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Sample records for fabricate high efficiency

  1. Vacuum MOCVD fabrication of high efficience cells

    Science.gov (United States)

    Partain, L. D.; Fraas, L. M.; Mcleod, P. S.; Cape, J. A.

    1985-01-01

    Vacuum metal-organic-chemical-vapor-deposition (MOCVD) is a new fabrication process with improved safety and easier scalability due to its metal rather than glass construction and its uniform multiport gas injection system. It uses source materials more efficiently than other methods because the vacuum molecular flow conditions allow the high sticking coefficient reactants to reach the substrates as undeflected molecular beams and the hot chamber walls cause the low sticking coefficient reactants to bounce off the walls and interact with the substrates many times. This high source utilization reduces the materials costs power device and substantially decreases the amounts of toxic materials that must be handled as process effluents. The molecular beams allow precise growth control. With improved source purifications, vacuum MOCVD has provided p GaAs layers with 10-micron minority carrier diffusion lengths and GaAs and GaAsSb solar cells with 20% AMO efficiencies at 59X and 99X sunlight concentration ratios. Mechanical stacking has been identified as the quickest, most direct and logical path to stacked multiple-junction solar cells that perform better than the best single-junction devices. The mechanical stack is configured for immediate use in solar arrays and allows interconnections that improve the system end-of-life performance in space.

  2. Fabrication of highly efficient flexible dye-sensitized solar cells

    Energy Technology Data Exchange (ETDEWEB)

    Chang, H., E-mail: f10381@ntut.edu.t [Department of Mechanical Engineering, National Taipei University of Technology, No.1 Sec.3, Chung Hsiao E. Rd., Taipei 10608, Taiwan (China); Chen, T.L. [Department of Industrial Design, National Taipei University of Technology, No.1 Sec.3, Chung Hsiao E. Rd., Taipei 10608, Taiwan (China); Huang, K.D. [Department of Vehicle Engineering, National Taipei University of Technology, No.1 Sec.3, Chung Hsiao E. Rd., Taipei 10608, Taiwan (China); Chien, S.H. [Institute of Chemistry, Academia Sinica, No. 128 Sec.2, Academia Rd., Nankang, Taipei 11529, Taiwan (China); Hung, K.C. [Department of Mechanical Engineering, National Taipei University of Technology, No.1 Sec.3, Chung Hsiao E. Rd., Taipei 10608, Taiwan (China)

    2010-08-15

    The paper studies the fabrication of a flexible dye-sensitized solar cell (DSSC). The photoelectrode substrates are flexible stainless steel sheet with thickness 0.07 mm and titanium (Ti) sheet with thickness 0.25 mm. For the photoelectrode fabrication process, eletrophoresis deposition (EPD) was employed for its merits of low-cost and fast fabrication. With an electric field of 40 V/cm, after undergoing EPD process twice, the TiO{sub 2} nanofilm thickness could be controlled to around 13 {mu}m thick. In addition, to achieve counter electrode, sputtering method was applied to deposit Pt on ITO-PET, resulting in thin films with four different thicknesses of 5, 8, 11 and 14 nm. The experimental results showed that the best colloid solution used in EPD process was a mixture of 100 ml isopropyl alcohol (IPA) and 0.4 g commercial TiO{sub 2} nanoparticles, Degussa P25. The best flatness for a 13 {mu}m thick film could be acquired under an electric field of 40 V/cm. Comparing the photoelectric conversion efficiency values of DSSC assembled by counter electrodes with different Pt thicknesses, the experimental results showed that the best Pt thickness was 11 nm, and the conversion efficiency could reach as high as 2.91%.

  3. Achieving high performance polymer optoelectronic devices for high efficiency, long lifetime and low fabrication cost

    Science.gov (United States)

    Huang, Jinsong

    This thesis described three types of organic optoelectronic devices: polymer light emitting diodes (PLED), polymer photovoltaic solar cell, and organic photo detector. The research in this work focuses improving their performance including device efficiency, operation lifetime simplifying fabrication process. With further understanding in PLED device physics, we come up new device operation model and improved device architecture design. This new method is closely related to understanding of the science and physics at organic/metal oxide and metal oxide/metal interface. In our new device design, both material and interface are considered in order to confine and balance all injected carriers, which has been demonstrated very be successful in increasing device efficiency. We created two world records in device efficiency: 18 lm/W for white emission fluorescence PLED, 22 lm/W for red emission phosphorescence PLED. Slow solvent drying process has been demonstrated to significantly increase device efficiency in poly(3-hexylthiophene) (P3HT) and [6,6]-phenyl C 61-butyric acid methyl ester (PCBM) mixture polymer solar cell. From the mobility study by time of flight, the increase of efficiency can be well correlated to the improved carrier transport property due to P3HT crystallization during slow solvent drying. And it is found that, similar to PLED, balanced carrier mobility is essential in high efficient polymer solar cell. There is also a revolution in our device fabrication method. A unique device fabrication method is presented by an electronic glue based lamination process combined with interface modification as a one-step polymer solar cell fabrication process. It can completely skip the thermal evaporation process, and benefit device lifetime by several merits: no air reactive. The device obtained is metal free, semi-transparent, flexible, self-encapsulated, and comparable efficiency with that by regular method. We found the photomultiplication (PM) phenomenon in C

  4. High Efficiency UV Photodiodes fabricated on p-type Substrate

    NARCIS (Netherlands)

    Ramachandra Rao, P.; Milosavljevic, S.; Kroth, U.; Laubis, C.; Nihtianov, S.

    2014-01-01

    Newly developed “pure-boron” photodiodes, with high sensitivity and stability in the whole ultraviolet range (UV), are described. The main purpose of this work is to create and characterize a large-area UV photodiode, representing a structure of a pixel in a backside illuminated CMOS image sensor, f

  5. High-efficiency fabrication of aspheric microlens arrays by holographic femtosecond laser-induced photopolymerization

    Science.gov (United States)

    Hu, Yanlei; Chen, Yuhang; Ma, Jianqiang; Li, Jiawen; Huang, Wenhao; Chu, Jiaru

    2013-09-01

    Manufacture of aspheric microlens has always been technically challenging for conventional approaches due to their complex curved profile and tiny sizes. Two-photon polymerization is capable of producing arbitrary shape with high spatial resolution, apart from the disadvantage of ultra-low rate of yield resulting from point-by-point writing strategy. Here, we report parallel fabrication of aspheric microlens arrays (AMLAs) by taking advantage of holographic femtosecond laser direct-writing. The inherent constraints of the spatial light modulator are taken into consideration for achieving improved intensity uniformity and enhanced diffraction efficiency. Closely-packed AMLAs with designable optical parameters are readily fabricated with excellent optical performance.

  6. Design, Fabrication and Test of a High Efficiency Refractive Secondary Concentrator for Solar Applications

    Science.gov (United States)

    Wong, Wayne A.; Geng, Steven M.; Castle, Charles H.; Macosko, Robert P.

    2000-01-01

    Common to many of the space applications that utilize solar thermal energy such as electric power conversion, thermal propulsion, and furnaces, is a need for highly efficient, solar concentration systems. An effort is underway to develop the refractive secondary concentrator, which uses refraction and total internal reflection to efficiently concentrate and direct solar energy. When used in combination with advanced primary concentrators, the refractive secondary concentrator enables very high system concentration ratios (10,000 to 1) and very high temperatures (greater than 2000 K). Presented is an overview of the effort at the NASA Glenn Research Center to evaluate the performance of a prototype single crystal sapphire refractive secondary concentrator and to compare the performance with analytical models. The effort involves the design and fabrication of a secondary concentrator, design and fabrication of a calorimeter and its support hardware, calibration of the calorimeter, testing of the secondary concentrator in NASA Glenn's Tank 6 solar thermal vacuum facility, and comparing the test results with predictions. Test results indicate an average throughput efficiency of 87%. It is anticipated that reduction of a known reflection loss with an anti-reflective coating would result in a secondary concentrator throughput efficiency of approximately 93%.

  7. Design and Fabrication of High-Efficiency CMOS/CCD Imagers

    Science.gov (United States)

    Pain, Bedabrata

    2007-01-01

    An architecture for back-illuminated complementary metal oxide/semiconductor (CMOS) and charge-coupled-device (CCD) ultraviolet/visible/near infrared- light image sensors, and a method of fabrication to implement the architecture, are undergoing development. The architecture and method are expected to enable realization of the full potential of back-illuminated CMOS/CCD imagers to perform with high efficiency, high sensitivity, excellent angular response, and in-pixel signal processing. The architecture and method are compatible with next-generation CMOS dielectric-forming and metallization techniques, and the process flow of the method is compatible with process flows typical of the manufacture of very-large-scale integrated (VLSI) circuits. The architecture and method overcome all obstacles that have hitherto prevented high-yield, low-cost fabrication of back-illuminated CMOS/CCD imagers by use of standard VLSI fabrication tools and techniques. It is not possible to discuss the obstacles in detail within the space available for this article. Briefly, the obstacles are posed by the problems of generating light-absorbing layers having desired uniform and accurate thicknesses, passivation of surfaces, forming structures for efficient collection of charge carriers, and wafer-scale thinning (in contradistinction to diescale thinning). A basic element of the present architecture and method - the element that, more than any other, makes it possible to overcome the obstacles - is the use of an alternative starting material: Instead of starting with a conventional bulk-CMOS wafer that consists of a p-doped epitaxial silicon layer grown on a heavily-p-doped silicon substrate, one starts with a special silicon-on-insulator (SOI) wafer that consists of a thermal oxide buried between a lightly p- or n-doped, thick silicon layer and a device silicon layer of appropriate thickness and doping. The thick silicon layer is used as a handle: that is, as a mechanical support for the

  8. Progress in high-efficient solution process organic photovoltaic devices fundamentals, materials, devices and fabrication

    CERN Document Server

    Li, Gang

    2015-01-01

    This book presents an important technique to process organic photovoltaic devices. The basics, materials aspects and manufacturing of photovoltaic devices with solution processing are explained. Solution processable organic solar cells - polymer or solution processable small molecules - have the potential to significantly reduce the costs for solar electricity and energy payback time due to the low material costs for the cells, low cost and fast fabrication processes (ambient, roll-to-roll), high material utilization etc. In addition, organic photovoltaics (OPV) also provides attractive properties like flexibility, colorful displays and transparency which could open new market opportunities. The material and device innovations lead to improved efficiency by 8% for organic photovoltaic solar cells, compared to 4% in 2005. Both academic and industry research have significant interest in the development of this technology. This book gives an overview of the booming technology, focusing on the solution process fo...

  9. High Quantum Efficiency and High Concentration Erbium-Doped Silica Glasses Fabricated by Sintering Nanoporous Glasses

    Institute of Scientific and Technical Information of China (English)

    2006-01-01

    A new method was used to prepare erbium-doped high silica (SiO2%>96%) glasses by sintering nanoporous glasses. The concentration of erbium ions in high silica glasses can be considerably more than that in silica glasses prepared by using conventional methods. The fluorescence of 1532 nm has an FWHM (Full Wave at Half Maximum) of 50 nm, wider than 35 nm of EDSFA (erbium-doped silica fiber amplifer), and hence the glass possesses potential application in broadband fiber amplifiers. The Judd-Ofelt theoretical analysis reflects that the quantum efficiency of this erbium-doped glass is about 0.78, although the erbium concentration in this glass (6×103) is about twenty times higher than that in silica glass. These excellent characteristics of Er-doped high silica glass will be conducive to its usage in optical amplifiers and microchip lasers.

  10. Low-cost fabrication of high efficiency solid-state neutron detectors

    Science.gov (United States)

    Wu, Jia-Woei; Huang, Kuan-Chih; Weltz, Adam; English, Erik; Hella, Mona M.; Dahal, Rajendra; Lu, James J.-Q.; Danon, Yaron; Bhat, Ishwara B.

    2016-05-01

    The development of high-efficiency solid state thermal neutron detectors at low cost is critical for a wide range of civilian and defense applications. The use of present neutron detector system for personal radiation detection is limited by the cost, size, weight and power requirements. Chip scale solid state neutron detectors based on silicon technology would provide significant benefits in terms of cost, volume, and allow for wafer level integration with charge preamplifiers and readout electronics. In this paper, anisotropic wet etching of (110) silicon wafers was used to replace deep reactive ion etching (DRIE) to produce microstructured neutron detectors with lower cost and compatibility with mass production. Deep trenches were etched by 30 wt% KOH at 85°C with a highest etch ratio of (110) to (111). A trench-microstructure thermal neutron detector described by the aforementioned processes was fabricated and characterized. The detector—which has a continuous p+-n junction diode—was filled with enriched boron (99% of 10B) as a neutron converter material. The device showed a leakage current of ~ 6.7 × 10-6 A/cm2 at -1V and thermal neutron detection efficiency of ~16.3%. The detector uses custom built charge pre-amplifier, a shaping amplifier, and an analogto- digital converter (ADC) for data acquisition.

  11. Report on cheap processes for fabrication of silicon solar cells of high efficiency

    Energy Technology Data Exchange (ETDEWEB)

    Safir, Y.; Proctor, W.G.; Leistiko, O.

    1984-01-01

    The pingroject is aimed at develop a process for fabrication of reproducible, stable silicon solar cells with high efficiency. A cheap and simple technology should substitute the present one without deterioration of the cell performance. The process here developed has used a spin-on doping, belt furnace instead of a quartz furnace tube, serigraphy instead of photolitography and surface treatment with a special edge protection techniques instead of various unstable methods for pn-transition isolating. The cell area has been enlarged from 5 cm/sup 2/ to 20 cm/sup 2/ and a procedure for p/sup +/nn/sup +/ cells and n/sup +/pp/sup +/ cells is developed. The best textured p/sup +/nn/sup +/ had Jsub(SC) = mA/cm/sup 2/, Vsub(oc) = 603 mV, FF = 0.78, itasub(AM)/sub 1/ = 11.8%. Typical values for n/sup +/pp/sup +/ cells inclusive AR layer was Jsub(SC)= 23.9 mA/cm/sup 2/, Vsub(oc) = 592 mV, FF = 0.77, itasub(AM)/sub 1/ = 11.0%. A solar cell panel with 6 n/sup +/pp/sup +/ cells gave Isub(SC) = 440 mA, Vsub(oc) - 3.5 V. Commercial monocrystalline solar cells are now generally of n/sup +/pp/sup +/ type and have coefficient of performance from 12 to 15% while cell area is varying from 20 to 80 cm/sup 2/.

  12. Facile fabrication of three-dimensional TiO2 structures for highly efficient perovskite solar cells

    Energy Technology Data Exchange (ETDEWEB)

    Jang, Segeun; Yoon, Jungjin; Ha, Kyungyeon; Kim, Min-cheol; Kim, Dong Hoe; Kim, Sang Moon; Kang, Seong Min; Park, Sei Jin; Jung, Hyun Suk; Choi, Mansoo

    2016-04-01

    The capability of fabricating three dimensional (3-D) nanostructures with desired morphology is a key to realizing effective light-harvesting strategy in optical applications. In this work, we report a novel 3-D nanopatterning technique that combines ion-assisted aerosol lithography (IAAL) and soft lithography that serves as a facile method to fabricate 3-D nanostructures. Aerosol nanoparticles can be assembled into desired 3-D nanostructures via ion-induced electrostatic focusing and antenna effects from charged nanoparticle structures. Replication of the structures with a polymeric mold allows high throughput fabrication of 3-D nanostructures with various liquid-soluble materials. 3-D flower-patterned polydimethylsiloxane (PDMS) stamp was prepared using the reported technique and utilized for fabricating 3-D nanopatterned mesoporous TiO2 layer, which was employed as the electron transport layer in perovskite solar cells. By incorporating the 3-D nanostructures, absorbed photon-to-current efficiency of >95% at 650 nm wavelength and overall power conversion efficiency of 15.96% were achieved. The enhancement can be attributed to an increase in light harvesting efficiency in a broad wavelength range from 400 to 800 nm and more efficient charge collection from enlarged interfacial area between TiO2 and perovskite layers. This hybrid nanopatterning technique has demonstrated to be an effective method to create textures that increase light harvesting and charge collection with 3-D nanostructures in solar cells.

  13. An Effective Modeling Approach for High Efficient Solar Cell Using Virtual Wafer Fabrication Tools

    Directory of Open Access Journals (Sweden)

    Khomdram Jolson Singh

    2011-01-01

    Full Text Available n order to give a real understanding and realization of all the phenomena occurring inside the photovoltaic cell devices, the development of a reliable simulated model first is also essential. In this paper, a novel method for developing a realistic model of an efficient solar cell is presented. An efficient model of a Dual Junction InGaP/GaAs solar cell having GaAs tunnel diode is prepared and fully simulated using Silvaco VWF/ATLAS code. An optimization of window layer, ARC, BSF etc are also performed incorporating the effect of some of the different parameters on the performance of this model. The major stages of the process are explained and the simulation results are compared with published experimental data to demonstrate the accuracy of our results produced by the model utilizing this technique. For this optimized InGaP/GaAs Dual Junction cell model having 125 nm DLAR on 18 nm InAlP textured window with effective 500 nm InAlGaP bottom BSF , a maximum conversion efficiency of 32.20 % (1 sun and 36.67 % (1000 suns is obtained under AM1.5G illumination. The introduction of this modeling technique to the photovoltaic community will prove to be of great importance in aiding in the design and development of advanced solar cells using Silvaco Virtual Wafer Fabrication Tools.

  14. Facile fabrication of AgNPs/(PVA/PEI) nanofibers: high electrochemical efficiency and durability for biosensors.

    Science.gov (United States)

    Zhu, Han; Du, MingLiang; Zhang, Ming; Wang, Pan; Bao, ShiYong; Wang, LiNa; Fu, YaQin; Yao, JuMing

    2013-11-15

    A novel, facile and green approach for the fabrication of H2O2, glutathione (GSH) and glucose detection biosensor using water-stable PVA and PVA/PEI nanofibers decorated with AgNPs by combining an in situ reduction approach and electrospinning technique has been demonstrated. Small, uniform and well-dispersed AgNPs embedded in the PVA nanofibers and immobilized on functionalized PVA/PEI nanofibers indicate the highly sensitive detection of H2O2 with a detection limit of 5 μM and exhibit a fast response, broad linear range, low detection limit and excellent stability and reusability.

  15. Flexible and conductive cotton fabric counter electrode coated with graphene nanosheets for high efficiency dye sensitized solar cell

    Science.gov (United States)

    Sahito, Iftikhar Ali; Sun, Kyung Chul; Arbab, Alvira Ayoub; Qadir, Muhammad Bilal; Choi, Yun Seon; Jeong, Sung Hoon

    2016-07-01

    Textile fabric based electrodes due to their lightweight, flexibility and cost effectiveness, coupled with the ease of fabrication are recently given a huge attention as wearable energy sources. The current dye sensitized solar cells (DSSCs) are based on Platinized-Fluorinated Tin oxide (Pt-FTO) glass electrode, which is not only expensive, but also rigid and heavyweight. In this work, a highly conductive-graphene coated cotton fabric (HC-GCF) is fabricated with a surface resistance of only 7 Ω sq-1. HC-GCF is used as an efficient counter electrode (CE) in DSSC and the results are examined using photovoltaic and electrochemical analysis. HC-GCF counter electrode shows a negligible change of resistance to bending at various bending positions and is also found extremely resistant to electrolyte solution and washing with water. Cyclic voltammogram, Nyquist and the Tafel plots suggest an excellent electro catalytic activity (ECA) for the reduction of tri-iodide (I3-) ions. Symmetrical cells prepared using HC-GCF, indicate a very low charge transfer resistance (RCT) of only 1.2 Ω, which is nearly same to that of the Pt with 1.04 Ω. Furthermore, a high photovoltaic conversion efficiency (PCE) of 6.93% is achieved using HC-GCF counter electrode using polymer electrolyte.

  16. High-efficiency superconducting nanowire single-photon detectors fabricated from MoSi thin-films

    CERN Document Server

    Verma, V B; Bussières, F; Horansky, R D; Dyer, S D; Lita, A E; Vayshenker, I; Marsili, F; Shaw, M D; Zbinden, H; Mirin, R P; Nam, S W

    2015-01-01

    We demonstrate high-efficiency superconducting nanowire single-photon detectors (SNSPDs) fabricated from MoSi thin-films. We measure a maximum system detection efficiency (SDE) of 87 +- 0.5 % at 1542 nm at a temperature of 0.7 K, with a jitter of 76 ps, maximum count rate approaching 10 MHz, and polarization dependence as low as 3.4 +- 0.7 % The SDE curves show saturation of the internal efficiency similar to WSi-based SNSPDs at temperatures as high as 2.3 K. We show that at similar cryogenic temperatures, MoSi SNSPDs achieve efficiencies comparable to WSi-based SNSPDs with nearly a factor of two reduction in jitter.

  17. High Throughput, High Yield Fabrication of High Quantum Efficiency Back-Illuminated Photon Counting, Far UV, UV, and Visible Detector Arrays

    Science.gov (United States)

    Nikzad, Shouleh; Hoenk, M. E.; Carver, A. G.; Jones, T. J.; Greer, F.; Hamden, E.; Goodsall, T.

    2013-01-01

    In this paper we discuss the high throughput end-to-end post fabrication processing of high performance delta-doped and superlattice-doped silicon imagers for UV, visible, and NIR applications. As an example, we present our results on far ultraviolet and ultraviolet quantum efficiency (QE) in a photon counting, detector array. We have improved the QE by nearly an order of magnitude over microchannel plates (MCPs) that are the state-of-the-art UV detectors for many NASA space missions as well as defense applications. These achievements are made possible by precision interface band engineering of Molecular Beam Epitaxy (MBE) and Atomic Layer Deposition (ALD).

  18. High Throughput, High Yield Fabrication of High Quantum Efficiency Back-Illuminated Photon Counting, Far UV, UV, and Visible Detector Arrays

    Science.gov (United States)

    Nikzad, Shouleh; Hoenk, M. E.; Carver, A. G.; Jones, T. J.; Greer, F.; Hamden, E.; Goodsall, T.

    2013-01-01

    In this paper we discuss the high throughput end-to-end post fabrication processing of high performance delta-doped and superlattice-doped silicon imagers for UV, visible, and NIR applications. As an example, we present our results on far ultraviolet and ultraviolet quantum efficiency (QE) in a photon counting, detector array. We have improved the QE by nearly an order of magnitude over microchannel plates (MCPs) that are the state-of-the-art UV detectors for many NASA space missions as well as defense applications. These achievements are made possible by precision interface band engineering of Molecular Beam Epitaxy (MBE) and Atomic Layer Deposition (ALD).

  19. A facile strategy for the fabrication of a bioinspired hydrophilic-superhydrophobic patterned surface for highly efficient fog-harvesting

    KAUST Repository

    Wang, Yuchao

    2015-08-10

    Fog water collection represents a meaningful effort in the places where regular water sources, including surface water and ground water, are scarce. Inspired by the amazing fog water collection capability of Stenocara beetles in the Namib Desert and based on the recent work in biomimetic water collection, this work reported a facile, easy-to-operate, and low-cost method for the fabrication of hydrophilic-superhydrophobic patterned hybrid surface toward highly efficient fog water collection. The essence of the method is incorporating a (super)hydrophobically modified metal-based gauze onto the surface of a hydrophilic polystyrene (PS) flat sheet by a simple lab oven-based thermal pressing procedure. The produced hybrid patterned surfaces consisted of PS patches sitting within the holes of the metal gauzes. The method allows for an easy control over the pattern dimension (e.g., patch size) by varying gauze mesh size and thermal pressing temperature, which is then translated to an easy optimization of the ultimate fog water collection efficiency. Given the low-cost and wide availability of both PS and metal gauze, this method has a great potential for scaling-up. The results showed that the hydrophilic-superhydrophobic patterned hybrid surfaces with a similar pattern size to Stenocara beetles’s back pattern produced significantly higher fog collection efficiency than the uniformly (super)hydrophilic or (super)hydrophobic surfaces. This work contributes to general effort in fabricating wettability patterned surfaces and to atmospheric water collection for direct portal use.

  20. Efficient analysis of selected estrogens using fabric phase sorptive extraction and high performance liquid chromatography-fluorescence detection.

    Science.gov (United States)

    Kumar, Rajesh; Gaurav; Heena; Malik, Ashok Kumar; Kabir, Abuzar; Furton, Kenneth G

    2014-09-12

    A simple, fast and sensitive analytical method using fabric phase sorptive extraction (FPSE) followed by high performance liquid chromatography with fluorescence detection (HPLC-FLD) has been developed for efficient quantification of biologically important molecules e.g., 17α-ethynylestradiol (EE2), β-estradiol (E2) and bisphenol A (BPA). FPSE is a new sorptive extraction technique that integrates the advantages of permeable sol-gel derived hybrid organic-inorganic sorbents with flexible and permeable fabric substrates, resulting in a highly efficient and sensitive extraction media that can be introduced directly into any kind of fluidic matrix. Various factors affecting the performance of FPSE technique were optimized. The chromatographic separation was carried using mobile phase acetonitrile/methanol/water (30:15:55; v/v) at a flow rate 1.0mL/min on C18 column with fluorescence detection (λex=280nm and λem=310nm). The calibration curves of the target analytes were prepared with good correlation coefficient values (R(2)>0.992). Limit of detection (LOD) values range from 20 to 42pg/mL. The developed method was applied successfully for the analysis of estrogen molecules in urine and various kinds of aqueous samples.

  1. Application of CIS to high-efficiency PV module fabrication. Phase 3 final technical report

    Energy Technology Data Exchange (ETDEWEB)

    Basol, B M; Kapur, V K; Leidholm, C R; Halani, A; Roe, R; Norsworthy, G [International Solar Electric Technology, Inglewood, CA (United States)

    1998-08-01

    During this research period, researchers at International Solar Electric Technology (ISET) concentrated their efforts on three different areas of research. Within the National CIS R and D Team, ISET participated in the substrate/Mo interactions working group and investigated issues such as Na diffusion from the soda-lime glass substrate into the Mo layers and CIS films. Researchers determined that the Na content within the Mo layers was not a strong function of the nature of the Mo film. However, they found that diffusion through the Mo layers was a function of the Mo film characteristics as well as a very strong function of the CIS growth process itself. Researchers showed conclusively that the Na resided on the grain boundaries of CIS layers. Another team activity involved evaluation of CdS-free CIS solar cells. ZnO/CIS junctions prepared by the two-stage process showed light-soaking effects. Cells left under illumination improved in efficiency and were similar to the CdS/CIS junctions. After storage in the dark, however, efficiency deteriorated greatly for the ZnO/CIS device, most of the decline coming from the open-circuit voltage values. Much of the effort during this period was spent on developing a low-cost, non-vacuum CIS deposition technique. The method developed involves particulate deposition and formation of precursor layers followed by the conversion of these layers into CIS. Test modules of 40--60 cm{sup 2} were adapted to understand the issues involved in this novel technology. At the present time, the submodule efficiencies are 6--7%. Single-cell efficiencies are in the 10--13% range.

  2. Fabrication of Unique Magnetic Bionanocomposite for Highly Efficient Removal of Hexavalent Chromium from Water

    Science.gov (United States)

    Zhong, Yunlei; Qiu, Xun; Chen, Dongyun; Li, Najun; Xu, Qingfeng; Li, Hua; He, Jinghui; Lu, Jianmei

    2016-08-01

    Biotreatment of hexavalent chromium has attracted widespread interest due to its cost effective and environmental friendliness. However, the difficult separation of biomass from aqueous solution and the slow hexavalent chromium bioreduction rate are bottlenecks for biotechnology application. In this approach, a core-shell structured functional polymer coated magnetic nanocomposite was prepared for enriching the hexavalent chromium. Then the nanocomposite was connected to the bacteria via amines on bacterial (Bacillus subtilis ATCC-6633) surface. Under optimal conditions, a series of experiments were launched to degrade hexavalent chromium from the aqueous solution using the as-prepared bionanocomposite. Results showed that B. subtilis@Fe3O4@mSiO2@MANHE (BFSM) can degrade hexavalent chromium from the water more effectively (a respectable degradation efficiency of about 94%) when compared with pristine B. subtilis and Fe3O4@mSiO2@MANHE (FSM). Moreover, the BFSM could be separated from the wastewater by magnetic separation technology conveniently due to the Fe3O4 core of FSM. These results indicate that the application of BFSM is a promising strategy for effective treating wastewater containing hexavalent chromium.

  3. High-Resolution, High-Efficiency, Curved Diffraction Gratings Fabricated by Conformable, Maskless,100-nm Lithography Project

    Data.gov (United States)

    National Aeronautics and Space Administration — In this program, we will develop a novel process for fabricating large-area ultraviolet diffraction gratings on curved surfaces. This process is based on a unique...

  4. Roll-to-roll fabrication of large scale and regular arrays of three-dimensional nanospikes for high efficiency and flexible photovoltaics.

    Science.gov (United States)

    Leung, Siu-Fung; Gu, Leilei; Zhang, Qianpeng; Tsui, Kwong-Hoi; Shieh, Jia-Min; Shen, Chang-Hong; Hsiao, Tzu-Hsuan; Hsu, Chin-Hung; Lu, Linfeng; Li, Dongdong; Lin, Qingfeng; Fan, Zhiyong

    2014-03-07

    Three-dimensional (3-D) nanostructures have demonstrated enticing potency to boost performance of photovoltaic devices primarily owning to the improved photon capturing capability. Nevertheless, cost-effective and scalable fabrication of regular 3-D nanostructures with decent robustness and flexibility still remains as a challenging task. Meanwhile, establishing rational design guidelines for 3-D nanostructured solar cells with the balanced electrical and optical performance are of paramount importance and in urgent need. Herein, regular arrays of 3-D nanospikes (NSPs) were fabricated on flexible aluminum foil with a roll-to-roll compatible process. The NSPs have precisely controlled geometry and periodicity which allow systematic investigation on geometry dependent optical and electrical performance of the devices with experiments and modeling. Intriguingly, it has been discovered that the efficiency of an amorphous-Si (a-Si) photovoltaic device fabricated on NSPs can be improved by 43%, as compared to its planar counterpart, in an optimal case. Furthermore, large scale flexible NSP solar cell devices have been fabricated and demonstrated. These results not only have shed light on the design rules of high performance nanostructured solar cells, but also demonstrated a highly practical process to fabricate efficient solar panels with 3-D nanostructures, thus may have immediate impact on thin film photovoltaic industry.

  5. A SnOx-brookite TiO2 bilayer electron collector for hysteresis-less high efficiency plastic perovskite solar cells fabricated at low process temperature.

    Science.gov (United States)

    Kogo, Atsushi; Ikegami, Masashi; Miyasaka, Tsutomu

    2016-06-21

    Thin plastic film-based CH3NH3PbI3-xClx perovskite solar cells were fabricated at low process temperature using a bilayer comprising an amorphous SnOx and mesoporous brookite TiO2 as electron collectors. Void-less high quality heterojunction structures achieve hysteresis-less photovoltaic performance with a power conversion efficiency as high as 13.4% and mechanical stability against cyclic bending.

  6. An Efficient Way of Fabric Simulation

    Institute of Scientific and Technical Information of China (English)

    ZHONG Yue-qi; WANG Shan-yuan

    2002-01-01

    A partide system model is presented for the simulation of fabric draping. The interaction of each partide is based on a refined mass-spring structure. Regarded the fabric material as an orthotropic continuum, the refinement of our model is focused on the construction of mechanical responses of bending and shearing springs by means of a piecewise polynomial approximation of KES-F testing data. In this way, the draping figure of a silk fabric, a wool fabric and a polyester fabric are simulated. The static final shape and animation of simulation proves that our model has developed an efficient technique on real fabric- drape modeling, and the little computation time of the simulation execution on a PC with Celeron 450 CPU may meet the requirement of real-time simulation.

  7. Fabrication of High T

    Science.gov (United States)

    Apperley, Miles Hyam

    1992-01-01

    Metal-clad high-T_{rm c} superconductor wires have been fabricated by conventional hot extrusion and wire drawing techniques. The fabrication processes which were used influenced the microstructure which, in turn, governed the superconducting properties of metal-clad Y-Ba-Cu-O (YBCO) and Bi-Pb-Sr-Ca-Cu-O (BPSCCO) superconductors. The ability to form these materials into long thin wires and the electrical properties of the wires were assessed. Extruded metal-clad wire was fabricated by coextruding a Cu billet containing a Ag-clad superconductor core at 920^circC and 800 ^circC for YBCO and BPSCCO materials, respectively. The deformation behaviour of the composite billets was investigated by extruding through dies with semicone angle alpha = 30 ^circ and using a range of core diameters and reduction ratios. For combinations of initial core diameter and reduction ratio, domains of deformation behaviour were established including sound flow, nonuniform flow, core fracture and sleeve fracture. Hot extruded YBCO and BPSCCO superconductor had densities estimated to be between 95% and 98% of the theoretical values. The material contained transverse cracks except for a sample of YBCO which had an addition of 10 wt% Ag. The microstructure of the YBCO material consisted of YBa _2Cu_3O{_{7-x}}, while the BPSCCO material contained an intimate mixture of the high-T _{rm c} (Bi,Pb)_2 Sr_2Ca_2Cu _3O{_ {10-x}} (110 K) and low-T _{rm c} (Bi,Pb)_2 Sr_2Ca_1Cu _2O{_ {8-x}} (80 K) phases with Ca _2CuO_3 and Sr-Ca -Cu-O impurity particles. X-ray polefigure goniometry of extruded BPSCCO superconductor revealed that the material was relatively untextured. As-extruded YBCO and BPSCCO were semiconducting. Oxygen treated YBCO had a lower normal-state resistivity than the as-extruded material, and a superconducting transition above 77 K was not achieved. Heat treatment of extruded BPSCCO regenerated superconductivity above 77 K, with the transition behaviour dependent on the proportion of high

  8. Fabrication of a TiO2@porphyrin nanofiber hybrid material: a highly efficient photocatalyst under simulated sunlight irradiation

    Science.gov (United States)

    La, Duong Duc; Rananaware, Anushri; Phuong Nguyen Thi, Hoai; Jones, Lathe; Bhosale, Sheshanath V.

    2017-03-01

    The solar spectrum consists of 8% UV radiation, while 45% of solar energy is from visible light. It is therefore desirable to fabricate a hybrid material which is able to harvest energy from a wide range of photons from the sun for applications such as solar cells, photovoltaics, and photocatalysis. In this study we report on the fabrication of a TiO2@porphyrin hybrid material by surfactant-assisted co-assembly of monomeric porphyrin molecules with TiO2 nanoparticles. The obtained TiO2@porphyrin composite shows excellent integration of TiO2 particles with diameters of 15–30 nm into aggregated porphyrin nanofibers, which have a width of 70–90 nm and are several µm long. SEM, XPS, XRD, FTIR, UV–Vis and fluorescence spectroscopy were employed to characterize the TiO2@TCPP hybrid material. This material exhibits efficient photocatalytic performance under simulated sunlight, due to synergistic photocatalytic activities of the porphyrin aggregates in visible light and TiO2 particles in the UV region. A plausible mechanism for photocatalytic degradation is also proposed and discussed.

  9. In situ fabrication of depth-type hierarchical CNT/quartz fiber filters for high efficiency filtration of sub-micron aerosols and high water repellency

    Science.gov (United States)

    Li, Peng; Zong, Yichen; Zhang, Yingying; Yang, Mengmeng; Zhang, Rufan; Li, Shuiqing; Wei, Fei

    2013-03-01

    We fabricated depth-type hierarchical CNT/quartz fiber (QF) filters through in situ growth of CNTs upon quartz fiber (QF) filters using a floating catalyst chemical vapor deposition (CVD) method. The filter specific area of the CNT/QF filters is more than 12 times higher than that of the pristine QF filters. As a result, the penetration of sub-micron aerosols for CNT/QF filters is reduced by two orders of magnitude, which reaches the standard of high-efficiency particulate air (HEPA) filters. Simultaneously, due to the fluffy brush-like hierarchical structure of CNTs on QFs, the pore size of the hybrid filters only has a small increment. The pressure drop across the CNT/QF filters only increases about 50% with respect to that of the pristine QF filters, leading to an obvious increased quality factor of the CNT/QF filters. Scanning electron microscope images reveal that CNTs are very efficient in capturing sub-micron aerosols. Moreover, the CNT/QF filters show high water repellency, implying their superiority for applications in humid conditions.We fabricated depth-type hierarchical CNT/quartz fiber (QF) filters through in situ growth of CNTs upon quartz fiber (QF) filters using a floating catalyst chemical vapor deposition (CVD) method. The filter specific area of the CNT/QF filters is more than 12 times higher than that of the pristine QF filters. As a result, the penetration of sub-micron aerosols for CNT/QF filters is reduced by two orders of magnitude, which reaches the standard of high-efficiency particulate air (HEPA) filters. Simultaneously, due to the fluffy brush-like hierarchical structure of CNTs on QFs, the pore size of the hybrid filters only has a small increment. The pressure drop across the CNT/QF filters only increases about 50% with respect to that of the pristine QF filters, leading to an obvious increased quality factor of the CNT/QF filters. Scanning electron microscope images reveal that CNTs are very efficient in capturing sub-micron aerosols

  10. Fabrication of Highly Stable and Efficient PtCu Alloy Nanoparticles on Highly Porous Carbon for Direct Methanol Fuel Cells.

    Science.gov (United States)

    Khan, Inayat Ali; Qian, Yuhong; Badshah, Amin; Zhao, Dan; Nadeem, Muhammad Arif

    2016-08-17

    Boosting the durability of Pt nanoparticles by controlling the composition and morphology is extremely important for fuel cells commercialization. We deposit the Pt-Cu alloy nanoparticles over high surface area carbon in different metallic molar ratios and optimize the conditions to achieve desired material. The novel bimetallic electro-catalyst {Pt-Cu/PC-950 (15:15%)} offers exceptional electrocatalytic activity when tested for both oxygen reduction reaction and methanol oxidation reactions. A high mass activity of 0.043 mA/μgPt (based on Pt mass) is recorded for ORR. An outstanding longevity of this electro-catalyst is noticed when compared to 20 wt % Pt loaded either on PC-950 or commercial carbon. The high surface area carbon support offers enhanced activity and prevents the nanoparticles from agglomeration, migration, and dissolution as evident by TEM analysis.

  11. In situ fabrication of depth-type hierarchical CNT/quartz fiber filters for high efficiency filtration of sub-micron aerosols and high water repellency.

    Science.gov (United States)

    Li, Peng; Zong, Yichen; Zhang, Yingying; Yang, Mengmeng; Zhang, Rufan; Li, Shuiqing; Wei, Fei

    2013-04-21

    We fabricated depth-type hierarchical CNT/quartz fiber (QF) filters through in situ growth of CNTs upon quartz fiber (QF) filters using a floating catalyst chemical vapor deposition (CVD) method. The filter specific area of the CNT/QF filters is more than 12 times higher than that of the pristine QF filters. As a result, the penetration of sub-micron aerosols for CNT/QF filters is reduced by two orders of magnitude, which reaches the standard of high-efficiency particulate air (HEPA) filters. Simultaneously, due to the fluffy brush-like hierarchical structure of CNTs on QFs, the pore size of the hybrid filters only has a small increment. The pressure drop across the CNT/QF filters only increases about 50% with respect to that of the pristine QF filters, leading to an obvious increased quality factor of the CNT/QF filters. Scanning electron microscope images reveal that CNTs are very efficient in capturing sub-micron aerosols. Moreover, the CNT/QF filters show high water repellency, implying their superiority for applications in humid conditions.

  12. Facile and Scalable Fabrication of Highly Efficient Lead Iodide Perovskite Thin-Film Solar Cells in Air Using Gas Pump Method.

    Science.gov (United States)

    Ding, Bin; Gao, Lili; Liang, Lusheng; Chu, Qianqian; Song, Xiaoxuan; Li, Yan; Yang, Guanjun; Fan, Bin; Wang, Mingkui; Li, Chengxin; Li, Changjiu

    2016-08-10

    Control of the perovskite film formation process to produce high-quality organic-inorganic metal halide perovskite thin films with uniform morphology, high surface coverage, and minimum pinholes is of great importance to highly efficient solar cells. Herein, we report on large-area light-absorbing perovskite films fabrication with a new facile and scalable gas pump method. By decreasing the total pressure in the evaporation environment, the gas pump method can significantly enhance the solvent evaporation rate by 8 times faster and thereby produce an extremely dense, uniform, and full-coverage perovskite thin film. The resulting planar perovskite solar cells can achieve an impressive power conversion efficiency up to 19.00% with an average efficiency of 17.38 ± 0.70% for 32 devices with an area of 5 × 2 mm, 13.91% for devices with a large area up to 1.13 cm(2). The perovskite films can be easily fabricated in air conditions with a relative humidity of 45-55%, which definitely has a promising prospect in industrial application of large-area perovskite solar panels.

  13. Micro-Fabrication and Circuit Optimization for Magnetic Components of High-Efficiency DC-DC Converters

    Science.gov (United States)

    Tian, Rui

    Magnetic components are essential parts of power converters. Inductors with magnetic cores are investigated. An eddy current loss model for pot-core inductors is developed with finite elemental analysis (FEA). The reliability of inductors using magnetic cores in a high-temperature environment is investigated. Working in up to 150°C circumstance for a short periods is not destructive for the inductors. Optimization of toroidal inductors in a DC-DC converter is investigated. Parasitic capacitance and the capacitive loss in toroidal inductors are modeled. Standard circuit optimization is performed to explore the energy conversion efficiency of the toroidal inductors. Thermal analysis, light-load efficiency and relative permeability of the toroidal inductor design are also investigated. The toroidal inductor can achieve about 85% efficiency for 3 A DC current and 1 W/mm2 power density. Inductor-only efficiency of toroidal inductors is investigated with revised model. At 100 MHz operating frequency, toroidal inductors can achieve more than 97% inductor efficiency with power density range of 0.7 W/mm2 to 6 W/mm2. The performance of our nanograngular magnetic core is dependent on the angle of the poling magnetic field compared to the field during operation. Experiments on a serious of samples show that the poling angle can deviate by up to 15 degrees from ideal with only a small penalty in performance. The field-angle experiment is intended to prove integrated toroidal inductor process possible. A magnetic fixture model is proposed for large-scale toroidal inductor processing.

  14. High-efficiency superconducting nanowire single-photon detectors fabricated from MoSi thin-films.

    Science.gov (United States)

    Verma, V B; Korzh, B; Bussières, F; Horansky, R D; Dyer, S D; Lita, A E; Vayshenker, I; Marsili, F; Shaw, M D; Zbinden, H; Mirin, R P; Nam, S W

    2015-12-28

    We report on MoSi SNSPDs which achieved high system detection efficiency (87.1 ± 0.5% at 1542 nm) at 0.7 K and we demonstrate that these detectors can also be operated with saturated internal efficiency at a temperature of 2.3 K in a Gifford-McMahon cryocooler. We measured a minimum system jitter of 76 ps, maximum count rate approaching 10 MHz, and polarization dependence as low as 3.3 ± 0.1%. The performance of MoSi SNSPDs at 2.3 K is similar to the performance of WSi SNSPDs at < 1 K. The higher operating temperature of MoSi SNSPDs makes these devices promising for widespread use due to the simpler and less expensive cryogenics required for their operation.

  15. A highly efficient, stable, durable, and recyclable filter fabricated by femtosecond laser drilling of a titanium foil for oil-water separation

    Science.gov (United States)

    Ye, Sen; Cao, Qiang; Wang, Qingsong; Wang, Tianyuan; Peng, Qing

    2016-11-01

    It has been a long standing challenge to efficiently separate oil and water since prehistoric times, and now it has become even more desirable in oily wastewater purification and oil spill cleanup. Here we introduce a super oil-water separation filter with superhydrophilicity and underwater superoleophobicity, fabricated using femtosecond laser micro-hole drilling of a titanium foil. Such a simply-made filter, without any modification, can achieve a separation efficiency exceeding 99% in eight typical oil-water mixtures. It remains highly efficient after 40 cycles of recycling and after suffering erosion by corrosive media. Furthermore, the used filter, polluted with oil, could be recovered by ultraviolet illumination. The flux of filtered water is tunable by simply selecting the aperture of the microhole or the spacing between adjacent microholes. Such advanced functionality is due to roughness and the TiO2 layers on the ablated surface during fabrication. With superhydrophilic and superoleophobic surfaces, this oil-water filer is also suitable for applications in anti-fouling, anti-smudge, anti-fog, and self-cleaning.

  16. High-Efficiency InGaN/GaN Quantum Well-Based Vertical Light-Emitting Diodes Fabricated on β-Ga2O3 Substrate

    KAUST Repository

    Muhammed, Mufasila

    2017-09-11

    We demonstrate a state-of-the-art high-efficiency GaN-based vertical light-emitting diode (VLED) grown on a transparent and conductive (-201)-oriented (β-Ga2O3) substrate, obtained using a straightforward growth process that does not require a high cost lift-off technique or complex fabrication process. The high-resolution scanning transmission electron microscopy (STEM) images confirm that we produced high quality upper layers, including a multi-quantum well (MQW) grown on the masked β-Ga2O3 substrate. STEM imaging also shows a well-defined MQW without InN diffusion into the barrier. Electroluminescence (EL) measurements at room temperature indicate that we achieved a very high internal quantum efficiency (IQE) of 78%; at lower temperatures, IQE reaches ~ 86%. The photoluminescence (PL) and time-resolved PL analysis indicate that, at a high carrier injection density, the emission is dominated by radiative recombination with a negligible Auger effect; no quantum-confined Stark effect is observed. At low temperatures, no efficiency droop is observed at a high carrier injection density, indicating the superior VLED structure obtained without lift-off processing, which is cost-effective for large-scale devices.

  17. Efficient bragg grating fabrication in Ge-rich fibre by high-intensity femtosecond 264 mm irradation

    DEFF Research Database (Denmark)

    Slattery, S.A.; Nikogasyan, D.N.; Plougmann, Nikolai;

    2004-01-01

    Fibre Bragg gratings (FBGs) are usually fabricated by UV laser light (typically, 248 nm radiation from a KrF* excimer laser), which spectrally coincides with the absorption band of defects in germanosilicate fibre core [1, 2]. Recently, it was demonstrated that the use of highintensity femtosecon...

  18. Efficient bragg grating fabrication in Ge-rich fibre by high-intensity femtosecond 264 mm irradation

    DEFF Research Database (Denmark)

    Slattery, S.A.; Nikogasyan, D.N.; Plougmann, Nikolai

    2004-01-01

    Fibre Bragg gratings (FBGs) are usually fabricated by UV laser light (typically, 248 nm radiation from a KrF* excimer laser), which spectrally coincides with the absorption band of defects in germanosilicate fibre core [1, 2]. Recently, it was demonstrated that the use of highintensity femtosecon...

  19. Anatase TiO2 pillar-nanoparticle composite fabricated by layer-by-layer assembly for high-efficiency dye-sensitized solar cells.

    Science.gov (United States)

    Zhang, Guoliang; Pan, Kai; Zhou, Wei; Qu, Yang; Pan, Qingjing; Jiang, Baojiang; Tian, Guohui; Wang, Guofeng; Xie, Ying; Dong, Youzhen; Miao, Xiaohuan; Tian, Chungui

    2012-11-07

    The anatase TiO(2) pillar (PL)-TiO(2) nanoparticle (NP) composite is fabricated via layer-by-layer assembly. The composition of the nanostructures (i.e. the pillar-to-nanoparticle ratio) can be conveniently tuned by controlling the experimental conditions of the layer-by-layer assembly. It has been used to fabricate photoelectrodes for high-efficiency dye-sensitized solar cells (DSSCs), which combine the advantages of the rapid electron transport in PLs with the high surface area of NPs. It was found that, with optimum preparation conditions, DSSCs with the composite photoelectrode show a better photoelectrical conversion efficiency (8.06%) than those with either the naked PL photoelectrode or the mechanically mixed PL-NP photoelectrode. This is explained by the photoelectron injection drive force and the interfacial electron transport of the DSSCs, which are quantitatively characterized using the surface photovoltage spectra and electrochemical impedance spectroscopy measurements. It is evident that the DSSC with the optimal PL/NP ratio displays the largest photoelectron injection drive force and the fastest interfacial electron transfer.

  20. Fundamental thermodynamics and experiments in fabricating high efficiency CuInSe[sub 2] solar cells by selenization without the use of H[sub 2]Se

    Energy Technology Data Exchange (ETDEWEB)

    Albin, D.; Carapella, J.; Gabor, A.; Tennant, A.; Tuttle, J.; Duda, A.; Matson, R.; Mason, A.; Contreras, M.; Noufi, R. (National Renewable Energy Laboratory, 1617 Cole Boulevard, Golden, Colorado 80401 (United States))

    1992-12-01

    Selenization is the current process by which state-of-the-art CuInSe[sub 2] polycrystalline thin-film photovoltaic modules are industrially fabricated. The distinguishing characteristic of this approach is that material deposition is separate from compound formation. In conventional selenization, In-Cu layers, often referred to as precursors, are deposited on molybdenum-coated glass substrates and subsequently transformed into CuInSe[sub 2] following exposure to a selenium-containing environment. Although the highly toxic gas, H[sub 2]Se, has been considered a necessary component of selenization, recent safety concerns have accelerated the development of Se vapor as a possible substitute for H[sub 2]Se. In more recent variations of the process, solid selenium is incorporated during the precursor fabrication step, and subsequent thermal annealing is used to form compounds among the three elements. In this paper, we discuss the thermodynamic fundamentals of selenization using elemental Se as an alternative to H[sub 2]Se. This discussion is augmented by empirical observations drawn from our own efforts in fabricating efficient ([gt]10%) CdS/CuInSe[sub 2] devices by selenization in thermally-evaporated Se vapors. Indium transport, presumably via the formation of In[sub 2]Se or InSe gaseous species, dominates the kinetics of selenization using sequentially evaporated (indium on copper) precursors, while lateral phase separation was observed in the case of co-deposited In+Cu precursors.

  1. One-step fabrication of copper sulfide nanoparticles decorated on graphene sheets as highly stable and efficient counter electrode for CdS-sensitized solar cells

    Science.gov (United States)

    Hessein, Amr; Wang, Feiju; Masai, Hirokazu; Matsuda, Kazunari; Abd El-Moneim, Ahmed

    2016-11-01

    Quantum-dot-sensitized solar cells (QDSSCs) are thin-film photovoltaics and highly promising as next-generation solar cells owing to their high theoretical efficiency, easy fabrication process, and low production cost. However, the practical photoconversion efficiencies (PCEs) of QDSSCs are still far below the theoretically estimated value owing to the lack of an applicable design of the materials and electrodes. In this work, we developed a highly stable and efficient counter electrode (CE) from copper sulfide nanocrystals and reduced graphene oxide (Cu x S@RGO) for QDSSC applications. The Cu x S@RGO electrocatalyst was successfully prepared by a facile one-pot hydrothermal method, then directly applied to a fluorine-doped tin oxide (FTO)-coated glass substrate by the simple drop-casting technique. Owing to the synergistic effect between Cu x S nanocrystals and conductive RGO sheets, the Cu x S@RGO CE showed high electrocatalytic activity for polysulfide electrolyte reduction. A CdS QDSSC based on the Cu x S@RGO CE yielded a high and reproducible PCE of 2.36%, exceeding those of 1.57 and 1.33% obtained with the commonly used Cu2S/brass and Pt CEs, respectively. Moreover, the QDSSC with the Cu x S@RGO CE showed excellent photostability in a light-soaking test without any obvious decay in the photocurrent, whereas the cell based on the Cu2S/brass CE was severely degraded.

  2. High efficiency

    Energy Technology Data Exchange (ETDEWEB)

    Baumann, G.

    1984-05-18

    The surgeon wants to have phlebograms with good contrast, which should show only the deep venous system and leaks to the superficial system, that means, the insufficient communicating veins and the inflow of the big and small saphenous vein into the deep vein must be visible. The most frequent causes for X-ray-prints of bad quality are: a too high position of the stowing, too high puncture at the back of the foot, bad focussing without showing the ankle joint or the popliteal region and too narrow sections of the X-ray-films as well as too late exposures with fullfilling of the total superficial venous system and extreme superposition on the film.

  3. Beam Shaping Technologies for High Efficiency Laser Fabrication%用于实现激光高效率加工的光束整形技术

    Institute of Scientific and Technical Information of China (English)

    夏国才; 孙小燕; 段吉安

    2012-01-01

    Laser has been widely used in the fabrication field due to its special features of high penetrability and intensity. However, certain modifications in space and time domain should be made to meet the high standards in the efficiency and precision of fabrication with laser. Spatial shaping technology is based on the dipodic principle, the diffraction principle and the polarization principle of light. Temporal shaping technology includes the pulse compression technique and the pulse train control technique.%激光凭借其穿透性和高强度的独特优势,已在加工领域得到广泛应用,但为了实现激光加工的高效率、高精度指标,需要对激光进行空域整形和时域整形.空域整形技术主要是基于折射原理、衍射原理或偏振原理的整形技术,时域整形技术主要包括脉冲压缩技术和脉冲序列控制技术.

  4. Fabrication of High Efficiency Dye-Sensitized Solar Cells Based on TiO2 Nanoparticles Embedded in Ti Substrate.

    Science.gov (United States)

    Kim, Kang-Pil; Lee, Sang-Ju; Hwang, Dae-Kue; Kim, Dae-Hwan; Heo, Young-Woo

    2015-01-01

    We have embedded a TiO2 nanoparticle (NP) photoelectrode in a Ti substrate to improve the cell efficiency of conventional TiO2 NP based dye-sensitized solar cells (DSSCs) using Ti substrate. Compared to the conventional standing-type (TiO2 NPs on Ti substrate) DSSCs, the embedded-type (TiO2 NPs embedded in Ti substrate) DSSCs have shown an approximately 35% improvement in power conversion efficiency due to the improvement of J(sc). The embedded-type DSSCs have more charge transport paths than do standing-type DSSCs due to the increase of contact area between the TiO2 NP sidewall and the Ti substrate. This increased contact area decreases the electrical resistance and increases the charge collection efficiency, which leads to the improvement of J(sc). The embedded-type NP-DSSCs are very effective DSSC structures for enhancing the power conversion efficiency of Ti substrate based DSSCs.

  5. Facile fabrication of high-efficiency near-infrared absorption film with tungsten bronze nanoparticle dense layer

    Science.gov (United States)

    Lee, Seong Yun; Kim, Jae Young; Lee, Jun Young; Song, Ho Jun; Lee, Sangkug; Choi, Kyung Ho; Shin, Gyojic

    2014-06-01

    An excellent transparent film with effective absorption property in near-infrared (NIR) region based on cesium-doped tungsten oxide nanoparticles was fabricated using a facile double layer coating method via the theoretical considerations. The optical performance was evaluated; the double layer-coated film exhibited 10% transmittance at 1,000 nm in the NIR region and over 80% transmittance at 550 nm in the visible region. To optimize the selectivity, the optical spectrum of this film was correlated with a theoretical model by combining the contributions of the Mie-Gans absorption-based localized surface plasmon resonance and reflections by the interfaces of the heterogeneous layers and the nanoparticles in the film. Through comparison of the composite and double layer coating method, the difference of the nanoscale distances between nanoparticles in each layer was significantly revealed. It is worth noting that the nanodistance between the nanoparticles decreased in the double layer film, which enhanced the optical properties of the film, yielding a haze value of 1% or less without any additional process. These results are very attractive for the nanocomposite coating process, which would lead to industrial fields of NIR shielding and thermo-medical applications.

  6. A high efficiency industrial polysilicon solar cell with a honeycomb-like surface fabricated by wet etching using a photoresist mask

    Science.gov (United States)

    Zhang, Hong; Ding, Bin; Chen, Tianhang

    2016-11-01

    In this paper, an effective and low cost method of texturization was introduced into the fabrication process for industrial multicrystalline silicon solar cell production. The purpose of the method was to reduce reflectance by creating a honeycomb-like textured surface using a masked wet etching process. A negative photoresist film was selected as an etching mask. Although large surface roughness of wafer was considered to affect the adhesion and acid resistance of etching mask, a honeycomb-like textured surface with a pitch of 18 μm was fabricated successfully. The etched pits had a nearly smooth spherical segment surface, an average aperture of 15.1 μm, and a depth of 6.5 μm. This regular textured surface had a low light reflectivity of approximately 20.5% and greatly increased the carrier lifetime. Compared with multicrystalline silicon solar cells textured by conventional acid etching, the average short circuit current increased by 2.2% and the average efficiency increased from 17.41% to 17.75%, a net gain of 0.34%. And a high throughput above 2400 pieces per hour was obtained. This texturing technique is expected to promote the application of diamond-wire cut multicrystalline silicon wafers with the low saw-damage in the future.

  7. Remarkably High Conversion Efficiency of Inverted Bulk Heterojunction Solar Cells: From Ultrafast Laser Spectroscopy and Electron Microscopy to Device Fabrication and Optimization

    KAUST Repository

    Alsulami, Qana

    2016-04-10

    In organic donor-acceptor systems, ultrafast interfacial charge transfer (CT), charge separation (CS), and charge recombination (CR) are key determinants of the overall performance of photovoltaic devices. However, a profound understanding of these photophysical processes at device interfaces remains superficial, creating a major bottleneck that circumvents advancements and the optimization of these solar cells. Here, results from time-resolved laser spectroscopy and high-resolution electron microscopy are examined to provide the fundamental information necessary to fabricate and optimize organic solar cell devices. In real time, CT and CS are monitored at the interface between three fullerene acceptors (FAs) (PC71BM, PC61BM, and IC60BA) and the PTB7-Th donor polymer. Femtosecond transient absorption (fs-TA) data demonstrates that photoinduced electron transfer from the PTB7-Th polymer to each FA occurs on the sub-picosecond time scale, leading to the formation of long-lived radical ions. It is also found that the power conversion efficiency improves from 2% in IC60BA-based solar cells to >9% in PC71BM-based devices, in support of our time-resolved results. The insights reported in this manuscript provide a clear understanding of the key variables involved at the device interface, paving the way for the exploitation of efficient CS and subsequently improving the photoconversion efficiency. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  8. Fabrication of high efficacy selective solar absorbers

    CSIR Research Space (South Africa)

    Tile, N

    2012-03-01

    Full Text Available High efficiency tandem selective solar absorber materials of carbon in nickel oxide (C-NiO) composite were fabricated on an aluminium substrate using a simple and cost effective sol-gel process. The process involved preparation of carbon and nickel...

  9. One-step fabrication of highly stable, superhydrophobic composites from controllable and low-cost PMHS/TEOS sols for efficient oil cleanup.

    Science.gov (United States)

    Guo, Ping; Zhai, Shangru; Xiao, Zuoyi; An, Qingda

    2015-05-15

    Facing the issues of significant increase of industrial oily wastewater and frequent accident of oil spills, the developing of efficient and affordable absorbents for improving oil pollution is of practical significance. Herein, several superhydrophobic and superoleophilic materials, utilizing filter paper, filter cloth and polyester sponge as substrates, through facile coating of hybrid SiO2 colloid particles from controllable PMHS-TEOS sol system were presented. These methyl-modified particles not only provided hierarchical micro/nano-scale structure with distinct roughness, but also largely lowered the surface energy of the coated substances, leading to excellent superhydrophobic and superoleophilic surfaces. The modified filter cloths could be applied for oil/water separation owing to the flexible and foldable property; sponges could efficiently absorb oil or organic solvents in situ on account of its low density and high porosity, and meanwhile the absorbed oil could be easily recollected by simple squeezing. It is worth mentioning that both modified filter cloths and sponges exhibited excellent selectivity, high efficiency, outstanding rapidity and remarkable recyclability. More importantly, after treatment of 100 abrasion cycles with metal scalpel and strongly acidic and basic water droplets, the whole WCA values of resultant filter cloths still maintained superhydrophobic character (>150°), illuminating the charming mechanical and chemical stability of sol-gel processed coating with hierarchical roughness and covalently bonded methyl groups. Combining controllable fabrication process and cheap raw precursors, this method enables scalable manufacturing of stable and superhydrophobic substances, which are promising in practical applications involved in oil/water separation and oil sorption. Copyright © 2015 Elsevier Inc. All rights reserved.

  10. High efficiency a-Si:H/a-SiGe:H tandem solar cells fabricated with the combination of V- and U-shaped band gap profiling techniques

    Science.gov (United States)

    Inthisang, Sorapong; Krajangsang, Taweewat; Hongsingthong, Aswin; Limmanee, Amornrat; Kittisontirak, Songkiate; Jaroensathainchok, Suttinan; Moolakorn, Apichan; Dousse, Adrien; Sritharathikhun, Jaran; Sriprapha, Kobsak

    2015-08-01

    Hydrogenated amorphous silicon germanium (a-SiGe:H) films prepared by very high frequency plasma-enhanced chemical vapor deposition (VHF-PECVD) using a mixture of SiH4, H2, and GeH4 were investigated for their use as the bottom cell of amorphous silicon/amorphous silicon germanium (a-Si:H/a-SiGe:H) tandem solar cell structures. Narrow optical band gaps (Eopt) in the range of 1.5 to 1.6 eV were obtained by varying the GeH4/(SiH4 + GeH4) gas flow rate ratio in low-temperature deposition. The a-SiGe:H films deposited with various GeH4/(SiH4 + GeH4) gas flow rate ratios were used as intrinsic layers for the a-Si:H/a-SiGe:H tandem solar cells with different graded band gaps: V-, VU-, and U-shapes. It was found that using the VU-shape improves the solar cell efficiency owing to a higher Jsc when compared with using V-shape. The VU-shape’s Voc and FF are also improved when compared with the U-shape’s Voc and FF. As a result, a high efficiency of 11.0% (Voc = 1.74 V, Jsc = 9.07 mA/cm2, and FF = 0.70) was successfully achieved with the solar cells fabricated using the VU-shape graded band gap technique.

  11. Highly Reproducible Perovskite Solar Cells with Average Efficiency of 18.3% and Best Efficiency of 19.7% Fabricated via Lewis Base Adduct of Lead(II) Iodide.

    Science.gov (United States)

    Ahn, Namyoung; Son, Dae-Yong; Jang, In-Hyuk; Kang, Seong Min; Choi, Mansoo; Park, Nam-Gyu

    2015-07-15

    High efficiency perovskite solar cells were fabricated reproducibly via Lewis base adduct of lead(II) iodide. PbI2 was dissolved in N,N-dimethyformamide with equimolar N,N-dimethyl sulfoxide (DMSO) and CH3NH3I. Stretching vibration of S═O appeared at 1045 cm(-1) for bare DMSO, which was shifted to 1020 and 1015 cm(-1) upon reacting DMSO with PbI2 and PbI2 + CH3NH3I, respectively, indicative of forming the adduct of PbI2·DMSO and CH3NH3I·PbI2·DMSO due to interaction between Lewis base DMSO and/or iodide (I(-)) and Lewis acid PbI2. Spin-coating of a DMF solution containing PbI2, CH3NH3I, and DMSO (1:1:1 mol %) formed a transparent adduct film, which was converted to a dark brown film upon heating at low temperature of 65 °C for 1 min due to removal of the volatile DMSO from the adduct. The adduct-induced CH3NH3PbI3 exhibited high charge extraction characteristics with hole mobility as high as 3.9 × 10(-3) cm(2)/(V s) and slow recombination rate. Average power conversion efficiency (PCE) of 18.3% was achieved from 41 cells and the best PCE of 19.7% was attained via adduct approach.

  12. High-Thermal-Conductivity Fabrics

    Science.gov (United States)

    Chibante, L. P. Felipe

    2012-01-01

    Heat management with common textiles such as nylon and spandex is hindered by the poor thermal conductivity from the skin surface to cooling surfaces. This innovation showed marked improvement in thermal conductivity of the individual fibers and tubing, as well as components assembled from them. The problem is centered on improving the heat removal of the liquid-cooled ventilation garments (LCVGs) used by astronauts. The current design uses an extensive network of water-cooling tubes that introduces bulkiness and discomfort, and increases fatigue. Range of motion and ease of movement are affected as well. The current technology is the same as developed during the Apollo program of the 1960s. Tubing material is hand-threaded through a spandex/nylon mesh layer, in a series of loops throughout the torso and limbs such that there is close, form-fitting contact with the user. Usually, there is a nylon liner layer to improve comfort. Circulating water is chilled by an external heat exchanger (sublimator). The purpose of this innovation is to produce new LCVG components with improved thermal conductivity. This was addressed using nanocomposite engineering incorporating high-thermalconductivity nanoscale fillers in the fabric and tubing components. Specifically, carbon nanotubes were added using normal processing methods such as thermoplastic melt mixing (compounding twin screw extruder) and downstream processing (fiber spinning, tubing extrusion). Fibers were produced as yarns and woven into fabric cloths. The application of isotropic nanofillers can be modeled using a modified Nielsen Model for conductive fillers in a matrix based on Einstein s viscosity model. This is a drop-in technology with no additional equipment needed. The loading is limited by the ability to maintain adequate dispersion. Undispersed materials will plug filtering screens in processing equipment. Generally, the viscosity increases were acceptable, and allowed the filled polymers to still be

  13. Fabrication of high-efficiency and low-stray-light grating by inductively coupled plasma(ICP) etching-polishing method.

    Science.gov (United States)

    Tan, X; Jiao, Q B; Qi, X D; Bayan, H

    2016-03-21

    Gratings with stray light of 4.99 × 10-7-5.67 × 10-7 and efficiency of 93%-95% in a wavelength range of 1592 nm-1632 nm on Si-surface-modification SiC, fused silica and BK7 have been fabricated by the method of ICP etching-polishing. The CHF3 and SF6 plasma were used to etch a preliminary grating profile. Ar and O2 plasma with low energy were then used to polish the grating to acquire low surface roughness and groove profiles closer to the ideal profiles. The morphologies of the gratings were characterized by AFM. The efficiencies and stray light were measured quantitatively by self-developed equipment. These results show that the ICP etching-polishing method is a promising candidate for production of good quality gratings into common optical materials.

  14. Research cooperation project on environmentally friendly technology for highly efficient mineral resources extraction and treatment. Detail design for pilot plant (Electrical fabrication)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    The paper prepared plans of the electrical equipment in the detailed design of a pilot plant in the joint research project on the environmental protection technology for highly efficient mineral resource extraction and treatment. (NEDO)

  15. Fabrication of Very High Efficiency 5.8 GHz Power Amplifiers using AlGaN HFETs on SiC Substrates for Wireless Power Transmission

    Science.gov (United States)

    Sullivan, Gerry

    2001-01-01

    For wireless power transmission using microwave energy, very efficient conversion of the DC power into microwave power is extremely important. Class E amplifiers have the attractive feature that they can, in theory, be 100% efficient at converting, DC power to RF power. Aluminum gallium nitride (AlGaN) semiconductor material has many advantageous properties, relative to silicon (Si), gallium arsenide (GaAs), and silicon carbide (SiC), such as a much larger bandgap, and the ability to form AlGaN/GaN heterojunctions. The large bandgap of AlGaN also allows for device operation at higher temperatures than could be tolerated by a smaller bandgap transistor. This could reduce the cooling requirements. While it is unlikely that the AlGaN transistors in a 5.8 GHz class E amplifier can operate efficiently at temperatures in excess of 300 or 400 C, AlGaN based amplifiers could operate at temperatures that are higher than a GaAs or Si based amplifier could tolerate. Under this program, AlGaN microwave power HFETs have been fabricated and characterized. Hybrid class E amplifiers were designed and modeled. Unfortunately, within the time frame of this program, good quality HFETs were not available from either the RSC laboratories or commercially, and so the class E amplifiers were not constructed.

  16. Efficient Synthesis of Graphene Nanoscrolls for Fabricating Sulfur-Loaded Cathode and Flexible Hybrid Interlayer toward High-Performance Li-S Batteries.

    Science.gov (United States)

    Guo, Yi; Zhao, Gang; Wu, Naiteng; Zhang, Yun; Xiang, Mingwu; Wang, Bo; Liu, Heng; Wu, Hao

    2016-12-21

    A modified lyophilization approach is developed and used for highly efficient transformation of 2D graphene oxide sheet into 1D graphene nanoscroll (GNS) with high topological transforming efficiency (∼94%). Because of the unique open tubular structure and large specific surface area (545 m(2) g(-1)), GNS is utilized for the first time as a porous cathode scaffold for encapsulating sulfur with a high loading (81 wt %), and also as a conductive skeleton for assembling MnO2 nanowires into a flexible free-standing hybrid interlayer, both enabling high-rate and long-life Li-S battery.

  17. Fabrication of electrocatalyst based on nitrogen doped graphene as highly efficient and durable support for using in polymer electrolyte fuel cell

    Science.gov (United States)

    Heydari, Ahmad; Gharibi, Hussein

    2016-09-01

    In this work, we have used an efficient approach to prepare nitrogen-doped graphene supported Pt nanoparticles (Pt/N-rGO). The nitrogen-doped graphene nanocomposites (N-rGO) were derived from pyrolysis of graphene oxide/polyaniline composites in nitrogen atmosphere. X-ray powder diffraction, FTIR spectroscopy, Raman spectroscopy, X-ray photoelectron spectroscopy and Transmission and Scanning electron microscopy (TEM&SEM) were used to characterize the morphology and microstructure of the prepared catalysts. The TEM and elemental mapping images indicate that metal nanoparticles are more uniformly dispersed on the surface of N-doped graphene than other supports, and Pt nanoparticles dispersed without any aggregation. The catalytic activity and durability of the catalysts was evaluated by various electrochemical techniques. Compared to undoped Pt/rGO and commercial Pt/C catalysts, an enhanced electrocatalytic activity was obtained in the case of the Pt/N-rGO with optimized composition and nanostructure. The maximum power density of MEA for Pt/N-rGO was 1.4 times more than that of MEA fabricated by commercial Pt/C 20%.

  18. Fabrication and characterization of Al2O3 /Si composite nanodome structures for high efficiency crystalline Si thin film solar cells

    Science.gov (United States)

    Zhang, Ruiying; Zhu, Jian; Zhang, Zhen; Wang, Yanyan; Qiu, Bocang; Liu, Xuehua; Zhang, Jinping; Zhang, Yi; Fang, Qi; Ren, Zhong; Bai, Yu

    2015-12-01

    We report on our fabrication and characterization of Al2O3/Si composite nanodome (CND) structures, which is composed of Si nanodome structures with a conformal cladding Al2O3 layer to evaluate its optical and electrical performance when it is applied to thin film solar cells. It has been observed that by application of Al2O3thin film coating using atomic layer deposition (ALD) to the Si nanodome structures, both optical and electrical performances are greatly improved. The reflectivity of less than 3% over the wavelength range of from 200 nm to 2000 nm at an incident angle from 0° to 45° is achieved when the Al2O3 film is 90 nm thick. The ultimate efficiency of around 27% is obtained on the CND textured 2 μm-thick Si solar cells, which is compared to the efficiency of around 25.75% and 15% for the 2 μm-thick Si nanodome surface-decorated and planar samples respectively. Electrical characterization was made by using CND-decorated MOS devices to measure device's leakage current and capacitance dispersion. It is found the electrical performance is sensitive to the thickness of the Al2O3 film, and the performance is remarkably improved when the dielectric layer thickness is 90 nm thick. The leakage current, which is less than 4x10-9 A/cm2 over voltage range of from -3 V to 3 V, is reduced by several orders of magnitude. C-V measurements also shows as small as 0.3% of variation in the capacitance over the frequency range from 10 kHz to 500 kHz, which is a strong indication of surface states being fully passivated. TEM examination of CND-decorated samples also reveals the occurrence of SiOx layer formed between the interface of Si and the Al2O3 film, which is thin enough that ensures the presence of field-effect passivation, From our theoretical and experimental study, we believe Al2O3 coated CND structures is a truly viable approach to achieving higher device efficiency.

  19. Fabrication and characterization of Al{sub 2}O{sub 3} /Si composite nanodome structures for high efficiency crystalline Si thin film solar cells

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Ruiying, E-mail: ryzhang2008@sinano.ac.cn [Key lab of nanodevices and applications, Chinese Academy of Sciences, Division of nano-devices and related materials, Suzhou Institute of Nano-tech and Nano-bionics, Chinese Academy of Sciences, Suzhou, 215123 (China); State Key Laboratory of Functional Materials for Informatics, Shanghai Institute of Microsystem and Information Technology, Chinese Academy of Sciences, 865 Changning Road, Shanghai 200050 China (China); Zhu, Jian; Zhang, Zhen; Wang, Yanyan; Qiu, Bocang [Key lab of nanodevices and applications, Chinese Academy of Sciences, Division of nano-devices and related materials, Suzhou Institute of Nano-tech and Nano-bionics, Chinese Academy of Sciences, Suzhou, 215123 (China); Liu, Xuehua; Zhang, Jinping; Zhang, Yi [Platform for Characterization & Test, Suzhou Institute of Nano-tech and Nano-bionics, Chinese Academy of Sciences, Suzhou, 215123 (China); Fang, Qi; Ren, Zhong [Oxford Instruments Plasma Technology, Yatton, Bristol, BS49 4AP (United Kingdom); Bai, Yu [School of Nano-Science and Nano-Engineering, Xi’an Jiaotong University, Suzhou, 215123 (China)

    2015-12-15

    We report on our fabrication and characterization of Al{sub 2}O{sub 3}/Si composite nanodome (CND) structures, which is composed of Si nanodome structures with a conformal cladding Al{sub 2}O{sub 3} layer to evaluate its optical and electrical performance when it is applied to thin film solar cells. It has been observed that by application of Al{sub 2}O{sub 3}thin film coating using atomic layer deposition (ALD) to the Si nanodome structures, both optical and electrical performances are greatly improved. The reflectivity of less than 3% over the wavelength range of from 200 nm to 2000 nm at an incident angle from 0° to 45° is achieved when the Al{sub 2}O{sub 3} film is 90 nm thick. The ultimate efficiency of around 27% is obtained on the CND textured 2 μm-thick Si solar cells, which is compared to the efficiency of around 25.75% and 15% for the 2 μm-thick Si nanodome surface-decorated and planar samples respectively. Electrical characterization was made by using CND-decorated MOS devices to measure device’s leakage current and capacitance dispersion. It is found the electrical performance is sensitive to the thickness of the Al{sub 2}O{sub 3} film, and the performance is remarkably improved when the dielectric layer thickness is 90 nm thick. The leakage current, which is less than 4x10{sup −9} A/cm{sup 2} over voltage range of from -3 V to 3 V, is reduced by several orders of magnitude. C-V measurements also shows as small as 0.3% of variation in the capacitance over the frequency range from 10 kHz to 500 kHz, which is a strong indication of surface states being fully passivated. TEM examination of CND-decorated samples also reveals the occurrence of SiO{sub x} layer formed between the interface of Si and the Al{sub 2}O{sub 3} film, which is thin enough that ensures the presence of field-effect passivation, From our theoretical and experimental study, we believe Al{sub 2}O{sub 3} coated CND structures is a truly viable approach to achieving higher device

  20. Fabrication and characterization of Al2O3 /Si composite nanodome structures for high efficiency crystalline Si thin film solar cells

    Directory of Open Access Journals (Sweden)

    Ruiying Zhang

    2015-12-01

    Full Text Available We report on our fabrication and characterization of Al2O3/Si composite nanodome (CND structures, which is composed of Si nanodome structures with a conformal cladding Al2O3 layer to evaluate its optical and electrical performance when it is applied to thin film solar cells. It has been observed that by application of Al2O3thin film coating using atomic layer deposition (ALD to the Si nanodome structures, both optical and electrical performances are greatly improved. The reflectivity of less than 3% over the wavelength range of from 200 nm to 2000 nm at an incident angle from 0° to 45° is achieved when the Al2O3 film is 90 nm thick. The ultimate efficiency of around 27% is obtained on the CND textured 2 μm-thick Si solar cells, which is compared to the efficiency of around 25.75% and 15% for the 2 μm-thick Si nanodome surface-decorated and planar samples respectively. Electrical characterization was made by using CND-decorated MOS devices to measure device’s leakage current and capacitance dispersion. It is found the electrical performance is sensitive to the thickness of the Al2O3 film, and the performance is remarkably improved when the dielectric layer thickness is 90 nm thick. The leakage current, which is less than 4x10−9 A/cm2 over voltage range of from -3 V to 3 V, is reduced by several orders of magnitude. C-V measurements also shows as small as 0.3% of variation in the capacitance over the frequency range from 10 kHz to 500 kHz, which is a strong indication of surface states being fully passivated. TEM examination of CND-decorated samples also reveals the occurrence of SiOx layer formed between the interface of Si and the Al2O3 film, which is thin enough that ensures the presence of field-effect passivation, From our theoretical and experimental study, we believe Al2O3 coated CND structures is a truly viable approach to achieving higher device efficiency.

  1. Facile fabrication of highly efficient AgI/ZnO heterojunction and its application of methylene blue and rhodamine B solutions degradation under natural sunlight

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Xinjun, E-mail: wxjtg2006@126.com; Wan, Xiaoli; Xu, Xiaoning; Chen, Xuenian

    2014-12-01

    Highlights: • A high-efficiency natural sunlight driven AgI/ZnO photocatalysts have been first prepared. • Our method is a simple, environment-friendly and cost-effective process. • The possible photocatalytic mechanism of AgI/ZnO was proposed. • AgI/ZnO exhibits higher efficiency for the degradation of methylene blue and rhodamine B under natural sunlight than a 500 W Xe lamp. - Abstract: The AgI/ZnO heterojunction was successfully synthesized by in situ deposition method and was found to be a natural sunlight driven photocatalyst. The photocatalytic efficiency of AgI/ZnO was evaluated by the degradation of rhodamine B under visible light irradiation. The influence of various operational parameters such as the effect of loading amount, catalyst dosage and initial RhB concentration on the photodegradation was investigated in detail and the results were discussed. The results indicated that the AgI/ZnO composites displayed much higher photocatalytic performances over ZnO as well as AgI. Moreover, the catalyst obviously showed higher efficiency for the degradation of methylene blue and rhodamine B under natural sunlight than a 500 W Xe lamp, and nearly 100% of dyes were degraded only in 120 min under the optimum conditions. At last, the quenching effects of different scavengers suggested that the reactive • OH and h{sup +} play the major role in the RhB degradation.

  2. An easy-to-fabricate low-temperature TiO2 electron collection layer for high efficiency planar heterojunction perovskite solar cells

    Directory of Open Access Journals (Sweden)

    B. Conings

    2014-08-01

    Full Text Available Organometal trihalide perovskite solar cells arguably represent the most auspicious new photovoltaic technology so far, as they possess an astonishing combination of properties. The impressive and brisk advances achieved so far bring forth highly efficient and solution processable solar cells, holding great promise to grow into a mature technology that is ready to be embedded on a large scale. However, the vast majority of state-of-the-art perovskite solar cells contains a dense TiO2 electron collection layer that requires a high temperature treatment (>450 °C, which obstructs the road towards roll-to-roll processing on flexible foils that can withstand no more than ∼150 °C. Furthermore, this high temperature treatment leads to an overall increased energy payback time and cumulative energy demand for this emerging photovoltaic technology. Here we present the implementation of an alternative TiO2 layer formed from an easily prepared nanoparticle dispersion, with annealing needs well within reach of roll-to-roll processing, making this technology also appealing from the energy payback aspect. Chemical and morphological analysis allows to understand and optimize the processing conditions of the TiO2 layer, finally resulting in a maximum obtained efficiency of 13.6% for a planar heterojunction solar cell within an ITO/TiO2/CH3NH3PbI3-xClxpoly(3-hexylthiophene/Ag architecture.

  3. An easy-to-fabricate low-temperature TiO2 electron collection layer for high efficiency planar heterojunction perovskite solar cells

    Science.gov (United States)

    Conings, B.; Baeten, L.; Jacobs, T.; Dera, R.; D'Haen, J.; Manca, J.; Boyen, H.-G.

    2014-08-01

    Organometal trihalide perovskite solar cells arguably represent the most auspicious new photovoltaic technology so far, as they possess an astonishing combination of properties. The impressive and brisk advances achieved so far bring forth highly efficient and solution processable solar cells, holding great promise to grow into a mature technology that is ready to be embedded on a large scale. However, the vast majority of state-of-the-art perovskite solar cells contains a dense TiO2 electron collection layer that requires a high temperature treatment (>450 °C), which obstructs the road towards roll-to-roll processing on flexible foils that can withstand no more than ˜150 °C. Furthermore, this high temperature treatment leads to an overall increased energy payback time and cumulative energy demand for this emerging photovoltaic technology. Here we present the implementation of an alternative TiO2 layer formed from an easily prepared nanoparticle dispersion, with annealing needs well within reach of roll-to-roll processing, making this technology also appealing from the energy payback aspect. Chemical and morphological analysis allows to understand and optimize the processing conditions of the TiO2 layer, finally resulting in a maximum obtained efficiency of 13.6% for a planar heterojunction solar cell within an ITO/TiO2/CH3NH3PbI3-xClxpoly(3-hexylthiophene)/Ag architecture.

  4. High sensitivity knitted fabric strain sensors

    Science.gov (United States)

    Xie, Juan; Long, Hairu; Miao, Menghe

    2016-10-01

    Wearable sensors are increasingly used in smart garments for detecting and transferring vital signals and body posture, movement and respiration. Existing fabric strain sensors made from metallized yarns have low sensitivity, poor comfort and low durability to washing. Here we report a knitted fabric strain sensor made from a cotton/stainless steel (SS) fibre blended yarn which shows much higher sensitivity than sensors knitted from metallized yarns. The fabric feels softer than pure cotton textiles owing to the ultrafine stainless steel fibres and does not lose its electrical property after washing. The reason for the high sensitivity of the cotton/SS knitted fabric sensor was explored by comparing its sensing mechanism with the knitted fabric sensor made from metallized yarns. The results show that the cotton/SS yarn-to-yarn contact resistance is highly sensitive to strain applied to hooked yarn loops.

  5. A review of high-efficiency silicon solar cells

    Science.gov (United States)

    Rohatgi, A.

    1986-01-01

    Various parameters that affect solar cell efficiency were discussed. It is not understood why solar cells produced from less expensive Czochralski (Cz) silicon are less efficient than cells fabricated from more expensive float-zone (Fz) silicon. Performance characteristics were presented for recently produced, high-efficient solar cells fabricated by Westinghouse Electric Corp., Spire Corp., University of New South Wales, and Stanford University.

  6. High efficiency incandescent lighting

    Science.gov (United States)

    Bermel, Peter; Ilic, Ognjen; Chan, Walker R.; Musabeyoglu, Ahmet; Cukierman, Aviv Ruben; Harradon, Michael Robert; Celanovic, Ivan; Soljacic, Marin

    2014-09-02

    Incandescent lighting structure. The structure includes a thermal emitter that can, but does not have to, include a first photonic crystal on its surface to tailor thermal emission coupled to, in a high-view-factor geometry, a second photonic filter selected to reflect infrared radiation back to the emitter while passing visible light. This structure is highly efficient as compared to standard incandescent light bulbs.

  7. High performance carbon nanotube - polymer nanofiber hybrid fabrics

    Science.gov (United States)

    Yildiz, Ozkan; Stano, Kelly; Faraji, Shaghayegh; Stone, Corinne; Willis, Colin; Zhang, Xiangwu; Jur, Jesse S.; Bradford, Philip D.

    2015-10-01

    Stable nanoscale hybrid fabrics containing both polymer nanofibers and separate and distinct carbon nanotubes (CNTs) are highly desirable but very challenging to produce. Here, we report the first instance of such a hybrid fabric, which can be easily tailored to contain 0-100% millimeter long CNTs. The novel CNT - polymer hybrid nonwoven fabrics were created by simultaneously electrospinning nanofibers onto aligned CNT sheets which were drawn and collected on a grounded, rotating mandrel. Due to the unique properties of the CNTs, the hybrids show very high tensile strength, very small pore size, high specific surface area and electrical conductivity. In order to further examine the hybrid fabric properties, they were consolidated under pressure, and also calendered at 70 °C. After calendering, the fabric's strength increased by an order of magnitude due to increased interactions and intermingling with the CNTs. The hybrids are highly efficient as aerosol filters; consolidated hybrid fabrics with a thickness of 20 microns and areal density of only 8 g m-2 exhibited ultra low particulate (ULPA) filter performance. The flexibility of this nanofabrication method allows for the use of many different polymer systems which provides the opportunity for engineering a wide range of nanoscale hybrid materials with desired functionalities.Stable nanoscale hybrid fabrics containing both polymer nanofibers and separate and distinct carbon nanotubes (CNTs) are highly desirable but very challenging to produce. Here, we report the first instance of such a hybrid fabric, which can be easily tailored to contain 0-100% millimeter long CNTs. The novel CNT - polymer hybrid nonwoven fabrics were created by simultaneously electrospinning nanofibers onto aligned CNT sheets which were drawn and collected on a grounded, rotating mandrel. Due to the unique properties of the CNTs, the hybrids show very high tensile strength, very small pore size, high specific surface area and electrical

  8. High Efficiency, High Performance Clothes Dryer

    Energy Technology Data Exchange (ETDEWEB)

    Peter Pescatore; Phil Carbone

    2005-03-31

    This program covered the development of two separate products; an electric heat pump clothes dryer and a modulating gas dryer. These development efforts were independent of one another and are presented in this report in two separate volumes. Volume 1 details the Heat Pump Dryer Development while Volume 2 details the Modulating Gas Dryer Development. In both product development efforts, the intent was to develop high efficiency, high performance designs that would be attractive to US consumers. Working with Whirlpool Corporation as our commercial partner, TIAX applied this approach of satisfying consumer needs throughout the Product Development Process for both dryer designs. Heat pump clothes dryers have been in existence for years, especially in Europe, but have not been able to penetrate the market. This has been especially true in the US market where no volume production heat pump dryers are available. The issue has typically been around two key areas: cost and performance. Cost is a given in that a heat pump clothes dryer has numerous additional components associated with it. While heat pump dryers have been able to achieve significant energy savings compared to standard electric resistance dryers (over 50% in some cases), designs to date have been hampered by excessively long dry times, a major market driver in the US. The development work done on the heat pump dryer over the course of this program led to a demonstration dryer that delivered the following performance characteristics: (1) 40-50% energy savings on large loads with 35 F lower fabric temperatures and similar dry times; (2) 10-30 F reduction in fabric temperature for delicate loads with up to 50% energy savings and 30-40% time savings; (3) Improved fabric temperature uniformity; and (4) Robust performance across a range of vent restrictions. For the gas dryer development, the concept developed was one of modulating the gas flow to the dryer throughout the dry cycle. Through heat modulation in a

  9. High Efficiency, High Performance Clothes Dryer

    Energy Technology Data Exchange (ETDEWEB)

    Peter Pescatore; Phil Carbone

    2005-03-31

    This program covered the development of two separate products; an electric heat pump clothes dryer and a modulating gas dryer. These development efforts were independent of one another and are presented in this report in two separate volumes. Volume 1 details the Heat Pump Dryer Development while Volume 2 details the Modulating Gas Dryer Development. In both product development efforts, the intent was to develop high efficiency, high performance designs that would be attractive to US consumers. Working with Whirlpool Corporation as our commercial partner, TIAX applied this approach of satisfying consumer needs throughout the Product Development Process for both dryer designs. Heat pump clothes dryers have been in existence for years, especially in Europe, but have not been able to penetrate the market. This has been especially true in the US market where no volume production heat pump dryers are available. The issue has typically been around two key areas: cost and performance. Cost is a given in that a heat pump clothes dryer has numerous additional components associated with it. While heat pump dryers have been able to achieve significant energy savings compared to standard electric resistance dryers (over 50% in some cases), designs to date have been hampered by excessively long dry times, a major market driver in the US. The development work done on the heat pump dryer over the course of this program led to a demonstration dryer that delivered the following performance characteristics: (1) 40-50% energy savings on large loads with 35 F lower fabric temperatures and similar dry times; (2) 10-30 F reduction in fabric temperature for delicate loads with up to 50% energy savings and 30-40% time savings; (3) Improved fabric temperature uniformity; and (4) Robust performance across a range of vent restrictions. For the gas dryer development, the concept developed was one of modulating the gas flow to the dryer throughout the dry cycle. Through heat modulation in a

  10. Improving Electron Mobility of Tetraphenylethene-Based AIEgens to Fabricate Nondoped Organic Light-Emitting Diodes with Remarkably High Luminance and Efficiency.

    Science.gov (United States)

    Lin, Gengwei; Peng, Huiren; Chen, Long; Nie, Han; Luo, Wenwen; Li, Yinghao; Chen, Shuming; Hu, Rongrong; Qin, Anjun; Zhao, Zujin; Tang, Ben Zhong

    2016-07-01

    Robust light-emitting materials with strong solid-state fluorescence as well as fast and balanced carrier transporting ability are crucial to achieve high-performance organic light-emitting diodes (OLEDs). In this contribution, two linear tetraphenylethene (TPE) derivatives (TPE-TPAPBI and TPE-DPBI) that are functionalized with hole-transporting triphenylamine and/or electron-transporting 1,2-diphenyl-1H-benzimidazole groups are synthesized and fully characterized. Both TPE-TPAPBI and TPE-DPBI have aggregation-induced emission attributes and excellent photoluminescence quantum yields approaching 100% in vacuum deposited films. They also possess good thermal property, giving high decomposition temperatures (480 and 483 °C) and glass-transition temperatures (141 and 157 °C). TPE-TPAPBI and TPE-DPBI present high electron mobilities of 1.80 × 10(-5) and 1.30 × 10(-4) cm(2) V (-1) s(-1), respectively, at an electric field of 3.6 × 10(5) V cm(-1), which are comparable or even superior to that of 1,3,5-tri(1-phenylbenzimidazol-2-yl)benzene. The nondoped OLED device employing TPE-TPAPBI as active layer performs outstandingly, affording ultrahigh luminance of 125 300 cd m(-2), and excellent maximum external quantum, power and current efficiencies of 5.8%, 14.6 lm W(-1), and 16.8 cd A(-1), respectively, with very small roll-offs, demonstrating that TPE-TPAPBI is a highly promising luminescent material for nondoped OLEDs.

  11. Efficient fabrication of high-capacity immobilized metal ion affinity chromatographic media: The role of the dextran-grafting process and its manipulation.

    Science.gov (United States)

    Zhao, Lan; Zhang, Jingfei; Huang, Yongdong; Li, Qiang; Zhang, Rongyue; Zhu, Kai; Suo, Jia; Su, Zhiguo; Zhang, Zhigang; Ma, Guanghui

    2016-03-01

    Novel high-capacity Ni(2+) immobilized metal ion affinity chromatographic media were prepared through the dextran-grafting process. Dextran was grafted to an allyl-activated agarose-based matrix followed by functionalization for the immobilized metal ion affinity chromatographic media. With elaborate regulation of the allylation degree, dextran was completely or partly grafted to agarose microspheres, namely, completely dextran-grafted agarose microspheres and partly dextran-grafted ones, respectively. Confocal laser scanning microscope results demonstrated that a good adjustment of dextran-grafting degree was achieved, and dextran was distributed uniformly in whole completely dextran-grafted microspheres, while just distributed around the outside of the partly dextran-grafted ones. Flow hydrodynamic properties were improved greatly after the dextran-grafting process, and the flow velocity increased by about 30% compared with that of a commercial chromatographic medium (Ni Sepharose FF). A significant improvement of protein binding performance was also achieved by the dextran-grafting process, and partly dextran-grafted Ni(2+) chelating medium had a maximum binding capacity for His-tagged lactate dehydrogenase about 2.5 times higher than that of Ni Sepharose FF. The results indicated that this novel chromatographic medium is promising for applications in high-efficiency and large-scale protein purification.

  12. Highly efficient high temperature electrolysis

    DEFF Research Database (Denmark)

    Hauch, Anne; Ebbesen, Sune; Jensen, Søren Højgaard;

    2008-01-01

    High temperature electrolysis of water and steam may provide an efficient, cost effective and environmentally friendly production of H-2 Using electricity produced from sustainable, non-fossil energy sources. To achieve cost competitive electrolysis cells that are both high performing i.e. minimum...... internal resistance of the cell, and long-term stable, it is critical to develop electrode materials that are optimal for steam electrolysis. In this article electrolysis cells for electrolysis of water or steam at temperatures above 200 degrees C for production of H-2 are reviewed. High temperature...... electrolysis is favourable from a thermodynamic point of view, because a part of the required energy can be supplied as thermal heat, and the activation barrier is lowered increasing the H-2 production rate. Only two types of cells operating at high temperature (above 200 degrees C) have been described...

  13. Facile fabrication of large-grain CH3NH3PbI3-xBrx films for high-efficiency solar cells via CH3NH3Br-selective Ostwald ripening

    Science.gov (United States)

    Yang, Mengjin; Zhang, Taiyang; Schulz, Philip; Li, Zhen; Li, Ge; Kim, Dong Hoe; Guo, Nanjie; Berry, Joseph J.; Zhu, Kai; Zhao, Yixin

    2016-08-01

    Organometallic halide perovskite solar cells (PSCs) have shown great promise as a low-cost, high-efficiency photovoltaic technology. Structural and electro-optical properties of the perovskite absorber layer are most critical to device operation characteristics. Here we present a facile fabrication of high-efficiency PSCs based on compact, large-grain, pinhole-free CH3NH3PbI3-xBrx (MAPbI3-xBrx) thin films with high reproducibility. A simple methylammonium bromide (MABr) treatment via spin-coating with a proper MABr concentration converts MAPbI3 thin films with different initial film qualities (for example, grain size and pinholes) to high-quality MAPbI3-xBrx thin films following an Ostwald ripening process, which is strongly affected by MABr concentration and is ineffective when replacing MABr with methylammonium iodide. A higher MABr concentration enhances I-Br anion exchange reaction, yielding poorer device performance. This MABr-selective Ostwald ripening process improves cell efficiency but also enhances device stability and thus represents a simple, promising strategy for further improving PSC performance with higher reproducibility and reliability.

  14. Highly efficient sorghum transformation

    OpenAIRE

    Liu, Guoquan; Godwin, Ian D.

    2012-01-01

    A highly efficient microprojectile transformation system for sorghum (Sorghum bicolor L.) has been developed by using immature embryos (IEs) of inbred line Tx430. Co-bombardment was performed with the neomycin phosphotransferase II (nptII) gene and the green fluorescent protein (gfp) gene, both under the control of the maize ubiquitin1 (ubi1) promoter. After optimization of both tissue culture media and parameters of microprojectile transformation, 25 independent transgenic events were obtain...

  15. Scalable, "Dip-and-Dry" Fabrication of a Wide-Angle Plasmonic Selective Absorber for High-Efficiency Solar-Thermal Energy Conversion.

    Science.gov (United States)

    Mandal, Jyotirmoy; Wang, Derek; Overvig, Adam C; Shi, Norman N; Paley, Daniel; Zangiabadi, Amirali; Cheng, Qian; Barmak, Katayun; Yu, Nanfang; Yang, Yuan

    2017-08-28

    A galvanic-displacement-reaction-based, room-temperature "dip-and-dry" technique is demonstrated for fabricating selectively solar-absorbing plasmonic-nanoparticle-coated foils (PNFs). The technique, which allows for facile tuning of the PNFs' spectral reflectance to suit different radiative and thermal environments, yields PNFs which exhibit excellent, wide-angle solar absorptance (0.96 at 15°, to 0.97 at 35°, to 0.79 at 80°), and low hemispherical thermal emittance (0.10) without the aid of antireflection coatings. The thermal emittance is on par with those of notable selective solar absorbers (SSAs) in the literature, while the wide-angle solar absorptance surpasses those of previously reported SSAs with comparable optical selectivities. In addition, the PNFs show promising mechanical and thermal stabilities at temperatures of up to 200 °C. Along with the performance of the PNFs, the simplicity, inexpensiveness, and environmental friendliness of the "dip-and-dry" technique makes it an appealing alternative to current methods for fabricating selective solar absorbers. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  16. High performance carbon nanotube--polymer nanofiber hybrid fabrics.

    Science.gov (United States)

    Yildiz, Ozkan; Stano, Kelly; Faraji, Shaghayegh; Stone, Corinne; Willis, Colin; Zhang, Xiangwu; Jur, Jesse S; Bradford, Philip D

    2015-10-28

    Stable nanoscale hybrid fabrics containing both polymer nanofibers and separate and distinct carbon nanotubes (CNTs) are highly desirable but very challenging to produce. Here, we report the first instance of such a hybrid fabric, which can be easily tailored to contain 0-100% millimeter long CNTs. The novel CNT - polymer hybrid nonwoven fabrics were created by simultaneously electrospinning nanofibers onto aligned CNT sheets which were drawn and collected on a grounded, rotating mandrel. Due to the unique properties of the CNTs, the hybrids show very high tensile strength, very small pore size, high specific surface area and electrical conductivity. In order to further examine the hybrid fabric properties, they were consolidated under pressure, and also calendered at 70 °C. After calendering, the fabric's strength increased by an order of magnitude due to increased interactions and intermingling with the CNTs. The hybrids are highly efficient as aerosol filters; consolidated hybrid fabrics with a thickness of 20 microns and areal density of only 8 g m(-2) exhibited ultra low particulate (ULPA) filter performance. The flexibility of this nanofabrication method allows for the use of many different polymer systems which provides the opportunity for engineering a wide range of nanoscale hybrid materials with desired functionalities.

  17. High Efficiency Polymer Solar Cells Technologies

    Institute of Scientific and Technical Information of China (English)

    Abdrhman M G; LI Hang-quan; ZHANG Li-ye; ZHOU Bing

    2006-01-01

    The conjugated polymer-based solar cell is one of the most promising devices in search of sustainable, renewable energy sources in last decade. It is the youngest field in organic solar cell research and also is certainly the fastest growing one at the moment. In addition, the key factor for polymer-based solar cells with high-efficiency is to invent new materials. Organic solar cell has attracted significant researches and commercial interest due to its low cost in fabrication and flexibility in applications. However, they suffer from relatively low conversion efficiency. The summarization of the significance and concept of high efficiency polymer solar cell technologies are presented.

  18. High-efficiency CARM

    Energy Technology Data Exchange (ETDEWEB)

    Bratman, V.L.; Kol`chugin, B.D.; Samsonov, S.V.; Volkov, A.B. [Institute of Applied Physics, Nizhny Novgorod (Russian Federation)

    1995-12-31

    The Cyclotron Autoresonance Maser (CARM) is a well-known variety of FEMs. Unlike the ubitron in which electrons move in a periodical undulator field, in the CARM the particles move along helical trajectories in a uniform magnetic field. Since it is much simpler to generate strong homogeneous magnetic fields than periodical ones for a relatively low electron energy ({Brit_pounds}{le}1-3 MeV) the period of particles` trajectories in the CARM can be sufficiently smaller than in the undulator in which, moreover, the field decreases rapidly in the transverse direction. In spite of this evident advantage, the number of papers on CARM is an order less than on ubitron, which is apparently caused by the low (not more than 10 %) CARM efficiency in experiments. At the same time, ubitrons operating in two rather complicated regimes-trapping and adiabatic deceleration of particles and combined undulator and reversed guiding fields - yielded efficiencies of 34 % and 27 %, respectively. The aim of this work is to demonstrate that high efficiency can be reached even for a simplest version of the CARM. In order to reduce sensitivity to an axial velocity spread of particles, a short interaction length where electrons underwent only 4-5 cyclotron oscillations was used in this work. Like experiments, a narrow anode outlet of a field-emission electron gun cut out the {open_quotes}most rectilinear{close_quotes} near-axis part of the electron beam. Additionally, magnetic field of a small correcting coil compensated spurious electron oscillations pumped by the anode aperture. A kicker in the form of a sloping to the axis frame with current provided a control value of rotary velocity at a small additional velocity spread. A simple cavity consisting of a cylindrical waveguide section restricted by a cut-off waveguide on the cathode side and by a Bragg reflector on the collector side was used as the CARM-oscillator microwave system.

  19. Fabrication and enhanced photoluminescence properties of NaLa(MoO$_4$)$_2$: Sm$^{3+}$, Bi$^{3+}$ phosphors with high efficiency white-light-emitting

    Indian Academy of Sciences (India)

    XINGSHUANG ZHANG; GUANGJUN ZHOU; JUAN ZHOU; PENG KONG; ZHICHAO YU; ZHICHAO YU; JIE ZHAN

    2017-09-01

    The tetragonal scheelite-type Sm$^{3+}$/Bi$^{3+}$ ions co-doped with NaLa(MoO$_4$)$_2$ phosphors were synthesized by a facile sol–gel and combustion process using citric acid as complexing agent. The crystal structure and morphology of theseas-prepared samples were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM). Furthermore,UV-absorption and the photoluminescence (PL) properties of these phosphors were systematically investigated and the PLof the phosphors shows strong white light emissions. Efficient energy transfer from the MoO$^{2-}_4$ group or Bi$^{3+}$ ions to Sm$^{3+}$ ions was established by PL investigation excited at 405 nm. The PL intensity of the studied materials was investigated asa function of different Sm$^{3+}$ and Bi$^{3+}$ concentrations. The PL investigations revealed that the phosphors exhibit apparentcharacteristic emissions, which is ascribed to the transition from the ground state energy level 4G5/2 to excited state energylevels ${}^6$H$_J$ ($J = 5/2$, 7/2, 9/2) and the NaLa(MoO$_4$)$_2$: 4 mol% Sm$^{3+}$ and NaLa(MoO$_4$)$_2$: 4 mol% Sm$^{3+}$, 8 mol% Bi$^{3+}$ present white emissions with the CIE coordinates of (0.350, 0.285) and (0.285, 0.229), respectively. The absolute quantum efficiencies of the phosphors are 40% (NaLa(MoO$_4$)$_2$: 4 mol% Sm$^{3+}$) and 52% (NaLa(MoO$_4$)$_2$: 4 mol% Sm$^{3+}$, 8 mol% Bi$^{3+}$), respectively.

  20. Fabrication and properties of high efficiency luminescent nanorods EuPO4·H2O by soft template method

    Institute of Scientific and Technical Information of China (English)

    Tran Thu Huong; Tran Kim Anh; Le Thi Vinh; W. Strek; Hoang Thi Khuyen; Le Quoc Minh

    2011-01-01

    Europium orthophosphate monohydrate (EuPO4.H2O) nanorods with typical dimensions of about 10-30 nm in diameter and 300-500 nm in length were prepared by using the soft template method.The effects of using diethylene glycol (DEG) and polyethylene glycol (PEG) polymers as well as the pH values on the size,crystalline structure and morphology of EuPO4·H2O nanorods were investigated.Field emission scanning electron microscopy (FESEM) and X-ray diffiaction (XRD) data of the prepared samples were elucidated.The nanorods were highly uniform and their mean length was reduced by using DEG and PEG as soft template agents.For all prepared samples,the rhabdophane-type hexagonal EuPO4·H2O was the dominated phase.The photoluminescence (PL) spectroscopy measurements of EuPO4·H2O nanorods revealed that,under UV excitation,EuPO4·H2O nanorods exhibited strong luminescence with narrow bands corresponding to the intra-4f transitions of 5D0→7Fj (j=1,2,3,4) of Eu3+ ions.The peaks were found at 594 nm (5D0→7F1),619 nm (5D0→7F2),652 nm (5D0→7F3),and 697 nm (5D0→7F4),with the strongest emission at 594 nm.

  1. Efficient fabrication of micro- and nano-systems

    DEFF Research Database (Denmark)

    Birkelund, Karen; Hanberg, Peter Jesper; Jørgensen, Anders Michael

    2014-01-01

    analyzing of e.g.waste water before it is lead out in our lakes and oceans or as sensors notifying when maintenance i srequired in due time before breakdown.More and more of these sensors are also made self-sufficient of power by harvesting the energy from e.g.the sun, thermal excess energy, environmental...... as minimizing the consumption of materials, etchants and process time. Danchip excels in optimizing micro- and nanofabrication in order to simplify processes, minimize cost and at the same time maximize yield. Danchips team of process generalists is ready to guide you through your design and planning phase...... as wellas to help you realizing your micro- and nano-devices in our clean room facilities. Danchips team of process specialists will help you with developing and optimizing new fabrication processes so you can reach your goals most efficiently. Our dedicated technical staff supports the infrastructure...

  2. High Efficiency Thermoelectric Materials and Devices

    Science.gov (United States)

    Kochergin, Vladimir (Inventor)

    2013-01-01

    Growth of thermoelectric materials in the form of quantum well super-lattices on three-dimensionally structured substrates provide the means to achieve high conversion efficiency of the thermoelectric module combined with inexpensiveness of fabrication and compatibility with large scale production. Thermoelectric devices utilizing thermoelectric materials in the form of quantum well semiconductor super-lattices grown on three-dimensionally structured substrates provide improved thermoelectric characteristics that can be used for power generation, cooling and other applications..

  3. Diffraction efficiency of plasmonic gratings fabricated by electron beam lithography using a silver halide film

    Science.gov (United States)

    Sudheer, Porwal, S.; Bhartiya, S.; Rao, B. T.; Tiwari, P.; Srivastava, Himanshu; Sharma, T. K.; Rai, V. N.; Srivastava, A. K.; Naik, P. A.

    2016-07-01

    The silver nanoparticle surface relief gratings of ˜10 μm period are fabricated using electron beam lithography on the silver halide film substrate. Morphological characterization of the gratings shows that the period, the shape, and the relief depth in the gratings are mainly dependent on the number of lines per frame, the spot size, and the accelerating voltage of electron beam raster in the SEM. Optical absorption of the silver nanoparticle gratings provides a broad localized surface plasmon resonance peak in the visible region, whereas the intensity of the peaks depends on the number density of silver nanoparticles in the gratings. The maximum efficiency of ˜7.2% for first order diffraction is observed for the grating fabricated at 15 keV. The efficiency is peaking at 560 nm with ˜380 nm bandwidth. The measured profiles of the diffraction efficiency for the gratings are found in close agreement with the Raman-Nath diffraction theory. This technique provides a simple and efficient method for the fabrication of plasmonic nanoparticle grating structures with high diffraction efficiency having broad wavelength tuning.

  4. Diffraction efficiency of plasmonic gratings fabricated by electron beam lithography using a silver halide film

    Energy Technology Data Exchange (ETDEWEB)

    Sudheer,, E-mail: sudheer@rrcat.gov.in, E-mail: sudheer.rrcat@gmail.com; Tiwari, P.; Srivastava, Himanshu; Rai, V. N.; Srivastava, A. K.; Naik, P. A. [Homi Bhabha National Institute, Mumbai, Maharashtra 400094 (India); Indus Synchrotrons Utilization Division, Raja Ramanna Centre for Advanced Technology, Indore, Madhya Pradesh 452013 (India); Porwal, S. [Solid State Lasers Division, Raja Ramanna Centre for Advanced Technology, Indore, Madhya Pradesh 452013 (India); Bhartiya, S. [Homi Bhabha National Institute, Mumbai, Maharashtra 400094 (India); Laser Materials Development and Device Division, Raja Ramanna Centre for Advanced Technology, Indore, Madhya Pradesh 452013 (India); Rao, B. T. [Homi Bhabha National Institute, Mumbai, Maharashtra 400094 (India); Laser Materials Processing Division, Raja Ramanna Centre for Advanced Technology, Indore, Madhya Pradesh 452013 (India); Sharma, T. K. [Homi Bhabha National Institute, Mumbai, Maharashtra 400094 (India); Solid State Lasers Division, Raja Ramanna Centre for Advanced Technology, Indore, Madhya Pradesh 452013 (India)

    2016-07-28

    The silver nanoparticle surface relief gratings of ∼10 μm period are fabricated using electron beam lithography on the silver halide film substrate. Morphological characterization of the gratings shows that the period, the shape, and the relief depth in the gratings are mainly dependent on the number of lines per frame, the spot size, and the accelerating voltage of electron beam raster in the SEM. Optical absorption of the silver nanoparticle gratings provides a broad localized surface plasmon resonance peak in the visible region, whereas the intensity of the peaks depends on the number density of silver nanoparticles in the gratings. The maximum efficiency of ∼7.2% for first order diffraction is observed for the grating fabricated at 15 keV. The efficiency is peaking at 560 nm with ∼380 nm bandwidth. The measured profiles of the diffraction efficiency for the gratings are found in close agreement with the Raman-Nath diffraction theory. This technique provides a simple and efficient method for the fabrication of plasmonic nanoparticle grating structures with high diffraction efficiency having broad wavelength tuning.

  5. Fabrication of high quality ferromagnetic Josephson junctions

    Energy Technology Data Exchange (ETDEWEB)

    Weides, M. [Institute for Solid State Research, Research Centre Juelich, D-52425 Juelich (Germany) and CNI-Center of Nanoelectronic Systems for Information Technology, Research Centre Juelich, D-52425 Juelich (Germany)]. E-mail: m.weides@fz-juelich.de; Tillmann, K. [Institute for Solid State Research, Research Centre Juelich, D-52425 Juelich (Germany); Ernst Ruska-Centre for Microscopy and Spectroscopy with Electrons, Research Centre Juelich, D-52425 Juelich (Germany); Kohlstedt, H. [Institute for Solid State Research, Research Centre Juelich, D-52425 Juelich (Germany); CNI-Center of Nanoelectronic Systems for Information Technology, Research Centre Juelich, D-52425 Juelich (Germany); Department of Material Science and Engineering and Department of Physics, University of Berkeley, CA 94720 (United States)

    2006-05-15

    We present ferromagnetic Nb/Al{sub 2}O{sub 3}/Ni{sub 60}Cu{sub 40}/Nb Josephson junctions (SIFS) with an ultrathin Al{sub 2}O{sub 3} tunnel barrier. The junction fabrication was optimized regarding junction insulation and homogeneity of current transport. Using ion-beam-etching and anodic oxidation we defined and insulated the junction mesas. The additional 2 nm thin Cu-layer below the ferromagnetic NiCu (SINFS) lowered interface roughness and ensured very homogeneous current transport. A high yield of junctional devices with j {sub c} spreads less than 2% was obtained.

  6. Fabrication of High Contrast Gratings for the Spectrum Splitting Dispersive Element in a Concentrated Photovoltaic System.

    Science.gov (United States)

    Yao, Yuhan; Liu, He; Wu, Wei

    2015-07-18

    High contrast gratings are designed and fabricated and its application is proposed in a parallel spectrum splitting dispersive element that can improve the solar conversion efficiency of a concentrated photovoltaic system. The proposed system will also lower the solar cell cost in the concentrated photovoltaic system by replacing the expensive tandem solar cells with the cost-effective single junction solar cells. The structures and the parameters of high contrast gratings for the dispersive elements were numerically optimized. The large-area fabrication of high contrast gratings was experimentally demonstrated using nanoimprint lithography and dry etching. The quality of grating material and the performance of the fabricated device were both experimentally characterized. By analyzing the measurement results, the possible side effects from the fabrication processes are discussed and several methods that have the potential to improve the fabrication processes are proposed, which can help to increase the optical efficiency of the fabricated devices.

  7. Mass-producible and efficient optical antennas with CMOS-fabricated nanometer-scale gap.

    Science.gov (United States)

    Seok, Tae Joon; Jamshidi, Arash; Eggleston, Michael; Wu, Ming C

    2013-07-15

    Optical antennas have been widely used for sensitive photodetection, efficient light emission, high resolution imaging, and biochemical sensing because of their ability to capture and focus light energy beyond the diffraction limit. However, widespread application of optical antennas has been limited due to lack of appropriate methods for uniform and large area fabrication of antennas as well as difficulty in achieving an efficient design with small mode volume (gap spacing antenna design, arch-dipole antenna, with optimal radiation efficiency and small mode volume, 5 nm gap spacing, fabricated by CMOS-compatible deep-UV spacer lithography. We demonstrate strong surface-enhanced Raman spectroscopy (SERS) signal with an enhancement factor exceeding 108 from the arch-dipole antenna array, which is two orders of magnitude stronger than that from the standard dipole antenna array fabricated by e-beam lithography. Since the antenna gap spacing, the critical dimension of the antenna, can be defined by deep-UV lithography, efficient optical antenna arrays with nanometer-scale gap can be mass-produced using current CMOS technology.

  8. High efficiency dielectric metasurfaces at visible wavelengths

    CERN Document Server

    Devlin, Robert C; Chen, Wei-Ting; Oh, Jaewon; Capasso, Federico

    2016-01-01

    Metasurfaces are planar optical elements that hold promise for overcoming the limitations of refractive and conventional diffractive optics1-3. Dielectric metasurfaces demonstrated thus far4-10 are limited to transparency windows at infrared wavelengths because of significant optical absorption and loss at visible wavelengths. It is critical that new materials and fabrication techniques be developed for dielectric metasurfaces at visible wavelengths to enable applications such as three-dimensional displays, wearable optics and planar optical systems11. Here, we demonstrate high performance titanium dioxide dielectric metasurfaces in the form of holograms for red, green and blue wavelengths with record absolute efficiency (>78%). We use atomic layer deposition of amorphous titanium dioxide that exhibits low surface roughness of 0.738 nm and ideal optical properties. To fabricate the metasurfaces we use a lift-off-like process that allows us to produce highly anisotropic nanofins with shape birefringence. This ...

  9. Partition efficiencies of newly fabricated universal high-speed counter-current chromatograph for separation of two different types of sugar derivatives with organic-aqueous two-phase solvent systems.

    Science.gov (United States)

    Shinomiya, Kazufusa; Sato, Kazuki; Yoshida, Kazunori; Tokura, Koji; Maruyama, Hiroshi; Yanagidaira, Kazuhiro; Ito, Yoichiro

    2013-12-27

    A new design of universal high-speed counter-current chromatograph (HSCCC) was fabricated in our laboratory. It holds a set of four column holders symmetrically around the rotary frame at a distance of 11.2cm from the central axis. By engaging the stationary gear on the central axis of the centrifuge to the planetary gears on the column holder shaft through a set of idle gears, two pairs of diagonally located column holders simultaneously rotate about their own axes in the opposite directions: one forward (type-J planetary motion) and the other backward (type-I planetary motion) each synchronously with the revolution. Using the eccentric coil assembly, partition efficiencies produced by these two planetary motions were compared on the separation of two different types of sugar derivatives (4-methylumbelliferyl and 5-bromo-4-chloro-3-indoxyl sugar derivatives) using organic-aqueous two-phase solvent systems composed of n-hexane/ethyl acetate/1-butanol/methanol/water and aqueous 0.1M sodium tetraborate, respectively. With lower phase mobile, better peak resolution was obtained by the type-J forward rotation for both samples probably due to higher retention of the stationary phase. With upper phase mobile, however, similar peak resolutions were obtained between these two planetary motions for both sugar derivatives. The overall results indicate that the present universal HSCCC is useful for counter-current chromatographic separation since each planetary motion has its specific applications: e.g., vortex CCC by the type-I planetary motion and HSCCC by the type-J planetary motion both for separation of various natural and synthetic products.

  10. High rate fabrication of compression molded components

    Energy Technology Data Exchange (ETDEWEB)

    Matsen, Marc R.; Negley, Mark A.; Dykstra, William C.; Smith, Glen L.; Miller, Robert J.

    2016-04-19

    A method for fabricating a thermoplastic composite component comprises inductively heating a thermoplastic pre-form with a first induction coil by inducing current to flow in susceptor wires disposed throughout the pre-form, inductively heating smart susceptors in a molding tool to a leveling temperature with a second induction coil by applying a high-strength magnetic field having a magnetic flux that passes through surfaces of the smart susceptors, shaping the magnetic flux that passes through surfaces of the smart susceptors to flow substantially parallel to a molding surface of the smart susceptors, placing the heated pre-form between the heated smart susceptors; and applying molding pressure to the pre-form to form the composite component.

  11. A biomimic thermal fabric with high moisture permeability

    Directory of Open Access Journals (Sweden)

    Fan Jie

    2013-01-01

    Full Text Available Moisture comfort is an essential factor for functional property of thermal cloth, especially for thick thermal cloth, since thick cloth may hinder effective moisture permeation, and high moisture concentration in the micro-climate between skin and fabric would cause cold feeling. Here, we report a biomimic thermal fabric with excellent warm retention and moisture management properties. In this fabric, the warp yarn system constructs many tree-shaped channel nets in the thickness direction of the fabric. Experimental result indicates that the special hierarchic configuration of warp yarns endows the biomimic thermal fabric with a better warm retention and water vapor management properties compared with the traditional fabrics.

  12. High efficiency interdigitated back contact silicon solar cells

    Science.gov (United States)

    Verlinden, P.; van de Wiele, F.; Stehelin, G.; Floret, F.; David, J. P.

    Interdigitated back contact (IBC) silicon solar cells with 25.6 percent efficiency at 10 W/sq cm and 24.4 percent at 30 W/ sq cm were fabricated. The authors report on the technological process, which produces a high effective carrier lifetime in the bulk (780 microsec), and on the characterization of the cells. The front side of these cells is textured and has an efficient polka-dot floating tandem junction. IBC and point-contact (PC) cells are fabricated on the same substrate and their efficiencies are compared. The possiblity of reaching 29 percent efficiency at 300X is shown.

  13. Towards highly efficient water photoelectrolysis

    Science.gov (United States)

    Elavambedu Prakasam, Haripriya

    ethylene glycol resulted in remarkable growth characteristics of titania nanotube arrays, hexagonal closed packed up to 1 mm in length, with tube aspect ratios of approximately 10,000. For the first time, complete anodization of the starting titanium foil has been demonstrated resulting in back to back nanotube array membranes ranging from 360 mum--1 mm in length. The nanotubes exhibited growth rates of up to 15 mum/hr. A detailed study on the factors affecting the growth rate and nanotube dimensions is presented. It is suggested that faster high field ionic conduction through a thinner barrier layer is responsible for the higher growth rates observed in electrolytes containing ethylene glycol. Methods to fabricate free standing, titania nanotube array membranes ranging in thickness from 50 microm--1000 mum has also been an outcome of this dissertation. In an effort to combine the charge transport properties of titania with the light absorption properties of iron (III) oxide, films comprised of vertically oriented Ti-Fe-O nanotube arrays on FTO coated glass substrates have been successfully synthesized in ethylene glycol electrolytes. Depending upon the Fe content the bandgap of the resulting films varied from about 3.26 to 2.17 eV. The Ti-Fe oxide nanotube array films demonstrated a photocurrent of 2 mA/cm2 under global AM 1.5 illumination with a 1.2% (two-electrode) photoconversion efficiency, demonstrating a sustained, time-energy normalized hydrogen evolution rate by water splitting of 7.1 mL/W·hr in a 1 M KOH solution with a platinum counter electrode under an applied bias of 0.7 V. The Ti-Fe-O material architecture demonstrates properties useful for hydrogen generation by water photoelectrolysis and, more importantly, this dissertation demonstrates that the general nanotube-array synthesis technique can be extended to other ternary oxide compositions of interest for water photoelectrolysis.

  14. Methodologies for high efficiency perovskite solar cells.

    Science.gov (United States)

    Park, Nam-Gyu

    2016-01-01

    Since the report on long-term durable solid-state perovskite solar cell in 2012, perovskite solar cells based on lead halide perovskites having organic cations such as methylammonium CH3NH3PbI3 or formamidinium HC(NH2)2PbI3 have received great attention because of superb photovoltaic performance with power conversion efficiency exceeding 22 %. In this review, emergence of perovskite solar cell is briefly introduced. Since understanding fundamentals of light absorbers is directly related to their photovoltaic performance, opto-electronic properties of organo lead halide perovskites are investigated in order to provide insight into design of higher efficiency perovskite solar cells. Since the conversion efficiency of perovskite solar cell is found to depend significantly on perovskite film quality, methodologies for fabricating high quality perovskite films are particularly emphasized, including various solution-processes and vacuum deposition method.

  15. Methodologies for high efficiency perovskite solar cells

    Science.gov (United States)

    Park, Nam-Gyu

    2016-06-01

    Since the report on long-term durable solid-state perovskite solar cell in 2012, perovskite solar cells based on lead halide perovskites having organic cations such as methylammonium CH3NH3PbI3 or formamidinium HC(NH2)2PbI3 have received great attention because of superb photovoltaic performance with power conversion efficiency exceeding 22 %. In this review, emergence of perovskite solar cell is briefly introduced. Since understanding fundamentals of light absorbers is directly related to their photovoltaic performance, opto-electronic properties of organo lead halide perovskites are investigated in order to provide insight into design of higher efficiency perovskite solar cells. Since the conversion efficiency of perovskite solar cell is found to depend significantly on perovskite film quality, methodologies for fabricating high quality perovskite films are particularly emphasized, including various solution-processes and vacuum deposition method.

  16. Optimizing SOI Slot Waveguide Fabrication Tolerances and Strip-Slot Coupling for Very Efficient Optical Sensing

    Directory of Open Access Journals (Sweden)

    Vittorio M. N. Passaro

    2012-02-01

    Full Text Available Slot waveguides are becoming more and more attractive optical components, especially for chemical and bio-chemical sensing. In this paper an accurate analysis of slot waveguide fabrication tolerances is carried out, in order to find optimum design criteria for either homogeneous or absorption sensing mechanisms, in cases of low and high aspect ratio slot waveguides. In particular, we have focused on Silicon On Insulator (SOI technology, representing the most popular technology for this kind of devices, simultaneously achieving high integration capabilities, small dimensions and low cost. An accurate analysis of single mode behavior for high aspect ratio slot waveguide has been also performed, in order to provide geometric limits for waveguide design purposes. Finally, the problem of coupling into a slot waveguide is addressed and a very compact and efficient slot coupler is proposed, whose geometry has been optimized to give a strip-slot-strip coupling efficiency close to 100%.

  17. Highly efficient tandem polymer solar cells with a photovoltaic response in the visible light range.

    Science.gov (United States)

    Zheng, Zhong; Zhang, Shaoqing; Zhang, Maojie; Zhao, Kang; Ye, Long; Chen, Yu; Yang, Bei; Hou, Jianhui

    2015-02-18

    Highly efficient polymer solar cells with a tandem structure are fabricated by using two excellent photovoltaic polymers and a highly transparent intermediate recombination layer. Power conversion -efficiencies over 10% can be realized with a photovoltaic response within 800 nm.

  18. One-Step Printable Perovskite Films Fabricated under Ambient Conditions for Efficient and Reproducible Solar Cells.

    Science.gov (United States)

    Jung, Yen-Sook; Hwang, Kyeongil; Heo, Youn-Jung; Kim, Jueng-Eun; Lee, Donmin; Lee, Cheol-Ho; Joh, Han-Ik; Yeo, Jun-Seok; Kim, Dong-Yu

    2017-08-23

    Despite the potential of roll-to-roll processing for the fabrication of perovskite films, the realization of highly efficient and reproducible perovskite solar cells (PeSCs) through continuous coating techniques and low-temperature processing is still challenging. Here, we demonstrate that efficient and reliable CH3NH3PbI3 (MAPbI3) films fabricated by a printing process can be achieved through synergetic effects of binary processing additives, N-cyclohexyl-2-pyrrolidone (CHP) and dimethyl sulfoxide (DMSO). Notably, these perovskite films are deposited from premixed perovskite solutions for facile one-step processing under a room-temperature and ambient atmosphere. The CHP molecules result in the uniform and homogeneous perovskite films even in the one-step slot-die system, which originate from the high boiling point and low vapor pressure of CHP. Meanwhile, the DMSO molecules facilitate the growth of perovskite grains by forming intermediate states with the perovskite precursor molecules. Consequently, fully printed PeSC based on the binary additive system exhibits a high PCE of 12.56% with a high reproducibility.

  19. High Efficiency Engine Technologies Program

    Energy Technology Data Exchange (ETDEWEB)

    Rich Kruiswyk

    2010-07-13

    Caterpillar's Product Development and Global Technology Division carried out a research program on waste heat recovery with support from DOE (Department of Energy) and the DOE National Energy Technology Laboratory. The objective of the program was to develop a new air management and exhaust energy recovery system that would demonstrate a minimum 10% improvement in thermal efficiency over a base heavy-duty on-highway diesel truck engine. The base engine for this program was a 2007 C15 15.2L series-turbocharged on-highway truck engine with a LPL (low-pressure loop) exhaust recirculation system. The focus of the program was on the development of high efficiency turbomachinery and a high efficiency turbocompound waste heat recovery system. The focus of each area of development was as follows: (1) For turbine stages, the focus was on investigation and development of technologies that would improve on-engine exhaust energy utilization compared to the conventional radial turbines in widespread use today. (2) For compressor stages, the focus was on investigating compressor wheel design parameters beyond the range typically utilized in production, to determine the potential efficiency benefits thereof. (3) For turbocompound, the focus was on the development of a robust bearing system that would provide higher bearing efficiencies compared to systems used in turbocompound power turbines in production. None of the turbocharger technologies investigated involved addition of moving parts, actuators, or exotic materials, thereby increasing the likelihood of a favorable cost-value tradeoff for each technology. And the turbocompound system requires less hardware addition than competing bottoming cycle technologies, making it a more attractive solution from a cost and packaging standpoint. Main outcomes of the program are as follows: (1) Two turbine technologies that demonstrated up to 6% improvement in turbine efficiency on gas stand and 1-3% improvement in thermal efficiency

  20. High Efficiency Engine Technologies Program

    Energy Technology Data Exchange (ETDEWEB)

    Rich Kruiswyk

    2010-07-13

    Caterpillar's Product Development and Global Technology Division carried out a research program on waste heat recovery with support from DOE (Department of Energy) and the DOE National Energy Technology Laboratory. The objective of the program was to develop a new air management and exhaust energy recovery system that would demonstrate a minimum 10% improvement in thermal efficiency over a base heavy-duty on-highway diesel truck engine. The base engine for this program was a 2007 C15 15.2L series-turbocharged on-highway truck engine with a LPL (low-pressure loop) exhaust recirculation system. The focus of the program was on the development of high efficiency turbomachinery and a high efficiency turbocompound waste heat recovery system. The focus of each area of development was as follows: (1) For turbine stages, the focus was on investigation and development of technologies that would improve on-engine exhaust energy utilization compared to the conventional radial turbines in widespread use today. (2) For compressor stages, the focus was on investigating compressor wheel design parameters beyond the range typically utilized in production, to determine the potential efficiency benefits thereof. (3) For turbocompound, the focus was on the development of a robust bearing system that would provide higher bearing efficiencies compared to systems used in turbocompound power turbines in production. None of the turbocharger technologies investigated involved addition of moving parts, actuators, or exotic materials, thereby increasing the likelihood of a favorable cost-value tradeoff for each technology. And the turbocompound system requires less hardware addition than competing bottoming cycle technologies, making it a more attractive solution from a cost and packaging standpoint. Main outcomes of the program are as follows: (1) Two turbine technologies that demonstrated up to 6% improvement in turbine efficiency on gas stand and 1-3% improvement in thermal efficiency

  1. New Fabrication Method Improves the Efficiency and Economics of Solar Cells (Fact Sheet)

    Energy Technology Data Exchange (ETDEWEB)

    2012-07-01

    Synthetic fabrication strategy optimizes the illumination geometry and transport properties of dye-sensitized solar cells. Using oriented titanium oxide (TiO{sub 2}) nanotube (NT) arrays has shown promise for dye-sensitized solar cells (DSSCs). High solar conversion efficiency requires that the incident light enters the cell from the photoelectrode side. However, for NT-based DSSCs, the light normally enters the cell through the counter electrode because a nontransparent titanium foil is typically used as the substrate for forming the aligned NTs and for making electrical contact with them. It has been synthetically challenging to prepare transparent TiO{sub 2} NT electrodes by directly anodizing Ti metal films on transparent conducting oxide (TCO) substrates because it is difficult to control the synthetic conditions. National Renewable Energy Laboratory (NREL) researchers have developed a general synthetic strategy for fabricating transparent TiO{sub 2} NT films on TCO substrates. With the aid of a conducting Nb-doped TiO{sub 2} (NTO) layer between the Ti film and TCO substrate, the Ti film can be anodized completely without degrading the TCO. The NTO layer protects the TCO from degradation through a self-terminating mechanism by arresting the electric field-assisted dissolution process at the NT-NTO interface. NREL researchers found that the illumination direction and wavelength of the light incident on the DSSCs strongly influenced the incident photon-to-current conversion efficiency, light-harvesting, and charge-collection properties, which, in turn, affect the photocurrent density, photovoltage, and solar energy conversion efficiency. Researchers also examined the effects of NT film thickness on the properties and performance of DSSCs and found that illuminating the cell from the photoelectrode side substantially increased the conversion efficiency compared with illuminating it from the counter-electrode side. This method solves a key challenge in fabricating

  2. Unconventional, High-Efficiency Propulsors

    DEFF Research Database (Denmark)

    Andersen, Poul

    1996-01-01

    The development of ship propellers has generally been characterized by search for propellers with as high efficiency as possible and at the same time low noise and vibration levels and little or no cavitation. This search has lead to unconventional propulsors, like vane-wheel propulsors, contra-r...

  3. High Efficiency Pb-In Binary Metal Perovskite Solar Cells.

    Science.gov (United States)

    Wang, Zhao-Kui; Li, Meng; Yang, Ying-Guo; Hu, Yun; Ma, Heng; Gao, Xing-Yu; Liao, Liang-Sheng

    2016-08-01

    Mixed Pb-In perovskite solar cells are fabricated by using lead(II) chloride and indium(III) chloride with methylammonium iodide. A maximum power conversion efficiency as high as 17.55% is achieved owing to the high quality of perovskites with multiple ordered crystal orientations. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  4. Highly Efficient L-Band Fibre -DFB Lasers

    Institute of Scientific and Technical Information of China (English)

    Libin Fu; Morten Ibsen; David J. Richardson; David N. Payne

    2003-01-01

    A more than 12 mW highly efficient fibre-DFB laser operating at 1618.3 nm is fabricated and characterised. Its high-power, low-noise and single-polarisation characteristics make it very suitable WDM-source for L-band transmission.

  5. Efficient Fabrication of Hierarchically Porous Graphene-Derived Aerogel and Its Application in Lithium Sulfur Battery.

    Science.gov (United States)

    Zhang, Kai; Qin, Furong; Lai, Yanqing; Li, Jie; Lei, Xiaoke; Wang, Mengran; Lu, Hai; Fang, Jing

    2016-03-09

    Hierarchically porous carbon/graphene aerogel (CGA) with relatively high surface area and pore volume is synthesized through an efficient fabrication strategy, which involves forming hydrothermal carbon layer on the pore wall as upholder and directly carbonizing the wet hydrogel from hydrothermal reaction, without using any special drying techniques. Cassava powder is used as carbon precursor which enables sustainable synthesis. Carbonizing the wet hydrothermal product is found to be a self-activation process, through which abundant pores are generated. The aerogel is used as host to encapsulate sulfur for lithium sulfur battery. Graphene, served as highly conductive scaffold, accelerates the transport of the electrons. The hierarchically porous structure is in favor of improving the electrochemical performance of lithium sulfur battery. Therefore, the cathode with high sulfur loading and high sulfur content can deliver very good performance.

  6. Delta-Doping at Wafer Level for High Throughput, High Yield Fabrication of Silicon Imaging Arrays

    Science.gov (United States)

    Hoenk, Michael E. (Inventor); Nikzad, Shoulch (Inventor); Jones, Todd J. (Inventor); Greer, Frank (Inventor); Carver, Alexander G. (Inventor)

    2014-01-01

    Systems and methods for producing high quantum efficiency silicon devices. A silicon MBE has a preparation chamber that provides for cleaning silicon surfaces using an oxygen plasma to remove impurities and a gaseous (dry) NH3 + NF3 room temperature oxide removal process that leaves the silicon surface hydrogen terminated. Silicon wafers up to 8 inches in diameter have devices that can be fabricated using the cleaning procedures and MBE processing, including delta doping.

  7. 14. 5% conversion efficiency GaAs solar cell fabricated on Si substrates

    Energy Technology Data Exchange (ETDEWEB)

    Itoh, Y.; Nishioka, T.; Yamamoto, A.; Yamaguchi, M.

    1986-12-08

    AlGaAs-GaAs heteroface p/sup +/-p-n solar cells have been fabricated directly on Si substrates using metalorganic chemical vapor deposition. GaAs on Si solar cell efficiency as high as exceeding 14.5% at AM1.5 was obtained by cleaning the substrate surface and repeating GaAs film growth interruption. This value is the highest ever reported for GaAs solar cells on Si substrates. Defects, which could not be observed in homoepitaxially grown GaAs film, were observed in the heteroepitaxial GaAs films through electron beam induced current image. Relatively low conversion efficiency of the GaAs cell on Si compared to the GaAs can be attributed to these defects.

  8. Biomimic design of multi-scale fabric with efficient heat transfer property

    Directory of Open Access Journals (Sweden)

    Fan Jie

    2012-01-01

    Full Text Available Wool fiber has a complex hierarchic structure. The multi-scale fibrils are assembled to form a tree-like channel net in wool fiber, providing an efficient heat transfer property. The optimal inner configuration of wool fiber can also be invited to biomimic design of textile fabrics to improve the thermal comfort of cloth. A heat transfer model of biomimic multi-scale fabric using the fractal derivative is established. Theoretical analysis indicates that the heat flux efficiency in the biomimic fabric can be 2 orders of magnitude comparing with that of the continuous medium.

  9. Highly Efficient InGaN-Based Solar Cells for High Intensity and High Temperature Operation Project

    Data.gov (United States)

    National Aeronautics and Space Administration — In this SBIR Phase I program, we propose to fabricate high-efficiency and radiation hard solar cells based on InGaN material system that can cover the whole solar...

  10. Investigation on high transmission efficiency 7 × 1 pump combiner

    Science.gov (United States)

    Cao, Yang; Shi, Wei; Sheng, Quan; Fu, Shijie; Zhang, Haiwei; Bai, Xiaolei; Qi, Liang; Yao, Jianquan

    2016-12-01

    The 7×1 end-pumped combiner employing 105/125 μm multimode fibers as pump fibers is investigated. The theoretical analysis reveals that sufficient taper length and low refractive index of the capillary should be adopted to fabricate high transmission efficiency combiners. Based on the simulation results, we fabricate a 7×1 end-pumped pump combiner with an average transmission efficiency of 98.9% and a total return loss of 1.1‰. The measured internal operating temperature of this combiner indicates it can endure pump power of the order of kilowatts.

  11. High performance broadband photodetector using fabricated nanowires of bismuth selenide.

    Science.gov (United States)

    Sharma, Alka; Bhattacharyya, Biplab; Srivastava, A K; Senguttuvan, T D; Husale, Sudhir

    2016-01-11

    Recently, very exciting optoelectronic properties of Topological insulators (TIs) such as strong light absorption, photocurrent sensitivity to the polarization of light, layer thickness and size dependent band gap tuning have been demonstrated experimentally. Strong interaction of light with TIs has been shown theoretically along with a proposal for a TIs based broad spectral photodetector having potential to perform at the same level as that of a graphene based photodetector. Here we demonstrate that focused ion beam (FIB) fabricated nanowires of TIs could be used as ultrasensitive visible-NIR nanowire photodetector based on TIs. We have observed efficient electron hole pair generation in the studied Bi2Se3 nanowire under the illumination of visible (532 nm) and IR light (1064 nm). The observed photo-responsivity of ~300 A/W is four orders of magnitude larger than the earlier reported results on this material. Even though the role of 2D surface states responsible for high reponsivity is unclear, the novel and simple micromechanical cleavage (exfoliation) technique for the deposition of Bi2Se3 flakes followed by nanowire fabrication using FIB milling enables the construction and designing of ultrasensitive broad spectral TIs based nanowire photodetector which can be exploited further as a promising material for optoelectronic devices.

  12. High performance broadband photodetector using fabricated nanowires of bismuth selenide

    Science.gov (United States)

    Sharma, Alka; Bhattacharyya, Biplab; Srivastava, A. K.; Senguttuvan, T. D.; Husale, Sudhir

    2016-01-01

    Recently, very exciting optoelectronic properties of Topological insulators (TIs) such as strong light absorption, photocurrent sensitivity to the polarization of light, layer thickness and size dependent band gap tuning have been demonstrated experimentally. Strong interaction of light with TIs has been shown theoretically along with a proposal for a TIs based broad spectral photodetector having potential to perform at the same level as that of a graphene based photodetector. Here we demonstrate that focused ion beam (FIB) fabricated nanowires of TIs could be used as ultrasensitive visible-NIR nanowire photodetector based on TIs. We have observed efficient electron hole pair generation in the studied Bi2Se3 nanowire under the illumination of visible (532 nm) and IR light (1064 nm). The observed photo-responsivity of ~300 A/W is four orders of magnitude larger than the earlier reported results on this material. Even though the role of 2D surface states responsible for high reponsivity is unclear, the novel and simple micromechanical cleavage (exfoliation) technique for the deposition of Bi2Se3 flakes followed by nanowire fabrication using FIB milling enables the construction and designing of ultrasensitive broad spectral TIs based nanowire photodetector which can be exploited further as a promising material for optoelectronic devices.

  13. High Efficiency Room Air Conditioner

    Energy Technology Data Exchange (ETDEWEB)

    Bansal, Pradeep [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

    2015-01-01

    This project was undertaken as a CRADA project between UT-Battelle and Geberal Electric Company and was funded by Department of Energy to design and develop of a high efficiency room air conditioner. A number of novel elements were investigated to improve the energy efficiency of a state-of-the-art WAC with base capacity of 10,000 BTU/h. One of the major modifications was made by downgrading its capacity from 10,000 BTU/hr to 8,000 BTU/hr by replacing the original compressor with a lower capacity (8,000 BTU/hr) but high efficiency compressor having an EER of 9.7 as compared with 9.3 of the original compressor. However, all heat exchangers from the original unit were retained to provide higher EER. The other subsequent major modifications included- (i) the AC fan motor was replaced by a brushless high efficiency ECM motor along with its fan housing, (ii) the capillary tube was replaced with a needle valve to better control the refrigerant flow and refrigerant set points, and (iii) the unit was tested with a drop-in environmentally friendly binary mixture of R32 (90% molar concentration)/R125 (10% molar concentration). The WAC was tested in the environmental chambers at ORNL as per the design rating conditions of AHAM/ASHRAE (Outdoor- 95F and 40%RH, Indoor- 80F, 51.5%RH). All these modifications resulted in enhancing the EER of the WAC by up to 25%.

  14. Shockwave Fabrication of High Performance Thermoelectrics Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Thermoelectric (TE) generators have the advantages of no moving parts and flexibility in deployment but suffer from low heat to electricity conversion efficiencies,...

  15. Automated Fabrication Technologies for High Performance Polymer Composites

    Science.gov (United States)

    Shuart , M. J.; Johnston, N. J.; Dexter, H. B.; Marchello, J. M.; Grenoble, R. W.

    1998-01-01

    New fabrication technologies are being exploited for building high graphite-fiber-reinforced composite structure. Stitched fiber preforms and resin film infusion have been successfully demonstrated for large, composite wing structures. Other automatic processes being developed include automated placement of tacky, drapable epoxy towpreg, automated heated head placement of consolidated ribbon/tape, and vacuum-assisted resin transfer molding. These methods have the potential to yield low cost high performance structures by fabricating composite structures to net shape out-of-autoclave.

  16. A gyroscope fabrication method for high sensitivity and robustness to fabrication tolerances

    Science.gov (United States)

    Sung, Jungwoo; Kim, Jin Young; Seok, Seyeong; Kwon, Hyuckjin J.; Kim, Minseo; Kim, Geonhwee; Lim, Geunbae

    2014-07-01

    MEMS gyroscopes have favorable characteristics, including small size, high throughput, and low cost. The performance of MEMS gyroscopes depends on the displacement sensitivity of the capacitors. In this paper, we describe the fabrication of 300-µm-thick gyroscopes that can provide high displacement sensitivity and are robust to fabrication tolerances, i.e. deep reactive ion etch (DRIE) rate uniformity. When thick structures are perforated using DRIE to achieve high-aspect-ratio features, footing is commonly observed. However, we describe a fabrication method that circumvents problems associated with footing and side-wall etching, so that the gyroscopes can have uniform dimensions and small variations across the wafer. Using a post-fabrication translation approach, the position of capacitors is modified following DRIE, and the gap in the gyroscopes can be reduced to 3 μm, which leads to an aspect ratio of 100. Using this method, we fabricated MEMS gyroscopes that can overcome the DRIE aspect ratio limit and have capacitors with higher sensitivities than those of other gyroscopes, which typically employ substrates that are less than 100 µm thick. The gyroscope had a resonant frequency of 9.91 kHz, a quality factor of 2500 and a sensitivity of 23 mV/[deg/s].

  17. One-pot hydrothermal route to fabricate nitrogen doped graphene/Ag-TiO2: Efficient charge separation, and high-performance "on-off-on" switch system based photoelectrochemical biosensing.

    Science.gov (United States)

    Jiang, Ding; Du, Xiaojiao; Chen, Danyang; Zhou, Lei; Chen, Wei; Li, Yaqi; Hao, Nan; Qian, Jing; Liu, Qian; Wang, Kun

    2016-09-15

    Charge separation is crucial for increasing the performances of semiconductor-based materials in many photoactive applications. In this paper, we designed novel nanocomposites consisting of TiO2 nanocrystals, Ag nanoparticles (NPs) and nitrogen doped graphene (NGR) via a facile one-pot hydrothermal route. The as-prepared ternary nanocomposites exhibited enhanced photoelectrochemical (PEC) performances owing to the introduction of Ag NPs and NGR, which increase the excitons' lifetime and improve the charge transfer. In particular, it is shown by means of the transient-state surface photocurrent responses that the photocurrent intensity of the as-fabricated composites exhibited 18.2 times higher than that of pristine TiO2. Based on the robust photocurrent signal, a new kind of "on-off-on" PEC aptasensor was established with the assistance of Pb(2+) aptamer, which integrates the advantages of low background signal and high sensitivity. Under optimal conditions, a wide linear response for Pb(2+) detection was obtained from 1pM to 5nM as well as a detection limit down to 0.3pM. With its simplicity, selectivity, and sensitivity, this proposed strategy shows great promise for Pb(2+) detection in food and environment analysis.

  18. Efficient Welding Fabrication of Extruded Aluminum Mat Panels

    Science.gov (United States)

    1991-09-01

    aged to produce the needle structure. This is confirmed by Enjo (Ref. 41) for 6063 - T5 alloy. However, as was shown by Dumolt (Ref. 38), increase in...According to Ref. 1, extrudability of 6061 alloy is rated as 60% of that of the standard 6063 alloy. The various combinations of properties and economics of...extrudability 2-17 TABLE 2-1. ExtrudabUilty of AI-Mg-SI Alloys A.A. Designation Grading Characteristics 6063 Low Strength Good finish, high extrusion

  19. Controlled fabrication of photoactive copper oxide-cobalt oxide nanowire heterostructures for efficient phenol photodegradation.

    Science.gov (United States)

    Shi, Wenwu; Chopra, Nitin

    2012-10-24

    Fabrication of oxide nanowire heterostructures with controlled morphology, interface, and phase purity is critical for high-efficiency and low-cost photocatalysis. Here, we have studied the formation of copper oxide-cobalt nanowire heterostructures by sputtering and subsequent air annealing to result in cobalt oxide (Co(3)O(4))-coated CuO nanowires. This approach allowed fabrication of standing nanowire heterostructures with tunable compositions and morphologies. The vertically standing CuO nanowires were synthesized in a thermal growth method. The shell growth kinetics of Co and Co(3)O(4) on CuO nanowires, morphological evolution of the shell, and nanowire self-shadowing effects were found to be strongly dependent on sputtering duration, air-annealing conditions, and alignment of CuO nanowires. Finite element method (FEM) analysis indicated that alignment and stiffness of CuO-Co nanowire heterostructures greatly influenced the nanomechanical aspects such as von Mises equivalent stress distribution and bending of nanowire heterostructures during the Co deposition process. This fundamental knowledge was critical for the morphological control of Co and Co(3)O(4) on CuO nanowires with desired interfaces and a uniform coating. Band gap energies and phenol photodegradation capability of CuO-Co(3)O(4) nanowire heterostructures were studied as a function of Co(3)O(4) morphology. Multiple absorption edges and band gap tailings were observed for these heterostructures, indicating photoactivity from visible to UV range. A polycrystalline Co(3)O(4) shell on CuO nanowires showed the best photodegradation performance (efficiency ~50-90%) in a low-powered UV or visible light illumination with a sacrificial agent (H(2)O(2)). An anomalously high efficiency (~67.5%) observed under visible light without sacrificial agent for CuO nanowires coated with thin (∼5.6 nm) Co(3)O(4) shell and nanoparticles was especially interesting. Such photoactive heterostructures demonstrate unique

  20. Investigation of non-halogenated solvent mixtures for high throughput fabrication of polymerfullerene solar cells

    NARCIS (Netherlands)

    Schmidt-Hansberg, B.; Sanyal, M.; Grossiord, N.; Galagan, Y.O.; Baunach, M.; Klein, M.F.G.; Colsmann, A.; Scharfer, P.; Lemmer, U.; Dosch, H.; Michels, J.J; Barrena, E.; Schabel, W.

    2012-01-01

    The rapidly increasing power conversion efficiencies of organic solar cells are an important prerequisite towards low cost photovoltaic fabricated in high throughput. In this work we suggest indane as a non-halogenated replacement for the commonly used halogenated solvent o-dichlorobenzene. Indane w

  1. Investigation of non-halogenated solvent mixtures for high throughput fabrication of polymerfullerene solar cells

    NARCIS (Netherlands)

    Schmidt-Hansberg, B.; Sanyal, M.; Grossiord, N.; Galagan, Y.O.; Baunach, M.; Klein, M.F.G.; Colsmann, A.; Scharfer, P.; Lemmer, U.; Dosch, H.; Michels, J.J; Barrena, E.; Schabel, W.

    2012-01-01

    The rapidly increasing power conversion efficiencies of organic solar cells are an important prerequisite towards low cost photovoltaic fabricated in high throughput. In this work we suggest indane as a non-halogenated replacement for the commonly used halogenated solvent o-dichlorobenzene. Indane w

  2. High Tc superconducting fabrication of loop antenna

    Directory of Open Access Journals (Sweden)

    Widad Mahmood Faisal

    2012-09-01

    Full Text Available Using a solid state reaction to prepared many samples of YBa2Cu3O7−δ And (YBa2Cu3O7−δ1−x(Ag2Ox by mixing the appropriate ratios of constituent oxides; BaO, CuO, and Y2O3 the mixture were ground to fine power and then calcined at 900 °C without Ag2O and 930 °C for using Ag2O as impurities. The calcined black power were grounded again and molded into pellets by applying a hydrostatic pressure from (0.3–0.6 Gpa. These pellets were sintered at 950 °C. Silver was added as impurities with the calcined powder with ratios of 0.3, 0.35 and 0.45 to increase its ductility. The transition temperature for the superconductor samples were done using non-contact technique. It is an easy and sensitive technique compared with four – point probe method. The maximum Tc was 110 K for YBa2Cu3O6.989. Evaporation deposition technique to deposited a thin film, of 2200 A° thickness on the surface of the samples and then annealed to room temperature. This technical reduces the resistance to 0.2 Ω and makes a good ohmic contact at liquid nitrogen boiling point (77 K metals of various conductivity such as copper, brass aluminum and iron were used to study the effect of eddy-current loss on them and then compared with the superconducting samples, with Ag2O or without Ag2O. The maximum power loss were obtained for the superconducting samples when they cooling at liquid nitrogen temperature. The sintered pellets were drilled manually by 6 mm drill and a slot was done along its radius, to fabricate a superconducting loop antenna for receiving magnetic field signal. The best received signal was obtained when the antenna cooled to liquid nitrogen temperature.

  3. High efficiency shale oil recovery

    Energy Technology Data Exchange (ETDEWEB)

    Adams, D.C.

    1993-04-22

    The overall project objective is to demonstrate the high efficiency of the Adams Counter-Current shale oil recovery process. The efficiency will first be demonstrated on a small scale, in the current phase, after which the demonstration will be extended to the operation of a small pilot plant. Thus the immediate project objective is to obtain data on oil shale retorting operations in a small batch rotary kiln that will be representative of operations in the proposed continuous process pilot plant. Although an oil shale batch sample is sealed in the batch kiln from the start until the end of the run, the process conditions for the batch are the same as the conditions that an element of oil shale would encounter in a continuous process kiln. Similar chemical and physical conditions (heating, mixing, pyrolysis, oxidation) exist in both systems.The two most important data objectives in this phase of the project are to demonstrate (1) that the heat recovery projected for this project is reasonable and (2) that an oil shale kiln will run well and not plug up due to sticking and agglomeration. The following was completed this quarter. (1) Twelve pyrolysis runs were made on five different oil shales. All of the runs exhibited a complete absence of any plugging, tendency. Heat transfer for Green River oil shale in the rotary kiln was 84.6 Btu/hr/ft[sup 2]/[degrees]F, and this will provide for ample heat exchange in the Adams kiln. (2) One retorted residue sample was oxidized at 1000[degrees]F. Preliminary indications are that the ash of this run appears to have been completely oxidized. (3) Further minor equipment repairs and improvements were required during the course of the several runs.

  4. Basic studies of 3-5 high efficiency cell components

    Energy Technology Data Exchange (ETDEWEB)

    Lundstrom, M.S.; Melloch, M.R.; Pierret, R.F.; Carpenter, M.S.; Chuang, H.L.; Dodd, P.E.; Keshavarzi, A.; Klausmeier-Brown, M.E.; Lush, G.B.; Stellwag, T.B. (Purdue Univ., Lafayette, IN (United States))

    1993-01-01

    This project's objective is to improve our understanding of the generation, recombination, and transport of carriers within III-V homo- and heterostructures. The research itself consists of fabricating and characterizing solar cell building blocks'' such as junctions and heterojunctions as well as basic measurements of material parameters. A significant effort is also being directed at characterizing loss mechanisms in high-quality, III-V solar cells fabricated in industrial research laboratories throughout the United States. The project's goal is to use our understanding of the device physics of high-efficiency cell components to maximize cell efficiency. A related goal is the demonstration of new cell structures fabricated by molecular beam epitaxy (MBE). The development of measurement techniques and characterization methodologies is also a project objective. This report describes our progress during the fifth and final year of the project. During the past five years, we've teamed a great deal about heavy doping effects in p[sup +] and n[sup +] GaAs and have explored their implications for solar cells. We have developed an understanding of the dominant recombination losses in present-day, high-efficiency cells. We've learned to appreciated the importance of recombination at the perimeter of the cell and have developed techniques for chemically passivating such edges. Finally, we've demonstrated that films grown by molecular beam epitaxy are suitable for high-efficiency cell research.

  5. High density semiconductor nanodots by direct laser fabrication

    Science.gov (United States)

    Haghizadeh, Anahita; Yang, Haeyeon

    2016-03-01

    We report a direct method of fabricating high density nanodots on the GaAs(001) surfaces using laser irradiations on the surface. Surface images indicate that the large clumps are not accompanied with the formation of nanodots even though its density is higher than the critical density above which detrimental large clumps begin to show up in the conventional Stranski-Krastanov growth technique. Atomic force microscopy is used to image the GaAs(001) surfaces that are irradiated by high power laser pulses interferentially. The analysis suggests that high density quantum dots be fabricated directly on semiconductor surfaces.

  6. Method of high-density foil fabrication

    Energy Technology Data Exchange (ETDEWEB)

    Blue, Craig A.; Sikka, Vinod K.; Ohriner, Evan K.

    2003-12-16

    A method for preparing flat foils having a high density includes the steps of mixing a powdered material with a binder to form a green sheet. The green sheet is exposed to a high intensity radiative source adapted to emit radiation of wavelengths corresponding to an absorption spectrum of the powdered material. The surface of the green sheet is heated while a lower sub-surface temperature is maintained. An apparatus for preparing a foil from a green sheet using a radiation source is also disclosed.

  7. High collection efficiency CVD diamond alpha detectors

    Energy Technology Data Exchange (ETDEWEB)

    Bergonzo, P.; Foulon, F.; Marshall, R.D.; Jany, C.; Brambilla, A. [CEA/Saclay, Gif-sur-Yvette (France); McKeag, R.D.; Jackman, R.B. [University College London (United Kingdom). Electronic and Electrical Engineering Dept.

    1998-06-01

    Advances in Chemical Vapor Deposited (CVD) diamond have enabled the routine use of this material for sensor device fabrication, allowing exploitation of its unique combination of physical properties (low temperature susceptibility (> 500 C), high resistance to radiation damage (> 100 Mrad) and to corrosive media). A consequence of CVD diamond growth on silicon is the formation of polycrystalline films which has a profound influence on the physical and electronic properties with respect to those measured on monocrystalline diamond. The authors report the optimization of physical and geometrical device parameters for radiation detection in the counting mode. Sandwich and co-planar electrode geometries are tested and their performances evaluated with regard to the nature of the field profile and drift distances inherent in such devices. The carrier drift length before trapping was measured under alpha particles and values as high as 40% of the overall film thickness are reported. Further, by optimizing the device geometry, they show that a gain in collection efficiency, defined as the induced charge divided by the deposited charge within the material, can be achieved even though lower bias values are used.

  8. Broadband circularly polarizing dichroism with high efficient plasmonic helical surface.

    Science.gov (United States)

    Hu, Jingpei; Zhao, Xiaonan; Li, Ruibin; Zhu, Aijiao; Chen, Linghua; Lin, Yu; Cao, Bing; Zhu, Xiaojun; Wang, Chinhua

    2016-05-16

    We propose and experimentally demonstrate a broadband and high efficient circularly polarizing dichroism using a simple single-cycle and single-helical plasmonic surface array arranged in square lattice. Two types of helical surface structures (partially or completely covered with a gold film) are investigated. It is shown that the circular polarization dichroism in the mid-IR range (3µm - 5µm) can reach 80% (when the surface is partially covered with gold) or 65% (when the surface is completely covered with gold) with a single-cycle and single-helical surface. Experimental fabrications of the proposed helical plasmonic surface are implemented with direct 3D laser writing followed by electron beam evaporation deposition of gold. The experimental evaluations of the circular polarization dichroism are in excellent agreement with the simulation. The proposed helical surface structure is of advantages of easy-fabrication, high-dichroism and scalable to other frequencies as a high efficient broadband circular polarizer.

  9. Environment and energy efficient dyeing of woollen fabric with sticta coronata

    Energy Technology Data Exchange (ETDEWEB)

    Mansour, Heba F. [Helwan University, Textile Printing, Dyeing and Finishing Department, Faculty of Applied Arts, Helwan (Egypt)

    2010-11-15

    For a trial to improve the natural dyeing cultural heritage to meet the environmental future demands technology to reach high quality dyed patterns. This paper deals with extraction, dyeing of woollen fabric with ''Sticta Coronata'' under ultrasonic energy and glucose/hydrogen peroxide based redox system. The efficiency of ultrasonic-assisted extraction in presence of 9:1 water:acetone solvent and dyeing in presence of redox system, followed by alum mordanting have been studied in compared when the system was absent and the traditional thermal technique. The influence of redox system, ultrasonic energy and alum mordanting on the rate of dyeing and dye fixation has been demonstrated, and the mechanism of glucose/hydrogen peroxide redox system has been tentatively suggested. The extraction with 9:1 water:acetone solvent possesses higher absorbency in shorter extraction time compared with the aqueous one. Redox system reduced the rate of dyeing at lower temperature with significant enhancement on the dye exhaustion and fixation, involving covalent bonding in addition to the usual coulombic bond. Mordanting process exhibited negligible effect and might decline the percentages of dye exhaustion and fixation in presence of redox system. Ultrasonic energy provided easy efficient route for dye extraction, dyeing, and mordanting processes in compared with the traditional thermal technique. (orig.)

  10. Efficiency and reliability assessments of retrofitted high-efficiency motors

    Energy Technology Data Exchange (ETDEWEB)

    Hsu, John S.; Otaduy, P.J.; Dueck, J.D.

    1994-12-31

    The majority of electric-motor applications are pumps, fans, blowers, and certain compressors that follow the load torque pattern described in this paper. It has been known for many years that simply replacing the old motor with a high-efficiency motor might not produce the expected efficiency gain. This paper suggests the calculations for the effective efficiency and temperature rise of the high-efficiency motor. The reliability in terms of temperature rise, downsizing, power factor, harmonics, mechanical structure, etc., are discussed.

  11. Laser-assisted fabrication of highly viscous alginate microsphere

    Science.gov (United States)

    Lin, Yafu; Huang, Yong

    2011-04-01

    Encapsulated microspheres have been widely used in various biomedical applications. However, fabrication of encapsulated microspheres from highly viscous materials has always been a manufacturing challenge. The objective of this study is to explore a novel metallic foil-assisted laser-induced forward transfer (LIFT), a laser-assisted fabrication technique, to make encapsulated microspheres using high sodium alginate concentration solutions. The proposed four-layer approach includes a quartz disk, a sacrificial and adhesive layer, a metallic foil, and a transferred suspension layer. It is found that the proposed four-layer modified LIFT approach provides a promising fabrication technology for making of bead-encapsulated microspheres from highly viscous solutions. During the process, the microsphere only can be formed if the direct-writing height is larger than the critical direct-writing height; otherwise, tail structured droplets are formed; and the encapsulated microsphere diameter linearly increases with the laser fluence and decreases with the sodium alginate concentration.

  12. Fabrication of Efficient Low-Bandgap Perovskite Solar Cells by Combining Formamidinium Tin Iodide with Methylammonium Lead Iodide.

    Science.gov (United States)

    Liao, Weiqiang; Zhao, Dewei; Yu, Yue; Shrestha, Niraj; Ghimire, Kiran; Grice, Corey R; Wang, Changlei; Xiao, Yuqing; Cimaroli, Alexander J; Ellingson, Randy J; Podraza, Nikolas J; Zhu, Kai; Xiong, Ren-Gen; Yan, Yanfa

    2016-09-28

    Mixed tin (Sn)-lead (Pb) perovskites with high Sn content exhibit low bandgaps suitable for fabricating the bottom cell of perovskite-based tandem solar cells. In this work, we report on the fabrication of efficient mixed Sn-Pb perovskite solar cells using precursors combining formamidinium tin iodide (FASnI3) and methylammonium lead iodide (MAPbI3). The best-performing cell fabricated using a (FASnI3)0.6(MAPbI3)0.4 absorber with an absorption edge of ∼1.2 eV achieved a power conversion efficiency (PCE) of 15.08 (15.00)% with an open-circuit voltage of 0.795 (0.799) V, a short-circuit current density of 26.86(26.82) mA/cm(2), and a fill factor of 70.6(70.0)% when measured under forward (reverse) voltage scan. The average PCE of 50 cells we have fabricated is 14.39 ± 0.33%, indicating good reproducibility.

  13. Fabrication of Efficient Low-Bandgap Perovskite Solar Cells by Combining Formamidinium Tin Iodide with Methylammonium Lead Iodide

    Energy Technology Data Exchange (ETDEWEB)

    Liao, Weiqiang; Zhao, Dewei; Yu, Yue; Shrestha, Niraj; Ghimire, Kiran; Grice, Corey R.; Wang, Changlei; Xiao, Yuqing; Cimaroli, Alexander J.; Ellingson, Randy J.; Podraza, Nikolas J.; Zhu, Kai; Xiong, Ren-Gen; Yan, Yanfa

    2016-09-28

    Mixed tin (Sn)-lead (Pb) perovskites with high Sn content exhibit low bandgaps suitable for fabricating the bottom cell of perovskite-based tandem solar cells. In this work, we report on the fabrication of efficient mixed Sn-Pb perovskite solar cells using precursors combining formamidinium tin iodide (FASnI3) and methylammonium lead iodide (MAPbI3). The best-performing cell fabricated using a (FASnI3)0.6(MAPbI3)0.4 absorber with an absorption edge of ~1.2 eV achieved a power conversion efficiency (PCE) of 15.08 (15.00)% with an open-circuit voltage of 0.795 (0.799) V, a short-circuit current density of 26.86(26.82) mA/cm2, and a fill factor of 70.6(70.0)% when measured under forward (reverse) voltage scan. The average PCE of 50 cells we have fabricated is 14.39 +/- 0.33%, indicating good reproducibility.

  14. High Efficiency Centrifugal Compressor for Rotorcraft Applications

    Science.gov (United States)

    Medic, Gorazd; Sharma, Om P.; Jongwook, Joo; Hardin, Larry W.; McCormick, Duane C.; Cousins, William T.; Lurie, Elizabeth A.; Shabbir, Aamir; Holley, Brian M.; Van Slooten, Paul R.

    2014-01-01

    The report "High Efficiency Centrifugal Compressor for Rotorcraft Applications" documents the work conducted at UTRC under the NRA Contract NNC08CB03C, with cost share 2/3 NASA, and 1/3 UTRC, that has been extended to 4.5 years. The purpose of this effort was to identify key technical barriers to advancing the state-of-the-art of small centrifugal compressor stages; to delineate the measurements required to provide insight into the flow physics of the technical barriers; to design, fabricate, install, and test a state-of-the-art research compressor that is representative of the rear stage of an axial-centrifugal aero-engine; and to acquire detailed aerodynamic performance and research quality data to clarify flow physics and to establish detailed data sets for future application. The design activity centered on meeting the goal set outlined in the NASA solicitation-the design target was to increase efficiency at higher work factor, while also reducing the maximum diameter of the stage. To fit within the existing Small Engine Components Test Facility at NASA Glenn Research Center (GRC) and to facilitate component re-use, certain key design parameters were fixed by UTRC, including impeller tip diameter, impeller rotational speed, and impeller inlet hub and shroud radii. This report describes the design effort of the High Efficiency Centrifugal Compressor stage (HECC) and delineation of measurements, fabrication of the compressor, and the initial tests that were performed. A new High-Efficiency Centrifugal Compressor stage with a very challenging reduction in radius ratio was successfully designed, fabricated and installed at GRC. The testing was successful, with no mechanical problems and the running clearances were achieved without impeller rubs. Overall, measured pressure ratio of 4.68, work factor of 0.81, and at design exit corrected flow rate of 3 lbm/s met the target requirements. Polytropic efficiency of 85.5 percent and stall margin of 7.5 percent were

  15. HIGH-EFFICIENCY INFRARED RECEIVER

    Directory of Open Access Journals (Sweden)

    A. K. Esman

    2016-01-01

    Full Text Available Recent research and development show promising use of high-performance solid-state receivers of the electromagnetic radiation. These receivers are based on the low-barrier Schottky diodes. The approach to the design of the receivers on the basis of delta-doped low-barrier Schottky diodes with beam leads without bias is especially actively developing because for uncooled receivers of the microwave radiation these diodes have virtually no competition. The purpose of this work is to improve the main parameters and characteristics that determine the practical relevance of the receivers of mid-infrared electromagnetic radiation at the operating room temperature by modifying the electrodes configuration of the diode and optimizing the distance between them. Proposed original design solution of the integrated receiver of mid-infrared radiation on the basis of the low-barrier Schottky diodes with beam leads allows to effectively adjust its main parameters and characteristics. Simulation of the electromagnetic characteristics of the proposed receiver by using the software package HFSS with the basic algorithm of a finite element method which implemented to calculate the behavior of electromagnetic fields on an arbitrary geometry with a predetermined material properties have shown that when the inner parts of the electrodes of the low-barrier Schottky diode is performed in the concentric elliptical convex-concave shape, it can be reduce the reflection losses to -57.75 dB and the standing wave ratio to 1.003 while increasing the directivity up to 23 at a wavelength of 6.09 μm. At this time, the rounded radii of the inner parts of the anode and cathode electrodes are equal 212 nm and 318 nm respectively and the gap setting between them is 106 nm. These parameters will improve the efficiency of the developed infrared optical-promising and electronic equipment for various purposes intended for work in the mid-infrared wavelength range. 

  16. A study of the antibacterial efficiency and coloration of dyed polyamide and polyester fabrics modified with colloidal Ag nanoparticles

    Directory of Open Access Journals (Sweden)

    VESNA ILIĆ

    2009-03-01

    Full Text Available In this study, the influence of dyeing on the antibacterial efficiency of polyamide and polyester fabrics loaded with colloidal Ag nanoparticles and the influence of the presence of Ag nanoparticles on the color change of dyed fabrics were investigated. Dyes C.I. acid green 25 and C.I. disperse blue 3 were used for dyeing of polyamide fabrics, while dye C.I. disperse violet 8 was used for dyeing of polyester fabrics. The influence of Ag nanoparticles on the color change of polyamide fabrics depends on the dye type, but generally it was lower compared to polyester fabrics. Polyester fabrics exhibited excellent antibacterial efficiency against Gram-positive bacterium Staphylococcus aureus and Gram-negative bacterium Escherichia coli, independent of the order of dyeing and Ag loading. Polyamide fabrics provided a desirable level of antibacterial activity only if the Ag loading was performed after dyeing.

  17. High Efficiency Refrigeration Process Project

    Data.gov (United States)

    National Aeronautics and Space Administration — It has been proposed by NASA JSC studies, that the most mass efficient (non-nuclear) method of Lunar habitat cooling is via photovoltaic (PV) direct vapor...

  18. Modeling, fabrication and high power optical characterization of plasmonic waveguides

    DEFF Research Database (Denmark)

    Lavrinenko, Andrei; Lysenko, Oleg

    2015-01-01

    This paper describes modeling, fabrication and high power optical characterization of thin gold films embedded in silicon dioxide. The propagation vector of surface plasmon polaritons has been calculated by the effective index method for the wavelength range of 750-1700 nm and film thickness of 15......, 30 and 45 nm. The fabrication process of such plasmonic waveguides with width in the range of 1-100 μm and their quality inspection are described. The results of optical characterization of plasmonic waveguides using a high power laser with the peak power wavelength 1064 nm show significant deviation...

  19. High efficiency turbine blade coatings.

    Energy Technology Data Exchange (ETDEWEB)

    Youchison, Dennis L.; Gallis, Michail A.

    2014-06-01

    The development of advanced thermal barrier coatings (TBCs) of yttria stabilized zirconia (YSZ) that exhibit lower thermal conductivity through better control of electron beam - physical vapor deposition (EB-PVD) processing is of prime interest to both the aerospace and power industries. This report summarizes the work performed under a two-year Lab-Directed Research and Development (LDRD) project (38664) to produce lower thermal conductivity, graded-layer thermal barrier coatings for turbine blades in an effort to increase the efficiency of high temperature gas turbines. This project was sponsored by the Nuclear Fuel Cycle Investment Area. Therefore, particular importance was given to the processing of the large blades required for industrial gas turbines proposed for use in the Brayton cycle of nuclear plants powered by high temperature gas-cooled reactors (HTGRs). During this modest (~1 full-time equivalent (FTE)) project, the processing technology was developed to create graded TBCs by coupling ion beam-assisted deposition (IBAD) with substrate pivoting in the alumina-YSZ system. The Electron Beam - 1200 kW (EB-1200) PVD system was used to deposit a variety of TBC coatings with micron layered microstructures and reduced thermal conductivity below 1.5 W/m.K. The use of IBAD produced fully stoichiometric coatings at a reduced substrate temperature of 600 oC and a reduced oxygen background pressure of 0.1 Pa. IBAD was also used to successfully demonstrate the transitioning of amorphous PVD-deposited alumina to the -phase alumina required as an oxygen diffusion barrier and for good adhesion to the substrate Ni2Al3 bondcoat. This process replaces the time consuming thermally grown oxide formation required before the YSZ deposition. In addition to the process technology, Direct Simulation Monte Carlo plume modeling and spectroscopic characterization of the PVD plumes were performed. The project consisted of five tasks. These included the production of layered

  20. High efficiency turbine blade coatings

    Energy Technology Data Exchange (ETDEWEB)

    Youchison, Dennis L. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Gallis, Michail A. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

    2014-06-01

    The development of advanced thermal barrier coatings (TBCs) of yttria stabilized zirconia (YSZ) that exhibit lower thermal conductivity through better control of electron beam - physical vapor deposition (EB-PVD) processing is of prime interest to both the aerospace and power industries. This report summarizes the work performed under a two-year Lab-Directed Research and Development (LDRD) project (38664) to produce lower thermal conductivity, graded-layer thermal barrier coatings for turbine blades in an effort to increase the efficiency of high temperature gas turbines. This project was sponsored by the Nuclear Fuel Cycle Investment Area. Therefore, particular importance was given to the processing of the large blades required for industrial gas turbines proposed for use in the Brayton cycle of nuclear plants powered by high temperature gas-cooled reactors (HTGRs). During this modest (~1 full-time equivalent (FTE)) project, the processing technology was developed to create graded TBCs by coupling ion beam-assisted deposition (IBAD) with substrate pivoting in the alumina-YSZ system. The Electron Beam - 1200 kW (EB-1200) PVD system was used to deposit a variety of TBC coatings with micron layered microstructures and reduced thermal conductivity below 1.5 W/m.K. The use of IBAD produced fully stoichiometric coatings at a reduced substrate temperature of 600°C and a reduced oxygen background pressure of 0.1 Pa. IBAD was also used to successfully demonstrate the transitioning of amorphous PVD-deposited alumina to the -phase alumina required as an oxygen diffusion barrier and for good adhesion to the substrate Ni2Al3 bondcoat. This process replaces the time consuming thermally grown oxide formation required before the YSZ deposition. In addition to the process technology, Direct Simulation Monte Carlo plume modeling and spectroscopic characterization of the PVD plumes were performed. The project consisted of five tasks. These included the

  1. Fabrication and characterization of novel Z-scheme photocatalyst WO{sub 3}/g-C{sub 3}N{sub 4} with high efficient visible light photocatalytic activity

    Energy Technology Data Exchange (ETDEWEB)

    Chen, Shifu, E-mail: chshifu@chnu.edu.cn [Department of Chemistry, Anhui Science and Technology University, Anhui, Fengyang 233100 (China); Department of Chemistry, Huaibei Normal University, Anhui, Huaibei 235000 (China); Hu, Yingfei; Jiang, Xiaoliang; Meng, Sugang; Fu, Xianliang [Department of Chemistry, Huaibei Normal University, Anhui, Huaibei 235000 (China)

    2015-01-15

    Developing a high-efficiency visible light photocatalyst is always a research hotspot in photocatalytic field. In this study, a novel Z-scheme photocatalyst WO{sub 3}/g-C{sub 3}N{sub 4} with high efficient visible light photocatalytic activity was prepared via ball milling and heat treatment methods. The photocatalyst was characterized by X-ray powder diffraction (XRD), UV–vis diffuse reflection spectroscopy (DRS), scanning electron microscopy (SEM), transmission electron microscopy (TEM), electron spin resonance (ESR), and photoluminescence (PL). The photocatalytic activity was evaluated by degradation of methylene blue (MB) and fuchsin (BF) under visible light illumination. The results showed that composite WO{sub 3}/g-C{sub 3}N{sub 4} exhibits a much higher photocatalytic activity than a single g-C{sub 3}N{sub 4}. The rate constants of photocatalytic degradation of MB and BF for WO{sub 3}(5.0 wt.%)/g-C{sub 3}N{sub 4} are 4.77 times and 3.84 times that of pure g-C{sub 3}N{sub 4}. The characterization results by physical and chemical methods demonstrated that composite WO{sub 3}/g-C{sub 3}N{sub 4} is a typical Z-scheme photocatalyst. The enhancement of the photocatalytic activity may be attributed to the formation of the Z-scheme system between g-C{sub 3}N{sub 4} and WO{sub 3}, which could result in the photoexcited electrons of g-C{sub 3}N{sub 4} and photoexcited holes of WO{sub 3} participating in oxidation and reduction reactions, respectively. - Graphical abstract: When WO{sub 3} is combined with g-C{sub 3}N{sub 4}, a Z-scheme system photocatalyst may be formed because of the short distance between the VB of g-C{sub 3}N{sub 4} and the CB of WO{sub 3}. Consequently, the photogenerated electrons in the CB of g-C{sub 3}N{sub 4} and holes in the VB of WO{sub 3} exhibit excellent reduction and oxidation ability, respectively. - Highlights: • WO{sub 3}/g-C{sub 3}N{sub 4} photocatalyst with high efficient visible light activity was prepared. • The WO{sub 3}/g

  2. Efficient Surface Enhanced Raman Scattering substrates from femtosecond laser based fabrication

    Science.gov (United States)

    Parmar, Vinod; Kanaujia, Pawan K.; Bommali, Ravi Kumar; Vijaya Prakash, G.

    2017-10-01

    A fast and simple femtosecond laser based methodology for efficient Surface Enhanced Raman Scattering (SERS) substrate fabrication has been proposed. Both nano scaffold silicon (black silicon) and gold nanoparticles (Au-NP) are fabricated by femtosecond laser based technique for mass production. Nano rough silicon scaffold enables large electromagnetic fields for the localized surface plasmons from decorated metallic nanoparticles. Thus giant enhancement (approximately in the order of 104) of Raman signal arises from the mixed effects of electron-photon-phonon coupling, even at nanomolar concentrations of test organic species (Rhodamine 6G). Proposed process demonstrates the low-cost and label-less application ability from these large-area SERS substrates.

  3. Development of fabrication technique of bulk high superconductor

    Energy Technology Data Exchange (ETDEWEB)

    Hong, Gye Won; Kim, Chang Joong; Kim, Ki Baik; Lee, Ho Jin; Lee, Hee Gyoun; Kwon, Sun Chil

    1997-05-01

    In order to realize the commercial application of HTSC materials, it is necessary to develop the fabrication process of high Tc oxide superconductor materials with desired shape and for practical application and high critical current density as well as good mechanical strength which critical current density as well as good mechanical strength which can withstand high lorenz force generated at high magnetic field. Much studies have been concentrated to develop the fabrication technique for high critical current density but still there are a lot of gap which should be overcome for large scale application of HTSC materials at liquid nitrogen temperature. Recently some new fabrication techniques have been developed for YBCO bulk superconductor with high mechanical strength and critical current density. In this project, plastic extrusion and melt process techniques were studied. The components materials for the current lead and the flywheel application were fabricated and their characteristics were investigated from the view point of microstructure and phase formation during heat treatment process. (author). 64 refs., 59 figs.

  4. High Energy Efficiency Air Conditioning

    Energy Technology Data Exchange (ETDEWEB)

    Edward McCullough; Patrick Dhooge; Jonathan Nimitz

    2003-12-31

    This project determined the performance of a new high efficiency refrigerant, Ikon B, in a residential air conditioner designed to use R-22. The refrigerant R-22, used in residential and small commercial air conditioners, is being phased out of production in developed countries beginning this year because of concerns regarding its ozone depletion potential. Although a replacement refrigerant, R-410A, is available, it operates at much higher pressure than R-22 and requires new equipment. R-22 air conditioners will continue to be in use for many years to come. Air conditioning is a large part of expensive summer peak power use in many parts of the U.S. Previous testing and computer simulations of Ikon B indicated that it would have 20 - 25% higher coefficient of performance (COP, the amount of cooling obtained per energy used) than R-22 in an air-cooled air conditioner. In this project, a typical new R-22 residential air conditioner was obtained, installed in a large environmental chamber, instrumented, and run both with its original charge of R-22 and then with Ikon B. In the environmental chamber, controlled temperature and humidity could be maintained to obtain repeatable and comparable energy use results. Tests with Ikon B included runs with and without a power controller, and an extended run for several months with subsequent analyses to check compatibility of Ikon B with the air conditioner materials and lubricant. Baseline energy use of the air conditioner with its original R-22 charge was measured at 90 deg F and 100 deg F. After changeover to Ikon B and a larger expansion orifice, energy use was measured at 90 deg F and 100 deg F. Ikon B proved to have about 19% higher COP at 90 deg F and about 26% higher COP at 100 deg F versus R-22. Ikon B had about 20% lower cooling capacity at 90 deg F and about 17% lower cooling capacity at 100 deg F versus R-22 in this system. All results over multiple runs were within 1% relative standard deviation (RSD). All of these

  5. Homogeneous PCBM layers fabricated by horizontal-dip coating for efficient bilayer heterojunction organic photovoltaic cells.

    Science.gov (United States)

    Huh, Yoon Ho; Bae, In-Gon; Jeon, Hong Goo; Park, Byoungchoo

    2016-10-31

    We herein report a homogeneous [6,6]-phenyl C61 butyric acid methyl ester (PCBM) layer, produced by a solution process of horizontal-dipping (H-dipping) to improve the photovoltaic (PV) effects of bilayer heterojunction organic photovoltaic cells (OPVs) based on a bi-stacked poly(3-hexylthiophene) (P3HT) electron donor layer and a PCBM electron acceptor layer (P3HT/PCBM). It was shown that a homogeneous and uniform coating of PCBM layers in the P3HT/PCBM bilayer OPVs resulted in reliable and reproducible device performance. We recorded a power conversion efficiency (PCE) of 2.89%, which is higher than that (2.00%) of bilayer OPVs with a spin-coated PCBM layer. Moreover, introducing surfactant additives of poly(oxyethylene tridecyl ether) (PTE) into the homogeneous P3HT/PCBM PV layers resulted in the bilayer OPVs showing a PCE value of 3.95%, which is comparable to those of conventional bulk-heterojunction (BHJ) OPVs (3.57-4.13%) fabricated by conventional spin-coating. This improved device performance may be attributed to the selective collection of charge carriers at the interfaces among the active layers and electrodes due to the PTE additives as well as the homogeneous formation of the functional PCBM layer on the P3HT layer. Furthermore, H-dip-coated PCBM layers were deposited onto aligned P3HT layers by a rubbing technique, and the rubbed bilayer OPV exhibited improved in-plane anisotropic PV effects with PCE anisotropy as high as 1.81, which is also higher than that (1.54) of conventional rubbed BHJ OPVs. Our results suggest that the use of the H-dip-coating process in the fabrication of PCBM layers with the PTE interface-engineering additive could be of considerable interest to those seeking to improve PCBM-based opto-electrical organic thin-film devices.

  6. High efficiency stationary hydrogen storage

    Energy Technology Data Exchange (ETDEWEB)

    Hynek, S.; Fuller, W.; Truslow, S. [Arthur D. Little, Inc., Cambridge, MA (United States)

    1995-09-01

    Stationary storage of hydrogen permits one to make hydrogen now and use it later. With stationary hydrogen storage, one can use excess electrical generation capacity to power an electrolyzer, and store the resultant hydrogen for later use or transshipment. One can also use stationary hydrogen as a buffer at fueling stations to accommodate non-steady fueling demand, thus permitting the hydrogen supply system (e.g., methane reformer or electrolyzer) to be sized to meet the average, rather than the peak, demand. We at ADL designed, built, and tested a stationary hydrogen storage device that thermally couples a high-temperature metal hydride to a phase change material (PCM). The PCM captures and stores the heat of the hydriding reaction as its own heat of fusion (that is, it melts), and subsequently returns that heat of fusion (by freezing) to facilitate the dehydriding reaction. A key component of this stationary hydrogen storage device is the metal hydride itself. We used nickel-coated magnesium powder (NCMP) - magnesium particles coated with a thin layer of nickel by means of chemical vapor deposition (CVD). Magnesium hydride can store a higher weight fraction of hydrogen than any other practical metal hydride, and it is less expensive than any other metal hydride. We designed and constructed an experimental NCM/PCM reactor out of 310 stainless steel in the form of a shell-and-tube heat exchanger, with the tube side packed with NCMP and the shell side filled with a eutectic mixture of NaCL, KCl, and MgCl{sub 2}. Our experimental results indicate that with proper attention to limiting thermal losses, our overall efficiency will exceed 90% (DOE goal: >75%) and our overall system cost will be only 33% (DOE goal: <50%) of the value of the delivered hydrogen. It appears that NCMP can be used to purify hydrogen streams and store hydrogen at the same time. These prospects make the NCMP/PCM reactor an attractive component in a reformer-based hydrogen fueling station.

  7. Highly efficient electron vortex beams generated by nanofabricated phase holograms

    Energy Technology Data Exchange (ETDEWEB)

    Grillo, Vincenzo, E-mail: vincenzo.grillo@nano.cnr.it [CNR-Istituto Nanoscienze, Centro S3, Via G Campi 213/a, I-41125 Modena (Italy); CNR-IMEM Parco Area delle Scienze 37/A, I-43124 Parma (Italy); Carlo Gazzadi, Gian [CNR-Istituto Nanoscienze, Centro S3, Via G Campi 213/a, I-41125 Modena (Italy); Karimi, Ebrahim [CNR-Istituto Nanoscienze, Centro S3, Via G Campi 213/a, I-41125 Modena (Italy); Department of Physics, University of Ottawa, 150 Louis Pasteur, Ottawa, Ontario K1N 6N5 (Canada); Mafakheri, Erfan [Dipartimento di Fisica Informatica e Matematica, Università di Modena e Reggio Emilia, via G Campi 213/a, I-41125 Modena (Italy); Boyd, Robert W. [Department of Physics, University of Ottawa, 150 Louis Pasteur, Ottawa, Ontario K1N 6N5 (Canada); Frabboni, Stefano [CNR-Istituto Nanoscienze, Centro S3, Via G Campi 213/a, I-41125 Modena (Italy); Dipartimento di Fisica Informatica e Matematica, Università di Modena e Reggio Emilia, via G Campi 213/a, I-41125 Modena (Italy)

    2014-01-27

    We propose an improved type of holographic-plate suitable for the shaping of electron beams. The plate is fabricated by a focused ion beam on a silicon nitride membrane and introduces a controllable phase shift to the electron wavefunction. We adopted the optimal blazed-profile design for the phase hologram, which results in the generation of highly efficient (25%) electron vortex beams. This approach paves the route towards applications in nano-scale imaging and materials science.

  8. Overview of Ecological Agriculture with High Efficiency

    Institute of Scientific and Technical Information of China (English)

    HUANG Guo-qin; ZHAO Qi-guo; GONG Shao-lin; SHI Qing-hua

    2012-01-01

    From the presentation, connotation, characteristics, principles, pattern, and technologies of ecological agriculture with high efficiency, we conduct comprehensive and systematic analysis and discussion of the theoretical and practical progress of ecological agriculture with high efficiency. (i) Ecological agriculture with high efficiency was first advanced in China in 1991. (ii) Ecological agriculture with high efficiency highlights "high efficiency", "ecology", and "combination". (iii) Ecological agriculture with high efficiency is characterized by diverse organisms, good environment, good structure, powerful function, good quality, high benefit, low emission, sustainability. (iv) The yield increase and efficiency increase principle of ecological agriculture with high efficiency lies in full land use, three-dimensional light use, sufficient use of season, multi-layer water consumption, efficient fertilizer consumption, symbiosis and mutual supplement, ecological disaster reduction, recycling. (v) The typical pattern of ecological agriculture with high efficiency includes three-dimensional use pattern, biological symbiosis pattern, multi-industry combination pattern, industrial extension pattern, technology-driven pattern, environmental renovation pattern, resource recycling pattern, leisure and sight-seeing pattern. (vi) The key technologies of ecological agriculture with high efficiency include resource-saving technology, water and fertilizer regulation technology, biological technology for increasing soil fertility, disaster prevention and mitigation technology, comprehensive utilization technology, water conservation technology, structural adjustment technology, energy development technology, watershed control technology, and modern high-tech technology.

  9. Fabrication of efficient thermoacoustic device with an interdigitated-like electrode on indium tin oxide glass

    Science.gov (United States)

    Tsai, Ming-shan; Yang, Ko-kang; Chen, Sy-hann; Ting, Chen-ching; Jiang, I.-min

    2016-10-01

    A thermoacoustic device was fabricated on indium tin oxide (ITO) glass, exhibiting an interdigitated-like electrode pattern. Our fabrication method enhanced the sound performance by approximately 20 dB compared with that of plain ITO film. Two approaches were adopted in this study to enhance the sound pressure level (SPL). One was to decrease the heat capacity per unit area of the device by reducing the thickness of the conductor film, and the other was to increase the thermal diffusivity of the device by applying a thin Au film on the electrode. We observed that heat generated by electron accumulation on ITO protrusions resulted in a large temperature oscillation of the surroundings and induced an SPL increase. A 4 nm Au film coating on the fabricated thermoacoustic device assisted thermal energy exchange with close-proximity air, improving the efficiency by an SPL of 7 dB.

  10. High-Efficiency Rad-Hard Ultra-Thin Si Photovoltaic Cell Technology for Space Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Improvements to solar cell efficiency that is consistent with low cost, high volume fabrication techniques are critical for future NASA space missions. In this...

  11. High Efficiency Particulate Air (HEPA) filters from polyester and polypropylene fibre nonwovens

    CSIR Research Space (South Africa)

    Boguslavsky, L

    2010-10-01

    Full Text Available In this work, High Efficiency Particulate Air (HEPA) Filters are designed to keep small harmful particles from entering a control environment or to prevent them from escaping. Nonwoven fabrics for filtration application were produced from...

  12. Modeling, fabrication and high power optical characterization of plasmonic waveguides

    DEFF Research Database (Denmark)

    Lavrinenko, Andrei; Lysenko, Oleg

    2015-01-01

    This paper describes modeling, fabrication and high power optical characterization of thin gold films embedded in silicon dioxide. The propagation vector of surface plasmon polaritons has been calculated by the effective index method for the wavelength range of 750-1700 nm and film thickness of 1...

  13. Fabrication of high-aspect ratio SU-8 micropillar arrays

    DEFF Research Database (Denmark)

    Amato, Letizia; Keller, Stephan S.; Heiskanen, Arto

    2012-01-01

    SU-8 is the preferred photoresist for development and fabrication of high aspect ratio (HAR) three dimensional patterns. However, processing of SU-8 is a challenging task, especially when the film thickness as well as the aspect ratio is increasing and the size of the features is close to the res...

  14. Design and Fabrication of High Sensitive Piezoresistive MEMS Accelerometer

    Directory of Open Access Journals (Sweden)

    JOSHI A.B

    2008-04-01

    Full Text Available This paper addresses the design and fabrication of high sensitive single axis piezoresistive micro-accelerometer for 50 g application. MEMS based accelerometer structure comprise of flexure fixed at one end and having attached proof mass at other end. This structure is designed and simulated using Coventorware. The simulation results show the sensitivity of 4mV/g. The structure is fabricated in N type silicon (100 substrate using Silicon bulk micromachining. This paper also discuses the use of PECVD Si3N4 layer as a masking material for silicon micromachining and process flow for accelerometer.

  15. Fabrication of High Quality Three-Dimensional Photonic Crystals

    Institute of Scientific and Technical Information of China (English)

    HU Xiao-Yong; LIU Yuan-Hao; CHENG Bing-Ying; ZHANG Dao-Zhong; MENG Qing-Bo

    2004-01-01

    High quality colloidal photonic crystals made from polystyrene spheres with diameter 240nm are fabricated by the vertical deposition method. The scanning electron microscopy (SEM) and the transmittance spectrum are used to characterize the properties of the photonic crystal. The SEM images show that there are few lattice defects. The transmittance of the photonic crystal is above 75% in the pass band at 700nm and is lower than 5% at the centre of the band gap, respectively. It is found that proper concentration is a very important factor to fabricate the photonic crystal when the diameter of the spheres is lower than 300nm.

  16. Fabrication of control rods for the High Flux Isotope Reactor

    Energy Technology Data Exchange (ETDEWEB)

    Sease, J.D.

    1998-03-01

    The High Flux Isotope Reactor (HFIR) is a research-type nuclear reactor that was designed and built in the early 1960s and has been in continuous operation since its initial criticality in 1965. Under current plans, the HFIR is expected to continue in operation until 2035. This report updates ORNL/TM-9365, Fabrication Procedure for HFIR Control Plates, which was mainly prepared in the early 1970's but was not issued until 1984, and reflects process changes, lessons learned in the latest control rod fabrication campaign, and suggested process improvements to be considered in future campaigns. Most of the personnel involved with the initial development of the processes and in part campaigns have retired or will retire soon. Because their unlikely availability in future campaigns, emphasis has been placed on providing some explanation of why the processes were selected and some discussions about the importance of controlling critical process parameters. Contained in this report is a description of the function of control rods in the reactor, the brief history of the development of control rod fabrication processes, and a description of procedures used in the fabrication of control rods. A listing of the controlled documents and procedures used in the last fabrication campaigns is referenced in Appendix A.

  17. Improving Light Outcoupling Efficiency for OLEDs with Microlens Array Fabricated on Transparent Substrate

    Directory of Open Access Journals (Sweden)

    Jun Wang

    2014-01-01

    Full Text Available Low light outcoupling efficiency restricts the wide application of organic light-emitting diodes in solid state light market although the internal quantum efficiency of the device could reach near to 100%. In order to improve the output efficiency, different kinds of microlens array on the substrate emission surface were designed and simulated using light tracing method. Simulation results indicate that the microlens array on the substrate could efficiently improve the light output efficiency and an enhancement of 1.8 could be obtained with optimized microlens structure design. The microlens array with semicircle shape using polymer material was fabricated on glass substrate by a facile approach. Finally, the organic device with microlens array substrate was manufactured and the light output of the device with surface microlens structure could increase to 1.64 times comparing with the device without microlens.

  18. High power, high efficiency millimeter wavelength traveling wave tubes for high rate communications from deep space

    Science.gov (United States)

    Dayton, James A., Jr.

    1991-01-01

    The high-power transmitters needed for high data rate communications from deep space will require a new class of compact, high efficiency traveling wave tubes (TWT's). Many of the recent TWT developments in the microwave frequency range are generically applicable to mm wave devices, in particular much of the technology of computer aided design, cathodes, and multistage depressed collectors. However, because TWT dimensions scale approximately with wavelength, mm wave devices will be physically much smaller with inherently more stringent fabrication tolerances and sensitivity to thermal dissipation.

  19. Highly Efficient Freestyle Magnetic Nanoswimmer.

    Science.gov (United States)

    Li, Tianlong; Li, Jinxing; Morozov, Konstantin I; Wu, Zhiguang; Xu, Tailin; Rozen, Isaac; Leshansky, Alexander M; Li, Longqiu; Wang, Joseph

    2017-08-09

    The unique swimming strategies of natural microorganisms have inspired recent development of magnetic micro/nanorobots powered by artificial helical or flexible flagella. However, as artificial nanoswimmers with unique geometries are being developed, it is critical to explore new potential modes for kinetic optimization. For example, the freestyle stroke is the most efficient of the competitive swimming strokes for humans. Here we report a new type of magnetic nanorobot, a symmetric multilinked two-arm nanoswimmer, capable of efficient "freestyle" swimming at low Reynolds numbers. Excellent agreement between the experimental observations and theoretical predictions indicates that the powerful "freestyle" propulsion of the two-arm nanorobot is attributed to synchronized oscillatory deformations of the nanorobot under the combined action of magnetic field and viscous forces. It is demonstrated for the first time that the nonplanar propulsion gait due to the cooperative "freestyle" stroke of the two magnetic arms can be powered by a plane oscillatory magnetic field. These two-arm nanorobots are capable of a powerful propulsion up to 12 body lengths per second, along with on-demand speed regulation and remote navigation. Furthermore, the nonplanar propulsion gait powered by the consecutive swinging of the achiral magnetic arms is more efficient than that of common chiral nanohelical swimmers. This new swimming mechanism and its attractive performance opens new possibilities in designing remotely actuated nanorobots for biomedical operation at the nanoscale.

  20. Efficient perovskite solar cells fabricated using an aqueous lead nitrate precursor.

    Science.gov (United States)

    Hsieh, Tsung-Yu; Wei, Tzu-Chien; Wu, Kuan-Lin; Ikegami, Masashi; Miyasaka, Tsutomu

    2015-09-04

    A novel, aqueous precursor system (Pb(NO3)2 + water) is developed to replace conventional (PbI2 + DMF) for fabricating methylammonium lead iodide (MAPbI3) perovskite solar cells (PSCs). When the morphology and surface coverage of the Pb(NO3)2 film was controlled during coating, a power conversion efficiency of 12.58% under standard conditions (AM1.5, 100 mW cm(-2)) was achieved for the PSC.

  1. Tailored Materials for High Efficiency CIDI Engines

    Energy Technology Data Exchange (ETDEWEB)

    Grant, G.J.; Jana, S.

    2012-03-30

    The overall goal of the project, Tailored Materials for High Efficiency Compression Ignition Direct Injection (CIDI) Engines, is to enable the implementation of new combustion strategies, such as homogeneous charge compression ignition (HCCI), that have the potential to significantly increase the energy efficiency of current diesel engines and decrease fuel consumption and environmental emissions. These strategies, however, are increasing the demands on conventional engine materials, either from increases in peak cylinder pressure (PCP) or from increases in the temperature of operation. The specific objective of this project is to investigate the application of a new material processing technology, friction stir processing (FSP), to improve the thermal and mechanical properties of engine components. The concept is to modify the surfaces of conventional, low-cost engine materials. The project focused primarily on FSP in aluminum materials that are compositional analogs to the typical piston and head alloys seen in small- to mid-sized CIDI engines. Investigations have been primarily of two types over the duration of this project: (1) FSP of a cast hypoeutectic Al-Si-Mg (A356/357) alloy with no introduction of any new components, and (2) FSP of Al-Cu-Ni alloys (Alloy 339) by physically stirring-in various quantities of carbon nanotubes/nanofibers or carbon fibers. Experimental work to date on aluminum systems has shown significant increases in fatigue lifetime and stress-level performance in aluminum-silicon alloys using friction processing alone, but work to demonstrate the addition of carbon nanotubes and fibers into aluminum substrates has shown mixed results due primarily to the difficulty in achieving porosity-free, homogeneous distributions of the particulate. A limited effort to understand the effects of FSP on steel materials was also undertaken during the course of this project. Processed regions were created in high-strength, low-alloyed steels up to 0.5 in

  2. High-efficiency solar concentrator

    Science.gov (United States)

    Lansing, F. L.; Dorman, J.

    1980-01-01

    A new type of solar concentrator is presented using liquid lenses and simple translational tracking mechanism. The concentrator achieves a 100:1 nominal concentration ratio and is compared in performance with a flat-plate collector having two sheets of glazing and non-selective coating. The results of the thermal analysis show that higher temperatures can be obtained with the concentrator than is possible with the non-concentrator flat-plate type. Furthermore, the thermal efficiency far exceeds that of the comparative flat-plate type for all operating conditions.

  3. PbSe quantum dot solar cells with more than 6% efficiency fabricated in ambient atmosphere.

    Science.gov (United States)

    Zhang, Jianbing; Gao, Jianbo; Church, Carena P; Miller, Elisa M; Luther, Joseph M; Klimov, Victor I; Beard, Matthew C

    2014-10-08

    Colloidal quantum dots (QDs) are promising candidates for the next generation of photovoltaic (PV) technologies. Much of the progress in QD PVs is based on using PbS QDs, partly because they are stable under ambient conditions. There is considerable interest in extending this work to PbSe QDs, which have shown an enhanced photocurrent due to multiple exciton generation (MEG). One problem complicating such device-based studies is a poor stability of PbSe QDs toward exposure to ambient air. Here we develop a direct cation exchange synthesis to produce PbSe QDs with a large range of sizes and with in situ chloride and cadmium passivation. The synthesized QDs have excellent air stability, maintaining their photoluminescence quantum yield under ambient conditions for more than 30 days. Using these QDs, we fabricate high-performance solar cells without any protection and demonstrate a power conversion efficiency exceeding 6%, which is a current record for PbSe QD solar cells.

  4. Fabrication and applications of highly nonlinear silica holey fibres

    OpenAIRE

    Belardi, W.; Monro, T.M.; Price, J.H.V.; Lee, J.H.; Petropoulos, P.; Richardson, D J

    2001-01-01

    Holey fibre (HF) technology provides a new way to fabricate novel highly nonlinear silica based fibres. The cladding of a HF is defined by an arrangement of air holes that run along the fibre length surrounding a central silica core. The reduction in core size and increase in refractive index contrast that is possible in a HF allows the production of fibres with extremely high effective nonlinearity. HFs can also exhibit, by design of the hole configuration [2], dispersion properties not poss...

  5. Fabrication

    Directory of Open Access Journals (Sweden)

    E.M.S. Azzam

    2013-12-01

    Full Text Available In the present work, the nanoclay composites were fabricated using the synthesized poly 6-(3-aminophenoxy hexane-1-thiol, poly 8-(3-aminophenoxy octane-1-thiol and poly 10-(3-aminophenoxy decane-1-thiol surfactants with gold nanoparticles. The polymeric thiol surfactants were first assembled on gold nanoparticles and then impregnated into the clay matrix. Different spectroscopic and microscopic techniques such as X-ray diffraction (XRD, Scanning electron microscope (SEM and Transmission microscope (TEM were used to characterize the fabricated nanoclay composites. The results showed that the polymeric thiol surfactants assembled on gold nanoparticles are located in the interlayer space of the clay mineral and affected the clay structure.

  6. Efficient single-photon source based on a deterministically fabricated single quantum dot - microstructure with backside gold mirror

    Science.gov (United States)

    Fischbach, Sarah; Kaganskiy, Arsenty; Tauscher, Esra Burcu Yarar; Gericke, Fabian; Thoma, Alexander; Schmidt, Ronny; Strittmatter, André; Heindel, Tobias; Rodt, Sven; Reitzenstein, Stephan

    2017-07-01

    We present an efficient broadband single-photon source which is fabricated by a flip-chip gold-bonding technique and in-situ electron beam lithography. The device comprises a single InGaAs quantum dot that is centered at the bottom of a monolithic mesa structure and located above a gold mirror for enhanced photon-extraction efficiency. We show a photon-extraction efficiency of ηex t=(18 ±2 ) % into a numerical aperture of 0.4 and a high suppression of multi-photon events from this source with g(2 )(0 )=0.015 ±0.009 . Our deterministic device with a backside gold mirror can be combined with electrical contacts and piezo-tuning capabilities in future refinements, which represents an important step towards a spectrally tunable plug-and-play quantum-light source with broadband enhancement for photonic quantum networks.

  7. Basic studies of 3-V high efficiency cell components

    Energy Technology Data Exchange (ETDEWEB)

    Lundstrom, M.S.; Melloch, M.R.; Pierret, R.F.; Carpenter, M.S.; Chuang, H.L.; Keshavarzi, A.; Klausmeier-Brown, M.E.; Lush, G.B.; Morgan, J.M.; Stellwag, T.B. (Purdue Univ., Lafayette, IN (USA). School of Electrical Engineering)

    1990-07-01

    This project's objective is to improve our fundamental understanding of the generation, recombination, and transport of carriers within III-V homo- and heterostructures. The research consists of fabricating and characterizing solar cell building blocks'' such as junctions and heterojunctions as well as basic measurements of material parameters. A significant effort is also being directed at characterizing loss mechanisms in high-quality, III-V solar cells fabricated in industrial research laboratories throughout the United States. The project's goal is to use our understanding of the device physics of high-efficiency cell components to maximize cell efficiency. A related goal is the demonstration of new cell structures fabricated by molecular beam epitaxy (MBE). The development of measurement techniques and characterization methodologies is also a project objective. We expect that the insight into III-V device physics occurring during the course of this work will help to identify paths toward higher efficiency III-V cells. This report describes our progress during the fourth year of the project. The past year's efforts centered on completing studies of heavy doping effects in p{sup +}-GaAs and assessing the importance of similar effects in n{sup +}-GaAs, and at continuing research on characterizing, controlling, and passivating perimeter recombination currents. We also initiated work to identify the dominant loss mechanism in Al{sub 0.2}Ga{sub 0.8} As solar cells and brought on-line a new MBE growth facility and demonstrated the high-quality of the films by fabricating, with assistance from Spire Corporation, 23.8% 1-sun solar cells.

  8. Fabrication and tolerances of optics for high concentration photovoltaics

    OpenAIRE

    Benitez Gimenez, Pablo; Miñano Dominguez, Juan Carlos; Ahmadpanaih, Hamed; Mendes Lopes, Joao; Zamora Herranz, Pablo

    2014-01-01

    High Concentration Photovoltaics (HCPV) require an optical system with high efficiency, low cost and large tolerance. We describe the particularities of the HCPV applications, which constrain the optics design and the manufacturing techonologies.

  9. Fabrication of High-Quality Niobium Superconducting Tunnel Junctions

    Institute of Scientific and Technical Information of China (English)

    XU Qin-Yin; CAO Chun-Hai; LI Meng-Yue; JIANG Yi; ZHA Shi-Tong; KANG Lin; XU Wei-Wei; CHEN Jian; WU Pei-Heng

    2011-01-01

    @@ For high-quality superconducting tunnel junctions(STJS), it is necessary to reduce leakage current as much as possible.We describe the fabrication of niobium STJs using the selective niobium(Nb) etching process and various ways to minimize the leakage current.The experiment shows that the leakage current mainly comes from shorts in the tunnel barrier layer rather than those around the junction edges.Through systematic analysis of the thin film stress, surface morphology and modified junction structures, we fabricate high-quality Nb STJs with a gap voltage of 2.8 mV and a leakage current at 1 m V as low as 8.1 % and 0.023% at 4.2K and 0.3 K, respectively.

  10. Fabricating High-Resolution X-Ray Collimators

    Science.gov (United States)

    Appleby, Michael; Atkinson, James E.; Fraser, Iain; Klinger, Jill

    2008-01-01

    A process and method for fabricating multi-grid, high-resolution rotating modulation collimators for arcsecond and sub-arcsecond x-ray and gamma-ray imaging involves photochemical machining and precision stack lamination. The special fixturing and etching techniques that have been developed are used for the fabrication of multiple high-resolution grids on a single array substrate. This technology has application in solar and astrophysics and in a number of medical imaging applications including mammography, computed tomography (CT), single photon emission computed tomography (SPECT), and gamma cameras used in nuclear medicine. This collimator improvement can also be used in non-destructive testing, hydrodynamic weapons testing, and microbeam radiation therapy.

  11. Efficient composite fabrication using electron-beam rapidly cured polymers engineered for several manufacturing processes

    Energy Technology Data Exchange (ETDEWEB)

    Walton, T.C. [Aeroplas Corp. International, Nashua, NH (United States); Crivello, J.V. [Rensselaer Polytechnic Inst., Troy, NY (United States). Dept. of Chemistry

    1995-10-01

    Low cost, efficiently processed ultra high specific strength and stiffness graphite fiber reinforced polymeric composite materials are of great interest to commercial transportation, construction and aerospace industries for use in various components with enhanced degrees of weight reduction, corrosion/erosion resistance and fatigue resistance. 10 MeV Electron Beam cure processing has been found to increase the cure rate by an order of magnitude over thermally cured systems yet provide less molded in stresses and high T{sub g}s. However, a limited range of resins are available which are easily processed with low shrinkage and with performance properties equal or exceeding those of state of the art toughened epoxies and BMI`s. The technology, introduced by an academia-industry partnership sparked by Langley Research Center utilizes a cost effective, rapid curing polymeric composite processing technique which effectively reduces the need for expensive tooling and energy inefficient autoclave processing and can cure the laminate in seconds (compared to hours for thermal curing) in ambient or sub-ambient conditions. The process is based on electron beam (E-Beam) curing of a new series of (65 to 1,000,000 cPs.) specially formulated resins that have been shown to exhibit excellent mechanical and physical properties once cured. Fabrication processes utilizing these specially formulated and newly commercialized resins, (e.g. including Vacuum Assist Resin Transfer molding (VARTM), vacuum bag prepreg layup, pultrusion and filament winding grades) are engineered to cure with low shrinkage, provide excellent mechanical properties, be processed solventless (environmentally friendly) and are inherently non toxic.

  12. High volume fabrication of laser targets using MEMS techniques

    Science.gov (United States)

    Spindloe, C.; Arthur, G.; Hall, F.; Tomlinson, S.; Potter, R.; Kar, S.; Green, J.; Higginbotham, A.; Booth, N.; Tolley, M. K.

    2016-04-01

    The latest techniques for the fabrication of high power laser targets, using processes developed for the manufacture of Micro-Electro-Mechanical System (MEMS) devices are discussed. These laser targets are designed to meet the needs of the increased shot numbers that are available in the latest design of laser facilities. Traditionally laser targets have been fabricated using conventional machining or coarse etching processes and have been produced in quantities of 10s to low 100s. Such targets can be used for high complexity experiments such as Inertial Fusion Energy (IFE) studies and can have many complex components that need assembling and characterisation with high precision. Using the techniques that are common to MEMS devices and integrating these with an existing target fabrication capability we are able to manufacture and deliver targets to these systems. It also enables us to manufacture novel targets that have not been possible using other techniques. In addition, developments in the positioning systems that are required to deliver these targets to the laser focus are also required and a system to deliver the target to a focus of an F2 beam at 0.1Hz is discussed.

  13. High-Efficiency dc/dc Converter

    Science.gov (United States)

    Sturman, J.

    1982-01-01

    High-efficiency dc/dc converter has been developed that provides commonly used voltages of plus or minus 12 Volts from an unregulated dc source of from 14 to 40 Volts. Unique features of converter are its high efficiency at low power level and ability to provide output either larger or smaller than input voltage.

  14. Catalytic liquid marbles: Ag nanowire-based miniature reactors for highly efficient degradation of methylene blue.

    Science.gov (United States)

    Miao, Yue-E; Lee, Hiang Kwee; Chew, Wee Shern; Phang, In Yee; Liu, Tianxi; Ling, Xing Yi

    2014-06-04

    Ag nanowire-based catalytic liquid marbles are fabricated as miniature reactors, which demonstrate highly efficient, support-free and rate-controllable heterogeneous degradation of methylene blue, with catalytic efficiency close to 100%. Our miniature catalytic liquid marbles are essential for reactions involving highly toxic/hazardous or costly reactants, where small volume preliminary reactions are preferred.

  15. High Efficiency Microwave Power Amplifier (HEMPA) Design

    Science.gov (United States)

    Sims, W. Herbert

    2004-01-01

    This paper will focus on developing an exotic switching technique that enhances the DC-to-RF conversion efficiency of microwave power amplifiers. For years, switching techniques implemented in the 10 kHz to 30 MHz region have resulted in DC-to-RF conversion efficiencies of 90-95-percent. Currently amplifier conversion efficiency, in the 2-3 GHz region approaches, 10-20-percent. Using a combination of analytical modeling and hardware testing, a High Efficiency Microwave Power Amplifier was built that demonstrated conversion efficiencies four to five times higher than current state of the art.

  16. Multicolor, High Efficiency, Nanotextured LEDs

    Energy Technology Data Exchange (ETDEWEB)

    Jung Han; Arto Nurmikko

    2011-09-30

    We report on research results in this project which synergize advanced material science approaches with fundamental optical physics concepts pertaining to light-matter interaction, with the goal of solving seminal problems for the development of very high performance light emitting diodes (LEDs) in the blue and green for Solid State Lighting applications. Accomplishments in the duration of the contract period include (i) heteroepitaxy of nitrogen-polar LEDs on sapphire, (ii) heteroepitaxy of semipolar (11{bar 2}2) green LEDs on sapphire, (iii) synthesis of quantum-dot loaded nanoporous GaN that emits white light without phosphor conversion, (iv) demonstration of the highest quality semipolar (11{bar 2}2) GaN on sapphire using orientation-controlled epitaxy, (v) synthesis of nanoscale GaN and InGaN medium, and (vi) development of a novel liftoff process for manufacturing GaN thin-film vertical LEDs. The body of results is presented in this report shows how a solid foundation has been laid, with several noticeable accomplishments, for innovative research, consistent with the stated milestones.

  17. High temperature SU-8 pyrolysis for fabrication of carbon electrodes

    DEFF Research Database (Denmark)

    Hassan, Yasmin Mohamed; Caviglia, Claudia; Hemanth, Suhith

    2017-01-01

    In this work, we present the investigation of the pyrolysis parameters at high temperature (1100 °C) for the fabrication of two-dimensional pyrolytic carbon electrodes. The electrodes were fabricated by pyrolysis of lithographically patterned negative epoxy based photoresist SU-8. A central...... composite experimental design was used to identify the influence of dwell time at the highest pyrolysis temperature and heating rate on electrical, electrochemical and structural properties of the pyrolytic carbon: Van der Pauw sheet resistance measurements, cyclic voltammetry, electrochemical impedance...... spectroscopy and Raman spectroscopy were used to characterize the pyrolytic carbon. The results show that the temperature increase from 900 °C to 1100 °C improves the electrical and electrochemical properties. At 1100 °C, longer dwell time leads to lower resistivity, while the variation of the pyrolysis...

  18. Highly Efficient, Simplified, Solution-Processed Thermally Activated Delayed-Fluorescence Organic Light-Emitting Diodes.

    Science.gov (United States)

    Kim, Young-Hoon; Wolf, Christoph; Cho, Himchan; Jeong, Su-Hun; Lee, Tae-Woo

    2016-01-27

    Highly efficient, simplified, solution-processed thermally activated delayed-fluorescence organic light-emitting diodes can be realized by using pure-organic thermally activated delayed fluorescence emitters and a multifunctional buffer hole-injection layer, in which high EQE (≈24%) and current efficiency (≈73 cd A(-1) ) are demonstrated. High-efficiency fluorescence red-emitting and blue-emitting devices can also be fabricated in this manner.

  19. Highly-efficient high-power pumps for fiber lasers

    Science.gov (United States)

    Gapontsev, V.; Moshegov, N.; Berezin, I.; Komissarov, A.; Trubenko, P.; Miftakhutdinov, D.; Berishev, I.; Chuyanov, V.; Raisky, O.; Ovtchinnikov, A.

    2017-02-01

    We report on high efficiency multimode pumps that enable ultra-high efficiency high power ECO Fiber Lasers. We discuss chip and packaged pump design and performance. Peak out-of-fiber power efficiency of ECO Fiber Laser pumps was reported to be as high as 68% and was achieved with passive cooling. For applications that do not require Fiber Lasers with ultimate power efficiency, we have developed passively cooled pumps with out-of-fiber power efficiency greater than 50%, maintained at operating current up to 22A. We report on approaches to diode chip and packaged pump design that possess such performance.

  20. Subwavelength-thick Lenses with High Numerical Apertures and Large Efficiency Based on High Contrast Transmitarrays

    CERN Document Server

    Arbabi, Amir; Ball, Alexander J; Bagheri, Mahmood; Faraon, Andrei

    2014-01-01

    We report subwavelength-thick, polarization insensitive micro-lenses operating at telecom wavelength with focal spots as small as 0.57 wavelengths and measured focusing efficiency up to 82%. The lens design is based on high contrast transmitarrays that enable control of optical phase fronts with subwavelength spatial resolution. A rigorous method for ultra-thin lens design, and the trade-off between high efficiency and small spot size (or large numerical aperture) are discussed. The transmitarrays, composed of silicon nano-posts on glass, could be fabricated by high-throughput photo or nanoimprint lithography, thus enabling widespread adoption.

  1. Groove shape characteristics of echelle gratings with high diffraction efficiency

    Science.gov (United States)

    Zhang, Shanwen; Mi, Xiaotao; Zhang, Qian; Jirigalantu; Feng, Shulong; Yu, Haili; Qi, Xiangdong

    2017-03-01

    The groove shape characteristics of echelle gratings with high diffraction efficiency are investigated. Using the coordinate transformation method (C method), an r-2 aluminum echelle with 79 grooves/mm is optimized through rigorous numerical simulations and shows high diffraction efficiency of 76-81% in the high Littrow orders. A grating is found to be essentially an echelle if it contains a series of reflective facets with a specific tilt angle that are located far from the nonworking facet of the grating and have a deep groove depth; any groove shape that meets these conditions can be called an echelle grating. The underlying mechanism is analyzed phenomenologically using electromagnetic theory. The universal model proposed here, which represents a new cognitive understanding of the concept of the echelle, is ready for use in manufacturing applications and offers a new perspective for the fabrication of these gratings.

  2. On-chip Fabrication of High Performance Nanostructured ZnO UV Detectors

    Science.gov (United States)

    Alenezi, Mohammad R.; Henley, Simon J.; Silva, S. R. P.

    2015-02-01

    Developing rationally controlled bottom-up device fabrication processes is essential for the achievement of high performance optimal devices. We report a controlled, seedless and site-selective hydrothermal technique to fabricate high-performance nanostructured ZnO UV-detectors directly on-chip. We demonstrate that by controlling the nanowire growth process, via tuning the experimental parameters such as the concentration of reactants and the growth time, and by introducing a refresh of the growth solution, the device structure efficiency can be enhanced to significantly improve its performance. The on-chip fabricated bridging nanosyringe ultraviolet detector demonstrates improved sensitivity (~105), nanowatts detectability, and ultrafast response-time (90 ms) and recovery-time (210 ms). The improvement in response-time and recovery-time is attributed to the unique nanowire-nanowire junction barrier dominated resistance and the direct contact between ZnO and Au electrodes. Furthermore, the enhanced sensitivity and nanowatts detectability of the bridging nanosyringe device are due to the reduction in dimensionality and ultrahigh surface-to-volume ratio. This work paves the way toward low cost, large scale, low temperature, seedless and site-selective fabrication of high performance ZnO nanowire sensors on flexible and transparent substrates.

  3. Sliver Solar Cells: High-Efficiency, Low-Cost PV Technology

    Directory of Open Access Journals (Sweden)

    Evan Franklin

    2007-01-01

    Full Text Available Sliver cells are thin, single-crystal silicon solar cells fabricated using standard fabrication technology. Sliver modules, composed of several thousand individual Sliver cells, can be efficient, low-cost, bifacial, transparent, flexible, shadow tolerant, and lightweight. Compared with current PV technology, mature Sliver technology will need 10% of the pure silicon and fewer than 5% of the wafer starts per MW of factory output. This paper deals with two distinct challenges related to Sliver cell and Sliver module production: providing a mature and robust Sliver cell fabrication method which produces a high yield of highly efficient Sliver cells, and which is suitable for transfer to industry; and, handling, electrically interconnecting, and encapsulating billions of sliver cells at low cost. Sliver cells with efficiencies of 20% have been fabricated at ANU using a reliable, optimised processing sequence, while low-cost encapsulation methods have been demonstrated using a submodule technique.

  4. Highly Efficient Thermoresponsive Nanocomposite for Controlled Release Applications

    Science.gov (United States)

    Yassine, Omar; Zaher, Amir; Li, Er Qiang; Alfadhel, Ahmed; Perez, Jose E.; Kavaldzhiev, Mincho; Contreras, Maria F.; Thoroddsen, Sigurdur T.; Khashab, Niveen M.; Kosel, Jurgen

    2016-06-01

    Highly efficient magnetic release from nanocomposite microparticles is shown, which are made of Poly (N-isopropylacrylamide) hydrogel with embedded iron nanowires. A simple microfluidic technique was adopted to fabricate the microparticles with a high control of the nanowire concentration and in a relatively short time compared to chemical synthesis methods. The thermoresponsive microparticles were used for the remotely triggered release of Rhodamine (B). With a magnetic field of only 1 mT and 20 kHz a drug release of 6.5% and 70% was achieved in the continuous and pulsatile modes, respectively. Those release values are similar to the ones commonly obtained using superparamagnetic beads but accomplished with a magnetic field of five orders of magnitude lower power. The high efficiency is a result of the high remanent magnetization of the nanowires, which produce a large torque when exposed to a magnetic field. This causes the nanowires to vibrate, resulting in friction losses and heating. For comparison, microparticles with superparamagnetic beads were also fabricated and tested; while those worked at 73 mT and 600 kHz, no release was observed at the low field conditions. Cytotoxicity assays showed similar and high cell viability for microparticles with nanowires and beads.

  5. Highly Efficient Thermoresponsive Nanocomposite for Controlled Release Applications

    KAUST Repository

    Yassine, Omar

    2016-06-23

    Highly efficient magnetic release from nanocomposite microparticles is shown, which are made of Poly (N-isopropylacrylamide) hydrogel with embedded iron nanowires. A simple microfluidic technique was adopted to fabricate the microparticles with a high control of the nanowire concentration and in a relatively short time compared to chemical synthesis methods. The thermoresponsive microparticles were used for the remotely triggered release of Rhodamine (B). With a magnetic field of only 1 mT and 20 kHz a drug release of 6.5% and 70% was achieved in the continuous and pulsatile modes, respectively. Those release values are similar to the ones commonly obtained using superparamagnetic beads but accomplished with a magnetic field of five orders of magnitude lower power. The high efficiency is a result of the high remanent magnetization of the nanowires, which produce a large torque when exposed to a magnetic field. This causes the nanowires to vibrate, resulting in friction losses and heating. For comparison, microparticles with superparamagnetic beads were also fabricated and tested; while those worked at 73 mT and 600 kHz, no release was observed at the low field conditions. Cytotoxicity assays showed similar and high cell viability for microparticles with nanowires and beads.

  6. Perspective: Maintaining surface-phase purity is key to efficient open air fabricated cuprous oxide solar cells

    Directory of Open Access Journals (Sweden)

    Robert L. Z. Hoye

    2015-02-01

    Full Text Available Electrochemically deposited Cu2O solar cells are receiving growing attention owing to a recent doubling in efficiency. This was enabled by the controlled chemical environment used in depositing doped ZnO layers by atomic layer deposition, which is not well suited to large-scale industrial production. While open air fabrication with atmospheric pressure spatial atomic layer deposition overcomes this limitation, we find that this approach is limited by an inability to remove the detrimental CuO layer that forms on the Cu2O surface. Herein, we propose strategies for achieving efficiencies in atmospherically processed cells that are equivalent to the high values achieved in vacuum processed cells.

  7. Fabrication and efficiency evaluation of a hybrid NiCrAl pressure cell up to 4 GPa.

    Science.gov (United States)

    Fujiwara, Naoki; Matsumoto, Takehiko; Koyama-Nakazawa, Kazuko; Hisada, Akihiko; Uwatoko, Yoshiya

    2007-07-01

    A hybrid NiCrAl pressure cell was fabricated to measure magnetic quantities under high pressure above 3 GPa. A pressure of 4.0 GPa was achieved and the pressure cell was found to be reusable even after a pressurizing trial up to 4.0 GPa. Pressure was monitored using (63)Cu nuclear quadrupole resonance of Cu(2)O and ruby fluorescence. The pressure efficiency of a fresh cell was maintained at 96%, and no appreciable deformation was observed at pressures below 3 GPa; on the other hand, the efficiency after pressurizing trials decreased gradually and reached 75% at 4 GPa accompanied by a maximum expansion inside the cylinder of 2%.

  8. Magnetic fabric and welding processes in high-grade tuffs

    Science.gov (United States)

    Pioli, L.; Ort, M.; Lanza, R.; Rosi, M.

    2003-04-01

    The welding fabric of tuffs is generally quantified through two main parameters: porosity and fiamme aspect ratio. However, these parameters are not useful for high-grade ignimbrites that display features indicating extensive rheomorphic flow, partial to complete obliteration of primary vitroclastic textures, and syn-depositional welding rather than load-related compaction. In this case, a 3D-microstructural characterization of the rock fabric is a fundamental proxy for the assessment of the dynamics and duration of welding processes. We have investigated the relations between magnetic fabric and welding textures in a rhyolitic, high-grade ignimbrite from the Sulcis volcanic District (SW Sardinia, Italy). The ignimbrite is characterized by dense welding throughout its preserved thickness and by regular lateral and vertical variations of welding, devitrification and vesiculation facies. Field and structural data indicate that syn-depositional welding and non-particulate (NP) flow were extensive and continuous during the emplacement of the ignimbrite. Paleomagnetic measurements of AMS, NRM, and AIRM of samples from the tuff indicate that the magnetic fabric is strain-sensitive and it is not significantly affected by post-depositional, static processes such as devitrification and vapor-phase alteration; in particular, magnetic susceptibility of the rock and the welding texture correlate well in terms of shape and orientation of the anisotropy ellipsoid. The direction of the K1 axis is indicative of the flow direction in the site of measurement. The anisotropy degree (P) increases with increasing welding and foliation (F) and lineation (L) are directly related to the strain facies. Onset of welding increased the degree of anisotropy and foliation; a non particulate, laminar flow stage further deformed the fabric stretching it along the flow direction and thus increasing L. The intensity of L is strictly related to the duration and the effect of simple shear (laminar

  9. Very High Efficiency Solar Cell Modules

    Energy Technology Data Exchange (ETDEWEB)

    Barnett, A.; Kirkpatrick, D.; Honsberg, C.; Moore, D.; Wanlass, M.; Emery, K.; Schwartz, R.; Carlson, D.; Bowden, S.; Aiken, D.; Gray, A.; Kurtz, S.; Kazmerski, L., et al

    2009-01-01

    The Very High Efficiency Solar Cell (VHESC) program is developing integrated optical system - PV modules for portable applications that operate at greater than 50% efficiency. We are integrating the optical design with the solar cell design, and have entered previously unoccupied design space. Our approach is driven by proven quantitative models for the solar cell design, the optical design, and the integration of these designs. Optical systems efficiency with an optical efficiency of 93% and solar cell device results under ideal dichroic splitting optics summing to 42.7 {+-} 2.5% are described.

  10. High efficiency diffraction grating for EUV lithography beamline monochromator

    Science.gov (United States)

    Voronov, D. L.; Warwick, T.; Gullikson, E. M.; Salmassi, F.; Naulleau, P.; Artemiev, N. A.; Lum, P.; Padmore, H. A.

    2016-09-01

    A blazed diffraction grating for the EUV lithography Beamline 12.0.1 of the Advanced Light Source has been fabricated using optical direct write lithography and anisotropic wet etching technology. A variable line spacing pattern was recorded on a photoresist layer and transferred to a hard mask layer of the grating substrate by a plasma etch. Then anisotropic wet etching was applied to shape triangular grating grooves with precise control of the ultralow blaze angle. Variation of the groove density along the grating length was measured with a Long Trace Profiler (LTP). Fourier analysis of the LTP data confirmed high groove placement accuracy of the grating. The grating coated with a Ru coating demonstrated diffraction efficiency of 69.6% in the negative first diffraction order which is close to theoretical efficiency at the wavelength of 13.5 nm. This work demonstrates an alternative approach to fabrication of highly efficient and precise x-ray diffraction gratings with ultra-low blaze angles.

  11. High Efficiency Low Scatter Echelle Grating Project

    Data.gov (United States)

    National Aeronautics and Space Administration — A high efficiency low scatter echelle grating will be developed using a novel technique of multiple diamond shaving cuts. The grating will have mirror surfaces on...

  12. Multi Band Gap High Efficiency Converter (RAINBOW)

    Science.gov (United States)

    Bekey, I.; Lewis, C.; Phillips, W.; Shields, V.; Stella, P.

    1997-01-01

    The RAINBOW multi band gap system represents a unique combination of solar cells, concentrators and beam splitters. RAINBOW is a flexible system which can readily expand as new high efficiency components are developed.

  13. High Efficiency Solar Furnace Core Project

    Data.gov (United States)

    National Aeronautics and Space Administration — It is proposed to develop a high efficiency solar furnace core that greatly lessens the heat losses from the furnace core, either greatly reducing the amount of...

  14. Perforated nanocap array: Facile fabrication process and efficient surface enhanced Raman scattering with fluorescence suppression

    Institute of Scientific and Technical Information of China (English)

    Wang Jun; Huang Li-Qing; Tong Hui-Min; Zhai Li-Peng; Yuan Lin; Zhao Li-Hua; Zhang Wei-Wei

    2013-01-01

    Recently,individual reduced-symmetry metal nanostructures and their plasmonic properties have been studied extensively.However,little attention has been paid to the approach to fabricating ordered reduced-symmetry metal nanostructure arrays.In this paper,a novel perforated silver nanocap array with high surface-enhanced Raman scattering (SERS) activity and fluorescence suppression is reported.The array is fabricated by electron beam evaporating Ag onto the perforated barrier layer side of a hard anodization (HA) anodic aluminum oxide (AAO) template.The morphology and optical property of the perforated silver nanocap array are characterized by an atomic force microscope (AFM),a scanning electron microscope (SEM),and absorption spectra.The results of SERS measurements reveal that the perforated silver nanocap array offers high SERS activity and fluorescence suppression compared with an imperforated silver nanocap array.

  15. Compact High Efficiency Adsorption Heat Pump

    OpenAIRE

    TeGrotenhuis, Ward E; Humble, Paul H; Sweeney, Josh B

    2012-01-01

    An innovative adsorption cycle heat pump technology is presented that is compact and capable of achieving high energy efficiency for integrated space heating, air conditioning, and water heating. High energy efficiency is accomplished by effectively recuperating heat within the system to minimize energy consumption. This substantially reduces the thermodynamic losses that occur when the sorbent beds are thermally cycled without effective heat recuperation. Furthermore, equipment cost is reduc...

  16. Efficient removal of antibiotics in a fluidized bed reactor by facile fabricated magnetic powdered activated carbon.

    Science.gov (United States)

    Ma, Jianqing; Yang, Qunfeng; Xu, Dongmei; Zeng, Xiaomei; Wen, Yuezhong; Liu, Weiping

    2017-02-01

    Powdered activated carbons (PACs) with micrometer size are showing great potential for enabling and improving technologies in water treatment. The critical problem in achieving practical application of PAC involves simple, effective fabrication of magnetic PAC and the design of a feasible reactor that can remove pollutants and recover the adsorbent efficiently. Herein, we show that such materials can be fabricated by the combination of PAC and magnetic Fe3O4 with chitosan-Fe hydrogel through a simple co-precipitation method. According to the characterization results, CS-Fe/Fe3O4/PAC with different micrometers in size exhibited excellent magnetic properties. The adsorption of tetracycline was fast and efficient, and 99.9% removal was achieved in 30 min. It also possesses good usability and stability to co-existing ions, organics, and different pH values due to its dispersive interaction nature. Finally, the prepared CS-Fe/Fe3O4/PAC also performed well in the fluidized bed reactor with electromagnetic separation function. It could be easily separated by applying a magnetic field and was effectively in situ regenerated, indicating a potential of practical application for the removal of pollutants from water.

  17. High efficiency quantum cascade laser frequency comb

    Science.gov (United States)

    Lu, Quanyong; Wu, Donghai; Slivken, Steven; Razeghi, Manijeh

    2017-03-01

    An efficient mid-infrared frequency comb source is of great interest to high speed, high resolution spectroscopy and metrology. Here we demonstrate a mid-IR quantum cascade laser frequency comb with a high power output and narrow beatnote linewidth at room temperature. The active region was designed with a strong-coupling between the injector and the upper lasing level for high internal quantum efficiency and a broadband gain. The group velocity dispersion was engineered for efficient, broadband mode-locking via four wave mixing. The comb device exhibits a narrow intermode beatnote linewidth of 50.5 Hz and a maximum wall-plug efficiency of 6.5% covering a spectral coverage of 110 cm‑1 at λ ~ 8 μm. The efficiency is improved by a factor of 6 compared with previous demonstrations. The high power efficiency and narrow beatnote linewidth will greatly expand the applications of quantum cascade laser frequency combs including high-precision remote sensing and spectroscopy.

  18. High efficiency quantum cascade laser frequency comb

    Science.gov (United States)

    Lu, Quanyong; Wu, Donghai; Slivken, Steven; Razeghi, Manijeh

    2017-01-01

    An efficient mid-infrared frequency comb source is of great interest to high speed, high resolution spectroscopy and metrology. Here we demonstrate a mid-IR quantum cascade laser frequency comb with a high power output and narrow beatnote linewidth at room temperature. The active region was designed with a strong-coupling between the injector and the upper lasing level for high internal quantum efficiency and a broadband gain. The group velocity dispersion was engineered for efficient, broadband mode-locking via four wave mixing. The comb device exhibits a narrow intermode beatnote linewidth of 50.5 Hz and a maximum wall-plug efficiency of 6.5% covering a spectral coverage of 110 cm−1 at λ ~ 8 μm. The efficiency is improved by a factor of 6 compared with previous demonstrations. The high power efficiency and narrow beatnote linewidth will greatly expand the applications of quantum cascade laser frequency combs including high-precision remote sensing and spectroscopy. PMID:28262834

  19. Fabricating high performance lithium-ion batteries using bionanotechnology

    Science.gov (United States)

    Zhang, Xudong; Hou, Yukun; He, Wen; Yang, Guihua; Cui, Jingjie; Liu, Shikun; Song, Xin; Huang, Zhen

    2015-02-01

    Designing, fabricating, and integrating nanomaterials are key to transferring nanoscale science into applicable nanotechnology. Many nanomaterials including amorphous and crystal structures are synthesized via biomineralization in biological systems. Amongst various techniques, bionanotechnology is an effective strategy to manufacture a variety of sophisticated inorganic nanomaterials with precise control over their chemical composition, crystal structure, and shape by means of genetic engineering and natural bioassemblies. This provides opportunities to use renewable natural resources to develop high performance lithium-ion batteries (LIBs). For LIBs, reducing the sizes and dimensions of electrode materials can boost Li+ ion and electron transfer in nanostructured electrodes. Recently, bionanotechnology has attracted great interest as a novel tool and approach, and a number of renewable biotemplate-based nanomaterials have been fabricated and used in LIBs. In this article, recent advances and mechanism studies in using bionanotechnology for high performance LIBs studies are thoroughly reviewed, covering two technical routes: (1) Designing and synthesizing composite cathodes, e.g. LiFePO4/C, Li3V2(PO4)3/C and LiMn2O4/C; and (2) designing and synthesizing composite anodes, e.g. NiO/C, Co3O4/C, MnO/C, α-Fe2O3 and nano-Si. This review will hopefully stimulate more extensive and insightful studies on using bionanotechnology for developing high-performance LIBs.

  20. High refractive index Fresnel lens on a fiber fabricated by nanoimprint lithography for immersion applications

    CERN Document Server

    Koshelev, Alexander; Piña-Hernandez, Carlos; Allen, Frances; Dhuey, Scott; Sassolini, Simone; Wong, Edward; Lum, Paul; Munechika, Keiko; Cabrini, Stefano

    2016-01-01

    In this Letter we present a Fresnel lens fabricated on the end of an optical fiber. The lens is fabricated using nanoimprint lithography of a functional high refractive index material, which is suitable for mass production. The main advantage of the presented Fresnel lens compared to a conventional fiber lens is its high refractive index (n=1.69), which enables efficient light focusing even inside other media such as water or adhesive. Measurement of the lens performance in an immersion liquid (n=1.51) shows a near diffraction limited focal spot of 810 nm in diameter at the 1/e2 intensity level for a wavelength of 660 nm. Applications of such fiber lenses include integrated optics, optical trapping and fiber probes.

  1. High refractive index Fresnel lens on a fiber fabricated by nanoimprint lithography for immersion applications.

    Science.gov (United States)

    Koshelev, Alexander; Calafiore, Giuseppe; Piña-Hernandez, Carlos; Allen, Frances I; Dhuey, Scott; Sassolini, Simone; Wong, Edward; Lum, Paul; Munechika, Keiko; Cabrini, Stefano

    2016-08-01

    In this Letter, we present a Fresnel lens fabricated on the end of an optical fiber. The lens is fabricated using nanoimprint lithography of a functional high refractive index material, which is suitable for mass production. The main advantage of the presented Fresnel lens compared to a conventional fiber lens is its high refractive index (n=1.68), which enables efficient light focusing even inside other media, such as water or an adhesive. Measurement of the lens performance in an immersion liquid (n=1.51) shows a near diffraction limited focal spot of 810 nm in diameter at the 1/e2 intensity level for a wavelength of 660 nm. Applications of such fiber lenses include integrated optics, optical trapping, and fiber probes.

  2. A metamaterial electromagnetic energy rectifying surface with high harvesting efficiency

    Science.gov (United States)

    Duan, Xin; Chen, Xing; Zhou, Lin

    2016-12-01

    A novel metamaterial rectifying surface (MRS) for electromagnetic energy capture and rectification with high harvesting efficiency is presented. It is fabricated on a three-layer printed circuit board, which comprises an array of periodic metamaterial particles in the shape of mirrored split rings, a metal ground, and integrated rectifiers employing Schottky diodes. Perfect impedance matching is engineered at two interfaces, i.e. one between free space and the surface, and the other between the metamaterial particles and the rectifiers, which are connected through optimally positioned vias. Therefore, the incident electromagnetic power is captured with almost no reflection by the metamaterial particles, then channeled maximally to the rectifiers, and finally converted to direct current efficiently. Moreover, the rectifiers are behind the metal ground, avoiding the disturbance of high power incident electromagnetic waves. Such a MRS working at 2.45 GHz is designed, manufactured and measured, achieving a harvesting efficiency up to 66.9% under an incident power density of 5 mW/cm2, compared with a simulated efficiency of 72.9%. This high harvesting efficiency makes the proposed MRS an effective receiving device in practical microwave power transmission applications.

  3. An easily fabricated high performance ionic polymer based sensor network

    Science.gov (United States)

    Zhu, Zicai; Wang, Yanjie; Hu, Xiaopin; Sun, Xiaofei; Chang, Longfei; Lu, Pin

    2016-08-01

    Ionic polymer materials can generate an electrical potential from ion migration under an external force. For traditional ionic polymer metal composite sensors, the output voltage is very small (a few millivolts), and the fabrication process is complex and time-consuming. This letter presents an ionic polymer based network of pressure sensors which is easily and quickly constructed, and which can generate high voltage. A 3 × 3 sensor array was prepared by casting Nafion solution directly over copper wires. Under applied pressure, two different levels of voltage response were observed among the nine nodes in the array. For the group producing the higher level, peak voltages reached as high as 25 mV. Computational stress analysis revealed the physical origin of the different responses. High voltages resulting from the stress concentration and asymmetric structure can be further utilized to modify subsequent designs to improve the performance of similar sensors.

  4. Fabrication of very high density fuel pellets of thorium dioxide

    Science.gov (United States)

    Shiratori, Tetsuo; Fukuda, Kosaku

    1993-06-01

    Very high density ThO 2 pellets were prepared without binders and lubricants from the ThO 2 powder originated by the thorium oxalate, which was aimed to simplify the fabrication process by skipping a preheat treatment. The as-received ThO 2 powder with a surface area of 4.56 m 2/g was ball-milled up to about 9 m 2/g in order to increase the green pellet density as high as possible. Both of the single-sided and the double-sided pressing were tested in the range from 2 to 5 t/cm 2 in the green pellet formation. Sintering temperature was such low as 1550°C. The pellet prepared in this experiment had a very high density in the range from about 96 to 98% TD without any cracks, in which a difference of the pellet density was not recognized in the single-sided pressing methods.

  5. Diamond turning of high-precision roll-to-roll imprinting molds for fabricating subwavelength gratings

    Science.gov (United States)

    Liu, Chun-Wei; Yan, Jiwang; Lin, Shih-Chieh

    2016-06-01

    Diamond turning of high-precision molds is a vital process for the roll-to-roll-based ultraviolet resin imprinting process in fabricating subwavelength gratings. The effects of the grating shape and grating period on diffraction efficiencies and diffraction angles were simulated. Experiments were then conducted to examine the effects of shape design, grating period, and cutting speed on machinability of the mold. According to the optical measurement results, the performance of the subwavelength gratings matched the design well at various incident angles. The results confirm that diamond turning of high-precision molds is a feasible approach for ensuring the continual mass production of subwavelength gratings.

  6. Crystalline, highly oriented MOF thin film: the fabrication and application.

    Science.gov (United States)

    Fu, Zhihua; Xu, Gang

    2016-10-24

    The thin film of metal-organic frameworks (MOFs) is a rapidly developing research area which has tremendous potential applications in many fields. One of the major challenges in this area is to fabricate MOF thin film with good crystallinity, high orientation and well-controlled thickness. In order to address this challenge, different appealing approaches have been studied intensively. Among various oriented MOF films, many efforts have also been devoted to developing novel properties and broad applications, such as in gas separator, thermoelectric, storage medium and photovoltaics. As a result, there has been a large demand for fundamental studies that can provide guidance and experimental data for further applications. In this account, we intend to present an overview of current synthetic methods for fabricating oriented crystalline MOF thin film and bring some updated applications. We give our perspective on the background, preparation and applications that led to the developments in this area and discuss the opportunities and challenges of using crystalline, highly oriented MOF thin film.

  7. Low-cost high-efficient 10-Watt X-band high-power amplifier

    NARCIS (Netherlands)

    Bent, G. van der; Hek, A.P. de; Bessemoulin, A.; Vliet, F.E. van

    2009-01-01

    A high power X-band amplifier with an output power over 10 Watts and a Power Added Efficiency (PAE) in excess of 40 percent has been developed. The design was fabricated in a 0.25 μm pHEMT GaAs process (WIN Semiconductor PP25-01). The small die area in combination with a 6-inch wafer technology prov

  8. Non-iridescent Transmissive Structural Color Filter Featuring Highly Efficient Transmission and High Excitation Purity

    OpenAIRE

    2014-01-01

    Nanostructure based color filtering has been considered an attractive replacement for current colorant pigmentation in the display technologies, in view of its increased efficiencies, ease of fabrication and eco-friendliness. For such structural filtering, iridescence relevant to its angular dependency, which poses a detrimental barrier to the practical development of high performance display and sensing devices, should be mitigated. We report on a non-iridescent transmissive structural color...

  9. Rapid fabrication of a poly(dimethylsiloxane) microfluidic capillary gel electrophoresis system utilizing high precision machining.

    Science.gov (United States)

    Zhao, Dong S; Roy, Binayak; McCormick, Matthew T; Kuhr, Werner G; Brazill, Sara A

    2003-05-01

    In this work, we demonstrate a rapid protocol to address one of the major barriers that exists in the fabrication of chip devices, creating the micron-sized structures in the substrate material. This approach makes it possible to design, produce, and fabricate a microfluidic system with channel features >10 microm in poly(dimethylsiloxane)(PDMS) in under 8 hours utilizing instrumentation common to most machine shops. The procedure involves the creation of a master template with negative features, using high precision machining. This master is then employed to create an acrylic mold that is used in the final fabrication step to cast channel structures into the PDMS substrate. The performance of the microfluidic system prepared using this fabrication procedure is evaluated by constructing a miniaturized capillary gel electrophoresis (micro-CGE) system for the analysis of DNA fragments. Agarose is utilized as the sieving medium in the micro-CGE device and is shown to give reproducible (RSD (n= 34) approximately 5.0%) results for about 34 individual separations without replenishing the gel. To demonstrate the functionality of the micro-CGE device, a DNA restriction ladder (spanning 26-700 base pairs) and DNA fragments generated by PCR are separated and detected with laser-induced fluorescence (LIF). The microchip is shown to achieve a separation efficiency of 2.53 x 10(5) plates m(-1).

  10. High Efficiency ELID Grinding of Garnet Ferrite

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    Hard and brittle materials such as ferrite, optical glass and ceramics have been widely used in many fields because of their good characteristics and still gain more attentions. However, it is difficult to machine and get good surface quality. Some parts made of these materials have large machining allowances and need to be produced with large batch, but the machining efficiency is very low with usual grinding method. So it is of great importance to research the high efficiency grinding technology of hard ...

  11. Fabrication of highly conductive carbon nanotube fibers for electrical application

    Science.gov (United States)

    Guo, Fengmei; Li, Can; Wei, Jinquan; Xu, Ruiqiao; Zhang, Zelin; Cui, Xian; Wang, Kunlin; Wu, Dehai

    2015-09-01

    Carbon nanotubes (CNTs) have great potential for use as electrical wires because of their outstanding electrical and mechanical properties. Here, we fabricate lightweight CNT fibers with electrical conductivity as high as that of stainless steel from macroscopic CNT films by drawing them through diamond wire-drawing dies. The entangled CNT bundles are straightened by suffering tension, which improves the alignment of the fibers. The loose fibers are squeezed by the diamond wire-drawing dies, which reduces the intertube space and contact resistance. The CNT fibers prepared by drawing have an electrical conductivity as high as 1.6 × 106 s m-1. The fibers are very stable when kept in the air and under cyclic tensile test. A prototype of CNT motor is demonstrated by replacing the copper wires with the CNT fibers.

  12. Research on Properties of Woven Fabrics Treated by High Pressure Water Jet

    Institute of Scientific and Technical Information of China (English)

    黄故

    2001-01-01

    The paper introduces a new technique for the treatment of the woven fabrics. Sprayed by high pressure water jet, the appearance, handle and stiffness of the fabric are improved. Other properties of the high pressure water treated fabrics like drape coefficient, air permeability, tenacity are also presented.

  13. Advances in CO2 laser fabrication for high power fibre laser devices

    Science.gov (United States)

    Boyd, Keiron; Rees, Simon; Simakov, Nikita; Daniel, Jae M. O.; Swain, Robert; Mies, Eric; Hemming, Alexander; Clarkson, W. A.; Haub, John

    2016-03-01

    CO2 laser processing facilitates contamination free, rapid, precise and reproducible fabrication of devices for high power fibre laser applications. We present recent progress in fibre end-face preparation and cladding surface modification techniques. We demonstrate a fine feature CO2 laser process that yields topography significantly smaller than that achieved with typical mechanical cleaving processes. We also investigate the side processing of optical fibres for the fabrication of all-glass cladding light strippers and demonstrate extremely efficient cladding mode removal. We apply both techniques to fibres with complex designs containing multiple layers of doped and un-doped silica as well as shaped and circularly symmetric structures. Finally, we discuss the challenges and approaches to working with various fibre and glass-types.

  14. Fabricating centimeter-scale high quality factor two-dimensional periodic photonic crystal slabs.

    Science.gov (United States)

    Lee, Jeongwon; Zhen, Bo; Chua, Song-Liang; Shapira, Ofer; Soljačić, Marin

    2014-02-10

    We present a fabrication route for centimeter-scale two-dimensional defect-free photonic crystal slabs with quality factors bigger than 10,000 in the visible, together with a unique way to quantify their quality factors. We fabricate Si(3)N(4) photonic crystal slabs, and perform an angle-resolved reflection measurement. This measurement data is used to retrieve the quality factors of the slabs by fitting it to a model based on temporal coupled-mode theory. The macroscopic nature of the structure and the high quality factors of their resonances could open up new opportunities for realizing efficient macroscale optoelectronic devices such as sensors, lasers, and energy harvesting systems.

  15. Photovoltaics. Interface engineering of highly efficient perovskite solar cells.

    Science.gov (United States)

    Zhou, Huanping; Chen, Qi; Li, Gang; Luo, Song; Song, Tze-bing; Duan, Hsin-Sheng; Hong, Ziruo; You, Jingbi; Liu, Yongsheng; Yang, Yang

    2014-08-01

    Advancing perovskite solar cell technologies toward their theoretical power conversion efficiency (PCE) requires delicate control over the carrier dynamics throughout the entire device. By controlling the formation of the perovskite layer and careful choices of other materials, we suppressed carrier recombination in the absorber, facilitated carrier injection into the carrier transport layers, and maintained good carrier extraction at the electrodes. When measured via reverse bias scan, cell PCE is typically boosted to 16.6% on average, with the highest efficiency of ~19.3% in a planar geometry without antireflective coating. The fabrication of our perovskite solar cells was conducted in air and from solution at low temperatures, which should simplify manufacturing of large-area perovskite devices that are inexpensive and perform at high levels.

  16. High Efficiency of Dye-Sensitized Solar Cells

    Institute of Scientific and Technical Information of China (English)

    Liyuan Han

    2005-01-01

    @@ 1Introduction Much attention has been paid to the development of dye-sensitized solar cells (DSCs) during the past decade. In general, a DSC comprises a nanocrystalline titanium dioxide (TiO2) electrode modified with a dye fabricated on a transparent conducting oxide (TCO), a platinum (Pt) counter electrode, and an electrolyte solution with a dissolved iodide ion/tri-iodide ion redox couple between the electrodes. Although a DSC using black dye with high efficiency of 10.4%, which was measured by NREL(U. S. A. ), was reported by Graetzel et al. [1], the efficiency of DSCs should be further improved for practical use in comparison with silicon solar cells.

  17. Technology Development for High Efficiency Optical Communications

    Science.gov (United States)

    Farr, William H.

    2012-01-01

    Deep space optical communications is a significantly more challenging operational domain than near Earth space optical communications, primarily due to effects resulting from the vastly increased range between transmitter and receiver. The NASA Game Changing Development Program Deep Space Optical Communications Project is developing four key technologies for the implementation of a high efficiency telecommunications system that will enable greater than 10X the data rate of a state-of-the-art deep space RF system (Ka-band) for similar transceiver mass and power burden on the spacecraft. These technologies are a low mass spacecraft disturbance isolation assembly, a flight qualified photon counting detector array, a high efficiency flight laser amplifier and a high efficiency photon counting detector array for the ground-based receiver.

  18. High Efficiency LED Lamp for Solid-State Lighting

    Energy Technology Data Exchange (ETDEWEB)

    James Ibbetson

    2006-12-31

    This report contains a summary of technical achievements during a three-year project to demonstrate high efficiency, solid-state lamps based on gallium nitride/silicon carbide light-emitting diodes. Novel chip designs and fabrication processes are described for a new type of nitride light-emitting diode with the potential for very high efficiency. This work resulted in the demonstration of blue light-emitting diodes in the one watt class that achieved up to 495 mW of light output at 350 mA drive current, corresponding to quantum and wall plug efficiencies of 51% and 45%, respectively. When combined with a phosphor in Cree's 7090 XLamp package, these advanced blue-emitting devices resulted in white light-emitting diodes whose efficacy exceeded 85 lumens per watt. In addition, up to 1040 lumens at greater than 85 lumens per watt was achieved by combining multiple devices to make a compact white lamp module with high optical efficiency.

  19. Ultrasonic effect on the desizing efficiency of α-amylase on starch-sized cotton fabrics.

    Science.gov (United States)

    Hao, Longyun; Wang, Rui; Fang, Kuanjun; Liu, Jingquan

    2013-07-25

    Enzymatic desizing by α-amylase and ultrasound irradiation are the two important clean technologies in the textile industry. In the present work, with the aim of giving a further insight to the influence of ultrasound on α-amylase activity and its desizing efficiency, the ultrasound-based experiments were afforded in two ways: (i) step-wise treatment of α-amylase by ultrasound and then enzymatic desizing, as well as; (ii) simultaneous utilization of ultrasound and α-amylase for the desizing. By the step-wise strategy, it is found that the ultrasound has negative impact on the α-amylase activity using soluble starch as substrate. However, the sonicated α-amylase possesses higher desizing efficiency because there are higher hydrophobic interactions between sonicated α-amylase protein and starch-sized cotton and thus intensifies its catalytic activity. By the simultaneous procedure, the enhancement to desizing efficiency is more pronounced than that by the step-wise procedure. This can be attributed to comprehensive actions of several reasons such as more effective stirring/mixing mechanism, damages or changes to substrate, more effective catalysis to hydrolytic reactions and faster removal of loosened products from the fabric bulk.

  20. High-aspect-ratio photoresist processing for fabrication of high resolution and thick micro-windings

    Science.gov (United States)

    Anthony, Ricky; Laforge, Elias; Casey, Declan P.; Rohan, James F.; O'Mathuna, Cian

    2016-10-01

    DC winding losses remain a major roadblock in realizing high efficiency micro-magnetic components (inductors/transformers). This paper reports an optimized photoresist process using negative tone and acrylic based THB-151N (from JSR Micro), to achieve one of the highest aspect ratio (17:1) and resolution (~5 µm) resist patterns for fabrication of thick (~80 µm) micro-winding using UV lithography. The process was optimized to achieve photoresist widths from 5 µm to 20 µm with resist thickness of ~85 µm in a single spin step. Unlike SU-8, this resist can be readily removed and shows a near-vertical (~91°) electroplated Cu side-wall profile. Moreover, the high resolution compared to available resist processes enables a further reduction in the footprint area and can potentially increase the number of winding thereby increasing the inductance density for micro-magnetic components. Resistance measurements of electroplated copper winding of air-core micro-inductors within the standard 0402 size (0.45 mm2 footprint area) suggested a 42% decrease in resistance (273 mΩ-159 mΩ) with the increase in electroplated Cu thickness (from 50 µm to 80 µm). Reduction of the spacings (from 10 µm to 5 µm) enabled further miniaturisation of the device footprint area (from 0.60 mm2 to 0.45 mm2) without significant increase in resistance.

  1. Perovskite solar cells with 18.21% efficiency and area over 1 cm2 fabricated by heterojunction engineering

    Science.gov (United States)

    Wu, Yongzhen; Yang, Xudong; Chen, Wei; Yue, Youfeng; Cai, Molang; Xie, Fengxian; Bi, Enbing; Islam, Ashraful; Han, Liyuan

    2016-11-01

    Perovskite solar cells (PSCs) are promising low-cost photovoltaic technologies with high solar-to-electric power conversion efficiency (PCE). The heterojunction structure between perovskite and charge extraction layers is crucial to the photovoltaic performance of PSCs. Here, we report efficient inverted-structured PSCs with a perovskite-fullerene graded heterojunction (GHJ), in which the electron-accepting material is distributed in the perovskite layer with a gradient. This structure can enhance the PCE as it improves the photoelectron collection and reduces recombination loss, especially for the formamidinium cation-based perovskite. The conformal fullerene coating on perovskite during the GHJ deposition achieves a full coverage with reduced layer thickness, thus minimizing the resistive loss in larger sized devices. Our strategy enables the fabrication of centimetre-scale PSCs showing high efficiency with small hysteresis and good stability. A PCE of 18.21% was certified by an independent institution for cells with an aperture area of 1.022 cm2.

  2. Measure Guideline: High Efficiency Natural Gas Furnaces

    Energy Technology Data Exchange (ETDEWEB)

    Brand, L.; Rose, W.

    2012-10-01

    This Measure Guideline covers installation of high-efficiency gas furnaces. Topics covered include when to install a high-efficiency gas furnace as a retrofit measure, how to identify and address risks, and the steps to be used in the selection and installation process. The guideline is written for Building America practitioners and HVAC contractors and installers. It includes a compilation of information provided by manufacturers, researchers, and the Department of Energy as well as recent research results from the Partnership for Advanced Residential Retrofit (PARR) Building America team.

  3. Highly efficient heralding of entangled single photons.

    Science.gov (United States)

    Ramelow, Sven; Mech, Alexandra; Giustina, Marissa; Gröblacher, Simon; Wieczorek, Witlef; Beyer, Jörn; Lita, Adriana; Calkins, Brice; Gerrits, Thomas; Nam, Sae Woo; Zeilinger, Anton; Ursin, Rupert

    2013-03-25

    Single photons are an important prerequisite for a broad spectrum of quantum optical applications. We experimentally demonstrate a heralded single-photon source based on spontaneous parametric down-conversion in collinear bulk optics, and fiber-coupled bolometric transition-edge sensors. Without correcting for background, losses, or detection inefficiencies, we measure an overall heralding efficiency of 83%. By violating a Bell inequality, we confirm the single-photon character and high-quality entanglement of our heralded single photons which, in combination with the high heralding efficiency, are a necessary ingredient for advanced quantum communication protocols such as one-sided device-independent quantum key distribution.

  4. Measure Guideline. High Efficiency Natural Gas Furnaces

    Energy Technology Data Exchange (ETDEWEB)

    Brand, L. [Partnership for Advanced Residential Retrofit (PARR), Des Plaines, IL (United States); Rose, W. [Partnership for Advanced Residential Retrofit (PARR), Des Plaines, IL (United States)

    2012-10-01

    This measure guideline covers installation of high-efficiency gas furnaces, including: when to install a high-efficiency gas furnace as a retrofit measure; how to identify and address risks; and the steps to be used in the selection and installation process. The guideline is written for Building America practitioners and HVAC contractors and installers. It includes a compilation of information provided by manufacturers, researchers, and the Department of Energy as well as recent research results from the Partnership for Advanced Residential Retrofit (PARR) Building America team.

  5. PRCA:A highly efficient computing architecture

    Institute of Scientific and Technical Information of China (English)

    Luo Xingguo

    2014-01-01

    Applications can only reach 8 %~15 % of utilization on modern computer systems. There are many obstacles to improving system efficiency. The key root is the conflict between the fixed general computer architecture and the variable requirements of applications. Proactive reconfigurable computing architecture (PRCA) is proposed to improve computing efficiency. PRCA dynamically constructs an efficient computing ar chitecture for a specific application via reconfigurable technology by perceiving requirements,workload and utilization of computing resources. Proactive decision support system (PDSS),hybrid reconfigurable computing array (HRCA) and reconfigurable interconnect (RIC) are intensively researched as the key technologies. The principles of PRCA have been verified with four applications on a test bed. It is shown that PRCA is feasible and highly efficient.

  6. Deep-blue efficient OLED based on NPB with little efficiency roll-off under high current density

    Science.gov (United States)

    Liu, Jian

    2017-03-01

    NPB usually is used as a hole-transport layer in OLED. In fact, it is a standard pure blue-emission material. However, its light-emitting efficiency in OLED is low due to emissive nature of organic material. Herein, a deep-blue OLDE based on NPB was fabricated. The light-emitting efficiency of the device demonstrates a moderate value, and efficiency roll-off is little under high current density. The device demonstrates that the electroplex's emission decreases with increasing electric field intensity.

  7. High-efficiency silicon heterojunction solar cells: Status and perspectives

    Energy Technology Data Exchange (ETDEWEB)

    De Wolf, S.; Geissbuehler, J.; Loper, P.; Martin de Nicholas, S.; Seif, J.; Tomasi, A.; Ballif, C.

    2015-05-11

    Silicon heterojunction technology (HJT) uses silicon thin-film deposition techniques to fabricate photovoltaic devices from mono-crystalline silicon wafers (c-Si). This enables energy-conversion efficiencies above 21 %, also at industrial-production level. In this presentation we review the present status of this technology and point out recent trends. We first discuss how the properties of thin hydrogenated amorphous silicon (a-Si:H) films can be exploited to fabricate passivating contacts, which is the key to high- efficiency HJT solar cells. Such contacts enable very high operating voltages, approaching the theoretical limits, and yield small temperature coefficients. With this approach, an increasing number of groups are reporting devices with conversion efficiencies well over 20 % on both-sides contacted n-type cells, Panasonic leading the field with 24.7 %. Exciting results have also been obtained on p-type wafers. Despite these high voltages, important efficiency gains can still be made in fill factor and optical design. This requires improved understanding of carrier transport across device interfaces and reduced parasitic absorption in HJT solar cells. For the latter, several strategies can be followed: Short-wavelength losses can be reduced by replacing the front a-Si:H films with wider-bandgap window layers, such as silicon alloys or even metal oxides. Long- wavelength losses are mitigated by introducing new high-mobility TCO’s such as hydrogenated indium oxide, and also by designing new rear reflectors. Optical shadow losses caused by the front metallization grid are significantly reduced by replacing printed silver electrodes with fine-line plated copper contacts, leading also to possible cost advantages. The ultimate approach to minimize optical losses is the implementation of back-contacted architectures, which are completely devoid of grid shadow losses and parasitic absorption in the front layers can be minimized irrespective of electrical

  8. High-efficiency silicon heterojunction solar cells: Status and perspectives

    Energy Technology Data Exchange (ETDEWEB)

    De Wolf, S.

    2015-04-27

    Silicon heterojunction technology (HJT) uses silicon thin-film deposition techniques to fabricate photovoltaic devices from mono-crystalline silicon wafers (c-Si). This enables energy-conversion efficiencies above 21 %, also at industrial-production level. In this presentation we review the present status of this technology and point out recent trends. We first discuss how the properties of thin hydrogenated amorphous silicon (a-Si:H) films can be exploited to fabricate passivating contacts, which is the key to high- efficiency HJT solar cells. Such contacts enable very high operating voltages, approaching the theoretical limits, and yield small temperature coefficients. With this approach, an increasing number of groups are reporting devices with conversion efficiencies well over 20 % on n-type wafers, Panasonic leading the field with 24.7 %. Exciting results have also been obtained on p-type wafers. Despite these high voltages, important efficiency gains can still be made in fill factor and optical design. This requires improved understanding of carrier transport across device interfaces and reduced parasitic absorption in HJT solar cells. For the latter, several strategies can be followed: Short- wavelength losses can be reduced by replacing the front a-Si:H films with wider-bandgap window layers, such as silicon alloys or even metal oxides. Long-wavelength losses are mitigated by introducing new high-mobility TCO’s such as hydrogenated indium oxide, and also by designing new rear reflectors. Optical shadow losses caused by the front metalisation grid are significantly reduced by replacing printed silver electrodes with fine-line plated copper contacts, leading also to possible cost advantages. The ultimate approach to minimize optical losses is the implementation of back-contacted architectures, which are completely devoid of grid shadow losses and parasitic absorption in the front layers can be minimized irrespective of electrical transport requirements. The

  9. Controlled fabrication of individual silicon quantum rods yielding high intensity, polarized light emission

    Science.gov (United States)

    Bruhn, Benjamin; Valenta, Jan; Linnros, Jan

    2009-12-01

    Elongated silicon quantum dots (also referred to as rods) were fabricated using a lithographic process which reliably yields sufficient numbers of emitters. These quantum rods are perfectly aligned and the vast majority are spatially separated well enough to enable single-dot spectroscopy. Not only do they exhibit extraordinarily high linear polarization with respect to both absorption and emission, but the silicon rods also appear to luminesce much more brightly than their spherical counterparts. Significantly increased quantum efficiency and almost unity degree of linear polarization render these quantum rods perfect candidates for numerous applications.

  10. Highly efficient fiber-to-chip evanescent coupling based on subwavelength-diameter optical fibers

    Institute of Scientific and Technical Information of China (English)

    Xiaowei Shen; Xinwan Li; Lijie Zhou; Zehua Hong; Xiaocao Yu; Ying Zhang; Jianping Chen

    2011-01-01

    @@ A novel, compact, and highly efficient fiber-to-chip evanescent coupling structure is proposed based on a subwavelength-diameter fiber.The coupling structure is characterized by a large misalignment tolerance and easy fabrication.The dependence of coupling efficiency on various parameters is calculated and analyzed.%A novel, compact, and highly efficient fiber-to-chip evanescent coupling structure is proposed based on a subwavelength-diameter fiber. The coupling structure is characterized by a large misalignment tolerance and easy fabrication. The dependence of coupling efficiency on various parameters is calculated and analyzed. The simulation results show that a coupling efficiency as high as 95% can be obtained within a coupling length of <4 μm.

  11. Highly Efficient Excitation of Surface Plasmons Using a Si Gable Tip

    CERN Document Server

    Dewanjee, Arnab; Aitchison, J Stewart; Mojahedi, Mo

    2016-01-01

    We propose a novel technique to efficiently excite a surface plasmon polariton (SPP) mode at a gold-glass interface by using an engineered high index (silicon) gabled tip at the telecom wavelengths. The proposed structure can theoretically convert 49% of the input optical power to a SPP mode. Also we experimentally validate the effective high efficiency coupling by the gabled tip. The device is compact, it will facilitate the on-chip excitation of the SPP, its fabrication is compatible with the standard Si fabrication processes, and as such, it is expected to be useful in the design of future integrated sensors.

  12. Fundamental understanding and development of low-cost, high-efficiency silicon solar cells

    Energy Technology Data Exchange (ETDEWEB)

    ROHATGI,A.; NARASIMHA,S.; MOSCHER,J.; EBONG,A.; KAMRA,S.; KRYGOWSKI,T.; DOSHI,P.; RISTOW,A.; YELUNDUR,V.; RUBY,DOUGLAS S.

    2000-05-01

    The overall objectives of this program are (1) to develop rapid and low-cost processes for manufacturing that can improve yield, throughput, and performance of silicon photovoltaic devices, (2) to design and fabricate high-efficiency solar cells on promising low-cost materials, and (3) to improve the fundamental understanding of advanced photovoltaic devices. Several rapid and potentially low-cost technologies are described in this report that were developed and applied toward the fabrication of high-efficiency silicon solar cells.

  13. Highly efficient, gearless drive; Hocheffizienter, getriebeloser Antrieb

    Energy Technology Data Exchange (ETDEWEB)

    Niederer, R.

    2004-07-01

    Highly efficient, gearless variable-speed drive systems for low-speed applications have been developed. These systems consist of an inverter with active switches (IGBTs, MOSFETs, resp.) and a synchronous machine excited with permanent magnets. Therefore, these systems can be used for drive as well as for generator applications. They operate very efficiently since a gearbox is obsolete, furthermore weight, dimensions, noise and maintenance can be reduced. The inverter controllers do not require any speed sensors, thus reliability is increased and costs are decreased. Application for low-speed variable-speed drive systems can be found in industrial applications, cable railways or wind turbines. Both systems have been optimized in several iterative loops, in what regards overall efficiency and material expenditure. For both systems, prototypes have been developed and tested. Both prototypes performed reliably and fulfilled the expectations. The high power system (1200 kW, 20 rpm) operated at rated load with an overall efficiency of 93.1%, the lower power system (3 kW, 60 rpm) with an overall efficiency of 85%. Thus the losses of these new systems are at rated load about 4% lower compared to conventional drive systems equipped with a mechanical gearbox. (author)

  14. Fabrication of high fidelity, high index three-dimensional photonic crystals using a templating approach

    Science.gov (United States)

    Xu, Yongan

    In this dissertation, we demonstrate the fabrication of high fidelity 3D photonic crystal through polymer template fabrication, backfilling and template removal to obtain high index inversed inorganic photonic crystals (PCs). Along the line, we study the photoresist chemistry to minimize the shrinkage, backfilling strategies for complete infiltration, and template removal at high and low temperatures to minimize crack-formation. Using multibeam interference lithography (MBIL), we fabricate diamond-like photonic structures from commercially available photoresist, SU-8, epoxy functionalized polyhedral oligomeric silsesquioxane (POSS), and narrowly distributed poly(glycidyl methacrylate)s (PGMA). The 3D structure from PGMA shows the lowest shrinkage in the [111] direction, 18%, compared to those fabricated from the SU-8 (41%) and POSS (48%) materials under the same conditions. To fabricate a photonic crystal with large and complete photonic bandgap, it often requires backfilling of high index inorganic materials into a 3D polymer template. We have studied different backfilling methods to create three different types of high index, inorganic 3D photonic crystals. Using SU-8 structures as templates, we systematically study the electrodeposition technique to create inversed 3D titania crystals. We find that 3D SU-8 template is completely infiltrated with titania sol-gel through a two-stage process: a conformal coating of a thin layer of films occurs at the early electrodeposition stage (simulated photonic bandgaps (PBGs) and the SEM observation, further supporting the complete filling by the wet chemistry. Since both PGMA and SU-8 decompose at a temperature above 400°C, leading to the formation of defects and cracks, a highly thermal and mechanical stable template is desired for PC fabrication. We fabricate the 3D POSS structures by MBIL, which can be converted to crack-free silica-like templates over the entire sample area (˜5 mm in diameter) by either thermal

  15. InP Gunn Diodes with Current Limiting Contact for High Efficiency Gunn Oscillators

    Science.gov (United States)

    Kim, Mi-Ra; Rhee, Jin-Koo; Lee, Chang-Woo; Chae, Yeon-Sik; Choi, Jae-Hyun; Kim, Wan-Joo

    We fabricated and examined current limiting effect for InP Gunn diodes with stable depletion layer mode operation of diodes for high efficiency Gunn oscillators. Current limiting at the cathode was achieved by a shallow Schottky barrier at the interface. We discussed fabrication procedure, the results for negative differential resistance and rf tests for InP Gunn diodes. It was shown that the fabricated Gunn diodes have the output power of 10.22dBm at a frequency of 90.13GHz. Its input voltage and corresponding current were 8.55V and 252mA, respectively.

  16. Fabrication of nanowire arrays over micropyramids for efficient Si solar cell

    Science.gov (United States)

    Pant, Namrata; Singh, Prashant; Srivastava, Sanjay Kumar; Shukla, Vivek Kumar

    2016-05-01

    To improve the efficiency of solar cell, trapping the sunlight and using it to its maximum limit has been the area of research for past several decades. In the present work, texturisation of silicon surface has been done to make nanowire arrays over micropyramids. Micropyramids on Si surface increases the surface area, reduce the reflectivity and hence help to enhance the solar cell performance. Additionally, with the aim to further reduce the reflectance of Si surface, nanowire arrays over micro pyramids were fabricated. For this, samples with variation in their nanotexturisation time (etching time) were prepared. Measurements like SEM and UV-Vis reflectance spectroscopy were performed on the samples to investigate the changes with etching time. It was observed that the reflectance of planar Si in the spectral range 400 to 1000 nm is ˜35%. The reflectance of microtextured (micropyramid) Si surface is significantly reduced to ˜11%. A further decrease in reflectivity was observed when nanowire arrays were grown over the micropyramids. This may be attributed to the effective light trapping caused by multiple scattering of the incident light from the nanowires over micropyramids. Hence, it may improve silicon solar cell efficiency.

  17. Highly efficient charged particle veto detector CUP

    Energy Technology Data Exchange (ETDEWEB)

    Palacz, M. [Heavy Ion Laboratory, Warsaw University, ul. Pasteura 5A, PL 02-093 Warsaw (Poland)]. E-mail: palacz@slcj.uw.edu.pl; Nyberg, J. [Department of Radiation Sciences, Uppsala University, Uppsala (Sweden); Bednarczyk, P. [Institute de Recherches Subatomiques, Strasbourg (France); Henryk Niewodniczanski Institute of Nuclear Physics, Polish Academy of Sciences, Cracow (Poland); Dworski, J. [Heavy Ion Laboratory, Warsaw University, ul. Pasteura 5A, PL 02-093 Warsaw (Poland); Gorska, M. [Gesellschaft fuer Schwerionenforschung, Darmstadt (Germany); Iwanicki, J. [Heavy Ion Laboratory, Warsaw University, ul. Pasteura 5A, PL 02-093 Warsaw (Poland); Kapusta, M. [Soltan Institute for Nuclear Studies, Swierk (Poland); Kownacki, J. [Heavy Ion Laboratory, Warsaw University, ul. Pasteura 5A, PL 02-093 Warsaw (Poland); Kulczycka, E. [Heavy Ion Laboratory, Warsaw University, ul. Pasteura 5A, PL 02-093 Warsaw (Poland); Lagergren, K. [Royal Institute of Technology, Stockholm (Sweden); Moszynski, M. [Soltan Institute for Nuclear Studies, Swierk (Poland); Pienkowski, L. [Heavy Ion Laboratory, Warsaw University, ul. Pasteura 5A, PL 02-093 Warsaw (Poland); Stolarz, A. [Heavy Ion Laboratory, Warsaw University, ul. Pasteura 5A, PL 02-093 Warsaw (Poland); Wolski, D. [Soltan Institute for Nuclear Studies, Swierk (Poland); Zieblinski, M. [Henryk Niewodniczanski Institute of Nuclear Physics, Polish Academy of Sciences, Cracow (Poland)

    2005-09-11

    A novel, highly efficient, plastic scintillator detector has been constructed. The primary application of the detector is to act as a veto device in heavy-ion-induced fusion-evaporation reactions, in which the structure of proton-rich nuclides is investigated by {gamma}-ray spectroscopy methods. The detector rejects events in which light charged particles, like protons and {alpha} particles, are emitted in the evaporation process, facilitating selection of reaction channels associated with emission of only neutrons. The detector was used in a EUROBALL experiment, with achieved efficiencies of 80% and 63% for protons and {alpha} particles, respectively. The design of the detector, its performance and limitations are discussed.

  18. High Efficiency Solar Integrated Roof Membrane Product

    Energy Technology Data Exchange (ETDEWEB)

    Partyka, Eric; Shenoy, Anil

    2013-05-15

    This project was designed to address the Solar Energy Technology Program objective, to develop new methods to integrate photovoltaic (PV) cells or modules within a building-integrated photovoltaic (BIPV) application that will result in lower installed cost as well as higher efficiencies of the encapsulated/embedded PV module. The technology assessment and development focused on the evaluation and identification of manufacturing technologies and equipment capable of producing such low-cost, high-efficiency, flexible BIPV solar cells on single-ply roofing membranes.

  19. High-efficiency electrical charger for nanoparticles

    Energy Technology Data Exchange (ETDEWEB)

    Alonso, M., E-mail: malonso@cenim.csic.es [National Centre for Metallurgical Research (CENIM-CSIC) (Spain); Huang, C. H. [Yuanpei University, Department of Environmental Engineering and Health (China)

    2015-08-15

    An electrical charger, based on a point-to-plate DC corona discharge, for the high-efficiency charging of aerosol particles with diameter of a few nanometers, has been designed, constructed, and evaluated. The discharge takes place between a needle and a perforated plate, and the results presented here have shown that this specific design allows reduction of electrostatic losses of charged particles within the charger in comparison with other typical designs. Besides, the small effective volume of the charger leads to a relatively small diffusion loss of particles. As a consequence of the reduced electrostatic and diffusion losses, the extrinsic charging efficiency attainable is higher than in similar devices.

  20. High Efficiency Reversible Fuel Cell Power Converter

    DEFF Research Database (Denmark)

    Pittini, Riccardo

    The large scale integration of renewable energy sources requires suitable energy storage systems to balance energy production and demand in the electrical grid. Bidirectional fuel cells are an attractive technology for energy storage systems due to the high energy density of fuel. Compared...... entitled "High Efficiency Reversible Fuel Cell Power Converter" and it presents the design of a high efficiency dc-dc converter developed and optimized for bidirectional fuel cell applications. First, a brief overview of fuel cell and energy storage technologies is presented. Different system topologies...... to traditional unidirectional fuel cell, bidirectional fuel cells have increased operating voltage and current ranges. These characteristics increase the stresses on dc-dc and dc-ac converters in the electrical system, which require proper design and advanced optimization. This work is part of the PhD project...

  1. High efficiency electrotransformation of Lactobacillus casei.

    Science.gov (United States)

    Welker, Dennis L; Hughes, Joanne E; Steele, James L; Broadbent, Jeff R

    2015-01-01

    We investigated whether protocols allowing high efficiency electrotransformation of other lactic acid bacteria were applicable to five strains of Lactobacillus casei (12A, 32G, A2-362, ATCC 334 and BL23). Addition of 1% glycine or 0.9 M NaCl during cell growth, limitation of the growth of the cell cultures to OD600 0.6-0.8, pre-electroporation treatment of cells with water or with a lithium acetate (100 mM)/dithiothreitol (10 mM) solution and optimization of electroporation conditions all improved transformation efficiencies. However, the five strains varied in their responses to these treatments. Transformation efficiencies of 10(6) colony forming units μg(-1) pTRKH2 DNA and higher were obtained with three strains which is sufficient for construction of chromosomal gene knock-outs and gene replacements.

  2. Complexity-aware high efficiency video coding

    CERN Document Server

    Correa, Guilherme; Agostini, Luciano; Cruz, Luis A da Silva

    2016-01-01

    This book discusses computational complexity of High Efficiency Video Coding (HEVC) encoders with coverage extending from the analysis of HEVC compression efficiency and computational complexity to the reduction and scaling of its encoding complexity. After an introduction to the topic and a review of the state-of-the-art research in the field, the authors provide a detailed analysis of the HEVC encoding tools compression efficiency and computational complexity.  Readers will benefit from a set of algorithms for scaling the computational complexity of HEVC encoders, all of which take advantage from the flexibility of the frame partitioning structures allowed by the standard.  The authors also provide a set of early termination methods based on data mining and machine learning techniques, which are able to reduce the computational complexity required to find the best frame partitioning structures. The applicability of the proposed methods is finally exemplified with an encoding time control system that emplo...

  3. High Efficiency, Low Emission Refrigeration System

    Energy Technology Data Exchange (ETDEWEB)

    Fricke, Brian A [ORNL; Sharma, Vishaldeep [ORNL

    2016-08-01

    Supermarket refrigeration systems account for approximately 50% of supermarket energy use, placing this class of equipment among the highest energy consumers in the commercial building domain. In addition, the commonly used refrigeration system in supermarket applications is the multiplex direct expansion (DX) system, which is prone to refrigerant leaks due to its long lengths of refrigerant piping. This leakage reduces the efficiency of the system and increases the impact of the system on the environment. The high Global Warming Potential (GWP) of the hydrofluorocarbon (HFC) refrigerants commonly used in these systems, coupled with the large refrigerant charge and the high refrigerant leakage rates leads to significant direct emissions of greenhouse gases into the atmosphere. Methods for reducing refrigerant leakage and energy consumption are available, but underutilized. Further work needs to be done to reduce costs of advanced system designs to improve market utilization. In addition, refrigeration system retrofits that result in reduced energy consumption are needed since the majority of applications address retrofits rather than new stores. The retrofit market is also of most concern since it involves large-volume refrigerant systems with high leak rates. Finally, alternative refrigerants for new and retrofit applications are needed to reduce emissions and reduce the impact on the environment. The objective of this Collaborative Research and Development Agreement (CRADA) between the Oak Ridge National Laboratory and Hill Phoenix is to develop a supermarket refrigeration system that reduces greenhouse gas emissions and has 25 to 30 percent lower energy consumption than existing systems. The outcomes of this project will include the design of a low emission, high efficiency commercial refrigeration system suitable for use in current U.S. supermarkets. In addition, a prototype low emission, high efficiency supermarket refrigeration system will be produced for

  4. High efficiency WCDMA power amplifier with Pulsed Load Modulation (PLM) technique

    Science.gov (United States)

    Liao, Shu-Hsien

    In wireless communication, high data rate complex modulation is used for spectral efficiency. However, power efficiency of power amplifier degrades when complex modulation is applied. Therefore, efficiency enhancement is necessary to maintain the performance. However, conventional efficiency enhancement schemes are nonlinear and performance improvement can only be optimized over a small range of power level. In order to preserve linearity and power efficiency, we propose a new digital power amplification technique "Pulsed Load Modulation (PLM)" for high efficiency and linear amplification. The PLM technique realizes load impedance modulation in digital fashion which is insensitive to device nonlinearity. Furthermore, the optimum power efficiency can be maintained over a wide range of output power. In this work, a PLM power amplifier module has been fabricated and to demonstrate the ability of PLM to provide high efficiency and linear amplification.

  5. Novel Methodology for the Highly-Efficient Separation of Oil and Water (Briefing Charts)

    Science.gov (United States)

    2014-03-16

    Fabric Pure PEGDA Pure PEGDA 10% POSS 20% POSS 10% POSS 20% POSS Water Rapeseed oil Water Rapeseed oil PEGDA surface reconfiguration leads to...Briefing Charts 3. DATES COVERED (From - To) March 2014- April 2014 4. TITLE AND SUBTITLE Novel Methodology for the Highly-Efficient Separation of Oil and...distrib tion unlimited. Novel Methodology for the Highly- Efficient Separation of Oil and Water Joseph Mabry, Anish Tuteja, Andrew Guenthner, Josiah Reams

  6. Template fabrication of highly ordered arrays of organic semiconductor nanowires

    Energy Technology Data Exchange (ETDEWEB)

    Heckel, Christian; Ostendorp, Stefan; Lei, Yong; Wilde, Gerhard [Institut fuer Materialphysik, Muenster (Germany)

    2011-07-01

    Porous alumina membrane (PAM) is a widely used template for the fabrication of highly ordered arrays of one-dimensional (1D) nanostructures. The structural parameters of the PAMs are adjustable, including the pore diameter and spacing, and the thickness of the membranes. And thus the structures of the 1D nanomaterials prepared using PAMs can be controlled. On the other hand, the investigation of organic semiconductors opens a new field of applications in computer technology like twistable displays or printing integrated circuits. In the current work, these two technologies are combined by depositing organic n-type semiconductors into the pores of PAMs using different synthesizing processes such as molecular evaporation and solution-phase self-assembly. As a result, highly ordered arrays of organic semiconducting wires are obtained within the pores with a diameter of about 50 nm, which indicates that it is possible to fill the pores with organic materials.The properties of these ''filled'' membranes are characterized by measuring the electrical properties of several nanowires pooled together and also of single nanowires by AFM-based methods.

  7. Designing and optimizing highly efficient grating for high-brightness laser based on spectral beam combining

    Energy Technology Data Exchange (ETDEWEB)

    Yang, Ying-Ying, E-mail: xclin@semi.ac.cn, E-mail: yangyy@semi.ac.cn; Zhao, Ya-Ping; Wang, Li-Rong; Zhang, Ling; Lin, Xue-Chun, E-mail: xclin@semi.ac.cn, E-mail: yangyy@semi.ac.cn [Laboratory of All Solid State Light Sources, Institute of Semiconductors, Chinese Academy of Sciences, Beijing 100083 (China)

    2015-03-14

    A highly efficient nano-periodical grating is theoretically investigated for spectral beam combining (SBC) and is experimentally implemented for attaining high-brightness laser from a diode laser array. The rigorous coupled-wave analysis with the S matrix method is employed to optimize the parameters of the grating. According the optimized parameters, the grating is fabricated and plays a key role in SBC cavity. The diffraction efficiency of this grating is optimized to 95% for the output laser which is emitted from the diode laser array. The beam parameter product of 3.8 mm mrad of the diode laser array after SBC is achieved at the output power of 46.3 W. The optical-to-optical efficiency of SBC cavity is measured to be 93.5% at the maximum operating current in the experiment.

  8. High Efficiency Micromachining System Applied in Nanolithography

    Science.gov (United States)

    Chen, Xing; Lee, Dong Weon; Choi, Young Soo

    Scanning probe lithography such as direct-writing lithographic processes and nanoscratching techniques based on scanning probe microscopy have presented new micromachining methods for microelectromechanical system (MEMS). In this paper, a micromachining system for thermal scanning probe lithography is introduced, which consists of the cantilever arrays and a big stroke micro XY-stage. A large machining area and high machining speed can be realized by combining arrays of cantilevers possessing sharp tips at their top with the novel micro XY-stage which can obtain big displacements under relatively low driving voltage and in a small size. According to the above configuration, this micromachining system is provided with high throughputs and suitable for industrialization due to its MEMS-based simple fabrication process. The novel micro XY-stage applied in this system is presented in detail including the unique structure and principles, which shows an obvious improvement and distinct advantages in comparison with traditional structures. It is analyzed by mathematical model and then simulated using finite element method (FEM), it is proved to be able to practically serve the micromachining system with high capability.

  9. Creation of High Efficient Firefly Luciferase

    Science.gov (United States)

    Nakatsu, Toru

    Firefly emits visible yellow-green light. The bioluminescence reaction is carried out by the enzyme luciferase. The bioluminescence of luciferase is widely used as an excellent tool for monitoring gene expression, the measurement of the amount of ATP and in vivo imaging. Recently a study of the cancer metastasis is carried out by in vivo luminescence imaging system, because luminescence imaging is less toxic and more useful for long-term assay than fluorescence imaging by GFP. However the luminescence is much dimmer than fluorescence. Then bioluminescence imaging in living organisms demands the high efficient luciferase which emits near infrared lights or enhances the emission intensity. Here I introduce an idea for creating the high efficient luciferase based on the crystal structure.

  10. High-efficiency photovoltaics based on semiconductor nanostructures

    Energy Technology Data Exchange (ETDEWEB)

    Yu, Paul K.L. [University of California, San Diego; Yu, Edward T. [University of Texas at Austin; Wang, Deli [University of California, San Diego

    2011-10-31

    The objective of this project was to exploit a variety of semiconductor nanostructures, specifically semiconductor quantum wells, quantum dots, and nanowires, to achieve high power conversion efficiency in photovoltaic devices. In a thin-film device geometry, the objectives were to design, fabricate, and characterize quantum-well and quantum-dot solar cells in which scattering from metallic and/or dielectric nanostructures was employed to direct incident photons into lateral, optically confined paths within a thin (~1-3um or less) device structure. Fundamental issues concerning nonequilibrium carrier escape from quantum-confined structures, removal of thin-film devices from an epitaxial growth substrate, and coherent light trapping in thin-film photovoltaic devices were investigated. In a nanowire device geometry, the initial objectives were to engineer vertical nanowire arrays to optimize optical confinement within the nanowires, and to extend this approach to core-shell heterostructures to achieve broadspectrum absorption while maintaining high opencircuit voltages. Subsequent work extended this approach to include fabrication of nanowire photovoltaic structures on low-cost substrates.

  11. Clean and Highly Efficient Utilization of Coal

    Institute of Scientific and Technical Information of China (English)

    WANG Jianguo; YANG Li

    2011-01-01

    @@ Clean and highly efficient utilization of coal is an important scientific and technological issue.As the petroleum resource decreases but its consumption increases, all of the countries in the world have to face the big issue of sustainable development of energy and economy and protection of environment.Therefore, study on clean coal technology (CCT) has attracted much attention and become one of important themes of energy research.

  12. Fabrication and Design Aspects of High-Temperature Compact Diffusion Bonded Heat Exchangers

    Energy Technology Data Exchange (ETDEWEB)

    Mylavarapu, Sai K. [Ohio State University; Sun, Xiaodong [Ohio State University; Christensen, Richard N. [Ohio State University; Glosup, Richard E. [Ohio State University; Unocic, Raymond R [ORNL

    2012-01-01

    The very high temperature reactor (VHTR), using gas-cooled reactor technology, is one of the six reactor concepts selected by the Generation IV International Forum and is anticipated to be the reactor type for the next generation nuclear plant (NGNP). In this type of reactor with an indirect power cycle system, a high-temperature and high integrity intermediate heat exchanger (IHX) with high effectiveness is required to efficiently transfer the core thermal output to secondary fluid for electricity production, process heat, or hydrogen cogeneration. The current Technology Readiness Level status issued by NGNP to all components associated with the IHX for reactor core outlet temperatures of 750-800oC is 3 on a scale of 1 to 10 with 10 being the most ready. At present, there is no proven high-temperature IHX concept for VHTRs. Amongst the various potential IHX concepts available, diffusion bonded heat exchangers (henceforth called printed circuit heat exchangers, or PCHEs) appear promising for NGNP applications. The design and fabrication of this key component of NGNP is the primary focus of this paper. In the current study, two PCHEs were fabricated using Alloy 617 plates and will be experimentally investigated for their thermal-hydraulic performance in a high-temperature helium test facility (HTHF). The HTHF was primarily designed and constructed to test the thermal-hydraulic performance of PCHEs The test facility is primarily of Alloy 800H construction and is designed to facilitate experiments at temperatures and pressures up to 800oC and 3 MPa, respectively. The PCHE fabrication related processes, i.e., photochemical machining and diffusion bonding are briefly discussed for Alloy 617 plates. Diffusion bonding of Alloy 617 plates with and without a Ni interlayer is discussed. Furthermore, preliminary microstructural and mechanical characterization studies of representative diffusion bonded Alloy 617 specimens are presented.

  13. High Efficiency Power Converter for Low Voltage High Power Applications

    DEFF Research Database (Denmark)

    Nymand, Morten

    , and remote power generation for light towers, camper vans, boats, beacons, and buoys etc. A review of current state-of-the-art is presented. The best performing converters achieve moderately high peak efficiencies at high input voltage and medium power level. However, system dimensioning and cost are often......The topic of this thesis is the design of high efficiency power electronic dc-to-dc converters for high-power, low-input-voltage to high-output-voltage applications. These converters are increasingly required for emerging sustainable energy systems such as fuel cell, battery or photo voltaic based...... determined by the performance at the system worst case operating point which is usually at minimum input voltage and maximum power. Except for the non-regulating V6 converters, all published solutions exhibit a very significant drop in conversion efficiency at minimum input voltage and maximum output power...

  14. Solution Chemistry Engineering toward High-Efficiency Perovskite Solar Cells.

    Science.gov (United States)

    Zhao, Yixin; Zhu, Kai

    2014-12-04

    Organic and inorganic hybrid perovskites (e.g., CH3NH3PbI3) have emerged as a revolutionary class of light-absorbing semiconductors that has demonstrated a rapid increase in efficiency within a few years of active research. Controlling perovskite morphology and composition has been found critical to developing high-performance perovskite solar cells. The recent development of solution chemistry engineering has led to fabrication of greater than 15-17%-efficiency solar cells by multiple groups, with the highest certified 17.9% efficiency that has significantly surpassed the best-reported perovskite solar cell by vapor-phase growth. In this Perspective, we review recent progress on solution chemistry engineering processes and various control parameters that are critical to the success of solution growth of high-quality perovskite films. We discuss the importance of understanding the impact of solution-processing parameters and perovskite film architectures on the fundamental charge carrier dynamics in perovskite solar cells. The cost and stability issues of perovskite solar cells will also be discussed.

  15. Bioblendstocks that Enable High Efficiency Engine Designs

    Energy Technology Data Exchange (ETDEWEB)

    McCormick, Robert L.; Fioroni, Gina M.; Ratcliff, Matthew A.; Zigler, Bradley T.; Farrell, John

    2016-11-03

    The past decade has seen a high level of innovation in production of biofuels from sugar, lipid, and lignocellulose feedstocks. As discussed in several talks at this workshop, ethanol blends in the E25 to E50 range could enable more highly efficient spark-ignited (SI) engines. This is because of their knock resistance properties that include not only high research octane number (RON), but also charge cooling from high heat of vaporization, and high flame speed. Emerging alcohol fuels such as isobutanol or mixed alcohols have desirable properties such as reduced gasoline blend vapor pressure, but also have lower RON than ethanol. These fuels may be able to achieve the same knock resistance benefits, but likely will require higher blend levels or higher RON hydrocarbon blendstocks. A group of very high RON (>150) oxygenates such as dimethyl furan, methyl anisole, and related compounds are also produced from biomass. While providing no increase in charge cooling, their very high octane numbers may provide adequate knock resistance for future highly efficient SI engines. Given this range of options for highly knock resistant fuels there appears to be a critical need for a fuel knock resistance metric that includes effects of octane number, heat of vaporization, and potentially flame speed. Emerging diesel fuels include highly branched long-chain alkanes from hydroprocessing of fats and oils, as well as sugar-derived terpenoids. These have relatively high cetane number (CN), which may have some benefits in designing more efficient CI engines. Fast pyrolysis of biomass can produce diesel boiling range streams that are high in aromatic, oxygen and acid contents. Hydroprocessing can be applied to remove oxygen and consequently reduce acidity, however there are strong economic incentives to leave up to 2 wt% oxygen in the product. This oxygen will primarily be present as low CN alkyl phenols and aryl ethers. While these have high heating value, their presence in diesel fuel

  16. Fabrication of high thermal conductive Al-cBN ceramic sinters by high temperature high pressure method

    Science.gov (United States)

    Wang, P. F.; Li, Zh. H.; Zhu, Y. M.

    2011-05-01

    Al-cBN ceramic sinters were fabricated by sintering micro-powder mixture of Al and cBN under high temperature and high pressure condition. Differential scanning calorimetry (DSC), X-ray diffraction (XRD), scanning electronic microscopy (SEM) and energy-dispersive X-ray spectroscopy (EDS) elemental mapping analyses and laser flashing thermal conductivity measurements were performed to investigate the sintering properties and thermal conductivity of the Al-cBN ceramic sinters. XRD analysis revealed these Al-cBN ceramic sinters were composed of a large portion of cBN and of a small portion of AlN, and very little amount of AlB 12 and hBN. Formation of boundary phase resulted in the rapid densification of the sinters, as well as the increase of their relative density with increasing Al additions. The Al-cBN ceramic sinters have a maximum thermal conductivity of about 1.94 W/cm K at room temperature and a much higher value of about 2.04 W/cm K at 200 °C. Their high thermal conductivity over that of AlN-hBN composites promise Al-cBN ceramic sinters favorite candidates as high efficiency heat sink materials for wide band gap semiconductors.

  17. Research on High Layer Thickness Fabricated of 316L by Selective Laser Melting

    Directory of Open Access Journals (Sweden)

    Shuo Wang

    2017-09-01

    Full Text Available Selective laser melting (SLM is a potential additive manufacturing (AM technology. However, the application of SLM was confined due to low efficiency. To improve efficiency, SLM fabrication with a high layer thickness and fine powder was systematically researched, and the void areas and hollow powders can be reduced by using fine powder. Single-track experiments were used to narrow down process parameter windows. Multi-layer fabrication relative density can be reached 99.99% at the exposure time-point distance-hatch space of 120 μs-40 μm-240 μm. Also, the building rate can be up to 12 mm3/s, which is about 3–10 times higher than the previous studies. Three typical defects were found by studying deeply, including the un-melted defect between the molten pools, the micro-pore defect within the molten pool, and the irregular distribution of the splashing phenomenon. Moreover, the microstructure is mostly equiaxed crystals and a small amount of columnar crystals. The averages of ultimate tensile strength, yield strength, and elongation are 625 MPa, 525 MPa, and 39.9%, respectively. As exposure time increased from 80 μs to 200 μs, the grain size is gradually grown up from 0.98 μm to 2.23 μm, the grain aspect ratio is close to 1, and the tensile properties are shown as a downward trend. The tensile properties of high layer thickness fabricated are not significantly different than those with a coarse-powder layer thickness of low in previous research.

  18. Fabrication of setup for high temperature thermal conductivity measurement

    Science.gov (United States)

    Patel, Ashutosh; Pandey, Sudhir K.

    2017-01-01

    In this work, we report the fabrication of an experimental setup for high temperature thermal conductivity (κ) measurement. It can characterize samples with various dimensions and shapes. Steady state based axial heat flow technique is used for κ measurement. Heat loss is measured using parallel thermal conductance technique. Simple design, lightweight, and small size sample holder is developed by using a thin heater and limited components. Low heat loss value is achieved by using very low thermal conductive insulator block with small cross-sectional area. Power delivered to the heater is measured accurately by using 4-wire technique and for this, the heater is developed with 4 wires. This setup is validated by using Bi0.36Sb1.45Te3, polycrystalline bismuth, gadolinium, and alumina samples. The data obtained for these samples are found to be in good agreement with the reported data. The maximum deviation of 6% in the value κ is observed. This maximum deviation is observed with the gadolinium sample. We also report the thermal conductivity of polycrystalline tellurium from 320 K to 550 K and the nonmonotonous behavior of κ with temperature is observed.

  19. High sensitivity measurements of thermal properties of textile fabrics

    CERN Document Server

    Romeli, D; Esposito, S; Rosace, G; Salesi, G

    2013-01-01

    A new testing apparatus is proposed to measure the thermal properties of fabrics made from polymeric materials. The calibration of the apparatus and the data acquisition procedure are considered in detail in order to measure thermal conductivity, resistance, absorption and diffusivity constants of the tested fabric samples. Differences between dry and wet fabrics have been carefully detected and analyzed. We have developed a new measurement protocol, the "ThermoTex" protocol, which agrees with the UNI EN 31092 standard and entails an accurate quantification of the experimental errors according to a standard statistical analysis, thus allowing a rigorous investigation of the physical behavior of the phenomena involved. As a consequence, our machinery exhibits great potentialities for optimizing the thermal comfort of fabrics, according to the market demand, thanks to the possible development of a predictive phenomenological theory of the effects involved.

  20. Highly efficient fully transparent inverted OLEDs

    Science.gov (United States)

    Meyer, J.; Winkler, T.; Hamwi, S.; Schmale, S.; Kröger, M.; Görrn, P.; Johannes, H.-H.; Riedl, T.; Lang, E.; Becker, D.; Dobbertin, T.; Kowalsky, W.

    2007-09-01

    One of the unique selling propositions of OLEDs is their potential to realize highly transparent devices over the visible spectrum. This is because organic semiconductors provide a large Stokes-Shift and low intrinsic absorption losses. Hence, new areas of applications for displays and ambient lighting become accessible, for instance, the integration of OLEDs into the windshield or the ceiling of automobiles. The main challenge in the realization of fully transparent devices is the deposition of the top electrode. ITO is commonly used as transparent bottom anode in a conventional OLED. To obtain uniform light emission over the entire viewing angle and a low series resistance, a TCO such as ITO is desirable as top contact as well. However, sputter deposition of ITO on top of organic layers causes damage induced by high energetic particles and UV radiation. We have found an efficient process to protect the organic layers against the ITO rf magnetron deposition process of ITO for an inverted OLED (IOLED). The inverted structure allows the integration of OLEDs in more powerful n-channel transistors used in active matrix backplanes. Employing the green electrophosphorescent material Ir(ppy) 3 lead to IOLED with a current efficiency of 50 cd/A and power efficiency of 24 lm/W at 100 cd/m2. The average transmittance exceeds 80 % in the visible region. The on-set voltage for light emission is lower than 3 V. In addition, by vertical stacking we achieved a very high current efficiency of more than 70 cd/A for transparent IOLED.

  1. Integratable and High Speed Complex-Coupled MQW-DFB Lasers Fabricated on Semi-Insulating Substrates

    Institute of Scientific and Technical Information of China (English)

    CHENG Yuan-Bing; WANG Yang; SUN Yu; PAN Jiao-Qing; BIAN Jing; AN Xin; ZHAO ling-juan; WANG Wei

    2009-01-01

    A novel integratable and high speed InGaAsP multi-quantum well (MQW) complex-coupled distributed feedback (DFB) laser is successfully fabricated on a semi-insulating substrate. The fabricated ridge DFB laser exhibits a threshold current of 26 mA, a slope efficiency of 0. 14 W.A-1 and a side mode suppression ratio of 40 dB together with a 3 dB bandwidth of more than 8 GHz. The device is suitable for 10 Gbit/s optical fiber communication.

  2. High-Efficiency Nitride-Base Photonic Crystal Light Sources

    Energy Technology Data Exchange (ETDEWEB)

    James Speck; Evelyn Hu; Claude Weisbuch; Yong-Seok Choi; Kelly McGroddy; Gregor Koblmuller; Elison Matioli; Elizabeth Rangel; Fabian Rol; Dobri Simeonov

    2010-01-31

    The research activities performed in the framework of this project represent a major breakthrough in the demonstration of Photonic Crystals (PhC) as a competitive technology for LEDs with high light extraction efficiency. The goals of the project were to explore the viable approaches to manufacturability of PhC LEDS through proven standard industrial processes, establish the limits of light extraction by various concepts of PhC LEDs, and determine the possible advantages of PhC LEDs over current and forthcoming LED extraction concepts. We have developed three very different geometries for PhC light extraction in LEDs. In addition, we have demonstrated reliable methods for their in-depth analysis allowing the extraction of important parameters such as light extraction efficiency, modal extraction length, directionality, internal and external quantum efficiency. The information gained allows better understanding of the physical processes and the effect of the design parameters on the light directionality and extraction efficiency. As a result, we produced LEDs with controllable emission directionality and a state of the art extraction efficiency that goes up to 94%. Those devices are based on embedded air-gap PhC - a novel technology concept developed in the framework of this project. They rely on a simple and planar fabrication process that is very interesting for industrial implementation due to its robustness and scalability. In fact, besides the additional patterning and regrowth steps, the process is identical as that for standard industrially used p-side-up LEDs. The final devices exhibit the same good electrical characteristics and high process yield as a series of test standard LEDs obtained in comparable conditions. Finally, the technology of embedded air-gap patterns (PhC) has significant potential in other related fields such as: increasing the optical mode interaction with the active region in semiconductor lasers; increasing the coupling of the incident

  3. Design and fabrication of branched polyamine functionalized mesoporous silica: an efficient absorbent for water remediation.

    Science.gov (United States)

    Nayab, Sana; Farrukh, Aleeza; Oluz, Zehra; Tuncel, Eylül; Tariq, Saadia Rashid; ur Rahman, Habib; Kirchhoff, Katrin; Duran, Hatice; Yameen, Basit

    2014-03-26

    A novel branched polyamine (polyethyleneimine, PEI) functionalized mesoporous silica (MS) adsorbent is developed via a facile "grafting-to" approach. X-ray photoelectron spectroscopy (XPS) and Fourier transform infrared (FT-IR) spectroscopy verified the effective surface functionalization of MS with monolayer and polymer. The transmission electron microscopy (TEM) was employed to reveal the morphology of the fabricated materials. The adsorption behavior of the polyamine functionalized mesoporous silica (MS-PEI) is assessed against anionic dyes. The adsorbent characteristics of MS-PEI are compared with a monolayer platform comprising of 3-aminopropyltriethoxy silane (APTES) functionalized mesoporous silica (MS-APTES). The adsorption behavior of the MS-PEI and MS-APTES toward anionic dyes is further evaluated by studying the effect of adsorbent dosage, pH, contact time, and temperature. Langmuir and Freundlich isotherm models are employed to understand the adsorption mechanism. The obtained kinetic data support a pseudo-second-order adsorption behavior for both monolayer and polymer functionalized MS. The associated thermodynamic parameters (ΔG°, ΔH°, and ΔS°) reveal that the process of adsorption with MS-PEI is more spontaneous and energetically favored as compared to the adsorption with MS-APTES. Taken together, the novel adsorbent system derived from a combination of MS and branched polymer (MS-PEI) shows the higher absorption efficiency and capacity toward the anionic dyes than the monolayer based adsorbent (MS-APTES).

  4. High Efficiency Colloidal Quantum Dot Phosphors

    Energy Technology Data Exchange (ETDEWEB)

    Kahen, Keith

    2013-12-31

    The project showed that non-Cd containing, InP-based nanocrystals (semiconductor materials with dimensions of ~6 nm) have high potential for enabling next-generation, nanocrystal-based, on chip phosphors for solid state lighting. Typical nanocrystals fall short of the requirements for on chip phosphors due to their loss of quantum efficiency under the operating conditions of LEDs, such as, high temperature (up to 150 °C) and high optical flux (up to 200 W/cm2). The InP-based nanocrystals invented during this project maintain high quantum efficiency (>80%) in polymer-based films under these operating conditions for emission wavelengths ranging from ~530 to 620 nm. These nanocrystals also show other desirable attributes, such as, lack of blinking (a common problem with nanocrystals which limits their performance) and no increase in the emission spectral width from room to 150 °C (emitters with narrower spectral widths enable higher efficiency LEDs). Prior to these nanocrystals, no nanocrystal system (regardless of nanocrystal type) showed this collection of properties; in fact, other nanocrystal systems are typically limited to showing only one desirable trait (such as high temperature stability) but being deficient in other properties (such as high flux stability). The project showed that one can reproducibly obtain these properties by generating a novel compositional structure inside of the nanomaterials; in addition, the project formulated an initial theoretical framework linking the compositional structure to the list of high performance optical properties. Over the course of the project, the synthetic methodology for producing the novel composition was evolved to enable the synthesis of these nanomaterials at a cost approximately equal to that required for forming typical conventional nanocrystals. Given the above results, the last major remaining step prior to scale up of the nanomaterials is to limit the oxidation of these materials during the tens of

  5. High Efficiency Power Converter for Low Voltage High Power Applications

    DEFF Research Database (Denmark)

    Nymand, Morten

    , and remote power generation for light towers, camper vans, boats, beacons, and buoys etc. In chapter 2, a review of current state-of-the-art is presented. The best performing converters achieve moderately high peak efficiencies at high input voltage and medium power level. However, system dimensioning...

  6. Highly efficient optical parametric generation in proton exchanged PPLN waveguides

    CERN Document Server

    Chanvillard, L; Baldi, P; De Micheli, M; Ostrowsky, D B; Huang, L; Bamford, G

    1999-01-01

    Summary form only given. Parametric fluorescence, amplification, and oscillation in PPLN waveguides have already been demonstrated. In all previous experiments, the measured efficiencies were smaller than the theoretically predicted values since the waveguide fabrication process utilized, annealed proton exchange (APE) can reduce or even destroy the nonlinear coefficient and/or the periodic domain orientation in a portion of the guiding structure. In the experiment reported here, we used a 2 cm long, Z-cut PPLN with a 18 mu m domain inversion period. The waveguides are created using a direct proton exchange process in a highly diluted melt, which induces no crystallographic phase transition. This allows preserving both the nonlinear coefficient and the domain orientation while fully benefiting from the power confinement associated with the guided wave configuration. (4 refs).

  7. Quantum wells for high-efficiency photovoltaics

    Science.gov (United States)

    Alonso-Álvarez, Diego; Ekins-Daukes, Nicholas

    2016-03-01

    Over the last couple of decades, there has been an intense research on strain balanced semiconductor quantum wells (QW) to increase the efficiency of multi-junction solar (MJ) solar cells grown monolithically on germanium. So far, the most successful application of QWs have required just to tailor a few tens of nanometers the absorption edge of a given subcell in order to reach the optimum spectral position. However, the demand for higher efficiency devices requiring 3, 4 or more junctions, represents a major difference in the challenges QWs must face: tailoring the absorption edge of a host material is not enough, but a complete new device, absorbing light in a different spectral region, must be designed. Among the most important issues to solve is the need for an optically thick structure to absorb enough light while keeping excellent carrier extraction using highly strained materials. Improvement of the growth techniques, smarter device designs - involving superlattices and shifted QWs, for example - or the use of quantum wires rather than QWs, have proven to be very effective steps towards high efficient MJ solar cells based on nanostructures in the last couple of years. But more is to be done to reach the target performances. This work discusses all these challenges, the limitations they represent and the different approaches that are being used to overcome them.

  8. High torque DC motor fabrication and test program

    Science.gov (United States)

    Makus, P.

    1976-01-01

    The testing of a standard iron and standard alnico permanent magnet two-phase, brushless dc spin motor for potential application to the space telescope has been concluded. The purpose of this study was to determine spin motor power losses, magnetic drag, efficiency and torque speed characteristics of a high torque dc motor. The motor was designed and built to fit an existing reaction wheel as a test vehicle and to use existing brass-board commutation and torque command electronics. The results of the tests are included in this report.

  9. Dual-Source Precursor Approach for Highly Efficient Inverted Planar Heterojunction Perovskite Solar Cells.

    Science.gov (United States)

    Luo, Deying; Zhao, Lichen; Wu, Jiang; Hu, Qin; Zhang, Yifei; Xu, Zhaojian; Liu, Yi; Liu, Tanghao; Chen, Ke; Yang, Wenqiang; Zhang, Wei; Zhu, Rui; Gong, Qihuang

    2017-05-01

    The highest efficiencies reported for perovskite solar cells so far have been obtained mainly with methylammonium and formamidinium mixed cations. Currently, high-quality mixed-cation perovskite thin films are normally made by use of antisolvent protocols. However, the widely used "antisolvent"-assisted fabrication route suffers from challenges such as poor device reproducibility, toxic and hazardous organic solvent, and incompatibility with scalable fabrication process. Here, a simple dual-source precursor approach is developed to fabricate high-quality and mirror-like mixed-cation perovskite thin films without involving additional antisolvent process. By integrating the perovskite films into the planar heterojunction solar cells, a power conversion efficiency of 20.15% is achieved with negligible current density-voltage hysteresis. A stabilized power output approaching 20% is obtained at the maximum power point. These results shed light on fabricating highly efficient perovskite solar cells via a simple process, and pave the way for solar cell fabrication via scalable methods in the near future. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  10. HIGH-EFFICIENCY AUTONOMOUS LASER ADAPTIVE OPTICS

    Energy Technology Data Exchange (ETDEWEB)

    Baranec, Christoph [Institute for Astronomy, University of Hawai' i at Mānoa, Hilo, HI, NZ 96720-2700 (United States); Riddle, Reed; Tendulkar, Shriharsh; Hogstrom, Kristina; Bui, Khanh; Dekany, Richard; Kulkarni, Shrinivas [Division of Physics, Mathematics, and Astronomy, California Institute of Technology, Pasadena, CA 91125 (United States); Law, Nicholas M. [Department of Physics and Astronomy, University of North Carolina at Chapel Hill, Chapel Hill, NC 27599-3255 (United States); Ramaprakash, A. N.; Burse, Mahesh; Chordia, Pravin; Das, Hillol; Punnadi, Sujit, E-mail: baranec@hawaii.edu [Inter-University Centre for Astronomy and Astrophysics, Ganeshkhind, Pune 411007 (India)

    2014-07-20

    As new large-scale astronomical surveys greatly increase the number of objects targeted and discoveries made, the requirement for efficient follow-up observations is crucial. Adaptive optics imaging, which compensates for the image-blurring effects of Earth's turbulent atmosphere, is essential for these surveys, but the scarcity, complexity and high demand of current systems limit their availability for following up large numbers of targets. To address this need, we have engineered and implemented Robo-AO, a fully autonomous laser adaptive optics and imaging system that routinely images over 200 objects per night with an acuity 10 times sharper at visible wavelengths than typically possible from the ground. By greatly improving the angular resolution, sensitivity, and efficiency of 1-3 m class telescopes, we have eliminated a major obstacle in the follow-up of the discoveries from current and future large astronomical surveys.

  11. High-efficiency Autonomous Laser Adaptive Optics

    CERN Document Server

    Baranec, Christoph; Law, Nicholas M; Ramaprakash, A N; Tendulkar, Shriharsh; Hogstrom, Kristina; Bui, Khanh; Burse, Mahesh; Chordia, Pravin; Das, Hillol; Dekany, Richard; Kulkarni, Shrinivas; Punnadi, Sujit

    2014-01-01

    As new large-scale astronomical surveys greatly increase the number of objects targeted and discoveries made, the requirement for efficient follow-up observations is crucial. Adaptive optics imaging, which compensates for the image-blurring effects of Earth's turbulent atmosphere, is essential for these surveys, but the scarcity, complexity and high demand of current systems limits their availability for following up large numbers of targets. To address this need, we have engineered and implemented Robo-AO, a fully autonomous laser adaptive optics and imaging system that routinely images over 200 objects per night with an acuity 10 times sharper at visible wavelengths than typically possible from the ground. By greatly improving the angular resolution, sensitivity, and efficiency of 1-3 m class telescopes, we have eliminated a major obstacle in the follow-up of the discoveries from current and future large astronomical surveys.

  12. High efficiency motors; Motores de alta eficiencia

    Energy Technology Data Exchange (ETDEWEB)

    Uranga Favela, Ivan Jaime [Energia Controlada de Mexico, S. A. de C. V., Mexico, D. F. (Mexico)

    1992-12-31

    This paper is a technical-financial study of the high efficiency and super-premium motors. As it is widely known, more than 60% of the electrical energy generated in the country is used for the operation of motors, in industry as well as in commerce. Therefore the importance that the motors have in the efficient energy use. [Espanol] El presente trabajo es un estudio tecnico-financiero de los motores de alta eficiencia y los motores super premium. Como es ampliamente conocido, mas del 60% de la energia electrica generada en el pais, es utilizada para accionar motores, dentro de la industria y el comercio. De alli la importancia que los motores tienen en el uso eficiente de la energia.

  13. InGaAsP/InP DH Ridge Waveguide Phase Modulator with High Modulation Efficiency

    Institute of Scientific and Technical Information of China (English)

    Young; Tae; Byun; Hwa; Sun; Park; Sung; Jin; Kim; Deok; Ha; Woo; Jong; Chang; Yi; Yoshiaki; Nakano

    2003-01-01

    The P-p-n-N InGaAsP/InP ridge waveguide phase modulator has been fabricated and investigated at a wavelength of 1550nm. The phase modulation efficiency measured by the Fabry-Perot resonance method is as high as 34°/V·mm for TE mode. The QEO effect becomes dominant from - 4V to - 8V.

  14. InGaAsP/InP DH Ridge Waveguide Phase Modulator with High Modulation Efficiency

    Institute of Scientific and Technical Information of China (English)

    Young Tae Byun; Hwa Sun Park; Sung Jin Kim; Deok Ha Woo; Jong Chang Yi; Yoshiaki Nakano

    2003-01-01

    The P-p-n-N InGaAsP/InP ridge waveguide phase modulator has been fabricated and investigated at a wavelength of 1550nm. The phase modulation efficiency measured by the Fabry-Perot resonance method is as high as 34°/V.mm for TE mode. The QEO effect becomes dominant from -4V to -8V.

  15. An isopropanol-assisted fabrication strategy of pinhole-free perovskite films in air for efficient and stable planar perovskite solar cells

    Science.gov (United States)

    Ren, Ziqiu; Zhu, Menghua; Li, Xin; Dong, Cunku

    2017-09-01

    As a promising photovoltaic device, perovskite solar cells have attracted numerous attention in recent years, where forming a compact and pinhole-free perovskite film in air is of great importance. Herein, we evaluate highly efficient and air stable planar perovskite solar cells in air (relative humidity over 50%) with the modified two-step sequential deposition method by adjusting the CH3NH3I (MAI) concentrations and regulating the crystallization process of the perovskite film. The optimum MAI concentration is 60 mg mL-1 in isopropanol. With a planar structure of FTO/TiO2/MAPbI3/spiro-OMeTAD/Au, the efficient devices composed of compact and pinhole-free perovskite films are constructed in air, achieving a high efficiency of up to 15.10% and maintaining over 80% after 20 days storing without any encapsulation in air. With a facile fabrication process and high photovoltaic performance, this work represents a promising method for fabricating low-cost, highly efficient and stable photovoltaic device.

  16. Highly efficient electrophosphorescence devices based on iridium complexes with high efficiency over a wide range of current densities

    Energy Technology Data Exchange (ETDEWEB)

    Zhang Liying; Li Bin; Hong Ziruo [Key Laboratory of Excited State Processes, Changchun Institute of Optics, Fine Mechanics and Physics, Changchun 130033 (China); Chen Ping; Liu Shiyong [State Key Lab of Integrated Optoelectronics, Jilin University, Changchun 130023 (China)], E-mail: lib020@ciomp.ac.cn, E-mail: syliu@mail.jlu.edu.cn

    2008-12-21

    Three new luminescent cyclometalated iridium (II I) complexes are successfully synthesized. The cyclometalated ligand used here is 2-(2-fluorophenyl)-benzothiazole (F-BT). The auxiliary ligands are acetylacetone (acac), 1,1,1-trifluoroacetylaceton (3F-acac), 1,1,1,5,5,5-hexafluoroacetylacetone (6F-acac), respectively. All complexes exhibit bright photoluminescence at room temperature. Organic light-emitting diodes are fabricated by doping the iridium (III) complexes in 4, 4' -N, N'-dicarbazole-biphenyl (CBP), and the device characteristics are investigated. Among these devices, the performances of the optimized devices based on 1 at high current density are among the best reported for devices with iridium (III) complexes as emitters. EL efficiencies show weak dependence on doping concentration and current density. The optimized device exhibits a peak current efficiency of 28.5 cd A{sup -1} and a power efficiency of 11.2 lm W{sup -1}, respectively, at 20 mA cm{sup -2}, an efficiency of 22.7 cd A{sup -1} at 100 mA cm{sup -2}, 80% of the maximum, can be achieved. Short triplet decay time of 1 measured in solid films is supposed to be responsible for the minor loss in EL efficiency, which suggests depressed triplet-triplet annihilation and site saturation of the phosphor. Efficient exciton formation on the molecules of 1 by direct charge trapping and confinement within the emissive layer also make for outstanding electrophosphorescent performances.

  17. A microfluidic chip for highly efficient cell capturing and pairing.

    Science.gov (United States)

    Cui, Shaoyan; Liu, Yaoping; Wang, Wei; Sun, Yan; Fan, Yubo

    2011-09-01

    This paper examined the feasibility of a microfluidics chip for cell capturing and pairing with a high efficiency. The chip was fabricated by the polydimethylsiloxane-based soft-lithography technique and contained two suction duct arrays set in parallel on both sides of a main microchannel. Cells were captured and paired by activating two sets of suction ducts one by one with the help of syringe pumps along with switching the cell suspensions inside the main microchannel correspondingly. The effects of suction flow rate and the dimensions of suction channels on the cell capturing and pairing efficiency were characterized. The present chip was capable of creating 1024 pairs of two different cell populations in parallel. The preliminary experimental results showed that the cell capturing efficiency was 100% and the pairing one was 88% with an optimal suction rate of 5 μl/min in the chip in the 2 μm-sized suction duct chip. The cell viability after capture inside the microfluidic device was 90.0 ± 5.3%. With this cell capturing and pairing chip, interaction between cells in a single pair mode can be studied. The ability to create cell pairs has a number of biological applications for cell fusion, cell-cell interaction studies, and cell toxicity screening.

  18. High Quantum Efficiency OLED Lighting Systems

    Energy Technology Data Exchange (ETDEWEB)

    Shiang, Joseph [General Electric (GE) Global Research, Fairfield, CT (United States)

    2011-09-30

    The overall goal of the program was to apply improvements in light outcoupling technology to a practical large area plastic luminaire, and thus enable the product vision of an extremely thin form factor high efficiency large area light source. The target substrate was plastic and the baseline device was operating at 35 LPW at the start of the program. The target LPW of the program was a >2x improvement in the LPW efficacy and the overall amount of light to be delivered was relatively high 900 lumens. Despite the extremely difficult challenges associated with scaling up a wet solution process on plastic substrates, the program was able to make substantial progress. A small molecule wet solution process was successfully implemented on plastic substrates with almost no loss in efficiency in transitioning from the laboratory scale glass to large area plastic substrates. By transitioning to a small molecule based process, the LPW entitlement increased from 35 LPW to 60 LPW. A further 10% improvement in outcoupling efficiency was demonstrated via the use of a highly reflecting cathode, which reduced absorptive loss in the OLED device. The calculated potential improvement in some cases is even larger, ~30%, and thus there is considerable room for optimism in improving the net light coupling efficacy, provided absorptive loss mechanisms are eliminated. Further improvements are possible if scattering schemes such as the silver nanowire based hard coat structure are fully developed. The wet coating processes were successfully scaled to large area plastic substrate and resulted in the construction of a 900 lumens luminaire device.

  19. Nanooptics for high efficient photon managment

    Science.gov (United States)

    Wyrowski, Frank; Schimmel, Hagen

    2005-09-01

    Optical systems for photon management, that is the generation of tailored electromagnetic fields, constitute one of the keys for innovation through photonics. An important subfield of photon management deals with the transformation of an incident light field into a field of specified intensity distribution. In this paper we consider some basic aspects of the nature of systems for those light transformations. It turns out, that the transversal redistribution of energy (TRE) is of central concern to achieve systems with high transformation efficiency. Besides established techniques nanostructured optical elements (NOE) are demanded to implement transversal energy redistribution. That builds a bridge between the needs of photon management, optical engineering, and nanooptics.

  20. Topology design and fabrication of an efficient double 90° photonic crystal waveguide bend

    DEFF Research Database (Denmark)

    Jensen, Jakob Søndergaard; Sigmund, Ole; Frandsen, Lars Hagedorn

    2005-01-01

    We have designed and fabricated a novel 90 bend in a photonic crystal waveguide. The design was obtained using topology optimization and the fabricated waveguide displays a bend loss for transverse-electric-polarized light of less than 1 dB per bend in a 200-nm wavelength range....

  1. High efficiency CSS CdTe solar cells

    Energy Technology Data Exchange (ETDEWEB)

    Ferekides, C.S.; Marinskiy, D.; Viswanathan, V.; Tetali, B.; Palekis, V.; Selvaraj, P.; Morel, D.L. [University of South Florida, Tampa, FL (United States). Dept. of Electrical Engineering

    2000-02-21

    Cadmium telluride (CdTe) has long been recognized as a strong candidate for thin film solar cell applications. It has a bandgap of 1.45 eV, which is nearly ideal for photovoltaic energy conversion. Due to its high optical absorption coefficient essentially all incident radiation with energy above its band-gap is absorbed within 1-2 {mu}m from the surface. Thin film CdTe solar cells are typically heterojunctions, with cadmium sulfide (CdS) being the n-type junction partner. Small area efficiencies have reached the 16.0% level and considerable efforts are underway to commercialize this technology. This paper will present work carried out at the University South Florida sponsored by the National Renewable Energy Laboratory of the United States Department of Energy, on CdTe/CdS solar cells fabricated using the close spaced sublimation (CSS) process. The CSS technology has attractive features for large area applications such as high deposition rates and efficient material utilization. The structural and optical properties of CSS CdTe and CdS films and junctions will be presented and the influence of some important CSS process parameters will be discussed. (orig.)

  2. A highly efficient 3D micromixer using soft PDMS bonding

    Science.gov (United States)

    Cha, Junghun; Kim, Jinseok; Ryu, Suk-Kyu; Park, Jungyul; Jeong, Yongwon; Park, Sewan; Park, Sukho; Kim, Hyeon Cheol; Chun, Kukjin

    2006-09-01

    This paper presents a novel highly efficient passive micromixer that employs diffusion for micromixing. Since conventional fabrication methods cannot form precise aligned microchannels, the realization of a complex 3D micromixer has been difficult. Here, we report a novel micromixer, named a chessboard mixer. In addition, a new polydimethylsiloxane (PDMS) bonding method was developed to produce the proposed mixer. The new PDMS bonding technique requires PDMS-to-PDMS bonding and the moldable flexibility of partially cured PDMS to form the structure. Accordingly, a two-step curing process was used to solve these problems. Adhesion control was also considered when forming the PDMS membranes. Complex 3D microchannels in the micromixer were aligned within 1 m using the proposed new bonding method. The presented micromixer could increase the mixing effect by expanding interfaces between mixing fluids. Thus, this mixer makes it possible to mix within a shorter distance than other pre-existing micromixers do. A simulation using computational fluid dynamics (CFD)-ACE software showed a highly efficient performance, and an experiment involving the mixing of NaOH and phenolphthalein confirmed the rapid mixing performance (<1400 µm).

  3. High efficiency triple-junction amorphous solar cells

    Science.gov (United States)

    Ishihara, T.; Terazono, S.; Sasaki, H.; Kawabata, K.; Itagaki, T.

    A fabrication technique for high-efficiency triple-junction a-SiGe:H and a-Si:H pin solar cells is described. The interfacial characteristics of the a-SiGe:H pin cell, which is used for the bottom cell, have been improved by inserting graded bandgap layers at both p/i and n/i interfaces. The photoconductivity of the a-SiGe:H film, prepared by diluting the silane and germane discharge with a large amount of H2 gas, has also been improved. For the a-Si:H pin cell, Vocs as high as 0.99 V have been achieved by optimizing deposition conditions for the microc-Si:H p-layer and a-Si:H i-layer. Thickness of each layer in the triple-junction cell has been adjusted to get maximum output current. A cell with conversion efficiency of 10.6 percent has been obtained for a cell size of 100 sq cm.

  4. Simple Motor Control Concept Results High Efficiency at High Velocities

    Science.gov (United States)

    Starin, Scott; Engel, Chris

    2013-09-01

    The need for high velocity motors in space applications for reaction wheels and detectors has stressed the limits of Brushless Permanent Magnet Motors (BPMM). Due to inherent hysteresis core losses, conventional BPMMs try to balance the need for torque verses hysteresis losses. Cong-less motors have significantly less hysteresis losses but suffer from lower efficiencies. Additionally, the inherent low inductance in cog-less motors result in high ripple currents or high switching frequencies, which lowers overall efficiency and increases performance demands on the control electronics.However, using a somewhat forgotten but fully qualified technology of Isotropic Magnet Motors (IMM), extremely high velocities may be achieved at low power input using conventional drive electronics. This paper will discuss the trade study efforts and empirical test data on a 34,000 RPM IMM.

  5. Multiscale approaches to high efficiency photovoltaics

    Directory of Open Access Journals (Sweden)

    Connolly James Patrick

    2016-01-01

    Full Text Available While renewable energies are achieving parity around the globe, efforts to reach higher solar cell efficiencies becomes ever more difficult as they approach the limiting efficiency. The so-called third generation concepts attempt to break this limit through a combination of novel physical processes and new materials and concepts in organic and inorganic systems. Some examples of semi-empirical modelling in the field are reviewed, in particular for multispectral solar cells on silicon (French ANR project MultiSolSi. Their achievements are outlined, and the limits of these approaches shown. This introduces the main topic of this contribution, which is the use of multiscale experimental and theoretical techniques to go beyond the semi-empirical understanding of these systems. This approach has already led to great advances at modelling which have led to modelling software, which is widely known. Yet, a survey of the topic reveals a fragmentation of efforts across disciplines, firstly, such as organic and inorganic fields, but also between the high efficiency concepts such as hot carrier cells and intermediate band concepts. We show how this obstacle to the resolution of practical research obstacles may be lifted by inter-disciplinary cooperation across length scales, and across experimental and theoretical fields, and finally across materials systems. We present a European COST Action “MultiscaleSolar” kicking off in early 2015, which brings together experimental and theoretical partners in order to develop multiscale research in organic and inorganic materials. The goal of this defragmentation and interdisciplinary collaboration is to develop understanding across length scales, which will enable the full potential of third generation concepts to be evaluated in practise, for societal and industrial applications.

  6. Novel Nanophosphors for High Efficiency Fluorescent Lamps

    Energy Technology Data Exchange (ETDEWEB)

    Alok Srivatava

    2007-03-31

    This is the Final Report of the Novel Nanophosphors for High Efficiency Fluorescent Lamps, Department of Energy (DOE). The overall goal of this three-year program is to develop novel hybrid phosphors by coating commercially available lamp phosphors with highly stable wide band-gap nanocrystalline phosphors (NCP). The prime technical approach is the development of NCP quantum-splitting phosphor (QSP) and ultra-violet (UV) emitting phosphors with quantum efficiencies exceeding that of the conventional phosphors at 185 nm. The novel hybrid phosphors will increase the efficiency of the fluorescent lamps by up to 32%, enabling total energy savings of 0.26 quads, the reduction in the U.S. energy bill by $6.5 billion and the reduction of the annual carbon emission by 4.1 billion kilogram. Our work started by investigating through modeling calculations the requirement for the particle size of the NCP. Our work to develop suitable nanocrystalline phosphors started with the known oxide quantum splitting and UV emitting phosphors. We demonstrated several synthesis techniques for the production of high quality nanocrystalline materials that crystallizes in the desired phase and with the desired particle size. In collaboration with our subcontractor we demonstrated the feasibility for the manufacture of NC phosphors. We also demonstrated novel techniques of coating the NCP on the surface of micron sized phosphors. Our chief achievement pertains to the successful testing of the coated hybrid phosphor systems in linear fluorescent lamps. In linear fluorescent lamp tests, we have demonstrated up to 7% increase in the efficacy of hybrid phosphors over the conventional (uncoated) phosphors. We have also demonstrated the improvement in the lumen maintenance of the coated phosphors. A hybrid phosphor system based on the commercial red emitting phosphor, Y{sub 2}O{sub 3}:Eu{sup 3+} did not show the anticipated improvement in lamp efficacy. We explored the reasons for this observation

  7. EMMP :a highly efficient membership management protocol

    Institute of Scientific and Technical Information of China (English)

    LI Renfa; XIE Yunlong; WEN Jigang; YUE Guangxue

    2007-01-01

    Gossip (or epidemic) algorithms have recently become popular solutions to multicast message dissemination in peer-to-peer systems.Nevertheless,it is not straightforward to apply gossip to on-demand streaming because it often fails to achieve a timely delivery.To solve this problem and taking into account the characteristic of peers randomly joining and leaving in peer-to-peer systems,an Efficient Membership Management Protocol (EMMP) has been presented.Every node only needs to keep contact with O (log(N)) nodes,and EMMP can support the reliable dissemination of messages.Considering the "distance" between peers,it causes the major data to be transmitted in a local area and reduces the backbone's traffic,and speeds up the dissemination of messages between peers.This paper has adopted the"goodfriend" mechanism to reduce the influence on the system when a peer fails or leaves.Simulation results show that EMMP is highly efficient,and both the redundancy and the delay of the system are well solved.

  8. Highly Stretchable 2D Fabrics for Wearable Triboelectric Nanogenerator under Harsh Environments.

    Science.gov (United States)

    Kim, Kyeong Nam; Chun, Jinsung; Kim, Jin Woong; Lee, Keun Young; Park, Jang-Ung; Kim, Sang-Woo; Wang, Zhong Lin; Baik, Jeong Min

    2015-06-23

    Highly stretchable 2D fabrics are prepared by weaving fibers for a fabric-structured triboelectric nanogenerator (FTENG). The fibers mainly consist of Al wires and polydimethylsiloxane (PDMS) tubes with a high-aspect-ratio nanotextured surface with vertically aligned nanowires. The fabrics were produced by interlacing the fibers, which was bonded to a waterproof fabric for all-weather use for fabric-structured triboelectric nanogenerator (FTENG). It showed a stable high-output voltage and current of 40 V and 210 μA, corresponding to an instantaneous power output of 4 mW. The FTENG also exhibits high robustness behavior even after 25% stretching, enough for use in smart clothing applications and other wearable electronics. For wearable applications, the nanogenerator was successfully demonstrated in applications of footstep-driven large-scale power mats during walking and power clothing attached to the elbow.

  9. Fabrication of laser deposited high-quality multilayer zone plates for hard X-ray nanofocusing

    Energy Technology Data Exchange (ETDEWEB)

    Eberl, Christian; Döring, Florian; Liese, Tobias; Schlenkrich, Felix; Roos, Burkhard; Hahn, Matthias [Institut für Materialphysik, University of Göttingen, Friedrich-Hund-Platz 1, 37077 Göttingen (Germany); Hoinkes, Thomas; Rauschenbeutel, Arno [Vienna Center for Quantum Science and Technology, TU Wien – Atominstitut, Stadionallee 2, 1020 Wien (Austria); Osterhoff, Markus; Salditt, Tim [Institut für Röntgenphysik, University of Göttingen, Friedrich-Hund-Platz 1, 37077 Göttingen (Germany); Krebs, Hans-Ulrich, E-mail: krebs@ump.gwdg.de [Institut für Materialphysik, University of Göttingen, Friedrich-Hund-Platz 1, 37077 Göttingen (Germany)

    2014-07-01

    Recently, we demonstrated unprecedented sub-5 nm point focusing of hard X-rays (at 7.9 keV) based on the combination of a high gain Kirkpatrick–Baez (KB) mirror system and a high resolution W/Si multilayer zone plate (MZP). This MZP was prepared by the combination of pulsed laser deposition (PLD) and focused ion beam (FIB). Despite the small focus size, the MZP's quality suffered from sufficient but comparatively low efficiency (2%). In this paper we discuss how to overcome limitations of MZP fabrication by PLD by investigating the material systems W/Si, W/ZrO{sub 2}, and Ta{sub 2}O{sub 5}/ZrO{sub 2}. We give a detailed description on the optimization processes for the deposition of smooth multilayers with highly precise layer thicknesses on a rotating wire. Furthermore, we present our latest results regarding a Ta{sub 2}O{sub 5}/ZrO{sub 2} MZP, which has been proven already to be a system of high potential in the very first experiments as the efficiency reached 6.9% (at 18 keV).

  10. High-efficiency photonic crystal narrowband thermal emitters

    Science.gov (United States)

    Farfan, G. B.; Su, M. F.; Reda Taha, M. M.; El-Kady, I.

    2010-02-01

    Photonic crystals (PhC) are artificial structures fabricated with a periodicity in the dielectric function. This periodic electromagnetic potential results in creation of energy bandgaps where photon propagation is prohibited. PhC structures have promising use in thermal applications if optimized to operate at specific thermal emission spectrum. Here, novel utilization of optimized PhC's in thermal applications is presented. We demonstrate through numerical simulation the modification of the thermal emission spectrum by a metallic photonic crystal (PhC) to create high-efficiency multispectral thermal emitters. These emitters funnel radiation from a broad emission spectrum associated with a Plancklike distribution into a prescribed narrow emission band. A detailed quantitative evaluation of the spectral and power efficiencies of a PhC thermal emitter and its portability across infrared (IR) spectral bands are provided. We show an optimized tungsten PhC with a predominant narrow-band emission profile with an emitter efficiency that is more than double that of an ideal blackbody and ~65-75% more power-efficiency across the IR spectrum. We also report on using optimal three-dimensional Lincoln log photonic crystal (LL-PhC) emitters for thermophotovoltaic (TPV) generation as opposed to using a passive filtering approach to truncate the broadband thermal source emission to match the bandgap of a photovoltaic (PV) cell. The emitter performance is optimized for the 1-2μm PV band using different PhC materials, specifically copper, silver and gold. The use of the proposed PhC in TPV devices can produce significant energy savings not reported before. The optimal design of the PhC geometry is obtained by implementing a variety of optimization methods integrated with artificial intelligence (AI) algorithms.

  11. High Efficiency Ka-Band Spatial Combiner

    Directory of Open Access Journals (Sweden)

    D. Passi

    2014-12-01

    Full Text Available A Ka-Band, High Efficiency, Small Size Spatial Combiner (SPC is proposed in this paper, which uses an innovatively matched quadruple Fin Lines to microstrip (FLuS transitions. At the date of this paper and at the Author's best knowledge no such FLuS innovative transitions have been reported in literature before. These transitions are inserted into a WR28 waveguide T-junction, in order to allow the integration of 16 Monolithic Microwave Integrated Circuit (MMIC Solid State Power Amplifiers (SSPA's. A computational electromagnetic model using the finite elements method has been implemented. A mean insertion loss of 2 dB is achieved with a return loss better the 10 dB in the 31-37 GHz bandwidth.

  12. Design of High Efficient MPPT Solar Inverter

    Directory of Open Access Journals (Sweden)

    Sunitha K. A.

    2017-01-01

    Full Text Available This work aims to design a High Efficient Maximum Power Point Tracking (MPPT Solar Inverter. A boost converter is designed in the system to boost the power from the photovoltaic panel. By this experimental setup a room consisting of 500 Watts load (eight fluorescent tubes is completely controlled. It is aimed to decrease the maintenance cost. A microcontroller is introduced for tracking the P&O (Perturb and Observe algorithm used for tracking the maximum power point. The duty cycle for the operation of the boost convertor is optimally adjusted by using MPPT controller. There is a MPPT charge controller to charge the battery as well as fed to inverter which runs the load. Both the P&O scheme with the fixed variation for the reference current and the intelligent MPPT algorithm were able to identify the global Maximum power point, however the performance of the MPPT algorithm was better.

  13. Environmentally Printing Efficient Organic Tandem Solar Cells with High Fill Factors: A Guideline Towards 20% Power Conversion Efficiency

    DEFF Research Database (Denmark)

    Li, Ning; Baran, Derya; Spyropoulos, George D.

    2014-01-01

    The tandem concept involves stacking two or more cells with complementary absorption spectra in series or parallel connection, harvesting photons at the highest possible potential. It is strongly suggested that the roll-to-roll production of organic solar cells will employ the tandem concept...... to enhance the power conversion efficiency (PCE). However, due to the undeveloped deposition techniques, the challenges in ink formulation as well as the lack of commercially available high performance active materials, roll-to-roll fabrication of highly efficient organic tandem solar cells currently...... presents a major challenge. The reported high PCE values from lab-scale spin-coated devices are, of course, representative, but not helpful for commercialization. Here, organic tandem solar cells with exceptionally high fill factors and PCE values of 7.66% (on glass) and 5.56% (on flexible substrate...

  14. A high-efficiency superhydrophobic plasma separator.

    Science.gov (United States)

    Liu, Changchun; Liao, Shih-Chuan; Song, Jinzhao; Mauk, Michael G; Li, Xuanwen; Wu, Gaoxiang; Ge, Dengteng; Greenberg, Robert M; Yang, Shu; Bau, Haim H

    2016-02-01

    To meet stringent limit-of-detection specifications for low abundance target molecules, a relatively large volume of plasma is needed for many blood-based clinical diagnostics. Conventional centrifugation methods for plasma separation are not suitable for on-site testing or bedside diagnostics. Here, we report a simple, yet high-efficiency, clamshell-style, superhydrophobic plasma separator that is capable of separating a relatively large volume of plasma from several hundred microliters of whole blood (finger-prick blood volume). The plasma separator consists of a superhydrophobic top cover with a separation membrane and a superhydrophobic bottom substrate. Unlike previously reported membrane-based plasma separators, the separation membrane in our device is positioned at the top of the sandwiched whole blood film to increase the membrane separation capacity and plasma yield. In addition, the device's superhydrophobic characteristics (i) facilitates the formation of well-defined, contracted, thin blood film with a high contact angle; (ii) minimizes biomolecular adhesion to surfaces; (iii) increases blood clotting time; and (iv) reduces blood cell hemolysis. The device demonstrated a "blood in-plasma out" capability, consistently extracting 65 ± 21.5 μL of plasma from 200 μL of whole blood in less than 10 min without electrical power. The device was used to separate plasma from Schistosoma mansoni genomic DNA-spiked whole blood with a recovery efficiency of >84.5 ± 25.8%. The S. mansoni genomic DNA in the separated plasma was successfully tested on our custom-made microfluidic chip by using loop mediated isothermal amplification (LAMP) method.

  15. Silicone Adhesives for High Temperature Inflatable Fabrics and Polymer Films Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Thin films, elastomeric materials, high temperature fabrics and adhesives that are capable of withstanding thermal extremes (-130oC to 500oC) are highly desirable...

  16. High-irradiance effects in femosecond laser fabrication

    Directory of Open Access Journals (Sweden)

    Buividas Ričardas

    2013-11-01

    Full Text Available Laser micro-fabrication and micro-structuring of materials is usually carried out at the conditions close to the dielectric breakdown. Interplay between multi-photon and avalanche generation of electrons and thermal relaxation become critically important at those conditions in photo-polymerization, waveguide writing in glasses and for creation of new materials at the focal region. Relevant mechanisms of structuring are reviewed and discussed.

  17. High collection efficiency thin film diamond particle detectors

    Energy Technology Data Exchange (ETDEWEB)

    Bergonzo, P.; Foulon, F.; Marshall, R.D.; Jany, C.; Brambilla, A. [CEA/Saclay, Gif-sur-Yvette (France); McKeag, R.D.; Jackman, R.B. [University College, London (United Kingdom)

    1998-12-31

    Diamond is a resilient material with rather extreme electronic properties. As such it is an interesting candidate for the fabrication of high performance solid state particle detectors. However, the commercially accessible form of diamond, grown by chemical vapor deposition (CVD) methods, is polycrystalline in nature and often displays rather poor electrical characteristics. This paper considers ways in which this material may be used to form alpha particle detectors with useful performance levels. One approach adopted has been to reduce the impurity levels within the feed-stock gases that are used to grow the diamond films. This has enabled significant improvements to be achieved in the mean carrier drift distance within the films leading to alpha detectors with up to 40% collection efficiencies. An alternative approach explored is the use of planar device geometries whereby charge collection is limited to the top surface of the diamond which comprises higher quality material than the bulk of the film. This has lead to collection efficiencies of 70%, the highest yet reported for polycrystalline CVD diamond based detectors. Techniques for improving the characteristics of these devices further are discussed.

  18. High efficiency holographic Bragg grating with optically prolonged memory

    Science.gov (United States)

    Khoo, Iam Choon; Chen, Chun-Wei; Ho, Tsung-Jui

    2016-10-01

    In this paper, we show that photosensitive azo-dye doped Blue-phase liquid crystals (BPLC) formed by natural molecular self-assembly are capable of high diffraction efficiency holographic recording with memory that can be prolonged from few seconds to several minutes by uniform illumination with the reference beam. Operating in the Bragg regime, we have observed 50 times improvement in the grating diffraction efficiency and shorter recording time compared to previous investigations. The enabling mechanism is BPLC’s lattice distortion and index modulation caused by the action of light on the azo-dopant; upon photo-excitation, the azo-molecules undergo transformation from the oblong-shaped Trans-state to the bent-shaped Cis-state, imparting disorder and also cause the surrounding BPLC molecules to undergo coupled flow & reorientation leading to lattice distortion and index modulation. We also showed that the same mechanism at work here that facilitates lattice distortion can be used to frustrate free relaxation of the lattice distortion, thereby prolonging the lifetime of the written grating, provided the reference beam is kept on after recording. Due to the ease in BPLC fabrication and the availability of azo-dopants with photosensitivity throughout the entire visible spectrum, one can optimize the controlling material and optical parameters to obtain even better performance.

  19. Fabrication of ordered NiO coated Si nanowire array films as electrodes for a high performance lithium ion battery.

    Science.gov (United States)

    Qiu, M C; Yang, L W; Qi, X; Li, Jun; Zhong, J X

    2010-12-01

    Highly ordered NiO coated Si nanowire array films are fabricated as electrodes for a high performance lithium ion battery via depositing Ni on electroless-etched Si nanowires and subsequently annealing. The structures and morphologies of as-prepared films are characterized by X-ray diffraction, scanning electron microscopy, and transmission electron microscopy. When the potential window versus lithium was controlled, the coated NiO can be selected to be electrochemically active to store and release Li+ ions, while highly conductive crystalline Si cores function as nothing more than a stable mechanical support and an efficient electrical conducting pathway. The hybrid nanowire array films exhibit superior cyclic stability and reversible capacity compared to that of NiO nanostructured films. Owing to the ease of large-scale fabrication and superior electrochemical performance, these hybrid nanowire array films will be promising anode materials for high performance lithium-ion batteries.

  20. High-performance rectifiers fabricated on a flexible substrate

    Science.gov (United States)

    Etor, David; Dodd, Linzi E.; Wood, David; Balocco, Claudio

    2016-11-01

    We report on the fabrication and testing of metal-insulator-metal (MIM) diodes on a flexible substrate where the thin insulating layer self-assembles as a monolayer sandwiched between the two metal electrodes. The current-voltage characteristic has a strong asymmetry and non-linearity at zero-bias. The diodes have a typical zero-bias resistance of 80 kΩ, a zero-bias curvature coefficient of 5.5 V-1, and a voltage responsivity of 3.1 kV/W at a frequency of 1 GHz. The fabrication yield was over 90%, and an encapsulation method to prevent MIM junction degradation has also been developed. The diodes show no significant degradation in performance when the substrate is stressed in a one-off bending experiment, although extensive testing does produce some loss in quality. The fabrication process is simple, cost effective, and carried out at low temperature, opening up the possibility of roll-to-roll volume manufacturing of fast MIM diodes.

  1. Efficient and facile fabrication of hierarchical carbon foams with abundant nanoscale pores for use in supercapacitors

    Energy Technology Data Exchange (ETDEWEB)

    Xiong, Wei; Yang, Gui Jun; Yang, Tae Hyeon; Jung, Yong Ju [Dept. of Chemical Engineering, Korea University of Technology and Education (KOREATECH), Cheonan (Korea, Republic of); Liu, Shan Tang [School of Chemistry and Environmental Engineering, Wuhan Institute of Technology, Wuhan (China)

    2017-03-15

    Hierarchical carbon foams (HCFs) with micro-, meso-, and macropores were successfully synthesized via a two-step process: (1) polymerization in oil-in-water (O/W) emulsions without any hard templates and (2) carbonization at 850°C. With the aim of both enhancing the stability of the emulsion and forming a micro- and mesoporous structure during the carbonization process, potassium citrate was introduced in an aqueous solution of resorcinol and formaldehyde. A series of HCFs were fabricated by changing the mass ratio of potassium citrate to total carbon sources from 0.25 to 1.5. The effect of potassium citrate on the porous structure of HCFs was investigated through nitrogen sorption tests. The prepared HCFs exhibited well-developed porous structures of micro-, meso- and macropores and high surface areas. The structural characteristics of the HCFs, including pore size distribution, surface area, and porosity, were significantly dependent on the amount of potassium citrate. It was concluded that potassium citrate greatly contributed to the formation of carbon foams with nano-sized pore structures and high porosity. Interestingly, it was found that when the mass ratio of potassium citrate to total carbon sources was 0.5, the HCFs showed the highest specific surface area (⁓1360 m{sup 2}/g). Furthermore, the capacitive performances of the HCFs were evaluated in a 6.0 M KOH aqueous solution using typical electrochemical methods such as cyclic voltammetry and galvanostatic charge/discharge tests. The capacitance of the HCFs tended to increase with the increase in surface area. In particular, the HCFs with the highest surface area also exhibited excellent electrochemical properties (high capacitance of 224 F/g at 1.0 A/g, high rate capability of 191 F/g at 10.0 A/g). These features may be attributed to both the resulting interconnected pore structure that is easily accessible to ions and the high surface area. We believe that this synthesis strategy can be easily

  2. White LED with High Package Extraction Efficiency

    Energy Technology Data Exchange (ETDEWEB)

    Yi Zheng; Matthew Stough

    2008-09-30

    The goal of this project is to develop a high efficiency phosphor converting (white) Light Emitting Diode (pcLED) 1-Watt package through an increase in package extraction efficiency. A transparent/translucent monolithic phosphor is proposed to replace the powdered phosphor to reduce the scattering caused by phosphor particles. Additionally, a multi-layer thin film selectively reflecting filter is proposed between blue LED die and phosphor layer to recover inward yellow emission. At the end of the project we expect to recycle approximately 50% of the unrecovered backward light in current package construction, and develop a pcLED device with 80 lm/W{sub e} using our technology improvements and commercially available chip/package source. The success of the project will benefit luminous efficacy of white LEDs by increasing package extraction efficiency. In most phosphor-converting white LEDs, the white color is obtained by combining a blue LED die (or chip) with a powdered phosphor layer. The phosphor partially absorbs the blue light from the LED die and converts it into a broad green-yellow emission. The mixture of the transmitted blue light and green-yellow light emerging gives white light. There are two major drawbacks for current pcLEDs in terms of package extraction efficiency. The first is light scattering caused by phosphor particles. When the blue photons from the chip strike the phosphor particles, some blue light will be scattered by phosphor particles. Converted yellow emission photons are also scattered. A portion of scattered light is in the backward direction toward the die. The amount of this backward light varies and depends in part on the particle size of phosphors. The other drawback is that yellow emission from phosphor powders is isotropic. Although some backward light can be recovered by the reflector in current LED packages, there is still a portion of backward light that will be absorbed inside the package and further converted to heat. Heat

  3. Highly efficient uniform ZnO nanostructures for an electron transport layer of inverted organic solar cells.

    Science.gov (United States)

    Kim, Sarah; Kim, Chul-Hyun; Lee, Sang Kyu; Jeong, Jun-Ho; Lee, Jihye; Jin, Sung-Ho; Shin, Won Suk; Song, Chang Eun; Choi, Jun-Hyuk; Jeong, Jong-Ryul

    2013-07-11

    A highly uniform and predesigned ZnO nanostructure fabricated by single step direct nanoimprinting was used as the efficient electron transport layer (ETL) in inverted bulk heterojunction organic solar cells. Improved photovoltaic cell efficiency with long-term stability can be observed due to the large interface between the active layer and nanostructured ZnO ETL.

  4. Ultra-High Speed Fabrication of TiO2 Photoanode by Flash Light for Dye-Sensitized Solar Cell.

    Science.gov (United States)

    Hwang, Hyun-Jun; Kim, Hak-Sung

    2015-07-01

    In this work, a new way to fabricate nanoporous TiO2 photoanode by flash light is demonstrated. TiO2 nanoparticles are sintered on FTO glass by flash light irradiation at room temperature in ambient condition, which is dramatically simple, ultrahigh speed and one-shot large area fabrication process compared to a conventional high temperature (120 °C) thermal sintering process. The effect of the flash light conditions (flash light energy, pulse numbers and pulse duration) on the nanostructures of sintered TiO2 layer, was studied and discussed using several microscopic and spectroscopic characterization techniques such as SEM, FT-IR, XRD and XPS. The sintered TiO2 photoanodes by flash light were used in DSSC and its performance were compared with that of DSSC fabricated by conventional thermal sintering process. It was found that a flash light sintered TiO2 photoanode has efficiency which is similar to that of the thermal sintered photoanode. It is expected that the newly developed flash light sintering technique of TiO2 nanoparticles would be a strong alternative to realize the room temperature and in-situ sintering of photoanode fabrication for outdoor solar cell fabrication.

  5. High efficiency diffusion molecular retention tumor targeting.

    Directory of Open Access Journals (Sweden)

    Yanyan Guo

    Full Text Available Here we introduce diffusion molecular retention (DMR tumor targeting, a technique that employs PEG-fluorochrome shielded probes that, after a peritumoral (PT injection, undergo slow vascular uptake and extensive interstitial diffusion, with tumor retention only through integrin molecular recognition. To demonstrate DMR, RGD (integrin binding and RAD (control probes were synthesized bearing DOTA (for (111 In(3+, a NIR fluorochrome, and 5 kDa PEG that endows probes with a protein-like volume of 25 kDa and decreases non-specific interactions. With a GFP-BT-20 breast carcinoma model, tumor targeting by the DMR or i.v. methods was assessed by surface fluorescence, biodistribution of [(111In] RGD and [(111In] RAD probes, and whole animal SPECT. After a PT injection, both probes rapidly diffused through the normal and tumor interstitium, with retention of the RGD probe due to integrin interactions. With PT injection and the [(111In] RGD probe, SPECT indicated a highly tumor specific uptake at 24 h post injection, with 352%ID/g tumor obtained by DMR (vs 4.14%ID/g by i.v.. The high efficiency molecular targeting of DMR employed low probe doses (e.g. 25 ng as RGD peptide, which minimizes toxicity risks and facilitates clinical translation. DMR applications include the delivery of fluorochromes for intraoperative tumor margin delineation, the delivery of radioisotopes (e.g. toxic, short range alpha emitters for radiotherapy, or the delivery of photosensitizers to tumors accessible to light.

  6. High bandgap III-V alloys for high efficiency optoelectronics

    Science.gov (United States)

    Alberi, Kirstin; Mascarenhas, Angelo; Wanlass, Mark

    2017-01-10

    High bandgap alloys for high efficiency optoelectronics are disclosed. An exemplary optoelectronic device may include a substrate, at least one Al.sub.1-xIn.sub.xP layer, and a step-grade buffer between the substrate and at least one Al.sub.1-xIn.sub.xP layer. The buffer may begin with a layer that is substantially lattice matched to GaAs, and may then incrementally increase the lattice constant in each sequential layer until a predetermined lattice constant of Al.sub.1-xIn.sub.xP is reached.

  7. High bandgap III-V alloys for high efficiency optoelectronics

    Energy Technology Data Exchange (ETDEWEB)

    Alberi, Kirstin; Mascarenhas, Angelo; Wanlass, Mark

    2017-01-10

    High bandgap alloys for high efficiency optoelectronics are disclosed. An exemplary optoelectronic device may include a substrate, at least one Al.sub.1-xIn.sub.xP layer, and a step-grade buffer between the substrate and at least one Al.sub.1-xIn.sub.xP layer. The buffer may begin with a layer that is substantially lattice matched to GaAs, and may then incrementally increase the lattice constant in each sequential layer until a predetermined lattice constant of Al.sub.1-xIn.sub.xP is reached.

  8. A general strategy for the fabrication of high performance microsupercapacitors

    KAUST Repository

    Kurra, Narendra

    2015-06-04

    We propose a generic strategy for microsupercapacitor fabrication that integrates layers of reduced graphene oxide (rGO) and pseudocapacitive materials to create electrode heterostructures with significantly improved cycling stability and performance. Our approach involves a combination of photolithography and a simple transfer method of free-standing reduced graphene oxide film onto an Au/patterned photoresist bilayer. The resulting stack (rGO/Au/patterned resist/substrate) is then used for the electrochemical deposition of various pseudocapacitive materials before the final step of lift-off. To prove the viability of this method, we have successfully fabricated microsupercapacitors (MSCs) with the following interdigitated electrode heterostructures: MnO2/rGO, Co(OH)2/rGO and PANI/rGO. These MSCs show better performance and cycling stability compared to the single layer, (i.e., rGO-free) counterparts. The interdigitated electrode heterostructures result in MSCs with energy densities in the range of 3–12 mW h/cm3 and power densities in the range of 400–1200 mW/cm3, which is superior to the Li thin film batteries (E=10 mW h/cm3), carbon, and metal oxide based MSCs (E=1–6 mW h/cm3) while device energy densities are in the range of 1.3–5.3 mW h/cm3, corresponding power densities are in the range of 178–533 mW/cm3. These results can be explained by a facilitated nucleation model, where surface topology of the rGO film creates a favorable environment for the nucleation and growth of pseudocapacitive materials with strong interfacial contacts and enhanced surface area. This approach opens up a new avenue in fabricating MSCs involving a variety of heterostructures combining electrical double layer carbon type with Faradaic pseudocapacitive materials for enhanced electrochemical performance.

  9. Ultrafast Flame Annealing of TiO2 Paste for Fabricating Dye-Sensitized and Perovskite Solar Cells with Enhanced Efficiency.

    Science.gov (United States)

    Kim, Jung Kyu; Chai, Sung Uk; Cho, Yoonjun; Cai, Lili; Kim, Sung June; Park, Sangwook; Park, Jong Hyeok; Zheng, Xiaolin

    2017-09-20

    Mesoporous TiO2 nanoparticle (NP) films are broadly used as electrodes in photoelectrochemical cells, dye-sensitized solar cells (DSSCs), and perovskite solar cells (PSCs). State-of-the-art mesoporous TiO2 NP films for these solar cells are fabricated by annealing TiO2 paste-coated fluorine-doped tin oxide glass in a box furnace at 500 °C for ≈30 min. Here, the use of a nontraditional reactor, i.e., flame, is reported for the high throughput and ultrafast annealing of TiO2 paste (≈1 min). This flame-annealing method, compared to conventional furnace annealing, exhibits three distinct benefits. First, flame removes polymeric binders in the initial TiO2 paste more completely because of its high temperature (≈1000 °C). Second, flame induces strong interconnections between TiO2 nanoparticles without affecting the underlying transparent conducting oxide substrate. Third, the flame-induced carbothermic reduction on the TiO2 surface facilitates charge injection from the dye/perovskite to TiO2 . Consequently, when the flame-annealed mesoporous TiO2 film is used to fabricate DSSCs and PSCs, both exhibit enhanced charge transport and higher power conversion efficiencies than those fabricated using furnace-annealed TiO2 films. Finally, when the ultrafast flame-annealing method is combined with a fast dye-coating method to fabricate DSSC devices, its total fabrication time is reduced from over 3 h to ≈10 min. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  10. Fabrication and Application of High Quality Diamond-coated Tools

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    Diamond-coated tools were fabricated using Co-cemented carbide inserts as substrates by the electronically aided hot filament chemical vapor deposition (EACVD). An amount of additive in an acid solution was used to promote the Co etching of the substrate surface. The surface of the WC-Co substrate was decarburized by microwave plasma with Ar-H 2 gas. Effect of the new substrate pretreatment on the adhesion of diamond films was investigated. A boron-doped solution was brushed on the tool surface to diffuse ...

  11. Application of High-Temperature Mold Materials to Die Cast Copper Motor Rotor for Improved Efficiency

    Energy Technology Data Exchange (ETDEWEB)

    John G. Cowie; Edwin F. Brush, Jr.; Dale T. Peters; Stephen P. Midson; Darryl J. Van Son

    2003-05-01

    The objective of the study, Application of High-Temperature Mold Materials to Die Cast Copper Motor Rotor for Improved Efficiency, was to support the Copper Development Association (CDA) in its effort to design, fabricate and demonstrate mold technologies designed to withstand the copper motor rotor die casting environment for an economically acceptable life. The anticipated result from the compiled data and tests were to: (1) identify materials suitable for die casting copper, (2) fabricate motor rotor molds and (3) supply copper rotor motors for testing in actual compressor systems. Compressor manufacturers can apply the results to assess the technical and economical viability of copper rotor motors.

  12. Series-Tuned High Efficiency RF-Power Amplifiers

    DEFF Research Database (Denmark)

    Vidkjær, Jens

    2008-01-01

    An approach to high efficiency RF-power amplifier design is presented. It addresses simultaneously efficiency optimization and peak voltage limitations when transistors are pushed towards their power limits.......An approach to high efficiency RF-power amplifier design is presented. It addresses simultaneously efficiency optimization and peak voltage limitations when transistors are pushed towards their power limits....

  13. High-Performance Permanent Magnets for Energy-Efficient Devices

    Science.gov (United States)

    Hadjipanayis, George

    2012-02-01

    Permanent magnets (PMs) are indispensable for many commercial applications including the electric, electronic and automobile industries, communications, information technologies and automatic control engineering. In most of these applications, an increase in the magnetic energy density of the PM, usually presented via the maximum energy product (BH)max, immediately increases the efficiency of the whole device and makes it smaller and lighter. Worldwide demand for high performance permanent magnets has increased dramatically in the past few years driven by hybrid and electric cars, wind turbines and other power generation systems. New energy challenges in the world require devices with higher energy efficiency and minimum environmental impact. The potential of 3d-4f compounds which revolutionized the PM science and technology is almost fully utilized, and the supply of 4f rare earth elements does not seem to be much longer assured. This talk will address the major principles guiding the development of PMs and overview state-of-the-art theoretical and experimental research. Recent progress in the development of nanocomposite PMs, consisting of a fine (at the scale of the magnetic exchange length) mixture of phases with high magnetization and large magnetic hardness will be discussed. Fabrication of such PMs is currently the most promising way to boost the (BH)max, while simultaneously decreasing, at least partially, the reliance on the rare earth elements. Special attention will be paid to the impact which the next-generation high-(BH)max magnets is expected to have on existing and proposed energy-saving technologies.

  14. Magnetic Refrigeration Technology for High Efficiency Air Conditioning

    Energy Technology Data Exchange (ETDEWEB)

    Boeder, A; Zimm, C

    2006-09-30

    Magnetic refrigeration was investigated as an efficient, environmentally friendly, flexible alternative to conventional residential vapor compression central air conditioning systems. Finite element analysis (FEA) models of advanced geometry active magnetic regenerator (AMR) beds were developed to minimize bed size and thus magnet mass by optimizing geometry for fluid flow and heat transfer and other losses. Conventional and magnetocaloric material (MCM) regenerator fabrication and assembly techniques were developed and advanced geometry passive regenerators were built and tested. A subscale engineering prototype (SEP) magnetic air conditioner was designed, constructed and tested. A model of the AMR cycle, combined with knowledge from passive regenerator experiments and FEA results, was used to design the regenerator beds. A 1.5 Tesla permanent magnet assembly was designed using FEA and the bed structure and plenum design was extensively optimized using FEA. The SEP is a flexible magnetic refrigeration platform, with individually instrumented beds and high flow rate and high frequency capability, although the current advanced regenerator geometry beds do not meet performance expectations, probably due to manufacturing and assembly tolerances. A model of the AMR cycle was used to optimize the design of a 3 ton capacity magnetic air conditioner, and the system design was iterated to minimize external parasitic losses such as heat exchanger pressure drop and fan power. The manufacturing cost for the entire air conditioning system was estimated, and while the estimated SEER efficiency is high, the magnetic air conditioning system is not cost competitive as currently configured. The 3 ton study results indicate that there are other applications where magnetic refrigeration is anticipated to have cost advantages over conventional systems, especially applications where magnetic refrigeration, through the use of its aqueous heat transfer fluid, could eliminate intermediate

  15. Non-iridescent transmissive structural color filter featuring highly efficient transmission and high excitation purity.

    Science.gov (United States)

    Shrestha, Vivek Raj; Lee, Sang-Shin; Kim, Eun-Soo; Choi, Duk-Yong

    2014-05-12

    Nanostructure based color filtering has been considered an attractive replacement for current colorant pigmentation in the display technologies, in view of its increased efficiencies, ease of fabrication and eco-friendliness. For such structural filtering, iridescence relevant to its angular dependency, which poses a detrimental barrier to the practical development of high performance display and sensing devices, should be mitigated. We report on a non-iridescent transmissive structural color filter, fabricated in a large area of 76.2 × 25.4 mm(2), taking advantage of a stack of three etalon resonators in dielectric films based on a high-index cavity in amorphous silicon. The proposed filter features a high transmission above 80%, a high excitation purity of 0.93 and non-iridescence over a range of 160°, exhibiting no significant change in the center wavelength, dominant wavelength and excitation purity, which implies no change in hue and saturation of the output color. The proposed structure may find its potential applications to large-scale display and imaging sensor systems.

  16. Non-iridescent Transmissive Structural Color Filter Featuring Highly Efficient Transmission and High Excitation Purity

    Science.gov (United States)

    Shrestha, Vivek Raj; Lee, Sang-Shin; Kim, Eun-Soo; Choi, Duk-Yong

    2014-05-01

    Nanostructure based color filtering has been considered an attractive replacement for current colorant pigmentation in the display technologies, in view of its increased efficiencies, ease of fabrication and eco-friendliness. For such structural filtering, iridescence relevant to its angular dependency, which poses a detrimental barrier to the practical development of high performance display and sensing devices, should be mitigated. We report on a non-iridescent transmissive structural color filter, fabricated in a large area of 76.2 × 25.4 mm2, taking advantage of a stack of three etalon resonators in dielectric films based on a high-index cavity in amorphous silicon. The proposed filter features a high transmission above 80%, a high excitation purity of 0.93 and non-iridescence over a range of 160°, exhibiting no significant change in the center wavelength, dominant wavelength and excitation purity, which implies no change in hue and saturation of the output color. The proposed structure may find its potential applications to large-scale display and imaging sensor systems.

  17. Multi-petascale highly efficient parallel supercomputer

    Energy Technology Data Exchange (ETDEWEB)

    Asaad, Sameh; Bellofatto, Ralph E.; Blocksome, Michael A.; Blumrich, Matthias A.; Boyle, Peter; Brunheroto, Jose R.; Chen, Dong; Cher, Chen -Yong; Chiu, George L.; Christ, Norman; Coteus, Paul W.; Davis, Kristan D.; Dozsa, Gabor J.; Eichenberger, Alexandre E.; Eisley, Noel A.; Ellavsky, Matthew R.; Evans, Kahn C.; Fleischer, Bruce M.; Fox, Thomas W.; Gara, Alan; Giampapa, Mark E.; Gooding, Thomas M.; Gschwind, Michael K.; Gunnels, John A.; Hall, Shawn A.; Haring, Rudolf A.; Heidelberger, Philip; Inglett, Todd A.; Knudson, Brant L.; Kopcsay, Gerard V.; Kumar, Sameer; Mamidala, Amith R.; Marcella, James A.; Megerian, Mark G.; Miller, Douglas R.; Miller, Samuel J.; Muff, Adam J.; Mundy, Michael B.; O' Brien, John K.; O' Brien, Kathryn M.; Ohmacht, Martin; Parker, Jeffrey J.; Poole, Ruth J.; Ratterman, Joseph D.; Salapura, Valentina; Satterfield, David L.; Senger, Robert M.; Smith, Brian; Steinmacher-Burow, Burkhard; Stockdell, William M.; Stunkel, Craig B.; Sugavanam, Krishnan; Sugawara, Yutaka; Takken, Todd E.; Trager, Barry M.; Van Oosten, James L.; Wait, Charles D.; Walkup, Robert E.; Watson, Alfred T.; Wisniewski, Robert W.; Wu, Peng

    2015-07-14

    A Multi-Petascale Highly Efficient Parallel Supercomputer of 100 petaOPS-scale computing, at decreased cost, power and footprint, and that allows for a maximum packaging density of processing nodes from an interconnect point of view. The Supercomputer exploits technological advances in VLSI that enables a computing model where many processors can be integrated into a single Application Specific Integrated Circuit (ASIC). Each ASIC computing node comprises a system-on-chip ASIC utilizing four or more processors integrated into one die, with each having full access to all system resources and enabling adaptive partitioning of the processors to functions such as compute or messaging I/O on an application by application basis, and preferably, enable adaptive partitioning of functions in accordance with various algorithmic phases within an application, or if I/O or other processors are underutilized, then can participate in computation or communication nodes are interconnected by a five dimensional torus network with DMA that optimally maximize the throughput of packet communications between nodes and minimize latency.

  18. High efficient wind-hydrogen facility

    Energy Technology Data Exchange (ETDEWEB)

    Bolcich, J.C. [Centro Atomico Bariloche, San Carlos de Bariloche, Rio Negro (Argentina); Bolcich, A.; Bolcich, D.; Wandyk, N. [ZVALT S.R.L., San Carlos de Bariloche, Rio Negro (Argentina)

    2001-06-01

    Considered a high efficiency and economical option for the conversion of wind energy, a new concept was developed in Patagonia, Argentina. It is called the Ducted Multirotor-Wind Energy Converter (DM-WEC) and was designed to be used in remote areas. Under study is the first prototype (10-30 Kilowatts), while the second prototype (3-5 Kilowatt) is being installed and is undergoing testing. This second prototype is of the multirotor type with the duct for air canalization as an added alternative. In this presentation, the authors described the technical attributes of the two prototypes and provided an evaluation of the potential for hydrogen production using small electrolysis units. They also included a comparison between the ducted and non-ducted prototypes with regard to maximum power attainable. The results obtained so far indicated that it represents an affordable energy source for remote areas with a higher power per unit cross section swept area. The rotating parts are encapsulated, reducing the noise level and vibrations. figs.

  19. A high-efficiency aerothermoelastic analysis method

    Science.gov (United States)

    Wan, ZhiQiang; Wang, YaoKun; Liu, YunZhen; Yang, Chao

    2014-06-01

    In this paper, a high-efficiency aerothermoelastic analysis method based on unified hypersonic lifting surface theory is established. The method adopts a two-way coupling form that couples the structure, aerodynamic force, and aerodynamic thermo and heat conduction. The aerodynamic force is first calculated based on unified hypersonic lifting surface theory, and then the Eckert reference temperature method is used to solve the temperature field, where the transient heat conduction is solved using Fourier's law, and the modal method is used for the aeroelastic correction. Finally, flutter is analyzed based on the p-k method. The aerothermoelastic behavior of a typical hypersonic low-aspect ratio wing is then analyzed, and the results indicate the following: (1) the combined effects of the aerodynamic load and thermal load both deform the wing, which would increase if the flexibility, size, and flight time of the hypersonic aircraft increase; (2) the effect of heat accumulation should be noted, and therefore, the trajectory parameters should be considered in the design of hypersonic flight vehicles to avoid hazardous conditions, such as flutter.

  20. Highly Efficient Contactless Electrical Energy Transmission System

    Science.gov (United States)

    Ayano, Hideki; Nagase, Hiroshi; Inaba, Hiromi

    This paper proposes a new concept for a contactless electrical energy transmission system for an elevator and an automated guided vehicle. The system has rechargeable batteries on the car and electrical energy is supplied at a specific place. When electric power is supplied to the car, it runs automatically and approaches the battery charger. Therefore, a comparatively large gap is needed between the primary transformer at the battery charger and the secondary transformer on the car in order to prevent damage which would be caused by a collision. In this case, a drop of the transformer coupling rate due to the large gap must be prevented. In conventional contactless electrical energy transmission technology, since electric power is received by a pick-up coil from a power line, a large-sized transformer is required. And when the distance over which the car runs is long, the copper loss of the line also increases. The developed system adopts a high frequency inverter using a soft switching method to miniaturize the transformer. The system has a coupling rate of 0.88 for a transformer gap length of 10mm and can operate at 91% efficiency.

  1. Large-Area and High-Throughput PDMS Microfluidic Chip Fabrication Assisted by Vacuum Airbag Laminator

    Directory of Open Access Journals (Sweden)

    Shuting Xie

    2017-07-01

    Full Text Available One of the key fabrication steps of large-area microfluidic devices is the flexible-to-hard sheet alignment and pre-bonding. In this work, the vacuum airbag laminator (VAL which is commonly used for liquid crystal display (LCD production has been applied for large-area microfluidic device fabrication. A straightforward, efficient, and low-cost method has been achieved for 400 × 500 mm2 microfluidic device fabrication. VAL provides the advantages of precise alignment and lamination without bubbles. Thermal treatment has been applied to achieve strong PDMS–glass and PDMS–PDMS bonding with maximum breakup pressure of 739 kPa, which is comparable to interference-assisted thermal bonding method. The fabricated 152 × 152 mm2 microfluidic chip has been successfully applied for droplet generation and splitting.

  2. Combined AFM nano-machining and reactive ion etching to fabricate high aspect ratio structures.

    Science.gov (United States)

    Peng, Ping; Shi, Tielin; Liao, Guanglan; Tang, Zirong

    2010-11-01

    In this paper, a new combined method of sub-micron high aspect ratio structure fabrication is developed which can be used for production of nano imprint template. The process includes atomic force microscope (AFM) scratch nano-machining and reactive ion etching (RIE) fabrication. First, 40 nm aluminum film was deposited on the silicon substrate by magnetron sputtering, and then sub-micron grooves were fabricated on the aluminum film by nano scratch using AFM diamond tip. As aluminum film is a good mask for etching silicon, high aspect ratio structures were finally fabricated by RIE process. The fabricated structures were studied by SEM, which shows that the grooves are about 400 nm in width and 5 microm in depth. To obtain sub-micron scale groove structures on the aluminum film, experiments of nanomachining on aluminum films under various machining conditions were conducted. The depths of the grooves fabricated using different scratch loads were also studied by the AFM. The result shows that the material properties of the film/substrate are elastic-plastic following nearly a bilinear law with isotropic strain hardening. Combined AFM nanomachining and RIE process provides a relative lower cost nano fabrication technique than traditional e-beam lithography, and it has a good prospect in nano imprint template fabrication.

  3. Bipolarly stacked electrolyser for energy and space efficient fabrication of supercapacitor electrodes

    Science.gov (United States)

    Liu, Xiaojuan; Wu, Tao; Dai, Zengxin; Tao, Keran; Shi, Yong; Peng, Chuang; Zhou, Xiaohang; Chen, George Z.

    2016-03-01

    Stacked electrolysers with titanium bipolar plates are constructed for electrodeposition of polypyrrole electrodes for supercapacitors. The cathode side of the bipolar Ti plates are pre-coated with activated carbon. In this new design, half electrolysis occurs which significantly lowers the deposition voltage. The deposited electrodes are tested in a symmetrical unit cell supercapacitor and an asymmetrical supercapacitor stack. Both devices show excellent energy storage performances and the capacitance values are very close to the design value, suggesting a very high current efficiency during the electrodeposition. The electrolyser stack offers multi-fold benefits for preparation of conducting polymer electrodes, i.e. low energy consumption, facile control of the electrode capacitance and simultaneous preparation of a number of identical electrodes. Therefore, the stacked bipolar electrolyser is a technology advance that offers an engineering solution for mass production of electrodeposited conducting polymer electrodes for supercapacitors.

  4. High performance mask fabrication process for the next-generation mask production

    Science.gov (United States)

    Yagawa, Keisuke; Ugajin, Kunihiro; Suenaga, Machiko; Kobayashi, Yoshihito; Motokawa, Takeharu; Hagihara, Kazuki; Saito, Masato; Itoh, Masamitsu

    2014-07-01

    ArF immersion lithography combined with double patterning has been used for fabricating below half pitch 40nm devices. However, when pattern size shrinks below 20nm, we must use new technology like quadruple patterning process or next generation lithography (NGL) solutions. Moreover, with change in lithography tool, next generation mask production will be needed. According to ITRS 2013, fabrication of finer patterns less than 15nm will be required on mask plate in NGL mask production 5 years later [1]. In order to fabricate finer patterns on mask, higher resolution EB mask writer and high performance fabrication process will be required. In a previous study, we investigated a potential of mask fabrication process for finer patterning and achieved 17nm dense line pattern on mask plate by using VSB (Variable Shaped Beam) type EB mask writer and chemically amplified resist [2][3]. After a further investigation, we constructed higher performance mask process by using new EB mask writer EBM9000. EBM9000 is the equipment supporting hp16nm generation's photomask production and has high accuracy and high throughput. As a result, we achieved 15.5nm pattern on mask with high productivity. Moreover, from evaluation of isolated pattern, we proved that current mask process has the capability for sub-10nm pattern. These results show that the performance of current mask fabrication process have the potential to fabricate the next-generation mask.

  5. Surface nanoscale axial photonics: Robust fabrication of high quality factor microresonators

    CERN Document Server

    Sumetsky, M; Dulashko, Y; Fini, J M; Liu, X; Monberg, E M; Taunay, T F

    2011-01-01

    Recently introduced Surface Nanoscale Axial Photonics (SNAP) makes it possible to fabricate high Q-factor microresonators and other photonic microdevices by dramatically small deformation of the optical fiber surface. To become a practical and robust technology, the SNAP platform requires methods enabling reproducible modification of the optical fiber radius at nanoscale. In this Letter, we demonstrate super-accurate fabrication of high Q-factor microresonators by nanoscale modification of the optical fiber radius and refractive index using the CO2 laser and the UV excimer laser beam exposures. The achieved fabrication accuracy is better than 2 angstroms in variation of the effective fiber radius.

  6. Fabrication of High Aspect Ratio SU-8 Structures for Integrated Spectrometers

    DEFF Research Database (Denmark)

    Anhøj, Thomas Aarøe

    2007-01-01

    of photolithography. Successful fabrication of re ection gratings requires a high degree of precision in the photolithographic process. The fabrication process has thus been optimized by optimizing the photolithographic process for fabrication of high aspect ratio structures, i.e. structures with details...... that are small compared to the height of the structure. A decisive factor is the ability of the process to separate closely- spaced structures. The primary measure of quality is thus the aspect ratio of the narrowest trench which it is possible to resolve in the lithographic process. The optimization...

  7. High numerical aperture imaging by using multimode fibers with micro-fabricated optics

    KAUST Repository

    Bianchi, Silvio

    2014-01-01

    Controlling light propagation into multimode optical fibers through spatial light modulators provides highly miniaturized endoscopes and optical micromanipulation probes. We increase the numerical aperture up to nearly 1 by micro-optics fabricated on the fiber-end.

  8. TRUSSELATOR - On-Orbit Fabrication of High Performance Support Structures for Solar Arrays Project

    Data.gov (United States)

    National Aeronautics and Space Administration — The Trusselator technology will enable on-orbit fabrication of support structures for high-power solar arrays and large antennas, achieving order-of-magnitude...

  9. TRUSSELATOR - On-Orbit Fabrication of High Performance Support Structures for Solar Arrays Project

    Data.gov (United States)

    National Aeronautics and Space Administration — TUI proposes to develop and demonstrate a process for fabricating high-performance composite truss structures on-orbit and integrating them with thin film solar cell...

  10. Fabrication of Pd Nanoparticles Embedded C@Fe3O4 Core-Shell Hybrid Nanospheres: An Efficient Catalyst for Cyanation in Aryl Halides.

    Science.gov (United States)

    Suresh Kumar, Basuvaraj; Amali, Arlin Jose; Pitchumani, Kasi

    2015-10-21

    Isolated chemical reactors were fabricated by integrating catalytically active sites (Pd) with magnetic functionality (Fe3O4) along with carbon while preserving the constituents functional properties to realize the structure-property relationship of Pd by comparing the catalytic activity of spherical Pd NPs with cubical Pd NPs for cyanation in aryl halides using K4[Fe(CN)6] as a green cyanating agent to yield corresponding nitriles. The superior catalytic reactivity of the cubical Pd NPs is attributed to the larger number of {100} surface facets. The TEM images of reused catalyst shows the change in structure from cubical to spherical nanoparticles, attributed to the efficient leaching susceptibility of Pd {100} surface facets. The cubical Pd NPs on carbon@Fe3O4 is attractive in view of its high catalytic efficiency, easy synthesis, magnetic separability, environmental friendliness, high stability, gram scale applicability, and reusability.

  11. Towards high efficiency segmented thermoelectric unicouples

    DEFF Research Database (Denmark)

    Pham, Hoang Ngan; Christensen, Dennis Valbjørn; Snyder, Gerald Jeffrey

    2014-01-01

    Segmentation of thermoelectric (TE) materials is a widely used solution to improve the efficiency of thermoelectric generators over a wide working temperature range. However, the improvement can only be obtained with appropriate material selections. In this work, we provide an overview...... of the theoretical efficiency of the best performing unicouples designed from segmenting the state-of-the-art TE materials. The efficiencies are evaluated using a 1D numerical model which includes all thermoelectric effects, heat conduction, Joule effects and temperature dependent material properties, but neglects...

  12. High efficiency quasi-monochromatic infrared emitter

    Science.gov (United States)

    Brucoli, Giovanni; Bouchon, Patrick; Haïdar, Riad; Besbes, Mondher; Benisty, Henri; Greffet, Jean-Jacques

    2014-02-01

    Incandescent radiation sources are widely used as mid-infrared emitters owing to the lack of alternative for compact and low cost sources. A drawback of miniature hot systems such as membranes is their low efficiency, e.g., for battery powered systems. For targeted narrow-band applications such as gas spectroscopy, the efficiency is even lower. In this paper, we introduce design rules valid for very generic membranes demonstrating that their energy efficiency for use as incandescent infrared sources can be increased by two orders of magnitude.

  13. High-resolution and high-conductive electrode fabrication on a low thermal resistance flexible substrate

    Science.gov (United States)

    Kang, Bongchul; Kno, Jinsung; Yang, Minyang

    2011-07-01

    Processes based on the liquid-state pattern transfer, like inkjet printing, have critical limitations including low resolution and low electrical conductivity when fabricating electrodes on low thermal resistance flexible substrates such as polyethylene terephthalate (PET). Those are due to the nonlinear transfer mechanism and the limit of the sintering temperature. Although the laser direct curing (LDC) of metallic inks is an alternative process to improve the resolution, it is also associated with the disadvantages of causing thermal damage to the polymer substrate. This paper suggests the laser induced pattern adhesion transfer method to fabricate electrodes of both high electrical conductivity and high resolution on a PET substrate. First, solid patterns are cost-effectively created by the LDC of the organometallic silver ink on a glass that is optically and thermally stable. The solid patterns sintered on the glass are transferred to the PET substrate by the photo-thermally generated adhesion force of the substrate. Therefore, we achieved electrodes with a minimum line width of 10 µm and a specific resistance of 3.6 μΩcm on the PET substrate. The patterns also showed high mechanical reliability.

  14. Efficient focusing of 8 keV X-rays with multilayer Fresnel zone plates fabricated by atomic layer deposition and focused ion beam milling.

    Science.gov (United States)

    Mayer, Marcel; Keskinbora, Kahraman; Grévent, Corinne; Szeghalmi, Adriana; Knez, Mato; Weigand, Markus; Snigirev, Anatoly; Snigireva, Irina; Schütz, Gisela

    2013-05-01

    Fresnel zone plates (FZPs) recently showed significant improvement by focusing soft X-rays down to ~10 nm. In contrast to soft X-rays, generally a very high aspect ratio FZP is needed for efficient focusing of hard X-rays. Therefore, FZPs had limited success in the hard X-ray range owing to difficulties of manufacturing high-aspect-ratio zone plates using conventional techniques. Here, employing a method of fabrication based on atomic layer deposition (ALD) and focused ion beam (FIB) milling, FZPs with very high aspect ratios were prepared. Such multilayer FZPs with outermost zone widths of 10 and 35 nm and aspect ratios of up to 243 were tested for their focusing properties at 8 keV and shown to focus hard X-rays efficiently. This success was enabled by the outstanding layer quality thanks to ALD. Via the use of FIB for slicing the multilayer structures, desired aspect ratios could be obtained by precisely controlling the thickness. Experimental diffraction efficiencies of multilayer FZPs fabricated via this combination reached up to 15.58% at 8 keV. In addition, scanning transmission X-ray microscopy experiments at 1.5 keV were carried out using one of the multilayer FZPs and resolved a 60 nm feature size. Finally, the prospective of different material combinations with various outermost zone widths at 8 and 17 keV is discussed in the light of the coupled wave theory and the thin-grating approximation. Al2O3/Ir is outlined as a promising future material candidate for extremely high resolution with a theoretical efficiency of more than 20% for as small an outermost zone width as 10 nm at 17 keV.

  15. High-efficiency Transformerless PV Inverter Circuits

    OpenAIRE

    Chen, Baifeng

    2015-01-01

    With worldwide growing demand for electric energy, there has been a great interest in exploring photovoltaic (PV) sources. For the PV generation system, the power converter is the most essential part for the efficiency and function performance. In recent years, there have been quite a few new transformerless PV inverters topologies, which eliminate the traditional line frequency transformers to achieve lower cost and higher efficiency, and maintain lower leakage current as well. With an ov...

  16. High efficiency silicon solar cell review

    Science.gov (United States)

    Godlewski, M. P. (Editor)

    1975-01-01

    An overview is presented of the current research and development efforts to improve the performance of the silicon solar cell. The 24 papers presented reviewed experimental and analytic modeling work which emphasizes the improvment of conversion efficiency and the reduction of manufacturing costs. A summary is given of the round-table discussion, in which the near- and far-term directions of future efficiency improvements were discussed.

  17. Effect of dyeing on antibacterial efficiency of silver coated cotton fabrics

    Science.gov (United States)

    Shahidi, Sheila; Rezaee, Sahar; Hezavehi, Emadaldin

    2014-04-01

    Despite numerous investigations during recent decades in the field of antimicrobial treating textile fibers using silver, many obscurities remain regarding the durability and dyeing ability and the influences of dyeing on the antimicrobial effectiveness of silver-treated fibers. In this research work, the cotton fabrics were sputtered using DC magnetron sputtering system for different times of exposure by silver. Then the silver coated samples were dyed by different classes of synthetic and natural dyes. The dye ability of coated samples was compared with untreated cotton. The reflective spectrophotometer was used for this purpose. The morphology of the cotton fabrics before and after dyeing was observed using a scanning electron microscope (SEM). The antibacterial activity of samples before and after dyeing, were investigated and compared. For antibacterial investigation, the antibacterial counting tests were used. It was concluded that, dyeing does not have any negative effect on antibacterial activity of coated samples and very good antibacterial activity was achieved after dyeing.

  18. High-Efficiency Flexible Solar Cells Based on Organometal Halide Perovskites.

    Science.gov (United States)

    Wang, Yuming; Bai, Sai; Cheng, Lu; Wang, Nana; Wang, Jianpu; Gao, Feng; Huang, Wei

    2016-06-01

    Flexible and light-weight solar cells are important because they not only supply power to wearable and portable devices, but also reduce the transportation and installation cost of solar panels. High-efficiency organometal halide perovskite solar cells can be fabricated by a low-temperature solution process, and hence are promising for flexible-solar-cell applications. Here, the development of perovskite solar cells is briefly discussed, followed by the merits of organometal halide perovskites as promising candidates as high-efficiency, flexible, and light-weight photovoltaic materials. Afterward, recent developments of flexible solar cells based on perovskites are reviewed.

  19. Fabrication of Chemically Doped, High Upper Critical Field Magnesium Diboride Superconducting Wires

    Energy Technology Data Exchange (ETDEWEB)

    Marzik, James, V.

    2005-10-13

    Controlled chemical doping of magnesium diboride (MgB2) has been shown to substantially improve its superconducting properties to the levels required for high field magnets, but the doping is difficult to accomplish through the usual route of solid state reaction and diffusion. Further, superconducting cables of MgB2 are difficult to fabricate because of the friable nature of the material. In this Phase I STTR project, doped and undoped boron fibers were made by chemical vapor deposition (CVD). Several >100m long batches of doped and undoped fiber were made by CVD codeposition of boron plus dopants. Bundles of these fibers infiltrated with liquid magnesium and subsequently converted to MgB2 to form Mg-MgB2 metal matrix composites. In a parallel path, doped boron nano-sized powder was produced by a plasma synthesis technique, reacted with magnesium to produce doped MgB2 superconducting ceramic bodies. The doped powder was also fabricated into superconducting wires several meters long. The doped boron fibers and powders made in this program were fabricated into fiber-metal composites and powder-metal composites by a liquid metal infiltration technique. The kinetics of the reaction between boron fiber and magnesium metal was investigated in fiber-metal composites. It was found that the presence of dopants had significantly slowed the reaction between magnesium and boron. The superconducting properties were measured for MgB2 fibers and MgB2 powders made by liquid metal infiltration. Properties of MgB2 products (Jc, Hc2) from Phase I are among the highest reported to date for MgB2 bulk superconductors. Chemically doped MgB2 superconducting magnets can perform at least as well as NbTi and NbSn3 in high magnetic fields and still offer an improvement over the latter two in terms of operating temperature. These characteristics make doped MgB2 an effective material for high magnetic field applications, such as magnetic confined fusion, and medical MRI devices. Developing

  20. Efficient Multicast Support in High-Speed Packet Switches

    Directory of Open Access Journals (Sweden)

    Lotfi Mhamdi

    2007-06-01

    Full Text Available The tremendous growth of the Internet coupled with newly emerging applications has created a vital need for multicast traffic support by backbone routers and ATM switches. Considerable research work has been done on Input Queued (IQ switches to handle multicast traffic flows. Unfortunately, all previously proposed solutions were of no practical value because they either lack performance or were simply too complex to implement. Internally Buffered Crossbar (IBC switches, where a limited small amount of memory is added in each crosspoint of the crossbar fabric, on the other hand, have been considered as a robust alternative to buffer-less crossbar switches to improve the switching performance. However, very little has been done on multicasting in IBC switches. In this paper, we fill this gap and study the multicasting problem in IBC switches. In particular, we propose a novel IBC based multicast architecture along with a simple scheduling scheme named Multicast cross-point Round Robin (MXRR. Our scheme was shown to handle multicast traffic more efficiently and far better than all previous schemes for both the multicast FIFO architecture as well as the multicast k FIFO queues architecture. Yet, MXRR is both practical and achieves high performance.

  1. Photo-Promoted Platinum Nanoparticles Decorated MoS2@Graphene Woven Fabric Catalyst for Efficient Hydrogen Generation.

    Science.gov (United States)

    Li, Xiao; Zhang, Li; Zang, Xiaobei; Li, Xinming; Zhu, Hongwei

    2016-05-01

    Hydrogen production from water splitting has been considered as an effective and sustainable method to solve future energy related crisis. Molybdenum sulfides (e.g., MoS2) show promising catalytic ability in hydrogen evolution reaction (HER). Combining MoS2 with conductive carbon-based materials has aroused tremendous research interest recently. In this work, a highly efficient multiple-catalyst is developed for HER by decorating Pt nanoparticles (Pt NPs) on MoS2@graphene protected nickel woven fabrics (NiWF) substrate, which comprises the following components: (i) Graphene protected NiWF acts as the underlying substrate, supporting the whole structure; (ii) MoS2 nanoplates serve as a central and essential photosensitive component, forming a heterostructure with graphene simultaneously; and (iii) on the basis of the intrinsic photoluminescence effect of MoS2, together with the photoelectric response at the MoS2/graphene interface, Pt NPs are successfully deposited on the whole structure under illumination. Particularly and foremost, this work emphasizes on discussion and verification of the underlying mechanism for photopromoted electroless Pt NPs deposition. Due to this assembly approach, the usage amount of Pt is controlled at ∼5 wt % (∼0.59 at. %) with respect to the whole catalyst. MoS2@Substrate with Pt NPs deposited under 643 nm illumination, with the synergistic effect of MoS2 active sites and Pt NPs, demonstrates the most superior electrocatalytic performance, with negligible overpotential and low Tafel slope of 39.4 mV/dec.

  2. Experimental Demonstration of a Highly Efficient Fan-out Polarization Grating.

    Science.gov (United States)

    Wan, Chenhao; Chen, Jian; Tang, Xiahui; Zhan, Qiwen

    2016-12-23

    Highly efficient fan-out elements are crucial in coherent beam combining architectures especially in coupled laser resonators where the beam passes through the fan-out element twice per round trip. Although the theoretical efficiency is usually less than 86%, the Dammann gratings are ubiquitously utilized in a variety of types of coherent beam combining systems due to the facile design and fabrication. In the current paper, we experimentally demonstrate a highly efficient fan-out polarization grating. It is the first time to our knowledge that all the three space-variant parameters of a polarization grating are simultaneously optimized to achieve the function of multi-beam splitting. Besides the high fan-out efficiency, the ability to control the polarization states of individual split beams is another advantage of this polarization grating. The novel polarization grating is promising to find applications in laser beam combining systems.

  3. Fabrication of high aspect ratio nanocell lattices by ion beam irradiation

    Energy Technology Data Exchange (ETDEWEB)

    Ishikawa, Osamu [School of Environmental Science and Technology, Kochi University of Technology, Tosayamada, Kami, Kochi 782-8502 (Japan); Nitta, Noriko, E-mail: nitta.noriko@kochi-tech.ac.jp [School of Environmental Science and Technology, Kochi University of Technology, Tosayamada, Kami, Kochi 782-8502 (Japan); Center for Nanotechnology, Research Institute, Kochi University of Technology, Tosayamada, Kami, Kochi 782-8502 (Japan); Taniwaki, Masafumi [School of Environmental Science and Technology, Kochi University of Technology, Tosayamada, Kami, Kochi 782-8502 (Japan)

    2016-11-01

    Highlights: • Nanocell lattice with a high aspect ratio on InSb semiconductor surface was fabricated by ion beam irradiation. • The fabrication technique consisting of top-down and bottom-up processes was performed in FIB. • High aspect ratio of 2 was achieved in nanocell lattice with a 100 nm interval. • The intermediate-flux irradiation is favorable for fabrication of nanocell with a high aspect ratio. - Abstract: A high aspect ratio nanocell lattice was fabricated on the InSb semiconductor surface using the migration of point defects induced by ion beam irradiation. The fabrication technique consisting of the top-down (formation of voids and holes) and bottom-up (growth of voids and holes into nanocells) processes was performed using a focused ion beam (FIB) system. A cell aspect ratio of 2 (cell height/cell diameter) was achieved for the nanocell lattice with a 100 nm dot interval The intermediate-flux ion irradiation during the bottom-up process was found to be optimal for the fabrication of a high aspect ratio nanocell.

  4. Processing and fabrication of high temperature oxide superconductors

    Science.gov (United States)

    Johnson, Sylvia M.

    1989-07-01

    During the past year, a process for synthesizing superconductor powders by freeze drying was optimized. The objectives were to develop an understanding of the processing of these powders and to fabricate simple shapes from freeze dried powders. A series of powders were synthesized from solutions of barium acetate, copper nitrate, and yttrium nitrate, with pH values of 2.8 to 9.8 and calcined at temperatures from 510 to 908 C. The surface area of these powders were determined by BET AND XRD. Selected powders are being characterized by SEM, DTA, ICP analysis (performed at Stanford University), carbon analysis, and tap density. The highest surface area (in lightly milled powders) of 4.4 sq m/g was achieved with a pH of 4 in a series of experiments in which the Ba and Y solutions were mixed together before the Cu nitrate solution was added, then calcined at 825 C. Surface areas decrease with increasing calcining temperature, however. It appears that calcining at 750 or 850 C gives the best critical temperature, with complete transitions at greater than 90 K. Critical temperature measurements performed at Standford show that the goal of a critical temperature of Tc greater than 90 K and a temperature difference, W, between 10 and 90 percent of transition of less than 2 K, were achieved.

  5. High-Efficiency, Commercial Ready CdTe Solar Cells

    Energy Technology Data Exchange (ETDEWEB)

    Sites, James R. [Colorado State Univ., Fort Collins, CO (United States)

    2015-11-19

    Colorado State’s F-PACE project explored several ways to increase the efficiency of CdTe solar cells and to better understand the device physics of those cells under study. Increases in voltage, current, and fill factor resulted in efficiencies above 17%. The three project tasks and additional studies are described in detail in the final report. Most cells studied were fabricated at Colorado State using an industry-compatible single-vacuum closed-space-sublimation (CSS) chamber for deposition of the key semiconductor layers. Additionally, some cells were supplied by First Solar for comparison purposes, and a small number of modules were supplied by Abound Solar.

  6. Designing high efficient solar powered lighting systems

    DEFF Research Database (Denmark)

    Poulsen, Peter Behrensdorff; Thorsteinsson, Sune; Lindén, Johannes;

    2016-01-01

    Some major challenges in the development of L2L products is the lack of efficient converter electronics, modelling tools for dimensioning and furthermore, characterization facilities to support the successful development of the products. We report the development of 2 Three-Port-Converters respec......Some major challenges in the development of L2L products is the lack of efficient converter electronics, modelling tools for dimensioning and furthermore, characterization facilities to support the successful development of the products. We report the development of 2 Three......-Port-Converters respectively for 1-10Wp and 10-50 Wp with a peak efficiency of 97% at 1.8 W of PV power for the 10 Wp version. Furthermore, a modelling tool for L2L products has been developed and a laboratory for feeding in component data not available in the datasheets to the model is described....

  7. Highly efficient method for production of radioactive silver seed cores for brachytherapy.

    Science.gov (United States)

    Cardoso, Roberta Mansini; de Souza, Carla Daruich; Rostelato, Maria Elisa Chuery Martins; Araki, Koiti

    2017-02-01

    A simple and highly efficient (shorter reaction time and almost no rework) method for production of iodine based radioactive silver seed cores for brachytherapy is described. The method allows almost quantitative deposition of iodine-131 on dozens of silver substrates at once, with even distribution of activity per core and insignificant amounts of liquid and solid radioactive wastes, allowing the fabrication of cheaper radioactive iodine seeds for brachytherapy.

  8. Highly efficient, high speed vertical photodiodes based on few-layer MoS2

    Science.gov (United States)

    Li, Zhen; Chen, Jihan; Dhall, Rohan; Cronin, Stephen B.

    2017-03-01

    Layered transition metal dichalcogenides, such as MoS2, have recently emerged as a promising material system for electronic and optoelectronic applications. The two-dimensional nature of these materials enables facile integration for vertical device design with novel properties. Here, we report highly efficient photocurrent generation from vertical MoS2 devices fabricated using asymmetric metal contacts, exhibiting an external quantum efficiency of up to 7%. Compared to in-plane MoS2 devices, the vertical design of these devices has a much larger junction area, which is essential for achieving highly efficient photovoltaic devices. Photocurrent and photovoltage spectra are measured over the photon energy range from 1.25 to 2.5 eV, covering both the 1.8 eV direct K-point optical transition and the 1.3 eV Σ-point indirect transition in MoS2. Photocurrent peaks corresponding to both direct and indirect transitions are observed in the photocurrent spectra and exhibit different photovoltage-current characteristics. Compared to previous in-plane devices, a substantially shorter photoresponse time of 7.3 μs is achieved due to fast carrier sweeping in the vertical devices, which exhibit a -3 dB cutoff frequency of 48 kHz.

  9. λ/26 silver nanodots fabricated by direct laser writing through highly sensitive two-photon photoreduction

    Energy Technology Data Exchange (ETDEWEB)

    Cao, Yaoyu; Gu, Min, E-mail: mgu@swin.edu.au [Centre for Micro-Photonics and CUDOS, Faculty of Engineering and Industrial Sciences, Swinburne University of Technology, P.O. Box 218, Hawthorn, Victoria 3122 (Australia)

    2013-11-18

    We demonstrated an approach to break the diffraction limit and realise deep-subwavelength two-photon direct laser writing by employing a highly sensitive photoreduction process. The photoreduction photosensitivity increased by at least 4 times while the wavelength of the fabrication laser beam was tuned from 800 nm to 580 nm. The increase of the photosensitivity resulted in improved resolution for the silver dot fabrication. By developing the photoreduction material with adding electron donors, the photosensitivity further increased and enabled the realisation of a single silver dot at 22 nm which is λ/26 for the wavelength of the fabrication laser beam.

  10. Polarization-independent high-index contrast grating and its fabrication tolerances

    DEFF Research Database (Denmark)

    Ikeda, Kazuhiro; Takeuchi, Kazuma; Takayose, Kentaro

    2013-01-01

    A polarization-independent, high-index contrast grating (HCG) with a single layer of cross stripes allowing simple fabrication is proposed. Since the cross stripes structure can be suspended in air by selectively wet-etching the layer below, all the layers can be grown at once when implemented...... also investigated the fabrication tolerances of the structure and found that, assuming careful optimizations of electron beam lithography for the precise grating width and dry-etching for the vertical sidewall, the suggested polarization-independent HCG can be fabricated using standard technologies....

  11. Wafer-scale fabrication of high-aspect ratio nanochannels based on edge-lithography technique.

    Science.gov (United States)

    Xie, Quan; Zhou, Qing; Xie, Fei; Sang, Jianming; Wang, Wei; Zhang, Haixia Alice; Wu, Wengang; Li, Zhihong

    2012-03-01

    This paper introduced a wafer-scale fabrication approach for the preparation of nanochannels with high-aspect ratio (the ratio of the channel depth to its width). Edge lithography was used to pattern nanogaps in an aluminum film, which was functioned as deep reactive ion etching mask thereafter to form the nanochannel. Nanochannels with aspect ratio up to 172 and width down to 44 nm were successfully fabricated on a 4-inch Si wafer with width nonuniformity less than 13.6%. A microfluidic chip integrated with nanometer-sized filters was successfully fabricated by utilizing the present method for geometric-controllable nanoparticle packing.

  12. High Efficiency Electron-Laser Interactions in Tapered Helical Undulators

    Science.gov (United States)

    Duris, Joseph Patrick

    Efficient coupling of relativistic electron beams with high power radiation lies at the heart of advanced accelerator and light source research and development. The inverse free electron laser is a stable accelerator capable of harnessing very high intensity laser electric fields to efficiently transfer large powers from lasers to electron beams. In this dissertation, we first present the theoretical framework to describe the interaction, and then apply our improved understanding of the IFEL to the design and numerical study of meter-long, GeV IFELs for compact light sources. The central experimental work of the dissertation is the UCLA BNL helical inverse free electron laser experiment at the Accelerator Test Facility in Brookhaven National Laboratory which used a strongly tapered 54cm long, helical, permanent magnet undulator and a several hundred GW CO2 laser to accelerate electrons from 52 to 106MeV, setting new records for inverse free electron laser energy gain (54MeV) and average accelerating gradient (100MeV/m). The undulator design and fabrication as well as experimental diagnostics are presented. In order to improve the stability and quality of the accelerated electron beam, we redesigned the undulator for a slightly reduced output energy by modifying the magnet gap throughout the undulator, and we used this modified undulator to demonstrated capture of >25% of the injected beam without prebunching. In the study of heavily loaded GeV inverse free electron lasers, we show that a majority of the power may be transferred from a laser to the accelerated electron beam. Reversing the process to decelerate high power electron beams, a mechanism we refer to as tapering enhanced stimulated superradiant amplification, offers a clear path to high power light sources. We present studies of radiation production for a wide range of wavelengths (10mum, 13nm, and 0.3nm) using this method and discuss the design for a deceleration experiment using the same undulator used

  13. Designing high efficient solar powered lighting systems

    DEFF Research Database (Denmark)

    Poulsen, Peter Behrensdorff; Thorsteinsson, Sune; Lindén, Johannes

    2016-01-01

    Some major challenges in the development of L2L products is the lack of efficient converter electronics, modelling tools for dimensioning and furthermore, characterization facilities to support the successful development of the products. We report the development of 2 Three-Port-Converters respec...

  14. Designing high efficient solar powered lighting systems

    DEFF Research Database (Denmark)

    Poulsen, Peter Behrensdorff; Thorsteinsson, Sune; Lindén, Johannes;

    2016-01-01

    Some major challenges in the development of L2L products is the lack of efficient converter electronics, modelling tools for dimensioning and furthermore, characterization facilities to support the successful development of the products. We report the development of 2 Three-Port-Converters respec...

  15. Designing high efficient solar powered lighting systems

    DEFF Research Database (Denmark)

    Poulsen, Peter Behrensdorff; Thorsteinsson, Sune; Lindén, Johannes;

    Some major challenges in the development of L2L products is the lack of efficient converter electronics, modelling tools for dimensioning and furthermore, characterization facilities to support the successful development of the products. We report the development of 2 Three-Port-Converters respec...

  16. Fabrication of highly active and cost effective SERS plasmonic substrates by electrophoretic deposition of gold nanoparticles on a DVD template

    Energy Technology Data Exchange (ETDEWEB)

    Leordean, Cosmin; Marta, Bogdan; Gabudean, Ana-Maria; Focsan, Monica; Botiz, Ioan; Astilean, Simion, E-mail: simion.astilean@phys.ubbcluj.ro

    2015-09-15

    Highlights: • Simple and cost effective electrophoretic method to fabricate plasmonic substrates. • SERS performance at three different excitation laser lines. • Promising applicability in SERS based biosensing. - Abstract: In this work we present a simple, rapid and cost effective method to fabricate highly active SERS substrates. This method consists in an electrophoretic deposition of gold nanoparticles on a metallic nanostructured template of a commercial digital versatile disk (DVD). The negatively charged gold nanoparticles self-assemble on the positively charged DVD metallic film connected to a positive terminal of a battery, due to the influence of the electric field. When gold nanoparticles self-assembled on DVD metallic film, a 10-fold additional enhancement of Raman signal was observed when compared with the case of GNPs self-assembled on a polycarbonate DVD substrate only. Finite-difference time-domain simulations demonstrated that the additional electromagnetic field arising in the hot-spots created between gold nanoparticles and DVD metallic film induces an additional enhancement of the Raman signal. SERS efficiency of the fabricated plasmonic substrate was successfully demonstrated through detection of para-aminothiophenol molecule with three different excitation laser lines (532, 633 and 785 nm). The enhancement factor was calculated to be 10{sup 6} and indicates that plasmonic substrates fabricated through this method could be a promising platform for future SERS based sensors.

  17. High resolution nanoimprint templates for dual damascene: fabrication and imprint results

    Science.gov (United States)

    Irmscher, Mathias; Butschke, Joerg; Carpio, Ron; Chao, Brook; Jen, Wei-Lun; Koepernik, Corinna; Nedelmann, Lorenz; Owens, Jordan; Palmieri, Frank; Pritschow, Marcus; Reuter, Christian; Sailer, Holger; Satoodeh, Ken; Wetzel, Jeff; Wilks, Bruce; Willson, Grant

    2008-03-01

    A dual damascene template fabrication process has been developed, which enables the structuring of high-resolution, high-aspect pillars on top of lines. Based on this technology templates with three different designs have been fabricated and characterized. Two templates are dedicated for an assessment of the fabrication process using a regular test design on one hand and an arbitrary CMOS design on the other hand. With the third template via chains shall be later realized as demonstrator for electrical tests. The templates have been imprinted in resist and sacrificial material on an Imprio 55 and an Imprio 100 tool. The usability of each fabricated template could be confirmed for the specific application. For the template manufacturing a Vistec variable shape e-beam (VSB) writer SB352HR and appropriate positive-tone and negative-tone chemically amplified resists (CAR) have been used.

  18. Highly efficient single-junction GaAs thin-film solar cell on flexible substrate

    Science.gov (United States)

    Moon, Sunghyun; Kim, Kangho; Kim, Youngjo; Heo, Junseok; Lee, Jaejin

    2016-07-01

    There has been much interest in developing a thin-film solar cell because it is lightweight and flexible. The GaAs thin-film solar cell is a top contender in the thin-film solar cell market in that it has a high power conversion efficiency (PCE) compared to that of other thin-film solar cells. There are two common structures for the GaAs solar cell: n (emitter)-on-p (base) and p-on-n. The former performs better due to its high collection efficiency because the electron diffusion length of the p-type base region is much longer than the hole diffusion length of the n-type base region. However, it has been limited to fabricate highly efficient n-on-p single-junction GaAs thin film solar cell on a flexible substrate due to technical obstacles. We investigated a simple and fast epitaxial lift-off (ELO) method that uses a stress originating from a Cr/Au bilayer on a 125-μm-thick flexible substrate. A metal combination of AuBe/Pt/Au is employed as a new p-type ohmic contact with which an n-on-p single-junction GaAs thin-film solar cell on flexible substrate was successfully fabricated. The PCE of the fabricated single-junction GaAs thin-film solar cells reached 22.08% under air mass 1.5 global illumination.

  19. Low cost, single crystal-like substrates for practical, high efficiency solar cells

    Energy Technology Data Exchange (ETDEWEB)

    Goyal, A.; Specht, E.D.; List, F.A. [and others

    1997-09-01

    It is well established that high efficiency (20%) solar cells can be routinely fabricated using single crystal photovoltaic (PV) materials with low defect densities. Polycrystalline materials with small grain sizes and no crystallographic texture typically result in reduced efficiences. This has been ascribed primarily to the presence of grain boundaries and their effect on recombination processes. Furthermore, lack of crystallographic texture can result in a large variation in dopant concentrations which critically control the electronic properties of the material. Hence in order to reproducibly fabricate high efficiency solar cells a method which results in near single crystal material is desirable. Bulk single crystal growth of PV materials is cumbersome, expensive and difficult to scale up. We present here a possible route to achieve this if epitaxial growth of photovoltaic materials on rolling-assisted-biaxially textured-substrates (RABiTS) can be achieved. The RABiTS process uses well-established, industrially scaleable, thermomechanical processing to produce a biaxially textured or single-crystal-like metal substrate with large grains (50-100 {mu}m). This is followed by epitaxial growth of suitable buffer layers to yield chemically and structurally compatible surfaces for epitaxial growth of device materials. Using the RABiTS process it should be possible to economically fabricate single-crystal-like substrates of desired sizes. Epitaxial growth of photovoltaic devices on such substrates presents a possible route to obtaining low-cost, high performance solar cells.

  20. An efficient luminescence conversion LED for white light emission, fabricated using a commercial InGaN LED and a 1,8-naphthalimide derivative

    Science.gov (United States)

    Kim, Hyun-Jeong; Jin, Ji-Young; Lee, Youn-Sik; Lee, Sang-Hee; Hong, Chang-Hee

    2006-11-01

    A highly efficient luminescence conversion light emitting diode (LUCO LED) was fabricated, using a commercial InGaN LED (460 nm) and 4- N, N-diphenyl-9-(4- tert-butylphenyl)-1,8-naphthalimide (DBN), dispersed in epoxy as the primary light source and LUCO material, respectively. The emission of very bright white light was observed at 20 mA, with CIE chromaticity coordinates of (0.32, 0.33) and conversion efficiency of 82%. The luminescent output of the LUCO LED decreased rapidly, but when the LUCO LED was prepared using DNB dispersed in poly(methyl methacrylate), it only decreased to about 67% of the initial value after 19 days of continual operation at 200 mA.

  1. Silicon-Light: a European FP7 Project Aiming at High Efficiency Thin Film Silicon Solar Cells on Foil

    DEFF Research Database (Denmark)

    Soppe, W.; Haug, F.-J.; Couty, P.

    2011-01-01

    Silicon-Light is a European FP7 project, which started January 1st, 2010 and aims at development of low cost, high-efficiency thin film silicon solar cells on foil. Three main routes are explored to achieve these goals: a) advanced light trapping by implementing nanotexturization through UV Nano...... calculations of ideal nanotextures for light trapping in thin film silicon solar cells; the fabrication of masters and the replication and roll-to-roll fabrication of these nanotextures. Further, results on ITO variants with improved work function are presented. Finally, the status of cell fabrication on foils...

  2. Efficient design, accurate fabrication and effective characterization of plasmonic quasicrystalline arrays of nano-spherical particles

    Science.gov (United States)

    Namin, Farhad A.; Yuwen, Yu A.; Liu, Liu; Panaretos, Anastasios H.; Werner, Douglas H.; Mayer, Theresa S.

    2016-02-01

    In this paper, the scattering properties of two-dimensional quasicrystalline plasmonic lattices are investigated. We combine a newly developed synthesis technique, which allows for accurate fabrication of spherical nanoparticles, with a recently published variation of generalized multiparticle Mie theory to develop the first quantitative model for plasmonic nano-spherical arrays based on quasicrystalline morphologies. In particular, we study the scattering properties of Penrose and Ammann- Beenker gold spherical nanoparticle array lattices. We demonstrate that by using quasicrystalline lattices, one can obtain multi-band or broadband plasmonic resonances which are not possible in periodic structures. Unlike previously published works, our technique provides quantitative results which show excellent agreement with experimental measurements.

  3. Experimental Research on Permeability of Airbag Fabrics at High Pressure Differential

    Institute of Scientific and Technical Information of China (English)

    WANG Xin-hou

    2004-01-01

    The air permeability of airbag fabrics was measured at high pressure differential up to 200kPa. It was found that permeability varied with pressure differential nonlinearly. The relationship between air permeability and the pressure differential was fitted well with power law curve. The study revealed that the coefficient c and exponent b in the power law equation had a strong correlation with porosity, which was chosen to characterize the airbag fabrics.

  4. High Resolution Magic Angle Spinning Nuclear Magnetic Resonance (HRMAS NMR) for Studies of Reactive Fabrics

    Science.gov (United States)

    2015-11-01

    Magnetic Resonance (HRMAS NMR) for Studies of Reactive Fabrics 5a. CONTRACT NUMBER W911SR-11-C-0047 5b. GRANT NUMBER 5c. PROGRAM ELEMENT NUMBER...ECBC-TR-1326 HIGH RESOLUTION MAGIC ANGLE SPINNING NUCLEAR MAGNETIC RESONANCE (HRMAS NMR) FOR STUDIES OF REACTIVE FABRICS David J. McGarvey...unlimited. 13. SUPPLEMENTARY NOTES 14. ABSTRACT An analytical chemistry method is described for measuring the reactivity and permeation of

  5. Biomimetic fabrication of WO{sub 3} for water splitting under visible light with high performance

    Energy Technology Data Exchange (ETDEWEB)

    Yin, Chao; Zhu, Shenmin, E-mail: smzhu@sjtu.edu.cn; Yao, Fan; Gu, Jiajun; Zhang, Wang [Shanghai Jiao Tong University, State Key Laboratory of Metal Matrix Composites (China); Chen, Zhixin [University of Wollongong, Faculty of Engineering (Australia); Zhang, Di, E-mail: zhangdi@sjtu.edu.cn [Shanghai Jiao Tong University, State Key Laboratory of Metal Matrix Composites (China)

    2013-08-15

    Inspired by the high light-harvesting properties of typical butterfly wings, ceramic WO{sub 3} butterfly wings with hierarchical structures of bio-butterfly wings was fabricated using a template of PapilioParis butterfly wings through a sol-gel method. The effect of calcination temperatures on the structures of the ceramic butterfly wings was investigated and the results showed that the WO{sub 3} butterfly wing replica calcined at 550 Degree-Sign C (WO{sub 3} replica-550) is a single phase and has a high crystallinity and relatively fine hierarchical structure. The average grain size of WO{sub 3} replica-550 and WO{sub 3} powder are around 32.6 and 42.2 nm, respectively. Compared with pure WO{sub 3} powder, WO{sub 3} replica-550 demonstrated a higher light-harvesting capability in the region from 460 to 700 nm and more importantly the higher charge separation rate, as evidenced by electron paramagnetic resonance measurements. Photocatalytic O{sub 2} evolutions from water were investigated on the ceramic butterfly wings and pure WO{sub 3} powder under visible light ({lambda} > 420 nm). The results showed that the amount of O{sub 2} produced from WO{sub 3} replica-550 is 50 % higher than that of the pure WO{sub 3} powder. The improved photocatalytic performance of WO{sub 3} replica-550 is attributed to the quasi-honeycomb structure inherited from the PapilioParis butterfly wings, providing both high light-harvesting efficiency and efficient charge transport through the WO{sub 3}.

  6. Energy efficiency indicators for high electric-load buildings

    Energy Technology Data Exchange (ETDEWEB)

    Aebischer, Bernard; Balmer, Markus A.; Kinney, Satkartar; Le Strat, Pascale; Shibata, Yoshiaki; Varone, Frederic

    2003-06-01

    Energy per unit of floor area is not an adequate indicator for energy efficiency in high electric-load buildings. For two activities, restaurants and computer centres, alternative indicators for energy efficiency are discussed.

  7. Enhancing the Effectiveness of Cycle Time Estimation in Wafer Fabrication-Efficient Methodology and Managerial Implications

    Directory of Open Access Journals (Sweden)

    Toly Chen

    2014-08-01

    Full Text Available Cycle time management plays an important role in improving the performance of a wafer fabrication factory. It starts from the estimation of the cycle time of each job in the wafer fabrication factory. Although this topic has been widely investigated, several issues still need to be addressed, such as how to classify jobs suitable for the same estimation mechanism into the same group. In contrast, in most existing methods, jobs are classified according to their attributes. However, the differences between the attributes of two jobs may not be reflected on their cycle times. The bi-objective nature of classification and regression tree (CART makes it especially suitable for tackling this problem. However, in CART, the cycle times of jobs of a branch are estimated with the same value, which is far from accurate. For these reason, this study proposes a joint use of principal component analysis (PCA, CART, and back propagation network (BPN, in which PCA is applied to construct a series of linear combinations of original variables to form new variables that are as unrelated to each other as possible. According to the new variables, jobs are classified using CART before estimating their cycle times with BPNs. A real case was used to evaluate the effectiveness of the proposed methodology. The experimental results supported the superiority of the proposed methodology over some existing methods. In addition, the managerial implications of the proposed methodology are also discussed with an example.

  8. Efficient and Highly Aldehyde Selective Wacker Oxidation

    KAUST Repository

    Teo, Peili

    2012-07-06

    A method for efficient and aldehyde-selective Wacker oxidation of aryl-substituted olefins using PdCl 2(MeCN) 2, 1,4-benzoquinone, and t-BuOH in air is described. Up to a 96% yield of aldehyde can be obtained, and up to 99% selectivity can be achieved with styrene-related substrates. © 2012 American Chemical Society.

  9. Peel-and-stick: mechanism study for efficient fabrication of flexible/transparent thin-film electronics.

    Science.gov (United States)

    Lee, Chi Hwan; Kim, Jae-Han; Zou, Chenyu; Cho, In Sun; Weisse, Jeffery M; Nemeth, William; Wang, Qi; van Duin, Adri C T; Kim, Taek-Soo; Zheng, Xiaolin

    2013-10-10

    Peel-and-stick process, or water-assisted transfer printing (WTP), represents an emerging process for transferring fully fabricated thin-film electronic devices with high yield and fidelity from a SiO2/Si wafer to various non-Si based substrates, including papers, plastics and polymers. This study illustrates that the fundamental working principle of the peel-and-stick process is based on the water-assisted subcritical debonding, for which water reduces the critical adhesion energy of metal-SiO2 interface by 70 ~ 80%, leading to clean and high quality transfer of thin-film electronic devices. Water-assisted subcritical debonding is applicable for a range of metal-SiO2 interfaces, enabling the peel-and-stick process as a general and tunable method for fabricating flexible/transparent thin-film electronic devices.

  10. Enhancement in Photoelectrochemical Efficiency by Fabrication of BiVO4@MWCNT Nanocomposites

    Directory of Open Access Journals (Sweden)

    Yan Zhang

    2011-01-01

    Full Text Available An enormous enhancement in the photo-to-current conversion efficiency over the nanocomposite material composed by BiVO4 on the surface of MWCNTs, with respect to electrode of pure BiVO4, was observed. The heterojunction formed between MWCNTs and nano-BiVO4 is beneficial for the separation of photogenerated electrons and holes, resulting in more electrons that are able to transport efficiently to the surface and therefore enhance the photoefficiency.

  11. Fabrication of High-power White LEDs and White Light Uniformity Testing

    Institute of Scientific and Technical Information of China (English)

    YU Xin-mei; RAO Hai-bo; HU Yue; LI Jun-fei; HOU Bin

    2007-01-01

    As the blue and yellow lights are complementary colors,a blue InGaN LED chip is coated by a yellow phosphor film to generate white light based on luminescence conversion mechanism.The emitted light of a blue LED is used as the primary source for exciting fluorescent material such as cerium doped yttrium aluminum garnet with the formula Y3Al5O12:Ce3+(in short:YAG:Ce3+).The matching of the spectrum of the blue LED chips and the YAG:Ce3+ yellow phosphor is studied to improve the conversion efficiency.The packaging methods and manufacturing processes for high-power single-chip-white-LEDs are introduced.The uniformity of the output white light is investigated.Based on the characteristics of the high-power white LEDs,some approaches and processes are suggested to improve the light uniformity when they are fabricated.The effectiveness of those approaches on the improvement of LEDs is discussed in detail and some interesting conclusions are also presented.

  12. Design, Simulation and Fabrication of Triaxial MEMS High Shock Accelerometer.

    Science.gov (United States)

    Zhang, Zhenhai; Shi, Zhiguo; Yang, Zhan; Xie, Zhihong; Zhang, Donghong; Cai, De; Li, Kejie; Shen, Yajing

    2015-04-01

    On the basis of analyzing the disadvantage of other structural accelerometer, three-axis high g MEMS piezoresistive accelerometer was put forward in order to apply to the high-shock test field. The accelerometer's structure and working principle were discussed in details. The simulation results show that three-axis high shock MEMS accelerometer can bear high shock. After bearing high shock impact in high-shock shooting test, three-axis high shock MEMS accelerometer can obtain the intact metrical information of the penetration process and still guarantee the accurate precision of measurement in high shock load range, so we can not only analyze the law of stress wave spreading and the penetration rule of the penetration process of the body of the missile, but also furnish the testing technology of the burst point controlling. The accelerometer has far-ranging application in recording the typical data that projectile penetrating hard target and furnish both technology guarantees for penetration rule and defend engineering.

  13. Roll-coating fabrication of flexible large area small molecule solar cells with power conversion efficiency exceeding 1%

    DEFF Research Database (Denmark)

    Liu, Wenqing; Liu, Shiyong; Zawacka, Natalia Klaudia

    2014-01-01

    All solution-processed flexible large area small molecule bulk heterojunction solar cells were fabricated via roll-coating technology. Our devices were produced from slot-die coating on a lab-scale mini roll-coater under ambient conditions without the use of spin-coating or vacuum evaporation.......01%, combined with an open circuit voltage of 0.73 V, a short-circuit current density of 3.13 mA cm (2) and a fill factor of 44% were obtained for the device with SM1, which was the first example reported for efficient roll-coating fabrication of flexible large area small molecule solar cells with PCE exceeding...... 1%. In addition, rollcoated devices based on SMs 2-4 also showed good performances with PCEs of 0.41%, 0.54%, and 0.31%, respectively. Our results prove that small molecules have the potential for use in industries for large scale production of efficient organic solar cells....

  14. High Thrust Efficiency MPD Thruster Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Magnetoplasmadynamic (MPD) thrusters can provide the high-specific impulse, high-power propulsion required to support human and robotic exploration missions to the...

  15. Copper-Based Ultrathin Nickel Nanocone Films with High-Efficiency Dropwise Condensation Heat Transfer Performance.

    Science.gov (United States)

    Zhao, Ye; Luo, Yuting; Zhu, Jie; Li, Juan; Gao, Xuefeng

    2015-06-10

    We report a type of copper-based ultrathin nickel nanocone films with high-efficiency dropwise condensation heat transfer (DCHT) performance, which can be fabricated by facile electrodeposition and low-surface-energy chemistry modification. Compared with flat copper samples, our nanosamples show condensate microdrop self-propelling (CMDSP) function and over 89% enhancement in the DCHT coefficient. Such remarkable enhancement may be ascribed to the cooperation of surface nanostructure-induced CMDSP function as well as in situ integration and ultrathin nature of nanofilms. These findings are very significant to design and develop advanced DCHT materials and devices, which help improve the efficiency of thermal management and energy utilization.

  16. Perovskite photovoltaics: a high-efficiency newcomer to the solar cell family.

    Science.gov (United States)

    Wang, Baohua; Xiao, Xudong; Chen, Tao

    2014-11-07

    Organometal trihalide perovskite-based light absorbers have attracted great attention due to their excellent photovoltaic properties. The swift developments in the device fabrication techniques have led to the power conversion efficiencies exceeding 17%. In this minireview, we will present the typical characteristics of the materials and device structures, followed by analysing updated understandings on the operational principles of the devices. We will also point out the outstanding issues regarding the materials and devices. Finally, as a high-efficiency newcomer to the solar cell family, the potential impact on the relevant photovoltaics will be discussed.

  17. Perovskite photovoltaics: a high-efficiency newcomer to the solar cell family

    Science.gov (United States)

    Wang, Baohua; Xiao, Xudong; Chen, Tao

    2014-10-01

    Organometal trihalide perovskite-based light absorbers have attracted great attention due to their excellent photovoltaic properties. The swift developments in the device fabrication techniques have led to the power conversion efficiencies exceeding 17%. In this minireview, we will present the typical characteristics of the materials and device structures, followed by analysing updated understandings on the operational principles of the devices. We will also point out the outstanding issues regarding the materials and devices. Finally, as a high-efficiency newcomer to the solar cell family, the potential impact on the relevant photovoltaics will be discussed.

  18. A Brief Description of High Temperature Solid Oxide Fuel Cell’s Operation, Materials, Design, Fabrication Technologies and Performance

    Directory of Open Access Journals (Sweden)

    Muneeb Irshad

    2016-03-01

    Full Text Available Today’s world needs highly efficient systems that can fulfill the growing demand for energy. One of the promising solutions is the fuel cell. Solid oxide fuel cell (SOFC is considered by many developed countries as an alternative solution of energy in near future. A lot of efforts have been made during last decade to make it commercial by reducing its cost and increasing its durability. Different materials, designs and fabrication technologies have been developed and tested to make it more cost effective and stable. This article is focused on the advancements made in the field of high temperature SOFC. High temperature SOFC does not need any precious catalyst for its operation, unlike in other types of fuel cell. Different conventional and innovative materials have been discussed along with properties and effects on the performance of SOFC’s components (electrolyte anode, cathode, interconnect and sealing materials. Advancements made in the field of cell and stack design are also explored along with hurdles coming in their fabrication and performance. This article also gives an overview of methods required for the fabrication of different components of SOFC. The flexibility of SOFC in terms fuel has also been discussed. Performance of the SOFC with varying combination of electrolyte, anode, cathode and fuel is also described in this article.

  19. PMMA lens with high efficiency and reliability

    Science.gov (United States)

    Matsuzaki, Ichiro; Abe, Koji; Fujita, Katsuhiro

    2013-09-01

    Polymethyl Methacrylate (PMMA) Fresnel lenses are increasingly being used in concentrated photovoltaic (CPV) systems installed outdoors and, accordingly, emphasis is being placed on the durability of such lenses with regard to light transmittance when subject to ultraviolet (UV) light and dust exposure. Accelerated testing methods for evaluating durability under UV exposure were established, allowing development of a lens material with improved UV resistance. Simultaneously, through a proprietary molding method, a Fresnel lens that boasts favorable light concentration efficiency with little deformation even after prolonged outdoor use was developed. Moreover, the lens incorporates a new hard-coat finish that possesses sand durability and UV resistance comparable to that of tempered glass.

  20. Efficient polymer solar cells based on poly(3-hexylthiophene) and indene-C₆₀ bisadduct fabricated with non-halogenated solvents.

    Science.gov (United States)

    Guo, Xia; Zhang, Maojie; Cui, Chaohua; Hou, Jianhui; Li, Yongfang

    2014-06-11

    The photovoltaic performance of poly(3-hexylthiophene) (P3HT) has been improved greatly by using indene-C60 bisadduct (ICBA) as acceptor instead of phenyl-C61-butyric acid methyl ester (PCBM). However, the solvent of dichlorobenzene (DCB) used in fabricating polymer solar cells (PSCs) limited the application of the PSCs, because of the environmental problem caused by the harmful halogenated solvent. In this work, we fabricated the PSCs based on P3HT/ICBA processed with four low-harmful non-halogenated solvents of toluene, o-xylene, m-xylene, and p-xylene. The PSCs based on P3HT/ICBA (1:1, w/w) with toluene as the solvent exhibit the optimized power conversion efficiency (PCE) of 4.5% with open-circuit voltage (Voc) of 0.84 V, short circuit current density (Jsc) of 7.2 mA/cm(2), and fill factor (FF) of 71%, under the illumination of AM 1.5G at 100 mW/cm(2). Upon using 1% N-methyl pyrrolidone (NMP) as a solvent additive in the toluene solvent, the PCE of the PSCs was greatly improved to 6.6% with a higher Jsc of 10.3 mA/cm(2) and a high FF of 75%, which is even higher than that of the devices fabricated with halogenated DCB solvent. The X-ray diffraction (XRD) measurement shows that the crystallinity of P3HT increased with the NMP additive. The investigations on morphology of the active layers by atomic force microscopy (AFM) and transmission electron microscopy (TEM) indicate that the NMP additive promotes effective phase separation and formation of nanoscaled interpenetrating network structure of the active layer, which is beneficial to the improvement of Jsc and PCE for the PSCs fabricated with toluene as the solvent.

  1. Quantum Confined Semiconductors for High Efficiency Photovoltaics

    Science.gov (United States)

    Beard, Matthew

    2014-03-01

    Semiconductor nanostructures, where at least one dimension is small enough to produce quantum confinement effects, provide new pathways for controlling energy flow and therefore have the potential to increase the efficiency of the primary photon-to-free energy conversion step. In this discussion, I will present the current status of research efforts towards utilizing the unique properties of colloidal quantum dots (NCs confined in three dimensions) in prototype solar cells and demonstrate that these unique systems have the potential to bypass the Shockley-Queisser single-junction limit for solar photon conversion. The solar cells are constructed using a low temperature solution based deposition of PbS or PbSe QDs as the absorber layer. Different chemical treatments of the QD layer are employed in order to obtain good electrical communication while maintaining the quantum-confined properties of the QDs. We have characterized the transport and carrier dynamics using a transient absorption, time-resolved THz, and temperature-dependent photoluminescence. I will discuss the interplay between carrier generation, recombination, and mobility within the QD layers. A unique aspect of our devices is that the QDs exhibit multiple exciton generation with an efficiency that is ~ 2 to 3 times greater than the parental bulk semiconductor.

  2. Highly Efficient PCDTBT:PC71 BM Based Photovoltaic Devices without Thermal Annealing Treatment

    Institute of Scientific and Technical Information of China (English)

    杨少鹏; 孔伟光; 刘博雅; 郑文耀; 李保民; 刘贤豪; 傅广生

    2011-01-01

    We propose an effective method to fabricate highly efficient organic photovoltaic cells based on poly [N-9"-hepta-decanyl-2, 7-carbazole-alt-5,5-(4'7'-di-2-thienyl-2'l '3'-b-enzothiadiazole):[6,6]-phenyl Cji-butyric acid methyl ester (PCDTBT.PC71BM). A power conversion efficiency of as high as 5.6% and a fill factor of 53.7% are achieved from the optimized cells. The influence of surface morphology of the active layer on the performance of the cells is also investigated.%We propose an effective method to fabricate highly efficient organic photovoltaic cells based on poly[N-9”-hepta-decanyl-2,7-carbazole-alt-5,5-(4'7'-di-2-thienyl-2'1 '3'-b-enzothiadiazole):[6,6]-phenyl C71-butyric acid methyl ester(PCDTBT:PC71BM).A power conversion efficiency of as high as 5.6% and a fill factor of 53.7% are achieved from the optimized cells.The influence of surface morphology of the active layer on the performance of the cells is also investigated.

  3. Preclinical Study for Application of Fabricated High Activity Ir-192

    Energy Technology Data Exchange (ETDEWEB)

    Chun, Mi Son; Kang, Seung Hee; Oh, Young Taek; Jeong, Chul; Kim, Mi Hwa; Hwang, Jeong Hye; Kim, Hee Seong; Im, Eun Jeong [Ajou University, Suwon (Korea, Republic of)

    2005-10-15

    This study was performed to evaluate the feasibility and safety of high activity Ir-192 sources manufactured by KAERI(Korea Atomic Energy Research Institute) for application to present equipment such as various applicators inserted to patients and PLATO(Nucletron, Netherland) of treatment planning system and to evaluate safety and accuracy of Ir-192 as practical clinic use through in vitro dosimetry of Ir-192. We confirmed the physical and radiobiological safety of KAERI sources to use practical. KAERI sources are applicable to commercial high dose rate brachytherapy machine safely. Then those can be substituted for the imported sources such as sources made by Nucletron, Gammamed and exported to the foreign country

  4. Fabrication of high gradient insulators by stack compression

    Energy Technology Data Exchange (ETDEWEB)

    Harris, John Richardson; Sanders, Dave; Hawkins, Steven Anthony; Norona, Marcelo

    2014-04-29

    Individual layers of a high gradient insulator (HGI) are first pre-cut to their final dimensions. The pre-cut layers are then stacked to form an assembly that is subsequently pressed into an HGI unit with the desired dimension. The individual layers are stacked, and alignment is maintained, using a sacrificial alignment tube that is removed after the stack is hot pressed. The HGI's are used as high voltage vacuum insulators in energy storage and transmission structures or devices, e.g. in particle accelerators and pulsed power systems.

  5. High-Efficient Circuits for Ternary Addition

    Directory of Open Access Journals (Sweden)

    Reza Faghih Mirzaee

    2014-01-01

    Full Text Available New ternary adders, which are fundamental components of ternary addition, are presented in this paper. They are on the basis of a logic style which mostly generates binary signals. Therefore, static power dissipation reaches its minimum extent. Extensive different analyses are carried out to examine how efficient the new designs are. For instance, the ternary ripple adder constructed by the proposed ternary half and full adders consumes 2.33 μW less power than the one implemented by the previous adder cells. It is almost twice faster as well. Due to their unique superior characteristics for ternary circuitry, carbon nanotube field-effect transistors are used to form the novel circuits, which are entirely suitable for practical applications.

  6. High-transparency, self-standable gel-SLIPS fabricated by a facile nanoscale phase separation.

    Science.gov (United States)

    Okada, Issei; Shiratori, Seimei

    2014-02-12

    Slippery liquid-infused porous surfaces (SLIPSs) that were both highly transparent and free-standing (self-standability) were fabricated by an extremely simple process using non-solvent-induced phase separation (NIPS) of a poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP)/di-n-butyl phthalate solution. We call these "Gel-SLIPS" because the porous PVDF-HFP film fabricated using the NIPS process has been used as a gel electrolyte in a lithium-ion battery. In previous reports, SLIPS fabrication required complex processes, high annealing temperatures, and drying. Gel-SLIPS can be fabricated from the adjusted solution and the lubricant at room temperature and pressure in 5 min by squeegee, cast, or dip methods. NIPS is based on a quick phase separation process in situ, and reduction of the surface energy is not required because of the considerable fluorine in PVDF-HFP. Moreover, because of the flexible nanonetwork structure of PVDF-HFP, Gel-SLIPS exhibited self-standability and high transmittance (>87% at 600 nm). Gel-SLIPS is thus highly versatile in terms of the fabrication process and film characteristics.

  7. Single-junction polymer solar cells with high efficiency and photovoltage

    Science.gov (United States)

    He, Zhicai; Xiao, Biao; Liu, Feng; Wu, Hongbin; Yang, Yali; Xiao, Steven; Wang, Cheng; Russell, Thomas P.; Cao, Yong

    2015-03-01

    Polymer solar cells are an exciting class of next-generation photovoltaics, because they hold promise for the realization of mechanically flexible, lightweight, large-area devices that can be fabricated by room-temperature solution processing. High power conversion efficiencies of ∼10% have already been reported in tandem polymer solar cells. Here, we report that similar efficiencies are achievable in single-junction devices by reducing the tail state density below the conduction band of the electron acceptor in a high-performance photoactive layer made from a newly developed semiconducting polymer with a deepened valence energy level. Control over band tailing is realized through changes in the composition of the active layer and the structure order of the blend, both of which are known to be important factors in cell operation. The approach yields cells with high power conversion efficiencies (∼9.94% certified) and enhanced photovoltage.

  8. Novel Polymers for High Efficiency Renewable and Portable Power Applications

    Science.gov (United States)

    2015-07-30

    systems with frontier orbital levels (HOMOs and LUMOs) and morphologies systematically investigated and optimized for high efficiency photoelectric and...of polymer-dye covalently linked systems that could efficiently convert light/heat into electrical power. Therefore, frontier orbital matching...force between the polymer and dye would result in weaker PL quenching and optoelectronic device power conversion efficiency , this experimentally

  9. Preparation of HCPT-Loaded Nanoneedles with Pointed Ends for Highly Efficient Cancer Chemotherapy

    Science.gov (United States)

    Wu, Shichao; Yang, Xiangrui; Li, Yang; Wu, Hongjie; Huang, Yu; Xie, Liya; Zhang, Ying; Hou, Zhenqing; Liu, Xiangyang

    2016-06-01

    The high-aspect-ratio nanoparticles were proved to be internalized much more rapidly and efficiently by cancer cells than the nanoparticles with an equal aspect ratio. Herein, a kind of high-aspect ratio, pointed-end nanoneedles (NDs) with a high drug loading (15.04 %) and the prolonged drug release profile were fabricated with an anti-tumor drug—10-hydroxycamptothecin (HCPT)—via an ultrasound-assisted emulsion crystallization technique. It is surprising to see that the cellular internalization of NDs with an average length of 5 μm and an aspect ratio of about 12:1 was even much faster and higher than that of nanorods with the same size and the nanospheres with a much smaller size of 150 nm. The results further validated that cellular internalization of the nanoparticles exhibited a strong shape-dependent effect, and cellular uptake may favor the particles with sharp ends as well as a high-aspect ratio instead of particle size. The NDs with enhanced cytotoxicity would lead to a promising sustained local drug delivery system for highly efficient anticancer therapy. More importantly, the fabrication of NDs opens a door to design new formulations of nanoneedle drug delivery systems for highly efficient cancer.

  10. Highly efficient multifunctional metasurface for high-gain lens antenna application

    Science.gov (United States)

    Hou, Haisheng; Wang, Guangming; Li, Haipeng; Guo, Wenlong; Li, Tangjing

    2017-07-01

    In this paper, a novel multifunctional metasurface combining linear-to-circular polarization conversion and electromagnetic waves focusing has been proposed and applied to design a high-gain lens antenna working at Ku band. The multifunctional metasurface consists of 15 × 15 unit cells. Each unit cell is composed of four identical metallic layers and three intermediate dielectric layers. Due to well optimization, the multifunctional metasurface can convert the linearly polarized waves generated by the source to circularly polarized waves and focus the waves. By placing a patch antenna operating at 15 GHz at the focal point of the metasurface and setting the focal distance to diameter ratio ( F/ D) to 0.34, we obtain a multifunctional lens antenna. Simulated and measured results coincide well, indicating that the metasurface can convert linearly polarized waves to right-handed circularly polarized waves at 15 GHz with excellent performances in terms of the 3 dB axial ratio bandwidth of 5.3%, realized gain of 16.9 dB and aperture efficiency of 41.2%. Because of the advantages of high gain, competitive efficiency and easy fabrication, the proposed lens antenna has a great potential application in wireless and satellite communication.

  11. Fabrication of highly modulable fibrous 3D extracellular microenvironments

    KAUST Repository

    Zhang, Xixiang

    2017-06-13

    Three-dimensional (3D) in vitro scaffolds that mimic the irregular fibrous structures of in vivo extracellular matrix (ECM) are critical for many important biological applications. However, structural properties modulation of fibrous 3D scaffolds remains a challenge. Here, we report the first highly modulable 3D fibrous scaffolds self-assembled by high-aspect-ratio (HAR) microfibers. The scaffolds structural properties can be easily tailored to incorporate various physical cues, including geometry, stiffness, heterogeneity and nanotopography. Moreover, the fibrous scaffolds are readily and accurately patterned on desired locations of the substrate. Cell culture exhibits that our scaffolds can elicit strong bidirectional cell-material interactions. Furthermore, a functional disparity between the two-dimensional substrate and our 3D scaffolds is identified by cell spreading and proliferation data. These results prove the potential of the proposed scaffold as a biomimetic extracellular microenvironment for cell study.

  12. Photolithographic Approaches for Fabricating Highly Ordered Nanopatterned Arrays

    Directory of Open Access Journals (Sweden)

    Li Xiaoru

    2008-01-01

    Full Text Available Abstract In this work, we report that large area metal nanowire and polymer nanotube arrays were successfully patterned by photolithographic approach using anodic aluminum oxide (AAO templates. Nanowires were produced by electrochemical deposition, and nanotubes by solution-wetting. The highly ordered patterns of nanowire and nanotube arrays were observed using scanning electron microscopy (SEM and found to stand free on the substrate. The method is expected to play an important role in the application of microdevices in the future.

  13. New fabrication techniques for high dynamic range tunneling sensors

    Science.gov (United States)

    Chang, David T.; Stratton, Fred P.; Kubena, Randall L.; Vickers-Kirby, Deborah J.; Joyce, Richard J.; Schimert, Thomas R.; Gooch, Roland W.

    2000-08-01

    We have developed high dynamic range (105-106 g's) tunneling accelerometers1,2 that may be ideal for smart munitions applications by employing both surface and bulk micromachining processing techniques. The highly miniaturized surface-micromachined devices can be manufactured at very low cost and integrated on chip with the control electronics. Bulk-micromachined devices with Si as the cantilever material should have reduced long-term bias drift as well as better stability at higher temperatures. Fully integrated sensors may provide advantages in minimizing microphonics for high-g applications. Previously, we described initial test results using electrostatic forces generated by a self-test electrode located under a Au cantilever3. In this paper, we describe more recent testing of Ni and Au cantilever devices on a shaker table using a novel, low input voltage (5 V) servo controller on both printed wiring board and surface-mount control circuitry. In addition, we report our initial test results for devices packaged using a low-temperature wafer-level vacuum packaging technique for low-cost manufacturing.

  14. Fabrication of interconnected microporous biomaterials with high hydroxyapatite nanoparticle loading

    Energy Technology Data Exchange (ETDEWEB)

    Zhang Wei; Yao Donggang [School of Polymer Textile and Fiber Engineering, Georgia Institute of Technology, Atlanta, GA (United States); Zhang Qingwei; Lelkes, Peter I [School of Biomedical Engineering, Science, and Health Systems, Drexel University, Philadelphia, PA 19104 (United States); Zhou, Jack G, E-mail: yao@gatech.ed [Department of Mechanical Engineering and Mechanics, Drexel University, Philadelphia, PA 19104 (United States)

    2010-09-15

    Hydroxyapatite (HA) is known to promote osteogenicity and enhance the mechanical properties of biopolymers. However, incorporating a large amount of HA into a porous biopolymer still remains a challenge. In the present work, a new method was developed to produce interconnected microporous poly(glycolic-co-lactic acid) (PLGA) with high HA nanoparticle loading. First, a ternary blend comprising PLGA/PS (polystyrene)/HA (40/40/20 wt%) was prepared by melt blending under conditions for formation of a co-continuous phase structure. Next, a dynamic annealing stage under small-strain oscillation was applied to the blend to facilitate nanoparticle redistribution. Finally, the PS phase was sacrificially extracted, leaving a porous matrix. The results from different characterizations suggested that the applied small-strain oscillation substantially accelerated the migration of HA nanoparticles during annealing from the PS phase to the PLGA phase; nearly all HA particles were uniformly presented in the PLGA phase after a short period of annealing. After dissolution of the PS phase, a PLGA material with interconnected microporous structure was successfully produced, with a high HA loading above 30 wt%. The mechanisms beneath the experimental observations, particularly on the enhanced particle migration process, were discussed, and strategies for producing highly particle loaded biopolymers with interconnected microporous structures were proposed.

  15. High Efficiency Regenerative Helium Compressor Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Helium plays several critical rolls in spacecraft propulsion. High pressure helium is commonly used to pressurize propellant fuel tanks. Helium cryocoolers can be...

  16. Advanced High Efficiency Durable DACS Thruster Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Systima is developing a high performance 25 lbf DACS thruster that operates with a novel non-toxic monopropellant. The monopropellant has a 30% higher...

  17. Novel CdTe Cell Fabrication Process with Potential for Low Cost and High Throughput

    Energy Technology Data Exchange (ETDEWEB)

    Wu, X.; Sheldon, P.

    2000-01-01

    There are several production disadvantages inherent in the conventional SnO(2)/CdS/CdTe manufacturing processes. In this paper, we report a novel manufacturing process for fabrication of polycrystalline Cd(2)SnO(4)/Zn(2)/SnO(4)/CdS/CdTe thin-film solar cells that yielded a CdS/CdTe device with an NREL-confirmed efficiency of 14.0%.

  18. Fabrication of the high power input coupler for BEPCⅡ superconducting cavities

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    The BEPCII storage ring adopts two 500 MHz superconducting cavities (SCC). Each one is equipped with a 500 MHz input power coupler. The coupler is to feed 150 kW power in continuous wave (CW) mode with both standing and traveling wave modes. Due to high power feeding and high frequency of the coupler, its fabrication is a big challenge. The fabrication started with two key components, the window and the antenna. Up to now, two sets including windows and antennas have beam made by IHEP. And a 270 kW RF power in CW has passed through the coupler during the high power test. The fabrication details are presented in this paper.

  19. High frequency PMN-PT single crystal focusing transducer fabricated by a mechanical dimpling technique.

    Science.gov (United States)

    Chen, Y; Lam, K H; Zhou, D; Cheng, W F; Dai, J Y; Luo, H S; Chan, H L W

    2013-02-01

    High frequency (∼30MHz and ∼80MHz) focusing ultrasound transducers were fabricated using a PMN-0.28PT single crystal by a mechanical dimpling technique. The dimpled single crystal was used as an active element for the focusing transducer. Compared with a plane transducer, the focusing transducer fabricated with a dimpled active element exhibits much broader bandwidth and higher sensitivity. Besides, a high quality image can be obtained by the 30MHz focusing transducer, in which the -6dB axial and lateral resolution is 27μm and 139μm, respectively. These results prove that the dimpling technique is capable to fabricate the high frequency focusing transducers with excellent performance for imaging applications.

  20. Femtosecond laser fabrication of highly hydrophobic stainless steel surface with hierarchical structures fabricated by combining ordered microstructures and LIPSS

    Science.gov (United States)

    Martínez-Calderon, M.; Rodríguez, A.; Dias-Ponte, A.; Morant-Miñana, M. C.; Gómez-Aranzadi, M.; Olaizola, S. M.

    2016-06-01

    In this work we have developed hierarchical structures that consist of micro-patterned surfaces covered by nanostructures with a femtosecond laser. The first part of this work is a study to determine the microscale modifications produced on a stainless steel alloy (AISI304) surface at high pulse energy, different velocities, and number of overscans in order to obtain microstructures with a selected depth of around 10 μm and line widths of 20 μm. The second part of the work is focused on finding the optimal irradiation parameters to obtain the nanostructure pattern. Nanostructures have been defined by means of Laser Induced Periodical Surface Structures (LIPSS) around 250 nm high and a period of 580 nm, which constitute the nanostructure pattern. Finally, dual scale gratings of 50 mm2 were fabricated with different geometries and their effect on the measured contact angle. Combining the micro-pattern with the LIPSS nano-pattern, highly hydrophobic surfaces have been developed with measured static contact angles higher than 150° on a stainless steel alloy.

  1. Preparation of highly efficient manganese catalase mimics.

    Science.gov (United States)

    Triller, Michael U; Hsieh, Wen-Yuan; Pecoraro, Vincent L; Rompel, Annette; Krebs, Bernt

    2002-10-21

    The series of compounds [Mn(bpia)(mu-OAc)](2)(ClO(4))(2) (1), [Mn(2)(bpia)(2)(muO)(mu-OAc)](ClO(4))(3).CH(3)CN (2), [Mn(bpia)(mu-O)](2)(ClO(4))(2)(PF(6)).2CH(3)CN (3), [Mn(bpia)(Cl)(2)](ClO)(4) (4), and [(Mn(bpia)(Cl))(2)(mu-O)](ClO(4))(2).2CH(3)CN (5) (bpia = bis(picolyl)(N-methylimidazol-2-yl)amine) represents a structural, spectroscopic, and functional model system for manganese catalases. Compounds 3 and 5 have been synthesized from 2 via bulk electrolysis and ligand exchange, respectively. All complexes have been structurally characterized by X-ray crystallography and by UV-vis and EPR spectroscopies. The different bridging ligands including the rare mono-mu-oxo and mono-mu-oxo-mono-mu-carboxylato motifs lead to a variation of the Mn-Mn separation across the four binuclear compounds of 1.50 A (Mn(2)(II,II) = 4.128 A, Mn(2)(III,III) = 3.5326 and 3.2533 A, Mn(2)(III,IV) = 2.624 A). Complexes 1, 2, and 3 are mimics for the Mn(2)(II,II), the Mn(2)(III,III), and the Mn(2)(III,IV) oxidation states of the native enzyme. UV-vis spectra of these compounds show similarities to those of the corresponding oxidation states of manganese catalase from Thermus thermophilus and Lactobacillus plantarum. Compound 2 exhibits a rare example of a Jahn-Teller compression. While complexes 1 and 3 are efficient catalysts for the disproportionation of hydrogen peroxide and contain an N(4)O(2) donor set, 4 and 5 show no catalase activity. These complexes have an N(4)Cl(2) and N(4)OCl donor set, respectively, and serve as mimics for halide inhibited manganese catalases. Cyclovoltammetric data show that the substitution of oxygen donor atoms with chloride causes a shift of redox potentials to more positive values. To our knowledge, complex 1 is the most efficient binuclear functional manganese catalase mimic exhibiting saturation kinetics to date.

  2. Highly smooth Nb surfaces fabricated by buffered electropolishing

    Energy Technology Data Exchange (ETDEWEB)

    Andy T. Wu; John Mammossor; H. Phillips; Jean Delayen; Charles Reece; Amy Wilkerson; David Smith; Robert Ike

    2005-05-01

    It is demonstrated that highly smooth Nb surfaces can be obtained through Buffered ElectroPolishing (BEP) employing an electrolyte consisting of lactic, sulfuric, and hydrofluoric acids. Parameters that control the polishing process are optimized to achieve the smoothest surface finish with the help of surface observations using a scanning electron microscope and a Metallographic Optical Microscope (MOM). The polishing rate of BEP is determined to be 0.646 {micro}m/min that is much higher than 0.381 {micro}m/min achieved by the conventional ElectroPolishing (EP) process widely used in the Superconducting Radio Frequency (SRF) community. A high precision and large scan area 3-D profilometer is used to view morphology of the treated Nb surfaces. Statistical data, such as, rms, total indicator runout, and arithmetic mean deviation of the Nb surfaces are extracted from the profilometer images. It is found that Nb surfaces treated by BEP are an order of magnitude smoother than those treated by the optimized EP process. The chemical composition of the Nb surfaces after BEP is analyzed by static and dynamic Secondary Ion Mass Spectrometer (SIMS) systems. Cracking patterns of the Nb surfaces under different primary ion sources of Ga{sup +}, Au{sup +}, and Ar{sup +} are reported. The depth profile of the surface niobium oxides is studied through continuously monitoring niobium and its relevant oxides' peaks as a function of time. Dynamic SIMS results imply that the surface oxide structure of Nb may be more complicated than what usually believed and can be inhomogeneous. Preliminary results of BEP on Nb SRF single cell cavities and half-cells are reported. It is shown that smooth and bright surfaces can be obtained in 30 minutes when the electric field inside a SRF cavity is uniform during a BEP process. This study reveals that BEP is a highly promising technique for surface treatment on Nb SRF cavities to be used in particle accelerators.

  3. Photosynthetic Diurnal Variation of Soybean Cultivars with High Photosynthetic Efficiency

    Institute of Scientific and Technical Information of China (English)

    MAN Wei-qun; DU Wei-guang; ZHANG Gui-ru; LUAN Xiao-yan; GE Qiao-ying; HAO Nai-bin; CHEN Yi

    2002-01-01

    The photosynthetic characters were investigated among soybean cultivars with high photosynthetic efficiency and high yield. The results indicated that: 1) There were significant differences in photosynthetic rate (Ph) and dark respiration rate (DR) under saturation light intensity and appropriate temperature.2) There were a little difference in light compensation point among them. Photo flux density (PFD) were mong the cultivars. Diurnal variation of Pn was shown a curve with two peaks. 4) The cultivars with high photosynthetic efficiency were subjected less to photoinhibition than that with high yield. Critical temperatures of photoinhibition in high photosynthetic efficiency cultivars were higher than that of high yield.

  4. High-Efficiency Polycrystalline Thin Film Tandem Solar Cells.

    Science.gov (United States)

    Kranz, Lukas; Abate, Antonio; Feurer, Thomas; Fu, Fan; Avancini, Enrico; Löckinger, Johannes; Reinhard, Patrick; Zakeeruddin, Shaik M; Grätzel, Michael; Buecheler, Stephan; Tiwari, Ayodhya N

    2015-07-16

    A promising way to enhance the efficiency of CIGS solar cells is by combining them with perovskite solar cells in tandem devices. However, so far, such tandem devices had limited efficiency due to challenges in developing NIR-transparent perovskite top cells, which allow photons with energy below the perovskite band gap to be transmitted to the bottom cell. Here, a process for the fabrication of NIR-transparent perovskite solar cells is presented, which enables power conversion efficiencies up to 12.1% combined with an average sub-band gap transmission of 71% for photons with wavelength between 800 and 1000 nm. The combination of a NIR-transparent perovskite top cell with a CIGS bottom cell enabled a tandem device with 19.5% efficiency, which is the highest reported efficiency for a polycrystalline thin film tandem solar cell. Future developments of perovskite/CIGS tandem devices are discussed and prospects for devices with efficiency toward and above 27% are given.

  5. Revealing the potential of Didodecyldimethylammonium bromide as efficient scaffold for fabrication of nano liquid crystalline structures.

    Science.gov (United States)

    Kanwar, Rohini; Kaur, Gurpreet; Mehta, S K

    2016-03-01

    To exploit the potential of Didodecyldimethylammonium bromide (D12DAB) as a core lipidic constituent, an attempt was made to fabricate and optimize cationic nanostructured lipid carriers (cNLCs) using a cost-effective microemulsification methodology. Designed composition was optimized by studying the effect of different microemulsion components on D12DAB cNLCs characteristics. ​Spherical shaped D12DAB cNLCs were obtained with an average size of ∼160 nm and zeta potential of +30.2 mV. Differential Scanning Calorimetry (DSC) depicted the presence of thermotropic character, whereas polarized optical microscopy confirmed the mesophase like behavior of D12DAB based cNLCs. In addition, hemolysis analysis revealed that the toxicity was concentration dependent as LC50 was reached at a concentration of 50 μg/mL of cNLCs. This class of cNLCs is expected to become a potent candidate for a broad spectrum of medicaments as carriers, targeting for pharmaceutical and medicinal purposes, due to the combination of a hard lipid with a soft lipid, where the liquid crystalline structure of the lipid co-exists.

  6. Compound-fluidic electrospray:An efficient method for the fabrication of microcapsules with multicompartment structure

    Institute of Scientific and Technical Information of China (English)

    CHEN HongYan; ZHAO Yong; JIANG Lei

    2009-01-01

    Microcapsules with multiple compartments are of significant importance in many applications such as smart drug delivery,microreactor,complicated sensor,end so on. Here we report a novel compound-fluidic electrospray method that could fabricate multicompartment microcapsules in a single step. The as-prepared microcapsules have multiple compartments inside. The compartments are separated from each other by inner walls made from shell materials,and different content can be independently loaded in each of them without any contact. We assemble a hierarchical compound nozzle by inserting certain numbers of metallic inner capillaries separately into a blunt metal needle. The particular configuration of the compound nozzle induces a completely and independently envelope of core fluids by shell fluid,as a result of which mulicomponent microcapsules with multicompartment structure can be obtained. And also,the number of inner compartments and the corresponding encapsulated components can be controlled by rationally designing the configuration of the compound nozzle.This general method can be readily extended to many other functional materials,especially for the effective encapsulation of active ingredients,such as sensitive and reactive materials.

  7. High-strength high-conductivity Cu-Nb microcomposite sheet fabricated via multiple roll bonding

    Science.gov (United States)

    Jha, S. C.; Delagi, R. G.; Forster, J. A.; Krotz, P. D.

    1993-01-01

    Copper-niobium microcomposites are a new class of high-strength high-conductivity materials that have attractive properties for room- and elevated-temperature applications. Since Nb has little solid solubility in Cu, addition of Nb to Cu does not affect its conductivity. Copper-niobium microcomposites are melted and cast so that the microstructure of cast Cu-Nb ingots consists of 1-to 10 μm Nb dendrites uniformly distributed within the copper matrix. Extensive wire drawing with a true processing strain ( η > 12) of Cu-Nb alloy leads to refinement and elongation of Nb dendrites into 1-to 10 nm-thick filaments. The presence of such fine Nb filaments causes a significant increase in the strength of Cu-Nb wires. The tensile strength of heavily drawn Cu-Nb wires was determined to be significantly higher than the values predicted by the rule of mixtures. This article reports the fabrication of high-strength Cu-Nb micro-composite sheet by multiple roll bonding. It is difficult and impractical to attain high processing strains ( η > 3) by simple cold rolling. In most practical cold-rolling operation, the thickness reduction does not exceed 90 pct ( η ≅ 2). Therefore, innovative processing is required to generate high strength in Cu-Nb microcomposite sheet. Multiple roll bonding of Cu-Nb has been utilized to store high processing strain ( η > 10) in the material and refine the Nb particle size within the copper matrix. This article describes the microstructure, mechanical properties, and thermal stability of roll-bonded Cu-Nb microcomposite sheet.

  8. High efficiency thin film CdTe and a-Si based solar cells

    Energy Technology Data Exchange (ETDEWEB)

    Compaan, A. D.; Deng, X.; Bohn, R. G.

    2000-01-04

    This report describes work done by the University of Toledo during the first year of this subcontract. During this time, the CdTe group constructed a second dual magnetron sputter deposition facility; optimized reactive sputtering for ZnTe:N films to achieve 10 ohm-cm resistivity and {approximately}9% efficiency cells with a copper-free ZnTe:N/Ni contact; identified Cu-related photoluminescence features and studied their correlation with cell performance including their dependence on temperature and E-fields; studied band-tail absorption in CdS{sub x}Te{sub 1{minus}x} films at 10 K and 300 K; collaborated with the National CdTe PV Team on (1) studies of high-resistivity tin oxide (HRT) layers from ITN Energy Systems, (2) fabrication of cells on the HRT layers with 0, 300, and 800-nm CdS, and (3) preparation of ZnTe:N-based contacts on First Solar materials for stress testing; and collaborated with Brooklyn College for ellipsometry studies of CdS{sub x}Te{sub 1{minus}x} alloy films, and with the University of Buffalo/Brookhaven NSLS for synchrotron X-ray fluorescence studies of interdiffusion in CdS/CdTe bilayers. The a-Si group established a baseline for fabricating a-Si-based solar cells with single, tandem, and triple-junction structures; fabricated a-Si/a-SiGe/a-SiGe triple-junction solar cells with an initial efficiency of 9.7% during the second quarter, and 10.6% during the fourth quarter (after 1166 hours of light-soaking under 1-sun light intensity at 50 C, the 10.6% solar cells stabilized at about 9%); fabricated wide-bandgap a-Si top cells, the highest Voc achieved for the single-junction top cell was 1.02 V, and top cells with high FF (up to 74%) were fabricated routinely; fabricated high-quality narrow-bandgap a-SiGe solar cells with 8.3% efficiency; found that bandgap-graded buffer layers improve the performance (Voc and FF) of the narrow-bandgap a-SiGe bottom cells; and found that a small amount of oxygen partial pressure ({approximately}2 {times} 10

  9. Fabrication of highly uniform conductive polypyrrole nanowires with DNA template.

    Science.gov (United States)

    Moon, Hock Key; Kim, Hyung Jin; Kim, Nam-Hoon; Roh, Yonghan

    2010-05-01

    Deoxyribonucleic acid (DNA) is considered as one of the alternative materials for electronic device applications; however, DNA has critical limitation to electronic device applications due to its low electrical conductivity and unreliability. Therefore, it is required for electronic devices to prepare the well defined conductive polymer nanowires with DNA as a template. Polypyrrole (PPy) is an attractive polymer due to its high conductivity and environmental stability in bulk; although it is well known that ammonium persulfate (APS) used for the polymerization of pyrrole causes the deformation of DNA molecules. We minimized the damage of immobilized DNA strands on (3-aminopropyl) triethoxysilane (APTES) modified silicon wafer during APS polymerization. Atomic force microscopy (AFM) images from different APS treatment times and from using the vortex process obviously showed the effect on the synthesis of individual and continuous polypyrrole nanowires (PPy NWs). The PPy NWs at various pyrrole concentrations had similar height; however, the higher concentration gave more residues. Fourier transform-infrared spectroscopy (FT-IR) spectroscopy provided the strong evidence that PPy NWs were successfully synthesized on the DNA strands.

  10. Simple and fast fabrication of superhydrophobic metal wire mesh for efficiently gravity-driven oil/water separation.

    Science.gov (United States)

    Song, Botao

    2016-12-15

    Superhydrophobic metal wire mesh (SMWM) has frequently been applied for the selective and efficient separation of oil/water mixture due to its porous structure and special wettability. However, current methods for the modification of metal wire mesh to be superhydrophobic suffered from problems with respect to complex experimental procedures or time-consuming process. In this study, a very simple, time-saving and single-step electrospray method was proposed to fabricate SMWM and the whole procedure required about only 2min. The morphology, surface composition and wettability of the SMWM were all evaluated, and the oil/water separation ability was further investigated. In addition, a commercial available sponge covered with SMWM was fabricated as an oil adsorbent for the purpose of oil recovery. This study demonstrated a convenient and fast method to modify the metal wire mesh to be superhydrophobic and such simple method might find practical applications in the large-scale removal of oils. Copyright © 2016 Elsevier Ltd. All rights reserved.

  11. Single-step direct fabrication of pillar-on-pore hybrid nanostructures in anodizing aluminum for superior superhydrophobic efficiency.

    Science.gov (United States)

    Jeong, Chanyoung; Choi, Chang-Hwan

    2012-02-01

    Conventional electrochemical anodizing processes of metals such as aluminum typically produce planar and homogeneous nanopore structures. If hydrophobically treated, such 2D planar and interconnected pore structures typically result in lower contact angle and larger contact angle hysteresis than 3D disconnected pillar structures and, hence, exhibit inferior superhydrophobic efficiency. In this study, we demonstrate for the first time that the anodizing parameters can be engineered to design novel pillar-on-pore (POP) hybrid nanostructures directly in a simple one-step fabrication process so that superior surface superhydrophobicity can also be realized effectively from the electrochemical anodization process. On the basis of the characteristic of forming a self-ordered porous morphology in a hexagonal array, the modulation of anodizing voltage and duration enabled the formulation of the hybrid-type nanostructures having controlled pillar morphology on top of a porous layer in both mild and hard anodization modes. The hybrid nanostructures of the anodized metal oxide layer initially enhanced the surface hydrophilicity significantly (i.e., superhydrophilic). However, after a hydrophobic monolayer coating, such hybrid nanostructures then showed superior superhydrophobic nonwetting properties not attainable by the plain nanoporous surfaces produced by conventional anodization conditions. The well-regulated anodization process suggests that electrochemical anodizing can expand its usefulness and efficacy to render various metallic substrates with great superhydrophilicity or -hydrophobicity by directly realizing pillar-like structures on top of a self-ordered nanoporous array through a simple one-step fabrication procedure.

  12. Orbital angular momentum generation and mode transformation with high efficiency using forked polarization gratings.

    Science.gov (United States)

    Li, Yanming; Kim, Jihwan; Escuti, Michael J

    2012-12-01

    We present a novel optical element that efficiently generates orbital angular momentum (OAM) of light and transforms light between OAM modes based on a polarization grating with a fork-shaped singularity. This forked polarization grating (FPG) is composed of liquid crystalline materials, and can be made either static or switchable with high diffraction efficiency (i.e., 100% theoretically) into a single order. By spatially varying the Pancharatnam-Berry phase, FPGs shape the wavefront and thus control the OAM mode. We demonstrate theoretically and empirically that a charge l(g) FPG creates helical modes with OAM charge ±l(g) when a gaussian beam is input, and more generally, transforms the incident helical mode with OAM charge l(in) into output modes with OAM charge l(in)±l(g). We also show for the first time that this conversion into a single mode can be very efficient (i.e., ∼95% experimentally) at visible wavelengths, and the relative power between the two possible output modes is polarization-controllable from 0% to ∼100%. We developed a fabrication method that substantially improves FPG quality and efficiency over prior work. We also successfully fabricated switchable FPGs, which can be electrically switched between an OAM generating/transforming state and a transmissive state. Our experimental results showed >92% conversion efficiency for both configurations at 633 nm. These holographically fabricated elements are compact (i.e., thin glass plates), lightweight, and easily optimized for nearly any wavelength from ultraviolet to infrared, for a wide range of OAM charge, and for large or small clear apertures. They are ideal elements for enhanced control of OAM, e.g., in optical trapping and high-capacity information.

  13. Silicon Needles Fabricated by Highly Selective Anisotropic Dry Etching and Their Field Emission Current Characteristics

    Science.gov (United States)

    Kanechika, Masakazu; Mitsushima, Yasuichi

    2000-12-01

    A new process to fabricate a silicon needle, whose tip radius is about 5 nm and aspect ratio is about 7, was developed. The silicon needles were fabricated by highly selective anisotropic dry etching. The etching mask was oxygen precipitation, which was formed by nitrogen ion implantation and the subsequent oxidation. The process is simple enough to be integrated with complementary metal-oxide-semiconductor (CMOS) circuits. The density of the silicon needle can be controlled by adjusting the dose for nitrogen ion implantation. The position of the silicon needle can be controlled by adjusting the position for nitrogen ion implantation, because silicon needles are formed only in the nitrogen ion implantation area. Furthermore, using these silicon needles as micro emitters, a field emission diode was fabricated. The Fowler-Nordheim plot shows that the field around the tip of the silicon needles was highly enhanced.

  14. Biologically inspired highly efficient buoyancy engine

    Science.gov (United States)

    Akle, Barbar; Habchi, Wassim; Abdelnour, Rita; Blottman, John, III; Leo, Donald

    2012-04-01

    Undersea distributed networked sensor systems require a miniaturization of platforms and a means of both spatial and temporal persistence. One aspect of this system is the necessity to modulate sensor depth for optimal positioning and station-keeping. Current approaches involve pneumatic bladders or electrolysis; both require mechanical subsystems and consume significant power. These are not suitable for the miniaturization of sensor platforms. Presented in this study is a novel biologically inspired method that relies on ionic motion and osmotic pressures to displace a volume of water from the ocean into and out of the proposed buoyancy engine. At a constant device volume, the displaced water will alter buoyancy leading to either sinking or floating. The engine is composed of an enclosure sided on the ocean's end by a Nafion ionomer and by a flexible membrane separating the water from a gas enclosure. Two electrodes are placed one inside the enclosure and the other attached to the engine on the outside. The semi-permeable membrane Nafion allows water motion in and out of the enclosure while blocking anions from being transferred. The two electrodes generate local concentration changes of ions upon the application of an electrical field; these changes lead to osmotic pressures and hence the transfer of water through the semi-permeable membrane. Some aquatic organisms such as pelagic crustacean perform this buoyancy control using an exchange of ions through their tissue to modulate its density relative to the ambient sea water. In this paper, the authors provide an experimental proof of concept of this buoyancy engine. The efficiency of changing the engine's buoyancy is calculated and optimized as a function of electrode surface area. For example electrodes made of a 3mm diameter Ag/AgCl proved to transfer approximately 4mm3 of water consuming 4 Joules of electrical energy. The speed of displacement is optimized as a function of the surface area of the Nafion

  15. Self-assembly of highly efficient, broadband plasmonic absorbers for solar steam generation.

    Science.gov (United States)

    Zhou, Lin; Tan, Yingling; Ji, Dengxin; Zhu, Bin; Zhang, Pei; Xu, Jun; Gan, Qiaoqiang; Yu, Zongfu; Zhu, Jia

    2016-04-01

    The study of ideal absorbers, which can efficiently absorb light over a broad range of wavelengths, is of fundamental importance, as well as critical for many applications from solar steam generation and thermophotovoltaics to light/thermal detectors. As a result of recent advances in plasmonics, plasmonic absorbers have attracted a lot of attention. However, the performance and scalability of these absorbers, predominantly fabricated by the top-down approach, need to be further improved to enable widespread applications. We report a plasmonic absorber which can enable an average measured absorbance of ~99% across the wavelengths from 400 nm to 10 μm, the most efficient and broadband plasmonic absorber reported to date. The absorber is fabricated through self-assembly of metallic nanoparticles onto a nanoporous template by a one-step deposition process. Because of its efficient light absorption, strong field enhancement, and porous structures, which together enable not only efficient solar absorption but also significant local heating and continuous stream flow, plasmonic absorber-based solar steam generation has over 90% efficiency under solar irradiation of only 4-sun intensity (4 kW m(-2)). The pronounced light absorption effect coupled with the high-throughput self-assembly process could lead toward large-scale manufacturing of other nanophotonic structures and devices.

  16. Structural and electrical characteristics of high-k/metal gate metal oxide semiconductor capacitors fabricated on flexible, semi-transparent silicon (100) fabric

    KAUST Repository

    Rojas, Jhonathan Prieto

    2013-02-12

    In pursuit of flexible computers with high performance devices, we demonstrate a generic process to fabricate 10 000 metal-oxide-semiconductor capacitors (MOSCAPs) with semiconductor industry\\'s most advanced high-k/metal gate stacks on widely used, inexpensive bulk silicon (100) wafers and then using a combination of iso-/anisotropic etching to release the top portion of the silicon with the already fabricated devices as a mechanically flexible (bending curvature of 133 m−1), optically semi-transparent silicon fabric (1.5 cm × 3 cm × 25 μm). The electrical characteristics show 3.7 nm effective oxide thickness, −0.2 V flat band voltage, and no hysteresis from the fabricated MOSCAPs.

  17. 40 CFR 761.71 - High efficiency boilers.

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 30 2010-07-01 2010-07-01 false High efficiency boilers. 761.71... PROHIBITIONS Storage and Disposal § 761.71 High efficiency boilers. (a) To burn mineral oil dielectric fluid containing a PCB concentration of ≥50 ppm, but boiler shall comply with the...

  18. High efficiency low cost GaAs/Ge cell technology

    Science.gov (United States)

    Ho, Frank

    1990-01-01

    Viewgraphs on high efficiency low cost GaAs/Ge cell technology are presented. Topics covered include: high efficiency, low cost GaAs/Ge solar cells; advantages of Ge; comparison of typical production cells for space applications; panel level comparisons; and solar cell technology trends.

  19. Energy Efficient and Compact RF High-Power Amplifiers

    NARCIS (Netherlands)

    Calvillo Cortés, D.A.

    2014-01-01

    The main objectives of this thesis are to improve the energy efficiency and physical form-factor of high-power amplifiers in base station applications. As such, the focus of this dissertation is placed on the outphasing amplifier concept, which can offer high-efficiency, good linearity and excellent

  20. Highly efficient carrier multiplication in PbS nanosheets

    NARCIS (Netherlands)

    Aerts, M.; Bielewicz, T.; Klinke, C.; Grozema, F.C.; Houtepen, A.J.; Schins, J.M.; Siebbeles, L.D.A.

    2014-01-01

    Semiconductor nanocrystals are promising for use in cheap and highly efficient solar cells. A high efficiency can be achieved by carrier multiplication (CM), which yields multiple electron-hole pairs for a single absorbed photon. Lead chalcogenide nanocrystals are of specific interest, since their b

  1. Thin Film Packaging Solutions for High Efficiency OLED Lighting Products

    Energy Technology Data Exchange (ETDEWEB)

    None

    2008-06-30

    was characterized as having less than 10% change in transmission during the 15,000 hour test period; (3) demonstrated thin film encapsulation of a phosphorescent OLED device with 1,500 hours of lifetime at 60 C and 80% RH; (4) demonstrated that a thin film laminate encapsulation, in addition to the direct thin film deposition process, of a polymer OLED device was another feasible packaging strategy for OLED lighting. The thin film laminate strategy was developed to mitigate defects, demonstrate roll-to-roll process capability for high volume throughput (reduce costs) and to support a potential commercial pathway that is less dependent upon integrated manufacturing since the laminate could be sold as a rolled good; (5) demonstrated that low cost 'blue' glass substrates could be coated with a siloxane barrier layer for planarization and ion-protection and used in the fabrication of a polymer OLED lighting device. This study further demonstrated that the substrate cost has potential for huge cost reductions from the white borosilicate glass substrate currently used by the OLED lighting industry; (6) delivered four-square feet of white phosphorescent OLED technology, including novel high efficiency devices with 82 CRI, greater than 50 lm/W efficiency, and more than 1,000 hours lifetime in a product concept model shelf; (7) presented and or published more than twenty internal studies (for private use), three external presentations (OLED workshop-for public use), and five technology-related external presentations (industry conferences-for public use); and (8) issued five patent applications, which are in various maturity stages at time of publication. Delivery of thin film encapsulated white phosphorescent OLED lighting technology remains a challenging technical achievement, and it seems that commercial availability of thin, bright, white OLED light that meets market requirements will continue to require research and development effort. However, there will be

  2. Highly efficient sources of single indistinguishable photons

    DEFF Research Database (Denmark)

    Gregersen, Niels

    2013-01-01

    Solid-state sources capable of emitting single photons on demand are of great interest in quantum information applications. Ideally, such a source should emit exactly one photon into the collection optics per trigger, the emitted photons should be indistinguishable and the source should...... be electrically driven. Several design strategies addressing these requirements have been proposed. In the cavity-based source, light emission is controlled using resonant cavity quantum electrodynamics effects, whereas in the waveguide-based source, broadband electric field screening effects are employed...... to direct the light emission into the optical mode of interest. For all the strategies, accurate modeling and careful optical engineering is required to achieve high performance....

  3. High-Efficiency Nitride-Based Solid-State Lighting

    Energy Technology Data Exchange (ETDEWEB)

    Paul T. Fini; Shuji Nakamura

    2005-07-30

    In this final technical progress report we summarize research accomplished during Department of Energy contract DE-FC26-01NT41203, entitled ''High-Efficiency Nitride-Based Solid-State Lighting''. Two teams, from the University of California at Santa Barbara (Principle Investigator: Dr. Shuji Nakamura) and the Lighting Research Center at Rensselaer Polytechnic Institute (led by Dr. N. Narendran), pursued the goals of this contract from thin film growth, characterization, and packaging/luminaire design standpoints. The UCSB team initially pursued the development of blue gallium nitride (GaN)-based vertical-cavity surface-emitting lasers, as well as ultraviolet GaN-based light emitting diodes (LEDs). In Year 2, the emphasis shifted to resonant-cavity light emitting diodes, also known as micro-cavity LEDs when extremely thin device cavities are fabricated. These devices have very directional emission and higher light extraction efficiency than conventional LEDs. Via the optimization of thin-film growth and refinement of device processing, we decreased the total cavity thickness to less than 1 {micro}m, such that micro-cavity effects were clearly observed and a light extraction efficiency of over 10% was reached. We also began the development of photonic crystals for increased light extraction, in particular for so-called ''guided modes'' which would otherwise propagate laterally in the device and be re-absorbed. Finally, we pursued the growth of smooth, high-quality nonpolar a-plane and m-plane GaN films, as well as blue light emitting diodes on these novel films. Initial nonpolar LEDs showed the expected behavior of negligible peak wavelength shift with increasing drive current. M-plane LEDs in particular show promise, as unpackaged devices had unsaturated optical output power of {approx} 3 mW at 200 mA drive current. The LRC's tasks were aimed at developing the subcomponents necessary for packaging UCSB's light

  4. Ultrafast laser direct hard-mask writing for high efficiency c-Si texture designs

    Science.gov (United States)

    Kumar, Kitty; Lee, Kenneth K. C.; Nogami, Jun; Herman, Peter R.; Kherani, Nazir P.

    2013-03-01

    This study reports a high-resolution hard-mask laser writing technique to facilitate the selective etching of crystalline silicon (c-Si) into an inverted-pyramidal texture with feature size and periodicity on the order of the wavelength which, thus, provides for both anti-reflection and effective light-trapping of infrared and visible light. The process also enables engineered positional placement of the inverted-pyramid thereby providing another parameter for optimal design of an optically efficient pattern. The proposed technique, a non-cleanroom process, is scalable for large area micro-fabrication of high-efficiency thin c-Si photovoltaics. Optical wave simulations suggest the fabricated textured surface with 1.3 μm inverted-pyramids and a single anti-reflective coating increases the relative energy conversion efficiency by 11% compared to the PERL-cell texture with 9 μm inverted pyramids on a 400 μm thick wafer. This efficiency gain is anticipated to improve further for thinner wafers due to enhanced diffractive light trapping effects.

  5. Composite nanofibers for highly efficient photocatalytic degradation of organic dyes from contaminated water.

    Science.gov (United States)

    Mohamed, Alaa; El-Sayed, Ramy; Osman, T A; Toprak, M S; Muhammed, M; Uheida, A

    2016-02-01

    In this study highly efficient photocatalyst based on composite nanofibers containing polyacrylonitrile (PAN), carbon nanotubes (CNT), and surface functionalized TiO2 nanoparticles was developed. The composite nanofibers were fabricated using electrospinning technique followed by chemical crosslinking. The surface modification and morphology changes of the fabricated composite nanofibers were examined through SEM, TEM, and FTIR analysis. The photocatalytic performance of the composite nanofibers for the degradation of model molecules, methylene blue and indigo carmine, under UV irradiation in aqueous solutions was investigated. The results demonstrated that high photodegradation efficiency was obtained in a short time and at low power intensity compared to other reported studies. The effective factors on the degradation of the dyes, such as the amount of catalyst, solution pH and irradiation time were investigated. The experimental kinetic data were fitted using pseudo-first order model. The effect of the composite nanofibers as individual components on the degradation efficiency of MB and IC was evaluated in order to understand the overall photodegradation mechanism. The results obtained showed that all the components possess significant effect on the photodegradation activity of the composite nanofibers. The stability studies demonstrated that the photodegradation efficiency can remain constant at the level of 99% after five consecutive cycles.

  6. Ultrafast laser direct hard-mask writing for high efficiency c-Si texture designs

    Directory of Open Access Journals (Sweden)

    Nogami Jun

    2013-03-01

    Full Text Available This study reports a high-resolution hard-mask laser writing technique to facilitate the selective etching of crystalline silicon (c-Si into an inverted-pyramidal texture with feature size and periodicity on the order of the wavelength which, thus, provides for both anti-reflection and effective light-trapping of infrared and visible light. The process also enables engineered positional placement of the inverted-pyramid thereby providing another parameter for optimal design of an optically efficient pattern. The proposed technique, a non-cleanroom process, is scalable for large area micro-fabrication of high-efficiency thin c-Si photovoltaics. Optical wave simulations suggest the fabricated textured surface with 1.3 μm inverted-pyramids and a single anti-reflective coating increases the relative energy conversion efficiency by 11% compared to the PERL-cell texture with 9 μm inverted pyramids on a 400 μm thick wafer. This efficiency gain is anticipated to improve further for thinner wafers due to enhanced diffractive light trapping effects.

  7. Compact and highly efficient laser pump cavity

    Energy Technology Data Exchange (ETDEWEB)

    Chang, Jim J. (Dublin, CA); Bass, Isaac L. (Castro Valley, CA); Zapata, Luis E. (Livermore, CA)

    1999-01-01

    A new, compact, side-pumped laser pump cavity design which uses non-conventional optics for injection of laser-diode light into a laser pump chamber includes a plurality of elongated light concentration channels. In one embodiment, the light concentration channels are compound parabolic concentrators (CPC) which have very small exit apertures so that light will not escape from the pumping chamber and will be multiply reflected through the laser rod. This new design effectively traps the pump radiation inside the pump chamber that encloses the laser rod. It enables more uniform laser pumping and highly effective recycle of pump radiation, leading to significantly improved laser performance. This new design also effectively widens the acceptable radiation wavelength of the diodes, resulting in a more reliable laser performance with lower cost.

  8. High-efficiency large-area CdTe panels

    Energy Technology Data Exchange (ETDEWEB)

    Albright, S.P.; Chamberlin, R.R.; Jordan, J.F. (Photon Energy, Inc., El Paso, TX (USA))

    1990-11-01

    The objective of this three year effort has been to develop an improved materials technology and fabrication process for limited volume production of 1 ft{sup 2} and 4 ft{sup 2} CdS/CdTe photovoltaic modules. The module stability objective by the end of this three year subcontract was to develop techniques to provide ten year life exploration with no greater than 10% degradation. In order to achieve these efficiency and stability objectives, the research program has been separated into tasks including: (1) analysis and characterization of CdS/CdTe Devices; (2) performance optimization on small cells; (3) encapsulation and stability testing; and (4) module efficiency optimization. 27 refs., 18 figs., 3 tabs.

  9. 2250-MHz High Efficiency Microwave Power Amplifier (HEMPA)

    Science.gov (United States)

    Sims, W. Herbert; Bell, Joseph L. (Technical Monitor)

    2001-01-01

    Tnis paper will focus on developing an exotic switching technique that enhances the DC-to-RF conversion efficiency of microwave power amplifiers. For years, switching techniques implemented in the 10 kHz to 30 MHz region have resulted in DC-to-RF conversion efficiencies of 90-95-percent. Currently amplifier conversion efficiency, in the 2-3 GHz region approaches, 10-20-percent. Using a combination of analytical modeling and hardware testing, a High Efficiency Microwave Power Amplifier was built that demonstrated conversion efficiencies four to five times higher than current state of the art.

  10. The waffle: a new photovoltaic diode geometry having high efficiency and backside contacts

    DEFF Research Database (Denmark)

    Leistiko, Otto

    1994-01-01

    By employing anisotropic etching techniques and advanced device processing it is possible to micromachine new types of mechanical, electronic, and optical devices of silicon, which have unique properties. In this paper the characteristics of a new type of photovoltaic diode fabricated employing...... these processing techniques are described. This novel device has not only high efficiency, but also has both contacts placed on the backside of the cell. The first devices which are only 50 mm in diameter are of relatively good quality with low leakage currents (nA), high breakdown voltages (80 V), and low series...

  11. Photovoltaic fabrics

    Science.gov (United States)

    2015-04-22

    during wire fabrication. Weaving was demonstrated for both military-type nylon -cotton blend (NYCO) warp fibers and cotton-polyester warp fibers. A...Lowell, MA 01852 14. ABSTRACT This report describes a project to improve photovoltaic fabrics. It had four objectives: 1) Efficiency – make PV wires on...a continuous basis that exhibit 7% efficiency; 2) Automated Welding – demonstrate an automated means of interconnecting the electrodes of one wire

  12. Energy efficient engine high-pressure turbine detailed design report

    Science.gov (United States)

    Thulin, R. D.; Howe, D. C.; Singer, I. D.

    1982-01-01

    The energy efficient engine high-pressure turbine is a single stage system based on technology advancements in the areas of aerodynamics, structures and materials to achieve high performance, low operating economics and durability commensurate with commercial service requirements. Low loss performance features combined with a low through-flow velocity approach results in a predicted efficiency of 88.8 for a flight propulsion system. Turbine airfoil durability goals are achieved through the use of advanced high-strength and high-temperature capability single crystal materials and effective cooling management. Overall, this design reflects a considerable extension in turbine technology that is applicable to future, energy efficient gas-turbine engines.

  13. Metamaterial-based high efficiency absorbers for high temperature solar applications (Conference Presentation)

    Science.gov (United States)

    Yellowhair, Julius E.; Kwon, Hoyeong; Alù, Andrea; Jarecki, Robert L.; Shinde, Subhash L.

    2016-09-01

    Operation of concentrated solar power receivers at higher temperatures (Existing coatings, however, tend to degrade rapidly at elevated temperatures. In this paper, we report on the initial designs, fabrication, and characterization of spectrally selective metamaterial-based absorbers for high-temperature, high-thermal flux environments important for solarized sCO2 power cycles. Metamaterials are structured media whose optical properties are determined by sub-wavelength structural features instead of bulk material properties, providing unique solutions by decoupling the optical absorption spectrum from thermal stability requirements. The key enabling innovative concept proposed is the use of structured surfaces with spectral responses that can be tailored to optimize the absorption and retention of solar energy for a given temperature range. In this initial study we use Tungsten for its stability in expected harsh environments, compatibility with microfabrication techniques, and required optical performance. Our goal is to tailor the optical properties for high (near unity) absorptivity across the majority of the solar spectrum and over a broad range of incidence angles, and at the same time achieve negligible absorptivity in the near infrared to optimize the energy absorbed and retained. To this goal, we apply the recently developed concept of plasmonic Brewster angle to suitably designed nanostructured Tungsten surfaces. We predict that this will improve the receiver thermal efficiencies by at least 10% over current solar receivers.

  14. Morphology Engineering: A Route to Highly Reproducible and High Efficiency Perovskite Solar Cells.

    Science.gov (United States)

    Bi, Dongqin; Luo, Jingshan; Zhang, Fei; Magrez, Arnaud; Athanasopoulou, Evangelia Nefeli; Hagfeldt, Anders; Grätzel, Michael

    2017-04-10

    Despite the rapid increase in the performance of perovskite solar cells (PSC), they still suffer from low lab-to-lab or people-to-people reproducibility. Aiming for a universal condition to high-performance devices, we investigated the morphology evolution of a composite perovskite by tuning annealing temperature and precursor concentration of the perovskite film. Here, we introduce thermal annealing as a powerful tool to generate a well-controlled excess of PbI2 in the perovskite formulation and show that this benefits the photovoltaic performance. We demonstrated the correlation between the film microstructure and electronic property and device performance. An optimized average grain size/thickness aspect ratio of the perovskite crystallite is identified, which brings about a highly reproducible power conversion efficiency (PCE) of 19.5 %, with a certified value of 19.08 %. Negligible hysteresis and outstanding morphology stability are observed with these devices. These findings lay the foundation for further boosting the PCE of PSC and can be very instructive for fabrication of high-quality perovskite films for a variety of applications, such as light-emitting diodes, field-effect transistors, and photodetectors. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

  15. Fabrication of High-Frequency pMUT Arrays on Silicon Substrates

    DEFF Research Database (Denmark)

    Pedersen, Thomas; Zawada, Tomasz; Hansen, Karsten

    2010-01-01

    A novel technique based on silicon micromachining for fabrication of linear arrays of high-frequency piezoelectric micromachined ultrasound transducers (pMUT) is presented. Piezoelectric elements are formed by deposition of lead zirconia titanate into etched features of a silicon substrate...

  16. Design, fabrication and characterization of a highly symmetrical capacitive triaxial accelerometer

    NARCIS (Netherlands)

    Lotters, Joost Conrad; Bomer, Johan G.; Verloop, A.J.; Droog, Adriaan; Olthuis, Wouter; Veltink, Petrus H.; Bergveld, Piet

    1998-01-01

    A highly symmetrical cubic capacitive triaxial accelerometer for biomedical applications has been designed, fabricated and characterized. The outer dimensions of the sensors are 5 mm × 5 mm × 5 mm. The devices are mounted on a standard IC package for easy testing. Features of the triaxial

  17. Materials aspects of integrated high-Tc dc-SQUID magnetometer fabrication

    NARCIS (Netherlands)

    Hilgenkamp, J.W.M.; IJsselsteijn, R.P.J.; Rijnders, A.J.H.M.; Tavares, P.A.C.; Flokstra, J.; Rogalla, H.

    1993-01-01

    An integrated high Tc dc-SQUID magnetometer is being developed. It has in total 10 layers of five different materials. Various materials aspects of the fabrication process will be discussed, especially the smoothness of the films and the techniques to obtain smooth edges. Cross-overs and superconduc

  18. The Chandra High Energy Transmission Grating: Design, Fabrication, Ground Calibration and Five Years in Flight

    CERN Document Server

    Canizares, C R; Dewey, D; Flanagan, K A; Galton, E B; Huenemoerder, D P; Ishibashi, K; Markert, T H; Marshall, H L; McGuirk, M; Schattenburg, M L; Schulz, N S; Smith, H I; Wise, M; Canizares, Claude R.; Davis, John E.; Dewey, Daniel; Flanagan, Kathryn A.; Galton, Eugene B.; Huenemoerder, David P.; Ishibashi, Kazunori; Markert, Thomas H.; Marshall, Herman L.; Guirk, Michael Mc; Schattenburg, Mark L.; Schulz, Norbert S.; Smith, Henry I.; Wise, Michael

    2005-01-01

    Details of the design, fabrication, ground and flight calibration of the High Energy Transmission Grating, HETG, on the Chandra X-ray Observatory are presented after five years of flight experience. Specifics include the theory of phased transmission gratings as applied to the HETG, the Rowland design of the spectrometer, details of the grating fabrication techniques, and the results of ground testing and calibration of the HETG. For nearly six years the HETG has operated essentially as designed, although it has presented some subtle flight calibration effects.

  19. New technique for fabrication of high frequency piezoelectric Micromachined Ultrasound Transducers

    DEFF Research Database (Denmark)

    Pedersen, T; Thomsen, Erik Vilain; Zawada, T

    2008-01-01

    A novel technique for fabrication of linear arrays of high frequency piezoelectric Micromachined Ultrasound Transducers (pMUT) on silicon substrates is presented. Piezoelectric elements are formed by deposition of PZT ((PbZrxTi1-x)O3) into etched features of the silicon substrate...... such that the depth of these features determine the element thickness and hence the resonance frequency. The process leaves a near planar surface which is ideal for further wafer level processing such as top electrode and interconnect formation. A fabricated single element is characterized by pulse echo response....

  20. High T(sub c) superconductors fabricated by plasma aerosol mist deposition technique

    Science.gov (United States)

    Wang, X. W.; Vuong, K. D.; Leone, A.; Shen, C. Q.; Williams, J.; Coy, M.

    1995-01-01

    We report new results on high T(sub c) superconductors fabricated by a plasma aerosol mist deposition technique, in atmospheric environment. Materials fabricated are YBaCuO, BiPbSrCaCuO, BaCaCuO precursor films for TlBaCaCuO, and other buffers such as YSZ. Depending on processing conditions, sizes of crystallites and/or particles are between dozens of nano-meters and several micrometers. Superconductive properties and other material characteristics can also be tailored.

  1. Improved Structure and Fabrication of Large, High-Power KHPS Rotors - Final Scientific/Technical Report

    Energy Technology Data Exchange (ETDEWEB)

    Corren, Dean [Verdant Power, Inc.; Colby, Jonathan [Verdant Power, Inc.; Adonizio, Mary Ann [Verdant Power, Inc.

    2013-01-29

    Verdant Power, Inc, working in partnership with the National Renewable Energy Laboratory (NREL), Sandia National Laboratories (SNL), and the University of Minnesota St. Anthony Falls Laboratory (SAFL), among other partners, used evolving Computational Fluid Dynamics (CFD) and Finite Element Analysis (FEA) models and techniques to improve the structure and fabrication of large, high-power composite Kinetic Hydropower System (KHPS) rotor blades. The objectives of the project were to: design; analyze; develop for manufacture and fabricate; and thoroughly test, in the lab and at full scale in the water, the improved KHPS rotor blade.

  2. Design and development of a high-concentration and high-efficiency photovoltaic concentrator using a curved Fresnel lens

    Energy Technology Data Exchange (ETDEWEB)

    Scharlack, R.S.; Moffat, A.

    1983-08-01

    Thermo Electron has designed a high concentration photovoltaic module that uses a domed, point-focus Fresnel lens. Their design, design optimization process, and results from lens and receiver tests are described in this report. A complete module has not been fabricated and probably will not be fabricated in the future; however, Thermo Electron's optical design, analysis, and testing of both secondary optical units and domed Fresnel lenses have made a significant contribution to our project. Tooling errors prevented the lens from reaching its potential efficiency by the end of the contract, and resolution of these tooling problems is currently being attempted with a follow-on contract, No. 68-9463.

  3. Reflecting and Polarizing Properties of Conductive Fabrics in Ultra-High Frequency Range

    Directory of Open Access Journals (Sweden)

    Oleg Kiprijanovič

    2015-09-01

    Full Text Available The system based on ultra-wide band (UWB signals was employed for qualitative estimation of attenuating, reflecting and polarizing properties of conductive fabrics, capable to prevent local static charge accumulation. Pulsed excitation of triangle monopole antenna of 6.5 cm height by rectangular electric pulses induced radiation of UWB signals with spectral density of power having maximum in ultra-high frequency (UHF range. The same antenna was used for the radiated signal receiving. Filters and amplifiers of different passband were employed to divide UHF range into subranges of 0.3-0.55 GHz, 0.55-1 GHz, 1-2 GHz and 2-4 GHz bands. The free space method, when conductive fabric samples of 50x50 cm2 were placed between transmitting and receiving antennas, was used to imitate a practical application. Received wideband signals corresponding to the defined range were detected by unbiased detectors. The fabrics made of two types of warps, containing different threads with conductive yarns, were investigated. It was estimated attenuation and reflective properties of the fabrics when electric field is collinear or perpendicular to thread direction. In the UHF range it was revealed good reflecting properties of the fabrics containing metallic component in the threads. The system has advantages but not without a certain shortcoming. Adapting it for specific tasks should lead to more effective usage, including yet unused properties of the UWB signals.

  4. Processing and Characterization of Peti Composites Fabricated by High Temperature Vartm (Section)

    Science.gov (United States)

    Ghose, Sayata; Cano, Roberto J.; Watson, Kent A.; Britton, Sean M.; Jensen, Brian J.; Connell, John W.; Smith, Joseph G., Jr.; Loos, Alfred C.; Heider, Dirk

    2011-01-01

    The use of composites as primary structures on aerospace vehicles has increased dramatically over the past decade, but so have the production costs associated with their fabrication. For certain composites, high temperature vacuum assisted resin transfer molding (HT-VARTM) can offer reduced fabrication costs compared to conventional autoclave techniques. The process has been successfully used with phenylethynyl terminated imide (PETI) resins developed by NASA Langley Research Center (LaRC). In the current study, three PETI resins have been used to make test specimens using HT-VARTM. Based on previous work at NASA LaRC, larger panels with a quasi-isotropic lay-up were fabricated. The resultant composite specimens exhibited void contents of 3% by volume depending on the type of carbon fabric preform used. Mechanical properties of the panels were determined at both room and elevated temperatures. Fabric permeability characterizations and limited process modeling efforts were carried out to determine infusion times and composite panel size limitations. In addition, new PETI based resins were synthesized specifically for HT-VARTM.

  5. Novel highly sensitive and wearable pressure sensors from conductive three-dimensional fabric structures

    Science.gov (United States)

    Li, Jianfeng; Xu, Bingang

    2015-12-01

    Pressure sensors based on three-dimensional fabrics have all the excellent properties of the textile substrate: excellent compressibility, good air permeability and moisture transmission ability, which will find applications ranging from the healthcare industry to daily usage. In this paper, novel pressure sensors based on 3D spacer fabrics have been developed by a proposed multi-coating method. By this coating method, carbon black can be coated uniformly on the silicon elastomer which is attached and slightly cured on the 3D fabric surface beforehand. The as-made pressure sensors have good conductivity and can measure external pressure up to 283 kPa with an electrical conductivity range of 9.8 kΩ. The sensitivity of 3D fabric pressure sensors can be as high as 50.31×10-3 kPa-1, which is better than other textile based pressure sensors. When the as-made sensors are pressed, their electrical resistance will decrease because of more conductive connections and bending of fibers in the spacer layer. The sensing mechanism related to fiber bending has been explored by using an equivalent resistance model. The newly developed 3D sensor devices can be designed to exhibit different sensing performances by simply changing the structures of fabric substrate, which endows this kind of device more flexibility in related applications.

  6. High efficiency in human muscle: an anomaly and an opportunity?

    Science.gov (United States)

    Nelson, Frank E; Ortega, Justus D; Jubrias, Sharon A; Conley, Kevin E; Kushmerick, Martin J

    2011-08-15

    Can human muscle be highly efficient in vivo? Animal muscles typically show contraction-coupling efficiencies FDI) muscle of the hand has an efficiency value in vivo of 68%. We examine two key factors that could account for this apparently high efficiency value: (1) transfer of cross-bridge work into mechanical work and (2) the use of elastic energy to do external work. Our analysis supports a high contractile efficiency reflective of nearly complete transfer of muscular to mechanical work with no contribution by recycling of elastic energy to mechanical work. Our survey of reported contraction-coupling efficiency values puts the FDI value higher than typical values found in small animals in vitro but within the range of values for human muscle in vivo. These high efficiency values support recent studies that suggest lower Ca(2+) cycling costs in working contractions and a decline in cost during repeated contractions. In the end, our analysis indicates that the FDI muscle may be exceptional in having an efficiency value on the higher end of that reported for human muscle. Thus, the FDI muscle may be an exception both in contraction-coupling efficiency and in Ca(2+) cycling costs, which makes it an ideal muscle model system offering prime conditions for studying the energetics of muscle contraction in vivo.

  7. DCM, FSM, dead time and width controllers for a high frequency high efficiency buck DC-DC converter over a wide load range

    Energy Technology Data Exchange (ETDEWEB)

    Pi Changming; Yan Wei; Zhang Ke; Li Wenhong, E-mail: wenhongli@fudan.edu.c [State Key Laboratory of ASIC and Systems, Fudan University, Shanghai 201203 (China)

    2010-08-15

    This paper presents a width controller, a dead time controller, a discontinuous current mode (DCM) controller and a frequency skipping modulation (FSM) controller for a high frequency high efficiency buck DC-DC converter. To improve the efficiency over a wide load range, especially at high switching frequency, the dead time controller and width controller are applied to enhance the high load efficiency, while the DCM controller and FSM controller are proposed to increase the light load efficiency. The proposed DC-DC converter controllers have been designed and fabricated in the Chartered 0.35 {mu}m CMOS process, and the measured results show that the efficiency of the buck DC-DC converter is above 80% over a wide load current range from 8 to 570 mA, and the peak efficiency is 86% at 10 MHz switching frequency. (semiconductor integrated circuits)

  8. SEMICONDUCTOR INTEGRATED CIRCUITS: DCM, FSM, dead time and width controllers for a high frequency high efficiency buck DC-DC converter over a wide load range

    Science.gov (United States)

    Changming, Pi; Wei, Yan; Ke, Zhang; Wenhong, Li

    2010-08-01

    This paper presents a width controller, a dead time controller, a discontinuous current mode (DCM) controller and a frequency skipping modulation (FSM) controller for a high frequency high efficiency buck DC-DC converter. To improve the efficiency over a wide load range, especially at high switching frequency, the dead time controller and width controller are applied to enhance the high load efficiency, while the DCM controller and FSM controller are proposed to increase the light load efficiency. The proposed DC-DC converter controllers have been designed and fabricated in the Chartered 0.35 μm CMOS process, and the measured results show that the efficiency of the buck DC-DC converter is above 80% over a wide load current range from 8 to 570 mA, and the peak efficiency is 86% at 10 MHz switching frequency.

  9. Chlorinated fluorine doped tin oxide electrodes with high work function for highly efficient planar perovskite solar cells

    Science.gov (United States)

    Deng, Li; Xie, Jiale; Wang, Baohua; Chen, Tao; Li, Chang Ming

    2017-06-01

    Perovskite solar cells (PSCs) demonstrate excellent high efficiencies over 20% and potential for a highly scalable manufacturing process. The work function of a transparent electrode (e.g., fluorine doped tin oxide, FTO) plays a critical role in the extraction and collection of electrons in PSCs. In this work, a chlorinated FTO (Cl-FTO) electrode with a high work function is used to fabricate a planar PSC at a low temperature of 100 °C with an optimal efficiency of 13.39% for a great improvement of 49% than plain FTO based cells. The change in the work function of FTO and Cl-FTO can reach up to 0.6 eV. The enhancement scientific insight is further explored, indicating that the increased work function of Cl-FTO provides well-matched energy levels between FTO and the CH3NH3PbI3 active material, facilitating the electron extraction and collection.

  10. High efficiency single Ag nanowire/p-GaN substrate Schottky junction-based ultraviolet light emitting diodes

    Energy Technology Data Exchange (ETDEWEB)

    Wu, Y.; Li, X.; Xu, P.; Wang, Y.; Shen, X.; Liu, X.; Yang, Q., E-mail: qingyang@zju.edu.cn [State Key Laboratory of Modern Optical Instrumentation, Department of Optical Engineering, Zhejiang University, Hangzhou 310027 (China); Hasan, T. [Cambridge Graphene Centre, University of Cambridge, Cambridge CB3 0FA (United Kingdom)

    2015-02-02

    We report a high efficiency single Ag nanowire (NW)/p-GaN substrate Schottky junction-based ultraviolet light emitting diode (UV-LED). The device demonstrates deep UV free exciton electroluminescence at 362.5 nm. The dominant emission, detectable at ultralow (<1 μA) forward current, does not exhibit any shifts when the forward current is increased. External quantum efficiency (EQE) as high as 0.9% is achieved at 25 μA current at room temperature. Experiments and simulation analysis show that devices fabricated with thinner Ag NWs have higher EQE. However, for very thin Ag NWs (diameter < 250 nm), this trend breaks down due to heat accumulation in the NWs. Our simple device architecture offers a potentially cost-effective scheme to fabricate high efficiency Schottky junction-based UV-LEDs.

  11. Fabrication of cermet bearings for the control system of a high temperature lithium cooled nuclear reactor

    Science.gov (United States)

    Yacobucci, H. G.; Heestand, R. L.; Kizer, D. E.

    1973-01-01

    The techniques used to fabricate cermet bearings for the fueled control drums of a liquid metal cooled reference-design reactor concept are presented. The bearings were designed for operation in lithium for as long as 5 years at temperatures to 1205 C. Two sets of bearings were fabricated from a hafnium carbide - 8-wt. % molybdenum - 2-wt. % niobium carbide cermet, and two sets were fabricated from a hafnium nitride - 10-wt. % tungsten cermet. Procedures were developed for synthesizing the material in high purity inert-atmosphere glove boxes to minimize oxygen content in order to enhance corrosion resistance. Techniques were developed for pressing cylindrical billets to conserve materials and to reduce machining requirements. Finishing was accomplished by a combination of diamond grinding, electrodischarge machining, and diamond lapping. Samples were characterized in respect to composition, impurity level, lattice parameter, microstructure and density.

  12. Fabrication of High Aspect Ratio Micro-Penning-Malmberg Gold Plated Silicon Trap Arrays

    CERN Document Server

    Narimannezhad, Alireza; Weber, Marc H; Lynn, Kelvin G

    2013-01-01

    Acquiring a portable high density charged particles trap might consist of an array of micro-Penning-Malmberg traps (microtraps) with substantially lower end barriers potential than conventional Penning-Malmberg traps [1]. We report on the progress of the fabrication of these microtraps designed for antimatter storage such as positrons. The fabrication of large length to radius aspect ratio (1000:1) microtrap arrays involved advanced techniques including photolithography, deep reactive ion etching (DRIE) of silicon wafers to achieve through-vias, gold sputtering of the wafers on the surfaces and inside the vias, and thermal compression bonding of the wafers. This paper describes the encountered issues during fabrication and addresses geometry errors and asymmetries. In order to minimize the patch effects on the lifetime of the trapped positrons, the bonded stacks were gold electroplated to achieve a uniform gold surface. We show by simulation and analytical calculation that how positrons confinement time depen...

  13. Fabrication of high-density collagen fibril matrix gels by renaturation of triple-helix collagen from gelatin.

    Science.gov (United States)

    Ohyabu, Yoshimi; Yunoki, Shunji; Hatayama, Hirosuke; Teranishi, Yoshikazu

    2013-11-01

    Collagen-based 3-D hydrogels often lack sufficient mechanical strength for tissue engineering. We developed a method for fabrication of high-density collagen fibril matrix (CFM) gels from concentrated solutions of uncleaved gelatin (UCG). Denatured random-coil UCG exhibited more rapid and efficient renaturation into collagen triple-helix than cleaved gelatin (CG) over a broad range of setting temperatures. The UCG solution formed opaque gels with high-density reconstituted collagen fibrils at 28-32 °C and transparent gels similar to CG at 5%) and elasticity (1.28 ± 0.15 kPa at 5% and 4.82 ± 0.38 kPa at 8%) with minimal cell loss. The elastic modulus of these gels was higher than that of conventional CFM containing 0.5% collagen. High-strength CFM may provide more durable hydrogels for tissue engineering and regenerative medicine.

  14. Design, Fabrication, and Efficiency Study of a Novel Solar Thermal Water Heating System: Towards Sustainable Development

    Directory of Open Access Journals (Sweden)

    M. Z. H. Khan

    2016-01-01

    Full Text Available This paper investigated a novel loop-heat-pipe based solar thermal heat-pump system for small scale hot water production for household purposes. The effective use of solar energy is hindered by the intermittent nature of its availability, limiting its use and effectiveness in domestic and industrial applications especially in water heating. The easiest and the most used method is the conversion of solar energy into thermal energy. We developed a prototype solar water heating system for experimental test. We reported the investigation of solar thermal conversion efficiency in different seasons which is 29.24% in summer, 14.75% in winter, and 15.53% in rainy season. This paper also discusses the DC heater for backup system and the current by using thermoelectric generator which are 3.20 V in summer, 2.120 V in winter, and 1.843 V in rainy season. This solar water heating system is mostly suited for its ease of operation and simple maintenance. It is expected that such novel solar thermal technology would further contribute to the development of the renewable energy (solar driven heating/hot water service and therefore lead to significant environmental benefits.

  15. Efficient spin-coating-free planar heterojunction perovskite solar cells fabricated with successive brush-painting

    Science.gov (United States)

    Lee, Jin-Won; Na, Seok-In; Kim, Seok-Soon

    2017-01-01

    To demonstrate fully brush-painted planar heterojunction perovskite solar cells (PeSCs), poly (3,4-ethylendioxythiophene): poly(styrenesulfonate) (PEDOT:PSS) hole transport layer (HTL), CH3NH3PbI3 perovskite photoactive layer, and [6,6]-phenyl C61-butyric acid methyl ester (PCBM) electron acceptor layer are successively brush-painted. In particular, correlation between morphology of perovskites and overall performance of PeSCs are investigated depending on the perovskites precursor. Devices with brush-painted perovskite using generally used N,N-dimethylformamide (DMF) solvent show poor performance and large deviation in cell-performance. However, PeSCs with brush-painted perovskite employing protic 2-Methoxyethanol (2-M) as DMF-alternative solvent exhibit comparable power conversion efficiency (PCE) of 9.08% to conventional spin-coated device and excellent reproducibility in device performance is observed as well. Furthermore, a fully brush-painted PeSC based on flexible substrates, showing PCE of 7.75%, is successfully demonstrated.

  16. Perovskite Solar Cells: High Efficiency Pb-In Binary Metal Perovskite Solar Cells (Adv. Mater. 31/2016).

    Science.gov (United States)

    Wang, Zhao-Kui; Li, Meng; Yang, Ying-Guo; Hu, Yun; Ma, Heng; Gao, Xing-Yu; Liao, Liang-Sheng

    2016-08-01

    On page 6695, X. Y. Gao, L.-S. Liao, and co-workers describe the fabrication of mixed Pb-In perovskite solar cells, using indium (III) chloride and lead (II) chloride with methylammonium iodide. A maximum power conversion efficiency as high as 17.55% is achieved owing to the high quality of the perovskites with multiple ordered crystal orientations. This work demonstrates the possibility of substituting the Pb (II) by using In (III), which opens a broad route to fabricating alloy perovskite solar cells with mitigated ecological impact. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  17. Design and fabrication of a passive droplet dispenser for portable high resolution imaging system

    Science.gov (United States)

    Kamal, Tahseen; Watkins, Rachel; Cen, Zijian; Rubinstein, Jaden; Kong, Gary; Lee, Woei Ming

    2017-01-01

    Moldless lens manufacturing techniques using standard droplet dispensing technology often require precise control over pressure to initiate fluid flow and control droplet formation. We have determined a series of interfacial fluid parameters optimised using standard 3D printed tools to extract, dispense and capture a single silicone droplet that is then cured to obtain high quality lenses. The dispensing process relies on the recapitulation of liquid dripping action (Rayleigh-Plateau instability) and the capturing method uses the interplay of gravitational force, capillary forces and liquid pinning to control the droplet shape. The key advantage of the passive lens fabrication approach is rapid scale-up using 3D printing by avoiding complex dispensing tools. We characterise the quality of the lenses fabricated using the passive approach by measuring wavefront aberration and high resolution imaging. The fabricated lenses are then integrated into a portable imaging system; a wearable thimble imaging device with a detachable camera housing, that is constructed for field imaging. This paper provides the full exposition of steps, from lens fabrication to imaging platform, necessary to construct a standalone high resolution imaging system. The simplicity of our methodology can be implemented using a regular desktop 3D printer and commercially available digital imaging systems.

  18. Fabrication of Aspheric Micro-Lens Mold with High Aspect Ratio

    Science.gov (United States)

    Naniwa, Irizo; Kanamaru, Masatoshi; Nakamura, Shigeo; Shimano, Takeshi; Horino, Masaya

    The optical pickup of our Small-Form-Factor Optical Disc Drives (SFFODDs) requires a micro-objective whose profile is composed of two aspheric surfaces. However, it is difficult to fabricate a micro-objective with an arbitrary aspheric surface and high aspect ratio using conventional techniques. We propose here a new method to fabricate an aspheric micro-lens mold with high aspect ratio. This method uses the micro-loading effect in Deep Reactive Ion Etching (DRIE) and isotropic Reactive Ion Etching (RIE). The micro-loading effect is a phenomenon that leads to different etching depths depending on the aperture size of the mask layer used in etching. We fabricated an aspheric micro-lens mold for the prototype by using the proposed method after experimental evaluations of the micro-loading effect for a feasibility study. The profile of the first prototype was slightly different from the designed one according as the distance from the lens center increase. The profile error of the second prototype was reduced by using a mask that had multiple apertures with the smallest aperture located outside the area where the crater was formed. Our proposed method was found to be effective for fabricating a micro-lens mold with an arbitrary aspheric surface and high aspect ratio.

  19. Design and fabrication of a passive droplet dispenser for portable high resolution imaging system

    Science.gov (United States)

    Kamal, Tahseen; Watkins, Rachel; Cen, Zijian; Rubinstein, Jaden; Kong, Gary; Lee, Woei Ming

    2017-01-01

    Moldless lens manufacturing techniques using standard droplet dispensing technology often require precise control over pressure to initiate fluid flow and control droplet formation. We have determined a series of interfacial fluid parameters optimised using standard 3D printed tools to extract, dispense and capture a single silicone droplet that is then cured to obtain high quality lenses. The dispensing process relies on the recapitulation of liquid dripping action (Rayleigh-Plateau instability) and the capturing method uses the interplay of gravitational force, capillary forces and liquid pinning to control the droplet shape. The key advantage of the passive lens fabrication approach is rapid scale-up using 3D printing by avoiding complex dispensing tools. We characterise the quality of the lenses fabricated using the passive approach by measuring wavefront aberration and high resolution imaging. The fabricated lenses are then integrated into a portable imaging system; a wearable thimble imaging device with a detachable camera housing, that is constructed for field imaging. This paper provides the full exposition of steps, from lens fabrication to imaging platform, necessary to construct a standalone high resolution imaging system. The simplicity of our methodology can be implemented using a regular desktop 3D printer and commercially available digital imaging systems. PMID:28128365

  20. High brilliance and high efficiency: optimized high power diode laser bars

    Science.gov (United States)

    Hülsewede, R.; Schulze, H.; Sebastian, J.; Schröder, D.; Meusel, J.; Hennig, P.

    2008-02-01

    The strong increasing laser market has ongoing demands to reduce the costs of diode laser pumped systems. For that reason JENOPTIK Diode Lab GmbH (JDL) optimized the bar brilliance (small vertical far field divergence) and bar efficiency (higher optical power operation) with respect to the pump applications. High efficiency reduces the costs for mounting and cooling and high brilliance increases the coupling efficiency. Both are carefully adjusted in the 9xx nm - high power diode laser bars for pump applications in disc- and fiber lasers. Based on low loss waveguide structures high brilliance bars with 19° fast axis beam divergence (FWHM) with 58 % maximum efficiency and 27° fast axis beam divergence (FWHM) with 62 % maximum efficiency are developed. Mounted on conductive cooled heat sinks high power operation with lifetime > 20.000 hours at 120 W output power level (50 % filling factor bars) and 80W (20 % filling factor bars) is demonstrated. 808nm bars used as pump sources for Nd:YAG solid state lasers are still dominating in the market. With respect to the demands on high reliability at high power operation current results of a 100 W high power life time test are showing more than 9000 hour operation time for passively cooled packaged high efficiency 50 % filling factor bars. Measurement of the COMD-level after this hard pulse life time test demonstrates very high power levels with no significant droop in COMD-power level. This confirms the high facet stability of JDL's facet technology. New high power diode laser bars with wavelength of 825 nm and 885 nm are still under development and first results are presented.

  1. A High Efficiency Multiple-Anode 260-340 GHz Frequency Tripler

    Science.gov (United States)

    Maestrini, Alain; Tripon-Canseliet, Charlotte; Ward, John S.; Gill, John J.; Mehdi, Imran

    2006-01-01

    We report on the fabrication at the Jet Propulsion Laboratory of a fixed-tuned split-block waveguide balanced frequency tripler working in the 260-340 GHz band. This tripler will be the first stage of a x3x3x3 multiplier chain to 2.7 THz (the last stages of which are being fabricated at JPL) and is therefore optimized for high power operation. The multiplier features six GaAs Schottky planar diodes in a balanced configuration integrated on a GaAs membrane. Special attention was put on splitting the input power as evenly as possible among the diodes in order to ensure that no diode is overdriven. Preliminary RF tests indicate that the multiplier covers the expected bandwidth and that the efficiency is in the range 1.5-7.5 % with 100 mW of input power.

  2. Highly Efficient Photothermal Semiconductor Nanocomposites for Photothermal Imaging of Latent Fingerprints.

    Science.gov (United States)

    Cui, Jiabin; Xu, Suying; Guo, Chang; Jiang, Rui; James, Tony D; Wang, Leyu

    2015-11-17

    Optical imaging of latent fingerprints (LFPs) has been widely used in forensic science and for antiterrorist applications, but it suffers from interference from autofluorescence and the substrates background color. Cu7S4 nanoparticles (NPs), with excellent photothermal properties, were synthesized using a new strategy and then fabricated into amphiphilic nanocomposites (NCs) via polymerization of allyl mercaptan coated on Cu7S4 NPs to offer good affinities toward LFPs. Here, we develop a facile and versatile photothermal LFP imaging method based on the high photothermal conversion efficiency (52.92%, 808 nm) of Cu7S4 NCs, indicating its effectiveness for imaging LFPs left on different substrates (with various background colors), which will be extremely useful for crime scene investigations. Furthermore, by fabricating Cu7S4-CdSe@ZnS NCs, a fluorescent-photothermal dual-mode imaging strategy was used to detect trinitrotoluene (TNT) in LFPs while still maintaining a complete photothermal image of LFP.

  3. Fabrication of Ni-Mn Microprobe Structure with Low Internal Stress and High Hardness by Employing DC Electrodeposition

    Directory of Open Access Journals (Sweden)

    Kuan-Hui Cheng

    2014-01-01

    Full Text Available Due to its widely tunable mechanical property and incompatibility with most solders, Ni-Mn alloy can become a viable candidate in the fabrication of testing probe for microelectronic devices. In this study, the electrodeposition of Ni-Mn alloy in nickel sulphamate electrolyte with the addition of manganese sulphate was investigated under direct current (DC power source. The effects of current density and Mn2+ concentration in the electrolyte on the coating composition, cathodic efficiency, microstructure and mechanical properties were explored. The results showed that the raise of the Mn2+ concentration in the electrolyte alone did not effectively increase the Mn content in the coating but reduce the cathodic efficiency. On the other hand, increasing the current density facilitated the codeposition of the Mn and rendered the crystallite from coarse columnar grain to the refined one. Thus, both hardness and internal stress of the coating increased. The fabrication of testing probes at 1 A/dm2 was shown to satisfy the high hardness, low internal stress, reasonable fatigue life, and nonsticking requirements for this microelectronic application.

  4. SiMPl - High efficient silicon photomultipliers with integrated bulk resistor

    Energy Technology Data Exchange (ETDEWEB)

    Jendrysik, Christian; Andricek, Ladislav; Liemann, Gerhard; Moser, Hans-Guenther; Ninkovic, Jelena; Richter, Rainer [Max-Planck-Institute for Physics, Semiconductor Laboratory, Munich (Germany); Lutz, Gerhard [PN Sensor GmbH, Munich (Germany)

    2010-07-01

    Silicon photomultipliers (SiPM) are avalanche photodetectors which tend to replace conventional photomultiplier tubes in many application areas where detectors with high photon detection efficiency (PDE) are in the focus of interest. For Geiger mode operation high ohmic polysilicon is needed as quench resistor. On the one hand this forms a barrier for incident light, thus decreasing the PDE, which is a crucial point at low light levels. On the other hand it's also the most cost driving technological issue in fabrication. We present a novel design for a high efficient SiPM with the quench resistors integrated into the silicon bulk. Therefore obstacles for light like metal lines or contacts within the active area can be omitted and the fill factor of the device is only limited by the gaps necessary for optical crosstalk suppression. First results of this novel light detector are presented.

  5. Bioinspired photonic structures by the reflector layer of firefly lantern for highly efficient chemiluminescence

    Science.gov (United States)

    Chen, Linfeng; Shi, Xiaodi; Li, Mingzhu; Hu, Junping; Sun, Shufeng; Su, Bin; Wen, Yongqiang; Han, Dong; Jiang, Lei; Song, Yanlin

    2015-08-01

    Fireflies have drawn considerable attention for thousands of years due to their highly efficient bioluminescence, which is important for fundamental research and photonic applications. However, there are few reports on the reflector layer (RL) of firefly lantern, which contributes to the bright luminescence. Here we presented the detailed microstructure of the RL consisting of random hollow granules, which had high reflectance in the range from 450 nm to 800 nm. Inspired by the firefly lantern, artificial films with high reflectance in the visible region were fabricated using hollow silica microparticles mimicking the structure of the RL. Additionally, the bioinspired structures provided an efficient RL for the chemiluminescence system and could substantially enhance the initial chemiluminescence intensity. The work not only provides new insight into the bright bioluminescence of fireflies, but also is importance for the design of photonic materials for theranostics, detection, and imaging.

  6. Highly-Efficient and Modular Medium-Voltage Converters

    Science.gov (United States)

    2015-09-28

    4. TITLE AND SUBTITLE Highly-Efficient and Modula Medium -Voltage Converters 6. AUTHOR(S) Maryam Saeedifard 7. PERFORMING ORGANIZATIC i NAME(S...realization of highly efficient, modular medium - voltage dc-ac and dc-dc energy conversion systems by development of new control strategies that improve the...Z39.18 a 01^ 100(0^5 Final Report for Grant N00014-14-1-0615 Highly-Efficient and Modular Medium -Voltage Converters Lead Organization: Georgia Tech

  7. EVALUATION OF A LOW FRICTION - HIGH EFFICIENCY ROLLER BEARING ENGINE

    Energy Technology Data Exchange (ETDEWEB)

    Kolarik, Robert V. II; Shattuck, Charles W.; Copper, Anthony P.

    2009-06-30

    This Low Friction (High Efficiency Roller Bearing) Engine (LFE) report presents the work done by The Timken Company to conduct a technology demonstration of the benefits of replacing hydrodynamic bearings with roller bearings in the crankshaft and camshaft assemblies of an internal combustion engine for the purpose of collecting data sufficient to prove merit. The engines in the present study have been more extensively converted to roller bearings than any previous studies (40 needle roller bearings per engine) to gain understanding of the full potential of application of bearing technology. The project plan called for comparative testing of a production vehicle which was already respected for having demonstrated low engine friction levels with a rollerized version of that engine. Testing was to include industry standard tests for friction, emissions and fuel efficiency conducted on instrumented dynamometers. Additional tests for fuel efficiency, cold start resistance and other measures of performance were to be made in the actual vehicle. Comparative measurements of noise, vibration and harshness (NVH), were planned, although any work to mitigate the suspected higher NVH level in the rollerized engine was beyond the scope of this project. Timken selected the Toyota Avalon with a 3.5L V-6 engine as the test vehicle. In an attempt to minimize cost and fabrication time, a ‘made-from’ approach was proposed in which as many parts as possible would be used or modified from production parts to create the rollerized engine. Timken commissioned its test partner, FEV Engine Technology, to do a feasibility study in which they confirmed that using such an approach was possible to meet the required dimensional restrictions and tolerances. In designing the roller bearing systems for the crank and cam trains, Timken utilized as many production engine parts as possible. The crankshafts were produced from production line forgings, which use Timken steel, modified with special

  8. Energy-Efficient Hydrogenated Zinc Oxide Nanoflakes for High-Performance Self-Powered Ultraviolet Photodetector.

    Science.gov (United States)

    Deka Boruah, Buddha; Misra, Abha

    2016-07-20

    Light absorption efficiency and doping induced charge carrier density play a vital role in self-powered optoelectronic devices. Unique vanadium-doped zinc oxide nanoflake array (VZnO NFs) is fabricated for self-powered ultraviolet (UV) photodetection. The light harvesting efficiency drastically improved from 84% in ZnO NRs to 98% in VZnO NFs. Moreover, the hydrogenation of as-synthesized VZnO (H:VZnO) NFs displayed an outstanding increase in response current as compared to pristine structures. The H:VZnO NFs device presents an extraordinary photoelastic behavior with faster photodetection speed in the order of ms under a low UV illumination signal. Excellent responsivity and external quantum efficiency with larger value of specific detectivity of H:VZnO NFs device promises an outstanding sensitivity for UV signal and self-powered high-performance visible-blind photodetector.

  9. High-efficiency electrochemical thermal energy harvester using carbon nanotube aerogel sheet electrodes

    Science.gov (United States)

    Im, Hyeongwook; Kim, Taewoo; Song, Hyelynn; Choi, Jongho; Park, Jae Sung; Ovalle-Robles, Raquel; Yang, Hee Doo; Kihm, Kenneth D.; Baughman, Ray H.; Lee, Hong H.; Kang, Tae June; Kim, Yong Hyup

    2016-02-01

    Conversion of low-grade waste heat into electricity is an important energy harvesting strategy. However, abundant heat from these low-grade thermal streams cannot be harvested readily because of the absence of efficient, inexpensive devices that can convert the waste heat into electricity. Here we fabricate carbon nanotube aerogel-based thermo-electrochemical cells, which are potentially low-cost and relatively high-efficiency materials for this application. When normalized to the cell cross-sectional area, a maximum power output of 6.6 W m-2 is obtained for a 51 °C inter-electrode temperature difference, with a Carnot-relative efficiency of 3.95%. The importance of electrode purity, engineered porosity and catalytic surfaces in enhancing the thermocell performance is demonstrated.

  10. Research on high-efficiency, single-junction, monolithic, thin-film amorphous silicon solar cells

    Science.gov (United States)

    Wiesmann, H.; Dolan, J.; Fricano, G.; Danginis, V.

    1987-02-01

    A study was undertaken of the optoelectronic properties of amorphous silicon-hydrogen thin films deposited from disilane at high deposition rates. The information derived from this study was used to fabricate amorphous silicon solar cells with efficiencies exceeding 7%. The intrinsic layer of these solar cells was deposited at 15 angstroms/second. Material properties investigated included dark conductivity, photoconductivity, minority carrier diffusion length, and density of states. The solar cells properties characterized were absolute quantum yield and simulated global AM 1.5 efficiencies. Investigations were undertaken utilizing optical and infrared spectroscopy to optimize the microstructures of the intrinsic amorphous silicon. That work was sponsored by the New York State Energy Research and Development Authority. The information was used to optimize the intrinsic layer of amorphous silicon solar cells, resulting in AM 1.5 efficiencies exceeding 7%.

  11. Design of high efficiency dual-mode buck DC-DC converter

    Science.gov (United States)

    Xinquan, Lai; Huali, Zeng; Qiang, Ye; Huisen, He; Shasha, Zhang; Yuqing, Sun

    2010-11-01

    A buck DC—DC switching regulator with high efficiency is implemented by automatically altering the modulation mode according to load current, and it can operate with an input range of 4.5 to 30 V. At light load current, the converter operates in skip mode. The converter enters PWM mode operation with increasing load current. It reduces the switching loss at light load and standby state, which results in prolonging battery lifetime and stand-by time. Meanwhile, externally adjustable soft-start minimizes the inrush supply current and avoids the overshoot of output voltage at initial startup. The regulator is fabricated by a 0.6 μm CDMOS process. The test results show that, under the condition of 3.3 V output, the efficiency is up to 64% at 5 mA and the maximum efficiency is 95.5%.

  12. Design of high efficiency dual-mode buck DC-DC converter

    Energy Technology Data Exchange (ETDEWEB)

    Lai Xinquan; Zeng Huali; Ye Qiang; He Huisen; Zhang Shasha; Sun Yuqing, E-mail: zenghuali4213@126.com, E-mail: xqlai@mail.xidian.edu.cn [Institute of Electronic CAD, Xidian University, Xi' an 710071 (China)

    2010-11-15

    A buck DC-DC switching regulator with high efficiency is implemented by automatically altering the modulation mode according to load current, and it can operate with an input range of 4.5 to 30 V. At light load current, the converter operates in skip mode. The converter enters PWM mode operation with increasing load current. It reduces the switching loss at light load and standby state, which results in prolonging battery lifetime and stand-by time. Meanwhile, externally adjustable soft-start minimizes the inrush supply current and avoids the overshoot of output voltage at initial startup. The regulator is fabricated by a 0.6 {mu}m CDMOS process. The test results show that, under the condition of 3.3 V output, the efficiency is up to 64% at 5 mA and the maximum efficiency is 95.5%.

  13. High-efficiency electrochemical thermal energy harvester using carbon nanotube aerogel sheet electrodes.

    Science.gov (United States)

    Im, Hyeongwook; Kim, Taewoo; Song, Hyelynn; Choi, Jongho; Park, Jae Sung; Ovalle-Robles, Raquel; Yang, Hee Doo; Kihm, Kenneth D; Baughman, Ray H; Lee, Hong H; Kang, Tae June; Kim, Yong Hyup

    2016-02-03

    Conversion of low-grade waste heat into electricity is an important energy harvesting strategy. However, abundant heat from these low-grade thermal streams cannot be harvested readily because of the absence of efficient, inexpensive devices that can convert the waste heat into electricity. Here we fabricate carbon nanotube aerogel-based thermo-electrochemical cells, which are potentially low-cost and relatively high-efficiency materials for this application. When normalized to the cell cross-sectional area, a maximum power output of 6.6 W m(-2) is obtained for a 51 °C inter-electrode temperature difference, with a Carnot-relative efficiency of 3.95%. The importance of electrode purity, engineered porosity and catalytic surfaces in enhancing the thermocell performance is demonstrated.

  14. Personalized implant for high tibial opening wedge: combination of solid freeform fabrication with combustion synthesis process.

    Science.gov (United States)

    Zhim, Fouad; Ayers, Reed A; Moore, John J; Moufarrège, Richard; Yahia, L'Hocine

    2012-09-01

    In this work a new generation of bioceramic personalized implants were developed. This technique combines the processes of solid freeform fabrication (SFF) and combustion synthesis (CS) to create personalized bioceramic implants with tricalcium phosphate (TCP) and hydroxyapatite (HA). These porous bioceramics will be used to fill the tibial bone gap created by the opening wedge high tibial osteotomy (OWHTO). A freeform fabrication with three-dimensional printing (3DP) technique was used to fabricate a metallic mold with the same shape required to fill the gap in the opening wedge osteotomy. The mold was subsequently used in a CS process to fabricate the personalized ceramic implants with TCP and HA compositions. The mold geometry was designed on commercial 3D CAD software. The final personalized bioceramic implant was produced using a CS process. This technique was chosen because it exploits the exothermic reaction between P₂O₅ and CaO. Also, chemical composition and distribution of pores in the implant could be controlled. To determine the chemical composition, the microstructure, and the mechanical properties of the implant, cylindrical shapes were also fabricated using different fabrication parameters. Chemical composition was performed by X-ray diffraction. Pore size and pore interconnectivity was measured and analyzed using an electronic microscope system. Mechanical properties were determined by a mechanical testing system. The porous TCP and HA obtained have an open porous structure with an average 400 µm channel size. The mechanical behavior shows great stiffness and higher load to failure for both ceramics. Finally, this personalized ceramic implant facilitated the regeneration of new bone in the gap created by OWHTO and provides additional strength to allow accelerated rehabilitation.

  15. Fabrication of thermal-resistant gratings for high-temperature measurements using geometric phase analysis

    Science.gov (United States)

    Zhang, Q.; Liu, Z.; Xie, H.; Ma, K.; Wu, L.

    2016-12-01

    Grating fabrication techniques are crucial to the success of grating-based deformation measurement methods because the quality of the grating will directly affect the measurement results. Deformation measurements at high temperatures entail heating and, perhaps, oxidize the grating. The contrast of the grating lines may change during the heating process. Thus, the thermal-resistant capability of the grating becomes a point of great concern before taking measurements. This study proposes a method that combines a laser-engraving technique with the processes of particle spraying and sintering for fabricating thermal-resistant gratings. The grating fabrication technique is introduced and discussed in detail. A numerical simulation with a geometric phase analysis (GPA) is performed for a homogeneous deformation case. Then, the selection scheme of the grating pitch is suggested. The validity of the proposed technique is verified by fabricating a thermal-resistant grating on a ZrO2 specimen and measuring its thermal strain at high temperatures (up to 1300 °C). Images of the grating before and after deformation are used to obtain the thermal-strain field by GPA and to compare the results with well-established reference data. The experimental results indicate that this proposed technique is feasible and will offer good prospects for further applications.

  16. Thermoplastic elastomers for microfluidics: towards a high-throughput fabrication method of multilayered microfluidic devices.

    Science.gov (United States)

    Roy, Emmanuel; Galas, Jean-Christophe; Veres, Teodor

    2011-09-21

    Multilayer soft lithography of polydimethylsiloxane (PDMS) is a well-known method for the fabrication of complex fluidic functions. With advantages and drawbacks, this technique allows fabrication of valves, pumps and micro-mixers. However, the process is inadequate for industrial applications. Here, we report a rapid prototyping technique for the fabrication of multilayer microfluidic devices, using a different and promising class of polymers. Using styrenic thermoplastic elastomers (TPE), we demonstrate a rapid technique for the fabrication and assembly of pneumatically driven valves in a multilayer microfluidic device made completely from thermoplastics. This material solution is transparent, biocompatible and as flexible as PDMS, and has high throughput thermoforming processing characteristics. We established a proof of principle for valving and mixing with three different grades of TPE using an SU-8 master mold. Specific viscoelastic properties of each grade allow us to report enhanced bonding capabilities from room temperature bonding to free pressure thermally assisted bonding. In terms of microfabrication, beyond classically embossing means, we demonstrate a high-throughput thermoforming method, where TPE molding experiments have been carried out without applied pressure and vacuum assistance within an overall cycle time of 180 s. The quality of the obtained thermoplastic systems show robust behavior and an opening/closing frequency of 5 Hz.

  17. Fabrication of thermal-resistant gratings for high-temperature measurements using geometric phase analysis.

    Science.gov (United States)

    Zhang, Q; Liu, Z; Xie, H; Ma, K; Wu, L

    2016-12-01

    Grating fabrication techniques are crucial to the success of grating-based deformation measurement methods because the quality of the grating will directly affect the measurement results. Deformation measurements at high temperatures entail heating and, perhaps, oxidize the grating. The contrast of the grating lines may change during the heating process. Thus, the thermal-resistant capability of the grating becomes a point of great concern before taking measurements. This study proposes a method that combines a laser-engraving technique with the processes of particle spraying and sintering for fabricating thermal-resistant gratings. The grating fabrication technique is introduced and discussed in detail. A numerical simulation with a geometric phase analysis (GPA) is performed for a homogeneous deformation case. Then, the selection scheme of the grating pitch is suggested. The validity of the proposed technique is verified by fabricating a thermal-resistant grating on a ZrO2 specimen and measuring its thermal strain at high temperatures (up to 1300 °C). Images of the grating before and after deformation are used to obtain the thermal-strain field by GPA and to compare the results with well-established reference data. The experimental results indicate that this proposed technique is feasible and will offer good prospects for further applications.

  18. Flexible semi-transparent silicon (100) fabric with high-k/metal gate devices

    KAUST Repository

    Rojas, Jhonathan Prieto

    2013-01-07

    Can we build a flexible and transparent truly high performance computer? High-k/metal gate stack based metal-oxide-semiconductor capacitor devices are monolithically fabricated on industry\\'s most widely used low-cost bulk single-crystalline silicon (100) wafers and then released as continuous, mechanically flexible, optically semi-transparent and high thermal budget compatible silicon fabric with devices. This is the first ever demonstration with this set of materials which allows full degree of freedom to fabricate nanoelectronics devices using state-of-the-art CMOS compatible processes and then to utilize them in an unprecedented way for wide deployment over nearly any kind of shape and architecture surfaces. Electrical characterization shows uncompromising performance of post release devices. Mechanical characterization shows extra-ordinary flexibility (minimum bending radius of 1 cm) making this generic process attractive to extend the horizon of flexible electronics for truly high performance computers. Schematic and photograph of flexible high-k/metal gate MOSCAPs showing high flexibility and C-V plot showing uncompromised performance. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  19. High slope efficiency and high refractive index change in direct-written Yb-doped waveguide lasers with depressed claddings.

    Science.gov (United States)

    Palmer, Guido; Gross, Simon; Fuerbach, Alexander; Lancaster, David G; Withford, Michael J

    2013-07-15

    We report the first Yb:ZBLAN and Yb:IOG10 waveguide lasers fabricated by the fs-laser direct-writing technique. Pulses from a Titanium-Sapphire laser oscillator with 5.1 MHz repetition rate were utilized to generate negative refractive index modifications in both glasses. Multiple modifications were aligned in a depressed cladding geometry to create a waveguide. For Yb:ZBLAN we demonstrate high laser slope efficiency of 84% with a maximum output power of 170 mW. By using Yb:IOG10 a laser performance of 25% slope efficiency and 72 mW output power was achieved and we measured a remarkably high refractive index change exceeding Δn = 2.3 × 10(-2).

  20. Highly Efficient Solid Oxide Electrolyzer & Sabatier System Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Paragon Space Development Corporation (Paragon) and ENrG Incorporated (ENrG) are teaming to provide a highly efficient reactor for carbon monoxide/carbon dioxide...

  1. Highly Efficient Solid Oxide Electrolyzer & Sabatier System Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Paragon Space Development Corporation® (Paragon) and ENrG Incorporated (ENrG) are teaming to provide a highly efficient reactor for carbon monoxide/carbon...

  2. High Efficiency Lighting with Integrated Adaptive Control (HELIAC) Project

    Data.gov (United States)

    National Aeronautics and Space Administration — The proposed project is the continued development of the High Efficiency Lighting with Integrated Adaptive Control (HELIAC) system. Solar radiation is not a viable...

  3. Compact Tunable High-Efficiency Entangled Photon Source Project

    Data.gov (United States)

    National Aeronautics and Space Administration — MagiQ proposes to develop a compact tunable high-efficiency low-power-consumption entangled photon source. The source, based on inter-Fabry-Perot-cavity Spontaneous...

  4. High Efficiency Lighting with Integrated Adaptive Control (HELIAC) Project

    Data.gov (United States)

    National Aeronautics and Space Administration — The innovation of the proposed project is the development of High Efficiency Lighting with Integrated Adaptive Control (HELIAC) systems to drive plant growth. Solar...

  5. High Efficiency Direct Methane Solid Oxide Fuel Cell System Project

    Data.gov (United States)

    National Aeronautics and Space Administration — NASA has a defined need for energy dense and highly efficient energy storage and power delivery systems for future space missions. Compared to other fuel cell...

  6. An Improved, Highly Efficient Method for the Synthesis of Bisphenols

    Directory of Open Access Journals (Sweden)

    L. S. Patil

    2011-01-01

    Full Text Available An efficient synthesis of bisphenols is described by condensation of substituted phenols with corresponding cyclic ketones in presence of cetyltrimethylammonium chloride and 3-mercaptopropionic acid as a catalyst in extremely high purity and yields.

  7. Global climate change: Mitigation opportunities high efficiency large chiller technology

    Energy Technology Data Exchange (ETDEWEB)

    Stanga, M.V.

    1997-12-31

    This paper, comprised of presentation viewgraphs, examines the impact of high efficiency large chiller technology on world electricity consumption and carbon dioxide emissions. Background data are summarized, and sample calculations are presented. Calculations show that presently available high energy efficiency chiller technology has the ability to substantially reduce energy consumption from large chillers. If this technology is widely implemented on a global basis, it could reduce carbon dioxide emissions by 65 million tons by 2010.

  8. Highly efficient procedure for the transesterification of vegetable oil

    Energy Technology Data Exchange (ETDEWEB)

    Liang, Xuezheng; Gao, Shan; He, Mingyuan [Shanghai Key Laboratory of Green Chemistry and Chemical Process, Department of Chemistry, East China Normal University, Shanghai 200062 (China); Yang, Jianguo [Shanghai Key Laboratory of Green Chemistry and Chemical Process, Department of Chemistry, East China Normal University, Shanghai 200062 (China); Energy Institute, Department of Materials Science and Engineering, Pennsylvania State University, University Park, PA 16802 (United States)

    2009-10-15

    The highly efficient procedure has been developed for the synthesis of biodiesel from vegetable oil and methanol. The KF/MgO has been selected as the most efficient catalyst for the reactions with the yield of 99.3%. Operational simplicity, without need of the purification of raw vegetable oil, low cost of the catalyst used, high activities, no saponification and reusability are the key features of this methodology. (author)

  9. The photonic nanowire: A highly efficient single-photon source

    DEFF Research Database (Denmark)

    Gregersen, Niels

    2014-01-01

    The photonic nanowire represents an attractive platform for a quantum light emitter. However, careful optical engineering using the modal method, which elegantly allows access to all relevant physical parameters, is crucial to ensure high efficiency.......The photonic nanowire represents an attractive platform for a quantum light emitter. However, careful optical engineering using the modal method, which elegantly allows access to all relevant physical parameters, is crucial to ensure high efficiency....

  10. New high fill-factor triangular micro-lens array fabrication method using UV proximity printing

    CERN Document Server

    Lin, T -H; Chao, C -K

    2008-01-01

    A simple and effective method to fabricate a high fill-factor triangular microlens array using the proximity printing in lithography process is reported. The technology utilizes the UV proximity printing by controlling a printing gap between the mask and substrate. The designed approximate triangle microlens array pattern can be fabricated the high fill-factor triangular microlens array in photoresist. It is due to the UV light diffraction to deflect away from the aperture edges and produce a certain exposure in photoresist material outside the aperture edges. This method can precisely control the geometric profile of high fill factor triangular microlens array. The experimental results showed that the triangular micro-lens array in photoresist could be formed automatically when the printing gap ranged from 240 micrometers to 840 micrometers. The gapless triangular microlens array will be used to increases of luminance for backlight module of liquid crystal displays.

  11. Fabrication of a highly sensitive penicillin sensor based on charge transfer techniques.

    Science.gov (United States)

    Lee, Seung-Ro; Rahman, M M; Sawada, Kazuaki; Ishida, Makoto

    2009-03-15

    A highly sensitive penicillin biosensor based on a charge-transfer technique (CTTPS) has been fabricated and demonstrated in this paper. CTTPS comprised a charge accumulation technique for penicilloic acid and H(+) ions perception system. With the proposed CTTPS, it is possible to amplify the sensing signals without external amplifier by using the charge accumulation cycles. The fabricated CTTPS exhibits excellent performance for penicillin detection and exhibit a high-sensitivity (47.852 mV/mM), high signal-to-noise ratio (SNR), large span (1445 mV), wide linear range (0-25 mM), fast response time (penicillin sensor and exhibited almost eight times greater sensitivity as compared to ISFET (6.56 mV/mM). The sensor system is implemented for the measurement of the penicillin concentration in penicillin fermentation broth.

  12. Microresonator Kerr frequency combs with high conversion efficiency

    CERN Document Server

    Xue, Xiaoxiao; Xuan, Yi; Qi, Minghao; Weiner, Andrew M

    2016-01-01

    Microresonator-based Kerr frequency comb (microcomb) generation can potentially revolutionize a variety of applications ranging from telecommunications to optical frequency synthesis. However, phase-locked microcombs have generally had low conversion efficiency limited to a few percent. Here we report experimental results that achieve ~30% conversion efficiency (~200 mW on-chip comb power excluding the pump) in the fiber telecommunication band with broadband mode-locked dark-pulse combs. We present a general analysis on the efficiency which is applicable to any phase-locked microcomb state. The effective coupling condition for the pump as well as the duty cycle of localized time-domain structures play a key role in determining the conversion efficiency. Our observation of high efficiency comb states is relevant for applications such as optical communications which require high power per comb line.

  13. Fabrication of ZnO nanoparticles based sensitive methanol sensor and efficient photocatalyst

    Science.gov (United States)

    Faisal, M.; Khan, Sher Bahadar; Rahman, Mohammed M.; Jamal, Aslam; Abdullah, M. M.

    2012-07-01

    ZnO nanoparticles (NPs) were prepared by hydrothermal treatment with starting materials (zinc chloride and urea) in the presence of ammonium hydroxide and characterized by powder X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), Fourier transform infrared spectroscopy (FTIR), Raman spectroscopy and UV-vis spectroscopy. The synthesized nanoparticles are crystalline with wurtzite hexagonal phase having average particle size in the range of 80-130 nm. Photocatalytic activity of the prepared ZnO NPs was evaluated by the degradation of methylene blue and almost complete degradation (91.0%) takes place within 85 min of irradiation time. Prepared ZnO nanostructures possessed high photocatalytic activity when compared with TiO2-UV100. Additionally, the sensing properties of the ZnO films were investigated for various concentrations of methanol in liquid phase by simple I-V technique at room conditions. It was observed that ZnO thin film exhibits good sensitivity (0.9554 μA cm-2 mM-1) towards detection of methanol at room conditions.

  14. High efficiency USC power plant - present status and future potential

    Energy Technology Data Exchange (ETDEWEB)

    Blum, R. [Faelleskemikerne I/S Fynsvaerket (Denmark); Hald, J. [Elsam/Elkraft/TU Denmark (Denmark)

    1998-12-31

    Increasing demand for energy production with low impact on the environment and minimised fuel consumption can be met with high efficient coal fired power plants with advanced steam parameters. An important key to this improvement is the development of high temperature materials with optimised mechanical strength. Based on the results of more than ten years of development a coal fired power plant with an efficiency above 50 % can now be realised. Future developments focus on materials which enable an efficiency of 52-55 %. (orig.) 25 refs.

  15. Fabrication of high aspect ratio nanogrid transparent electrodes via capillary assembly of Ag nanoparticles

    Science.gov (United States)

    Kang, Juhoon; Park, Chang-Goo; Lee, Su-Han; Cho, Changsoon; Choi, Dae-Geun; Lee, Jung-Yong

    2016-05-01

    In this report, we describe the fabrication of periodic Ag nanogrid electrodes by capillary assembly of silver nanoparticles (AgNPs) along patterned nanogrid templates. By assembling the AgNPs into these high-aspect-ratio nanogrid patterns, we can obtain high-aspect-ratio nanogratings, which can overcome the inherent trade-off between the optical transmittance and the sheet resistance of transparent electrodes. The junction resistance between the AgNPs is effectively reduced by photochemical welding and post-annealing. The fabricated high-aspect-ratio nanogrid structure with a line width of 150 nm and a height of 450 nm has a sheet resistance of 15.2 Ω sq-1 and an optical transmittance of 85.4%.In this report, we describe the fabrication of periodic Ag nanogrid electrodes by capillary assembly of silver nanoparticles (AgNPs) along patterned nanogrid templates. By assembling the AgNPs into these high-aspect-ratio nanogrid patterns, we can obtain high-aspect-ratio nanogratings, which can overcome the inherent trade-off between the optical transmittance and the sheet resistance of transparent electrodes. The junction resistance between the AgNPs is effectively reduced by photochemical welding and post-annealing. The fabricated high-aspect-ratio nanogrid structure with a line width of 150 nm and a height of 450 nm has a sheet resistance of 15.2 Ω sq-1 and an optical transmittance of 85.4%. Electronic supplementary information (ESI) available. See DOI: 10.1039/c6nr01896c

  16. Field test of radioactive high efficiency filter and filter exchange techniques of fuel cycle examination facility

    Energy Technology Data Exchange (ETDEWEB)

    Hwang, Yong Hwa; Lee, Hyung Kwon; Chun, Young Bum; Park, Dae Gyu; Ahn, Sang Bok; Chu, Yong Sun; Kim, Eun Ka

    1997-12-01

    The development of high efficiency filter was started to protect human beings from the contamination of radioactive particles, toxic gases and bacillus, and its gradual performance increment led to the fabrication of Ultra Low Penetration Air Filter (ULPA) today. The application field of ULPA has been spread not only to the air conditioning of nuclear power facilities, semiconductor industries, life science, optics, medical care and general facilities but also to the core of ultra-precision facilities. Periodic performance test on the filters is essential to extend its life-time through effective maintenance. Especially, the bank test on HEPA filter of nuclear facilities handling radioactive materials is required for environmental safety. Nowadays, the bank test technology has been reached to the utilization of a minimized portable detecting instruments and the evaluation techniques can provide high confidence in the area of particle distribution and leakage test efficiency. (author). 16 refs., 13 tabs., 14 figs.

  17. A High-Efficiency Compact Planar Antenna for ISM Wireless Systems

    Directory of Open Access Journals (Sweden)

    Tao Zhou

    2017-01-01

    Full Text Available A novel high-efficiency compact planar antenna at 433 MHz with minimized size and low-cost and easy to integrate into the ISM wireless applications is designed, fabricated, and measured. Capacitive strips that are formed by cutting inter-digital slots and the meander lines on both sides are introduced to greatly reduce the antenna size yet maintain the high efficiency. The proposed antenna has a simple planar structure and occupies a small area (i.e., 45 × 30 mm2. This novel electrically small antenna can be operated well without any lumped elements for impedance matching. Details of the antenna design and experimental results are presented and discussed.

  18. Ultra-High Density Single Nanometer-Scale Anodic Alumina Nanofibers Fabricated by Pyrophosphoric Acid Anodizing

    Science.gov (United States)

    Kikuchi, Tatsuya; Nishinaga, Osamu; Nakajima, Daiki; Kawashima, Jun; Natsui, Shungo; Sakaguchi, Norihito; Suzuki, Ryosuke O.

    2014-12-01

    Anodic oxide fabricated by anodizing has been widely used for nanostructural engineering, but the nanomorphology is limited to only two oxides: anodic barrier and porous oxides. Therefore, the discovery of an additional anodic oxide with a unique nanofeature would expand the applicability of anodizing. Here we demonstrate the fabrication of a third-generation anodic oxide, specifically, anodic alumina nanofibers, by anodizing in a new electrolyte, pyrophosphoric acid. Ultra-high density single nanometer-scale anodic alumina nanofibers (1010 nanofibers/cm2) consisting of an amorphous, pure aluminum oxide were successfully fabricated via pyrophosphoric acid anodizing. The nanomorphologies of the anodic nanofibers can be controlled by the electrochemical conditions. Anodic tungsten oxide nanofibers can also be fabricated by pyrophosphoric acid anodizing. The aluminum surface covered by the anodic alumina nanofibers exhibited ultra-fast superhydrophilic behavior, with a contact angle of less than 1°, within 1 second. Such ultra-narrow nanofibers can be used for various nanoapplications including catalysts, wettability control, and electronic devices.

  19. High Efficiency of Two Efficient QSDC with Authentication Is at the Cost of 1Their Security

    Institute of Scientific and Technical Information of China (English)

    QIN Su-Juan; WEN Qiao-Yan; MENG Luo-Ming; ZHU Fu-Chen

    2009-01-01

    Two efficient protocols of quantum secure direct communication with authentication [Chin. Phys. Lett. 25 (2008)2354] were recently proposed by Liu et al. to improve the efficiency of two protocols presented in [Phys. Rev. A 75 (2007) 026301] by four Pauli operations. We show that the high efficiency of the two protocols is at the expense of their security. The authenticator Trent can reach half the secret by a particular attack strategy in the first protocol. In the second protocol, not only Trent but also an eavesdropper outside can elicit half-information about the secret from the public declaration.

  20. Highly efficient Nd: YAG ceramic CW laser with 59.8% slope-efficiency

    Institute of Scientific and Technical Information of China (English)

    Yunfeng Qi; Qihong Lou; Haixia Ma; Jingxing Dong

    2005-01-01

    @@ In this paper, a highly efficient Ti:sapphire end-pumped 1 at.-% Nd:YAG ceramic laser that is comparable in efficiency with Nd:YAG single crystal lasers has been developed. Optical absorption and emission spectra for Nd:YAG ceramics have been measured. With 673-mW pumping, 295-mW laser output at 1064 nm has been obtained. The laser threshold is only 13 mW. Deducted the transmitted light, the corresponding optical-to-optical conversion efficiency is 58.4%. The lasing characteristics of Nd:YAG ceramic are nearly equal to those of Nd:YAG single crystal.