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Sample records for fe kalpha line

  1. X-ray Fluorescent Fe Kalpha Lines from Stellar Photospheres

    CERN Document Server

    Drake, Jeremy J; Swartz, Douglas A

    2007-01-01

    X-ray spectra from stellar coronae are reprocessed by the underlying photosphere through scattering and photoionization events. While reprocessed X-ray spectra reaching a distant observer are at a flux level of only a few percent of that of the corona itself, characteristic lines formed by inner shell photoionization of some abundant elements can be significantly stronger. The emergent photospheric spectra are sensitive to the distance and location of the fluorescing radiation and can provide diagnostics of coronal geometry and abundance. Here we present Monte Carlo simulations of the photospheric Kalpha doublet arising from quasi-neutral Fe irradiated by a coronal X-ray source. Fluorescent line strengths have been computed as a function of the height of the radiation source, the temperature of the ionising X-ray spectrum, and the viewing angle. We also illustrate how the fluorescence efficiencies scale with the photospheric metallicity and the Fe abundance. Based on the results we make three comments: (1) fl...

  2. Dependence of the broad Fe K$\\alpha$ line on the physical parameters of AGN

    CERN Document Server

    Liu, Zhu; Lu, Youjun; Carrera, Francisco J; Falocco, Serena; Dong, Xiao-Bo

    2016-01-01

    In this paper, the dependence of the broad Fe K$\\alpha$ line on the physical parameters of AGN, such as the black hole mass $M_{BH}$, accretion rate (equivalently represented by Eddington ratio $\\lambda_{Edd}$), and optical classification, is investigated by applying the X-ray spectra stacking method to a large sample of AGN which have well measured optical parameters. A broad line feature is detected ($>3\\sigma$) in the stacked spectra of the high $\\lambda_{Edd}$ sub-sample ($\\log\\lambda_{Edd}>-0.9$). The profile of the broad line can be well fitted with relativistic broad line model, with the line energy consistent with highly ionized Fe K$\\alpha$ line (i.e. Fe xxvi). A model consisting of multiple narrow lines cannot be ruled out, however. We found hints that the Fe K line becomes broader as the $\\lambda_{Edd}$ increases. No broad line feature is shown in the sub-sample of broad-line Seyfert 1 (BLS1) galaxies and in the full sample, while a broad line might be present, though at low significance, in the su...

  3. Microlensing of the Fe K$\\alpha$ line and the X-ray continuum

    CERN Document Server

    Popovic, L C; Mediavilla, E; Zakharov, A F; Abajas, C; Muñoz, J A; Chartas, G

    2005-01-01

    The observed enhancement of the Fe K$\\alpha$ line in three gravitationally lensed QSOs (MG J0414+0534, QSO 2237+0305, H1413+117) is interpreted in terms of microlensing, even when equivalent X-ray continuum amplification is not observed. In order to interpret these observations, first we studied the effects of microlensing on quasars spectra, produced by straight fold caustic crossing over standard relativistic accretion disk. The disk emission was analyzed using the ray tracing method, considering Schwarzschild and Kerr metrics. When the emission is separated in two regions (an inner disk corresponding to the Fe K$\\alpha$ line and an outer annulus corresponding to the continuum, or vice-versa) we find microlensing events which enhance the Fe K$\\alpha$ line without noticeable amplification of the X-ray continuum, but only during a limited time interval. Continuum amplification is expected if a complete microlensing event is monitored. Second, we studied a more realistic case of amplification by caustic magnif...

  4. Resolving the Composite Fe K-alpha Emission Line in the Galactic Black Hole Cygnus X-1 with Chandra

    CERN Document Server

    Miller, J M; Wijnands, R; Remillard, R A; Wojdowski, P S; Schulz, N S; Matteo, T D; Marshall, H L; Canizares, C R; Pooley, D; Lewin, W H G

    2002-01-01

    We observed the Galactic black hole Cygnus X-1 with the Chandra High Energy Transmission Grating Spectrometer for 30 kiloseconds on 4 January, 2001. The source was in an intermediate state, with a flux that was approximately twice that commonly observed in its persistent low/hard state. Our best-fit model for the X-ray spectrum includes narrow Gaussian emission line (E = 6.415 +/- 0.007 keV, FWHM = 80 (+28, -19) eV, W = 16 (+3, -2) eV) and broad line (E = 5.82 (+0.06, -0.07) keV, FWHM = 1.9 (+0.5, -0.3) keV, W = 140 (+70, -40) eV) components, and a smeared edge at 7.3 +/- 0.2 keV (tau ~ 1.0). The broad line profile is not as strongly skewed as those observed in some Seyfert galaxies. We interpret these features in terms of an accretion disk with irradiation of the inner disk producing a broad Fe K-alpha emission line and edge, and irradiation of the outer disk producing a narrow Fe K-alpha emission line. The broad line is likely shaped predominantly by Doppler shifts and gravitational effects, and to a lesser...

  5. The dust sublimation radius as an outer envelope to the bulk of the narrow Fe Kalpha line emission in Type 1 AGN

    CERN Document Server

    Gandhi, Poshak; Kishimoto, Makoto

    2015-01-01

    The Fe Kalpha emission line is the most ubiquitous feature in the X-ray spectra of active galactic nuclei (AGN), but the origin of its narrow core remains uncertain. Here, we investigate the connection between the sizes of the Fe Kalpha core emission regions and the measured sizes of the dusty tori in 13 local Type 1 AGN. The observed Fe Kalpha emission radii (R_fe) are determined from spectrally resolved line widths in X-ray grating spectra, and the dust sublimation radii (R_dust) are measured either from optical/near-infrared reverberation time lags or from resolved near-infrared interferometric data. This direct comparison shows that the dust sublimation radius forms an outer envelope to the bulk of the Fe Kalpha emission. R_fe matches R_dust well in the AGN with the best constrained line widths currently. In a significant fraction of objects without a clear narrow line core, R_fe is similar to, or smaller than the radius of the optical broad line region. These facts place important constraints on the toru...

  6. On the equivalent width of the Fe K$\\alpha$ line produced by a dusty absorber in active galactic nuclei

    CERN Document Server

    Gohil, Raj

    2015-01-01

    Obscured AGNs provide an opportunity to study the material surrounding the central engine. Geometric and physical constraints on the absorber can be deduced from the reprocessed AGN emission. In particular, the obscuring gas may reprocess the nuclear X-ray emission producing a narrow Fe K$\\alpha$ line and a Compton reflection hump. In recent years, models of the X-ray reflection from an obscuring torus have been computed; however, although the reflecting gas may be dusty, the models do not yet take into account the effects of dust on the predicted spectrum. We study this problem by analyzing two sets of models, with and without the presence of dust, using the one dimensional photo-ionization code Cloudy. The calculations are performed for a range of column densities ($22 <{\\rm log}[N_H(\\rm cm^{-2})]< 24.5$ ) and hydrogen densities ( $6 <{\\rm log}[n_H(\\rm cm^{-3})]< 8$). The calculations show the presence of dust can enhance the Fe K$\\alpha$ equivalent width (EW) in the reflected spectrum by factor...

  7. X-ray resonant photoexcitation: line widths and energies of K{\\alpha} transitions in highly charged Fe ions

    CERN Document Server

    Rudolph, J K; Epp, S W; Steinbrügge, R; Beilmann, C; Brown, G V; Eberle, S; Graf, A; Harman, Z; Hell, N; Leutenegger, M; Müller, A; Schlage, K; Wille, H -C; Yavas, H; Ullrich, J; López-Urrutia, J R Crespo

    2013-01-01

    Photoabsorption by and fluorescence of the K{\\alpha} transitions in highly charged iron ions are essential mechanisms for X-ray radiation transfer in astrophysical environments. We study photoabsorption due to the main K{\\alpha} transitions in highly charged iron ions from heliumlike to fluorinelike (Fe 24+...17+) using monochromatic X-rays around 6.6 keV at the PETRA III synchrotron photon source. Natural linewidths were determined with hitherto unattained accuracy. The observed transitions are of particular interest for the understanding of photoexcited plasmas found in X-ray binaries and active galactic nuclei.

  8. A Relativistic Fe K-alpha Emission Line in the Intermediate Luminosity BeppoSAX Spectrum of the Galactic Microquasar V4641 Sgr

    CERN Document Server

    Miller, J M; in 't Zand, J J M; Reynolds, C S; Wijnands, R; Nowak, M A; Lewin, W H G

    2002-01-01

    Broad Fe K-alpha emission lines have recently been reported in a number of Galactic black holes. Such lines are useful accretion flow diagnostics because they may be produced at the inner accretion disk and shaped by relativistic effects, but in general they have only been observed at luminosities of L_X = 10^(37-38) erg/s in soft X-rays. The Galactic microquasar V4641 Sgr -- widely known for its 12.2 Crab (1.5-12 keV) outburst in 1999 September -- displayed low-level activity in 1999 March. BeppoSAX observed the source in this state and Fe K-alpha line emission was found (in 't Zand et al. 2000). In re-analyzing these data, we find strong evidence that the Fe K-alpha line profile is broadened. For the most likely values of the source distance and black hole mass measured by Orosz et al. (2001), our fits to the total spectrum indicate that the source was observed at a luminosity of L_X = 1.9 (+1.0, -0.8) * 10^(36) erg/s (2-10 keV), or L_(2-10)/L_(Eddington) = 1.8 (+0.9, -0.8) * 10^(-3). Advection-dominated ac...

  9. An intense and broad FeKalpha line observed in the X-ray luminous quasar Q0056-363 with XMM-Newton

    CERN Document Server

    Porquet, D; Porquet, Delphine

    2003-01-01

    We present an XMM-Newton observation of the radio-quiet quasar Q0056-363 (z=0.162). This is the first time that this quasar is observed in the hard X-ray range (above 2 keV). We find that Q0056-363 is a powerful X-ray quasar, with a 0.3-12 keV unabsorbed luminosity of about 1.2 x 10^45 erg s-1 with the largest part (~67%) emitted below 2 keV. The spectrum reveals a large featureless soft X-ray excess below 2 keV and a strong broad FeKalpha line at 6.4 keV (in the quasar frame). The FeK alpha line is due to low to moderate ionization states of iron (i.e., < Fe XVII), with an equivalent width of about 250 eV and a velocity width of about 25,000 km s-1. Q0056-363 is presently the most luminous AGN known to exhibit such a broad and intense FeKalpha line profile from near neutral iron. The line can be fitted with a relativistic profile from an accretion disc around either a Schwarzschild (non-rotating) or a Kerr (rotating) black hole. A combination of two thermal Comptonization components and a disc reflection ...

  10. The ASCA X-Ray Spectrum Of The Broad-Line Radio Galaxy Pictor A A Simple Power Law With No Fe K-$\\alpha$ Line

    CERN Document Server

    Eracleous, M; Eracleous, Michael; Halpern, Jules P.

    1998-01-01

    We present the X-ray spectrum of the broad-line radio galaxy Pictor A as observed by ASCA in 1996. The main objective of the observation was to detect and study the profiles of the Fe~K$\\alpha$ lines. The motivation was the fact that the Balmer lines of this object show well-separated displaced peaks, suggesting an origin in an accretion disk. The 0.5-10 keV X-ray spectrum is described very well by a model consisting of a power law of photon index 1.77 modified by interstellar photoelectric absorption. We find evidence for neither a soft nor a hard (Compton reflection) excess. More importantly, we do not detect an Fe K-alpha line, in marked contrast with the spectra of typical Seyfert galaxies and other broad-line radio galaxies observed by ASCA. The 99%-confidence upper limit on the equivalent width of an unresolved line at a rest energy of 6.4 keV is 100 eV, while for a broad line (FWHM of approximately 60,000 km/s) the corresponding upper limit is 135 eV. We discuss several possible explanations for the we...

  11. A redshifted Fe K$\\alpha$ line from the unusual gamma-ray source PMN J1603-4904

    CERN Document Server

    Müller, C; Dauser, T; Kreikenbohm, A; Beuchert, T; Kadler, M; Ojha, R; Wilms, J; Böck, M; Carpenter, B; Markowitz, A; McConville, W; Pottschmidt, K; Stawarz, L; Taylor, G B

    2015-01-01

    Multiwavelength observations have revealed the highly unusual properties of the gamma-ray source PMN J1603-4904, which are difficult to reconcile with any other well established gamma-ray source class. The object is either a very atypical blazar or compact jet source seen at a larger angle to the line of sight. In order to determine the physical origin of the high-energy emission processes in PMN J1603-4904, we study the X-ray spectrum in detail. We performed quasi-simultaneous X-ray observations with XMM-Newton and Suzaku in 2013 September, resulting in the first high signal-to-noise X-ray spectrum of this source. The 2-10 keV X-ray spectrum can be well described by an absorbed power law with an emission line at 5.44$\\pm$0.05 keV (observed frame). Interpreting this feature as a K{\\alpha} line from neutral iron, we determine the redshift of PMN J1603-4904 to be z=0.18$\\pm$0.01, corresponding to a luminosity distance of 872$\\pm$54 Mpc. The detection of a redshifted X-ray emission line further challenges the or...

  12. The narrow Fe K$\\alpha$ line and the molecular torus in active galactic nuclei - an IR/X-ray view

    CERN Document Server

    Ricci, Claudio; Ichikawa, Kohei; Paltani, Stephane; Boissay, Rozenn; Gandhi, Poshak; Stalevski, Marko; Awaki, Hisamitsu

    2014-01-01

    The narrow component of the iron K$\\alpha$ is an almost ubiquitous feature in the X-ray spectra of active galactic nuclei (AGN) and is believed to originate in neutral material, possibly located in the molecular torus. This would imply a tight connection between the Fe K$\\alpha$ equivalent width (EW) and the physical properties of the torus. In a recent work we have shown that the decrease of the covering factor of the torus with the luminosity, as expected by luminosity-dependent unification models, would be able to explain the decrease of Fe K$\\alpha$ EW with the luminosity (i.e., the X-ray Baldwin effect). Recent developments in the study of the mid-IR (MIR) spectrum of AGN allow important parameters of the torus to be deduced, such as its covering factor ($f_{\\rm\\,obs}$) and equatorial column density ($N_{\\rm\\,H}^{\\rm\\,T}$), by applying clumpy torus models. Using XMM-Newton/EPIC observations of a sample of 24 type-I AGN, we investigate the relation between the physical parameters of the torus obtained by ...

  13. Comment on "The dust sublimation radius as an outer envelope to the bulk of the narrow Fe K$\\alpha$ line emission in Type 1 AGN"

    CERN Document Server

    Minezaki, Takeo

    2015-01-01

    Recently, Gandhi, H\\"onig, and Kishimoto submitted a manuscript to the arXiv e-print service on the location of the emitting region of the narrow FeK$\\alpha $ line that appears in the X-ray spectra of active galactic nuclei (AGNs) compared with the inner radius of the dust torus (arXiv:1502.02661). Prior to their manuscript, a similar discussion had already been presented in a section of Minezaki & Matsushita (2015), which had been accepted for publication in the Astrophysical Journal. Because Gandhi et al. made no reference to Minezaki & Matsushita (2015) apart from improperly citing it merely as an application of the dust reverberation of AGNs, we present a brief comparison of both papers. Gandhi et al. compared the location of the FeK$\\alpha$ emitting region with the individually measured radius of the dust torus for type 1 AGNs, whereas Minezaki & Matsushita (2015) examined it based on the scaling relation of the dust reverberation radius for both type 1 and type 2 AGNs. Nevertheless, Gandhi e...

  14. Variable Iron K-alpha Lines in Seyfert 1 Galaxies

    CERN Document Server

    Weaver, K A; Yaqoob, T

    2001-01-01

    We find that variability of the iron K-alpha line is common in Seyfert 1 galaxies. Using data from the ASCA archive for objects that have been observed more than once during the mission, we study the time-averaged spectra from individual observations, thereby probing variability on timescales that range from days to years. Since the statistics of the data do not warrant searches for line variability in terms of a complex physical model, we use a a simple Gaussian to model the gross shape of the line, and then use the centroid energy, intensity and equivalent width as robust indicators of changes in the line profile. We find that ~70% of Seyfert 1s (ten out of fifteen) show variability in at least one of these parameters: the centroid energy, intensity, and equivalent width vary in six, four, and eight sources respectively. Due to the low S/N, limited sampling and time averaging, we consider these results to represent lower limits to the rate of incidence of variability. In most cases changes in the line do no...

  15. Iron K$\\alpha$ line of boson stars

    CERN Document Server

    Cao, Zheng; Zhou, Menglei; Bambi, Cosimo; Herdeiro, Carlos A R; Radu, Eugen

    2016-01-01

    The present paper is a sequel to our previous work [Y. Ni et al., JCAP 1607, 049 (2016)] in which we studied the iron K$\\alpha$ line expected in the reflection spectrum of Kerr black holes with scalar hair. These metrics are solutions of Einstein's gravity minimally coupled to a massive, complex scalar field. They form a continuous bridge between a subset of Kerr black holes and a family of rotating boson stars depending on one extra parameter, the dimensionless scalar hair parameter $q$, ranging from 0 (Kerr black holes) to 1 (boson stars). Here we study the limiting case $q=1$, corresponding to rotating boson stars. For comparison, spherical boson stars are also considered. We simulate observations with XIS/Suzaku. Using the fact that current observations are well fit by the Kerr solution and thus requiring that acceptable alternative compact objects must be compatible with a Kerr fit, we find that some boson star solutions are relatively easy to rule out as potential candidates to explain astrophysical bla...

  16. Fe K$\\alpha$ Profiles from Simulations of Accreting Black Holes

    CERN Document Server

    Kinch, Brooks E; Kallman, Timothy R; Krolik, Julian H

    2016-01-01

    We present first results from a new technique for the prediction of Fe K$\\alpha$ profiles directly from general relativistic magnetohydrodynamic (GRMHD) simulations. Data from a GRMHD simulation are processed by a Monte Carlo global radiation transport code, which determines the X-ray flux irradiating the disk surface and the coronal electron temperature self-consistently. With that irradiating flux and the disk's density structure drawn from the simulation, we determine the reprocessed Fe K$\\alpha$ emission from photoionization equilibrium and solution of the radiation transfer equation. We produce maps of the surface brightness of Fe K$\\alpha$ emission over the disk surface, which---for our example of a $10 M_\\odot$, Schwarzschild black hole accreting at $1\\%$ the Eddington value---rises steeply one gravitational radius outside the radius of the innermost stable circular orbit and then falls $\\propto r^{-2}$ at larger radii. We explain these features of the Fe K$\\alpha$ radial surface brightness profile as ...

  17. Simulations of the Fe K-alpha Energy Spectra from Gravitationally Microlensed Quasars

    CERN Document Server

    Krawczynski, Henric

    2016-01-01

    Chartas et al. (2012, 2016a,b) reported the discovery of multiple and energy variable peaks of the Fe K-alpha emission from the gravitationally lensed quasar RX J1131-1231. The authors explain the observations by the microlensing (produced by the stars of the lensing galaxy) of the emission from different regions of the accretion disk with different Doppler and gravitational frequency shifts. In this paper, we combine detailed simulations of the Fe K-alpha emission of the accretion disk in the Kerr spacetime of the black hole with calculations of the effect of gravitational microlensing on the observed energy spectra. The simulations give multiply peaked energy spectra similar to the observed ones. We explore the dependence of the spectral characteristics on black hole spin, accretion disk inclination, corona height, and microlensing amplification factor, and show that the measurements can be used to constrain these parameters. The detailed simulations described in this paper confirm the earlier constraints o...

  18. X-ray bumps, iron K-alpha lines, and X-ray suppression by obscuring tori in Seyfert galaxies

    Science.gov (United States)

    Krolik, Julian H.; Madau, Piero; Zycki, Piotr T.

    1994-01-01

    We investigate the X-ray spectral properties of unobscured type 1 and obscured type 2 Seyferts as predicted by the unified Seyfert scheme. We consider the reprocessing of X-ray photons by photoelectric absorption, iron fluorescence, and Compton downscattering in the obscuring tori surrounding these active nuclei, and compute by Monte Carlo methods the reprocessed spectra as a function of the viewing angle. Depending on the optical depth and shape of the torus, and on the viewing angle, the X-ray flux can be suppressed by substantial factors when our line of sight is obscured. We show that an immediate consequence of the existence of an obscuring thick torus is the production in the spectra of type 1 Seyfert galaxies of a bump in the continuum above 10-20 keV and an Fe K-alpha line with significant equivalent width. In those type 2 Seyferts for which the hard X-ray spectrum has been substantially suppressed, the equivalent width of the Fe K-alpha line in the transmitted spectrum can be very large.

  19. Revealing the broad iron Kalpha line in Cygnus X-1 through simultaneous XMM-Newton, RXTE, and INTEGRAL observations

    CERN Document Server

    Duro, Refiz; Grinberg, Victoria; Miškovičová, Ivica; Rodriguez, Jérôme; Tomsick, John; Hanke, Manfred; Pottschmidt, Katja; Nowak, Michael A; Kreykenbohm, Sonja; Bel, Marion Cadolle; Bodaghee, Arash; Lohfink, Anne; Kendziorra, Eckhard; Kirsch, Marcus G F; Staubert, Rüdiger; Wilms, Jörn

    2016-01-01

    We report on the analysis of the broad Fe Kalpha line feature of Cygnus X-1 in the spectra of four simultaneous hard intermediate state observations made with the X-ray Multiple Mirror mission (XMM-Newton), the Rossi X-ray Timing Explorer (RXTE), and the International Gamma-Ray Astrophysics Laboratory (INTEGRAL). The high quality of the XMM-Newton data taken in the Modified Timing Mode of the EPIC-pn camera provides a great opportunity to investigate the broadened Fe Kalpha reflection line at 6.4keV with a very high signal to noise ratio. The 4-500keV energy range is used to constrain the underlying continuum and the reflection at higher energies. We first investigate the data by applying a phenomenological model that consists of the sum of an exponentially cutoff power law and relativistically smeared reflection. Additionally, we apply a more physical approach and model the irradiation of the accretion disk directly from the lamp post geometry. All four observations show consistent values for the black hole ...

  20. Broad K$\\alpha$ iron line from accretion disks around traversable wormholes

    CERN Document Server

    Bambi, Cosimo

    2013-01-01

    It has been proposed that the supermassive black hole candidates at the centers of galaxies might be wormholes formed in the early Universe and connecting our Universe with other sister Universes. The analysis of the profile of the relativistic K$\\alpha$ iron line is currently the only available approach to probe the spacetime geometry around these objects. In this paper, I compute the expected K$\\alpha$ iron line in some wormhole spacetimes and I compare the results with the line produced around Kerr black holes. The line produced in accretion disks around non-rotating or very slow-rotating wormholes is relatively similar to the one expected around Kerr black holes with mid or high value of spin parameter and current observations are still marginally compatible with the possibility that the supermassive black hole candidates in galactic nuclei are these objects. For wormholes with spin parameter $a_* \\gtrsim 0.02$, the associated K$\\alpha$ iron line is instead quite different from the one produced around Ker...

  1. The Broad Iron K-alpha line of Cygnus X-1 as Seen by XMM-Newton in the EPIC-pn Modified Timing Mode

    Science.gov (United States)

    Duro, Refiz; Dauser, Thomas; Wilms, Jorn; Pottschmidt, Katja; Nowak, Michael A.; Fritz, Sonja; Kendziorra, Eckhard; Kirsch, Marcus G. F.; Reynolds, Christopher S.; Staubert, Rudiger

    2011-01-01

    We present the analysis of the broadened, flourescent iron K(alpha) line in simultaneous XMM-Newton and RXTE data from the black hole Cygnus X-I. The XMM-Newton data were taken in a modified version of the Timing Mode of the EPIC-pn camera. In this mode the lower energy threshold of the instrument is increased to 2.8 keV to avoid telemetry drop outs due to the brightness of the source, while at the same time preserving the signal to noise ratio in the Fe K(alpha) band. We find that the best-fit spectrum consists of the sum of an exponentially cut-off power-law and relativistically smeared, ionized reflection. The shape of the broadened Fe K(alpha) feature is due to strong Compton broadening combined with relativistic broadening. Assuming a standard, thin accretion disk, the black hole is close to maximally rotating. Key words. X-rays: binaries - black hole physics - gravitation

  2. Discovery of Red-Skewed K_alpha iron line in Cyg X-2 with Suzaku

    CERN Document Server

    Shaposhnikov, Nikolai; Laurent, Philippe

    2009-01-01

    We report on the Suzaku observation of neutron star low-mass X-ray binary Cygnus X-2 which reveals a presence of the iron K_alpha emission line. The line profile shows a significant red wing. This discovery increases the number of neutron star sources where red-skewed iron lines were observed and strongly suggests that this phenomenon is common not only in black holes but also in other types of accreting compact objects. We examine the line profile in terms of models which attribute its production to the relativistic effects due to reflection of X-ray radiation from a cold accretion disk and also as a result of the line formation in the extended wind/outflow configuration. Both models are able to adequately represent the observed line profile. We consider the results of line modeling in the context of subsecond variability. While we were unable to conclusively disqualify one of the models, we find that the wind paradigm has several advantages over the relativistic disk reflection model.

  3. K$\\alpha$ iron line profile from accretion disks around regular and singular exotic compact objects

    CERN Document Server

    Bambi, Cosimo

    2013-01-01

    The nature of the super-massive black hole candidates in galactic nuclei can be tested by analyzing the profile of the K$\\alpha$ iron line observed in their X-ray spectrum. In this paper, we consider the possibility that the spacetime in the immediate vicinity of these objects may be described by some non vacuum exact solutions of Einstein's equations resulting as the end-state of gravitational collapse. The vacuum far away portion of the spacetime is described by the Schwarzschild metric, while the interior part may be either regular or have a naked singularity at the center. The iron line generated around this class of objects has specific features, which can be used to distinguish such objects from Kerr black holes. In particular, their iron line cannot have the characteristic low-energy tail of the line generated from accretion disks around fast-rotating Kerr black holes. We can thus conclude that the super-massive black hole candidates whose spin parameter has been estimated to be close to 1 assuming the...

  4. XMM-Newton Observation of Fe K(alpha) Emission from a BAL QSO: Mrk 231

    Science.gov (United States)

    Turner, T. J.; Kraemer, S. B.

    2003-01-01

    We present results from a 20 ksec XMM-Newton observation of Mrk 231. EPIC spectral data reveal strong line emission due to Fe K alpha, which has rarely been detected in this class, as BAL QSOs are very faint in the X-ray band. The line energy is consistent with an origin in neutral Fe. The width of the line is equivalent to a velocity dispersion approximately 18,000 kilometers per second and thus the line may be attributed to transmission and/or reflection from a distribution of emitting clouds. If, instead, the line originates in the accretion disk then the line strength and flat X-ray continuum support some contribution from a reflected component, although the data disfavor a model where the hard X-ray band is purely reflected X-rays. The line parameters are similar to those obtained for the Fe Ka line detected in another BAL QSO, H1413 + 117.

  5. Iron K$\\alpha$ line of Kerr black holes with scalar hair

    CERN Document Server

    Ni, Yueying; Cardenas-Avendano, Alejandro; Bambi, Cosimo; Herdeiro, Carlos A R; Radu, Eugen

    2016-01-01

    Recently, a family of hairy black holes in 4-dimensional Einstein gravity minimally coupled to a complex, massive scalar field was discovered (Herdeiro & Radu, 2014). Besides the mass $M$ and spin angular momentum $J$, these objects are characterized by a Noether charge $Q$, measuring the amount of scalar hair, which is not associated to a Gauss law and cannot be measured at spatial infinity. Introducing a dimensionless scalar hair parameter $q$, ranging from 0 to 1, we recover (a subset of) Kerr black holes for $q=0$ and a family of rotating boson stars for $q=1$. In the present paper, we explore the possibility of measuring $q$ for astrophysical black holes with current and future X-ray missions. We study the iron K$\\alpha$ line expected in the reflection spectrum of such hairy black holes and we simulate observations with Suzaku and eXTP. As a proof of concept we show, by analyzing a sample of hairy black holes, that current observations can already rule out a region in the space of solutions, because ...

  6. The Seyfert 2 galaxy NGC 2110: hard X-ray emission observed by NuSTAR and variability of the iron K$\\alpha$ line

    CERN Document Server

    Marinucci, A; Bianchi, S; Lu, T N; Arevalo, P; Baloković, M; Ballantyne, D; Bauer, F E; Boggs, S E; Christensen, F E; Craig, W W; Gandhi, P; Hailey, C J; Harrison, F; Puccetti, S; Rivers, E; Walton, D J; Stern, D; Zhang, W

    2014-01-01

    We present NuSTAR observations of the bright Seyfert 2 galaxy NGC 2110 obtained in 2012, when the source was at the highest flux level ever observed, and in 2013, when the source was at a more typical flux level. We include archival observations from other X-ray satellites, namely XMM-Newton, Suzaku, BeppoSAX, Chandra and Swift. Simultaneous NuSTAR and Swift broad band spectra (in the 3-80 keV range) indicate a cutoff energy $E_{\\rm c}>210$ keV, with no detectable contribution from Compton reflection. NGC 2110 is one of the very few sources where no evidence for distant Compton thick scattering is found and, by using temporal information collected over more than a decade, we investigate variations of the iron K$\\alpha$ line on time scales of years. The Fe K$\\alpha$ line is likely the sum of two components: one constant (originating from distant Compton-thick material) and the other one variable and linearly correlated with the source flux (possibly arising from Compton-thin material much closer to the black h...

  7. Special relativistic effects on the strength of the fluorescent $K\\alpha$ iron line from black hole accretion disks

    CERN Document Server

    Reynolds, C S

    1997-01-01

    The broad iron K$\\alpha$ emission line, commonly seen in the X-ray spectrum of Seyfert nuclei, is thought to originate when the inner accretion disk is illuminated by an active disk-corona. We show that relative motion between the disk and the X-ray emitting material can have an important influence on the observed equivalent width (EW) of this line via special relativistic aberration and Doppler effects. We suggest this may be relevant to understanding why the observed EW often exceeds the prediction of the standard X-ray reflection model. Several observational tests are suggested that could disentangle these special relativistic effects from iron abundance effects.

  8. Wavelengths, oscillator strengths and radiative transition rates for K{alpha} lines in titanium x-ray spectra

    Energy Technology Data Exchange (ETDEWEB)

    Hu Feng; Wang Chuangke; Zhao Xuefeng [Research Center of Laser Fusion, China Academy of Engineering Physics, Mianyang 621900 (China); Yang Jiamin; Jiang Gang, E-mail: yjm70018@my-public.sc.cninfo.net [Institute of Atomic and Molecular Physics, Sichuan University, Chengdu 610064 (China)

    2011-06-15

    The oscillator strengths, line strengths and wavelengths are presented for all 1s-2p transitions in titanium ions. X-ray emission from titanium is extensively used, for example for diagnosis, in fusion experiments. The K{alpha} 1s-2p transitions are limited to transitions from helium-like to fluorine-like ion as the 2p subshell is filled beyond fluorine. While there are two 1s-2p transitions (1s{sup 2}S{sub 1/2}-2p{sup 2}P{sub 1/2} and 1s{sup 2}S{sub 1/2}-2p{sup 2}P{sub 3/2}) for hydrogen-like titanium, Ti{sup 20+}, the number varies depending on the number of electrons in the 2p subshell before and after the transition. For example, there are 35 1s-2p transitions giving the same number of K{alpha} lines for carbon-like titanium, Ti{sup 16+}. The present results are obtained from configuration interaction atomic structure calculations using the code GRASPVU, which includes relativistic effects in the Dirac-Fock approximation. The results have been benchmarked for a few ionic states. A comparison of our results with the very few transitions in the literature as well as those from other codes shows reasonable accuracy of the present results.

  9. Constraining possible variations of the fine structure constant in strong gravitational fields with the K$\\alpha$ iron line

    CERN Document Server

    Bambi, Cosimo

    2013-01-01

    Extensions of general relativity and theories aiming at unifying gravity with the forces of the Standard Model are usually characterized by new degrees of freedom and violations of the Einstein Equivalence Principle. The search for time and/or space variations of fundamental parameters like the fine structure constant $\\alpha$ tests the assumption of Local Position Invariance. In this letter, I show that the analysis of the K$\\alpha$ iron line observed in the X-ray spectrum of black holes can probe $\\alpha$ in gravitational potentials relative to Earth of $\\Delta \\phi \\approx 0.1$. From the measurements of the black hole in Cygnus X-1 reported in the literature, one obtains $|\\Delta \\alpha / \\alpha| \\lesssim 0.01$.

  10. Complex X-ray Absorption and the Fe K(alpha) Profile in NGC 3516

    Science.gov (United States)

    Turner, T. J.; Kraemer, S. B.; George, I. M.; Reeves, J. N.; Botorff, M. C.

    2004-01-01

    We present data from simultaneous Chandra, XMM-Newton and BeppoSAX observations of the Seyfert 1 galaxy NGC 3516, taken during 2001 April and November. We have investigated the nature of the very flat observed X-ray spectrum. Chandra grating data show the presence of X-ray absorption lines, revealing two distinct components of the absorbing gas, one which is consistent with our previous model of the UV/X-ray absorber while the other, which is outflowing at a velocity of approximately 1100 kilometers per second, has a larger column density and is much more highly ionized. The broad-band spectral characteristics of the X-ray continuum observed with XMM during 2001 April, reveal the presence of a third layer of absorption consisting of a very large column (approximately 2.5 x 10(exp 23) per square centimeter) of highly ionized gas with a covering fraction approximately 50%. This low covering fraction suggests that the absorber lies within a few 1t-days of the X-ray source and/or is filamentary in structure. Interestingly, these absorbers are not in thermal equilibrium with one another. The two new components are too highly ionized to be radiatively accelerated, which we suggest is evidence for a hydromagnetic origin for the outflow. Applying our model to the November dataset, we can account for the spectral variability primarily by a drop in the ionization states of the absorbers, as expected by the change in the continuum flux. When this complex absorption is accounted for we find the underlying continuum to be typical of Seyfert 1 galaxies. The spectral curvature attributed to the high column absorber, in turn, reduces estimates of the flux and extent of any broad Fe emission line from the accretion disk.

  11. Discovery of the Red-Skewed K-alpha Iron Line in Cyg X-2 with Suzaku

    Science.gov (United States)

    Shaposhnikov, Nikolai; Titarchuk, Lev; Laurent, Philippe

    2008-01-01

    We report on the Suzaku observation of neutron star low-mass X-ray binary Cygnus X-2 which reveals strong iron K-alpha emission line. The line profile shows a prominent red wing extending down to 4 keV. This discovery increases the number of neutron star sources where red-skewed iron lines were observed and strongly suggests that this phenomenon is common not only in black holes but also in other types of compact objects. We examine the line profile by fitting it with the model which attributes its production to the relativistic effects due to disk reflection of X-ray radiation. We also apply an alternative model where the red wing is a result of down-scattering effect of the first order with respect to electron velocity in the wind outflow. Both models describe adequately the observed line profile. However, the X-ray variability in a state similar to that in the Suzaku observation which we establish by analysing RXTE observation favors the wind origin of the line formation.

  12. The Seyfert 2 Galaxy NGC 2110: Hard X-Ray Emission Observed by NuStar and Variability of the Iron K-Alpha Line

    Science.gov (United States)

    Marinucci, A.; Matt, G.; Bianchi, S.; Lu, T. N.; Arevalo, P.; Balokovic, M.; Ballantyne, D.; Bauer, F. E.; Boggs, S. E.; Stern, D.; Zhang, William W.

    2014-01-01

    We present NuSTAR observations of the bright Seyfert 2 galaxy NGC 2110 obtained in 2012, when the source was at the highest flux level ever observed, and in 2013, when the source was at a more typical flux level. We include archival observations from other X-ray satellites, namely XMM-Newton, Suzaku, BeppoSAX, Chandra and Swift. Simultaneous NuSTAR and Swift broad band spectra (in the 3-80 keV range) indicate a cutoff energy E(sub c) greater than 210 keV, with no detectable contribution from Compton reflection. NGC 2110 is one of the very few sources where no evidence for distant Compton thick scattering is found and, by using temporal information collected over more than a decade, we investigate variations of the iron K(alpha) line on time scales of years. The Fe K alpha line is likely the sum of two components: one constant (originating from distant Compton-thick material) and the other one variable and linearly correlated with the source flux (possibly arising from Compton-thin material much closer to the black hole).

  13. The iron $K_\\alpha$ lines as a tool for magnetic field estimations in non-flat accretion flows

    CERN Document Server

    Zakharov, A F; Bao, Y

    2004-01-01

    Observations of AGNs and microquasars by ASCA, RXTE, Chandra and XMM-Newton indicate the existence of broad X-ray emission lines of ionized heavy elements in their spectra. Such spectral lines were discovered also in X-ray spectra of neutron stars and X-ray afterglows of GRBs. Recently, Zakharov et al. (MNRAS, 2003, 342, 1325) described a procedure to estimate an upper limit of the magnetic fields in regions from which X-ray photons are emitted. The authors simulated typical profiles of the iron $K_\\alpha$ line in the presence of magnetic field and compared them with observational data in the framework of the widely accepted accretion disk model. Here we further consider typical Zeeman splitting in the framework of a model of non-flat accretion flows, which is a generalization of previous consideration into non-equatorial plane motion of particles emitting X-ray photons. Using perspective facilities of space borne instruments (e.g. Constellation-X mission) a better resolution of the blue peak structure of iro...

  14. MCDF-RCI predictions for structure and width of $K\\alpha_{1,2}$ x-ray line of Al and Si

    CERN Document Server

    Kozioł, Karol

    2014-01-01

    Multiconfiguration Dirac-Fock and Relativistic Configuration Interaction methods have been employed to predict the structure and the width of $K\\alpha_{1,2}$ x-ray lines of Al and Si. The influences of electron correlation and inclusion of possible satellite contributions on spectra structure have been studied. The widths of $K$ and $L_{2,3}$ atomic levels of Al and Si have been also computed.

  15. Complex X-ray Absorption and the Fe Kalpha Profile in NGC 3516

    CERN Document Server

    Turner, T J; George, I M; Reeves, J N; Bottorff, M C

    2004-01-01

    We present data from simultaneous Chandra, XMM-Newton and BeppoSAX observations of the Seyfert 1 galaxy NGC 3516, taken during 2001 April and Nov. We have investigated the nature of the very flat observed X-ray spectrum. Chandra grating data show the presence of X-ray absorption lines, revealing two distinct components of the absorbing gas, one which is consistent with our previous model of the UV/X-ray absorber while the other, which is outflowing at a velocity of ~1100 km/s has a larger column density and is much more highly ionized. The broad-band spectral characteristics of the X-ray continuum observed with XMM during 2001 April, reveal the presence of a third layer of absorption consisting of a very large column (~2.5 x 10E23 cm^-2) of highly ionized gas with a covering fraction ~50%. This low covering fraction suggests that the absorber lies within a few lt-days of the X-ray source and/or is filamentary in structure. Interestingly, these absorbers are not in thermal equilibrium with one another. The two...

  16. Iron K$\\alpha$ emission in type-I and type-II Active Galactic Nuclei

    CERN Document Server

    Ricci, Claudio; Paltani, Stephane; Ichikawa, Kohei; Gandhi, Poshak; Awaki, Hisamitsu

    2014-01-01

    The narrow Fe K$\\alpha$ line is one of the main signatures of the reprocessing of X-ray radiation from the material surrounding supermassive black holes, and it has been found to be omnipresent in the X-ray spectra of active galactic nuclei (AGN). In this work we study the characteristics of the narrow Fe K$\\alpha$ line in different types of AGN. Using the results of a large Suzaku study we find that Seyfert 2s have on average lower Fe K$\\alpha$ luminosities than Seyfert 1s for the same 10-50 keV continuum luminosity. Simulating dummy Sy1s and Sy2s populations using physical torus models of X-ray reflected emission, we find that this difference can be explained by means of different average inclination angles with respect to the torus, as predicted by the unified model. Alternative explanations include differences in the intensities of Compton humps or in the photon index distributions. We show that the ratio between the flux of the broad and narrow Fe K$\\alpha$ line in the 6.35-6.45 keV range depends on the ...

  17. SMM observations of K-alpha radiation from fluorescence of photospheric iron by solar flare X-rays

    Science.gov (United States)

    Parmar, A. N.; Culhane, J. L.; Rapley, C. G.; Wolfson, C. J.; Acton, L. W.; Phillips, K. J. H.; Dennis, B. R.

    1984-01-01

    High-resolution Fe K-alpha spectra near 1.94 A observed during solar flares with the Bent Crystal Spectrometer on the Solar Maximum Mission are presented. The evidence for two possible excitation mechanisms, electron impact and fluorescence, is examined. It is found that the fluorescence mechanism satisfactorily describes the results, while the observations do not support electron collisional excitation of the Fe K-alpha transitions in low ionization stages (II-XII) of iron. Using Bai's model of the fluorescent excitation process, the photospheric iron abundance relative to that of hydrogen is estimated to be 5-6 x 10 to the -5th. The mean height of the soft X-ray source producing the K-alpha fluorescence is calculated on the basis of this model for about 40 large flares. The solar K-alpha lines are found to be about 25 percent wider than those measured in the laboratory. Weak line features observed at wavelengths shorter than that of the K-alpha lines are discussed.

  18. Sensitivity of the Fe K-alpha Compton shoulder to the geometry and variability of the X-ray illumination of cosmic objects

    CERN Document Server

    Odaka, Hirokazu; Takahashi, Tadayuki; Fabian, Andrew

    2016-01-01

    In an X-ray reflection spectrum, a tail-like spectral feature generated via Compton down-scattering, known as a Compton shoulder (CS), appears at the low-energy side of the iron K$\\alpha$ line. Despite its great diagnostic potential, its use as a spectral probe of the reflector has been seriously limited due to observational difficulties and modelling complexities. We revisit the basic nature of the CS by systematic investigation into its dependence on spatial and temporal parameters. The calculations are performed by Monte-Carlo simulations for sphere and slab geometries. The dependence is obtained in a two-dimensional space of column density and metal abundance, demonstrating that the CS solves parameter degeneration between them which was seen in conventional spectral analysis using photoelectric absorption and fluorescence lines. Unlike the iron line, the CS does not suffer from any observational dependence on the spectral hardness. The CS profile is highly dependent on the inclination angle of the slab g...

  19. Testing the space-time geometry around black hole candidates with the analysis of the broad K$\\alpha$ iron line

    CERN Document Server

    Bambi, Cosimo

    2012-01-01

    Astrophysical black hole candidates are thought to be the Kerr black holes predicted by General Relativity, but there is not yet a clear evidence that the geometry of the space-time around these objects is really described by the Kerr metric. In order to confirm the Kerr black hole hypothesis, we have to observe strong gravity features and check they are in agreement with the ones predicted by General Relativity. In this paper, I study what kind of information can be extracted by analyzing the broad K$\\alpha$ iron line, which is often seen in the X-ray spectrum of both stellar-mass and super-massive black hole candidates and whose shape is supposed to be strongly affected by the space-time geometry. I extend previous studies in the literature. It turns out that there is a strong degeneracy between the spin parameter and the deformation parameter; that is, the line emitted around a Kerr black hole with a certain spin can be very similar to the one coming from the space-time around a non-Kerr object with a quit...

  20. A disk wind interpretation of the strong Fe K{\\alpha} features in 1H 0707-495

    CERN Document Server

    Hagino, Kouichi; Done, Chris; Tomaru, Ryota; Watanabe, Shin; Takahashi, Tadayuki

    2015-01-01

    1H 0707-495 is the most convincing example of a supermassive black hole with an X-ray spectrum being dominated by extremely smeared, relativistic reflection. However, here we show that the iron features in its 2--10 keV spectrum are rather similar to the archetypal wind dominated source, PDS 456. We fit all the 2--10 keV spectra from 1H 0707-495 using the same wind model as used for PDS 456, but viewed at higher inclination so that the iron absorption line is broader but not so blueshifted. This gives a good overall fit to the data from 1H 0707-495, and an extrapolation of this model to higher energies also gives a good match to the NuSTAR data. Small remaining residuals may indicate that the emission from the wind is stronger than in PDS 456, consistent with the wider angle wind expected from a continuum driven wind from the super-Eddington mass accretion rate in 1H 0707-495. We suggest that the spectrum of 1H 0707-495 is sculpted more by absorption in a wind than by extreme relativistic effects in strong gr...

  1. A Suzaku Observation of the Low-Ionization Fe-Line Emission from RCW 86

    CERN Document Server

    Ueno, M; Kataoka, J; Bamba, A; Harrus, I; Hiraga, J; Hughes, J P; Kilbourne, C A; Koyama, K; Kokubun, M; Nakajima, H; Ozaki, M; Petre, R; Takahashi, T; Tanaka, T; Tomida, H; Yamaguchi, H; Ueno, Masaru; Sato, Rie; Kataoka, Jun; Bamba, Aya; Harrus, Ilana; Hiraga, Junko; Hughes, John P.; Kilbourne, Caroline A.; Koyama, Katsuji; Kokubun, Motohide; Nakajima, Hiroshi; Ozaki, Masanobu; Petre, Robert; Takahashi, Tadayuki; Tanaka, Takaaki; Tomida, Hiroshi; Yamaguchi, Hiroya

    2006-01-01

    The newly operational X-ray satellite Suzaku observed the southwestern quadrant of the supernova remnant (SNR) RCW 86 in February 2006 to study the nature of the 6.4 keV emission line first detected with the Advanced Satellite for Cosmology and Astronomy (ASCA). The new data confirm the existence of the line, localizing it for the first time; most of the line emission is adjacent and interior to the forward shock and not at the locus of the continuum hard emission. We also report the first detection of a 7.1 keV line that we interpret as the K-beta emission from low-ionization iron. The Fe-K line features are consistent with a non-equilibrium plasma of Fe-rich ejecta with n_{e}t <~ 10^9 cm^-3 s and kT_{e} ~ 5 keV. This combination of low n_{e}t and high kT_{e} suggests collisionless electron heating in an SNR shock. The Fe K-alpha line shows evidence for intrinsic broadening, with a width of 47 (34--59) eV (99% error region). The difference of the spatial distributions of the hard continuum above 3 keV and...

  2. Study of the Many Fluorescent Lines and the Absorption Variability in GX 301-2 with XMM-Newton

    Science.gov (United States)

    Fuerst, F.; Suchy, S.; Kreykenbohm, I.; Barragan, L.; Wilms, J.; Pottschmidt, K.; Caballero, I.; Kretschmar, P.; Ferrigno, C.; Rothschild, R. E.

    2011-01-01

    We present an in-depth study of the High Mass X-ray Binary (HMXB) GX 301-2 during its pre-periastron flare using data from the XMM-Newton satellite. The energy spectrum shows a power law continuum absorbed by a large equivalent hydrogen column on the order of 10(exp 24)/ sq cm and a prominent Fe K-alpha fluorescent emission line. Besides the Fe K-alpha line, evidence for Fe K-Beta, Ni K-alpha, Ni K-Beta, S K-alpha, Ar K-alpha, Ca K-alpha, and Cr K-alpha fluorescent lines is found. The observed line strengths are consistent with fluorescence in a cold absorber. This is the first time that Cr K-alpha is seen in emission in the X-ray spectrum of a HMXB. In addition to the modulation by the strong pulse period of approx 685 sec the source is highly variable and shows different states of activity. We perform time-resolved as well as pulse-to-pulse resolved spectroscopy to investigate differences between these states of activity. We find that fluorescent line fluxes are strongly variable and generally follow the overall flux. The N-H value is variable by a factor of 2, but not correlated to continuum normalization. We find an interval of low flux in the light curve in which the pulsations cease almost completely, without any indication of an increasing absorption column. We investigate this dip in detail and argue that it is most likely that during the dip the accretion ceased and the afterglow of the fluorescent iron accounted for the main portion of the X-ray flux. A similar dip was found earlier in RXTE data, and we compare our findings to these results.

  3. K-Alpha Emission Spectra From Non-Equilibrium Ionizing Plasmas

    Energy Technology Data Exchange (ETDEWEB)

    Jacobs, V L; Decaux, V; Beiersdorfer, P

    2004-12-16

    K{alpha} X-ray emission spectra from highly charged Fe ions have been theoretically predicted using a detailed and systematic spectral model. Account has been taken of the fundamental atomic radiative-emission processes associated with inner-shell electron collisional excitation and ionization, as well as dielectronic recombination. Particular emphasis has been directed at extreme non-equilibrium or transient-ionization conditions, which can occur in astrophysical and tokamak plasmas. Good agreement has been found in comparisons with spectral observations on the EBIT-II electron beam ion trap at the Lawrence Livermore National Laboratory. We have identified spectral features that can serve as diagnostics of the electron density, the line-formation mechanism, and the charge-state distribution.

  4. Relativistic Iron Line Emission from the Neutron Star Low-mass X-ray Binary 4U 1636-536

    OpenAIRE

    Pandel, Dirk; Kaaret, Philip; Corbel, Stephane

    2008-01-01

    We present an analysis of XMM-Newton and RXTE data from three observations of the neutron star LMXB 4U 1636-536. The X-ray spectra show clear evidence of a broad, asymmetric iron emission line extending over the energy range 4-9 keV. The line profile is consistent with relativistically broadened Fe K-alpha emission from the inner accretion disk. The Fe K-alpha line in 4U 1636-536 is considerably broader than the asymmetric iron lines recently found in other neutron star LMXBs, which indicates...

  5. A Fe K Line in GRB 970508

    Science.gov (United States)

    Protassov, R.; van Dyk, D.; Connors, A.; Kashyap, V.; Siemiginowska, A.

    2000-12-01

    We examine the x-ray spectrum of the afterglow of GRB 970508, analyzed for Fe line emission by Piro et al (1999, ApJL, 514, L73). This is a difficult and extremely important measurement: the detection of x-ray afterglows from γ -ray bursts is at best a tricky business, relying on near-real satellite time response to unpredictable events; and a great deal of luck in catching a burst bright enough for a useful spectral analysis. Detecting a clear atomic (or cyclotron) line in the generally smooth and featureless afterglow (or burst) emission not only gives one of the few very specific keys to the physics local to the emission region, but also provides clues or confirmation of its distance (via redshift). Unfortunately, neither the likelihood ratio test or the related F-statistic commonly used to detect spectral lines adhere to their nominal Chi square and F-distributions. Thus we begin by calibrating the F-statistic used in Piro et al (1999, ApJL, 514, L73) via a simulation study. The simulation study relies on a completely specified source model, i.e. we do Monte Carlo simulations with all model parameters fixed (so--called ``parametric bootstrapping''). Second, we employ the method of posterior predictive p-values to calibrate a LRT statistic while accounting for the uncertainty in the parameters of the source model. Our analysis reveals evidence for the Fe K line.

  6. Resonant Auger Destruction and Iron K-Alpha Spectra in Compact X-ray Sources

    OpenAIRE

    Liedahl, Duane A.

    2005-01-01

    We examine the effects of resonant Auger destruction in modifying the intensities and flux distributions of K-alpha spectra from iron L-shell ions. Applications include X-ray irradiated stellar winds in X-ray binaries and accretion disk atmospheres. Using detailed atomic models, we find that resonant Auger destruction is selective, in that only a subset of the emitted K-alpha lines is highly attenuated. We also show that that the local excitation conditions can have a dramatic effect on the K...

  7. X-ray fluorescent lines from the Compton-thick AGN in M5

    CERN Document Server

    Xu, Weiwei; Gou, Lijun; Liu, Jiren

    2015-01-01

    The cold disk/torus gas surrounding AGN emits fluorescent lines when irradiated by hard X-ray photons. The fluorescent lines of elements other than Fe and Ni are rarely detected due to their relative faintness. We report the detection of K$\\alpha$ lines of neutral Si, S, Ar, Ca, Cr, and Mn, along with the prominent Fe K$\\alpha$, Fe K$\\beta$, and Ni K$\\alpha$ lines, from the deep Chandra observation of the low-luminosity Compton-thick AGN in M51. The Si K$\\alpha$ line at 1.74 keV is detected at $\\sim3\\sigma$, the other fluorescent lines have a significance between 2 and 2.5 $\\sigma$, while the Cr line has a significance of $\\sim1.5\\sigma$. These faint fluorescent lines are made observable due to the heavy obscuration of the intrinsic spectrum of M51, which is revealed by Nustar observation above 10 keV. The hard X-ray continuum of M51 from Chandra and Nustar can be fitted with a power-law spectrum with an index of 1.8, reprocessed by a torus with an equatorial column density of $N_{\\rm H}\\sim7\\times10^{24}$ cm...

  8. Infrared [Fe II] Emission Lines from Radiative Atomic Shocks

    CERN Document Server

    Koo, Bon-Chul; Kim, Hyun-Jeong

    2016-01-01

    [Fe II] emission lines are prominent in the infrared (IR), and they are important diagnostic tools for radiative atomic shocks. We investigate the emission characteristics of [Fe II] lines using a shock code developed by Raymond (1979) with updated atomic parameters. We first review general characteristics of IR [Fe II] emission lines from shocked gas, and derive [Fe II] line fluxes as a function of shock speed and ambient density. We have compiled the available IR [Fe II] line observations of interstellar shocks and compare them to the ratios predicted from our model. The sample includes both young and old supernova remnants in the Galaxy and the Large Magellanic Cloud and several Herbig-Haro objects. We find that the observed ratios of IR [Fe II] lines generally fall on our grid of shock models, but the ratios of some mid-infrared lines, e.g., [Fe II] 35.35 um/[Fe II] 25.99 um, [Fe II] 5.340 um/[Fe II] 25.99 um, and [Fe II] 5.340 um/[Fe II] 17.94 um, are significantly offset from our model grid. We discuss ...

  9. X-ray spectral and temporal analysis of Narrow Line Seyfert 1 galaxy Was 61

    CERN Document Server

    Dou, Liming; Ai, Yanli; Yuan, Weimin; Zhou, Hongyan; Dong, Xiao-Bo

    2016-01-01

    We present an analysis of spectrum and variability of the bright reddened narrow line Seyfert 1 galaxy Was~61 using 90 ks archival {\\it XMM-Newton} data. The X-ray spectrum in 0.2-10 keV can be characterized by an absorbed power-law plus soft excess and an Fe K$\\alpha$ emission line. The power-law spectral index remains constant during the flux variation. The absorbing material is mildly ionized, with a column density of 3.2$\\times$10$^{21}$ cm$^{-2}$, and does not appear to vary during the period of the X-ray observation. If the same material causes the optical reddening (E(B-V)$\\simeq$0.6 mag), it must be located outside the narrow line region with a dust-to-gas ratio similar to the average Galactic value. We detect significant variations of the Fe K$\\alpha$ line during the observational period. A broad Fe K$\\alpha$ line at $\\simeq$6.7 keV with a width of $\\sim$0.6 keV is detected in the low flux segment of the first 40 ks exposure, and is absent in the spectra of other segments; a narrow Fe K$\\alpha$ emiss...

  10. MODELING THE Fe K LINE PROFILES IN TYPE I ACTIVE GALACTIC NUCLEI WITH A COMPTON-THICK DISK WIND

    Energy Technology Data Exchange (ETDEWEB)

    Tatum, M. M.; Turner, T. J. [Department of Physics, University of Maryland, Baltimore County, Baltimore, MD 21250 (United States); Sim, S. A. [Research School of Astronomy and Astrophysics, Mount Stromlo Observatory, Cotter Road, Weston Creek, ACT 2611 (Australia); Miller, L. [Department of Physics, University of Oxford, Denys Wilkinson Building, Keble Road, Oxford OX1 3RH (United Kingdom); Reeves, J. N.; Patrick, A. R. [Astrophysics Group, School of Physical and Geographical Sciences, Keele University, Keele, Staffordshire ST5 5BG (United Kingdom); Long, K. S. [Space Telescope Science Institute, 3700 San Martin Drive, Baltimore, MD 21218 (United States)

    2012-06-20

    We have modeled a small sample of Seyfert galaxies that were previously identified as having simple X-ray spectra with little intrinsic absorption. The sources in this sample all contain moderately broad components of Fe K-shell emission and are ideal candidates for testing the applicability of a Compton-thick accretion disk wind model to active galactic nucleus (AGN) emission components. Viewing angles through the wind allow the observer to see the absorption signature of the gas, whereas face-on viewing angles allow the observer to see the scattered light from the wind. We find that the Fe K emission line profiles are well described with a model of a Compton-thick accretion disk wind of solar abundances, arising tens to hundreds of gravitational radii from the central black hole. Further, the fits require a neutral component of Fe K{alpha} emission that is too narrow to arise from the inner part of the wind, and likely comes from a more distant reprocessing region. Our study demonstrates that a Compton-thick wind can have a profound effect on the observed X-ray spectrum of an AGN, even when the system is not viewed through the flow.

  11. HIGHLY IONIZED Fe-K ABSORPTION LINE FROM CYGNUS X-1 IN THE HIGH/SOFT STATE OBSERVED WITH SUZAKU

    Energy Technology Data Exchange (ETDEWEB)

    Yamada, S.; Yoshikawa, A.; Makishima, K. [Cosmic Radiation Laboratory, Institute of Physical and Chemical Research (RIKEN), Wako, Saitama 351-0198 (Japan); Torii, S.; Noda, H. [Department of Physics, University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033 (Japan); Mineshige, S. [Department of Astronomy, Kyoto University, Kitashirakawa-Oiwake-cho, Sakyo-ku, Kyoto 606-8502 (Japan); Ueda, Y. [Department of Physics, Kyoto University, Kitashirakawa-Oiwake-cho, Sakyo-ku, Kyoto 606-8502 (Japan); Kubota, A. [Department of Electronic Information Systems, Shibaura Institute of Technology, 307 Fukasaku, Minuma-ku, Saitama-shi, Saitama 337-8570 (Japan); Gandhi, P. [Institute of Space and Astronautical Science, JAXA, 3-1-1 Yoshinodai, Sagamiharas, 229-8510 Kanagawa (Japan); Done, C. [Department of Physics, Durham University, South Road, Durham DH1 3LE (United Kingdom)

    2013-04-20

    We present observations of a transient He-like Fe K{alpha} absorption line in Suzaku observations of the black hole binary Cygnus X-1 on 2011 October 5 near superior conjunction during the high/soft state, which enable us to map the full evolution from the start to the end of the episodic accretion phenomena or dips for the first time. We model the X-ray spectra during the event and trace their evolution. The absorption line is rather weak in the first half of the observation, but instantly deepens for {approx}10 ks, and weakens thereafter. The overall change in equivalent width is a factor of {approx}3, peaking at an orbital phase of {approx}0.08. This is evidence that the companion stellar wind feeding the black hole is clumpy. By analyzing the line with a Voigt profile, it is found to be consistent with a slightly redshifted Fe XXV transition, or possibly a mixture of several species less ionized than Fe XXV. The data may be explained by a clump located at a distance of {approx}10{sup 10-12} cm with a density of {approx}10{sup (-13)-(-11)} g cm{sup -3}, which accretes onto and/or transits the line of sight to the black hole, causing an instant decrease in the observed degree of ionization and/or an increase in density of the accreting matter. Continued monitoring for individual events with future X-ray calorimeter missions such as ASTRO-H and AXSIO will allow us to map out the accretion environment in detail and how it changes between the various accretion states.

  12. Collapsar Jets, Bubbles and Fe Lines

    CERN Document Server

    Mészáros, P

    2001-01-01

    According to collapsar models, gamma ray bursts are caused by relativistic jets that expel energy along the rotation axis of a collapsing stellar core. We discuss how the structure and time-dependence of such jets depends on the properties of the stellar envelope and the central engine. It takes a few seconds for the jet to bore its way through the core of the star; most of the energy output during that period goes into a cocoon of relativistic plasma surrounding the jet. This material subsequently forms a bubble of highly-magnetised plasma that would take several hours to expand, subrelativistically, through the extended envelope of a high-mass supergiant. Shock waves and magnetic dissipation in this plasma (where the internal fields could still be $10^5$ G) can contribute a non thermal UV/X-ray afterglow, and also excite Fe line emission from thermal gas, in addition to the standard power-law afterglow from the jet deceleration shock.

  13. Number Density Distribution of Near-Infrared Sources on a Sub-Degree Scale in the Galactic Center: Comparison with the Fe XXV Ka Line at 6.7 keV

    CERN Document Server

    Yasui, Kazuki; Yoshikawa, Tatsuhito; Nagatomo, Schun; Uchiyama, Hideki; Tsuru, Takeshi G; Koyama, Katsuji; Tamura, Motohide; Kwon, Jungmi; Sugitani, Koji; Schödel, Rainer; Nagata, Tetsuya

    2015-01-01

    The stellar distribution derived from an $H$ and $K_{\\mathrm S}$-band survey of the central region of our Galaxy is compared with the Fe XXV K$\\alpha$ (6.7 keV) line intensity observed with the Suzaku satellite. The survey is for the Galactic coordinates $|l| \\lesssim 3^{\\circ}.0$ and $|b| \\lesssim 1^{\\circ}.0$ (equivalent to 0.8 kpc $\\times$ 0.3 kpc for $R_0 = 8$ kpc), and the number-density distribution $N(K_{\\mathrm S,0}; l, b)$ of stars is derived using the extinction-corrected magnitude $K_{\\mathrm S,0}=10.5$. This is deep enough to probe the old red giant population and in turn to estimate the ($l$, $b$) distribution of faint X-ray point sources such as coronally active binaries and cataclysmic variables. In the Galactic plane ($b=0^{\\circ}$), $N(10.5; l, b)$ increases to the Galactic center as $|l|^{-0.30 \\pm 0.03}$ in the range of $-0^{\\circ}.1 \\geq l \\geq -0^{\\circ}.7$, but this increase is significantly slower than the increase ($|l|^{-0.44 \\pm 0.02}$ ) of the Fe XXV K$\\alpha$ line intensity. If nor...

  14. K-alpha X-rays from cosmic-ray oxygen. [subrelativistic interstellar oxygen ions

    Science.gov (United States)

    Pravdo, S. H.; Boldt, E. A.

    1975-01-01

    Equilibrium charge fractions are calculated for subrelativistic cosmic-ray oxygen ions in the interstellar medium. These are used to determine the expected flux of K-alpha rays arising from atomic processes for a number of different postulated interstellar oxygen spectra. Relation of these results to the diffuse X-ray background measured at the appropriate energy (about 0.6 keV) suggests an observable broadened line feature.

  15. The intrinsic line width of the Fe Ka line of AGN

    CERN Document Server

    Liu, Jiren

    2016-01-01

    X-ray fluorescent lines are unique features of the reflection spectrum of the cold torus when irradiated by the central AGN. Their intrinsic line widths can be used to probe the line-emitting region. The line widths of the Fe \\Ka line measured from the first order Chandra High Energy Grating (HEG) spectra are $3-5$ times larger than those measured with the Si \\Ka line for Circinus, Mrk 3, and NGC 1068. Because the observed Si \\Ka and Fe \\Ka lines are not necessarily coming from the same physical region, it is uncertain whether the line widths of the Fe \\Ka line are over-estimated or not. We measured the intrinsic line widths of the Fe \\Ka line of several nearby bright AGN using the second and third order Chandra HEG spectra, whose spectral resolutions are better than the first order data. We found the measured widths are all smaller than those from the first order data. The results clearly show that the widths of the Fe \\Ka line measured from the first order HEG data are over-estimated. It indicates that the ...

  16. A K-alpha x-ray source using high energy and high repetition rate laser system for phase contrast imaging.

    Science.gov (United States)

    Serbanescu, Cristina; Fourmaux, Sylvain; Kieffer, Jean-Claude; Kincaid, Russell; Krol, Andrzej

    2009-01-01

    K-alpha x-ray sources from laser produced plasmas provide completely new possibilities for x-ray phase-contrast imaging applications. By tightly focusing intense femtosecond laser pulses onto a solid target K-alpha x-ray pulses are generated through the interaction of energetic electrons created in the plasma with the bulk target. In this paper, we present a continuous and efficient Mo K-alpha x-ray source produced by a femtosecond laser system operating at 100 Hz repetition rate with maximum pulse energy of 110 mJ before compression. The source has an x-ray conversion efficiency of greater than 10(-5) into K-alpha line emission. In preparation for phase contrast imaging applications, the size of the resultant K-alpha x-ray emission spot has been also characterized. The source exhibits sufficient spatial coherence to observe phase contrast. We observe a relatively small broadening of the K-alpha source size compared to the size of the laser beam itself. Detailed characterization of the source including the x-ray spectrum and the x-ray average yield along with phase contrast images of test objects will be presented.

  17. Optimization of cold K-alpha emission using copper foams

    Science.gov (United States)

    Hussein, Amina; Hager, Jonathan; Flippo, Kirk

    2015-11-01

    Experiments were conducted at the Trident Laser Facility to increase the conversion efficiency of short-pulse, copper K-alpha x-ray backlighter sources. New target designs using copper foams are in development to investigate the role of underdense/near-critical density targets on the optimization of cold K-alpha emission. K-alpha emission was measured using Highly Ordered Pyrolytic Graphic (HOPG) and imaged with a toroidally bent quartz crystal to determine uniformity, spatial resolution and conversion efficiency of the new designs. Results from this experiment will help inform the development of short-pulse Cu K-alpha back-lighters on facilities like Omega, OmegaEP and the NIF, with a particular emphasis on creating advanced narrow-band backlighter sources capable of producing strong signal to noise with high x-ray fluxes.

  18. The weak neutral Fe fluorescence line and long-term X-ray evolution of the Compton-thick AGN in NGC 7674

    CERN Document Server

    Gandhi, P; Lansbury, G B; Stern, D; Alexander, D M; Bauer, F E; Bianchi, S; Boggs, S E; Boorman, P G; Brandt, W N; Brightman, M; Christensen, F E; Comastri, A; Craig, W W; Del Moro, A; Elvis, M; Guainazzi, M; Hailey, C J; Harrison, F A; Koss, M; Lamperti, I; Malaguti, G; Masini, A; Matt, G; Puccetti, S; Ricci, C; Rivers, E; Walton, D J; Zhang, W W

    2016-01-01

    We present NuSTAR X-ray observations of the active galactic nucleus (AGN) in NGC 7674. The source shows a flat X-ray spectrum, suggesting that it is obscured by Compton-thick gas columns. Based upon long-term flux dimming, previous work suggested the alternate possibility that the source is a recently switched-off AGN with the observed X-rays being the lagged echo from the torus. Our high-quality data show the source to be reflection-dominated in hard X-rays, but with a relatively weak neutral Fe Kalpha emission line (equivalent width [EW] of ~0.4 keV) and a strong Fe XXVI ionised line (EW~0.2 keV). We construct an X-ray light curve of NGC 7674 spanning 37 years and find that the observed 2-10 keV X-ray flux has remained constant for the past ~20 years. Light travel time arguments constrain the minimum radius of the reflector to be ~3.2 pc under the switched-off AGN scenario, ~30x larger than the expected dust sublimation radius, rendering this possibility unlikely. A combination of intrinsic fading and patch...

  19. The diagnostic potential of Fe lines applied to protostellar jets

    Energy Technology Data Exchange (ETDEWEB)

    Giannini, T.; Nisini, B.; Antoniucci, S. [INAF-Osservatorio Astronomico di Roma, via Frascati 33, I-00040 Monte Porzio Catone (Italy); Alcalá, J. M. [INAF-Osservatorio Astronomico di Capodimonte, via Moiariello 16, I-80131 Napoli (Italy); Bacciotti, F. [INAF-Osservatorio Astrofisico di Arcetri, Largo E. Fermi 5, I-50125 Firenze (Italy); Bonito, R.; Stelzer, B. [INAF-Osservatorio Astronomico di Palermo, Piazza del Parlamento 1, I-90134 Palermo (Italy); Podio, L. [UJF-Grenoble 1/CNRS-INSU, Institut de Planetologie et d' Astrophysique de Grenoble (IPAG) UMR 5274, Grenoble, F-38041 (France); Whelan, E. T. [Institut für Astronomie und Astrophysik, Kepler Center for Astro and Particle Physics, Eberhard Karls Universität, D-72076 Tübingen (Germany)

    2013-11-20

    We investigate the diagnostic capabilities of iron lines for tracing the physical conditions of shock-excited gas in jets driven by pre-main sequence stars. We have analyzed the 3000-25000 Å, X-shooter spectra of two jets driven by the pre-main sequence stars ESO-Hα 574 and Par-Lup 3-4. Both spectra are very rich in [Fe II] lines over the whole spectral range; in addition, lines from [Fe III] are detected in the ESO-Hα 574 spectrum. Non-local thermal equilibrium codes solving the equations of the statistical equilibrium along with codes for the ionization equilibrium are used to derive the gas excitation conditions of electron temperature and density and fractional ionization. An estimate of the iron gas-phase abundance is provided by comparing the iron lines emissivity with that of neutral oxygen at 6300 Å. The [Fe II] line analysis indicates that the jet driven by ESO-Hα 574 is, on average, colder (T {sub e} ∼ 9000 K), less dense (n {sub e} ∼ 2 × 10{sup 4} cm{sup –3}), and more ionized (x {sub e} ∼ 0.7) than the Par-Lup 3-4 jet (T {sub e} ∼ 13,000 K, n {sub e} ∼ 6 × 10{sup 4} cm{sup –3}, x {sub e} < 0.4), even if the existence of a higher density component (n {sub e} ∼ 2 × 10{sup 5} cm{sup –3}) is probed by the [Fe III] and [Fe II] ultra-violet lines. The physical conditions derived from the iron lines are compared with shock models suggesting that the shock at work in ESO-Hα 574 is faster and likely more energetic than the Par-Lup 3-4 shock. This latter feature is confirmed by the high percentage of gas-phase iron measured in ESO-Hα 574 (50%-60% of its solar abundance in comparison with less than 30% in Par-Lup 3-4), which testifies that the ESO-Hα 574 shock is powerful enough to partially destroy the dust present inside the jet. This work demonstrates that a multiline Fe analysis can be effectively used to probe the excitation and ionization conditions of the gas in a jet without any assumption on ionic abundances. The main

  20. On the transition rates of the Fe X and Fe XIV corona lines

    Energy Technology Data Exchange (ETDEWEB)

    Trabert, E

    2003-11-20

    Despite a considerable scatter of the theoretical predictions of the M1/E2 transition rate of the ''red iron line'' (FeX) in the solar corona, there is disagreement of all the results with the single measurement that used an electrostatic ion trap. Employing a heavy-ion storage ring for measuring the same transition in isoelectronic ions of Co, Ni, and Cu, the situation has been clarified, and a new data point for FeX can be determined by extrapolation. This result agrees with the basic atomic structure prediction for the line strength in combination with the experimental transition energy. For the ''green iron line'' (FeXIV), a recent measurement with an electron beam ion trap has resolved similar discrepancies.

  1. Accretion Disk Line Emission in AGN a Devil's Advocacy

    CERN Document Server

    Sulentic, J W; Dultzin-Hacyan, D

    1998-01-01

    We review the evidence for AGN optical and X-ray broad line emission from an accretion disk. We argue that there is little, if any, statistical evidence to support this assertion. The inconsistency is strongest for the rare class of Balmer profiles that show double peaks. The line profiles predicted by a simple illuminated disk model are often incompatible with the observations. We suggest that the Fe Kalpha line in Seyfert 1 galaxies, where a broad line is most often and most strongly detected, is actually a composite of two lines both with Gaussian profiles; one narrow/unshifted and the other broad/redshifted.

  2. The diagnostic potential of Fe lines applied to protostellar jets

    CERN Document Server

    Giannini, T; Antoniucci, S; Alcala', J M; Bacciotti, F; Bonito, R; Podio, L; Stelzer, B; Whelan, E T

    2013-01-01

    We investigate the diagnostic capabilities of the iron lines for tracing the physical conditions of the shock-excited gas in jets driven by pre-main sequence stars. We have analyzed the 300-2500 nm X-shooter spectra of two jets driven by the pre-main sequence stars ESO-Halpha 574 and Par-Lup 3-4. Both spectra are very rich in [FeII] lines over the whole spectral range; in addition, lines from [FeIII] are detected in the ESO-H\\alpha 574 spectrum. NLTE codes along with codes for the ionization equilibrium are used to derive the gas excitation conditions of electron temperature and density, and fractional ionization. The iron gas-phase abundance is provided by comparing the iron lines emissivity with that of [OI] 630 nm. The [FeII] lines indicate ESO-Halpha 574 jet is, on average, colder (T_e = 9000 K), less dense (n_e = 2 10^4 cm^-3) and more ionized (x_e = 0.7) than the Par-Lup 3-4 jet (T_e = 13000 K, n_e = 6 10^4 cm^-3, x_e < 0.4), even if the existence of a higher density component (n_e = 2 10^5 cm^-3) is...

  3. Constraining FeLoBAL outflows from absorption line variability

    CERN Document Server

    McGraw, S M; Hamann, F W; Capellupo, D M; Gallagher, S C; Brandt, W N

    2015-01-01

    FeLoBALs are a rare class of quasar outflows with low-ionization broad absorption lines (BALs), large column densities, and potentially large kinetic energies that might be important for `feedback' to galaxy evolution. In order to probe the physical properties of these outflows, we conducted a multiple-epoch, absorption line variability study of 12 FeLoBAL quasars spanning a redshift range between 0.7 and 1.9 over rest frame time-scales of approximately 10 d to 7.6 yr. We detect absorption line variability with greater than 8 sigma confidence in 3 out of the 12 sources in our sample over time-scales of 0.6 to 7.6 yr. Variable wavelength intervals are associated with ground and excited state Fe II multiplets, the Mg II 2796, 2803 doublet, Mg I 2852, and excited state Ni II multiplets. The observed variability along with evidence of saturation in the absorption lines favors transverse motions of gas across the line of sight (LOS) as the preferred scenario, and allows us to constrain the outflow distance from th...

  4. Detectivity of FeLines in Gamma-Ray Bursts by Cerenkov Line Mechanism

    Institute of Scientific and Technical Information of China (English)

    SU Jie; JIN Sheng-Zhen

    2005-01-01

    @@ The Felines in gamma-ray bursts (GRBs) produced with the Cerenkov line mechan ism are studied. We theoretically predict the Feline luminosities in both the early (before 1 hour) and late (~ 1 day) afterglows. Assuming about 200 GRBs could be detected by Swift per year, we sampled the redshift of these GRBs using the Monte Carlo method according to the GRB formation rate derived from the statistical correlation between the spectral peak energy and the peak luminosity of GRBs.

  5. Spatial and Temporal Variations of the Diffuse Iron 6.4 keV Line in the Galactic Center Region

    CERN Document Server

    Chernyshov, D O; Nobukawa, M; Tsuru, T G; Koyama, K; Uchiyama, H; Matsumoto, H

    2011-01-01

    We analyze the diffuse Fe I K-alpha line generated in the diffuse interstellar molecular hydrogen by primary photons or subrelativistic protons injected by Sagittarius (Sgr) A*. We showed that unlike emission from compact molecular clouds, this emission can be permanently observed in the directions of the Galactic center. We conclude that the diffuse emission of 6.4 keV line observed at present is probably due to Fe I K-alpha vacancy production by primary photons if the X-ray luminosity of Sgr A* was about Lx ~ 10^39-10^40 erg/s. In principle these data can also be described in the framework of the model when the 6.4 keV line emission is generated by subrelativistic protons generated by accretion onto the central black hole but in this case extreme parameters of this model are necessary.

  6. Atomic Data and Spectral Line Intensities for fe XI

    Science.gov (United States)

    Bhatia, A. K.; Doschek, G. A.; Eissner, W.

    2002-11-01

    Electron impact collision strengths and spontaneous radiative decay rates are calculated for Fe XI. The data pertain to the 96 levels of the configurations 3s23p4, 3s3p5, 3s23p33d, 3p6, 3s23p34s, and 3s23p34d. Collision strengths are calculated at 10 incident electron energies: 1.0, 3.4, 6.0, 12.0, 15.0, 30.0, 45.0, 60.0, 75.0, and 90.0 Ry. These atomic data are generated to support the interpretation of spectra of astrophysical objects, which frequently contain emission lines from Fe XI and similar ions. This work supplements previous work published on Fe XI by extending the calculation of collision strengths and radiative decay rates to levels within n=4 configurations. Relative spectral line intensities are calculated for all astrophysically important transitions. These are obtained by computing the excitation rate coefficients (cm3 s-1), i.e., the collision strengths integrated over a Maxwellian electron distribution, and then solving the equations of detailed balance for the populations of the 96 energy levels, assuming a collisional excitation model and an electron temperature of 1.3×106 K. This temperature is typical for Fe XI when formed at equilibrium by collisional ionization and recombination. Using the excitation rate coefficients and the radiative decay rates, level populations are computed for several electron densities. The calculation of line intensities and level populations includes proton excitation because hydrogen is the most abundant element in astrophysical plasmas relevant to Fe XI emission.

  7. K-alpha X-rays from cosmic ray oxygen. [Detection and calculation of equilibrium charge fractions

    Science.gov (United States)

    Pravdo, S. H.; Boldt, E. A.

    1975-01-01

    Equilibrium charge fractions are calculated for subrelativistic cosmic ray oxygen ions in the interstellar medium. These are used to determine the expected flux of K-alpha rays arising from atomic processes for a number of different postulated interstellar oxygen spectra. Relating these results to the diffuse X-ray background measured at the appropriate energy level suggests an observable line feature. If the flux of low energy cosmic ray oxygen is sufficiently large, K-alpha X-ray line emission from these nuclei will comprise a significant fraction of the total diffuse flux at approximately 0.6 keV. A satellite borne detector with a resolution greater than 30 percent could observe this feature if the subrelativistic interstellar cosmic ray oxygen spectrum is as large as certain theoretical estimates expressed in the text.

  8. The broad Fe K line profile in NGC 4151

    CERN Document Server

    Wang, J; Wang, T; Wang, Junxian.; Zhou, Youyuan.; Wang, Tinggui.

    1999-01-01

    We present an analysis of the Fe K line profile of NGC 4151 by using long ASCA observation data obtained in May 1995. The unprecedented good data quality, which is much better in the energy band around 6.4 keV than that of the famous 4.2-day ASCA observation of MCG -6-30-15 in July 1994, offers a unique opportunity to study the details of Fe K line profile. Apart from those characteristics already noticed in earlier ASCA observations on this object (Yaqoob et al. 1995): a broad and skewed profile, with a strong peak at about 6.4 keV and a large red wing extending to $\\sim$4 - 5 keV, which is remarkably similar to that of MCG -6-30-15, we also find a weak blue wing extending to about 8 keV, thanks to the good quality of the data. When fitted by a relativistic accretion disk line plus a narrow core at 6.4 keV, the data constrain the accretion disk to be nearly face-on, contrary to the edge-on geometry inferred from optical and UV observations. However, the extended blue wing can not be well fitted even after we...

  9. The Weak Fe Fluorescence Line and Long-Term X-Ray Evolution of the Compton-Thick Active Galactic Nucleus in NGC7674

    Science.gov (United States)

    Ghandi, P.; Annuar, A.; Lansbury, G. B.; Stern, D.; Alexander, D. M.; Bauer, F. E.; Bianchi, S.; Boggs, S. E.; Boorman, P. G.; Brandt, W. N.; hide

    2017-01-01

    We present NuSTAR X-ray observations of the active galactic nucleus (AGN) in NGC7674.The source shows a flat X-ray spectrum, suggesting that it is obscured by Compton-thick gas columns. Based upon long-term flux dimming, previous work suggested the alternate possibility that the source is a recently switched-off AGN with the observed X-rays being the lagged echo from the torus. Our high-quality data show the source to be reflection-dominated in hard X-rays, but with a relatively weak neutral Fe K(alpha) emission line (equivalent width [EW] of approximately 0.4 keV) and a strong Fe XXVI ionized line (EW approximately 0.2 keV).We construct an updated long-term X-ray light curve of NGC7674 and find that the observed 2-10 keV flux has remained constant for the past approximately 20 yr, following a high-flux state probed by Ginga. Light travel time arguments constrain the minimum radius of the reflector to be approximately 3.2 pc under the switched-off AGN scenario, approximately 30 times larger than the expected dust sublimation radius, rendering this possibility unlikely. A patchy Compton-thick AGN (CTAGN) solution is plausible, requiring a minimum line-of-sight column density (N(sub H)) of 3 x 10(exp 24) cm(exp -2) at present, and yields an intrinsic 2-10 keV luminosity of (3-5) x 10(exp 43) erg s(exp -1). Realistic uncertainties span the range of approximately (1-13) x 10(exp 43) erg s1. The source has one of the weakest fluorescence lines amongst bona fide CTAGN, and is potentially a local analogue of bolometrically luminous systems showing complex neutral and ionized Fe emission. It exemplifies the difficulty of identification and proper characterization of distant CTAGN based on the strength of the neutral Fe K line

  10. THE CONNECTIONS BETWEEN THE UV AND OPTICAL Fe ii EMISSION LINES IN TYPE 1 AGNs

    Energy Technology Data Exchange (ETDEWEB)

    Kovacević-Dojcinović, Jelena; Popović, Luka Č., E-mail: jkovacevic@aob.bg.ac.rs, E-mail: lpopovic@aob.bg.ac.rs [Astronomical Observatory, Volgina 7, 11060 Belgrade (Serbia)

    2015-12-15

    We investigate the spectral properties of the UV (λλ2650–3050 Å) and optical (λλ4000–5500 Å) Fe ii emission features in a sample of 293 Type 1 active galactic nuclei (AGNs) from the Sloan Digital Sky Survey database. We explore different correlations between their emission line properties, as well as the correlations with other emission lines from the spectral range. We find several interesting correlations and outline the most interesting results as follows. (i) There is a kinematical connection between the UV and optical Fe ii lines, indicating that the UV and optical Fe ii lines originate from the outer part of the broad line region, the so-called intermediate line region. (ii) The unexplained anticorrelations of the optical Fe ii equivalent width (EW Fe ii{sub opt}) versus EW [O iii] 5007 Å and EW Fe ii{sub opt} versus FWHM Hβ have not been detected for the UV Fe ii lines. (iii) The significant averaged redshift in the UV Fe ii lines, which is not present in optical Fe ii, indicates an inflow in the UV Fe ii emitting clouds, and probably their asymmetric distribution. (iv) Also, we confirm the anticorrelation between the intensity ratio of the optical and UV Fe ii lines and the FWHM of Hβ, and we find the anticorrelations of this ratio with the widths of Mg ii 2800 Å, optical Fe ii, and UV Fe ii. This indicates a very important role for the column density and microturbulence in the emitting gas. We discuss the starburst activity in high-density regions of young AGNs as a possible explanation of the detected optical Fe ii correlations and intensity line ratios of the UV and optical Fe ii lines.

  11. Suzaku Monitoring of the Iron K Emission Line in the Type 1 AGN NGC 5548

    CERN Document Server

    Liu, Yuan; McHardy, Ian M; Grupe, Dirk; Wilkes, Belinda J; Reeves, James; Brickhouse, Nancy; Krongold, Yair; Mathur, Smita; Minezaki, Takeo; Nicastro, Fabrizio; Yoshii, Yuzuru; Zhang, Shuang Nan

    2010-01-01

    We present 7 sequential weekly observations of NGC 5548 conducted in 2007 with the \\textit{Suzaku} X-ray Imaging Spectrometer (XIS) in the 0.2-12 keV band and Hard X-ray Detector (HXD) in 10-600 keV band. The iron K$\\alpha$ line is well detected in all seven observations and K$\\beta$ line is also detected in four observations. In this paper, we investigate the origin of the Fe K lines using both the width of the line and the reverberation mapping method. With the co-added XIS and HXD spectra, we identify Fe K$\\alpha$ and K$\\beta$ line at 6.396$_{-0.007}^{+0.009}$ keV and 7.08$_{-0.05}^{+0.05}$ keV, respectively. The width of line obtained from the co-added spectra is 38$_{-18}^{+16}$ eV ($\\textrm{FWHM}=4200_{-2000}^{+1800}$ km/s) which corresponds to a radius of 20$_{-10}^{+50}$ light days, for the virial production of $1.220\\times10^7$ M$_{\\odot}$ in NCG 5548. To quantitatively investigate the origin of the narrow Fe line by the reverberation mapping method, we compare the observed light curves of Fe K$\\alph...

  12. An extreme Fe II emitter the narrow line quasar PHL 1092

    CERN Document Server

    Bergeron, J

    1980-01-01

    A search for Fe II emission in a sample of radio-quiet quasars has revealed the outstanding properties of PHL 1092. Intense Fe II lines dominate the entire spectrum, and the Fe II UV multiplets are nearly as strong as the optical ones. In contrast the extreme weakness of the Balmer and Mg II lines is striking. For the first time, Fe I lines are identified in an extra-galactic object. The lines are narrow, with a FWHM of 1300 km s/sup -1/. The presence of Fe II UV lines and Fe I lines from the ground state requires moderate column densities. However Fe/sup 0/ can exist only in a region completely shielded from the UV continuum. The weakness of Mg II and H beta relative to Fe II lines is best explained by their thermalization. The emitting region is of high electron density n/sub e/ approximately=10/sup 12/ cm/sup -3/, low temperature T approximately=10000K, and has an optical depth in the Fe II UV lines tau /sub UV/ approximately=10/sup 3/-10/sup 4/. It is speculated that for higher densities all the lines wou...

  13. Discovery of strong Iron K{\\alpha} emitting Compton thick quasars at z=2.5 and 2.9

    CERN Document Server

    Feruglio, C; Fiore, F; Alexander, D M; Piconcelli, E; Malacaria, C

    2011-01-01

    We report the detection of the 6.4 keV Iron K{\\alpha} emission line in two infrared-luminous, massive, star-forming BzK galaxies at z = 2.578 and z = 2.90 in the CDF-S. The Chandra 4 Ms spectra of BzK4892 and BzK8608 show a reflection dominated continuum with strong Iron lines, with rest-frame equivalent widths EW-2.3 keV and 1.2 keV, respectively, demonstrating Compton thick obscuration of the central AGN. For BzK8608 the line identification closely matches the existing photometric redshift derived from the stellar emission. We use the observed luminosities of the Iron K{\\alpha} line, of the rest-frame mid-IR continuum and of the UV rest-frame narrow emission lines to infer intrinsic L(2-10 keV)>1e44 erg/s, about 1.0-2.5 dex larger than the observed ones, hence confirming the presence of an absorber with N(H) > 1e24 cm-2. The two BzK galaxies have stellar masses of 5e10 M\\odot and, based on VLA 1.4 GHz and submm 870{\\mu}m observations, they appear to host vigorous starburst activity with SFR - 300-700 M\\odot...

  14. Intensity ratio measurements for density sensitive lines of highly charged Fe ions

    Energy Technology Data Exchange (ETDEWEB)

    Ali, Safdar, E-mail: safdaruetian@gmail.com; Shimizu, Erina [Institute for Laser Science, The University of Electro-Communications (Japan); Sakaue, Hiroyuki A.; Kato, Daiji; Murakami, Izumi [National Institute for Fusion Science (Japan); Yamamoto, Norimasa [Chubu University (Japan); Hara, Hirohisa; Watanabe, Tetsuya [The Graduate University of Advanced Studies (SOKENDAI) (Japan); Nakamura, Nobuyuki, E-mail: n-nakamu@ils.uec.ac.jp [Institute for Laser Science, The University of Electro-Communications (Japan)

    2015-11-15

    Intensity ratio of density sensitive emission lines emitted from Fe ions in the extreme ultraviolet region is important for astrophysics applications. We report high-resolution intensity ratio measurements for Fe ions performed at Tokyo EBIT laboratory by employing a flat-field grazing incidence spectrometer. The experimental intensity ratios of Fe X and Fe XII are plotted as a function of electron density for different electron beam currents. The experimental results are compared with the predicted intensity ratios from the model calculations.

  15. Astrophysical Lasers Operating in optical Fe II Lines Lines in Stellar Ejecta of Eta Carinae

    CERN Document Server

    Johansson, S

    2004-01-01

    After the discovery of space masers based on OH radicals (Weaver et al, 1965) and H2O (Cheung et al, 1969) such microwave lasers have been found to work in more than 100 molecular species (Elitzur, 1992; Townes, 1997), as well as in highly excited H atoms (Strelnitski et al,1996). In the IR region (10 microns), the effect of stimulated emission of radiation in the CO2 molecule has been discovered in the Martian and Venus' atmospheres (Betz et al, 1976; Mumma et al, 1981). We report here on the discovery of laser action in the range 0.9-2 micr. in several spectral lines of Fe II, which are associated with transitions from "pseudo-metastable" states populated by spontaneous transitions from Ly-alpha pumped Fe II levels. The intense Ly-alpha radiation is formed in the HII region of gas condensations close to the star Eta Carinae. The laser transitions form together with spontaneous transitions closed radiative cycles, one of which includes the extremely bright 2507/09 A lines. Closed radiative cycles, together w...

  16. Ultra-fast Measurements of Optically Induced Lattice Dynamics in LuMnO3 Using Aluminum K-alpha X-Ray Diffraction.

    Science.gov (United States)

    Workman, J.; Wark, J. S.

    2005-10-01

    An experiment to study the structural dynamics at the ultra-fast time scale in optically-pumped samples is presented. Measurements of lattice dynamics in LuMnO3 are presented and compared to calculations using dynamical diffraction theory modified for hexagonal crystal structure. Ultra-fast x-ray emission is used to measure Bragg peak shifts using diffraction and compared to calculations. Results are presented for optical pump energy densities of 8 and 20-mJ/cm^2. The experiment uses ˜150 mJ of a 100fs Ti:Sapphire laser to excite K-alpha x-ray emission in an aluminum wire with ˜1-2% split off for the material pump. The x-ray emission is relayed using a spherical Quartz crystal to the sample target. Plans for experiments using Cu K-alpha emission to probe Fe samples will also be described.

  17. Evidence for Ionised Accretion Discs in Five Narrow-Line Seyfert 1 Galaxies

    CERN Document Server

    Ballantyne, D R; Fabian, A C

    2000-01-01

    (Abridged) We present the results of fitting ASCA spectra of six narrow-line Seyfert 1 (NLS1) galaxies with the ionised reflection models of Ross & Fabian (1993). We find that five of the galaxies (TONS 180, PKS 0558-504, Ark 564, Mrk 335 and PG 1244+026) are well fit by the ionised disc model, and these are often better fits than the alternative models considered. The sixth galaxy, NGC 4051, has additional spectral complexity that cannot be well described by a simple ionised disc model or any of the other alternative models. All six of the NLS1s we considered show evidence for a broad Fe Kalpha line, but none of the line centroids are consistent with emission from highly ionised Fe. This is most likely due to the line being redshifted because of relativistic effects. We note that sources with larger ionisation parameters tend to have larger Fe Kalpha EWs. We interpret this as evidence that ionised Fe features are making their presence felt in the spectra. Since most of our sources have steep spectra, hig...

  18. Excitation Cross Section Measurement for n=3 to n=2 Line Emission in Fe17+ to Fe23+

    Energy Technology Data Exchange (ETDEWEB)

    Chen, H; Gu, M F; Beiersdorfer, P; Boyce, K R; Brown, G V; Kahn, S M; Kelley, R L; Kilbourne, C A; Porter, F S; Scofield, J H

    2006-02-08

    The authors report the measurement of electron impact excitation cross sections for the strong iron L-shell 3 {yields} 2 lines of Fe XVIII through Fe XXIV at the EBIT-I electron beam ion trap using a crystal spectrometer and a 6 x 6 pixel array microcalorimeter. The cross sections were determined by direct normalization to the well established cross section of radiative electron capture through a sophisticated model analysis which results in the excitation cross section for 48 lines at multiple electron energies. They also studied the electron density dependent nature of the emission lines, which is demonstrated by the effective excitation cross section of the 3d {yields} 2p transition in Fe XXI.

  19. Electron Impact Excitation Cross Section Measurement for n=3 to n=2 Line Emission in Fe17+ to Fe23+

    Energy Technology Data Exchange (ETDEWEB)

    Chen, H; Beiersdorfer, P; Brown, G V; Scofield, J; Gu, M F; Kahn, S M; Boyce, K; Kelley, R; Kilbourne, C; Porter, F S

    2006-04-20

    We have measured the electron impact excitation cross sections for the strong iron L-shell 3 {yields} 2 lines of Fe XVIII to Fe XXIV at the EBIT-I electron beam ion trap using a crystal spectrometer and NASA-Goddard Space Flight Centers 6 x 6 pixel array microcalorimeter. The cross sections were determined by direct normalization to the well established cross section of radiative electron capture through a sophisticated model analysis which results in the excitation cross section for the strong Fe L-shell lines at multiple electron energies. This measurement is part of a laboratory X-ray astrophysics program utilizing the Livermore electron beam ion traps EBIT-I and EBIT-II.

  20. Laboratory Measurements of the X-ray Line Emission from Neon-like Fe XVII

    Science.gov (United States)

    Brown, G. V.; Beiersdorfer, P.; Chen, H.; Scofield, J. H.; Boyce, K. R.; Kelley, R. L.; Kilbourne, C. A.; Porter, F. S.; Gu, M. F.; Kahn, S. M.

    2006-01-01

    We have conducted a systematic study of the dominant x-ray line emission from Fe XVII. These studies include relative line intensities in the optically thin limit, intensities in the presence of radiation from satellite lines from lower charge states of iron, and the absolute excitation cross sections of some of the strongest lines. These measurements were conducted at the Lawrence Livermore National Laboratory electron beam ion trap facility using crystal spectrometers and a NASA-Goddard Space Flight Center microcalorimeter array.

  1. Suzaku Observations of Iron K-lines from the Intracluster Medium of the Coma Cluster

    CERN Document Server

    Sato, Takuya; Ota, Naomi; Sato, Kosuke; Nakazawa, Kazuhiro; Sarazin, Craig L

    2011-01-01

    The Coma cluster was observed with an X-ray Imaging Spectrometer (XIS) onboard Suzaku in six pointings, including the central X-ray peak region, the 14'west offset region, 30'and 34'north-west offset regions, and 44'and 60'south-west offset regions. Owing to its lower background level, Suzaku has better sensitivity to Fe K-alpha lines than other satellites. Using precise Fe line measurements, we studied the temperature structure, possible bulk motions, and iron abundance distributions in the intracluster medium (ICM). The observed spectra were well-represented by a single-temperature model, and two- or three- temperature model did not improve chi-square substantially. The temperature, derived from K-alpha line ratios of H-like and He-like Fe, agree with those derived from the single-temperature model. Because the line ratio is a steep function of temperature, the consistency supports the accuracy of temperature measurements conducted with Suzaku. Within the 34'region, the redshift derived from the central ene...

  2. NEW Fe I LEVEL ENERGIES AND LINE IDENTIFICATIONS FROM STELLAR SPECTRA

    Energy Technology Data Exchange (ETDEWEB)

    Peterson, Ruth C. [SETI Institute and Astrophysical Advances, 607 Marion Place, Palo Alto, CA 94301 (United States); Kurucz, Robert L., E-mail: peterson@ucolick.org [Harvard-Smithsonian Center for Astrophysics, 60 Garden Street, Cambridge, MA 02138 (United States)

    2015-01-01

    The spectrum of the Fe I atom is critical to many areas of astrophysics and beyond. Measurements of the energies of its high-lying levels remain woefully incomplete, however, despite extensive laboratory and solar analysis. In this work, we use high-resolution archival absorption-line ultraviolet and optical spectra of stars whose warm temperatures favor moderate Fe I excitation. We derive the energy for a particular upper level in Kurucz's semiempirical calculations by adopting a trial value that yields the same wavelength for a given line predicted to be about as strong as that of a strong unidentified spectral line observed in the stellar spectra, then checking the new wavelengths of other strong predicted transitions that share the same upper level for coincidence with other strong observed unidentified lines. To date, this analysis has provided the upper energies of 66 Fe I levels. Many new energy levels are higher than those accessible to laboratory experiments; several exceed the Fe I ionization energy. These levels provide new identifications for over 2000 potentially detectable lines. Almost all of the new levels of odd parity include UV lines that were detected but unclassified in laboratory Fe I absorption spectra, providing an external check on the energy values. We motivate and present the procedure, provide the resulting new energy levels and their uncertainties, list all the potentially detectable UV and optical new Fe I line identifications and their gf values, point out new lines of astrophysical interest, and discuss the prospects for additional Fe I energy level determinations.

  3. Fe-K Line Time variability and Ni abundance of Distant Reflector in Seyfert Galaxies

    CERN Document Server

    Fukazawa, Yasushi; Hayashi, Kazuma; Ohno, Masanori; Hiragi, Kazuyoshi; Noda, Hirofumi

    2016-01-01

    We have performed systematic studies of narrow Fe-K line (6.4 keV) flux variability and Ni-K line intensity for Seyfert galaxies, using {\\em Suzaku} and {\\em XMM-Newton} archival data. Significant Fe-K line variability of several tens percents was detected for a pair of observations separated by 1000--2000 days (Cen A, IC 4329 A, NGC 3516, and NGC 4151) and 158 days (NGC 3516). These timescales are larger by a factor of 10--100 than the inner radius of torus, consistent with the view that X-ray reflection by torus is a main origin of a narrow Fe-K line. Ni-K line was detected with $>2\\sigma$ level for the Circinus galaxy, Cen A, MRK 3, NGC 4388, and NGC 4151. A mean and variance of Ni-K$\\alpha$ to Fe-K$\\alpha$ line intensity ratio are 0.066 and 0.026, respectively. Comparing this with the Monte-Carlo simulation of reflection, Ni to Fe abundance ratio is 1.9$\\pm$0.8 solar. We discuss the results and possibility of Ni abundance enhancement.

  4. Excitation Cross Section Measurement for n=3 to n=2 Line Emission in Fe{sup 20+} to Fe{sup 23+}

    Energy Technology Data Exchange (ETDEWEB)

    Chen, H; Beiersdorfer, P; Scofield, J; Brown, G; Boyce, K; Kelley, R L; Kilbourne, C A; Porter, F S; Gu, M F; Kahn, S M

    2004-08-25

    Electron impact excitation cross sections have been measured for iron L-shell 3 {yields} 2 lines of FeXXI to FeXXIV at the EBIT-II electron beam ion trap using a crystal spectrometer and a 6 x 6-element array microcalorimeter. The cross sections were determined by direct normalization to the well established cross section of radiative electron capture and a summary of calculated energy dependent radiative recombination cross sections for electron capture into the ground state fine structure levels of Fe{sup 16+} to Fe{sup 23+} ions is given. The measurement results for 17 lines and their comparison with model calculations are presented. While agreement of the model calculations with experiment is good for most measured lines, significant discrepancies were found for a few lines, including the strongest line in Fe XXI.

  5. Discovery of Oxygen Kalpha X-ray Emission from the Rings of Saturn

    CERN Document Server

    Bhardwaj, A; Waite, J H; Gladstone, G R; Cravens, T E; Ford, P G; Bhardwaj, Anil; Elsner, Ronald F.; Cravens, Thomas E.; Ford, Peter G.

    2005-01-01

    Using the Advanced CCD Imaging Spectrometer (ACIS), the Chandra X-ray Observatory (CXO) observed the Saturnian system for one rotation of the planet (~37 ks) on 20 January, 2004, and again on 26-27 January, 2004. In this letter we report the detection of X-ray emission from the rings of Saturn. The X-ray spectrum from the rings is dominated by emission in a narrow (~130 eV wide) energy band centered on the atomic oxygen K-alpha fluorescence line at 0.53 keV. The X-ray power emitted from the rings in the 0.49-0.62 keV band is 84 MW, which is about one-third of that emitted from Saturn disk in the photon energy range 0.24-2.0 keV. Our analysis also finds a clear detection of X-ray emission from the rings in the 0.49-0.62 keV band in an earlier (14-15 April, 2003) Chandra ACIS observation of Saturn. Fluorescent scattering of solar X-rays from oxygen atoms in the H2O icy ring material is the likely source mechanism for ring X-rays, consistent with the scenario of solar photo-production of a tenuous ring oxygen at...

  6. The nature of a broad line radio galaxy: Simultaneous RXTE and Chandra HETG observations of 3C 382

    CERN Document Server

    Gliozzi, M; Eracleous, M; Yaqoob, T

    2007-01-01

    We present the results from simultaneous chandra and rxte observations of the X-ray bright Broad-Line Radio Galaxy (BLRG) 3C 382. The long (120 ks) exposure with chandra HETG allows a detailed study of the soft X-ray continuum and of the narrow component of the Fe Kalpha line. The rxte PCA data are used to put an upper limit on the broad line component and constrain the hard X-ray continuum. A strong soft excess below 1 keV is observed in the time-averaged HETG spectrum, which can be parameterized with a steep power law or a thermal model. The flux variability at low energies indicates that the origin of the soft excess cannot be entirely ascribed to the circumnuclear diffuse emission, detected by chandra on scales of 20-30 arcsec (22-33 kpc). A narrow (sigma<90 eV) Fe Kalpha line (with EW< 100 eV) is observed by the chandra HEG. Similar values for the line parameters are measured by the rxte PCA, suggesting that the contribution from a broad line component is negligible. The fact that the exposure is s...

  7. EMPIRICAL DETERMINATION OF EINSTEIN A-COEFFICIENT RATIOS OF BRIGHT [Fe II] LINES

    Energy Technology Data Exchange (ETDEWEB)

    Giannini, T.; Antoniucci, S.; Nisini, B.; Lorenzetti, D. [INAF-Osservatorio Astronomico di Roma, Via Frascati 33, I-00040 Monte Porzio Catone (Italy); Alcalá, J. M. [INAF-Osservatorio Astronomico di Capodimonte, Via Moiariello 16, I-80131 Napoli (Italy); Bacciotti, F.; Podio, L. [INAF-Osservatorio Astrofisico di Arcetri, Largo E. Fermi 5, I-50125 Firenze (Italy); Bonito, R.; Stelzer, B., E-mail: teresa.giannini@oa-roma.inaf.it [INAF-Osservatorio Astronomico di Palermo, Piazza del Parlamento 1, I-90134 Palermo (Italy)

    2015-01-01

    The Einstein spontaneous rates (A-coefficients) of Fe{sup +} lines have been computed by several authors with results that differ from each other by up to 40%. Consequently, models for line emissivities suffer from uncertainties that in turn affect the determination of the physical conditions at the base of line excitation. We provide an empirical determination of the A-coefficient ratios of bright [Fe II] lines that would represent both a valid benchmark for theoretical computations and a reference for the physical interpretation of the observed lines. With the ESO-Very Large Telescope X-shooter instrument between 3000 Å and 24700 Å, we obtained a spectrum of the bright Herbig-Haro object HH 1. We detect around 100 [Fe II] lines, some of which with a signal-to-noise ratios ≥100. Among these latter lines, we selected those emitted by the same level, whose dereddened intensity ratios are direct functions of the Einstein A-coefficient ratios. From the same X-shooter spectrum, we got an accurate estimate of the extinction toward HH 1 through intensity ratios of atomic species, H I  recombination lines and H{sub 2} ro-vibrational transitions. We provide seven reliable A-coefficient ratios between bright [Fe II] lines, which are compared with the literature determinations. In particular, the A-coefficient ratios involving the brightest near-infrared lines (λ12570/λ16440 and λ13209/λ16440) are in better agreement with the predictions by the Quinet et al. relativistic Hartree-Fock model. However, none of the theoretical models predict A-coefficient ratios in agreement with all of our determinations. We also show that literature data of near-infrared intensity ratios better agree with our determinations than with theoretical expectations.

  8. Solar Flare Termination Shock and Synthetic Emission Line Profiles of the Fe xxi 1354.08 Å Line

    Science.gov (United States)

    Guo, Lijia; Li, Gang; Reeves, Kathy; Raymond, John

    2017-09-01

    Solar flares are among the most energetic phenomena that occur in the solar system. In the standard solar flare model, a fast mode shock, often referred to as the flare termination shock (TS), can exist above the loop-top source of hard X-ray emissions. The existence of the TS has been recently related to spectral hardening of a flare’s hard X-ray spectra at energies >300 keV. Observations of the Fe xxi 1354.08 Å line during solar flares by the Interface Region Imaging Spectrograph (IRIS) spacecraft have found significant redshifts with >100 km s‑1, which is consistent with a reconnection downflow. The ability to detect such a redshift with IRIS suggests that one may be able to use IRIS observations to identify flare TSs. Using a magnetohydrodynamic simulation to model magnetic reconnection of a solar flare and assuming the existence of a TS in the downflow of the reconnection plasma, we model the synthetic emission of the Fe xxi 1354.08 line in this work. We show that the existence of the TS in the solar flare may manifest itself in the Fe xxi 1354.08 Å line.

  9. Empirical determination of Einstein A-coefficient ratios of bright [Fe II] lines

    CERN Document Server

    Giannini, T; Nisini, B; Lorenzetti, D; Alcala', J M; Bacciotti, F; Bonito, R; Podio, L; Stelzer, B

    2014-01-01

    The Einstein spontaneous rates (A-coefficients) of Fe^+ lines have been computed by several authors, with results that differ from each other up to 40%. Consequently, models for line emissivities suffer from uncertainties which in turn affect the determination of the physical conditions at the base of line excitation. We provide an empirical determination of the A-coefficient ratios of bright [Fe II] lines, which would represent both a valid benchmark for theoretical computations and a reference for the physical interpretation of the observed lines. With the ESO-VLT X-shooter instrument between 3,000 A, and 24,700 A, we obtained a spectrum of the bright Herbig-Haro object HH1. We detect around 100 [Fe II] lines, some of which with a signal-to-noise ratio > 100. Among these latter, we selected those emitted by the same level, whose de-reddened intensity ratio is a direct function of the Einstein A-coefficient ratios. From the same X-shooter spectrum, we got an accurate estimate of the extinction toward HH1 thr...

  10. Relativistic Feline study in Seyfert 1 galaxies observed with Suzaku

    Science.gov (United States)

    Mantovani, G.; Nandra, K.; Ponti, G.

    2016-06-01

    We present an analysis of a sample of Seyfert 1 galaxies observed with Suzaku. The aim of this work is to examine critically the evidence for a relativistic Feline in the X-ray spectra of these active galactic nuclei. The sample was compiled from those sources in which a relativistic component was missing in at least one XMM-Newton observation. We analysed the Suzaku spectra of these objects in order to have more constraints on the high-energy emission, including the Compton reflection hump. The results show that the relativistic Feline is detected (at >95 per cent confidence) in all sources observed with high-signal-to-noise ratio (e.g. where the counts in the 5-7 keV energy band are ≳4 × 104). This is in agreement with the idea that relativistic lines are a ubiquitous feature in the spectra of Seyfert galaxies, but are often difficult to detect without very high-quality data. We also investigate the relation between the Feline and the reflection continuum at high energies. For most of the sample, the strength of the reflection component is consistent with that of the line. There are exceptions in both senses, however i.e. where the reflection continuum is strong but with weak line emission, and vice versa. These observations present a challenge for standard reflection models.

  11. 5.9 keV Mn K-shell X-ray luminosity from the decay of 55Fe in Type Ia supernova models

    CERN Document Server

    Seitenzahl, I R; Krauss, F; Sim, S A; Diehl, R; Elsaesser, D; Fink, M; Hillebrandt, W; Kromer, M; Maeda, K; Mannheim, K; Pakmor, R; Roepke, F K; Ruiter, A J; Wilms, J

    2014-01-01

    We show that the X-ray line flux of the Mn Kalpha line at 5.9 keV from the decay of 55Fe is a promising diagnostic to distinguish between Type Ia supernova (SN Ia) explosion models. Using radiation transport calculations, we compute the line flux for two 3D explosion models: a near-Chandrasekhar mass delayed detonation and a violent merger of two white dwarfs. Both models are based on solar metallicity zero-age main sequence progenitors. Due to explosive nuclear burning at higher density, the delayed-detonation model synthesises 3.5 times more radioactive 55Fe than the merger model. As a result, we find that the peak Mn Kalpha line flux of the delayed-detonation model exceeds that of the merger model by a factor of 4.5. Since in both models the 5.9 keV X-ray flux peaks five to six years after the explosion, a single measurement of the X-ray line emission at this time can place a constraint on the explosion physics that is complementary to those derived from earlier phase optical spectra or light curves. We pe...

  12. New Fe I level energies and line identifications from stellar spectra

    CERN Document Server

    Peterson, Ruth C

    2014-01-01

    The spectrum of the Fe I atom is critical to many areas of astrophysics and beyond. Measurements of the energies of its high-lying levels remain woefully incomplete, however, despite extensive analysis of ultraviolet laboratory iron absorption spectra, optical laboratory iron emission spectra, and the solar infrared spectrum. In this work we use as sources the high-resolution archival absorption-line ultraviolet and optical spectra of stars, whose warm temperatures favor moderate Fe I excitation. We derive the energy for a particular upper level by adopting a trial value that yields the same wavelength for a given line predicted to be about as strong as that of a strong unidentified spectral line observed in the stellar spectra, then checking the new wavelengths of other strong predicted transitions that share the same upper level for coincidence with other strong observed unidentified lines. To date this analysis has provided the upper energies of 37 Fe I levels. Many new level energies are higher than those...

  13. Relativistic Fe K alpha line study in Seyfert 1 galaxies observed with Suzaku

    CERN Document Server

    Mantovani, Giulia; Ponti, Gabriele

    2016-01-01

    We present an analysis of a sample of Seyfert 1 galaxies observed with Suzaku. The aim of this work is to examine critically the evidence for a relativistic Fe K alpha line in the X-ray spectra of these AGN. The sample was compiled from those sources in which a relativistic component was missing in at least one XMM-Newton observation. We analysed the Suzaku spectra of these objects in order to have more constraints on the high energy emission, including the Compton reflection hump. The results show that the relativistic Fe K alpha line is detected (at >95% confidence) in all sources observed with high signal-to-noise ratio (e.g. where the counts in the 5-7 keV energy band are > 4 x 10^4). This is in agreement with the idea that relativistic lines are a ubiquitous feature in the spectra of Seyfert galaxies, but are often difficult to detect without very high quality data. We also investigate the relation between the Fe K alpha line and the reflection continuum at high energies. For most of the sample, the stre...

  14. Method for characterization of a spherically bent crystal for K.alpha. X-ray imaging of laser plasmas using a focusing monochromator geometry

    Science.gov (United States)

    Kugland, Nathan; Doeppner, Tilo; Glenzer, Siegfried; Constantin, Carmen; Niemann, Chris; Neumayer, Paul

    2015-04-07

    A method is provided for characterizing spectrometric properties (e.g., peak reflectivity, reflection curve width, and Bragg angle offset) of the K.alpha. emission line reflected narrowly off angle of the direct reflection of a bent crystal and in particular of a spherically bent quartz 200 crystal by analyzing the off-angle x-ray emission from a stronger emission line reflected at angles far from normal incidence. The bent quartz crystal can therefore accurately image argon K.alpha. x-rays at near-normal incidence (Bragg angle of approximately 81 degrees). The method is useful for in-situ calibration of instruments employing the crystal as a grating by first operating the crystal as a high throughput focusing monochromator on the Rowland circle at angles far from normal incidence (Bragg angle approximately 68 degrees) to make a reflection curve with the He-like x-rays such as the He-.alpha. emission line observed from a laser-excited plasma.

  15. CORONIUM IN THE LABORATORY: MEASURING THE Fe XIV GREEN CORONAL LINE BY LASER SPECTROSCOPY

    Energy Technology Data Exchange (ETDEWEB)

    Schnorr, K.; Mäckel, V.; Oreshkina, N. S.; Brunner, F.; Harman, Z.; Keitel, C. H.; Ullrich, J.; Crespo López-Urrutia, J. R. [Max-Planck-Institut für Kernphysik, Saupfercheckweg 1, D-69117 Heidelberg (Germany); Augustin, S. [Justus-Liebig-Univerität Giessen, Heinrich-Buff-Ring 16, D-35392 Giessen (Germany)

    2013-10-20

    The green coronal line at 530.3 nm was first observed during the total solar eclipse of 1869. Once identified as emitted by Fe XIV, it became clear that this highly charged ion was typical for the range of temperatures found in coronal plasmas, stellar winds, outflows, and accretion disks. Under these conditions of high ionization, the strongest transitions are in the X-ray, extreme ultraviolet, and ultraviolet wavelength range, with only few optical lines. For these so-called forbidden coronal lines, only scarce laboratory data is available, and even advanced atomic theory codes cannot yet predict their wavelengths with the accuracy required for precise absolute velocity determinations of such plasmas. Here we report on a study of the Fe XIV line, a key coronal transition of a highly charged ion, using laser spectroscopy in an electron beam ion trap, obtaining the first laboratory measurement of 530.2801(4) nm for its rest wavelength. The result enables the determination of absolute line shifts and line broadenings in hot turbulent plasmas and astrophysical environments, with an error bar of only 0.24 km s{sup –1}. In addition, our measurement provides a much-needed benchmark for advanced atomic structure calculations, which are fundamental for astronomy.

  16. UV and x-ray spectral lines of FeXXIII ion for plasma diagnostics

    CERN Document Server

    Murakami, I; Murakami, Izumi; Kato, Takako

    1996-01-01

    We have calculated X-ray and UV spectra of Be-like Fe (FeXXIII) ion in collisional-radiative model including all fine-structure transitions among the 2s^2, 2s2p, 2p^2, 2snl, and 2pnl levels where n=3 and 4, adopting data for the collision strengths by Zhang & Sampson (1992) and by Sampson, Goett, & Clark (1984). Some line intensity ratios can be used for the temperature diagnostics. We show 5 ratios in UV region and 9 ratios in X-ray region as a function of electron temperature and density at 0.3keV < T_e < 10keV and n_e = 1 - 10^{25} cm^{-3}. The effect of cascade in these line ratios and in the level population densities are discussed.

  17. Grazing incidence Fe-line telescopes using W/B4C multilayers

    DEFF Research Database (Denmark)

    Joensen, K. D.; Gorenstein, P.; Christensen, Finn Erland;

    1995-01-01

    The loss of throughput observed at higher energies for traditional grazing-incidence X-ray telescopes coated with high-Z elements can be partly countered by employing multilayers on the outermost reflectors. Using 8-keV reflectivity data from a periodic W/B4C multilayer, the expected performance ...... reflectors required by the Kirkpatrick-Baez telescope exists, so that an Fe-line multilayer telescope could be built today...

  18. Solar Flare Termination Shock and the Synthetic Fe XXI 1354.08 Å line

    Science.gov (United States)

    Guo, Lijia; Li, Gang; Reeves, Kathy

    2017-08-01

    Solar flares are one of the most energetic phenomena occurred in the solar system. In the standard solar flare model, a fast mode shock, which is often referred to as the flare termination shock (TS), can exist above the loop-top source of hard X-ray emissions. The existence of the termination shock has been recently related to spectral hardening of flare hard X-ray spectrum at energies > 300 keV. Observations of the Fe XXI 1354.08 Å line during solar flares by the IRIS spacecraft have found significant redshift with >100 km/s, which is consistent with a reconnection downflow. The ability to identify such a redshift by IRIS is made possible by IRIS's high time resolution, high spatial resolution, high sensitivity and cadence spectral observations. The ability to identify such a redshift by IRIS suggests that one may be able to use IRIS observations to identify flare termination shocks. Using an MHD simulation to model magnetic reconnection of a solar flare and assuming the existence of a TS in the downflow of the reconnection plasma, we model the synthetic emission of the Fe XXI 1354.08 Å line in this work. We show that the existence of the TS in the solar flare may manifest itself from the Fe XXI 1354.08 Å line.

  19. Study on Emission Spectral Lines of Iron, Fe in Laser-Induced Breakdown Spectroscopy (LIBS) on Soil Samples

    Science.gov (United States)

    Idris, Nasrullah; Lahna, Kurnia; Fadhli; Ramli, Muliadi

    2017-05-01

    In this work, LIBS technique has been used for detection of heavy metal especially iron, Fe in soil sample. As there are a large number of emission spectral lines due to Fe and other constituents in soil, this study is intended to identify emission spectral lines of Fe and finally to find best fit emission spectral lines for carrying out a qualitative and quantitative analysis. LIBS apparatus used in this work consists of a laser system (Neodymium Yttrium Aluminum Garnet, Nd-YAG: Quanta Ray; LAB SERIES; 1,064 nm; 500 mJ; 8 ns) and an optical multichannel analyzer (OMA) system consisting of a spectrograph (McPherson model 2061; 1,000 mm focal length; f/8.6 Czerny- Turner) and an intensified charge coupled device (ICCD) 1024x256 pixels (Andor I*Star). The soil sample was collected from Banda Aceh city, Aceh, Indonesia. For spectral data acquisition, the soil sample has been prepared by a pressing machine in the form of pellet. The laser beam was focused using a high density lens (f=+150 mm) and irradiated on the surface of the pellet for generating luminous plasma under 1 atmosphere of air surrounding. The plasma emission was collected by an optical fiber and then sent to the optical multichannel analyzer (OMA) system for acquisition of the emission spectra. It was found that there are many Fe emission lines both atomic lines (Fe I) and ionic lines (Fe II) appeared in all detection windows in the wavelength regions, ranging from 200 nm to 1000 nm. The emission lines of Fe with strong intensities occurs together with emission lines due to other atoms such as Mg, Ca, and Si. Thus, the identification of emission lines from Fe is complicated by presence of many other lines due to other major and minor elements in soil. Considering the features of the detected emission lines, several emission spectral lines of Fe I (atomic emission line), especially Fe I 404.58 nm occurring at visible range are potential to be good candidate of analytical lines in relation to detection

  20. Relations between forbidden line Fe/H and delta Mone for F and early-G stars

    Science.gov (United States)

    McNamara, D. H.; Powell, J. M.

    1985-11-01

    The new catalog of forbidden line Fe/H determinations of Cayrel de Strobel et al. (1985) have been used to calibrate forbidden line Fe/H in terms of the metal abundance parameter delta mone. Three relations were found corresponding to F1-F5 stars, F5-F8 stars, and F8-G2 stars. Quadratic equations were found necessary to represent the data of the two early groups. Serious errors in forbidden line Fe/H determinations of early metal-poor F stars can result if the previous linear calibrations are used.

  1. FeII/MgII Emission Line Ratio in High Redshift Quasars

    DEFF Research Database (Denmark)

    Dietrich, M.; Hamann, F.; Appenzeller, I.

    2003-01-01

    We present results of the analysis of near infrared spectroscopic observations of 6 high-redshift quasars (z > 4), emphasizing the measurement of the ultraviolet FeII/MgII emission line strength in order to estimate the beginning of intense star formation in the early universe. To investigate...... the evolution of the FeII/MgII ratio over a wider range in cosmic time, we measured this ratio for composite quasar spectra which cover a redshift range of 0 4 quasars must have started already at an epoch corresponding to z_f = 6 to 9, when the age of the universe was ~0.5 Gyr (H_o = 72 km/s/Mpc, Omega_M = 0...

  2. Stark width measurements of Fe II lines with wavelengths in the range 260-300 nm

    Energy Technology Data Exchange (ETDEWEB)

    Aragon, C; Aguilera, J A [Departamento de Fisica, Universidad Publica de Navarra, Campus de ArrosadIa, E-31006 Pamplona (Spain); Vega, P, E-mail: carlos.aragon@unavarra.es [Departamento de Fisica, Facultad de Ciencias, Universidad de Oviedo, C/Calvo Sotelo s/n, E-33007 Oviedo (Spain)

    2011-03-14

    The Stark widths of 21 Fe II lines with wavelengths in the range 260-300 nm have been measured using laser-induced plasmas as spectroscopic sources. A set of Fe-Cu samples has been employed to generate the plasmas. To reduce self-absorption, each line has been measured using a different sample, with an iron concentration determined by means of the curve-of-growth methodology. The remaining error due to self-absorption has been estimated to be lower than 10%. Different instants of the plasma evolution, from 0.84 to 2.5 {mu}s, are included in the measurements. The electron density, in the range (1.6-7.3) x 10{sup 17} cm{sup -3}, is determined by the Stark broadening of the H{sub {alpha}} line. Within this range, the Stark widths are found to be proportional to the electron density. The Boltzmann plot method is used to obtain the plasma temperature, which is in the range 12 900-15 200 K. The Stark widths obtained have been compared with available experimental and theoretical data.

  3. Broad Band X-Ray Observations of the Narrow Line X-Ray Galaxy NGC 5506

    CERN Document Server

    Wang, T G; Otani, C; Matsuoka, M; Awaki, H

    1999-01-01

    We present a detailed analysis of broad band X-ray data of the Seyfert 2 galaxy NGC5506. 2-10 keV band are detected during a 1-day ASCA observation, while no significant change in the 2-10 keV continuum shape is found. The ASCA spectrum consists of an absorbed power-law, a 'soft excess' below 2 keV, and an Fe K$\\alpha$ emission line at 6.4 keV. The 'soft excess' can be well described by either thermal emission from very low abundance material at a temperature kT$\\simeq$0.8 keV, or scattered/leaking flux from the primary power-law plus a small amount of thermal emission. Analysis of ROSAT HRI data reveals that the soft X-ray emission is extended on kpc scales in this object, and the extended component may account for most of the soft X-ray excess observed by the ASCA. The result suggests that in this type 2 AGN, the 'soft excess' at least partly comes from an extended region, imposing serious problem for the model in which the source is partially covered. Fe K$\\alpha$ profile is complex and can not be satisfac...

  4. Emission Lines of Fe XI - XIII in the Extreme Ultraviolet Region

    Science.gov (United States)

    Lepson, Jaan; Beiersdorfer, Peter; Liedahl, Duane; Desai, Priya; Brickhouse, Nancy; Dupree, Andrea; Kahn, Steven

    2009-05-01

    Iron is one of the most abundant heavy elements in extreme ultraviolet spectra of astrophysical and laboratory plasmas, and its various ions radiate profusely in the extreme ultraviolet (EUV) wavelength band. Iron emission in the EUV provides important d iagnostic tools for such properties as plasma temperature and density, and perhaps even magnetic field strength. Despite its importance to astrophysics and magnetic fusion, knowledge of the EUV spectrum of iron is incomplete. Identification of iron emis sion lines is hampered by the paucity of accurate laboratory measurements and the uncertainty of even the best atomic models. As part of a project to measure and compile emission line data in the EUV, we present here spectra and lines of Fe XI - XIII recorded on the Livermore EBIT-II electron beam ion trap in the 50 - 120 åregion. We measured line positions to 0.02 åand relative intensities with an accuracy of one part in twenty. Many new lines are identified and added to the available databa ses. Part of this work was performed under the auspices of the U S Department of Energy by Lawrence Livermore National Laboratory under Contract DE-AC52-07NA27344 and was supported by NASA's Astronomy and Physics Research and Analysis Program under Con t ract NNH07AF811.

  5. The Beam Line X NdFe-steel hybrid wiggler for SSRL

    Energy Technology Data Exchange (ETDEWEB)

    Hoyer, E.; Halbach, K.; Humphries, D.; Marks, S.; Plate, D.; Shuman, D.; Karpenko, V.P.; Kulkarni, S.; Tirsell, K.G.

    1987-03-10

    A wiggler magnet with 15 periods, each 12.85 cm long, which achieves 1.40 T at a 2.1 cm gap (2.26T at 0.8 cm) has been designed and is now in fabrication at LBL. This wiggler will be the radiation source of the high intensity synchrotron radiation beam line for the Beam Line X PRT facility at SSRL. The magnet utilizes Neodymium-Iron (NdFe) material and Vanadium Permendur (steel) in the hybrid configuration to achieve simultaneously a high magnetic field and short period. Magnetic field adjustment is with a driven chain and ball screw drive system. The magnetic structure is external to an s.s. vacuum chamber which has thin walls, 0.76 mm thickness, at each pole tip for higher field operation. Magnetic design, construction details and magnetic measurements are presented.

  6. Discoveries of Diffuse Iron Line Sources from the Sgr B Region

    CERN Document Server

    Koyama, K; Hyodo, Y; Matsumoto, H; Tsuru, T G; Maeda, Y; Murakami, H; Yamauchi, S; Kissel, S E; Soong, C Y; Koyama, Katsuji; Inui, Tatsuya; Hyodo, Yoshiaki; Matsumoto, Hironori; Tsuru, Takeshi Go; Maeda, Yoshitomo; Murakami, Hiroshi; Yamauchi, Shigeo; Kissel, Steven E.; Soong, Chan Yang

    2006-01-01

    The radio complex Sgr B region is observed with the X-Ray Imaging Spectrometers (XIS) on board Suzaku. This region exhibits diffuse iron lines at 6.4, 6.7 and 6.9 keV, which are K$\\alpha$ lines of Fe \\emissiontype{I} (neutral iron), Fe\\emissiontype{XXV} (He-like iron) and Fe\\emissiontype{XXVI} (H-like iron), respectively. The high energy resolving power of the XIS provides the separate maps of the K-shell transition lines from Fe\\emissiontype{I} (6.4 keV) and Fe\\emissiontype{XXV} (6.7 keV). Although the 6.7 keV line is smoothly distributed over the Sgr B region, a local excess is found near at $(l, b) = (\\timeform {0D.61}, \\timeform{0D.01})$, possibly a new SNR. The plasma temperature is \\textit{kT} $\\sim$3 keV and the age is estimated to be around several$\\times10^{3}$ years. The 6.4 keV image is clumpy with local excesses nearby Sgr B2 and at $(l, b) = (\\timeform{0D.74}, -\\timeform{0D.09})$. Like Sgr B2, this excess may be another candidate of an X-ray reflection nebula (XRN).

  7. The Stagger-grid: A grid of 3D stellar atmosphere models - V. Fe line shapes, shifts and asymmetries

    CERN Document Server

    Magic, Zazralt; Asplund, Martin

    2014-01-01

    We present a theoretical study of the effects and signatures of realistic velocity field and atmospheric inhomogeneities associated with convective motions at the surface of cool late-type stars on the emergent profiles of iron spectral lines for a large range in stellar parameters. We compute 3D spectral line flux profiles under the assumption of local thermodynamic equilibrium (LTE) by employing state-of-the-art, time-dependent, 3D, radiative-hydrodynamical atmosphere models from the Stagger-grid. A set of 35 real unblended, optical FeI and FeII lines of varying excitation potential are considered. Additionally, fictitious Fe i and Fe ii lines (5000A and 0, 2, 4 eV) are used to construct general curves of growth and enable comparison of line profiles with the same line strength to illustrate systematical trends stemming from the intrinsic structural differences among 3D model atmospheres with different stellar parameters. Theoretical line shifts and bisectors are derived to analyze the shapes, shifts, and a...

  8. Fe Line Diagnostics of Cataclysmic Variables and Galactic Ridge X-ray Emission

    CERN Document Server

    Xu, Xiao-jie; Li, Xiang-Dong

    2016-01-01

    The properties of the Galactic Ridge X-ray Emission (GRXE) observed in the 2-10 keV band place fundamental constraints on various types of X-ray sources in the Milky Way. Although the primarily discrete origin of the emission is now well established, the responsible populations of these sources remain uncertain, especially at relatively low fluxes. To provide insights into this issue, we systematically characterize the Fe emission line properties of the candidate types of the sources in the solar neighborhood and compare them with those measured for the GRXE. Our source sample includes 6 symbiotic stars (SSs), 16 intermediate polars (IPs), 3 polars, 16 quiescent dwarf novae (DNe) and 4 active binaries (ABs). We find that the mean equivalent width ($EW_{6.7}$) of the 6.7-keV line and the mean 7.0/6.7-keV line ratio are $107\\pm16.0$ eV and $0.71\\pm 0.04$ for intermediate polars and $221\\pm 135$ eV and $0.44\\pm 0.14$ for polars, respectively, which are all substantially different from those ($490\\pm15 $~eV and $...

  9. Evidence of Decay of Flux Ratio of Fe to Fe–Ni Line Features with Electron Temperature in Solar Flares

    Indian Academy of Sciences (India)

    Rajmal Jain; Malini Aggarwal; Raghunandan Sharma

    2010-09-01

    We report observational evidence of the decay of the flux ratio of Fe to Fe–Ni line features as a function of plasma electron temperature in solar flares in comparison to that theoretically predicted by Phillips (2004). We present the study of spectral analysis of 14 flares observed by the Solar X-ray Spectrometer (SOXS) – Low Energy Detector (SLD) payload. The SLD payload employs the state-of-the-art solid state detectors, viz., Si PIN and Cadmium-Zinc-Telluride (CZT) devices. The sub-keV energy resolution of Si PIN detector allows us to study the Fe-line and Fe–Ni line features appearing at 6.7 and 8 keV, respectively, in greater detail. In order to best-fit the whole spectrum at one time in the desired energy range between 4 and 25 keV we considered Gaussian-line, the multi-thermal power-law and broken power-law functions. We found that the flux ratio of Fe to Fe–Ni line features decays with flare electron temperature by the asymptotic form of polynomial of inverse third order. The relative flux ratio is ∼ 30 at temperature 12 MK which drops to half, ∼ 15 at 20 MK, and at further higher temperatures it decreases smoothly reaching to ∼ 8 at ∼ 50 MK. The flux ratio, however, at a given flare plasma temperature, and its decrease with temperature is significantly lower than that predicted theoretically. We propose that the difference may be due to the consideration of higher densities of Fe and Fe–Ni lines in the theoretical model of Phillips (2004). We suggest revising the Fe and Fe–Ni line densities in the corona. The decay of flux ratio explains the variation of equivalent width and peak energy of these line features with temperature.

  10. A search for supernova remnants in NGC 6946 using the [Fe II] 1.64 μm line

    Energy Technology Data Exchange (ETDEWEB)

    Bruursema, Justice; Meixner, Margaret [Department of Physics and Astronomy, The Johns Hopkins University, 3400 North Charles Street, Baltimore, MD 21218 (United States); Long, Knox S.; Otsuka, Masaaki, E-mail: justiceb@pha.jhu.edu [Space Telescope Science Institute, 3700 San Martin Drive, Baltimore, MD 21218 (United States)

    2014-09-01

    Shock models indicate and observations show that in the infrared (IR), supernova remnants (SNRs) emit strongly in [Fe II] at 1.64 μm. Here, we report the results of a search for SNRs in NGC 6946 relying on [Fe II] 1.64 μm line emission, where we employed an adjacent [Fe II]{sub Off} filter to accurately assess the local continuum levels. For this study, we used the WIYN High Resolution Infrared Camera on the WIYN 3.5 m telescope to image NGC 6946 in broadbands J and H and narrowbands [Fe II], [Fe II]{sub Off}, Paβ, and Paβ{sub Off}. From our search, we have identified 48 SNR candidates (SNRcs), 6 of which are coincident with sources found in prior radio, optical, and/or X-ray studies. The measured [Fe II] fluxes of our SNRcs range from 1.5 × 10{sup –16} to 4.2 × 10{sup –15} erg s{sup –1} cm{sup –2} and are among the highest of previously published extragalactic SNR [Fe II] fluxes. All of the candidates now need to be confirmed spectroscopically. However, the fact that we detect as many objects as we did suggests that [Fe II] can be used as an effective search tool to find extragalactic SNRs.

  11. Somatic Mutations in PI3Kalpha: Structural Basis for Enzyme Activation and Drug Design

    Energy Technology Data Exchange (ETDEWEB)

    S Gabelli; D Mandelker; O Schmidt-Kittler; B Vogelstein; L Amzel

    2011-12-31

    The PI3K pathway is a communication hub coordinating critical cell functions including cell survival, cell growth, proliferation, motility and metabolism. Because PI3K{alpha} harbors recurrent somatic mutations resulting in gains of function in human cancers, it has emerged as an important drug target for many types of solid tumors. Various PI3K isoforms are also being evaluated as potential therapeutic targets for inflammation, heart disease, and hematological malignancies. Structural biology is providing insights into the flexibility of the PI3Ks, and providing basis for understanding the effects of mutations, drug resistance and specificity.

  12. Using k-alpha emission to determine fast electron spectra using the Hybrid code ZEPHYROS

    CERN Document Server

    White, Thomas; Gregori, Gianluca

    2014-01-01

    A high intensity laser-solid interaction invariably drives a non-thermal fast electron current through the target, however characterizing these fast electron distributions can prove difficult. An understanding of how these electrons propagate through dense materials is of fundamental interest and has applications relevant to fast ignition schemes and ion acceleration. Here, we utilize an upgraded version of the Hybrid code ZEPHYROS to demonstrate how the resulting k-alpha emission from such an interaction can be used as a diagnostic to obtain the characteristic temperature, divergence and total energy of the fast electron population.

  13. K-alpha conversion efficiency measurments for x-ray scattering in inertial confinement fusion plasmas

    Energy Technology Data Exchange (ETDEWEB)

    Kritcher, A L; Neumayer, P; Urry, M K; Robey, H; Niemann, C; Landen, O L; Morse, E; Glenzer, S H

    2006-11-21

    The conversion efficiency of ultra short-pulse laser radiation to K-{alpha} x-rays has been measured for various chlorine-containing targets to be used as x-ray scattering probes of dense plasmas. The spectral and temporal properties of these sources will allow spectrally-resolved x-ray scattering probing with picosecond temporal resolution required for measuring the plasma conditions in inertial confinement fusion experiments. Simulations of x-ray scattering spectra from these plasmas show that fuel capsule density, capsule ablator density, and shock timing information may be inferred.

  14. Intensity of the Fe XV emission line corona, the level of geomagnetic activity, and the velocity of the solar wind

    Science.gov (United States)

    Bell, B.; Noci, G.

    1976-01-01

    The method of superposed epochs is used to determine the average solar wind velocity and the Kp index following central meridian passage of coronal weak and bright features identified from OSO 7 isophotograms of the Fe XV (284 A) emission line. It is found that bright coronal regions possess magnetic fields of closed configuration, thus reducing particle escape, while coronal holes possess open magnetic field lines favorable to particle escape or enhanced outflow of the solar wind.

  15. RXTE, Chandra, and XMM Spectroscopy of the Fe-K Lines and Compton Reflection in Type 1 AGN

    Science.gov (United States)

    Yaqoob, Tahir

    2004-01-01

    This award pertains to an RXTE observation of the Seyfert 1 galaxy Akn 120. The purpose of the observation was to measure the Fe-K emission line and the Compton reflection continuum with RXTE, simultaneously with Chandra and XMM. Such measurements can severely constrain accretion disk models of the central engine since the Fe-K line emission and Compton reflection are intimately related in terms of the physics of X-ray reprocessing in optically-thick matter. Akn 120 was selected for this study because it is amongst the brightest AGN in its class and has a particularly strong and apparently broad Fe-K emission line. The results could then also be used to lay the ground work for even higher resolution studies with Astro-E2. Unfortunately, the Chandra observation was not performed but a contemporaneous XMM observation was performed by another group of researchers. Those data recently became public and can be compared with the RXTE data. In addition, non-contemporaneous observations with other missions do still provide additional important constraints (for example any non-varying line or continuum emission components can be established and used to reject or preserve various model scenarios). We analyzed the RXTE data and found a strong Fe-K emission line (resolved even with the poor resolution of RXTE), and a strong Compton-reflection continuum (see Fig. l(a)). We found that the results of archival ASCA data on Akn 120 had not been published in the literature so we analyzed the ASCA data too, in order to compare with the new RXTE data. Fig. l(b) shows that the ASCA data also reveal a strong, broad FeK emission line (but the data are not sensitive to the Compton-reflection continuum). We compared our spectral fitting results for the RXTE and ASCA data with the results from XMM and from previous RXTE observations.

  16. Measurement of atomic Stark parameters of many Mn I and Fe I spectral lines using GMAW process

    Energy Technology Data Exchange (ETDEWEB)

    Zielinska, S; Pellerin, S; Valensi, F [GREMI, Universite d' Orleans (Site de Bourges)/CNRS, BP 4043, 18028 Bourges cedex (France); Dzierzega, K; Musiol, K [Marian Smoluchowski Institute of Physics, Jagellonian University, Krakow (Poland); Briand, F, E-mail: sylwia.zielinska@airliquide.co, E-mail: stephane.pellerin@univ-orleans.f, E-mail: krzycho@netmail.if.uj.edu.p, E-mail: flavien.valensi@laplace.univ-tsle.f, E-mail: ufmusiol@cyf-kr.edu.p, E-mail: francis.briand@airliquide.co [CTAS-Air Liquide Welding, Saint Ouen l' Aunone, 95315 Cergy-Pontoise cedex (France)

    2010-11-03

    The particular character of the welding arc working in pure argon, whose emission spectrum consists of many spectral lines strongly broadened by the Stark effect, has allowed measurement, sometimes for the first time, of the Stark parameters of 15 Mn I and 10 Fe I atomic spectral lines, and determination of the dependence on temperature of normalized Stark broadening in N{sub e} = 10{sup 23} m{sup -3} of the 542.4 nm atomic iron line. These results show that special properties of the MIG plasma may be useful in this domain because composition of the wire-electrode may be easily adapted to the needs of an experiment.

  17. The complex circumnuclear environment of the broad-line radio galaxy 3C 390.3 revealed by Chandra HETG

    CERN Document Server

    Tombesi, F; Kallman, T; Reynolds, C S; Mushotzky, R F; Braito, V; Behar, E; Leutenegger, M A; Cappi, M

    2016-01-01

    We present the first high spectral resolution X-ray observation of the broad-line radio galaxy 3C 390.3 obtained with the high energy transmission grating (HETG) spectrometer on board the Chandra X-ray Observatory. The spectrum shows complex emission and absorption features in both the soft X-rays and Fe K band. We detect emission and absorption lines in the energy range between E = 700-1000 eV associated with ionized Fe L transitions (Fe XVII-XX). An emission line at the energy of E=6.4 keV consistent with the Fe K\\alpha is also observed. Our best-fit model requires at least three different components: (i) a hot emission component likely associated with the hot interstellar medium in this elliptical galaxy with temperature kT=0.5+/-0.1 keV; (ii) a warm absorber with ionization parameter log\\xi=2.3+/-0.5 erg s^{-1} cm, column density logN_H=20.7+/-0.1 cm^{-2}, and outflow velocity of v_{out}<150 km s^{-1}; (iii) a lowly ionized reflection component in the Fe K band likely associated with the optical broad ...

  18. An assessment of Fe xx-Fe xxii emission lines in SDO/EVE data as diagnostics for high-density solar flare plasmas using EUVE stellar observations

    Science.gov (United States)

    Keenan, F. P.; Milligan, R. O.; Mathioudakis, M.; Christian, D. J.

    2017-06-01

    The Extreme Ultraviolet Variability Experiment (EVE) on the Solar Dynamics Observatory obtains extreme-ultraviolet (EUV) spectra of the full-disc Sun at a spectral resolution of ˜1 Å and cadence of 10 s. Such a spectral resolution would normally be considered to be too low for the reliable determination of electron density (Ne) sensitive emission line intensity ratios, due to blending. However, previous work has shown that a limited number of Fe xxi features in the 90-160 Å wavelength region of EVE do provide useful Ne-diagnostics at relatively low flare densities (Ne ≃ 1011-1012 cm-3). Here, we investigate if additional highly ionized Fe line ratios in the EVE 90-160 Å range may be reliably employed as Ne-diagnostics. In particular, the potential for such diagnostics to provide density estimates for high Ne (˜1013 cm-3) flare plasmas is assessed. Our study employs EVE spectra for X-class flares, combined with observations of highly active late-type stars from the EUVE satellite plus experimental data for well-diagnosed tokamak plasmas, both of which are similar in wavelength coverage and spectral resolution to those from EVE. Several ratios are identified in EVE data, which yield consistent values of electron density, including Fe xx 113.35/121.85 and Fe xxii 114.41/135.79, with confidence in their reliability as Ne-diagnostics provided by the EUVE and tokamak results. These ratios also allow the determination of density in solar flare plasmas up to values of ˜1013 cm-3.

  19. A K-alpha x-ray source using high energy and high repetition rate laser system for phase contrast imaging

    OpenAIRE

    Serbanescu, Cristina; Fourmaux, Sylvain; Kieffer, Jean-Claude; Kincaid, Russell; Krol, Andrzej

    2009-01-01

    K-alpha x-ray sources from laser produced plasmas provide completely new possibilities for x-ray phase-contrast imaging applications. By tightly focusing intense femtosecond laser pulses onto a solid target K-alpha x-ray pulses are generated through the interaction of energetic electrons created in the plasma with the bulk target. In this paper, we present a continuous and efficient Mo K-alpha x-ray source produced by a femtosecond laser system operating at 100 Hz repetition rate with maximum...

  20. On the validity of the 630 nm Fe I nm lines for the magnetometry of the internetwork quiet Sun

    CERN Document Server

    Gonzalez, M J M; Cobo, B R

    2006-01-01

    The purpose of this work is to analyze the reliability of the magnetic field strengths inferred from the 630 nm pair of Fe I lines at internetwork quiet Sun regions. Some numerical experiments have been performed that demonstrate the inability of these lines to recover the magnetic field strength in such low flux solar regions. It is shown how different model atmospheres, with magnetic field strengths ranging from few hundred Gauss to kiloGauss, give rise to Stokes profiles that can not be distinguished. The reasons for this degeneracy are discussed.

  1. Highly Ionized Fe-K Absorption Line from Cygnus X-1 in the High/Soft State Observed with Suzaku

    CERN Document Server

    Yamada, S; Mineshige, S; Ueda, Y; Kubota, A; Gandhi, P; Done, C; Noda, H; Yoshikawa, A; Makishima, K

    2013-01-01

    We present observations of a transient He-like Fe K alpha absorption line in Suzaku observations of the black hole binary Cygnus X-1 on 2011 October 5 near superior conjunction during the high/soft state, which enable us to map the full evolution from the start and the end of the episodic accretion phenomena or dips for the first time. We model the X-ray spectra during the event and trace their evolution. The absorption line is rather weak in the first half of the observation, but instantly deepens for ~10 ks, and weakens thereafter. The overall change in equivalent width is a factor of ~3, peaking at an orbital phase of ~0.08. This is evidence that the companion stellar wind feeding the black hole is clumpy. By analyzing the line with a Voigt profile, it is found to be consistent with a slightly redshifted Fe XXV transition, or possibly a mixture of several species less ionized than Fe XXV. The data may be explained by a clump located at a distance of ~10^(10-12) cm with a density of ~10^((-13)-(-11)) g cm^-...

  2. On-line optical determination of floc size of Fe( Ⅲ ) coagulants

    Institute of Scientific and Technical Information of China (English)

    WANG Yan; GAO Bao-yu; YUE Qin-yan; ZHOU Wei-zhi; CHU Yong-bao

    2005-01-01

    This study investigated the floc aggregation, average floc size, floc size variance and floc growth velocity when ferric chloride (FeCl3) and polyferric chloride (PFC) were used to treat the simulated water samples. The factors including coagulant dose, ionic strength and solution pH, which affect the floc aggregation, were studied. Experiments were carried out in a bench-scale reactor using photometric dispersion analyzer (PDA). Results showed that there were great differences between the floc aggregation of PFC and FeCl3.The average floc size and floc growth velocity of PFC were much larger than those of FeCl3. Compared with FeCl3, PFC gave a better coagulation performance in wider range of pH, dosage and ionic strength. It was also found that the coagulation efficiency of PFC did not depend on average floc size but on floc growth velocity.

  3. Magnetic fields in M-dwarfs: quantitative results from detailed spectral synthesis in FeH lines

    CERN Document Server

    Shulyak, D; Wende, S; Kochukhov, O; Piskunov, N; Seifahrt, A

    2010-01-01

    Strong surface magnetic fields are ubiquitously found in M-dwarfs with mean intensities on the order of few thousand Gauss-three orders of magnitude higher than the mean surface magnetic field of the Sun. These fields and their interaction with photospheric convection are the main source of stellar activity, which is of big interest to study links between parent stars and their planets. Moreover, the understanding of stellar magnetism, as well as the role of different dynamo-actions in particular, is impossible without explaining magnetic fields in M-dwarfs. Measuring magnetic field intensities and geometries in such cool objects, however, is strongly limited to our ability to simulate the Zeeman effect in molecular lines. In this work, we present quantitative results of modelling and analysis of the magnetic fields in selected M-dwarfs in FeH Wing-Ford lines and strong atomic lines. Some particular FeH lines are found to be the excellent probes of the magnetic field.

  4. NuSTAR Reveals the Comptonizing Corona of the Broad-Line Radio Galaxy 3C 382

    DEFF Research Database (Denmark)

    Ballantyne, D. R.; Bollenbacher, J. M.; Brenneman, L. W.;

    2014-01-01

    an excellent fit to both spectra and show that the coronal plasma cooled from $kT_e=330\\pm 30$ keV in the low flux data to $231^{+50}_{-88}$ keV in the high flux observation. This cooling behavior is typical of Comptonizing corona in Seyfert galaxies and is distinct from the variations observed in jet......-dominated sources. In the high flux observation, simultaneous Swift data are leveraged to obtain a broadband spectral energy distribution and indicates that the corona intercepts $\\sim 10$% of the optical and ultraviolet emitting accretion disk. 3C 382 exhibits very weak reflection features, with no detectable...... relativistic Fe K$\\alpha$ line, that may be best explained by an outflowing corona combined with an ionized inner accretion disk....

  5. An unusual radiation dose dependent EPR line at g{sub eff} = 2.54 in feldspars: possible evidence of Fe{sup 3+}O{sup 2-} {r_reversible} Fe{sup 2+}O{sup -} and exchange coupled Fe{sup 3+}-Fe{sup 2+}-nO{sup -}

    Energy Technology Data Exchange (ETDEWEB)

    Sastry, M D [Physical Research Laboratory, Navrangpura, Ahmedabad, 380 009 (India); Nagar, Y C [Physical Research Laboratory, Navrangpura, Ahmedabad, 380 009 (India); Bhushan, B [Food Technology Division, Bhabha Atomic Research Center, Trombay, Mumbai, 400 085 (India); Mishra, K P [Radiation Biology and Health Sciences, Bhabha Atomic Research Center, Mumbai, 400 085 (India); Balaram, V [Geochemistry Division, National Geophysical Research Institute, Hyderabad, 500 007 (India); Singhvi, A K [Physical Research Laboratory, Navrangpura, Ahmedabad, 380 009 (India)

    2008-01-16

    We report electron paramagnetic resonance (EPR) results on natural feldspar grains extracted from sediment samples of three widely different source regions. The XRD analysis indicated that the samples had albite, microcline and Ca/Ba-orthoclase as the major constituents. The EPR spectrum of all the samples exhibited an intense line around g{sub eff} = 4.3. This is characteristic of Fe{sup 3+} with a zero field splitting that is significantly larger than the microwave quantum. More interesting was the presence of a strong EPR signal in the region of g{sub eff} = 2.54-2.7. On irradiation with gamma rays the position of the line shifted to higher magnetic field. The possible origin of this line and its unusual behavior with dose is explained as being due to the interaction of a hopping 'hole' on oxygen with iron centers. The possibilities considered include (1) the valence fluctuation of an Fe{sup 3+} center at a tetrahedral site (2) oscillation of FeO{sub 4}{sup -} between two resonant forms, Fe{sup 2+}O{sup -} and Fe{sup 3+}O{sup 2-}, and (3) exchange coupling between Fe{sup 3+}, Fe{sup 2+} and O{sup -}. The concentration of the latter is dose dependent and, consequently, it results in the observed dose dependent line shift.

  6. THE DUST SUBLIMATION RADIUS AS AN OUTER ENVELOPE TO THE BULK OF THE NARROW FeLINE EMISSION IN TYPE 1 AGNs

    Energy Technology Data Exchange (ETDEWEB)

    Gandhi, Poshak; Hönig, Sebastian F. [School of Physics and Astronomy, University of Southampton, Highfield, Southampton, SO17 1BJ (United Kingdom); Kishimoto, Makoto [Kyoto Sangyo University, Motoyama, Kamigamo, Kita-ku, Kyoto 603-8555 (Japan)

    2015-10-20

    The Fe Kα emission line is the most ubiquitous feature in the X-ray spectra of active galactic nuclei (AGNs), but the origin of its narrow core remains uncertain. Here, we investigate the connection between the sizes of the Fe Kα core emission regions and the measured sizes of the dusty tori in 13 local Type 1 AGNs. The observed Fe Kα emission radii (R{sub Fe}) are determined from spectrally resolved line widths in X-ray grating spectra, and the dust sublimation radii (R{sub dust}) are measured either from optical/near-infrared (NIR) reverberation time lags or from resolved NIR interferometric data. This direct comparison shows, on an object-by-object basis, that the dust sublimation radius forms an outer envelope to the bulk of the Fe Kα emission. R{sub Fe} matches R{sub dust} well in the AGNs, with the best constrained line widths currently. In a significant fraction of objects without a clear narrow line core, R{sub Fe} is similar to, or smaller than, the radius of the optical broad line region. These facts place important constraints on the torus geometries for our sample. Extended tori in which the solid angle of fluorescing gas peaks at well beyond the dust sublimation radius can be ruled out. We also test for luminosity scalings of R{sub Fe}, finding that the Eddington ratio is not a prime driver in determining the line location in our sample. We also discuss in detail potential caveats of data analysis and instrumental limitations, simplistic line modeling, uncertain black hole masses, and sample selection, showing that none of these is likely to bias our core result. The calorimeter on board Astro-H will soon vastly increase the parameter space over which line measurements can be made, overcoming many of these limitations.

  7. Kinetics of Fe(II)-catalyzed transformation of 6-line ferrihydrite under anaerobic flow conditions

    Energy Technology Data Exchange (ETDEWEB)

    Yang, L.; Steefel, C.I.; Marcus, M.A.; Bargar, J.R.

    2010-04-01

    The readsorption of ferrous ions produced by the abiotic and microbially-mediated reductive dissolution of iron oxy-hydroxides drives a series of transformations of the host minerals. To further understand the mechanisms by which these transformations occur and their kinetics within a microporous flow environment, flow-through experiments were conducted in which capillary tubes packed with ferrihydrite-coated glass spheres were injected with inorganic Fe(II) solutions under circumneutral pH conditions at 25 C. Synchrotron X-ray diffraction was used to identify the secondary phase(s) formed and to provide data for quantitative kinetic analysis. At concentrations at and above 1.8 mM Fe(II) in the injection solution, magnetite was the only secondary phase formed (no intermediates were detected), with complete transformation following a nonlinear rate law requiring 28 hours and 150 hours of reaction at 18 and 1.8 mM Fe(II), respectively. However, when the injection solution consisted of 0.36 mM Fe(II), goethite was the predominant reaction product and formed much more slowly according to a linear rate law, while only minor magnetite was formed. When the rates are normalized based on the time to react half of the ferrihydrite on a reduced time plot, it is apparent that the 1.8 mM and 18 mM input Fe(II) experiments can be described by the same reaction mechanism, while the 0.36 input Fe(II) experiment is distinct. The analysis of the transformation kinetics suggest that the transformations involved an electron transfer reaction between the aqueous as well as sorbed Fe(II) and ferrihydrite acting as a semiconductor, rather than a simple dissolution and recrystallization mechanism. A transformation mechanism involving sorbed inner sphere Fe(II) alone is not supported, since the essentially equal coverage of sorption sites in the 18 mM and 1.8 mM Fe(II) injections cannot explain the difference in the transformation rates observed.

  8. Kinetics of Fe(II)-catalyzed transformation of 6-line ferrihydrite under anaerobic flow conditions

    Energy Technology Data Exchange (ETDEWEB)

    Yang, L.; Steefel, C.I.; Marcus, M.A.; Bargar, J.R.

    2010-04-01

    The readsorption of ferrous ions produced by the abiotic and microbially-mediated reductive dissolution of iron oxy-hydroxides drives a series of transformations of the host minerals. To further understand the mechanisms by which these transformations occur and their kinetics within a microporous flow environment, flow-through experiments were conducted in which capillary tubes packed with ferrihydrite-coated glass spheres were injected with inorganic Fe(II) solutions under circumneutral pH conditions at 25 C. Synchrotron X-ray diffraction was used to identify the secondary phase(s) formed and to provide data for quantitative kinetic analysis. At concentrations at and above 1.8 mM Fe(II) in the injection solution, magnetite was the only secondary phase formed (no intermediates were detected), with complete transformation following a nonlinear rate law requiring 28 hours and 150 hours of reaction at 18 and 1.8 mM Fe(II), respectively. However, when the injection solution consisted of 0.36 mM Fe(II), goethite was the predominant reaction product and formed much more slowly according to a linear rate law, while only minor magnetite was formed. When the rates are normalized based on the time to react half of the ferrihydrite on a reduced time plot, it is apparent that the 1.8 mM and 18 mM input Fe(II) experiments can be described by the same reaction mechanism, while the 0.36 input Fe(II) experiment is distinct. The analysis of the transformation kinetics suggest that the transformations involved an electron transfer reaction between the aqueous as well as sorbed Fe(II) and ferrihydrite acting as a semiconductor, rather than a simple dissolution and recrystallization mechanism. A transformation mechanism involving sorbed inner sphere Fe(II) alone is not supported, since the essentially equal coverage of sorption sites in the 18 mM and 1.8 mM Fe(II) injections cannot explain the difference in the transformation rates observed.

  9. 3D simulations of M star atmosphere velocities and their influence on molecular FeH lines

    CERN Document Server

    Wende, S; Ludwig, H -G

    2009-01-01

    We present an investigation of the velocity fields in early to late M-type star hydrodynamic models, and we simulate their influence on FeH molecular line shapes. The M star model parameters range between log g of 3.0 - 5.0 and Teff of 2500 K and 4000 K. Our aim is to characterize the Teff- and log g -dependence of the velocity fields and express them in terms of micro- and macro-turbulent velocities in the one dimensional sense. We present also a direct comparison between 3D hydrodynamical velocity fields and 1D turbulent velocities. The velocity fields strongly affect the line shapes of FeH, and it is our goal to give a rough estimate for the log g and Teff parameter range in which 3D spectral synthesis is necessary and where 1D synthesis suffices. In order to calculate M-star structure models we employ the 3D radiative-hydrodynamics (RHD) code CO5BOLD. The spectral synthesis on these models is performed with the line synthesis code LINFOR3D. We describe the 3D velocity fields in terms of a Gaussian standar...

  10. FERO (Finding Extreme Relativistic Objects: statistics of relativistic broad Fe K lines in AGN

    Directory of Open Access Journals (Sweden)

    A. L. Longinotti

    2008-01-01

    Full Text Available Las propiedades de las líneas de emisión Fe Kα ensanchadas relativísticamente en núcleos activos de galaxias (AGN son aún materia de debate en la comunidad. Los trabajos recientes parecen excluir que la línea ancha de Fe es un rasgo común en los AGN. Se presenta el análisis de una gran muestra de 157 observaciones de archivo del XMM-Newton de AGN radio callados. Este trabajo en curso es lo desarrollado desde lo reportado en Guainazzi et al. (2006.

  11. High energy x-ray reflectivity and scattering study from spectrum-x-gamma flight mirrors

    DEFF Research Database (Denmark)

    Christensen, Finn Erland; Budtz-Jørgensen, Carl; Frederiksen, P. Kk

    1993-01-01

    Line radiation from Fe K-alpha(1), Cu K-alpha(1), and Ag K-alpha(1) is used to study the high energy X-ray reflectivity and scattering behavior of flight-quality X-ray mirrors having various Al substrates. When both the specular and the scattered radiation are integrated, near theoretical...

  12. High energy x-ray reflectivity and scattering study from spectrum-x-gamma flight mirrors

    DEFF Research Database (Denmark)

    Christensen, Finn Erland; Budtz-Jørgensen, Carl; Frederiksen, P. Kk

    1993-01-01

    Line radiation from Fe K-alpha(1), Cu K-alpha(1), and Ag K-alpha(1) is used to study the high energy X-ray reflectivity and scattering behavior of flight-quality X-ray mirrors having various Al substrates. When both the specular and the scattered radiation are integrated, near theoretical...

  13. A focussing iron line crystal spectrometer for Spacelab. [cosmic X-ray detection

    Science.gov (United States)

    Catura, R. C.; Culhane, J. L.; Rapley, C. G.; Gabriel, A. H.; Walker, A. B. C., Jr.; Woodgate, B. E.

    1977-01-01

    A crystal spectrometer system is described which employs conical focusing of 12 curved LiF crystal panels to minimize the detector size and reduce the background counting rate. The wavelength range from 1.70 to 1.98 A is covered, including the resonance lines of Fe XXV and Fe XXVI as well as the Fe I K-alpha line and absorption edge. Operation of the spectrometer is discussed, noting that diffracted X-rays are registered in one-dimensional position-sensitive detectors and that the arrival position of a photon in a detector is related to its wavelength due to the fixed curvature of the crystal panels in the dispersion plane. Some characteristics of the multianode position-sensitive detectors are reviewed along with the crystal arrangement and mounting. The instrument sensitivity is evaluated in relation to the strengths of 6.7-keV emission features detected by the Ariel 5 and OSO 8 proportional-counter spectrometers.

  14. Solution structure of BmKalphaIT01, an alpha-insect toxin from the venom of the Chinese scorpion Buthus martensii Karsch.

    Science.gov (United States)

    Tong, Xiaotian; Zhu, Jing; Ma, Yuguang; Chen, Xiang; Wu, Gong; He, Fahu; Cao, Chunyang; Wu, Houming

    2007-10-09

    The solution structure of an alpha-insect toxin from Buthus martensii Karsch, BmKalphaIT01, has been determined by two-dimensional NMR spectroscopy and molecular modeling techniques. Combining the sequence homology comparison and toxicity bioassays, BmKalphaIT01 has been suggested to be a natural mutant of alpha-insect toxins and so can serve as a tool to study the relationship of structure-function among this group of toxins. The overall structure of BmKalphaIT01 shares a common core structure consisting of an alpha-helix packed against a three-stranded antiparallel beta-sheet, which exhibits distinctive local conformations within the loops connecting these secondary structure elements. The solution structure of BmKalphaIT01 features a non-proline cis peptide bond between Asn9 and Tyr10, which is proposed to mediate the spatial closing of the five-residue turn (Gln8-Cys12) and the C-terminal segment (Arg58-His64) to form the NC domain and confer the toxin insect-specific bioactivity. Conformational heterogeneity is observed in the solution of BmKalphaIT01 and could be attributed to the cis-trans isomerization of the peptide bond between residues 9 and 10. The minor conformation of BmKalphaIT01 with a trans peptide bond between Asn9 and Tyr10 may be responsible for its moderate bioactivity against mammals. The cis-trans isomerization of the peptide bond between residues 9 and 10 may be the structural basis of dual pharmacological activities of alpha-insect and alpha-like scorpion toxins, which is supported by the fact that conformational heterogeneity occurs in the solution structures of LqhalphaIT, LqqIII, and LqhIII and by comparison of the solution structure of BmKalphaIT01 with those of some relevant alpha-type toxins.

  15. Signatures of the non-Maxwellian $\\kappa$-distributions in optically thin line spectra \\subtitle{I. Theory and synthetic Fe IX--XIII spectra}

    CERN Document Server

    Dudík, J; Mason, H E; Dzifčáková, E

    2014-01-01

    We investigate the possibility of diagnosing the degree of departure from the Maxwellian distribution using single-ion spectra originating in astrophysical plasmas in collisional ionization equilibrium. New atomic data for excitation of Fe IX-XIII are integrated under the assumption of a kappa-distribution of electron energies. Diagnostic methods using lines of a single ion formed at any wavelength are explored. Such methods minimize uncertainties from the ionization and recombination rates, as well as the possible presence of non-equilibrium ionization. Approximations to the collision strengths are also investigated. The calculated intensities of most of the Fe IX-XIII EUV lines show consistent behaviour with kappa at constant temperature. Intensities of these lines decrease with kappa, with the vast majority of ratios of strong lines showing little or no sensitivity to kappa. Several of the line ratios, especially involving temperature-sensitive lines, show a sensitivity to kappa that is of the order of sev...

  16. A brief review of the intensity of lines 3C and 3D in neon-like Fe XVII

    Energy Technology Data Exchange (ETDEWEB)

    Brown, G V

    2007-06-13

    X-ray emission from neon-like Fe XVII has been measured with high-resolution spectrometers from laboratory or celestial sources for nearly seven decades. Two of the strongest lines regularly identified in these spectra are the {sup 1}P{sub 1} {yields} {sup 1}S{sub 0} resonance, and {sup 3}D{sub 1} {yields} {sup 1}S{sub 0} intercombination line, known as 3C and 3D, respectively. This paper gives a brief overview of measurements of the intensities of the lines 3C and 3D from laboratory and celestial sources, and their comparison to model calculations, with an emphasis on measurements completed using an electron beam ion trap. It includes a discussion of the measured absolute cross sections compared to results from modern atomic theory calculations, as well as the diagnostic utility of the relative intensity, R = I{sub 3C}/I{sub 3D}, as it applies to the interpretation of spectra measured from the Sun and extra-Solar sources.

  17. Characterization of phosphoproteins from electrophoretic gels by nanoscale Fe(III) affinity chromatography with off-line mass spectrometry analysis

    DEFF Research Database (Denmark)

    Stensballe, A; Andersen, Søren; Jensen, Ole Nørregaard

    2001-01-01

    Detailed characterization of phosphoproteins as well as other post-translationally modified proteins is required to fully understand protein function and regulatory events in cells and organisms. Here we present a mass spectrometry (MS) based experimental strategy for the identification and mapping...... chromatography (Fe(III)-IMAC) columns were employed for enrichment of phosphorylated peptides from crude peptide mixtures prior to off-line analysis by matrix-assisted laser desorption/ionization (MALDI) MS or nanoelectrospray tandem mass spectrometry (MS/MS). An optimized and sensitive procedure for alkaline...... of phosphorylation sites. The advantages and limitations of the experimental strategy was demonstrated by enrichment, identification and sequencing of phosphopeptides from the model proteins ovalbumin and bovine beta-casein isolated by gel electrophoresis. Furthermore, an autophosphorylation site at Ser-3...

  18. On the Fe K absorption - accretion state connection in the Galactic center neutron star X-ray binary AX J1745.6-2901

    CERN Document Server

    Ponti, G; Munoz-Darias, T; DeMarco, B; Dwelly, T; Fender, R P; Nandra, K; Rea, N; Mori, K; Haggard, D; Heinke, C O; Degenaar, N; Aramaki, T; Clavel, M; Goldwurm, A; Hailey, C J; Israel, G L; Morris, M R; Rushton, A; Terrier, R

    2014-01-01

    AX J1745.6-2901 is a high-inclination (eclipsing) neutron star Low Mass X-ray Binary (LMXB) located less than ~1.5 arcmin from Sgr A*. Ongoing monitoring campaigns have targeted Sgr A* frequently and these observations also cover AX J1745.6-2901. We present here an X-ray analysis of AX J1745.6-2901 using a large dataset of 38 XMM-Newton observations, including eleven which caught AX J1745.6-2901 in outburst. Fe K absorption is clearly seen when AX J1745.6-2901 is in the soft state, but disappears during the hard state. The variability of these absorption features does not appear to be due to changes in the ionizing continuum. The small Kalpha/Kbeta ratio of the equivalent widths of the Fe xxv and Fe xxvi lines suggests that the column densities and turbulent velocities of the absorbing ionised plasma are in excess of N_H ~ 10^23 cm^-2 and v_turb >~ 500 km s^-1. These findings strongly support a connection between the wind (Fe K absorber) and the accretion state of the binary. These results reveal strong simil...

  19. Variability of the Fe K line relativistic component in a sample of Seyfert 1 galaxies

    CERN Document Server

    De Marco, B L; Dadina, M; Palumbo, G G C

    2006-01-01

    We present the analysis of X-ray spectral varability made on a sample of 7 Seyfert 1 bright galaxies, using XMM-Newton data. From the "XMM-Newton Science Archive" we selected those bright Seyfert 1 showing one or more prominent flares in their 2-10 keV light curves. For each of them we extracted spectra in 3 different time intervals: before, during and after the flare. We fitted them with a simple power law and then shifted a narrow emission and absorption line template across the 2.5-10 keV data, in order to investigate the presence of line-like features with a confidence level greater than 99%. Some highly significant features were detected in 3 out of 7 sources studied. In particular, the 3 sources, namely PG 1211+143, NGC 4051 and NGC 3783, showed the presence of a variable emission feature in the 4.5-5.8 keV band, characterized by an increase of its intensity after the flare peak. Because of the observed variability pattern, this feature seems to be ascribable to a reverbered redshifted relativistic comp...

  20. Solution structure of BmKalphaTx11, a toxin from the venom of the Chinese scorpion Buthus martensii Karsch.

    Science.gov (United States)

    Zhu, Jing; Tong, Xiaotian; Cao, Chunyang; Wu, Gong; Zhang, Naixia; Wu, Houming

    2010-01-01

    The solution structure of BmKalphaTx11 presented by this paper is distinctive from any other structures of wide-type scorpion alpha-toxins reported so far, for its trans-9,10 peptide bond conformation is accompanied by 'protruding' topology of the 'NC-domain'. The orientation of the C-tail of BmKalphaTx11 is obviously different from that of classical alpha-toxins (e.g., AaH2, BmK-M8), despite the fact that they share common trans conformation of peptide bond between residues 9 and 10. Accordingly, there must be other structural factors dominating the orientation of the C-tail except the conformation of peptide bond 9-10. Our study reveals that residues at position 58 play an important role in it, and different type of residues at this position (e.g., Lys, Arg, Met, Ile) result in different spatial relationship between the C-terminus and the 'five-residue-turn' and then different topology of the 'NC-domain', therefore residues at position 58 are believed to function as structure and bioactivity switch for specificity of scorpion alpha-toxins. The mechanism for stabilizing the geometry of the 'NC-domain' in wide-type scorpion alpha-toxins is also discussed.

  1. Chandra Detects Relativistic Broad Absorption Lines from APM 08279+5255

    CERN Document Server

    Chartas, G; Garmire, G P; Gallagher, S C

    2002-01-01

    We report the discovery of X-ray broad absorption lines (BALs) from the BALQSO APM 08279+5255 originating from material moving at relativistic velocities with respect to the central source. The large flux magnification by a factor of ~ 100 provided by the gravitational lens effect combined with the large redshift (z = 3.91) of the quasar have facilitated the acquisition of the first high signal-to-noise X-ray spectrum of a quasar containing X-ray BALs. Our analysis of the X-ray spectrum of APM 08279+5255 places the rest-frame energies of the two observed absorption lines at 8.1 and 9.8 keV. The detection of each of these lines is significant at the > 99.9% confidence level based on the F-test. Assuming that the absorption lines are from Fe xxv Kalpha, the implied bulk velocities of the X-ray BALs are ~ 0.2c and ~ 0.4c, respectively. The observed high bulk velocities of the X-ray BALs combined with the relatively short recombination time-scales of the X-ray absorbing gas imply that the absorbers responsible fo...

  2. Test of relativistic gravity using microlensing of relativistically broadened lines in gravitationally lensed quasars

    CERN Document Server

    Neronov, A

    2015-01-01

    We show that observation of the time-dependent effect of microlensing of relativistically broadened emission lines (such as e.g. the Fe Kalpha line in X-rays) in strongly lensed quasars could provide data on celestial mechanics of circular orbits in the direct vicinity of the horizon of supermassive black holes. This information can be extracted from the observation of evolution of red / blue edge of the magnified line just before and just after the period of crossing of the innermost stable circular orbit by the microlensing caustic. The functional form of this evolution is insensitive to numerous astrophysical parameters of the accreting black hole and of the microlensing caustics network system (as opposed to the evolution the full line spectrum). Measurement of the temporal evolution of the red / blue edge could provide a precision measurement of the radial dependence of the gravitational redshift and of velocity of the circular orbits, down to the innermost stable circular orbit. These measurements could...

  3. Non-LTE line formation of Fe in late-type stars - IV. Modelling of the solar centre-to-limb variation in 3D

    DEFF Research Database (Denmark)

    Lind, K.; Amarsi, A. M.; Asplund, M.

    2017-01-01

    and quantum mechanical calculations of collisional excitation and charge transfer with neutral hydrogen; the latter effectively remove a free parameter that has hampered all previous line formation studies of Fe in non-local thermodynamic equilibrium (NLTE). For the first time, we use realistic 3D NLTE...

  4. 提钒转炉用MgO--Fe--C砖性能研究%Study on the properties of MgO--Fe--C bricks as the linings of vanadium-extraction converters

    Institute of Scientific and Technical Information of China (English)

    刘磊; 孙文杰; 张灵犀; 李学慧

    2016-01-01

    To extend the service life of MgO-C bricks which used as the linings of vanadium-extraction converters, MgO-Fe-C bricks were fabricated in this study. The service properties of this novel refractory were comparatively investigated between traditional MgO-C bricks and MgO-Fe-C bricks. The results show that the poor sinterability and anti-erosion property of the decarburized layer at the service temperature of 1400 ℃ are responsible for the short service life of MgO-C bricks. However, for MgO-Fe-C bricks, Fe particles are oxidized in the oxidized layer and in-situ MgO-FeOss forms under the working condition. This can effectively improve the sintering performance, form a decarburized layer with enhanced compactness and bonding strength, and significantly improve the oxidation resistance and slag corrosion resistance of this layer, contributing to extend the service life. MgO-Fe-C bricks have a prom-ising prospect of applications in the substitute for MgO-C bricks as the linings of vanadium-extraction converters.%为延长MgO-C砖在提钒转炉上的使用寿命,本研究开发了一种新型MgO-Fe-C砖,通过与传统的MgO-C砖进行对比研究,考察这种新型耐火材料的使用性能。研究结果表明:在1400℃的使用温度下,导致提钒转炉用MgO- C砖使用寿命短的原因是脱碳层的烧结性差,抗冲刷性不理想;而对于本研究所开发的MgO-Fe-C砖,铁粉在氧化层氧化及使用条件下原位形成MgO-FeOss,有效地改善脱碳层的烧结性能,并形成致密且高结合强度的脱碳层,显著地提高了耐火材料的抗熔渣侵蚀性和抗氧化性,有利于耐火材料寿命的提高,因此MgO-Fe-C砖是具有良好应用前景的提钒转炉用MgO-C砖的替代品。

  5. Simultaneous NuSTAR and XMM-Newton 0.5-80 KeV Spectroscopy of the Narrow-Line Seyfert 1 Galaxy SWIFT J2127.4+5654

    Science.gov (United States)

    Marinucci, A.; Matt, G.; Kara, E.; Miniutti, G.; Elvis, M.; Arevalo, P.; Ballantyne, D. R.; Balokovic, M.; Bauer, F.; Brenneman, L.; Boggs, S. E.; Cappi, M.; Christensen, F. E.; Craig, W. W.; Fabian, A. C.; Fuerst, F.; Hailey, C. J.; Harrison, F. A.; Risaliti, G.; Reynolds, C. S.; Stern, D. K.; Walton, D. J.; Zhang, W.

    2014-01-01

    We present a broad-band spectral analysis of the joint XMM-Newton and Nuclear Spectroscopic Telescope Array observational campaign of the narrow-line Seyfert 1 SWIFT J2127.4+5654, consisting of 300 kiloseconds performed during three XMM-Newton orbits. We detect a relativistic broadened iron K-alpha line originating from the innermost regions of the accretion disc surrounding the central black hole, from which we infer an intermediate spin of a = 0.58 (sup +0.11) (sub -0.17). The intrinsic spectrum is steep (gamma = 2.08 plus or minus 0.01) as commonly found in narrow-line Seyfert 1 galaxies, while the cutoff energy (E (sub c) = 108 (sup +11) (sub -10) kiloelectronvolts) falls within the range observed in broad-line Seyfert 1 galaxies. We measure a low-frequency lag that increases steadily with energy, while at high frequencies, there is a clear lag following the shape of the broad Fe K emission line. Interestingly, the observed Fe K lag in SWIFT J2127.4+5654 is not as broad as in other sources that have maximally spinning black holes. The lag amplitude suggests a continuum-to-reprocessor distance of about 10-20 radius of gyration. These timing results independently support an intermediate black hole spin and a compact corona.

  6. Inhibition of hTERT Gene Expression by Silibinin-Loaded PLGA-PEG-Fe3O4 in T47D Breast Cancer Cell Line

    Directory of Open Access Journals (Sweden)

    Zohreh Ebrahimnezhad

    2013-05-01

    Full Text Available Introduction: Nowadays, using drug delivery is an essential method to improve cancer therapy through decreasing drug toxicity and increasing efficiency of treatment. Silibinin (C25H22O10, a polyphenolic flavonoid which is isolated from the milk thistle plant, has various applications in cancer therapy but it has hydrophobic structure with low water solubility and bioavailability. To increase the effect of silibinin, silibinin-loaded PLGA-PEG-Fe3O4 was prepared to determine the inhibitory effect of this nanodrug on Telomerase gene expression. Methods: The rate of silibinin loaded into PLGA-PEG-Fe3O4 was measured. Then, the cytotoxic effect of silibinin-loaded PLGA-PEG-Fe3O4 was determined by Methyl Thiazol Tetrazolium (MTT assay. After that, inhibition of Telomerase gene expression was indicated through Real-time PCR. Results: Data analysis from MTT assay showed that silibinin-loaded PLGA-PEG-Fe3O4 had dose dependent cytotoxic effect on T47D cell line. MTT assay showed no cytotoxic effect of free PLGA-PEG- Fe3O4 on T47D breast cancer cell line. Real Time PCR analysis showed that the level of telomerase gene expression more efficiently decreased with silibinin-loaded PLGA-PEG- Fe3O4 than with free silibinin alone. Conclusion: The present study indicates that this nanodrug causes down-regulation of Telomerase gene expression in cancer cells. Therefore, PLGA-PEG- Fe3O4 could be an appropriate carrier for hydrophobic agents such as silibinin to improve their action in cancer therapy.

  7. Three-dimensional non-LTE radiative transfer effects in Fe I lines I. Flux sheet and flux tube geometries

    CERN Document Server

    Holzreuter, R

    2012-01-01

    In network and active region plages, the magnetic field is concentrated into structures often described as flux tubes (FTs) and sheets (FSs). 3-D radiative transfer (RT) is important for energy transport in these concentrations. It is also expected to be important for diagnostic purposes but has rarely been applied for that purpose. Using true 3-D, non-LTE (NLTE) RT in FT/FS models, we compute Fe line profiles commonly used to diagnose the Sun's magnetic field by comparing the results with those obtained from LTE/1-D (1.5-D) NLTE calculations. Employing a multilevel iron atom, we study the influence of basic parameters such as Wilson depression, wall thickness, radius/width, thermal stratification or magnetic field strength on all Stokes $I$ parameters in the thin-tube approximation. The use of different levels of approximations of RT may lead to considerable differences in profile shapes, intensity contrasts, equivalent widths, and the determination of magnetic field strengths. In particular, LTE, which ofte...

  8. Insight into “Changing-look” AGN Mrk 1018 from the FeLine: The Reprocessing Gas Has Yet to Fully Respond to the Fading of the AGN

    Science.gov (United States)

    LaMassa, Stephanie M.; Yaqoob, Tahir; Kilgard, Roy

    2017-05-01

    Mrk 1018 is a “changing-look” active galactic nucleus (AGN) whose optical spectrum transitioned from a Type 1.9 to a Type 1 between 1979 and 1984, and then back to a Type 1.9 in 2015. This latest transition was accompanied by a decrease in X-ray flux. We analyze the Chandra spectra from 2010 and 2016 and NuSTAR spectra from 2016, with a careful treatment of pileup in the Chandra spectrum from 2010, and self-consistently model absorption, reflection, and Feline emission in the X-ray spectra from 2016. We demonstrate that while the 2-10 keV X-ray flux decreased by an order of magnitude (1.46{}-0.13+0.10× {10}-11-{1.31}-0.04+0.09× {10}-12 erg s-1 cm-2), the Fe Kα equivalent width (EW) increased from {0.18}-0.12+0.17 to {0.61}-0.25+0.27 keV due to a depressed AGN continuum. We jointly fit the Chandra and NuSTAR spectra from 2016 using the physically motivated MYTorus model, and find that the torus orientation is consistent with a face-on geometry and that lines of sight intersecting the torus are ruled out. While we measure no line-of-sight absorption, we do measure a column density of {N}{{H}}={5.38}-4.0+14× {10}22 cm-2 for gas out of the line of sight that reprocesses the X-ray emission. We find a high relative normalization between the Compton-scattered emission and transmitted continuum, which is indicative of time lags between the primary X-ray source and reprocessing gas. We predict that the Feline will respond to the decrease in AGN flux, which would manifest as a decrease in the Fe Kα EW.

  9. Discovery of an ionized Fe-K edge in the z=3.91 Broad Absorption Line Quasar APM 08279+5255 with XMM-Newton

    CERN Document Server

    Hasinger, G; Komossa, S

    2002-01-01

    Recent XMM-Newton observations of the high-redshift, lensed, broad absorption line (BAL) quasi-stellar object APM 08279+5255, one of the most luminous objects in the universe, allowed the detection of a high column density absorber ($N_H \\approx 10^{23}$ cm$^{-2}$) in the form of a K-shell absorption edge of significantly ionized iron (Fe XV - XVIII) and corresponding ionized lower-energy absorption. Our findings confirm a basic prediction of phenomenological geometry models for the BAL outflow and can constrain the size of the absorbing region. The Fe/O abundance of the absorbing material is significantly higher than solar (Fe/O = 2-5), giving interesting constraints on the gas enrichment history in the early Universe.

  10. c2d Spitzer IRS Spectra of Disks around T Tauri Stars. III. [Ne II], [Fe I], and H_2 gas-phase lines

    CERN Document Server

    Lahuis, Fred; Blake, Geoffrey A; Evans, Neal J; Kessler-Silacci, Jacqueline E; Pontoppidan, Klaus M

    2007-01-01

    We present a survey of mid-infrared gas-phase lines toward a sample of 76 circumstellar disks around low mass pre-main sequence stars from the Spitzer "Cores to Disks" legacy program. We report the first detections of [Ne II] and [Fe I] toward classical T Tauri stars in ~20% respectively ~9% of our sources. The observed [Ne II] line fluxes and upper limits are consistent with [Ne II] excitation in an X-ray irradiated disk around stars with X-ray luminosities L_X=10^{29}-10^{31} erg s^{-1}. [Fe I] is detected at ~10^-5-10^-4 L_Sun, but no [S I] or [Fe II] is detected down to ~10^{-6} L_Sun. The [Fe I] detections indicate the presence of gas-rich disks with masses of >~0.1 M_J. No H_2 0-0 S(0) and S(1) disk emission is detected, except for S(1) toward one source. These data give upper limits on the warm (T~100-200K) gas mass of a few Jovian masses, consistent with recent T Tauri disk models which include gas heating by stellar radiation. Compact disk emission of hot (T>~500K) gas is observed through the H_2 0-0...

  11. Systematic evaluation of biocompatibility of magnetic Fe3O4 nanoparticles with six different mammalian cell lines

    Science.gov (United States)

    Liu, Yingxun; Chen, Zhongping; Wang, Jinke

    2011-01-01

    This article systematically evaluated the biocompatibility of multiple mammalian cell lines to 11-nm DMSA-coated Fe3O4 magnetic nanoparticles (MNPs). Cells including RAW264.7, THP-1, Hepa1-6, HepG2, HL-7702, and HeLa were incubated with six different concentrations (0, 20, 30, 40, 50, and 100 μg/mL) of MNPs for 48 h, and then the cell labeling, iron loading, cell viability, apoptosis, cycle, and oxidative stress were all quantitatively evaluated. The results revealed that all the cells were effectively labeled by the nanoparticles; however, the iron loading of RAW264.7 was significantly higher than that of other cells at any dose. The proliferations of all the cells were not significantly suppressed by MNPs at the studied dose except HepG2 that was exposed to 100 μg/mL MNPs. The investigation of oxidative stress demonstrated that the levels of total superoxide dismutase and xanthine oxidase had no significant changes in all the cells treated by all the doses of MNPs, while the levels of malonyldialdehyde activity of MNP-treated cells significantly increased. The nanoparticles did not produce any significant effect on cell cycles at any of the doses, but resulted in significant apoptosis of THP-1 and HepG2 cells at the highest concentration of 100 μg/mL. At a concentration of 30 μg/mL which was used in human studies with an intravascular nanoparticle imaging agent (Combidex), the nanoparticles efficiently labeled all the cells studied, but did not produce any significant influence on their viability, oxidative stress, and apoptosis and cycle. Therefore, the nanoparticles were concluded with better biocompatibility, which provided some useful information for its clinical applications.

  12. Chandra/HETGS Spectroscopy of the Galactic Black Hole GX 339-4: A Relativistic Iron Line and Evidence for a Seyfert-like Warm Absorber

    CERN Document Server

    Miller, J M; Fabian, A C; Homan, J; Nowak, M A; Wijnands, R; Van der Klis, M; Belloni, T; Tomsick, J A; Smith, D M; Charles, P A; Lewin, W H G

    2004-01-01

    We observed the Galactic black hole GX 339-4 with the Chandra High Energy Transmission Grating Spectrometer (HETGS) for 75 ksec during the decline of its 2002-2003 outburst. The sensitivity of this observation provides an unprecedented glimpse of a Galactic black hole at about a tenth of the luminosity of the outburst peak. The continuum spectrum is well described by a model consisting of multicolor disk blackbody (kT = 0.6 keV) and power-law (Gamma = 2.5) components. X-ray reflection models yield improved fits. A strong, relativistic Fe K-alpha emission line is revealed, indicating that the inner disk extends to the innermost stable circular orbit. The line is not sufficiently broad to strongly require black hole spin. Absorption lines from H-like and He-like O, and He-like Ne and Mg are detected, as well as lines which are likely due to Ne II and Ne III. The measured line properties make it difficult to associate the absorption with the coronal phase of the interstellar medium. A scenario wherein the absorp...

  13. LINES

    Directory of Open Access Journals (Sweden)

    Minas Bakalchev

    2015-10-01

    Full Text Available The perception of elements in a system often creates their interdependence, interconditionality, and suppression. The lines from a basic geometrical element have become the model of a reductive world based on isolation according to certain criteria such as function, structure, and social organization. Their traces are experienced in the contemporary world as fragments or ruins of a system of domination of an assumed hierarchical unity. How can one release oneself from such dependence or determinism? How can the lines become less “systematic” and forms more autonomous, and less reductive? How is a form released from modernistic determinism on the new controversial ground? How can these elements or forms of representation become forms of action in the present complex world? In this paper, the meaning of lines through the ideas of Le Corbusier, Leonidov, Picasso, and Hitchcock is presented. Spatial research was made through a series of examples arising from the projects of the architectural studio “Residential Transformations”, which was a backbone for mapping the possibilities ranging from playfulness to exactness, as tactics of transformation in the different contexts of the contemporary world.

  14. Deriving the Extinction to Young Stellar Objects using [Fe II] Near-infrared Emission Lines: Prescriptions from GIANO High-resolution Spectra

    Science.gov (United States)

    Pecchioli, T.; Sanna, N.; Massi, F.; Oliva, E.

    2016-07-01

    The near-infrared (NIR) emission lines of Fe+ at 1.257, 1.321, and 1.644 μm share the same upper level; their ratios can then be exploited to derive the extinction to a line emitting region once the relevant spontaneous emission coefficients are known. This is commonly done, normally from low-resolution spectra, in observations of shocked gas from jets driven by Young Stellar Objects. In this paper we review this method, provide the relevant equations, and test it by analyzing high-resolution (R ∼ 50,000) NIR spectra of two young stars, namely the Herbig Be star HD 200775 and the Be star V1478 Cyg, which exhibit intense emission lines. The spectra were obtained with the new GIANO echelle spectrograph at the Telescopio Nazionale Galileo. Notably, the high-resolution spectra allowed checking the effects of overlapping telluric absorption lines. A set of various determinations of the Einstein coefficients are compared to show how much the available computations affect extinction derivation. The most recently obtained values are probably good enough to allow reddening determination within 1 visual mag of accuracy. Furthermore, we show that [Fe ii] line ratios from low-resolution pure emission-line spectra in general are likely to be in error due to the impossibility to properly account for telluric absorption lines. If low-resolution spectra are used for reddening determinations, we advice that the ratio 1.644/1.257, rather than 1.644/1.321, should be used, being less affected by the effects of telluric absorption lines.

  15. K(alpha) x-ray emission characterization of 100 Hz, 15 mJ femtosecond laser system with high contrast ratio.

    Science.gov (United States)

    Fourmaux, S; Serbanescu, C; Kincaid, R E; Krol, A; Kieffer, J C

    2008-12-12

    We report K(alpha) x-ray production with a high energy (110 mJ per pulse at 800 nm before compression/15 mJ at 400 nm after compression), high repetition rate (100 Hz), and high pulse contrast (better than 10(-9) at 400 nm) laser system. To develop laser-based x-ray sources for biomedical imaging requires to use high-energy and high-power ultra-fast laser system where compression is achieved under vacuum. Using this type of laser system, we demonstrate long-term stability of the x-ray yield, conversion efficiency higher than 1.5 x 10(-5) with a Mo target, and the x-ray spot size close to the optical focal spot. This high-repetition K(alpha) x-ray source can be very useful for x-ray phase-contrast imaging.

  16. Evidence for ultra-fast outflows in radio-quiet AGNs: I - detection and statistical incidence of Fe K-shell absorption lines

    CERN Document Server

    Tombesi, F; Reeves, J N; Palumbo, G G C; Yaqoob, T; Braito, V; Dadina, M

    2010-01-01

    We performed a blind search for narrow absorption features at energies greater than 6.4 keV in a sample of 42 radio-quiet AGNs observed with XMM-Newton. We detect 36 narrow absorption lines on a total of 101 XMM-Newton EPIC pn observations. The number of absorption lines at rest-frame energies E>7 keV is 22. Their global probability to be generated by random fluctuations is very low, less than 3x10^-8, and their detection have been independently confirmed by a spectral analysis of the MOS data, with associated random probability <10^-7. We identify the lines as Fe XXV and Fe XXVI K-shell resonant absorption. They are systematically blue-shifted, with a velocity distribution ranging from zero up to 0.3c, with a peak and mean value at 0.1c. We detect variability of the lines on both EWs and blue-shifted velocities among different observations even on time-scales as short as a few days, possibly suggesting somewhat compact absorbers. Moreover, we find no significant correlation between the cosmological red-sh...

  17. Irreversibility line and flux pinning properties in iron-based high-T{sub c} superconductor SmFeAsO{sub 0.85}

    Energy Technology Data Exchange (ETDEWEB)

    Ahmad, D.; Park, I.; Kim, G.C.; Lee, J.H. [Department of Physics, Pusan National University, Busan 609-735 (Korea, Republic of); Ren, Z.-A. [National Laboratory for Superconductivity, Institute of Physics, Chinese Academy of Sciences, P.O. Box 603, Beijing 100190 (China); Kim, Y.C., E-mail: yckim@pusan.ac.k [Department of Physics, Pusan National University, Busan 609-735 (Korea, Republic of)

    2009-10-15

    The irreversibility line and flux pinning properties of high-T{sub c} superconductor SmFeAsO{sub 0.85} were studied using DC magnetization data. Polycrystalline SmFeAsO{sub 0.85} was prepared in a high pressure synthesis apparatus under the pressure of 6 GPa. The results of DC susceptibility showed the superconducting transition at about 55 K. A critical current density J{sub c}(B) was calculated using Bean's critical state model. At low temperatures (<=20 K), J{sub c}(B) showed a relatively high value with weak dependence on an applied magnetic field. At higher temperatures, a stronger dependence of the magnetic field was observed, which resulted from decrease in a critical current density probably due to the flux creep effect. The irreversibility line (IL) agreed well with the flux creep theory of Matsushita et al. A comparison of normalized pinning force density with the theoretical models showed that the irreversible behavior in SmFeAsO{sub 0.85} is dominated mainly by normal point pinning (deltaT{sub c}) and surface pinning mechanisms.

  18. Supermassive Black Holes with High Accretion Rates in Active Galactic Nuclei. III. Detection of Fe II Reverberation in Nine Narrow-Line Seyfert 1 Galaxies

    CERN Document Server

    Hu, Chen; Lu, Kai-Xing; Li, Yan-Rong; Wang, Fang; Qiu, Jie; Bai, Jin-Ming; Kaspi, Shai; Ho, Luis C; Netzer, Hagai; Wang, Jian-Min

    2015-01-01

    This is the third in a series of papers reporting on a large reverberation-mapping campaign aimed to study the properties of active galactic nuclei (AGNs) with high accretion rates. We present new results on the variability of the optical Fe II emission lines in 10 AGNs observed by the Yunnan Observatory 2.4m telescope during 2012--2013. We detect statistically significant time lags, relative to the AGN continuum, in nine of the sources. This accurate measurement is achieved by using a sophisticated spectral fitting scheme that allows for apparent flux variations of the host galaxy, and several narrow lines, due to the changing observing conditions. Six of the newly detected lags are indistinguishable from the Hbeta lags measured in the same sources. Two are significantly longer and one is slightly shorter. Combining with Fe II lags reported in previous studies, we find a Fe II radius--luminosity relationship similar to the one for Hbeta, although our sample by itself shows no clear correlation. The results s...

  19. In vitro toxicity test and searching the possibility of cancer cell line extermination by magnetic heating with using Fe{sub 3}O{sub 4} magnetic fluid

    Energy Technology Data Exchange (ETDEWEB)

    Pham Hoai Linh; Nguyen Chi Thuan; Nguyen Anh Tuan; Pham Van Thach; Nguyen Xuan Phuc; Le Van Hong [Institute of Materials Science, Vietnam Academy of Science and Technology, 18 Hoang Quoc Viet Road, Cau Giay Distr., Hanoi (Viet Nam); Tran Cong Yen; Nguyen Thi Quy; Hoang Thi My Nhung; Phi Thi Xuyen [Biology Faculty, Hanoi University of Science, 334 Nguyen Trai Road, Thanh Xuan, Hanoi (Viet Nam)], E-mail: honglv@ims.vast.ac.vn

    2009-09-01

    A Fe{sub 3}O{sub 4} based magnetic fluid with different concentrations ranged between 0.15 ng/cell to 10 ng/cell (nano gram/cell) was used in the in vitro toxicity test on several cancer cell lines, Sarcoma 180, HeLa and H358. It shows that the fluid with a concentration of Fe{sub 3}O{sub 4} below 1.2 ng/cell is completely non-toxic for these cell lines. Even through in the presence of the highest concentration of 10 ng/cell, the cell viability still reaches more than 60%. The magnetic fluid with Fe{sub 3}O{sub 4} concentration of about 0.1 ng/cell was also used to search ex-vivo the possibility of Sarcoma 180 extermination by magnetic heating with an AC field of 120Oe and 184 KHz. The result shows that after a heat treatment for 30 min., 40% of Sarcoma 180 cells was killed.

  20. A frequent kinase domain mutation that changes the interaction between PI3K[alpha] and the membrane

    Energy Technology Data Exchange (ETDEWEB)

    Mandelker, Diana; Gabelli, Sandra B.; Schmidt-Kittler, Oleg; Zhu, Jiuxiang; Cheong, Ian; Huang, Chuan-Hsiang; Kinzler, Kenneth W.; Vogelstein, Bert; Amzel, L. Mario; (JHU-MED); (HHMI)

    2009-12-01

    Mutations in oncogenes often promote tumorigenesis by changing the conformation of the encoded proteins, thereby altering enzymatic activity. The PIK3CA oncogene, which encodes p110{alpha}, the catalytic subunit of phosphatidylinositol 3-kinase alpha (PI3K{alpha}), is one of the two most frequently mutated oncogenes in human cancers. We report the structure of the most common mutant of p110{alpha} in complex with two interacting domains of its regulatory partner (p85{alpha}), both free and bound to an inhibitor (wortmannin). The N-terminal SH2 (nSH2) domain of p85{alpha} is shown to form a scaffold for the entire enzyme complex, strategically positioned to communicate extrinsic signals from phosphopeptides to three distinct regions of p110{alpha}. Moreover, we found that Arg-1047 points toward the cell membrane, perpendicular to the orientation of His-1047 in the WT enzyme. Surprisingly, two loops of the kinase domain that contact the cell membrane shift conformation in the oncogenic mutant. Biochemical assays revealed that the enzymatic activity of the p110{alpha} His1047Arg mutant is differentially regulated by lipid membrane composition. These structural and biochemical data suggest a previously undescribed mechanism for mutational activation of a kinase that involves perturbation of its interaction with the cellular membrane.

  1. Resonant K-alpha spectroscopy of a hot dense plasma created by the LCLS x-ray free electron laser

    Science.gov (United States)

    Cho, Byoung-Ick; Engelhorn, K.; Falcone, R. W.; Heimann, P. A.; Vinko, S. M.; Ciricosta, O.; Higginbotham, A.; Murphy, C.; Wark, J. S.; Chung, H.-K.; Brown, C. R. D.; Burian, T.; Vysin, L.; Juha, L.; Lee, H. J.; Messersmidt, M.; Schlotter, W.; Turner, J.; Nagler, B.; Ping, Y.; Lee, R. W.; Toleikis, S.; Zastrau, U.

    2011-10-01

    We present one of the first experimental studies of the interaction of high intensity x-ray free electron laser radiation with solid density matter. In the experiment performed at the LCLS, an intense 80 fs x-ray pulse at 1017 Wcm-2 with photon energies of 1480 ~ 1560 eV is focused on a thin Al foil and K-alpha emission spectra are observed. Although x-ray photon energy is lower than the absorption edge, because of its high intensity the sample is surprisingly heated up to 100 ~200 eV in the pulse duration and a hot dense plasma is created. Observed x-ray spectra indicate this dense plasma resonantly interacts with the x-ray photons. The emission spectra are also simulated using the collisional-radiative code, SCFLY which provides information about the electron temperature and density, the charge state distribution and opacity. The comparison of experiment and simulation provides a detailed description of a dense plasma resonantly interacting with an intense x-ray pulse.

  2. Evidence for ultra-fast outflows in radio-quiet AGNs. I. Detection and statistical incidence of Fe K-shell absorption lines

    Science.gov (United States)

    Tombesi, F.; Cappi, M.; Reeves, J. N.; Palumbo, G. G. C.; Yaqoob, T.; Braito, V.; Dadina, M.

    2010-10-01

    Context. Blue-shifted Fe K absorption lines have been detected in recent years between 7 and 10 keV in the X-ray spectra of several radio-quiet AGNs. The derived blue-shifted velocities of the lines can often reach mildly relativistic values, up to 0.2-0.4c. These findings are important because they suggest the presence of a previously unknown massive and highly ionized absorbing material outflowing from their nuclei, possibly connected with accretion disk winds/outflows. Aims: The scope of the present work is to statistically quantify the parameters and incidence of the blue-shifted Fe K absorption lines through a uniform analysis on a large sample of radio-quiet AGNs. This allows us to assess their global detection significance and to overcome any possible publication bias. Methods: We performed a blind search for narrow absorption features at energies greater than 6.4 keV in a sample of 42 radio-quiet AGNs observed with XMM-Newton. A simple uniform model composed by an absorbed power-law plus Gaussian emission and absorption lines provided a good fit for all the data sets. We derived the absorption lines parameters and calculated their detailed detection significance making use of the classical F-test and extensive Monte Carlo simulations. Results: We detect 36 narrow absorption lines on a total of 101 XMM-Newton EPIC pn observations. The number of absorption lines at rest-frame energies higher than 7 keV is 22. Their global probability to be generated by random fluctuations is very low, less than 3 × 10-8, and their detection have been independently confirmed by a spectral analysis of the MOS data, with associated random probability UFOs) those highly ionized absorbers with outflow velocities higher than 104 km s-1, then the majority of the lines are consistent with being associated to UFOs and the fraction of objects with detected UFOs in the whole sample is at least ~35%. This fraction is similar for type 1 and type 2 sources. The global covering fraction of

  3. Magnetic-field-induced crossover of vortex-line coupling in SmFeAsO0.85 single crystal

    Science.gov (United States)

    Lee, Hyun-Sook; Bartkowiak, Marek; Kim, Jun Sung; Lee, Hu-Jong

    2010-09-01

    We take the resistivity (ρ) and the current-voltage (I-V) characteristics of a SmFeAsO0.85 single crystal as a function of temperature (T) for various magnetic fields up to 18 T along the c axis. The tail region of ρ(T) well fits the three-dimensional (3D) vortex-glass critical behavior. The critical exponents for the vortex-glass scaling of (dlnρ/dT)-1-T , I-V curves, and the thermal activation energies of vortices in magnetic fields show a crossover for magnetic fields around 3 T. The crossover behavior results from the change in the strength of the vortex pinning and the entanglement of vortex lines in the stacked superconducting structure of SmFeAsO0.85 material with the c -axis vortex-line coupling lying in between highly anisotropic Bi-based cuprates with decoupled two-dimensional vortices and less-anisotropic YBa2Cu3O7-δ with coupled 3D vortices.

  4. Evidence for ultra-fast outflows in radio-quiet AGNs: II - detailed photo-ionization modeling of Fe K-shell absorption lines

    CERN Document Server

    Tombesi, F; Reeves, J N; Palumbo, G G C; Braito, V; Dadina, M

    2011-01-01

    X-ray absorption line spectroscopy has recently shown evidence for previously unknown Ultra-fast Outflows (UFOs) in radio-quiet AGNs. In the previous paper of this series we defined UFOs as those absorbers with an outflow velocity higher than 10,000km/s and assessed the statistical significance of the associated blueshifted FeK absorption lines in a large sample of 42 local radio-quiet AGNs observed with XMM-Newton. In the present paper we report a detailed curve of growth analysis and directly model the FeK absorbers with the Xstar photo-ionization code. We confirm that the frequency of sources in the radio-quiet sample showing UFOs is >35%. The outflow velocity distribution spans from \\sim10,000km/s (\\sim0.03c) up to \\sim100,000km/s (\\sim0.3c), with a peak and mean value of \\sim42,000km/s (\\sim0.14c). The ionization parameter is very high and in the range log\\xi 3-6erg s^{-1} cm, with a mean value of log\\xi 4.2 erg s^{-1} cm. The associated column densities are also large, in the range N_H\\sim10^{22}-10^{24...

  5. Temperature sensitivity of Cu K(alpha) imaging efficiency using a spherical Bragg reflecting crystal

    Energy Technology Data Exchange (ETDEWEB)

    Akli, K U; Key, M H; Chung, H K; Hansen, S B; Freeman, R R; Chen, M H; Gregori, G; Hatchett, S; Hey, D; Izumi, N; King, J A; Kuba, J; Norreys, P; Mackinnon, A J; Murphy, C D; Snavely, R; Stepehens, R; Stoeckel, C; Theobald, W; Zhang, B

    2006-08-07

    The Vulcan laser facility at the Rutherford Appleton Laboratory was used to study the interaction of a 75 J 10 ps, high intensity laser beam with low-mass solid, Cu targets. Two instruments were fielded as diagnostics of the Cu K-shell emission from the targets: A single photon counting CCD spectrometer provided the absolute K{sub {alpha}} yield and a spherically bent Bragg crystal recorded 2D monochromatic images with a spatial resolution of 10 {micro}m. Due to the shifting and broadening of the K{sub {alpha}} spectral lines with increasing temperature, there is a temperature dependence of the crystal collection efficiency. This provides a temperature diagnostic when cross calibrated against a single hit CCD spectrometer, and it affects measurements of the spatial pattern of electron transport. The experimental data showing changing collection efficiency are presented. The results are discussed in light of modeling of the temperature-dependent spectrum of Cu K-shell emission.

  6. Deriving the extinction to young stellar objects using [FeII] near-infrared emission lines. Prescriptions from GIANO high-resolution spectra

    CERN Document Server

    Pecchioli, Tommaso; Massi, Fabrizio; Oliva, Ernesto

    2016-01-01

    The near-infrared emission lines of Fe$^{+}$ at 1.257, 1.321, and 1.644 $\\mu$m share the same upper level; their ratios can then be exploited to derive the extinction to a line emitting region once the relevant spontaneous emission coefficients are known. This is commonly done, normally from low-resolution spectra, in observations of shocked gas from jets driven by Young Stellar Objects. In this paper we review this method, provide the relevant equations, and test it by analyzing high-resolution ($R \\sim 50000$) near-infrared spectra oftwo young stars, namely the Herbig Be star HD 200775 and the Be star V1478 Cyg, which exhibit intense emission lines. The spectra were obtained with the new GIANO echelle spectrograph at the Telescopio Nazionale Galileo. Notably, the high-resolution spectra allowed checking the effects of overlapping telluric absorption lines. A set of various determinations of the Einstein coefficients are compared to show how much the available computations affect extinction derivation. The m...

  7. Evidence for Ultra-fast Outflows in Radio-quiet Active Galactic Nuclei. II. Detailed Photoionization Modeling of Fe K-shell Absorption Lines

    Science.gov (United States)

    Tombesi, F.; Cappi, M.; Reeves, J. N.; Palumbo, G. G. C.; Braito, V.; Dadina, M.

    2011-11-01

    X-ray absorption line spectroscopy has recently shown evidence for previously unknown Ultra-fast Outflows (UFOs) in radio-quiet active galactic nuclei (AGNs). These have been detected essentially through blueshifted Fe XXV/XXVI K-shell transitions. In the previous paper of this series we defined UFOs as those highly ionized absorbers with an outflow velocity higher than 10,000 km s-1 and assessed the statistical significance of the associated blueshifted absorption lines in a large sample of 42 local radio-quiet AGNs observed with XMM-Newton. The present paper is an extension of that work. First, we report a detailed curve of growth analysis of the main Fe XXV/XXVI transitions in photoionized plasmas. Then, we estimate an average spectral energy distribution for the sample sources and directly model the Fe K absorbers in the XMM-Newton spectra with the detailed Xstar photoionization code. We confirm that the frequency of sources in the radio-quiet sample showing UFOs is >35% and that the majority of the Fe K absorbers are indeed associated with UFOs. The outflow velocity distribution spans from ~10,000 km s-1 (~0.03c) up to ~100,000 km s-1 (~0.3c), with a peak and mean value of ~42,000 km s-1 (~0.14c). The ionization parameter is very high and in the range log ξ ~ 3-6 erg s-1 cm, with a mean value of log ξ ~ 4.2 erg s-1 cm. The associated column densities are also large, in the range N H ~ 1022-1024 cm-2, with a mean value of N H ~ 1023 cm-2. We discuss and estimate how selection effects, such as those related to the limited instrumental sensitivity at energies above 7 keV, may hamper the detection of even higher velocities and higher ionization absorbers. We argue that, overall, these results point to the presence of extremely ionized and possibly almost Compton-thick outflowing material in the innermost regions of AGNs. This also suggests that UFOs may potentially play a significant role in the expected cosmological feedback from AGNs and their study can

  8. XRD line-broadening characteristics of M-oxides (M = Mg, Mg-Al, Y, Fe) nanoparticles produced by coprecipitation method

    Science.gov (United States)

    Pratapa, S.; Susanti, L.; Insany, Y. A. S.; Alfiati, Z.; Hartono, B.; Mashuri, Taufiq, Ahmad; Fuad, Abdullah; Triwikantoro, Baqiya, M. A.; Purwaningsih, S.; Yahya, E.; Darminto

    2010-10-01

    Simple coprecipitation method has been used to produce nanoparticles of MgO (magnesia), MgOṡAl2O3 (spinel), Y2O3 (yttria) and Fe3O4 (ferrite). The raw materials were, in respective, magnesium powder, magnesium and aluminium powders, ytrria powder, and natural sand. The coprecipitation included the use of suitable acid and base to dissolve the powders or sand and to produce precipitates, as well as the use of water to wash and purify the precipitates, and drying at relatively low temperatures, namely lower than 100° C, followed by heating at 450° C, 750° C, 600° C and 200° C to produce magnesia, spinel, yttria and ferrite nanopowders, respectively. X-ray diffractometry was used to characterise the purity and nanocrystallinity of the final powders. It was found qualitatively that the powders were of high purity. Further line-broadening analysis using single-line and Rietveld-based softwares was performed to reveal the nanocrystallinity of the powders. Different line breadth values were found for the powders, indicating different crystallite sizes. It was also found that, particularly for spinel and yttria, the diffraction peaks exhibited `longer' tails, indicating broader crystallite size distribution. The average crystallite size for the powders ranged from 3 to 70 nm. The results could then be used as `fingerprints' for nanocrystallinity using x-ray diffractometry. The XRD crystallite sizes for yttria and ferrite nanocrystals are in fair agreement with their counterparts from electron microscopy observation.

  9. Broad Fe-emission line in the new X-ray transient XTE J1652-453

    NARCIS (Netherlands)

    Hiemstra, Beike

    2010-01-01

    Broad iron-emission lines, as detected in X-ray spectra of black-hole binaries, are thought to be reflection signatures of the inner part of the accretion disk and could be used to explore the physical properties of the emitting region close to the black hole. Here we present the recent results of t

  10. An Fe XXIV Absorption Line in the Persistent Spectrum of the Dipping Low-Mass X-Ray Binary 1A 1744-361

    Science.gov (United States)

    Gavriil, Fotis P.; Strohmayer, Tod E.; Bhattacharyya, Sudip

    2012-01-01

    We report on Chandra X-ray Observatory (Chandra) High Energy Transmission Grating spectra of the dipping low-mass X-ray binary 1A 1744-361 during its 2008 July outburst. We find that its persistent emission is well modeled by a blackbody (kT approx. 1.0 keV) plus power law (Gamma approx. 1.7) with an absorption edge. In the residuals of the combined spectrum, we find a significant absorption line at 6.961 +/- 0.002 keV, consistent with the Fe xxvi (hydrogen-like Fe) 2-1 transition.We place an upper limit on the velocity of a redshifted flow of nu 103.6 erg cm/s. We discuss what implications the feature has on the system and its geometry. We also present Rossi X-ray Timing Explorer data accumulated during this latest outburst and, via an updated color-color diagram, clearly show that 1A 1744-361 is an "atoll" source

  11. Vortex dynamics and irreversibility line in optimally doped SmFeAsO0.8F0.2 from ac susceptibility and magnetization measurements

    Science.gov (United States)

    Prando, G.; Carretta, P.; de Renzi, R.; Sanna, S.; Palenzona, A.; Putti, M.; Tropeano, M.

    2011-05-01

    Ac susceptibility and static magnetization measurements were performed in the optimally doped SmFeAsO0.8F0.2 superconductor. The field-temperature phase diagram of the superconducting state was drawn, and, in particular, the features of the flux lines were derived. The dependence of the intragrain depinning energy on the magnetic field intensity was derived in the thermally activated flux-creep framework, enlightening a typical 1/H dependence in the high-field regime. The intragrain critical current density was extrapolated in the zero-temperature and zero-magnetic-field limit, showing a remarkably high value Jc0(0)~2×107 A/cm2, which demonstrates that this material is rather interesting for potential future technological applications.

  12. 3D-FE Modeling of 316 SS under Strain-Controlled Fatigue Loading and CFD Simulation of PWR Surge Line

    Energy Technology Data Exchange (ETDEWEB)

    Mohanty, Subhasish [Argonne National Lab. (ANL), Argonne, IL (United States); Barua, Bipul [Argonne National Lab. (ANL), Argonne, IL (United States); Listwan, Joseph [Argonne National Lab. (ANL), Argonne, IL (United States); Majumdar, Saurin [Argonne National Lab. (ANL), Argonne, IL (United States); Natesan, Ken [Argonne National Lab. (ANL), Argonne, IL (United States)

    2017-03-01

    In financial year 2017, we are focusing on developing a mechanistic fatigue model of surge line pipes for pressurized water reactors (PWRs). To that end, we plan to perform the following tasks: (1) conduct stress- and strain-controlled fatigue testing of surge-line base metal such as 316 stainless steel (SS) under constant, variable, and random fatigue loading, (2) develop cyclic plasticity material models of 316 SS, (3) develop one-dimensional (1D) analytical or closed-form model to validate the material models and to understand the mechanics associated with 316 SS cyclic hardening and/or softening, (4) develop three-dimensional (3D) finite element (FE) models with implementation of evolutionary cyclic plasticity, and (5) develop computational fluid dynamics (CFD) model for thermal stratification, thermal-mechanical stress, and fatigue of example reactor components, such as a PWR surge line under plant heat-up, cool-down, and normal operation with/without grid-load-following. This semi-annual progress report presents the work completed on the above tasks for a 316 SS laboratory-scale specimen subjected to strain-controlled cyclic loading with constant, variable, and random amplitude. This is the first time that the accurate 3D-FE modeling of the specimen for its entire fatigue life, including the hardening and softening behavior, has been achieved. We anticipate that this work will pave the way for the development of a fully mechanistic-computer model that can be used for fatigue evaluation of safety-critical metallic components, which are traditionally evaluated by heavy reliance on time-consuming and costly test-based approaches. This basic research will not only help the nuclear reactor industry for fatigue evaluation of reactor components in a cost effective and less time-consuming way, but will also help other safety-related industries, such as aerospace, which is heavily dependent on test-based approaches, where a single full-scale fatigue test can cost

  13. A CARMA Spectral Line and Continuum Survey of the Central Molecular Zone

    Science.gov (United States)

    Pound, Marc W.; Yusef-Zadeh, F.

    2014-01-01

    Because of its large angular extent, the Central Molecular Zone has to date only been mapped at millimeter wavelengths with singledish telescopes, with resolution about 1.2 pc (30"). We have completed a 3 mm continuum and spectral line interferometric maps made with CARMA of a 90 pc X 50 pc region of the CMZ (0.6 < l < -0.2; 0.15 < b < -0.2), with resolution of ~0.3 pc We present here the first results of this survey. One of the advantages of observing the Galactic Center at 3mm with CARMA iis that it allows identification of different classes of objects in this confusing region of the Galaxy. This is the first 3mm continuum survey showing a high concentration of HII complexes, and thermal and nonthermal sources distributed throughout the region. Our continuum survey identifies a number of infrared dark clouds, the most prominent of which is G0.253+0.016, part of a chain of clouds forming a ridge of molecular gas between G0.253+0.016 and Sgr B2. We also see emission from the magnetized filaments in the l = 0.2 Radio Arc. We combined our spectral line maps of SiO(2-1), HCO+(1-0), HCN(1-0), N2H+(1-0) with the MOPRA singledish survey so the final maps include all spatial frequencies down to 3". The combined CARMA plus MOPRA maps show a rich structure of both compact and filamentary clouds. We examine the relationship between the distribution of molecular line emission, the 6.4 keV Fe K-alpha emission, and the nonthermal radio emission and discuss preliminary results of the analysis.

  14. Testing the Kerr Nature of Black Hole Candidates using Iron Line Spectra in the CPR Framework

    CERN Document Server

    Jiang, Jiachen; Steiner, James F

    2015-01-01

    The iron K$\\alpha$ line commonly observed in the X-ray spectrum of both stellar-mass and supermassive black hole candidates originates from X-ray fluorescence of the inner accretion disk. Accordingly, it can be used to map the spacetime geometry around these objects. In this paper, we extend previous work using the iron K$\\alpha$ line to test the Kerr black hole hypothesis. We adopt the Cardoso-Pani-Rico parametrization and we test the possibility of constraining possible deviations from the Kerr solution that can be obtained from observations across the range of black hole spins and inclination angles. We confirm previous claims that the iron K$\\alpha$ line is potentially a quite powerful probe for testing the Kerr metric given sufficiently high quality data and with systematics under control, especially in the case of fast-rotating black holes and high inclination angles since both conditions serve to maximize relativistic effects. We find that some geometric perturbations from Kerr geometry manifest more s...

  15. Suzaku Discovery of Fe K-Shell Line from the O-Rich SNR G292.0+1.8

    CERN Document Server

    Kamitsukasa, Fumiyoshi; Tsunemi, Hiroshi; Hayashida, Kiyoshi; Nakajima, Hiroshi; Takahashi, Hiroaki; Ueda, Shutaro; Mori, Koji; Katsuda, Satoru; Uchida, Hiroyuki

    2014-01-01

    We report the Suzaku/XIS results of the Galactic oxygen-rich supernova remnant (SNR), G292.0+1.8, a remnant of a core-collapse supernova. The X-ray spectrum of G292.0+1.8 consists of two type plasmas, one is in collisional ionization equilibrium (CIE) and the other is in non-equilibrium ionization (NEI). The CIE plasma has nearly solar abundances, and hence would be originated from the circumstellar and interstellar mediums. The NEI plasma has super-solar abundances, and the abundance pattern indicates that the plasma originates from the supernova ejecta with a main sequence of 30-35 Msolar. Iron K-shell line at energy of 6.6 keV is detected for the first time in the NEI plasma.

  16. An FE Based On-line Model for the Prediction of Work Roll Thermal Profile in Hot Strip Rolling

    Science.gov (United States)

    Choi, Ji Won; Lee, Jung Hyeung; Sun, Cheng Gang; Hwang, Sang Moo

    2010-06-01

    Prediction and control of the thermal deformation of the work roll is vital for enhancing product quality in hot strip and plate rolling. In this paper, we present an on-line model for the prediction of the work roll thermal profile. The model is developed on the basis of an integrated finite element model for the coupled analysis of heat transfer and deformation occurring at the bite zone, to rigorously take into account the effect of various rolling parameters on the thermal behavior of the work roll. The validity of the model is demonstrated through comparison with measurements made in an industrial hot strip mill. Also, an emphasis is given to the examination the effect of some selected rolling parameters in an actual production environment.

  17. Evidence for Ultra-Fast Outflows in Radio-Quiet AGNs. 2; Detailed Photoionization Modeling of Fe K-Shell Absorption Lines

    Science.gov (United States)

    Tombesi, Francesco; Clapp, M.; Reeves, J. N.; Palumbo, G. G. C.; Braito, V.; Dadina, M.

    2011-01-01

    X-ray absorption line spectroscopy has recently shown evidence for previously unknown Ultra-fast Outflows (UFOs) in radio-quiet AGNs. In the previous paper of this series we defined UFOs as those absorbers with an outflow velocity higher than 10,000km/s and assessed the statistical significance of the associated blue shifted FeK absorption lines in a large sample of 42 local radio-quiet AGNs observed with XMM-Newton. In the present paper we report a detailed curve of growth analysis and directly model the FeK absorbers with the Xstar photo-ionization code. We confirm that the frequency of sources in the radio-quiet sample showing UFOs is >35%. The outflow velocity distribution spans from \\sim10,000km/s (\\sim0.03c) up to \\siml00,000kmis (\\sim0.3c), with a peak and mean value of\\sim42,000km/s (\\sim0.14c). The ionization parameter is very high and in the range log\\xi 3-6 erg s/cm, with a mean value of log\\xi 4.2 erg s/cm. The associated column densities are also large, in the range N_H\\siml0(exp 22)-10(exp 24)/sq cm, with a mean value of N_H\\siml0(exp23)/sq cm. We discuss and estimate how selection effects, such as those related to the limited instrumental sensitivity at energies above 7keV, may hamper the detection of even higher velocities and higher ionization absorbers. We argue that, overall, these results point to the presence of extremely ionized and possibly almost Compton thick outflowing material in the innermost regions of AGNs. This also suggests that UFOs may potentially play a significant role in the expected cosmological feedback from AGNs and their study can provide important clues on the connection between accretion disks, winds and jets.

  18. Investigation of superparamagnetic (Fe3O4) nanoparticles and magnetic field exposures on CHO-K1 cell line

    Science.gov (United States)

    Coker, Zachary; Estlack, Larry; Hussain, Saber; Choi, Tae-Youl; Ibey, Bennett L.

    2016-03-01

    Rapid development in nanomaterial synthesis and functionalization has led to advanced studies in actuation and manipulation of cellular functions for biomedical applications. Often these actuation techniques employ externally applied magnetic fields to manipulate magnetic nanomaterials inside cell bodies in order to drive or trigger desired effects. While cellular interactions with low-frequency magnetic fields and nanoparticles have been extensively studied, the fundamental mechanisms behind these interactions remain poorly understood. Additionally, modern investigations on these concurrent exposure conditions have been limited in scope, and difficult to reproduce. This study presents an easily reproducible method of investigating the biological impact of concurrent magnetic field and nanoparticle exposure conditions using an in-vitro CHO-K1 cell line model, with the purpose of establishing grounds for in-depth fundamental studies of the mechanisms driving cellular-level interactions. Cells were cultured under various nanoparticle and magnetic field exposure conditions from 0 to 500 μg/ml nanoparticle concentrations, and DC, 50 Hz, or 100 Hz magnetic fields with 2.0 mT flux density. Cells were then observed by confocal fluorescence microscopy, and subject to biological assays to determine the effects of concurrent extreme-low frequency magnetic field and nanoparticle exposures on cellnanoparticle interactions, such as particle uptake and cell viability by MTT assay. Current results indicate little to no variation in effect on cell cultures based on magnetic field parameters alone; however, it is clear that deleterious synergistic effects of concurrent exposure conditions exist based on a significant decrease in cell viability when exposed to high concentrations of nanoparticles and concurrent magnetic field.

  19. DENSITY DETERMINATIONS OF THE CORONAE OF COOL STARS USING A NEWLY ASSIGNED PAIR OF Fe xiv LINES IN THE SPECTRA OF α CANIS MINOR, α CENTAURI, AND THE SUN

    Energy Technology Data Exchange (ETDEWEB)

    Beiersdorfer, P.; Hell, N. [Physics Division, Lawrence Livermore National Laboratory, Livermore, CA 94550 (United States); Lepson, J. K. [Space Sciences Laboratory, University of California, Berkeley, CA 94720 (United States); Diaz, F.; Ishikawa, Y., E-mail: beiersdorfer@llnl.gov [Department of Chemistry and the Chemical Physics Program, University of Puerto Rico, San Juan, PR 00931 (United States)

    2015-12-10

    We have identified a previously unassigned pair of lines between 169 and 170 Å in the coronae of cool stars. We attribute these lines to Fe xiv and show that their intensity ratio is sensitive to the electron density. Using observations taken with the Low Energy Transmission Grating Spectrometer of the Chandra X-ray Observatory we infer a density of log(n{sub e}/cm{sup −3})  =  10.2 ± 0.7 and 10.3 ± 0.8 from the newly identified line pair in the coronae of Procyon and α Cen A, respectively.

  20. Determination of Histamine in Silages Using Nanomaghemite Core (γ-Fe2O3)-Titanium Dioxide Shell Nanoparticles Off-Line Coupled with Ion Exchange Chromatography

    Science.gov (United States)

    Cernei, Natalia; Lackova, Zuzana; Guran, Roman; Hynek, David; Skladanka, Jiri; Horky, Pavel; Zitka, Ondrej; Adam, Vojtech

    2016-01-01

    The presence of biogenic amines is a hallmark of degraded food and its products. Herein, we focused on the utilization of magnetic nanoparticles off-line coupled with ion exchange chromatography with post-column ninhydrin derivatization and Vis detection for histamine (Him) separation and detection. Primarily, we described the synthesis of magnetic nanoparticles with nanomaghemite core (γ-Fe2O3) functionalized with titanium dioxide and, then, applied these particles to specific isolation of Him. To obtain further insight into interactions between paramagnetic particles’ (PMP) surface and Him, a scanning electron microscope was employed. It was shown that binding of histamine causes an increase of relative current response of deprotonated PMPs, which confirmed formation of Him-PMPs clusters. The recovery of the isolation showed that titanium dioxide-based particles were able to bind and preconcentrate Him with recovery exceeding 90%. Finally, we successfully carried out the analyses of real samples obtained from silage. We can conclude that our modified particles are suitable for Him isolation, and thus may serve as the first isolation step of Him from biological samples, as it is demonstrated on alfalfa seed variety Tereza silage. PMID:27626434

  1. Determination of Histamine in Silages Using Nanomaghemite Core (γ-Fe2O3-Titanium Dioxide Shell Nanoparticles Off-Line Coupled with Ion Exchange Chromatography

    Directory of Open Access Journals (Sweden)

    Natalia Cernei

    2016-09-01

    Full Text Available The presence of biogenic amines is a hallmark of degraded food and its products. Herein, we focused on the utilization of magnetic nanoparticles off-line coupled with ion exchange chromatography with post-column ninhydrin derivatization and Vis detection for histamine (Him separation and detection. Primarily, we described the synthesis of magnetic nanoparticles with nanomaghemite core (γ-Fe2O3 functionalized with titanium dioxide and, then, applied these particles to specific isolation of Him. To obtain further insight into interactions between paramagnetic particles’ (PMP surface and Him, a scanning electron microscope was employed. It was shown that binding of histamine causes an increase of relative current response of deprotonated PMPs, which confirmed formation of Him-PMPs clusters. The recovery of the isolation showed that titanium dioxide-based particles were able to bind and preconcentrate Him with recovery exceeding 90%. Finally, we successfully carried out the analyses of real samples obtained from silage. We can conclude that our modified particles are suitable for Him isolation, and thus may serve as the first isolation step of Him from biological samples, as it is demonstrated on alfalfa seed variety Tereza silage.

  2. Luminous and Variable Stars in M31 and M33. II. Luminous Blue Variables, Candidate LBVs, Fe II Emission Line Stars, and Other Supergiants

    CERN Document Server

    Humphreys, Roberta M; Davidson, Kris; Bomans, D J; Burggraf, Birgitta

    2014-01-01

    An increasing number of non-terminal eruptions are being found in the numerous surveys for optical transients. Very little is known about these giant eruptions, their progenitors and their evolutionary state. A greatly improved census of the likely progenitor class, including the most luminous evolved stars, the Luminous Blue Varaibles (LBVs), and the warm and cool hypergiants is now needed for a complete picture of the final pre-SN stages of very massive stars. We have begun a survey of the evolved and un stable luminous star populations in several nearby resolved galaxies. In this second paper on M31 and M33, we review the spectral characteristics, spectral energy distributions, circumstellar ejecta, and evidence for mass loss for 82 luminous and variable stars.We show that many of these stars have warm circumstellar dust including several of the Fe II emission line stars, but conclude that the confirmed LBVs in M31 and M33 do not. The confirmed LBVs have relatively low wind speeds even in their hot, quiesc...

  3. Evidence for a relativistic iron line in GRS 1915+105

    CERN Document Server

    Martocchia, A; Karas, V; Belloni, T; Feroci, M

    2002-01-01

    We report on the discovery of a relativistic iron K\\alpha fluorescent emission line in the BeppoSAX spectrum of the microquasar GRS 1915+105, taken on April 19, 1998, when the line was unusually intense. The feature is broad and skewed, clearly indicating emission from the innermost regions of the accretion disc. The inner emitting orbit is larger than the innermost stable orbit, even in Schwarzschild metric: thus, a non-zero BH spin is not required by these data.

  4. Umbelliprenin-coated Fe{sub 3}O{sub 4} magnetite nanoparticles: Antiproliferation evaluation on human Fibrosarcoma cell line (HT-1080)

    Energy Technology Data Exchange (ETDEWEB)

    Khorramizadeh, M.R. [Department of Pathobiology, Faculty of Public Health, Tehran University of Medical Sciences, Tehran (Iran, Islamic Republic of); Esmail-Nazari, Z. [Department of Pharmaceutical Biotechnology and Biotechnology Research Center, Faculty of Pharmacy, Tehran University of Medical Sciences, Tehran (Iran, Islamic Republic of); Zarei-Ghaane, Z. [Department of Pathobiology, Faculty of Public Health, Tehran University of Medical Sciences, Tehran (Iran, Islamic Republic of); Shakibaie, M. [Department of Pharmaceutical Biotechnology and Biotechnology Research Center, Faculty of Pharmacy, Tehran University of Medical Sciences, Tehran (Iran, Islamic Republic of); Department of Pharmaceutical Biotechnology, Faculty of Pharmacy, Kerman University of Medical Sciences, Kerman (Iran, Islamic Republic of); Mollazadeh-Moghaddam, K. [Students Scientific Research Center, Tehran University of Medical Sciences, Tehran (Iran, Islamic Republic of); Iranshahi, M. [Department of Pharmacognosy, Faculty of Pharmacy, Mashhad University of Medical Sciences, Mashhad (Iran, Islamic Republic of); Shahverdi, A.R., E-mail: shahverd@sina.tums.ac.ir [Department of Pharmaceutical Biotechnology and Biotechnology Research Center, Faculty of Pharmacy, Tehran University of Medical Sciences, Tehran (Iran, Islamic Republic of)

    2010-08-30

    The potential applications of Fe{sub 3}O{sub 4} magnetite nanoparticles (MNPs) in nanomedicine as drug delivery systems are well known. In this study we prepared umbelliprenin-coated Fe{sub 3}O{sub 4} MNPs and evaluated the antiproliferative effect of combination in vitro. After synthesis of Fe{sub 3}O{sub 4} MNPs, particles were characterized by transmission electron microscopy, energy-dispersive spectroscopy, and X-ray diffraction spectroscopy techniques. The natural candidate compound - umbelliprenin- was isolated and identified and umbelliprenin-coated Fe{sub 3}O{sub 4} MNPs were prepared, using precipitation method. The surface chemistry of umbelliprenin-coated Fe{sub 3}O{sub 4} MNPs as well as their thermal decomposition characteristics was examined using Fourier transform infrared spectroscopy and Thermogravimetric Analyzer equipment, respectively. HT-1080 cells were cultured until the logarithmic phase of growth, and MTT assay was successfully carried out to evaluate the possible cytotoxic effects of umbelliprenin-coated Fe{sub 3}O{sub 4} MNPs in viable cells in vitro. The results demonstrated that umbelliprenin has moderate antiproliferative effects with IC{sub 50} value of 50 {mu}g/mL. However, the combination of umbelliprenin and Fe{sub 3}O{sub 4} MNPs showed the IC{sub 50} value of 9 {mu}g/mL. In other words, cell proliferation decreased to the remarkably-low proportion of 45% after treating cells with umbelliprenin-coated Fe{sub 3}O{sub 4} MNPs. This suggests that with the aid of nanoparticles as carriers, natural products may have even broader range of medical applications in future.

  5. Development and operation of a Pr2 Fe14 B based cryogenic permanent magnet undulator for a high spatial resolution x-ray beam line

    Science.gov (United States)

    Benabderrahmane, C.; Valléau, M.; Ghaith, A.; Berteaud, P.; Chapuis, L.; Marteau, F.; Briquez, F.; Marcouillé, O.; Marlats, J.-L.; Tavakoli, K.; Mary, A.; Zerbib, D.; Lestrade, A.; Louvet, M.; Brunelle, P.; Medjoubi, K.; Herbeaux, C.; Béchu, N.; Rommeluere, P.; Somogyi, A.; Chubar, O.; Kitegi, C.; Couprie, M.-E.

    2017-03-01

    Short period, high field undulators are used to produce hard x-rays on synchrotron radiation based storage ring facilities of intermediate energy and enable short wavelength free electron laser. Cryogenic permanent magnet undulators take benefit from improved magnetic properties of RE2 Fe14B (Rare Earth based magnets) at low temperatures for achieving short period, high magnetic field and high coercivity. Using Pr2 Fe14B instead of Nd2 Fe14B , which is generally employed for undulators, avoids the limitation caused by the spin reorientation transition phenomenon, and simplifies the cooling system by allowing the working temperature of the undulator to be directly at the liquid nitrogen one (77 K). We describe here the development of a full scale (2 m), 18 mm period Pr2 Fe14B cryogenic permanent magnet undulator (U18). The design, construction and optimization, as well as magnetic measurements and shimming at low temperature are presented. The commissioning and operation of the undulator with the electron beam and spectrum measurement using the Nanoscopmium beamline at SOLEIL are also reported.

  6. Development and operation of a Pr_{2}Fe_{14}B based cryogenic permanent magnet undulator for a high spatial resolution x-ray beam line

    Directory of Open Access Journals (Sweden)

    C. Benabderrahmane

    2017-03-01

    Full Text Available Short period, high field undulators are used to produce hard x-rays on synchrotron radiation based storage ring facilities of intermediate energy and enable short wavelength free electron laser. Cryogenic permanent magnet undulators take benefit from improved magnetic properties of RE_{2}Fe_{14}B (Rare Earth based magnets at low temperatures for achieving short period, high magnetic field and high coercivity. Using Pr_{2}Fe_{14}B instead of Nd_{2}Fe_{14}B, which is generally employed for undulators, avoids the limitation caused by the spin reorientation transition phenomenon, and simplifies the cooling system by allowing the working temperature of the undulator to be directly at the liquid nitrogen one (77 K. We describe here the development of a full scale (2 m, 18 mm period Pr_{2}Fe_{14}B cryogenic permanent magnet undulator (U18. The design, construction and optimization, as well as magnetic measurements and shimming at low temperature are presented. The commissioning and operation of the undulator with the electron beam and spectrum measurement using the Nanoscopmium beamline at SOLEIL are also reported.

  7. The Redshifted Hydrogen Balmer and Metastable He I Absorption Line System in Mini-FeLoBAL Quasar SDSS J112526.12+002901.3: A Parsec Scale Accretion Inflow?

    CERN Document Server

    Shi, Xi-Heng; Wang, Hui-Yuan; Zhang, Shao-Hua; Ji, Tuo; Liu, Wen-Juan; Zhou, Hong-Yan

    2016-01-01

    The accretion of interstellar medium onto the central super massive black holes is widely accepted as the source of the gigantic energy released by the active galactic nuclei. But few pieces of observational evidence have been confirmed directly demonstrating the existence of the inflows. The absorption line system in the spectra of quasar SDSS J112526.12+002901.3 presents an interesting example, in which the rarely detected hydrogen Balmer and metastable He I absorption lines are found redshifted to the quasar's rest frame along with the low-ionization metal absorption lines Mg II, Fe II, etc. The repeated SDSS spectroscopic observations suggest a transverse velocity smaller than the radial velocity. The motion of the absorbing medium is thus dominated by infall. The He I* lines present a powerful probe to the strength of ionizing flux, while the Balmer lines imply a dense environment. With the help of photoionization simulations, we find the absorbing medium is exposed to the radiation with ionization param...

  8. A deep X-ray view of the bare AGN Ark 120. II. Evidence for Fe K emission transients

    CERN Document Server

    Nardini, E; Reeves, J N; Braito, V; Lobban, A; Matt, G

    2016-01-01

    We report on the results from a large observational campaign on the bare Seyfert galaxy Ark 120, jointly carried out in 2014 with XMM-Newton, Chandra, and NuSTAR. The fortunate line of sight to this source, devoid of any significant absorbing material, provides an incomparably clean view to the nuclear regions of an active galaxy. Here we focus on the analysis of the iron fluorescence features, which form a composite emission pattern in the 6$-$7 keV band. The prominent K$\\alpha$ line from neutral iron at 6.4 keV is resolved in the Chandra High-Energy Transmission Grating spectrum to a full-width at half maximum of 4700$^{+2700}_{-1500}$ km s$^{-1}$, consistent with an origin from the optical broad-line region. Excess components are detected on both sides of the narrow K$\\alpha$ line: the red one (6.0$-$6.3 keV) clearly varies in strength in about one year, and hints at the presence of a broad, mildly asymmetric line from the accretion disk; the blue one (6.5$-$7.0 keV), instead, is likely a blend of differen...

  9. Crystal structure of Fe(HPO sub 3 ). Structure cristalline du phosphite acide de Fe sup III , Fe(HPO sub 3 H) sub 3

    Energy Technology Data Exchange (ETDEWEB)

    Sghyar, M.; Rafiq, M. (Faculte des Sciences, Fes (Morocco). Lab. de Chimie Minerale Appliquee); Durand, J.; Cox, L. (Centre National de la Recherche Scientifique, 34 - Montpellier (France). Lab. de Physicochimie des Materiaux)

    1991-01-15

    Fe(HPO{sub 3}H){sub 3}, M{sub r}=298.8, monoclinic, Cc, a=13.619(4), b=6.422(1), c=9.699(3) A, {beta}=106.27(2)deg, V=814.3(7) A{sup 3}, Z=4, D{sub m}=2.507 (by picnometry), D{sub x}=2.438 Mg m{sup -3}, {lambda}(Mo K{alpha})=0.71069 A, {mu}=2.21 mm{sup -1}, F(000)=428, room temperature. Final R=0.051, wR=0.35 for 642 independent reflections. Fe(HPO{sub 3}H){sub 3} has been studied by single-crystal X-ray analysis with an automatic diffractometer. The structure is built up of a three-dimensional network of FeO{sub 6} octahedra and HPO{sub 3}H{sup -} tetrahedra. Three hydrogenphosphite anions are hydrogen bonded and constituted an (HPO{sub 3}H){sub 3}{sup 3-} anion. (orig.).

  10. Magnetism of SmFeAsO1-xFx

    Science.gov (United States)

    Kamihara, Yoichi; Kobayashi, Yasuhiro; Kitao, Shinji; Yoda, Yoshitaka; Seto, Makoto; Hosono, Hideo; Jst Collaboration; Jst Collaboration

    2011-03-01

    Magnetic properties of superconducting SmFeAs O1 - x Fx are demonstrated by 57 Fe Mossbauer spectroscopy (MS) and 149 Sm Nuclear resonant forward scattering (NRFS). Polycrystalline SmFeAs O1 - x Fx samples were synthesized using two-step solid state reaction described elsewhere. [New J. Phys. 12, 033005 (2010).] Purity of samples was checked by X-ray diffraction patterns using Cu K-alpha radiation. Resistivity and magnetization measurements, as well as by 57 Fe MS and 149 Sm NRFS spectroscopy, at various temperatures were performed to define superconducting, magnetic ordering temperatures. [Phys. Rev. B 78, 184512 (2008) & J. Phys. Soc. Japan 77, 103706 (2008).] A magnetic phase diagram we have proposed is closer to that by Hess et al [Europhys. Lett. 87, 17005 (2009).]; that is long-range AF ordering of Fe (a static magnetism) does not persist in the superconducting regime. Such a relation between spin dynamics and SC is a common feature among LnFeAs O1 - x Fx (Ln = La, Ce, Pr, Nd, and Sm). Our results indicate that the relation between the static magnetism and Tc of LnFeAs O1 - x Fx shows similar topology to that of copper-based high-Tc superconductors. [Phys. Rev. B 42, 7981 (1990).] One (Y. K) of us was financially supported by the Keio Leading-edge Laboratory of Science and Technology (KLL).

  11. X-Ray Line Measurements with High Efficiency Bragg Crystals

    Energy Technology Data Exchange (ETDEWEB)

    Pak, A; Gregori, G; Knight, J; Campbell, K; Landen, O; Glenzer, S

    2004-04-01

    We have studied the focusing properties of two highly oriented pyrolitic graphite (HOPG) spectrometers, which differ in the degree of the mosaic spread: ZYA with a low mosaic spread ({gamma}=0.4 degrees) and ZYH with a large mosaic spread ({gamma}=3.5 degrees). In order to assess the crystal performance for a variety of different experiments, various K{alpha} and K{beta} x-ray lines have been produced using a high-intensity ({approx}>10{sup 17} W/cm{sup 2}) short-pulse ({approx} 100 fs) laser beam focused onto Ti, V, Zn, and Cu foils. The measured spectral resolution of the HOPG crystals in both first and second order diffraction has been compared with theoretical predictions. Using known values for the peak reflectivity of HOPG crystals, we have also computed K{alpha} x-ray conversion efficiencies of Ti, V, Zn, and Cu. These results are important to estimate the optimal conditions under which different types of HOPG monochromators can be used for the detection of weak x-ray signals as the one encountered in x-ray Thomson/Compton scattering experiments.

  12. Intraoperative detection of ¹⁸F-FDG-avid tissue sites using the increased probe counting efficiency of the K-alpha probe design and variance-based statistical analysis with the three-sigma criteria.

    Science.gov (United States)

    Povoski, Stephen P; Chapman, Gregg J; Murrey, Douglas A; Lee, Robert; Martin, Edward W; Hall, Nathan C

    2013-03-04

    Intraoperative detection of (18)F-FDG-avid tissue sites during 18F-FDG-directed surgery can be very challenging when utilizing gamma detection probes that rely on a fixed target-to-background (T/B) ratio (ratiometric threshold) for determination of probe positivity. The purpose of our study was to evaluate the counting efficiency and the success rate of in situ intraoperative detection of (18)F-FDG-avid tissue sites (using the three-sigma statistical threshold criteria method and the ratiometric threshold criteria method) for three different gamma detection probe systems. Of 58 patients undergoing (18)F-FDG-directed surgery for known or suspected malignancy using gamma detection probes, we identified nine (18)F-FDG-avid tissue sites (from amongst seven patients) that were seen on same-day preoperative diagnostic PET/CT imaging, and for which each (18)F-FDG-avid tissue site underwent attempted in situ intraoperative detection concurrently using three gamma detection probe systems (K-alpha probe, and two commercially-available PET-probe systems), and then were subsequently surgical excised. The mean relative probe counting efficiency ratio was 6.9 (± 4.4, range 2.2-15.4) for the K-alpha probe, as compared to 1.5 (± 0.3, range 1.0-2.1) and 1.0 (± 0, range 1.0-1.0), respectively, for two commercially-available PET-probe systems (P < 0.001). Successful in situ intraoperative detection of 18F-FDG-avid tissue sites was more frequently accomplished with each of the three gamma detection probes tested by using the three-sigma statistical threshold criteria method than by using the ratiometric threshold criteria method, specifically with the three-sigma statistical threshold criteria method being significantly better than the ratiometric threshold criteria method for determining probe positivity for the K-alpha probe (P = 0.05). Our results suggest that the improved probe counting efficiency of the K-alpha probe design used in conjunction with the three-sigma statistical

  13. Fe II Diagnostic Tools for Quasars

    CERN Document Server

    Verner, E; Verner, D; Johansson, S; Kallman, T; Gull, T R

    2004-01-01

    The enrichment of Fe, relative to alpha-elements such as O and Mg, represents a potential means to determine the age of quasars and probe the galaxy formation epoch. To explore how \\ion{Fe}{2} emission in quasars is linked to physical conditions and abundance, we have constructed a 830-level \\ion{Fe}{2} model atom and investigated through photoionization calculations how \\ion{Fe}{2} emission strengths depend on non-abundance factors. We have split \\ion{Fe}{2} emission into three major wavelength bands, \\ion{Fe}{2} (UV), \\ion{Fe}{2}(Opt1), and \\ion{Fe}{2}(Opt2), and explore how the \\ion{Fe}{2}(UV)/\\ion{Mg}{2}, \\ion{Fe}{2}(UV)/\\ion{Fe}{2}(Opt1) and \\ion{Fe}{2}(UV)/\\ion{Fe}{2}(Opt2) emission ratios depend upon hydrogen density and ionizing flux in broad-line regions (BLR's) of quasars. Our calculations show that: 1) similar \\ion{Fe}{2}(UV)/\\ion{Mg}{2} ratios can exist over a wide range of physical conditions; 2) the \\ion{Fe}{2}(UV)/\\ion{Fe}{2}(Opt1) and \\ion{Fe}{2}(UV)/\\ion{Fe}{2}(Opt2) ratios serve to constrain...

  14. IMPACT OF PHOSPHORUS AND MOLYBDENUM ON MECHANISM AND KINETICS OF FORMING BOUNDS LINE IN COMPOSITE MATERIALS WITH FE-B-C CONNECTION

    OpenAIRE

    Sukhova, E. V.; Syrovatko, Yu. V.

    2010-01-01

    The structure and properties of Fe-B-C alloys containing 1.8 weight per cent В, 3.0 weight per cent С, including those that were additionally alloyed with 0…1 weight per cent Р, 0…0.5 weight per cent Mo, were investigated in this work. The alloys were studied to work out the binder of composites strengthened with tungsten carbides. The ways to reduce the intensity of contact interaction processes taking place at the interfaces of composites during infiltration were determined.

  15. IMPACT OF PHOSPHORUS AND MOLYBDENUM ON MECHANISM AND KINETICS OF FORMING BOUNDS LINE IN COMPOSITE MATERIALS WITH FE-B-C CONNECTION

    Directory of Open Access Journals (Sweden)

    E. V. Sukhova

    2010-05-01

    Full Text Available The structure and properties of Fe-B-C alloys containing 1.8 weight per cent В, 3.0 weight per cent С, including those that were additionally alloyed with 0…1 weight per cent Р, 0…0.5 weight per cent Mo, were investigated in this work. The alloys were studied to work out the binder of composites strengthened with tungsten carbides. The ways to reduce the intensity of contact interaction processes taking place at the interfaces of composites during infiltration were determined.

  16. Lipid raft facilitated ligation of K-{alpha}1-tubulin by specific antibodies on epithelial cells: Role in pathogenesis of chronic rejection following human lung transplantation

    Energy Technology Data Exchange (ETDEWEB)

    Tiriveedhi, Venkataswarup; Angaswamy, Nataraju [Department of Surgery, Pathology and Immunology, Washington University School of Medicine, St. Louis, MO (United States); Weber, Joseph [Department of Medicine, Washington University School of Medicine, St. Louis, MO (United States); Mohanakumar, T., E-mail: kumart@wustl.edu [Department of Surgery, Pathology and Immunology, Washington University School of Medicine, St. Louis, MO (United States)

    2010-08-20

    Research highlights: {yields} Addition of KAT Abs (+) sera to NHBE culture causes upregulation of growth factors. {yields} Cholesterol depletion causes down regulation of growth factor expression. {yields} Cholesterol depletion is accompanied by loss of membrane bound caveolin. {yields} Thus, we demonstrate lipid raft are critical for efficient ligation of the KAT Abs. -- Abstract: Long term function of human lung allografts is hindered by development of chronic rejection manifested as Bronchiolitis Obliterans Syndrome (BOS). We have previously identified the development of antibodies (Abs) following lung transplantation to K-{alpha}1-tubulin (KAT), an epithelial surface gap junction cytoskeletal protein, in patients who develop BOS. However, the biochemical and molecular basis of the interactions and signaling cascades mediated by KAT Abs are yet to be defined. In this report, we investigated the biophysical basis of the epithelial cell membrane surface interaction between KAT and its specific Abs. Towards this, we analyzed the role of the lipid raft-domains in the membrane interactions which lead to cell signaling and ultimately increased growth factor expression. Normal human bronchial epithelial (NHBE) cells, upon specific ligation with Abs to KAT obtained either from the serum of BOS(+) patients or monoclonal KAT Abs, resulted in upregulation of growth factors VEGF, PDGF, and bFGF (6.4 {+-} 1.1-, 3.2 {+-} 0.9-, and 3.4 {+-} 1.1-fold increase, respectively) all of which are important in the pathogenesis of BOS. To define the role for lipid raft in augmenting surface interactions, we analyzed the changes in the growth factor expression pattern upon depletion and enrichment with lipid raft following the ligation of the epithelial cell membranes with Abs specific for KAT. NHBE cells cultured in the presence of {beta}-methyl cyclodextran ({beta}MCD) had significantly reduced growth factor expression (1.3 {+-} 0.3, vs {beta}MCD untreated being 6.4 {+-} 1.1-fold

  17. Non-LTE line formation of Fe in late-type stars - III. 3D non-LTE analysis of metal-poor stars

    Science.gov (United States)

    Amarsi, A. M.; Lind, K.; Asplund, M.; Barklem, P. S.; Collet, R.

    2016-08-01

    As one of the most important elements in astronomy, iron abundance determinations need to be as accurate as possible. We investigate the accuracy of spectroscopic iron abundance analyses using archetypal metal-poor stars. We perform detailed 3D non-LTE radiative transfer calculations based on 3D hydrodynamic STAGGER model atmospheres, and employ a new model atom that includes new quantum-mechanical neutral hydrogen collisional rate coefficients. With the exception of the red giant HD122563, we find that the 3D non-LTE models achieve Fe I/Fe II excitation and ionization balance as well as not having any trends with equivalent width to within modelling uncertainties of 0.05 dex, all without having to invoke any microturbulent broadening; for HD122563 we predict that the current best parallax-based surface gravity is overestimated by 0.5 dex. Using a 3D non-LTE analysis, we infer iron abundances from the 3D model atmospheres that are roughly 0.1 dex higher than corresponding abundances from 1D MARCS model atmospheres; these differences go in the same direction as the non-LTE effects themselves.We make available grids of departure coefficients, equivalent widths and abundance corrections, calculated on 1D MARCS model atmospheres and horizontally- and temporally-averaged 3D STAGGER model atmospheres.

  18. Non-LTE line formation of Fe in late-type stars - III. 3D non-LTE analysis of metal-poor stars

    Science.gov (United States)

    Amarsi, A. M.; Lind, K.; Asplund, M.; Barklem, P. S.; Collet, R.

    2016-12-01

    As one of the most important elements in astronomy, iron abundance determinations need to be as accurate as possible. We investigate the accuracy of spectroscopic iron abundance analyses using archetypal metal-poor stars. We perform detailed 3D non-LTE radiative transfer calculations based on 3D hydrodynamic STAGGER model atmospheres, and employ a new model atom that includes new quantum-mechanical neutral hydrogen collisional rate coefficients. With the exception of the red giant HD122563, we find that the 3D non-LTE models achieve Fe I/Fe II excitation and ionization balance as well as not having any trends with equivalent width to within modelling uncertainties of 0.05 dex, all without having to invoke any microturbulent broadening; for HD122563 we predict that the current best parallax-based surface gravity is overestimated by 0.5 dex. Using a 3D non-LTE analysis, we infer iron abundances from the 3D model atmospheres that are roughly 0.1 dex higher than corresponding abundances from 1D MARCS model atmospheres; these differences go in the same direction as the non-LTE effects themselves. We make available grids of departure coefficients, equivalent widths and abundance corrections, calculated on 1D MARCS model atmospheres and horizontally and temporally averaged 3D STAGGER model atmospheres.

  19. Non-LTE line formation of Fe in late-type stars - III. 3D non-LTE analysis of metal-poor stars

    CERN Document Server

    Amarsi, A M; Asplund, M; Barklem, P S; Collet, R

    2016-01-01

    As one of the most important elements in astronomy, iron abundance determinations need to be as accurate as possible. We investigate the accuracy of spectroscopic iron abundance analyses using archetypal metal-poor stars. We perform detailed 3D non-LTE radiative transfer calculations based on 3D hydrodynamic Stagger model atmospheres, and employ a new model atom that includes new quantum-mechanical neutral hydrogen collisional rate coefficients. With the exception of the red giant HD122563, we find that the 3D non-LTE models achieve Fe i/Fe ii excitation and ionization balance as well as not having any trends with equivalent width to within modelling uncertainties of 0.05 dex, all without having to invoke any microturbulent broadening; for HD122563 we predict that the current best parallax-based surface gravity is over-estimated by 0.5 dex. Using a 3D non-LTE analysis, we infer iron abundances from the 3D model atmospheres that are roughly 0.1 dex higher than corresponding abundances from 1D MARCS model atmos...

  20. Determination of intrinsic FMR line broadening in ferromagnetic (Fe{sub 44}Co{sub 56}){sub 77}Hf{sub 12}N{sub 11} nanocomposite films

    Energy Technology Data Exchange (ETDEWEB)

    Seemann, K., E-mail: klaus.seemann@kit.ed [Karlsruhe Institute of Technology (KIT), Institute for Materials Research I, Hermann-von-Helmholtz-Platz 1, D-76344 Eggenstein-Leopoldshafen (Germany); Leiste, H.; Klever, Ch. [Karlsruhe Institute of Technology (KIT), Institute for Materials Research I, Hermann-von-Helmholtz-Platz 1, D-76344 Eggenstein-Leopoldshafen (Germany)

    2010-10-15

    Ferromagnetic nanocomposite (Fe{sub 44}Co{sub 56}){sub 77}Hf{sub 12}N{sub 11} films were deposited to investigate their intrinsic damping mechanisms due to scattering of itinerant electrons, which carry the magnetic moment of the ferromagnetic transition elements. The films were produced by reactive r.f. magnetron sputtering using a 6 in. Fe{sub 37}Co{sub 46}Hf{sub 17} target. They were annealed at 400 {sup o}C in a static magnetic field, in order to induce in-plane uniaxial anisotropy. Subsequently, the films can be considered as uniformly magnetised. A ferromagnetic resonance frequency (FMR) of around 2.3 GHz could be attained, which was determined by measuring the real and imaginary parts of the frequency dependent permeability up to 5 GHz. The imaginary part, which represents a typical resonance curve, was utilised to obtain its full-width at half-maximum {Delta}f{sub eff} (FWHM) for the total damping behaviour characterisation. Thereby, it is possible to extract the intrinsic Gilbert damping parameter {alpha}{sub int}, which in turn can be decomposed into two additional damping terms {alpha}{sub sf} and {alpha}{sub os} allocated to 'spin-flip' and 'ordinary scattering', respectively. This result is correlated and discussed in terms of a verified theoretic model, to identify whether damping due to spin-flip scattering and/or ordinary scattering is dominant.

  1. X-ray spectra of Hercules X-1. I - Iron line fluorescence from a subrelativistic shell

    Science.gov (United States)

    Pravdo, S. H.; Becker, R. H.; Boldt, E. A.; Holt, S. S.; Serlemitsos, P. J.; Swank, J. H.

    1977-01-01

    The X-ray spectrum of Her X-1 was observed in the energy range from 2 to 24 keV from August 29 to September 3, 1975. Emission features are observed near the K-alpha iron-line energy which exhibit both broadening and a double line structure. The total luminosity in these features is about 4 by 10 to the 35th power ergs/s. Iron line fluorescence from an opaque cool (not exceeding 1 million K) shell of material at the Alfven surface provides the necessary luminosity in this feature. The double line structure and the line energy width can be due to Doppler shifts if the shell is forced to corotate with the pulsar at a radius of at least 800 million cm. Implications of this model regarding physical conditions near Her X-1 are discussed.

  2. The ^{55}Fe X-ray Energy Response of Mercury Cadmium Telluride Near-Infrared Detector Arrays

    CERN Document Server

    Fox, Ori D; Wen, Yiting; Foltz, Roger D; Hill, Robert J; Kimble, Randy A; Malumuth, Eliot; Rauscher, Bernard J

    2009-01-01

    A technique involving ^{55}Fe X-rays provides a straightforward method to measure the response of a detector. The detector's response can lead directly to a calculation of the conversion gain (e^- ADU^{-1}), as well as aid detector design and performance studies. We calibrate the ^{55}Fe X-ray energy response and pair production energy of HgCdTe using 8 HST WFC3 1.7 \\micron flight grade detectors. The results show that each K$\\alpha$ X-ray generates 2273 \\pm 137 electrons, which corresponds to a pair-production energy of 2.61 \\pm 0.16 eV. The uncertainties are dominated by our knowledge of the conversion gain. In future studies, we plan to eliminate this uncertainty by directly measuring conversion gain at very low light levels.

  3. Temperature induced ferromagnetic resonance frequency change and resonance line broadening of a Fe-Co-Hf-N film with in-plane uniaxial anisotropy - a theoretical and experimental study

    Science.gov (United States)

    Seemann, K.; Krüger, K.; Leiste, H.

    2014-11-01

    A soft ferromagnetic Fe-Co-Hf-N film was produced by reactive r.f. magnetron sputtering, in order to study its high-frequency behaviour by means of frequency domain permeability measurements up to the GHz range. It resulted in the composition Fe33Co43Hf10N14 and exhibits a saturation polarisation Js of around 1.35 T. The film is consequently considered as being uniformly magnetised due to an in-plane uniaxial anisotropy of approximately μ0.Hu≈4.5 mT after annealing it at 400 °C in a static magnetic field for 1 h. While heating the film from room temperature to 300 °C during the high-frequency measurement procedure a marked ferromagnetic resonance peak shift (maximum of the imaginary part of the frequency-dependent permeability) from 2.35 GHz down to 1.84 GHz is conspicuous. This is in a very good agreement with the theory established by taking the “real” ferromagnetic resonance formula for ferromagnetic films into account. Simultaneously, the full width at half maximum (FWHM) ΔfFMR of the resonance line, which is a consequence of precession damping of the magnetic moments, clearly increases. This behaviour does not correlate with the ferromagnetic resonance value decrease, and is qualitatively discussed in terms of exchange interaction with the intrinsic spin-lattice relaxation process due to not totally supressed orbital momenta (≠0) of Fe2+ and Co2+ or the occupation change of their spectral levels within the induced uniaxial anisotropy field.

  4. Ferromagnetic resonance frequency increase and resonance line broadening of a ferromagnetic Fe-Co-Hf-N film with in-plane uniaxial anisotropy by high-frequency field perturbation

    Science.gov (United States)

    Seemann, K.; Leiste, H.; Krüger, K.

    2013-11-01

    Soft ferromagnetic Fe-Co-Hf-N films, produced by reactive r.f. magnetron sputtering, are useful to study the ferromagnetic resonance (FMR) by means of frequency domain permeability measurements up to the GHz range. Films with the composition Fe33Co43Hf10N14 exhibit a saturation polarisation Js of around 1.35 T. They are consequently considered as being uniformly magnetised due to an in-plane uniaxial anisotropy of approximately μ0Hu≈4.5 m T after annealing them, e.g., at 400 °C in a static magnetic field for 1 h. Being exposed to a high-frequency field, the precession of magnetic moments leads to a marked frequency-dependent permeability with a sharp Lorentzian shaped imaginary part at around 2.33 GHz (natural resonance peak), which is in a very good agreement with the modified Landau-Lifschitz-Gilbert (LLG) differential equation. A slightly increased FMR frequency and a clear increase in the resonance line broadening due to an increase of the exciting high-frequency power (1-25.1 mW), considered as an additional perturbation of the precessing system of magnetic moments, could be discovered. By solving the homogenous LLG differential equation with respect to the in-plane uniaxial anisotropy, it was revealed that the high-frequency field perturbation impacts the resonance peak position fFMR and resonance line broadening ΔfFMR characterised by a completed damping parameter α=αeff+Δα. Adapted from this result, the increase in fFMR and decrease in lifetime of the excited level of magnetic moments associated with ΔfFMR, similar to a spin-½ particle in a static magnetic field, was theoretically elaborated as well as compared with experimental data.

  5. XMM-Newton Spectroscopy of the X-ray Detected Broad Absorption Line QSO CSO 755

    Science.gov (United States)

    Brandt, Niel

    2005-01-01

    We present the results from XMM-Newton observations of the highly optically polarized broad absorption line quasar (BALQSO) CSO 755. By analyzing its X-ray spectrum with a total of approximately 3000 photons we find that this source has an X-ray continuum of "typical" radio-quiet quasars, with a photon index of Gamma=1.83, and a rather flat (X-ray bright) intrinsic optical-to-X-ray spectral slope of alpha_ox=- 1.51. The source shows evidence for intrinsic absorption, and fitting the spectrum with a neutral-absorption model gives a column density of N_H approximately 1.2x10^22 cm^{-2}; this is among the lowest X-ray columns measured for BALQSOs. We do not detect, with high significance, any other absorption features in the X-ray spectrum. Upper limits we place on the rest-frame equivalent width of a neutral (ionized) Fe K-alpha line, less than =180 eV (less than =120 eV), and on the Compton-reflection component parameter, R less than =0.2, suggest that most of the X-rays from the source are directly observed rather than being scattered or reflected; this is also supported by the relatively flat intrinsic alpha ox we measure. The possibility that most of the X-ray flux is scattered due to the high level of UV-optical polarization is ruled out. Considering data for 46 BALQSOs from the literature, including CSO 755, we have found that the UV-optical continuum polarization level of BALQSOs is not correlated with any of their X-ray properties. A lack of significant short-term and long-term X-ray flux variations in the source may be attributed to a large black-hole mass in CSO 755. We note that another luminous BALQSO, PG 2112+059, has both similar shallow C IV BALs and moderate X-ray absorption.

  6. Missing Fe: hydrogenated iron nanoparticles

    CERN Document Server

    Bilalbegovic, G; Mohacek-Grosev, V

    2016-01-01

    Although it was found that the FeH lines exist in the spectra of some stars, none of the spectral features in the ISM have been assigned to this molecule. We suggest that iron atoms interact with hydrogen and produce Fe-H nanoparticles which sometimes contain many H atoms. We calculate infrared spectra of hydrogenated iron nanoparticles using density functional theory methods and find broad, overlapping bands. Desorption of H2 could induce spinning of these small Fe-H dust grains. Some of hydrogenated iron nanoparticles posses magnetic and electric moments and should interact with electromagnetic fields in the ISM. Fe_nH_m nanoparticles could contribute to the polarization of the ISM and the anomalous microwave emission. We discuss the conditions required to form FeH and Fe_nH_m in the ISM.

  7. Line Strengths in Early-Type Cluster Galaxies at z=0.33: Implications for alpha/Fe, Nitrogen and the Histories of E/S0s

    CERN Document Server

    Kelson, D D; Franx, M; Van Dokkum, P G; Kelson, Daniel D.; Illingworth, Garth D.; Franx, Marijn

    2006-01-01

    [Heavily Abbreviated] In this paper we analyze previously published spectra with high signal-to-noise ratios of E/S0 galaxies in the rich cluster CL1358+62 at z=0.33, and introduce techniques for fitting stellar population models to the data. Here we focus on the 19 E and S0 galaxies with an homogeneous set of eight blue Lick indices. We explore the galaxy properties using six-parameter stellar population models from the literature, and describe an approach for fitting the models differentially, such that the largest systematic errors are avoided. We find: (1) no differences between the stellar population parameters of Es and S0s, at fixed sigma; (2) the stars in the Es and S0s are uniformly old, consistent with previously published results using M/L ratios; (3) a significant correlation of [Z/H] with sigma, in a manner consistent with the observed B-V colors of the galaxies; (4) no significant correlation of [alpha/Fe] with sigma; and (5) a significant anti-correlation of [alpha/N] with [Z/H], which we inter...

  8. Spin transition in [Fe

    Science.gov (United States)

    Garcia, Y.; Ksenofontov, V.; Campbell, S. J.; Lord, J. S.; Boland, Y.; Gütlich, P.

    2004-12-01

    The reversible thermal spin transition which occurs in [Fe(phen)2(NCS)2] around T1/2 177 K has been investigated by muon spin relaxation (μSR) (10-280 K). The depolarisation curves are well described by two Lorentzian lines represent fast and slow components in the decay curves, with the initial asymmetry parameter of the fast component found to track the spin transition in [Fe(phen)2(NCS)2]. Comparison of zero-field and transverse field (20 Oe) μSR measurements shows that diamagnetic muonic species occur over the entire temperature range.

  9. Irreversibility line of Ba{sub 1-x}K{sub x}Fe{sub 2}As{sub 2} (T{sub c} = 36.9 K) superconductor studied with ac-susceptibility measurements

    Energy Technology Data Exchange (ETDEWEB)

    Pissas, M., E-mail: mpissas@ims.demokritos.gr [Institute of Materials Science, NCSR, Demokritos, 15310 Aghia Paraskevi, Athens (Greece); Zeibekis, M.; Stamopoulos, D. [Institute of Materials Science, NCSR, Demokritos, 15310 Aghia Paraskevi, Athens (Greece); Wang Chunlei; Ma Yanwei [Key Laboratory of Applied Superconductivity, Institute of Electrical Engineering, Chinese Academy of Sciences, PO Box 2703, Beijing 100190 (China)

    2012-06-15

    We have studied the phase diagram of a Ba{sub 1-x}K{sub x}Fe{sub 2}As{sub 2} (T{sub c} = 36.9 K) single crystal superconductor by employing ac-susceptibility measurements, both as a function of temperature for constant external magnetic field and of magnetic dc-field for constant temperature for angles {Theta} = Angle (H, c-axis) = 0 Degree-Sign , 30 Degree-Sign , 45 Degree-Sign , 60 Degree-Sign , 75 Degree-Sign and 90 Degree-Sign , between the c-axis and the magnetic field. The irreversibility lines (H{sub irr}(T, {Theta})) are estimated from the onset of non-zero values of the amplitude of the third harmonic susceptibility. H{sub irr}-lines for all the studied angles can be reproduced from the equation H{sub irr} = H{sub 0}({Theta})(1 - T/T{sub c}){sup n}, with n Almost-Equal-To 4/3. From the angular dependence of H{sub 0}({Theta}) parameter, we estimated the anisotropy of the irreversibility lines. In the temperature interval [35, T{sub c}] the anisotropy parameter was estimated {gamma}=H{sub irr}{sup ab}/H{sub irr}{sup c}=2.2{+-}0.1. The measurements of the real part of the fundamental (first harmonic) ac-susceptibility {chi} Prime (T) for constant temperature as a function of dc-magnetic field revealed, for high values of the ac-field amplitude, a second peak in the critical current. The second peak line is located far from H{sub irr}-line and exists up to T{sub c}. Although the particular sample has high critical densities, contrary to the predictions of the Bean's model, the maximum of the imaginary part of the fundamental ac-susceptibility {chi} Double-Prime exhibits lower values. This behavior could be explained by assuming a reversible motion of the flux lines around the pinning centers for low values of the ac-magnetic field amplitude.

  10. K-shell Emission of Neutral Iron Line from Sgr B2 Excited by Subrelativistic Protons

    CERN Document Server

    Dogiel, Vladimir; Koyama, Katsuji; Nobukawa, Masayoshi; Cheng, Kwong-Sang

    2011-01-01

    We investigated the emission of K$\\alpha$ iron line from the massive molecular clouds in the Galactic center (GC). We assume that at present the total flux of this emission consists of time variable component generated by primary X-ray photons ejected by Sagittarius A$^\\ast$ (Sgr A$^\\ast$) in the past and a relatively weak quasi-stationary component excited by impact of protons which were generated by star accretion onto the central black hole. The level of background emission was estimated from a rise of the 6.4 keV line intensity in the direction of several molecular clouds, that we interpreted as a stage when the X-ray front ejected by Sgr A$^\\ast$ entered into these clouds. The 6.4 keV emission before this intensity jump we interpreted as emission generated by subrelativistic cosmic rays there. The cross-section of K$\\alpha$ vacancies produced by protons differs from that of electrons or X-rays. Therefore, we expect that this processes can be distinguished from the analysis of the equivalent width of the ...

  11. Simplification Study of FE Model for 1000kV AC Transmission Line Insulator String Voltage and Grading Ring Surface Electric Field Distribution Calculation

    Directory of Open Access Journals (Sweden)

    Guoli Wang

    2013-09-01

    Full Text Available The finite element model of the 1000kV Ultra High Voltage (UHV AC transmission line porcelain insulator string voltage distribution and grading ring surface electric field distribution calculation has the characteristics of large size, complicated structure and various mediums. To insure the accuracy, related influencing factors should be considered to simplify the model reasonably for improving computational efficiency. A whole model and a simplified 3D finite element model of UHV AC transmission line porcelain insulator string were built. The influencing factors including tower, phase conductors, hardware fittings, yoke plate and phase interaction were considered in the analysis. And finally, the rationality of the simplified model was validated. The results comparison show that building a simplified model of three-phase bundled conductors within a certain length, simplifying the tower reasonably, omitting the hardware fittings and yoke plate and containing only single-phase insulator string model is feasible. The simplified model could replace the whole model to analyze the voltage distribution along the porcelain insulator string and the electric field distribution on the grading ring surface, and it can reduce the calculation scale, improve optimization efficiency of insulators string and grading ring parameters.

  12. FeII/MgII, [Fe/Mg] Ratios and High-z Quasars

    CERN Document Server

    Korista, K; Corbin, M R; Freudling, W; Korista, Kirk; Kodituwakku, Nalaka; Corbin, Michael; Freudling, Wolfram

    2003-01-01

    It has been suggested in the literature that the (Fe/alpha) abundance ratio may be used as a chronometer, due to a delay in this ratio reaching its solar value as predicted by galactic chemical evolution models. Using grids of photoionization models along a sequence of the (Fe/Mg) abundance ratio vs.\\ metallicity with time in a giant elliptical starburst scenario, we investigate the relationship between the (Fe/Mg) abundance ratio and the FeII/MgII emission line flux ratio under the assumption that these lines originate in photoionized clouds within the broad emission line regions of quasars.

  13. Research on efficiency of amorphous and nanocrystal line Nd2Fe14B/α-Fe powder prepared by two milling methods%两种球磨方法对Nd2Fe14B/α-Fe形成非晶和纳米晶效率的研究

    Institute of Scientific and Technical Information of China (English)

    王迎; 王尔德; 于洋

    2006-01-01

    搅拌式高能球磨效率大于行星式球磨效率,这是公认的.但究竟相差多少,没有进行具体比较.通过采用行星式和搅拌式两种球磨机对Nd2Fe14B/α-Fe进行球磨试验研究,通过XRD、TEM等分析方法得出采用搅拌式球磨机球磨5h就能够得到Nd2Fe14B非晶相和晶粒尺寸在10nm左右的α-Fe纳米晶粉末.通过理论计算得出,搅拌式球磨机的球磨能量远高于行星式球磨机的球磨能量.因此,采用搅拌式球磨机球磨的方法,不仅有利于提高生产效率,同时制备的纳米复相Nd2Fe14B/α-Fe永磁材料具有良好的微观组织.

  14. Characterization of magnetic nano particles of CoFe{sub 2}O{sub 4} and CoZnFe{sub 2}O{sub 4} prepared by the chemical co-precipitation method; Caracterizacion de nanoparticulas magneticas de CoFe{sub 2}O{sub 4} y CoZnFe{sub 2}O{sub 4} preparadas por el metodo de coprecipitacion quimica

    Energy Technology Data Exchange (ETDEWEB)

    Lopez, J.; Zambrano, G.; Gomez, M. E. [Universidad del Valle, Departamento de Fisica, Laboratorio de Peliculas Delgadas, Ciudad Universitaria Melendez, 25360 Cali (Colombia); Prieto, P. [Universidad del Valle, Centro de Excelencia en Nuevos Materiales, Ciudad Universitaria Melendez, 25360 Cali (Colombia); Espinoza B, F. J., E-mail: javierlo21@gmail.com [IPN, Centro de Investigacion y de Estudios Avanzados, Unidad Queretaro, Libramiento Norponiente No. 2000, Fracc. Real de Juriquilla, 76230 Queretaro (Mexico)

    2012-07-01

    Magnetic cobalt ferrite nanoparticles of CoFe{sub 2}O{sub 4} and CoZnFe{sub 2}O{sub 4} were prepared by co-precipitation technique from aqueous salt solutions of Co (II), ZnSO{sub 4} and Fe (III), in an alkaline medium. CoFe{sub 2}O{sub 4} powder samples were structurally characterized by X-ray diffraction, showing the presence of the most intense peat at 2{theta} = 413928{sup o} (Co K{alpha}1) corresponding to the (311) crystallographic orientation of the CoFe{sub 2}O{sub 4} spinel phase. The mean size of the crystalline of CoFe{sub 2}O{sub 4} and CoZnFe{sub 2}O{sub 4} nanoparticles determined from the full width at half maximum of the strongest reflection of the (311) peak by using the Scherrer approximation was calculated to be 11.4 and 7.0 ({+-} o.2) nm, respectively. Transmission electron microscopy studies permitted determining nanoparticle size of CoZnFe{sub 2}O{sub 4}. Fourier transform infrared spectroscopy was used to confirm the formation of Fe-O bonds, allowing identifying the presence of ferrite spinel structure. Magnetic properties were investigated with the aid of a vibrating sample magnetometer at room temperature Herein, the sample showed superparamagnetic behavior, determined by the hysteresis loop finally, due to the hysteresis loop of the CoZnFe{sub 2}O{sub 4} is very small, our magnetic nanoparticles can be considered as a soft magnetic material. These magnetic nanoparticles have interesting technological applications in biomedicine given their biocompatibility, in nano technology, and in ferro fluid preparation. (Author)

  15. Physical conditions in CaFe interstellar clouds

    CERN Document Server

    Gnacinski, P

    2007-01-01

    Interstellar clouds that exhibit strong Ca I and Fe I lines were called CaFe clouds. The ionisation equilibrium equations were used to model the column densities of Ca II, Ca I, K I, Na I, Fe I and Ti II in CaFe clouds. The chemical composition of CaFe clouds is that of the Solar System and no depletion of elements onto dust grains is seen. The CaFe clouds have high electron densities n=1 cm^-3 that leads to high column densities of neutral Ca and Fe.

  16. Physical conditions in CaFe interstellar clouds

    OpenAIRE

    Gnacinski, P.; Krogulec, M.

    2007-01-01

    Interstellar clouds that exhibit strong Ca I and Fe I lines were called CaFe clouds. The ionisation equilibrium equations were used to model the column densities of Ca II, Ca I, K I, Na I, Fe I and Ti II in CaFe clouds. The chemical composition of CaFe clouds is that of the Solar System and no depletion of elements onto dust grains is seen. The CaFe clouds have high electron densities n=1 cm^-3 that leads to high column densities of neutral Ca and Fe.

  17. Insights into Resistance to Fe Deficiency Stress from a Comparative Study of In Vitro-Selected Novel Fe-Efficient and Fe-Inefficient Potato Plants

    Directory of Open Access Journals (Sweden)

    Georgina A. Boamponsem

    2017-09-01

    Full Text Available Iron (Fe deficiency induces chlorosis (IDC in plants and can result in reduced plant productivity. Therefore, development of Fe-efficient plants is of great interest. To gain a better understanding of the physiology of Fe-efficient plants, putative novel plant variants were regenerated from potato (Solanum tubersosum L. var. ‘Iwa’ callus cultures selected under Fe deficient or low Fe supply (0–5 μM Fe. Based on visual chlorosis rating (VCR, 23% of callus-derived regenerants were classified as Fe-efficient (EF and 77% as Fe-inefficient (IFN plant lines when they were grown under Fe deficiency conditions. Stem height was found to be highly correlated with internodal distance, leaf and root lengths in the EF plant lines grown under Fe deficiency conditions. In addition, compared to the IFN plant lines and control parental biotype, the EF plants including the lines named A1, B2, and B9, exhibited enhanced formation of lateral roots and root hairs as well as increased expression of ferritin (fer3 in the leaf and iron-regulated transporter (irt1 in the root. These morphological adaptations and changes in expression the fer3 and irt1 genes of the selected EF potato lines suggest that they are associated with resistance to low Fe supply stress.

  18. Missing Fe: hydrogenated iron nanoparticles

    Science.gov (United States)

    Bilalbegović, G.; Maksimović, A.; Mohaček-Grošev, V.

    2017-03-01

    Although it was found that the FeH lines exist in the spectra of some stars, none of the spectral features in the interstellar medium (ISM) have been assigned to this molecule. We suggest that iron atoms interact with hydrogen and produce Fe-H nanoparticles which sometimes contain many H atoms. We calculate infrared spectra of hydrogenated iron nanoparticles using density functional theory methods and find broad, overlapping bands. Desorption of H2 could induce spinning of these small Fe-H dust grains. Some of hydrogenated iron nanoparticles possess magnetic and electric moments and should interact with electromagnetic fields in the ISM. FenHm nanoparticles could contribute to the polarization of the ISM and the anomalous microwave emission. We discuss the conditions required to form FeH and FenHm in the ISM.

  19. Effects of Cu Layer Width on the Giant Magneto-impedance Effect in Sandwich FeCuNbCrSiB/Cu/FeCuNbCrSiB Films With a Meander Line Structure%Cu层宽度对弯曲型三明治结构FeCuNbCrSiB/Cu/FeCuNbCrSiB多层膜巨磁阻抗效应的影响

    Institute of Scientific and Technical Information of China (English)

    张亚民; 陈吉安; 周勇; 丁文; 王明军; 高孝裕; 周志敏

    2005-01-01

    采用射频磁控溅射方法和微细加工工艺制备了不同Cu层宽度的弯曲型三明治结构的FeCuNbCrSiB/Cu/FeCuNbCrSiB多层膜,在频率1~40MHz下研究了Cu层宽度对多层膜的纵向和横向巨磁阻抗效应的影响.结果表明,弯曲型三明治结构多层膜的巨磁阻抗率随Cu层宽度的变化具有显著的变化,在频率10MHz、磁场12kA/m下,当Cu层宽度为0.4mm时,纵向、横向巨磁阻抗率分别达-57%、-65%.

  20. The structure of Fe sub 2 (PO sub 3 H) sub 3. Structure du phosphite de Fer: Fe sub 2 (PO sub 3 H) sub 3

    Energy Technology Data Exchange (ETDEWEB)

    Sghyar, M. (Lab. de Chimie Minerale Appliquee, Faculte des Sciences, Fes (Morocco)); Durand, J.; Cot, L. (Lab. de Physicochimie des Materiaux, Ecole Nationale Superieure de Chimie de Montpellier, 34 - Motpellier (France)); Rafiq, M. (Lab. de Chimie Minerale Appliquee, Faculte des Sciences, Fes (Morocco))

    1992-12-15

    M{sub r}=351.7, hexagonal, P6{sub 3}/m, a=8.037(2), c=7.352(2) A, V=411.3(3) A{sup 3}, Z=4, D{sub m}=5.664 (by pycnometry), D{sub x}=5.682 Mg m{sup -3}, {lambda}(Mo K{alpha})=0.71069 A, {mu}=39.79 mm{sup -1}, F(000)=292, room temperature, final R=0.028, wR=0.035 for 397 independent reflections. Fe{sub 2}(PO{sub 3}H){sub 3} has been studied by single-crystal X-ray analysis with an automatic diffractometer. The structure is built from one pair of face-sharing octahedra perpendicular to the c axis. PO{sub 3}H{sup 2-} tetrahedra and FeO{sub 6} octahedra only share vertices. Hydrogen atoms of the PO{sub 3}H{sup 2-} anions are in the 3 A diameter channel around the 6{sub 3} axis. (orig.).

  1. Precision Measurement of the Energies and Line Shapes of Antiprotonic Lyman and Balmer Transitions From Hydrogen and Helium Isotopes

    CERN Multimedia

    2002-01-01

    % PS207 \\\\ \\\\ For the study of the antiproton-proton and antiproton-nuclear spin-spin and spin-orbital interaction at threshold a high resolution measurement is proposed of the line shapes and energy shifts of antiprotonic K$\\alpha$ and L$\\alpha$ transitions of hydrogen and helium isotopes. The intense LEAR beam, stopped in the cyclotron trap at low gas pressure, provides a unique~X-ray~source with sufficient brightness. Charge coupled devices with their excellent background rejection and energy resolution allow a precise determination of the strong shifts and widths of the 1s hyperfine states of protonium, in addition the detection of the $\\bar{p}$D K$\\alpha$ transition should be possible. A focussing crystal spectrometer with a resolution $\\Delta$E/E of about l0$ ^- ^{4} $, which is superior in the accuracy of the energy determination by two orders of magnitude as compared to the present detection methods, will be used to measure the energies of the L$\\alpha$ transitions. This permits a first direct measure...

  2. Moessbauer-spectroscopic study of structure and magnetism of the exchange-coupled layer systems Fe/FeSn{sub 2}, and Fe/FeSi/Si and the ion-implanted diluted magnetic semiconductor SiC(Fe); Moessbauerspektroskopische Untersuchung von Struktur und Magnetismus der austauschgekoppelten Schichtsysteme Fe/FeSn{sub 2} und Fe/FeSi/Si und des ionenimplantierten verduennten magnetischen Halbleiters SiC(Fe)

    Energy Technology Data Exchange (ETDEWEB)

    Stromberg, Frank

    2009-07-07

    In line with this work the structural and magnetic properties of the exchange coupled layered systems Fe/FeSn{sub 2} and Fe/FeSi/Si and of the Fe ion implanted diluted magnetic semiconductor (DMS) SiC(Fe) were investigated. The main measuring method was the isotope selective {sup 57}Fe conversion electron Moessbauer spectroscopy (CEMS), mostly in connection with the {sup 57}Fe tracer layer technique, in a temperature range from 4.2 K to 340 K. Further measurement techniques were X-ray diffraction (XRD), electron diffraction (LEED, RHEED), SQUID magnetometry and FMR (Ferromagnetic Resonance). In the first part of this work the properties of thin AF FeSn{sub 2}(001) films and of the exchange-bias system Fe/FeSn{sub 2}(001) on InSb(001) were investigated. With the application of {sup 57}Fe-tracer layers and CEMS both the Fe-spin structure and the temperature dependence of the magnetic hyperfine field (B{sub hf}) of FeSn{sub 2} could be examined. The evaporation of Fe films on the FeSn{sub 2} films produced in the latter ones a high perpendicular spin component at the Fe/FeSn{sub 2} interface. In some distance from the interface the Fe spins rotate back into the sample plane. Furthermore {sup 57}Fe-CEMS provided a correlation between the absolute value of the exchange field vertical stroke He vertical stroke and the amount of magnetic defects within the FeSn{sub 2}. Temperature dependent CEMS-measurements yielded informations about the spin dynamics within the AF. The transition temperatures T{sub B}{sup *}, which were interpreted as superparamagnetic blocking temperatures, obtain higher values compared to the temperatures T{sub B} of the exchange-bias effect, obtained with magnetometry measurements. The second part of this work deals with the indirect exchange coupling within Fe/FeSi/Si/FeSi/Fe multilayers and FeSi diffusion barriers. The goal was to achieve Fe free Si interlayers. The CEMS results show that starting from a thickness of t{sub FeSi}=10-12 A of the

  3. An extreme, blueshifted iron line profile in the Narrow Line Seyfert 1 PG 1402+261; an edge-on accretion disk or highly ionized absorption?

    CERN Document Server

    Reeves, J N; Turner, T J

    2004-01-01

    We report on a short XMM-Newton observation of the radio-quiet Narrow Line Seyfert 1 PG 1402+261. The EPIC X-ray spectrum of PG 1402+261 shows a strong excess of counts between 6-9 keV in the rest frame. This feature can be modeled by an unusually strong (equivalent width 2 keV) and very broad (FWHM velocity of 110000 km/s) iron K-shell emission line. The line centroid energy at 7.3 keV appears blue-shifted with respect to the iron Kalpha emission band between 6.4-6.97 keV, while the blue-wing of the line extends to 9 keV in the quasar rest frame. The line profile can be fitted by reflection from the inner accretion disk, but an inclination angle of >60 deg is required to model the extreme blue-wing of the line. Furthermore the extreme strength of the line requires a geometry whereby the hard X-ray emission from PG 1402+261 above 2 keV is dominated by the pure-reflection component from the disk, while little or none of the direct hard power-law is observed. Alternatively the spectrum above 2 keV may instead b...

  4. Measuring the Kerr spin parameter of a non-Kerr compact object with the continuum-fitting and the iron line methods

    CERN Document Server

    Bambi, Cosimo

    2013-01-01

    Under the assumption that astrophysical black hole candidates are the Kerr black holes of general relativity, the continuum-fitting method and the analysis of the K$\\alpha$ iron line are today the only available techniques capable of providing a relatively reliable estimate of the spin parameter of these objects. If we relax the Kerr black hole hypothesis and we try to test the nature of black hole candidates, we find that there is a strong correlation between the measurement of the spin and possible deviations from the Kerr solution. The properties of the radiation emitted in a Kerr spacetime with spin parameter $a_*$ are indeed very similar, and practically indistinguishable, from the ones of the radiation emitted around a non-Kerr object with different spin. In this paper, I address the question whether measuring the Kerr spin with both the continuum-fitting method and the K$\\alpha$ iron line analysis of the same object can be used to claim the Kerr nature of the black hole candidate in the case of consist...

  5. Fe/Ni ratio in the Ant Nebula Mz 3

    CERN Document Server

    Zhang, Y

    2006-01-01

    We have analyzed the [Fe II] and [Ni II] emission lines in the bipolar planetary nebula Mz~3. We find that the [Fe II] and [Ni II] lines arise exclusively from the central regions. Fluorescence excitation in the formation process of these lines is negligible for this low-excitation nebula. From the [Fe II]/[Ni II] ratio, we obtain a higher Fe/Ni abundance ratio with respect to the solar value. The current result provides further supporting evidence for Mz 3 as a symbiotic Mira.

  6. Spectral properties of the Narrow-Line Seyfert 1 Quasar PG1211+143

    CERN Document Server

    Janiuk, A; Madejski, G M; Janiuk, Agnieszka; Czerny, Bozena; Madejski, Grzegorz M.

    2001-01-01

    We propose a theoretical model to explain the spectrum of the quasar PG1211+143 emitted in the Optical/X-ray bands. In particular, we suggest that the inner accretion disk may develop a warm, optically thick skin, which produces a profound emission feature observed in the soft X-ray band. This is well modelled with the Comptonized black body emission. The same warm, mildly ionized medium may also be responsible for the hard X-ray reflection and the presence of the iron $K_{\\alpha}$ line. However, in our model it still remains an open question, whether the seed photons for Comptonization come from the cold accretion disc or from the hotter plasma. High resolution spectroscopy available through the Chandra and XMM data may provide now an independent test of the physical conditions in the Comptonizing and reflecting warm skin.

  7. Magnetic Properties and Microstructure of FeOx/Fe/FePt and FeOx/FePt Films

    Directory of Open Access Journals (Sweden)

    Jai-Lin Tsai

    2013-01-01

    Full Text Available The Fe(6 nm/FePt film with perpendicular magnetization was deposited on the glass substrate. To study the oxygen diffusion effect on the coupling of Fe/FePt bilayer, the plasma oxidation with 0.5~7% oxygen flow ratio was performed during sputtered part of Fe layer and formed the FeOx(3 nm/Fe(3 nm/FePt trilayer. Two-step magnetic hysteresis loops were found in trilayer with oxygen flow ratio above 1%. The magnetization in FeOx and Fe/FePt layers was decoupled. The moments in FeOx layer were first reversed and followed by coupled Fe/FePt bilayer. The trilayer was annealed again at 500°C and 800°C for 3 minutes. When the FeOx(3 nm/Fe(3 nm/FePt trilayer was annealed at 500°C, the layers structure was changed to FeOx(6 nm/FePt bilayer due to oxygen diffusion. The hard-magnetic FeOx(6 nm/FePt film was coupled with single switching field. The FeOx/(disordered FePt layer structure was observed with further annealing at 800°C and presented soft-magnetic loop. In summary, the coupling between soft-magnetic Fe, FeOx layer, and hard-magnetic L10 FePt layer can be controlled by the oxygen diffusion behavior, and the oxidation of Fe layer was tuned by the annealing temperature. The ordered L10 FePt layer was deteriorated by oxygen and became disordered FePt when the annealed temperature was up to 800°C.

  8. No Signatures of Black-Hole Spin in the X-ray Spectrum of the Seyfert 1 Galaxy Fairall 9

    CERN Document Server

    Yaqoob, Tahir; Tatum, Malachi M; Trevor, Max; Scholtes, Alexis

    2016-01-01

    Fairall 9 is one of several type 1 active galactic nuclei for which it has been claimed that the angular momentum (or spin) of the supermassive black hole can be robustly measured, using the Fe K$\\alpha$ emission line and Compton-reflection continuum in the X-ray spectrum. The method rests upon the interpretation of the Fe K$\\alpha$ line profile and associated Compton-reflection continuum in terms of relativistic broadening in the strong gravity regime in the innermost regions of an accretion disc, within a few gravitational radii of the black hole. Here, we re-examine a Suzaku X-ray spectrum of Fairall 9 and show that a face-on toroidal X-ray reprocessor model involving only nonrelativistic and mundane physics provides an excellent fit to the data. The Fe K$\\alpha$ line emission and Compton reflection continuum are calculated self-consistently, the iron abundance is solar, and an equatorial column density of $\\sim 10^{24} \\ \\rm cm^{-2}$ is inferred. In this scenario, neither the Fe K$\\alpha$ line, nor the Co...

  9. Theoretical simulations of emission spectra of Fe7+ and Fe8+

    Institute of Scientific and Technical Information of China (English)

    Zeng Jiao-Long; Wang Yan-Gui; Zhao Gang; Yuan Jian-Min

    2006-01-01

    The energy levels, oscillator strengths, spontaneous radiative decay rates, and electron impact collision strengths are calculated for Fe Ⅷ and Fe Ⅸ using the recently developed flexible atomic code (FA3. These atomic data are used to analyse the emission spectra of both laboratory and astrophysical plasmas. The nf-3d emission lines have been simulated for Fe Ⅷ and Fe Ⅸ in a wavelength range of 6-14 nm. For Fe Ⅷ, the predicted relative intensities of lines are insensitive to temperature. For Fe Ⅸ, however, the intensity ratios are very sensitive to temperature, implying that the information of temperature in the experiment can be inferred. Detailed line analyses have also been carried out in a wavelength range of 60-80 nm for Fe Ⅷ, where the solar ultraviolet measurements of emitted radiation spectrometer records a large number of spectra. More lines can be identified with the aid of present atomic data. A complete dataset is available electronically from http://www.astrnomy.csdb.cn/EIE/.

  10. Synthesis, Characterization, and Study of In Vitro Cytotoxicity of ZnO-Fe3O4 Magnetic Composite Nanoparticles in Human Breast Cancer Cell Line (MDA-MB-231) and Mouse Fibroblast (NIH 3T3).

    Science.gov (United States)

    Bisht, Gunjan; Rayamajhi, Sagar; Kc, Biplab; Paudel, Siddhi Nath; Karna, Deepak; Shrestha, Bhupal G

    2016-12-01

    Novel magnetic composite nanoparticles (MCPs) were successfully synthesized by ex situ conjugation of synthesized ZnO nanoparticles (ZnO NPs) and Fe3O4 NPs using trisodium citrate as linker with an aim to retain key properties of both NPs viz. inherent selectivity towards cancerous cell and superparamagnetic nature, respectively, on a single system. Successful characterization of synthesized nanoparticles was done by XRD, TEM, FTIR, and VSM analyses. VSM analysis showed similar magnetic profile of thus obtained MCPs as that of naked Fe3O4 NPs with reduction in saturation magnetization to 16.63 emu/g. Also, cell viability inferred from MTT assay showed that MCPs have no significant toxicity towards noncancerous NIH 3T3 cells but impart significant toxicity at similar concentration to breast cancer cell MDA-MB-231. The EC50 value of MCPs on MDA-MB-231 is less than that of naked ZnO NPs on MDA-MB-231, but its toxicity on NIH 3T3 was significantly reduced compared to ZnO NPs. Our hypothesis for this prominent difference in cytotoxicity imparted by MCPs is the synergy of selective cytotoxicity of ZnO nanoparticles via reactive oxygen species (ROS) and exhausting scavenging activity of cancerous cells, which further enhance the cytotoxicity of Fe3O4 NPs on cancer cells. This dramatic difference in cytotoxicity shown by the conjugation of magnetic Fe3O4 NPs with ZnO NPs should be further studied that might hold great promise for the development of selective and site-specific nanoparticles. Schematic representation of the conjugation, characterization and cytotoxicity analysis of Fe3O4-ZnO magnetic composite particles (MCPs).

  11. The spectrum of Fe II

    CERN Document Server

    Nave, Gillian

    2012-01-01

    The spectrum of singly-ionized iron (Fe II) has been recorded using high-resolution Fourier transform and grating spectroscopy over the wavelength range 900 {\\AA} to 5.5 {\\mu}m. The spectra were observed in high-current continuous and pulsed hollow cathode discharges using Fourier transform (FT) spectrometers at the Kitt Peak National Observatory, Tucson, AZ and Imperial College, London and with the 10.7 m Normal Incidence Spectrograph at the National Institute of Standards and Technology. Roughly 12 900 lines were classified using 1027 energy levels of Fe II that were optimized to measured wavenumbers. The wavenumber uncertainties of lines in the FT spectra range from 10-4 cm-1 for strong lines around 4 {\\mu}m to 0.05 cm-1 for weaker lines around 1500 {\\AA}. The wavelength uncertainty of lines in the grating spectra is 0.005 {\\AA}. The ionization energy of (130 655.4+-0.4) cm-1 was estimated from the 3d6(5D)5g and 3d6(5D)6h levels.

  12. THE SPECTRUM OF Fe II

    Energy Technology Data Exchange (ETDEWEB)

    Nave, Gillian [National Institute of Standards and Technology, Gaithersburg, MD 20899-8422 (United States); Johansson, Sveneric, E-mail: gillian.nave@nist.gov [Lund Observatory, University of Lund, Box 43, SE-22100 Lund (Sweden)

    2013-01-15

    The spectrum of singly ionized iron (Fe II) has been recorded using high-resolution Fourier transform (FT) and grating spectroscopy over the wavelength range 900 A to 5.5 {mu}m. The spectra were observed in high-current continuous and pulsed hollow cathode discharges using FT spectrometers at the Kitt Peak National Observatory, Tucson, AZ and Imperial College, London and with the 10.7 m Normal Incidence Spectrograph at the National Institute of Standards and Technology. Roughly 12,900 lines were classified using 1027 energy levels of Fe II that were optimized to measured wavenumbers. The wavenumber uncertainties of lines in the FT spectra range from 10{sup -4} cm{sup -1} for strong lines around 4 {mu}m to 0.05 cm{sup -1} for weaker lines around 1500 A. The wavelength uncertainty of lines in the grating spectra is 0.005 A. The ionization energy of (130,655.4 {+-} 0.4) cm{sup -1} was estimated from the 3d{sup 6}({sup 5}D)5g and 3d{sup 6}({sup 5}D)6h levels.

  13. Synthesis, Characterization, and Study of In Vitro Cytotoxicity of ZnO-Fe3O4 Magnetic Composite Nanoparticles in Human Breast Cancer Cell Line (MDA-MB-231) and Mouse Fibroblast (NIH 3T3)

    Science.gov (United States)

    Bisht, Gunjan; Rayamajhi, Sagar; KC, Biplab; Paudel, Siddhi Nath; Karna, Deepak; Shrestha, Bhupal G.

    2016-12-01

    Novel magnetic composite nanoparticles (MCPs) were successfully synthesized by ex situ conjugation of synthesized ZnO nanoparticles (ZnO NPs) and Fe3O4 NPs using trisodium citrate as linker with an aim to retain key properties of both NPs viz. inherent selectivity towards cancerous cell and superparamagnetic nature, respectively, on a single system. Successful characterization of synthesized nanoparticles was done by XRD, TEM, FTIR, and VSM analyses. VSM analysis showed similar magnetic profile of thus obtained MCPs as that of naked Fe3O4 NPs with reduction in saturation magnetization to 16.63 emu/g. Also, cell viability inferred from MTT assay showed that MCPs have no significant toxicity towards noncancerous NIH 3T3 cells but impart significant toxicity at similar concentration to breast cancer cell MDA-MB-231. The EC50 value of MCPs on MDA-MB-231 is less than that of naked ZnO NPs on MDA-MB-231, but its toxicity on NIH 3T3 was significantly reduced compared to ZnO NPs. Our hypothesis for this prominent difference in cytotoxicity imparted by MCPs is the synergy of selective cytotoxicity of ZnO nanoparticles via reactive oxygen species (ROS) and exhausting scavenging activity of cancerous cells, which further enhance the cytotoxicity of Fe3O4 NPs on cancer cells. This dramatic difference in cytotoxicity shown by the conjugation of magnetic Fe3O4 NPs with ZnO NPs should be further studied that might hold great promise for the development of selective and site-specific nanoparticles.

  14. Iron and zinc availability in maize lines

    Directory of Open Access Journals (Sweden)

    Valéria Aparecida Vieira Queiroz

    2011-09-01

    Full Text Available The aim of this study was to characterize the Zn and Fe availability by phytic acid/Zn and phytic acid/Fe molar ratios, in 22 tropical maize inbred lines with different genetic backgrounds. The Zn and Fe levels were determined by atomic absorption spectrophotometry and the P through colorimetry method. Three screening methods for phytic acid (Phy analysis were tested and one, based on the 2,2'-bipyridine reaction, was select. There was significant variability in the contents of zinc (17.5 to 42 mg.kg-1, iron (12.2 to 36.7 mg.kg-1, phosphorus (230 to 400 mg.100 g-1, phytic acid (484 to 1056 mg.100 g-1, phytic acid P (140 to 293 mg.100 g-1 and available-P (43.5 to 199.5 mg.100 g-1, and in the available-P/total-P ratio (0.14 to 0.50, Phy/Zn (18.0 to 43.5 and Phy/Fe (16.3 to 45.5 molar ratios. Lines 560977, 560978 and 560982 had greater availability of Zn and lines 560975, 560977, 561010 and 5610111 showed better Fe availability. Lines 560975, 560977 and 560978 also showed better available-P/total-P ratio. Thus, the lines 560975, 560977 and 560978 were considered to have the potential for the development of cultivars of maize with high availability of Fe and/or Zn.

  15. Effect of heat treatment on Fe-B-Si-Nb alloy powder prepared by mechanical alloying

    Directory of Open Access Journals (Sweden)

    Rodrigo Estevam Coelho

    2005-06-01

    Full Text Available The effect of heat treatment on crystallization behavior of Fe73.5B15Si10Nb1.5 alloy powder prepared by mechanical alloying was studied. The powder samples were prepared by mechanical alloying (MA and for different milling times (1, 5, 25, 70 and 100 hours. Crystalline powders of iron, boron, silicon and niobium were sealed with tungsten carbide balls in a cylindrical vial under nitrogen atmosphere. The ball-to-powder weight ratio was 20 to 1. A Fritsch Pulverizette 5 planetary ball mill was used for MA the powders at room temperature and at 250 rpm. To study the microstructural evolution, a small amount of powder was collected after different milling times and examined by X-ray diffraction, using CuKalpha radiation (lambda = 0.15418 nm. The crystallization behavior was studied by differential thermal analysis, from 25 up to 1000 °C at a heating rate of 25 °C min-1.

  16. Measure Lines

    Science.gov (United States)

    Crissman, Sally

    2011-01-01

    One tool for enhancing students' work with data in the science classroom is the measure line. As a coteacher and curriculum developer for The Inquiry Project, the author has seen how measure lines--a number line in which the numbers refer to units of measure--help students not only represent data but also analyze it in ways that generate…

  17. [Determination of Total Iron and Fe2+ in Basalt].

    Science.gov (United States)

    Liu, Jian-xun; Chen, Mei-rong; Jian, Zheng-guo; Wu, Gang; Wu, Zhi-shen

    2015-08-01

    Basalt is the raw material of basalt fiber. The content of FeO and Fe2O3 has a great impact on the properties of basalt fibers. ICP-OES and dichromate method were used to test total Fe and Fe(2+) in basalt. Suitable instrument parameters and analysis lines of Fe were chosen for ICP-OES. The relative standard deviation (RSD) of ICP-OES is 2.2%, and the recovery is in the range of 98%~101%. The method shows simple, rapid and highly accurate for determination of total Fe and Fe(2+) in basalt. The RSD of ICP-OES and dichromate method is 0.42% and 1.4%, respectively.

  18. High Pressure Behavior of FeOOH

    Science.gov (United States)

    Reagan, M. M.; Gleason, A. E.; Mao, W. L.

    2013-12-01

    Understanding the stability and properties of simple hydroxides at high pressures and temperatures offers an important first step toward quantifying more complex hydrogen-bearing compounds relevant to the Earth's interior. We focus on iron-oxy-hydroxides because they may be an important Fe and water bearing component in the deep Earth. Goethite (α-FeOOH) transforms to a high-pressure phase, ɛ-FeOOH, which is isostructural with δ-AlOOH, a material which may transport hydrogen to the core-mantle boundary. Here we present XES spectroscopy data of powder samples of synthesized alpha-FeOOH, beta-FeOOH and gamma-FeOOH monitoring their electronic spin transition. The samples was loaded into a Beryllium gasket, where a 50 micron hole served as the sample chamber with 300 micron culet diamond paired with a beveled 150 micron diamond in a diamond-anvil cell (DAC) without a pressure transmitting medium. Pressure was determined using ruby fluorescence (Mao et al. 1978). Using the incident X-ray energy centered at 11.3 KeV from the Advanced Photon Source, beam line HPCAT 16-ID-D, we measured Fe K-β 13 emission to pressures greater than 73 GPa. For alpha-FeOOH, we saw a clear shift in the main peak to lower energy, and an increasingly diminishing K beta prime peak intensity, indicating the sample was undergoing an electronic spin transition. The K beta prime peak completely disappeared at a pressure greater than 73 GPa. Beta-FeOOH showed no evidence of the beginnings of a spin transition, while gamma- FeOOH underwent an incomplete transition.

  19. The Fe II problem in NLS1s

    CERN Document Server

    Collin, S

    2000-01-01

    For more than twenty years, strong Fe II emission lines have been observed in Active Galactic Nuclei and in particular in Narrow Line Seyfert 1 galaxies. A quick overview of the observations and of the models proposed to interpret the Fe II spectrum is given. The influence of atomic data and of physical parameters are discussed, and it is shown that the strengths of the Fe II lines cannot be explained in the framework of photoionization models. A non-radiative heating, for instance due to shocks, with an overabundance of iron, can help to solve the problem. A comparison with other objects emitting intense Fe II lines favors also the presence of strong outflows and shocks. We suggest some issues in the context of AGN evolution.

  20. Presence of magnetic excitations in SmFeAsO

    Science.gov (United States)

    Pelliciari, Jonathan; Dantz, Marcus; Huang, Yaobo; Strocov, Vladimir N.; Xing, Lingyi; Wang, Xiancheng; Jin, Changqing; Schmitt, Thorsten

    2016-09-01

    We measured dispersive spin excitations in SmFeAsO, a parent compound of SmFeAsO1 -xFx and one of the highest temperature superconductors of Fe pnictides (TC ≈ 55 K). We determine the magnetic excitations to disperse with a bandwidth energy of ca 170 meV at (0.47, 0) and (0.34, 0.34), which merges into the elastic line approaching the Γ point. Comparing our results with other parent Fe pnictides, we show the importance of structural parameters for the magnetic excitation spectrum, with small modifications of the tetrahedron angles and As height strongly affecting the magnetism.

  1. XMM-Newton observation of the Seyfert 1.8 ESO 113-G010: discovery of a highly redshifted iron line at 5.4 keV

    CERN Document Server

    Porquet, D; Uttley, P; Turner, T J

    2004-01-01

    We present a spectral analysis of the Seyfert 1.8 ESO 113-G010 observed with XMM-Newton for 4 ks. The spectrum shows a soft excess below 0.7 keV and more interestingly a narrow emission Gaussian line at 5.4 keV (in its rest-frame), most probably originating from a redshifted iron Kalpha line. No significant line at or above 6.4 keV is found contrary to other objects showing redshifted lines, ruling out a strong blue-wing to the line profile. The line is detected at 99% confidence, from performing Monte Carlo simulations which fully account for the range of energies where a narrow iron line is likely to occur. The energy of the line could indicate emission from relativistic (0.17 - 0.23 c) ejected matter moving away from the observer, as proposed for Mrk 766 by Turner et al. (2004). Alternatively, the emission from a narrow annulus at the surface of the accretion disk.

  2. Enhanced leaf photosynthesis as a target to increase grain yield: insights from transgenic rice lines with variable Rieske FeS protein content in the cytochrome b6 /f complex.

    Science.gov (United States)

    Yamori, Wataru; Kondo, Eri; Sugiura, Daisuke; Terashima, Ichiro; Suzuki, Yuji; Makino, Amane

    2016-01-01

    Although photosynthesis is the most important source for biomass and grain yield, a lack of correlation between photosynthesis and plant yield among different genotypes of various crop species has been frequently observed. Such observations contribute to the ongoing debate whether enhancing leaf photosynthesis can improve yield potential. Here, transgenic rice plants that contain variable amounts of the Rieske FeS protein in the cytochrome (cyt) b6 /f complex between 10 and 100% of wild-type levels have been used to investigate the effect of reductions of these proteins on photosynthesis, plant growth and yield. Reductions of the cyt b6 /f complex did not affect the electron transport rates through photosystem I but decreased electron transport rates through photosystem II, leading to concomitant decreases in CO2 assimilation rates. There was a strong control of plant growth and grain yield by the rate of leaf photosynthesis, leading to the conclusion that enhancing photosynthesis at the single-leaf level would be a useful target for improving crop productivity and yield both via conventional breeding and biotechnology. The data here also suggest that changing photosynthetic electron transport rates via manipulation of the cyt b6 /f complex could be a potential target for enhancing photosynthetic capacity in higher plants.

  3. Unveiling the broad band X-ray continuum and iron line complex in Mkr 841

    CERN Document Server

    Petrucci, P O; Matt, G; Longinotti, A L; Malzac, J; Mouchet, M; Boisson, C; Maraschi, L; Nandra, K; Ferrando, P

    2007-01-01

    Mkr 841 is a bright Seyfert 1 galaxy known to harbor a strong soft excess and a variable K$\\alpha$ iron line. It has been observed during 3 different periods by XMM for a total cumulated exposure time of $\\sim$108 ks. We present in this paper a broad band spectral analysis of the complete EPIC-pn data sets. We were able to test two different models for the soft excess, a relativistically blurred photoionized reflection (\\r model) and a relativistically smeared ionized absorption (\\a model). The continuum is modeled by a simple cut-off power law and we also add a neutral reflection. These observations reveal the extreme and puzzling spectral and temporal behaviors of the soft excess and iron line. The 0.5-3 keV soft X-ray flux decreases by a factor 3 between 2001 and 2005 and the line shape appears to be a mixture of broad and narrow components. We succeed in describing this complex broad-band 0.5-10 keV spectral variability using either \\r or \\a to fit the soft excess. Both models give statistically equivalen...

  4. Testing the Kerr nature of black hole candidates using iron line reverberation mapping in the CPR framework

    CERN Document Server

    Jiang, Jiachen; Steiner, James F

    2016-01-01

    The iron K$\\alpha$ line commonly observed in the X-ray spectrum of black hole candidates is produced by X-ray fluorescence of the inner accretion disk. This line can potentially be quite a powerful tool to probe the spacetime geometry around these objects and test the Kerr black hole hypothesis. In a previous paper, we studied the ability to constrain possible deviations from the Kerr solution from the standard time-integrated iron line spectrum within the Cardoso-Pani-Rico framework. In the present work, we expand on that study and consider iron line reverberation mapping in the CPR framework. That is, we consider the time-evolution of the iron line profile in response to fluctuations in the X-ray primary source. Our simulations clearly show that the time information in reverberation mapping can better constrain the background metric than the time-integrated approach, and this is true, notably, for the deformation parameter $\\epsilon^r_3$, which is only weakly informed by a time-integrated observation.

  5. Fe K emission from active galaxies in the COSMOS field

    CERN Document Server

    Iwasawa, K; Brusa, M; Comastri, A; Gilli, R; Vignali, C; Hasinger, G; Sanders, D B; Cappelluti, N; Impey, C D; Koekemoer, A; Lanzuisi, G; Lusso, E; Merloni, A; Salvato, M; Taniguchi, Y; Trump, J R

    2011-01-01

    We present a rest-frame spectral stacking analysis of ~1000 X-ray sources detected in the XMM-COSMOS field in order to investigate the iron K line properties of active galaxies beyond redshift z~1. In Type I AGN that have a typical X-ray luminosity of Lx~1.5e44 erg/s and z~1.6, the cold Fe K at 6.4 keV is weak (EW~0.05keV), in agreement with the known trend. In contrast, high-ionization lines of Fe XXV and Fe XXVI are pronounced. These high-ionization Fe K lines appear to have a connection with high accretion rates. While no broad Fe emission is detected in the total spectrum, it might be present, albeit at low significance, when the X-ray luminosity is restricted to the range below 3e44 erg/s, or when an intermediate range of Eddington ratio around 0.1 is selected. In Type II AGN, both cold and high-ionzation lines become weak with increasing X-ray luminosity. However, strong high-ionization Fe K (EW~0.3 keV) is detected in the spectrum of objects at z>2, while no 6.4 keV line is found. It is then found that...

  6. Isothermal corrosion Fe3Si alloy in liquid zinc

    Institute of Scientific and Technical Information of China (English)

    Wen jun Wang; Junping Lin; Yanli Wang; Guoliang Chen

    2007-01-01

    The isothermal corrosion testing,microscopic examination and the performance of Fe3Si alloy as materials of construction for bath hardware in continuous hot-dipping lines were studied.The corrosion of Fe3Si alloy in molten zinc was controlled by attacking the grain boundaries preferentially.Aluminum reacted with iron of Fe3Si alloy firstly while the samples were immersed in molten zinc,although aluminum contents in the molten zinc were very low.The phase of reaction product was thought to be Fe2Al5.The corrosion rate of the Fe3Si alloy in molten zinc was determined to be approximately 2.9×10-3 mm/h,therefore the liquid zinc corrosion resistance of Fe3Si alloy was very weak.

  7. High Line

    DEFF Research Database (Denmark)

    Kiib, Hans

    2015-01-01

    At just over 10 meters above street level, the High Line extends three kilometers through three districts of Southwestern Manhattan in New York. It consists of simple steel construction, and previously served as an elevated rail line connection between Penn Station on 34th Street and the many....... The High Line project has been carried out as part of an open conversion strategy. The result is a remarkable urban architectural project, which works as a catalyst for the urban development of Western Manhattan. The greater project includes the restoration and reuse of many old industrial buildings...... in close proximity to the park bridge and new projects being added to fit the context. The outcome is a conglomeration of non-contemporary urban activities along the High Line, where mechanical workshops, small wholesale stores. etc. mix with new exclusive residential buildings, eminent cafés...

  8. High Line

    DEFF Research Database (Denmark)

    Kiib, Hans

    2015-01-01

    in close proximity to the park bridge and new projects being added to fit the context. The outcome is a conglomeration of non-contemporary urban activities along the High Line, where mechanical workshops, small wholesale stores. etc. mix with new exclusive residential buildings, eminent cafés......At just over 10 meters above street level, the High Line extends three kilometers through three districts of Southwestern Manhattan in New York. It consists of simple steel construction, and previously served as an elevated rail line connection between Penn Station on 34th Street and the many...... factories and warehouses on Gansevoort Street. Today the High Line is a beautiful park covered with new tiles, viewing platforms and smaller recreational areas. The park bridge has simple, uniform, urban fittings and features a variety of flowering plants, grasses, shrubs and trees from around the world...

  9. Variations in Ratio and Correlation of Solar Magnetic Fields in the Fe i 525.02 nm and Na i 589.59 nm Lines According to Mount Wilson Measurements During 2000 - 2012

    Science.gov (United States)

    Golubeva, Elena

    2016-10-01

    Variations in the solar magnetic-field ratio over 13 years are analyzed, relying on the comparison of simultaneous measurements in two spectral lines at the Mount Wilson Observatory (MWO). The ratio and correlation coefficient are calculated over the general working range of measured magnetic-field values and in various ranges of the field magnitudes. Variations in both parameters are considered. We found the following tendencies: i) the parameters show changes with the cycle of solar activity in the general case; ii) their dependence on magnetic-field magnitude is a nonlinear function of time, and this is especially pronounced in the ratio behavior; iii) several separate ranges of the field magnitudes can be distinguished based on the behavioral patterns of the ratio variations. Correspondences between these ranges and the known structural objects of the solar atmosphere are discussed. This permits us to reach the conclusion that the dependence of parameters considered on the magnetic-field magnitude and time is connected with the variety of magnetic structural components and their cyclic rearrangements. The results represented may be useful for solving interpretation problems of solar magnetic-field measurements and for the cross-calibration of applicable instruments. They can also be of interest for tasks related to the creation of a uniform long temporal series of solar magnetic-field data from various sources.

  10. Magnetism of FePt Nanoclusters in Polyimide

    Directory of Open Access Journals (Sweden)

    Mircea Chipara

    2015-01-01

    Full Text Available FePt nanoclusters have been implanted onto polyimide films and subjected to thermal annealing in order to obtain a special magnetic phase (L10 dispersed within the polymer. SQUID measurements quantified the magnetic features of the as-prepared and annealed hybrid films. As-implanted FePt nanoparticles in polyimide films exhibited a blocking temperature of 70 ± 5 K. Thermal annealing in zero and 10 kOe applied magnetic field increased the magnetic anisotropy and coercivity of the samples. Wide Angle X-Ray Scattering confirmed the presence of FePt and L10 phase. All samples (as deposited and annealed exhibited electron spin resonance spectra consisting of two overlapping lines. The broad line was a ferromagnetic resonance originating from FePt nanoparticles. Its angular dependence indicated the magnetic anisotropy of FePt nanoparticles. SEM micrographs suggest a negligible coalescence of FePt nanoparticles, supporting that the enhancement of the magnetic properties is a consequence of the improvement of the L10 structure. The narrow ESR line was assigned to nonmagnetic (paramagnetic impurities within the samples consistent with graphite-like structures generated by the local degradation of the polymer during implantation and annealing. Raman spectroscopy confirmed the formation of graphitic structures in annealed KHN and in KHN-FePt.

  11. An XMM-Newton survey of broad iron lines in AGN

    CERN Document Server

    Nandra, K; George, I M; Reeves, J N; Turner, T J

    2006-01-01

    We report on the iron K-alpha line properties of a sample of Seyfert galaxies observed with the XMM-Newton EPIC pn instrument. Using a systematic and uniform analysis, we find that complexity at iron-K is extremely common in the XMM spectra. Once appropriate soft X-ray absorption, narrow 6.4 keV emission and associated Compton reflection are accounted for, ~75 of the sample show an improvement when a further Gaussian component is introduced. The typical properties of the broad emission are both qualitatively and quantitatively consistent with previous results from ASCA. The complexity is in general very well described by relativistic accretion disk models. In most cases the characteristic emission radius is constrained to be within ~50 R_g, where strong gravitational effects become important. We find in about 1/3 of the sample the accretion disk interpretation is strongly favoured over competing models. In a few objects no broad line is apparent. We find evidence for emission within 6 R_g in only two cases, b...

  12. Fluorescent iron lines as a probe of astrophysical black hole systems

    CERN Document Server

    Reynolds, C S; Reynolds, Christopher S.; Nowak, Michael A.

    2003-01-01

    (abridged) With most physicists and astrophysicists in agreement that black holes do indeed exist, the focus of astrophysical black hole research has shifted to the detailed properties of these systems. Nature has provided us with an extremely useful probe of the region very close to an accreting black hole - X-ray irradiation of relatively cold material in the vicinity of the black hole can imprint characteristic features into the X-ray spectra of black hole systems, most notably the Kalpha fluorescent line of iron. Detailed X-ray spectroscopy of these features can be used to study Doppler and gravitational redshifts, thereby providing key information on the location and kinematics of the cold material. This is a powerful tool that allows us to probe within a few gravitational radii, or less, of the event horizon. Here, we present a comprehensive review of relativistic iron line studies for both accreting stellar mass black holes (i.e., Galactic Black Hole Candidate systems; GBHCs), and accreting supermassiv...

  13. Testing the Kerr metric with the iron line and the KRZ parametrization

    CERN Document Server

    Ni, Yueying; Bambi, Cosimo

    2016-01-01

    The spacetime geometry around astrophysical black holes is supposed to be well approximated by the Kerr metric, but deviations from the Kerr solution are predicted in a number of scenarios involving new physics. Broad iron K$\\alpha$ lines are commonly observed in the X-ray spectrum of black holes and originate by X-ray fluorescence of the inner accretion disk. The profile of the iron line is sensitively affected by the spacetime geometry in the strong gravity region and can be used to test the Kerr black hole hypothesis. In this paper, we extend previous work in the literature. In particular: i) as test-metric, we employ the parametrization recently proposed by Konoplya, Rezzolla, and Zhidenko, which has a number of subtle advantages with respect to the existing approaches; ii) we perform simulations with specific X-ray missions, and we consider NuSTAR as a prototype of current observational facilities and eXTP as an example of the next generation of X-ray observatories. We find a significant difference betwe...

  14. $Ly \\alpha$ Fluorescent Excitation of FeII in Active Galactic Nuclei

    CERN Document Server

    Sigut, T A A; Pradhan, Anil K.

    1998-01-01

    We have calculated FeII emission line strengths for Active Galactic Nuclei Broad-Line Regions using precise radiative transfer and Iron Project atomic data. We improve the treatment of all previously considered excitation mechanisms for the FeII emission, continuum fluorescence, collisional excitation, fluorescence by self-overlap among the iron lines, and fluorescent excitation by Lyman-alpha. We demonstrate that Lyman-alpha fluorescence is of fundamental importance in determining the strength of the FeII emission. In addition to enhancing the ultraviolet and optical FeII flux, Lyman-alpha fluorescence also results in significant near-infrared FeII emission in the 8500-9500 Angstrom wavelength range. New observations are suggested to probe this effect in strong FeII emitting quasars.

  15. [2Fe-2S] Proteins in chlorosomes

    DEFF Research Database (Denmark)

    Johnson, T. Wade; Li, Hui; Frigaard, Niels-Ulrik;

    2013-01-01

    The chlorosome envelope of Chlorobaculum tepidum contains 10 polypeptides, three of which, CsmI, CsmJ, and CsmX, have an adrenodoxin-like domain harboring a single [2Fe-2S] cluster. Mutants that produced chlorosomes containing two, one, or none of these Fe-S proteins were constructed [Li, H., et al....... (2013) Biochemistry 52, preceding paper in this issue ( DOI: 10.1021/bi301454g )]. The electron paramagnetic resonance (EPR) spectra, g values, and line widths of the Fe-S clusters in individual CsmI, CsmJ, and CsmX proteins were obtained from studies with isolated chlorosomes. The Fe-S clusters...... in these proteins were characterized by EPR and could be differentiated on the basis of their g values and line widths. The EPR spectrum of wild-type chlorosomes could be simulated by a 1:1 admixture of the CsmI and CsmJ spectra. No contribution of CsmX to the EPR spectrum of chlorosomes was observed because of its...

  16. Predicted profiles of ultraviolet interstellar absorption lines

    Energy Technology Data Exchange (ETDEWEB)

    Welty, D.E.; Hobbs, L.M.; York, D.G. (Chicago, University, IL (USA))

    1991-02-01

    In this paper, values of the column density, line width parameter, and velocity are determined for as many components derived from optical interstellar absorption-line profiles of Na I and K I as needed to reproduce the observed high-resolution optical profiles of the D lines of Na I toward eight lightly reddened stars and of the 7698 A line of K I toward six moderately reddened stars. The derived component structures are then used to predict UV absorption-line profiles due to C I, Mg I, S I, Si I, and Fe I along the same lines of sight. Comparison of the predicted profiles with existing lower resolution line profiles and equivalent width data suggests that this simple scaling procedure can in many cases fairly reliably predict the UV profiles from the observed optical ones. 64 refs.

  17. Electrochemical alkaline Fe(VI) water purification and remediation.

    Science.gov (United States)

    Licht, Stuart; Yu, Xingwen

    2005-10-15

    Fe(VI) is an unusual and strongly oxidizing form of iron, which provides a potentially less hazardous water-purifying agent than chlorine. A novel on-line electrochemical Fe(VI) water purification methodology is introduced. Fe(VI) addition had been a barrier to its effective use in water remediation, because solid Fe(VI) salts require complex (costly) syntheses steps and solutions of Fe(VI) decompose. Online electrochemical Fe(VI) water purification avoids these limitations, in which Fe(VI) is directly prepared in solution from an iron anode as the FeO42- ion, and is added to the contaminant stream. Added FeO42- decomposes, by oxidizing a wide range of water contaminants including sulfides (demonstrated in this study) and other sulfur-containing compounds, cyanides (demonstrated in this study), arsenic (demonstrated in this study), ammonia and other nitrogen-containing compounds (previously demonstrated), a wide range of organics (phenol demonstrated in this study), algae, and viruses (each previously demonstrated).

  18. Fe XVII Emission from Hot, Collisional Plasmas

    Energy Technology Data Exchange (ETDEWEB)

    Beiersdorfer, P; Bitter, M; von Goeler, S; Hill, K W

    2004-12-03

    The ratios of the Fe XVII 3s {yields} 2p transitions to that of the dominant 3d {yields} 2p transition measured in high-temperature tokamak plasmas are compared to solar and astrophysical observations. Good agreement is found, indicating that the collisional line formation processes active in opacity-free, low-density, high-temperature laboratory plasmas are a good description of those found in astrophysical plasmas.

  19. Spin and orbital magnetic moments of Fe in the n-type ferromagnetic semiconductor (In,Fe)As

    Energy Technology Data Exchange (ETDEWEB)

    Kobayashi, M., E-mail: masakik@post.kek.jp; Oshima, M. [Department of Applied Chemistry, School of Engineering, University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656 (Japan); Synchrotron Radiation Research Organization, University of Tokyo, 1-490-2 Kouto, Sayo-cho, Tatsuno, Hyogo 679-5165 (Japan); Anh, L. D.; Hai, P. N.; Tanaka, M. [Department of Electrical Engineering and Information Systems, University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656 (Japan); Takeda, Y.; Okane, T.; Saitoh, Y.; Yamagami, H. [Synchrotron Radiation Research Unit, Japan Atomic Energy Agency, Sayo-gun, Hyogo 679-5148 (Japan); Sakamoto, S.; Kadono, T.; Fujimori, A. [Department of Physics, University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033 (Japan); Harada, Y. [Synchrotron Radiation Research Organization, University of Tokyo, 1-490-2 Kouto, Sayo-cho, Tatsuno, Hyogo 679-5165 (Japan); Institute for Solid State Physics, The University of Tokyo, 1-1-1 Koto, Sayo, Hyogo 679-5198 (Japan)

    2014-07-21

    The electronic and magnetic properties of Fe atoms in the ferromagnetic semiconductor (In,Fe)As codoped with Be have been studied by x-ray absorption spectroscopy (XAS) and x-ray magnetic circular dichroism (XMCD) at the Fe L{sub 2,3} edge. The XAS and XMCD spectra showed simple spectral line shapes similar to Fe metal, but the ratio of the orbital and spin magnetic moments (M{sub orb}/M{sub spin}) estimated using the XMCD sum rules was significantly larger than that of Fe metal, indicating a significant orbital moment of Fe 3d electrons in (In,Fe)As:Be. The positive value of M{sub orb}/M{sub spin} implies that the Fe 3d shell is more than half-filled, which arises from the hybridization of the Fe{sup 3+} (d{sup 5}) state with the charge-transfer d{sup 6}L{sub ¯} states, where L{sub ¯} is a ligand hole in the host valence band. The XMCD intensity as a function of magnetic field indicated hysteretic behavior of the superparamagnetic-like component due to discrete ferromagnetic domains.

  20. Fe atom exchange between aqueous Fe2+ and magnetite.

    Science.gov (United States)

    Gorski, Christopher A; Handler, Robert M; Beard, Brian L; Pasakarnis, Timothy; Johnson, Clark M; Scherer, Michelle M

    2012-11-20

    The reaction between magnetite and aqueous Fe(2+) has been extensively studied due to its role in contaminant reduction, trace-metal sequestration, and microbial respiration. Previous work has demonstrated that the reaction of Fe(2+) with magnetite (Fe(3)O(4)) results in the structural incorporation of Fe(2+) and an increase in the bulk Fe(2+) content of magnetite. It is unclear, however, whether significant Fe atom exchange occurs between magnetite and aqueous Fe(2+), as has been observed for other Fe oxides. Here, we measured the extent of Fe atom exchange between aqueous Fe(2+) and magnetite by reacting isotopically "normal" magnetite with (57)Fe-enriched aqueous Fe(2+). The extent of Fe atom exchange between magnetite and aqueous Fe(2+) was significant (54-71%), and went well beyond the amount of Fe atoms found at the near surface. Mössbauer spectroscopy of magnetite reacted with (56)Fe(2+) indicate that no preferential exchange of octahedral or tetrahedral sites occurred. Exchange experiments conducted with Co-ferrite (Co(2+)Fe(2)(3+)O(4)) showed little impact of Co substitution on the rate or extent of atom exchange. Bulk electron conduction, as previously invoked to explain Fe atom exchange in goethite, is a possible mechanism, but if it is occurring, conduction does not appear to be the rate-limiting step. The lack of significant impact of Co substitution on the kinetics of Fe atom exchange, and the relatively high diffusion coefficients reported for magnetite suggest that for magnetite, unlike goethite, Fe atom diffusion is a plausible mechanism to explain the rapid rates of Fe atom exchange in magnetite.

  1. UV spectra of iron-doped carbon clusters FeC_n n = 3-6

    CERN Document Server

    Steglich, Mathias; Johnson, Anatoly; Maier, John P

    2015-01-01

    Electronic transitions of jet-cooled FeC$_n$ clusters ($n = 3 - 6$) were measured between 230 and 300 nm by a mass-resolved 1+1 resonant two-photon ionization technique. Rotational profiles were simulated based on previous calculations of ground state geometries and compared to experimental observations. Reasonable agreement is found for the planar fan-like structure of FeC$_3$. The FeC$_4$ data indicate a shorter distance between the Fe atom and the bent C$_4$ unit of the fan. The transitions are suggested to be $^{3}$A$_{2} \\leftarrow ^{3}$B$_{1}$ for FeC$_3$ and $^{5}$A$_{1} \\leftarrow ^{5}$A$_{1}$ for FeC$_4$. In contrast to the predicted C$_{\\infty \\text{v}}$ geometry, non-linear FeC$_5$ is apparently observed. Line width broadening prevents analysis of the FeC$_6$ spectrum.

  2. production lines

    Directory of Open Access Journals (Sweden)

    Jingshan Li

    2000-01-01

    Full Text Available In this work, serial production lines with finished goods buffers operating in the pull regime are considered. The machines are assumed to obey Bernoulli reliability model. The problem of satisfying customers demand is addressed. The level of demand satisfaction is quantified by the due-time performance (DTP, which is defined as the probability to ship to the customer a required number of parts during a fixed time interval. Within this scenario, the definitions of DTP bottlenecks are introduced and a method for their identification is developed.

  3. The Ca II triplet in red giant spectra: [Fe/H] determinations and the role of [Ca/Fe

    CERN Document Server

    Da Costa, G S

    2015-01-01

    Measurements are presented and analyzed of the strength of the Ca II triplet lines in red giants in Galactic globular and open clusters, and in a sample of red giants in the LMC disk that have significantly different [Ca/Fe] abundance ratios to the Galactic objects. The Galactic objects are used to generate a calibration between Ca II triplet line strength and [Fe/H], which is then used to estimate [Fe/H]_CaT for the LMC stars. The values are then compared with the [Fe/H]_spec determinations from high dispersion spectroscopy. After allowance for a small systematic offset the two abundance determinations are in excellent agreement. Further, as found in earlier studies, e.g., Battaglia et al. (2008), the difference is only a very weak function of the [Ca/Fe] ratio. For example, changing [Ca/Fe] from +0.3 to -0.2 causes the Ca II based abundance to underestimate [Fe/H]_spec by only ~0.15 dex, assuming a Galactic calibration. Consequently, the Ca II triplet approach to metallicity determinations can be used witho...

  4. Theoretical modelling of the AGN iron-line/continuum time-lags in the lamp-post geometry

    CERN Document Server

    Epitropakis, A; Dovčiak, M; Pecháček, Tomáš; Emmanoulopoulos, D; Karas, V; McHardy, I M

    2016-01-01

    Context: Theoretical modelling of time-lags between variations in the Fe K$\\alpha$ emission and the X-ray continuum has the potential of shedding light on the physics and geometry of the X-ray emitting region in active galaxies (AGN) and X-ray binaries. In this work, we present the results from a systematic analysis of time-lags between variations in two energy bands ($5-7$ versus $2-4\\,\\mathrm{keV}$) for seven X-ray bright and variable AGN. Aims: To estimate time-lags as accurately as possible, and fit them with theoretical models, in the context of the `lamp-post' geometry, to constrain the geometry of the X-ray emitting region in AGN. Methods: We used all available archival \\textit{XMM-Newton} data for the sources in our sample and extracted light curves in the $5-7$ and $2-4\\,\\mathrm{keV}$ energy bands. We used these light curves and applied a thoroughly tested (through extensive numerical simulations) recipe in order to estimate time-lags which have minimal bias, approximately follow a Gaussian distribut...

  5. Electronic structure and magnetism of ThFeAsN

    Science.gov (United States)

    Wang, Guangtao; Shi, Xianbiao

    2016-03-01

    The electronic structure and magnetic properties of ThFeAsN, a newly discovered superconductor, are investigated by means of first-principles calculations. ThFeAsN shares electronic structure and magnetic properties similar to those of LaOFeAs. Its calculated ground state is the stripe antiferromagnetic state. The hole-like Fermi surfaces (FSs) along the Γ\\text-Z line largely overlap with the electron-like FS along the M\\text-A line with the vector q= (π, π, 0) . Such significant FS nesting induces a peak of the bare susceptibility χ0(q ) at the M-point.

  6. The [Fe IV] Discrepancy: Constraining the Iron Abundances in Nebulae

    CERN Document Server

    Rodríguez, M; Einert, Thomas; Lipowsky, Peter; Schilling, Jorg; Bowick, Mark; Bausch, Andreas; Rodriguez, Monica; Rubin, Robert H.

    2005-01-01

    We study the current discrepancy between the model-predicted and measured concentrations of Fe++ and Fe3+ in ionized nebulae. We calculate a set of photoionization models, updated with the atomic data relevant to the problem, and compare their results with those derived for the available nebulae where both [Fe III] and [Fe IV] lines have been measured. Our new model results are closer to the measured values than the results of previous calculations, but a discrepancy remains. This discrepancy translates into an uncertainty in the derived Fe abundances of a factor up to ~4. We explore the possible causes of this discrepancy and find that errors in the Fe atomic data may be the most likely explanation. The discrepancy can be fully accounted for by any of the following changes: (1) an increase by a factor of ~10 in the recombination rate (radiative plus dielectronic, or charge transfer) for Fe3+, (2) an increase by a factor of 2-3 in the effective collision strengths for Fe++, or (3) a decrease by a factor of 2-...

  7. Parallel Lines

    Directory of Open Access Journals (Sweden)

    James G. Worner

    2017-05-01

    Full Text Available James Worner is an Australian-based writer and scholar currently pursuing a PhD at the University of Technology Sydney. His research seeks to expose masculinities lost in the shadow of Australia’s Anzac hegemony while exploring new opportunities for contemporary historiography. He is the recipient of the Doctoral Scholarship in Historical Consciousness at the university’s Australian Centre of Public History and will be hosted by the University of Bologna during 2017 on a doctoral research writing scholarship.   ‘Parallel Lines’ is one of a collection of stories, The Shapes of Us, exploring liminal spaces of modern life: class, gender, sexuality, race, religion and education. It looks at lives, like lines, that do not meet but which travel in proximity, simultaneously attracted and repelled. James’ short stories have been published in various journals and anthologies.

  8. The catalytic degradation of dye wastewater by Fe-ZnO nanocrystalline%纳米Fe-ZnO晶体光催化降解染料废水

    Institute of Scientific and Technical Information of China (English)

    弓莹; 刘慧瑾; 高雯雯; 焦玉荣

    2016-01-01

    Fe-ZnO nanocrystalline was prepared in the EtOH-H2 O solution by the NAC-FAS process,and Fe-ZnO nanocrystalline was characterized by XRD and SEM and ultraviolet-visible spectrometer with the structure and optical properties .The results show that:with the increase of Fe doping ratio ,the photocata-lytic activity of Fe-ZnO is increased , and photocatalytic activity of Fe-ZnO nanocrystalline was the best with the proportion of Fe ion is 9%.Photocatalytic activity of Fe-ZnO nanocrystalline was increased with photocatalytic degradation of methyl orange under the common action with H 2 O2 and Fe-ZnO nanocrystal-line .Fe-ZnO nanocrystalline ’ s photocatalytic properties was better than others with photocatalytic degra-dation of methyl orange when mass concentration of Fe-ZnO is 10 g/L.%采用NAC-FAS工艺在醇水溶液中制备了纳米Fe-ZnO晶体,利用XRD、SEM和UV-Vis等方法对样品的结构及光学性能进行了表征。结果表明,随着Fe掺杂比例的增加Fe-ZnO的光催化活性增加,当Fe掺杂比例为9%时的纳米Fe-ZnO晶体光催化活性最优。双氧水和纳米Fe-ZnO晶体协同作用下可以增加对甲基橙的降解率,纳米Fe-ZnO晶体的质量浓度为10 g/L时对甲基橙的降解率最佳。

  9. Magnetic structure of Fe-Fe oxide nanoparticles made by ...

    African Journals Online (AJOL)

    user

    cobalt oxide at the surface results in a magnetic system with unidirectional ... Fe / FeO particles were synthesized using laser pyrolysis by Dumitrache et al. ..... nanoparticles for magnetic targeted drug delivery and hyperthermia treatment.

  10. Determination of the Fe-rich portion of the Fe-Ni-C phase diagram

    Science.gov (United States)

    Romig, A. D., Jr.; Goldstein, J. I.

    1978-01-01

    The iron-enriched section of the phase diagram for the ternary alloy Fe-Ni-C of various compositions is determined at 773, 873, 923, and 1003 C. The two-phase tie lines and three-phase tie triangles are measured by electron microprobe analyses. Tie lines in samples without bulk equilibrium are obtained by extrapolated interface compositions under the assumption of local equilibrium at the interface. It is shown that Ni addition somewhat reduces carbon solubility in austenite while decreasing the stability of the carbide phase. In particular, the carbide is always poor in Ni relative to the coexisting metal phase(s).

  11. Iron and Nickel Line Diagnostics for the Galactic Center Diffuse Emission

    CERN Document Server

    Koyama, K; Inui, T; Nakajima, H; Matsumoto, H; Tsuru, T G; Takahashi, T; Maeda, Y; Yamazaki, N; Murakami, H; Yamauchi, S; Tsuboi, Y; Senda, A; Kataoka, J; Takahashi, H; Holt, S S; Brown, G V; Koyama, Katsuji; Hyodo, Yoshiaki; Inui, Tatsuya; Nakajima, Hiroshi; Matsumoto, Hironori; Tsuru, Takeshi Go; Takahashi, Tadayuki; Maeda, Yoshitomo; Yamazaki, Noriko; Murakami, Hiroshi; Yamauchi, Shigeo; Tsuboi, Yohko; Senda, Atsushi; Kataoka, Jun; Takahashi, Hiromitsu; Holt, Stephen S; Brown, Gregory V

    2006-01-01

    We have observed the diffuse X-ray emission from the Galactic center (GC) using the X-ray Imaging Spectrometer (XIS) on Suzaku. The high-energy resolution and the low-background orbit provide excellent spectra of the GC diffuse X-rays (GCDX). The XIS found many emission lines in the GCDX near the energy of K-shell transitions of iron and nickel. The most pronounced features are FeI K alpha at 6.4 keV and K-shell absorption edge at 7.1 keV, which are from neutral and/or low ionization states of iron, and the K-shell lines at 6.7 keV and 6.9 keV from He-like (FeXXV K alpha) and hydrogenic (FeXXVI Ly alpha) ions of iron. In addition, K alpha lines from neutral or low ionization nickel (NiI K alpha) and He-like nickel (NiXXVII K alpha), and FeI K beta, FeXXV K beta, FeXXVI Ly beta, FeXXV K gamma and FeXXVI Ly gamma are detected for the first time. The line center energies and widths of FeXXV K alpha and FeXXVI Ly alpha favor a collisional excitation (CE) plasma for the origin of the GCDX. The electron temperature...

  12. Origin of Magnetism in Hydrothermally Aged 2-Line Ferrihydrite Suspensions.

    Science.gov (United States)

    Cao, Liang; Jiang, Zhao-Xia; Du, Yong-Hua; Yin, Xin-Mao; Xi, Shi-Bo; Wen, Wen; Roberts, Andrew P; Wee, Andrew T S; Xiong, Yi-Min; Liu, Qing-Song; Gao, Xing-Yu

    2017-03-07

    As an iron oxyhydroxide, nanosized ferrihydrite (Fh) is important in Earth science, biology, and industrial applications. However, its basic structure and origin of its magnetism have long been debated. We integrate synchrotron-based techniques to explore the chemical structures of 2-line ferrihydrite and to determine the origin of its magnetism during hydrothermal aging in air. Our results demonstrate that both the magnetism and X-ray magnetic circular dichroism (XMCD) signal of 2-line ferrihydrite are enhanced with aging time, and that XMCD spectral patterns resemble that of maghemite (γ-Fe2O3) rather than magnetite (Fe3O4). Fe L-edge and K-edge X-ray absorption spectroscopy (XAS) further indicate formation of both maghemite and hematite (α-Fe2O3) with increasing concentrations with longer hydrothermal aging time. Thus, magnetic enhancement with longer hydrothermal aging time is attributed to increasing maghemite concentration instead of a magnetically ordered ferrihydrite as previously reported. Moreover, L-edge and K-edge XAS spectra with different probing depths yield different ratios of these Fe oxides, which suggest the formation of a core (ferrihydrite-rich)-shell (with a mixture of both allotropes; α-Fe2O3 and γ-Fe2O3) structure during hydrothermal aging. Our results provide insights into the chemical evolution of 2-line ferrihydrite that reveal unambiguously the origin of its magnetism.

  13. Near-Infrared Coronal Lines in Narrow-Line Seyfert 1 Galaxies

    CERN Document Server

    Rodríguez-Ardila, A; Pastoriza, M G; Prato, L; Rodriguez-Ardila, Alberto; Viegas, Sueli M.; Pastoriza, Miriani G.; Prato, Lisa

    2002-01-01

    We report spectroscopic observations in the wavelength region 0.8-2.4 microns aimed at detecting near-infrared coronal lines in a sample of 5 narrow-line and 1 broad-line Seyfert 1 galaxies. Our measurements show that [SiVI] 1.963mu, [SIX] 1.252mu and [SVIII] 0.991mu are present in most of the objects and are useful tracers of nuclear activity. Line ratios between coronal and low ionization forbidden lines are larger in narrow-line Seyfert 1 galaxies. A positive correlation between FHWM and ionization potential of the forbidden lines is observed. Some coronal lines have widths similar to that of lines emitted in the broad line region (BLR), indicating that part of their flux originates in gas close to the outer portions of the BLR. Most coronal lines are blueshifted relative to the systemic velocity of the galaxy and this shift increases with the increase in line width. Assymetries towards the blue are observed in the profiles of high-ionization Fe lines, suggesting that the emitting gas is related to winds o...

  14. Fe-S Cluster Biogenesis in Isolated Mammalian Mitochondria

    Science.gov (United States)

    Pandey, Alok; Pain, Jayashree; Ghosh, Arnab K.; Dancis, Andrew; Pain, Debkumar

    2015-01-01

    Iron-sulfur (Fe-S) clusters are essential cofactors, and mitochondria contain several Fe-S proteins, including the [4Fe-4S] protein aconitase and the [2Fe-2S] protein ferredoxin. Fe-S cluster assembly of these proteins occurs within mitochondria. Although considerable data exist for yeast mitochondria, this biosynthetic process has never been directly demonstrated in mammalian mitochondria. Using [35S]cysteine as the source of sulfur, here we show that mitochondria isolated from Cath.A-derived cells, a murine neuronal cell line, can synthesize and insert new Fe-35S clusters into aconitase and ferredoxins. The process requires GTP, NADH, ATP, and iron, and hydrolysis of both GTP and ATP is necessary. Importantly, we have identified the 35S-labeled persulfide on the NFS1 cysteine desulfurase as a genuine intermediate en route to Fe-S cluster synthesis. In physiological settings, the persulfide sulfur is released from NFS1 and transferred to a scaffold protein, where it combines with iron to form an Fe-S cluster intermediate. We found that the release of persulfide sulfur from NFS1 requires iron, showing that the use of iron and sulfur for the synthesis of Fe-S cluster intermediates is a highly coordinated process. The release of persulfide sulfur also requires GTP and NADH, probably mediated by a GTPase and a reductase, respectively. ATP, a cofactor for a multifunctional Hsp70 chaperone, is not required at this step. The experimental system described here may help to define the biochemical basis of diseases that are associated with impaired Fe-S cluster biogenesis in mitochondria, such as Friedreich ataxia. PMID:25398879

  15. AP stars with resolved Zeeman split lines

    Science.gov (United States)

    Mathys, G.

    1990-06-01

    High-resolution, high SNR observations of a sample of sharp-lined A stars and of Ap stars showing resolved Zeeman split lines are presented. The Fe II lines 6147.7 A and 6149.2 A unexpectedly appear to be asymmetric in all stars where they are resolved. The blue component of the 6149.2 line, which is a Zeeman doublet, is deeper and narrower than its red component. For line 6147.7, whose Zeeman pattern does not differ much from a quadruplet, the red components are deeper than the blue ones. It is shown that a partial Paschen-Back effect can account for these properties. The potential implications of this finding for studies of magnetic Ap stars are discussed.

  16. the Fe-N System

    Directory of Open Access Journals (Sweden)

    S. Matar

    1993-01-01

    of Fe2N for the two nitrides. The magnetization is low (0.95 μB/at. for Fe2N and vanishes for FeN. The decrease of the magnetization with increasing amount of N is assessed within the Fe-N system in a model derived from a Slater-Pauling type behavior. Accordingly, a trend from weak to strong ferromagnetism is suggested.

  17. Variability in Low Ionization Broad Absorption Line Outflows

    CERN Document Server

    Vivek, M; Petitjean, P; Mohan, V; Mahabal, A; Samui, S

    2014-01-01

    We present results of our time variability studies of Mg II and Al III absorption lines in a sample of 22 Low Ionization Broad Absorption Line QSOs (LoBAL QSOs) at 0.2 = 1 year) absorption line variability is seen in 8 cases (36% systems) while only 4 of them (i.e 18% systems) show variability over short time-scales (i.e < 1 year). We notice a tendency of highly variable LoBAL QSOs to have high ejection velocity, low equivalent width and low redshift. The detection rate of variability in LoBAL QSOs showing Fe fine-structure lines (FeLoBAL QSOs) is less than that seen in non-Fe LoBAL QSOs. Absorption line variability is more frequently detected in QSOs having continuum dominated by Fe emission lines compared to rest of the QSOs. Confirming these trends with a bigger sample will give vital clues for understanding the physical distinction between different BAL QSO sub-classes. We correlate the absorption line variability with various parameters derived from continuum light curves and find no clear correlation...

  18. Dissecting X-ray-emitting Gas around the Center of our Galaxy

    CERN Document Server

    Wang, Q D; Markoff, S B; Baganoff, F K; Nayakshin, S; Yuan, F; Cuadra, J; Davis, J; Dexter, J; Fabian, A C; Grosso, N; Haggard, D; Houck, J; Ji, L; Li, Z; Neilsen, J; Porquet, D; Ripple, F; Shcherbakov, R V

    2013-01-01

    Most supermassive black holes (SMBHs) are accreting at very low levels and are difficult to distinguish from the galaxy centers where they reside. Our own Galaxy's SMBH provides a uniquely instructive exception, and we present a close-up view of its quiescent X-ray emission based on 3 mega-second of Chandra observations. Although the X-ray emission is elongated and aligns well with a surrounding disk of massive stars, we can rule out a concentration of low-mass coronally active stars as the origin of the emission based on the lack of predicted Fe Kalpha emission. The extremely weak H-like Fe Kalpha line further suggests the presence of an outflow from the accretion flow onto the SMBH. These results provide important constraints for models of the prevalent radiatively inefficient accretion state.

  19. Precise measurement of stellar temperatures using line-depth ratios

    Energy Technology Data Exchange (ETDEWEB)

    Gray, D.F.; Johanson, H.L. (Western Ontario, University, London (Canada))

    1991-05-01

    The ratio of line depth for two spectral lines is used to determine stellar temperatures with a precision = 10 K = 0.2 percent. For stars between late-F and early-K spectral types, the V I 6251 to Fe I 6253 depth ratio is easy to measure. It is also applicable to other temperature regimes if suitable lines can be found. 14 refs.

  20. Nonreciprocal spin wave spectroscopy of thin Ni–Fe stripes

    NARCIS (Netherlands)

    Khalili Amiri, P.K.; Rejaei, B.; Vroubel, M.; Zhuang, Y.

    2007-01-01

    The authors report on the observation of nonreciprocal spin wave propagation in a thin ( ∼ 200 nm) patterned Ni–Fe stripe. The spin wave transmission spectrum is measured using a pair of microstrip lines as antennas. The nonreciprocity of surface wave dispersion brought about by an adjacent aluminum

  1. Magnetic fluctuations in nanosized goethite (alpha-FeOOH) grains

    DEFF Research Database (Denmark)

    Madsen, Daniel Esmarch; Gontard, Lionel Cervera; Kasama, Takeshi

    2009-01-01

    Mossbauer spectra of antiferromagnetic goethite (alpha-FeOOH) particles usually show an asymmetric line broadening, which increases with increasing temperature, although the magnetic anisotropy is expected to be so large that magnetic relaxation effects should be negligible. By use of high resolu...

  2. Coupled perpendicular magnetization in Fe/Cu/Fe trilayers

    Energy Technology Data Exchange (ETDEWEB)

    Repetto, D. [Max Planck Institut fuer Festkoerperforschung, Heisenbergstr. 1, D-70569 Stuttgart (Germany)]. E-mail: D.Repetto@fkf.mpg.de; Enders, A. [Max Planck Institut fuer Festkoerperforschung, Heisenbergstr. 1, D-70569 Stuttgart (Germany); Kern, K. [Max Planck Institut fuer Festkoerperforschung, Heisenbergstr. 1, D-70569 Stuttgart (Germany)

    2006-05-15

    Ultrathin epitaxial Fe films on Cu(1 0 0) with perpendicular magnetization have been used as templates for the preparation of FCC Fe/Cu/Fe trilayers. The magnetic anisotropy and the coupling of these films have been studied by in-situ magneto optical Kerr effect measurements and Kerr microscopy. The magnetic coupling of both Fe layers is found to be dominated by magnetostatic interaction. Adsorbate-induced spin reorientation in the top layer also causes spin reorientation in the bottom layer. The governing role of the Fe-vacuum interface for the magnetism of the whole trilayer is demonstrated.

  3. Measuring FeO variation using astronomical spectroscopic observations

    Science.gov (United States)

    Unterguggenberger, Stefanie; Noll, Stefan; Feng, Wuhu; Plane, John M. C.; Kausch, Wolfgang; Kimeswenger, Stefan; Jones, Amy; Moehler, Sabine

    2017-03-01

    Airglow emission lines of OH, O2, O and Na are commonly used to probe the MLT (mesosphere-lower thermosphere) region of the atmosphere. Furthermore, molecules like electronically excited NO, NiO and FeO emit a (pseudo-) continuum. These continua are harder to investigate than atomic emission lines. So far, limb-sounding from space and a small number of ground-based low-to-medium resolution spectra have been used to measure FeO emission in the MLT. In this study the medium-to-high resolution echelle spectrograph X-shooter at the Very Large Telescope (VLT) in the Chilean Atacama Desert (24°37' S, 70°24' W; 2635 m) is used to study the FeO pseudo-continuum in the range from 0.5 to 0.72 µm based on 3662 spectra. Variations of the FeO spectrum itself, as well as the diurnal and seasonal behaviour of the FeO and Na emission intensities, are reported. These airglow emissions are linked by their common origin, meteoric ablation, and they share O3 as a common reactant. Major differences are found in the main emission peak of the FeO airglow spectrum between 0.58 and 0.61 µm, compared with a theoretical spectrum. The FeO and Na airglow intensities exhibit a similar nocturnal variation and a semi-annual seasonal variation with equinoctial maxima. This is satisfactorily reproduced by a whole atmosphere chemistry climate model, if the quantum yields for the reactions of Fe and Na with O3 are 13 ± 3 and 11 ± 2 % respectively. However, a comparison between the modelled O3 in the upper mesosphere and measurements of O3 made with the SABER satellite instrument suggests that these quantum yields may be a factor of ˜ 2 smaller.

  4. Electronic structure and characteristics of Fe 3d valence states of Fe(1.01)Se superconductors under pressure probed by x-ray absorption spectroscopy and resonant x-ray emission spectroscopy.

    Science.gov (United States)

    Chen, J M; Haw, S C; Lee, J M; Chen, S A; Lu, K T; Deng, M J; Chen, S W; Ishii, H; Hiraoka, N; Tsuei, K D

    2012-12-28

    The electronic structure and characteristics of Fe 3d valence states of iron-chalcogenide Fe(1.01)Se superconductors under pressure were probed with x-ray absorption spectroscopy and resonant x-ray emission spectroscopy (RXES). The intensity of the pre-edge peak at ~7112.7 eV of the Fe K-edge x-ray absorption spectrum of Fe(1.01)Se decreases for pressure from 0.5 GPa increased to 6.9 GPa. The satellite line Kβ' was reduced in intensity upon applying pressure and became absent for pressure 52 GPa. Fe(1.01)Se shows a small net magnetic moment of Fe(2+), likely arising from strong Fe-Fe spin fluctuations. The 1s3p-RXES spectra of Fe(1.01)Se at pressures 0.5, 6.9, and 52 GPa recorded at the Fe K-edge reveal that unoccupied Fe 3d states exhibit a delocalized character, stemming from hybridization of Fe 3d and 4p orbitals arising from a local distortion around the Fe atom in a tetrahedral site. Application of pressure causes suppression of this on-site Fe 3d-Fe 4p hybridization, and thereby decreases the intensity of the pre-edge feature in the Fe K-edge absorption spectrum of Fe(1.01)Se. Compression enhances spin fluctuations at Fe sites in Fe(1.01)Se and increases the corresponding T(c), through a competition between nearest-neighbor ferromagnetic and next-nearest-neighbor antiferromagnetic superexchange interactions. This result aids our understanding of the physics underlying iron-based superconductors.

  5. Microstructural characterization and amorphous phase formation in Co{sub 40}Fe{sub 22}Ta{sub 8}B{sub 30} powders produced by mechanical alloying

    Energy Technology Data Exchange (ETDEWEB)

    Taghvaei, Amir Hossein, E-mail: amirtaghvaei@gmail.com [Department of Materials Science and Engineering, School of Engineering, Shiraz University, Shiraz (Iran, Islamic Republic of); Stoica, Mihai [IFW Dresden, Institute for Complex Materials, Helmholtzstr. 20, D-01069 Dresden (Germany); Vaughan, Gavin [ESRF, F-38042 Grenoble (France); Ghaffari, Mohammad [School of Electrical and Electronic Engineering, Nanyang Technological University, Nanyang Avenue, Singapore 639798 (Singapore); Maleksaeedi, Saeed [Singapore Institute of Manufacturing Technology, 71 Nanyang Drive, Singapore 638075 (Singapore); Janghorban, Kamal [Department of Materials Science and Engineering, School of Engineering, Shiraz University, Shiraz (Iran, Islamic Republic of)

    2012-01-25

    Highlights: Black-Right-Pointing-Pointer Mechanical alloying developed the amorphous phase in Co{sub 40}Fe{sub 22}Ta{sub 8}B{sub 30} alloy. Black-Right-Pointing-Pointer The powders had 96 wt% amorphous phase after 200 h milling. Black-Right-Pointing-Pointer The 200 h milled powders showed the huge relaxation hump in the DSC plot. Black-Right-Pointing-Pointer The mean volume lattice strain was calculated based on the Miracle's model. - Abstract: In this work, microstructural evolution and amorphous phase formation in Co{sub 40}Fe{sub 22}Ta{sub 8}B{sub 30} alloy produced by mechanical alloying (MA) of the elemental powder mixture under argon gas atmosphere was investigated. Milling time had a profound effect on the phase transformation, microstructure, morphological evolution and thermal behavior of the powders. These effects were studied by the X-ray powder diffraction (XRD) in reflection mode using Cu K{alpha} and in transmission configuration using synchrotron radiation, transmission electron microscopy (TEM), scanning electron microscopy (SEM) and differential scanning calorimetry (DSC). The results showed that at the early stage of the milling, microstructure consisted of nanocrystalline bcc-(Fe, Co) phases and unreacted tantalum. Further milling, produced an amorphous phase, which became a dominant phase with a fraction of 96 wt% after 200 h milling. The DSC profile of 200 h milled powders demonstrated a huge and broad exothermic hump due to the structural relaxation, followed by a single exothermic peak, indicating the crystallization of the amorphous phase. Further XRD studies in transmission mode by synchrotron radiation revealed that the crystalline products were (Co, Fe){sub 20.82}Ta{sub 2.18}B{sub 6}, (Co, Fe){sub 21} Ta{sub 2} B{sub 6}, and (Co, Fe){sub 3}B{sub 2}. The amorphization mechanisms were discussed in terms of severe grain refinement, atomic size effect, the concept of local topological instability and the heat of mixing of the reactants.

  6. THE Fe II EMISSION IN ACTIVE GALACTIC NUCLEI: EXCITATION MECHANISMS AND LOCATION OF THE EMITTING REGION

    Energy Technology Data Exchange (ETDEWEB)

    Marinello, M. [Universidade Federal de Itajubá, Rua Doutor Pereira Cabral 1303, 37500-903, Itajubá, MG (Brazil); Rodríguez-Ardila, A.; Garcia-Rissmann, A. [Laboratório Nacional de Astrofísica, Rua Estados Unidos 154, Itajubá, MG, 37504-364 (Brazil); Sigut, T. A. A. [The University of Western Ontario, London, ON N6A 3K7 (Canada); Pradhan, A. K., E-mail: murilo.marinello@gmail.com [McPherson Laboratory, The Ohio State University, 140 W. 18th Ave., Columbus, OH 43210-1173 (United States)

    2016-04-01

    We present a study of Fe ii emission in the near-infrared region (NIR) for 25 active galactic nuclei (AGNs) to obtain information about the excitation mechanisms that power it and the location where it is formed. We employ an NIR Fe ii template derived in the literature and find that it successfully reproduces the observed Fe ii spectrum. The Fe ii bump at 9200 Å detected in all objects studied confirms that Lyα fluorescence is always present in AGNs. The correlation found between the flux of the 9200 Å bump, the 1 μm lines, and the optical Fe ii implies that Lyα fluorescence plays an important role in Fe ii production. We determined that at least 18% of the optical Fe ii is due to this process, while collisional excitation dominates the production of the observed Fe ii. The line profiles of Fe ii λ10502, O i λ11287, Ca ii λ8664, and Paβ were compared to gather information about the most likely location where they are emitted. We found that Fe ii, O i and Ca ii have similar widths and are, on average, 30% narrower than Paβ. Assuming that the clouds emitting the lines are virialized, we show that the Fe ii is emitted in a region twice as far from the central source than Paβ. The distance, though, strongly varies: from 8.5 light-days for NGC 4051 to 198.2 light-days for Mrk 509. Our results reinforce the importance of the Fe ii in the NIR to constrain critical parameters that drive its physics and the underlying AGN kinematics, as well as more accurate models aimed at reproducing this complex emission.

  7. Hyperthermia and chemotherapy using Fe(Salen) nanoparticles might impact glioblastoma treatment

    Science.gov (United States)

    Ohtake, Makoto; Umemura, Masanari; Sato, Itaru; Akimoto, Taisuke; Oda, Kayoko; Nagasako, Akane; Kim, Jeong-Hwan; Fujita, Takayuki; Yokoyama, Utako; Nakayama, Tomohiro; Hoshino, Yujiro; Ishiba, Mai; Tokura, Susumu; Hara, Masakazu; Muramoto, Tomoya; Yamada, Sotoshi; Masuda, Takatsugu; Aoki, Ichio; Takemura, Yasushi; Murata, Hidetoshi; Eguchi, Haruki; Kawahara, Nobutaka; Ishikawa, Yoshihiro

    2017-01-01

    We previously reported that μ-oxo N,N’-bis(salicylidene)ethylenediamine iron [Fe(Salen)], a magnetic organic compound, has direct anti-tumor activity, and generates heat in an alternating magnetic field (AMF). We showed that Fe(Salen) nanoparticles are useful for combined hyperthermia-chemotherapy of tongue cancer. Here, we have examined the effect of Fe(Salen) on human glioblastoma (GB). Fe(Salen) showed in vitro anti-tumor activity towards several human GB cell lines. It inhibited cell proliferation, and its apoptosis-inducing activity was greater than that of clinically used drugs. Fe(Salen) also showed in vivo anti-tumor activity in the mouse brain. We evaluated the drug distribution and systemic side effects of intracerebrally injected Fe(Salen) nanoparticles in rats. Further, to examine whether hyperthermia, which was induced by exposing Fe(Salen) nanoparticles to AMF, enhanced the intrinsic anti-tumor effect of Fe(Salen), we used a mouse model grafted with U251 cells on the left leg. Fe(Salen), BCNU, or normal saline was injected into the tumor in the presence or absence of AMF exposure. The combination of Fe(Salen) injection and AMF exposure showed a greater anti-tumor effect than did either Fe(Salen) or BCNU alone. Our results indicate that hyperthermia and chemotherapy with single-drug nanoparticles could be done for GB treatment. PMID:28218292

  8. Evidence for Fluorescent Fe II Emission from Extended Low Ionization Outflows in Obscured Quasars

    Science.gov (United States)

    Wang, Tinggui; Ferland, Gary J.; Yang, Chenwei; Wang, Huiyuan; Zhang, Shaohua

    2016-06-01

    Recent studies have shown that outflows in at least some broad absorption line (BAL) quasars are extended well beyond the putative dusty torus. Such outflows should be detectable in obscured quasars. We present four WISE selected infrared red quasars with very strong and peculiar ultraviolet Fe ii emission lines: strong UV Fe ii UV arising from transitions to ground/low excitation levels, and very weak Fe ii at wavelengths longer than 2800 Å. The spectra of these quasars display strong resonant emission lines, such as C iv, Al iii and Mg ii but sometimes, a lack of non-resonant lines such as C iii], S iii and He ii. We interpret the Fe ii lines as resonantly scattered light from the extended outflows that are viewed nearly edge-on, so that the accretion disk and broad line region are obscured by the dusty torus, while the extended outflows are not. We show that dust free gas exposed to strong radiation longward of 912 Å produces Fe ii emission very similar to that observed. The gas is too cool to collisionally excite Fe ii lines, accounting for the lack of optical emission. The spectral energy distribution from the UV to the mid-infrared can be modeled as emission from a clumpy dusty torus, with UV emission being reflected/scattered light either by the dusty torus or the outflow. Within this scenario, we estimate a minimum covering factor of the outflows from a few to 20% for the Fe ii scattering region, suggesting that Fe ii BAL quasars are at a special stage of quasar evolution.

  9. Iron Features in the XMM-Newton spectrum of NGC 4151

    CERN Document Server

    Schurch, N J; Griffiths, R E; Ptak, A F

    2002-01-01

    We present a detailed analysis of the hard X-ray (>2.5 keV) EPIC spectra from the first observations of NGC 4151 made by XMM-Newton. We fit the spectra with a model consisting of a power-law continuum modified by line-of-sight absorption (arising in both partially photoionized and neutral gas) plus additional iron-K emission and absorption features. This model provides an excellent overall fit to the EPIC spectra. The iron K-alpha line is well modelled as a narrow Gaussian component. In contrast to several earlier studies based on data from ASCA, a relativistically broadened iron K-alpha emission feature is not required by the XMM-Newton data. The upper limit on the flux contained in any additional broad line is ~8% of that in the narrow line. The measured intrinsic line width (sigma =32+_7 eV) may be ascribed to (i) the doublet nature of the iron K-alpha line and (ii) emission from low ionization states of iron, ranging from neutral up to ~FeXVII. The additional iron absorption edge arises in cool material a...

  10. Evershed flow observed in neutral and singly ionized iron lines

    CERN Document Server

    Khomenko, E; Shchukina, N; Diaz, A

    2015-01-01

    The amplitudes of the Evershed flow are measured using pairs of carefully selected FeI and FeII spectral lines located close in wavelength and registered simultaneously. A sunspot belonging to the NOAA 11582 group was scanned using the spectrograph of the German Vacuum Tower Telescope (Observatorio del Teide, Tenerife). Velocities were extracted from intensity profiles using the lambda-meter technique. The formation heights of the observed spectral lines were calculated using semi-empirical models of a bright and dark penumbral filament taking into account the sunspot location at the limb. Our objective is to compare azimuthally averaged amplitudes of the Evershed flow extracted from neutral and ion lines. We find measurable differences in the radial component of the flow. All five pairs of lines show the same tendency, with a few hundred m/s larger amplitude of the flow measured from FeI lines compared to FeII lines. This tendency is preserved at all photospheric heights and radial distances in the penumbra....

  11. Evershed flow observed in neutral and singly ionized iron lines

    Science.gov (United States)

    Khomenko, E.; Collados, M.; Shchukina, N.; Díaz, A.

    2015-12-01

    The amplitudes of the Evershed flow are measured using pairs of carefully selected Fe i and Fe ii spectral lines that are close in wavelength and registered simultaneously. A sunspot belonging to the NOAA 11582 group was scanned using the spectrograph of the German Vacuum Tower Telescope (Observatorio del Teide, Tenerife). Velocities were extracted from intensity profiles using the λ-meter technique. The formation heights of the observed spectral lines were calculated using semi-empirical models of a bright and dark penumbral filament taking into account the sunspot location at the limb. Our objective is to compare azimuthally averaged amplitudes of the Evershed flow extracted from neutral and ion lines. We find measurable differences in the radial component of the flow. All five pairs of lines show the same tendency; the flow measured from the Fe i lines has an amplitude that is a few hundred ms-1 larger than that of the Fe ii lines. This tendency is preserved at all photospheric heights and radial distances in the penumbra. We discuss the possible origin of this effect.

  12. Fe I Oscillator Strengths for the Gaia-ESO Survey

    CERN Document Server

    Ruffoni, M P; Lawler, J E; Brewer, N R; Lind, K; Nave, G; Pickering, J C

    2014-01-01

    The Gaia-ESO Public Spectroscopic Survey (GES) is conducting a large-scale study of multi-element chemical abundances of some 100 000 stars in the Milky Way with the ultimate aim of quantifying the formation history and evolution of young, mature and ancient Galactic populations. However, in preparing for the analysis of GES spectra, it has been noted that atomic oscillator strengths of important Fe I lines required to correctly model stellar line intensities are missing from the atomic database. Here, we present new experimental oscillator strengths derived from branching fractions and level lifetimes, for 142 transitions of Fe I between 3526 {\\AA} and 10864 {\\AA}, of which at least 38 are urgently needed by GES. We also assess the impact of these new data on solar spectral synthesis and demonstrate that for 36 lines that appear unblended in the Sun, Fe abundance measurements yield a small line-by-line scatter (0.08 dex) with a mean abundance of 7.44 dex in good agreement with recent publications.

  13. Absolute Energy Calibration of X-ray TESs with 0.04 eV Uncertainty at 6.4 keV in a Hadron-Beam Environment

    CERN Document Server

    Tatsuno, H; Bennett, D A; Curceanu, C; Fowler, J W; Gard, J; Gustafsson, F P; Hashimoto, T; Hayano, R S; Hays-Wehle, J P; Hilton, G C; Iliescu, M; Ishimoto, S; Itahashi, K; Iwasaki, M; Kuwabara, K; Ma, Y; Marton, J; Noda, H; O'Neil, G C; Okada, S; Outa, H; Reintsema, C D; Sato, M; Schmidt, D R; Shi, H; Suzuki, K; Suzuki, T; Uhlig, J; Ullom, J N; Widmann, E; Yamada, S; Zmeskal, J; Swetz, D S

    2016-01-01

    A performance evaluation of superconducting transition-edge sensors (TESs) in the environment of a pion beam line at a particle accelerator is presented. Averaged across the 209 functioning sensors in the array, the achieved energy resolution is 5.2 eV FWHM at Co $K_{\\alpha}$ (6.9 keV) when the pion beam is off and 7.3 eV at a beam rate of 1.45 MHz. Absolute energy uncertainty of $\\pm$0.04 eV is demonstrated for Fe $K_{\\alpha}$ (6.4 keV) with in-situ energy calibration obtained from other nearby known x-ray lines. To achieve this small uncertainty, it is essential to consider the non-Gaussian energy response of the TESs and thermal cross-talk pile-up effects due to charged-particle hits in the silicon substrate of the TES array.

  14. Local electronic structure of olivine phases of LixFePO4.

    Science.gov (United States)

    Miao, Shu; Kocher, Michael; Rez, Peter; Fultz, Brent; Yazami, Rachid; Ahn, Channing C

    2007-05-24

    Changes in the local electronic structure at atoms around Li sites in the olivine phase of LiFePO4 were studied during delithiation. Electron energy loss spectrometry was used for measuring shifts and intensities of the near-edge structure at the K-edge of O and at the L-edges of P and Fe. Electronic structure calculations were performed on these materials with a plane-wave pseudopotential code and with an atomic multiplet code with crystal fields. It is found that both Fe and O atoms accommodate some of the charge around the Li+ ion, evidently in a hybridized Fe-O state. The O 2p levels appear to be fully occupied at the composition LiFePO4. With delithiation, however, these states are partially emptied, suggestive of a more covalent bonding to the oxygen atom in FePO4 as compared to LiFePO4. The same behavior is found for the white lines at the Fe L2,3-edges, which also undergo a shift in energy upon delithiation. A charge transfer of up to 0.48 electrons is found at the Fe atoms, as determined from white line intensity variations after delithiation, while the remaining charge is compensated by O atoms. No changes are evident at the P L2,3-edges.

  15. Revisited abundance diagnostics in quasars: Fe II/Mg II ratios

    CERN Document Server

    Verner, E M; Verner, D A; Johansson, S; Gull, T R

    2003-01-01

    Both the Fe II UV emission in the 2000- 3000 A region [Fe II (UV)] and resonance emission line complex of Mg II at 2800 A are prominent features in quasar spectra. The observed Fe II UV/ Mg II emission ratios have been proposed as means to measure the buildup of the Fe abundance relative to that of the alpha-elements C, N, O, Ne and Mg as a function of redshift. The current observed ratios show large scatter and no obvious dependence on redshift. Thus, it remains unresolved whether a dependence on redshift exists and whether the observed Fe II UV/ Mg II ratios represent a real nucleosynthesis diagnostic. We have used our new 830-level model atom for Fe+ in photoionization calculations, reproducing the physical conditions in the broad line regions of quasars. This modeling reveals that interpretations of high values of Fe II UV/ Mg II are sensitive not only to Fe and Mg abundance, but also to other factors such as microturbulence, density, and properties of the radiation field. We find that the Fe II UV/ Mg II...

  16. Bottom and top AF/FM interfaces of NiFe/FeMn/NiFe trilayers

    Science.gov (United States)

    Nascimento, V. P.; Passamani, E. C.; Alvarenga, A. D.; Biondo, A.; Pelegrini, F.; Saitovitch, E. Baggio

    2008-01-01

    X-ray reflectivity analyses were performed in the Si/WTi (7 nm)/NiFe (30 nm)/FeMn (13 nm)/NiFe (10 nm)/WTi (7 nm) exchange-biased system prepared by magnetron sputtering under three different argon working pressures. Layer-by-layer analyses were realized in order to obtain the interfacial roughness parameters quantitatively. For a fixed argon pressure, the root-mean-square roughness (including the atomic grading) of the upper (FeMn/NiFe) interface are greater than that for the lower one in all studied samples. Argon working pressure also has severe influence over the NiFe/FeMn interfaces, being more pronounced at the upper interfaces.

  17. Relations between the IR-UV-X-ray Continuum and Emission Lines for a Large Composite Sample of Narrow Line and Normal Seyfert i Galaxies

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    We report on our research on the UV, optical line parameters and the infrared through UV to soft X-ray continuum parameters for a composite sample of narrow line and normal Seyfert 1 galaxies. The strong correlations among the line width of Hβ, optical line strength of Fe II and the soft X-ray slope are confirmed. We found no correlations between the UV line parameters, the equivalent widths of Lya and CIV and their ratio on one hand and the optical line parameters on the other. The UV and X-ray luminosities strongly correlate with the line widths of Hβand the Fe II/Hβ ratio. No significant correlation is found between the infrared-soft X-ray continuum slope αix and the line width of Hβ.

  18. Investigations of Deep-Level Fe-centres in Si by Mössbauer Spectroscopy

    CERN Multimedia

    Dietrich, M

    2002-01-01

    %IS359\\\\ \\\\Electronic, vibrational and diffusional properties of interstitial and substitutional Fe impurities in silicon are studied by $ ^{57} $Fe Mössbauer emission spectroscopy utilizing implanted radioactive $ ^{57}$Mn$^{+} $ parent ions from ISOLDE as probe atoms. Thus the electronic charge density and the impurity mean-square vibrational amplitude shall be determined for substitutional Fe$_{s} $ and for interstitial Fe$_{i}^{0/+} $ in its two different charge states. These quantities are complementary to previously determined hyperfine interaction parameters and are expected to shed light on the nature of the deviations between calculated and measured parameters. The supposedly different diffusivities of interstitial Fe$_{i}^{0} $ and Fe$_{i}^{+} $ shall be measured by the broadening of the Mössbauer lines, i.e. at a temperature where diffusion jumps occur on an atomic scale within the lifetime of the Mössbauer state.

  19. Pressure-Induced Electronic Spin Transition of Iron in Magnesiow?stite-(Mg,Fe)O

    Energy Technology Data Exchange (ETDEWEB)

    Lin, J F; Gavriliuk, A G; Struzhkin, V V; Jacobsen, S D; Sturhahn, W; Hu, M Y; Chow, P; Yoo, C S

    2005-10-05

    An electronic transition of iron in magnesiowuestite has been studied with synchrotron Moessbauer and X-ray emission spectroscopies under high pressures. Synchrotron Moessbauer studies show that the quadrupole splitting disappears and the isomer shift drops significantly across the spin-paring transition of iron in (Mg{sub 0.75},Fe{sub 0.25})O between 62 and 70 GPa, whereas X-ray emission spectroscopy of the Fe-K{sub {beta}} fluorescence lines in dilute (Mg{sub 0.95},Fe{sub 0.05})O also confirms that a high-spin to low-spin transition occurs between 46 GPa and 55 GPa. Based upon current results and percolation theory, we reexamine the high-pressure phase diagram of (Mg,Fe)O and find that iron-iron exchange interaction plays an important role in stabilizing the high-spin state of iron in FeO-rich (Mg,Fe)O.

  20. CEMS study of defect annealing in Fe implanted AlN

    Science.gov (United States)

    Bharuth-Ram, K.; Geburt, S.; Ronning, C.; Masenda, H.; Naidoo, D.

    2016-12-01

    An AlN thin film grown on sapphire substrate was implanted with 45 keV 57Fe and 56Fe ions at several energies to achieve a homogeneous concentration profile of approximately 2.6 at.%. in the AlN film. Conversion electron Mössbauer Spectroscopy data were collected after annealing the sample up to 900 °C. The spectra were fitted with three components, a single line attributed to small Fe clusters, and two quadrupole split doublets attributed to Fe substituting Al in the wurtzite AlN lattice and to Fe located in implantation induced lattice damage. The damage component shows significant decrease on annealing up to 900 °C, accompanied by corresponding increases in the singlet component and the substitutional Fe.

  1. (75)As NQR studies on FeAs2.

    Science.gov (United States)

    Lehmann-Horn, J A; Yong, R; Miljak, D G; Bastow, T J

    2015-10-01

    (75)As NQR spectra and relaxation times of synthetic and natural FeAs2 samples have been studied at variable static magnetic field and temperature. FeAs2 is a well understood diamagnetic semiconductor and occurs as the natural mineral lollingite in selected ore deposits. We observed a spin-spin relaxation time enhancement of up to five in synthetic powders in the presence of a weak external static magnetic field. The effect is of interest with regard to signal-to-noise ratio improvement for materials characterization applications where broad NQR absorption lines are excited with wideband pulse sequences.

  2. Fe Kα Profiles from Simulations of Accreting Black Holes

    Science.gov (United States)

    Kinch, Brooks E.; Schnittman, Jeremy D.; Kallman, Timothy R.; Krolik, Julian H.

    2016-07-01

    We present the first results from a new technique for the prediction of Fe Kα profiles directly from general relativistic magnetohydrodynamic (GRMHD) simulations. Data from a GRMHD simulation are processed by a Monte Carlo global radiation transport code, which determines the X-ray flux irradiating the disk surface and the coronal electron temperature self-consistently. With that irradiating flux and the disk’s density structure drawn from the simulation, we determine the reprocessed Fe Kα emission from photoionization equilibrium and solution of the radiation transfer equation. We produce maps of the surface brightness of Fe Kα emission over the disk surface, which—for our example of a 10{M}⊙ Schwarzschild black hole accreting at 1% the Eddington value—rises steeply one gravitational radius outside the radius of the innermost stable circular orbit and then falls ∝r -2 at larger radii. We explain these features of the Fe Kα radial surface brightness profile as consequences of the disk’s ionization structure and an extended coronal geometry, respectively. We also present the corresponding Feline profiles as would be seen by distant observers at several inclinations. Both the shapes of the line profiles and the equivalent widths of our predicted Kα lines are qualitatively similar to those typically observed from accreting black holes. Most importantly, this work represents a direct link between theory and observation: in a fully self-consistent way, we produce observable results—iron fluorescence line profiles—from the theory of black hole accretion with almost no phenomenological assumptions.

  3. EELS spectroscopy of iron fluorides and FeFx/C nanocomposite electrodes used in Li-ion batteries.

    Science.gov (United States)

    Cosandey, Frederic; Al-Sharab, Jafar F; Badway, Fadwa; Amatucci, Glenn G; Stadelmann, Pierre

    2007-04-01

    A new type of positive electrode for Li-ion batteries has been developed recently based on FeF3/C and FeF2/C nanocomposites. The microstructural and redox evolution during discharge and recharge processes was followed by electron energy loss spectroscopy (EELS) to determine the valence state of Fe by measuring the Fe L3 line energy shift and from Fe L3/L2 line intensity ratios. In addition, transition metal fluorides were found to be electron beam sensitive, and the effect of beam exposure on EELS spectra was also investigated. The EELS results indicate that for both FeF3/C and FeF2/C nanocomposite systems, a complete reduction of iron to FeO is observed upon discharge to 1.5 V with the formation of a finer FeO/LiF subnanocomposite ( approximately 7 nm). Upon complete recharging to 4.5 V, EELS data reveal a reoxidation process to a Fe2+ state with the formation of a carbon metal fluoride nanocomposite related to the FeF2 structure.

  4. Evidence for Fluorescent Fe II Emission from Extended Low Ionization Outflows in Obscured Quasars

    CERN Document Server

    Wang, Tinggui; Yang, Chenwei; Wang, Huiyuan; Zhang, Shaohua

    2016-01-01

    Recent studies have shown that outflows in at least some broad absorption line (BAL) quasars are extended well beyond the putative dusty torus. Such outflows should be detectable in obscured quasars. We present four WISE selected infrared red quasars with very strong and peculiar ultraviolet Fe ii emission lines: strong UV Fe II UV arising from transitions to ground/low excitation levels, and very weak Fe II at wavelengths longer than 2800 {\\AA}. The spectra of these quasars display strong resonant emission lines, such as C IV, Al III and Mg II but sometimes, a lack of non-resonant lines such as C III], S III and He II. We interpret the Fe II lines as resonantly scattered light from the extended outflows that are viewed nearly edge-on, so that the accretion disk and broad line region are obscured by the dusty torus, while the extended outflows are not. We show that dust free gas exposed to strong radiation longward of 912 {\\AA} produces Fe II emission very similar to that observed. The gas is too cool to coll...

  5. Beam line to S155

    CERN Multimedia

    1977-01-01

    The experiment S155 was designed by the Orsay (CSNM-CNRS) Collaboration to observe the properties of exotic light nuclei. It was installed in the PS neutrino tunnel. The photo shows a mass spectrometer (in the background) on line with the PS proton beam which arrives (bottom, right) from the fast extraction FE74. Roger Fergeau stands on the left. The alkaline isotopes produced in the carbon-uranium target heated at 2000°C were swiftly extracted, mass separated, and brought to a detector behind the shielding. Sodium 34 (11 protons and 23 neutrons) was observed and its half-life of only 5 ms was measured. The excited levels 2+ of Magnesium 30 and Magnesium 32 (Sodium descendants) were localised, and the magic number 20 was found to vanish. Thus, the discovery made earlier for Sodium 30 and Sodium 32, with the same apparatus, was confirmed. (See also photo 7706511.)

  6. Central line infections - hospitals

    Science.gov (United States)

    ... infection; Central venous catheter - infection; CVC - infection; Central venous device - infection; Infection control - central line infection; Nosocomial infection - central line infection; Hospital acquired ...

  7. A Study of Ceramic-Lined Composite Steel Pipes Prepared by SHS Centrifugal-Thermite Process

    National Research Council Canada - National Science Library

    Yuxin Li; Letao Jiang; Qing Lu; Peikang Bai; Bin Liu; Jianhong Wang

    2016-01-01

    .... The result showed the ceramic lined pipe is composed of the three main layers of various compositions, which were subsequently determined to be Fe layer, the transition layer and the ceramic layer...

  8. Tunnel Magneto Resistance of Fe/Insulator/Fe

    Science.gov (United States)

    Aryee, Dennis; Seifu, Dereje

    Tri-layer thin films of Fe/Insulator/Fe were synthesized using magnetron DC/ RF sputtering with MgO insulator and Bi2Te3 topological insulators as middle buffer layer. The multi-layered samples thus produced were studied using in-house built magneto-optic Kerr effect (MOKE) instrument, vibrating sample magnetometer (VSM), torque magnetometer (TMM), AFM, MFM, and magneto-resistance (MR). This system, that is Fe/Insulator/Fe on MgO(100) substrate, is a well-known tunnel magneto resistance (TMR) structure often used in magnetic tunnel junction (MTJ) devices. TMR effect is a method by which MTJs are used in developing magneto-resistive random access memory (MRAM), magnetic sensors, and novel logic devices. The main purpose behind this research is to measure the magnetic anisotropy of Fe/Insulator /Fe structure and correlate it to magneto-resistance. In this presentation, we will present results from MOKE, VSM, TMM, AFM, MFM, and MR studies of Fe/Insulator/Fe on MgO(100). We would like to acknowledge support by NSF-MRI-DMR-1337339.

  9. Fe-B-Y-Nb bulk metallic glasses in relation to clusters

    Institute of Scientific and Technical Information of China (English)

    CHENG Xu; WANG Qing; CHEN WeiRong; DONG Chuang

    2008-01-01

    Bulk metallic glass formations in the Fe-B-Y-Nb quaternary alloy system were in-vestigated by using the cluster line rule in combination with the minor alloying principle. The Fe-B-Y ternary system was selected as the basic system and the intersections of cluster lines were taken as the basic ternary compositions. The basic compositions were further alloyed with minor amounts of Nb. After 3-5 at.% Nb was added, the basic composition Fe68.6B25.7Y5.7, which was developed from the most densely packed cluster Fe8B3, formed 3 mm bulk metallic glasses. These quaternary bulk metallic glasses (Fe68.6B25.7Y5.7)100-xNbx (x=3-5at. %) are expressed approximately with a unified simple composition formula: (Fe8B3)1(Y, Nb)1. The (Fe68.6B25.7Y5.7)97Nb3 bulk metallic glass has the largest glass forming ability with the following characteristic parameters Tg=907 K, Tx=1006 K, Tg/T1=0.644, γ= 0.434, and Iongness t=22 mm. The combination of the cluster line rule and the minor-alloying principle is a promising new route towards the quantitative composition design of multi-component metallic glasses.

  10. Fe-B-Y-Nb bulk metallic glasses in relation to clusters

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    Bulk metallic glass formations in the Fe-B-Y-Nb quaternary alloy system were in-vestigated by using the cluster line rule in combination with the minor alloying principle. The Fe-B-Y ternary system was selected as the basic system and the intersections of cluster lines were taken as the basic ternary compositions. The basic compositions were further alloyed with minor amounts of Nb. After 3-5 at.% Nb was added,the basic composition Fe68.6B25.7Y5.7,which was developed from the most densely packed cluster Fe8B3,formed 3 mm bulk metallic glasses. These quaternary bulk metallic glasses (Fe68.6B25.7Y5.7)100-xNbx (x=3-5 at.%) are expressed approximately with a unified simple composition formula: (Fe8B3)1(Y,Nb)1. The (Fe68.6B25.7Y5.7)97Nb3 bulk metallic glass has the largest glass forming ability with the following characteristic parameters Tg=907 K,Tx=1006 K,Tg/Tl=0.644,γ=0.434,and longness t=22 mm. The combination of the cluster line rule and the minor-alloying principle is a promising new route towards the quantitative composition design of multi-component metallic glasses.

  11. Paramagnetism in Mn/Fe implanted ZnO

    CERN Document Server

    Gunnlaugsson, HP; Weyer, G; Kobayashi, Y; Bharuth-Ram, K; Olafsson, S; Gislason, H P; Gunnlaugsson, H P; Yoshida, Y; Langouche, G; Molholt, T E; Masenda, H; Johnston, K; Sielemann, R; Dlamini, W B; ISOLDE Collaboration; Naidoo, D; Mantovan, R

    2010-01-01

    Prompted by the generally poor understanding of the nature of magnetic phenomena in 3d-metal doped ZnO, we have undertaken on-line Fe-57 Mossbauer spectroscopy on ZnO single crystals in an external magnetic field of 0.6 T, following the implantation of radioactive Mn-57 ions at room temperature. The Mossbauer spectra of the dilute Fe impurities are dominated by sextets whose angular dependence rules out an ordered magnetic state (which had been previously proposed) but are well accounted for on the basis of Fe3+ paramagnetic centers on substitutional Zn sites with unusually long relaxation times (> 20 ns). (C) 2010 American Institute of Physics. {[}doi:10.1063/1.3490708

  12. About cosmic gamma ray lines

    Science.gov (United States)

    Diehl, Roland

    2017-06-01

    Gamma ray lines from cosmic sources convey the action of nuclear reactions in cosmic sites and their impacts on astrophysical objects. Gamma rays at characteristic energies result from nuclear transitions following radioactive decays or high-energy collisions with excitation of nuclei. The gamma-ray line from the annihilation of positrons at 511 keV falls into the same energy window, although of different origin. We present here the concepts of cosmic gamma ray spectrometry and the corresponding instruments and missions, followed by a discussion of recent results and the challenges and open issues for the future. Among the lessons learned are the diffuse radioactive afterglow of massive-star nucleosynthesis in 26Al and 60Fe gamma rays, which is now being exploited towards the cycle of matter driven by massive stars and their supernovae; large interstellar cavities and superbubbles have been recognised to be of key importance here. Also, constraints on the complex processes making stars explode as either thermonuclear or core-collapse supernovae are being illuminated by gamma-ray lines, in this case from shortlived radioactivities from 56Ni and 44Ti decays. In particular, the three-dimensionality and asphericities that have recently been recognised as important are enlightened in different ways through such gamma-ray line spectroscopy. Finally, the distribution of positron annihilation gamma ray emission with its puzzling bulge-dominated intensity disctribution is measured through spatially-resolved spectra, which indicate that annihilation conditions may differ in different parts of our Galaxy. But it is now understood that a variety of sources may feed positrons into the interstellar medium, and their characteristics largely get lost during slowing down and propagation of positrons before annihilation; a recent microquasar flare was caught as an opportunity to see positrons annihilate at a source.

  13. New Teff and [Fe/H] spectroscopic calibration for FGK dwarfs and GK giants

    CERN Document Server

    Teixeira, G D C; Tsantaki, M; Monteiro, M J P F G; Santos, N C; Israelian, G

    2016-01-01

    The ever-growing number of large spectroscopic survey programs has increased the importance of fast and reliable methods with which to determine precise stellar parameters. Some of these methods are highly dependent on correct spectroscopic calibrations. The goal of this work is to obtain a new spectroscopic calibration for a fast estimate of Teff and [Fe/H] for a wide range of stellar spectral types. We used spectra from a joint sample of 708 stars, compiled from 451 FGK dwarfs and 257 GK-giant stars. We used homogeneously determined spectroscopic stellar parameters to derive temperature calibrations using a set of selected EW line-ratios, and [Fe/H] calibrations using a set of selected FeI lines. We have derived 322 EW line-ratios and 100 FeI lines that can be used to compute Teff and [Fe/H], respectively. We show that these calibrations are effective for FGK dwarfs and GK-giant stars in the following ranges: 4500 K < Teff < 6500 K , 2.5 < logg < 4.9 dex, and -0.8 < [Fe/H] < 0.5 dex. The n...

  14. Fractionation of Fe isotopes during Fe(II) oxidation by a marine photoferrotroph is controlled by the formation of organic Fe-complexes and colloidal Fe fractions

    Science.gov (United States)

    Swanner, Elizabeth D.; Wu, Wenfang; Schoenberg, Ronny; Byrne, James; Michel, F. Marc; Pan, Yongxin; Kappler, Andreas

    2015-09-01

    Much interest exists in finding mineralogical, organic, morphological, or isotopic biosignatures for Fe(II)-oxidizing bacteria (FeOB) that are retained in Fe-rich sediments, which could indicate the activity of these organisms in Fe-rich seawater, more common in the Precambrian Era. To date, the effort to establish a clear Fe isotopic signature in Fe minerals produced by Fe(II)-oxidizing metabolisms has been thwarted by the large kinetic fractionation incurred as freshly oxidized aqueous Fe(III) rapidly precipitates as Fe(III) (oxyhydr)oxide minerals at near neutral pH. The Fe(III) (oxyhydr)oxide minerals resulting from abiotic Fe(II) oxidation are isotopically heavy compared to the Fe(II) precursor and are not clearly distinguishable from minerals formed by FeOB isotopically. However, in marine hydrothermal systems and Fe(II)-rich springs the minerals formed are often isotopically lighter than expected considering the fraction of Fe(II) that has been oxidized and experimentally-determined fractionation factors. We measured the Fe isotopic composition of aqueous Fe (Feaq) and the final Fe mineral (Feppt) produced in batch experiment using the marine Fe(II)-oxidizing phototroph Rhodovulum iodosum. The δ56Feaq data are best described by a kinetic fractionation model, while the evolution of δ56Feppt appears to be controlled by a separate fractionation process. We propose that soluble Fe(III), and Fe(II) and Fe(III) extracted from the Feppt may act as intermediates between Fe(II) oxidation and Fe(III) precipitation. Based on 57Fe Mössbauer spectroscopy, extended X-ray absorption fine structure (EXAFS) spectroscopy, and X-ray total scattering, we suggests these Fe phases, collectively Fe(II/III)interm, may consist of organic-ligand bound, sorbed, and/or colloidal Fe(II) and Fe(III) mineral phases that are isotopically lighter than the final Fe(III) mineral product. Similar intermediate phases, formed in response to organic carbon produced by FeOB and inorganic

  15. Superconductivity in Fe-chalcogenides

    Energy Technology Data Exchange (ETDEWEB)

    Chang, C.C.; Chen, T.K. [Institute of Physics, Academia Sinica, Taipei, Taiwan (China); Lee, W.C. [Department of Physics, Applied Physics, and Astronomy, Binghamton University – SUNY (United States); Lin, P.H. [National Synchrotron Research Center, Hsinchu, Taiwan (China); Wang, M.J. [Institute of Astrophysics and Astronomy, Academia Sinica, Taipei, Taiwan (China); Wen, Y.C. [Institute of Physics, Academia Sinica, Taipei, Taiwan (China); Wu, P.M. [Deparment of Applied Physics and Geballe Laboratory for Advanced Materials, Stanford University, Stanford, CA (United States); Wu, M.K., E-mail: mkwu@mail.ndhu.edu.tw [Institute of Physics, Academia Sinica, Taipei, Taiwan (China); National Donghwa University, Hualien, Taiwan (China)

    2015-07-15

    FeSe, which has the simplest crystal structure among the Fe based superconductors, and related chalcogenide superconductors are ideal candidates for investigating the detailed mechanism of the iron-based superconductors. Here, we summarize recent studies on the Fe-chalcogenides, with the goal to address some unresolved questions such as what is the influence of chemical stoichiometry on the phase diagram, what is the exact parent phase of FeSe system, and why can T{sub c}s be so dramatically enhanced in FeSe based superconductors? Recent developments in novel synthesis to prepare chalcogenide crystals, nano-materials and thin films allow the community to begin to address these issues. Then we review physical properties of the Fe chalcogenides, specifically focusing on optical properties, scanning tunneling spectroscopy and angle-resolved photoemission spectroscopy (ARPES) results. These measurements along with recent theories provide a framework for better understanding the origin of superconductivity in FeSe and Fe-chalcogenides.

  16. Roles of Fe-Nx and Fe-Fe3C@C Species in Fe-N/C Electrocatalysts for Oxygen Reduction Reaction.

    Science.gov (United States)

    Kim, Jae Hyung; Sa, Young Jin; Jeong, Hu Young; Joo, Sang Hoon

    2017-03-22

    Iron and nitrogen codoped carbons (Fe-N/C) have emerged as promising nonprecious metal catalysts for the oxygen reduction reaction (ORR). While Fe-Nx sites have been widely considered as active species for Fe-N/C catalysts, very recently, iron and/or iron carbide encased with carbon shells (Fe-Fe3C@C) has been suggested as a new active site for the ORR. However, most of synthetic routes to Fe-N/C catalysts involve high-temperature pyrolysis, which unavoidably yield both Fe-Nx and Fe-Fe3C@C species, hampering the identification of exclusive role of each species. Herein, in order to establish the respective roles of Fe-Nx and Fe-Fe3C@C sites we rationally designed model catalysts via the phase conversion reactions of Fe3O4 nanoparticles supported on carbon nanotubes. The resulting catalysts selectively contained Fe-Nx, Fe-Fe3C@C, and N-doped carbon (C-Nx) sites. It was revealed that Fe-Nx sites dominantly catalyze ORR via 4-electron (4 e(-)) pathway, exerting a major role for high ORR activity, whereas Fe-Fe3C@C sites mainly promote 2 e(-) reduction of oxygen followed by 2 e(-) peroxide reduction, playing an auxiliary role.

  17. Studies of De-excited Spectra of Heavy Ions FeI and CuI at Low Energy

    Institute of Scientific and Technical Information of China (English)

    王友德; 杨治虎; 马新文; 徐谦; 刘惠萍; 赵孟春

    1994-01-01

    The de-excited spectra of FeI and CuI after the interaction of Fe+ and Cu+ ions with a carbon foil (8.5μg/cm2) have been investigated by using the Beam-foil(BF) technique at an incident energy of 110 keV.The measured lines in the spectra are mainly from de-excited atoms FeI and CuI.The lifetime of stronger lines,including seven lines of FeI and three lines of CuI of the spectra are also measured.Some progress has been made in preparing foils with high quality and in adjusting the intensity of ion beams During measurements,the lifetime of carbon foil targets is more than 30 minutes.

  18. The Last Line Effect

    NARCIS (Netherlands)

    Beller, M.; Zaidman, A.E.; Karpov, A.

    2015-01-01

    Micro-clones are tiny duplicated pieces of code; they typically comprise only a few statements or lines. In this paper, we expose the “last line effect,” the phenomenon that the last line or statement in a micro-clone is much more likely to contain an error than the previous lines or statements. We

  19. The Language of Lines.

    Science.gov (United States)

    Breig-Allen, Cheryl; Hill, Janet; Geismar-Ryan, Lori; Cadwell, Louise Boyd

    1998-01-01

    Describes a project about lines in the environment used with 2- and 3-year olds and based on the Reggio Emilia approach. Activities included making tracks with riding toys, drawing lines on papers, seeing cloud lines, and making lines with yarn and Cuisenaire rods. Shows how young children's observations and ongoing discoveries can uncover their…

  20. Dolo y mala fe

    Directory of Open Access Journals (Sweden)

    Carlos Arturo Gómez Pavajeau

    2010-12-01

    Full Text Available Se ha dicho por grandes penalistas que las tesis en nuestra disciplina son una eterna vuelta al pasado. Empero, debe constatarse, que ello se ha dicho en un sentido de lo clásico: una vuelta a lo que resulta digno de admirar en cualquier época, toda vez que las experiencias históricas negativas nos previenen de repetir el pasado, razón fundamental por la cual debemos conocerlo. En este escrito pretendemos mostrar cómo algunas tendencias actuales nos indican que épocas nefastas ya superadas pueden repetirse, lo cual particularmente sucede tanto con la noción de dolo como con la de mala fe, concepto que de imponerse destruiría, a la manera como se derrumba un castillo de naipes, el sólido edificio dogmático construido por el Derecho penal liberal.

  1. Lines of Blaschko.

    Science.gov (United States)

    Bolognia, J L; Orlow, S J; Glick, S A

    1994-08-01

    The lines of Blaschko represent a pattern followed by many skin disorders. We review the clinical and histologic features of X-linked, congenital/nevoid, and acquired skin diseases that follow these lines. We also include cutaneous disorders that have a linear distribution but do not follow Blaschko's lines. Finally, we differentiate Blaschko's lines from other patterns on the skin such as dermatomes and Langer's lines.

  2. SPECTRAL OPTICAL MONITORING OF THE NARROW-LINE SEYFERT 1 GALAXY Ark 564

    Energy Technology Data Exchange (ETDEWEB)

    Shapovalova, A. I.; Burenkov, A. N. [Special Astrophysical Observatory of the Russian AS, Nizhnij Arkhyz, Karachaevo-Cherkesia 369167 (Russian Federation); Popovic, L. C.; Kovacevic, J. [Astronomical Observatory, Volgina 7, 11160 Belgrade 74 (Serbia); Chavushyan, V. H.; Valdes, J. R.; Torrealba, J.; Carrasco, L. [Instituto Nacional de Astrofisica, Optica y Electronica, Apartado Postal 51-216, 72000 Puebla (Mexico); Ilic, D.; Kovacevic, A. [Isaac Newton Institute of Chile, Yugoslavia Branch, Belgrade (Serbia); Kollatschny, W. [Institut fuer Astrophysik, Georg-August-Universitaet, Goettingen (Germany); Bochkarev, N. G. [Sternberg Astronomical Institute, Moscow (Russian Federation); Leon-Tavares, J. [Aalto University Metsaehovi Radio Observatory, Metsaehovintie 114, FIN-02540 Kylmaelae (Finland); Mercado, A. [Universidad Politecnica de Baja California, Av. de la Industria 291, 21010 Mexicali, B.C. (Mexico); Benitez, E.; Dultzin, D. [Instituto de Astronomia, Universidad Nacional Autonoma de Mexico, Apartado Postal 70-264, Mexico, D.F. 04510 (Mexico); De la Fuente, E., E-mail: ashap@sao.ru [Instituto de Astronomia y Meteorologia, Dpto. de Fisica CUCEI, Universidad de Guadalajara, Av. Vallarta 2602, 44130 Guadalajara, Jalisco (Mexico)

    2012-09-15

    We present the results of a long-term (1999-2010) spectral optical monitoring campaign of the active galactic nucleus (AGN) Ark 564, which shows a strong Fe II line emission in the optical. This AGN is a narrow-line Seyfert 1 (NLS1) galaxy, a group of AGNs with specific spectral characteristics. We analyze the light curves of the permitted H{alpha}, H{beta}, optical Fe II line fluxes, and the continuum flux in order to search for a time lag between them. Additionally, in order to estimate the contribution of iron lines from different multiplets, we fit the H{beta} and Fe II lines with a sum of Gaussian components. We find that during the monitoring period the spectral variation (F{sub max}/F{sub min}) of Ark 564 is between 1.5 for H{alpha} and 1.8 for the Fe II lines. The correlation between the Fe II and H{beta} flux variations is of higher significance than that of H{alpha} and H{beta} (whose correlation is almost absent). The permitted-line profiles are Lorentzian-like and do not change shape during the monitoring period. We investigate, in detail, the optical Fe II emission and find different degrees of correlation between the Fe II emission arising from different spectral multiplets and the continuum flux. The relatively weak and different degrees of correlations between permitted lines and continuum fluxes indicate a rather complex source of ionization of the broad-line emission region.

  3. Magnetic properties of Fe1-xMnx/Fe nanocomposites

    DEFF Research Database (Denmark)

    Anhøj, Thomas Aarøe; Jacobsen, Claus Schelde; Mørup, Steen

    2004-01-01

    We have prepared nanocomposites of mixtures of ferromagnetic alpha-Fe and antiferromagnetic gamma-Fe50Mn50 nanoparticles, and studied their magnetic and structural properties by magnetization measurements, Mössbauer spectroscopy, and x-ray diffraction. A sample consisting of a 1:1 mixture...... of the two materials showed enhanced coercivity, but almost negligible exchange bias at room temperature after field cooling from 520 K. However, samples with higher content of gamma-Fe50Mn50 showed significant exchange bias. The mechanisms for exchange bias and enhanced coercivity in the system...

  4. In Situ Characterization of CuFe2O4 and Cu/Fe3O4 Water-Gas Shift Catalysts

    Energy Technology Data Exchange (ETDEWEB)

    Estrella, M.; Barrio, L; Zhou, G; Wang, X; Wang, Q; Wen, W; Hanson, J; Frenkel, A; Rodriguez, J

    2009-01-01

    Mixtures of copper and iron oxides are used as industrial catalysts for the water-gas shift (WGS, CO + H2O f H2 + CO2). In-situ time-resolved X-ray diffraction, X-ray absorption fine structure, and atomic pair distribution function analysis were used to study the reduction of CuFe2O4 with CO and the behavior of CuFe2O4 and Cu/Fe2O3 catalysts under WGS reaction conditions. MetalToxygenTmetal interactions enhance the stability of Cu 2+ and Fe 3+ in the CuFe2O4 lattice, and the mixed-metal oxide is much more difficult to reduce than CuO or Fe2O3. Furthermore, after heating mixtures of CuFe2O4/CuO in the presence of CO or CO/H2O, the cations of CuO migrate into octahedral sites of the CuFe2O4 lattice at temperatures (200-250 C) in which CuO is not stable. Above 250 C, copper leaves the oxide, the occupancy of the octahedral sites in CuFe2O4 decreases, and diffraction lines for metallic Cu appear. From 350 to 450 C, there is a massive reduction of CuFe2O4 with the formation of metallic Cu and Fe3O4. At this point, the sample becomes catalytically active for the production of H2 from the reaction of H2O with CO. Neutral Cu 0 (i.e., no Cu 1+ or Cu 2+ cations) is the active species in the catalysts, but interactions with the oxide support cannot be neglected. These studies illustrate the importance of in situ characterization when dealing with mixed-metal oxide WGS catalysts.

  5. In-situ Characterization of CuFe2O4 and Cu/Fe3O4 Water-Gas Shift Catalysts

    Energy Technology Data Exchange (ETDEWEB)

    Rodriguez,J.A.; Estrella, M.; Barrio, L.; Zhou, G.; Wang, X.; Wang, Q.; Wen, W.; Hanson, J.C.; Frenkel, A.

    2009-08-13

    Mixtures of copper and iron oxides are used as industrial catalysts for the water-gas shift (WGS, CO + H2O → H2 + CO2). In-situ time-resolved X-ray diffraction, X-ray absorption fine structure, and atomic pair distribution function analysis were used to study the reduction of CuFe2O4 with CO and the behavior of CuFe2O4 and Cu/Fe2O3 catalysts under WGS reaction conditions. Metal↔oxygen↔metal interactions enhance the stability of Cu2+ and Fe3+ in the CuFe2O4 lattice, and the mixed-metal oxide is much more difficult to reduce than CuO or Fe2O3. Furthermore, after heating mixtures of CuFe2O4/CuO in the presence of CO or CO/H2O, the cations of CuO migrate into octahedral sites of the CuFe2O4 lattice at temperatures (200-250 oC) in which CuO is not stable. Above 250 oC, copper leaves the oxide, the occupancy of the octahedral sites in CuFe2O4 decreases, and diffraction lines for metallic Cu appear. From 350 to 450 oC, there is a massive reduction of CuFe2O4 with the formation of metallic Cu and Fe3O4. At this point, the sample becomes catalytically active for the production of H2 from the reaction of H2O with CO. Neutral Cu0 (i.e. no Cu+1 or Cu+2 cations) is the active species in the catalysts, but interactions with the oxide support are necessary in order to obtain high catalytic activity. These studies illustrate the importance of in-situ characterization when dealing with mixed-metal oxide WGS catalysts.

  6. Non-Lorentzian diffusion-broadened Mössbauer lines

    DEFF Research Database (Denmark)

    Heilmann, Ian; Olsen, Boye; Jensen, Jens Højgaard

    1974-01-01

    Non-Lorentzian diffusion-broadened Mossbauer lines are reported for two different systems: (i) SnO, particles in silicon grease; and (ii) Fe(C,H,O,), dissolved in 1,3-propanediol. Both results are discussed as superpositions of Lorentzians each representing a particular situation of a Mossbauer...

  7. Fe II Emission in 14 Low-Redshift Quasars. I. Observations

    Science.gov (United States)

    Tsuzuki, Yumihiko; Kawara, Kimiaki; Yoshii, Yuzuru; Oyabu, Shinki; Tanabé, Toshihiko; Matsuoka, Yoshiki

    2006-10-01

    We present the spectra of 14 quasars with a wide coverage of rest wavelengths from 1000 to 7300 Å. The redshift ranges from z=0.061 to 0.555 and the luminosity from MB=-22.69 to -26.32. These spectra of high quality result from combining Hubble Space Telescope spectra with those taken from ground-based telescopes. We describe the procedure of generating the template spectrum of Fe II line emission from the spectrum of a narrow-line Seyfert 1 galaxy, I Zw 1, that covers two wavelength regions of 2200-3500 and 4200-5600 Å. Our template Fe II spectrum is semiempirical in the sense that the synthetic spectrum calculated with the CLOUDY photoionization code is used to separate the Fe II emission from the Mg II λ2798 line. The procedure of measuring the strengths of Fe II emission lines is twofold: (1) subtracting the continuum components by fitting models of the power-law and Balmer continua in the continuum windows, which are relatively free from line emissions, and (2) fitting models of the Fe II emission based on the Fe II template to the continuum-subtracted spectra. From 14 quasars including I Zw 1, we obtained the Fe II fluxes in five wavelength bands (U1 [2200-2660 Å], U2 [2660-3000 Å], U3 [3000-3500 Å], O1 [4400-4700 Å], and O2 [5100-5600 Å]), the total flux of Balmer continuum, and the fluxes of Mg II λ2798, Hα, and other emission lines, together with the full widths at half-maximum (FWHMs) of these lines. Regression analysis was performed by assuming a linear relation between any two of these quantities. Eight correlations were found with a confidence level higher than 99%: (1) larger Mg II FWHM for larger Hα FWHM, (2) larger Γ for fainter MB, (3) smaller Mg II FWHM for larger Γ, (4) larger Mg II FWHM for smaller Fe II(O1)/Mg II, (5) larger MBH for smaller Γ, (6) larger MBH for smaller Fe II(O1)/Mg II, (7) larger [O III]/Hβ for larger Mg II FWHM, and (8) larger Fe II(O1)/Mg II for larger Fe II(O1)/Fe II(U1). The fact that six of these eight are

  8. Maturation of [FeFe]-hydrogenases: Structures and mechanisms

    Energy Technology Data Exchange (ETDEWEB)

    Nicolet, Yvain; Fontecilla-Camps, Juan C. [Laboratoire de Cristallographie et Cristallogenese des Proteines, Institut de Biologie Structurale J.P. Ebel, Universite Joseph Fourier, Grenoble, CNRS, UMR 5075, CEA, DSV/IBS, 41 rue J. Horowitz F-38027 Grenoble cedex 1 (France); Fontecave, Marc [Laboratoire de Chimie et Biologie des Metaux; Universite Joseph Fourier, Grenoble, CNRS, UMR 5249, CEA, DSV/iRTSV, 17 rue des Martyrs F-38054 Grenoble cedex 9 (France); College de France, 11 place Marcelin-Berthelot 75231 Paris cedex 05 (France)

    2010-10-15

    Maturation of [FeFe]-hydrogenases, consisting in the synthesis and assembly of a di-iron center with a dithiolate bridging ligand as well as CO and CN ligands, depends on the concerted action of three metalloproteins, HydE, HydF and HydG. HydE and HydG are ''Radical-SAM'' enzymes involved in the synthesis of the ligands. HydF is proposed to function as a scaffold protein in which the di-iron center is assembled before being transferred to the hydrogenase. Here we review the current knowledge regarding the structure of the three maturases and the mechanisms of synthesis and assembly of the di-iron center of [FeFe]-hydrogenases. (author)

  9. A study of ceramic-lined composite steel pipes prepared by SHS centrifugal-thermite process

    Directory of Open Access Journals (Sweden)

    Li Yuxin

    2016-01-01

    Full Text Available Al2O3 ceramic-lined steel pipe was produced by self-propagating high-temperature synthesis centrifugal thermite process (SHS C-T process from Fe2O3 and Al as the raw materials. The composition, phase separation and microstructures were investigated. The result showed the ceramic lined pipe is composed of the three main layers of various compositions, which were subsequently determined to be Fe layer, the transition layer and the ceramic layer. Fe layer is composed of austenite and ferrite, the transition layer consisted of Al2O3 ceramic and Fe, the ceramic layer consisted of the dendritic-shaped Al2O3 and the spinel-shaped structured FeAl2O4.

  10. Multi-epoch Spectropolarimetry of SN 2011fe

    CERN Document Server

    Milne, Peter A; Porter, Amber; Smith, Paul S; Smith, Nathan; Leising, Mark D; Jannuzi, Buell T; Green, E M

    2016-01-01

    We present multiple spectropolarimetric observations of the nearby Type Ia supernova (SN) 2011fe in M101, obtained before, during, and after the time of maximum apparent visual brightness. The excellent time coverage of our spectropolarimetry has allowed better monitoring of the evolution of polarization features than is typical, which has allowed us new insight into the nature of normal SNe Ia. SN 2011fe exhibits time-dependent polarization in both the continuum and strong absorption lines. At early epochs, red wavelengths exhibit a degree of continuum polarization of up to 0.4\\%, likely indicative of a mild asymmetry in the electron-scattering photosphere. This behavior is more common in sub-luminous SNe Ia than in normal events, such as SN2011fe. The degree of polarization across a collection of absorption lines varies dramatically from epoch to epoch. During the earliest epoch a $\\lambda$4600-5000 \\AA\\ complex of absorption lines shows enhanced polarization at a different position angle than the continuum...

  11. A Near-infrared Fluorescent Probe for Selective Simultaneous Detection of Fe2+ and CI- in Living Cells%A Near-infrared Fluorescent Probe for Selective Simultaneous Detection of Fe2+ and CI- in Living Cells

    Institute of Scientific and Technical Information of China (English)

    李平; 肖海滨; 唐波

    2012-01-01

    A naked-eyed chromo-near infrared fluorescent probe for simultaneous detection of Fe2+ and C1 has been developed, based on photoinduced electron transfer mechanism (PET). The fluorophore is cyanine (Cy-SO3), and the Fe2+ receptor is 4'-(aminomethylphenyl)-2,2',6',2"-terpyridine (Tpy). The probe responds linearly and rapidly to [Fe2+] and [C1 ] variations under physiological conditions and exhibits high sensitivity, good photostability, and excellent cell membrane permeability. The real-time imaging of cellular Fe2+ was achieved successfully in living HL-7702, HepG2, and RAW264.7 cell lines.

  12. Thickness of Santa Fe Group sediments in the Espanola Basin south of Santa Fe, New Mexico, as estimated from aeromagnetic data

    Science.gov (United States)

    Phillips, Jeffrey D.; Grauch, V.J.S.

    2004-01-01

    In the southern Espa?ola basin south of Santa Fe, New Mexico, weakly magnetic Santa Fe Group sediments of Oligocene to Pleistocene age, which represent the primary aquifers for the region, are locally underlain by moderately to strongly magnetic igneous and volcaniclastic rocks of Oligocene age. Where this relationship exists, the thickness of Santa Fe Group sediments, and thus the maximum thickness of the aquifers, can be estimated from quantitative analysis of high-resolution aeromagnetic data. These thickness estimates provide guidance for characterizing the ground-water resources in between scattered water wells in this area of rapid urban development and declining water supplies. This report presents one such analysis based on the two-step extended Euler method for estimating depth to magnetic sources. The results show the general form of a north-trending synclinal basin located between the Cerrillos Hills and Eldorado with northward thickening of Santa Fe Group sediments. The increase in thickness is gradual from the erosional edge on the south to a U-shaped Santa Fe embayment hinge line, north of which sediments thicken much more dramatically. Along the north-south basin axis, Santa Fe Group sediments thicken from 300 feet (91 meters) at the hinge line near latitude 35o32'30'N to 2,000 feet (610 meters) at the Cerrillos Road interchange at Interstate 25, north of latitude 35o36'N. The depth analysis indicates that, superimposed on this general synclinal form, there are many local areas where the Santa Fe Group sediments may be thickened by a few hundred feet, presumably due to erosional relief on the underlying Oligocene volcanic and volcaniclastic rocks. Some larger areas of greater apparent thickening occur where the presence of magnetic rocks directly underlying the Santa Fe Group is uncertain. Where magnetic rocks are absent beneath the Santa Fe Group, the thickness cannot be estimated from the aeromagnetic data.

  13. Spectral Optical Monitoring of the Narrow Line Seyfert 1 galaxy Ark 564

    CERN Document Server

    Shapovalova, A I; Burenkov, A N; Chavushyan, V H; Ilic, D; Kovacevic, A; Kollatschny, W; Kovacevic, J; Bochkarev, N G; Valdes, J R; Torrealba, J; Leon-Tavares, J; Mercado, A; Benitez, E; Carrasco, L; Dultzin, D; de la Fuente, E

    2012-01-01

    We present the results of a long-term (1999--2010) spectral optical monitoring campaign of the active galactic nucleus (AGN) Ark 564, which shows a strong Fe II line emission in the optical. This AGN is a narrow line Seyfert 1 (NLS1) galaxies, a group of AGNs with specific spectral characteristics. We analyze the light curves of the permitted Ha, Hb, optical Fe II line fluxes, and the continuum flux in order to search for a time lag between them. Additionally, in order to estimate the contribution of iron lines from different multiplets, we fit the Hb and Fe II lines with a sum of Gaussian components. We found that during the monitoring period the spectral variation (F_max/F_min) of Ark 564 was between 1.5 for Ha to 1.8 for the Fe II lines. The correlation between the Fe II and Hb flux variations is of higher significance than that of Ha and Hb (whose correlation is almost absent). The permitted-line profiles are Lorentzian-like, and did not change shape during the monitoring period. We investigated, in detai...

  14. [Determination of 22 Elements in Herb Tea by X-Ray Fluorescence Spectrometry].

    Science.gov (United States)

    Li, Dan; Ge, Liang-quan; Wang, Guang-xi; Lai, Wan-chang; Zhai, Juan; Chen, Lu

    2015-07-01

    N, Na, Mg, Al, Si, P, S, Cl, K, Ca, Ti, Cr, Mn, Fe, Ni, Cu, Zn, Br, Rb, Sr, Ba and Pb in herb tea were determined by X-ray fluorescence spectrometry with pressed powder pellets. The measuring conditions of target elements were investigated, including how to select its analytical line. In addition to Ba and Pb using L line, Kalpha line was selected for the rest. When the Compton scattered radiation of Rh Kalpha was measured, The X-ray tube voltage should be appropriately reduced, and the appropriate tube current should be selected. The matrix effect was corrected by empirical coefficient method and using scattered radiation (the Rayleigh scattered radiation of Rh Lalpha, the scattered background of 0.1876 nm wavelength position and the Compton scattered radiation of Rh Kalpha) as internal standard, and the spectral overlapping interference of some elements (N, Na, Ca, Ti, Mn, Sr and Ba) was corrected. For the target elements, the detection limit of this method was low, and its accuracy and precision were high. The results showed that there were abandon of elements in herb tea, of which different kinds had different components, even the same kind of herb tea with different source had some difference in element and content more or less, however, there was a lot of similarity between the features of its components. In a word, this method could achieve multi-element determination of herb tea, and it was simple in operation, low cost, rapid, and accurate.

  15. Scale heights and equivalent widths of the iron K-shell lines in the Galactic diffuse X-ray emission

    CERN Document Server

    Yamauchi, Shigeo; Nobukawa, Masayoshi; Uchiyama, Hideki; Koyama, Katsuji

    2016-01-01

    This paper reports the analysis of the X-ray spectra of the Galactic diffuse X-ray emission (GDXE) in the Suzaku archive. The fluxes of the Fe I K alpha (6.4 keV), Fe XXV,He alpha (6.7 keV) and Fe XXVI Ly alpha (6.97 keV) lines are separately determined. From the latitude distributions, we confirm that the GDXE is decomposed into the Galactic center (GCXE), the Galactic bulge (GBXE) and the Galactic ridge (GRXE) X-ray emissions. The scale heights (SHs) of the Fe XXV He alpha line of the GCXE, GBXE and GRXE are determined to be ~40, ~310 and ~140 pc, while those of the Fe I K alpha line are ~30, ~160 and ~70 pc, respectively. The mean equivalent widths (EWs) of the sum of the Fe XXV He alpha and Fe XXVI Ly alpha lines are ~750 eV, ~600 eV and ~550 eV, while those of the Fe I K alpha line are ~150~eV, ~60~eV and ~100~eV for the GCXE, GBXE and GRXE, respectively. The origin of the GBXE, GRXE and GCXE is separately discussed based on the new results of the SHs and EWs, in comparison with those of the Cataclysmic ...

  16. Effectiveness of FeEDDHA, FeEDDHMA, and FeHBED in Preventing Iron-Deficiency Chlorosis in Soybean

    NARCIS (Netherlands)

    Bin, Levi M.; Weng, Liping; Bugter, Marcel H.J.

    2016-01-01

    The performance of FeHBED in preventing Fe deficiency chlorosis in soybean (Glycine max (L.) Merr.) in comparison to FeEDDHA and FeEDDHMA was studied, as well as the importance of the ortho-ortho and ortho-para/rest isomers in defining the performance. To this end, chlorophyll production (SPAD),

  17. Effectiveness of FeEDDHA, FeEDDHMA, and FeHBED in Preventing Iron-Deficiency Chlorosis in Soybean

    NARCIS (Netherlands)

    Bin, Levi M.; Weng, Liping; Bugter, Marcel H.J.

    2016-01-01

    The performance of FeHBED in preventing Fe deficiency chlorosis in soybean (Glycine max (L.) Merr.) in comparison to FeEDDHA and FeEDDHMA was studied, as well as the importance of the ortho-ortho and ortho-para/rest isomers in defining the performance. To this end, chlorophyll production (SPAD),

  18. From Forbidden Coronal Lines to Meaningful Coronal Magnetic Fields

    CERN Document Server

    Judge, Philip G; Landi, Enrico

    2013-01-01

    We review methods to measure magnetic fields within the corona using the polarized light in magnetic-dipole (M1) lines. We are particularly interested in both the global magnetic-field evolution over a solar cycle, and the local storage of magnetic free energy within coronal plasmas. We address commonly held skepticisms concerning angular ambiguities and line-of-sight confusion. We argue that ambiguities are in principle no worse than more familiar remotely sensed photospheric vector-fields, and that the diagnosis of M1 line data would benefit from simultaneous observations of EUV lines. Based on calculations and data from eclipses, we discuss the most promising lines and different approaches that might be used. We point to the S-like [Fe {\\sc XI}] line (J=2 to J=1) at 789.2nm as a prime target line (for ATST for example) to augment the hotter 1074.7 and 1079.8 nm Si-like lines of [Fe {\\sc XIII}] currently observed by the Coronal Multi-channel Polarimeter (CoMP). Significant breakthroughs will be made possibl...

  19. Fe(3+) /SeO42(-) dual doped nano hydroxyapatite: A novel material for biomedical applications.

    Science.gov (United States)

    Alshemary, Ammar Z; Engin Pazarceviren, Ahmet; Tezcaner, Aysen; Evis, Zafer

    2017-02-02

    Dual ions substituted hydroxyapatite (HA) received attention from scientists and researchers in the biomedical field owing to their excellent biological properties. This paper presents a novel biomaterial, which holds potential for bone tissue applications. Herein, we have successfully incorporated ferric (Fe(3+) )/selenate (SeO42-) ions into the HA structure (Ca10-x-y Fey (PO4 )6-x (SeO4 )x (OH)2-x-y Oy ) (Fe-SeHA) through a microwave refluxing process. The Fe-SeHA materials were characterized by X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy, and field emission scanning electron microscopy (FESEM). XRD and FTIR analyses revealed that Fe-SeHA samples were phase pure at 900°C. FESEM images showed that formation of rod-like shaped particles was inhibited dramatically with increasing Fe(3+) amount. The Vickers hardness (HV) test showed that hardness values increased with increasing Fe(3+) concentrations. Optical spectra of Fe-SeHA materials contained broadband over (200-600) nm. In vitro degradation and bioactivity tests were conducted in simulated body fluid (SBF). The incorporation of Fe(3+) /SeO42- ions into the HA structure resulted in a remarkably higher degradation rate along with intense growth of apatite granules on the surface of the Fe-SeHA discs with Ca/P ratio of 1.35-1.47. In vitro protein adsorption assay was conducted in fetal bovine serum (FBS) and it was observed that the adsorption of serum proteins on Fe-SeHA samples significantly increased with increasing Fe(3+) concentration. In vitro cytotoxicity tests were performed with human fetal osteoblast (hFOB) cell line and the results demonstrated that hFOB cells attached and proliferated faster on the Fe-SeHA materials compared to pure HA showing that Fe-SeHA materials were cytocompatible. ALP activity and intracellular calcium of hFOB cells on 1Fe-SeHA discs were statistically higher than pure HA, suggesting that presence of Fe(3+) ion supported osteogenic differentiation of

  20. Moessbauer spectroscopy of Mg(0.9)Fe(0.1)SiO3 perovskite

    Science.gov (United States)

    Jeanloz, Raymond; O'Neill, Bridget; Pasternak, Moshe P.; Taylor, R. D.; Bohlen, Steven R.

    1992-01-01

    Ambient pressure Moessbauer spectra of Mg(0.9)Fe-57(0.1)SiO3 perovskite synthesized at pressure-temperature conditions of about 50 GPa and 1700 K show that the iron is entirely high-spin Fe(2+) and appears to be primarily located in the octahedral site within the crystal structure. We observe broad Moessbauer lines, suggesting a distribution of electric-field gradients caused by disorder associated with the Fe ions. Also, the perovskite exhibits magnetic ordering at temperatures lower than 5 K, implying that there is a magnetic contribution to the absolute ('third-law') entropy of this phase.

  1. VT Electric Transmission Line Corridors - corridor lines

    Data.gov (United States)

    Vermont Center for Geographic Information — (Link to Metadata) The ELTRN layer depicts electric transmission line corridors in Vermont. Various methods have been used to digitize features. The data layer...

  2. Peripheral intravenous line (image)

    Science.gov (United States)

    A peripheral intravenous line is a small, short plastic catheter that is placed through the skin into a vein, ... or foot, but occasionally in the head. A peripheral intravenous line is used to give fluids and ...

  3. Peripheral arterial line (image)

    Science.gov (United States)

    A peripheral arterial line is a small, short plastic catheter placed through the skin into an artery of the arm or leg. The purpose of a peripheral arterial line is to allow continuous monitoring of ...

  4. Near-IR [Fe II] emission diagnostics applied to cold disk winds in young stars

    CERN Document Server

    Pesenti, N; Cabrit, S; O'Brien, D; García, P; Ferreira, J

    2003-01-01

    We investigate the emissivity properties of the main near-IR transitions of the Fe+ ion in the conditions prevailing in the inner regions of jets from young stars, based on a simplified 16-level atom model. We present new diagnostic diagrams involving prominent near-IR line ratios that allow us to constrain the electronic density, temperature, and Fe gas phase abundance ratio, independently of the heating process. Comparison with recent near-IR observations of a sample of HH objects indicates gas phase Fe abundances ranging from 15-50 % up to 100 % of the solar value in agreement with the moderate depletions previously derived from optical line ratios or shock models. Hence, it appears that Fe-bearing dust is efficiently destroyed in stellar jets. We then use our Fe+ emissivity model to predict near-IR [Fe II] emission maps for self-similar, cold MHD disk wind models. We show that observations in [Fe II] with AMBER on the VLTI could severely constrain the MHD solution and the inner launch radius of the jet. W...

  5. Calculated oscillation periods of the interlayer coupling in Fe/Cr/Fe and Fe/Mo/Fe sandwiches

    DEFF Research Database (Denmark)

    Mirbt, S.; Niklasson, A.M.N.; Johansson, B.

    1996-01-01

    We have performed an ab initio study of the oscillation periods of the interlayer coupling in sandwiches of [100] layers of body centered cubic Cr, respectively, Mo, with up to 20 monolayers thickness embedded in an Fe host. Our derived values for the oscillation periods of the interlayer coupling...... the influence of the lattice constant on the interlayer coupling and also the dependence of the interlayer coupling amplitude on the Fe magnetic moment....

  6. Nebular spectra and abundance tomography of the type Ia supernova SN 2011fe: a normal SN Ia with a stable Fe core

    CERN Document Server

    Mazzali, P A; Filippenko, A V; Garnavich, P M; Clubb, K I; Maguire, K; Pan, Y -C; Shappee, R; Silverman, J M; Benetti, S; Hachinger, S; Nomoto, K; Pian, E

    2015-01-01

    A series of optical and one near-infrared nebular spectra covering the first year of the Type Ia supernova SN 2011fe are presented and modelled. The density profile that proved best for the early optical/ultraviolet spectra, "rho-11fe", was extended to lower velocities to include the regions that emit at nebular epochs. Model rho-11fe is intermediate between the fast deflagration model W7 and a low-energy delayed-detonation. Good fits to the nebular spectra are obtained if the innermost ejecta are dominated by neutron-rich, stable Fe-group species, which contribute to cooling but not to heating. The correct thermal balance can thus be reached for the strongest [FeII] and [FeIII] lines to be reproduced with the observed ratio. The 56Ni mass thus obtained is 0.47 +/- 0.05 Mo. The bulk of 56Ni has an outermost velocity of ~8500 km/s. The mass of stable iron is 0.23 +/- 0.03 Mo. Stable Ni has low abundance, ~10^{-2} Mo. This is sufficient to reproduce an observed emission line near 7400 A. A sub-Chandrasekhar exp...

  7. Open Verlinde line operators

    CERN Document Server

    Gaiotto, Davide

    2014-01-01

    We reformulate the action of Verlinde line operators on conformal blocks in a 3d TFT language and extend it to line operators labelled by open paths joining punctures on the Riemann surface. We discuss the possible applications of open Verlinde line operators to quantum Teichm\\"uller theory, supersymmetric gauge theory and quantum groups

  8. Lined canvas paintings

    DEFF Research Database (Denmark)

    Krarup Andersen, Cecil

    2013-01-01

    and tensile testing samples from the tacking edges as well as lined mock-up samples. The ability of the different lining techniques to support canvas paintings is evaluated in terms of their initial stretching and during fluctuations of relative humidity. Six different combinations of lining adhesives...

  9. On the emitting region of X-ray fluorescent lines around Compton-thick AGN

    CERN Document Server

    Liu, Jiren

    2016-01-01

    X-ray fluorescent lines are unique features of the reflection spectrum of the torus when irradiated by the central AGN. Their intrinsic line width can be used to probe the line-emitting region. Previous studies have focused on the Fe Ka line at 6.4 keV, which is the most prominent fluorescent line. These studies, however, are limited by the spectral resolution of currently available instruments, the best of which is $\\sim1860$ km s$^{-1}$ afforded by the Chandra High-Energy Grating (HEG). The HEG spectral resolution is improved by a factor of 4 at 1.74 keV, where the Si Ka line is located. We measured the FWHM of the Si Ka line for Circinus, Mrk 3, and NGC 1068, which are $570\\pm240$, $730\\pm320$, and $320\\pm280$ km s$^{-1}$, respectively. They are $3-5$ times smaller than those measured with the Fe Ka line previously. It shows that the intrinsic widths of the Fe Ka line are most likely to be over-estimated. The measured widths of the Si Ka line put the line-emitting region outside the dust sublimation radius...

  10. New Teff and [Fe/H] spectroscopic calibration for FGK dwarfs and GK giants

    Science.gov (United States)

    Teixeira, G. D. C.; Sousa, S. G.; Tsantaki, M.; Monteiro, M. J. P. F. G.; Santos, N. C.; Israelian, G.

    2016-10-01

    Context. The ever-growing number of large spectroscopic survey programs has increased the importance of fast and reliable methods with which to determine precise stellar parameters. Some of these methods are highly dependent on correct spectroscopic calibrations. Aims: The goal of this work is to obtain a new spectroscopic calibration for a fast estimate of Teff and [Fe/H] for a wide range of stellar spectral types. Methods: We used spectra from a joint sample of 708 stars, compiled from 451 FGK dwarfs and 257 GK-giant stars. We used homogeneously determined spectroscopic stellar parameters to derive temperature calibrations using a set of selected EW line-ratios, and [Fe/H] calibrations using a set of selected Fe I lines. Results: We have derived 322 EW line-ratios and 100 Fe I lines that can be used to compute Teff and [Fe/H], respectively. We show that these calibrations are effective for FGK dwarfs and GK-giant stars in the following ranges: 4500 K computer code, GeTCal, for automatically producing new calibration files based on any new sample of stars.

  11. Effects of Fe-deficient conditions on Fe uptake and utilization in P-efficient soybean.

    Science.gov (United States)

    Qiu, Wei; Dai, Jing; Wang, Nanqi; Guo, Xiaotong; Zhang, Xiaoli; Zuo, Yuanmei

    2017-03-01

    Phosphorus (P)-efficient soybean (Glycine max) plants absorb and utilize P with high efficiency. To investigate the effects of iron (Fe)-deficient conditions on the absorption and utilization of Fe in P-efficient soybean plants, two soybean cultivars with different P efficiency, the 03-3 (P-efficient variety) and Bd-2 (P-inefficient variety), were used in this study. The two soybean cultivars were grown in nutrient solution containing Fe concentrations of 0 (Fe0), 20 (Fe20), 40 (Fe40), or 80 (Fe80) μM for 7 days. The Fe reductase activity of roots was higher in 03-3 plants grown under the Fe0, Fe20, and Fe40 treatments than in Bd-2 plants and the total Fe uptake was greater in 03-3 plants under the Fe40 treatment. GmFRD3a was much more highly expressed in the stem of 03-3 than in that of Bd-2, and significantly more iron was transported to 03-3 plant shoots during Fe0 treatment. Chlorosis in young leaves caused by Fe deficiency under the Fe0 and Fe20 treatments was alleviated by increased Fe concentration in shoots. Increased levels of active Fe in young 03-3 leaves under Fe-deprivation conditions (Fe0) and maintenance of stable Fe concentrations in 03-3 shoots subjected to Fe20, Fe40, and Fe80 treatments suggested that the P-efficient 03-3 cultivar is also Fe-efficient. It is suggested that 03-3 soybean cultivar should be a good resource for application to farm field.

  12. Magneto-induced Line Broadening of Magneto-sensitive Lines in Solar Magnetized Atmospheres

    Institute of Scientific and Technical Information of China (English)

    Zhong-Quan Qu; Shuai Wang; Cheng-Lin Xu; Xiao-Yu Zhang; Ming-Guo Sun; Chun-Lan Jin

    2005-01-01

    We analyze the spectral line broadening of those magneto-sensitive lines in solar magnetized atmospheres. The broadening at the line wings is due to the increase of the effective width of energy levels involved in Zeeman splitting,and the broadening at the line core also originated in Zeeman splitting under the condition that the Zeeman components are mixed. Therefore, the magnetoinduced or Zeeman broadening take effects on the whole line. The observed Stokes parameter data in a sunspot and outside it acquired by Solar Stokes Spectrum Telescope (S3T) are analyzed for the demonstration of this mechanism, and the Zeeman broadening rates are calculated for FeI 6302.5 under some assumptions.Our result shows that the broadening is increased as the magnetic field strength becomes stronger, but the rate of increase at the line core is decreased as the field strength increases, while the rate at the wing does not show such an obvious regularity. The broadening is more effective in the line core than in the wings.

  13. Relativistic lines and reflection from the inner accretion disks around neutron stars

    NARCIS (Netherlands)

    Cackett, E.M.; Miller, J.M.; Ballantyne, D.R.; Barret, D.; Bhattacharyya, S.; Boutelier, M.; Miller, M.C.; Strohmayer, T.E.; Wijnands, R.

    2010-01-01

    A number of neutron star low-mass X-ray binaries (LMXBs) have recently been discovered to show broad, asymmetric Fe K emission lines in their X-ray spectra. These lines are generally thought to be the most prominent part of a reflection spectrum, originating in the inner part of the accretion disk w

  14. Magnetic field measurements in sunspots using spectral lines with different Lande factors

    Science.gov (United States)

    Lozitsky, V.; Osipov, S.

    2017-06-01

    Results of direct measurements of magnetic fields in sunspots are presented. Observations were carried out in June-July 2015 on Horizontal Solar Telescope AtsU-5 of Main Astronomical Observatory of National Academy of Science of Ukraine. Magnetic fields were measured by the Zeeman splitting of some spectral lines of FeI, MnI and NiI placed nearly FeI 5434.5 Å and FeI 6093.66 Å Effective Lande factors of these lines, geff, are in range from -0.22 - 2.14. Significant differences were found both for lines with different and closest values of geff. In some places of sunspots, FeI 5434.5 Å line (geff = -0.014) displays a realible splitting which corresponds to magnetic field strengths up to 2.5 kG. In all cases under study, FeI 6094.419 Å line with negative Lande factor (geff = -0.22) has the sign of splitting as a line with positive Lande factor (geff > 0). The possible reasons of this effect are discussed.

  15. [FeFe]-hydrogenase models assembled into vesicular structures.

    Science.gov (United States)

    Menzel, Kristin; Apfel, Ulf-Peter; Wolter, Nonio; Rüger, Ronny; Alpermann, Theodor; Steiniger, Frank; Gabel, Detlef; Förster, Stephan; Weigand, Wolfgang; Fahr, Alfred

    2014-03-01

    Compartmentalization is a major prerequisite for the origin of life on earth according to Wächtershäuser "Iron-Sulfur-World". The hypothesis is mainly based on an autocatalytic inorganic energy reproducing redox system consisting of iron and sulfur as requirement for the subsequent synthesis of complex organic structures. Here, we modified [FeFe]-hydrogenase models by means of covalent coupling to either oleic acid or the amphiphilic block copolymer polybutadiene-polyethyleneoxide (PB-PEO) and incorporated those into the membranes of vesicles composed of phospholipids (liposomes) or the unmodified amphiphilic polymer (polymersomes). We employed a [2Fe-2S] cluster as a hydrogenase model, since these structures are known to be suitable catalysts for the generation of H2 in the presence of weak acids. Successful incorporation was confirmed by spectrophotometric iron quantification and the vesicles formed were characterized by size determination (photon correlation spectroscopy (PCS)), and zeta potential as well as by cryo-transmission electron microscopy (Cryo-TEM). The modified models could be incorporated into liposomes or polymersomes up to molar proportions of 3.15% and 28%, respectively. Due to the immobilization in vesicular bilayers the [FeFe]-hydrogenase models can even exhibit catalytic action under the particular conditions of the intravesicular microenvironment. Our results suggest that the vesicular systems described may be applied as a nanoreactor for the reduction of encapsulated substances by generating hydrogen and thus as a minimal cell model.

  16. Isotopic fractionation associated with [NiFe]- and [FeFe]-hydrogenases

    Energy Technology Data Exchange (ETDEWEB)

    Yang, Hui; Gandhi, Hasand; Cornish, Adam J.; Moran, James J.; Kreuzer, Helen W.; Ostrom, Nathaniel; Hegg, Eric L.

    2016-01-30

    Hydrogenases catalyze the reversible formation of H2 from electrons and protons with high efficiency. Understanding the relationships between H2 production, H2 uptake, and H2-H2O exchange can provide insight into the metabolism of microbial communities in which H2 is an essential component in energy cycling. In this manuscript, we used stable H isotopes (1H and 2H) to probe the isotope effects associated with three [FeFe]-hydrogenases and three [NiFe]-hydrogenases. All six hydrogenases displayed fractionation factors for H2 formation that were significantly less than 1, producing H2 that was severely depleted in 2H relative to the substrate, water. Consistent with differences in their active site structure, the fractionation factors for each class appear to cluster, with the three [NiFe]-hydrogenases (α = 0.27-0.40) generally having smaller values than the three [FeFe]-hydrogenases (α = 0.41-0.55). We also obtained isotopic fractionation factors associated with H2 uptake and H2-H2O exchange under conditions similar to those utilized for H2 production, providing us with a more complete picture of the three reactions catalyzed by hydrogenases. The fractionation factors determined in our studies can be used as signatures for different hydrogenases to probe their activity under different growth conditions and to ascertain which hydrogenases are most responsible for H2 production and/or uptake in complex microbial communities.

  17. Si and Fe depletion in Galactic star-forming regions observed by the Spitzer Space Telescope

    CERN Document Server

    Okada, Yoko; Miyata, Takashi; Okamoto, Yoshiko K; Sakon, Itsuki; Shibai, Hiroshi; Takahashi, Hidenori

    2008-01-01

    We report the results of the mid-infrared spectroscopy of 14 Galactic star-forming regions with the high-resolution modules of the Infrared Spectrograph (IRS) on board the Spitzer Space Telescope. We detected [SiII] 35um, [FeII] 26um, and [FeIII] 23um as well as [SIII] 33um and H2 S(0) 28um emission lines. Using the intensity of [NII] 122um or 205um and [OI] 146um or 63um reported by previous observations in four regions, we derived the ionic abundance Si+/N+ and Fe+/N+ in the ionized gas and Si+/O0 and Fe+/O0 in the photodissociation gas. For all the targets, we derived the ionic abundance of Si+/S2+ and Fe2+/S2+ for the ionized gas. Based on photodissociation and HII region models the gas-phase Si and Fe abundance are suggested to be 3-100% and <8% of the solar abundance, respectively, for the ionized gas and 16-100% and 2-22% of the solar abundance, respectively, for the photodissociation region gas. Since the [FeII] 26um and [FeIII] 23um emissions are weak, the high sensitivity of the IRS enables to de...

  18. Cytotoxic, Genotoxic, and Neurotoxic Effects of Mg, Pb, and Fe on Pheochromocytoma (PC-12) Cells

    Science.gov (United States)

    Sanders, Talia; Liu, Yi-Ming; Tchounwou, Paul B.

    2014-01-01

    Metals such as lead (Pb), magnesium (Mg), and iron (Fe) are ubiquitous in the environment as a result of natural occurrence and anthropogenic activities. Although Mg, Fe and others are considered essential elements, high level of exposure has been associated with severe adverse health effects including cardiovascular, hematological, nephrotoxic, hepatotoxic, and neurologic abnormalities in humans. In the present study we hypothesized that Mg, Pb, and Fe are cytotoxic, genotoxic and neurotoxic, and their toxicity is mediated through oxidative stress and alteration in protein expression. To test the hypothesis, we used the pheochromocytoma (PC-12) cell line as a neuro cell model and performed the LDH assay for cell viability, Comet assay for DNA damage, Western blot for oxidative stress, and HPLC-MS to assess the concentration levels of neurological biomarkers such as glutamate, dopamine (DA), and 3-methoxytyramine (3-MT). The results of this study clearly show that Mg, Pb, and Fe, respectively in the form of MgSO4, Pb(NO3)2, FeCl2, and FeCl3 induce cytotoxicity, oxidative stress, and genotoxicity in PC-12 cells. In addition, exposure to these metallic compounds caused significant changes in the concentration levels of glutamate, dopamine, and 3-MT in PC-12 cells. Taken together the findings suggest that MgSO4, Pb(NO3)2, FeCl2, and FeCl3 have the potential to induce substantial toxicity to PC-12 cells. PMID:24942330

  19. Structure of Fe(III) precipitates generated by Fe(0) electrocoagulation in the presence of groundwater ions

    Science.gov (United States)

    van Genuchten, C. M.; Pena, J.; Addy, S. E.; Gadgil, A. J.

    2012-12-01

    -ranged atomic pair correlations as 2-line ferrihydrite (2LFH), rather than lepidocrocite (Lp) which is generated in an NaCl electrolyte. However, when Ca or Mg is added to oxyanion electrolytes, Fe-Fe polymerization and particle size both tend to increase and a Lp-like material with characteristic Fe-O and Fe-Fe pair correlations is once again favored. The presence of either Ca or Mg also enhances the removal P, As(V), and to a lesser extent, Si per mass of Fe. The analysis from EXAFS and PDF spectra provide new insights into the polyhedral connectivity of nanoscale oxyanion-bearing HFO formed under a wide range of chemical conditions, improving predictions of EC performance in the field and allowing for knowledge-based improvements in the design of future EC systems. Our PDF data also show that the most disordered EC precipitate samples (formed at high oxyanion/Fe ratios) all share a similar "backbone" of 3-4 peaks beyond the first 4 Å, regardless of the oxyanion present during synthesis. Using 2LFH as a reference, we index all atomic pair correlations throughout the coherently scattering structure of our disordered samples.

  20. Antitumor activity of 6-(cyclohexylamino)-1, 3-dimethyl-5(2-pyridyl)furo[2,3-d]pyrimidine-2,4(1H,3H)-dione and Its Ti(IV), Zn(II), Fe(III), and Pd(II) complexes on K562 and Jurkat cell lines.

    Science.gov (United States)

    Shabani, Fahmideh; Ghammamy, Shahriar; Mehrani, Khayroallah; Teimouri, Mohammad Bagher; Soleimani, Masoud; Kaviani, Saeid

    2008-01-01

    (6-(cyclohexylamino)-1,3-dimethyl-5(2-pyridyl)furo[2,3-d]pyrimidine-2,4(1H,3H)-dione) abbreviated as CDP was synthesized and characterized. Ti(IV), Zn(II), Fe(III), and Pd(II) metal complexes of this ligand are prepared by the reaction of salts of Ti(IV), Zn(II), Fe(III), and Pd(II) with CDP in acetonitrile. Characterization of the ligand and its complexes was made by microanalyses, FT-IR, (1)H NMR, (13)C NMR, and UV-Visible spectroscopy. All complexes were characterized by several techniques using elemental analysis (C, H, N), FT-IR, electronic spectra, and molar conductance measurements. The elemental analysis data suggest the stoichiometry to be 1:1 [M:L] ratio formation. The molar conductance measurements reveal the presence of 1:1 electrolytic nature complexes. These new complexes showed excellent antitumor activity against two kinds of cancer cells that are K562 (human chronic myeloid leukemia) cells and Jurkat (human T lymphocyte carcinoma) cells.

  1. Multi-wavelength study of the Seyfert 1 galaxy NGC 3783 with XMM-Newton

    CERN Document Server

    Blustin, A J; Behar, E; Kaastra, J S; Kahn, S M; Page, M J; Sako, M; Steenbrugge, K C

    2002-01-01

    We present the analysis of multi-wavelength XMM-Newton data from the Seyfert galaxy NGC 3783, including UV imaging, X-ray and UV lightcurves, the 0.2-10 keV X-ray continuum, the iron K-alpha emission line, and high-resolution spectroscopy and modelling of the soft X-ray warm absorber. The 0.2-10 keV spectral continuum can be well reproduced by a power-law at higher energies; we detect a prominent Fe K-alpha emission line, with both broad and narrow components, and a weaker emission line at 6.9 keV which is probably a combination of Fe K-beta and Fe XXVI. We interpret the significant deficit of counts in the soft X-ray region as being due to absorption by ionised gas in the line of sight. This is demonstrated by the large number of narrow absorption lines in the RGS spectrum from iron, oxygen, nitrogen, carbon, neon, argon, magnesium, silicon and sulphur. The wide range of iron states present in the spectrum enables us to deduce the ionisation structure of the absorbing medium. We find that our spectrum contai...

  2. Effect of phosphate, silicate, and Ca on the morphology, structure and elemental composition of Fe(III)-precipitates formed in aerated Fe(II) and As(III) containing water

    Science.gov (United States)

    Kaegi, Ralf; Voegelin, Andreas; Folini, Doris; Hug, Stephan J.

    2010-10-01

    We investigated Fe(III)-precipitates formed from Fe(II) oxidation in water at pH 7 as a function of dissolved Fe(II), As(III), phosphate, and silicate in the absence and presence of Ca. We used transmission electron microscopy (TEM), including selected area electron diffraction (SAED) and energy dispersive X-ray spectroscopy (EDX) to characterize the morphology, structure and elemental composition of the precipitates. Results from our companion X-ray absorption spectroscopy (XAS) study suggested that the oxidation of Fe(II) leads to the sequential formation of distinct polymeric units in the following order: Fe(III)-phosphate oligomers in the presence of phosphate, silicate-rich hydrous ferric oxide (HFO-Si) at high Si/Fe (>0.5) or 2-line ferrihydrite (2L-Fh) at lower Si/Fe (˜0.1-0.5), and lepidocrocite (Lp) in the absence of phosphate at low Si/Fe (arrangement of the different polymeric units within Fe(III)-precipitates. The resulting structural and compositional heterogeneity of short-range-ordered Fe(III)-precipitates likely affects their colloidal stability and their chemical reactivity and needs to be considered when addressing the fate of co-transformed trace elements such as arsenic.

  3. Suzaku observation of IRAS 00521-7054, a peculiar type-II AGN with a very broad feature at 6 keV

    CERN Document Server

    Ricci, Claudio; Ueda, Yoshihiro; Paltani, Stephane; Boissay, Rozenn; Terashima, Yuichi

    2014-01-01

    IRAS 00521$-$7054 is the first Seyfert 2 in which the presence of an extremely large Fe K$\\alpha$ line has been claimed. We report here on the analysis of a 100 ks Suzaku observation of the source. We confirm the existence of a very strong excess over the power-law X-ray continuum at $E\\sim6$ keV ($EW\\simeq 800$ eV), extending down to $\\sim 4.5$ keV, and found that the X-ray spectrum of the source can be explained by two different models. i) An absorption scenario, in which the X-ray source is obscured by two fully-covering ionized absorbers, with a strong reflection component from neutral material ($R\\sim 1.7$), a black body component and four narrow Gaussian lines (corresponding to Fe K$\\alpha$, Fe K$\\beta$, Fe xxv and Fe xxvi). ii) A reflection scenario, in which the X-ray spectrum is dominated by an obscured ($\\log N_{\\rm\\,H}\\sim 22.9$) blurred reflection produced in an ionized disk around a rotating supermassive black hole with a spin of $a \\geq 0.73$, and affected by light-bending ($R\\sim 2.7$), plus tw...

  4. Magnetic properties of Fe/NiO/Fe(001) trilayers

    Energy Technology Data Exchange (ETDEWEB)

    Biagioni, P. [INFM - Dipartimento di Fisica, Politecnico di Milano, Piazza Leonardo da Vinci 32, 20133 Milan (Italy)]. E-mail: paolo.biagioni@polimi.it; Brambilla, A. [INFM - Dipartimento di Fisica, Politecnico di Milano, Piazza Leonardo da Vinci 32, 20133 Milan (Italy); Portalupi, M. [INFM - Dipartimento di Fisica, Politecnico di Milano, Piazza Leonardo da Vinci 32, 20133 Milan (Italy); Lawrence Berkeley National Laboratory, Berkeley, CA 94720 (United States); Rougemaille, N. [Lawrence Berkeley National Laboratory, Berkeley, CA 94720 (United States); Schmid, A.K. [Lawrence Berkeley National Laboratory, Berkeley, CA 94720 (United States); Lanzara, A. [Lawrence Berkeley National Laboratory, Berkeley, CA 94720 (United States); Department of Physics, University of California at Berkeley, Berkeley, CA 94720 (United States); Vavassori, P. [INFM - Dipartimento di Fisica, Universita di Ferrara, Via Paradiso 12, 44100 Ferrara (Italy); Zani, M. [INFM - Dipartimento di Fisica, Politecnico di Milano, Piazza Leonardo da Vinci 32, 20133 Milan (Italy); Finazzi, M. [INFM - Dipartimento di Fisica, Politecnico di Milano, Piazza Leonardo da Vinci 32, 20133 Milan (Italy); Duo, L. [INFM - Dipartimento di Fisica, Politecnico di Milano, Piazza Leonardo da Vinci 32, 20133 Milan (Italy); Ciccacci, F. [INFM - Dipartimento di Fisica, Politecnico di Milano, Piazza Leonardo da Vinci 32, 20133 Milan (Italy)

    2005-04-15

    We have investigated the magnetic properties of epitaxially grown Fe/NiO/Fe(001) trilayers, for different thicknesses of the NiO spacer. Magneto Optical Kerr Effect has been exploited to study the in-plane magnetization reversal processes in the iron layers. We found that the NiO thickness t{sub AFM} has a critical value t{sub C} for the magnetic coupling between the Fe layers: for t{sub AFM}

  5. Charge Exchange-induced X-Ray Emission of Fe xxv and Fe xxvI via a Streamlined Model

    Science.gov (United States)

    Mullen, P. D.; Cumbee, R. S.; Lyons, D.; Stancil, P. C.

    2016-06-01

    Charge exchange (CX) is an important process for the modeling of X-ray spectra obtained by the Chandra, XMM-Newton, and Suzaku X-ray observatories, as well as the anticipated Astro-H mission. The understanding of the observed X-ray spectra produced by many astrophysical environments is hindered by the current incompleteness of available atomic and molecular data—especially for CX. Here, we implement a streamlined program set that applies quantum defect methods and the Landau-Zener theory to generate total, n-resolved, and n{\\ell }S-resolved cross sections for any given projectile ion/target CX collision. By using these data in a cascade model for X-ray emission, theoretical spectra for such systems can be predicted. With these techniques, Fe25+ and Fe26+ CX collisions with H, He, H2, N2, H2O, and CO are studied for single-electron capture (SEC). These systems have been selected because they illustrate computational difficulties for high projectile charges. Furthermore, Fe xxv and Fe xxvi emission lines have been detected in the Galactic center and Galactic ridge. Theoretical X-ray spectra for these collision systems are compared to experimental data generated by an electron-beam ion trap study. Several ℓ-distribution models have been tested for Fe25+ and Fe26+ SEC. Such analyses suggests that commonly used ℓ-distribution models struggle to accurately reflect the true distribution of electron capture as understood by more advanced theoretical methods.

  6. Departure of high temperature iron lines from the equilibrium state in flaring solar plasmas

    CERN Document Server

    Kawate, Tomoko; Jess, David B

    2016-01-01

    The aim of this study is to clarify if the assumption of ionization equilibrium and a Maxwellian electron energy distribution is valid in flaring solar plasmas. We analyze the 2014 December 20 X1.8 flare, in which the \\ion{Fe}{xxi} 187~\\AA, \\ion{Fe}{xxii} 253~\\AA, \\ion{Fe}{xxiii} 263~\\AA\\ and \\ion{Fe}{xxiv} 255~\\AA\\ emission lines were simultaneously observed by the EUV Imaging Spectrometer onboard the Hinode satellite. Intensity ratios among these high temperature Fe lines are compared and departures from isothermal conditions and ionization equilibrium examined. Temperatures derived from intensity ratios involving these four lines show significant discrepancies at the flare footpoints in the impulsive phase, and at the looptop in the gradual phase. Among these, the temperature derived from the \\ion{Fe}{xxii}/\\ion{Fe}{xxiv} intensity ratio is the lowest, which cannot be explained if we assume a Maxwellian electron distribution and ionization equilibrium, even in the case of a multi-thermal structure. This re...

  7. Neutron quantum well states in Fe/Co/Fe trilayers

    Science.gov (United States)

    Feygenson, M.; Toperverg, B. P.; Rücker, U.; Kentzinger, E.; Brückel, Th.

    2004-07-01

    We report on neutron quantum well states in Fe/Co/Fe trilayers, in which the reflection potential exhibits a quantum well for both spin states of the neutron. It is shown, that the resonance state in such a system exists and manifests itself as a dip in the reflectivity plateau below the critical angle of total reflection. The range of trilayer parameters was numerically analyzed to find optimal experimental conditions for the enhancement of the neutron wave field in the Co spacer. Enhancement of the wave field by a resonance is suggested as a way to substantially increase the off-specular scattering signal from lateral domains in buried layers of Co.

  8. Neutron quantum well states in Fe/Co/Fe trilayers

    Energy Technology Data Exchange (ETDEWEB)

    Feygenson, M.; Toperverg, B.P.; Ruecker, U.; Kentzinger, E.; Brueckel, Th

    2004-07-15

    We report on neutron quantum well states in Fe/Co/Fe trilayers, in which the reflection potential exhibits a quantum well for both spin states of the neutron. It is shown, that the resonance state in such a system exists and manifests itself as a dip in the reflectivity plateau below the critical angle of total reflection. The range of trilayer parameters was numerically analyzed to find optimal experimental conditions for the enhancement of the neutron wave field in the Co spacer. Enhancement of the wave field by a resonance is suggested as a way to substantially increase the off-specular scattering signal from lateral domains in buried layers of Co.

  9. X-ray spectral analysis of the low-luminosity active galactic nucleus NGC 7213 using long XMM-Newton observations

    CERN Document Server

    Emmanoulopoulos, D; Nicastro, F; McHardy, I M

    2012-01-01

    We present the X-ray spectral results from the longest X-ray multi-mirror mission-Newton observation, 133 ks, of the low luminosity active galactic nucleus NGC 7213. The hardness ratio analysis of the X-ray light curves discloses a rather constant X-ray spectral shape, at least for the observed exposure time, enabling us to perform X-ray spectral studies using the total observed spectrum. Apart from a neutral Fe K\\alpha emission line, we also detect narrow emission lines from the ionised iron species, Fe xxv and Fe xxvi. Our analysis suggests that the neutral Fe K\\alpha originates from a Compton-thin reflector, while the gas responsible for the high ionisation lines is collisionally excited. The overall spectrum, in the 0.3-10 keV energy band, registered by the European Photon Imaging Camera, can be modelled by a power-law component (with a slope of \\Gamma\\simeq1.9) plus two thermal components at 0.36 and 8.84 keV. The low-energy thermal component is entirely consistent with the X-ray spectral data obtained b...

  10. Influence of an Fe cap layer on the structural and magnetic properties of Fe49Pt51/Fe bi-layers

    Institute of Scientific and Technical Information of China (English)

    Duan Chao-Yang; Ma Bin; Wei Fu-Lin; Zhang zong-Zhi; Jin Qing-Yuan

    2009-01-01

    The influences of an Fe cap layer on the structural and magnetic properties of FePt/Fe bi-layers are investigated.Compared with single FePt alloy films, a thin Fe layer can affect the crystalline orientation and improve the chemical ordering of L10 FePt films. Moreover, the coercivity increases when a thin Fe layer covers the FePt layer. Beyond a critical thickness, however, the Fe cover layer quickens the magnetization reversal of Fe49Pt51/Fe bi-layers by their exchange coupling.

  11. High energy beam lines

    Science.gov (United States)

    Marchetto, M.; Laxdal, R. E.

    2014-01-01

    The ISAC post accelerator comprises an RFQ, DTL and SC-linac. The high energy beam lines connect the linear accelerators as well as deliver the accelerated beams to two different experimental areas. The medium energy beam transport (MEBT) line connects the RFQ to the DTL. The high energy beam transport (HEBT) line connects the DTL to the ISAC-I experimental stations (DRAGON, TUDA-I, GPS). The DTL to superconducting beam (DSB) transport line connects the ISAC-I and ISAC-II linacs. The superconducting energy beam transport (SEBT) line connects the SC linac to the ISAC-II experimental station (TUDA-II, HERACLES, TIGRESS, EMMA and GPS). All these lines have the function of transporting and matching the beams to the downstream sections by manipulating the transverse and longitudinal phase space. They also contain diagnostic devices to measure the beam properties.

  12. Effects of metal ions on the reactivity and corrosion electrochemistry of Fe/FeS nanoparticles.

    Science.gov (United States)

    Kim, Eun-Ju; Kim, Jae-Hwan; Chang, Yoon-Seok; Turcio-Ortega, David; Tratnyek, Paul G

    2014-04-01

    Nano-zerovalent iron (nZVI) formed under sulfidic conditions results in a biphasic material (Fe/FeS) that reduces trichloroethene (TCE) more rapidly than nZVI associated only with iron oxides (Fe/FeO). Exposing Fe/FeS to dissolved metals (Pd(2+), Cu(2+), Ni(2+), Co(2+), and Mn(2+)) results in their sequestration by coprecipitation as dopants into FeS and FeO and/or by electroless precipitation as zerovalent metals that are hydrogenation catalysts. Using TCE reduction rates to probe the effect of metal amendments on the reactivity of Fe/FeS, it was found that Mn(2+) and Cu(2+) decreased TCE reduction rates, while Pd(2+), Co(2+), and Ni(2+) increased them. Electrochemical characterization of metal-amended Fe/FeS showed that aging caused passivation by growth of FeO and FeS phases and poisoning of catalytic metal deposits by sulfide. Correlation of rate constants for TCE reduction (kobs) with electrochemical parameters (corrosion potentials and currents, Tafel slopes, and polarization resistance) and descriptors of hydrogen activation by metals (exchange current density for hydrogen reduction and enthalpy of solution into metals) showed the controlling process changed with aging. For fresh Fe/FeS, kobs was best described by the exchange current density for activation of hydrogen, whereas kobs for aged Fe/FeS correlated with electrochemical descriptors of electron transfer.

  13. Electrocatalytic activity of porous nanostructured Fe/Pt-Fe electrode for methanol electrooxidation in alkaline media

    Institute of Scientific and Technical Information of China (English)

    Javad Hosseini; Mehdi Abdolmaleki; Hamid Reza Pouretedal; Mohammad Hossein Keshavarz

    2015-01-01

    An electrochemical approach to fabricate a nanostructured Fe/Pt-Fe catalyst through electrodepo-sition followed by galvanic replacement is presented. An Fe/Pt-Fe nanostructured electrode was prepared by deposition of Fe-Zn onto a Fe electrode surface, followed by replacement of the Zn by Pt at open-circuit potential in a Pt-containing alkaline solution. Scanning electron microscopy and energy-dispersive X-ray techniques reveal that the Fe/Pt-Fe electrode is porous and contains Pt. The electrocatalytic activity of the Fe/Pt-Fe electrode for oxidation of methanol was examined by cyclic voltammetry and chronoamperometry. The electrooxidation current on the Fe/Pt-Fe catalyst is much higher than that on flat Pt and smooth Fe catalysts. The onset potential and peak potential on the Fe/Pt-Fe catalyst are more negative than those on flat Pt and smooth Fe electrodes for methanol electrooxidation. All results show that this nanostructured Fe/Pt-Fe electrode is very attractive for integrated fuel cell applications in alkaline media.

  14. Series Transmission Line Transformer

    Science.gov (United States)

    Buckles, Robert A.; Booth, Rex; Yen, Boris T.

    2004-06-29

    A series transmission line transformer is set forth which includes two or more of impedance matched sets of at least two transmissions lines such as shielded cables, connected in parallel at one end ans series at the other in a cascading fashion. The cables are wound about a magnetic core. The series transmission line transformer (STLT) which can provide for higher impedance ratios and bandwidths, which is scalable, and which is of simpler design and construction.

  15. Covariant electromagnetic field lines

    Science.gov (United States)

    Hadad, Y.; Cohen, E.; Kaminer, I.; Elitzur, A. C.

    2017-08-01

    Faraday introduced electric field lines as a powerful tool for understanding the electric force, and these field lines are still used today in classrooms and textbooks teaching the basics of electromagnetism within the electrostatic limit. However, despite attempts at generalizing this concept beyond the electrostatic limit, such a fully relativistic field line theory still appears to be missing. In this work, we propose such a theory and define covariant electromagnetic field lines that naturally extend electric field lines to relativistic systems and general electromagnetic fields. We derive a closed-form formula for the field lines curvature in the vicinity of a charge, and show that it is related to the world line of the charge. This demonstrates how the kinematics of a charge can be derived from the geometry of the electromagnetic field lines. Such a theory may also provide new tools in modeling and analyzing electromagnetic phenomena, and may entail new insights regarding long-standing problems such as radiation-reaction and self-force. In particular, the electromagnetic field lines curvature has the attractive property of being non-singular everywhere, thus eliminating all self-field singularities without using renormalization techniques.

  16. Iron line profiles in Suzaku spectra of bare Seyfert galaxies

    CERN Document Server

    Patrick, A R; Porquet, D; Markowitz, A G; Lobban, A P; Terashima, Y

    2010-01-01

    We methodically model the broad-band Suzaku spectra of a small sample of six 'bare' Seyfert galaxies: Ark 120, Fairall 9, MCG-02-14-009, Mrk 335, NGC 7469 and SWIFT J2127.4+5654. The analysis of bare Seyferts allows a consistent and physical modelling of AGN due to a weak amount of any intrinsic warm absorption, removing the degeneracy between the spectral curvature due to warm absorption and the red-wing of the Fe K region. Through effective modelling of the broad-band spectrum and investigating the presence of narrow neutral or ionized emission lines and reflection from distant material, we obtain an accurate and detailed description of the Fe K line region using models such as laor, kerrdisk and kerrconv. Results suggest that ionized emission lines at 6.7 keV and 6.97 keV (particularly Fe XXVI) are relatively common and the inclusion of these lines can greatly affect the parameters obtained with relativistic models i.e. spin, emissivity, inner radius of emission and inclination. Moderately broad components...

  17. Preparation of magnetic recoverable nanosize Cu-Fe2O3/Fe photocatalysts.

    Science.gov (United States)

    Kang, Hsu-Ya; Wang, H Paul

    2013-07-02

    Iron based catalysts generally have the advantage of the easily operated magnetically recovery from application sites. In the present work, paramagnetic iron and copper core-shell nanoparticles having the iron fractions (X(Fe) = Fe/(Cu+Fe)) of 0.33-1.0 were prepared and characterized by in situ synchrotron X-ray absorption and scattering spectroscopy. During the temperature-programmed carbonization (TPC) of Cu(2+)- and Fe(3+)-β-cyclodextrin (CD) complexes, a rapid reduction of Cu(II) occurs at about 453 K together with a growth of the metallic copper (Cu). Iron proceeds in the distinct growth path. At 453-513 K, the Fe(III) → Fe(II) → Fe consecutive reduction is observed. The unreduced Fe(III) (7-13%) is coated on the surfaces of the Fe nanoparticles (as Fe2O3/Fe). Growth of the Fe nanoparticle is inhibited by the surface Fe2O3, while the steady growth in Cu is observed. The Cu has a size range of 14-18 nm in diameter, compared to the small Fe2O3/Fe ones (3-6 nm). Under the UV-visible light irradiation for four hours, methylene blue can be photocatalytically degraded (>90%) by the (Cu-Fe2O3/Fe)@C. The (Cu-Fe2O3/Fe)@C photocatalysts can effectively oxidize dye molecules, providing a promising alternative for dye degradation using solar energy. Recovery of the (Cu-Fe2O3/Fe)@C photocatalysts can be attained by applying external magnetic field to trap the ferromagnetic Cu-Fe2O3/Fe nanoparticles, which suggests an economically attractive process, especially applied in photocatalytic degradation of dye-contaminated wastewater.

  18. Cytotoxicity and genotoxicity of GO-Fe3O4 hybrid in cultured mammalian cells

    Directory of Open Access Journals (Sweden)

    Jedrzejczak-Silicka Magdalena

    2017-03-01

    Full Text Available The study was aimed at investigating the effect of the Fe3O4 hybrid deposited on graphene oxide (GO-Fe3O4 on the relative viability and DNA integrity. The properties of the GO-Fe3O4 hybrid were analyzed using a transmission electron microscopy (TEM, X-ray diffraction technique (XRD and thermal gravimetric method (TGA, while the efficiency of graphene oxide covalent functionalization with iron oxide nanospheres was determined by Fourier transform infrared spectroscopy (FT-IR. L929 and MCF-7 cell lines were selected to analyze the biocompatibility of GO-Fe3O4 nanoparticles. The hybrid was tested using WST-1 and LDH leakage assays. DNA integrity was analyzed by agarose gel electrophoresis and micronucleus assay was performed to examine chromosomal damage in the exposed cell lines. The tested GO-Fe3O4 hybrid did not significantly reduce cell metabolism of L929 cells. GO-Fe3O4 hybrid particles only slightly affected the integrity of cell membranes. DNA integrity and micronucleus assays did not indicate genotoxicity of the hybrid.

  19. Direct Measurement of the Metastable Liquid Miscibility Gap in Fe-Co-Cu Ternary Alloy System

    Institute of Scientific and Technical Information of China (English)

    CAO Chong-De; Georg P.G(O)RLER

    2005-01-01

    @@ The metastable liquid-liquid phase separation in undercooled Fe-Co-Cu ternary alloy melts (XCu = 0.10-0.84;XCo:XFe = 1:3,1:1 and 3:1) is investigated by differential thermal analysis in combination with glass fluxing technique. In almost every case, the undercooling of the homogeneous alloy melt was sufficient to reach the boundary line of the submerged miscibility gap. The differential-thermal-analysis signals indicate that this separation into a (Fe, Co)-rich liquid phase L1 and a Cu-rich liquid L2 is exothermic and proceeds until the rapid solidification of the L1 phase occurs. At a given Cu concentration and with the increase of Co content, the phase separation temperatures decrease monotonically between the corresponding values of the boundary systems Fe-Cu and Co-Cu. The boundary lines of the miscibility gap, which are determined for the three quasi-binary cross-sections of the (Fe, Co)-Cu alloy system, show remarkably flat domes. The occurrence of the liquid phase separation shows an evident influence on the subsequent γ-Fe(Co, Cu)→α-Fe(Co, Cu) solid phase transformation.

  20. What controls the FeII strength in active galactic nuclei?

    CERN Document Server

    Dong, Xiaobo; Wang, Tinggui; Wang, Huiyuan; Fan, Xiaohui; Zhou, Hongyan; Yuan, Weimin

    2009-01-01

    We have investigated the correlations of the equivalent widths (EWs) of narrow and broad FeII emission lines and the FeII/MgII intensity ratio with fundamental physical parameters of active galactic nuclei (AGNs), luminosity (L), black hole mass (M_{BH}) and Eddington ratio (L/Ledd), using a homogenous sample of z<0.8 Seyfert 1 galaxies and QSOs in the spectroscopic data set of Sloan Digital Sky Survey Fourth Data Release (SDSS DR4). The sample comprises 4178 spectra that are selected to suffer little from the host-galaxy starlight contamination. We find that the strongest correlations of almost all the emission-line intensity ratios and EWs are with L/Ledd, either positively (e.g. FeII EW) or negatively (e.g. MgII EW), rather than with L or M_{BH}; In particular, the intensity ratios of both the ultraviolet and optical FeII emissions to MgII 2800 correlate quite tightly with L/Ledd (e.g., Spearman r_s = 0.74 for the [narrow FeII]/MgII -- L/Ledd correlation). We have also investigated the FeII emission in ...

  1. Equilibrium Fe isotope fractionation between inorganic aqueous Fe(III) and the siderophore complex, Fe(III)-desferrioxamine B

    DEFF Research Database (Denmark)

    Dideriksen, Knud; Baker, Joel A.; Stipp, Susan Louise Svane

    2008-01-01

    In oxic oceans, most of the dissolved iron (Fe) exists as complexes with siderophore-like, strongly coordinating organic ligands. Thus, the isotope composition of the little amount of free inorganic Fe that is available for precipitation and preservation in the geological record may largely...... differently complexed Fe(III) pools were separated by addition of Na2CO3, which led to immediate precipitation of the inorganic Fe without causing significant dissociation of Fe-desferrioxamine complexes. Experiments using enriched 57Fe tracer showed that isotopic equilibration between the 57Fe......(III)-bearing environments, such as soils and rivers, and may, for example, largely control the Fe isotope composition of marine Fe–Mn crusts....

  2. Asymmetric interfaces in Fe/Ag and Ag/Fe bilayers prepared by molecular beam evaporation

    Energy Technology Data Exchange (ETDEWEB)

    Tunyogi, A. [KFKI Research Institute for Particle and Nuclear Physics, P.O. Box 49, H-1525 Budapest (Hungary)]. E-mail: tunyogi@rmki.kfki.hu; Paszti, F. [KFKI Research Institute for Particle and Nuclear Physics, P.O. Box 49, H-1525 Budapest (Hungary); Osvath, Z. [MTA Research Institute for Technical Physics and Materials Science, P.O. Box 49, H-1525 Budapest (Hungary); Tancziko, F. [KFKI Research Institute for Particle and Nuclear Physics, P.O. Box 49, H-1525 Budapest (Hungary); Major, M. [KFKI Research Institute for Particle and Nuclear Physics, P.O. Box 49, H-1525 Budapest (Hungary); Szilagyi, E. [KFKI Research Institute for Particle and Nuclear Physics, P.O. Box 49, H-1525 Budapest (Hungary)

    2006-08-15

    Single layers of Fe and Ag, as well as Fe/Ag (iron deposited first) and Ag/Fe bilayers were prepared by molecular beam evaporation onto Si. The samples were investigated with backscattering spectrometry (BS) and atomic force microscopy (AFM). BS spectra of Fe/Ag and Ag/Fe indicate a significant difference at the interface. In the case of Fe/Ag the Ag peak has a long tail at the interface, while for Ag/Fe the interface is abrupt. The tail in the Fe/Ag spectrum is too large to be caused by double or plural scattering. According to AFM, the effect of surface roughness is also negligible. In spite of the fact that Fe and Ag are completely immiscible in equilibrium, this tail, however, suggests that some Ag is located in the Fe layer. After annealing, both samples show mixing between the two layers; this is much larger again for Fe/Ag.

  3. Preparation of DyFe2 and TbFe2 by Reduction-Diffusion Process

    Institute of Scientific and Technical Information of China (English)

    Guangsi GUO; Guangtai WANG; Zhitong SUI

    2004-01-01

    The pure intermetallic compounds (Tb1-xDyx)Fe2 are super-magnetostriction materials, which were produced from DyFe2and TbFe2 in this paper. The thermodynamic possibility and kinetic feasible conditions for DyFe2 and TbFe2 preparation by reduction-diffusion in Ca-Dy2O3-Fe and Ca-Tb4O7-Fe systems were analyzed and the products of DyFe2 and TbFe2 were confirmed by XRD. The contracting core model was applied to describe the reduction-diffusion process in which the diffusion is a rate-controlled step. The apparent activation energies of DyFe2 and TbFe2 processes are 45 and 39 k J/mol respectively.

  4. A Far Ultraviolet Spectroscopic Explorer Survey of Coronal Forbidden Lines in Late-Type Stars

    CERN Document Server

    Redfield, S; Linsky, J L; Ake, T B; Dupree, A K; Robinson, R D; Young, P R; Redfield, Seth; Ayres, Thomas R.; Linsky, Jeffrey L.; Ake, Thomas B.; Robinson, Richard D.; Young, Peter R.

    2002-01-01

    We present a survey of coronal forbidden lines detected in Far Ultraviolet Spectroscopic Explorer (FUSE) spectra of nearby stars. Two strong coronal features, Fe XVIII 974 A and Fe XIX 1118 A, are observed in 10 of the 26 stars in our sample. Various other coronal forbidden lines, observed in solar flares, also were sought but not detected. The Fe XVIII feature, formed at log T (K) = 6.8, appears to be free of blends, whereas the Fe XIX line can be corrupted by a C I multiplet. FUSE observations of these forbidden iron lines at spectral resolution R ~ 15,000 provides the opportunity to study dynamics of hot coronal plasmas. We find that the velocity centroid of the Fe XVIII feature deviates little from the stellar rest frame, confirming that the hot coronal plasma is confined. The observed line widths generally are consistent with thermal broadening at the high temperatures of formation and show little indication of additional turbulent broadening. The fastest rotating stars, 31 Com, alpha Aur Ab, and AB Dor,...

  5. Spin structure of exchange biased heterostructures. Fe/MnF{sub 2} and Fe/FeF{sub 2}

    Energy Technology Data Exchange (ETDEWEB)

    Sahoo, B.

    2006-12-18

    In this work, the {sup 57}Fe probe layer technique is used in order to investigate the depth- and temperature-dependent Fe-layer spin structure of exchange biased Fe/MnF{sub 2} and Fe/FeF{sub 2} (pseudo-twinned) antiferromagnetic (AFM) systems by conversion electron Moessbauer spectroscopy (CEMS) and nuclear resonant scattering (NRS) of synchrotron radiation. Two kinds of samples with a 10 A {sup 57}Fe probe layer directly at or 35 A away from the interface, labeled as interface and center sample, respectively, were studied in this work. The results obtained by CEMS for Fe/MnF{sub 2} suggests that, at 80 K, i.e., above T{sub N}=67 K of MnF{sub 2}, the remanent state Fe-layer spin structure of the two studied samples are slightly different due to their different microstructure. In the temperature range from 300 K to 80 K, the Fe-layer spin structure does not change just by zero-field cooling the sample in remanence. For Fe/FeF{sub 2}, a continuous non-monotonic change of the remanent-state Fe spin structure was observed by cooling from 300 K to 18 K. NRS of synchrotron radiation was used to investigate the temperature- and depth-dependent Fe-layer spin structure during magnetization reversal in pseudo-twinned Fe/MnF{sub 2}. A depthdependent Fe spin structure in an applied magnetic field (applied along the bisector of the twin domains) was observed at 10 K, where the Fe spins closer to the interface are not aligned along the field direction. The depth-dependence disappears at 150 K. (orig.)

  6. Thermodynamics of Fe(II)Fe(III) oxide systems I. Hydrothermal Fe3O4

    Science.gov (United States)

    Bartel, J.J.; Westrum, E.F.; Haas, J.L.

    1976-01-01

    The heat capacity of a hydrothermally-prepared polycrystalline sample of Fe3O4 was measured from 53 to 350 K, primarily to study the thermophysics of the Verwey transitions. Although the bifurcation of the transition was confirmed, the sample was found to contain traces of manganese. The observed transition temperatures of 117.0 and 123.0 K are 3.7 and 4.2 K higher respectively than those found in pure Fe3O4. Ancillary analytical results are consistent and indicate a stoichiometry of Mn0.008Fe2.992O4 for this material. Characteristics in the transition region are ascribed to dopant effects. ?? 1976.

  7. Minnesota County Boundaries - lines

    Data.gov (United States)

    Minnesota Department of Natural Resources — Minnesota county boundaries derived from a combination of 1:24,000 scale PLS lines, 1:100,000 scale TIGER, 1:100,000 scale DLG, and 1:24,000 scale hydrography lines....

  8. Line graphs for fractals

    Science.gov (United States)

    Warchalowski, Wiktor; Krawczyk, Malgorzata J.

    2017-03-01

    We found the Lindenmayer systems for line graphs built on selected fractals. We show that the fractal dimension of such obtained graphs in all analysed cases is the same as for their original graphs. Both for the original graphs and for their line graphs we identified classes of nodes which reflect symmetry of the graph.

  9. Database of emission lines

    Science.gov (United States)

    Binette, L.; Ortiz, P.; Joguet, B.; Rola, C.

    1998-11-01

    A widely accessible data bank (available through Netscape) and consiting of all (or most) of the emission lines reported in the litterature is being built. It will comprise objects as diverse as HII regions, PN, AGN, HHO. One of its use will be to define/refine existing diagnostic emission line diagrams.

  10. Molecular Hydrogen and [Fe II] in Active Galactic Nuclei III: LINERS and Star Forming Galaxies

    CERN Document Server

    Riffel, R; Aleman, I; Brotherton, M S; Pastoriza, M G; Bonatto, C J; Dors, O L

    2013-01-01

    We study the kinematics and excitation mechanisms of H2 and [Fe II] lines in a sample of 67 emission-line galaxies with Infrared Telescope Facility SpeX near-infrared (NIR, 0.8-2.4 micrometers) spectroscopy together with new photoionisation models. H2 emission lines are systematically narrower than narrow-line region (NLR) lines, suggesting that the two are, very likely, kinematically disconnected. The new models and emission-line ratios show that the thermal excitation plays an important role not only in active galactic nuclei but also in star forming galaxies. The importance of the thermal excitation in star forming galaxies may be associated with the presence of supernova remnants close to the region emitting H2 lines. This hypothesis is further supported by the similarity between the vibrational and rotational temperatures of H2. We confirm that the diagram involving the line ratios H2 2.121/Br_gamma and [Fe II] 1.257/Pa_beta is an efficient tool for separating emission-line objects according to their dom...

  11. Physical properties optimization of polycrystalline LiFeAs

    Energy Technology Data Exchange (ETDEWEB)

    Singh, Shiv J., E-mail: s.j.singh@ifw-dresden.de [Leibniz-Institute for Solid State and Material Research, IFW-Dresden, 01171 Dresden Germany (Germany); Research Center for Environmentally Friendly Materials Engineering, Muroran Institute of Technology, 27-1 Mizumoto-cho, Muroran, Hokkaido, 050-8585 (Japan); Gräfe, Uwe; Beck, Robert; Wolter, Anja U.B.; Grafe, Hans-Joachim [Leibniz-Institute for Solid State and Material Research, IFW-Dresden, 01171 Dresden Germany (Germany); Hess, Christian [Leibniz-Institute for Solid State and Material Research, IFW-Dresden, 01171 Dresden Germany (Germany); Center for Transport and Devices of Emergent Materials, Technische Universität Dresden, 01069 Dresden (Germany); Wurmehl, Sabine [Leibniz-Institute for Solid State and Material Research, IFW-Dresden, 01171 Dresden Germany (Germany); Institut für Festkörperphysik, Technische Universität Dresden, 01069 Dresden (Germany); Büchner, Bernd [Leibniz-Institute for Solid State and Material Research, IFW-Dresden, 01171 Dresden Germany (Germany); Center for Transport and Devices of Emergent Materials, Technische Universität Dresden, 01069 Dresden (Germany); Institut für Festkörperphysik, Technische Universität Dresden, 01069 Dresden (Germany)

    2016-10-15

    Highlights: • Synthesis of polycrystalline LiFeAs in a very broad heating temp. range (200–900 °C). • These samples are characterized by various physical and magnetic measurements. • Interestingly, the LiFeAs phase starts to form at 200 °C with T{sub c} of 19.2 K. • 600 °C synthesis temperature yields optimal high quality polycrystalline LiFeAs. • The properties of the best sample are consistent with that of LiFeAs single crystal. - Abstract: We present a study of parameter optimization for synthesizing truly stoichiometric polycrystalline LiFeAs. Stoichiometric LiFeAs has been prepared in a very broad range of synthesis temperature (200–900 °C) under otherwise exactly the same conditions, and has been characterized by structural, magnetic, transport, nuclear quadrupole resonance (NQR), and specific heat measurements. Our study showed that the LiFeAs phase is formed at 200 °C with a large amount of impurity phases. The amount of these impurity phases reduces with increasing synthesis temperature and the clean LiFeAs phase is obtained at a synthesis temperature of 600 °C. Magnetic susceptibility and resistivity measurements confirmed that the superconducting properties such as the critical temperature T{sub c}, and the upper critical field H{sub c2} do not depend on the synthesis temperature (≤ 700 °C), remaining at almost the same value of ∼19 K and ∼40 T, respectively. However, the width ΔT{sub c} of the transition and the NQR line width decrease with increasing the synthesis temperature and reached to minimum value for the synthesis temperature of 600 °C. Our careful analysis suggests that the best sample obtained at 600 °C is optimal concerning the low resistivity, high residual resistivity ratio (RRR), low ΔT{sub c}, high T{sub c} and H{sub c2}, and a small NQR line width with values which are comparable to that reported for LiFeAs single crystals. Specific heat measurements confirmed the bulk superconducting nature of the samples

  12. Single Crystals (M = Fe, Co)

    Science.gov (United States)

    Cabrera-Baez, M.; Magnavita, E. Thizay; Ribeiro, Raquel A.; Avila, Marcos A.

    2014-06-01

    FeGa3 and related compounds have been subjects of recent investigation for their interesting thermoelectric, electronic, and magnetic behaviors. Here, single crystals of FeGa3- y Ge y were grown by the self-flux technique with effective y = 0, 0.09(1), 0.11(1), and 0.17(1) in order to investigate the evolution of the diamagnetic semiconducting compound FeGa3 into a ferromagnetic metal, which occurs through the electron doping and band structure modifications that result from substitution of Ge for Ga. Heat capacity and magnetization measurements reveal non-Fermi liquid behavior in the vicinity of the transition from a paramagnetic to ferromagnetic ground state, suggesting the presence of a ferromagnetic quantum critical point (FMQCP). We also present the first results of hole doping in this system by the growth of FeGa3- y Zn y single crystals, and electron- and hole doping of the related compound CoGa3 by CoGa3- y Ge y and CoGa3- y Zn y crystal growths, aiming to search for further routes to band structure and charge carrier tuning, thermoelectric optimization, and quantum criticality in this family of compounds. The ability to tune the charge carrier type warrants further investigation of the MGa3 system's thermoelectric properties above room temperature.

  13. CNOOC Cooperates with Santa Fe

    Institute of Scientific and Technical Information of China (English)

    Cao Sanyong; Wang Keyu

    1997-01-01

    @@ China National Offshore Oil Corporatian (CNOOC) signed the Petroleum Contract for 15/34 Block in the Pearl River Mouth Basin of South China Sea and the Petroleum Contract for 23/28 Block in the Beibu Gulf of South China Sea with Santa Fe Resources Inc. of the United States in Beijing on January 16, 1997.

  14. Electronic structure of Fe2P(10 1 bar 0) studied by soft X-ray photoelectron spectroscopy and X-ray absorption spectroscopy

    Science.gov (United States)

    Sugizaki, Y.; Motoyama, H.; Edamoto, K.; Ozawa, K.

    2017-10-01

    The electronic structure of Fe2P(10 1 bar 0) has been investigated by photoelectron spectroscopy (PES) and X-ray absorption spectroscopy (XAS). The surface prepared by cycles of Ar+ ion sputtering and annealing at 500-800 °C showed a c(2 × 2) low-energy electron diffraction (LEED) pattern. An Fe 3d-P 3p hybrid band (main band) and a satellite were observed at 0-4 eV and 5-8 eV, respectively, in PES spectra of c(2 × 2) Fe2P(10 1 bar 0). The main band showed a clear cut-off at the Fermi edge, indicating the metallic nature of Fe2P. The satellite intensity showed a resonant maximum around the Fe 3p threshold, suggesting that the satellite is caused through a shake-up process. Three types of surface-shifted components were found in P 2p PES spectra. All the P 2p peaks have symmetric line shapes, while the Fe 2p PES and Fe L-edge XAS spectra have asymmetric line shapes, suggesting that the electronic states around the Fermi level are mostly composed of Fe 3d components. These results suggest that the stabilization of the electronic structure at metal sites through the bonding with P atoms is ineffective on Fe2P(10 1 bar 0), as in the case of Fe2P(0001).

  15. Infrared spectroscopic study on lattice dynamics in CaFeO3

    Science.gov (United States)

    Zhang, C. X.; Xia, H. L.; Liu, H.; Dai, Y. M.; Xu, B.; Yang, R.; Qiu, Z. Y.; Sui, Q. T.; Long, Y. W.; Meng, S.; Qiu, X. G.

    2017-02-01

    The change of the lattice dynamics upon the charge disproportionation (CD) transition has been investigated for the CaFeO3 crystal by measuring its infrared optical spectra. Across the CD transition, CaFeO3 undergoes a metal-insulator transition, and it is found that below TC D≈ 290 K the low-frequency optical conductivity gradually decreases to a rather low value and is dominated by a series of infrared-active phonons. Intriguingly, accompanied by the CD transition, two prominent phonon modes at ˜243 and ˜559 cm-1associated with the vibrations of Fe-O bonds show obvious redshift and asymmetric line shapes characterized by a Fano profile, suggesting a strong electron-phonon coupling. This coupling behavior reveals an intimate relationship between charge and lattice in the CD transition of CaFeO3.

  16. Synthesis of MIL-100(Fe at Low Temperature and Atmospheric Pressure

    Directory of Open Access Journals (Sweden)

    Jing Shi

    2013-01-01

    Full Text Available MIL-100(Fe, a mesoporous metal-organic framework (MOF, has a large BET specific surface area and pore volume with the presence of a significant amount of accessible Lewis acid metal sites upon dehydration. The structural characteristics of MIL-100(Fe make it a good candidate for potential applications in gas storage, separation, and heterogeneous catalysis. Mainly, this MOF is obtained by the hydrothermal synthesis in a Teflon-lined autoclave at high temperature (>150°C under static conditions. However, this method has several disadvantages such as high temperature, high (autogenous pressure, long time, and comparable low MOF yield. Therefore, development of a facile method for synthesis of MIL-100(Fe is vitally important for fundamental understanding and practical application. Herein, MIL-100(Fe is synthesized by a facile low-temperature (90% still could be achieved, suggesting that this simple and energy saving method has the potential to be used practically.

  17. Synthesis of Fe Nanoparticles Functionalized with Oleic Acid Synthesized by Inert Gas Condensation

    Directory of Open Access Journals (Sweden)

    L. G. Silva

    2014-01-01

    Full Text Available In this work, we study the synthesis of monodispersed Fe nanoparticles (Fe-NPs in situ functionalized with oleic acid. The nanoparticles were self-assembled by inert gas condensation (IGC technique by using magnetron-sputtering process. Structural characterization of Fe-NPs was performed by transmission electron microscopy (TEM. Particle size control was carried out through the following parameters: (i condensation zone length, (ii magnetron power, and (iii gas flow (Ar and He. Typically the nanoparticles generated by IGC showed diameters which ranged from ~0.7 to 20 nm. Mass spectroscopy of Fe-NPs in the deposition system allowed the study of in situ nanoparticle formation, through a quadrupole mass filter (QMF that one can use together with a mass filter. When the deposition system works without quadrupole mass filter, the particle diameter distribution is around +/−20%. When the quadrupole is in line, then the distribution can be reduced to around +/−2%.

  18. Mössbauer spectroscopy of Fe 60Ni 40 alloy films

    Science.gov (United States)

    Mahmood, Sami H.; Rousan, Khitam K.; Lehlooh, A.-F.; Mahmoud, Sabri S.

    1995-09-01

    Films of the alloy Fe 60Ni 40 are prepared by thermal evaporation of the alloy powder onto Al foils. Mössbauer spectra of the films on the Al substrate show a dominent central paramagnetic line during the first month after their preparation, which is attributed to the Fe-rich γ' f.c.c. phase. The spectrum collected four months after preparation shows a 25% decrease in the relative intensity of the paramagnetic signal. However, the paramagnetic intensity drops by 65% upon removal of the film from the substrate, reaching a value close to that for the original alloy powder. This is interpreted as due to the atomic diffusion of Fe atoms from Fe-rich clusters into the surrounding FeNi matrix, and the occurrence of a phase relaxation to a state similar to that of the original powder, implying that the relative proportion of the γ' phase could be dictated by the chemical composition of the alloy.

  19. Variability of Fe II in Two NLS1s, PG 1700+815 and NGC 4051

    Indian Academy of Sciences (India)

    Weihao Bian; Zhen Yang

    2011-03-01

    We analyze the spectral variability for two narrow line Seyfert 1 galaxies, PG 1700+518 and NGC 4051 using the spectral decomposition method. We focus on their optical Fe II variability to investigate the origin of Fe II in AGNs. For PG 1700+518, we find that the Fe II size is about 200 light-days, which is consistent with the H size derived from the empirical R–L relation. For NGC 4051, the [O III] 5007 Å flux is strongly correlated with continuum flux, suggesting that we should recalibrate the spectral flux on a scale defined by [O III] flux. The corrected light curves of Fe II, H, He II, (5100 Å) are given here. A detailed analysis will be given in the near future.

  20. Variability of factors that affect availability of iron, manganese and zinc in maize lines

    Directory of Open Access Journals (Sweden)

    Dragičević Vesna

    2013-01-01

    Full Text Available Deficiencies of some mineral elements are causing serious health problems, which could be prevented by increase of mineral nutrients in food with supplementation, food fortification or plant breeding. From this point, experiment with 78 maize inbred lines was set up to determine maize lines with improved contents of Fe, Zn and Mn, as well as their relations with phytic acid, inorganic phosphorus and β-carotene, as factors which affect their absorption. Obtained results suggest that investigated maize lines show high variability in concentration of Fe, Mn and Zn, as well as phytic acid (which sustain availability of mineral elements and β-carotene (which enables better absorption of mineral element and minimize negative effect of phytic acid. From this point of view, group of genotypes with phytic P ≤ 3 g kg-1 was interesting. Among them, L2 and L23 are maize lines with relatively high inorganic P, Fe and Zn contents, and together with relatively low ratio between phytic and inorganic P, they could be used as a good source of P, Fe and Zn. On the other hand, L1 and L4 are also maize lines with high inorganic P, β-carotene and Mn, and favourable ratio between phytic acid and Fe and Zn, what could give them advance as source of Mn in breeding programs. The same maize lines could also be candidates with improved ability for Fe and Zn absorption, what is based on high β-carotene content. Maize line L14, with relatively high concentration of all three. [Projekat Ministarstva nauke Republike Srbije, br. TR 31068: Improving the quality of maize and soybean by conventional and molecular breeding

  1. Presence of 60Fe in eucrite Piplia Kalan: A new perspective to the initial 60Fe/ 56Fe in the early solar system

    Digital Repository Service at National Institute of Oceanography (India)

    Rudraswami, N.G.; Sahijpal, S.; Bhandari, N.

    - formed on Fe-rich silicate phases of chondrule and troilite from unequilibrated ordinary chondrites (UOCs) 4,8–10 provided an initial 60 Fe/ 56 Fe from (1–10) × 10 –7 . The wide range does not allow us to constrain the initial 60 Fe/ 56 Fe values... metamorphic grade did have a widespread distribution of initial 60 Fe/ 56 Fe. In fact, the spread in the initial 60 Fe/ 56 Fe does seem to gain support for the heterogeneous distribution in the solar system, unlike that of 26 Al. Whether 60 Fe...

  2. Fe I OSCILLATOR STRENGTHS FOR TRANSITIONS FROM HIGH-LYING EVEN-PARITY LEVELS

    Energy Technology Data Exchange (ETDEWEB)

    Den Hartog, E. A.; Lawler, J. E.; Brewer, N. R. [Department of Physics, University of Wisconsin, Madison, WI 53706 (United States); Ruffoni, M. P.; Pickering, J. C. [Blackett Laboratory, Imperial College London, London SW7 2BW (United Kingdom); Lind, K., E-mail: eadenhar@wisc.edu [Department of Physics and Astronomy, Uppsala University, Box 516, SE-751 20 Uppsala (Sweden)

    2015-01-01

    New radiative lifetimes, measured to ±5% accuracy, are reported for 31 even-parity levels of Fe I ranging from 45061 cm{sup –1} to 56842 cm{sup –1}. These lifetimes have been measured using single-step and two-step time-resolved laser-induced fluorescence on a slow atomic beam of iron atoms. Branching fractions have been attempted for all of these levels, and completed for 20 levels. This set of levels represents an extension of the collaborative work reported in Ruffoni et al. The radiative lifetimes combined with the branching fractions yields new oscillator strengths for 203 lines of Fe I. Utilizing a 1D-LTE model of the solar photosphere, spectral syntheses for a subset of these lines which are unblended in the solar spectrum yields a mean iron abundance of (log[ε(Fe)]) = 7.45 ± 0.06.

  3. The Fe/Ni ratio in ionized nebulae: clues on dust depletion patterns

    CERN Document Server

    Delgado-Inglada, Gloria; García-Rojas, Jorge; Rodríguez, Mónica; Esteban, César

    2015-01-01

    We perform a homogeneous analysis of the Fe/Ni abundance ratio in eight Galactic planetary nebulae (PNe) and three Galactic H II regions that include the Orion nebula, where we study four nebular zones and one shocked region. We use [Fe ii], [Fe iii], and [Ni iii] lines, and ionization correction factors (ICFs) that account for the unobserved ions. We derive an ICF for nickel from an extensive grid of photoionization models. We compare our results with those derived by other authors for 16 neutral clouds in the solar neighbourhood with available Fe/Ni ratios in the literature. We find an excellent agreement between the ionized nebulae and the diffuse clouds, with both types of regions showing a clear correlation between the Fe/Ni ratios and the iron and nickel depletion factors. The trend shows that the objects with a relatively low depletion have near solar Fe/Ni ratios whereas at higher depletions the Fe/Ni ratio increases with the depletion. Our results confirm that, compared to iron atoms, nickel ones are...

  4. Physical properties optimization of polycrystalline LiFeAs

    Science.gov (United States)

    Singh, Shiv J.; Gräfe, Uwe; Beck, Robert; Wolter, Anja U. B.; Grafe, Hans-Joachim; Hess, Christian; Wurmehl, Sabine; Büchner, Bernd

    2016-10-01

    We present a study of parameter optimization for synthesizing truly stoichiometric polycrystalline LiFeAs. Stoichiometric LiFeAs has been prepared in a very broad range of synthesis temperature (200-900 °C) under otherwise exactly the same conditions, and has been characterized by structural, magnetic, transport, nuclear quadrupole resonance (NQR), and specific heat measurements. Our study showed that the LiFeAs phase is formed at 200 °C with a large amount of impurity phases. The amount of these impurity phases reduces with increasing synthesis temperature and the clean LiFeAs phase is obtained at a synthesis temperature of 600 °C. Magnetic susceptibility and resistivity measurements confirmed that the superconducting properties such as the critical temperature Tc, and the upper critical field Hc2 do not depend on the synthesis temperature (≤ 700 °C), remaining at almost the same value of ∼19 K and ∼40 T, respectively. However, the width ΔTc of the transition and the NQR line width decrease with increasing the synthesis temperature and reached to minimum value for the synthesis temperature of 600 °C. Our careful analysis suggests that the best sample obtained at 600 °C is optimal concerning the low resistivity, high residual resistivity ratio (RRR), low ΔTc, high Tc and Hc2, and a small NQR line width with values which are comparable to that reported for LiFeAs single crystals. Specific heat measurements confirmed the bulk superconducting nature of the samples. The Hc2 value estimated from the specific heat is consistent with that of the resistivity measurements. Concisely, 600 °C synthesis temperature yields optimal high quality polycrystalline LiFeAs bulk samples. Further improvement of the quality of the sample prepared at 600 °C could be obtained by a controlled slow cooling process. Microstructural analysis reveals that the abundance of micro-cracks becomes strongly reduced by the slow cooling process, resulting in an increase in clean and

  5. Atom exchange between aqueous Fe(II) and structural Fe in clay minerals.

    Science.gov (United States)

    Neumann, Anke; Wu, Lingling; Li, Weiqiang; Beard, Brian L; Johnson, Clark M; Rosso, Kevin M; Frierdich, Andrew J; Scherer, Michelle M

    2015-03-03

    Due to their stability toward reductive dissolution, Fe-bearing clay minerals are viewed as a renewable source of Fe redox activity in diverse environments. Recent findings of interfacial electron transfer between aqueous Fe(II) and structural Fe in clay minerals and electron conduction in octahedral sheets of nontronite, however, raise the question whether Fe interaction with clay minerals is more dynamic than previously thought. Here, we use an enriched isotope tracer approach to simultaneously trace Fe atom movement from the aqueous phase to the solid ((57)Fe) and from the solid into the aqueous phase ((56)Fe). Over 6 months, we observed a significant decrease in aqueous (57)Fe isotope fraction, with a fast initial decrease which slowed after 3 days and stabilized after about 50 days. For the aqueous (56)Fe isotope fraction, we observed a similar but opposite trend, indicating that Fe atom movement had occurred in both directions: from the aqueous phase into the solid and from the solid into aqueous phase. We calculated that 5-20% of structural Fe in clay minerals NAu-1, NAu-2, and SWa-1 exchanged with aqueous Fe(II), which significantly exceeds the Fe atom layer exposed directly to solution. Calculations based on electron-hopping rates in nontronite suggest that the bulk conduction mechanism previously demonstrated for hematite1 and suggested as an explanation for the significant Fe atom exchange observed in goethite2 may be a plausible mechanism for Fe atom exchange in Fe-bearing clay minerals. Our finding of 5-20% Fe atom exchange in clay minerals indicates that we need to rethink how Fe mobility affects the macroscopic properties of Fe-bearing phyllosilicates and its role in Fe biogeochemical cycling, as well as its use in a variety of engineered applications, such as landfill liners and nuclear repositories.

  6. A SCUBA-2 survey of FeLoBAL QSOs: Are FeLoBALs in a `transition phase' between ULIRGs and QSOs?

    CERN Document Server

    Violino, Giulio; Stevens, Jason A; Farrah, Duncan; Geach, James E; Alexander, Dave M; Hickox, Ryan; Smith, Daniel J B; Wardlow, Julie L

    2015-01-01

    It is thought that a class of broad absorption line (BAL) QSOs, characterised by Fe absorption features in their UV spectra (called `FeLoBALs'), could mark a transition stage between the end of an obscured starburst event and a youthful QSO beginning to shed its dust cocoon, where Fe has been injected into the interstellar medium by the starburst. To test this hypothesis we have undertaken deep SCUBA-2 850 $\\mu$m observations of a sample of 17 FeLoBAL QSOs with 0.89 $\\leq$ z $\\leq$ 2.78 and -23.31 $\\leq$ M$_{B}$ $\\leq$-28.50 to directly detect an excess in the thermal emission of the dust which would probe enhanced star-formation activity. We find that FeLoBALs are not luminous sources in the submillimetre, none of them are individually detected at 850 $\\mu$m, nor as a population through stacking ($F_{s}=1.14\\pm0.58$ mJy). Statistical and survival analyses reveal that FeLoBALs have sub-mm properties consistent with BAL and non-BAL QSOs with matched redshifts and magnitudes. An SED fitting analysis shows that ...

  7. Speciation of Fe(II) and Fe(III) by the modified ferrozine method, FIA-spectrophotometry, and flame AAS after cloud-point extraction

    Energy Technology Data Exchange (ETDEWEB)

    Giokas, Dimosthenis L.; Paleologos, Evangelos K.; Karayannis, Miltiades I. [Laboratory of Analytical Chemistry, Department of Chemistry, University of Ioannina (Greece)

    2002-07-01

    A method has been developed for the simultaneous determination of traces of Fe(III) and Fe(II) in water by on-line coupling of spectrophotometry with flame atomic absorption spectrometry (FAAS). The method involves cloud-point extraction (CPE) of both species with ammonium pyrrolidinecarbodithioate (APDC) under standard conditions, which facilitates the in situ complexation and extraction of both species. Differentiation of the oxidation states of iron is achieved by using mathematical equations to overcome the interference of Fe(III) in the spectrophotometric determination of Fe(II) when they are both present in the same solution. In this manner the time-consuming and labor-intensive steps of preoxidation of Fe(II) or reduction of Fe(III) are eliminated. By preconcentrating a 10-mL sample solution detection limits as low as 7 {mu}g L{sup -1}, were obtained after a single-step extraction procedure. The relative standard deviation (n=4, 30 {mu}g L{sup -1}) was 2.6 % and 1.8 % for spectrophotometry and FAAS, respectively. Recoveries in the range of 96-105 % were obtained by analysis of spiked real samples. The method was further verified by analyzing a certified reference material (IMEP-9); for this the recovery was 98.5 %. (orig.)

  8. Modelling the broad Fe Kα reverberation in the AGN NGC 4151

    NARCIS (Netherlands)

    E.M. Cackett; A. Zoghbi; C. Reynolds; A.C. Fabian; E. Kara; P. Uttley; D.R. Wilkins

    2014-01-01

    The recent detection of X-ray reverberation lags, especially in the Feline region, around active galactic nuclei (AGN) has opened up the possibility of studying the time-resolved response (reflection) of hard X-rays from the accretion disc around supermassive black holes. Here, we use general re

  9. Biogeochemical speciation of Fe in ocean water

    NARCIS (Netherlands)

    Hiemstra, T.; Riemsdijk, van W.H.

    2006-01-01

    The biogeochemical speciation of Fe in seawater has been evaluated using the consistent Non-Ideal Competitive Adsorption model (NICA¿Donnan model). Two types of data sets were used, i.e. Fe-hydroxide solubility data and competitive ligand equilibration/cathodic stripping voltammetry (CLE/CSV) Fe

  10. Arsenate uptake and arsenite simultaneous sorption and oxidation by Fe-Mn binary oxides: influence of Mn/Fe ratio, pH, Ca2+, and humic acid.

    Science.gov (United States)

    Zhang, Gaosheng; Liu, Huijuan; Qu, Jiuhui; Jefferson, William

    2012-01-15

    Arsenate retention, arsenite sorption and oxidation on the surfaces of Fe-Mn binary oxides may play an important role in the mobilization and transformation of arsenic, due to the common occurrence of these oxides in the environment. However, no sufficient information on the sorption behaviors of arsenic on Fe-Mn binary oxides is available. This study investigated the influences of Mn/Fe molar ratio, solution pH, coexisting calcium ions, and humic acids have on arsenic sorption by Fe-Mn binary oxides. To create Fe-Mn binary oxides, simultaneous oxidation and co-precipitation methods were employed. The Fe-Mn binary oxides exhibited a porous crystalline structure similar to 2-line ferrihydrite at Mn/Fe ratios 1:3 and below, whereas exhibited similar structures to δ-MnO(2) at higher ratios. The As(V) sorption maximum was observed at a Mn/Fe ratio of 1:6, but As(III) uptake maximum was at Mn/Fe ratio 1:3. However, As(III) adsorption capacity was much higher than that of As(V) at each Mn/Fe ratio. As(V) sorption was found to decrease with increasing pH, while As(III) sorption edge was different, depending on the content of MnO(2) in the binary oxides. The presence of Ca(2+) enhanced the As(V) uptake under alkaline pH, but did not significantly influence the As(III) sorption by 1:9 Fe-Mn binary oxide; whereas the presence of humic acid slightly reduced both As(V) and As(III) uptake. These results indicate that As(III) is more easily immobilized than As(V) in the environment, where Fe-Mn binary oxides are available as sorbents and they represent attractive adsorbents for both As(V) and As(III) removal from water and groundwater. Copyright © 2011 Elsevier Inc. All rights reserved.

  11. Magnetostrictive GMR spin valves with composite FeGa/FeCo free layers

    OpenAIRE

    Luping Liu; Qingfeng Zhan; Huali Yang; Huihui Li; Shuanglan Zhang; Yiwei Liu; Baomin Wang; Xiaohua Tan; Run-Wei Li

    2016-01-01

    We have fabricated strain-sensitive spin valves on flexible substrates by utilizing the large magnetostrictive FeGa alloy to promote the strain sensitivity and the composite free layer of FeGa/FeCo to avoid the drastic reduction of giant magnetoresistance (GMR) ratio. This kind of spin valve (SV-FeGa/FeCo) displays a MR ratio about 5.9%, which is comparable to that of the conventional spin valve (SV-FeCo) with a single FeCo free layer. Different from the previously reported works on magnetost...

  12. Wood pole overhead lines

    CERN Document Server

    Wareing, Brian

    2005-01-01

    This new book concentrates on the mechanical aspects of distribution wood pole lines, including live line working, environmental influences, climate change and international standards. Other topics include statutory requirements, safety, profiling, traditional and probabilistic design, weather loads, bare and covered conductors, different types of overhead systems, conductor choice, construction and maintenance. A section has also been devoted to the topic of lightning, which is one of the major sources of faults on overhead lines. The book focuses on the effects of this problem and the strate

  13. Relativistic Disc lines

    CERN Document Server

    Fabian, A C; Parker, M L

    2014-01-01

    Broad emission lines, particularly broad iron-K lines, are now commonly seen in the X-ray spectra of luminous AGN and Galactic black hole binaries. Sensitive NuSTAR spectra over the energy range of 3-78 keV and high frequency reverberation spectra now confirm that these are relativistic disc lines produced by coronal irradiation of the innermost accretion flow around rapidly spinning black holes. General relativistic effects are essential in explaining the observations. Recent results are briefly reviewed here.

  14. Process and genes for expression and overexpression of active [FeFe] hydrogenases

    Science.gov (United States)

    Seibert, Michael; King, Paul W; Ghirardi, Maria Lucia; Posewitz, Matthew C; Smolinski, Sharon L

    2014-09-16

    A process for expression of active [FeFe]-hydrogenase in a host organism that does not contain either the structural gene(s) for [FeFe]-hydrogenases and/or homologues for the maturation genes HydE, HydF and HyG, comprising: cloning the structural hydrogenase gene(s) and/or the maturation genes HydE, HydF and HydG from an organisms that contains these genes into expression plasmids; transferring the plasmids into an organism that lacks a native [FeFe]-hydrogenase or that has a disrupted [FeFe]-hydrogenase and culturing it aerobically; and inducing anaerobiosis to provide [FeFe] hydrogenase biosynthesis and H?2#191 production.

  15. Process and genes for expression and overexpression of active [FeFe] hydrogenases

    Energy Technology Data Exchange (ETDEWEB)

    Seibert, Michael; King, Paul W; Ghirardi, Maria Lucia; Posewitz, Matthew C; Smolinski, Sharon L

    2014-09-16

    A process for expression of active [FeFe]-hydrogenase in a host organism that does not contain either the structural gene(s) for [FeFe]-hydrogenases and/or homologues for the maturation genes HydE, HydF and HyG, comprising: cloning the structural hydrogenase gene(s) and/or the maturation genes HydE, HydF and HydG from an organisms that contains these genes into expression plasmids; transferring the plasmids into an organism that lacks a native [FeFe]-hydrogenase or that has a disrupted [FeFe]-hydrogenase and culturing it aerobically; and inducing anaerobiosis to provide [FeFe] hydrogenase biosynthesis and H?2#191 production.

  16. Implications of Coronal Line Emission in NGC 4696

    CERN Document Server

    Chatzikos, M; Ferland, G J; Canning, R E A; Fabian, A C; Sanders, J S; van Hoof, P A M; Johnstone, R M; Lykins, M; Porter, R L

    2014-01-01

    We announce a new facility in the spectral code CLOUDY that enables tracking the evolution of a cooling parcel of gas with time. For gas cooling from temperatures relevant to galaxy clusters, earlier calculations estimated the [Fe XIV] {\\lambda}5303 / [Fe X] {\\lambda}6375 luminosity ratio, a critical diagnostic of a cooling plasma, to slightly less than unity. By contrast, our calculations predict a ratio ~3. We revisit recent optical coronal line observations along the X-ray cool arc around NGC 4696 by Canning et al. (2011), which detected [Fe X] {\\lambda}6375, but not [Fe XIV] {\\lambda}5303. We show that these observations are not consistent with predictions of cooling flow models. Differential extinction could in principle account for the observations, but it requires extinction levels (A_V > 3.625) incompatible with previous observations. The non-detection of [Fe XIV] implies a temperature ceiling of 2.1 million K. Assuming cylindrical geometry and transonic turbulent pressure support, we estimate the gas...

  17. Spectroscopic Diagnostics of Solar Magnetic Flux Ropes Using Iron Forbidden Line

    Science.gov (United States)

    Cheng, X.; Ding, M. D.

    2016-05-01

    In this Letter, we present Interface Region Imaging Spectrograph Fe xxi 1354.08 Å forbidden line emission of two magnetic flux ropes (MFRs) that caused two fast coronal mass ejections with velocities of ≥1000 km s-1 and strong flares (X1.6 and M6.5) on 2014 September 10 and 2015 June 22, respectively. The extreme-ultraviolet images at the 131 and 94 Å passbands provided by the Atmospheric Imaging Assembly on board Solar Dynamics Observatory reveal that both MFRs initially appear as suspended hot channel-like structures. Interestingly, part of the MFRs is also visible in the Fe xxi 1354.08 forbidden line, even prior to the eruption, e.g., for the SOL2014-09-10 event. However, the line emission is very weak and that only appears at a few locations but not the whole structure of the MFRs. This implies that the MFRs could be comprised of different threads with different temperatures and densities, based on the fact that the formation of the Fe xxi forbidden line requires a critical temperature (˜11.5 MK) and density. Moreover, the line shows a non-thermal broadening and a blueshift in the early phase. It suggests that magnetic reconnection at that time has initiated; it not only heats the MFR and, at the same time, produces a non-thermal broadening of the Fe xxi line but also produces the poloidal flux, leading to the ascension of the MFRs.

  18. Numerical Methods for Plate Forming by Line Heating

    DEFF Research Database (Denmark)

    Clausen, Henrik Bisgaard

    2000-01-01

    Line heating is the process of forming originally flat plates into a desired shape by means of heat treatment. Parameter studies are carried out on a finite element model to provide knowledge of how the process behaves with varying heating conditions. For verification purposes, experiments are ca...... are carried out; one set of experiments investigates the actual heat flux distribution from a gas torch and another verifies the validty of the FE calculations. Finally, a method to predict the heating pattern is described....

  19. The Warm Absorber constrained by the coronal lines in Seyfert 1 galaxies

    CERN Document Server

    Porquet, D; Collin, S; Mouchet, M; Porquet, Delphine; Dumont, Anne-Marie; Collin, Suzy; Mouchet, Martine

    1999-01-01

    We present results of the photoionization code IRIS, which calculates the spectrum emitted by the Warm Absorber (WA) in Seyfert 1 galaxies for a large grid of parameters (density, column density, ionization parameter...). We show that in Seyfert 1s, coronal lines ([Fe X], [Fe XI], [Fe XIV]...), unlike the absorption edges, such as those of O VII and O VIII observed in soft X-rays which are produced by the WA, strongly constrain the physical parameters of the WA, especially the hydrogen density. Indeed, in order to avoid producing coronal line equivalent widths larger than observed, a high density ($n_{H} models (photoionized medium in or out of thermal equilibrium). This result is obtained for the mean observed Seyfert 1 features, as well as for the case study of MCG-6-30-15. It implies that the distance of the WA from the incident radiation source is of the order of that of the Broad Line Region (BLR).

  20. Illustrating the Euler Line.

    Science.gov (United States)

    Rubillo, James M.

    1987-01-01

    Euler's discovery about the centroid of a triangle trisecting the line segment joining its circumference to its orthocenter is discussed. An activity that will help students review fundamental concepts is included. (MNS)

  1. Agate Hydrologic Lines Edited

    Data.gov (United States)

    National Park Service, Department of the Interior — This theme includes all hydrologic lines including rivers, intermittent streams, and pond shorelines. The source spatial data comes from agfohydp which is a DLG file...

  2. Electric Power Transmission Lines

    Data.gov (United States)

    Department of Homeland Security — Transmission Lines are the system of structures, wires, insulators and associated hardware that carry electric energy from one point to another in an electric power...

  3. Kansas Electric Transmission Lines

    Data.gov (United States)

    Kansas Data Access and Support Center — This data set is a digital representation of the EletcircTransmission lines for the State of Kansas as maintained by the Kansas Corporation Commission. Data is...

  4. Veterans Crisis Line

    Data.gov (United States)

    Department of Veterans Affairs — The caring responders at the Veterans Crisis Line are specially trained and experienced in helping Veterans of all ages and circumstances. Some of the responders are...

  5. X-ray diagnostics of chemical composition of the accretion disk and donor star in UCXBs II: XMM-Newton observations

    CERN Document Server

    Koliopanos, Filippos; Trigo, Maria Diaz

    2014-01-01

    We search for the Fe K${\\alpha}$ line in spectra of Ultra Compact X-ray Binaries (UCXBs). For this purpose we have analyzed XMM-Newton observations of five confirmed UCXBs. We find that the object 2S 0918-549 - whose optical spectrum bears tentative signatures of a C/O accretion disk - is devoid of any emission features in the 6-7 keV range, with an upper limit of less than 10 eV for the equivalent width (EW) of the iron line. 4U 1916-05 - whose optical spectrum is consistent with reflection from a He-rich accretion disk - exhibits a bright broad iron emission line. This behavior is in agreement with the theoretical predictions presented in Koliopanos, Gilfanov and Bildsten (2013). Namely, we expect strong suppression of the Fe K${\\alpha}$ emission line in spectra originating in moderately bright (LogLx less than $\\approx$ 37.5) UCXBs with C/O or O/Ne/Mg-rich donors. On the other hand the EW of the iron line in spectra from UCXBs with He-rich donors is expected to retain its nominal value of $\\approx$ 100 eV....

  6. Storage of cell lines.

    Science.gov (United States)

    Parker, Katharine A

    2011-01-01

    The successful storage of cell lines depends upon many factors, including the condition of the cells to be frozen and the experience of the operator. Attempting to freeze down unhealthy, contaminated or poorly labelled cells can have huge implications for a research laboratory. This chapter outlines the importance of good record keeping, vigilant monitoring, aseptic technique, and high-quality reagents in the successful storage and downstream propagation of cell lines.

  7. Explosive Line Wave Generators

    Science.gov (United States)

    2013-12-01

    curvature produced by each line wave generator. Piezoelectric pins were used for an additional assessment of the explosive lens design...to a visual assessment of the wave curvature from the high speed camera images, the explosive lens design was also evaluated using piezoelectric pins...High Explosive Firing Complex (HEFC). The various explosive line wave generators were taped vertically on a supporting board and the detonation wave

  8. Fe-Ni-O体系中Fe/Ni的还原行为%Reduction behavior of Fe/Ni in the Fe-Ni-O system

    Institute of Scientific and Technical Information of China (English)

    魏文洁; 张延玲; 魏芬绒; 杨小刚; 胡晓军

    2013-01-01

    取电阻炉实验和热重分析等手段,探讨了Fe-Ni-O体系中不同条件下的产物组成及Fe/Ni的还原行为.结果表明:五种样品的还原难度由低到高依次为NiO<Fe2O3+Ni<Fe2O3+NiO<NiFe2O4 <Fe2O3; Ni元素能够促进铁氧化物还原,其促进作用由Ni元素的初始状态决定,单质Ni>氧化物NiO>NiFe2O4中的Ni;NiFe2O4的还原过程中各产物由低温到高温依次出现的次序为Fe3O4、Ni、(Fe,Ni)、Fe和Fe0.64Ni0.36.根据实验结果,对五种氧化物体系的还原过程进行了探讨,并获得了活化能、控速环节等重要参数及相关反应机理.%The product composition under different conditions and the reduction behavior of Fe and Ni in the Fe-Ni-O system were studied by electric resistance furnace experiments and thermogravimetric analysis. The order of difficult degree for reducing Fe/Ni oxides in five systems is NiONiO>Ni released from NiFe2O4. As the temperature increases, the reduction products of NiFe2O4 are in order of Fe3O4, Ni, (Fe, Ni), Fe, and Fe0.64Ni0.36- Based on these experimental results, the reduction processes and the kinetics such as activation energy and rate-controlling step for reducing the five oxides were analyzed and discussed.

  9. Quantitative FE-EPMA measurement of formation and inhibition of carbon contamination on Fe for trace carbon analysis.

    Science.gov (United States)

    Tanaka, Yuji; Yamashita, Takako; Nagoshi, Masayasu

    2017-04-01

    Hydrocarbon contamination introduced during point, line and map analyses in a field emission electron probe microanalysis (FE-EPMA) was investigated to enable reliable quantitative analysis of trace amounts of carbon in steels. The increment of contamination on pure iron in point analysis is proportional to the number of iterations of beam irradiation, but not to the accumulated irradiation time. A combination of a longer dwell time and single measurement with a liquid nitrogen (LN2) trap as an anti-contamination device (ACD) is sufficient for a quantitative point analysis. However, in line and map analyses, contamination increases with irradiation time in addition to the number of iterations, even though the LN2 trap and a plasma cleaner are used as ACDs. Thus, a shorter dwell time and single measurement are preferred for line and map analyses, although it is difficult to eliminate the influence of contamination. While ring-like contamination around the irradiation point grows during electron-beam irradiation, contamination at the irradiation point increases during blanking time after irradiation. This can explain the increment of contamination in iterative point analysis as well as in line and map analyses. Among the ACDs, which are tested in this study, specimen heating at 373 K has a significant contamination inhibition effect. This technique makes it possible to obtain line and map analysis data with minimum influence of contamination. The above-mentioned FE-EPMA data are presented and discussed in terms of the contamination-formation mechanisms and the preferable experimental conditions for the quantification of trace carbon in steels. © The Author 2016. Published by Oxford University Press on behalf of The Japanese Society of Microscopy. All rights reserved. For permissions, please e-mail: journals.permissions@oup.com.

  10. On-Line and Off-Line Assessment of Metacognition

    Science.gov (United States)

    Saraç, Seda; Karakelle, Sema

    2012-01-01

    The study investigates the interrelationships between different on-line and off-line measures for assessing metacognition. The participants were 47 fifth grade elementary students. Metacognition was assessed through two off-line and two on-line measures. The off-line measures consisted of a teacher rating scale and a self-report questionnaire. The…

  11. Rapid degradation of dyes in water by magnetic Fe(0)/Fe3O4/graphene composites.

    Science.gov (United States)

    Chong, Shan; Zhang, Guangming; Tian, Huifang; Zhao, He

    2016-06-01

    Magnetic Fe(0)/Fe3O4/graphene has been successfully synthesized by a one-step reduction method and investigated in rapid degradation of dyes in this work. The material was characterized by N2 sorption-desorption, scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FT-IR), vibrating-sample magnetometer (VSM) measurements and X-ray photoelectron spectroscopy (XPS). The results indicated that Fe(0)/Fe3O4/graphene had a layered structure with Fe crystals highly dispersed in the interlayers of graphene, which could enhance the mass transfer process between Fe(0)/Fe3O4/graphene and pollutants. Fe(0)/Fe3O4/graphene exhibited ferromagnetism and could be easily separated and re-dispersed for reuse in water. Typical dyes, such as Methyl Orange, Methylene Blue and Crystal Violet, could be decolorized by Fe(0)/Fe3O4/graphene rapidly. After 20min, the decolorization efficiencies of methyl orange, methylene blue and crystal violet were 94.78%, 91.60% and 89.07%, respectively. The reaction mechanism of Fe(0)/Fe3O4/graphene with dyes mainly included adsorption and enhanced reduction by the composite. Thus, Fe(0)/Fe3O4/graphene prepared by the one-step reduction method has excellent performance in removal of dyes in water.

  12. Mechanochemical synthesis of nanocrystalline Fe and Fe-B magnetic alloys

    Science.gov (United States)

    Mohammadi, Majid; Ghasemi, Ali; Tavoosi, Majid

    2016-12-01

    Mechanochemical synthesis and magnetic characterization of nanocrystalline Fe and Fe-B magnetic alloys was the goal of this study. In this regard, different Fe2O3-B2O3 powder mixtures with sufficient amount of CaH2 were milled in a planetary ball mill in order to produce nanocrystalline Fe, Fe95B5 and Fe85B15 alloys. The produced samples were characterized using X-ray diffraction (XRD), differential scanning calorimetry (DSC), scanning electron microscopy (SEM) and vibrating sample magnetometer (VSM). The results showed that, nanocrystalline Fe, Fe95B5 and Fe85B15 alloys can be successfully synthesized by the reduction reaction of Fe2O3 and B2O3 with CaH2 during mechanical alloying. The structure of produced Fe95B5 and Fe85B15 alloys was a combination of Fe and Fe2B phases with average crystallite sizes of about 15 and 10 nm, respectively. The produced nanocrystalline alloys exhibited soft magnetic properties with the coercivity and saturation of magnetization in the range of 170-240 Oe and 9-28 emu/g, respectively. Increasing the boron content has a destructive effect on soft magnetic properties of Fe-B alloys.

  13. UNSHIFTED METASTABLE He I* MINI-BROAD ABSORPTION LINE SYSTEM IN THE NARROW-LINE TYPE 1 QUASAR SDSS J080248.18+551328.9

    Energy Technology Data Exchange (ETDEWEB)

    Ji, Tuo; Zhou, Hongyan; Jiang, Peng; Wang, Tinggui; Wang, Huiyuan; Liu, Wenjuan; Yang, Chenwei [Polar Research Institute of China, 451 Jinqiao Road, Pudong, Shanghai 200136 (China); Ge, Jian; Hamann, Fred [Department of Astronomy, University of Florida, Gainesville, FL 32611 (United States); Komossa, S.; Yuan, Weimin [National Astronomical Observatories, Chinese Academy of Sciences, 20A Datun Road, Beijing 100012 (China); Zuther, Jens [Physikalisches Institut, Universität zu Köln, Zülpicher Strasse 77, D-50937 Köln (Germany); Lu, Honglin [Key Laboratory for Research in Galaxies and Cosmology, The University of Science and Technology of China, Chinese Academy of Sciences, Hefei, Anhui, 230026 (China); Zuo, Wenwen, E-mail: jituo@pric.gov.cn [Shanghai Astronomical Observatory, Nandan Road 80, Shanghai 200030 (China)

    2015-02-10

    We report the identification of an unusual absorption-line system in the quasar SDSS J080248.18+551328.9 and present a detailed study of the system, incorporating follow-up optical and near-IR spectroscopy. A few tens of absorption lines are detected, including He I*, Fe II*, and Ni II*, which arise from metastable or excited levels, as well as resonant lines in Mg I, Mg II, Fe II, Mn II, and Ca II. All of the isolated absorption lines show the same profile of width Δv ∼ 1500 km s{sup –1} centered at a common redshift as that of the quasar emission lines, such as [O II], [S II], and hydrogen Paschen and Balmer series. With narrow Balmer lines, strong optical Fe II multiplets, and weak [O III] doublets, its emission-line spectrum is typical for that of a narrow-line Seyfert 1 galaxy (NLS1). We have derived reliable measurements of the gas-phase column densities of the absorbing ions/levels. Photoionization modeling indicates that the absorber has a density of n {sub H} ∼ (1.0-2.5) × 10{sup 5} cm{sup –3} and a column density of N {sub H} ∼ (1.0-3.2) × 10{sup 21} cm{sup –2} and is located at R ∼100-250 pc from the central supermassive black hole. The location of the absorber, the symmetric profile of the absorption lines, and the coincidence of the absorption- and emission-line centroid jointly suggest that the absorption gas originates from the host galaxy and is plausibly accelerated by stellar processes, such as stellar winds and/or supernova explosions. The implications for the detection of such a peculiar absorption-line system in an NLS1 are discussed in the context of coevolution between supermassive black hole growth and host galaxy buildup.

  14. The effect of FeF{sub 2} on the magneto-optic response in FeF{sub 2}/Fe/FeF{sub 2} sandwiches

    Energy Technology Data Exchange (ETDEWEB)

    Pistora, J; Lesnak, M [Institute of Physics, VSB-Technical University of Ostrava (Czech Republic); Liskova, E; Visnovsky, S [Institute of Physics, Charles University, Prague (Czech Republic); Harward, I; Maslankiewicz, P; Balin, K; Celinski, Z [Center for Magnetism and Magnetic Nanostructures, University of Colorado at Colorado Springs, Colorado Springs, CO 80918 (United States); MistrIk, J; Yamaguchi, T [Research Institute of Electronics, Shizuoka University, Hamamatsu (Japan); Lopusnik, R [Seagate Technology, 7801 Computer Ave., Bloomington, MN 55435 (United States); Vlcek, J, E-mail: jaromir.pistora@vsb.c [Department of Mathematics and Descriptive Geometry, VSB-Technical University of Ostrava (Czech Republic)

    2010-04-21

    The room temperature optical constants n and k of MBE grown FeF{sub 2} films are reported. Because of poor chemical stability, FeF{sub 2} had to be coated with a protective Au layer. Reflection spectral ellipsometry in the photon energy range between 1.3 and 5.2 eV was performed on structures with a typical profile Au(0.5 nm)/FeF{sub 2}(120 nm)/Au(30 nm)/Ag(20 nm)/Fe(0.6 nm) grown on GaAs(0 0 1) substrate. The spectra of n and k in FeF{sub 2} were subsequently employed in the design of FeF{sub 2}/Fe/FeF{sub 2} sandwiches considered as magneto-optic (MO) sensors for weak microwave currents. Their MO response was evaluated using reflection MO (Kerr) spectroscopy at polar magnetization. The present results may be of interest in MO studies of magnetic nanostructures with Fe/FeF{sub 2}/Fe, including MO magnetometry and MO magnetic domain imaging.

  15. Bias voltage effects on tunneling magnetoresistance in Fe/MgAl2O4/Fe (001 ) junctions: Comparative study with Fe/MgO/Fe(001) junctions

    Science.gov (United States)

    Masuda, Keisuke; Miura, Yoshio

    2017-08-01

    We investigate bias voltage effects on the spin-dependent transport properties of Fe/MgAl 2O 4 /Fe(001) magnetic tunneling junctions (MTJs) by comparing them with those of Fe/MgO/Fe(001) MTJs. By means of the nonequilibrium Green's function method and the density functional theory, we calculate bias voltage dependencies of magnetoresistance (MR) ratios in both the MTJs. We find that in both the MTJs, the MR ratio decreases as the bias voltage increases and finally vanishes at a critical bias voltage Vc. We also find that the critical bias voltage Vc of the MgAl 2O 4 -based MTJ is clearly larger than that of the MgO-based MTJ. Since the in-plane lattice constant of the Fe/MgAl 2O 4 /Fe(001) supercell is twice that of the Fe/MgO/Fe(001) one, the Fe electrodes in the MgAl 2O 4 -based MTJs have an identical band structure to that obtained by folding the Fe band structure of the MgO-based MTJs in the Brillouin zone of the in-plane wave vector. We show that such a difference in the Fe band structure is the origin of the difference in the critical bias voltage Vc between the MgAl 2O 4 - and MgO-based MTJs.

  16. Mechanochemical synthesis of Fe-S materials

    DEFF Research Database (Denmark)

    Jiang, Jianzhong; Larsen, R.K.; Lin, R.

    1998-01-01

    Powder mixtures of metallic iron and sulfur have been milled in a high-energy planetary ball mill and the formation of iron sulfides has been studied by x-ray diffraction, Mossbauer spectroscopy, and scanning electron microscopy. For Fe:S ratios of 1:1 and 1:2 the final products are FeS with the ......Powder mixtures of metallic iron and sulfur have been milled in a high-energy planetary ball mill and the formation of iron sulfides has been studied by x-ray diffraction, Mossbauer spectroscopy, and scanning electron microscopy. For Fe:S ratios of 1:1 and 1:2 the final products are Fe......S with the modified NiAs structure and FeS2 (pyrite), respectively. No other iron sulfides were formed for any of the Fe:S ratios studied. The FeS phase has been tested as an electrode material in lithium batteries....

  17. Mineralogy, 57Fe Mössbauer spectra and magnetization of chalcolithic pottery

    Science.gov (United States)

    Keller, R.; Masch, L.; Pohl, J.; Schmidbauer, E.

    2005-06-01

    Three chalcolithic pottery sherds, paint removed from the surface of each sherd, and an unheated red pigment (Tell-Halaf culture, Turkey) were analysed within the frame of archaeometric studies using mineralogical methods, 57Fe Mössbauer spectroscopy, magnetization and rotational hysteresis data. From mineralogical results, the individual minerals forming the cores of the sherds were determined. It was found that the sherds are lime-rich. High temperature X-ray analysis on comparable Ca-rich material showed that the established composition is consistent with a firing temperature of 750-950°C. Apart from the pigment, each Mössbauer spectrum of Fe-bearing components consists of dominating paramagnetic doublets, arising mostly from silicate phases, and of a six-line pattern with reduced intensity, due to ferri- and/or antiferromagnetic Fe-oxide phases. For three samples, an Fe3+ silicate component of the spectra is clearly dominating, which points to oxidizing conditions during firing. For the others Fe2+ and Fe3+ components occur in about equal intensities. For the pigment, the magnetic sextet is of similar intensity to the Fe3+ silicate component. From magnetic analysis of ferrimagnetic phases it follows that a low percentage of particles of solid solutions γ-Fe2O3 Fe3O4 exist, probably in part ≤0.1 μm in diameter. The ferrimagnetic particles of at least one paint are probably covered by a thin layer of hematite as found from rotational hysteresis data. An attempt is made to draw conclusions from the experimental results, regarding the firing conditions of the sherds and paints.

  18. NGC 6752 AGB stars revisited. I. Improved AGB temperatures remove apparent overionisation of Fe I

    Science.gov (United States)

    Campbell, S. W.; MacLean, B. T.; D'Orazi, V.; Casagrande, L.; de Silva, G. M.; Yong, D.; Cottrell, P. L.; Lattanzio, J. C.

    2017-09-01

    Context. A recent study reported a strong apparent depression of Fe i, relative to Fe II, in the AGB stars of NGC 6752. This depression is much greater than that expected from the neglect of non-local thermodynamic equilibrium effects, in particular the dominant effect of overionisation. The iron abundances derived from Fe I were then used to scale all other neutral species in the study. Aims: Here we attempt to reproduce the apparent Fe discrepancy, and investigate differences in reported sodium abundances. Methods: We compare in detail the methods and results of the recent study with those of an earlier study of NGC 6752 AGB stars. Iron and sodium abundances are derived using Fe i, Fe II, and Na I lines. We explore various uncertainties to test the robustness of our abundance determinations. Results: We reproduce the large Fe I depression found by the recent study, using different observational data and computational tools. Further investigation shows that the degree of the apparent Fe I depression is strongly dependent on the adopted stellar effective temperature. To minimise uncertainties in Fe I we derive temperatures for each star individually using the infrared flux method (IRFM). We find that the Teff scales used by both the previous studies are cooler, by up to 100 K; such underestimated temperatures amplify the apparent Fe I depression. Our IRFM temperatures result in negligible apparent depression, consistent with theory. We also re-derived sodium abundances and, remarkably, found them to be unaffected by the new temperature scale. [Na/H] in the AGB stars is consistent between all studies. Since Fe is constant, it follows that [Na/Fe] is also consistent between studies, apart from any systematic offsets in Fe. Conclusions: We recommend the use of (V-K) relations for AGB stars, based on comparisons with our individually-derived IRFM temperatures, and their inherently low uncertainties. We plan to investigate the effect of the improved temperature scale on

  19. Intrinsic Absorption in the Spectrum of Mrk 279: Simultaneous Chandra, FUSE, and STIS Observations

    OpenAIRE

    Scott, Jennifer E.; Kriss, Gerard A.; Lee, Julia C; Arav, Nahum; Ogle, Patrick; Roraback, Kenneth; Weaver, Kimberly; Alexander, Tal; Brotherton, Michael; Green, Richard F.; Hutchings, John; Kaiser, Mary Elizabeth; Marshall, Herman; Oegerle, William; Zheng, Wei

    2004-01-01

    We present a study of the intrinsic X-ray and far-ultraviolet absorption in the Seyfert 1.5 galaxy Markarian 279 using simultaneous observations from the Chandra X-ray Observatory, the Space Telescope Imaging Spectrograph aboard the Hubble Space Telescope, and the Far Ultraviolet Spectroscopic Explorer (FUSE). We also present FUSE observations made at three additional epochs. We detect the Fe K-alpha emission line in the Chandra spectrum, and its flux is consistent with the low X-ray continuu...

  20. Fe II emission in AGN

    Directory of Open Access Journals (Sweden)

    M. Joly

    2008-01-01

    Full Text Available El espectro óptico de las galaxias Seyfert 1 muestra una gran variedad de líneas de emisión producidas por FeII. Damos tres ejemplos e investigamos la formación de estas líneas con el fin de determinar las condiciones físicas de las regiones en donde se emiten.

  1. Grain size effect on the Neel temperature and magnetic properties of nanocrystalline $NiFe{_2}O{_4}$ spinel

    OpenAIRE

    Chinnasamy, CN; Narayanasamy, A.; Ponpandian, N; Joseyphus, RJ; Jeyadevan, B.; Tohji, K.; Chattopadhyay, K.

    2002-01-01

    Nanocrystalline NiFe2O4 spinel ferrites with various grain sizes have been synthesized by ball milling the bulk NiFe2O4. The average grain sizes were estimated from the X-ray line broadening of the (3 1 1) reflection. The Neel temperatures of NiFe2O4 for various grain sizes were determined by magneto thermogravimetric method. The magnetic behaviour has been explained by combining the effects of changes in cation distribution on milling and finite size scaling. The shift in B-H loops has been ...

  2. 2009 Santa Fe Bone symposium.

    Science.gov (United States)

    Lewiecki, E Michael; Bilezikian, John P; Laster, Andrew J; Miller, Paul D; Recker, Robert R; Russell, R Graham G; Whyte, Michael P

    2010-01-01

    Osteoporosis is a common skeletal disease with serious clinical consequences because of fractures. Despite the availability of clinical tools to diagnose osteoporosis and assess fracture risk, and drugs proven to reduce fracture risk, it remains a disease that is underdiagnosed and undertreated. When treatment is started, it is commonly not taken correctly or long enough to be effective. Recent advances in understanding of the regulators and mediators of bone remodeling have led to new therapeutic targets and the development of drugs that may offer advantages over current agents in reducing the burden of osteoporotic fractures. Many genetic factors that play a role in the pathogenesis of osteoporosis and metabolic bone disease have now been identified. At the 2009 Santa Fe Bone Symposium, held in Santa Fe, New Mexico, USA, the links between advances in genetics, basic bone science, recent clinical trials, and new and emerging therapeutic agents were presented and explored. Socioeconomic challenges and opportunities in the care of osteoporosis were discussed. This is a collection of medical essays based on key presentations at the 2009 Santa Fe Bone Symposium.

  3. Magnetostriction of FM/TbFe (FM=Fe, Py-permalloy, FeCo) coupled bilayer

    Energy Technology Data Exchange (ETDEWEB)

    Li Jianjun, E-mail: ljj8081@tom.com [National Key Laboratory of Science and Technology on Advanced Composites in Special Environments, Harbin Institute of Technology, Harbin150080 (China); Laboratoire de Magnetisme de Bretagne-CNRS FRE 3117, Universite de Bretagne Occidentale, 6, Avenue le Gorgeu C.S. 93837, 29238 Brest Cedex 3 (France)

    2012-04-15

    Choosing TbFe as the magnetostrictive layer and using soft ferromagnetic materials (FM=Fe, Py-permalloy, FeCo) as the inductive layer, we report the magnetization and magnetostriction of the S/FM(10 nm)/TbFe(10 nm) coupled bilayer (S-glass substrate). The magnetization of the coupled bilayer is attributed to the soft ferromagnetic layer and there is no contribution from the TbFe layer. Interfacial exchange interaction plays an important role in determining the magnetostriction of the coupled bilayer. The effect coming from the deposition Argon pressure on the magnetostriction of the coupled bilayer was also investigated. - Highlights: Black-Right-Pointing-Pointer Choosing TbFe as magnetostrictive layer and with soft ferromagnetic material (FM=Fe, Py-permalloy, FeCo) as inductive layer. Black-Right-Pointing-Pointer We report the magnetization and magnetostriction of the S/FM(10 nm)/TbFe(10 nm) coupled bilayer (S-glass substrate). Black-Right-Pointing-Pointer The magnetization of coupled bilayer is attributed to soft ferromagnetic layer and there is no contribution from TbFe layer. Black-Right-Pointing-Pointer Interfacial exchange interaction plays an important role in determining the magnetostriction of the coupled bilayer.

  4. Line Lengths and Starch Scores.

    Science.gov (United States)

    Moriarty, Sandra E.

    1986-01-01

    Investigates readability of different line lengths in advertising body copy, hypothesizing a normal curve with lower scores for shorter and longer lines, and scores above the mean for lines in the middle of the distribution. Finds support for lower scores for short lines and some evidence of two optimum line lengths rather than one. (SKC)

  5. Efficient use of Fe metal as an electron transfer agent in a heterogeneous Fenton system based on Fe0/Fe3O4 composites.

    Science.gov (United States)

    Moura, Flávia C C; Araujo, Maria Helena; Costa, Regina C C; Fabris, José D; Ardisson, José D; Macedo, Waldemar A A; Lago, Rochel M

    2005-08-01

    In this work a novel heterogeneous Fenton system based on Fe(0)/Fe3O4 composites is described. The composites with several Fe(0)/Fe3O4 ratios were prepared by two different methods, i.e. mechanical alloying of Fe(0) and Fe3O4 powders and controlled reduction of Fe3O4 with H2. Reaction studies and detailed Conversion Electron Mössbauer surface characterization of the composites Fe(0)/Fe3O4, Fe(0), Fe3O4, alpha-Fe2O3 and gamma-Fe2O3 suggested that Fe2+surf species are essential to produce an active Fenton system. Kinetic studies for the oxidation of the dye methylene blue, used as an organic model molecule, and for the peroxide decomposition suggest that the reactions proceed via HO* radicals generated from Fe2+surf species and H2O2 in a Fenton like mechanism. The increase in activity caused by the addition of Fe(0) is discussed in terms of a creation of Fe2+surf species during the preparation of the composite and by an electron transfer mechanism from Fe(0) to Fe3+surf during the Fenton reaction to regenerate the Fe2+surf active species.

  6. Optical Properties of ZnFe2O4-SiO2 Granular Films Prepared by Radio-Frequency Magnetron Sputtering

    Institute of Scientific and Technical Information of China (English)

    晋云霞; 李广海; 张云霞; 张立德

    2002-01-01

    We report on the optical properties of ZnFe2O4-SiO2 granular films prepared on quartz substrates by the radio-frequency magnetron sputtering method. Post-annealing was performed at different temperatures under flow oxygen atmosphere. The morphology and structures of ZnFe2 O4 nanoparticles were characterized by x-ray diffraction, transmission electron microscopy and optical absorption spectra. It has been found that there are two different line types in the optical absorption curves of ZnFe2 O4-SiO2 granular films. The critical transition of line types occurs when ZnFe2O4 changes from amorphous to crystalline, and the transition temperature increases with the increasing content of ZnFe2O4. There is an obvious blueshift of the optical absorption edge of the granular films with the decreasing annealing temperature.

  7. The Line of Sight to HD 206267

    Science.gov (United States)

    Green, James C.

    This proposal requests an observation of HD 206267 (O6, E(B-V) = 0.52). An IUE observation of this target will allow the measurement of several atomic and molecular lines that, when combined with a high resolution sounding rocket observation (scheduled for 1993) will allow a detailed study of transluscent cloud chemistry. In addition, the independent rocket observation of molecular CO will allow a test of CO determinations using IUE, which has been a topic of some concern recently. In addition to the CO lines, we intend to observe lines of CI, CII, OI, Fe, Mg and Mn. In coordination with the H2 measurements with the rocket data, and HI determination from Ly-alpha (using the methods of Bohlin 1975; Shull and Van Steenberg 1985) we will be able to determine accurate depletions and quantify the cloud chemistry to a level not previously possible. This data will form a part of the Lead-Investigator's Ph.D. thesis.

  8. Effect of spatial spin modulation on relaxation and NMR frequencies of sup 5 sup 7 Fe nuclei in ferroelectric antiferromagnetic BiFeO sub 3

    CERN Document Server

    Zalessky, A V; Zvezdin, A K; Gippius, A A; Morozova, E N; Khozeev, D F; Bush, A S; Pokatilov, V S

    2002-01-01

    The NMR spectra on the iron nuclei in the BiFeO sub 3 antiferromagnetic sample enriched by the sup 5 sup 7 Fe (95.43%) with the spatially-modulated magnetic structure are studied. It is established that the cycloid-type spin modulation in the BiFeO sub 3 produces spatial modulation of the nuclear spin-spin relaxation velocity and leads to the spectral nonuniform widening of the NMR local line. It is determined also that the local magnetic moments of the iron ions on various cycloid sections differently depend on temperature which testifies to different character of the spin waves excitation. The analogy of the experimental results with the NMR regularities in the Bloch wall is discussed

  9. Effect of Fe Particle on the Surface Peeling in Cu-Fe-P Lead Frame

    Institute of Scientific and Technical Information of China (English)

    SU Juanhua; LIU Ping; DONG Qiming; LI Hejun; TIAN Baohong

    2006-01-01

    Under the surface peeling of Cu-Fe-P lead frame alloy larger Fe particles were observed by energy dispersive spectroscopy. By using the large strain two-dimension plane strain model and elastic-plastic finite element method, the cause for peeling damage of Cu-Fe-P lead frame alloy was investigated. The results show that when the content of Fe particles is more than 30% at local Fe-rich area the intense stress concentration in the Fe particle would make the Fe particle broken up. The high equivalent stress mutation and the mismatch of equivalent strain 10% at the two sides of interface make it easy to develop the crack and peeling damage on finish rolling. The larger Fe particles in the Cu-Fe-P alloy should be avoided.

  10. DETECTION OF REST-FRAME OPTICAL LINES FROM X-SHOOTER SPECTROSCOPY OF WEAK EMISSION-LINE QUASARS

    Energy Technology Data Exchange (ETDEWEB)

    Plotkin, Richard M.; Gallo, Elena [Department of Astronomy, University of Michigan, 1085 South University Avenue, Ann Arbor, MI 48109 (United States); Shemmer, Ohad [Department of Physics, University of North Texas, Denton, TX 76203 (United States); Trakhtenbrot, Benny [Institute for Astronomy, Department of Physics, ETH Zurich, Wolfgang-Pauli-Strasse 27, CH-8093 Zurich (Switzerland); Anderson, Scott F. [Department of Astronomy, University of Washington, Box 351580, Seattle, WA 98195 (United States); Brandt, W. N.; Luo, Bin; Schneider, Donald P. [Department of Astronomy and Astrophysics, 525 Davey Lab, The Pennsylvania State University, University Park, PA 16802 (United States); Fan, Xiaohui [Steward Observatory, University of Arizona, 933 North Cherry Avenue, Tucson, AZ 85721 (United States); Lira, Paulina [Departamento de Astronomia, Universidad de Chile, Camino del Observatorio 1515, Santiago (Chile); Richards, Gordon T. [Department of Physics, Drexel University, 3141 Chestnut Street, Philadelphia, PA 19104 (United States); Strauss, Michael A. [Department of Astrophysical Sciences, Princeton University, Princeton, NJ 08544 (United States); Wu, Jianfeng, E-mail: rplotkin@umich.edu [Harvard-Smithsonian Center for Astrophysics, MS 6, 60 Garden Street Cambridge, MA 02138 (United States)

    2015-06-01

    Over the past 15 yr, examples of exotic radio-quiet quasars with intrinsically weak or absent broad emission line regions (BELRs) have emerged from large-scale spectroscopic sky surveys. Here, we present spectroscopy of seven such weak emission line quasars (WLQs) at moderate redshifts (z = 1.4–1.7) using the X-shooter spectrograph, which provides simultaneous optical and near-infrared spectroscopy covering the rest-frame ultraviolet (UV) through optical. These new observations effectively double the number of WLQs with spectroscopy in the optical rest-frame, and they allow us to compare the strengths of (weak) high-ionization emission lines (e.g., C iv) to low-ionization lines (e.g., Mg ii, Hβ, Hα) in individual objects. We detect broad Hβ and Hα emission in all objects, and these lines are generally toward the weaker end of the distribution expected for typical quasars (e.g., Hβ has rest-frame equivalent widths ranging from 15–40 Å). However, these low-ionization lines are not exceptionally weak, as is the case for high-ionization lines in WLQs. The X-shooter spectra also display relatively strong optical Fe ii emission, Hβ FWHM ≲ 4000 km s{sup −1}, and significant C iv blueshifts (≈1000–5500 km s{sup −1}) relative to the systemic redshift; two spectra also show elevated UV Fe ii emission, and an outflowing component to their (weak) Mg ii emission lines. These properties suggest that WLQs are exotic versions of “wind-dominated” quasars. Their BELRs either have unusual high-ionization components, or their BELRs are in an atypical photoionization state because of an unusually soft continuum.

  11. Magnetostrictive GMR spin valves with composite FeGa/FeCo free layers

    Directory of Open Access Journals (Sweden)

    Luping Liu

    2016-03-01

    Full Text Available We have fabricated strain-sensitive spin valves on flexible substrates by utilizing the large magnetostrictive FeGa alloy to promote the strain sensitivity and the composite free layer of FeGa/FeCo to avoid the drastic reduction of giant magnetoresistance (GMR ratio. This kind of spin valve (SV-FeGa/FeCo displays a MR ratio about 5.9%, which is comparable to that of the conventional spin valve (SV-FeCo with a single FeCo free layer. Different from the previously reported works on magnetostrictive spin valves, the SV-FeGa/FeCo displays an asymmetric strain dependent GMR behavior. Upon increasing the lateral strain, the MR ratio for the ascending branch decreases more quickly than that for the descending branch, which is ascribed to the formation of a spiraling spin structure around the FeGa/FeCo interface under the combined influences of both magnetic field and mechanical strain. A strain sensitivity of GF = 7.2 was achieved at a magnetic bias field of -30 Oe in flexible SV-FeGa/FeCo, which is significantly larger than that of SV-FeCo.

  12. Magnetostrictive GMR spin valves with composite FeGa/FeCo free layers

    Science.gov (United States)

    Liu, Luping; Zhan, Qingfeng; Yang, Huali; Li, Huihui; Zhang, Shuanglan; Liu, Yiwei; Wang, Baomin; Tan, Xiaohua; Li, Run-Wei

    2016-03-01

    We have fabricated strain-sensitive spin valves on flexible substrates by utilizing the large magnetostrictive FeGa alloy to promote the strain sensitivity and the composite free layer of FeGa/FeCo to avoid the drastic reduction of giant magnetoresistance (GMR) ratio. This kind of spin valve (SV-FeGa/FeCo) displays a MR ratio about 5.9%, which is comparable to that of the conventional spin valve (SV-FeCo) with a single FeCo free layer. Different from the previously reported works on magnetostrictive spin valves, the SV-FeGa/FeCo displays an asymmetric strain dependent GMR behavior. Upon increasing the lateral strain, the MR ratio for the ascending branch decreases more quickly than that for the descending branch, which is ascribed to the formation of a spiraling spin structure around the FeGa/FeCo interface under the combined influences of both magnetic field and mechanical strain. A strain sensitivity of GF = 7.2 was achieved at a magnetic bias field of -30 Oe in flexible SV-FeGa/FeCo, which is significantly larger than that of SV-FeCo.

  13. FeLoBAL Outflow Variability Constraints from Multi-Year Observations

    CERN Document Server

    McGraw, Sean M; Hamann, Frederick W; Capellupo, Daniel M; Gallagher, Sarah C; Brandt, William N

    2013-01-01

    The physical properties and dynamical behavior of Broad Absorption Line (BAL) outflows are crucial themes in understanding the connections between galactic centers and their hosts. FeLoBALs (identified with the presence of low-ionization Fe II BALs) are a peculiar class of quasar outflows that constitute approximately 1% of the BAL population. With their large column densities and apparent outflow kinetic luminosities, FeLoBALs appear to be exceptionally powerful and are strong candidates for feedback in galaxy evolution. We conducted variability studies of 12 FeLoBAL quasars with emission redshifts between 0.69 and 1.93, spanning both weekly and multi-year timescales in the quasar's rest frame. We detected absorption-line variability from low-ionization species (Fe II, Mg II) in four of our objects, with which we established a representative upper limit for the distance of the absorber from the supermassive black hole (SMBH) to be approximately 20 parsecs. Our goals are to understand the mechanisms producing...

  14. Magnetic fluctuations in nanosized goethite ({alpha}-FeOOH) grains

    Energy Technology Data Exchange (ETDEWEB)

    Madsen, D E; Frandsen, C; Moerup, S [Department of Physics, Building 307, Technical University of Denmark, DK-2800 Kongens Lyngby (Denmark); Cervera-Gontard, L; Dunin-Borkowski, R E [Center for Electron Nanoscopy, Building 307, Technical University of Denmark, DK-2800 Kongens Lyngby (Denmark); Kasama, T [Department of Materials Science and Metallurgy, University of Cambridge, Pembroke Street, Cambridge CB2 3QZ (United Kingdom); Koch, C B [Department of Natural Sciences, Faculty of Life Sciences, University of Copenhagen, Thorvaldsensvej 40, DK-1871 Frederiksberg C (Denmark); Hansen, M F [Department of Micro- and Nanotechnology, Technical University of Denmark, DTU Nanotech, Building 345 East, DK-2800 Kongens Lyngby (Denmark)], E-mail: Mikkel.Hansen@nanotech.dtu.dk

    2009-01-07

    Moessbauer spectra of antiferromagnetic goethite ({alpha}-FeOOH) particles usually show an asymmetric line broadening, which increases with increasing temperature, although the magnetic anisotropy is expected to be so large that magnetic relaxation effects should be negligible. By use of high resolution transmission electron microscopy we have studied a sample of goethite particles and have found that the particles contain many defects such as low angle grain boundaries, in accordance with previous studies of other samples of goethite particles. Such defects can result in a magnetic mismatch at the grain boundaries between nanometer-sized grains, leading to a weakened magnetic coupling between the grains. We show that the Moessbauer data of goethite can be explained by fluctuations of the sublattice magnetization directions in such weakly coupled grains. It is likely that the influence of defects such as low angle grain boundaries also plays a role with regards to the magnetic properties in other antiferromagnetic nanograin systems. We discuss the results in relation to Moessbauer studies of {alpha}-Fe{sub 2}O{sub 3} and {alpha}-Fe{sub 2}O{sub 3}/NiO nanoparticles.

  15. High-resolution H-band spectroscopy of Be stars with SDSS-III/apogee. I. New Be stars, line identifications, and line profiles

    Energy Technology Data Exchange (ETDEWEB)

    Chojnowski, S. Drew; Majewski, Steven R.; Hall, Matthew; Beaton, Rachael; Burton, Adam; Damke, Guillermo; Wilson, John [Department of Astronomy, University of Virginia, P.O. Box 400325, Charlottesville, VA 22904-4325 (United States); Whelan, David G. [Department of Physics, Austin College, 900 N. Grand Ave., Sherman, TX 75090 (United States); Wisniewski, John P. [Department of Physics and Astronomy, The University of Oklahoma, 440 W. Brooks St., Norman, OK 73019 (United States); Shetrone, Matthew [Department of Astronomy, The University of Texas at Austin, 2515 Speedway, Stop C1400 Austin, Texas 78712-1205 (United States); Eikenberry, Steve [Department of Astronomy, University of Florida, 211 Bryant Space Science Center, Gainesville, FL 32611-2055 (United States); Hasselquist, Sten; Holtzman, Jon A.; Brewington, Howard; Brinkmann, J. [Apache Point Observatory and New Mexico State University, P.O. Box 59, Sunspot, NM, 88349-0059 (United States); Mészáros, Szabolcs [ELTE Gothard Astrophysical Observatory, 1H-9704 Szombathely, Szent Imre herceg st. 112 (Hungary); Nidever, David [Department of Astronomy, University of Michigan, 830 Dennison, 500 Church St., Ann Arbor, MI 48109-1042 (United States); Schneider, Donald P. [Department of Astronomy and Astrophysics, The Pennsylvania State University, University Park, PA 16802 (United States); Zasowski, Gail [Department of Physics and Astronomy, Johns Hopkins University, Bloomberg Center for Physics and Astronomy, Room 366, 3400 N. Charles Street, Baltimore, MD 21218 (United States); Bizyaev, Dmitry, E-mail: drewski@virginia.edu [Institute for Gravitation and the Cosmos, The Pennsylvania State University, University Park, PA 16802 (United States); and others

    2015-01-01

    The Apache Point Observatory Galactic Evolution Experiment (APOGEE) has amassed the largest ever collection of multi-epoch, high-resolution (R∼22,500), H-band spectra for B-type emission line (Be) stars. These stars were targeted by APOGEE as telluric standard stars and subsequently identified via visual inspection as Be stars based on H i Brackett series emission or shell absorption in addition to otherwise smooth continua and occasionally non-hydrogen emission features. The 128/238 APOGEE Be stars for which emission had never previously been reported serve to increase the total number of known Be stars by ∼6%. Because the H band is relatively unexplored compared to other wavelength regimes, we focus here on identification of the H-band lines and analysis of the emission peak velocity separations (Δv{sub p}) and emission peak intensity ratios (V/R) of the usually double-peaked H i and non-hydrogen emission lines. H i Br11 emission is found to preferentially form in the circumstellar disks at an average distance of ∼2.2 stellar radii. Increasing Δv{sub p} toward the weaker Br12–Br20 lines suggests these lines are formed interior to Br11. By contrast, the observed IR Fe ii emission lines present evidence of having significantly larger formation radii; distinctive phase lags between IR Fe ii and H i Brackett emission lines further supports that these species arise from different radii in Be disks. Several emission lines have been identified for the first time including C i 16895, a prominent feature in the spectra for almost a fifth of the sample and, as inferred from relatively large Δv{sub p} compared to the Br11–Br20, a tracer of the inner regions of Be disks. Emission lines at 15760 Å and 16781 Å remain unidentified, but usually appear along with and always have similar line profile morphology to Fe ii 16878. Unlike the typical metallic lines observed for Be stars in the optical, the H-band metallic lines, such as Fe ii 16878, never exhibit any

  16. An experimental observation of the different behavior of ionic and neutral lines of iron as a function of number density in a binary carbon–iron mixture

    Energy Technology Data Exchange (ETDEWEB)

    Sivakumar, P.; Taleh, L.; Markushin, Y. [Optical Science Center for Applied Research and Applications, Department of Physics and Pre-Engineering, Delaware State University, Dover, DE 19901 (United States); Melikechi, N., E-mail: nmelikechi@desu.edu [Optical Science Center for Applied Research and Applications, Department of Physics and Pre-Engineering, Delaware State University, Dover, DE 19901 (United States); Lasue, J. [Université de Toulouse, UPS-OMP, IRAP, 9 Av. Colonel Roche, BP 44346, F-31028 Toulouse Cedex 4 (France); ISR, MS D466, Los Alamos National Laboratory, Los Alamos, NM 87545 (United States); Lunar and Planetary Institute, 3600 Bay Area Boulevard, Houston, TX 77058 (United States)

    2013-04-01

    We report on the dependence of the intensities of atomic and ionic lines emitted by a nanosecond laser-induced plasma on the atomic number densities of the constituents of a binary mixture formed of carbon and iron. We show that the packing density of the sample greatly affects the relative standard deviation of the emission lines. Furthermore, we show that the variation of the intensities of the C and Fe emission lines depends in a non-trivial way on the relative C–Fe concentration. The intensities of Fe neutral atomic lines behave differently than those of the ionic ones particularly at and above concentrations of 75%–80% Fe embedded in a carbon matrix. Unlike the emission from neutral Fe, those from ionic Fe yield a very sharp decrease followed by an equally strong increase of the emission lines over a relatively small range of relative concentration of C and Fe. To better investigate this effect, we have compared the results obtained with nanosecond-LIBS to those with femtosecond-LIBS and found that this phenomenon disappears. The physical interpretation of the sharp decrease followed by an equally sharp increase in the emission intensities from Fe ions as the concentration of Fe is increased requires more studies. - Highlights: ► The effects of the size of the particles on the fluctuations of the LIBS signals ► The variation of LIBS signals with the concentrations of Fe embedded in C is nontrivial. ► The intensities of neutral atomic lines can behave differently than those of ions.

  17. Synthesis and Raman scattering of multiferroic Fe-Pb(Zr{sub 0.2}Ti{sub 0.8})O{sub 3} core-shell wire arrays

    Energy Technology Data Exchange (ETDEWEB)

    Baibarac, Mihaela; Sima, Marian; Matei, Elena; Pasuk, Iuliana; Mihut, Lucian [National Institute of Materials Physics, Magurele (Romania)

    2014-01-15

    A new method to fabricate an Fe-PZT core-shell wire arrays developed in three steps is reported in this paper. This involves the electrochemical growth of an iron wire array by template method, deposition by spin coating of the PZT precursor prepared by sol-gel technique on the iron wires surface and annealing treatment to obtain Fe-PZT core-shell structures. The structure of the Fe-PZT core-shell wire array was characterized by scanning electron microscopy (SEM) and Raman scattering. Raman lines situated at 372 and 575 cm{sup -1} indicate the formation of the FeO particles on the Fe wires surface as a result of the use of an aqueous solution for electrochemical synthesis. An upshift of Raman lines of Fe decorated with FeO wires was observed after formation of Fe-PZT core-shell structure. The annealing treatment of this structure involves a partial transformation of the FeO into Fe{sub 2}O{sub 3} particles both with structure rhombohedral and cubic that were evidenced by Raman lines peaked at 243 and 497 cm{sup -1}, respectively. (copyright 2014 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  18. Interstitial Fe in MgO

    CERN Document Server

    Mølholt, T E; Gunnlaugsson, H P; Svane, A; Masenda, H; Naidoo, D; Bharuth-Ram, K; Fanciulli, M; Gislason, H P; Johnston, K; Langouche, G; Ólafsson, S; Sielemann, R; Weyer, G

    2014-01-01

    Isolated Fe-57 atoms were studied in MgO single-crystals by emission Mossbauer spectroscopy following implantation of Mn-57 decaying to Fe-57. Four Mossbauer spectral components were found corresponding to different Fe lattice positions and/or charge states. Two components represent Fe atoms substituting Mg as Fe2+ and Fe3+, respectively; a third component is due to Fe in a strongly implantation-induced disturbed region. The fourth component, which is the focus of this paper, can be assigned to Fe at an interstitial site. Comparison of its measured isomer shift with ab initio calculations suggests that the interstitial Fe is located on, or close to, the face of the rock-salt MgO structure. To harmonize such an assignment with the measured near-zero quadrupole interaction a local motion process (cage motion) of the Fe has to be stipulated. The relation of such a local motion as a starting point for long range diffusion is discussed.

  19. VT Digital Line Graph Railroads

    Data.gov (United States)

    Vermont Center for Geographic Information — (Link to Metadata) This datalayer is comprised of major railroad lines for the state of Vermont. These railroad lines line up well along quadrangle boundaries, but...

  20. Redox cycling of Fe(II) and Fe(III) in magnetite by Fe-metabolizing bacteria

    Science.gov (United States)

    Byrne, James M.; Klueglein, Nicole; Pearce, Carolyn; Rosso, Kevin M.; Appel, Erwin; Kappler, Andreas

    2015-03-01

    Microorganisms are a primary control on the redox-induced cycling of iron in the environment. Despite the ability of bacteria to grow using both Fe(II) and Fe(III) bound in solid-phase iron minerals, it is currently unknown whether changing environmental conditions enable the sharing of electrons in mixed-valent iron oxides between bacteria with different metabolisms. We show through magnetic and spectroscopic measurements that the phototrophic Fe(II)-oxidizing bacterium Rhodopseudomonas palustris TIE-1 oxidizes magnetite (Fe3O4) nanoparticles using light energy. This process is reversible in co-cultures by the anaerobic Fe(III)-reducing bacterium Geobacter sulfurreducens. These results demonstrate that Fe ions bound in the highly crystalline mineral magnetite are bioavailable as electron sinks and electron sources under varying environmental conditions, effectively rendering magnetite a naturally occurring battery.

  1. Synthesis of high magnetization Fe and FeCo nanoparticles by high temperature chemical reduction

    Energy Technology Data Exchange (ETDEWEB)

    Kandapallil, B; Colborn, RE; Bonitatibus, PJ; Johnson, F

    2015-03-15

    Fe and FeCo ferromagnetic nanoparticles in the 5-10 nm size regimes featuring high magnetization were synthesized using a modified chemical reduction method. The structure and morphology of these nanoparticles were confirmed by XRD and TOM analysis. These small, monodisperse and phase pure nanoparticles exhibited magnetic saturation of 210 emu/g (Fe) and 220 emu/g (Fe+Co) for Fe and FeCo nanoparticles respectively. The magnetization was found to be dependent on the temperature at which the reducing agent was introduced. (C) 2014 Elsevier B.V. All rights reserved,

  2. Effect of Iron Fe (II and Fe (III in a Binary System Evaluated Bioluminescent Method

    Directory of Open Access Journals (Sweden)

    Elena Sorokina

    2013-01-01

    Full Text Available The effect of iron ions Fe2+ and Fe3+ on the bioluminescent recombinant strain of Escherichia coli in a single-component and binary system. Found that for the bacteria E. coli Fe3+ ions are more toxic than Fe2+. Under the combined effect of iron toxicity increases, the percentage of luminescence quenching increases, but the value is much less than the sum of the indicator for the Fe2+ and Fe3+. The biological effect of insertion of iron is not proportional to their content in the mixture.

  3. Fe3O4/MgO/Fe Heteroepitaxial Structures for Magnetic Tunnel Junctions

    Energy Technology Data Exchange (ETDEWEB)

    Orna, J. [University of Zaragoza, Spain; Morellon, Luis [University of Zaragoza, Spain; Algarabel, Pedro A. [University of Zaragoza, Spain; Pardo, J. A. [University of Zaragoza, Spain; Sangiao, S [Instituto de Nanociencia de Aragón, Universidad de Zaragoza, Zaragoza, 50009 Spain; Magen, C [Oak Ridge National Laboratory (ORNL); Snoeck, E. [CEMES-CNRS, Toulouse, France; De Teresa, J M [Instituto de Ciencia de Materiales de Aragón, Universidad de Zaragoza-CSIC, Zaragoza, 50009 Spain; Ibarra, M. Ricardo [University of Zaragoza, Spain

    2008-01-01

    In this work we report the growth and structural and magnetic characterization of heteroepitaxial Fe O/MgO/Fe junctions. All three layers have been deposited by pulsed laser deposition. Combining High Resolution Transmission Electron Microscopy and X-ray results, we have obtained for the heterostructure the epitaxy relation MgO(001) [100]//Fe O(001)[100]/MgO(001) [100]/Fe(001)[110]. All interfaces appear very sharp with relatively small root-mean square (rms) roughness, 0.2 nm. The magnetic coupling between Fe O and Fe electrodes is also very small, 0.03 mJ/

  4. Topological nodal line semimetals

    Science.gov (United States)

    Fang, Chen; Weng, Hongming; Dai, Xi; Fang, Zhong

    2016-11-01

    We review the recent, mainly theoretical, progress in the study of topological nodal line semimetals in three dimensions. In these semimetals, the conduction and the valence bands cross each other along a one-dimensional curve in the three-dimensional Brillouin zone, and any perturbation that preserves a certain symmetry group (generated by either spatial symmetries or time-reversal symmetry) cannot remove this crossing line and open a full direct gap between the two bands. The nodal line(s) is hence topologically protected by the symmetry group, and can be associated with a topological invariant. In this review, (i) we enumerate the symmetry groups that may protect a topological nodal line; (ii) we write down the explicit form of the topological invariant for each of these symmetry groups in terms of the wave functions on the Fermi surface, establishing a topological classification; (iii) for certain classes, we review the proposals for the realization of these semimetals in real materials; (iv) we discuss different scenarios that when the protecting symmetry is broken, how a topological nodal line semimetal becomes Weyl semimetals, Dirac semimetals, and other topological phases; and (v) we discuss the possible physical effects accessible to experimental probes in these materials. Project partially supported by the National Key Research and Development Program of China (Grant Nos. 2016YFA0302400 and 2016YFA0300604), partially by the National Natural Science Foundation of China (Grant Nos. 11274359 and 11422428), the National Basic Research Program of China (Grant No. 2013CB921700), and the “Strategic Priority Research Program (B)” of the Chinese Academy of Sciences (Grant No. XDB07020100).

  5. Mutiwavelength Observations of Radio Galaxy 3C 120 with XMM-Newton

    CERN Document Server

    Ogle, P M; Antonucci, R; Colbert, J W; Malkan, M A; Page, M J; Sasseen, T P; Tornikoski, M

    2004-01-01

    We present XMM-Newton observations of the radio galaxy 3C 120. The hard X-ray spectrum contains a marginally resolved Fe I K-alpha emission line with FWHM=9,000 km/s and an equivalent width of 57 eV. The line arises via fluorescence in a broad-line region with covering fraction of 0.4. There is no evidence of relativistically broad Fe K-alpha, contrary to some previous reports. The normal equivalent widths of the X-ray and optical emission lines exclude a strongly beamed synchrotron component to the hard X-ray and optical continua. There is an excess of 0.3-2 keV soft X-ray continuum over an extrapolation of the hard X-ray power-law, which may arise in a disk corona. Analysis of an archival Chandra image shows that extended emission from the jet and other sources contributes <3% of the total X-ray flux. A break in the X-ray spectrum below 0.6 keV indicates an excess neutral hydrogen column density of N_H=1.57 * 10^21 cm^{-2}. However, the neutral absorber must have an oxygen abundance of <1/50 of the so...

  6. Analysis of () Line Shape

    Indian Academy of Sciences (India)

    Xu Wei; Li Yan

    2014-09-01

    The particles energy distribution is derived directly from the () line shape, which is measured by two sets of OMA. The dissociative excitation of molecular is dominating when the local electron temperature is > 10 eV. The line shape is also simulated by the Monte–Carlo method, the molecular dissociation contributes to 57% neutral atoms and 53% emission intensity in front of the limiter, and 85% neutral atoms and 82% emission intensity in front of the wall. The processes of atoms and molecules influence on the energy balance is discussed in SOL, the power loss from molecular dissociation is 6 × 104 kW at SOL.

  7. Two-Component Structure of the Hbeta Broad-Line Region in Quasars. I. Evidence from Spectral Principal Component Analysis

    CERN Document Server

    Hu, Chen; Ho, Luis C; Ferland, Gary J; Baldwin, Jack A; Wang, Ye

    2012-01-01

    We report on a spectral principal component analysis (SPCA) of a sample of 816 quasars, selected to have small Fe II velocity shifts with spectral coverage in the rest wavelength range 3500--5500 \\AA. The sample is explicitly designed to mitigate spurious effects on SPCA induced by Fe II velocity shifts. We improve the algorithm of SPCA in the literature and introduce a new quantity, \\emph{the fractional-contribution spectrum}, that effectively identifies the emission features encoded in each eigenspectrum. The first eigenspectrum clearly records the power-law continuum and very broad Balmer emission lines. Narrow emission lines dominate the second eigenspectrum. The third eigenspectrum represents the Fe II emission and a component of the Balmer lines with kinematically similar intermediate velocity widths. Correlations between the weights of the eigenspectra and parametric measurements of line strength and continuum slope confirm the above interpretation for the eigenspectra. Monte Carlo simulations demonstr...

  8. Mn and Fe Impurities in Si$_{1-x}$ Ge$_{x}$ alloys

    CERN Multimedia

    2002-01-01

    Following our investigations of Mn and Fe impurities in elemental semiconductors and in silicon in particular by means of on-line $^{57}$Fe Mössbauer spectroscopy, utilizing radioactive $^{57}$Mn$^{+}$ ion beams at ISOLDE, we propose to extend these studies to bulk and epitaxially-grown Si$_{1-x}$Ge$_{x}$ alloys. In these materials, although already successfully employed in electronic devices, little is known about point defects and important harmful 3d impurities. The experiments aim to determine a variety of fundamental properties: The lattice location of ion-implanted Mn/Fe, the electronic and vibrational properties of dilute Fe impurities in different lattice sites, the charge-state and composition dependence of the diffusivity of interstitial Fe on an atomic scale, the reactions and formation of complexes with lattice defects created by the $^{57}$Mn implantation or by the recoil effect in the nuclear decay to the Mössbauer state of $^{57m}$Fe. Feasibility studies in 2003 indicate that these aims can b...

  9. Effects of helium injection mode on void formation in Fe-Ni-Cr alloys

    Science.gov (United States)

    Kimoto, T.; Lee, E. H.; Mansur, L. K.

    1988-09-01

    The effect of the helium injection mode on void formation during ion irradiation of the pure solution-annealing alloys Fe-15Ni-7Cr, Fe-35Ni-7Cr, Fe-45Ni-7Cr, Fe-10Ni-13Cr, Fe-40Ni-13Cr, Fe-45Ni-15Cr was examined. Ion irradiation was carried out with 4 MeV Ni ions at 948 K to doses of 30 to 100 dpa with: (1) no helium injection, (2) simultaneous helium injection and (3) helium preinjection and aging. Swelling variation with helium injection differed among the 7Cr alloys and 13-15Cr alloys. Only the simultaneous helium injection mode produced a bimodal cavity size distribution in the high Ni alloys. The critical radius, as estimated from the cavity size distributions appears to have increased with increasing dose, but no clear variation of the critical radius with composition was observed. Helium preinjection and one-hour aging at 948 K formed helium bubbles along the residual dislocations, while subsequent Ni irradiation caused void formation along the dislocation lines. The calculated helium concentration deduced from observable helium bubbles was low compared with the injected helium concentration in the alloys containing higher Ni and lower Cr.

  10. Strong magnetoelectric and spin phonon coupling in SmFeO3/PMN-PT composite

    Science.gov (United States)

    Ahlawat, Anju; Satapathy, S.; Sathe, V. G.; Choudhary, R. J.; Gupta, P. K.

    2016-08-01

    We have investigated spin phonon coupling in the strain coupled magnetoelectric SmFeO3/0.65Pb(Mg1/3Nb2/3)O3-0.35PbTiO3 (PMN-PT) composite in the temperature range of 300-650 K by Raman spectroscopy and magnetic measurements. The SmFeO3/PMN-PT composite shows sharp rise in magnetic moment across ferroelectric transition temperature (Tc) of PMN-PT. Around this transition temperature (Tc of PMN-PT), the temperature evolution of Raman spectra of the composite also shows anomalies in the phonon frequencies and line width corresponding to the SmFeO3 phase which indicate structural modifications in the SmFeO3 phase around Tc of PMN-PT. The observed structural, magnetic, and phonon anomalies of SmFeO3 around Tc of PMN-PT in SmFeO3/PMN-PT are attributed to spin-phonon coupling providing evidence of strong strain mediated magnetoelectric effects.

  11. Magnetism of Fe nanostructure on ultrathin BaTiO3 film

    Science.gov (United States)

    Chen, X.; Kim, J.; Yang, S.; Kim, J. S.; Rojas, G.; Skomski, R.; Bode, M.; Bhattacharya, A.; Santos, T.; Guisinger, N.; Lu, H.; Gruverman, A.; Binek, C.; Sessi, V.; Honolka, J.; Enders, A.

    2011-03-01

    A study of Fe nanostructure on BaTi O3 (BTO) thin films with variable temperature scanning tunneling microscopy (STM) and X-Ray Magnetic Circular Dichroism (XMCD) under ultrahigh vacuum is presented. Fe/BTO is a prototype system for the study of magneto-electric effects but it is experimentally challenging to achieve high quality metal-oxide interfaces. Our approach is to use atomically flat, unreconstructed and stoichiometric BTO films of 13 unit cell thickness on Sr TO3 , and to deposit Fe impurity atoms and small clusters with molecular beam epitaxy at T = 8 K and compact nanometer clusters by buffer layer assisted growth for comparison. The magnetism of both systems was studied by XMCD at the Fe L3/2 absorption edges. The key observation is that even isolated Fe atoms on the BTO have a sizeable magnetic moment, which quickly increases with increasing coverage. This, together with a detailed analysis of the L 3/2 line shape, is evidence that intermixing and oxidation at the Fe/BTO interface is strongly suppressed. The interface quality achieved can thus potentially be exploited to experimentally observe a magneto-electric interface effect predicted by Tsymbal et al. [Phys. Rev. Lett. 97, 047201 (2006)].

  12. Magnetic ordering in Ho{sub 2}Fe{sub 2}Si{sub 2}C

    Energy Technology Data Exchange (ETDEWEB)

    Susilo, R. A., E-mail: resta.susilo@student.adfa.edu.au; Cadogan, J. M.; Cobas, R.; Hutchison, W. D.; Campbell, S. J. [School of Physical, Environmental and Mathematical Sciences, UNSW Canberra at the Australian Defence Force Academy, Canberra BC 2610 (Australia); Avdeev, M. [Bragg Institute, ANSTO, PMB 1, Menai, New South Wales 2234 (Australia)

    2015-05-07

    We have used neutron diffraction and {sup 57}Fe Mössbauer spectroscopy, complemented by magnetisation and specific heat measurements, to examine the magnetic ordering of Ho{sub 2}Fe{sub 2}Si{sub 2}C. We have established that Ho{sub 2}Fe{sub 2}Si{sub 2}C orders antiferromagnetically below T{sub N} = 16(1) K with a magnetic structure involving ordering of the Ho sublattice along the b-axis with a propagation vector k=[0 0 1/2 ]. {sup 57}Fe Mössbauer spectra collected below T{sub N} show no evidence of a magnetic splitting, demonstrating the absence of long range magnetic ordering of the Fe sublattice. A small line broadening is observed in the {sup 57}Fe spectra below T{sub N}, which is due to a transferred hyperfine field—estimated to be around 0.3 T at 10 K—from the Ho sublattice.

  13. Creep performance of Zr-1Nb-0.75Sn-0.1Fe cladding tubes with optimized Sn content

    Science.gov (United States)

    Kim, Won Nyeon; Choi, Yong; Hong, Sun Ig

    2014-12-01

    Creep properties of stress-relieved Zr-1Nb-0.75Sn-0.1Fe alloy with a lower Sn content were studied. Zr-1Nb-0.75Sn-0.1Fe alloy was found to have stress exponents of 6-7, independent of stress level, unlike Zr-1Nb-1Sn-0.1Fe alloy, in which the transition of stress exponent with increase of stress was observed. The constancy of stress exponent, without the transition observed in Zr-1Nb-0.75Sn-0.1Fe alloy with lower Sn content, is associated with the decrease of Sn atoms. The activation energies for creep deformation were calculated to be between 210 and 260 kJ/mol for the Zr-1Nb-0.75Sn-0.1Fe alloy with a lower Sn content. The slightly smaller creep activation energy in Zr-1Nb-0.75Sn-0.1Fe, compared with that of Zr-1Nb-1Sn-0.1Fe alloy, is thought to be attributed to the lower Sn content. The creep data obtained at different temperatures and stress fell close to a single line, suggesting the creep life of Zr-1Nb-0.75Sn-0.1Fe alloy with a lower Sn content is well expressed by the Larson-Miller Parameter.

  14. 57Fe emission Mössbauer spectroscopy following dilute implantation of 57Mn into In 2O3

    Science.gov (United States)

    Mokhles Gerami, A.; Johnston, K.; Gunnlaugsson, H. P.; Nomura, K.; Mantovan, R.; Masenda, H.; Matveyev, Y. A.; Mølholt, T. E.; Ncube, M.; Shayestehaminzadeh, S.; Unzueta, I.; Gislason, H. P.; Krastev, P. B.; Langouche, G.; Naidoo, D.; Ólafsson, S.

    2016-12-01

    Emission Mössbauer spectroscopy has been utilised to characterize dilute 57Fe impurities in In 2O3 following implantation of 57Mn ( T 1/2 = 1.5 min.) at the ISOLDE facility at CERN. From stoichiometry considerations, one would expect Fe to adopt the valence state 3 + , substituting In 3+, however the spectra are dominated by spectral lines due to paramagnetic Fe2+. Using first principle calculations in the framework of density functional theory (DFT), the density of states of dilute Fe and the hyperfine parameters have been determined. The hybridization between the 3d-band of Fe and the 2p band of oxygen induces a spin-polarized hole on the O site close to the Fe site, which is found to be the cause of the Fe2+ state in In 2O3. Comparison of experimental data to calculated hyperfine parameters suggests that Fe predominantly enters the 8b site rather than the 24d site of the cation site in the Bixbyite structure of In 2O3. A gradual transition from an amorphous to a crystalline state is observed with increasing implantation/annealing temperature.

  15. Analysis of Al and Fe transport coefficients in LHD core plasmas based on space-resolved EUV spectroscopy

    Science.gov (United States)

    Huang, Xianli; Morita, Shigeru; Oishi, Tetsutarou; Murakami, Izumi; Goto, Motoshi; Zhang, Hongming; Liu, Yang

    2016-10-01

    With impurity pellet injection and a one-dimensional transport code, the transport of Al and Fe ions has been analyzed in the Large Helical Device (LHD) based on extreme ultraviolet (EUV) space-resolved spectroscopy. The total density of Fe ions in the plasma core has been analyzed from the radial profiles of the Fe n =3-2 Lα emissions. When the ne profile is peaked or hollow, the Fe density also exhibits a peaked or hollow profile, respectively. Fe transport analysis shows that the convective velocity (V) is outward in the plasma core and inward near the edge when the ne profile is hollow. On the other hand, the V takes negative value over the whole radial range in the peaked ne profile. Therefore, the different Fe density profiles between peaked and hollow ne profiles can be explained by the significant difference in the V profile. Comparison of the transport coefficients between Al and Fe shows the magnitude of V for Al ions seems to be smaller than that for Fe ions while the difference in the diffusion coefficient profile is not significant. The difference in the decay time of line emissions between the two speices is attributed to the weaker convection for the Al.

  16. Nature of impurities in fertilizers containing EDDHMA/Fe(3+), EDDHSA/Fe(3+), and EDDCHA/Fe(3+) chelates.

    Science.gov (United States)

    Alvarez-Fernández, Ana; Cremonini, Mauro A; Sierra, Miguel A; Placucci, Giuseppe; Lucena, Juan J

    2002-01-16

    Iron chelates derived from ethylenediaminedi(o-hydroxyphenylacetic) acid (EDDHA), ethylenediaminedi(o-hydroxy-p-methylphenylacetic) acid (EDDHMA), ethylenediaminedi(2-hydroxy-5-sulfophenylacetic) acid (EDDHSA), and ethylenediaminedi(5-carboxy-2-hydroxyphenylacetic) acid (EDDCHA) are remarkably efficient in correcting iron chlorosis in plants growing in alkaline soils. This work reports the determination of impurities in commercial samples of fertilizers containing EDDHMA/Fe(3+), EDDHSA/Fe(3+), and EDDCHA/Fe(3+). The active components (EDDHMA/Fe(3+), EDDHSA/Fe(3+), and EDDCHA/Fe(3+)) were separated easily from other compounds present in the fertilizers by HPLC. Comparison of the retention times and the UV-visible spectra of the peaks obtained from commercial EDDHSA/Fe(3+) and EDDCHA/Fe(3+) samples with those of standard solutions showed that unreacted starting materials (p-hydroxybenzenesulfonic acid and p-hydroxybenzoic acid, respectively) were always present in the commercial products. 1D and 2D NMR experiments showed that commercial fertilizers based on EDDHMA/Fe(3+) contained impurities having structures tentatively assigned to iron chelates of two isomers of EDDHMA. These findings suggest that current production processes of iron chelates used in agriculture need to be improved.

  17. Pair correlation functions of FeAs-based superconductors: Quantum Monte Carlo study

    Science.gov (United States)

    Kashurnikov, V. A.; Krasavin, A. V.

    2015-01-01

    The new generalized quantum continuous time world line Monte Carlo algorithm was developed to calculate pair correlation functions for two-dimensional FeAs-clusters modeling of iron-based superconductors within the framework of the two-orbital model. The analysis of pair correlations depending on the cluster size, temperature, interaction, and the type of symmetry of the order parameter is carried out. The data obtained for clusters with sizes up to 1 0x1 0 FeAs-cells favor the possibility of an effective charge carrier's attraction that is corresponding the A1g-symmetry, at some parameters of interaction.

  18. Momentum distribution of occupation numbers in FeAs-based superconductors

    Science.gov (United States)

    Kashurnikov, V. A.; Krasavin, A. V.; Zhumagulov, Ya V.

    2016-08-01

    The momentum distribution of charge carriers in two-dimensional FeAs-clusters modeling iron-based superconductors was calculated within the limits of the two-orbital model. The calculation was implemented by use of quantum world-line Monte Carlo algorithm. Matsubara Green's function was calculated for clusters with sizes up to 10x10 FeAs-cells. Profiles of the distributions are presented for the entire Brillouin zone. The data indicate the presence of a jump near the Fermi level, which is the evidence of the Fermi-type distribution. The influence on the momentum distribution of the value of the interaction parameter is discussed.

  19. Modeling and analysis of soybean (Glycine max. L Cu/Zn, Mn and Fe superoxide dismutases

    Directory of Open Access Journals (Sweden)

    V. Ramana Gopavajhula

    2013-01-01

    Full Text Available Superoxide dismutase (SOD, EC 1.15.1.1 is an important metal-containing antioxidant enzyme that provides the first line of defense against toxic superoxide radicals by catalyzing their dismutation to oxygen and hydrogen peroxide. SOD is classified into four metalloprotein isoforms, namely, Cu/Zn SOD, Mn SOD, Ni SOD and Fe SOD. The structural models of soybean SOD isoforms have not yet been solved. In this study, we describe structural models for soybean Cu/Zn SOD, Mn SOD and Fe SOD and provide insights into the molecular function of this metal-binding enzyme in improving tolerance to oxidative stress in plants.

  20. Effects of Fe fine powders doping on hot deformed NdFeB magnets

    Energy Technology Data Exchange (ETDEWEB)

    Lin, Min, E-mail: linm@nimte.ac.cn [Ningbo Institute of Material Technology & Engineering Chinese Academy of Science, Ningbo 315201 (China); Wang, Huijie [Ningbo Jinji Strong Magnetic Material Company, Ningbo 315041 (China); Zheng, Jingwu [Zhejiang University of Technology, Hangzhou 310014 (China); Yan, Aru [Ningbo Institute of Material Technology & Engineering Chinese Academy of Science, Ningbo 315201 (China)

    2015-04-01

    The composite NdFeB magnets with blending melt-spun flakes and Fe fine powders were prepared by the hot-pressed and hot-deformed route. Characterizations of the hot-deformed NdFeB magnets affected by the doped Fe powders were tested. The doped Fe powders decrease the hot-deformed pressure when the strain is between 15 and 50%. XRD patterns show that the doped Fe powders have little influence on the c-axis alignment of hot-deformed NdFeB magnets in the press direction. The B{sub r} and the (BH){sub max} get improved when the doped Fe powders are less than 3 wt%. The doped Fe of hot-deformed NdFeB magnets exists in the elongated state and the spherical state surrounded by the Nd-rich phase. With the Fe fraction increasing, the potential of magnet moves to the positive direction and the diameter of the Nyquist arc becomes larger, which indicate that the corrosion resistance improved effectively. The bending strength was enhanced by the elongated α-Fe phase embedded in the matrix 2:14:1 phase. - Highlights: • The doped Fe powders have little influence on the c-axis alignment of magnets. • The elongated Fe powders are more than the spherical Fe powders in the magnets. • The corrosion resistance is improved effectively with the increasing Fe fraction. • The bending strength is enhanced by the elongated α-Fe phase embedded in the matrix.

  1. Lattice locations and properties of Fe in Co/Fe co-implanted ZnO

    DEFF Research Database (Denmark)

    Gunnlaugsson, H.P.; Johnston, K.; Mølholt, T.E.;

    2012-01-01

    The lattice locations and electronic configurations of Fe in 57Co/57Fe implanted ZnO (to (5‐6) × 1014 Fe/cm−2) have been studied by 57Fe Mössbauer emission spectroscopy. The spectra acquired upon room temperature implantation show ∼20% of the probe atoms as Fe2+ on perturbed Zn sites and the rema...... likely takes place at relatively low temperatures, thus explaining some of the discrepancies in the literature regarding magnetic properties of 3d metal‐doped ZnO.......The lattice locations and electronic configurations of Fe in 57Co/57Fe implanted ZnO (to (5‐6) × 1014 Fe/cm−2) have been studied by 57Fe Mössbauer emission spectroscopy. The spectra acquired upon room temperature implantation show ∼20% of the probe atoms as Fe2+ on perturbed Zn sites...... and the remaining fraction as Fe2+ in damage sites of interstitial character. After annealing at 773 K, ∼20% remain on crystalline sites, while the damage fraction has partly disappeared and instead a ∼30% fraction occurs as high‐spin Fe3+, presumably in precipitates. This suggests that precipitation of Co/Fe in ZnO...

  2. Recombinant antibodies for specific detection of clostridial [Fe-Fe] hydrogenases

    Science.gov (United States)

    Mangayil, Rahul; Karp, Matti; Lamminmäki, Urpo; Santala, Ville

    2016-01-01

    Biological hydrogen production is based on activity of specific enzymes called hydrogenases. Hydrogenases are oxygen sensitive metalloenzymes containing Ni and/or Fe atoms at the active site, catalyzing reversible reduction of protons. Generally, [Fe-Fe] hydrogenases prefer proton reduction to molecular hydrogen, a potential energy carrier molecule that can be produced by bioprocesses in sustainable manner. Thus, monitoring tools have been developed to study the relationship between [Fe-Fe] hydrogenases and biohydrogen production in bioreactors at DNA and RNA levels. In the present study, novel molecular tools are introduced for quantitative monitoring of clostridial [Fe-Fe] hydrogenases at the protein level. Aerobic and anaerobic biopanning (for inactive and active [Fe-Fe] hydrogenase, respectively) of phage displayed single-chain variable fragment (scFv) antibody libraries aided in isolating nine potential scFvs. The enriched antibodies demonstrated high specificity towards Clostridium spp. [Fe-Fe] hydrogenases allowing detection from pure and mixed cultures. Additionally, the antibodies showed different binding characteristics towards hydrogenase catalytic states, providing a possible means for functional detection of clostridial [Fe-Fe] hydrogenases. From hydrogenase-antibody interaction studies we observed that though antibody binding reduced the enzyme catalytic activity, it facilitated to retain hydrogen evolution from oxygen exposed hydrogenases. PMID:27786270

  3. Recombinant antibodies for specific detection of clostridial [Fe-Fe] hydrogenases.

    Science.gov (United States)

    Mangayil, Rahul; Karp, Matti; Lamminmäki, Urpo; Santala, Ville

    2016-10-27

    Biological hydrogen production is based on activity of specific enzymes called hydrogenases. Hydrogenases are oxygen sensitive metalloenzymes containing Ni and/or Fe atoms at the active site, catalyzing reversible reduction of protons. Generally, [Fe-Fe] hydrogenases prefer proton reduction to molecular hydrogen, a potential energy carrier molecule that can be produced by bioprocesses in sustainable manner. Thus, monitoring tools have been developed to study the relationship between [Fe-Fe] hydrogenases and biohydrogen production in bioreactors at DNA and RNA levels. In the present study, novel molecular tools are introduced for quantitative monitoring of clostridial [Fe-Fe] hydrogenases at the protein level. Aerobic and anaerobic biopanning (for inactive and active [Fe-Fe] hydrogenase, respectively) of phage displayed single-chain variable fragment (scFv) antibody libraries aided in isolating nine potential scFvs. The enriched antibodies demonstrated high specificity towards Clostridium spp. [Fe-Fe] hydrogenases allowing detection from pure and mixed cultures. Additionally, the antibodies showed different binding characteristics towards hydrogenase catalytic states, providing a possible means for functional detection of clostridial [Fe-Fe] hydrogenases. From hydrogenase-antibody interaction studies we observed that though antibody binding reduced the enzyme catalytic activity, it facilitated to retain hydrogen evolution from oxygen exposed hydrogenases.

  4. Magnetic properties of ball-milled TbFe2 and TbFe2B

    Indian Academy of Sciences (India)

    J Arout Chelvane; S Kasiviswanathan; M V Rao; G Markandeyulu

    2004-04-01

    The magnetic properties of ball-milled TbFe2 and TbFe2B were studied by magnetization measurements. X-ray diffraction studies on TbFe2B showed that boron occupied interstitial position in the crystal structure, just as hydrogen did. The value of the saturation magnetization of TbFe2B was found to be smaller than that of TbFe2. This is explained on the basis of a charge transfer between the boron atoms and the 3d band of Fe. The anisotropy of TbFe2B was found to be large compared to that of TbFe2. X-ray diffractograms for the ball milled samples showed that after 80 h of milling, a predominantly amorphous phase was obtained. TbFe2B was found to undergo easy amorphization compared to TbFe2. Magnetization of TbFe2 was found to decrease rapidly with initial milling hours and was found to be constant with further hours of milling. TbFe2B exhibited an anomalous behaviour with an increase in moment with milling hours and this may be due to the segregation of -Fe.

  5. Nematic antiferromagnetic states in bulk FeSe

    Science.gov (United States)

    Liu, Kai; Lu, Zhong-Yi; Xiang, Tao

    2016-05-01

    The existence of nematic order, which breaks the lattice rotational symmetry with nonequivalent a and b axes in iron-based superconductors, is a well-established experimental fact. An antiferromagnetic (AFM) transition is accompanying this order, observed in nearly all parent compounds, except bulk FeSe. The absence of the AFM order in FeSe casts doubt on the magnetic mechanism of iron-based superconductivity, since the nematic order is believed to be driven by the same interaction that is responsible for the superconducting pairing in these materials. Here we show, through systematic first-principles electronic structure calculations, that the ground state of FeSe is in fact strongly AFM correlated but without developing a magnetic long-range order. Actually, there are a series of staggered n -mer AFM states with corresponding energies below that of the single stripe AFM state, which is the ground state for the parent compounds of most iron-based superconductors. Here, the staggered n -mer (n any integer >1 ) means a set of n adjacent parallel spins on a line along the b axis with antiparallel spins between n -mers along both a and b axes. Moreover, different n -mers can antiparallelly mix with each other to coexist. Among all the states, we find that the lowest energy states formed by the staggered dimer, staggered trimer, and their random antiparallel aligned spin states along the b axis are quasidegenerate. The thermal average of these states does not show any magnetic long-range order, but it does possess a hidden one-dimensional AFM order along the a axis, which can be detected by elastic neutron scattering measurements. Our finding gives a natural account for the absence of long-range magnetic order and suggests that the nematicity is driven predominantly by spin fluctuations even in bulk FeSe, providing a unified description on the phase diagram of iron-based superconductors.

  6. Charge stripe structure in FeTe

    Energy Technology Data Exchange (ETDEWEB)

    Kawashima, Y., E-mail: yukik@eng.hokudai.ac.jp [Department of Applied Physics, Hokkaido University, Sapporo 060-8628 (Japan); Ichimura, K. [Department of Applied Physics, Hokkaido University, Sapporo 060-8628 (Japan); Center of Education and Research for Topological Science and Technology, Hokkaido University, Sapporo 060-8628 (Japan); Ishioka, J. [Department of Applied Physics, Hokkaido University, Sapporo 060-8628 (Japan); Kurosawa, T. [Department of Physics, Hokkaido University, Sapporo 060-0810 (Japan); Oda, M. [Center of Education and Research for Topological Science and Technology, Hokkaido University, Sapporo 060-8628 (Japan); Department of Physics, Hokkaido University, Sapporo 060-0810 (Japan); Yamaya, K. [Department of Applied Physics, Hokkaido University, Sapporo 060-8628 (Japan); Tanda, S. [Department of Applied Physics, Hokkaido University, Sapporo 060-8628 (Japan); Center of Education and Research for Topological Science and Technology, Hokkaido University, Sapporo 060-8628 (Japan)

    2012-06-01

    We report the STM study on a single-crystalline sample of FeTe at 7.8 K. FeTe is one of the iron-based superconductor. We measured the resistivity and the magnetization of FeTe. FeTe shows SDW transition at 58 K on these measurements. We study the electronic state of FeTe by using STM/STS for observing FeTe from a microscopic viewpoint. We observed the iron layer and the tellurium layer with atomic resolution. Moreover, we discover the charge stripe structure on STM/STS measurement. We find the charge stripe structure is caused by iron atoms from the analysis. The gap structure of 9 meV was observed in tunneling spectra. This gap size is consistent with the SDW gap which is expected from mean field theory with T{sub N}=58 K.

  7. [Fe IV] Emission in Ionized Nebulae

    Directory of Open Access Journals (Sweden)

    M. Rodríguez

    2003-01-01

    Full Text Available Se presentan los resultados de un análisis de la emisión en [Fe IV] en varias nebulosas ionizadas, basado en nuevas identificaciones y medidas anteriores de líneas de [Fe IV]. Las abundancias de Fe obtenidas al sumar las abundancias de los iones relevantes (principalmente Fe++ y Fe3+ resultan ser menores, por factores en el rango 2.6-5.9, que las abundancias implicadas por las líneas de [Fe III] y un factor de corrección por la ionizacion obtenido con modelos de ionizacion. Se discuten las posibles razones de esta discrepancia así como las implicaciones que tiene para nuestro entendimiento tanto de la evolución del polvo en nebulosas ionizadas como de la historia química de galaxias de baja metalicidad.

  8. Preparation of γ-Fe2O3/Ni2O3/FeCl3(FeCl2 Composite Nanoparticles by Hydrothermal Process Useful for Ferrofluids

    Directory of Open Access Journals (Sweden)

    Qingmei Zhang

    2011-01-01

    Full Text Available Using a hydrothermal process in FeCl2 solution, γ-Fe2O3/Ni2O3/FeCl3(FeCl2 composite nanoparticles were obtained from the FeOOH/Ni(OH2 precursor prepared by coprecipitation. The precursor and the as-prepared nanoparticles were investigated by vibrating sample magnetometer (VSM, X-ray diffraction (XRD, energy disperse X-ray spectroscopy (EDX, X-ray photoelectron spectroscopy (XPS, and transmission electron microscopy (TEM. The experimental results showed that the paramagnetic amorphous precursor, in which Ni(OH2 is formed outside FeOOH, is transformed to ferrimagnetic γ-Fe2O3/Ni2O3 composite when it is processed in FeCl2 solution (0.25, 0.50, 1.00 M in an autoclave at 100°C for 1 hr. In addition, the dismutation reaction of FeCl2 produces FeCl3 and Fe. Some FeCl3 and little FeCl2 can be absorbed to form γ-Fe2O3/Ni2O3/FeCl3(FeCl2 composite nanoparticles in which Ni2O3 forms outside the γ-Fe2O3 core and the outermost layer is FeCl3 (FeCl2. The content of FeCl3 (FeCl2 in the particles increased, and the magnetization of the particles decreased with the concentration of FeCl2 solution increasing in the hydrothermal process. The FeCl3 (FeCl2 surface is chemically passive and nonmagnetic (paramagnetic. Accordingly, the composite nanoparticles are chemically stable, and their aggregation is prevented. The specific saturation magnetization of such composite nanoparticles can get to 57.4–62.2 emu/g and could be very suitable for synthesizing ferrofluids.

  9. Subjective poverty line definitions

    NARCIS (Netherlands)

    J. Flik; B.M.S. van Praag (Bernard)

    1991-01-01

    textabstractIn this paper we will deal with definitions of subjective poverty lines. To measure a poverty threshold value in terms of household income, which separates the poor from the non-poor, we take into account the opinions of all people in society. Three subjective methods will be discussed

  10. Draw the Line!

    DEFF Research Database (Denmark)

    present proceedings from the UPGEM conference "Draw the Line!" in Copenhagen May 2008. The proceedings include contributions by UPGEM researchers, conference speeches by other researchers, politicians and gender equality officers in which they relate their work and research with the research done in UPGEM...

  11. CyLineUp

    NARCIS (Netherlands)

    Nijveen, Harm; Dias Costa, Maria; Slijkhuis, T.; Ligterink, Wilco; Hilhorst, Henk W.M.; Ridder, de Dick

    2016-01-01

    CyLineUp is a Cytoscape 3 app for the projection of high-throughput measurement data from multiple experiments/samples on a network or pathway map using "small multiples" This visualization method allows for easy comparison of different experiments in the context of the network or pathway. The

  12. Subjective poverty line definitions

    NARCIS (Netherlands)

    J. Flik; B.M.S. van Praag (Bernard)

    1991-01-01

    textabstractIn this paper we will deal with definitions of subjective poverty lines. To measure a poverty threshold value in terms of household income, which separates the poor from the non-poor, we take into account the opinions of all people in society. Three subjective methods will be discussed a

  13. Glue-paste linings

    DEFF Research Database (Denmark)

    Fuster-López, Laura; Andersen, Cecil Krarup; Bouillon, Nicolas

    2017-01-01

    Glue-paste linings of (Western) canvas paintings have been performed with a variety of materials throughout history and are present in a very significant amount of artworks in collections in Europe and elsewhere. Cereal flours and animal glues were usually the main ingredients because they were r...

  14. Mixed lubricated line contacts

    OpenAIRE

    Faraon, Irinel Cosmin

    2005-01-01

    The present work deals with friction in mixed lubricated line contacts. Components in systems are becoming smaller and due to, for instance power transmitted, partial contact may occur. In industrial applications, friction between the moving contacting surfaces cannot be avoided, therefore it is essential that an engineer is able to predict friction.

  15. Central venous line - infants

    Science.gov (United States)

    A central venous line (CVL) is a long, soft, plastic tube that is put into a large vein in the chest. WHY IS A CVL USED? A CVL is often put in when a baby cannot get a ... (MCC). A CVL can be used to give nutrients or medicines to a ...

  16. Redrawing the Poverty Line

    Institute of Scientific and Technical Information of China (English)

    2011-01-01

    A new threshold means more than 100 million impoverished people will be eligible for government assistance as China continues to battle poverty The Chinese Government has decided to set the nation’s poverty line at an annual per-capita net income

  17. America's Assembly Line

    DEFF Research Database (Denmark)

    Nye, David Edwin

    A social history of the assembly line, invented in 1913. Both praised as a boon to consumers and as a curse for workers, it has been satirized, imitated, and celebrated for 100 years. It has inspired fiction, comedy, cafeteria layouts, and suburban housing. It transformed industrial labor...

  18. America's Assembly Line

    DEFF Research Database (Denmark)

    Nye, David Edwin

    A social history of the assembly line, invented in 1913. Both praised as a boon to consumers and as a curse for workers, it has been satirized, imitated, and celebrated for 100 years. It has inspired fiction, comedy, cafeteria layouts, and suburban housing. It transformed industrial labor and pro...

  19. LEAR: antiproton extraction lines

    CERN Multimedia

    Photographic Service

    1992-01-01

    Antiprotons, decelerated in LEAR to a momentum of 100 MeV/c (kinetic energy of 5.3 MeV), were delivered to the experiments in an "Ultra-Slow Extraction", dispensing some 1E9 antiprotons over times counted in hours. Beam-splitters and a multitude of beam-lines allowed several users to be supplied simultaneously.

  20. Field-induced microwave absorption in Fe3O4 nanoparticles and Fe3O4/polyaniline composites synthesized by different methods

    Science.gov (United States)

    Kurlyandskaya, G. V.; Cunanan, Jessica; Bhagat, S. M.; Aphesteguy, J. C.; Jacobo, S. E.

    2007-08-01

    Three kinds of nanoscale powders containing Fe3O4 nanoparticles (NPs) have been studied by ferromagnetic resonance (FMR): (i) Fe3O4 NPs grown and then covered with polyaniline (PANI), (ii) unclad Fe3O4 NPs, and (iii) Fe3O4 NPs grown “in situ” with the PANI. In every case, there is no low field microwave absorption, rather a single FMR line is observed. However, the half-power widths are of order of 1 kOe presumably due to a distribution of internal fields. For type I particles with a low concentration (below 40%) of Fe3O4, the observed resonance fields (Hr) are close to those expected for spheres with negligible magnetocrystalline anisotropy. For all other cases, Hr values are significantly lower. Such shortfalls can be roughly understood by invoking dipolar interactions between the grains, stresses frozen in grains during manufacture (method III), as well as anisotropy fields when the specimens are prepared in an aligning field.