental estimate.

Analysis and suppression of reflections in far-field antenna measurement ranges

OpenAIRE

Sierra Castañer, Manuel; Cano Facila, Francisco Jose; Foged, Lars Jacob; Saccardi, Francesco; Nader Kawassaki, Guilherme; Raimundi, Lucas dos Reis; Vilela Rezende, Stefano Albino

2013-01-01

This paper presents the analysis of the reflections in two kind of spherical far field ranges: one if the classical acquisition where the AUT is rotated and the second one corresponds to the systems where the AUT is fixed and the antenna probe is rotated. In large far field systems this is not possible, but this can be used to the measurement of small antennas, for instance, with the SATIMO StarGate system. In both cases, it is assumed that only one frequency is acquired and the results shoul...

Transient field behavior in an electromagnetic pulse from neutral-beam reflection

International Nuclear Information System (INIS)

Strobel, G.L.

1990-01-01

A neutral beam of electrons and positrons catches up to an electromagnetic pulse moving in a medium with refractive index n. The neutral beam is reflected and deposits some of its energy in a current region in the tail of the pulse. The location, size, and shape of the transient-induced electric fields in the current region are modeled using current densities from uniform averaged fields. The electric field in the current region is predicted to rise linearly with time, with a doubling time determined by the beam parameters and the initial local electromagnetic field. A coordinate frame comoving with the pulse is used to determine the extent of and conditions within the current region. In this comoving frame the Lorentz-transformed electric field is zero, but there is an enhanced Lorentz-transformed magnetic field. The extent of the current region is found from the radius of the semicircular charged-particle orbits in the comoving frame

Transmission versus reflectance spectroscopy for quantitation

Science.gov (United States)

Gardner, Craig M.

2018-01-01

The objective of this work was to compare the accuracy of analyte concentration estimation when using transmission versus diffuse reflectance spectroscopy of a scattering medium. Monte Carlo ray tracing of light through the medium was used in conjunction with pure component absorption spectra and Beer-Lambert absorption along each ray's pathlength to generate matched sets of pseudoabsorbance spectra, containing water and six analytes present in skin. PLS regression models revealed an improvement in accuracy when using transmission compared to reflectance for a range of medium thicknesses and instrument noise levels. An analytical expression revealed the source of the accuracy degradation with reflectance was due both to the reduced collection efficiency for a fixed instrument etendue and to the broad pathlength distribution that detected light travels in the medium before exiting from the incident side.

Hawking radiation spectra for scalar fields by a higher-dimensional Schwarzschild-de Sitter black hole

Science.gov (United States)

Pappas, T.; Kanti, P.; Pappas, N.

2016-07-01

In this work, we study the propagation of scalar fields in the gravitational background of a higher-dimensional Schwarzschild-de Sitter black hole as well as on the projected-on-the-brane four-dimensional background. The scalar fields have also a nonminimal coupling to the corresponding, bulk or brane, scalar curvature. We perform a comprehensive study by deriving exact numerical results for the greybody factors, and study their profile in terms of particle and spacetime properties. We then proceed to derive the Hawking radiation spectra for a higher-dimensional Schwarzschild-de Sitter black hole, and we study both bulk and brane channels. We demonstrate that the nonminimal field coupling, which creates an effective mass term for the fields, suppresses the energy emission rates while the cosmological constant assumes a dual role. By computing the relative energy rates and the total emissivity ratio for bulk and brane emission, we demonstrate that the combined effect of a large number of extra dimensions and value of the field coupling gives to the bulk channel the clear domination in the bulk-brane energy balance.

LAMOST OBSERVATIONS IN THE KEPLER FIELD. I. DATABASE OF LOW-RESOLUTION SPECTRA

Energy Technology Data Exchange (ETDEWEB)

Cat, P. De; Ren, A. B.; Yang, X. H. [Royal observatory of Belgium, Ringlaan 3, B-1180 Brussel (Belgium); Fu, J. N. [Department of Astronomy, Beijing Normal University, 19 Avenue Xinjiekouwai, Beijing 100875 (China); Shi, J. R.; Luo, A. L.; Yang, M.; Wang, J. L.; Zhang, H. T.; Shi, H. M.; Zhang, W. [Key Lab for Optical Astronomy, National Astronomical Observatories, Chinese Academy of Sciences, Beijing 100012 (China); Dong, Subo [Kavli Institute for Astronomy and Astrophysics, Peking University, Yi He Yuan Road 5, Hai Dian District, Beijing, 100871 (China); Catanzaro, G.; Frasca, A. [INAF—Osservatorio Astrofisico di Catania, Via S. Sofia 78, I-95123 Catania (Italy); Corbally, C. J. [Vatican Observatory Research Group, Steward Observatory, Tucson, AZ 85721-0065 (United States); Gray, R. O. [Department of Physics and Astronomy, Appalachian State University, Boone, NC 28608 (United States); Żakowicz, J. Molenda- [Astronomical Institute of the University of Wrocław, ul. Kopernika 11, 51-622 Wrocław (Poland); Uytterhoeven, K. [Instituto de Astrofísica de Canarias (IAC), E-38200 La Laguna, Tenerife (Spain); Briquet, M. [Institut d’Astrophysique et de Géophysique, Université de Liège, Allée du 6 Août 19C, B-4000 Liège (Belgium); Bruntt, H., E-mail: Peter.DeCat@oma.be [Stellar Astrophysics Center, Department of Physics and Astronomy, Aarhus University, Ny Munkegade 120, DK-8000 Aarhus C (Denmark); and others

2015-09-15

The nearly continuous light curves with micromagnitude precision provided by the space mission Kepler are revolutionizing our view of pulsating stars. They have revealed a vast sea of low-amplitude pulsation modes that were undetectable from Earth. The long time base of Kepler light curves allows for the accurate determination of the frequencies and amplitudes of pulsation modes needed for in-depth asteroseismic modeling. However, for an asteroseismic study to be successful, the first estimates of stellar parameters need to be known and they cannot be derived from the Kepler photometry itself. The Kepler Input Catalog provides values for the effective temperature, surface gravity, and metallicity, but not always with sufficient accuracy. Moreover, information on the chemical composition and rotation rate is lacking. We are collecting low-resolution spectra for objects in the Kepler field of view with the Large Sky Area Multi-Object Fiber Spectroscopic Telescope (lamost, Xinglong observatory, China). All of the requested fields have now been observed at least once. In this paper, we describe those observations and provide a useful database for the whole astronomical community.

Combined reflection and transmission microscope for telemedicine applications in field settings.

Science.gov (United States)

Biener, Gabriel; Greenbaum, Alon; Isikman, Serhan O; Lee, Kelvin; Tseng, Derek; Ozcan, Aydogan

2011-08-21

We demonstrate a field-portable upright and inverted microscope that can image specimens in both reflection and transmission modes. This compact and cost-effective dual-mode microscope weighs only ∼135 grams (image of the specimen onto an opto-electronic sensor-array that is positioned above the beam-splitter cube. In addition to this, the illumination beam is also partially transmitted through the same specimen, which then casts lensfree in-line holograms of the same objects onto a second opto-electronic sensor-array that is positioned underneath the beam-splitter cube. By rapid digital reconstruction of the acquired lensfree holograms, transmission images (both phase and amplitude) of the same specimen are also created. We tested the performance of this field-portable microscope by imaging various micro-particles, blood smears as well as a histopathology slide corresponding to skin tissue. Being compact, light-weight and cost-effective, this combined reflection and transmission microscope might especially be useful for telemedicine applications in resource limited settings. This journal is © The Royal Society of Chemistry 2011

Improving interpretation of infrared spectra for OM characterization by subtraction of spectra from incinerated samples

Science.gov (United States)

Ellerbrock, Ruth H.; Gerke, Horst H.; Leue, Martin

2017-04-01

Non-destructive methods such as diffuse reflectance infrared Fourier transform spectroscopy (DRIFT) have been applied to characterize organic matter (OM) at intact structural surfaces among others. However, it is often difficult to distinguish effects of organic components on DRIFT signal intensities from those of mineral components. The objective of this study was to re-evaluate DRIFT spectra from intact earthworm burrow walls and coated cracks to improve the interpretation of C-H and C=O bands. We compared DRIFT and transmission Fourier transform infrared (FTIR) spectra of entire samples that were from the same pedogenetic soil horizon, but different in mineral composition and texture (i.e., glacial till versus loess). Spectra of incinerated samples were subtracted from the original spectra. Transmission FTIR and DRIFT spectra were almost identical for entire soil samples. However, the DRIFT spectra were affected by the bulk mode bands (i.e., wavenumbers 2000 to 1700 cm-1) that affected spectral resolution and reproducibility. The ratios between C-H and C=O band intensities as indicator for OM quality obtained with DRIFT were smaller than those obtained from transmission FTIR. A spectral subtraction procedure was found to reduce effects of mineral absorption bands on DRIFT spectra allowing an improved interpretation. DRIFT spectroscopy as a non-destructive method for analyzing OM composition at intact surfaces in structured soils could be calibrated with information obtained with the more detailed transmission FTIR and complementary methods.

Diffuse Reflectance Spectroscopy of Human Skin Using a Commercial Fiber Optic Spectrometer

International Nuclear Information System (INIS)

Atencio, J. A. Delgado; Rodriguez, M. Cunill; Montiel, S. Vazquez y; Castro, Jorge; Rodriguez, A. Cornejo; Gutierrez, J. L.; Martinez, F.; Gutierrez, B.; Orozco, E.

2008-01-01

Diffuse reflectance spectroscopy is a reliable and easy to implement technique in human tissue characterization. In this work we evaluate the performance of the commercial USB4000 miniature fiber optic spectrometer in the in-vivo measurement of the diffuse reflectance spectra of different healthy skin sites and lesions in a population of 54 volunteers. Results show, that this spectrometer reproduces well the typical signatures of skin spectra over the 400-1000 nm region. Remarkable spectral differences exist between lesions and normal surrounding skin. A diffusion-based model was used to simulate reflectance spectra collected by the optical probe of the system

Reflectance spectroscopy of indoor settled dust in Tel Aviv, Israel: comparison between the spring and the summer seasons

Directory of Open Access Journals (Sweden)

A. A. Chudnovsky

2007-07-01

Full Text Available The influence of mineral and anthropogenic dust components on the VIS-NIR-SWIR spectral reflectance of artificial laboratory dust mixtures was evaluated and used in combination with Partial Least Squares (PLS regression to construct a model that correlates the dust content with its reflectance. Small amounts of dust (0.018–0.33 mg/cm² were collected using glass traps placed in different indoor environments in Tel Aviv, Israel during the spring and summer of 2005. The constructed model was applied to reflectance spectroscopy measurements derived from the field dust samples to assess their mineral content. Additionally, field samples were examined using Principal Component Analysis (PCA to identify the most representative spectral pattern for each season. Across the visible range of spectra two main spectral shapes were observed, convex and concave, though spectra exhibiting hybrid shapes were also seen. Spectra derived from spring season dust samples were characterized mostly by a convex shape, which indicates a high mineral content. In contrast, the spectra generated from summer samples were characterized generally by a concave shape, which indicates a high organic matter content. In addition to this seasonal variation in spectral patterns, spectral differences were observed associated with the dwelling position in the city. Samples collected in the city center showed higher organic content, whereas samples taken from locations at the city margins, near the sea and next to open areas, exhibited higher mineral content. We conclude that mineral components originating in the outdoor environment influence indoor dust loads, even when considering relatively small amounts of indoor settled dust. The sensitive spectral-based method developed here has potentially many applications for environmental researchers and policy makers concerned with dust pollution.

Moessbauer spectra of some complex compounds of Fe(II) with pyridine

International Nuclear Information System (INIS)

Teodorescu, M.; Filoti, G.

1975-01-01

The Moessbauer spectra of [Fe(II)py 6 ]Br 2 at 298 and 80 K and the reflectance spectra of the same compound at room temperature are presented. Isomer shift and quadrupole splitting were determined for [Fe(II)py 6 ]Br 2 at 298 and 80 K, their values being correlated with those obtained from electronic spectra measured in the solid state. (Z.S.)

Ground-Based VIS/NIR Reflectance Spectra of 25143 Itokawa: What Hayabusa will See and How Ground-Based Data can Augment Analyses

Science.gov (United States)

Vilas, Faith; Abell, P. A.; Jarvis, K. S.

2004-01-01

Planning for the arrival of the Hayabusa spacecraft at asteroid 25143 Itokawa includes consideration of the expected spectral information to be obtained using the AMICA and NIRS instruments. The rotationally-resolved spatial coverage the asteroid we have obtained with ground-based telescopic spectrophotometry in the visible and near-infrared can be utilized here to address expected spacecraft data. We use spectrophotometry to simulate the types of data that Hayabusa will receive with the NIRS and AMICA instruments, and will demonstrate them here. The NIRS will cover a wavelength range from 0.85 m, and have a dispersion per element of 250 Angstroms. Thus, we are limited in coverage of the 1.0 micrometer and 2.0 micrometer mafic silicate absorption features. The ground-based reflectance spectra of Itokawa show a large component of olivine in its surface material, and the 2.0 micrometer feature is shallow. Determining the olivine to pyroxene abundance ratio is critically dependent on the attributes of the 1.0- and 2.0 micrometer features. With a cut-off near 2,1 micrometer the longer edge of the 2.0- feature will not be obtained by NIRS. Reflectance spectra obtained using ground-based telescopes can be used to determine the regional composition around space-based spectral observations, and possibly augment the longer wavelength spectral attributes. Similarly, the shorter wavelength end of the 1.0 micrometer absorption feature will be partially lost to the NIRS. The AMICA filters mimic the ECAS filters, and have wavelength coverage overlapping with the NIRS spectral range. We demonstrate how merging photometry from AMICA will extend the spectral coverage of the NIRS. Lessons learned from earlier spacecraft to asteroids should be considered.

Pulsed zero field NMR of solids and liquid crystals

International Nuclear Information System (INIS)

Thayer, A.M.

1987-02-01

This work describes the development and applications to solids and liquid crystals of zero field nuclear magnetic resonance (NMR) experiments with pulsed dc magnetic fields. Zero field NMR experiments are one approach for obtaining high resolution spectra of amorphous and polycrystalline materials which normally (in high field) display broad featureless spectra. The behavior of the spin system can be coherently manipulated and probed in zero field with dc magnetic field pulses which are employed in a similar manner to radiofrequency pulses in high field NMR experiments. Nematic phases of liquid crystalline systems are studied in order to observe the effects of the removal of an applied magnetic field on sample alignment and molecular order parameters. In nematic phases with positive and negative magnetic susceptibility anisotropies, a comparison between the forms of the spin interactions in high and low fields is made. High resolution zero field NMR spectra of unaligned smectic samples are also obtained and reflect the symmetry of the liquid crystalline environment. These experiments are a sensitive measure of the motionally induced asymmetry in biaxial phases. Homonuclear and heteronuclear solute spin systems are compared in the nematic and smectic phases. Nonaxially symmetric dipolar couplings are reported for several systems. The effects of residual fields in the presence of a non-zero asymmetry parameter are discussed theoretically and presented experimentally. Computer programs for simulations of these and other experimental results are also reported. 179 refs., 75 figs

Detection of undistorted continuous wave (CW) electron paramagnetic resonance (EPR) spectra with non-adiabatic rapid sweep (NARS) of the magnetic field

Science.gov (United States)

Kittell, Aaron W.; Camenisch, Theodore G.; Ratke, Joseph J.; Sidabras, Jason W.; Hyde, James S.

2011-01-01

A continuous wave (CW) electron paramagnetic resonance (EPR) spectrum is typically displayed as the first harmonic response to the application of 100 kHz magnetic field modulation, which is used to enhance sensitivity by reducing the level of 1/f noise. However, magnetic field modulation of any amplitude causes spectral broadening and sacrifices EPR spectral intensity by at least a factor of two. In the work presented here, a CW rapid-scan spectroscopic technique that avoids these compromises and also provides a means of avoiding 1/f noise is developed. This technique, termed non-adiabatic rapid sweep (NARS) EPR, consists of repetitively sweeping the polarizing magnetic field in a linear manner over a spectral fragment with a small coil at a repetition rate that is sufficiently high that receiver noise, microwave phase noise, and environmental microphonics, each of which has 1/f characteristics, are overcome. Nevertheless, the rate of sweep is sufficiently slow that adiabatic responses are avoided and the spin system is always close to thermal equilibrium. The repetitively acquired spectra from the spectral fragment are averaged. Under these conditions, undistorted pure absorption spectra are obtained without broadening or loss of signal intensity. A digital filter such as a moving average is applied to remove high frequency noise, which is approximately equivalent in bandwidth to use of an integrating time constant in conventional field modulation with lock-in detection. Nitroxide spectra at L- and X-band are presented. PMID:21741868

Polarization Spectra of Extrasolar Giant Planets

NARCIS (Netherlands)

Stam, D.M.

2004-01-01

We present simulated spectra of the flux and degree of polarization of starlight that is reflected by extrasolar giant planets (EGPs). In particular the polarization depends strongly on the structure of the planetary atmosphere, and appears to be a valuable tool for the characterization of EGPs.

State-of-the art comparability of corrected emission spectra. 2. Field laboratory assessment of calibration performance using spectral fluorescence standards.

Science.gov (United States)

Resch-Genger, Ute; Bremser, Wolfram; Pfeifer, Dietmar; Spieles, Monika; Hoffmann, Angelika; DeRose, Paul C; Zwinkels, Joanne C; Gauthier, François; Ebert, Bernd; Taubert, R Dieter; Voigt, Jan; Hollandt, Jörg; Macdonald, Rainer

2012-05-01

In the second part of this two-part series on the state-of-the-art comparability of corrected emission spectra, we have extended this assessment to the broader community of fluorescence spectroscopists by involving 12 field laboratories that were randomly selected on the basis of their fluorescence measuring equipment. These laboratories performed a reference material (RM)-based fluorometer calibration with commercially available spectral fluorescence standards following a standard operating procedure that involved routine measurement conditions and the data evaluation software LINKCORR developed and provided by the Federal Institute for Materials Research and Testing (BAM). This instrument-specific emission correction curve was subsequently used for the determination of the corrected emission spectra of three test dyes, X, QS, and Y, revealing an average accuracy of 6.8% for the corrected emission spectra. This compares well with the relative standard uncertainties of 4.2% for physical standard-based spectral corrections demonstrated in the first part of this study (previous paper in this issue) involving an international group of four expert laboratories. The excellent comparability of the measurements of the field laboratories also demonstrates the effectiveness of RM-based correction procedures.

Analysis of the profile characteristics of corn and soybeans using field reflectance data

Science.gov (United States)

Crist, E. P.

1982-01-01

The typical patterns of spectral development (profiles) for corn and soybeans are presented, based on field-collected reflectance data transformed to correspond to LANDSAT-MSS Tasseled Cap coordinates. Reasonable variations in field conditions and cultural practices are shown to significantly influence profile features. The separability of the two crops is determined to be primarily related to the maximum value of the reflectance equivalent of Greenness, and to the plateau effect seen in corn Greenness profiles. The impact of changes in conditions on separability is described. In addition, association is made between profile features and stages of development for corn and soybeans. Corn is shown to peak at a stage well before tasseling or maximum LAI, while the characteristics of the soybean profile are shown to be unrelated to any particular stage of development.

Challenging Narcissus, or Reflecting on Reflecting.

Science.gov (United States)

Achilles, C. M.

The concept of reflective practice and teaching people to be reflective practitioners is examined. The document begins with a look at professional knowledge according to three prominent professionals in the educational administration field: Schon, Schein, and Achilles. "Reflective" strategies that could be incorporated into courses and…

Predicting ambient aerosol thermal-optical reflectance (TOR) measurements from infrared spectra: extending the predictions to different years and different sites

Science.gov (United States)

Reggente, Matteo; Dillner, Ann M.; Takahama, Satoshi

2016-02-01

Organic carbon (OC) and elemental carbon (EC) are major components of atmospheric particulate matter (PM), which has been associated with increased morbidity and mortality, climate change, and reduced visibility. Typically OC and EC concentrations are measured using thermal-optical methods such as thermal-optical reflectance (TOR) from samples collected on quartz filters. In this work, we estimate TOR OC and EC using Fourier transform infrared (FT-IR) absorbance spectra from polytetrafluoroethylene (PTFE Teflon) filters using partial least square regression (PLSR) calibrated to TOR OC and EC measurements for a wide range of samples. The proposed method can be integrated with analysis of routinely collected PTFE filter samples that, in addition to OC and EC concentrations, can concurrently provide information regarding the functional group composition of the organic aerosol. We have used the FT-IR absorbance spectra and TOR OC and EC concentrations collected in the Interagency Monitoring of PROtected Visual Environments (IMPROVE) network (USA). We used 526 samples collected in 2011 at seven sites to calibrate the models, and more than 2000 samples collected in 2013 at 17 sites to test the models. Samples from six sites are present both in the calibration and test sets. The calibrations produce accurate predictions both for samples collected at the same six sites present in the calibration set (R2 = 0.97 and R2 = 0.95 for OC and EC respectively), and for samples from 9 of the 11 sites not included in the calibration set (R2 = 0.96 and R2 = 0.91 for OC and EC respectively). Samples collected at the other two sites require a different calibration model to achieve accurate predictions. We also propose a method to anticipate the prediction error; we calculate the squared Mahalanobis distance in the feature space (scores determined by PLSR) between new spectra and spectra in the calibration set. The squared Mahalanobis distance provides a crude method for assessing the

Spatial distribution of reflected gamma rays by Monte Carlo simulation

International Nuclear Information System (INIS)

Jehouani, A.; Merzouki, A.; Boutadghart, F.; Ghassoun, J.

2007-01-01

In nuclear facilities, the reflection of gamma rays of the walls and metals constitutes an unknown origin of radiation. These reflected gamma rays must be estimated and determined. This study concerns reflected gamma rays on metal slabs. We evaluated the spatial distribution of the reflected gamma rays spectra by using the Monte Carlo method. An appropriate estimator for the double differential albedo is used to determine the energy spectra and the angular distribution of reflected gamma rays by slabs of iron and aluminium. We took into the account the principal interactions of gamma rays with matter: photoelectric, coherent scattering (Rayleigh), incoherent scattering (Compton) and pair creation. The Klein-Nishina differential cross section was used to select direction and energy of scattered photons after each Compton scattering. The obtained spectra show peaks at 0.511 * MeV for higher source energy. The Results are in good agreement with those obtained by the TRIPOLI code [J.C. Nimal et al., TRIPOLI02: Programme de Monte Carlo Polycinsetique a Trois dimensions, CEA Rapport, Commissariat a l'Energie Atomique.

Deconvoluting double Doppler spectra

International Nuclear Information System (INIS)

Ho, K.F.; Beling, C.D.; Fung, S.; Chan, K.L.; Tang, H.W.

2001-01-01

The successful deconvolution of data from double Doppler broadening of annihilation radiation (D-DBAR) spectroscopy is a promising area of endeavour aimed at producing momentum distributions of a quality comparable to those of the angular correlation technique. The deconvolution procedure we test in the present study is the constrained generalized least square method. Trials with computer simulated DDBAR spectra are generated and deconvoluted in order to find the best form of regularizer and the regularization parameter. For these trials the Neumann (reflective) boundary condition is used to give a single matrix operation in Fourier space. Experimental D-DBAR spectra are also subject to the same type of deconvolution after having carried out a background subtraction and using a symmetrize resolution function obtained from an 85 Sr source with wide coincidence windows. (orig.)

Titan's surface spectra at the Huygens landing site and Shangri-La

Science.gov (United States)

Rannou, P.; Toledo, D.; Lavvas, P.; D'Aversa, E.; Moriconi, M. L.; Adriani, A.; Le Mouélic, S.; Sotin, C.; Brown, R.

2016-05-01

Titan is an icy satellite of Saturn with a dense atmosphere and covered by a global photochemical organic haze. Ground based observations and the Huygens descent probe allowed to retrieve the main spectral signature of the water ice (Griffith, C.A. et al. [2003]. Science 300(5619), 628-630; Coustenis, A. et al. [2005]. Icarus 177, 89-105) at the surface, possibly covered by a layer of sedimented organic material (Tomasko, M.G. et al. [2005]. Nature 438(7069), 765-778). However, the spectrum of the surface is not yet understood. In this study, we find that the surface reflectivity at the Huygens Landing Site (HLS) is well modeled by a layer of water ice grains overlaid by a moist layer of weakly compacted photochemical aggregated aerosols. Moist soils have spectra shifted toward short wavelengths relatively to spectra of dry soils. Cassini observations of Shangri-La region from orbit also show a very dark surface with a reflectivity peak shifted toward short wavelengths in respect to the reflectivity peak of bright surfaces, revealing a dichotomy between terrains based to their spectra in visible.

Polarized photomodulated reflectivity and photoluminescence studies of ordered InGaP2 under pressure

International Nuclear Information System (INIS)

Thomas, R.J.; Chandrasekhar, H.R.; Chandrasekhar, M.; Jones, E.D.; Schneider, R.P. Jr.

1994-01-01

Spontaneous ordering of ternary alloys grown on misoriented substrates has been of recent interest. Ordering induced band gap reduction, and valence band splittings exhibiting novel polarization properties have been investigated by theory and experiment. This paper discusses polarized photomodulated reflectivity (PR) and photoluminescence (PL) studies of MOCVD grown InGaP 2 epilayers lattice-matched to a GaAs substrate. These structures were grown on a (001) face with a niisorientation of two degrees along . The high degree of ordering has enabled us to accurately measure the crystal field splitting and additional structure not reported in the PR spectra. For the electric field E parallel to [110] two features in the PR spectra are seen; for E parallel[110], however, additional features are observed. Comparison with spectra of disordered samples of the same alloy composition has enabled a determination of the band gap reduction due to ordering. Linewidths of the PR peaks are approximately 5--10 meV which has enabled us to study them in detail as a function of hydrostatic pressure at cryogenic temperatures. The pressure dependence is slightly sublinear with the first order term of 8--9 meV/kbar for pressures well below the l-X crossover. Also observed is the indirect level crossing which occurs under pressure at about 40-kbar. A comparison of PR lineshapes at 1-bar is also presented at several commonly used experimental temperatures. Data indicate a substantial change in PR lineshapes, showing that interpretation of reflectivity data for these samples must be handled carefully

Wave reflections from breakwaters

OpenAIRE

Dickson, William S.

1994-01-01

A new method is presented for estimating the reflection of a random, multi-directional sea from a coastal structure. The technique is applicable to an array of wave gauges of arbitrary geometry deployed seaward of the reflector. An expansion for small oblique wave incidence angles is used to derive an approximate relationship between measured array cross-spectra and a small number of parameters that describe the incident wave properties and the reflectivity of the structure. Model tests with ...

Characterizing the surface heterogeneity of fire effects using multi-temporal reflective wavelength data

CSIR Research Space (South Africa)

Roy, DP

2005-10-10

Full Text Available fires lit in South Africa to substantiate and illustrate the model findings. We discuss the implications of our findings for algorithms that examine change in reflectance to map fire-affected areas and discuss the possibility of deriving cc and f from... measurements were taken in the laboratory to reduce field measurement errors and because we were concerned only with obtaining representative spectra for illustrative modelling. SAFARI 2000 4203 The measurements were made under diffuse illumination conditions...

Exchange and crystal field effects in the ESR spectra of Eu2+ in LaB6

Science.gov (United States)

Duque, J. G. S.; Urbano, R. R.; Venegas, P. A.; Pagliuso, P. G.; Rettori, C.; Fisk, Z.; Oseroff, S. B.

2007-09-01

Electron spin resonance of Eu2+ ( 4f7 , S=7/2 ) in a La hexaboride (LaB6) single crystal shows a single anisotropic Dysonian resonance. From the observed negative g shift of the resonance, it is inferred that the Eu2+ ions are covalent exchange coupled to the B2p -like host conduction electrons. From the anisotropy of the spectra (linewidth and field for resonance), we found that the S ground state of Eu2+ ions experience a cubic crystal field of a negative fourth order crystal field parameter (CFP), b4=-11.5(2.0)Oe , in agreement with the negative fourth order CFP, A4 , found for the non- S ground state R hexaborides. These results support covalency as the dominant contribution to the fourth order CFP for the whole R hexaboride family.

Multifractal spectra in shear flows

Science.gov (United States)

Keefe, L. R.; Deane, Anil E.

1989-01-01

Numerical simulations of three-dimensional homogeneous shear flow and fully developed channel flow, are used to calculate the associated multifractal spectra of the energy dissipation field. Only weak parameterization of the results with the nondimensional shear is found, and this only if the flow has reached its asymptotic development state. Multifractal spectra of these flows coincide with those from experiments only at the range alpha less than 1.

Compendium on neutron spectra in criticality accident dosimetry

International Nuclear Information System (INIS)

Ing, H.

1978-01-01

Graphical and tabulated neutron spectra are presented: from selected critical assemblies; from critical solutions; of fission neutrons through shielding; of H 2 O-moderated fission neutrons through shielding; of D 2 O-moderated fission neutrons through shielding; of fission neutrons reflected from various materials; from the D(T, 4 He)n reaction (''14 MeV'' neutrons) through shielding and of ''14 MeV'' neutrons reflected from various materials

Seasonal trends in separability of leaf reflectance spectra for Ailanthus altissima and four other tree species

Science.gov (United States)

Burkholder, Aaron

This project investigated the spectral separability of the invasive species Ailanthus altissima, commonly called tree of heaven, and four other native species. Leaves were collected from Ailanthus and four native tree species from May 13 through August 24, 2008, and spectral reflectance factor measurements were gathered for each tree using an ASD (Boulder, Colorado) FieldSpec Pro full-range spectroradiometer. The original data covered the range from 350-2500 nm, with one reflectance measurement collected per one nm wavelength. To reduce dimensionality, the measurements were resampled to the actual resolution of the spectrometer's sensors, and regions of atmospheric absorption were removed. Continuum removal was performed on the reflectance data, resulting in a second dataset. For both the reflectance and continuum removed datasets, least angle regression (LARS) and random forest classification were used to identify a single set of optimal wavelengths across all sampled dates, a set of optimal wavelengths for each date, and the dates for which Ailanthus is most separable from other species. It was found that classification accuracy varies both with dates and bands used. Contrary to expectations that early spring would provide the best separability, the lowest classification error was observed on July 22 for the reflectance data, and on May 13, July 11 and August 1 for the continuum removed data. This suggests that July and August are also potentially good months for species differentiation. Applying continuum removal in many cases reduced classification error, although not consistently. Band selection seems to be more important for reflectance data in that it results in greater improvement in classification accuracy, and LARS appears to be an effective band selection tool. The optimal spectral bands were selected from across the spectrum, often with bands from the blue (401-431 nm), NIR (1115 nm) and SWIR (1985-1995 nm), suggesting that hyperspectral sensors with

Polarization of the interference field during reflection of electromagnetic waves from an intermedia boundary

Science.gov (United States)

Bulakhov, M. G.; Buyanov, Yu. I.; Yakubov, V. P.

1996-10-01

It has been shown that a full vector measurement of the total field allows one to uniquely distinguish the incident and reflected waves at each observation point without the use of a spatial difference based on an analysis of the polarization structure of the interference pattern which arises during reflection of electromagnetic waves from an intermedia boundary. We have investigated the stability of these procedures with respect to measurement noise by means of numerical modeling.

Crystal-field spectra of fassaite from the Angra dos Reis meteorite

Energy Technology Data Exchange (ETDEWEB)

Mao, H K; Bell, P M; Virgo, D [Carnegie Institution of Washington, D.C. (USA)

1977-06-01

Fassaitic pyroxene from the Angra dos Reis meteorite has striking spectral properties. The /sup 57/Fe Moessbauer spectra show no Fe/sup 3 +/, and thus the absorption is thought to originate from a complex charge-transfer process. Intense absorption at 480 nm dominates the spectrum of the meteorite and may be important in the interpretation of telescope spectra of objects in space.

Mass spectra in N = 1 SQCD with additional colorless but flavored fields

Energy Technology Data Exchange (ETDEWEB)

Chernyak, Victor L. [Budker Institute of Nuclear Physics, Novosibirsk (Russian Federation); Novosibirsk State University, Novosibirsk (Russian Federation)

2017-01-15

Considered is the N = 1 supersymmetric QCD-like Φ-theory with SU(N{sub c}) colors and 0 < N{sub F} < 2N{sub c} flavors of light quarks Q{sup i}{sub a}, Q{sup a}{sub j} with equal small masses. In addition to quarks and gluons of the standard N = 1 SQCD, it includes N{sup 2}{sub F} colorless but flavored fields Φ{sub i}{sup j}, with the large mass parameter μ{sub Φ} >> Λ{sub Q} (Λ{sub Q} is the scale factor of the gauge coupling), interacting with quarks through the Yukawa coupling in the superpotential. The mass spectra of this (direct) Φ-theory are first directly calculated in all vacua with the unbroken or spontaneously broken flavor symmetry U(N{sub F}) → U(n{sub 1}) x U(n{sub 2}) at 0 < N{sub F} < N{sub c}, in which case this theory is logarithmically weakly coupled. Further, the mass spectra of both, this direct Φ-theory and its Seiberg's dual variant with SU(N{sub F}-N{sub c}) dual colors, the dΦ-theory, are calculated at 3N{sub c}/2 < N{sub F} < 2N{sub c} and at various values of μ{sub Φ} (in strong coupling regimes with coupling constants O(1)), now using the dynamical scenario introduced by the author in his previous article (Chernyak in JETP 114:61, arXiv:0811.4283 [hep-th], 2012). This scenario assumes that quarks in this case can be in two different standard phases only: either this is the HQ (heavy quark) phase with left angle Q{sup i}{sub a} right angle = 0 where they are confined, or they are higgsed with some components left angle Q{sup i}{sub a} right angle ≠ 0, at appropriate values of lagrangian parameters. It is shown that mass spectra of the direct Φ- and dual dΦ-theories are parametrically different, so that they are not equivalent. Besides it is shown in the direct Φ-theory that a qualitatively new phenomenon takes place: under appropriate conditions, the seemingly heavy and dynamically irrelevant fields Φ 'turn back' and there appear two additional generations of light Φ-particles with small masses �

Rapid, nondestructive estimation of surface polymer layer thickness using attenuated total reflection fourier transform infrared (ATR FT-IR) spectroscopy and synthetic spectra derived from optical principles.

Science.gov (United States)

Weinstock, B André; Guiney, Linda M; Loose, Christopher

2012-11-01

We have developed a rapid, nondestructive analytical method that estimates the thickness of a surface polymer layer with high precision but unknown accuracy using a single attenuated total reflection Fourier transform infrared (ATR FT-IR) measurement. Because the method is rapid, nondestructive, and requires no sample preparation, it is ideal as a process analytical technique. Prior to implementation, the ATR FT-IR spectrum of the substrate layer pure component and the ATR FT-IR and real refractive index spectra of the surface layer pure component must be known. From these three input spectra a synthetic mid-infrared spectral matrix of surface layers 0 nm to 10,000 nm thick on substrate is created de novo. A minimum statistical distance match between a process sample's ATR FT-IR spectrum and the synthetic spectral matrix provides the thickness of that sample. We show that this method can be used to successfully estimate the thickness of polysulfobetaine surface modification, a hydrated polymeric surface layer covalently bonded onto a polyetherurethane substrate. A database of 1850 sample spectra was examined. Spectrochemical matrix-effect unknowns, such as the nonuniform and molecularly novel polysulfobetaine-polyetherurethane interface, were found to be minimal. A partial least squares regression analysis of the database spectra versus their thicknesses as calculated by the method described yielded an estimate of precision of ±52 nm.

Disentangling overlapping high-field EPR spectra of organic radicals: Identification of light-induced polarons in the record fullerene-free solar cell blend PBDB-T:ITIC

Science.gov (United States)

Van Landeghem, Melissa; Maes, Wouter; Goovaerts, Etienne; Van Doorslaer, Sabine

2018-03-01

We present a combined high-field EPR and DFT study of light-induced radicals in the bulk heterojunction blend of PBDB-T:ITIC, currently one of the highest efficiency non-fullerene donor:acceptor combinations in organic photovoltaics. We demonstrate two different approaches for disentangling the strongly overlapping high-field EPR spectra of the positive and negative polarons after charge separation: (1) relaxation-filtered field-swept EPR based on the difference in T1 spin-relaxation times and (2) field-swept EDNMR-induced EPR by exploiting the presence of 14N hyperfine couplings in only one of the radical species, the small molecule acceptor radical. The approach is validated by light-induced EPR spectra on related blends and the spectral assignment is underpinned by DFT computations. The broader applicability of the spectral disentangling methods is discussed.

Reflective practice and vocational training: theoretical approaches in the field of Health and Nursing

Directory of Open Access Journals (Sweden)

Luciana Netto

2018-02-01

Full Text Available Abstract Objective: Theoretical reflection that uses Reflexivity as a theoretical reference and its objective is to approach Donald Schön's reflective thinking, interrelating it with the innovative curriculum. Method: The writings of Schön and other authors who addressed the themes in their works were used. Results: The innovative curriculum as an expression of dissatisfaction with the fragmentation paradigm may favor reflective practice, since it is necessary to mobilize reflexivity for actions and contexts that are unpredictable in the field of health promotion. Conclusions: The innovative curriculum favors and is favored by a reflective practice and the development of competencies for the promotion of health. Implications for practice: The findings apply to the practice of nurses to deal with the conditioning and determinants of the health-disease process.

Solar Energetic Particle Spectra

Science.gov (United States)

Ryan, J. M.; Boezio, M.; Bravar, U.; Bruno, A.; Christian, E. R.; de Nolfo, G. A.; Martucci, M.; Mergè, M.; Munini, R.; Ricci, M.; Sparvoli, R.; Stochaj, S.

2017-12-01

We report updated event-integrated spectra from several SEP events measured with PAMELA. The measurements were made from 2006 to 2014 in the energy range starting at 80 MeV and extending well above the neutron monitor threshold. The PAMELA instrument is in a high inclination, low Earth orbit and has access to SEPs when at high latitudes. Spectra have been assembled from these high-latitude measurements. The field of view of PAMELA is small and during the high-latitude passes it scans a wide range of asymptotic directions as the spacecraft orbits. Correcting for data gaps, solid angle effects and improved background corrections, we have compiled event-integrated intensity spectra for twenty-eight SEP events. Where statistics permit, the spectra exhibit power law shapes in energy with a high-energy exponential roll over. The events analyzed include two genuine ground level enhancements (GLE). In those cases the roll-over energy lies above the neutron monitor threshold ( 1 GV) while the others are lower. We see no qualitative difference between the spectra of GLE vs. non-GLE events, i.e., all roll over in an exponential fashion with rapidly decreasing intensity at high energies.

Probing molecular chirality by coherent optical absorption spectra

Energy Technology Data Exchange (ETDEWEB)

Jia, W. Z. [Quantum Optoelectronics Laboratory, School of Physics and Technology, Southwest Jiaotong University, Chengdu 610031 (China); Wei, L. F. [Quantum Optoelectronics Laboratory, School of Physics and Technology, Southwest Jiaotong University, Chengdu 610031 (China); State Key Laboratory of Optoelectronic Materials and Technologies, School of Physics and Engineering, Sun Yat-Sen University, Guangzhou 510275 (China)

2011-11-15

We propose an approach to sensitively probe the chirality of molecules by measuring their coherent optical-absorption spectra. It is shown that quantum dynamics of the cyclic three-level chiral molecules driven by appropriately designed external fields is total-phase dependent. This will result in chirality-dependent absorption spectra for the probe field. As a consequence, the charality-dependent information in the spectra (such as the locations and relative heights of the characteristic absorption peaks) can be utilized to identify molecular chirality and determinate enantiomer excess (i.e., the percentages of different enantiomers). The feasibility of the proposal with chiral molecules confined in hollow-core photonic crystal fiber is also discussed.

Infrared spectra of lunar soils. [using a Michelson interferometer

Science.gov (United States)

Aronson, J. R.; Emslie, A. G.; Smith, E. M.

1979-01-01

Measured data obtained by Michelson interferometer spectrometer were stored in a computer file and smoothed by being passed forward and backward through a digital four-pole low pass filter. Infrared spectra of the 10 lunar samples are presented in the format of brightness temperature versus frequency. The mol % of feldspar, pyroxene, olivine, ilmenite and ferromagnetic silicate in each sample is presented in tables. The reflectance spectra of ilmenite and enstatite are shown in graphs.

Many-body effects on the x-ray spectra of metals

International Nuclear Information System (INIS)

Satpathy, S.S.

1982-01-01

The effects of band structure, of a solid surface, of temperature, and of disorder on the many-electron x-ray spectra of metals are evaluated in a change-of-mean-field approximation using a one-dimensional nearest-neighbor tight-binding model of a metal. The x-ray spectral shapes are determined by both the band structure and the final-state interactions. The effect of the band being non-free-electron-like is not felt at the x-ray threshold, but away from it such effects are noticeable. When the core hole is created at the surface, the spectra at the edge exhibit a Nozieres-de Dominicis-type singularity with the appropriate surface phase-shifts. At energies away from the edge, the one-particle effects are prominent with the x-ray emission and absorption spectra closely reflecting the local one-electron density of states. The recoil spectrum of a Fermi sea at a non-zero temperature has less asymmetry than the zero-temperature case. It was found that at ordinary temperatures the reduction of the asymmetry due to the thermal distribution of one-electron states is not very significant. Finally, using a one-dimensional Anderson model, the effect of lattice disorder on the x-ray absorption spectra is studied for the first time. There are two effects: (1) the strong infrared divergence peak is gradually quenched as disorder is increased, and (2) the threshold is broadened because the threshold energies for absorption at different sites in the crystal depend on the varying local lattice environment. It is proposed that the x-ray spectra may be useful as a tool for studying the degree of electron localization in disordered many-electron systems

Numerical solutions of several reflected shock-wave flow fields with nonequilibrium chemical reactions

Science.gov (United States)

Hanson, R. K.; Presley, L. L.; Williams, E. V.

1972-01-01

The method of characteristics for a chemically reacting gas is used in the construction of the time-dependent, one-dimensional flow field resulting from the normal reflection of an incident shock wave at the end wall of a shock tube. Nonequilibrium chemical reactions are allowed behind both the incident and reflected shock waves. All the solutions are evaluated for oxygen, but the results are generally representative of any inviscid, nonconducting, and nonradiating diatomic gas. The solutions clearly show that: (1) both the incident- and reflected-shock chemical relaxation times are important in governing the time to attain steady state thermodynamic properties; and (2) adjacent to the end wall, an excess-entropy layer develops wherein the steady state values of all the thermodynamic variables except pressure differ significantly from their corresponding Rankine-Hugoniot equilibrium values.

Estimating soil zinc concentrations using reflectance spectroscopy

Science.gov (United States)

Sun, Weichao; Zhang, Xia

2017-06-01

Soil contamination by heavy metals has been an increasingly severe threat to nature environment and human health. Efficiently investigation of contamination status is essential to soil protection and remediation. Visible and near-infrared reflectance spectroscopy (VNIRS) has been regarded as an alternative for monitoring soil contamination by heavy metals. Generally, the entire VNIR spectral bands are employed to estimate heavy metal concentration, which lacks interpretability and requires much calculation. In this study, 74 soil samples were collected from Hunan Province, China and their reflectance spectra were used to estimate zinc (Zn) concentration in soil. Organic matter and clay minerals have strong adsorption for Zn in soil. Spectral bands associated with organic matter and clay minerals were used for estimation with genetic algorithm based partial least square regression (GA-PLSR). The entire VNIR spectral bands, the bands associated with organic matter and the bands associated with clay minerals were incorporated as comparisons. Root mean square error of prediction, residual prediction deviation, and coefficient of determination (R2) for the model developed using combined bands of organic matter and clay minerals were 329.65 mg kg-1, 1.96 and 0.73, which is better than 341.88 mg kg-1, 1.89 and 0.71 for the entire VNIR spectral bands, 492.65 mg kg-1, 1.31 and 0.40 for the organic matter, and 430.26 mg kg-1, 1.50 and 0.54 for the clay minerals. Additionally, in consideration of atmospheric water vapor absorption in field spectra measurement, combined bands of organic matter and absorption around 2200 nm were used for estimation and achieved high prediction accuracy with R2 reached 0.640. The results indicate huge potential of soil reflectance spectroscopy in estimating Zn concentrations in soil.

Audibility of individual reflections in a complete sound field, III

DEFF Research Database (Denmark)

Bech, Søren

1996-01-01

This paper reports on the influence of individual reflections on the auditory localization of a loudspeaker in a small room. The sound field produced by a single loudspeaker positioned in a normal listening room has been simulated using an electroacoustic setup. The setup models the direct sound......-independent absorption coefficients of the room surfaces, and (2) a loudspeaker with directivity according to a standard two-way system and absorption coefficients according to real materials. The results have shown that subjects can distinguish reliably between timbre and localization, that the spectrum level above 2 k...

Vibrational spectra of double oxides of calcium and indium

International Nuclear Information System (INIS)

Porotnikov, N.V.; Kondratov, O.I.; Petrov, K.I.; Olikov, I.I.

1980-01-01

Vibrational spectra of Ca 40 In 2 O 4 and Ca 44 In 2 O 4 dioxides have been studied. Calculations of a theoretical vibrational spectrum of isotope-substituted compounds have been carried out in the approximation of polymer chains of the valence-force field method. The assignment of experimental spectra is proposed. The force field of crystals is evaluated [ru

Beer-Lambert-Law Parametric Model of Reflectance Spectra for Dyed Fabrics

Science.gov (United States)

2016-06-06

reflections from layered systems (i.e., scattering matrix formulations) [12,13,14], the Kubelka-Munk theory of diffuse reflectance (and formulations...mode. The Lambda 1050 incorporated a double beam, 150 mm integrating sphere housing a photomultiplier tube (PMT) detector for the UV-Vis (175 – 860 nm...of the combined system of dye and fabric. This relation follows from the Beer-Lambert law and formalism of the scattering- matrix [20]. In particular

Disentangling overlapping high-field EPR spectra of organic radicals: Identification of light-induced polarons in the record fullerene-free solar cell blend PBDB-T:ITIC.

Science.gov (United States)

Van Landeghem, Melissa; Maes, Wouter; Goovaerts, Etienne; Van Doorslaer, Sabine

2018-03-01

We present a combined high-field EPR and DFT study of light-induced radicals in the bulk heterojunction blend of PBDB-T:ITIC, currently one of the highest efficiency non-fullerene donor:acceptor combinations in organic photovoltaics. We demonstrate two different approaches for disentangling the strongly overlapping high-field EPR spectra of the positive and negative polarons after charge separation: (1) relaxation-filtered field-swept EPR based on the difference in T 1 spin-relaxation times and (2) field-swept EDNMR-induced EPR by exploiting the presence of 14 N hyperfine couplings in only one of the radical species, the small molecule acceptor radical. The approach is validated by light-induced EPR spectra on related blends and the spectral assignment is underpinned by DFT computations. The broader applicability of the spectral disentangling methods is discussed. Copyright © 2018 Elsevier Inc. All rights reserved.

Universal Signatures of Quantum Critical Points from Finite-Size Torus Spectra: A Window into the Operator Content of Higher-Dimensional Conformal Field Theories.

Science.gov (United States)

Schuler, Michael; Whitsitt, Seth; Henry, Louis-Paul; Sachdev, Subir; Läuchli, Andreas M

2016-11-18

The low-energy spectra of many body systems on a torus, of finite size L, are well understood in magnetically ordered and gapped topological phases. However, the spectra at quantum critical points separating such phases are largely unexplored for (2+1)D systems. Using a combination of analytical and numerical techniques, we accurately calculate and analyze the low-energy torus spectrum at an Ising critical point which provides a universal fingerprint of the underlying quantum field theory, with the energy levels given by universal numbers times 1/L. We highlight the implications of a neighboring topological phase on the spectrum by studying the Ising* transition (i.e. the transition between a Z_{2} topological phase and a trivial paramagnet), in the example of the toric code in a longitudinal field, and advocate a phenomenological picture that provides qualitative insight into the operator content of the critical field theory.

Applicability of a Diffuse Reflectance Infrared Fourier Transform handheld spectrometer to perform in situ analyses on Cultural Heritage materials.

Science.gov (United States)

Arrizabalaga, Iker; Gómez-Laserna, Olivia; Aramendia, Julene; Arana, Gorka; Madariaga, Juan Manuel

2014-08-14

This work studies the applicability of a Diffuse Reflectance Infrared Fourier Transform handheld device to perform in situ analyses on Cultural Heritage assets. This portable diffuse reflectance spectrometer has been used to characterise and diagnose the conservation state of (a) building materials of the Guevara Palace (15th century, Segura, Basque Country, Spain) and (b) different 19th century wallpapers manufactured by the Santa Isabel factory (Vitoria-Gasteiz, Basque Country, Spain) and by the well known Dufour and Leroy manufacturers (Paris, France), all of them belonging to the Torre de los Varona Castle (Villanañe, Basque Country, Spain). In all cases, in situ measurements were carried out and also a few samples were collected and measured in the laboratory by diffuse reflectance spectroscopy (DRIFT) in order to validate the information obtained by the handheld instrument. In the analyses performed in situ, distortions in the diffuse reflectance spectra can be observed due to the presence of specular reflection, showing the inverted bands caused by the Reststrahlen effect, in particular on those IR bands with the highest absorption coefficients. This paper concludes that the results obtained in situ by a diffuse reflectance handheld device are comparable to those obtained with laboratory diffuse reflectance spectroscopy equipment and proposes a few guidelines to acquire good spectra in the field, minimising the influence caused by the specular reflection. Copyright © 2014 Elsevier B.V. All rights reserved.

Observation of magnetic domains using a reflection mode scanning near-field optical microscope

NARCIS (Netherlands)

Durkam, C.; Shvets, I.V.; Lodder, J.C.

1997-01-01

It is demonstrated that it is possible to image magnetic domains with a resolution of better than 60 nm with the Kerr effect in a reflection-mode scanning near-field optical microscope. Images taken of tracks of thermomagnetically prewritten bits in a Co/Pt multilayer structure magnetized out-of

Investigation of omnidirectional reflection band in ZnTe/ZnSe distributed Bragg reflector

Energy Technology Data Exchange (ETDEWEB)

Huang, Ying-Shin [Department of Electrical Engineering, National Taiwan Ocean University, Keelung 20224, Taiwan (China); Hu, Sheng-Yao [Department of Digital Technology Design, Tungfang Design University, Kaohsiung 82941, Taiwan (China); Lee, Yueh-Chien, E-mail: jacklee@mail.tnu.edu.tw [Department of Electronic Engineering, Tungnan University, New Taipei City 22202, Taiwan (China); Chang, Chung-Cheng; Tiong, Kwong-Kau [Department of Electrical Engineering, National Taiwan Ocean University, Keelung 20224, Taiwan (China); Shen, Ji-Lin [Department of Physics, Chung Yuan Christian University, Chung-Li 32023, Taiwan (China); Chou, Wu-Ching [Department of Electrophysics, National Chiao Tung University, Hsinchu 30010, Taiwan (China)

2015-11-15

We report the characteristics of reflectance spectra of the 15- and 20-period ZnTe/ZnSe distributed Bragg reflector grown on GaAs (001) substrates by molecular beam epitaxy. The reflectance spectra measured at various incident angles and polarizations were investigated by the theoretical curves simulated using transfer matrix method. The wavelength variation of the refractive indices described by Sellmeier equation and random thickness model were also considered for the interpretation of the experimentally observed curves. An omnidirectional reflection range defined from the edge of incident-angle-dependent reflection band with TE and TM polarizations is about 15 nm, and is consistent with the observed experimental curves. The results showed that the selected ZnTe and ZnSe materials are suitable for constructing multilayer structures having omnidirectional reflection band. - Highlights: • ZnTe/ZnSe distributed Bragg reflector grown by molecular beam epitaxy. • The reflectance spectra are measured at various incidence angles and polarizations. • The theoretical curves are considered by Sellmeier and random thickness models. • An observed omnidirectional reflection range in ZnTe/ZnSe DBR is about 15 nm.

Neutron optics using transverse field neutron spin echo method

International Nuclear Information System (INIS)

Achiwa, Norio; Hino, Masahiro; Yamauchi, Yoshihiro; Takakura, Hiroyuki; Tasaki, Seiji; Akiyoshi, Tsunekazu; Ebisawa, Toru.

1993-01-01

A neutron spin echo (NSE) spectrometer with perpendicular magnetic field to the neutron scattering plane, using an iron yoke type electro-magnet has been developed. A combination of cold neutron guider, supermirror neutron polarizer of double reflection type and supermirror neutron analyser was adopted for the spectrometer. The first application of the NSE spectrometer to neutron optics by passing Larmor precessing neutrons through gas, solid and liquid materials of several different lengths which are inserted in one of the precession field have been examined. Preliminary NSE spectra of this sample geometry are discussed. (author)

Different spectra with the same neutron source

International Nuclear Information System (INIS)

Vega C, H. R.; Ortiz R, J. M.; Hernandez D, V. M.; Martinez B, M. R.; Hernandez A, B.; Ortiz H, A. A.; Mercado, G. A.

2010-01-01

Using as source term the spectrum of a 239 Pu-Be source several neutron spectra have been calculated using Monte Carlo methods. The source term was located in the centre of spherical moderators made of light water, heavy water and polyethylene of different diameters. Also a 239 Pu-Be source was used to measure its neutron spectrum, bare and moderated by water. The neutron spectra were measured at 100 cm with a Bonner spheres spectrometer. Monte Carlo calculations were used to calculate the neutron spectra of bare and water-moderated spectra that were compared with those measured with the spectrometer. Resulting spectra are similar to those found in power plants with PWR, BWR and Candu nuclear reactors. Beside the spectra the dosimetric features were determined. Using moderators and a single neutron source can be produced neutron spectra alike those found in workplaces, this neutron fields can be utilized to calibrate neutron dosimeters and area monitors. (Author)

Final Technical Report - Polymeric Multilayer Infrared Reflecting Mirrors

Energy Technology Data Exchange (ETDEWEB)

Reed, John [3M Company, St. Paul, MN (United States)

2016-09-16

The goal of this project was to develop a clear, polymeric, multilayer film with an expanded infrared (IR) reflection band which would allow improved rejection of incident IR energy. The IR reflection band is covering the region from about 850 nm to 1830 nm. This film is essentially clear and colorless in the visible portion of the electromagnetic spectra (visible light transmission of about 89%) while reflecting 90-95% of the IR energy over the portion of the spectra indicated above. This film has a nominal thickness of 3 mils, is polymeric in nature (contains no metals, metal oxides, or other material types) and is essentially clear in appearance This film can then be used as a component of other products such as a solar window film, an IR reflecting interlayer for laminated glass, a heat rejecting skylight film, a base film for daylight redirecting products, a greenhouse film, and many more applications. One of the main strengths of this product is that because it is a standalone IR rejecting film, it can be incorporated and retrofitted into many applications that desire or require the transmission of visible light, but want to block other portions of the solar spectra, especially the IR portion. Many of the applications exist in the window glazing product area where this film can provide for substantial energy improvements in applications where visible light is desired.

Assessment of reflectivity of noise barriers in the far field – QUIESST method compared to traditional approach

NARCIS (Netherlands)

Roo, F. de

2013-01-01

The sound reflectivity of noise barriers elements is one of the major acoustic product characteristics. Traditionally this property was tested in reverberation rooms according to EN 1793-1 and the results were used to predict the effect of sound reflections in the far field. As in many cases these

Will algorithms modified with soil and weather information improve in-field reflectance-sensing corn nitrogen applications?

Science.gov (United States)

Nitrogen (N) needs to support corn (Zea mays L.) production can be highly variable within fields. Canopy reflectance sensing for assessing crop N health has been implemented on many farmers’ fields to side-dress or top-dress variable-rate N application, but at times farmers report the performance of...

A New Ka-Band Scanning Radar Facility: Polarimetric and Doppler Spectra Measurements of Snow Events

Science.gov (United States)

Oue, M.; Kollias, P.; Luke, E. P.; Mead, J.

2017-12-01

Polarimetric radar analyses offer the capability of identification of ice hydrometeor species as well as their spatial distributions. In addition to polarimetric parameter observations, Doppler spectra measurements offer unique insights into ice particle properties according to particle fall velocities. In particular, millimeter-wavelength radar Doppler spectra can reveal supercooled liquid cloud droplets embedded in ice precipitation clouds. A Ka-band scanning polarimetric radar, named KASPR, was installed in an observation facility at Stony Brook University, located 22 km west of the KOKX NEXRAD radar at Upton, NY. The KASPR can measure Doppler spectra and full polarimetric variables, including radar reflectivity, differential reflectivity (ZDR), differential phase (φDP), specific differential phase (KDP), correlation coefficient (ρhv), and linear depolarization ratio (LDR). The facility also includes a micro-rain radar and a microwave radiometer capable of measuring reflectivity profiles and integrated liquid water path, respectively. The instruments collected initial datasets during two snowstorm events and two snow shower events in March 2017. The radar scan strategy was a combination of PPI scans at 4 elevation angles (10, 20, 45, and 60°) and RHI scans in polarimetry mode, and zenith pointing with Doppler spectra collection. During the snowstorm events the radar observed relatively larger ZDR (1-1.5 dB) and enhanced KDP (1-2 ° km-1) at heights corresponding to a plate/dendrite crystal growth regime. The Doppler spectra showed that slower-falling particles ( 1 m s-1). The weakly increased ZDR could be produced by large, faster falling particles such as quasi-spherical aggregates, while the enhanced KDP could be produced by highly-oriented oblate, slowly-falling particles. Below 2 km altitude, measurements of dual wavelength ratio (DWR) based on Ka and S-band reflectivities from the KASPR and NEXRAD radars were available. Larger DWR (>10 dB) suggested

Theoretical and experimental study of high-magnetic-field XMCD spectra at the L2,3 absorption edges of mixed-valence rare-earth compounds

International Nuclear Information System (INIS)

Kotani, Akio; Matsuda, Yasuhiro H; Nojiri, Hiroyuki

2009-01-01

X-ray magnetic circular dichroism(XMCD) spectra at the L 2,3 edges of mixed-valence rare-earth compounds in high magnetic fields are studied both theoretically and experimentally. The theoretical study is based on a new framework proposed recently by Kotani. The Zeeman splitting of 4f states, the mixed-valence character of 4f states, and the 4f-5d exchange interaction are incorporated into a single impurity Anderson model. New XMCD experiments in high magnetic fields up to 40 T are carried out for the mixed-valence compounds EuNi 2 (Si 0.18 Ge 0.82 ) 2 and YbInCu 4 by using a miniature pulsed magnet, which was developed recently by Matsuda et al. The XMCD data are taken at 5 K by transmission measurements for incident X-rays with ± helicities at BL39XU in SPring-8. After giving a survey on recent developments in the theory of XMCD spectra for mixed-valence Ce and Yb compounds, we calculate the XMCD spectra of YbInCu 4 at the field-induced valence transition around 32 T by applying the recent theoretical framework and by newly introducing at 32 T a discontinuous change in the Yb 4f level and that in the hybridization strength between the Yb 4f and conduction electrons. The calculated results are compared with the experimental ones.

Three-reflections telescope proposal as flat-field anastigmat for wide field observations at Dome C

Science.gov (United States)

Ferrari, M.; Lemaître, G.; Viotti, R.; La Padula, C.; Comte, G.; Blanc, M.; Boer, M.

It is now evident that the exceptional seeing at Dome C will allow, in the next years, to pursue astronomical programs with conditions better than at any other observatory in the world, and very close to space experiments. Considering a new type of wide-field telescope, particular astronomical programs could be well optimized for observations at Dome C such as surveys for the discovery and follow up of near-Earth asteroids, search for extra-solar planets using transit or micro-lensing events, and stellar luminosity variations. We propose to build a 1.5 2m class three-reflections telescope, with 1 1.5degree FOV, four times shorter than an equivalent Schmidt telescope, and providing a flat field without requiring a triplet- or quadruplet-lens corrector since its design is anastigmatic. We present the preliminary optical tests of such designs: MINITRUST1 and 2 are two 45cm identical prototypes based in France and Italy, and manufactured using active optics techniques.

Investigation of gamma spectra analysis

International Nuclear Information System (INIS)

Wu Huailong; Liu Suping; Hao Fanhua; Gong Jian; Liu Xiaoya

2006-01-01

In the investigation of radiation fingerprint comparison, it is found out that some of the popular gamma spectra analysis software have shortcomings, which decrease the radiation fingerprint comparison precision. So a new analysis software is developed for solving the problems. In order to display the advantage of developed program, some typical simulative warhead gamma spectra are analyzed respectively by present software and GAMMAVISION and GENNIE2000. Present software can be applied not only in nuclear warheads deep-cuts verification, but also in any radiation measurement field. (authors)

Simple emergent power spectra from complex inflationary physics

International Nuclear Information System (INIS)

Dias, Mafalda; Frazer, Jonathan; Marsh, M.C. David

2016-04-01

We construct ensembles of random scalar potentials for N f interacting scalar fields using non-equilibrium random matrix theory, and use these to study the generation of observables during small-field inflation. For N f =O(few), these heavily featured scalar potentials give rise to power spectra that are highly non-linear, at odds with observations. For N f >>1, the superhorizon evolution of the perturbations is generically substantial, yet the power spectra simplify considerably and become more predictive, with most realisations being well approximated by a linear power spectrum. This provides proof of principle that complex inflationary physics can give rise to simple emergent power spectra. We explain how these results can be understood in terms of large N f universality of random matrix theory.

The effect of radiation-thermal treatment on the physicochemical properties of the Ni-Mo/Al2O3 hydrotreatment catalyst. II. UV-Vis diffuse reflectance spectra of surface compounds after irradiation

International Nuclear Information System (INIS)

Solovetskii, Yu.I.; Miroshinichenko, I.I.; Lunin, V.V.

1993-01-01

Radiation-thermal damage of the surface and the active metal phases of hydrodesulfurization Ni-Mo/Al 2 O 3 catalysts by a fast electron beam of up to 2.0 MeV energy was studied. UV-Vis diffuse reflectance spectra of the industrial and model coked systems after radiation-thermal treatment were measured. 14 refs., 2 figs

Hyperspectral reflectance of leaves and flowers of an outbreak species discriminates season and successional stage of vegetation

Science.gov (United States)

Carvalho, Sabrina; Schlerf, Martin; van der Putten, Wim H.; Skidmore, Andrew K.

2013-10-01

Spectral reflectance can be used to assess large-scale performances of plants in the field based on plant nutrient balance as well as composition of defence compounds. However, plant chemical composition is known to vary with season - due to its phenology - and it may even depend on the succession stage of its habitat. Here we investigate (i) how spectral reflectance could be used to discriminate successional and phenological stages of Jacobaea vulgaris in both leaf and flower organs and (ii) if chemical content estimation by reflectance is flower or leaf dependent. We used J. vulgaris, which is a natural outbreak plant species on abandoned arable fields in north-western Europe and studied this species in a chronosequence representing successional development during time since abandonment. The chemical content and reflectance between 400 and 2500 nm wavelengths of flowers and leaves were measured throughout the season in fields of different successional ages. The data were analyzed with multivariate statistics for temporal discrimination and estimation of chemical contents in both leaf and flower organs. Two main effects were revealed by spectral reflectance measurements: (i) both flower and leaf spectra show successional and seasonal changes, but the pattern is complex and organ specific (ii) flower head pyrrolizidine alkaloids, which are involved in plant defence against herbivores, can be detected through hyperspectral reflectance.We conclude that spectral reflectance of both leaves and flowers can provide information on plant performance during season and successional stages. As a result, remote sensing studies of plant performance in complex field situations will benefit from considering hyperspectral reflectance of different plant organs. This approach may enable more detailed studies on the link between spectral information and plant defence dynamics both aboveground and belowground.

Automated spectro-goniometer: A spherical robot for the field measurement of the directional reflectance of snow

International Nuclear Information System (INIS)

Painter, Thomas H.; Paden, Brad; Dozier, Jeff

2003-01-01

We describe an automated spectro-goniometer (ASG) that rapidly measures the spectral hemispherical-directional reflectance factor (HDRF) of snow in the field across the wavelength range 0.4≤λ≤2.5 μm. Few measurements of snow's HDRF exist in the literature, in part caused by a lack of a portable instrument capable of rapid, repeatable sampling. The ASG is a two-link spherical robot coupled to a field spectroradiometer. The ASG is the first revolute joint and first automated field goniometer for use over snow and other smooth surfaces. It is light enough (∼50 kg) to be portable in a sled by an individual. The ASG samples the HDRF at arbitrary angular resolution and 0.5 Hz sampling rate. The arm attaches to the fixed-point frame 0.65 m above the surface. With vertical and oblique axes, the ASG places the sensor of the field spectroradiometer at any point on the hemisphere above a snow target. In standard usage, the ASG has the sun as the illumination source to facilitate in situ measurements over fragile surfaces not easily transported to the laboratory and to facilitate simultaneous illumination conditions for validation and calibration of satellite retrievals. The kinematics of the ASG is derived using Rodrigues' formula applied to the 2 degree-of-freedom arm. We describe the inverse kinematics for the ASG and solve the inverse problem from a given view angle to the necessary rotation about each axis. Its two-dimensional hemispheric sampling space facilitates the measurement of spectral reflectance from snow and other relatively smooth surfaces into any direction. The measurements will be used to validate radiative transfer model results of directional reflectance and to validate/calibrate directional satellite measurements of reflectance from these smooth surfaces

Absorption spectra of AA-stacked graphite

International Nuclear Information System (INIS)

Chiu, C W; Lee, S H; Chen, S C; Lin, M F; Shyu, F L

2010-01-01

AA-stacked graphite shows strong anisotropy in geometric structures and velocity matrix elements. However, the absorption spectra are isotropic for the polarization vector on the graphene plane. The spectra exhibit one prominent plateau at middle energy and one shoulder structure at lower energy. These structures directly reflect the unique geometric and band structures and provide sufficient information for experimental fitting of the intralayer and interlayer atomic interactions. On the other hand, monolayer graphene shows a sharp absorption peak but no shoulder structure; AA-stacked bilayer graphene has two absorption peaks at middle energy and abruptly vanishes at lower energy. Furthermore, the isotropic features are expected to exist in other graphene-related systems. The calculated results and the predicted atomic interactions could be verified by optical measurements.

Built-in electric field effect on optical absorption spectra of strained (In,Ga)N–GaN nanostructures

Energy Technology Data Exchange (ETDEWEB)

El Ghazi, Haddou, E-mail: hadghazi@gmail.com [LPS, Faculty of Science, Dhar EL Mehrez, BP 1796 Fes-Atlas (Morocco); Special Mathematics, CPGE Rabat, Rabat (Morocco); John Peter, A. [Department of Physics, Govt. Arts and Science College, Melur, 625106 Madurai (India)

2015-08-15

Based on the effective-mass and the one band parabolic approximations, first order linear, third-order nonlinear and total optical properties related to 1s–1p intra-conduction band transition in wurtzite strained (In,Ga)N–GaN spherical QDs are calculated. The built-in electric field effect, due to the spontaneous and piezoelectric components, is investigated variationally under finite confinement potential. The results reveal that size and internal composition of the dot have a great influence on in-built electric field which affects strongly the optical absorption spectra. It is also found that the modulation of the absorption coefficient, which is suitable for the better performance of optical device applications, can be easily obtained by adjusting geometrical size and internal composition.

Analysis of bacteria on steel surfaces using reflectance micro-Fourier transform infrared spectroscopy.

Science.gov (United States)

Ojeda, Jesús J; Romero-González, María E; Banwart, Steven A

2009-08-01

Reflectance micro-Fourier transform infrared (FT-IR) analysis has been applied to characterize biofilm formation of Aquabacterium commune, a common microorganism present on drinking water distribution systems, onto the increasingly popular pipe material stainless steel EN1.4307. The applicability of the reflectance micro-FT-IR technique for analyzing the bacterial functional groups is discussed, and the results are compared to spectra obtained using more conventional FT-IR techniques: transmission micro-FT-IR, attenuated transmitted reflectance (ATR), and KBr pellets. The differences between the infrared spectra of wet and dried bacteria, as well as free versus attached bacteria, are also discussed. The spectra obtained using reflectance micro-FT-IR spectroscopy were comparable to those obtained using other FT-IR techniques. The absence of sample preparation, the potential to analyze intact samples, and the ability to characterize opaque and thick samples without the need to transfer the bacterial samples to an infrared transparent medium or produce a pure culture were the main advantages of reflectance micro-FT-IR spectroscopy.

Reconstructing in-vivo reflectance spectrum of pigmented skin lesion by Monte Carlo simulation

Science.gov (United States)

Wang, Shuang; He, Qingli; Zhao, Jianhua; Lui, Harvey; Zeng, Haishan

2012-03-01

In dermatology applications, diffuse reflectance spectroscopy has been extensively investigated as a promising tool for the noninvasive method to distinguish melanoma from benign pigmented skin lesion (nevus), which is concentrated with the skin chromophores like melanin and hemoglobin. We carried out a theoretical study to examine melanin distribution in human skin tissue and establish a practical optical model for further pigmented skin investigation. The theoretical simulation was using junctional nevus as an example. A multiple layer skin optical model was developed on established anatomy structures of skin, the published optical parameters of different skin layers, blood and melanin. Monte Carlo simulation was used to model the interaction between excitation light and skin tissue and rebuild the diffuse reflectance process from skin tissue. A testified methodology was adopted to determine melanin contents in human skin based on in vivo diffuse reflectance spectra. The rebuild diffuse reflectance spectra were investigated by adding melanin into different layers of the theoretical model. One of in vivo reflectance spectra from Junctional nevi and their surrounding normal skin was studied by compare the ratio between nevus and normal skin tissue in both the experimental and simulated diffuse reflectance spectra. The simulation result showed a good agreement with our clinical measurements, which indicated that our research method, including the spectral ratio method, skin optical model and modifying the melanin content in the model, could be applied in further theoretical simulation of pigmented skin lesions.

Scaling properties of optical reflectance from quasi-periodic superlattices

International Nuclear Information System (INIS)

Wu Xiang; Yao Hesheng; Feng Weiguo

1991-08-01

The scaling properties of the optical reflectance from two types of quasi-periodic metal-insulator superlattices, one with the structure of Cantor bars and the other with the structure of Cantorian-Fibonaccian train, have been studied for the region of s-polarized soft x-rays and extreme ultraviolet. By using the hydrodynamic model of electron dynamics and transfer-matrix method, and be taking into account retardation effects, we have presented the formalism of the reflectivity for the superlattices. From our numerical results, we found that the reflection spectra of the quasi-superlattices have a rich structure of self-similarity. The interesting scaling indices, which are related to the fractal dimensions, of the spectra are also discussed for the two kinds of the quasi-superlattices. (author). 10 refs, 7 figs

Lunar surface remanent magnetic fields detected by the electron reflection method

Science.gov (United States)

Lin, R. P.; Anderson, K. A.; Bush, R.; Mcguire, R. E.; Mccoy, J. E.

1976-01-01

We present maps of the lunar surface remanent magnetic fields detected by the electron reflection method. These maps provide substantial coverage of the latitude band from 30 N southward to 30 S with a resolution of about 40 km and a sensitivity of about 0.2 gamma at the lunar surface. Regions of remanent magnetization are observed ranging in size from the resolution limit of 1.25 deg to above approximately 60 deg. The largest contiguous region fills the Big Backside Basin where it is intersected by the spacecraft orbital tracks. Preliminary analyses of the maps show that the source regions of lunar limb compressions correspond to regions of strong surface magnetism, and that there does not appear to be sharply discontinuous magnetization at the edges of maria. We also analyze the electron reflection observations to obtain information on the direction and distribution of magnetization in the Van de Graaff anomaly region.

Polar phonons in β-Ga2O3 studied by IR reflectance spectroscopy and first-principle calculations

Science.gov (United States)

Azuhata, Takashi; Shimada, Kazuhiro

2017-08-01

IR reflectance spectra of β-Ga2O3 are measured in the range from 400 to 1100 cm-1 using the (\\bar{2}01) and (010) planes for pure transverse Au- and Bu-mode phonons, respectively. The spectra measured using the (010) plane depend remarkably on the polarization direction of the incident light because of the monoclinic symmetry. Reflectance spectra simulated using parameters obtained from first-principle calculations are in good agreement with the experimental spectra. By adjusting the calculated phonon parameters so as to reproduce the experimental spectra, the polar phonon parameters were determined for six modes above 400 cm-1.

Investigation of gamma spectra analysis

International Nuclear Information System (INIS)

Wu Huailong; Liu Suping; Hao Fanhua

2006-12-01

During the investigation of radiation fingerprint comparison, it is found out that the popular gamma spectra analysis softwares are faultful, which decrease the precision of radiation fingerprint comparison. So a new analysis software is development for solving the problems. In order to display the advantage of new program, some typical simulative gamma spectra of radiation source are analyzed respectively by our software and GAMMAVISION and GENNIE2000. The software can be applied not only in nuclear warheads deep-cuts verification, but also in any radiation measurement field. (authors)

UV, visible, and near-IR reflectivity data for magnetic soils/rocks from Brazil

Science.gov (United States)

Vempati, R. K.; Morris, R. V.; Lauer, H. V., Jr.; Coey, J. M. D.

1991-01-01

The objective is to obtain UV, visible, and near-IR reflectivity spectra for several magnetic Brazilian soils/rocks and compare them to corresponding data for Mars to see if these materials satisfy both magnetic and spectral constraints for Mars. Selected physical properties of the magnetic Brazilian soils/rocks are presented. In general, the spectral features resulting from ferric crystal-field transitions are much better defined in the spectra of the magnetic Brazilian soils/rocks than in Martian spectral data. Presumably, this results from a relatively higher proportion of crystalline ferric oxides for the former. The apparent masking of the spectral signature of maghemite by hematite or goethite for the Brazilian samples implies the magnetic and spectral constraints for Mars can be decoupled. That is, maghemite may be present in magnetically-significant but optically-insignificant amounts compared to crystalline hematite.

Assessing Pearl Quality Using Reflectance UV-Vis Spectroscopy: Does the Same Donor Produce Consistent Pearl Quality?

Directory of Open Access Journals (Sweden)

Paul C. Southgate

2010-09-01

Full Text Available Two groups of commercial quality (“acceptable” pearls produced using two donors, and a group of “acceptable” pearls from other donors were analyzed using reflectance UV-Vis spectrophotometry. Three pearls with different colors produced by the same donor showed different absorption spectra. Cream and gold colored pearls showed a wide absorption from 320 to about 460 nm, while there was just slight reflectance around 400 nm by the white pearl with a pink overtone. Cream and gold pearls reached a reflectance peak at 560 to 590 nm, while the white pearl with pink overtone showed slightly wider absorption in this region. Both cream and gold pearls showed an absorption peak after the reflectance peak, at about 700 nm for the cream pearl and 750 nm for the gold pearl. Two other pearls produced by the same donor (white with cream overtone and cream with various overtones showed similar spectra, which differed in their intensity. One of these pearls had very high lustre and its spectrum showed a much higher percentage reflectance than the second pearl with inferior lustre. This result may indicate that reflectance is a useful quantitative indicator of pearl lustre. The spectra of two white pearls resulting from different donors with the same color nacre (silver showed a reflectance at 260 nm, followed by absorption at 280 nm and another reflectance peak at 340 nm. After this peak the spectra for these pearls remained flat until a slight absorption peak around 700 nm. Throughout the visible region, all white pearls used in this study showed similar reflectance spectra although there were differences in reflectance intensity. Unlike the spectral results from white pearls, the results from yellow and gold pearls varied according to color saturation of the pearl. The results of this study show that similarities between absorption and reflectance spectra of cultured pearls resulting from the same saibo donor are negligible and could not be detected

Defects in UV-vis-NIR reflectance spectra as method for forgery detections in writing documents

Energy Technology Data Exchange (ETDEWEB)

Somma, F; Aloe, P; Schirripa Spagnolo, G

2010-11-01

Documents have taken up a very important place in our society. Frauds committed in connection with documents are not at all uncommon, and, in fact, represent a very large domain of the forensic science called 'questioned documents'. In the field of forensic examination of questioned documents, the legitimacy of an ink entry is often an essential question. A common type of forgery consists in materially altering an existing writing or adding a new writing. These changes can be characterized by means of optical spectroscopy. The aim of this work is to perform the UV-vis-NIR reflectance spectrophotometry to analyze a range of blue and black commercial ballpoint pens, in order to investigate the discriminating abilities of the different inks found on the same document.

Simple emergent power spectra from complex inflationary physics

Energy Technology Data Exchange (ETDEWEB)

Dias, Mafalda; Frazer, Jonathan [Deutsches Elektronen-Synchrotron (DESY), Hamburg (Germany); Marsh, M.C. David [Cambridge Univ. (United Kingdom). Dept. of Applied Mathematics and Theoretical Physics (DAMTP)

2016-04-15

We construct ensembles of random scalar potentials for N{sub f} interacting scalar fields using non-equilibrium random matrix theory, and use these to study the generation of observables during small-field inflation. For N{sub f}=O(few), these heavily featured scalar potentials give rise to power spectra that are highly non-linear, at odds with observations. For N{sub f}>>1, the superhorizon evolution of the perturbations is generically substantial, yet the power spectra simplify considerably and become more predictive, with most realisations being well approximated by a linear power spectrum. This provides proof of principle that complex inflationary physics can give rise to simple emergent power spectra. We explain how these results can be understood in terms of large N{sub f} universality of random matrix theory.

Electromagnetically induced reflectance and Fano resonance in one dimensional superconducting photonic crystal

Science.gov (United States)

Athe, Pratik; Srivastava, Sanjay; Thapa, Khem B.

2018-04-01

In the present work, we demonstrate the generation of optical Fano resonance and electromagnetically induced reflectance (EIR) in one-dimensional superconducting photonic crystal (1D SPC) by numerical simulation using transfer matrix method as analysis tool. We investigated the optical response of 1D SPC structure consisting of alternate layer of two different superconductors and observed that the optical spectra of this structure exhibit two narrow reflectance peaks with zero reflectivity of sidebands. Further, we added a dielectric cap layer to this 1D SPC structure and found that addition of dielectric cap layer transforms the line shape of sidebands around the narrow reflectance peaks which leads to the formation of Fano resonance and EIR line shape in reflectance spectra. We also studied the effects of the number of periods, refractive index and thickness of dielectric cap layer on the lineshape of EIR and Fano resonances. It was observed that the amplitude of peak reflectance of EIR achieves 100% reflectance by increasing the number of periods.

Reflection and refraction of a transient temperature field at a plane interface using Cagniard-de Hoop approach.

Science.gov (United States)

Shendeleva, M L

2001-09-01

An instantaneous line heat source located in the medium consisting of two half-spaces with different thermal properties is considered. Green's functions for the temperature field are derived using the Laplace and Fourier transforms in time and space and their inverting by the Cagniard-de Hoop technique known in elastodynamics. The characteristic feature of the proposed approach consists in the application of the Cagniard-de Hoop method to the transient heat conduction problem. The idea is suggested by the fact that the Laplace transform in time reduces the heat conduction equation to a Helmholtz equation, as for the wave propagation. Derived solutions exhibit some wave properties. First, the temperature field is decomposed into the source field and the reflected field in one half-space and the transmitted field in the other. Second, the laws of reflection and refraction can be deduced for the rays of the temperature field. In this connection the ray concept is briefly discussed. It is shown that the rays, introduced in such a way that they are consistent with Snell's law do not represent the directions of heat flux in the medium. Numerical computations of the temperature field as well as diagrams of rays and streamlines of the temperature field are presented.

Coherent manipulation of spontaneous emission spectra in coupled semiconductor quantum well structures.

Science.gov (United States)

Chen, Aixi

2014-11-03

In triple coupled semiconductor quantum well structures (SQWs) interacting with a coherent driving filed, a coherent coupling field and a weak probe field, spontaneous emission spectra are investigated. Our studies show emission spectra can easily be manipulated through changing the intensity of the driving and coupling field, detuning of the driving field. Some interesting physical phenomena such as spectral-line enhancement/suppression, spectral-line narrowing and spontaneous emission quenching may be obtained in our system. The theoretical studies of spontaneous emission spectra in SQWS have potential application in high-precision spectroscopy. Our studies are based on the real physical system [Appl. Phys. Lett.86(20), 201112 (2005)], and this scheme might be realizable with presently available techniques.

Foliar Reflectance and Fluorescence Responses for Plants Under Nitrogen Stress Determined with Active and Passive Systems

Science.gov (United States)

Middleton, E. M.; McMurtrey, J. E.; Campbell, P. K. Entcheva; Corp, L. A.; Butcher, L. M.; Chappelle, E. W.

2003-01-01

Vegetation productivity is driven by nitrogen (N) availability in soils. Both excessive and low soil N induce physiological changes in plant foliage. In 2001, we examined the use of spectral fluorescence and reflectance measurements to discriminate among plants provided different N fertilizer application rates: 20%, 50%, 100% and 150% of optimal N levels. A suite of optical, fluorescence, and biophysical measurements were collected on leaves from field grown corn (Zea mays L.) and soybean plants (Glycine max L.) grown in pots (greenhouse + ambient sunlight daily). Three types of steady state laser-induced fluorescence measurements were made on adaxial and abaxial surfaces: 1) fluorescence images in four 10 nm bands (blue, green, red, far-red) resulting from broad irradiance excitation; 2) emission spectra (5 nm resolution) produced by excitation at single wavelengths (280,380 or 360, and 532 nm); and 3) excitation spectra (2 nm resolution), with emission wavelengths fixed at wavelengths centered on selected solar Fraunhofer lines (532,607,677 and 745 nm). Two complementary sets of high resolution (less than 2 nm) optical spectra were acquired for both adaxial and abaxial leaf surfaces: 1) optical properties (350-2500 nm) for reflectance, transmittance, and absorptance; and 2) reflectance spectra (500-1000 nm) acquired with and without a short pass filter at 665 nm to determine the fluorescence contribution to apparent reflectance in the 650-750 spectrum, especially at the 685 and 740 nm chlorophyll fluorescence (ChIF) peaks. The strongest relationships between foliar chemistry and optical properties were demonstrated for C/N content and two optical parameters associated with the red edge inflection point. Select optical properties and ChIF parameters were highly correlated for both species. A significant contribution of ChIF to apparent reflectance was observed, averaging 10-25% at 685 nm and 2 - 6% at 740 nm over all N treatments. Discrimination of N treatment

Classification spectra of Sanduleak and Stephenson emission-line stars

International Nuclear Information System (INIS)

Allen, D.A.

1978-01-01

Low dispersion slit spectra of 89 emission-line stars are described; these stars were originally located and classified by Sanduleak and Stephenson in an objective-prism survey. The new data broadly confirm the classification scheme adopted by Sanduleak and Stephenson. In particular most of the large number of symbiotic stars they classified have been confirmed and others found. Many of these contain strong, broad emission bands in their red spectra. Two new Wolf-Rayet stars, one new planetary nebula and two new bipolar reflection nebulae involving hidden emission-line stars have been found. (author)

Classification spectra of Sanduleak and Stephenson emission-line stars

Energy Technology Data Exchange (ETDEWEB)

Allen, D A [Anglo-Australian Observatory, Epping (Australia)

1978-09-01

Low dispersion slit spectra of 89 emission-line stars are described; these stars were originally located and classified by Sanduleak and Stephenson in an objective-prism survey. The new data broadly confirm the classification scheme adopted by Sanduleak and Stephenson. In particular most of the large number of symbiotic stars they classified have been confirmed and others found. Many of these contain strong, broad emission bands in their red spectra. Two new Wolf-Rayet stars, one new planetary nebula and two new bipolar reflection nebulae involving hidden emission-line stars have been found.

Magnetic fields and star formation: evidence from imaging polarimetry of the Serpens Reflection Nebula

Energy Technology Data Exchange (ETDEWEB)

Warren-Smith, R F; Draper, P W; Scarrott, S M

1987-08-01

CCD imaging of the Serpens bipolar reflection nebula shows it to be surrounded by dark material having spiral density structure. Multi-colour polarization mapping also reveals details of the surrounding magnetic field, indicating that this also has spiral structure. These observations are discussed along with current ideas about the role of magnetic fields during star formation. An interpretation involving the non-axisymmetric magnetically braked collapse of a protostellar cloud is proposed and a resulting magnetic field configuration is described which can account for the observations. Evidence is also discussed for the formation of a binary star system within the nebula, resulting from the fragmentation of a magnetized protostellar disc.

Electro-optical properties of zigzag and armchair boron nitride nanotubes under a transverse electric field: Tight binding calculations

Science.gov (United States)

Chegel, Raad; Behzad, Somayeh

2012-02-01

The electro-optical properties of zigzag and armchair BNNTs in a uniform transverse electric field are investigated within tight binding approximation. It is found that the electric field modifies the band structure and splits band degeneracy where these effects reflect in the DOS and JDOS spectra. A decrease in the band gap, as a function of the electric field, is observed. This gap reduction increases with the diameter and it is independent of chirality. An analytic function to estimate the electric field needed for band gap closing is proposed which is in good agreement with DFT results. In additional, we show that the larger diameter tubes are more sensitive than small ones. Number and position of peaks in DOS and JDOS spectra for armchair and zigzag tubes with similar radius are dependent on electric field strength.

Angular dependance of spectral reflection for different materials

Science.gov (United States)

Kiefer, Pascal M.

2017-10-01

Parameters like the sun angle as well as the measurement angle mostly are not taken into account when simulating because their influence on the reflectivity is weak. Therefore the impact of a changing measurement and illumination angle on the reflectivity is investigated. Furthermore the impact of humidity and chlorophyll in the scenery is studied by analyzing reflectance spectra of different vegetative background areas. It is shown that the measurement as well as the illumination angle has an important influence on the absolute reflection values which raises the importance of measurements of the bidirectional reflectance distribution function (BRDF).

A reflecting time-of-flight mass spectrometer

Energy Technology Data Exchange (ETDEWEB)

Tang, X

1991-01-01

The design, construction and operation of a reflecting time-of-flight mass spectrometer and the details of the ion mirror are discussed. The principle of velocity focusing with a single-stage ion mirror and the effect of the acceleration region are discussed. The performance of the reflecting instrument is described. Its detection limit is illustrated by observation of [M + H][sup +] ions from [approximately]5-35 femtomoles of various peptides. The factors that affect the resolution are discussed. The principle and operation of the reflecting instrument as a tandem mass spectrometer is described; this involves correlated detection of neutral and ionized fragments. The efficiency, resolution, sensitivity, and mass determination of daughter ions by this method are discussed. Methods of sample preparation are described. By using a nitrocellulose substrate, organic molecular ions as large as bovine insulin (MW 5733) were detected for the first time with low energy (keV) ion bombardment of a solid surface. Many daughter ion spectra resulting from metastable decay of parent ions have been studied. Secondary ions [(CsI)[sub n]Cs][sup +] with n up to [approximately]50 were detected; all clusters were found to be metastable, with most lifetimes <100 [mu]s, and for n>10 the daughter ions are dominant in the mass spectrum. Peptides of mass up to [approximately]2000 u have been studied with the correlated method; the daughter ion spectra were found to be strongly influenced by the identity of the bound cation (H[sup +], Na[sup +], K[sup +], or Ag[sup +]). Many daughter ions formed by known reactions yield structure and sequence information about the peptides. In addition, the [M + Na][sup +] and [M + Ag][sup +] ions decompose by a previously unreported pathway, namely, rearrangement of a C-terminal carboxyl oxygen onto the daughter ion containing the N-terminus. Both the reflected spectra and daughter ion spectra were found useful in peptide sequencing.

Photoluminescence spectra of n-doped double quantum wells in a parallel magnetic field

International Nuclear Information System (INIS)

Huang, D.; Lyo, S.K.

1999-01-01

We show that the photoluminescence (PL) line shapes from tunnel-split ground sublevels of n-doped thin double quantum wells (DQW close-quote s) are sensitively modulated by an in-plane magnetic field B parallel at low temperatures (T). The modulation is caused by the B parallel -induced distortion of the electronic structure. The latter arises from the relative shift of the energy-dispersion parabolas of the two quantum wells (QW close-quote s) in rvec k space, both in the conduction and valence bands, and formation of an anticrossing gap in the conduction band. Using a self-consistent density-functional theory, the PL spectra and the band-gap narrowing are calculated as a function of B parallel , T, and the homogeneous linewidths. The PL spectra from symmetric and asymmetric DQW close-quote s are found to show strikingly different behavior. In symmetric DQW close-quote s with a high density of electrons, two PL peaks are obtained at B parallel =0, representing the interband transitions between the pair of the upper (i.e., antisymmetric) levels and that of the lower (i.e., symmetric) levels of the ground doublets. As B parallel increases, the upper PL peak develops an N-type kink, namely a maximum followed by a minimum, and merges with the lower peak, which rises monotonically as a function of B parallel due to the diamagnetic energy. When the electron density is low, however, only a single PL peak, arising from the transitions between the lower levels, is obtained. In asymmetric DQW close-quote s, the PL spectra show mainly one dominant peak at all B parallel close-quote s. In this case, the holes are localized in one of the QW close-quote s at low T and recombine only with the electrons in the same QW. At high electron densities, the upper PL peak shows an N-type kink like in symmetric DQW close-quote s. However, the lower peak is absent at low B parallel close-quote s because it arises from the inter-QW transitions. Reasonable agreement is obtained with recent

Microcavity-coupled fiber Bragg grating with tunable reflection spectra and speed of light.

Science.gov (United States)

Chen, Lei; Han, Ya; Liu, Qian; Liu, Yan-Ge; Zhang, Weigang; Chou, Keng C

2018-04-15

After a fiber Bragg grating (FBG) is fabricated, the reflection spectrum of the FBG is generally not tunable without mechanical deformation or temperature adjustment. Here we present a microcavity-coupled FBG with both a tunable reflection lineshape and dispersion using electromagnetically induced transparency. The Fano interference of light in the FBG and the microcavity allows for dramatic modification of the reflection spectrum. The phase of the reflected spectrum is continuously tunable between 0 and 2π to produce various Fano lineshapes. The dispersion of the output light is adjustable from normal dispersion to abnormal dispersion, consequently providing an adjustable speed of light. Additionally, it allows the FBG to switch from a notch filter to a bandpass filter at the resonant wavelength, which is not possible in a conventional uniform FBG.

Resolution Improvements in in Vivo1H NMR Spectra with Increased Magnetic Field Strength

Science.gov (United States)

Gruetter, Rolf; Weisdorf, Sally A.; Rajanayagan, Vasantham; Terpstra, Melissa; Merkle, Hellmut; Truwit, Charles L.; Garwood, Michael; Nyberg, Scott L.; Ugurbil, Kâmil

1998-11-01

The measurement of cerebral metabolites using highly homologous localization techniques and similar shimming methods was performed in the human brain at 1.5 and 4 T as well as in the dog and rat brain at 9.4 T. In rat brain, improved resolution was achieved by shimming all first- and second-order shim coils using a fully adiabatic FASTMAP sequence. The spectra showed a clear improvement in spectral resolution for all metabolite resonances with increased field strength. Changes in cerebral glutamine content were clearly observed at 4 T compared to 1.5 T in patients with hepatic encephalopathy. At 9.4 T, glutamine H4 at 2.46 ppm was fully resolved from glutamate H4 at 2.37 ppm, as was the potential resonance from γ-amino-butyric acid at 2.30 ppm and N-acetyl-aspartyl-glutamate at 2.05 ppm. Singlet linewidths were found to be as low as 6 Hz (0.015 ppm) at 9.4 T, indicating a substantial decrease in ppm linewidth with field strength. Furthermore, the methylene peak of creatine was partially resolved from phosphocreatine, indicating a close to 1:1 relationship in gray matter. We conclude that increasing the magnetic field strength increases spectral resolution also for1H NMR, which can lead to more than linear sensitivity gains.

Techniques for Handling and Removal of Spectral Channels in Fourier Transform Synchrotron-Based Spectra

International Nuclear Information System (INIS)

Ibrahim, Amr; Predoi-Cross, Adriana; Teillet, Philippe M.

2010-01-01

Channel spectra are a big problem for those attempting to use synchrotron-based Fourier transform spectra for spectral lineshape studies. Due to the layout of the optical system at the CLS far-infrared beamline, the synchrotron beam undergoes unavoidable multiple reflections on the steering mirrors, beam splitter, several sets of windows, and filters. We present a method for eliminating channel spectra and compare the results of our technique with other methods available in the literature.

Profile of male-field dependent (FD) prospective teacher's reflective thinking in solving contextual mathematical problem

Science.gov (United States)

Agustan, S.; Juniati, Dwi; Siswono, Tatag Yuli Eko

2017-08-01

Reflective thinking is an important component in the world of education, especially in professional education of teachers. In learning mathematics, reflective thinking is one way to solve mathematical problem because it can improve student's curiosity when student faces a mathematical problem. Reflective thinking is also a future competence that should be taught to students to face the challenges and to respond of demands of the 21st century. There are many factors which give impact toward the student's reflective thinking when student solves mathematical problem. One of them is cognitive style. For this reason, reflective thinking and cognitive style are important things in solving contextual mathematical problem. This research paper describes aspect of reflective thinking in solving contextual mathematical problem involved solution by using some mathematical concept, namely linear program, algebra arithmetic operation, and linear equations of two variables. The participant, in this research paper, is a male-prospective teacher who has Field Dependent. The purpose of this paper is to describe aspect of prospective teachers' reflective thinking in solving contextual mathematical problem. This research paper is a descriptive by using qualitative approach. To analyze the data, the researchers focus in four main categories which describe prospective teacher's activities using reflective thinking, namely; (a) formulation and synthesis of experience, (b) orderliness of experience, (c) evaluating the experience and (d) testing the selected solution based on the experience.

EPR spectroscopy of MRI-related Gd(III) complexes: simultaneous analysis of multiple frequency and temperature spectra, including static and transient crystal field effects.

Science.gov (United States)

Rast, S; Borel, A; Helm, L; Belorizky, E; Fries, P H; Merbach, A E

2001-03-21

For the first time, a very general theoretical method is proposed to interpret the full electron paramagnetic resonance (EPR) spectra at multiple temperatures and frequencies in the important case of S-state metal ions complexed in liquid solution. This method is illustrated by a careful analysis of the measured spectra of two Gd3+ (S = 7/2) complexes. It is shown that the electronic relaxation mechanisms at the origin of the EPR line shape arise from the combined effects of the modulation of the static crystal field by the random Brownian rotation of the complex and of the transient zero-field splitting. A detailed study of the static crystal field mechanism shows that, contrarily to the usual global models involving only second-order terms, the fourth and sixth order terms can play a non-negligible role. The obtained parameters are well interpreted in the framework of the physics of the various underlying relaxation processes. A better understanding of these mechanisms is highly valuable since they partly control the efficiency of paramagnetic metal ions in contrast agents for medical magnetic resonance imaging (MRI).

Surface composition of Mercury from reflectance spectrophotometry

Science.gov (United States)

Vilas, Faith

1988-01-01

The controversies surrounding the existing spectra of Mercury are discussed together with the various implications for interpretations of Mercury's surface composition. Special attention is given to the basic procedure used for reducing reflectance spectrophotometry data, the factors that must be accounted for in the reduction of these data, and the methodology for defining the portion of the surface contributing the greatest amount of light to an individual spectrum. The application of these methodologies to Mercury's spectra is presented.

The optics of gyrotropic crystals in the field of two counter-propagating ultrasound waves

International Nuclear Information System (INIS)

Gevorgyan, A H; Harutyunyan, E M; Hovhannisyan, M A; Matinyan, G K

2014-01-01

We consider oblique light propagation through a layer of a gyrotropic crystal in the field of two counter-propagating ultrasound waves. The problem is solved by Ambartsumyan's layer addition modified method. The results of the reflection spectra for different values of the problem parameters are presented. The possibilities of such system applications are discussed.

The Charge State of Polycyclic Aromatic Hydrocarbons across a Reflection Nebula, an H II Region, and a Planetary Nebula

Science.gov (United States)

Boersma, C.; Bregman, J.; Allamandola, L. J.

2018-05-01

Low-resolution Spitzer-IRS spectral map data of a reflection nebula (NGC 7023), H II region (M17), and planetary nebula (NGC 40), totaling 1417 spectra, are analyzed using the data and tools available through the NASA Ames PAH IR Spectroscopic Database. The polycyclic aromatic hydrocarbon (PAH) emission is broken down into PAH charge and size subclass contributions using a database-fitting approach. The resulting charge breakdown results are combined with those derived using the traditional PAH band strength ratio approach, which interprets particular PAH band strength ratios as proxies for PAH charge. Here the 6.2/11.2 μm PAH band strength ratio is successfully calibrated against its database equivalent: the {n}PAH}+}/{n}PAH}0} ratio. In turn, this ratio is converted into the PAH ionization parameter, which relates it to the strength of the radiation field, gas temperature, and electron density. Population diagrams are used to derive the {{{H}}}2 density and temperature. The bifurcated plot of the 8.6 versus 11.2 μm PAH band strength for the northwest photo dissociation region in NGC 7023 is shown to be a robust diagnostic template for the {n}PAH}+}/{n}PAH}0} ratio in all three objects. Template spectra for the PAH charge and size subclasses are determined for each object and shown to favorably compare. Using the determined template spectra from NGC 7023 to fit the emission in all three objects yields, upon inspection of the Structure SIMilarity maps, satisfactory results. The choice of extinction curve proves to be critical. Concluding, the distinctly different astronomical environments of a reflection nebula, H II region, and planetary nebula are reflected in their PAH emission spectra.

‘Postage-stamp PIV’: small velocity fields at 400 kHz for turbulence spectra measurements

Science.gov (United States)

Beresh, Steven J.; Henfling, John F.; Spillers, Russell W.; Spitzer, Seth M.

2018-03-01

Time-resolved particle image velocimetry recently has been demonstrated in high-speed flows using a pulse-burst laser at repetition rates reaching 50 kHz. Turbulent behavior can be measured at still higher frequencies if the field of view is greatly reduced and lower laser pulse energy is accepted. Current technology allows image acquisition at 400 kHz for sequences exceeding 4000 frames but for an array of only 128  ×  120 pixels, giving the moniker of ‘postage-stamp PIV’. The technique has been tested far downstream of a supersonic jet exhausting into a transonic crossflow. Two-component measurements appear valid until 120 kHz, at which point a noise floor emerges whose magnitude is dependent on the reduction of peak locking. Stereoscopic measurement offers three-component data for turbulent kinetic energy spectra, but exhibits a reduced signal bandwidth and higher noise in the out-of-plane component due to the oblique camera images. The resulting spectra reveal two regions exhibiting power-law dependence describing the turbulent decay. The frequency response of the present measurement configuration exceeds nearly all previous velocimetry measurements in high speed flow.

Foliar Reflectance and Fluorescence Responses for Corn and Soybean Plants Under Nitrogen Stress

Science.gov (United States)

Middleton, E. M.; Campbell, P. K. Entcheva; Corp, L. A.; Butcher, L. M.; McMurtrey, J. E.

2003-01-01

We are investigating the use of spectral indices derived from actively induced fluorescence spectra and passive optical spectra. We examined the influence of photosynthetic pigment, carbon (C) and nitrogen (N) content on the spectral fluorescence and passive optical property characteristics of mature, upper leaves from plants provided different N fertilizer application rates: 20%, 50%, 100% and 150% of recommended N levels. A suite of optical, fluorescence, and biophysical measurements were collected on leaves from field grown corn (Zea mays L.) and soybean plants (Glycine max L.) grown in pots (greenhouse + ambient sunlight. Steady state laser-induced fluorescence emission spectra (5 nm resolution) were obtained from adaxial and abaxial surfaces resulting from excitation at single wavelengths (280, 380 or 360, and 532 nm). For emission spectra produced by each of these excitation wavelengths, ratios of emission peaks were calculated, including the red far-red chlorophyll fluorescence (ChlF) ratio (F685/F740) and the far-red/green (F740/F525) ratio. High resolution (treatment groups was possible with specific fluorescence band ratios (e.g., F740/F525 obtained with 380 nm excitation). Higher ChlF and blue-green emissions were measured from the abaxial leaf surfaces. Abaxial surfaces also produced higher reflectances, in general, in the 400-800 nm spectrum.

Plasmonic reflectance anisotropy spectroscopy of metal nanoparticles on a semiconductor surface

Science.gov (United States)

Kosobukin, V. A.; Korotchenkov, A. V.

2016-12-01

A theory of plasmonic differential anisotropic reflection of light from nanoparticles located near the interface between media is developed. The model of a monolayer consisting of identical ellipsoidal metal particles occupying sites of a rectangular lattice is investigated. Effective plasmonic polarizabilities of nanoparticles in the layer are calculated self-consistently using the Green's function technique in the quasipoint dipole approximation. The local-field effect caused by anisotropic dipole plasmons of particles in the layer and their image dipoles is taken into account. The lately observed resonant reflectance anisotropy spectra of indium nanoclusters on InAs surface are explained by the difference between frequencies of plasmons with the orthogonal polarizations in the surface plane. The difference between the plasmon frequencies is attributed to anisotropy of the particles shape or/and the layer structure; the signs of frequency difference for the two types of anisotropy being different.

Theoretical studies on core-level spectra of solids

International Nuclear Information System (INIS)

Kotani, Akio

1995-01-01

I present a review on theoretical studies of core-level spectra (CLS) in solids. In CLS, the dynamical response of outer electrons to a core hole is reflected through the screening of core hole potential. Impurity Anderson model (IAM) or cluster model is successfully applied to the analysis of X-ray photoemission spectra (XPS) and X-ray absorption spectra (XAS) in f and d electron systems, where the f and d electron states are hybridized with the other valence or conduction electron states. The effect of the core-hole potential in the final state of XPS and XAS plays an important role, as well as the solid state hybridization and intra-atomic multiplet coupling effects. As typical examples, the calculated results for XPS of rare-earth compounds and transition metal compounds are shown, and some discussions are given. As a subject of remarkable progress with high brightness synchrotron radiation sources, I discuss some theoretical aspects of X-ray emission spectra (XES) and their resonant enhancement at the X-ray absorption threshold. Some experimental data and their theoretical analysis are also given. (author)

Influence of hurricane wind field in the structure of directional wave spectra.

Science.gov (United States)

Esquivel-Trava, Bernardo; García-Nava, Hector; Osuna, Pedro; Ocampo-Torres, Francisco J.

2017-04-01

Three numerical experiments using the spectral wave prediction model SWAN were carried out to gain insight into the mechanism that controls the directional and frequency distributions of hurricane wave energy. One particular objective is to evaluate the effect of the translation speed of the hurricane and the presence of concentric eye walls, on both the wave growth process and the shape of the directional wave spectrum. The HRD wind field of Hurricane Dean on August 20 at 7:30 was propagated at two different velocities (5 and 10 m/s). An idealized concentric eye wall (a Gaussian function that evolve in time along a path in the form of an Archimedean spiral) was imposed to the wind field. The white-capping formulation of Westhuysen et al. (2007) was selected. The wave model represents fairly well the directionality of the energy and the shape of the directional spectra in the hurricane domain. The model results indicate that the forward movement of the storm influences the development of the waves, consistent with field observations. Additionally the same experiments were carried out using the Wave Watch III model with the source terms formulation proposed by Ardhuin et al., 2010, with the aim of making comparisons between the physical processes that represent each formulation, and the latest results will be addressed. References Ardhuin, F., Rogers, E., Babanin, A. V., Filipot, J.-F., Magne, R., Roland, A., van der Westhuysen, A., et al. (2010). Semiempirical Dissipation Source Functions for Ocean Waves. Part I: Definition, Calibration, and Validation. Journal of Physical Oceanography, 40(9), 1917-1941. doi:10.1175/2010JPO4324.1 Van der Westhuysen, A. J., Zijlema, M., & Battjes, J. A. (2007). Nonlinear saturation-based whitecapping dissipation in SWAN for deep and shallow water. Coast. Eng., 54(2), 151-170. doi:10.1016/j.coastaleng.2006.08.006

Retrieval of optical properties of skin from measurement and modeling the diffuse reflectance

Science.gov (United States)

Douven, Lucien F. A.; Lucassen, Gerald W.

2000-06-01

We present results on the retrieval of skin optical properties obtained by fitting of measurements of the diffuse reflectance of human skin. Reflectance spectra are simulated using an analytical model based on the diffusion approximation. This model is implemented in a simplex fit routine. The skin optical model used consists of five layers representing epidermis, capillary blood plexus, dermis, deep blood plexus and hypodermis. The optical properties of each layer are assumed homogeneously distributed. The main optical absorbers included are melanin in epidermis and blood. The experimental setup consists of a HP photospectrometer equipped with a remote fiber head. Total reflectance spectra were measured in the 400 - 820 nm wavelength range on the volar underarm of 19 volunteers under various conditions influencing the blood content and oxygenation degree. Changes in the reflectance spectra were observed. Using the fit routine changes in blood content in the capillary blood plexus and in the deep blood plexus could be quantified. These showed different influences on the total reflectance. The method can be helpful to quantitatively assess changes in skin color appearance such as occurs in the treatment of port wine stains, blanching, skin irritation and tanning.

Reflections about the capitalism influences in the field of Library Science and Information science

Directory of Open Access Journals (Sweden)

Giovana Deliberali Maimone

2008-01-01

Full Text Available Introduces the relation among the different stages of the teaching of Library Science and Information Science in Brazil and the capitalism. To demonstrate these relations, the capitalist way of production and its respective stages are shown, contextualizing its influence over the area and study of the information professional. The relations between Capitalism and Library Science teach allows us to develop reflections regarding the models and contents of the courses offered in this field. Such an understanding of the articulation way of the curricular parameters reflects the conceptions and values in a temporal period. At last, terminological questions are made to exemplify the comparisons mentioned.

Conductance spectra of asymmetric ferromagnet/ferromagnet/ferromagnet junctions

Energy Technology Data Exchange (ETDEWEB)

Pasanai, K., E-mail: krisakronmsu@gmail.com

2017-01-15

A theory of tunneling spectroscopy of ferromagnet/ferromagnet/ferromagnet junctions was studied. We applied a delta-functional approximation for the interface scattering properties under a one-dimensional system of a free electron approach. The reflection and transmission probabilities were calculated in the ballistic regime, and the conductance spectra were then calculated using the Landauer formulation. The magnetization directions were set to be either parallel (P) or anti-parallel (AP) alignments, for comparison. We found that the conductance spectra was suppressed when increasing the interfacial scattering at the interfaces. Moreover, the electron could exhibit direct transmission when the thickness was rather thin. Thus, there was no oscillation in this case. However, in the case of a thick layer the conductance spectra oscillated, and this oscillation was most prominent when the middle layer thickness increased. In the case of direct transmission, the conductance spectra of P and AP systems were definitely suppressed with increased exchange energy of the middle ferromagnet. This also refers to an increase in the magnetoresistance of the junction. In the case of oscillatory behavior, the positions of the resonance peaks were changed as the exchange energy was changed. - Highlights: • The conductance spectra of a FM/FM/FM junction were calculated. • The conductance spectra were suppressed by the exchange energy. • The exchange energy and the potential strength play similar roles in the junctions.

Conductance spectra of asymmetric ferromagnet/ferromagnet/ferromagnet junctions

International Nuclear Information System (INIS)

Pasanai, K.

2017-01-01

A theory of tunneling spectroscopy of ferromagnet/ferromagnet/ferromagnet junctions was studied. We applied a delta-functional approximation for the interface scattering properties under a one-dimensional system of a free electron approach. The reflection and transmission probabilities were calculated in the ballistic regime, and the conductance spectra were then calculated using the Landauer formulation. The magnetization directions were set to be either parallel (P) or anti-parallel (AP) alignments, for comparison. We found that the conductance spectra was suppressed when increasing the interfacial scattering at the interfaces. Moreover, the electron could exhibit direct transmission when the thickness was rather thin. Thus, there was no oscillation in this case. However, in the case of a thick layer the conductance spectra oscillated, and this oscillation was most prominent when the middle layer thickness increased. In the case of direct transmission, the conductance spectra of P and AP systems were definitely suppressed with increased exchange energy of the middle ferromagnet. This also refers to an increase in the magnetoresistance of the junction. In the case of oscillatory behavior, the positions of the resonance peaks were changed as the exchange energy was changed. - Highlights: • The conductance spectra of a FM/FM/FM junction were calculated. • The conductance spectra were suppressed by the exchange energy. • The exchange energy and the potential strength play similar roles in the junctions.

Forensic applications of microscopical infrared internal reflection spectroscopy

Science.gov (United States)

Tungol, Mary W.; Bartick, Edward G.; Reffner, John A.

1994-01-01

Applications of microscopical infrared internal reflection spectroscopy in forensic science are discussed. Internal reflection spectra of single fibers, hairs, paint chips, vehicle rubber bumpers, photocopy toners, carbon copies, writing ink on paper, lipstick on tissue, black electrical tape, and other types of forensic evidence have been obtained. The technique is convenient, non-destructive, and may permit smeared materials to be analyzed in situ.

Calculations of oscillation spectra of disordered interstitial solid solutions of vanadium-oxygen system

International Nuclear Information System (INIS)

Danilkin, S.A.

1978-01-01

The frequency spectra calculation of disordered solid interstitial solutions of a vanadium-oxygen system for oxygen concentration of 5.9% and 15.8% (V 16 O and V 16 O 3 ) is carried out. The axially-symmetric model of crystal lattice dinamics with consideration of vanadium-oxygen and vanadium-vanadium interactions up to the second coordination sphere is used. On the whole, the obtained spectra are in qualitative agreement with experiment and reflect correctly all the changes in frequency spectra of pure vanadium on doping with oxygen

Finite temperature magnon spectra in yttrium iron garnet from a mean field approach in a tight-binding model

Science.gov (United States)

Shen, Ka

2018-04-01

We study magnon spectra at finite temperature in yttrium iron garnet using a tight-binding model with nearest-neighbor exchange interaction. The spin reduction due to thermal magnon excitation is taken into account via the mean field approximation to the local spin and is found to be different at two sets of iron atoms. The resulting temperature dependence of the spin wave gap shows good agreement with experiment. We find that only two magnon modes are relevant to the ferromagnetic resonance.

Probing spin-polarized edge state superconductivity by Andreev reflection in in-plane magnetic fields

Energy Technology Data Exchange (ETDEWEB)

Reinthaler, Rolf W.; Tkachov, Grigory; Hankiewicz, Ewelina M. [Faculty of Physics and Astrophysics, University of Wuerzburg, Wuerzburg (Germany)

2015-07-01

Finding signatures of unconventional superconductivity in Quantum Spin Hall systems is one of the challenges of solid state physics. Here we induce superconductivity in a 3D topological insulator thin film to cause the formation of helical edge states, which are protected against backscattering even in finite magnetic fields. Above a critical in-plane magnetic field, which is much smaller than the critical field of typical superconductors, the quasi-particle gap closes, giving rise to energy-dependent spin polarization. In this regime the spin-polarized edge state superconductivity can be detected by Andreev reflection. We propose measurement setups to experimentally observe the spin-dependent excess current and dI/dV characteristics.

The structure of BPS spectra

Science.gov (United States)

Longhi, Pietro

In this thesis we develop and apply novel techniques for analyzing BPS spectra of supersymmetric quantum field theories of class S. By a combination of wall-crossing, spectral networks and quiver methods we explore the BPS spectra of higher rank four-dimensional N = 2 super Yang-Mills, uncovering surprising new phenomena. Focusing on the SU(3) case, we prove the existence of wild BPS spectra in field theory, featuring BPS states of higher spin whose degeneracies grow exponentially with the energy. The occurrence of wild BPS states is surprising because it appears to be in tension with physical expectations on the behavior of the entropy as a function of the energy scale. The solution to this puzzle comes from realizing that the size of wild BPS states grows rapidly with their mass, and carefully analyzing the volume-dependence of the entropy of BPS states. We also find some interesting structures underlying wild BPS spectra, such as a Regge-like relation between the maximal spin of a BPS multiplet and the square of its mass, and the existence of a universal asymptotic distribution of spin-j irreps within a multiplet of given charge. We also extend the spectral networks construction by introducing a refinement in the topological classification of 2d-4d BPS states, and identifying their spin with a topological invariant known as the "writhe of soliton paths". A careful analysis of the 2d-4d wall-crossing behavior of this refined data reveals that it is described by motivic Kontsevich-Soibelman transformations, controlled by the Protected Spin Character, a protected deformation of the BPS index encoding the spin of BPS states. Our construction opens the way for the systematic study of refined BPS spectra in class S theories. We apply it to several examples, including ones featuring wild BPS spectra, where we find an interesting relation between spectral networks and certain functional equations. For class S theories of A 1 type, we derive an alternative technique for

Link between optical spectra, crystal-field parameters, and local environments of Eu3+ ions in Eu2O3-doped sodium disilicate glass

International Nuclear Information System (INIS)

Qin, T.; Mountjoy, G.; Afify, N. D.; Reid, M. F.; Yeung, Y. Y.; Speghini, A.; Bettinelli, M.

2011-01-01

Rare-earth-doped glasses are key materials for optical technology due to the luminescent properties of 4f n ions. The crystal-field model describes the effect of local environment on transitions between 4f electrons. We present a detailed modeling study of the optical spectra of sodium disilicate glass, 33Na 2 O·67SiO 2 , doped with 0.2% and 1.0 mol%Eu 2 O 3 . This study uses very large molecular dynamics models with up to 100 Eu 3+ ions, the superposition model for covalent and overlap effects on crystal-field parameters, and realistic values for homogeneous linewidth broadening. The simulated spectra are in reasonable agreement with experiment. The trends in 7 F J energy levels across different Eu 3+ ion sites have been examined and a very detailed analysis is presented that looks at how features of the spectra are related to features of the local environment of Eu 3+ ions. Increasing the crystal-field strength S total causes the 7 F 0 energy level to decrease and causes the splitting of 7 F J manifolds to increase, and this is due to increasing mixing of 4f wave functions. To a reasonable approximation the crystal-field strength components S k depend on angular positions of ligands independently of distances to ligands. The former are seen to be more significant in determining S k , which are closely related to the rotationally invariant bond-orientational order parameters Q k . The values of S 2 are approximately linear in Q 2 , and the values of Q 2 are higher for fivefold than sixfold coordinated rare-earth ions. These results can be of importance for efforts to enhance the local environment of rare-earth ions in oxide glasses for optical applications.

Vibrational spectra of double oxides of calcium and scandium

International Nuclear Information System (INIS)

Porotnikov, N.V.; Kondratov, O.I.; Petrov, K.I.; Olikov, I.I.

1981-01-01

The vibrational spectra of calcium and scandium double oxides 40 CaSc 2 O 4 and 44 CaSc 2 O 4 in the range of 30-1000 cm -1 are studied. In the approximation of the polymer chains of the method of valent-force field the calculation of the theoretical vibrational spectrum of isotope-substituted compounds is made, the attribution of the experimental spectra is suggested, the frequency branches of the vibrations of periodic chains are built, the force field of crystals is evaluated [ru

Analysis of Specular Reflections Off Geostationary Satellites

Science.gov (United States)

Jolley, A.

2016-09-01

Many photometric studies of artificial satellites have attempted to define procedures that minimise the size of datasets required to infer information about satellites. However, it is unclear whether deliberately limiting the size of datasets significantly reduces the potential for information to be derived from them. In 2013 an experiment was conducted using a 14 inch Celestron CG-14 telescope to gain multiple night-long, high temporal resolution datasets of six geostationary satellites [1]. This experiment produced evidence of complex variations in the spectral energy distribution (SED) of reflections off satellite surface materials, particularly during specular reflections. Importantly, specific features relating to the SED variations could only be detected with high temporal resolution data. An update is provided regarding the nature of SED and colour variations during specular reflections, including how some of the variables involved contribute to these variations. Results show that care must be taken when comparing observed spectra to a spectral library for the purpose of material identification; a spectral library that uses wavelength as the only variable will be unable to capture changes that occur to a material's reflected spectra with changing illumination and observation geometry. Conversely, colour variations with changing illumination and observation geometry might provide an alternative means of determining material types.

Naturally enhanced ion-acoustic spectra and their interpretation

DEFF Research Database (Denmark)

Sedgemore-Schulthess, K.J.F.; St. Maurice, J.P.

2001-01-01

acceleration, wave-particle and wave-wave interactions in the ionosphere, and their association with magnetospheric processes. There is now a substantial body of literature documenting observations of enhanced ion-acoustic spectra, but there remains controversy over generation mechanisms. We present a review...... years there has been much interest in naturally occurring (as opposed to artificially stimulated) enhanced ion-acoustic spectra seen in the auroral zone and cusp/cleft region. A study of the plasma instability processes that lead to such spectra will help us to better understand auroral particle...... of literature documenting observations of naturally enhanced ion-acoustic spectra, observed mainly along the geomagnetic field direction, along with a discussion of the theories put forward to explain such phenomena....

Chemical state analysis of heat-treated 6, 13-bis(triisopropylsilylethynyl) pentacene investigated by XPS valence band spectra, XANES spectra and first-principles calculation

International Nuclear Information System (INIS)

Muro, Maiko; Natsume, Yutaka; Kikuma, Jun; Setoyama, Hiroyuki

2014-01-01

X-ray photoelectron spectroscopy (XPS) valence band spectra reflect the chemical bonding states. To take this advantage, we tried to interpret experimental spectra by the occupied density of states (DOS) based on first principles calculation. In this work, we discussed XPS and X-ray Absorption Near Edge Structure (XANES) spectra of 6, 13-bis(triisopropylsilylethynyl) pentacene (TIPS-Pen), which is well known as an organic semiconductor. We studied chemical structure change of TIPS-Pen caused by heat-treatment at 300degC under nitrogen and under the air. It has been suggested that the structural change of pentacene skeleton by Diels-Alder type reaction occurs in both cases. In addition, the sample heat-treated under the air showed desorption of the isopropyl group and increase of oxygen concentration. (author)

Analytic and numerical calculations of quantum synchrotron spectra from relativistic electron distributions

International Nuclear Information System (INIS)

Brainerd, J.J.; Petrosian, V.

1987-01-01

Calculations are performed numerically and analytically of synchrotron spectra for thermal and power-law electron distributions using the single-particle synchrotron power spectrum derived from quantum electrodynamics. It is found that the photon energy at which quantum effects appear is proportional to temperature and independent of field strength for thermal spectra; quantum effects introduce an exponential roll-off away from the classical spectra. For power law spectra, the photon energy at which quantum effects appear is inversely proportional to the magnetic field strength; quantum effects produce a steeper power law than is found classically. The results are compared with spectra derived from the classical power spectrum with an energy cutoff ensuring conservation of energy. It is found that an energy cutoff is generally an inadequate approximation of quantum effects for low photon energies and for thermal spectra, but gives reasonable results for high-energy emission from power-law electron distributions. 17 references

Field Spectroscopy in the VNIR-SWIR Region to Discriminate between Mediterranean Native Plants and Exotic-Invasive Shrubs Based on Leaf Tannin Content

Directory of Open Access Journals (Sweden)

Jan Rudolf Karl Lehmann

2015-01-01

Full Text Available The invasive shrub, Acacia longifolia, native to southeastern Australia, has a negative impact on vegetation and ecosystem functioning in Portuguese dune ecosystems. In order to spectrally discriminate A. longifolia from other non-native and native species, we developed a classification model based on leaf reflectance spectra (350–2500 nm and condensed leaf tannin content. High variation of leaf tannin content is common for Mediterranean shrub and tree species, in particular between N-fixing and non-N-fixing species, as well as within the genus, Acacia. However, variation in leaf tannin content has not been studied in coastal dune ecosystems in southwest Portugal. We hypothesized that condensed tannin concentration varies significantly across species, further allowing for distinguishing invasive, nitrogen-fixing A. longifolia from other vegetation based on leaf spectral reflectance data. Spectral field measurements were carried out using an ASD FieldSpec FR spectroradiometer attached to an ASD leaf clip in order to collect 750 in situ leaf reflectance spectra of seven frequent plant species at three study sites in southwest Portugal. We applied partial least squares (PLS regression to predict the obtained leaf reflectance spectra of A. longifolia individuals to their corresponding tannin concentration. A. longifolia had the lowest tannin concentration of all investigated species. Four wavelength regions (675–710 nm, 1060–1170 nm, 1360–1450 nm and 1630–1740 nm were identified as being highly correlated with tannin concentration. A spectra-based classification model of the different plant species was calculated using a principal component analysis-linear discriminant analysis (PCA-LDA. The best prediction of A. longifolia was achieved by using wavelength regions between 1360–1450 nm and 1630–1740 nm, resulting in a user’s accuracy of 98.9%. In comparison, selecting the entire wavelength range, the best user accuracy only reached 86

Field evaluation of reflective insulation in south east Asia

Science.gov (United States)

Teh, Khar San; Yarbrough, David W.; Lim, Chin Haw; Salleh, Elias

2017-12-01

The objective of this research was to obtain thermal performance data for reflective insulations in a South East Asia environment. Thermal resistance data (RSI, m2 ṡ K/W) for reflective insulations are well established from 1-D steady-state tests, but thermal data for reflective insulation in structures like those found in South East Asia are scarce. Data for reflective insulations in South East Asia will add to the worldwide database for this type of energy-conserving material. RSI were obtained from heat flux and temperature data of three identical structures in the same location. One unit did not have insulation above the ceiling, while the second and third units were insulated with reflective insulation with emittance less than 0.05. RSI for the uninsulated test unit varied from 0.37 to 0.40 m2 ṡ K/W. RSI for a single-sheet reflective insulation (woven foil) varied from 2.15 to 2.26 m2 ṡ K/W, while bubble-foil insulation varied from 2.69 to 3.09 m2 ṡ K/W. The range of RSI values resulted from differences in the spacing between the reflective insulation and the roof. In addition, the reflective insulation below the roof lowered attic temperatures by as much as 9.7° C. Reductions in ceiling heat flux of 80 to 90% relative to the uninsulated structure, due to the reflective insulation, were observed.

Autonomous Acqisition of Science Grade Spectra From UAS's

Science.gov (United States)

Mandl, D.; Campbell, P. K. E.; Sohlberg, R. A.; Ong, L.; Cappelaere, P. G.

2017-12-01

We assembled a payload box which contains a QE Pro and a Flame hyperspectral instruments. The payload was mounted on a DJI Matrice 600 drone. The total weight of the drone and the payload was 38 lbs. It was flown over a United States Department of Agricultural (USDA) research field where corn and soybeans were grown. The fields were subdivided into areas that had a variety of treatments such as low nitrogen and high nitrogen. The research is centered on correlating the treatments with the year-end crop yields. Our effort was to monitor spectral data to recognize photosynthetic activity via proxies such as solar induced fluorescence (SIF). To detect SIF requires optimized spectra which is normalized into reflectance. We perform the optimization routine onboard. The intent is to demonstrate a viable measurement campaign that would enable a researcher to measure the fields diurnally over a growing season. What we found out is that there was more complexity to trying to make this happen then we originally thought. For one thing, we had limited battery life, limited payload capacity and sometimes the cloud cover did not cooperate. So the question was how to intelligently apply the resources using some onboard processing and software. Our long term vision is to have multiple drones act as an intelligent cluster and self-manage their own deployment at multiple locations and multiple altitudes, auto-adjustments and intelligent management of errors. This presentation will go over lessons learned, achievements and future directions.

Optical Reflectance and Fluorescence for Detecting Nitrogen Needs in Zea mays L.

Science.gov (United States)

McMurtrey, J. E.; Middleton, E. M.; Corp. L. A.; Campbell, P. K. Entcheva; Butcher, L. M.; Daughtry, C. S. T.

2003-01-01

Nitrogen (N) status in field grown corn (Zea mays L.) was assessed using spectral techniques. Passive reflectance remote sensing and, both passive and active fluorescence sensing methods were investigated. Reflectance and fluorescence methods are reported to detect changes in the primary plant pigments (chlorophylls a and b; carotenoids) in higher plant species. As a general rule, foliar chlorophyll a (Chl a) and chlorophyll b (Chl b) usually exist in approx.3:l ratio. In plants under stress, Chl b content is affected before Chl a reductions occur. For reflectance, a version of the chlorophyll absorption in reflectance index (CARI) method was tested with narrow bands from the Airborne Imaging Spectroradiometer for Applications (ASIA). CARI minimizes the effects of soil background on the signal from green canopies. A modified CARI (MCARI) was used to track total Chl a levels in the red dip of the spectrum from the corn canopy. A second MCARI was used to track the auxiliary plant pigments (Chl b and the carotenoids) in the yellow/orange/red edge part of the reflectance spectrum. The difference between these two MCARI indices detected variations in N levels across the field plot canopies using ASIA data. At the leaf level, ratios of fluorescence emissions in the blue, green, red and far-red wavelengths sensed responses that were associated with the plant pigments, and were indicative of energy transfer in the photosynthetic process. N stressed corn stands could be distinguish from those with optimally applied N with fluorescence emission spectra obtained from individual corn leaves. Both reflectance and fluorescence methods are sensitive in detecting corn N needs and may be especially powerful in monitoring crop conditions if both types of information can be combined.

Active Multispectral Band Selection and Reflectance Measurement System

National Research Council Canada - National Science Library

Rennich, Bradley

1999-01-01

.... To aid in the selection of these bands, a novel multispectral band selection technique is presented based on the cross-correlation of the material class reflectance spectra over a wavelength range of 1 - 5 microns...

Effect of Shear Applied During a Pharmaceutical Process on Near Infrared Spectra.

Science.gov (United States)

Hernández, Eduardo; Pawar, Pallavi; Rodriguez, Sandra; Lysenko, Sergiy; Muzzio, Fernando J; Romañach, Rodolfo J

2016-03-01

This study describes changes observed in the near-infrared (NIR) diffuse reflectance (DR) spectra of pharmaceutical tablets after these tablets were subjected to different levels of strain (exposure to shear) during the mixing process. Powder shearing is important in the mixing of powders that are cohesive. Shear stress is created in a system by moving one surface over another causing displacements in the direction of the moving surface and is part of the mixing dynamics of particulates in many industries including the pharmaceutical industry. In continuous mixing, shear strain is developed within the process when powder particles are in constant movement and can affect the quality attributes of the final product such as dissolution. These changes in the NIR spectra could affect results obtained from NIR calibration models. The aim of the study was to understand changes in the NIR diffuse reflectance spectra that can be associated with different levels of strain developed during blend shearing of laboratory samples. Shear was applied using a Couette cell and tablets were produced using a tablet press emulator. Tablets with different shear levels were measured using NIR spectroscopy in the diffuse reflectance mode. The NIR spectra were baseline corrected to maintain the scattering effect associated with the physical properties of the tablet surface. Principal component analysis was used to establish the principal sources of variation within the samples. The angular dependence of elastic light scattering shows that the shear treatment reduces the size of particles and produces their uniform and highly isotropic distribution. Tablet compaction further reduces the diffuse component of scattering due to realignment of particles. © The Author(s) 2016.

Reflections on the Evolution of Higher Education as a Field of Study in Canada

Science.gov (United States)

Jones, Glen A.

2012-01-01

This paper provides a reflective analysis of the evolution of higher education as a field of scholarship in Canada. The first professors of higher education in Canada were appointed in the mid-1960s and, by the early-1970s, a small higher-education research community had emerged, with the creation of a national association and a scholarly journal.…

Conductance spectra of asymmetric ferromagnet/ferromagnet/ferromagnet junctions

Science.gov (United States)

Pasanai, K.

2017-01-01

A theory of tunneling spectroscopy of ferromagnet/ferromagnet/ferromagnet junctions was studied. We applied a delta-functional approximation for the interface scattering properties under a one-dimensional system of a free electron approach. The reflection and transmission probabilities were calculated in the ballistic regime, and the conductance spectra were then calculated using the Landauer formulation. The magnetization directions were set to be either parallel (P) or anti-parallel (AP) alignments, for comparison. We found that the conductance spectra was suppressed when increasing the interfacial scattering at the interfaces. Moreover, the electron could exhibit direct transmission when the thickness was rather thin. Thus, there was no oscillation in this case. However, in the case of a thick layer the conductance spectra oscillated, and this oscillation was most prominent when the middle layer thickness increased. In the case of direct transmission, the conductance spectra of P and AP systems were definitely suppressed with increased exchange energy of the middle ferromagnet. This also refers to an increase in the magnetoresistance of the junction. In the case of oscillatory behavior, the positions of the resonance peaks were changed as the exchange energy was changed.

Imprints of the Molecular Electronic Structure in the Photoelectron Spectra of Strong-Field Ionized Asymmetric Triatomic Model Molecules

Science.gov (United States)

Paul, Matthias; Yue, Lun; Gräfe, Stefanie

2018-06-01

We examine the circular dichroism in the angular distribution of photoelectrons of triatomic model systems ionized by strong-field ionization. Following our recent work on this effect [Paul, Yue, and Gräfe, J. Mod. Opt. 64, 1104 (2017), 10.1080/09500340.2017.1299883], we demonstrate how the symmetry and electronic structure of the system is imprinted into the photoelectron momentum distribution. We use classical trajectories to reveal the origin of the threefolded pattern in the photoelectron momentum distribution, and show how an asymmetric nuclear configuration of the triatomic system effects the photoelectron spectra.

On the origin of cyclotron lines in the spectra of X-ray pulsars

Directory of Open Access Journals (Sweden)

Mushtukov A. A.

2014-01-01

Full Text Available Cyclotron resonance scattering features are observed in the spectra of some X-ray pulsars and show significant changes in the line energy with the pulsar luminosity. In a case of bright sources, the line centroid energy is anti-correlated with the luminosity. Such a behaviour is often associated with the onset and growth of the accretion column, which is believed to be the origin of the observed emission and the cyclotron lines. However, this scenario inevitably implies large gradient of the magnetic field strength within the line-forming region, and it makes the formation of the observed line-like features problematic. Moreover, the observed variation of the cyclotron line energy is much smaller than could be anticipated for the corresponding luminosity changes. We argue that a more physically realistic situation is that the cyclotron line forms when the radiation emitted by the accretion column is reflected from the neutron star surface. The idea is based on the facts that a substantial part of column luminosity is intercepted by the neutron star surface and the reflected radiation should contain absorption features. The reflection model is developed and applied to explain the observed variations of the cyclotron line energy in a bright X-ray pulsar V 0332+53 over a wide range of luminosities.

Sulfur Hazes in Giant Exoplanet Atmospheres: Impacts on Reflected Light Spectra

Energy Technology Data Exchange (ETDEWEB)

Gao, Peter; Marley, Mark S.; Zahnle, Kevin [NASA Ames Research Center, Moffett Field, CA 94035 (United States); Robinson, Tyler D. [Department of Astronomy and Astrophysics, University of California, Santa Cruz, Santa Cruz, CA 95064 (United States); Lewis, Nikole K., E-mail: pgao@caltech.edu [Space Telescope Science Institute, Baltimore, MD 21218 (United States)

2017-03-01

Recent work has shown that sulfur hazes may arise in the atmospheres of some giant exoplanets, due to the photolysis of H{sub 2}S. We investigate the impact such a haze would have on an exoplanet’s geometric albedo spectrum and how it may affect the direct imaging results of the Wide Field Infrared Survey Telescope ( WFIRST ), a planned NASA space telescope. For temperate (250 K <  T {sub eq} < 700 K) Jupiter-mass planets, photochemical destruction of H{sub 2}S results in the production of ∼1 ppmv of S{sub 8} between 100 and 0.1 mbar, which, if cool enough, will condense to form a haze. Nominal haze masses are found to drastically alter a planet’s geometric albedo spectrum: whereas a clear atmosphere is dark at wavelengths between 0.5 and 1 μ m, due to molecular absorption, the addition of a sulfur haze boosts the albedo there to ∼0.7, due to scattering. Strong absorption by the haze shortward of 0.4 μ m results in albedos <0.1, in contrast to the high albedos produced by Rayleigh scattering in a clear atmosphere. As a result, the color of the planet shifts from blue to orange. The existence of a sulfur haze masks the molecular signatures of methane and water, thereby complicating the characterization of atmospheric composition. Detection of such a haze by WFIRST is possible, though discriminating between a sulfur haze and any other highly reflective, high-altitude scatterer will require observations shortward of 0.4 μ m, which is currently beyond WFIRST ’s design.

Double photoionisation spectra of molecules

CERN Document Server

Eland, John

2017-01-01

This book contains spectra of the doubly charged positive ions (dications) of some 75 molecules, including the major constituents of terrestrial and planetary atmospheres and prototypes of major chemical groups. It is intended to be a new resource for research in all areas of molecular spectroscopy involving high energy environments, both terrestrial and extra-terrestrial. All the spectra have been produced by photoionisation using laboratory lamps or synchrotron radiation and have been measured using the magnetic bottle time-of-flight technique by coincidence detection of correlated electron pairs. Full references to published work on the same species are given, though for several molecules these are the first published spectra. Double ionisation energies are listed and discussed in relation to the molecular electronic structure of the molecules. A full introduction to the field of molecular double ionisation is included and the mechanisms by which double photoionisation can occur are examined in detail. A p...

Resonant Raman and FTIR spectra of carbon doped GaN

Science.gov (United States)

Ito, S.; Kobayashi, H.; Araki, K.; Suzuki, K.; Sawaki, N.; Yamashita, K.; Honda, Y.; Amano, H.

2015-03-01

Intentionally carbon (C) doped (0 0 0 1)GaN was grown using C2H2 on a sapphire substrate by metalorganic vapor phase epitaxy. Optical spectra of the heavily doped samples were investigated at room temperature. In Raman spectra excited by the 325 nm line of a He-Cd laser, multiple LO phonon scattering signals up to 7th order were observed, and the A1(LO) phonon energy was determined to be 737.5 cm-1 (91.45 meV). In infrared reflectance spectra, on the other hand, a local vibration mode was found at 777.5 cm-1, which is attributed to a Ga-C bond in the GaN matrix suggesting that the C sits on an N site (CN). In spite of the strong suggestion of CN, the samples did not show p-type conduction. Possible origin of the carrier compensation is discussed in relation to the enhancement of defect related yellow luminescence in the photoluminescence spectra.

Decomposing the permeability spectra of nanocrystalline finemet core

Science.gov (United States)

Varga, Lajos K.; Kovac, Jozef

2018-04-01

In this paper we present a theoretical and experimental investigation on the magnetization contributions to permeability spectra of normal annealed Finemet core with round type hysteresis curve. Real and imaginary parts of the permeability were determined as a function of exciting magnetic field (HAC) between 40 Hz -110 MHz using an Agilent 4294A type Precision Impedance Analyzer. The amplitude of the exciting field was below and around the coercive field of the sample. The spectra were decomposed using the Levenberg-Marquardt algorithm running under Origin 9 software in four contributions: i) eddy current; ii) Debye relaxation of magnetization rotation, iii) Debye relaxation of damped domain wall motion and iv) resonant type DW motion. For small exciting amplitudes the first two components dominate. The last two contributions connected to the DW appear for relative large HAC only, around the coercive force. All the contributions will be discussed in detail accentuating the role of eddy current that is not negligible even for the smallest applied exciting field.

The physical basis for estimating wave-energy spectra with the radar ocean-wave spectrometer

Science.gov (United States)

Jackson, Frederick C.

1987-01-01

The derivation of the reflectivity modulation spectrum of the sea surface for near-nadir-viewing microwave radars using geometrical optics is described. The equations required for the derivation are presented. The derived reflectivity modulation spectrum provides data on the physical basis of the radar ocean-wave spectrometer measurements of ocean-wave directional spectra.

Statistical Analysis of the Reflectivity of a Heliostats Field. Application to the CR S Heliostats Field of the Plataforma Solar de Almeria; Analisis Estadistico de la Reflectividad de un Campo de Heliostatos CRS de la Plataforma Solar de Almeria

Energy Technology Data Exchange (ETDEWEB)

Fernandez Reche, J.

2003-07-01

Reflectivity measuring in a heliostats field of a solar central tower is a task that should performed periodically. The reflectivity of the field is a value that should be known to evaluate the system, moreover it plays an important role in several simulation codes which are useful for the daily operation of the system. When the size of the heliostats field increases (terns of heliostats) it is necessary to find a method, due to operability reasons, that allows us to offer a reflectivity value measuring only in fe facets guaranteeing that the statistical error of this value is within a reasonable range. In this report a statistical analysis of the reflectivity in a heliostats field is presented. The analysis was particularized for the CRS heliostats field of the Plataforma Solar de Almeria. The results of the present study allow us to guarantee a reflectivity value of the heliostats field with a statistical error below 1% measuring only 12 facets (instead of the 1116 facets that compose the field). (Author) 6 refs.

Sub-wavelength imaging by depolarization in a reflection near-field optical microscope using an uncoated fiber probe

DEFF Research Database (Denmark)

Madsen, Steen; Bozhevolnyi, Sergey I.; Hvam, Jørn Märcher

1998-01-01

We present a reflection scanning near-field optical microscope utilizing counter-directional light propagation in an uncoated fiber probe, cross-polarized detection and shear-force feedback. Topographical and near-field optical imaging with a scanning speed of up to 10 mu m/s and a lateral...... resolution better than 40 nm are demonstrated with a latex projection test sample. Determination of the optical resolution as well as correlation between topographical and near-field optical images are discussed. (C) 1998 Elsevier Science B.V....

Functional visual fields: a cross-sectional UK study to determine which visual field paradigms best reflect difficulty with mobility function.

Science.gov (United States)

Subhi, Hikmat; Latham, Keziah; Myint, Joy; Crossland, Michael

2017-11-20

To develop an appropriate method of assessing visual field (VF) loss which reflects its functional consequences, this study aims to determine which method(s) of assessing VF best reflect mobility difficulty. This cross-sectional observational study took place within a single primary care setting. Participants attended a single session at a University Eye Clinic, Cambridge, UK, with data collected by a single researcher (HS), a qualified optometrist. 50 adult participants with peripheral field impairment were recruited for this study. Individuals with conditions not primarily affecting peripheral visual function, such as macular degeneration, were excluded from the study. Participants undertook three custom and one standard binocular VF tests assessing VF to 60°, and also integrated monocular threshold 24-2 visual fields (IVF). Primary VF outcomes were average mean threshold, percentage of stimuli seen and VF area. VF outcomes were compared with self-reported mobility function assessed with the Independent Mobility Questionnaire, and time taken and patient acceptability were also considered. Receiver operating characteristic (ROC) curves determined which tests best predicted difficulty with mobility tasks. Greater VF loss was associated with greater self-reported mobility difficulty with all field paradigms (R 2 0.38-0.48, all Pmobility tasks in ROC analysis. Mean duration of the tests ranged from 1 min 26 s (±9 s) for kinetic assessment to 9 min 23 s (±24 s) for IVF. The binocular VF tests extending to 60° eccentricity all relate similarly to self-reported mobility function, and slightly better than integrated monocular VFs. A kinetic assessment of VF area is quicker than and as effective at predicting mobility function as static threshold assessment. © Article author(s) (or their employer(s) unless otherwise stated in the text of the article) 2017. All rights reserved. No commercial use is permitted unless otherwise expressly granted.

Construction of imaging system for wide-field-range ESR spectra using localized microwave field and its case study of crystal orientation in suspension of copper sulfate pentahydrate (CuSO4.5H2O)

International Nuclear Information System (INIS)

Tani, Atsushi; Ueno, Takehiro; Yamanaka, Chihiro; Katsura, Makoto; Ikeya, Motoji

2005-01-01

A scanning electron spin resonance (ESR) microscope using a localized microwave field was redesigned to measure ESR spectra from 0 to 400mT using electromagnets. Divalent copper ion (Cu 2+ ) in copper sulfate pentahydrate (CuSO 4 .5H 2 O) was imaged, after the powdered samples were cemented in silicone rubber under a magnetic field. The ratio of the two signal intensities at g=2.27 and 2.08 clearly indicates the orientation of the particles. This method can be used for mapping the local magnetic field and its direction

Construction of imaging system for wide-field-range ESR spectra using localized microwave field and its case study of crystal orientation in suspension of copper sulfate pentahydrate (CuSO4 . 5H2O).

Science.gov (United States)

Tani, Atsushi; Ueno, Takehiro; Yamanaka, Chihiro; Katsura, Makoto; Ikeya, Motoji

2005-02-01

A scanning electron spin resonance (ESR) microscope using a localized microwave field was redesigned to measure ESR spectra from 0 to 400 mT using electromagnets. Divalent copper ion (Cu2+) in copper sulfate pentahydrate (CuSO4 . 5H2O) was imaged, after the powdered samples were cemented in silicone rubber under a magnetic field. The ratio of the two signal intensities at g=2.27 and 2.08 clearly indicates the orientation of the particles. This method can be used for mapping the local magnetic field and its direction.

Giant Magnetic Field Enhancement in Hybridized MIM Structures

KAUST Repository

Alrasheed, Salma

2017-10-23

We propose numerically an approach to narrow the plasmon linewidth and enhance the magnetic near field intensity at a magnetic hot spot in a hybridized metal-insulatormetal (MIM) structure. First we insert in part of the dielectric layer of the MIM, at its center, another dielectric material of a high refractive index (HRI). This results in an increase in the magnetic near field enhancement of the magnetic plasmon (MP) resonance by 82% compared with the MIM without the HRI material. We then couple this enhanced MP resonance to a propagating surface plasmon polariton (SPP) to achieve a further enhancement of 438%. The strong coupling between the MP and the SPP is demonstrated by the large anti-crossing in the reflection spectra. The resulting maximum magnetic field enhancement at the gap is ~ |H / Hi|² = 3555.

Invisible structures in the X-ray absorption spectra of actinides

NARCIS (Netherlands)

Kvashnina, Kristina O.; De Groot, Frank M F

The X-ray absorption spectra of actinides are discussed with an emphasis on the fundamental effects that influence their spectral shape, including atomic multiplet theory, charge transfer theory and crystal field theory. Many actinide spectra consist of a single peak and it is shown that the use of

Alteration of the UV-visible reflectance spectra of H2O ice by ion bombardment

Science.gov (United States)

Sack, N. J.; Boring, J. W.; Johnson, R. E.; Baragiola, R. A.; Shi, M.

1991-01-01

Satellite in the Jovian and Saturnian system exhibit differences in reflectivity between their 'leading' and 'trailing' surfaces which can affect the local vapor pressure. Since these differences are thought to be due to differences in the flux of bombarding magnetospheric ions, the influence of ion impact on the UV-visible reflectance of water ice surfaces (20-90 K) by keV ion bombardment was studied. An observed decrease in reflectance in the UV is attributed to rearrangement processes that affect the physical microstructure and surface 'roughness'. The ratio in reflectance of bombarded to freshly deposited films is compared to the ratio of the reflectance of the leading and trailing hemispheres for Europa and Ganymede.

Analysis of petroleum-contaminated soils by diffuse reflectance spectroscopy and sequential ultrasonic solvent extraction–gas chromatography

International Nuclear Information System (INIS)

Okparanma, Reuben N.; Coulon, Frederic; Mouazen, Abdul M.

2014-01-01

In this study, we demonstrate that partial least-squares regression analysis with full cross-validation of spectral reflectance data estimates the amount of polycyclic aromatic hydrocarbons in petroleum-contaminated tropical rainforest soils. We applied the approach to 137 field-moist intact soil samples collected from three oil spill sites in Ogoniland in the Niger Delta province (5.317°N, 6.467°E), Nigeria. We used sequential ultrasonic solvent extraction–gas chromatography as the reference chemical method. We took soil diffuse reflectance spectra with a mobile fibre-optic visible and near-infrared spectrophotometer (350–2500 nm). Independent validation of combined data from studied sites showed reasonable prediction precision (root-mean-square error of prediction = 1.16–1.95 mg kg −1 , ratio of prediction deviation = 1.86–3.12, and validation r 2 = 0.77–0.89). This suggests that the methodology may be useful for rapid assessment of the spatial variability of polycyclic aromatic hydrocarbons in petroleum-contaminated soils in the Niger Delta to inform risk assessment and remediation. -- Highlights: • We model NIR diffuse reflectance spectra for PAH prediction in contaminated soils. • Soil diffuse reflectance decreases with increasing PAH concentration. • Mechanism of prediction relies on co-variation of PAH with other soil properties. • Positions of important wavelengths are largely similar for studied sites. • Positive regression coefficients around 1647 nm show a link to PAH. -- This approach may be used to collect large spatial data at reduced cost and time to assess the variability of polycyclic aromatic hydrocarbons in petroleum release sites

Reconstruction of reflectance data using an interpolation technique.

Science.gov (United States)

Abed, Farhad Moghareh; Amirshahi, Seyed Hossein; Abed, Mohammad Reza Moghareh

2009-03-01

A linear interpolation method is applied for reconstruction of reflectance spectra of Munsell as well as ColorChecker SG color chips from the corresponding colorimetric values under a given set of viewing conditions. Hence, different types of lookup tables (LUTs) have been created to connect the colorimetric and spectrophotometeric data as the source and destination spaces in this approach. To optimize the algorithm, different color spaces and light sources have been used to build different types of LUTs. The effects of applied color datasets as well as employed color spaces are investigated. Results of recovery are evaluated by the mean and the maximum color difference values under other sets of standard light sources. The mean and the maximum values of root mean square (RMS) error between the reconstructed and the actual spectra are also calculated. Since the speed of reflectance reconstruction is a key point in the LUT algorithm, the processing time spent for interpolation of spectral data has also been measured for each model. Finally, the performance of the suggested interpolation technique is compared with that of the common principal component analysis method. According to the results, using the CIEXYZ tristimulus values as a source space shows priority over the CIELAB color space. Besides, the colorimetric position of a desired sample is a key point that indicates the success of the approach. In fact, because of the nature of the interpolation technique, the colorimetric position of the desired samples should be located inside the color gamut of available samples in the dataset. The resultant spectra that have been reconstructed by this technique show considerable improvement in terms of RMS error between the actual and the reconstructed reflectance spectra as well as CIELAB color differences under the other light source in comparison with those obtained from the standard PCA technique.

Reflectance spectroscopy from TiO2 particles embedded in polyurethane

DEFF Research Database (Denmark)

Gudla, Visweswara Chakravarthy; Canulescu, Stela; Johansen, Villads Egede

2013-01-01

This paper presents the results of a physical simulation carried out using TiO2-Polyurethane composite coating on bright aluminium surface to understand the light scattering effect for designing white surfaces. Polyurethane matrix is selected due to the matching refractive index (1.7) with Al2O3...... layer on anodized aluminium surfaces. Three different TiO2 particle distributions were dispersed in polyurethane and spin coated onto high gloss and caustic etched aluminium substrates. Reflectance spectra of TiO2-polyurethane films of various concentrations were analysed using an integrating sphere....... The results show that the TiO2-polyurethane coatings have a high diffuse reflectance as a result of multiple scattering from TiO2 particles. Diffuse reflectance spectra of TiO2 containing films vary weakly with particle concentration and reach a steady state value at a concentration of 0.75 wt.%. Using...

Reflection of Plane Waves in Generalized Thermoelastic Half Space under the Action of Uniform Magnetic Field

Directory of Open Access Journals (Sweden)

Narottam Maity

2016-01-01

Full Text Available Reflection of longitudinal displacement waves in a generalized thermoelastic half space under the action of uniform magnetic field has been investigated. The magnetic field is applied in such a direction that the problem can be considered as a two-dimensional one. The discussion is based on the three theories of generalized thermoelasticity: Lord-Shulman (L-S, Green-Lindsay (G-L, and Green-Naghdi (G-N with energy dissipation. We compute the possible wave velocities for different models. Amplitude ratios have been presented. The effects of magnetic field on various subjects of interest are discussed and shown graphically.

Spectral reflectance "deconstruction" of the Murchison CM2 carbonaceous chondrite and implications for spectroscopic investigations of dark asteroids

Science.gov (United States)

Cloutis, Edward A.; Pietrasz, Valerie B.; Kiddell, Cain; Izawa, Matthew R. M.; Vernazza, Pierre; Burbine, Thomas H.; DeMeo, Francesca; Tait, Kimberly T.; Bell, James F.; Mann, Paul; Applin, Daniel M.; Reddy, Vishnu

2018-05-01

Carbonaceous chondrites (CCs) are important materials for understanding the early evolution of the solar system and delivery of volatiles and organic material to the early Earth. Presumed CC-like asteroids are also the targets of two current sample return missions: OSIRIS-REx to asteroid Bennu and Hayabusa-2 to asteroid Ryugu, and the Dawn orbital mission at asteroid Ceres. To improve our ability to identify and characterize CM2 CC-type parent bodies, we have examined how factors such as particle size, particle packing, and viewing geometry affect reflectance spectra of the Murchison CM2 CC. The derived relationships have implications for disc-resolved examinations of dark asteroids and sampleability. It has been found that reflectance spectra of slabs are more blue-sloped (reflectance decreasing toward longer wavelengths as measured by the 1.8/0.6 μm reflectance ratio), and generally darker, than powdered sample spectra. Decreasing the maximum grain size of a powdered sample results in progressively brighter and more red-sloped spectra. Decreasing the average grain size of a powdered sample results in a decrease in diagnostic absorption band depths, and redder and brighter spectra. Decreasing porosity of powders and variations in surface texture result in spectral changes that may be different as a function of viewing geometry. Increasing thickness of loose dust on a denser powdered substrate leads to a decrease in absorption band depths. Changes in viewing geometry lead to different changes in spectral metrics depending on whether the spectra are acquired in backscatter or forward-scatter geometries. In backscattered geometry, increasing phase angle leads to an initial increase and then decrease in spectral slope, and a general decrease in visible region reflectance and absorption band depths, and frequent decreases in absorption band minima positions. In forward scattering geometry, increasing phase angle leads to small non-systematic changes in spectral slope

ChemCam passive reflectance spectroscopy of surface materials at the Curiosity landing site, Mars

Science.gov (United States)

Johnson, Jeffrey R.; Bell, J. F.; Bender, S.; Blaney, D.; Cloutis, E.; DeFlores, L.; Ehlmann, B.; Gasnault, O.; Gondet, B.; Kinch, K.; Lemmon, M.; Le Mouélic, S.; Maurice, S.; Rice, M.; Wiens, R. C.

2015-03-01

The spectrometers on the Mars Science Laboratory (MSL) ChemCam instrument were used in passive mode to record visible/near-infrared (400-840 nm) radiance from the martian surface. Using the onboard ChemCam calibration targets' housing as a reflectance standard, we developed methods to collect, calibrate, and reduce radiance observations to relative reflectance. Such measurements accurately reproduce the known reflectance spectra of other calibration targets on the rover, and represent the highest spatial resolution (0.65 mrad) and spectral sampling (rocks and soils match those from orbital observations and multispectral data from the MSL Mastcam camera. Preliminary analyses of the band depths, spectral slopes, and reflectance ratios of the more than 2000 spectra taken during the first year of MSL operations demonstrate at least six spectral classes of materials distinguished by variations in ferrous and ferric components. Initial comparisons of ChemCam spectra to laboratory spectra of minerals and Mars analog materials demonstrate similarities with palagonitic soils and indications of orthopyroxene in some dark rocks. Magnesium-rich "raised ridges" tend to exhibit distinct near-infrared slopes. The ferric absorption downturn typically found for martian materials at rocks and drill tailings, consistent with their more ferrous nature. Calcium-sulfate veins exhibit the highest relative reflectances observed, but are still relatively red owing to the effects of residual dust. Such dust is overall less prominent on rocks sampled within the "blast zone" immediately surrounding the landing site. These samples were likely affected by the landing thrusters, which partially removed the ubiquitous dust coatings. Increased dust coatings on the calibration targets during the first year of the mission were documented by the ChemCam passive measurements as well. Ongoing efforts to model and correct for this dust component should improve calibration of the relative reflectance

Rotational structure in molecular infrared spectra

CERN Document Server

di Lauro, Carlo

2013-01-01

Recent advances in infrared molecular spectroscopy have resulted in sophisticated theoretical and laboratory methods that are difficult to grasp without a solid understanding of the basic principles and underlying theory of vibration-rotation absorption spectroscopy. Rotational Structure in Molecular Infrared Spectra fills the gap between these recent, complex topics and the most elementary methods in the field of rotational structure in the infrared spectra of gaseous molecules. There is an increasing need for people with the skills and knowledge to interpret vibration-rotation spectra in many scientific disciplines, including applications in atmospheric and planetary research. Consequently, the basic principles of vibration-rotation absorption spectroscopy are addressed for contemporary applications. In addition to covering operational quantum mechanical methods, spherical tensor algebra, and group theoretical methods applied to molecular symmetry, attention is also given to phase conventions and their effe...

The effect of grain size and phosphorous-doping of polycrystalline 3C–SiC on infrared reflectance spectra

International Nuclear Information System (INIS)

Rooyen, I.J. van; Engelbrecht, J.A.A.; Henry, A.; Janzén, E.; Neethling, J.H.; Rooyen, P.M. van

2012-01-01

Highlights: ► IR is investigated as a technique to measure grain size and P-doping of polycrystalline SiC. ► Infrared plasma minima can be used to determine doping levels in 3C–SiC for doping levels greater than 5 × 10 17 cm −3 . ► A linear relationship is found between FWHM and the inverse of grain size of 3C–SiC irrespective of P-doping level. ► It is further found that ω p is not influenced by the grain size. ► P-doping level has no significant effect on the linear relationship between grain size and surface roughness. - Abstract: The effect of P-doping and grain size of polycrystalline 3C–SiC on the infrared reflectance spectra is reported. The relationship between grain size and full width at half maximum (FWHM) suggest that the behavior of the 3C–SiC with the highest phosphorous doping level (of 1.2 × 10 19 at. cm −3 ) is different from those with lower doping levels ( 18 at. cm −3 ). It is also further demonstrated that the plasma resonance frequency (ω p ) is not influenced by the grain size.

Light reflection by the cuticle of C. aurigans scarabs: a biological broadband reflector of left handed circularly polarized light

Science.gov (United States)

Libby, E.; Azofeifa, D. E.; Hernández-Jiménez, M.; Barboza-Aguilar, C.; Solís, A.; García-Aguilar, I.; Arce-Marenco, L.; Hernández, A.; Vargas, W. E.

2014-08-01

Measured reflection spectra from elytra of Chrysina aurigans scarabs are reported. They show a broad reflection band for wavelengths from 0.525 to 1.0 μm with a sequence of maxima and minima reflection values superimposed on a mean value of around 40% for the high reflection band. Different mechanisms contributing to the reflection spectra have been considered, with the dominant effect, reflection of left handed circularly polarized light, being produced by a laminated left handed twisted structure whose pitch changes with depth through the procuticle in a more complex way than that characterizing broad band circular polarizers based on cholesteric liquid crystals.

Light reflection by the cuticle of C. aurigans scarabs: a biological broadband reflector of left handed circularly polarized light

International Nuclear Information System (INIS)

Libby, E; Azofeifa, D E; Hernández-Jiménez, M; García-Aguilar, I; Arce-Marenco, L; Hernández, A; Vargas, W E; Barboza-Aguilar, C; Solís, A

2014-01-01

Measured reflection spectra from elytra of Chrysina aurigans scarabs are reported. They show a broad reflection band for wavelengths from 0.525 to 1.0 μm with a sequence of maxima and minima reflection values superimposed on a mean value of around 40% for the high reflection band. Different mechanisms contributing to the reflection spectra have been considered, with the dominant effect, reflection of left handed circularly polarized light, being produced by a laminated left handed twisted structure whose pitch changes with depth through the procuticle in a more complex way than that characterizing broad band circular polarizers based on cholesteric liquid crystals. (fast track communication)

The Sociology of Youth: A Reflection on Its Contribution to the Field and Future Directions

Science.gov (United States)

Wyn, Johanna

2011-01-01

This article expands on a piece in the inaugural "Sociology of Youth Newsletter," edited by Steven Threadgold (Wyn 2010). The present article provides an opportunity to engage in a more critical exploration of the issues that youth sociology in Australia contributes to the wider field of sociology and to reflect on challenges that it…

Anisotropic Behaviour of Magnetic Power Spectra in Solar Wind Turbulence.

Science.gov (United States)

Banerjee, S.; Saur, J.; Gerick, F.; von Papen, M.

2017-12-01

Introduction:High altitude fast solar wind turbulence (SWT) shows different spectral properties as a function of the angle between the flow direction and the scale dependent mean magnetic field (Horbury et al., PRL, 2008). The average magnetic power contained in the near perpendicular direction (80º-90º) was found to be approximately 5 times larger than the average power in the parallel direction (0º- 10º). In addition, the parallel power spectra was found to give a steeper (-2) power law than the perpendicular power spectral density (PSD) which followed a near Kolmogorov slope (-5/3). Similar anisotropic behaviour has also been observed (Chen et al., MNRAS, 2011) for slow solar wind (SSW), but using a different method exploiting multi-spacecraft data of Cluster. Purpose:In the current study, using Ulysses data, we investigate (i) the anisotropic behaviour of near ecliptic slow solar wind using the same methodology (described below) as that of Horbury et al. (2008) and (ii) the dependence of the anisotropic behaviour of SWT as a function of the heliospheric latitude.Method:We apply the wavelet method to calculate the turbulent power spectra of the magnetic field fluctuations parallel and perpendicular to the local mean magnetic field (LMF). According to Horbury et al., LMF for a given scale (or size) is obtained using an envelope of the envelope of that size. Results:(i) SSW intervals always show near -5/3 perpendicular spectra. Unlike the fast solar wind (FSW) intervals, for SSW, we often find intervals where power parallel to the mean field is not observed. For a few intervals with sufficient power in parallel direction, slow wind turbulence also exhibit -2 parallel spectra similar to FSW.(ii) The behaviours of parallel and perpendicular power spectra are found to be independent of the heliospheric latitude. Conclusion:In the current study we do not find significant influence of the heliospheric latitude on the spectral slopes of parallel and perpendicular

Decoding Pure Rotational Molecular Spectra for Asymmetric Molecules

Directory of Open Access Journals (Sweden)

S. A. Cooke

2013-01-01

Full Text Available Rotational spectroscopy can provide insights of unparalleled precision with respect to the wavefunctions of molecular systems that have relevance in fields as diverse as astronomy and biology. In this paper, we demonstrate how asymmetric molecular pure rotational spectra may be analyzed “pictorially” and with simple formulae. It is shown that the interpretation of such spectra relies heavily upon pattern recognition. The presentation of some common spectral line positions in near-prolate asymmetric rotational spectra provides a means by which spectral assignment, and approximate rotational constant determination, may be usefully explored. To aid in this endeavor we have created a supporting, free, web page and mobile web page.

DMSO-Water Clustering in Solution Observed in Soft X-ray Spectra.

Science.gov (United States)

Engel, Nicholas; Atak, Kaan; Lange, Kathrin M; Gotz, Malte; Soldatov, Mikhail; Golnak, Ronny; Suljoti, Edlira; Rubensson, Jan-Erik; Aziz, Emad F

2012-12-20

The significant deviation from the ideality of dimethyl sulfoxide (DMSO)/water mixtures can be addressed based on the change of the local molecular orbitals of each solvent upon mixing. Oxygen K-edge absorption and emission spectra of DMSO/water solutions were measured using the liquid microjet technique. The spectra demonstrate that the hydrogen bond network in liquid water is already influenced at small DMSO concentrations, and at the molar fraction xDMSO = 0.43 we find strong evidence of DMSO-water clustering reflected by the influence on the occupied molecular orbitals.

Surface Compositional Units on Mercury from Spectral Reflectance at Ultraviolet to Near-infrared Wavelengths

Science.gov (United States)

Izenberg, N. R.; Holsclaw, G. M.; Domingue, D. L.; McClintock, W. E.; Klima, R. L.; Blewett, D. T.; Helbert, J.; Head, J. W.; Sprague, A. L.; Vilas, F.; Solomon, S. C.

2012-12-01

The Mercury Atmospheric and Surface Composition Spectrometer (MASCS) on the MErcury Surface, Space ENvironment, GEochemistry, and Ranging (MESSENGER) spacecraft has been acquiring reflectance spectra of Mercury's surface for over 16 months. The Visible and Infrared Spectrograph (VIRS) component of MASCS has accumulated a global data set of more than 2 million spectra over the wavelength range 300-1450 nm. We have derived a set of VIRS spectral units (VSUs) from the following spectral parameters: visible brightness (R575: reflectance at 575 nm); visible/near-infrared reflectance ratio (VISr: reflectance at 415 nm to that at 750 nm); and ultraviolet reflectance ratio (UVr: reflectance at 310 nm to that at 390 nm). Five broad, slightly overlapping VSUs may be distinguished from these parameters. "Average VSU" areas have spectral parameters close to mean global values. "Dark blue VSU" areas have spectra with low R575 and high UVr. "Red VSU" areas have spectra with low UVr and higher VISr and R575 than average. "Intermediate VSU" areas have spectra with higher VISr than VSU red, generally higher R575, and a wide range of UVr. "Bright VSU" areas have high R575 and VISr and intermediate UVr. Several units defined by morphological or multispectral criteria correspond to specific VSUs, including low-reflectance material (dark blue VSU), pyroclastic deposits (red VSU), and hollows (intermediate VSU), but these VSUs generally include other types of areas as well. VSU definitions are complementary to those obtained by unsupervised clustering analysis. The global distribution of VIRS spectral units provides new information on Mercury's geological evolution. Much of Mercury's northern volcanic plains show spectral properties ranging from those of average VSU to those of red VSU, as does a large region in the southern hemisphere centered near 50°S, 245°E. Dark blue VSU material is widely distributed, with concentrations south of the northern plains, around the Rembrandt and

Optical absorption and scattering spectra of pathological stomach tissues

Science.gov (United States)

Giraev, K. M.; Ashurbekov, N. A.; Lakhina, M. A.

2011-03-01

Diffuse reflection spectra of biotissues in vivo and transmission and reflection coefficients for biotissues in vitro are measured over 300-800 nm. These data are used to determine the spectral absorption and scattering indices and the scattering anisotropy factor for stomach mucous membranes under normal and various pathological conditions (chronic atrophic and ulcerous defects, malignant neoplasms). The most importan tphysiological (hemodynamic and oxygenation levels) and structural-morphological (scatterer size and density) parameters are also determined. The results of a morphofunctional study correlate well with the optical properties and are consistent with data from a histomorphological analysis of the corresponding tissues.

Radio synchrotron spectra of star-forming galaxies

Science.gov (United States)

Klein, U.; Lisenfeld, U.; Verley, S.

2018-03-01

We investigated the radio continuum spectra of 14 star-forming galaxies by fitting nonthermal (synchrotron) and thermal (free-free) radiation laws. The underlying radio continuum measurements cover a frequency range of 325 MHz to 24.5 GHz (32 GHz in case of M 82). It turns out that most of these synchrotron spectra are not simple power-laws, but are best represented by a low-frequency spectrum with a mean slope αnth = 0.59 ± 0.20 (Sν ∝ ν-α), and by a break or an exponential decline in the frequency range of 1-12 GHz. Simple power-laws or mildly curved synchrotron spectra lead to unrealistically low thermal flux densities, and/or to strong deviations from the expected optically thin free-free spectra with slope αth = 0.10 in the fits. The break or cutoff energies are in the range of 1.5-7 GeV. We briefly discuss the possible origin of such a cutoff or break. If the low-frequency spectra obtained here reflect the injection spectrum of cosmic-ray electrons, they comply with the mean spectral index of Galactic supernova remnants. A comparison of the fitted thermal flux densities with the (foreground-corrected) Hα fluxes yields the extinction, which increases with metallicity. The fraction of thermal emission is higher than believed hitherto, especially at high frequencies, and is highest in the dwarf galaxies of our sample, which we interpret in terms of a lack of containment in these low-mass systems, or a time effect caused by a very young starburst.

Using visible and near-infrared diffuse reflectance spectroscopy for predicting soil properties based on regression with peaks parameters as derived from continuum-removed spectra

Science.gov (United States)

Vasat, Radim; Klement, Ales; Jaksik, Ondrej; Kodesova, Radka; Drabek, Ondrej; Boruvka, Lubos

2014-05-01

Visible and near-infrared diffuse reflectance spectroscopy (VNIR-DRS) provides a rapid and inexpensive tool for simultaneous prediction of a variety of soil properties. Usually, some sophisticated multivariate mathematical or statistical methods are employed in order to extract the required information from the raw spectra measurement. For this purpose especially the Partial least squares regression (PLSR) and Support vector machines (SVM) are the most frequently used. These methods generally benefit from the complexity with which the soil spectra are treated. But it is interesting that also techniques that focus only on a single spectral feature, such as a simple linear regression with selected continuum-removed spectra (CRS) characteristic (e.g. peak depth), can often provide competitive results. Therefore, we decided to enhance the potential of CRS taking into account all possible CRS peak parameters (area, width and depth) and develop a comprehensive methodology based on multiple linear regression approach. The eight considered soil properties were oxidizable carbon content (Cox), exchangeable (pHex) and active soil pH (pHa), particle and bulk density, CaCO3 content, crystalline and amorphous (Fed) and amorphous Fe (Feox) forms. In four cases (pHa, bulk density, Fed and Feox), of which two (Fed and Feox) were predicted reliably accurately (0.50 interestingly, in the case of particle density, the presented approach outperformed the PLSR and SVM dramatically offering a fairly accurate prediction (R2cv = 0.827) against two failures (R2cv = 0.034 and 0.121 for PLSR and SVM, resp.). In last two cases (Cox and CaCO3) a slightly worse results were achieved then with PLSR and SVM with overall fairly accurate prediction (R2cv > 0.80). Acknowledgment: Authors acknowledge the financial support of the Ministry of Agriculture of the Czech Republic (grant No. QJ1230319).

Observation of magnetic domains using a reflection-mode scanning near-field optical microscope

OpenAIRE

SHVETS, IGOR

1997-01-01

PUBLISHED It is demonstrated that it is possible to image magnetic domains with a resolution of better than 60 nm with the Kerr effect in a reflection-mode scanning near-field optical microscope. Images taken of tracks of thermomagnetically prewritten bits in a Co/Pt multilayer structure magnetized out-of plane showed optical features in a track pattern whose appearance was determined by the position of an analyzer in front of the photomultiplier tube. These features were not apparent in t...

Observation of magnetic domains using a reflection mode scanning near-field optical microscope

OpenAIRE

Durkam, C.; Shvets, I.V.; Lodder, J.C.

1997-01-01

It is demonstrated that it is possible to image magnetic domains with a resolution of better than 60 nm with the Kerr effect in a reflection-mode scanning near-field optical microscope. Images taken of tracks of thermomagnetically prewritten bits in a Co/Pt multilayer structure magnetized out-of plane showed optical features in a track pattern whose appearance was determined by the position of an analyzer in front of the photomultiplier tube. These features were not apparent in the topography...

Quantitative Comparison of the Variability in Observed and Simulated Shortwave Reflectance

Science.gov (United States)

Roberts, Yolanda, L.; Pilewskie, P.; Kindel, B. C.; Feldman, D. R.; Collins, W. D.

2013-01-01

The Climate Absolute Radiance and Refractivity Observatory (CLARREO) is a climate observation system that has been designed to monitor the Earth's climate with unprecedented absolute radiometric accuracy and SI traceability. Climate Observation System Simulation Experiments (OSSEs) have been generated to simulate CLARREO hyperspectral shortwave imager measurements to help define the measurement characteristics needed for CLARREO to achieve its objectives. To evaluate how well the OSSE-simulated reflectance spectra reproduce the Earth s climate variability at the beginning of the 21st century, we compared the variability of the OSSE reflectance spectra to that of the reflectance spectra measured by the Scanning Imaging Absorption Spectrometer for Atmospheric Cartography (SCIAMACHY). Principal component analysis (PCA) is a multivariate decomposition technique used to represent and study the variability of hyperspectral radiation measurements. Using PCA, between 99.7%and 99.9%of the total variance the OSSE and SCIAMACHY data sets can be explained by subspaces defined by six principal components (PCs). To quantify how much information is shared between the simulated and observed data sets, we spectrally decomposed the intersection of the two data set subspaces. The results from four cases in 2004 showed that the two data sets share eight (January and October) and seven (April and July) dimensions, which correspond to about 99.9% of the total SCIAMACHY variance for each month. The spectral nature of these shared spaces, understood by examining the transformed eigenvectors calculated from the subspace intersections, exhibit similar physical characteristics to the original PCs calculated from each data set, such as water vapor absorption, vegetation reflectance, and cloud reflectance.

Interrelating meteorite and asteroid spectra at UV-Vis-NIR wavelengths using novel multiple-scattering methods

Science.gov (United States)

Martikainen, Julia; Penttilä, Antti; Gritsevich, Maria; Muinonen, Karri

2017-10-01

Asteroids have remained mostly the same for the past 4.5 billion years, and provide us information on the origin, evolution and current state of the Solar System. Asteroids and meteorites can be linked by matching their respective reflectance spectra. This is difficult, because spectral features depend strongly on the surface properties, and meteorite surfaces are free of regolith dust present in asteroids. Furthermore, asteroid surfaces experience space weathering which affects their spectral features.We present a novel simulation framework for assessing the spectral properties of meteorites and asteroids and matching their reflectance spectra. The simulations are carried out by utilizing a light-scattering code that takes inhomogeneous waves into account and simulates light scattering by Gaussian-random-sphere particles large compared to the wavelength of the incident light. The code uses incoherent input and computes phase matrices by utilizing incoherent scattering matrices. Reflectance spectra are modeled by combining olivine, pyroxene, and iron, the most common materials that dominate the spectral features of asteroids and meteorites. Space weathering is taken into account by adding nanoiron into the modeled asteroid spectrum. The complex refractive indices needed for the simulations are obtained from existing databases, or derived using an optimization that utilizes our ray-optics code and the measured spectrum of the material.We demonstrate our approach by applying it to the reflectance spectrum of (4) Vesta and the reflectance spectrum of the Johnstown meteorite measured with the University of Helsinki integrating-sphere UV-Vis-NIR spectrometer.Acknowledgments. The research is funded by the ERC Advanced Grant No. 320773 (SAEMPL).

Evaluation of apparent viscosity of Para rubber latex by diffuse reflection near-infrared spectroscopy.

Science.gov (United States)

Sirisomboon, Panmanas; Chowbankrang, Rawiphan; Williams, Phil

2012-05-01

Near-infrared spectroscopy in diffuse reflection mode was used to evaluate the apparent viscosity of Para rubber field latex and concentrated latex over the wavelength range of 1100 to 2500 nm, using partial least square regression (PLSR). The model with ten principal components (PCs) developed using the raw spectra accurately predicted the apparent viscosity with correlation coefficient (r), standard error of prediction (SEP), and bias of 0.974, 8.6 cP, and -0.4 cP, respectively. The ratio of the SEP to the standard deviation (RPD) and the ratio of the SEP to the range (RER) for the prediction were 4.4 and 16.7, respectively. Therefore, the model can be used for measurement of the apparent viscosity of field latex and concentrated latex in quality assurance and process control in the factory.

Beta spectra. II-Positron spectra

International Nuclear Information System (INIS)

Grau, A.; Garcia-Torano, E.

1981-01-01

Using the Fermi theory of beta decay, the beta spectra for 30 positron emitters have been computed, introducing a correction factor for unique forbidden transitions. The spectra are ploted vs. energy, once normalised, and tabulated with the related Fermi functions. The average and median energies are calculated. (author)

A Spectral Library of Emissivity Spectra for MERTIS on BepiColombo

Science.gov (United States)

Maturilli, A.; Helbert, J.; Varatharajan, I.; D'Amore, M.; Hiesinger, H.

2018-05-01

At PSL we measured emissivity spectra in vacuum for a suite of Mercury surface analogues for temperatures from 100°C to >400°C. The spectral library is completed by reflectance on samples fresh and post-heating (0.2 to 200 µm spectral range).

Predicting transmittance spectra of electrophotographic color prints

Science.gov (United States)

Mourad, Safer; Emmel, Patrick; Hersch, Roger D.

2000-12-01

For dry toner electrophotographic color printers, we present a numerical simulation model describing the color printer responses based on a physical characterization of the different electrophotographic process steps. The proposed model introduces a Cross Transfer Efficiency designed to predict the color transmittance spectra of multi-color prints by taking into account the transfer influence of each deposited color toner layer upon the other layers. The simulation model leads to a better understanding of the factors that have an impact on printing quality. In order to avoid the additional optical non-linearities produced by light reflection on paper, we have limited the present investigation to transparency prints. The proposed model succeeded to predict the transmittance spectra of printed wedges combining two color toner layers with a mean deviation less than CIE-LAB (Delta) E equals 2.5.

BETA SPECTRA. I. Negatrons spectra

International Nuclear Information System (INIS)

Grau Malonda, A.; Garcia-Torano, E.

1978-01-01

Using the Fermi theory of beta decay, the beta spectra for 62 negatrons emitters have been computed introducing a correction factor for unique forbidden transitions. These spectra are plotted vs. energy, once normal i sed, and tabulated with the related Fermi functions. The average and median energies are calculated. (Author)

Primordial spectra from sudden turning trajectory

Science.gov (United States)

Noumi, Toshifumi; Yamaguchi, Masahide

2013-12-01

Effects of heavy fields on primordial spectra of curvature perturbations are discussed in inflationary models with a sudden turning trajectory. When heavy fields are excited after the sudden turn and oscillate around the bottom of the potential, the following two effects are generically induced: deformation of the inflationary background spacetime and conversion interactions between adiabatic and isocurvature perturbations, both of which can affect the primordial density perturbations. In this paper, we calculate primordial spectra in inflationary models with sudden turning potentials taking into account both of the two effects appropriately. We find that there are some non-trivial correlations between the two effects in the power spectrum and, as a consequence, the primordial scalar power spectrum has a peak around the scale exiting the horizon at the turn. Though both effects can induce parametric resonance amplifications, they are shown to be canceled out for the case with the canonical kinetic terms. The peak feature and the scale dependence of bispectra are also discussed.

Marginally bound resonances of charged massive scalar fields in the background of a charged reflecting shell

Energy Technology Data Exchange (ETDEWEB)

Hod, Shahar, E-mail: shaharhod@gmail.com [The Ruppin Academic Center, Emeq Hefer 40250 (Israel); The Hadassah Academic College, Jerusalem 91010 (Israel)

2017-05-10

We study analytically the characteristic resonance spectrum of charged massive scalar fields linearly coupled to a spherically symmetric charged reflecting shell. In particular, we use analytical techniques in order to solve the Klein–Gordon wave equation for the composed charged-shell–charged-massive-scalar-field system. Interestingly, it is proved that the resonant oscillation frequencies of this composed physical system are determined by the characteristic zeroes of the confluent hypergeometric function. Following this observation, we derive a remarkably compact analytical formula for the resonant oscillation frequencies which characterize the marginally-bound charged massive scalar field configurations. The analytically derived resonance spectrum is confirmed by numerical computations.

Stationary spectra in a quasi neutral current-carrying plasma

International Nuclear Information System (INIS)

Vakulenko, M.O.

1992-01-01

The low-frequency short-wave equilibrium spectra of electromagnetic fluctuations are obtained, accounting for cross-field correlations. The statistical analysis shows that a longitudinal current in a dense quasi neutral (α e ≡4πnomec 2 /Bo 2 >>1) plasma destroys the stationary of fluctuation spectra corresponding to zero fluxes of motion invariants, and may alter also the anomalous electron heat conductivity. 2 refs. (author)

Calculated Hanle transmission and absorption spectra of the 87Rb D1 line with residual magnetic field for arbitrarily polarized light

International Nuclear Information System (INIS)

Noh, Heung-Ryoul; Moon, Han Seb

2010-01-01

This paper reports a theoretical study on the transmission spectra of an arbitrarily polarized laser beam through a rubidium cell with or without a buffer gas in Hanle-type coherent population trapping (CPT). This study examined how laser polarization, transverse magnetic field, and collisions with buffer gas affects the spectrum. The transmission spectrum due to CPT and the absorption spectrum due to the level crossing absorption (LCA) were calculated according to the laser polarization. The results show that the LCA is strongly dependent on the transverse magnetic field and interaction time of the atoms with a laser light via collisions with the buffer gas. In addition, the spectral shape of the calculated Hanle spectrum is closely related to the direction between the (stray) transverse magnetic field and polarization of the laser.

Nonlinear FMR spectra in yttrium iron garnet

Directory of Open Access Journals (Sweden)

Yu.M. Bunkov, P.M. Vetoshko, I.G. Motygullin, T.R. Safin, M.S. Tagirov, N.A. Tukmakova

2015-12-01

Full Text Available Results of demagnetizing effect studies in yttrium iron garnet Y3Fe5O12 thin films are reported. Experiments were performed on X-Band of electron paramagnetic resonance spectrometer at room temperature. The ferromagnetic resonance (FMR spectra were obtained for one-layer single crystal YIG films for different values of the applied microwave power. Nonlinear FMR spectra transformation by the microwave power increasing in various directions of magnetic field sweep was observed. It is explained by the influence of the demagnetization action of nonequilibrium magnons.

Dynamical characteristics of an electromagnetic field under conditions of total reflection

Science.gov (United States)

Bekshaev, Aleksandr Ya

2018-04-01

The dynamical characteristics of electromagnetic fields include energy, momentum, angular momentum (spin) and helicity. We analyze their spatial distributions near the planar interface between two transparent and non-dispersive media, when the incident monochromatic plane wave with arbitrary polarization is totally reflected, and an evanescent wave is formed in the medium with lower optical density. Based on the recent arguments in favor of the Minkowski definition of the electromagnetic momentum in a material medium (Philbin 2011 Phys. Rev. A 83 013823; Philbin and Allanson 2012 86 055802; Bliokh et al 2017 Phys. Rev. Lett. 119 073901), we derive the explicit expressions for the dynamical characteristics in both media, with special attention to their behavior at the interface. In particular, the ‘extraordinary’ spin and momentum components orthogonal to the plane of incidence are described, and a canonical (spin-orbital) momentum decomposition is performed that contains no singular terms. The field energy, helicity, the spin momentum and orbital momentum components are everywhere regular but experience discontinuities at the interface; the spin components parallel to the interface appear to be continuous, which testifies to the consistency of the adopted Minkowski picture. The results supply a meaningful example of the electromagnetic momentum decomposition, with separation of spatial and polarization degrees of freedom, in inhomogeneous media, and can be used in engineering the structured fields designed for optical sorting, dispatching and micromanipulation.

Logging into the Field—Methodological Reflections on Ethnographic Research in a Pluri-Local and Computer-Mediated Field

Directory of Open Access Journals (Sweden)

Heike Mónika Greschke

2007-09-01

Full Text Available This article aims to introduce an ethnic group inhabiting a common virtual space in the World Wide Web (WWW, while being physically located in different socio-geographical contexts. Potentially global in its geographical extent, this social formation is constituted by means of interrelating virtual-global dimensions with physically grounded parts of the actors' lifeworlds. In addition, the communities' social life relies on specific communicative practices joining mediated forms of communication with co-presence based encounters. Ethnographic research in a pluri-local and computer-mediated field poses a set of problems which demand thorough reflection as well as a search for creative solutions. How can the boundaries of the field be determined? What does "being there" signify in such a case? Is it possible to enter the field while sitting at my own desk, just by visiting the respective site in the WWW, simply observing the communication going on without even being noticed by the subjects in the field? Or does "being in the field" imply that I ought to turn into a member of the studied community? Am I supposed to effectively live with the others for a while? And then, what can "living together" actually mean in that case? Will I learn enough about the field simply by participating in its virtual activities? Or do I have to account for the physically grounded dimensions of the actors' lifeworlds, as well? Ethnographic research in a pluri-local and computer-mediated field in practice raises a lot of questions regarding the ways of entering the field and being in the field. Some of them will be discussed in this paper by means of reflecting research experiences gained in the context of a recently concluded case study. URN: urn:nbn:de:0114-fqs0703321

Exponential power spectra, deterministic chaos and Lorentzian pulses in plasma edge dynamics

International Nuclear Information System (INIS)

Maggs, J E; Morales, G J

2012-01-01

Exponential spectra have been observed in the edges of tokamaks, stellarators, helical devices and linear machines. The observation of exponential power spectra is significant because such a spectral character has been closely associated with the phenomenon of deterministic chaos by the nonlinear dynamics community. The proximate cause of exponential power spectra in both magnetized plasma edges and nonlinear dynamics models is the occurrence of Lorentzian pulses in the time signals of fluctuations. Lorentzian pulses are produced by chaotic behavior in the separatrix regions of plasma E × B flow fields or the limit cycle regions of nonlinear models. Chaotic advection, driven by the potential fields of drift waves in plasmas, results in transport. The observation of exponential power spectra and Lorentzian pulses suggests that fluctuations and transport at the edge of magnetized plasmas arise from deterministic, rather than stochastic, dynamics. (paper)

Decomposing the permeability spectra of nanocrystalline finemet core

Directory of Open Access Journals (Sweden)

Lajos K. Varga

2018-04-01

Full Text Available In this paper we present a theoretical and experimental investigation on the magnetization contributions to permeability spectra of normal annealed Finemet core with round type hysteresis curve. Real and imaginary parts of the permeability were determined as a function of exciting magnetic field (HAC between 40 Hz -110 MHz using an Agilent 4294A type Precision Impedance Analyzer. The amplitude of the exciting field was below and around the coercive field of the sample. The spectra were decomposed using the Levenberg–Marquardt algorithm running under Origin 9 software in four contributions: i eddy current; ii Debye relaxation of magnetization rotation, iii Debye relaxation of damped domain wall motion and iv resonant type DW motion. For small exciting amplitudes the first two components dominate. The last two contributions connected to the DW appear for relative large HAC only, around the coercive force. All the contributions will be discussed in detail accentuating the role of eddy current that is not negligible even for the smallest applied exciting field.

Spontaneous emission spectra from a staggered-array undulator

International Nuclear Information System (INIS)

Shimada, Shigeki; Okada, Kouji; Masuda, Kai; Sobajima, Masaaki; Yoshikawa, Kiyoshi; Ohnishi, Masami; Yamamoto, Yasushi; Toku, Hisayuki

1997-01-01

A staggered-array undulator set inside the superconducting solenoid coils is shown to be able to provide high undulator fields larger than the longitudinal magnetic fields, a small undulator period, easy tunability through the solenoid coil current, and compact and easy fabrication. The overall performance characteristics of this undulator were studied mainly with respect to iron and aluminum disk widths, and spontaneous emission spectra through the numerical calculations. The maximum undulator field is found to be obtained for the ratio of the aluminum disk width to the undulator period of 0.45. The line widths (FWHM) of the spontaneous emission spectra, however, do not show N w -1 dependence on the number of the undulator period N w for practical beams with a Gaussian distribution, compared with for a single electron. The energy spread among various parameters is seen to play an important role in reducing the FWHM with increase of N w . The large tunability of the wavelength is proved to cover 6-10 mm by changing the solenoid magnetic field from 0.4 T to 1.6 T. (author)

Polarized infrared reflectance studies for wurtzite InN epilayers on Si(111) grown by molecular beam expitaxy

International Nuclear Information System (INIS)

Ooi, P.K.; Lee, S.C.; Ng, S.S.; Hassan, Z.; Abu Hassan, H.; Chen, W.L.

2011-01-01

Room temperature polarized infrared reflectance technique is employed to study the optical properties of wurtzite InN epilayers on Si(111) grown by molecular beam expitaxy. The reflection spectra are compared to the calculated spectra generated based on the anisotropic dielectric function model. Good agreement between the measured and calculated spectra is obtained. From the fit of the experimental curve, the reststrahlen parameters at the center of Brillouin zone, the carrier concentration and mobility as well as the epilayers thicknesses are determined. The values of the carrier concentration and mobility are in good agreement with the results obtained from the Hall effects measurements.

X-ray absorption spectra and emission spectra of plasmas

International Nuclear Information System (INIS)

Peng Yonglun; Yang Li; Wang Minsheng; Li Jiaming

2002-01-01

The author reports a theoretical method to calculate the resolved absorption spectra and emission spectra (optically thin) of hot dense plasmas. Due to its fully relativistic treatment incorporated with the quantum defect theory, it calculates the absorption spectra and emission spectra for single element or multi-element plasmas with little computational efforts. The calculated absorption spectra of LTE gold plasmas agree well with the experimental ones. It also calculates the optical thin emission spectra of LTE gold plasmas, which is helpful to diagnose the plasmas of relevant ICF plasmas. It can also provide the relevant parameters such as population density of various ionic stages, precise radiative properties for ICF studies

Use of Reflectance Ratios as a Proxy for Coastal Water Constituent Monitoring in the Pearl River Estuary

Directory of Open Access Journals (Sweden)

Hong-Li Li

2009-01-01

Full Text Available Spectra, salinity, total suspended solids (TSS, in mg/L and colored dissolved organic matter (CDOM, ag(400 at 400 nm sampled in stations in 44 different locations on December 18, 19 and 21, in 2006 were measured and analyzed. The studied field covered a large variety of optically different waters, the absorption coefficient of CDOM ([ag(400] in m-1 varied between 0.488 and 1.41 m-1, and the TSS concentrations (mg/L varied between 7.0 and 241.1 mg/L. In order to detect salinity of the Pearl River Estuary, we analyzed the spectral properties of TSS and CDOM, and the relationships between field water reflectance spectra and water constituents’ concentrations based on the synchronous in-situ and satellite hyper-spectral image analysis. A good correlation was discovered (the positive correlation by linear fit, between in-situ reflectance ratio R680/R527 and TSS concentrations (R2 = 0.65 for the salinity range of 1.74-22.12. However, the result also showed that the absorption coefficient of CDOM was not tightly correlated with reflectance. In addition, we also observed two significant relationships (R2 > 0.77, one between TSS concentrations and surface salinity and the other between the absorption coefficient of CDOM and surface salinity. Finally, we develop a novel method to understand surface salinity distribution of estuarine waters from the calibrated EO-1 Hyperion reflectance data in the Pearl River Estuary, i.e. channels with high salinity and shoals with low salinity. The EO-1 Hyperion derived surface salinity and TSSconcentrations were validated using in-situ data that were collected on December 21, 2006, synchronous with EO-1 Hyperion satellite imagery acquisition. The results showed that the semi-empirical relationships are capable of predicting salinity from EO-1 Hyperion imagery in the Pearl River Estuary (RMSE < 2‰.

Spectrophotometry of Pluto-Charon mutual events - Individual spectra of Pluto and Charon

Science.gov (United States)

Sawyer, S. R.; Barker, E. S.; Cochran, A. L.; Cochran, W. D.

1987-01-01

Time-resolved spectra of the March 3 and April 4, 1987 mutual events of Pluto and Charon, obtained with spectral coverage from 5500 to 10,000 A with 25-A spectral resolution, are discussed. Charon has a featureless reflectance spectrum, with no evidence of methane absorption. Charon's reflectance appears neutral in color and corresponds to a geometric albedo of about 0.37 at 6000 A. The Pluto reflectance spectrum displays methane absorption bands at 7300, 7900, 8400, 8600, and 8900 A and is red in color, with a geometric albedo of about 0.56 at 6000 A.

Response spectra for nuclear structures on rock sites considering the near-fault directivity effect

Institute of Scientific and Technical Information of China (English)

Xu Longiun; Yang Shengchao; Xie Lili

2010-01-01

Near-fault ground motions, potentially with large amplitude and typical velocity pulses, may significantly impact the performance of a wide range of structures. The current study is aimed at evaluating the safety implications of the near-fault effect on nuclear power plant facilities designed according to the Chinese code. To this end, a set of near-fault ground motions at rock sites with typical forward-directivity effect is examined with special emphasis on several key parameters and response spectra. Spectral comparison of the selected records with the Chinese and other code design spectra was conducted. The bi-normalized response spectra in terms of different comer periods are utilized to derive nuclear design spectra. It is concluded that nuclear design spectra on rock sites derived from typical rupture directivity records are significantly influenced both by the earthquake magnitude and the rupture distance. The nuclear design spectra specified in the code needs to be adjusted to reflect the near-fault directivity effect of large earthquakes.

Construction of imaging system for wide-field-range ESR spectra using localized microwave field and its case study of crystal orientation in suspension of copper sulfate pentahydrate (CuSO{sub 4}.5H{sub 2}O)

Energy Technology Data Exchange (ETDEWEB)

Tani, Atsushi [Department of Earth and Space Science, Graduate School of Science, Osaka University, 1-1 Machikaneyama Toyonaka, Osaka 560-0043 (Japan)]. E-mail: atani@ess.sci.osaka-u.ac.jp; Ueno, Takehiro [Department of Earth and Space Science, Graduate School of Science, Osaka University, 1-1 Machikaneyama Toyonaka, Osaka 560-0043 (Japan); Yamanaka, Chihiro [Department of Earth and Space Science, Graduate School of Science, Osaka University, 1-1 Machikaneyama Toyonaka, Osaka 560-0043 (Japan); Katsura, Makoto [Department of Earth and Space Science, Graduate School of Science, Osaka University, 1-1 Machikaneyama Toyonaka, Osaka 560-0043 (Japan); Ikeya, Motoji [Department of Earth and Space Science, Graduate School of Science, Osaka University, 1-1 Machikaneyama Toyonaka, Osaka 560-0043 (Japan)

2005-02-01

A scanning electron spin resonance (ESR) microscope using a localized microwave field was redesigned to measure ESR spectra from 0 to 400mT using electromagnets. Divalent copper ion (Cu{sup 2+}) in copper sulfate pentahydrate (CuSO{sub 4}.5H{sub 2}O) was imaged, after the powdered samples were cemented in silicone rubber under a magnetic field. The ratio of the two signal intensities at g=2.27 and 2.08 clearly indicates the orientation of the particles. This method can be used for mapping the local magnetic field and its direction.

PGOPHER: A program for simulating rotational, vibrational and electronic spectra

International Nuclear Information System (INIS)

Western, Colin M.

2017-01-01

The PGOPHER program is a general purpose program for simulating and fitting molecular spectra, particularly the rotational structure. The current version can handle linear molecules, symmetric tops and asymmetric tops and many possible transitions, both allowed and forbidden, including multiphoton and Raman spectra in addition to the common electric dipole absorptions. Many different interactions can be included in the calculation, including those arising from electron and nuclear spin, and external electric and magnetic fields. Multiple states and interactions between them can also be accounted for, limited only by available memory. Fitting of experimental data can be to line positions (in many common formats), intensities or band contours and the parameters determined can be level populations as well as rotational constants. PGOPHER is provided with a powerful and flexible graphical user interface to simplify many of the tasks required in simulating, understanding and fitting molecular spectra, including Fortrat diagrams and energy level plots in addition to overlaying experimental and simulated spectra. The program is open source, and can be compiled with open source tools. This paper provides a formal description of the operation of version 9.1. - Highlights: • Easy-to-use graphical interface for assigning and understanding molecular spectra. • Simulates rotational and vibrational structure of many types of molecular spectra. • Fits molecular properties to line positions or spectral contours. • Handles linear molecules and symmetric and asymmetric tops. • Handles perturbations, nuclear and electron spin, and electric and magnetic fields.

Multivariate analysis of ATR-FTIR spectra for assessment of oil shale organic geochemical properties

Science.gov (United States)

Washburn, Kathryn E.; Birdwell, Justin E.

2013-01-01

In this study, attenuated total reflectance (ATR) Fourier transform infrared spectroscopy (FTIR) was coupled with partial least squares regression (PLSR) analysis to relate spectral data to parameters from total organic carbon (TOC) analysis and programmed pyrolysis to assess the feasibility of developing predictive models to estimate important organic geochemical parameters. The advantage of ATR-FTIR over traditional analytical methods is that source rocks can be analyzed in the laboratory or field in seconds, facilitating more rapid and thorough screening than would be possible using other tools. ATR-FTIR spectra, TOC concentrations and Rock–Eval parameters were measured for a set of oil shales from deposits around the world and several pyrolyzed oil shale samples. PLSR models were developed to predict the measured geochemical parameters from infrared spectra. Application of the resulting models to a set of test spectra excluded from the training set generated accurate predictions of TOC and most Rock–Eval parameters. The critical region of the infrared spectrum for assessing S1, S2, Hydrogen Index and TOC consisted of aliphatic organic moieties (2800–3000 cm−1) and the models generated a better correlation with measured values of TOC and S2 than did integrated aliphatic peak areas. The results suggest that combining ATR-FTIR with PLSR is a reliable approach for estimating useful geochemical parameters of oil shales that is faster and requires less sample preparation than current screening methods.

Remote Sensing Combined with Field Spectroscopy for the Detection and Monitoring of Heavy Metal Contamination from Informal E-waste Recycling

Science.gov (United States)

Friedlander, L. R.; Garb, Y.

2017-12-01

Electronic waste (e-waste) is one of today's fastest growing waste streams. Made up of discarded electronics, e-waste disposal is complex. However, e-waste also provides economic opportunity through the processing and extraction of precious metals. Sometimes referred to as "urban mining," this recycling operates informally or illegally and is characterized by dangerous practices such as, open-pit burning, acid leaching, and burning of low value wastes. Poorly controlled e-waste recycling releases dangerous contaminants, especially heavy metals, directly to the surface environment where they can infiltrate water resources and spread through precipitation events. Despite growing recognition of the prevalence of unregulated e-waste processing, systematic data on the extent and persistence of the released contamination is still limited. In general, contamination is established through techniques that provide only a snapshot in time and in a limited geographic area. Here we present preliminary results from attempts to combine field, laboratory, and remote sensing studies toward a systematic remote sensing methodology for e-waste contamination detection and monitoring. The ongoing work utilizes a tragic "natural experiment," in which over 500 e-waste burn sites were active over more than a decade in a variety of agricultural, residential, and natural contexts. We have collected over 100 soil samples for which we have both XRF and ICP-AES measurements showing soil Pb concentrations as high as 14000 ppm. We have also collected 480 in-situ reflectance spectra with corresponding soil samples over 4 field transects of areas with long-term burn activity. The most heavily contaminated samples come from within the burn sites and are made up of ash. Field spectra of these samples reflect their dark color with low overall reflectance and shallow spectral features. These spectra are challenging to use for image classification due to their similarity with other low-reflectance parts

Northeastern Brazilian margin: Regional tectonic evolution based on integrated analysis of seismic reflection and potential field data and modelling

Science.gov (United States)

Blaich, Olav A.; Tsikalas, Filippos; Faleide, Jan Inge

2008-10-01

Integration of regional seismic reflection and potential field data along the northeastern Brazilian margin, complemented by crustal-scale gravity modelling, is used to reveal and illustrate onshore-offshore crustal structure correlation, the character of the continent-ocean boundary, and the relationship of crustal structure to regional variation of potential field anomalies. The study reveals distinct along-margin structural and magmatic changes that are spatially related to a number of conjugate Brazil-West Africa transfer systems, governing the margin segmentation and evolution. Several conceptual tectonic models are invoked to explain the structural evolution of the different margin segments in a conjugate margin context. Furthermore, the constructed transects, the observed and modelled Moho relief, and the potential field anomalies indicate that the Recôncavo, Tucano and Jatobá rift system may reflect a polyphase deformation rifting-mode associated with a complex time-dependent thermal structure of the lithosphere. The constructed transects and available seismic reflection profiles, indicate that the northern part of the study area lacks major breakup-related magmatic activity, suggesting a rifted non-volcanic margin affinity. In contrast, the southern part of the study area is characterized by abrupt crustal thinning and evidence for breakup magmatic activity, suggesting that this region evolved, partially, with a rifted volcanic margin affinity and character.

Derivation of the radial profile of ion temperature from the measured energy spectra of charge-exchanged neutrals

Energy Technology Data Exchange (ETDEWEB)

Nakamura, K; Hiraki, N; Toi, K; Itoh, S

1980-01-01

In the TRIAM-1 tokamak the energy spectra of charge-exchanged neutrals are observed by scanning the neutral energy analyzer vertically. The measured ion temperature obtained from the only energy spectrum observed in the peripheral region is much higher than that predicted by the neoclassical transport theory because of reflection (backscattering) of neutrals at the wall. The actual ion temperature profile is derived from all observed energy spectra by the numerical code in which a wall-reflection effect of neutrals and an impermeability of plasma are taken into account. The reflection coefficient is adjusted so that the calculated ion temperature profile should be the best fit for the ion temperatures measured by the Doppler broadening of the visible lines He II 4686 A and H-alpha at the relevant radial positions.

Optical spectra of composite silver-porous silicon (Ag-pSi) nanostructure based periodical lattice

Science.gov (United States)

Amedome Min-Dianey, Kossi Aniya; Zhang, Hao-Chun; Brohi, Ali Anwar; Yu, Haiyan; Xia, Xinlin

2018-03-01

Numerical finite differential time domain (FDTD) tools were used in this study for predicting the optical characteristics through the nanostructure of composite silver-porous silicon (Ag-pSi) based periodical lattice. This is aimed at providing an interpretation of the optical spectra at known porosity in improvement of the light manipulating efficiency through a proposed structure. With boundary conditions correctly chosen, the numerical simulation was achieved using FDTD Lumerical solutions. This was used to investigate the effect of porosity and the number of layers on the reflection, transmission and absorption characteristics through a proposed structure in a visible wavelength range of 400-750 nm. The results revealed that the higher the number of layers, the lower the reflection. Also, the reflection increases with porosity increase. The transmission characteristics were the inverse to those found in the case of reflection spectra and optimum transmission was attained at high number of layers. Also, increase in porosity results in reduced transmission. Increase in porosity as well as in the number of layers led to an increase in absorption. Therefore, absorption into such structure can be enhanced by elevating the number of layers and the degree of porosity.

The effect of grain size and phosphorous-doping of polycrystalline 3C-SiC on infrared reflectance spectra

Energy Technology Data Exchange (ETDEWEB)

Rooyen, I.J. van, E-mail: Isabella.vanRooyen@inl.gov [Fuel Performance and Design Department, Idaho National Laboratory, Idaho Falls, ID 83415-6188 (United States); Department of Physics, Nelson Mandela Metropolitan University, Port Elizabeth (South Africa); Engelbrecht, J.A.A. [Department of Physics, Nelson Mandela Metropolitan University, Port Elizabeth (South Africa); Henry, A.; Janzen, E. [Department of Physics, Chemistry and Biology, Semiconductor Materials, Linkoeping University, Linkoeping 58183 (Sweden); Neethling, J.H. [Department of Physics, Nelson Mandela Metropolitan University, Port Elizabeth (South Africa); Rooyen, P.M. van [Philip M van Rooyen Network Consultants, Midlands Estates (South Africa)

2012-03-15

Highlights: Black-Right-Pointing-Pointer IR is investigated as a technique to measure grain size and P-doping of polycrystalline SiC. Black-Right-Pointing-Pointer Infrared plasma minima can be used to determine doping levels in 3C-SiC for doping levels greater than 5 Multiplication-Sign 10{sup 17} cm{sup -3}. Black-Right-Pointing-Pointer A linear relationship is found between FWHM and the inverse of grain size of 3C-SiC irrespective of P-doping level. Black-Right-Pointing-Pointer It is further found that {omega}{sub p} is not influenced by the grain size. Black-Right-Pointing-Pointer P-doping level has no significant effect on the linear relationship between grain size and surface roughness. - Abstract: The effect of P-doping and grain size of polycrystalline 3C-SiC on the infrared reflectance spectra is reported. The relationship between grain size and full width at half maximum (FWHM) suggest that the behavior of the 3C-SiC with the highest phosphorous doping level (of 1.2 Multiplication-Sign 10{sup 19} at. cm{sup -3}) is different from those with lower doping levels (<6.6 Multiplication-Sign 10{sup 18} at. cm{sup -3}). It is also further demonstrated that the plasma resonance frequency ({omega}{sub p}) is not influenced by the grain size.

Electron and phonon spectra in La2-xSrxCuI4+δ

International Nuclear Information System (INIS)

Nomerovannaya, L.V.; Makhnev, A.A.; Malyuk, A.N.; Bolotin, G.A.; Shtrapenin, G.L.; Ignatenkov, A.N.

1995-01-01

Ellipsometric measurements of optical constants and measurements of reflection spectra of La 2-x Sr x CuI 4+δ monocrystals were carried out. Variation of peculiarities of electron and phonon spectra at strontium doping was followed. Formulae to calculate ε dielectric permittivity tensor component on the ground of ellipsometric measurements for tetragonal and orthorhombic crystals are given. Effect of superstoichiometric oxygen content on anisotropy of La 2 CuO 4+δ optical properties was studied. 18 refs., 5 figs., 1 tab

Regression-based model of skin diffuse reflectance for skin color analysis

Science.gov (United States)

Tsumura, Norimichi; Kawazoe, Daisuke; Nakaguchi, Toshiya; Ojima, Nobutoshi; Miyake, Yoichi

2008-11-01

A simple regression-based model of skin diffuse reflectance is developed based on reflectance samples calculated by Monte Carlo simulation of light transport in a two-layered skin model. This reflectance model includes the values of spectral reflectance in the visible spectra for Japanese women. The modified Lambert Beer law holds in the proposed model with a modified mean free path length in non-linear density space. The averaged RMS and maximum errors of the proposed model were 1.1 and 3.1%, respectively, in the above range.

Operation of a scanning near field optical microscope in reflection in combination with a scanning force microscope

NARCIS (Netherlands)

van Hulst, N.F.; Moers, M.H.P.; Moers, M.H.P.; Noordman, O.F.J.; Noordman, O.F.J.; Faulkner, T.; Segerink, Franciscus B.; van der Werf, Kees; de Grooth, B.G.; Bölger, B.; Bölger, B.

1992-01-01

Images obtained with a scanning near field optical microscope (SNOM) operating in reflection are presented. We have obtained the first results with a SiN tip as optical probe. The instrument is simultaneously operated as a scanning force microscope (SFM). Moreover, the instrument incorporates an

Skew Projection of Echo-Detected EPR Spectra for Increased Sensitivity and Resolution

Science.gov (United States)

Bowman, Michael K.; Krzyaniak, Matthew D.; Cruce, Alex A.; Weber, Ralph T.

2013-01-01

The measurement of EPR spectra during pulsed EPR experiments is commonly accomplished by recording the integral of the electron spin echo as the applied magnetic field is stepped through the spectrum. This approach to echo-detected EPR spectral measurement (ED-EPR) limits sensitivity and spectral resolution and can cause gross distortions in the resulting spectra because some of the information present in the electron spin echo is discarded in such measurements. However, Fourier Transformation of echo shapes measured at a series of magnetic field values followed by skew projection onto either a magnetic field or resonance frequency axis can increase both spectral resolution and sensitivity without the need to trade one against the other. Examples of skew-projected spectra with single crystals, glasses and powders show resolution improvements as large as a factor of seven with sensitivity increases of as much as a factor of five. PMID:23644351

Visible/near-infrared spectral diversity from in situ observations of the Bagnold Dune Field sands in Gale Crater, Mars

Science.gov (United States)

Johnson, Jeffrey R.; Achilles, Cherie; Bell, James F.; Bender, Steve; Cloutis, Edward; Ehlmann, Bethany; Fraeman, Abigail; Gasnault, Olivier; Hamilton, Victoria E.; Le Mouélic, Stéphane; Maurice, Sylvestre; Pinet, Patrick; Thompson, Lucy; Wellington, Danika; Wiens, Roger C.

2017-12-01

As part of the Bagnold Dune campaign conducted by Mars Science Laboratory rover Curiosity, visible/near-infrared reflectance spectra of dune sands were acquired using Mast Camera (Mastcam) multispectral imaging (445-1013 nm) and Chemistry and Camera (ChemCam) passive point spectroscopy (400-840 nm). By comparing spectra from pristine and rover-disturbed ripple crests and troughs within the dune field, and through analysis of sieved grain size fractions, constraints on mineral segregation from grain sorting could be determined. In general, the dune areas exhibited low relative reflectance, a weak 530 nm absorption band, an absorption band near 620 nm, and a spectral downturn after 685 nm consistent with olivine-bearing sands. The finest grain size fractions occurred within ripple troughs and in the subsurface and typically exhibited the strongest 530 nm bands, highest relative reflectances, and weakest red/near-infrared ratios, consistent with a combination of crystalline and amorphous ferric materials. Coarser-grained samples were the darkest and bluest and exhibited weaker 530 nm bands, lower relative reflectances, and stronger downturns in the near-infrared, consistent with greater proportions of mafic minerals such as olivine and pyroxene. These grains were typically segregated along ripple crests and among the upper surfaces of grain flows in disturbed sands. Sieved dune sands exhibited progressive decreases in reflectance with increasing grain size, as observed in laboratory spectra of olivine size separates. The continuum of spectral features observed between the coarse- and fine-grained dune sands suggests that mafic grains, ferric materials, and air fall dust mix in variable proportions depending on aeolian activity and grain sorting.

Off-great-circle paths in transequatorial propagation: 2. Nonmagnetic-field-aligned reflections

Science.gov (United States)

Tsunoda, Roland T.; Maruyama, Takashi; Tsugawa, Takuya; Yokoyama, Tatsuhiro; Ishii, Mamoru; Nguyen, Trang T.; Ogawa, Tadahiko; Nishioka, Michi

2016-11-01

There is considerable evidence that plasma structure in nighttime equatorial F layer develops from large-scale wave structure (LSWS) in bottomside F layer. However, crucial details of how this process proceeds, from LSWS to equatorial plasma bubbles (EPBs), remain to be sorted out. A major obstacle to success is the paucity of measurements that provide a space-time description of the bottomside F layer over a broad geographical region. The transequatorial propagation (TEP) experiment is one of few methods that can do so. New findings using a TEP experiment, between Shepparton (SHP), Australia, and Oarai (ORI), Japan, are presented in two companion papers. In Paper 1 (P1), (1) off-great-circle (OGC) paths are described in terms of discrete and diffuse types, (2) descriptions of OGC paths are generalized from a single-reflection to a multiple-reflection process, and (3) discrete type is shown to be associated with an unstructured but distorted upwelling, whereas the diffuse type is shown to be associated with EPBs. In Paper 2 (P2), attention is placed on differences in east-west (EW) asymmetry, found between OGC paths from the SHP-ORI experiment and those from another near-identical TEP experiment. Differences are reconciled by allowing three distinct sources for the EW asymmetries: (1) reflection properties within an upwelling (see P1), (2) OGC paths that depend on magnetic declination of geomagnetic field (B), and (3) OGC paths supported by non-B-aligned reflectors at latitudes where inclination of B is finite.

Influence of pure dephasing on emission spectra from single photon sources

DEFF Research Database (Denmark)

Næsby Rasmussen, Andreas; Skovgård, Troels Suhr; Kristensen, Philip Trøst

2008-01-01

We investigate the light-matter interaction of a quantum dot with the electromagnetic field in a lossy microcavity and calculate emission spectra for nonzero detuning and dephasing. It is found that dephasing shifts the intensity of the emission peaks for nonzero detuning. We investigate the char......We investigate the light-matter interaction of a quantum dot with the electromagnetic field in a lossy microcavity and calculate emission spectra for nonzero detuning and dephasing. It is found that dephasing shifts the intensity of the emission peaks for nonzero detuning. We investigate...

Multivariate curve resolution applied to infrared reflection measurements of soil contaminated with an organophosphorus analyte.

Science.gov (United States)

Gallagher, Neal B; Blake, Thomas A; Gassman, Paul L; Shaver, Jeremy M; Windig, Willem

2006-07-01

Multivariate curve resolution (MCR) is a powerful technique for extracting chemical information from measured spectra of complex mixtures. A modified MCR technique that utilized both measured and second-derivative spectra to account for observed sample-to-sample variability attributable to changes in soil reflectivity was used to estimate the spectrum of dibutyl phosphate (DBP) adsorbed on two different soil types. This algorithm was applied directly to measurements of reflection spectra of soils coated with analyte without resorting to soil preparations such as grinding or dilution in potassium bromide. The results provided interpretable spectra that can be used to guide strategies for detection and classification of organic analytes adsorbed on soil. Comparisons to the neat DBP liquid spectrum showed that the recovered analyte spectra from both soils showed spectral features from methyl, methylene, hydroxyl, and P=O functional groups, but most conspicuous was the absence of the strong PO-(CH2)3CH3 stretch absorption at 1033 cm(-1). These results are consistent with those obtained previously using extended multiplicative scatter correction.

Effects of a primordial magnetic field with log-normal distribution on the cosmic microwave background

International Nuclear Information System (INIS)

Yamazaki, Dai G.; Ichiki, Kiyotomo; Takahashi, Keitaro

2011-01-01

We study the effect of primordial magnetic fields (PMFs) on the anisotropies of the cosmic microwave background (CMB). We assume the spectrum of PMFs is described by log-normal distribution which has a characteristic scale, rather than power-law spectrum. This scale is expected to reflect the generation mechanisms and our analysis is complementary to previous studies with power-law spectrum. We calculate power spectra of energy density and Lorentz force of the log-normal PMFs, and then calculate CMB temperature and polarization angular power spectra from scalar, vector, and tensor modes of perturbations generated from such PMFs. By comparing these spectra with WMAP7, QUaD, CBI, Boomerang, and ACBAR data sets, we find that the current CMB data set places the strongest constraint at k≅10 -2.5 Mpc -1 with the upper limit B < or approx. 3 nG.

A proximal retarding field analyzer for scanning probe energy loss spectroscopy

Science.gov (United States)

Bauer, Karl; Murphy, Shane; Palmer, Richard E.

2017-03-01

A compact proximal retarding field analyzer for scanning probe energy loss spectroscopy measurements is described. Using the scanning tunneling microscope (STM) tip as a field emission (FE) electron source in conjunction with this analyzer, which is placed at a glancing angle to the surface plane, FE sample current and electron reflectivity imaging may be performed simultaneously. This is demonstrated in measurements of Ag nanostructures prepared on graphite by electron-beam lithography, where a material contrast of 13% is observed, with a lateral resolution of 25 nm, between the silver and graphite in electron reflectivity images. Topological contrast mechanisms such as edge enhancement and shadowing are also observed, giving rise to additional features in the electron reflectivity images. The same instrument configuration has been used to measure electron energy loss spectra on bare graphite, where the zero loss peak, π band plasmon loss peak and secondary electron peaks are observed. Using this simple and compact analyzer an STM, with sufficient open access to the tip-sample junction, may easily be augmented to provide simultaneous elemental and topographic mapping, supplementing STM image measurements with FE sample current and electron reflectivity images, as well as electron energy loss spectroscopy measurements, in the same instrument.

Identification of cattle, llama and horse meat by near infrared reflectance or transflectance spectroscopy.

Science.gov (United States)

Mamani-Linares, L W; Gallo, C; Alomar, D

2012-02-01

Visible and near infrared reflectance spectroscopy (VIS-NIRS) was used to discriminate meat and meat juices from three livestock species. In a first trial, samples of Longissimus lumborum muscle, corresponding to beef (31) llamas (21) and horses (27), were homogenised and their spectra collected in reflectance (NIRSystems 6500 scanning monochromator, in the range of 400-2500 nm). In the second trial, samples of meat juice (same muscle) from the same species (20 beef, 19 llama and 19 horse) were scanned in folded transmission (transflectance). Discriminating models (PLS regression) were developed against "dummy" variables, testing different mathematical treatments of the spectra. Best models indentified the species of almost all samples by their meat (reflectance) or meat juice (transflectance) spectra. A few (three of beef and one of llama, for meat samples; one of beef and one of horse, for juice samples) were classified as uncertain. It is concluded that NIRS is an effective tool to recognise meat and meat juice from beef, llama and horses. Copyright © 2011 Elsevier Ltd. All rights reserved.

Infrared reflectance studies of hillock-like porous zinc oxide thin films

International Nuclear Information System (INIS)

Ching, C.G.; Lee, S.C.; Ng, S.S.; Hassan, Z.; Abu Hassan, H.

2013-01-01

We investigated the infrared (IR) reflectance characteristics of hillock-like porous zinc oxide (ZnO) thin films on silicon substrates. The IR reflectance spectra of the porous samples exhibited an extra resonance hump in the reststrahlen region of ZnO compared with the as-grown sample. Oscillation fringes with different behaviors were also observed in the non-reststrahlen region of ZnO. Standard multilayer optic technique was used with the effective medium theory to analyze the observations. Results showed that the porous ZnO layer consisted of several sublayers with different porosities and thicknesses. These findings were confirmed by scanning electron microscopy measurements. - Highlights: • Multilayer porous assumption qualitatively increased the overall spectra fitting. • IR reflectance is a sensitive method to probe the multilayer porous structure. • Hillock-like porous ZnO thin films fabricated using electrochemical etching method. • The thickness and porosity of the samples were determined. • Formation of extra resonance hump was due to splitting of reststrahlen band

A library based fitting method for visual reflectance spectroscopy of human skin

International Nuclear Information System (INIS)

Verkruysse, Wim; Zhang Rong; Choi, Bernard; Lucassen, Gerald; Svaasand, Lars O; Nelson, J Stuart

2005-01-01

The diffuse reflectance spectrum of human skin in the visible region (400-800 nm) contains information on the concentrations of chromophores such as melanin and haemoglobin. This information may be extracted by fitting the reflectance spectrum with an optical diffusion based analytical expression applied to a layered skin model. With the use of the analytical expression, it is assumed that light transport is dominated by scattering. For port wine stain (PWS) and highly pigmented human skin, however, this assumption may not be valid resulting in a potentially large error in visual reflectance spectroscopy (VRS). Monte Carlo based techniques can overcome this problem but are currently too computationally intensive to be combined with previously used fitting procedures. The fitting procedure presented herein is based on a library search which enables the use of accurate reflectance spectra based on forward Monte Carlo simulations or diffusion theory. This allows for accurate VRS to characterize chromophore concentrations in PWS and highly pigmented human skin. The method is demonstrated using both simulated and measured reflectance spectra. An additional advantage of the method is that the fitting procedure is very fast

A library based fitting method for visual reflectance spectroscopy of human skin

Energy Technology Data Exchange (ETDEWEB)

Verkruysse, Wim [Beckman Laser Institute, University of California, Irvine, CA 92612 (United States); Zhang Rong [Beckman Laser Institute, University of California, Irvine, CA 92612 (United States); Choi, Bernard [Beckman Laser Institute, University of California, Irvine, CA 92612 (United States); Lucassen, Gerald [Personal Care Institute, Philips Research, Prof Holstlaan 4, Eindhoven (Netherlands); Svaasand, Lars O [Department of Physical Electronics Norwegian University of Science and Technology, N-7491 Trondheim (Norway); Nelson, J Stuart [Beckman Laser Institute, University of California, Irvine, CA 92612 (United States)

2005-01-07

The diffuse reflectance spectrum of human skin in the visible region (400-800 nm) contains information on the concentrations of chromophores such as melanin and haemoglobin. This information may be extracted by fitting the reflectance spectrum with an optical diffusion based analytical expression applied to a layered skin model. With the use of the analytical expression, it is assumed that light transport is dominated by scattering. For port wine stain (PWS) and highly pigmented human skin, however, this assumption may not be valid resulting in a potentially large error in visual reflectance spectroscopy (VRS). Monte Carlo based techniques can overcome this problem but are currently too computationally intensive to be combined with previously used fitting procedures. The fitting procedure presented herein is based on a library search which enables the use of accurate reflectance spectra based on forward Monte Carlo simulations or diffusion theory. This allows for accurate VRS to characterize chromophore concentrations in PWS and highly pigmented human skin. The method is demonstrated using both simulated and measured reflectance spectra. An additional advantage of the method is that the fitting procedure is very fast.

A library based fitting method for visual reflectance spectroscopy of human skin

Science.gov (United States)

Verkruysse, Wim; Zhang, Rong; Choi, Bernard; Lucassen, Gerald; Svaasand, Lars O.; Nelson, J. Stuart

2005-01-01

The diffuse reflectance spectrum of human skin in the visible region (400-800 nm) contains information on the concentrations of chromophores such as melanin and haemoglobin. This information may be extracted by fitting the reflectance spectrum with an optical diffusion based analytical expression applied to a layered skin model. With the use of the analytical expression, it is assumed that light transport is dominated by scattering. For port wine stain (PWS) and highly pigmented human skin, however, this assumption may not be valid resulting in a potentially large error in visual reflectance spectroscopy (VRS). Monte Carlo based techniques can overcome this problem but are currently too computationally intensive to be combined with previously used fitting procedures. The fitting procedure presented herein is based on a library search which enables the use of accurate reflectance spectra based on forward Monte Carlo simulations or diffusion theory. This allows for accurate VRS to characterize chromophore concentrations in PWS and highly pigmented human skin. The method is demonstrated using both simulated and measured reflectance spectra. An additional advantage of the method is that the fitting procedure is very fast.

Temperature-reflection I

DEFF Research Database (Denmark)

McGady, David A.

2017-01-01

-temperature path integrals for quantum field theories (QFTs) should be T-reflection invariant. Because multi-particle partition functions are equal to Euclidean path integrals for QFTs, we expect them to be T-reflection invariant. Single-particle partition functions though are often not invariant under T......In this paper, we revisit the claim that many partition functions are invariant under reflecting temperatures to negative values (T-reflection). The goal of this paper is to demarcate which partition functions should be invariant under T-reflection, and why. Our main claim is that finite...... that T-reflection is unrelated to time-reversal. Finally, we study the interplay between T-reflection and perturbation theory in the anharmonic harmonic oscillator in quantum mechanics and in Yang-Mills in four-dimensions. This is the first in a series of papers on temperature-reflections....

Non-destructive quality evaluation of pepper (Capsicum annuum L.) seeds using LED-induced hyperspectral reflectance imaging

Science.gov (United States)

In this study, we develop a viability evaluation method for pepper (Capsicum annuum L.) seed based on hyperspectral reflectance imaging. The reflectance spectra of pepper seeds in the 400–700 nm range are collected from hyperspectral reflectance images obtained using blue, green, and red LED illumin...

An assessment of thin cloud detection by applying bidirectional reflectance distribution function model-based background surface reflectance using Geostationary Ocean Color Imager (GOCI): A case study for South Korea

Science.gov (United States)

Kim, Hye-Won; Yeom, Jong-Min; Shin, Daegeun; Choi, Sungwon; Han, Kyung-Soo; Roujean, Jean-Louis

2017-08-01

In this study, a new assessment of thin cloud detection with the application of bidirectional reflectance distribution function (BRDF) model-based background surface reflectance was undertaken by interpreting surface spectra characterized using the Geostationary Ocean Color Imager (GOCI) over a land surface area. Unlike cloud detection over the ocean, the detection of cloud over land surfaces is difficult due to the complicated surface scattering characteristics, which vary among land surface types. Furthermore, in the case of thin clouds, in which the surface and cloud radiation are mixed, it is difficult to detect the clouds in both land and atmospheric fields. Therefore, to interpret background surface reflectance, especially underneath cloud, the semiempirical BRDF model was used to simulate surface reflectance by reflecting solar angle-dependent geostationary sensor geometry. For quantitative validation, Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observation (CALIPSO) data were used to make a comparison with the proposed cloud masking result. As a result, the new cloud masking scheme resulted in a high probability of detection (POD = 0.82) compared with the Moderate Resolution Imaging Spectroradiometer (MODIS) (POD = 0.808) for all cloud cases. In particular, the agreement between the CALIPSO cloud product and new GOCI cloud mask was over 94% when detecting thin cloud (e.g., altostratus and cirrus) from January 2014 to June 2015. This result is relatively high in comparison with the result from the MODIS Collection 6 cloud mask product (MYD35).

Measurement and modelization of silica opal reflection properties: Optical determination of the silica index

Science.gov (United States)

Avoine, Amaury; Hong, Phan Ngoc; Frederich, Hugo; Frigerio, Jean-Marc; Coolen, Laurent; Schwob, Catherine; Nga, Pham Thu; Gallas, Bruno; Maître, Agnès

2012-10-01

Self-assembled artificial opals (in particular silica opals) constitute a model system to study the optical properties of three-dimensional photonic crystals. The silica optical index is a key parameter to correctly describe an opal but is difficult to measure at the submicrometer scale and usually treated as a free parameter. Here, we propose a method to extract the silica index from the opal reflection spectra and we validate it by comparison with two independent methods based on infrared measurements. We show that this index gives a correct description of the opal reflection spectra, either by a band structure or by a Bragg approximation. In particular, we are able to provide explanations in quantitative agreement with the measurements for two features : the observation of a second reflection peak in specular direction, and the quasicollapse of the p-polarized main reflection peak at a typical angle of 54∘.

Laser Sensing of Vegetation Based on Dual Spectrum Measurements of Reflection Coefficients

Directory of Open Access Journals (Sweden)

M. L. Belov

2017-01-01

Full Text Available Currently, a promising trend in remote sensing of environment is to monitor the vegetative cover: evaluate the productivity of agricultural crops; evaluate the moisture content of soils and the state of ecosystems; provide mapping the sites of bogging, desertification, drought, etc.; control the phases of vegetation of crops, etc.Development of monitoring systems for remote detection of vegetation sites being under unfavorable conditions (low or high temperature, excess or lack of water, soil salinity, disease, etc. is of relevance. Optical methods are the most effective for this task. These methods are based on the physical features of reflection spectra in the visible and near infrared spectral range for vegetation under unfavorable conditions and vegetation under normal conditions.One of the options of optoelectronic equipment for monitoring vegetation condition is laser equipment that allows remote sensing of vegetation from the aircraft and mapping of vegetation sites with abnormal (inactive periods of vegetation reflection spectra with a high degree of spatial resolution.The paper deals with development of a promising dual-spectrum method for laser remote sensing of vegetation. Using the experimentally measured reflection spectra of different vegetation types, mathematical modeling of probability for appropriate detection and false alarms to solve a problem of detecting the vegetation under unfavorable conditions (with abnormal reflection spectra is performed based on the results of dual-spectrum measurements of the reflection coefficient.In mathematical modeling, the lidar system was supposed to provide sensing at wavelengths of 0.532 μm and 0.85 μm. The noise of the measurement was supposed to be normal with zero mean value and mean-square value of 1% -10%.It is shown that the method of laser sensing of vegetation condition based on the results of dual-spectrum measurement of the reflection coefficient at wavelengths of 0.532 μm and 0

RESEARCH OF THE ENTRANCE ANGLE EFFECT ON THE REFLECTANCE SPECTRA OF THE STAINLESS STEEL SURFACE OXIDIZED BY PULSED LASER RADIATION

Directory of Open Access Journals (Sweden)

V. P. Veiko

2016-05-01

Full Text Available Subject of Research.Oxide films on the metal surfaces can be obtained both by surface-uniform infrared heating and local laser treatment e.g. by sequence of nanosecond laser pulses. Due to interference in created films the coloration of treated area is observed. The present work shows the results of spectrophotometric measurements for various light entrance angles in the range of 10-60°. Method. AISI 304 stainless steel plates were oxidized by two methods: in muffle furnace FM - 10 (Т= 500-600° С, t = 5-7 min. and at line-by-line scanning by sequence of nanosecond laser pulses (λ = 1.06 μm, τ =100 ns, r = 25 μm,q=2.91∙107 W/cm2, Nx = 30, Ny = 1. Surface research in optical resolution was realized by Carl Zeiss Axio Imager A1M. Reflectance spectra were obtained with spectrophotometer Lambda Perkin 1050 with integrating sphere at different fixed light incidence angles. Topographic features were detected by scanning probe microscopy investigation with NanoEducator equipment. Main Results. The quantitative surface geometry characteristics of AISI 304 stainless steel patterns treated by different methods are obtained. It was found that the increase of light entrance angle has no influence on the form of reflection coefficient dependence from a wavelength, but a blue-shift occurs especially for the case of laser treatment. This difference can be caused by surface topology formed by laser heating and variety of oxide film thickness. This effect results in more significant change in observed sample color for laser treatment then for infrared heating. Practical Relevance. The results obtained in the present work can be used to implement a new element of product protection against forgery with the product marking.

VizieR Online Data Catalog: Sulamitis and Clarissa asteroids spectra (Morate+, 2018)

Science.gov (United States)

Morate, D.; de, Leon J.; de Pra, M.; Licandro, J.; Cabrera-Lavers, A.; Campins, H.; Pinilla-Alonso, N.

2017-11-01

A total of 97 low-resolution visible spectra were obtained for the asteroids in the Sulamitis and Clarissa families (64 and 33 objects, respectively), using the Optical System for Imaging and Low Resolution Integrated Spectroscopy (OSIRIS) camera spectrograph at the 10.4m Gran Telescopio Canarias (GTC), located at the El Roque de los Muchachos Observatory (ORM) in La Palma, Canary Islands, Spain. In addition, we obtained three spectra of (752) Sulamitis using the Intermediate Dispersion Spectrograph (IDS) at the 2.5m Isaac Newton Telescope, also located at the ORM in La Palma, as part of program C97 (2015), on July 22, 2015. All the spectra files included here are named ast_ASTEROIDNUMBER.txt, except for the spectra of (752) taken with the INT (named ast752INT.txt). The first column is the wavelength, expressed in microns, and the second column is the reflectance value (which is normalized at 1 at 0.55 microns). (3 data files).

Non-invasive identification of metal-oxalate complexes on polychrome artwork surfaces by reflection mid-infrared spectroscopy.

Science.gov (United States)

Monico, Letizia; Rosi, Francesca; Miliani, Costanza; Daveri, Alessia; Brunetti, Brunetto G

2013-12-01

In this work a reflection mid-infrared spectroscopy study of twelve metal-oxalate complexes, of interest in art conservation science as alteration compounds, was performed. Spectra of the reference materials highlighted the presence of derivative-like and/or inverted features for the fundamental vibrational modes as result of the main contribution from the surface component of the reflected light. In order to provide insights in the interpretation of theses spectral distortions, reflection spectra were compared with conventional transmission ones. The Kramers-Kronig (KK) algorithm, employed to correct for the surface reflection distortions, worked properly only for the derivative-like bands. Therefore, to pay attention to the use of this algorithm when interpreting the reflection spectra is recommended. The outcome of this investigation was exploited to discriminate among different oxalates on thirteen polychrome artworks analyzed in situ by reflection mid-infrared spectroscopy. The visualization of the νs(CO) modes (1400-1200 cm(-1)) and low wavenumber bands (below 900 cm(-1)) in the raw reflection profiles allowed Ca, Cu and Zn oxalates to be identified. Further information about the speciation of different hydration forms of calcium oxalates were obtained by using the KK transform. The work proves reflection mid-infrared spectroscopy to be a reliable and sensitive spectro-analytical method for identifying and mapping different metal-oxalate alteration compounds on the surface of artworks, thus providing conservation scientists with a non-invasive tool to obtain information on the state of conservation and causes of alteration of artworks. Copyright © 2013 Elsevier B.V. All rights reserved.

EVOLUTION OF MAGNETIC HELICITY AND ENERGY SPECTRA OF SOLAR ACTIVE REGIONS

International Nuclear Information System (INIS)

Zhang, Hongqi; Brandenburg, Axel; Sokoloff, D. D.

2016-01-01

We adopt an isotropic representation of the Fourier-transformed two-point correlation tensor of the magnetic field to estimate the magnetic energy and helicity spectra as well as current helicity spectra of two individual active regions (NOAA 11158 and NOAA 11515) and the change of the spectral indices during their development as well as during the solar cycle. The departure of the spectral indices of magnetic energy and current helicity from 5/3 are analyzed, and it is found that it is lower than the spectral index of the magnetic energy spectrum. Furthermore, the fractional magnetic helicity tends to increase when the scale of the energy-carrying magnetic structures increases. The magnetic helicity of NOAA 11515 violates the expected hemispheric sign rule, which is interpreted as an effect of enhanced field strengths at scales larger than 30–60 Mm with opposite signs of helicity. This is consistent with the general cycle dependence, which shows that around the solar maximum the magnetic energy and helicity spectra are steeper, emphasizing the large-scale field

EVOLUTION OF MAGNETIC HELICITY AND ENERGY SPECTRA OF SOLAR ACTIVE REGIONS

Energy Technology Data Exchange (ETDEWEB)

Zhang, Hongqi [Key Laboratory of Solar Activity, National Astronomical Observatories, Chinese Academy of Sciences, Beijing 100012 (China); Brandenburg, Axel [Nordita, KTH Royal Institute of Technology and Stockholm University, Roslagstullsbacken 23, SE-10691 Stockholm (Sweden); Sokoloff, D. D., E-mail: hzhang@bao.ac.cn [Department of Physics, Moscow University, 119992 Moscow (Russian Federation)

2016-03-10

We adopt an isotropic representation of the Fourier-transformed two-point correlation tensor of the magnetic field to estimate the magnetic energy and helicity spectra as well as current helicity spectra of two individual active regions (NOAA 11158 and NOAA 11515) and the change of the spectral indices during their development as well as during the solar cycle. The departure of the spectral indices of magnetic energy and current helicity from 5/3 are analyzed, and it is found that it is lower than the spectral index of the magnetic energy spectrum. Furthermore, the fractional magnetic helicity tends to increase when the scale of the energy-carrying magnetic structures increases. The magnetic helicity of NOAA 11515 violates the expected hemispheric sign rule, which is interpreted as an effect of enhanced field strengths at scales larger than 30–60 Mm with opposite signs of helicity. This is consistent with the general cycle dependence, which shows that around the solar maximum the magnetic energy and helicity spectra are steeper, emphasizing the large-scale field.

Impact of one-layer assumption on diffuse reflectance spectroscopy of skin

Science.gov (United States)

Hennessy, Ricky; Markey, Mia K.; Tunnell, James W.

2015-02-01

Diffuse reflectance spectroscopy (DRS) can be used to noninvasively measure skin properties. To extract skin properties from DRS spectra, you need a model that relates the reflectance to the tissue properties. Most models are based on the assumption that skin is homogenous. In reality, skin is composed of multiple layers, and the homogeneity assumption can lead to errors. In this study, we analyze the errors caused by the homogeneity assumption. This is accomplished by creating realistic skin spectra using a computational model, then extracting properties from those spectra using a one-layer model. The extracted parameters are then compared to the parameters used to create the modeled spectra. We used a wavelength range of 400 to 750 nm and a source detector separation of 250 μm. Our results show that use of a one-layer skin model causes underestimation of hemoglobin concentration [Hb] and melanin concentration [mel]. Additionally, the magnitude of the error is dependent on epidermal thickness. The one-layer assumption also causes [Hb] and [mel] to be correlated. Oxygen saturation is overestimated when it is below 50% and underestimated when it is above 50%. We also found that the vessel radius factor used to account for pigment packaging is correlated with epidermal thickness.

Derivation of the radial profile of ion temperature from the 'measured' energy spectra of charge-exchanged neutrals

International Nuclear Information System (INIS)

Nakamura, Kazuo; Hiraki, Naoji; Toi, Kazuo; Itoh, Satoshi

1980-01-01

In the TRIAM-1 tokamak the energy spectra of charge-exchanged neutrals are observed by scanning the neutral energy analyzer vertically. The ''measured'' ion temperature obtained from only energy spectrum observed in the peripheral region is much higher than that predicted by the neoclassical transport theory because of reflection (backscattering) of neutrals at the wall. The ''actual'' ion temperature profile is derived from all observed energy spectra by using the numerical code in which a wall-reflection effect of neutrals and an impermeability of plasma are taken into account. In this numerical analysis, the reflection coefficient is adjusted so that the above calculated ion temperature profile should be best fit for the ion temperatures measured by the Doppler broadening of the visible lines HeII 4686 A and H sub(α) at the relevant radial positions. (author)

Derivation of the radial profile of ion temperature from the 'measured' energy spectra of charge-exchanged neutrals

Energy Technology Data Exchange (ETDEWEB)

Nakamura, K; Hiraki, N; Toi, K; Itoh, S [Kyushu Univ., Fukuoka (Japan). Research Inst. for Applied Mechanics

1980-07-01

In the TRIAM-1 tokamak the energy spectra of charge-exchanged neutrals are observed by scanning the neutral energy analyzer vertically. The ''measured'' ion temperature obtained from only energy spectrum observed in the peripheral region is much higher than that predicted by the neoclassical transport theory because of reflection (backscattering) of neutrals at the wall. The ''actual'' ion temperature profile is derived from all observed energy spectra by using the numerical code in which a wall-reflection effect of neutrals and an impermeability of plasma are taken into account. In this numerical analysis, the reflection coefficient is adjusted so that the above calculated ion temperature profile should be best fit for the ion temperatures measured by the Doppler broadening of the visible lines HeII 4686 A and H sub(..cap alpha..) at the relevant radial positions.

Characterization of reflectance variability in the industrial paint application of automotive metallic coatings by using principal component analysis

Science.gov (United States)

Medina, José M.; Díaz, José A.

2013-05-01

We have applied principal component analysis to examine trial-to-trial variability of reflectances of automotive coatings that contain effect pigments. Reflectance databases were measured from different color batch productions using a multi-angle spectrophotometer. A method to classify the principal components was used based on the eigenvalue spectra. It was found that the eigenvalue spectra follow distinct power laws and depend on the detection angle. The scaling exponent provided an estimation of the correlation between reflectances and it was higher near specular reflection, suggesting a contribution from the deposition of effect pigments. Our findings indicate that principal component analysis can be a useful tool to classify different sources of spectral variability in color engineering.

Total internal reflection effect on gyrotropic interface

Science.gov (United States)

Glushchenko, Alexander G.; Glushchenko, Eugene P.; Zhukov, Sergey V.

2018-02-01

This article considers the physical features of total internal reflection at gyrotropic and isotropic interfaces for two cases: electrical gyrotropy (plasma) and magnetic gyrotropy (ferrite). It is shown that the plasma magnetization may lead to the formation of the total internal reflection effect, which does not occur in isotropic plasma. The threshold values of the magnetic field, which are necessary for the total internal reflection effect, are determined. The total internal reflection effect on a ferrite-dielectric interface for waves emanating from different angles is observed in various frequency ranges and magnetization fields. The study points out the possibility of changing the total internal reflection angle value in large limits due to a change in the external magnetic field magnitude. The calculation results of the total internal reflection angle dependence on the external magnetic field magnitude are presented. The formulas are elaborated for calculating the total internal reflection angles of different interfaces for gyrotropic and isotropic media. The generalized formulas are defined for calculating the Doppler effect in the gyrotropic media. The study demonstrates how the velocity of the media interface affects the limiting angle of total internal refection.

Spectral distribution of particle fluence in small field detectors and its implication on small field dosimetry.

Science.gov (United States)

Benmakhlouf, Hamza; Andreo, Pedro

2017-02-01

Correction factors for the relative dosimetry of narrow megavoltage photon beams have recently been determined in several publications. These corrections are required because of the several small-field effects generally thought to be caused by the lack of lateral charged particle equilibrium (LCPE) in narrow beams. Correction factors for relative dosimetry are ultimately necessary to account for the fluence perturbation caused by the detector. For most small field detectors the perturbation depends on field size, resulting in large correction factors when the field size is decreased. In this work, electron and photon fluence differential in energy will be calculated within the radiation sensitive volume of a number of small field detectors for 6 MV linear accelerator beams. The calculated electron spectra will be used to determine electron fluence perturbation as a function of field size and its implication on small field dosimetry analyzed. Fluence spectra were calculated with the user code PenEasy, based on the PENELOPE Monte Carlo system. The detectors simulated were one liquid ionization chamber, two air ionization chambers, one diamond detector, and six silicon diodes, all manufactured either by PTW or IBA. The spectra were calculated for broad (10 cm × 10 cm) and narrow (0.5 cm × 0.5 cm) photon beams in order to investigate the field size influence on the fluence spectra and its resulting perturbation. The photon fluence spectra were used to analyze the impact of absorption and generation of photons. These will have a direct influence on the electrons generated in the detector radiation sensitive volume. The electron fluence spectra were used to quantify the perturbation effects and their relation to output correction factors. The photon fluence spectra obtained for all detectors were similar to the spectrum in water except for the shielded silicon diodes. The photon fluence in the latter group was strongly influenced, mostly in the low-energy region, by

Near-field reflection backscattering apertureless optical microscopy: Application to spectroscopy experiments on opaque samples, comparison between lock-in and digital photon counting detection techniques

International Nuclear Information System (INIS)

Diziain, S.; Bijeon, J.-L.; Adam, P.-M.; Lamy de la Chapelle, M.; Thomas, B.; Deturche, R.; Royer, P.

2007-01-01

An apertureless scanning near-field optical microscope (ASNOM) in reflection backscattering configuration is designed to conduct spectroscopic experiments on opaque samples constituted of latex beads. The ASNOM proposed takes advantage of the depth-discrimination properties of confocal microscopes to efficiently extract the near-field optical signal. Given their importance in a spectroscopic experiment, we systematically compare the lock-in and synchronous photon counting detection methods. Some results of Rayleigh's scattering in the near field of the test samples are used to illustrate the possibilities of this technique for reflection backscattering spectroscopy

Near-field reflection backscattering apertureless optical microscopy: Application to spectroscopy experiments on opaque samples, comparison between lock-in and digital photon counting detection techniques

Energy Technology Data Exchange (ETDEWEB)

Diziain, S. [Institut Charles Delaunay, CNRS FRE 2848, Laboratoire de Nanotechnologie et d' Instrumentation Optique, Universite de technologie de Troyes, 12 rue Marie Curie, BP 2060, 10010 Troyes cedex (France); Bijeon, J.-L. [Institut Charles Delaunay, CNRS FRE 2848, Laboratoire de Nanotechnologie et d' Instrumentation Optique, Universite de technologie de Troyes, 12 rue Marie Curie, BP 2060, 10010 Troyes cedex (France)]. E-mail: bijeon@utt.fr; Adam, P.-M. [Institut Charles Delaunay, CNRS FRE 2848, Laboratoire de Nanotechnologie et d' Instrumentation Optique, Universite de technologie de Troyes, 12 rue Marie Curie, BP 2060, 10010 Troyes cedex (France); Lamy de la Chapelle, M. [Institut Charles Delaunay, CNRS FRE 2848, Laboratoire de Nanotechnologie et d' Instrumentation Optique, Universite de technologie de Troyes, 12 rue Marie Curie, BP 2060, 10010 Troyes cedex (France); Thomas, B. [Institut Charles Delaunay, CNRS FRE 2848, Laboratoire de Nanotechnologie et d' Instrumentation Optique, Universite de technologie de Troyes, 12 rue Marie Curie, BP 2060, 10010 Troyes cedex (France); Deturche, R. [Institut Charles Delaunay, CNRS FRE 2848, Laboratoire de Nanotechnologie et d' Instrumentation Optique, Universite de technologie de Troyes, 12 rue Marie Curie, BP 2060, 10010 Troyes cedex (France); Royer, P. [Institut Charles Delaunay, CNRS FRE 2848, Laboratoire de Nanotechnologie et d' Instrumentation Optique, Universite de technologie de Troyes, 12 rue Marie Curie, BP 2060, 10010 Troyes cedex (France)

2007-01-15

An apertureless scanning near-field optical microscope (ASNOM) in reflection backscattering configuration is designed to conduct spectroscopic experiments on opaque samples constituted of latex beads. The ASNOM proposed takes advantage of the depth-discrimination properties of confocal microscopes to efficiently extract the near-field optical signal. Given their importance in a spectroscopic experiment, we systematically compare the lock-in and synchronous photon counting detection methods. Some results of Rayleigh's scattering in the near field of the test samples are used to illustrate the possibilities of this technique for reflection backscattering spectroscopy.

REFLECTIVE LEARNING IN SOCIAL WORK EDUCATION IN THE FIELD OF SUBSTANCE ABUSE

Directory of Open Access Journals (Sweden)

Slabbert, Ilze

2015-11-01

Full Text Available is very much part of social work education. A qualitative study was proposed with final-year social work students at a selected university in South Africa doing a course in the field of substance abuse. The participants completed a reflective exercise on abstaining from an aspect/habit/substance in their own lives for three weeks. Six themes emerged, namely abstinence from: depressants, stimulants, opioids, food, social media and bad habits. Findings indicated that students gained an insight into possible harmful patterns in their own lives as well as into the complexity of life-long abstinence in prospective clients’ lives. Recommendations are provided for social work education, practice and research.

Dynamics and fluctuation spectra of electrostatic resistive interchange turbulence

International Nuclear Information System (INIS)

Sydora, R.D.; Leboeuf, J.N.; An, Z.G.; Diamond, P.H.; Lee, G.S.; Hahm, T.S.

1985-11-01

The saturation mechanism for density and potential fluctuation spectra which evolve from linearly unstable electrostatic resistive interchange modes, are investigated using particle simulations. Detailed comparisons of the nonlinear evolution, saturation levels and resultant spectra between two- and three-dimensional sheared magnetic field configurations are made. Significant differences appear. The single rational surface, quasilinear-dominated evolution, fluctuation spectrum is adequately described using a density convection model. For the multiple rational surface case, the potential fluctuations are adequately represented by a balance between the nonlinearly modified source (curvature drive) and linear sink (parallel resistive field line diffusion). An accurate description of the density spectrum requires a mode coupling theory based on the two-point density correlation evolution equation. 24 refs., 15 figs

Absorption spectra analysis of hydrated uranium(III) complex chlorides

Science.gov (United States)

Karbowiak, M.; Gajek, Z.; Drożdżyński, J.

2000-11-01

Absorption spectra of powdered samples of hydrated uranium(III) complex chlorides of the formulas NH 4UCl 4 · 4H 2O and CsUCl 4 · 3H 2O have been recorded at 4.2 K in the 4000-26 000 cm -1 range. The analysis of the spectra enabled the determination of crystal-field parameters and assignment of 83 and 77 crystal-field levels for the tetrahydrate and trihydrate, respectively. The energies of the levels were computed by applying a simplified angular overlap model as well as a semiempirical Hamiltonian representing the combined atomic and crystal-field interactions. Ab initio calculations have enabled the application of a simplified parameterization and the determination of the starting values of the AOM parameters. The received results have proved that the AOM approach can quite well predict both the structure of the ground multiplet and the positions of the crystal-field levels in the 17 000-25 000 cm -1 range, usually obscured by strong f-d bands.

TURBULENCE IN THE SUB-ALFVENIC SOLAR WIND DRIVEN BY REFLECTION OF LOW-FREQUENCY ALFVEN WAVES

International Nuclear Information System (INIS)

Verdini, A.; Velli, M.; Buchlin, E.

2009-01-01

We study the formation and evolution of a turbulent spectrum of Alfven waves driven by reflection off the solar wind density gradients, starting from the coronal base up to 17 solar radii, well beyond the Alfvenic critical point. The background solar wind is assigned and two-dimensional shell models are used to describe nonlinear interactions. We find that the turbulent spectra are influenced by the nature of the reflected waves. Close to the base, these give rise to a flatter and steeper spectrum for the outgoing and reflected waves, respectively. At higher heliocentric distance both spectra evolve toward an asymptotic Kolmogorov spectrum. The turbulent dissipation is found to account for at least half of the heating required to sustain the background imposed solar wind and its shape is found to be determined by the reflection-determined turbulent heating below 1.5 solar radii. Therefore, reflection and reflection-driven turbulence are shown to play a key role in the acceleration of the fast solar wind and origin of the turbulent spectrum found at 0.3 AU in the heliosphere.

Reflective thinking in solving an algebra problem: a case study of field independent-prospective teacher

Science.gov (United States)

Agustan, S.; Juniati, Dwi; Yuli Eko Siswono, Tatag

2017-10-01

Nowadays, reflective thinking is one of the important things which become a concern in learning mathematics, especially in solving a mathematical problem. The purpose of this paper is to describe how the student used reflective thinking when solved an algebra problem. The subject of this research is one female student who has field independent cognitive style. This research is a descriptive exploratory study with data analysis using qualitative approach to describe in depth reflective thinking of prospective teacher in solving an algebra problem. Four main categories are used to analyse the reflective thinking in solving an algebra problem: (1) formulation and synthesis of experience, (2) orderliness of experience, (3) evaluating the experience and (4) testing the selected solution based on the experience. The results showed that the subject described the problem by using another word and the subject also found the difficulties in making mathematical modelling. The subject analysed two concepts used in solving problem. For instance, geometry related to point and line while algebra is related to algebra arithmetic operation. The subject stated that solution must have four aspect to get effective solution, specifically the ability to (a) understand the meaning of every words; (b) make mathematical modelling; (c) calculate mathematically; (d) interpret solution obtained logically. To test the internal consistency or error in solution, the subject checked and looked back related procedures and operations used. Moreover, the subject tried to resolve the problem in a different way to compare the answers which had been obtained before. The findings supported the assertion that reflective thinking provides an opportunity for the students in improving their weakness in mathematical problem solving. It can make a grow accuracy and concentration in solving a mathematical problem. Consequently, the students will get the right and logic answer by reflective thinking.

Shifting Sands: Reflections from the Field of Higher Education.

Science.gov (United States)

Harrison, Barbara

2001-01-01

Discusses the benefits of reflection in higher education, highlighting one academic's reflections on herself as a woman in academia and how the attitudes she learned during her childhood and youth created problems during her own higher education and in her work as an academic. Also looks at educational discrimination against other minority groups.…

Portable microcomputer unit for the analysis of plutonium gamma-ray spectra

International Nuclear Information System (INIS)

Ruhter, W.D.; Camp, D.C.

1981-10-01

A portable microcomputer has been developed for the IAEA to perform in-field analysis of plutonium gamma-ray spectra. The unit includes a 16-bit LSI-11/2 microprocessor, 32K words of memory, a 20-character display for user prompting, and a 20-character thermal printer for hardcopy output. Only the positions of the 148-keV Pu-241 and 208-keV U-237 peaks are required for spectral analysis. The unit was tested against gamma-ray spectra taken of NBS plutonium standards and IAEA spectra. Results obtained are presented

The coherence and spectra of a Bose condensate generated by an atomic laser

International Nuclear Information System (INIS)

Kozlovskii, A.V.

2003-01-01

The first-order coherence dynamics of a Bose condensate generated by a cw atomic laser with evaporative cooling is analyzed. For the atomic-laser multimode model, the coherence functions and atomic field spectra are calculated by the master equation technique. Elastic collisions in the trapped atomic gas lead to significant broadening of the atomic laser line, a shift of its center, and a multi peak structure of the spectra. The oscillatory time dynamics of the atomic-field coherence function is studied. For the atomic laser, the free phase diffusion of the field typical of optical lasers, and characterized by monotonically decreasing mean field with a constant mean phase, is absent due to elastic collisions

Electric field-induced ferromagnetic resonance in a CoFeB/MgO magnetic tunnel junction under dc bias voltages

Science.gov (United States)

Kanai, Shun; Gajek, Martin; Worledge, D. C.; Matsukura, Fumihiro; Ohno, Hideo

2014-12-01

We measure homodyne-detected ferromagnetic resonance (FMR) induced by the electric-field effect in a CoFeB/MgO/CoFeB magnetic tunnel junction (MTJ) with perpendicular magnetic easy axis under dc bias voltages up to 0.1 V. From the bias dependence of the resonant frequency, we find that the first order perpendicular magnetic anisotropy is modulated by the applied electric field, whereas the second order component is virtually independent of the electric field. The lineshapes of the FMR spectra are bias dependent, which are explained by the combination of electric-field effect and reflection of the bias voltage from the MTJ.

Influence of aerosols, clouds, and sunglint on polarization spectra of Earthshine

Science.gov (United States)

Emde, Claudia; Buras-Schnell, Robert; Sterzik, Michael; Bagnulo, Stefano

2017-08-01

Context. Ground-based observations of the Earthshine, I.e., the light scattered by Earth to the Moon, and then reflected back to Earth, simulate space observations of our planet and represent a powerful benchmark for the studies of Earth-like planets. Earthshine spectra are strongly linearly polarized, owing to scattering by molecules and small particles in the atmosphere of the Earth and surface reflection, and may allow us to measure global atmospheric and surface properties of planet Earth. Aims: We aim to interpret already published spectropolarimetric observations of the Earthshine by comparing them with new radiative transfer model simulations including a fully realistic three-dimensional (3D) surface-atmosphere model for planet Earth. Methods: We used the highly advanced Monte Carlo radiative transfer model MYSTIC to simulate polarized radiative transfer in the atmosphere of the Earth without approximations regarding the geometry, taking into account the polarization from surface reflection and multiple scattering by molecules, aerosol particles, cloud droplets, and ice crystals. Results: We have shown that Earth spectropolarimetry is highly sensitive to all these input parameters, and we have presented simulations of a fully realistic Earth atmosphere-surface model including 3D cloud fields and two-dimensional (2D) surface property maps. Our modeling results show that scattering in high ice water clouds and reflection from the ocean surface are crucial to explain the continuum polarization at longer wavelengths as has been reported in Earthshine observations taken at the Very Large Telescope in 2011 (3.8% and 6.6% at 800 nm, depending on which part of Earth was visible from the Moon at the time of the observations). We found that the relatively high degree of polarization of 6.6% can be attributed to light reflected by the ocean surface in the sunglint region. High ice-water clouds reduce the amount of absorption in the O2A band and thus explain the weak O2

Generation of synthetic gamma spectra with MATLAB

International Nuclear Information System (INIS)

Palmerio, Julian J.; Coppo, Anibal D.

2009-01-01

Objectives: The aim of this work is the simulation of gamma spectra using the MATLAB program to generate the calibration curves in efficiency, which will be used to measure radioactive waste in drums. They are necessary for the proper characterization of these drums. A Monte Carlo simulation was basically developed with the random number generator Mersenne Twister and nuclear data obtained from NIST. This paper shows the results obtained and difficulties encountered until today. The physical correction of the simulated spectra has been the only aspect we have been working, up to this moment. Procedures: A simplified representation of the 'Laboratorio de Verificacion y Control de la Calidad' was chosen. Drums with cemented liquid waste are routinely measured in this laboratory. The commercial program MCNP was also used to get a valid reference in the field of simulation of spectra. We analyzed the spectra obtained by MATLAB in the light of classical literature photon detection and the spectrum obtained by MCNP. Conclusions: Currently the program developed seems adequate to simulate a measurement in the 'Laboratorio de Verificacion y Control de la Calidad'. The spectra obtained by MATLAB seem to physically represent what is observed in real spectra. However, it is a slow program. The current development efforts are directed to improve the speed of simulation. An alternative is to use the CUDA language for NVIDIA video cards to parallelized the simulation. An adequate simulation of the electronic measuring chain is also needed to obtain better representations of the shapes of the peaks. (author)

Resonant Inverse Compton Scattering Spectra from Highly Magnetized Neutron Stars

Science.gov (United States)

Wadiasingh, Zorawar; Baring, Matthew G.; Gonthier, Peter L.; Harding, Alice K.

2018-02-01

Hard, nonthermal, persistent pulsed X-ray emission extending between 10 and ∼150 keV has been observed in nearly 10 magnetars. For inner-magnetospheric models of such emission, resonant inverse Compton scattering of soft thermal photons by ultrarelativistic charges is the most efficient production mechanism. We present angle-dependent upscattering spectra and pulsed intensity maps for uncooled, relativistic electrons injected in inner regions of magnetar magnetospheres, calculated using collisional integrals over field loops. Our computations employ a new formulation of the QED Compton scattering cross section in strong magnetic fields that is physically correct for treating important spin-dependent effects in the cyclotron resonance, thereby producing correct photon spectra. The spectral cutoff energies are sensitive to the choices of observer viewing geometry, electron Lorentz factor, and scattering kinematics. We find that electrons with energies ≲15 MeV will emit most of their radiation below 250 keV, consistent with inferred turnovers for magnetar hard X-ray tails. More energetic electrons still emit mostly below 1 MeV, except for viewing perspectives sampling field-line tangents. Pulse profiles may be singly or doubly peaked dependent on viewing geometry, emission locale, and observed energy band. Magnetic pair production and photon splitting will attenuate spectra to hard X-ray energies, suppressing signals in the Fermi-LAT band. The resonant Compton spectra are strongly polarized, suggesting that hard X-ray polarimetry instruments such as X-Calibur, or a future Compton telescope, can prove central to constraining model geometry and physics.

Spectra of turbulent static pressure fluctuations in jet mixing layers

Science.gov (United States)

Jones, B. G.; Adrian, R. J.; Nithianandan, C. K.; Planchon, H. P., Jr.

1977-01-01

Spectral similarity laws are derived for the power spectra of turbulent static pressure fluctuations by application of dimensional analysis in the limit of large turbulent Reynolds number. The theory predicts that pressure spectra are generated by three distinct types of interaction in the velocity fields: a fourth order interaction between fluctuating velocities, an interaction between the first order mean shear and the third order velocity fluctuations, and an interaction between the second order mean shear rate and the second order fluctuating velocity. Measurements of one-dimensional power spectra of the turbulent static pressure fluctuations in the driven mixing layer of a subsonic, circular jet are presented, and the spectra are examined for evidence of spectral similarity. Spectral similarity is found for the low wavenumber range when the large scale flow on the centerline of the mixing layer is self-preserving. The data are also consistent with the existence of universal inertial subranges for the spectra of each interaction mode.

Reflectance and transmittance of light scattering scales stacked on the wings of pierid butterflies

NARCIS (Netherlands)

Stavenga, DG; Giraldo, MA; Hoenders, BJ

2006-01-01

The colors of butterfly wings are determined by the structural as well as pigmentary properties of the wing scales. Reflectance spectra of the wings of a number of pierid butterfly species, specifically the small white, Pieris rapae, show that the long-wavelength reflectance of the scales in situ,

A new theory and its application to remove the effect of surface-reflected light in above-surface radiance data from clear and turbid waters

International Nuclear Information System (INIS)

Dev, Pravin Jeba; Shanmugam, Palanisamy

2014-01-01

Water-leaving radiances (L w ) measured from the deck of a ship or boat in oceanic and lake waters are widely and operationally used for satellite sensor vicarious calibration and validation and development of remote-sensing algorithms to understand interdisciplinary coastal ocean properties and processes. However, accurate determination of L w remains to be a challenging issue because of the limitations of the existing methods to accurately remove the undesired signal (surface-reflected light of the sky and sun) from above-surface measurements of the total upwelling radiance leaving the water surface. In this study, a new theory is developed and applied to the above-surface radiometric data measured from clear, turbid and eutrophic waters. The new method effectively removes surface-reflected contributions from the total upwelling radiance signal under different sky (clear sky to overcast sky) and sun glint conditions. The L w spectra obtained from the above-surface radiance data using the new method are found to match well with those extrapolated from the upwelling radiances (L u ) measured with another set of underwater radiometers (used just below the sea surface). The new method proves to be a viable alternative, especially in circumstances when the above-surface measurements of radiances are severally contaminated by the surface-reflected light fields. Since spectral radiance measurements are also sensitive to the observation angles, and to the magnitude of the radiometer's solid angle field of view, above-surface radiances are also measured for different viewing angles in highly eutrophic waters. Such measurements show large deviations in L w spectra except at lower viewing angles (30°). When applied to these data, the new method eliminates the undesired signal encountered at higher viewing angles and delivers accurate water-leaving radiance data. These results suggest that the new method is capable of removing the surface-reflected light fields from both

VO-compliant libraries of high resolution spectra of cool stars

Science.gov (United States)

Montes, D.

2008-10-01

In this contribution we describe a Virtual Observatory (VO) compliant version of the libraries of high resolution spectra of cool stars described by Montes et al. (1997; 1998; and 1999). Since their publication the fully reduced spectra in FITS format have been available via ftp and in the World Wide Web. However, in the VO all the spectra will be accessible using a common web interface following the standards of the International Virtual Observatory Alliance (IVOA). These libraries include F, G, K and M field stars, from dwarfs to giants. The spectral coverage is from 3800 to 10000 Å, with spectral resolution ranging from 0.09 to 3.0 Å.

Development of a theory of the spectral reflectance of minerals, part 4

Science.gov (United States)

Aronson, J. R.; Emslie, A. G.; Smith, E. M.

1972-01-01

A theory of the spectral reflectance or emittance of particulate minerals was developed. The theory is expected to prove invaluable in the interpretation of the remote infrared spectra of planetary surfaces.

Dynamic Bidirectional Reflectance Distribution Functions: Measurement and Representation

Science.gov (United States)

2008-02-01

be included in the harmonic fits. Other sets of orthogonal functions such as Zernike polynomials have also been used to characterize BRDF and could...reflectance spectra of 3D objects,” Proc. SPIE 4663, 370–378 2001. 13J. R. Shell II, C. Salvagio, and J. R. Schott, “A novel BRDF measurement technique

Using reflectance spectroscopy to predict beef tenderness.

Science.gov (United States)

Bowling, M B; Vote, D J; Belk, K E; Scanga, J A; Tatum, J D; Smith, G C

2009-05-01

A study was conducted to determine if reflectance measurements made in the near-infrared region of the spectrum were additive to reflectance measurements made in the visible region of the spectrum for predicting Warner-Bratzler shear force (WBSF) values. Eighty seven strip loins were collected following fabrication over 3d at a commercial beef processing facility from heifer carcasses with Slight or Traces marbling scores. Spectroscopic measurements were made at approximately 50h postmortem using a Hunter-Lab UltraScan. Subsequently, all strip loins were aged for 14d, cooked to an internal temperature of 70°C, and sheared to obtain WBSF values. Reflectance measurements obtained in the near-infrared region of the spectrum were correlated with WBSF values, however, these measurements were not additive to the predictive ability of reflectance measurements (R(2) values did not differ) made in the visible portion of the spectrum when the use of broad-band wavelength filters were simulated. It was therefore determined, that both the visible and near-infrared spectra measure reflectance and that both methods are acceptable methods of tenderness prediction.

Trasmission and Reflection (ATR)Far-Infrared Spectroscopy Applied in the Analysis of Cultural Heritage Materials

OpenAIRE

Kendix, Elsebeth Langholz

2009-01-01

FIR spectroscopy is an alternative way of collecting spectra of many inorganic pigments and corrosion products found on art objects, which is not normally observed in the MIR region. Most FIR spectra are traditionally collected in transmission mode but as a real novelty it is now also possible to record FIR spectra in ATR (Attenuated Total Reflectance) mode. In FIR transmission we employ polyethylene (PE) for preparation of pellets by embedding the sample in PE. Unfortunately, ...

Infrared spectra of jennite and tobermorite from first-principles

Energy Technology Data Exchange (ETDEWEB)

Vidmer, Alexandre, E-mail: alexandre@vidmer.com; Sclauzero, Gabriele; Pasquarello, Alfredo

2014-06-01

The infrared absorption spectra of jennite, tobermorite 14 Å, anomalous tobermorite 11 Å, and normal tobermorite 11 Å are simulated within a density-functional-theory scheme. The atomic coordinates and the cell parameters are optimized resulting in structures which agree with previous studies. The vibrational frequencies and modes are obtained for each mineral. The vibrational density of states is analyzed through extensive projections on silicon tetrahedra, oxygen atoms, OH groups, and water molecules. The coupling with the electric field is achieved through the use of density functional perturbation theory, which yields Born effective charges and dielectric constants. The simulated absorption spectra reproduce well the experimental spectra, thereby allowing for a detailed interpretation of the spectral features in terms of the underlying vibrational modes. In the far-infrared part of the absorption spectra, the interplay between Ca and Si related vibrations leads to differences which are sensitive to the calcium/silicon ratio of the mineral.

Photoelectron spectra as a probe of double-core resonsance in two-electron atoms

International Nuclear Information System (INIS)

Grobe, R.; Haan, S.L.; Eberly, J.H.

1996-01-01

The authors calculate photoelectron spectra for a two-electron atom under the influence of two external driving fields, using an essential states formalism. They focus on the regime of so-called coherence transfer, in which electron-electron correlation transfers field-induced photo-coherence from one electron to the other. In the case studied here, two laser fields are resonant with coupled atomic transitions, in the manner familiar from three-level dark-state spectroscopy. Dynamical two electron effects are monitored via the photoelectron energy spectrum. The authors show that the distribution of the photoelectron energies can be singly, doubly or triply peaked depending on the relative laser intensities. The electron spectra are independent of the turn-on sequence of the fields

Optical studies of 2DEGs in Zinc Selenide quantum wells in high magnetic fields

International Nuclear Information System (INIS)

Ossau, Wolfgang J.; Astakhov, G.V.; Yakovlev, D.R.; Crooker, Scott A.; Waag, A.

2002-01-01

Optical properties of a two-dimensional electron gas in ZnSe/(Zn,Be,Mg)Se quantum well structures have been examined by means of photoluminescence and reflectivity techniques in external magnetic fields up to 50 T. For these structures the Fermi energy of the two-dimensional electron gas is falling in the range between the trion binding energy and the exciton binding energy, which keeps the dominating role of Coulombic interaction between electrons and photoexcited holes. Characteristic peculiarities of optical spectra are discussed.

Optical studies of 2DEGs in ZnSe quantum wells in high magnetic fields.

Energy Technology Data Exchange (ETDEWEB)

Ossau, Wolfgang J.; Astakhov, G. V.; Yakovlev, D. R.; Crooker, S. A. (Scott A.); Waag, A.

2002-01-01

Optical properties of a two-dimensional electron gas in ZnSe/(Zn,Be,Mg)Se quantum well structures have been examined by means of photoluminescence and reflectivity techniques in external magnetic fields up to 50 T. For these structures the Fermi energy of the two-dimensional electron gas is falling in the range between the trion binding energy and the exciton binding energy, which keeps the dominating role of Coulombic interaction between electrons and photoexcited holes. Characteristic peculiarities of optical spectra are discussed.

Hybrid reflection type metasurface of nano-antennas designed for optical needle field generation

Science.gov (United States)

Wang, Shiyi; Zhan, Qiwen

2015-03-01

We propose a reflection type metal-insulator-metal (MIM) metasurface composed of hybrid optical antennas for comprehensive spatial engineering the properties of optical fields. Its capability is illustrated with an example to create a radially polarized vectorial beam for optical needle field generation. Functioning as local quarter-wave-plates (QWP), the MIM metasurface is designed to convert circularly polarized incident into local linear polarization to create an overall radial polarization with corresponding binary phases and desired normalized amplitude modulation ranged from 0.07 to 1. To obtain enough degrees of freedom, the optical-antenna layer comprises periodic arrangements of double metallic nano-bars with perpendicular placement and single nano-bars respectively for different amplitude modulation requirements. Both of the antennas enable to introduce π/2 retardation while reaching the desired modulation range both for phase and amplitude. Through adjusting the antennas' geometry and array carefully, we shift the gap-surface plasmon resonances facilitated by optical antennas to realize the manipulation of vectorial properties. Designed at 1064 nm wavelength, the particularly generated vectorial light output can be further tightly focused by a high numerical aperture objective to obtain longitudinally polarized flat-top focal field. The so-called optical needle field is a promising candidate for novel applications that transcend disciplinary boundaries. The proposed metasurface establishes a new class of compact optical components based on nano-scale structures, leading to compound functions for vectorial light generation.

Extracting ion emission lines from femtosecond-laser plasma x-ray spectra heavily contaminated by spikes

International Nuclear Information System (INIS)

Gasilov, S. V.; Faenov, A. Ya.; Pikuz, T. A.; Villoresi, P.; Poletto, L.; Stagira, S.; Calegari, F.; Vozzi, C.; Nisoli, M.

2007-01-01

Nowadays charged-coupled device (CCD) detectors are widely used for the registration of multicharged ions x-ray spectra. These spectra are generated in a plasma during interaction of ultrashort, ultraintense laser pulses with solid targets. Strong parasitic radiation from the plasma affects CCD detectors and contaminates resulting spectra, so that spectral features can be completely covered by noise even during measurements with a very short accumulation time. In this work we propose a ''mean to median'' (M2M) algorithm for noise suppression in femtosecond laser plasma x-ray spectra. Series of spectra is necessary for the identification of corrupted data points by the developed method. The algorithm was tested with model spectra which reflect main features of experimental data. In practice we used it for extracting information about spectral lines of Ne-like Fe ions and He-like Al ions which allowed us to calculate plasma parameters. It is demonstrated that M2M method is able to clean spectra with more than 10% of corrupted pixels. Fluctuations in intensity of spectral lines induced by laser instability do not affect validity of the proposed method

Reflectance, absorbance and transmittance spectra of bermudagrass and manilagrass turfgrass canopies.

Science.gov (United States)

Volterrani, Marco; Minelli, Alberto; Gaetani, Monica; Grossi, Nicola; Magni, Simone; Caturegli, Lisa

2017-01-01

Leaves act as a primary organ for the interception of solar radiation and their spatial arrangement determines how the plant canopy interacts with light. Many studies have been carried out on the penetration of radiation into crops however to date, few results are available on turfgrasses, mainly due to the difficulties of introducing sensors into the turf without disturbing the natural position of the leaves. In the present research two warm season turfgrasses, hybrid bermudagrass (Cynodon dactylon × transvaalensis) 'Patriot' and manilagrass (Zoysia matrella) 'Zeon', were studied. The aim was to describe their canopy architecture grown with minimal disturbance to the natural arrangement of the leaves and stems, and to determine the potential effects of canopy architecture on light penetration and reflectance. Radiometric measurements were carried out at eight different profile levels of turfgrasses that were up to 12 cm tall. A LI-COR 1800 spectroradiometer with an optical fiber cable and a 7 mm diameter sensor was used. Measurements were carried out in the 390-1100 nm region at 5 nm intervals. The LAI value was higher for the manilagrass (9.0) than for the hybrid bermudagrass (5.6). The transmitted radiation was found to be closely dependent on downward cumulative LAI. Despite a more upright habit (mean insertion angle of 22.4° ±3.4), Zoysia matrella showed a higher NIR reflectance compared to Cdxt, which has a horizontal leaf arrangement (mean insertion angle 62.1° ± 9.6). The species studied showed substantial differences both in terms of phytometric characteristics and in the capacity to attenuate solar radiation.

The optical spectra of 24 mu m galaxies in the cosmos field. I. Spitzer MIPS bright sources in the zCOSMOS-bright 10k catalog

NARCIS (Netherlands)

Caputi, K. I.; Lilly, S. J.; Aussel, H.; Sanders, D.; Frayer, D.; Le Fevre, O.; Renzini, A.; Zamorani, G.; Scodeggio, M.; Contini, T.; Scoville, N.; Carollo, C. M.; Hasinger, G.; Iovino, A.; Le Brun, V.; Le Floc'h, E.; Maier, C.; Mainieri, V.; Mignoli, M.; Salvato, M.; Schiminovich, D.; Silverman, J.; Surace, J.; Tasca, L.; Abbas, U.; Bardelli, S.; Bolzonella, M.; Bongiorno, A.; Bottini, D.; Capak, P.; Cappi, A.; Cassata, P.; Cimatti, A.; Cucciati, O.; de la Torre, S.; de Ravel, L.; Franzetti, P.; Fumana, M.; Garilli, B.; Halliday, C.; Ilbert, O.; Kampczyk, P.; Kartaltepe, J.; Kneib, J. -P.; Knobel, C.; Kovac, K.; Lamareille, F.; Leauthaud, A.; Le Borgne, J. F.; Maccagni, D.; Marinoni, C.; McCracken, H.; Meneux, B.; Oesch, P.; Pello, R.; Perez-Montero, E.; Porciani, C.; Ricciardelli, E.; Scaramella, R.; Scarlata, C.; Tresse, L.; Vergani, D.; Walcher, J.; Zamojski, M.; Zucca, E.

2008-01-01

We study zCOSMOS-bright optical spectra for 609 Spitzer MIPS 24 mu m-selected galaxies with S-24 (mu m) > 0: 30 mJy and I <22.5 (AB mag) over 1.5 deg(2) of the COSMOS field. From emission-line diagnostics we find the following: (1) SFRs derived from the observed H alpha lambda 6563 and H beta lambda

General and efficient method for calculating modulation ressponses and noise spectra of active semiconductor waveguides

DEFF Research Database (Denmark)

Blaaberg, Søren; Öhman, Filip; Mørk, Jesper

2008-01-01

We present a theoretical method for obtaining small-signal responses in a spatially resolved active semiconductor waveguide including finite end-facet reflectivities and amplified spontaneous emission. RF-modulation responses and output noise spectra of an SOA are shown....

A BAND SELECTION METHOD FOR SUB-PIXEL TARGET DETECTION IN HYPERSPECTRAL IMAGES BASED ON LABORATORY AND FIELD REFLECTANCE SPECTRAL COMPARISON

Directory of Open Access Journals (Sweden)

S. Sharifi hashjin

2016-06-01

Full Text Available In recent years, developing target detection algorithms has received growing interest in hyperspectral images. In comparison to the classification field, few studies have been done on dimension reduction or band selection for target detection in hyperspectral images. This study presents a simple method to remove bad bands from the images in a supervised manner for sub-pixel target detection. The proposed method is based on comparing field and laboratory spectra of the target of interest for detecting bad bands. For evaluation, the target detection blind test dataset is used in this study. Experimental results show that the proposed method can improve efficiency of the two well-known target detection methods, ACE and CEM.

On-line monitoring of the crystallization process: relationship between crystal size and electrical impedance spectra

International Nuclear Information System (INIS)

Zhao, Yanlin; Yao, Jun; Wang, Mi

2016-01-01

On-line monitoring of crystal size in the crystallization process is crucial to many pharmaceutical and fine-chemical industrial applications. In this paper, a novel method is proposed for the on-line monitoring of the cooling crystallization process of L-glutamic acid (LGA) using electrical impedance spectroscopy (EIS). The EIS method can be used to monitor the growth of crystal particles relying on the presence of an electrical double layer on the charged particle surface and the polarization of double layer under the excitation of alternating electrical field. The electrical impedance spectra and crystal size were measured on-line simultaneously by an impedance analyzer and focused beam reflectance measurement (FBRM), respectively. The impedance spectra were analyzed using the equivalent circuit model and the equivalent circuit elements in the model can be obtained by fitting the experimental data. Two equivalent circuit elements, including capacitance ( C 2 ) and resistance ( R 2 ) from the dielectric polarization of the LGA solution and crystal particle/solution interface, are in relation with the crystal size. The mathematical relationship between the crystal size and the equivalent circuit elements can be obtained by a non-linear fitting method. The function can be used to predict the change of crystal size during the crystallization process. (paper)

Reflection effects in multimode fiber systems utilizing laser transmitters

Science.gov (United States)

Bates, Harry E.

1991-11-01

A number of optical communication lines are now in use at NASA-Kennedy for the transmission of voice, computer data, and video signals. Now, all of these channels use a single carrier wavelength centered near 1300 or 1550 nm. Engineering tests in the past have given indications of the growth of systematic and random noise in the RF spectrum of a fiber network as the number of connector pairs is increased. This noise seems to occur when a laser transmitter is used instead of a LED. It has been suggested that the noise is caused by back reflections created at connector fiber interfaces. Experiments were performed to explore the effect of reflection on the transmitting laser under conditions of reflective feedback. This effort included computer integration of some of the instrumentation in the fiber optic lab using the Lab View software recently acquired by the lab group. The main goal was to interface the Anritsu Optical and RF spectrum analyzers to the MacIntosh II computer so that laser spectra and network RF spectra could be simultaneously and rapidly acquired in a form convenient for analysis. Both single and multimode fiber is installed at Kennedy. Since most are multimode, this effort concentrated on multimode systems.

Photoelectron reflection and scattering at Venus: an upper limit on the "polar wind" ambipolar electric field, and a new source of top-side ionospheric heating

Science.gov (United States)

Collinson, Glyn; Glocer, Alex; Grebowsky, Joe; Peterson, William; Frahm, Rudy; Moore, Thomas; Gilbert, Lin; Coates, Andrew

2015-04-01

An important mechanism in the generation of Earth's polar wind is the ambipolar potential generated by the outflow along open field lines of superthermal electrons. This ≈20V electric potential assists ions in overcoming the gravitational potential, and is a key mechanism for Terrestrial ionospheric escape. At Venus, except in rare circumstances, every field line is open, and a similar outflow of ionospheric electrons is observed. It is thus hypothesized that a similar electric potential may be present at Venus, contributing to global ionospheric loss. However, a very sensitive electric field instrument would be required to directly measure this potential, and no such instrument has yet been flown to Venus. In this pilot study, we examine photoelectron spectra measured by the ASPERA-ELS instrument on the Venus Express to put an initial upper bound on the total potential drop above 350km of Φ current understanding, a "polar wind" like ambipolar electric field may not be as important a mechanism for atmospheric escape as previously suspected. Additionally, we find our spectra are consistent with the scattering of photoelectrons, the heating from which which we hypothesize may act as a source of top-side ionospheric heating, and may play a role in influencing the scale height of the ionosphere.

A comparison of telescopic and Phobos-2 ISM spectra of Mars in the short-wave near-infrared (0.76-1.02 microns)

Science.gov (United States)

Bell, James F., III; Mustard, John F.

1993-01-01

Recent analyses of near-IR (0.76-3.16 microns) Mars surface reflectance spectra obtained by the Phobos-2 ISM instrument during early 1989 have revealed the presence of substantial variability in surface spectral properties. Strong absorption features seen in the 0.85-1.05 micron region are up to 10-15 percent deep relative to the local continuum and have been interpreted as evidence of Fe(2+) and Fe(3+) bearing minerals (pyroxenes and iron oxides, respectively). Though these observed band depths are comparable to those seen in laboratory reflectance spectra, they are up to three times larger than most previously reported band depths for Mars spectra at these wavelengths. Six regions of variable albedo and geologic setting were identified where ISM and 1988 opposition telescopic coverage either overlapped physically or sampled the same surface geologic unit. The areal sizes and positions of the regions measured telescopically were compiled by Bell et al. ISM pixels falling within these spots were averaged to produce a spatially convolved spectrum that simulates what would have been seen telescopically. To facilitate comparisons of absorption band positions and relative strengths, the convolved ISM data and the 1988 telescopic spectra were scaled to unity at 0.81 microns and are presented. The data have also been convolved to equivalent band pass normalized reflectances in the region of spectral overlap. A scatter diagram of telescopic vs. ISM reflectances is shown. The results from the investigation are discussed.

Determination of the optical absorption spectra of thin layers from their photoacoustic spectra

Science.gov (United States)

Bychto, Leszek; Maliński, Mirosław; Patryn, Aleksy; Tivanov, Mikhail; Gremenok, Valery

2018-05-01

This paper presents a new method for computations of the optical absorption coefficient spectra from the normalized photoacoustic amplitude spectra of thin semiconductor samples deposited on the optically transparent and thermally thick substrates. This method was tested on CuIn(Te0.7Se0.3)2 thin films. From the normalized photoacoustic amplitude spectra, the optical absorption coefficient spectra were computed with the new formula as also with the numerical iterative method. From these spectra, the value of the energy gap of the thin film material and the type of the optical transitions were determined. From the experimental optical transmission spectra, the optical absorption coefficient spectra were computed too, and compared with the optical absorption coefficient spectra obtained from photoacoustic spectra.

Modeling of A-DLTS Spectra of MOS Structures

Directory of Open Access Journals (Sweden)

Peter Hockicko

2008-01-01

Full Text Available Acquisition of basic characteristic of defects has become possible through a wide class of measurement techniqueswhich probe the interface, the near interface, as well as the bulk of semiconductor. Results presented here are basedessentially on the acoustic version of Deep Level Transient Spectroscopy (A-DLTS measurements. This method is based onthe acoustoelectric response effect observed at the interface. The A-DLTS uses the acoustoelectric response signal (ARSproduced by MOS structure interface when a longitudal acoustic wave propagates through a structure. The ARS is extremelysensitive to external conditions of the structure and reflects any changes in the charge distribution connected with chargedtraps. The temperature dependence of ARS after bias voltage step application is investigated and the activation energies andsome other parameters of traps at the insulator – semiconductor interface are determined. The results obtained formArrhenius plots of A-DLTS spectra of selected MOS structures are compared with results obtained from modeling of ADLTS spectra using theoretical model.

C-X neutral spectra from ZT-40M

International Nuclear Information System (INIS)

Munson, C.; Carolan, P.G.; Bunting, C.A.

1988-01-01

A series of experiments have recently been completed on the ZT-40M Reversed Field Pinch at Los Alamos for which Neutral Charge Exchange (C-X) spectra have been measured using both the previously reported Time-of-Flight (TOF) system, and a 5 channel electrostatic Neutral Particle Analyzer (NPA). The experiments involved measurements of ion and electron temperatures for a variety of discharge conditions including scans of flat-top current levels, different values of the toroidal field reversal parameter (F = B phi (a)/ phi >), ramped current discharges, discharges with a movable graphite paddle limiter inserted into the edge of the plasma from above, and discharges with Deuterium pellet injection. Both the TOF and NPA systems view the plasma along chords from the outside midplane, and are separated by 60 0 toroidally. Core ion temperatures are obtained by examining the asymptotic tail of the neutral particle efflux spectrum. Detailed comparisons of the neutral particle spectra obtained with these two systems for the various operating conditions will be presented

Design and Analysis of Multilayered Waveguide Structure With Metal-Dielectric Gratings for Sensing With Reflection Narrowband Notch Filter

Directory of Open Access Journals (Sweden)

Guiju ZHANG

2015-11-01

Full Text Available Developments in micro and nanofabrication technologies have led a variety of grating waveguide structures (GWS being proposed and implemented in optics and laser application systems. A new design of multilayered nanostructure double-grating is described for reflection notch filter. Thin metal film and dielectric film are used and designed with one-dimensional composite gratings. The results calculated by rigorous coupled-wave analysis (RCWA present that the thin metal film between substrate and grating can produce significant attenuated reflections and efficiency in a broad reflected spectral range. The behavior of such a reflection filter is evaluated for refractive index sensing, which can be applied inside the integrated waveguide structure while succeeding cycles in measurement. The filter peaks are designed and obtained in a visible range with full width half maximum (FWHM of several nanometers to less than one nanometer. The multilayered structure shows a sensitivity of refractive index of 220nm/RIU as changing the surroundings. The reflection spectra are studied under different periods, depths and duty cycles. The passive structure and its characteristics can achieve practical applications in various fields, such as optical sensing, color filtering, Raman spectroscopy and laser technology.DOI: http://dx.doi.org/10.5755/j01.ms.21.4.9625

Fully automated laboratory and field-portable goniometer used for performing accurate and precise multiangular reflectance measurements

Science.gov (United States)

Harms, Justin D.; Bachmann, Charles M.; Ambeau, Brittany L.; Faulring, Jason W.; Ruiz Torres, Andres J.; Badura, Gregory; Myers, Emily

2017-10-01

Field-portable goniometers are created for a wide variety of applications. Many of these applications require specific types of instruments and measurement schemes and must operate in challenging environments. Therefore, designs are based on the requirements that are specific to the application. We present a field-portable goniometer that was designed for measuring the hemispherical-conical reflectance factor (HCRF) of various soils and low-growing vegetation in austere coastal and desert environments and biconical reflectance factors in laboratory settings. Unlike some goniometers, this system features a requirement for "target-plane tracking" to ensure that measurements can be collected on sloped surfaces, without compromising angular accuracy. The system also features a second upward-looking spectrometer to measure the spatially dependent incoming illumination, an integrated software package to provide full automation, an automated leveling system to ensure a standard frame of reference, a design that minimizes the obscuration due to self-shading to measure the opposition effect, and the ability to record a digital elevation model of the target region. This fully automated and highly mobile system obtains accurate and precise measurements of HCRF in a wide variety of terrain and in less time than most other systems while not sacrificing consistency or repeatability in laboratory environments.

Euclidean mirrors: enhanced vacuum decay from reflected instantons

Science.gov (United States)

Akal, Ibrahim; Moortgat-Pick, Gudrid

2018-05-01

We study the tunnelling of virtual matter–antimatter pairs from the quantum vacuum in the presence of a spatially uniform, time-dependent electric background composed of a strong, slow field superimposed with a weak, rapid field. After analytic continuation to Euclidean spacetime, we obtain from the instanton equations two critical points. While one of them is the closing point of the instanton path, the other serves as an Euclidean mirror which reflects and squeezes the instanton. It is this reflection and shrinking which is responsible for an enormous enhancement of the vacuum pair production rate. We discuss how important features of two different mechanisms can be analysed and understood via such a rotation in the complex plane. (a) Consistent with previous studies, we first discuss the standard assisted mechanism with a static strong field and certain weak fields with a distinct pole structure in order to show that the reflection takes place exactly at the poles. We also discuss the effect of possible sub-cycle structures. We extend this reflection picture then to weak fields which have no poles present and illustrate the effective reflections with explicit examples. An additional field strength dependence for the rate occurs in such cases. We analytically compute the characteristic threshold for the assisted mechanism given by the critical combined Keldysh parameter. We discuss significant differences between these two types of fields. For various backgrounds, we present the contributing instantons and perform analytical computations for the corresponding rates treating both fields nonperturbatively. (b) In addition, we also study the case with a nonstatic strong field which gives rise to the assisted dynamical mechanism. For different strong field profiles we investigate the impact on the critical combined Keldysh parameter. As an explicit example, we analytically compute the rate by employing the exact reflection points. The validity of the predictions

Giant Planets in Reflected Light: What Science Can We Expect?

Science.gov (United States)

Marley, Mark

2016-01-01

Interpreting the reflection spectra of cool giant planets will be a challenge. Spectra of such worlds are expected to be primarily shaped by scattering from clouds and hazes and punctuated by absorption bands of methane, water, and ammonia. While the warmest giants may be cloudless, their atmospheres will almost certainly sport substantial photochemical hazes. Furthermore the masses of most direct imaging targets will be constrained by radial velocity observations, their radii, and thus atmospheric gravity, will be imperfectly known. The uncertainty in planet radius and gravity will compound with uncertain aerosol properties to make estimation of key absorber abundances difficult. To address such concerns our group is developing atmospheric retrieval tools to constrain quantities of interest, particular gas mixing ratios. We have applied our Markov Chain Monte Carlo methods to simulated data of the quality expected from the WFIRST CGI instrument and found that given sufficiently high SNR data we can confidentially identify and constrain the abundance of methane, cloud top pressures, gravity, and the star-planet-observer phase angle. In my presentation I will explain the expected characteristics of cool extrasolar giant planet reflection spectra, discuss these and other challenges in their interpretation, and summarize the science results we can expect from direct imaging observations.

Polynomial Poisson algebras: Gel'fand-Kirillov problem and Poisson spectra

OpenAIRE

Lecoutre, César

2014-01-01

We study the fields of fractions and the Poisson spectra of polynomial Poisson algebras.\\ud \\ud First we investigate a Poisson birational equivalence problem for polynomial Poisson algebras over a field of arbitrary characteristic. Namely, the quadratic Poisson Gel'fand-Kirillov problem asks whether the field of fractions of a Poisson algebra is isomorphic to the field of fractions of a Poisson affine space, i.e. a polynomial algebra such that the Poisson bracket of two generators is equal to...

Effects of the ohmic current on collective scattering spectra

International Nuclear Information System (INIS)

Castiglioni, S.; Lontano, M.; Tartari, U.

1993-01-01

A numerical and analytical study of the modifications induced in the collective scattering spectra by the ohmic current governing the equilibrium magnetic configuration in toroidal plasmas is presented. The spectral density function is calculated assuming equilibrium distributions for the (bulk and impurity) ion species and a Spitzer-like distribution to describe the response of the electrons to the applied DC electric field. As expected, the spectral asymmetries can be non-negligibly enhanced in the region of the ion-acoustic frequency. They reach their maxima for tangential scattering geometries, where the magnetic effects on the spectra are negligible. This justifies the assumption of the non-magnetized spectra. A theoretically motivated potential is shown to exist for a more detailed experimental investigation of the feasibility of current-density measurements in ohmic plasmas, based on collective scattering. (author)

Near IR Scanning Angle Total Internal Reflection Raman Spectroscopy at Smooth Gold Films

Energy Technology Data Exchange (ETDEWEB)

McKee, Kristopher; Meyer, Matthew; Smith, Emily

2012-04-13

Total internal reflection (TIR) Raman and reflectivity spectra were collected for nonresonant analytes as a function of incident angle at sapphire or sapphire/smooth 50 nm gold interfaces using 785 nm excitation. For both interfaces, the Raman signal as a function of incident angle is well-modeled by the calculated interfacial mean square electric field (MSEF) relative to the incident field times the thickness of the layer being probed in the Raman measurement (D{sub RS}). The Raman scatter was reproducibly enhanced at the interface containing a gold film relative to the sapphire interface by a factor of 4.3–4.6 for aqueous pyridine or 2.2–3.7 for neat nitrobenzene, depending on the analyzed vibrational mode. The mechanism for the increased Raman signal is the enhanced MSEF at incident angles where propagating surface plasmons are excited in the metal film. The background from the TIR prism was reduced by 89–95% with the addition of the gold film, and the percent relative uncertainty in peak area was reduced from 15 to 1.7% for the 1347 cm–1 mode of nitrobenzene. Single monolayers of benzenethiol (S/N = 6.8) and 4-mercaptopyridine (S/N = 16.5) on gold films were measured by TIR Raman spectroscopy with 785 nm excitation (210 mW) without resonant enhancement in 1 min.

Sensitivity of NMR spectra properties to different inversion algorithms. Abstract 97

International Nuclear Information System (INIS)

Bryan, J.; Wang, G.; Vargas, S.; Kantzas, A.

2004-01-01

'Full text:' Low field NMR technology has many applications in the petroleum industry. NMR spectra obtained from logging tools or laboratory instruments can be used to provide an incredible wealth of useful information for formation evaluation and reservoir fluid characterization purposes. In recent years, research performed at the University of Calgary has been instrumental in developing this technology for heavy oil and bitumen related problems. Specifically, low field NMR has been used in several niche applications: in-situ viscosity estimates of heavy oil and bitumen, water-in-oil emulsion and solvent-bitumen mixture viscosity, water cut in produced fluid streams, and oil-water-solids content in oil sands mining samples. The majority of all NMR analyses are based on the interpretation of NMR spectra. These spectra are inverted numerically from the measured NMR decay data. The mathematics of the inversion is generally assumed to be correct, and the analyses revolve around interpretations of how the spectra relate to physical properties of the samples. However, when measuring high viscosity fluids or clay-bound water, the NMR signal relaxes very quickly and it becomes extremely important to ensure that the spectrum obtained is accurate before relating its properties to physics. This work investigates the effect of different inversion algorithms on the generated spectra, and attempts to quantify the magnitude of the errors that can be associated with the mathematics of inversion. This leads to a better understanding of the accuracy of NMR estimates of rock and fluid properties. (author)

Reflectance, absorbance and transmittance spectra of bermudagrass and manilagrass turfgrass canopies.

Directory of Open Access Journals (Sweden)

Marco Volterrani

Full Text Available Leaves act as a primary organ for the interception of solar radiation and their spatial arrangement determines how the plant canopy interacts with light. Many studies have been carried out on the penetration of radiation into crops however to date, few results are available on turfgrasses, mainly due to the difficulties of introducing sensors into the turf without disturbing the natural position of the leaves. In the present research two warm season turfgrasses, hybrid bermudagrass (Cynodon dactylon × transvaalensis 'Patriot' and manilagrass (Zoysia matrella 'Zeon', were studied. The aim was to describe their canopy architecture grown with minimal disturbance to the natural arrangement of the leaves and stems, and to determine the potential effects of canopy architecture on light penetration and reflectance. Radiometric measurements were carried out at eight different profile levels of turfgrasses that were up to 12 cm tall. A LI-COR 1800 spectroradiometer with an optical fiber cable and a 7 mm diameter sensor was used. Measurements were carried out in the 390-1100 nm region at 5 nm intervals. The LAI value was higher for the manilagrass (9.0 than for the hybrid bermudagrass (5.6. The transmitted radiation was found to be closely dependent on downward cumulative LAI. Despite a more upright habit (mean insertion angle of 22.4° ±3.4, Zoysia matrella showed a higher NIR reflectance compared to Cdxt, which has a horizontal leaf arrangement (mean insertion angle 62.1° ± 9.6. The species studied showed substantial differences both in terms of phytometric characteristics and in the capacity to attenuate solar radiation.

A new interpretation of the feature of SiO maser spectra associated with M-type star

International Nuclear Information System (INIS)

Liu Hanping; Sun Jin

1989-09-01

There exists a systematic redshift of spectra (ν=1,2; J=1-0) of SiO masers associated with a number of late-type M stars. On the contrary, the redshift is rather small for the spectra (ν=1; J=2-1). The latter is approximately symmetrical with respect to the star. For the above, no good interpretation has been given up to now. A new redshift mechanism of SiO spectra, the mechanism of radiation frequency shift, has been derived here from the interaction between the radiation field of the star and the energy levels of the maser. Detailed calculations show that, under the influence of the radiation field of the star, the redshift of the SiO spectra (J=1-0) is more substantial than that of the spectra (J=2-1). This is consistent with the result of the observation, and shows that the non-kinematic effect of the spectra is non negligible for the SiO maser of the star. (author). 10 refs, 1 fig., 1 tab

Field-modulation spectroscopy of pentacene thin films using field-effect devices: Reconsideration of the excitonic structure

Science.gov (United States)

Haas, Simon; Matsui, Hiroyuki; Hasegawa, Tatsuo

2010-10-01

We report pure electric-field effects on the excitonic absorbance of pentacene thin films as measured by unipolar field-effect devices that allowed us to separate the charge accumulation effects. The field-modulated spectra between 1.8 and 2.6 eV can be well fitted with the first derivative curve of Frenkel exciton absorption and its vibronic progression, and at higher energy a field-induced feature appears at around 2.95 eV. The results are in sharp contrast to the electroabsorption spectra reported by Sebastian in previous studies [Chem. Phys. 61, 125 (1981)10.1016/0301-0104(81)85055-0], and leads us to reconsider the excitonic structure including the location of charge-transfer excitons. Nonlinear π -electronic response is discussed based on second-order electro-optic (Kerr) spectra.

Fourier evaluation of broad Moessbauer spectra

International Nuclear Information System (INIS)

Vincze, I.

1981-01-01

It is shown by the Fourier analysis of broad Moessbauer spectra that the even part of the distribution of the dominant hyperfine interaction (hyperfine field or quadrupole splitting) can be obtained directly without using least-square fitting procedures. Also the odd part of this distribution correlated with other hyperfine parameters (e.g. isomer shift) can be directly determined. Examples for amorphous magnetic and paramagnetic iron-based alloys are presented. (author)

The US Geological Survey, digital spectral reflectance library: version 1: 0.2 to 3.0 microns

Science.gov (United States)

Clark, Roger N.; Swayze, Gregg A.; King, Trude V. V.; Gallagher, Andrea J.; Calvin, Wendy M.

1993-01-01

We have developed a digital reflectance spectral library, with management and spectral analysis software. The library includes 500 spectra of 447 samples (some samples include a series of grain sizes) measured from approximately 0.2 to 3.0 microns. The spectral resolution (Full Width Half Maximum) of the reflectance data is less than or equal to 4 nm in the visible (0.2-0.8 microns) and less than or equal 10 nm in the NIR (0.8-2.35 microns). All spectra were corrected to absolute reflectance using an NBS Halon standard. Library management software lets users search on parameters (e.g. chemical formulae, chemical analyses, purity of samples, mineral groups, etc.) as well as spectral features. Minerals from sulfide, oxide, hydroxide, halide, carbonate, nitrate, borate, phosphate, and silicate groups are represented. X-ray and chemical analyses are tabulated for many of the entries, and all samples have been evaluated for spectral purity. The library also contains end and intermediate members for the olivine, garnet, scapolite, montmorillonite, muscovite, jarosite, and alunite solid-solution series. We have included representative spectra of H2O ice, kerogen, ammonium-bearing minerals, rare-earth oxides, desert varnish coatings, kaolinite crystallinity series, kaolinite-smectite series, zeolite series, and an extensive evaporite series. Because of the importance of vegetation to climate-change studies we have include 17 spectra of tree leaves, bushes, and grasses.

Origin of the turbulent spectra in the high-altitude cusp: Cluster spacecraft observations

Directory of Open Access Journals (Sweden)

K. Nykyri

2006-05-01

Full Text Available High-resolution magnetic field data from Cluster Flux Gate Magnetometer (FGM and the Spatio-Temporal Analysis of Field Fluctuations (STAFF instruments are used to study turbulent magnetic field fluctuations during the high-altitude cusp crossing on 17 March 2001. Despite the quiet solar wind conditions, the cusp was filled with magnetic field turbulence whose power correlates with the field-aligned ion plasma flux. The magnetic field wave spectra shows power law behavior with both double and single slopes with break in the spectra usually occurring in the vicinity of the local ion cyclotron frequency. Strong peaks in the wave power close to local ion cyclotron frequency were sometimes observed, with secondary peaks at higher harmonics indicative of resonant processes between protons and the waves. We show that the observed spectral break point may be caused partly by damping of obliquely propagating kinetic Alfvén (KAW waves and partly by cyclotron damping of ion cyclotron waves.

Efficient anomalous reflection through near-field interactions in metasurfaces

Science.gov (United States)

Chalabi, H.; Ra'di, Y.; Sounas, D. L.; Alù, A.

2017-08-01

Gradient metasurfaces have been extensively used in the past few years for advanced wave manipulation over a thin surface. These metasurfaces have been mostly designed based on the generalized laws of reflection and refraction. However, it was recently revealed that metasurfaces based on this approach tend to suffer from inefficiencies and complex design requirements. We have recently proposed a different approach to the problem of efficient beam steering using a surface, based on bianisotropic particles in a periodic array. Here, we show highly efficient reflective metasurfaces formed by pairs of isotropic dielectric rods, which can offer asymmetrical scattering of normally incident beams with unitary efficiency. Our theory shows that moderately broadband anomalous reflection can be achieved with suitably designed periodic arrays of isotropic nanoparticles. We also demonstrate practical designs using TiO2 cylindrical nanorods to deflect normally incident light toward a desired direction. The proposed structures may pave the way to a broader range of light management opportunities, with applications in energy harvesting, signaling, and communications.

Stealth metamaterial objects characterized in the far field by Radar Cross Section measurements

DEFF Research Database (Denmark)

Iwaszczuk, Krzysztof; Fan, K.; Strikwerda, A. C.

Reflection spectra and radar cross sections (RCS) at terahertz frequencies are measured on structures incorporating absorbing metamaterials. Reduction of the RCS by the factor of 375 at the resonant frequencies is observed.......Reflection spectra and radar cross sections (RCS) at terahertz frequencies are measured on structures incorporating absorbing metamaterials. Reduction of the RCS by the factor of 375 at the resonant frequencies is observed....

Predicting foliar biochemistry of tea (Camellia sinensis) using reflectance spectra measured at powder, leaf and canopy levels

Science.gov (United States)

Bian, Meng; Skidmore, Andrew K.; Schlerf, Martin; Wang, Tiejun; Liu, Yanfang; Zeng, Rong; Fei, Teng

2013-04-01

Some biochemical compounds are closely related with the quality of tea (Camellia sinensis (L.)). In this study, the concentration of these compounds including total tea polyphenols, free amino acids and soluble sugars were estimated using reflectance spectroscopy at three different levels: powder, leaf and canopy, with partial least squares regression. The focus of this study is to systematically compare the accuracy of tea quality estimations based on spectroscopy at three different levels. At the powder level, the average r2 between predictions and observations was 0.89 for polyphenols, 0.81 for amino acids and 0.78 for sugars, with relative root mean square errors (RMSE/mean) of 5.47%, 5.50% and 2.75%, respectively; at the leaf level, the average r2 decreased to 0.46-0.81 and the relative RMSE increased to 4.46-7.09%. Compared to the results yielded at the leaf level, the results from canopy spectra were slightly more accurate, yielding average r2 values of 0.83, 0.77 and 0.56 and relative RMSE of 6.79%, 5.73% and 4.03% for polyphenols, amino acids and sugars, respectively. We further identified wavelength channels that influenced the prediction model. For powder and leaves, some bands identified can be linked to the absorption features of chemicals of interest (1648 nm for phenolic, 1510 nm for amino acids, 2080 nm and 2270 nm for sugars), while more indirectly related wavelengths were found to be important at the canopy level for predictions of chemical compounds. Overall, the prediction accuracies achieved at canopy level in this study are encouraging for future study on tea quality estimated at the landscape scale using airborne and space-borne sensors.

Determination of continuous complex refractive index dispersion of biotissue based on internal reflection

Science.gov (United States)

Deng, Zhichao; Wang, Jin; Ye, Qing; Sun, Tengqian; Zhou, Wenyuan; Mei, Jianchun; Zhang, Chunping; Tian, Jianguo

2016-01-01

The complex refractive index dispersion (CRID), which contains the information on the refractive index dispersion and extinction coefficient spectra, is an important optical parameter of biotissue. However, it is hard to perform the CRID measurement on biotissues due to their high scattering property. Continuous CRID measurement based on internal reflection (CCRIDM-IR) is introduced. By using a lab-made apparatus, internal reflectance spectra of biotissue samples at multiple incident angles were detected, from which the continuous CRIDs were calculated based on the Fresnel formula. Results showed that in 400- to 750-nm range, hemoglobin solution has complicated dispersion and extinction coefficient spectra, while other biotissues have normal dispersion properties, and their extinction coefficients do not vary much with different wavelengths. The normal dispersion can be accurately described by several coefficients of dispersion equations (Cauchy equation, Cornu equation, and Conrady equation). To our knowledge, this is the first time that the continuous CRID of scattering biotissue over a continuous spectral region is measured, and we hereby have proven that CCRIDM-IR is a good method for continuous CRID research of biotissue.