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Sample records for exchange charge

  1. Hydration shells exchange charge with their protein

    DEFF Research Database (Denmark)

    Abitan, Haim; Lindgård, Per-Anker; Nielsen, Bjørn Gilbert

    2010-01-01

    Investigation of the interaction between a protein and its hydration shells is an experimental and theoretical challenge. Here, we used ultrasonic pressure waves in aqueous solutions of a protein to explore the conformational states of the protein and its interaction with its hydration shells....... In our experiments, the amplitude of an ultrasonic pressure wave is gradually increased (0–20 atm) while we simultaneously measure the Raman spectra from the hydrated protein (β-lactoglobulin and lysozyme). We detected two types of spectral changes: first, up to 70% increase in the intensity...... the presence of an ultrasonic pressure, a protein and its hydration shells are in thermodynamic and charge equilibrium, i.e. a protein and its hydration shells exchange charges. The ultrasonic wave disrupts these equilibria which are regained within 30–45 min after the ultrasonic pressure is shut off....

  2. Ion thruster charge-exchange plasma flow

    Science.gov (United States)

    Carruth, M. R., Jr.; Gabriel, S. B.; Kitamura, S.

    1982-01-01

    The electron bombardment ion thruster has been under development for a number of years and during this time, studies of the plasmas produced by the thrusters and their interactions with spacecraft have been evaluated, based on available data. Due to diagnostic techniques used and facility effects, there is uncertainty as to the reliability of data from these early studies. This paper presents data on the flow of the charge-exchange plasma produced just downstream of the thruster's ion optics. The 'end-effect' of a cylindrical Langmuir probe is used to determine ion density and directed ion velocity. Results are compared with data obtained from a retarding potential analyzer-Faraday cup.

  3. Fine structure of charge exchange lines observed in laboratory plasmas

    Energy Technology Data Exchange (ETDEWEB)

    Ida, K.; Nishimura, S. [National Inst. for Fusion Science, Nagoya (Japan); Kondo, K.

    1997-01-01

    The influence of the fine structure of charge exchange lines appears only at the plasma edge or in the recombining phase where the ion temperature is low enough. The observed spectra in Li III and C VI are consistent with the sum of fine-structure components populated by statistical weights (assuming complete l-mixing) not by direct charge exchange cross sections. Some discrepancy was observed in the intensity ratio of fine-structure components between the observation and calculation for C VI in the recombining phase. The fine-structure of charge exchange lines gives an apparent Doppler shift in plasma rotation velocity measurement using charge exchange spectroscopy. (author)

  4. X-ray emission from charge exchange of highly-charged ions in atoms and molecules

    Science.gov (United States)

    Greenwood, J. B.; Williams, I. D.; Smith, S. J.; Chutjian, A.

    2000-01-01

    Charge exchange followed by radiative stabilization are the main processes responsible for the recent observations of X-ray emission from comets in their approach to the Sun. A new apparatus was constructed to measure, in collisions of HCIs with atoms and molecules, (a) absolute cross sections for single and multiple charge exchange, and (b) normalized X-ray emission cross sections.

  5. Characterization of an atomic hydrogen source for charge exchange experiments

    Energy Technology Data Exchange (ETDEWEB)

    Leutenegger, M. A. [NASA Goddard Space Flight Center, Code 662, Greenbelt, Maryland 20771 (United States); CRESST/University of Maryland Baltimore County, 1000 Hilltop Circle, Baltimore, Maryland 21250 (United States); Beiersdorfer, P.; Brown, G. V.; Magee, E. W. [Lawrence Livermore National Laboratory, 7000 East Ave., Livermore, California 94550 (United States); Betancourt-Martinez, G. L. [NASA Goddard Space Flight Center, Code 662, Greenbelt, Maryland 20771 (United States); University of Maryland College Park, College Park, Maryland 20742 (United States); Hell, N. [Lawrence Livermore National Laboratory, 7000 East Ave., Livermore, California 94550 (United States); Dr. Karl-Remeis-Sternwarte and ECAP, FAU Erlangen-Nürnberg, Sternwartstr. 7, 96049 Bamberg (Germany); Kelley, R. L.; Kilbourne, C. A.; Porter, F. S. [NASA Goddard Space Flight Center, Code 662, Greenbelt, Maryland 20771 (United States)

    2016-11-15

    We characterized the dissociation fraction of a thermal dissociation atomic hydrogen source by injecting the mixed atomic and molecular output of the source into an electron beam ion trap containing highly charged ions and recording the x-ray spectrum generated by charge exchange using a high-resolution x-ray calorimeter spectrometer. We exploit the fact that the charge exchange state-selective capture cross sections are very different for atomic and molecular hydrogen incident on the same ions, enabling a clear spectroscopic diagnostic of the neutral species.

  6. Measurement of absorption and charge exchange of $\\pi^+$ on carbon

    CERN Document Server

    Ieki, K; Berkman, S; Bhadra, S; Cao, C; de Perio, P; Hayato, Y; Ikeda, M; Kanazawa, Y; Kim, J; Kitching, P; Mahn, K; Nakaya, T; Nicholson, M; Olchanski, K; Rettie, S; Tanaka, H A; Wilking, M J; Tobayama, S; Yamauchi, T; Yen, S; Yokoyama, M

    2015-01-01

    The combined cross section for absorption and charge exchange interactions of positively charged pions with carbon nuclei for the momentum range 200 MeV/c to 300 MeV/c have been measured with the DUET experiment at TRIUMF. The uncertainty is reduced by nearly half compared to previous experiments. This result will be a valuable input to existing models to constrain pion interactions with nuclei.

  7. Charge exchange spectroscopy as a fast ion diagnostic on TEXTOR

    NARCIS (Netherlands)

    Delabie, E.; Jaspers, R. J. E.; von Hellermann, M. G.; Nielsen, S.K.; Marchuk, O.

    2008-01-01

    An upgraded charge exchange spectroscopy diagnostic has been taken into operation at the TEXTOR tokamak. The angles of the viewing lines with the toroidal magnetic field are close to the pitch angles at birth of fast ions injected by one of the neutral beam injectors. Using another neutral beam for

  8. Charge Exchange and Chemical Reactions with Trapped Th$^{3+}$

    CERN Document Server

    Churchill, L R; Chapman, M S

    2010-01-01

    We have measured the reaction rates of trapped, buffer gas cooled Th$^{3+}$ and various gases and have analyzed the reaction products using trapped ion mass spectrometry techniques. Ion trap lifetimes are usually limited by reactions with background molecules, and the high electron affinity of multiply charged ions such as Th$^{3+}$ make them more prone to loss. Our results show that reactions of Th$^{3+}$ with carbon dioxide, methane, and oxygen all occur near the classical Langevin rate, while reaction rates with argon, hydrogen, and nitrogen are orders of magnitude lower. Reactions of Th$^{3+}$ with oxygen and methane proceed primarily via charge exchange, while simultaneous charge exchange and chemical reaction occurs between Th$^{3+}$ and carbon dioxide. Loss rates of Th$^{3+}$ in helium are consistent with reaction with impurities in the gas. Reaction rates of Th$^{3+}$ with nitrogen and argon depend on the internal electronic configuration of the Th$^{3+}$.

  9. Peculiarity of the charge-exchange quadrupole excitation in nuclei

    Energy Technology Data Exchange (ETDEWEB)

    Leonardi, R.; Lipparini, E.; Stringari, S.

    1987-04-01

    The experimental isovector quadrupole strength in the charge exchange channels is smaller than predicted by random phase approximation calculations using conventional nuclear interactions. The introduction of nonlocal components in the interaction combined with the existence of a low-lying 0h-dash-bar..omega.. rotational 2/sup +/ quadrupole state in the daughter nucleus can explain this behavior. These nonlocal interactions do not play a role in the properties of the isovector monopole and dipole resonance.

  10. Charge exchange reactions as tests for structures of exotic nuclei

    CERN Document Server

    Karataglidis, S

    2010-01-01

    Charge exchange reactions serve as alternative tests of the structures of exotic nuclei. Of particular relevance is the (p, n) reaction, which is related to the Gamow-Teller matrix element. The (p, n) reaction is also related to (p, p′) in the case of transitions to the isobaric analogue state (IAS). There are few measurements of (p, n) reactions using exotic beams. We revisit the case of 6He(p, n)6Li and discuss apparent discrepancies with other available data.

  11. Excited State Atom-Ion Charge-Exchange

    Science.gov (United States)

    Li, Ming; Makrides, Constantinos; Petrov, Alexander; Kotochigova, Svetlana

    2017-04-01

    We theoretically investigate the exothermic charge-exchange reaction between an excited atom and a ground-state positive ion. In particular, we focus on MOT-excited Ca*(4s4p 1P) atoms colliding with ground-state Yb+ ions, which are under active study by the experimental group of E. Hudson at UCLA. Collisions between an excited atom and an ion are guided by two major contributions to the long-range interaction potentials, the induction C4 /R4 and charge-quadrupole C3 /R3 potentials, and their coupling by the electron-exchange interaction. Our model of these forces leads to close-coupling equations for multiple reaction channels. We find several avoided crossings between the potentials that couple to the nearby asymptotic limits of Yb*+Ca+, some of which can possibly provide large charge exchange rate coefficients above 10-10 cm3 / s. We acknowledge support from the US Army Research Office, MURI Grants W911NF-14-1-0378 and the US National Science Foundation, Grant PHY-1619788.

  12. Charge-exchange plasma generated by an ion thruster

    Science.gov (United States)

    Kaufman, H. R.

    1975-01-01

    The use of high voltage solar arrays greatly reduces or eliminates power processing requirements in space electric propulsion systems. This use also requires substantial areas of solar array to be at high positive potential relative to space and most of the spacecraft. The charge exchange plasma conducts electrons from the ion beam to such positive surfaces, and thereby electrically load the high voltage solar array. To evaluate this problem, the charge-exchange plasma generated by an ion beam was investigated experimentally. Based upon the experimental data, a simple model was derived for the charge-exchange plasma. This model is conservative in the sense that both the electron/ion density and the electron current density should be equal to, or less than, the preducted value for all directions in the hemisphere upstream of the ion beam direction. Increasing the distance between a positive potential surface (such as a high voltage solar array) and the thruster is the simplest way to control interactions. Both densities and currents vary as the inverse square of this distance.

  13. Charge exchange in fluid description of partially ionized plasmas

    CERN Document Server

    Vranjes, J; Luna, M

    2015-01-01

    The effects of charge exchange on waves propagating in weakly ionized plasmas are discussed. It is shown that for low-frequency processes, ions and neutrals should be treated as a single fluid with some effective charge on all of them. We have derived a new momentum equation which should be used in such an environment. As a result, the low-frequency magnetic waves can propagate even if particles are not magnetized, which is entirely due to the charge exchange and the fact that it is not possible to separate particles into two different populations as charged and neutral species. So there can be no friction force between ions and neutrals in the usual sense. The mean force per particle is proportional to the ionization ratio $n_i/(n_i+ n_n)$. Regarding the application of the theory to the Alfven wave propagation in the lower solar atmosphere, the results predict that the plane of displacement of the fluid must change by 90 degrees when an Alfven wave propagates from the area where particles are un-magnetized (...

  14. Interdefect charge exchange in silicon particle detectors at cryogenic temperatures

    CERN Document Server

    MacEvoy, B; Hall, G; Moscatelli, F; Passeri, D; Santocchia, A

    2002-01-01

    Silicon particle detectors in the next generation of experiments at the CERN Large Hadron Collider will be exposed to a very challenging radiation environment. The principal obstacle to long-term operation arises from changes in detector doping concentration (N/sub eff/), which lead to an increase in the bias required to deplete the detector and hence achieve efficient charge collection. We have previously presented a model of interdefect charge exchange between closely spaced centers in the dense terminal clusters formed by hadron irradiation. This manifestly non-Shockley-Read-Hall (SRH) mechanism leads to a marked increase in carrier generation rate and negative space charge over the SRH prediction. There is currently much interest in the subject of cryogenic detector operation as a means of improving radiation hardness. Our motivation, however, is primarily to investigate our model further by testing its predictions over a range of temperatures. We present measurements of spectra from /sup 241/Am alpha par...

  15. Exciting baryon resonances in isobar charge-exchange reactions

    Science.gov (United States)

    Benlliure, J.; Rodriguez-Sanchez, J. L.; Vargas, J.; Alavarez-Pol, H.; Aumann, T.; Atkinson, J.; Ayyad, Y.; Beceiro, S.; Boretzky, K.; Chatillon, A.; Cortina, D.; Diaz, P.; Estrade, A.; Geissel, H.; Lenske, H.; Litvinov, Y.; Mostazo, M.; Paradela, C.; Pietri, S.; Prochazka, A.; Takechi, M.; Vidaña, I.; Weick, H.; Winfield, J.

    2017-11-01

    Isobaric charge-exchange reactions induced by different tin isotopes have been investigated at GSI. The high-resolving power of the FRS spectrometer made it possible to separate elastic and inelastic components in the missing-energy spectra of the ejectiles. The inelastic component was associated to the in-medium excitation of nucleon resonances such as the Delta and Roper resonances. These data are expected to contribute to better understand the in-medium properties of baryon resonances but also to investigate the abundance of protons and neutrons at the nuclear periphery.

  16. Progress Towards Charge Exchange Cross-Sections with Highly Charged Ions: Computation and Experiment

    Science.gov (United States)

    Bromley, Steven James

    This thesis is a summary of the computational and experimental progress towards measuring the charge exchange cross-section of highly charged ions (HCIs). Electronic structure calculations were carried out for the molecular ion LiHe+ using NWChem on the Clemson University Palmetto Cluster. Potential energy surfaces for 40 electronic states are presented. The electronic configurations of the six lowest states have been identified by their energies in the separate atom limit, which deviate from experimental values by at most 1.2%. Future work will investigate higher charge states of LiHe and the interaction between low-Z HCIs and neutral gases. Two experimental apparatus were designed and constructed for experiments with HCIs. To aid in the detection of trapped HCIs, a time-of-flight mass spectrometer for radial extraction from Paul traps was constructed and tested using a Mg + source. Lastly, a gas cell was designed and constructed for charge exchange cross-section measurements using HCIs produced in the Clemson University Electron Beam Ion Trap (CUEBIT).

  17. Nucleon charge-exchange reactions at intermediate energy

    Energy Technology Data Exchange (ETDEWEB)

    Alford, W.P. [Western Ontario Univ., London, ON (Canada). Dept. of Physics]|[TRIUMF, Vancouver, BC (Canada); Spicer, B.M. [Melbourne Univ., Parkville, VIC (Australia). School of Physics

    1997-12-31

    An historical review of the development of ideas pertaining to Gamow-Teller giant resonances is given, and a description of the emergence of techniques for the study of charge exchange reactions - particularly the technical advances which yielded the recent volume of new date. The present status of charge exchange reactions is reviewed and assessed. Evidence is presented from the {sup 14}C(p,n) reaction for the dominance of the spin-isospin component of the nucleon-nucleon interaction in intermediate energy reactions. In (p,n) reactions the Gamow-Teller giant resonance dominates the spectra, with higher multipoles contributing. By contrast, in (n,p) reactions in the heavier nuclei, the Gamow-Teller transitions are substantially Pauli-blocked and the spin dipole resonance dominates, with contributions from higher multipoles. Discussions of the multipole decomposition process, used to obtain from the data the contributions of the different multipoles, and the contributions of the multipoles, are given. 226 refs., 19 figs.

  18. Laser-assisted H^{-} charge exchange injection in magnetic fields

    Directory of Open Access Journals (Sweden)

    T. Gorlov

    2010-05-01

    Full Text Available The use of stripping foils for charge exchange injection can cause a number of operational problems in high intensity hadron accelerators. A recently proposed three-step method of laser-assisted injection is capable of overcoming these problems. This paper presents advances in the physical model of laser-assisted charge exchange injection of H^{-} beams and covers a wide field of atomic physics. The model allows the calculation of the evolution of an H^{0} beam taking into account spontaneous emission, field ionization, and external electromagnetic fields. Some new data on the hydrogen atom related to the problem are calculated. The numerical calculations in the model use realistic descriptions of laser field and injection beam. Generally, the model can be used for design and optimization of a laser-assisted injection cell within an accelerator lattice. Example calculations of laser-assisted injection for an intermediate experiment at SNS in Oak Ridge and for the PS2 accelerator at CERN are presented. Two different schemes, distinctively characterized by various magnetic fields at the excitation point, are discussed. It was shown that the emittance growth of an injected beam can be drastically decreased by moving the excitation point into a strong magnetic field.

  19. Charge Exchange: Velocity Dependent X-ray Emission Modeling

    Science.gov (United States)

    Cumbee, Renata

    2017-06-01

    Atomic collisions play a fundamental role in astrophysics, plasma physics, and fusion physics. Here, we focus on charge exchange (CX) between hot ions and neutral atoms and molecules. Even though charge exchange calculations can provide vital information, including neutral and ion density distributions, ion temperatures, elemental abundances, and ion charge state distributions in the environments considered, both theoretical calculations and laboratory studies of these processes lack the necessary reliability and/or coverage. In order to better understand the spectra we observe in astrophysical environments in which both hot plasma and neutral gas are present, including comets, the heliosphere, supernova remnants, galaxy clusters, star forming galaxies, the outflows of starburst galaxies, and cooling flows of hot gas in the intracluster medium, a thorough CX X-ray model is needed. Included in this model should be a complete set of X-ray line ratios for relevant ion and neutral interactions for a range of energies.In this work, theoretical charge exchange emission spectra are produced using cross sections calculated with widely applied approaches including the quantum mechanical molecular orbital close coupling (QMOCC), atomic orbital close coupling (AOCC), classical trajectory Monte Carlo (CTMC), and the multichannel Landau-Zener (MCLZ) methods. When possible, theoretical data are benchmarked to experiments. Using a comprehensive, but still far from complete, CX database, new models are performed for a variety of X-ray emitting environments. In an attempt to describe the excess emission in X-rays of the starburst galaxy M82, Ne X CX line ratios are compared to line ratios observed in the region. A more complete XSPEC X-ray emission model is produced for H-like and He-like C-Al ions colliding with H and He for a range of energies; 200 to 5000 eV/u. This model is applied to the northeast rim of the Cygnus Loop supernova remnant in an attempt to determine the

  20. Anion exchangers with negatively charged functionalities in hyperbranched ion-exchange layers for ion chromatography.

    Science.gov (United States)

    Uzhel, Anna S; Zatirakha, Alexandra V; Smirnov, Konstantin N; Smolenkov, Alexandr D; Shpigun, Oleg A

    2017-01-27

    Novel pellicular poly(styrene-divinylbenzene)-based (PS-DVB) anion exchangers with covalently-bonded hyperbranched functional ion-exchange layers containing negatively charged functionalities are obtained and examined. The hyperbranched coating is created on the surface of aminated PS-DVB substrate by repeating the modification cycles including alkylation with 1,4-butanediol diglycidyl ether (1,4-BDDGE), and amination of the terminal epoxide rings with methylamine (MA) or glycine (Gly). The influence of the position and the number of the layers with glycine, as well as of the total number of the layers of amine in the coating on the chromatographic properties of the obtained stationary phases is investigated. Chromatographic performance of the obtained stationary phases is evaluated using the model mixtures of inorganic and organic anions with hydroxide eluent. It is shown that the best selectivity toward weakly retained organic acids and oxyhalides is possessed by the anion exchanger obtained after 5 modification cycles, with glycine being used in the first one. Such anion exchanger packed in 25-cm long column is capable of separating 22 anions in 58min including 7 standard anions, mono-, di- and trivalent organic acids, oxyhalides, and some other double- and triple-charged anions. Copyright © 2016 Elsevier B.V. All rights reserved.

  1. Spermine Sepharose as a clustered-charge anion exchange adsorbent.

    Science.gov (United States)

    Dhamane, Sagar; Ruiz-Ruiz, Federico; Chen, Wen-hsiang; Kourentzi, Katerina; Benavides, Jorge; Rito-Palomares, Marco; Willson, Richard C

    2014-01-10

    We previously showed that the affinity and capacity of ion exchange adsorbents of a given total charge density are improved by immobilization of the charges in pre-ordered clusters, rather than individually in random locations. This previous work used pentalysinamide and pentaargininamide as clustered ligands. This approach allows close control of cluster size, but is uneconomically expensive for some research and most practical applications. In this work, we demonstrate that the inexpensive synthetic analog of the natural polyamine spermine (H2N-CH2-CH2-CH2-NH-CH2-CH2-CH2-CH2-NH-CH2-CH2-CH2-NH2) also can serve as the basis of effective clustered adsorbents. The calcium-depleted form of the protein α-lactalbumin, and RNA from baker's yeast, were adsorbed on a spermine Sepharose adsorbent. This adsorbent exhibited enhanced α-lactalbumin binding capacity (Qmax>1.6 and 1.3-fold higher than those for Qiagen DEAE and GE DEAE Sepharose adsorbents of much greater charge density) and higher initial binding affinity (Qmax/KD 2.4 and 2.1-fold higher, respectively). The new spermine-based matrix exhibited a higher value of the Z parameter, suggesting an increased number of apparent interaction sites between the protein and the resin, and functioned well in column mode. Copyright © 2013 Elsevier B.V. All rights reserved.

  2. Charge exchange spectroscopy as a fast ion diagnostic on TEXTOR

    DEFF Research Database (Denmark)

    Delabie, E.; Jaspers, R.J.E.; von Hellermann, M.G.

    2008-01-01

    for active spectroscopy, injected counter the direction in which fast ions injected by the first beam are circulating, we can simultaneously measure a fast ion tail on the blue wing of the D-alpha spectrum while the beam emission spectrum is Doppler shifted to the red wing. An analysis combining the two......An upgraded charge exchange spectroscopy diagnostic has been taken into operation at the TEXTOR tokamak. The angles of the viewing lines with the toroidal magnetic field are close to the pitch angles at birth of fast ions injected by one of the neutral beam injectors. Using another neutral beam...... parts of the spectrum offers possibilities to improve the accuracy of the absolute (fast) ion density profiles. Fast beam modulation or passive viewing lines cannot be used for background subtraction on this diagnostic setup and therefore the background has to be modeled and fitted to the data together...

  3. H^{-} charge-exchange injection without hazardous stripping foils

    Directory of Open Access Journals (Sweden)

    Isao Yamane

    1998-09-01

    Full Text Available A new scheme of H^{-} charge-exchange injection without stripping foils is proposed. It is composed of a neutralizer of the H^{-} beam using Lorentz stripping, the colliding system of a high power laser and the H^{0} beam to excite H^{0} atoms to the 3P state using the Rabi oscillation, and a magnet to strip the H^{0}(3P to a proton beam by Lorentz stripping. The necessary laser wavelength, laser power, magnetic-field gradient, and maximum magnetic field are estimated for a beam energy from 1.0 to 3.0 GeV. The result shows that such a scheme is sufficiently feasible for H^{-} beams with an energy discussed here.

  4. Charge Exchange Cross Sections Measured at Low Energies in Q-Machines

    DEFF Research Database (Denmark)

    Andersen, S. A.; Jensen, Vagn Orla; Michelsen, Poul

    1972-01-01

    A new technique for measurements of charge exchange cross sections at low energies is described. The measurements are performed in a single‐ended Q machine. The resonance charge exchange cross section for Cs at 2 eV was found to be 0.6×10−13 cm2±20%.......A new technique for measurements of charge exchange cross sections at low energies is described. The measurements are performed in a single‐ended Q machine. The resonance charge exchange cross section for Cs at 2 eV was found to be 0.6×10−13 cm2±20%....

  5. XMM-Newton Observations of Solar Wind Charge Exchange Emission

    Science.gov (United States)

    Snowden, S. L.; Collier, M. R.; Kuntz, K. D.

    2004-01-01

    We present an XMM-Newton spectrum of diffuse X-ray emission from within the solar system. The spectrum is dominated by O VII and O VIII lines at 0.57 keV and 0.65 keV, O VIII (and possibly Fe XVII) lines at approximately 0.8 keV, Ne IX lines at approximately 0.92 keV, and Mg XI lines at approximately 1.35 keV. This spectrum is consistent with what is expected from charge exchange emission between the highly ionized solar wind and either interstellar neutrals in the heliosphere or material from Earth's exosphere. The emission is clearly seen as a low-energy ( E less than 1.5 keV) spectral enhancement in one of a series of observations of the Hubble Deep Field North. The X-ray enhancement is concurrent with an enhancement in the solar wind measured by the ACE satellite. The solar wind enhancement reaches a flux level an order of magnitude more intense than typical fluxes at 1 AU, and has ion ratios with significantly enhanced higher ionization states. Whereas observations of the solar wind plasma made at a single point reflect only local conditions which may only be representative of solar wind properties with spatial scales ranging from less than half of an Earth radii (approximately 10 s) to 100 Earth radii, X-ray observations of solar wind charge exchange are remote sensing measurements which may provide observations which are significantly more global in character. Besides being of interest in its own right for studies of the solar system, this emission can have significant consequences for observations of more cosmological objects. It can provide emission lines at zero redshift which are of particular interest (e.g., O VII and O VIII) in studies of diffuse thermal emission, and which can therefore act as contamination in objects which cover the entire detector field of view. We propose the use of solar wind monitoring data, such as from the ACE and Wind spacecraft, as a diagnostic to screen for such possibilities.

  6. Charge Reduction Potentials of Several Refrigerants Based on Experimentally Validated Micro-Channel Heat Exchangers Performance and Charge Model

    OpenAIRE

    Padilla Fuentes, Yadira; Hrnjak, Predrag S.

    2012-01-01

    This paper presents an experimentally validated simulation model developed to obtain accurate prediction of evaporator microchannel heat exchanger performance and charge. Effects of using various correlations are presented and discussed with focus on serpentine microchannel evaporators. Experiments with propane are used to validate the model. The experimentally validated model is used to compare the charge reduction potential of various refrigerants. The procedure for charge reduction analysi...

  7. Charge-exchange reactions with a secondary triton beam

    CERN Document Server

    Sherrill, B M; Austin, S M; Bazin, D; Berg, A; Berg, G P A; Caggiano, J; Daito, I; Fujimura, H; Fujita, Y; Fujiwara, M; Hara, K; Harakeh, M N; Jänecke, J; Kawabata, T; Navin, A; Roberts, D A; Steiner, M

    1999-01-01

    A secondary triton beam from fragmentation of 560-MeV alpha-particles has been used in a high-resolution (t, sup 3 He) charge-exchange experiment at intermediate bombarding energies. The experiment was carried out at the National Superconducting Cyclotron Laboratory using a sup 4 He beam from the K1200 cyclotron. The radioactive triton beam of (0.5-1.0)x10 sup 6 particles/s with a mean energy of 350 MeV was produced in a production target of the A1200 fragment separator and transported to the target position of the S800 magnetic spectrometer. Ray-tracing and dispersion-matching techniques were employed to detect sup 3 He particles from the sup 1 sup 2 C(t, sup 3 He) sup 1 sup 2 B reaction near 0 deg. . An energy resolution of DELTA E approx 160 keV or DELTA E/E approx 4.6x10 sup - sup 4 (FWHM) was achieved. This is an improvement over our previous results and opens the possibility for studying high-resolution (n,p)-type reactions at intermediate bombarding energies. (author)

  8. Toroidal charge exchange recombination spectroscopy measurements on MST

    Energy Technology Data Exchange (ETDEWEB)

    Magee, R. M.; Den Hartog, D. J.; Fiksel, G.; Kumar, S. T. A. [University of Wisconsin, 1150 University Avenue, Madison, Wisconsin 53706 (United States); Craig, D. [Wheaton College, 501 College Avenue, Wheaton, Illinois 60187 (United States)

    2010-10-15

    Charge exchange recombination spectroscopy measurements of the poloidal component of the C{sup +6} temperature and flow in the Madison Symmetric Torus have been vital in advancing the understanding of the ion dynamics in the reversed field pinch. Recent work has expanded the diagnostic capability to include toroidal measurements. A new toroidal view overcomes a small signal-to-background ratio (5%-15%) to make the first localized measurements of the parallel component of the impurity ion temperature in the core of the reversed field pinch. The measurement is made possible through maximal light collection in the optical design and extensive atomic modeling in the fitting routine. An absolute calibration of the system allowed the effect of Poisson noise in the signal on line fitting to be quantified. The measurement is made by stimulating emission with a recently upgraded 50 keV hydrogen diagnostic neutral beam. Radial localization is {approx}4 cm{sup 2}, and good temporal resolution (100 {mu}s) is achieved by making simultaneous emission and background measurements with a high-throughput double-grating spectrometer.

  9. 76 FR 10498 - Exchange Visitor Program-Fees and Charges

    Science.gov (United States)

    2011-02-25

    ... finds that educational and cultural exchanges are both the cornerstone of U.S. public diplomacy and an... Cultural exchange program. Accordingly, 22 CFR part 62 is amended as follows: PART 62--EXCHANGE VISITOR..., 1977 Comp. p. 200; E.O. 12048 of March 27, 1978; 3 CFR, 1978 Comp. p. 168; the Illegal Immigration...

  10. Gain measurements of the Ca-Xe charge exchange system. [for UV lasers

    Science.gov (United States)

    Michels, C. J.; Chubb, D. L.

    1978-01-01

    Charge-exchange-pumped Ca(+) was studied for possible positive laser gain at 370.6 and 315.9 nm using an Xe MPD arc as the Xe(+) source. The present paper describes the MPD arc, the calcium injection system, the diagnostics for gain, and spontaneous emission measurements and results. No positive gain measurements were observed. A small Xe-Ca charge exchange cross section compared to He-metal laser systems charge exchange cross sections is the most probable reason why the result was negative.

  11. 75 FR 60674 - Exchange Visitor Program-Fees and Charges

    Science.gov (United States)

    2010-10-01

    ... entities to conduct educational and cultural exchange programs pursuant to a broad grant of authority provided by the Mutual Educational and Cultural Exchange Act of 1961, as amended (Fulbright- Hays Act), 22 U.S.C. 2451 et seq.; the Immigration and Nationality Act, 8 U.S.C. 1101(a)(15)(J); the Foreign...

  12. 78 FR 6263 - Exchange Visitor Program-Fees and Charges

    Science.gov (United States)

    2013-01-30

    ... Illegal Immigration Reform and Immigrant Responsibility Act (IIRIRA) of 1996, Pub. L. 104-208, Div. C, 110... Exchange Act of 1961, as amended (Fulbright-Hays Act), 22 U.S.C. 2451 et seq.; the Immigration and...

  13. Charge exchange from D(n=2) atoms to low-Z receiver ions

    NARCIS (Netherlands)

    Hoekstra, R; Anderson, H; Bliek, FW; von Hellermann, M; Maggi, CF; Olson, RE; Summers, HP

    To elucidate the influence on charge-exchange Spectroscopy of metastable deuterium donors, the corresponding cross sections for state-selective charge transfer have been calculated using the classical trajectory Monte Carlo method. The cross sections for electron capture from D(n = 2) by fully

  14. X-ray Signature of Charge Exchange in the Spectra of L-shell Iron Ions

    Energy Technology Data Exchange (ETDEWEB)

    Beiersdorfer, P; Schweikhard, L; Liebisch, P; Brown, G V

    2007-01-05

    The X-ray signature of charge exchange between highly charged L-shell iron ions and neutral gas atoms was studied in the laboratory in order to assess its diagnostic utility. Significant differences with spectra formed by electron-impact excitation were observed. In particular, a strong enhancement was found of the emission corresponding to n {le} 4 {yields} n = 2 transitions relative to the n = 3 {yields} n = 2 emission. This enhancement was detectable even with relatively low-resolution X-ray instrumentation (E/{Delta}E {approx} 10) and may enable future identification of charge exchange as a line-formation mechanism in astrophysical spectra.

  15. Laboratory simulation of charge exchange-produced X-ray emission from comets.

    Science.gov (United States)

    Beiersdorfer, P; Boyce, K R; Brown, G V; Chen, H; Kahn, S M; Kelley, R L; May, M; Olson, R E; Porter, F S; Stahle, C K; Tillotson, W A

    2003-06-06

    In laboratory experiments using the engineering spare microcalorimeter detector from the ASTRO-E satellite mission, we recorded the x-ray emission of highly charged ions of carbon, nitrogen, and oxygen, which simulates charge exchange reactions between heavy ions in the solar wind and neutral gases in cometary comae. The spectra are complex and do not readily match predictions. We developed a charge exchange emission model that successfully reproduces the soft x-ray spectrum of comet Linear C/1999 S4, observed with the Chandra X-ray Observatory.

  16. Line reversal, SU$_{3}, and exchange degeneracy in K$\\pm$N charge exchange at 4 GeV/c

    CERN Document Server

    Elvekjaer, F

    1974-01-01

    The recent data on charge exchange reactions K/sup +/n to K/sup 0/p and K/sup -/p to K/sup 0/n are discussed. The data are shown to be consistent with SU/sub 3/ octet symmetry for helicity flip rho and A /sub 2/ quantum-number exchange. The sizeable breaking of line reversal symmetry is not consistent with the standard model which blames the s-channel helicity-non flip amplitude, while supposing that the flip amplitude is EXD and Regge pole like. A model of alpha broken EXD poles may work for the flip amplitude. (20 refs).

  17. Removal of charged micropollutants from water by ion-exchange polymers -- effects of competing electrolytes.

    Science.gov (United States)

    Bäuerlein, Patrick S; Ter Laak, Thomas L; Hofman-Caris, Roberta C H M; de Voogt, Pim; Droge, Steven T J

    2012-10-15

    A wide variety of environmental compounds of concern, e.g. pharmaceuticals or illicit drugs, are acids or bases that may predominantly be present as charged species in drinking water sources. These charged micropollutants may prove difficult to remove by currently used water treatment steps (e.g. UV/H(2)O(2), activated carbon (AC) or membranes). We studied the sorption affinity of some ionic organic compounds to both AC and different charged polymeric materials. Ion-exchange polymers may be effective as additional extraction phases in water treatment, because sorption of all charged compounds to oppositely charged polymers was stronger than to AC, especially for the double-charged cation metformin. Tested below 1% of the polymer ion-exchange capacity, the sorption affinity of charged micropollutants is nonlinear and depends on the composition of the aqueous medium. Whereas oppositely charged electrolytes do not impact sorption of organic ions, equally charged electrolytes do influence sorption indicating ion-exchange (IE) to be the main sorption mechanism. For the tested polymers, a tenfold increased salt concentration lowered the IE-sorption affinity by a factor two. Different electrolytes affect IE with organic ions in a similar way as inorganic ions on IE-resins, and no clear differences in this trend were observed between the sulphonated and the carboxylated cation-exchanger. Sorption of organic cations is five fold less in Ca(2+) solutions compared to similar concentrations of Na(+), while that of anionic compounds is three fold weaker in SO(4)(2-) solutions compared to equal concentrations of Cl(-). Copyright © 2012 Elsevier Ltd. All rights reserved.

  18. Ion temperatures in HIP-1 and SUMMA from charge-exchange neutral optical emission spectra

    Science.gov (United States)

    Patch, R. W.; Lauver, M. R.

    1976-01-01

    Ion temperatures were obtained from observations of the H sub alpha, D sub alpha, and He 587.6 nm lines emitted from hydrogen, deuterium, and helium plasmas in the SUMMA and HIP-1 mirror devices at Lewis Research Center. Steady state discharges were formed by applying a radially inward dc electric field between cylindrical or annular anodes and hollow cathodes located at the peaks of the mirrors. The ion temperatures were found from the Doppler broadening of the charge-exchange components of spectral lines. A statistical method was developed for obtaining scaling relations of ion temperature as a function of current, voltage, and magnetic flux density. Derivations are given that take into account triangular monochromator slit functions, loss cones, and superimposed charge-exchange processes. In addition, the Doppler broadening was found to be sensitive to the influence of drift on charge-exchange cross section. The effects of finite ion-cyclotron radius, cascading, and delayed emission are reviewed.

  19. Characterization of charge-exchange collisions between ultracold 6Li atoms and 40Ca+ ions

    Science.gov (United States)

    Saito, R.; Haze, S.; Sasakawa, M.; Nakai, R.; Raoult, M.; Da Silva, H.; Dulieu, O.; Mukaiyama, T.

    2017-03-01

    We investigate the energy dependence and the internal-state dependence of the charge-exchange collision cross sections in a mixture of 6Li atoms and 40Ca+ ions. Deliberately excited ion micromotion is used to control collision energy of atoms and ions. The energy dependence of the charge-exchange collision cross section obeys the Langevin model in the temperature range of the current experiment, and the measured magnitude of the cross section is correlated to the internal state of the 40Ca+ ions. Revealing the relationship between the charge-exchange collision cross sections and the interaction potentials is an important step toward the realization of the full quantum control of the chemical reactions at an ultralow-temperature regime.

  20. Charge exchange excitations in N not = Z nuclei: Vlasov and hydrodynamic equations

    Energy Technology Data Exchange (ETDEWEB)

    Lipparini, E.; Stringari, S.

    1987-06-01

    Macroscopic equations of motion for charge exchange reactions in N not = Z nuclei are derived starting from the time dependent Hartree-Fock theory. Application is made to the study of the dipole giant resonance in isospin channels and ..mu..- capture in N not = Z nuclei.

  1. A high etendue spectrometer suitable for core charge eXchange recombination spectroscopy on ITER

    NARCIS (Netherlands)

    Jaspers, R.J.E.; Scheffer, M.; Kappatou, A.; Valk, N.C.J. van der; Durkut, M.; Snijders, B.; Marchuk, O.; Biel, W.; Pokol, G.I.; Erdei, G.; Zoletnik, S.; Dunai, D.

    2012-01-01

    A feasibility study for the use of core charge exchange recombination spectroscopy on ITER has shown that accurate measurements on the helium ash require a spectrometer with a high etendue of 1mm 2sr to comply with the measurement requirements [S. Tugarinov, Rev. Sci. Instrum. 74, 2075

  2. Evidence of electron saddle swap oscillations in angular differential ion-atom charge exchange cross sections

    NARCIS (Netherlands)

    Otranto, S.; Blank, I.; Olson, R. E.; Hoekstra, R.

    2012-01-01

    State selective charge exchange processes in 1-10 keV/amu Ne8+ +Na(3s) collisions were measured by means of the magneto-optical trap recoil-ion momentum spectroscopy technique and compared to classical trajectory Monte Carlo calculations. We find that for electron capture to n-levels >= 10, the

  3. Conceptual design of the ITER upper port plug for charge exchange diagnostic

    NARCIS (Netherlands)

    Sadakov, S.; Baross, T.; Biel, W.; Borsuk, V.; Hawkes, N.; Hellermann, M. von; Gille, P.; Kiss, G.; Koning, J.; Knaup, M.; Klinkhamer, J.F.F.; Krasikov, Yu.; Litnovsky, A.; Neubauer, O.; Panin, A.

    2009-01-01

    A plug for the ITER core charge exchange recombination spectroscopy (core CXRS) is located in the upper port 3. It transfers the light emitted by interaction of plasma ions with the diagnostic neutral beam (DNB). The plug consists of a main shell, a shielding cassette and a retractable tube. The

  4. Pion Double Charge Exchange at 50 MeV on 14C

    Science.gov (United States)

    Navon, I.; Leitch, M. J.; Bryman, D. A.; Numao, T.; Schlatter, P.; Azuelos, G.; Poutissou, R.; Burnham, R. A.; Hasinoff, M.; Poutissou, J. M.; MacDonald, J. A.; Spuller, J. E.; Hargrove, C. K.; Mes, H.; Blecher, M.; Gotow, K.; Moinester, M.; Baer, H.

    1984-01-01

    The first measurement of pion double charge exchange at low energy is reported. The reaction 14C(π+,π-)14O was measured at an incident pion energy of 50 MeV. Differential cross sections of the double analog transition are given in the angular range 50°-120°. Strong nonanalog transitions were also observed.

  5. An Integrated Data Analysis model to determine ion effective charge from beam attenuation and charge exchange emission measurements

    Science.gov (United States)

    Nornberg, M. D.; den Hartog, D. J.; Reusch, L. M.

    2017-10-01

    We have created a forward model for charge-exchange impurity density measurements that incorporates neutral beam attenuation measurements self-consistently for determining the ion effective charge Zeff in MST PPCD plasmas. Detailed knowledge of Zeff is critical to determining the resistive dissipation of hot plasmas and requires knowledge of the impurity content and dynamics. Previously, Zeff profiles were determined from soft-x-ray brightness measurements by using charge-exchange impurity density measurements as prior information using an Integrated Data Analysis (IDA) method. The model is extended to include a self-consistent calculation of the neutral beam attenuation and includes measurements of the beam Doppler-shift spectrum and shine-through particle flux. Methods of experimental design are employed to calculate the information gained from different diagnostic combinations. The analysis shows that while attenuation measurements alone do not provide a unique impurity density measurement in the case of a multi-species inhomogeneous plasmas, they do provide a valuable measurement of the Zeff profile and constrain the range of contributing impurity densities. Supported by US DOE.

  6. Achievement of the charge exchange work diminishing of an internal combustion engine in part load

    Directory of Open Access Journals (Sweden)

    Stefan POSTRZEDNIK

    2012-01-01

    Full Text Available Internal combustion engines, used for driving of different cars, occurs not only at full load, but mostly at the part load. The relative load exchange work at the full (nominal engine load is significantly low. At the part load of the IC engine its energy efficiency ηe is significantly lower than in the optimal (nominal field range of the performance parameters. One of the numerous reasons of this effect is regular growing of the relative load exchange work of the IC engine. It is directly connected with the quantitative regulation method commonly used in the IC engines. From the thermodynamic point of view - the main reason of this effect is the throttling process (causing exergy losses occurring in the inlet and outlet channels. The known proposals for solving of this problem are based on applying of the fully electronic control of the motion of inlet, outlet valves and new reference cycles.The idea presented in the paper leads to diminishing the charge exchange work of the IC engines. The problem can be solved using presented in the paper a new concept of the reference cycle (called as eco-cycle of IC engine. The work of the engine basing on the eco-cycle occurs in two 3-stroke stages; the fresh air is delivered only once for both stages, but in range of each stage a new portion of fuel is burned. Normally the charge exchange occurs once during each engine cycle realized. Elaborated proposition bases on the elimination of chosen charge exchange processes and through this the dropping of the charge exchange work can be achieved.

  7. Transport, charge exchange and loss of energetic heavy ions in the earth's radiation belts - Applicability and limitations of theory

    Science.gov (United States)

    Spjeldvik, W. N.

    1981-01-01

    Computer simulations of processes which control the relative abundances of ions in the trapping regions of geospace are compared with observations from discriminating ion detectors. Energy losses due to Coulomb collisions between ions and exospheric neutrals are considered, along with charge exchange losses and internal charge exchanges. The time evolution of energetic ion fluxes of equatorially mirroring ions under radial diffusion is modelled to include geomagnetic and geoelectric fluctutations. Limits to the validity of diffusion transport theory are discussed, and the simulation is noted to contain provisions for six ionic charge states and the source effect on the radiation belt oxygen ion distributions. Comparisons are made with ion flux data gathered on Explorer 45 and ISEE-1 spacecraft and results indicate that internal charge exchanges cause the radiation belt ion charge state to be independent of source charge rate characteristics, and relative charge state distribution is independent of the radially diffusive transport rate below the charge state redistribution zone.

  8. Anion Exchange Capacity As a Mechanism for Deep Soil Carbon Storage in Variable Charge Soils

    Science.gov (United States)

    Dietzen, C.; James, J. N.; Ciol, M.; Harrison, R. B.

    2014-12-01

    Soil is the most important long-term sink for carbon (C) in terrestrial ecosystems, containing more C than plant biomass and the atmosphere combined. However, soil has historically been under-represented in C cycling literature, especially in regards to information about subsurface (>1.0 m) layers and processes. Previous research has indicated that Andisols with large quantities of noncrystalline, variable-charge minerals, including allophane, imogolite, and ferrihydrite, contain more C both in total and at depth than other soil types in the Pacific Northwest. The electrostatic charge of variable-charge soils depends on pH and is sometimes net positive, particularly in acid conditions, such as those commonly developed under the coniferous forests of the Pacific Northwest. However, even soils with a net negative charge may contain a mixture of negative and positive exchange sites and can hold some nutrient anions through the anion exchange capacity. To increase our understanding of the effects of variable-charge on soil organic matter stabilization, deep sampling is under way at the Fall River Long-Term Soil Productivity Site in western Washington. This site has a deep, well-drained soil with few rocks, which developed from weathered basalt and is classified as an Andisol of the Boistfort Series. Samples have been taken to a depth of 3 m at eight depth intervals. In addition to analyzing total soil C, these soils will be analyzed to determine functional groups present, cation exchange capacity, anion exchange capacity, and non-crystalline mineral content. These data will be analyzed to determine any correlations that may exist between these mineralogical characteristics, total soil C, and types of functional groups stored at depth. The most abundant organic functional groups, including carboxylic and phenolic groups, are anionic in nature, and soil positive charge may play an important role in binding and stabilizing soil organic matter and sequestering C.

  9. Surfactant-mediated ion exchange and charge reversal at ionic liquid interfaces.

    Science.gov (United States)

    Chen, Lang G; Lerum, Ronald V; Aranda-Espinoza, Helim; Bermudez, Harry

    2010-09-09

    Room-temperature ionic liquids (ILs) exhibit a unique set of properties due to their charged character, presenting opportunities for numerous applications. Here, we show that the combination of charged surfactants with ILs leads to rich interfacial behavior due to the interplay between electrostatic and surface forces. Using traditional measures of surface activity and X-ray photoelectron spectroscopy (XPS), we find that sodium alkyl sulfates and alkyl trimethylammonium bromides are, indeed, surface-active at the air-IL interfaces of both [EMIM][EtSO(4)] and [BHEDMA][MeSO(3)]. XPS also reveals that surfactant counterions readily dissociate into the bulk, which when combined with the surfactant surface activity has striking consequences. We find that ion exchange occurs between surfactants and like-charged IL ions, with the greatest exchange for short surfactant alkyl chains. The initial negative surface charge of neat [EMIM][EtSO(4)] can be switched to positive by the addition of alkyl trimethylammonium bromides, with the effect most pronounced at short chain lengths. By contrast, the surface charge of [BHEDMA][MeSO(3)] is largely unaffected by the added surfactants, suggesting a key role for the strength of ion-pairing within the IL. The results here illustrate a simple but effective means of manipulating IL interfacial properties.

  10. The coherent weak flavour charge of ordinary matter for neutrino-exchange forces

    Science.gov (United States)

    Segarra, Alejandro

    2017-09-01

    We study the long-range force arising between two aggregates of ordinary matter due to a neutrino-pair exchange, in the limit of zero neutrino mass. Even if matter is neutral of electric charge, it is charged for this weak force. The interaction is described in terms of a coherent charge, which we call the weak flavour charge of aggregated matter. For each one of the interacting aggregates, this charge depends on the neutrino flavour as Q_W{ν _e} = 2Z - N,Q_W{ν _μ } = Q_W{ν _τ } = - N, where Z is the number of protons and N the number of neutrons. Q_W{ν _e} depends explicitly on Z because of the charged current contribution to νee elastic scattering, while the N term in the three charges comes from the universal neutral current contribution. The effective potential describing this force is repulsive and decreases as r -5. Due to its specific behaviour on (Z, N) and r, this interaction is distinguishable from both gravitation and residual electromagnetic forces. As neutrinos are massive and mixed, this potential is valid for r ≲ 1/mν .

  11. ROSAT Observations of Solar Wind Charge Exchange with the Lunar Exosphere

    Science.gov (United States)

    Collier, Michael R.; Snowden, S. L.; Benna, M.; Carter, J. A.; Cravens, T. E.; Hills, H. Kent; Hodges, R. R.; Kuntz, K. D.; Porter, F. Scott; Read, A.; hide

    2012-01-01

    We analyze the ROSAT PSPC soft X-ray image of the Moon taken on 29 June 1990 by examining the radial profile of the count rate in three wedges, two wedges (one north and one south) 13-32 degrees off (19 degrees wide) the terminator towards the dark side and one wedge 38 degrees wide centered on the anti-solar direction. The radial profiles of both the north and the south wedges show substantial limb brightening that is absent in the 38 degree wide antisolar wedge. An analysis of the count rate increase associated with the limb brightening shows that its magnitude is consistent with that expected due to solar wind charge exchange (SWCX) with the tenuous lunar atmosphere. Along with Mars, Venus, and Earth, the Moon represents another solar system body at which solar wind charge exchange has been observed. This technique can be used to explore the solar wind-lunar interaction.

  12. Analysing powers and spin correlations in deuteron–proton charge exchange at 726 MeV

    Directory of Open Access Journals (Sweden)

    S. Dymov

    2015-05-01

    Full Text Available The charge exchange of vector polarised deuterons on a polarised hydrogen target has been studied in a high statistics experiment at the COSY-ANKE facility at a deuteron beam energy of Td=726 MeV. By selecting two fast protons at low relative energy Epp, the measured analysing powers and spin correlations are sensitive to interference terms between specific neutron–proton charge-exchange amplitudes at a neutron kinetic energy of Tn≈12Td=363 MeV. An impulse approximation calculation, which takes into account corrections due to the angular distribution in the diproton, describes reasonably the dependence of the data on both Epp and the momentum transfer. This lends broad support to the current neutron–proton partial wave solution that was used in the estimation.

  13. Charge-Exchange Neutral Particle Analyzer Diagnostic of TJ-II

    Energy Technology Data Exchange (ETDEWEB)

    Fontdecaba, J. M.; Balbin, R.; Petrov, S.; TJ-II team

    2003-07-01

    A description of the Charge Exchange Neutral Particle Analyzers in operation in the heliac flexible TJ-II is reported. A description of the detectors, as well as the operation characteristics, hardware and software used in the control and analysis of the data obtained with the diagnostic is detailed. Two NPAs are in operation in TJ-II. One of them is a 5-channel analyzer and another one is an Acord-12. The 5-channel analyzer provides measurements of charge exchange neutral fluxes at five energy channels, whereas the Acord-12 can measure simultaneously two different hydrogen isotopes (H and D) at six energy channels. Their lines of sight can be varied poloidally in order to observe the different sections of the plasma. (Author) 10 refs.

  14. Charge exchange contamination of CRIT-II barium CIV experiment. [critical ionization velocity in ionosphere

    Science.gov (United States)

    Swenson, G. R.; Mende, S. B.; Meyerott, R. E.; Rairden, R. L.

    1991-01-01

    Experiments have been recently performed which attempted to confirm critical ionization velocity (CIV) ionization by deploying chemicals at high velocity in the ionosphere. Specifically, the CRIT-II rocket performed a barium release in the ionosphere, where observations of Ba(+) resonant emissions following the release are believed to have resulted from the CIV process. Calculations are presented which suggest a significant fraction (if not all) of the Ba(+) observed likely resulted from charge exchange with the thermosphere ions and not through CIV processes. The results presented here are pertinent to other CIV experiments performed in the ionosphere. It is recommended that laboratory measurements should be made of the charge exchange cross section between O(+) and Ba as well as other metal vapors used in CIV experiments.

  15. Simulation of charge exchange neutrals interactions with gaps in first wall cladding

    Energy Technology Data Exchange (ETDEWEB)

    Kurnaev, V.A. [Moscow Engineering and Physics Institute, Kashirskoe sh. 31, 115409 Moscow (Russian Federation)]. E-mail: kurnaev@plasma.mephi.ru; Matveev, D.I. [Moscow Engineering and Physics Institute, Kashirskoe sh. 31, 115409 Moscow (Russian Federation); Trifonov, N.N. [Moscow Engineering and Physics Institute, Kashirskoe sh. 31, 115409 Moscow (Russian Federation)

    2007-06-15

    Angular distributions of particles impinging PFC in fusion devices with magnetic confinement are briefly discussed. It is shown that simulation of charge exchange neutrals interaction with the first wall should be made for inclined incidence of particles. Particle reflection coefficients and sputtering yields for gaps in Be, C and W first wall cladding are found with Monte Carlo computer simulations for hydrogen isotopes in the energy range {approx}5-5 x 10{sup 3} eV as well as for the flux integrated over the ITER charge exchange neutrals energy spectrum. Trapping of deuterons by the gap in the W wall increases two times (up to {approx}0.6) as compared with the flat surface, while trapping in the Be gap is close to unity. The influence of isotope mass on trapping and sputtering is shown to follow data for the flat surface. Roughness of gap sidewalls taken into account slightly contributes to calculated data.

  16. Measurement of charge exchange cross sections for highly charged xenon and thorium ions with molecular hydrogen in a Penning Ion Trap

    Energy Technology Data Exchange (ETDEWEB)

    Weinberg, G.M.

    1995-12-01

    Highly charged xenon (35+ to 46+) and thorium (72+ to 79+) ions were produced in an Electron Beam Ion Trap (EBIT). The ions were extracted from EBIT in a short pulse. Ions of one charge state were selected using an electromagnet. The ions were recaptured at low energy in a cryogenic Penning trap (RETRAP). As the ions captured electrons from molecular hydrogen, populations of the various charge states were obtained by measuring the image currents induced by the ions on the electrodes of the trap. Data on the number of ions in each charge state vs. time were compared to theoretical rate equations in order to determine the average charge exchange rates. These rates were compared to charge exchange rates of an ion with a known charge exchange cross section (Ar{sup 11+}) measured in a similar manner in order to determine the average charge exchange cross sections for the highly charged ions. The energy of interaction between the highly charged ions and hydrogen was estimated to be 4 eV in the center of mass frame. The mean charge exchange cross sections were 9 {times} 10{sup {minus}14} cm{sup 2} for Xe{sup 43+} to Xe{sup 46+} and 2 {times} 10{sup {minus}13} cm{sup 2} for Th{sup 73+} to Th{sup 79+}. Double capture was approximately 20--25% of the total for both xenon and thorium. A fit indicated that the cross sections were approximately proportional to q. This is consistent with a linear dependence of cross section on q within the measurement uncertainties.

  17. Macroscopic models for charge exchange reactions in N not = Z nuclei

    Energy Technology Data Exchange (ETDEWEB)

    Stringari, S.; Lipparini, E.

    1987-10-19

    Vlasov equations in the isospin channels are derived in the framework of the time dependent Hartree-Fock theory. The local equilibrium (hydrodynamic) approximation is then considered and applied to study isovector giant resonances excited in charge exchange reactions and ..mu../sup -/ inclusive capture in N not = Z nuclei. The theoretical predictions well account for the observed energy splitting between different isospin fragments and for the quenching of the ..delta..T/sub Z/ = +1 strength.

  18. Pion double charge exchange at 50 MeV on /sup 14/C

    Energy Technology Data Exchange (ETDEWEB)

    Navon, I.; Leitch, M.J.; Bryman, D.A.; Numao, T.; Schlatter, P.; Azuelos, G.; Poutissou, R.; Burnham, R.A.; Hasinoff, M.; Poutissou, J.M.

    1984-01-09

    The first measurement of pion double charge exchange at low energy is reported. The reaction /sup 14/C(..pi../sup +/,..pi../sup -/) /sup 14/O was measured at an incident pion energy of 50 MeV. Differential cross sections of the double analog transition are given in the angular range 50/sup 0/--120/sup 0/. Strong nonanalog transitions were also observed.

  19. USING KAPPA FUNCTIONS TO CHARACTERIZE OUTER HELIOSPHERE PROTON DISTRIBUTIONS IN THE PRESENCE OF CHARGE-EXCHANGE

    Energy Technology Data Exchange (ETDEWEB)

    Zirnstein, E. J.; McComas, D. J., E-mail: ezirnstein@swri.edu, E-mail: dmccomas@swri.edu [Southwest Research Institute, San Antonio, TX 78228 (United States)

    2015-12-10

    Kappa functions have long been used in the analysis and modeling of suprathermal particles in various space plasmas. In situ observations of the supersonic solar wind show its distribution contains a cold ion core and power-law tail, which is well-represented by a kappa function. In situ plasma observations by Voyager, as well as observations of energetic neutral atom (ENA) spectra by the Interstellar Boundary Explorer (IBEX), showed that the compressed and heated inner heliosheath (IHS) plasma beyond the termination shock can also be represented by a kappa function. IBEX exposes the IHS plasma properties through the detection of ENAs generated by charge-exchange in the IHS. However, charge-exchange modifies the plasma as it flows through the IHS, and makes it difficult to ascertain the parent proton distribution. In this paper we investigate the evolution of proton distributions, initially represented by a kappa function, that experience losses due to charge-exchange in the IHS. In the absence of other processes, it is no longer representable by a single kappa function due to the energy-dependent, charge-exchange process. While one can still fit a kappa function to the evolving proton distribution over limited energy ranges, this yields fitting parameters (pseudo-density, pseudo-temperature, pseudo-kappa index) that depend on the energy range of the fit. We discuss the effects of fitting a kappa function to the IHS proton distribution over limited energy ranges, its dependence on the initial proton distribution properties at the termination shock, and implications for understanding the observations.

  20. Moving Towards a State of the Art Charge-Exchange Reaction Code

    Science.gov (United States)

    Poxon-Pearson, Terri; Nunes, Filomena; Potel, Gregory

    2017-09-01

    Charge-exchange reactions have a wide range of applications, including late stellar evolution, constraining the matrix elements for neutrinoless double β-decay, and exploring symmetry energy and other aspects of exotic nuclear matter. Still, much of the reaction theory needed to describe these transitions is underdeveloped and relies on assumptions and simplifications that are often extended outside of their region of validity. In this work, we have begun to move towards a state of the art charge-exchange reaction code. As a first step, we focus on Fermi transitions using a Lane potential in a few body, Distorted Wave Born Approximation (DWBA) framework. We have focused on maintaining a modular structure for the code so we can later incorporate complications such as nonlocality, breakup, and microscopic inputs. Results using this new charge-exchange code will be shown compared to the analysis in for the case of 48Ca(p,n)48Sc. This work was supported in part by the National Nuclear Security Administration under the Stewardship Science Academic Alliances program through the U.S. DOE Cooperative Agreement No. DE- FG52-08NA2855.

  1. The role of electron capture and energy exchange of positively charged particles passing through matter

    CERN Document Server

    Ulmer, W

    2011-01-01

    The conventional treatment of the Bethe-Bloch equation for protons accounts for electron capture at the end of the projectile track by the small Barkas correction. This is only a possible way for protons, whereas for light and heavier charged nuclei the exchange of energy and charge along the track has to be accounted for by regarding the projectile charge q as a function of the residual energy. This leads to a significant modification of the Bethe-Bloch equation, otherwise the range in a medium is incorrectly determined. The LET in the Bragg peak domain and distal end is significantly influenced by the electron capture. A rather significant result is that in the domain of the Bragg peak the superiority of carbon ions is reduced compared to protons.

  2. Performance of the CERN PSB at 160 MeV with $H^{-}$ charge exchange injection

    CERN Document Server

    AUTHOR|(CDS)2084247; Santoni, Claudio

    As part of the LHC Injectors Upgrade Project, the CERN PS Booster (PSB) will be upgraded with a H- charge exchange injection system and its injection energy will be raised from 50 MeV to 160 MeV to obtain the beam brightness required for the LHC High-Luminosity Upgrade. Space charge effects like beam losses and transverse emittance blow-up at injection are expected to be the main limitations towards the achievement of the required high brightness. Studies of beam dynamics in presence of space charge in order to evaluate the performances of the PSB after the Upgrade have been performed. The first part of the work consists of measurements in the present machine, to study the effects of space charge and its interplay with resonances and to have a good set of data for code benchmarking. The code chosen for the beam tracking in presence of space charge is PTC-Orbit (and PyOrbit). Necessary numerical convergence studies are presented together with a benchmark with the PSB measurements. Once assessed the code and it...

  3. The charge-exchange induced coupling between plasma-gas counterflows in the heliosheath

    Directory of Open Access Journals (Sweden)

    H. J. Fahr

    2003-06-01

    Full Text Available Many hydrodynamic models have been presented which give similar views of the interaction of the solar wind plasma bubble with the counterstreaming partially ionized interstellar medium. In the more recent of these models it is taken into account that the solar and interstellar hydrodynamic flows of neutral atoms and protons are coupled by mass-, momentum-, and energy-exchange terms due to charge exchange processes. We shall reinvestigate the theoretical basis of this coupling here by use of a simplified description of the heliospheric interface and describe the main physics of the H-atom penetration through the more or less standing well-known plasma wall ahead of the heliopause. Thereby we can show that the type of charge exchange coupling terms used in up-to-now hydrodynamic treatments unavoidably leads to an O-type critical point at the sonic point of the H-atom flow, thus not allowing for a continuation of the integration of the hydrodynamic set of differential equations. The remedy for this problem is given by a more accurate formulation of the momentum exchange term for quasi-and sub-sonic H-atom flows. With a refined momentum exchange term derived from basic kinetic Boltzmann principles, we instead arrive at a characteristic equation with an X-type critical point, allowing for a continuous solution from supersonic to subsonic flow conditions. This necessitates that the often treated problem of the propagation of inter-stellar H-atoms through the heliosheath has to be solved using these newly derived, differently effective plasma – gas friction forces. Substantially different results are to be expected from this context for the filtration efficiency of the heliospheric interface.Key words. Interplanetary physics (heliopause and solar wind termination; interstellar gas – Ionosphere (plasma temperature and density

  4. The charge-exchange induced coupling between plasma-gas counterflows in the heliosheath

    Directory of Open Access Journals (Sweden)

    H. J. Fahr

    Full Text Available Many hydrodynamic models have been presented which give similar views of the interaction of the solar wind plasma bubble with the counterstreaming partially ionized interstellar medium. In the more recent of these models it is taken into account that the solar and interstellar hydrodynamic flows of neutral atoms and protons are coupled by mass-, momentum-, and energy-exchange terms due to charge exchange processes. We shall reinvestigate the theoretical basis of this coupling here by use of a simplified description of the heliospheric interface and describe the main physics of the H-atom penetration through the more or less standing well-known plasma wall ahead of the heliopause. Thereby we can show that the type of charge exchange coupling terms used in up-to-now hydrodynamic treatments unavoidably leads to an O-type critical point at the sonic point of the H-atom flow, thus not allowing for a continuation of the integration of the hydrodynamic set of differential equations. The remedy for this problem is given by a more accurate formulation of the momentum exchange term for quasi-and sub-sonic H-atom flows. With a refined momentum exchange term derived from basic kinetic Boltzmann principles, we instead arrive at a characteristic equation with an X-type critical point, allowing for a continuous solution from supersonic to subsonic flow conditions. This necessitates that the often treated problem of the propagation of inter-stellar H-atoms through the heliosheath has to be solved using these newly derived, differently effective plasma – gas friction forces. Substantially different results are to be expected from this context for the filtration efficiency of the heliospheric interface.

    Key words. Interplanetary physics (heliopause and solar wind termination; interstellar gas – Ionosphere (plasma temperature and density

  5. Development of Laboratory Experimental System to Clarify Solar Wind Charge Exchange Mechanism with TES Microcalorimeter

    Science.gov (United States)

    Enoki, T.; Ishisaki, Y.; Akamatsu, H.; Ezoe, Y.; Ohashi, T.; Kanda, T.; Ishida, T.; Tanuma, H.; Ohashi, H.; Shinozaki, K.; Mitsuda, K.

    2012-06-01

    Significant fraction of the cosmic diffuse soft X-ray emission (0.1-1 keV) is caused by the Solar Wind Charge eXchange (SWCX) process between the solar wind ion (C q+, N q+, O q+ etc.) and the interplanetary neutral matter. It is difficult to identify spectral features of SWCX with the spectral resolution of existing X-ray astronomy satellites. We are developing a laboratory experimental system with transition edge sensor (TES) X-ray microcalorimeters, in order to clarify the SWCX mechanism. This experiment is designed to measure Charge eXchange (CX) X-rays using Electron Cyclotron Resonance Ion Source (ECRIS) that generates multi-charged ions. Emission lines (OVIII: 2p→1s; 654 eV) by CX between O8+ and neutral He atom is aimed to be measured with energy resolution better than 10 eV. The TES microcalorimeter is cooled by a double-stage adiabatic demagnetization refrigerator (DADR), however, our TES microcalorimeter are not working potentially due to magnetic field contamination. This paper reports our experimental system, present results, and future prospects.

  6. Development of two-grating spectrometer for the charge exchange spectroscopy system on KSTAR

    Science.gov (United States)

    Lee, Hyungho; Song, Eun-ji; Park, Young-dong; Oh, Soo-ghee; Ko, Won-Ha

    2011-06-01

    The charge exchange spectroscopy (CES) system on Korea Superconducting Tokamak Advanced Research (KSTAR) was installed last year and had been applied to measure the C VI ion temperature and rotation velocity profiles. The ion temperature and rotation velocity profiles had been estimated from the C VI 5290.5 Å (n = 8-7) charge-exchange spectrum signal measured by a Czerny-Turner type spectrometer and a thinned back-illuminated charge coupled device (CCD) camera. However, the Czerny-Turner type spectrometer used for the KSTAR CES system showed so low signal to noise ratio for KSTAR plasmas in the 2010 experimental campaign that the time resolution of the CES system had been limited to 100 ms due to the increased exposure time of the attached CCD camera. Then, new two-grating spectrometer had been developed in order to improve the time resolution of the CES system. The spectrometer consists of two gratings (1200 g/mm and 1800 g/mm each) with additive configuration, concave mirrors (f = 50 cm), and a cylindrical lens (f = 50 cm). The time resolution of the CES system increases by a factor of 2-4 with the two-grating spectrometer. The C VI ion temperature and rotation velocity profiles obtained by the two-grating spectrometer are compared to those by Czerny-Turner type spectrometer in this paper.

  7. Cometary X-rays. Solar wind charge exchange in cometary atmospheres

    Science.gov (United States)

    Bodewits, Dennis

    2007-06-01

    The interaction of the solar wind with the planets and the interstellar medium is of key importance for the evolution of our solar system. The interaction with Earth's atmosphere is best known for the northern light. In case of Mars, the interaction with the solar wind might have lead to the erosion of its atmosphere. Solar wind-atmosphere interactions can be studied particularly well in cometary atmospheres, because in that case the solar wind flow is not attenuated by a planetary magnetic field and interacts directly with its atmosphere, the coma. The size of the cometary atmosphere (in the order of 10(4-10^5) km) allows remote tracking of the ions as they penetrate into the comet's atmosphere, offering a unique window on the cometary atmosphere, the solar wind and the interaction of these two plasmas. When solar wind ions fly through an atmosphere they are neutralized via charge exchange reactions with the neutral gaseous species. These reactions depend strongly on target species and collision velocity. The resulting X-ray and Far-UV emission can therefore be regarded as a fingerprint of the underlying reaction, with many diagnostic qualities. My thesis studies have focussed on all aspects relevant for X-ray emission from comets: experimental studies of state-to-state charge exchange cross sections, observations of X-ray emission from comets with Chandra, XMM, and Swift, and theoretical modelling of the interaction of solar wind ions with cometary gasses and the resulting X-ray emission spectrum. Together, this has greatly improved our understanding of the interaction of the solar wind with solar system objects and in more general, of physical processes in wind-environment collisions. The thorough understanding of cometary charge exchange emission has opened the door to the direct observation of more complex solar wind interactions such as those with Mars and Venus.

  8. Correlation between charge transfer and exchange coupling in carbon-based magnetic materials

    Energy Technology Data Exchange (ETDEWEB)

    Nguyen, Anh Tuan, E-mail: tuanna@hus.edu.vn [Faculty of Physics, VNU University of Science, 334 Nguyen Trai, Thanh Xuan, Ha Noi (Viet Nam); Science and Technology Department, Vietnam National University, Hanoi, 144 Xuan Thuy, Cau Giay, Hanoi (Viet Nam); Japan Advanced Institute of Science and Technology, 1-1, Asahidai, Nomi, Ishikawa, 923-1292 Japan (Japan); Nguyen, Van Thanh; Nguyen, Huy Sinh [Faculty of Physics, VNU University of Science, 334 Nguyen Trai, Thanh Xuan, Ha Noi (Viet Nam); Pham, Thi Tuan Anh [Faculty of Physics, VNU University of Science, 334 Nguyen Trai, Thanh Xuan, Ha Noi (Viet Nam); Faculty of Science, College of Hai Duong, Nguyen Thi Due, Hai Duong (Viet Nam); Do, Viet Thang [Faculty of Physics, VNU University of Science, 334 Nguyen Trai, Thanh Xuan, Ha Noi (Viet Nam); Faculty of Science, Haiphong University, 171 Phan Dang Luu, Kien An, Hai Phong (Viet Nam); Dam, Hieu Chi [Japan Advanced Institute of Science and Technology, 1-1, Asahidai, Nomi, Ishikawa, 923-1292 Japan (Japan)

    2015-10-15

    Several forms of carbon-based magnetic materials, i.e. single radicals, radical dimers, and alternating stacks of radicals and diamagnetic molecules, have been investigated using density-functional theory with dispersion correction and full geometry optimization. Our calculated results demonstrate that the C{sub 31}H{sub 15} (R{sub 4}) radical has a spin of ½. However, in its [R{sub 4}]{sub 2} dimer structure, the net spin becomes zero due to antiferromagnetic spin-exchange between radicals. To avoid antiferromagnetic spin-exchange of identical face-to-face radicals, eight alternating stacks, R{sub 4}/D{sub 2m}/R{sub 4} (with m = 3-10), were designed. Our calculated results show that charge transfer (Δn) between R{sub 4} radicals and the diamagnetic molecule D{sub 2m} occurs with a mechanism of spin exchange (J) in stacks. The more electrons that transfer from R{sub 4} to D{sub 2m}, the stronger the ferromagnetic spin-exchange in stacks. In addition, our calculated results show that Δn can be tailored by adjusting the electron affinity (E{sub a}) of D{sub 2m}. The correlation between Δn, E{sub a}, m, and J is discussed. These results give some hints for the design of new ferromagnetic carbon-based materials.

  9. Correlation between charge transfer and exchange coupling in carbon-based magnetic materials

    Directory of Open Access Journals (Sweden)

    Anh Tuan Nguyen

    2015-10-01

    Full Text Available Several forms of carbon-based magnetic materials, i.e. single radicals, radical dimers, and alternating stacks of radicals and diamagnetic molecules, have been investigated using density-functional theory with dispersion correction and full geometry optimization. Our calculated results demonstrate that the C31H15 (R4 radical has a spin of ½. However, in its [R4]2 dimer structure, the net spin becomes zero due to antiferromagnetic spin-exchange between radicals. To avoid antiferromagnetic spin-exchange of identical face-to-face radicals, eight alternating stacks, R4/D2m/R4 (with m = 3-10, were designed. Our calculated results show that charge transfer (Δn between R4 radicals and the diamagnetic molecule D2m occurs with a mechanism of spin exchange (J in stacks. The more electrons that transfer from R4 to D2m, the stronger the ferromagnetic spin-exchange in stacks. In addition, our calculated results show that Δn can be tailored by adjusting the electron affinity (Ea of D2m. The correlation between Δn, Ea, m, and J is discussed. These results give some hints for the design of new ferromagnetic carbon-based materials.

  10. Phenomenological characteristics of absorption in charge- and hypercharge-exchange reactions

    CERN Document Server

    Sadoulet, B

    1973-01-01

    The author tries to explain in a unique framework charge- and hypercharge-exchange reactions above 3 GeV/c. His approach is based on exchange degenerate and SU(3) symmetric Regge poles to which absorption corrections are applied. In the absence of a firm theoretical basis for the corrections he adopts the approach of fixing the Regge poles through theoretical and phenomenological considerations; he then determines what kind of absorption he should apply. At intermediate energy (around 5 GeV/c) his results indicate complete absorption of the s-wave amplitude. Of the two terms 1 and e /sup -i pi alpha / of the Regge signature factor, the latter should be more strongly absorbed. This effect may explain especially the breaking of line-reversal symmetry for hypercharge-exchange reactions, pi /sup -/p to pi /sup 0/n polarization data, and the difference of peripherality of rho - omega and A/sub 2/-f/sub 0/ contributions. In addition, K-exchange in pp to Lambda Lambda has been studied. (50 refs).

  11. Observation of large enhancements of charge exchange cross sections with neutron-rich carbon isotopes

    Science.gov (United States)

    Tanihata, I.; Terashima, S.; Kanungo, R.; Ameil, F.; Atkinson, J.; Ayyad, Y.; Cortina-Gil, D.; Dillmann, I.; Estradé, A.; Evdokimov, A.; Farinon, F.; Geissel, H.; Guastalla, G.; Janik, R.; Knoebel, R.; Kurcewicz, J.; Litvinov, Yu. A.; Marta, M.; Mostazo, M.; Mukha, I.; Nociforo, C.; Ong, H. J.; Pietri, S.; Prochazka, A.; Scheidenberger, C.; Sitar, B.; Strmen, P.; Takechi, M.; Tanaka, J.; Toki, H.; Vargas, J.; Winfield, J. S.; Weick, H.

    2016-04-01

    Production cross sections of nitrogen isotopes from high-energy (˜ 950 MeV per nucleon) carbon isotopes on hydrogen and carbon targets have been measured for the first time for a wide range of isotopes (A = 12 to 19). The fragment separator FRS at GSI was used to deliver C-isotope beams. The cross sections of the production of N-isotopes were determined by charge measurements of forward-going fragments. The cross sections show a rapid increase with the number of neutrons in the projectile. Since the production of nitrogen is mostly due to charge-exchange (Cex) reactions below the proton separation energies, the present data suggests a concentration of Gamow-Teller and/or Fermi transition strength at low excitation energies for neutron-rich carbon isotopes. It was also observed that the Cex cross sections were enhanced much more strongly for neutron-rich isotopes in the C-target data.

  12. Molecular (Feshbach) treatment of charge exchange Li/sup 3 +/+He collisions. II. Cross sections

    Energy Technology Data Exchange (ETDEWEB)

    Errea, L.F.; Martin, F.; Mendez, L.; Riera, A.; Yanez, M.

    1986-05-15

    Using the wave functions calculated in the preceding article, and a common translation factor, the charge exchange cross section for the Li/sup 3 +/+He(1s/sup 2/) reaction is calculated, and the mechanism of the process discussed. We show how small deviations from the Landau--Zener model, which are unrelated to Nikitin's conditions for its validity, lead to a minimum of the cross section at an impact energy Eapprox. =1 keV, and to larger values of sigma at intermediate nuclear velocities.

  13. Towards hot electron mediated charge exchange in hyperthermal energy ion-surface interactions

    DEFF Research Database (Denmark)

    Ray, M. P.; Lake, R. E.; Thomsen, Lasse Bjørchmar

    2010-01-01

    We have made Na + and He + ions incident on the surface of solid state tunnel junctions and measured the energy loss due to atomic displacement and electronic excitations. Each tunnel junction consists of an ultrathin film metal–oxide–semiconductor device which can be biased to create a band of hot...... shows that the primary energy loss mechanism is the atomic displacement of Au atoms in the thin film of the metal–oxide–semiconductor device. We propose that neutral particle detection of the scattered flux from a biased device could be a route to hot electron mediated charge exchange....

  14. Excitation of Nucleon Resonances in Heavy-Ion Charge-Exchange Reactions

    Science.gov (United States)

    Benlliure, J.; Vargas, J.; Alvarez-Pol, H.; Aumann, T.; Atkinson, J.; Ayyad, Y.; Beceiro, S.; Borezky, K.; Chatillon, A.; Cortina, D.; Diaz, P.; Estrade, A.; Geissel, H.; Lenske, H.; Litvinov, Y.; Mostazo, M.; Paradela, C.; Pietri, S.; Prochazka, A.; Taieb, J.; Takechi, M.; Vidaña, I.; Weick, H.; Winfield, J.

    Isobaric charge-exchange reactions induced by different tin isotopes have been investigated at GSI. The high-resolving power of the FRS spectrometer made it possible to separate elastic and inelastic components in the missing-energy spectra of the ejectiles. The inelastic component was associated to the in-medium excitation of nucleon resonances such as the Delta and Roper resonances. These data are expected to contribute to better understand the role of subnuclear degrees of freedom in three body forces or the missing strength in Gamow-Teller transitions but also to investigate the abundance of protons and neutrons at the nuclear periphery.

  15. High resolution probe of coherence in low-energy charge exchange collisions with oriented targets

    CERN Document Server

    Leredde, A; Cassimi, A; Hennecart, D; Pons, B

    2013-01-01

    The trapping lasers of a magneto-optical trap (MOT) are used to bring Rb atoms into well defined oriented states. Coupled to recoil-ion momentum spectroscopy (RIMS), this yields a unique MOTRIMS setup which is able to probe scattering dynamics, including their coherence features, with unprecedented resolution. This technique is applied to the low-energy charge exchange processes Na$^+$+Rb($5p_{\\pm 1}$) $\\rightarrow$ Na($3p,4s$)+Rb$^+$. The measurements reveal detailed features of the collisional interaction which are employed to improve the theoretical description. All of this enables to gauge the reliability of intuitive pictures predicting the most likely capture transitions.

  16. A high etendue spectrometer suitable for core charge eXchange recombination spectroscopy on ITER

    Energy Technology Data Exchange (ETDEWEB)

    Jaspers, R. J. E.; Scheffer, M. [Science and Technology of Nuclear Fusion, Eindhoven University of Technology, Eindhoven (Netherlands); Kappatou, A. [FOM Institute DIFFER - Dutch Institute for Fundamental Energy Research, Association EURATOM-FOM, Nieuwegein (Netherlands); Valk, N. C. J. van der; Durkut, M.; Snijders, B. [TNO Science and Industry, P.O. Box 155, 2600 AD Delft (Netherlands); Marchuk, O.; Biel, W. [Institut fuer Energie und Klimaforschung-IEK-4 Forschungszentrum, Juelich GmbH, 52425 Juelich (Germany); Pokol, G. I. [Institute of Nuclear Techniques, Budapest University of Technology and Economics, EURATOM Association, P. O. Box 91, H-1521 Budapest (Hungary); Erdei, G. [Department of Atomic Physics, Budapest University of Technology and Economics, EURATOM Association, P. O. Box 91, H-1521 Budapest (Hungary); Zoletnik, S.; Dunai, D. [WIGNER RCP, RMKI, EURATOM Association, P. O. Box 91, H-1521 Budapest (Hungary)

    2012-10-15

    A feasibility study for the use of core charge exchange recombination spectroscopy on ITER has shown that accurate measurements on the helium ash require a spectrometer with a high etendue of 1mm{sup 2}sr to comply with the measurement requirements [S. Tugarinov et al., Rev. Sci. Instrum. 74, 2075 (2003)]. To this purpose such an instrument has been developed consisting of three separate wavelength channels (to measure simultaneously He/Be, C/Ne, and H/D/T together with the Doppler shifted direct emission of the diagnostic neutral beam, the beam emission (BES) signal), combining high dispersion (0.02 nm/pixel), sufficient resolution (0.2 nm), high efficiency (55%), and extended wavelength range (14 nm) at high etendue. The combined measurement of the BES along the same sightline within a third wavelength range provides the possibility for in situ calibration of the charge eXchange recombination spectroscopy signals. In addition, the option is included to use the same instrument for measurements of the fast fluctuations of the beam emission intensity up to 2 MHz, with the aim to study MHD activity.

  17. Cold neutral atoms via charge exchange from excited state positronium: a proposal

    CERN Document Server

    Bertsche, W A; Eriksson, S

    2016-01-01

    We present a method for generating cold neutral atoms via charge exchange reactions between trapped ions and Rydberg positronium. The high charge exchange reaction cross section leads to efficient neutralisation of the ions and since the positronium-ion mass ratio is small, the neutrals do not gain appreciable kinetic energy in the process. When the original ions are cold the reaction produces neutrals that can be trapped or further manipulated with electromagnetic fields. Because a wide range of species can be targeted we envisage that our scheme may enable experiments at low temperature that have been hitherto intractable due to a lack of cooling methods. We present an estimate for achievable temperatures, neutral number and density in an experiment where the neutrals are formed at a milli-Kelvin temperature from either directly or sympathetically cooled ions confined on an ion chip. The neutrals may then be confined by their magnetic moment in a co-located magnetic minimum well also formed on the chip. We ...

  18. First measurement of the edge charge exchange recombination spectroscopy on EAST tokamak

    Energy Technology Data Exchange (ETDEWEB)

    Li, Y. Y., E-mail: liyy@ipp.ac.cn; Fu, J.; Jiang, D.; Lyu, B.; Hu, C. D.; Wan, B. N. [Institute of Plasma Physics, Chinese Academy of Sciences, Hefei (China); Yin, X. H.; Feng, S. Y. [Institute of Plasma Physics, Chinese Academy of Sciences, Hefei (China); School of Nuclear Science and Technology, University of Science and Technology of China, Hefei (China); Shi, Y. J. [School of Nuclear Science and Technology, University of Science and Technology of China, Hefei (China); Department of Nuclear Engineering, Seoul National University, Seoul 151-742 (Korea, Republic of); Yi, Y.; Ye, M. Y. [School of Nuclear Science and Technology, University of Science and Technology of China, Hefei (China); Zhou, X. J. [Anhui Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Hefei 230031 (China)

    2016-11-15

    An edge toroidal charge exchange recombination spectroscopy (eCXRS) diagnostic, based on a heating neutral beam injection (NBI), has been deployed recently on the Experimental Advanced Superconducting Tokamak (EAST). The eCXRS, which aims to measure the plasma ion temperature and toroidal rotation velocity in the edge region simultaneously, is a complement to the exiting core CXRS (cCXRS). Two rows with 32 fiber channels each cover a radial range from ∼2.15 m to ∼2.32 m with a high spatial resolution of ∼5-7 mm. Charge exchange emission of Carbon VI CVI at 529.059 nm induced by the NBI is routinely observed, but can be tuned to any interested wavelength in the spectral range from 400 to 700 nm. Double-slit fiber bundles increase the number of channels, the fibers viewing the same radial position are binned on the CCD detector to improve the signal-to-noise ratio, enabling shorter exposure time down to 5 ms. One channel is connected to a neon lamp, which provides the real-time wavelength calibration on a shot-to-shot basis. In this paper, an overview of the eCXRS diagnostic on EAST is presented and the first results from the 2015 experimental campaign will be shown. Good agreements in ion temperature and toroidal rotation are obtained between the eCXRS and cCXRS systems.

  19. A high etendue spectrometer suitable for core charge eXchange recombination spectroscopy on ITERa)

    Science.gov (United States)

    Jaspers, R. J. E.; Scheffer, M.; Kappatou, A.; van der Valk, N. C. J.; Durkut, M.; Snijders, B.; Marchuk, O.; Biel, W.; Pokol, G. I.; Erdei, G.; Zoletnik, S.; Dunai, D.

    2012-10-01

    A feasibility study for the use of core charge exchange recombination spectroscopy on ITER has shown that accurate measurements on the helium ash require a spectrometer with a high etendue of 1mm2sr to comply with the measurement requirements [S. Tugarinov et al., Rev. Sci. Instrum. 74, 2075 (2003)], 10.1063/1.1537443. To this purpose such an instrument has been developed consisting of three separate wavelength channels (to measure simultaneously He/Be, C/Ne, and H/D/T together with the Doppler shifted direct emission of the diagnostic neutral beam, the beam emission (BES) signal), combining high dispersion (0.02 nm/pixel), sufficient resolution (0.2 nm), high efficiency (55%), and extended wavelength range (14 nm) at high etendue. The combined measurement of the BES along the same sightline within a third wavelength range provides the possibility for in situ calibration of the charge eXchange recombination spectroscopy signals. In addition, the option is included to use the same instrument for measurements of the fast fluctuations of the beam emission intensity up to 2 MHz, with the aim to study MHD activity.

  20. Cold neutral atoms via charge exchange from excited state positronium: a proposal

    Science.gov (United States)

    Bertsche, W. A.; Charlton, M.; Eriksson, S.

    2017-05-01

    We present a method for generating cold neutral atoms via charge exchange reactions between trapped ions and Rydberg positronium. The high charge exchange reaction cross section leads to efficient neutralisation of the ions and since the positronium-ion mass ratio is small, the neutrals do not gain appreciable kinetic energy in the process. When the original ions are cold the reaction produces neutrals that can be trapped or further manipulated with electromagnetic fields. Because a wide range of species can be targeted we envisage that our scheme may enable experiments at low temperature that have been hitherto intractable due to a lack of cooling methods. We present an estimate for achievable temperatures, neutral number and density in an experiment where the neutrals are formed at a milli-Kelvin temperature from either directly or sympathetically cooled ions confined on an ion chip. The neutrals may then be confined by their magnetic moment in a co-located magnetic minimum well also formed on the chip. We discuss general experimental requirements.

  1. Determination of plasma ion velocity distribution via charge-exchange recombination spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Fonck, R.J.; Darrow, D.S.; Jaehnig, K.P.

    1983-12-01

    Spectroscopy of line radiation from plasma impurity ions excited by charge-exchange recombination reactions with energetic neutral beam atoms is rapidly becoming recognized as a powerful technique for measuring ion temperature, bulk plasma motion, impurity transport, and more exotic phenomena such as fast alpha particle distributions. In particular, this diagnostic offers the capability of obtaining space- and time-resolved ion temperature and toroidal plasma rotation profiles with relatively simple optical systems. Cascade-corrected excitation rate coefficients for use in both fully stripped impurity density studies and ion temperature measurements have been calculated to the principal ..delta..n = 1 transitions of He+, C/sup 5 +/, and O/sup 7 +/ with neutral beam energies of 5 to 100 keV/amu. A fiber optically coupled spectrometer system has been used on PDX to measure visible He/sup +/ radiation excited by charge exchange. Central ion temperatures up to 2.4 keV and toroidal rotation speeds up to 1.5 x 10/sup 7/ cm/s were observed in diverted discharges with P/sub INJ/ less than or equal to 3.0 MW.

  2. Solar wind charge exchange emission in the Chandra deep field north

    Energy Technology Data Exchange (ETDEWEB)

    Slavin, Jonathan D.; Wargelin, Bradford J. [Harvard-Smithsonian Center for Astrophysics, 60 Garden Street, Cambridge, MA 02138 (United States); Koutroumpa, Dimitra [LATMOS/IPSL, CNRS, Université Versailles Saint Quentin, 11 Boulevard d' Alembert, F-78280, Guyancourt (France)

    2013-12-10

    The diffuse soft X-ray background comes from distant galaxies, from hot Galactic gas, and from within the solar system. The latter emission arises from charge exchange between highly charged solar wind ions and neutral gas. This so-called solar wind charge exchange (SWCX) emission is spatially and temporally variable and interferes with our measurements of more distant cosmic emission while also providing important information on the nature of the solar wind-interstellar medium interaction. We present the results of our analysis of eight Chandra observations of the Chandra Deep Field North (CDFN) with the goal of measuring the cosmic and SWCX contributions to the X-ray background. Our modeling of both geocoronal and heliospheric SWCX emission is the most detailed for any observation to date. After allowing for ∼30% uncertainty in the SWCX emission and subtracting it from the observational data, we estimate that the flux of cosmic background for the CDFN in the O VII Kα, Kβ, and O VIII Lyα lines totals 5.8 ± 1.1 photons s{sup –1} cm{sup –2} sr{sup –1} (or LU). Heliospheric SWCX emission varied for each observation due to differences in solar wind conditions and the line of sight through the solar system, but was typically about half as strong as the cosmic background (i.e., one-third of the total) in those lines. The modeled geocoronal emission was 0.82 LU in one observation but averaged only 0.15 LU in the others. Our measurement of the cosmic background is lower than but marginally consistent with previous estimates based on XMM-Newton data.

  3. Design of a strong cation exchange methodology for the evaluation of charge heterogeneity in glatiramer acetate.

    Science.gov (United States)

    Campos-García, Víctor R; López-Morales, Carlos A; Benites-Zaragoza, Eleuterio; Jiménez-Miranda, Armando; Espinosa-de la Garza, Carlos E; Herrera-Fernández, Daniel; Padilla-Calderón, Jesús; Pérez, Néstor O; Flores-Ortiz, Luis F; Medina-Rivero, E

    2017-01-05

    Complex pharmaceuticals are in demand of competent analytical methods able to analyze charge heterogeneity as a critical quality attribute (CQA), in compliance with current regulatory expectations. A notorious example is glatiramer acetate (GA), a complex polypeptide mixture useful for the treatment of relapsing-remitting multiple sclerosis. This pharmaceutical challenges the current state of analytical technology in terms of the capacity to study their constituent species. Thus, a strong cation exchange methodology was designed under the lifecycle approach to support the establishment of GA identity, trough the evaluation of its chromatographic profile, which acts as a charge heterogeneity fingerprint. In this regard, a maximum relative margin of error of 5% for relative retention time and symmetry factor were proposed for the analytical target profile. The methodology met the proposed requirements after precision and specificity tests results, the former comprised of sensitivity and selectivity. Subsequently, method validation was conducted and showed that the method is able to differentiate between intact GA and heterogeneity profiles coming from stressed, fractioned or process-modified samples. In summary, these results provide evidence that the method is adequate to assess charge heterogeneity as a CQA of this complex pharmaceutical. Copyright © 2016 Elsevier B.V. All rights reserved.

  4. The velocity dependence of X-ray emission due to Charge Exchange in the Cygnus Loop

    Science.gov (United States)

    Cumbee, Renata; Lyons, David; Mullen, Patrick Dean; Shelton, Robin L.; Stancil, Phillip C.; Schultz, David R.

    2016-01-01

    The fundamental collisional process of charge exchange (CX) has been been established as a primary source of X-ray emission from the heliosphere [1], planetary exospheres [2], and supernova remnants [3,4]. In this process, X-ray emission results from the capture of an electron by a highly charged ion from a neutral atom or molecule, to form a highly-excited, high charge state ion. As the captured electron cascades down to the lowest energy level, photons are emitted, including X-rays.To provide reliable CX-induced X-ray spectral models to realistically simulate these environments, line ratios and spectra are computed using theoretical CX cross-sections obtained with the multi-channel Landau-Zener, atomic-orbital close-coupling, and classical-trajectory Monte Carlo methods for various collisional velocities relevant to astrophysics for collisions of bare and H-like C to Al ions with H, He, and H2. Using these line ratios, XSPEC models of CX emission in the northeast rim of the Cygnus Loop supernova remnant will be shown as an example with ion velocity dependence.[1] Henley, D. B. & Shelton, R. L. 2010, ApJSS, 187, 388[2] Dennerl, K. et al. 2002, A&A 386, 319[3] Katsuda, S. et al. 2011, ApJ 730 24[4] Cumbee, R. S. et al. 2014, ApJ 787 L31This work was partially supported by NASA grant NNX09AC46G.

  5. Charge-exchange, ionization and excitation in low-energy Li$^{+}-$ Ar, K$^{+}-$ Ar, and Na$^{+}-$He collisions

    CERN Document Server

    Lomsadze, Ramaz A; Kezerashvili, RomanYa; Schulz, Michael

    2016-01-01

    Absolute cross sections are measured for charge-exchange, ionization, and excitation within the same experimental setup for the Li$^{+}-$Ar, K$^{+}-$ Ar, and Na$^{+}-$ He collisions in the ion energy range $0.5-10$ keV. Results of our measurements along with existing experimental data and the schematic correlation diagrams are used to analyze and determine the mechanisms for these processes. The experimental results show that the charge-exchange processes are realized with high probabilities and electrons are predominately captured in ground states. The cross section ratio for charge exchange, ionization and excitation processes roughly attains the value $10:2:1$, respectively. The contributions of various partial inelastic channels to the total ionization cross sections are estimated and a primary mechanism for the process is defined. The energy-loss spectrum, in addition, is applied to estimate the relative contribution of different inelastic channels and to determine the mechanisms for the ionization and f...

  6. Molecular (Feshbach) treatment of charge exchange Li/sup 3 +/+He collisions. I. Energies and couplings

    Energy Technology Data Exchange (ETDEWEB)

    Martin, F.; Riera, A.; Yanez, M.

    1986-05-15

    We point out a fundamental difference between the molecular treatment of charge exchange X/sup n/++H(1s) and X/sup n/++He(1s/sup 2/) collisions, which is that the latter process involves molecular states that are formally autoionizing. Then standard ab initio methods do not, in general, yield the relevant wave functions that are needed in the collision treatment, irrespective of whether quasimolecular autoionization be significant or not during the collision. We implement a particularly simple and useful form of the Feshbach formalism to calculate the energies of those two electron systems, and a method to evaluate the corresponding dynamical couplings is presented for the first time. Our implementation of this formalism together with the new computational techniques involved are presented in detail.

  7. Effect of injection energy on residual dose around the charge exchange foil

    Directory of Open Access Journals (Sweden)

    Kazami Yamamoto

    2012-12-01

    Full Text Available The rapid cycling synchrotron (RCS of Japan Proton Accelerator Research Complex (J-PARC and the accumulator ring (AR of Spallation Neutron Source (SNS can be used as high-power pulsed neutron sources. In both cases, the injection region becomes one of the highest activation areas in the ring. However, residual dose distributions have revealed that the highest activation points in the J-PARC RCS and the SNS AR are different in detail. The dose of the charge exchange chamber in the SNS is more than 100 times larger than that of the RCS though the ratio of beam power is less than 10. We investigated the reason of this difference by Geant4 and MARS, and the calculation results indicated that the difference was due to the dependence of the neutron and pion production rate on the injection energy.

  8. Final-state-resolved charge exchange in C5 + collisions with H

    Science.gov (United States)

    Nolte, J. L.; Stancil, P. C.; Liebermann, H. P.; Buenker, R. J.; Hui, Y.; Schultz, D. R.

    2012-12-01

    We report charge exchange cross sections for the collision system C5 + + H using the quantum mechanical molecular-orbital close-coupling method. The multi-reference single- and double-excitation configuration interaction method is used to produce potential and coupling data, and scattering calculations are performed for collision energies between 0.01 eV/u to 1 keV/u for all l,S-resolved states within the n = 3 and 4 manifolds. The n = 5 manifold is represented through the inclusion of the 5s state. To predict cross sections at higher energies, we include new results from atomic-orbital close-coupling and classical trajectory Monte Carlo calculations. We briefly discuss applications to x-ray emission within the solar system.

  9. Non-coherent contributions in charge-exchange reactions and η-η{sup '} mixing

    Energy Technology Data Exchange (ETDEWEB)

    Nekrasov, M.L. [NRC ' ' Kurchatov Institute' ' , Institute for High Energy Physics, Protvino (Russian Federation)

    2017-05-15

    We analyse K{sup -}p → (η,η{sup '},π{sup 0})Λ on the basis of the fit of data in a wide region of energies, and π{sup -}p → (η,η{sup '})n at the energies of GAMS-4π. We show that disagreements between the data and the predictions of Regge theory may be explained by the mode change of summation of intermediate contributions at increasing energy, from coherent to non-coherent. A method of experimental measurement of the non-coherent contributions is proposed. On the basis of available data on the charge-exchange reactions the η-η{sup '} mixing is estimated. (orig.)

  10. High efficiency laser-assisted H- charge exchange for microsecond duration beams

    Science.gov (United States)

    Cousineau, Sarah; Rakhman, Abdurahim; Kay, Martin; Aleksandrov, Alexander; Danilov, Viatcheslav; Gorlov, Timofey; Liu, Yun; Long, Cary; Menshov, Alexander; Plum, Michael; Shishlo, Andrei; Webster, Andrew; Johnson, David

    2017-12-01

    Laser-assisted stripping is a novel approach to H- charge exchange that overcomes long-standing limitations associated with the traditional, foil-based method of producing high-intensity, time-structured beams of protons. This paper reports on the first successful demonstration of the laser stripping technique for microsecond duration beams. The experiment represents a factor of 1000 increase in the stripped pulse duration compared with the previous proof-of-principle demonstration. The central theme of the experiment is the implementation of methods to reduce the required average laser power such that high efficiency stripping can be accomplished for microsecond duration beams using conventional laser technology. The experiment was performed on the Spallation Neutron Source 1 GeV H- beam using a 1 MW peak power UV laser and resulted in ˜95 % stripping efficiency.

  11. Charge ordering and exchange bias behaviors in Co3O4 porous nanoplatelets and nanorings

    Science.gov (United States)

    Debnath, J. C.; Wang, Jianli; Zeng, R.

    2017-01-01

    We present the synthesis of α-Co3O4 porous nanoplatelets and hexagonal nanorings using microwave-assisted hydrothermal and conventional chemical reaction methods. The x-ray diffraction (XRD) and refinement analyses indicate the α-Co3O4 crystal structure, and the x-ray photoelectron spectrum (XPS) indicates the high purity of the samples. The M-T (including 1/χ-T) curves indicate an antiferromagnetic transition at about 35 K in both kind of samples but the interesting finding was made that a charge-ordered (CO) state appears at 250 K for the nanoplatelets sample whereas it is inattentive for the nanorings. The antiferromagnetic transition temperature TN is lower than that of the bulk α-Co3O4 single crystal due to the nanosized structures. We observed quite significant exchange bias for nanorings. The exchange bias behavior of the α-Co3O4 hexagonal nanorings is consistent with an antiferromagnetic (AFM) Co3O4 core and spin-glass like shell.

  12. Most exchange plans charge lower tobacco surcharges than allowed, but many tobacco users lack affordable coverage.

    Science.gov (United States)

    Kaplan, Cameron M; Graetz, Ilana; Waters, Teresa M

    2014-08-01

    Beginning in 2014, federal guidelines for health plans sold to people in the individual market allow insurers to charge tobacco users up to 50 percent more for premiums, compared to nonusers. We examined variations in tobacco surcharges for plans offered through the state and federal health insurance exchanges, or Marketplaces. The plan with the median surcharge had only 10 percent higher premiums for tobacco users compared to nonusers, and nine in ten plans charged a lower surcharge than allowed. Even with such lower-than-allowed surcharges, tobacco users lacked affordable coverage-defined as access to at least one plan with premiums of less than 8 percent of income after subsidies-in more states than did nonusers. Higher premiums could encourage tobacco users to opt out of coverage. Our results also suggest that the variation in tobacco surcharges may result in the sorting of tobacco users and nonusers into different plans. Project HOPE—The People-to-People Health Foundation, Inc.

  13. X-ray spectroscopic study of charge exchange phenomena in plasma-wall interaction

    Directory of Open Access Journals (Sweden)

    Renner O.

    2013-11-01

    Full Text Available Jets of energetic ions launched at laser-burnt-through foils represent an efficient tool for investigation of plasma interaction with solid surfaces (plasma-wall interaction, PWI and for description of transient phenomena occurring close to the walls. Highly charged ions approaching the secondary target interpenetrate the near surface layer, collide with the counter-propagating matter and capture a large number of electrons. This results in a creation of atoms in highly excited Rydberg states or hollow ions with multiple inner vacancies; plasma jet and target ions may also undergo charge exchange (CE processes. We report PWI experiments with Al/Si(PMMA and Al/C targets irradiated at normal or oblique laser incidence. The distinct dip structures observed in red wings of Al Lyγ self-emission is interpreted in terms of CE between C6+ and Al12+ in the near-wall zone. The spectroscopic identification of CE phenomena is supported by results of analytical and numerical calculations.

  14. Modeling the Magnetospheric X-ray Emission from Solar Wind Charge Exchange with Verification from XMM-Newton Observations

    Science.gov (United States)

    2016-08-26

    Earth (i.e., hydrogen) to a heavy , high charge state, ion in the solarwind. The electron can be captured in an excited state and transition to lower... heavy ions , Geophys Res. Lett., 24, 105–109, doi:10.1029/96GL03780. Cravens, T. E. (2000), Heliospheric X-ray emission associated with charge transfer...quantifying charge exchange from other ions with emission lines around the 1 4 keV band have also been performed, though the lack of cross-sectional

  15. Overview on R&D and design activities for the ITER core charge exchange spectroscopy diagnostic system

    NARCIS (Netherlands)

    Biel, W.; Baross, T.; Bourauel, P.; Dunai, D.; Durkut, M.; Erdei, G.; Hawkes, N.; Hellermann, M. von; Hogenbirk, A.; Jaspers, R.; Kiss, G.; Klinkhamer, J.F.F.; Koning, J.F.; Kotov, V.; Krasikov, Y.; Krimmer, A.; Lischtschenko, O.; Litnovsky, A.; Marchuk, O.; Neubauer, O.; Offermanns, G.; Panin, A.; Patel, K.; Pokol, G.; Schrader, M.; Snijders, B.; Szabo, V.; Valk, N.J.C. van der; Voinchet, R.; Wolters, J.; Zoletnik, S.

    2011-01-01

    The ITER core charge exchange recombination spectroscopy (core CXRS) diagnostic system is designed to provide experimental access to various measurement quantities in the ITER core plasma such as ion densities, temperatures and velocities. The implementation of the approved CXRS diagnostic principle

  16. Impact of exact exchange in the description of the electronic structure of organic charge-transfer molecular crystals

    KAUST Repository

    Fonari, Alexandr

    2014-10-21

    We evaluate the impact that the amount of nonlocal Hartree-Fock (%HF) exchange included in a hybrid density functional has on the microscopic parameters (transfer integrals, band gaps, bandwidths, and effective masses) describing charge transport in high-mobility organic crystals. We consider both crystals based on a single molecule, such as pentacene, and crystals based on mixed-stack charge-transfer systems, such as dibenzo-TTF–TCNQ. In the pentacene crystal, the band gap decreases and the effective masses increase linearly with an increase in the amount of %HF exchange. In contrast, in the charge-transfer crystals, while the band gap increases linearly, the effective masses vary only slightly with an increase in %HF exchange. We show that the superexchange nature of the electronic couplings in charge-transfer systems is responsible for this peculiar evolution of the effective masses. We compare the density functional theory results with results obtained within the G0W0 approximation as a way of benchmarking the optimal amount of %HF exchange needed in a given functional.

  17. Mechanistic modeling of ion-exchange process chromatography of charge variants of monoclonal antibody products.

    Science.gov (United States)

    Kumar, Vijesh; Leweke, Samuel; von Lieres, Eric; Rathore, Anurag S

    2015-12-24

    Ion-exchange chromatography (IEX) is universally accepted as the optimal method for achieving process scale separation of charge variants of a monoclonal antibody (mAb) therapeutic. These variants are closely related to the product and a baseline separation is rarely achieved. The general practice is to fractionate the eluate from the IEX column, analyze the fractions and then pool the desired fractions to obtain the targeted composition of variants. This is, however, a very cumbersome and time consuming exercise. A mechanistic model that is capable of simulating the peak profile will be a much more elegant and effective way to make a decision on the pooling strategy. This paper proposes a mechanistic model, based on the general rate model, to predict elution peak profile for separation of the main product from its variants. The proposed approach uses inverse fit of process scale chromatogram for estimation of model parameters using the initial values that are obtained from theoretical correlations. The packed bed column has been modeled along with the chromatographic system consisting of the mixer, tubing and detectors as a series of dispersed plug flow and continuous stirred tank reactors. The model uses loading ranges starting at 25% to a maximum of 70% of the loading capacity and hence is applicable to process scale separations. Langmuir model has been extended to include the effects of salt concentration and temperature on the model parameters. The extended Langmuir model that has been proposed uses one less parameter than the SMA model and this results in a significant ease of estimating the model parameters from inverse fitting. The proposed model has been validated with experimental data and has been shown to successfully predict peak profile for a range of load capacities (15-28mg/mL), gradient lengths (10-30CV), bed heights (6-20cm), and for three different resins with good accuracy (as measured by estimation of residuals). The model has been also

  18. X-ray emission from the local hot bubble and solar wind charge exchange

    Science.gov (United States)

    Uprety, Youaraj

    DXL (Diffuse X-rays from the Local galaxy) is a sounding rocket mission to quantify the Solar Wind Charge Exchange (SWCX) X-ray emission in the interplanetary medium, and separate its contribution from the Local Hot Bubble (LHB) emission. The first launch of DXL took place in December 2012. This thesis will describe the DXL instrumentation and calibrations, and discuss the results obtained. The mission uses two large area proportional counters to scan through the Helium Focusing Cone (HFC), a high helium density region in the solar system emitting excess X-rays due to SWCX. Using well determined models of the interplanetary neutral distribution and comparing the DXL results with data from the same region obtained by the ROSAT satellite away from the cone, we calculated that SWCX contributes at most 36% to the ¼ keV ROSAT band and 13% to the ¾ keV ROSAT band, in the galactic plane. This provides a firm proof for existence of a LHB which dominates the Diffuse X-ray Background (DXB) at ¼ keV, while raising new questions on the origin of the ¾ keV emission.

  19. Charge exchange and X-ray emission in 70 MeV/u Bi-Au collisions

    Energy Technology Data Exchange (ETDEWEB)

    Verma, P. [GSI, D-64291 Darmstadt (Germany) and Vaish College, Rohtak 124 001 (India) and J. Liebig University, D-35392 Giessen (Germany)]. E-mail: P.Verma@gsi.de; Mokler, P.H. [GSI, D-64291 Darmstadt (Germany); JMI University, New Delhi 110 025 (India); Braeuning-Demian, A. [GSI, D-64291 Darmstadt (Germany); Braeuning, H. [JMI University, New Delhi 110 025 (India); Berdermann, E. [GSI, D-64291 Darmstadt (Germany); Chatterjee, S. [GSI, D-64291 Darmstadt (Germany); Gumberidze, A. [GSI, D-64291 Darmstadt (Germany); Hagmann, S. [J.W. Goethe University, D-60486 Frankfurt (Germany); Kozhuharov, C. [GSI, D-64291 Darmstadt (Germany); Orsic-Muthig, A. [GSI, D-64291 Darmstadt (Germany); Reuschl, R. [J.W. Goethe University, D-60486 Frankfurt (Germany); Schoeffler, M. [J.W. Goethe University, D-60486 Frankfurt (Germany); Spillmann, U. [GSI, D-64291 Darmstadt (Germany); Stoehlker, Th. [GSI, D-64291 Darmstadt (Germany); Stachura, Z. [Institute for Nuclear Physics, PL-31-342 Cracow (Poland); Tashenov, S. [GSI, D-64291 Darmstadt (Germany); Wahab, M.A. [Vaish College, Rohtak 124 001 (India)

    2005-07-01

    Charge exchange and X-ray emission for 70 MeV/u highly charged ions of Bi {sup q+} [77 q 82] colliding with thin Au targets [21 t in {mu}g/cm{sup 2} 225] were measured at the heavy ion synchrotron SIS at GSI. For the innermost shells this beam energy implies a quasiadiabatic collision regime. The charge state distribution of the emerging ions was measured by a position sensitive CVD-diamond detector after being analyzed by a magnet spectrometer. Charge exchange cross sections have been deduced from the target thickness dependence of the charge state distribution. Electron capture at distant collision dominates completely over ionization at close collision. The X-ray emission from the collision partners were measured by solid state detectors, Ge(i). The K X-ray emission for closed and open incoming projectile K vacancies gives access to vacancy transfer in the superheavy quasi-molecule transiently formed during collision for the innermost shells.

  20. Protein adsorption on ion exchange resins and monoclonal antibody charge variant modulation.

    Science.gov (United States)

    Guélat, Bertrand; Khalaf, Rushd; Lattuada, Marco; Costioli, Matteo; Morbidelli, Massimo

    2016-05-20

    A novel multicomponent adsorption equilibrium model for proteins on ion-exchange resins is developed on a statistical thermodynamic basis including surface coverage effects and protein-resin and protein-protein interactions. The resulting model exhibits a general competitive Langmuirian behavior and was applied to the study and optimization of the separation of monoclonal antibody charge variants on two strong cation exchangers. The model accounts explicitly for the effect of both pH and salt concentration, and its parameters can be determined in diluted conditions, that is, through physically sound assumptions, all model parameters can be obtained using solely experiments in diluted conditions, and be used to make predictions in overloaded conditions. The parameterization of the model and optimization of the separation is based on a two-step approach. First, gradient experiments in diluted conditions are undertaken in order to determine the model parameters. Based on these experiments and on information about the proteins of interest and the stationary phase used, all the model parameters can be estimated. Second, using the parameterized model, an initial Pareto optimization is undertaken where overloaded operating conditions are investigated. Experiments from this Pareto set are then used to refine the estimation of the model parameters. A second Pareto optimization can then be undertaken, this time with the refined parameters. This can be repeated until a satisfactory set of model parameters is found. This iterative approach is shown to be extremely efficient and to provide large amounts of knowledge based on only a few experiments. It is shown that due to the strong physical foundation of the model and the very low number of adjustable parameters, the number of iterations is expected to be at most two or three. Furthermore, the model based tool is improved as more experimental knowledge is provided, allowing for better estimations of the chromatographic

  1. Astrophysical Applications for Charge-Exchange with H, He, and H2 Targets

    Science.gov (United States)

    Cumbee, Renata S.; Mullen, Patrick D.; Shelton, Robin L.; Schultz, David R.; Stancil, Phillip C.

    2018-01-01

    When a hot plasma collides with a cold neutral gas, interactions occur between the constituents at the interface of the collision, including charge exchange (CX). CX is a process in which an electron can be transferred from a neutral atom or molecule into an excited energy level of an ion. Following this transfer, the excited electron relaxes to lower energy levels, emitting X-rays. This process has been established as a primary source of X-ray emission within our solar system, such as when the solar wind interacts with cometary and planetary atmospheres, and outside of our solar system, such as in the hot outflows of starburst galaxies.As the CX X-ray emission spectrum varies greatly with collision velocity, it is critical that realistic CX data are included in X-ray spectral models in regions in which CX might be significant so that the ion abundance and plasma velocities can be estimated most accurately. Here, a set of CX X-ray line ratios and spectra will be shown for a variety of collision velocities for C-Cl ions colliding with H, He, and H2. An X-ray emission model including these line ratios performed in XSPEC will be presented for a region of the Cygnus Loop supernova remnant and the starburst galaxy M82 in order to highlight the variation in CX spectral models with collision energy and neutral target species.R. Cumbee’s research was partially supported by an appointment to the NASA Postdoctoral Program at NASA GSFC, administered by Universities Space Research Association under contract with NASA. Work at UGA was partially supported by NASA grants NNX09AC46G and NNG09WF24I.

  2. Charge-exchange collision dynamics and ion engine grid geometry optimization

    Science.gov (United States)

    Morris, Bradford

    The development of a new three-dimensional model for determining the absolute energy distribution of ions at points corresponding to spacecraft surfaces to the side of an ion engine is presented. The ions resulting from elastic collisions, both charge-exchange (CEX) and direct, between energetic primary ions and thermal neutral xenon atoms are accounted for. Highly resolved energy distributions of CEX ions are found by integration over contributions from all points in space within the main beam formed by the primary ions.The sputtering rate due to impingement of these ions on a surface is calculated. The CEX ions that obtain significant energy (10 eV or more) in the collision are responsible for the majority of the sputtering, though this can depend on the specific material being sputtered. In the case of a molybdenum surface located 60 cm to the side of a 30 cm diameter grid, nearly 90% of the sputtering is due to the 5% of ions with the highest collision exit energies. Previous models that do not model collision energetics cannot predict this. The present results agree with other models and predict that the majority of the ion density is due to collisions where little to no energy is transferred.The sputtering model is combined with a grid-structure model in an optimization procedure where the sputtering rate at specified locations is minimized by adjustment of parameters defining the physical shape of the engine grids. Constraints are imposed that require that the deflection of the grid under a specified load does not exceed a maximum value, in order to ensure survivability of the grids during launch. To faciliate faster execution of the calculations, simplifications based on the predicted behavior of the CEX ions are implemented. For diametrically opposed sputtering locations, a rounded barrel-vault shape reduces the expected sputtering rate by up to 30% in comparison to an NSTAR-shaped grid.

  3. Heavy-ion double charge exchange reactions: A tool toward 0 νββ nuclear matrix elements

    Energy Technology Data Exchange (ETDEWEB)

    Cappuzzello, F.; Bondi, M. [Universita di Catania, Dipartimento di Fisica e Astronomia, Catania (Italy); INFN, Laboratori Nazionali del Sud, Catania (Italy); Cavallaro, M.; Agodi, C.; Carbone, D.; Cunsolo, A. [INFN, Laboratori Nazionali del Sud, Catania (Italy); Foti, A. [Universita di Catania, Dipartimento di Fisica e Astronomia, Catania (Italy); INFN, Sezione di Catania, Catania (Italy)

    2015-11-15

    The knowledge of the nuclear matrix elements for the neutrinoless double beta decay is fundamental for neutrino physics. In this paper, an innovative technique to extract information on the nuclear matrix elements by measuring the cross section of a double charge exchange nuclear reaction is proposed. The basic point is that the initial- and final-state wave functions in the two processes are the same and the transition operators are similar. The double charge exchange cross sections can be factorized in a nuclear structure term containing the matrix elements and a nuclear reaction factor. First pioneering experimental results for the {sup 40}Ca({sup 18}O,{sup 18}Ne){sup 40}Ar reaction at 270 MeV incident energy show that such cross section factorization reasonably holds for the crucial 0{sup +} → 0{sup +} transition to {sup 40}Ar{sub gs}, at least at very forward angles. (orig.)

  4. CrossRef Large numbers of cold positronium atoms created in laser-selected Rydberg states using resonant charge exchange

    CERN Document Server

    McConnell, R; Kolthammer, WS; Richerme, P; Müllers, A; Walz, J; Grzonka, D; Zielinski, M; Fitzakerley, D; George, MC; Hessels, EA; Storry, CH; Weel, M

    2016-01-01

    Lasers are used to control the production of highly excited positronium atoms (Ps*). The laser light excites Cs atoms to Rydberg states that have a large cross section for resonant charge-exchange collisions with cold trapped positrons. For each trial with 30 million trapped positrons, more than 700 000 of the created Ps* have trajectories near the axis of the apparatus, and are detected using Stark ionization. This number of Ps* is 500 times higher than realized in an earlier proof-of-principle demonstration (2004 Phys. Lett. B 597 257). A second charge exchange of these near-axis Ps* with trapped antiprotons could be used to produce cold antihydrogen, and this antihydrogen production is expected to be increased by a similar factor.

  5. Study of the pd→→n{pp}s charge-exchange reaction using a polarised deuterium target

    Directory of Open Access Journals (Sweden)

    B. Gou

    2015-02-01

    Full Text Available The vector and tensor analysing powers, Ay and Ayy, of the pd→→n{pp}s charge-exchange reaction have been measured at a beam energy of 600 MeV at the COSY-ANKE facility by using an unpolarised proton beam incident on an internal storage cell target filled with polarised deuterium gas. The low energy recoiling protons were measured in a pair of silicon tracking telescopes placed on either side of the target. Putting a cut of 3 MeV on the diproton excitation energy ensured that the two protons were dominantly in the S01 state, here denoted by {pp}s. The polarisation of the deuterium gas was established through measurements in parallel of proton–deuteron elastic scattering. By analysing events where both protons entered the same telescope, the charge-exchange reaction was measured for momentum transfers q≥160 MeV/c. These data provide a good continuation of the earlier results at q≤140 MeV/c obtained with a polarised deuteron beam. They are also consistent with impulse approximation predictions with little sign evident for any modifications due to multiple scatterings. These successful results confirm that the ANKE deuteron charge-exchange programme can be extended to much higher energies with a polarised deuterium target than can be achieved with a polarised deuteron beam.

  6. Charge exchange recombination in X-ray spectra of He-like argon measured at the tokamak TEXTOR

    Energy Technology Data Exchange (ETDEWEB)

    Schlummer, Tobias

    2014-06-16

    Charge exchange recombination between ions and atomic hydrogen is an important atomic process in magnetically confined fusion plasmas. Besides radiative cooling of the plasma edge, charge exchange causes modifications of the ionization balance and the population densities of excited ion states. The central goal of this work is to investigate the influence of charge exchange on X-ray spectra measured at the tokamak TEXTOR. A new 2D X-ray spectrometer developed for future use at the stellarator W7-X was recently installed at TEXTOR. The spectrometer is optimized for measuring the K{sub α}-spectrum of He-like argon (1s2l - 1s{sup 2}) at wavelengths close to 4 Aa. K{sub α}-spectroscopy on He-like impurity ions is an established diagnostic for electron and ion temperature measurements in fusion plasmas. Still, up to now the observed intensity ratios of the K{sub α}-lines and their associated satellites are not fully understood. They show significant deviations from the predictions made by basic corona models. In the past charge exchange with the neutral particle background and radial impurity transport have been discussed as likely explanations. Yet a detailed description of the experimental spectra still has not been achieved. To reconstruct the 2D K{sub α}-spectra measured at TEXTOR the radial argon ion distribution is modeled using an impurity transport code. The model accounts for charge exchange and transport on basis of given radial profiles of the neutral particle density n{sub 0}(r) and the diffusion coefficient D {sub perpendicular} {sub to} (r). The theoretical spectrum is then constructed based on the processes relevant for line emission. Within an iterative procedure n{sub 0}(r) and D {sub perpendicular} {sub to} (r) are varied until consistency between the theoretical and the experimental spectra is achieved. It is shown that the 2D K{sub α}-spectra allow a clear distinction of charge exchange and transport effects, ensuring unique solutions for n

  7. Solar Wind Charge Exchange Contribution To The ROSAT Sky Survey Maps

    Science.gov (United States)

    Uprety, Y.; Chiao, M.; Collier, M. R.; Cravens, T.; Galeazzi, M.; Koutroumpa, D.; Kuntz, K. D.; Lallement, R.; Lepri, S. T.; Liu, W.; hide

    2016-01-01

    DXL (Diffuse X-ray emission from the Local Galaxy) is a sounding rocket mission designed to estimate the contribution of solar wind charge eXchange (SWCX) to the diffuse X-ray background and to help determine the properties of the Local Hot Bubble. The detectors are large area thin-window proportional counters with a spectral response that is similar to that of the PSPC (Position Sensitive Proportional Counters) used in the ROSAT All Sky Survey (RASS). A direct comparison of DXL and RASS data for the same part of the sky viewed from quite different vantage points in the solar system, and the assumption of approximate isotropy for the solar wind, allowed us to quantify the SWCX contribution to all six RASS bands (R1-R7, excluding R3). We find that the SWCX contribution at l = 140 degrees, b = 0 degrees, where the DXL path crosses the Galactic plane, is 33 percent plus or minus 6 percent (statistical) plus or minus 12 percent (systematic) for R1, 44 percent plus or minus 6 percent plus or minus 5 percent for R2, 18 percent plus or minus 12 percent plus or minus 11 percent for R4, 14 percent plus or minus 11 percent plus or minus 9 percent for R5, and negligible for the R6 and R7 bands. Reliable models for the distribution of neutral H and He in the solar system permit estimation of the contribution of interplanetary SWCX emission over the the whole sky and correction of the RASS maps. We find that the average SWCX contribution in the whole sky is 26 percent plus or minus 6 percent plus or minus 13 percent for R1, 30 percent plus or minus 4 percent plus or minus 4 percent for R2, 8 percent plus or minus 5 percent plus or minus 5 percent for R4, 6 percent plus or minus 4 percent plus or minus 4 percent for R5, and negligible for R6 and R7.

  8. Charge Exchange X-Ray Emission due to Highly Charged Ion Collisions with H, He, and H2: Line Ratios for Heliospheric and Interstellar Applications

    Science.gov (United States)

    Cumbee, R. S.; Mullen, P. D.; Lyons, D.; Shelton, R. L.; Fogle, M.; Schultz, D. R.; Stancil, P. C.

    2018-01-01

    The fundamental collisional process of charge exchange (CX) has been established as a primary source of X-ray emission from the heliosphere, planetary exospheres, and supernova remnants. In this process, X-ray emission results from the capture of an electron by a highly charged ion from a neutral atom or molecule, to form a highly excited, high-charge state ion. As the captured electron cascades down to the lowest energy level, photons are emitted, including X-rays. To provide reliable CX-induced X-ray spectral models to realistically simulate these environments, line ratios and spectra are computed using theoretical CX cross sections obtained with the multi-channel Landau-Zener, atomic-orbital close-coupling, molecular-orbital close-coupling, and classical trajectory Monte Carlo methods for various collisional velocities relevant to astrophysics. X-ray spectra were computed for collisions of bare and H-like C to Al ions with H, He, and H2 with results compared to available experimental data. Using these line ratios, XSPEC models of CX emission in the northeast rim of the Cygnus Loop supernova remnant and the heliosphere are shown as examples with ion velocity dependence.

  9. Removal of charged micropollutants from water by ion-exchange polymers - effects of competing electrolytes

    NARCIS (Netherlands)

    Bäuerlein, P.S.; ter Laak, T.L.; Hofman-Caris, R.C.H.M.; de Voogt, P.; Droge, S.T.J.

    2012-01-01

    A wide variety of environmental compounds of concern, e.g. pharmaceuticals or illicit drugs, are acids or bases that may predominantly be present as charged species in drinking water sources. These charged micropollutants may prove difficult to remove by currently used water treatment steps (e.g.

  10. Removal of charged micropollutants from water by ion-exchange polymers - Effects of competing electrolytes

    NARCIS (Netherlands)

    Bauerlein, P.S.; ter Laak, T.L.; Hofman-Caris, R.C.; Droge, S.T.J.

    2012-01-01

    A wide variety of environmental compounds of concern, e.g. pharmaceuticals or illicit drugs, are acids or bases that may predominantly be present as charged species in drinking water sources. These charged micropollutants may prove difficult to remove by currently used water treatment steps (e.g.

  11. Separation of Flip and Non-Flip parst of Charge Exchange np->pn at energies Tn = 0.5 - 2.0 GeV

    CERN Document Server

    Shindin, R A; Chernykh, E V; Guriev, D K; Nomofilov, A A; Prytkov, V Yu; Sharov, V I; Strunov, L I

    2008-01-01

    The new Delta-Sigma experimental data on the ratio $R_{dp}$ allowed separating the Flip and Non-Flip parts of the differential cross section of $np\\to pn$ charge exchange process at the zero angle by the Dean formula. The PSA solutions for the $np\\to np$ elastic scattering are transformed to the $np\\to pn$ charge exchange representation using unitary transition, and good agreement is obtain.

  12. Ultrafast spin exchange-coupling torque via photo-excited charge-transfer processes

    National Research Council Canada - National Science Library

    Ma, X; Fang, F; Li, Q; Zhu, J; Yang, Y; Wu, Y Z; Zhao, H B; Lüpke, G

    2015-01-01

    .... Recently developed optical approaches such as ultrafast demagnetization, spin-transfer and spin-orbit torques open new pathways to manipulate spin through its interaction with photon, orbit, charge or phonon...

  13. The atmosphere of comet 67P/Churyumov-Gerasimenko diagnosed by charge-exchanged solar wind alpha particles

    Science.gov (United States)

    Simon Wedlund, C.; Kallio, E.; Alho, M.; Nilsson, H.; Stenberg Wieser, G.; Gunell, H.; Behar, E.; Pusa, J.; Gronoff, G.

    2016-03-01

    Context. The ESA/Rosetta mission has been orbiting comet 67P/Churyumov-Gerasimenko since August 2014, measuring its dayside plasma environment. The ion spectrometer onboard Rosetta has detected two ion populations, one energetic with a solar wind origin (H+, He2+, He+), the other at lower energies with a cometary origin (water group ions such as H2O+). He+ ions arise mainly from charge-exchange between solar wind alpha particles and cometary neutrals such as H2O. Aims: The He+ and He2+ ion fluxes measured by the Rosetta Plasma Consortium Ion Composition Analyser (RPC-ICA) give insight into the composition of the dayside neutral coma, into the importance of charge-exchange processes between the solar wind and cometary neutrals, and into the way these evolve when the comet draws closer to the Sun. Methods: We combine observations by the ion spectrometer RPC-ICA onboard Rosetta with calculations from an analytical model based on a collisionless neutral Haser atmosphere and nearly undisturbed solar wind conditions. Results: Equivalent neutral outgassing rates Q can be derived using the observed RPC-ICA He+/He2+ particle flux ratios as input into the analytical model in inverse mode. A revised dependence of Q on heliocentric distance Rh in AU is found to be Rh-7.06 between 1.8 and 3.3 AU, suggesting that the activity in 2015 differed from that of the 2008 perihelion passage. Conversely, using an outgassing rate determined from optical remote sensing measurements from Earth, the forward analytical model results are in relatively good agreement with the measured RPC-ICA flux ratios. Modelled ratios in a 2D spherically-symmetric plane are also presented, showing that charge exchange is most efficient with solar wind protons. Detailed cometocentric profiles of these ratios are also presented. Conclusions: In conclusion, we show that, with the help of a simple analytical model of charge-exchange processes, a mass-capable ion spectrometer such as RPC-ICA can be used as a

  14. Prospects of real-time ion temperature and rotation profiles based on neural-network charge exchange analysis

    Energy Technology Data Exchange (ETDEWEB)

    Koenig, R.W.T.; Von Hellermann, M. [Commission of the European Communities, Abingdon (United Kingdom). JET Joint Undertaking; Svensson, J. [Royal Inst. of Tech., Stockholm (Sweden)

    1994-07-01

    A back-propagation neural network technique is used at JET to extract plasma parameters like ion temperature, rotation velocities or spectral line intensities from charge exchange (CX) spectra. It is shown that in the case of the C VI CX spectra, neural networks can give a good estimation (better than +-20% accuracy) for the main plasma parameters (Ti, V{sub rot}). Since the neural network approach involves no iterations or initial guesses the speed with which a spectrum is processed is so high (0.2 ms/spectrum) that real time analysis will be achieved in the near future. 4 refs., 8 figs.

  15. A quark model calculation for the short-range contribution in the pion double charge exchange reaction

    Energy Technology Data Exchange (ETDEWEB)

    Zou Bingsong; Jiang Huanqing (Institute of Theoretical Physics and Institute of High Energy Physcis, Academia Sinica, Beijing (CN))

    1989-10-01

    A quark model calculation for the short-range contribution in the pion double charge exchange (DCX) reaction is presented. In the framework of this new model the angular distributions of {sup 18}O({pi}{sup +},{pi}{sup {minus}}){sup 18}Ne(g.s.) at low energies are calculated and compared with the experimental data. It is found that this model can explain the anomalous'' increasing behavior for the DCX reaction around 50 MeV quite well.

  16. Initial Assessment of Electron and X-Ray Production and Charge Exchange in the NDCX-II Accelerator

    Energy Technology Data Exchange (ETDEWEB)

    COHEN, R.H.

    2010-02-18

    The purpose of this note is to provide initial assessments of some atomic physics effects for the accelerator section of NDCX-II. There are several effects we address: the production of electrons associated with loss of beam ions to the walls, the production of electrons associated with ionization of background gas, the possibly resultant production of X-rays when these electrons hit bounding surfaces, and charge exchange of beam ions on background gas. The results presented here are based on a number of caveats that will be stated below, which we will attempt to remove in the near future.

  17. Charge ordering and exchange bias behaviors in Co{sub 3}O{sub 4} porous nanoplatelets and nanorings

    Energy Technology Data Exchange (ETDEWEB)

    Debnath, J.C., E-mail: jcd341@uowmail.edu.au [Institute for Frontier Materials, Deakin University, Geelong, VIC 3216 (Australia); Wang, Jianli [Institute for Superconductivity and Electronic Materials, University of Wollongong, Wollongong, NSW 2522 (Australia); Zeng, R. [Institute for Superconductivity and Electronic Materials, University of Wollongong, Wollongong, NSW 2522 (Australia); School of Materials Science and Engineering, Faculty of Science, UNSW, Sydney NSW 2052 (Australia)

    2017-01-01

    We present the synthesis of α-Co{sub 3}O{sub 4} porous nanoplatelets and hexagonal nanorings using microwave-assisted hydrothermal and conventional chemical reaction methods. The x-ray diffraction (XRD) and refinement analyses indicate the α-Co{sub 3}O{sub 4} crystal structure, and the x-ray photoelectron spectrum (XPS) indicates the high purity of the samples. The M–T (including 1/χ–T) curves indicate an antiferromagnetic transition at about 35 K in both kind of samples but the interesting finding was made that a charge-ordered (CO) state appears at 250 K for the nanoplatelets sample whereas it is inattentive for the nanorings. The antiferromagnetic transition temperature T{sub N} is lower than that of the bulk α-Co{sub 3}O{sub 4} single crystal due to the nanosized structures. We observed quite significant exchange bias for nanorings. The exchange bias behavior of the α-Co{sub 3}O{sub 4} hexagonal nanorings is consistent with an antiferromagnetic (AFM) Co{sub 3}O{sub 4} core and spin-glass like shell. - Highlights: ●Charge-ordered state appears for the Co{sub 3}O{sub 4} nanoplatelets but absent for the nanorings. ●Quite significant exchange bias is only observed for Co{sub 3}O{sub 4} nanorings. ●Exchange bias behavior of Co{sub 3}O{sub 4} nanorings is consistent with spin-glass like shell. ●Potential for ultrahigh-density magnetic recording and spin valve devices.

  18. Laboratory Measurements of Solar-Wind/Comet X-Ray Emission and Charge-Exchange Cross Sections

    Science.gov (United States)

    Chutjian, A.; Ĉade, I.; Greenwood, J. B.; Mawhorter, R. J.; Smith, S. J.; Lozano, J.

    2002-11-01

    The detection of X-rays from comets such as Hyakutake, Hale-Bopp, d'Arrest, and Linear as they approach the Sun has been both unexpected and exciting. This phenomenon, moreover, should be quite general, occurring wherever a fast solar or stellar wind interacts with neutrals in a comet, a planetary atmosphere, or a circumstellar cloud. Comet-modeling calculations to date have (a) used an approximate, over-barrier expression for the charge-exchange (CE) cross section, (b) assumed a flat energy dependence of cross section, and (c) neglected multiple charge exchanges. In support of the understanding of the X-ray emissions (their intensity and spatial extent) laboratory measurements have been carred out at the JPL Highly-Charged Ion Facility [1]. The projectiles have been partially- and fully-stripped H, He, C, N, O, and Ne ions interacting with the comet molecules He, H2, CO, CO2, and H2O. Absolute CE cross sections have been measured, and normalized X-ray emission cross sections reported for these major HCI components of the solar wind [2-5]. The minor, heavier HCI components will produce high-energy X-rays. A large body of data has been acquired on Fe(5-13)+[6]. The experimental approach will be discussed and results given. Future work will be extended to Mgq+ charge states, and include as well NH3 as the target. R. Mawhorter thanks the National Research Council for a fellowship though the NASA-NRC program. This work was carried out at the Jet Propulsion Laboratory, California Institute of Technology, and was supported under contract with the National Aeronautics and Space Administration.

  19. Magnetic Field Generation through Angular Momentum Exchange between Circularly Polarized Radiation and Charged Particles

    Energy Technology Data Exchange (ETDEWEB)

    G. Shvets; N.J. Fisch; J.-M. Rax

    2002-01-18

    The interaction between circularly polarized (CP) radiation and charged particles can lead to generation of magnetic field through an inverse Faraday effect. The spin of the circularly polarized electromagnetic wave can be converted into the angular momentum of the charged particles so long as there is dissipation. We demonstrate this by considering two mechanisms of angular momentum absorption relevant for laser-plasma interactions: electron-ion collisions and ionization. The precise dissipative mechanism, however, plays a role in determining the efficiency of the magnetic field generation.

  20. Inelastic process observed in charge-exchange reactions of 56Fe at 500 MeV/u

    Directory of Open Access Journals (Sweden)

    Momota S.

    2014-03-01

    Full Text Available The inelastic (IE component of the reaction product, which is produced through charge-exchange reactions at relativistic energies of E ~ 1 GeV/u, is one of the hopeful probes used to study the nuclear medium effect on Δ excitation. In the present study, the longitudinal-momentum (PL distribution of 56Co, produced by bombarding C-and CH2-target with a primary beam of 56Fe at E=500 MeV/u, was observed by means of the spectrometer at HIMAC facility. The IE peak of 56Co, produced from H and C targets, was successfully observed in energy transfer spectrum. The behaviors of the IE peaks are consistent with those observed in previous experiments. A remarkable reduction of the energy transfer for the IE process was also observed with C target compared with H target. The present results have shown the feasibility to investigate the energy transfer in charge-exchange reactions for heavy reaction system at the energy down to 500 MeV/u.

  1. Local charge exchange of He{sup +} ions at Aluminum surfaces

    Energy Technology Data Exchange (ETDEWEB)

    Riccardi, P., E-mail: pierfrancesco.riccardi@fis.unical.it [Dipartimento di Fisica, Università della Calabria and INFN – Gruppo collegato di Cosenza, Via P. Bucci cubo 33C, Arcavacata di Rende, Cosenza (Italy); Sindona, A. [Dipartimento di Fisica, Università della Calabria and INFN – Gruppo collegato di Cosenza, Via P. Bucci cubo 33C, Arcavacata di Rende, Cosenza (Italy); Dukes, C.A. [Laboratory for Astrophysics and Surface Physics, Materials Science and Engineering University of Virginia, Charlottesville, VA 22904 (United States)

    2017-04-04

    We report on experiments designed to observe the correlation between the autoionization of doubly excited helium atoms and the Auger decay of 2p vacancies in Al. The autoionizing states are formed when incident He{sup +*} and He{sup ++} are neutralized by resonant electron capture at the surface. 2p excitation in Al occurs in dielectronic charge transfer during the close encounter of an excited helium ion and an Al atom. These results clarify the mechanism for Al-2p excitation in the case of singly charged ground state He{sup +}(1s) ion impact, where the dielectronic transition occurs after promotion of the 1s electron of incoming ions. - Highlights: • We observe the correlation between autoionization of doubly excited helium atoms and the Auger decay of 2p vacancies in Al. • 2p excitation in Al occurs in dielectronic charge transfer during the close encounter of an excited helium ion and an Al atom. • These results clarify the mechanism for Al-2p excitation in the case of singly charged ground state He{sup +}(1s) ion impact.

  2. The velocity dependence of X-ray emission due to Charge Exchange: Applications in the Cygnus Loop

    Science.gov (United States)

    Cumbee, Renata; Lyons, David; Mullen, Patrick; Shelton, Robin L.; Stancil, Phillip C.; Schultz, David R.

    2016-04-01

    The fundamental collisional process of charge exchange (CX) has been been established as a primary source of X-ray emission from the heliosphere [1], planetary exospheres [2], and supernova remnants [3,4]. In this process, X-ray emission results from the capture of an electron by a highly charged ion from a neutral atom or molecule, to form a highly-excited, high charge state ion. As the captured electron cascades down to the lowest energy level, photons are emitted, including X-rays.To provide reliable CX-induced X-ray spectral models to realistically simulate high-energy astrophysical environments, line ratios and spectra are computed using theoretical CX cross-sections obtained with the multi-channel Landau-Zener, atomic-orbital close-coupling, and classical-trajectory Monte Carlo methods for various collisional velocities. Collisions of bare and H-like C to Al ions with H, He, and H2 are considered. Using these line ratios, XSPEC models of CX emission in the northeast rim of the Cygnus Loop supernova remnant will be shown as an example with ion velocity dependence.[1] Henley, D. B. & Shelton, R. L. 2010, ApJSS, 187, 388[2] Dennerl, K. et al. 2002, A&A 386, 319[3] Katsuda, S. et al. 2011, ApJ 730 24[4] Cumbee, R. S. et al. 2014, ApJ 787 L31

  3. Ion Mobility Spectrometry-Hydrogen Deuterium Exchange Mass Spectrometry of Anions: Part 2. Assessing Charge Site Location and Isotope Scrambling.

    Science.gov (United States)

    Khakinejad, Mahdiar; Kondalaji, Samaneh Ghassabi; Donohoe, Gregory C; Valentine, Stephen J

    2016-03-01

    Ion mobility spectrometry (IMS) coupled with gas-phase hydrogen deuterium exchange (HDX)-mass spectrometry (MS) and molecular dynamic simulations (MDS) has been used for structural investigation of anions produced by electrospraying a sample containing a synthetic peptide having the sequence KKDDDDDIIKIIK. In these experiments the potential of the analytical method for locating charge sites on ions as well as for utilizing collision-induced dissociation (CID) to reveal the degree of deuterium uptake within specific amino acid residues has been assessed. For diffuse (i.e., more elongated) [M - 2H](2-) ions, decreased deuterium content along with MDS data suggest that the D4 and D6 residues are charge sites, whereas for the more diffuse [M - 3H](3-) ions, the data suggest that the D4, D7, and the C-terminus are deprotonated. Fragmentation of mobility-selected, diffuse [M - 2H](2-) ions to determine deuterium uptake at individual amino acid residues reveals a degree of deuterium retention at incorporation sites. Although the diffuse [M - 3H](3-) ions may show more HD scrambling, it is not possible to clearly distinguish HD scrambling from the expected deuterium uptake based on a hydrogen accessibility model. The capability of the IMS-HDX-MS/MS approach to provide relevant details about ion structure is discussed. Additionally, the ability to extend the approach for locating protonation sites on positively-charged ions is presented.

  4. Dual capillary tube / heat exchanger in combination with cycle priming for reducing charge migration

    Science.gov (United States)

    Gomes, Alberto Regio; Kuehl, Steven J.; Litch, Andrew D.; Wu, Guolian

    2017-07-04

    A refrigerator appliance including a multi-capacity compressor and a refrigerant circuit with two conduits and pressure reducing devices arranged in parallel between an evaporator and a condenser. Refrigerant can flow through one, both or none of the conduits and pressure reducing devices. The appliance also has a heat exchanger in contact with either one pressure reducing device, or one conduit between the pressure reducing device and the valve system. The appliance also includes a controller for priming the compressor above a nominal capacity for a predetermined or calculated duration at the beginning of an ON-cycle.

  5. Charge exchange recombination detection of low-Z and medium-Z impurities in the extreme UV using a digital lock-in technique.

    Science.gov (United States)

    Brooks, N H; Burrell, K H; Isler, R C; Meyer, O; Pablant, N A

    2010-10-01

    More sensitive detection of charge exchange recombination lines from low-Z elements, and first-time detection from the medium-Z elements nickel and copper, has been achieved in DIII-D plasmas with a digital lock-in technique. That portion of the extreme UV spectrum varying synchronously in time with the square-wave modulation of a high energy, neutral heating beam is extracted by forming a scalar product of a correlation function with the data record of each pixel in the linear array detector. The usual, dense array of collisionally excited, metallic lines from the tokamak plasma is strongly suppressed, leaving only a sparse spectrum of lines dominated by charge exchange recombination transitions from fully stripped, low-Z elements. In plasmas with high metal content, charge exchange recombination lines from the Li-like ions of nickel and copper have been positively identified.

  6. Chromatography of proteins on charge-variant ion exchangers and implications for optimizing protein uptake rates.

    Science.gov (United States)

    Langford, John F; Xu, Xuankuo; Yao, Yan; Maloney, Sean F; Lenhoff, Abraham M

    2007-09-07

    Intraparticle transport of proteins usually represents the principal resistance controlling their uptake in preparative separations. In ion-exchange chromatography two limiting models are commonly used to describe such uptake: pore diffusion, in which only free protein in the pore lumen contributes to transport, and homogeneous diffusion, in which the transport flux is determined by the gradient in the total protein concentration, free or adsorbed. Several studies have noted a transition from pore to homogeneous diffusion with increasing ionic strength in some systems, and here we investigate the mechanistic basis for this transition. The studies were performed on a set of custom-synthesized methacrylate-based strong cation exchangers differing in ligand density into which uptake of two proteins was examined using confocal microscopy and frontal loading experiments. We find that the transition in uptake mechanism occurs in all cases studied, and generally coincides with an optimum in the dynamic binding capacity at moderately high flow rates. The transition appears to occur when protein-surface attraction is weakened sufficiently, and this is correlated with the isocratic retention factor k' for the system of interest: the transition occurs in the vicinity of k' approximately 3000. This result, which may indicate that adsorption is sufficiently weak to allow the protein to diffuse along or near the surface, provides a predictive basis for optimizing preparative separations using only isocratic retention data.

  7. What Can Be Learned from X-Ray Spectroscopy Concerning Hot Gas in the Local Bubble and Charge Exchange Processes?

    Science.gov (United States)

    Snowden, S. L.

    2008-01-01

    Both solar wind charge exchange emission and diffuse thermal emission from the Local Bubble are strongly dominated in the soft X-ray band by lines from highly ionized elements. While both processes share many of the same lines, the spectra should differ significantly due to the different production mechanisms, abundances, and ionization states. Despite their distinct spectral signatures, current and past observatories have lacked the spectral resolution to adequately distinguish between the two sources. High-resolution X-ray spectroscopy instrumentation proposed for future missions has the potential to answer fundamental questions such as whether there is any hot plasma in the Local Hot Bubble, and if so, what are the abundances of the emitting plasma and whether the plasma is in equilibrium. Such instrumentation will provide dynamic information about the solar wind including data on ion species which are currently difficult to track. It will also make possible remote sensing of the solar wind.

  8. Charge Exchange in Low-Energy H, D + C4+ Collisions with Full Account of Electron Translation

    Directory of Open Access Journals (Sweden)

    N. Vaeck

    2002-03-01

    Full Text Available We report the application of the quantum approach, which takes full account of electron translation at low collisional energies, to the charge exchange process H, D + C4+ → H+, D+ + C3+(3s; 3p; 3d. The partial and the total integral cross sections of the process are calculated in the energy range from 1 till 60 eV/amu. It is shown that the present results are independent from the upper integration limit for numerical solution of the coupled channel equations although nonadiabatic couplings remain nonzero up to infinity. The calculated partial and total cross sections are in agreement with the previous low-energy calculations and the available experimental data. It is shown that for low collisional energies the isotopic effect takes place. The observed effect is explained in terms of the nonadiabatic dynamics.

  9. A microscopic approach based on particle-vibration coupling: application to charge-exchange transitions and multiplets in odd nuclei

    Directory of Open Access Journals (Sweden)

    Colò Gianluca

    2016-01-01

    Full Text Available In this contribution, we shall describe a formalism that goes beyond the simple time-dependent mean field and is based on particle-vibration coupling (PVC. Such a formalism has been developed with the idea of being self-consistent. It makes use of Skyrme effective forces, and has been used for several applications. We will focus on charge-exchange transitions, namely we will show that our model describes well both the Gamow-Teller giant resonance width, and the low-lying transitions associated with β-decay. In this latter case, including PVC produces a significant improvement of the half-lives obtained at mean-field level, and leads to a good agreement with experimental data. We will end by discussing particle-phonon multiplets in odd nuclei.

  10. Numerical solutions to a kinetic model for the plasma-sheath problem with charge exchange collisions of ions.

    Science.gov (United States)

    Sternovsky, Z; Downum, K; Robertson, S

    2004-08-01

    A kinetic model of the plasma-sheath problem is presented that includes the effects of charge-exchange collisions of the ion. The collisions are modeled as a sink for accelerated ions and as a source of cold ions. Solutions are obtained by numerical integration of Poisson's equation from a point near the plasma midplane to the wall. In the quasineutral region, these solutions agree with earlier analytic work. As the mean free path is decreased, the current density at the wall decreases and the potential profile in the quasineutral region shows a smooth transition from a parabolic profile to a nearly cubic profile determined by the ion mobility. An approximate expression is found for the ion flux to the wall in the collisional limit.

  11. Charge exchange fluxes of ripple trapped slowing-down ions during L-to-H transition and ELMs

    Energy Technology Data Exchange (ETDEWEB)

    Herrmann, W. [Association Euratom-Max-Planck-Institut fuer Plasmaphysik, Garching (Germany); Fahrbach, H.U. [Association Euratom-Max-Planck-Institut fuer Plasmaphysik, Garching (Germany); Kaufmann, M. [Association Euratom-Max-Planck-Institut fuer Plasmaphysik, Garching (Germany); Lackner, K. [Association Euratom-Max-Planck-Institut fuer Plasmaphysik, Garching (Germany); Ryter, F. [Association Euratom-Max-Planck-Institut fuer Plasmaphysik, Garching (Germany); Zohm, H. [Association Euratom-Max-Planck-Institut fuer Plasmaphysik, Garching (Germany); Albrecht, M. [Association Euratom-Max-Planck-Institut fuer Plasmaphysik, Garching (Germany); Alexander, M. [Association Euratom-Max-Planck-Institut fuer Plasmaphysik, Garching (Germany); Asmussen, K. [Association Euratom-Max-Planck-Institut fuer Plasmaphysik, Garching (Germany); Behler, K. [Association Euratom-Max-Planck-Institut fuer Plasmaphysik, Garching (Germany); Behringer, K. [Association Euratom-Max-Planck-Institut fuer Plasmaphysik, Garching (Germany); Bessenrodt-Weberpals, M. [Association Euratom-Max-Planck-Institut fuer Plasmaphysik, Garching (Germany); Bosch, H.S. [Association Euratom-Max-Planck-Institut fuer Plasmaphysik, Garching (Germany); Buechl, K. [Association Euratom-Max-Planck-Institut fuer Plasmaphysik, Garching (Germany); Carlson, A. [Association Euratom-Max-Planck-Institut fuer Plasmaphysik, Garching (Germany); Coster, D. [Association Euratom-Max-Planck-Institut fuer Plasmaphysik, Garching (Germany); Blank, H.J. de [Association Euratom-Max-Planck-Institut fuer Plasmaphysik, Garching (Germany); Drube, R. [Association Euratom-Max-Planck-Institut fuer Plasmaphysik, Garching (Germany); Dux, R. [Association Euratom-Max-Planck-Institut fuer Plasmaphysik, Garching (Germany); Engelhardt, W. [Association Euratom-Max-Planck-Institut fuer Plasmaphysik, Garching (Germany); Gehre, O. [Association Euratom-Max-Planck-Institut fuer Plasmaphysik, Garching (Germany)

    1995-06-01

    Neutral fluxes from charge exchange with ripple-trapped particles show a remarkably different behaviour during L and H mode; their measurement provides a new diagnostic for the mode discrimination of the plasma. A possible reason for the changes of the fluxes is the action of a radial electric field. This seems to grow steadily after the L-to-H transition with a strong increase (jump in the ms range) at the transition to the quiescent H-mode. During ELMs the fluxes reduce to L-mode level. Measurements with 100 {mu} time resolution show no action in the fluxes piror to the change in the D{sub {alpha}}-signal at the start of type 1 ELM. (orig.)

  12. Optimization and application of cooled avalanche photodiodes for spectroscopic fluctuation measurements with ultra-fast charge exchange recombination spectroscopy

    Science.gov (United States)

    Truong, D. D.; Fonck, R. J.; McKee, G. R.

    2016-11-01

    The Ultra-Fast Charge Exchange Recombination Spectroscopy (UF-CHERS) diagnostic is a highly specialized spectroscopic instrument with 2 spatial channels consisting of 8 spectral channels each and a resolution of ˜0.25 nm deployed at DIII-D to measure turbulent ion temperature fluctuations. Charge exchange emissions are obtained between 528 and 530 nm with 1 μs time resolution to study plasma instabilities. A primary challenge of extracting fluctuation measurements from raw UF-CHERS signals is photon and electronic noise. In order to reduce dark current, the Avalanche Photodiode (APD) detectors are thermo-electrically cooled. State-of-the-art components are used for the signal amplifiers and conditioners to minimize electronic noise. Due to the low incident photon power (≤1 nW), APDs with a gain of up to 300 are used to optimize the signal to noise ratio. Maximizing the APDs' gain while minimizing the excess noise factor (ENF) is essential since the total noise of the diagnostic sets a floor for the minimum level of detectable broadband fluctuations. The APDs' gain should be high enough that photon noise dominates electronic noise, but not excessive so that the ENF overwhelms plasma fluctuations. A new generation of cooled APDs and optimized preamplifiers exhibits significantly enhanced signal-to-noise compared to a previous generation. Experiments at DIII-D have allowed for characterization and optimization of the ENF vs. gain. A gain of ˜100 at 1700 V is found to be near optimal for most plasma conditions. Ion temperature and toroidal velocity fluctuations due to the edge harmonic oscillation in quiescent H-mode plasmas are presented to demonstrate UF-CHERS' capabilities.

  13. Career Development of College Students through Part-Time Work: The Role of Leader-Member Exchange and Taking Charge Behavior

    OpenAIRE

    Tomoki Sekiguchi

    2010-01-01

    This study examines the potential benefit of college students' part-time work on their career development by focusing on leader-member exchange (LMX) and taking charge behavior in the workplace. Using a sample of Japanese college students, results from this study indicate that taking charge behavior in part-time work mediates the relationship between LMX quality with supervisors and career development (focus of career exploration, self-efficacy toward postcollege employment and proactive care...

  14. Mechanistic Modeling Based PAT Implementation for Ion-Exchange Process Chromatography of Charge Variants of Monoclonal Antibody Products.

    Science.gov (United States)

    Kumar, Vijesh; Rathore, Anurag S

    2017-09-01

    Process chromatography is typically used to remove product related impurities and variants that have very similar physicochemical properties to the product. Baseline separation may not be achieved in most cases due to high protein loading and thus, pooling of the elution peak can be challenging for maximizing yield and achieving consistency in product quality. Batch-to-batch variability in quality of the feed material also occurs in commercial manufacturing. Mechanistic modeling of process chromatography, though non-trivial, can be an enabler for implementation of Process Analytical Technology. This paper presents one such application involving prediction of the impact of variability in feed quality and in gradient shape on separation of charge variants by cation exchange process chromatography and thereby facilitating feed forward control. Five batches having different compositions of charge variants have been used to demonstrate the proposed pooling strategy based on simulated chromatograms and the outcome has been compared to offline pooling based on fractionation. For all the conditions examined and for the desired target of main product (67%), the proposed approach resulted in remarkable consistency in product quality (67 ± 2%) while delivering a yield of greater than 90%. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  15. Experimental investigation of the reaction of helium ions with dimethyl ether: stereodynamics of the dissociative charge exchange process.

    Science.gov (United States)

    Cernuto, Andrea; Tosi, Paolo; Martini, Luca Matteo; Pirani, Fernando; Ascenzi, Daniela

    2017-08-02

    The fate of dimethyl ether (DME, CH3OCH3) in collisions with He+ ions is of high relevance for astrochemical models aimed at reproducing the abundances of complex organic molecules in the interstellar medium. Here we report an investigation on the reaction of He+ ions with DME carried out using a Guided Ion Beam Mass Spectrometer (GIB-MS), which allows the measurement of reactive cross-sections and branching ratios (BRs) as a function of the collision energy. We obtain insights into the dissociative charge (electron) exchange mechanism by investigating the nature of the non-adiabatic transitions between the relevant potential energy surfaces (PESs) in an improved Landau-Zener approach. We find that the large interaction anisotropy could induce a pronounced orientation of the polar DME molecule in the electric field generated by He+ so that at short distances the collision complex is confined within pendular states, a particular case of bending motion, which gives rise to intriguing stereodynamic effects. The positions of the intermolecular potential energy curve crossings indicate that He+ captures an electron from an inner valence orbital of DME, thus causing its dissociation. In addition to the crossing positions, the symmetry of the electron density distribution of the involved DME orbitals turns out to be a further major point affecting the probability of electron transfer. Thus, the anisotropy of the intermolecular interaction and the electron densities of the orbitals involved in the reaction are the key "ingredients" for describing the dynamics of this dissociative charge transfer.

  16. Impurity line emission due to thermal charge exchange in JET edge plasmas

    Energy Technology Data Exchange (ETDEWEB)

    Maggi, C.F.; Horton, L.D.; Koenig, R.; Stamp, M. [Commission of the European Communities, Abingdon (United Kingdom). JET Joint Undertaking; Summers, H.P. [Strathclyde Univ., Glasgow (United Kingdom)

    1994-07-01

    High n-shell emission from hydrogen-like carbon (C VI, n=8-7) has been routinely observed from the plasma edge of JET. By comparing the measured spectral line intensities with the signals predicted by advanced atomic physics modelling of carbon and hydrogen radiation, integrated with modelling of the divertor and edge plasma, it is concluded that charge transfer from excited state hydrogen donors into fully stripped carbon ions can account for the observed spectral emission, but that the hydrogen distribution and to a lesser extent the carbon distribution away from the strike zone predicted by the transport model are too low. Data presented are those of three upper X-point discharges, where the target material was carbon. 5 refs., 1 fig., 3 tabs.

  17. Charge-exchange-induced two-electron satellite transitions from autoionizing levels in dense plasmas.

    Science.gov (United States)

    Rosmej, F B; Griem, H R; Elton, R C; Jacobs, V L; Cobble, J A; Faenov, A Ya; Pikuz, T A; Geissel, M; Hoffmann, D H H; Süss, W; Uskov, D B; Shevelko, V P; Mancini, R C

    2002-11-01

    Order-of-magnitude anomalously high intensities for two-electron (dielectronic) satellite transitions, originating from the He-like 2s(2) 1S0 and Li-like 1s2s(2) (2)S(1/2) autoionizing states of silicon, have been observed in dense laser-produced plasmas at different laboratories. Spatially resolved, high-resolution spectra and plasma images show that these effects are correlated with an intense emission of the He-like 1s3p 1P-1s(2) 1S lines, as well as the K(alpha) lines. A time-dependent, collisional-radiative model, allowing for non-Maxwellian electron-energy distributions, has been developed for the determination of the relevant nonequilibrium level populations of the silicon ions, and a detailed analysis of the experimental data has been carried out. Taking into account electron density and temperature variations, plasma optical-depth effects, and hot-electron distributions, the spectral simulations are found to be not in agreement with the observations. We propose that highly stripped target ions (e.g., bare nuclei or H-like 1s ground-state ions) are transported into the dense, cold plasma (predominantly consisting of L- and M-shell ions) near the target surface and undergo single- and double-electron charge-transfer processes. The spectral simulations indicate that, in dense and optically thick plasmas, these charge-transfer processes may lead to an enhancement of the intensities of the two-electron transitions by up to a factor of 10 relative to those of the other emission lines, in agreement with the spectral observations.

  18. Structure-property relationships in non-epitaxial chalcogenide heterostructures: the role of interface density on charge exchange

    Science.gov (United States)

    Bauers, S. R.; Ditto, J.; Moore, D. B.; Johnson, D. C.

    2016-07-01

    A homologous series of quasi-2D ([PbSe]1+δ)m(TiSe2)m nanolayered heterostructures are prepared via self-assembly of designed precursors with 1 rock salt structured PbSe layers alternating with TiSe2 layers, and that grain size increases with m. The compounds are all metallic with upturns in resistivity at low temperature suggesting electron localization, with room temperature resistivity of 1-3 10-5 Ω m, negative Hall coefficients and Seebeck coefficients between -50 and -100 μV K-1. A decrease in the mobile carrier concentration with temperature is observed for all m and the rate increases with increasing low-dimensionality. Decreasing the interface density also decreases the average carrier concentration while increasing the electron mobility. The Seebeck coefficients systematically increase in magnitude as m is increased, but the net effect to the power factor is small due to a compensating increase in resistivity. The observed transport behavior is not described by the simple rigid band models with charge transfer between constituents used previously. Charge exchange between constituents stabilizes the intergrowth, but also introduces mobile carriers and interfacial band bending that must play a role in the transport behavior of the heterostructures. As chemical potentials equilibrate in high m heterostructures there is a decrease in total coulombic stabilization as there are fewer interfaces, so m = 1 is likely to be most stable. This rationalizes why the structurally similar misfit layer compounds with m = 1 are often the only intergrowths that can be prepared. Charge transfer and band bending at interfaces should occur in other heterostructures with similar type II broken-gap band alignments and are important considerations regarding both their stability and transport properties.

  19. Charge exchange and energy loss of slowed down heavy ions channeled in silicon crystals; Echanges de charge et perte d'energie d'ions lourds ralentis, canalises dans des cristaux de silicium

    Energy Technology Data Exchange (ETDEWEB)

    Testa, E

    2005-10-15

    This work is devoted to the study of charge exchange processes and of the energy loss of highly charged heavy ions channeled in thin silicon crystals. The two first chapters present the techniques of heavy ion channeling in a crystal, the ion-electron processes and the principle of our simulations (charge exchange and trajectory of channeled ions). The next chapters describe the two experiments performed at the GSI facility in Darmstadt, the main results of which follow: the probability per target atom of the mechanical capture (MEC) of 20 MeV/u U{sup 91+} ions as a function of the impact parameter (with the help of our simulations), the observation of the strong polarization of the target electron gas by the study of the radiative capture and the slowing down of Pb{sup 81+} ions from 13 to 8,5 MeV/u in channeling conditions for which electron capture is strongly reduced. (author)

  20. Precision evaluation of the Ga-71(nu(e),e(-)) solar neutrino capture rate from the (He-3,t) charge-exchange reaction

    NARCIS (Netherlands)

    Frekers, D.; Adachi, T.; Akimune, H.; Alanssari, M.; Brown, B. A.; Cleveland, B. T.; Ejiri, H.; Fujita, H.; Fujita, Y.; Fujiwara, M.; Gavrin, V. N.; Harakeh, M. N.; Hatanaka, K.; Holl, M.; Iwamoto, C.; Lennarz, A.; Okamoto, A.; Okamura, H.; Suzuki, T.; Tamii, A.

    2015-01-01

    A precision measurement of the Ga-71(He-3,t)Ge-71 charge-exchange reaction was performed. By using a rather complete set of theoretical form factors to describe the cross-section angular distributions over a large angular range, the Gamow-Teller strength distribution up to the effective

  1. CROSS-SECTIONS FOR HEII(N=4-]N=3) AND CVI(N=7-]N=6) EMISSION FOR CHARGE-EXCHANGE DIAGNOSTICS AT TOKAMAKS

    NARCIS (Netherlands)

    BLIEK, FW; FOLKERTS, HO; MORGENSTERN, R; HOEKSTRA, R; MENG, L; OLSON, RE; FRITSCH, W; VONHELLERMANN, M; SUMMERS, HP

    Charge exchange spectroscopy of fusion plasmas relies on an accurate knowledge of state selective electron capture cross sections. Here we discuss the gathering and evaluation of such cross sections, with emphasis on electron capture by He2+ and C6+. The influence of metastable atoms on the plasma

  2. Chandra observations of comet 2P/Encke 2003 : First detection of a collisionally thin, fast solar wind charge exchange system

    NARCIS (Netherlands)

    Lisse, CM; Christian, DJ; Dennerl, K; Wolk, SJ; Bodewits, Dennis; Hoekstra, Ronnie; Combi, MR; Makinen, T; Dryer, M; Fry, CD; Weaver, H

    2005-01-01

    We report the results of 15 hr of Chandra observations of comet 2P/Encke 2003 on November 24. X-ray emission from comet Encke was resolved on scales of 500-40,000 km, with unusual morphology due to the presence of a low-density, collisionally thin (to charge exchange) coma. A light curve with

  3. Benchmarking charge exchange theory in the dawning era of space-born high-resolution X-ray spectrometers

    Science.gov (United States)

    Betancourt-Martinez, Gabriele

    2017-08-01

    Charge Exchange (CX) is a process in which a highly charged ion captures one or more electrons from a neutral atom or molecule into an excited state during a close interaction. The electron's subsequent radiative cascade to the ground state produces diagnostic line emission in the X-ray band. CX with solar wind ions occurs frequently in the solar system, and CX may also occur astrophysically. In order to properly identify CX in astrophysical spectra and make use of its diagnostic properties, we must be able to model the emission. Theoretical treatments of CX are often computationally expensive, experimental benchmarks at high resolution are fairly scarce, and there is often poor agreement between the two. This dissertation seeks to build a better understanding of the mechanics and spectral signatures of CX through high-resolution experimental data paired with theoretical calculations of CX. Chapter 1 outlines the necessary ingredients for modeling and identifying CX spectra, describes several astrophysical environments in which CX has been observed or postulated to occur, and presents some of the challenges we are facing in identifying and understanding this emission. Chapter 2 describes the theoretical and computational tools used in this work. Chapter 3 discusses the experimental tools and facilities we use, namely an Electron Beam Ion Trap (EBIT) and an X-ray microcalorimeter. Chapter 4 presents experimental K-shell data that highlights both the subtle nature of the CX interaction and the difficulty in including those nuances in spectral synthesis codes. Chapter 5 presents the first high-resolution L-shell CX spectra of Ne-like Ni and describes what we can learn from these results. In Chapter 6, we take these data a step further and present a pipeline to calculate relative state-selective capture cross sections, previously only available from theoretical modeling. We then compare some of our results to theory. In Chapter 7, we discuss several future steps for

  4. Overview on R and D and design activities for the ITER core charge exchange spectroscopy diagnostic system

    Energy Technology Data Exchange (ETDEWEB)

    Biel, W., E-mail: w.biel@fz-juelich.de [Institut fuer Energieforschung - Plasmaphysik, Forschungszentrum Juelich Gmbh, Association EURATOM-FZJ, member of Trilateral Euregio Cluster, 52425 Juelich (Germany); Baross, T. [KFKI RMKI, EURATOM Association, PO Box 49, H-1521 Budapest (Hungary); Bourauel, P. [Institut fuer Energieforschung - Plasmaphysik, Forschungszentrum Juelich Gmbh, Association EURATOM-FZJ, member of Trilateral Euregio Cluster, 52425 Juelich (Germany); Dunai, D. [KFKI RMKI, EURATOM Association, PO Box 49, H-1521 Budapest (Hungary); Durkut, M. [TNO Science and Industry, Partner in ITER-NL, P.O. Box 155, 2600 AD Delft (Netherlands); Erdei, G. [BME, EURATOM Association, PO Box 91, H-1521 Budapest (Hungary); Hawkes, N. [Association EURATOM/CCFE, OX14 3DB Abingdon (United Kingdom); Hellermann, M. von [FOM-Institute for Plasma Physics Rijnhuizen, Association EURATOM-FOM, partner in the Trilateral Euregio Cluster and ITER-NL, P.O. Box 1207, 3430 BE Nieuwegein (Netherlands); Hogenbirk, A. [Nuclear Research and Consultancy Group V.o.F., Petten (Netherlands); Jaspers, R. [Department of Applied Physics, Eindhoven University of Technology (Netherlands); Kiss, G. [Institut fuer Energieforschung - Plasmaphysik, Forschungszentrum Juelich Gmbh, Association EURATOM-FZJ, member of Trilateral Euregio Cluster, 52425 Juelich (Germany); Klinkhamer, F. [TNO Science and Industry, Partner in ITER-NL, P.O. Box 155, 2600 AD Delft (Netherlands); Koning, J.F. [FOM-Institute for Plasma Physics Rijnhuizen, Association EURATOM-FOM, partner in the Trilateral Euregio Cluster and ITER-NL, P.O. Box 1207, 3430 BE Nieuwegein (Netherlands); Kotov, V.; Krasikov, Y.; Krimmer, A. [Institut fuer Energieforschung - Plasmaphysik, Forschungszentrum Juelich Gmbh, Association EURATOM-FZJ, member of Trilateral Euregio Cluster, 52425 Juelich (Germany)

    2011-10-15

    The ITER core charge exchange recombination spectroscopy (core CXRS) diagnostic system is designed to provide experimental access to various measurement quantities in the ITER core plasma such as ion densities, temperatures and velocities. The implementation of the approved CXRS diagnostic principle on ITER faces significant challenges: First, a comparatively low CXRS signal intensity is expected, together with a high noise level due to bremsstrahlung, while the requested measurement accuracy and stability for the core CXRS system go far beyond the level commonly achieved in present-day fusion experiments. Second, the lifetime of the first mirror surface is limited due to either erosion by fast particle bombardment or deposition of impurities. Finally, the hostile technical environment on ITER imposes challenging boundary conditions for the diagnostic integration and operation, including high neutron loads, electro-magnetic loads, seismic events and a limited access for maintenance. A brief overview on the R and D and design activities for the core CXRS system is presented here, while the details are described in parallel papers.

  5. Using (18)O/(16)O exchange to probe an equilibrium space-charge layer at the surface of a crystalline oxide: method and application.

    Science.gov (United States)

    De Souza, Roger A; Martin, Manfred

    2008-05-07

    The use of an (18)O/(16)O exchange experiment as a means for probing surface space-charge layers in oxides is examined theoretically and experimentally. On the basis of a theoretical treatment, isotope penetration profiles are calculated for (18)O/(16)O exchange across a gas-solid interface and subsequent diffusion of the labelled isotope through an equilibrium space-charge layer depleted of mobile oxygen vacancies and into a homogeneous bulk phase. Profiles calculated for a range of conditions all have a characteristic shape: a sharp drop in isotope fraction close to the surface followed by a normal bulk diffusion profile. Experimental (18)O profiles in an exchanged (001) oriented single crystal of Fe-doped SrTiO(3) were measured by time-of-flight secondary ion mass spectrometry (ToF-SIMS). By extracting the space-charge potential from such profiles, we demonstrate that this method allows the spatially resolved characterization of space-charge layers at the surfaces of crystalline oxides under thermodynamically well-defined conditions.

  6. Core-ion temperature measurement of the ADITYA tokamak using passive charge exchange neutral particle energy analyzer

    Energy Technology Data Exchange (ETDEWEB)

    Pandya, Santosh P.; Ajay, Kumar; Mishra, Priyanka; Dhingra, Rajani D.; Govindarajan, J. [Institute for Plasma Research, Bhat, Gandhinagar 382 428, Gujarat (India)

    2013-02-15

    Core-ion temperature measurements have been carried out by the energy analysis of passive charge exchange (CX) neutrals escaping out of the ADITYA tokamak plasma (minor radius, a= 25 cm and major radius, R= 75 cm) using a 45 Degree-Sign parallel plate electrostatic energy analyzer. The neutral particle analyzer (NPA) uses a gas cell configuration for re-ionizing the CX-neutrals and channel electron multipliers (CEMs) as detectors. Energy calibration of the NPA has been carried out using ion-source and {Delta}E/E of high-energy channel has been found to be {approx}10%. Low signal to noise ratio (SNR) due to VUV reflections on the CEMs was identified during the operation of the NPA with ADITYA plasma discharges. This problem was rectified by upgrading the system by incorporating the additional components and arrangements to suppress VUV radiations and improve its VUV rejection capabilities. The noise rejection capability of the NPA was experimentally confirmed using a standard UV-source and also during the plasma discharges to get an adequate SNR (>30) at the energy channels. Core-ion temperature T{sub i}(0) during flattop of the plasma current has been measured to be up to 150 eV during ohmically heated plasma discharges which is nearly 40% of the average core-electron temperature (typically T{sub e}(0) {approx} 400 eV). The present paper describes the principle of tokamak ion temperature measurement, NPA's design, development, and calibration along with the modifications carried out for minimizing the interference of plasma radiations in the CX-spectrum. Performance of the NPA during plasma discharges and experimental results on the measurement of ion-temperature have also been reported here.

  7. $\\beta$- decay of $^{58}$Zn. A critical test for the charge-exchange reaction as a probe for the $\\beta$- decay strength distribution

    CERN Multimedia

    2002-01-01

    % IS353 \\\\ \\\\ Due to its importance in fundamental physics and astrophysics, a great effort both theoretically and experimentally is devoted to study Gamow Teller (GT)-strength. The GT-strength and its distribution play a key role in late stellar evolution. During the pre-supernova core-collapse of massive stars, the electron capture and nuclear $\\beta$ -decay determine the electron-to-baryon ratio, which influences the infall dynamics and the mass of the final core. The cross-section of the charge-exchange reaction at forward angles with energies above 100~MeV is expected to be proportional to the squares of Fermi and GT matrix elements. This proportionality should provide a Q-value free method to probe the weak interaction strength and renormalization effects in nuclei. Thus charge-exchange reactions are often used to determine the experimental GT-strength. However, the connection between the GT-strength and the cross-section of the charge-exchange reaction is partially model-dependent and the question aris...

  8. Validation of a pH gradient-based ion-exchange chromatography method for high-resolution monoclonal antibody charge variant separations.

    Science.gov (United States)

    Rea, Jennifer C; Moreno, G Tony; Lou, Yun; Farnan, Dell

    2011-01-25

    Ion-exchange chromatography is widely used for profiling the charge heterogeneity of proteins, including monoclonal antibodies. Despite good resolving power and robustness, ionic strength-based ion-exchange separations are product-specific and time-consuming to develop. We have previously reported a novel pH-based separation of proteins by cation exchange chromatography that was multi-product, high-resolution, and robust against variations in sample matrix salt concentration and pH. In this study, a pH gradient-based separation method using cation exchange chromatography was evaluated in a mock validation. This method was shown to be robust for monoclonal antibodies and suitable for its intended purpose of charge heterogeneity analysis. Simple mixtures of defined buffer components were used to generate the pH gradients that separated closely related antibody species. Validation characteristics, such as precision and linearity, were evaluated. Robustness to changes in protein load, buffer pH and column oven temperature was demonstrated. The stability-indicating capability of this method was determined using thermally stressed antibody samples. In addition, intermediate precision was demonstrated using multiple instruments, multiple analysts, multiple column lots, and different column manufacturers. Finally, the precision for this method was compared to conventional ion-exchange chromatography and imaged capillary isoelectric focusing. These results demonstrate the superior precision and robustness of this multi-product method, which can be used for the high-throughput evaluation of in-process and final product samples. Copyright © 2010 Elsevier B.V. All rights reserved.

  9. Folding model study of the charge-exchange scattering to the isobaric analog state and implication for the nuclear symmetry energy

    Energy Technology Data Exchange (ETDEWEB)

    Khoa, Dao T.; Thang, Dang Ngoc [VINATOM, Institute for Nuclear Science and Technique, Hanoi (Viet Nam); Loc, Bui Minh [VINATOM, Institute for Nuclear Science and Technique, Hanoi (Viet Nam); University of Pedagogy, Ho Chi Minh City (Viet Nam)

    2014-02-15

    The Fermi transition (ΔL = ΔS = 0 and ΔT = 1) between the nuclear isobaric analog states (IAS), induced by the charge-exchange (p, n) or ({sup 3}He, t) reaction, can be considered as ''elastic'' scattering of proton or {sup 3}He by the isovector term of the optical potential (OP) that flips the projectile isospin. The accurately measured (p, n) or ({sup 3}He, t) scattering cross section to the IAS can be used, therefore, to probe the isospin dependence of the proton or {sup 3}He optical potential. Within the folding model, the isovector part of the OP is determined exclusively by the neutron-proton difference in the nuclear densities and the isospin dependence of the effective nucleon-nucleon (NN) interaction. Because the isovector coupling explicitly links the isovector part of the proton or {sup 3}He optical potential to the cross section of the charge-exchange (p, n) or ({sup 3}He, t) scattering to the IAS, the isospin dependence of the effective (in-medium) NN interaction can be well tested in the folding model analysis of these charge-exchange reactions. On the other hand, the same isospin- and density-dependent NN interaction can also be used in a Hartree-Fock calculation of asymmetric nuclear matter, to estimate the nuclear matter energy and its asymmetry part (the nuclear symmetry energy). As a result, the fine-tuning of the isospin dependence of the effective NN interaction against the measured (p, n) or ({sup 3}He, t) cross sections should allow us to make some realistic prediction of the nuclear symmetry energy and its density dependence. (orig.)

  10. Effect of ligand exchange of Cu2ZnSnS4 nanocrystals on the charge transport and photovoltaic performance of nanostructured depleted bulk heterojunction solar cell

    Science.gov (United States)

    Zhang, Zhuo-Xi; Zhou, Zheng-Ji; Bai, Bing; Liu, Ming-Hua; Zhou, Wen-Hui; Kou, Dong-Xing; Wu, Si-Xin

    2015-12-01

    Cu2ZnSnS4 (CZTS) nanocrystals combining the advantage of feasible solution-phase synthesis and processing are perceived as promising materials for application in efficient, low-cost photovoltaic technology. Herein, we have got surfactant-free CZTS nanocrystals by a novel ligand exchange method, and the obtained CZTS nanocrystals were deposited onto ZnO nanorod arrays to construct depleted bulk heterojunction solar cell. The all-inorganic CZTS nanocrystal solar cells demonstrated a remarkable improvement in J sc (from 8.14 to 13.97 mA/cm2) and power conversion efficiency (from 1.83 to 3.34 %) compared with surfactant-capped CZTS nanocrystals. Using surface photovoltage spectrum, the influence of ligand exchange of CZTS nanocrystals on the charge transport and photovoltaic performance of the nanostructured CZTS solar cells was discussed.

  11. Design of a Fast Neutral He Beam System for Feasibility Study of Charge-Exchange Alpha-Particle Diagnostics in a Thermonuclear Fusion Reactor

    CERN Document Server

    Shinto, Katsuhiro; Kitajima, Sumio; Kiyama, Satoru; Nishiura, Masaki; Sasao, Mamiko; Sugawara, Hiroshi; Takenaga, Mahoko; Takeuchi, Shu; Wada, Motoi

    2005-01-01

    For alpha-particle diagnostics in a thermonuclear fusion reactor, neutralization using a fast (~2 MeV) neutral He beam produced by the spontaneous electron detachment of a He- is considered most promising. However, the beam transport of produced fast neutral He has not been studied, because of difficulty for producing high-brightness He- beam. Double-charge-exchange He- sources and simple beam transport systems were developed and their results were reported in the PAC99* and other papers.** To accelerate an intense He- beam and verify the production of the fast neutral He beam, a new test stand has been designed. It consists of a multi-cusp He+

  12. DXL: A Sounding Rocket Mission for the Study of Solar Wind Charge Exchange and Local Hot Bubble X-Ray Emission

    Science.gov (United States)

    Galeazzi, M.; Prasai, K.; Uprety, Y.; Chiao, M.; Collier, M. R.; Koutroumpa, D.; Porter, F. S.; Snowden, S.; Cravens, T.; Robertson, I.; hide

    2011-01-01

    The Diffuse X-rays from the Local galaxy (DXL) mission is an approved sounding rocket project with a first launch scheduled around December 2012. Its goal is to identify and separate the X-ray emission generated by solar wind charge exchange from that of the local hot bubble to improve our understanding of both. With 1,000 square centimeters proportional counters and grasp of about 10 square centimeters sr both in the 1/4 and 3/4 keV bands, DXL will achieve in a 5-minute flight what cannot be achieved by current and future X-ray satellites.

  13. Measurement of anomalously strong emission from the 1s-9p transition in the spectrum of H-like phosphorus following charge exchange with molecular hydrogen

    CERN Document Server

    Leutenegger, M A; Brown, G V; Kelley, R L; Kilbourne, C A; Porter, F S

    2010-01-01

    We have measured K-shell x-ray spectra of highly ionized argon and phosphorus following charge exchange with molecular hydrogen at low collision energy in an electron beam ion trap using an x-ray calorimeter array with $\\sim$6 eV resolution. We find that the emission at the high-end of the Lyman series is greater by a factor of 2 for phosphorus than for argon, even though the measurement was performed concurrently and the atomic numbers are similar. This does not agree with current theoretical models and deviates from the trend observed in previous measurements.

  14. Differential cross section of the pion-nucleon charge-exchange reaction in the momentum range from 148 to 323 MeV/c

    CERN Document Server

    Sadler, M E; Abaev, V V; Allgower, C; Barker, A; Bekrenev, V; Bircher, C; Briscoe, W J; Cadman, R; Carter, C; Clajus, M; Comfort, J R; Craig, K; Daugherity, M; Draper, B; Grosnick, D P; Hayden, S; Huddleston, J; Isenhower, D; Jerkins, M; Joy, M; Knecht, N; Koetke, D D; Kozlenko, N; Kruglov, S; Kycia, T; Lolos, G J; Lopatin, I; Manley, D M; Manweiler, R; Marusic, A; McDonald, S; Nefkens, B M K; Olmsted, J; Papandreou, Z; Peaslee, D; Peterson, J; Phaisangittisakul, N; Prakhov, S N; Price, J W; Ramírez, A; Robinson, C; Shafi, A; Spinka, H; Stanislaus, S; Starostin, A; Staudenmaier, H M; Strakovsky, I I; Supek, I; Tippens, W B; Watson, S

    2004-01-01

    Measured values of the differential cross section for pion-nucleon charge exchange are presented at momenta 148, 174, 188, 212, 238, 271, 298, and 323 MeV/c, a region dominated by the Delta resonance. Complete angular distributions were obtained using the Crystal Ball detector at the Alternating Gradient Synchrotron (AGS) at Brookhaven National Laboratory (BNL). Statistical uncertainties of the differential cross sections are typically 2-6%, exceptions being the results at the lowest momentum and at the most forward measurements of the five lowest momenta. We estimate the systematic uncertainties to be 3-6%.

  15. Differential cross sections of the charge-exchange reaction pi- p --> pi0 n in the momentum range from 103 to 178 MeV/c

    CERN Document Server

    Mekterović, D; Abaev, V; Bekrenev, V; Bircher, C; Briscoe, W J; Cadman, R V; Clajus, M; Comfort, J R; Craig, K; Grosnick, D; Isenhover, D; Jerkins, M; Joy, M; Knecht, N; Koetke, D D; Kozlenko, N; Kulbardis, A; Kruglov, S; Lolos, G; Lopatin, I; Manley, D M; Manweiler, R; Marušić, A; McDonald, S; Nefkens, B M K; Olmsted, J; Papandreou, Z; Peaslee, D; Peterson, J; Phaisangittisakul, N; Prakhov, S N; Price, J W; Ramírez, A; Sadler, M E; Shafi, A; Spinka, H; Stanislaus, S; Starostin, A; Staudenmaier, H M; Strakovsky, I; Tippens, W B; Watson, S

    2009-01-01

    Measured values of the differential cross sections for pion-nucleon charge exchange, pi- p --> pi0 n, are presented for pi- momenta of 103, 112, 120, 130, 139, 152, and 178 MeV/c. Complete angular distributions were obtained by using the Crystal Ball detector at the Alternating Gradient Synchrotron at Brookhaven National Laboratory. Statistical uncertainties of the differential cross sections vary from 3% to 6% in the backward angle region, and from 6% to about 20% in the forward region with the exception of the two most forward angles. The systematic uncertainties are estimated to be about 3% for all momenta.

  16. Computer-aided model analysis for ionic strength-dependent effective charge of protein in ion-exchange chromatography

    DEFF Research Database (Denmark)

    Lim, Young-il; Jørgensen, Sten Bay; Kim, In-Ho

    2005-01-01

    differential algebraic equation (PDAE) system, a fast and accurate numerical method (i.e., conservation element/solution element (CE/SE) method), is proposed. Sensitivity and elasticity of the model parameters (e.g., steric/shape factors, adsorption heat coefficient, effective protein charge, equilibrium...... constant, mass transfer coefficient, axial dispersion coefficient and bed voidage) are analyzed for a BSA-salt system in a low protein concentration range. Within a low concentration range of bovine serum albumin (BSA) where linear adsorption isotherms are shown, the adsorption heat coefficient, shape...... salt concentrations, it is proposed that the effective protein charge could depend upon the salt concentration (or ionic strength). The reason for this dependence may be a steric hindrance of protein binding sites combined with a salt shielding effect neutralizing the surface charges of the protein. (c...

  17. On Lunar Exospheric Column Densities and Solar Wind Access Beyond the Terminator from ROSAT Soft X-ray Observations of Solar Wind Charge Exchange (SWCX)

    Science.gov (United States)

    Collier, M. R.; Snowden, S. L.; Sarantos, M.; Benna, M.; Carter, J. A.; Cravens, T.; Farrell, W. M.; Fatemi, S.; Hills, H. K.; Hodges, R. R.; Holmstrom, M.; Kuntz, K. D.; Porter, F. S.; Read, A.; Robertson, I. P.; Sembay, S. F.; Sibeck, D. G.; Stubbs, T. J.; Travnicek, P. M.

    2013-12-01

    We analyze the ROSAT PSPC soft X-ray image of the Moon taken on 29 June 1990 by examining the radial profile of the count rate in three wedges, two wedges (one north and one south) 13-32 degrees off (19 degrees wide) the terminator towards the dark side and one wedge 38 degrees wide centered on the antisolar point. The radial profiles of both the north and the south wedges show substantial limb brightening that is absent in the 38 degree wide antisolar wedge. An analysis of the soft X-ray intensity increase associated with the limb brightening shows that its magnitude is consistent with that expected due to solar wind charge exchange (SWCX) with the tenuous lunar atmosphere based on lunar exospheric models and hybrid simulation results of solar wind access beyond the terminator. Soft X-ray imaging thus can independently infer the total lunar limb column density including all species, a property that before now has not been measured, and provide a large-scale picture of the solar wind-lunar interaction. Because the SWCX signal appears dominated by exospheric species arising from solar wind implantation, this technique can also monitor how the exosphere varies with solar wind conditions. Now along with Mars, Venus, and Earth, the Moon represents another solar system body at which solar wind charge exchange has been observed.

  18. Charge heterogeneity profiling of monoclonal antibodies using low ionic strength ion-exchange chromatography and well-controlled pH gradients on monolithic columns.

    Science.gov (United States)

    Talebi, Mohammad; Nordborg, Anna; Gaspar, Andras; Lacher, Nathan A; Wang, Qian; He, Xiaoping Z; Haddad, Paul R; Hilder, Emily F

    2013-11-22

    In this work, the suitability of employing shallow pH gradients generated using single component buffer systems as eluents through cation-exchange (CEX) monolithic columns is demonstrated for the high-resolution separation of monoclonal antibody (mAb) charge variants in three different biopharmaceuticals. A useful selection of small molecule buffer species is described that can be used within very narrow pH ranges (typically 1 pH unit) defined by their buffer capacity for producing controlled and smooth pH profiles when used together with porous polymer monoliths. Using very low ionic strength eluents also enabled direct coupling with electrospray ionisation mass spectrometry. The results obtained by the developed pH gradient approach for the separation of closely related antibody species appear to be consistent with those obtained by imaged capillary isoelectric focusing (iCE) in terms of both resolution and separation profile. Both determinants of resolution, i.e., peak compression and peak separation contribute to the gains in resolution, evidently through the Donnan potential effect, which is increased by decreasing the eluent concentration, and also through the way electrostatic charges are distributed on the protein surface. Retention mechanisms based on the trends observed in retention of proteins at pH values higher than the electrophoretic pI are also discussed using applicable theories. Employing monolithic ion-exchangers is shown to enable fast method development, short analysis time, and high sample throughput owing to the accelerated mass transport of the monolithic media. The possibility of short analysis time, typically less than 15 min, and high sample throughput is extremely useful in the assessment of charge-based changes to the mAb products, such as during manufacturing or storage. Copyright © 2013 Elsevier B.V. All rights reserved.

  19. Analysis of the charge-exchange reaction $pp \\rightarrow (p\\pi^{+}) (p\\pi^{-}$ and of \\delta^{++}\\delta^{0}$ production at the CERN ISR

    CERN Document Server

    Goggi, Giorgio V; Conta, C; Fraternali, M; Impellizzeri, F; Mantovani, G C; Pastore, F; Rimoldi, A; Rossini, B

    1978-01-01

    The results of a systematic analysis of charge-exchange double dissociation in proton-proton collisions at the CERN Intersecting Storage Rings are presented. The data cover the entire ISR energy range between square root s=23 GeV and square root s=63 GeV at five standard energies. Double resonance production is observed in the Delta /sup ++/ Delta /sup 0/ and Delta /sup ++/N/sup 0/(1688) final states. The mass spectra of the p pi /sup -/ system show more pronounced resonant signals in the backward Jackson hemisphere. A detailed analysis ofdifferential cross sections shows a forward peak typical of absorbed pion exchanges decreasing as s/sup -1.81+or-0.06/, followed by a much gentler exponential behaviour associated with a trajectory typical of rho -A/sub 2/ exchange. The high-energy transition to this regime is also indicated by a dramatic change in the s-dependence of total cross sections as compared with low-energy data. (20 refs).

  20. Charge Exchange in Low-Energy H, D + C4+ Collisions with Full Account of Electron Translation

    Directory of Open Access Journals (Sweden)

    A. Riera

    2002-03-01

    Full Text Available The effect of the anisotropy of the interaction potential on ion-diatom non-adiabatic collisions is analized by considering the influence of the anisotropy on orientation averaged total cross sections for charge transfer in H++H2(X1Σ+g collisions. We discuss the possibility of employing simpli ed methods such as an isotropic approximation, where only the electronic energies and interactions of a single orientation are necessary. The use of several isotropic calculations to evaluate the orientation averaged cross section is analized.

  1. High resolution spectral signatures of X-ray emission following charge exchange recombination between highly charged iron and neutral helium, molecular hydrogen and molecular nitrogen: A comparison between theory and experiment

    Science.gov (United States)

    Brown, Gregory V.; Cumbee, Renata; Gu, Liyi; Kelley, Richard L.; Kilbourne, Caroline; Leutenegger, Maurice A.; Porter, Frederick S.; Beiersdorfer, Peter

    2017-08-01

    We have used the LLNL electron beam ion trap EBIT-I and a NASA/GSFC quantum microcalorimeter to measure the X-ray emission following charge exchange recombination between highly charged Fe25+ and Fe 26+ and neutral helium, molecular hydrogen, and molecular nitrogen. The ~ 5 eV energy resolution of the microcalorimeter has made it possible to measure and resolve n to 1 K-shell transitions from up to n = 14. We compare the measurements to a model based on the Landau-Zener theory and also the models found in SPEX and APEC. Our results include relative intensities of the 1P1 resonance line to the 3S1 forbidden line, commonly referred to as lines w and z. These results are especially useful for interpreting spectra from celestial sources measured with XARM's Resolve and ATHENA's X-IFU. These data have also proved useful in the interpretation of Hitomi's SXS spectrum of the Perseus cluster.Part of this work was performed under the auspices of the U.S. Department of Energy by Lawrence Livermore National Laboratory under Contract DE-AC52-07NA27344.

  2. Charge-exchange dipole excitations in neutron-rich nuclei: -1 ℏ ω0 , anti-analog pygmy and anti-analog giant resonances

    Science.gov (United States)

    Yoshida, Kenichi

    2017-11-01

    The occurrence of low-lying charge-exchange non-spin-flip dipole modes below the giant resonance in neutron-rich nuclei is predicted on the basis of nuclear density functional theory. The ground and excited states are described within the framework of the self-consistent Hartree-Fock-Bogoliubov theory and the proton-neutron quasiparticle-random-phase approximation employing a Skyrme-type energy density functional. The model calculations are performed for the spherical neutron-rich Ca, Ni, and Sn isotopes. It is found that the low-lying states appear sensitive to the shell structure associated with the -1 ℏ ω0 excitation below the Gamow-Teller states. Furthermore, the pygmy resonance emerges below the giant resonance when the neutrons occupy the low-ℓ (ℓ ≤2 -3 ) orbitals analogous to the pygmy resonance seen in the electric-dipole response.

  3. Grazing incidence collisions of ions and atoms with surfaces: from charge exchange to atomic diffraction; Collisions rasantes d'ions ou d'atomes sur les surfaces: de l'echange de charge a la diffraction atomique

    Energy Technology Data Exchange (ETDEWEB)

    Rousseau, P

    2006-09-15

    This thesis reports two studies about the interaction with insulating surfaces of keV ions or atoms under grazing incidence. The first part presents a study of charge exchange processes occurring during the interaction of singly charged ions with the surface of NaCl. In particular, by measuring the scattered charge fraction and the energy loss in coincidence with electron emission, the neutralization mechanism is determined for S{sup +}, C{sup +}, Xe{sup +}, H{sup +}, O{sup +}, Kr{sup +}, N{sup +}, Ar{sup +}, F{sup +}, Ne{sup +} and He{sup +}. These results show the importance of the double electron capture as neutralization process for ions having too much potential energy for resonant capture and not enough for Auger neutralization. We have also studied the ionisation of the projectile and of the surface, and the different Auger-like neutralization processes resulting in electron emission, population of conduction band or excited state. For oxygen scattering, we have measured an higher electron yield in coincidence with scattered negative ion than with scattered atom suggesting the transient formation above the surface of the oxygen doubly negative ion. The second study deals with the fast atom diffraction, a new phenomenon observed for the first time during this work. Due to the large parallel velocity, the surface appears as a corrugated wall where rows interfere. Similarly to the Thermal Atom Scattering the diffraction pattern corresponds to the surface potential and is sensitive to vibrations. We have study the H-NaCl and He-LiF atom-surface potentials in the 20 meV - 1 eV range. This new method offers interesting perspectives for surface characterisation. (author)

  4. Nonadiabatic ionic--covalent transitions. Exponential-linear model for the charge exchange and neutralization reactions Na+H arrow-right-left Na/sup +/+H/sup -/

    Energy Technology Data Exchange (ETDEWEB)

    Errea, L.F.; Mendez, L.; Mo, O.; Riera, A.

    1986-01-01

    A previous study of charge exchange processes taking place through ionic--covalent transitions is extended to the case of Na+H and Na/sup +/+H/sup -/ collisions. A five-state molecular expansion, with the inclusion of two-electron translation factors, is employed to calculate the charge exchange and neutralization cross sections. Transitions at the first two pseudocrossings between the energy curves, practically determine the cross sections in the energy range 0.16--5 keV amu/sup -1/. We also show that the widely used multichannel Landau--Zener theory is totally inadequate, to treat these transitions.

  5. Modeling the adsorption of hydrogen, sodium, chloride and phthalate on goethite using a strict charge-neutral ion-exchange theory

    Science.gov (United States)

    Ndu, Udonna

    2017-01-01

    Simultaneous adsorption modeling of four ions was predicted with a strict net charge-neutral ion-exchange theory and its corresponding equilibrium and mass balance equations. An important key to the success of this approach was the proper collection of all the data, particularly the proton adsorption data, and the inclusion of variable concentrations of conjugate ions from the experimental pH adjustments. Using IExFit software, the ion-exchange model used here predicted the competitive retention of several ions on goethite by assuming that the co-adsorption or desorption of all ions occurred in the correct stoichiometries needed to maintain electroneutrality. This approach also revealed that the retention strength of Cl− ions on goethite increases in the presence of phthalate ions. That is, an anion-anion enhancement effect was observed. The retention of Cl− ions was much weaker than phthalate ions, and this also resulted in a higher sensitivity of the Cl− ions toward minor variations in the surface reactivity. The proposed model uses four goethite surface sites. The drop in retention of phthalate ions at low pH was fully described here as resulting from competitive Cl− reactions, which were introduced in increasing concentrations into the matrix as the conjugate base to the acid added to lower the pH. PMID:28464020

  6. Modeling the adsorption of hydrogen, sodium, chloride and phthalate on goethite using a strict charge-neutral ion-exchange theory.

    Directory of Open Access Journals (Sweden)

    Cristian P Schulthess

    Full Text Available Simultaneous adsorption modeling of four ions was predicted with a strict net charge-neutral ion-exchange theory and its corresponding equilibrium and mass balance equations. An important key to the success of this approach was the proper collection of all the data, particularly the proton adsorption data, and the inclusion of variable concentrations of conjugate ions from the experimental pH adjustments. Using IExFit software, the ion-exchange model used here predicted the competitive retention of several ions on goethite by assuming that the co-adsorption or desorption of all ions occurred in the correct stoichiometries needed to maintain electroneutrality. This approach also revealed that the retention strength of Cl- ions on goethite increases in the presence of phthalate ions. That is, an anion-anion enhancement effect was observed. The retention of Cl- ions was much weaker than phthalate ions, and this also resulted in a higher sensitivity of the Cl- ions toward minor variations in the surface reactivity. The proposed model uses four goethite surface sites. The drop in retention of phthalate ions at low pH was fully described here as resulting from competitive Cl- reactions, which were introduced in increasing concentrations into the matrix as the conjugate base to the acid added to lower the pH.

  7. Effects of weakly coupled and dense quantum plasmas environments on charge exchange and ionization processes in Na+ + Rb(5s) atom collisions

    Science.gov (United States)

    Pandey, Mukesh Kumar; Lin, Yen-Chang; Ho, Yew Kam

    2017-02-01

    The effects of weakly coupled or classical and dense quantum plasmas environment on charge exchange and ionization processes in Na+ + Rb(5s) atom collision at keV energy range have been investigated using classical trajectory Monte Carlo (CTMC) method. The interaction of three charged particles are described by the Debye-Hückel screen potential for weakly coupled plasma, whereas exponential cosine-screened Coulomb potential have been used for dense quantum plasma environment and the effects of both conditions on the cross sections are compared. It is found that screening effects on cross sections in high Debye length condition is quite small in both plasma environments. However, enhanced screening effects on cross sections are observed in dense quantum plasmas for low Debye length condition, which becomes more effective while decreasing the Debye length. Also, we have found that our calculated results for plasma-free case are comparable with the available theoretical results. These results are analyzed in light of available theoretical data with the choice of model potentials.

  8. Nearest-neighbor Kitaev exchange blocked by charge order in electron-doped α -RuCl3

    Science.gov (United States)

    Koitzsch, A.; Habenicht, C.; Müller, E.; Knupfer, M.; Büchner, B.; Kretschmer, S.; Richter, M.; van den Brink, J.; Börrnert, F.; Nowak, D.; Isaeva, A.; Doert, Th.

    2017-10-01

    A quantum spin liquid might be realized in α -RuCl3 , a honeycomb-lattice magnetic material with substantial spin-orbit coupling. Moreover, α -RuCl3 is a Mott insulator, which implies the possibility that novel exotic phases occur upon doping. Here, we study the electronic structure of this material when intercalated with potassium by photoemission spectroscopy, electron energy loss spectroscopy, and density functional theory calculations. We obtain a stable stoichiometry at K0.5RuCl3 . This gives rise to a peculiar charge disproportionation into formally Ru2 + (4 d6 ) and Ru3 + (4 d5 ). Every Ru 4 d5 site with one hole in the t2 g shell is surrounded by nearest neighbors of 4 d6 character, where the t2 g level is full and magnetically inert. Thus, each type of Ru site forms a triangular lattice, and nearest-neighbor interactions of the original honeycomb are blocked.

  9. Magnetic charge distribution and stray field landscape of asymmetric néel walls in a magnetically patterned exchange bias layer system

    Science.gov (United States)

    Zingsem, Norbert; Ahrend, Florian; Vock, Silvia; Gottlob, Daniel; Krug, Ingo; Doganay, Hatice; Holzinger, Dennis; Neu, Volker; Ehresmann, Arno

    2017-12-01

    The 3D stray field landscape above an exchange bias layer system with engineered domain walls has been fully characterized by quantitative magnetic force microscopy (qMFM) measurements. This method is based on a complete quantification of the MFM tip’s imaging properties and the subtraction of its contribution from the measured MFM data by deconvolution in Fourier space. The magnetically patterned Ir17Mn83/Co70Fe30-exchange-bias-multilayers have been designed to contain asymmetric head-to-head (hh)/tail-to-tail (tt) Néel walls between domains of different magnetic anisotropies for potential use in guided particle transport. In the current application, qMFM reveals the effective magnetic charge profile on the surface of the sample—with high spatial resolution and in an absolute quantitative manner. These data enable to calculate the magnetostatic potential and the full stray field landscape above the sample surface. It has been successfully tested against: (i) micromagnetic simulations of the magnetization structure of a comparable exchange-bias layer system, (ii) measurements of the magnetization profile across the domain boundary with x-ray photoemission electron microscopy, and (iii) direct stray field measurements obtained by scanning Hall probe microscopy at elevated scan heights. This approach results in a quantitative determination of the stray field landscape at close distances to the sample surface, which will be of importance for remote magnetic particle transport applications in lab-on-a-chip devices. Furthermore, the highly resolving and quantitative MFM approach reveals details of the domain transition across the artificially structured phase boundary, which have to be attributed to a continuous change in the materials parameters across this boundary, rather than an abrupt one.

  10. a Calculation of the Doubly Differential Cross Section for Inclusive Pion - HELIUM-4 Double Charge Exchange at Incident Pion Kinetic Energy Less than 270 Mev

    Science.gov (United States)

    Kulkarni, Arun Venkatesh

    Pi-nuclear scattering calculations that use multiple scattering usually require the knowledge not only of the pi-nucleon interaction in free space but also its modification inside a nuclear medium. A relativistic 3-Body model consisting of the pion, the i^ {rm th}-nucleon and the residual nucleus also called the core, is developed. In this model the nucleon core separation in co-ordinate space is approximated by the separation between the center of mass of the pi-i^{rm th} nucleon subsystem called the Composite, and the core. The instant form of dynamics was employed to introduce interactions between the pion and the nucleon and between the pi N Composite and the Core. The Composite-Core Hamiltonian is assumed to admit no bound states. The relativistic 3-Body total Hamiltonian is then diagonalized by nested-separable eigenfunctions. This diagonalization allows the construction of an expression for matrix elements of the medium modified pi N scattering operator tau_ {i} in the lab frame in terms of the CM pi N free space t-matrix elements. Terms that are quadratic in the pi N t -matrix elements in this expression are neglected. The Sequential Single Charge eXchange (SSCX) mechanism contribution to inclusive pi- ^4He Double Charge eXchange (DCX) is calculated using only the double scattering term of the Watson multiple scattering series. The tau-matrix elements obtained from the 3-Body model are used for the first scattering. It contains explicit dependance upon the matrix elements of the Composite-Core scattering operator t_{pi N-C}. This explicit dependance is ignored in the second scattering. The pole of the intermediate pion Green function is fixed from 3-Body model considerations and the requirement that pion be on the mass shell at the pole. The calculated inclusive cross sections {{d^2sigma}over{d Omega dT_pi}} are compared with the Kinney et al. experimental results and essential agreement with the spectrum for incident pion kinetic energy T_sp{pi}{rm In

  11. Effect of health information exchange on recognition of medication discrepancies is interrupted when data charges are introduced: results of a cluster-randomized controlled trial.

    Science.gov (United States)

    Boockvar, Kenneth S; Ho, William; Pruskowski, Jennifer; DiPalo, Katherine E; Wong, Jane J; Patel, Jessica; Nebeker, Jonathan R; Kaushal, Rainu; Hung, William

    2017-11-01

    To determine the effect of health information exchange (HIE) on medication prescribing for hospital inpatients in a cluster-randomized controlled trial, and to examine the prescribing effect of availability of information from a large pharmacy insurance plan in a natural experiment. Patients admitted to an urban hospital received structured medication reconciliation by an intervention pharmacist with (intervention) or without (control) access to a regional HIE. The HIE contained prescribing information from the largest hospitals and pharmacy insurance plan in the region for the first 10 months of the study, but only from the hospitals for the last 21 months, when data charges were imposed by the insurance plan. The primary endpoint was discrepancies between preadmission and inpatient medication regimens, and secondary endpoints included adverse drug events (ADEs) and proportions of rectified discrepancies. Overall, 186 and 195 patients were assigned to intervention and control, respectively. Patients were 60 years old on average and took a mean of 7 medications before admission. There was no difference between intervention and control in number of risk-weighted discrepancies (6.4 vs 5.8, P = .452), discrepancy-associated ADEs (0.102 vs 0.092 per admission, P = .964), or rectification of discrepancies (0.026 vs 0.036 per opportunity, P = .539). However, patients who received medication reconciliation with pharmacy insurance data available had more risk-weighted medication discrepancies identified than those who received usual care (8.0 vs 5.9, P = .038). HIE may improve outcomes of medication reconciliation. Charging for access to medication information interrupts this effect. Efforts are needed to understand and increase prescribers' rectification of medication discrepancies.

  12. Charge variants characterization of a monoclonal antibody by ion exchange chromatography coupled on-line to native mass spectrometry: Case study after a long-term storage at +5°C.

    Science.gov (United States)

    Leblanc, Y; Ramon, C; Bihoreau, N; Chevreux, G

    2017-03-24

    Numerous putative post-translational modifications may induce variations of monoclonal antibodies charge distribution that can potentially affect their biological activity. The characterization and the monitoring of these charge variants are critical quality requirements to ensure stability and process consistency. Charge variants are usually characterized by preparative ion exchange chromatography, collection of fractions and subsequent reverse-phase liquid chromatography with mass spectrometry analysis. While this process can be automatized by on-line two-dimensional chromatography, it remains often complex and time consuming. For this reason, a straightforward on-line charge variant analysis method is highly desirable and analytical laboratories are actively pursuing efforts to overcome this challenge. In this study, a mixed mode ion exchange chromatographic method using volatile salts and coupled on-line to native mass spectrometry was developed in association with a middle-up approach for a detailed characterization of monoclonal antibodies charge variants. An aged monoclonal antibody, presenting a complex charge variant profile was successfully investigated by this methodology as a case study. Results demonstrate that deamidation of the heavy chain was the major degradation pathway after long-term storage at 5°C while oxidation was rather low. The method was also very useful to identify all the clipped forms of the antibody. Copyright © 2017 LFB Biotechnologies. Published by Elsevier B.V. All rights reserved.

  13. On lunar exospheric column densities and solar wind access beyond the terminator from ROSAT soft X-ray observations of solar wind charge exchange

    Science.gov (United States)

    Collier, Michael R.; Snowden, S. L.; Sarantos, M.; Benna, M.; Carter, J. A.; Cravens, T. E.; Farrell, W. M.; Fatemi, S.; Hills, H. Kent; Hodges, R. R.; Holmström, M.; Kuntz, K. D.; Porter, F. Scott; Read, A.; Robertson, I. P.; Sembay, S. F.; Sibeck, D. G.; Stubbs, T. J.; Travnicek, P.; Walsh, B. M.

    2014-07-01

    We analyze the Röntgen satellite (ROSAT) position sensitive proportional counter soft X-ray image of the Moon taken on 29 June 1990 by examining the radial profile of the surface brightness in three wedges: two 19° wedges (one north and one south) 13-32° off the terminator toward the dark side and one wedge 38° wide centered on the antisolar direction. The radial profiles of both the north and the south wedges show significant limb brightening that is absent in the 38° wide antisolar wedge. An analysis of the soft X-ray intensity increase associated with the limb brightening shows that its magnitude is consistent with that expected due to solar wind charge exchange (SWCX) with the tenuous lunar atmosphere based on lunar exospheric models and hybrid simulation results of solar wind access beyond the terminator. Soft X-ray imaging thus can independently infer the total lunar limb column density including all species, a property that before now has not been measured, and provide a large-scale picture of the solar wind-lunar interaction. Because the SWCX signal appears to be dominated by exospheric species arising from solar wind implantation, this technique can also determine how the exosphere varies with solar wind conditions. Now, along with Mars, Venus, and Earth, the Moon represents another solar system body at which SWCX has been observed.

  14. Deuterium charge exchange recombination spectroscopy from the top of the pedestal to the scrape off layer in H-mode plasmas

    Science.gov (United States)

    Haskey, S. R.; Grierson, B. A.; Stagner, L.; Burrell, K. H.; Chrystal, C.; Groebner, R. J.; Ashourvan, A.; Pablant, N. A.

    2017-10-01

    Recent completion of the thirty two channel main-ion (deuterium) charge exchange recombination spectroscopy (CER) diagnostic on DIII-D [J.L. Luxon, Nucl. Fusion 42 (2002) 614] enables detailed comparisons between impurity and main-ion temperature, density, and toroidal rotation. Sixteen sightlines cover the core of the plasma and another sixteen are densely packed towards the edge, providing high resolution measurements of the pedestal and steep gradient edge region of H-mode plasmas. The complexities of the Dα spectrum require fitting with a comprehensive model, as well as using iterative collisional radiative modeling to determine the underlying thermal deuterium ion properties. Large differences in the structure and magnitude of impurity (C6+) and main-ion (D+) toroidal rotation profiles are seen in the H-mode pedestal. Additionally the D+ temperature can be half the value of the C6+ temperature at the separatrix and shows more of a pedestal structure. Typically only the impurity properties are measured and the main-ion properties are either assumed to be the same, or inferred using neoclassical models, which require validation in the steep gradient region. These measured differences have implications for transport model validation, intrinsic rotation studies, pedestal stability, and the boundary conditions for scrape off layer and plasma material interactions studies.

  15. H- and He-like Charge-Exchange Induced X-ray Emission due to Ion Collisions with H, He, and H2

    Science.gov (United States)

    Cumbee, Renata; Mullen, Patrick; Miller, Ansley; Lyons, David; Shelton, Robin L.; Schultz, David R.; Stancil, Phillip C.; Leutenegger, Maurice A.

    2017-08-01

    When a hot plasma collides with a cold neutral gas interactions occur between the microscopic constituents including charge exchange (CX). CX is a process in which an electron can be transferred from a neutral atom or molecule into an excited energy level of an ion. Following this transfer, the excited electron relaxes to lower energy levels, emitting X-rays. This process has been established as a primary source of X-ray emission within our solar system, such as when the solar wind interacts with cometary and planetary atmospheres, and outside of our solar system, such as in the hot outflows of starburst galaxies.Since the CX X-ray emission spectrum varies greatly with collision velocity, it is critical that realistic CX data are included in X-ray spectral models of astrophysical environments in which CX might be significant in order to correctly estimate the ion abundance and plasma velocities. Here, line ratios and spectra are computed using theoretical CX cross sections obtained with the multi-channel Landau-Zener, atomic-orbital close-coupling, and classical-trajectory Monte Carlo methods for a variety of collision energies relevant to various astrophysical environments. Collisions of bare and H-like C, N, O, Ne, Mg, Al, Si, P, S, and Cl ions are shown with H, He, and H2 as the neutral collision targets. An X-ray model using line ratios for C-Si ions is then performed within XSPEC for a region of the Cygnus Loop supernova remnant for 8 collision energies in order to highlight the variation in CX spectral models with collision energy.R. Cumbee’s research was partially supported by an appointment to the NASA Postdoctoral Program at NASA GSFC, administered by Universities Space Research Association under contract with NASA. Work at UGA was partially supported by NASA grants NNX09AC46G and NNG09WF24I.

  16. Experimental study on the influence of charge exchange on the stopping power in the interaction of chlorine with a gas and a deuterium plasma; Etude experimentale de l`influence des echanges de charges sur le pouvoir d`arret dans l`interaction d`ions chlore avec un gaz et un plasma de deuterium

    Energy Technology Data Exchange (ETDEWEB)

    Nectoux, Marie [Inst. de Physique Nucleaire, Paris-11 Univ., 91 - Orsay (France)

    1998-01-06

    This thesis is placed in the context of the physics of energy deposition of a multicharged heavy ion beam in matter at intermediate energies. The experiment gave measurements of energy loss as a function of final charge state for chlorine ions at 1.7 MeV/u in deuterium gas or plasma. In this way, we explore the influence of charge state evolution, depending on experimentally measured capture and ionization cross sections and the electron density of the target, on energy loss. The target is cylindrical and enclosed by two fast valves. The plasma is created in the gas by a discharge, which induces a magnetic perturbation of the beam (lens effect). This effect induces a divergent and misaligned outgoing beam. A simulation including charge state and velocity evolution of the projectile in flight in the magnetic field has been made in order to optimize beam analysis, to reach a precision better than 10{sup -3} in energy measurement. This study led to removal of the target to the `Split Pole`, a refocusing magnetic spectrometer. The first results obtained clearly show the dependence of energy loss on exit charge and especially on its evolution in the target. This is explained in terms of the lengths covered by the projectile in its successive charge states in the target, which depends on target electron density and the medium considered. In plasma, we observed an energy distribution with exit charge twice that observed in gas, because of a strong decrease of charge exchange. A comparison of data obtained in gas with stopping power calculated from Bethe-Bloch-Barkas theory leads to the necessity of including spatial extension of the projectile charge in the theory. (author) 81 refs., 62 figs., 5tabs.

  17. Effect of ligand exchange of Cu{sub 2}ZnSnS{sub 4} nanocrystals on the charge transport and photovoltaic performance of nanostructured depleted bulk heterojunction solar cell

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Zhuo-Xi; Zhou, Zheng-Ji, E-mail: zzj@henu.edu.cn; Bai, Bing; Liu, Ming-Hua; Zhou, Wen-Hui; Kou, Dong-Xing; Wu, Si-Xin, E-mail: wusixin@henu.edu.cn [Henan University, Key Laboratory for Special Functional Materials of Ministry of Education (China)

    2015-12-15

    Cu{sub 2}ZnSnS{sub 4} (CZTS) nanocrystals combining the advantage of feasible solution-phase synthesis and processing are perceived as promising materials for application in efficient, low-cost photovoltaic technology. Herein, we have got surfactant-free CZTS nanocrystals by a novel ligand exchange method, and the obtained CZTS nanocrystals were deposited onto ZnO nanorod arrays to construct depleted bulk heterojunction solar cell. The all-inorganic CZTS nanocrystal solar cells demonstrated a remarkable improvement in J{sub sc} (from 8.14 to 13.97 mA/cm{sup 2}) and power conversion efficiency (from 1.83 to 3.34 %) compared with surfactant-capped CZTS nanocrystals. Using surface photovoltage spectrum, the influence of ligand exchange of CZTS nanocrystals on the charge transport and photovoltaic performance of the nanostructured CZTS solar cells was discussed.

  18. Measurement of Absolute Single and Double Charge Exchange Cross Sections for Si(7–10)+ at 0.88–2.50 KeV/u Impacting He and H2

    Science.gov (United States)

    Moradmand, A.; El Ghazaly, M. O. A.; Mahaptra, D. P.; Chutjian, A.

    2018-01-01

    First measurements are reported for total, absolute, single, and double charge-exchange (CE) cross sections for Si(7–10)+ ions in the solar wind (SW), colliding with the prevalent astrophysical species H2 and He found in comets, the interplanetary medium, and planetary atmospheres. Measurements are in the energy range 0.88–2.50 keV/u, corresponding to the energies of the “fast” and “slow” ion components of the SW. Limited agreement is found with single-exchange results calculated in the classical over-the-barrier model. These CE data are useful for understanding, in laboratory and astrophysical plasmas, photon emissions in the X-ray to visible energy range arising from resulting ion-stabilization steps.

  19. High-Performance Liquid Chromatography of Nucleobases, Nucleosides and Nucleotides : II. Mobile Phase Composition for the Separation of Charged Solutes by Ion-Exchange Chromatography

    NARCIS (Netherlands)

    Haastert, Peter J.M. van

    1981-01-01

    The polarity, pH, ion concentration and polarity of the buffer ions of the mobile phase were modified systematically in order to find optimal conditions for the separation of nucleobases, nucleosides and nucleotides by ion-exchange chromatography. The effects of these mobile phase parameters on the

  20. Enhancement in charge transfer by non-ligand exchange process for colloidal hybrid organic(MEH-PPV):inorganic(CdSe) nanocomposites

    Science.gov (United States)

    Mehta, Aarti; Sharma, Shailesh N.; Singh, V. N.; Srivastva, A. K.; Chand, S.

    2012-10-01

    In this work, we demonstrate the effect of surface modification of as-synthesized oleylamine-capped spherical CdSe QDs of size (5-7 nm). The as-prepared CdSe QDs are highly luminescent, monodispersive and exhibit energy transfer effects upon their dispersion in MEH-PPV polymer matrix. However, repetitive washing of CdSe QDs upon suitable chemical treatment leads to enhancement in charge transfer process as observed in their corresponding MEH-PPV: CdSe nanocomposites. Here, no evidence of agglomeration effects and surface states were found. This enhancement in charge transfer is mainly due to the partial removal of oleylamine capping ligand, which acts as a hindrance in the interaction between polymer and CdSe QDs. The importance of this study is that as-synthesized CdSe QDs show effective energy transfer whereas after chemical treatment, it shows enhanced charge transfer mechanism which makes their corresponding nanocomposites useful for different applications in organic electronic devices such as efficient electroluminescent (OLED) and photovoltaic (OPV) devices respectively.

  1. Mass-charge-heat coupled transfers in a single cell of a proton exchange membrane fuel cell; Transferts couples masse-charge-chaleur dans une cellule de pile a combustible a membrane polymere

    Energy Technology Data Exchange (ETDEWEB)

    Ramousse, J.

    2005-11-15

    Understanding and modelling of coupled mass, charges and heat transfers phenomena are fundamental to analyze the electrical behaviour of the system. The aim of the present model is to describe electrical performances of a PEFMC according to the fluidic and thermal operating conditions. The water content of the membrane and the water distribution in the single cell are estimated according to the coupled simulations of mass transport in the thickness of the single cell and in the feeding channels of the bipolar plates. A microscopic model of a Gas Diffusion Electrode is built up to describe charges transfer phenomena occurring at the electrodes. Completed by a study of heat transfer in the Membrane Electrode Assembly, conditions and preferential sites of water vapor condensation can be highlighted. A set of measurements of the effective thermal conductivity of carbon felts used in fuel cells as porous backing layers have also been performed. Although the value of this parameter is essential for the study of heat transfer, it is still under investigation because of the strong thermal anisotropy of the medium. (author)

  2. The spin-parity structure of the $(K^{-}\\pi^{+})$ and $(\\overline{K}^{0}\\pi^{+}\\pi^{-})$ systems produced in charged exchange reactions

    CERN Document Server

    Sotiriou, D S

    1975-01-01

    Partial wave analyses have been performed for the $(K^-\\pi^+)$ and $(K^{-O}\\pi^+\\pi^-)$ systems produced in the reactions $K^-p\\to K^-\\pi^+$ n and $K^-p\\to K^{-O}\\pi^+\\pi^-$ n, respectively. It is found that the S-wave $(K^-\\pi^+)$ system is consistent with a Breit-Wigner shape peaked at 1.3 GeV and 0.6 GeV wide . The low mass $(K^{-O}\\pi^+\\pi^-)$ system composed mainly of $J^P$ = $o^-$ , $l^+$ and $2^+$ states, resembles in its structure the $(K^{\\pi}{\\pi}^-)$ ­ system produced in diffractive reactions. This implies, in particular , that the presence of unnatural spin-parity states produced by natural parity exchanges cannot be considered as an exclusive characteristic of diffractive processes. A method of analysing the $(N^{\\pi})$ systems is described.

  3. Recovery of infective virus particles in ion-exchange and hydrophobic interaction monolith chromatography is influenced by particle charge and total-to-infective particle ratio.

    Science.gov (United States)

    Sviben, Dora; Forcic, Dubravko; Ivancic-Jelecki, Jelena; Halassy, Beata; Brgles, Marija

    2017-06-01

    Viral particles are used in medical applications as vaccines or gene therapy vectors. In order to obtain product of high purity, potency and safety for medical use purification of virus particles is a prerequisite, and chromatography is gaining increased attention to meet this aim. Here, we report on the use of ion-exchange and hydrophobic interaction chromatography on monolithic columns for purification of mumps virus (MuV) and measles virus (MeV). Efficiency of the process was monitored by quantification of infective virus particles (by 50% cell culture infective dose assay) and total virus particles, and monitoring of their size (by Nanoparticle Tracking Analysis). Ion-exchange chromatography was shown to be inefficient for MuV and best results for MeV were obtained on QA column with recovery around 17%. Purification of MuV and MeV by hydrophobic interaction chromatography resulted in recoveries around 60%. Results showed that columns with small channels (d=1.4μm) are not suitable for MuV and MeV, although their size is below 400nm, whereas columns with large channels (6μm) showed to be efficient and recoveries independent on the flow rate up to 10mL/min. Heterogeneity of the virus suspension and its interday variability mostly regarding total-to-infective particle ratio was observed. Interestingly, a trend in recovery depending on the day of the harvest was also observed for both viruses, and it correlated with the total-to-infective particle ratio, indicating influence of the virus sample composition on the chromatography results. Copyright © 2017. Published by Elsevier B.V.

  4. Inner-shell spectroscopy and exchange interaction of Rydberg electrons bound by singly and doubly charged Kr and Xe atoms in small clusters

    Energy Technology Data Exchange (ETDEWEB)

    Nagasaka, Masanari; Hatsui, Takaki; Setoyama, Hiroyuki; Ruehl, Eckart [Institute for Molecular Science, Myodaiji, Okazaki 444-8585 (Japan); Kosugi, Nobuhiro, E-mail: kosugi@ims.ac.j [Institute for Molecular Science, Myodaiji, Okazaki 444-8585 (Japan)

    2011-01-15

    Surface-site resolved Kr 3d{sub 5/2}{sup -1}5p and 3d{sub 5/2}{sup -1}6p and Xe 4d{sub 5/2}{sup -1}6p and 4d{sub 5/2}{sup -1}7p Rydberg excited states in small van der Waals Kr and Xe clusters with a mean size of = 15 are investigated by X-ray absorption spectroscopy. Furthermore, surface-site resolved Kr 4s{sup -2}5p, 4s{sup -2}6p, and 4s{sup -1}4p{sup -1}5p shakeup-like Rydberg states in small Kr clusters are investigated by resonant Auger electron spectroscopy. The exchange interaction of the Rydberg electron with the surrounding atoms and the induced polarization of the surrounding atoms in the singly and doubly ionized atoms are deduced from the experimental spectra to analyze different surface-site contributions in small clusters, assuming that the corner, edge, face, and bulk sites have 3, 5-6, 8, and 12 nearest neighbor atoms. These energies are almost proportional to the number of the nearest neighbor atoms. The present analysis indicates that small Kr and Xe clusters with = 15 have an average or mixture structure between the fcc-like cubic and icosahedron-like spherical structures.

  5. Formation of self-organized domain structures with charged domain walls in lithium niobate with surface layer modified by proton exchange

    Science.gov (United States)

    Shur, V. Ya.; Akhmatkhanov, A. R.; Chuvakova, M. A.; Dolbilov, M. A.; Zelenovskiy, P. S.; Lobov, A. I.

    2017-03-01

    We have studied the self-organized dendrite domain structures appeared as a result of polarization reversal in the uniform field in lithium niobate single crystals with the artificial surface layer created by proton exchange. We have revealed the self-organized sub-micron scale dendrite domain patterns consisting of domain stripes oriented along the X crystallographic directions separated by arrays of dashed residual domains at the surface by scanning probe microscopy. Raman confocal microscopy allowed visualizing the quasi-regular dendrite domain structures with similar geometry in the vicinity of both polar surfaces. The depth of the structure was about 20 μm for Z+ polar surface and 70 μm for Z- one. According to the proposed mechanism, the dendrite structure formation at the surface was related to the ineffective screening of the residual depolarization field. The computer simulation of the structure formation based on the cellular automata model with probabilistic switching rule proved the eligibility of the proposed scheme, the simulated dendrite domain patterns at various depths being similar to the experimental ones.

  6. Study of the elastic scattering and of the (p,n) charge exchange reaction with neutron-rich light exotic beams; Etude de la diffusion elastique et de la reaction d`echange de charge (p,n) avec des faisceaux exotiques legers riches en neutrons

    Energy Technology Data Exchange (ETDEWEB)

    Cortina Gil, D.

    1996-07-05

    We have measured at GANIL, with the high resolution spectrometer SPEG, the elastic scattering of several neutron rich secondary beams ({sup 6}He, {sup 10}Be and {sup 11}Be) on a polypropylene target and the charge exchange reaction p({sup 6}He, {sup 6}Li)n. These exotic beams were produced by nuclear fragmentation and re-focalized with the SISSI device (superconducting solenoids). The signature of a halo structure in these nuclei has been analysed. Special attention has been paid to several aspects of the associated calculations namely, the proton and neutron density distributions and the small binding energy for the last nucleons in these exotic nuclei. Break-up mechanisms are seen to play an important role in these nuclei. 100 refs.

  7. Around the laboratories: Dubna: Physics results and progress on bubble chamber techniques; Stanford (SLAC): Operation of a very rapid cycling bubble chamber; Daresbury: Photographs of visitors to the Laboratory; Argonne: Charge exchange injection tests into the ZGS in preparation for a proposed Booster

    CERN Multimedia

    1969-01-01

    Around the laboratories: Dubna: Physics results and progress on bubble chamber techniques; Stanford (SLAC): Operation of a very rapid cycling bubble chamber; Daresbury: Photographs of visitors to the Laboratory; Argonne: Charge exchange injection tests into the ZGS in preparation for a proposed Booster

  8. Anion exchange membrane

    Science.gov (United States)

    Verkade, John G; Wadhwa, Kuldeep; Kong, Xueqian; Schmidt-Rohr, Klaus

    2013-05-07

    An anion exchange membrane and fuel cell incorporating the anion exchange membrane are detailed in which proazaphosphatrane and azaphosphatrane cations are covalently bonded to a sulfonated fluoropolymer support along with anionic counterions. A positive charge is dispersed in the aforementioned cations which are buried in the support to reduce the cation-anion interactions and increase the mobility of hydroxide ions, for example, across the membrane. The anion exchange membrane has the ability to operate at high temperatures and in highly alkaline environments with high conductivity and low resistance.

  9. Investigation Of A Transient Energetic Charge Exchange Fux Enhancement ('spike-on-tail') Observed In Neutral-beam-heated H-mode Discharges In The National Spherical Torus Experiment

    Energy Technology Data Exchange (ETDEWEB)

    Medley et al, S S

    2011-08-04

    In the National Spherical Torus Experiment (NSTX), a large increase in the charge exchange neutral flux localized at the Neutral Beam (NB) injection full energy is measured by the E||B (superimposed parallel electric and magnetic fields) Neutral Particle Analyzer (NPA). Termed the High-Energy Feature (HEF), it appears on the NB-injected energetic ion spectrum only in discharges where tearing or kink-type modes (f < 50 kHz) are absent, Toroidal Alfvén Eigenmode (TAE) activity (f ~ 50 - 150 kHz) is weak and Global Alfvén Eigenmode (GAE) activity (f ~ 400 – 1000 kHz) is robust. Compressional Alfvén eigenmode (CAE) activity (f > 1000 kHz) is usually sporadic or absent during the HEF event. The HEF exhibits growth times of Δt ~ 20 - 80 ms, durations of ~ 100 – 600 ms and peak-to-base flux ratios up to H = Fmax /Fmin ~ 10. In infrequent cases, a slowing down distribution below the HEF energy can develop that continues to evolve over periods > 100 ms, a time scale long compared with the typical fast ion equilibration times. HEFs are Transient energetic charge exchange flux enhancement ('spike-on-tail') 2 observed only in H-mode (not L-mode) discharges with injected power Pb ≥ 4 MW and in the pitch range χ = vll /v ~ 0.7 – 0.9; i.e. only for passing particles. Increases of ~ 10 - 30 % in the measured neutron yield and total stored energy that are observed to coincide with the feature appear to be driven by concomitant broadening of measured Te(r), Ti(r) and ne(r) profiles and not the HEF itself. While the HEF has minimal impact on plasma performance, it nevertheless poses a challenging wave-particle interaction phenomenon to understand. Candidate mechanisms for HEF formation are developed based on quasilinear theory of wave-particle interaction. The only mechanism found to lead to the large NPA flux ratios, H = Fmax /Fmin , observed in NSTX is the quasilinear evolution of the energetic ion distribution, Fb(E,χ,r), in phase space and the concomitant

  10. Ion exchange phenomena

    Energy Technology Data Exchange (ETDEWEB)

    Bourg, I.C.; Sposito, G.

    2011-05-01

    Ion exchange phenomena involve the population of readily exchangeable ions, the subset of adsorbed solutes that balance the intrinsic surface charge and can be readily replaced by major background electrolyte ions (Sposito, 2008). These phenomena have occupied a central place in soil chemistry research since Way (1850) first showed that potassium uptake by soils resulted in the release of an equal quantity of moles of charge of calcium and magnesium. Ion exchange phenomena are now routinely modeled in studies of soil formation (White et al., 2005), soil reclamation (Kopittke et al., 2006), soil fertilitization (Agbenin and Yakubu, 2006), colloidal dispersion/flocculation (Charlet and Tournassat, 2005), the mechanics of argillaceous media (Gajo and Loret, 2007), aquitard pore water chemistry (Tournassat et al., 2008), and groundwater (Timms and Hendry, 2007; McNab et al., 2009) and contaminant hydrology (Chatterjee et al., 2008; van Oploo et al., 2008; Serrano et al., 2009).

  11. The STORM and CuPID soft X-ray cameras on the DXL sounding rocket mission: Employment of slumped micropore optics to image solar wind charge exchange X-ray emission in the magnetosheath.

    Science.gov (United States)

    Thomas, N.

    2016-12-01

    The Sheath Transport Observer for the Redistribution of Mass (STORM) and the Cusp Plasma Imaging Detector (CuPID) instruments are soft X-ray cameras the utilize slumped micropore ('lobster-eye') optics. These lobster-eye optics, developed by the University of Leicester and the Photonis Corporation, provide for wide field-of-view imaging of X-ray line emission produced via charge exchange between hydrogen in the Earth's exosphere and heavy ions in the solar wind. Both instruments have position sensitize, chevron configuration, microchannel plate detectors in their respective focal planes. STORM possess two, 4 cm by 4 cm, lobster-eye optics, each with a focal length of 37.5 cm. It flew as a piggy back payload on the Diffuse X-ray emission from the Local galaxy (DXL) sounding rocket mission which was launched in December of 2012 from White Sands Missile Range, New Mexico. STORM operated successfully during this mission and represents the first use of lobster-eye optics in space. A future version of STORM, in high orbit, could image a significant portion of the magnetosheath to infer the locations of the magnetopause and the bow shock. CuPID is a 3U CubeSat variant of STORM that uses a single optic with a 27.5 cm focal length. A sounding rocket borne CuPID flew as a science payload with DXL from White Sands in December of 2015 with results forthcoming.

  12. 77 FR 48576 - Self-Regulatory Organizations; BATS Exchange, Inc.; Notice of Filing and Immediate Effectiveness...

    Science.gov (United States)

    2012-08-14

    ... or event that affects the Exchange at the Exchange's primary data center. Thus, the secondary data... charging for certain physical ports used to access the Exchange at the Exchange's secondary data center... Ports to Secondary Data Center The Exchange currently charges for both ``logical'' ports used for order...

  13. Barter exchanges

    DEFF Research Database (Denmark)

    Sudzina, Frantisek

    Although barter is often perceived as something that proceeded money, barter is still used. The focus of the paper is on barter exchanges. Barter exchanges are used both in developing countries as well as in developed countries (including the U.S.). They are used by both organizations...... and individuals. They usually allow to exchange good but some include also services. Some exchanges allow only for bi-directional barter, i.e. when only two parties are involved in the exchange. But probably most of the barter exchanges use barter money; this makes it easier to exchange goods and services...

  14. Electronic device for measuring the polarization parameter in the {pi}{sup -}p {yields} {pi}{sup 0}n charge exchange reaction on a polarized proton target; Un appareillage electronique destine a la mesure du parametre de polarisation dans la reaction d'echange de charge {pi}{sup -}p {yields} {pi}{sup 0}n sur cible de protons polarises

    Energy Technology Data Exchange (ETDEWEB)

    Brehin, S. [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1967-12-15

    An electronic apparatus has been constructed to measure the polarization parameter P{sub 0}(t) in {pi}{sup -}p {yields} {pi}{sup 0}n charge exchange scattering at 5.9 GeV/c and 11,2 GeV/c on polarized proton target. This device insures triggering of a heavy plate spark chamber, allowing visualisation of {gamma} rays from the {pi}{sup 0} decays when the associated neutron offers suitable characteristics in direction and energy. The neutron is detected by an array of 32 counters and his energy is measured by a time of flight method. Electronic circuits of this apparatus are described as test and calibration methods used. (author) [French] Un appareillage electronique a ete realise pour mesurer le parametre de polarisation P{sub 0}(t) dans la reaction d'echange de charge {pi}{sup -}p {yields} {pi}{sup 0}n a 5,9 GeV/c et 11,2 GeV/c sur une cible de protons polarises. Ce dispositif assure le declenchement d'une chambre a etincelles a plaques lourdes, permettant de visualiser les {gamma} de desitegration du {pi}{sup 0}, lorsque le neutron associe presente les caracteristiques convenables en direction et en energie. Le neutron est detecte par un ensemble de 32 compteurs et son energie est mesuree par une methode de temps de vol. Les circuits composant cet appareillage sont decrits ainsi que les methodes d'etalonnage et de verification utilisees. (auteur)

  15. CHARGE IMBALANCE

    Energy Technology Data Exchange (ETDEWEB)

    Clarke, John

    1980-09-01

    The purpose of this article is to review the theory of charge imbalance, and to discuss its relevance to a number of experimental situations. We introduce the concepts of quasiparticle charge and charge imbalance, and discuss the generation and detection of charge imbalance by tunneling. We describe the relaxation of the injected charge imbalance by inelastic scattering processes, and show how the Boltzmann equation can be solved to obtain the steady state quasiparticle distribution and the charge relaxation rate. Details are given of experiments to measure charge imbalance and the charge relaxation rate when inelastic scattering is the predominant relaxation mechanism. Experiments on and theories of other charge relaxation mechanisms are discussed, namely relaxation via elastic scattering in the presence of energy gap anisotropy, or in the presence of a pair breaking mechanism such as magnetic impurities or an applied supercurrent or magnetic field. We describe three other situations in which charge imbalance occurs, namely the resistance of the NS interface, phase slip centers, and the flow of a supercurrent in the presence of a temperature gradient.

  16. Internal Charging

    Science.gov (United States)

    Minow, Joseph I.

    2014-01-01

    (1) High energy (>100keV) electrons penetrate spacecraft walls and accumulate in dielectrics or isolated conductors; (2) Threat environment is energetic electrons with sufficient flux to charge circuit boards, cable insulation, and ungrounded metal faster than charge can dissipate; (3) Accumulating charge density generates electric fields in excess of material breakdown strenght resulting in electrostatic discharge; and (4) System impact is material damage, discharge currents inside of spacecraft Faraday cage on or near critical circuitry, and RF noise.

  17. Intersite Coulomb interaction and Heisenberg exchange

    NARCIS (Netherlands)

    Eder, R; van den Brink, J.; Sawatzky, G.A

    1996-01-01

    Based on exact diagonalization results for small clusters we discuss the effect of intersite Coulomb repulsion in Mott-Hubbard or charge transfers insulators. Whereas the exchange constant J for direct exchange is enhanced by intersite Coulomb interaction, that for superexchange is suppressed. The

  18. Space charge

    CERN Document Server

    Schindl, Karlheinz

    2005-01-01

    The Coulomb forces between the charged particles of a high-intensity beam in an accelerator create a self-field which acts on the particles inside the beam like a distributed lens, defocusing in both transverse planes. A beam moving with speed n is accompanied by a magnetic field which partially cancels the electrostatic defocusing effect, with complete cancellation at c, the speed of light. The effect of this 'direct space charge' is evaluated for transport lines and synchrotrons where the number of betatron oscillations per machine turn, Q, is reduced by DQ. In a real accelerator, the beam is also influenced by the environment (beam pipe, magnets, etc.) which generates 'indirect' space charge effects. For a smooth and perfectly conducting wall, they can easily be evaluated by introducing image charges and currents. These 'image effects' do not cancel when n approaches c, thus they become dominant for high-energy synchrotrons. Each particle in the beam has its particular incoherent tune Q and incoherent tune...

  19. Exchange Network

    Science.gov (United States)

    The Environmental Information Exchange Network (EIEN) is an Internet-based system used by state, tribal and territorial partners to securely share environmental and health information with one another and EPA.

  20. Hydrogen exchange

    DEFF Research Database (Denmark)

    Jensen, Pernille Foged; Rand, Kasper Dyrberg

    2016-01-01

    Hydrogen exchange (HX) monitored by mass spectrometry (MS) is a powerful analytical method for investigation of protein conformation and dynamics. HX-MS monitors isotopic exchange of hydrogen in protein backbone amides and thus serves as a sensitive method for probing protein conformation...... and dynamics along the entire protein backbone. This chapter describes the exchange of backbone amide hydrogen which is highly quenchable as it is strongly dependent on the pH and temperature. The HX rates of backbone amide hydrogen are sensitive and very useful probes of protein conformation......, as they are distributed along the polypeptide backbone and form the fundamental hydrogen-bonding networks of basic secondary structure. The effect of pressure on HX in unstructured polypeptides (poly-dl-lysine and oxidatively unfolded ribonuclease A) and native folded proteins (lysozyme and ribonuclease A) was evaluated...

  1. 47 CFR 69.152 - End user common line for price cap local exchange carriers.

    Science.gov (United States)

    2010-10-01

    ... section for Basic Rate Interface integrated services digital network (ISDN) service. (2) Local exchange... exchange carriers. 69.152 Section 69.152 Telecommunication FEDERAL COMMUNICATIONS COMMISSION (CONTINUED) COMMON CARRIER SERVICES (CONTINUED) ACCESS CHARGES Computation of Charges for Price Cap Local Exchange...

  2. Exchange Options

    NARCIS (Netherlands)

    Jamshidian, F.

    2007-01-01

    The contract is described and market examples given. Essential theoretical developments are introduced and cited chronologically. The principles and techniques of hedging and unique pricing are illustrated for the two simplest nontrivial examples: the classical Black-Scholes/Merton/Margrabe exchange

  3. Threshold-Based Random Charging Scheme for Decentralized PEV Charging Operation in a Smart Grid.

    Science.gov (United States)

    Kwon, Ojin; Kim, Pilkee; Yoon, Yong-Jin

    2016-12-26

    Smart grids have been introduced to replace conventional power distribution systems without real time monitoring for accommodating the future market penetration of plug-in electric vehicles (PEVs). When a large number of PEVs require simultaneous battery charging, charging coordination techniques have become one of the most critical factors to optimize the PEV charging performance and the conventional distribution system. In this case, considerable computational complexity of a central controller and exchange of real time information among PEVs may occur. To alleviate these problems, a novel threshold-based random charging (TBRC) operation for a decentralized charging system is proposed. Using PEV charging thresholds and random access rates, the PEVs themselves can participate in the charging requests. As PEVs with a high battery state do not transmit the charging requests to the central controller, the complexity of the central controller decreases due to the reduction of the charging requests. In addition, both the charging threshold and the random access rate are statistically calculated based on the average of supply power of the PEV charging system that do not require a real time update. By using the proposed TBRC with a tolerable PEV charging degradation, a 51% reduction of the PEV charging requests is achieved.

  4. Ion exchange equilibrium constants

    CERN Document Server

    Marcus, Y

    2013-01-01

    Ion Exchange Equilibrium Constants focuses on the test-compilation of equilibrium constants for ion exchange reactions. The book first underscores the scope of the compilation, equilibrium constants, symbols used, and arrangement of the table. The manuscript then presents the table of equilibrium constants, including polystyrene sulfonate cation exchanger, polyacrylate cation exchanger, polymethacrylate cation exchanger, polysterene phosphate cation exchanger, and zirconium phosphate cation exchanger. The text highlights zirconium oxide anion exchanger, zeolite type 13Y cation exchanger, and

  5. Refrigerant charge management in a heat pump water heater

    Science.gov (United States)

    Chen, Jie; Hampton, Justin W.

    2014-06-24

    Heat pumps that heat or cool a space and that also heat water, refrigerant management systems for such heat pumps, methods of managing refrigerant charge, and methods for heating and cooling a space and heating water. Various embodiments deliver refrigerant gas to a heat exchanger that is not needed for transferring heat, drive liquid refrigerant out of that heat exchanger, isolate that heat exchanger against additional refrigerant flowing into it, and operate the heat pump while the heat exchanger is isolated. The heat exchanger can be isolated by closing an electronic expansion valve, actuating a refrigerant management valve, or both. Refrigerant charge can be controlled or adjusted by controlling how much liquid refrigerant is driven from the heat exchanger, by letting refrigerant back into the heat exchanger, or both. Heat pumps can be operated in different modes of operation, and segments of refrigerant conduit can be interconnected with various components.

  6. Refrigerant charge management in a heat pump water heater

    Science.gov (United States)

    Chen, Jie; Hampton, Justin W.

    2016-07-05

    Heat pumps that heat or cool a space and that also heat water, refrigerant management systems for such heat pumps, and methods of managing refrigerant charge. Various embodiments remove idle refrigerant from a heat exchanger that is not needed for transferring heat by opening a refrigerant recovery valve and delivering the idle refrigerant from the heat exchanger to an inlet port on the compressor. The heat exchanger can be isolated by closing an electronic expansion valve, actuating a refrigerant management valve, or both. Refrigerant charge can be controlled by controlling how much refrigerant is drawn from the heat exchanger, by letting some refrigerant back into the heat exchanger, or both. Heat pumps can be operated in different modes of operation, and various components can be interconnected with refrigerant conduit. Some embodiments deliver refrigerant gas to the heat exchanger and drive liquid refrigerant out prior to isolating the heat exchanger.

  7. CHARGE Association

    Directory of Open Access Journals (Sweden)

    Semanti Chakraborty

    2012-01-01

    Full Text Available We present here a case of 17-year-old boy from Kolkata presenting with obesity, bilateral gynecomastia, mental retardation, and hypogonadotrophic hypogonadism. The patient weighed 70 kg and was of 153 cm height. Facial asymmetry (unilateral facial palsy, gynecomastia, decreased pubic and axillary hair, small penis, decreased right testicular volume, non-palpable left testis, and right-sided congenital inguinal hernia was present. The patient also had disc coloboma, convergent squint, microcornea, microphthalmia, pseudohypertelorism, low set ears, short neck, and choanalatresia. He had h/o VSD repaired with patch. Laboratory examination revealed haemoglobin 9.9 mg/dl, urea 24 mg/dl, creatinine 0.68 mg/dl. IGF1 77.80 ng/ml (decreased for age, GH <0.05 ng/ml, testosterone 0.25 ng/ml, FSH-0.95 ΅IU/ml, LH 0.60 ΅IU/ml. ACTH, 8:00 A.M cortisol, FT3, FT4, TSH, estradiol, DHEA-S, lipid profile, and LFT was within normal limits. Prolactin was elevated at 38.50 ng/ml. The patient′s karyotype was 46XY. Echocardiography revealed ventricularseptal defect closed with patch, grade 1 aortic regurgitation, and ejection fraction 67%. Ultrasound testis showed small right testis within scrotal sac and undescended left testis within left inguinal canal. CT scan paranasal sinuses revealed choanalatresia and deviation of nasal septum to the right. Sonomammography revealed bilateral proliferation of fibroglandular elements predominantly in subareoalar region of breasts. MRI of brain and pituitary region revealed markedly atrophic pituitary gland parenchyma with preserved infundibulum and hypothalamus and widened suprasellar cistern. The CHARGE association is an increasingly recognized non-random pattern of congenital anomalies comprising of coloboma, heart defect, choanal atresia, retarded growth and development, genital hypoplasia, ear abnormalities, and/or deafness. [1] These anomalies have a higher probability of occurring together. In this report, we have

  8. 78 FR 41453 - Self-Regulatory Organizations; BATS Exchange, Inc.; Notice of Filing and Immediate Effectiveness...

    Science.gov (United States)

    2013-07-10

    ... Exchange's primary data center and no logical port fees are assessed for redundant secondary data center... feed'' and ``D feed'', as well as all ports made available in the Exchange's secondary data center... Exchange's primary data center. Beginning July 1, 2013, the Exchange proposes to charge $400 per month per...

  9. Solar Wind Earth Exchange Project (SWEEP)

    Science.gov (United States)

    2016-10-28

    highly charged ions of the solar wind. The main challenge in predicting the resultant photon flux in the X-ray energy bands is due to the...Newton, an X-ray astronomical observatory. We use OMNI solar wind conditions, heavy ion composition data from ACE, the Hodges neutral hydrogen model...of SWEEP was to compare theoretical models of X-ray emission in the terrestrial magnetosphere caused by the Solar Wind Charge Exchange

  10. Workplace Charging. Charging Up University Campuses

    Energy Technology Data Exchange (ETDEWEB)

    Giles, Carrie [ICF International, Fairfax, VA (United States); Ryder, Carrie [ICF International, Fairfax, VA (United States); Lommele, Stephen [National Renewable Energy Lab. (NREL), Golden, CO (United States)

    2016-03-01

    This case study features the experiences of university partners in the U.S. Department of Energy's (DOE) Workplace Charging Challenge with the installation and management of plug-in electric vehicle (PEV) charging stations.

  11. Segmented heat exchanger

    Science.gov (United States)

    Baldwin, Darryl Dean; Willi, Martin Leo; Fiveland, Scott Byron; Timmons, Kristine Ann

    2010-12-14

    A segmented heat exchanger system for transferring heat energy from an exhaust fluid to a working fluid. The heat exchanger system may include a first heat exchanger for receiving incoming working fluid and the exhaust fluid. The working fluid and exhaust fluid may travel through at least a portion of the first heat exchanger in a parallel flow configuration. In addition, the heat exchanger system may include a second heat exchanger for receiving working fluid from the first heat exchanger and exhaust fluid from a third heat exchanger. The working fluid and exhaust fluid may travel through at least a portion of the second heat exchanger in a counter flow configuration. Furthermore, the heat exchanger system may include a third heat exchanger for receiving working fluid from the second heat exchanger and exhaust fluid from the first heat exchanger. The working fluid and exhaust fluid may travel through at least a portion of the third heat exchanger in a parallel flow configuration.

  12. Insulator - Insulator Contact Charging as a Function of Pressure

    Science.gov (United States)

    Hogue, Michael D.; Mucciolo, E. R.; Calle, C. I.

    2006-01-01

    Metal - metal and metal - insulator contact or triboelectric charging are well known phenomena with good theoretical understanding of the charge exchange mechanism. However, insulator - insulator charging is not as well understood. Theoretical and experimental research has been performed that shows that the surface charge on an insulator after triboelectric charging with another insulator is rapidly dissipated with lowered atmospheric pressure. This pressure discharge is consistent with surface ions being evaporated off the surface once their vapor pressure is attained. A two-phase equilibrium model based on an ideal gas of singly charged ions in equilibrium with a submonolayer adsorbed film was developed to describe the pressure dependence of the surface charge on an insulator. The resulting charge density equation is an electrostatic version of the Langmuir isotherm.

  13. Do Charge State Signatures Guarantee Protein Conformations?

    Science.gov (United States)

    Hall, Zoe; Robinson, Carol V.

    2012-07-01

    The extent to which proteins in the gas phase retain their condensed-phase structure is a hotly debated issue. Closely related to this is the degree to which the observed charge state reflects protein conformation. Evidence from electron capture dissociation, hydrogen/deuterium exchange, ion mobility, and molecular dynamics shows clearly that there is often a strong correlation between the degree of folding and charge state, with the most compact conformations observed for the lowest charge states. In this article, we address recent controversies surrounding the relationship between charge states and folding, focussing also on the manipulation of charge in solution and its effect on conformation. `Supercharging' reagents that have been used to effect change in charge state can promote unfolding in the electrospray droplet. However for several protein complexes, supercharging does not appear to perturb the structure in that unfolding is not detected. Consequently, a higher charge state does not necessarily imply unfolding. Whilst the effect of charge manipulation on conformation remains controversial, there is strong evidence that a folded, compact state of a protein can survive in the gas phase, at least on a millisecond timescale. The exact nature of the side-chain packing and secondary structural elements in these compact states, however, remains elusive and prompts further research.

  14. 7 CFR 1427.22 - Commodity certificate exchanges.

    Science.gov (United States)

    2010-01-01

    ... ending with the 2009 crop and will not be available for subsequent crops. (b) The exchange rate is the lesser of: (1) The loan rate and charges, plus interest applicable to the loan, or (2) The adjusted world... 7 Agriculture 10 2010-01-01 2010-01-01 false Commodity certificate exchanges. 1427.22 Section 1427...

  15. 7 CFR 1421.110 - Commodity certificate exchanges.

    Science.gov (United States)

    2010-01-01

    ... commodity certificate for the marketing assistance loan collateral. (b) The exchange rate is the lesser of: (1) The loan rate and charges, plus interest applicable to the loan; (2) The prevailing world market... determined by CCC. (c) Commodity certificate exchanges may not be used when locking in a repayment rate under...

  16. Using Ion Exchange Chromatography to Separate and Quantify Complex Ions

    Science.gov (United States)

    Johnson, Brian J.

    2014-01-01

    Ion exchange chromatography is an important technique in the separation of charged species, particularly in biological, inorganic, and environmental samples. In this experiment, students are supplied with a mixture of two substitution-inert complex ions. They separate the complexes by ion exchange chromatography using a "flash"…

  17. Charge transfer in ultracold gases via Feshbach resonances

    Science.gov (United States)

    Gacesa, Marko; Côté, Robin

    2017-06-01

    We investigate the prospects of using magnetic Feshbach resonance to control charge exchange in ultracold collisions of heteroisotopic combinations of atoms and ions of the same element. The proposed treatment, readily applicable to alkali or alkaline-earth metals, is illustrated on cold collisions of +9Be and 10Be. Feshbach resonances are characterized by quantum scattering calculations in a coupled-channel formalism that includes non-Born-Oppenheimer terms originating from the nuclear kinetic operator. Near a resonance predicted at 322 G, we find the charge exchange rate coefficient to rise from practically zero to values greater than 10-12cm3 /s. Our results suggest controllable charge exchange processes between different isotopes of suitable atom-ion pairs, with potential applications to quantum systems engineered to study charge diffusion in trapped cold atom-ion mixtures and emulate many-body physics.

  18. Hybrid Quantum Systems with Trapped Charged Particles

    Science.gov (United States)

    Kotler, Shlomi; Leibfried, Dietrich; Simmonds, Raymond; Wineland, Dave

    We will review a joint effort by the Ion Storage Group and the Advanced Microwave Photonics Group at NIST (Boulder, CO) to design a hybrid system that interfaces charged particles with macroscopic high-Q resonators. We specifically consider coupling trapped charges to superconducting LC resonators, the mechanical modes of Silicon-Nitride membranes, and piezo-electric materials. We aim to achieve the strong coupling regime, where a single quantum of motion of the trapped charge can be coherently exchanged with harmonic motion of the macroscopic entity (electrical and/or mechanical). These kind of devices could potentially take advantage of both macroscopic control techniques and the long quantum coherence of its trapped charged particles.

  19. Group IV nanocrystals with ion-exchangeable surface ligands and methods of making the same

    Energy Technology Data Exchange (ETDEWEB)

    Wheeler, Lance M.; Nichols, Asa W.; Chernomordik, Boris D.; Anderson, Nicholas C.; Beard, Matthew C.; Neale, Nathan R.

    2018-01-09

    Methods are described that include reacting a starting nanocrystal that includes a starting nanocrystal core and a covalently bound surface species to create an ion-exchangeable (IE) nanocrystal that includes a surface charge and a first ion-exchangeable (IE) surface ligand ionically bound to the surface charge, where the starting nanocrystal core includes a group IV element.

  20. 78 FR 26667 - Self-Regulatory Organizations; EDGA Exchange, Inc.; Notice of Filing and Immediate Effectiveness...

    Science.gov (United States)

    2013-05-07

    ... charges as its billing for port fees is reasonably constrained by competitive alternatives.\\10\\ If a... competitive dynamic imposes powerful restraints on the ability of any exchange to charge unreasonable fees for... discussed above, the Exchange believes that fees for connectivity are constrained by the robust competition...

  1. 78 FR 26669 - Self-Regulatory Organizations; EDGX Exchange, Inc.; Notice of Filing and Immediate Effectiveness...

    Science.gov (United States)

    2013-05-07

    ..., and other charges as its billing for port fees is reasonably constrained by competitive alternatives... that this competitive dynamic imposes powerful restraints on the ability of any exchange to charge... the Act. As discussed above, the Exchange believes that fees for connectivity are constrained by the...

  2. Totalization Data Exchange (TDEX)

    Data.gov (United States)

    Social Security Administration — The Totalization Data Exchange (TDEX) process is an exchange between SSA and its foreign country partners to identify deaths of beneficiaries residing abroad. The...

  3. 17 CFR 256.457-2 - Indirect costs charged to associate companies.

    Science.gov (United States)

    2010-04-01

    ... 17 Commodity and Securities Exchanges 3 2010-04-01 2010-04-01 false Indirect costs charged to associate companies. 256.457-2 Section 256.457-2 Commodity and Securities Exchanges SECURITIES AND EXCHANGE COMMISSION (CONTINUED) UNIFORM SYSTEM OF ACCOUNTS FOR MUTUAL SERVICE COMPANIES AND SUBSIDIARY SERVICE COMPANIES, PUBLIC UTILITY HOLDING COMPANY...

  4. 17 CFR 256.458-2 - Indirect costs charged to nonassociate companies.

    Science.gov (United States)

    2010-04-01

    ... 17 Commodity and Securities Exchanges 3 2010-04-01 2010-04-01 false Indirect costs charged to nonassociate companies. 256.458-2 Section 256.458-2 Commodity and Securities Exchanges SECURITIES AND EXCHANGE COMMISSION (CONTINUED) UNIFORM SYSTEM OF ACCOUNTS FOR MUTUAL SERVICE COMPANIES AND SUBSIDIARY SERVICE COMPANIES, PUBLIC UTILITY HOLDING COMPAN...

  5. Electrically switched ion exchange

    Energy Technology Data Exchange (ETDEWEB)

    Lilga, M.A. [Pacific Northwest National Lab., Richland, WA (United States); Schwartz, D.T.; Genders, D.

    1997-10-01

    A variety of waste types containing radioactive {sup 137}Cs are found throughout the DOE complex. These waste types include water in reactor cooling basins, radioactive high-level waste (HLW) in underground storage tanks, and groundwater. Safety and regulatory requirements and economics require the removal of radiocesium before these wastes can be permanently disposed of. Electrically Switched Ion Exchange (ESIX) is an approach for radioactive cesium separation that combines IX and electrochemistry to provide a selective, reversible, and economic separation method that also produces little or no secondary waste. In the ESIX process, an electroactive IX film is deposited electrochemically onto a high-surface area electrode, and ion uptake and elution are controlled directly by modulating the potential of the film. For cesium, the electroactive films under investigation are ferrocyanides, which are well known to have high selectivities for cesium in concentrated sodium solutions. When a cathode potential is applied to the film, Fe{sup +3} is reduced to the Fe{sup +2} state, and a cation must be intercalated into the film to maintain charge neutrality (i.e., Cs{sup +} is loaded). Conversely, if an anodic potential is applied, a cation must be released from the film (i.e., Cs{sup +} is unloaded). Therefore, to load the film with cesium, the film is simply reduced; to unload cesium, the film is oxidized.

  6. 76 FR 2934 - Self-Regulatory Organizations; Chicago Board Options Exchange, Incorporated; Notice of Filing and...

    Science.gov (United States)

    2011-01-18

    ... Immediate Effectiveness of Proposed Rule Change Related to Exchange Fees for Fiscal Year 2011 January 11... one or more exchanges in connection with the Options Order Protection and Locked/Crossed Market Plan... Fees Schedule: Booth Fees: The Exchange currently charges $185 per month for use of a perimeter booth...

  7. Charged Domain Walls

    OpenAIRE

    Campanelli, L.; Cea, P.; Fogli, G. L.; Tedesco, L.

    2003-01-01

    In this paper we investigate Charged Domain Walls (CDW's), topological defects that acquire surface charge density $Q$ induced by fermion states localized on the walls. The presence of an electric and magnetic field on the walls is also discussed. We find a relation in which the value of the surface charge density $Q$ is connected with the existence of such topological defects.

  8. Electron Charged Graphite-based Hydrogen Storage Material

    Energy Technology Data Exchange (ETDEWEB)

    Dr. Chinbay Q. Fan; D Manager

    2012-03-14

    The electron-charge effects have been demonstrated to enhance hydrogen storage capacity using materials which have inherent hydrogen storage capacities. A charge control agent (CCA) or a charge transfer agent (CTA) was applied to the hydrogen storage material to reduce internal discharge between particles in a Sievert volumetric test device. GTI has tested the device under (1) electrostatic charge mode; (2) ultra-capacitor mode; and (3) metal-hydride mode. GTI has also analyzed the charge distribution on storage materials. The charge control agent and charge transfer agent are needed to prevent internal charge leaks so that the hydrogen atoms can stay on the storage material. GTI has analyzed the hydrogen fueling tank structure, which contains an air or liquid heat exchange framework. The cooling structure is needed for hydrogen fueling/releasing. We found that the cooling structure could be used as electron-charged electrodes, which will exhibit a very uniform charge distribution (because the cooling system needs to remove heat uniformly). Therefore, the electron-charge concept does not have any burden of cost and weight for the hydrogen storage tank system. The energy consumption for the electron-charge enhancement method is quite low or omitted for electrostatic mode and ultra-capacitor mode in comparison of other hydrogen storage methods; however, it could be high for the battery mode.

  9. 78 FR 28137 - Exchange Visitor Program-Fees and Charges

    Science.gov (United States)

    2013-05-14

    ... Management and Budget (OMB) Circular A-25 regarding such fee calculation. The Department received thirteen... have an annual effect on the economy of $100,000,000 or more. The Department estimates that... monetary effect on the economy that the Department is able to identify. A rule is also considered ``major...

  10. Space Charge Effects

    CERN Document Server

    Ferrario, M.; Palumbo, L.

    2014-12-19

    The space charge forces are those generated directly by the charge distribution, with the inclusion of the image charges and currents due to the interaction of the beam with a perfectly conducting smooth pipe. Space charge forces are responsible for several unwanted phenomena related to beam dynamics, such as energy loss, shift of the synchronous phase and frequency , shift of the betatron frequencies, and instabilities. We will discuss in this lecture the main feature of space charge effects in high-energy storage rings as well as in low-energy linacs and transport lines.

  11. Electrodynamics of Radiating Charges

    Directory of Open Access Journals (Sweden)

    Øyvind Grøn

    2012-01-01

    Full Text Available The theory of electrodynamics of radiating charges is reviewed with special emphasis on the role of the Schott energy for the conservation of energy for a charge and its electromagnetic field. It is made clear that the existence of radiation from a charge is not invariant against a transformation between two reference frames that has an accelerated motion relative to each other. The questions whether the existence of radiation from a uniformly accelerated charge with vanishing radiation reaction force is in conflict with the principle of equivalence and whether a freely falling charge radiates are reviewed. It is shown that the resolution of an electromagnetic “perpetuum mobile paradox” associated with a charge moving geodetically along a circular path in the Schwarzschild spacetime requires the so-called tail terms in the equation of motion of a charged particle.

  12. Ion Exchange Resins Transforming Drug Delivery Systems.

    Science.gov (United States)

    Gupta, Shweta; Benien, Parul; Sahoo, P K

    2010-07-01

    Ion-exchange resins are light, porous, three-dimensional high molecular weight cross - linked matrix of hydrocarbon chains carrying positively or negatively charged sites that can attract an ion of opposite charge from the surrounding medium. There is stoichiometric exchange of mobile ions between the solid and the solution called as Ion-exchange which does not lead to any radical change in the properties and structure of the solid. Depending upon the type of Ionexchanged it can be either Cation-exchange or Anion-exchange. They are prepared in the form of granules, beads or sheets. As drug delivery systems they have received considerable attention after the 1950s due to their inertness, freedom from side effects, high drug loading capacity, ease of sterilization and the fact that their structure can be easily altered to achieve the desired drug release characteristics. Their use is revolutionizing all traditional delivery systems namely - oral, nasal, ophthalmic and parenteral. Ion- exchange resins have been used for the development of novel drug delivery systems (NDDSs), to modify the characteristics of the dosage form and various other biomedical applications. The present article deals with the varied applications of ion-exchange resins for taste making, as resinates (simple and microencapsulated or coated), Pennkinetic systems, in selective recovery of pharmaceuticals, in pH and ionic strength responsive systems, in gastro-retentive systems, in hollow fiber systems, as sigmoidal release systems, as site specific delivery systems and as inotophoretically assisted transdermal drug delivery systems. They also have an immense importance when used as disintegrants / superdisintegrants in formulation of orodispersible tablets, powder processing aids and in the dissolution and stabilization of drugs.

  13. VT Telephone Exchange Boundaries

    Data.gov (United States)

    Vermont Center for Geographic Information — (Link to Metadata) The UtilityTelecom_EXCHANGE represents Vermont Telephone Exchange boundaries as defined by the VT Public Service Board. The original data was...

  14. Effects of graphene coating and charge injection on water adsorption of solid surfaces.

    Science.gov (United States)

    Guo, Yufeng; Guo, Wanlin

    2013-11-07

    The adhesion and cohesion of water molecules on graphene-coated and bare copper and mica substrates under charge injection have been extensively studied by first-principles calculations. Water adsorption on graphene-coated copper surface is weakened by injecting negative charges into the substrate, while enhanced by positive charges. Both negatively and positively charge injecting on graphene-coated mica strengthen the adsorption between water and the surface. While the adhesive and cohesive energies of water adsorption on charged bare copper and mica exhibit similar trends and much stronger response to charge injection. The charge sensitivity of water adsorbing on positively charged surfaces is significantly weakened by the graphene coating layer, mainly due to lower interfacial charge exchange. Our results suggest a viable way to modify water adsorption on a graphene-coated surface and unveil the role of graphene as a passivation layer for the wetting of a charged substrate.

  15. Charged slurry droplet research

    Science.gov (United States)

    Kelly, A. J.

    1989-02-01

    Rayleigh Bursting, wherein critically charged droplets explosively expel a number of micron sized sibling droplets, enhances atomization and combustion of all liquid fuels. Droplet surface charge is retained during evaporation, permitting multiple Rayleigh Bursts to occur. Moreover, the charge is available for the deagglomeration of residual particulate flocs from slurry droplet evaporation. To fill gaps in our knowledge of these processes, an experimental program involving the use of a charged droplet levitator and a Quadrupole Mass Spectrometer, High Speed Electrometer (QMS/HSE) has been undertaken to observe the disruption and to measure quantitatively the debris. A charged droplet levitator based on a new video frame grabber technology to image transient events, is described. Sibling droplet size is ten microns or less and is close to, if not coincident with, the predicted phase transition in droplet charging level. The research effort has focused on the exploration of this transition and its implications.

  16. Fast Charging and Smart Charging Tests for Electric Vehicles Batteries Using Renewable Energy

    Directory of Open Access Journals (Sweden)

    Forero Camacho Oscar Mauricio

    2016-01-01

    Full Text Available Electric Vehicles (EV technologies are still relatively new and under strong development. Although some standardized solutions are being promoted and becoming a new trend, there is an outstanding need for common platforms and sharing of knowledge and core technologies. This paper presents the development of a test platform, including three Li-ion batteries designed for EV applications, and three associated bi-directional power converters, for testing impacts on different advanced loadings of EV batteries. Different charging algorithms/profiles have been tested, including constant current and power, and forced and pulsed power. The aim of the tests has been to study the impact of smart charging and fast charging on the power system, on the battery state of health and degradation, and to find out the limitations of the batteries for a Smart Grid. The paper outlines the advantages and disadvantages of both tests in terms of regulation of the aggregated local power, power capacity and the power exchange with the grid. The smart charging tests performed have demonstrated that even with a simple control algorithm, without any forecasting, it is possible to provide the required charging and at the same time the power system services, reducing the peak power and the energy losses in the power connection line of the power exchange with the national grid.

  17. Variable Charge Soils: Mineralogy and Chemistry

    Energy Technology Data Exchange (ETDEWEB)

    Qafoku, Nik; Van Ranst, Eric; Noble, Andrew; Baert, Geert

    2003-11-01

    ferromagnesian-rich parent materials) the surfaces of phyllosilicates are coated to a lesser or greater extent by amorphous or crystalline, oppositely charged nanoparticles of Fe and Al oxides. These coatings exhibit a high reactive surface area and help cementing larger particles with one another. As a result of these electrostatic interactions, stable microaggregates that are difficult to disperse are formed in variable charge soils. Most of highly weathered soils have reached the “advanced stage” of Jackson-Sherman weathering sequence that is characterized by the removal of Na, K, Ca, Mg, and Fe(II), the presence of Fe and Al polymers, and very dilute soil solutions with an ionic strength (IS) of less than 1 mmol L-1. The inter-penetration or overlapping of the diffuse double layers on oppositely charged surfaces may occur in these dilute systems. These diffuse layer interactions may affect the magnitude of the effective charge, i.e., the counter-ion charge (4). In addition, salt adsorption, which is defined as the simultaneous adsorption in equivalent amounts of the cation and anion of an electrolyte with no net release of other ions into the soil solution, appears to be a common phenomenon in these soils. They act as cation- and anion-exchangers and as salt-sorbers. The magnitude of salt adsorption depends strongly on initial IS in the soil solution and the presence in appreciable amounts of oppositely charged surfaces. Among the authors that have made illustrious contributions towards a better understanding of these fascinating soil systems are S. Matson, R.K. Schofield, van Olphen, M.E. Sumner, G.W. Thomas, G.P. Gillman, G. Uehara, B.K.G. Theng, K. Wada, N.J. Barrow, J.W. Bowden, R.J. Hunter and G. Sposito. This entry is mainly based on publications by these authors.

  18. Trapping a Charged Atom

    Energy Technology Data Exchange (ETDEWEB)

    Hla, Saw-Wai [Center for Nanoscale Materials, Nanoscience and Technology Division, Argonne National Laboratory, Lemont, Illinois 60439, United States; Nanoscience and Quantum Phenomena Institute and Condensed Matter and Surface Science Program, Ohio University, Athens, Ohio 45701, United States

    2015-09-01

    Engineering of supramolecular assemblies on surfaces is an emerging field of research impacting chemistry, electronics, and biology. Among supramolecular assemblies, metal-containing structures provide rich properties and enable robust nanostructured designs. In this issue of ACS Nano, Feng eta!, report that supramolecular assemblies can trap gold adatoms that maintain a charged state on a Au(111) surface. Such charged adatoms may offer additional degrees of freedom in designing novel supramolecular architectures for efficient catalysts, memory, and charge storage for medical applications.

  19. Contractor Software Charges

    National Research Council Canada - National Science Library

    Granetto, Paul

    1994-01-01

    .... Examples of computer software costs that contractors charge through indirect rates are material management systems, security systems, labor accounting systems, and computer-aided design and manufacturing...

  20. Ideal Heat Exchange System

    Science.gov (United States)

    Tsirlin, A. M.

    2017-09-01

    The requirements with which a heat exchange system should comply in order that at certain values of the total contact surface and heat load the entropy production in it should be minimal have been determined. It has been shown that this system can serve as a standard for real systems of irreversible heat exchange. We have found the conditions for physical realizability of a heat exchange system in which heat exchange occurs by a law linear with respect to the temperature difference between contacting flows. Analogous conditions are given without deriving for the case of heat exchange by the Fourier law.

  1. Resolution exchange simulation.

    Science.gov (United States)

    Lyman, Edward; Ytreberg, F Marty; Zuckerman, Daniel M

    2006-01-20

    We extend replica-exchange simulation in two ways and apply our approaches to biomolecules. The first generalization permits exchange simulation between models of differing resolution--i.e., between detailed and coarse-grained models. Such "resolution exchange" can be applied to molecular systems or spin systems. The second extension is to "pseudoexchange" simulations, which require little CPU usage for most levels of the exchange ladder and also substantially reduce the need for overlap between levels. Pseudoexchanges can be used in either replica or resolution exchange simulations. We perform efficient, converged simulations of a 50-atom peptide to illustrate the new approaches.

  2. Surface Charging and Points of Zero Charge

    CERN Document Server

    Kosmulski, Marek

    2009-01-01

    Presents Points of Zero Charge data on well-defined specimen of materials sorted by trademark, manufacturer, and location. This text emphasizes the comparison between particular results obtained for different portions of the same or very similar material and synthesizes the information published in research reports over the past few decades

  3. Charged weak currents

    CERN Document Server

    Turlay, René

    1979-01-01

    In this review of charged weak currents the author concentrates on inclusive high energy neutrino physics. The authors discusses the general structure of charged currents, new results on total cross- sections, the Callan-Gross relation, antiquark distributions, scaling violations and tests of QCD. A very short summary on multilepton physics is given. (44 refs).

  4. Benchmarking charging infrastructure utilization

    NARCIS (Netherlands)

    Wolbertus, R.; van den Hoed, R.; Maase, S.

    2016-01-01

    Since 2012 the dutch metropolitan area (the metropole region of amsterdam, the city of amsterdam, rotterdam, the hague, utrecht ) cooperate in finding the best way to stimulate electric mobility through the implementation of a public charging infrastructure. with more than 5600 charge points and 1.6

  5. Induced Charge Capacitive Deionization

    CERN Document Server

    Rubin, S; Biesheuvel, P M; Bercovici, M

    2016-01-01

    We demonstrate the phenomenon of induced-charge capacitive deionization (ICCDI) that occurs around a porous and conducting particle immersed in an electrolyte, under the action of an external electrostatic field. The external electric field induces an electric dipole in the porous particle, leading to capacitive charging of its volume by both cations and anions at opposite poles. This regime is characterized both by a large RC charging time and a small electrochemical charge relaxation time, which leads to rapid and significant deionization of ionic species from a volume which is on the scale of the particle. We show by theory and experiment that the transient response around a cylindrical particle results in spatially non-uniform charging and non-steady growth of depletion regions which emerge around the particle's poles. Potentially, ICCDI can be useful in applications where fast concentration changes of ionic species are required over large volumes.

  6. Electric vehicle battery charging controller

    OpenAIRE

    Pedersen, Anders Bro; Andersen, Peter Bach; Sørensen, Thomas Meier; Martinenas, Sergejus

    2016-01-01

    The present invention provides an electric vehicle charging controller. The charging controller comprises a first interface connectable to an electric vehicle charge source for receiving a charging current, a second interface connectable to an electric vehicle for providing the charging current to a battery management system in the electric vehicle to charge a battery therein, a first communication unit for receiving a charging message via a communication network, and a control unit for contr...

  7. Ethical leadership and followers' taking charge: trust in, and identification with, leader as mediators

    National Research Council Canada - National Science Library

    Lee, Kihyun

    2016-01-01

    .... Drawing on both social exchange theory and social identity theory, I examined the influence of ethical leadership on followers taking charge through the mediation of trust in leader and identification with leader...

  8. Electric vehicle battery charging controller

    DEFF Research Database (Denmark)

    2016-01-01

    The present invention provides an electric vehicle charging controller. The charging controller comprises a first interface connectable to an electric vehicle charge source for receiving a charging current, a second interface connectable to an electric vehicle for providing the charging current...... to a battery management system in the electric vehicle to charge a battery therein, a first communication unit for receiving a charging message via a communication network, and a control unit for controlling a charging current provided from the charge source to the electric vehicle, the controlling at least...

  9. Adaptively Compressed Exchange Operator

    CERN Document Server

    Lin, Lin

    2016-01-01

    The Fock exchange operator plays a central role in modern quantum chemistry. The large computational cost associated with the Fock exchange operator hinders Hartree-Fock calculations and Kohn-Sham density functional theory calculations with hybrid exchange-correlation functionals, even for systems consisting of hundreds of atoms. We develop the adaptively compressed exchange operator (ACE) formulation, which greatly reduces the computational cost associated with the Fock exchange operator without loss of accuracy. The ACE formulation does not depend on the size of the band gap, and thus can be applied to insulating, semiconducting as well as metallic systems. In an iterative framework for solving Hartree-Fock-like systems, the ACE formulation only requires moderate modification of the code, and can be potentially beneficial for all electronic structure software packages involving exchange calculations. Numerical results indicate that the ACE formulation can become advantageous even for small systems with tens...

  10. Charge gradient microscopy

    Energy Technology Data Exchange (ETDEWEB)

    Roelofs, Andreas; Hong, Seungbum

    2018-02-06

    A method for rapid imaging of a material specimen includes positioning a tip to contact the material specimen, and applying a force to a surface of the material specimen via the tip. In addition, the method includes moving the tip across the surface of the material specimen while removing electrical charge therefrom, generating a signal produced by contact between the tip and the surface, and detecting, based on the data, the removed electrical charge induced through the tip during movement of the tip across the surface. The method further includes measuring the detected electrical charge.

  11. 75 FR 59310 - Self-Regulatory Organizations; New York Stock Exchange LLC; Order Approving a Proposed Rule...

    Science.gov (United States)

    2010-09-27

    ... From the Federal Register Online via the Government Publishing Office SECURITIES AND EXCHANGE COMMISSION Self-Regulatory Organizations; New York Stock Exchange LLC; Order Approving a Proposed Rule Change Amending Its Price List To Reflect Fees Charged for Co-Location Services September 21, 2010. On August 3, 2010, New York Stock Exchange LLC (`...

  12. Laser Processed Heat Exchangers

    Science.gov (United States)

    Hansen, Scott

    2017-01-01

    The Laser Processed Heat Exchanger project will investigate the use of laser processed surfaces to reduce mass and volume in liquid/liquid heat exchangers as well as the replacement of the harmful and problematic coatings of the Condensing Heat Exchangers (CHX). For this project, two scale unit test articles will be designed, manufactured, and tested. These two units are a high efficiency liquid/liquid HX and a high reliability CHX.

  13. Microsoft Exchange 2013 cookbook

    CERN Document Server

    Van Horenbeeck, Michael

    2013-01-01

    This book is a practical, hands-on guide that provides the reader with a number of clear, step-by-step exercises.""Microsoft Exchange 2013 Cookbook"" is targeted at network administrators who deal with the Exchange server in their day-to-day jobs. It assumes you have some practical experience with previous versions of Exchange (although this is not a requirement), without being a subject matter expert.

  14. Microtube strip heat exchanger

    Science.gov (United States)

    Doty, F. D.

    1991-07-01

    During the last quarter, Doty Scientific, Inc. (DSI) continued to make progress on the microtube strip (MTS) heat exchanger. The DSI completed a heat exchanger stress analysis of the ten-module heat exchanger bank; and performed a shell-side flow inhomogeneity analysis of the three-module heat exchanger bank. The company produced 50 tubestrips using an in-house CNC milling machine and began pressing them onto tube arrays. The DSI revised some of the tooling required to encapsulate a tube array and press tubestrips into the array to improve some of the prototype tooling.

  15. Charged cosmological black hole

    Science.gov (United States)

    Moradi, Rahim; Stahl, Clément; Firouzjaee, Javad T.; Xue, She-Sheng

    2017-11-01

    The cosmological black holes are black holes living not in an asymptotically flat universe but in an expanding spacetime. They have a rich dynamics especially for their mass and horizon. In this article, we perform a natural step in investigating this new type of black hole: we consider the possibility of a charged cosmological black hole. We derive the general equations of motion governing its dynamics and report a new analytic solution for the special case of the charged Lematre-Tolman-Bondi equations of motion that describe a charged cosmological black hole. We then study various relevant quantities for the characterization of the black hole, such as the C-function, the effect of the charge on the black hole flux, and the nature of the singularity. We also perform numerical investigations to strengthen our results. Finally, we challenge a model of gamma ray burst within our framework.

  16. EV Charging Infrastructure Roadmap

    Energy Technology Data Exchange (ETDEWEB)

    Karner, Donald [Electric Transportation Inc., Rogers, AR (United States); Garetson, Thomas [Electric Transportation Inc., Rogers, AR (United States); Francfort, Jim [Idaho National Lab. (INL), Idaho Falls, ID (United States)

    2016-08-01

    As highlighted in the U.S. Department of Energy’s EV Everywhere Grand Challenge, vehicle technology is advancing toward an objective to “… produce plug-in electric vehicles that are as affordable and convenient for the average American family as today’s gasoline-powered vehicles …” [1] by developing more efficient drivetrains, greater battery energy storage per dollar, and lighter-weight vehicle components and construction. With this technology advancement and improved vehicle performance, the objective for charging infrastructure is to promote vehicle adoption and maximize the number of electric miles driven. The EV Everywhere Charging Infrastructure Roadmap (hereafter referred to as Roadmap) looks forward and assumes that the technical challenges and vehicle performance improvements set forth in the EV Everywhere Grand Challenge will be met. The Roadmap identifies and prioritizes deployment of charging infrastructure in support of this charging infrastructure objective for the EV Everywhere Grand Challenge

  17. Water Quality Protection Charges

    Data.gov (United States)

    Montgomery County of Maryland — The Water Quality Protection Charge (WQPC) is a line item on your property tax bill. WQPC funds many of the County's clean water initiatives including: • Restoration...

  18. Space-Charge Effect

    CERN Document Server

    Chauvin, N.

    2013-12-16

    First, this chapter introduces the expressions for the electric and magnetic space-charge internal fields and forces induced by high-intensity beams. Then, the root-mean-square equation with space charge is derived and discussed. In the third section, the one-dimensional Child-Langmuir law, which gives the maximum current density that can be extracted from an ion source, is exposed. Space-charge compensation can occur in the low-energy beam transport lines (located after the ion source). This phenomenon, which counteracts the spacecharge defocusing effect, is explained and its main parameters are presented. The fifth section presents an overview of the principal methods to perform beam dynamics numerical simulations. An example of a particles-in-cells code, SolMaxP, which takes into account space-charge compensation, is given. Finally, beam dynamics simulation results obtained with this code in the case of the IFMIF injector are presented.

  19. Electric Vehicle Charging Modeling

    OpenAIRE

    Grahn, Pia

    2014-01-01

    With an electrified passenger transportation fleet, carbon dioxide emissions could be reduced significantly depending on the electric power production mix. Increased electric power consumption due to electric vehicle charging demands of electric vehicle fleets may be met by increased amount of renewable power production in the electrical systems. With electric vehicle fleets in the transportation system there is a need for establishing an electric vehicle charging infrastructure that distribu...

  20. Charge Breeding Techniques

    CERN Document Server

    Wenander, F

    2004-01-01

    The numerous newly built and forthcoming post-accelerators for radioactive ions, produced with the isotope separator on-line (ISOL) technique, all have a need for an efficient method to accelerate the precious primary ions. By increasing the ion charge-to-mass ratio directly after the radioactive ion production stage, a short and compact linear accelerator can be employed. Not only the efficiency, but also the rapidity of such a charge-to-mass increasing process, called charge breeding, is a crucial factor for the often short-lived radioisotopes. The traditional foil or gas stripping technique was challenged some five to ten years ago by novel schemes for charge breeding. The transformation from 1+ to n+ charged ions takes place inside an Electron Beam Ion Source/Trap (EBIS/T) or Electron Cyclotron Resonance Ion Source/Trap (ECRIS/T) by electron-ion collisions. These charge breeders are located in the low-energy part of the machine before the accelerating structures. Because of the capability of these devices...

  1. MOSFET Electric-Charge Sensor

    Science.gov (United States)

    Robinson, Paul A., Jr.

    1988-01-01

    Charged-particle probe compact and consumes little power. Proposed modification enables metal oxide/semiconductor field-effect transistor (MOSFET) to act as detector of static electric charges or energetic charged particles. Thickened gate insulation acts as control structure. During measurements metal gate allowed to "float" to potential of charge accumulated in insulation. Stack of modified MOSFET'S constitutes detector of energetic charged particles. Each gate "floats" to potential induced by charged-particle beam penetrating its layer.

  2. 17 CFR 256.457-1 - Direct costs charged to associate companies.

    Science.gov (United States)

    2010-04-01

    ... charged to associate companies. This account shall include those direct costs which can be identified through a work order system as being applicable to services performed for associate companies. This... associate companies. 256.457-1 Section 256.457-1 Commodity and Securities Exchanges SECURITIES AND EXCHANGE...

  3. Multiply charged ion dissociation in Fourier transform ion cyclotron resonance mass spectrometer

    Energy Technology Data Exchange (ETDEWEB)

    Wu, Qinyuan; Bakhtair, R.; Sherman, M.G.; Hofstadler, S.A.; Smith, R.D. [Pacific Northwest Laboratory, Richland, WA (United States)

    1994-12-31

    Bimolecular ions of up to MDa size with thousands of charges have recently been trapped and studied in this laboratory using electrospray ionization (ESI) and Fourier transform ion cyclotron resonance mass spectrometer (FTICRMS). For structural analysis, multiply charged ions generated by ESI can be dissociated at the interface, by collision induced dissociation (CID) or Surface induced dissociation (SID). However, charge exchange with the surface and charge partition among the fragments significantly complicate the SID and CID spectra of multiply charged large ions. High resolution FTICR is an ideal solution to this problem.

  4. GRUNDTVIG in transnational exchange

    DEFF Research Database (Denmark)

    Grundtvig in transnational exchange is the report from the seminar in december 2015 in cooperation with University of Cape Town and University of Hamburg.......Grundtvig in transnational exchange is the report from the seminar in december 2015 in cooperation with University of Cape Town and University of Hamburg....

  5. Optimization of Heat Exchangers

    Energy Technology Data Exchange (ETDEWEB)

    Ivan Catton

    2010-10-01

    The objective of this research is to develop tools to design and optimize heat exchangers (HE) and compact heat exchangers (CHE) for intermediate loop heat transport systems found in the very high temperature reator (VHTR) and other Generation IV designs by addressing heat transfer surface augmentation and conjugate modeling. To optimize heat exchanger, a fast running model must be created that will allow for multiple designs to be compared quickly. To model a heat exchanger, volume averaging theory, VAT, is used. VAT allows for the conservation of mass, momentum and energy to be solved for point by point in a 3 dimensional computer model of a heat exchanger. The end product of this project is a computer code that can predict an optimal configuration for a heat exchanger given only a few constraints (input fluids, size, cost, etc.). As VAT computer code can be used to model characteristics )pumping power, temperatures, and cost) of heat exchangers more quickly than traditional CFD or experiment, optimization of every geometric parameter simultaneously can be made. Using design of experiment, DOE and genetric algorithms, GE, to optimize the results of the computer code will improve heat exchanger disign.

  6. Education and Industry Exchange

    Science.gov (United States)

    Webb, Gerald A.

    1974-01-01

    Through an exchange plan a school representative worked at the personnel counter of a local company, and a supervisor from that company worked with counselors, faculty, administrators, and students from the local school. The exchange of ideas and insights were of benefit to the school and the company. (KP)

  7. Charge densities and charge noise in mesoscopic conductors

    Indian Academy of Sciences (India)

    February 2002 physics pp. 241–257. Charge densities and charge noise in mesoscopic conductors ... the charge noise [6] based on the scattering approach. Similar to the discussion of linear ...... a novel resistance which determines the dissipative effects in charging and decharging a. 254. Pramana – J. Phys., Vol. 58, No.

  8. Charge transfer in time-dependent density functional theory

    Science.gov (United States)

    Maitra, Neepa T.

    2017-10-01

    Charge transfer plays a crucial role in many processes of interest in physics, chemistry, and bio-chemistry. In many applications the size of the systems involved calls for time-dependent density functional theory (TDDFT) to be used in their computational modeling, due to its unprecedented balance between accuracy and efficiency. However, although exact in principle, in practise approximations must be made for the exchange-correlation functional in this theory, and the standard functional approximations perform poorly for excitations which have a long-range charge-transfer component. Intense progress has been made in developing more sophisticated functionals for this problem, which we review. We point out an essential difference between the properties of the exchange-correlation kernel needed for an accurate description of charge-transfer between open-shell fragments and between closed-shell fragments. We then turn to charge-transfer dynamics, which, in contrast to the excitation problem, is a highly non-equilibrium, non-perturbative, process involving a transfer of one full electron in space. This turns out to be a much more challenging problem for TDDFT functionals. We describe dynamical step and peak features in the exact functional evolving over time, that are missing in the functionals currently used. The latter underestimate the amount of charge transferred and manifest a spurious shift in the charge transfer resonance position. We discuss some explicit examples.

  9. Taming Highly Charged Radioisotopes

    Science.gov (United States)

    Chowdhury, Usman; Eberhardt, Benjamin; Jang, Fuluni; Schultz, Brad; Simon, Vanessa; Delheij, Paul; Dilling, Jens; Gwinner, Gerald

    2012-10-01

    The precise and accurate mass of short-lived radioisotopes is a very important parameter in physics. Contribution to the improvement of nuclear models, metrological standard fixing and tests of the unitarity of the Caibbibo-Kobayashi-Maskawa (CKM) matrix are a few examples where the mass value plays a major role. TRIUMF's ion trap for atomic and nuclear physics (TITAN) is a unique facility of three online ion traps that enables the mass measurement of short-lived isotopes with high precision (˜10-8). At present TITAN's electron beam ion trap (EBIT) increases the charge state to increase the precision, but there is no facility to significantly reduce the energy spread introduced by the charge breeding process. The precision of the measured mass of radioisotopes is linearly dependent on the charge state while the energy spread of the charged radioisotopes affects the precision adversely. To boost the precision level of mass measurement at TITAN without loosing too many ions, a cooler Penning trap (CPET) is being developed. CPET is designed to use either positively (proton) or negatively (electron) charged particles to reduce the energy spread via sympathetic cooling. Off-line setup of CPET is complete. Details of the working principles and updates are presented

  10. 78 FR 21993 - Self-Regulatory Organizations; BOX Options Exchange LLC; Notice of Filing and Immediate...

    Science.gov (United States)

    2013-04-12

    ... Schedule. Transactions in Non-Penny Pilot Classes Exchange Total fee \\11\\ Add fee charged Effect Treated as... Effectiveness of a Proposed Rule Change To Amend the Fee Schedule for Trading on BOX April 8, 2013. Pursuant to... Securities and Exchange Commission (``Commission'') a proposed rule change to amend the Fee Schedule for...

  11. 77 FR 42026 - Self-Regulatory Organizations; International Securities Exchange, LLC; Notice of Filing and...

    Science.gov (United States)

    2012-07-17

    ... currently charges to other market participants that employ a similar trading strategy. The Exchange also... order book.\\11\\ \\11\\ Id. The Exchange believes that the price differentiation between the various market... unfairly discriminatory because the proposed fees are consistent with price differentiation that exists...

  12. 77 FR 16304 - Self-Regulatory Organizations; International Securities Exchange, LLC; Notice of Filing and...

    Science.gov (United States)

    2012-03-20

    ... From the Federal Register Online via the Government Publishing Office SECURITIES AND EXCHANGE... Proposed Rule Change 1. Purpose The Exchange currently assesses per contract transaction charges and... Plus at the end of each month by looking back at each Market Maker's quoting statistics during that...

  13. 76 FR 63971 - Self-Regulatory Organizations; Chicago Board Options Exchange, Incorporated; Notice of Filing and...

    Science.gov (United States)

    2011-10-14

    ... COMMISSION Self-Regulatory Organizations; Chicago Board Options Exchange, Incorporated; Notice of Filing and...\\ notice is hereby given that on October 3, 2011, the Chicago Board Options Exchange, Incorporated (the... and Firms as either electronic or manual. See NYSE Amex Options Fees Schedule, Trade Related Charges...

  14. 77 FR 10595 - Self-Regulatory Organizations; EDGX Exchange, Inc.; Notice of Filing and Immediate Effectiveness...

    Science.gov (United States)

    2012-02-22

    ... delivery charges will apply to it. \\6\\ Although the size of the dataset can vary from day to day based on... connection with the same, the Exchange is proposing to amend its fee schedule applicable to Members and non... trading day. The downloaded file will contain the exact messages that were disseminated via the Exchange...

  15. 77 FR 10593 - Self-Regulatory Organizations; EDGA Exchange, Inc.; Notice of Filing and Immediate Effectiveness...

    Science.gov (United States)

    2012-02-22

    ... delivery charges will apply to it. \\6\\ Although the size of the dataset can vary from day to day based on... with the same, the Exchange is proposing to amend its fee schedule applicable to Members and non... trading day. The downloaded file will contain the exact messages that were disseminated via the Exchange...

  16. Heat exchanger design handbook

    CERN Document Server

    Thulukkanam, Kuppan

    2013-01-01

    Completely revised and updated to reflect current advances in heat exchanger technology, Heat Exchanger Design Handbook, Second Edition includes enhanced figures and thermal effectiveness charts, tables, new chapter, and additional topics--all while keeping the qualities that made the first edition a centerpiece of information for practicing engineers, research, engineers, academicians, designers, and manufacturers involved in heat exchange between two or more fluids.See What's New in the Second Edition: Updated information on pressure vessel codes, manufacturer's association standards A new c

  17. 76 FR 21076 - Self-Regulatory Organizations; EDGA Exchange, Inc.; Notice of Filing and Immediate Effectiveness...

    Science.gov (United States)

    2011-04-14

    ... on the Exchange's Internet Web site at http://www.directedge.com . \\3\\ A Member is any registered... Parallel D or Parallel 2D with the DRT (Dark routing technique) option on BZX. BZX charges $0.0020 per.... Currently, when a Member uses the ROUT strategy, it is charged $0.0030 per share (Flag ``I'') when it routes...

  18. 76 FR 21416 - Self-Regulatory Organizations; International Securities Exchange, LLC; Notice of Filing and...

    Science.gov (United States)

    2011-04-15

    ... (GB) network connection. The Exchange currently has a tiered ] structure for the Ethernet/Managed Service Provider fee charged to Members. The Ethernet/Managed Service Provider fee is a fee charged to ISE Members to access the ISE's trading system via an Ethernet connection or via a third-party managed service...

  19. 3D printed micro/nanofluidic preconcentrator for charged sample based on ion concentration polarization

    Science.gov (United States)

    Pi, Hailong; Tong, Jianhua; Bian, Chao; Xia, Shanhong

    2017-05-01

    In this paper, we introduce a novel and simple method to fabricate a preconcentrator based on the ion concentration polarization phenomenon (ICP). Using a three-dimensional printed layer, the microchannels could be easily integrated with an ion exchange membrane which plays the role of the nanoporous junction needed for ICP. To demonstrate the preconcentration ability of the devices, we conducted experiments with negatively charged fluorescein sodium and positively charged rhodamine 6G. As a result, the negatively charged sample could be preconcentrated more than 18 fold by using a cation exchange membrane. The positively charged sample could be preconcentrated more than 40 fold by using an anion exchange membrane. This preconcentrator with a simple fabrication process could be implemented in various microfluidic systems for biochemical assays.

  20. Data Exchange Inventory System (DEXI)

    Data.gov (United States)

    Social Security Administration — Enterprise tool used to identify data exchanges occurring between SSA and our trading partners. DEXI contains information on both incoming and outgoing exchanges and...

  1. Microplate Heat Exchanger Project

    Data.gov (United States)

    National Aeronautics and Space Administration — We propose a microplate heat exchanger for cryogenic cooling systems used for continuous flow distributed cooling systems, large focal plane arrays, multiple cooling...

  2. Exchange Risk Management Policy

    CERN Document Server

    2005-01-01

    At the Finance Committee of March 2005, following a comment by the CERN Audit Committee, the Chairman invited the Management to prepare a document on exchange risk management policy. The Finance Committee is invited to take note of this document.

  3. HUD Exchange Grantee Database

    Data.gov (United States)

    Department of Housing and Urban Development — The About Grantees section of the HUD Exchange brings up contact information, reports, award, jurisdiction, and location data for organizations that receive HUD...

  4. NASA Earth Exchange (NEX)

    Data.gov (United States)

    National Aeronautics and Space Administration — The NASA Earth Exchange (NEX) represents a new platform for the Earth science community that provides a mechanism for scientific collaboration and knowledge sharing....

  5. Anion exchange polymer electrolytes

    Science.gov (United States)

    Kim, Yu Seung; Kim, Dae Sik

    2015-06-02

    Anion exchange polymer electrolytes that include guanidinium functionalized polymers may be used as membranes and binders for electrocatalysts in preparation of anodes for electrochemical cells such as solid alkaline fuel cells.

  6. Spacecraft Surface Charging Handbook

    Science.gov (United States)

    1992-11-01

    Location High potential si&e of C Pulser output Wires on drive pU~ Sensor Woih-voltuge Probe Cuwaln prole Current protw Connection tard ...477, 1982. 316 Gabriel , S. B. and Garrett, H. B.. "An Overview of Charging Environments," Space Environmental Effects on Materials Workshop, p. 495

  7. Charged fluids with symmetries

    Indian Academy of Sciences (India)

    Abstract. We investigate the role of symmetries for charged perfect fluids by assuming that spacetime admits a conformal Killing vector. The existence of a conformal symmetry places restrictions on the model. It is possible to find a general relationship for the Lie derivative of the electromagnetic field along the integral curves ...

  8. Charged particle beams

    CERN Document Server

    Humphries, Stanley

    2013-01-01

    Detailed enough for a text and sufficiently comprehensive for a reference, this volume addresses topics vital to understanding high-power accelerators and high-brightness-charged particle beams. Subjects include stochastic cooling, high-brightness injectors, and the free electron laser. Humphries provides students with the critical skills necessary for the problem-solving insights unique to collective physics problems. 1990 edition.

  9. Cryptographic Combinatorial Securities Exchanges

    Science.gov (United States)

    Thorpe, Christopher; Parkes, David C.

    We present a useful new mechanism that facilitates the atomic exchange of many large baskets of securities in a combinatorial exchange. Cryptography prevents information about the securities in the baskets from being exploited, enhancing trust. Our exchange offers institutions who wish to trade large positions a new alternative to existing methods of block trading: they can reduce transaction costs by taking advantage of other institutions’ available liquidity, while third party liquidity providers guarantee execution—preserving their desired portfolio composition at all times. In our exchange, institutions submit encrypted orders which are crossed, leaving a “remainder”. The exchange proves facts about the portfolio risk of this remainder to third party liquidity providers without revealing the securities in the remainder, the knowledge of which could also be exploited. The third parties learn either (depending on the setting) the portfolio risk parameters of the remainder itself, or how their own portfolio risk would change if they were to incorporate the remainder into a portfolio they submit. In one setting, these third parties submit bids on the commission, and the winner supplies necessary liquidity for the entire exchange to clear. This guaranteed clearing, coupled with external price discovery from the primary markets for the securities, sidesteps difficult combinatorial optimization problems. This latter method of proving how taking on the remainder would change risk parameters of one’s own portfolio, without revealing the remainder’s contents or its own risk parameters, is a useful protocol of independent interest.

  10. Spectroscopy with trapped highly charged ions

    Energy Technology Data Exchange (ETDEWEB)

    Beiersdorfer, P

    2008-01-23

    We give an overview of atomic spectroscopy performed on electron beam ion traps at various locations throughout the world. Spectroscopy at these facilities contributes to various areas of science and engineering, including but not limited to basic atomic physics, astrophysics, extreme ultraviolet lithography, and the development of density and temperature diagnostics of fusion plasmas. These contributions are accomplished by generating, for example, spectral surveys, making precise radiative lifetime measurements, accounting for radiative power emitted in a given wavelength band, illucidating isotopic effects, and testing collisional-radiative models. While spectroscopy with electron beam ion traps had originally focused on the x-ray emission from highly charged ions interacting with the electron beam, the operating modes of such devices have expanded to study radiation in almost all wavelength bands from the visible to the hard x-ray region; and at several facilities the ions can be studied even in the absence of an electron beam. Photon emission after charge exchange or laser excitation has been observed, and the work is no longer restricted to highly charged ions. Much of the experimental capabilities are unique to electron beam ion traps, and the work performed with these devices cannot be undertaken elsewhere. However, in other areas the work on electron beam ion traps rivals the spectroscopy performed with conventional ion traps or heavy-ion storage rings. The examples we present highlight many of the capabilities of the existing electron beam ion traps and their contributions to physics.

  11. Exchanging Description Logic Knowledge Bases

    NARCIS (Netherlands)

    Arenas, M.; Botoeva, E.; Calvanese, D.; Ryzhikov, V.; Sherkhonov, E.

    2012-01-01

    In this paper, we study the problem of exchanging knowledge between a source and a target knowledge base (KB), connected through mappings. Differently from the traditional database exchange setting, which considers only the exchange of data, we are interested in exchanging implicit knowledge. As

  12. Measurement of Neutrino Induced, Charged Current, Charged Pion Production

    Energy Technology Data Exchange (ETDEWEB)

    Wilking, Michael Joseph [Univ. of Colorado, Boulder, CO (United States)

    2009-05-01

    Neutrinos are among the least understood particles in the standard model of particle physics. At neutrino energies in the 1 GeV range, neutrino properties are typically determined by observing the outgoing charged lepton produced in a charged current quasi-elastic interactions. The largest charged current background to these measurements comes from charged current pion production interactions, for which there is very little available data.

  13. Using ion exchange chromatography to purify a recombinantly expressed protein.

    Science.gov (United States)

    Duong-Ly, Krisna C; Gabelli, Sandra B

    2014-01-01

    Ion exchange chromatography (IEX) separates molecules by their surface charge, a property that can vary vastly between different proteins. There are two types of IEX, cation exhange and anion exchange chromatography. The protocol that follows was designed by the authors for anion exchange chromatography of a recombinantly expressed protein having a pI of 4.9 and containing two cysteine residues and one tryptophan residue, using an FPLC system. Prior to anion exchange, the protein had been salted out using ammonium sulfate precipitation and partially purified via hydrophobic interaction chromatography (see Salting out of proteins using ammonium sulfate precipitation and Use and Application of Hydrophobic Interaction Chromatography for Protein Purification). Slight modifications to this protocol may be made to accommodate both the protein of interest and the availability of equipment. © 2014 Elsevier Inc. All rights reserved.

  14. Negative Spin Exchange in a Multielectron Quantum Dot

    Science.gov (United States)

    Martins, Frederico; Malinowski, Filip K.; Nissen, Peter D.; Fallahi, Saeed; Gardner, Geoffrey C.; Manfra, Michael J.; Marcus, Charles M.; Kuemmeth, Ferdinand

    2017-12-01

    We use a one-electron quantum dot as a spectroscopic probe to study the spin properties of a gate-controlled multielectron GaAs quantum dot at the transition between odd and even occupation numbers. We observe that the multielectron ground-state transitions from spin-1 /2 -like to singletlike to tripletlike as we increase the detuning towards the next higher charge state. The sign reversal in the inferred exchange energy persists at zero magnetic field, and the exchange strength is tunable by gate voltages and in-plane magnetic fields. Complementing spin leakage spectroscopy data, the inspection of coherent multielectron spin exchange oscillations provides further evidence for the sign reversal and, inferentially, for the importance of nontrivial multielectron spin exchange correlations.

  15. High Voltage Charge Pump

    KAUST Repository

    Emira, Ahmed A.

    2014-10-09

    Various embodiments of a high voltage charge pump are described. One embodiment is a charge pump circuit that comprises a plurality of switching stages each including a clock input, a clock input inverse, a clock output, and a clock output inverse. The circuit further comprises a plurality of pumping capacitors, wherein one or more pumping capacitors are coupled to a corresponding switching stage. The circuit also comprises a maximum selection circuit coupled to a last switching stage among the plurality of switching stages, the maximum selection circuit configured to filter noise on the output clock and the output clock inverse of the last switching stage, the maximum selection circuit further configured to generate a DC output voltage based on the output clock and the output clock inverse of the last switching stage.

  16. Charge independence, charge symmetry breaking in the S-wave nucleon-nucleon interaction, and renormalization

    Energy Technology Data Exchange (ETDEWEB)

    Alvaro Calle Cordon,Manuel Pavon Valderrama,Enrique Ruiz Arriola

    2012-02-01

    We study the interplay between charge symmetry breaking and renormalization in the NN system for S-waves. We find a set of universality relations which disentangle explicitly the known long distance dynamics from low energy parameters and extend them to the Coulomb case. We analyze within such an approach the One-Boson-Exchange potential and the theoretical conditions which allow to relate the proton-neutron, proton-proton and neutron-neutron scattering observables without the introduction of extra new parameters and providing good phenomenological success.

  17. Extension of a Kinetic-Theory Approach for Computing Chemical-Reaction Rates to Reactions with Charged Particles

    Science.gov (United States)

    Liechty, Derek S.; Lewis, Mark J.

    2010-01-01

    Recently introduced molecular-level chemistry models that predict equilibrium and nonequilibrium reaction rates using only kinetic theory and fundamental molecular properties (i.e., no macroscopic reaction rate information) are extended to include reactions involving charged particles and electronic energy levels. The proposed extensions include ionization reactions, exothermic associative ionization reactions, endothermic and exothermic charge exchange reactions, and other exchange reactions involving ionized species. The extensions are shown to agree favorably with the measured Arrhenius rates for near-equilibrium conditions.

  18. Decentralized Electric Vehicle Charging Strategies for Reduced Load Variation and Guaranteed Charge Completion in Regional Distribution Grids

    Directory of Open Access Journals (Sweden)

    Weige Zhang

    2017-01-01

    Full Text Available A novel, fully decentralized strategy to coordinate charge operation of electric vehicles is proposed in this paper. Based on stochastic switching control of on-board chargers, this strategy ensures high-efficiency charging, reduces load variations to the grid during charging periods, achieves charge completion with high probability, and accomplishes approximate “valley-filling”. Further improvements on the core strategy, including individualized power management, adaptive strategies, and battery support systems, are introduced to further reduce power fluctuation variances and to guarantee charge completion. Stochastic analysis is performed to establish the main properties of the strategies and to quantitatively show the performance improvements. Compared with the existing decentralized charging strategies, the strategies proposed in this paper can be implemented without any information exchange between grid operators and electric vehicles (EVs, resulting in a communications cost reduction. Additionally, it is shown that by using stochastic charging rules, a grid-supporting battery system with a very small energy capacity can achieve substantial reduction of EV load fluctuations with high confidence. An extensive set of simulations and case studies with real-world data are used to demonstrate the benefits of the proposed strategies.

  19. Triboelectric, Corona, and Induction Charging of Insulators as a Function of Pressure

    Science.gov (United States)

    Hogue, Michael D.; Mucciolo, Eduardo R.; Calle, Carlos I.

    2006-01-01

    Theoretical and experimental research has been performed that shows that the surface charge on an insulator after triboelectric charging with another insulator is rapidly dissipated with lowered atmospheric pressure. This pressure discharge is consistent with surface ions being evaporated off the surface once their vapor pressure is attained. In this paper we will report on the results of three different charging techniques (triboelectric, corona, and induction) performed on selected polymers with varying atmospheric pressure. This data will show that ion exchange between the polymer samples is the mechanism responsible for most of the surface charge on the polymer surfaces.

  20. Microgravity condensing heat exchanger

    Science.gov (United States)

    Thomas, Christopher M. (Inventor); Ma, Yonghui (Inventor); North, Andrew (Inventor); Weislogel, Mark M. (Inventor)

    2011-01-01

    A heat exchanger having a plurality of heat exchanging aluminum fins with hydrophilic condensing surfaces which are stacked and clamped between two cold plates. The cold plates are aligned radially along a plane extending through the axis of a cylindrical duct and hold the stacked and clamped portions of the heat exchanging fins along the axis of the cylindrical duct. The fins extend outwardly from the clamped portions along approximately radial planes. The spacing between fins is symmetric about the cold plates, and are somewhat more closely spaced as the angle they make with the cold plates approaches 90.degree.. Passageways extend through the fins between vertex spaces which provide capillary storage and communicate with passageways formed in the stacked and clamped portions of the fins, which communicate with water drains connected to a pump externally to the duct. Water with no entrained air is drawn from the capillary spaces.

  1. Partially massless monopoles and charges

    Science.gov (United States)

    Hinterbichler, Kurt; Rosen, Rachel A.

    2015-11-01

    Massive higher spin fields on de Sitter space exhibit enhanced gauge symmetries at special values of the mass. These fields are known as "partially massless." We study the structure of the charges and Gauss laws which characterize sources for the partially massless spin-2. Despite having a simple scalar gauge symmetry, there is a rich structure of gauge charges. The charges come in electric and magnetic varieties, each taking values in the fundamental representation of the de Sitter group. We find two invariant electriclike charges and two invariant magneticlike charges and we find the pointlike monopole solutions which carry these charges, analogous to the electric point-charge solution and Dirac monopole solution of Maxwell electrodynamics. These solutions are related by partially massless duality, analogous to the electromagnetic duality that relates electric to magnetic charges.

  2. Submerged AUV Charging Station

    Science.gov (United States)

    Jones, Jack A.; Chao, Yi; Curtin, Thomas

    2014-01-01

    Autonomous Underwater Vehicles (AUVs) are becoming increasingly important for military surveillance and mine detection. Most AUVs are battery powered and have limited lifetimes of a few days to a few weeks. This greatly limits the distance that AUVs can travel underwater. Using a series of submerged AUV charging stations, AUVs could travel a limited distance to the next charging station, recharge its batteries, and continue to the next charging station, thus traveling great distances in a relatively short time, similar to the Old West “Pony Express.” One solution is to use temperature differences at various depths in the ocean to produce electricity, which is then stored in a submerged battery. It is preferred to have the upper buoy submerged a reasonable distance below the surface, so as not to be seen from above and not to be inadvertently destroyed by storms or ocean going vessels. In a previous invention, a phase change material (PCM) is melted (expanded) at warm temperatures, for example, 15 °C, and frozen (contracted) at cooler temperatures, for example, 8 °C. Tubes containing the PCM, which could be paraffin such as pentadecane, would be inserted into a container filled with hydraulic oil. When the PCM is melted (expanded), it pushes the oil out into a container that is pressurized to about 3,000 psi (approx equals 20.7 MPa). When a valve is opened, the high-pressure oil passes through a hydraulic motor, which turns a generator and charges a battery. The low-pressure oil is finally reabsorbed into the PCM canister when the PCM tubes are frozen (contracted). Some of the electricity produced could be used to control an external bladder or a motor to the tether line, such that depth cycling is continued for a very long period of time. Alternatively, after the electricity is generated by the hydraulic motor, the exiting low-pressure oil from the hydraulic motor could be vented directly to an external bladder on the AUV, such that filling of the bladder

  3. Heat exchanger panel

    Science.gov (United States)

    Warburton, Robert E. (Inventor); Cuva, William J. (Inventor)

    2005-01-01

    The present invention relates to a heat exchanger panel which has broad utility in high temperature environments. The heat exchanger panel has a first panel, a second panel, and at least one fluid containment device positioned intermediate the first and second panels. At least one of the first panel and the second panel have at least one feature on an interior surface to accommodate the at least one fluid containment device. In a preferred embodiment, each of the first and second panels is formed from a high conductivity, high temperature composite material. Also, in a preferred embodiment, the first and second panels are joined together by one or more composite fasteners.

  4. Microscale Regenerative Heat Exchanger

    Science.gov (United States)

    Moran, Matthew E.; Stelter, Stephan; Stelter, Manfred

    2006-01-01

    The device described herein is designed primarily for use as a regenerative heat exchanger in a miniature Stirling engine or Stirling-cycle heat pump. A regenerative heat exchanger (sometimes called, simply, a "regenerator" in the Stirling-engine art) is basically a thermal capacitor: Its role in the Stirling cycle is to alternately accept heat from, then deliver heat to, an oscillating flow of a working fluid between compression and expansion volumes, without introducing an excessive pressure drop. These volumes are at different temperatures, and conduction of heat between these volumes is undesirable because it reduces the energy-conversion efficiency of the Stirling cycle.

  5. Magnetic Forces on Moving Charges

    OpenAIRE

    2003-01-01

    sim drag Simulation Drag-and-Drop Exercise Interactive Media Element This interactive tutorial provides the practice to reinforce the concept of magnetic force of moving charges. The key concepts covered include: The direction of the resultant magnetic force is always perpendicular to the plane defined by the velocity vector of the charge and the magnetic field vector., The direction of motion of the charge is also influenced by the sign/polarity of the charge., If the velocity...

  6. Modular Battery Charge Controller

    Science.gov (United States)

    Button, Robert; Gonzalez, Marcelo

    2009-01-01

    A new approach to masterless, distributed, digital-charge control for batteries requiring charge control has been developed and implemented. This approach is required in battery chemistries that need cell-level charge control for safety and is characterized by the use of one controller per cell, resulting in redundant sensors for critical components, such as voltage, temperature, and current. The charge controllers in a given battery interact in a masterless fashion for the purpose of cell balancing, charge control, and state-of-charge estimation. This makes the battery system invariably fault-tolerant. The solution to the single-fault failure, due to the use of a single charge controller (CC), was solved by implementing one CC per cell and linking them via an isolated communication bus [e.g., controller area network (CAN)] in a masterless fashion so that the failure of one or more CCs will not impact the remaining functional CCs. Each micro-controller-based CC digitizes the cell voltage (V(sub cell)), two cell temperatures, and the voltage across the switch (V); the latter variable is used in conjunction with V(sub cell) to estimate the bypass current for a given bypass resistor. Furthermore, CC1 digitizes the battery current (I1) and battery voltage (V(sub batt) and CC5 digitizes a second battery current (I2). As a result, redundant readings are taken for temperature, battery current, and battery voltage through the summation of the individual cell voltages given that each CC knows the voltage of the other cells. For the purpose of cell balancing, each CC periodically and independently transmits its cell voltage and stores the received cell voltage of the other cells in an array. The position in the array depends on the identifier (ID) of the transmitting CC. After eight cell voltage receptions, the array is checked to see if one or more cells did not transmit. If one or more transmissions are missing, the missing cell(s) is (are) eliminated from cell

  7. Interplay of chemical microenvironment and redox environment on thiol-disulfide exchange kinetics.

    Science.gov (United States)

    Wu, Chuanliu; Belenda, Cristina; Leroux, Jean-Christophe; Gauthier, Marc A

    2011-08-29

    The interplay between the chemical microenvironment surrounding disulfides and the redox environment of the media on thiol-disulfide exchange kinetics was examined by using a peptide platform. Exchange kinetics of up to 34 cysteine-containing peptides were measured in several redox buffers. The electrostatic attraction/repulsion between charged peptides and reducing agents such as glutathione was found to have a very pronounced effect on thiol-disulfide exchange kinetics (differences of ca. three orders of magnitude). Exchange kinetics could be directly correlated to peptide charge over the entire range examined. This study highlights the possibility of finely and predictably tuning thiol-disulfide exchange, and demonstrates the importance of considering both the local environment surrounding the disulfide and the nature of the major reducing species present in the environment for which their use is intended (e.g., in drug delivery systems, sensors, etc). Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  8. 77 FR 39292 - Self-Regulatory Organizations; New York Stock Exchange LLC; Notice of Filing of Proposed Rule...

    Science.gov (United States)

    2012-07-02

    ... Services) provides for ``External Telco/Inter-Cabinet Connectivity'' and includes charges corresponding... ``Telco Connectivity Expedite Fee.'' See Securities Exchange Act Release No. 62397 (June 28, 2010), 75 FR...

  9. Secure Plug-in Electric Vehicle PEV Charging in a Smart Grid Network

    Directory of Open Access Journals (Sweden)

    Khaled Shuaib

    2017-07-01

    Full Text Available Charging of plug-in electric vehicles (PEVs exposes smart grid systems and their users to different kinds of security and privacy attacks. Hence, a secure charging protocol is required for PEV charging. Existing PEV charging protocols are usually based on insufficiently represented and simplified charging models that do not consider the user’s charging modes (charging at a private location, charging as a guest user, roaming within one’s own supplier network or roaming within other suppliers’ networks. However, the requirement for charging protocols depends greatly on the user’s charging mode. Consequently, available solutions do not provide complete protocol specifications. Moreover, existing protocols do not support anonymous user authentication and payment simultaneously. In this paper, we propose a comprehensive end-to-end charging protocol that addresses the security and privacy issues in PEV charging. The proposed protocol uses nested signatures to protect users’ privacy from external suppliers, their own suppliers and third parties. Our approach supports anonymous user authentication, anonymous payment, as well as anonymous message exchange between suppliers within a hierarchical smart grid architecture. We have verified our protocol using the AVISPA software verification tool and the results showed that our protocol is secure and works as desired.

  10. Charge orders in organic charge-transfer salts

    Science.gov (United States)

    Kaneko, Ryui; Tocchio, Luca F.; Valentí, Roser; Becca, Federico

    2017-10-01

    Motivated by recent experimental suggestions of charge-order-driven ferroelectricity in organic charge-transfer salts, such as κ-(BEDT-TTF)2Cu[N(CN)2]Cl, we investigate magnetic and charge-ordered phases that emerge in an extended two-orbital Hubbard model on the anisotropic triangular lattice at 3/4 filling. This model takes into account the presence of two organic BEDT-TTF molecules, which form a dimer on each site of the lattice, and includes short-range intramolecular and intermolecular interactions and hoppings. By using variational wave functions and quantum Monte Carlo techniques, we find two polar states with charge disproportionation inside the dimer, hinting to ferroelectricity. These charge-ordered insulating phases are stabilized in the strongly correlated limit and their actual charge pattern is determined by the relative strength of intradimer to interdimer couplings. Our results suggest that ferroelectricity is not driven by magnetism, since these polar phases can be stabilized also without antiferromagnetic order and provide a possible microscopic explanation of the experimental observations. In addition, a conventional dimer-Mott state (with uniform density and antiferromagnetic order) and a nonpolar charge-ordered state (with charge-rich and charge-poor dimers forming a checkerboard pattern) can be stabilized in the strong-coupling regime. Finally, when electron–electron interactions are weak, metallic states appear, with either uniform charge distribution or a peculiar 12-site periodicity that generates honeycomb-like charge order.

  11. Long-Term Percutaneous Nephrostomy Management of Malignant Urinary Obstruction: Estimation of Optimal Exchange Frequency and Estimation of the Financial Impact of Patient Compliance.

    Science.gov (United States)

    McDevitt, Joseph L; Acosta-Torres, Stefany; Zhang, Ning; Hu, Tianshen; Odu, Ayobami; Wang, Jijia; Xi, Yin; Lamus, Daniel; Miller, David S; Pillai, Anil K

    2017-07-01

    To estimate the least costly routine exchange frequency for percutaneous nephrostomies (PCNs) placed for malignant urinary obstruction, as measured by annual hospital charges, and to estimate the financial impact of patient compliance. Patients with PCNs placed for malignant urinary obstruction were studied from 2011 to 2013. Exchanges were classified as routine or due to 1 of 3 complication types: mechanical (tube dislodgment), obstruction, or infection. Representative cases were identified, and median representative charges were used as inputs for the model. Accelerated failure time and Markov chain Monte Carlo models were used to estimate distribution of exchange types and annual hospital charges under different routine exchange frequency and compliance scenarios. Long-term PCN management was required in 57 patients, with 87 total exchange encounters. Median representative hospital charges for pyelonephritis and obstruction were 11.8 and 9.3 times greater, respectively, than a routine exchange. The projected proportion of routine exchanges increased and the projected proportion of infection-related exchanges decreased when moving from a 90-day exchange with 50% compliance to a 60-day exchange with 75% compliance, and this was associated with a projected reduction in annual charges. Projected cost reductions resulting from increased compliance were generally greater than reductions resulting from changes in exchange frequency. This simulation model suggests that the optimal routine exchange interval for PCN exchange in patients with malignant urinary obstruction is approximately 60 days and that the degree of reduction in charges likely depends more on patient compliance than exact exchange interval. Copyright © 2017 SIR. Published by Elsevier Inc. All rights reserved.

  12. Nature's Heat Exchangers.

    Science.gov (United States)

    Barnes, George

    1991-01-01

    Discusses the heat-transfer systems of different animals. Systems include heat conduction into the ground, heat transferred by convection, heat exchange in lizards, fish and polar animals, the carotid rete system, electromagnetic radiation from animals and people, and plant and animal fiber optics. (MDH)

  13. Basic Exchange Rate Theories

    NARCIS (Netherlands)

    J.G.M. van Marrewijk (Charles)

    2005-01-01

    textabstractThis four-chapter overview of basic exchange rate theories discusses (i) the elasticity and absorption approach, (ii) the (long-run) implications of the monetary approach, (iii) the short-run effects of monetary and fiscal policy under various economic conditions, and (iv) the transition

  14. Technology Performance Exchange

    Energy Technology Data Exchange (ETDEWEB)

    2015-09-01

    To address the need for accessible, high-quality data, the Department of Energy has developed the Technology Performance Exchange (TPEx). TPEx enables technology suppliers, third-party testing laboratories, and other entities to share product performance data. These data are automatically transformed into a format that technology evaluators can easily use in their energy modeling assessments to inform procurement decisions.

  15. Telephone Exchange Maintenance

    CERN Document Server

    2005-01-01

    Urgent maintenance work on CERN telephone exchanges will be performed on 24 March from 6 a.m. to 8 a.m. Telephone services may be disrupted or even interrupted during this time. For more details, please contact us by email at Standard.Telephone@cern.ch.

  16. Baltic Exchange toodi Tallinna

    Index Scriptorium Estoniae

    2007-01-01

    Viimane osa merekonteineritesse kokkupakitud Londoni laevandus- ja merebörsi Baltic Exchange'i endise peakorteri detailidest jõudis 2007. a. juunis Tallinna. Hoone detailid ostnud ärimehed Heiti Hääl ja Eerik-Niiles Kross plaanivad leida hoonele koha Tallinna kesklinnas. E.-N. Krossi kommentaar

  17. Heat exchanger. Varmeveksler

    Energy Technology Data Exchange (ETDEWEB)

    Rosman, I.E.; Wagner, W.R.

    1986-03-17

    The invention concerns a manifold for a plate-type heat exchanger, and includes a side channel connected the inlet of the manifold. The plates can be designed as an integral assembly together with the integrated side- and external end-manifolds as well. 16 drawings.

  18. Chemical exchange program analysis.

    Energy Technology Data Exchange (ETDEWEB)

    Waffelaert, Pascale

    2007-09-01

    As part of its EMS, Sandia performs an annual environmental aspects/impacts analysis. The purpose of this analysis is to identify the environmental aspects associated with Sandia's activities, products, and services and the potential environmental impacts associated with those aspects. Division and environmental programs established objectives and targets based on the environmental aspects associated with their operations. In 2007 the most significant aspect identified was Hazardous Materials (Use and Storage). The objective for Hazardous Materials (Use and Storage) was to improve chemical handling, storage, and on-site movement of hazardous materials. One of the targets supporting this objective was to develop an effective chemical exchange program, making a business case for it in FY07, and fully implementing a comprehensive chemical exchange program in FY08. A Chemical Exchange Program (CEP) team was formed to implement this target. The team consists of representatives from the Chemical Information System (CIS), Pollution Prevention (P2), the HWMF, Procurement and the Environmental Management System (EMS). The CEP Team performed benchmarking and conducted a life-cycle analysis of the current management of chemicals at SNL/NM and compared it to Chemical Exchange alternatives. Those alternatives are as follows: (1) Revive the 'Virtual' Chemical Exchange Program; (2) Re-implement a 'Physical' Chemical Exchange Program using a Chemical Information System; and (3) Transition to a Chemical Management Services System. The analysis and benchmarking study shows that the present management of chemicals at SNL/NM is significantly disjointed and a life-cycle or 'Cradle-to-Grave' approach to chemical management is needed. This approach must consider the purchasing and maintenance costs as well as the cost of ultimate disposal of the chemicals and materials. A chemical exchange is needed as a mechanism to re-apply chemicals on site. This

  19. Charge, from EM fields only

    OpenAIRE

    Collins, R. L.

    2006-01-01

    Consider the electric field E about an electron. Its source has been thought a substance called charge, enclosed within a small volume that defines the size of the electron. Scattering experiments find no size at all. Charge is useful, but mysterious. This study concludes that charge is not real. Useful, but not real. Absent real charge, the electric field must look to a different source. We know another electric field, vxB, not sourced by charge. A simple model of the electron, using EM fiel...

  20. High resolution printing of charge

    Science.gov (United States)

    Rogers, John; Park, Jang-Ung

    2015-06-16

    Provided are methods of printing a pattern of charge on a substrate surface, such as by electrohydrodynamic (e-jet) printing. The methods relate to providing a nozzle containing a printable fluid, providing a substrate having a substrate surface and generating from the nozzle an ejected printable fluid containing net charge. The ejected printable fluid containing net charge is directed to the substrate surface, wherein the net charge does not substantially degrade and the net charge retained on the substrate surface. Also provided are functional devices made by any of the disclosed methods.

  1. Counterflow Regolith Heat Exchanger

    Science.gov (United States)

    Zubrin, Robert; Jonscher, Peter

    2013-01-01

    A problem exists in reducing the total heating power required to extract oxygen from lunar regolith. All such processes require heating a great deal of soil, and the heat energy is wasted if it cannot be recycled from processed material back into new material. The counterflow regolith heat exchanger (CoRHE) is a device that transfers heat from hot regolith to cold regolith. The CoRHE is essentially a tube-in-tube heat exchanger with internal and external augers attached to the inner rotating tube to move the regolith. Hot regolith in the outer tube is moved in one direction by a right-hand - ed auger, and the cool regolith in the inner tube is moved in the opposite direction by a left-handed auger attached to the inside of the rotating tube. In this counterflow arrangement, a large fraction of the heat from the expended regolith is transferred to the new regolith. The spent regolith leaves the heat exchanger close to the temperature of the cold new regolith, and the new regolith is pre-heated close to the initial temperature of the spent regolith. Using the CoRHE can reduce the heating requirement of a lunar ISRU system by 80%, reducing the total power consumption by a factor of two. The unique feature of this system is that it allows for counterflow heat exchange to occur between solids, instead of liquids or gases, as is commonly done. In addition, in variants of this concept, the hydrogen reduction can be made to occur within the counterflow heat exchanger itself, enabling a simplified lunar ISRU (in situ resource utilization) system with excellent energy economy and continuous nonbatch mode operation.

  2. Analytical applications of ion exchangers

    CERN Document Server

    Inczédy, J

    1966-01-01

    Analytical Applications of Ion Exchangers presents the laboratory use of ion-exchange resins. This book discusses the development in the analytical application of ion exchangers. Organized into 10 chapters, this book begins with an overview of the history and significance of ion exchangers for technical purposes. This text then describes the properties of ion exchangers, which are large molecular water-insoluble polyelectrolytes having a cross-linked structure that contains ionic groups. Other chapters consider the theories concerning the operation of ion-exchange resins and investigate th

  3. ANISOTROPY EFFECTS IN SINGLE-ELECTRON TRANSFER BETWEEN LASER-EXCITED ATOMS AND HIGHLY-CHARGED IONS

    NARCIS (Netherlands)

    Recent collision experiments are reviewed in which one-electron transfer between laser excited target atoms and (highly charged) keV-ions has been studied. Especially results showing a dependence of the charge exchange on the initial target orbital alignment are discussed. The question to what

  4. Sorption and binary exchange of nitrate, sulfate, and uranium on an anion-exchange resin.

    Science.gov (United States)

    Gu, Baohua; Ku, Yee-Kyoung; Jardine, Philip M

    2004-06-01

    Competitive ion-exchange reactions were studied on a strong-base anion-exchange resin to remove NO3- and uranium from a contaminated groundwater containing high levels of NO3- (approximately 140 mM), SO4(2-) (approximately 10 mM), and U(VI) (approximately 0.2 mM). Results indicate that although SO4(2-) carries divalent negative charges, it showed the least selectivity for sorption by the Purolite A-520E resin, which is functionalized with triethylamine exchange sites. Nitrate was the most strongly sorbed. Sorption selectivity followed the order of NO3- > Cl- > SO4(2-) under the experimental conditions. Nitrate competitively sorbed and displaced previously sorbed SO4(2-) in a column flow-through experiment and resulted in a high elution front of SO4(2-) in the effluent. Although the concentration of uranium in groundwater is orders of magnitude lower than that of NO3- or SO4(2-), it was found to be strongly sorbed by the anion-exchange resin. Because the most stable uranium species in oxic and suboxic environments is the UO2(2+) cation, its strong sorption by anion-exchange resins is hypothesized to be the result of the co-ion effect of NO3- by forming anionic UO2(NO3)3- complexes in the resin matrix. These observations point out a potential alternative remediation strategy that uses strong-base anion-exchange resins to remove uranium from this site-specific groundwater, which has a low pH and a relatively high NO3- concentration.

  5. A novel silica based click lysine anion exchanger for ion exchange chromatography.

    Science.gov (United States)

    Guo, Hongyue; Chu, Changhu; Li, Yan; Yang, Bingcheng; Liang, Xinmiao

    2011-12-21

    Ion chromatography (IC) is one of the most powerful analysis technologies for the determination of charged compounds. A novel click lysine stationary phase was prepared via Cu(I) catalyzed alkyne-azide 1,3-dipolar cycloaddition (CuAAC) and applied to the analysis of inorganic ions. The chromatographic evaluation demonstrated good performance (e.g. the plate number of thiocyanate is ∼50,000 plates m(-1)) and effective separation ability for the common inorganic anions with aqueous Na(2)SO(4) eluent. The separation mechanism was observed to be mainly dominated by ion exchange interaction. The retention of these analytes is highly dependent on the pH value of eluent. Compared with the lysine stationary phase prepared via the conventional manner, the click lysine exchanger demonstrated shorter retention time and better ion separation characteristics under the same chromatographic conditions, which is a great advantage for rapid separation and analysis of inorganic ions.

  6. Charging of ice-vapor interfaces: applications to thunderstorms

    Directory of Open Access Journals (Sweden)

    J. Nelson

    2003-01-01

    Full Text Available The build-up of intrinsic Bjerrum and ionic defects at ice-vapor interfaces electrically charges ice surfaces and thus gives rise to many phenomena including thermoelectricity, ferroelectric ice films, sparks from objects in blizzards, electromagnetic emissions accompanying cracking in avalanches, glaciers, and sea ice, and charge transfer during ice-ice collisions in thunderstorms. Fletcher's theory of the ice surface in equilibrium proposed that the Bjerrum defects have a higher rate of creation at the surface than in the bulk, which produces a high concentration of surface D defects that then attract a high concentration of OH- ions at the surface. Here, we add to this theory the effect of a moving interface caused by growth or sublimation. This effect can increase the amount of ionic surface charges more than 10-fold for growth rates near 1 mm s-1 and can extend the spatial separation of interior charges in qualitative agreement with many observations. In addition, ice-ice collisions should generate sufficient pressure to melt ice at the contact region and we argue that the ice particle with the initially sharper point at contact loses more mass of melt than the other particle. A simple analytic model of this process with parameters that are consistent with observations leads to predicted collisional charge exchange that semiquantitatively explains the negative charging region of thunderstorms. The model also has implications for snowflake formation, ferroelectric ice, polarization of ice in snowpacks, and chemical reactions in ice surfaces

  7. Charged Galileon black holes

    Energy Technology Data Exchange (ETDEWEB)

    Babichev, Eugeny; Charmousis, Christos [Laboratoire de Physique Théorique (LPT), Univ. Paris-Sud, CNRS UMR 8627, F-91405 Orsay (France); Hassaine, Mokhtar, E-mail: eugeny.babichev@th.u-psud.fr, E-mail: christos.charmousis@th.u-psud.fr, E-mail: hassaine@inst-mat.utalca.cl [Instituto de Matemática y Física, Universidad de Talca, Casilla 747, Talca (Chile)

    2015-05-01

    We consider an Abelian gauge field coupled to a particular truncation of Horndeski theory. The Galileon field has translation symmetry and couples non minimally both to the metric and the gauge field. When the gauge-scalar coupling is zero the gauge field reduces to a standard Maxwell field. By taking into account the symmetries of the action, we construct charged black hole solutions. Allowing the scalar field to softly break symmetries of spacetime we construct black holes where the scalar field is regular on the black hole event horizon. Some of these solutions can be interpreted as the equivalent of Reissner-Nordstrom black holes of scalar tensor theories with a non trivial scalar field. A self tuning black hole solution found previously is extended to the presence of dyonic charge without affecting whatsoever the self tuning of a large positive cosmological constant. Finally, for a general shift invariant scalar tensor theory we demonstrate that the scalar field Ansatz and method we employ are mathematically compatible with the field equations. This opens up the possibility for novel searches of hairy black holes in a far more general setting of Horndeski theory.

  8. Space charge physics for particle accelerators

    CERN Document Server

    Hofmann, Ingo

    2017-01-01

    Understanding and controlling the physics of space charge effects in linear and circular proton and ion accelerators are essential to their operation, and to future high-intensity facilities. This book presents the status quo of this field from a theoretical perspective, compares analytical approaches with multi-particle computer simulations and – where available – with experiments. It discusses fundamental concepts of phase space motion, matched beams and modes of perturbation, along with mathematical models of analysis – from envelope to Vlasov-Poisson equations. The main emphasis is on providing a systematic description of incoherent and coherent resonance phenomena; parametric instabilities and sum modes; mismatch and halo; error driven resonances; and emittance exchange due to anisotropy, as well as the role of Landau damping. Their distinctive features are elaborated in the context of numerous sample simulations, and their potential impacts on beam quality degradation and beam loss are discussed....

  9. Battery charging control methods, electric vehicle charging methods, battery charging apparatuses and rechargeable battery systems

    Science.gov (United States)

    Tuffner, Francis K [Richland, WA; Kintner-Meyer, Michael C. W. [Richland, WA; Hammerstrom, Donald J [West Richland, WA; Pratt, Richard M [Richland, WA

    2012-05-22

    Battery charging control methods, electric vehicle charging methods, battery charging apparatuses and rechargeable battery systems. According to one aspect, a battery charging control method includes accessing information regarding a presence of at least one of a surplus and a deficiency of electrical energy upon an electrical power distribution system at a plurality of different moments in time, and using the information, controlling an adjustment of an amount of the electrical energy provided from the electrical power distribution system to a rechargeable battery to charge the rechargeable battery.

  10. Radiative charge transfer in collisions of C with He+

    CERN Document Server

    Babb, James F

    2016-01-01

    Radiative charge exchange collisions between a carbon atom C(${}^3$P) and a helium ion He+, both in their ground state, are investigated theoretically. Detailed quantum chemistry calculations are carried out to obtain potential energy curves and transition dipole matrix elements for doublet and quartet molecular states of the HeC+ cation. Radiative charge transfer cross sections and rate coefficients are calculated and are found at thermal and lower energies to be large compared to those for direct charge transfer. The present results might be applicable to modelling the complex interplay of [C II] (or C+), C, and CO at the boundaries of photon dominated regions (PDRs) and in xray dominated regions (XDRs), where the abundance of He+ affects the abundance of CO.

  11. MEASUREMENTS OF A STEEL CHARGE EMISSIVITY UNDER STRONG IRRADIANCE CONDITIONS

    Directory of Open Access Journals (Sweden)

    Agnieszka Benduch

    2014-09-01

    Full Text Available Steel bars are manufactured in the rolling process, whereby they are characterized by strain hardening and poor plastic properties. In many application cases such properties are improper, therefore, additional heat treatment is required. Crucial influence on the products quality after heat treatment has an appropriate selection of process parameters. In many modern technologies of heat treatment the charge of porous structure is subjected to the heating process. Proper control of heat treatment parameters of bundles of rods requires knowledge on their thermal properties. However, it also requires accurate identification of complex heat transfer processes occurring in the porous material. Such analysis, with respect to bundles of bars, provide a response of qualitative nature of the heat exchange area of these charges. The article describes the emissivity measurements of samples of the steel charge using a thermal imaging camera.

  12. Data Exchange Inventory (DEXI) System

    Data.gov (United States)

    Social Security Administration — DEXI is an intranet application used by SSA users to track all incoming and outgoing data exchanges between SSA and our data exchange partners. Information such as...

  13. Charge Breeding of Radioactive Ions

    CERN Document Server

    Wenander, F J C

    2013-01-01

    Charge breeding is a technique to increase the charge state of ions, in many cases radioactive ions. The singly charged radioactive ions, produced in an isotope separator on-line facility, and extracted with a low kinetic energy of some tens of keV, are injected into a charge breeder, where the charge state is increased to Q. The transformed ions are either directed towards a dedicated experiment requiring highly charged ions, or post-accelerated to higher beam energies. In this paper the physics processes involved in the production of highly charged ions will be introduced, and the injection and extraction beam parameters of the charge breeder defined. A description of the three main charge-breeding methods is given, namely: electron stripping in gas jet or foil; external ion injection into an electron-beam ion source/trap (EBIS/T); and external ion injection into an electron cyclotron resonance ion source (ECRIS). In addition, some preparatory devices for charge breeding and practical beam delivery aspects ...

  14. Ion-exchange chromatography purification of extracellular vesicles.

    Science.gov (United States)

    Kosanović, Maja; Milutinović, Bojana; Goč, Sanja; Mitić, Ninoslav; Janković, Miroslava

    2017-08-01

    Despite numerous studies, isolating pure preparations of extracellular vesicles (EVs) has proven challenging. Here, we compared ion-exchange chromatography (IEC) to the widely used sucrose density gradient (SDG) centrifugation method for the purification of EVs. EVs in bulk were isolated from pooled normal human amniotic fluid (AF) by differential centrifugation followed by IEC or sucrose density gradient separation. The purity of the isolated EVs was evaluated by electrophoresis and lectin blotting/immuno blotting to monitor the distribution of total proteins, different EVs markers, and selected N-glycans. Our data showed efficient separation of negatively charged EVs from other differently charged molecules, while comparative profiling of EVs using SDG centrifugation confirmed anion-exchange chromatography is advantageous for EV purification. Finally, although this IEC-based method was validated using AF, the approach should be readily applicable to isolation of EVs from other sources as well.

  15. Combined effect of salt concentration and pressure gradients across charged membranes

    DEFF Research Database (Denmark)

    Benavente, Juana; Jonsson, Gunnar Eigil

    2002-01-01

    The combined effect of both concentration and pressure differences on electrical potential (Deltaphi) for two ion-exchanger membranes, one positively charged (AE) and another negatively charged (CE), measured with the membranes in contact with NaCl solutions was studied. Results show a linear...... to correlate the behaviour of the BP membrane with that corresponding to each sublayer, the same kind of measurements was carried out for both opposite external conditions, this means, applying the pressure on the cation exchanger (CABM) or on the anion exchanger membrane (ACBM), respectively. From values...... obtained at DeltaP = 0, the counter-ion transport number in each ion-exchange membrane was obtained and the contribution of membrane potential on Deltaphi values can be evaluated. Results show clear differences on both the membrane potential and the effect of pressure in the bipolar membrane depending...

  16. Dynamical Clustering of Exchange Rates

    OpenAIRE

    Fenn, Daniel J.; Porter, Mason A.; Mucha, Peter J; Mark McDonald; Stacy Williams; Johnson, Neil F.; Jones, Nick S

    2009-01-01

    We use techniques from network science to study correlations in the foreign exchange (FX) market over the period 1991--2008. We consider an FX market network in which each node represents an exchange rate and each weighted edge represents a time-dependent correlation between the rates. To provide insights into the clustering of the exchange rate time series, we investigate dynamic communities in the network. We show that there is a relationship between an exchange rate's functional role withi...

  17. Serial tempering without exchange.

    Science.gov (United States)

    Nymeyer, Hugh

    2010-09-21

    Serial tempering is a computational method that turns the temperature T (or more generally any independent λ parameter) into a dynamical variable. It is shown that, under conditions for which this variable is fast, serial tempering is equivalent to the umbrella sampling method with a single effective potential. This equivalence is demonstrated using both a small one-dimensional system and a small solvated peptide. The suggestion is then made to replace the serial tempering protocol with the equivalent umbrella sampling calculation. This approach, serial tempering without exchange (STeWiE), has the same performance as serial tempering in the limit that exchanges are frequent, is simpler to implement, and has fewer adjustable parameters than conventional serial tempering. The equivalence of serial tempering and STeWiE also provides a convenient route for estimating and optimizing the performance of serial tempering simulations and other generalized-ensemble methods.

  18. Lipid exchange by ultracentrifugation

    DEFF Research Database (Denmark)

    Drachmann, Nikolaj Düring; Olesen, Claus

    2014-01-01

    Lipids play an important role in maintaining P-type ATPase structure and function, and often they are crucial for ATPase activity. When the P-type ATPases are in the membrane, they are surrounded by a mix of different lipids species with varying aliphatic chain lengths and saturation......, and the complex interplay between the lipids and the P-type ATPases are still not well understood. We here describe a robust method to exchange the majority of the lipids surrounding the ATPase after solubilisation and/or purification with a target lipid of interest. The method is based on an ultracentrifugation...... step, where the protein sample is spun through a dense buffer containing large excess of the target lipid, which results in an approximately 80-85 % lipid exchange. The method is a very gently technique that maintains protein folding during the process, hence allowing further characterization...

  19. Charge Storage, Conductivity and Charge Profiles of Insulators as Related to Spacecraft Charging

    Science.gov (United States)

    Dennison, J. R.; Swaminathan, Prasanna; Frederickson, A. R.

    2004-01-01

    Dissipation of charges built up near the surface of insulators due to space environment interaction is central to understanding spacecraft charging. Conductivity of insulating materials is key to determine how accumulated charge will distribute across the spacecraft and how rapidly charge imbalance will dissipate. To understand these processes requires knowledge of how charge is deposited within the insulator, the mechanisms for charge trapping and charge transport within the insulator, and how the profile of trapped charge affects the transport and emission of charges from insulators. One must consider generation of mobile electrons and holes, their trapping, thermal de-trapping, mobility and recombination. Conductivity is more appropriately measured for spacecraft charging applications as the "decay" of charge deposited on the surface of an insulator, rather than by flow of current across two electrodes around the sample. We have found that conductivity determined from charge storage decay methods is 102 to 104 smaller than values obtained from classical ASTM and IEC methods for a variety of thin film insulating samples. For typical spacecraft charging conditions, classical conductivity predicts decay times on the order of minutes to hours (less than typical orbit periods); however, the higher charge storage conductivities predict decay times on the order of weeks to months leading to accumulation of charge with subsequent orbits. We found experimental evidence that penetration profiles of radiation and light are exceedingly important, and that internal electric fields due to charge profiles and high-field conduction by trapped electrons must be considered for space applications. We have also studied whether the decay constants depend on incident voltage and flux or on internal charge distributions and electric fields; light-activated discharge of surface charge to distinguish among differing charge trapping centers; and radiation-induced conductivity. Our

  20. 78 FR 21651 - Self-Regulatory Organizations; BATS Y-Exchange, Inc.; Notice of Filing and Immediate...

    Science.gov (United States)

    2013-04-11

    ... liquidity sets the national best bid or offer (the ``NBBO Setter Program''). The Exchange charges Members... ADV used in conjunction with TCV for the NBBO Setter Program and the tiered pricing structures for... the price and volume discovery process. Accordingly, the Exchange believes that the proposal is...

  1. Understanding the Linkage between Charging Network Coverage and Charging Opportunity

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Changzheng [ORNL; Lin, Zhenhong [ORNL; Kontou, Eleftheria [University of Florida, Gainesville; Wu, Xing [Lamar University

    2016-01-01

    Using GPS-based travel survey data, this paper estimates the relationship between public charging network coverage and charging opportunity, defined as the probability of being able to access public charging for a driver at one of his/her stops or at one travel day. Understanding this relationship is of important interests to the electric vehicle industry and government in determining appropriate charging infrastructure deployment level and estimating the impact of public charging on market adoption of electric vehicles. The analysis finds that drivers trip destinations concentrate on a few popular places. If top 1% of most popular places are installed with public chargers, on average, drivers will be able to access public charging at 20% of all their stops and 1/3 of their travel days; If 20% of most popular places are installed with public chargers, drivers will be able to access public charging at 89% of all their stops and 94% of their travel days. These findings are encouraging, implying charging network can be efficiently designed by concentrating at a few popular places while still providing a high level of charging opportunity.

  2. Exchange rate rebounds after foreign exchange market interventions

    Science.gov (United States)

    Hoshikawa, Takeshi

    2017-03-01

    This study examined the rebounds in the exchange rate after foreign exchange intervention. When intervention is strongly effective, the exchange rate rebounds at next day. The effect of intervention is reduced slightly by the rebound after the intervention. The exchange rate might have been 67.12-77.47 yen to a US dollar without yen-selling/dollar-purchasing intervention of 74,691,100 million yen implemented by the Japanese government since 1991, in comparison to the actual exchange rate was 103.19 yen to the US dollar at the end of March 2014.

  3. Performance enhancement study of mobile air conditioning system using microchannel heat exchangers

    Energy Technology Data Exchange (ETDEWEB)

    Qi, Zhaogang; Zhao, Yu.; Chen, Jiangping [Institute of Refrigeration and Cryogenics, Shanghai Jiao Tong University, No. 800, Dongchuan Road, Shanghai 200240 (China)

    2010-03-15

    In the present paper, two retrofitted compact and high efficient microchannel heat exchangers were proposed. The new microchannel heat exchangers have advantages in compactness (17.2% and 15.1% volume reduction for evaporator and condenser, respectively), weight (2.8% and 14.9% lighter for evaporator and condenser, respectively), heat transfer characteristics compared with the currently used heat exchangers in mobile air conditioning (MAC) industry. One enhanced and one baseline R134a MAC systems were established including the new microchannel heat exchangers and the traditional MAC heat exchangers, respectively. The system performances have been experimentally carried out under variable ambient conditions in psychrometric calorimeter test bench. The optimal system refrigerant charge amounts for both systems were tested and the results showed that the enhanced system with more compact heat exchangers could reduce system charge amount and the minimum effective charge amount was less than that of the baseline system. The enhanced system could supply more cooling capacity to car compartment under all test conditions because of higher performance heat exchangers. The coefficient of performance (COP) of the enhanced system was slightly lower than that of the baseline system under idle conditions but higher under all the other test conditions. Cooling capacity and COP of the enhanced system was increased by about 5% and 8% under high vehicle speed condition. (author)

  4. O3 and NOx Exchange

    NARCIS (Netherlands)

    Loubet, B.; Castell, J.F.; Laville, P.; Personne, E.; Tuzet, A.; Ammann, C.; Emberson, L.; Ganzeveld, L.; Kowalski, A.S.; Merbold, L.; Stella, P.; Tuovinen, J.P.

    2015-01-01

    This discussion was based on the background document “Review on modelling atmosphere-biosphere exchange of Ozone and Nitrogen oxides”, which reviews the processes contributing to biosphere-atmosphere exchange of O3 and NOx, including stomatal and non-stomatal exchange of O3 and NO, NO2.

  5. The stability of exchange networks

    NARCIS (Netherlands)

    Doğan, G.; Assen, M. van; Rijt, A. van de; Buskens, V.W.

    2009-01-01

    Economic and sociological exchange theories predict divisions of exchange benefits given an assumed fixed network of exchange relations. Since network structure has been found to have a large impact on actors’ payoffs, actors have strong incentives for network change.Weanswer the question what

  6. Integrated foreign exchange risk management

    DEFF Research Database (Denmark)

    Aabo, Tom; Høg, Esben; Kuhn, Jochen

    2010-01-01

    Empirical research has focused on export as a proxy for exchange rate exposure and the use of foreign exchange derivatives as an instrument to deal with this exposure. This empirical study applies an integrated foreign exchange risk management approach with a particular focus on the role of impor...

  7. Integrated Foreign Exchange Risk Management

    DEFF Research Database (Denmark)

    Aabo, Tom; Høg, Esben; Kuhn, Jochen

    Empirical research has focused on export as a proxy for the exchange rate exposure and the use of foreign exchange derivatives as the instrument to deal with this exposure. This empirical study applies an integrated foreign exchange risk management approach with a particular focus on the role...

  8. Scraped surface heat exchangers.

    Science.gov (United States)

    Rao, Chetan S; Hartel, Richard W

    2006-01-01

    Scraped surface heat exchangers (SSHEs) are commonly used in the food, chemical, and pharmaceutical industries for heat transfer, crystallization, and other continuous processes. They are ideally suited for products that are viscous, sticky, that contain particulate matter, or that need some degree of crystallization. Since these characteristics describe a vast majority of processed foods, SSHEs are especially suited for pumpable food products. During operation, the product is brought in contact with a heat transfer surface that is rapidly and continuously scraped, thereby exposing the surface to the passage of untreated product. In addition to maintaining high and uniform heat exchange, the scraper blades also provide simultaneous mixing and agitation. Heat exchange for sticky and viscous foods such as heavy salad dressings, margarine, chocolate, peanut butter, fondant, ice cream, and shortenings is possible only by using SSHEs. High heat transfer coefficients are achieved because the boundary layer is continuously replaced by fresh material. Moreover, the product is in contact with the heating surface for only a few seconds and high temperature gradients can be used without the danger of causing undesirable reactions. SSHEs are versatile in the use of heat transfer medium and the various unit operations that can be carried out simultaneously. This article critically reviews the current understanding of the operations and applications of SSHEs.

  9. Timing Foreign Exchange Markets

    Directory of Open Access Journals (Sweden)

    Samuel W. Malone

    2016-03-01

    Full Text Available To improve short-horizon exchange rate forecasts, we employ foreign exchange market risk factors as fundamentals, and Bayesian treed Gaussian process (BTGP models to handle non-linear, time-varying relationships between these fundamentals and exchange rates. Forecasts from the BTGP model conditional on the carry and dollar factors dominate random walk forecasts on accuracy and economic criteria in the Meese-Rogoff setting. Superior market timing ability for large moves, more than directional accuracy, drives the BTGP’s success. We explain how, through a model averaging Monte Carlo scheme, the BTGP is able to simultaneously exploit smoothness and rough breaks in between-variable dynamics. Either feature in isolation is unable to consistently outperform benchmarks throughout the full span of time in our forecasting exercises. Trading strategies based on ex ante BTGP forecasts deliver the highest out-of-sample risk-adjusted returns for the median currency, as well as for both predictable, traded risk factors.

  10. Paste heat exchange

    Energy Technology Data Exchange (ETDEWEB)

    1943-07-30

    The subject of coal paste heat exchangers is discussed in this letter report from Gelsenberg A.G. to I.G. Farbenindustrie A.G. Gelsenberg had given little consideration to the heating of coal paste by means of regeneration (heat exchange) because of the lack of experience in paste regeneration with bituminous coal, especially at 700 atmospheres. At the I.G. Farben plant at Poelitz, paste regeneration was carried out so that low concentration coal paste was heated in the regenerator together with the process gas, and the remaining coal was fed into the cold pass of the preheater in a thicker paste. Later tests proved this process viable. Gelsenberg heated normal coal paste and the gas in heat exchangers with the goal of relieving the preheater. Good results were achieved without change in design. The coal paste was heated with process gas in the regenerator at up to 315 degrees with constant pressure difference, so that after three months no decrease in K-values and no deposition or thickening was observed. Through the omission of paste gas, the pressure difference of the system became more constant and did not rise above the former level. The temperature also was more controllable, the chamber smoother running. Principal thermal data are given in a table. 1 table, 1 graph.

  11. The exchangeability of shape

    Directory of Open Access Journals (Sweden)

    Kaba Dramane

    2010-10-01

    Full Text Available Abstract Background Landmark based geometric morphometrics (GM allows the quantitative comparison of organismal shapes. When applied to systematics, it is able to score shape changes which often are undetectable by traditional morphological studies and even by classical morphometric approaches. It has thus become a fast and low cost candidate to identify cryptic species. Due to inherent mathematical properties, shape variables derived from one set of coordinates cannot be compared with shape variables derived from another set. Raw coordinates which produce these shape variables could be used for data exchange, however they contain measurement error. The latter may represent a significant obstacle when the objective is to distinguish very similar species. Results We show here that a single user derived dataset produces much less classification error than a multiple one. The question then becomes how to circumvent the lack of exchangeability of shape variables while preserving a single user dataset. A solution to this question could lead to the creation of a relatively fast and inexpensive systematic tool adapted for the recognition of cryptic species. Conclusions To preserve both exchangeability of shape and a single user derived dataset, our suggestion is to create a free access bank of reference images from which one can produce raw coordinates and use them for comparison with external specimens. Thus, we propose an alternative geometric descriptive system that separates 2-D data gathering and analyzes.

  12. Battery charging stations

    Energy Technology Data Exchange (ETDEWEB)

    Bergey, M.

    1997-12-01

    This paper discusses the concept of battery charging stations (BCSs), designed to service rural owners of battery power sources. Many such power sources now are transported to urban areas for recharging. A BCS provides the opportunity to locate these facilities closer to the user, is often powered by renewable sources, or hybrid systems, takes advantage of economies of scale, and has the potential to provide lower cost of service, better service, and better cost recovery than other rural electrification programs. Typical systems discussed can service 200 to 1200 people, and consist of stations powered by photovoltaics, wind/PV, wind/diesel, or diesel only. Examples of installed systems are presented, followed by cost figures, economic analysis, and typical system design and performance numbers.

  13. Ion exchange chromatography – basic principles and application

    OpenAIRE

    Cummins, Phil; Dowling, Oonagh; O'Connor, Brendan

    2011-01-01

    Ion-Exchange Chromatography (IEC) allows for the separation of ionizable molecules on the basis of differences in charge properties. Its large sample-handling capacity, broad applicability (particularly to proteins and enzymes), moderate cost, powerful resolving ability, and ease of scale-up and automation have led to it becoming one of the most versatile and widely used of all liquid chromatography (LC) techniques. In this chapter, we review the basic principles of IEC, as well as the broade...

  14. 12 CFR 226.4 - Finance charge.

    Science.gov (United States)

    2010-01-01

    ... 12 Banks and Banking 3 2010-01-01 2010-01-01 false Finance charge. 226.4 Section 226.4 Banks and... LENDING (REGULATION Z) General § 226.4 Finance charge. (a) Definition. The finance charge is the cost of...) Charges by third parties. The finance charge includes fees and amounts charged by someone other than the...

  15. Electronic Strengthening of Graphene by Charge Doping

    Science.gov (United States)

    Si, Chen; Liu, Zheng; Duan, Wenhui; Liu, Feng

    2013-03-01

    Graphene is known as the strongest 2D material in nature, yet we show that moderate charge doping of either electrons or holes can further enhance its ideal strength by up to ~17%, based on first principles calculations. This unusual electronic enhancement, versus conventional structural enhancement, of material's strength is achieved by an intriguing physical mechanism of charge doping counteracting on strain induced enhancement of Kohn anomaly, which leads to an overall stiffening of zone boundary K1 phonon mode whose softening under strain is responsible for graphene failure. Electrons and holes work in the same way due to the high electron-hole symmetry around the Dirac point of graphene, while over doping may weaken the graphene by softening other phonon modes. Our findings uncover another fascinating property of graphene with broad implications in graphene-based electromechanical devices. The work is support by DOE-BES program. C.S. thanks Tsinghua exchange student fund for supporting her visit at U. of Utah. W. D. thanks support by the Ministry of Science and Technology of China

  16. The surface charge of trypanosomatids

    Directory of Open Access Journals (Sweden)

    SOUTO-PADRÓN THAÏS

    2002-01-01

    Full Text Available The surface charge of trypanosomatids was evaluated by means of the binding of cationic particles, as visualized by electron microscopy and by direct measurements of the electrophoretic mobility of cells. The results obtained indicate that most of the trypanosomatids exhibit a negatively charged surface whose value is species specific and varies according to the developmental stages. Sialic acids associated with glycoproteins, glycolipids and phosphate groups are the major components responsible for the net negative surface charge of the trypanosomatids.

  17. An Electric Bus with a Battery Exchange System

    Directory of Open Access Journals (Sweden)

    Jeongyong Kim

    2015-07-01

    Full Text Available As part of the ongoing effort to be independent of petroleum resources and to be free from pollutant emission issues, various electric vehicles have been developed and tested through their integration with real world systems. In the current paper, yet another application specific EV for public transportation, an electric bus, is introduced and explained with results from the pilot test program which was carried out under real traffic conditions. The main feature of the current system is a battery exchanging mechanism mounted on the roof of the bus. The current configuration certainly requires an externally fabricated battery exchanging robot system that would complement the electric bus for a fully automated battery exchanging process. The major advantage of the current system is the quick re-charging of the electric energy through the physical battery exchange and the possible utilization of the battery exchange station as a mini scale energy storage system for grid system peak power shaving. With the total system solution approach for the public transportation system, it is fully expected to create outstanding business opportunities in number of areas such as battery suppliers, battery exchanging station management, battery leasing and many more.

  18. Manipulating adenoviral vector ion-exchange chromatography: Hexon versus fiber.

    Science.gov (United States)

    Ruščić, Jelena; Ambriović-Ristov, Andreja; Majhen, Dragomira; Kolundžija, Sandra; Barut, Miloš; Benihoud, Karim; Krajačić, Mladen

    2016-11-01

    The serotype specificity of adenovirus ion-exchange chromatography has previously been studied using standard particle-based columns, and the hexon protein has been reported to determine retention time. In this study, we have submitted Adenovirus type 5 recombinants to anion-exchange chromatography using methacrylate monolithic supports. Our experiments with hexon-modified adenoviral vectors show more precisely that the retention time is affected by the substitution of amino acids in hypervariable region 5, which lies within the hexon DE1 loop. By exploring the recombinants modified in the fiber protein, we have proven the previously predicted chromatographic potential of this surface constituent. Modifications that preserve the net charge of the hexon protein, or those that cause only a small charge difference in the fiber protein, in addition to shortening the fiber shaft, did not change the chromatographic behavior of the adenovirus particles. However, modifications that include the deletion of just two negatively charged amino acids in the hexon protein, or the introduction of a heterologous fiber protein, derived from another serotype, revealed recognizable changes in anion-exchange chromatography. This could be useful in facilitating chromatography-approach purification by creating targeted capsid modifications, thereby shifting adenovirus particles away from particular interfering substances present in the crude lysate. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  19. Fractional Charge Definitions and Conditions

    Energy Technology Data Exchange (ETDEWEB)

    Goldhaber, A.S.

    2004-06-04

    Fractional charge is known through theoretical and experimental discoveries of isolable objects carrying fractions of familiar charge units--electric charge Q, spin S, and the difference of baryon and lepton numbers B-L. With a few simple assumptions all these effects may be described using a generalized version of charge renormalization for locally conserved charges, in which medium correlations yield familiar adiabatic, continuous renormalization, or sometimes nonadiabatic, discrete renormalization. Fractional charges may be carried by fundamental particles or fundamental solitons. Either picture works for the simplest fractional-quantum-Hall-effect quasiholes, though the particle description is far more general. The only known fundamental solitons in three or fewer space dimensions d are the kink (d = 1), the vortex (d = 2), and the magnetic monopole (d = 3). Further, for a charge not intrinsically coupled to the topological charge of a soliton, only the kink and the monopole may carry fractional values. The same reasoning enforces fractional values of B-L for electrically charged elementary particles.

  20. LISA and LISA Pathfinder charging

    Energy Technology Data Exchange (ETDEWEB)

    Sumner, T J; Shaul, D N A; Schulte, M O; Waschke, S; Hollington, D; Araujo, H, E-mail: t.sumner@imperial.ac.u [Imperial College London, Prince Consort Road, London SW7 2AZ (United Kingdom)

    2009-05-07

    Charging of the isolated proof masses which form the mirrors defining the path lengths for the LISA and LISA Pathfinder (LISAPF) interferometers turns out to be one of the limiting sources of spurious noise for both missions. An overview of the charging effects and processes will be given which set the scale of the charge-induced noise contributions within the overall LISA sensitivity budget. The current charge control hardware and operations for LISAPF will be described, followed by a forward look to the necessary further developments needed for LISA.

  1. Charge distribution of d*(2380 )

    Science.gov (United States)

    Dong, Yubing; Huang, Fei; Shen, Pengnian; Zhang, Zongye

    2017-11-01

    Based on a chiral constituent quark model, we calculate the charge distributions of d*(2380 ). We consider the existence of two different interpretations of the d*: a compact structure in the two-coupled-channel (Δ Δ +C C ) approximation, and a resonant structure of D12π . We calculate the charge distribution of the d* with a compact structure, and we also roughly estimate the charge distribution for a D12π structure on the same base. The result shows that there is a remarkable difference in the charge distributions of the two structural pictures. Therefore, we expect that future experiments may provide a clear signal for the d* structure.

  2. Charged Polaritons with Spin 1

    Directory of Open Access Journals (Sweden)

    Samoilov V.

    2011-04-01

    Full Text Available We present a new model for metal which is based on the stimulated vibration of independent charged Fermi-ions, representing as independent harmonic oscillators with natural frequencies, under action of longitudinal and transverse elastic waves. Due to application of the elastic wave-particle principle and ion-wave dualities, we predict the existence of two types of charged Polaritons with spin 1 which are induced by longitudinal and transverse elastic fields. As result of presented theory, at small wavenumbers, these charged polaritons represent charged phonons.

  3. Low-charge-state linac

    Energy Technology Data Exchange (ETDEWEB)

    Shepard, K.W.; Kim, J.W.

    1995-08-01

    A design is being developed for a low-charge-state linac suitable for injecting ATLAS with a low-charge-state, radioactive beam. Initial work indicates that the existing ATLAS interdigital superconducting accelerating structures, together with the superconducting quadrupole transverse focussing element discussed above, provides a basis for a high-performance low-charge-state linac. The initial 2 or 3 MV of such a linac could be based on a normally-conducting, low-frequency RFQ, possibly combined with 24-MHz superconducting interdigital structures. Beam dynamics studies of the whole low-charge-state post-accelerator section were carried out in early FY 1995.

  4. Charge Pricing Optimization Model for Private Charging Piles in Beijing

    Directory of Open Access Journals (Sweden)

    Xingping Zhang

    2017-11-01

    Full Text Available This paper develops a charge pricing model for private charging piles (PCPs by considering the environmental and economic effects of private electric vehicle (PEV charging energy sources and the impact of PCP charging load on the total load. This model simulates users’ responses to different combinations of peak-valley prices based on the charging power of PCPs and user charging transfer rate. According to the regional power structure, it calculates the real-time coal consumption, carbon dioxide emissions reduction, and power generation costs of PEVs on the power generation side. The empirical results demonstrate that the proposed peak-valley time-of-use charging price can not only minimize the peak-valley difference of the total load but also improve the environmental effects of PEVs and the economic income of the power system. The sensitivity analysis shows that the load-shifting effect of PCPs will be more obvious when magnifying the number of PEVs by using the proposed charging price. The case study indicates that the proposed peak, average, and valley price in Beijing should be 1.8, 1, and 0.4 yuan/kWh, which can promote the large-scale adoption of PEVs.

  5. Charge migration and charge transfer in molecular systems

    Directory of Open Access Journals (Sweden)

    Hans Jakob Wörner

    2017-11-01

    Full Text Available The transfer of charge at the molecular level plays a fundamental role in many areas of chemistry, physics, biology and materials science. Today, more than 60 years after the seminal work of R. A. Marcus, charge transfer is still a very active field of research. An important recent impetus comes from the ability to resolve ever faster temporal events, down to the attosecond time scale. Such a high temporal resolution now offers the possibility to unravel the most elementary quantum dynamics of both electrons and nuclei that participate in the complex process of charge transfer. This review covers recent research that addresses the following questions. Can we reconstruct the migration of charge across a molecule on the atomic length and electronic time scales? Can we use strong laser fields to control charge migration? Can we temporally resolve and understand intramolecular charge transfer in dissociative ionization of small molecules, in transition-metal complexes and in conjugated polymers? Can we tailor molecular systems towards specific charge-transfer processes? What are the time scales of the elementary steps of charge transfer in liquids and nanoparticles? Important new insights into each of these topics, obtained from state-of-the-art ultrafast spectroscopy and/or theoretical methods, are summarized in this review.

  6. Generic Construction of Privacy-Preserving Optimistic Fair Exchange Protocols

    Directory of Open Access Journals (Sweden)

    Qingwen Guo

    2017-05-01

    Full Text Available Privacy-preserving optimistic fair exchange (P2OFE is a kind of protocols which aim to solve the fairness problem in the exchange of digital signatures between two parties and in the meanwhile protect their privacy. In P2OFE, no one else including the semi-trusted third party in charge of arbitration can confirm an exchange even after resolving a dispute. In this paper we present a black-box construction of P2OFE based on a tag-based public key encryption scheme and a standard digital signature scheme. Our construction follows the ‘sign-then-encrypt’ paradigm, and is secure in the standard model. Our construction is generic and admits more instantiations of P2OFE.

  7. Charge-order fluctuations and superconductivity in two-dimensional organic metals

    Science.gov (United States)

    Girlando, Alberto; Masino, Matteo; Schlueter, John A.; Drichko, Natalia; Kaiser, Stefan; Dressel, Martin

    2014-05-01

    We report comprehensive Raman and infrared investigations of charge-order (CO) fluctuations in the organic metal β''-(BEDT-TTF)2SF5CHFSO3 and superconductor β''-(BEDT-TTF)2SF5CH2CF2SO3. The charge-sensitive vibrational bands are analyzed through an extension of the well-known Kubo model for the spectral signatures of an equilibrium between two states. At room temperature, both salts exhibit charge fluctuations between two differently charged molecular states with an exchange frequency of about 6×1011s-1. The exchange rate of the metallic salt remains roughly constant down to 10 K, while in the superconductor, the exchange velocity starts to decrease below 200 K, and a "frozen" charge-ordered state emerges and coexists with the charge-order fluctuation state down to the superconducting temperature. These findings are confronted with other spectroscopic experiments, and a tentative phase diagram is proposed for the β'' BEDT-TTF quarter-filled salts.

  8. The Dynamics of Multilateral Exchange

    Science.gov (United States)

    Hausken, Kjell; Moxnes, John F.

    The article formulates a dynamic mathematical model where arbitrarily many players produce, consume, exchange, loan, and deposit arbitrarily many goods over time to maximize utility. Consuming goods constitutes a benefit, and producing, exporting, and loaning away goods constitute a cost. Utilities are benefits minus costs, which depend on the exchange ratios and bargaining functions. Three-way exchange occurs when one player acquires, through exchange, one good from another player with the sole purpose of using this good to exchange against the desired good from a third player. Such a triple handshake is not merely a set of double handshakes since the player assigns no interest to the first good in his benefit function. Cognitive and organization costs increase dramatically for higher order exchanges. An exchange theory accounting for media of exchange follows from simple generalization of two-way exchange. The examples of r-way exchange are the triangle trade between Africa, the USA, and England in the 17th and 18th centuries, the hypothetical hypercycle involving RNAs as players and enzymes as goods, and reaction-diffusion processes. The emergence of exchange, and the role of trading agents are discussed. We simulate an example where two-way exchange gives zero production and zero utility, while three-way exchange causes considerable production and positive utility. Maximum utility for each player is reached when exchanges of the same order as the number of players in society are allowed. The article merges micro theory and macro theory within the social, natural, and physical sciences.

  9. Noise suppression and long-range exchange coupling for gallium arsenide spin qubits

    DEFF Research Database (Denmark)

    Malinowski, Filip

    of the qubit splitting with respect to gate voltages. We show that for singlet-triplet and resonant exchange qubit this can be achieved by operating a quantum dot array in a highly symmetric configuration. The symmetrization approach results in a factor-of-six improvement of the double dot singlet......-triplet exchange oscillations quality factor while the dephasing times for the threeelectron resonant exchange qubit are marginally longer. Second, we present the study of the Overhauser field noise arising due to interaction with the nuclear spin bath. We show that the Overhauser field noise conforms to classical...... dot in nine different charge occupancies and identify ground state spin in all cases. For even-occupied spin-1/2 multielectron quantum dot a variation of the gate voltage by a few milivolts in the vicinity of the charge transition leads to sign change of the exchange interaction with a single...

  10. Cryogenic regenerative heat exchangers

    CERN Document Server

    Ackermann, Robert A

    1997-01-01

    An in-depth survey of regenerative heat exchangers, this book chronicles the development and recent commercialization of regenerative devices for cryogenic applications. Chapters cover historical background, concepts, practical applications, design data, and numerical solutions, providing the latest information for engineers to develop advanced cryogenic machines. The discussions include insights into the operation of a regenerator; descriptions of the cyclic and fluid temperature distributions in a regenerator; data for various matrix geometries and materials, including coarse and fine bronze, stainless steel-woven wire mesh screens, and lead spheres; and unique operating features of cryocoolers that produce deviations from ideal regenerator theory.

  11. Quantum charged rigid membrane

    Energy Technology Data Exchange (ETDEWEB)

    Cordero, Ruben [Departamento de Fisica, Escuela Superior de Fisica y Matematicas del I.P.N., Unidad Adolfo Lopez Mateos, Edificio 9, 07738 Mexico, D.F. (Mexico); Molgado, Alberto [Unidad Academica de Fisica, Universidad Autonoma de Zacatecas, Zacatecas Zac. (Mexico); Rojas, Efrain, E-mail: cordero@esfm.ipn.mx, E-mail: amolgado@fisica.uaz.edu.mx, E-mail: efrojas@uv.mx [Departamento de Fisica, Facultad de Fisica e Inteligencia Artificial, Universidad Veracruzana, 91000 Xalapa, Veracruz (Mexico)

    2011-03-21

    The early Dirac proposal to model the electron as a charged membrane is reviewed. A rigidity term, instead of the natural membrane tension, involving linearly the extrinsic curvature of the worldvolume swept out by the membrane is considered in the action modeling the bubble in the presence of an electromagnetic field. We set up this model as a genuine second-order derivative theory by considering a non-trivial boundary term which plays a relevant part in our formulation. The Lagrangian in question is linear in the bubble acceleration and by means of the Ostrogradski-Hamiltonian approach, we observed that the theory comprises the management of both first- and second-class constraints. We thus show that our second-order approach is robust allowing for a proper quantization. We found an effective quantum potential which permits us to compute bounded states for the system. We comment on the possibility of describing brane world universes by invoking this kind of second-order correction terms.

  12. Searches for charged Higgs bosons

    CERN Document Server

    Ellert, M

    2002-01-01

    The results of the searches for charged Higgs bosons at the four experiments at the LEP collider have been combined in order derive an exclusion limit using the largest possible data sample. This combined analysis excludes the existence of charged Higgs bosons with masses lower than 78.6 GeV/c/sup 2/ at 95% confidence level. (5 refs).

  13. Point Charges and Polygonal Linkages

    NARCIS (Netherlands)

    Khimshiashvili, Giorgi; Panina, Gaiane; Siersma, Dirk; Zolotov, Vladimir

    We investigate the critical points of Coulomb potential of point charges placed at the vertices of a planar polygonal linkage. It is shown that, for a collection of positive charges on a pentagonal linkage, there is a unique critical point in the set of convex configurations which is the point of

  14. Charged-lepton flavour physics

    Indian Academy of Sciences (India)

    Abstract. This write-up on a talk at the 2011 Lepton–Photon symposium in Mumbai, India, summarizes recent results in the charged-lepton flavour sector. Searches for charged-lepton flavour violation, lepton electric dipole moments and flavour-conserving CP violation are reviewed here. Recent progress in -lepton physics ...

  15. A Critical Assessment of Two-Phase Flow Distribution in Microchannel Heat Exchangers

    OpenAIRE

    Panghat, Karthik; Mehendale, Sunil S

    2016-01-01

    Due to the many benefits offered by Microchannel Heat Exchangers (MCHX), such as compactness, high heat transfer coefficients, reduced refrigerant charge, and energy and material cost savings, microchannel condensers and evaporators continue to be increasingly applied and investigated in the HVAC&R fields. One of the practical challenges associated with MCHX is the uniform distribution of two-phase refrigerant in the headers and tubes of the heat exchanger. In MCHX, which typically have port ...

  16. Pion-exchange contribution to the parity-violating asymmetry in pp scattering

    Science.gov (United States)

    Silbar, Richard R.; Kloet, W. M.; Kisslinger, Leonard S.; Dubach, J.

    1989-05-01

    Charged pion exchange, producing nΔ++ intermediate states, contributes negatively to the weak scattering asymmetry in longitudinally-polarized pp scattering. Including this contribution moves the theoretical prediction away from the 800 MeV experimental datum. The pion-exchange contribution has both inelastic and elastic scattering components and is sizeable even below the pion production threshold. Strong distortions enhance the magnitude of the effect.

  17. Pion-exchange contribution to the parity-violating asymmetry in pp scattering

    Energy Technology Data Exchange (ETDEWEB)

    Silbar, R.R. (Los Alamos National Laboratory, Los Alamos, NM 87545 (US)); Kloet, W.M. (Rutgers University, New Brunswick, NJ 08903); Kisslinger, L.S. (Carnegie-Mellon University, Pittsburgh, PA 15213); Dubach, J. (University of Massachusetts, Amherst, MA 01003)

    1989-05-01

    Charged pion exchange, producing n{Delta}{sup ++} intermediate states, contributes negatively to the weak scattering asymmetry in longitudinally-polarized pp scattering. Including this contribution moves the theoretical prediction away from the 800 MeV experimental datum. The pion-exchange contribution has both inelastic and elastic scattering components and is sizeable even below the pion production threshold. Strong distortions enhance the magnitude of the effect.

  18. A study of heat-transfer processes in a countercurrent cyclone heat exchanger

    Energy Technology Data Exchange (ETDEWEB)

    M.G. Abuov; P.A. Kovgan [TOO Gornoe Byuro (Mining Bureau), Alma Aty (Kazakhstan)

    2009-07-01

    Heat-transfer processes in a countercurrent cyclone heat exchanger are investigated on a pilot installation. Volumetric coefficients of heat transfer from gases to a flow of solid particles are determined during operation with tangentially swirled flow of gas suspension, separation of solid particles on the heat-exchanger walls, and deceleration of flue gas flows as they collide with the charge mixture fed to the apparatus.

  19. Charge Master: Friend or Foe?

    Science.gov (United States)

    Wan, Wenshuai; Itri, Jason

    2016-01-01

    Prices charged for imaging services can be found in the charge master, a catalog of retail list prices for medical goods and services. This article reviews the evolution of reimbursement in the United States and provides a balanced discussion of the factors that influence charge master prices. Reduced payments to hospitals have pressured hospitals to generate additional revenue by increasing charge master prices. An unfortunate consequence is that those least able to pay for health care, the uninsured, are subjected to the highest charges. Yet, differences in pricing also represent an opportunity for radiology practices, which provide imaging services that are larger in scope or superior in quality to promote product differentiation. Physicians, hospital executives, and policy makers need to work together to improve the existing reimbursement system to promote high-quality, low-cost imaging. Copyright © 2016 Mosby, Inc. All rights reserved.

  20. Static Gas-Charging Plug

    Science.gov (United States)

    Indoe, William

    2012-01-01

    A gas-charging plug can be easily analyzed for random vibration. The design features two steeped O-rings in a radial configuration at two different diameters, with a 0.050-in. (.1.3-mm) diameter through-hole between the two O-rings. In the charging state, the top O-ring is engaged and sealing. The bottom O-ring outer diameter is not squeezed, and allows air to flow by it into the tank. The inner diameter is stretched to plug the gland diameter, and is restrained by the O-ring groove. The charging port bushing provides mechanical stop to restrain the plug during gas charge removal. It also prevents the plug from becoming a projectile when removing gas charge from the accumulator. The plug can easily be verified after installation to ensure leakage requirements are met.

  1. Portable refrigerant charge meter and method for determining the actual refrigerant charge in HVAC systems

    Science.gov (United States)

    Gao, Zhiming; Abdelaziz, Omar; LaClair, Tim L.

    2017-08-08

    A refrigerant charge meter and a method for determining the actual refrigerant charge in HVAC systems are described. The meter includes means for determining an optimum refrigerant charge from system subcooling and system component parameters. The meter also includes means for determining the ratio of the actual refrigerant charge to the optimum refrigerant charge. Finally, the meter includes means for determining the actual refrigerant charge from the optimum refrigerant charge and the ratio of the actual refrigerant charge to the optimum refrigerant charge.

  2. Sedimentation of a charged porous particle in a charged cavity.

    Science.gov (United States)

    Chang, Ya J; Keh, Huan J

    2013-10-10

    The sedimentation of a charged porous sphere at the center of a charged spherical cavity filled with an electrolyte solution is analyzed. The thickness of the electric double layers around the particle and cavity wall is arbitrary, and their relaxation effect is considered. Through the use of a set of linearized electrokinetic equations and a perturbation method, the ionic electrochemical potential energy, electric potential, and velocity fields in the fluid are solved with the fixed space charge density of the particle and surface charge density of the cavity as the small perturbation parameters, and an explicit formula for the sedimentation velocity is obtained. Due to the electroosmotic enhancement on the fluid recirculation in the cavity caused by the sedimentation-induced electric field, the presence of the surface charges on the cavity wall increases the sedimentation velocity of the porous particle. For the sedimentation of a porous particle in a cavity with their fixed charges of the same sign, the effect of electric interaction between the particle and cavity wall in general increases the sedimentation velocity. For the case of their fixed charges with opposite signs, the sedimentation velocity is increased/reduced if the magnitude of the fixed charge density of the cavity wall is relatively large/small. The effect of the surface charges at the cavity wall on the sedimentation of the porous particle increases with an increase in the permeability for fluid flow within the particle and with a decrease in the particle-to-cavity radius ratio (i.e., an increase in the surface area of the cavity wall relative to a given size of the particle, which enhances the fluid recirculation effect).

  3. Reptation Quantum Monte Carlo Calculation of Charge Transfer in The Na-Cl Dimer

    Science.gov (United States)

    Yao, Yi; Kanai, Yosuke

    2015-03-01

    Reptation Quantum Monte Carlo (QMC) calculations are performed to describe the charge transfer behavior in a NaCl dimer. Influence of fixed node approximation on the charge transfer was examined by obtaining electron density via reputation QMC. We employ Slater-Jastrow wavefunction as the trial wavefunction, and the fermion nodes are obtained from single particle orbitals of Hartree-Fock and Density Functional Theory (DFT) with several exchange-correlation approximations. We will discuss our QMC results together with DFT calculations to give insights into observed dependence of the charge transfer behavior on the fixed-node approximation.

  4. Radiation by moving charges

    Energy Technology Data Exchange (ETDEWEB)

    Geloni, Gianluca [European XFEL GmbH, Hamburg (Germany); Kocharyan, Vitali; Saldin, Evgeni [Deutsches Elektronen-Synchrotron (DESY), Hamburg (Germany)

    2017-04-15

    It is generally accepted that in order to describe the dynamics of relativistic particles in the laboratory (lab) frame it is sufficient to take into account the relativistic dependence of the particle momenta on the velocity. This solution of the dynamics problem in the lab frame makes no reference to Lorentz transformations. For this reason they are not discussed in particle tracking calculations in accelerator and plasma physics. It is generally believed that the electrodynamics problem can be treated within the same ''single inertial frame'' description without reference to Lorentz transformations. In particular, in order to evaluate radiation fields arising from charged particles in motion we need to know their velocities and positions as a function of the lab frame time t. The relativistic motion of a particle in the lab frame is described by Newton's second law ''corrected'' for the relativistic dependence of momentum on velocity. It is assumed in all standard derivations that one can perform identification of the trajectories in the source part of the usual Maxwell's equations with the trajectories vector x(t) measured (or calculated by using the corrected Newton's second law) in the lab frame. This way of coupling fields and particles is considered since more than a century as the relativistically correct procedure.We argue that this procedure needs to be changed, and we demonstrate the following, completely counterintuitive statement: the results of conventional theory of radiation by relativistically moving charges are not consistent with the principle of relativity. In order to find the trajectory of a particle in the lab frame consistent with the usual Maxwell's equations, one needs to solve the dynamic equation inmanifestly covariant form by using the coordinate-independent proper time τ to parameterize the particle world-line in space-time. We show that there is a difference between &apos

  5. Effects and Implications for Adoption of Brokerage System in Korea's Foreign Exchange Market

    Directory of Open Access Journals (Sweden)

    Yunjong Wang

    1999-03-01

    Full Text Available Since January 1st 1999, the South Korean government has begun to establish the understructure of the foreign exchange market in order to achieve the liberalization of foreign exchange. As one of the plans, the trade of foreign exchange which was under the monopolized mediation of the capital medium of financial settlement center will be in the charge of several commercial brokers. In the developed countries, the foreign exchange & stock system and the liberalization of foreign exchange are both widely used in a flexible way. So it is predicted that the introduction of commercial foreign exchange & stock system will bring positive effect to the enhancement of the market efficiency and the function of price both in South Korean market and overseas market, the foster of competitive power of the domestic broker and the improvement of the understructure of domestic foreign exchange market. But more importantly is that the foreign exchange market must expand the scale of its participator, bring in various relevant foreign exchange products and develop the bond market which has a close relationship with the foreign exchange market for further development.

  6. Phase behavior of charged colloids : many-body effects, charge renormalization and charge regulation

    NARCIS (Netherlands)

    Zoetekouw, Bastiaan

    2006-01-01

    The main topic of this thesis is Poisson–Boltzmann theory for suspensions of charged colloids in two of its approximations: cell-type approximations that explicitly take into account non-linear effects near the colloidal surfaces, such as charge renormalization, at the expense of neglecting any

  7. Developing bulk exchange spring magnets

    Energy Technology Data Exchange (ETDEWEB)

    Mccall, Scott K.; Kuntz, Joshua D.

    2017-06-27

    A method of making a bulk exchange spring magnet by providing a magnetically soft material, providing a hard magnetic material, and producing a composite of said magnetically soft material and said hard magnetic material to make the bulk exchange spring magnet. The step of producing a composite of magnetically soft material and hard magnetic material is accomplished by electrophoretic deposition of the magnetically soft material and the hard magnetic material to make the bulk exchange spring magnet.

  8. Characteristics of model heat exchanger

    Science.gov (United States)

    Kolínský, Jan

    2017-09-01

    The aim of this paper is thermal analysis of model water to water heat exchanger at different mass flow rates. Experimental study deals with determination of total heat transfer - power of the heat exchanger. Furthermore the paper deals with analysis of heat exchanger charakcteristic using a definition of thermal efficiency. It is demonstrated that it is advisable to monitor the dependence of thermal efficiency and flow ratio.

  9. When Charged Black Holes Merge

    Science.gov (United States)

    Kohler, Susanna

    2016-08-01

    Most theoretical models assume that black holes arent charged. But a new study shows that mergers of charged black holes could explain a variety of astrophysical phenomena, from fast radio bursts to gamma-ray bursts.No HairThe black hole no hair theorem states that all black holes can be described by just three things: their mass, their spin, and their charge. Masses and spins have been observed and measured, but weve never measured the charge of a black hole and its widely believed that real black holes dont actually have any charge.That said, weve also never shown that black holes dont have charge, or set any upper limits on the charge that they might have. So lets suppose, for a moment, that its possible for a black hole to be charged. How might that affect what we know about the merger of two black holes? A recent theoretical study by Bing Zhang (University of Nevada, Las Vegas) examines this question.Intensity profile of a fast radio burst, a sudden burst of radio emission that lasts only a few milliseconds. [Swinburne Astronomy Productions]Driving TransientsZhangs work envisions a pair of black holes in a binary system. He argues that if just one of the black holes carries charge possibly retained by a rotating magnetosphere then it may be possible for the system to produce an electromagnetic signal that could accompany gravitational waves, such as a fast radio burst or a gamma-ray burst!In Zhangs model, the inspiral of the two black holes generates a global magnetic dipole thats perpendicular to the plane of the binarys orbit. The magnetic flux increases rapidly as the separation between the black holes decreases, generating an increasingly powerful magnetic wind. This wind, in turn, can give rise to a fast radio burst or a gamma-ray burst, depending on the value of the black holes charge.Artists illustration of a short gamma-ray burst, thought to be caused by the merger of two compact objects. [ESO/A. Roquette]Zhang calculates lower limits on the charge

  10. Charge-pump voltage converter

    Science.gov (United States)

    Brainard, John P [Albuquerque, NM; Christenson, Todd R [Albuquerque, NM

    2009-11-03

    A charge-pump voltage converter for converting a low voltage provided by a low-voltage source to a higher voltage. Charge is inductively generated on a transfer rotor electrode during its transit past an inductor stator electrode and subsequently transferred by the rotating rotor to a collector stator electrode for storage or use. Repetition of the charge transfer process leads to a build-up of voltage on a charge-receiving device. Connection of multiple charge-pump voltage converters in series can generate higher voltages, and connection of multiple charge-pump voltage converters in parallel can generate higher currents. Microelectromechanical (MEMS) embodiments of this invention provide a small and compact high-voltage (several hundred V) voltage source starting with a few-V initial voltage source. The microscale size of many embodiments of this invention make it ideally suited for MEMS- and other micro-applications where integration of the voltage or charge source in a small package is highly desirable.

  11. Big break for charge symmetry

    CERN Document Server

    Miller, G A

    2003-01-01

    Two new experiments have detected charge-symmetry breaking, the mechanism responsible for protons and neutrons having different masses. Symmetry is a crucial concept in the theories that describe the subatomic world because it has an intimate connection with the laws of conservation. The theory of the strong interaction between quarks - quantum chromodynamics - is approximately invariant under what is called charge symmetry. In other words, if we swap an up quark for a down quark, then the strong interaction will look almost the same. This symmetry is related to the concept of sup i sospin sup , and is not the same as charge conjugation (in which a particle is replaced by its antiparticle). Charge symmetry is broken by the competition between two different effects. The first is the small difference in mass between up and down quarks, which is about 200 times less than the mass of the proton. The second is their different electric charges. The up quark has a charge of +2/3 in units of the proton charge, while ...

  12. Charge-Transfer in Time-Dependent Density Functional Theory: Insights from the Asymmetric Hubbard Dimer

    CERN Document Server

    Fuks, J I

    2013-01-01

    We show that an asymmetric two-fermion two-site Hubbard model illustrates the essential features of long-range charge-transfer dynamics in a real-space molecule. We apply a resonant field that transfers one fermion from one site to the other. Via constrained search we find the exact ground-state exchange-correlation functional, and use it to propagate the Kohn-Sham system, giving the first "adiabatically-exact" calculation of time-resolved charge-transfer. This propagation fails to properly transfer charge. We analyze why by comparing the exact and adiabatically-exact potentials and discuss the role of the derivative discontinuity. The implication for real-space molecules is that even the best possible adiabatic approximation, despite capturing non-local step features relevant to dissociation and charge-transfer excitations, cannot capture fully time-resolved charge-transfer dynamics.

  13. Flywheel-Based Fast Charging Station - FFCS for Electric Vehicles and Public Transportation

    Science.gov (United States)

    Gabbar, Hossam A.; Othman, Ahmed M.

    2017-08-01

    This paper demonstrates novel Flywheel-based Fast Charging Station (FFCS) for high performance and profitable charging infrastructures for public electric buses. The design criteria will be provided for fast charging stations. The station would support the private and open charging framework. Flywheel Energy storage system is utilized to offer advanced energy storage for charging stations to achieve clean public transportation, including electric buses with reducing GHG, including CO2 emission reduction. The integrated modelling and management system in the station is performed by a decision-based control platform that coordinates the power streams between the quick chargers, the flywheel storage framework, photovoltaic cells and the network association. There is a tidy exchange up between the capacity rate of flywheel framework and the power rating of the network association.”

  14. What Drives Stock Exchange Integration?

    National Research Council Canada - National Science Library

    Ekaterina Dorodnykh

    2013-01-01

    .... After a broad discussion of the existent literature, the investigation combines a large number of potentially relevant determinants for the explanation of whether stock exchanges are participating...

  15. Mastering Microsoft Exchange Server 2013

    CERN Document Server

    Elfassy, David

    2013-01-01

    The bestselling guide to Exchange Server, fully updated for the newest version Microsoft Exchange Server 2013 is touted as a solution for lowering the total cost of ownership, whether deployed on-premises or in the cloud. Like the earlier editions, this comprehensive guide covers every aspect of installing, configuring, and managing this multifaceted collaboration system. It offers Windows systems administrators and consultants a complete tutorial and reference, ideal for anyone installing Exchange Server for the first time or those migrating from an earlier Exchange Server version.Microsoft

  16. Ferromagnetism and interlayer exchange coupling in thin metallic films

    Energy Technology Data Exchange (ETDEWEB)

    Kienert, Jochen

    2008-07-15

    This thesis is concerned with the ferromagnetic Kondo lattice (s-d,s-f) model for film geometry. The spin-fermion interaction of this model refers to substances in which localized spins interact with mobile charge carriers like in (dilute) magnetic semiconductors, manganites, or rare-earth compounds. The carrier-mediated, indirect interaction between the localized spins comprises the long-range, oscillatory RKKY exchange interaction in the weak-coupling case and the short-range doubleexchange interaction for strong spin-fermion coupling. Both limits are recovered in this work by mapping the problem onto an effective Heisenberg model. The influence of reduced translational symmetry on the effective exchange interaction and on the magnetic properties of the ferromagnetic Kondo lattice model is investigated. Curie temperatures are obtained for different parameter constellations. The consequences of charge transfer and of lattice relaxation on the magnetic stability at the surface are considered. Since the effective exchange integrals are closely related to the electronic structure in terms of the density of states and of the kinetic energy, the discussion is based on the modifications of these quantities in the dimensionally-reduced case. The important role of spin waves for thin film and surface magnetism is demonstrated. Interlayer exchange coupling represents a particularly interesting and important manifestation of the indirect interaction among localized magnetic moments. The coupling between monatomic layers in thin films is studied in the framework of an RKKY approach. It is decisively determined by the type of in-plane and perpendicular dispersion of the charge carriers and is strongly suppressed above a critical value of the Fermi energy. Finally, the temperature-dependent magnetic stability of thin interlayer-coupled films is addressed and the conditions for a temperature-driven magnetic reorientation transition are discussed. (orig.)

  17. Hybrid Heat Exchangers

    Science.gov (United States)

    Tu, Jianping Gene; Shih, Wei

    2010-01-01

    A hybrid light-weight heat exchanger concept has been developed that uses high-conductivity carbon-carbon (C-C) composites as the heat-transfer fins and uses conventional high-temperature metals, such as Inconel, nickel, and titanium as the parting sheets to meet leakage and structural requirements. In order to maximize thermal conductivity, the majority of carbon fiber is aligned in the fin direction resulting in 300 W/m.K or higher conductivity in the fin directions. As a result of this fiber orientation, the coefficient of thermal expansion (CTE) of the C-C composite in both non-fiber directions matches well with the CTE of various high-temperature metal alloys. This allows the joining of fins and parting sheets by using high-temperature braze alloys.

  18. The Radioecology Exchange

    Energy Technology Data Exchange (ETDEWEB)

    Barnett, Catherine L.; Beresford, Nicholas A.; Patel, Sabera; Wells, Claire; Howard, Brenda J. [NERC Centre for Ecology and Hydrology, CEH Lancaster, Lancaster Environment Centre, Library Av., Bailrigg, Lancaster, LA1 4AP (United Kingdom); Mora, Juan Carlos; Real, Almudena [Centro de Investigaciones Energeticas, Medioambientales y Tecnologicas (CIEMAT), Avenida complutense 22, Madrid, 28040 (Spain); Beaugelin-Seiller, Karine; Gilbin, Rodolphe; Hinton, Thomas [IRSN-Institut de Radioprotection et de Surete Nucleaire, 31, Avenue de la Division Leclerc, 92260 Fontenay-Aux-Roses (France); Vesterbacka, Pia; Muikku, Maarit; Outola, Iisa [Radiation and Nuclear Safety Authority, P.O. Box 14, FI-00881 Helsinki (Finland); Skuterud, Lavrans; AlbumYtre-Eide, Martin [Norwegian Radiation Protection Authority, Grini Naeringspark 13, Oesteraas, 1332 (Norway); Bradshaw, Clare; Stark, Karolina; Jaeschke, Ben [Stockholms Universitet, Universitetsvaegen 10, Stockholm, 10691 (Sweden); Oughton, Deborah; Skipperud, Lindis [NMBU Norwegian University of Life Science P.O. Box 5003N-1432 Aas, Oslo (Norway); Vandenhove, Hildegarde; Vanhoudt, Nathalie [SCK.CEN, Studiecentrum voor Kernenergie/Centre d' Etude de l' Energie Nucleaire, Avenue Herrmann-Debroux 40, BE-1160 Brussels (Belgium); Willrodt, Christine; Steiner, Martin [Bundesamt fuer Strahlenschutz, Willy-Brandt-Strasse 5, 38226 Salzgitter (Germany)

    2014-07-01

    The Radioecology Exchange (www.radioecology-exchange.org) was created in 2011 under the EU FP7 STAR (Strategy for Allied Radioecology) network of excellence. The project aims to integrate the research efforts on radioecology of nine European organisations into a sustainable network. The web site (together with associated Twitter feeds and Facebook page) currently provides the gateway to project outputs and other on-line radiation protection and radioecological resources. In 2013, the EU FP7 COMET (Coordination and implementation of a pan-European instrument for radioecology) project commenced; it aims to strengthen research on the impact of radiation on man and the environment. COMET includes the STAR partners with the addition of one Japanese and two Ukrainian research institutes. As STAR and COMET interact closely together and with the European Radioecology Alliance (www.er-alliance.org/), the Radioecology Exchange will be modified to become an international 'hub' for information related to radioecology. Project specific information will be hosted on separate web sites www.star-radioecology.org and www.comet-radioecology.org. This paper will present an overview of the resources hosted on the Radioecology Exchange inviting other scientists to contribute. Highlighted aspects of the site include: Social media (News blog, Twitter, Facebook) - Items announcing project outputs, training courses, jobs, studentships etc. Virtual laboratory - Information which encourages integration through joint research and integrated use of data and sample materials. These pages will focus on three categories: (1) Methodological: descriptions and video clips of commonly used analytical methods and protocols and the procedures used in STAR and COMET; (2) Informative: databases made available by STAR/COMET partners together with details of sample archives held. Fact-sheets on radio-ecologically important radionuclides and 'topical descriptions' which show absorbed

  19. Rewritable artificial magnetic charge ice

    Science.gov (United States)

    Wang, Yong-Lei; Xiao, Zhi-Li; Snezhko, Alexey; Xu, Jing; Ocola, Leonidas E.; Divan, Ralu; Pearson, John E.; Crabtree, George W.; Kwok, Wai-Kwong

    2016-05-01

    Artificial ices enable the study of geometrical frustration by design and through direct observation. However, it has proven difficult to achieve tailored long-range ordering of their diverse configurations, limiting both fundamental and applied research directions. We designed an artificial spin structure that produces a magnetic charge ice with tunable long-range ordering of eight different configurations. We also developed a technique to precisely manipulate the local magnetic charge states and demonstrate write-read-erase multifunctionality at room temperature. This globally reconfigurable and locally writable magnetic charge ice could provide a setting for designing magnetic monopole defects, tailoring magnonics, and controlling the properties of other two-dimensional materials.

  20. Pion-exchange contribution to the parity-violating asymmetry in p-->p scattering

    Science.gov (United States)

    Silbar, Richard R.; Kloet, W. M.; Kisslinger, Leonard S.; Dubach, J.

    1989-11-01

    Charged pion exchange, resulting in an nΔ++ state, contributes positively to the weak scattering asymmetry in longitudinally polarized p-->p scattering at medium energy. This pion-exchange contribution combined with the traditional ρ and ω ``elastic'' contributions moves the total theoretical prediction into better agreement with the 800-MeV experimental data point. The pion-exchange contribution has both inelastic and elastic scattering components and is sizable even below the pion production threshold. Strong distortions enhance the magnitude of the effect.

  1. Pion-exchange contribution to the parity-violating asymmetry in rvec p p scattering

    Energy Technology Data Exchange (ETDEWEB)

    Silbar, R.R. (Theoretical Division, Los Alamos National Laboratory, University of California, Los Alamos, New Mexico 87545 (US)); Kloet, W.M. (Department of Physics and Astronomy, Rutgers University, New Brunswick, New Jersey 08903); Kisslinger, L.S. (Department of Physics, Carnegie-Mellon University, Pittsburgh, Pennsylvania 15213); Dubach, J. (Department of Physics and Astronomy, University of Massachusetts, Amherst, Massachusetts 01003 Continuous Electron Beam Accelerator Facility (CEBAF), 12000 Jefferson Avenue, Newport News, Virginia 23606)

    1989-11-01

    Charged pion exchange, resulting in an {ital n}{Delta}{sup ++} state, contributes positively to the weak scattering asymmetry in longitudinally polarized {ital {rvec p}p} scattering at medium energy. This pion-exchange contribution combined with the traditional {rho} and {omega} elastic'' contributions moves the total theoretical prediction into better agreement with the 800-MeV experimental data point. The pion-exchange contribution has both inelastic and elastic scattering components and is sizable even below the pion production threshold. Strong distortions enhance the magnitude of the effect.

  2. A novel magnetoresistance induced by charge ordering in ferromagnetic/charge-ordered/ferromagnetic trilayers

    Science.gov (United States)

    Wang, Haiou; Li, Jinwei; Su, Kunpeng; Huo, Dexuan; Tan, Weishi

    2015-10-01

    Microstructure, magnetoresistance (MR) and magnetic properties of Pr0.7Sr0.3MnO3/La0.5Ca0.5MnO3/Pr0.7Sr0.3MnO3 trilayers, which are shown to be tunable with different La0.5Ca0.5MnO3 spacer thickness, are investigated. The trilayer with 6 nm thick La0.5Ca0.5MnO3 spacer show \\text{MR}∼37{%} at 195 K in 1 T and \\text{MR}∼80{%} at 220 K in 9 T, which is realized through the double-exchange mechanism. In contrast, trilayers with the thicker La0.5Ca0.5MnO3 spacer show enhanced MR at a wide low-temperature range. The obtained \\text{MR}∼52{%} at 50 K in 1 T in the trilayer with 18 nm thick La0.5Ca0.5MnO3 spacer is superior to that of other magnetic nanoscales. We surmise that this MR originates in the ferromagnetic/antiferromagnetic competition accompanied with the formation of a charge-ordered antiferromagnetic state and the collapse of the charge-ordered state at the applied magnetic field, rather than in the double-exchange mechanism. Large and tunable MR can be realized by controlling the strain state (the thickness of the La0.5Ca0.5MnO3 spacer), which can be applied in the used devices.

  3. Sequential tentacle grafting and charge modification for enhancing charge density of mono-sized beads for facilitated protein refolding and purification from inclusion bodies.

    Science.gov (United States)

    Dong, Xiao-Yan; Chen, Ran; Yang, Chun-Yan; Sun, Yan

    2014-06-20

    We have previously found that addition of like-charged media in a refolding solution can greatly enhance the refolding of pure proteins by suppressing protein aggregation. Herein, negatively charged mono-sized microspheres with sulfonic groups were fabricated to explore the facilitating effect of like-charged media on the refolding of enhanced green fluorescent protein (EGFP) expressed as inclusion bodies (IBs). A sequential polymer-tentacle grafting and sulfonate modification strategy was developed to increase the charge density of mono-sized poly(glycidyl methacrylate) (pGMA) beads (2.4μm). Namely, GMA was first grafted onto the beads by grafting polymerization to form poly(GMA) tentacles on the pGMA beads, and then the epoxy groups on the tentacles were converted into sulfonic groups by modification with sodium sulfite. By this fabrication strategy, the charge density of the beads reached 793μmol/g, about 2.8 times higher than that modified without prior grafting of the pGMA beads (285μmol/g). The negatively charged beads of different charge densities were used for facilitating the refolding of like-charged EGFP from IBs. The refolding yield as well as refolding rate increased with increasing charge density. The anti-aggregation effects of urea and like-charged microspheres were synergetic. In addition, partial purification of EGFP was achieved because the ion-exchange adsorption led to 52% removal of positively charged contaminant proteins in the refolded solution. Finally, reusability of the tentacle beads was demonstrated by repetitive EGFP refolding and recovery cycles. Copyright © 2014 Elsevier B.V. All rights reserved.

  4. VT Data - Electric Charging Stations

    Data.gov (United States)

    Vermont Center for Geographic Information — Locations of Electric Charging Stations provided by the NREL national laboratory of the U.S. Department of Energy, Office of Energy Efficiency and Renewable Energy....

  5. Measurements of W Charge Asymmetry

    Energy Technology Data Exchange (ETDEWEB)

    Holzbauer, J. L. [Mississippi U.

    2015-10-06

    We discuss W boson and lepton charge asymmetry measurements from W decays in the electron channel, which were made using 9.7 fb$^{-1}$ of RunII data collected by the D0 detector at the Fermilab Tevatron Collider. The electron charge asymmetry is presented as a function of pseudo-rapidity out to |$\\eta$| $\\le$ 3.2, in five symmetric and asymmetric kinematic bins of electron transverse momentum and the missing transverse energy of the event. We also give the W charge asymmetry as a function of W boson rapidity. The asymmetries are compared with next-to-leading order perturbative quantum chromodynamics calculations. These charge asymmetry measurements will allow more accurate determinations of the proton parton distribution functions and are the most precise to date.

  6. Tuning a High Transmission Ion Guide to Prevent Gas-Phase Proton Exchange During H/D Exchange MS Analysis

    Science.gov (United States)

    Guttman, Miklos; Wales, Thomas E.; Whittington, Dale; Engen, John R.; Brown, Jeffery M.; Lee, Kelly K.

    2016-04-01

    Hydrogen/deuterium exchange (HDX) mass spectrometry (MS) for protein structural analysis has been adopted for many purposes, including biopharmaceutical development. One of the benefits of examining amide proton exchange by mass spectrometry is that it can readily resolve different exchange regimes, as evidenced by either binomial or bimodal isotope patterns. By careful analysis of the isotope pattern during exchange, more insight can be obtained on protein behavior in solution. However, one must be sure that any observed bimodal isotope patterns are not artifacts of analysis and are reflective of the true behavior in solution. Sample carryover and certain stationary phases are known as potential sources of bimodal artifacts. Here, we describe an additional undocumented source of deuterium loss resulting in artificial bimodal patterns for certain highly charged peptides. We demonstrate that this phenomenon is predominantly due to gas-phase proton exchange between peptides and bulk solvent within the initial stages of high-transmission conjoined ion guides. Minor adjustments of the ion guide settings, as reported here, eliminate the phenomenon without sacrificing signal intensity. Such gas-phase deuterium loss should be appreciated for all HDX-MS studies using such ion optics, even for routine studies not focused on interpreting bimodal spectra.

  7. Rewritable Artificial Magnetic Charge Ice

    OpenAIRE

    Wang, Yong-Lei; Xiao, Zhi-Li; Snezhko, Alexey; Xu, Jing; Ocola, Leonidas E.; Divan, Ralu; Pearson, John E.; Crabtree, George W.; Kwok, Wai-Kwong

    2016-01-01

    Artificial ices enable the study of geometrical frustration by design and through direct observation. However, it has proven difficult to achieve tailored long-range ordering of their diverse configurations, limiting both fundamental and applied research directions. We designed an artificial spin structure that produces a magnetic charge ice with tunable long-range ordering of eight different configurations. We also developed a technique to precisely manipulate the local magnetic charge state...

  8. 78 FR 69910 - Joint Industry Plan; BATS Exchange, Inc., BATS-Y Exchange, Inc., BOX Options Exchange LLC, C2...

    Science.gov (United States)

    2013-11-21

    ... COMMISSION Joint Industry Plan; BATS Exchange, Inc., BATS-Y Exchange, Inc., BOX Options Exchange LLC, C2... LLC, NYSE Arca, Inc. and Topaz Exchange, LLC; Notice of Filing of Proposed National Market System Plan... and Exchange Commission (``Commission'') the proposed National Market System (``NMS'') Plan Governing...

  9. Fractional Effective Charges and Misner-Wheeler Charge without Charge Effect in Metamaterials

    Directory of Open Access Journals (Sweden)

    Igor Smolyaninov

    2016-07-01

    Full Text Available Transformation optics enables engineering of the effective topology and dimensionality of the optical space in metamaterials. Nonlinear optics of such metamaterials may mimic Kaluza-Klein theories having one or more kinds of effective charges. As a result, novel photon blockade devices may be realized. Here we demonstrate that an electromagnetic wormhole may be designed, which connects two points of such an optical space and changes its effective topological connectivity. Electromagnetic field configurations, which exhibit fractional effective charges, appear as a result of such topology change. Moreover, such effects as Misner-Wheeler “charge without charge” may be replicated.

  10. Selective anion exchange with nanogated isoreticular positive metal-organic frameworks.

    Science.gov (United States)

    Zhao, Xiang; Bu, Xianhui; Wu, Tao; Zheng, Shou-Tian; Wang, Le; Feng, Pingyun

    2013-01-01

    Crystalline porous materials, especially inorganic porous solids such as zeolites, usually have negative frameworks with extra-framework mobile cations and are widely used for cation exchange. It is highly desirable to develop new materials with positive frameworks for selective anion exchange and separation or storage and delivery. Recent advances in metal-organic framework synthesis have created new opportunities in this direction. Here we report the synthesis of a series of positive indium metal-organic frameworks and their utilization as a platform for the anion exchange-based separation process. This process is capable of size- or charge-selective ion-exchange of organic dyes and may form the basis for size-selective ion chromatography. Ion-exchange dynamics of a series of organic dyes and their selective encapsulation and release are also studied, highlighting the advantages of metal-organic framework compositions for designing host materials tailored for applications in anion separation and purification.

  11. Liquid/liquid heat exchanger

    Science.gov (United States)

    Miller, C. G.

    1980-01-01

    Conceptual design for heat exchanger, utilizing two immiscible liquids with dissimilar specific gravities in direct contact, is more efficient mechanism of heat transfer than conventional heat exchangers with walls or membranes. Concept could be adapted for collection of heat from solar or geothermal sources.

  12. Educators Exchange: A Program Evaluation.

    Science.gov (United States)

    Armstrong, William B.

    The Educators Exchange Program (EEP) was established under a training and educational exchange agreement reached by California's San Diego Community College District (SDCCD) and the republic of Mexico. In the program, the District provided a 4-week technological training program to faculty at Centros de Capacitacion Tecnologica Industrial…

  13. Risk Balance in Exchange Protocols

    NARCIS (Netherlands)

    M.T. Dashti (Mohammad); Y. Wang (Yanjing); I. Cervesato

    2007-01-01

    htmlabstractWe study the behaviour of rational agents in exchange protocols which rely on trustees. We allow malicious parties to compromise the trustee by paying a cost and, thereby, present a game analysis that advocates exchange protocols which induce balanced risks on the participants. We also

  14. Professional Exchange: Mapping the Future.

    Science.gov (United States)

    Dingman, Robert L.

    1993-01-01

    New associate editor of Professional Exchange section of "Journal of Mental Health Counseling" discusses importance of section. Lists potential topics suggested in 1989, then adds several other topics to the list. Concludes with guidelines for submission to Professional Exchange section. (NB)

  15. Space-charge electrostatic precipitation

    Energy Technology Data Exchange (ETDEWEB)

    Middleton, C.E.

    1977-05-01

    An improved electrostatic precipitator called a space charge precipitator was tested and studied. A space charge precipitator differs from a conventional model in that the fields necessary to move the particles from the gas to the collecting surfaces are provided by a cloud of charged innocuous drops, such as glycerine or water, rather than by a charged electrode system. The flow conditions, electrical equipment, and physical dimensions of the test precipitator are typical of industrial applications. Experiments using water fog at a velocity of 10 ft/sec and a residence time of 0.6 sec, for a system charged at 25 kV, show a removal of iron oxide particles of approximately 52 percent. Theoretical calculations, assuming 2 micron particles, predict a removal of 50 percent. The results with glycerine fog are comparable. Experiments at various flowrates for both water fog and glycerine fog show a trend of decreasing particle removal for increasing flowrate. An identical trend is predicted by the space charge theory. Electron micrographs verify that only particles smaller than two microns are present in the laboratory precipitator.

  16. Enabling fast charging - Vehicle considerations

    Science.gov (United States)

    Meintz, Andrew; Zhang, Jiucai; Vijayagopal, Ram; Kreutzer, Cory; Ahmed, Shabbir; Bloom, Ira; Burnham, Andrew; Carlson, Richard B.; Dias, Fernando; Dufek, Eric J.; Francfort, James; Hardy, Keith; Jansen, Andrew N.; Keyser, Matthew; Markel, Anthony; Michelbacher, Christopher; Mohanpurkar, Manish; Pesaran, Ahmad; Scoffield, Don; Shirk, Matthew; Stephens, Thomas; Tanim, Tanvir

    2017-11-01

    To achieve a successful increase in the plug-in battery electric vehicle (BEV) market, it is anticipated that a significant improvement in battery performance is required to increase the range that BEVs can travel and the rate at which they can be recharged. While the range that BEVs can travel on a single recharge is improving, the recharge rate is still much slower than the refueling rate of conventional internal combustion engine vehicles. To achieve comparable recharge times, we explore the vehicle considerations of charge rates of at least 400 kW. Faster recharge is expected to significantly mitigate the perceived deficiencies for long-distance transportation, to provide alternative charging in densely populated areas where overnight charging at home may not be possible, and to reduce range anxiety for travel within a city when unplanned charging may be required. This substantial increase in charging rate is expected to create technical issues in the design of the battery system and the vehicle's electrical architecture that must be resolved. This work focuses on vehicle system design and total recharge time to meet the goals of implementing improved charge rates and the impacts of these expected increases on system voltage and vehicle components.

  17. Ion Transport through Diffusion Layer Controlled by Charge Mosaic Membrane

    Directory of Open Access Journals (Sweden)

    Akira Yamauchi

    2012-01-01

    Full Text Available The kinetic transport behaviors in near interface of the membranes were studied using commercial anion and cation exchange membrane and charge mosaic membrane. Current-voltage curve gave the limiting current density that indicates the ceiling of conventional flux. From chronopotentiometry above the limiting current density, the transition time was estimated. The thickness of boundary layer was derived with conjunction with the conventional limiting current density and the transition time from steady state flux. On the other hand, the charge mosaic membrane was introduced in order to examine the ion transport on the membrane surface in detail. The concentration profile was discussed by the kinetic transport number with regard to the water dissociation (splitting on the membrane surface.

  18. Heat exchanger leakage problem location

    Directory of Open Access Journals (Sweden)

    Jícha Miroslav

    2012-04-01

    Full Text Available Recent compact heat exchangers are very often assembled from numerous parts joined together to separate heat transfer fluids and to form the required heat exchanger arrangement. Therefore, the leak tightness is very important property of the compact heat exchangers. Although, the compact heat exchangers have been produced for many years, there are still technological problems associated with manufacturing of the ideal connection between the individual parts, mainly encountered with special purpose heat exchangers, e.g. gas turbine recuperators. This paper describes a procedure used to identify the leakage location inside the prime surface gas turbine recuperator. For this purpose, an analytical model of the leaky gas turbine recuperator was created to assess its performance. The results obtained are compared with the experimental data which were acquired during the recuperator thermal performance analysis. The differences between these two data sets are used to indicate possible leakage areas.

  19. Transendothelial lipoprotein exchange and microalbuminuria

    DEFF Research Database (Denmark)

    Jensen, Jan Skov; Feldt-Rasmussen, Bo; Jensen, Kurt Svarre

    2004-01-01

    OBJECTIVE: Microalbuminuria associates with increased risk of atherosclerosis in individuals without diabetes. We hypothesized that transendothelial lipoprotein exchange is elevated among such individuals, possibly explaining increased intimal lipoprotein accumulation and thus atherosclerosis....... METHODS: Using an in vivo isotope technique, transendothelial exchange of low density lipoprotein (LDL) was measured in 77 non-diabetic individuals. Autologous 131-iodinated LDL was reinjected intravenously, and the 1-h fractional escape rate was calculated as index of transendothelial exchange. RESULTS......: There was no difference in transendothelial LDL exchange between subjects with microalbuminuria versus normoalbuminuria (mean (95% confidence interval) 3.8%/h (3.3-4.3%/h) versus 4.2%/h (3.7-4.7%/h); P=0.33). In contrast, there was a positive correlation between transendothelial LDL exchange and (logarithmically...

  20. Next Generation Microchannel Heat Exchangers

    CERN Document Server

    Ohadi, Michael; Dessiatoun, Serguei; Cetegen, Edvin

    2013-01-01

    In Next Generation Microchannel Heat Exchangers, the authors’ focus on the new generation highly efficient heat exchangers and presentation of novel data and technical expertise not available in the open literature.  Next generation micro channels offer record high heat transfer coefficients with pressure drops much less than conventional micro channel heat exchangers. These inherent features promise fast penetration into many mew markets, including high heat flux cooling of electronics, waste heat recovery and energy efficiency enhancement applications, alternative energy systems, as well as applications in mass exchangers and chemical reactor systems. The combination of up to the minute research findings and technical know-how make this book very timely as the search for high performance heat and mass exchangers that can cut costs in materials consumption intensifies.

  1. High Temperature Heat Exchanger Project

    Energy Technology Data Exchange (ETDEWEB)

    Anthony E. Hechanova, Ph.D.

    2008-09-30

    The UNLV Research Foundation assembled a research consortium for high temperature heat exchanger design and materials compatibility and performance comprised of university and private industry partners under the auspices of the US DOE-NE Nuclear Hydrogen Initiative in October 2003. The objectives of the consortium were to conduct investigations of candidate materials for high temperature heat exchanger componets in hydrogen production processes and design and perform prototypical testing of heat exchangers. The initial research of the consortium focused on the intermediate heat exchanger (located between the nuclear reactor and hydrogen production plan) and the components for the hydrogen iodine decomposition process and sulfuric acid decomposition process. These heat exchanger components were deemed the most challenging from a materials performance and compatibility perspective

  2. The Role of Variable-Charge Minerals in Deep Soil Carbon Storage in a Pacific Northwest Andisol

    Science.gov (United States)

    Dietzen, C.; Root, A.; James, J. N.; Holub, S. M.; Harrison, R. B.

    2015-12-01

    Soil is the most important long-term sink for carbon (C) in terrestrial ecosystems, containing more C than plant biomass and the atmosphere combined. However, soil has historically been under-represented in C cycling literature, especially in regards to information about subsurface (>1.0 m) layers and processes. Previous research has indicated that Andisols with large quantities of noncrystalline, variable-charge minerals, including allophane, imogolite, and ferrihydrite, contain more C both in total and at depth than other soil types in the Pacific Northwest. The electrostatic charge of variable-charge soils depends on pH and is sometimes net positive, particularly in acid conditions, such as those commonly developed under the coniferous forests of the Pacific Northwest. However, even soils with a net negative charge may contain a mixture of negative and positive exchange sites and can hold some nutrient anions through the anion exchange capacity. The most abundant organic functional groups, including carboxylic and phenolic groups, are anionic in nature, and soil positive charge may play an important role in binding and stabilizing soil organic matter and sequestering C. To increase our understanding of the role of variable-charge minerals in soil organic matter stabilization in deep soils, samples were taken to a depth of 3 m at the Fall River Long-Term Soil Productivity Site in western Washington. This site has a deep, well-drained soil with few rocks, which developed from weathered basalt and is classified as an Andisol of the Boistfort Series. Analysis of soil charge characteristics over a pH range allowed for the determination of anion exchange capacity and point of zero net charge at 8 depth intervals. These results, along with total carbon analysis and C-14 dating at each depth interval, are used to evaluate the importance of the anion exchange capacity as a mechanism for storing carbon at depth in variable-charge soils.

  3. Monte Carlo simulation of charge mediated magnetoelectricity in multiferroic bilayers

    Energy Technology Data Exchange (ETDEWEB)

    Ortiz-Álvarez, H.H. [Universidad de Caldas, Manizales (Colombia); Universidad Nacional de Colombia Sede Manizales, Manizales, Caldas (Colombia); Bedoya-Hincapié, C.M. [Universidad Nacional de Colombia Sede Manizales, Manizales, Caldas (Colombia); Universidad Santo Tomás, Bogotá (Colombia); Restrepo-Parra, E., E-mail: erestrepopa@unal.edu.co [Universidad Nacional de Colombia Sede Manizales, Manizales, Caldas (Colombia)

    2014-12-01

    Simulations of a bilayer ferroelectric/ferromagnetic multiferroic system were carried out, based on the Monte Carlo method and Metropolis dynamics. A generic model was implemented with a Janssen-like Hamiltonian, taking into account magnetoelectric interactions due to charge accumulation at the interface. Two different magnetic exchange constants were considered for accumulation and depletion states. Several screening lengths were also included. Simulations exhibit considerable magnetoelectric effects not only at low temperature, but also at temperature near to the transition point of the ferromagnetic layer. The results match experimental observations for this kind of structure and mechanism.

  4. Fault-Tolerant Heat Exchanger

    Science.gov (United States)

    Izenson, Michael G.; Crowley, Christopher J.

    2005-01-01

    A compact, lightweight heat exchanger has been designed to be fault-tolerant in the sense that a single-point leak would not cause mixing of heat-transfer fluids. This particular heat exchanger is intended to be part of the temperature-regulation system for habitable modules of the International Space Station and to function with water and ammonia as the heat-transfer fluids. The basic fault-tolerant design is adaptable to other heat-transfer fluids and heat exchangers for applications in which mixing of heat-transfer fluids would pose toxic, explosive, or other hazards: Examples could include fuel/air heat exchangers for thermal management on aircraft, process heat exchangers in the cryogenic industry, and heat exchangers used in chemical processing. The reason this heat exchanger can tolerate a single-point leak is that the heat-transfer fluids are everywhere separated by a vented volume and at least two seals. The combination of fault tolerance, compactness, and light weight is implemented in a unique heat-exchanger core configuration: Each fluid passage is entirely surrounded by a vented region bridged by solid structures through which heat is conducted between the fluids. Precise, proprietary fabrication techniques make it possible to manufacture the vented regions and heat-conducting structures with very small dimensions to obtain a very large coefficient of heat transfer between the two fluids. A large heat-transfer coefficient favors compact design by making it possible to use a relatively small core for a given heat-transfer rate. Calculations and experiments have shown that in most respects, the fault-tolerant heat exchanger can be expected to equal or exceed the performance of the non-fault-tolerant heat exchanger that it is intended to supplant (see table). The only significant disadvantages are a slight weight penalty and a small decrease in the mass-specific heat transfer.

  5. Spin and charge thermopower effects in the ferromagnetic graphene junction

    Energy Technology Data Exchange (ETDEWEB)

    Vahedi, Javad, E-mail: javahedi@gmail.com [Department of Physics, Sari Branch, Islamic Azad University, Sari (Iran, Islamic Republic of); Center for Theoretical Physics of Complex Systems, Institute for Basic Science (IBS), Daejeon (Korea, Republic of); Barimani, Fattaneh [Center for Theoretical Physics of Complex Systems, Institute for Basic Science (IBS), Daejeon (Korea, Republic of)

    2016-08-28

    Using wave function matching approach and employing the Landauer-Buttiker formula, a ferromagnetic graphene junction with temperature gradient across the system is studied. We calculate the thermally induced charge and spin current as well as the thermoelectric voltage (Seebeck effect) in the linear and nonlinear regimes. Our calculation revealed that due to the electron-hole symmetry, the charge Seebeck coefficient is, for an undoped magnetic graphene, an odd function of chemical potential while the spin Seebeck coefficient is an even function regardless of the temperature gradient and junction length. We have also found with an accurate tuning external parameter, namely, the exchange filed and gate voltage, the temperature gradient across the junction drives a pure spin current without accompanying the charge current. Another important characteristic of thermoelectric transport, thermally induced current in the nonlinear regime, is examined. It would be our main finding that with increasing thermal gradient applied to the junction the spin and charge thermovoltages decrease and even become zero for non zero temperature bias.

  6. 77 FR 20680 - Self-Regulatory Organizations; Chicago Board Options Exchange, Incorporated; Notice of Filing and...

    Science.gov (United States)

    2012-04-05

    ... Immediate Effectiveness of a Proposed Rule Change Relating to FLEX Transaction Fees March 30, 2012. Pursuant... orders that are initially entered as the contra party to an Agency/Primary Order, the transaction fee... standard transaction fees) because the Exchange believes charging a lower fee to the contra-party in CFLEX...

  7. Plant diseases caused by heavy metals and their phytiatry with cation exchangers

    Directory of Open Access Journals (Sweden)

    C. Van Assche

    2015-06-01

    Full Text Available The noxious influence of heavy metals as lead, zinc, copper and lead on higher plants and soil fungi was described. Addition to the soil of Levatit cation exchangers consisting of polystyrene porous resins, charged with calcium or manganese in granulated or powdered form, restored normal plant growth and inhibited the uptake of heavy metals ions.

  8. In-situ soft X-ray absorption of over-exchanged Fe/ZSM5

    NARCIS (Netherlands)

    Heijboer, WM; Battiston, AA; Knop-Gericke, A; Havecker, M; Mayer, R; Bluhm, H; Schlogl, R; Weckhuysen, BM|info:eu-repo/dai/nl/285484397; Koningsberger, DC; de Groot, FMF|info:eu-repo/dai/nl/08747610X

    2003-01-01

    In-situ soft X-ray absorption spectroscopy (XAS) has been applied to study the iron redox behavior in over-exchanged Fe/ZSM5. The Fe L-2,L-3 XAS and O K spectral shapes of the Fe/ZSM5 surface have been measured during heat treatments and reduction/oxidation cycles. Charge-transfer multiplet

  9. 76 FR 40948 - Self-Regulatory Organizations; Chicago Board Options Exchange, Incorporated; Notice of Filing and...

    Science.gov (United States)

    2011-07-12

    ... COMMISSION Self-Regulatory Organizations; Chicago Board Options Exchange, Incorporated; Notice of Filing and...\\ and Rule 19b-4 thereunder,\\2\\ ] notice is hereby given that on June 29, 2011, the Chicago Board... and Firms as either electronic or manual. See NYSE Amex Options Fees Schedule, Trade Related Charges...

  10. 78 FR 3044 - Exchange Traded Spreads Trust, et al.; Notice of Application

    Science.gov (United States)

    2013-01-15

    ... Creation Unit from a Fund will be charged a fee (``Transaction Fee'') to prevent the dilution of the... investment company or mutual fund. Instead, each Fund will be marketed as an ``actively managed exchange... Trust nor any Fund will be advertised or marketed as an open-end investment company or a mutual fund...

  11. Release of proteins via ion exchange from albumin-heparin microspheres

    NARCIS (Netherlands)

    Kwon, Glen S.; Bae, You Han; Cremers, H.F.M.; Cremers, Harry; Feijen, Jan; Kim, Sung Wan

    1992-01-01

    Albumin-heparin and albumin microspheres were prepared as ion exchange gels for the controlled release of positively charged polypeptides and proteins. The adsorption isotherms of chicken egg and human lysozyme, as model proteins, on microspheres were obtained. An adsorption isotherm of chicken egg

  12. 76 FR 64409 - Self-Regulatory Organizations; EDGX Exchange, Inc.; Notice of Filing and Immediate Effectiveness...

    Science.gov (United States)

    2011-10-18

    ... change is available on the Exchange's Internet Web site at http://www.directedge.com . \\3\\ A Member is... charges as it is designed to incentivize Members to add hidden liquidity to the book, but not reward them... for hidden liquidity by BATS (rebate of $0.0017 per share), Nasdsaq tiered rate of .0010/.0015), and...

  13. Deuterium Exchange in the Systems of H2O+/H2O and H3O+/H2O

    Science.gov (United States)

    Anicich, V. G.; Sen, A. D.

    1995-01-01

    Using tandem mass spectrometry various water ion interactions were observed. These reactions consisted of a series of charge transfer, proton transfer, and isotopic exchange steps. The experimental data sets consist of variations of ion abundances over a neutral pressure range. An expected sequence of isotopic exchange reactions is given along with differential equation solutions & reaction rate data.

  14. Capillary ion-exchange chromatography with nanogram sensitivity for the analysis of monoclonal antibodies.

    Science.gov (United States)

    Rea, Jennifer C; Freistadt, Benny S; McDonald, Daniel; Farnan, Dell; Wang, Yajun Jennifer

    2015-12-11

    Ion-exchange chromatography (IEC) is widely used for profiling the charge heterogeneity of proteins, including monoclonal antibodies (mAbs). Despite good resolving power and robustness, ionic strength-based ion-exchange separations are generally product specific and can be time consuming to develop. In addition, conventional analytical scale ion-exchange separations require tens of micrograms of mAbs for each injection, amounts that are often unavailable in sample-limited applications. We report the development of a capillary IEC (c-IEC) methodology for the analysis of nanogram amounts of mAb charge variants. Several key modifications were made to a commercially available liquid chromatography system to perform c-IEC for charge variant analysis of mAbs with nanogram sensitivity. We demonstrate the method for multiple monoclonal antibodies, including antibody fragments, on different columns from different manufacturers. Relative standard deviations of <10% were achieved for relative peak areas of main peak, acidic and basic regions, which are common regions of interest for quantifying monoclonal antibody charge variants using IEC. The results herein demonstrate the excellent sensitivity of this c-IEC characterization method, which can be used for analyzing charge variants in sample-limited applications, such as early-stage candidate screening and in vivo studies. Copyright © 2015 Elsevier B.V. All rights reserved.

  15. Custom, contract, and kidney exchange.

    Science.gov (United States)

    Healy, Kieran; Krawiec, Kimberly D

    2012-01-01

    In this Essay, we examine a case in which the organizational and logistical demands of a novel form of organ exchange (the nonsimultaneous, extended, altruistic donor (NEAD) chain) do not map cleanly onto standard cultural schemas for either market or gift exchange, resulting in sociological ambiguity and legal uncertainty. In some ways, a NEAD chain resembles a form of generalized exchange, an ancient and widespread instance of the norm of reciprocity that can be thought of simply as the obligation to “pay it forward” rather than the obligation to reciprocate directly with the original giver. At the same time, a NEAD chain resembles a string of promises and commitments to deliver something in exchange for some valuable consideration--that is, a series of contracts. Neither of these salient "social imaginaries" of exchange--gift giving or formal contract--perfectly meets the practical demands of the NEAD system. As a result, neither contract nor generalized exchange drives the practice of NEAD chains. Rather, the majority of actual exchanges still resemble a simpler form of exchange: direct, simultaneous exchange between parties with no time delay or opportunity to back out. If NEAD chains are to reach their full promise for large-scale, nonsimultaneous organ transfer, legal uncertainties and sociological ambiguities must be finessed, both in the practices of the coordinating agencies and in the minds of NEAD-chain participants. This might happen either through the further elaboration of gift-like language and practices, or through a creative use of the cultural form and motivational vocabulary, but not necessarily the legal and institutional machinery, of contract.

  16. HEAT EXCHANGERS IN SEWAGE PIPES

    OpenAIRE

    Podobeková, Veronika; Peráčková, Jana

    2014-01-01

    The article discusses utilization of heat from waste water in sewage. During the year, temperature of water in sewage ranges between 10 °C and 20 °C and the heat from sewage could be used for heating, cooling and hot water preparation in building. The heat is extracted through a transfer surface area of the heat exchanger into the heat pump, which is able to utilize the low–potential energy. Different design and types of the heat exchangers in sewage are dealt with: heat exchangers embedded i...

  17. Relational and XML Data Exchange

    CERN Document Server

    Arenas, Marcelo

    2010-01-01

    Data exchange is the problem of finding an instance of a target schema, given an instance of a source schema and a specification of the relationship between the source and the target. Such a target instance should correctly represent information from the source instance under the constraints imposed by the target schema, and it should allow one to evaluate queries on the target instance in a way that is semantically consistent with the source data. Data exchange is an old problem that re-emerged as an active research topic recently, due to the increased need for exchange of data in various for

  18. Heat exchanger using graphite foam

    Science.gov (United States)

    Campagna, Michael Joseph; Callas, James John

    2012-09-25

    A heat exchanger is disclosed. The heat exchanger may have an inlet configured to receive a first fluid and an outlet configured to discharge the first fluid. The heat exchanger may further have at least one passageway configured to conduct the first fluid from the inlet to the outlet. The at least one passageway may be composed of a graphite foam and a layer of graphite material on the exterior of the graphite foam. The layer of graphite material may form at least a partial barrier between the first fluid and a second fluid external to the at least one passageway.

  19. Iodide uptake by negatively charged clay interlayers?

    Science.gov (United States)

    Miller, Andrew; Kruichak, Jessica; Mills, Melissa; Wang, Yifeng

    2015-09-01

    Understanding iodide interactions with clay minerals is critical to quantifying risk associated with nuclear waste disposal. Current thought assumes that iodide does not interact directly with clay minerals due to electrical repulsion between the iodide and the negatively charged clay layers. However, a growing body of work indicates a weak interaction between iodide and clays. The goal of this contribution is to report a conceptual model for iodide interaction with clays by considering clay mineral structures and emergent behaviors of chemical species in confined spaces. To approach the problem, a suite of clay minerals was used with varying degrees of isomorphic substitution, chemical composition, and mineral structure. Iodide uptake experiments were completed with each of these minerals in a range of swamping electrolyte identities (NaCl, NaBr, KCl) and concentrations. Iodide uptake behaviors form distinct trends with cation exchange capacity and mineral structure. These trends change substantially with electrolyte composition and concentration, but do not appear to be affected by solution pH. The experimental results suggest that iodide may directly interact with clays by forming ion-pairs (e.g., NaI(aq)) which may concentrate within the interlayer space as well as the thin areas surrounding the clay particle where water behavior is more structured relative to bulk water. Ion pairing and iodide concentration in these zones is probably driven by the reduced dielectric constant of water in confined space and by the relatively high polarizability of the iodide species. Copyright © 2015 Elsevier Ltd. All rights reserved.

  20. Assessing the Sodium Exchange Capacity in Rainfed and Irrigated Soils in the Mediterranean Basin Using GIS

    Directory of Open Access Journals (Sweden)

    Luís Loures

    2017-03-01

    Full Text Available The soil exchange complex consists of colloidal materials on which ion exchange phenomena occur allowing it to attract, retain, and exchange elements that have opposite electric charges. Since their mineral constituents (clay and organic components (humus are mainly of a negative nature retained or exchanged ion are predominantly cations. Historically, failing to monitor parameters like the exchange sodium percentage (ESP has led to the permanent deterioration of soils which have become completely unproductive, largely reducing the sustainability of the agricultural systems. This study assesses how the sodium exchange capacity in irrigated soils differs from the rainfed ones through a sample survey that was carried out in the 15,031 ha of the Caia Irrigation Perimeter and adjacent areas, located in the municipalities of Elvas and Campo Maior, Portalegre District, Portugal where 14,280 georeferenced samples were collected from the top soil layer (0–20 cm, which were mixed 10 at a time so that each composite sample representing 11.1 ha. Then the samples were analyzed regarding the most relevant parameters for characterizing the soil exchange complex including the concentrations of exchanged bases and Cation Exchange Capacity (CEC. The results were arranged in a georeferenced grid with 1451 entries. Using classical statistical analysis and Geographic Information Systems (GIS software, it was possible to relate the individual soil samples analyzed with the cultural system practiced (irrigated or rainfed and the present soil group which permitted us to analyze the influence of the cultural system in the soil exchange complex. The distribution chart of the exchange sodium and CEC were created. The obtained results confirm a general decrease of CEC values and an increase of the exchangeable sodium content of irrigated explored soils when compared to the rainfed ones, putting forward noteworthy ideas not only regarding the necessary changes towards

  1. Unconventional spin-charge phase separation in a model 2D cuprate

    Science.gov (United States)

    Panov, Yu. D.; Budrin, K. S.; Chikov, A. A.; Moskvin, A. S.

    2017-09-01

    In this Letter we address a challenging problem of a competition of charge and spin orders for high-Tc cuprates within a simplified 2D spin-pseudospin model which takes into account both conventional Heisenberg Cu2+-Cu2+ antiferromagnetic spin exchange coupling (J) and the on-site (U) and inter-site (V) charge correlations in the CuO2 planes with the on-site Hilbert space reduced to only three effective charge states (nominally Cu1+;2+;3+). We performed classical Monte-Carlo calculations for large square lattices implying the mobile doped charges and focusing on a case of a small inter-site repulsion V ≪ J. The on-site attraction (U 0) the homogeneous ground state antiferromagnetic solutions of the doped system found in a mean-field approximation are shown to be unstable with respect to a phase separation with the charge and spin subsystems behaving like immiscible quantum liquids. Puzzlingly, with lowering the temperature one can observe two sequential phase transitions: first, an antiferromagnetic ordering in the spin subsystem diluted by randomly distributed charges, then, a charge condensation in the charge droplets. The effects are illustrated by the Monte-Carlo calculations of the specific heat and longitudinal magnetic susceptibility.

  2. Alternator control for battery charging

    Science.gov (United States)

    Brunstetter, Craig A.; Jaye, John R.; Tallarek, Glen E.; Adams, Joseph B.

    2015-07-14

    In accordance with an aspect of the present disclosure, an electrical system for an automotive vehicle has an electrical generating machine and a battery. A set point voltage, which sets an output voltage of the electrical generating machine, is set by an electronic control unit (ECU). The ECU selects one of a plurality of control modes for controlling the alternator based on an operating state of the vehicle as determined from vehicle operating parameters. The ECU selects a range for the set point voltage based on the selected control mode and then sets the set point voltage within the range based on feedback parameters for that control mode. In an aspect, the control modes include a trickle charge mode and battery charge current is the feedback parameter and the ECU controls the set point voltage within the range to maintain a predetermined battery charge current.

  3. Rewritable artificial magnetic charge ice.

    Science.gov (United States)

    Wang, Yong-Lei; Xiao, Zhi-Li; Snezhko, Alexey; Xu, Jing; Ocola, Leonidas E; Divan, Ralu; Pearson, John E; Crabtree, George W; Kwok, Wai-Kwong

    2016-05-20

    Artificial ices enable the study of geometrical frustration by design and through direct observation. However, it has proven difficult to achieve tailored long-range ordering of their diverse configurations, limiting both fundamental and applied research directions. We designed an artificial spin structure that produces a magnetic charge ice with tunable long-range ordering of eight different configurations. We also developed a technique to precisely manipulate the local magnetic charge states and demonstrate write-read-erase multifunctionality at room temperature. This globally reconfigurable and locally writable magnetic charge ice could provide a setting for designing magnetic monopole defects, tailoring magnonics, and controlling the properties of other two-dimensional materials. Copyright © 2016, American Association for the Advancement of Science.

  4. CHARGEd with neural crest defects.

    Science.gov (United States)

    Pauli, Silke; Bajpai, Ruchi; Borchers, Annette

    2017-10-30

    Neural crest cells are highly migratory pluripotent cells that give rise to diverse derivatives including cartilage, bone, smooth muscle, pigment, and endocrine cells as well as neurons and glia. Abnormalities in neural crest-derived tissues contribute to the etiology of CHARGE syndrome, a complex malformation disorder that encompasses clinical symptoms like coloboma, heart defects, atresia of the choanae, retarded growth and development, genital hypoplasia, ear anomalies, and deafness. Mutations in the chromodomain helicase DNA-binding protein 7 (CHD7) gene are causative of CHARGE syndrome and loss-of-function data in different model systems have firmly established a role of CHD7 in neural crest development. Here, we will summarize our current understanding of the function of CHD7 in neural crest development and discuss possible links of CHARGE syndrome to other developmental disorders. © 2017 Wiley Periodicals, Inc.

  5. 75 FR 7411 - Schedule of Water Charges

    Science.gov (United States)

    2010-02-19

    ... COMMISSION 18 CFR Part 410 Schedule of Water Charges AGENCY: Delaware River Basin Commission. ACTION: Notice... Regulations--Water Supply Charges to revise the schedule of water charges. DATES: The Commission will hold a... the subject line ``Schedule of Water Charges.'' FOR FURTHER INFORMATION, CONTACT: Please contact Paula...

  6. 76 FR 10233 - Schedule of Water Charges

    Science.gov (United States)

    2011-02-24

    ... COMMISSION 18 CFR Part 420 Schedule of Water Charges AGENCY: Delaware River Basin Commission. ACTION: Final...--Water Supply Charges. Accordingly, the Commission's water charging rates for consumptive use and non.... FOR FURTHER INFORMATION CONTACT: For questions about the water charging program, please contact Ms...

  7. Zp-graded charge coherent states

    Science.gov (United States)

    Chung, Won Sang

    2014-06-01

    A new kind of charge coherent state called a Zp-graded charge coherent state is constructed by using the complex solution of the equation qp = 1. The p-1 charge operators are also explicitly constructed. We explicitly investigate some nonclassical properties for the Z3-graded charge coherent state.

  8. The tight binding model study of the role of anisotropic AFM spin ordering in the charge ordered CMR manganites

    Science.gov (United States)

    Kar, J. K.; Panda, Saswati; Rout, G. C.

    2017-05-01

    We propose here a tight binding model study of the interplay between charge and spin orderings in the CMR manganites taking anisotropic effect due to electron hoppings and spin exchanges. The Hamiltonian consists of the kinetic energies of eg and t2g electrons of manganese ion. It further includes double exchange and Heisenberg interactions. The charge density wave interaction (CDW) describes an extra mechanism for the insulating character of the system. The CDW gap and spin parameters are calculated using Zubarev's Green's function technique and computed self-consistently. The results are reported in this communication.

  9. Nanotribology of charged polymer brushes

    Science.gov (United States)

    Klein, Jacob

    Polymers at surfaces, whose modern understanding may be traced back to early work by Sam Edwards1, have become a paradigm for modification of surface properties, both as steric stabilizers and as remarkable boundary lubricants2. Charged polymer brushes are of particular interest, with both technological implications and especially biological relevance where most macromolecules are charged. In the context of biolubrication, relevant in areas from dry eye syndrome to osteoarthritis, charged polymer surface phases and their complexes with other macromolecules may play a central role. The hydration lubrication paradigm, where tenaciously-held yet fluid hydration shells surrounding ions or zwitterions serve as highly-efficient friction-reducing elements, has been invoked to understand the excellent lubrication provided both by ionized3 and by zwitterionic4 brushes. In this talk we describe recent advances in our understanding of the nanotribology of such charged brush systems. We consider interactions between charged end-grafted polymers, and how one may disentangle the steric from the electrostatic surface forces5. We examine the limits of lubrication by ionized brushes, both synthetic and of biological origins, and how highly-hydrated zwitterionic chains may provide extremely effective boundary lubrication6. Finally we describe how the lubrication of articular cartilage in the major joints, a tribosystem presenting some of the greatest challenges and opportunities, may be understood in terms of a supramolecular synergy between charged surface-attached polymers and zwitterionic groups7. Work supported by European Research Council (HydrationLube), Israel Science Foundation (ISF), Petroleum Research Fund of the American Chemical Society, ISF-NSF China Joint Program.

  10. Bounds on charged lepton mixing with exotic charged leptons Ф

    Indian Academy of Sciences (India)

    EL. 0-. R = 0-. OR. 0-. ER. (2) in which subscripts 'O' and 'E' stand for ordinary and exotic leptons respectively. Here we classify all charged leptons as either ordinary or exotic according to their ... EL is a column vector of СL exotic fields. ..... universal reduction of the strength of the normal neutral current, due to mixing.

  11. The Shaped Charge Concept. Part 3. Applications of Shaped Charges

    Science.gov (United States)

    1990-10-01

    perforating charges. Well perforator cones usually have an apex angle of 450 to About 600. The smaller angle increases penetation , but the hole size is...hole digging and underwaterdemlition via shaped charles . Byei (1949.1950) picacuw novel shaped chare designs for mining, hole drilling, and boulde

  12. Aircraft Battery State of Charge and Charge Control System.

    Science.gov (United States)

    1987-04-01

    electrode for oxygen comsumption . This concept divides the functions of charge and discharge and eliminates prob- lems encountered in conventional two...Marathon batteries will be performed at constant low temperatures. Two more aircraft batteries-- General Electric and one to be furnished by the

  13. Charge densities and charge noise in mesoscopic conductors

    Indian Academy of Sciences (India)

    We introduce a hierarchy of density of states to characterize the charge distribution in a mesoscopic conductor. At the bottom of this hierarchy are the partial density of states which represent the contribution to the local density of states if both the incident and the out-going scattering channel is prescribed. The partial density ...

  14. Ion-Exchange Chromatography: Basic Principles and Application.

    Science.gov (United States)

    Cummins, Philip M; Rochfort, Keith D; O'Connor, Brendan F

    2017-01-01

    Ion-Exchange Chromatography (IEC) allows for the separation of ionizable molecules on the basis of differences in charge properties. Its large sample-handling capacity, broad applicability (particularly to proteins and enzymes), moderate cost, powerful resolving ability, and ease of scale-up and automation have led to it becoming one of the most versatile and widely used of all liquid chromatography (LC) techniques. In this chapter, we review the basic principles of IEC, as well as the broader criteria for selecting IEC conditions. By way of further illustration, we outline basic laboratory protocols to partially purify a soluble serine peptidase from bovine whole brain tissue, covering crude tissue extract preparation through to partial purification of the target enzyme using anion-exchange chromatography. Protocols for assaying total protein and enzyme activity in both pre- and post-IEC fractions are also described.

  15. Spin relaxation via exchange with donor impurity-bound electrons

    Science.gov (United States)

    Appelbaum, Ian

    In the Bir-Aronov-Pikus depolarization process affecting conduction electrons in p-type cubic semiconductors, spin relaxation is driven by exchange with short-lived valence band hole states. We have identified an analogous spin relaxation mechanism in nominally undoped silicon at low temperatures, when many electrons are bound to dilute dopant ion potentials. Inelastic scattering with externally injected conduction electrons accelerated by electric fields can excite transitions into highly spin-orbit-mixed bound excited states, driving strong spin relaxation of the conduction electrons via exchange interaction. We reveal the consequences of this spin depolarization mechanism both below and above the impact ionization threshold, where conventional charge and spin transport are restored. Based upon: Lan Qing, Jing Li, Ian Appelbaum, and Hanan Dery, Phys Rev. B 91, 241405(R) (2015). We acknowledge support from NSF, DTRA, and ONR.

  16. Autonomous Electrical Vehicles’ Charging Station

    Directory of Open Access Journals (Sweden)

    Józef Paska

    2016-09-01

    Full Text Available This paper presents a model of an autonomous electrical vehicles’ charging station. It consists of renewable energy sources: wind turbine system, photovoltaic cells, as well as an energy storage, load, and EV charging station. In order to optimise the operating conditions, power electronic converters were added to the system. The model was implemented in the Homer Energy programme. The first part of the paper presents the design assumptions and technological solutions. Further in the paper simulation results are discussed and analysed, and then problems observed in the simulation and possible solutions.

  17. Charge confinement by classical instabilities

    Energy Technology Data Exchange (ETDEWEB)

    Hey, A.J.G.; Mandula, J.E.

    1979-03-15

    The theory of classical massless scalar electrodynamics in the presence of a large external source is examined in both one and three spatial dimensions. In three dimensions the Coulomb solution is shown to be unstable above a critical coupling strength; the one-dimensional Coulomb solution is shown to be unstable for any value of the coupling. Finite-energy solutions of the one-dimensional problem are explicitly exhibited. In these solutions, the external charge is completely screened by the charged scalar field, and no trace remains of the original long-range potential.

  18. Pu Anion Exchange Process Intensification

    Energy Technology Data Exchange (ETDEWEB)

    Taylor-Pashow, K. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

    2015-10-08

    This project seeks to improve the efficiency of the plutonium anion-exchange process for purifying Pu through the development of alternate ion-exchange media. The objective of the project in FY15 was to develop and test a porous foam monolith material that could serve as a replacement for the current anion-exchange resin, Reillex® HPQ, used at the Savannah River Site (SRS) for purifying Pu. The new material provides advantages in efficiency over the current resin by the elimination of diffusive mass transport through large granular resin beads. By replacing the large resin beads with a porous foam there is much more efficient contact between the Pu solution and the anion-exchange sites present on the material. Several samples of a polystyrene based foam grafted with poly(4-vinylpyridine) were prepared and the Pu sorption was tested in batch contact tests.

  19. Liquid droplet heat exchanger studies

    Science.gov (United States)

    Bruckner, A. P.; Hedges, D. E.; Yungster, S.

    1987-01-01

    Recent analytical and experimental investigations of the liquid droplet heat exchanger (LDHX) concept for space power applications are described. The performance of the LDHX is compared to that of a conventional heat exchanger for heat rejection applications in a Brayton cycle, using the mass-specific heat exchanger effectiveness as a figure of merit. It is shown that the LDHX has an order of magnitude advantage over the conventional heat exchanger. Furthermore, significant improvement in cycle efficiency and power to mass ratio is possible. Two-phase flow experiments in a laboratory scale LDHX, using air and water as the two media, show very good agreement with the quasi-one-dimensional model used in the parametric studies.

  20. Estimating Foreign Exchange Reserve Adequacy

    Directory of Open Access Journals (Sweden)

    Abdul Hakim

    2013-04-01

    Full Text Available Accumulating foreign exchange reserves, despite their cost and their impacts on other macroeconomics variables, provides some benefits. This paper models such foreign exchange reserves. To measure the adequacy of foreign exchange reserves for import, it uses total reserves-to-import ratio (TRM. The chosen independent variables are gross domestic product growth, exchange rates, opportunity cost, and a dummy variable separating the pre and post 1997 Asian financial crisis. To estimate the risky TRM value, this paper uses conditional Value-at-Risk (VaR, with the help of Glosten-Jagannathan-Runkle (GJR model to estimate the conditional volatility. The results suggest that all independent variables significantly influence TRM. They also suggest that the short and long run volatilities are evident, with the additional evidence of asymmetric effects of negative and positive past shocks. The VaR, which are calculated assuming both normal and t distributions, provide similar results, namely violations in 2005 and 2008.

  1. VLER Health Exchange by Area

    Data.gov (United States)

    Department of Veterans Affairs — “Connect Your Docs” through the Virtual Lifetime Electronic Record (VLER) Health Exchange program. This program gives VA and community health care providers secure...

  2. Counterflow Regolith Heat Exchanger Project

    Data.gov (United States)

    National Aeronautics and Space Administration — The counterflow regolith heat exchanger (CoRHE) is a device that transfers heat from hot regolith to cold regolith. The CoRHE is essentially a tube-in-tube heat...

  3. Computer simulation of methanol exchange dynamics around cations and anions

    Energy Technology Data Exchange (ETDEWEB)

    Roy, Santanu; Dang, Liem X.

    2016-03-03

    In this paper, we present the first computer simulation of methanol exchange dynamics between the first and second solvation shells around different cations and anions. After water, methanol is the most frequently used solvent for ions. Methanol has different structural and dynamical properties than water, so its ion solvation process is different. To this end, we performed molecular dynamics simulations using polarizable potential models to describe methanol-methanol and ion-methanol interactions. In particular, we computed methanol exchange rates by employing the transition state theory, the Impey-Madden-McDonald method, the reactive flux approach, and the Grote-Hynes theory. We observed that methanol exchange occurs at a nanosecond time scale for Na+ and at a picosecond time scale for other ions. We also observed a trend in which, for like charges, the exchange rate is slower for smaller ions because they are more strongly bound to methanol. This work was supported by the US Department of Energy, Office of Science, Office of Basic Energy Sciences, Division of Chemical Sciences, Geosciences, and Biosciences. The calculations were carried out using computer resources provided by the Office of Basic Energy Sciences.

  4. Transient response of a proton exchange membrane fuel cell

    Science.gov (United States)

    Weydahl, Helge; Møller-Holst, Steffen; Hagen, Georg; Børresen, Børre

    The transient response of a proton exchange membrane fuel cell (PEMFC) supplied with pure hydrogen and oxygen was investigated by load step measurements assisted by electrochemical impedance spectroscopy and chronoamperometry. Using an in-house designed resistance board, the uncontrolled response in both cell voltage and current upon step changes in a resistive load was observed. The PEMFC was found to respond quickly and reproducibly to load changes. The transient PEMFC response was limited by a cathodic charge transfer process with a potential-dependent response time. For load steps to high-current densitities, a second transient process with a constant response time was observed. This transient was offset from the charge transfer transient by a temporarily stable plateau. Results from chronoamperometry indicated that the second transient could be related to a diffusion process. Transient paths were plotted in the V- i diagram, matching a predicted pattern with overshooting cell voltage and current during a load step.

  5. International Prices and Exchange Rates

    OpenAIRE

    Gopinath, Gita; Burstein, Ariel

    2013-01-01

    We survey the recent empirical and theoretical developments in the literature on the relation between prices and exchange rates. After updating some of the major findings in the empirical literature we present a simple framework to interpret this evidence. We review theoretical models that generate insensitivity of prices to exchange rate changes through variable markups, both under flexible prices and nominal rigidities, first in partial equilibrium and then in general equilibrium.

  6. Exchange rate determination in Vietnam

    OpenAIRE

    Thai-Ha Le

    2015-01-01

    This study investigates the determinants of the exchange rate in Vietnam and suggests policy implications. Gregory-Hansen cointegration tests and generalised variance decomposition (VDC) analysis were applied to monthly data from July 2004 to December 2013. The model was built based on the three popular approaches to exchange rate determination, which are purchasing power parity (PPP) approach, balance of payment (BOP) approach, and monetary and portfolio approach. This study finds that the p...

  7. Shared Year Exchange in Nursing

    DEFF Research Database (Denmark)

    Vedsegaard, Helle Wendner; Wederkinck, Elisabeth

    2010-01-01

    Beskrivelse af Shared Year Exchange in Nursing, et udviklingsporjekt omhandlende udvikling, beskrivelse og implementering af et fælles studieår for sygeplejerskestuderende ved Metropol og La Trobe University Australien.......Beskrivelse af Shared Year Exchange in Nursing, et udviklingsporjekt omhandlende udvikling, beskrivelse og implementering af et fælles studieår for sygeplejerskestuderende ved Metropol og La Trobe University Australien....

  8. Measurements of the Total Charge-Changing Cross Sections for Collisions of Fast Ions with Target Gas Using High Current Experiment

    Energy Technology Data Exchange (ETDEWEB)

    Covo, Michel Kireeff; Molvik, Arthur W.; Kaganovich, Igor D.; Shnidman, Ariel; Vujic, Jasmina L.

    2009-04-13

    The sum of ionization and charge-exchange cross sections of several gas targets (H2, N2, He, Ne, Kr, Xe, Ar, and water vapor) impacted by 1MeV K+ beam are measured. In a high current ion beam, the self-electric field of the beam is high enough that ions produced from the gas ionization or charge exchange by the ion beam are quickly swept to the sides of accelerator. The flux of the expelled ions is measured by a retarding field analyzer. This allows accurate measuring of the total charge-changing cross sections (ionization plus charge exchange) of the beam interaction with gas. Cross sections for H2, He, and N2 are simulated using classical trajectory Monte Carlo (CTMC) method and compared with the experimental results, showing good agreement.

  9. Heisenberg exchange enhancement by orbital relaxation in cuprate compounds

    NARCIS (Netherlands)

    van Oosten, A.B.; Broer, R.; Nieuwpoort, WC

    1996-01-01

    We calculate the Heisenberg exchange J in the quasi-2D antiferromagnetic cuprates La2CuO4, YBa2Cu3O6, Nd2CuO4 and Sr2CuO2Cl2. We apply all-electron (MC)SCF and non-orthogonal CI calculations to [Cu2O11](18-), [Cu2O9](14-), [Cu2O7](10-) and [Cu2O7Cl4](14-) clusters in a model charge embedding. The

  10. Scalable Graphene-Based Membranes for Ionic Sieving with Ultrahigh Charge Selectivity.

    Science.gov (United States)

    Hong, Seunghyun; Constans, Charlotte; Surmani Martins, Marcos Vinicius; Seow, Yong Chin; Guevara Carrió, Juan Alfredo; Garaj, Slaven

    2017-02-08

    Nanostructured graphene-oxide (GO) laminate membranes, exhibiting ultrahigh water flux, are excellent candidates for next generation nanofiltration and desalination membranes, provided the ionic rejection could be further increased without compromising the water flux. Using microscopic drift-diffusion experiments, we demonstrated the ultrahigh charge selectivity for GO membranes, with more than order of magnitude difference in the permeabilities of cationic and anionic species of equivalent hydration radii. Measuring diffusion of a wide range of ions of different size and charge, we were able to clearly disentangle different physical mechanisms contributing to the ionic sieving in GO membranes: electrostatic repulsion between ions and charged chemical groups; and the compression of the ionic hydration shell within the membrane's nanochannels, following the activated behavior. The charge-selectivity allows us to rationally design membranes with increased ionic rejection and opens up the field of ion exchange and electrodialysis to the GO membranes.

  11. Interaction of low-energy highly charged ions with matter; Wechselwirkung niederenergetischer hochgeladener Ionen mit Materie

    Energy Technology Data Exchange (ETDEWEB)

    Ginzel, Rainer

    2010-06-09

    The thesis presented herein deals with experimental studies of the interaction between highly charged ions and neutral matter at low collision energies. The energy range investigated is of great interest for the understanding of both charge exchange reactions between ions comprising the solar wind and various astrophysical gases, as well as the creation of near-surface nanostructures. Over the course of this thesis an experimental setup was constructed, capable of reducing the kinetic energy of incoming ions by two orders of magnitude and finally focussing the decelerated ion beam onto a solid or gaseous target. A coincidence method was employed for the simultaneous detection of photons emitted during the charge exchange process together with the corresponding projectile ions. In this manner, it was possible to separate reaction channels, whose superposition presumably propagated large uncertainties and systematic errors in previous measurements. This work has unveiled unexpectedly strong contributions of slow radiative decay channels and clear evidence of previously only postulated decay processes in charge exchange-induced X-ray spectra. (orig.)

  12. Evaluation of the thermal effect on separation selectivity in anion-exchange processes using superheated water ion-exchange chromatography.

    Science.gov (United States)

    Shibukawa, Masami; Taguchi, Akihiko; Suzuki, Yusuke; Saitoh, Kazunori; Hiaki, Toshihiko; Yarita, Takashi

    2012-07-07

    The thermal effect on retention and separation selectivity of inorganic anions and aromatic sulfonate ions in anion-exchange chromatography is studied on a quaternized styrene-divinylbenzene copolymer anion-exchange column in the temperature range of 40-120 °C using superheated water chromatography. The selectivity coefficient for a pair of identically charged anions approaches unity as temperature increases provided the ions have the same effective size, such that the retention of an analyte ion decreases with an increase in temperature when the analyte ion has stronger affinity for the ion-exchanger than that of the eluent counterion, whereas it increases when it has weaker affinity. The change in anion-exchange selectivity with temperature observed with superheated water chromatography has been discussed on the basis of the effect of temperature on hydration of the ions. At elevated temperatures, especially in superheated water, the electrostatic interaction or association of the ions with the fixed ion in the resin phase becomes a predominant factor resulting in a different separation selectivity from that obtained at ambient temperature.

  13. Price Based Electric Vehicle Charging

    DEFF Research Database (Denmark)

    Mahat, Pukar; Handl, Martin; Kanstrup, Kenneth

    2012-01-01

    It is expected that a lot of the new light vehicles in the future will be electrical vehicles (EV). The storage capacity of these EVs has the potential to complement renewable energy resources and mitigate its intermittency. However, EV charging may have negative impact on the power grid...

  14. Take Charge of Your Career

    Science.gov (United States)

    Brown, Marshall A.

    2013-01-01

    Today's work world is full of uncertainty. Every day, people hear about another organization going out of business, downsizing, or rightsizing. To prepare for these uncertain times, one must take charge of their own career. This article presents some tips for surviving in today's world of work: (1) Be self-managing; (2) Know what you…

  15. Sounding the Charge for Change

    Science.gov (United States)

    Haycock, Brooke

    2011-01-01

    Lessons emerging now from successful schools have much to teach us about the practices of dynamic leaders. But if leaders can't talk about the what and the why of those practices in ways that inspire their staffs to action, they may change programs or policies, but they'll never change people. There are hard-charging school and district leaders…

  16. A charged spherically symmetric solution

    Indian Academy of Sciences (India)

    By setting the charge contribution to zero we regain an (uncharged) perfect fluid solution found previously with the equation of state =+ constant, which is a generalisation of a stiff equation of state. Our class of ... Govinder1. School of Mathematical and Statistical Sciences, University of Natal, Durban 4041, South Africa ...

  17. Space-charge limited photocurrent

    NARCIS (Netherlands)

    Mihailetchi, VD; Wildeman, J; Blom, PWM

    2005-01-01

    In 1971 Goodman and Rose predicted the occurrence of a fundamental electrostatic limit for the photocurrent in semiconductors at high light intensities. Blends of conjugated polymers and fullerenes are an ideal model system to observe this space-charge limit experimentally, since they combine an

  18. Smart charging in the Netherlands

    NARCIS (Netherlands)

    Tamis, M.; van den Hoed, R.; Thorsdottir, H.

    2017-01-01

    As the Dutch electric vehicle (EV) fleet continues to expand, so will the amount of charging sessions increase. This expanding demand for energy will add on to the already existing strain on the grid, primarily during peak hours on workdays in the early morning and evening. This growing energy

  19. A charged spherically symmetric solution

    Indian Academy of Sciences (India)

    Despite the global observed neutrality of the universe, it is important to study the Einstein–Maxwell field equations for a number of reasons [2]. For example, the role of charge in gravitational collapse has been pointed out in a number of treatments. Also, the electromagnetic field may play a role in preventing a Big Bang ...

  20. Charge transfer dissociation (CTD) mass spectrometry of peptide cations using kiloelectronvolt helium cations.

    Science.gov (United States)

    Hoffmann, William D; Jackson, Glen P

    2014-11-01

    A kiloelectronvolt beam of helium ions is used to ionize and fragment precursor peptide ions starting in the 1+ charge state. The electron affinity of helium cations (24.6 eV) exceeds the ionization potential of protonated peptides and can therefore be used to abstract an electron from--or charge exchange with--the isolated precursor ions. Kiloelectronvolt energies are used, (1) to overcome the Coulombic repulsion barrier between the cationic reactants, (2) to overcome ion-defocussing effects in the ion trap, and (3) to provide additional activation energy. Charge transfer dissociation (CTD) of the [M+H](+) precursor of Substance P gives product ions such as [M+H](2+•) and a dominant series of a ions in both the 1+ and 2+ charge states. These observations, along with the less-abundant a + 1 ions, are consistent with ultraviolet photodissociation (UVPD) results of others and indicate that C-C(α) cleavages are possible through charge exchange with helium ions. Although the efficiencies and timescale of CTD are not yet suitable for on-line chromatography, this new approach to ion activation provides an additional potential tool for the interrogation of gas phase ions.

  1. Liquid cooled plate heat exchanger for battery cooling of an electric vehicle (EV)

    Science.gov (United States)

    Rahman, M. M.; Rahman, H. Y.; Mahlia, T. M. I.; Sheng, J. L. Y.

    2016-03-01

    A liquid cooled plate heat exchanger was designed to improve the battery life of an electric vehicle which suffers from premature aging or degradation due to the heat generation during discharging and charging period. Computational fluid dynamics (CFD) was used as a tool to analyse the temperature distribution when a constant surface heat flux was set at the bottom surface of the battery. Several initial and boundary conditions were set based on the past studies on the plate heat exchanger in the simulation software. The design of the plate heat exchanger was based on the Nissan Leaf battery pack to analyse the temperature patterns. Water at different mass flow rates was used as heat transfer fluid. The analysis revealed the designed plate heat exchanger could maintain the surface temperature within the range of 20 to 40°C which is within the safe operating temperature of the battery.

  2. Fair Exchange in Strand Spaces

    Directory of Open Access Journals (Sweden)

    Joshua D. Guttman

    2009-10-01

    Full Text Available Many cryptographic protocols are intended to coordinate state changes among principals. Exchange protocols coordinate delivery of new values to the participants, e.g. additions to the set of values they possess. An exchange protocol is fair if it ensures that delivery of new values is balanced: If one participant obtains a new possession via the protocol, then all other participants will, too. Fair exchange requires progress assumptions, unlike some other protocol properties. The strand space model is a framework for design and verification of cryptographic protocols. A strand is a local behavior of a single principal in a single session of a protocol. A bundle is a partially ordered global execution built from protocol strands and adversary activities. The strand space model needs two additions for fair exchange protocols. First, we regard the state as a multiset of facts, and we allow strands to cause changes in this state via multiset rewriting. Second, progress assumptions stipulate that some channels are resilient-and guaranteed to deliver messages-and some principals are assumed not to stop at certain critical steps. This method leads to proofs of correctness that cleanly separate protocol properties, such as authentication and confidentiality, from invariants governing state evolution. G. Wang's recent fair exchange protocol illustrates the approach.

  3. Pu Anion Exchange Process Intensification

    Energy Technology Data Exchange (ETDEWEB)

    Taylor-Pashow, Kathryn M. L. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

    2017-10-06

    This research is focused on improving the efficiency of the anion exchange process for purifying plutonium. While initially focused on plutonium, the technology could also be applied to other ion-exchange processes. Work in FY17 focused on the improvement and optimization of porous foam columns that were initially developed in FY16. These foam columns were surface functionalized with poly(4-vinylpyridine) (PVP) to provide the Pu specific anion-exchange sites. Two different polymerization methods were explored for maximizing the surface functionalization with the PVP. The open-celled polymeric foams have large open pores and large surface areas available for sorption. The fluid passes through the large open pores of this material, allowing convection to be the dominant mechanism by which mass transport takes place. These materials generally have very low densities, open-celled structures with high cell interconnectivity, small cell sizes, uniform cell size distributions, and high structural integrity. These porous foam columns provide advantages over the typical porous resin beads by eliminating the slow diffusion through resin beads, making the anion-exchange sites easily accessible on the foam surfaces. The best performing samples exceeded the Pu capacity of the commercially available resin, and also offered the advantage of sharper elution profiles, resulting in a more concentrated product, with less loss of material to the dilute heads and tails cuts. An alternate approach to improving the efficiency of this process was also explored through the development of a microchannel array system for performing the anion exchange.

  4. Electrically Switched Cesium Ion Exchange

    Energy Technology Data Exchange (ETDEWEB)

    JPH Sukamto; ML Lilga; RK Orth

    1998-10-23

    This report discusses the results of work to develop Electrically Switched Ion Exchange (ESIX) for separations of ions from waste streams relevant to DOE site clean-up. ESIX combines ion exchange and electrochemistry to provide a selective, reversible method for radionuclide separation that lowers costs and minimizes secondary waste generation typically associated with conventional ion exchange. In the ESIX process, an electroactive ion exchange film is deposited onto. a high surface area electrode, and ion uptake and elution are controlled directly by modulating the potential of the film. As a result, the production of secondary waste is minimized, since the large volumes of solution associated with elution, wash, and regeneration cycles typical of standard ion exchange are not needed for the ESIX process. The document is presented in two parts: Part I, the Summary Report, discusses the objectives of the project, describes the ESIX concept and the approach taken, and summarizes the major results; Part II, the Technology Description, provides a technical description of the experimental procedures and in-depth discussions on modeling, case studies, and cost comparisons between ESIX and currently used technologies.

  5. charge

    African Journals Online (AJOL)

    Often, the events that initiate the lecture may carry much pain occasioned by man' s inhumanity to man-such as we .... Dental Consultant' Association of Nigeria. At our inception we bound ourselves by certain principles .... defence of felony or unprofessional conduct, but an erring colleague rest assured that he or she will be.

  6. Pressure Dependence of Insulator-Insulator Contact Charging

    Science.gov (United States)

    Hogue, Michael D.

    2005-01-01

    The mechanism of insulator-insulator triboelectric (contact) charging is being studied by the Electrostatics and Surface Physics Laboratory at KSC. The hypothesis that surface ion exchange is the primary mechanism is being tested experimentally. A two-phase model based on a small partial pressure of singly charged ions in an ambient ideal gas in equilibrium with a submonolayer adsorbed film will provide predictions about charging as a function Of ion mass, pressure, temperature, and surface adsorption energy. Interactions between ions will be considered in terms of coulombic and screened potential energies. This work is yielding better understanding of the triboelectrification of insulators, which is an important problem in. space exploration technology. The work is also relevant to important industrial processes such as xerography and the application of paints and coatings. Determining a better understanding of the fundamental mechanism of insulator-insulator triboelectrification will hopefully lead to better means of eliminating or at least mitigating its hazards and enhancing its useful applications.

  7. Solute location in a nanoconfined liquid depends on charge distribution

    Science.gov (United States)

    Harvey, Jacob A.; Thompson, Ward H.

    2015-07-01

    Nanostructured materials that can confine liquids have attracted increasing attention for their diverse properties and potential applications. Yet, significant gaps remain in our fundamental understanding of such nanoconfined liquids. Using replica exchange molecular dynamics simulations of a nanoscale, hydroxyl-terminated silica pore system, we determine how the locations explored by a coumarin 153 (C153) solute in ethanol depend on its charge distribution, which can be changed through a charge transfer electronic excitation. The solute position change is driven by the internal energy, which favors C153 at the pore surface compared to the pore interior, but less so for the more polar, excited-state molecule. This is attributed to more favorable non-specific solvation of the large dipole moment excited-state C153 by ethanol at the expense of hydrogen-bonding with the pore. It is shown that a change in molecule location resulting from shifts in the charge distribution is a general result, though how the solute position changes will depend upon the specific system. This has important implications for interpreting measurements and designing applications of mesoporous materials.

  8. Interfacial charge separation and trapping in composite photocatalysts

    Science.gov (United States)

    Chakarov, Dinko

    We explore the phenomena of interfacial charge separation and trapping in composite metal-semiconductor systems and the interaction (energy and charge exchange) between optically excited nanoparticles and the surrounding medium. Disc-shaped copper nanoparticles (Cu NPs) were fabricated by hole-mask colloidal lithography on bare and thin titania film covered fused silica substrates. The dynamics of Cu oxide formation around the NPs were studied in water by localized surface plasmon resonance (LSPR) spectroscopy. We found that the oxidation rate is strongly enhanced under UV irradiation when the NPs are on the surface of the titania film, in comparison to NPs deposited on an inert fused silica substrate. The reason is sought in the ability of TiO2 to create hydroxyl radicals with strong oxidative potential in water under UV irradiation and the charge transfer at the interface between the Cu NPs and the TiO2. The results demonstrate the potential of using LSPR spectroscopy to monitor the oxidation of Cu NPs in situ and in different environments. The work was financially supported by The Nordic Energy Research Council through Project N-I-S-F-D.

  9. Invisible Surface Charge Pattern on Inorganic Electrets

    DEFF Research Database (Denmark)

    Wang, Fei; Hansen, Ole

    2013-01-01

    We propose an easy method to pattern the surface charge of ${\\rm SiO}_{2}$ electrets without patterning the dielectric layer. By eliminating the use of metal guard electrodes, both the charge efficiency and the surface charge stability in humid environments improve. We apply the concept to a vibr......We propose an easy method to pattern the surface charge of ${\\rm SiO}_{2}$ electrets without patterning the dielectric layer. By eliminating the use of metal guard electrodes, both the charge efficiency and the surface charge stability in humid environments improve. We apply the concept...

  10. Charge symmetry at the partonic level

    Energy Technology Data Exchange (ETDEWEB)

    Londergan, J. T.; Peng, J. C.; Thomas, A. W.

    2010-07-01

    This review article discusses the experimental and theoretical status of partonic charge symmetry. It is shown how the partonic content of various structure functions gets redefined when the assumption of charge symmetry is relaxed. We review various theoretical and phenomenological models for charge symmetry violation in parton distribution functions. We summarize the current experimental upper limits on charge symmetry violation in parton distributions. A series of experiments are presented, which might reveal partonic charge symmetry violation, or alternatively might lower the current upper limits on parton charge symmetry violation.

  11. Stability of charged strange quark stars

    Energy Technology Data Exchange (ETDEWEB)

    Arbañil, José D. V.; Malheiro, Manuel [Departamento de Física, Instituto Tecnológico de Aeronáutica, Centro Técnico Aeroespacial, 12228-900 São José dos Campos, SP (Brazil)

    2015-12-17

    We investigate the hydrostatic equilibrium and the stability of charged stars made of a charged perfect fluid. The matter contained in the star follows the MIT bag model equation of state and the charge distribution to a power-law of the radial coordinate. The hydrostatic equilibrium and the stability of charged strange stars are analyzed using the Tolman-Oppenheimer-Volkoff equation and the Chandrasekhar’s equation pulsation, respectively. These two equation are modified from their original form to the inclusion of the electric charge. We found that the stability of the star decreases with the increment of the central energy density and with the increment of the amount of charge.

  12. An Research on Electrical Vehicle'S Charge-Discharge Behavior Based on Logit Model

    Science.gov (United States)

    Xiaoyin, Wang; Junyong, Liu

    Electric Vehicle is the future trend of the automobile industry, and the energy exchanging between the electrical vehicles and the grid through the vehicle-to-grid (V2G) technology becomes possiable. V2G leads to a rapid load growth effecting the benefit of the grid, which wasn't discussed. The charge and discharge model of the electrical vehicles is discussed using the multinomial logit model based on the discrete choice theory, then preliminarily evaluates the effects of economic benefit both on the motorist and the grid. Finally, suggestions on period division and electricity pricing for charge and discharge of the electrical vehicle are given.

  13. Pervaporation with ion exchange membranes

    Energy Technology Data Exchange (ETDEWEB)

    Boeddeker, K.W.; Wenzlaff, A.

    1986-01-01

    Sorption and pervaporation of aqueous-organic solvent systems (water-ethanol; water-carboxylic acids) with commercial ion exchange membranes are compared to obtain information on polymersolvent interaction vs. coupling. Close agreement between sorption selectivity and pervaporation selectivity indicates coupling. If pervaporation is less selective than sorption, polymer-solvent interaction overtakes coupling, the limit of de-coupling being phase separation within the sorbate as signaled by a sudden increase in permeability of the lesser interacting component. As long as sorption and pervaporation operate in parallel, favoring enrichment of the same component, coupling enhances the separation effect. If pervaporation counteracts sorption, coupling is detrimental to the separation effect. Potential applications include the dehydration of pre-concentrated water-ethanol using anion exchange membranes, and the enrichment of acetic acid from dilute aqueous solution by pervaporative removal of water through cation exchange membranes.

  14. Geometrical charged-particle optics

    CERN Document Server

    Rose, Harald

    2012-01-01

    This second edition is an extended version of the first edition of Geometrical Charged-Particle Optics. The updated reference monograph is intended as a guide for researchers and graduate students who are seeking a comprehensive treatment of the design of instruments and beam-guiding systems of charged particles and their propagation in electromagnetic fields. Wave aspects are included in this edition for explaining electron holography, the Aharanov-Bohm effect and the resolution of electron microscopes limited by diffraction. Several methods for calculating the electromagnetic field are presented and procedures are outlined for calculating the properties of systems with arbitrarily curved axis. Detailed methods are presented for designing and optimizing special components such as aberration correctors, spectrometers, energy filters monochromators, ion traps, electron mirrors and cathode lenses. In particular, the optics of rotationally symmetric lenses, quadrupoles, and systems composed of these elements are...

  15. Charged gravastars in higher dimensions

    Directory of Open Access Journals (Sweden)

    S. Ghosh

    2017-04-01

    Full Text Available We explore possibility to find out a new model of gravastars in the extended D-dimensional Einstein–Maxwell space–time. The class of solutions as obtained by Mazur and Mottola of a neutral gravastar [1,2] have been observed as a competent alternative to D-dimensional versions of the Schwarzschild–Tangherlini black hole. The outer region of the charged gravastar model therefore corresponds to a higher dimensional Reissner–Nordström black hole. In connection to this junction conditions, therefore we have formulated mass and the related Equation of State of the gravastar. It has been shown that the model satisfies all the requirements of the physical features. However, overall observational survey of the results also provide probable indication of non-applicability of higher dimensional approach for construction of a gravastar with or without charge from an ordinary 4-dimensional seed as far as physical ground is concerned.

  16. The economics of workplace charging

    DEFF Research Database (Denmark)

    Fetene, Gebeyehu Manie; Hirte, Georg; Kaplan, Sigal

    2016-01-01

    To overcome the range-anxiety problem and further shortcomings associated with electric vehicles, workplace charging (WPC) is gaining increasing attention. We propose a microeconomic model of WPC and use the approach to shed light on the incentives and barriers employees and employers face when...... deciding on demand for and supply of WPC. It is shown that under market conditions there is no WPC contract an employer is willing to offer and at the same time the majority of employees is willing to accept. To overcome the lack of demand or underprovision of WPC we discuss various ‘remedies’, involving...... subsidies to charging facility costs and adjustments in electricity tariffs or loading technologies. We find that direct subsidies to WPC facilities or subsidies combined with specific energy price policies could be a way to foster WPC provision. In contrast measures on the employee side that may help...

  17. Charged gravastars in higher dimensions

    Energy Technology Data Exchange (ETDEWEB)

    Ghosh, S., E-mail: shnkghosh122@gmail.com [Department of Physics, Indian Institute of Engineering Science and Technology, B. Garden, Howrah 711103, West Bengal (India); Rahaman, F., E-mail: rahaman@associates.iucaa.in [Department of Mathematics, Jadavpur University, Kolkata 700032, West Bengal (India); Guha, B.K., E-mail: bkguhaphys@gmail.com [Department of Physics, Indian Institute of Engineering Science and Technology, B. Garden, Howrah 711103, West Bengal (India); Ray, Saibal, E-mail: saibal@associates.iucaa.in [Department of Physics, Government College of Engineering and Ceramic Technology, 73 A.C.B. Lane, Kolkata 700010, West Bengal (India)

    2017-04-10

    We explore possibility to find out a new model of gravastars in the extended D-dimensional Einstein–Maxwell space–time. The class of solutions as obtained by Mazur and Mottola of a neutral gravastar have been observed as a competent alternative to D-dimensional versions of the Schwarzschild–Tangherlini black hole. The outer region of the charged gravastar model therefore corresponds to a higher dimensional Reissner–Nordström black hole. In connection to this junction conditions, therefore we have formulated mass and the related Equation of State of the gravastar. It has been shown that the model satisfies all the requirements of the physical features. However, overall observational survey of the results also provide probable indication of non-applicability of higher dimensional approach for construction of a gravastar with or without charge from an ordinary 4-dimensional seed as far as physical ground is concerned.

  18. TOPICAL REVIEW: Highly charged ions

    Science.gov (United States)

    Gillaspy, J. D.

    2001-10-01

    This paper reviews some of the fundamental properties of highly charged ions, the methods of producing them (with particular emphasis on table-top devices), and their use as a tool for both basic science and applied technology. Topics discussed include: charge dependence and scaling laws along isoelectronic or isonuclear sequences (for wavefunction size or Bohr radius, ionization energy, dipole transition energy, relativistic fine structure, hyperfine structure, Zeeman effect, Stark effect, line intensities, linewidths, strength of parity violation, etc), changes in angular momentum coupling schemes, selection rules, interactions with surfaces, electron-impact ionization, the electron beam ion trap (EBIT), ion accelerators, atomic reference data, cosmic chronometers, laboratory x-ray astrophysics, vacuum polarization, solar flares, ion implantation, ion lithography, ion microprobes (SIMS and x-ray microscope), nuclear fusion diagnostics, nanotechnology, quantum computing, cancer therapy and biotechnology.

  19. Electrostatic charge characteristics of jet nebulized aerosols.

    Science.gov (United States)

    Kwok, Philip Chi Lip; Trietsch, Sebastiaan J; Kumon, Michiko; Chan, Hak-Kim

    2010-06-01

    Liquid droplets can be spontaneously charged in the absence of applied electric fields by spraying. It has been shown by computational simulation that charges may influence particle deposition in the airways. The electrostatic properties of jet nebulized aerosols and their potential effects on lung deposition have hardly been studied. A modified electrical low pressure impactor (ELPI) was employed to characterize the aerosol charges generated from jet nebulized commercial products. The charge and size measurements were conducted at 50% RH and 22 degrees C with a modified ELPI. Ventolin, Bricanyl, and Atrovent were nebulized using PARI LC Plus jet nebulizers coupled to a DeVilbiss Pulmo-Aide compressor. The aerosols were sampled in 30-sec durations. The drug deposits on the impactor stages were assayed chemically using high-performance liquid chromatography (HPLC). The charges of nebulized deionized water, isotonic saline, and the three commercial products diluted with saline were also measured to analyze the contributions of the major nebule ingredients on charging. No mass assays were performed on these runs. All three commercial nebules generated net negative charges. The magnitude of the charges reduced over the period of nebulization. Ventolin and Bricanyl yielded similar charge profiles. Highly variable charges were produced from deionized water. On the other hand, nebulized saline reproducibly generated net positive charges. Diluted commercial nebules showed charge polarity inversion. The charge profiles of diluted salbutamol and terbutaline solutions resembled those of saline, while the charges from diluted ipratropium solutions fluctuated near neutrality. The charge profiles were shown to be influenced by the concentration and physicochemical properties of the drugs, as well as the history of nebulization. The drugs may have unique isoelectric concentrations in saline at which the nebulized droplets would carry near-zero charges. According to results from

  20. Criminal Charges in Corporate Scandals

    Science.gov (United States)

    2004-04-26

    Criminal Charges in Corporate Scandals Summary Since the collapse of Enron Corp . in late 2001, there has been a series of scandals involving major U .S...to the series of corporate scandals that began with Enron by passing the Sarbanes-Oxley Act of 2002 . That law created a new oversight body for... corporate auditors, imposed new disclosure requirements on corporations , including a mandate that CEOs personally certify the accuracy of their firms